Sample records for worth actinide burner

  1. Evaluating the efficacy of a minor actinide burner

    Energy Technology Data Exchange (ETDEWEB)

    Dobbin, K.D.; Kessler, S.F.; Nelson, J.V.; Omberg, R.P.; Wootan, D.W.


    The efficacy of a minor actinide burner can be evaluated by comparing safety and economic parameters to the support ratio. Minor actinide mass produced per unit time in this number of Light Water Reactors (LWRs) can be burned during the same time period in one burner system. The larger the support ratio for a given set of safety and economic parameters, the better. To illustrate this concept, the support ratio for selected Liquid Metal Reactor (LMR) burner core designs was compared with corresponding coolant void worths, a fundamental safety concern following the Chernobyl accident. Results can be used to evaluate the cost in reduced burning of minor actinides caused by LMR sodium void reduction efforts or to compare with other minor actinide burner systems.

  2. Neutronics design study on a minor actinide burner for transmuting spent fuel

    Energy Technology Data Exchange (ETDEWEB)

    Choi, Hang Bok


    A liquid metal reactor was designed for the primary purpose of burning the minor actinide waste from commercial light water reactors. The design was constrained to maintain acceptable safety performance as measured by the burnup reactivity swing, the doppler coefficient, and the sodium void worth. Sensitivity studies were performed for homogeneous and decoupled core designs, and a minor actinide burner design was determined to maximize actinide consumption and satisfy safety constraints. One of the principal innovations was the use of two core regions, with a fissile plutonium outer core and an inner core consisting only of minor actinides. The physics studies performed here indicate that a 1200 MWth core is able to transmute the annual minor actinide inventory of about 16 LWRs and still exhibit reasonable safety characteristics. (author). 34 refs., 22 tabs., 14 figs.

  3. Actinide transmutation using inert matrix fuels versus recycle in a low conversion fast burner reactor

    Energy Technology Data Exchange (ETDEWEB)

    Deinert, M.R.; Schneider, E.A.; Recktenwald, G.; Cady, K.B. [The Department of Mechanical Engineering, The University of Texas at Austin, 1 University Station, C2200, Austin, 78712 (United States)


    would require an infinite fuel residence time. In previous work we have shown that the amount of fluence required to achieve a unit of burnup in yttrium stabilized ZrO{sub 2} based IMF with 85 w/o zirconium oxide and 15 w/o minor actinides (MA) and plutonium increases dramatically beyond 750 MWd/kgIHM (75% burnup). In this paper we discuss the repository implications for recycle of actinides in LWR's using this type of IMF and compare this to actinide recycle in a low conversion fast burner reactor. We perform the analysis over a finite horizon of 100 years, in which reprocessing of spent LWR fuel begins in 2020. Reference [1] C. Lombardi and A. Mazzola, Exploiting the plutonium stockpiles in PWRs by using inert matrix fuel, Annals of Nuclear Energy. 23 (1996) 1117-1126. [2] U. Kasemeyer, J.M. Paratte, P. Grimm and R. Chawla, Comparison of pressurized water reactor core characteristics for 100% plutonium-containing loadings, Nuclear Technology. 122 (1998) 52-63. [3] G. Ledergerber, C. Degueldre, P. Heimgartner, M.A. Pouchon and U. Kasemeyer, Inert matrix fuel for the utilisation of plutonium, Progress in Nuclear Energy. 38 (2001) 301-308. [4] U. Kasemeyer, C. Hellwig, J. Lebenhaft and R. Chawla, Comparison of various partial light water reactor core loadings with inert matrix and mixed oxide fuel, Journal of Nuclear Materials. 319 (2003) 142-153. [5] E.A. Schneider, M.R. Deinert and K.B. Cady, Burnup simulations of an inert matrix fuel using a two region, multi-group reactor physics model, in Proceedings of the physics of advanced fuel cycles, PHYSOR 2006, Vancouver, BC, 2006. [6] E.A. Schneider, M.R. Deinert and K.B. Cady, Burnup simulations and spent fuel characteristics of ZRO{sub 2} based inert matrix fuels, Journal of Nuclear Materials. 361 (2007) 41-51. (authors)

  4. Conceptual design of minor actinides burner with an accelerator-driven subcritical system.

    Energy Technology Data Exchange (ETDEWEB)

    Cao, Y.; Gohar, Y. (Nuclear Engineering Division)


    In the environmental impact study of the Yucca Mountain nuclear waste repository, the limit of spent nuclear fuel (SNF) for disposal is assessed at 70,000 metric tons of heavy metal (MTHM), among which 63,000 MTHM are the projected SNF discharge from U.S. commercial nuclear power plants though 2011. Within the 70,000 MTHM of SNF in storage, approximately 115 tons would be minor actinides (MAs) and 585 tons would be plutonium. This study describes the conceptual design of an accelerator-driven subcritical (ADS) system intended to utilize (burn) the 115 tons of MAs. The ADS system consists of a subcritical fission blanket where the MAs fuel will be burned, a spallation neutron source to drive the fission blanket, and a radiation shield to reduce the radiation dose to an acceptable level. The spallation neutrons are generated from the interaction of a 1 GeV proton beam with a lead-bismuth eutectic (LBE) or liquid lead target. In this concept, the fission blanket consists of a liquid mobile fuel and the fuel carrier can be LBE, liquid lead, or molten salt. The actinide fuel materials are dissolved, mixed, or suspended in the liquid fuel carrier. Therefore, fresh fuel can be fed into the fission blanket to adjust its reactivity and to control system power during operation. Monte Carlo analyses were performed to determine the overall parameters of an ADS system utilizing LBE as an example. Steady-state Monte Carlo simulations were studied for three fission blanket configurations that are similar except that the loaded amount of actinide fuel in the LBE is either 5, 7, or 10% of the total volume of the blanket, respectively. The neutron multiplication factor values of the three configurations are all approximately 0.98 and the MA initial inventories are each approximately 10 tons. Monte Carlo burnup simulations using the MCB5 code were performed to analyze the performance of the three conceptual ADS systems. Preliminary burnup analysis shows that all three conceptual ADS

  5. Applicability of RELAP5-3D for Thermal-Hydraulic Analyses of a Sodium-Cooled Actinide Burner Test Reactor

    Energy Technology Data Exchange (ETDEWEB)

    C. B. Davis


    The Actinide Burner Test Reactor (ABTR) is envisioned as a sodium-cooled, fast reactor that will burn the actinides generated in light water reactors to reduce nuclear waste and ease proliferation concerns. The RELAP5-3D computer code is being considered as the thermal-hydraulic system code to support the development of the ABTR. An evaluation was performed to determine the applicability of RELAP5-3D for the analysis of a sodium-cooled fast reactor. The applicability evaluation consisted of several steps, including identifying the important transients and phenomena expected in the ABTR, identifying the models and correlations that affect the code’s calculation of the important phenomena, and evaluating the applicability of the important models and correlations for calculating the important phenomena expected in the ABTR. The applicability evaluation identified code improvements and additional models needed to simulate the ABTR. The accuracy of the calculated thermodynamic and transport properties for sodium was also evaluated.

  6. The uncertainty analysis of a liquid metal reactor for burning minor actinides from light water reactors

    Energy Technology Data Exchange (ETDEWEB)

    Choi, Hang Bok [Korea Atomic Energy Research Institute, Taejon (Korea, Republic of)


    The neutronics analysis of a liquid metal reactor for burning minor actinides has shown that uncertainties in the nuclear data of several key minor actinide isotopes can introduce large uncertainties in the predicted performance of the core. A comprehensive sensitivity and uncertainty analysis was performed on a 1200 MWth actinide burner designed for a low burnup reactivity swing, negative doppler coefficient, and low sodium void worth. Sensitivities were generated using depletion perturbation methods for the equilibrium cycle of the reactor and covariance data was taken ENDF-B/V and other published sources. The relative uncertainties in the burnup swing, doppler coefficient, and void worth were conservatively estimated to be 180%, 97%, and 46%, respectively. 5 refs., 1 fig., 3 tabs. (Author)

  7. Burner (Stinger) (United States)

    ... feel overly tired. These are symptoms of a concussion . The doctor will ask you questions about what ... a Burner? Injuries to the brachial plexus can happen when a person's head is pushed forcefully down ...

  8. Multifuel burner

    Energy Technology Data Exchange (ETDEWEB)

    Raybould, J.D.


    A design is proposed for turbulent burner (B) for simultaneous burning of powder, liquid and/or gaseous fuel (F). The liquid F is sprayed with the help of a rotation sprayer arranged on the axis of the burner device. The gas can be supplied through the opening made in the dish-shaped bottom encompassing the central part of the B. The powder F (aeromixture) enters the combustion zone through the channels with vortex blades arranged on the periphery of the bottom of the B. Through the annular channel arranged around the rotation sprayer, primary air is supplied, and through the channels arranged on the periphery of the B, secondary air. The percentage of solid F during operation of the B can be 75-90%.

  9. Actinides-1981

    Energy Technology Data Exchange (ETDEWEB)


    Abstracts of 134 papers which were presented at the Actinides-1981 conference are presented. Approximately half of these papers deal with electronic structure of the actinides. Others deal with solid state chemistry, nuclear physic, thermodynamic properties, solution chemistry, and applied chemistry.

  10. Gas flat flame burner

    Energy Technology Data Exchange (ETDEWEB)

    Revun, M.P.; Chernov, V.Ye.; Perelman, L.D.; Rudnitskiy, O.I.; Yerinov, A.Ye.; Zyryanov, V.V.


    A burner is proposed in which it is possible to burn gas with low calorific value, Q/SUB n//SUP p/. The burner consists of a housing and screw-shaped insert installed on the central gassupply pipe. The latter ends at the outlet adapter equipped with nozzles of elliptical outlet section directed towards twisting of the air stream. The nozzles are bent at a right angle, and their axes are also arranged at the angle ..cap alpha.. in relation to the section plane of the adapter. ..cap alpha.. changes in limits of 0-45/sup 0/ depending on Q /SUB n/ /SUP p/ the lower the calorific value of the burned fuel, the higher the size of the angle ..cap alpha.. might be.

  11. Research in actinide chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Choppin, G.R.


    This research studies the behavior of the actinide elements in aqueous solution. The high radioactivity of the transuranium actinides limits the concentrations which can be studied and, consequently, limits the experimental techniques. However, oxidation state analogs (trivalent lanthanides, tetravalent thorium, and hexavalent uranium) do not suffer from these limitations. Behavior of actinides in the environment are a major USDOE concern, whether in connection with long-term releases from a repository, releases from stored defense wastes or accidental releases in reprocessing, etc. Principal goal of our research was expand the thermodynamic data base on complexation of actinides by natural ligands (e.g., OH[sup [minus

  12. Catalyzed Ceramic Burner Material

    Energy Technology Data Exchange (ETDEWEB)

    Barnes, Amy S., Dr.


    Catalyzed combustion offers the advantages of increased fuel efficiency, decreased emissions (both NOx and CO), and an expanded operating range. These performance improvements are related to the ability of the catalyst to stabilize a flame at or within the burner media and to combust fuel at much lower temperatures. This technology has a diverse set of applications in industrial and commercial heating, including boilers for the paper, food and chemical industries. However, wide spread adoption of catalyzed combustion has been limited by the high cost of precious metals needed for the catalyst materials. The primary objective of this project was the development of an innovative catalyzed burner media for commercial and small industrial boiler applications that drastically reduce the unit cost of the catalyzed media without sacrificing the benefits associated with catalyzed combustion. The scope of this program was to identify both the optimum substrate material as well as the best performing catalyst construction to meet or exceed industry standards for durability, cost, energy efficiency, and emissions. It was anticipated that commercial implementation of this technology would result in significant energy savings and reduced emissions. Based on demonstrated achievements, there is a potential to reduce NOx emissions by 40,000 TPY and natural gas consumption by 8.9 TBtu in industries that heavily utilize natural gas for process heating. These industries include food manufacturing, polymer processing, and pulp and paper manufacturing. Initial evaluation of commercial solutions and upcoming EPA regulations suggests that small to midsized boilers in industrial and commercial markets could possibly see the greatest benefit from this technology. While out of scope for the current program, an extension of this technology could also be applied to catalytic oxidation for volatile organic compounds (VOCs). Considerable progress has been made over the course of the grant

  13. Thermodynamic Properties of Actinides and Actinide Compounds (United States)

    Konings, Rudy J. M.; Morss, Lester R.; Fuger, Jean

    The necessity of obtaining accurate thermodynamic quantities for the actinide elements and their compounds was recognized at the outset of the Manhattan Project, when a dedicated team of scientists and engineers initiated the program to exploit nuclear energy for military purposes. Since the end of World War II, both fundamental and applied objectives have motivated a great deal of further study of actinide thermodynamics. This chapter brings together many research papers and critical reviews on this subject. It also seeks to assess, to systematize, and to predict important properties of the actinide elements, ions, and compounds, especially for species in which there is significant interest and for which there is an experimental basis for the prediction.

  14. Subsurface Biogeochemistry of Actinides

    Energy Technology Data Exchange (ETDEWEB)

    Kersting, Annie B. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States). Univ. Relations and Science Education; Zavarin, Mavrik [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States). Glenn T. Seaborg Inst.


    A major scientific challenge in environmental sciences is to identify the dominant processes controlling actinide transport in the environment. It is estimated that currently, over 2200 metric tons of plutonium (Pu) have been deposited in the subsurface worldwide, a number that increases yearly with additional spent nuclear fuel (Ewing et al., 2010). Plutonium has been shown to migrate on the scale of kilometers, giving way to a critical concern that the fundamental biogeochemical processes that control its behavior in the subsurface are not well understood (Kersting et al., 1999; Novikov et al., 2006; Santschi et al., 2002). Neptunium (Np) is less prevalent in the environment; however, it is predicted to be a significant long-term dose contributor in high-level nuclear waste. Our focus on Np chemistry in this Science Plan is intended to help formulate a better understanding of Pu redox transformations in the environment and clarify the differences between the two long-lived actinides. The research approach of our Science Plan combines (1) Fundamental Mechanistic Studies that identify and quantify biogeochemical processes that control actinide behavior in solution and on solids, (2) Field Integration Studies that investigate the transport characteristics of Pu and test our conceptual understanding of actinide transport, and (3) Actinide Research Capabilities that allow us to achieve the objectives of this Scientific Focus Area (SFA and provide new opportunities for advancing actinide environmental chemistry. These three Research Thrusts form the basis of our SFA Science Program (Figure 1).

  15. Ecothal burner development; Ecothal braennarutveckling

    Energy Technology Data Exchange (ETDEWEB)

    Lewin, Thomas [KANTHAL AB, Hallstahammar (Sweden)


    A SER burner system with catalytic cleaning have been optimised for an outer tube OD 100-115 mm. The aim has been to develop a burner with an emission of nitrogen oxides below 50 ppm and an efficiency higher than 80%. An optimised burner system have been realised but will not be stable enough for commercialisation. In order to fullfill the requirements it have to be regulated with closed loop oxygen sensor system regulating the air/gas supply (Lambda-value). Practically it is possible to reach 200-300 ppm nitrogen oxide with an efficiency around 70-80%. Following work have to focus on how to improve the stability considering geometrical changes when in operation but also towards accomodation of production tolerances and fluctuations in gas supply systems.

  16. Numerical simulation of porous burners and hole plate surface burners

    Directory of Open Access Journals (Sweden)

    Nemoda Stevan


    Full Text Available In comparison to the free flame burners the porous medium burners, especially those with flame stabilization within the porous material, are characterized by a reduction of the combustion zone temperatures and high combustion efficiency, so that emissions of pollutants are minimized. In the paper the finite-volume numerical tool for calculations of the non-isothermal laminar steady-state flow, with chemical reactions in laminar gas flow as well as within porous media is presented. For the porous regions the momentum and energy equations have appropriate corrections. In the momentum equations for the porous region an additional pressure drop has to be considered, which depends on the properties of the porous medium. For the heat transfer within the porous matrix description a heterogeneous model is considered. It treats the solid and gas phase separately, but the phases are coupled via a convective heat exchange term. For the modeling of the reaction of the methane laminar combustion the chemical reaction scheme with 164 reactions and 20 chemical species was used. The proposed numerical tool is applied for the analyses of the combustion and heat transfer processes which take place in porous and surface burners. The numerical experiments are accomplished for different powers of the porous and surface burners, as well as for different heat conductivity character is tics of the porous regions.

  17. Actinide oxide photodiode and nuclear battery

    Energy Technology Data Exchange (ETDEWEB)

    Sykora, Milan; Usov, Igor


    Photodiodes and nuclear batteries may utilize actinide oxides, such a uranium oxide. An actinide oxide photodiode may include a first actinide oxide layer and a second actinide oxide layer deposited on the first actinide oxide layer. The first actinide oxide layer may be n-doped or p-doped. The second actinide oxide layer may be p-doped when the first actinide oxide layer is n-doped, and the second actinide oxide layer may be n-doped when the first actinide oxide layer is p-doped. The first actinide oxide layer and the second actinide oxide layer may form a p/n junction therebetween. Photodiodes including actinide oxides are better light absorbers, can be used in thinner films, and are more thermally stable than silicon, germanium, and gallium arsenide.

  18. Pulverized fuel-oxygen burner (United States)

    Taylor, Curtis; Patterson, Brad; Perdue, Jayson


    A burner assembly combines oxygen and fuel to produce a flame. The burner assembly includes an oxygen supply tube adapted to receive a stream of oxygen and a solid fuel conduit arranged to extend through the oxygen tube to convey a stream of fluidized, pulverized, solid fuel into a flame chamber. Oxygen flowing through the oxygen supply tube passes generally tangentially through a first set of oxygen-injection holes formed in the solid fuel conduit and off-tangentially from a second set of oxygen-injection holes formed in the solid fuel conduit and then mixes with fluidized, pulverized, solid fuel passing through the solid fuel conduit to create an oxygen-fuel mixture in a downstream portion of the solid fuel conduit. This mixture is discharged into a flame chamber and ignited in the flame chamber to produce a flame.

  19. Optimization of burners in oxygen-gas fired glass furnace

    NARCIS (Netherlands)

    Kersbergen, M.J. van; Beerkens, R.G.C.; Sarmiento-Darkin, W.; Kobayashi, H.


    The energy efficiency performance, production stability and emissions of oxygen-fired glass furnaces are influenced by the type of burner, burner nozzle sizes, burner positions, burner settings, oxygen-gas ratios and the fuel distribution among all the burners. These parameters have been optimized

  20. Furnaces with multiple ?ameless combustion burners

    NARCIS (Netherlands)

    Danon, B.


    In this thesis three different combustion systems, equipped with either a single or multiple ?ameless combustion burner(s), are discussed. All these setups were investigated both experimentally and numerically, i.e., using Computational Fluid Dynamics (CFD) simulations. Flameless combustion is a

  1. Computational fluid dynamics in oil burner design

    Energy Technology Data Exchange (ETDEWEB)

    Butcher, T.A. [Brookhaven National Labs., Upton, NY (United States)


    In Computational Fluid Dynamics, the differential equations which describe flow, heat transfer, and mass transfer are approximately solved using a very laborious numerical procedure. Flows of practical interest to burner designs are always turbulent, adding to the complexity of requiring a turbulence model. This paper presents a model for burner design.

  2. Actinide speciation in environmental remediation

    Energy Technology Data Exchange (ETDEWEB)

    Plaue, Jon; Czerwinski, Ken R. [Massachusetts Institute of Technology, Nuclear Engineering Dept., Cambridge, MA (United States)


    Environmental actinide remediation is often performed in the absence of a clear understanding of the contaminant chemical forms. Remediation efforts are more concerned with the initial and final concentration of the contaminant actinides. Allowable final concentrations of actinides in remediation sites are mainly based on expected dose or prenegotiated levels. However, understanding the chemical forms of actinides in the environment is key to assessing their long-term behavior and developing enhanced analytical methods for their environmental detection. The dominant environmental chemical form will dictate the actinide transport behavior through solubility, colloid formation, or the interaction with natural ligands. This information can be used to evaluate the fate and potential transport of actinides. If the dominant environmental chemical species are understood, analytical methods for enhanced counting statistics and a reduction of counting error can be developed. A reduction in counting error will increase the fraction of verifiable waste below a given threshold, thereby increasing the rate of site clean up while reducing the cost. The impact of actinide speciation is presented in 2 sites contaminated with Am and Pu undergoing remediation. Actinide speciation has affected remediation strategies, regulatory response, and costs. (author)

  3. Burners (United States)

    ... and Sugar Substitutes Exercise and Fitness Exercise Basics Sports Safety Injury Rehabilitation Emotional Well-Being Mental Health Sex and ... and Sugar Substitutes Exercise and Fitness Exercise Basics Sports Safety Injury Rehabilitation Emotional Well-Being Mental Health Sex and ...

  4. Actinide AMS at DREAMS

    Energy Technology Data Exchange (ETDEWEB)

    Khojasteh, Nasrin B.; Merchel, Silke; Rugel, Georg; Scharf, Andreas; Ziegenruecker, Rene [HZDR, Dresden (Germany); Pavetich, Stefan [HZDR, Dresden (Germany); ANU, Canberra (Australia)


    Radionuclides such as {sup 236}U and {sup 239}Pu were introduced into the environment by atmospheric nuclear weapon tests, reactor accidents (Chernobyl, Fukushima), releases from nuclear reprocessing facilities (Sellafield, La Hague), radioactive waste disposal, and accidents with nuclear devices (Palomares, Thule) [1]. Accelerator Mass Spectrometry (AMS) is the most sensitive method to measure these actinides. The DREsden AMS (DREAMS) facility is located at a 6 MV accelerator, which is shared with ion beam analytics and implantation users, preventing major modifications of the accelerator and magnetic analyzers. DREAMS was originally designed for {sup 10}Be, {sup 26}Al, {sup 36}Cl, {sup 41}Ca, and {sup 129}I. To modify the system for actinide AMS, a Time-of-Flight (TOF) beamline at the high-energy side has been installed and performance tests are on-going. Ion beam and detector simulations are carried out to design a moveable ionization chamber. Especially, the detector window and anode dimensions have to be optimized. This ionization chamber will act as an energy detector of the system and its installation is planned as closely as possible to the stop detector of the TOF beamline for highest detection efficiency.


    Directory of Open Access Journals (Sweden)

    M.M. Noor


    Full Text Available This paper discusses the design and development of the Moderate and Intense Low oxygen Dilution (MILD combustion burner using Computational Fluid Dynamics (CFD simulations. The CFD commercial package was used to simulate preliminary designs for the burner before the final design was sent to the workshop for fabrication. The burner is required to be a non-premixed and open burner. To capture and use the exhaust gas, the burner was enclosed within a large circular shaped wall with an opening at the top. An external EGR pipe was used to transport the exhaust gas which was mixed with the fresh oxidant. To control the EGR and exhaust flow, butterfly valves were installed at the top opening as a damper to close the exhaust gas flow at a certain ratio for EGR and exhaust out to the atmosphere. High temperature fused silica glass windows were installed to view and capture images of the flame and analyze the flame propagation. The burner simulation shows that MILD combustion was achieved for the oxygen mole fraction of 3-13%. The final design of the burner was fabricated and ready for the experimental validation.

  6. Actinide transmutation in nuclear reactors

    Energy Technology Data Exchange (ETDEWEB)

    Ganev, I.K.; Lopatkin, A.V.; Naumov, V.V.; Tocheny, L.V.


    Of some interest is the comparison between the actinide nuclide burning up (fission) rates such as americium 241, americium 242, curium 244, and neptunium 237, in the reactors with fast or thermal neutron spectra.

  7. Burners and combustion apparatus for carbon nanomaterial production (United States)

    Alford, J. Michael; Diener, Michael D; Nabity, James; Karpuk, Michael


    The invention provides improved burners, combustion apparatus, and methods for carbon nanomaterial production. The burners of the invention provide sooting flames of fuel and oxidizing gases. The condensable products of combustion produced by the burners of this invention produce carbon nanomaterials including without limitation, soot, fullerenic soot, and fullerenes. The burners of the invention do not require premixing of the fuel and oxidizing gases and are suitable for use with low vapor pressure fuels such as those containing substantial amounts of polyaromatic hydrocarbons. The burners of the invention can operate with a hot (e.g., uncooled) burner surface and require little, if any, cooling or other forms of heat sinking. The burners of the invention comprise one or more refractory elements forming the outlet of the burner at which a flame can be established. The burners of the invention provide for improved flame stability, can be employed with a wider range of fuel/oxidizer (e.g., air) ratios and a wider range of gas velocities, and are generally more efficient than burners using water-cooled metal burner plates. The burners of the invention can also be operated to reduce the formation of undesirable soot deposits on the burner and on surfaces downstream of the burner.

  8. CHP Integrated with Burners for Packaged Boilers

    Energy Technology Data Exchange (ETDEWEB)

    Castaldini, Carlo; Darby, Eric


    The objective of this project was to engineer, design, fabricate, and field demonstrate a Boiler Burner Energy System Technology (BBEST) that integrates a low-cost, clean burning, gas-fired simple-cycle (unrecuperated) 100 kWe (net) microturbine (SCMT) with a new ultra low-NOx gas-fired burner (ULNB) into one compact Combined Heat and Power (CHP) product that can be retrofit on new and existing industrial and commercial boilers in place of conventional burners. The Scope of Work for this project was segmented into two principal phases: (Phase I) Hardware development, assembly and pre-test and (Phase II) Field installation and demonstration testing. Phase I was divided into five technical tasks (Task 2 to 6). These tasks covered the engineering, design, fabrication, testing and optimization of each key component of the CHP system principally, ULNB, SCMT, assembly BBEST CHP package, and integrated controls. Phase I work culminated with the laboratory testing of the completed BBEST assembly prior to shipment for field installation and demonstration. Phase II consisted of two remaining technical tasks (Task 7 and 8), which focused on the installation, startup, and field verification tests at a pre-selected industrial plant to document performance and attainment of all project objectives. Technical direction and administration was under the management of CMCE, Inc. Altex Technologies Corporation lead the design, assembly and testing of the system. Field demonstration was supported by Leva Energy, the commercialization firm founded by executives at CMCE and Altex. Leva Energy has applied for patent protection on the BBEST process under the trade name of Power Burner and holds the license for the burner currently used in the product. The commercial term Power Burner is used throughout this report to refer to the BBEST technology proposed for this project. The project was co-funded by the California Energy Commission and the Southern California Gas Company (SCG), a

  9. 33rd Actinide Separations Conference

    Energy Technology Data Exchange (ETDEWEB)

    McDonald, L M; Wilk, P A


    Welcome to the 33rd Actinide Separations Conference hosted this year by the Lawrence Livermore National Laboratory. This annual conference is centered on the idea of networking and communication with scientists from throughout the United States, Britain, France and Japan who have expertise in nuclear material processing. This conference forum provides an excellent opportunity for bringing together experts in the fields of chemistry, nuclear and chemical engineering, and actinide processing to present and discuss experiences, research results, testing and application of actinide separation processes. The exchange of information that will take place between you, and other subject matter experts from around the nation and across the international boundaries, is a critical tool to assist in solving both national and international problems associated with the processing of nuclear materials used for both defense and energy purposes, as well as for the safe disposition of excess nuclear material. Granlibakken is a dedicated conference facility and training campus that is set up to provide the venue that supports communication between scientists and engineers attending the 33rd Actinide Separations Conference. We believe that you will find that Granlibakken and the Lake Tahoe views provide an atmosphere that is stimulating for fruitful discussions between participants from both government and private industry. We thank the Lawrence Livermore National Laboratory and the United States Department of Energy for their support of this conference. We especially thank you, the participants and subject matter experts, for your involvement in the 33rd Actinide Separations Conference.

  10. Nuclear waste forms for actinides (United States)

    Ewing, Rodney C.


    The disposition of actinides, most recently 239Pu from dismantled nuclear weapons, requires effective containment of waste generated by the nuclear fuel cycle. Because actinides (e.g., 239Pu and 237Np) are long-lived, they have a major impact on risk assessments of geologic repositories. Thus, demonstrable, long-term chemical and mechanical durability are essential properties of waste forms for the immobilization of actinides. Mineralogic and geologic studies provide excellent candidate phases for immobilization and a unique database that cannot be duplicated by a purely materials science approach. The “mineralogic approach” is illustrated by a discussion of zircon as a phase for the immobilization of excess weapons plutonium. PMID:10097054

  11. Fuel-flexible burner apparatus and method for fired heaters

    Energy Technology Data Exchange (ETDEWEB)

    Zink, Darton J.; Isaacs, Rex K.; Jamaluddin, A. S. (Jamal); Benson, Charles E.; Pellizzari, Roberto O.; Little, Cody L.; Marty, Seth A.; Imel, K. Parker; Barnes, Jonathon E.; Parker, Chris S.


    A burner apparatus for a fired heating system and a method of burner operation. The burner provides stable operation when burning gas fuels having heating values ranging from low to high and accommodates sudden wide changes in the Wobbe value of the fuel delivered to the burner. The burner apparatus includes a plurality of exterior fuel ejectors and has an exterior notch which extends around the burner wall for receiving and combusting a portion of the gas fuel. At least a portion of the hot combustion product gas produced in the exterior notch is delivered through channels formed in the burner wall to the combustion area at the forward end of the burner. As the Wobbe value of the gas fuel decreases, one or more outer series of addition ejectors can be automatically activated as needed to maintain the amount of heat output desired.

  12. Actinides and Life's Origins (United States)

    Adam, Zachary


    There are growing indications that life began in a radioactive beach environment. A geologic framework for the origin or support of life in a Hadean heavy mineral placer beach has been developed, based on the unique chemical properties of the lower-electronic actinides, which act as nuclear fissile and fertile fuels, radiolytic energy sources, oligomer catalysts, and coordinating ions (along with mineralogically associated lanthanides) for prototypical prebiotic homonuclear and dinuclear metalloenzymes. A four-factor nuclear reactor model was constructed to estimate how much uranium would have been required to initiate a sustainable fission reaction within a placer beach sand 4.3 billion years ago. It was calculated that about 1-8 weight percent of the sand would have to have been uraninite, depending on the weight percent, uranium enrichment, and quantity of neutron poisons present within the remaining placer minerals. Radiolysis experiments were conducted with various solvents with the use of uranium- and thorium-rich minerals (metatorbernite and monazite, respectively) as proxies for radioactive beach sand in contact with different carbon, hydrogen, oxygen, and nitrogen reactants. Radiation bombardment ranged in duration of exposure from 3 weeks to 6 months. Low levels of acetonitrile (estimated to be on the order of parts per billion in concentration) were conclusively identified in 2 setups and tentatively indicated in a 3rd by gas chromatography/mass spectrometry. These low levels have been interpreted within the context of a Hadean placer beach prebiotic framework to demonstrate the promise of investigating natural nuclear reactors as power production sites that might have assisted the origins of life on young rocky planets with a sufficiently differentiated crust/mantle structure. Future investigations are recommended to better quantify the complex relationships between energy release, radioactive grain size, fissionability, reactant phase, phosphorus

  13. Industrial Energy Conservation, Forced Internal Recirculation Burner

    Energy Technology Data Exchange (ETDEWEB)

    Joseph Rabovitser


    The overall objective of this research project is to develop and evaluate an industrial low NOx burner for existing and new gas-fired combustion systems for intermediate temperature (1400 degree to 2000 degree F) industrial heating devices such as watertube boilers and process fluid heaters. A multi-phase effort is being pursued with decision points to determine advisability of continuance. The current contract over Phases II and III of this work. The objectives of each phase are as follows. Phase II - to design, fabricate, and evaluate prototype burners based on the Forced Internal Recirculation (FIR) concept. Phase III - to evaluate the performance of an FIR burner under actual operating conditions in a full-scale field test and establish the performance necessary for subsequent commercialization

  14. Preliminary considerations concerning actinide solubilities

    Energy Technology Data Exchange (ETDEWEB)

    Newton, T.W.; Bayhurst, B.P.; Daniels, W.R.; Erdal, B.R.; Ogard, A.E.


    Work at the Los Alamos Scientific Laboratory on the fundamental solution chemistry of the actinides has thus far been confined to preliminary considerations of the problems involved in developing an understanding of the precipitation and dissolution behavior of actinide compounds under environmental conditions. Attempts have been made to calculate solubility as a function of Eh and pH using the appropriate thermodynamic data; results have been presented in terms of contour maps showing lines of constant solubility as a function of Eh and pH. Possible methods of control of the redox potential of rock-groundwater systems by the use of Eh buffers (redox couples) is presented.

  15. 30 CFR 56.7803 - Lighting the burner. (United States)


    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Lighting the burner. 56.7803 Section 56.7803... Piercing Rotary Jet Piercing § 56.7803 Lighting the burner. A suitable means of protection shall be provided for the employee when lighting the burner. ...

  16. 30 CFR 57.7803 - Lighting the burner. (United States)


    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Lighting the burner. 57.7803 Section 57.7803... Jet Piercing Rotary Jet Piercing-Surface Only § 57.7803 Lighting the burner. A suitable means of protection shall be provided for the employee when lighting the burner. ...

  17. Assessment of Startup Fuel Options for the GNEP Advanced Burner Reactor (ABR)

    Energy Technology Data Exchange (ETDEWEB)

    Jon Carmack (062056); Kemal O. Pasamehmetoglu (103171); David Alberstein


    The Global Nuclear Energy Program (GNEP) includes a program element for the development and construction of an advanced sodium cooled fast reactor to demonstrate the burning (transmutation) of significant quantities of minor actinides obtained from a separations process and fabricated into a transuranic bearing fuel assembly. To demonstrate and qualify transuranic (TRU) fuel in a fast reactor, an Advanced Burner Reactor (ABR) prototype is needed. The ABR would necessarily be started up using conventional metal alloy or oxide (U or U, Pu) fuel. Startup fuel is needed for the ABR for the first 2 to 4 core loads of fuel in the ABR. Following start up, a series of advanced TRU bearing fuel assemblies will be irradiated in qualification lead test assemblies in the ABR. There are multiple options for this startup fuel. This report provides a description of the possible startup fuel options as well as possible fabrication alternatives available to the program in the current domestic and international facilities and infrastructure.

  18. Environmental research on actinide elements

    Energy Technology Data Exchange (ETDEWEB)

    Pinder, J.E. III; Alberts, J.J.; McLeod, K.W.; Schreckhise, R.G. (eds.)


    The papers synthesize the results of research sponsored by DOE's Office of Health and Environmental Research on the behavior of transuranic and actinide elements in the environment. Separate abstracts have been prepared for the 21 individual papers. (ACR)

  19. Bed burners for grate boilers; Baeddbraennare foer rosterpannor

    Energy Technology Data Exchange (ETDEWEB)

    Sendelius, Mikael; Schuster, Robert [AaF-Energikonsult AB, Stockholm (Sweden)


    The objective of this work is to increase the knowledge of bed burners and their optimal positions in furnaces. The results from several computational fluid mechanics calculations are presented. An investigation concerning bed burners among plant owners is included as well. A bed burner is defined as a burner used for enhancing the combustion process on the bed i.e. it is used to dry incoming wet fuel. A load burner is used to quickly increase the boiler load and primarily not for creating better combustion conditions on the grate. Fluid mechanics calculations have been performed for five different cases, including the reference case. The following four bed burner arrangements have been examined: flat flame burner, six burners placed in the combustion chamber, two symmetric placed burners and two asymmetric placed burners. The same furnace model has been used through all the simulations. The incident radiation has been calculated in order to determine which one of the bed burners having the best possibility to improve the combustion process on the grate. The results showed that the flat flame burner and the six burners placed in the combustion chamber gave the most incident radiation on the first two grate zones. Bed burners placed further back in the furnace gave less good results. A comparison between the reference case (the case without burners) and the case with two burners showed that there was almost no difference in incident radiation between the two cases. The case with six burners placed in the combustion chamber gave most incident radiation, however this arrangement gave an irregular distribution of the radiation on the bed. Too high or irregular distributed radiation increases the risk for getting regions, on the grate, where the fuel is completely burnt. Primary air will pass through these regions. This phenomenon will lead to high temperatures that cause increased levels of emissions, in particular NO{sub x}. Reorganizing the burner positions and

  20. Pressure Melting and Ice Skating / Bunsen Burner

    Indian Academy of Sciences (India)

    Home; Journals; Resonance – Journal of Science Education; Volume 1; Issue 5. Pressure Melting and Ice Skating / Bunsen Burner - Revisited. Classroom Volume 1 Issue 5 May 1996 pp 71-78. Fulltext. Click here to view fulltext PDF. Permanent link: Resonance ...

  1. On Bunsen Burners, Bacteria and the Bible

    Indian Academy of Sciences (India)

    Home; Journals; Resonance – Journal of Science Education; Volume 1; Issue 2. On Bunsen Burners, Bacteria and the Bible. Milind Watve. Classroom Volume 1 Issue 2 February 1996 pp 84-89. Fulltext. Click here to view fulltext PDF. Permanent link: ...

  2. Burner Characteristics for Activated Carbon Production

    Directory of Open Access Journals (Sweden)

    zakaria Supaat


    Full Text Available Carbonization process has become an important stage in developing activated carbon. However, existing burner are not efficient in time production which take 24 hours to15 days for charcoal production. Therefore, new design of burner/kilns is quite needed in order to produce larger number of charcoal in short time production, to improve charcoal quality regarding to the smooth surface area and pore volume. This research proposed new design burner which divided into two types which are vertical and horizontal types. Vertical is not completed by auto-rotating system while horizontal type is complete by auto-rotating and fume handling system. It developed using several equipment such as welding, oxy-cutting, drilling grinding and cutting machine. From the result of carbonization process shows that coconut shell charcoal need shorter time of 30 minutes as compared to palm shell charcoal of 2 h to completely carbonized. This result claim that the new design better than existing kiln that need longer time up to 24 h. The result of the palm and coconut shell charcoal believe will produce better properties of activated carbon in large surface area and higher total volume of pores. Therefore, this burner is high recommended for producing palm and coconut shell charcoal as well as other bio-based material.

  3. Market assessment for the fan atomized oil burner

    Energy Technology Data Exchange (ETDEWEB)

    Westphalen, D. [A.D. Little, Inc., Cambridge, MA (United States)


    The market potential for the fan atomized burner (FAB) in water and space heating applications was examined. The major findings of the study are as follows. (1). The FAB`s low-input capability allows development of oil-fired room heaters and wall furnaces, a new market area for oil heat. (2). Among conventional oil-fired products, furnaces will benefit most from the burner`s low input capability due to (1) their quick delivery of heat and (2) their more prevalent use in warmer climates and smaller homes. (3). The greatest potential for increased product sales or oil sales exists in the use of the burner with new products (i.e., room heaters). Sales of boilers and direct-fired water heaters are not likely to increase with the use of the burner. (4). Acceptance of the burner will be dependent on proof of reliability. Proof of better reliability than conventional burners would accelerate acceptance.

  4. Actinide cation-cation complexes

    Energy Technology Data Exchange (ETDEWEB)

    Stoyer, Nancy Jane [Univ. of California, Berkeley, CA (United States)


    The +5 oxidation state of U, Np, Pu, and Am is a linear dioxo cation (AnO2+) with a formal charge of +1. These cations form complexes with a variety of other cations, including actinide cations. Other oxidation states of actinides do not form these cation-cation complexes with any cation other than AnO2+; therefore, cation-cation complexes indicate something unique about AnO2+ cations compared to actinide cations in general. The first cation-cation complex, NpO2+•UO22+, was reported by Sullivan, Hindman, and Zielen in 1961. Of the four actinides that form AnO2+ species, the cation-cation complexes of NpO2+ have been studied most extensively while the other actinides have not. The only PuO2+ cation-cation complexes that have been studied are with Fe3+ and Cr3+ and neither one has had its equilibrium constant measured. Actinides have small molar absorptivities and cation-cation complexes have small equilibrium constants; therefore, to overcome these obstacles a sensitive technique is required. Spectroscopic techniques are used most often to study cation-cation complexes. Laser-Induced Photacoustic Spectroscopy equilibrium constants for the complexes NpO2+•UO22+, NpO2+•Th4+, PuO2+•UO22+, and PuO2+•Th4+ at an ionic strength of 6 M using LIPAS are 2.4 ± 0.2, 1.8 ± 0.9, 2.2 ± 1.5, and ~0.8 M-1.

  5. Catalytic burners in larger boiler appliances

    Energy Technology Data Exchange (ETDEWEB)

    Silversand, Fredrik; Persson, Mikael (Catator AB, Lund (Sweden))


    This project focuses on the scale up of a Catator's catalytic burner technology to enable retrofit installation in existing boilers and the design of new innovative combinations of catalytic burners and boilers. Different design approaches are discussed and evaluated in the report and suggestions are made concerning scale-up. Preliminary test data, extracted from a large boiler installation are discussed together with an accurate analysis of technical possibilities following an optimization of the boiler design to benefit from the advantages of catalytic combustion. The experimental work was conducted in close collaboration with ICI Caldaie (ICI), located in Verona, Italy. ICI is a leading European boiler manufacturer in the effect segment ranging from about 20 kWt to several MWt. The study shows that it is possibly to scale up the burner technology and to maintain low emissions. The boilers used in the study were designed around conventional combustion and were consequently not optimized for implementation of catalytic burners. From previous experiences it stands clear that the furnace volume can be dramatically decreased when applying catalytic combustion. In flame combustion, this volume is normally dimensioned to avoid flame impingement on cold surfaces and to facilitate completion of the gas-phase reactions. The emissions of nitrogen oxides can be reduced by decreasing the residence time in the furnace. Even with the over-dimensioned furnace used in this study, we easily reached emission values close to 35 mg/kWh. The emissions of carbon monoxide and unburned hydrocarbons were negligible (less than 5 ppmv). It is possible to decrease the emissions of nitrogen oxides further by designing the furnace/boiler around the catalytic burner, as suggested in the report. Simultaneously, the size of the boiler installation can be reduced greatly, which also will result in material savings, i.e. the production cost can be reduced. It is suggested to optimize the

  6. Actinide Waste Forms and Radiation Effects (United States)

    Ewing, R. C.; Weber, W. J.

    Over the past few decades, many studies of actinides in glasses and ceramics have been conducted that have contributed substantially to the increased understanding of actinide incorporation in solids and radiation effects due to actinide decay. These studies have included fundamental research on actinides in solids and applied research and development related to the immobilization of the high level wastes (HLW) from commercial nuclear power plants and processing of nuclear weapons materials, environmental restoration in the nuclear weapons complex, and the immobilization of weapons-grade plutonium as a result of disarmament activities. Thus, the immobilization of actinides has become a pressing issue for the twenty-first century (Ewing, 1999), and plutonium immobilization, in particular, has received considerable attention in the USA (Muller et al., 2002; Muller and Weber, 2001). The investigation of actinides and

  7. Fuel burner and combustor assembly for a gas turbine engine (United States)

    Leto, Anthony


    A fuel burner and combustor assembly for a gas turbine engine has a housing within the casing of the gas turbine engine which housing defines a combustion chamber and at least one fuel burner secured to one end of the housing and extending into the combustion chamber. The other end of the fuel burner is arranged to slidably engage a fuel inlet connector extending radially inwardly from the engine casing so that fuel is supplied, from a source thereof, to the fuel burner. The fuel inlet connector and fuel burner coact to anchor the housing against axial movement relative to the engine casing while allowing relative radial movement between the engine casing and the fuel burner and, at the same time, providing fuel flow to the fuel burner. For dual fuel capability, a fuel injector is provided in said fuel burner with a flexible fuel supply pipe so that the fuel injector and fuel burner form a unitary structure which moves with the fuel burner.

  8. Bias estimates used in lieu of validation of fission products and minor actinides in MCNP Keff calculations for PWR burnup credit casks

    Energy Technology Data Exchange (ETDEWEB)

    Mueller, Don [ORNL; Marshall, William BJ J [ORNL; Wagner, John C [ORNL; Bowen, Douglas G [ORNL


    The U.S. Nuclear Regulatory Commission (NRC) Division of Spent Fuel Storage and Transportation recently issued Interim Staff Guidance (ISG) 8, Revision 3. This ISG provides guidance for burnup credit (BUC) analyses supporting transport and storage of PWR pressurized water reactor (PWR) fuel in casks. Revision 3 includes guidance for addressing validation of criticality (keff) calculations crediting the presence of a limited set of fission products and minor actinides (FP&MA). Based on previous work documented in NUREG/CR-7109, recommendation 4 of ISG-8, Rev. 3, includes a recommendation to use 1.5 or 3% of the FP&MA worth to conservatively cover the bias due to the specified FP&MAs. This bias is supplementary to the bias and bias uncertainty resulting from validation of keff calculations for the major actinides in SNF and does not address extension to actinides and fission products beyond those identified herein. The work described in this report involves comparison of FP&MA worths calculated using SCALE and MCNP with ENDF/B-V, -VI, and -VII based nuclear data and supports use of the 1.5% FP&MA worth bias when either SCALE or MCNP codes are used for criticality calculations, provided the other conditions of the recommendation 4 are met. The method used in this report may also be applied to demonstrate the applicability of the 1.5% FP&MA worth bias to other codes using ENDF/B V, VI or VII based nuclear data. The method involves use of the applicant s computational method to generate FP&MA worths for a reference SNF cask model using specified spent fuel compositions. The applicant s FP&MA worths are then compared to reference values provided in this report. The applicants FP&MA worths should not exceed the reference results by more than 1.5% of the reference FP&MA worths.

  9. Refinery burner simulation design architecture summary.

    Energy Technology Data Exchange (ETDEWEB)

    Pollock, Guylaine M.; McDonald, Michael James; Halbgewachs, Ronald D.


    This report describes the architectural design for a high fidelity simulation of a refinery and refinery burner, including demonstrations of impacts to the refinery if errors occur during the refinery process. The refinery burner model and simulation are a part of the capabilities within the Sandia National Laboratories Virtual Control System Environment (VCSE). Three components comprise the simulation: HMIs developed with commercial SCADA software, a PLC controller, and visualization software. All of these components run on different machines. This design, documented after the simulation development, incorporates aspects not traditionally seen in an architectural design, but that were utilized in this particular demonstration development. Key to the success of this model development and presented in this report are the concepts of the multiple aspects of model design and development that must be considered to capture the necessary model representation fidelity of the physical systems.


    Energy Technology Data Exchange (ETDEWEB)

    Robert States


    Non steady impingement heat transfer is measured. Impingement heating consumes 130 T-BTU/Yr in paper drying, but is only 25% thermally efficient. Pulse impingement is experimentally shown to enhance heat transfer by 2.8, and may deliver thermal efficiencies near 85%. Experimental results uncovered heat transfer deviations from steady theory and from previous investigators, indicating the need for further study and a better theoretical framework. The pulse burner is described, and its roll in pulse impingement is analyzed.

  11. Coal-water mixture fuel burner (United States)

    Brown, T.D.; Reehl, D.P.; Walbert, G.F.


    The present invention represents an improvement over the prior art by providing a rotating cup burner arrangement for use with a coal-water mixture fuel which applies a thin, uniform sheet of fuel onto the inner surface of the rotating cup, inhibits the collection of unburned fuel on the inner surface of the cup, reduces the slurry to a collection of fine particles upon discharge from the rotating cup, and further atomizes the fuel as it enters the combustion chamber by subjecting it to the high shear force of a high velocity air flow. Accordingly, it is an object of the present invention to provide for improved combustion of a coal-water mixture fuel. It is another object of the present invention to provide an arrangement for introducing a coal-water mixture fuel into a combustion chamber in a manner which provides improved flame control and stability, more efficient combustion of the hydrocarbon fuel, and continuous, reliable burner operation. Yet another object of the present invention is to provide for the continuous, sustained combustion of a coal-water mixture fuel without the need for a secondary combustion source such as natural gas or a liquid hydrocarbon fuel. Still another object of the present invention is to provide a burner arrangement capable of accommodating a coal-water mixture fuel having a wide range of rheological and combustion characteristics in providing for its efficient combustion. 7 figs.

  12. Perbandingan Unjuk Kerja Kompor Methanol dengan Variasi Diameter Burner

    Directory of Open Access Journals (Sweden)

    Subroto Subroto


    Full Text Available Sampai saat ini sebagian masyarakat masih anyak menggunakan minyak tanah sebagai bahan bakar untuk keperluan rumah tangga maupun industri, walaupun harga minyak tanah naik cukup tinggi karena subsidi dari pemerintah dicabut. Untuk mengurangi ketergantungan minyak tanah perlu penggunaan bahan bakar alternatif yaitu methanol. Methanol mempunyai kelebihan mudah didapatkan di lapangan dan dengan harga yang lebih murah dari minyak tanah. Kompor methanol sudah dikenal masyarakat akan tetapi penggunaannya masih sangat terbatas karena unjuk kerjanya masih kurang baik dibandingkan kompor minyak tanah. Penelitian ini bertujuan untuk mengetahui unjuk kerja kompor methanol melalui pengaruh variasi diameter burner.               Penelitian dimulai dengan rancang bangun burner terbuat dari bahan kuningan dengan tiga macam model dengan variasi diameter burner dan tinggi burner maupun jumlah lubang tetap. Pengujian unjuk kerja berdasarkan karakteristik pembakaran dilakukan melalui water boiling test. Parameter yang diukur meliputi temperatur api pembakaran, temperatur air, konsumsi bahan bakar, dan waktu pendidihan.               Hasil penelitian menunjukkan bahwa variasi diameter burner berpengaruh terhadap karakteristik pembakaran yang dihasilkan. Temperatur pembakaran yang tinggi dicapai oleh burner dengan diameter 12,8mm dan 10mm, konsumsi bahan bakar yang kecil burner diameter 12,8mm dan waktu pendidihan yang pendek dicapai burner 12,8mm. Jadi kompor methanol dengan unjuk kerja terbaik adalah kompor methanol dengan diameter burner 12,8mm.

  13. Prompt fission neutron spectrum of actinides

    Energy Technology Data Exchange (ETDEWEB)

    Capote, R. [International Atomic Energy Agency, Vienna (Austria); Chen, Y. -J. [China Institute of Atomic Energy, Beijing (China); Hambsch, F. J. [European Commission, Joint Research Centre - IRRM, Geel (Belgium); Jurado, B. [CENBG, CNRS/IN2P3, Gradignan (France); Kornilov, N. [Ohio Univ., Athens, OH (United States); Lestone, J. P. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Litaize, O. [CEA, DEN, DER, SPRC, Saint-Paul-Lez-Durance (France); Morillon, B. [CEA, DAM, DIF, Arpajon (France); Neudecker, D. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Oberstedt, S. [European Commission, Joint Research Centre - IRRM, Geel (Belgium); Ohsawa, T. [Kinki Univ., Osaka-fu (Japan); Otuka, N. [International Atomic Energy Agency, Vienna (Austria); Pronyaev, V. G. [Institute of Physics and Power Engineering, Obninsk (Russian Federation); Saxena, A. [Bhabha Atomic Research Centre, Mumbai (India); Schmidt, K. H. [CENBG, CNRS/IN2P3, Gradignan (France); Serot, O. [CEA, DEN, DER, SPRC, Saint-Paul-Lez-Durance (France); Shcherbakov, O. A. [Petersburg Nuclear Physics Institute of NRC " Kurchatov Institute" , Gatchina (Russian Federation); Shu, N. -C. [China Institute of Atomic Energy, Beijing (China); Smith, D. L. [Argonne National Lab. (ANL), Argonne, IL (United States); Talou, P. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Trkov, A. [International Atomic Energy Agency, Vienna (Austria); Tudora, A. C. [Univ. of Bucharest, Magurele (Romania); Vogt, R. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Univ. of California, Davis, CA (United States); Vorobyev, A. S. [Petersburg Nuclear Physics Institute of NRC " Kurchatov Institute" , Gatchina (Russian Federation)


    Here, the energy spectrum of prompt neutron emitted in fission (PFNS) plays a very important role in nuclear science and technology. A Coordinated Research Project (CRP) "Evaluation of Prompt Fission Neutron Spectra of Actinides" was established by the IAEA Nuclear Data Section in 2009, with the major goal to produce new PFNS evaluations with uncertainties for actinide nuclei.

  14. Calculated Atomic Volumes of the Actinide Metals

    DEFF Research Database (Denmark)

    Skriver, H.; Andersen, O. K.; Johansson, B.


    The equilibrium atomic volume is calculated for the actinide metals. It is possible to account for the localization of the 5f electrons taking place in americium.......The equilibrium atomic volume is calculated for the actinide metals. It is possible to account for the localization of the 5f electrons taking place in americium....

  15. Catalytic Organic Transformations Mediated by Actinide Complexes

    Directory of Open Access Journals (Sweden)

    Isabell S. R. Karmel


    Full Text Available This review article presents the development of organoactinides and actinide coordination complexes as catalysts for homogeneous organic transformations. This chapter introduces the basic principles of actinide catalysis and deals with the historic development of actinide complexes in catalytic processes. The application of organoactinides in homogeneous catalysis is exemplified in the hydroelementation reactions, such as the hydroamination, hydrosilylation, hydroalkoxylation and hydrothiolation of alkynes. Additionally, the use of actinide coordination complexes for the catalytic polymerization of α-olefins and the ring opening polymerization of cyclic esters is presented. The last part of this review article highlights novel catalytic transformations mediated by actinide compounds and gives an outlook to the further potential of this field.

  16. Burners for Supersonic Ramjets - Some Observations on Instability in a Two-Inch Ramjet Burner (United States)


    a burner comprising a simple 0.75" oxyhydrogen pilot cone (Igniter 1-2, Figure 3) is much more prone to insta- bility than one comprising the same...occurred largely with a "poor igniter." Most of the work described above was done with a simple 0.75 inch oxyhydrogen cone. 2. It was accompanied

  17. Some parameters and conditions defining the efficiency of burners ...

    Indian Academy of Sciences (India)

    A number of new wordings and statements regarding the targeted problem of destruction of long-lived wastes (transmutation) is considered. Some new criteria concerning the efficiency of a particular burner type are proposed. It is shown that the destruction efficiency of a specific burner is greatly influenced by the ...


    Sonotech, Inc. (Sonotech), of Atlanta, GA, the developer of the Cello® pulse combustion burner, claims that its burner system can be beneficial to a variety of combustion processes. The system incorporates a combustor that can be tuned to induce large amplitude sonic pulsation...

  19. Combustion starter and maintenance burner for pulverized solid fossil fuels, and combustion chamber equipped with burners of the kind

    Energy Technology Data Exchange (ETDEWEB)

    Vidal, J.; Malaubier, F.; Mevel, J-C.


    A power station boiler is described, which is fired by pulverized coal. The boiler has an axial conduit for feeding the pulverized fuel in a primary combustion supporting gas. The burner incorporates a flame detector and an igniter in the refractory tap-hole or in the axial conduit. The advantage of the burner is improved efficiency and reduced operating cost.

  20. Experimental studies of actinides in molten salts

    Energy Technology Data Exchange (ETDEWEB)

    Reavis, J.G.


    This review stresses techniques used in studies of molten salts containing multigram amounts of actinides exhibiting intense alpha activity but little or no penetrating gamma radiation. The preponderance of studies have used halides because oxygen-containing actinide compounds (other than oxides) are generally unstable at high temperatures. Topics discussed here include special enclosures, materials problems, preparation and purification of actinide elements and compounds, and measurements of various properties of the molten volts. Property measurements discussed are phase relationships, vapor pressure, density, viscosity, absorption spectra, electromotive force, and conductance. 188 refs., 17 figs., 6 tabs.

  1. Recent developments in the central worth discrepancy

    Energy Technology Data Exchange (ETDEWEB)

    Smith, K S; Schaefer, R W


    Results of recent fissile small-sample worth experiments in three fast reactor diagnostic critical assemblies are presented. These experiments produced significant insight into heterogeneity-related errors in standard calculational models of worth experiments in plate-type critical assemblies. Results of improved techniques for calculation of worth experiments are presented, and the mean ratios of calculated to experimental (C/E) worths in the three new benchmark critical assemblies are shown to be in the range of 0.97 to 1.04. The implications of the improved understanding of small-sample worth experiments with respect to previously-reported critical experiments are discussed.

  2. Subsurface interactions of actinide species and microorganisms : implications for the bioremediation of actinide-organic mixtures.

    Energy Technology Data Exchange (ETDEWEB)

    Banaszak, J.E.; Reed, D.T.; Rittmann, B.E.


    By reviewing how microorganisms interact with actinides in subsurface environments, we assess how bioremediation controls the fate of actinides. Actinides often are co-contaminants with strong organic chelators, chlorinated solvents, and fuel hydrocarbons. Bioremediation can immobilize the actinides, biodegrade the co-contaminants, or both. Actinides at the IV oxidation state are the least soluble, and microorganisms accelerate precipitation by altering the actinide's oxidation state or its speciation. We describe how microorganisms directly oxidize or reduce actinides and how microbiological reactions that biodegrade strong organic chelators, alter the pH, and consume or produce precipitating anions strongly affect actinide speciation and, therefore, mobility. We explain why inhibition caused by chemical or radiolytic toxicities uniquely affects microbial reactions. Due to the complex interactions of the microbiological and chemical phenomena, mathematical modeling is an essential tool for research on and application of bioremediation involving co-contamination with actinides. We describe the development of mathematical models that link microbiological and geochemical reactions. Throughout, we identify the key research needs.

  3. Advanced Aqueous Separation Systems for Actinide Partitioning

    Energy Technology Data Exchange (ETDEWEB)

    Nash, Kenneth L.; Clark, Sue; Meier, G Patrick; Alexandratos, Spiro; Paine, Robert; Hancock, Robert; Ensor, Dale


    One of the most challenging aspects of advanced processing of spent nuclear fuel is the need to isolate transuranium elements from fission product lanthanides. This project expanded the scope of earlier investigations of americium (Am) partitioning from the lanthanides with the synthesis of new separations materials and a centralized focus on radiochemical characterization of the separation systems that could be developed based on these new materials. The primary objective of this program was to explore alternative materials for actinide separations and to link the design of new reagents for actinide separations to characterizations based on actinide chemistry. In the predominant trivalent oxidation state, the chemistry of lanthanides overlaps substantially with that of the trivalent actinides and their mutual separation is quite challenging.

  4. BWR Assembly Optimization for Minor Actinide Recycling

    Energy Technology Data Exchange (ETDEWEB)

    G. Ivan Maldonado; John M. Christenson; J.P. Renier; T.F. Marcille; J. Casal


    The Primary objective of the proposed project is to apply and extend the latest advancements in LWR fuel management optimization to the design of advanced boiling water reactor (BWR) fuel assemblies specifically for the recycling of minor actinides (MAs).

  5. Spin and orbital moments in actinide compounds

    DEFF Research Database (Denmark)

    Lebech, B.; Wulff, M.; Lander, G.H.


    The extended spatial distribution of both the transition-metal 3d electrons and the actinide 5f electrons results in a strong interaction between these electron states when the relevant elements are alloyed. A particular interesting feature of this hybridization, which is predicted by single-electron...... band-structure calculations, is that the orbital moments of the actinide 5f electrons are considerably reduced from the values anticipated by a simple application of Hund's rules. To test these ideas, and thus to obtain a measure of the hybridization, we have performed a series of neutron scattering...... experiments designed to determine the magnetic moments at the actinide and transition-metal sublattice sites in compounds such as UFe2, NpCo2, and PuFe2 and to separate the spin and orbital components at the actinide sites. The results show, indeed, that the ratio of the orbital to spin moment is reduced...

  6. Fan Atomized Burner design advances & commercial development progress

    Energy Technology Data Exchange (ETDEWEB)

    Kamath, B. [Heat-Wise, Inc., Ridge, NY (United States); Butcher, T.A. [Brookhaven National Lab., Upton, NY (United States)


    As a part of the Oil Heat Research and Development program, sponsored by the US Department of Energy, Brookhaven National Laboratory (BNL) has an on-going interest in advanced combustion technologies. This interest is aimed at: improving the initial efficiency of heating equipment, reducing long term fouling and efficiency degradation, reducing air pollutant emissions, and providing practical low-firing rate technologies which may lead to new, high efficiency oil-fired appliances. The Fan-Atomized Burner (FAB) technology is being developed at BNL as part of this general goal. The Fan-Atomized Burner uses a low pressure, air atomizing nozzle in place of the high pressure nozzle used in conventional burners. Because it is air-atomized the burner can operate at low firing rates without the small passages and reliability concerns of low input pressure nozzles. Because it uses a low pressure nozzle the burner can use a fan in place of the small compressor used in other air-atomized burner designs. High initial efficiency of heating equipment is achieved because the burner can operate at very low excess air levels. These low excess air levels also reduce the formation of sulfuric acid in flames. Sulfuric acid is responsible for scaling and fouling of heat exchanger surfaces.


    Moore, R.H.


    BS>A process is given for preparing alloys of aluminum with plutonium, uranium, and/or thorium by chlorinating actinide oxide dissolved in molten alkali metal chloride with hydrochloric acid, chlorine, and/or phosgene, adding aluminum metal, and passing air and/or water vapor through the mass. Actinide metal is formed and alloyed with the aluminum. After cooling to solidification, the alloy is separated from the salt. (AEC)

  8. Predictive Modeling in Actinide Chemistry and Catalysis

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Ping [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)


    These are slides from a presentation on predictive modeling in actinide chemistry and catalysis. The following topics are covered in these slides: Structures, bonding, and reactivity (bonding can be quantified by optical probes and theory, and electronic structures and reaction mechanisms of actinide complexes); Magnetic resonance properties (transition metal catalysts with multi-nuclear centers, and NMR/EPR parameters); Moving to more complex systems (surface chemistry of nanomaterials, and interactions of ligands with nanoparticles); Path forward and conclusions.

  9. Flashback Avoidance in Swirling Flow Burners

    Directory of Open Access Journals (Sweden)

    Vigueras-Zúñiga Marco Osvaldo


    Full Text Available Lean premixed combustion using swirling flows is widely used in gas turbines and combustion. Although flashback is not generally a problem with natural gas combustion, there are some reports of flashback damage with existing gas turbines, whilst hydrogen enriched fuel blends cause concerns in this area. Thus, this paper describes a practical approach to study and avoid flashback in a pilot scale 100 kW tangential swirl burner. The flashback phenomenon is studied experimentally via the derivation of flashback limits for a variety of different geometrical conditions. A high speed camera is used to visualize the process and distinguish new patterns of avoidance. The use of a central fuel injector is shown to give substantial benefits in terms of flashback resistance. Conclusions are drawn as to mitigation technologies.

  10. Firing in fluid beds and burners

    Energy Technology Data Exchange (ETDEWEB)

    Frandsen, F.; Lans, R. van der; Storm Pedersen, L.; Philbert Nielsen, H.; Aslaug Hansen, L.; Lin, W.; Johnsson, J.E.; Dam-Johansen, K.


    An investigation of the effect of co-firing straw and pulverized coal was performed. Based on experiments from pilot-scale and full-scale it was concluded that a higher fraction of straw in the fuel feedstock mixture results in lower NO and SO{sub 2} emissions. The lower NO emission was mainly due to the higher volatile content of the straw, which leads to lower stoichiometry in the gas phase and in subsequent suppression of NO{sub x} formation. This conclusion is consistent with experimental and modeling results for pure coal combustion. The effect of coal quality on NO emissions has been investigated with three coals of different characteristics in three furnaces: in the Funen power station, unit 7 (FVO7), the Midtkraft Studstrup power station, unit 4 (MKS4), and the Mitsui Babcock Energy Ltd (MBEL) test-rig. The MBEL test-rig was able to reproduce qualitatively the emissions from the MKS4 plant, and quantitatively the emissions from the FVO7 plant. The better agreement between the MBEL test-rig and FVO7 is presumed to be related to the existence of a large primary zone with a relatively low stoichiometry, diminishing the influence of near burner air and fuel mixing rate on the NO emissions. An engineering model has been developed for the prediction of NO emissions and burnout from pulverized fuel combustion in swirl burners. A simplified model for reduction of N{sub 2}O in CFBC has been developed, and simulation results are in good agreement with experimental data from a 12 MW{sub th} CFB-boiler. (EG) EFP-94. 108 refs.

  11. Investigation of the Combustion Stability of Methane-Air Mixture in Recuperative Burners of Different Geometries

    Directory of Open Access Journals (Sweden)

    Krainov Alexey


    Full Text Available The results of numerical investigations of 5.5% methane-air combustion stability in heat recuperative burners (counter flow burner, U-shape burner and Swiss-roll burner are presented in this paper. The investigation is carried out with the use of commercial CFD package Ansys-Fluent. The boundaries of combustion stability of 5.5% methane-air mixture depending on the gas flow rate at the inlet of the burners are determined.

  12. Recovery of Actinides from Actinide-Aluminium Alloys: Chlorination Route

    Energy Technology Data Exchange (ETDEWEB)

    Mendes, E.; Malmbeck, R.; Soucek, P.; Jardin, R.; Glatz, J.P. [European Commission, JRC, Institute for Transuranium Elements, Postfach 2340, 76125 Karlsruhe (Germany); Cassayre, L. [Laboratoire de Genie Chimique (LGC), Universite Paul Sabatier, UMR CNRS 5503, 118 route de Narbonne, 31062 Toulouse Cedex 04 (France)


    A method for recovery of actinides (An) from An-Al alloys formed by electrochemical separation of metallic spent nuclear fuel on solid aluminium electrodes in molten chloride salts is described. The proposed route consists of three main steps: -) vacuum distillation of salt adhered on the electrodes, -) chlorination of An-Al alloy by pure chlorine gas and -) sublimation of formed AlCl{sub 3}. A thermochemical study of the route was performed to determine important chemical reactions and to find optimum experimental conditions for all process steps. Vacuum distillation of the electrode is efficient for complete removal of remaining salt and most fission products, full chlorination of the An-Al alloys is possible at any working temperature and evaporation of AlCl{sub 3} is achieved by heating under argon. Experiments have been carried out using U-Al alloy in order to define parameters providing full alloy chlorination without formation of volatile UCl{sub 5} and UCl{sub 6}. It was shown that full chlorination of An-Al alloys without An losses should be possible at a temperature approx. 150 deg. C. (authors)

  13. Assessment of PWR plutonium burners for nuclear energy centers

    Energy Technology Data Exchange (ETDEWEB)

    Frankel, A J; Shapiro, N L


    The purpose of the study was to explore the performance and safety characteristics of PWR plutonium burners, to identify modifications to current PWR designs to enhance plutonium utilization, to study the problems of deploying plutonium burners at Nuclear Energy Centers, and to assess current industrial capability of the design and licensing of such reactors. A plutonium burner is defined to be a reactor which utilizes plutonium as the sole fissile addition to the natural or depleted uranium which comprises the greater part of the fuel mass. The results of the study and the design analyses performed during the development of C-E's System 80 plant indicate that the use of suitably designed plutonium burners at Nuclear Energy Centers is technically feasible.

  14. Actinide transmutation in nuclear reactors

    Energy Technology Data Exchange (ETDEWEB)

    Bultman, J.H.


    An optimization method is developed to maximize the burning capability of the ALMR while complying with all constraints imposed on the design for reliability and safety. This method leads to a maximal transuranics enrichment, which is being limited by constraints on reactivity. The enrichment can be raised by using the neutrons less efficiently by increasing leakage from the fuel. With the developed optimization method, a metallic and an oxide fueled ALMR were optimized. Both reactors perform equally well considering the burning of transuranics. However, metallic fuel has a much higher heat conductivity coefficient, which in general leads to better safety characteristics. In search of a more effective waste transmuter, a modified Molten Salt Reactor was designed. A MSR operates on a liquid fuel salt which makes continuous refueling possible, eliminating the issue of the burnup reactivity loss. Also, a prompt negative reactivity feedback is possible for an overmoderated reactor design, even when the Doppler coefficient is positive, due to the fuel expansion with fuel temperature increase. Furthermore, the molten salt fuel can be reprocessed based on a reduction process which is not sensitive to the short-lived spontaneously fissioning actinides. (orig./HP).

  15. Simulation tools for the design of natural gas domestic burners

    Energy Technology Data Exchange (ETDEWEB)

    Hilka, M. [DEG Gaz de France, Saint Denise la Plaine (France). Direction de la Recherche; Quilichini, V.; Gicquel, O.; Darabiha, N. [Laboratoire E.M2.C., Ecole Centrale Paris, CNRS, Chatenay-Malabry (France)


    The design of domestic burners crucially depends on the availability of tools taking into account complex interactions between flame chemistry, heat transfer and fluid flow. A very promising approach is therefore the development of modern simulation tools incorporating appropriate physical models that enable the predicition of flame stability and pollutant formation in practical devices. Given the complex, 3D geometry of practical burners, we decided to adapt the commercially available, general purpose CFD-code ESTET to the simulation of combustion in domestic burners. This has been achieved through the implementation of a complex chemical kinetics library (BISCUIT) within the CFD code and an adaptation of the graphical user interface. The resulting tool is capable to predict partially premixed flames that characterize domestic burners, as well as the formation of pollutants such as NO{sub x} and has been carefully validated against experimental data obtained for a model burner. Computational ressources required for multi-dimensional burner configurations are standard UNIX workstations. Computing time typically varies from 3 h to 150 h, depending on the physical models used. (orig.)

  16. Advanced burner test reactor preconceptual design report.

    Energy Technology Data Exchange (ETDEWEB)

    Chang, Y. I.; Finck, P. J.; Grandy, C.; Cahalan, J.; Deitrich, L.; Dunn, F.; Fallin, D.; Farmer, M.; Fanning, T.; Kim, T.; Krajtl, L.; Lomperski, S.; Moisseytsev, A.; Momozaki, Y.; Sienicki, J.; Park, Y.; Tang, Y.; Reed, C.; Tzanos, C; Wiedmeyer, S.; Yang, W.; Chikazawa, Y.; JAEA


    The goals of the Global Nuclear Energy Partnership (GNEP) are to expand the use of nuclear energy to meet increasing global energy demand, to address nuclear waste management concerns and to promote non-proliferation. Implementation of the GNEP requires development and demonstration of three major technologies: (1) Light water reactor (LWR) spent fuel separations technologies that will recover transuranics to be recycled for fuel but not separate plutonium from other transuranics, thereby providing proliferation-resistance; (2) Advanced Burner Reactors (ABRs) based on a fast spectrum that transmute the recycled transuranics to produce energy while also reducing the long term radiotoxicity and decay heat loading in the repository; and (3) Fast reactor fuel recycling technologies to recover and refabricate the transuranics for repeated recycling in the fast reactor system. The primary mission of the ABR Program is to demonstrate the transmutation of transuranics recovered from the LWR spent fuel, and hence the benefits of the fuel cycle closure to nuclear waste management. The transmutation, or burning of the transuranics is accomplished by fissioning and this is most effectively done in a fast spectrum. In the thermal spectrum of commercial LWRs, some transuranics capture neutrons and become even heavier transuranics rather than being fissioned. Even with repeated recycling, only about 30% can be transmuted, which is an intrinsic limitation of all thermal spectrum reactors. Only in a fast spectrum can all transuranics be effectively fissioned to eliminate their long-term radiotoxicity and decay heat. The Advanced Burner Test Reactor (ABTR) is the first step in demonstrating the transmutation technologies. It directly supports development of a prototype full-scale Advanced Burner Reactor, which would be followed by commercial deployment of ABRs. The primary objectives of the ABTR are: (1) To demonstrate reactor-based transmutation of transuranics as part of an

  17. TUCS/phosphate mineralization of actinides

    Energy Technology Data Exchange (ETDEWEB)

    Nash, K.L. [Argonne National Lab., IL (United States)


    This program has as its objective the development of a new technology that combines cation exchange and mineralization to reduce the concentration of heavy metals (in particular actinides) in groundwaters. The treatment regimen must be compatible with the groundwater and soil, potentially using groundwater/soil components to aid in the immobilization process. The delivery system (probably a water-soluble chelating agent) should first concentrate the radionuclides then release the precipitating anion, which forms thermodynamically stable mineral phases, either with the target metal ions alone or in combination with matrix cations. This approach should generate thermodynamically stable mineral phases resistant to weathering. The chelating agent should decompose spontaneously with time, release the mineralizing agent, and leave a residue that does not interfere with mineral formation. For the actinides, the ideal compound probably will release phosphate, as actinide phosphate mineral phases are among the least soluble species for these metals. The most promising means of delivering the precipitant would be to use a water-soluble, hydrolytically unstable complexant that functions in the initial stages as a cation exchanger to concentrate the metal ions. As it decomposes, the chelating agent releases phosphate to foster formation of crystalline mineral phases. Because it involves only the application of inexpensive reagents, the method of phosphate mineralization promises to be an economical alternative for in situ immobilization of radionuclides (actinides in particular). The method relies on the inherent (thermodynamic) stability of actinide mineral phases.

  18. Enhanced Combustion Low NOx Pulverized Coal Burner

    Energy Technology Data Exchange (ETDEWEB)

    David Towle; Richard Donais; Todd Hellewell; Robert Lewis; Robert Schrecengost


    For more than two decades, Alstom Power Inc. (Alstom) has developed a range of low cost, infurnace technologies for NOx emissions control for the domestic U.S. pulverized coal fired boiler market. This includes Alstom's internally developed TFS 2000{trademark} firing system, and various enhancements to it developed in concert with the U.S. Department of Energy. As of the date of this report, more than 270 units representing approximately 80,000 MWe of domestic coal fired capacity have been retrofit with Alstom low NOx technology. Best of class emissions range from 0.18 lb/MMBtu for bituminous coal to 0.10 lb/MMBtu for subbituminous coal, with typical levels at 0.24 lb/MMBtu and 0.13 lb/MMBtu, respectively. Despite these gains, NOx emissions limits in the U.S. continue to ratchet down for new and existing boiler equipment. On March 10, 2005, the Environmental Protection Agency (EPA) announced the Clean Air Interstate Rule (CAIR). CAIR requires 25 Eastern states to reduce NOx emissions from the power generation sector by 1.7 million tons in 2009 and 2.0 million tons by 2015. Low cost solutions to meet such regulations, and in particular those that can avoid the need for a costly selective catalytic reduction system (SCR), provide a strong incentive to continue to improve low NOx firing system technology to meet current and anticipated NOx control regulations. The overall objective of the work is to develop an enhanced combustion, low NOx pulverized coal burner, which, when integrated with Alstom's state-of-the-art, globally air staged low NOx firing systems will provide a means to achieve: Less than 0.15 lb/MMBtu NOx emissions when firing a high volatile Eastern or Western bituminous coal, Less than 0.10 lb/MMBtu NOx emissions when firing a subbituminous coal, NOx reduction costs at least 25% lower than the costs of an SCR, Validation of the NOx control technology developed through large (15 MWt) pilot scale demonstration, and Documentation required for

  19. Flashback Analysis in Tangential Swirl Burners

    Directory of Open Access Journals (Sweden)

    Valera-Medina A.


    Full Text Available Premixed lean combustion is widely used in Combustion Processes due to the benefits of good flame stability and blowoff limits coupled with low NOx emissions. However, the use of novel fuels and complex flows have increased the concern about flashback, especially for the use of syngas and highly hydrogen enriched blends. Thus, this paper describes a combined practical and numerical approach to study the phenomenon in order to reduce the effect of flashback in a pilot scale 100 kW tangential swirl burner. Natural gas is used to establish the baseline results and effects of different parameters changes. The flashback phenomenon is studied with the use of high speed photography. The use of a central fuel injector demonstrates substantial benefits in terms of flashback resistance, eliminating coherent structures that may appear in the flow channels. The critical boundary velocity gradient is used for characterization, both via the original Lewis and von Elbe formula and via analysis using CFD and investigation of boundary layer conditions in the flame front.

  20. The Actinide-Lanthanide Separation Process

    Energy Technology Data Exchange (ETDEWEB)

    Lumetta, Gregg J.; Gelis, Artem V.; Carter, Jennifer C.; Niver, Cynthia M.; Smoot, Margaret R.


    The Actinide-Lanthanide SEParation (ALSEP) process is described. The process uses an extractant phase consisting of either N,N,N',N'-tetraoctyldiglycolamide (TODGA) or N,N,N',N'-tetra(2 ethylhexyl)diglycolamide (T2EHDGA) combined with 2-ethylhexylphosphonic acid mono-2-ethylhexyl ester (HEH[EHP]). The neutral TODGA or T2EHDGA serves to co-extract the trivalent actinide and lanthanide ions from nitric acid media. Switching the aqueous phase chemistry to a citrate buffered diethylenetriaminepentaacetic acid (DTPA) solution at pH 2.5 to 4 results in selective transfer of the actinides to the aqueous phase, thus resulting in separation of these two groups of elements.

  1. Monazite as a suitable actinide waste form

    Energy Technology Data Exchange (ETDEWEB)

    Schlenz, Hartmut; Heuser, Julia; Schmitz, Stephan; Bosbach, Dirk [Forschungszentrum Juelich GmbH (Germany). Inst. fuer Energie und Klimaforschung (IEK), Nukleare Entsorgung und Reaktorsicherheit (IEK-6); Neumann, Andreas [Forschungszentrum Juelich GmbH (Germany). Inst. fuer Energie und Klimaforschung (IEK), Nukleare Entsorgung und Reaktorsicherheit (IEK-6); RWTH Aachen Univ. (Germany). Inst. for Crystallography


    The conditioning of radioactive waste from nuclear power plants and in some countries even of weapons plutonium is an important issue for science and society. Therefore the research on appropriate matrices for the immobilization of fission products and actinides is of great interest. Beyond the widely used borosilicate glasses, ceramics are promising materials for the conditioning of actinides like U, Np, Pu, Am, and Cm. Monazite-type ceramics with general composition LnPO{sub 4} (Ln = La to Gd) and solid solutions of monazite with cheralite or huttonite represent important materials in this field. Monazite appears to be a promising candidate material, especially because of its outstanding properties regarding radiation resistance and chemical durability. This article summarizes the most recent results concerning the characterization of monazite and respective solid solutions and the study of their chemical, thermal, physical and structural properties. The aim is to demonstrate the suitability of monazite as a secure and reliable waste form for actinides. (orig.)

  2. Universal worth: construct and scale development. (United States)

    Rouse, Steven V


    Although research has demonstrated that narcissistic, contingent, and unsubstantiated forms of self-esteem correlate with undesirable behavior patterns, other researchers have searched for prosocial forms of belief in one's worth. Universal worth is proposed as the belief that (a) one is valued by a deity; (b) one's value is not contingent on success or failure; and (c) one is not valued by a deity more or less than others are valued. The Universal Worth Scale (UWS) was developed to measure this set of beliefs. Psychometric analyses showed that UWS scores were both internally consistent and temporally stable. Although scores on this scale were correlated with measures of constructs that were expected to be associated, the pattern of correlations suggests that UWS scores measure a distinct construct. Future research is suggested to explore universal worth in relation to sociometer theory and terror management theory, and within the continued search for prosocial foundations of self-worth.

  3. Influence of burner form and pellet type on domestic pellet boiler performance (United States)

    Rastvorov, D. V.; Osintsev, K. V.; Toropov, E. V.


    The study presents combustion and emission results obtained using two serial pellet boilers of the same heating capacity 40 kW. These boilers have been designed by producers for domestic conditions of exploitation. The principal difference between boilers was the type of the burner. The study concerns the efficiency and ecological performance difference between burners of circular and rectangular forms. The features of the combustion process in both types of burners were studied when boiler operated with different sorts of pellets. The results suggest that the burner of circular form excels the rectangular form burner. However, there is some difference of NOx emission between circular and rectangular burners.

  4. Development of a non-premixed radiant burner. Experimental results

    Energy Technology Data Exchange (ETDEWEB)

    Andersen, P.; Myken, A.N.; Rasmussen, N.B.


    The objective was to develop and test a non-premixed radiant burner. A burner concept, pro-type 1, was developed with special attention to minimise emissions and foam peak-temperatures. During the test of the prototype it became evident that the construction was not feasible, because the ceramic gas distribution tubes eventually were blocked by soot. Experiments to investigate if the gas would crack conducted prior to the construction of the burner did not indicate that any problems would occur. It can therefore be concluded that the experiments did not simulate burner conditions adequately. Alternative prototypes in which the gas is not heated prior to injection into the combustion chamber have been established. The concept operated satisfactorily without preheating of the combustion air, although NO{sub x}-emissions were high. The measured process efficiencies were superior to previous results for different kinds of surface burners. When the combustion air was preheated to 400 deg. C, the foam sections broke down. The experimental results can be summarised in the following conclusions: The developed prototypes can not be operated with combustion air preheated to 400 deg. C or higher; A relative improvement of the process efficiency by 22% has been observed when the combustion air is preheated to 400 deg. C; The NO{sub x}-emissions increase significantly and much more than the process efficiency when the combustion air is preheated; The process efficiency obtained with prototype 5 is better than previously investigated surface burners, especially at high loads. Possible means to improve durability, efficiency and emission level for both burner concepts are suggested. These include cooling of the gas in prototype 1, coating of the downstream side of the foam section to improve the radiant efficiency and multistep combustion. (EHS)

  5. Spin–orbit coupling in actinide cations

    DEFF Research Database (Denmark)

    Bagus, Paul S.; Ilton, Eugene S.; Martin, Richard L.


    The limiting case of Russell–Saunders coupling, which leads to a maximum spin alignment for the open shell electrons, usually explains the properties of high spin ionic crystals with transition metals. For actinide compounds, the spin–orbit splitting is large enough to cause a significantly reduc...... spin alignment. Novel concepts are used to explain the dependence of the spin alignment on the 5f shell occupation. We present evidence that the XPS of ionic actinide materials may provide direct information about the angular momentum coupling within the 5f shell....

  6. Actinide and fission product separation and transmutation

    Energy Technology Data Exchange (ETDEWEB)



    The second international information exchange meeting on actinide and fission product separation and transmutation, took place in Argonne National Laboratory in Illinois United States, on 11-13 November 1992. The proceedings are presented in four sessions: Current strategic system of actinide and fission product separation and transmutation, progress in R and D on partitioning processes wet and dry, progress in R and D on transmutation and refinements of neutronic and other data, development of the fuel cycle processes fuel types and targets. (A.L.B.)

  7. Advanced Burner Reactor Preliminary NEPA Data Study.

    Energy Technology Data Exchange (ETDEWEB)

    Briggs, L. L.; Cahalan, J. E.; Deitrich, L. W.; Fanning, T. H.; Grandy, C.; Kellogg, R.; Kim, T. K.; Yang, W. S.; Nuclear Engineering Division


    The Global Nuclear Energy Partnership (GNEP) is a new nuclear fuel cycle paradigm with the goals of expanding the use of nuclear power both domestically and internationally, addressing nuclear waste management concerns, and promoting nonproliferation. A key aspect of this program is fast reactor transmutation, in which transuranics recovered from light water reactor spent fuel are to be recycled to create fast reactor transmutation fuels. The benefits of these fuels are to be demonstrated in an Advanced Burner Reactor (ABR), which will provide a representative environment for recycle fuel testing, safety testing, and modern fast reactor design and safeguard features. Because the GNEP programs will require facilities which may have an impact upon the environment within the meaning of the National Environmental Policy Act of 1969 (NEPA), preparation of a Programmatic Environmental Impact Statement (PEIS) for GNEP is being undertaken by Tetra Tech, Inc. The PEIS will include a section on the ABR. In support of the PEIS, the Nuclear Engineering Division of Argonne National Laboratory has been asked to provide a description of the ABR alternative, including graphics, plus estimates of construction and operations data for an ABR plant. The compilation of this information is presented in the remainder of this report. Currently, DOE has started the process of engaging industry on the design of an Advanced Burner Reactor. Therefore, there is no specific, current, vendor-produced ABR design that could be used for this PEIS datacall package. In addition, candidate sites for the ABR vary widely as to available water, geography, etc. Therefore, ANL has based its estimates for construction and operations data largely on generalization of available information from existing plants and from the environmental report assembled for the Clinch River Breeder Reactor Plant (CRBRP) design [CRBRP, 1977]. The CRBRP environmental report was chosen as a resource because it thoroughly

  8. Actinide measurements by AMS using fluoride matrices

    Energy Technology Data Exchange (ETDEWEB)

    Cornett, R.J., E-mail: [André E. Lalonde AMS Laboratory, University of Ottawa, 150 Louis Pasteur, Ottawa, ON K1N 6N5 (Canada); Department of Earth Sciences, University of Ottawa, 150 Louis Pasteur, Ottawa, ON K1N 6N5 (Canada); Kazi, Z.H. [André E. Lalonde AMS Laboratory, University of Ottawa, 150 Louis Pasteur, Ottawa, ON K1N 6N5 (Canada); Department of Earth Sciences, University of Ottawa, 150 Louis Pasteur, Ottawa, ON K1N 6N5 (Canada); Zhao, X.-L. [André E. Lalonde AMS Laboratory, University of Ottawa, 150 Louis Pasteur, Ottawa, ON K1N 6N5 (Canada); Department of Physics, University of Ottawa, 150 Louis Pasteur, Ottawa, ON K1N 6N5 (Canada); Chartrand, M.G. [André E. Lalonde AMS Laboratory, University of Ottawa, 150 Louis Pasteur, Ottawa, ON K1N 6N5 (Canada); Department of Earth Sciences, University of Ottawa, 150 Louis Pasteur, Ottawa, ON K1N 6N5 (Canada); Charles, R.J.; Kieser, W.E. [André E. Lalonde AMS Laboratory, University of Ottawa, 150 Louis Pasteur, Ottawa, ON K1N 6N5 (Canada); Department of Physics, University of Ottawa, 150 Louis Pasteur, Ottawa, ON K1N 6N5 (Canada)


    Actinides can be measured by alpha spectroscopy (AS), mass spectroscopy or accelerator mass spectrometry (AMS). We tested a simple method to separate Pu and Am isotopes from the sample matrix using a single extraction chromatography column. The actinides in the column eluent were then measured by AS or AMS using a fluoride target matrix. Pu and Am were coprecipitated with NdF{sub 3}. The strongest AMS beams of Pu and Am were produced when there was a large excess of fluoride donor atoms in the target and the NdF{sub 3} precipitates were diluted about 6–8 fold with PbF{sub 2}. The measured concentrations of {sup 239,240}Pu and {sup 241}Am agreed with the concentrations in standards of known activity and with two IAEA certified reference materials. Measurements of {sup 239,240}Pu and {sup 241}Am made at A.E. Lalonde AMS Laboratory agree, within their statistical uncertainty, with independent measurements made using the IsoTrace AMS system. This work demonstrated that fluoride targets can produce reliable beams of actinide anions and that the measurement of actinides using fluorides agree with published values in certified reference materials.

  9. Actinide and fission product partitioning and transmutation

    Energy Technology Data Exchange (ETDEWEB)



    The third international information exchange meeting on actinide and fission product partitioning and transmutation, took place in Cadarache France, on 12-14 December 1994. The proceedings are presented in six sessions : an introduction session, the major programmes and international cooperation, the systems studies, the reactors fuels and targets, the chemistry and a last discussions session. (A.L.B.)

  10. Electronic Structure of the Actinide Metals

    DEFF Research Database (Denmark)

    Johansson, B.; Skriver, Hans Lomholt


    itinerant to localized 5f electron behaviour calculated to take place between plutonium and americium. From experimental data it is shown that the screening of deep core-holes is due to 5f electrons for the lighter actinide elements and 6d electrons for the heavier elements. A simplified model for the full...

  11. Calculated Bulk Properties of the Actinide Metals

    DEFF Research Database (Denmark)

    Skriver, Hans Lomholt; Andersen, O. K.; Johansson, B.


    Self-consistent relativistic calculations of the electronic properties for seven actinides (Ac-Am) have been performed using the linear muffin-tin orbitals method within the atomic-sphere approximation. Exchange and correlation were included in the local spin-density scheme. The theory explains t...

  12. Compact Green's Function for a Generic Rijke Burner

    Directory of Open Access Journals (Sweden)

    P. R. Murray


    Full Text Available A theoretical examination is made of the thermo-acoustic properties of a Rijke burner of large aspect ratio rectangular cross-section. Such a generic device has been proposed by Kok et al. (2009 paper presented at the 16th International Congress on Sound & Vibration to make canonical studies of combustion instabilities. An aeroacoustic Green's function is derived which permits the sound pressure produced by arbitrary thermal and vortex sources within the burner to be calculated by convolution. The Green's function corresponds to the potential flow sound field produced by an impulsive point source; its calculation taking account of flame-holder geometry is facilitated by use of the Schwarz-Christoffel transformation. The transformation is performed numerically to accommodate complex burner geometry and validated by comparison with an alternative procedure involving the direct numerical integration of Laplace's equation.

  13. Adventures in Actinide Chemistry: A Year of Exploring Uranium and Thorium in Los Alamos

    Energy Technology Data Exchange (ETDEWEB)

    Pagano, Justin [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)


    The first part of this collection of slides is concerned with considerations when working with actinides. The topics discussed in the document as a whole are the following: Actinide chemistry vs. transition metal chemistry--tools we can use; New synthetic methods to obtain actinide hydrides; Actinide metallacycles: synthesis, structure, and properties; and Reactivity of actinide metallacycles.

  14. Use of freeze-casting in advanced burner reactor fuel design

    Energy Technology Data Exchange (ETDEWEB)

    Lang, A. L.; Yablinsky, C. A.; Allen, T. R. [Dept. of Engineering Physics, Univ. of Wisconsin Madison, 1500 Engineering Drive, Madison, WI 53711 (United States); Burger, J.; Hunger, P. M.; Wegst, U. G. K. [Thayer School of Engineering, Dartmouth College, 8000 Cummings Hall, Hanover, NH 03755 (United States)


    This paper will detail the modeling of a fast reactor with fuel pins created using a freeze-casting process. Freeze-casting is a method of creating an inert scaffold within a fuel pin. The scaffold is created using a directional solidification process and results in open porosity for emplacement of fuel, with pores ranging in size from 300 microns to 500 microns in diameter. These pores allow multiple fuel types and enrichments to be loaded into one fuel pin. Also, each pore could be filled with varying amounts of fuel to allow for the specific volume of fission gases created by that fuel type. Currently fast reactors, including advanced burner reactors (ABR's), are not economically feasible due to the high cost of operating the reactors and of reprocessing the fuel. However, if the fuel could be very precisely placed, such as within a freeze-cast scaffold, this could increase fuel performance and result in a valid design with a much lower cost per megawatt. In addition to competitive costs, freeze-cast fuel would also allow for selective breeding or burning of actinides within specific locations in fast reactors. For example, fast flux peak locations could be utilized on a minute scale to target specific actinides for transmutation. Freeze-cast fuel is extremely flexible and has great potential in a variety of applications. This paper performs initial modeling of freeze-cast fuel, with the generic fast reactor parameters for this model based on EBR-II. The core has an assumed power of 62.5 MWt. The neutronics code used was Monte Carlo N-Particle (MCNP5) transport code. Uniform pore sizes were used in increments of 100 microns. Two different freeze-cast scaffold materials were used: ceramic (MgO-ZrO{sub 2}) and steel (SS316L). Separate models were needed for each material because the freeze-cast ceramic and metal scaffolds have different structural characteristics and overall porosities. Basic criticality results were compiled for the various models

  15. Lessons Worth Remembering: Combat In Urban Areas (United States)


    Lessons Worth Remembering: Combat in Urban Areas A Monograph by MAJ Ron Hernandez...Monograph June 20 15 - .tv1ay 20 16 4. TITLE AND SUBTITLE Sa. CONTRACT NUMBER Lessons Worth Remembering: Combat in Urban Areas Sb. GRANT NUMBER Sc...alarming rate. In 1950, twenty-nine percent of the world’s population lived in urban areas. Today, this statistic stands at fifty-four percent. By 2030

  16. Minor Actinide Transmutation Physics for Low Conversion Ratio Sodium Fast Reactors

    Energy Technology Data Exchange (ETDEWEB)

    Mehdi Asgari; Samuel E. Bays; Benoit Forget; Rodolfo Ferrer


    The effects of varying the reprocessing strategy used in the closed cycle of a Sodium Fast Reactor (SNF) prototype are presented in this paper. The isotopic vector from the aqueous separation of transuranic (TRU) elements in Light Water Reactor (LWR) spent nuclear fuel (SNF) is assumed to also vary according to the reprocessing strategy of the closed fuel cycle. The decay heat, gamma energy, and neutron emission of the fuel discharge at equilibrium are found to vary depending on the separation strategy. The SFR core used in this study corresponds to a burner configuration with a conversion ratio of ~0.5 based on the Super-PRISM design. The reprocessing strategies stemming from the choice of either metal or oxide fuel for the SFR are found to have a large impact on the equilibrium discharge decay heat, gamma energy, and neutron emission. Specifically, metal fuel SFR with pyroprocessing of the discharge produces the largest amount of TRU consumption (166 kg per Effective Full Power Year or EFPY), but also the highest decay heat, gamma energy, and neutron emission. On the other hand, an oxide fuel SFR with PUREX reprocessing minimizes the decay heat and related parameters of interest to a minimum, even when compared to thermal Mixed Oxide (MOX) or Inert Matrix Fuel (IMF) on a per mass basis. On an assembly basis, however, the metal SFR discharge has a lower decay heat than an equivalent oxide SFR assembly for similar minor actinide consumptions (~160 kg/EFPY.) Another disadvantage in the oxide PUREX reprocessing scenario is that there is no consumption of americium and curium, since PUREX reprocessing separates these minor actinides (MA) and requires them to be disposed of externally.

  17. Recovery of actinides from actinide-aluminium alloys by chlorination: Part I

    Energy Technology Data Exchange (ETDEWEB)

    Cassayre, L., E-mail: [Laboratoire de Genie Chimique (LGC), Departement Procedes Electrochimiques, CNRS-UMR 5503, Universite de Toulouse III - Paul Sabatier, 31062 Toulouse (France); Soucek, P.; Mendes, E.; Malmbeck, R.; Nourry, C.; Eloirdi, R.; Glatz, J.-P. [European Commission, JRC, Institute for Transuranium Elements, Postfach 2340, 76125 Karlsruhe (Germany)


    Pyrochemical processes in molten LiCl-KCl are being developed in ITU for recovery of actinides from spent nuclear fuel. The fuel is anodically dissolved to the molten salt electrolyte and actinides are electrochemically reduced on solid aluminium cathodes forming solid actinide-aluminium alloys. A chlorination route is being investigated for recovery of actinides from the alloys. This route consists in three steps: Vacuum distillation for removal of the salt adhered on the electrode, chlorination of the actinide-aluminium alloys by chlorine gas and sublimation of the formed AlCl{sub 3}. A thermochemical study showed thermodynamic feasibility of all three steps. On the basis of the conditions identified by the calculations, experiments using pure UAl{sub 3} alloy were carried out to evaluate and optimise the chlorination step. The work was focused on determination of the optimal temperature and Cl{sub 2}/UAl{sub 3} molar ratio, providing complete chlorination of the alloy without formation of volatile UCl{sub 5} and UCl{sub 6}. The results showed high efficient chlorination at a temperature of 150 deg. C.

  18. Experiments on a rotating-pipe swirl burner

    NARCIS (Netherlands)

    Hübner, A.W.; Tummers, M.J.; Hanjalic, K.; van der Meer, Theodorus H.


    Laser-Doppler measurements of mean velocity components and Reynolds stresses are reported in the near-field of a stable swirling flame of a newly designed natural-gas-fired experimental burner. The swirling motion is generated by the rotating outer pipe of the annular air passage, thus providing

  19. How Efficient is a Laboratory Burner in Heating Water? (United States)

    Jansen, Michael P.


    Describes an experiment in which chemistry students determine the efficiency of a laboratory burner used to heat water. The reaction is assumed to be the complete combustion of methane, CH4. The experiment is appropriate for secondary school chemistry students familiar with heats of reaction and simple calorimetry. Contains pre-laboratory and…

  20. Camping Burner-Based Flame Emission Spectrometer for Classroom Demonstrations (United States)

    Ne´el, Bastien; Crespo, Gasto´n A.; Perret, Didier; Cherubini, Thomas; Bakker, Eric


    A flame emission spectrometer was built in-house for the purpose of introducing this analytical technique to students at the high school level. The aqueous sample is sprayed through a homemade nebulizer into the air inlet of a consumer-grade propane camping burner. The resulting flame is analyzed by a commercial array spectrometer for the visible…

  1. Transmutation of nuclear waste. Status report RAS programme 1994: Recycling and transmutation of actinides and fission products

    Energy Technology Data Exchange (ETDEWEB)

    Cordfunke, E.H.P.; Gruppelaar, H.; Franken, W.M.P.


    This report describes the status and progress of the Dutch RAS programme on `Recycling and Transmutation of Actinides and Fission Products` over the year 1994, which is the first year of the second 4-year programme. This programme is outlined and a short progress report is given over 1994, including a listing of 23 reports and publications over the year 1994. Highlights of 1994 were: The completion of long-lived fission-product transmutation studies, the initiation of small-scale demonstration experiments in the HFR on Tc and I, the issue of reports on the potential of the ALMR (Advanced Liquid Metal Reactor) for transmutation adn the participation and international cooperation on irradiation experiments with actinides in inert matrices. The remaining chapters contain more extended contributions on recent developments and selected topics, under the headings: Benefits and risks of partitioning and transmutation, Perspective of chemical partitioning, Inert matrices, Evolutionary options (MOX), Perspective of heavy water reactors, Perspective of fast burners, Perspective of accelerator-based systems, Thorium cycle, Fission-product transmutation, End scenarios, and Executive summary and recommendations. (orig.).

  2. Actinide and fission product separation and transmutation

    Energy Technology Data Exchange (ETDEWEB)



    The first international information exchange meeting on actinide and fission product separation and transmutation, took place in Mito in Japan, on 6-8 November 1990. It starts with a number of general overview papers to give us some broad perspectives. Following that it takes a look at some basic facts about physics and about the quantities of materials it is talking about. Then it proceeds to some specific aspects of partitioning, starting with evolution from today commercially applied processes and going on to other possibilities. At the end of the third session it takes a look at the significance of partitioning and transmutation of actinides before it embarks on two sessions on transmutation, first in reactors and second in accelerators. The last session is designed to throw back into the discussion the main points which need to be looked at when considering future work in this area. (A.L.B.)

  3. Microbial Transformations of Actinides and Other Radionuclides

    Energy Technology Data Exchange (ETDEWEB)

    Francis,A.J.; Dodge, C. J.


    Microorganisms can affect the stability and mobility of the actinides and other radionuclides released from nuclear fuel cycle and from nuclear fuel reprocessing plants. Under appropriate conditions, microorganisms can alter the chemical speciation, solubility and sorption properties and thus could increase or decrease the concentrations of radionuclides in solution in the environment and the bioavailability. Dissolution or immobilization of radionuclides is brought about by direct enzymatic action or indirect non-enzymatic action of microorganisms. Although the physical, chemical, and geochemical processes affecting dissolution, precipitation, and mobilization of radionuclides have been extensively investigated, we have only limited information on the effects of microbial processes and biochemical mechanisms which affect the stability and mobility of radionuclides. The mechanisms of microbial transformations of the major and minor actinides U, Pu, Cm, Am, Np, the fission products and other radionuclides such as Ra, Tc, I, Cs, Sr, under aerobic and anaerobic conditions in the presence of electron donors and acceptors are reviewed.

  4. Actinide uptake by transferrin and ferritin metalloproteins

    Energy Technology Data Exchange (ETDEWEB)

    Den Auwer, C.; Llorens, I.; Moisy, Ph. [CEA Marcoule DEN/DRCP/SCPS, Bagnols sur Ceze (France); Vidaud, C. [CEA Marcoule DSV/DIEP/SBTN, Bagnols sur Ceze (France); Goudard, F.; Barbot, C. [Univ. de Nantes, Faculte des Sciences, Biochim., Nantes (France); Solari, P.L. [BM29, ESRF, Grenoble (France); Funke, H. [FZR, Rossendorf beamline (BM20), ESRF, Grenoble (France)


    In order to better understand the mechanisms of actinide uptake by specific biomolecules, it is essential to explore the intramolecular interactions between the cation and the protein binding site. Although this has long been done for widely investigated transition metals, very few studies have been devoted to complexation mechanisms of actinides by active chelation sites of metalloproteins. In this field, X-ray absorption spectroscopy has been extensively used as a structural and electronic metal cation probe. The two examples that are presented here are related to two metalloproteins in charge of iron transport and storage in eukaryote cells: transferrin and ferritin. U(VI)O{sub 2}{sup 2+}, Np(IV) and Pu(IV) have been selected because of their possible role as contaminant from the geosphere. (orig.)

  5. Actinide and fission product partitioning and transmutation

    Energy Technology Data Exchange (ETDEWEB)



    The fourth international information exchange meeting on actinide and fission product partitioning and transmutation, took place in Mito City in Japan, on 111-13 September 1996. The proceedings are presented in six sessions: the major programmes and international cooperation, the partitioning and transmutation programs, feasibility studies, particular separation processes, the accelerator driven transmutation, and the chemistry of the fuel cycle. (A.L.B.)

  6. Actinide Topological Insulator Materials with Strong Interaction


    Zhang, X.; Zhang, H.; Wang, J.; Felser, C.; Zhang, S.-C.


    Topological band insulators have recently been discovered in spin-orbit coupled two and three dimensional systems. In this work, we theoretically predict a class of topological Mott insulators where interaction effects play a dominant role. In actinide elements, simple rocksalt compounds formed by Pu and Am lie on the boundary of metal to insulator transition. We show that interaction drives a quantum phase transition to a topological Mott insulator phase with a single Dirac cone on the surface.

  7. Preparation, properties, and some recent studies of the actinide metals

    Energy Technology Data Exchange (ETDEWEB)

    Haire, R.G.


    The actinide elements form a unique series of metals. The variation in their physial properties combined with the varying availability of the different elements offers a challenge to the preparative scientist. This article provides a brief review of selected methods used for preparing to kg amounts of the actinide metals and the properties of these metals. In addition, some recent studies on selected actinide metals are discussed. 62 refs.

  8. Actinide and lanthanide separation process (ALSEP) (United States)

    Guelis, Artem V.


    The process of the invention is the separation of minor actinides from lanthanides in a fluid mixture comprising, fission products, lanthanides, minor actinides, rare earth elements, nitric acid and water by addition of an organic chelating aid to the fluid; extracting the fluid with a solvent comprising a first extractant, a second extractant and an organic diluent to form an organic extractant stream and an aqueous raffinate. Scrubbing the organic stream with a dicarboxylic acid and a chelating agent to form a scrubber discharge. The scrubber discharge is stripped with a simple buffering agent and a second chelating agent in the pH range of 2.5 to 6.1 to produce actinide and lanthanide streams and spent organic diluents. The first extractant is selected from bis(2-ethylhexyl)hydrogen phosphate (HDEHP) and mono(2-ethylhexyl)2-ethylhexyl phosphonate (HEH(EHP)) and the second extractant is selected from N,N,N,N-tetra-2-ethylhexyl diglycol amide (TEHDGA) and N,N,N',N'-tetraoctyl-3-oxapentanediamide (TODGA).

  9. Design and flow analysis for an oxygen-blown pulverized coal burner

    Energy Technology Data Exchange (ETDEWEB)

    Haeyang Pak; Nobuyuki Iwashima; Noriyuki Kobayashi; Masanobu Hasatani [Nagoya University, Nagoya (Japan). Department of Energy Engineering and Science


    An oxygen-blown pulverized coal burner for utilization of various kinds of coal was newly proposed and developed. The combustion efficiency of 99.7% was achieved by the moderate swirl burner. The flame stabilization could not be realized by the strong swirl burner, and the content of unburned carbon in ash was more than that of the moderate swirl burner experiment. The distribution of vorticity in the moderate swirling flow was equally proportioned even though the flow ratio was changed between 0.15 and 0.88. Additionally, the state of untidiness was observed near the central part of the burner nozzle in the strong swirling flow. The close relationship between combustion efficiency and vorticity profiles was found by PIV analysis of the flow. The moderate swirl burner was suitable for designing the burner structure in oxygen-blown pulverized coal combustion.

  10. Hydrothermal decomposition of actinide(IV oxalates: a new aqueous route towards reactive actinide oxide nanocrystals

    Directory of Open Access Journals (Sweden)

    Walter Olaf


    Full Text Available The hydrothermal decomposition of actinide(IV oxalates (An= Th, U, Pu at temperatures between 95 and 250 °C is shown to lead to the production of highly crystalline, reactive actinide oxide nanocrystals (NCs. This aqueous process proved to be quantitative, reproducible and fast (depending on temperature. The NCs obtained were characterised by X-ray diffraction and TEM showing their size to be smaller than 15 nm. Attempts to extend this general approach towards transition metal or lanthanide oxalates failed in the 95–250 °C temperature range. The hydrothermal decomposition of actinide oxalates is therefore a clean, flexible and powerful approach towards NCs of AnO2 with possible scale-up potential.

  11. Development of the Actinide-Lanthanide Separation (ALSEP) Process

    Energy Technology Data Exchange (ETDEWEB)

    Lumetta, Gregg J.; Carter, Jennifer C.; Niver, Cynthia M.; Gelis, Artem V.


    Separating the minor actinide elements (Am and Cm) from acidic high-level raffinates arising from the reprocessing of irradiated nuclear fuel is an important step in closing the nuclear fuel cycle. Most proposed approaches to this problem involve two solvent extraction steps: 1) co-extraction of the trivalent lanthanides and actinides, followed by 2) separation of the actinides from the lanthanides. The objective of our work is to develop a single solvent-extraction process for isolating the minor actinide elements. We report here a solvent containing N,N,N',N'-tetra(2 ethylhexyl)diglycolamide (T2EHDGA) combined with 2-ethylhexylphosphonic acid mono-2-ethylhexyl ester (HEH[EHP]) that can be used to separate the minor actinides in a single solvent-extraction process. T2EHDGA serves to co-extract the trivalent actinide and lanthanide ions from nitric acid solution. Switching the aqueous phase chemistry to a citrate buffered solution of N-(2-hydroxyethyl)ethylenediamine-N,N',N'-triacetic acid at pH 2.5 to 4 results in selective transfer of the actinides to the aqueous phase, thus affecting separation of the actinides from the lanthanides. Separation factors between the lanthanides and actinides are approximately 20 in the pH range of 3 to 4, and the distribution ratios are not highly dependent on the pH in this system.

  12. Analyses in Support of Z-Pinch IFE and Actinide Transmutation - LLNL Progress Report for FY-06

    Energy Technology Data Exchange (ETDEWEB)

    Meier, W R; Moir, R W; Abbott, R


    This report documents results of LLNL's work in support of two studies being conducted by Sandia National Laboratories (SNL): the development of the Z-pinch driven inertial fusion energy (Z-IFE), and the use of Z-pinch driven inertial fusion as a neutron source to destroy actinides from fission reactor spent fuel. LLNL's efforts in FY06 included: (1) Development of a systems code for Z-IFE and use of the code to examine the operating parameter space in terms of design variables such as the Z-pinch driver energy, the chamber pulse repetition rate, the number of chambers making up the power plant, and the total net electric power of the plant. This is covered in Section 3 with full documentation of the model in Appendix A. (2) Continued development of innovative concepts for the design and operation of the recyclable transmission line (RTL) and chamber for Z-IFE. The work, which builds on our FY04 and FY05 contributions, emphasizes design features that are likely to lead to a more attractive power plant including: liquid jets to protect all structures from direct exposure to neutrons, rapid insertion of the RTL to maximize the potential chamber rep-rate, and use of cast flibe for the RTL to reduce recycling and remanufacturing costs and power needs. See Section 4 and Appendix B. (3) Description of potential figures of merit (FOMs) for actinide transmutation technologies and a discussion of how these FOMs apply and can be used in the ongoing evaluation of the Z-pinch actinide burner, referred to as the In-Zinerator. See Section 5. (4) A critique of, and suggested improvements to, the In-Zinerator chamber design in response to the SNL design team's request for feedback on its preliminary design. This is covered in Section 6.

  13. Advanced Aqueous Separation Systems for Actinide Partitioning

    Energy Technology Data Exchange (ETDEWEB)

    Nash, Ken [Washington State Univ., Pullman, WA (United States); Martin, Leigh [Idaho National Lab. (INL), Idaho Falls, ID (United States); Lumetta, Gregg [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)


    One of the most challenging aspects of advanced processing of used nuclear fuel is the separation of transplutonium actinides from fission product lanthanides. This separation is essential if actinide transmutation options are to be pursued in advanced fuel cycles, as lanthanides compete with actinides for neutrons in both thermal and fast reactors, thus limiting efficiency. The separation is difficult because the chemistry of Am3+ and Cm3+ is nearly identical to that of the trivalent lanthanides (Ln3+). The prior literature teaches that two approaches offer the greatest probability of devising a successful group separation process based on aqueous processes: 1) the application of complexing agents containing ligand donor atoms that are softer than oxygen (N, S, Cl-) or 2) changing the oxidation state of Am to the IV, V, or VI state to increase the essential differences between Am and lanthanide chemistry (an approach utilized in the PUREX process to selectively remove Pu4+ and UO22+ from fission products). The latter approach offers the additional benefit of enabling a separation of Am from Cm, as Cm(III) is resistant to oxidation and so can easily be made to follow the lanthanides. The fundamental limitations of these approaches are that 1) the soft(er) donor atoms that interact more strongly with actinide cations than lanthanides form substantially weaker bonds than oxygen atoms, thus necessitating modification of extraction conditions for adequate phase transfer efficiency, 2) soft donor reagents have been seen to suffer slow phase transfer kinetics and hydro-/radiolytic stability limitations and 3) the upper oxidation states of Am are all moderately strong oxidants, hence of only transient stability in media representative of conventional aqueous separations systems. There are examples in the literature of both approaches having been described. However, it is not clear at present that any extant process is sufficiently robust for application at the scale


    Energy Technology Data Exchange (ETDEWEB)



    A significant experimental program was conducted in the early Hanford reactors to understand the reactor production of actinides. These experiments were conducted with sufficient rigor, in some cases, to provide useful information that can be utilized today in development of benchmark experiments that may be used for the validation of present computer codes for the production of these actinides in low enriched uranium fuel.

  15. Process for Making a Ceramic Composition for Immobilization of Actinides

    Energy Technology Data Exchange (ETDEWEB)

    Ebbinghaus, Bartley B.; Van Konynenburg, Richard A.; Vance, Eric R.; Stewart, Martin W.; Walls, Philip A.; Brummond, William Allen; Armantrout, Guy A.; Curtis, Paul G.; Hobson, Beverly F.; Farmer, Joseph; Herman, Connie Cicero; Herman, David Thomas


    Disclosed is a process for making a ceramic composition for the immobilization of actinides, particularly uranium and plutonium. The ceramic is a titanate material comprising pyrochlore, brannerite and rutile. The process comprises oxidizing the actinides, milling the oxides to a powder, blending them with ceramic precursors, cold pressing the blend and sintering the pressed material.

  16. Detailed calculations of minor actinide transmutation in a fast reactor

    Energy Technology Data Exchange (ETDEWEB)

    Takeda, Toshikazu [Research Institute of Nuclear Engineering, University of Fukui, Kanawacho1-2-4,Tsuruga, Fukui, Japan 914-0051 (Japan)


    The transmutation of minor actinides in a fast reactor is investigated by a new method to investigate the transmutation behavior of individual minor actinides. It is found that Np-237 and Am-241 mainly contributes to the transmutation rate though the transmutation behaviors are very different.

  17. The zero age main sequence of WIMP burners (United States)

    Fairbairn, Malcolm; Scott, Pat; Edsjö, Joakim


    We modify a stellar structure code to estimate the effect upon the main sequence of the accretion of weakly-interacting dark matter onto stars and its subsequent annihilation. The effect upon the stars depends upon whether the energy generation rate from dark matter annihilation is large enough to shut off the nuclear burning in the star. Main sequence weakly-interacting massive particles (WIMP) burners look much like proto-stars moving on the Hayashi track, although they are in principle completely stable. We make some brief comments about where such stars could be found, how they might be observed and more detailed simulations which are currently in progress. Finally we comment on whether or not it is possible to link the paradoxically hot, young stars found at the galactic center with WIMP burners.

  18. Physicochemical properties of nanoparticles titania from alcohol burner calcination

    Directory of Open Access Journals (Sweden)

    Supan Yodyingyong


    Full Text Available The physicochemical properties of synthesized TiO2 nanoparticles from integrating sol-gel with flame-based techniques were studied. The synthesized nanoparticles properties were compared after using methanol, ethanol, and propanol fuel sources. The synthesized TiO2 were characterized by X-ray diffraction (XRD, transmission electron microscopy (TEM, thermal analysis (thermogravimetric analysis, TGA, and differential scanning calorimetry, DSC, and surface area Brunauer–Emmett–Teller (BET method. The photocatalytic activity of TiO2 nanoparticles was investigated by measuring the degradation of methylene blue. It was found that methanol and ethanol burners can be used as an alternative furnace that can yield TiO2 nanoparticles with physicochemical properties comparable to that of commercial TiO2 nanoparticles, while a propanol burner cannot be used as an alternative fuel.

  19. Estimation of irradiated control rod worth

    Energy Technology Data Exchange (ETDEWEB)

    Varvayanni, M., E-mail: melina@ipta.demokritos.g [NCSR ' DEMOKRITOS' , PO Box 60228, 15310 Aghia Paraskevi (Greece); Catsaros, N. [NCSR ' DEMOKRITOS' , PO Box 60228, 15310 Aghia Paraskevi (Greece); Antonopoulos-Domis, M. [School of Electrical and Computer Engineering, Aristotle University of Thessaloniki, Thessaloniki (Greece)


    When depleted control rods are planned to be used in new core configurations, their worth has to be accurately predicted in order to deduce key design and safety parameters such as the available shutdown margin. In this work a methodology is suggested for the derivation of the distributed absorbing capacity of a depleted rod, useful in the case that the level of detail that is known about the irradiation history of the control rod does not allow an accurate calculation of the absorber's burnup. The suggested methodology is based on measurements of the rod's worth carried out in the former core configuration and on corresponding calculations based on the original (before first irradiation) absorber concentration. The methodology is formulated for the general case of the multi-group theory; it is successfully tested for the one-group approximation, for a depleted control rod of the Greek Research Reactor, containing five neutron absorbers. The computations reproduce satisfactorily the irradiated rod worth measurements, practically eliminating the discrepancy of the total rod worth, compared to the computations based on the nominal absorber densities.

  20. Quantifying data worth toward reducing predictive uncertainty (United States)

    Dausman, A.M.; Doherty, J.; Langevin, C.D.; Sukop, M.C.


    The present study demonstrates a methodology for optimization of environmental data acquisition. Based on the premise that the worth of data increases in proportion to its ability to reduce the uncertainty of key model predictions, the methodology can be used to compare the worth of different data types, gathered at different locations within study areas of arbitrary complexity. The method is applied to a hypothetical nonlinear, variable density numerical model of salt and heat transport. The relative utilities of temperature and concentration measurements at different locations within the model domain are assessed in terms of their ability to reduce the uncertainty associated with predictions of movement of the salt water interface in response to a decrease in fresh water recharge. In order to test the sensitivity of the method to nonlinear model behavior, analyses were repeated for multiple realizations of system properties. Rankings of observation worth were similar for all realizations, indicating robust performance of the methodology when employed in conjunction with a highly nonlinear model. The analysis showed that while concentration and temperature measurements can both aid in the prediction of interface movement, concentration measurements, especially when taken in proximity to the interface at locations where the interface is expected to move, are of greater worth than temperature measurements. Nevertheless, it was also demonstrated that pairs of temperature measurements, taken in strategic locations with respect to the interface, can also lead to more precise predictions of interface movement. Journal compilation ?? 2010 National Ground Water Association.

  1. District heating biofuel burner efficiency and energy balance


    Okoro, Oluwashola Aderemi


    District heating is an optimal system of distributing heat to residential building in a centralized location through pipeline networks. The district heating of woodchip is cost effective, improve energy efficiency, reduce gas emissions and improve energy security. The thermal efficiency and energy balance in a boiler is obtained by combustion analysis of the wood (fuel). In this report, the district heating bio fuel burner in Skien Fjernvarme is considered. The capacity of the boiler is 6MW a...

  2. Structure of diffusion flames from a vertical burner (United States)

    Mark A. Finney; Dan Jimenez; Jack D. Cohen; Isaac C. Grenfell; Cyle Wold


    Non-steady and turbulent flames are commonly observed to produce flame contacts with adjacent fuels during fire spread in a wide range of fuel bed depths. A stationary gas-fired burner (flame wall) was developed to begin study of flame edge variability along an analagous vertical fuel source. This flame wall is surrogate for a combustion interface at the edge of a deep...

  3. Effect of cycled combustion ageing on a cordierite burner plate

    Energy Technology Data Exchange (ETDEWEB)

    Garcia, Eugenio [Instituto de Ceramica y Vidrio, CSIC, c/ Kelsen 5, Campus de Cantoblanco, 28049 Madrid (Spain); Gancedo, J. Ramon [Instituto de Quimica Fisica ' Rocasolano' , CSIC, c/ Serrano 119, 28006 Madrid (Spain); Gracia, Mercedes, E-mail: [Instituto de Quimica Fisica ' Rocasolano' , CSIC, c/ Serrano 119, 28006 Madrid (Spain)


    A combination of {sup 57}Fe-Moessbauer spectroscopy and X-ray Powder Diffraction analysis has been employed to study modifications in chemical and mechanical stability occurring in a cordierite burner aged under combustion conditions which simulate the working of domestic boilers. Moessbauer study shows that Fe is distributed into the structural sites of the cordierite lattice as Fe{sup 2+} and Fe{sup 3+} ions located mostly at octahedral sites. Ferric oxide impurities, mainly hematite, are also present in the starting cordierite material accounting for {approx_equal}40% of the total iron phases. From Moessbauer and X-ray diffraction data it can be deduced that, under the combustion conditions used, new crystalline phases were formed, some of the substitutional Fe{sup 3+} ions existing in the cordierite lattice were reduced to Fe{sup 2+}, and ferric oxides underwent a sintering process which results in hematite with higher particle size. All these findings were detected in the burner zone located in the proximity of the flame and were related to possible chemical reactions which might explain the observed deterioration of the burner material. Research Highlights: {yields}Depth profile analyses used as a probe to understand changes in refractory structure. {yields}All changes take place in the uppermost surface of the burner, close to the flame. {yields}Reduction to Fe{sup 2+} of substitutional Fe{sup 3+} ions and partial cordierite decomposition. {yields}Heating-cooling cycling induces a sintering of the existing iron oxide particles. {yields}Chemical changes can explain the alterations observed in the material microstructure.

  4. Actinide-Aluminate Speciation in Alkaline Radioactive Waste

    Energy Technology Data Exchange (ETDEWEB)

    Dr. David L. Clark; Dr. Alexander M. Fedosseev


    Investigation of behavior of actinides in alkaline media containing AL(III) showed that no aluminate complexes of actinides in oxidation states (IIII-VIII) were formed in alkaline solutions. At alkaline precipitation IPH (10-14) of actinides in presence of AL(III) formation of aluminate compounds is not observed. However, in precipitates contained actinides (IIV)<(VI), and to a lesser degree actinides (III), some interference of components takes place that is reflected in change of solid phase properties in comparison with pure components or their mechanical mixture. The interference decreases with rise of precipitation PH and at PH 14 is exhibited very feebly. In the case of NP(VII) the individual compound with AL(III) is obtained, however it is not aluminate of neptunium(VII), but neptunate of aluminium(III) similar to neptunates of other metals obtained earlier.

  5. Research in actinide chemistry. Progress report, 1990--1993

    Energy Technology Data Exchange (ETDEWEB)

    Choppin, G.R.


    This research studies the behavior of the actinide elements in aqueous solution. The high radioactivity of the transuranium actinides limits the concentrations which can be studied and, consequently, limits the experimental techniques. However, oxidation state analogs (trivalent lanthanides, tetravalent thorium, and hexavalent uranium) do not suffer from these limitations. Behavior of actinides in the environment are a major USDOE concern, whether in connection with long-term releases from a repository, releases from stored defense wastes or accidental releases in reprocessing, etc. Principal goal of our research was expand the thermodynamic data base on complexation of actinides by natural ligands (e.g., OH{sup {minus}}, CO{sub 3}{sup 2{minus}}, PO{sub 4}{sup 3{minus}}, humates). The research undertakes fundamental studies of actinide complexes which can increase understanding of the environmental behavior of these elements.

  6. Status of nuclear data for actinides

    Energy Technology Data Exchange (ETDEWEB)

    Guzhovskii, B.Y.; Gorelov, V.P.; Grebennikov, A.N. [Russia Federal Nuclear Centre, Arzamas (Russian Federation)] [and others


    Nuclear data required for transmutation problem include many actinide nuclei. In present paper the analysis of neutron fission, capture, (n,2n) and (n,3n) reaction cross sections at energy region from thermal point to 14 MeV was carried out for Th, Pa, U, Np, Pu, Am and Cm isotops using modern evaluated nuclear data libraries and handbooks of recommended nuclear data. Comparison of these data indicates on substantial discrepancies in different versions of files, that connect with quality and completeness of original experimental data.

  7. Fission cross section measurements for minor actinides

    Energy Technology Data Exchange (ETDEWEB)

    Fursov, B. [IPPE, Obninsk (Russian Federation)


    The main task of this work is the measurement of fast neutron induced fission cross section for minor actinides of {sup 238}Pu, {sup 242m}Am, {sup 243,244,245,246,247,248}Cm. The task of the work is to increase the accuracy of data in MeV energy region. Basic experimental method, fissile samples, fission detectors and electronics, track detectors, alpha counting, neutron generation, fission rate measurement, corrections to the data and error analysis are presented in this paper. (author)

  8. Actinide management with commercial fast reactors

    Energy Technology Data Exchange (ETDEWEB)

    Ohki, Shigeo [Japan Atomic Energy Agency, 4002, Narita-cho, O-arai-machi, Higashi-Ibaraki-gun, Ibaraki 311-1393 (Japan)


    The capability of plutonium-breeding and minor-actinide (MA) transmutation in the Japanese commercial sodium-cooled fast reactor offers one of practical solutions for obtaining sustainable energy resources as well as reducing radioactive toxicity and inventory. The reference core design meets the requirement of flexible breeding ratio from 1.03 to 1.2. The MA transmutation amount has been evaluated as 50-100 kg/GW{sub e}y if the MA content in fresh fuel is 3-5 wt%, where about 30-40% of initial MA can be transmuted in the discharged fuel.

  9. Combustion Characteristics of Butane Porous Burner for Thermoelectric Power Generation

    Directory of Open Access Journals (Sweden)

    K. F. Mustafa


    Full Text Available The present study explores the utilization of a porous burner for thermoelectric power generation. The porous burner was tested with butane gas using two sets of configurations: single layer porcelain and a stacked-up double layer alumina and porcelain. Six PbSnTe thermoelectric (TE modules with a total area of 54 cm2 were attached to the wall of the burner. Fins were also added to the cold side of the TE modules. Fuel-air equivalence ratio was varied between the blowoff and flashback limit and the corresponding temperature, current-voltage, and emissions were recorded. The stacked-up double layer negatively affected the combustion efficiency at an equivalence ratio of 0.20 to 0.42, but single layer porcelain shows diminishing trend in the equivalence ratio of 0.60 to 0.90. The surface temperature of a stacked-up porous media is considerably higher than the single layer. Carbon monoxide emission is independent for both porous media configurations, but moderate reduction was recorded for single layer porcelain at lean fuel-air equivalence ratio. Nitrogen oxides is insensitive in the lean fuel-air equivalence ratio for both configurations, even though slight reduction was observed in the rich region for single layer porcelain. Power output was found to be highly dependent on the temperature gradient.

  10. Multifuel burners based on the porous burner technology for the application in fuel cell systems; Mehrstofffaehige Brenner auf Basis der Porenbrennertechnik fuer den Einsatz in Brennstoffzellensystemen

    Energy Technology Data Exchange (ETDEWEB)

    Diezinger, S.


    The present doctoral thesis describes the development of multifuel burners based on the porous burner technology for the application in hydrocarbon driven fuel cell systems. One objective of such burners is the heating of the fuel cell system to the operating temperature at the cold start. In stationary operation the burner has to postcombust the waste gases from the fuel cell and the gas processing system in order to reduce the pollutant emissions. As the produced heat is required for endothermal processes like the steam reforming the burner has a significant influence on the system's efficiency. The performed investigations are targeting on a gasoline driven PEMFC-System with steam reforming. In such systems the burner has to be capable to combust the system's fuel gasoline at the cold start, a low calorific fuel cell offgas (HU = 6,4 MJ/kg) in stationary operation and a hydrogen rich gas in the case of an emergency shut down. Pre-tests revealed that in state of the art porous burners the flame front of hydrogen/air combustion can only be stabilized at very high excess air ratios. In basic investigations concerning the stabilization of flame fronts in porous media the dominant influence parameters were determined. Based on this findings a new flame trap was developed which increases the operational range with hydrogen rich mixtures significantly. Furthermore the burning velocity at stationary combustion in porous media was investigated. The dependency of the porous burning velocity on the excess air ratio for different hydrocarbons and hydrogen as well as for mixtures of both was determined. The results of these basic investigations were applied for the design of a multifuel burner. In order to achieve an evaporation of the gasoline without the use of additional energy, an internal heat exchanger section for heating the combustion air was integrated into the burner. Additionally different experimental and numerical methods were applied for designing the

  11. Design and analysis of the federal aviation administration next generation fire test burner (United States)

    Ochs, Robert Ian

    The United States Federal Aviation Administration makes use of threat-based fire test methods for the certification of aircraft cabin materials to enhance the level of safety in the event of an in-flight or post-crash fire on a transport airplane. The global nature of the aviation industry results in these test methods being performed at hundreds of laboratories around the world; in some cases testing identical materials at multiple labs but yielding different results. Maintenance of this standard for an elevated level of safety requires that the test methods be as well defined as possible, necessitating a comprehensive understanding of critical test method parameters. The tests have evolved from simple Bunsen burner material tests to larger, more complicated apparatuses, requiring greater understanding of the device for proper application. The FAA specifies a modified home heating oil burner to simulate the effects of large, intense fires for testing of aircraft seat cushions, cargo compartment liners, power plant components, and thermal acoustic insulation. Recently, the FAA has developed a Next Generation (NexGen) Fire Test burner to replace the original oil burner that has become commercially unavailable. The NexGen burner design is based on the original oil burner but with more precise control of the air and fuel flow rates with the addition of a sonic nozzle and a pressurized fuel system. Knowledge of the fundamental flow properties created by various burner configurations is desired to develop an updated and standardized burner configuration for use around the world for aircraft materials fire testing and airplane certification. To that end, the NexGen fire test burner was analyzed with Particle Image Velocimetry (PIV) to resolve the non-reacting exit flow field and determine the influence of the configuration of burner components. The correlation between the measured flow fields and the standard burner performance metrics of flame temperature and

  12. Direct ignition of pulverized coal. A new burner for a 600 MWe boiler

    Energy Technology Data Exchange (ETDEWEB)

    Fernandez, J.P.; Malaubier, F.; Mevel, J.C.

    Operation of pulverized coal boilers requires gas or oil burners for starting up which is expensive especially in France where electricity is produced by nuclear energy and for peak hours by coal burners. A 1 MW pilot plant was developed in 1983 and an industrial 10.7 MW burner for a 600 MW boiler was built in 1985 and tested in 1986. Results are reported.

  13. Evaluation of actinide biosorption by microorganisms

    Energy Technology Data Exchange (ETDEWEB)

    Happel, A.M.


    Conventional methods for removing metals from aqueous solutions include chemical precipitation, chemical oxidation or reduction, ion exchange, reverse osmosis, electrochemical treatment and evaporation. The removal of radionuclides from aqueous waste streams has largely relied on ion exchange methods which can be prohibitively costly given increasingly stringent regulatory effluent limits. The use of microbial cells as biosorbants for heavy metals offers a potential alternative to existing methods for decontamination or recovery of heavy metals from a variety of industrial waste streams and contaminated ground waters. The toxicity and the extreme and variable conditions present in many radionuclide containing waste streams may preclude the use of living microorganisms and favor the use of non-living biomass for the removal of actinides from these waste streams. In the work presented here, we have examined the biosorption of uranium by non-living, non-metabolizing microbial biomass thus avoiding the problems associated with living systems. We are investigating biosorption with the long term goal of developing microbial technologies for the remediation of actinides.

  14. Effects of Burner Configurations on the Natural Oscillation Characteristics of Laminar Jet Diffusion Flames

    Directory of Open Access Journals (Sweden)

    K. R. V. Manikantachari


    Full Text Available In this work, effects of burner configurations on the natural oscillations of methane laminar diffusion flames under atmospheric pressure and normal gravity conditions have been studied experimentally. Three regimes of laminar diffusion flames, namely, steady, intermittent flickering and continuous flickering have been investigated. Burner configurations such as straight pipe, contoured nozzle and that having an orifice plate at the exit have been considered. All burners have the same area of cross section at the exit and same burner lip thickness. Flame height data has been extracted from direct flame video using MATLAB. Shadowgraph videos have been captured to analyze the plume width characteristics. Results show that, the oscillation characteristics of the orifice burner is significantly different from the other two burners; orifice burner produces a shorter flame and wider thermal plume width in the steady flame regime and the onset of the oscillation/flickering regimes for the orifice burner occurs at a higher fuel flow rate. In the natural flickering regime, the dominating frequency of flame flickering remains within a small range, 12.5 Hz to 15 Hz, for all the burners and for all fuel flow rates. The time-averaged flame length-scale parameters, such as the maximum and the minimum flame heights, increase with respect to the fuel flow rate, however, the difference in the maximum and the minimum flame heights remains almost constant.

  15. Crystal growth methods dedicated to low solubility actinide oxalates

    Energy Technology Data Exchange (ETDEWEB)

    Tamain, C., E-mail: [CEA, Nuclear Energy Division, Marcoule, RadioChemistry & Processes Department, F-30207 Bagnols sur Cèze (France); Arab-Chapelet, B. [CEA, Nuclear Energy Division, Marcoule, RadioChemistry & Processes Department, F-30207 Bagnols sur Cèze (France); Rivenet, M. [University Lille Nord de France, Unité de Catalyse et de Chimie du Solide, UCCS UMR CNRS 8181, ENSCL-USTL, B.P. 90108, F-59652 Villeneuve d’Ascq Cedex (France); Grandjean, S. [CEA, Nuclear Energy Division, Marcoule, RadioChemistry & Processes Department, F-30207 Bagnols sur Cèze (France); Abraham, F. [University Lille Nord de France, Unité de Catalyse et de Chimie du Solide, UCCS UMR CNRS 8181, ENSCL-USTL, B.P. 90108, F-59652 Villeneuve d’Ascq Cedex (France)


    Two novel crystal growth syntheses dedicated to low solubility actinide-oxalate systems and adapted to glove box handling are described. These methods based on the use of precursors of either actinide metal or oxalic acid have been optimized on lanthanide systems (analogue of actinides(III)) and then assessed on real actinide systems. They allow the synthesis of several actinide oxalate single crystals, Am{sub 2}(C{sub 2}O{sub 4}){sub 3}(H{sub 2}O){sub 3}·xH{sub 2}O, Th(C{sub 2}O{sub 4}){sub 2}·6H{sub 2}O, M{sub 2+x}[Pu{sup IV}{sub 2−x}Pu{sup III}{sub x}(C{sub 2}O{sub 4}){sub 5}]·nH{sub 2}O and M{sub 1−x}[Pu{sup III}{sub 1−x}Pu{sup IV}{sub x}(C{sub 2}O{sub 4}){sub 2}·H{sub 2}O]·nH{sub 2}O. It is the first time that these well-known compounds are formed by crystal growth methods, thus enabling direct structural studies on transuranic element systems and acquisition of basic data beyond deductions from isomorphic (or not) lanthanide compounds. Characterizations by X-ray diffraction, UV–visible solid spectroscopy, demonstrate the potentialities of these two crystal growth methods to obtain oxalate compounds. - Graphical abstract: Two new single crystal growth methods dedicated to actinide oxalate compounds. - Highlights: • Use of diester as oxalate precursor for crystal growth of actinide oxalates. • Use of actinide oxide as precursor for crystal growth of actinide oxalates. • Crystal growth of Pu(III) and Am(III) oxalates. • Crystal growth of mixed Pu(III)/Pu(IV) oxalates.

  16. An emergency bioassay method for actinides in urine. (United States)

    Dai, Xiongxin; Kramer-Tremblay, Sheila


    A rapid bioassay method has been developed for the sequential measurements of actinides in human urine samples. The method involves actinide separation from a urine matrix by co-precipitation with hydrous titanium oxide (HTiO), followed by anion exchange and extraction chromatography column purification, and final counting by alpha spectrometry after cerium fluoride micro-precipitation. The minimal detectable activities for the method were determined to be 20 mBq L(-1) or less for plutonium, uranium, americium and curium isotopes, with an 8-h sample turn-around time. Spike tests showed that this method would meet the requirements for actinide bioassay following a radiation emergency.

  17. Review of actinide nitride properties with focus on safety aspects

    Energy Technology Data Exchange (ETDEWEB)

    Albiol, Thierry [CEA Cadarache, St Paul Lez Durance Cedex (France); Arai, Yasuo [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment


    This report provides a review of the potential advantages of using actinide nitrides as fuels and/or targets for nuclear waste transmutation. Then a summary of available properties of actinide nitrides is given. Results from irradiation experiments are reviewed and safety relevant aspects of nitride fuels are discussed, including design basis accidents (transients) and severe (core disruptive) accidents. Anyway, as rather few safety studies are currently available and as many basic physical data are still missing for some actinide nitrides, complementary studies are proposed. (author)

  18. Separating the Minor Actinides Through Advances in Selective Coordination Chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Lumetta, Gregg J.; Braley, Jenifer C.; Sinkov, Sergey I.; Carter, Jennifer C.


    This report describes work conducted at the Pacific Northwest National Laboratory (PNNL) in Fiscal Year (FY) 2012 under the auspices of the Sigma Team for Minor Actinide Separation, funded by the U.S. Department of Energy Office of Nuclear Energy. Researchers at PNNL and Argonne National Laboratory (ANL) are investigating a simplified solvent extraction system for providing a single-step process to separate the minor actinide elements from acidic high-level liquid waste (HLW), including separating the minor actinides from the lanthanide fission products.

  19. Extracting and conducting solids for the separation of actinides

    Energy Technology Data Exchange (ETDEWEB)

    Racimor, David; Picart, Sebastien; Thouvenot, Rene; Bidan, Gerard; Jobelin, Isabelle


    The preparation of both extracting and conducting materials for chromatography is of great interest for the separation of actinides [1,2]. Indeed, most of actinides are relatively stable in aqueous media at different oxidation states and their affinity for extracting group is dependant of this oxidation state. Thus, the possibility to perform an extraction on a solid support at a controlled potential could favour a specific interaction between an actinide at a precise oxidation state and a grafted ligand. This study then concerns the synthesis of conductive materials incorporating complexing poly-oxo-metallates in their structure.

  20. Separations and Actinide Science -- 2005 Roadmap

    Energy Technology Data Exchange (ETDEWEB)


    The Separations and Actinide Science Roadmap presents a vision to establish a separations and actinide science research (SASR) base composed of people, facilities, and collaborations and provides new and innovative nuclear fuel cycle solutions to nuclear technology issues that preclude nuclear proliferation. This enabling science base will play a key role in ensuring that Idaho National Laboratory (INL) achieves its long-term vision of revitalizing nuclear energy by providing needed technologies to ensure our nation's energy sustainability and security. To that end, this roadmap suggests a 10-year journey to build a strong SASR technical capability with a clear mission to support nuclear technology development. If nuclear technology is to be used to satisfy the expected growth in U.S. electrical energy demand, the once-through fuel cycle currently in use should be reconsidered. Although the once-through fuel cycle is cost-effective and uranium is inexpensive, a once-through fuel cycle requires long-term disposal to protect the environment and public from long-lived radioactive species. The lack of a current disposal option (i.e., a licensed repository) has resulted in accumulation of more than 50,000 metric tons of spent nuclear fuel. The process required to transition the current once-through fuel cycle to full-recycle will require considerable time and significant technical advancement. INL's extensive expertise in aqueous separations will be used to develop advanced separations processes. Computational chemistry will be expanded to support development of future processing options. In the intermediate stage of this transition, reprocessing options will be deployed, waste forms with higher loading densities and greater stability will be developed, and transmutation of long-lived fission products will be explored. SASR will support these activities using its actinide science and aqueous separations expertise. In the final stage, full recycle will be

  1. Fuel Sustainability And Actinide Production Of Doping Minor Actinide In Water-Cooled Thorium Reactor (United States)

    Permana, Sidik


    Fuel sustainability of nuclear energy is coming from an optimum fuel utilization of the reactor and fuel breeding program. Fuel cycle option becomes more important for fuel cycle utilization as well as fuel sustainability capability of the reactor. One of the important issues for recycle fuel option is nuclear proliferation resistance issue due to production plutonium. To reduce the proliferation resistance level, some barriers were used such as matrial barrier of nuclear fuel based on isotopic composition of even mass number of plutonium isotope. Analysis on nuclear fuel sustainability and actinide production composition based on water-cooled thorium reactor system has been done and all actinide composition are recycled into the reactor as a basic fuel cycle scheme. Some important parameters are evaluated such as doping composition of minor actinide (MA) and volume ratio of moderator to fuel (MFR). Some feasible parameters of breeding gains have been obtained by additional MA doping and some less moderation to fuel ratios (MFR). The system shows that plutonium and MA are obtained low compositions and it obtains some higher productions of even mass plutonium, which is mainly Pu-238 composition, as a control material to protect plutonium to be used as explosive devices.

  2. Development of Metallic Fuels for Actinide Transmutation

    Energy Technology Data Exchange (ETDEWEB)

    Hayes, Steven Lowe [Idaho National Laboratory; Fielding, Randall Sidney [Idaho National Laboratory; Benson, Michael Timothy [Idaho National Laboratory; Chichester, Heather Jean MacLean [Idaho National Laboratory; Carmack, William Jonathan [Idaho National Laboratory


    Research and development activities on metallic fuels are focused on their potential use for actinide transmutation in future sodium fast reactors. As part of this application, there is also a need for a near zero-loss fabrication process and a desire to demonstrate a multifold increase in burnup potential. The incorporation of Am and Np into the traditional U-20Pu-10Zr metallic fuel alloy was demonstrated in the US during the Integral Fast Reactor Program of the 1980’s and early 1990’s. However, the conventional counter gravity injection casting method performed under vacuum, previously used to fabricate these metallic fuel alloys, was not optimized for mitigating loss of the volatile Am constituent in the casting charge; as a result, approximately 40% of the Am casting charge failed to be incorporated into the as-cast fuel alloys. Fabrication development efforts of the past few years have pursued an optimized bottom-pour casting method to increase utilization of the melted charge to near 100%, and a differential pressure casting approach, performed under an argon overpressure, has been demonstrated to result in essentially no loss of Am due to volatilization during fabrication. In short, a path toward zero-loss fabrication of metallic fuels including minor actinides has been shown to be feasible. Irradiation testing of advanced metallic fuel alloys in the Advanced Test Reactor (ATR) has been underway since 2003. Testing in the ATR is performed inside of cadmium-shrouded positions to remove >99% of the thermal flux incident on the test fuels, resulting in an epi-thermal driven fuel test that is free from gross flux depression and producing an essentially prototypic radial temperature profile inside the fuel rodlets. To date, three irradiation test series (AFC-1,2,3) have been completed. Over 20 different metallic fuel alloys have been tested to burnups as high as 30% with constituent compositions of Pu up to 30%, Am up to 12%, Np up to 10%, and Zr between 10

  3. Aqueous recovery of actinides from aluminum alloys

    Energy Technology Data Exchange (ETDEWEB)

    Gray, J.H.; Chostner, D.F.; Gray, L.W.


    Early in the 1980's, a joint Rocky Flats/Savannah River program was established to recover actinides from scraps and residues generated during Rocky Flats purification operations. The initial program involved pyrochemical treatment of Molten Salt Extraction (MSE) chloride salts and Electrorefining (ER) anode heel metal to form aluminum alloys suitable for aqueous processing at Savannah River. Recently Rocky Flats has expressed interest in expanding the aluminum alloy program to include treatment of chloride salt residues from a modified Molten Salt Extraction process and from the Electrorefining purification operations. Samples of the current aluminum alloy buttons were prepared at Rocky Flats and sent to Savannah River Laboratory for flowsheet development and characterization of the alloys. A summary of the scrub alloy-anode heel alloy program will be presented along with recent results from aqueous dissolution studies of the new aluminum alloys. 2 figs., 4 tabs.

  4. Engineering models for low-NO{sub x} burners

    Energy Technology Data Exchange (ETDEWEB)

    Storm Pedersen, Lars


    The present Ph.D. thesis describes a theoretical investigation of NO formation in pulverised coal combustion and an experimental investigation of co-combustion of straw and pulverised coal. The theoretical work has resulted in a simplified mathematical model of a swirling pulverised coal flame able to predict the NO emission and the burnout of coal. In order to simplify the flow pattern of a confined swirling flame, the residence time distribution (RTD) in a swirling pulverised coal flame was determined. This was done by using the solution of a detailed fluid dynamic mathematical model for a 2.2 MW{sub th} and a 12 MW{sub th} pulverised coal flame. From the mathematical solution the RTD was simulated by tracing a number of fluid particles or inert particles. The RTD in the near burner zone was investigated by use of the mathematical model for the 2.2 MW{sub th} and 12 MW{sub th} flame. Results showed that the gas phase in the near burner zone may be approximated as a CSTR and that the mean residence time increased with particle size. In pulverised coal flames, the most important volatile nitrogen component forming NO{sub x} is HCN. To be able to model the nitrogen chemistry in coal flames it is necessary to have an adequate model for HCN oxidation. In order to develop a model for HCN/NH{sub 3}/NO conversion, a systematic reduction of a detailed chemical kinetic model was performed. Based on the simplification of the flow pattern for a swirling flame and the reduced chemistry developed, a chemical engineering model of pulverised coal flame was established. The objectives were to predict the NO emission, the CO emission, and the burnout of char. The effects of co-firing straw and pulverised coal was investigated in a 2.5 MW{sub th} pilot-scale burner and a 250 MW{sub e} utility boiler. In the 2.5 MW{sub th} trial the straw was chopped and fed separately to the burner, whereas in the full-scale experiment the straw was pre-processed as pellets and pulverised with the

  5. Pyrometallurgical processes for recovery of actinide elements

    Energy Technology Data Exchange (ETDEWEB)

    Battles, J.E.; Laidler, J.J.; McPheeters, C.C.; Miller, W.E.


    A metallic fuel alloy, nominally U-20-Pu-lOZr, is the key element of the Integral Fast Reactor (IFR) fuel cycle. Metallic fuel permits the use of an innovative, simple pyrometallurgical process, known as pyroprocessing, (the subject of this report), which features fused salt electrorefining of the spent fuel. Electrorefining separates the actinide elements from fission products, without producing a separate stream of plutonium. The plutonium-bearing product is contaminated with higher actinides and with a minor amount of rare earth fission products, making it diversion resistant while still suitable as a fuel material in the fast spectrum of the IFR core. The engineering-scale demonstration of this process will be conducted in the refurbished EBR-II Fuel Cycle Facility, which has entered the start-up phase. An additional pyrometallurgical process is under development for extracting transuranic (TRU) elements from Light Water Reactor (LWR) spent fuel in a form suitable for use as a feed to the IFR fuel cycle. Four candidate extraction processes have been investigated and shown to be chemically feasible. The main steps in each process are oxide reduction with calcium or lithium, regeneration of the reductant and recycle of the salt, and separation of the TRU product from the bulk uranium. Two processes, referred to as the lithium and salt transport (calcium reductant) processes, have been selected for engineering-scale demonstration, which is expected to start in late 1993. An integral part of pyroprocessing development is the treatment and packaging of high-level waste materials arising from the operations, along with the qualification of these waste forms for disposal in a geologic repository.

  6. Studies of actinides in a superanoxic fjord

    Energy Technology Data Exchange (ETDEWEB)

    Roos, P.


    Water column and sediment profiles of Pu, Am, Th and U have been obtained in the superanoxic Framvaren fjord, southern Norway. The concentration of bomb test fallout Pu, Am as well as `dissolved` Th in the bottom water are the highest recorded in the marine environment. The behaviour of the actinides in the anoxic water mass is to a large extent governed by the behaviour of the colloidal material. Ultrafiltration reveals that 40-60% of the actinides are associated to the large colloids, surprisingly this is valid also for U. The sediment acts as a source for Pu, Am, and Th to the water column but primarily as a sink for U. The remobilization of Pu, Am and Th is evident from the water column profiles which have similar diffusion shape profiles as other constituents originating from the sediments. The vertical eddy diffusion coefficient calculated from the Pu profile is in the same order of magnitude as reported from the H{sub 2}S profile. Decreased bottom water concentrations (but a constant water column inventory) between 1989 and 1995 as well as pore water Pu concentrations nearly identical to the overlaying bottom water indicates that the present Pu flux from the sediments are low. Contrary to Pu and Am, the water column Th inventory ({sup 232}Th and {sup 230}Th) continues to increase. The flux of {sup 232}Th from the sediments was determined from changes in water column inventory between 1989 and 1995 and from a pore water profile to be in the order of 2-8 Bq/m{sup 2}/y. 208 refs.

  7. Radiochemical studies of neutron deficient actinide isotopes

    Energy Technology Data Exchange (ETDEWEB)

    Williams, K.E.


    The production of neutron deficient actinide isotopes in heavy ion reactions was studied using alpha, gamma, x-ray, and spontaneous fission detection systems. A new isotope of berkelium, /sup 242/Bk, was produced with a cross-section of approximately 10 in reactions of boron on uranium and nitrogen on thorium. It decays by electron capture with a half-life of 7.0 +- 1.3 minutes. The alpha-branching ratio for this isotope is less than 1% and the spontaneous fission ratio is less than 0.03%. Studies of (Heavy Ion, pxn) and (Heavy Ion, ..cap alpha..xn) transfer reactions in comparison with (Heavy ion, xn) compound nucleus reactions revealed transfer reaction cross-sections equal to or greater than the compound nucleus yields. The data show that in some cases the yield of an isotope produced via a (H.I.,pxn) or (H.I.,..cap alpha..xn) reaction may be higher than its production via an xn compound nucleus reaction. These results have dire consequences for proponents of the ''Z/sub 1/ + Z/sub 2/ = Z/sub 1+2/'' philosophy. It is no longer acceptable to assume that (H.I.,pxn) and (H.I.,..cap alpha..xn) product yields are of no consequence when studying compound nucleus reactions. No evidence for spontaneous fission decay of /sup 228/Pu, /sup 230/Pu, /sup 232/Cm, or /sup 238/Cf was observed indicating that strictly empirical extrapolations of spontaneous fission half-life data is inadequate for predictions of half-lives for unknown neutron deficient actinide isotopes.

  8. The chemistry of the actinide elements, Volume II

    Energy Technology Data Exchange (ETDEWEB)

    Katz, J.J.; Seaborg, G.T.; Morss, L.R.


    The Chemistry of the Actinide Elements is an exposition of the chemistry and related properties of the 5f series of elements: actinium, thorium, protactinium, uranium and the first eleven. This second edition has been completely restructured and rewritten to incorporate current research in all areas of actinide chemistry and chemical physics. The descriptions of each element include accounts of their history, separation, metallurgy, solid-state chemistry, solution chemistry, thermo-dynamics and kinetics. Additionally, separate chapters on spectroscopy, magnetochemistry, thermodynamics, solids, the metallic state, complex ions and organometallic compounds emphasize the comparative chemistry and unique properties of the actinide series of elements. Comprehensive lists of properties of all actinide compounds and ions in solution are given, and there are special sections on such topics as biochemistry, superconductivity, radioisotope safety, and waste management, as well as discussion of the transactinides and future elements.

  9. Chemistry of the actinide elements. Vol. 1, 2nd Ed

    Energy Technology Data Exchange (ETDEWEB)

    Katz, J.J.; Morss, L.R.; Seaborg, L.R. (eds.)


    The Chemistry of the Actinide Elements is a comprehensive, contemporary and authoritative exposition of the chemistry and related properties of the 5f series of elements: actinium, thorium, protactinium, uranium and the first eleven transuranium elements. This second edition has been completely restructured and rewritten to incorporate current research in all areas of actinide chemistry and chemical physics. The descriptions of each element include accounts of their history, separation, metallurgy, solid-state chemistry, solution chemistry, thermodynamics and kinetics. Additionally, separate chapters on spectroscopy, magnetochemistry, thermodynamics, solids, the metallic state, complex ions and organometallic compounds emphasize the comparative chemistry and unique properties of the actinide series of elements. Comprehensive lists of properties of all actinide compounds and ions in solution are given, and there are special sections on such topics as biochemistry, superconductivity, radioisotope safety, and waste management, as well as discussion of the transactinides and future elements.

  10. The chemistry of the actinide elements. Volume I

    Energy Technology Data Exchange (ETDEWEB)

    Katz, J.J.; Seaborg, G.T.; Morss, L.R.


    The Chemistry of the Actinide Elements is a comprehensive, contemporary and authoritative exposition of the chemistry and related properties of the 5f series of elements: actinium, thorium, protactinium, uranium and the first eleven. This second edition has been completely restructured and rewritten to incorporate current research in all areas of actinide chemistry and chemical physics. The descriptions of each element include accounts of their history, separation, metallurgy, solid-state chemistry, solution chemistry, thermo-dynamics and kinetics. Additionally, separate chapters on spectroscopy, magnetochemistry, thermodynamics, solids, the metallic state, complex ions and organometallic compounds emphasize the comparative chemistry and unique properties of the actinide series of elements. Comprehensive lists of properties of all actinide compounds and ions in solution are given, and there are special sections on such topics as biochemistry, superconductivity, radioisotope safety, and waste management, as well as discussion of the transactinides and future elements.

  11. Advanced techniques for actinide spectroscopy (ATAS 2012). Abstract book

    Energy Technology Data Exchange (ETDEWEB)

    Foerstendorf, Harald; Mueller, Katharina; Steudtner, Robin (eds.)


    The abstract book of the International workshop on advanced techniques for actinide spectroscopy (ATAS 2012) include contributions concerning the following issues: environmental applications, NMR spectroscopy, vibrational spectroscopy, X-ray spectroscopy and theory, technical application: separation processes, emission spectroscopy.

  12. Valence instabilities as a possible source of actinide system inconsistencies

    Energy Technology Data Exchange (ETDEWEB)

    Sandenaw, T.A.


    The presence of a mixed-valence state in light actinides appears evident from the crystal structures of certain U, Np, and Pu phases. As supporting evidence, the physical property response of these actinide elements (and some of their alloys) is compared with that of rare-earth metallic compounds known to have an unstable valence. Impurities may stabilize an intermediate (different) valence state locally in rare-earth compounds in the presence of the valence state of the bulk phase. Impurity elements from different periodic table groupings may likewise stabilize different intermediate valence states in light actinide elements, thus contributing to inconsistencies in results reported by different experimentalists. Any model (theory) advanced for explaining the physical property behavior of U, Np, and Pu may also require consideration of a configurational limit. A phenomenological connection could exist between a martensitic transformation and the fluctuation temperature in both rare earth and actinide systems.

  13. Actinide targets for the synthesis of super-heavy elements

    Energy Technology Data Exchange (ETDEWEB)

    Roberto, J.B., E-mail:; Alexander, C.W.; Boll, R.A.; Burns, J.D.; Ezold, J.G.; Felker, L.K.; Hogle, S.L.; Rykaczewski, K.P.


    Since 2000, six new super-heavy elements with atomic numbers 113 through 118 have been synthesized in hot fusion reactions of {sup 48}Ca beams on actinide targets. These target materials, including {sup 242}Pu, {sup 244}Pu, {sup 243}Am, {sup 245}Cm, {sup 248}Cm, {sup 249}Cf, and {sup 249}Bk, are available in very limited quantities and require specialized production and processing facilities resident in only a few research centers worldwide. This report describes the production and chemical processing of heavy actinide materials for super-heavy element research, current availabilities of these materials, and related target fabrication techniques. The impact of actinide materials in super-heavy element discovery is reviewed, and strategies for enhancing the production of rare actinides including {sup 249}Bk, {sup 251}Cf, and {sup 254}Es are described.

  14. Formation of actinides in irradiated HTGR fuel elements

    Energy Technology Data Exchange (ETDEWEB)

    dos Santos, A. M.


    Actinide nuclide concentrations of 11 spent AVR fuel elements were determined experimentally. The burnup of the spheres varied in the range between 10% and 100% fifa, the Th : U ratio was 5 : 1. The separation procedures for an actinide isolation were tested with highly irradiated ThO/sub 2/. Separation and decontamination factors are presented. Build-up of /sup 232/U was discussed. The AVR breeding rate was ascertained to be 0.5. The hazard potential of high activity waste was calculated. Actinide recovery factors were proposed in order to reduce the hazard potential of the waste by an actinide removal under consideration of the reprocessing technology which is available presently.

  15. Oil fired boiler/solar tank- and natural gas burner/solar tank-units

    DEFF Research Database (Denmark)

    Furbo, Simon; Vejen, Niels Kristian; Frederiksen, Karsten Vinkler


    During the last few years new units consisting of a solar tank and either an oil fired boiler or a natural gas burner have been introduced on the Danish market. Three different marketed units - two based on a natural gas burner and one based on an oil fired boiler - have been tested in a heat...

  16. Thin extractive membrane for monitoring actinides in aqueous streams

    Energy Technology Data Exchange (ETDEWEB)

    Chavan, Vivek [Radiochemistry Division, Trombay, Mumbai 400 085 (India); Paul, Sumana [Fuel Chemistry Division, Trombay, Mumbai 400 085 (India); Pandey, Ashok K., E-mail: [Radiochemistry Division, Trombay, Mumbai 400 085 (India); Kalsi, P.C.; Goswami, A. [Radiochemistry Division, Trombay, Mumbai 400 085 (India)


    Highlights: • Thin polymer inclusion membrane has been developed for selective actinide sorption. • Actinide sorption in membrane is dependent on acidity and oxidation states. • A scheme for selective preconcentration of target actinide has been developed. • Quantification of actinide in membrane is possible by SSNTD or α-spectrometry. • This membrane was used for assay of Pu in acidic waste and urine -- Abstract: Alpha spectrometry and solid state nuclear track detectors (SSNTDs) are used for monitoring ultra-trace amount of alpha emitting actinides in different aqueous streams. However, these techniques have limitations i.e. alpha spectrometry requires a preconcentration step and SSNTDs are not chemically selective. Therefore, a thin polymer inclusion membrane (PIM) supported on silanized glass was developed for preconcentraion and determination of ultra-trace concentration of actinides by α-spectrometry and SSNTDs. PIMs were formed by spin coating on hydrophobic glass slide or solvent casting to form thin and self-supported membranes, respectively. Sorption experiments indicated that uptakes of actinides in the PIM were highly dependent on acidity of solution i.e. Am(III) sorbed up to 0.1 mol L{sup −1} HNO{sub 3}, U(VI) up to 0.5 mol L{sup −1} HNO{sub 3} and Pu(IV) from HNO{sub 3} concentration as high as 4 mol L{sup −1}. A scheme was developed for selective sorption of target actinide in the PIM by adjusting acidity and oxidation state of actinide. The actinides sorbed in PIMs were quantified by alpha spectrometry and SSNTDs. For SSNTDs, neutron induced fission-fragment tracks and α-particle tracks were registered in Garware polyester and CR-39 for quantifications of natural uranium and α-emitting actinides ({sup 241}Am/{sup 239}Pu/{sup 233}U), respectively. Finally, the membranes were tested to quantify Pu in 4 mol L{sup −1} HNO{sub 3} solutions and synthetic urine samples.

  17. Numerical investigation of a novel burner to combust anode exhaust gases of SOFC stacks

    Directory of Open Access Journals (Sweden)

    Pianko-Oprych Paulina


    Full Text Available The aim of the present study was a numerical investigation of the efficiency of the combustion process of a novel concept burner under different operating conditions. The design of the burner was a part of the development process of a complete SOFC based system and a challenging combination of technical requirements to be fulfilled. A Computational Fluid Dynamics model of a non-premixed burner was used to simulate combustion of exhaust gases from the anode region of Solid Oxide Fuel Cell stacks. The species concentrations of the exhaust gases were compared with experimental data and a satisfactory agreement of the conversion of hydrocarbons was obtained. This validates the numerical methodology and also proves applicability of the developed approach that quantitatively characterized the interaction between the exhaust gases and burner geometry for proper combustion modelling. Thus, the proposed CFD approach can be safely used for further numerical optimisation of the burner design.

  18. Laboratory measurements in a turbulent, swirling flow. [measurement of soot inside a flame-tube burner (United States)

    Hoult, D. P.


    Measurements of soot inside a flame-tube burner using a special water-flushed probe are discussed. The soot is measured at a series of points at each burner, and upon occasion gaseous constitutents NO, CO, hydrocarbons, etc., were also measured. Four geometries of flame-tube burners were studied, as well as a variety of different fuels. The role of upstream geometry on the downstream pollutant formation was studied. It was found that the amount of soot formed in particularly sensitive to how aerodynamically clean the configuration of the burner is upstream of the injector swirl vanes. The effect of pressure on soot formation was also studied. It was found that beyond a certain Reynolds number, the peak amount of soot formed in the burner is constant.

  19. Development of the Radiation Stabilized Distributed Flux Burner - Phase III Final Report

    Energy Technology Data Exchange (ETDEWEB)

    J. D. Sullivan; A. Webb


    The development and demonstration of the Radiation Stabilized Burner (RSB) was completed as a project funded by the US Department of Energy Office of Industrial Technologies. The technical goals of the project were to demonstrate burner performance that would meet or exceed emissions targets of 9 ppm NOx, 50 ppm CO, and 9 ppm unburned hydrocarbons (UHC), with all values being corrected to 3 percent stack oxygen, and incorporate the burner design into a new industrial boiler configuration that would achieve ultra-low emissions while maintaining or improving thermal efficiency, operating costs, and maintenance costs relative to current generation 30 ppm low NOx burner installations. Both the ultra-low NOx RSB and the RSB boiler-burner package are now commercially available.

  20. Workshop on environmental research for actinide elements

    Energy Technology Data Exchange (ETDEWEB)

    Watters, R.L. (ed.)


    The discussions in this fifth workshop were directed to the advances which have been made in the environmental chemistry of plutonium and to the feasibility and worth of developing environmental transport models which might serve as predictive tools for long term behavior and as guides for future research needs. Two plutonium models of the soil/plant pathway were presented for critique and as examples of possible approaches. Reports of the following four panels are presented in this proceedings: model development; marine; terrestrial and freshwater/groundwater.

  1. Smart FPA's: are they worth the effort? (United States)

    Leijtens, Johan; Theuwissen, Albert; Magnan, Pierre


    CMOS APS technology allows including signal processing in the sensor array. Inclusion of functionality however will come at a cost both financially and in the field of limited applicability. Based on two real world examples (micro digital sunsensor core and lightning flash detector for Meteosat Third Generation (MTG)) it will be demonstrated that large system gains can be obtained by devising smart focal planes. Therefore it is felt that the advantages outweigh the disadvantages for some applications, making it worth to spend the effort on system integration.

  2. Heterogeneous sodium fast reactor designed for transmuting minor actinide waste isotopes into plutonium fuel (United States)

    Bays, Samuel Eugene


    In the past several years there has been a renewed interest in sodium fast reactor (SFR) technology for the purpose of destroying transuranic waste (TRU) produced by light water reactors (LWR). The utility of SFRs as waste burners is due to the fact that higher neutron energies allow all of the actinides, including the minor actinides (MA), to contribute to fission. It is well understood that many of the design issues of LWR spent nuclear fuel (SNF) disposal in a geologic repository are linked to MAs. Because the probability of fission for essentially all the "non-fissile" MAs is nearly zero at low neutron energies, these isotopes act as a neutron capture sink in most thermal reactor systems. Furthermore, because most of the isotopes produced by these capture reactions are also non-fissile, they too are neutron sinks in most thermal reactor systems. Conversely, with high neutron energies, the MAs can produce neutrons by fast fission. Additionally, capture reactions transmute the MAs into mostly plutonium isotopes, which can fission more readily at any energy. The transmutation of non-fissile into fissile atoms is the premise of the plutonium breeder reactor. In a breeder reactor, not only does the non-fissile "fertile" U-238 atom contribute fast fission neutrons, but also transmutes into fissile Pu-239. The fissile value of the plutonium produced by MA transmutation can only be realized in fast neutron spectra. This is due to the fact that the predominate isotope produced by MA transmutation, Pu-238, is itself not fissile. However, the Pu-238 fission cross section is significantly larger than the original transmutation parent, predominately: Np-237 and Am-241, in the fast energy range. Also, Pu-238's fission cross section and fission-to-capture ratio is almost as high as that of fissile Pu-239 in the fast neutron spectrum. It is also important to note that a neutron absorption in Pu-238, that does not cause fission, will instead produce fissile Pu-239. Given this

  3. A Spectrum is Worth a Thousand Pictures (United States)

    Gelderman, Richard F.


    A wise astronomer once pointed out that if a picture is worth a thousand words, then a spectrum is worth a thousand pictures. Unfortunately, spectra are rarely emphasized in the introductory astronomy courses and few students exit such a course with any meaningful understanding or appreciation of spectroscopy. Part of the problem is lack of background knowledge; the typical introductory astronomy student has little experience with spectroscopy or atomic physics. Another issue is that spectra are not pretty pictures and are not intuitively understandable. We present and discuss a series of “minds-on” exercises and activities built into a college-level “stars, galaxies, and cosmology” intro astronomy course. The lessons are structured to help students improve their ability to recognize patterns and improve their ability to really see the details in front of them. Another goal is for students to realize there is “more than meets the eye” to learn how to discover “hidden” diagnostics, such as different sources of light their eyes see as white light. A curriculum that emphasizes spectroscopy also provides the opportunity to stress the story of the “Harvard Women,” a tale that bridges gender gaps and often humanizes scientists in the eyes of non-science majors. Finally, with a solid foundation in spectroscopy, students are better prepared to understand exciting topics such as Hubble’s Law and the importance of primordial nucleosynthesis.

  4. LIBS Spectral Data for a Mixed Actinide Fuel Pellet Containing Uranium, Plutonium, Neptunium and Americium

    Energy Technology Data Exchange (ETDEWEB)

    Judge, Elizabeth J. [Los Alamos National Laboratory; Berg, John M. [Los Alamos National Laboratory; Le, Loan A. [Los Alamos National Laboratory; Lopez, Leon N. [Los Alamos National Laboratory; Barefield, James E. [Los Alamos National Laboratory


    Laser-induced breakdown spectroscopy (LIBS) was used to analyze a mixed actinide fuel pellet containing 75% UO{sub 2}/20% PuO{sub 2}/3% AmO{sub 2}/2% NpO{sub 2}. The preliminary data shown here is the first report of LIBS analysis of a mixed actinide fuel pellet, to the authors knowledge. The LIBS spectral data was acquired in a plutonium facility at Los Alamos National Laboratory where the sample was contained within a glove box. The initial installation of the glove box was not intended for complete ultraviolet (UV), visible (VIS) and near infrared (NIR) transmission, therefore the LIBS spectrum is truncated in the UV and NIR regions due to the optical transmission of the window port and filters that were installed. The optical collection of the emission from the LIBS plasma will be optimized in the future. However, the preliminary LIBS data acquired is worth reporting due to the uniqueness of the sample and spectral data. The analysis of several actinides in the presence of each other is an important feature of this analysis since traditional methods must chemically separate uranium, plutonium, neptunium, and americium prior to analysis. Due to the historic nature of the sample fuel pellet analyzed, the provided sample composition of 75% UO{sub 2}/20% PuO{sub 2}/3% AmO{sub 2}/2% NpO{sub 2} cannot be confirm without further analytical processing. Uranium, plutonium, and americium emission lines were abundant and easily assigned while neptunium was more difficult to identify. There may be several reasons for this observation, other than knowing the exact sample composition of the fuel pellet. First, the atomic emission wavelength resources for neptunium are limited and such techniques as hollow cathode discharge lamp have different dynamics than the plasma used in LIBS which results in different emission spectra. Secondly, due to the complex sample of four actinide elements, which all have very dense electronic energy levels, there may be reactions and

  5. Attachment styles and contingencies of self-worth. (United States)

    Park, Lora E; Crocker, Jennifer; Mickelson, Kristin D


    Previous research on attachment theory has focused on mean differences in level of self-esteem among people with different attachment styles. The present study examines the associations between attachment styles and different bases of self-esteem, or contingencies of self-worth, among a sample of 795 college students. Results showed that attachment security was related to basing self-worth on family support. Both the preoccupied attachment style and fearful attachment style were related to basing self-worth on physical attractiveness. The dismissing attachment style was related to basing self-worth less on others' approval, family support, and God's love.

  6. A small porous-plug burner for studies of combustion chemistry and soot formation. (United States)

    Campbell, M F; Schrader, P E; Catalano, A L; Johansson, K O; Bohlin, G A; Richards-Henderson, N K; Kliewer, C J; Michelsen, H A


    We have developed and built a small porous-plug burner based on the original McKenna burner design. The new burner generates a laminar premixed flat flame for use in studies of combustion chemistry and soot formation. The size is particularly relevant for space-constrained, synchrotron-based X-ray diagnostics. In this paper, we present details of the design, construction, operation, and supporting infrastructure for this burner, including engineering attributes that enable its small size. We also present data for charactering the flames produced by this burner. These data include temperature profiles for three premixed sooting ethylene/air flames (equivalence ratios of 1.5, 1.8, and 2.1); temperatures were recorded using direct one-dimensional coherent Raman imaging. We include calculated temperature profiles, and, for one of these ethylene/air flames, we show the carbon and hydrogen content of heavy hydrocarbon species measured using an aerosol mass spectrometer coupled with vacuum ultraviolet photoionization (VUV-AMS) and soot-volume-fraction measurements obtained using laser-induced incandescence. In addition, we provide calculated mole-fraction profiles of selected gas-phase species and characteristic profiles for seven mass peaks from AMS measurements. Using these experimental and calculated results, we discuss the differences between standard McKenna burners and the new miniature porous-plug burner introduced here.

  7. Actinides AMS at CIRCE in Caserta (Italy) (United States)

    De Cesare, M.; Gialanella, L.; Rogalla, D.; Petraglia, A.; Guan, Y.; De Cesare, N.; D'Onofrio, A.; Quinto, F.; Roca, V.; Sabbarese, C.; Terrasi, F.


    The operation of Nuclear Power Plants and atmospheric tests of nuclear weapons performed in the past, together with production, transport and reprocessing of nuclear fuel, lead to the release into the environment of a wide range of radioactive nuclides, such as uranium, plutonium, fission and activation products. These nuclides are present in the environment at ultra trace levels. Their detection requires sensitive techniques like AMS (Accelerator Mass Spectrometry). In order to perform isotopic ratio measurements of the longer-lived actinides, e.g., of 236U relative to the primary 238U and various Pu isotopes relative to 239Pu, an upgrade of the CIRCE accelerator (Center for Isotopic Research on Cultural and Environmental Heritage) in Caserta, Italy, is underway. In this paper we report on the results of simulations aiming to define the best ion optics and to understand the origin of possible measurement background. The design of a high resolution TOF- E (Time of Flight-Energy) detector system is described, which will be used to identify the rare isotopes among interfering background signals.

  8. Development of KB-200. Kawasaki digital burner control system

    Energy Technology Data Exchange (ETDEWEB)

    Miyayama, Toshio; Hoshino, Norihiko; Nakamori, Hideki; Wasada, Norihiko


    Control equipments of a thermal generation plant are making progress in getting higher in level, complex and integrated digitalization. Concerning the digital control technology, as micro-electronics technology progresses, programmable controller which excels in flexibility and expandability of software is now widely popularized. Recently, however, higher level of reliability, maintenance ability and safety are required as in the discovery of abnormality and fact-finding or the protection of human error. To respond to these, Kawasaki Heavy Industries, in cooperationwith Fuji Electric Co., has developed a distributed digital burner control unit on the basis of the recent programmable controller. This report outlines the system control functions, construction, measures for high reliability, controllers, and system maintenance, etc.. (8 figs, 2 tabs, 2 refs)

  9. Deposition stress effects on thermal barrier coating burner rig life (United States)

    Watson, J. W.; Levine, S. R.


    A study of the effect of plasma spray processing parameters on the life of a two layer thermal barrier coating was conducted. The ceramic layer was plasma sprayed at plasma arc currents of 900 and 600 amps onto uncooled tubes, cooled tubes, and solid bars of Waspalloy in a lathe with 1 or 8 passes of the plasma gun. These processing changes affected the residual stress state of the coating. When the specimens were tested in a Mach 0.3 cyclic burner rig at 1130 deg C, a wide range of coating lives resulted. Processing factors which reduced the residual stress state in the coating, such as reduced plasma temperature and increased heat dissipation, significantly increased coating life.

  10. Pulverized straw combustion in a low-NOx multifuel burner

    DEFF Research Database (Denmark)

    Mandø, Matthias; Rosendahl, Lasse; Yin, Chungen


    , the influence of inlet boundary conditions and the effect of particles on the carrier phase turbulence. It is concluded that straw combustion is associated with a significantly longer flame and smaller recirculation zones compared to coal combustion for the present air flow specifications. The particle size......A CFD simulation of pulverized coal and straw combustion using a commercial multifuel burner have been undertaken to examine the difference in combustion characteristics. Focus has also been directed to development of the modeling technique to deal with larger non-spherical straw particles...... and to determine the relative importance of different modeling choices for straw combustion. Investigated modeling choices encompass the particle size and shape distribution, the modification of particle motion and heating due to the departure from the spherical ideal, the devolatilization rate of straw...

  11. Exposure calculation code module for reactor core analysis: BURNER

    Energy Technology Data Exchange (ETDEWEB)

    Vondy, D.R.; Cunningham, G.W.


    The code module BURNER for nuclear reactor exposure calculations is presented. The computer requirements are shown, as are the reference data and interface data file requirements, and the programmed equations and procedure of calculation are described. The operating history of a reactor is followed over the period between solutions of the space, energy neutronics problem. The end-of-period nuclide concentrations are determined given the necessary information. A steady state, continuous fueling model is treated in addition to the usual fixed fuel model. The control options provide flexibility to select among an unusually wide variety of programmed procedures. The code also provides user option to make a number of auxiliary calculations and print such information as the local gamma source, cumulative exposure, and a fine scale power density distribution in a selected zone. The code is used locally in a system for computation which contains the VENTURE diffusion theory neutronics code and other modules.

  12. Combustion of solid alternative fuels in the cement kiln burner

    DEFF Research Database (Denmark)

    Nørskov, Linda Kaare

    stability, and process efficiency. Alternative fuel substitution in the calciner unit has reached close to 100% at many cement plants and to further increase the use of alternative fuels rotary kiln substitution must be enhanced. At present, limited systematic knowledge of the alternative fuel combustion...... properties and the influence on the flame formation is available. In this project a scientific approach to increase the fundamental understanding of alternative fuel conversion in the rotary kiln burner is employed through literature studies, experimental combustion characterisation studies, combustion...... modelling, data collection and observations at an industrial cement plant firing alternative fuels. Alternative fuels may differ from conventional fossil fuels in combustion behaviour through differences in physical and chemical properties and reaction kinetics. Often solid alternative fuels are available...

  13. A quantitative study of acoustic growth rates in a characterized Rijke burner with particle combustion (United States)

    Newbold, Brian Russell


    The acoustic growth rate, frequency, and limiting amplitude of a characterized Rijke burner were quantitatively measured during the combustion of aluminum and zirconium carbide particles, which are common solid propellant additives. Extremely narrow size distributions of aluminum particles with mean diameters of 9.2, 19.0, 35.6, and 68.7 μm were tested at mass loadings up to 3% for frequencies of 800 and 1200 Hz. Large aluminum particles were ignited in the C3H8/O2 flame of a welding nozzle, mounted flush with the burner's flat, C3H8/O 2/N2 flame. Testing provided no conclusive evidence of distributed particle combustion affecting the acoustic driving in the Rijke burner. In solid propellant rockets, the distributed combustion of aluminum particles far from the propellant surface may contribute to pressure oscillations caused by acoustic combustion instability. The Rijke burner was developed as an experimental platform to investigate the phenomenon. Research into the transient acoustic response of Rijke burners is almost nonexistent; consequently, the current burner's acoustic response was quantified as a function of gas flow rate, gas composition, geometry, and burner orientation for two frequencies. Acoustic growth rate trends were explained in terms of the pulsing flame's heat release and the flame's position relative to the optimal acoustic driving point. Variations in gas flow rate, flame temperature, geometry, and exhaust temperature profile could affect a 300 s-1 change in acoustic growth rate for the conditions tested. Frequency remained approximately constant, except for acoustic mode shifts which occurred due to geometry alterations or changing gas temperatures in the burner's hot section. The Rijke burner's acoustic response was not significantly altered by the installation of the welding nozzle with its gas mixture operated near stoichiometric or fuel rich. The radial and axial temperature profiles of the gas temperatures in the burner's hot section

  14. Premixed burner experiments: Geometry, mixing, and flame structure issues

    Energy Technology Data Exchange (ETDEWEB)

    Gupta, A.K.; Lewis, M.J.; Gupta, M. [Univ of Maryland, College Park, MD (United States)] [and others


    This research program is exploring techniques for improved fuel-air mixing, with the aim of achieving combustor operations up to stoichiometric conditions with minimal NO x and maximum efficiency. The experimental studies involve the use of a double-concentric natural gas burner that is operable in either premixed or non-premixed modes, and the system allows systematic variation of equivalence ratio, swirl strength shear length region and flow momentum in each annulus. Flame structures formed with various combinations of swirl strengths, flow throughput and equivalence ratios in premixed mode show the significant impact of swirl flow distribution on flame structure emanating from the mixedness. This impact on flame structure is expected to have a pronounced effect on the heat release rate and the emission of NO{sub x}. Thus, swirler design and configuration remains a key factor in the quest for completely optimized combustion. Parallel numerical studies of the flow and combustion phenomena were carried out, using the RSM and thek-{epsilon} turbulence models. These results have not only indicated the strengths and limitations of CFD in performance and pollutants emission predictions, but have provided guidelines on the size and strength of the recirculation produced and the spatio-temporal structure of the combustion flowfield. The first stage of parametric studies on geometry and operational parameters at Morgan State University have culminated in the completion of a one-dimensional flow code that is integrated with a solid, virtual model of the existing premixed burner. This coupling will provide the unique opportunity to study the impact of geometry on the flowfield and vice-versa, with particular emphasis on concurrent design optimization.

  15. Development of the Chalmers Grouped Actinide Extraction Process

    Directory of Open Access Journals (Sweden)

    Halleröd Jenny


    Full Text Available Several solvents for Grouped ActiNide EXtraction (GANEX processes have been investigated at Chalmers University of Technology in recent years. Four different GANEX solvents; cyclo-GANEX (CyMe4- -BTBP, 30 vol.% tri-butyl phosphate (TBP and cyclohexanone, DEHBA-GANEX (CyMe4-BTBP, 20 vol.% N,N-di-2(ethylhexyl butyramide (DEHBA and cyclohexanone, hexanol-GANEX (CyMe4-BTBP, 30 vol.% TBP and hexanol and FS-13-GANEX (CyMe4-BTBP, 30 vol.% TBP and phenyl trifluoromethyl sulfone (FS-13 have been studied and the results are discussed and compared in this work. The cyclohexanone based solvents show fast and high extraction of the actinides but a somewhat poor diluent stability in contact with the acidic aqueous phase. FS-13-GANEX display high separation factors between the actinides and lanthanides and a good radiolytic and hydrolytic stability. However, the distribution ratios of the actinides are lower, compared to the cyclohexanone based solvents. The hexanol-GANEX is a cheap solvent system using a rather stable diluent but the actinide extraction is, however, comparatively low.

  16. A Summary of Actinide Enrichment Technologies and Capability Gaps

    Energy Technology Data Exchange (ETDEWEB)

    Patton, Bradley D. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Robinson, Sharon M. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)


    The evaluation performed in this study indicates that a new program is needed to efficiently provide a national actinide radioisotope enrichment capability to produce milligram-to-gram quantities of unique materials for user communities. This program should leverage past actinide enrichment, the recent advances in stable isotope enrichment, and assessments of the future requirements to cost effectively develop this capability while establishing an experience base for a new generation of researchers in this vital area. Preliminary evaluations indicate that an electromagnetic isotope separation (EMIS) device would have the capability to meet the future needs of the user community for enriched actinides. The EMIS technology could be potentially coupled with other enrichment technologies, such as irradiation, as pre-enrichment and/or post-enrichment systems to increase the throughput, reduce losses of material, and/or reduce operational costs of the base EMIS system. Past actinide enrichment experience and advances in the EMIS technology applied in stable isotope separations should be leveraged with this new evaluation information to assist in the establishment of a domestic actinide radioisotope enrichment capability.

  17. Hydrophilic actinide complexation studied by solvent extraction radiotracer technique

    Energy Technology Data Exchange (ETDEWEB)

    Rydberg, J. [Chalmers Univ. of Technology, Goeteborg (Sweden). Dept. of Nuclear Chemistry and Radiochemistry Consultant Group, Vaestra Froelunda (Sweden)


    Actinide migration in the ground water is enhanced by the formation of water soluble complexes. It is essential to the risk analysis of a wet repository to know the concentration of central atoms and the ligands in the ground water, and the stability of complexes formed between them. Because the chemical behavior at trace concentrations often differ from that at macro concentrations, it is important to know the chemical behavior of actinides at trace concentrations in ground water. One method used for such investigations is the solvent extraction radiotracer (SXRT) technique. This report describes the SXRT technique in some detail. A particular reason for this analysis is the claim that complex formation constants obtained by SXRT are less reliable than results obtained by other techniques. It is true that several difficulties are encountered in the application of SXRT technique to actinide solution, such as redox instability, hydrophilic complexation by side reactions and sorption, but it is also shown that a careful application of the SXRT technique yields results as reliable as by any other technique. The report contains a literature survey on solvent extraction studies of actinide complexes formed in aqueous solutions, particularly by using the organic reagent thenoyltrifluoroacetone (TTA) dissolved in benzene or chloroform. Hydrolysis constants obtained by solvent extraction are listed as well as all actinide complexes studied by SX with inorganic and organic ligands. 116 refs, 11 tabs.

  18. Dependence of control rod worth on fuel burnup

    Energy Technology Data Exchange (ETDEWEB)

    Savva, P., E-mail: savvapan@ipta.demokritos.g [NCSR ' DEMOKRITOS' , PoB 60228, 15310 Aghia Paraskevi (Greece); Varvayanni, M., E-mail: melina@ipta.demokritos.g [NCSR ' DEMOKRITOS' , PoB 60228, 15310 Aghia Paraskevi (Greece); Catsaros, N., E-mail: nicos@ipta.demokritos.g [NCSR ' DEMOKRITOS' , PoB 60228, 15310 Aghia Paraskevi (Greece)


    Research highlights: Diffusion and MC calculations for rod worth dependence on burnup and Xe in reactors. One-step rod withdrawal/insertion are used for rod worth estimation. The study showed that when Xe is present the rods worth is significantly reduced. Rod worth variation with burnup depends on rod position in core. Rod worth obtained with MC code is higher than that obtained from deterministic. - Abstract: One important parameter in the design and the analysis of a nuclear reactor core is the reactivity worth of the control rods, i.e. their efficiency to absorb excess reactivity. The control rod worth is affected by parameters such as the fuel burnup in the rod vicinity, the Xe concentration in the core, the operational time of the rod and its position in the core. In the present work, two different computational approaches, a deterministic and a stochastic one, were used for the determination of the rods worth dependence on the fuel burnup level and the Xe concentration level in a conceptual, symmetric reactor core, based on the MTR fuel assemblies used in the Greek Research Reactor (GRR-1). For the deterministic approach the neutronics code system composed by the SCALE modules NITAWL and XSDRN and the diffusion code CITATION was used, while for the stochastic one the Monte Carlo code TRIPOLI was applied. The study showed that when Xe is present in the core, the rods worth is significantly reduced, while the rod worth variation with increasing burnup depends on the rods position in the core grid. The rod worth obtained with the use of the Monte Carlo code is higher than the one obtained from the deterministic code.

  19. Reducing Actinide Production Using Inert Matrix Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Deinert, Mark [Colorado School of Mines, Golden, CO (United States)


    The environmental and geopolitical problems that surround nuclear power stem largely from the longlived transuranic isotopes of Am, Cm, Np and Pu that are contained in spent nuclear fuel. New methods for transmuting these elements into more benign forms are needed. Current research efforts focus largely on the development of fast burner reactors, because it has been shown that they could dramatically reduce the accumulation of transuranics. However, despite five decades of effort, fast reactors have yet to achieve industrial viability. A critical limitation to this, and other such strategies, is that they require a type of spent fuel reprocessing that can efficiently separate all of the transuranics from the fission products with which they are mixed. Unfortunately, the technology for doing this on an industrial scale is still in development. In this project, we explore a strategy for transmutation that can be deployed using existing, current generation reactors and reprocessing systems. We show that use of an inert matrix fuel to recycle transuranics in a conventional pressurized water reactor could reduce overall production of these materials by an amount that is similar to what is achievable using proposed fast reactor cycles. Furthermore, we show that these transuranic reductions can be achieved even if the fission products are carried into the inert matrix fuel along with the transuranics, bypassing the critical separations hurdle described above. The implications of these findings are significant, because they imply that inert matrix fuel could be made directly from the material streams produced by the commercially available PUREX process. Zirconium dioxide would be an ideal choice of inert matrix in this context because it is known to form a stable solid solution with both fission products and transuranics.

  20. 29 CFR 4062.5 - Net worth record date. (United States)


    ... 29 Labor 9 2010-07-01 2010-07-01 false Net worth record date. 4062.5 Section 4062.5 Labor Regulations Relating to Labor (Continued) PENSION BENEFIT GUARANTY CORPORATION LIABILITY LIABILITY FOR... to or abuse of the plan termination insurance system, may establish as the net worth record date an...

  1. 76 FR 81793 - Net Worth Standard for Accredited Investors (United States)


    ... of ``accredited investor'' in our Securities Act rules to exclude the value of a person's primary... amendments, exclusion of the value of the primary residence would reduce the investor's net worth by the same... Proposing Release, we believe that reducing an investor's net worth by the value of the primary residence...

  2. 76 FR 60364 - Net Worth and Equity Ratio (United States)


    ... ADMINISTRATION 12 CFR Parts 700, 701, 702, 725, and 741 RIN 3133-AD87 Net Worth and Equity Ratio AGENCY: National... worth'' and ``equity ratio'' in the Federal Credit Union Act. Through this final rule, NCUA is making... regulation and the definition of ``equity ratio'' as it appears in NCUA's Requirements for Insurance...

  3. 76 FR 16345 - Net Worth and Equity Ratio (United States)


    ... ADMINISTRATION 12 CFR Parts 700, 701, 702, and 741 RIN 3133-AD87 Net Worth and Equity Ratio AGENCY: National... worth'' and ``equity ratio'' in the Federal Credit Union Act. NCUA proposes to make conforming... the definition of ``equity ratio'' as it appears in NCUA's Requirements for Insurance regulation. NCUA...

  4. Ground-state electronic structure of actinide monocarbides and mononitrides

    DEFF Research Database (Denmark)

    Petit, Leon; Svane, Axel; Szotek, Z.


    The self-interaction corrected local spin-density approximation is used to investigate the ground-state valency configuration of the actinide ions in the actinide monocarbides, AC (A=U,Np,Pu,Am,Cm), and the actinide mononitrides, AN. The electronic structure is characterized by a gradually...... to the localization transition. The calculated valence electron densities of states are in good agreement with photoemission data....... increasing degree of f electron localization from U to Cm, with the tendency toward localization being slightly stronger in the (more ionic) nitrides compared to the (more covalent) carbides. The itinerant band picture is found to be adequate for UC and acceptable for UN, while a more complex manifold...

  5. Measurement of Actinides in Molybdenum-99 Solution Analytical Procedure

    Energy Technology Data Exchange (ETDEWEB)

    Soderquist, Chuck Z. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Weaver, Jamie L. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)


    This document is a companion report to a previous report, PNNL 24519, Measurement of Actinides in Molybdenum-99 Solution, A Brief Review of the Literature, August 2015. In this companion report, we report a fast, accurate, newly developed analytical method for measurement of trace alpha-emitting actinide elements in commercial high-activity molybdenum-99 solution. Molybdenum-99 is widely used to produce 99mTc for medical imaging. Because it is used as a radiopharmaceutical, its purity must be proven to be extremely high, particularly for the alpha emitting actinides. The sample of 99Mo solution is measured into a vessel (such as a polyethylene centrifuge tube) and acidified with dilute nitric acid. A gadolinium carrier is added (50 µg). Tracers and spikes are added as necessary. Then the solution is made strongly basic with ammonium hydroxide, which causes the gadolinium carrier to precipitate as hydrous Gd(OH)3. The precipitate of Gd(OH)3 carries all of the actinide elements. The suspension of gadolinium hydroxide is then passed through a membrane filter to make a counting mount suitable for direct alpha spectrometry. The high-activity 99Mo and 99mTc pass through the membrane filter and are separated from the alpha emitters. The gadolinium hydroxide, carrying any trace actinide elements that might be present in the sample, forms a thin, uniform cake on the surface of the membrane filter. The filter cake is first washed with dilute ammonium hydroxide to push the last traces of molybdate through, then with water. The filter is then mounted on a stainless steel counting disk. Finally, the alpha emitting actinide elements are measured by alpha spectrometry.

  6. Design of Counter Flow Burner for Oxy-Combustion Studies Using CFD (United States)

    Holifield, Laura; Uddi, Mruthunjaya


    Flat flames are useful for studying the fundamental physics of combustion through laser diagnostics and comparison with commercially (or open source) available 1D software such as Chemkin or Cantera. A counter flow burner is capable of producing this flat flame by achieving a flat velocity profile along the outlet. However, what is necessary to achieve this is not readily available. In order to find the optimal design parameters for a counter flow burner, different geometries and velocities were tested at the University of Alabama using Ansys Fluent CFD software. The geometry was axisymmetric and oriented horizontally on the xy-plane. The design of this burner was aimed at reducing the boundary layer while keeping the radial velocity at a minimum. The objective of this paper is to examine the effects of varying the angle, nozzle length, filet radius, inlet to outlet ratio, and velocity on the boundary layer and radial velocity of a counter flow burner. NSF Grant: EEC 1659710.

  7. Development of stoker-burner wood chip combustion systems for the UK market

    Energy Technology Data Exchange (ETDEWEB)



    The document makes a case for the development of a design of wood chip stoker-burner more suited to the UK than those currently imported from Sweden and Finland. The differences would centre on market conditions, performance and cost-effectiveness and the devices would be manufactured or part-manufactured in the UK. Econergy Limited was contracted by the DTI as part of its Sustainable Energy Programmes to design and construct an operational prototype stoker-burner rated at 120 kWth. A test rig was built to: (i) study modified burner heads and (ii) develop control hardware and a control strategy. Both (i) and (ii) are described. Tests brought about an increase in performance of the burner head and its wet wood performance. It was considered that further improvements are achievable and six areas for future study were suggested.

  8. Thermally unstable complexants/phosphate mineralization of actinides

    Energy Technology Data Exchange (ETDEWEB)

    Nash, K. [Argonne National Lab., IL (United States)


    In situ immobilization is an approach to isolation of radionuclides from the hydrosphere that is receiving increasing attention. Rather than removing the actinides from contaminated soils, this approach transforms the actinides into intrinsically insoluble mineral phases resistant to leaching by groundwater. The principal advangates of this concept are the low cost and low risk of operator exposure and/or dispersion of the radionuclides to the wider environment. The challenge of this approach is toe accomplish the immobilization without causing collateral damage to the environment (the cure shouldn`t be worse than the disease) and verification of system performance.

  9. New molecules for the separation of actinides (III): the picolinamides

    Energy Technology Data Exchange (ETDEWEB)

    Cordier, P.Y.; Condamines, N.; Berthon, L.; Madic, C.


    Minor actinide partitioning from high level liquid wastes produced during the reprocessing of nuclear fuels by the Purex process, requires the design of new extracting molecules. These new extractants must be able to separate, for example, actinides from lanthanides. This separation is very difficult, due to the similar chemical properties of these metallic species, but it can possibly be reached by using extractants with soft donor atoms (N or S). Some new molecules : the picolinamides are investigated in this way. The general chemical formula and the behaviour of these compounds in acidic media are given. (O.L.). 3 refs.


    Hildebrandt, R.A.; Hyman, H.H.; Vogler, S.


    A process of countercurrently extracting an aqueous mineral acid feed solution for the separation of actinides from lanthanides dissolved therern is described. The feed solution is made acid-defrcient with alkali metal hydroxide prior with acid extractant; during extraction, however, acid is transferred from organic to aqueous solution and the aqueous solution gradually becomes acid. The acid-deficient phase ' of the process promotes the extraction of the actinides, while the latter acid phase'' of the process improves retention of the lanthanides in the aqueous solution. This provides for an improved separation. (AEC)


    Energy Technology Data Exchange (ETDEWEB)



    The conclusions of this paper are: (1) mining of actinide cross-sections from reactor data is a viable and inexpensive approach to confirm burn-up codes; (2) extensive data for actinides in Hanford test data ({approx} 200 radiochemical analyses); (3) not only cross-section values and reaction rates can be established but also possible benchmark like data can be constructed to test and validate reactor and criticality safety codes such as SCALE/KENO or MCNPX; and (4) analysis along multiple transmutation paths can be evaluated to show consistency.

  12. Mathematical model of stacked one-sided arrangement of the burners

    Directory of Open Access Journals (Sweden)

    Oraz J.A.


    Full Text Available Paper is aimed at computer simulation of the turbulent methane-air combustion in upgraded U-shaped boiler unit. To reduce the temperature in the flame and hence NOx release every burner output was reduced, but the number of the burners was increased. The subject of studying: complex of characteristics with space-time fields in the upgraded steam boiler E-370 with natural circulation. The flare structure, temperature and concentrations were determined computationally.

  13. A flat flame burner for the calibration of laser thermometry techniques (United States)

    Hartung, G.; Hult, J.; Kaminski, C. F.


    The design and experimental characterization of a burner is described, which has favourable characteristics for the accurate calibration of a range of optical thermometry techniques. The burner supports stable laminar flames and combines many of the advantages of several widely used burner designs without their disadvantages. It permits the application of point measurement techniques, line-of-sight techniques and planar imaging techniques; trace species, such as metal atoms, can be easily introduced into the flame. The implementation of the burner is described, followed by the presentation of data obtained from coherent anti-Stokes Raman scattering (CARS) measurements and numerical simulations. Spatially resolved measurements were performed over the entire flame profile at three different stoichiometries and factors causing systematic and random errors are described in detail. Measurement errors on mean temperatures were determined to be less than 1%. The shot-to-shot measurement precision was determined to be 3.5-4.0% (FWHM of temperature probability density function). The burner design together with the data presented in this paper can be used for the validation and calibration, respectively, of a variety of combustion thermometry techniques. Complete details of the burner design together with the obtained temperature data will be provided on the World Wide Web. Other researchers intending to validate and calibrate their own laser-based thermometry techniques will be able to cost-effectively reconstruct this burner and adopt the characterization presented here, thus being able to apply it without the need of their own basic validation. The authors are confident that a reconstructed burner, which is applied under the same conditions, will yield the same high level of accuracy and precision as that presented in this paper.

  14. Low NOx Burner Design and Analysis for Conceptual Design of Oxygen-Based PC Boiler

    Energy Technology Data Exchange (ETDEWEB)

    Andrew Seltzer


    The objective of the low NOx burner design and analysis task of the Conceptual Design of Oxygen-Based PC Boiler study is to optimize the burner design to ensure stable ignition, to provide safe operation, and to minimize pollutant formation. The burners were designed and analyzed using the Fluent computer program. Four burner designs were developed: (1) with no over-fire gas (OFG) and 65% flue gas recycle, (2) with 20% OFG and 65% flue gas recycle, (3) with no OFG and 56% flue gas recycle and (4) with 20% OFG and 56% flue gas recycle. A 3-D Fluent simulation was made of a single wall-fired burner and horizontal portion of the furnace from the wall to the center. Without primary gas swirl, coal burnout was relatively small, due to the low oxygen content of the primary gas stream. Consequently, the burners were modified to include primary gas swirl to bring the coal particles in contact with the secondary gas. An optimal primary gas swirl was chosen to achieve sufficient burnout.

  15. Molecular and electronic structure of actinide hexa-cyanoferrates; Structure moleculaire et electronique des hexacyanoferrates d'actinides

    Energy Technology Data Exchange (ETDEWEB)

    Bonhoure, I


    The goal of this work is to improve our knowledge on the actinide-ligand bond properties. To this end, the hexacyanoferrate entities have been used as pre-organized ligand. We have synthesized, using mild chemistry, the following series of complexes: An{sup IV}[Fe{sup II}(CN){sub 6}].xH{sub 2}O (An = Th, U, Np, Pu); Am{sup III}[Fe{sup III}(CN){sub 6}].xH{sub 2}O; Pu {sup III}[Co{sup III}(CN){sub 6}].xH{sub 2}O and K(H?)An{sup III}[Fe{sup II}(CN){sub 6}].xH{sub 2}O (An = Pu, Am). The metal oxidation states have been obtained thanks to the {nu}{sub CN}, stretching vibration and to the actinide L{sub III} absorption edge studies. As Prussian Blue, the An{sup IV}[Fe{sup II}(CN){sub 6}].xH{sub 2}O (An = Np, Pu) are class II of Robin and Day compounds. X-ray Diffraction has shown besides that these complexes crystallize in the P6{sub 3}/m space group, as the isomorphic LaKFe(CN){sub 6}.4H{sub 2}O complex used as structural model. The EXAFS oscillations at the iron K edge and at the An L{sub III} edge allowed to determine the An-N, An-O, Fe-C and Fe-N distances. The display of the multiple scattering paths for both edges explains the actinide contribution absence at the iron edge, whereas the iron signature is present at the actinide edge. We have shown that the actinide coordination sphere in actinides hexa-cyanoferrates is comparable to the one of lanthanides. However, the actinides typical behavior towards the lanthanides is brought to the fore by the An{sup IV} versus Ln{sup III} ions presence in this family of complexes. Contrarily to the 4f electrons, the 5f electrons influence the electronic properties of the compounds of this family. However, the gap between the An-N and Ln-N distances towards the corresponding metals ionic radii do not show any covalence bond evolution between the actinide and lanthanide series. (author)

  16. Something worth remembering: visual discrimination in sharks. (United States)

    Fuss, Theodora; Schluessel, Vera


    This study investigated memory retention capabilities of juvenile gray bamboo sharks (Chiloscyllium griseum) using two-alternative forced-choice experiments. The sharks had previously been trained in a range of visual discrimination tasks, such as distinguishing between squares, triangles and lines, and their corresponding optical illusions (i.e., the Kanizsa figures or Müller-Lyer illusions), and in the present study, we tested them for memory retention. Despite the absence of reinforcement, sharks remembered the learned information for a period of up to 50 weeks, after which testing was terminated. In fish, as in other vertebrates, memory windows vary in duration depending on species and task; while it may seem beneficial to retain some information for a long time or even indefinitely, other information may be forgotten more easily to retain flexibility and save energy. The results of this study indicate that sharks are capable of long-term memory within the framework of selected cognitive skills. These could aid sharks in activities such as food retrieval, predator avoidance, mate choice or habitat selection and therefore be worth being remembered for extended periods of time. As in other cognitive tasks, intraspecific differences reflected the behavioral breadth of the species.

  17. Experimental Evaluation of Actinide Transport in a Fractured Granodiorite

    Energy Technology Data Exchange (ETDEWEB)

    Dittrich, Timothy M. [Los Alamos National Laboratory; Reimus, Paul W. [Los Alamos National Laboratory


    The objective of this study was to demonstrate and evaluate new experimental methods for quantifying the potential for actinide transport in deep fractured crystalline rock formations. We selected a fractured granodiorite at the Grimsel Test Site (GTS) in Switzerland as a model system because field experiments have already been conducted with uranium and additional field experiments using other actinides are planned at the site. Thus, working on this system provides a unique opportunity to compare lab experiment results with fieldscale observations. Rock cores drilled from the GTS were shipped to Los Alamos National Laboratory, characterized by x-ray diffraction and microscopy, and used in batch sorption and column breakthrough experiments. Solutions with pH 6.8 and 8.8 were tested. Solutions were switched to radionuclide-free synthetic Grimsel groundwater after near-steady actinide/colloid breakthrough occurred in column experiments. We are currently evaluating actinide adsorption/desorption rates as a function of water chemistry (initial focus on pH), with future testing planned to evaluate the influence of carbonate concentrations, flow rates, and mineralogy in solutions and suspensions with bentonite colloids. (auth)

  18. Colloid-borne forms of tetravalent actinides: a brief review. (United States)

    Zänker, Harald; Hennig, Christoph


    Tetravalent actinides, An(IV), are usually assumed to be little mobile in near-neutral environmental waters because of their low solubility. However, there are certain geochemical scenarios during which mobilization of An(IV) in a colloid-borne (waterborne) form cannot be ruled out. A compilation of colloid-borne forms of tetravalent actinides described so far for laboratory experiments together with several examples of An(IV) colloids observed in field experiments and real-world scenarios are given. They are intended to be a knowledge base and a tool for those who have to interpret actinide behavior under environmental conditions. Synthetic colloids containing structural An(IV) and synthetic colloids carrying adsorbed An(IV) are considered. Their behavior is compared with the behavior of An(IV) colloids observed after the intentional or unintentional release of actinides into the environment. A list of knowledge gaps as to the behavior of An(IV) colloids is provided and items which need further research are highlighted. Copyright © 2013 Elsevier B.V. All rights reserved.

  19. Citrate based ``TALSPEAK`` lanthanide-actinide separation process

    Energy Technology Data Exchange (ETDEWEB)

    Del Cul, G.D.; Bond, W.D.; Toth, L.M.; Davis, G.D.; Dai, S.; Metcalf, D.H.


    The potential hazard posed to future generations by long-lived radionuclides such as the transuranic elements (TRU) is perceived as a major problem associated with the use of nuclear power. TRU wastes have to remain isolated from the environment for ``geological`` periods of time. The costs of building, maintaining, and operating a ``geological TRU repository`` can be very high. Therefore, there are significant economical advantages in segregating the relatively low volume of TRU wastes from other nuclear wastes. The chemical behavior of lanthanides and actinides, 4f and 5f elements respectively, is rather similar. As a consequence, the separation of these two groups is difficult. The ``TALSPEAK`` process (Trivalent Actinide Lanthanide Separations by Phosphorus-reagent Extraction from Aqueous Complexes) is one of the few means available to separate the trivalent actinides from the lanthanides. The method is based on the preferential complexation of the trivalent actinides by an aminopolyacetic acid. Cold experiments showed that by using citric acid the deleterious effects produced by impurities such as zirconium are greatly reduced.

  20. Actinide Sputtering Induced by Fission with Ultra-cold Neutrons (United States)

    Shi, Tan; Venuti, Michael; Fellers, Deion; Martin, Sean; Morris, Chris; Makela, Mark


    Understanding the effects of actinide sputtering due to nuclear fission is important for a wide range of applications, including nuclear fuel storage, space science, and national defense. A new program at the Los Alamos Neutron Science Center uses ultracold neutrons (UCN) to induce fission in actinides such as uranium and plutonium. By controlling the UCN energy, it is possible to induce fission at the sample surface within a well-defined depth. It is therefore an ideal tool for studying the effects of fission-induced sputtering as a function of interaction depth. Since the mechanism for fission-induced surface damage is not well understood, this work has the potential to deconvolve the various damage mechanisms. During the irradiation with UCN, NaI detectors are used to monitor the fission events and were calibrated by monitoring fission fragments with an organic scintillator. Alpha spectroscopy of the ejected actinide material is performed in an ion chamber to determine the amount of sputtered material. Actinide samples with various sample properties and surface conditions are irradiated and analyzed. In this talk, I will discuss our experimental setup and present the preliminary results from the testing of multiple samples. This work has been supported by Los Alamos National Laboratory and Seaborg Summer Research Fellowship.

  1. Electron-phonon coupling of the actinide metals

    DEFF Research Database (Denmark)

    Skriver, H. L.; Mertig, I.


    -phonon parameter λ is found to attain its maximum value in Ac, and they predict a transition temperature of 9K for this metal. In the light actinides Th through Pu, λ is found to be of order 0.4 and within a factor of 2 of experiments which is also the accuracy found in studies of the transition metals...

  2. Fat burners: nutrition supplements that increase fat metabolism. (United States)

    Jeukendrup, A E; Randell, R


    The term 'fat burner' is used to describe nutrition supplements that are claimed to acutely increase fat metabolism or energy expenditure, impair fat absorption, increase weight loss, increase fat oxidation during exercise, or somehow cause long-term adaptations that promote fat metabolism. Often, these supplements contain a number of ingredients, each with its own proposed mechanism of action and it is often claimed that the combination of these substances will have additive effects. The list of supplements that are claimed to increase or improve fat metabolism is long; the most popular supplements include caffeine, carnitine, green tea, conjugated linoleic acid, forskolin, chromium, kelp and fucoxanthin. In this review the evidence for some of these supplements is briefly summarized. Based on the available literature, caffeine and green tea have data to back up its fat metabolism-enhancing properties. For many other supplements, although some show some promise, evidence is lacking. The list of supplements is industry-driven and is likely to grow at a rate that is not matched by a similar increase in scientific underpinning. © 2011 The Authors. obesity reviews © 2011 International Association for the Study of Obesity.

  3. Development of a lean premixed burner for hydrogen utilization

    Energy Technology Data Exchange (ETDEWEB)

    Keller, J.O. [Sandia National Lab., Livermore, CA (United States)


    The long-term mandate of the hydrogen program is to develop the technologies needed to establish a hydrogen economy. Although a hydrogen fueled automobile has been established as a demonstration project, there are at least three other end use sectors that are recognized by the H{sub 2} program and that are addressed by this project. These end uses are: (1) power generation from stationary turbines, (2) generation of process heat or steam, and (3) commercial and residential direct use applications. Eliminating carbon from the fuel will remove carbon containing species from the emissions, however, NO{sub x} resulting from thermal NO production cannot be ignored. Thermal NO production is minimized by reducing the peak combustion temperature and the residence time at the peak temperature. NO can be reduced to extremely low levels (a few ppm) by operating sufficiently lean to reduce the peak combustion temperatures below 1700 to 1800 K. The objectives for this project are to: (1) develop an environmentally benign and safe burner operating on hydrogen in a lean premixed mode, (2) provide a facility in which fundamental investigations can be performed to support other programs.

  4. Preliminary safety evaluation of the advanced burner test reactor.

    Energy Technology Data Exchange (ETDEWEB)

    Dunn, F. E.; Fanning, T. H.; Cahalan, J. E.; Nuclear Engineering Division


    Results of a preliminary safety evaluation of the Advanced Burner Test Reactor (ABTR) pre-conceptual design are reported. The ABTR safety design approach is described. Traditional defense-in-depth design features are supplemented with passive safety performance characteristics that include natural circulation emergency decay heat removal and reactor power reduction by inherent reactivity feedbacks in accidents. ABTR safety performance in design-basis and beyond-design-basis accident sequences is estimated based on analyses. Modeling assumptions and input data for safety analyses are presented. Analysis results for simulation of simultaneous loss of coolant pumping power and normal heat rejection are presented and discussed, both for the case with reactor scram and the case without reactor scram. The analysis results indicate that the ABTR pre-conceptual design is capable of undergoing bounding design-basis and beyond-design-basis accidents without fuel cladding failures. The first line of defense for protection of the public against release of radioactivity in accidents remains intact with significant margin. A comparison and evaluation of general safety design criteria for the ABTR conceptual design phase are presented in an appendix. A second appendix presents SASSYS-1 computer code capabilities and modeling enhancements implemented for ABTR analyses.

  5. Innovative SANEX process for trivalent actinides separation from PUREX raffinate

    Energy Technology Data Exchange (ETDEWEB)

    Sypula, Michal


    Recycling of nuclear spent fuel and reduction of its radiotoxicity by separation of long-lived radionuclides would definitely help to close the nuclear fuel cycle ensuring sustainability of the nuclear energy. Partitioning of the main radiotoxicity contributors followed by their conversion into short-lived radioisotopes is known as partitioning and transmutation strategy. To ensure efficient transmutation of the separated elements (minor actinides) the content of lanthanides in the irradiation targets has to be minimised. This objective can be attained by solvent extraction using highly selective ligands that are able to separate these two groups of elements from each other. The objective of this study was to develop a novel process allowing co-separation of minor actinides and lanthanides from a high active acidic feed solution with subsequent actinide recovery using just one cycle, so-called innovative SANEX process. The conditions of each step of the process were optimised to ensure high actinide separation efficiency. Additionally, screening tests of several novel lipophilic and hydrophilic ligands provided by University of Twente were performed. These tests were aiming in better understanding the influence of the extractant structural modifications onto An(III)/Ln(III) selectivity and complexation properties. Optimal conditions for minor actinides separation were found and a flow-sheet of a new innovative SANEX process was proposed. Tests using a single centrifugal contactor confirmed high Eu(III)/Am(III) separation factor of 15 while the lowest SF{sub Ln/Am} obtained was 6,5 (for neodymium). In addition, a new masking agent for zirconium was found as a substitution for oxalic acid. This new masking agent (CDTA) was also able to mask palladium without any negative influence on An(III)/Ln(III). Additional tests showed no influence of CDTA on plutonium present in the feed solution unlike oxalic acid which causes Pu precipitation. Therefore, CDTA was proposed as


    Energy Technology Data Exchange (ETDEWEB)

    E.G. Eddings; A. Molina; D.W. Pershing; A.F. Sarofim; T.H. Fletcher; H. Zhang; K.A. Davis; M. Denison; H. Shim


    The focus of this program is to provide insight into the formation and minimization of NO{sub x} in multi-burner arrays, such as those that would be found in a typical utility boiler. Most detailed studies are performed in single-burner test facilities, and may not capture significant burner-to-burner interactions that could influence NO{sub x} emissions. Thus, investigations of such interactions were made by performing a combination of single and multiple burner experiments in a pilot-scale coal-fired test facility at the University of Utah, and by the use of computational combustion simulations to evaluate full-scale utility boilers. In addition, fundamental studies on nitrogen release from coal were performed to develop greater understanding of the physical processes that control NO formation in pulverized coal flames--particularly under low NO{sub x} conditions. A CO/H{sub 2}/O{sub 2}/N{sub 2} flame was operated under fuel-rich conditions in a flat flame reactor to provide a high temperature, oxygen-free post-flame environment to study secondary reactions of coal volatiles. Effects of temperature, residence time and coal rank on nitrogen evolution and soot formation were examined. Elemental compositions of the char, tar and soot were determined by elemental analysis, gas species distributions were determined using FTIR, and the chemical structure of the tar and soot was analyzed by solid-state {sup 13}C NMR spectroscopy. A laminar flow drop tube furnace was used to study char nitrogen conversion to NO. The experimental evidence and simulation results indicated that some of the nitrogen present in the char is converted to nitric oxide after direct attack of oxygen on the particle, while another portion of the nitrogen, present in more labile functionalities, is released as HCN and further reacts in the bulk gas. The reaction of HCN with NO in the bulk gas has a strong influence on the overall conversion of char-nitrogen to nitric oxide; therefore, any model that

  7. Sequestering agents for the removal of actinides from waste streams

    Energy Technology Data Exchange (ETDEWEB)

    Raymond, K.N.; White, D.J.; Xu, Jide; Mohs, T.R. [Univ. of California, Berkeley, CA (United States)


    The goal of this project is to take a biomimetic approach toward developing new separation technologies for the removal of radioactive elements from contaminated DOE sites. To achieve this objective, the authors are investigating the fundamental chemistry of naturally occurring, highly specific metal ion sequestering agents and developing them into liquid/liquid and solid supported actinide extraction agents. Nature produces sideophores (e.g., Enterobactin and Desferrioxamine B) to selectivity sequester Lewis acidic metal ions, in particular Fe(III), from its surroundings. These chelating agents typically use multiple catechols or hydroxamic acids to form polydentate ligands that chelate the metal ion forming very stable complexes. The authors are investigating and developing analogous molecules into selective chelators targeting actinide(IV) ions, which display similar properties to Fe(III). By taking advantage of differences in charge, preferred coordination number, and pH stability range, the transition from nature to actinide sequestering agents has been applied to the development of new and highly selective actinide extraction technologies. Additionally, the authors have shown that these chelating ligands are versatile ligands for chelating U(VI). In particular, they have been studying their coordination chemistry and fundamental interactions with the uranyl ion [UO{sub 2}]{sup 2+}, the dominant form of uranium found in aqueous media. With an understanding of this chemistry, and results obtained from in vivo uranium sequestration studies, it should be possible to apply these actinide(IV) extraction technologies to the development of new extraction agents for the removal of uranium from waste streams.

  8. The INE-Beamline for actinide science at ANKA. (United States)

    Rothe, J; Butorin, S; Dardenne, K; Denecke, M A; Kienzler, B; Löble, M; Metz, V; Seibert, A; Steppert, M; Vitova, T; Walther, C; Geckeis, H


    Since its inauguration in 2005, the INE-Beamline for actinide research at the synchrotron source ANKA (KIT North Campus) provides dedicated instrumentation for x-ray spectroscopic characterization of actinide samples and other radioactive materials. R&D work at the beamline focuses on various aspects of nuclear waste disposal within INE's mission to provide the scientific basis for assessing long-term safety of a final nuclear waste repository. The INE-Beamline is accessible for the actinide and radiochemistry community through the ANKA proposal system and the European Union Integrated Infrastructure Initiative ACTINET-I3. Experiments with activities up to 1 × 10(+6) times the European exemption limit are feasible within a safe but flexible containment concept. Measurements with monochromatic radiation are performed at photon energies varying between ~2.1 keV (P K-edge) and ~25 keV (Pd K-edge), including the lanthanide L-edges and the actinide M- and L3-edges up to Cf. The close proximity of the INE-Beamline to INE controlled area labs offers infrastructure unique in Europe for the spectroscopic and microscopic characterization of actinide samples. The modular beamline design enables sufficient flexibility to adapt sample environments and detection systems to many scientific questions. The well-established bulk techniques x-ray absorption fine structure (XAFS) spectroscopy in transmission and fluorescence mode have been augmented by advanced methods using a microfocused beam, including (confocal) XAFS/x-ray fluorescence detection and a combination of (micro-)XAFS and (micro-)x-ray diffraction. Additional instrumentation for high energy-resolution x-ray emission spectroscopy has been successfully developed and tested. © 2012 American Institute of Physics

  9. Thermo-Acoustic Properties of a Burner with Axial Temperature Gradient: Theory and Experiment

    Directory of Open Access Journals (Sweden)

    Béla Kosztin


    Full Text Available This paper presents a model for thermo-acoustic effects in a gas turbine combustor. A quarter-wavelength burner with rectangular cross-section has been built and studied from an experimental and theoretical perspective. It has a premixed methane-air flame, which is held by a bluff body, and spans the width of the burner. The flame is compact, i.e. its length is much smaller than that of the burner. The fundamental mode of the burner is unstable; its frequency and pressure distribution have been measured. The complex pressure reflection coefficients at the upstream and downstream end of the burner were also measured. For the theoretical considerations, we divide the burner into three regions (the cold pre-combustion chamber, the flame region and the hot outlet region, and assume one-dimensional acoustic wave propagation in each region. The acoustic pressure and velocity are assumed continuous across the interface between the precombustion chamber and flame region, and across the interface between the flame region and outlet region. The burner ends are modelled by the measured pressure reflection coefficients. The mean temperature is assumed to have the following profile: uniformly cold and uniformly hot in the pre-combustion chamber and outlet region, respectively, and rising continuously from cold to hot in the flame region. For comparison, a discontinuous temperature profile, jumping directly from cold to hot, is also considered. The eigenfrequencies are calculated, and the pressure distribution of the fundamental mode is predicted. There is excellent agreement with the experimental results. The exact profile of the mean temperature in the flame region is found to be unimportant. This study gives us an experimentally validated Green's function, which is a very useful tool for further theoretical studies.

  10. Comparable Worth: The Labor Theory of Value and Worse. (United States)

    Baird, Charles W.


    The concept of comparable worth is criticized for possible problems it could cause in the assessment of comparable values of different occupational categories, the cost to taxpayers, and the chaos it could cause in the economic system. (MD)

  11. 5 CFR 2610.202 - Net worth exhibit. (United States)


    ....202 Administrative Personnel OFFICE OF GOVERNMENT ETHICS ORGANIZATION AND PROCEDURES IMPLEMENTATION OF THE EQUAL ACCESS TO JUSTICE ACT Information Required From Applicants § 2610.202 Net worth exhibit. (a... Government Ethics' established procedures under the Freedom of Information Act. ...

  12. Development of advanced low NOx and wide range burner for pulverized coal combustion; Bifunsumiyo choteiNOx {center_dot} waidorenjibana no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    Makino, Naoto; Kimoto, Masayoshi [Central Research Institure of Electric Power Inductry, Tokyo (Japan); Kiga, Takashi; Endo, Kiyohiko [Ishikawajima-Harima Heavy Industries Co., Ltd., Tokyo (Japan)


    Coal is becoming more and more important as an energy source for thermal power generation. In pulverized coal fired boilers, it is necessary to develop econometrically friendly technology for reducing NOx emission and unburned carbon in fly ash, and stable combustion technology at low flexible operation. An advanced low NOx burner (CI-{alpha} burner) has been developed, this burner is capable of reducing the NOx formation to about 30% lower than conventional burners at the same unburned carbon important to add the ability which the pulverized coal can be concentrated in the burner before ignition. In this paper, two coal particle concentrating methods are investigated for the CI-{alpha} burner. Each method can concentrate the pulverized coal particles greater than 1.5 times in the primary air nozzle. The new burner which combines this concentrating equipment with the CI-{alpha} burner offers stable combustion at 20%, on the same level as oil burners. This advanced low NOx and wide range burner (CI-{alpha} {center_dot} WR burner) has same the NOx and unburned carbon generation characteristics at the standard load as the CI-{alpha} burner and can reduce the unburned carbon in fly ash lower than the CI-{alpha} burner at low loads. (author)

  13. A critical review of noise production models for turbulent, gas-fueled burners (United States)

    Mahan, J. R.


    The combustion noise literature for the period between 1952 and early 1984 is critically reviewed. Primary emphasis is placed on past theoretical and semi-empirical attempts to predict or explain observed direct combustion noise characteristics of turbulent, gas-fueled burners; works involving liquid-fueled burners are reviewed only when ideas equally applicable to gas-fueled burners are pesented. The historical development of the most important contemporary direct combustion noise theories is traced, and the theories themselves are compared and criticized. While most theories explain combustion noise production by turbulent flames in terms of randomly distributed acoustic monopoles produced by turbulent mixing of products and reactants, none is able to predict the sound pressure in the acoustic farfield of a practical burner because of the lack of a proven model which relates the combustion noise source strenght at a given frequency to the design and operating parameters of the burner. Recommendations are given for establishing a benchmark-quality data base needed to support the development of such a model.

  14. Parametric Study of High-Efficiency and Low-Emission Gas Burners

    Directory of Open Access Journals (Sweden)

    Shuhn-Shyurng Hou


    Full Text Available The objective of this study is to investigate the influence of three significant parameters, namely, swirl flow, loading height, and semi-confined combustion flame, on thermal efficiency and CO emissions of a swirl flow gas burner. We focus particularly on the effects of swirl angle and inclination angle on the performance of the swirl flow burner. The results showed that the swirl flow burner yields higher thermal efficiency and emits lower CO concentration than those of the conventional radial flow burner. A greater swirl angle results in higher thermal efficiency and CO emission. With increasing loading height, the thermal efficiency increases but the CO emission decreases. For a lower loading height (2 or 3 cm, the highest efficiency occurs at the inclination angle 15°. On the other hand, at a higher loading height, 4 cm, thermal efficiency increases with the inclination angle. Moreover, the addition of a shield can achieve a great increase in thermal efficiency, about 4-5%, and a decrease in CO emissions for the same burner (swirl flow or radial flow.

  15. Actinides compounds for the transmutation: scientific contributions of american and japanese collaborations; Composes d'actinides pour la transmutation: apports scientifiques de collaborations americaines et japonaises

    Energy Technology Data Exchange (ETDEWEB)

    Raison, Ph.; Albiot, T


    This paper deals with the minor actinides transmutation and the scientific contribution of the ORNL and the JAERI. It presents researches on the Am-Zr-Y-O system in the framework of the heterogeneous reprocessing, the curium and pyrochlore structures, with the ORNL contribution and phase diagrams, data of Thermodynamics, actinides nitrides, with the JAERI. (A.L.B.)

  16. Solubility of actinides and surrogates in nuclear glasses; Solubilite des actinides et de leurs simulants dans les verres nucleaires. Limites d'incorporation et comprehension des mecanismes

    Energy Technology Data Exchange (ETDEWEB)

    Lopez, Ch


    The nuclear wastes are currently incorporated in borosilicate glass matrices. The resulting glass must be perfectly homogeneous. The work discussed here is a study of actinide (thorium and plutonium) solubility in borosilicate glass, undertaken to assess the extent of actinide solubility in the glass and to understand the mechanisms controlling actinide solubilization. Glass specimens containing; actinide surrogates were used to prepare and optimize the fabrication of radioactive glass samples. These preliminary studies revealed that actinide Surrogates solubility in the glass was enhanced by controlling the processing temperature, the dissolution kinetic of the surrogate precursors, the glass composition and the oxidizing versus reducing conditions. The actinide solubility was investigated in the borosilicate glass. The evolution of thorium solubility in borosilicate glass was determined for temperatures ranging from 1200 deg C to 1400 deg C.Borosilicate glass specimens containing plutonium were fabricated. The experimental result showed that the plutonium solubility limit ranged from 1 to 2.5 wt% PuO{sub 2} at 1200 deg C. A structural approach based on the determination of the local structure around actinides and their surrogates by EXAFS spectroscopy was used to determine their structural role in the glass and the nature of their bonding with the vitreous network. This approach revealed a correlation between the length of these bonds and the solubility of the actinides and their surrogates. (author)

  17. Effects of the Burner Diameter on the Flame Structure and Extinction Limit of Counterflow Non-Premixed Flames

    Directory of Open Access Journals (Sweden)

    Chang Bo Oh


    Full Text Available Experiments and numerical simulations were conducted to investigate the effects of the burner diameter on the flame structure and extinction limit of counterflow non-premixed methane flames in normal gravity and microgravity. Experiments were performed for counterflow flames with a large inner diameter (d of 50 mm in normal gravity to compare the extinction limits with those obtained by previous studies where a small burner (d < 25 mm was used. Two-dimensional (2D simulations were performed to clarify the flame structure and extinction limits of counterflow non-premixed flame with a three-step global reaction mechanism. One-dimensional (1D simulations were also performed with the same three-step global reaction mechanism to provide reference data for the 2D simulation and experiment. For microgravity, the effect of the burner diameter on the flame location at the centerline was negligible at both high (ag = 50 s−1 and low (ag = 10 s−1 strain rates. However, a small burner flame (d = 15 mm in microgravity showed large differences in the maximum flame temperature and the flame size in radial direction compared to a large burner flame (d = 50 mm at low strain rate. In addition, for normal gravity, a small burner flame (d = 23.4 mm showed differences in the flame thickness, flame location, local strain rate, and maximum heat release rate compared to a large burner flame (d = 50 mm at low strain rate. Counterflow non-premixed flames with low and high strain rates that were established in a large burner were approximated by 1D simulation for normal gravity and microgravity. However, a counterflow non-premixed flame with a low strain rate in a small burner could not be approximated by 1D simulation for normal gravity due to buoyancy effects. The 2D simulations of the extinction limits correlated well with experiments for small and large burner flames. For microgravity, the extinction limit of a small burner flame (d = 15 mm was much lower than that

  18. Development of lean premixed low-swirl burner for low NO{sub x} practical application

    Energy Technology Data Exchange (ETDEWEB)

    Yegian, D.T.; Cheng, R.K.


    Laboratory experiments have been performed to evaluate the performance of a premixed low-swirl burner (LSB) in configurations that simulate commercial heating appliances. Laser diagnostics were used to investigate changes in flame stabilization mechanism, flowfield, and flame stability when the LSB flame was confined within quartz cylinders of various diameters and end constrictions. The LSB adapted well to enclosures without generating flame oscillations and the stabilization mechanism remained unchanged. The feasibility of using the LSB as a low NO{sub x} commercial burner has also been verified in a laboratory test station that simulates the operation of a water heater. It was determined that the LSB can generate NO{sub x} emissions < 10 ppm (at 3% O{sub 2}) without significant effect on the thermal efficiency of the conventional system. The study has demonstrated that the lean premixed LSB has commercial potential for use as a simple economical and versatile burner for many low emission gas appliances.

  19. Optimal Switching Control of Burner Setting for a Compact Marine Boiler Design

    DEFF Research Database (Denmark)

    Solberg, Brian; Andersen, Palle; Maciejowski, Jan M.


    This paper discusses optimal control strategies for switching between different burner modes in a novel compact  marine boiler design. The ideal behaviour is defined in a performance index the minimisation of which defines an ideal trade-off between deviations in boiler pressure and water level...... approach is based on a generalisation of hysteresis control. The strategies are verified on a simulation model of the compact marine boiler for control of low/high burner load switches.  ...... from their respective setpoints and the cost of burner switches and variation of continuous input flows. Direct minimisation was found computational infeasible and two different suboptimal strategies have beenconsidered. The first one is based on the Mixed Logical Dynamical framework. Thesecond...

  20. Development and certification of the innovative pioneer oil burner for residential heating appliances

    Energy Technology Data Exchange (ETDEWEB)

    Kamath, B. [Heat Wise Inc., Ridge, NY (United States)


    The Pioneer burner represents another important milestone for the oil heat industry. It is the first practical burner design that is designated for use in small capacity heating appliances matching the needs of modern energy efficient home designs. Firing in the range of 0.3 GPH to 0.65 GPH (40,000-90,000 Btu/hr) it allows for new oil heating appliance designs to compete with the other major fuel choices in the small design load residential market. This market includes energy efficient single family houses, town-houses, condominiums, modular units, and mobile homes. The firing range also is wide enough to cover a large percentage of more conventional heating equipment and home designs as well. Having recently passed Underwriters Laboratory certification tests the burner in now being field tested in several homes and samples are being made available to interested boiler and furnace manufacturers for product development and application testing.

  1. Chemistry of the actinide elements. Vol. 2. 2. Ed

    Energy Technology Data Exchange (ETDEWEB)

    Katz, J.J.; Morss, L.R.; Seaborg, G.T. (eds.)


    This is a comprehensive, exposition of the chemistry and related properties of the 5f series of elements: actinium, thorium, protactinium, uranium and the first eleven transuranium elements. The descriptions of each element include accounts of their history, separation, metallurgy, solid-state chemistry, solution chemistry, thermodynamics and kinetics. Additionally, separate chapters on spectroscopy, magnetochemistry, thermodynamics, solids, the metallic state, complex ions and organometallic compounds emphasize the comparative chemistry and unique properties of the actinide series of elements. Comprehensive list of properties of all actinide compounds and ions in solution are given, and there are special sections on such topics as biochemistry, superconductivity, radioisotope safety, and waste management, as well as discussion of the transactinides and future elements.

  2. Superabsorbing gel for actinide, lanthanide, and fission product decontamination (United States)

    Kaminski, Michael D.; Mertz, Carol J.


    The present invention provides an aqueous gel composition for removing actinide ions, lanthanide ions, fission product ions, or a combination thereof from a porous surface contaminated therewith. The composition comprises a polymer mixture comprising a gel forming cross-linked polymer and a linear polymer. The linear polymer is present at a concentration that is less than the concentration of the cross-linked polymer. The polymer mixture is at least about 95% hydrated with an aqueous solution comprising about 0.1 to about 3 percent by weight (wt %) of a multi-dentate organic acid chelating agent, and about 0.02 to about 0.6 molar (M) carbonate salt, to form a gel. When applied to a porous surface contaminated with actinide ions, lanthanide ions, and/or other fission product ions, the aqueous gel absorbs contaminating ions from the surface.

  3. Actinide-specific sequestering agents and decontamination applications

    Energy Technology Data Exchange (ETDEWEB)

    Smith, William L. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Materials and Molecular Research Division; Univ. of California, Berkeley, CA (United States). Dept. of Chemistry; Raymond, Kenneth N. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Materials and Molecular Research Division; Univ. of California, Berkeley, CA (United States). Dept. of Chemistry


    With the commercial development of nuclear reactors, the actinides have become very important industrial elements. A major concern of the nuclear industry is the biological hazard associated with nuclear fuels and their wastes. The acute chemical toxicity of tetravalent actinides, as exemplified by Th(IV), is similar to Cr(III) or Al(III). However, the acute toxicity of 239Pu(IV) is similar to strychnine, which is much more toxic than any of the non-radioactive metals such as mercury. Although the more radioactive isotopes of the transuranium elements are more acutely toxic by weight than plutonium, the acute toxicities of 239Pu, 241Am, and 244Cm are nearly identical in radiation dose, ~100 μCi/kg in rodents. Finally and thus, the extreme acute toxicity of 239Pu is attributed to its high specific activity of alpha emission.

  4. Status of measurements of fission neutron spectra of Minor Actinides

    Energy Technology Data Exchange (ETDEWEB)

    Drapchinsky, L.; Shiryaev, B. [V.G. Khlopin Radium Inst., Saint Petersburg (Russian Federation)


    The report considers experimental and theoretical works on studying the energy spectra of prompt neutrons emitted in spontaneous fission and neutron induced fission of Minor Actinides. It is noted that neutron spectra investigations were done for only a small number of such nuclei, most measurements, except those of Cf-252, having been carried out long ago by obsolete methods and imperfectapparatus. The works have no detailed description of experiments, analysis of errors, detailed numerical information about results of experiments. A conclusion is made that the available data do not come up to modern requirements. It is necessary to make new measurements of fission prompt neutron spectra of transuranium nuclides important for the objectives of working out a conception of minor actinides transmutation by means of special reactors. (author)

  5. Development of a remote bushing for actinide vitrification

    Energy Technology Data Exchange (ETDEWEB)

    Schumacher, R.F.; Ramsey, W.G.; Johnson, F.M. [and others


    The Savannah River Site (SRS) and the Savannah River Technology Center (SRTC) are combining their existing experience in handling highly radioactive, special nuclear materials with commercial glass fiberization technology in order to assemble a small vitrification system for radioactive actinide solutions. The vitrification system or {open_quotes}brushing{close_quotes}, is fabricated from platinum-rhodium alloy and is based on early marble remelt fiberization technology. Advantages of this unique system include its relatively small size, reliable operation, geometrical safety (nuclear criticality), and high temperature capability. The bushing design should be capable of vitrifying a number of the actinide nuclear materials, including solutions of americium/curium, neptunium, and possibly plutonium. State of the art, mathematical and oil model studies are being combined with basic engineering evaluations to verify and improve the thermal and mechanical design concepts.

  6. Partitioning of Mercury from Actinides in the TRUEX Process

    Energy Technology Data Exchange (ETDEWEB)

    Fiskum, Sandra K.(BATTELLE (PACIFIC NW LAB)); Rapko, Brian M.(BATTELLE (PACIFIC NW LAB)); Lumetta, Gregg J.(BATTELLE (PACIFIC NW LAB))


    A mercury complexant, L-cysteine hydrochloride, was tested for use in separating Hg from actinides during TRUEX processing of wastes at the Idaho National Engineering and Environmental Laboratory (INEEL). Mercury, americium, plutonium and uranyl distributions from TRUEX solvent were characterized over a nitric acid concentration range of 0.01 to 2 M. The applicability of cysteine was also evaluated for selective Hg complexation in an INEEL sodium-bearing waste simulant. A test was also conducted to evaluate the applicability of cysteine to separate Hg from Sr in the SREX process with Sr Resin used as a stand-in for the SREX process solvent. In all cases, the use of L-cysteine HCl retained Hg in the aqueous phase while causing no or little perturbation in the actinide and Sr distribution behavior.

  7. Atomic properties of actinide ions with particle-hole configurations (United States)

    Safronova, M. S.; Safronova, U. I.; Kozlov, M. G.


    We study the effects of higher-order electronic correlations in the systems with particle-hole excited states using a relativistic hybrid method that combines configuration interaction and linearized coupled-cluster approaches. We find the configuration interaction part of the calculation sufficiently complete for eight electrons while maintaining good quality of the effective coupled-cluster potential for the core. Excellent agreement with experiment was demonstrated for a test case of La3 +. We apply our method for homolog actinide ions Th4 + and U6 + which are of experimental interest due to a puzzle associated with the resonant excitation Stark ionization spectroscopy method. These ions are also of interest to actinide chemistry.

  8. Regenerative burner systems for batch furnaces in the steel industry; Regenerativbrenner fuer Doppel-P-Strahlheizrohre in einer Feuerverzinkungslinie

    Energy Technology Data Exchange (ETDEWEB)

    Georgiew, Alexander [Salzgitter Flachstahl GmbH, Salzgitter (Germany); Wuenning, Joachim G.; Bonnet, Uwe [WS Waermeprozesstechnik GmbH, Renningen (Germany)


    This article will describe the application of a new self regenerative burner in a continuous galvanizing line. After a brief introduction of the process line, the self regenerative burner will be described. Very high air preheat temperatures enable considerable energy savings and flameless oxidation suppresses the formation of NO{sub X}. (orig.)

  9. Development of combined low-emissions burner devices for low-power boilers (United States)

    Roslyakov, P. V.; Proskurin, Yu. V.; Khokhlov, D. A.


    Low-power water boilers are widely used for autonomous heat supply in various industries. Firetube and water-tube boilers of domestic and foreign manufacturers are widely represented on the Russian market. However, even Russian boilers are supplied with licensed foreign burner devices, which reduce their competitiveness and complicate operating conditions. A task of developing efficient domestic low-emissions burner devices for low-power boilers is quite acute. A characteristic property of ignition and fuel combustion in such boilers is their flowing in constrained conditions due to small dimensions of combustion chambers and flame tubes. These processes differ significantly from those in open combustion chambers of high-duty power boilers, and they have not been sufficiently studied yet. The goals of this paper are studying the processes of ignition and combustion of gaseous and liquid fuels, heat and mass transfer and NO x emissions in constrained conditions, and the development of a modern combined low-emissions 2.2 MW burner device that provides efficient fuel combustion. A burner device computer model is developed and numerical studies of its operation on different types of fuel in a working load range from 40 to 100% of the nominal are carried out. The main features of ignition and combustion of gaseous and liquid fuels in constrained conditions of the flame tube at nominal and decreased loads are determined, which differ fundamentally from the similar processes in steam boiler furnaces. The influence of the burner devices design and operating conditions on the fuel underburning and NO x formation is determined. Based on the results of the design studies, a design of the new combined low-emissions burner device is proposed, which has several advantages over the prototype.

  10. Thermal performances and CO emissions of gas-fired cooker-top burners

    Energy Technology Data Exchange (ETDEWEB)

    Li, H.B.; Wong, T.T.; Leung, C.W. [The Hong Kong Polytechnic University, Kowloon (Hong Kong). Department of Mechanical Engineering; Probert, S.D. [Cranfield University, Bedford (United Kingdom). School of Mechanical Engineering


    Domestic cooker-top burners operate at low pressure and low Reynolds numbers. They do not usually have a flue, and are fired with impinging premixed natural-gas/air flames. There are two major considerations in using such burners, namely, poor energy utilization and indoor-air pollution. Because of the large number of cooker-top burners being used, even a slight improvement in thermal performance resulting from a better design will lead to significant reductions of domestic and commercial energy consumptions. In view of the need to raise the thermal performance and to reduce indoor-air pollution, advanced statistical experimental designs have been applied in the present study to evaluate the individual and combined effects of the major cooker-top design parameters. The experimental study was carried out using a 4-factor and 3-level Box-Behnken design-method, utilizing a premixed gas-fired impinging-flame. A cooker-top burner, with circular nozzles with an inner diameter of 3mm, was used in this experiment. Design parameters of the burner under consideration include Reynolds number, equivalence ratio, nozzle-to-plate distance, and jet-to-jet spacing. Based on an analysis of the experimental data, variations of the thermal efficiency and the carbon monoxide (CO) emission with each of the above mentioned parameters have been reported. Multiple regression models of the thermal efficiency and the CO emissions were obtained in terms of all the major design parameters. Some of the 2-factor interactions on the thermal efficiency and the CO emissions were significant. The findings are important for the designer of a fuel-efficient and environmentally-friendly cooker-top burner. (author)

  11. Development of the Radiation Stabilized Distributed Flux Burner. Phase 1, final report

    Energy Technology Data Exchange (ETDEWEB)

    Sullivan, J.D.; Duret, M.J.


    The RSB was first developed for Thermally Enhanced Oil Recovery steamers which fire with a single 60 MMBtu/hr burner; the California Energy Commission and Chevron USA were involved in the burner development. The burner has also since found applications in refinery and chemical plant process heaters. All Phase I goals were successfully met: the RSB achieved sub-9 ppM NOx and sub-50 ppM CO emissions using high excess air, external flue gas recirculation (FGR), and fuel staging in the 3 MMBtu/hr laboratory watertube boiler. In a test in a 50,000 lb/hr oil field steamer with fuel staging, it consistently achieved sub-20 ppM NOx and as low as 10 ppM NOx. With high CO{sub 2} casing gas in this steamer, simulating external FGR, sub-20 ppM NOx and as low as 5 ppM NOx were achieved. Burner material cost was reduced by 25% on a per Btu basis by increasing the effective surface firing rate at the burner; further reductions will occur in Phase II. The market for 30 ppM and 9 ppM low NOx burners has been identified as package boilers in the 50,000 to 250,000 lb/hr size range (the 30 ppM is for retrofit, the 9 ppM for the new boiler market). Alzeta and Babcock & Wilcox have teamed to sell both boiler retrofits and new boilers; they have identified boiler designs which use the compact flame shape of the RSB and can increase steam capacity while maintaining the same boiler footprint. Alzeta, Chevron, and B & W have teamed to identify sites to demonstrate the RSB in Phases II and III. In Phase II, the RSB will be demonstrated in a 100,000 lb/hr industrial watertube boiler.

  12. Comparative Study of f-Element Electronic Structure across a Series of Multimetallic Actinide, Lanthanide-Actinide and Lanthanum-Actinide Complexes Possessing Redox-Active Bridging Ligands

    Energy Technology Data Exchange (ETDEWEB)

    Schelter, Eric J.; Wu, Ruilian; Veauthier, Jacqueline M.; Bauer, Eric D.; Booth, Corwin H.; Thomson, Robert K.; Graves, Christopher R.; John, Kevin D.; Scott, Brian L.; Thompson, Joe D.; Morris, David E.; Kiplinger, Jaqueline L.


    A comparative examination of the electronic interactions across a series of trimetallic actinide and mixed lanthanide-actinide and lanthanum-actinide complexes is presented. Using reduced, radical terpyridyl ligands as conduits in a bridging framework to promote intramolecular metal-metal communication, studies containing structural, electrochemical, and X-ray absorption spectroscopy are presented for (C{sub 5}Me{sub 5}){sub 2}An[-N=C(Bn)(tpy-M{l_brace}C{sub 5}Me4R{r_brace}{sub 2})]{sub 2} (where An = Th{sup IV}, U{sup IV}; Bn = CH{sub 2}C{sub 6}H{sub 5}; M = La{sup III}, Sm{sup III}, Yb{sup III}, U{sup III}; R = H, Me, Et) to reveal effects dependent on the identities of the metal ions and R-groups. The electrochemical results show differences in redox energetics at the peripheral 'M' site between complexes and significant wave splitting of the metal- and ligand-based processes indicating substantial electronic interactions between multiple redox sites across the actinide-containing bridge. Most striking is the appearance of strong electronic coupling for the trimetallic Yb{sup III}-U{sup IV}-Yb{sup III}, Sm{sup III}-U{sup IV}-Sm{sup III}, and La{sup III}-U{sup IV}-La{sup III} complexes, [8]{sup -}, [9b]{sup -} and [10b]{sup -}, respectively, whose calculated comproportionation constant K{sub c} is slightly larger than that reported for the benchmark Creutz-Taube ion. X-ray absorption studies for monometallic metallocene complexes of U{sup III}, U{sup IV}, and U{sup V} reveal small but detectable energy differences in the 'white-line' feature of the uranium L{sub III}-edges consistent with these variations in nominal oxidation state. The sum of this data provides evidence of 5f/6d-orbital participation in bonding and electronic delocalization in these multimetallic f-element complexes. An improved, high-yielding synthesis of 4{prime}-cyano-2,2{prime}:6{prime},2{double_prime}-terpyridine is also reported.

  13. Chemical and Ceramic Methods Toward Safe Storage of Actinides

    Energy Technology Data Exchange (ETDEWEB)

    P.E.D. Morgan; R.M. Housley; J.B. Davis; M.L. DeHaan


    A very import, extremely-long-term, use for monazite as a radwaste encapsulant has been proposed. THe use of ceramic La-monazite for sequestering actinides (isolating them from the environment), especially plutonium and some other radioactive elements )e.g., fission-product rare earths), had been especially championed by Lynn Boatner of ORNL. Monazite may be used alone or, copying its compatibility with many other minerals in nature, may be used in diverse composite combinations.

  14. Surface energy and work function of the light actinides

    DEFF Research Database (Denmark)

    Kollár, J.; Vitos, Levente; Skriver, Hans Lomholt


    We have calculated the surface energy and work function of the light actinides Fr, Ra, Ac, Th, Pa, U, Np, and Pu by means of a Green's-function technique based on the linear-muffin-tin-orbitals method within the tight-binding representation. In these calculations we apply an energy functional which....... The calculated surface energies and work functions are in good agreement with the limited experimental data....

  15. Chemical properties of the heavier actinides and transactinides

    Energy Technology Data Exchange (ETDEWEB)

    Hulet, E.K.


    The chemical properties of each of the elements 99 (Es) through 105 are reviewed and their properties correlated with the electronic structure expected for 5f and 6d elements. A major feature of the heavier actinides, which differentiates them from the comparable lanthanides, is the increasing stability of the divalent oxidation state with increasing atomic number. The divalent oxidation state first becomes observable in the anhydrous halides of californium and increases in stability through the series to nobelium, where this valency becomes predominant in aqueous solution. In comparison with the analogous 4f electrons, the 5f electrons in the latter part of the series are more tightly bound. Thus, there is a lowering of the 5f energy levels with respect to the Fermi level as the atomic number increases. The metallic state of the heavier actinides has not been investigated except from the viewpoint of the relative volatility among members of the series. In aqueous solutions, ions of these elements behave as a normal trivalent actinides and lanthanides (except for nobelium). Their ionic radii decrease with increasing nuclear charge which is moderated because of increased screening of the outer 6p electrons by the 5f electrons. The actinide series of elements is completed with the element lawrencium (Lr) in which the electronic configuration is 5f/sup 14/7s/sup 2/7p. From Mendeleev's periodicity and Dirac-Fock calculations, the next group of elements is expected to be a d-transition series corresponding to the elements Hf through Hg. The chemical properties of elements 104 and 105 only have been studied and they indeed appear to show the properties expected of eka-Hf and eka-Ta. However, their nuclear lifetimes are so short and so few atoms can be produced that a rich variety of chemical information is probably unobtainable.

  16. Validation of minor actinides fission neutron cross-sections

    Directory of Open Access Journals (Sweden)

    Pešić Milan P.


    Full Text Available Verification of neutron fission cross-sections of minor actinides from some recently available evaluated nuclear data libraries was carried out by comparison of the reaction rates calculated by the MCNP6.1 computer code to the experimental values. The experimental samples, containing thin layers of 235U, 237Np, 238,239,240,241Pu, 242mAm, 243Cm, 245Cm, and 247Cm, deposited on metal support and foils of 235U (pseudo-alloy 27Al + 235U, 238U, natIn, 64Zn, 27Al, and multi-component sample alloy 27Al + 55Mn + natCu + natLu + 197Au, were irradiated in the channels of the tank containing fluorine salts 0.52NaF + 0.48ZrF4, labelled as the Micromodel Salt Blanket, inserted in the lattice centre of the MAKET heavy water critical assembly at the Institute for Theoretical and Experimental Physics, Moscow. This paper is a continuation of earlier initiated scientific-research activities carried out for validation of the evaluated fission cross-sections of actinides that were supposed to be used for the quality examination of the fuel design of the accelerator driven systems or fast reactors, and consequently, determination of transmutation rates of actinides, and therefore, determination of operation parameters of these reactor facilities. These scientific-research activities were carried out within a frame of scientific projects supported by the International Science and Technology Center and the International Atomic Energy Agency co-ordinated research activities, from 1999 to 2010. Obtained results confirm that further research is needed in evaluations in order to establish better neutron cross-section data for the minor actinides and selected nuclides which could be used in the accelerator driven systems or fast reactors.

  17. Application of roof radiant burners in large pusher-type furnaces

    Directory of Open Access Journals (Sweden)

    A. Varga


    Full Text Available The paper deals with the application of roof flat-flame burners in the pusher-type steel slab reheating furnaces, after furnace reconstruction and replacement of conventional torch burners, with the objective to increase the efficiency of radiative heat transfer from the refractory roof to the charge. Based on observations and on measurements of the construction and process parameters under operating conditions, the advantages and disadvantages of indirectly oriented radiant heat transfer are analysed in relation to the heat transfer in classically fired furnaces.


    Energy Technology Data Exchange (ETDEWEB)

    Hamid Farzan; Jennifer Sivy; Alan Sayre; John Boyle


    Under sponsorship of the Department of Energy's National Energy Technology Laboratory (NETL), McDermott Technology, Inc. (MTI), the Babcock & Wilcox Company (B&W), and Fuel Tech teamed together to investigate an integrated solution for NOx control. The system was comprised of B&W's DRB-4Z{trademark} low-NO{sub x} pulverized coal (PC) burner technology and Fuel Tech's NO{sub x}OUT{reg_sign}, a urea-based selective non-catalytic reduction (SNCR) technology. The technology's emission target is achieving 0.15 lb NO{sub x}/10{sup 6} Btu for full-scale boilers. Development of the low-NOx burner technology has been a focus in B&W's combustion program. The DRB-4Z{trademark} burner (see Figure 1.1) is B&W's newest low-NO{sub x} burner capable of achieving very low NO{sub x}. The burner is designed to reduce NO{sub x} by diverting air away from the core of the flame, which reduces local stoichiometry during coal devolatilization and, thereby, reduces initial NO{sub x} formation. Figure 1.2 shows the historical NO{sub x} emission levels from different B&W burners. Figure 1.2 shows that based on three large-scale commercial installations of the DRB-4Z{trademark} burners in combination with OFA ports, using Western subbituminous coal, the NO{sub x} emissions ranged from 0.16 to 0.18 lb/10{sup 6} Btu. It appears that with continuing research and development the Ozone Transport Rule (OTR) emission level of 0.15 lb NO{sub x}/10{sup 6} Btu is within the reach of combustion modification techniques for boilers using western U.S. subbituminous coals. Although NO{sub x} emissions from the DRB-4Z{trademark} burner are nearing OTR emission level with subbituminous coals, the utility boiler owners that use bituminous coals can still benefit from the addition of an SNCR and/or SCR system in order to comply with the stringent NO{sub x} emission levels facing them.

  19. Crystalline matrices for the immobilization of plutonium and actinides

    Energy Technology Data Exchange (ETDEWEB)

    Anderson, E.B.; Burakov, E.E.; Galkin, Ya.B.; Starchenko, V.A.; Vasiliev, V.G. [V.G. Khlopin Radium Institute, St. Petersburg (Russian Federation)


    The management of weapon plutonium, disengaged as a result of conversion, is considered together with the problem of the actinide fraction of long-lived high level radioactive wastes. It is proposed to use polymineral ceramics based on crystalline host-phases: zircon ZrSiO{sub 4} and zirconium dioxide ZrO{sub 2}, for various variants of the management of plutonium and actinides (including the purposes of long-term safe storage or final disposal from the human activity sphere). It is shown that plutonium and actinides are able to form with these phases on ZrSiO{sub 4} and ZrO{sub 2} was done on laboratory level by the hot pressing method, using the plasmochemical calcination technology. To incorporate simulators of plutonium into the structure of ZrSiO{sub 4} and ZrO{sub 2} in the course of synthesis, an original method developed by the authors as a result of studying the high-uranium zircon (Zr,U) SiO{sub 4} form Chernobyl {open_quotes}lavas{close_quotes} was used.


    Energy Technology Data Exchange (ETDEWEB)

    Maxwell, S.; Culligan, B.; Noyes, G.


    A new rapid method for the determination of actinides in soil and sediment samples has been developed at the Savannah River Site Environmental Lab (Aiken, SC, USA) that can be used for samples up to 2 grams in emergency response situations. The actinides in soil method utilizes a rapid sodium hydroxide fusion method, a lanthanum fluoride soil matrix removal step, and a streamlined column separation process with stacked TEVA, TRU and DGA Resin cartridges. Lanthanum was separated rapidly and effectively from Am and Cm on DGA Resin. Vacuum box technology and rapid flow rates are used to reduce analytical time. Alpha sources are prepared using cerium fluoride microprecipitation for counting by alpha spectrometry. The method showed high chemical recoveries and effective removal of interferences. This new procedure was applied to emergency soil samples received in the NRIP Emergency Response exercise administered by the National Institute for Standards and Technology (NIST) in April, 2009. The actinides in soil results were reported within 4-5 hours with excellent quality.

  1. Development of ion beam sputtering techniques for actinide target preparation (United States)

    Aaron, W. S.; Zevenbergen, L. A.; Adair, H. L.


    Ion beam sputtering is a routine method for the preparation of thin films used as targets because it allows the use of a minimum quantity of starting material, and losses are much lower than most other vacuum deposition techniques. Work is underway in the Isotope Research Materials Laboratory (IRML) at ORNL to develop the techniques that will make the preparation of actinide targets up to 100 μg/cm 2 by ion beam sputtering a routinely available service from IRML. The preparation of the actinide material in a form suitable for sputtering is a key to this technique, as is designing a sputtering system that allows the flexibility required for custom-ordered target production. At present, development work is being conducted on low-activity actinides in a bench-top system. The system will then be installed in a hood or glove box approved for radioactive materials handling where processing of radium, actinium, and plutonium isotopes among others will be performed.

  2. Advances in Metallic Fuels for High Burnup and Actinide Transmutation

    Energy Technology Data Exchange (ETDEWEB)

    Hayes, S. L.; Harp, J. M.; Chichester, H. J. M.; Fielding, R. S.; Mariani, R. D.; Carmack, W. J.


    Research and development activities on metallic fuels in the US are focused on their potential use for actinide transmutation in future sodium fast reactors. As part of this application, there is a desire to demonstrate a multifold increase in burnup potential. A number of metallic fuel design innovations are under investigation with a view toward significantly increasing the burnup potential of metallic fuels, since higher discharge burnups equate to lower potential actinide losses during recycle. Promising innovations under investigation include: 1) lowering the fuel smeared density in order to accommodate the additional swelling expected as burnups increase, 2) utilizing an annular fuel geometry for better geometrical stability at low smeared densities, as well as the potential to eliminate the need for a sodium bond, and 3) minor alloy additions to immobilize lanthanide fission products inside the metallic fuel matrix and prevent their transport to the cladding resulting in fuel-cladding chemical interaction. This paper presents results from these efforts to advance metallic fuel technology in support of high burnup and actinide transmutation objectives. Highlights include examples of fabrication of low smeared density annular metallic fuels, experiments to identify alloy additions effective in immobilizing lanthanide fission products, and early postirradiation examinations of annular metallic fuels having low smeared densities and palladium additions for fission product immobilization.

  3. Behavior of actinides in the Integral Fast Reactor fuel cycle

    Energy Technology Data Exchange (ETDEWEB)

    Courtney, J.C. [Louisiana State Univ., Baton Rouge, LA (United States). Nuclear Science Center; Lineberry, M.J. [Argonne National Lab., Idaho Falls, ID (United States). Technology Development Div.


    The Integral Fast Reactor (IFR) under development by Argonne National Laboratory uses metallic fuels instead of ceramics. This allows electrorefining of spent fuels and presents opportunities for recycling minor actinide elements. Four minor actinides ({sup 237}Np, {sup 240}Pu, {sup 241}Am, and {sup 243}Am) determine the waste storage requirements of spent fuel from all types of fission reactors. These nuclides behave the same as uranium and other plutonium isotopes in electrorefining, so they can be recycled back to the reactor without elaborate chemical processing. An experiment has been designed to demonstrate the effectiveness of the high-energy neutron spectra of the IFR in consuming these four nuclides and plutonium. Eighteen sets of seven actinide and five light metal targets have been selected for ten day exposure in the Experimental Breeder Reactor-2 which serves as a prototype of the IFR. Post-irradiation analyses of the exposed targets by gamma, alpha, and mass spectroscopy are used to determine nuclear reaction-rates and neutron spectra. These experimental data increase the authors` confidence in their ability to predict reaction rates in candidate IFR designs using a variety of neutron transport and diffusion programs.

  4. Actinides and lanthanides under pressure: the pseudopotential approach; Actinides et terres rares sous pression: approche pseudopotentiel

    Energy Technology Data Exchange (ETDEWEB)

    Richard, N


    In the Density Functional Theory Framework, the pseudopotential formalism offers a broader scope of study than other theoretical methods such as global relaxation of the parameters of the cell or ab initio molecular dynamics simulations. This method has been widely used to study light elements or transition metals but never to study f elements. We have generated two non local norm conserving Trouillier-Martins pseudopotentials (one in LDA and one in GGA) for the cerium. To check the validity of the pseudopotentials, we have calculated the equilibrium volume and the incompressibility modulus and compared our results to previous all-electron calculations. If the GGA and non linear core corrections are used, the equation of state is in a good agreement with the experimental equation of state. A static study of the previously proposed high pressure phases give a transitions fcc-a''(I)-bct. Using the pseudopotentials we have generated, an ab initio molecular dynamics simulation at constant pressure, in the region between 5 and 12 GPa where the stable phase of cerium is not well defined, lead us to predict that a centred monoclinic structure, as the a''(I) phase previously observed in some experiments, is the most stable phase. We have also generated pseudopotentials for the light actinides (Th, Pa, U and Np). We have study their phase transitions under pressure at zero temperature. We compared our results with all electron results. The structure parameters have always been relaxed in this study. And for the first time in pseudopotential calculation, the spin-orbit coupling has been taken into account. The curves describing the variation of the volume or the incompressibility modulus depending on the elements and the phase transitions are always in agreement with the one found in the all electron calculations. (author)

  5. Chemical properties of the trans-actinide elements studied in liquid phase with SISAK

    Energy Technology Data Exchange (ETDEWEB)

    Omtvedt, J.P.; Alstad, J.; Bjornstad, T.; Opel, K.; Polakova, D.; Samadani, F.; Schulz, F.; Stavsetra, L.; Zheng, L. [Oslo Univ., Centre for Accelerator based Research and Energy Physics (SAFE) (Norway); Dullmann, Ch.E; Gregorich, K.E.; Hoffman, D.C.; Nitsche, H.; Sudowe, R. [Lawrence Berkeley National Laboratory (LBNL), Nuclear Science Div., One Cyclotron Road, Berkeley, CA (United States); Dullmann, Ch.E.; Hoffman, D.C.; Nitsche, H. [California Univ., Dept. of Chemistry, Berkeley, CA (United States); Skarnemark, G. [Chalmers Univ. of Technology, Nuclear Chemistry, Dept. of Chemical and Biological Engineering (Sweden)


    This article starts with a review of the current SISAK liquid-liquid extraction system, as used after the physical pre-separator BGS (Berkeley Gas-filled Separator) at Lawrence Berkeley National Laboratory (LBNL) for chemical studies of trans-actinide elements. Emphasis will be on new additions and developments. Then the possibilities offered by the new TASCA (Trans-Actinide Separator and Chemistry Apparatus) separator at GSI (Darmstadt, Germany) and the use of actinide targets at both GSI and LBNL are discussed with respect to future SISAK trans-actinide experiments. Finally, current and future liquid-liquid extraction systems for studying elements Rutherfordium up to Hassium are discussed. (authors)

  6. Advanced processes for minor actinides recycling: studies towards potential industrialization

    Energy Technology Data Exchange (ETDEWEB)

    Rostaing, C.; Baron, P.; Warin, D.; Duhamet, J.; Ochem, D. [CEA, Bagnols sur Ceze, Gard 30207 (France)


    In June 2006, a new act on sustainable management of radioactive waste was voted by the French parliament with a national plan on radioactive materials and radioactive waste management (PNG-MDR). Concerning partitioning and transmutation, the program is connected to 4. generation reactors, in which transmutation of minor actinides could be operated. In this frame, the next important milestone is 2012, with the assessment of the possible transmutation roads, which are either homogeneous recycling of the minor actinides in the whole reactor fleet, with a low content of M.A ({approx}3%) in all fuel assemblies, or heterogeneous recycling of the minor actinides in about one third of the reactor park, with a higher content of M.A. ({approx}20%) in dedicated targets dispatched in the periphery of the reactor. Advanced processes for the recycling of minor actinides are being developed to address the challenges of these various management options. An important part of the program consists in getting closer to process implementation conditions. The processes based on liquid-liquid extraction benefit from the experience gained by operating the PUREX process at the La Hague plant. In the field of extracting apparatus, a large experience is available. In the field of extracting apparatus, a large experience is already available. Nevertheless, the processes present specificities which have to be considered more precisely. They have been classified in the following fields: - Evolution of the simulation codes, including phenomenological representations: with such a simulation tool, it will be possible to assess operating tolerances, lead sensitivity studies and calculate transient states; - Definition of the implementation conditions in continuous contactors (such as pulse columns), according to the extractant physico-chemical characteristics; - Scale-up of new extractants, such as malonamides used in the DIAMEX process, facing purity specifications and costs estimation; - Solvent

  7. Trust and Competing Orders of Worth in Organizations

    DEFF Research Database (Denmark)

    Jagd, Søren

    Trust is a multi-dimensional concept. This paper suggests that a fruitful framework for bringing order to this multi-dimensionality of the trust concept is the order of worth framework developed by Luc Boltanski and Laurent Thévenot (Boltanski and Thévenot, 2006). The paper explores how trust is ...... is conceptualized differently in the seven orders of worth highlighted by Boltanski and Thévenot. Last I discuss how this perspective of competing forms of trust may contribute to trust research in organizations....

  8. Confronting the "Bra-Burners": Teaching Radical Feminism with a Case Study (United States)

    Kreydatus, Beth


    In many of the U.S. History courses the author has taught, she has encountered students who refer to the second-wave feminists of the 1960s and 1970s as "bra-burners." Unsurprisingly, these students know very little about the origin of this epithet, and frequently, they know even less about the women's movement generally. Second-wave feminism, and…


    Sonotech, Inc. (Sonotech) of Atlanta, Georgia, has developed a pulse combustion burner technology that claims to offer benefits when applied in a variety of combustion processes. The technology incorporates a combustor that can be tuned to induce large-amplitude acoustic or soni...

  10. Formation of nitric oxide in an industrial burner measured by 2-D laser induced fluorescence

    Energy Technology Data Exchange (ETDEWEB)

    Arnold, A.; Bombach, R.; Kaeppeli, B. [Paul Scherrer Inst. (PSI), Villigen (Switzerland)


    We have performed two-dimensional Laser Induced Fluorescence (2-D LIF) measurements of nitric oxide and hydroxyl radical distributions in an industrial burner at atmospheric pressure. The relative 2-D LIF data of NO were set to an absolute scale by calibration with probe sampling combined with gas analysis. (author) 3 figs., 7 refs.

  11. ASU nitrogen sweep gas in hydrogen separation membrane for production of HRSG duct burner fuel (United States)

    Panuccio, Gregory J.; Raybold, Troy M.; Jamal, Agil; Drnevich, Raymond Francis


    The present invention relates to the use of low pressure N2 from an air separation unit (ASU) for use as a sweep gas in a hydrogen transport membrane (HTM) to increase syngas H2 recovery and make a near-atmospheric pressure (less than or equal to about 25 psia) fuel for supplemental firing in the heat recovery steam generator (HRSG) duct burner.

  12. Improvement of cyclic operation on pulverized coal fired boilers by applying wide range burners

    Energy Technology Data Exchange (ETDEWEB)

    Yamada, Toshihiko; Watanabe, Shinji; Kiga, Takashi; Koyata, Kazuo


    There are recently urgent requirements to operate pulverized coal fired power plants as well as oil fired units cyclically or at low loads. In order to cope with this, wide range burners (WRB) were jointly developed to obtain a high turndown operation by the Central Research Institute of Electric Power Industry (CRIEPI) and Ishikawajima-Harima Heavy Industries Co., Ltd. (IHI). In accordance with the results of various fundamental researches, including combustion tests with a tunnel furnace of 12 MW[thermal], it was confirmed the stability of the flame and the combustion characteristics at low loads as well as that of ordinary burners. The WRB have been applied to the new actual boilers that are Saijo Power Station NO. 2 unit of Sikoku Electric Power Co., Inc., Nanao-Ota Power Station NO. 2 unit of Hokuriku Electric Power Co., Inc. and Miike Power Station NO. 1 unit of Miike Thermal Power Co., Ltd.. The results of the trial operation have shown that the minimum burner load was below half of that of conventional burners, and accordingly the pulverized coal firing minimum load could be reduced. This paper explains about the cyclic operation of their boilers and the improvement effect by applying WRBs.

  13. Control of flames by tangential jet actuators in oxy-fuel burners

    Energy Technology Data Exchange (ETDEWEB)

    Boushaki, Toufik [CORIA UMR 6614 CNRS-Universite et INSA de ROUEN, Site Universitaire du Madrillet, 76801 Saint Etienne du Rouvray, Cedex (France); Universite de Toulouse-INPT-UPS, IMFT (Institut de Mecanique des Fluides de Toulouse), Allee Camille Soula, F-31400 Toulouse, Cedex (France); Sautet, Jean-Charles [CORIA UMR 6614 CNRS-Universite et INSA de ROUEN, Site Universitaire du Madrillet, 76801 Saint Etienne du Rouvray, Cedex (France); Labegorre, Bernard [Air Liquide, Centre de Recherche Claude-Delorme, Les Loges-en-Josas, B.P. 126 78354 Jouy-en-Josas, Cedex (France)


    The active control of oxy-fuel flames from burners with separated jets is investigated. The control system consists of four small jet actuators, placed tangential to the exit of the main jets to generate a swirling flow. These actuators are able to modify the flow structure and to act on mixing between the reactants and consequently on the flame behavior. The burner (25 kW) is composed of separated jets, one jet of natural gas and one or two jets of pure oxygen. Experiments are conducted with three burner configurations, according to the number of jets, the jet exit velocities, and the separation distance between the jets. OH chemiluminescence measurements, particle image velocimetry, and measurements of NO{sub x} emissions are used to characterize the flow and the flame structure. Results show that the small jet actuators have a significant influence on the behavior of jets and the flame characteristics, particularly in the stabilization zone. It is shown that the control leads to a decrease in lift-off heights and to better stability of the flame. The use of jet actuators induces high jet spreading and an increase in turbulence intensity, which improves the mixing between the reactants and the surrounding fluid. Pollutant measurements show important results in terms of NO{sub x} reductions (up to 60%), in particular for low swirl intensity. The burner parameters, such as the number of jets and the spacing between the jets, also impact the flame behavior and NO{sub x} formation. (author)

  14. Research and Development of Natural Draft Ultra-Low Emissions Burners for Gas Appliances

    Energy Technology Data Exchange (ETDEWEB)

    Therkelsen, Peter [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Cheng, Robert [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Sholes, Darren [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)


    Combustion systems used in residential and commercial cooking appliances must be robust and easy to use while meeting air quality standards. Current air quality standards for cooking appliances are far greater than other stationary combustion equipment. By developing an advanced low emission combustion system for cooking appliances, the air quality impacts from these devices can be reduced. This project adapted the Lawrence Berkeley National Laboratory (LBNL) Ring-Stabilizer Burner combustion technology for residential and commercial natural gas fired cooking appliances (such as ovens, ranges, and cooktops). LBNL originally developed the Ring-Stabilizer Burner for a NASA funded microgravity experiment. This natural draft combustion technology reduces NOx emissions significantly below current SCAQMD emissions standards without post combustion treatment. Additionally, the Ring-Stabilizer Burner technology does not require the assistance of a blower to achieve an ultra-low emission lean premix flame. The research team evaluated the Ring-Stabilizer Burner and fabricated the most promising designs based on their emissions and turndown.

  15. Comparison of heat transfer and soil impacts of air curtain burner burning and slash pile burning (United States)

    Woongsoon Jang; Deborah S. Page-Dumroese; Han-Sup Han


    We measured soil heating and subsequent changes in soil properties between two forest residue disposal methods: slash pile burning (SPB) and air curtain burner (ACB). The ACB consumes fuels more efficiently and safely via blowing air into a burning container. Five burning trials with different fuel sizes were implemented in northern California, USA. Soil temperature...

  16. Characteristics of premixed flames stabilized in an axisymmetric curved-wall jet burner with tip modification

    KAUST Repository

    Kim, Daejoong


    The stabilization characteristics of premixed flames in an axisymmetric curved-wall jet burner have been experimentally investigated. This burner utilized the Coanda effect on top of a burner tip. The initially spherical burner tip was modified to a flat tip and a concave tip in order to improve flame stabilization by providing enough space for flow recirculation above the burner tip region. The flow characteristics have been visualized using a schlieren technique. Small-scale turbulence structure has been observed mainly in the interaction jet region (located downstream of the recirculation region) for large jet velocity (Reynolds number >11,500). An appreciable amount of air entrainment was exhibited from the half-angle of the jet spread, approximately 20. The averaged planar laser-induced fluorescence images of the flames for this large velocity demonstrated that the strong signal of OH radicals, representing reaction zones, existed in the recirculation zone, while it was weak in the interaction jet region due to intermittency and local extinction by the generation of small scale turbulence. The OH radical signals strengthened again in the merged jet region (downstream of the interaction jet region). In extreme cases of Reynolds number over 19,000, a unique flame exhibiting OH radicals only in the recirculation zone was observed for the concave tip. The flame stabilization has been mapped by varying jet velocity and equivalence ratio, and the result showed that the stabilization characteristics were improved appreciably from the initial spherical tip design, especially for rich mixtures. The flow fields measured by a laser Doppler velocimetry confirmed the existence of recirculation zone and the expansion of the recirculation zones for the modified tips. The temperature profile measured by a coherent anti-Stokes Raman spectroscopy exhibited an intermittent nature, especially near the recirculation zone.

  17. Low NO sub x /SO sub x Burner retrofit for utility cyclone boilers

    Energy Technology Data Exchange (ETDEWEB)


    The objective of this project is to demonstrate the LNS Burner as retrofitted to the host cyclone boiler for effective low-cost control of NO{sub x} and SO{sub x} emissions while firing a bituminous coal. The LNS Burner employs a simple, innovative combustion process to burn pulverized coal at high temperatures and provides effective, low-cost control of sulfur dioxide (SO{sub 2}) and nitrogen oxides (NO{sub x}) emissions. The coal ash contains sulfur and is removed in the form of molten slag and flyash. Cyclone-fired boiler units are typically older units firing high-sulfur bituminous coals at very high temperatures which results in very high NO{sub x} and SO{sub x} emissions. The addition of conventional emission control equipment, such as wet scrubbers, to these older cyclone units in order to meet current and future environmental regulations is generally not economic. Further, the units are generally not compatible with low sulfur coal switching for S0{sub 2} control or selective catalytic reduction technologies for NO{sub x} control. Because the LNS Burner operates at the same very high temperatures as a typical cyclone boiler and produces a similar slag product, it may offer a viable retrofit option for cyclone boiler emission control. This was confirmed by the Cyclone Boiler Retrofit Feasibility Study carried out by TransAlta and an Operating Committee formed of cyclone boiler owners in 1989. An existing utility cyclone boiler, was then selected for the evaluation of the cost and performance study. It was concluded that the LNS Burner retrofit would be a cost-effective option for control of cyclone boiler emissions. A full-scale demonstration of the LNS Burner retrofit was selected in October 1988 as part of the DOE's Clean Coal Technology Program Round II.

  18. Theoretical investigation on electronic and mechanical properties of ternary actinide (U, Np, Pu) nitrides (United States)

    Zhang, Yu-Juan; Zhou, Zhang-Jian; Lan, Jian-Hui; Bo, Tao; Ge, Chang-Chun; Chai, Zhi-Fang; Shi, Wei-Qun


    Actinide mononitrides as a promising advanced nuclear fuel have recently earned much attention. We herein studied the electronic and mechanical properties of the ternary actinide mixed mononitrides A0.5B0.5 N (A, B = U, Np, and Pu) using the density functional theory +U method. It is found that in the studied ternary mixed mononitrides, the 5f electronic states of all actinide atoms maintain the local electronic character and do not overlap with each other. Compared with their corresponding binary mononitrides, the U-N bond becomes more ionic, where the Np-N and Pu-N bonds become more covalent in ternary actinide mixed mononitrides. The mechanical properties (such as bulk and shear moduli, Young's modulus, and Poisson's ratio) of three ternary actinide (U-Pu) mononitrides are found to be similar to that of their corresponding binary actinide mononitrides and thus are expected not to misbehave with actinide mononitrides in respect of mechanics. In addition, all the three ternary actinide mononitrides have no imaginary frequencies in their vibration curves and correspondingly satisfy the stability criteria for elastic constants of tetragonal structures.

  19. Polymer Inclusion Membrane Containing a Tripodal Diglycolamide Ligand: Actinide Ion Uptake and Transport Studies

    NARCIS (Netherlands)

    Mahanty, B.; Mohapatra, P.K.; Raut, D.R.; Das, D.K.; Behere, P.G.; Afzal, M.; Verboom, Willem


    A cellulose triacetate (CTA)-based polymer inclusion membrane (PIM) containing a C-pivot tripodal diglycolamide (T-DGA) as the carrier extractant and 2-nitrophenyl octyl ether (NPOE) as the plasticizer shows potential for the uptake of actinides from acidic feed solutions. The uptake of actinides

  20. Screening Evaluation of Sodium Nonatitanate for Strontium and Actinide Removal from Alkaline Salt Solution

    Energy Technology Data Exchange (ETDEWEB)

    Hobbs, D.T.


    This report describes results from screening tests evaluating strontium and actinide removal characteristics of a sodium titanate material developed by Clearfield and coworkers at Texas A and M University and offered commercially by Honeywell. Sodium nonatitanate may exhibit improved actinide removal kinetics and filtration characteristics compared to MST and thus merit testing.

  1. Invisible structures in the X-ray absorption spectra of actinides

    NARCIS (Netherlands)

    Kvashnina, Kristina O.; De Groot, Frank M F|info:eu-repo/dai/nl/08747610X

    The X-ray absorption spectra of actinides are discussed with an emphasis on the fundamental effects that influence their spectral shape, including atomic multiplet theory, charge transfer theory and crystal field theory. Many actinide spectra consist of a single peak and it is shown that the use of

  2. 76 FR 5307 - Net Worth Standard for Accredited Investors (United States)


    ...) requires the definitions of ``accredited investor'' in our Securities Act rules to exclude the value of a... estimated fair market value of the property.''As so amended, the accredited investor net worth standards in...'' of the investor. How should the ``value of the primary residence'' be determined for purposes of...

  3. Book Review: What’s worth fighting for in education?


    Fatma Kayan


    The review discusses “What’s worth fighting for in education?” by Andy Hargreaves and Michael Fullan. While the book is now 10 years old, the problems of determining the important issues in school (and higher) education and fostering collaborative links between schools and the communities which they serve are as critical now as they have ever been.

  4. Gender Differences in Comparisons and Entitlement: Implications for Comparable Worth. (United States)

    Major, Brenda


    Addresses the role of comparison processes in the persistence of the gender wage gap, its toleration by those disadvantaged by it, and resistance to comparable worth as a corrective strategy. Argues that gender segregation and undercompensation for women's jobs leads women to use different comparison standards when evaluating what they deserve.…

  5. Evaluation of reliability worth in an electric power system

    Energy Technology Data Exchange (ETDEWEB)

    Billinton, Roy [Saskatchewan Univ., Saskatoon, SK (Canada). Power System Research Group


    This paper illustrates the application of basic power system reliability evaluation techniques to the quantification for reliability worth. The approach presented links customer interruption cost estimates with predictable indices of power system reliability. The technique is illustrated by application in the areas of generation, composite generation and transmission, and distribution system assessment using a hypothetical test system. (author)

  6. Control rod worth calculations using deterministic and stochastic methods

    Energy Technology Data Exchange (ETDEWEB)

    Varvayanni, M. [NCSR ' DEMOKRITOS' , PO Box 60228, 15310 Aghia Paraskevi (Greece); Savva, P., E-mail: melina@ipta.demokritos.g [NCSR ' DEMOKRITOS' , PO Box 60228, 15310 Aghia Paraskevi (Greece); Catsaros, N. [NCSR ' DEMOKRITOS' , PO Box 60228, 15310 Aghia Paraskevi (Greece)


    Knowledge of the efficiency of a control rod to absorb excess reactivity in a nuclear reactor, i.e. knowledge of its reactivity worth, is very important from many points of view. These include the analysis and the assessment of the shutdown margin of new core configurations (upgrade, conversion, refuelling, etc.) as well as several operational needs, such as calibration of the control rods, e.g. in case that reactivity insertion experiments are planned. The control rod worth can be assessed either experimentally or theoretically, mainly through the utilization of neutronic codes. In the present work two different theoretical approaches, i.e. a deterministic and a stochastic one are used for the estimation of the integral and the differential worth of two control rods utilized in the Greek Research Reactor (GRR-1). For the deterministic approach the neutronics code system SCALE (modules NITAWL/XSDRNPM) and CITATION is used, while the stochastic one is made using the Monte Carlo code TRIPOLI. Both approaches follow the procedure of reactivity insertion steps and their results are tested against measurements conducted in the reactor. The goal of this work is to examine the capability of a deterministic code system to reliably simulate the worth of a control rod, based also on comparisons with the detailed Monte Carlo simulation, while various options are tested with respect to the deterministic results' reliability.

  7. Experience composite worth: A combination of experience quality ...

    African Journals Online (AJOL)

    This research suggests that experience quality and experience value be combined into a single multi-dimensional construct, termed experience composite worth. It briefly describes customer experience, experience quality and experience value and the overlap in the dimensions used in outlining experience quality and ...

  8. Report on Adolescent Pregnancy in Fort Worth, Texas. (United States)

    Tees, Sandra

    Teenage pregnancy is an overwhelming problem in Fort Worth, Texas. To examine the problem of teenage pregnancy, figures on total live births by age, race, repeat pregnancy, and at-risk infants were gathered from 1981 and 1982 Department of Public Health data. In addition, consequences of teenage pregnancy and motivation factors were examined. An…

  9. Impurities that cause difficulty in stripping actinides from commercial tetraalkylcarbamoylmethylphosphonates

    Energy Technology Data Exchange (ETDEWEB)

    Bahner, C. T.; Shoun, R. R.; McDowell, W. J.


    Dihexyl((diethylcarbamoyl)methyl)phosphonate (DHDECMP) in diethylbenzene extracts actinides well from 6 M nitric acid solution, but commercially available DHDECMP contains impurities which interfere with stripping the actinides from the organic extract. DHDECMP purified by molecular distillation does not contain these impurities, but the pot residue contains increased concentrations of them. Heating the purified DHDECMP causes the formation of products which interfere with stripping in the same way, suggesting that high temperatures employed in the manufacture of DHDECMP may produce the offending impurities. These impurities can be separated from the heat-decomposed material or the pot residues by dilution with a large volume of hexanes (causing part of the impurities to separate as a second liquid phase) followed by equilibration of the hexane solution with dilute alkali. After the treatment with hexane and dilute alkali, the DHDECMP is readily recovered and functions well in the actinide extraction process. Dibutyl((dibutylcarbamoyl)methyl)-phosphonate (DBDBCMP) and di(2-ethylhexyl)((diethylcarbamoyl)-methyl)phosphonate (DEHDECMP) are purified less effectively by these methods. Similar separation methods using diethylbenzene or CCl/sub 4/ as solvent do not remove impurities as completely as the hexane process. Impurities can also be removed from a benzene solution of the DHDECMP pot residue by passing it through a column packed with silica gel or diethylaminoethyl cellulose. These impurities have been separated into fractions for analytical examination by use of various solvents and by column chromatography. Hexyl hydrogen ((diethylcarbamoyl)methyl)-phosphonate has been identified tentatively as a principal objectionable impurity. Dihexyl phosphoric acid and possibly dihexylphosphonate have been identified in other fractions.

  10. Detection of the actinides and cesium from environmental samples (United States)

    Snow, Mathew Spencer

    Detection of the actinides and cesium in the environment is important for a variety of applications ranging from environmental remediation to safeguards and nuclear forensics. The utilization of multiple different elemental concentrations and isotopic ratios together can significantly improve the ability to attribute contamination to a unique source term and/or generation process; however, the utilization of multiple elemental "signatures" together from environmental samples requires knowledge of the impact of chemical fractionation for various elements under a variety of environmental conditions (including predominantly aqueous versus arid conditions). The research reported in this dissertation focuses on three major areas: 1. Improving the understanding of actinide-mineral interactions at ultra-low concentrations. Chapter 2 reports a batch sorption and modeling study of Np(V) sorption to the mineral goethite from attomolar to micromolar concentrations. 2. Improving the detection capabilities for Thermal Ionization Mass Spectrometry (TIMS) analyses of ultra-trace cesium from environmental samples. Chapter 4 reports a new method which significantly improves the chemical yields, purification, sample processing time, and ultimately, the detection limits for TIMS analyses of femtogram quantities of cesium from a variety of environmental sample matrices. 3. Demonstrating how actinide and cesium concentrations and isotopic ratios from environmental samples can be utilized together to determine a wealth of information including environmental transport mechanisms (e.g. aqueous versus arid transport) and information on the processes which generated the original material. Chapters1, 3 and 5 demonstrate these principles using Pu, Am, Np, and Cs concentrations and isotopic ratios from contaminated soils taken near the Subsurface Disposal Area (SDA) of Idaho National Laboratory (INL) (a low level radioactive waste disposal site in southeastern Idaho).

  11. Electronic structure and ionicity of actinide oxides from first principles

    DEFF Research Database (Denmark)

    Petit, Leon; Svane, Axel; Szotek, Z.


    The ground-state electronic structures of the actinide oxides AO, A2O3, and AO2 (A=U, Np, Pu, Am, Cm, Bk, and Cf) are determined from first-principles calculations, using the self-interaction corrected local spin-density approximation. Emphasis is put on the degree of f-electron localization, which...... for AO2 and A2O3 is found to follow the stoichiometry, namely, corresponding to A4+ ions in the dioxide and A3+ ions in the sesquioxides. In contrast, the A2+ ionic configuration is not favorable in the monoxides, which therefore become metallic. The energetics of the oxidation and reduction...

  12. Comparison of fission and capture cross sections of minor actinides

    CERN Document Server

    Nakagawa, T


    The fission and capture cross sections of minor actinides given in JENDL-3.3 are compared with other evaluated data and experimental data. The comparison was made for 32 nuclides of Th-227, 228, 229, 230, 233, 234, Pa-231, 232, 233, U-232, 234, 236, 237, Np-236, 237, 238, Pu-236, 237, 238, 242, 244, Am-241, 242, 242m, 243, Cm-242, 243, 244, 245, 246, 247 and 248. Given in the present report are figures of these cross sections and tables of cross sections at 0.0253 eV and resonance integrals.

  13. Detection of Actinides via Nuclear Isomer De-Excitation

    Energy Technology Data Exchange (ETDEWEB)

    Francy, Christopher J. [Oregon State Univ., Corvallis, OR (United States)


    This dissertation discusses a data collection experiment within the Actinide Isomer Identification project (AID). The AID project is the investigation of an active interrogation technique that utilizes nuclear isomer production, with the goal of assisting in the interdiction of illicit nuclear materials. In an attempt to find and characterize isomers belonging to 235U and its fission fragments, a 232Th target was bombarded with a monoenergetic 6Li ion beam, operating at 45 MeV.

  14. Dipole strength functions in the actinide mass region

    Energy Technology Data Exchange (ETDEWEB)

    Gardner, D.G.; Gardner, M.A.; Hoff, R.W.


    We have calculated a number of neutron- and photon-induced reactions for the actinide nuclei /sup 232/Th, /sup 238/U, and /sup 237/Np. By fitting average resonance capture (ARC) measurements and total neutron capture data, we deduced absolute dipole strength functions for /sup 233/Th and /sup 239/U. We have found that the M1/E1 ratio is the same as in the /sup 176/Lu case, but the total transition strength was larger by about 27%. 17 refs., 4 figs., 1 tab.

  15. Burners. Reduction of nitrogen oxides in combustion: 2. generation of GR LONOxFLAM burner; Les bruleurs. La reduction des oxydes d`azote dans la combustion: bruleur GR LONOxFLAM de 2. generation

    Energy Technology Data Exchange (ETDEWEB)

    Gauthier, J.C. [EGCI Pillard, 13 - Marseille (France)


    This paper presents the research work carried out by the French Pillard company in collaboration with Gaz de France for the design of low NO{sub x} burners. The different type of low NO{sub x} burners are presented according to the type of fuel: gas, liquid fuels and fuel oils. The gas burner uses the fuel staging principle and the recirculation of smokes and leads to NO{sub x} emissions lower than 100 mg/Nm{sup 3}. The liquid fuel and fuel oil burners use the separate flames and the smoke self-recirculation methods (fuel-air mixture staging, reduction of flame temperature and of the residence time in flames). (J.S.)

  16. Burners. The decrease of nitrogen oxides in combustion process: the 2 nd generation GR LONOxFLAM burner; Les bruleurs, la reduction des oxydes d`azote dans la combustion: bruleur GR LONOxFLAM de 2. generation

    Energy Technology Data Exchange (ETDEWEB)

    Gauthier, J.C. [EGCI Pillard, 13 - Marseille (France)


    The Pillard company has developed, in cooperation with GDF (the French national gas utility), the GR-LONOxFLAM burner concept for reducing NOx emission levels and solid combustion products. The concept consists, for gaseous fuels, in the combination of an internal recirculation and a gas staging process; for liquid fuels, a separated flame process and air staging are combined. These concepts allow for an important reduction in NOx and non-burned residues, even with standard-size burners

  17. IR sensor for monitoring of burner flame; IR sensor foer oevervakning av braennarflamma

    Energy Technology Data Exchange (ETDEWEB)

    Svanberg, Marcus; Funkquist, Jonas; Clausen, Soennik; Wetterstroem, Jonas


    To obtain a smooth operation of the coal-fired power plants many power plant managers have installed online mass flow measurement of coal to all burners. This signal is used to monitor the coal mass flow to the individual burner and match it with appropriate amount of air and also to monitor the distribution of coal between the burners. The online mass flow measurement system is very expensive (approximately 150 kEUR for ten burners) and is not beneficial for smaller plants. The accuracy of the measurement and the sample frequency are also questionable. The idea in this project has been to evaluate a cheaper system that can present the same information and may also provide better accuracy and faster sample frequency. The infrared sensor is a cheap narrow banded light emission sensor that can be placed in a water cooed probe. The sensor was directed at the burner flame and the emitted light was monitored. Through calibration the mass flow of coal can be presented. Two measurement campaigns were performed. Both campaigns were carried out in Nordjyllandsverket in Denmark even though the second campaign was planned to be in Uppsala. Due to severe problems in the Uppsala plant the campaign was moved to Nordjyllandsverket. The pre-requisites for the test plant were that online measurement of coal flow was installed. In Nordjyllandsverket 4 out of 16 burners have the mass flow measurement installed. Risoe Laboratories has vast experiences in the IR technology and they provided the IR sensing equipment. One IR sensor was placed in the flame guard position just behind the flame directed towards the ignition zone. A second sensor was placed at the boiler wall directed towards the flame. The boiler wall position did not give any results and the location was not used during the second campaign. The flame-guard-positioned-sensor- signal was thoroughly evaluated and the results show that there is a clear correlation between the coal mass flow and the IR sensor signal. Tests were

  18. Actinide production from xenon bombardments of curium-248

    Energy Technology Data Exchange (ETDEWEB)

    Welch, R.B.


    Production cross sections for many actinide nuclides formed in the reaction of /sup 129/Xe and /sup 132/Xe with /sup 248/Cm at bombarding energies slightly above the coulomb barrier were determined using radiochemical techniques to isolate these products. These results are compared with cross sections from a /sup 136/Xe + /sup 248/Cm reaction at a similar energy. When compared to the reaction with /sup 136/Xe, the maxima in the production cross section distributions from the more neutron deficient projectiles are shifted to smaller mass numbers, and the total cross section increases for the production of elements with atomic numbers greater than that of the target, and decreases for lighter elements. These results can be explained by use of a potential energy surface (PES) which illustrates the effect of the available energy on the transfer of nucleons and describes the evolution of the di-nuclear complex, an essential feature of deep-inelastic reactions (DIR), during the interaction. The other principal reaction mechanism is the quasi-elastic transfer (QE). Analysis of data from a similar set of reactions, /sup 129/Xe, /sup 132/Xe, and /sup 136/Xe with /sup 197/Au, aids in explaining the features of the Xe + Cm product distributions, which are additionally affected by the depletion of actinide product yields due to deexcitation by fission. The PES is shown to be a useful tool to predict the general features of product distributions from heavy ion reactions.

  19. Actinide Solubility and Speciation in the WIPP [PowerPoint

    Energy Technology Data Exchange (ETDEWEB)

    Reed, Donald T. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)


    The presentation begins with the role and need for nuclear repositories (overall concept, international updates (Sweden, Finland, France, China), US approach and current status), then moves on to the WIPP TRU repository concept (design, current status--safety incidents of February 5 and 14, 2014, path forward), and finally considers the WIPP safety case: dissolved actinide concentrations (overall approach, oxidation state distribution and redox control, solubility of actinides, colloidal contribution and microbial effects). The following conclusions are set forth: (1) International programs are moving forward, but at a very slow and somewhat sporadic pace. (2) In the United States, the Salt repository concept, from the perspective of the long-term safety case, remains a viable option for nuclear waste management despite the current operational issues/concerns. (3) Current model/PA prediction (WIPP example) are built on redundant conservatisms. These conservatisms are being addressed in the ongoing and future research to fill existing data gaps--redox control of plutonium by Fe(0, II), thorium (analog) solubility studies in simulated brine, contribution of intrinsic and biocolloids to the mobile concentration, and clarification of microbial ecology and effects.

  20. The EBR-II X501 Minor Actinide Burning Experiment

    Energy Technology Data Exchange (ETDEWEB)

    W. J. Carmack; M. K. Meyer; S. L. Hayes; H. Tsai


    The X501 experiment was conducted in EBR II as part of the Integral Fast Reactor program to demonstrate minor actinide burning through the use of a homogeneous recycle scheme. The X501 subassembly contained two metallic fuel elements loaded with relatively small quantities of americium and neptunium. Interest in the behavior of minor actinides (MA) during fuel irradiation has prompted further examination of existing X501 data and generation of new data where needed in support of the U.S. waste transmutation effort. The X501 experiment is one of the few MA bearing fuel irradiation tests conducted worldwide, and knowledge can be gained by understanding the changes in fuel behavior due to addition of MAs. Of primary interest are the effect of the MAs on fuel cladding chemical interaction and the redistribution behavior of americium. The quantity of helium gas release from the fuel and any effects of helium on fuel performance are also of interest. It must be stressed that information presented at this time is based on the limited PIE conducted in 1995–1996 and, currently, represents a set of observations rather than a complete understanding of fuel behavior. This report provides a summary of the X501 fabrication, characterization, irradiation, and post irradiation examination.

  1. Development of an advanced high efficiency coal combustor for boiler retrofit. Task 1, Cold flow burner development: Final report

    Energy Technology Data Exchange (ETDEWEB)

    LaFlesh, R.C.; Rini, M.J.; McGowan, J.G.


    The overall objective of this program is to develop a high efficiency advanced coal combustor (HEACC) for coal-based fuels capable of being retrofitted to industrial boilers originally designed for firing natural gas, distillate, and/or residual oil. The HEACC system is to be capable of firing microfine coal water fuel (MCWF), MCWF with alkali sorbent (for SO{sub 2} reduction), and dry microfine coal. Design priorities for the system are that it be simple to operate and will offer significant reductions in NO{sub x}, SO{sub x}, and particulate emissions as compared with current coal fired combustor technology. The specific objective of this report is to document the work carried out under Task 1.0 of this contract, ``Cold Flow Burner Development``. As are detailed in the report, key elements of this work included primary air swirler development, burner register geometry design, cold flow burner model testing, and development of burner scale up criteria.

  2. Experimental data regarding the characterization of the flame behavior near lean blowout in a non-premixed liquid fuel burner

    Directory of Open Access Journals (Sweden)

    Maria Grazia De Giorgi


    The data are related to the research article “Image processing for the characterization of flame stability in a non-premixed liquid fuel burner near lean blowout” in Aerospace Science and Technology [1].

  3. Combustion systems: a porous-matrix burner and a surface combustor. Topical report, June 1984-December 1985

    Energy Technology Data Exchange (ETDEWEB)

    Jasionowski, W.J.; Kunc, W.; Khinkis, M.J.; Zawacki, T.S.


    In this study, two combustion systems were experimentally evaluated for potential application to gas-fired appliances: an atmospheric porous-matrix burner and a packed-bed surface combustor. The normal radiant output of a porous matrix burner was measured over a range of input from 30,000 to 110,000 Btu/h-sq ft and aerations from 0% to 40% excess air. The data were compared to similar published data for radiant tile burners. Emissions of nitric oxide (NO), nitrogen dioxide (NO/sub 2/), and carbon monoxide (CO) were also measured and reported. The potential advantage of the type of burner is its ability to produce high levels of radiation heat at high gas-loading levels (Btu/h-sq ft.).

  4. Case Study: A Picture Worth a Thousand Words? Making a Case for Video Case Studies (United States)

    Pai, Aditi


    A picture, they say, is worth a thousand words. If a mere picture is worth a thousand words, how much more are "moving pictures" or videos worth? The author poses this not merely as a rhetorical question, but because she wishes to make a case for using videos in the traditional case study method. She recommends four main approaches of…

  5. 77 FR 20888 - Proposed Information Collection (Income, Net Worth, and Employment Statement) Activity: Comment... (United States)


    ... AFFAIRS Proposed Information Collection (Income, Net Worth, and Employment Statement) Activity: Comment... forms of information technology. Title: Income, Net Worth, and Employment Statement. OMB Control Number... to obtain current employment, dependency, and family income and net worth information to determine a...

  6. Performance test reports and comparison of emission characteristics of prototype liquid multifuel burners developed for US military field cooking applications

    Energy Technology Data Exchange (ETDEWEB)

    Litzke, W.; Celebi, Y.; McDonald, R.


    The objective of this project is to provide data to the U.S. Army Natick RD&E Center on the performance of three prototype burners, which have the capability of firing with multiple types of fuels (diesel and JP-8), and the conventional gasoline-fired M-2 burner. The prototype burners are intended to replace the M-2 unit currently used in food cooking appliances in the Army. The burners supplied to Brookhaven National Laboratory (BNL) for the purpose of testing under this project included one M-2 unit, one M-3 prototype unit designed by Natick, one Babington prototype unit designed by Babington Engineering, and one ITR prototype designed by International Thermal Research Ltd. It should be noted, however, that after the project began, Babington Engineering provided an upgraded prototype unit for testing which replaced the unit initially provided by the Natick Center. The M-3 unit replaced the Karcher unit listed in the contract. The test procedures which were described in a Test Method Report allowed for the measurement of the concentrations of specific compounds emitted from the burners. These compounds included oxygen (O{sub 2}), carbon monoxide (CO), oxides of nitrogen (NOx), formaldehyde, and particulate emissions. The level of smoke produced was also measured by using a Bacharach Smoke Number system (ASTM Standard D2156). A separate Performance Test Report for each burner was prepared as part of this project, and is attached as part of this report. In those reports details of the measurement techniques, instrumentation, test operating conditions, and data for each burner were included. This paper provides a summary and a comparison of the results for all burners. A brief discussion of emissions from other similar small oil combustion systems is also part of this document to provide perspective on the type of contaminants and levels expected from these systems.

  7. Full-scale demonstration of low-NO{sub x} cell{trademark} burner retrofit. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Eckhart, C.F.; Kitto, J.B.; Kleisley, R.J. [and others


    The objective of the Low-NO{sub x} Cell{trademark}Burner (LNCB{trademark}) demonstration is to evaluate the applicability of this technology for reducing NO{sub x} emissions in full-scale, cell burner-equipped boilers. More precisely, the program objectives are to: (1) Achieve at least a 50% reduction in NO{sub x} emissions. (2) Reduce NO{sub x} with no degradation to boiler performance or life of the unit. (3) Demonstrate a technically and economically feasible retrofit technology. Cell burner equipped boilers comprise 13% of the Pre-New Source Performance Standards (NSPS) coal-fired generating capacity. This relates to 34 operating units generating 23,639 MWe, 29 of which are opposed wall fired with two rows of two-nozzle cell burners on each wall. The host site was one of these 29. Dayton Power & Light offered use of J.M. Stuart Station`s Unit No. 4 as the host site. It was equipped with 24, two-nozzle cell burners arranged in an opposed wall configuration. To reduce NO{sub x} emissions, the LNCB{trademark} has been designed to delay the mixing of the fuel and combustion air. The delayed mixing, or staged combustion, reduces the high temperatures normally generated in the flame of a standard cell burner. A key design criterion for the burner was accomplishing delayed fuel-air mixing with no pressure part modifications to facilitate a {open_quotes}plug-in{close_quotes} design. The plug-in design reduces material costs and outage time required to complete the retrofit, compared to installing conventional, internally staged low-NO{sub x} burners.

  8. Increased Coal Replacement in a Cement Kiln Burner by Feeding a Mixture of Solid Hazardous Waste and Shredded Plastic Waste


    Ariyaratne, W.K. Hiromi; Melaaen, Morten Christian; Tokheim, Lars-André


    The present study aims to find the maximum possible replacement of coal by combined feeding of plastic waste and solid hazardous waste mixed with wood chips (SHW) in rotary kiln burners used in cement kiln systems. The coal replacement should be achieved without negative impacts on product quality, emissions or overall operation of the process. A full-scale experiment was carried out in the rotary kiln burner of a cement kiln by varying SHW and plastic waste feeding rates. Experimental result...

  9. Phytosiderophore Effects on Subsurface Actinide Contaminants: Potential for Phytostabilization and Phytoextraction

    Energy Technology Data Exchange (ETDEWEB)

    Ruggiero, Christy


    This project seeks to understand the influence of phytosiderophore-producing plants (grasses, including crops such as wheat and barley) on the biogeochemistry of actinide and other metal contaminants in the subsurface environment, and to determine the potential of phytosiderophore-producing plants for phytostabilization and phytoextraction of actinides and some metal soil contaminants. Phytosiderophores are secreted by graminaceous plants such as barley and wheat for the solubilization, mobilization and uptake of Fe and other essential nutrients from soils. The ability for these phytosiderophores to chelate and absorb actinides using the same uptake system as for Fe is being investigated though characterization of actinide-phytosiderophore complexes (independently of plants), and characterization of plant uptake of such complexes. We may also show possible harm caused by these plants through increased chelation of actinides that increase in actinide mobilization & migration in the subsurface environment. This information can then be directly applied by either removal of harmful plants, or can be used to develop plant-based soil stabilization/remediation technologies. Such technologies could be the low-cost, low risk solution to many DOE actinide contamination problems.

  10. Industrial thermal oxidation with an innovative burner management system; Industrielle thermische Nachverbrennung mit innovativem Brenner-Managementsystem

    Energy Technology Data Exchange (ETDEWEB)

    Gnoss, T. [Siemens Building Technologies HVAC Product GmbH, Rastatt (Germany); Pilz, R. [Control and Heating-Systems, Felsberg-Gensungen (Switzerland); Saenger, P. [Siemens Building Technologies HVAC Product GmbH, Frankfurt am Main(Germany)


    In view of rising energy costs and the emission limits stipulated by the latest 'TA-Luft' (Technical Directive: Prevention of Air Pollution) and 'BImSchV' (Federal Immission Control Ordinance in force in Germany), industrial thermal oxidation plants must be either completely replaced or a new burner system must be installed to ensure compliance with the latest environmental standards that demand restriction of pollutant emissions. Replacement of the original burner control system by a state-of-the-art burner management system improves not only the combustion process and the flue gas quality but also saves energy and thus costs through the use of a thermal incinerator. One of the key features of a thermal oxidation plant is a new technology used for controlling and monitoring the burner. The following article examines the innovative LMV5.. burner management system which offers a host of functions, such as burner control, electronic fuel / air ratio control, valve proving and load control - components which, previously, had to be separately assembled and electrically interconnected. (orig.)

  11. Correction of edge-flame propagation speed in a counterflow, annular slot burner

    KAUST Repository

    Tran, Vu Manh


    To characterize the propagation modes of flames, flame propagation speed must be accurately calculated. The impact of propagating edge-flames on the flow fields of unburned gases is limited experimentally. Thus, few studies have evaluated true propagation speeds by subtracting the flow velocities of unburned gases from flame displacement speeds. Here, we present a counterflow, annular slot burner that provides an ideal one-dimensional strain rate and lengthwise zero flow velocity that allowed us to study the fundamental behaviors of edge-flames. In addition, our burner has easy optical access for detailed laser diagnostics. Flame displacement speeds were measured using a high-speed camera and related flow fields of unburned gases were visualized by particle image velocimetry. These techniques allowed us to identify significant modifications to the flow fields of unburned gases caused by thermal expansion of the propagating edges, which enabled us to calculate true flame propagation speeds that took into account the flow velocities of unburned gases.

  12. Large Eddy Simulation of Flow Structures in the Sydney Swirl Burner

    DEFF Research Database (Denmark)

    Yang, Yang

    This thesis represents the research on swirling flow using large eddy simulation(LES). Three cases from the Sydney swirl burner database have been chosen as test cases; one medium swirl isothermal case N29S054, one high swirl isothermal case N16S159 and one medium swirl reacting case SM1...... zone which starts at the burner surface. As for the medium swirling isothermal case, there are two reverse flow zones in the reacting case. Due to the low stoichiometric mixture fraction in the methane flame, only the outer layer of the bluff‐body induced reverse zone is reactive. The main reactive...... zone is held at the bubblerecirculation. By using two‐dimensional proper orthogonal decomposition (POD) on the cross‐plane, the periodic oscillating movement of the jet has been interpretation. Through this research, a practical guideline is provided for the industry LES user. Nevertheless, the LES...

  13. An Advanced TALSPEAK Concept for Separating Minor Actinides. Part 2. Flowsheet Test with Actinide-spiked Simulant

    Energy Technology Data Exchange (ETDEWEB)

    Wilden, Andreas [Forschungszentrum Jülich GmbH, Institut für Energie – und Klimaforschung – Nukleare Entsorgung und Reaktorsicherheit (IEK-6), Jülich, Germany; Lumetta, Gregg J. [Nuclear Science and Engineering Group, Pacific Northwest National Laboratory, Richland, DC, USA; Sadowski, Fabian [Forschungszentrum Jülich GmbH, Institut für Energie – und Klimaforschung – Nukleare Entsorgung und Reaktorsicherheit (IEK-6), Jülich, Germany; Schmidt, Holger [Forschungszentrum Jülich GmbH, Institut für Energie – und Klimaforschung – Nukleare Entsorgung und Reaktorsicherheit (IEK-6), Jülich, Germany; Schneider, Dimitri [Forschungszentrum Jülich GmbH, Institut für Energie – und Klimaforschung – Nukleare Entsorgung und Reaktorsicherheit (IEK-6), Jülich, Germany; Gerdes, Markus [Forschungszentrum Jülich GmbH, Institut für Energie – und Klimaforschung – Nukleare Entsorgung und Reaktorsicherheit (IEK-6), Jülich, Germany; Law, Jack D. [Aqueous Separations and Radiochemistry Department, Idaho National Laboratory, Idaho Falls, ID, USA; Geist, Andreas [Karlsruhe Institute of Technology (KIT), Institute for Nuclear Waste Disposal (INE), Karlsruhe, Germany; Bosbach, Dirk [Forschungszentrum Jülich GmbH, Institut für Energie – und Klimaforschung – Nukleare Entsorgung und Reaktorsicherheit (IEK-6), Jülich, Germany; Modolo, Giuseppe [Forschungszentrum Jülich GmbH, Institut für Energie – und Klimaforschung – Nukleare Entsorgung und Reaktorsicherheit (IEK-6), Jülich, Germany


    A solvent extraction system has been developed for separating trivalent actinides from lanthanides. This “Advanced TALSPEAK” system uses 2-ethylhexylphosphonic acid mono-2-ethylhexyl ester to extract the lanthanides into a n-dodecane-based solvent phase, while the actinides are retained in a citrate-buffered aqueous phase by complexation to N-(2-hydroxyethyl)ethylenediamine-N,N',N'-triacetic acid. Batch distribution measurements indicate that the separation of americium from the light lanthanides decreases as the pH decreases. For example, the separation factor between La and Am increases from 2.5 at pH 2.0 to 19.3 at pH 3.0. However, previous investigations indicated that the extraction rates for the heavier lanthanides decrease with increasing pH. So, a balance between these two competing effects is required. An aqueous phase in which the pH was set at 2.6 was chosen for further process development because this offered optimal separation, with a minimum separation factor of ~8.4, based on the separation between La and Am. Centrifugal contactor single-stage efficiencies were measured to characterize the performance of the system under flow conditions.

  14. Worth their while?: Pursuing a rape complaint through the criminal ...

    African Journals Online (AJOL)

    If the criminal justice system were to advertise itself to victims of sexual violence, would its tag line be L'Oreal's 'Because you're worth it'? Or would the Foundry ... Certainly, a lack of faith in, or fear of, legal processes, is one of the reasons why eight out of nine women who are raped do not report the matter to the police.1 ...

  15. Coal Particle Flow Patterns for O2 Enriched, Low NOx Burners

    Energy Technology Data Exchange (ETDEWEB)

    Jennifer Sinclair Curtis


    This project involved a systematic investigation examining the effect of near-flame burner aerodynamics on standoff distance and stability of turbulent diffusion flames and the resultant NO{sub x} emissions from actual pulverized coal diffusion flames. Specifically, the scope of the project was to understand how changes in near-flame aerodynamics and transport air oxygen partial pressure can influence flame attachment and coal ignition, two properties essential to proper operation of low NO{sub x} burners. Results from this investigation utilized a new 2M tall, 0.5m in diameter combustor designed to evaluate near-flame combustion aerodynamics in terms of transport air oxygen partial pressure (Po{sub 2}), coal fines content, primary fuel and secondary air velocities, and furnace wall temperature furnish insight into fundamental processes that occur during combustion of pulverized coal in practical systems. Complementary cold flow studies were conducted in a geometrically similar chamber to analyze the detailed motion of the gas and particles using laser Doppler velocimetry. This final technical report summarizes the key findings from our investigation into coal particle flow patterns in burners. Specifically, we focused on the effects of oxygen enrichment, the effect of fines, and the effect of the nozzle velocity ratio on the resulting flow patterns. In the cold flow studies, detailed measurements using laser Doppler velocimetry (LDV) were made to determine the details of the flow. In the hot flow studies, observations of flame stability and measurements of NO{sub x} were made to determine the effects of the flow patterns on burner operation.

  16. CFD simulation of a burner for syngas characterization and experimental validation

    Energy Technology Data Exchange (ETDEWEB)

    Fantozzi, Francesco; Desideri, Umberto [University of Perugia (Italy). Dept. of Industrial Engineering], Emails:,; D' Amico, Michele [University of Perugia (Italy). Dept. of Energetic Engineering], E-mail:


    Biomass and waste are distributed and renewable energy sources that may contribute effectively to sustainability if used on a small and micro scale. This requires the transformation through efficient technologies (gasification, pyrolysis and anaerobic digestion) into a suitable gaseous fuel to use in small internal combustion engines and gas turbines. The characterization of biomass derived syngas during combustion is therefore a key issue to improve the performance of small scale integrated plants because synthesis gas show significant differences with respect to Natural Gas (mixture of gases, low calorific value, hydrogen content, tar and particulate content) that may turn into ignition problems, combustion instabilities, difficulties in emission control and fouling. To this aim a burner for syngas combustion and LHV measurement through mass and energy balance was realized and connected to the rotary-kiln laboratory scale pyrolyzer at the Department of Industrial Engineering of the University of Perugia. A computational fluid dynamics (CFD) simulation of the burner was carried out considering the combustion of propane to investigate temperature and pressure distribution, heat transmission and distribution of the combustion products and by products. The simulation was carried out using the CFD program Star-CD. Before the simulation a geometrical model of the burner was built and the volume of model was subdivided in cells. A sensibility analysis of cells was carried out to estimate the approximation degree of the model. Experimental data about combustion emission were carried out with the propane combustion in the burner, the comparison between numerical results and experimental data was studied to validate the simulation for future works involved with the combustion of treated or raw (syngas with tar) syngas obtained from pyrolysis process. (author)

  17. Pollutant Exposures from Natural Gas Cooking Burners: A Simulation-Based Assessment for Southern California

    Energy Technology Data Exchange (ETDEWEB)

    Logue, Jennifer M.; Klepeis, Neil E.; Lobscheid, Agnes B.; Singer, Brett C.


    Residential natural gas cooking burners (NGCBs) can emit substantial quantities of pollutants and they are typically used without venting. The objective of this study is to quantify pollutant concentrations and occupant exposures resulting from NGCB use in California homes. A mass balance model was applied to estimate time-dependent pollutant concentrations throughout homes and the "exposure concentrations" experienced by individual occupants. The model was applied to estimate nitrogen dioxide (NO{sub 2}), carbon monoxide (CO), and formaldehyde (HCHO) concentrations for one week each in summer and winter for a representative sample of Southern California homes. The model simulated pollutant emissions from NGCBs, NO{sub 2} and CO entry from outdoors, dilution throughout the home, and removal by ventilation and deposition. Residence characteristics and outdoor concentrations of CO and NO{sub 2} were obtained from available databases. Ventilation rates, occupancy patterns, and burner use were inferred from household characteristics. Proximity to the burner(s) and the benefits of using venting range hoods were also explored. Replicate model executions using independently generated sets of stochastic variable values yielded estimated pollutant concentration distributions with geometric means varying less than 10%. The simulation model estimates that in homes using NGCBs without coincident use of venting range hoods, 62%, 9%, and 53% of occupants are routinely exposed to NO{sub 2}, CO, and HCHO levels that exceed acute health-based standards and guidelines. NGCB use increased the sample median of the highest simulated 1-hr indoor concentrations by 100, 3000, and 20 ppb for NO{sub 2}, CO, and HCHO, respectively. Reducing pollutant exposures from NGCBs should be a public health priority. Simulation results suggest that regular use of even moderately effective venting range hoods would dramatically reduce the percentage of homes in which concentrations exceed health

  18. Advanced Extraction Methods for Actinide/Lanthanide Separations

    Energy Technology Data Exchange (ETDEWEB)

    Scott, M.J.


    The separation of An(III) ions from chemically similar Ln(III) ions is perhaps one of the most difficult problems encountered during the processing of nuclear waste. In the 3+ oxidation states, the metal ions have an identical charge and roughly the same ionic radius. They differ strictly in the relative energies of their f- and d-orbitals, and to separate these metal ions, ligands will need to be developed that take advantage of this small but important distinction. The extraction of uranium and plutonium from nitric acid solution can be performed quantitatively by the extraction with the TBP (tributyl phosphate). Commercially, this process has found wide use in the PUREX (plutonium uranium extraction) reprocessing method. The TRUEX (transuranium extraction) process is further used to coextract the trivalent lanthanides and actinides ions from HLLW generated during PUREX extraction. This method uses CMPO [(N, N-diisobutylcarbamoylmethyl) octylphenylphosphineoxide] intermixed with TBP as a synergistic agent. However, the final separation of trivalent actinides from trivalent lanthanides still remains a challenging task. In TRUEX nitric acid solution, the Am(III) ion is coordinated by three CMPO molecules and three nitrate anions. Taking inspiration from this data and previous work with calix[4]arene systems, researchers on this project have developed a C3-symmetric tris-CMPO ligand system using a triphenoxymethane platform as a base. The triphenoxymethane ligand systems have many advantages for the preparation of complex ligand systems. The compounds are very easy to prepare. The steric and solubility properties can be tuned through an extreme range by the inclusion of different alkoxy and alkyl groups such as methyoxy, ethoxy, t-butoxy, methyl, octyl, t-pentyl, or even t-pentyl at the ortho- and para-positions of the aryl rings. The triphenoxymethane ligand system shows promise as an improved extractant for both tetravalent and trivalent actinide recoveries form

  19. Use of superheated liquid dispersion technique for measuring alpha-emitting actinides in environmental samples (United States)

    Wang, C. K.; Lim, W.; Pan, L. K.


    This paper presents a novel fast screening technique of measuring concentrations of alpha-emitting actinides in environmental samples. This novel technique is called superheated liquid dispersion (SLD), which involves dispersing fine superheated liquid (e.g. Freon-12) droplets into a mixture of glycerin and the actinide-containing chemical extractant. The interactions between alpha particles and superheated liquid droplets trigger bubbles. Therefore, one may relate the number of bubbles to the actinide concentration in the sample. The results obtained from the computer simulation and the experiment support the above claim.

  20. Actinides recovery from irradiated metallic fuel in LiCl–KCl melts

    Energy Technology Data Exchange (ETDEWEB)

    Murakami, T., E-mail: [Central Research Institute of Electric Power Industry (CRIEPI), Komaeshi, Tokyo 201-8511 (Japan); Rodrigues, A.; Ougier, M. [Joint Research Center-Institute for Transuranium Elements (JRC-ITU), P.O. Box 2340, 76125 Karlsruhe (Germany); Iizuka, M.; Tsukada, T. [Central Research Institute of Electric Power Industry (CRIEPI), Komaeshi, Tokyo 201-8511 (Japan); Glatz, J.-P. [Joint Research Center-Institute for Transuranium Elements (JRC-ITU), P.O. Box 2340, 76125 Karlsruhe (Germany)


    Electrorefining of irradiated metallic fuels was successfully demonstrated: Actinides (U, Pu, Np, Am and Cm) in the fuels were dissolved in LiCl–KCl melts with high dissolution ratios, while U was selectively deposited on a solid cathode and the simultaneous recovery of actinides in a liquid Cd cathode was confirmed. The behavior of actinides, the fuel matrix stabilizer Zr and fission products such as lanthanide, alkaline, alkaline earth and noble metal, at the electrorefining is discussed based on the ICP-MS analysis of the samples taken from molten salt electrolyte, anode fuel residues and cathode deposits.

  1. Actinide-zirconia based materials for nuclear applications: Cubic stabilized zirconia versus pyrochlore oxide (United States)

    Raison, P. E.; Haire, R. G.


    Concepts about nuclear energy and nuclear materials have changed considerably over the past six decades. Regardless of one's position on the nuclear generation of electric power, there are serious needs for pursuing fundamental and technological science of existing actinide materials. These needs are best addressed by obtaining an atomic and molecular understanding of these actinides and actinide containing materials. Although electro-nuclear energy is considered less polluting in terms of uncontrolled releases (e.g., SO2, heavy metals, CO2, etc.) into the environment, its use produces solid wastes, which offer a challenge for scientists. Fortunately, concepts are being developed to appropriately handle these materials after irradiation, reprocessing, etc.

  2. Conjugates of Actinide Chelator-Magnetic Nanoparticles for Used Fuel Separation Technology

    Energy Technology Data Exchange (ETDEWEB)

    Qiang, You; Paszczynski, Andrzej; Rao, Linfeng


    The actinide separation method using magnetic nanoparticles (MNPs) functionalized with actinide specific chelators utilizes the separation capability of ligand and the ease of magnetic separation. This separation method eliminated the need of large quantity organic solutions used in the liquid-liquid extraction process. The MNPs could also be recycled for repeated separation, thus this separation method greatly reduces the generation of secondary waste compared to traditional liquid extraction technology. The high diffusivity of MNPs and the large surface area also facilitate high efficiency of actinide sorption by the ligands. This method could help in solving the nuclear waste remediation problem.

  3. Fuel Evaporation in an Atmospheric Premixed Burner: Sensitivity Analysis and Spray Vaporization

    Directory of Open Access Journals (Sweden)

    Dávid Csemány


    Full Text Available Calculation of evaporation requires accurate thermophysical properties of the liquid. Such data are well-known for conventional fossil fuels. In contrast, e.g., thermal conductivity or dynamic viscosity of the fuel vapor are rarely available for modern liquid fuels. To overcome this problem, molecular models can be used. Currently, the measurement-based properties of n-heptane and diesel oil are compared with estimated values, using the state-of-the-art molecular models to derive the temperature-dependent material properties. Then their effect on droplet evaporation was evaluated. The critical parameters were liquid density, latent heat of vaporization, boiling temperature, and vapor thermal conductivity where the estimation affected the evaporation time notably. Besides a general sensitivity analysis, evaporation modeling in a practical burner ended up with similar results. By calculating droplet motion, the evaporation number, the evaporation-to-residence time ratio can be derived. An empirical cumulative distribution function is used for the spray of the analyzed burner to evaluate evaporation in the mixing tube. Evaporation number did not exceed 0.4, meaning a full evaporation prior to reaching the burner lip in all cases. As droplet inertia depends upon its size, the residence time has a minimum value due to the phenomenon of overshooting.

  4. Reconsideration of natural-gas immersion burners to melt recycled aluminum

    Energy Technology Data Exchange (ETDEWEB)

    Clark, John A., III; Thekdi, Arvind (E3M, Inc., North Potomac, MD); Ningileri, S. (Secat Inc, Lexington KY); Han, Q. (Oak Ridge National Laboratory)


    The best open flame reverberatory aluminum melting furnaces are approximately 45% efficient. Furnace efficiency can be increased by using immersed tube burners. Currently, recuperated tube burners with capacities to remelt aluminum are available. Tube burners would allow remelt furnaces to operate at lower temperatures, reduce dross formation, reduce particulate emissions, and provide clean flue gas to other energy intensive processes. Babcock and Wilcox, under GRI (now GTI – Gas Technology Institute) contract in the late-1980’s, demonstrated the technically feasibility of immersion melting of aluminum. However, tube reliability was problematic due to metal penetration, dross build-up, thermal shock, and mechanical failure. Also, the concept of “cold start” melting was not addressed. The Albany Research Center (U.S. DOE) is cooperating with Secat, E3M Inc., the University of Kentucky, and Oak Ridge National Laboratory in an ITP-sponsored program to combine emerging technologies in a retrofitable furnace package targeting improved remelt efficiency ranging from 55% to 75%.

  5. Testing of a low NOx wire-mesh duct burner for micro-cogeneration unit

    Energy Technology Data Exchange (ETDEWEB)

    Ramadan, O.B.; Gauthier, J.E.D. [Carleton Univ., Ottawa, ON (Canada). Dept. of Mechanical and Aerospace Engineering; Hughes, P.M.; Brandon, R. [Natural Resources Canada, Ottawa, ON (Canada). CANMET Energy Technology Centre


    Combined heat and power (CHP) or cogeneration involves the generation of electricity in addition to the productive use of waste heat from the combustion process using the same primary fuel. An alternative to combined electrical power and heat generation is a micro-cogeneration unit which uses a micro-turbine as a prime mover. This type of unit is expected to result in a shift from large and centralized plants to smaller, more economical on-site generation plants. This paper presented a new low nitrogen oxide (NOx) wire-mesh duct burner (WMDB) for the development of a more efficient micro-cogeneration unit. In order to increase its thermal output, the low NOx WMDB was designed, built and integrated for evaluation with the Ingersol-Rand 70 kw micro-cogeneration unit. The wire-mesh burner had a conical shape and was manufactured by ACOTECH. The paper also discussed the advantages of micro-CHP units which are more attractive to building owners, retail establishments, commercial and light industrial facilities. Advantages include quality of the power supply; more economical, cleaner power; and the addition of new capacity without new transmission lines. It was concluded that low levels of emission were achieved with the development of a low NOx wire-mesh duct burner for a micro-cogeneration plant. 2 refs., 5 figs.

  6. Performance evaluation of premixed burner fueled with biomass derived producer gas

    Directory of Open Access Journals (Sweden)

    P. Punnarapong


    Full Text Available Energy consumption of liquefied petroleum gas (LPG in ceramic firing process accounts for about 15–40% of production cost. Biomass derived producer gas may be used to replace LPG. In this work, a premixed burner originally designed for LPG was modified for producer gas. Its thermal performance in terms of axial and radial flame temperature distribution, thermal efficiency and emissions was investigated. The experiment was conducted at various gas production rates with equivalence ratios between 0.8 and 1.2. Flame temperatures of over 1200 °C can be achieved, with maximum value of 1260 °C. It was also shown that the burner can be operated at 30.5–39.4 kWth with thermal efficiency in the range of 84 – 91%. The maximum efficiency of this burner was obtained at producer gas flow rate of 24.3 Nm3/h and equivalence ratio of 0.84.


    Energy Technology Data Exchange (ETDEWEB)

    E.G. Eddings; A. Molina; D.W. Pershing; A.F. Sarofim; K.A. Davis; M.P. Heap; T.H. Fletcher; H. Zhang


    Coal continues to be one of the principal energy sources for electric power generation in the United States. One of the biggest environmental challenges involved with coal utilization is the reduction of nitrogen oxides (NO{sub x}) formed during coal combustion. The most economical method of NO{sub x} abatement in coal combustion is through burner modification. Air-staging techniques have been widely used in the development of low-NO{sub x} pulverized coal burners, promoting the conversion of NO{sub x} to N{sub 2} by delaying the mixing in the fuel-rich zone near the burner inlet. Previous studies have looked at the mechanisms of NO{sub x} evolution at relatively low temperatures where primary pyrolysis is dominant, but data published for secondary pyrolysis in the pulverized coal furnace are scarce. In this project, the nitrogen evolution behavior during secondary coal pyrolysis will be explored. The end result will be a complete model of nitrogen evolution and NO{sub x} precursor formation due to primary and secondary pyrolysis.

  8. Application of CALPUFF to PM10 emissions from beehive burners in British Columbia

    Energy Technology Data Exchange (ETDEWEB)

    Ciccone, A.D. [Jacques Whitford and Associates Limited, Vancouver, BC (Canada); Waddell, G. [Canadian Forest Products Ltd., Prince George, BC (Canada)


    The complex local topography of the Bulkley Valley in the British Columbia interior greatly influences the local meteorology and climatology. The communities of Smithers and Houston which are located in the valley are hosts to three mills which operate conical burners for waste disposal and which define the extent of airshed. The CALMET/CALPUFF modelling system was chosen as a means to evaluate the contribution of the burners to the local airshed. CALPUFF was chosen because of the combined conditions of complex terrain and low wind speed in the region. Since MM5 gridded meteorological data was available from the BC Ministry of Environment to initialize the wind fields for CALMET in 1995, modelling was conducted in that year. CALPUFF provided 24-hour PM10 ground level concentrations over a 54 km by 72 km range. This included monitoring stations in the airshed. The impact from the conical burners was found to be low compared to the monitoring data which was collected. However, it was determined that the model was able to describe hourly changes in ambient PM10 levels, which reflected the hourly monitoring station data. The region is now equipped with a modelling platform that can be used to help in air pollution source appointment as well as for the management general air quality.

  9. Advanced Burner Reactor with Breed-and-Burn Thorium Blankets for Improved Economics and Resource Utilization

    Energy Technology Data Exchange (ETDEWEB)

    Greenspan, Ehud [Univ. of California, Berkeley, CA (United States)


    This study assesses the feasibility of designing Seed and Blanket (S&B) Sodium-cooled Fast Reactor (SFR) to generate a significant fraction of the core power from radial thorium fueled blankets that operate on the Breed-and-Burn (B&B) mode without exceeding the radiation damage constraint of presently verified cladding materials. The S&B core is designed to maximize the fraction of neutrons that radially leak from the seed (or “driver”) into the subcritical blanket and reduce neutron loss via axial leakage. The blanket in the S&B core makes beneficial use of the leaking neutrons for improved economics and resource utilization. A specific objective of this study is to maximize the fraction of core power that can be generated by the blanket without violating the thermal hydraulic and material constraints. Since the blanket fuel requires no reprocessing along with remote fuel fabrication, a larger fraction of power from the blanket will result in a smaller fuel recycling capacity and lower fuel cycle cost per unit of electricity generated. A unique synergism is found between a low conversion ratio (CR) seed and a B&B blanket fueled by thorium. Among several benefits, this synergism enables the very low leakage S&B cores to have small positive coolant voiding reactivity coefficient and large enough negative Doppler coefficient even when using inert matrix fuel for the seed. The benefits of this synergism are maximized when using an annular seed surrounded by an inner and outer thorium blankets. Among the high-performance S&B cores designed to benefit from this unique synergism are: (1) the ultra-long cycle core that features a cycle length of ~7 years; (2) the high-transmutation rate core where the seed fuel features a TRU CR of 0.0. Its TRU transmutation rate is comparable to that of the reference Advanced Burner Reactor (ABR) with CR of 0.5 and the thorium blanket can generate close to 60% of the core power; but requires only one sixth of the reprocessing and

  10. Evaluation of Gas Reburning and Low N0x Burners on a Wall Fired Boiler

    Energy Technology Data Exchange (ETDEWEB)



    Under the U.S. Department of Energy's Clean Coal Technology Program (Round 3), a project was completed to demonstrate control of boiler NOX emissions and to a lesser degree, due to coal replacement, SO2 emissions. The project involved combining Gas Reburning with Low NOX Burners (GR-LNB) on a coal-fired electric utility boiler to determine if high levels of NO, reduction (70VO) could be achieved. Sponsors of the project included the U.S. Depatiment of Energy, the Gas Research Institute, Public Service Company of Colorado, Colorado Interstate Gas, Electric Power Research Institute, and the Energy and Environmental Research Corporation. The GR-LNB demonstration was petformed on Public Service Company of Colorado's (PSCO) Cherokee Unit #3, located in Denver, Colorado. This unit is a 172 MW~ wall-fired boiler that uses Colorado bituminous, low-sulfur coal. It had a baseline NO, emission level of 0.73 lb/1 OG Btu using conventional burners. Low NOX burners are designed to yield lower NOX emissions than conventional burners. However, the NOX control achieved with this technique is limited to 30-50Y0. Also, with LNBs, CO emissions can increase to above acceptable standards. Gas Reburning (GR) is designed to reduce NO, in the flue gas by staged fuel combustion. This technology involves the introduction of' natural gas into the hot furnace flue gas stream. When combined, GR and LNBs minimize NOX emissions and maintain acceptable levels of CO emissions. A comprehensive test program was completed, operating over a wide range of boiler conditions. Over 4,000 hours of operation were achieved, providing substantial data. Measurements were taken to quantify reductions in NOX emissions, the impact on boiler equipment and operability and factors influencing costs. The GR-LNB technology achieved good NO, emission reductions and the goals of the project were achieved. Although the performance of the low NOX burners (supplied by others) was less than expected, a NOX

  11. Synthesis of Titanium Dioxide Nanoparticles Using a Double-Slit Curved Wall-Jet Burner

    KAUST Repository

    Ismail, Mohamed


    A novel double-slit curved wall-jet (DS-CWJ) burner was proposed and utilized for flame synthesis. This burner was comprised of double curved wall-jet nozzles with coaxial slits; the inner slit was for the delivery of titanium tetraisopropoxide (TTIP) precursor while the outer one was to supply premixed fuel/air mixture of ethylene (C2H4) or propane (C3H8). This configuration enabled rapid mixing between the precursor and reactants along the curved surface and inside the recirculation zone of the burner. Particle growth of titanium dioxide (TiO2) nanoparticles and their phases was investigated with varying equivalence ratio and Reynolds number. Flow field and flame structure were measured using particle image velocimetry (PIV) and OH planar laser-induced fluorescence (PLIF) techniques, respectively. The nanoparticles were characterized using high-resolution transmission electron microscopy (HRTEM), X-ray diffraction (XRD), and nitrogen adsorption Brunauer–Emmett–Teller (BET) for surface area analysis. The flow field consisted of a wall-jet region leading to a recirculation zone, an interaction jet region, followed by a merged-jet region. The DS-CWJ burner revealed appreciable mixing characteristics between the precursor and combustion gases near the nozzle regions, with a slight increase in the axial velocity due to the precursor injection. The precursor supply had a negligible effect on the flame structure. The burner produced a reasonably uniform size (13–18 nm) nanoparticles with a high BET surface area (>100 m2/g). The phase of TiO2 nanoparticles was mainly dependent on the equivalence ratio and fuel type, which impact flame height, heat release rate, and high temperature residence time of the precursor vapor. For ethylene flames, the anatase content increased with the equivalence ratio, whereas it decreased in the case of propane flames. The synthesized TiO2 nanoparticles exhibited high crystallinity and the anatase phase was dominant at high equivalence

  12. Facilities for preparing actinide or fission product-based targets

    CERN Document Server

    Sors, M


    Research and development work is currently in progress in France on the feasibility of transmutation of very long-lived radionuclides such as americium, blended with an inert medium such as magnesium oxide and pelletized for irradiation in a fast neutron reactor. The process is primarily designed to produce ceramics for nuclear reactors, but could also be used to produce targets for accelerators. The Actinide Development Laboratory is part of the ATALANTE complex at Marcoule, where the CEA investigates reprocessing, liquid and solid waste treatment and vitrification processes. The laboratory produces radioactive sources; after use, their constituents are recycled, notably through R and D programs requiring such materials. Recovered americium is purified, characterized and transformed for an experiment known as ECRIX, designed to demonstrate the feasibility of fabricating americium-based ceramics and to determine the reactor transmutation coefficients.

  13. Influence of FIMA burnup on actinides concentrations in PWR reactors

    Directory of Open Access Journals (Sweden)

    Oettingen Mikołaj


    Full Text Available In the paper we present the study on the dependence of actinides concentrations in the spent nuclear fuel on FIMA burnup. The concentrations of uranium, plutonium, americium and curium isotopes obtained in numerical simulation are compared with the result of the post irradiation assay of two spent fuel samples. The samples were cut from the fuel rod irradiated during two reactor cycles in the Japanese Ohi-2 Pressurized Water Reactor. The performed comparative analysis assesses the reliability of the developed numerical set-up, especially in terms of the system normalization to the measured FIMA burnup. The numerical simulations were preformed using the burnup and radiation transport mode of the Monte Carlo Continuous Energy Burnup Code – MCB, developed at the Department of Nuclear Energy, Faculty of Energy and Fuels of AGH University of Science and Technology.

  14. Room temperature electrodeposition of actinides from ionic solutions

    Energy Technology Data Exchange (ETDEWEB)

    Hatchett, David W.; Czerwinski, Kenneth R.; Droessler, Janelle; Kinyanjui, John


    Uranic and transuranic metals and metal oxides are first dissolved in ozone compositions. The resulting solution in ozone can be further dissolved in ionic liquids to form a second solution. The metals in the second solution are then electrochemically deposited from the second solutions as room temperature ionic liquid (RTIL), tri-methyl-n-butyl ammonium n-bis(trifluoromethansulfonylimide) [Me.sub.3N.sup.nBu][TFSI] providing an alternative non-aqueous system for the extraction and reclamation of actinides from reprocessed fuel materials. Deposition of U metal is achieved using TFSI complexes of U(III) and U(IV) containing the anion common to the RTIL. TFSI complexes of uranium were produced to ensure solubility of the species in the ionic liquid. The methods provide a first measure of the thermodynamic properties of U metal deposition using Uranium complexes with different oxidation states from RTIL solution at room temperature.

  15. Scissors strength in the quasi-continuum of actinides

    Directory of Open Access Journals (Sweden)

    Guttormsen M.


    Full Text Available The M1-scissors resonance has been measured for the first time in the quasi-continuum of actinides. The strength and position of the resonances in 231,232,233Th were determined by particle-γ coincidences using deuteron induced reactions on a 232Th target. The residual nuclei show a strong integrated strength of BM1 = 9 − 11 µn2 in the Eγ = 1.0 − 3.5 MeV region. The presence of the scissors resonance modifies significantly the (n,γ cross section, which has impact on fuel-cycle simulations of fast nuclear reactors and nucleosynthesis in explosive stellar environments.

  16. Specific sequestering agents for iron and the actinides

    Energy Technology Data Exchange (ETDEWEB)

    Raymond, K.N.


    The transuranium actinide ions represent one unique environmental hazard associated with the waste of the nuclear power industry. A major component associated with that waste and a potential hazard is plutonium. The synthesis of metal-ion-specific complexing agents for ions such as Pu(IV) potentially represents a powerful new approach to many of the problems posed by waste treatment. This document is a progress report of a rational approach to the synthesis of such chelating agents based on the similarities of Pu(IV) and Fe(III), the structures of naturally-occurring complexing agents which are highly specific for Fe(III), and the incorporation of the same kinds of ligating groups present in the iron complexes to make octadentate complexes highly specific for plutonium. Both thermodynamic and animal test results indicate that a relatively high degree of success has already been achieved in this aim.

  17. Chemistry of tetravalent actinides phosphates. The thorium phosphate-diphosphate as immobilisation matrix of actinides; Chimie des phosphates d'actinides tetravalents. Le phosphate-diphosphate de thorium en tant que matrice d'imobilisation des actinides

    Energy Technology Data Exchange (ETDEWEB)

    Dacheux, N


    The author presents in this document its scientific works from 1992 to 2001, in order to obtain the enabling to manage scientific and chemical researches at the university Paris Sud Orsay. The first part gives an abstract of the thesis on the characterizations, lixiviation and synthesis of uranium and thorium based phosphate matrix in the framework of the search for a ceramic material usable in the radioactive waste storage. The second part presents briefly the researches realized at the CEA, devoted to a reliable, independent and accurate measure of some isotopes activity. The last part presents the abstracts of researches activities from 1996 to 2001 on the tetravalent actinides phosphates chemistry, the sintering of PDT and solid solutions of PDTU and the kinetic and thermodynamical studies of the PDT dissolution. Many references and some publication in full text are provided. (A.L.B.)

  18. Angular distributions in the neutron-induced fission of actinides

    CERN Multimedia

    In 2003 the n_TOF Collaboration performed the fission cross section measurement of several actinides ($^{232}$Th, $^{233}$U, $^{234}$U, $^{237}$Np) at the n_TOF facility using an experImental setup made of Parallel Plate Avalanche Counters (PPAC). The method based on the detection of the 2 fragments in coincidence allowed to clearly disentangle the fission reactions among other types of reactions occurring in the spallation domain. We have been therefore able to cover the very broad neutron energy range 1eV-1GeV, taking full benefit of the unique characteristics of the n_TOF facility. Figure 1 shows an example obtained in the case of $^{237}$Np where the n_ TOF measurement showed that the cross section was underestimated by a large factor in the resonance region.

  19. Aqueous chemistry of Ce(iv): estimations using actinide analogues. (United States)

    Marsac, Rémi; Réal, Florent; Banik, Nidhu Lal; Pédrot, Mathieu; Pourret, Olivier; Vallet, Valérie


    The prediction of cerium (Ce) aqueous speciation is relevant in many research fields. Indeed, Ce compounds are used for many industrial applications, which may require the control of Ce aqueous chemistry for their synthesis. The aquatic geochemistry of Ce is also of interest. Due to its growing industrial use and its release into the environment, Ce is now considered as an emerging contaminant. Cerium is also used as a proxy of (paleo)redox conditions due to the Ce(iv)/Ce(iii) redox transition. Finally, Ce(iv) is often presented as a relevant analogue of tetravalent actinides (An(iv)). In the present study, quantum chemical calculations were conducted to highlight the similarities between the structures of Ce(iv) and tetravalent actinide (An(iv); An = Th, Pa, U, Np, Pu) aqua-ions, especially Pu(iv). The current knowledge of An(iv) hydrolysis, solubility and colloid formation in water was briefly reviewed but important discrepancies were observed in the available data for Ce(iv). Therefore, new estimations of the hydrolysis constants of Ce(iv) and the solubility of Ce(iv)-(hydr)oxides are proposed, by analogy with Pu(iv). By plotting pH-Eh (Pourbaix) diagrams, we showed that the pH values corresponding to the onset of Ce(iv) species formation (i.e. Ce(iv)-(hydr)oxide or dissolved Ce(iv)) agreed with various experimental results. Although further experimental studies are required to obtain a more accurate thermodynamic database, the present work might yet help to predict more accurately the Ce chemical behavior in aqueous solution.

  20. Organophosphorus reagents in actinide separations: Unique tools for production, cleanup and disposal

    Energy Technology Data Exchange (ETDEWEB)

    Nash, K. L.


    Interactions of actinide ions with phosphate and organophosphorus reagents have figured prominently in nuclear science and technology, particularly in the hydrometallurgical processing of irradiated nuclear fuel. Actinide interactions with phosphorus-containing species impact all aspects from the stability of naturally occurring actinides in phosphate mineral phases through the application of the bismuth phosphate and PUREX processes for large-scale production of transuranic elements to the development of analytical separation and environment restoration processes based on new organophosphorus reagents. In this report, an overview of the unique role of organophosphorus compounds in actinide production, disposal, and environment restoration is presented. The broad utility of these reagents and their unique chemical properties is emphasized.

  1. Review and needs in actinide chemistry in relation with biological purposes

    Energy Technology Data Exchange (ETDEWEB)

    Ansoborlo, E.; Moulin, V.; Bion, L.; Doizi, D.; Moulin, C.; Cote, G.; Madic, C.; Van der Lee, J


    In case of accidental release of radionuclides in the environment, actinides could occur and may present an healthy risk for human beings. In order to study their behavior in human organism (metabolism, retention, excretion), it is of prime importance to know solution actinide chemistry, and more particularly thermodynamic constants, which will allow to determine their speciation: speciation governs biological availability and toxicity of elements and is also of great interest for decorporation purposes. In this framework, a CEA working group on speciation has been created in order to share data both on thermodynamic constants and on speciation analytical methods, interesting chemists, environmentalists and biologists. It has been focused, in a first time, on actinides. The purpose of this paper is to present the state of the art on actinide speciation within biological media and to focus on the lack of information in order to orientate future research. (authors)

  2. SACSESS – the EURATOM FP7 project on actinide separation from spent nuclear fuels

    Directory of Open Access Journals (Sweden)

    Bourg Stéphane


    Full Text Available Recycling of actinides by their separation from spent nuclear fuel, followed by transmutation in fast neutron reactors of Generation IV, is considered the most promising strategy for nuclear waste management. Closing the fuel cycle and burning long-lived actinides allows optimizing the use of natural resources and minimizing the long-term hazard of high-level nuclear waste. Moreover, improving the safety and sustainability of nuclear power worldwide. This paper presents the activities striving to meet these challenges, carried out under the Euratom FP7 collaborative project SACSESS (Safety of Actinide Separation Processes. Emphasis is put on the safety issues of fuel reprocessing and waste storage. Two types of actinide separation processes, hydrometallurgical and pyrometallurgical, are considered, as well as related aspects of material studies, process modeling and the radiolytic stability of solvent extraction systems. Education and training of young researchers in nuclear chemistry is of particular importance for further development of this field.

  3. Separation of actinides using capillary extraction chromatography-inductively coupled plasma mass spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Peterson, Dominic S [Los Alamos National Laboratory


    Trace levels of actinides have been separated on extraction chromatography columns. Detection of the actinides was achieved using an inductively coupled plasma mass spectrometer (ICP-MS), which was coupled with the extraction chromatography system. In this study we compare 30 cm long, 4.6 mm ID columns to capillary columns (750 {micro}m ID) with lengths from 30 cm up to 150 cm. The columns that were tested were packed with TRU resin. We were able to separate a mixture of five actinides ({sup 232}Th, {sup 238}U, {sup 237}Np, {sup 239}pU, {sup 241}Am). This work has application to rapid bioassay as well as for automated separations of actinide materials.

  4. Radiochemical separation of actinides for their determination in environmental samples and waste products

    Energy Technology Data Exchange (ETDEWEB)

    Gleisberg, B. [Nuclear Engineering and Analytics Rossendorf, Inc. (VKTA), Dresden (Germany)


    The determination of low level activities of actinides in environmental samples and waste products makes high demands on radiochemical separation methods. Artificial and natural actinides were analyzed in samples form the surrounding areas of NPP and of uranium mines, incorporation samples, solutions containing radioactive fuel, solutions and solids resutling from the process, and in wastes. The activities are measured by {alpha}-spectrometry and {gamma}-spectrometry. (DG)

  5. An instrument for the investigation of actinides with spin resolved photoelectron spectroscopy and bremsstrahlung isochromat spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Yu, S.-W. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Tobin, J. G. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Chung, B. W. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)


    A new system for spin resolved photoelectron spectroscopy and bremsstrahlung isochromat spectroscopy has been built and commissioned at Lawrence Livermore National Laboratory for the investigation of the electronic structure of the actinides.Actinide materials are very toxic and radioactive and therefore cannot be brought to most general user facilities for spectroscopic studies. The technical details of the new system and preliminary data obtained therein will be presented and discussed.

  6. A conceptual performance assessment model of the dissolved actinide source term for the WIPP

    Energy Technology Data Exchange (ETDEWEB)

    Weiner, R.F.; Stockman, C.T.; Wang, Y.; Novak, C.F.


    This paper presents a performance assessment model of dissolved actinide concentrations for the Waste Isolation Pilot Plant (WIPP). The model assesses the concentration of each actinide oxidation state and combines these concentrations with an oxidation state distribution. The chemical behavior of actinides in the same oxidation state is presumed to be very similar for almost all situations, but exceptions arising from experimental evidence are accommodated. The code BRAGFLO calculates the gas pressure, brine mass, gas volume, and mass of remaining Fe and cellulosics for each time step and computational cell. The total CO{sub 2} in the repository and dissolved Ca(OH){sub 2} is estimated. Lookup tables are constructed for pmH and f(CO{sub 2}) as a function of brine type and volume, moles of CO{sub 2}, and Ca(OH){sub 2}. Amounts of five soluble complexants are considered. A model based on the formulation of Harvie et al. produces tables of solubilities for each actinide oxidation state as a function of pmH, f(CO{sub 2}), brine composition, and complexant. Experimental data yield lookup tables of fractions of Th, U, Np, Pu, and Am in each oxidation state as a function of f(CO{sub 2}) and complexant. The tables are then used to provide a concentration of a particular actinide at particular values of pmH and f(CO{sub 2}). Under steady-state conditions, the oxidation state of each actinide that is most stable in the particular chemical environment controls the concentration of that actinide in solution. In the absence of steady-state conditions, the oxidation state distribution of interest is that of the dissolved actinide, and the oxidation states may be treated as if they were separate compounds.

  7. Actinide interactions with aerobic soil microbes and their exudates: The reduction of plutonium with desferrioxamine siderophores (United States)

    Ruggiero, C. E.; Matonic, J. H.; Neu, M. P.; Reilly, S. P.


    Plutonium is thought to exist mostly as very low soluble and/or strongly sorbed plutonium(IV) hydroxide and oxide species in the environment, and therefore, has low risk of becoming mobile or bioavailable. However, compounds that solubilize plutonium can significantly increase its bioavailability and mobility. We are examining the fundamental inorganic chemistry of actinides with one type of biogenic chelator, microbial siderophores, in order to understand how they could affect actinide biogeochemistry.

  8. LLNL SFA OBER SBR FY17 Program Management and Performance Report: Subsurface Biogeochemistry of Actinides

    Energy Technology Data Exchange (ETDEWEB)

    Kersting, Annie B. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)


    A major scientific challenge in environmental sciences is to identify the dominant processes controlling actinide transport in the environment. It is estimated that currently, over 2200 metric tons of anthropogenic plutonium (Pu) has accumulated worldwide, a number that increases yearly with additional spent nuclear fuel (Ewing et al., 2010). Plutonium has been shown to migrate on the scale of kilometers, giving way to a critical concern that the fundamental biogeochemical processes that control its behavior in the subsurface are not well understood (Kersting et al. 1999; Novikov et al. 2006; Santschi et al. 2002). Neptunium (Np) is less prevalent in the environment; however, it is predicted to be a significant long-term dose contributor in high-level nuclear waste. Our focus on Np chemistry in this Science Plan is intended to help formulate a better understanding of Pu redox transformations in the environment and clarify the differences between the two long-lived actinides. The research approach of our Science Plan combines (1) Fundamental Mechanistic Studies that identify and quantify biogeochemical processes that control actinide behavior in solution and on solids, (2) Field Integration Studies that investigate the transport characteristics of Pu and test our conceptual understanding of actinide transport, and (3) Actinide Research Capabilities that allow us to achieve the objectives of this Scientific Focus Area (SFA) and provide new opportunities for advancing actinide environmental chemistry. These three Research Thrusts form the basis of our SFA Science Program.

  9. Factors influencing the transport of actinides in the groundwater environment. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Sheppard, J.C.; Kittrick, J.A.


    This report summarizes investigations of factors that significantly influence the transport of actinide cations in the groundwater environment. Briefly, measurements of diffusion coefficients for Am(III), Cm(III), and Np(V) in moist US soils indicated that diffusion is negligible compared to mass transport in flowing groundwater. Diffusion coefficients do, however, indicate that, in the absence of flowing water, actinide elements will migrate only a few centimeters in a thousand years. The remaining investigations were devoted to the determination of distribution ratios (K/sub d/s) for representative US soils, factors influencing them, and chemical and physical processes related to transport of actinides in groundwaters. The computer code GARD was modified to include complex formation to test the importance of humic acid complexing on the rate of transport of actinides in groundwaters. Use of the formation constant and a range of humic acid, even at rather low concentrations of 10/sup -5/ to 10/sup -6/ molar, significantly increases the actinide transport rate in a flowing aquifer. These computer calculations show that any strong complexing agent will have a similar effect on actinide transport in the groundwater environment. 32 references, 9 figures.

  10. Enhancing the actinide sciences in Europe through hot laboratories networking and pooling: from ACTINET to TALISMAN

    Energy Technology Data Exchange (ETDEWEB)

    Bourg, S.; Poinssot, C. [French Nuclear and Alternative Energies Commission, CEA, Nuclear Energy Division, F RadioChemistry and Processes Department, CEA Marcoule, 30207 Bagnols sur Ceze (France)


    Since 2004, Europe supports the strengthening of the European actinides sciences scientific community through the funding of dedicated networks: (i) from 2004 to 2008, the ACTINET6 network of excellence (6. Framework Programme) gathered major laboratories involved in nuclear research and a wide range of academic research organisations and universities with the specific aims of funding and implementing joint research projects to be performed within the network of pooled facilities; (ii) from 2009 to 2013, the ACTINET-I3 integrated infrastructure initiative (I3) supports the cost of access of any academics in the pooled EU hot laboratories. In this continuation, TALISMAN (Trans-national Access to Large Infrastructures for a Safe Management of Actinides) gathers now the main European hot laboratories in actinides sciences in order to promote their opening to academics and universities and strengthen the EU-skills in actinides sciences. Furthermore, a specific focus is set on the development of advanced cutting-edge experimental and spectroscopic capabilities, the combination of state-of-the art experimental with theoretical first-principle methods on a quantum mechanical level and to benefit from the synergy between the different scientific and technical communities. ACTINET-I3 and TALISMAN attach a great importance and promote the Education and Training of the young generation of actinides scientists in the Trans-national access but also by organizing Schools (general Summer Schools or Theoretical User Lab Schools) or by granting students to attend International Conference on actinide sciences. (authors)


    Energy Technology Data Exchange (ETDEWEB)

    Nash, Kenneth L.


    In this project, both the fundamental chemistry of actinides in alkaline solutions (relevant to those present in Hanford-style waste storage tanks), and their dissolution from sludge simulants (and interactions with supernatants) have been investigated under representative sludge leaching procedures. The leaching protocols were designed to go beyond conventional alkaline sludge leaching limits, including the application of acidic leachants, oxidants and complexing agents. The simulant leaching studies confirm in most cases the basic premise that actinides will remain in the sludge during leaching with 2-3 M NaOH caustic leach solutions. However, they also confirm significant chances for increased mobility of actinides under oxidative leaching conditions. Thermodynamic data generated improves the general level of experiemental information available to predict actinide speciation in leach solutions. Additional information indicates that improved Al removal can be achieved with even dilute acid leaching and that acidic Al(NO3)3 solutions can be decontaminated of co-mobilized actinides using conventional separations methods. Both complexing agents and acidic leaching solutions have significant potential to improve the effectiveness of conventional alkaline leaching protocols. The prime objective of this program was to provide adequate insight into actinide behavior under these conditions to enable prudent decision making as tank waste treatment protocols develop.

  12. Actinides reduction by recycling in a thermal reactor; Reduccion de actinidos por reciclado en un reactor termico

    Energy Technology Data Exchange (ETDEWEB)

    Ramirez S, J. R.; Martinez C, E.; Balboa L, H., E-mail: [ININ, Carretera Mexico-Toluca s/n, 52750 Ocoyoacac, Estado de Mexico (Mexico)


    This work is directed towards the evaluation of an advanced nuclear fuel cycle in which radioactive actinides could be recycled to remove most of the radioactive material; firstly a production reference of actinides in standard nuclear fuel of uranium at the end of its burning in a BWR reactor is established, after a fuel containing plutonium is modeled to also calculate the actinides production in MOX fuel type. Also it proposes a design of fuel rod containing 6% of actinides in a matrix of uranium from the tails of enrichment, then four standard uranium fuel rods are replaced by actinides rods to evaluate the production and transmutation thereof, the same procedure was performed in the fuel type MOX and the end actinide reduction in the fuel was evaluated. (Author)

  13. Studies of Actinides Reduction on Iron Surfaces by Means ofResonant Inelastic X-ray Scattering

    Energy Technology Data Exchange (ETDEWEB)

    Kvashnina, K.O.; Butorin, S.M.; Shuh, D.K.; Ollila, K.; Soroka,I.; Guo, J.-H.; Werme, L.; Nordgren, J.


    The interaction of actinides with corroded iron surfaces was studied using resonant inelastic x-ray scattering (RIXS) spectroscopy at actinide 5d edges. RIXS profiles, corresponding to the f-f excitations are found to be very sensitive to the chemical states of actinides in different systems. Our results clearly indicate that U(VI) (as soluble uranyl ion) was reduced to U(IV) in the form of relatively insoluble uranium species, indicating that the iron presence significantly affects the mobility of actinides, creating reducing conditions. Also Np(V) and Pu (VI) in the ground water solution were getting reduced by the iron surface to Np(IV) and Pu (IV) respectively. Studying the reduction of actinides compounds will have an important process controlling the environmental behavior. Using RIXS we have shown that actinides, formed by radiolysis of water in the disposal canister, are likely to be reduced on the inset corrosion products and prevent release from the canister.

  14. Scale-up of Advanced Low NO{sub x} and High Turndown Pulverized Coal Burner; Teifuka taioyo tei NO{sub x} bana no sukeruappu kento

    Energy Technology Data Exchange (ETDEWEB)

    Kimoto, Masayoshi.; Tsuji, Hirofumi.; Makino, Hisao. [Central research institute of electric power industry, Tokyo (Japan). Chemical energy engineering department; Kiga, Takashi. [Ishikawajima-Harima Heavy Industries Crop., Tokyo (Japan). Combustion engineering department, Power plant division


    The specific low NOx burner, which is enabled to reduce both NOx and unburned carbon extremely and to perform the stable combustion at 20% load as like an oil burner, has been developed with a small size burner whose coal feed rate is 0.12 t/h in the previous study. To apply this burner to utility boilers, the influence of burner capacity on the combustion characteristics was investigated by comparison between the small burner (0.12 t/h) and a large burner (1.5 t/h) in this paper. The concept of this burner is follows. Coal particle is concentrated at outside of primary air nozzle by centrifugal force, and the coal concentration is controlled by a ring. At the exit of nozzle, the swirl of primary air is inhibited by straightener to reduce NOx efficiently. The swirl at the burner exit decreased with the increase of the straightener coefficient, which is a ratio of the gross area of the straightener to the cross section area of the primary pipe. When the straightener coefficient became greater than 1.2, the swirl was inhibited completely as sane as 0.12 t/h burner. When the pulverized coal concentration control ring was placed close to the exit of nozzle, the local concentration of pulverized coal rose 1.7 times as high as the mean concentration in primary air. With this arrangement, the comproved to 20% as like an oil burner. The unburned carbon in the fly ash was reduced very efficiently with a little increase of the NOx emission at lower load by controlling the coal concentration higher. (author)

  15. Scale-up of Advanced Low NO[sub x] and High Turndown Pulverized Coal Burner. Teifuka taioyo tei NO[sub x] bana no sukeruappu kento

    Energy Technology Data Exchange (ETDEWEB)

    Kimoto, Masayoshi.; Tsuji, Hirofumi.; Makino, Hisao. (Central research institute of electric power industry, Tokyo (Japan). Chemical energy engineering department); Kiga, Takashi. (Ishikawajima-Harima Heavy Industries Crop., Tokyo (Japan). Combustion engineering department, Power plant division)


    The specific low NOx burner, which is enabled to reduce both NOx and unburned carbon extremely and to perform the stable combustion at 20% load as like an oil burner, has been developed with a small size burner whose coal feed rate is 0.12 t/h in the previous study. To apply this burner to utility boilers, the influence of burner capacity on the combustion characteristics was investigated by comparison between the small burner (0.12 t/h) and a large burner (1.5 t/h) in this paper. The concept of this burner is follows. Coal particle is concentrated at outside of primary air nozzle by centrifugal force, and the coal concentration is controlled by a ring. At the exit of nozzle, the swirl of primary air is inhibited by straightener to reduce NOx efficiently. The swirl at the burner exit decreased with the increase of the straightener coefficient, which is a ratio of the gross area of the straightener to the cross section area of the primary pipe. When the straightener coefficient became greater than 1.2, the swirl was inhibited completely as sane as 0.12 t/h burner. When the pulverized coal concentration control ring was placed close to the exit of nozzle, the local concentration of pulverized coal rose 1.7 times as high as the mean concentration in primary air. With this arrangement, the comproved to 20% as like an oil burner. The unburned carbon in the fly ash was reduced very efficiently with a little increase of the NOx emission at lower load by controlling the coal concentration higher. (author)

  16. Low Emissions Burner Technology for Metal Processing Industry using Byproducts and Biomass Derived Liquid Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Agrawal, Ajay; Taylor, Robert


    This research and development efforts produced low-emission burner technology capable of operating on natural gas as well as crude glycerin and/or fatty acids generated in biodiesel plants. The research was conducted in three stages (1) Concept definition leading to the design and development of a small laboratory scale burner, (2) Scale-up to prototype burner design and development, and (3) Technology demonstration with field vefiication. The burner design relies upon the Flow Blurring (FB) fuel injection based on aerodynamically creating two-phase flow near the injector exit. The fuel tube and discharge orifice both of inside diameter D are separated by gap H. For H < 0.25D, the atomizing air bubbles into liquid fuel to create a two-phase flow near the tip of the fuel tube. Pressurized two-phase fuel-air mixture exits through the discharge orifice, which results in expansion and breakup of air bubbles yielding a spray with fine droplets. First, low-emission combustion of diesel, biodiesel and straight VO (soybean oil) was achieved by utilizing FB injector to yield fine sprays for these fuels with significantly different physical properties. Visual images for these baseline experiments conducted with heat release rate (HRR) of about 8 kW illustrate clean blue flames indicating premixed combustion for all three fuels. Radial profiles of the product gas temperature at the combustor exit overlap each other signifying that the combustion efficiency is independent of the fuel. At the combustor exit, the NOx emissions are within the measurement uncertainties, while CO emissions are slightly higher for straight VO as compared to diesel and biodiesel. Considering the large variations in physical and chemical properties of fuels considered, the small differences observed in CO and NOx emissions show promise for fuel-flexible, clean combustion systems. FB injector has proven to be very effective in atomizing fuels with very different physical properties, and it offers a

  17. The three-dimensional numerical aerodynamics of a movable block burner

    Directory of Open Access Journals (Sweden)

    Fudihara T.J.


    Full Text Available Computational fluid-dynamics techniques were employed to study the aerodynamics of a movable block swirl burner, developed by the International Flame Research Foundation, IFRF, which is characterized by the ability to adjust continuously and dynamically the intensity of the swirl by means of the simultaneous rotation of eight movable blocks, inserted between eight fixed blocks. Five three-dimensional grids were constructed for the burner, corresponding to five positions of the movable blocks. Both the k-e and RNG k-e isotropic turbulence models were applied. Only the latter described the existence of a central reverse flow along the annular duct. The employment of first-order and second-order interpolation schemes provided distinct results. The later provided results closer to the experimental tests. The swirl number decayed in the annular duct. The predicted swirl numbers for this movable block swirl burner were lower than the corresponding IFRF's experimental data, as was also observed by other researchers. This gave rise to the suspicion of some possible measurement error in the IFRF's experiments. On the other hand, the lack of agreement between the experimental data and the predictions regarding swirling flows could be attributed to the possible inadequate performance of the k-e model, as a consequence of its isotropic approximation. Still another possible explanation could be a phenomenon called bifurcation, in which one given swirl number can be associated with two distinct conditions of steady state flow. In addition, this complex flows requires a scrupulous development of the grids for the boundary condition and the employment of adequate interpolation schemes.

  18. Impact of fuel quality and burner capacity on the performance of wood pellet stove

    Directory of Open Access Journals (Sweden)

    Petrović-Bećirović Sanja B.


    Full Text Available Pellet stoves may play an important role in Serbia in the future when fossil fuel fired conventional heating appliances are replaced by more efficient and environmentally friendly devices. Experimental investigation was conducted in order to examine the influence of wood pellet quality, as well as burner capacity (6, 8 and 10 kW, used in the same stove configuration, on the performance of pellet stove with declared nameplate capacity of 8 kW. The results obtained showed that in case of nominal load and combustion of pellets recommended by the stove manufacturer, stove efficiency of 80.03% was achieved. The use of lower quality pellet caused additional 1.13 kW reduction in heat output in case of nominal load and 0.63 kW in case of reduced load. This was attributed to less favourable properties and lower bulk and particle density of lower quality pellet. The use of different burner capacity has shown to have little effect on heat output and efficiency of the stove when pre-set values in the control system of the stove were not altered. It is concluded that replacement of the burner only is not sufficient to increase/decrease the declared capacity of the same stove configuration, meaning that additional measures are necessary. These measures include a new set up of the stove control system, which needs to be properly adjusted for each alteration in stove configuration. Without the adjustment mentioned, declared capacity of the stove cannot be altered, while its CO emission shall be considerably increased.

  19. Premixing hydrogen burners for surface refinement of glass; Vormischende Wasserstoffbrenner zur Oberflaechenbearbeitung von Glas

    Energy Technology Data Exchange (ETDEWEB)

    Goerisch, Matthias [Linde AG, Linde Gas Deutschland, Nuernberg (Germany)


    As a result, inter alia, of unceasing globalisation, European glass producers in practically all sectors - flat glass, container glass, crystal glass and special glasses - are faced with ever tougher competition from Asia. In the 2012 to 2015 period and beyond, the principal focuses in the manufacture of glass products will again be on reducing overall production costs and increasing process efficiency wherever possible, on greater productivity and on enhanced product (surface) quality. To meet these challenges in the field of surface refinement and flame polishing of glass products as efficiently as possible, Linde AG/Linde Gases Division has developed premixing Hydropox {sup registered} burner technology for hydrogen/oxygen fuels. (orig.)

  20. A numerical study of porous medium properties effect on late mixing porous burner performance

    Directory of Open Access Journals (Sweden)

    Kanokkarn Wongwatcharaphon


    Full Text Available The objective of this research is to investigate the effect of properties of porous combustor (PC of the late mixing porous burner (LMPB on the thermal structure and radiant output efficiency by mean of numerical modeling. The flow and heat transfer are one-dimensional. The combustion reaction is considered as a single-step first order reaction. The parametric study is a porosity and absorption coefficient. The results indicate that the optimum property of porous medium that is used as porous combustor of LMPB is a porosity in the range of 0.4 - 0.6 and absorption coefficient is 100.

  1. Combustion of low calorific value gases in porous burners; Verbrennung von niederkalorischen Gasen in Porenbrennern

    Energy Technology Data Exchange (ETDEWEB)

    Diezinger, S.; Talukdar, P.; Issendorff, F. von; Trimis, D. [Lehrstuhl fuer Stroemungsmechanik Friedrich-Alexander-Univ., Erlangen-Nuernberg (Germany)


    By the use of low calorific value gases significant energy amounts can be saved, emissions can be reduced and system efficients can be increased. These mixtures are generated in different fields like waste sites and fuel cell systems with reformation of hydrocarbons. Conventional combustion techniques are not suited for the combustion of this kind of gases. Due to its high internal heat recuperation the porous burner technology has great potential for the combustion of low calorific value gases. In this work the influence of the combustion zone properties, the surface load and the educt temperature were determined by numerical simulations and experiments. (orig.)

  2. Experimental verification of corrosive vapor deposition rate theory in high velocity burner rigs (United States)

    Gokoglu, S. A.; Santoro, G. J.


    The ability to predict deposition rates is required to facilitate modelling of high temperature corrosion by fused salt condensates in turbine engines. A corrosive salt vapor deposition theory based on multicomponent chemically frozen boundary layers (CFBL) has been successfully verified by high velocity burner rig experiments. The experiments involved internally air-impingement cooled, both rotating full and stationary segmented cylindrical collectors located in the crossflow of sodium-seeded combustion gases. Excellent agreement is found between the CFBL theory an the experimental measurements for both the absolute amounts of Na2SO4 deposition rates and the behavior of deposition rate with respect to collector temperature, mass flowrate (velocity) and Na concentration.

  3. Interim design status and operational report for remote handling fixtures: primary and secondary burners

    Energy Technology Data Exchange (ETDEWEB)

    Burgoyne, R.M.


    The HTGR reprocessing flowsheet consists of two basic process elements: (1) spent fuel crushing and burning and (2) solvent extraction. Fundamental to these elements is the design and development of specialized process equipment and support facilities. A major consideration of this design and development program is equipment maintenance: specifically, the design and demonstration of selected remote maintenance capabilities and the integration of these into process equipment design. This report documents the current status of the development of remote handling and maintenance fixtures for the primary and secondary burners.

  4. Numerical Study of NOx and Flame Shape of a DLE Burner


    Hamedi, Naser


    For natural gas combustion, there is a large amount of experience in the gas turbine industry. However, much of the design work is based on costly combustion tests due to insufficient accuracy of existing prediction tools for data such as emissions and effects due to fuel composition. In the present work, Computational Fluid Dynamics (CFD) approach is used to study partially premixed combustion in the 3rd generation DLE (Dry Low Emission) burner that is used in SGT-700 and SGT-800 gas turbine...

  5. Enhancing BWR proliferation resistance fuel with minor actinides (United States)

    Chang, Gray S.


    To reduce spent fuel for storage and enhance the proliferation resistance for the intermediate-term, there are two major approaches (a) increase the discharged spent fuel burnup in the advanced light water reactor- LWR (Gen-III Plus), which not only can reduce the spent fuel for storage, but also increase the 238Pu isotopes ratio to enhance the proliferation resistance, and (b) use of transuranic nuclides ( 237Np and 241Am) in the high burnup fuel, which can drastically increase the proliferation resistance isotope ratio of 238Pu/Pu. For future advanced nuclear systems, minor actinides (MA) are viewed more as a resource to be recycled, and transmuted to less hazardous and possibly more useful forms, rather than simply disposed of as a waste stream in an expensive repository facility. As a result, MAs play a much larger part in the design of advanced systems and fuel cycles, not only as additional sources of useful energy, but also as direct contributors to the reactivity control of the systems into which they are incorporated. In the study, a typical boiling water reactor (BWR) fuel unit lattice cell model with UO 2 fuel pins will be used to investigate the effectiveness of minor actinide reduction approach (MARA) for enhancing proliferation resistance and improving the fuel cycle performance in the intermediate-term goal for future nuclear energy systems. To account for the water coolant density variation from the bottom (0.76 g/cm 3) to the top (0.35 g/cm 3) of the core, the axial coolant channel and fuel pin were divided to 24 nodes. The MA transmutation characteristics at different elevations were compared and their impact on neutronics criticality discussed. The concept of MARA, which involves the use of transuranic nuclides ( 237Np and/or 241Am), significantly increases the 238Pu/Pu ratio for proliferation resistance, as well as serves as a burnable absorber to hold-down the initial excess reactivity. It is believed that MARA can play an important role in

  6. Numerical investigation on burning stability of the coal-dust methane-air mixture in a recuperative burner (United States)

    Krainov, A. Yu; Moiseeva, K. M.; Moiseev, D. M.


    The paper is devoted to numerical investigation on combustion singularities of the bi-dispersed coal-dust methane-air mixture in a slot recuperative burner. The aim of the research is to determine the stable combustion conditions of the methane-air mixture depending on the fuel flow rate at the inlet of the burner and on the parameters of the mixture (the particle size and the mass concentration of the coal particles, the percentage composition of inert particles and the methane volume content). The problem was solved by finite difference method. The regimes of stable combustion for the coal-dust methane-air mixture depending on the fuel content and the fuel flow rate at the inlet of the burner the have been defined.

  7. 40 CFR Appendix A to Part 76 - Phase I Affected Coal-Fired Utility Units With Group 1 or Cell Burner Boilers (United States)


    ... Units With Group 1 or Cell Burner Boilers A Appendix A to Part 76 Protection of Environment... 1 or Cell Burner Boilers Table 1—Phase I Tangentially Fired Units State Plant Unit Operator ALABAMA... TOWER 9 CEN ILLINOIS PUB SER. INDIANA CULLEY 2 STHERN IND GAS & EL. INDIANA CULLEY 3 STHERN IND GAS & EL...

  8. Design process and instrumentation of a low NOx wire-mesh duct burner for micro-cogeneration unit

    Energy Technology Data Exchange (ETDEWEB)

    Ramadan, O.B.; Gauthier, J.E.D. [Carleton Univ., Ottawa, ON (Canada). Dept. of Mechanical and Aerospace Engineering; Hughes, P.M.; Brandon, R. [Natural Resources Canada, Ottawa, ON (Canada). CANMET Energy Technology Centre


    Air pollution and global climate change have become a serious environmental problem leading to increasingly stringent government regulations worldwide. New designs and methods for improving combustion systems to minimize the production of toxic emissions, like nitrogen oxides (NOx) are therefore needed. In order to control smog, acid rain, ozone depletion, and greenhouse-effect warming, a reduction of nitrogen oxide is necessary. One alternative for combined electrical power and heat generation (CHP) are micro-cogeneration units which use a micro-turbine as a prime mover. However, to increase the efficiencies of these units, micro-cogeneration technology still needs to be developed further. This paper described the design process, building, and testing of a new low NOx wire-mesh duct burner (WMDB) for the development of a more efficient micro-cogeneration unit. The primary goal of the study was to develop a practical and simple WMDB, which produces low emissions by using lean-premixed surface combustion concept and its objectives were separated into four phases which were described in this paper. Phase I involved the design and construction of the burner. Phase II involved a qualitative flow visualization study for the duct burner premixer to assist the new design of the burner by introducing an efficient premixer that could be used in this new application. Phase III of this research program involved non-reacting flow modeling on the burner premixer flow field using a commercial computational fluid dynamic model. In phase IV, the reacting flow experimental investigation was performed. It was concluded that the burner successfully increased the quantity and the quality of the heat released from the micro-CHP unit and carbon monoxide emissions of less than 9 ppm were reached. 3 refs., 3 figs.

  9. Experimental and numerical investigation of flame characteristics during swirl burner operation under conventional and oxy-fuel conditions

    Directory of Open Access Journals (Sweden)

    Jovanović Rastko D.


    Full Text Available Oxy-fuel coal combustion, together with carbon capture and storage or utilization, is a set of technologies allowing to burn coal without emitting globe warming CO2. As it is expected that oxy-fuel combustion may be used for a retrofit of existing boilers, development of a novel oxy-burners is very important step. It is expected that these burners will be able to sustain stable flame in oxy-fuel conditions, but also, for start-up and emergency reasons, in conventional, air conditions. The most cost effective way of achieving dual-mode boilers is to introduce dual-mode burners. Numerical simulations allow investigation of new designs and technologies at a relatively low cost, but for the results to be trustworthy they need to be validated. This paper proposes a workflow for design, modeling, and validation of dual-mode burners by combining experimental investigation and numerical simulations. Experiments are performed with semi-industrial scale burners in 0.5 MWt test facility for flame investigation. Novel CFD model based on ANSYS FLUENT solver, with special consideration of coal combustion process, especially regarding devolatilization, ignition, gaseous and surface reactions, NOx formation, and radiation was suggested. The main model feature is its ability to simulate pulverized coal combustion under different combusting atmospheres, and thus is suitable for both air and oxy-fuel combustion simulations. Using the proposed methodology two designs of pulverized coal burners have been investigated both experimentally and numerically giving consistent results. The improved burner design proved to be a more flexible device, achieving stable ignition and combustion during both combustion regimes: conventional in air and oxy-fuel in a mixture of O2 and CO2 (representing dry recycled flue gas with high CO2 content. The proposed framework is expected to be of use for further improvement of multi-mode pulverized fuel swirl burners but can be also used

  10. Actinide-specific complexing agents: their structural and solution chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Raymond, K.N.; Freeman, G.E.; Kappel, M.J.


    The synthesis of a series of tetracatecholate ligands designed to be specific for Pu(IV) and other actinide(IV) ions has been achieved. Although these compounds are very effective as in vivo plutonium removal agents, potentiometric and voltammetric data indicate that at neutral pH full complexation of the Pu(IV) ion by all four catecholate groups does not occur. Spectroscopic results indicate that the tetracatecholates, 3,4,3-LICAMS and 3,4,3-LICAMC, complex Am(III). The Am(IV)/(III)-catecholate couple (where catecholate = 3,4,3-LICAMS or 3,4,3-LICAMC) is not observed, but may not be observable due to the large currents associated with ligand oxidation. However, within the potential range where ligand oxidation does not occur, these experiments indicate that the reduction potential of free Am(IV)/(III) is probably greater than or equal to + 2.6 V vs NHE or higher. Proof of the complexation of americium in the trivalent oxidation state by 3,4,3-LICAMS and 3,4,3-LICAMC elimates the possibility of tetracatholates stabilizing Am(IV) in vivo.

  11. Iron (III) Matrix Effects on Mineralization and Immobilization of Actinides

    Energy Technology Data Exchange (ETDEWEB)

    Cynthia-May S. Gong; Tyler A. Sullens; Kenneth R. Czerwinski


    Abstract - A number of models for the Yucca Mountain Project nuclear waste repository use studies of actinide sorption onto well-defined iron hydroxide materials. In the case of a waste containment leak, however, a complex interaction between dissolved waste forms and failed containment vessel components can lead to immediate precipitation of migratory iron and uranyl in the silicate rich near-field environment. Use of the Fe(III) and UO22+ complexing agent acetohydroxamic acid (AHA) as a colorimetric agent for visible spectrophotometry is well-known. Using the second derivative of these spectra a distinct shift in iron complexation in the presence of silicate is seen that is not seen with uranyl or alone. Silica also decreases the ability of uranyl and ferric solutions to absorb hydroxide, hastening precipitation. These ferric silicate precipitates are highly amorphous and soluble. Precipitates formed in the presence of uranyl below ~1 mol% exhibit lower solubility than precipitates from up to 50 mol % and of uranyl silicates alone.

  12. First ionization potential of the heaviest actinide lawrencium, element 103

    Directory of Open Access Journals (Sweden)

    Sato Tetsuya K.


    Full Text Available The first ionization potential (IP1 of element 103, lawrencium (Lr, has been successfully determined for the first time by using a newly developed method based on a surface ionization process. The measured IP1 value is 4.9630.080.07 eV. This value is the smallest among those of actinide elements and is in excellent agreement with the value of 4.963(15 eV predicted by state-of-the-art relativistic calculations also performed in this work. Our results strongly support that the Lr atom has an electronic configuration of [Rn]7s25f147p11/2, which is influenced by strong relativistic effects. The present work provides a reliable benchmark for theoretical calculations and also opens the way for studies on atomic properties of heavy elements with atomic number Z > 100. Moreover, the present achievement has triggered a controversy on the position of lutetium (Lu and Lr in the Periodic Table of Elements.

  13. Synthesis and Evaluation of new Polyfunctional Molecules for Group Actinide Extraction; Synthese et evaluation de Nouvelles Molecules Polyfonctionnelles pour la Separation Groupee des Actinides

    Energy Technology Data Exchange (ETDEWEB)

    Marie, C.


    The aim of this project is to design new extracting molecules for spent nuclear fuel reprocessing. In order to minimize the long-term residual radiotoxicity of the waste, the GANEX process is an option based on homogeneous recycling of actinides. All actinides (U, Np, Pu, Am, Cm), present in a highly acidic aqueous solution, would be extracted together and separated from fission products (especially from lanthanides) using liquid-liquid extraction. In this context, twenty new bi-topic ligands constituted of a nitrogen poly-aromatic unit functionalized by amide groups were synthesized. Liquid-liquid extraction tests with these ligands dissolved alone in the organic phase show that N, N, N', N'-tetra-alkyl-6, 6''(2, 2':6', 2''-terpyridine)-diamides are able to selectively extract actinides at different oxidation states (Np(V et VI), U(VI), Pu(IV), Am(III), Cm(III)) from an aqueous solution 3M HNO{sub 3}. Nevertheless, actinides(III) are poorly extracted. According to crystallographic structures of complexes with Nd(III) and U(VI) determined by X-rays diffraction, these ligands are penta-dentate. In solution (methanol), complexes stoichiometries (1:1) of Nd(III), U(VI) and Pu(IV) were determined by electro-spray ionization mass spectrometry. Stability constants, evaluated by UV-visible spectrophotometry in MeOH/H{sub 2}O solutions, confirm the selectivity of ligands toward actinides(III) with respect to lanthanides(III). Associate to nuclear magnetic resonance experiments and DFT calculations (Density Functional Theory), a better knowledge of their coordination mode was achieved. (author)

  14. Gas fired boilers: Perspective for near future fuel composition and impact on burner design process (United States)

    Schiro, Fabio; Stoppato, Anna; Benato, Alberto


    The advancements on gas boiler technology run in parallel with the growth of renewable energy production. The renewable production will impact on the fuel gas quality, since the gas grid will face an increasing injection of alternative fuels (biogas, biomethane, hydrogen). Biogas allows producing energy with a lower CO2 impact; hydrogen production by electrolysis can mitigate the issues related to the mismatch between energy production by renewable and energy request. These technologies will contribute to achieve the renewable production targets, but the impact on whole fuel gas production-to-consumption chain must be evaluated. In the first part of this study, the Authors present the future scenario of the grid gas composition and the implications on gas fed appliances. Given that the widely used premixed burners are currently designed mainly by trial and error, a broader fuel gas quality range means an additional hitch on this design process. A better understanding and structuring of this process is helpful for future appliance-oriented developments. The Authors present an experimental activity on a premixed condensing boiler setup. A test protocol highlighting the burners' flexibility in terms of mixture composition is adopted and the system fuel flexibility is characterized around multiple reference conditions.

  15. Computational fluid dynamics analysis of a synthesis gas turbulent combustion in a round jet burner (United States)

    Mansourian, Mohammad; Kamali, Reza


    In this study, the RNG-Large Eddy Simulation (RNG-LES) methodology of a synthesis gas turbulent combustion in a round jet burner is investigated, using OpenFoam package. In this regard, the extended EDC extinction model of Aminian et al. for coupling the reaction and turbulent flow along with various reaction kinetics mechanisms such as Skeletal and GRI-MECH 3.0 have been utilized. To estimate precision and error accumulation, we used the Smirinov's method and the results are compared with the available experimental data under the same conditions. As a result, it was found that the GRI-3.0 reaction mechanism has the least computational error and therefore, was considered as a reference reaction mechanism. Afterwards, we investigated the influence of various working parameters including the inlet flow temperature and inlet velocity on the behavior of combustion. The results show that the maximum burner temperature and pollutant emission are affected by changing the inlet flow temperature and velocity.

  16. Chemical and toxicological characterization of residential oil burner emissions. II. Mutagenic, tumorigenic, and potential teratogenic activity

    Energy Technology Data Exchange (ETDEWEB)

    Braun, A.G.; Busby, W.F. Jr.; Liber, H.L.; Thilly, W.G.


    Extracts of effluents from a modern residential oil burner have been evaluated in several toxicological assay systems. Bacterial mutagens were detected in extracts from both the particulate and vapor phase emissions. Effluents from continuous operation were an order of magnitude less mutagenic than those from cyclic (5 min on, 10 min off) operations. No difference in the yield of bacterial mutagens per gram of fuel burned was found between cyclic operation under low and moderate sooting conditions. On the basis of elution behavior from alumina it appeared that the bacterial mutagens collected from high sooting effluents were more polar than those from low sooting effluent. An extract that was mutagenic in bacteria did not induce a significant increase in mutation frequency to human lymphoblasts. No evidence of tumorigenicity was observed in a limited number of newborn mice after IP injection of effluent extract when compared to historical control data. Putative nonmutagenic teratogens were detected in effluent using an attachment inhibition assay. The level of these agents was reduced in effluents from continuous oil burner operation.

  17. Modeling Population Exposures to Pollutants Emitted from Natural Gas Cooking Burners

    Energy Technology Data Exchange (ETDEWEB)

    Lobscheid, Agnes; Singer, Brett C.; Klepeis, Neil E.


    We developed a physics-based data-supported model to investigate indoor pollutant exposure distributions resulting from use of natural gas cooking appliances across households in California. The model was applied to calculate time-resolved indoor concentrations of CO, NO2 and formaldehyde resulting from cooking burners and entry with outdoor air. Exposure metrics include 1-week average concentrations and frequency of exceeding ambient air quality standards. We present model results for Southern California (SoCal) using two air-exchange scenarios in winter: (1) infiltration-only, and (2) air exchange rate (AER) sampled from lognormal distributions derived from measurements. In roughly 40percent of homes in the SoCal cohort (N=6634) the 1-hour USEPA NO2 standard (190 ?g/m3) was exceeded at least once. The frequency of exceeding this standard was largely independent of AER assumption, and related primarily to building volume, emission rate and amount of burner use. As expected, AER had a more substantial impact on one-week average concentrations.

  18. A numerical investigation of the aerodynamics of a furnace with a movable block burner

    Directory of Open Access Journals (Sweden)

    T. J. Fudihara


    Full Text Available In this work the air flow in a furnace was computationally investigated. The furnace, for which experimental test data are available, is composed of a movable block burner connected to a cylindrical combustion chamber by a conical quarl. The apertures between the movable and the fixed blocks of the burner determine the ratio of the tangential to the radial air streams supplied to the furnace. Three different positions of the movable blocks were studied at this time. A three-dimensional investigation was performed by means of the finite volume method. The numerical grid was developed by the multiblock technique. The turbulence phenomenon was addressed by the RNG k-epsilon model. Profiles of the axial, tangential and radial velocities in the combustion chamber were outlined. The map of the predicted axial velocity in the combustion chamber was compared with a map of the experimental axial velocity. The internal space of the furnace was found to be partially filled with a reverse flow that extended around the longitudinal axis. A swirl number profile along the furnace length is presented and shows an unexpected increase in the swirl in the combustion chamber.

  19. Investigation of aerodynamic structure of isothermal swirl flow in a two-stage burner (United States)

    Yusupov, R. R.; Krasinsky, D. V.; Shtork, S. I.


    The work is devoted to experimental and numerical study of aerodynamic structure of a swirl flow in isothermal model of a vortex burner device that is characterized by the fluid flow supply via two sequentially-mounted tangential swirlers. Depending on the way of the flow supply into the second-stage swirler, either co-swirl or counter-swirl of two flows can be realized. The effect of the second-stage supply direction on the resulting aerodynamic structure has been investigated. Using LDA measurement system the profiles of averaged axial and tangential velocity components were obtained. Experiments have shown that in the co-swirl case the flow inside the vortex burner model is characterized by strong non-uniformity, while in the counter-swirl regime a rapid mixing of the flows from the first and second stages occurs, resulting in a uniform distribution of the flow across the chamber section. Numerical simulation of 3D isothermal turbulent flow has been performed for the counter-swirl regime using the differential Reynolds stress model in the time-dependent formulation. Using the Q-criterion for the identification of vortices in numerical data arrays, the evolution of large-scale vortex structures of the swirl flow inside the vortex chamber has been visualized, indicating the presence of two spiral-shape vortex filaments in the vortex chamber. The periodic character of dynamics of these vortex structures has been revealed.

  20. Numerical Investigation of the Low-Caloric Gas Burning Process in a Bottom Burner

    Directory of Open Access Journals (Sweden)

    Redko A.


    Full Text Available The use of low-grade gases in the fuel and energy balance of enterprises makes it possible to increase the energy efficiency of technological processes. The volumes of low-grade gases (blast furnace and coke oven gases, synthesis gas of coal gasification processes, biogas, coal gas, etc. that are utilized more significant in technological processes but their calorific value are low. At the same time artificial gases contain ballast gaseous (СО2, H2O and mechanical impurities that are harmful gas impurities. Their use requires technological preparation. Thus coal methane is characterized of high humidity, coal dust and drip moisture, variable composition. Thus was effective burning of coal methane it is required the development of constructive and regime measures that ensure a stable and complete burning of gaseous fuels. In this article it is presented the results of computer simulation of a stationary turbulent diffusion flame in a restricted space in the process of burning natural gas and coal methane in a bottom burner. The calculation results contain the fields of gear, temperature, concentration of CH4‚ CO‚ H2O‚ CO2 and nitrogen oxides. The structural elements of the flame (recirculation zone, hot "dome", mixing layer and far trace are determined. It has been established that complete combustion of coal methane in a modified bottom burner is ensured and the numerical values of nitrogen oxide concentrations in the flame are consistent with the literature data.

  1. Behaviors of tribrachial edge flames and their interactions in a triple-port burner

    KAUST Repository

    Yamamoto, Kazuhiro


    In a triple-port burner, various non-premixed flames have been observed previously. Especially for the case with two lifted flames, such configuration could be suitable in studying interaction between two tribrachial flames. In the present study, the flame characteristics have been investigated numerically by adopting a reduced kinetic mechanism in the triple-port burner. Four different types of flame configurations, including two attached flames, inner lifted/outer attached flames, inner attached/outer lifted flames, and twin lifted flames, were successfully simulated depending on the flow conditions. The representative edge propagation speed of a single lifted flame or an upstream lifted flame in the case of twin lifted flames increased as the liftoff height became higher. In the twin lifted flames, the inner lifted flame was affected appreciably when the other flame was located further upstream such that the lifted flame located further downstream encountered the axial velocity acceleration induced by the gas expansion from the lifted flame located upstream, while thermal effects were not observed since the temperature of the incoming flow toward the lifted flame was not affected. A unique flip-flop behavior between the inner and outer flames, observed experimentally previously, was successfully captured in the simulation such that the inner lifted flame became attached to the nozzle as the liftoff height of the outer lifted flame grew higher with an increase in the outer air velocity.

  2. Propagating nonpremixed edge-flames in a counterflow, annular slot burner under DC electric fields

    KAUST Repository

    Tran, Vu Manh


    Characteristics of propagating nonpremixed edge-flames were investigated in a counterflow, annular slot burner. A high-voltage direct current (DC) was applied to the lower part of the burner and the upper part was grounded, creating electric field lines perpendicular to the direction of edge-flame propagation. Upon application of an electric field, an ionic wind is caused by the migration of positive and negative ions to lower and higher electrical potential sides of a flame, respectively. Under an applied DC, we found a significant decrease in edge-flame displacement speeds unlike several previous studies, which showed an increase in displacement speed. Within a moderate range of field intensity, we found effects on flame propagation speeds to be negligible after correcting the flame displacement speed with respect to the unburned flow velocity ahead of the flame edge. This indicates that the displacement speed of an edge-flame strongly depends on ionic wind and that an electric field has little or no impact on propagation speed. The ionic wind also influenced the location of the stoichiometric contour in front of the propagating edge in a given configuration such that a propagating edge was relocated to the higher potential side due to an imbalance between ionic winds originating from positive and negative ions. In addition, we observed a steadily wrinkled flame following transient propagation of the edge-flame, a topic for future research. © 2016 The Combustion Institute

  3. Hazardous waste and used oil fuel burning; Continuing regulatory concerns for generators, marketers and burners

    Energy Technology Data Exchange (ETDEWEB)

    Voelpel, J.W. (Honigman Miller Schwartz and Cohn, Detroit, MI (US))


    With the closing of interim status 'windows' and with the interest of many present HWF blenders and burners in restricting entry into the field, the concerns and opportunities associated with the blending and burning marketplace remain topical and in some areas not yet clearly defined. Also, further regulation, such as the promised rules for burners due in April, 1987, may force some to leave the field, thus creating additional concerns and opportunities. In any event, because hazardous wastes with substantial heat value will be generated for many years to come and because of the present load on available hazardous waste incinerators, blending and burning of HWF and used oil promise to remain an extremely important means of destruction of these materials. The author presents a discussion of the following areas: history, who can blend and who can't, who can burn and who can't, regulation of combustion residuals, impact of the land disposal ban rules, and state and other federal regulatory impacts.

  4. A New Method to Measure Temperature and Burner Pattern Factor Sensing for Active Engine Control (United States)

    Ng, Daniel


    The determination of the temperatures of extended surfaces which exhibit non-uniform temperature variation is very important for a number of applications including the "Burner Pattern Factor" (BPF) of turbine engines. Exploratory work has shown that use of BPF to control engine functions can result in many benefits, among them reduction in engine weight, reduction in operating cost, increase in engine life, while attaining maximum engine efficiency. Advanced engines are expected to operate at very high temperature to achieve high efficiency. Brief exposure of engine components to higher than design temperatures due to non-uniformity in engine burner pattern can reduce engine life. The engine BPF is a measure of engine temperature uniformity. Attainment of maximum temperature uniformity and high temperatures is key to maximum efficiency and long life. A new approach to determine through the measurement of just one radiation spectrum by a multiwavelength pyrometer is possible. This paper discusses a new temperature sensing approach and its application to determine the BPF.

  5. Large-eddy simulation of a fuel-lean premixed turbulent swirl-burner

    Energy Technology Data Exchange (ETDEWEB)

    Galpin, Jeremy [IFP, B.P. 311, 92506 Rueil-Malmaison Cedex (France); INSA - CORIA - CNRS, Institut National des Sciences Appliquees de Rouen (France); Naudin, Alexandre; Vervisch, Luc; Domingo, Pascale [INSA - CORIA - CNRS, Institut National des Sciences Appliquees de Rouen (France); Angelberger, Christian; Colin, Olivier [IFP, B.P. 311, 92506 Rueil-Malmaison Cedex (France)


    Large-eddy simulation (LES) of a fuel-lean premixed turbulent swirling flame is performed, in the configuration of a burner experimentally studied by Meier et al. [Combust. Flame 150 (1-2) (2007) 2-26]. Measurements of velocity field, temperature, and major species concentrations are compared against LES results. The unresolved sub-grid scale turbulent species and temperature fluctuations are accounted for using a presumed probability density function and flamelet tabulated detailed chemistry. Before the turbulent burner is simulated, various strategies to introduce tabulated detailed chemistry into a fully compressible Navier-Stokes solver are discussed and tested for laminar flames. The objective is to ensure a proper coupling between chemical tables and unsteady solutions of the Navier-Stokes equations in their fully compressible form, accounting for the inherent constraints of high-performance computing. Comparisons of LES results with experiments are discussed in terms of filtered quantities, leading to the introduction of an extra term to account for the difference in filter sizes used in experiment and LES. Velocity, temperature, and major species LES fields are then compared against measurements. Most of the turbulent flame features are reproduced, and observed discrepancies are analyzed to seek out possible improvements of the subgrid-scale modeling. (author)

  6. Gas fired boilers: Perspective for near future fuel composition and impact on burner design process

    Directory of Open Access Journals (Sweden)

    Schiro Fabio


    Full Text Available The advancements on gas boiler technology run in parallel with the growth of renewable energy production. The renewable production will impact on the fuel gas quality, since the gas grid will face an increasing injection of alternative fuels (biogas, biomethane, hydrogen. Biogas allows producing energy with a lower CO2 impact; hydrogen production by electrolysis can mitigate the issues related to the mismatch between energy production by renewable and energy request. These technologies will contribute to achieve the renewable production targets, but the impact on whole fuel gas production-to-consumption chain must be evaluated. In the first part of this study, the Authors present the future scenario of the grid gas composition and the implications on gas fed appliances. Given that the widely used premixed burners are currently designed mainly by trial and error, a broader fuel gas quality range means an additional hitch on this design process. A better understanding and structuring of this process is helpful for future appliance-oriented developments. The Authors present an experimental activity on a premixed condensing boiler setup. A test protocol highlighting the burners' flexibility in terms of mixture composition is adopted and the system fuel flexibility is characterized around multiple reference conditions.

  7. Application of chemical structure and bonding of actinide oxide materials for forensic science

    Energy Technology Data Exchange (ETDEWEB)

    Wilkerson, Marianne Perry [Los Alamos National Laboratory


    We are interested in applying our understanding of actinide chemical structure and bonding to broaden the suite of analytical tools available for nuclear forensic analyses. Uranium- and plutonium-oxide systems form under a variety of conditions, and these chemical species exhibit some of the most complex behavior of metal oxide systems known. No less intriguing is the ability of AnO{sub 2} (An: U, Pu) to form non-stoichiometric species described as AnO{sub 2+x}. Environmental studies have shown the value of utilizing the chemical signatures of these actinide oxide materials to understand transport following release into the environment. Chemical speciation of actinide-oxide samples may also provide clues as to the age, source, or process history of the material. The scientific challenge is to identify, measure and understand those aspects of speciation of actinide analytes that carry information about material origin and history most relevant to forensics. Here, we will describe our efforts in material synthesis and analytical methods development that we will use to provide the fundamental science to characterize actinide oxide molecular structures for forensic science. Structural properties and initial results to measure structural variability of uranium oxide samples using synchrotron-based X-ray Absorption Fine Structure will be discussed.

  8. The role of the 5f valence orbitals of early actinides in chemical bonding (United States)

    Vitova, T.; Pidchenko, I.; Fellhauer, D.; Bagus, P. S.; Joly, Y.; Pruessmann, T.; Bahl, S.; Gonzalez-Robles, E.; Rothe, J.; Altmaier, M.; Denecke, M. A.; Geckeis, H.


    One of the long standing debates in actinide chemistry is the level of localization and participation of the actinide 5f valence orbitals in covalent bonds across the actinide series. Here we illuminate the role of the 5f valence orbitals of uranium, neptunium and plutonium in chemical bonding using advanced spectroscopies: actinide M4,5 HR-XANES and 3d4f RIXS. Results reveal that the 5f orbitals are active in the chemical bonding for uranium and neptunium, shown by significant variations in the level of their localization evidenced in the spectra. In contrast, the 5f orbitals of plutonium appear localized and surprisingly insensitive to different bonding environments. We envisage that this report of using relative energy differences between the 5fδ/φ and 5fπ*/5fσ* orbitals as a qualitative measure of overlap-driven actinyl bond covalency will spark activity, and extend to numerous applications of RIXS and HR-XANES to gain new insights into the electronic structures of the actinide elements.

  9. Actinides and other radionuclides in sediments and submerged plants of the Yenisei River

    Energy Technology Data Exchange (ETDEWEB)

    Bolsunovsky, A. [Institute of Biophysics, Siberian Branch of the Russian Academy of Sciences, Krasnoyarsk (Russian Federation)], E-mail:; Bondareva, L. [Institute of Biophysics, Siberian Branch of the Russian Academy of Sciences, Krasnoyarsk (Russian Federation)


    The source of radioactive contamination of the Yenisei River floodplain, including contamination with actinides, is the Mining-and-Chemical combine (MCC), which has for many years been producing weapons-grade plutonium. Actinides have been detected not only in the soil and sediment of the river but also in the biomass of aquatic plants. The aim of our investigation was to assess the levels of actinides and other radionuclides in sediments and aquatic plants both near the MCC and at a considerable distance from it, down the Yenisei River. Investigations of the Yenisei River sediment samples revealed high activity concentrations of actinides (Pu isotopes and {sup 241}Am), which were 100 times higher than their global fallout levels. Sequential extraction of radionuclides from samples of sediments collected near the MCC showed that the amounts of extracted {sup 241}Am were the largest (up to 98% of initial activity). It was found that aquatic plants of the Yenisei River collected both near the MCC discharge site and at a distance up to 200 km downstream contained several actinide isotopes. The aquatic moss, Fontinalis antipyretica, was found to contain higher levels of radionuclides than Potamogeton lucens. Leaves of P. lucens contained higher levels of radionuclides, including {sup 239}Np, than stems. Sequential extraction of radionuclides from samples of aquatic plants showed that {sup 239}Np levels in exchangeable and adsorption fractions of P. lucens biomass were higher than in the respective fractions of F. antipyretica biomass.

  10. Gas core reactors for actinide transmutation and breeder applications. Annual report

    Energy Technology Data Exchange (ETDEWEB)

    Clement, J.D.; Rust, J.H.


    This work consists of design power plant studies for four types of reactor systems: uranium plasma core breeder, uranium plasma core actinide transmuter, UF6 breeder and UF6 actinide transmuter. The plasma core systems can be coupled to MHD generators to obtain high efficiency electrical power generation. A 1074 MWt UF6 breeder reactor was designed with a breeding ratio of 1.002 to guard against diversion of fuel. Using molten salt technology and a superheated steam cycle, an efficiency of 39.2% was obtained for the plant and the U233 inventory in the core and heat exchangers was limited to 105 Kg. It was found that the UF6 reactor can produce high fluxes (10 to the 14th power n/sq cm-sec) necessary for efficient burnup of actinide. However, the buildup of fissile isotopes posed severe heat transfer problems. Therefore, the flux in the actinide region must be decreased with time. Consequently, only beginning-of-life conditions were considered for the power plant design. A 577 MWt UF6 actinide transmutation reactor power plant was designed to operate with 39.3% efficiency and 102 Kg of U233 in the core and heat exchanger for beginning-of-life conditions.

  11. Minor actinide fission induced by multi-nucleon transfer reaction in inverse kinematics

    Directory of Open Access Journals (Sweden)

    Taieb J.


    Full Text Available In the framework of nuclear waste incineration and design of new generation nuclear reactors, experimental data on fission probabilities and on fission fragment yields of minor actinides are crucial to design prototypes. Transfer-induced fission has proven to be an efficient method to study fission probabilities of actinides which cannot be investigated with standard techniques due to their high radioactivity. We report on the preliminary results of an experiment performed at GANIL that investigates fission probabilities with multi-nucleon transfer reactions in inverse kinematics between a 238U beam on a 12C target. Actinides from U to Cm were produced with an excitation energy range from 0 to 30 MeV. In addition, inverse kinematics allowed to characterize the fission fragments in mass and charge. A key point of the analysis resides in the identification of the actinides produced in the different transfer channels. The new annular telescope SPIDER was used to tag the target-like recoil nucleus of the transfer reaction and to determine the excitation energy of the actinide. The fission probability for each transfer channel is accessible and the preliminary results for 238U are promising.

  12. Swedish-German actinide migration experiment at ASPO hard rock laboratory. (United States)

    Kienzler, B; Vejmelka, P; Römer, J; Fanghänel, E; Jansson, M; Eriksen, T E; Wikberg, P


    Within the scope of a bilateral cooperation between Svensk Kärnbränslehantering (SKB) and Forschungszentrum Karlsruhe, Institut für Nukleare Entsorgung (FZK-INE), an actinide migration experiment is currently being performed at the Aspö Hard Rock Laboratory (HRL) in Sweden. This paper covers laboratory and in situ investigations on actinide migration in single-fractured granite core samples. For the in situ experiment, the CHEMLAB 2 probe developed by SKB was used. The experimental setup as well as the breakthrough of inert tracers and of the actinides Am, Np and Pu are presented. The breakthrough curves of inert tracers were analyzed to determine hydraulic properties of the fractured samples. Postmortem analyses of the solid samples were performed to characterize the flow path and the sorbed actinides. After cutting the cores, the abraded material was analyzed with respect to sorbed actinides. The slices were scanned optically to visualize the flow path. Effective volumes and inner surface areas were measured. In the experiments, only breakthrough of Np(V) was observed. In each experiment, the recovery of Np(V) was < or = 40%. Breakthrough of Am(III) and Pu(IV) as well as of Np(IV) was not observed. Copyright 2002 Elsevier Science B.V.

  13. Swedish-German actinide migration experiment at ÄSPÖ hard rock laboratory (United States)

    Kienzler, B.; Vejmelka, P.; Römer, J.; Fanghänel, E.; Jansson, M.; Eriksen, T. E.; Wikberg, P.


    Within the scope of a bilateral cooperation between Svensk Kärnbränslehantering (SKB) and Forschungszentrum Karlsruhe, Institut für Nukleare Entsorgung (FZK-INE), an actinide migration experiment is currently being performed at the Äspö Hard Rock Laboratory (HRL) in Sweden. This paper covers laboratory and in situ investigations on actinide migration in single-fractured granite core samples. For the in situ experiment, the CHEMLAB 2 probe developed by SKB was used. The experimental setup as well as the breakthrough of inert tracers and of the actinides Am, Np and Pu are presented. The breakthrough curves of inert tracers were analyzed to determine hydraulic properties of the fractured samples. Postmortem analyses of the solid samples were performed to characterize the flow path and the sorbed actinides. After cutting the cores, the abraded material was analyzed with respect to sorbed actinides. The slices were scanned optically to visualize the flow path. Effective volumes and inner surface areas were measured. In the experiments, only breakthrough of Np(V) was observed. In each experiment, the recovery of Np(V) was ≤40%. Breakthrough of Am(III) and Pu(IV) as well as of Np(IV) was not observed.

  14. Research in actinide chemistry. Final report, March 1, 1993--February 28, 1996

    Energy Technology Data Exchange (ETDEWEB)

    Choppin, G R


    The present three-year grant period has been a fruitful one for the laboratory as research entered some new areas while continuing in others in which the group has been successful. As in past grant periods, the principal focus has been on complexation of actinide elements with inorganic and organic ligands. The ligands to study have been chosen for their value (known or potential) in actinide separations or for their potential role in environmental behavior of the actinides. Since the radioactivity of some actinides limits the variety of techniques which can be used in their study, we have used {open_quotes}oxidation state analogs{close_quotes}. These analogs have the same oxidation state and very similar chemical behavior but are stable or very long-lived. Also, the analogs are chosen for their redox stability to avoid uncertainties in interpretation of systems in which several oxidations may coexist (e.g., in the case of Pu). Examples of such analogs which we have used are: Nd(III), Eu(III) for Pu(III), Am(III), Cm(III); Th(IV) for U(IV), Pu(IV); NpO{sub 2}{sup +} for PuO{sub 2}{sup +}; UO{sub 2}{sup 2+} for NpO{sub 2}{sup 2+}, PuO{sub 2}{sup 2+}. These analogs have allowed use of techniques which can increase significantly our understanding of actinide complexation.

  15. Data on Occurrence of Selected Trace Metals, Organochlorines, and Semivolatile Organic Compounds in Edible Fish Tissues From Lake Worth, Fort Worth, Texas 1999

    National Research Council Canada - National Science Library

    Moring, J. B


    .... Air Force and in collaboration with the Texas Department of Health, collected samples of edible fish tissues from Lake Worth for analysis of selected trace metals, organochlorines, and semivolatile...

  16. Derivation of the acceptance and self-worth adjustment scale. (United States)

    Tabrett, Daryl R; Latham, Keziah


    The original 55-item Nottingham Adjustment Scale (NAS) is a first generation self-report instrument constructed using classical test theory to evaluate adjustment to vision loss. This study assesses the function of the NAS using Rasch analysis in a sample of adults with visual impairment and presents a revised second-generation instrument. Ninety-nine subjects with established vision loss (median onset 5 years) were administered the NAS. Rasch analysis was performed to: (1) determine optimum response scale function, (2) aid item reduction, (3) determine reliability indices and item targeting, (4) assess unidimensionality using Rasch-based principal component analysis, (5) assess differential item functioning (notable defined as >1.0 logit), and (6) formulate person measures to correlate with Geriatric Depression Scale scores and distance visual acuity to indicate convergent and discriminant validity, respectively. Response categories exhibited underutilization, which when repaired improved response scale functioning and ordered structural calibrations. Misfitting items were removed iteratively until all items had mean-square infit and outfit values of 0.70 to 1.30. However, principal component analysis confirmed insufficient unidimensionality (two contrasts identified, eigenvalues 2.4 and 2.3). Removal of these contrasts and two further iterations restored unidimensionality. Despite item mistargeting (1.58 logits), the revised 19-item instrument demonstrated good person (0.85) and item (0.96) reliability coefficients, good convergent and discriminant validity, and no systematic differential item functioning. The resultant 19-item instrument was termed the Acceptance and Self-Worth Adjustment Scale (AS-WAS). In those with established vision loss, the 19-item Acceptance and Self-Worth Adjustment Scale is a reliable and valid instrument that estimates the level of adjustment concerned with acceptance, attitudes, self-esteem, self-efficacy, and locus of control. An

  17. The perceived relative worth of reaching and maintaining goal weight. (United States)

    O'Neil, P M; Smith, C F; Foster, G D; Anderson, D A


    To examine the perceived relative worth of reaching and maintaining a self-selected goal weight, for obese and non-obese individuals. Cross-sectional study. Twenty-five obese treatment-seekers (age 41.0 y, BMI 42.5) and a community sample of 31 obese (age 40.8 y, BMI 32.2) and 64 non-obese participants (age 32.4 y, BMI 23.4). An 18-item forced-choice questionnaire evaluating what participants would hypothetically sacrifice to reach and maintain their goal weight. Most obese treatment-seekers would hypothetically endure much to achieve their desired weight. For example, 88% or more would forego a job promotion, retiring with full-pay, eliminating the national debt, or winning their dream house or car or an all-expense-paid vacation, and smaller majorities would suffer loss of half their income or a job demotion. Many non-treatment-seeking obese would forfeit future rewards to reach goal weight, but fewer would incur negative events. About a third of non-obese participants would forgo certain positive events, but few would suffer an adverse event to achieve goal weight. Within the combined obese sample, females viewed attaining goal weight as more important than did males, but there were no significant racial differences. An index of overall worth of weight goal was related positively to current weight and BMI and negatively to goal weight as percentage of current weight (Prealistic weight goals, particularly but not exclusively by treatment-seeking and heavier obese people and those who desire greater weight loss. Clinicians should take this phenomenon into consideration, and public health initiatives should attempt to place body weight in a more balanced perspective.

  18. Recovery of actinides from TBP-Na/sub 2/Co/sub 3/ scrub-waste solutions: the ARALEX process

    Energy Technology Data Exchange (ETDEWEB)

    Horwitz, E.P.; Bloomquist, C.A.A.; Mason, G.W.; Leonard, R.A.; Ziegler, A.A.


    A flowsheet for the recovery of actinides from TBP-Na/sub 2/CO/sub 3/ scrub-waste solutions has been developed, based on batch extraction data, and tested, using laboratory-scale countercurrent extraction techniques. The process, called the ARALEX process, uses 2-ethyl-1-hexanol (2-EHOH) to extract the TBP degradation products (HDBP and H/sub 2/MBP) from acidified Na/sub 2/CO/sub 3/ scrub waste leaving the actinides in the aqueous phase. Dibutyl and monobutyl phosphoric acids are attached to the 2-EHOH molecules through hydrogen bonds, which also diminish the ability of the HDBP and H/sub 2/MBP to complex actinides. Thus all actinides remain in the aqueous raffinate. Dilute sodium hydroxide solutions can be used to back-extract the dibutyl and monobutyl phosphoric acid esters as their sodium salts. The 2-EHOH can then be recycled. After extraction of the acidified carbonate waste with 2-EHOH, the actinides may be readily extracted from the raffinate with DHDECMP or, in the case of tetra- and hexavalent actinides, with TBP. The ARALEX process can also be applied to other actinide waste streams which contain appreciable concentrations of polar organic compounds (e.g., detergents) that interfere with conventional actinide ion exchange and liquid-liquid extraction procedures. 20 figures, 6 tables.

  19. Education without Moral Worth? Kantian Moral Theory and the Obligation to Educate Others (United States)

    Martin, Christopher


    This article examines the possibility of a Kantian justification of the intrinsic moral worth of education. The author critiques a recent attempt to secure such justification via Kant's notion of the Kingdom of Ends. He gives four reasons why such an account would deny any intrinsic moral worth to education. He concludes with a tentative…

  20. Worth assessments of approach to landing. [for general aviation and air carrier pilots (United States)

    Curry, R. E.


    The objective of worth assessment is to determine a descriptive model of how attributes of a set of objects are combined into preferences for the objects. The technique is described and is applied to the assessment of worth functions in approach to landing for general aviation and air carrier pilots.

  1. Beyond Rational Autonomy: Levinas and the Incomparable Worth of the Student as Singular Other (United States)

    Joldersma, Clarence W.


    This article explores the question: Why are students of worth? Educationally, an answer often involves a Kantian response: They are of worth because they are always ends and never means. This response is usually connected to a notion of autonomy interpreted as individual, rational self-determination. The article argues for a different answer. The…

  2. 78 FR 66330 - Foreign-Trade Zone 196-Fort Worth, Texas, Authorization of Production Activity, Flextronics... (United States)


    ... Foreign-Trade Zones Board Foreign-Trade Zone 196--Fort Worth, Texas, Authorization of Production Activity, Flextronics International USA, Inc. (Mobile Phone Assembly and Kitting), Fort Worth, Texas On June 14, 2013, Flextronics International USA, Inc. submitted a notification of proposed production activity to the Foreign...

  3. 75 FR 39621 - Proposed Information Collection (Income-Net Worth and Employment Statement) Activity: Comment... (United States)


    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF VETERANS AFFAIRS Proposed Information Collection (Income-Net Worth and Employment Statement) Activity: Comment... forms of information technology. Title: Income-Net Worth and Employment Statement. OMB Control Number...

  4. Splittings, Satellites and Fine Structure in the Soft X-ray Spectroscopy of the Actinides

    Energy Technology Data Exchange (ETDEWEB)

    Tobin, J. G.; Yu, S. -W.; Chung, B. W.


    Perhaps the most demanding and powerful actinide spectroscopy is that using soft X-ray and VUV photons. Because of the relatively low energy and fairly small sampling depths of these photons and the corresponding electrons, it is necessary to use un-encapsulated samples with highly cleaned and well-prepared surfaces. This causes a myriad of sample containment problems for these radioactive materials. Despite these hindrances and difficulties, the soft-X-ray and ultra-violet spectroscopy of the actinides can provide an amazing level of detailed information, particularly having to do with 5f electronic structure. In this paper, the splittings, satellites and fine structure of the following actinide soft X-ray spectroscopies will be discussed: X-ray photoelectron spectroscopy; X-ray absorption spectroscopy; and inverse photoelectron spectroscopy, including Bremstrahlung isochromat spectroscopy and resonant inverse photoelectron spectroscopy.

  5. Strontium and Actinide Separations from High Level Nuclear Waste Solutions using Monosodium Titanate - Actual Waste Testing

    Energy Technology Data Exchange (ETDEWEB)

    Peters, T.B.; Barnes, M.J.; Hobbs,D.T.; Walker, D.D.; Fondeur, F.F.; Norato, M.A.; Pulmano, R.L.; Fink, S.D.


    Pretreatment processes at the Savannah River Site will separate {sup 90}Sr, alpha-emitting and radionuclides (i.e., actinides) and {sup 137}Cs prior to disposal of the high-level nuclear waste. Separation of {sup 90}Sr and alpha-emitting radionuclides occurs by ion exchange/adsorption using an inorganic material, monosodium titanate (MST). Previously reported testing with simulants indicates that the MST exhibits high selectivity for strontium and actinides in high ionic strength and strongly alkaline salt solutions. This paper provides a summary of data acquired to measure the performance of MST to remove strontium and actinides from actual waste solutions. These tests evaluated the effects of ionic strength, mixing, elevated alpha activities, and multiple contacts of the waste with MST. Tests also provided confirmation that MST performs well at much larger laboratory scales (300-700 times larger) and exhibits little affinity for desorption of strontium and plutonium during washing.

  6. New unsymmetrical digycolamide ligands for trivalent actinide separation

    Energy Technology Data Exchange (ETDEWEB)

    Ravi, Jammu; Venkatesan, K.A.; Antony, M.P.; Srinivasan, T.G.; Rao, P.R. Vasudeva [Indira Gandhi Centre for Atomic Research, Kalpakkam (India). Fuel Chemistry Div.


    New unsymmetrical diglycolamides (UDGAs), N,N-di-butyl-N',N'-di-dodecyl-3-oxapentane-1,5-diamide (C{sub 12}-C{sub 4}), N,N-di-dodecyl-N',N'-di-hexyl-3-oxapentane-1,5-diamide (C{sub 12}-C{sub 6}), N,N-di-decyl-N',N'-di-dodecyl-3-oxapentane-1,5-diamide (C{sub 12}-C{sub 10}) have been synthesized, and evaluated for the separation of americium(III) and europium(III) from nitric acid medium. The extraction behavior of Am(III), Eu(III), and Sr(II) in a solution of these UDGAs in n-dodecane was studied as a function of concentration of nitric acid in the aqueous phase. The distribution ratio of Am(III) and Eu(III) increased with increase in the concentration of nitric acid. The third phase formation behavior of nitric acid and neodymium(III) in 0.1 M UDGA/n-dodecane was studied. The third phase formation was not observed in all these UDGAs in n-dodecane (0.1 M), when the concentration of Nd(III) was ∝ 500 mM in 3-4M nitric acid. The stoichiometry of Am(III)-UDGA was determined from the slope analysis of the extraction data, which indicated the formation of 1:3 complex in all cases. Our studies revealed that the UDGA ligands with dodecyl group attached to one amidic nitrogen atom is inevitable for preventing third phase formation and the alkyl group at the other amidic nitrogen can be varied from butyl to decyl group for obtaining efficient extraction of trivalent actinides from high-level nuclear waste. (orig.)


    Energy Technology Data Exchange (ETDEWEB)

    Martino, C.; Herman, D.; Pike, J.; Peters, T.


    Filtration within the Actinide Removal Process (ARP) currently limits the throughput in interim salt processing at the Savannah River Site. In this process, batches of salt solution with Monosodium Titanate (MST) sorbent are concentrated by crossflow filtration. The filtrate is subsequently processed to remove cesium in the Modular Caustic Side Solvent Extraction Unit (MCU) followed by disposal in saltstone grout. The concentrated MST slurry is washed and sent to the Defense Waste Processing Facility (DWPF) for vitrification. During recent ARP processing, there has been a degradation of filter performance manifested as the inability to maintain high filtrate flux throughout a multi-batch cycle. The objectives of this effort were to characterize the feed streams, to determine if solids (in addition to MST) are precipitating and causing the degraded performance of the filters, and to assess the particle size and rheological data to address potential filtration impacts. Equilibrium modelling with OLI Analyzer{sup TM} and OLI ESP{sup TM} was performed to determine chemical components at risk of precipitation and to simulate the ARP process. The performance of ARP filtration was evaluated to review potential causes of the observed filter behavior. Task activities for this study included extensive physical and chemical analysis of samples from the Late Wash Pump Tank (LWPT) and the Late Wash Hold Tank (LWHT) within ARP as well as samples of the tank farm feed from Tank 49H. The samples from the LWPT and LWHT were obtained from several stages of processing of Salt Batch 6D, Cycle 6, Batch 16.

  8. Hybrid model predictive control applied to switching control of burner load for a compact marine boiler design

    DEFF Research Database (Denmark)

    Solberg, Brian; Andersen, Palle; Maciejowski, Jan


    This paper discusses the application of hybrid model predictive control to control switching between different burner modes in a novel compact marine boiler design. A further purpose of the present work is to point out problems with finite horizon model predictive control applied to systems for w...

  9. Making a Low-Cost Soda Can Ethanol Burner for Out-of-Laboratory Flame Test Demonstrations and Experiments (United States)

    Yu, Henson L. Lee; Domingo, Perfecto N., Jr.; Yanza, Elliard Roswell S.; Guidote, Armando M., Jr.


    This article demonstrates how to make a low-cost ethanol burner utilizing soda cans. It burns with a light blue flame suitable for out-of-laboratory flame test demonstrations where interference from a yellow flame needs to be avoided.

  10. Increasing the speed of computational fluid dynamics procedure for minimization the nitrogen oxide polution from the premixed atmospheric gas burner

    Directory of Open Access Journals (Sweden)

    Fotev Vasko G.


    Full Text Available This article presents innovative method for increasing the speed of procedure which includes complex computational fluid dynamic calculations for finding the distance between flame openings of atmospheric gas burner that lead to minimal NO pollution. The method is based on standard features included in commercial computational fluid dynamic software and shortens computer working time roughly seven times in this particular case.

  11. 41 CFR 101-26.602-3 - Procurement of gasoline, fuel oil (diesel and burner), kerosene, and solvents. (United States)


    ... 41 Public Contracts and Property Management 2 2010-07-01 2010-07-01 true Procurement of gasoline, fuel oil (diesel and burner), kerosene, and solvents. 101-26.602-3 Section 101-26.602-3 Public... REGULATIONS SUPPLY AND PROCUREMENT 26-PROCUREMENT SOURCES AND PROGRAM 26.6-Procurement Sources Other Than GSA...

  12. Biomass Suspension Combustion: Effect of Two-Stage Combustion on NOx Emissions in a Laboratory-Scale Swirl Burner

    DEFF Research Database (Denmark)

    Lin, Weigang; Jensen, Peter Arendt; Jensen, Anker Degn


    A systematic study was performed in a suspension fired 20 kW laboratory-scale swirl burner test rig for combustion of biomass and co-combustion of natural gas and biomass. The main focus is put on the effect of two-stage combustion on the NO emission, as well as its effect on the incomplete...

  13. Fuel rich and fuel lean catalytic combustion of the stabilized confined turbulent gaseous diffusion flames over noble metal disc burners

    Directory of Open Access Journals (Sweden)

    Amal S. Zakhary


    Full Text Available Catalytic combustion of stabilized confined turbulent gaseous diffusion flames using Pt/Al2O3 and Pd/Al2O3 disc burners situated in the combustion domain under both fuel-rich and fuel-lean conditions was experimentally studied. Commercial LPG fuel having an average composition of: 23% propane, 76% butane, and 1% pentane was used. The thermal structure of these catalytic flames developed over Pt/Al2O3 and Pd/Al2O3 burners were examined via measuring the mean temperature distribution in the radial direction at different axial locations along the flames. Under-fuel-rich condition the flames operated over Pt catalytic disc attained high temperature values in order to express the progress of combustion and were found to achieve higher activity as compared to the flames developed over Pd catalytic disc. These two types of catalytic flames demonstrated an increase in the reaction rate with the downstream axial distance and hence, an increase in the flame temperatures was associated with partial oxidation towards CO due to the lack of oxygen. However, under fuel-lean conditions the catalytic flame over Pd catalyst recorded comparatively higher temperatures within the flame core in the near region of the main reaction zone than over Pt disc burner. These two catalytic flames over Pt and Pd disc burners showed complete oxidation to CO2 since the catalytic surface is covered by more rich oxygen under the fuel-lean condition.

  14. Seeing red: How perceptions of social status and worth influence hostile attributions and endorsement of aggression. (United States)

    Davis, James R; Reyna, Christine


    Within social hierarchies, low social status is associated with increased vigilance, hostile expectations, and reactive aggression. We propose that societal devaluation is common across many low social status groups and produces a sense of threatened social worth. Threatened social worth may lead those of low status to be more vigilant towards social threats, thereby increasing the likelihood of hostile attributions and endorsement of aggression. Integrating theory on belongingness, social rejection, and stigma compensation, two studies test a sequential process model demonstrating that threatened social worth mediates the relationship between status, hostile attributions, and endorsement of aggression. Employing a relative status manipulation, Study 2 reveals a causal effect of status and highlights the importance of perceptions of low social status on threatened social worth. These data demonstrate the role of social worth in explaining the link between status and hostility and have implications for research in the social, health, and developmental domains. © 2015 The British Psychological Society.

  15. Investigation on Flame Characteristics and Burner Operability Issues of Oxy-Fuel Combustion

    Energy Technology Data Exchange (ETDEWEB)

    Choudhuri, Ahsan [Univ. Of Texas, El Paso, TX (United States)


    Oxy-fuel combustion has been used previously in a wide range of industrial applications. Oxy- combustion is carried out by burning a hydrocarbon fuel with oxygen instead of air. Flames burning in this configuration achieve higher flame temperatures which present opportunities for significant efficiency improvements and direct capture of CO2 from the exhaust stream. In an effort to better understand and characterize the fundamental flame characteristics of oxy-fuel combustion this research presents the experimental measurements of flame stability of various oxyfuel flames. Effects of H2 concentration, fuel composition, exhaust gas recirculation ratio, firing inputs, and burner diameters on the flame stability of these fuels are discussed. Effects of exhaust gas recirculation i.e. CO2 and H2O (steam) acting as diluents on burner operability are also presented. The roles of firing input on flame stability are then analyzed. For this study it was observed that many oxy-flames did not stabilize without exhaust gas recirculation due to their higher burning velocities. In addition, the stability regime of all compositions was observed to decrease as the burner diameter increased. A flashback model is also presented, using the critical velocity gradient gF) values for CH4-O2-CO2 flames. The second part of the study focuses on the experimental measurements of the flow field characteristics of premixed CH4/21%O2/79%N2 and CH4/38%O2/72%CO2 mixtures at constant firing input of 7.5 kW, constant, equivalence ratio of 0.8, constant swirl number of 0.92 and constant Reynolds Numbers. These measurements were taken in a swirl stabilized combustor at atmospheric pressure. The flow field visualization using Particle Imaging Velocimetry (PIV) technique is implemented to make a better understanding of the turbulence characteristics of

  16. Highly stabilized partially premixed flames of propane in a concentric flow conical nozzle burner with coflow

    KAUST Repository

    Elbaz, Ayman M.


    Partially premixed turbulent flames with non-homogeneous jet of propane were generated in a concentric flow conical nozzle burner in order to investigate the effect of the coflow on the stability and flame structure. The flame stability is first mapped and then high-speed stereoscopic particle image velocimetry, SPIV, plus OH planar laser-induced fluorescence, OH-PLIF, measurements were conducted on a subset of four flames. The jet equivalence ratio Φ = 2, Jet exit Reynolds number Re = 10,000, and degree of premixing are kept constant for the selected flames, while the coflow velocity, Uc, is progressively changed from 0 to 15 m/s. The results showed that the flame is stable between two extinction limits of mixture inhomogeneity, and the optimum stability is obtained at certain degree of mixture inhomogeneity. Increasing Φ, increases the span between these two extinction limits, while these limits converge to a single point (corresponding to optimum mixture inhomogeneity) with increasing Re. Regardless the value of Φ, increasing the coflow velocity improves the flame stability. The correlation between recessed distance of the burner tubes and the fluctuation of the mixture fraction, Δξ, shows that at Δξ around 40% of the flammability limits leads to optimum flame stability. The time averaged SPIV results show that the coflow induces a big annular recirculation zone surrounds the jet flames. The size and the location of this zone is seen to be sensitive to Uc. However, the instantaneous images show the existence of a small vortical structure close to the shear layer, where the flame resides there in the case of no-coflow. These small vertical structures are seen playing a vital role in the flame structure, and increasing the flame corrugation close to the nozzle exit. Increasing the coflow velocity expands the central jet at the expense of the jet velocity, and drags the flame in the early flame regions towards the recirculation zone, where the flame tracks

  17. A first principles investigation of the electronic structure of actinide oxides

    DEFF Research Database (Denmark)

    Petit, Leon; Svane, Axel; Szotek, Zdzislawa


    The ground state electronic structures of the actinide oxides AO, A2O3 and AO2 (A=U, Np, Pu, Am, Cm, Bk, Cf) are determined from first-principles calculations using the selfinteraction corrected local spin-density approximation. Our study reveals a strong link between preferred oxidation number...... and degree of localization. The ionic nature of the actinide oxides emerges from the fact that those oxides where the ground state is calculated to be metallic do not exist in nature, as the corresponding delocalized f-states favour the accommodation of additional O atoms into the crystal lattice....

  18. A comparison of new reagents and processes for hydrometallurgical processing of actinides

    Energy Technology Data Exchange (ETDEWEB)

    Nash, K.L. [Argonne National Lab., IL (United States). Chemistry Div


    The future viability of nuclear power as an electricity generation technology depends greatly on addressing all aspects of radioactive waste disposal. A closed fuel cycle with recycle and burnup of actinides is one important option for solving long-term waste sequestration issues. The 50 years of accumulated experience in application of solvent extraction to the processing of spent nuclear fuels uniquely qualifies this technology for actinide partitioning. However, employment of new reagents and development of new processes must be reconciled with century 21 expectations for environment protection. The interrelationship between the separations potential and waste disposal aspects of new reagents and processes are discussed in this report. (author)

  19. Synthesis of Actinide Materials for the Study of Basic Actinide Science and Rapid Separation of Fission Products

    Energy Technology Data Exchange (ETDEWEB)

    Dorhout, Jacquelyn Marie [Univ. of Nevada, Las Vegas, NV (United States)


    This dissertation covers several distinct projects relating to the fields of nuclear forensics and basic actinide science. Post-detonation nuclear forensics, in particular, the study of fission products resulting from a nuclear device to determine device attributes and information, often depends on the comparison of fission products to a library of known ratios. The expansion of this library is imperative as technology advances. Rapid separation of fission products from a target material, without the need to dissolve the target, is an important technique to develop to improve the library and provide a means to develop samples and standards for testing separations. Several materials were studied as a proof-of-concept that fission products can be extracted from a solid target, including microparticulate (< 10 μm diameter) dUO2, porous metal organic frameworks (MOFs) synthesized from depleted uranium (dU), and other organicbased frameworks containing dU. The targets were irradiated with fast neutrons from one of two different neutron sources, contacted with dilute acids to facilitate the separation of fission products, and analyzed via gamma spectroscopy for separation yields. The results indicate that smaller particle sizes of dUO2 in contact with the secondary matrix KBr yield higher separation yields than particles without a secondary matrix. It was also discovered that using 0.1 M HNO3 as a contact acid leads to the dissolution of the target material. Lower concentrations of acid were used for future experiments. In the case of the MOFs, a larger pore size in the framework leads to higher separation yields when contacted with 0.01 M HNO3. Different types of frameworks also yield different results.

  20. Testing and Modeling Fuel Regression Rate in a Miniature Hybrid Burner

    Directory of Open Access Journals (Sweden)

    Luciano Fanton


    Full Text Available Ballistic characterization of an extended group of innovative HTPB-based solid fuel formulations for hybrid rocket propulsion was performed in a lab-scale burner. An optical time-resolved technique was used to assess the quasisteady regression history of single perforation, cylindrical samples. The effects of metalized additives and radiant heat transfer on the regression rate of such formulations were assessed. Under the investigated operating conditions and based on phenomenological models from the literature, analyses of the collected experimental data show an appreciable influence of the radiant heat flux from burnt gases and soot for both unloaded and loaded fuel formulations. Pure HTPB regression rate data are satisfactorily reproduced, while the impressive initial regression rates of metalized formulations require further assessment.

  1. Pollutant exposures from unvented gas cooking burners: A Simulation-based Assessment for Southern California

    Energy Technology Data Exchange (ETDEWEB)

    Logue, Jennifer M. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Indoor Environment Group and Residential Building Systems Group; Klepeis, Neil E. [Stanford Univ., CA (United States). Dept. of Civil and Environmental Engineering; San Diego Univ., CA (United States). Center for Behavioral Epidemiology and Community Health; Lobscheid, Agnes B. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Indoor Environment Group; Singer, Brett C. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Indoor Environment Group and Residential Building Systems Group


    Residential natural gas cooking burners (NGCBs) can emit substantial quantities of pollutants, and they are typically used without venting range hoods. In this study, LBNL researchers quantified pollutant concentrations and occupant exposures resulting from NGCB use in California homes.The simulation model estimated that—in homes using NGCBs without coincident use of venting range hoods -- 62%, 9%, and 53% of occupants are routinely exposed to NO2, CO, and HCHO levels that exceed acute health-based standards and guidelines. NGCB use increased the sample median of the highest simulated 1-hr indoor concentrations by 100, 3,000, and 20 ppb for NO2, CO, and HCHO, respectively. The study recommends that reducing pollutant exposures from NGCBs should be a public health priority. Simulation results suggest that regular use of even moderately effective venting range hoods would dramatically reduce the percentage of homes in which concentrations exceed health-based standards.

  2. Deposition stress effects on the life of thermal barrier coatings on burner rigs (United States)

    Watson, J. W.; Levine, S. R.


    A study of the effect of plasma spray processing parameters on the life of a two layer thermal barrier coating was conducted. The ceramic layer was plasma sprayed at plasma arc currents of 900 and 600 amps onto uncooled tubes, cooled tubes, and solid bars of Waspalloy in a lathe with 1 or 8 passes of the plasma gun. These processing changes affected the residual stress state of the coating. When the specimens were tested in a Mach 0.3 cyclic burner rig at 1130 deg C, a wide range of coating lives resulted. Processing factors which reduced the residual stress state in the coating, such as reduced plasma temperature and increased heat dissipation, significantly increased coating life.

  3. Numerical study of turbulent normal diffusion flame CH4-air stabilized by coaxial burner

    Directory of Open Access Journals (Sweden)

    Riahi Zouhair


    Full Text Available The practical combustion systems such as combustion furnaces, gas turbine, engines, etc. employ non-premixed combustion due to its better flame stability, safety, and wide operating range as compared to premixed combustion. The present numerical study characterizes the turbulent flame of methane-air in a coaxial burner in order to determine the effect of airflow on the distribution of temperature, on gas consumption and on the emission of NOx. The results in this study are obtained by simulation on FLUENT code. The results demonstrate the influence of different parameters on the flame structure, temperature distribution and gas emissions, such as turbulence, fuel jet velocity, air jet velocity, equivalence ratio and mixture fraction. The lift-off height for a fixed fuel jet velocity is observed to increase monotonically with air jet velocity. Temperature and NOx emission decrease of important values with the equivalence ratio, it is maximum about the unity.

  4. Experiments on the TECFLAM standard burner. Final colloquium; Experimente am TECFLAM Standard-Brenner. Abschlusskolloquium

    Energy Technology Data Exchange (ETDEWEB)



    This year's annual seminar had two main subjects: First, the final colloquium of the CRAY-TECFLAM project in which an industrial code for simulation of combustion processes in furnaces and gas turbines was developed in cooperation with the relevant industry, and secondly, investigations on a TECFLAM standard burner which served to establish a reliable set of state variables by different methods that were applied simultaneously, as well as the validation of the mathematical models. [German] Das alljaehrliche oeffentliche Seminar stand in diesem Jahr unter zwei zentralen Themen: zum einen das Abschlusskolloquium des CRAY-TECFLAM-Projekts, in dem ein Industriecode zur Simulation der Verbrennungsvorgaenge in Feuerungen und Gasturbinen - unter Beteiligung der relevanten Industrie - entwickelt wurde, zum anderen die Untersuchungen am TECFLAM Standardbrenner, mit denen ein verlaesslicher Satz von Zustandsgroessen mit unterschiedlichen, aber simultan angewandten Messmethoden ermittelt wird und die mathematischen Modelle validiert werden. (orig.)

  5. Numerical Simulation of Air Staged Mechanism Effect in a High Velocity Burner

    Directory of Open Access Journals (Sweden)

    Bernardo A. Herrera-Múnera


    Full Text Available In this work, staged air combustion in a high speed burner was analyzed by mean of numerical simulation in order to determine its effects on temperature distribution and pollutant chemical species formation such as CO and NOx. The simulations were achieved using the commercial software ANSYS FLUENT as a design tool to predict the behavior of the thermal system and to establish operation conditions with or without staged air. Eddy Dissipation model was used for combustion simulation, while k - ε Realizable and Discrete Ordinates models were utilized for turbulence and radiation simulation, respectively. Results show that staged air mechanism allows better flame stabilization, combustion reactions initiation and fuel-air mixing. The CO formation was different in reaction zone and NOx emissions were not significantly influenced by the staged air.

  6. Studi Eksperimen Distribusi Temperatur Nyala Api Kompor Bioetanol Tipe Side Burner dengan Variasi Diameter Firewall

    Directory of Open Access Journals (Sweden)

    R.R. Vienna Sona Saputri Soetadi


    Full Text Available Untuk mendapatkan kompor bioetanol efisiensi thermal maksimal diperlukan penelitian komprehensif. Salah satunya adalah penelitian terhadap posisi peletakkan beban pada kompor bioetanol kompak. Pengujian dilakukan pada kompor uji bioetanol dengan kadar 99%, yaitu kompor bioetanol tipe side burner dengan firewall 2.5 inci dan firewall 3 inci. Pengukuran temperatur api dengan 13 thermocouple K dengan pengukuran searah api keatas setiap 5 mm-an. Kemudian, water boiling test dilakukan untuk mendapatkan daya dan beban dan dilanjutkan mengukur waktu pendidihan air. Hasil penelitian ini menunjukkan gambaran total distribusi temperatur nyala api difusi. Hasil menunjukkan untuk kompor 2.5 inci dengan daya 1.6 kW mempunyai temperatur 542 ºC dengan jarak ketinggian 5 mm dari rim kompor sedangkan kompor 3 inci menghasilkan daya 2.38 kW dengan temperatur 516 ºC.

  7. Use of ceramic recuperator burners for process optimization of a hearth bogie furnace; Prozessoptimierung an einem Herdwagenofen durch Einsatz keramischer Rekuperatorbrenner

    Energy Technology Data Exchange (ETDEWEB)

    Maeder, Dirk; Rakette, Roland [NOXMAT GmbH (Germany); Schlager, Stefan [Schlager Industrieofenbau GmbH, Hagen (Germany)


    Potentials for optimization are outlined using the example of a new hearth bogie furnace for a heat-treatment installation. The use of modern recuperator burners which, in this case, are employed for direct heating, favors the exhaustive exploitation of these potentials. The burner and furnace technologies are examined in detail, and initial operating experience is reported. Many of the provisions outlined can be applied analogously to other furnace types, including existing installations. Close cooperation between the burner manufacturer, the furnace engineer and the operator plays a vital role in process optimization. (orig.)


    Directory of Open Access Journals (Sweden)

    Marzena Gibczyńska


    Full Text Available The use of biomass in system energetics for the purpose of increasing the share of renewable energy sources in the overall energy mix by biomass and coal co-combustion is not an optimal solution in the light of previous experience in Poland. It is appropriate to develop local biomass market for energy purposes as a basis for future distributed energy generation based on biomass. This solution facilitates the use of ash from biomass combustion for plant fertilisation. The present paper concerns the assessment of the use of ash from combustion of pellets in an innovative gasifying pellet burner – LESTER type, for soil fertilisation. The paper presents the analysis of the content of macro- and microelements in ash against the chemical composition of pellets in relation to permissible contents in fertilisers. The content of phosphorus, potassium, calcium and magnesium in bottom and fly ash from combustion of wood pellet and rye straw in LESTER gasifying burner validates the use of this material for soil fertilisation purposes. However, due to low nitrogen content – comparable to that found in soil, the material is not to be considered as fertiliser supplying this macroelement to soil. The analysed bottom ash used for fertilisation meets the conditions set out in the Regulation of the Minister of Environment of 9 September 2002. However, fly ash should be used with considerable caution due to high content of iron, zinc and nickel. The yield of bottom ash is several times higher than that of fly ash, therefore the possibility of its use in the form of mixtures in adequate proportions should be considered.

  9. What's it worth? A general manager's guide to valuation. (United States)

    Luehrman, T A


    Behind every major resource-allocation decision a company makes lies some calculation of what that move is worth. So it is not surprising that valuation is the financial analytical skill general managers want to learn more than any other. Managers whose formal training is more than a few years old, however, are likely to have learned approaches that are becoming obsolete. What do generalists need in an updated valuation tool kit? In the 1970s, discounted-cash-flow analysis (DCF) emerged as best practice for valuing corporate assets. And one version of DCF-using the weighted-average cost of capital (WACC)-became the standard. Over the years, WACC has been used by most companies as a one-size-fits-all valuation tool. Today the WACC standard is insufficient. Improvements in computers and new theoretical insights have given rise to tools that outperform WACC in the three basic types of valuation problems managers face. Timothy Luehrman presents an overview of the three tools, explaining how they work and when to use them. For valuing operations, the DCF methodology of adjusted present value allows managers to break a problem into pieces that make managerial sense. For valuing opportunities, option pricing captures the contingent nature of investments in areas such as R&D and marketing. And for valuing ownership claims, the tool of equity cash flows helps managers value their company's stake in a joint venture, a strategic alliance, or an investment that uses project financing.

  10. Calculation of RABBIT and Simulator Worth in the HFIR Hydraulic Tube and Comparison with Measured Values

    Energy Technology Data Exchange (ETDEWEB)

    Slater, CO


    To aid in the determinations of reactivity worths for target materials in a proposed High Flux Isotope Reactor (HFIR) target configuration containing two additional hydraulic tubes, the worths of cadmium rabbits within the current hydraulic tube were calculated using a reference model of the HFIR and the MCNP5 computer code. The worths were compared to measured worths for both static and ejection experiments. After accounting for uncertainties in the calculations and the measurements, excellent agreement between the two was obtained. Computational and measurement limitations indicate that accurate estimation of worth is only possible when the worth exceeds 10 cents. Results indicate that MCNP5 and the reactor model can be used to predict reactivity worths of various samples when the expected perturbations are greater than 10 cents. The level of agreement between calculation and experiment indicates that the accuracy of such predictions would be dependent solely on the quality of the nuclear data for the materials to be irradiated. Transients that are approximated by ''piecewise static'' computational models should likewise have an accuracy that is dependent solely on the quality of the nuclear data.

  11. Contingent self-worth moderates the relationship between school stressors and psychological stress responses. (United States)

    Ishizu, Kenichiro


    This study examined the moderating role of contingent self-worth on the relationships between school stressors and psychological stress responses among Japanese adolescents. A total of 371 Japanese junior high school students (184 boys and 187 girls, Mage = 12.79 years, SD = 0.71) completed the Japanese version of the Self-Worth Contingency Questionnaire and a mental health checklist at two points separated by a two-month interval. Hierarchical multiple regression analyses were then used to determine whether contingent self-worth moderated the relationship between school stressors and psychological stress responses. The results indicated that, when psychological stress responses were controlled for at Time 1, contingent self-worth did not predict the psychological stress responses at Time 2. However, a two-way interaction between contingent self-worth and stressors was found to significantly influence psychological stress responses, thus indicating that stressors had a stronger impact on psychological stress responses among those with high contingent self-worth compared to those with low contingent self-worth. Copyright © 2017 The Foundation for Professionals in Services for Adolescents. Published by Elsevier Ltd. All rights reserved.

  12. Sorption Speciation of Lanthanides/Actinides on Minerals by TRLFS, EXAFS and DFT Studies: A Review

    Directory of Open Access Journals (Sweden)

    Xiaoli Tan


    Full Text Available Lanthanides/actinides sorption speciation on minerals and oxides by means of time resolved laser fluorescence spectroscopy (TRLFS, extended X-ray absorption fine structure spectroscopy (EXAFS and density functional theory (DFT is reviewed in the field of nuclear disposal safety research. The theoretical aspects of the methods are concisely presented. Examples of recent research results of lanthanide/actinide speciation and local atomic structures using TRLFS, EXAFS and DFT are discussed. The interaction of lanthanides/actinides with oxides and minerals as well as their uptake are also of common interest in radionuclide chemistry. Especially the sorption and inclusion of radionuclides into several minerals lead to an improvement in knowledge of minor components in solids. In the solid-liquid interface, the speciation and local atomic structures of Eu(III, Cm(III, U(VI, and Np(IV/VI in several natural and synthetic minerals and oxides are also reviewed and discussed. The review is important to understand the physicochemical behavior of lanthanides/actinides at a molecular level in the natural environment.

  13. Assessment of SFR fuel pin performance codes under advanced fuel for minor actinide transmutation

    Energy Technology Data Exchange (ETDEWEB)

    Bouineau, V.; Lainet, M.; Chauvin, N.; Pelletier, M. [French Alternative Energies and Atomic Energy Commission - CEA, CEA Cadarache, DEN/DEC/SESC, 13108 Saint Paul lez Durance (France); Di Marcello, V.; Van Uffelen, P.; Walker, C. [European Commission, Joint Research Centre, Institute for Transuranium Elements, Hermann-von-Helmholtz-Platz 1, D- 76344 Eggenstein-Leopoldshafen (Germany)


    Americium is a strong contributor to the long term radiotoxicity of high activity nuclear waste. Transmutation by irradiation in nuclear reactors of long-lived nuclides like {sup 241}Am is, therefore, an option for the reduction of radiotoxicity and residual power packages as well as the repository area. In the SUPERFACT Experiment four different oxide fuels containing high and low concentrations of {sup 237}Np and {sup 241}Am, representing the homogeneous and heterogeneous in-pile recycling concepts, were irradiated in the PHENIX reactor. The behavior of advanced fuel materials with minor actinide needs to be fully characterized, understood and modeled in order to optimize the design of this kind of fuel elements and to evaluate its performances. This paper assesses the current predictability of fuel performance codes TRANSURANUS and GERMINAL V2 on the basis of post irradiation examinations of the SUPERFACT experiment for pins with low minor actinide content. Their predictions have been compared to measured data in terms of geometrical changes of fuel and cladding, fission gases behavior and actinide and fission product distributions. The results are in good agreement with the experimental results, although improvements are also pointed out for further studies, especially if larger content of minor actinide will be taken into account in the codes. (authors)

  14. Studies of Fission-Induced Surface Damage in Actinides Using Ultracold Neutrons

    Energy Technology Data Exchange (ETDEWEB)

    Broussard, Leah J. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)


    This report describes the results of the fission-induced actinide studies at LANL. Previously, there was no fission data at these energies though there were initial characterizations of UCN energy dependence and material thickness. The proof of principle was demonstrated and the initial characterizations of sputtered rates, angular and size distribution are underway.

  15. Further studies on the absorption of actinide elements from the gastrointestinal tract of neonatal animals

    Energy Technology Data Exchange (ETDEWEB)

    Sullivan, M.F.; Gorham, L.S. (Pacific Northwest Lab., Richland, WA (USA))


    Plutonium retention was measured after intragastric administration to neonatal rats, dogs and swine. At 1 week after administration, substantially more of the actinide remained in swine and dog than in rats. The quantity of /sup 238/Pu absorbed by piglets was markedly influenced by such factors as compound solubility, mass of plutonium administered, oxidation state of the actinide, and age of the animal at gavage. Cortisone treatment reduced absorption, but was less effective in piglets than in neonatal rats. Measurements of /sup 238/Pu transport from ligated segments of the neonatal swine intestine indicated highest absorption from the duodenum, where the actinide was shown, autoradiographically, to be deposited in the epithelial region; in the ileum, deposition was predominantly in the lacteal region. Absorption of actinides by neonatal swine decreased in the order of /sup 233/U> /sup 238/Pu>/sup 237/Np>/sup 24/4Cm>/sup 241/Am. Measurements at 1 yr after gavage showed a much higher retention by swine than by rats.

  16. Further studies on the absorption of actinide elements from the gastrointestinal tract of neonatal animals

    Energy Technology Data Exchange (ETDEWEB)

    Sullivan, M.F.; Gorham, L.S.


    Plutonium retention was measured after intragastric administration to neonatal rats, dogs and swine. At 1 week after administration, substantially more of the actinide remained in swine and dogs than in rats. The quantity of /sup 238/Pu absorbed by piglets was markedly influenced by such factors as compound solubility, mass of plutonium administered, oxidation state of the actinide, and age of the animal at gavage. Cortisone treatment reduced absorption, but was less effective in piglets than in neonatal rats. Measurements of /sup 238/Pu transport from ligated segments of the neonatal swine intestine indicated highest absorption from the duodenum, where the actinide was shown, autoradiographically, to be deposited in the epithelial region; in the ileum, deposition was predominantly in the lacteal region. Absorption of actinides by neonatal swine decreased in the order of /sup 233/U greater than /sup 238/Pu greater than /sup 237/Np greater than /sup 244/Cm greater than /sup 241/Am. Measurements at 1 yr after gavage showed a much higher retention by swine than by rats.

  17. New orthophosphates matrices of the NZP-like structure for immobilization of actinides

    Energy Technology Data Exchange (ETDEWEB)

    Tomilin, S.V.; Lukinykh, A.N.; Lizin, A.A.; Spirykov, V.I. [FSUE SSC RF ' ' Research Institute of Atomic Reactors' ' , Dimitrovgrad (Russian Federation); Orlova, A.I. [Nizhny Novgorod State Univ. (Russian Federation)


    This work presents the results of synthesis and X-ray diffraction analysis of new actinides orthophosphates A{sup I}M{sub 2}{sup IV}(PO{sub 4}){sub 3} where A{sup I} = Li, Na, K, Rb; and M{sup IV} = U, Np and Pu. The compounds were obtained by the high-temperature synthesis. (orig.)


    Energy Technology Data Exchange (ETDEWEB)

    Maxwell, S; Jay Hutchison, J; Don Faison, D


    The analysis of actinides in animal tissue samples is very important for environmental monitoring. There is a need to measure actinide isotopes with very low detection limits in animal tissue samples, including fish, deer, hogs, beef and shellfish. A new, rapid actinide separation method has been developed and implemented that allows the measurement of plutonium, neptunium, uranium, americium, curium and strontium isotopes in large animal tissue samples (100-200 g) with high chemical recoveries and effective removal of matrix interferences. This method uses stacked TEVA Resin{reg_sign}, TRU Resin{reg_sign} and DGA-Resin{reg_sign} cartridges from Eichrom Technologies (Darien, IL, USA) that allows the rapid separation of plutonium (Pu), neptunium (Np), uranium (U), americium (Am), and curium (Cm) using a single multi-stage column combined with alpha spectrometry. Sr-90 is collected on Sr Resin{reg_sign} from Eichrom Technologies (Darien, IL, USA). After acid digestion and furnace heating of the animal tissue samples, the actinides and Sr-89/90 are separated using column extraction chromatography. This method has been shown to be effective over a wide range of animal tissue matrices. By using vacuum box cartridge technology with rapid flow rates, sample preparation time is minimized.

  19. Screening Evaluation of Alternate Sorbents and Methods for Strontium and Actinide Removal from Alkaline Salt Solution

    Energy Technology Data Exchange (ETDEWEB)

    Hobbs, D.T.


    This report describes results from screening tests evaluating strontium and actinide removal characteristics of three different titanium-containing sorbents, crystalline silicotitanate (CST) manufactured by UPO, SrTreat(R) offered by Fortum Engineering, sodium nonatitanate developed by Clearfield and coworkers at Texas A and M University and offered commercially by Honeywell. We also report results from an alternate removal method, coprecipitation.

  20. Georgia Institute of Technology research on the Gas Core Actinide Transmutation Reactor (GCATR) (United States)

    Clement, J. D.; Rust, J. H.; Schneider, A.; Hohl, F.


    The program reviewed is a study of the feasibility, design, and optimization of the GCATR. The program is designed to take advantage of initial results and to continue work carried out on the Gas Core Breeder Reactor. The program complements NASA's program of developing UF6 fueled cavity reactors for power, nuclear pumped lasers, and other advanced technology applications. The program comprises: (1) General Studies--Parametric survey calculations performed to examine the effects of reactor spectrum and flux level on the actinide transmutation for GCATR conditions. The sensitivity of the results to neutron cross sections are to be assessed. Specifically, the parametric calculations of the actinide transmutation are to include the mass, isotope composition, fission and capture rates, reactivity effects, and neutron activity of recycled actinides. (2) GCATR Design Studies--This task is a major thrust of the proposed research program. Several subtasks are considered: optimization criteria studies of the blanket and fuel reprocessing, the actinide insertion and recirculation system, and the system integration. A brief review of the background of the GCATR and ongoing research is presented.

  1. Inter-comparison of Hauser-Feshbach model codes toward better actinide evaluations

    Directory of Open Access Journals (Sweden)

    Capote Roberto


    Full Text Available The Hauser-Feshbach codes, EMPIRE, TALYS, CCONE, and CoH3, which are widely utilized in nuclear data evaluations, are compared, with a particular focus on neutron-induced reactions on major actinides. We report the results of Hauser-Feshbach calculations using well-defined input parameters, and discuss the differences among these codes.

  2. Uncertainty of Doppler reactivity worth due to uncertainties of JENDL-3.2 resonance parameters

    Energy Technology Data Exchange (ETDEWEB)

    Zukeran, Atsushi [Hitachi Ltd., Hitachi, Ibaraki (Japan). Power and Industrial System R and D Div.; Hanaki, Hiroshi; Nakagawa, Tuneo; Shibata, Keiichi; Ishikawa, Makoto


    Analytical formula of Resonance Self-shielding Factor (f-factor) is derived from the resonance integral (J-function) based on NR approximation and the analytical expression for Doppler reactivity worth ({rho}) is also obtained by using the result. Uncertainties of the f-factor and Doppler reactivity worth are evaluated on the basis of sensitivity coefficients to the resonance parameters. The uncertainty of the Doppler reactivity worth at 487{sup 0}K is about 4 % for the PNC Large Fast Breeder Reactor. (author)

  3. Sigma Team for Advanced Actinide Recycle FY2015 Accomplishments and Directions

    Energy Technology Data Exchange (ETDEWEB)

    Moyer, Bruce A. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)


    The Sigma Team for Minor Actinide Recycle (STAAR) has made notable progress in FY 2015 toward the overarching goal to develop more efficient separation methods for actinides in support of the United States Department of Energy (USDOE) objective of sustainable fuel cycles. Research in STAAR has been emphasizing the separation of americium and other minor actinides (MAs) to enable closed nuclear fuel recycle options, mainly within the paradigm of aqueous reprocessing of used oxide nuclear fuel dissolved in nitric acid. Its major scientific challenge concerns achieving selectivity for trivalent actinides vs lanthanides. Not only is this challenge yielding to research advances, but technology concepts such as ALSEP (Actinide Lanthanide Separation) are maturing toward demonstration readiness. Efforts are organized in five task areas: 1) combining bifunctional neutral extractants with an acidic extractant to form a single process solvent, developing a process flowsheet, and demonstrating it at bench scale; 2) oxidation of Am(III) to Am(VI) and subsequent separation with other multivalent actinides; 3) developing an effective soft-donor solvent system for An(III) selective extraction using mixed N,O-donor or all-N donor extractants such as triazinyl pyridine compounds; 4) testing of inorganic and hybrid-type ion exchange materials for MA separations; and 5) computer-aided molecular design to identify altogether new extractants and complexants and theory-based experimental data interpretation. Within these tasks, two strategies are employed, one involving oxidation of americium to its pentavalent or hexavalent state and one that seeks to selectively complex trivalent americium either in the aqueous phase or the solvent phase. Solvent extraction represents the primary separation method employed, though ion exchange and crystallization play an important role. Highlights of accomplishments include: Confirmation of the first-ever electrolytic oxidation of Am(III) in a

  4. Effect on Particulate and Gas Emissions by Combusting Biodiesel Blend Fuels Made from Different Plant Oil Feedstocks in a Liquid Fuel Burner

    National Research Council Canada - National Science Library

    Abdul Rahim, Norwazan; Mohd Jaafar, Mohammad; Sapee, Syazwan; Elraheem, Hazir


    .... The biodiesel blend fuel combustion experiments were carried out using a liquid fuel burner and biodiesel fuel made from various plant oil feedstocks, including jatropha, palm and coconut oils...

  5. The role of actinide burning and the Integral Fast Reactor in the future of nuclear power

    Energy Technology Data Exchange (ETDEWEB)

    Hollaway, W.R.; Lidsky, L.M.; Miller, M.M.


    A preliminary assessment is made of the potential role of actinide burning and the Integral Fast Reactor (IFR) in the future of nuclear power. The development of a usable actinide burning strategy could be an important factor in the acceptance and implementation of a next generation of nuclear power. First, the need for nuclear generating capacity is established through the analysis of energy and electricity demand forecasting models which cover the spectrum of bias from anti-nuclear to pro-nuclear. The analyses take into account the issues of global warming and the potential for technological advances in energy efficiency. We conclude, as do many others, that there will almost certainly be a need for substantial nuclear power capacity in the 2000--2030 time frame. We point out also that any reprocessing scheme will open up proliferation-related questions which can only be assessed in very specific contexts. The focus of this report is on the fuel cycle impacts of actinide burning. Scenarios are developed for the deployment of future nuclear generating capacity which exploit the advantages of actinide partitioning and actinide burning. Three alternative reactor designs are utilized in these future scenarios: The Light Water Reactor (LWR); the Modular Gas-Cooled Reactor (MGR); and the Integral Fast Reactor (FR). Each of these alternative reactor designs is described in some detail, with specific emphasis on their spent fuel streams and the back-end of the nuclear fuel cycle. Four separation and partitioning processes are utilized in building the future nuclear power scenarios: Thermal reactor spent fuel preprocessing to reduce the ceramic oxide spent fuel to metallic form, the conventional PUREX process, the TRUEX process, and pyrometallurgical reprocessing.

  6. Analysis and optimization of minor actinides transmutation blankets with regards to neutron and gamma sources

    Directory of Open Access Journals (Sweden)

    Kooyman Timothée


    Full Text Available Heterogeneous loading of minor actinides in radial blankets is a potential solution to implement minor actinides transmutation in fast reactors. However, to compensate for the lower flux level experienced by the blankets, the fraction of minor actinides to be loaded in the blankets must be increased to maintain acceptable performances. This severely increases the decay heat and neutron source of the blanket assemblies, both before and after irradiation, by more than an order of magnitude in the case of neutron source for instance. We propose here to implement an optimization methodology of the blankets design with regards to various parameters such as the local spectrum or the mass to be loaded, with the objective of minimizing the final neutron source of the spent assembly while maximizing the transmutation performances of the blankets. In a first stage, an analysis of the various contributors to long- and short-term neutron and gamma source is carried out whereas in a second stage, relevant estimators are designed for use in the effective optimization process, which is done in the last step. A comparison with core calculations is finally done for completeness and validation purposes. It is found that the use of a moderated spectrum in the blankets can be beneficial in terms of final neutron and gamma source without impacting minor actinides transmutation performances compared to more energetic spectrum that could be achieved using metallic fuel for instance. It is also confirmed that, if possible, the use of hydrides as moderating material in the blankets is a promising option to limit the total minor actinides inventory in the fuel cycle. If not, it appears that focus should be put upon an increased residence time for the blankets rather than an increase in the acceptable neutron source for handling and reprocessing.


    Energy Technology Data Exchange (ETDEWEB)

    Rudisill, T.; Thompson, M.


    Processes for the removal of residual sludge from SRS waste tanks have historically used solutions containing up to 0.9 M oxalic acid to dissolve the remaining material following sludge removal. The selection of this process was based on a comparison of a number of studies performed to evaluate the dissolution of residual sludge. In contrast, the dissolution of the actinide mass, which represents a very small fraction of the waste, has not been extensively studied. The Pu, Np, and Am in the sludge is reported to be present as hydrated and crystalline oxides. To identify aqueous solutions which have the potential to increase the solubility of the actinides, the alkaline and mildly acidic test solutions shown below were selected as candidates for use in a series of solubility experiments. The efficiency of the solutions in solubilizing the actinides was evaluated using a simulated sludge prepared by neutralizing a HNO{sub 3} solution containing Pu, Np, and Am. The hydroxide concentration was adjusted to a 1.2 M excess and the solids were allowed to age for several weeks prior to starting the experiments. The sludge was washed with 0.01 M NaOH to prepare the solids for use. Following the addition of an equal portion of the solids to each test solution, the concentrations of Pu, Np, and Am were measured as a function of time over a 792 h (33 day) period to provide a direct comparison of the efficiency of each solution in solubilizing the actinide elements. Although the composition of the sludge was limited to the hydrated actinide oxides (and did not contain other components of demonstrated importance), the results of the study provides guidance for the selection of solutions which should be evaluated in subsequent tests with a more realistic surrogate sludge and actual tank waste.

  8. Correlation of retention of lanthanide and actinide complexes with stability constants and their speciation

    Energy Technology Data Exchange (ETDEWEB)

    Datta, A.; Sivaraman, N.; Viswanathan, K.S.; Ghosh, Suddhasattwa; Srinivasan, T.G.; Vasudeva Rao, P.R. [Indira Gandhi Centre for Atomic Research, Kalpakkam (India). Chemistry Group


    The present study describes a correlation that is developed from retention of lanthanide and actinide complexes with the stability constant. In these studies, an ion-pairing reagent, camphor-10-sulphonic acid (CSA) was used as the modifier and organic acids such as {alpha}-hydroxy isobutyric acid ({alpha}-HIBA), mandelic acid, lactic acid and tartaric acid were used as complexing reagent for elution. From these studies, a correlation has been established between capacity factor of a metal ion, concentration of ion-pairing reagent and complexing agent with the stability constant of metal complex. Based on these studies, it has been shown that the stability constant of lanthanide and actinide complexes can be estimated using a single lanthanide calibrant. Validation of the method was carried out with the complexing agents such as {alpha}-HIBA and lactic acid. It was also demonstrated that data from a single chromatogram can be used for estimation of stability constant at various ionic strengths. These studies also demonstrated that the method can be applied for estimation of stability constant of actinides with a ligand whose value is not reported yet, e.g., ligands of importance in the lanthanide-actinide separations, chelation therapy etc. The chromatographic separation method is fast and the estimation of stability constant can be done in a very short time, which is a significant advantage especially in dealing with radioactive elements. The stability constant data was used to derive speciation data of plutonium in different oxidation states as well as that of americium with {alpha}-HIBA. The elution behavior of actinides such as Pu and Am from reversed phase chromatographic technique could be explained based on these studies. (orig.)

  9. Actinide partitioning studies using dihexyl-N,N-diethycarbamolymehtyl phosphonate and dissolved zirconium calcine

    Energy Technology Data Exchange (ETDEWEB)

    Brewer, K.N.; Herbst, R.S.; Law, J.D.; Garn, T.G.; Tillotson, R.D.; Todd, T.A.


    A baseline flowsheet capable of partitioning the transuranic (TRU) elements from dissolved zirconium calcines has been developed. The goal of the TRU partitioning process is to remove the TRUs from solutions of dissolved zirconium calcines to below the 10 CFR 61.55 Class A waste limit of 10 nCi/g. Extraction, scrub, strip, and wash distribution coefficients for several elements, including the actinides, were measured in the laboratory by performing equal volume batch contacts. A solvent containing diheyl-N, N- diethylcarbamoylmethyl phosphonate (CMP), tributylphosphate (TBP), and a branched chain hydrocarbon as the diluent were used to develop this process. A non-radioactive zirconium pilot-plant calcine was spiked with the TRUs, U, Tc, or a radioactive isotope of zirconium to simulate the behavior of these elements in actual dissolved zirconium calcine feed. Distribution coefficient data obtained from laboratory testing were used to recommend: (1) solvent composition, (2) scrub solutions capable of selectively removing extracted zirconium while minimizing actinide recycle, (3) optimized strip solutions which quantitatively recover extracted actinides, and (4) feed adjustments necessary for flowsheet efficiency. Laboratory distribution coefficients were used in conjunction with the Generic TRUEX Model (GTM) to develop and recommend a flowsheet for testing in the 5.5-cm Centrifugal Contractor Mockup. GTM results indicate that the recommended flowsheet should remove the actinides from dissolved zirconium calcine feed to below the Class A waste limit of 10 nCi/g. Less than 0.01 wt% of the extracted zirconium will report to the high- activity waste (HAW) fraction using the 0.05 M H{sub 2}C{sub 2}O{sub 4} in 3.0 M HNO{sub 3} scrub, and greater than 99% of the extracted actinides are recovered with 0.001 M HEDPA.

  10. Analysis and optimization of minor actinides transmutation blankets with regards to neutron and gamma sources (United States)

    Kooymana, Timothée; Buiron, Laurent; Rimpault, Gérald


    Heterogeneous loading of minor actinides in radial blankets is a potential solution to implement minor actinides transmutation in fast reactors. However, to compensate for the lower flux level experienced by the blankets, the fraction of minor actinides to be loaded in the blankets must be increased to maintain acceptable performances. This severely increases the decay heat and neutron source of the blanket assemblies, both before and after irradiation, by more than an order of magnitude in the case of neutron source for instance. We propose here to implement an optimization methodology of the blankets design with regards to various parameters such as the local spectrum or the mass to be loaded, with the objective of minimizing the final neutron source of the spent assembly while maximizing the transmutation performances of the blankets. In a first stage, an analysis of the various contributors to long and short term neutron and gamma source is carried out while in a second stage, relevant estimators are designed for use in the effective optimization process, which is done in the last step. A comparison with core calculations is finally done for completeness and validation purposes. It is found that the use of a moderated spectrum in the blankets can be beneficial in terms of final neutron and gamma source without impacting minor actinides transmutation performances compared to more energetic spectrum that could be achieved using metallic fuel for instance. It is also confirmed that, if possible, the use of hydrides as moderating material in the blankets is a promising option to limit the total minor actinides inventory in the fuel cycle. If not, it appears that focus should be put upon an increased residence time for the blankets rather than an increase in the acceptable neutron source for handling and reprocessing.

  11. The effects of actinide based fuels on incremental cross sections in a Candu reactor

    Energy Technology Data Exchange (ETDEWEB)

    Morreale, A.C.; Ball, M.R.; Novog, D.R.; Luxat, J.C., E-mail:, E-mail:, E-mail:, E-mail: [Department of Engineering Physics, McMaster University, Ontario (Canada)


    The reprocessing of spent fuel such as the extraction of actinide materials for use in mixed oxide fuels is a key component of reducing the end waste from nuclear power plant operations. Using recycled spent fuels in current reactors is becoming a popular option to help close the fuel cycle. In order to ensure safe and consistent operations in existing facilities, the properties of these fuels must be compatible with current reactor designs. This paper examines the features of actinide mixed oxide fuel, TRUMOX, in a CANDU reactor. Specifically, the effect of this fuel design on the incremental cross sections related to the use of adjuster rods is investigated. The actinide concentrations studied in this work were based on extraction from thirty year cooled spent fuel and mixed with natural uranium to yield a MOX fuel of 4.75% actinide by weight. The incremental cross sections were calculated using the DRAGON neutron transport code. The results for the actinide fuel were compared to those for standard natural uranium fuel and for a slightly enriched (1% U-235) fuel designed to reduce void reactivity. Adjuster reactivity effect calculations and void reactivity simulations were also performed. The impact of the adjuster on reactivity decreased by as much as 56% with TRUMOX fuel while the CVR was reduced by 71% due to the addition of central burnable poison. The incremental cross sections were largely affected by the use of the TRUMOX fuel primarily due to its increased level of fissile material (five times that of NU). The largest effects are in the thermal neutron group where the Σ{sub T} value is increased by 46.7%, the Σ{sub ny)} values increased by 13.0% and 9.9%. The value associated with thermal fission, υΣ{sub f}, increased by 496.6% over regular natural uranium which is expected due to the much higher reactivity of the fuel. (author)

  12. ISOS: A job evaluation system to implement comparable worth

    Directory of Open Access Journals (Sweden)

    Albert Corominas


    Full Text Available A fair pay structure is an essential element of the personnel policy of a firm. If the pay structure is perceived as arbitrary by the members of the staff, it becomes a cause of disturbance of the labor relations. Particularly, a pay structure is unfair if it discriminates against women. Job evaluation is a traditional tool used by companies to assist in the process of determining pay structures that can be also useful to detect and combat wage discrimination, since allow determining whether two jobs are of comparable worth or not. Although there are many kinds of systems, authors agree when defining point factor methods as the most appropriate and fair job evaluation systems. However, even being well defined from a technical point of view, most existing systems give discriminatory results regarding to gender. ISOS, a new job evaluation system which is described in this paper, has been designed, with the aim to define a neutral system with regard to gender, based on present jobs characteristics, existing job evaluation systems and job description questionnaires, international experts’ knowledge and a wide body of literature on gender discrimination and its relation with job evaluation. Using ISOS can contribute to detect, combat and eliminate part of the existing wage discrimination in general and, in particular, against women. ISOS includes all aspects of the work so no characteristics are omitted. The system can be applied in any company and to evaluate any job, and offers flexibility to be adapted to the specific characteristics of an organization. ISOS can also be used to detect and combat wage discrimination. Furthermore, characteristics of present jobs, such as cross-training or flexible working time, are also included so the system can be considered innovative in a very traditional field of industrial engineering.

  13. Freight Advanced Traveler Information System (FRATIS) - Dallas-Fort Worth (DFW) prototype : final report. (United States)

    This is the Final Report for the FRATIS Dallas-Fort Worth DFW prototype system. The FRATIS prototype in : DFW consisted of the following components: optimization algorithm, terminal wait time, route specific : navigation/traffic/weather, and advanced...

  14. An investigation of the associations between contingent self-worth and aspirations among Iranian university students. (United States)

    Sabzehara, Milad; Ferguson, Yuna Lee; Sarafraz, Mehdi Reza; Mohammadi, Mostafa


    This study investigated the novel associations between intrinsic and extrinsic aspirations and internal and external domains of contingent self-worth among a sample of 502 Iranian university students. We found a meaningful pattern showing that intrinsic aspirations were positively associated with internal domains, whereas extrinsic aspirations were positively associated with external domains. Our survey data also suggested that the factor structure of the Aspiration Index, as well as the factor structure of the Contingencies of Self-Worth Scale in our Iranian sample were consistent with factor structures of foreign samples. Finally, the types of aspirations and domains of contingencies of self-worth meaningfully predicted variables related to well-being, confirming previous research. We discuss the nature of the associations between the aspirations and the domains of contingent self-worth.

  15. For the First Time, Life Seems Worth Living | NIH MedlinePlus the Magazine (United States)

    ... page please turn JavaScript on. Feature: Depression For the First Time, Life Seems Worth Living Past Issues / ... ends. But research is continuing. Dr. Carlos Zarate: "The research on ketamine is very exciting." Carlos A. ...

  16. Healthy Blood Pressure "It's worth the effort!" | NIH MedlinePlus the Magazine (United States)

    ... page please turn Javascript on. Special Section: Healthy Blood Pressure Healthy Blood Pressure: "It's worth the effort!" Past Issues / Winter 2010 ... Photo: Christopher Klose Cheryl Fells controls her high blood pressure through regular exercise and healthy eating By Christopher ...

  17. Heat transfer characteristics of a porous radiant burner under the influence of a 2-D radiation field

    Energy Technology Data Exchange (ETDEWEB)

    Talukdar, Prabal; Mishra, S.C. E-mail:; Trimis, D.; Durst, F


    This paper deals with the heat transfer analysis of a 2-D rectangular porous radiant burner. Combustion in the porous medium is modelled as a spatially dependent heat generation zone. The gas and the solid phases are considered in non-local thermal equilibrium, and separate energy equations are used for the two phases. The solid phase is assumed to be absorbing, emitting and scattering, while the gas phase is considered transparent to radiation. The radiative part of the energy equation is solved using the collapsed dimension method. The alternating direction implicit scheme is used to solve the transient 2-D energy equations. Effects of various parameters on the performance of the burner are studied.

  18. Flat flame burner on an aluminium melting and holding furnace. A demonstration at Alycast Ltd. (Telford (GB)). Final report

    Energy Technology Data Exchange (ETDEWEB)


    The installation of a flat flame burner furnace at a pressure diecasting foundry as part of a UK Energy Efficiency Demonstration Project is described. The new furnace has a higher thermal efficiency, requires reduced maintenance and has increased operational flexibility compared to conventional furnaces. The energy savings are such as to achieve a payback period of six months. Suggestions for future improvements are also included.

  19. Central fuel worth in the Fast Test Reactor (FTR) engineering mockup

    Energy Technology Data Exchange (ETDEWEB)

    Dobbin, K.D.; Daughtry, J.W.


    An experiment was performed in the FTR-EMC to measure the total reactivity worth and the axial worth profile of withdrawing the central subassembly into the axial regions above the core. Calculations using three-dimensional X-Y-Z and two-dimensional R-Z models have been made to obtain reactivity worths for comparison with the experimental results. Another experiment measured the reactivity worth of replacing the fueled section of the central subassembly with sodium channel composition. The purposes of the analysis of this experiment are: (1) to determine if the C/E values obtained in the earlier three-dimensional calculations could be reproduced using another experiment from the FTR engineering mockup for comparison, (2) to determine what type of axial buckling adjustments are required to give the same calculated central fuel worths with a two-dimensional X-Y model that were obtained using the three-dimensional model, and (3) to obtain C/E values for the worths of an inner driver subassembly and an outer driver subassembly relative to sodium channel composition at the center of the EMC. A brief description of the experiments, a detailed explanation of the analytical methods, the measured and calculated results, and a comparison of these results.


    Energy Technology Data Exchange (ETDEWEB)

    Heaven, Michael C.; Gibson, John K.; Marcalo, Joaquim


    In this chapter we review the spectroscopic data for actinide molecules and the reaction dynamics for atomic and molecular actinides that have been examined in the gas phase or in inert cryogenic matrices. The motivation for this type of investigation is that physical properties and reactions can be studied in the absence of external perturbations (gas phase) or under minimally perturbing conditions (cryogenic matrices). This information can be compared directly with the results from high-level theoretical models. The interplay between experiment and theory is critically important for advancing our understanding of actinide chemistry. For example, elucidation of the role of the 5f electrons in bonding and reactivity can only be achieved through the application of experimentally verified theoretical models. Theoretical calculations for the actinides are challenging due the large numbers of electrons that must be treated explicitly and the presence of strong relativistic effects. This topic has been reviewed in depth in Chapter 17 of this series. One of the goals of the experimental work described in this chapter has been to provide benchmark data that can be used to evaluate both empirical and ab initio theoretical models. While gas-phase data are the most suitable for comparison with theoretical calculations, there are technical difficulties entailed in generating workable densities of gas-phase actinide molecules that have limited the range of species that have been characterized. Many of the compounds of interest are refractory, and problems associated with the use of high temperature vapors have complicated measurements of spectra, ionization energies, and reactions. One approach that has proved to be especially valuable in overcoming this difficulty has been the use of pulsed laser ablation to generate plumes of vapor from refractory actinide-containing materials. The vapor is entrained in an inert gas, which can be used to cool the actinide species to room

  1. Is It Worth It? - the Economics of Reusable Space Transportation (United States)

    Webb, Richard


    Over the past several decades billions of dollars have been invested by governments and private companies in the pursuit of lower cost access to space through earth-to-orbit (ETO) space transportation systems. Much of that investment has been focused on the development and operation of various forms of reusable transportation systems. From the Space Shuttle to current efforts by private commercial companies, the overarching belief of those making such investments has been that reusing system elements will be cheaper than utilizing expendable systems that involve throwing away costly engines, avionics, and other hardware with each flight. However, the view that reusable systems are ultimately a "better" approach to providing ETO transportation is not held universally by major stakeholders within the space transportation industry. While the technical feasibility of at least some degree of reusability has been demonstrated, there continues to be a sometimes lively debate over the merits and drawbacks of reusable versus expendable systems from an economic perspective. In summary, is it worth it? Based on our many years of direct involvement with the business aspects of several expendable and reusable transportation systems, it appears to us that much of the discussion surrounding reusability is hindered by a failure to clearly define and understand the financial and other metrics by which the financial "goodness" of a reusable or expandable approach is measured. As stakeholders, the different users and suppliers of space transportation have a varied set of criteria for determining the relative economic viability of alternative strategies, including reusability. Many different metrics have been used to measure the affordability of space transportation, such as dollars per payload pound (kilogram) to orbit, cost per flight, life cycle cost, net present value/internal rate of return, and many others. This paper will examine the key considerations that influence

  2. Actinide bioimaging in tissues: Comparison of emulsion and solid track autoradiography techniques with the iQID camera.

    Directory of Open Access Journals (Sweden)

    Stephanie Lamart

    Full Text Available This work presents a comparison of three autoradiography techniques for imaging biological samples contaminated with actinides: emulsion-based, plastic-based autoradiography and a quantitative digital technique, the iQID camera, based on the numerical analysis of light from a scintillator screen. In radiation toxicology it has been important to develop means of imaging actinide distribution in tissues as these radionuclides may be heterogeneously distributed within and between tissues after internal contamination. Actinide distribution determines which cells are exposed to alpha radiation and is thus potentially critical for assessing absorbed dose. The comparison was carried out by generating autoradiographs of the same biological samples contaminated with actinides with the three autoradiography techniques. These samples were cell preparations or tissue sections collected from animals contaminated with different physico-chemical forms of actinides. The autoradiograph characteristics and the performances of the techniques were evaluated and discussed mainly in terms of acquisition process, activity distribution patterns, spatial resolution and feasibility of activity quantification. The obtained autoradiographs presented similar actinide distribution at low magnification. Out of the three techniques, emulsion autoradiography is the only one to provide a highly-resolved image of the actinide distribution inherently superimposed on the biological sample. Emulsion autoradiography is hence best interpreted at higher magnifications. However, this technique is destructive for the biological sample. Both emulsion- and plastic-based autoradiography record alpha tracks and thus enabled the differentiation between ionized forms of actinides and oxide particles. This feature can help in the evaluation of decorporation therapy efficacy. The most recent technique, the iQID camera, presents several additional features: real-time imaging, separate imaging of

  3. Lanthanides and actinides extraction by calixarenes containing CMPO groups; Extraction des lanthanides et des actinides au moyen de calixarenes portant des groupements CMPO

    Energy Technology Data Exchange (ETDEWEB)

    Garcia Carrera, A


    In the framework of the French program SPIN concerning the radioactive waste management, researches are performed to develop processes allowing the separation of long-lived radioisotopes in order to their transmutation or their specific conditioning. These studies deal with the extraction and the separation of trivalent lanthanides and actinides in acid solution. Many systems ''calixarene-diluent-aqueous phase'' are examined by extraction liquid-liquid and membrane transport. The extraction efficiency and the selectivity of the synthesized calixarene-CMPO and of the CMPO are compared with these cations, as the nitric acid extraction by these molecules. (A.L.B.)

  4. Evaluating measurements of carbon dioxide emissions using a precision source--A natural gas burner. (United States)

    Bryant, Rodney; Bundy, Matthew; Zong, Ruowen


    A natural gas burner has been used as a precise and accurate source for generating large quantities of carbon dioxide (CO2) to evaluate emissions measurements at near-industrial scale. Two methods for determining carbon dioxide emissions from stationary sources are considered here: predicting emissions based on fuel consumption measurements-predicted emissions measurements, and direct measurement of emissions quantities in the flue gas-direct emissions measurements. Uncertainty for the predicted emissions measurement was estimated at less than 1%. Uncertainty estimates for the direct emissions measurement of carbon dioxide were on the order of ±4%. The relative difference between the direct emissions measurements and the predicted emissions measurements was within the range of the measurement uncertainty, therefore demonstrating good agreement. The study demonstrates how independent methods are used to validate source emissions measurements, while also demonstrating how a fire research facility can be used as a precision test-bed to evaluate and improve carbon dioxide emissions measurements from stationary sources. Fossil-fuel-consuming stationary sources such as electric power plants and industrial facilities account for more than half of the CO2 emissions in the United States. Therefore, accurate emissions measurements from these sources are critical for evaluating efforts to reduce greenhouse gas emissions. This study demonstrates how a surrogate for a stationary source, a fire research facility, can be used to evaluate the accuracy of measurements of CO2 emissions.

  5. Oxy-Combustion Burner and Integrated Pollutant Removal Research and Development Test Facility

    Energy Technology Data Exchange (ETDEWEB)

    Mark Schoenfield; Manny Menendez; Thomas Ochs; Rigel Woodside; Danylo Oryshchyn


    A high flame temperature oxy-combustion test facility consisting of a 5 MWe equivalent test boiler facility and 20 KWe equivalent IPR® was constructed at the Hammond, Indiana manufacturing site. The test facility was operated natural gas and coal fuels and parametric studies were performed to determine the optimal performance conditions and generated the necessary technical data required to demonstrate the technologies are viable for technical and economic scale-up. Flame temperatures between 4930-6120F were achieved with high flame temperature oxy-natural gas combustion depending on whether additional recirculated flue gases are added to balance the heat transfer. For high flame temperature oxy-coal combustion, flame temperatures in excess of 4500F were achieved and demonstrated to be consistent with computational fluid dynamic modeling of the burner system. The project demonstrated feasibility and effectiveness of the Jupiter Oxygen high flame temperature oxy-combustion process with Integrated Pollutant Removal process for CCS and CCUS. With these technologies total parasitic power requirements for both oxygen production and carbon capture currently are in the range of 20% of the gross power output. The Jupiter Oxygen high flame temperature oxy-combustion process has been demonstrated at a Technology Readiness Level of 6 and is ready for commencement of a demonstration project.

  6. Time evolution of propagating nonpremixed flames in a counterflow, annular slot burner under AC electric fields

    KAUST Repository

    Tran, Vu Manh


    The mechanism behind improved flame propagation speeds under electric fields is not yet fully understood. Although evidence supports that ion movements cause ionic wind, how this wind affects flame propagation has not been addressed. Here, we apply alternating current electric fields to a gap between the upper and lower parts of a counterflow, annular slot burner and present the characteristics of the propagating nonpremixed edge-flames produced. Contrary to many other previous studies, flame displacement speed decreased with applied AC voltage, and, depending on the applied AC frequency, the trailing flame body took on an oscillatory wavy motion. When flame displacement speeds were corrected using measured unburned flow velocities, we found no significant difference in flame propagation speeds, indicating no thermal or chemical effects by electric fields on the burning velocity. Thus, we conclude that the generation of bidirectional ionic wind is responsible for the impact of electric fields on flames and that an interaction between this bidirectional ionic wind and the flame parameters creates visible and/or measurable phenomenological effects. We also explain that the presence of trailing flame bodies is a dynamic response to an electric body force on a reaction zone, an area that can be considered to have a net positively charged volume. In addition, we characterize the wavy motion of the transient flame as a relaxation time independent of mixture strength, strain rate, and Lewis number.

  7. Curved wall-jet burner for synthesizing titania and silica nanoparticles

    KAUST Repository

    Ismail, Mohamed


    A novel curved wall-jet (CWJ) burner was designed for flame synthesis, by injecting precursors through a center tube and by supplying fuel/air mixtures as an annular-inward jet for rapid mixing of the precursors in the reaction zone. Titanium dioxide (TiO2) and silicon dioxide (SiO2) nanoparticles were produced in ethylene (C2H4)/air premixed flames using titanium tetraisopropoxide (TTIP) and hexamethyldisiloxane (HMDSO) as the precursors, respectively. Particle image velocimetry measurements confirmed that the precursors can be injected into the flames without appreciably affecting flow structure. The nanoparticles were characterized using X-ray diffraction, Raman spectroscopy, the Brunauer-Emmett-Teller (BET) method, and high-resolution transmission electron microscopy. In the case of TiO2, the phase of nanoparticles could be controlled by adjusting the equivalence ratio, while the particle size was dependent on the precursor loading rate and the flame temperature. The synthesized TiO2 nanoparticles exhibited high crystallinity and the anatase phase was dominant at high equivalence ratios (φ > 1.3). In the case of SiO2, the particle size could be controlled from 11 to 18 nm by adjusting the precursor loading rate. © 2014 The Combustion Institute. Published by Elsevier Inc. All rights reserved.

  8. Research on Performance of H2 Rich Blowout Limit in Bluff-Body Burner

    Directory of Open Access Journals (Sweden)

    Hongtao Zheng


    Full Text Available In order to investigate H2 rich blowout limit at different blockage ratios and flow velocities, a CFD software FLUENT was used to simulate H2 burning flow field in bluff-body burner, and the software CHEMKIN was adopted to analyze the sensitivity of each elementary reaction. Composition Probability Density Function (C-PDF model was adopted to simulate H2 combustion field in turbulence flame. The numerical results show that reactions R2 and R9 possess the largest positive and negative temperature sensitivity. Temperature has a very important influence on these two reactions. When equivalence ratio is 1, the mixture is most ignitable, and the critical ignition temperature is 1550 K. There should be an optimal blockage ratio which can stabilize the flame best. When the blockage ratio remains unchanged, the relationship between H2 RBL and flow velocity is a logarithmic function. When the flow velocity remains unchanged, the relationship between H2 RBL and blockage ratio is a parabolic function. A complete extinction requires three phases: the temperature sudden decline in the main stream, the energy dissipation from the recirculation zone to the main stream, and the complete extinction of the flame.

  9. Flame emission spectroscopy measurement of a steam blast and air blast burner

    Directory of Open Access Journals (Sweden)

    Jozsa Viktor


    Full Text Available Control and online monitoring of combustion have become critical to meet the increasingly strict pollutant emission standards. For such a purpose, optical sensing methods, like flame emission spectrometry, seem to be the most feasible technique. Spectrometry is capable to provide information about the local equivalence ratio inside the flame through the chemiluminescence intensity ratio measurement of various radicals. In the present study, a 15 kW atmospheric burner was analyzed utilizing standard diesel fuel. Its plain jet type atomizer was operated with both air and steam atomizing mediums. Up to now, injection of steam into the reaction zone has attracted less scientific attention contrary to its practical importance. Spatial plots of OH*, CH*, and C2* excited radicals were analyzed at 0.35, 0.7, and 1 bar atomization gauge pressures, utilizing both atomizing mediums. The C2* was found to decrease strongly with increasing steam addition. The OH*/CH* and OH*/C2* chemiluminescence intensity ratios along the axis showed a divergent behavior in all the analyzed cases. Nevertheless, CH*/C2* chemiluminescence intensity ratio decreased only slightly, showing low sensitivity to the position of the spectrometer. The findings may be directly applied in steady operating combustion systems, i. e., gas turbines, boilers, and furnaces.

  10. Large Eddy Simulations of the Vortex-Flame Interaction in a Turbulent Swirl Burner (United States)

    Lu, Zhen; Elbaz, Ayman M.; Hernandez Perez, Francisco E.; Roberts, William L.; Im, Hong G.


    A series of swirl-stabilized partially premixed flames are simulated using large eddy simulation (LES) along with the flamelet/progress variable (FPV) model for combustion. The target burner has separate and concentric methane and air streams, with methane in the center and the air flow swirled through the tangential inlets. The flame is lifted in a straight quarl, leading to a partially premixed state. By fixing the swirl number and air flow rate, the fuel jet velocity is reduced to study flame stability as the flame approaches the lean blow-off limit. Simulation results are compared against measured data, yielding a generally good agreement on the velocity, temperature, and species mass fraction distributions. The proper orthogonal decomposition (POD) method is applied on the velocity and progress variable fields to analyze the dominant unsteady flow structure, indicating a coupling between the precessing vortex core (PVC) and the flame. The effects of vortex-flame interactions on the stabilization of the lifted swirling flame are also investigated. For the stabilization of the lifted swirling flame, the effects of convection, enhanced mixing, and flame stretching introduced by the PVC are assessed based on the numerical results. This research work was sponsored by King Abdullah University of Science and Technology (KAUST) and used computational resources at KAUST Supercomputing Laboratory.

  11. Large Eddy Simulation Analysis on Confined Swirling Flows in a Gas Turbine Swirl Burner

    Directory of Open Access Journals (Sweden)

    Tao Liu


    Full Text Available This paper describes a Large Eddy Simulation (LES investigation into flow fields in a model gas turbine combustor equipped with a swirl burner. A probability density function was used to describe the interaction physics of chemical reaction and turbulent flow as liquid fuel was directly injected into the combustion chamber and rapidly mixed with the swirling air. Simulation results showed that heat release during combustion accelerated the axial velocity motion and made the recirculation zone more compact. As the combustion was taking place under lean burn conditions, NO emissions was less than 10 ppm. Finally, the effects of outlet contraction on swirling flows and combustion instability were investigated. Results suggest that contracted outlet can enhance the generation of a Central Vortex Core (CVC flow structure. As peak RMS of velocity fluctuation profiles at center-line suggested the turbulent instability can be enhanced by CVC motion, the Power Spectrum Density (PSD amplitude also explained that the oscillation at CVC position was greater than other places. Both evidences demonstrated that outlet contraction can increase the instability of the central field.

  12. Evaluation of the Battelle Agglomerating Ash Burner High Btu Coal Gasification Process

    Energy Technology Data Exchange (ETDEWEB)

    Malow, M.; West, A.S.


    The economics of the Battelle Agglomerating Ash Burner Process for the production of high Btu gas (SNG) from coal has been evaluated. A conceptual process design including process flowsheets, heat and material balances and equipment specifications has been prepared. Capital costs, operating costs and gas costs have been developed using the CFBraun ''Gas Cost Guidelines''. The estimated capital and gas costs for the Battelle process have been compared to the alternative high Btu processes described in CFBraun's ''Factored Estimates for Western Coal Commercial Concepts'' and were found to be economically unattractive. Some of the reasons for the higher capital cost and gas costs for the Battelle process are: Low Gasifier and Combustor Operating Pressure, Low Methane Make and Concentration in the Gasifier Effluent, Large Volume of Combustion Gases Produced and SO/sub 2/ Content, Use of Dual CO/sub 2/ Removal Units, and the Methanation Scheme. The Battelle process shows thermal efficiencies significantly lower than the most efficient processes, i.e., HYGAS, CO/sub 2/ Acceptor and BI-GAS.

  13. Standard test method for sulfur in liquefied petroleum gases (oxyhydrogen burner or lamp)

    Energy Technology Data Exchange (ETDEWEB)


    This method covers the determination of total sulfur in LP-gases containing more than 1 ppM. Samples should not contain more than 100 ppM of halogens. The sample is burned in an oxy-hydrogen burner, or in a lamp in a closed system in a carbon dioxide-oxygen atmosphere. The latter is not recommended for trace quantities of sulfur due to the inordinately long combustion times needed. The oxides of sulfur are absorbed and oxidized to sulfuric acid in a hydrogen peroxide solution. The sulfate ions are then determined by either of the following finishes: barium perchlorate titration - the sulfate is titrated with barium perchlorate using a thorin-methylene blue mixed indicator; turbidimetric - the sulfate is precipitated as barium sulfate and the turbidity of a suspension of the precipitate is measured with a photometer. It is important to have the sulfur content of liquefied petroleum gases at low enough concentration to meet government regulations. The presence of sulfur may result in corrosion of metal surfaces. Sulfur may be poisonous to catalysts in subsequent processing.

  14. Research on the numerical simulation of secondary air diffusion angle to the swirl burners combustion process (United States)

    Yu, Lei; Chang, Zhen; Liu, He; Yang, Guotian; Li, Xinli


    In this paper, the combustion process of swirl burners during 660 MW unit power plant is simulated. The influence of secondary air diffusion angle on the furnace temperature and furnace slagging is studied. In detail the temperature field and the carbon concentration field and velocity field inside the furnace are analysed when the secondary air diffusion angle is set as 30 °, 45 ° and 60 ° respectively. The simulation results show that when the secondary air diffusion angle is set as 30°, the center temperature of the furnace is highest, and at this time the pulverized coal combustion is sufficient, the carbon concentration near the water wall is the lowest, moreover, it is not easy to slag in the furnace. With the increase of secondary air diffusion angle, the center temperature of boiler burning zone gradually decline, carbon concentration near the water wall increase, it is the more prone to coking inside the furnace. The numerical simulation results not only provide a reference basis for the boiler operation, but also provide an important reference value for exquisite combustion research of the boiler.

  15. Blow-off characteristics of turbulent premixed flames in curved-wall Jet Burner

    KAUST Repository

    Mansour, Morkous S.


    This study concerns the flame dynamics of a curved-wall jet (CWJ) stabilized turbulent premixed flame as it approaches blow-off conditions. Time resolved OH planar laser-induced fluorescence (PLIF) delineated reaction zone contours and simultaneously stereoscopic particle image velocimetry (SPIV) quantified the turbulent flow field features. Ethylene/air flames were stabilized in CWJ burner to determine the sequence of events leading to blowoff. For stably burning flames far from blowoff, flames are characterized with a recirculation zone (RZ) upstream for flame stabilization followed by an intense turbulent interaction jet (IJ) and merged-jet regions downstream; the flame front counterparts the shear layer vortices. Near blowoff, as the velocity of reactants increases, high local stretch rates exceed the extinction stretch rates instantaneously resulting in localized flame extinction along the IJ region. As Reynolds number (Re) increases, flames become shorter and are entrained by larger amounts of cold reactants. The increased strain rates together with heat loss effects result in further fragmentation of the flame, eventually leading to the complete quenching of the flame. This is explained in terms of local turbulent Karlovitz stretch factor (K) and principal flow strain rates associated with C contours. Hydrogen addition and increasing the RZ size lessen the tendency of flames to be locally extinguished.

  16. A high turndown, ultra low emission low swirl burner for natural gas, on-demand water heaters

    Energy Technology Data Exchange (ETDEWEB)

    Rapp, Vi H. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Cheng, Robert K. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Therkelsen, Peter L. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)


    Previous research has shown that on-demand water heaters are, on average, approximately 37% more efficient than storage water heaters. However, approximately 98% of water heaters in the U.S. use storage water heaters while the remaining 2% are on-demand. A major market barrier to deployment of on-demand water heaters is their high retail cost, which is due in part to their reliance on multi-stage burner banks that require complex electronic controls. This project aims to research and develop a cost-effective, efficient, ultra-low emission burner for next generation natural gas on-demand water heaters in residential and commercial buildings. To meet these requirements, researchers at the Lawrence Berkeley National Laboratory (LBNL) are adapting and testing the low-swirl burner (LSB) technology for commercially available on-demand water heaters. In this report, a low-swirl burner is researched, developed, and evaluated to meet targeted on-demand water heater performance metrics. Performance metrics for a new LSB design are identified by characterizing performance of current on-demand water heaters using published literature and technical specifications, and through experimental evaluations that measure fuel consumption and emissions output over a range of operating conditions. Next, target metrics and design criteria for the LSB are used to create six 3D printed prototypes for preliminary investigations. Prototype designs that proved the most promising were fabricated out of metal and tested further to evaluate the LSB’s full performance potential. After conducting a full performance evaluation on two designs, we found that one LSB design is capable of meeting or exceeding almost all the target performance metrics for on-demand water heaters. Specifically, this LSB demonstrated flame stability when operating from 4.07 kBTU/hr up to 204 kBTU/hr (50:1 turndown), compliance with SCAQMD Rule 1146.2 (14 ng/J or 20 ppm NOX @ 3% O2), and lower CO emissions than state

  17. Pollutant Concentrations and Emission Rates from Scripted Natural Gas Cooking Burner Use in Nine Northern California Homes

    Energy Technology Data Exchange (ETDEWEB)

    Singer, Brett C.; Delp, William W.; Lorenzetti, David M.; Maddalena, Randy L.


    METHODS: Combustion pollutant concentrations were measured during the scripted operation of natural gas cooking burners in nine homes. In addition to a base condition of closed windows, no forced air unit (FAU) use, and no mechanical exhaust, additional experiments were conducted while operating an FAU and/or vented range hood. Test homes included a 26m2 two-room apartment, a 134m2 first floor flat, and seven detached homes of 117–226m2. There were four single-story, four two-story and one 1.5 story homes. Cooktop use entailed boiling and simmering activities, using water as a heat sink. Oven and broiler use also were simulated. Time-resolved concentrations of carbon dioxide (CO2), nitric oxide (NO), nitrogen oxides (NOX), nitrogen dioxide (NO2), particles with diameters of 6 nm or larger (PN), carbon monoxide (CO), and fine particulate matter (PM2.5) were measured in the kitchen (K) and bedroom area (BR) of each home. CO2, NO, NO2, and PN data from sequential experiments were analyzed to quantify the contribution of burner use to the highest 1h and 4h time-integrated concentrations in each room. RESULTS: Four of the nine homes had kitchen 1h NO2 exceed the national ambient air quality standard (100 ppb). Two other homes had 1h NO2 exceed 50 ppb in the kitchen, and three had 1h NO2 above 50 ppb in the bedroom, suggesting substantial exposures to anyone at home when burners are used for a single substantial event. In all homes, the highest 1h kitchen PN exceeded 2 x105 cm-3-h, and the highest 4h PN exceeded 3 x105 cm-3-hr in all homes. The lowest 1h kitchen/bedroom ratios were 1.3–2.1 for NO in the apartment and two open floor plan homes. The largest K/BR ratios of 1h NO2 were in a two-story 1990s home retrofitted for deep energy savings: ratios in this home were 3.3 to 6.6. Kitchen 1h ratios of NO, NO2 and PN to CO2 were used to calculate fuel normalized emission factors (ng J-1). Range hood use substantially reduced cooking burner pollutant concentrations both

  18. Validity of the Worth 4 Dot Test in Patients with Red-Green Color Vision Defect. (United States)

    Bak, Eunoo; Yang, Hee Kyung; Hwang, Jeong-Min


    The Worth four dot test uses red and green glasses for binocular dissociation, and although it has been believed that patients with red-green color vision defects cannot accurately perform the Worth four dot test, this has not been validated. Therefore, the purpose of this study was to demonstrate the validity of the Worth four dot test in patients with congenital red-green color vision defects who have normal or abnormal binocular vision. A retrospective review of medical records was performed on 30 consecutive congenital red-green color vision defect patients who underwent the Worth four dot test. The type of color vision anomaly was determined by the Hardy Rand and Rittler (HRR) pseudoisochromatic plate test, Ishihara color test, anomaloscope, and/or the 100 hue test. All patients underwent a complete ophthalmologic examination. Binocular sensory status was evaluated with the Worth four dot test and Randot stereotest. The results were interpreted according to the presence of strabismus or amblyopia. Among the 30 patients, 24 had normal visual acuity without strabismus nor amblyopia and 6 patients had strabismus and/or amblyopia. The 24 patients without strabismus nor amblyopia all showed binocular fusional responses by seeing four dots of the Worth four dot test. Meanwhile, the six patients with strabismus or amblyopia showed various results of fusion, suppression, and diplopia. Congenital red-green color vision defect patients of different types and variable degree of binocularity could successfully perform the Worth four dot test. They showed reliable results that were in accordance with their estimated binocular sensory status.

  19. Research in nuclear chemistry. Progress report, March 1, 1976--February 28, 1977. [Actinide and lanthanide complexes with organic and inorganic ligands

    Energy Technology Data Exchange (ETDEWEB)

    Choppin, Gregory R.


    The study of the binding of actinide ions by the humic and fulvic acid fractions of humus soil has been initiated. Comparison of the thermodynamics of binding of actinides by these soil fractions with the analogous data for a variety of monomer ligands of the type expected to be present in humic acid may enable us to derive a useful model for actinide sorption by humus soils. Inasmuch as humus constitutes a large fraction of the soils of the world, development of a model for its binding of actinide ions could be most helpful in understanding the environmental chemistry of the actinide elements. Our investigation of the binding of the actinide ions by these soil fractions has been coupled with a study of the protonation thermodynamics of humic acid in order to provide a more full characterization of these materials.

  20. Blending of hydrogen in natural gas distribution systems. Volume II. Combustion tests of blends in burners and appliances. Final report, June 1, 1976--August 30, 1977. [8, 11, 14, 20, 22, 25, and 31% hydrogen

    Energy Technology Data Exchange (ETDEWEB)



    The emerging ''hydrogen economy'' is a strong contender as one method to supplement or extend the domestic natural gas supply. This volume of the subject study ''Blending Hydrogen in Natural Gas Distribution Systems'' describes combustion studies to determine the maximum amount of hydrogen that can be blended in natural gas and utilized satisfactorily in typical appliances with no adjustment or conversion. Eleven pilot burners and twenty-three main burners typical of those in current use were operated on hydrogen-natural gas mixtures containing approximately 8, 11, 14, 20, 22, 25, and 31 percent, by volume, hydrogen. The eleven pilot burners and thirteen main burners were tested outside the appliance they were a part of. Ten main burners were tested in their respective appliances. Performance of the various burners tested are as follows: (1) Gas blends containing more than 6 to 11% hydrogen are the limiting mixtures for target type pilot burners. (2) Gas blends containing more than 20 to 22% hyrogen are the limiting mixtures for main burners operating in the open. (3) Gas blends containing more than 22 to 25% hydrogen are the limiting mixtures for main burners tested in appliances. (4) Modification of the orifice in target pilots or increasing the supply pressure to a minimum of 7 inches water column will permit the use of gas blends with 20% hydrogen.

  1. Spent nuclear fuel corrosion: The application of ICP-MS to direct actinide analysis

    Energy Technology Data Exchange (ETDEWEB)

    Forsyth, R. [Caledon-Consult AB, Nykoeping (Sweden); Eklund, U.B. [Studsvik Nuclear AB, Nykoeping (Sweden)


    The ICP-MS technique has been applied to the analysis of the actinide contents of corrodant solutions from experiments performed to study the corrosion of spent nuclear fuel in simulated groundwaters. Analysis was performed directly on the solutions, without employing separation or isotope dilution techniques. The results from two analytical campaigns using natural indium and thorium internal standards are compared. Under both oxic and anoxic conditions, the U contents can be determined with good accuracy and precision. The same applies to Np and Pu under oxic conditions, where the solution concentrations range down to about 0.1 ppb. Under anoxic conditions, where solution concentrations are lower by one or two orders of magnitude, reasonable results for these two actinides can be obtained, but with much lower precision. Direct analysis of Am and Cm, however, gave unsatisfactory results, since the technique is limited by poor measurement statistics and background uncertainty.

  2. Oxyhydroxy Silicate Colloids: A New Type of Waterborne Actinide(IV) Colloids (United States)

    Weiss, Stephan; Hennig, Christoph; Brendler, Vinzenz; Ikeda‐Ohno, Atsushi


    Abstract At the near‐neutral and reducing aquatic conditions expected in undisturbed ore deposits or in closed nuclear waste repositories, the actinides Th, U, Np, and Pu are primarily tetravalent. These tetravalent actinides (AnIV) are sparingly soluble in aquatic systems and, hence, are often assumed to be immobile. However, AnIV could become mobile if they occur as colloids. This review focuses on a new type of AnIV colloids, oxyhydroxy silicate colloids. We herein discuss the chemical characteristics of these colloids and the potential implication for their environmental behavior. The binary oxyhydroxy silicate colloids of AnIV could be potentially more mobile as a waterborne species than the well‐known mono‐component oxyhydroxide colloids. PMID:27957406

  3. Actinides sorption onto hematite. Experimental data, surface complexation modeling and linear free energy relationship

    Energy Technology Data Exchange (ETDEWEB)

    Romanchuk, Anna Y.; Kalmykov, Stephan N. [Lomonosov Moscow State Univ., Moscow (Russian Federation). Dept. of Chemistry


    The sorption of actinides in different valence states - Am(III), Th(IV), Np(V) and U(VI) onto hematite have been revisited with the special emphasis on the equilibrium constants of formation of surface species. The experimental sorption data have been treated using surface complexation modeling from which the set of new values of equilibrium constants were obtained. Formation of inner sphere monodentate surface species adequately describes the pH-sorption edges for actinide ions indicative the ionic electrostatic nature of bonding with small or no covalency contribution. The linear free energy relationship representing the correlation between the hydrolysis constants and surface complexation constants has been developed for various cations including K(I), Li(I), Na(I), Ag(I), Tl(I), Sr(II), Cu(II), Co(II), La(III), Eu(III), Ga(III), Am(III), Th(IV), Np(V), U(VI). (orig.)

  4. Selective Media for Actinide Collection and Pre-Concentration: Results of FY 2006 Studies

    Energy Technology Data Exchange (ETDEWEB)

    Lumetta, Gregg J.; Addleman, Raymond S.; Hay, Benjamin P.; Hubler, Timothy L.; Levitskaia, Tatiana G.; Sinkov, Sergey I.; Snow, Lanee A.; Warner, Marvin G.; Latesky, Stanley L.


    In this work, we have investigated new materials for potential use in automated radiochemical separations. The work can be divided into three primary tasks: (1) synthesis of new ligands with high affinity for actinide ions, (2) evaluation of new materials for actinide ion affinity, and (3) computational design of advanced ligand architectures for highly selective binding of actinide ions. Ligand Synthesis Work was conducted on synthesizing Kl?ui ligand derivatives containing functionalized pendant groups on the cyclopentadienyl ring. The functionalized pendent groups would allow these ligands to be attached to organic and inorganic solid supports. This work focused on synthesizing the compound Na[Cp?Co(PO(OC2H5)2)3], where Cp?= C5H4C(O)OCH3. Synthesizing this compound is feasible, but the method used in FY 2006 produced an impure material. A modified synthetic scheme has been developed and will be pursued in FY 2007. Work was also initiated on synthesizing bicyclic diamides functionalized for binding to polymeric resins or other surfaces. Researchers at the University of Oregon are collaborators in this work. To date, this effort has focused on synthesizing and characterizing a symmetrically substituted bicyclic diamide ligand with the ?COOH functionality. Again, this synthetic effort will continue into FY 2007. Separations Material Evaluation Work was conducted in FY 2006 to provide a more extensive set of data on the selectivity and affinity of extraction chromatography resins prepared by sorption of Kl?ui ligand onto an inert macroreticular polymeric support. Consistent with previous observations, it was found that these materials strongly bind tetravalent actinides. These materials also adsorb trivalent actinides at low nitric acid concentrations, but the affinity for the trivalent actinides decreases with increasing nitric acid concentration. These materials have relatively low affinity for U(VI), but they do sorb U(VI) to a greater extent than Am(III) at [HNO

  5. Evaluation and testing of sequestering agents for the removal of actinides from waste streams

    Energy Technology Data Exchange (ETDEWEB)

    Hoffman, D.C.; Romanovski, V.V.; Veeck, A.C. [Lawrence Livermore National Lab., CA (United States)] [and others


    The purpose of this project is to evaluate and test the complexing ability of a variety of promising new complexing agents synthesized by Professor Kenneth Raymond`s group at the University of California, Berkeley (ESP-CP TTP Number SF16C311). Some of these derivatives have already shown the potential for selectivity binding Pu(IV) in a wide range of solutions in the presence of other metals. Professor Raymond`s group uses molecular modeling to design and synthesize ligands based on modification of natural siderophores, or their analogs, for chelation of actinides. The ligands are then modified for use as liquid/liquid and solid/liquid extractants. The authors` group at the Glenn T. Seaborg Institute for Transactinium Science (ITS) at Lawrence Livermore National Laboratory determines the complex formation constants between the ligands and actinide ions, the capacity and time dependence for uptake on the resins, and the effect of other metal ions and pH.

  6. Advancing Chemistry with the Lanthanide and Actinide Elements: Final Report, September 2013

    Energy Technology Data Exchange (ETDEWEB)

    Evans, William John [Univ. of California, Irvine, CA (United States). Dept. of Chemistry


    The objective of this research is to use the unique chemistry available from complexes of the lanthanides and actinides, as well as related heavy metals such as scandium, yttrium, and bismuth to advance chemistry in energy-related areas. The lanthanides and actinides have a combination of properties in terms of size, charge, electropositive character, and f valence orbitals that provides special opportunities to probe reactivity and catalysis in ways not possible with the other metals in the periodic table. We seek to discover reaction pathways and structural types that reveal new options in reaction chemistry related to energy. Identification of new paradigms in structure and reactivity should stimulate efforts to develop new types of catalytic processes that at present are not under consideration because either the transformation or the necessary intermediates are unknown.

  7. Standard practice for mounting actinides for alpha spectrometry using neodymium fluoride

    CERN Document Server

    American Society for Testing and Materials. Philadelphia


    1.1 This practice covers the preparation of separated fractions of actinides for alpha spectrometry as an alternate to electrodeposition. It is applicable to any of the actinides that can be dissolved in dilute hydrochloric acid. Examples of applicable samples would be the final elution from an ion exchange separation or the final strip from a solvent extraction separation. 1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. 1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For a specific hazard statement, see Section 9.

  8. Final Technical Progress Report Long term risk from actinides in the environment: Modes of mobility

    Energy Technology Data Exchange (ETDEWEB)

    Thomas B. Kirchner


    The key source of uncertainty in assessing actinide mobility is the relative importance of transport by: (1) wind erosion, (2) water erosion, and (3) vertical migration. Each of these three processes depends on several environmental factors and they compete with one another. A scientific assessment of the long-term risks associated with actinides in surface soils depends on better quantifying each of these three modes of mobility. The objective from our EMSP study was to quantify the mobility of soil actinides by wind erosion, water erosion, and vertical migration at three semiarid sites where actinide mobility is a key technical, social and legal issue. This EMSP project was the first to evaluate all three factors at a site. The approach has been to investigate both short- and long-term issues based on field and lab studies and model comparisons. Our results demonstrate the importance of incorporating threshold responses into a modeling framework that accounts for environmental factors and natural disturbances that trigger large changes in actinide mobility. The study measured erosional losses of sediment and fallout cesium (an actinide analogue) from field plots located near WIPP in 1998. The results highlight the large effect of burning as a disturbance on contaminant transport and mobility via runoff and erosion. The results show that runoff, erosion, and actinide transport are (1) strongly site specific-differences in radionuclide transport between WIPP and Rocky Flats differed by a factor of twelve because of soil and vegetation differences, and (2) are strongly impacted by disturbances such as fire, which can increase runoff, erosion, and actinide transport by more than an order of magnitude. In addition, a laboratory experiment using soil columns was conducted to investigate the vertical transport of contaminants in sandy soils. Nine columns of soil collected from the vicinity of the WIPP site were prepared. The column consisted of a piece of PVC pipe 20 cm

  9. Evaluation of extractants and chelating resins in polishing actinide-contaminated waste streams

    Energy Technology Data Exchange (ETDEWEB)

    Schreiber, S.B.; Dunn, S.L.; Yarbro, S.L.


    At the Los Alamos National Laboratory Plutonium Facility, anion exchange is used for recovering plutonium from nitric acid solutions. Although this approach recovers >99%, the trace amounts of plutonium and other actinides remaining in the effluent require additional processing. We are doing research to develop a secondary unit operation that can directly polish the effluent so that actinide levels are reduced to below the maximum allowed for facility discharge. We selected solvent extraction, the only unit operation that can meet the stringent process requirements imposed; several carbonyl and phosphoryl extractants were evaluated and their performance characterized. We also investigated various engineering approaches for solvent extraction; the most promising was a chelating resin loaded with extractant. Our research now focuses on the synthesis of malonamides, and our goal is to bond these extractants to a resin matrix. 7 refs., 12 figs., 1 tab.

  10. MEDOR, a didactic tool to support interpretation of bioassay data after internal contamination by actinides

    Energy Technology Data Exchange (ETDEWEB)

    Miele, A.; Blanchin, N. [Service medical du travail, CEA Cadarache, 13108 Saint Paul lez Durance (France); Raynaud, P. [Service de sante au travail, COGEMA Marcoule, 30207 Bagnols sur Ceze (France); Quesne, B. [COGEMA-AREVA, BP 4, 78141 Velizy (France); Giraud, J.M.; Piechowski, J. [CEA, 31 rue de la Federation, 75752 Paris Cedex 15 (France); Fottorino, R. [Laboratoire d' analyses de biologie medicale, CEA Cadarache, 13108 Saint Paul lez Durance (France); Berard, P. [Laboratoire d' Analyses BioMedicales, DSM, CEA Saclay, 91191 Gif sur Yvette (France); Ansoborlo, E. [CETAMA DRCP/DEN/CEAVALRHO Marcoule, BP 17171, 30207 Bagnols sur Ceze (France); Franck, D.; Blanchardon, E.; Challeton-de Vathaire, C. [Laboratoire d' evaluation de la dose interne, IRSN, BP 17, 92262 Fontenay-aux-Roses Cedex (France); Lebaron-Jacobs, L. [CARMIN, CEA/DSV, BP 6, 92262 Fontenay-aux-Roses Cedex (France); Poncy, J.L.; Fritsch, P. [Laboratoire de Radiotoxicologie, SRCA/DRR/DSV/CEA, BP 12, 91680 Bruyeres le Chatel (France)


    A didactic software, Methodes Dosimetriques de Reference (MEDOR), is being developed to provide help in the interpretation of biological data. Its main purpose is to evaluate the pertinence of the application of different models. This paper describes its first version that is focused on inhalation exposure to actinide aerosols. With this tool, sensitivity analysis on different parameters of the ICRP models can be easily done for aerosol deposition, in terms of activity and particle number, actinide biokinetics and doses. The user can analyse different inhalation cases showing either that dose per unit intake cannot be applied if the aerosol contains a low number of particles or that an inhibition of the late pulmonary clearance by particle transport can occur which contributes to a 3-4 fold increase in effective dose as compared with application of default parameters. This underlines the need to estimate systematically the number of deposited particles, as well as to do chest monitoring as long as possible. (authors)

  11. Neutron-based measurements for nondestructive assay of minor actinides produced in nuclear power reactors

    Energy Technology Data Exchange (ETDEWEB)

    Stewart, J.E.; Eccleston, G.W.; Ensslin, N.; Cremers, T.L.; Foster, L.A.; Menlove, H.O.; Rinard, P.M.


    Because of their impacts on long-term storage of high-level radioactive waste and their value as nuclear fuels, measurement and accounting of the minor actinides produced in nuclear power reactors are becoming significant issues. This paper briefly reviews the commercial nuclear fuel cycle with emphasis on reprocessing plants and key measurement points therein. Neutron signatures and characteristics are compared and contrasted for special nuclear materials (SNMs) and minor actinides (MAs). The paper focuses on application of neutron-based nondestructive analysis (NDA) methods that can be extended for verification of MAs. We describe current IAEA methods for NDA of SNMs and extension of these methods to satisfy accounting requirements for MAs in reprocessing plant dissolver solutions, separated products, and high-level waste. Recommendations for further systems studies and development of measurement methods are also included.

  12. Nonaxial shapes of even–even lantanide and actinide nuclei in excited collective states

    Energy Technology Data Exchange (ETDEWEB)

    Nadirbekov, M. S., E-mail:; Bozarov, O. A. [Uzbek Academy of Sciences, Institute of Nuclear Physics (Uzbekistan)


    Quadrupole-type excited states of even–even nuclei are studied on the basis of arbitrary-triaxiality model. It is shown that the inclusion of high-order terms in the expansion of the rotational-energy operator in the variable γ improves substantially agreement between our theoretical results and respective experimental data. The proposed model makes it possible to explain the intricate character of the spectrum of excited states of even–even lanthanide and actinide nuclei.

  13. Micromagnetic susceptometer for the measurement of the magnetic susceptibility of the actinides

    Energy Technology Data Exchange (ETDEWEB)

    Nave, Stanley Eugene [Univ. of Tennessee, Knoxville, TN (United States)


    A device with the sensitivity for measuring the magnetic susceptibility of small volume samples (10-7 cm3) as a function of temperature from 4.2K to 300K is described as designed specifically for measurements with microgram or submicrogram quantities of the actinide metals. Specifically, results are given for the susceptibility of curium-248 in the temperature range from 4.2K to 300K.

  14. Ionization potentials of the lanthanides and actinides - towards atomic spectroscopy of super-heavy elements (United States)

    Wendt, K.; Gottwald, T.; Mattolat, C.; Raeder, S.


    A study on the systematic of the atomic ionization potentials for both, the lanthanide and actinide elements have been performed. The existing experimental basis, predominantly relying on results from resonance ionization spectroscopy, has been extended by novel laser spectroscopic investigations on the elements Au, Dy, Pr and Pa. Conclusive results of suitable precision for the ionization potentials could be obtained except for Pa, due to the complexity of its atomic spectrum. Nevertheless, a consistent interpretation of the observed trends for the ionization potentials of lanthanides and actinides was attempted. The series of lanthanides depicts the two well-known, completely smooth, linear trends above and below half-shell closure, from which an expectation value for the missing ionization potential of the all radioactive element promethium of IP Pm= 44985(140) cm -1 was derived. In contrast, the lighter members of the actinide series below the half-filled shell exhibit a significant deviation from predictions, which are ascribed dominantly to relativistic influences affecting the energetic position of the multitude of low-lying configurations. With the assumption of removal of a 6d electron during the ionization process agreement between theory and experiment and a smooth, even though not linear behavior, is obtained also in this region of the Periodic Table. This new interpretation could help to better predict similar trends and systematics for elements heavier than the actinides. Particularly relevant in this respect are the super-heavy elements, which are produced only in minuscule atom numbers and thus were not accessible for any atomic physics study yet.

  15. Directed evolution of the periodic table: probing the electronic structure of late actinides. (United States)

    Marsh, M L; Albrecht-Schmitt, T E


    Recent investigations of the coordination chemistry and physical properties of berkelium (Z = 97) and californium (Z = 98) have revealed fundamental differences between post-curium elements and lighter members of the actinide series. This review highlights these developments and chronicles key findings and concepts from the last half-century that have helped usher in a new understanding of the evolution of electronic structure in the periodic table.

  16. Approaches to the RAW (Actinides, Fission Products) transmutation in fusion blankets

    Energy Technology Data Exchange (ETDEWEB)

    Lopatkin, A.; Tocheniy, L. [ENTEK-RDIPE, Moscow (Russian Federation)


    Within the framework of developing the general concept of large-scale environmentally safe use of nuclear reactor energy RDIPE, executes research of ways to radically decrease the hazard of high-level radioactive wastes (actinides, fission products) to be buried into the Earth. The opportunities are appreciated for replacement and transmutation of RAW fractions and nuclides into nuclear reactor with various spectrum at various irradiation regime, including specialized reactor with utmost parameters and blankets of fusion and linac-driven reactors. The results indicate on expediency of transmutation of actinides in fast reactor in closed fuel cycle. As to fission products, one part of them can be used in radiative technologies (Cs, Sr) or reused in reactor (Zr), other part (Sm, I, Tc) can be transmuted into power-generating reactor, so that together with other after long-time (200-300 years) controllable cooling to be bured into the Earth. In blanket the considerable influence on result of actinide irradiation can are rendered by the fast neutrons (fusion ones in the case of thermonuclear reactor or spalation ones in accelerator driven machine), the threshold reactions of (n,f), (n,2n), (n,3n) and etc. The fusion reactor has wide enough opportunities to form spectrum of neutrons, optimum for reactions (n,f), (n;{gamma}), (n,2n), including threshold ones, as well as the replacement of mass of several tons of RAW are technically possible. However, at fast neutron spectrum light actinide isotopes (U-232, Pu-236) are produced in quantities on 2-3 order up then in the case of fission reactor, but at softer one the probabilities of threshold reactions of even nuclei are reduced. This scheme in general permits to ensure the completion of radiative equivalence of uranium taken from the Earth, and appropriate RAW, directed into the Earth.

  17. Strategic Design and Optimization of Inorganic Sorbents for Cesium, Strontium and Actinides

    Energy Technology Data Exchange (ETDEWEB)

    Maginn, Edward J.


    The basic science goal in this project is to identify structure/affinity relationships for selected radionuclides and existing sorbents. The research will then apply this knowledge to the design and synthesis of sorbents that will exhibit increased cesium, strontium and actinide removal. The target problem focuses on the treatment of high-level nuclear wastes. The general approach can likewise be applied to non-radioactive separations.

  18. Strategic Design and Optimization of Inorganic Sorbents For Cesium, Strontium and Actinides

    Energy Technology Data Exchange (ETDEWEB)

    Hobbs, D.; Nyman, M.; Clearfield, A.; Maginn, E.


    The basic science goal in this project identifies structure/affinity relationships for selected radionuclides and existing sorbents. The task will apply this knowledge to the design and synthesis of new sorbents that will exhibit increased affinity for cesium, strontium and actinide separations. The target problem focuses on the treatment of high-level nuclear wastes. The general approach can likewise be applied to nonradioactive separations.

  19. Descriptive study of the even-even actinide nuclei 230 - 234Th isotopes using IBM-1 (United States)

    Al-Dahan, N.


    The nuclear structure of the actinide even-even thorium isotopes from A=230-234 have been investigated within the framework of the Interacting Boson Model (IBM-1). Predictions are given for the excited state energies for the ground state, β and γ-bands, the transition probabilities between these states, the rotational moment of inertia, and the energy staggering in the γ-band energies. The results of these calculations are compared with the experimental data on these isotopes.

  20. Influence of microorganisms on the oxidation state distribution of multivalent actinides under anoxic conditions

    Energy Technology Data Exchange (ETDEWEB)

    Reed, Donald Timothy [Los Alamos National Laboratory; Borkowski, Marian [Los Alamos National Laboratory; Lucchini, Jean - Francois [Los Alamos National Laboratory; Ams, David [Los Alamos National Laboratory; Richmann, M. K. [Los Alamos National Laboratory; Khaing, H. [Los Alamos National Laboratory; Swanson, J. S. [Los Alamos National Laboratory


    The fate and potential mobility of multivalent actinides in the subsurface is receiving increased attention as the DOE looks to cleanup the many legacy nuclear waste sites and associated subsurface contamination. Plutonium, uranium and neptunium are the near-surface multivalent contaminants of concern and are also key contaminants for the deep geologic disposal of nuclear waste. Their mobility is highly dependent on their redox distribution at their contamination source as well as along their potential migration pathways. This redox distribution is often controlled, especially in the near-surface where organic/inorganic contaminants often coexist, by the direct and indirect effects of microbial activity. Under anoxic conditions, indirect and direct bioreduction mechanisms exist that promote the prevalence of lower-valent species for multivalent actinides. Oxidation-state-specific biosorption is also an important consideration for long-term migration and can influence oxidation state distribution. Results of ongoing studies to explore and establish the oxidation-state specific interactions of soil bacteria (metal reducers and sulfate reducers) as well as halo-tolerant bacteria and Archaea for uranium, neptunium and plutonium will be presented. Enzymatic reduction is a key process in the bioreduction of plutonium and uranium, but co-enzymatic processes predominate in neptunium systems. Strong sorptive interactions can occur for most actinide oxidation states but are likely a factor in the stabilization of lower-valent species when more than one oxidation state can persist under anaerobic microbiologically-active conditions. These results for microbiologically active systems are interpreted in the context of their overall importance in defining the potential migration of multivalent actinides in the subsurface.

  1. Defect engineering in metal-organic frameworks: a new strategy to develop applicable actinide sorbents. (United States)

    Yuan, Liyong; Tian, Ming; Lan, Jianhui; Cao, Xingzhong; Wang, Xiaolin; Chai, Zhifang; Gibson, John K; Shi, Weiqun


    The preliminary results described here show that the adsorbability of uranyl ions by a highly stable MOF UiO-66 can be drastically enhanced by tailoring the missing-linker defects in this MOF. The combination of defect-induced functionality improvement with the acid-resistant nature of UiO-66 substantiates the applicability of this material for actinide capture from acidic media.

  2. Measurement of actinides in environmental samples by Photo-Electron Rejecting Alpha Liquid Scintillation

    Energy Technology Data Exchange (ETDEWEB)

    Cadieux, J.R. [Westinghouse Savannah River Co., Aiken, SC (United States); Clark, S. [Savannah River Ecology Lab., Univ. of Georgia (United States); Fjeld, R.A.; Reboul, S.; Sowder, A. [Clemson Univ., SC (United States). Dept. of Environmental Systems Engineering


    This work describes the adaptation of extractive scintillation with a Photo-Electron Rejecting Alpha Liquid Scintillation (PERALS) (ORDELA, Inc.) spectrometer to the analysis of actinides in environmental samples from the Savannah River Site (SRS). Environmental quality assurance standards and actual water samples were treated by one of two methods; either a two step direct extraction, or for more complex samples, pretreatment by an extraction chromatographic separation prior to measurement of the alpha activity by PERALS.

  3. Benchmark Evaluation of Dounreay Prototype Fast Reactor Minor Actinide Depletion Measurements

    Energy Technology Data Exchange (ETDEWEB)

    Hess, J. D.; Gauld, I. C.; Gulliford, J.; Hill, I.; Okajima, S.


    Historic measurements of actinide samples in the Dounreay Prototype Fast Reactor (PFR) are of interest for modern nuclear data and simulation validation. Samples of various higher-actinide isotopes were irradiated for 492 effective full-power days and radiochemically assayed at Oak Ridge National Laboratory (ORNL) and Japan Atomic Energy Research Institute (JAERI). Limited data were available regarding the PFR irradiation; a six-group neutron spectra was available with some power history data to support a burnup depletion analysis validation study. Under the guidance of the Organisation for Economic Co-Operation and Development Nuclear Energy Agency (OECD NEA), the International Reactor Physics Experiment Evaluation Project (IRPhEP) and Spent Fuel Isotopic Composition (SFCOMPO) Project are collaborating to recover all measurement data pertaining to these measurements, including collaboration with the United Kingdom to obtain pertinent reactor physics design and operational history data. These activities will produce internationally peer-reviewed benchmark data to support validation of minor actinide cross section data and modern neutronic simulation of fast reactors with accompanying fuel cycle activities such as transportation, recycling, storage, and criticality safety.

  4. Lanthanide and actinide chemistry at high C/O ratios in the solar nebula (United States)

    Lodders, Katharina; Fegley, Bruce, Jr.


    Chemical equilibrium calculations were performed to study the condensation chemistry of the REE and actinides under the highly reducing conditions which are necessary for the formation of the enstatite chondrites. Our calculations confirm that the REE and actinides condensed into oldhamite (CaS), the major REE and actinide host phase in enstatite chondrites, at a carbon-oxygen (C/O) ratio not less than 1 in an otherwise solar gas. Five basic types of REE abundance patterns, several of which are analogous to REE abundance patterns observed in the Ca, Al-rich inclusions in carbonaceous chondrites, are predicted to occur in meteoritic oldhamites. All of the reported REE patterns in oldhamites in enstatite chondrites can be interpreted in terms of our condensation calculations. The observed patterns fall into three of the five predicted categories. The reported Th and U enrichments and ratios in meteoritic oldhamites are also consistent with predictions of the condensation calculations. Pure REE sulfides are predicted to condense in the 10 exp -6 to 10 exp -9 bar range and may be found in enstatite chondrites if they formed in this pressure range.

  5. Actinide chemistry research supporting the Waste Isolation Pilot Plant (WIPP): FY94 results

    Energy Technology Data Exchange (ETDEWEB)

    Novak, C.F. [ed.


    This document contains six reports on actinide chemistry research supporting the Waste Isolation Pilot Plant (WIPP). These reports, completed in FY94, are relevant to the estimation of the potential dissolved actinide concentrations in WIPP brines under repository breach scenarios. Estimates of potential dissolved actinide concentrations are necessary for WIPP performance assessment calculations. The specific topics covered within this document are: the complexation of oxalate with Th(IV) and U(VI); the stability of Pu(VI) in one WIPP-specific brine environment both with and without carbonate present; the solubility of Nd(III) in a WIPP Salado brine surrogate as a function of hydrogen ion concentration; the steady-state dissolved plutonium concentrations in a synthetic WIPP Culebra brine surrogate; the development of a model for Nd(III) solubility and speciation in dilute to concentrated sodium carbonate and sodium bicarbonate solutions; and the development of a model for Np(V) solubility and speciation in dilute to concentrated sodium Perchlorate, sodium carbonate, and sodium chloride media.

  6. Electron-phonon coupling of light-actinides. Effect of spin-orbit coupling

    Energy Technology Data Exchange (ETDEWEB)

    Gonzalez-Castelazo, Paola; Pena-Seaman, Omar de la [Benemerita Universidad Autonoma de Puebla (BUAP), Institute of Physics (IFUAP) (Mexico); Heid, Rolf; Bohnen, Klaus-Peter [Karlsruher Institut fuer Technologie (KIT), Institut fuer Festkoerperphysik (IFP) (Germany)


    The physics of actinide metals is quite complex and rich due to the behavior of 5f electrons in the valence region: it goes from itinerant on the early stages of the actinide series to highly localized for the elements with a higher number of 5f electrons involved. In addition, in this systems should be mandatory the inclusion of spin-orbit coupling (SOC). However, only in few cases on electronic and lattice dynamical properties the SOC has been taking into account, while for the electron-phonon (e-ph) coupling such analysis has not been performed so far. Thus, as a first approach we have systematically studied the SOC influence on the full-phonon dispersion and the e-ph coupling for the simplest light-actinide metals: Ac and Th. These elements have been studied within the framework of density functional perturbation theory, using a mixed-basis pseudopotential method. The full-phonon dispersion as well as the Eliashberg spectral function and the electron-phonon coupling parameter have been calculated with and without SOC. The observed effects of SOC in the full-phonon dispersion and Eliashberg function are discussed in detail, together with an analysis of the differences on the electronic properties due to the SOC inclusion in the calculations.

  7. Actinide, lanthanide and fission product speciation and electrochemistry in high and low temperature ionic melts

    Energy Technology Data Exchange (ETDEWEB)

    Bhatt, Anand I.; Kinoshita, Hajime; Koster, Anne L.; May, Iain; Sharrad, Clint A.; Volkovich, Vladimir A.; Fox, O. Danny; Jones, Chris J.; Lewin, Bob G.; Charnock, John M.; Hennig, Christoph


    There is currently a great deal of research interest in the development of molten salt technology, both classical high temperature melts and low temperature ionic liquids, for the electrochemical separation of the actinides from spent nuclear fuel. We are interested in gaining a better understanding of actinide and key fission product speciation and electrochemical properties in a range of melts. Our studies in high temperature alkali metal melts (including LiCl and LiCl-KCl and CsCl-NaCl eutectics) have focussed on in-situ species of U, Th, Tc and Ru using X-ray absorption spectroscopy (XAS, both EXAFS and XANES) and electronic absorption spectroscopy (EAS). We report unusual actinide speciation in high temperature melts and an evaluation of the likelihood of Ru or Tc volatilization during plant operation. Our studies in lower temperature melts (ionic liquids) have focussed on salts containing tertiary alkyl group 15 cations and the bis(tri-fluor-methyl)sulfonyl)imide anion, melts which we have shown to have exceptionally wide electrochemical windows. We report Ln, Th, U and Np speciation (XAS, EAS and vibrational spectroscopy) and electrochemistry in these melts and relate the solution studies to crystallographic characterised benchmark species. (authors)

  8. Development of Radioanalytical and Microanalytical Procedures for the Determination of Actinides in Environmental Samples

    Energy Technology Data Exchange (ETDEWEB)

    Macsik, Zsuzsanna [Institute of Nuclear Techniques, Moegyetem rakpart 9, H-1111 Budapest (Hungary); Vajda, Nora [RadAnal Ltd., Bimbo ut 119/a, H-1026 Budapest (Hungary); Bene, Balazs [National Institute of Standards and Technology, Gaithersburg, MD 20899 (United States); Varga, Zsolt [Institute of Isotopes, Konkoly-Thege M. ut 29-33, H-1121 Budapest (Hungary)


    A radio-analytical procedure has been developed for the simultaneous determination of actinides in swipe samples by alpha-spectrometry after the separation of the actinides by extraction chromatography. The procedure is based on the complete decomposition of the sample by destruction with microwave digestion or ashing in furnace. Actinides are separated on an extraction chromatographic column filled with TRU resin (product of Eichrom Industries Inc.). Alpha sources prepared from the separated fractions of americium, plutonium, thorium and uranium are counted by alpha spectrometry. Micro-analytical procedure is being developed for the location and identification of individual particles containing fissile material using solid state nuclear track detectors. The parameters of alpha and fission track detection have been optimized and a procedure has been elaborated to locate the particles on the sample by defining the coordinates of the tracks created by the particles on the track detector. Development of a procedure is planned to separate the located particles using micromanipulator and these particles will be examined individually by different micro- and radio-analytical techniques. (authors)

  9. Preparation of higher-actinide burnup and cross section samples. [LMFBR

    Energy Technology Data Exchange (ETDEWEB)

    Adair, H.L.; Kobisk, E.H.; Quinby, T.C.; Thomas, D.K.; Dailey, J.M.


    A joint research program involving the United States and the United Kingdom was instigated about four years ago for the purpose of studying burnup of higher actinides using in-core irradiation in the fast reactor at Dounreay, Scotland. Simultaneously, determination of cross sections of a wide variety of higher actinide isotopes was proposed. Coincidental neutron flux and energy spectral measurements were to be made using vanadium encapsulated dosimetry materials in the immediate region of the burnup and cross section samples. The higher actinide samples chosen for the burnup study were /sup 241/Am and /sup 244/Cm in the forms of Am/sub 2/O/sub 3/, Cm/sub 2/O/sub 3/, and Am/sub 6/ Cm(RE)/sub 7/O/sub 21/, where (RE) represents a mixture of lanthanide sesquioxides. It is the purpose of this paper to describe technology development and its application in the preparation of the fuel specimens and the cross section specimens that are being used in this cooperative program.

  10. Conjugates of magnetic nanoparticle-actinide specific chelator for radioactive waste separation. (United States)

    Kaur, Maninder; Zhang, Huijin; Martin, Leigh; Todd, Terry; Qiang, You


    A novel nanotechnology for the separation of radioactive waste that uses magnetic nanoparticles (MNPs) conjugated with actinide specific chelators (MNP-Che) is reviewed with a focus on design and process development. The MNP-Che separation process is an effective way of separating heat generating minor actinides (Np, Am, Cm) from spent nuclear fuel solution to reduce the radiological hazard. It utilizes coated MNPs to selectively adsorb the contaminants onto their surfaces, after which the loaded particles are collected using a magnetic field. The MNP-Che conjugates can be recycled by stripping contaminates into a separate, smaller volume of solution, and then become the final waste form for disposal after reusing number of times. Due to the highly selective chelators, this remediation method could be both simple and versatile while allowing the valuable actinides to be recovered and recycled. Key issues standing in the way of large-scale application are stability of the conjugates and their dispersion in solution to maintain their unique properties, especially large surface area, of MNPs. With substantial research progress made on MNPs and their surface functionalization, as well as development of environmentally benign chelators, this method could become very flexible and cost-effective for recycling used fuel. Finally, the development of this nanotechnology is summarized and its future direction is discussed.

  11. Interaction of selected actinides (U, Cm) with bacteria relevant to nuclear waste disposal

    Energy Technology Data Exchange (ETDEWEB)

    Luetke, Laura


    To assess the safety of a site destined for storage of nuclear waste enhanced research effort is demanded to investigate the complex interactions of released radionuclides with parts of the environment that includes indigenous microorganisms. This work aimed at assessing the interactions of two bacterial strains with the actinides uranium and curium with a focus on thermodynamics to provide stability constants of the actinide bacteria species formed usable for modelling the distribution of these actinides in the environment. The influences of Pseudomonas fluorescens (CCUG 32456A) isolated from the granitic aquifers at Aespoe(Sweden) and a novel isolate from Mont Terri Opalinus clay (Switzerland), Paenibacillus sp. MT-2.2, were investigated. A combined approach using microbiological and spectroscopic techniques as well as potentiometry was employed to characterize the U(VI) and Cm(III) binding onto the cell surface functional groups structurally and thermodynamically. Further, due to its similar ionic radius to Cm(III) also Eu(III) was studied as non-radioactive analog.

  12. Fundamental Thermodynamics of Actinide-Bearing Mineral Waste Forms - Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Williamson, Mark A.; Ebbinghaus, Bartley B.; Navrotsky, Alexandra


    The end of the Cold War raised the need for the technical community to be concerned with the disposition of excess nuclear weapon material. The plutonium will either be converted into mixed-oxide fuel for use in nuclear reactors or immobilized in glass or ceramic waste forms and placed in a repository. The stability and behavior of plutonium in the ceramic materials as well as the phase behavior and stability of the ceramic material in the environment is not well established. In order to provide technically sound solutions to these issues, thermodynamic data are essential in developing an understanding of the chemistry and phase equilibria of the actinide-bearing mineral waste form materials proposed as immobilization matrices. Mineral materials of interest include zircon, zirconolite, and pyrochlore. High temperature solution calorimetry is one of the most powerful techniques, sometimes the only technique, for providing the fundamental thermodynamic data needed to establish optimum material fabrication parameters, and more importantly understand and predict the behavior of the mineral materials in the environment. The purpose of this project is to experimentally determine the enthalpy of formation of actinide orthosilicates, the enthalpies of formation of actinide substituted zirconolite and pyrochlore, and develop an understanding of the bonding characteristics and stabilities of these materials.

  13. An Advanced TALSPEAK Concept for Separating Minor Actinides. Part 1. Process Optimization and Flowsheet Development

    Energy Technology Data Exchange (ETDEWEB)

    Lumetta, Gregg J. [Pacific Northwest National Laboratory, Nuclear Science and Engineering Group, Richland, WA, USA; Levitskaia, Tatiana G. [Pacific Northwest National Laboratory, Nuclear Science and Engineering Group, Richland, WA, USA; Wilden, Andreas [Forschungszentrum Jülich GmbH, Institut für Energie- und Klimaforschung – Nukleare Entsorgung und Reaktorsicherheit (IEK-6), Jülich, Germany; Casella, Amanda J. [Pacific Northwest National Laboratory, Nuclear Science and Engineering Group, Richland, WA, USA; Hall, Gabriel B. [Pacific Northwest National Laboratory, Nuclear Science and Engineering Group, Richland, WA, USA; Lin, Leigh [Pacific Northwest National Laboratory, Nuclear Science and Engineering Group, Richland, WA, USA; Sinkov, Sergey I. [Pacific Northwest National Laboratory, Nuclear Science and Engineering Group, Richland, WA, USA; Law, Jack D. [Idaho National Laboratory, Aqueous Separations and Radiochemistry Department, Idaho Falls, ID, USA; Modolo, Giuseppe [Forschungszentrum Jülich GmbH, Institut für Energie- und Klimaforschung – Nukleare Entsorgung und Reaktorsicherheit (IEK-6), Jülich, Germany


    A system is being developed to separate trivalent actinides from lanthanide fission product elements that uses 2-ethylhexylphosphonic acid mono-2-ethylhexyl ester to extract the lanthanide ions into an organic phase, while the actinide ions are held in the citrate-buffered aqueous phase by complexation to N-(2-hydroxyethyl)ethylenediamine-N,N',N'-triacetic acid (HEDTA). Earlier investigations of this system using a 2-cm centrifugal contactor revealed that the relatively slow extraction of Sm3+, Eu3+, and Gd3+ resulted in low separation factors from Am3+. In the work reported here, adjustments to the aqueous phase chemistry were made to improve the extraction rates. The results suggest that increasing the concentration of the citric acid buffer from 0.2 to 0.6 mol/L, and lowering the pH from 3.1 to 2.6, significantly improved lanthanide extraction rates resulting in an actinide/lanthanide separation system suitable for deployment in centrifugal contactors. Experiments performed to evaluate whether the lanthanide extraction rates can be improved by replacing aqueous HEDTA with nitrilotriacetic acid (NTA) exhibited promising results. However, NTA exhibited an unsatisfactorily high distribution value for Am3+ under the extraction conditions examined.

  14. JOWOG 22/2 - Actinide Chemical Technology (July 9-13, 2012)

    Energy Technology Data Exchange (ETDEWEB)

    Jackson, Jay M. [Los Alamos National Laboratory; Lopez, Jacquelyn C. [Los Alamos National Laboratory; Wayne, David M. [Los Alamos National Laboratory; Schulte, Louis D. [Los Alamos National Laboratory; Finstad, Casey C. [Los Alamos National Laboratory; Stroud, Mary Ann [Los Alamos National Laboratory; Mulford, Roberta Nancy [Los Alamos National Laboratory; MacDonald, John M. [Los Alamos National Laboratory; Turner, Cameron J. [Los Alamos National Laboratory; Lee, Sonya M. [Los Alamos National Laboratory


    The Plutonium Science and Manufacturing Directorate provides world-class, safe, secure, and reliable special nuclear material research, process development, technology demonstration, and manufacturing capabilities that support the nation's defense, energy, and environmental needs. We safely and efficiently process plutonium, uranium, and other actinide materials to meet national program requirements, while expanding the scientific and engineering basis of nuclear weapons-based manufacturing, and while producing the next generation of nuclear engineers and scientists. Actinide Process Chemistry (NCO-2) safely and efficiently processes plutonium and other actinide compounds to meet the nation's nuclear defense program needs. All of our processing activities are done in a world class and highly regulated nuclear facility. NCO-2's plutonium processing activities consist of direct oxide reduction, metal chlorination, americium extraction, and electrorefining. In addition, NCO-2 uses hydrochloric and nitric acid dissolutions for both plutonium processing and reduction of hazardous components in the waste streams. Finally, NCO-2 is a key team member in the processing of plutonium oxide from disassembled pits and the subsequent stabilization of plutonium oxide for safe and stable long-term storage.

  15. Conjugates of Magnetic Nanoparticle -- Actinide Specific Chelator for Radioactive Waste Separation

    Energy Technology Data Exchange (ETDEWEB)

    Maninder Kaur; Huijin Zhang; Leigh Martin; Terry Todd; You Qiang


    A novel nanotechnology for the separation of radioactive waste that uses magnetic nanoparticles (MNPs) conjugated with actinide specific chelators (MNP-Che) is reviewed with a focus on design and process development. The MNP-Che separation process is an effective way of separating heat generating minor actinides (Np, Am, Cm) from spent nuclear fuel solution to reduce the radiological hazard. It utilizes coated MNPs to selectively adsorb the contaminants onto their surfaces, after which the loaded particles are collected using a magnetic field. The MNP-Che conjugates can be recycled by stripping contaminates into a separate, smaller volume of solution, and then become the final waste form for disposal after reusing number of times. Due to the highly selective chelators, this remediation method could be both simple and versatile while allowing the valuable actinides to be recovered and recycled. Key issues standing in the way of large-scale application are stability of the conjugates and their dispersion in solution to maintain their unique properties, especially large surface area, of MNPs. With substantial research progress made on MNPs and their surface functionalization, as well as development of environmentally benign chelators, this method could become very flexible and cost-effective for recycling used fuel. Finally, the development of this nanotechnology is summarized and its future direction is discussed.

  16. Actinides(3)/lanthanides(3) separation by nano-filtration assisted by complexation; Separation actinides(3)lanthanides(3) par nanofiltration assistee par complexation

    Energy Technology Data Exchange (ETDEWEB)

    Sorin, A


    In France, one of the research trend concerning the reprocessing of spent nuclear fuel consists to separate selectively the very radio-toxic elements with a long life to be recycled (Pu) or transmuted (Am, Cm, Np). The aim of this thesis concerns the last theme about actinides(III)/lanthanides(III) separation by a process of nano-filtration assisted by complexation. Thus, a pilot of tangential membrane filtration was designed and established in a glove box at the ATALANTE place of CEA-Marcoule. Physico-chemical characterisation of the Desal GH membrane (OSMONICS), selected to carry out actinides(III)/lanthanides(III) separation, was realized to determine the zeta potential of the active layer and its resistance to ionizing radiations. Moreover, a parametric study was also carried out to optimize the selectivity of complexation, and the operating conditions of complex retention (influences of the transmembrane pressure, solute concentration, tangential velocity and temperature). Finally, the separation of traces of Am(III) contained in a mixture of lanthanides(III), simulating the real load coming from a reprocessing cycle, was evaluated with several chelating agents such as poly-amino-carboxylic acids according to the solution acidity and the [Ligand]/[Cation(III)] ratio. (author)

  17. Partnew - New solvent extraction processes for minor actinides - final report; Partnew - Nouveaux procedes d'extraction par solvant pour les actinides mineurs - rapport final

    Energy Technology Data Exchange (ETDEWEB)

    Madic, C.; Testard, F.; Hudson, M.J.; Liljenzin, J.O.; Christiansen, B.; Ferrando, M.; Facchini, A.; Geist, A.; Modolo, G.; Gonzalez-Espartero, A.; Mendoza, J. de


    The objectives of the European project PARTNEW were to define solvent extraction processes for the partitioning of the minor actinides, Am and Cm, from the aqueous high active raffinate or high active concentrate issuing the reprocessing of nuclear spent fuels by the PUREX process. Eleven laboratories participated to the research: 1/ CEA-DEN (Marcoule), 2/ CEA-DSM (Saclay), 3/ UREAD (U.K.), 4/ CTU (Sweden), 5/ ITU (Germany), 6/ ENEA (Italy), 7/ PoliMi (Italy), 8/ FZK-INE (Germany), 9/ FZJ-ISR (Germany), 10/ CIEMAT (Spain) and 11/ UAM (Spain). The research was organised into eight work packages (WP): Basic and applied DIAMEX studies, using diamide extractants for the co-extraction of actinides(III) (An(III)) and lanthanides(III) (Ln(III)) nitrates (WP1 and WP2), Basic and applied SANEX studies based on the use of polydentate N-ligands for the An(III)/Ln(III) separation (WP3 and WP4), Basic and applied SANEX studies based on the use of synergistic mixtures made of bis-(chloro-phenyl)-di-thio-phosphinic acid + neutral O-bearing ligand, (WP5 and WP6), Basic SANEX studies for the An(III)/Ln(III) separation, based on the use of new S-bearing ligands, Basic and applied studies for the Am(III)/Cm(III) separation. The work done in the fundamental and applied domains was very fruitful. Several processes have been successfully tested with genuine high active raffinates and concentrate. (authors)

  18. No Occasion for Pleasure: The Self-Worth Contingency of a Setback and Coping With Humor

    Directory of Open Access Journals (Sweden)

    Fay Caroline Mary Geisler


    Full Text Available Whether or not one uses humor to cope with a setback may depend on the idiosyncratic relation of the setback to feeling of self-worth. All people pursue the higher order goal of self-validation, but people differ in what domains of life their self-worth is contingent upon and to what extent. In this article based on an incongruity theory of humor we argue that the use of humor in coping with a highly self-worth-contingent setback may be impeded by two cognitive-motivational processes: goal-driven activation and goal shielding. From the outlined theory we derived the hypothesis that the more a domain is contingent upon self-worth, the less likely a person will be to use humor to deal with a setback in that domain. We tested this hypothesis in two studies employing two forms of self-report, i.e., ratings of reaction likelihood to setbacks described at an abstract domain level (Study 1, and ranking of reaction likelihood to concrete setbacks from different domains (Study 2. The hypothesis was affirmed in different domains of self-worth contingency controlling for the influence of habitual coping with humor, coping by disengagement, and global self-esteem.

  19. Selection of Actinide Chemical Analogues for WIPP Tests: Potential Nonradioactive Sorbing and Nonsorbing Tracers for Study of Ion Transport in the Environment

    Energy Technology Data Exchange (ETDEWEB)

    Dale Spall; Robert Villarreal


    Chemical characteristics of the actinides (Th, U, Np, Pu, Am) have been studied relative to nonradioactive chemical elements that have similar characteristics in an attempt to identify a group of actinide chemical analogues that are nonradioactive. In general, the chemistries of the actinides, especially U, Np, Pu, and Am, are very complex and attempts to identify a single chemical analogue for each oxidation state were not successful. However, the rationale for selecting a group of chemical analogues that would mimic the actinides as a group is provided. The categorization of possible chemical analogues (tracers) with similar chemical properties was based on the following criteria. Categorization was studied according.

  20. Duquesne Light Company`s burner modification for NO{sub x} RACT compliance on a 200 MW single face fired pulverized coal unit

    Energy Technology Data Exchange (ETDEWEB)

    Bionda, J.P. [Energy Systems Associates, Pittsburgh, PA (United States); Gabrielson, J.E.; Hallo, A.


    This paper discusses the result of a research test program conducted on Duquesne Light Company`s Elrama Unit 4. The program was designed to determine the viability of achieving compliance with the recently enacted PA DER Reasonably Available Control Technology (RACT) regulations. These regulations stipulate presumptive RACT requirements for wall fired boilers which include the installations and operation of low NO{sub x} burners with separated overfire air. Duquesne Light Company contracted Energy Systems, Associates (ESA) to aide in the design and testing of a novel low NO{sub x} burner design and separated overfire air system. By modifying the coal burners, it has been possible to reduce the NO{sub x} emissions by 50% to 60% on Unit 4, with minimal impact to the unburned carbon in the ash. The burner modifications create fuel rich streams which are surrounded by air rich zones in the primary flame region, thus staging combustion at the burner. Additional NO{sub x} reductions are realized when the combustion is further staged by use of the separated overfire air system.