WorldWideScience

Sample records for worldwide myth co2

  1. Dispelling some myths about the CO2 solubility in ionic liquids.

    Science.gov (United States)

    Carvalho, P J; Kurnia, K A; Coutinho, J A P

    2016-06-01

    Ionic liquids have been objects of extensive research for physical sorption of CO2 and a number of myths have been perpetuated in the literature, for lack of a critical analysis, concerning their potential for CO2 capture. This study carries a critical analysis of a number of widely accepted ideas and others not so well accepted that have been repeatedly expressed in the literature concerning the CO2 physical sorption in ionic liquids. Using the CO2 solubility in eicosane as benchmark, it will be shown that there is no evidence that ILs display a physical sorption of CO2 larger than n-alkanes when analyzed in adequate concentration units; the fluorination of the ions has no impact on the CO2 solubility and the oxygenation will marginally contribute to a decrease of the solubility. Ionic liquid-based deep eutectic systems are also shown to have a poor CO2 solubility. Although these widely used approaches to physically enhance the CO2 solubility in ILs do not seem to have any positive influence, this does not mean that other types of interaction cannot provide enhanced CO2 solubility as in the case of the anion [B(CN)4] confirmed here by a critical analysis of the published data. The mechanism of CO2 physical sorption in ionic liquids is discussed based on the results analyzed, supported by spectroscopic measurements and molecular simulations previously reported and further suggestions of possibilities for enhanced physical sorption based on fluorinated aromatic rings, other cyano based anions, mixtures with other ILs or solvents or the use of porous liquids are proposed.

  2. Enhanced photosynthetic efficiency in trees world-wide by rising atmospheric CO2 levels

    Science.gov (United States)

    Ehlers, Ina; Wieloch, Thomas; Groenendijk, Peter; Vlam, Mart; van der Sleen, Peter; Zuidema, Pieter A.; Robertson, Iain; Schleucher, Jürgen

    2014-05-01

    signals is a fundamental advantage of isotopomer ratios (Augusti et al., Chem. Geol 2008). These results demonstrate that increasing [CO2] has reduced the ratio of photorespiration to photosynthesis on a global scale. Photorespiration is a side reaction that decreases the C gain of plants; the suppression of photorespiration in all analyzed trees indicates that increasing atmospheric [CO2] is enhancing the photosynthetic efficiency of trees world-wide. The consensus response of the trees agrees with the response of annual plants in greenhouse experiments, with three important conclusions. First, the generality of the isotopomer shift confirms that the CO2 response reflects the ratio of photosynthesis to photorespiration, and that it creates a robust signal in tree rings. Second, the agreement between greenhouse-grown plants and trees indicates that there has not been an acclimation response of the trees during the past centuries. Third, the results show that the regulation of tree gas exchange has during past centuries been governed by the same rules as observed in manipulative experiments, in contradiction to recent reports (Keenan et al., Nature 2013).

  3. Ongoing Relative Performance Evaluation for a CO2 EOR Asset in a Worldwide Peer Group

    Science.gov (United States)

    Zhao, C. F.; Li, X. S.; Wang, G. H.; Li, L.

    2017-10-01

    Abstract. Operators of a CO2 EOR asset need to know the relative performance level of their asset against its peers. The ongoing relative performance evaluation method is appropriate for this purpose. We first choose 52 CO2 assets around the world as the peer group, and then define the four ranking levels in terms of CO2consumption ratio. Only the final values of CO2consumption ratio for the group are obtained, and therefore cannot be used for an ongoing evaluation during a CO2 EOR asset’s life circle. Consequently, numerical reservoir simulation is employed to quantify the process values corresponding to the four ranking levels. Type curve plots are generated on the basis of the process values and utilized for the ongoing relative performance evaluation of a CO2 EOR asset in China.

  4. Global Cooling: Increasing World-Wide Urban Albedos to Offset CO2

    Energy Technology Data Exchange (ETDEWEB)

    Akbari, Hashem; Menon, Surabi; Rosenfeld, Arthur

    2008-01-14

    Modification of urban albedos reduces summertime urban temperatures, resulting in a better urban air quality and building air-conditioning savings. Furthermore, increasing urban albedos has the added benefit of reflecting some of the incoming global solar radiation and countering to some extent the effects of global warming. In many urban areas, pavements and roofs constitute over 60% of urban surfaces (roof 20-25%, pavements about 40%). Using reflective materials, both roof and the pavement albedos can be increased by about 0.25 and 0.10, respectively, resulting in a net albedo increase for urban areas of about 0.1. Many studies have demonstrated building cooling-energy savings in excess of 20% upon raising roof reflectivity from an existing 10-20% to about 60% (a U.S. potential savings in excess of $1 billion (B) per year in net annual energy bills). On a global basis, our preliminary estimate is that increasing the world-wide albedos of urban roofs and paved surfaces will induce a negative radiative forcing on the earth equivalent to removing {approx} 22-40 Gt of CO{sub 2} from the atmosphere. Since, 55% of the emitted CO{sub 2} remains in the atmosphere, removal of 22-40 Gt of CO{sub 2} from the atmosphere is equivalent to reducing global CO{sub 2} emissions by 40-73 Gt. At {approx} $25/tonne of CO{sub 2}, a 40-73 Gt CO{sub 2} emission reduction from changing the albedo of roofs and paved surfaces is worth about $1,000B to 1800B. These estimated savings are dependent on assumptions used in this study, but nevertheless demonstrate considerable benefits that may be obtained from cooler roofs and pavements.

  5. Islamic Myths and Memories

    DEFF Research Database (Denmark)

    Islamic myths and collective memory are very much alive in today’s localized struggles for identity, and are deployed in the ongoing construction of worldwide cultural networks. This book brings the theoretical perspectives of myth-making and collective memory to the study of Islam and globalizat......Islamic myths and collective memory are very much alive in today’s localized struggles for identity, and are deployed in the ongoing construction of worldwide cultural networks. This book brings the theoretical perspectives of myth-making and collective memory to the study of Islam...

  6. CO2 blood test

    Science.gov (United States)

    Bicarbonate test; HCO3-; Carbon dioxide test; TCO2; Total CO2; CO2 test - serum; Acidosis - CO2; Alkalosis - CO2 ... The CO2 test is most often done as part of an electrolyte or basic metabolic panel. Changes in your ...

  7. Alzheimer's Myths

    Science.gov (United States)

    ... home. Myth 3: Only older people can get Alzheimer's Reality: Alzheimer's can strike people in their 30s, ... Myth 7: Silver dental fillings increase risk of Alzheimer's disease Reality: According to the best available scientific ...

  8. Busting Myths

    Science.gov (United States)

    Chick, Helen

    2013-01-01

    Arecent episode of "MythBusters" (Williams, 2013) involved a series of "battles of the sexes" to examine myths and urban legends about things that men are supposedly better (or worse) at doing than women. Some of the processes that were used on the show to investigate these myths, along with the data they generated, can be used…

  9. CO2-Neutral Fuels

    NARCIS (Netherlands)

    Goede, A.; van de Sanden, M. C. M.

    2016-01-01

    Mimicking the biogeochemical cycle of System Earth, synthetic hydrocarbon fuels are produced from recycled CO2 and H2O powered by renewable energy. Recapturing CO2 after use closes the carbon cycle, rendering the fuel cycle CO2 neutral. Non-equilibrium molecular CO2 vibrations are key to high energy

  10. Pan-Gaean Flood myths: Gondwana myths -- and beyond

    OpenAIRE

    Witzel, Michael E.J.

    2010-01-01

    Mythological compendia and indexes such as that by Stith Thompson create the impression that flood myths are rare in Africa and Australia. Erroneously, I too thought so in my short summary of Laurasian mythology (2001). A closer look at the worldwide distribution of flood myths tells differently. While they are fairly widespread in the Laurasian Area (Eurasia, Polynesia, the Americas), they are by no means absent from what I like to call the Gondwana belt (sub-Saharan Africa, New Guinea / M...

  11. Carbon Sequestration: Hydrogenation of CO2 to Formic Acid

    Directory of Open Access Journals (Sweden)

    Upadhyay Praveenkumar

    2016-10-01

    Full Text Available The concentration CO2 gas has become a great worldwide challenge because CO2 is considered as an important counterpart of greenhouse gases. The tremendous increase in the concentration of CO2 gas, elevated the worldwide temperature as well as it altered the climatic changes. Various physiochemical approached have been reported to trap the CO2 gas and the chemical conversion of CO2 to useful chemicals is one of them. This review covers the conversion of CO2 gas to formic acid. In this CO2 hydrogenation reaction, both the homogeneous as well as heterogeneous catalytic systems were discussed along with the effect of solvent systems on reaction kinetics.

  12. Grammar Myths

    Science.gov (United States)

    Berry, Roger

    2015-01-01

    This paper looks at the continued survival of "myths" about English grammar, for example, the statement that in negative and interrogative sentences "any" should be used instead of "some". It is based on a survey of 195 Hong Kong students majoring in English, in five different cohorts, which found that such myths are…

  13. CO2NNIE

    DEFF Research Database (Denmark)

    Krogh, Benjamin Bjerre; Andersen, Ove; Lewis-Kelham, Edwin

    2015-01-01

    We propose a system for calculating the personalized annual fuel consumption and CO2 emissions from transportation. The system, named CO2NNIE, estimates the fuel consumption on the fastest route between the frequent destinations of the user. The travel time and fuel consumption estimated are based......% of the actual fuel consumption (4.6% deviation on average). We conclude, that the system provides new detailed information on CO2 emissions and fuel consumption for any make and model....

  14. CO2 laser resurfacing.

    Science.gov (United States)

    Fitzpatrick, R E

    2001-07-01

    The CO2 Laser offers a variety of unique features in resurfacing facial photodamage and acne scarring. These include hemostasis, efficient removal of the epidermis in a single pass, thermally induced tissue tightening, and safe, predictable tissue interaction. Knowledge of these mechanisms will result in the capability of using the CO2 laser effectively and safely whether the goal is superficial or deep treatment.

  15. CO2 uit buitenlucht

    NARCIS (Netherlands)

    Weel, van P.A.; Vanthoor, B.H.E.

    2016-01-01

    The supply of additional CO2 in a greenhouse will be restricted in the future. The concentration in outside air has risen above 400 ppm. This may open the possibility to blow this air through the canopy to increase growth. In this project, the vertical CO2 concentration was measured in a vertical

  16. Diabetes Myths

    Science.gov (United States)

    ... Text Size: A A A Listen En Español Diabetes Myths On behalf of the millions of Americans ... or obese, you will eventually develop type 2 diabetes. Fact: Being overweight is a risk factor for ...

  17. Outsourcing CO2 Emissions

    Science.gov (United States)

    Davis, S. J.; Caldeira, K. G.

    2009-12-01

    CO2 emissions from the burning of fossil fuels are the primary cause of global warming. Much attention has been focused on the CO2 directly emitted by each country, but relatively little attention has been paid to the amount of emissions associated with consumption of goods and services in each country. This consumption-based emissions inventory differs from the production-based inventory because of imports and exports of goods and services that, either directly or indirectly, involved CO2 emissions. Using the latest available data and reasonable assumptions regarding trans-shipment of embodied carbon through third-party countries, we developed a global consumption-based CO2 emissions inventory and have calculated associated consumption-based energy and carbon intensities. We find that, in 2004, 24% of CO2 emissions are effectively outsourced to other countries, with much of the developed world outsourcing CO2 emissions to emerging markets, principally China. Some wealthy countries, including Switzerland and Sweden, outsource over half of their consumption-based emissions, with many northern Europeans outsourcing more than three tons of emissions per person per year. The United States is both a big importer and exporter of emissions embodied in trade, outsourcing >2.6 tons of CO2 per person and at the same time as >2.0 tons of CO2 per person are outsourced to the United States. These large flows indicate that CO2 emissions embodied in trade must be taken into consideration when considering responsibility for increasing atmospheric greenhouse gas concentrations.

  18. Capnography: monitoring CO2.

    Science.gov (United States)

    Casey, Georgina

    2015-10-01

    MONITORING RESPIRATORY and metabolic function by using capnography to measure end tidal carbon dioxide is standard practice in anaesthesia. It is also becoming more common in intensive care units and during procedural sedation. End tidal carbon dioxide (EtCO2) monitoring may also be used to assess effectiveness of cardiopulmonary resuscitation. Capnography is now emerging in general medical and surgical wards to monitor respiratory depression in patients using opioid analgesics. Using EtCO2 to monitor respiratory function offers many benefits over pulse oximetry. It is important to understand the differences between these two monitoring methods, and why capnography is increasingly favoured in many situations. An understanding of the physiological processes involved in CO2 excretion allows nurses to use capnography in a safe and meaningful way, while monitoring at-risk patients in acute care.

  19. CO2-strategier

    DEFF Research Database (Denmark)

    Jørgensen, Michael Søgaard

    2008-01-01

    I 2007 henvendte Lyngby-Taarbæk kommunens Agenda 21 koordinator sig til Videnskabsbutikken og spurgte om der var interesse for at samarbejde om CO2-strategier. Da Videnskabsbutikken DTU er en åben dør til DTU for borgerne og deres organisationer, foreslog Videnskabsbutikken DTU at Danmarks...... Naturfredningsforening’s lokalkomité for Lyngby blev en del af samarbejdet for at få borgerne i kommunen involveret i arbejdet med at udvikle strategier for reduktion af CO2. Siden sommeren 2007 har Videnskabsbutikken DTU, Lyngby-Taarbæk kommune og Danmarks Naturfredningsforening i Lyngby-Taarbæk samarbejdet om analyse...... og innovation i forhold til CO2-strategier....

  20. CO2 cycle

    Science.gov (United States)

    Titus, Timothy N.; Byrne, Shane; Colaprete, Anthony; Forget, Francois; Michaels, Timothy I.; Prettyman, Thomas H.

    2017-01-01

    This chapter discusses the use of models, observations, and laboratory experiments to understand the cycling of CO2 between the atmosphere and seasonal Martian polar caps. This cycle is primarily controlled by the polar heat budget, and thus the emphasis here is on its components, including solar and infrared radiation, the effect of clouds (water- and CO2-ice), atmospheric transport, and subsurface heat conduction. There is a discussion about cap properties including growth and regression rates, albedos and emissivities, grain sizes and dust and/or water-ice contamination, and curious features like cold gas jets and araneiform (spider-shaped) terrain. The nature of the residual south polar cap is discussed as well as its long-term stability and ability to buffer atmospheric pressures. There is also a discussion of the consequences of the CO2 cycle as revealed by the non-condensable gas enrichment observed by Odyssey and modeled by various groups.

  1. Myth Dispelled

    Centers for Disease Control (CDC) Podcasts

    2013-03-20

    Dr. Adam Possner, an assistant professor of general internal medicine at George Washington University, reads and discusses his poem, "Myth Dispelled.".  Created: 3/20/2013 by National Center for Emerging and Zoonotic Infectious Diseases (NCEZID).   Date Released: 3/21/2013.

  2. CO2NSL (Datalogger)

    DEFF Research Database (Denmark)

    Andersen, Sune Sick

    ,1500 street lamps around Copenhagen will be changed for light sources with low power consumption. Technical and Environmental turn down the energy as a part of Copenhagen goal of reducing the citys CO2 emissions by 20 percent by the end of year 2015. But how much power will the new lamps comsume? And can...

  3. CO2-neutral fuels

    Directory of Open Access Journals (Sweden)

    Goede A. P. H.

    2015-01-01

    Full Text Available The need for storage of renewable energy (RE generated by photovoltaic, concentrated solar and wind arises from the fact that supply and demand are ill-matched both geographically and temporarily. This already causes problems of overcapacity and grid congestion in countries where the fraction of RE exceeds the 20% level. A system approach is needed, which focusses not only on the energy source, but includes conversion, storage, transport, distribution, use and, last but not least, the recycling of waste. Furthermore, there is a need for more flexibility in the energy system, rather than relying on electrification, integration with other energy systems, for example the gas network, would yield a system less vulnerable to failure and better adapted to requirements. For example, long-term large-scale storage of electrical energy is limited by capacity, yet needed to cover weekly to seasonal demand. This limitation can be overcome by coupling the electricity net to the gas system, considering the fact that the Dutch gas network alone has a storage capacity of 552 TWh, sufficient to cover the entire EU energy demand for over a month. This lecture explores energy storage in chemicals bonds. The focus is on chemicals other than hydrogen, taking advantage of the higher volumetric energy density of hydrocarbons, in this case methane, which has an approximate 3.5 times higher volumetric energy density. More importantly, it allows the ready use of existing gas infrastructure for energy storage, transport and distribution. Intermittent wind electricity generated is converted into synthetic methane, the Power to Gas (P2G scheme, by splitting feedstock CO2 and H2O into synthesis gas, a mixture of CO and H2. Syngas plays a central role in the synthesis of a range of hydrocarbon products, including methane, diesel and dimethyl ether. The splitting is accomplished by innovative means; plasmolysis and high-temperature solid oxygen electrolysis. A CO2-neutral fuel

  4. CO2-neutral fuels

    Science.gov (United States)

    Goede, A. P. H.

    2015-08-01

    The need for storage of renewable energy (RE) generated by photovoltaic, concentrated solar and wind arises from the fact that supply and demand are ill-matched both geographically and temporarily. This already causes problems of overcapacity and grid congestion in countries where the fraction of RE exceeds the 20% level. A system approach is needed, which focusses not only on the energy source, but includes conversion, storage, transport, distribution, use and, last but not least, the recycling of waste. Furthermore, there is a need for more flexibility in the energy system, rather than relying on electrification, integration with other energy systems, for example the gas network, would yield a system less vulnerable to failure and better adapted to requirements. For example, long-term large-scale storage of electrical energy is limited by capacity, yet needed to cover weekly to seasonal demand. This limitation can be overcome by coupling the electricity net to the gas system, considering the fact that the Dutch gas network alone has a storage capacity of 552 TWh, sufficient to cover the entire EU energy demand for over a month. This lecture explores energy storage in chemicals bonds. The focus is on chemicals other than hydrogen, taking advantage of the higher volumetric energy density of hydrocarbons, in this case methane, which has an approximate 3.5 times higher volumetric energy density. More importantly, it allows the ready use of existing gas infrastructure for energy storage, transport and distribution. Intermittent wind electricity generated is converted into synthetic methane, the Power to Gas (P2G) scheme, by splitting feedstock CO2 and H2O into synthesis gas, a mixture of CO and H2. Syngas plays a central role in the synthesis of a range of hydrocarbon products, including methane, diesel and dimethyl ether. The splitting is accomplished by innovative means; plasmolysis and high-temperature solid oxygen electrolysis. A CO2-neutral fuel cycle is

  5. Myth & Bones

    DEFF Research Database (Denmark)

    Marchetti, Emanuela

    2011-01-01

    Recently museums are re-discussing traditional practices, as they became concerned with visitors' experience and learning. In this study communication is found to be mono-directional, especially towards captive audiences, like primary school children. The diachronic perspective seems neglected, a...... design of a new interactive installation, conducted with 8-10 years old children. Field study and initial evaluation show that introduction of notions related to human life-cycle and myth may further enrich learning from children's perspective....

  6. Tatar Myths

    OpenAIRE

    Kamalov, İlyas

    2005-01-01

    The Turks of Tataristan have a long tradition of sedentary life and written culture in the region where they currently live. In this environment, rich mythological elements of the Turkic world have got more chance to survive the long historical times. Their mythology grew richer, in the course of time, with various inner and outer influences, and have got more mythological materials. This article summarizes personalities in the Tatar myths and legends.

  7. Greek and Roman Myths.

    Science.gov (United States)

    Carr, Fredella; Faggionato, Michael

    Designed for use with the text "Greek and Roman Myths," this junior high school learning activity packet introduces students to mythology and examines the influence of myths on contemporary culture. Over 20 exercises, tagged to specific readings in the text, cover identification of the major gods, the Prometheus myth, the Atlas myth,…

  8. Global CO2 Levels and the Calvin Cycle

    Science.gov (United States)

    1990-01-01

    half of the total CO2 fixed world-wide is processed by marine algae . Presently, three mechanisms have been described by which CO 2 may be...information on the autotrophic process in eukaryotes has been derived almost exclusively from terrestrial plants and green algae (the Chlorophyta...However, two additional supertaxa of plants also fix CO 2. The Chromophyta represent a large assemblage of algae that include the diatoms and

  9. Decoupling of CO2 emissions and GDP

    Directory of Open Access Journals (Sweden)

    Yves Rocha de Salles Lima

    2016-12-01

    Full Text Available The objetive of this work is to analyze the variation of CO2 emissions and GDP per capita throughout the years and identify the possible interaction between them. For this purpose, data from the International Energy Agency was collected on two countries, Brazil and the one with the highest GDP worldwide, the United States. Thus, the results showed that CO2 emissions have been following the country’s economic growth for many years. However, these two indicators have started to decouple in the US in 2007 while in Brazil the same happened in 2011. Furthermore, projections for CO2 emissions are made until 2040, considering 6 probable scenarios. These projections showed that even if the oil price decreases, the emissions will not be significantly affected as long as the economic growth does not decelerate.

  10. Continuous CO2 extractor and methods

    Energy Technology Data Exchange (ETDEWEB)

    None listed

    2010-06-15

    The purpose of this CRADA was to assist in technology transfer from Russia to the US and assist in development of the technology improvements and applications for use in the U.S. and worldwide. Over the period of this work, ORNL has facilitated design, development and demonstration of a low-pressure liquid extractor and development of initial design for high-pressure supercritical CO2 fluid extractor.

  11. MYTH Screening: iMYTH and tMYTH Variants.

    Science.gov (United States)

    Snider, Jamie; Stagljar, Igor

    2016-01-04

    Once a bait has been generated and validated for the membrane yeast two-hybrid (MYTH) assay, it can be used for either high-throughput screening to generate a detailed interaction map (interactome) or in low-throughput experiments to examine interactions with specific targets. Here we describe how to carry out high-throughput MYTH library screening of a validated bait generated using integrated or traditional MYTH. The principles herein can be easily adapted for use in a smaller-scale format if required. A typical MYTH library screen can be completed in ∼3-4 wk. © 2016 Cold Spring Harbor Laboratory Press.

  12. Biosequestration of atmospheric CO2 and flue gas-containing CO2 by microalgae.

    Science.gov (United States)

    Cheah, Wai Yan; Show, Pau Loke; Chang, Jo-Shu; Ling, Tau Chuan; Juan, Joon Ching

    2015-05-01

    The unceasing rise of greenhouse gas emission has led to global warming and climate change. Global concern on this phenomenon has put forward the microalgal-based CO2 sequestration aiming to sequester carbon back to the biosphere, ultimately reducing greenhouse effects. Microalgae have recently gained enormous attention worldwide, to be the valuable feedstock for renewable energy production, due to their high growth rates, high lipid productivities and the ability to sequester carbon. The photosynthetic process of microalgae uses atmospheric CO2 and CO2 from flue gases, to synthesize nutrients for their growth. In this review article, we will primarily discuss the efficiency of CO2 biosequestration by microalgae species, factors influencing microalgal biomass productions, microalgal cultivation systems, the potential and limitations of using flue gas for microalgal cultivation as well as the bio-refinery approach of microalgal biomass. Copyright © 2014 Elsevier Ltd. All rights reserved.

  13. A CO2-strategy for BTC [Belgian Development Agency

    Energy Technology Data Exchange (ETDEWEB)

    Bailly, J. [Prospect C and S, Brussels (Belgium); Hanekamp, E. [Partners for Innovation, Amsterdam (Netherlands)

    2008-09-15

    The CO2 footprint is determined the CO2 strategy is developed for the Belgian Technical Cooperation (BTC). BTC is the Belgian agency for development cooperation, and finances development projects in 23 partner countries. The CO2 footprint covered BTC's activities in 2007 in all their offices worldwide. Footprint and strategy were finalised and adopted by the Executive Board at the end of 2008. Meanwhile, the BTC began with the introduction of the proposed strategy. Partners for Innovation and Prospect were asked to support the introduction of the strategy and to determine the CO2 footprint of 2008.

  14. Forecasting global atmospheric CO2

    Science.gov (United States)

    Agustí-Panareda, A.; Massart, S.; Chevallier, F.; Boussetta, S.; Balsamo, G.; Beljaars, A.; Ciais, P.; Deutscher, N. M.; Engelen, R.; Jones, L.; Kivi, R.; Paris, J.-D.; Peuch, V.-H.; Sherlock, V.; Vermeulen, A. T.; Wennberg, P. O.; Wunch, D.

    2014-11-01

    A new global atmospheric carbon dioxide (CO2) real-time forecast is now available as part of the pre-operational Monitoring of Atmospheric Composition and Climate - Interim Implementation (MACC-II) service using the infrastructure of the European Centre for Medium-Range Weather Forecasts (ECMWF) Integrated Forecasting System (IFS). One of the strengths of the CO2 forecasting system is that the land surface, including vegetation CO2 fluxes, is modelled online within the IFS. Other CO2 fluxes are prescribed from inventories and from off-line statistical and physical models. The CO2 forecast also benefits from the transport modelling from a state-of-the-art numerical weather prediction (NWP) system initialized daily with a wealth of meteorological observations. This paper describes the capability of the forecast in modelling the variability of CO2 on different temporal and spatial scales compared to observations. The modulation of the amplitude of the CO2 diurnal cycle by near-surface winds and boundary layer height is generally well represented in the forecast. The CO2 forecast also has high skill in simulating day-to-day synoptic variability. In the atmospheric boundary layer, this skill is significantly enhanced by modelling the day-to-day variability of the CO2 fluxes from vegetation compared to using equivalent monthly mean fluxes with a diurnal cycle. However, biases in the modelled CO2 fluxes also lead to accumulating errors in the CO2 forecast. These biases vary with season with an underestimation of the amplitude of the seasonal cycle both for the CO2 fluxes compared to total optimized fluxes and the atmospheric CO2 compared to observations. The largest biases in the atmospheric CO2 forecast are found in spring, corresponding to the onset of the growing season in the Northern Hemisphere. In the future, the forecast will be re-initialized regularly with atmospheric CO2 analyses based on the assimilation of CO2 products retrieved from satellite measurements and

  15. Myths about drinking alcohol

    Science.gov (United States)

    ... gov/ency/patientinstructions/000856.htm Myths about drinking alcohol To use the sharing features on this page, ... We know much more about the effects of alcohol today than in the past. Yet, myths remain ...

  16. Meningitis Myths and Facts

    Science.gov (United States)

    ... May 2014) 14 Adult Vaccine-Preventable Diseases Infographic Meningitis Myths and Facts Myth: Meningococcal disease is easy ... infected person, such as shaking hands. Fact: Meningococcal meningitis is spread through air droplets and direct contact ...

  17. Biology Myth-Killers

    Science.gov (United States)

    Lampert, Evan

    2014-01-01

    "Biology Myth-Killers" is an activity designed to identify and correct common misconceptions for high school and college introductory biology courses. Students identify common myths, which double as biology misconceptions, and use appropriate sources to share the "truth" about the myths. This learner-centered activity is a fun…

  18. CO2 as a refrigerant

    CERN Document Server

    2014-01-01

    A first edition, the IIR guide “CO2 as a Refrigerant” highlights the application of carbon dioxide in supermarkets, industrial freezers, refrigerated transport, and cold stores as well as ice rinks, chillers, air conditioning systems, data centers and heat pumps. This guide is for design and development engineers needing instruction and inspiration as well as non-technical experts seeking background information on a specific topic. Written by Dr A.B. Pearson, a well-known expert in the field who has considerable experience in the use of CO2 as a refrigerant. Main topics: Thermophysical properties of CO2 – Exposure to CO2, safety precautions – CO2 Plant Design – CO2 applications – Future prospects – Standards and regulations – Bibliography.

  19. Enzymes in CO2 Capture

    DEFF Research Database (Denmark)

    Fosbøl, Philip Loldrup; Gladis, Arne; Thomsen, Kaj

    The enzyme Carbonic Anhydrase (CA) can accelerate the absorption rate of CO2 into aqueous solutions by several-fold. It exist in almost all living organisms and catalyses different important processes like CO2 transport, respiration and the acid-base balances. A new technology in the field...... of carbon capture is the application of enzymes for acceleration of typically slow ternary amines or inorganic carbonates. There is a hidden potential to revive currently infeasible amines which have an interesting low energy consumption for regeneration but too slow kinetics for viable CO2 capture. The aim...... of this work is to discuss the measurements of kinetic properties for CA promoted CO2 capture solvent systems. The development of a rate-based model for enzymes will be discussed showing the principles of implementation and the results on using a well-known ternary amine for CO2 capture. Conclusions...

  20. CO2 Sequestration short course

    Energy Technology Data Exchange (ETDEWEB)

    DePaolo, Donald J. [Lawrence Berkeley National Laboratory; Cole, David R [The Ohio State University; Navrotsky, Alexandra [University of California-Davis; Bourg, Ian C [Lawrence Berkeley National Laboratory

    2014-12-08

    Given the public’s interest and concern over the impact of atmospheric greenhouse gases (GHGs) on global warming and related climate change patterns, the course is a timely discussion of the underlying geochemical and mineralogical processes associated with gas-water-mineral-interactions encountered during geological sequestration of CO2. The geochemical and mineralogical processes encountered in the subsurface during storage of CO2 will play an important role in facilitating the isolation of anthropogenic CO2 in the subsurface for thousands of years, thus moderating rapid increases in concentrations of atmospheric CO2 and mitigating global warming. Successful implementation of a variety of geological sequestration scenarios will be dependent on our ability to accurately predict, monitor and verify the behavior of CO2 in the subsurface. The course was proposed to and accepted by the Mineralogical Society of America (MSA) and The Geochemical Society (GS).

  1. Connecting CO2. Feasibility study CO2 network Southwest Netherlands; Connecting CO2. Haalbaarheidsstudie CO2-netwerk Zuidwest-Nederland

    Energy Technology Data Exchange (ETDEWEB)

    Rutten, M.

    2009-06-10

    An overview is given of supply and demand of CO2 in the region Southwest Netherlands and the regions Antwerp and Gent in Belgium. Also attention is paid to possible connections between these regions [Dutch] Een inventarisatie wordt gegeven van vraag en aanbod van CO2 in de regio Zuidwest- Nederland en de regios Antwerpen en Gent in Belgie. Ook worden mogelijke koppelingen tussen de regios besproken.

  2. Do physicists need myths?

    Science.gov (United States)

    Brown, Harold I.

    2006-05-01

    In textbooks and popular writings physicists repeat familiar stories about the history of physics that historians have long identified as myths. Examples of remarks about Galileo and Aristotle are used to illustrate this practice. These examples lead to a discussion of several reasons why these myths might play a positive role for physicists and whether physicists can dispense with myths about the history of their field.

  3. The CO2nnect activities

    Science.gov (United States)

    Eugenia, Marcu

    2014-05-01

    Climate change is one of the biggest challenges we face today. A first step is the understanding the problem, more exactly what is the challenge and the differences people can make. Pupils need a wide competencies to meet the challenges of sustainable development - including climate change. The CO2nnect activities are designed to support learning which can provide pupils the abilities, skills, attitudes and awareness as well as knowledge and understanding of the issues. The project "Together for a clean and healthy world" is part of "The Global Educational Campaign CO2nnect- CO2 on the way to school" and it was held in our school in the period between February and October 2009. It contained a variety of curricular and extra-curricular activities, adapted to students aged from 11 to 15. These activities aimed to develop in students the necessary skills to understanding man's active role in improving the quality of the environment, putting an end to its degrading process and to reducing the effects of climate changes caused by the human intervention in nature, including transport- a source of CO2 pollution. The activity which I propose can be easily adapted to a wide range of age groups and linked to the curricula of many subjects: - Investigate CO2 emissions from travel to school -Share the findings using an international database -Compare and discuss CO2 emissions -Submit questions to a climate- and transport expert -Partner with other schools -Meet with people in your community to discuss emissions from transport Intended learning outcomes for pupils who participate in the CO2nnect campaign are: Understanding of the interconnected mobility- and climate change issue climate change, its causes and consequences greenhouse-gas emissions from transport and mobility the interlinking of social, environmental, cultural and economic aspects of the local transport system how individual choices and participation can contribute to creating a more sustainable development

  4. Myths of Library Automation.

    Science.gov (United States)

    Hegarty, Kevin

    1985-01-01

    This analysis of nine myths of library automation highlights cost effectiveness, circulation control and delinquency rates, budget allocation, staff needs, technical services productivity, the online catalog, need for consultants, the MARC format, and turnkey systems. Views of the reality regarding each myth are offered. (EJS)

  5. Stars and Star Myths.

    Science.gov (United States)

    Eason, Oliver

    Myths and tales from around the world about constellations and facts about stars in the constellations are presented. Most of the stories are from Greek and Roman mythology; however, a few Chinese, Japanese, Polynesian, Arabian, Jewish, and American Indian tales are also included. Following an introduction, myths are presented for the following 32…

  6. Debunking the Cinderella Myth.

    Science.gov (United States)

    Lee, Mildred K.

    1984-01-01

    Focuses on debunking the Cinderella Myth--that relates the tale of Cinderella who is abused and exploited until she finds Prince Charming and lives happily ever after--and indicates that the same strategies are applicable to the debunking of other sex-biased myths. (JOW)

  7. Tracking industrial energy efficiency and CO2 emissions

    National Research Council Canada - National Science Library

    2007-01-01

    ... decades, energy use and CO 2 emissions in manufacturing industries could be reduced by a further quarter to a third, if best available technology were to be applied worldwide. Some of these additional reductions may not be economic in the shortand medium-term, but the sheer extent of the potential suggests that striving for significa...

  8. Reducing cement's CO2 footprint

    Science.gov (United States)

    van Oss, Hendrik G.

    2011-01-01

    The manufacturing process for Portland cement causes high levels of greenhouse gas emissions. However, environmental impacts can be reduced by using more energy-efficient kilns and replacing fossil energy with alternative fuels. Although carbon capture and new cements with less CO2 emission are still in the experimental phase, all these innovations can help develop a cleaner cement industry.

  9. Partial pressure (or fugacity) of carbon dioxide, salinity and other variables collected from Surface underway observations using Carbon dioxide (CO2) gas analyzer and other instruments from unknown platforms in the world-wide oceans from 1968-11-16 to 2007-12-31 (NODC Accession 0101726)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0101726 includes Surface underway, chemical, meteorological and physical data collected from unknown platforms in the world-wide oceans from...

  10. Partial pressure (or fugacity) of carbon dioxide, salinity and other variables collected from Surface underway observations using Carbon dioxide (CO2) gas analyzer and other instruments from unknown platforms in the world-wide oceans from 1968-11-16 to 2013-12-31 (NCEI Accession 0160918)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0160918 includes Surface underway, chemical, meteorological, navigational and physical data collected from unknown platforms in the world-wide oceans...

  11. Partial pressure (or fugacity) of carbon dioxide, salinity and other variables collected from Surface underway observations using Carbon dioxide (CO2) gas analyzer and other instruments from unknown platforms in the world-wide oceans from 1968-11-16 to 2011-12-31 (NCEI Accession 0157631)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0157631 includes Surface underway, chemical, meteorological, navigational and physical data collected from unknown platforms in the world-wide oceans...

  12. Partial pressure (or fugacity) of carbon dioxide collected from Surface underway observations using Carbon dioxide (CO2) gas analyzer and other instruments from unknown platforms in the world-wide oceans from 1996-01-01 to 2004-12-31 (NCEI Accession 0157733)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0157733 includes Surface underway and chemical data collected from unknown platforms in the world-wide oceans from 1996-01-01 to 2004-12-31. These...

  13. Generation and Validation of MYTH Baits: iMYTH and tMYTH Variants.

    Science.gov (United States)

    Snider, Jamie; Stagljar, Igor

    2016-01-04

    Generation of baits for membrane yeast two-hybrid (MYTH) screening differs depending on the nature of the protein(s) being studied. When using native yeast proteins with cytoplasmic carboxyl termini, the integrated form of MYTH (iMYTH) is the method of choice. iMYTH involves endogenous carboxy-terminal tagging of the gene of interest within the yeast chromosome, leaving the gene under the control of its natural promoter. When studying proteins not native to yeast, or native yeast proteins with only cytoplasmic amino termini, traditional MYTH (tMYTH) must be used. In the tMYTH approach, amino- or carboxy-terminally tagged proteins are expressed ectopically from a plasmid. In this protocol, we describe the generation and validation of iMYTH and tMYTH baits. MYTH bait generation can typically be completed in ∼1-2 wk. © 2016 Cold Spring Harbor Laboratory Press.

  14. Fang CO2 med Aminosyrer

    DEFF Research Database (Denmark)

    Lerche, Benedicte Mai

    2010-01-01

    Med såkaldte “carbon capture-teknikker” er det muligt at rense røgen fra kulfyrede kraftværker, således at den er næsten helt fri for drivhusgassen CO2. Kunsten er at gøre processen tilstrækkeligt billig. Et lovende fangstredskab i denne proces er aminosyrer.......Med såkaldte “carbon capture-teknikker” er det muligt at rense røgen fra kulfyrede kraftværker, således at den er næsten helt fri for drivhusgassen CO2. Kunsten er at gøre processen tilstrækkeligt billig. Et lovende fangstredskab i denne proces er aminosyrer....

  15. Outsourcing CO2 within China.

    Science.gov (United States)

    Feng, Kuishuang; Davis, Steven J; Sun, Laixiang; Li, Xin; Guan, Dabo; Liu, Weidong; Liu, Zhu; Hubacek, Klaus

    2013-07-09

    Recent studies have shown that the high standard of living enjoyed by people in the richest countries often comes at the expense of CO2 emissions produced with technologies of low efficiency in less affluent, developing countries. Less apparent is that this relationship between developed and developing can exist within a single country's borders, with rich regions consuming and exporting high-value goods and services that depend upon production of low-cost and emission-intensive goods and services from poorer regions in the same country. As the world's largest emitter of CO2, China is a prominent and important example, struggling to balance rapid economic growth and environmental sustainability across provinces that are in very different stages of development. In this study, we track CO2 emissions embodied in products traded among Chinese provinces and internationally. We find that 57% of China's emissions are related to goods that are consumed outside of the province where they are produced. For instance, up to 80% of the emissions related to goods consumed in the highly developed coastal provinces are imported from less developed provinces in central and western China where many low-value-added but high-carbon-intensive goods are produced. Without policy attention to this sort of interprovincial carbon leakage, the less developed provinces will struggle to meet their emissions intensity targets, whereas the more developed provinces might achieve their own targets by further outsourcing. Consumption-based accounting of emissions can thus inform effective and equitable climate policy within China.

  16. Global Warming: A Myth?

    Indian Academy of Sciences (India)

    Home; Journals; Resonance – Journal of Science Education; Volume 6; Issue 7. Global Warming: A Myth? - Credibility of Climate Scenarios Predicted by Systems Simulations. Deepanjan Majumdar. General Article Volume 6 Issue 7 July 2001 pp 13-21 ...

  17. Liberating Interdisciplinarity from Myth

    DEFF Research Database (Denmark)

    Madsen, Dorte

    2016-01-01

    Schools and what is assumed to be a major institutional redrawing of boundaries, there is a pressing need to conceptualize interdisciplinary practices and boundary work. This paper explores the “weak” discipline through a discourse analytical lens and identifies a myth. Perceiving the discipline as weak is part...... of a myth, fueled by the ideal of a unitary discipline; the ideal discipline has strong boundaries, and as long as the discourse continues to focus on a need for boundaries, the only available discourse is one that articulates the discipline as weak. Thus, the myth is a vicious circle that can be broken...... if weakness is no longer ascribed to the discipline by tradition. The paper offers an explanation of the workings of the myth so that its particular way of interpreting the world does not mislead us when theorizing interdisciplinarity. This is a conceptual paper, and the examples serve as an empirical...

  18. Morphine: Myths and Reality

    Science.gov (United States)

    ... section All Articles & Stories News Morphine: Myths and Reality Feb 2, 2013 Share The mere mention of “ ... due to misinformation and lack of training. The reality is that Morphine (and other opiates that work ...

  19. Global Warming: A Myth?

    Indian Academy of Sciences (India)

    Home; Journals; Resonance – Journal of Science Education; Volume 6; Issue 6. Global Warming: A Myth? - Anomalous Temperature Trends Recorded from Satellites and Radiosondes. Deepanjan Majumdar. General Article Volume 6 Issue 6 June 2001 pp 43-52 ...

  20. AIDS Myths and Misunderstandings

    Science.gov (United States)

    ... HIV is being spread by needles left in theater seats or vending machine coin returns. Reality: There ... cells (see fact sheet 124 ) could drop, a sign of immune damage. Myth: AIDS drugs are poison ...

  1. RODZAJE METOD SEKWESTRACJI CO2

    Directory of Open Access Journals (Sweden)

    Zofia LUBAŃSKA

    Full Text Available Z pojęciem ochrony środowiska wiąże się bardzo szeroko w ostatnim czasie omawiane zagadnienie dotyczące ograniczenia emisji CO2. Konsekwencją globalnych zmian klimatu wywołanego przez ludzi jest wzrost stężenia atmosferycznego gazów cieplarnianych, które powodują nasilający się efekt cieplarniany. Wzrasta na świecie liczba ludności, a co za tym idzie wzrasta konsumpcja na jednego mieszkańca, szczególnie w krajach szeroko rozwiniętych gospodarczo. Protokół z Kioto ściśle określa działania jakie należy podjąć w celu zmniejszenia stężenia dwutlenku węgla w atmosferze. Pomimo maksymalnej optymalizacji procesu spalania paliw kopalnianych wykorzystywanych do produkcji energii, zastosowania odnawialnych źródeł energii zmiana klimatu jest nieunikniona i konsekwentnie będzie postępować przez kolejne dekady. Prognozuje się, że duże znaczenie odegra nowoczesna technologia, która ma za zadanie wychwycenie CO2 a następnie składowanie go w odpowiednio wybranych formacjach geologicznych (CCS- Carbon Capture and Storage. Eksperci są zgodni, że ta technologia w niedalekiej przyszłości stanie się rozwiązaniem pozwalającym ograniczyć ogromną ilość emisji CO2 pochodzącą z procesów wytwarzania energii z paliw kopalnych. Z analiz Raportu IPCC wynika, iż technologia CSS może się przyczynić do ok. 20% redukcji emisji dwutlenku węgla przewidzianej do 2050 roku [3]. Zastosowanie jej napotyka na wiele barier, nie tylko technologicznych i ekonomicznych, ale także społecznych. Inną metodą dającą ujemne źródło emisji CO2 jest możliwość wykorzystania obszarów leśnych o odpowiedniej strukturze drzewostanu. Środkiem do tego celu, oprócz ograniczenia zużycia emisjogennych paliw kopalnych (przy zachowaniu zasad zrównoważonego rozwoju może być intensyfikacja zalesień. Zwiększanie lesistości i prawidłowa gospodarka leśna należy do najbardziej efektywnych sposobów kompensowania

  2. Diffuse soil CO_2 degassing from Linosa island

    Directory of Open Access Journals (Sweden)

    Dario Cellura

    2014-06-01

    Full Text Available Normal 0 14 false false false MicrosoftInternetExplorer4 Normal 0 14 false false false IT X-NONE X-NONE MicrosoftInternetExplorer4 Herein, we present and discuss the result of 148 measurements of soil CO2 flux performed for the first time in Linosa island (Sicily Channel, Italy, a Plio-Pleistocene volcanic complex no longer active but still of interest owing to its location within a seismically active portion of the Sicily Channel rift system. The main purpose of this survey was to assess the occurrence of CO2 soil degassing, and compare flux estimations from this island with data of soil degassing from worldwide active volcanic as well as non-volcanic areas. To this aim soil CO2 fluxes were measured over a surface of about 4.2 km2 covering ~80% of the island. The soil CO2 degassing was observed to be mainly concentrated in the eastern part of the island likely due to volcano-tectonic lineaments, the presence of which is in good agreement with the known predominant regional faults system. Then, the collected data were interpreted using sequential Gaussian simulation that allowed estimating the total CO2 emissions of the island. Results show low levels of CO2 emissions from the soil of the island (~55 ton d-1 compared with CO2 emissions of currently active volcanic areas, such as Miyakejima (Japan and Vulcano (Italy. Results from this study suggest that soil degassing in Linosa is mainly fed by superficial organic activity with a moderate contribution of a deep CO2 likely driven by NW-SE trending active tectonic structures in the eastern part of the island.

  3. Geoelectric Monitoring of geological CO2 storage at Ketzin, Germany (CO2SINK project): Downhole and Surface-Downhole measurements

    Science.gov (United States)

    Kiessling, D.; Schuett, H.; Schoebel, B.; Krueger, K.; Schmidt-Hattenberger, C.; Schilling, F.

    2009-04-01

    Numerical models of the CO2 storage experiment CO2SINK (CO2 Storage by Injection into a Natural Saline Aquifer at Ketzin), where CO2 is injected into a deep saline aquifer at roughly 650 m depth, yield a CO2 saturation of approximately 50% for large parts of the plume. Archie's equation predicts an increase of the resistivity by a factor of approximately 3 to 4 for the reservoir sandstone, and laboratory tests on Ketzin reservoir samples support this prediction. Modeling results show that tracking the CO2 plume may be doable with crosshole resistivity surveys under these conditions. One injection well and two observation wells were drilled in 2007 to a depth of about 800 m and were completed with "smart" casings, arranged L-shaped with distances of 50 m and 100 m. 45 permanent ring-shaped steel electrodes were attached to the electrically insulated casings of the three Ketzin wells at 590 m to 735 m depth with a spacing of about 10 m. It is to our knowledge the deepest permanent vertical electrical resistivity array (VERA) worldwide. The electrodes are connected to the current power supply and data registration units at the surface through custom-made cables. This deep electrode array allows for the registration of electrical resistivity tomography (ERT) data sets at basically any desired repetition rate and at very low cost, without interrupting the injection operations. The installation of all 45 electrodes succeeded. The electrodes are connected to the electrical cable, and the insulated casing stood undamaged. Even after 2-odd years under underground conditions only 6 electrodes are in a critical state now, caused by corrosion effects. In the framework of the COSMOS project (CO2-Storage, Monitoring and Safety Technology), supported by the German "Geotechnologien" program, the geoelectric monitoring has been performed. The 3D crosshole time-laps measurements are taken using dipole-dipole configurations. The data was inverted using AGI EarthImager 3D to obtain 3D

  4. A global CO2 tax for sustainable development?

    DEFF Research Database (Denmark)

    Brandt, Urs Steiner; Svendsen, Gert Tinggaard

    2014-01-01

    The Rio+20 conference in 2012 called for goals of promoting green industries and improving the quality of institutions worldwide. Is a global CO2 tax the best global solution for achieving this twin goal? As most countries in the world are highly corrupt, an adequate regulatory instrument should...... be able to work in a simple way that does not rely on strong formal institutions for enforcement. We argue that this is the case for a global CO2 tax. A uniform CO2 tax can be introduced as a “painted” energy tax that provides the needed incentive to switch from brown to green industries and minimizes...... the risk of carbon leakage. The achievement of the specific 2-degree target level is discussed as an example implying huge tax revenues that may be invested in better institutions. In perspective, the idea of having one instrument solving one problem will probably ease forthcoming political discussions...

  5. The Myth in the Discourse.

    Science.gov (United States)

    Breen, Myles; Corcoran, Farrel

    Reflecting the ideas of Roland Barthes, this paper examines the nature and importance of myth as a type of speech. The investigation proceeds by discussing myth from the perspectives of both traditional and contemporary disciplines, then considers the universality of myth, its religious impulse, and its functions. Using examples from television…

  6. Teachers' Strikes: Maxims or Myths.

    Science.gov (United States)

    Shreeve, William; And Others

    Seven commonly held myths concerning the effects of teachers' strikes on school districts are explored. Administrators from 124 school districts that experienced teacher strikes during the three-year period 1981-1984 responded to a questionnaire about the seven myths. The myths discussed include: (1) superintendents leave districts as a result of…

  7. Rising CO2 levels will intensify phytoplankton blooms in eutrophic and hypertrophic lakes

    NARCIS (Netherlands)

    Verspagen, J.M.H.; van de Waal, D.B.; Finke, J.F.; Visser, P.M.; van Donk, E.; Huisman, J.

    2014-01-01

    Harmful algal blooms threaten the water quality of many eutrophic and hypertrophic lakes and cause severe ecological and economic damage worldwide. Dense blooms often deplete the dissolved CO2 concentration and raise pH. Yet, quantitative prediction of the feedbacks between phytoplankton growth, CO2

  8. Amine based solvent for CO2 absorption. From molecular structure to process.

    NARCIS (Netherlands)

    Singh, P.

    2011-01-01

    Global warming is a well-known, worldwide concern, most probably caused by increasing concentrations of CO2 and other greenhouse gases in the earth’s atmosphere, due to human activities. Carbon Capture and Storage (CCS) offers the opportunity to reduce the CO2 emissions associated with the use of

  9. Passive CO2 concentration in higher plants.

    Science.gov (United States)

    Sage, Rowan F; Khoshravesh, Roxana

    2016-06-01

    Photorespiratory limitations on C3 photosynthesis are substantial in warm, low CO2 conditions. To compensate, certain plants evolved mechanisms to actively concentrate CO2 around Rubisco using ATP-supported CO2 pumps such as C4 photosynthesis. Plants can also passively accumulate CO2 without additional ATP expenditure by localizing the release of photorespired and respired CO2 around Rubisco that is diffusively isolated from peripheral air spaces. Passive accumulation of photorespired CO2 occurs when glycine decarboxylase is localized to vascular sheath cells in what is termed C2 photosynthesis, and through forming sheaths of chloroplasts around the periphery of mesophyll cells. The peripheral sheaths require photorespired CO2 to re-enter chloroplasts where it can be refixed. Passive accumulation of respiratory CO2 is common in organs such as stems, fruits and flowers, due to abundant heterotrophic tissues and high diffusive resistance along the organ periphery. Chloroplasts within these organs are able to exploit this high CO2 to reduce photorespiration. CO2 concentration can also be enhanced passively by channeling respired CO2 from roots and rhizomes into photosynthetic cells of stems and leaves via lacunae, aerenchyma and the xylem stream. Through passive CO2 concentration, C3 species likely improved their carbon economy and maintained fitness during episodes of low atmospheric CO2. Copyright © 2016 Elsevier Ltd. All rights reserved.

  10. Rapid adaptation of harmful cyanobacteria to rising CO2.

    Science.gov (United States)

    Sandrini, Giovanni; Ji, Xing; Verspagen, Jolanda M H; Tann, Robert P; Slot, Pieter C; Luimstra, Veerle M; Schuurmans, J Merijn; Matthijs, Hans C P; Huisman, Jef

    2016-08-16

    Rising atmospheric CO2 concentrations are likely to affect many ecosystems worldwide. However, to what extent elevated CO2 will induce evolutionary changes in photosynthetic organisms is still a major open question. Here, we show rapid microevolutionary adaptation of a harmful cyanobacterium to changes in inorganic carbon (Ci) availability. We studied the cyanobacterium Microcystis, a notorious genus that can develop toxic cyanobacterial blooms in many eutrophic lakes and reservoirs worldwide. Microcystis displays genetic variation in the Ci uptake systems BicA and SbtA, where BicA has a low affinity for bicarbonate but high flux rate, and SbtA has a high affinity but low flux rate. Our laboratory competition experiments show that bicA + sbtA genotypes were favored by natural selection at low CO2 levels, but were partially replaced by the bicA genotype at elevated CO2 Similarly, in a eutrophic lake, bicA + sbtA strains were dominant when Ci concentrations were depleted during a dense cyanobacterial bloom, but were replaced by strains with only the high-flux bicA gene when Ci concentrations increased later in the season. Hence, our results provide both laboratory and field evidence that increasing carbon concentrations induce rapid adaptive changes in the genotype composition of harmful cyanobacterial blooms.

  11. The CO2 emission registries; De CO2 registers

    Energy Technology Data Exchange (ETDEWEB)

    De Witt Wijnen, H.R. [De Brauw Blackstone Westbroek, Den Haag (Netherlands)

    2004-02-01

    The European Commission has made a first draft available of the Regulation for a standardized and secured system of CO2 -emissions registries. Transactions under the European emissions trading scheme will be settled in accordance with the rules of this Regulation. This article gives a summary of the Regulation and describes the way emissions transactions are going to take place. Any person can open an account in an emissions register. The relation between the Kyoto Protocol and the Regulation is discussed, such as the role of the Commitment Period Reserve. Emission Reductions will not qualify as registered goods under Dutch law, as information on individual accounts will not be made public. [Dutch] Begin november van het vorig jaar heeft de Europese Commissie een concept voor commentaar laten circuleren van een verordening inzake een gestandaardiseerd en beveiligd stelsel van registers (de 'Register Verordening'). Aangezien er op dit moment hard gewerkt wordt aan een wijziging van de Wet milieubeheer in verband met de invoering van een hoofdstuk inzake de handel in emissierechten, lijkt het nuttig om de Register Verordening thans al te bespreken. De Wet milieubeheer zal de Register Verordening hebben te volgen. Bovendien zal kennismaking met de Register Verordening het begrip voor de beoogde werking van de toekomstige Europese emissiehandel vergroten. In dit artikel is mede gebruik gemaakt van wetenswaardigheden opgedaan tijdens een bijeenkomst met de opstellers van de Register Verordening in november 2003.

  12. Hair Loss Myths.

    Science.gov (United States)

    DiMarco, Gabriella; McMichael, Amy

    2017-07-01

    INTRODUCTION: Hair loss is a common complaint seen in dermatology clinics. From frustration and attempts at self-help, patients with hair loss may present to the dermatologist with false beliefs, or myths, about the causes of their condition and what treatments are effective. METHODS: We identified 12 common myths about hair loss, categorized as myths about minoxidil treatment, vitamin and mineral supplements, natural topical treatments, and hair care practices. We performed a PubMed search to find evidence to support or refute each myth. RESULTS: We found that there is little evidence to support many of these common hair loss myths. In some cases, randomized controlled trials have investigated the effects of particular therapies and point to the effectiveness of certain hair loss treatments. DISCUSSION: In many cases, there have not been sufficient randomized controlled trials to evaluate the effect of different therapies and hair care practices on hair loss. It is best to guide patients toward treatments with a long track record of efficacy and away from those where little is known scientifically. J Drugs Dermatol. 2017;16(7):690-694..

  13. The ins and outs of CO2

    National Research Council Canada - National Science Library

    Raven, John A; Beardall, John

    2016-01-01

    ...; this article examines what is known and where there are gaps in knowledge. Irreversible decarboxylases produce CO2, and CO2 is the substrate/product of enzymes that act as carboxylases and decarboxylases...

  14. ISLSCP II Globalview: Atmospheric CO2 Concentrations

    Data.gov (United States)

    National Aeronautics and Space Administration — The GlobalView Carbon Dioxide (CO2) data product contains synchronized and smoothed time series of atmospheric CO2 concentrations at selected sites that were created...

  15. CO2 Capture for Cement Technology

    DEFF Research Database (Denmark)

    Pathi, Sharat Kumar

    Production of cement is an energy intensive process and is the source of considerable CO2emissions. Itis estimated that the cement industry contributes around 8% of total global CO2emissions. CO2is oneof the major greenhouse gases. In the atmosphere, the CO2concentration has increased from 310...... ppmvin 1960 to 390 ppmv in 2012, probably due to human activity. A lot of research is being carried out forreducing CO2emissions from large stationary sources. Ofwhich, the carbonate looping process is anew process and has the potential to reduce CO2emissions with lower energy penalties. Most of thework...... performed recently has focused on CO2capture from fossil fuel-based power plants. Inherently,this process is especially suitablefor cement plants, as CaO used for CO2capture is also a majoringredient for clinker production. Thus, a detailed investigation was carried outto study the applicationof...

  16. CO2 Virtual Science Data Environment API

    Data.gov (United States)

    National Aeronautics and Space Administration — The CO2 Virtual Data Environment is a comprehensive effort at bringing together the models, data, and tools necessary to perform research on atmospheric CO2.This...

  17. ISLSCP II Globalview: Atmospheric CO2 Concentrations

    Data.gov (United States)

    National Aeronautics and Space Administration — ABSTRACT: The GlobalView Carbon Dioxide (CO2) data product contains synchronized and smoothed time series of atmospheric CO2 concentrations at selected sites that...

  18. Response of microalgae to elevated CO2 and temperature: impact of climate change on freshwater ecosystems.

    Science.gov (United States)

    Li, Wei; Xu, Xiaoguang; Fujibayashi, Megumu; Niu, Qigui; Tanaka, Nobuyuki; Nishimura, Osamu

    2016-10-01

    To estimate the combined effects of elevated CO2 and temperature on microalgae, three typical and worldwide freshwater species, the green alga Scenedesmus acuminatus, the diatom Cyclotella meneghiniana, and the cyanobacterium Microcystis aeruginosa, as well as mixes of these three species were continuously cultured in controlled environment chambers with CO2 at 390 and 1000 ppm and temperatures of 20, 25, and 30 °C. CO2 and temperature significantly affected the production of microalgae. The cell productivity increased under elevated CO2 and temperature. Although the green alga dominated in the mixed culture within all CO2 and temperature conditions, rising temperature and CO2 intensified the competition of the cyanobacterium with other microalgae. CO2 affected the extracellular polymeric substances (EPS) characteristics of the green alga and the cyanobacterium. Elevated CO2 induced the generation of humic substances in the EPS fractions of the green alga, the cyanobacterium, and the mixed culture. The extracellular carbohydrates of the diatom and the extracellular proteins of the cyanobacterium increased with elevated CO2 and temperature, while the extracellular carbohydrates and proteins of the green alga and the mixes increased under elevated CO2 and temperature. There were synergistic effects of CO2 and temperature on the productivity and the EPS of microalgae. Climate change related CO2 and temperature increases will promote autochthonous organic carbon production in aquatic ecosystems and facilitate the proliferation of cyanobacteria, which potentially changes the carbon cycling and undermines the functioning of ecosystems.

  19. Carbon Dioxide (CO2) in Blood

    Science.gov (United States)

    ... https://medlineplus.gov/labtests/carbondioxideco2inblood.html Carbon Dioxide (CO2) in Blood To use the sharing features on ... please enable JavaScript. What is a Carbon Dioxide (CO2) Blood Test? Carbon dioxide (CO2) is an odorless, ...

  20. Prognose CO2-emissie glastuinbouw 2020

    NARCIS (Netherlands)

    Velden, van der Nico; Smit, Pepijn

    2016-01-01

    The greenhouse horticulture sector and government agreed in a covenant on a CO2 emission budget
    for 2020. It appeared that the 2014 CO2 emissions were considerably lower than this CO2 emission
    budget. The covenant signatories also agreed that an interim evaluation would be carried out

  1. Seven Myths about Beginners' Language

    DEFF Research Database (Denmark)

    Lund, Karen; Kirkebæk, Mads Jakob

    2015-01-01

    ) the myth about ‘the only thing’ (the method), (4) the myth about “we tried that before”, (5) the myth about “one people and one teaching method, (6) the myth about easy and difficult languages, and (7) the myth about students with no competences and a worthless past. The article suggests language teachers...... to use a ‘myth-detector’ to detect, reflect on and possibly reject myths they may meet in their profession. The ‘myth-detector’ consists of four simple questions, namely (1) Where do we know it from? (2) What is it built on? (3) What views on learning, language and culture lie behind? and (4) Who (gets......In the article the authors have selected seven myths about beginners’ language for discussion, reflection and possible rejection. These are (1) the myth about the necessity of mastering the system before being able to speak the language, (2) the myth about limited capacity on the ‘hard disc’, (3...

  2. Forest succession at elevated CO2

    Energy Technology Data Exchange (ETDEWEB)

    Clark, James S.; Schlesinger, William H.

    2002-02-01

    We tested hypotheses concerning the response of forest succession to elevated CO2 in the FACTS-1 site at the Duke Forest. We quantified growth and survival of naturally recruited seedlings, tree saplings, vines, and shrubs under ambient and elevated CO2. We planted seeds and seedlings to augment sample sites. We augmented CO2 treatments with estimates of shade tolerance and nutrient limitation while controlling for soil and light effects to place CO2 treatments within the context of natural variability at the site. Results are now being analyzed and used to parameterize forest models of CO2 response.

  3. Marketing the Count's way: how Dracula's myth can revive Romanian tourism

    Directory of Open Access Journals (Sweden)

    Adina Nicoleta CANDREA

    2016-07-01

    Full Text Available Tourism destinations associated with the place myth phenomena often experience increased visitation and marketing opportunities. Considering the popularity of the Dracula myth worldwide, Romania has a great opportunity to improve its image as a unique destination on the international tourism market. Thus, the present study aims to analyze the exploitation of the Dracula myth in the Romanian tourism context, as well as the managerial and marketing implications of such an approach. It begins with an overview of the imaginary and historical links between Romania and the Dracula myth. Further on, it reviews the national initiatives to develop Dracula tourism, from both private and governmental perspectives. The paper concludes by highlighting the opportunities of developing Dracula tourism in Romania and embracing the Dracula myth as a unique competitive advantage of the country as a tourism destination.

  4. CO2 clearance by membrane lungs.

    Science.gov (United States)

    Sun, Liqun; Kaesler, Andreas; Fernando, Piyumindri; Thompson, Alex J; Toomasian, John M; Bartlett, Robert H

    2017-10-01

    Commercial membrane lungs are designed to transfer a specific amount of oxygen per unit of venous blood flow. Membrane lungs are much more efficient at removing CO2 than adding oxygen, but the range of CO2 transfer is rarely reported. Commercial membrane lungs were studied with the goal of evaluating CO2 removal capacity. CO2 removal was measured in 4 commercial membrane lungs under standardized conditions. CO2 clearance can be greater than 4 times that of oxygen at a given blood flow when the gas to blood flow ratio is elevated to 4:1 or 8:1. The CO2 clearance was less dependent on surface area and configuration than oxygen transfer. Any ECMO system can be used for selective CO2 removal.

  5. Extraction of stevia glycosides with CO2 + water, CO2 + ethanol, and CO2 + water + ethanol

    Directory of Open Access Journals (Sweden)

    A. Pasquel

    2000-09-01

    Full Text Available Stevia leaves are an important source of natural sugar substitute. There are some restrictions on the use of stevia extract because of its distinctive aftertaste. Some authors attribute this to soluble material other than the stevia glycosides, even though it is well known that stevia glycosides have to some extent a bitter taste. Therefore, the purpose of this work was to develop a process to obtain stevia extract of a better quality. The proposed process includes two steps: i Pretreatment of the leaves by SCFE; ii Extraction of the stevia glycosides by SCFE using CO2 as solvent and water and/or ethanol as cosolvent. The mean total yield for SCFE pretreatment was 3.0%. The yields for SCFE with cosolvent of stevia glycosides were below 0.50%, except at 120 bar, 16°C, and 9.5% (molar of water. Under this condition, total yield was 3.4%. The quality of the glycosidic fraction with respect to its capacity as sweetener was better for the SCFE extract as compared to extract obtained by the conventional process. The overall extraction curves were well described by the Lack extended model.

  6. Myths in test automation

    Directory of Open Access Journals (Sweden)

    Jazmine Francis

    2015-01-01

    Full Text Available Myths in automation of software testing is an issue of discussion that echoes about the areas of service in validation of software industry. Probably, the first though that appears in knowledgeable reader would be Why this old topic again? What's New to discuss the matter? But, for the first time everyone agrees that undoubtedly automation testing today is not today what it used to be ten or fifteen years ago, because it has evolved in scope and magnitude. What began as a simple linear scripts for web applications today has a complex architecture and a hybrid framework to facilitate the implementation of testing applications developed with various platforms and technologies. Undoubtedly automation has advanced, but so did the myths associated with it. The change in perspective and knowledge of people on automation has altered the terrain. This article reflects the points of views and experience of the author in what has to do with the transformation of the original myths in new versions, and how they are derived; also provides his thoughts on the new generation of myths.

  7. Between myth and reality

    DEFF Research Database (Denmark)

    Hyldegård, Jette

    2010-01-01

    in an educational practice. The research on young people’s information behaviour by Rowlands et al. was carried out in 2007. To determine whether the picture of the Google generation is consistent with reality a number of the myths investigated in 2007 were explored among 43 Danish secondary school pupils in 2009...

  8. More Myths of Migration.

    Science.gov (United States)

    Basch, Linda; Lerner, Gail

    1986-01-01

    Challenges "myths" about women and migration, including (1) the causes of migration are economic, not racism; (2) migrant women receive support from feminist groups and trade unions; (3) transnational corporations are positive forces in developing nations; (4) migration today has little impact on family life; and (5) most migrants cluster in…

  9. The Myth about Einstien

    Indian Academy of Sciences (India)

    Home; Journals; Resonance – Journal of Science Education; Volume 11; Issue 1. The Myth about Einstien. Sushanta Dattagupta. General Article Volume 11 Issue 1 January 2006 pp 63-78. Fulltext. Click here to view fulltext PDF. Permanent link: http://www.ias.ac.in/article/fulltext/reso/011/01/0063-0078. Keywords.

  10. Diet myths and facts

    Science.gov (United States)

    ... yourself to healthy snacks such as low-fat yogurt or baby carrots. MYTH? You cannot be overweight and healthy. FACT: There are some people who are overweight with healthy blood pressure, cholesterol, and blood sugar levels. For most people, excess ...

  11. CO2 flux from Javanese mud volcanism

    Science.gov (United States)

    Queißer, M.; Burton, M. R.; Arzilli, F.; Chiarugi, A.; Marliyani, G. I.; Anggara, F.; Harijoko, A.

    2017-06-01

    Studying the quantity and origin of CO2 emitted by back-arc mud volcanoes is critical to correctly model fluid-dynamical, thermodynamical, and geochemical processes that drive their activity and to constrain their role in the global geochemical carbon cycle. We measured CO2 fluxes of the Bledug Kuwu mud volcano on the Kendeng Fold and thrust belt in the back arc of Central Java, Indonesia, using scanning remote sensing absorption spectroscopy. The data show that the expelled gas is rich in CO2 with a volume fraction of at least 16 vol %. A lower limit CO2 flux of 1.4 kg s-1 (117 t d-1) was determined, in line with the CO2 flux from the Javanese mud volcano LUSI. Extrapolating these results to mud volcanism from the whole of Java suggests an order of magnitude total CO2 flux of 3 kt d-1, comparable with the expected back-arc efflux of magmatic CO2. After discussing geochemical, geological, and geophysical evidence we conclude that the source of CO2 observed at Bledug Kuwu is likely a mixture of thermogenic, biogenic, and magmatic CO2, with faulting controlling potential pathways for magmatic fluids. This study further demonstrates the merit of man-portable active remote sensing instruments for probing natural gas releases, enabling bottom-up quantification of CO2 fluxes.

  12. CO2 flux from Javanese mud volcanism.

    Science.gov (United States)

    Queißer, M; Burton, M R; Arzilli, F; Chiarugi, A; Marliyani, G I; Anggara, F; Harijoko, A

    2017-06-01

    Studying the quantity and origin of CO2 emitted by back-arc mud volcanoes is critical to correctly model fluid-dynamical, thermodynamical, and geochemical processes that drive their activity and to constrain their role in the global geochemical carbon cycle. We measured CO2 fluxes of the Bledug Kuwu mud volcano on the Kendeng Fold and thrust belt in the back arc of Central Java, Indonesia, using scanning remote sensing absorption spectroscopy. The data show that the expelled gas is rich in CO2 with a volume fraction of at least 16 vol %. A lower limit CO2 flux of 1.4 kg s-1 (117 t d-1) was determined, in line with the CO2 flux from the Javanese mud volcano LUSI. Extrapolating these results to mud volcanism from the whole of Java suggests an order of magnitude total CO2 flux of 3 kt d-1, comparable with the expected back-arc efflux of magmatic CO2. After discussing geochemical, geological, and geophysical evidence we conclude that the source of CO2 observed at Bledug Kuwu is likely a mixture of thermogenic, biogenic, and magmatic CO2, with faulting controlling potential pathways for magmatic fluids. This study further demonstrates the merit of man-portable active remote sensing instruments for probing natural gas releases, enabling bottom-up quantification of CO2 fluxes.

  13. Porous Organic Polymers for CO2 Capture

    KAUST Repository

    Teng, Baiyang

    2013-05-01

    Carbon dioxide (CO2) has long been regarded as the major greenhouse gas, which leads to numerous negative effects on global environment. The capture and separation of CO2 by selective adsorption using porous materials proves to be an effective way to reduce the emission of CO2 to atmosphere. Porous organic polymers (POPs) are promising candidates for this application due to their readily tunable textual properties and surface functionalities. The objective of this thesis work is to develop new POPs with high CO2 adsorption capacities and CO2/N2 selectivities for post-combustion effluent (e.g. flue gas) treatment. We will also exploit the correlation between the CO2 capture performance of POPs and their textual properties/functionalities. Chapters Two focuses on the study of a group of porous phenolic-aldehyde polymers (PPAPs) synthesized by a catalyst-free method, the CO2 capture capacities of these PPAPs exceed 2.0 mmol/g at 298 K and 1 bar, while keeping CO2/N2 selectivity of more than 30 at the same time. Chapter Three reports the gas adsorption results of different hyper-cross-linked polymers (HCPs), which indicate that heterocyclo aromatic monomers can greatly enhance polymers’ CO2/N2 selectivities, and the N-H bond is proved to the active CO2 adsorption center in the N-contained (e.g. pyrrole) HCPs, which possess the highest selectivities of more than 40 at 273 K when compared with other HCPs. Chapter Four emphasizes on the chemical modification of a new designed polymer of intrinsic microporosity (PIM) with high CO2/N2 selectivity (50 at 273 K), whose experimental repeatability and chemical stability prove excellent. In Chapter Five, we demonstrate an improvement of both CO2 capture capacity and CO2/N2 selectivity by doping alkali metal ions into azo-polymers, which leads a promising method to the design of new porous organic polymers.

  14. Metal-Organic Framework-Stabilized CO2/Water Interfacial Route for Photocatalytic CO2Conversion.

    Science.gov (United States)

    Luo, Tian; Zhang, Jianling; Li, Wei; He, Zhenhong; Sun, Xiaofu; Shi, Jinbiao; Shao, Dan; Zhang, Bingxing; Tan, Xiuniang; Han, Buxing

    2017-11-29

    Here, we propose a CO 2 /water interfacial route for photocatalytic CO 2 conversion by utilizing a metal-organic framework (MOF) as both an emulsifier and a catalyst. The CO 2 reduction occurring at the CO 2 /water interface produces formate with remarkably enhanced efficiency as compared with that in conventional solvent. The route is efficient, facile, adjustable, and environmentally benign, which is applicable for the CO 2 transformation photocatalyzed by different kinds of MOFs.

  15. Urine as a CO2 absorbent.

    Science.gov (United States)

    Aguilar, Manuel Jiménez

    2012-04-30

    The aim of this work was to investigate the effect of urine on the absorption of greenhouse gases such as CO(2). Human urine diluted with olive-oil-mill wastewaters (OMW) could be used to capture CO(2) from flue gas of coal-fired power plant and convert CO(2) emissions into valuable fertilizers (mainly, NH(4)HCO(3)) that can enhance CO(2) sequestration into soil and subsoil layers. Thus, the CO(2) emissions could be reduced between 0.1 and 1%. The proposed strategy requires further research to increase CO(2) absorption and assess the risks associated with wastewater reuse and xenobiotics in the agroecological environment. Copyright © 2012 Elsevier B.V. All rights reserved.

  16. CO2 Capture by Cement Raw Meal

    DEFF Research Database (Denmark)

    Pathi, Sharat Kumar; Lin, Weigang; Illerup, Jytte Boll

    2013-01-01

    The cement industry is one of the major sources of CO2 emissions and is likely to contribute to further increases in the near future. The carbonate looping process has the potential to capture CO2 emissions from the cement industry, in which raw meal for cement production could be used...... as the sorbent. Cyclic experiments were carried out in a TGA apparatus using industrial cement raw meal and synthetic raw meal as sorbents, with limestone as the reference. The results show that the CO2 capture capacities of the cement raw meal and the synthetic raw meal are comparable to those of pure limestone....... The CO2 capture capacity of limestone in the raw meal is lower than for pure limestone. The difference in the CO2 capture capacity decreases with an increase in cycle number. The calcination conditions and composition are major factors that influence the CO2 capture capacity of limestone. At 850 °C in N2...

  17. Advanced technology development reducing CO2 emissions

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Dong Sup

    2010-09-15

    Responding to Korean government policies on green growth and global energy/ environmental challenges, SK energy has been developing new technologies to reduce CO2 emissions by 1) CO2 capture and utilization, 2) efficiency improvement, and 3) Li-ion batteries. The paper introduces three advanced technologies developed by SK energy; GreenPol, ACO, and Li-ion battery. Contributing to company vision, a more energy and less CO2, the three technologies are characterized as follows. GreenPol utilizes CO2 as a feedstock for making polymer. Advanced Catalytic Olefin (ACO) reduces CO2 emission by 20% and increase olefin production by 17%. Li-ion Batteries for automotive industries improves CO2 emission.

  18. CO2 Hydration Shell Structure and Transformation.

    Science.gov (United States)

    Zukowski, Samual R; Mitev, Pavlin D; Hermansson, Kersti; Ben-Amotz, Dor

    2017-07-06

    The hydration-shell of CO2 is characterized using Raman multivariate curve resolution (Raman-MCR) spectroscopy combined with ab initio molecular dynamics (AIMD) vibrational density of states simulations, to validate our assignment of the experimentally observed high-frequency OH band to a weak hydrogen bond between water and CO2. Our results reveal that while the hydration-shell of CO2 is highly tetrahedral, it is also occasionally disrupted by the presence of entropically stabilized defects associated with the CO2-water hydrogen bond. Moreover, we find that the hydration-shell of CO2 undergoes a temperature-dependent structural transformation to a highly disordered (less tetrahedral) structure, reminiscent of the transformation that takes place at higher temperatures around much larger oily molecules. The biological significance of the CO2 hydration shell structural transformation is suggested by the fact that it takes place near physiological temperatures.

  19. Bosch - An alternate CO2 reduction technology

    Science.gov (United States)

    Heppner, D. B.; Hallick, T. M.; Clark, D. C.; Quattrone, P. D.

    1979-01-01

    The Bosch process is the most promising CO2 reduction concept for future prolonged space missions. The paper presents the design of a three-person-capacity preprototype B-CRS (Bosch-based CO2 Reduction Subsystem). It is sized to reduce 3.0 kg/d CO2 generated by the crew and to supply the product water to an O2 generation subsystem to obtain O2. The design supports future development of the B-CRS as an alternative CO2 reduction subsystem to the Sabatier-based process presently under test at NASA. The discussion covers the Bosch CO2 reduction concept, process and hardware description, performance parameters, design specifications, subsystem schematic and operation, mechanical subsystem summary, control/monitor instrumentation, and subsystem packaging. A B-CRS with a proven technological base is an attractive CO2 reduction subsystem that eliminates overboard venting.

  20. [Modernity in dreams and myths].

    Science.gov (United States)

    Scopelliti, Paolo

    2009-01-01

    The very presence of myths in psychoanalysis raises questions about their scientific status: that leads to reconsider the whole issue of Freudian mythology in a non-medical manner, by envisaging it in the more general context of modern myths, both political and artistic. Special attention is then paid to Surrealism, as the only avant-garde movement at the same time focused on psychoanalysis and politics: the role played by dreams in foundering myths is examined in both Surrealism and psychoanalysis. Surrealistic myths, such as Dalí's Grand Paranoïaque Comestible, finally prove to be so non-oedipian as the Nazi Ubermensch myth; nevertheless, their comparison with Freudian mythology points out their common origin, as they all fulfilled the need of the mass society for a modern myth, able to express his deeply renewed self-awareness.

  1. CO2 Activation over Catalytic Surfaces.

    Science.gov (United States)

    Álvarez, Andrea; Borges, Marta; Corral-Pérez, Juan José; Olcina, Joan Giner; Hu, Lingjun; Cornu, Damien; Huang, Rui; Stoian, Dragos; Urakawa, Atsushi

    2017-11-17

    This article describes the main strategies to activate and convert carbon dioxide (CO2 ) into valuable chemicals over catalytic surfaces. Coherent elements such as common intermediates are identified in the different strategies and concisely discussed based on the reactivity of CO2 with the aim to understand the decisive factors for selective and efficient CO2 conversion. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  2. CO2 Allowance and Electricity Price Interaction

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2007-07-01

    With the introduction of CO2 emission constraints on power generators in the European Union, climate policy is starting to have notable effects on energy markets. This paper sheds light on the links between CO2 prices, electricity prices, and electricity costs to industry. It is based on a series of interviews with industrial and electricity stakeholders, as well as a rich literature seeking to estimate the exact effect of CO2 prices on electricity prices.

  3. The impact of elevated CO2 concentrations on soil microbial community, soil organic matter storage and nutrient cycling at a natural CO2 vent in NW Bohemia

    Science.gov (United States)

    Nowak, Martin; Beulig, Felix; von Fischer, Joe; Muhr, Jan; Kuesel, Kirsten; Trumbore, Susan

    2014-05-01

    Natural CO2 vents or 'mofettes' are diffusive or advective exhalations of geogenic CO2 from soils. These structures occur at several places worldwide and in most cases they are linked to volcanic activity. Characteristic for mofette soils are high CO2 concentrations of up to more than 90% as well as a lack of oxygen, low pH values and reducing conditions. Mofette soils usually are considered to be sites of carbon accumulation, which is not only due to the absence of oxygen, but might also result from lower plant litter quality due to CO2 fertilization of CO2 influenced plants and reduced availability of N and P for the decomposer community. Furthermore, fermentation processes and the formation of reduced elements by anoxic decomposition might fuel chemo-lithoautotrophic or mixotrophic microbial CO2 uptake, a process which might have important ecological functions by closing internal element cycles, formation of trace gasses as well as by re-cycling and storing of carbon. Several studies of microbial community structure revealed a shift towards CO2 utilizing prokaryotes in moffete soils compared to a reference site. Here, we use combined stable and radiocarbon isotope data from mofette soils in NW Bohemia to quantify the contribution of geogenic CO2 to soil organic carbon formation within mofette soils, either resulting from plant litter or from microbial CO2 uptake. This is possible because the geogenic CO2 has a distinct isotopic signature (δ13C = -2 o Δ14C = -1000 ) that is very different from the isotopic signature of atmospheric CO2. First results show that mofette soils have a high Corg content (20 to 40 %) compared to a reference site (2 to 20 %) and soil organic matter is enriched in 13C as well as depleted in 14C. This indicates that geogenic CO2 is re-fixed and stored as SOM. In order to quantify microbial contribution to CO2 fixation and SOM storage, microbial CO2 uptake rates were determined by incubating mofette soils with 13CO2 labelled gas. The

  4. CO2 capture in different carbon materials.

    Science.gov (United States)

    Jiménez, Vicente; Ramírez-Lucas, Ana; Díaz, José Antonio; Sánchez, Paula; Romero, Amaya

    2012-07-03

    In this work, the CO(2) capture capacity of different types of carbon nanofibers (platelet, fishbone, and ribbon) and amorphous carbon have been measured at 26 °C as at different pressures. The results showed that the more graphitic carbon materials adsorbed less CO(2) than more amorphous materials. Then, the aim was to improve the CO(2) adsorption capacity of the carbon materials by increasing the porosity during the chemical activation process. After chemical activation process, the amorphous carbon and platelet CNFs increased the CO(2) adsorption capacity 1.6 times, whereas fishbone and ribbon CNFs increased their CO(2) adsorption capacity 1.1 and 8.2 times, respectively. This increase of CO(2) adsorption capacity after chemical activation was due to an increase of BET surface area and pore volume in all carbon materials. Finally, the CO(2) adsorption isotherms showed that activated amorphous carbon exhibited the best CO(2) capture capacity with 72.0 wt % of CO(2) at 26 °C and 8 bar.

  5. Global Mapping of CO2 on Enceladus

    Science.gov (United States)

    McCord, T. B.; Combe, J. P.; Matson, D.; Johnson, T. V.

    2014-12-01

    We present the first global map of CO2 on Enceladus. The purpose is to determine whether CO2 is associated to fractures and eruptions, and if it formed recently. Cassini observed tectonic features and plumes on Enceladus, which could be caused by a warm subsurface ocean containing dissolved gases. CO2 should be one of these gases (Postberg F. et al., Nature, 2009), and some of it should be erupted and condensed onto the surface (Matson et al., Icarus, 2012). Validation of this hypothesis could be done by determining the amount, location and molecular state of the CO2. Free CO2 ice and complexed CO2 were reported on Enceladus (Brown et al., Science, 2006; Hansen, LPSC, 2010) from analysis of Cassini Visual and Infrared Mapping Spectrometer (VIMS) data, and on other Saturn icy satellites (Cruikshank et al., Icarus, 2010 ; Filacchione et al., Icarus, 2010). Complexed CO2 has also been found from Galileo Near-Infrared Mapping Spectrometer (NIMS) spectra on the icy Galilean satellites (McCord et al., Science, 1997 and JGR, 1998), apparently due to both interior outgassing and radiation processing. CO2 has an asymmetric stretching mode that creates an absorption band, the wavelength position of which is sensitive to the nature of molecular associations between CO2 and their neighbors. Free CO2 ice absorbs at 4.268 μm for (Sandford and Allamandola, 1990) and CO2 complexed with other molecules absorbs at shorter wavelengths, around 4.25 μm or shorter (Chaban et al., Icarus, 2007). In VIMS spectra of Enceladus, this stretching mode absorption band is near the instrument detection limit. We utilized all VIMS data sets available that had significant spatial resolution to increase the statistics of the observations for any given location and improve the signal to noise. CO2 has also a smaller absorption at 2.7 μm, although it occurs in a range of wavelength that has higher signal-to-noise ratio by several magnitudes, because the surface of Enceladus (mostly H2O ice) has

  6. Large-scale CO2 storage — Is it feasible?

    Directory of Open Access Journals (Sweden)

    Johansen H.

    2013-06-01

    Full Text Available CCS is generally estimated to have to account for about 20% of the reduction of CO2 emissions to the atmosphere. This paper focuses on the technical aspects of CO2 storage, even if the CCS challenge is equally dependent upon finding viable international solutions to a wide range of economic, political and cultural issues. It has already been demonstrated that it is technically possible to store adequate amounts of CO2 in the subsurface (Sleipner, InSalah, Snøhvit. The large-scale storage challenge (several Gigatons of CO2 per year is more an issue of minimizing cost without compromising safety, and of making international regulations.The storage challenge may be split into 4 main parts: 1 finding reservoirs with adequate storage capacity, 2 make sure that the sealing capacity above the reservoir is sufficient, 3 build the infrastructure for transport, drilling and injection, and 4 set up and perform the necessary monitoring activities. More than 150 years of worldwide experience from the production of oil and gas is an important source of competence for CO2 storage. The storage challenge is however different in three important aspects: 1 the storage activity results in pressure increase in the subsurface, 2 there is no production of fluids that give important feedback on reservoir performance, and 3 the monitoring requirement will have to extend for a much longer time into the future than what is needed during oil and gas production. An important property of CO2 is that its behaviour in the subsurface is significantly different from that of oil and gas. CO2 in contact with water is reactive and corrosive, and may impose great damage on both man-made and natural materials, if proper precautions are not executed. On the other hand, the long-term effect of most of these reactions is that a large amount of CO2 will become immobilized and permanently stored as solid carbonate minerals. The reduced opportunity for direct monitoring of fluid samples

  7. Large-scale CO2 storage — Is it feasible?

    Science.gov (United States)

    Johansen, H.

    2013-06-01

    CCS is generally estimated to have to account for about 20% of the reduction of CO2 emissions to the atmosphere. This paper focuses on the technical aspects of CO2 storage, even if the CCS challenge is equally dependent upon finding viable international solutions to a wide range of economic, political and cultural issues. It has already been demonstrated that it is technically possible to store adequate amounts of CO2 in the subsurface (Sleipner, InSalah, Snøhvit). The large-scale storage challenge (several Gigatons of CO2 per year) is more an issue of minimizing cost without compromising safety, and of making international regulations.The storage challenge may be split into 4 main parts: 1) finding reservoirs with adequate storage capacity, 2) make sure that the sealing capacity above the reservoir is sufficient, 3) build the infrastructure for transport, drilling and injection, and 4) set up and perform the necessary monitoring activities. More than 150 years of worldwide experience from the production of oil and gas is an important source of competence for CO2 storage. The storage challenge is however different in three important aspects: 1) the storage activity results in pressure increase in the subsurface, 2) there is no production of fluids that give important feedback on reservoir performance, and 3) the monitoring requirement will have to extend for a much longer time into the future than what is needed during oil and gas production. An important property of CO2 is that its behaviour in the subsurface is significantly different from that of oil and gas. CO2 in contact with water is reactive and corrosive, and may impose great damage on both man-made and natural materials, if proper precautions are not executed. On the other hand, the long-term effect of most of these reactions is that a large amount of CO2 will become immobilized and permanently stored as solid carbonate minerals. The reduced opportunity for direct monitoring of fluid samples close to the

  8. The Myth of Data Rights

    Science.gov (United States)

    2015-11-01

    Defense AT&L: November–December 2015 46 The Myth of Data Rights Peter A. Czech Czech is a Professor of Program Management in the School of Program...following: What are data rights? How can we remove some of the myths surrounding them? What can we do if we don’t own the data rights? Before we answer...hand we want the best outcome or product for the pub- lic sector. Where does the myth of data rights originate? Myths The Merriam-Webster Diction

  9. Six dangerous myths about pay.

    Science.gov (United States)

    Pfeffer, J

    1998-01-01

    Every day, executives make decisions about pay, and they do so in a landscape that's shifting. As more and more companies base less of their compensation on straight salary and look to other financial options, managers are bombarded with advice about the best approaches to take. Unfortunately, much of that advice is wrong. Indeed, much of the conventional wisdom and public discussion about pay today is misleading, incorrect, or both. The result is that business people are adopting wrongheaded notions about how to pay people and why. In particular, they are subscribing to six dangerous myths about pay. Myth #1: labor rates are the same as labor costs. Myth #2: cutting labor rates will lower labor costs. Myth #3: labor costs represent a large portion of a company's total costs. Myth #4: keeping labor costs low creates a potent and sustainable competitive edge. Myth #5: individual incentive pay improves performance. Myth #6: people work primarily for the money. The author explains why these myths are so pervasive, shows where they go wrong, and suggests how leaders might think more productively about compensation. With increasing frequency, the author says, he sees managers harming their organizations by buying into--and acting on--these myths. Those that do, he warns, are probably doomed to endless tinkering with pay that at the end of the day will accomplish little but cost a lot.

  10. Experimental Ion Mobility measurements in Ne-CO$_2$ and CO$_2$-N$_2$ mixtures

    CERN Document Server

    Encarnação, P.M.C.C.; Veenhof, R.; Neves, P.N.B.; Santos, F.P.; Trindade, A.M.F.; Borges, F.I.G.M.; Conde, C.A.N.

    2016-01-01

    In this paper we present the experimental results for the mobility, K0, of ions in neon-carbon dioxide (Ne-CO2) and carbon dioxide-nitrogen (CO2-N2) gaseous mixtures for total pressures ranging from 8–12 Torr, reduced electric fields in the 10–25 Td range, at room temperature. Regarding the Ne-CO2 mixture only one peak was observed for CO2 concentrations above 25%, which has been identified as an ion originated in CO2, while below 25% of CO2 a second-small peak appears at the left side of the main peak, which has been attributed to impurities. The mobility values for the main peak range between 3.51 ± 0.05 and 1.07 ± 0.01 cm2V−1s−1 in the 10%-99% interval of CO2, and from 4.61 ± 0.19 to 3.00 ± 0.09 cm2V−1s−1 for the second peak observed (10%–25% of CO2). For the CO2-N2, the time-of-arrival spectra displayed only one peak for CO2 concentrations above 10%, which was attributed to ions originated in CO2, namely CO2+(CO2), with a second peak appearing for CO2 concentrations below 10%. This secon...

  11. Transcritical CO2-booster installations for supermarkets; Transkritische CO2-boosterinstallaties bij supermarkten

    Energy Technology Data Exchange (ETDEWEB)

    Berger, M. [ECR Nederland, Hoofddorp (Netherlands); Jongejans, D. [Assumburg Koeltechniek, Uitgeest (Netherlands)

    2010-11-15

    To meet the demand for CO2 installations, Assumburg Refrigeration cooperates with a Swedish partner (Green and Cool), which provides complete CO2 packs, including well-developed software. At the moment Green and Cool now has about one hundred and fifty stores equipped with a transcritical CO2 system. [Dutch] Om aan de vraag naar CO2-installaties te kunnen voldoen, werkt Assumburg Koeltechniekdaar samen met een Zweedse partner (Green and Cool), die complete CO2-packs levert, inclusief goed ontwikkelde software. Green and Cool heeft op dit moment al zo'n honderdvijftig winkels voorzien van een transkritische CO2-installatie.

  12. Drinking water microbial myths.

    Science.gov (United States)

    Allen, Martin J; Edberg, Stephen C; Clancy, Jennifer L; Hrudey, Steve E

    2015-01-01

    Accounts of drinking water-borne disease outbreaks have always captured the interest of the public, elected and health officials, and the media. During the twentieth century, the drinking water community and public health organizations have endeavored to craft regulations and guidelines on treatment and management practices that reduce risks from drinking water, specifically human pathogens. During this period there also evolved misunderstandings as to potential health risk associated with microorganisms that may be present in drinking waters. These misunderstanding or "myths" have led to confusion among the many stakeholders. The purpose of this article is to provide a scientific- and clinically-based discussion of these "myths" and recommendations for better ensuring the microbial safety of drinking water and valid public health decisions.

  13. More myths of migration.

    Science.gov (United States)

    Basch, L; Lerner, G

    1986-01-01

    This paper discusses some of the myths of migration. The 5 myths presented are: 1) racism has little to do with the causes of migration and does not necessarily impede the adjustment or success of migrants; 2) in areas where there is a strong feminist movement and trade unions, migrant women receive their support and can count on the solidarity of these organizations; 3) transnational corporations are positive forces in the developing countries where they operate--not only do they provide these states with new sources of capital, but they also impart new industrial skills to the labor force; 4) migration today is essentially short-term in nature--it therefore does not have a strong impact on family life; and 5) most migrants cluster together in ethnic enclaves which provide a strong source of support and diminish dislocation inherent in the migrant process.

  14. CO2 capture, transport, storage and utilisation

    NARCIS (Netherlands)

    Brouwer, J.H.

    2013-01-01

    Reducing CO2 emissions requires an integrated CO2 management approach. The dependency between the different industry sectors is higher than commonly acknowledged and covers all areas; capture, transport, storage and utilisation. TNO is one of Europe’s largest independent research organisations and

  15. Recent development of capture of CO2

    CERN Document Server

    Chavez, Rosa Hilda

    2014-01-01

    "Recent Technologies in the capture of CO2" provides a comprehensive summary on the latest technologies available to minimize the emission of CO2 from large point sources like fossil-fuel power plants or industrial facilities. This ebook also covers various techniques that could be developed to reduce the amount of CO2 released into the atmosphere. The contents of this book include chapters on oxy-fuel combustion in fluidized beds, gas separation membrane used in post-combustion capture, minimizing energy consumption in CO2 capture processes through process integration, characterization and application of structured packing for CO2 capture, calcium looping technology for CO2 capture and many more. Recent Technologies in capture of CO2 is a valuable resource for graduate students, process engineers and administrative staff looking for real-case analysis of pilot plants. This eBook brings together the research results and professional experiences of the most renowned work groups in the CO2 capture field...

  16. CO2 Capture with Enzyme Synthetic Analogue

    Energy Technology Data Exchange (ETDEWEB)

    Cordatos, Harry

    2010-11-08

    Overview of an ongoing, 2 year research project partially funded by APRA-E to create a novel, synthetic analogue of carbonic anhydrase and incorporate it into a membrane for removal of CO2 from flue gas in coal power plants. Mechanism background, preliminary feasibility study results, molecular modeling of analogue-CO2 interaction, and program timeline are provided.

  17. Membrane Technologies for CO2 Capture

    NARCIS (Netherlands)

    Simons-Fischbein, K.

    2010-01-01

    This thesis investigates the potential of membrane technology for the effective CO2/CH4 separation. The work focuses on two different membrane processes to accomplish the separation: 1) The use of a gas-liquid membrane contactor for the selective absorption of CO2 from CH4 2) The use of thin, dense

  18. CO2 capture research in the Netherlands

    NARCIS (Netherlands)

    Meerman, J.C.; Kuramochi, T.; Egmond, S. van

    2008-01-01

    The global climate is changing due to human activities. This human‑induced climate change is mainly caused by global emissions of carbon dioxide (CO2) into the atmosphere. Most scientists agree that in order to mitigate climate change, by 2050, global CO2 emissions must be reduced by at least 50%

  19. Iconic CO2 Time Series at Risk

    Energy Technology Data Exchange (ETDEWEB)

    Houweling, S. [SRON Netherlands Institute for Space Research, 3584 CA, Utrecht (Netherlands); Badawy, B. [Max-Planck-Institute for Biogeochemistry, 07745, Jena (Germany); Vermeulen, A.T. [Energieonderzoek Centrum Nederland ECN, 1755 ZG Petten (Netherlands)] [and others

    2012-08-31

    The Mauna Loa CO2 time series is iconic evidence of the effect of human-caused fossil fuel and land-use change emissions on the atmospheric increase of CO2. The continuity of such records depends critically on having stable funding, which is currently threatened by the financial crisis.

  20. Photocatalytic CO2 Activation by Water

    NARCIS (Netherlands)

    Yang, Chieh-Chao

    2011-01-01

    Photocatalytic activation of CO2 and water has potential for producing fuels by conversion of photon energy. However, the low productivity still limits practical application. In this study, the goal was to gain more fundamental insight in CO2 activation, and to provide guidelines for rational design

  1. Toxic emissions and devalued CO2-neutrality

    DEFF Research Database (Denmark)

    Czeskleba-Dupont, Rolf

    friendly effects of substituting wood burning for fossil fuels. With reference to Bent Sørensen's classical work on 'Renewable Energy' the assumption of CO2-neutrality regarding incineration is problematised when applied to plants with long rotation periods as trees. Registered CO2-emissions from wood...

  2. Options for CO2 sequestration in Kuwait

    NARCIS (Netherlands)

    Neele, F.; Vandeweijer, V.; Mayyan, H.; Sharma, S.R.; Kamal, D.

    2017-01-01

    In preparation for future requirements to abate CO2 emission levels, a CO2 storage feasibility study was carried out for the country of Kuwait. At present, no definite plans exist to install capture facilities at the larger emission points in the country; the study presented is one of the first

  3. Monitoring Options for CO2 Storage

    NARCIS (Netherlands)

    Arts, R.; Winthaegen, P.

    2005-01-01

    This chapter provides an overview of various monitoring techniques for CO2 storage that is structured into three categories-instrumentation in a well (monitoring well); instrumentation at the (near) surface (surface geophysical methods); and sampling at the (near) surface measuring CO2

  4. Aqueous ethylenediamine for CO(2) capture.

    Science.gov (United States)

    Zhou, Shan; Chen, Xi; Nguyen, Thu; Voice, Alexander K; Rochelle, Gary T

    2010-08-23

    Aqueous ethylenediamine (EDA) has been investigated as a solvent for CO(2) capture from flue gas. EDA can be used at 12 M (mol kg(-1) H(2)O) with an acceptable viscosity of 16 cP (1 cP=10(-3) Pa s) with 0.48 mol CO(2) per equivalent of EDA. Similar to monoethanolamine (MEA), EDA can be used up to 120 degrees C in a stripper without significant thermal degradation. Inhibitor A will effectively eliminate oxidative degradation. Above 120 degrees C, loaded EDA degrades with the production of its cyclic urea and other related compounds. Unlike piperazine, when exposed to oxidative degradation, EDA does not result in excessive foaming. Over much of the loading range, the CO(2) absorption rate with 12 M EDA is comparable to 7 M MEA. However, at typical rich loading, 12 M EDA absorbs CO(2) 2 times slower than 7 M MEA. The capacity of 12 M EDA is 0.72 mol CO(2)/(kg H(2)O+EDA) (for P(CO(2) )=0.5 to 5 kPa at 40 degrees C), which is about double that of MEA. The apparent heat of CO(2) desorption in EDA solution is 84 kJ mol(-1) CO(2); greater than most other amine systems.

  5. Key site abandonment steps in CO2 storage

    Science.gov (United States)

    Kühn, M.; Wipki, M.; Durucan, S.; Deflandre, J.-P.; Lüth, S.; Wollenweber, J.; Chadwick, A.; Böhm, G.

    2012-04-01

    CO2CARE is an EU funded project within FP7-research, which started in January 2011 with a funding period of three years. The project objectives will be achieved through an international consortium consisting of 23 partners from Europe, USA, Canada, Japan, and Australia, belonging to universities, research institutes, and energy companies. According to the EC Guidance Document 3, the lifetime of a CO2 storage site can be generally subdivided into 6 phases: 1. assessment, 2. characterisation, 3. development, 4. operation, 5. post-closure/pre-transfer, and 6. post transfer. CO2CARE deals with phases 5 and 6. The main goals of the project are closely linked to the three high-level requirements of the EU Directive 2009/31/EC, Article 18 for CO2 storage which are: (i) absence of any detectable leakage, (ii) conformity of actual behaviour of the injected CO2 with the modelled behaviour, and (iii) the storage site is evolving towards a situation of long-term stability. These criteria have to be fulfilled prior to subsequent transfer of responsibility to the competent authorities, typically 20 or 30 years after site closure. CO2CARE aims to formulate robust procedures for site abandonment which will meet the regulatory requirements and ensure long-term integrity of the storage complex. We present key results from the first year of the project via a report on international regulatory requirements on CO2 geological storage and site abandonment that includes a general overview on the current state-of-the art in abandonment methodologies in the oil and gas industry worldwide. Due to the long time-frames involved in CO2 storage (in the range of several thousands of years), the behaviour of a system with respect to, for example, long-term well stability can be demonstrated only by using long-term predictive modelling tools to study potential leakage pathways. Trapping mechanisms for CO2 are of high interest concerning a quantitative estimation of physically captured, capillary

  6. CO2 fluxes near a forest edge

    DEFF Research Database (Denmark)

    Sogachev, Andrey; Leclerc, Monique Y.; Zhang, Gensheng

    2008-01-01

    In contrast with recent advances on the dynamics of the flow at a forest edge, few studies have considered its role on scalar transport and, in particular, on CO2 transfer. The present study addresses the influence of the abrupt roughness change on forest atmosphere CO2 exchange and contrasts...... the concentration and flux fields against those of a uniform forested surface. We use an atmospheric boundary layer two-equation closure model that accounts for the flow dynamics and vertical divergence of CO2 sources/sinks within a plant canopy. This paper characterizes the spatial variation of CO2 fluxes...... as a function of both sources/sinks distribution and the vertical structure of the canopy. Results suggest that the ground source plays a major role in the formation of wave-like vertical CO2 flux behavior downwind of a forest edge, despite the fact that the contribution of foliage sources/sinks changes...

  7. Thermodynamic modeling of CO2 mixtures

    DEFF Research Database (Denmark)

    Bjørner, Martin Gamel

    Knowledge of the thermodynamic properties and phase equilibria of mixtures containing carbon dioxide (CO2) is important in several industrial processes such as enhanced oil recovery, carbon capture and storage, and supercritical extractions, where CO2 is used as a solvent. Despite this importance......, accurate predictions of the thermodynamic properties and phase equilibria of mixtures containing CO2 are challenging with classical models such as the Soave-Redlich-Kwong (SRK) equation of state (EoS). This is believed to be due to the fact, that CO2 has a large quadrupole moment which the classical models...... complicated due to parameter identifiability issues. In an attempt to quantify and illustrate these issues, the uncertainties in the pure compound parameters of CO2 were investigated using qCPA as well as different CPA approaches. The approaches employ between three and five parameters. The uncertainties...

  8. Underwater CO2 Sequestration Program in Korea

    Science.gov (United States)

    Kang, S.; Park, Y.; Choi, S.; Kim, Y.; Hwang, J.; Lee, J.

    2008-12-01

    In Korea an interdisciplinary project on underwater CO2 sequestration has been started. One of the main potential sites for the sequestration is the "DolGoRae (Dolphin)" gas field located over the southwestern part of the East/Japan Sea. We plan to deliver CO2 captured from the largest steel company in Korea (POSCO) to this site through pipe lines. To meet this end, chemical engineers study the behavior of CO2 hydrates, mechanical engineers design the pipe lines and injection systems, geologists and geological engineers survey the geological structure of the potential sites, and oceanographers assess the environmental effects. From a preliminary study, we find that we can store captured CO2 to the gas filed safely. In case the CO2 leaks from the storage site it would move to the north along the Korean coast on the average.

  9. Zinc depolarized electrochemical CO2 concentration

    Science.gov (United States)

    Woods, R. R.; Marshall, R. D.; Schubert, F. H.

    1975-01-01

    Two zinc depolarized electrochemical carbon dioxide concentrator concepts were analytically and experimentally evaluated for portable life support system carbon dioxide (CO2) removal application. The first concept, referred to as the zinc hydrogen generator electrochemical depolarized CO2 concentrator, uses a ZHG to generate hydrogen for direct use in an EDC. The second concept, referred to as the zinc/electrochemical depolarized concentrator, uses a standard EDC cell construction modified for use with the Zn anode. The Zn anode is consumed and subsequently regenerated, thereby eliminating the need to supply H2 to the EDC for the CO2 removal process. The evaluation was based primarily on an analytical evaluation of the two ZnDCs at projected end item performance and hardware design levels. Both ZnDC concepts for PLSS CO2 removal application were found to be noncompetitive in both total equivalent launch weight and individual extravehicular activity mission volume when compared to other candidate regenerable PLSS CO2 scrubbers.

  10. Space, myth and cinematography

    Science.gov (United States)

    Hambardzumov, Arsen

    2016-12-01

    There exist both ancient and modern myths. The competition of good and evil, sanctity, mythic hero character, etc. make up those myths. Connection between the myth and literature, art and mainly cinematography is highly essential. Hollywood is a striking example of that connection, in other words "A Dream Factory". The mythic component in American films is obvious. It refers to the product structure which is frequently created by mythic rules. One of its striking examples is D. Lucas's film "Star wars. Episode IV - New Hope" (1977): The film plot is built on the struggle between the good and the evil. On one hand those are the representatives of the Empire with Darth Vader and princess Leia with her devotees on the other. The space has played a unique role for Greek philosophers as well. It was the symbol of perfection and grace. The attempt to approach this perfection, the desire to see the internal similarity besides the external one has been reflected in S. Kubrick's film "2001: Space Odyssey" (1968). Showing the space distance director looks for perfection in us which lies in the harmony of truth, human and nature.

  11. The ins and outs of CO2.

    Science.gov (United States)

    Raven, John A; Beardall, John

    2016-01-01

    It is difficult to distinguish influx and efflux of inorganic C in photosynthesizing tissues; this article examines what is known and where there are gaps in knowledge. Irreversible decarboxylases produce CO2, and CO2 is the substrate/product of enzymes that act as carboxylases and decarboxylases. Some irreversible carboxylases use CO2; others use HCO3(-). The relative role of permeation through the lipid bilayer versus movement through CO2-selective membrane proteins in the downhill, non-energized, movement of CO2 is not clear. Passive permeation explains most CO2 entry, including terrestrial and aquatic organisms with C3 physiology and biochemistry, terrestrial C4 plants and all crassulacean acid metabolism (CAM) plants, as well as being part of some mechanisms of HCO3(-) use in CO2 concentrating mechanism (CCM) function, although further work is needed to test the mechanism in some cases. However, there is some evidence of active CO2 influx at the plasmalemma of algae. HCO3(-) active influx at the plasmalemma underlies all cyanobacterial and some algal CCMs. HCO3(-) can also enter some algal chloroplasts, probably as part of a CCM. The high intracellular CO2 and HCO3(-) pools consequent upon CCMs result in leakage involving CO2, and occasionally HCO3(-). Leakage from cyanobacterial and microalgal CCMs involves up to half, but sometimes more, of the gross inorganic C entering in the CCM; leakage from terrestrial C4 plants is lower in most environments. Little is known of leakage from other organisms with CCMs, though given the leakage better-examined organisms, leakage occurs and increases the energetic cost of net carbon assimilation. © The Author 2015. Published by Oxford University Press on behalf of the Society for Experimental Biology.

  12. The ins and outs of CO2

    Science.gov (United States)

    Raven, John A.; Beardall, John

    2016-01-01

    It is difficult to distinguish influx and efflux of inorganic C in photosynthesizing tissues; this article examines what is known and where there are gaps in knowledge. Irreversible decarboxylases produce CO2, and CO2 is the substrate/product of enzymes that act as carboxylases and decarboxylases. Some irreversible carboxylases use CO2; others use HCO3 –. The relative role of permeation through the lipid bilayer versus movement through CO2-selective membrane proteins in the downhill, non-energized, movement of CO2 is not clear. Passive permeation explains most CO2 entry, including terrestrial and aquatic organisms with C3 physiology and biochemistry, terrestrial C4 plants and all crassulacean acid metabolism (CAM) plants, as well as being part of some mechanisms of HCO3 – use in CO2 concentrating mechanism (CCM) function, although further work is needed to test the mechanism in some cases. However, there is some evidence of active CO2 influx at the plasmalemma of algae. HCO3 – active influx at the plasmalemma underlies all cyanobacterial and some algal CCMs. HCO3 – can also enter some algal chloroplasts, probably as part of a CCM. The high intracellular CO2 and HCO3 – pools consequent upon CCMs result in leakage involving CO2, and occasionally HCO3 –. Leakage from cyanobacterial and microalgal CCMs involves up to half, but sometimes more, of the gross inorganic C entering in the CCM; leakage from terrestrial C4 plants is lower in most environments. Little is known of leakage from other organisms with CCMs, though given the leakage better-examined organisms, leakage occurs and increases the energetic cost of net carbon assimilation. PMID:26466660

  13. A usage of CO2 hydrate: convenient method to increase CO2 concentration in culturing algae.

    Science.gov (United States)

    Nakano, Sho; Chang, Kwang-Hyeon; Shijima, Atsushi; Miyamoto, Hiroyuki; Sato, Yukio; Noto, Yuji; Ha, Jin-Yong; Sakamoto, Masaki

    2014-11-01

    The addition of CO2 to algal culture systems can increase algal biomass effectively. Generally, gas bubbling is used to increase CO2 levels in culture systems; however, it is difficult to quantitatively operate to control the concentration using this method. In this study, we tested the usability of CO2 hydrate for phytoplankton culture. Specifically, green algae Pseudokirchneriella subcapitata were cultured in COMBO medium that contained dissolved CO2 hydrate, after which its effects were evaluated. The experiment was conducted according to a general bioassay procedure (OECD TG201). CO2 promoted algae growth effectively (about 2-fold relative to the control), and the decrease in pH due to dissolution of the CO2 in water recovered soon because of photosynthesis. Since the CO2 hydrate method can control a CO2 concentration easily and quantitatively, it is expected to be useful in future applications. Copyright © 2014 Elsevier Ltd. All rights reserved.

  14. Dynamics of CO2 fluxes and concentrations during a shallow subsurface CO2 release

    Energy Technology Data Exchange (ETDEWEB)

    Lewicki, J.L.; Hilley, G.E.; Dobeck, L.; Spangler, L.

    2009-09-01

    A field facility located in Bozeman, Montana provides the opportunity to test methods to detect, locate, and quantify potential CO2 leakage from geologic storage sites. From 9 July to 7 August 2008, 0.3 t CO2 d{sup -1} were injected from a 100-m long, {approx}2.5 m deep horizontal well. Repeated measurements of soil CO2 fluxes on a grid characterized the spatio-temporal evolution of the surface leakage signal and quantified the surface leakage rate. Infrared CO2 concentration sensors installed in the soil at 30 cm depth at 0 to 10 m from the well and at 4 cm above the ground at 0 and 5 m from the well recorded surface breakthrough of CO2 leakage and migration of CO2 leakage through the soil. Temporal variations in CO2 concentrations were correlated with atmospheric and soil temperature, wind speed, atmospheric pressure, rainfall, and CO2 injection rate.

  15. Myths and Truths from Exercise Physiology

    Science.gov (United States)

    Kieffer, H. Scott

    2008-01-01

    This article addresses some of the common myths in the field of exercise physiology. Some of the myths are misconstrued facts that have developed over time, such as the myth of localized fat reduction. Other myths are unproved or collective beliefs used to justify a social institution; we see this occur in the form of "fitness fads." Society is…

  16. Ricoeur on myth and demythologising

    African Journals Online (AJOL)

    2016-07-08

    Jul 8, 2016 ... using the Religionsgeschichtliche definition of myth and applying. Hans Jonas's .... Beyond the self-understanding of a society there is an opaque ... just like languages. Just as languages are translatable, so are myths, giving them a horizon of universality that allows them to be understood by other cultures.

  17. Myth, Method and International News.

    Science.gov (United States)

    Lule, Jack

    Defining myth as a cultural narrative in symbolic form that articulates a world view and offers consensus with that view, this paper uses a brief "New York Times" report on the Soviet shooting down of South Korean airline flight 007 as the basis for comparison of international news and myth. Following a review of the literature on myth…

  18. Myths about Energy in Schools.

    Science.gov (United States)

    Department of Energy, Washington, DC. Office of Energy Efficiency and Renewable Energy.

    This publication from the EnergySmart Schools initiative, a program that focuses on improving communities nationwide through energy-saving solutions, examines some myths and misconceptions about energy in schools and provides facts that can help school districts make smarter energy choices. The myths discussed are: (1) energy isn't a major budget…

  19. Myths about English Language Learning

    Science.gov (United States)

    Medina-Jerez, William; Campbell, Todd

    2015-01-01

    As the ethnic and racial diversity in U.S. classrooms continues to grow, myths about the education of English Language Learners (ELLs) persist, while many teachers feel ill-prepared to meet these students' academic needs. This article focuses on myths shared by in-service science teachers enrolled in a master's program at the University of Texas…

  20. Electrocatalytic Alloys for CO2 Reduction.

    Science.gov (United States)

    He, Jingfu; Johnson, Noah J J; Huang, Aoxue; Berlinguette, Curtis P

    2018-01-10

    Electrochemically reducing CO2 using renewable energy is a contemporary global challenge that will only be met with electrocatalysts capable of efficiently converting CO2 into fuels and chemicals with high selectivity. Although many different metals and morphologies have been tested for CO2 electrocatalysis over the last several decades, relatively limited attention has been committed to the study of alloys for this application. Alloying is a promising method to tailor the geometric and electric environments of active sites. The parameter space for discovering new alloys for CO2 electrocatalysis is particularly large because of the myriad products that can be formed during CO2 reduction. In this Minireview, mixed-metal electrocatalyst compositions that have been evaluated for CO2 reduction are summarized. A distillation of the structure-property relationships gleaned from this survey are intended to help in the construction of guidelines for discovering new classes of alloys for the CO2 reduction reaction. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  1. Assessing the potential impact of the CO2 performance ladder on CO2 emission reduction

    NARCIS (Netherlands)

    Kornelis Blok; dr. Martijn Rietbergen

    2013-01-01

    The aim of this research is to assess the potential impact of the CO2 Performance Ladder on CO2 emission reduction. The CO2 Performance Ladder is a new green procurement scheme that has been adopted by several public authorities in the Netherlands; it is a staged certification scheme for energy and

  2. Regenerable Sorbent for CO2 Removal

    Science.gov (United States)

    Alptekin, Gokhan; Jayaraman, Ambal

    2013-01-01

    A durable, high-capacity regenerable sorbent can remove CO2 from the breathing loop under a Martian atmosphere. The system design allows near-ambient temperature operation, needs only a small temperature swing, and sorbent regeneration takes place at or above 8 torr, eliminating the potential for Martian atmosphere to leak into the regeneration bed and into the breathing loop. The physical adsorbent can be used in a metabolic, heat-driven TSA system to remove CO2 from the breathing loop of the astronaut and reject it to the Martian atmosphere. Two (or more) alternating sorbent beds continuously scrub and reject CO2 from the spacesuit ventilation loop. The sorbent beds are cycled, alternately absorbing CO2 from the vent loop and rejecting the adsorbed material into the environment at a high CO2 partial pressure (above 8 torr). The system does not need to run the adsorber at cryogenic temperatures, and uses a much smaller temperature swing. The sorbent removes CO2 via a weak chemical interaction. The interaction is strong enough to enable CO2 adsorption even at 3 to 7.6 torr. However, because the interaction between the surface adsorption sites and the CO2 is relatively weak, the heat input needed to regenerate the sorbent is much lower than that for chemical absorbents. The sorbent developed in this project could potentially find use in a large commercial market in the removal of CO2 emissions from coal-fired power plants, if regulations are put in place to curb carbon emissions from power plants.

  3. Energy Balance of Global CO_2 Recycling and Amounts of Reduction of CO_2 Emission

    OpenAIRE

    Hashimoto, K; Akiyama, E.; Habazaki, H.; Kawashima, A.; Komori, M.; SHIMAMURA, K.; Kumagai, N.

    1997-01-01

    On the basis of tailoring of amorphous alloy electrodes for seawater electrolysis to form H_2 and amorphous alloy catalysts for conversion of CO_2 to CH_4, we are proposing global CO_2 recycling : At deserts; power generation by solar energy, at coasts close to the deserts; production of H_2 by electrolysis of seawater, production of CH_4 by the reaction of H_2 and CO_2 transported, and at energy consuming districts; combustion of CH_4, recovery of CO_2 and transportation of liquefied CO_2 to...

  4. Amateur mythographies: Fan fiction and the myth of myth

    Directory of Open Access Journals (Sweden)

    Ika Willis

    2016-03-01

    Full Text Available This paper draws on classical scholarship on myth in order to critically examine three ways in which scholars and fans have articulated a relationship between fan fiction and myth. These are (1 the notion of fan fiction as a form of folk culture, reclaiming popular story from corporate ownership; (2 the notion of myth as counterhegemonic, often feminist, discourse; (3 the notion of myth as a commons of story and a universal story world. I argue that the first notion depends on an implicit primitivizing of fan fiction and myth, which draws ultimately on the work of Gottfried von Herder in the 18th century and limits our ability to produce historically and politically nuanced understandings of fan fiction. The second notion, which is visible in the work of Henry Jenkins and Constance Penley, is more helpful because of its attention to the politics of narration. However, it is the third model of myth, as a universal story world, where we find the richest crossover between fan fiction's creative power and contemporary classical scholarship on myth, especially in relation to Sarah Iles Johnston's analysis of hyperserial narrative. I demonstrate this through some close readings of fan fiction from the Greek and Roman Mythology fandom on Archive of Our Own. I conclude the paper by extending Johnston's arguments to show that fan-fictional hyperseriality, specifically, can be seen as mythic because it intervenes not only in the narrative worlds of its source materials but also in the social world of its telling.

  5. A cost effective CO2 strategy

    DEFF Research Database (Denmark)

    In January 2008 the Danish Government decided to prepare a strategy for reducing CO2 from the transport sector in Denmark. The decision to prepare the strategy was part of the follow-up to the national Infrastructure Commission report of January 2008. The preparations have been chaired...... by the Ministry of Transport, with the Technical University of Denmark as one of the main contributors. The CO2-strategy was to be based on the principle of cost-effectiveness. A model was set up to assist in the assessment. The model consists of a projection of CO2-emissions from road and rail modes from 2020......, a scenario-part and a cost-benefit part. Air and sea modes are not analyzed. The model adopts a bottom-up approach to allow a detailed assessment of transport policy measures. Four generic areas of intervention were identified and the likely effect on CO2 emissions, socioeconomic efficiency and other...

  6. The ATLAS IBL CO2 Cooling System

    CERN Document Server

    Verlaat, Bartholomeus; The ATLAS collaboration

    2016-01-01

    The Atlas Pixel detector has been equipped with an extra B-layer in the space obtained by a reduced beam pipe. This new pixel detector called the ATLAS Insertable B-Layer (IBL) is installed in 2014 and is operational in the current ATLAS data taking. The IBL detector is cooled with evaporative CO2 and is the first of its kind in ATLAS. The ATLAS IBL CO2 cooling system is designed for lower temperature operation (<-35⁰C) than the previous developed CO2 cooling systems in High Energy Physics experiments. The cold temperatures are required to protect the pixel sensors for the high expected radiation dose up to 550 fb^-1 integrated luminosity. This paper describes the design, development, construction and commissioning of the IBL CO2 cooling system. It describes the challenges overcome and the important lessons learned for the development of future systems which are now under design for the Phase-II upgrade detectors.

  7. Sustainable Process Networks for CO2 Conversion

    DEFF Research Database (Denmark)

    Frauzem, Rebecca; Kongpanna, P.; Pavarajam, V.

    that are thermodynamically feasible, including the co-reactants, catalysts, operating conditions and reactions. Research has revealed that there are a variety of reactions that fulfill the aforementioned criteria. The products that are formed fall into categories: fuels, bulk chemicals and specialty chemicals. While fuels...... the emissions is the conversion of CO2 into useful products, such as methanol [3]. In this work, through a computer-aided framework for process network synthesis-design, a network of feasible conversion processes that all use emitted CO2 is investigated. CO2 is emitted into the environment from various sources......, such as methanol (MeOH) have the largest market, this network will include a variety of thermodynamically feasible conversion paths [4]. From reviews of work previously done, there are ranges of possible products that are formed from CO2 and another co-reactant directly. Methanol, dimethyl ether, dimethyl...

  8. CO2 Removal from Mars EMU Project

    Data.gov (United States)

    National Aeronautics and Space Administration — CO2 control for during ExtraVehicular Activity (EVA) on mars is challenging. Lithium hydroxide (LiOH) canisters have impractical logistics penalties, and regenerable...

  9. Compact, High Accuracy CO2 Monitor Project

    Data.gov (United States)

    National Aeronautics and Space Administration — This Small Business Innovative Research Phase I proposal seeks to develop a low cost, robust, highly precise and accurate CO2 monitoring system. This system will...

  10. Compact, High Accuracy CO2 Monitor Project

    Data.gov (United States)

    National Aeronautics and Space Administration — This Small Business Innovative Research Phase II proposal seeks to develop a low cost, robust, highly precise and accurate CO2 monitoring system. This system will...

  11. CO2 emissions in the steel industry

    Directory of Open Access Journals (Sweden)

    M. Kundak

    2009-07-01

    Full Text Available Global CO2 emissions caused by the burning of fossil fuels over the past century are presented. Taking into consideration the total world production of more than 1,3 billion tons of steel, the steel industry produces over two billion tons of CO2. Reductions in CO2 emissions as a result of technological improvements and structural changes in steel production in industrialized countries during the past 40 years are described. Substantial further reductions in those emissions will not be possible using conventional technologies. Instead, a radical cutback may be achieved if, instead of carbon, hydrogen is used for direct iron ore reduction. The cost and the ensuing CO2 generation in the production of hydrogen as a reducing agent from various sources are analysed.

  12. Photocatalytic Conversion of CO2 on Mars

    Science.gov (United States)

    Meier, Annie; Hare, Bryan

    2016-01-01

    Light on Mars shows potential for providing the energy means necessary for enhanced In-Situ Resource Utilization (ISRU). Through photocatalysis, the energy barrier required to convert CO2 is lowered and CH4 production is favorable.

  13. CO2 Removal from Mars EMU Project

    Data.gov (United States)

    National Aeronautics and Space Administration — A practical CO2 control system for ExtraVehicular Activity (EVA) on Mars have not yet been developed. TDA Research, Inc. proposes to develop a durable,...

  14. CO2 binding in the (quinoline-CO2)- anionic complex

    Science.gov (United States)

    Graham, Jacob D.; Buytendyk, Allyson M.; Wang, Yi; Kim, Seong K.; Bowen, Kit H.

    2015-06-01

    We have studied the (quinoline-CO2)- anionic complex by a combination of mass spectrometry, anion photoelectron spectroscopy, and density functional theory calculations. The (quinoline-CO2)- anionic complex has much in common with previously studied (N-heterocycle-CO2)- anionic complexes both in terms of geometric structure and covalent bonding character. Unlike the previously studied N-heterocycles, however, quinoline has a positive electron affinity, and this provided a pathway for determining the binding energy of CO2 in the (quinoline-CO2)- anionic complex. From the theoretical calculations, we found CO2 to be bound within the (quinoline-CO2)- anionic complex by 0.6 eV. We also showed that the excess electron is delocalized over the entire molecular framework. It is likely that the CO2 binding energies and excess electron delocalization profiles of the previously studied (N-heterocycle-CO2)- anionic complexes are quite similar to that of the (quinoline-CO2)- anionic complex. This class of complexes may have a role to play in CO2 activation and/or sequestration.

  15. Rising CO2 Levels Will Intensify Phytoplankton Blooms in Eutrophic and Hypertrophic Lakes

    Science.gov (United States)

    Verspagen, Jolanda M. H.; Van de Waal, Dedmer B.; Finke, Jan F.; Visser, Petra M.; Van Donk, Ellen; Huisman, Jef

    2014-01-01

    Harmful algal blooms threaten the water quality of many eutrophic and hypertrophic lakes and cause severe ecological and economic damage worldwide. Dense blooms often deplete the dissolved CO2 concentration and raise pH. Yet, quantitative prediction of the feedbacks between phytoplankton growth, CO2 drawdown and the inorganic carbon chemistry of aquatic ecosystems has received surprisingly little attention. Here, we develop a mathematical model to predict dynamic changes in dissolved inorganic carbon (DIC), pH and alkalinity during phytoplankton bloom development. We tested the model in chemostat experiments with the freshwater cyanobacterium Microcystis aeruginosa at different CO2 levels. The experiments showed that dense blooms sequestered large amounts of atmospheric CO2, not only by their own biomass production but also by inducing a high pH and alkalinity that enhanced the capacity for DIC storage in the system. We used the model to explore how phytoplankton blooms of eutrophic waters will respond to rising CO2 levels. The model predicts that (1) dense phytoplankton blooms in low- and moderately alkaline waters can deplete the dissolved CO2 concentration to limiting levels and raise the pH over a relatively wide range of atmospheric CO2 conditions, (2) rising atmospheric CO2 levels will enhance phytoplankton blooms in low- and moderately alkaline waters with high nutrient loads, and (3) above some threshold, rising atmospheric CO2 will alleviate phytoplankton blooms from carbon limitation, resulting in less intense CO2 depletion and a lesser increase in pH. Sensitivity analysis indicated that the model predictions were qualitatively robust. Quantitatively, the predictions were sensitive to variation in lake depth, DIC input and CO2 gas transfer across the air-water interface, but relatively robust to variation in the carbon uptake mechanisms of phytoplankton. In total, these findings warn that rising CO2 levels may result in a marked intensification of

  16. Udvikling af CO2 neutralt byrumsarmatur

    DEFF Research Database (Denmark)

    Poulsen, Peter Behrensdorff; Dam-Hansen, Carsten; Corell, Dennis Dan

    Denne rapport indeholder en beskrivelse af arbejdet udført i og resultaterne af forsknings- og udviklingsprojektet ” Udvikling af CO2 neutralt byrumsarmatur” og udgør slutrapportering for dette projekt.......Denne rapport indeholder en beskrivelse af arbejdet udført i og resultaterne af forsknings- og udviklingsprojektet ” Udvikling af CO2 neutralt byrumsarmatur” og udgør slutrapportering for dette projekt....

  17. Bifunctional Catalysts for CO2 Reduction

    Science.gov (United States)

    2014-09-30

    product distribution as a function of catalyst composition (ligand, metal ions), electrolyte, acid and CO2 pressure. 4. Examine reaction chemistry ...alternative ligand platforms to seek transition metal complexes that would feature inner-sphere reduction chemistry with CO2 and promote the desired multi...into these polyamine based-ligands typically involves a transamination reaction with metal-amide or organometallic starting materials (e.g., M2(N

  18. Density of aqueous solutions of CO2

    OpenAIRE

    Garcia, Julio E.

    2001-01-01

    In this report, we present a numerical representation for the partial molar volume of CO2 in water and the calculation of the corresponding aqueous solution density. The motivation behind this work is related to the importance of having accurate representations for aqueous phase properties in the numerical simulation of carbon dioxide disposal into aquifers as well as in geothermal applications. According to reported experimental data the density of aqueous solutions of CO2 can be as mu...

  19. Photoacoustic CO2-Sensor for Automotive Applications

    OpenAIRE

    Huber, J; C. Weber; Eberhardt, A.; Wöllenstein, J.

    2016-01-01

    We present a field-tested miniaturized spectroscopic CO2 sensor which is based on the photoacoustic effect. The sensor is developed for automotive applications and considers the requirements for the usage in vehicles. The sensor measures two measurement ranges simultaneously: The monitoring of the indoor air quality and the detection of possible leakages of the coolant in CO2 air-conditioning systems. The sensor consists of a miniaturized innovative photoacoustic sensor unit with integrated e...

  20. Combustion of hythane diluted with CO2

    Directory of Open Access Journals (Sweden)

    Hraiech Ibtissem

    2015-01-01

    Full Text Available With increasing concern about energy shortage and environmental protection, improving engine fuel economy and reducing exhaust emissions have become major research topics in combustion and engine development. Hythane (a blend of hydrogen H2 and natural gas NG has generated a significant interest as an alternative fuel for the future. This paper describes an experimental study of the effects of CO2 addition on the stability of a turbulent jet diffusion NG-H2 flame. The mole fraction of hydrogen (% H2 in NG-H2 mixture was varied from 0% to 50%. The equivalence ratio of the hythane/CO2/air mixture was kept at stoichiometry. The results show that the lift-off height increases with the addition of CO2 at various % H2 content in hythane. However, we observe that with 20% H2, we can obtain a stable flame diluted with 40% CO2, while for 0% H2, the flame is blown out above 20% CO2. This means that the limits of flame blowing out are pushed with the additions of H2. Moreover, the results show that for %H2 content in NG-H2 fuel up to 10%, the addition of CO2 could produce lifted flame if the % CO2 is low. At higher % CO2 dilution, flame would remain attached until blow-out. This is mainly due to the fact that the dilution leads to ejection velocities very high but reactivity of the mixture does not change so the flame tends to stretch.

  1. Application of advanced technologies for CO2 capture from industrial sources

    Energy Technology Data Exchange (ETDEWEB)

    Romano, M.C. [Politecnico di Milano, Energy Department, via Lambruschini 4, 20156 Milano (Italy); Anantharaman, R. [SINTEF Energy Research, Sem Saelands vei 11, 7465 Trondheim (Norway); Arasto, A. [VTT Technical Research Centre of Finland, P.O. Box 1000, FI-02044 VTT (Finland); Ozcan, D.C.; Ahnd, Hyungwoong [IMP-SEE, The University of Edinburgh, Mayfield Road, Edinburgh, EH9 3JL (United Kingdom); Dijkstra, J.W.; Carbo, M. [Energy research Centre of the Netherlands ECN, P.O. Box 1, 1755 ZG Petten (Netherlands); Boavida, D. [LNEG - Laboratorio Nacional de Energia e Geologia, Estrada do Paco do Lumiar, 22 Edif J, 1649-038 Lisboa (Portugal)

    2013-07-01

    The great majority of the research on CO2 capture worldwide is today devoted to the integration of new technologies in power plants, which are responsible for about 80% of the worldwide CO2 emission from large stationary sources. The remaining 20% are emitted from industrial sources, mainly cement production plants ({approx}7% of the total emission), refineries ({approx}6%) and iron and steel industry ({approx}5%). Despite their lower overall contribution, the CO2 concentration in flue gas and the average emission per source can be higher than in power plants. Therefore, application of CO2 capture processes on these sources can be more effective and can lead to competitive cost of the CO2 avoided with respect to power plants. Furthermore, industrial CO2 capture could be an important early-opportunity application, or a facilitate demonstration of capture technology at a relative small scale or in a side stream. This paper results from a collaborative activity carried out within the Joint Programme on Carbon Capture and Storage of the European Energy Research Alliance (EERA CCS-JP) and aims at investigating the potentiality of new CO2 technologies in the application on the major industrial emitters.

  2. Energy use and CO2 emissions of consumer goods transport. Trends of Dutch imports in the period 1969-2010

    NARCIS (Netherlands)

    Breeuwer, Jelco

    2012-01-01

    SUMMARY The energy use and CO2 emissions related to world-wide transportation of consumer goods have increased sharply during the last years. It is expected that this trend will continue in the future. Because the energy use and CO2 emissions related to

  3. Density of aqueous solutions of CO2

    Energy Technology Data Exchange (ETDEWEB)

    Garcia, Julio E.

    2001-10-10

    In this report, we present a numerical representation for the partial molar volume of CO2 in water and the calculation of the corresponding aqueous solution density. The motivation behind this work is related to the importance of having accurate representations for aqueous phase properties in the numerical simulation of carbon dioxide disposal into aquifers as well as in geothermal applications. According to reported experimental data the density of aqueous solutions of CO2 can be as much as 2-3% higher than pure water density. This density variation might produce an influence on the groundwater flow regime. For instance, in geologic sequestration of CO2, convective transport mixing might occur when, several years after injection of carbon dioxide has stopped, the CO2-rich gas phase is concentrated at the top of the formation, just below an overlaying caprock. In this particular case the heavier CO2 saturated water will flow downward and will be replaced by water with a lesser CO2 content.

  4. CO2 efflux from cleared mangrove peat.

    Directory of Open Access Journals (Sweden)

    Catherine E Lovelock

    Full Text Available BACKGROUND: CO(2 emissions from cleared mangrove areas may be substantial, increasing the costs of continued losses of these ecosystems, particularly in mangroves that have highly organic soils. METHODOLOGY/PRINCIPAL FINDINGS: We measured CO(2 efflux from mangrove soils that had been cleared for up to 20 years on the islands of Twin Cays, Belize. We also disturbed these cleared peat soils to assess what disturbance of soils after clearing may have on CO(2 efflux. CO(2 efflux from soils declines from time of clearing from ∼10,600 tonnes km(-2 year(-1 in the first year to 3000 tonnes km(2 year(-1 after 20 years since clearing. Disturbing peat leads to short term increases in CO(2 efflux (27 umol m(-2 s(-1, but this had returned to baseline levels within 2 days. CONCLUSIONS/SIGNIFICANCE: Deforesting mangroves that grow on peat soils results in CO(2 emissions that are comparable to rates estimated for peat collapse in other tropical ecosystems. Preventing deforestation presents an opportunity for countries to benefit from carbon payments for preservation of threatened carbon stocks.

  5. Anthropogenic CO2 in the ocean

    Directory of Open Access Journals (Sweden)

    Tsung-Hung Peng

    2005-06-01

    Full Text Available The focus of this review article is on the anthropogenic CO2 taken up by the ocean. There are several methods of identifying the anthropogenic CO2 signal and quantifying its inventory in the ocean. The ?C* method is most frequently used to estimate the global distribution of anthropogenic CO2 in the ocean. Results based on analysis of the dataset obtained from the comprehensive surveys of inorganic carbon distribution in the world oceans in the 1990s are given. These surveys were jointly conducted during the World Ocean Circulation Experiment (WOCE and the Joint Global Ocean Flux Study (JGOFS. This data set consists of 9618 hydrographic stations from a total of 95 cruises, which represents the most accurate and comprehensive view of the distribution of inorganic carbon in the global ocean available today. The increase of anthropogenic CO2 in the ocean during the past few decades is also evaluated using direct comparison of results from repeat surveys and using statistical method of Multi-parameter Linear Regression (MLR. The impact of increasing oceanic anthropogenic CO2 on the calcium carbonate system in the ocean is reviewed briefly as well. Extensive studies of CaCO3 dissolution as a result of increasing anthropogenic CO2 in the ocean have revealed several distinct oceanic regions where the CaCO3 undersaturation zone has expanded.

  6. Monitoring CO2 in shock states.

    Science.gov (United States)

    Danin, Pierre-Eric; Siegenthaler, Nils; Levraut, Jacques; Bernardin, Gilles; Dellamonica, Jean; Bendjelid, Karim

    2015-10-01

    The primary end point when treating acute shock is to restore blood circulation, mainly by reaching macrocirculatory parameters. However, even if global haemodynamic goals can be achieved, microcirculatory perfusion may remain impaired, leading to cellular hypoxia and organ damage. Interestingly, few methods are currently available to measure the adequacy of organ blood flow and tissue oxygenation. The rise in tissue partial pressure of carbon dioxide (CO2) has been observed when tissue perfusion is decreased. In this regard, tissue partial pressure of CO2 has been proposed as an early and reliable marker of tissue hypoxia even if the mechanisms of tissue partial pressure in CO2 rise during hypoperfusion remain unclear. Several technologies allow the estimation of CO2 content from different body sites: vascular, tissular (in hollow organs, mucosal or cutaneous), and airway. These tools remain poorly evaluated, and some are used but are not widely used in clinical practice. The present review clarifies the physiology of increasing tissue CO2 during hypoperfusion and underlines the specificities of the different technologies that allow bedside estimation of tissue CO2 content.

  7. Advanced CO2 Removal and Reduction System

    Science.gov (United States)

    Alptekin, Gokhan; Dubovik, Margarita; Copeland, Robert J.

    2011-01-01

    An advanced system for removing CO2 and H2O from cabin air, reducing the CO2, and returning the resulting O2 to the air is less massive than is a prior system that includes two assemblies . one for removal and one for reduction. Also, in this system, unlike in the prior system, there is no need to compress and temporarily store CO2. In this present system, removal and reduction take place within a single assembly, wherein removal is effected by use of an alkali sorbent and reduction is effected using a supply of H2 and Ru catalyst, by means of the Sabatier reaction, which is CO2 + 4H2 CH4 + O2. The assembly contains two fixed-bed reactors operating in alternation: At first, air is blown through the first bed, which absorbs CO2 and H2O. Once the first bed is saturated with CO2 and H2O, the flow of air is diverted through the second bed and the first bed is regenerated by supplying it with H2 for the Sabatier reaction. Initially, the H2 is heated to provide heat for the regeneration reaction, which is endothermic. In the later stages of regeneration, the Sabatier reaction, which is exothermic, supplies the heat for regeneration.

  8. Roger Caillois’ Biology of Myth and the Myth of Biology

    OpenAIRE

    Eidelpes, Rosa

    2014-01-01

    The article focuses on the “mythical” epistemology of Roger Caillois (1913-1987). For the French sociologist, writer and literary critic myth can no longer be confined to the specialist area of a cultural analysis of mythology, but is part of a « diagonal science ». In his work Le mythe et l’homme (1938), he aims to develop a “biological” basis for the theory of myths. He argues that human imagination is dominated by instincts and that natural processes control cultural production. Thus, Le m...

  9. CO2 Emission Factors for Coals

    Directory of Open Access Journals (Sweden)

    P. Orlović-Leko

    2015-03-01

    Full Text Available Emission factors are used in greenhouse gas inventories to estimate emissions from coal combustion. In the absence of direct measures, emissions factors are frequently used as a quick, low cost way to estimate emissions values. Coal combustion has been a major contributor to the CO2 flux into the atmosphere. Nearly all of the fuel carbon (99 % in coal is converted to CO2 during the combustion process. The carbon content is the most important coal parameter which is the measure of the degree of coalification (coal rank. Coalification is the alteration of vegetation to form peat, succeeded by the transformation of peat through lignite, sub-bituminous, bituminous to anthracite coal. During the geochemical or metamorphic stage, the progressive changes that occur within the coal are an increase in the carbon content and a decrease in the hydrogen and oxygen content resulting in a loss of volatiles. Heterogeneous composition of coal causes variation in CO2 emission from different coals. The IPCC (Intergovernmental Panel on Climate Change has produced guidelines on how to produce emission inventories which includes emission factors. Although 2006 IPCC Guidelines provided the default values specified according to the rank of the coal, the application of country-specific emission factors was recommended when estimating the national greenhouse gas emissions. This paper discusses the differences between country-specific emission factors and default IPCC CO2 emission factors, EF(CO2, for coals. Also, this study estimated EF(CO2 for two different types of coals and peat from B&H, on the basis fuel analyses. Carbon emission factors for coal mainly depend on the carbon content of the fuel and vary with both rank and geographic origin, which supports the idea of provincial variation of carbon emission factors. Also, various other factors, such as content of sulphur, minerals and macerals play an important role and influence EF(CO2 from coal. Carbonate minerals

  10. Baikal: Myth and Image

    Directory of Open Access Journals (Sweden)

    Konstantin Lidin

    2013-09-01

    Full Text Available Baikal is not only one of the greatest lakes of the world. Baikal is a system of myths and images which has been formed for many centuries. The analysis of old maps shows that only 200-300 years ago the existence of Baikal was the subject of wild speculations. Today the image of Baikal is a world brand. However citizens of Irkutsk and other towns located around Baikal can hardly make any profit on it. The reason is the absence of specialists who would be able to work with such a complex and strong image as Baikal.

  11. Scientific myth-conceptions

    Science.gov (United States)

    Allchin, Douglas

    2003-05-01

    Using several familiar examples - Gregor Mendel, H. B. D. Kettlewell, Alexander Fleming, Ignaz Semmelweis, and William Harvey - I analyze how educators currently frame historical stories to portray the process of science. They share a rhetorical architecture of myth, which misleads students about how science derives its authority. Narratives of error and recovery from error, alternatively, may importantly illustrate the nature of science, especially its limits. Contrary to recent claims for reform, we do not need more history in science education. Rather, we need different types of history that convey the nature of science more effectively.

  12. Authorship: Few Myths and Misconceptions.

    Science.gov (United States)

    Menezes, Ritesh G; Kharoshah, Magdy A; Madadin, Mohammed; Marakala, Vijaya; Lasrado, Savita; Al Tamimi, Dalal M

    2016-12-01

    This article seeks to address and dispel some of the popular myths and misconceptions surrounding authorship of a scientific publication as this is often misconstrued by beginners in academia especially those in the developing world. While ethical issues in publishing related to authorship have been increasingly discussed, not much has been written about the myths and misconceptions of who might be an author. Dispelling these myths and misconceptions would go a long way in shaping the thoughts and plans of students, junior faculty and researchers in academia especially in the developing world.

  13. Modern myths of Mars

    Science.gov (United States)

    Levin, Gilbert V.

    2006-08-01

    July 30, 2006 was the 30 th anniversary of the Viking Mission's first Labeled Release (LR) life detection experiment on Mars. The strong response, together with supporting results from eight additional LR tests of Martian soil, established the presence of an active agent that was inhibited by heating. The data satisfied the pre-mission criteria for the detection of living microorganisms. However, the scientific community reacted cautiously, generally concluding that the activity in the soil was caused by chemistry or physics. Over the last three decades, investigation of Mars has greatly increased. Soil, rock and atmospheric analyses have been made. Multi-spectral observations have been made from Mars and Earth orbits and from Earth-based telescopes. Knowledge of extreme habitats and bizarre life forms that populate them on Earth has increased dramatically. However, this vast amount of new astrobiological information has yet to be integrated into an objective scientific evaluation of the LR results and the possibilities for life on Mars. Indeed, in part upon misinterpretations of the new findings, myths have been embedded into the scientific literature of Mars. Based on these myths as key ingredients, a false "standard model" of Martian life potential has been developed. It has been accepted by much of the astrobiological community, and, through its endorsement, the world at large. This paper attempts to bring the supportable facts together in calling for a revision of the current consensus regarding life on Mars. It recommends actions to facilitate the paradigm change.

  14. Mesopotamia: myth and reality

    Directory of Open Access Journals (Sweden)

    Alfred Haldar

    1972-06-01

    Full Text Available Was there a myth relating to the state in ancient Mesopotamia? There were several complexes of such myth. An example of this is Hammurabi, the king of Babylonian dynasty who extended Babylon’s control throughout Mesopotamia. His most important reform was Marduk's rise to a position as the chief deity of the whole kingdom. Whether or not the Epic of Creation obtained its final literary form in the reign of Hammurabi is a question, which is not easily answered. There is sufficient evidence of the main features of Marduk's character before Hammurabi's reign, but quite another question is that of the literary process. In any case, Marduk's position as the chief deity of the realm coincided with Hammurabi's adopting the feudal system of administration. In the Ur III period, as we have seen, the early system still prevailed, and the earlier city states continued their existence, although as provinces of the unity. This system was continued in the period of the Isin and Larsa dynasties. In the reign of Shamshi-Adad of Asshur, at any rate, we meet with a typical feudal system, as is evident, for instance, from his correspondence with his son Yasmah-Adad, viceroy of Mari. This system implies that the king considered himself the possessor of the ground, particularly such as belonged to the temples, and its products as well.

  15. MYTH. OTHERNESS DISCOURSE

    Directory of Open Access Journals (Sweden)

    Liliana G. VOȘ

    2015-11-01

    Full Text Available The aim of the study is to explain the concept of otherness as a mythical dimension of the man as a creator in the context of contemporary drama. The approach is a hermeneutics one, but the intention is to extend the analysis towards an interdisciplinary approach due to the multiple ways that otherness reveals on the background of the insular space of the theater as interface of cultural and social. We wish to draw attention to the mythical-symbolic elements that catalyzes the relation between drama and its putting on stage . In our point of view the importance of the drama is the revealing the way that a prototype lives in everyone and the myth is a generating center of identities and otherness in a World of correlations. Mythical models are bringing the imaginary and objectivity into a manageable collaboration that resonate a sense of reality in order to make seen the unseen by ritual as a link between myth and culture.

  16. Between myth and reality

    DEFF Research Database (Denmark)

    Hyldegård, Jette

    Many myths exist about the Google Generation which tend to overestimate the positive impact of ICT’s on young people. This paper presents and discusses the results of an exploratory case study of 43 Danish secondary school pupils’ information behaviour. Four research questions guided the study: 1......, this ‘optimal’ behaviour was found to be in conflict with a rational approach to information practice across secondary school pupils.......Many myths exist about the Google Generation which tend to overestimate the positive impact of ICT’s on young people. This paper presents and discusses the results of an exploratory case study of 43 Danish secondary school pupils’ information behaviour. Four research questions guided the study: 1......) What characterises the information behaviour of Danish secondary school pupils? 2) Does the information behaviour differ across year of study? If so, in which way does it differ? 3) How is information seeking conceptualized and experienced? 4) How is the study centre and library conceptualized...

  17. CO2-Water-Rock Wettability: Variability, Influencing Factors, and Implications for CO2Geostorage.

    Science.gov (United States)

    Iglauer, Stefan

    2017-05-16

    Carbon geosequestration (CGS) has been identified as a key technology to reduce anthropogenic greenhouse gas emissions and thus significantly mitigate climate change. In CGS, CO 2 is captured from large point-source emitters (e.g., coal fired power stations), purified, and injected deep underground into geological formations for disposal. However, the CO 2 has a lower density than the resident formation brine and thus migrates upward due to buoyancy forces. To prevent the CO 2 from leaking back to the surface, four trapping mechanisms are used: (1) structural trapping (where a tight caprock acts as a seal barrier through which the CO 2 cannot percolate), (2) residual trapping (where the CO 2 plume is split into many micrometer-sized bubbles, which are immobilized by capillary forces in the pore network of the rock), (3) dissolution trapping (where CO 2 dissolves in the formation brine and sinks deep into the reservoir due to a slight increase in brine density), and (4) mineral trapping (where the CO 2 introduced into the subsurface chemically reacts with the formation brine or reservoir rock or both to form solid precipitates). The efficiency of these trapping mechanisms and the movement of CO 2 through the rock are strongly influenced by the CO 2 -brine-rock wettability (mainly due to the small capillary-like pores in the rock which form a complex network), and it is thus of key importance to rigorously understand CO 2 -wettability. In this context, a substantial number of experiments have been conducted from which several conclusions can be drawn: of prime importance is the rock surface chemistry, and hydrophilic surfaces are water-wet while hydrophobic surfaces are CO 2 -wet. Note that CO 2 -wet surfaces dramatically reduce CO 2 storage capacities. Furthermore, increasing pressure, salinity, or dissolved ion valency increases CO 2 -wettability, while the effect of temperature is not well understood. Indeed theoretical understanding of CO 2 -wettability and the

  18. Carbon Dioxide Clusters: (CO_2)_6 to (CO_2)13

    Science.gov (United States)

    McKellar, A. R. W.; Oliaee, J. Norooz; Dehghany, M.; Moazzen-Ahmadi, N.

    2011-06-01

    We recenty reported assignments of specific infrared bands in the CO_2 νb{3} region (˜2350 wn) to (CO_2)_6, (CO_2)_7, (CO_2)_9, (CO_2)10, (CO_2)11, (CO_2)12, and (CO_2)13. Spectra are obtained by direct absorption using a rapid-scan tuneable diode laser spectrometer to probe a pulsed supersonic slit-jet expansion and assignments are facilitated by recent calculations of Takeuchi based on the Murthy potential. (CO_2)_6 is a symmetric top with S_6 point group symmetry which can be thought of as a stack of two planar cyclic trimers. (CO_2)13 is also an S_6 symmetric top, and consists of a single CO_2 monomer surrounded by an slightly distorted icosahedral cage. The remaining clusters are asymmetric tops without symmetry. Here we report additional CO_2 cluster results. Calculations based on the SAPT-s potential indicate that the structure of (CO_2)10 may be slightly different from that given by Takeuchi/Murthy. An additional band is observed for each of (CO_2)13 and (CO_2)10. A feature observed at 2378.2 wn is assigned as a (CO_2)_6 parallel combination band involving the sum of a fundamental and a low-lying intermolecular vibration. Most significantly, two bands are assigned to a second isomer of (CO_2)_6. This is also a symmetric top, but now with S_4 symmetry. The two symmetric hexamer isomers observed spectroscopically correspond well with the lowest energy structures given by both the SAPT-s and Murthy intermolecular potentials. [1] J. Norooz Oliaee, M. Dehgany, N. Moazzen-Ahmadi, and A.R.W. McKellar, Phys. Chem. Chem. Phys. 13, 1297 (2011). [2] H. Takeuchi, J. Phys. Chem. A 107, 5703 (2008); C.S. Murthy, S.F. O'Shea, and I.R. McDonald, Mol. Phys. 50, 531 (1983). [3] R. Bukowski, J. Sadlej, B. Jeziorski, P. Jankowski, K. Szalewicz, S.A. Kucharski, H.L. Williams, and B.M. Rice, J. Chem. Phys. 110, 3785 (1999)

  19. Direct CO2-Methanation of flue gas

    Science.gov (United States)

    Müller, Klaus; Fleige, Michael; Rachow, Fabian; Israel, Johannes; Schmeißer, Dieter

    2013-04-01

    Already discovered by Paul Sabatier in 1902 the Hydrogenation according to CO2 + 4H2 ->CH4 + 2H2O nowadays is discussed in the course of the "Power-to-Gas" approach to utilize excess energy from renewable electricity generation in times of oversupply of electricity. We investigate the behavior of this process in a simulated flue gas atmosphere of conventional base load power plants, which could be used as constant sources of the reactant CO2. In relation to an approach related to carbon capture and cycling, the conversion of CO2 directly from the flue gas of a conventional power plant is a new aspect and has several advantages: The conversion of CO2 into methane could be integrated directly into the combustion process. Even older power plants could be upgraded and used as a possible source for CO2, in the same sense as the amine cleaning of flue gas, as a post combustion process. Further, waste heat of the power plant could be used as process energy for the catalytic reaction. Therefore the influence of different flue gas compositions such as varying contents of nitrogen and residual oxygen are tested in a laboratory scale. The heterogeneous catalysis process is investigated with regard to conversion rates, yield and selectivity and long-term stability of the Ni-catalyst. Also the influence of typical contaminations like SO2 is investigated and will be presented.

  20. CO2 and CO simulations and their source signature indicated by CO/CO2

    Science.gov (United States)

    Kawa, S. R.; Bian, H.

    2004-12-01

    Three years (2000-2002) atmospheric CO2 and CO fields are simulated by a Chemistry Transport Model driven by the assimilated meteorological fields from GEOS_4. The simulated CO2 and CO are evaluated by measurements from surface (CMDL), satellite (MOPITT/CO), and aircraft. The model-observation comparisons indicate reasonable agreement in both source and remote regions, and in the lower and upper troposphere. The simulation also captures the seasonality of CO2 and CO variations. The ratios of CO/CO2 are analyzed over different representative regions to identify the source signature, since the anthropogenic CO comes from the same combustion processes as CO2. This work enables us to improve satellite inversion estimates of CO2 sources and sinks by simultaneously using satellite CO measurement.

  1. CO2 sensing and CO2 regulation of stomatal conductance: advances and open questions

    Science.gov (United States)

    Engineer, Cawas; Hashimoto-Sugimoto, Mimi; Negi, Juntaro; Israelsson-Nordstrom, Maria; Azoulay-Shemer, Tamar; Rappel, Wouter-Jan; Iba, Koh; Schroeder, Julian

    2015-01-01

    Guard cells form epidermal stomatal gas exchange valves in plants and regulate the aperture of stomatal pores in response to changes in the carbon dioxide (CO2) concentration in leaves. Moreover, the development of stomata is repressed by elevated CO2 in diverse plant species. Evidence suggests that plants can sense CO2 concentration changes via guard cells and via mesophyll tissues in mediating stomatal movements. We review new discoveries and open questions on mechanisms mediating CO2-regulated stomatal movements and CO2 modulation of stomatal development, which together function in CO2-regulation of stomatal conductance and gas exchange in plants. Research in this area is timely in light of the necessity of selecting and developing crop cultivars which perform better in a shifting climate. PMID:26482956

  2. CO2-Switchable Membranes Prepared by Immobilization of CO2-Breathing Microgels.

    Science.gov (United States)

    Zhang, Qi; Wang, Zhenwu; Lei, Lei; Tang, Jun; Wang, Jianli; Zhu, Shiping

    2017-12-20

    Herein, we report the development of a novel CO 2 -responsive membrane system through immobilization of CO 2 -responsive microgels into commercially available microfiltration membranes using a method of dynamic adsorption. The microgels, prepared from soap-free emulsion polymerization of CO 2 -responsive monomer 2-(diethylamino)ethyl methacrylate (DEA), can be reversibly expanded and shrunken upon CO 2 /N 2 alternation. When incorporated into the membranes, this switching behavior was preserved and further led to transformation between microfiltration and ultrafiltration membranes, as indicated from the dramatic changes on water flux and BSA rejection results. This CO 2 -regulated performance switching of membranes was caused by the changes of water transportation channel, as revealed from the dynamic water contact angle tests and SEM observation. This work represents a simple yet versatile strategy for making CO 2 -responsive membranes.

  3. CO2 and CO Simulations and Their Source Signature Indicated by CO/CO2

    Science.gov (United States)

    Kawa, Randy; Huisheng, Bian

    2004-01-01

    Three years (2000-2002) atmospheric CO2 and CO fields are simulated by a Chemistry Transport Model driven by the assimilated meteorological fields from GEOS-4. The simulated CO2 and CO are evaluated by measurements from surface (CMDL), satellite (MOPITT/CO), and aircraft. The model-observation comparisons indicate reasonable agreement in both source and remote regions, and in the lower and upper troposphere. The simulation also captures the seasonality of CO2 and CO variations. The ratios of CO/CO2 are analyzed over different representative regions to identify the source signature, since the anthropogenic CO comes fiom the same combustion processes as CO2. This work enables us to improve satellite inversion estimates of CO2 sources and sinks by simultaneously using satellite CO measurement.

  4. Worldwide Airfield Summary

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The Worldwide Airfield Summary contains a selection of climatological data produced by the U.S. Air Force, Air Weather Service. The reports were compiled from dozens...

  5. Metal-CO2 Batteries on the Road: CO2 from Contamination Gas to Energy Source.

    Science.gov (United States)

    Xie, Zhaojun; Zhang, Xin; Zhang, Zhang; Zhou, Zhen

    2017-04-01

    Rechargeable nonaqueous metal-air batteries attract much attention for their high theoretical energy density, especially in the last decade. However, most reported metal-air batteries are actually operated in a pure O2 atmosphere, while CO2 and moisture in ambient air can significantly impact the electrochemical performance of metal-O2 batteries. In the study of CO2 contamination on metal-O2 batteries, it has been gradually found that CO2 can be utilized as the reactant gas alone; namely, metal-CO2 batteries can work. On the other hand, investigations on CO2 fixation are in focus due to the potential threat of CO2 on global climate change, especially for its steadily increasing concentration in the atmosphere. The exploitation of CO2 in energy storage systems represents an alternative approach towards clean recycling and utilization of CO2 . Here, the aim is to provide a timely summary of recent achievements in metal-CO2 batteries, and inspire new ideas for new energy storage systems. Moreover, critical issues associated with reaction mechanisms and potential directions for future studies are discussed. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  6. Measuring Nitrous Oxide Mass Transfer into Non-Aqueous CO2BOL CO2 Capture Solvents

    Energy Technology Data Exchange (ETDEWEB)

    Whyatt, Greg A.; Freeman, Charles J.; Zwoster, Andy; Heldebrant, David J.

    2016-03-28

    This paper investigates CO2 absorption behavior in CO2BOL solvents by decoupling the physical and chemical effects using N2O as a non-reactive mimic. Absorption measurements were performed using a wetted-wall contactor. Testing was performed using a “first generation” CO2 binding organic liquid (CO2BOL), comprised of an independent base and alcohol. Measurements were made with N2O at a lean (0.06 mol CO2/mol BOL) and rich (0.26 mol CO2/mol BOL) loading, each at three temperatures (35, 45 and 55 °C). Liquid-film mass transfer coefficients (kg') were calculated by subtracting the gas film resistance – determined from a correlation from literature – from the overall mass transfer measurement. The resulting kg' values for N2O in CO2BOLs were found to be higher than that of 5 M aqueous MEA under comparable conditions, which is supported by published measurements of Henry’s coefficients for N2O in various solvents. These results suggest that the physical solubility contribution for CO2 absorption in CO2BOLs is greater than that of aqueous amines, an effect that may pertain to other non-aqueous solvents.

  7. THE HIGH GAIN CO2 LASER BY EFFECTIVE MIXING OF N2 AND CO2 GAS

    OpenAIRE

    Hara, H.; Fujisawa, A.

    1980-01-01

    A high-gain CO2 laser is described in which vibrationally excited N2 gas and cold CO2 gas are mixed effectively by means of the diffusion of CO2 gas into N2 gas. By using different types of mixing techniques, a maximum gain of 11 m-1 was obtained when CO2 gas was injected parallel to the expanding N2 gas flow. An output power of 4 W was obtained from an 1.2 cm active length. In addition, He gas addition to the N2 gas flow was found to decrease the small-signal gain with increasing He gas flow...

  8. Investigation into Optimal CO2 Concentration for CO2 Capture from Aluminium Production

    OpenAIRE

    Mathisen, Anette; Sørensen, Henriette; Melaaen, Morten; Müller, Gunn-Iren

    2013-01-01

    Capture of CO2 from aluminum production has been simulated using Aspen Plus and Aspen Hysys. The technology used for aluminum production is the Hall-Héroult and the current cell design necessitates that large amounts of false air is supplied to the cells. This results in a CO2 concentration in the process gas at around 1 vol%, which is considered uneconomical for CO2 capture. Therefore, the aim of this investigation is to evaluate the CO2 capture from aluminum production when the process gas ...

  9. Behavior of CO2/water flow in porous media for CO2geological storage.

    Science.gov (United States)

    Jiang, Lanlan; Yu, Minghao; Liu, Yu; Yang, Mingjun; Zhang, Yi; Xue, Ziqiu; Suekane, Tetsuya; Song, Yongchen

    2017-04-01

    A clear understanding of two-phase fluid flow properties in porous media is of importance to CO 2 geological storage. The study visually measured the immiscible and miscible displacement of water by CO 2 using MRI (magnetic resonance imaging), and investigated the factor influencing the displacement process in porous media which were filled with quartz glass beads. For immiscible displacement at slow flow rates, the MR signal intensity of images increased because of CO 2 dissolution; before the dissolution phenomenon became inconspicuous at flow rate of 0.8mLmin -1 . For miscible displacement, the MR signal intensity decreased gradually independent of flow rates, because supercritical CO 2 and water became miscible in the beginning of CO 2 injection. CO 2 channeling or fingering phenomena were more obviously observed with lower permeable porous media. Capillary force decreases with increasing particle size, which would increase permeability and allow CO 2 and water to invade into small pore spaces more easily. The study also showed CO 2 flow patterns were dominated by dimensionless capillary number, changing from capillary finger to stable flow. The relative permeability curve was calculated using Brooks-Corey model, while the results showed the relative permeability of CO 2 slightly decreases with the increase of capillary number. Copyright © 2016 Elsevier Inc. All rights reserved.

  10. The Abundance of Atmospheric CO2 in Ocean Exoplanets: a Novel CO2 Deposition Mechanism

    Science.gov (United States)

    Levi, A.; Sasselov, D.; Podolak, M.

    2017-03-01

    We consider super-Earth sized planets which have a water mass fraction large enough to form an external mantle composed of high-pressure water-ice polymorphs and also lack a substantial H/He atmosphere. We consider such planets in their habitable zone, so that their outermost condensed mantle is a global, deep, liquid ocean. For these ocean planets, we investigate potential internal reservoirs of CO2, the amount of CO2 dissolved in the ocean for the various saturation conditions encountered, and the ocean-atmosphere exchange flux of CO2. We find that, in a steady state, the abundance of CO2 in the atmosphere has two possible states. When wind-driven circulation is the dominant CO2 exchange mechanism, an atmosphere of tens of bars of CO2 results, where the exact value depends on the subtropical ocean surface temperature and the deep ocean temperature. When sea-ice formation, acting on these planets as a CO2 deposition mechanism, is the dominant exchange mechanism, an atmosphere of a few bars of CO2 is established. The exact value depends on the subpolar surface temperature. Our results suggest the possibility of a negative feedback mechanism, unique to water planets, where a reduction in the subpolar temperature drives more CO2 into the atmosphere to increase the greenhouse effect.

  11. Exposing the Bathtub Coriolis Myth.

    Science.gov (United States)

    Salzsieder, John C.

    1994-01-01

    Presents a demonstration that employs angular momentum to disprove the myth that water spirals down a bathtub drain clockwise in one hemisphere and counterclockwise in the other because of the Coriolis force on water. (ZWH)

  12. Newton's Principia: Myth and Reality

    Science.gov (United States)

    Smith, George

    2016-03-01

    Myths about Newton's Principia abound. Some of them, such as the myth that the whole book was initially developed using the calculus and then transformed into a geometric mathematics, stem from remarks he made during the priority controversy with Leibniz over the calculus. Some of the most persistent, and misleading, arose from failures to read the book with care. Among the latter are the myth that he devised his theory of gravity in order to explain the already established ``laws'' of Kepler, and that in doing so he took himself to be establishing that Keplerian motion is ``absolute,'' if not with respect to ``absolute space,'' then at least with respect to the fixed stars taken as what came later to be known as an inertial frame. The talk will replace these two myths with the reality of what Newton took himself to have established.

  13. Filtering Dialysis Myths from Facts

    Science.gov (United States)

    ... Menu Menu Search Home Prevention Kidney Disease Patients Organ Donation & Transplantation Professionals Events Advocacy Donate A to Z ... the area if needed. Myth: Dialysis is a death sentence. Fact: Dialysis is a treatment that helps ...

  14. Contraception. Myths, facts and methods.

    Science.gov (United States)

    Perlman, S E; Richmond, D M; Sabatini, M M; Krueger, H; Rudy, S J

    2001-02-01

    After reading this article, the reader should be able to: 1. Recognize the mechanism of action, side effects, contraindications, precautions and instructions for use of a variety of contraceptive methods. 2. Understand the advantages and disadvantages of the various contraceptive methods. 3. List the common myths and misconceptions about conception and contraception, and recognize how they can influence contraceptive decisions. Unintended pregnancy is a serious problem in the United States. Counseling a patient about conception and contraception involves more than simply imparting information and answering questions. Clinicians should actively detect and correct any myths and misapprehensions on the patient's part. These myths are quite common and can interfere with treatment if not attended to. This article summarizes common myths about pregnancy and contraception and reviews the key facts about both.

  15. Chilled Ammonia Process for CO2 Capture

    DEFF Research Database (Denmark)

    Darde, Victor Camille Alfred; Thomsen, Kaj; Well, Willy J.M. van

    2010-01-01

    The chilled ammonia process absorbs the CO2 at low temperature (2–10°C). The heat of absorption of carbon dioxide by ammonia is significantly lower than for amines. In addition, degradation problems can be avoided and a high carbon dioxide capacity is achieved. Hence, this process shows good...... perspectives for decreasing the heat requirement. However, a scientific understanding of the processes is required. The thermodynamic properties of the NH3–CO2–H2O system were described using the extended UNIQUAC electrolyte model developed by Thomsen and Rasmussen in a temperature range from 0 to 110°C...... and pressure up to 100bars. The results show that solid phases consisting of ammonium carbonate and bicarbonate are formed in the absorber. The heat requirements in the absorber and in the desorber have been studied. The enthalpy calculations show that a heat requirement for the desorber lower than 2GJ/ton CO2...

  16. The ATLAS IBL CO2 Cooling System

    CERN Document Server

    AUTHOR|(INSPIRE)INSPIRE-00237783; The ATLAS collaboration; Zwalinski, L.; Bortolin, C.; Vogt, S.; Godlewski, J.; Crespo-Lopez, O.; Van Overbeek, M.; Blaszcyk, T.

    2017-01-01

    The ATLAS Pixel detector has been equipped with an extra B-layer in the space obtained by a reduced beam pipe. This new pixel detector called the ATLAS Insertable B-Layer (IBL) is installed in 2014 and is operational in the current ATLAS data taking. The IBL detector is cooled with evaporative CO2 and is the first of its kind in ATLAS. The ATLAS IBL CO2 cooling system is designed for lower temperature operation (<-35⁰C) than the previous developed CO2 cooling systems in High Energy Physics experiments. The cold temperatures are required to protect the pixel sensors for the high expected radiation dose up to 550 fb^-1 integrated luminosity.

  17. CW CO2 Laser Induced Chemical Reactions

    Science.gov (United States)

    Pola, Joseph

    1989-05-01

    CW CO2 laser driven reactions between sulfur hexafluoride and carbon oxide, carbon suboxide, carbonyl sulfide and carbon disulfide proceed at subatmospheric pressures and yield fluorinated carbon compounds and sulfur tetrafluoride. CW CO2 laser driven reactions of organic compounds in the presence of energy-conveying sulfur hexafluoride show reaction course different from that normally observed due to elimination of reactor hot surface effects. The examples concern the decomposition of polychlorohydrocarbons, 2-nitropropane, tert.-butylamine, allyl chloride, spirohexane, isobornyl acetate and the oxidation of haloolefins. CW CO2 laser induced fragmentation of 1-methyl-l-silacyclobutanes and 4-silaspiro(3.4)octane in the presence of sulfur hexafluoride is an effective way for preparation and deposition of stable organosilicon polymers.

  18. CO2 utilization: Developments in conversion processes

    Directory of Open Access Journals (Sweden)

    Erdogan Alper

    2017-03-01

    The potential utilization of CO2, captured at power plants, should also been taken into consideration for sustainability. This CO2 source, which is potentially a raw material for the chemical industry, will be available at sufficient quality and at gigantic quantity upon realization of on-going tangible capture projects. Products resulting from carboxylation reactions are obvious conversions. In addition, provided that enough supply of energy from non-fossil resources, such as solar [1], is ensured, CO2 reduction reactions can produce several valuable commodity chemicals including multi-carbon compounds, such as ethylene and acrylic acid, in addition to C1 chemicals and polymers. Presently, there are only few developing technologies which can find industrial applications. Therefore, there is a need for concerted research in order to assess the viability of these promising exploratory technologies rationally.

  19. The Idea of Global CO2 Trade

    DEFF Research Database (Denmark)

    Svendsen, Gert Tinggaard

    1999-01-01

    The US has been criticized for wanting to earn a fortune on a global CO2 market. However, compared to the situation without trade and provided that such a market is designed so that it does not pay to cheat, a global CO2 market may provide the world with an epoch-making means of cost......-effective control which can solve future global environmental problems. The economic gains from 'hot air' distributions of permits and CO2 trade make the system politically attractive to potential participants. For example, vital financial subsidies from the EU to Eastern Europe are to be expected. It will probably...... not pay to cheat if quotas are renewed periodically by the UN. Cheating countries are then to be excluded from further profitable trade. Also, a periodical renewal of permits makes it possible to tighten target levels in the future....

  20. The Idea of Global CO2 Trade

    DEFF Research Database (Denmark)

    Svendsen, Gert Tinggaard

    1998-01-01

    The US has been criticized for wanting to earn a fortune on a global CO2 market. However, compared to the situation without trade and provided that such a market is designed so that it does not pay to cheat, a global CO2 market may provide the world with an epoch-making means of cost......-effective control which can solve future global environmental problems. The gains from CO2 trade may give vital financial subsidies from the EU to Eastern Europe, for example, and it will probably not pay to cheat if quotas are renewed periodically by the UN. Cheating countries are then to be excluded from further...... profitable trade. Also, a periodical renewal of permits makes it possible to tighten target levels in the future....

  1. Membraneless water filtration using CO2

    Science.gov (United States)

    Shin, Sangwoo; Shardt, Orest; Warren, Patrick B.; Stone, Howard A.

    2017-05-01

    Water purification technologies such as microfiltration/ultrafiltration and reverse osmosis utilize porous membranes to remove suspended particles and solutes. These membranes, however, cause many drawbacks such as a high pumping cost and a need for periodic replacement due to fouling. Here we show an alternative membraneless method for separating suspended particles by exposing the colloidal suspension to CO2. Dissolution of CO2 into the suspension creates solute gradients that drive phoretic motion of particles. Due to the large diffusion potential generated by the dissociation of carbonic acid, colloidal particles move either away from or towards the gas-liquid interface depending on their surface charge. Using the directed motion of particles induced by exposure to CO2, we demonstrate a scalable, continuous flow, membraneless particle filtration process that exhibits low energy consumption, three orders of magnitude lower than conventional microfiltration/ultrafiltration processes, and is essentially free from fouling.

  2. Cutting weeds with a CO2 laser

    DEFF Research Database (Denmark)

    Heisel, T.; Schou, Jørgen; Christensen, S.

    2001-01-01

    Stems of Chenopodium album. and Sinapis arvensis. and leaves of Lolium perenne. were cut with a CO2 laser or with a pair of scissors. Treatments were carried out on greenhouse-grown pot plants at three different growth stages and at two heights. Plant dry matter was measured 2 to 5 weeks after...... treatment. The relationship between dry weight and laser energy was analysed using a non-linear dose-response regression model. The regression parameters differed significantly between the weed species. At all growth stages and heights S. arvensis was more difficult to cut with a CO2 laser than C. album....... When stems were cut below the meristems, 0.9 and 2.3 J mm(-1) of CO2 laser energy dose was sufficient to reduce by 90% the biomass of C. album and S. arvensis respectively. Regrowth appeared when dicotyledonous plant stems were cut above meristems, indicating that it is important to cut close...

  3. Equilibrium Solubility of CO2 in Alkanolamines

    DEFF Research Database (Denmark)

    Waseem Arshad, Muhammad; Fosbøl, Philip Loldrup; von Solms, Nicolas

    2014-01-01

    Equilibrium solubility of CO2 were measured in aqueous solutions of Monoethanolamine (MEA) and N,N-diethylethanolamine(DEEA). Equilibrium cells are generally used for these measurements. In this study, the equilibrium data were measured from the calorimetry. For this purpose a reaction calorimeter...... (model CPA 122 from ChemiSens AB, Sweden) was used. The advantage of this method is being the measurement of both heats of absorption and equilibrium solubility data of CO2 at the same time. The measurements were performed for 30 mass % MEA and 5M DEEA solutions as a function of CO2 loading at three...... different temperatures 40, 80 and 120 ºC. The measured 30 mass % MEA and 5M DEEA data were compared with the literature data obtained from different equilibrium cells which validated the use of calorimeters for equilibrium solubility measurements....

  4. Oxygen isotope fractionation in stratospheric CO2

    Science.gov (United States)

    Thiemens, M. H.; Jackson, T.; Mauersberger, K.; Schueler, B.; Morton, J.

    1991-01-01

    A new cryogenic collection system has been flown on board a balloon gondola to obtain separate samples of ozone and carbon dioxide without entrapping major atmospheric gases. Precision laboratory isotopic analysis of CO2 samples collected between 26 and 35.5 km show a mass-independent enrichment in both O-17 and O-18 of about 11 per mil above tropospheric values. Ozone enrichment in its heavy isotopes was 9 to 16 percent in O3-50 and 8 to 11 percent in O3-49, respectively (Schueler et al., 1990). A mechanism to explain the isotope enrichment in CO2 has been recently proposed by Yung et al. (1991). The model is based on the isotope exchange between CO2 and O3 via O(1D), resulting in a transfer of the ozone isotope enrichment to carbon dioxide. Predicted enrichment and measured values agree well.

  5. Kronikken: Handel og handling med CO2

    DEFF Research Database (Denmark)

    Andersen, M. S.

    2000-01-01

    De fleksible mekanismer i Kyoto-aftalen fortjener indgående overvejelser, ikke kun fordi de giver mulighed for en rabat på CO2-reduktionen, men også fordi de rummer globale og sikkerhedspolitiske dimensioner som er essentielle.......De fleksible mekanismer i Kyoto-aftalen fortjener indgående overvejelser, ikke kun fordi de giver mulighed for en rabat på CO2-reduktionen, men også fordi de rummer globale og sikkerhedspolitiske dimensioner som er essentielle....

  6. Do Tree Stems Recapture Respired CO2?

    Science.gov (United States)

    Hilman, B.; Angert, A.

    2016-12-01

    Tree stem respiration is an important, yet not well understood, component of the terrestrial carbon cycle. Predicting how trees as whole organisms respond to changes in climate and atmospheric CO2 requires understanding of the variability in the fraction of assimilated carbon allocated to respiration, versus the allocation to growth, damage repair, and to rhizosphere symbionts. Here we used the ratio of CO2 efflux/O2 influx (Apparent Respiratory Quotient, ARQ) to study stem respiration. The ARQ in trees stems is predicted to be 1.0, as a result of carbohydrates metabolism. Lower than 1.0 ARQ values may indicate a local assimilation of respired CO2, or dissolution and transport of CO2 in the xylem stream. We measured stems ARQ in 16 tree species at tropical, Mediterranean and temperate ecosystems using stem chambers and in-vitro incubations. The CO2 and O2 were measured by a system we developed, which is based on an IRGA and a Fuel-cell O2 analyzer (Hilman and Angert 2016). We found typical values of ARQ in the range of 0.4-0.8. Since incubations of detach stem tissues yielded similar ARQ values, and since the influence of natural variations in the transpiration stream on ARQ was found to be small, we conclude that the removal of the respired CO2 is not via dissolution in the xylem stream. Using 13C labeling, dark fixation of stem tissues was detected, which is most probably phosphoenolpyruvate carboxylase (PEPC) mediated. Hence, we suggest that in-stem dark fixation of respired CO2 to organic acids (e.g. malate) affects the outgoing efflux. Further research should determine if these organic acids are transported to the canopy, stored in the stem, or transported to the roots to serve as exudates. Hilman B, Angert A (2016) Measuring the ratio of CO2 efflux to O2 influx in tree stem respiration. Tree Physiol 2016, doi: 10.1093/treephys/tpw057

  7. 10 MW Supercritical CO2 Turbine Test

    Energy Technology Data Exchange (ETDEWEB)

    Turchi, Craig

    2014-01-29

    The Supercritical CO2 Turbine Test project was to demonstrate the inherent efficiencies of a supercritical carbon dioxide (s-CO2) power turbine and associated turbomachinery under conditions and at a scale relevant to commercial concentrating solar power (CSP) projects, thereby accelerating the commercial deployment of this new power generation technology. The project involved eight partnering organizations: NREL, Sandia National Laboratories, Echogen Power Systems, Abengoa Solar, University of Wisconsin at Madison, Electric Power Research Institute, Barber-Nichols, and the CSP Program of the U.S. Department of Energy. The multi-year project planned to design, fabricate, and validate an s-CO2 power turbine of nominally 10 MWe that is capable of operation at up to 700°C and operates in a dry-cooled test loop. The project plan consisted of three phases: (1) system design and modeling, (2) fabrication, and (3) testing. The major accomplishments of Phase 1 included: Design of a multistage, axial-flow, s-CO2 power turbine; Design modifications to an existing turbocompressor to provide s-CO2 flow for the test system; Updated equipment and installation costs for the turbomachinery and associated support infrastructure; Development of simulation tools for the test loop itself and for more efficient cycle designs that are of greater commercial interest; Simulation of s-CO2 power cycle integration into molten-nitrate-salt CSP systems indicating a cost benefit of up to 8% in levelized cost of energy; Identification of recuperator cost as a key economic parameter; Corrosion data for multiple alloys at temperatures up to 650ºC in high-pressure CO2 and recommendations for materials-of-construction; and Revised test plan and preliminary operating conditions based on the ongoing tests of related equipment. Phase 1 established that the cost of the facility needed to test the power turbine at its full power and temperature would exceed the planned funding for Phases 2 and 3. Late

  8. Modelling the Martian CO2 Ice Clouds

    Science.gov (United States)

    Listowski, Constantino; Määttänen, A.; Montmessin, F.; Lefèvre, F.

    2012-10-01

    Martian CO2 ice cloud formation represents a rare phenomenon in the Solar System: the condensation of the main component of the atmosphere. Moreover, on Mars, condensation occurs in a rarefied atmosphere (large Knudsen numbers, Kn) that limits the growth efficiency. These clouds form in the polar winter troposphere and in the mesosphere near the equator. CO2 ice cloud modeling has turned out to be challenging: recent efforts (e.g. [1]) fail in explaining typical small sizes (80 nm-130 nm) observed for mesospheric clouds [2]. Supercold pockets (TWood, S. E., (1999), Ph.D. thesis, UCLA [6] Young, J. B., J. Geophys. Res., 36, 294-2956, 1993

  9. CO2 flux from Javanese mud volcanism

    OpenAIRE

    Quei?er, M.; Burton, M.; Arzilli, F.; Chiarugi, A.; Marliyani, G.I; Anggara, F.; Harijoko, A.

    2017-01-01

    Abstract Studying the quantity and origin of CO2 emitted by back?arc mud volcanoes is critical to correctly model fluid?dynamical, thermodynamical, and geochemical processes that drive their activity and to constrain their role in the global geochemical carbon cycle. We measured CO2 fluxes of the Bledug Kuwu mud volcano on the Kendeng Fold and thrust belt in the back arc of Central Java, Indonesia, using scanning remote sensing absorption spectroscopy. The data show that the expelled gas is r...

  10. Toxic emissions and devaluated CO2-neutrality

    DEFF Research Database (Denmark)

    Czeskleba-Dupont, Rolf

    Environmental, energy and climate policies need fresh reflections. In order to evaluate toxics reduction policies the Stockholm Convention on Persistent Organic Pollutants is mandatory. Denmark's function as lead country for dioxin research in the context of the OSPAR Convention is contrasted...... with a climate policy whose goals of CO2-reduction were made operational by green-wash. Arguments are given for the devaluation of CO2- neutrality in case of burning wood. Alternative practices as storing C in high quality wood products and/or leaving wood in the forest are recommended. A counter...

  11. Leak Path Development in CO2 Wells

    Science.gov (United States)

    Torsater, M.; Todorovic, J.; Opedal, N.; Lavrov, A.

    2014-12-01

    Wells have in numerous scientific works been denoted the "weak link" of safe and cost-efficient CO2 Capture and Storage (CCS). Whether they are active or abandoned, all wells are man-made intrusions into the storage reservoir with sealing abilities depending on degradable materials like steel and cement. If dense CO2 is allowed to expand (e.g. due to leakage) it will cool down its surroundings and cause strong thermal and mechanical loading on the wellbore. In addition, CO2 reacts chemically with rock, cement and steel. To ensure long-term underground containment, it is therefore necessary to study how, why, where and when leakage occurs along CO2wells. If cement bonding to rock or casing is poor, leak paths can form already during drilling and completion of the well. In the present work, we have mapped the bonding quality of cement-rock and cement-steel interfaces - and measured their resistance towards CO2 flow. This involved a large experimental matrix including different rocks, steels, cement types and well fluids. The bonding qualities were measured on composite cores using micro computed tomography (µ-CT), and CO2 was flooded through the samples to determine leakage rates. These were further compared to numerical simulations of leakage through the digitalized µ-CT core data, and CO2chemical interactions with the materials were mapped using electron microscopy. We also present a new laboratory set-up for measuring how well integrity is affected by downhole temperature variations - and we showcase some initial results. Our work concludes that leak path development in CO2 wells depends critically on the drilling fluids and presflushes/spacers chosen already during drilling and completion of a well. Fluid films residing on rock and casing surfaces strongly degrade the quality of cement bonding. The operation of the well is also important, as even slight thermal cycling (between 10°C and 95°C on casing) leads to significant de-bonding of the annular cement.

  12. Myths About Press Freedom

    Directory of Open Access Journals (Sweden)

    Kaarle Nordenstreng

    2007-06-01

    Full Text Available This article intends to rectify three popular beliefs related to press freedom: (1 that the idea of a free marketplace of ideas with a self-righting truth belongs to original liberalism, (2 that UNESCO’s primary mission is to promote freedom of information, and (3 that the Universal Declaration of Human Rights provides legal safeguards for the media. These beliefs are shown, on the basis of the legacy of liberalism and documents of the international community, to be misleading myths. Instead of accurate readings of the idea of freedom, they serve as ideological positions which are harmful to democracy. The Millennium Declaration provides further proof that the international community has a much more balanced view of freedom of information than that typically held by media professionals. Therefore it is important to liberate the concept of press freedom from its ideological baggage.

  13. Sustained effects of atmospheric [CO2] and nitrogen availability on forest soil CO2 efflux

    Science.gov (United States)

    A. Christopher Oishi; Sari Palmroth; Kurt H. Johnsen; Heather R. McCarthy; Ram. Oren

    2014-01-01

    Soil CO2 efflux (Fsoil) is the largest source of carbon from forests and reflects primary productivity as well as how carbon is allocated within forest ecosystems. Through early stages of stand development, both elevated [CO2] and availability of soil nitrogen (N; sum of mineralization, deposition, and fixation) have been shown to increase gross primary productivity,...

  14. Uncertainties in the CO2 buget associated to boundary layer dynamics and CO2-advection

    NARCIS (Netherlands)

    Kaikkonen, J.P.; Pino, D.; Vilà-Guerau de Arellano, J.

    2012-01-01

    The relationship between boundary layer dynamics and carbon dioxide (CO2) budget in the convective boundary layer (CBL) is investigated by using mixed-layer theory. We derive a new set of analytical relations to quantify the uncertainties on the estimation of the bulk CO2 mixing ratio and the

  15. Heterotrophic fixation of CO2 in soil

    Czech Academy of Sciences Publication Activity Database

    Šantrůčková, Hana; Bird, M. I.; Elhottová, Dana; Novák, Jaroslav; Picek, T.; Šimek, Miloslav; Tykva, Richard

    2005-01-01

    Roč. 49, č. 2 (2005), s. 218-225 ISSN 0095-3628 R&D Projects: GA ČR(CZ) GA206/02/1036; GA AV ČR(CZ) IAA6066901 Institutional research plan: CEZ:AV0Z60660521 Keywords : heterotrophic fixation * CO2 * soil Subject RIV: EH - Ecology, Behaviour Impact factor: 2.674, year: 2005

  16. Carbon dioxide (CO2) utilizing strain database

    African Journals Online (AJOL)

    Jane

    2011-10-17

    Oct 17, 2011 ... Culling of excess carbon dioxide from our environment is one of the major challenges to scientific communities. Many physical, chemical and biological methods have been practiced to overcome this problem. The biological means of CO2 fixation using various microorganisms is gaining importance.

  17. 76 FR 15249 - Deferral for CO2

    Science.gov (United States)

    2011-03-21

    ... From the Federal Register Online via the Government Publishing Office ENVIRONMENTAL PROTECTION AGENCY 40 CFR Parts 51, 52, 70, and 71 RIN 2060-AQ79 Deferral for CO2 Emissions From Bioenergy and Other Biogenic Sources Under the Prevention of Significant Deterioration (PSD) and Title V Programs: Proposed...

  18. Artificial photosynthesis - CO2 towards methanol

    Science.gov (United States)

    Nazimek, D.; Czech, B.

    2011-03-01

    The new insight into the problem of carbon dioxide utilization into valuable compound - methanol and then its transformation into fuel is presented. Because the highly endothermic requirements of the reaction of CO2 hydrogenation a photocatalytic route is applied. Combining of the two reactions: water splitting and CO2 hydrogenation using H2O as a source of hydrogen at the same time and place are proposed. The studies over modified TiO2 catalysts supported on Al2O3 were conducted in a self-designed circulated photocatalytic reaction system under at room temperature and constant pressure. Experimental results indicated that the highest yield of the photoreduction of CO2 with H2O were obtained using TiO2 with the active anatase phase modified by Ru and WO3 addition. The conversion was very high - almost 97% of CO2 was transformed mainly into methanol (14%vol.) and into small amount of formic and acetic acid and ester.

  19. Iconic CO2 Time Series at Risk

    NARCIS (Netherlands)

    Houweling, S.; Badawy, B.; Basu, S.; Krol, M.C.; Röckmann, T.; Vermeulen, A.

    2012-01-01

    THE STEADY RISE IN ATMOSPHERIC LONGlived greenhouse gas concentrations is the main driver of contemporary climate change. The Mauna Loa CO2 time series (1, 2), started by C. D. Keeling in 1958 and maintained today by the Scripps Institution of Oceanography and the Earth System Research Laboratory

  20. Bosch CO2 Reduction System Development

    Science.gov (United States)

    Holmes, R. F.; King, C. D.; Keller, E. E.

    1976-01-01

    Development of a Bosch process CO2 reduction unit was continued, and, by means of hardware modifications, the performance was substantially improved. Benefits of the hardware upgrading were demonstrated by extensive unit operation and data acquisition in the laboratory. This work was accomplished on a cold seal configuration of the Bosch unit.

  1. Harvesting Energy from CO2 Emissions

    NARCIS (Netherlands)

    Hamelers, H.V.M.; Schaetzle, O.; Paz-García, J.M.; Biesheuvel, P.M.; Buisman, C.J.N.

    2014-01-01

    When two fluids with different compositions are mixed, mixing energy is released. This holds true for both liquids and gases, though in the case of gases, no technology is yet available to harvest this energy source. Mixing the CO2 in combustion gases with air represents a source of energy with a

  2. Dispelling Seven Myths about Grid Resource Management

    National Research Council Canada - National Science Library

    Natrajan, Anand; Grimshaw, Andrew S; Humphrey, Marty A; Nguyen-Tuong, Anh

    2004-01-01

    ... policies, respecting permissions for use, and so on. In this article we will present seven "myths" or common beliefs about grid resource management and dispel each myth by presenting counter-examples or "observations...

  3. Extraction of lipids from microalgae using CO2-expanded methanol and liquid CO2.

    Science.gov (United States)

    Paudel, Ashok; Jessop, Michael J; Stubbins, Spencer H; Champagne, Pascale; Jessop, Philip G

    2015-05-01

    The use of CO2-expanded methanol (cxMeOH) and liquid carbon dioxide (lCO2) is proposed to extract lipids from Botryococcus braunii. When compressed CO2 dissolves in methanol, the solvent expands in volume, decreases in polarity and so increases in its selectivity for biodiesel desirable lipids. Solid phase extraction of the algal extract showed that the cxMeOH extracted 21 mg of biodiesel desirable lipids per mL of organic solvent compared to 3mg/mL using either neat methanol or chloroform/methanol mixture. The non-polar lCO2 showed a high affinity for non-polar lipids. Using lCO2, it is possible to extract up to 10% neutral lipids relative to the mass of dry algae. Unlike extractions using conventional solvents, these new methods require little to no volatile, flammable, or chlorinated organic solvents. Copyright © 2014 Elsevier Ltd. All rights reserved.

  4. Flash scanning the CO2 laser: a revival of the CO2 laser in plastic surgery

    Science.gov (United States)

    Lach, Elliot

    1994-09-01

    The CO2 laser has broad clinical application yet also presents a number of practical disadvantages. These drawbacks have limited the success and utilization of this laser in plastic surgery. Flashscanner technology has recently been used for char-free CO2 laser surgery of the oropharynx, the external female genital tract, and perirectal mucosa. A commercially available optomechanical flashscanner unit `Swiftlase,' was adapted to a CO2 laser and used for treatment in numerous plastic surgical applications. Conditions and situations that were treated in this study included generalized neurofibromatosis, tuberous sclerosis, rhinophyma, viral warts, breast reconstruction, and deepithelialization prior to microsurgery or local flap transfer and/or skin graft placement. There were no significant wound healing complications. Some patients previously sustained undue scarring from conventional CO2 laser surgery. Conservative, primarily ablative CO2 laser surgery with the Swiftlase has usefulness for treatment of patients in plastic surgery including those that were previously unsuccessfully treated.

  5. The Li–CO2 battery: a novel method for CO2 capture and utilization

    KAUST Repository

    Xu, Shaomao

    2013-01-01

    We report a novel primary Li-CO2 battery that consumes pure CO2 gas as its cathode. The battery exhibits a high discharge capacity of around 2500 mA h g-1 at moderate temperatures. At 100 °C the discharge capacity is close to 1000% higher than that at 40 °C, and the temperature dependence is significantly weaker for higher surface area carbon cathodes. Ex-situ FTIR and XRD analyses convincingly show that lithium carbonate (Li2CO3) is the main component of the discharge product. The feasibility of similar primary metal-CO2 batteries based on earth abundant metal anodes, such as Al and Mg, is demonstrated. The metal-CO2 battery platform provides a novel approach for simultaneous capturing of CO2 emissions and producing electrical energy. © 2013 The Royal Society of Chemistry.

  6. Rapid CO2 permeation across biological membranes: implications for CO2 venting from tissue.

    Science.gov (United States)

    Hulikova, Alzbeta; Swietach, Pawel

    2014-07-01

    The degree to which cell membranes are barriers to CO2 transport remains controversial. Proteins, such as aquaporins and Rh complex, have been proposed to facilitate CO2 transport, implying that the nonchannel component of membranes must have greatly reduced CO2 permeability. To determine whether membrane CO2 permeation is rate limiting for gas transport, the spread of CO2 across multicellular tissue growths (spheroids) was measured using intracellular pH as a spatial readout. Colorectal HCT116 cells have basal water and NH3 permeability, indicating the functional absence of aquaporins and gas channels. However, CO2 diffusivity in HCT116 spheroids was only 24 ± 4% lower than in pure water, which can be accounted for fully by volume exclusion due to proteins. Diffusivity was unaffected by blockers of aquaporins and Rh complex (Hg(2+), p-chloromercuribenzoic acid, and 4,4'-diisothiocyano-2,2'-stilbene-disulfonic acid) but decreased under hypertonic conditions (by addition of 300 mOsm mannitol), which increases intracellular protein crowding. Similar CO2 diffusivity was measured in spheroids of T47D breast cells (basal water permeability) and NHDF-Ad fibroblasts (aquaporin-facilitated water permeability). In contrast, diffusivity of NH3, a smaller but less lipophilic gas, was considerably slower than in pure water, as expected from rate-limiting membrane permeation. In conclusion, membranes, even in the functional absence of proposed gas channels, do not restrict CO2 venting from tissue growths.-Hulikova, A., Swietach, P. Rapid CO2 permeation across biological membranes: implications for CO2 venting from tissue. © FASEB.

  7. Isolation of microorganisms from CO2 sequestration sites through enrichments under high pCO2

    Science.gov (United States)

    Peet, K. C.; Freedman, A. J.; Boreham, C.; Thompson, J. R.

    2012-12-01

    Carbon Capture and Storage (CCS) in geologic formations has the potential to reduce greenhouse gas emissions from fossil fuel processing and combustion. However, little is known about the effects that CO2 may have on biological activity in deep earth environments. To understand microorganisms associated with these environments, we have developed a simple high-pressure enrichment methodology to cultivate organisms capable of growth under supercritical CO2 (scCO2). Growth media targeting different subsurface functional metabolic groups is added to sterilized 316 stainless steel tubing sealed with quarter turn plug valves values and pressurized to 120-136 atm using a helium-padded CO2 tank, followed by incubation at 37 °C to achieve the scCO2 state. Repeated passages of crushed subsurface rock samples and growth media under supercritical CO2 headspaces are assessed for growth via microscopic enumeration. We have utilized this method to survey sandstone cores for microbes capable of growth under scCO2 from two different geologic sites targeted for carbon sequestration activities. Reproducible growth of microbial biomass under high pCO2 has been sustained from each site. Cell morphologies consist of primarily 1-2 μm rods and oval spores, with densities from 1E5-1E7 cells per ml of culture. We have purified and characterized a bacterial strain most closely related to Bacillus subterraneus (99% 16S rRNA identity) capable of growth under scCO2. Preliminary physiological characterization of this strain indicates it is a spore-forming facultative anaerobe able to grow in 0.5 to 50 ppt salinity. Genome sequencing and analysis currently in progress will help reveal genetic mechanisms of acclimation to high pCO2 conditions associated with geologic carbon sequestration.

  8. The Role of the CO2 Laser and Fractional CO2 Laser in Dermatology.

    Science.gov (United States)

    Omi, Tokuya; Numano, Kayoko

    2014-03-27

    Tremendous advances have been made in the medical application of the laser in the past few decades. Many diseases in the dermatological field are now indications for laser treatment that qualify for reimbursement by many national health insurance systems. Among laser types, the carbon dioxide (CO2) laser remains an important system for the dermatologist. The lasers used in photosurgery have wavelengths that differ according to their intended use and are of various types, but the CO2 laser is one of the most widely used lasers in the dermatology field. With its wavelength in the mid-infrared at 10,600 nm, CO2 laser energy is wellabsorbed in water. As skin contains a very high water percentage, this makes the CO2 laser ideal for precise, safe ablation with good hemostasis. In addition to its efficacy in ablating benign raised lesions, the CO2 laser has been reported to be effective in the field of esthetic dermatology in the revision of acne scars as well as in photorejuvenation. With the addition of fractionation of the beam of energy into myriad microbeams, the fractional CO2 laser has offered a bridge between the frankly full ablative indications and the nonablative skin rejuvenation systems of the 2000s in the rejuvenation of photoaged skin on and off the face. The CO2 laser remains an efficient, precise and safe system for the dermatologist. Technological advances in CO2 laser construction have meant smaller spot sizes and greater precision for laser surgery, and more flexibility in tip sizes and protocols for fractional CO2 laser treatment. The range of dermatological applications of the CO2 laser is expected to continue to increase in the future.

  9. The physical origins of rapid soil CO2 release following wetting

    Science.gov (United States)

    Schymanski, Stanislaus; Grahm, Lina; Or, Dani

    2017-04-01

    A rainfall event after an extended dry period is known to produce large spikes in CO2 release from soil, a phenomenon referred to as the "Birch effect". The Birch effect is commonly attributed to biological factors, such as the rapid activation of dormant microbial populations and stimulation of soil organic carbon turnover. Evidence suggests that CO2 emissions set in at time scales too short for microbial activation and growth (seconds to minutes after onset of wetting). We conducted controlled wetting experiments on sterilized soil in the lab showing CO2 efflux dynamics that are consistent in magnitude with those reported in field studies (up to 4 mmol m-2 s-1 per mm of precipitation). The explanation proposed is purely physical, involving desorption of CO2 from soil surfaces as it is replaced by the more polar water during wetting. We present experimental results and a CO2 adsorption and desorption model that lend credence to the notion that a large fraction of the early soil CO2 emission during wetting (minutes to an hour) is associated with physical processes independent of microbial activity. This suggests that a significant amount of atmospheric CO2 becomes bound to soil surfaces during dry seasons and is rapidly released at the onset of wet seasons world-wide, irrespective of the soil organic carbon cycle.

  10. Volcanic CO2 flux measurement at Campi Flegrei by tunable diode laser absorption spectroscopy

    Science.gov (United States)

    Pedone, M.; Aiuppa, A.; Giudice, G.; Grassa, F.; Cardellini, C.; Chiodini, G.; Valenza, M.

    2014-04-01

    Near-infrared room temperature tunable diode lasers (TDL) have recently found increased usage in atmospheric chemistry and air monitoring research, but applications in volcanology are still limited to a few examples. Here, we explored the potential of a commercial infrared laser unit (GasFinder 2.0 from Boreal Laser Ltd) for measurement of volcanic CO2 mixing ratios, and ultimately for estimating the volcanic CO2 flux. Our field tests were conducted at Campi Flegrei near Pozzuoli, Southern Italy, where the GasFinder was used during three campaigns in October 2012, January 2013 and May 2013 to repeatedly measure the path-integrated mixing ratios of CO2 along cross sections of the atmospheric plumes of two major fumarolic fields (Solfatara and Pisciarelli). By using a tomographic post-processing routine, we resolved, for each of the two fields, the contour maps of CO2 mixing ratios in the atmosphere, from the integration of which (and after multiplication by the plumes' transport speeds) the CO2 fluxes were finally obtained. We evaluate a total CO2 output from the Campi Flegrei fumaroles of ˜490 Mg/day, in line with independent estimates based on in situ (Multi-GAS) observations. We conclude that TDL technique may enable CO2 flux quantification at other volcanoes worldwide.

  11. CO2 dispersion modelling over Paris region within the CO2-MEGAPARIS project

    Directory of Open Access Journals (Sweden)

    C. Lac

    2013-05-01

    Full Text Available Accurate simulation of the spatial and temporal variability of tracer mixing ratios over urban areas is a challenging and interesting task needed to be performed in order to utilise CO2 measurements in an atmospheric inverse framework and to better estimate regional CO2 fluxes. This study investigates the ability of a high-resolution model to simulate meteorological and CO2 fields around Paris agglomeration during the March field campaign of the CO2-MEGAPARIS project. The mesoscale atmospheric model Meso-NH, running at 2 km horizontal resolution, is coupled with the Town Energy Balance (TEB urban canopy scheme and with the Interactions between Soil, Biosphere and Atmosphere CO2-reactive (ISBA-A-gs surface scheme, allowing a full interaction of CO2 modelling between the surface and the atmosphere. Statistical scores show a good representation of the urban heat island (UHI with stronger urban–rural contrasts on temperature at night than during the day by up to 7 °C. Boundary layer heights (BLH have been evaluated on urban, suburban and rural sites during the campaign, and also on a suburban site over 1 yr. The diurnal cycles of the BLH are well captured, especially the onset time of the BLH increase and its growth rate in the morning, which are essential for tall tower CO2 observatories. The main discrepancy is a small negative bias over urban and suburban sites during nighttime (respectively 45 m and 5 m, leading to a few overestimations of nocturnal CO2 mixing ratios at suburban sites and a bias of +5 ppm. The diurnal CO2 cycle is generally well captured for all the sites. At the Eiffel tower, the observed spikes of CO2 maxima occur every morning exactly at the time at which the atmospheric boundary layer (ABL growth reaches the measurement height. At suburban ground stations, CO2 measurements exhibit maxima at the beginning and at the end of each night, when the ABL is fully contracted, with a strong spatio-temporal variability. A

  12. Urban Myths about Learning and Education

    NARCIS (Netherlands)

    De Bruyckere, Pedro; Kirschner, Paul A.; Hulshof, Casper

    2016-01-01

    In this book, the most common popular myths relating to learning and education are discussed with respect to whether there is any truth in the myth and what good educational and psychological research has to say about them. Examples of such myths range from: learning styles to neuromyths such as

  13. CO2-helium and CO2-neon mixtures at high pressures.

    Science.gov (United States)

    Mallick, B; Ninet, S; Le Marchand, G; Munsch, P; Datchi, F

    2013-01-28

    The properties of mixtures of carbon dioxide with helium or neon have been investigated as a function of CO(2) concentration and pressure up to 30 GPa at room temperature. The binary phase diagrams of these mixtures are determined over the full range of CO(2) concentrations using visual observations and Raman scattering measurements. Both diagrams are of eutectic type, with a fluid-fluid miscibility gap for CO(2) concentrations in the range [5, 75] mol. % for He and [8, 55] mol. % for Ne, and a complete separation between the two components in the solid phase. The absence of alloys or stoichiometric compounds for these two binary systems is consistent with the Hume-Rothery rules of hard sphere mixtures. The Raman spectra and x-ray diffraction patterns of solid CO(2) embedded in He or Ne for various initial concentrations have been measured up to 30 GPa and 12 GPa, respectively. The frequencies of the Raman modes and the volume of solid phase I are identical, within error bars, to those reported for 100% CO(2) samples, thus confirming the total immiscibility of CO(2) with He and Ne in the solid phase. These results demonstrate the possibility to perform high-pressure experiments on solid CO(2) under (quasi-)hydrostatic conditions using He or Ne as pressure transmitting medium.

  14. Root-derived CO2 efflux via xylem stream rivals soil CO2 efflux.

    Energy Technology Data Exchange (ETDEWEB)

    Aubrey, Doug, P.; Teskey, Robert, O.

    2009-07-01

    • Respiration consumes a large portion of annual gross primary productivity in forest ecosystems and is dominated by belowground metabolism. Here, we present evidence of a previously unaccounted for internal CO2 flux of large magnitude from tree roots through stems. If this pattern is shown to persist over time and in other forests, it suggests that belowground respiration has been grossly underestimated. • Using an experimental Populus deltoides plantation as a model system, we tested the hypothesis that a substantial portion of the CO2 released from belowground autotrophic respiration remains within tree root systems and is transported aboveground through the xylem stream rather than diffusing into the soil atmosphere. • On a daily basis, the amount of CO2 that moved upward from the root system into the stem via the xylem stream (0.26 mol CO2 m-2 d-1) rivalled that which diffused from the soil surface to the atmosphere (0.27 mol CO2 m-2 d-1). We estimated that twice the amount of CO2 derived from belowground autotrophic respiration entered the xylem stream as diffused into the soil environment. • Our observations indicate that belowground autotrophic respiration consumes substantially more carbohydrates than previously recognized and challenge the paradigm that all root-respired CO2 diffuses into the soil atmosphere.

  15. Global CO2 fluxes estimated from GOSAT retrievals of total column CO2

    Directory of Open Access Journals (Sweden)

    S. Basu

    2013-09-01

    Full Text Available We present one of the first estimates of the global distribution of CO2 surface fluxes using total column CO2 measurements retrieved by the SRON-KIT RemoTeC algorithm from the Greenhouse gases Observing SATellite (GOSAT. We derive optimized fluxes from June 2009 to December 2010. We estimate fluxes from surface CO2 measurements to use as baselines for comparing GOSAT data-derived fluxes. Assimilating only GOSAT data, we can reproduce the observed CO2 time series at surface and TCCON sites in the tropics and the northern extra-tropics. In contrast, in the southern extra-tropics GOSAT XCO2 leads to enhanced seasonal cycle amplitudes compared to independent measurements, and we identify it as the result of a land–sea bias in our GOSAT XCO2 retrievals. A bias correction in the form of a global offset between GOSAT land and sea pixels in a joint inversion of satellite and surface measurements of CO2 yields plausible global flux estimates which are more tightly constrained than in an inversion using surface CO2 data alone. We show that assimilating the bias-corrected GOSAT data on top of surface CO2 data (a reduces the estimated global land sink of CO2, and (b shifts the terrestrial net uptake of carbon from the tropics to the extra-tropics. It is concluded that while GOSAT total column CO2 provide useful constraints for source–sink inversions, small spatiotemporal biases – beyond what can be detected using current validation techniques – have serious consequences for optimized fluxes, even aggregated over continental scales.

  16. Effects of CO2 on stomatal conductance: do stomata open at very high CO2 concentrations?

    Science.gov (United States)

    Wheeler, R. M.; Mackowiak, C. L.; Yorio, N. C.; Sager, J. C.

    1999-01-01

    Potato and wheat plants were grown for 50 d at 400, 1000 and 10000 micromoles mol-1 carbon dioxide (CO2). and sweetpotato and soybean were grown at 1000 micromoles mol-1 CO2 in controlled environment chambers to study stomatal conductance and plant water use. Lighting was provided with fluorescent lamps as a 12 h photoperiod with 300 micromoles m-2 s-1 PAR. Mid-day stomatal conductances for potato were greatest at 400 and 10000 micromoles mol-1 and least at 1000 micromoles mol-1 CO2. Mid-day conductances for wheat were greatest at 400 micromoles mol-1 and least at 1000 and 10000 micromoles mol-1 CO2. Mid-dark period conductances for potato were significantly greater at 10000 micromoles mol-1 than at 400 or 1000 micromoles mol-1, whereas dark conductance for wheat was similar in all CO2 treatments. Temporarily changing the CO2 concentration from the native 1000 micromoles mol-1 to 400 micromoles mol-1 increased mid-day conductance for all species, while temporarily changing from 1000 to 10000 micromoles mol-1 also increased conductance for potato and sweetpotato. Temporarily changing the dark period CO2 from 1000 to 10000 micromoles mol-1 increased conductance for potato, soybean and sweetpotato. In all cases, the stomatal responses were reversible, i.e. conductances returned to original rates following temporary changes in CO2 concentration. Canopy water use for potato was greatest at 10000, intermediate at 400, and least at 1000 micromoles mol-1 CO2, whereas canopy water use for wheat was greatest at 400 and similar at 1000 and 10000 micromoles mol-1 CO2. Elevated CO2 treatments (i.e. 1000 and 10000 micromoles mol-1) resulted in increased plant biomass for both wheat and potato relative to 400 micromoles mol-1, and no injurious effects were apparent from the 10000 micromoles mol-1 treatment. Results indicate that super-elevated CO2 (i.e. 10000 micromoles mol-1) can increase stomatal conductance in some species, particularly during the dark period, resulting in

  17. Streamer parameters and breakdown in CO2

    Science.gov (United States)

    Seeger, M.; Avaheden, J.; Pancheshnyi, S.; Votteler, T.

    2017-01-01

    CO2 is a promising gas for the replacement of SF6 in high-voltage transmission and distribution networks due to its lower environmental impact. The insulation properties of CO2 are, therefore, of great interest. For this, the properties of streamers are important, since they determine the initial discharge propagation and possibly the transition to a leader. The present experimental investigation addresses the streamer inception and propagation at ambient temperature in the pressure range 0.05-0.5 MPa at both polarities. Streamer parameters, namely the stability field, radius and velocity, were deduced in uniform and in strongly non-uniform background fields. The measured breakdown fields can then be understood by streamer propagation and streamer-to-leader transition.

  18. CO2-DISSOLVED and Aqueous Gas Separation

    OpenAIRE

    Gorensek, Maximillian; Hamm, Luther; Blount, Gerald; Kervévan, Christophe; O'Neil, Kathleen

    2016-01-01

    International audience; CO2-DISSOLVED (Kervévan et al, 2014) is a multinational project funded by the French National Research Agency (ANR) with Phase II funded as one of the first Geodenergies projects. Geodenergies is a French industry-driven initiative grouping 18 companies and research organizations aiming at: (1) structuring a community of expertise to promote subsurface energy technologies that are key to a global energy transition; (2) cross-fertilizing to develop 3 emerging industrial...

  19. Aridity under conditions of increased CO2

    Science.gov (United States)

    Greve, Peter; Roderick, Micheal L.; Seneviratne, Sonia I.

    2016-04-01

    A string of recent of studies led to the wide-held assumption that aridity will increase under conditions of increasing atmospheric CO2 concentrations and associated global warming. Such results generally build upon analyses of changes in the 'aridity index' (the ratio of potential evaporation to precipitation) and can be described as a direct thermodynamic effect on atmospheric water demand due to increasing temperatures. However, there is widespread evidence that contradicts the 'warmer is more arid' interpretation, leading to the 'global aridity paradox' (Roderick et al. 2015, WRR). Here we provide a comprehensive assessment of modeled changes in a broad set of dryness metrics (primarily based on a range of measures of water availability) over a large range of realistic atmospheric CO2 concentrations. We use an ensemble of simulations from of state-of-the-art climate models to analyse both equilibrium climate experiments and transient historical simulations and future projections. Our results show that dryness is, under conditions of increasing atmospheric CO2 concentrations and related global warming, generally decreasing at global scales. At regional scales we do, however, identify areas that undergo changes towards drier conditions, located primarily in subtropical climate regions and the Amazon Basin. Nonetheless, the majority of regions, especially in tropical and mid- to northern high latitudes areas, display wetting conditions in a warming world. Our results contradict previous findings and highlight the need to comprehensively assess all aspects of changes in hydroclimatological conditions at the land surface. Roderick, M. L., P. Greve, and G. D. Farquhar (2015), On the assessment of aridity with changes in atmospheric CO2, Water Resour. Res., 51, 5450-5463

  20. CO2 flux geothermometer for geothermal exploration

    Science.gov (United States)

    Harvey, M. C.; Rowland, J. V.; Chiodini, G.; Rissmann, C. F.; Bloomberg, S.; Fridriksson, T.; Oladottir, A. A.

    2017-09-01

    A new geothermometer (TCO2 Flux) is proposed based on soil diffuse CO2 flux and shallow temperature measurements made on areas of steam heated, thermally altered ground above active geothermal systems. This CO2 flux geothermometer is based on a previously reported CO2 geothermometer that was designed for use with fumarole analysis. The new geothermometer provides a valuable additional exploration tool for estimating subsurface temperatures in high-temperature geothermal systems. Mean TCO2 Flux estimates fall within the range of deep drill hole temperatures at Wairakei (New Zealand), Tauhara (New Zealand), Rotokawa (New Zealand), Ohaaki (New Zealand), Reykjanes (Iceland) and Copahue (Argentina). The spatial distribution of geothermometry estimates is consistent with the location of major upflow zones previously reported at the Wairakei and Rotokawa geothermal systems. TCO2 Flux was also evaluated at White Island (New Zealand) and Reporoa (New Zealand), where limited sub-surface data exists. Mode TCO2 Flux at White Island is high (320 °C), the highest of the systems considered in this study. However, the geothermometer relies on mineral-water equilibrium in neutral pH reservoir fluids, and would not be reliable in such an active and acidic environment. Mean TCO2 Flux at Reporoa (310 °C) is high, which indicates Reporoa has a separate upflow from the nearby Waiotapu geothermal system; an outflow from Waiotapu would not be expected to have such high temperature.

  1. CO2 cooling for HEP experiments

    CERN Document Server

    Verlaat; Van Lysebetten, A

    2008-01-01

    The new generation silicon detectors require more efficient cooling of the front-end electronics and the silicon sensors themselves. To minimize reverse annealing of the silicon sensors the cooling temperatures need to be reduced. Other important requirements of the new generation cooling systems are a reduced mass and a maintenance free operation of the hardware inside the detector. Evaporative CO2 cooling systems are ideal for this purpose as they need smaller tubes than conventional systems. The heat transfer capability of evaporative CO2 is high. CO2 is used as cooling fluid for the LHCb-VELO and the AMS-Tracker cooling systems. A special method for the fluid circulation is developed at Nikhef to get a very stable temperature of both detectors without any active components like valves or heaters inside. This method is called 2-phase Accumulator Controlled Loop (2PACL) and is a good candidate technology for the design of the future cooling systems for the Atlas and CMS upgrades.

  2. Electrochemical CO2 Reduction: A Classification Problem.

    Science.gov (United States)

    Bagger, Alexander; Ju, Wen; Varela, Ana Sofia; Strasser, Peter; Rossmeisl, Jan

    2017-11-17

    In this work, we propose four non-coupled binding energies of intermediates as descriptors, or "genes", for predicting the product distribution in CO2 electroreduction. Simple reactions can be understood by the Sabatier principle (catalytic activity vs. one descriptor), while more complex reactions tend to give multiple very different products and consequently the product selectivity is a more complex property to understand. We approach this, as a logistical classification problem, by grouping metals according to their major experimental product from CO2 electroreduction: H2 , CO, formic acid and beyond CO* (hydrocarbons or alcohols). We compare the groups in terms of multiple binding energies of intermediates calculated by density functional theory. Here, we find three descriptors to explain the grouping: the adsorption energies of H*, COOH*, and CO*. To further classify products beyond CO*, we carry out formaldehyde experiments on Cu, Ag, and Au and combine these results with the literature to group and differentiate alcohol or hydrocarbon products. We find that the oxygen binding (adsorption energy of CH3 O*) is an additional descriptor to explain the alcohol formation in reduction processes. Finally, the adsorption energy of the four intermediates, H*, COOH*, CO*, and CH3 O*, can be used to differentiate, group, and explain products in electrochemical reduction processes involving CO2 , CO, and carbon-oxygen compounds. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  3. Revealing myths about people, energy and buildings

    Energy Technology Data Exchange (ETDEWEB)

    Diamond, R.; Moezzi, M.

    2000-05-01

    In this essay we take a closer look at some energy myths, focusing on the ways energy professionals and the public alike, talk, write and teach about how energy affects the way in which we design, operate, retrofit and inhabit buildings. What myths about people, energy and buildings are current today? Who tells these myths and why do we believe them? How do myths affect our behavior? Myths are a way of understanding the world we live in. They may represent incomplete understanding, or be based on premises that are scientifically not valid, but they help us understand and explain how the world works, and we shape our behavior accordingly.

  4. Integration of the electrochemical depolorized CO2 concentrator with the Bosch CO2 reduction subsystem

    Science.gov (United States)

    Schubert, F. H.; Wynveen, R. A.; Hallick, T. M.

    1976-01-01

    Regenerative processes for the revitalization of spacecraft atmospheres require an Oxygen Reclamation System (ORS) for the collection of carbon dioxide and water vapor and the recovery of oxygen from these metabolic products. Three life support subsystems uniquely qualified to form such an ORS are an Electrochemical CO2 Depolarized Concentrator (EDC), a CO2 Reduction Subsystem (BRS) and a Water Electrolysis Subsystem (WES). A program to develop and test the interface hardware and control concepts necessary for integrated operation of a four man capacity EDC with a four man capacity BRS was successfully completed. The control concept implemented proved successful in operating the EDC with the BRS for both constant CO2 loading as well as variable CO2 loading, based on a repetitive mission profile of the Space Station Prototype (SSP).

  5. Natural Analogues of CO2 Geological Storage; Analogos Naturales del Almacenamiento Geologico de CO2

    Energy Technology Data Exchange (ETDEWEB)

    Perez del Villar, L.; Pelayo, M.; Recreo, F.

    2007-07-20

    Geological storage of carbon dioxide is nowadays, internationally considered as the most effective method for greenhouse gas emission mitigation, in order to minimize the global climate change universally accepted. Nevertheless, the possible risks derived of this long-term storage have a direct influence on its public acceptance. Among the favourable geological formations to store CO2, depleted oil and gas fields, deep saline reservoirs, and unamiable coal seams are highlighted. One of the most important objectives of the R and D projects related to the CO2 geological storage is the evaluation of the CO2 leakage rate through the above mentioned geological formations. Therefore, it is absolutely necessary to increase our knowledge on the interaction among CO2, storage and sealing formations, as well as on the flow paths and the physical resistance of the sealing formation. The quantification of the CO2 leakage rate is essential to evaluate the effects on the human and animal health, as well as for the ecosystem and water quality. To achieve these objectives, the study of the natural analogues is very useful in order to know the natural leakage rate to the atmosphere, its flow paths, the physical, chemical and mineralogical modifications due to the long term interaction processes among the CO2 and the storage and sealing formations, as well as the effects on the groundwaters and ecosystems. In this report, we have tried to summarise the main characteristics of the natural reservoirs and surficial sources of CO2, which are both natural analogues of the geological storage and CO2 leakage, studied in EEUU, Europe and Australia. The main objective of this summary is to find the possible applications for long-term risk prediction and for the performance assessment by means of conceptual and numerical modelling, which will allow to validate the predictive models of the CO2 storage behaviour, to design and develop suitable monitoring techniques to control the CO2 behaviour

  6. Myth and One-Dimensionality

    Directory of Open Access Journals (Sweden)

    William Hansen

    2017-12-01

    Full Text Available A striking difference between the folk-narrative genres of legend and folktale is how the human characters respond to supernatural, otherworldly, or uncanny beings such as ghosts, gods, dwarves, giants, trolls, talking animals, witches, and fairies. In legend the human actors respond with fear and awe, whereas in folktale they treat such beings as if they were ordinary and unremarkable. Since folktale humans treat all characters as belonging to a single realm, folklorists have described the world of the folktale as one-dimensional, in contrast to the two-dimensionality of the legend. The present investigation examines dimensionality in the third major genre of folk narrative: myth. Using the Greek and Hebrew myths of primordial paradise as sample narratives, the present essay finds—surprisingly—that the humans in these stories respond to the otherworldly one-dimensionally, as folktale characters do, and suggests an explanation for their behavior that is peculiar to the world of myth.

  7. The solar flare myth

    Science.gov (United States)

    Gosling, J. T.

    1993-01-01

    Many years of research have demonstrated that large, nonrecurrent geomagnetic storms, shock wave disturbances in the solar wind, and energetic particle events in interplanetary space often occur in close association with large solar flares. This result has led to a pradigm of cause and effect - that large solar flares are the fundamental cause of these events in the near-Earth space environmemt. This paradigm, which I call 'the solar flare myth,' dominates the popular perception of the relationship between solar activity and interplanetary and geomagnetic events and has provided much of the pragmatic rationale for the study of the solar flare phenomenon. Yet there is good evidence that this paradigm is wrong and that flares do not generally play a central role in producing major transient disturbances in the near-Earth space environment. In this paper I outline a different paradigm of cause and effect that removes solar flares from their central position in the chain of events leading from the Sun to near-Earth space. Instead, this central role is given to events known as coronal mass ejections.

  8. CO2-Responsive Polymer-Functionalized Au Nanoparticles for CO2 Sensor.

    Science.gov (United States)

    Ma, Ying; Promthaveepong, Kittithat; Li, Nan

    2016-08-16

    Metallic nanoparticles (NPs) coated with stimuli-responsive polymers (SRPs) exhibit tunable optical properties responding to external stimuli and show promising sensing applications. We present a new CO2-responsive polymer, poly(N-(3-amidino)-aniline) (PNAAN), coated gold NPs (AuNPs) synthesized by directly reducing HAuCl4 with a CO2-responsive monomer N-(3-amidino)-aniline (NAAN). The amidine group of PNAAN can be protonated into a hydrophilic amidinium group by dissolved CO2 (dCO2). This induces the PNAAN to swell and detach from the AuNP surface, resulting in AuNP aggregation and color change. By monitoring the UV absorbance change of AuNPs, a sensitive dCO2 sensor with a linear range of 0.0132 to 0.1584 hPa and a limit of detection (LOD) of 0.0024 hPa is developed. This method shows dramatic improvement in sensitivity and convenience of sample preparation compared with the previously reported dCO2 sensor.

  9. Recycling CO 2 ? Computational Considerations of the Activation of CO 2 with Homogeneous Transition Metal Catalysts

    KAUST Repository

    Drees, Markus

    2012-08-10

    Faced with depleting fossil carbon sources, the search for alternative energy carriers and energy storage possibilities has become an important issue. Nature utilizes carbon dioxide as starting material for storing sun energy in plant hydrocarbons. A similar approach, storing energy from renewable sources in chemical bonds with CO 2 as starting material, may lead to partial recycling of CO 2 created by human industrial activities. Unfortunately, currently available routes for the transformation of CO 2 involve high temperatures and are often not selective. With the development of more sophisticated methods and better software, theoretical studies have become both increasingly widespread and useful. This concept article summarizes theoretical investigations of the current state of the feasibility of CO 2 activation with molecular transition metal catalysts, highlighting the most promising reactions of CO 2 with olefins to industrially relevant acrylic acid/acrylates, and the insertion of CO 2 into metal-element bonds, particularly for the synthesis of cyclic carbonates and polymers. Rapidly improving computational power and methods help to increase the importance and accuracy of calculations continuously and make computational chemistry a useful tool helping to solve some of the most important questions for the future. © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  10. Effective Use of Natural CO2-RICH Systems for Stakeholder Communication: CO2FACTS.ORG

    Science.gov (United States)

    Olson, H. C.; Romanak, K.; Osborne, V.; Hovorka, S. D.; Clift, S.; Castner, A.

    2011-12-01

    The impact of using natural analogues as an avenue for communicating about CO2 injection and storage technology with stakeholders has been addressed by previous researchers, e.g., Romanak et al (2011), Dixon et al (2011). Analogies between natural CO2-rich systems and engineered CO2 storage are not necessarily straightforward, and stakeholder opinion is often based on factors other than technical accuracy of information (e.g., lack of trust, confidence, and fear). In order to enhance this communication pathway, STORE (Sequestration Training, Outreach, Research and Education), the outreach arm of the Gulf Coast Carbon Center at The University of Texas at Austin, has created an online resource (www.co2facts.org) to help stakeholders better understand the injection and storage of CO2 underground. The online resource includes frequently asked questions (FAQs) for a variety of CO2-storage-related issues, including those related to natural analogues, and uses examples of natural systems of CO2 release for communication. The content targets various levels of technical education and understanding. A unique feature of the online resource is its approach to verification of information. Each FAQ and example is "fact-checked" by an actual expert in the field. Part of this verification process is to provide an online link to background, credentials, scientific research and images of actual experts in the field at natural release sites. This approach helps put a face to, and potentially builds a relationship of trust with, the scientist behind the technical information. Videos of experts discussing natural systems and their similarities and differences with CO2 injection and storage sites are also part of the resource. Stakeholders commonly draw incorrect parallels between natural disasters that gain attention in the media (e.g., Lake Nyos) and CO2 injection and storage technology. The video images available at www.co2facts.org are a useful tool for assuaging environmental fears

  11. Metabolic effects of Carbon Dioxide (CO 2 ) insufflation during ...

    African Journals Online (AJOL)

    Metabolic effects of Carbon Dioxide (CO 2 ) insufflation during laparoscopic surgery: changes in pH, arterial partial Pressure of Carbon Dioxide (PaCo 2 ) and End Tidal Carbon Dioxide (EtCO ... EtCO2 is still a good non-invasive monitor for estimation of PaCO2 during low tidal volume ventilation during pneumoperitoneum.

  12. In silico screening of zeolite membranes for CO2 capture

    NARCIS (Netherlands)

    Krishna, R.; van Baten, J.M.

    2010-01-01

    The separation of CO2/H-2, CO2/CH4, and CO2/N-2 mixtures is of practical importance for CO2 capture and other applications in the processing industries. Use of membranes with microporous layers of zeolites, metal-organic frameworks (MOFs), and zeolitic imidazolate frameworks (ZIFs) offer

  13. Debunking Health IT Usability Myths

    Science.gov (United States)

    Staggers, N.; Xiao, Y.; Chapman, L.

    2013-01-01

    Poor usability is a threat to patient safety and linked to productivity loss, workflow disruption, user frustration, sub-optimal product use and system de-installations. Although usability is receiving more attention nationally and internationally, myths about usability persist. This editorial debunks five common myths about usability (1) usability only concerns the look and feel of a product and is, therefore, only a minor concern, (2) usability is not measurable, (3) usability stifles innovation, (4) vendors are solely responsible for product usability, and (5) usability methods are not practical for use in healthcare. PMID:23874361

  14. Air-sea CO2 fluxes along the coast of Chile: From CO2 outgassing in central northern upwelling waters to CO2 uptake in southern Patagonian fjords

    Science.gov (United States)

    Torres, Rodrigo; Pantoja, Silvio; Harada, Naomi; GonzáLez, Humberto E.; Daneri, Giovanni; Frangopulos, MáXimo; Rutllant, José A.; Duarte, Carlos M.; Rúiz-Halpern, Sergio; Mayol, Eva; Fukasawa, Masao

    2011-09-01

    Carbon system parameters measured during several expeditions along the coast of Chile (23°S-56°S) have been used to show the main spatial and temporal trends of air-sea CO2 fluxes in the coastal waters of the eastern South Pacific. Chilean coastal waters are characterized by strong pCO2 gradients between the atmosphere and the surface water, with high spatial and temporal variability. On average, the direction of the carbon flux changes from CO2 outgassing at the coastal upwelling region to CO2 sequestering at the nonupwelling fjord region in Chilean Patagonia. Estimations of surface water pCO2 along the Patagonian fjord region showed that, while minimum pCO2 levels (strong CO2 undersaturation) occurs during the spring and summer period, maximum levels (including CO2 supersaturation) occur during the austral winter. CO2 uptake in the Patagonia fjord region during spring-summer is within the order of -5 mol C m-2 yr-1, indicating a significant regional sink of atmospheric CO2 during that season. We suggest that the CO2 sink at Patagonia most probably exceeds the CO2 source exerted by the coastal upwelling system off central northern Chile.

  15. PLAINS CO2 REDUCTION (PCOR) PARTNERSHIP

    Energy Technology Data Exchange (ETDEWEB)

    Edward N. Steadman; Daniel J. Daly; Lynette L. de Silva; John A. Harju; Melanie D. Jensen; Erin M. O' Leary; Wesley D. Peck; Steven A. Smith; James A. Sorensen

    2006-01-01

    During the period of October 1, 2003, through September 30, 2005, the Plains CO2 Reduction (PCOR) Partnership, identified geologic and terrestrial candidates for near-term practical and environmentally sound carbon dioxide (CO2) sequestration demonstrations in the heartland of North America. The PCOR Partnership region covered nine states and three Canadian provinces. The validation test candidates were further vetted to ensure that they represented projects with (1) commercial potential and (2) a mix that would support future projects both dependent and independent of CO2 monetization. This report uses the findings contained in the PCOR Partnership's two dozen topical reports and half-dozen fact sheets as well as the capabilities of its geographic information system-based Decision Support System to provide a concise picture of the sequestration potential for both terrestrial and geologic sequestration in the PCOR Partnership region based on assessments of sources, sinks, regulations, deployment issues, transportation, and capture and separation. The report also includes concise action plans for deployment and public education and outreach as well as a brief overview of the structure, development, and capabilities of the PCOR Partnership. The PCOR Partnership is one of seven regional partnerships under Phase I of the U.S. Department of Energy National Energy Technology Laboratory's Regional Carbon Sequestration Partnership program. The PCOR Partnership, comprising 49 public and private sector members, is led by the Energy & Environmental Research Center at the University of North Dakota. The international PCOR Partnership region includes the Canadian provinces of Alberta, Saskatchewan, and Manitoba and the states of Montana (part), Wyoming (part), North Dakota, South Dakota, Nebraska, Missouri, Iowa, Minnesota, and Wisconsin.

  16. Method for tracing simulated CO2 leak in terrestrial environment with a 13CO2 tracer

    Science.gov (United States)

    Moni, Christophe; Rasse, Daniel

    2013-04-01

    Facilities for the geological storage of carbon dioxide (CO2) as part of carbon capture and storage (CCS) schemes will be designed to prevent any leakage from the defined 'storage complex'. However, developing regulations and guidance throughout the world (e.g. the EC Directive and the USEPA Vulnerability Evaluation Framework) recognize the importance of assessing the potential for environmental impacts from CO2 storage. RISCS, a European (FP7) project, aims to improve understanding of those impacts that could plausibly occur in the hypothetical case that unexpected leakage occurs. As part of the RISCS project the potential impacts that an unexpected CO2 leaks might have on a cropland ecosystems was investigated. A CO2 exposure field experiment based on CO2 injection at 85 cm depth under an oats culture was designed. To facilitate the characterization of the simulated leaking zone the gas used for injection was produced from natural gas and had a δ13C of -46‰. The aim of the present communication is to depict how the injected gas was traced within the soil-vegetation-atmosphere continuum using 13CO2 continuous cavity ring-down spectrometry (CRDS). Four subsurface experimental injection plots (6m x 3m) were set up. In order to test the effects of different intensity of leakage, the field experiment was designed as to create a longitudinal CO2 gradient for each plot. For this purpose gas supply pipes were inserted at one extremity of each plot at the base of a 45 cm thick layer of sand buried 40 cm below the surface under the clayey plough layer of Norwegian moraine soils. Soil CO2 concentration and isotopic signature were punctually recorded: 1) in the soil at 20 cm depth at 6 positions distributed on the central transect, 2) at the surface following a (50x50 cm) grid sampling pattern, and 3) in the canopy atmosphere at 10, 20, 30 cm along three longitudinal transects (seven sampling point per transect). Soil CO2 fluxes and isotopic signature were finally

  17. Upscaling of enzyme enhanced CO2 capture

    DEFF Research Database (Denmark)

    Gladis, Arne Berthold

    Fossil fuels are the backbone of the energy generation in the coming decades for USA, China, India and Europe, hence high greenhouse gas emissions are expected in future. Carbon capture and storage technology (CCS) is the only technology that can mitigate greenhouse gas emissions from fossil fuel...... fired power by selectively capturing CO2 from flue gases. High capital and high operational costs of this process are the major obstacles of industrial implementation. In the field of CCS the chemical absorption process is the most mature technology. The use of kinetic rate promoters that enhance...

  18. Chilled ammonia process for CO2 capture

    DEFF Research Database (Denmark)

    Darde, Victor Camille Alfred; Thomsen, Kaj; van Well, Willy J. M

    2009-01-01

    The chilled ammonia process absorbs the CO2 at low temperature (2-10 degrees C). The heat of absorption of carbon dioxide by ammonia is significantly lower than for amines. In addition, degradation problems can be avoided and a high carbon dioxide capacity is achieved. Hence, this process shows...... C and pressure up to 100 bars [1]. The results show that solid phases consisting of ammonium carbonate and bicarbonate are formed in the absorber. The energy requirements in the absorber and in the desorber have been studied. The enthalpy calculations show that an energy requirement for the desorber...

  19. Saturated CO2 inhibits microbial processes in CO2-vented deep-sea sediments

    Directory of Open Access Journals (Sweden)

    D. de Beer

    2013-08-01

    Full Text Available This study focused on biogeochemical processes and microbial activity in sediments of a natural deep-sea CO2 seepage area (Yonaguni Knoll IV hydrothermal system, Japan. The aim was to assess the influence of the geochemical conditions occurring in highly acidic and CO2 saturated sediments on sulfate reduction (SR and anaerobic methane oxidation (AOM. Porewater chemistry was investigated from retrieved sediment cores and in situ by microsensor profiling. The sites sampled around a sediment-hosted hydrothermal CO2 vent were very heterogeneous in porewater chemistry, indicating a complex leakage pattern. Near the vents, droplets of liquid CO2 were observed emanating from the sediments, and the pH reached approximately 4.5 in a sediment depth > 6 cm, as determined in situ by microsensors. Methane and sulfate co-occurred in most sediment samples from the vicinity of the vents down to a depth of 3 m. However, SR and AOM were restricted to the upper 7–15 cm below seafloor, although neither temperature, low pH, nor the availability of methane and sulfate could be limiting microbial activity. We argue that the extremely high subsurface concentrations of dissolved CO2 (1000–1700 mM, which disrupt the cellular pH homeostasis, and lead to end-product inhibition. This limits life to the surface sediment horizons above the liquid CO2 phase, where less extreme conditions prevail. Our results may have to be taken into consideration in assessing the consequences of deep-sea CO2 sequestration on benthic element cycling and on the local ecosystem state.

  20. Choice of satellite-based CO2 product (XCO¬2, vertical profile) alters surface CO2 flux estimate

    Science.gov (United States)

    Liu, J.; Bowman, K. W.; Lee, M.; Henze, D. K.; Fisher, J. B.; Frankenberg, C.; Polhamus, A.

    2011-12-01

    The ACOS (Atmospheric CO2 Observations from Space) algorithm provides column-averaged CO2 products in units of dry-air mole fraction (XCO2) based on GOSAT radiances. However, XCO2 is derived from a linear transformation of the CO2 vertical profiles estimated from the ACOS retrieval algorithm. In theory, XCO2 vertical columns should provide no more information than the original CO2 profiles. However, the different sensitivities of either CO2 profiles or XCO2 to transport errors can significantly alter surface CO2 flux estimates. Though it has been argued that XCO2 may be less sensitive to transport error than CO2 vertical profiles, there is no study so far investigating the actual impact on surface CO2 flux estimation due to the choice of observation format, which could have significant impact on future satellite CO2 profile mission concepts. In this presentation, we will present the sensitivity of surface CO2 flux estimation to a suite of CO2 observation products, which includes CO2 vertical profiles, XCO2, and the lowest 3 levels of CO2 from CO2 vertical profiles. The CO2 observations are ACOS products covering from July 2009 to June 2010. We will present both OSSE and real observation experiments. In the OSSE experiments, we will present both perfect model experiments and experiments with model errors that are introduced by changing the planetary boundary height. In the real observations, we will show the annual and seasonal CO2 flux as function of regions from using the three observation products. The accuracy of CO2 flux estimation will be examined by comparing CO2 concentrations forced by posterior CO2 flux to independent CO2 observations. The surface CO2 flux estimation framework is based on GEOS-Chem adjoint model that is developed by the Carbon Monitoring Study flux pilot project.

  1. Worldwide regulations for mycotoxins.

    Science.gov (United States)

    van Egmond, Hans P

    2002-01-01

    Since the discovery of the aflatoxins in the 1960s, regulations have been established in many countries to protect the consumer from the harmful effects of mycotoxins that may contaminate foodstuffs. Various factors play a role in the decision-making process of setting limits for mycotoxins. These include scientific factors such as the availability of toxicological data, survey data, knowledge about the distribution of mycotoxins in commodities, and analytical methodology. Economical and political factors such as commercial interests and sufficiency of food supply have their impact as well. International enquiry's on existing mycotoxin legislation in foodstuffs and animal feedstuffs have been carried out several times in the 1980s and 1990s and details about tolerances, legal basis, responsible authorities, official protocols of analysis and sampling have been published. Recently a comprehensive update on worldwide regulations was published as FAO Food and Nutrition Paper 64. It appeared that at least 77 countries now have specific regulations for mycotoxins, 13 countries are known to have no specific regulations, whereas no data are available for about 50 countries, many of them in Africa. Over the years, a large diversity in tolerance levels for mycotoxins has remained. Some free trade zones (EU, MERCOSUR) are in the process of harmonizing the limits and regulations for mycotoxins in their respective member states, but it is not likely that worldwide harmonized limits for mycotoxins will soon be within reach.

  2. Confronting myths with science.

    Science.gov (United States)

    Barnett, B

    1994-12-01

    Family Health International (FHI) staff arranged for a workshop on contraceptive facts and fallacies within 48 hours for the 10-day meeting of the Nongovernmental Organization (NGO) Forum in Cairo, Egypt. Since policy and advocacy groups affect family planning service delivery and are often misinformed, the quality of client services is impaired. This workshop would allow NGO Forum participants to receive basic information on contraception and to correct any misinformation. FHI hoped that the workshop would stimulate dialogue among scientists, women's groups, and policymakers. Panel speakers were a deputy assistant secretary for population affairs with the US Department of Health and Human Services, an obstetrics-gynecology (OB-GYN) professor at Emory University in Atlanta, who was also a member of FHI's Board of Directors, and a native Indian, now practicing OB-GYN in the US, who was a former medical director at FHI. FHI senior vice president for reproductive health programs moderated the panel. The panel addressed the following myths: male condoms fail often and condom use increases the spread of sexually transmitted diseases (STDs), natural family planning (NFP) does not prevent pregnancy, oral contraceptives (OCs) cause cancer, spermicides increase the risk of acquiring AIDS and STDs. The panel provided the following facts: Condom breakage and slippage occurs in 0-12% of acts of intercourse. Education on proper use of condoms can reduce the likelihood of condom failure. If used correctly, NFP is 98% effective. OCs protect against ovarian and endometrial cancers. We still do not know whether or not they contribute to cervical cancer development. A study has found an association between OCs and a form of liver cancer common in developing countries (due to a high prevalence of hepatitis B infection). Spermicide use reduces the risk of bacterial STDs (e.g., gonorrhea and chlamydia), but it is not yet clear whether it affects the risk of viral STDs (e.g., HIV).

  3. CO2 acclimation impacts leaf isoprene emissions: evidence from past to future CO2 levels

    Science.gov (United States)

    de Boer, Hugo; van der Laan, Annick; Dekker, Stefan; Holzinger, Rupert

    2017-04-01

    Isoprene is emitted by many plant species as a side-product of photosynthesis. Once in the atmosphere, isoprene exhibits climate forcing through various feedback mechanisms. In order to quantify the climate feedbacks of biogenic isoprene emission it is crucial to establish how isoprene emissions are effected by plant acclimation to rising atmospheric CO2 levels. A promising development for modelling CO2-induced changes in isoprene emissions is the Leaf-Energetic-Status model (referred to as LES-model hereafter, see Harrison et al., 2013 and Morfopoulos et al., 2014). This model simulates isoprene emissions based on the hypothesis that isoprene biosynthesis depends on the imbalance between the photosynthetic electron supply of reducing power and the electron demands of carbon fixation. The energetic imbalance is critically related to the photosynthetic electron transport capacity (Jmax) and the maximum carboxylation capacity of Rubisco (Vcmax). Here we compare predictions of the LES-model with observed isoprene emission responses of Quercus robur (pedunculate oak) specimen that acclimated to CO2 growth conditions representative of the last glacial, the present and the end of this century (200, 400 and 800 ppm, respectively) for two growing seasons. These plants were grown in walk-in growth chambers with tight control of light, temperature, humidity and CO2 concentrations. Photosynthetic biochemical parameters Vcmax and Jmax were determined with a Licor LI-6400XT photosynthesis system. The relationship between photosynthesis and isoprene emissions was measured by coupling the photosynthesis system with a Proton-Transfer Reaction Time-of-Flight Mass Spectrometer. Our empirical results support the LES-model and show that the fractional allocation of carbon to isoprene biosynthesis is reduced in response to both short-term and long-term CO2 increases. In the short term, an increase in CO2 stimulates photosynthesis through an increase in the leaf interior CO2

  4. Global CO2 emissions from cement production

    Science.gov (United States)

    Andrew, Robbie M.

    2018-01-01

    The global production of cement has grown very rapidly in recent years, and after fossil fuels and land-use change, it is the third-largest source of anthropogenic emissions of carbon dioxide. The required data for estimating emissions from global cement production are poor, and it has been recognised that some global estimates are significantly inflated. Here we assemble a large variety of available datasets and prioritise official data and emission factors, including estimates submitted to the UNFCCC plus new estimates for China and India, to present a new analysis of global process emissions from cement production. We show that global process emissions in 2016 were 1.45±0.20 Gt CO2, equivalent to about 4 % of emissions from fossil fuels. Cumulative emissions from 1928 to 2016 were 39.3±2.4 Gt CO2, 66 % of which have occurred since 1990. Emissions in 2015 were 30 % lower than those recently reported by the Global Carbon Project. The data associated with this article can be found at https://doi.org/10.5281/zenodo.831455" target="_blank">https://doi.org/10.5281/zenodo.831455.

  5. Public Acceptance for Geological CO2-Storage

    Science.gov (United States)

    Schilling, F.; Ossing, F.; Würdemann, H.; Co2SINK Team

    2009-04-01

    Public acceptance is one of the fundamental prerequisites for geological CO2 storage. In highly populated areas like central Europe, especially in the vicinity of metropolitan areas like Berlin, underground operations are in the focus of the people living next to the site, the media, and politics. To gain acceptance, all these groups - the people in the neighbourhood, journalists, and authorities - need to be confident of the security of the planned storage operation as well as the long term security of storage. A very important point is to show that the technical risks of CO2 storage can be managed with the help of a proper short and long term monitoring concept, as well as appropriate mitigation technologies e.g adequate abandonment procedures for leaking wells. To better explain the possible risks examples for leakage scenarios help the public to assess and to accept the technical risks of CO2 storage. At Ketzin we tried the following approach that can be summed up on the basis: Always tell the truth! This might be self-evident but it has to be stressed that credibility is of vital importance. Suspiciousness and distrust are best friends of fear. Undefined fear seems to be the major risk in public acceptance of geological CO2-storage. Misinformation and missing communication further enhance the denial of geological CO2 storage. When we started to plan and establish the Ketzin storage site, we ensured a forward directed communication. Offensive information activities, an information centre on site, active media politics and open information about the activities taking place are basics. Some of the measures were: - information of the competent authorities through meetings (mayor, governmental authorities) - information of the local public, e.g. hearings (while also inviting local, regional and nation wide media) - we always treated the local people and press first! - organizing of bigger events to inform the public on site, e.g. start of drilling activities (open

  6. Effect of CO2 partial pressure and different CO2 phases on carbon steel corrosion

    Science.gov (United States)

    Mahlobo, MGR; Premlall, K.; Olubambi, PA

    2017-12-01

    Carbon capture and storage (CCS) is the recent promising technology aimed at reducing greenhouse gas emission. Like many other developed technologies, CCS is faced with great challenges such as pipeline transportation failure due to corrosion. There are many factors contributing to steel corrosion during the pipeline transportation of carbon dioxide (CO2). This study focuses on CO2 partial pressure and different phases of CO2 as some of the factors contributing to steel corrosion. Carbon steel was used as a testing specimen. High pressure reactor was used in this study to compress CO2 from low to high pressures ultimately changing the CO2 from gaseous phase to gas/liquid phase (subcritical) and to dense phase (supercritical). Weight loss method was employed to determine the corrosion rate while scanning electron microscopy (SEM) and X-Ray diffraction (XRD) were used to study the carbon steel morphology and phase analysis. Using low magnification digital camera, the type of corrosion that took place on the carbon steel surface was identified.

  7. Myths and Facts about SIDS and Safe Infant Sleep

    Science.gov (United States)

    ... Myths and Facts About SIDS and Safe Infant Sleep Page Content Myth: Babies can “catch” SIDS. Fact: ... sleep environment for your baby. Myth: Babies who sleep on their backs will choke if they spit ...

  8. Romanian Post‑Revolution Electoral Myths

    Directory of Open Access Journals (Sweden)

    Alfred Bulai

    2015-12-01

    Full Text Available The article analyzes some of the political and electoral myths of the post-communist transition, myths that have occupied the political agenda and the public debate throughout this period. Myths are seen as simple or complex narratives that have an explanatory and justificatory function in relation to social life, focused on Romanian society’s problems. They define and legitimizes a certain way to solve them and guides the development of society on the basis of some axiomatic principles. The article analyzes such myths, older or more recent, such as the myth of changing the electoral system, the myth of renewing the political class, the myth of the fundamental power of the referendum, the myth of the reform of the state, or of the constitutional amendments. The proposed analysis highlights the negative effects of using myths as instruments of the political and social changing on public policies and more generally on governance, and also the long-term harmful effects of the use of myths in defining political vision and Romania’s governmental development strategies.

  9. Intermittent Water Injection on Top of Continuous CO2 Injection to Co-Optimize Oil Recovery and CO2-Storage

    OpenAIRE

    Pranoto, Arif

    2016-01-01

    Master's thesis in Petroleum engineering The objective of this project is to maximize oil recovery and the CO2 stored during CO2-EOR. To reach that goal there are two important things to be achieved: gas production rate reduction and the oil production rate improvement. To attain the co-optimization, the following CO2 injection approaches were compared: CO2 continuous injection, WAG, Continuous water injection over continuous CO2 injection, and intermittent water injection over continuous ...

  10. Common High Blood Pressure Myths

    Science.gov (United States)

    ... Artery Disease Venous Thromboembolism Aortic Aneurysm More Common High Blood Pressure Myths Updated:Dec 8,2017 Knowing the facts ... health. This content was last reviewed October 2016. High Blood Pressure • Home • Get the Facts About HBP Introduction What ...

  11. The Myth of Peer Pressure.

    Science.gov (United States)

    Ungar, Michael T.

    2000-01-01

    The construct of peer pressure was examined as part of a qualitative study of the determinants of mental health for 41 high-risk adolescents. While the concept of peer pressure enables adults to explain youths' troubling behaviors, content analysis of the participants' accounts of their lives reveals peer pressure to be a myth. (Author/MKA)

  12. Debunking the Myths about Change

    Science.gov (United States)

    Chirichello, Michael

    2008-01-01

    When principals travel down the road of change, they often find potholes of resistance, many resulting from misconceptions about the process. In this article, the author debunks five myths about change: (1) Change is always the answer; (2) The destination is more important than the journey; (3) Change depends on the principal's leadership; (4)…

  13. The myths of the Bear

    CERN Document Server

    Antonello, E

    2013-01-01

    Following previous works on ancient myths in Greek and Latin literature regarding Ursa Major, and the possible relation with the ancient shape of the constellation, we discuss further this case in the light of the evolution of Homo sapiens and the ethnographic records of populations of Eurasia and North America.

  14. The Influence of CO2 Solubility in Brine on Simulation of CO2 Injection into Water Flooded Reservoir and CO2 WAG

    DEFF Research Database (Denmark)

    Yan, Wei; Stenby, Erling Halfdan

    2010-01-01

    Injection of CO2 into depleted oil reservoirs is not only a traditional way to enhance oil recovery but also a relatively cheaper way to sequester CO2 underground since the increased oil production can offset some sequestration cost. CO2 injection process is often applied to water flooded...... reservoirs and in many situations alternating injection of water and CO2 is required to stabilize the injection front. Both scenarios involve a large amount of water, making CO2 solubility in brine, which is around ten times higher than methane solubility, a non-negligible factor in the relevant reservoir...... simulations. In our previous study, a 1-D slimtube simulator, which rigorously accounts for both CO2 solubility in brine and water content in hydrocarbon phases using the Peng-Robinson EoS modified by Soreide and Whitson, has been used to investigate the influence of CO2 solubility on the simulation...

  15. Cyanobacterial carbon concentrating mechanisms facilitate sustained CO2 depletion in eutrophic lakes

    Directory of Open Access Journals (Sweden)

    A. M. Morales-Williams

    2017-06-01

    Full Text Available Phytoplankton blooms are increasing in frequency, intensity, and duration in aquatic ecosystems worldwide. In many eutrophic lakes, these high levels of primary productivity correspond to periods of CO2 depletion in surface waters. Cyanobacteria and other groups of phytoplankton have the ability to actively transport bicarbonate (HCO3− across their cell membrane when CO2 concentrations are limiting, possibly giving them a competitive advantage over algae not using carbon concentrating mechanisms (CCMs. To investigate whether CCMs can maintain phytoplankton bloom biomass under CO2 depletion, we measured the δ13C signatures of dissolved inorganic carbon (δ13CDIC and phytoplankton particulate organic carbon (δ13Cphyto in 16 mesotrophic to hypereutrophic lakes during the ice-free season of 2012. We used mass–balance relationships to determine the dominant inorganic carbon species used by phytoplankton under CO2 stress. We found a significant positive relationship between phytoplankton biomass and phytoplankton δ13C signatures as well as a significant nonlinear negative relationship between water column ρCO2 and isotopic composition of phytoplankton, indicating a shift from diffusive uptake to active uptake by phytoplankton of CO2 or HCO3− during blooms. Calculated photosynthetic fractionation factors indicated that this shift occurs specifically when surface water CO2 drops below atmospheric equilibrium. Our results indicate that active HCO3− uptake via CCMs may be an important mechanism in maintaining phytoplankton blooms when CO2 is depleted. Further increases in anthropogenic pressure, eutrophication, and cyanobacteria blooms are therefore expected to contribute to increased bicarbonate uptake to sustain primary production.

  16. Cyanobacterial carbon concentrating mechanisms facilitate sustained CO2 depletion in eutrophic lakes

    Science.gov (United States)

    Morales-Williams, Ana M.; Wanamaker, Alan D., Jr.; Downing, John A.

    2017-06-01

    Phytoplankton blooms are increasing in frequency, intensity, and duration in aquatic ecosystems worldwide. In many eutrophic lakes, these high levels of primary productivity correspond to periods of CO2 depletion in surface waters. Cyanobacteria and other groups of phytoplankton have the ability to actively transport bicarbonate (HCO3-) across their cell membrane when CO2 concentrations are limiting, possibly giving them a competitive advantage over algae not using carbon concentrating mechanisms (CCMs). To investigate whether CCMs can maintain phytoplankton bloom biomass under CO2 depletion, we measured the δ13C signatures of dissolved inorganic carbon (δ13CDIC) and phytoplankton particulate organic carbon (δ13Cphyto) in 16 mesotrophic to hypereutrophic lakes during the ice-free season of 2012. We used mass-balance relationships to determine the dominant inorganic carbon species used by phytoplankton under CO2 stress. We found a significant positive relationship between phytoplankton biomass and phytoplankton δ13C signatures as well as a significant nonlinear negative relationship between water column ρCO2 and isotopic composition of phytoplankton, indicating a shift from diffusive uptake to active uptake by phytoplankton of CO2 or HCO3- during blooms. Calculated photosynthetic fractionation factors indicated that this shift occurs specifically when surface water CO2 drops below atmospheric equilibrium. Our results indicate that active HCO3- uptake via CCMs may be an important mechanism in maintaining phytoplankton blooms when CO2 is depleted. Further increases in anthropogenic pressure, eutrophication, and cyanobacteria blooms are therefore expected to contribute to increased bicarbonate uptake to sustain primary production.

  17. Field demonstration of CO2 leakage detection in potable aquifers with a pulselike CO2-release test.

    Science.gov (United States)

    Yang, Changbing; Hovorka, Susan D; Delgado-Alonso, Jesus; Mickler, Patrick J; Treviño, Ramón H; Phillips, Straun

    2014-12-02

    This study presents two field pulselike CO2-release tests to demonstrate CO2 leakage detection in a shallow aquifer by monitoring groundwater pH, alkalinity, and dissolved inorganic carbon (DIC) using the periodic groundwater sampling method and a fiber-optic CO2 sensor for real-time in situ monitoring of dissolved CO2 in groundwater. Measurements of groundwater pH, alkalinity, DIC, and dissolved CO2 clearly deviated from their background values, showing responses to CO2 leakage. Dissolved CO2 observed in the tests was highly sensitive in comparison to groundwater pH, DIC, and alkalinity. Comparison of the pulselike CO2-release tests to other field tests suggests that pulselike CO2-release tests can provide reliable assessment of geochemical parameters indicative of CO2 leakage. Measurements by the fiber-optic CO2 sensor, showing obvious leakage signals, demonstrated the potential of real-time in situ monitoring of dissolved CO2 for leakage detection at a geologic carbon sequestration (GCS) site. Results of a two-dimensional reactive transport model reproduced the geochemical measurements and confirmed that the decrease in groundwater pH and the increases in DIC and dissolved CO2 observed in the pulselike CO2-release tests were caused by dissolution of CO2 whereas alkalinity was likely affected by carbonate dissolution.

  18. CO2 Emissions from Fuel Combustion - 2012 Highlights

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2012-07-01

    How much CO2 are countries emitting? Where is it coming from? In the lead-up to the UN climate negotiations in Doha, the latest information on the level and growth of CO2 emissions, their source and geographic distribution will be essential to lay the foundation for a global agreement. To provide input to and support for the UN process the IEA is making available for free download the 'Highlights' version of CO2 Emissions from Fuel Combustion. This annual publication contains: estimates of CO2 emissions by country from 1971 to 2010; selected indicators such as CO2/GDP, CO2/capita, CO2/TPES and CO2/kWh; and CO2 emissions from international marine and aviation bunkers, and other relevant information.

  19. Photocatalytic Reduction of Low Concentration of CO2.

    Science.gov (United States)

    Nakajima, Takuya; Tamaki, Yusuke; Ueno, Kazuki; Kato, Eishiro; Nishikawa, Tetsuya; Ohkubo, Kei; Yamazaki, Yasuomi; Morimoto, Tatsuki; Ishitani, Osamu

    2016-10-05

    A novel molecular photocatalytic system with not only high reduction ability of CO2 but also high capture ability of CO2 has been developed using a Ru(II)-Re(I) dinuclear complex as a photocatalyst. By using this photocatalytic system, CO2 of 10% concentration could be selectively converted to CO with almost same photocatalysis to that under a pure CO2 atmosphere (TONCO > 1000, ΦCO > 0.4). Even 0.5% concentration of CO2 was reduced with 60% initial efficiency of CO formation by using the same system compared to that using pure CO2 (TONCO > 200). The Re(I) catalyst unit in the photocatalyst can efficiently capture CO2, which proceeds CO2 insertion to the Re-O bond, and then reduce the captured CO2 by using an electron supplied from the photochemically reduced Ru photosensitizer unit.

  20. CO(2) Inhibits Respiration in Leaves of Rumex crispus L.

    Science.gov (United States)

    Amthor, J S; Koch, G W; Bloom, A J

    1992-02-01

    Curly dock (Rumex crispus L.) was grown from seed in a glasshouse at an ambient CO(2) partial pressure of about 35 pascals. Apparent respiration rate (CO(2) efflux in the dark) of expanded leaves was then measured at ambient CO(2) partial pressure of 5 to 95 pascals. Calculated intercellular CO(2) partial pressure was proportional to ambient CO(2) partial pressure in these short-term experiments. The CO(2) level strongly affected apparent respiration rate: a doubling of the partial pressure of CO(2) typically inhibited respiration by 25 to 30%, whereas a decrease in CO(2) elicited a corresponding increase in respiration. These responses were readily reversible. A flexible, sensitive regulatory interaction between CO(2) (a byproduct of respiration) and some component(s) of heterotrophic metabolism is indicated.

  1. CO2 Emissions from Fuel Combustion 2011: Highlights

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2011-07-01

    How much CO2 are countries emitting? Where is it coming from? In the lead-up to the UN climate negotiations in Durban, the latest information on the level and growth of CO2 emissions, their source and geographic distribution will be essential to lay the foundation for a global agreement. To provide input to and support for the UN process the IEA is making available for free download the 'Highlights' version of CO2 Emissions from Fuel Combustion. This annual publication contains: - estimates of CO2 emissions by country from 1971 to 2009; - selected indicators such as CO2/GDP, CO2/capita, CO2/TPES and CO2/kWh; - CO2 emissions from international marine and aviation bunkers, and other relevant information. These estimates have been calculated using the IEA energy databases and the default methods and emission factors from the Revised 1996 IPCC Guidelines for National Greenhouse Gas Inventories.

  2. Reducing CO2 from shipping – do non-CO2 effects matter?

    Directory of Open Access Journals (Sweden)

    M. S. Eide

    2013-04-01

    Full Text Available Shipping is a growing sector in the global economy, and it contributions to global CO2 emissions are expected to increase. CO2 emissions from the world shipping fleet will likely be regulated in the near future, and studies have shown that significant emission reductions can be achieved at low cost. Regulations are being discussed for both existing ships as well as for future additions to the fleet. In this study a plausible CO2 emission reduction inventory is constructed for the cargo fleet existing in 2010, as well as for container ships, bulk ships and tankers separately. In the reduction inventories, CO2 emissions are reduced by 25–32% relative to baseline by applying 15 technical and operational emission reduction measures in accordance with a ship-type-specific cost-effectiveness criterion, and 9 other emission compounds are changed as a technical implication of reducing CO2. The overall climate and environmental effects of the changes to all 10 emission components in the reduction inventory are assessed using a chemical transport model, radiative forcing (RF models and a simple climate model. We find substantial environmental and health benefits with up to 5% reduction in surface ozone levels, 15% reductions in surface sulfate and 10% reductions in wet deposition of sulfate in certain regions exposed to heavy ship traffic. The major ship types show distinctly different contributions in specific locations. For instance, the container fleet contributes 50% of the sulfate decline on the west coast of North America. The global radiative forcing from a 1 yr emission equal to the difference between baseline and reduction inventory shows an initial strong positive forcing from non-CO2 compounds. This warming effect is due to reduced cooling by aerosols and methane. After approximately 25 yr, the non-CO2 forcing is balanced by the CO2 forcing. For the global mean temperature change, we find a shift from warming to cooling after approximately 60

  3. A global coupled Eulerian-Lagrangian model and 1 × 1 km CO2 surface flux dataset for high-resolution atmospheric CO2 transport simulations

    Directory of Open Access Journals (Sweden)

    R. Toumi

    2012-02-01

    Full Text Available We designed a method to simulate atmospheric CO2 concentrations at several continuous observation sites around the globe using surface fluxes at a very high spatial resolution. The simulations presented in this study were performed using the Global Eulerian-Lagrangian Coupled Atmospheric model (GELCA, comprising a Lagrangian particle dispersion model coupled to a global atmospheric tracer transport model with prescribed global surface CO2 flux maps at a 1 × 1 km resolution. The surface fluxes used in the simulations were prepared by assembling the individual components of terrestrial, oceanic and fossil fuel CO2 fluxes. This experimental setup (i.e. a transport model running at a medium resolution, coupled to a high-resolution Lagrangian particle dispersion model together with global surface fluxes at a very high resolution, which was designed to represent high-frequency variations in atmospheric CO2 concentration, has not been reported at a global scale previously. Two sensitivity experiments were performed: (a using the global transport model without coupling to the Lagrangian dispersion model, and (b using the coupled model with a reduced resolution of surface fluxes, in order to evaluate the performance of Eulerian-Lagrangian coupling and the role of high-resolution fluxes in simulating high-frequency variations in atmospheric CO2 concentrations. A correlation analysis between observed and simulated atmospheric CO2 concentrations at selected locations revealed that the inclusion of both Eulerian-Lagrangian coupling and high-resolution fluxes improves the high-frequency simulations of the model. The results highlight the potential of a coupled Eulerian-Lagrangian model in simulating high-frequency atmospheric CO2 concentrations at many locations worldwide. The model performs well in representing observations of atmospheric CO2 concentrations at high spatial and temporal resolutions, especially for coastal sites and sites located close to

  4. A very high-resolution (1 km?1 km) global fossil fuel CO2 emission inventory derived using a point source database and satellite observations of nighttime lights

    National Research Council Canada - National Science Library

    T. Oda; S. Maksyutov

    2011-01-01

    .... We developed a global 1 km×1 km annual fossil fuel CO 2 emission inventory for the years 1980-2007 by combining a worldwide point source database and satellite observations of the global nightlight distribution...

  5. Supercritical CO2 as a substitute of volatile hydrocarbons; Superkritisch CO2 vervangt vluchtige koolwaterstoffen

    Energy Technology Data Exchange (ETDEWEB)

    Folkerts, G. (ed.)

    2006-05-15

    In many cases supercritical carbon dioxide can replace volatile hydrocarbons in extraction processes. Currently gaseous or liquid CO2 is already used for industrial purification processes, extraction of caffeine from coffee and as a solvent for paint. Although supercritical extraction s a batch process the technique can be applied as a continuous process. [Dutch] In processen waar vluchtige koolwaterstoffen worden ingezet om stoffen te extraheren, biedt superkritisch CO2 een milieuvriendelijk alternatief. Het koolzuur dat zowel in de vloeistof- als gasfase zit, wordt dan ook steeds meer ingezet in extractieprocessen.

  6. Responses of soil CO2 efflux to changes in plant CO2 uptake and transpiration

    Science.gov (United States)

    Balogh, János; de Luca, Giulia; Mészáros, Ádám; Trieber, Júlia; Gecse, Bernadett; Fóti, Szilvia; Pintér, Krisztina; Nagy, Zoltán

    2017-04-01

    Biotic drivers of soil respiration represent a significant supply-side (plant) control of the process. Those biotic drivers that integrate over longer time periods are useful in describing the phenological changes and physiological state of the vegetation, but they are not suitable to explain the diel variability of soil respiration. Two plant physiological processes, acting in opposite directions, could be relevant at diel timescale: (1) photosynthesis, and (2) transpiration. Firstly, it was recently found that photosynthesis has a time-lagged (a few hours) positive effect on the respiration of roots and root-associated microbes. This can be explainedby an increase in easily accessible non-structural hydrocarbon sources for the roots and root-associated organisms within this period. Secondly, it was found that the effect of transpiration could reduce root respiration due to CO2 transport through the transpiration stream, and this effect is expected to be immediate. Removing the effect of the abiotic drivers from the soil efflux signal could help to clarify the role of other driving variables. In the present study, we conducted manipulation measurements in lab environment to be able to detect the effects of the plant physiological variables (CO2 uptake, transpiration) on soil CO2 efflux. Plant individuals were planted into field soil samples in small pots. Transpiration manipulation was done by regulating vapour pressure of the air around the plant canopy and by inhibitors. Photosynthesis manipulation consisted of programmed absence of light. Isotopic signatures of soil respiration were used for estimating the contribution of the autotrophic and heterotrophic soil respiration components. 13CO2 concentration of the CO2 efflux of the different soil components was measured continuously in open system by cavity ring-down spectroscopy (Picarro G1101-i gas analyser). Keeling-plot approach was also used to calculate the isotopic signals of the sources. According to the

  7. Plasma Arc Augmented CO2 laser welding

    DEFF Research Database (Denmark)

    Bagger, Claus; Andersen, Mikkel; Frederiksen, Niels

    2001-01-01

    In order to reduce the hardness of laser beam welded 2.13 mm medium strength steel CMn 250, a plasma arc has been used simultaneously with a 2.6 kW CO2 laser source. In a number of systematic laboratory tests, the plasma arc current, plasma gas flow and distance to the laser source were varied...... with all laser parameters fixed. The welds were quality assessed and hardness measured transversely to the welding direction in the top, middle and root of the seam. In the seams welded by laser alone, hardness values between 275 and 304 HV1 were measured, about the double of the base material, 150 HV1...

  8. High gain, multiatmosphere CO2 laser amplifier

    Science.gov (United States)

    Stuart, G. C.; Houtman, H.; Meyer, J.

    1987-02-01

    A novel TE discharge, 15-mm aperture, multiatmosphere, CO2 laser amplifier is described, with measured electrical characteristics and gain measurements on the 9.294-micron, 9R (16) line. The electrical circuit used in this amplifier is a realistic alternative to the Marx bank or conventional LC inversion circuit and, similarly, it would be useful for excitation of other gas lasers as well. This automatically preionized, double-sided, fourfold LC inversion circuit uses only one spark gap, and it is shown to provide small-signal gains of 5.7 percent/cm, at 120 J/l atm and 10 atm. The generalization to an n-stage device, which would be suitable for higher pressures, and larger apertures, is discussed.

  9. CO2 laser therapy of rhinophyma

    Science.gov (United States)

    Voigt, Peggy; Jovanovic, Sergije; Sedlmaier, Benedikt W.

    2000-06-01

    Laser treatment of skin changes has become common practice in recent years. High absorption of the CO2 laser wavelength in water is responsible for its low penetration dpt in biological tissue. Shortening the tissue exposure time minimizes thermic side effects of laser radiation such as carbonization and coagulation. This can be achieved with scanner systems that move the focused laser beam over a defined area by microprocessor-controlled rapidly rotating mirrors. This enables controlled and reliable removal of certain dermal lesions, particularly hypertrophic scar/span>s, scars after common acne, wrinkles and rhinophyma. Laser ablation of rhinophyma is a stress-minimizing procedure for the surgeon and the patient, since it is nearly bloodless and can be performed under local anaesthesia. Cosmetically favorable reepithelization of the lasered surfaces is achieved within a very short period of time.

  10. Smart Transportation CO2 Emission Reduction Strategies

    Science.gov (United States)

    Tarulescu, S.; Tarulescu, R.; Soica, A.; Leahu, C. I.

    2017-10-01

    Transport represents the sector with the fastest growing greenhouse gas emissions around the world. The main global objective is to reduce energy usage and associated greenhouse gas emissions from the transportation sector. For this study it was analyzed the road transportation system from Brasov Metropolitan area. The study was made for the transportation route that connects Ghimbav city to the main surrounding objectives. In this study ware considered four optimization measures: vehicle fleet renewal; building the detour belt for the city; road increasing the average travel speed; making bicycle lanes; and implementing an urban public transport system for Ghimbav. For each measure it was used a mathematical model to calculate the energy consumption and carbon emissions from the road transportation sector. After all four measures was analyzed is calculated the general energy consumption and CO2 reduction if this are applied from year 2017 to 2020.

  11. Enhanced Molecular Sieve CO2 Removal Evaluation

    Science.gov (United States)

    Rose, Susan; ElSherif, Dina; MacKnight, Allen

    1996-01-01

    The objective of this research is to quantitatively characterize the performance of two major types of molecular sieves for two-bed regenerative carbon dioxide removal at the conditions compatible with both a spacesuit and station application. One sorbent is a zeolite-based molecular sieve that has been substantially improved over the materials used in Skylab. The second sorbent is a recently developed carbon-based molecular sieve. Both molecular sieves offer the potential of high payoff for future manned missions by reducing system complexity, weight (including consumables), and power consumption in comparison with competing concepts. The research reported here provides the technical data required to improve CO2 removal systems for regenerative life support systems for future IVA and EVA missions.

  12. Phase Locking of CO(2) Lasers.

    Science.gov (United States)

    Weingartner, W; Schröder, K; Schuöcker, D

    2001-05-20

    A method of phase locking two CO(2) lasers by radiation exchange is presented. This phase-locking was achieved by use of a copper prism as a beam folding device in the resonators and extraction of the output radiation by a common output coupler. Energy exchange led to a phase-locked state if several locking conditions were fulfilled. The amount of radiation injected from one resonator to the second cavity could be adjusted by movement of the prism. The influence of the strength of coupling on the locking range was studied. The beat signal between the two unlocked lasers could be measured, whereas in the case of phase-locked operation twice the intensity was detected. Despite the inclusion of several assumptions, a simplified mathematical model delivered good agreement between calculated and experimental results.

  13. Experimental Investigations into CO2 Interactions with Injection Well Infrastructure for CO2 Storage

    Science.gov (United States)

    Syed, Amer; Shi, Ji-Quan; Durucan, Sevket; Nash, Graham; Korre, Anna

    2013-04-01

    Wellbore integrity is an essential requirement to ensure the success of a CO2 Storage project as leakage of CO2 from the injection or any other abandoned well in the storage complex, could not only severely impede the efficiency of CO2 injection and storage but also may result in potential adverse impact on the surrounding environment. Early research has revealed that in case of improper well completions and/or significant changes in operating bottomhole pressure and temperature could lead to the creation of microannulus at cement-casing interface which may constitute a preferential pathway for potential CO2 leakage during and post injection period. As a part of a European Commission funded CO2CARE project, the current research investigates the sealing behaviour of such microannulus at the cement-casing interface under simulated subsurface reservoir pressure and temperature conditions and uses the findings to develop a methodology to assess the overall integrity of CO2 storage. A full scale wellbore experimental test set up was constructed for use under elevated pressure and temperature conditions as encountered in typical CO2 storage sites. The wellbore cell consists of an assembly of concentric elements of full scale casing (Diameter= 0.1524m), cement sheath and an outer casing. The stainless steel outer ring is intended to simulate the stiffness offered by the reservoir rock to the displacement applied at the wellbore. The Central Loading Mechanism (CLM) consists of four case hardened shoes that can impart radial load onto the well casing. The radial movement of the shoes is powered through the synchronised movement of four precision jacks controlled hydraulically which could impart radial pressures up to 15 MPa. The cell body is a gas tight enclosure that houses the wellbore and the central loading mechanism. The setup is enclosed in a laboratory oven which acts both as temperature and safety enclosure. Prior to a test, cement mix is set between the casing and

  14. Geochemical monitoring of Taal volcano (Philippines) by means of diffuse CO2 degassing studies

    Science.gov (United States)

    Padrón, Eleazar; Hernández, Pedro A.; Arcilla, Carlo; Pérez, Nemesio M.; Lagmay, Alfredo M.; Rodríguez, Fátima; Quina, Gerald; Alonso, Mar; Padilla, Germán D.; Aurelio, Mario A.

    2017-04-01

    Observing changes in the discharge rate of CO2 is an important part of volcanic monitoring programs, because it is released by progressive depressurization of magma during ascent and reach the surface well before their parental magma. Taal Volcano in Southwest Luzon, Philippines, lies between a volcanic arc front facing the subduction zone along the Manila Trench and a volcanic field formed from extension beyond the arc front. Taal Volcano Island is formed by a main tuff cone surrounded by several smaller tuff cones, tuff rings and scoria cones. This island is located in the center of the 30 km wide Taal Caldera, now filled by Taal Lake. To monitor the volcanic activity of Taal volcano is a priority task in the Philippines, because several million people live within a 20-km radius of Taal's caldera rim. During the last period of volcanic unrest from 2010 to 2011, the main crater lake of Taal volcano released the highest diffuse CO2 emission rates through the water surface reported to date by volcanic lakes worldwide. The maximum CO2 emission rate measured in the study period occurred two months before the strongest seismic activity recorded during the unrest period (Arpa et al., 2013, Bull Volcanol 75:747). After the unrest period, diffuse CO2 emission has remained in the range 532-860 t/d in the period 2013-2016. In January 2016, an automatic geochemical station to monitor in a continuous mode the diffuse CO2 degassing in a selected location of Taal, was installed in January 2016 to improve the early warning system at the volcano. The station is located at Daang Kastila, at the northern portion of the main crater rim. It measures hourly the diffuse CO2 efflux, atmospheric CO2 concentration, soil water content and temperature, wind speed and direction, air temperature and humidity, rainfall, and barometric pressure. The 2016 time series show CO2 efflux values in the range 20-690 g m-2 d-1.Soil temperature, heavily influenced by rainfall, ranged between 74 and 96o

  15. Debunking the Myth of the Strategic Corporal

    Science.gov (United States)

    2015-04-13

    To) 13-04-2015 Master’ s Thesis 21-07-2014 to 12-06-2015 4. TITLE AND SUBTITLE Sa. CONTRACT NUMBER Debunking the Myth of the Strategic Corporal...anyone but themselves . A thorough analysis of a series of contemporary historical case studies debunks the myth of the strategic corporal and...demonstrates errors in policy or strategic level decisions ultimately affect the outcome of an operation and because the strategic corporal is a myth

  16. Enhanced transport phenomena in CO2 sequestration and CO2 EOR

    NARCIS (Netherlands)

    Farajzadeh, R.

    2009-01-01

    The results of this thesis give insight into the (mass)-transfer during flow of gases, especially CO2, in various gas-liquid systems. A number of experiments was performed to investigate the transport phenomena through interfaces with and without surfactant monolayers. The observed phenomena have

  17. Root-derived CO2 efflux via xylem stream rivals soil CO2 efflux

    Science.gov (United States)

    Doug P. Aubrey; Robert O. Teskey

    2009-01-01

    Respiration consumes a large portion of annual gross primary productivity in forest ecosystems and is dominated by belowground metabolism. Here, we present evidence of a previously unaccounted for internal CO2 flux of large magnitude from tree roots through stems. If this pattern is shown to persist over time and in other forests, it suggests...

  18. DEPLETED HYDROCARBON RESERVOIRS AND CO2 INJECTION WELLS –CO2 LEAKAGE ASSESSMENT

    Directory of Open Access Journals (Sweden)

    Nediljka Gaurina-Međimurec

    2017-03-01

    Full Text Available Migration risk assessment of the injected CO2 is one of the fi rst and indispensable steps in determining locations for the implementation of projects for carbon dioxide permanent disposal in depleted hydrocarbon reservoirs. Within the phase of potential storage characterization and assessment, it is necessary to conduct a quantitative risk assessment, based on dynamic reservoir models that predict the behaviour of the injected CO2, which requires good knowledge of the reservoir conditions. A preliminary risk assessment proposed in this paper can be used to identify risks of CO2 leakage from the injection zone and through wells by quantifying hazard probability (likelihood and severity, in order to establish a risk-mitigation plan and to engage prevention programs. Here, the proposed risk assessment for the injection well is based on a quantitative risk matrix. The proposed assessment for the injection zone is based on methodology used to determine a reservoir probability in exploration and development of oil and gas (Probability of Success, abbr. POS, and modifi ed by taking into account hazards that may lead to CO2 leakage through the cap rock in the atmosphere or groundwater. Such an assessment can eliminate locations that do not meet the basic criteria in regard to short-term and long-term safety and the integrity of the site

  19. CO2-ECBM and CO2 Sequestration in Polish Coal Seam – Experimental Study

    Directory of Open Access Journals (Sweden)

    Paweł Baran

    2014-01-01

    Originality/value: The results indicate successful sorption of carbon dioxide in each experiment. This provides the rationale to study the application of the coal tested to obtain methane genetic origin genetic methane with the use of the CO2 injection.

  20. FISH PRODUCTION WORLDWIDE

    Directory of Open Access Journals (Sweden)

    Georgiana Melania COSTAICHE

    2014-12-01

    Full Text Available Fishing is one of the oldest occupations, which over the years has gone through several stages. In the economic terms the increase in intensive industrial system of the fish is advantageous because the specific energy consumption is low, given that they not need to maintain body temperature at high temperatures. Having regard to demographic trends in continue increasing, and the tendency of decrease fisheries leads to increased the production of aquaculture fish by order to ensure enough quantity and quality. The purpose of this paper is to highlight the evolution of fish production worldwide and in particular to show the evolution of production of fish from fisheries and aquaculture. To highlight the evolution global fish production given two ways to get fish respectively from aquaculture and fisheries, that have used data from FAOSTAT for 2007-2012. Also we can see that approximately 90% of the fish production is fished in the sea and only 10% in the territorial waters. The fish production in Africa had an ascending trend in the period under review. Analyzing fish production the share of total world continents is noted that Asia has a share of 68% in 2007 and increase to 73% in 2012.

  1. New worldwide lipid guidelines.

    Science.gov (United States)

    Saraf, Smriti; Ray, Kausik K

    2015-07-01

    Atherosclerotic cardiovascular disease (ASCVD) remains the leading cause of morbidity and mortality in most countries. Modification of common risk factors such as dyslipidaemia can result in significant reduction of ASCVD incidence in the population and improve clinical outcomes. The purpose of this review is to discuss and compare the latest worldwide lipid guidelines, and to demonstrate the variation in practice in different parts of the world. The lipid guidelines have recently been updated in different countries. The National Institute for Health and Care Excellence (NICE) guidelines in the United Kingdom were issued in July 2014, are risk based and are broadly similar to the American College of Cardiology/American Heart Association task force guidelines that were published in November 2013. Both these guidelines are in variance with both the Canadian Guidelines and the European Society of Cardiology/European Atherosclerosis Society guidelines 2011, which are target based and have different risk scoring systems, which results in significant variation in practice and increased healthcare costs in certain countries. The difference in guidelines in different countries makes it difficult for the clinician to standardize the treatment provided to individuals. The variance in risk scoring systems makes it difficult to compare risk prediction tools across countries and hence the optimum treatment available for a given population. Standardization of guidelines based on randomized controlled trial data and validation and calibration of various risk scoring systems could help improve clinical outcomes in this high-risk group of individuals at risk of ASCVD within individual countries.

  2. Construction Management--Exploding Some Myths.

    Science.gov (United States)

    Kluenker, Charles

    1986-01-01

    Construction management on educational facility projects provides boards of education with documentation showing the project is on track. Eight "myths" surrounding construction management are explained. (MLF)

  3. Novel Long-Term CO2 Removal System Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Current Technology for CO2 removal from enclosed air of spacecraft utilizes LiOH canisters for CO2 absorption. This absorption is irreversible so longer flights...

  4. Framework for Assessing Biogenic CO2 Emissions from Stationary Sources

    Science.gov (United States)

    This revision of the 2011 report, Accounting Framework for Biogenic CO2 Emissions from Stationary Sources, evaluates biogenic CO2 emissions from stationary sources, including a detailed study of the scientific and technical issues associated with assessing biogenic carbon dioxide...

  5. Comparison of regional and ecosystem CO2 fluxes

    DEFF Research Database (Denmark)

    Gryning, Sven-Erik; Søgaard, Henrik; Batchvarova, Ekaterina

    2009-01-01

    A budget method to derive the regional surface flux of CO2 from the evolution of the boundary layer is presented and applied. The necessary input for the method can be deduced from a combination of vertical profile measurements of CO2 concentrations by i.e. an airplane, successive radio......-soundings and standard measurements of the CO2 concentration near the ground. The method was used to derive the regional flux of CO2 over an agricultural site at Zealand in Denmark during an experiment on 12–13 June 2006. The regional fluxes of CO2 represent a combination of agricultural and forest surface conditions....... It was found that the regional flux of CO2 in broad terms follows the behavior of the flux of CO2 at the agricultural (grassland) and the deciduous forest station. The regional flux is comparable not only in size but also in the diurnal (daytime) cycle of CO2 fluxes at the two stations....

  6. Non-CO2 Greenhouse Gases: International Emissions and Projections

    Science.gov (United States)

    EPA August 2011 report on global non-CO2 emissions projections (1990-2030) for emissions of non-CO2 greenhouse gases (methane, nitrous oxide, and fluorinated greenhouse gases) from more than twenty emissions sources.

  7. Understanding and predicting trends in north Atlantic CO2 uptake

    Science.gov (United States)

    Halloran, Paul; Lebehot, Alice; Watson, Andy; McNeall, Doug; Ford, David; Schuster, Ute

    2017-04-01

    To determine the maximum carbon dioxide (CO2) emissions society must commit to, to remain below a given atmospheric CO2 threshold, the scientific community must robustly quantify what proportion of human emitted CO2 will be taken up by the land and marine carbon reservoirs. The North Atlantic Ocean is the most intense marine sink of anthropogenic CO2 on the planet, accounting for about a fifth of the global oceanic anthropogenic CO2 uptake, despite covering just 15% of the global ocean area. Carefully assessing uncertainties, we quantify the real-world trend in North Atlantic CO2 uptake over the past two decades. Comparing this to results from state-of-the-art climate models, we find that models are systematically underestimating the observed CO2 uptake trend. By performing a set of targeted climate model simulations, we diagnose and account for this bias, and produce the first set of observation-informed future ocean CO2 uptake predictions.

  8. Chemical reduction of CO2 facilitated by C-nucleophiles.

    Science.gov (United States)

    Janes, Trevor; Yang, Yanxin; Song, Datong

    2017-10-17

    The abundance of atmospheric CO2 presents both an opportunity and a challenge for synthetic chemists to transform CO2 into value-added products. A promising strategy involves CO2 reduction driven by the energy stored in chemical bonds and promoted by molecules containing nucleophilic carbon sites. This approach allows the synthesis of new C-C or C-H bonds from CO2-derived carbon. The first part of this Feature article deals with uncatalyzed reductions of CO2 such as insertion into metal-carbon bonds and reactivity towards multidentate actor ligands and metal-free compounds. The second part covers catalytic reduction of CO2 in which a nucleophilic C-site is involved. This review brings together two general approaches in the chemical CO2 reduction field, showing how the discovery of fundamental reactivity of CO2 leads to synthetic applications, and proposes directions for further development.

  9. Le soleil devient un mythe

    Directory of Open Access Journals (Sweden)

    Ildikó Lőrinszky

    2009-01-01

    Full Text Available Partant d’une phrase énigmatique datant de 1858 et puisée dans la Correspondance de Flaubert, cet article s’interroge sur la relation entre soleil et mythe, qui constituera l’un des éléments clefs de la dimension mythologique de Salammbô. Il se propose d’examiner la façon dont cette question apparaît dans deux ouvrages représentatifs des études mythographiques : d’une part, L’Origine de tous les cultes de Charles-François Dupuis, d’autre part, Les Religions de l’Antiquité..., publié sous les noms de Frédéric Creuzer et de son adaptateur français, Joseph-Daniel Guigniault. La version française de la grande synthèse de Creuzer, assortie d’une série importante de planches, a été richement exploitée par Flaubert au cours de la genèse du roman carthaginois. Dans Salammbô, le mythe apparaît sous de multiples formes. L’analyse de ce texte peut nous amener à réfléchir sur le « bon usage » du mythe auquel chaque créateur (et chaque lecteur se trouve nécessairement confronté.Starting from an enigmatic phrase in Flaubert’s correspondence, dating from 1858, this article examines the relation between the Sun and myth, which constitutes one of the key elements of the mythological dimension of Salammbô. It especially focuses on the treatment of this question in two representative works of mythographic studies, The Origin of All Religious Worship by Charles-François Dupuis, and Les Religions de l’Antiquité..., the French adaptation of Frédéric Creuzer’s Symbolik und Mythologie der alten Völker by Joseph-Daniel Guigniault. The French version of Creuzer’s great synthesis, supplied with a remarkable set of prints, was abundantly consulted by Flaubert when writing his Carthaginian novel. In Salammbô, myth takes on various forms. Analyzing this text might lead one to reconsider “the right way” to use myths — a problem all writers (and readers find themselves confronted with.

  10. Proliferation: myth or reality?; La proliferation: mythe ou realite?

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2005-07-01

    This article analyzes the proliferation approach, its technical condition and political motivation, and the share between the myth (political deception, assumptions and extrapolations) and the reality of proliferation. Its appreciation is complicated by the irrational behaviour of some political actors and by the significant loss of the non-use taboo. The control of technologies is an important element for proliferation slowing down but an efficient and autonomous intelligence system remains indispensable. (J.S.)

  11. Atmospheric measurement of point source fossil fuel CO2 emissions

    Science.gov (United States)

    Turnbull, J. C.; Keller, E. D.; Baisden, W. T.; Brailsford, G.; Bromley, T.; Norris, M.; Zondervan, A.

    2013-11-01

    We use the Kapuni Gas Treatment Plant to examine methodologies for atmospheric monitoring of point source fossil fuel CO2 (CO2ff) emissions. The Kapuni plant, located in rural New Zealand, removes CO2 from locally extracted natural gas and vents that CO2 to the atmosphere, at a rate of ~0.1 Tg carbon per year. The plant is located in a rural dairy farming area, with no other significant CO2ff sources nearby, but large, diurnally varying, biospheric CO2 fluxes from the surrounding highly productive agricultural grassland. We made flask measurements of CO2 and 14CO2 (from which we derive the CO2ff component) and in situ measurements of CO2 downwind of the Kapuni plant, using a Helikite to sample transects across the emission plume from the surface up to 100 m a.g.l. We also determined the surface CO2ff content averaged over several weeks from the 14CO2 content of grass samples collected from the surrounding area. We use the WindTrax plume dispersion model to compare the atmospheric observations with the emissions reported by the Kapuni plant, and to determine how well atmospheric measurements can constrain the emissions. The model has difficulty accurately capturing the fluctuations and short-term variability in the Helikite samples, but does quite well in representing the observed CO2ff in 15 min averaged surface flask samples and in ~1 week integrated CO2ff averages from grass samples. In this pilot study, we found that using grass samples, the modeled and observed CO2ff emissions averaged over one week agreed to within 30%. The results imply that greater verification accuracy may be achieved by including more detailed meteorological observations and refining 14CO2 sampling strategies.

  12. Can elevated CO(2) improve salt tolerance in olive trees?

    Science.gov (United States)

    Melgar, Juan Carlos; Syvertsen, James P; García-Sánchez, Francisco

    2008-04-18

    We compared growth, leaf gas exchange characteristics, water relations, chlorophyll fluorescence, and Na(+) and Cl(-) concentration of two cultivars ('Koroneiki' and 'Picual') of olive (Olea europaea L.) trees in response to high salinity (NaCl 100mM) and elevated CO(2) (eCO(2)) concentration (700microLL(-1)). The cultivar 'Koroneiki' is considered to be more salt sensitive than the relatively salt-tolerant 'Picual'. After 3 months of treatment, the 9-month-old cuttings of 'Koroneiki' had significantly greater shoot growth, and net CO(2) assimilation (A(CO(2))) at eCO(2) than at ambient CO(2), but this difference disappeared under salt stress. Growth and A(CO(2)) of 'Picual' did not respond to eCO(2) regardless of salinity treatment. Stomatal conductance (g(s)) and leaf transpiration were decreased at eCO(2) such that leaf water use efficiency (WUE) increased in both cultivars regardless of saline treatment. Salt stress increased leaf Na(+) and Cl(-) concentration, reduced growth and leaf osmotic potential, but increased leaf turgor compared with non-salinized control plants of both cultivars. Salinity decreased A(CO(2)), g(s), and WUE, but internal CO(2) concentrations in the mesophyll were not affected. eCO(2) increased the sensitivity of PSII and chlorophyll concentration to salinity. eCO(2) did not affect leaf or root Na(+) or Cl(-) concentrations in salt-tolerant 'Picual', but eCO(2) decreased leaf and root Na(+) concentration and root Cl(-) concentration in the more salt-sensitive 'Koroneiki'. Na(+) and Cl(-) accumulation was associated with the lower water use in 'Koroneiki' but not in 'Picual'. Although eCO(2) increased WUE in salinized leaves and decreased salt ion uptake in the relatively salt-tolerant 'Koroneiki', growth of these young olive trees was not affected by eCO(2).

  13. [Effects of plastic film mulching on soil CO2 efflux and CO2 concentration in an oasis cotton field].

    Science.gov (United States)

    Yu, Yong-xiang; Zhao, Cheng-yi; Jia, Hong-tao; Yu, Bo; Zhou, Tian-he; Yang, Yu-guang; Zhao, Hua

    2015-01-01

    A field study was conducted to compare soil CO2 efflux and CO2 concentration between mulched and non-mulched cotton fields by using closed chamber method and diffusion chamber technique. Soil CO2 efflux and CO2 concentration exhibited a similar seasonal pattern, decreasing from July to October. Mulched field had a lower soil CO2 efflux but a higher CO2 concentration, compared to those of non-mulched fields. Over the measurement period, cumulative CO2 efflux was 1871.95 kg C . hm-2 for mulched field and 2032.81 kg C . hm-2 for non-mulched field. Soil CO2 concentration was higher in mulched field (ranging from 5137 to 25945 µL . L-1) than in non- mulched field (ranging from 2165 to 23986 µL . L-1). The correlation coefficients between soil CO2 concentrations at different depths and soil CO2 effluxes were 0.60 to 0.73 and 0.57 to 0.75 for the mulched and non-mulched fields, indicating that soil CO2 concentration played a crucial role in soil CO2 emission. The Q10 values were 2.77 and 2.48 for the mulched and non-mulched fields, respectively, suggesting that CO2 efflux in mulched field was more sensitive to the temperature.

  14. Ultimate doctor liability: a myth of ignorance or myth of control?

    Science.gov (United States)

    Cashin, Andrew; Carey, Michael; Watson, Ngaire; Clark, Greg; Newman, Claire; Waters, Cheryl D

    2009-01-01

    Ultimate medical doctor responsibility for the care delivered to patients by all professionals is a myth. Legally Lord Denning dismissed the myth in the mid-20th century in England. The assumption that a medical doctor is responsible for the care delivered by nurses has not existed in English and Australian law since that time, and it has been actively refuted. Yet it is a myth that continues to circulate influencing health service, state and federal health policy. For some it is a myth of ignorance and for others it is a means of control. This paper outlines the relevant case law to debunk the myth of ultimate medical doctor control.

  15. Methods to Assess Geological CO2 Storage Capacity: Status and Best Practice

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2013-08-01

    To understand the emission reduction potential of carbon capture and storage (CCS), decision makers need to understand the amount of CO2 that can be safely stored in the subsurface and the geographical distribution of storage resources. Estimates of storage resources need to be made using reliable and consistent methods. Previous estimates of CO2 storage potential for a range of countries and regions have been based on a variety of methodologies resulting in a correspondingly wide range of estimates. Consequently, there has been uncertainty about which of the methodologies were most appropriate in given settings, and whether the estimates produced by these methods were useful to policy makers trying to determine the appropriate role of CCS. In 2011, the IEA convened two workshops which brought together experts for six national surveys organisations to review CO2 storage assessment methodologies and make recommendations on how to harmonise CO2 storage estimates worldwide. This report presents the findings of these workshops and an internationally shared guideline for quantifying CO2 storage resources.

  16. CO2 (dry ice) cleaning system

    Science.gov (United States)

    Barnett, Donald M.

    1995-03-01

    Tomco Equipment Company has participated in the dry ice (solid carbon dioxide, CO2) cleaning industry for over ten years as a pioneer in the manufacturer of high density, dry ice cleaning pellet production equipment. For over four years Tomco high density pelletizers have been available to the dry ice cleaning industry. Approximately one year ago Tomco introduced the DI-250, a new dry ice blast unit making Tomco a single source supplier for sublimable media, particle blast, cleaning systems. This new blast unit is an all pneumatic, single discharge hose device. It meters the insertion of 1/8 inch diameter (or smaller), high density, dry ice pellets into a high pressure, propellant gas stream. The dry ice and propellant streams are controlled and mixed from the blast cabinet. From there the mixture is transported to the nozzle where the pellets are accelerated to an appropriate blasting velocity. When directed to impact upon a target area, these dry ice pellets have sufficient energy to effectively remove most surface coatings through dry, abrasive contact. The meta-stable, dry ice pellets used for CO2 cleaning, while labeled 'high density,' are less dense than alternate, abrasive, particle blast media. In addition, after contacting the target surface, they return to their equilibrium condition: a superheated gas state. Most currently used grit blasting media are silicon dioxide based, which possess a sharp tetrahedral molecular structure. Silicon dioxide crystal structures will always produce smaller sharp-edged replicas of the original crystal upon fracture. Larger, softer dry ice pellets do not share the same sharp-edged crystalline structures as their non-sublimable counterparts when broken. In fact, upon contact with the target surface, dry ice pellets will plastically deform and break apart. As such, dry ice cleaning is less harmful to sensitive substrates, workers and the environment than chemical or abrasive cleaning systems. Dry ice cleaning system

  17. A liquid CO2-compatible hydrocarbon surfactant: experiment and modelling

    NARCIS (Netherlands)

    Banerjee, S.; Kleijn, J.M.; Cohen Stuart, M.A.; Leermakers, F.A.M.

    2013-01-01

    Surfactants soluble in liquid CO2 are rare and knowledge on interfacial and self-assembly behaviour is fragmented. We found that polyoxyethylene (5) isooctylphenyl ether is interfacially active at the water–liquid CO2 interface. Water–liquid CO2 interfacial tension was measured at various surfactant

  18. Activation of CO2 by phosphinoamide hafnium complexes.

    Science.gov (United States)

    Sgro, Michael J; Stephan, Douglas W

    2013-04-04

    Hf-phosphinoamide cation complexes behave as metal-based frustrated Lewis pairs and bind one or two equivalent of CO2 and in as well can activate CO2 in a bimetallic fashion to give a pseudo-tetrahedral P2CO2 fragment linking two Hf centres.

  19. CO2-laserchirurgie van leukoplakie van het mondslijmvlies

    NARCIS (Netherlands)

    Roodenburg, Johannes Leendert Nicolaas

    1985-01-01

    The purpose of this investigation is: 1. to gain an insight into the direct effect of CO2-laserlight on oral mucosa; 2. to study the healing of oral mucosa after being damaged by CO2-laserlight; 3. to evaluate the CO2-laserevaporataion as a treatment modality for oral leukoplakia. ... Zie: Summary

  20. Impacts: economic trade-offs for CO2 impurity specification

    NARCIS (Netherlands)

    Eickhoff, C.; Neele, F.P.; Hammer, M.; DiBiagio, M.; Hofstee, C.; Koenen, M.; Fischer, S.; Isaenko, A.; Brown, A.; Kovacs, T.

    2014-01-01

    The IMPACTS project has a stated broad objective to develop the knowledge base of CO2 quality required for establishing norms and regulations to ensure safe and reliable design, construction and operation of CO2 pipelines and injection equipment, and safe long-term geological storage of CO2. More

  1. Thermogravimetric and model-free kinetic studies on CO2 ...

    Indian Academy of Sciences (India)

    Coal gasification with CO 2 has emerged as a cleaner and more efficient way for the production of energy, and it offers the advantages of CO 2 mitigation policies through simultaneous CO 2 sequestration. In the present investigation, a feasibility study on the gasification of three low-quality, high-sulphur coals fromthe ...

  2. Ventilation in Sewers Quantified by Measurements of CO2

    DEFF Research Database (Denmark)

    Fuglsang, Emil Dietz; Vollertsen, Jes; Nielsen, Asbjørn Haaning

    2012-01-01

    H, alkalinity and sewer-air CO2 concentrations. An intercepting sewer was studied and an average sewer-air retention time of approximately 1.5-2.5 hours was found at CO2 levels around 4-6 times the natural background. Also an upstream sub-catchment was studied. In this part of the sewer system the level of CO2...

  3. Designing an oscillating CO2 concentration experiment for field chambers

    Science.gov (United States)

    Questions have arisen about photosynthetic response to fluctuating carbon dioxide (CO2), which might affect yield in free-air CO2 enrichment (FACE) systems and in open top chambers. A few studies have been conducted based on CO2 controlled to cycles of fixed time-periods and fixed, large amplitude....

  4. Designing an oscillating CO2 concentration experiment for fild chambers

    Science.gov (United States)

    Questions have arisen about photosynthetic response to fluctuating carbon dioxide (CO2), which might affect yield in free-air CO2 enrichment (FACE) systems and in open top chambers. A few studies have been conducted based on CO2 controlled to cycles of fixed time-periods and fixed, large amplitude....

  5. End tidal CO2 versus arterial CO2 monitoring in patients undergoing coronary artery bypass graft

    Directory of Open Access Journals (Sweden)

    Hassani E

    2009-12-01

    Full Text Available "n Normal 0 false false false EN-US X-NONE AR-SA MicrosoftInternetExplorer4 /* Style Definitions */ table.MsoNormalTable {mso-style-name:"Table Normal"; mso-tstyle-rowband-size:0; mso-tstyle-colband-size:0; mso-style-noshow:yes; mso-style-priority:99; mso-style-qformat:yes; mso-style-parent:""; mso-padding-alt:0in 5.4pt 0in 5.4pt; mso-para-margin:0in; mso-para-margin-bottom:.0001pt; mso-pagination:widow-orphan; font-size:11.0pt; font-family:"Calibri","sans-serif"; mso-ascii-font-family:Calibri; mso-ascii-theme-font:minor-latin; mso-fareast-font-family:"Times New Roman"; mso-fareast-theme-font:minor-fareast; mso-hansi-font-family:Calibri; mso-hansi-theme-font:minor-latin; mso-bidi-font-family:Arial; mso-bidi-theme-font:minor-bidi;} Background: Measuring end tidal carbon dioxide (ETCo2 is one of the methods used for estimating arterial carbon dioxide (PaCo2 during general anesthesia. ETCo2 measurements maybe obviate the need for repeating arterial puncture for determination of arterial PaCo2. This study performed to determine the accuracy of ETCo2 levels as a measure of PaCo2 levels in patients undergoing coronary artery bypass graft and also to evaluate variation of the gradient between PaCo2 and ETCo2, peri- cardiopulmonary bypass operation."n"nMethods: In a prospective, cross-sectional study, a total of 40 patients with age 57±11 (35-73 years old undergoing coronary artery bypass graft were enrolled. ETCo2 levels (mmHg were recorded using side stream capnography at the time of arterial blood gas sampling, before (T0 and after (T1 cardiopulmonary bypass."n"nResults: Mean P(a-ETCo2 at T0 was 4.3±4.4mmHg, with the mean PaCo2, 33±6mmHg and mean ETCo2, 29±5mmHg and these values at T1 were 4.5±4.1mmHg, 33±5mmHg and 29±2mmHg respectively. There was no variation of the mean gradient (PaCo2-PETCo2 during, before and after cardiopulmonary bypass (p>0.870. Significant correlation was found between ETCo2 and PaCo2 at T0 and T1 (r=0.754 and 0

  6. Sensory Transduction of the CO2 Response of Guard Cells

    Energy Technology Data Exchange (ETDEWEB)

    Dr. Eduardo Zeiger

    2003-06-30

    Stomata have a key role in the regulation of gas exchange and intercellular CO2 concentrations of leaves. Guard cells sense internal and external signals in the leaf environment and transduce these signals into osmoregulatory processes that control stomatal apertures. This research proposal addresses the characterization of the sensory transduction of the CO2 signal in guard cells. Recent studies have shown that in Vicia leaves kept at constant light and temperature in a growth chamber, changes in ambient CO2 concentrations cause large changes in guard cell zeaxanthin that are linear with CO2-dependent changes in stomatal apertures. Research proposed here will test the hypothesis that zeaxanthin function as a transducer of CO2 signals in guard cells. Three central aspects of this hypothesis will be investigated: CO2 sensing by the carboxylation reaction of Rubisco in the guard cell chloroplast, which would modulate zeaxanthin concentrations via changes in lumen pH; transduction of the CO2 signal by zeaxanthin via a transducing cascade that controls guard cell osmoregulation; and blue light dependence of the CO2 signal transduction by zeaxanthin, required for the formation of an isomeric form of zeaxanthin that is physiologically active as a transducer. The role of Rubisco in CO2 sensing will be investigated in experiments characterizing the stomatal response to CO2 in the Arabidopsis mutants R100 and rca-, which have reduced rates of Rubisco-dependent carboxylation. The role of zeaxanthin as a CO2 transducer will be studied in npq1, a zeaxanthin-less mutant. The blue light-dependence of CO2 sensing will be studied in experiments characterizing the stomatal response to CO2 under red light. Arabidopsis mutants will also be used in further studies of an acclimation of the stomatal response to CO2, and a possible role of the xanthophyll cycle of the guard cell chloroplast in acclimations of the stomatal response to CO2. Studies on the osmoregulatory role of sucrose in

  7. CO2 Condensation Models for Mars

    Science.gov (United States)

    Colaprete, A.; Haberle, R.

    2004-01-01

    During the polar night in both hemispheres of Mars, regions of low thermal emission, frequently referred to as "cold spots", have been observed by Mariner 9, Viking and Mars Global Surveyor (MGS) spacecraft. These cold spots vary in time and appear to be associated with topographic features suggesting that they are the result of a spectral-emission effect due to surface accumulation of fine-grained frost or snow. Presented here are simulations of the Martian polar night using the NASA Ames General Circulation Cloud Model. This cloud model incorporates all the microphysical processes of carbon dioxide cloud formation, including nucleation, condensation and sedimentation and is coupled to a surface frost scheme that includes both direct surface condensation and precipitation. Using this cloud model we simulate the Mars polar nights and compare model results to observations from the Thermal Emission Spectrometer (TES) and the Mars Orbiter Laser Altimeter (MOLA). Model predictions of "cold spots" compare well with TES observations of low emissivity regions, both spatially and as a function of season. The model predicted frequency of CO2 cloud formation also agrees well with MOLA observations of polar night cloud echoes. Together the simulations and observations in the North indicate a distinct shift in atmospheric state centered about Ls 270 which we believe may be associated with the strength of the polar vortex.

  8. Removing extra CO2 in COPD patients.

    Science.gov (United States)

    Lund, Laura W; Federspiel, William J

    2013-01-01

    For patients experiencing acute respiratory failure due to a severe exacerbation of chronic obstructive pulmonary disease (COPD), noninvasive positive pressure ventilation has been shown to significantly reduce mortality and hospital length of stay compared to respiratory support with invasive mechanical ventilation. Despite continued improvements in the administration of noninvasive ventilation (NIV), refractory hypercapnia and hypercapnic acidosis continue to prevent its successful use in many patients. Recent advances in extracorporeal gas exchange technology have led to the development of systems designed to be safer and simpler by focusing on the clinical benefits of partial extracorporeal carbon dioxide removal (ECCO2R), as opposed to full cardiopulmonary support. While the use of ECCO2R has been studied in the treatment of acute respiratory distress syndrome (ARDS), its use for acute hypercapnic respiratory during COPD exacerbations has not been evaluated until recently. This review will focus on literature published over the last year on the use of ECCO2R for removing extra CO2 in patients experiencing an acute exacerbation of COPD.

  9. Food intolerance- facts and myths

    OpenAIRE

    Ptáčková, Zuzana

    2017-01-01

    This bachelor's thesis focuses on the facts and myths about two kinds of food intolerance: celiac disease and lactose intolerance. The thesis consists of a practical and a theoretical part. The theoretical part is further divided into three sections. The first one focuses on celiac disease and describes gluten, epidemiology, etiology, pathogenesis, symptoms of the disease, diagnostics, dietary solutions, celiac disease screening, other similar diseases and also a comparison of allergy to glut...

  10. Confronting Myths about Teacher Leadership

    OpenAIRE

    Sinha, Somnath; Hanuscin, Deborah; Rebello, Carina; Muslu, Nilay; Cheng, Ya-Wen

    2012-01-01

      Leadership in Freshman Physics is an NSF-funded professional development program designed to support 9th grade teacher leaders in the successful implementation of a ‘Physics First’ or curriculum sequence that places physics prior to biology and chemistry. Leadership is viewed as an essential component in the initial success and long-term sustainability of such reforms. This article is an account of myths about teacher leadership held by participants and the ways...

  11. Faith healers, myths and deaths.

    Science.gov (United States)

    Wasti, Harihar; Kanchan, Tanuj; Acharya, Jenash

    2015-09-01

    Science and myth have been closely linked and argued upon by philosophers, educationalists, scientists, enthusiasts and the general public. Faith healing, when added as an adjuvant or alternative aid to medical science, will not necessarily be confined to mere arguments and debates but may also give rise to series of complications, medical emergencies and even result in death. We present an unusual case where reliance on faith healing led to the death of a young man. © The Author(s) 2015.

  12. Determining CO2 storage potential during miscible CO2 enhanced oil recovery: Noble gas and stable isotope tracers

    Science.gov (United States)

    Shelton, Jenna L.; McIntosh, Jennifer C.; Hunt, Andrew; Beebe, Thomas L; Parker, Andrew D; Warwick, Peter D.; Drake, Ronald; McCray, John E.

    2016-01-01

    Rising atmospheric carbon dioxide (CO2) concentrations are fueling anthropogenic climate change. Geologic sequestration of anthropogenic CO2 in depleted oil reservoirs is one option for reducing CO2 emissions to the atmosphere while enhancing oil recovery. In order to evaluate the feasibility of using enhanced oil recovery (EOR) sites in the United States for permanent CO2 storage, an active multi-stage miscible CO2flooding project in the Permian Basin (North Ward Estes Field, near Wickett, Texas) was investigated. In addition, two major natural CO2 reservoirs in the southeastern Paradox Basin (McElmo Dome and Doe Canyon) were also investigated as they provide CO2 for EOR operations in the Permian Basin. Produced gas and water were collected from three different CO2 flooding phases (with different start dates) within the North Ward Estes Field to evaluate possible CO2 storage mechanisms and amounts of total CO2retention. McElmo Dome and Doe Canyon were sampled for produced gas to determine the noble gas and stable isotope signature of the original injected EOR gas and to confirm the source of this naturally-occurring CO2. As expected, the natural CO2produced from McElmo Dome and Doe Canyon is a mix of mantle and crustal sources. When comparing CO2 injection and production rates for the CO2 floods in the North Ward Estes Field, it appears that CO2 retention in the reservoir decreased over the course of the three injections, retaining 39%, 49% and 61% of the injected CO2 for the 2008, 2010, and 2013 projects, respectively, characteristic of maturing CO2 miscible flood projects. Noble gas isotopic composition of the injected and produced gas for the flood projects suggest no active fractionation, while δ13CCO2 values suggest no active CO2dissolution into formation water, or mineralization. CO2 volumes capable of dissolving in residual formation fluids were also estimated along with the potential to store pure-phase supercritical CO2. Using a combination

  13. Leaching of organic acids from macromolecular organic matter by non-supercritical CO2

    Science.gov (United States)

    Sauer, P.; Glombitza, C.; Kallmeyer, J.

    2012-04-01

    The storage of CO2 in underground reservoirs is discussed controversly in the scientific literature. The worldwide search for suitable storage formations also considers coal-bearing strata. CO2 is already injected into seams for enhanced recovery of coal bed methane. However, the effects of increased CO2 concentration, especially on organic matter rich formations, are rarely investigated. The injected CO2 will dissolve in the pore water, causing a decrease in pH and resulting in acidic formation waters. Huge amounts of low molecular weight organic acids (LMWOAs) are chemically bound to the macromolecular matrix of sedimentary organic matter and may be liberated by hydrolysis, which is enhanced by the acidic porewater. Recent investigations outlined the importance of LMWOAs as a feedstock for microbial life in the subsurface [1]. Therefore, injection of CO2 into coal formations may result in enhanced nutrient supply for subsurface microbes. To investigate the effect of high concentrations of dissolved CO2 on the release of LMWOAs from coal we developed an inexpensive high-pressure high temperature system that allows manipulating the partial pressure of dissolved gases at pressures and temperatures up to 60 MPa and 120° C, respectively. In a reservoir vessel, gases are added to saturate the extraction medium to the desired level. Inside the extraction vessel hangs a flexible and inert PVDF sleeve (polyvinylidene fluoride, almost impermeable for gases), holding the sample and separating it from the pressure fluid. The flexibility of the sleeve allows for subsampling without loss of pressure. Coal samples from the DEBITS-1 well, Waikato Basin, NZ (R0 = 0.29, TOC = 30%). were extracted at 90° C and 5 MPa, either with pure or CO2-saturated water. Subsamples were taken at different time points during the extraction. The extracted LMWOAs such as formate, acetate and oxalate were analysed by ion chromatography. Yields of LMWOAs were higher with pure water than with CO2

  14. Worldwide prevalence of hypospadias.

    Science.gov (United States)

    Springer, A; van den Heijkant, M; Baumann, S

    2016-06-01

    Hypospadias is a common congenital malformation. Surgical repair and management of the long-term consequences require a substantial amount of socioeconomic resources. It is generally accepted that genetic and environmental factors play a major role in the etiology of hypospadias. There have been contradictory reports on rising hypospadias rates, and regional and ethnical differences. The exact prevalence of hypospadias is of major interest for healthcare providers, clinical medicine, and research. To review the literature regarding the worldwide prevalence of hypospadias. Pubmed, EMBASE and Google were systematically screened for: hypospadias, congenital malformation, anomaly, incidence, prevalence, and epidemiology. Exclusion criteria were surgical and risk-factor studies. To give an additional comprehensive overview, prevalence data were harvested from the Annual Report of the International Clearinghouse Centre for Birth Defects Surveillance and Research. Prevalence was reported as per 10,000 live births. Data were available from 1910 to 2013. The median study period was 9 years (range: 1-36 years). Approximately 90,255,200 births have been screened in all studies. The mean prevalence were: Europe 19.9 (range: 1-464), North America 34.2 (6-129.8), South America 5.2 (2.8-110), Asia 0.6-69, Africa 5.9 (1.9-110), and Australia 17.1-34.8. There were major geographical, regional, and ethnical differences, with an extreme heterogeneity of published studies. Numerous studies showed an increasing prevalence; on the other hand, there were a lot of contradictory data on the prevalence of hypospadias. The summary table shows contradictory data from the five largest international studies available. There was huge literature available on the prevalence of hypospadias. Most data derived from Europe and North America. Many methodological factors influenced the calculation of an accurate prevalence, and even more of the true changes in prevalence over time (no generally accepted

  15. Thermodynamic Properties of CO2 Mixtures and Their Applications in Advanced Power Cycles with CO2 Capture Processes

    OpenAIRE

    Li, Hailong

    2008-01-01

    The thermodynamic properties of CO2-mixtures are essential for the design and operation of CO2 Capture and Storage (CCS) systems. A better understanding of the thermodynamic properties of CO2 mixtures could provide a scientific basis to define a proper guideline of CO2 purity and impure components for the CCS processes according to technical, safety and environmental requirements. However the available accurate experimental data cannot cover the whole operation conditions of CCS processes. In...

  16. Greenhouse gas capture. Norwegian test facility for CO2-technology; Broeikasgasvangers. Noors testcentrum voor CO2-technologie

    Energy Technology Data Exchange (ETDEWEB)

    Van Velzen, T.

    2012-02-03

    In Norway a large research center on the capture of CO2 will be opened in the spring of 2012: the CO2 Technology Centre Mongstad. It allows companies to test concepts for CCS (carbon dioxide capture and storage) [Dutch] In Noorwegen wordt in de lente van 2012 een groot centrum voor onderzoek naar het afvangen van CO2 geopend: het CO2 Technology Centre Mongstad. Daar kunnen bedrijven hun concepten voor CCS beproeven.

  17. CO2 niet meer dan genoeg: Teelt van Tomaat in 2012 bij Improvement Centre met lichtafhankelijk doseren van CO2

    NARCIS (Netherlands)

    Gelder, de A.; Warmenhoven, M.G.; Dieleman, J.A.; Klapwijk, P.; Baar, van P.H.

    2014-01-01

    Wageningen UR Glastuinbouw heeft met financiering van Kas als Energiebron en Samenwerken aan Vaardigheden onderzoek gedaan naar efficienter gebruik van CO2. In een kasproef bij GreenQ/Improvement Centre is een CO2 doseerstrategie getest, waarbij iets meer CO2 wordt gegeven dan er op basis van de

  18. Detection of CO2 leaks from carbon capture and storage sites with combined atmospheric CO2 and O-2 measurements

    NARCIS (Netherlands)

    van Leeuwen, Charlotte; Meijer, Harro A. J.

    2015-01-01

    This paper presents a transportable instrument that simultaneously measures the CO2 and (relative) O-2 concentration of the atmosphere with the purpose to aid in the detection of CO2 leaks from CCS sites. CO2 and O-2 are coupled in most processes on earth (e.g., photosynthesis, respiration and

  19. The effects of CO2-differentiated vehicle tax systems on car choice, CO2 emissions and tax revenues

    NARCIS (Netherlands)

    Kok, R.

    2011-01-01

    This paper assesses the impacts of a CO2-differentiated tax policy designed to influence car purchasing trends towards lower CO2 emitting vehicles in the Netherlands. Since 2009, gasoline and diesel cars up to 110 and 95 gram CO2 per km are exempted from the vehicle registration tax (VRT). In

  20. Application of ammonia and CO2 in supermarkets; Toepassing van ammoniak en CO2 in supermarkten

    Energy Technology Data Exchange (ETDEWEB)

    Stoecker, W.F.; Hrnjak, P.J. [University of Illinois, Urbana-Champaign, IL (United States); Infante Ferreiria, C.A. [Technische Universiteit Delft, Delft (Netherlands)

    2001-08-01

    The application of microchannel condensers in ammonia installations makes it possible to go down as far as 18 g NH3 per kW refrigeration. The use of ammonia in combination with CO2 contributes to economic effective and energy efficient solutions for supermarket applications. In this article also the experiences in Sweden, Denmark and Italy with indirect, cascade and transcritical supermarket refrigeration systems with carbon dioxide are described. 8 refs.

  1. Recent global CO2 flux inferred from atmospheric CO2 observations and its regional analyses

    Directory of Open Access Journals (Sweden)

    J. M. Chen

    2011-11-01

    Full Text Available The net surface exchange of CO2 for the years 2002–2007 is inferred from 12 181 atmospheric CO2 concentration data with a time-dependent Bayesian synthesis inversion scheme. Monthly CO2 fluxes are optimized for 30 regions of the North America and 20 regions for the rest of the globe. Although there have been many previous multiyear inversion studies, the reliability of atmospheric inversion techniques has not yet been systematically evaluated for quantifying regional interannual variability in the carbon cycle. In this study, the global interannual variability of the CO2 flux is found to be dominated by terrestrial ecosystems, particularly by tropical land, and the variations of regional terrestrial carbon fluxes are closely related to climate variations. These interannual variations are mostly caused by abnormal meteorological conditions in a few months in the year or part of a growing season and cannot be well represented using annual means, suggesting that we should pay attention to finer temporal climate variations in ecosystem modeling. We find that, excluding fossil fuel and biomass burning emissions, terrestrial ecosystems and oceans absorb an average of 3.63 ± 0.49 and 1.94 ± 0.41 Pg C yr−1, respectively. The terrestrial uptake is mainly in northern land while the tropical and southern lands contribute 0.62 ± 0.47, and 0.67 ± 0.34 Pg C yr−1 to the sink, respectively. In North America, terrestrial ecosystems absorb 0.89 ± 0.18 Pg C yr−1 on average with a strong flux density found in the south-east of the continent.

  2. Improved Efficiency of Miscible CO2 Floods and Enhanced Prospects for CO2 Flooding Heterogeneous Reservoirs

    Energy Technology Data Exchange (ETDEWEB)

    Grigg, Reid B.; Schechter, David S.

    1999-10-15

    The goal of this project is to improve the efficiency of miscible CO2 floods and enhance the prospects for flooding heterogeneous reservoirs. This report provides results of the second year of the three-year project that will be exploring three principles: (1) Fluid and matrix interactions (understanding the problems). (2) Conformance control/sweep efficiency (solving the problems. 3) Reservoir simulation for improved oil recovery (predicting results).

  3. The Influence of CO2 Solubility in Brine on Simulation of CO2 Injection into Water Flooded Reservoir and CO2 WAG

    DEFF Research Database (Denmark)

    Yan, Wei; Stenby, Erling Halfdan

    2010-01-01

    simulations. In our previous study, a 1-D slimtube simulator, which rigorously accounts for both CO2 solubility in brine and water content in hydrocarbon phases using the Peng-Robinson EoS modified by Soreide and Whitson, has been used to investigate the influence of CO2 solubility on the simulation...

  4. The Creation of Inequality: Myths of Potential and Ability

    Science.gov (United States)

    Dorling, Danny; Tomlinson, Sally

    2016-01-01

    The old myth about the ability and variability of potential in children is a comforting myth, for those who are uneasy with the degree of inequality they see and would rather seek to justify it than confront it. The myth of inherent potential helps some explain to themselves why they are privileged. Extend the myth to believe in inherited ability…

  5. Sequestering CO2 in the Built Environment

    Science.gov (United States)

    Constantz, B. R.

    2009-12-01

    Calera’s Carbonate Mineralization by Aqueous Precipitation (CMAP) technology with beneficial reuse has been called, “game-changing” by Carl Pope, Director of the Sierra Club. Calera offers a solution to the scale of the carbon problem. By capturing carbon into the built environment through carbonate mineralization, Calera provides a sound and cost-effective alternative to Geologic Sequestration and Terrestrial Sequestration. The CMAP technology permanently converts carbon dioxide into a mineral form that can be stored above ground, or used as a building material. The process produces a suite of carbonate-containing minerals of various polymorphic forms. Calera product can be substituted into blends with ordinary Portland cements and used as aggregate to produce concrete with reduced carbon, carbon neutral, or carbon negative footprints. For each ton of product produced, approximately half a ton of carbon dioxide can be sequestered using the Calera process. Coal and natural gas are composed of predominately istopically light carbon, as the carbon in the fuel is plant-derived. Thus, power plant CO2 emissions have relatively low δ13C values.The carbon species throughout the CMAP process are identified through measuring the inorganic carbon content, δ13C values of the dissolved carbonate species, and the product carbonate minerals. Measuring δ13C allows for tracking the flue gas CO2 throughout the capture process. Initial analysis of the capture of propane flue gas (δ13C ˜ -25 ‰) with seawater (δ13C ˜ -10 ‰) and industrial brucite tailings from a retired magnesium oxide plant in Moss Landing, CA (δ13C ˜ -7 ‰ from residual calcite) produced carbonate mineral products with a δ13C value of ˜ -20 ‰. This isotopically light carbon, transformed from flue gas to stable carbonate minerals, can be transferred and tracked through the capture process, and finally to the built environment. CMAP provides an economical solution to global warming by producing

  6. Monitoring and Modeling CO2 Dynamics in the Vadose Zone near an Abandoned Historic Oil Well: Implications for Detecting CO2 Leakage at Geological CO2 Sequestration Sites

    Science.gov (United States)

    Yang, C.; Romanak, K.; Hovorka, S.; Reedy, R. C.; Trevino, R.; Scanlon, B. R.

    2010-12-01

    Soil-gas monitoring is proposed for detecting CO2 leakage at geological CO2 sequestration sites. At the Cranfield oil field, about 25 km east of Natchez, Mississippi, an integrated near-surface monitoring program is being implemented where supercritical CO2 is being injected for enhanced oil recovery (EOR). The purpose of the study is to understand how natural factors may affect soil CO2 monitoring at geologic carbon storage sites. A near-surface observatory, constructed on an engineered well pad near a 1950’s era open pit and plugged and abandoned well, was used to monitor atmospheric parameters such as air temperature, relative humility, barometric pressure, wind speed and direction, solar radiation, and precipitation. Soil temperature, soil CO2 concentrations, water content, and matric potential were also monitored at various depths to a maximum of 5 m in the vadose zone. The integrated monitoring system was installed in September 2009 and continued collecting data each half hour for about 240 days. CO2 concentrations measured at 1.5 m depth are about two times that of atmospheric CO2 concentrations and show daily fluctuations. However, CO2 concentrations measured at 3 m depth decreased from 11% in November 2009 to 9% in January 2010, then gradually increased to 10.5% in June 2010. There should be no CO2 contribution from root respiration because the engineered pad is bare of vegetation. Monitored CO2 in the vadose zone at this site most likely is derived from oxidation of methane with a suspected source related to the 1950’s era plugged and abandoned well. A 1-D numerical model was also used to simulate variably saturated water flow, CO2 transport, CH4 oxidation for understanding mechanisms that dominate CO2 transport at this site. Results of this study suggest that CO2 transport in the vadose zone is very complicated and can be affected by many factors including precipitation, barometric pressure, soil temperature, oxidation of methane, and therefore may

  7. Revisiting the Common Myths about Homeschooling

    Science.gov (United States)

    Romanowski, Michael H.

    2006-01-01

    The author examines four common myths that still influence individuals regarding their perspective and understanding of the role homeschooling plays in the education of American children. Myth 1 is that homeschooling produces social misfits, stemming from the belief that homeschooled students lack the socialization skills necessary for normal…

  8. Myth and Other Norms in World Society

    DEFF Research Database (Denmark)

    Petersen, Hanne

    2017-01-01

    This article uses the Thule Case at the Danish Supreme Court as an example of normativity in world society. Here norms, which may turn out to be important in world society could be myths of several kinds such as 'narrative normativity'. One myth may be that of (exclusive) sovereignty...

  9. MYTHS--LITERATURE CURRICULUM I, STUDENT VERSION.

    Science.gov (United States)

    KITZHABER, ALBERT

    PRESENTED HERE WAS A STUDY GUIDE FOR STUDENT USE IN A SEVENTH-GRADE LITERATURE CURRICULUM. INTRODUCTORY MATERIAL WAS PRESENTED ON GREEK MYTHS, NORSE MYTHOLOGY, AND AMERICAN INDIAN MYTHOLOGY. STUDY QUESTIONS, SUGGESTED ACTIVITIES, AND A REFERENCE BOOK OF MYTHS WERE PRESENTED. AN ACCOMPANYING GUIDE WAS PREPARED FOR TEACHERS (ED 010 140). (WN)

  10. Dangerous Myths about "Gifted" Mathematics Students

    Science.gov (United States)

    Sheffield, Linda Jensen

    2017-01-01

    A number of myths about mathematically gifted students, mathematics itself, and programs designed to serve these students tend to inhibit educators, parents and students themselves from developing students' mathematical creativity, expertise and enjoyment. This paper discusses some of the myths that can discourage students' mathematical…

  11. The Meaning Behind Popular Myths About Suicide.

    Science.gov (United States)

    Neuringer, Charles

    1988-01-01

    Examines several common human-serving fallacies about suicide as to their validity and discusses these myths in terms of how they operate to reduce anxiety about quality of life and death. Asserts need to dispel myths and seek truths in order to understand and prevent suicide. (Author/NB)

  12. Fifteen Prevalent Myths Concerning Adolescent Suicide.

    Science.gov (United States)

    King, Keith A.

    1999-01-01

    Examines 15 common myths about adolescent suicide, presenting the actual facts corresponding to each. The myths relate to such issues as prevalence, warning signs, education about suicide, differences between males and females, common methods of adolescent suicide, mental illness and suicide, suicide prevention, genetic factors, poverty and…

  13. Pre-Columbian Mayan Myths. Project Mexico.

    Science.gov (United States)

    Callanan, Margaret

    This document outlines a course unit on Pre-Columbian Mayan Myths intended to be part of a semester-long survey course on world mythology. The intended unit length of three weeks for three hours per week allows time for consideration of a brief geographical, historical, and cosmological background against which to place Mayan myths, study of the…

  14. Five feminist myths about women's employment.

    Science.gov (United States)

    Hakim, C

    1995-09-01

    Feminist sociology has contributed substantial revisions to theory, especially in the sociology of work and employment. But it is also creating new feminist myths to replace the old patriarchal myths about women's attitudes and behaviour. Five feminist myths about women's employment are discussed whose acceptance as fact is not damaged by being demonstrably untrue. Arguably the most pervasive is the myth of rising female employment. The myth that women's work commitment is the same as that of men is often adduced to resist labour market discrimination. The myth of childcare problems as the main barrier to women's employment is commonplace in advocacy research reports. The myth of poor quality part-time jobs is used to blame employers for the characteristic behaviour of part-time workers, including high labour turnover. The issue of the sex differential in labour turnover and employment stability illustrates clearly how feminist orthodoxy has replaced dispassionate sociological research in certain topics. The concluding section considers the implications of such feminist myths for an academic community that claims to be in the truth business and for theories on the sexual division of labour.

  15. Atmospheric measurement of point source fossil CO2 emissions

    Science.gov (United States)

    Turnbull, J. C.; Keller, E. D.; Baisden, T.; Brailsford, G.; Bromley, T.; Norris, M.; Zondervan, A.

    2014-05-01

    We use the Kapuni Gas Treatment Plant to examine methodologies for atmospheric monitoring of point source fossil fuel CO2 (CO2ff) emissions. The Kapuni plant, located in rural New Zealand, removes CO2 from locally extracted natural gas and vents that CO2 to the atmosphere, at a rate of ~0.1 Tg carbon per year. The plant is located in a rural dairy farming area, with no other significant CO2ff sources nearby, but large, diurnally varying, biospheric CO2 fluxes from the surrounding highly productive agricultural grassland. We made flask measurements of CO2 and 14CO2 (from which we derive the CO2ff component) and in situ measurements of CO2 downwind of the Kapuni plant, using a Helikite to sample transects across the emission plume from the surface up to 100 m above ground level. We also determined the surface CO2ff content averaged over several weeks from the 14C content of grass samples collected from the surrounding area. We use the WindTrax plume dispersion model to compare the atmospheric observations with the emissions reported by the Kapuni plant, and to determine how well atmospheric measurements can constrain the emissions. The model has difficulty accurately capturing the fluctuations and short-term variability in the Helikite samples, but does quite well in representing the observed CO2ff in 15 min averaged surface flask samples and in ~ one week integrated CO2ff averages from grass samples. In this pilot study, we found that using grass samples, the modeled and observed CO2ff emissions averaged over one week agreed to within 30%. The results imply that greater verification accuracy may be achieved by including more detailed meteorological observations and refining 14C sampling strategies.

  16. Use of sediment CO2 by submersed rooted plants.

    Science.gov (United States)

    Winkel, Anders; Borum, Jens

    2009-05-01

    Submersed plants have different strategies to overcome inorganic carbon limitation. It is generally assumed that only small rosette species (isoetids) are able to utilize the high sediment CO(2) availability. The present study examined to what extent five species of submersed freshwater plants with different morphology and growth characteristics (Lobelia dortmanna, Lilaeopsis macloviana, Ludwigia repens, Vallisneria americana and Hydrocotyle verticillata) are able to support photosynthesis supplied by uptake of CO(2) from the sediment. Gross photosynthesis was measured in two-compartment split chambers with low inorganic carbon availability in leaf compartments and variable CO(2) availability (0 to >8 mmol L(-1)) in root compartments. Photosynthetic rates based on root-supplied CO(2) were compared with maximum rates obtained at saturating leaf CO(2) availability, and (14)C experiments were conducted for two species to localize bottlenecks for utilization of sediment CO(2). All species except Hydrocotyle were able to use sediment CO(2), however, with variable efficiency, and with the isoetid, Lobelia, as clearly the most effective and the elodeid, Ludwigia, as the least efficient. At a water column CO(2) concentration in equilibrium with air, Lobelia, Lilaeopsis and Vallisneria covered >75% of their CO(2) requirements by sediment uptake, and sediment CO(2) contributed substantially to photosynthesis at water CO(2) concentrations up to 1000 micromol L(-1). For all species except Ludwigia, the shoot to root ratio on an areal basis was the single factor best explaining variability in the importance of sediment CO(2). For Ludwigia, diffusion barriers limited uptake or transport from roots to stems and transport from stems to leaves. Submersed plants other than isoetids can utilize sediment CO(2), and small and medium sized elodeids with high root to shoot area in particular may benefit substantially from uptake of sediment CO(2) in low alkaline lakes.

  17. Subsurface oxide plays a critical role in CO2activation by Cu(111) surfaces to form chemisorbed CO2, the first step in reduction of CO2.

    Science.gov (United States)

    Favaro, Marco; Xiao, Hai; Cheng, Tao; Goddard, William A; Yano, Junko; Crumlin, Ethan J

    2017-06-27

    A national priority is to convert CO 2 into high-value chemical products such as liquid fuels. Because current electrocatalysts are not adequate, we aim to discover new catalysts by obtaining a detailed understanding of the initial steps of CO 2 electroreduction on copper surfaces, the best current catalysts. Using ambient pressure X-ray photoelectron spectroscopy interpreted with quantum mechanical prediction of the structures and free energies, we show that the presence of a thin suboxide structure below the copper surface is essential to bind the CO 2 in the physisorbed configuration at 298 K, and we show that this suboxide is essential for converting to the chemisorbed CO 2 in the presence of water as the first step toward CO 2 reduction products such as formate and CO. This optimum suboxide leads to both neutral and charged Cu surface sites, providing fresh insights into how to design improved carbon dioxide reduction catalysts.

  18. At the foot of Mount Olympus: A theory on myth

    Directory of Open Access Journals (Sweden)

    Flip Schutte

    2006-09-01

    Full Text Available A cult normally develops around myths and rituals. In this article myth as phenomenon will be investigated. Different types and categories of myths will be listed, while research done in the past on myths will also be dealt with. Furthermore, the issue of ritual accompanying the myth will be briefly discussed. This article wants to promote the notion that one does not need any particular worldview, be it mythological, orthodox, fundamentalistic, or biblisistic, to use, understand, and appreciate myths. Even in a postmodern world the value of myths can be appreciated.

  19. Dynamics of soil CO 2 efflux under varying atmospheric CO 2 concentrations reveal dominance of slow processes

    Science.gov (United States)

    Dohyoung Kim; Ram Oren; James S. Clark; Sari Palmroth; A. Christopher Oishi; Heather R. McCarthy; Chris A. Maier; Kurt Johnsen

    2017-01-01

    We evaluated the effect on soil CO2 efflux (FCO2) of sudden changes in photosynthetic rates by altering CO2 concentration in plots subjected to +200 ppmv for 15 years. Five-day intervals of exposure to elevated CO2 (eCO2) ranging 1.0–1.8 times ambient did not affect FCO2. FCO2 did not decrease until 4 months after termination of the long-term eCO2 treatment, longer...

  20. The personal myth: a re-evaluation.

    Science.gov (United States)

    Sirois, François

    2014-04-01

    This paper presents a re-evaluation of Kris's personal myth. The notion has been used rather sparingly despite the Delphi Symposium in 1984 on the question of its clinical usefulness. After framing the notion of myth, some difficulties related to the question are identified. A clinical vignette exemplifies some of the ambiguities in its definition but stresses its clinical relevance. A discussion expands on these situations so as to propose three various aspects of personal myths to account for the two variants identified by Kris. The actualization of the underlying fantasy in the character organization is a third form and the technical aspect associated with it is reviewed from a new perspective. The family romance is revisited to reassess its role as the basis of the personal myth in the face of studies favouring an earlier development of the myth. Copyright © 2014 Institute of Psychoanalysis.

  1. Tityus: a forgotten myth of liver regeneration.

    Science.gov (United States)

    Tiniakos, Dina G; Kandilis, Apostolos; Geller, Stephen A

    2010-08-01

    The ancient Greek myth of Tityus is related to liver regeneration in the same way as the well known myth of Prometheus is. Depictions of the punishment of Prometheus are frequently used by lecturers on liver regeneration; however, Tityus remains unknown despite the fact that he received the same punishment and his myth could also be used as a paradigm for the organ's extraordinary ability to regenerate. Nevertheless, there is no convincing evidence that ancient Greeks had any specific knowledge about liver regeneration, a concept introduced in the early 19th century. We describe and analyze the myth of Tityus and compare it to the myth of Prometheus. We also explore artistic and literary links and summarize recent scientific data on the mechanisms of liver regeneration. Finally, we highlight links of the legend of Tityus with other sciences. Copyright 2010 European Association for the Study of the Liver. Published by Elsevier B.V. All rights reserved.

  2. Development of a stable MnCo2O4 cocatalyst for photocatalytic CO2 reduction with visible light.

    Science.gov (United States)

    Wang, Sibo; Hou, Yidong; Wang, Xinchen

    2015-02-25

    The synthesis of uniform MnCo2O4 microspheres and their cooperation with a visible light harvester to achieve efficient photocatalytic CO2 reduction under ambient conditions are reported here. The MnCo2O4 materials were prepared by a facile two-step solvothermal-calcination method and were characterized by XRD, SEM, TEM, EDX, XPS, elemental mapping, and N2 adsorption measurements. By using the MnCo2O4 microspheres as a heterogeneous cocatalyst, the photocatalytic performance of the CO2-to-CO conversion catalysis was remarkably enhanced, and no decrease in the promotional effect of the cocatalyst was observed after repeatedly operating the reaction for six cycles. (13)CO2 isotope tracer experiments verified that the CO product originated from the CO2 reactant. The effect of synthetic conditions and various reaction parameters on the photocatalytic activity of the system were investigated and optimized. The stability of the MnCo2O4 cocatalyst in the CO2 reduction system was confirmed by several techniques. Moreover, a possible mechanism for MnCo2O4-cocatalyzed CO2 photoreduction catalysis is proposed.

  3. Research on the physical properties of supercritical CO2 and the log evaluation of CO2-bearing volcanic reservoirs

    Science.gov (United States)

    Pan, Baozhi; Lei, Jian; Zhang, Lihua; Guo, Yuhang

    2017-10-01

    CO2-bearing reservoirs are difficult to distinguish from other natural gas reservoirs during gas explorations. Due to the lack of physical parameters for supercritical CO2, particularly neutron porosity, at present a hydrocarbon gas log evaluation method is used to evaluate CO2-bearing reservoirs. The differences in the physical properties of hydrocarbon and CO2 gases have led to serious errors. In this study, the deep volcanic rock of the Songliao Basin was the research area. In accordance with the relationship between the density and acoustic velocity of supercritical CO2 and temperature and pressure, the regularity between the CO2 density and acoustic velocity, and the depth of the area was established. A neutron logging simulation was completed based on a Monte Carlo method. Through the simulation of the wet limestone neutron logging, the relationship between the count rate ratio of short and long space detectors and the neutron porosity was acquired. Then, the nature of the supercritical CO2 neutron moderation was obtained. With consideration given to the complexity of the volcanic rock mineral composition, a volcanic rock volume model was established, and the matrix neutron and density parameters were acquired using the ECS log. The properties of CO2 were applied in the log evaluation of the CO2-bearing volcanic reservoirs in the southern Songliao Basin. The porosity and saturation of CO2 were obtained, and a reasonable application was achieved in the CO2-bearing reservoir.

  4. Canopy CO2 exchange of sugar beet under different CO2 concentrations and nitrogen supply: results from a free-air CO2 enrichment study.

    Science.gov (United States)

    Burkart, S; Manderscheid, R; Weigel, H-J

    2009-11-01

    Sugar beet (Beta vulgaris ssp. altissima Döll) was grown in the field under free-air CO(2) enrichment (FACE, 550 ppm) and different nitrogen (N) supply (2001: 126 (N100) and 63 kg.ha(-1) (N50); 2004: 156 (N100) and 75 kg.ha(-1)) during two crop rotations. Canopy CO(2) exchange rates (CCER) were measured during the main growth phase (leaf area index > or =2) using a dynamic chamber system. Canopy CO(2) exchange data were analysed with respect to treatment effects on seasonal means and light use efficiency and light response characteristics. CO(2) enrichment enhanced CCER throughout the season. However, in both years, CCER declined after the second half of August independent of radiation and [CO(2)]. Elevated [CO(2)] strongly stimulated CCER on a seasonal basis, whereas the reduction of CCER caused by low N was below 10% and not significant. There were no effects of N on daily radiation use efficiency of carbon gain calculated from CCER data, but a strong enhancement by CO(2) enrichment. CCER closely tracked diurnal variations in incident photosynthetic photon flux density (PPFD, mumol.m(-2).s(-1)). The relationship between CCER and incident PPFD was curvilinear. In both seasons, initial slopes and maximum rates (CCER(max)) were determined from two 6-day periods using these relationships. The first period was measured after canopy closure (first half of July) and the second in the second half of August. In the first period, elevated [CO(2)] increased the initial slopes. Low N supply affected neither the initial slopes nor their response to elevated [CO(2)] in either period. In contrast to initial slopes, N stress limited the [CO(2)] response of CCER(max) in the first period. In the second period, however, this interaction of [CO(2)] and N on CCER(max) was completely dominated by a general decline of CCER(max) whereas no general decline of the initial slopes occurred in the second period. This response of light response parameters to [CO(2)] and N suggests that, in

  5. Microbial growth under a high-pressure CO2 environment

    Science.gov (United States)

    Thompson, J. R.; Hernandez, H. H.

    2009-12-01

    Carbon capture and storage (CCS) of CO2 has the potential to significantly reduce the emission of greenhouse gasses associated with fossil fuel combustion. The largest potential for storing captured CO2 in the United Sates is in deep geologic saline formations. Currently, little is known about the effects of CO2 storage on biologically active microbial communities found in the deep earth biosphere. Therefore, to investigate how deep earth microbial communities will be affected by the storage of CO2, we have built a high-pressure microbial growth system in which microbial samples are subjected to a supercritical CO2 (scCO2) environment. Recently we have isolated a microbial consortium that is capable of growth and extracellular matrix production in nutrient media under a supercritical CO2 headspace. This consortium was cultivated from hydrocarbon residues associated with saline formation waters and includes members of the gram-positive Bacillus genus. The cultivation of actively growing cells in an environment containing scCO2 is unexpected based on previous experimental evidence of microbial sterilization attributed to the acidic, desiccating, and solvent-like properties of scCO2. Such microbial consortia have potential for development as (i) biofilm barriers for geological carbon-dioxide sequestration, and as (ii) agents of biocatalysis in environmentally-friendly supercritical (sc) CO2 solvent systems. The discovery that microbes can remain biologically active, and grow, in these environments opens new frontiers for the use of self-regenerating biological systems in engineering applications.

  6. Metal-Free Carbon Materials for CO2 Electrochemical Reduction.

    Science.gov (United States)

    Duan, Xiaochuan; Xu, Jiantie; Wei, Zengxi; Ma, Jianmin; Guo, Shaojun; Wang, Shuangyin; Liu, Huakun; Dou, Shixue

    2017-11-01

    The rapid increase of the CO2 concentration in the Earth's atmosphere has resulted in numerous environmental issues, such as global warming, ocean acidification, melting of the polar ice, rising sea level, and extinction of species. To search for suitable and capable catalytic systems for CO2 conversion, electrochemical reduction of CO2 (CO2 RR) holds great promise. Emerging heterogeneous carbon materials have been considered as promising metal-free electrocatalysts for the CO2 RR, owing to their abundant natural resources, tailorable porous structures, resistance to acids and bases, high-temperature stability, and environmental friendliness. They exhibit remarkable CO2 RR properties, including catalytic activity, long durability, and high selectivity. Here, various carbon materials (e.g., carbon fibers, carbon nanotubes, graphene, diamond, nanoporous carbon, and graphene dots) with heteroatom doping (e.g., N, S, and B) that can be used as metal-free catalysts for the CO2 RR are highlighted. Recent advances regarding the identification of active sites for the CO2 RR and the pathway of reduction of CO2 to the final product are comprehensively reviewed. Additionally, the emerging challenges and some perspectives on the development of heteroatom-doped carbon materials as metal-free electrocatalysts for the CO2 RR are included. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  7. Waste benefits of CO2 policies in Japan.

    Science.gov (United States)

    Gielen, D J; Moriguchi, Y

    2002-02-01

    A linear programming model REAP (Regional Environmental strategy Analysis Program) has been developed for the analysis of the consequences of a CO2 tax for petrochemical products such as plastics (CO2, carbon dioxide, is the most important greenhouse gas). Special attention has been paid to the impacts on waste management. The results suggest that a 10,000 Y t(-1) CO2 tax would result in a significant reduction of CO2 emissions in the petrochemical life cycle, ranging from 40 Mt in 2015 to 70 Mt CO2 in later decades (more than 50% emission reduction). Waste quantities will be reduced simultaneously. The CO2 tax results in an 18% reduction of plastic waste weight in 2015 (3 Mt waste). Lower tax levels that may be politically more acceptable would result in proportionally lower environmental benefits. CO2 benefits and waste benefits of a CO2 tax are of equal importance in policy terms. Apart from changes in waste volume, CO2 taxes would affect the cost-effectiveness of waste handling technologies. Energy recovery in industrial kilns may replace conventional waste incineration. Recycling constitutes half of the total waste treatment. Given these results, current investments in new incineration capacity may suffer from insufficient waste availability during the next two decades in case CO2 taxes are introduced. A third effect of a CO2 tax is a significant increase of waste transportation. The results show that this increase is concentrated in the central part of Honshu (Kinki, Chubu & Kanto). Such transportation can result in new local environmental impacts that should be analysed in more detail. Given the strong impact of CO2 taxes on waste quantities and waste treatment it is recommended to co-ordinate CO2 policies and solid waste policies.

  8. Forecasting CO2 emissions in the Persian Gulf States

    Directory of Open Access Journals (Sweden)

    F.A. Olabemiwo

    2017-12-01

    Full Text Available The Persian Gulf States (Bahrain. Iran, Iraq, Qatar, Saudi Arabia, Kuwait and United Arab Emirate have dominated the oil and gas sector since the discovery of oil in the region. They are the world largest producers of crude oil, producing about 35 and 25 percent of the world natural gas and crude oil respectively. The use of fossil fuels is directly linked to the release of CO2 into the environment. CO2 accounts for 58.8 percent of all greenhouse gases released via human activities, consequently, presenting a malign impact on the environment through climate change, global warming, biodiversity, acid rain and desertification among others. Due to its importance, the data on CO2 emission obtained from US EIA from 1980 – 2010 was regressed using least square techniques and projections were made to the year 2050. Results indicated that each country’s p-value was less than 0.05 which implies that the models can be used for predicting CO2 emissions into the future. The data shows the emission of CO2 by countries from the highest to the lowest in 2016 as: Iran (590.72 Mtonnes; 7.58 tonnes of CO2/person > Saudi Arabia (471.82 Mtonnes; 18 tonnes of CO2/person > UAE (218.58 Mtonnes; 41.31 tonnes of CO2/person > Iraq (114.01 Mtonees; 3.71 tonnes of CO2/person > Kuwait (92.58 Mtonnes; 36.31 tonnes of CO2/person > Qatar (68.26 Mtonnes; 37 tonnes of CO2/person > Bahrain (33.16 Mtonnes; 27.5 tonnes of CO2/person". The sequence from the country with highest emission (Iran to the country with lowest emission (Bahrain will remain the same until 2050. A projection depicting a 7.7 percent yearly increase in CO2 emission in the Persian Gulf States.

  9. Natural analogue study of CO2 storage monitoring using probability statistics of CO2-rich groundwater chemistry

    Science.gov (United States)

    Kim, K. K.; Hamm, S. Y.; Kim, S. O.; Yun, S. T.

    2016-12-01

    For confronting global climate change, carbon capture and storage (CCS) is one of several very useful strategies as using capture of greenhouse gases like CO2 spewed from stacks and then isolation of the gases in underground geologic storage. CO2-rich groundwater could be produced by CO2 dissolution into fresh groundwater around a CO2 storage site. As consequence, natural analogue studies related to geologic storage provide insights into future geologic CO2 storage sites as well as can provide crucial information on the safety and security of geologic sequestration, the long-term impact of CO2 storage on the environment, and field operation and monitoring that could be implemented for geologic sequestration. In this study, we developed CO2 leakage monitoring method using probability density function (PDF) by characterizing naturally occurring CO2-rich groundwater. For the study, we used existing data of CO2-rich groundwaters in different geological regions (Gangwondo, Gyeongsangdo, and Choongchungdo provinces) in South Korea. Using PDF method and QI (quantitative index), we executed qualitative and quantitative comparisons among local areas and chemical constituents. Geochemical properties of groundwater with/without CO2 as the PDF forms proved that pH, EC, TDS, HCO3-, Ca2+, Mg2+, and SiO2 were effective monitoring parameters for carbonated groundwater in the case of CO2leakage from an underground storage site. KEY WORDS: CO2-rich groundwater, CO2 storage site, monitoring parameter, natural analogue, probability density function (PDF), QI_quantitative index Acknowledgement This study was supported by the "Basic Science Research Program through the National Research Foundation of Korea (NRF), which is funded by the Ministry of Education (NRF-2013R1A1A2058186)" and the "R&D Project on Environmental Management of Geologic CO2 Storage" from KEITI (Project number: 2014001810003).

  10. Estimation and diminution of CO2 emissions by clean development mechanism option at power sector in Oman

    Energy Technology Data Exchange (ETDEWEB)

    Singh Solanki, Parmal; Sarma Mallela, Venkateswara [Caledonian (University) College of Engineering, Muscat (Oman); Zhou, Chengke [Glasgow Caledonian University, Glasgow, Scotland (United Kingdom)

    2013-07-01

    Carbon dioxide (CO2) is one of the major pollutants among greenhouse gases emitted by fossil fuel based power plants and responsible for environmental tribulations. Therefore diminution of carbon dioxide level by Clean Development Mechanism (CDM) is now serious concern worldwide. This paper evaluates the emission factors of national electric grid in Oman and proposes a wind energy based CDM project to diminish the CO2 emissions. Estimations show that operating margin emission factors of national grid during five years lies in the range of 0.74 to 0.69 kg CO2/kWh. Further, proposed CDM project revealed the annual baseline emissions reduction of 45552 ton CO2 and able to earn the revenue of US$ 61.49 million by certify emission reductions in the first crediting period of project. Paper also critically analyse the opportunities for CDM project, its lucrative aspect, barrier and challenges.

  11. Modeling light use efficiency in a subtropical mangrove forest equipped with CO2 eddy covariance

    Directory of Open Access Journals (Sweden)

    J. G. Barr

    2013-03-01

    Full Text Available Despite the importance of mangrove ecosystems in the global carbon budget, the relationships between environmental drivers and carbon dynamics in these forests remain poorly understood. This limited understanding is partly a result of the challenges associated with in situ flux studies. Tower-based CO2 eddy covariance (EC systems are installed in only a few mangrove forests worldwide, and the longest EC record from the Florida Everglades contains less than 9 years of observations. A primary goal of the present study was to develop a methodology to estimate canopy-scale photosynthetic light use efficiency in this forest. These tower-based observations represent a basis for associating CO2 fluxes with canopy light use properties, and thus provide the means for utilizing satellite-based reflectance data for larger scale investigations. We present a model for mangrove canopy light use efficiency utilizing the enhanced green vegetation index (EVI derived from the Moderate Resolution Imaging Spectroradiometer (MODIS that is capable of predicting changes in mangrove forest CO2 fluxes caused by a hurricane disturbance and changes in regional environmental conditions, including temperature and salinity. Model parameters are solved for in a Bayesian framework. The model structure requires estimates of ecosystem respiration (RE, and we present the first ever tower-based estimates of mangrove forest RE derived from nighttime CO2 fluxes. Our investigation is also the first to show the effects of salinity on mangrove forest CO2 uptake, which declines 5% per each 10 parts per thousand (ppt increase in salinity. Light use efficiency in this forest declines with increasing daily photosynthetic active radiation, which is an important departure from the assumption of constant light use efficiency typically applied in satellite-driven models. The model developed here provides a framework for estimating CO2 uptake by these forests from reflectance data and

  12. Stable isotope and modelling evidence that CO2 drives vegetation changes in the tropics

    Science.gov (United States)

    Bragg, F. J.; Prentice, I. C.; Harrison, S. P.; Eglinton, G.; Foster, P. N.; Rommerskirchen, F.; Rullkötter, J.

    2012-11-01

    Atmospheric CO2 concentration is hypothesized to influence vegetation distribution via tree-grass competition, with higher CO2 concentrations favouring trees. The stable carbon isotope (δ13C) signature of vegetation is influenced by the relative importance of C4 plants (including most tropical grasses) and C3 plants (including nearly all trees), and the degree of stomatal closure - a response to aridity - in C3 plants. Compound-specific δ13C analyses of leaf-wax biomarkers in sediment cores of an offshore South Atlantic transect are used here as a record of vegetation changes in subequatorial Africa. These data suggest a large increase in C3 relative to C4 plant dominance after the Last Glacial Maximum. Using a process-based biogeography model that explicitly simulates 13C discrimination, we show that climate change alone cannot explain the observed shift in δ13C values. The physiological effect of increasing CO2 concentration is decisive, altering the C3 / C4 balance and bringing the simulated and observed δ13C values into line. It is concluded that CO2 concentration itself was a key agent of tropical vegetation change during the last glacial-interglacial transition. Two additional inferences follow. First, long-term variations in terrestrial δ13C values are not simply a proxy for regional rainfall as has sometimes been assumed. Such interpretations need to be re-examined. Second, rising CO2 concentration today is likely to be influencing tree-grass competition in a similar way, and thus contributing to the "woody thickening" observed in savannas worldwide. This second inference points to the importance of experiments to determine how vegetation composition in savannas is likely to be influenced by the continuing rise in CO2 concentration.

  13. Biofiksasi CO2 Oleh Mikroalga Chlamydomonas sp dalam Photobioreaktor Tubular

    Directory of Open Access Journals (Sweden)

    Hadiyanto Hadiyanto

    2014-05-01

    Full Text Available Mikroalga memiliki potensi dalam membiofiksasi CO2 dan dapat dimanfaatkan untuk mengurangi kadar CO2 dalam gas pencemar. Pertumbuhan mikroalga sangat dipengaruhi oleh konsentrasi gas CO2 di dalam gas pencemar. Tujuan penelitian ini adalah untuk mengeetahui kemampuan mikroalga Chlamydomonas sp yang dikultivasi dalam photobioreaktor tubular dalam penyerapan gas CO2 serta untuk mengetahui konsentrasi maksimum gas CO2 dalam umpan untuk memproduksi biomasa mikroalga yang optimal. Percobaan dilakukan dnegan memvariasi laju alir dari 0.03 -0.071 L/menit dan konsentrasi CO2 dalam umpan 10-30%. Hasil penelitian menunjukkan bahwa biomasa mikroalga dapat diproduksi dengan maksimal dengan konsentrasi gas CO2 20% dengan laju alir 0.07 L/min. Semakin tinggi laju alir maka produksi biomasa alga semakin besar. Kecepatan pertumbuhan alga maksimum terjadi pada 0.31 /hari. Pada konsentrasi gas CO2 30%, terjadi substrate inhibition yang disebabkan carbon dalam bentuk ion bicarbonate tidak dapat dikonsumsi lagi di dalam kultur alga. Kata kunci : Mikroalga, chlamydomonas sp, biofiksasi CO2, biogas Abstract Microalgae have a potential for CO2 biofixation and therefore can be used to reduce the CO2 concentration in the gas pollutants. Moreover, microalgae growth is strongly affected by the concentration of CO2 in the exhaust gas pollutants. The objective of this research was to investigate the ability of microalgae Chlamydomonas sp which was cultivated in a tubular photobioreactor for CO2 absorption as well as to determine the maximum concentration of CO2 in the feed gas to obtain optimum microalgae biomass. The experiments were performed by varying the gas flow rate of 0.03 -0.071 L / min and the concentration of CO2 in the feed of 10-30%. The results showed that the maximum biomass of microalgae can be produced with CO2 concentration of 20% vol with a flow rate of 0.07 L / min. The result also showed that increasing the gas flow rate, the greater of the production of

  14. Air-sea CO2 fluxes along the coast of Chile: From CO2 outgassing in central northern upwelling waters to CO2 uptake in southern Patagonian fjords

    OpenAIRE

    Torres, Rodrigo; Duarte, Carlos M.; Ruiz-Halpern, Sergio; Fukasawa, Masao

    2011-01-01

    Carbon system parameters measured during several expeditions along the coast of Chile (23°S-56°S) have been used to show the main spatial and temporal trends of air-sea CO2 fluxes in the coastal waters of the eastern South Pacific. Chilean coastal waters are characterized by strong pCO2 gradients between the atmosphere and the surface water, with high spatial and temporal variability. On average, the direction of the carbon flux changes from CO2 outgassing at the coastal upwelling region to C...

  15. Recent enlightening strategies for co2 capture: a review

    Science.gov (United States)

    Yuan, Peng; Qiu, Ziyang; Liu, Jia

    2017-05-01

    The global climate change has seriously affected the survival and prosperity of mankind, where greenhouse effect owing to atmospheric carbon dioxide (CO2) enrichment is a great cause. Accordingly, a series of down-to-earth measures need to be implemented urgently to control the output of CO2. As CO2 capture appears as a core issue in developing low-carbon economy, this review provides a comprehensive introduction of recent CO2 capture technologies used in power plants or other industries. Strategies for CO2 capture, e.g. pre-combustion, post-combustion and oxyfuel combustion, are covered in this article. Another enlightening technology for CO2 capture based on fluidized beds is intensively discussed.

  16. Financial development and sectoral CO2emissions in Malaysia.

    Science.gov (United States)

    Maji, Ibrahim Kabiru; Habibullah, Muzafar Shah; Saari, Mohd Yusof

    2017-03-01

    The paper examines the impacts of financial development on sectoral carbon emissions (CO 2 ) for environmental quality in Malaysia. Since the financial sector is considered as one of the sectors that will contribute to Malaysian economy to become a developed country by 2020, we utilize a cointegration method to investigate how financial development affects sectoral CO 2 emissions. The long-run results reveal that financial development increases CO 2 emissions from the transportation and oil and gas sector and reduces CO 2 emissions from manufacturing and construction sectors. However, the elasticity of financial development is not significant in explaining CO 2 emissions from the agricultural sector. The results for short-run elasticities were also consistent with the long-run results. We conclude that generally, financial development increases CO 2 emissions and reduces environmental quality in Malaysia.

  17. A Circular Bioeconomy with Biobased Products from CO2 Sequestration.

    Science.gov (United States)

    Venkata Mohan, S; Modestra, J Annie; Amulya, K; Butti, Sai Kishore; Velvizhi, G

    2016-06-01

    The unprecedented climate change influenced by elevated concentrations of CO2 has compelled the research world to focus on CO2 sequestration. Although existing natural and anthropogenic CO2 sinks have proven valuable, their ability to further assimilate CO2 is now questioned. Thus, we highlight here the importance of biological sequestration methods as alternate and viable routes for mitigating climate change while simultaneously synthesizing value-added products that could sustainably fuel the circular bioeconomy. Four conceptual models for CO2 biosequestration and the synthesis of biobased products, as well as an integrated CO2 biorefinery model, are proposed. Optimizing and implementing this biorefinery model might overcome the limitations of existing sequestration methods and could help realign the carbon balance. Copyright © 2016 Elsevier Ltd. All rights reserved.

  18. CO2 measurements during transcranial Doppler examinations in headache patients

    DEFF Research Database (Denmark)

    Thomsen, L L; Iversen, Helle Klingenberg

    1994-01-01

    Transcranial Doppler (TCD) examinations are increasingly being used in studies of headache pathophysiology. Because blood velocity is highly dependent on PCO2, these parameters should be measured simultaneously. The most common way of performing measurements during TCD examinations is as end......-tidal pCO2 with a capnograph. When patients are nauseated and vomit, as in migraine, the mask or mouthpiece connected to the capnograph represents a problem. We therefore evaluated whether a transcutaneous pCO2 electrode was as useful as the capnograph for pCO2 measurements in TCD examinations. We...... conclude that this is not the case, and recommend capnographic end-tidal pCO2 measurements during TCD examinations. However, transcutaneous pCO2 measurements may represent a supplement to spot measurements of end-tidal pCO2 in stable conditions when long-term monitoring is needed, and the mask...

  19. CO2 Storage related Groundwater Impacts and Protection

    Science.gov (United States)

    Fischer, Sebastian; Knopf, Stefan; May, Franz; Rebscher, Dorothee

    2016-03-01

    Injection of CO2 into the deep subsurface will affect physical and chemical conditions in the storage environment. Hence, geological CO2 storage can have potential impacts on groundwater resources. Shallow freshwater can only be affected if leakage pathways facilitate the ascent of CO2 or saline formation water. Leakage associated with CO2 storage cannot be excluded, but potential environmental impacts could be reduced by selecting suitable storage locations. In the framework of risk assessment, testing of models and scenarios against operational data has to be performed repeatedly in order to predict the long-term fate of CO2. Monitoring of a storage site should reveal any deviations from expected storage performance, so that corrective measures can be taken. Comprehensive R & D activities and experience from several storage projects will enhance the state of knowledge on geological CO2 storage, thus enabling safe storage operations at well-characterised and carefully selected storage sites while meeting the requirements of groundwater protection.

  20. Climate-dependent CO2 emissions from lakes

    Science.gov (United States)

    Kosten, Sarian; Roland, FáBio; da Motta Marques, David M. L.; van Nes, Egbert H.; Mazzeo, NéStor; Sternberg, Leonel Da S. L.; Scheffer, Marten; Cole, Jon J.

    2010-06-01

    Inland waters, just as the world's oceans, play an important role in the global carbon cycle. While lakes and reservoirs typically emit CO2, they also bury carbon in their sediment. The net CO2 emission is largely the result of the decomposition or preservation of terrestrially supplied carbon. What regulates the balance between CO2 emission and carbon burial is not known, but climate change and temperature have been hypothesized to influence both processes. We analyzed patterns in carbon dioxide partial pressure (pCO2) in 83 shallow lakes over a large climatic gradient in South America and found a strong, positive correlation with temperature. The higher pCO2 in warmer lakes may be caused by a higher, temperature-dependent mineralization of organic carbon. This pattern suggests that cool lakes may start to emit more CO2 when they warm up because of climate change.

  1. Non-CO2 greenhouse gases and climate change.

    Science.gov (United States)

    Montzka, S A; Dlugokencky, E J; Butler, J H

    2011-08-03

    Earth's climate is warming as a result of anthropogenic emissions of greenhouse gases, particularly carbon dioxide (CO(2)) from fossil fuel combustion. Anthropogenic emissions of non-CO(2) greenhouse gases, such as methane, nitrous oxide and ozone-depleting substances (largely from sources other than fossil fuels), also contribute significantly to warming. Some non-CO(2) greenhouse gases have much shorter lifetimes than CO(2), so reducing their emissions offers an additional opportunity to lessen future climate change. Although it is clear that sustainably reducing the warming influence of greenhouse gases will be possible only with substantial cuts in emissions of CO(2), reducing non-CO(2) greenhouse gas emissions would be a relatively quick way of contributing to this goal.

  2. CO2 emission benefit of diesel (versus gasoline) powered vehicles.

    Science.gov (United States)

    Sullivan, J L; Baker, R E; Boyer, B A; Hammerle, R H; Kenney, T E; Muniz, L; Wallington, T J

    2004-06-15

    Concerns regarding global warming have increased the pressure on automobile manufacturers to decrease emissions of CO2 from vehicles. Diesel vehicles have higher fuel economy and lower CO2 emissions than their gasoline counterparts. Increased penetration of diesel powered vehicles into the market is a possible transition strategy toward a more sustainable transportation system. To facilitate discussions regarding the relative merits of diesel vehicles it is important to have a clear understanding of their CO2 emission benefits. Based on European diesel and gasoline certification data, this report quantifies such CO2 reduction opportunities for cars and light duty trucks in today's vehicles and those in the year 2015. Overall, on a well-to-wheels per vehicle per mile basis, the CO2 reduction opportunity for today's vehicles is approximately 24-33%. We anticipate that the gap between diesel and gasoline well-to-wheel vehicle CO2 emissions will decrease to approximately 14-27% by the year 2015.

  3. Transport Mechanisms for CO2-CH4 Exchange and Safe CO2 Storage in Hydrate-Bearing Sandstone

    Directory of Open Access Journals (Sweden)

    Knut Arne Birkedal

    2015-05-01

    Full Text Available CO2 injection in hydrate-bearing sediments induces methane (CH4 production while benefitting from CO2 storage, as demonstrated in both core and field scale studies. CH4 hydrates have been formed repeatedly in partially water saturated Bentheim sandstones. Magnetic Resonance Imaging (MRI and CH4 consumption from pump logs have been used to verify final CH4 hydrate saturation. Gas Chromatography (GC in combination with a Mass Flow Meter was used to quantify CH4 recovery during CO2 injection. The overall aim has been to study the impact of CO2 in fractured and non-fractured samples to determine the performance of CO2-induced CH4 hydrate production. Previous efforts focused on diffusion-driven exchange from a fracture volume. This approach was limited by gas dilution, where free and produced CH4 reduced the CO2 concentration and subsequent driving force for both diffusion and exchange. This limitation was targeted by performing experiments where CO2 was injected continuously into the spacer volume to maintain a high driving force. To evaluate the effect of diffusion length multi-fractured core samples were used, which demonstrated that length was not the dominating effect on core scale. An additional set of experiments is presented on non-fractured samples, where diffusion-limited transportation was assisted by continuous CO2 injection and CH4 displacement. Loss of permeability was addressed through binary gas (N2/CO2 injection, which regained injectivity and sustained CO2-CH4 exchange.

  4. Numerical Study on CO2-Brine-Rock Interaction of Enhanced Geothermal Systems with CO2 as Heat Transmission Fluid

    Directory of Open Access Journals (Sweden)

    Wan Yuyu

    2016-01-01

    Full Text Available Enhanced Geothermal Systems (EGS with CO2 instead of water as heat transmission fluid is an attractive concept for both geothermal resources development and CO2 geological sequestration. Previous studies show that CO2 has lots of favorable properties as heat transmission fluid and also can offer geologic storage of CO2 as an ancillary benefit. However, after CO2 injection into geological formations, chemical reaction between brine and rock can change chemical characteristics of saline and properties of rock such as porosity and permeability. Is this advantage or disadvantage for EGS operating? To answer this question, we have performed chemically reactive transport modeling to investigate fluid-rock interactions and CO2 mineral carbonation of Enhanced Geothermal Systems (EGS site at Desert Peak (Nevada operated with CO2. The simulation results show that (1 injection CO2 can create a core zone fulfilled with CO2 as main working domain for EGS, and (2 CO2 storage can induced self-enhancing alteration of EGS.

  5. Implications of overestimated anthropogenic CO2 emissions on East Asian and global land CO2 flux inversion

    Science.gov (United States)

    Saeki, Tazu; Patra, Prabir K.

    2017-12-01

    Measurement and modelling of regional or country-level carbon dioxide (CO2) fluxes are becoming critical for verification of the greenhouse gases emission control. One of the commonly adopted approaches is inverse modelling, where CO2 fluxes (emission: positive flux, sink: negative flux) from the terrestrial ecosystems are estimated by combining atmospheric CO2 measurements with atmospheric transport models. The inverse models assume anthropogenic emissions are known, and thus the uncertainties in the emissions introduce systematic bias in estimation of the terrestrial (residual) fluxes by inverse modelling. Here we show that the CO2 sink increase, estimated by the inverse model, over East Asia (China, Japan, Korea and Mongolia), by about 0.26 PgC year-1 (1 Pg = 1012 g) during 2001-2010, is likely to be an artifact of the anthropogenic CO2 emissions increasing too quickly in China by 1.41 PgC year-1. Independent results from methane (CH4) inversion suggested about 41% lower rate of East Asian CH4 emission increase during 2002-2012. We apply a scaling factor of 0.59, based on CH4 inversion, to the rate of anthropogenic CO2 emission increase since the anthropogenic emissions of both CO2 and CH4 increase linearly in the emission inventory. We find no systematic increase in land CO2 uptake over East Asia during 1993-2010 or 2000-2009 when scaled anthropogenic CO2 emissions are used, and that there is a need of higher emission increase rate for 2010-2012 compared to those calculated by the inventory methods. High bias in anthropogenic CO2 emissions leads to stronger land sinks in global land-ocean flux partitioning in our inverse model. The corrected anthropogenic CO2 emissions also produce measurable reductions in the rate of global land CO2 sink increase post-2002, leading to a better agreement with the terrestrial biospheric model simulations that include CO2-fertilization and climate effects.

  6. CO2 laser welding of magnesium alloys

    Science.gov (United States)

    Dhahri, Mohammed; Masse, Jean Eric; Mathieu, J. F.; Barreau, Gerard; Autric, Michel L.

    2000-02-01

    Metallic alloys with a low mass density can be considered to be basic materials in aeronautic and automotive industry. Magnesium alloys have better properties than aluminum alloys in respect of their low density and high resistance to traction. The main problems of magnesium alloy welding are the inflammability, the crack formation and the appearance of porosity during the solidification. The laser tool is efficient to overcome the difficulties of manufacturing by conventional processing. Besides, the laser processing mainly using shielding gases allows an effective protection of the metal against the action of oxygen and a small heat affected zone. In this paper, we present experimental results about 5 kW CO2 laser welding of 4 mm-thick magnesium alloy plates provided by Eurocopter France. The focused laser beam has about 0.15 mm of diameter. We have investigated the following sample: WE43, alloy recommended in aeronautic and space applications, is constituted with Mg, Y, Zr, rare earth. More ductile, it can be used at high temperatures until 250 degrees Celsius for times longer than 5000 hours without effects on its mechanical properties. A sample of RZ5 (French Norm: GZ4TR, United States Norm ZE41) is composed of Mg, Zn, Zr, La, rare earth. This alloy has excellent properties of foundry and it allows to the realization of components with complex form. Also, it has a good resistance and important properties of tightness. The parameters of the process were optimized in the following fields: laser power: 2 to 5 kW, welding speed: 1 to 4.5 m/min, focal position: -3 mm to +3 mm below or on the top of the metal surface, shielding gas: helium with a flow of 10 to 60 l/min at 4 bars. Metallurgical analyses and mechanical control are made (macroscopic structure, microscopic structure, interpretations of the structures and localization of possible defects, analyse phases, chemical composition, hardness, tensile test etc.) to understand the parameters influence of welding

  7. CO2 hydrogenation to hydrocarbons over iron nanoparticles ...

    Indian Academy of Sciences (India)

    Hydrogenation of CO2 to hydrocarbons over iron nanoparticles supported on oxygen- functionalized multi-walled carbon nanotubes was studied in a fixed-bed U-tube reactor at 25 bar with a. H2:CO2 ratio of 3. Conversion of CO2 was approximately 35% yielding C1–C5 products at 360. ◦. C with methane and CO as major ...

  8. Holiday CO2: Inference from the Salt Lake City data

    Science.gov (United States)

    Ryoo, J.; Fung, I. Y.; Ehleringer, J. R.; Stephens, B. B.

    2013-12-01

    A network of high-frequency CO2 sensors has been established in Salt Lake City (SLC), Utah (http://co2.utah.edu/), and the annual/monthly pattern of CO2 variability is consistent with a priori estimates of CO2 fluxes (McKain et al., 2012). Here we ask if short-term changes in anthropogenic sources can be detected, and present a case study of Thanksgiving holiday, when traffic and energy use patterns are expected to be different from that during the rest of the month. CO2 mole fraction is much higher during the Thanksgiving holidays than the other days in November 2008 for all 5 sites in SLC, and a similar pattern is found in other years. Taking into account that the wind speed is relatively low in downtown SLC compared to the other SLC sites, the downtown site is further investigated to minimize the meteorological influence on CO2. In order to understand the relative contributions to the high level of CO2 during the Thanksgiving holidays, we carried out a multiple linear regression (MLR) analysis of the rate of CO2 change against various sources. Mobile CO2 sources are assumed to be proportional to local traffic data and residential CO2 sources are assumed to depend exponentially on temperature. Vulcan data were used to specify the other anthropogenic sources (commercial, industrial, nonroad, electricity, aircraft, and cement). The MLR analysis shows that during the Thanksgiving holidays CO2 contributions from residential and commercial CO2 are larger than that during the rest of November, and mobile sources represent only a relatively small contribution. The study demonstrates the feasibility of detecting changes in urban source contributions using high-frequency measurements in combination with daily PBL height and local traffic volume data.

  9. Simulating Remediation of CO2 Leakage from Geological Storage Sites

    Science.gov (United States)

    Zhang, Y.; Oldenburg, C. M.; Benson, S. M.

    2003-12-01

    One strategy to reduce net greenhouse gas emissions is to inject carbon dioxide (CO2) deep into subsurface formations where presumably it would be stored indefinitely. Although geologic storage formations will be carefully selected, CO2 injected into a target formation may unexpectedly migrate upwards and ultimately seep out at the ground surface, creating a potential hazard to human beings and ecosystems. In this case, CO2 that has leaked from the geologic storage site is considered a contaminant, and remediation strategies such as passive venting and active pumping are needed. The purpose of this study is to investigate remediation strategies for CO2 leakage from geologic storage sites. We use the integral finite-difference code TOUGH2 to simulate the remediation of CO2 in subsurface systems. We consider the components of water, CO2 and air, and model flow and transport in aqueous and gas phases subject to a variety of initial and boundary conditions including passive venting and active pumping. We have investigated the time it takes for a gas plume of CO2 to be removed from the vadose zone both by natural attenuation processes and by active extraction wells. The time for removal is parameterized in terms of a CO2 plume half-life, defined as the time required for one-half of the CO2 mass to be removed. Initial simulations show that barometric pressure fluctuations enhance the removal of CO2 from the vadose zone, but that CO2 trapped near the water table is difficult to remove by either passive or active remediation approaches. This work was supported by a Cooperative Research and Development Agreement (CRADA) between BP Corporation North America, as part of the CO2 Capture Project (CCP), and the U.S. Department of Energy (DOE) through the National Energy Technologies Laboratory (NETL), and by the U.S. Department of Energy under contract DE-AC03-76SF00098.

  10. CO2^{*} chemiluminescence study at low and elevated pressures

    Science.gov (United States)

    Kopp, M.; Brower, M.; Mathieu, O.; Petersen, E.; Güthe, F.

    2012-06-01

    Chemiluminescence experiments have been performed to assess the state of current CO2^{*} kinetics modeling. The difficulty with modeling CO2^{*} lies in its broad emission spectrum, making it a challenge to isolate it from background emission of species such as CH∗ and CH2O∗. Experiments were performed in a mixture of 0.0005H2+0.01N2O+0.03CO+0.9595Ar in an attempt to isolate CO2^{*} emission. Temperatures ranged from 1654 K to 2221 K at two average pressures, 1.4 and 10.4 atm. The unique time histories of the various chemiluminescence species in the unconventional mixture employed at these conditions allow for easy identification of the CO2^{*} concentration. Two different wavelengths to capture CO2^{*} were used; one optical filter was centered at 415 nm and the other at 458 nm. The use of these two different wavelengths was done to verify that broadband CO2^{*} was in fact being captured, and not emission from other species such as CH∗ and CH2O∗. As a baseline for time history and peak magnitude comparison, OH∗ emission was captured at 307 nm simultaneously with the two CO2^{*} filters. The results from the two CO2^{*} filters were consistent with each other, implying that indeed the same species (i.e., CO2^{*}) was being measured at both wavelengths. A first-generation kinetics model for CO2^{*} and CH2O∗ was developed, since no comprehensively validated one exists to date. CH2O∗ and CH∗ were ruled out as being present in the experiments at any measurable level, based on calculations and comparisons with the data. Agreement with the CO2^{*} model was only fair, which necessitates future improvements for a better understanding of CO2^{*} chemiluminescence as well as the kinetics of the ground state species.

  11. Corrosion studies on casing steel in CO2 storage environments

    NARCIS (Netherlands)

    Zhang, X.; Zevenbergen, J.F.; Benedictus, T.

    2013-01-01

    The corrosion behavior of casing steel N80 in brine plus CO2 was studied in autoclave to simulate the CO2 storage environment. The brine solution used in the study contained 130 g/l NaCl, 22.2 g/l CaCl2 and 4 g/l MgCl2. The CO2 was charged in the autoclave at different pressures (60, 80 and 100 bar)

  12. CO 2 hydrogenation to hydrocarbons over iron nanoparticles ...

    Indian Academy of Sciences (India)

    Hydrogenation of CO2 to hydrocarbons over iron nanoparticles supported on oxygenfunctionalized multi-walled carbon nanotubes was studied in a fixed-bed U-tube reactor at 25 bar with a H2:CO2 ratio of 3. Conversion of CO2 was approximately 35% yielding C1-C5 products at 360°C with methane and CO as major ...

  13. CO2 laser resurfacing of the face and neck.

    Science.gov (United States)

    Goldman, M P

    2001-05-01

    Laser resurfacing with the short-pulsed, high-energy CO2 laser has been used to treat photodamaged skin and acne scars. Efficacy and safety have been demonstrated with this technique since 1992. Newer treatment methods, including sequential or combination treatment with the Er:YAG laser have led to increased efficacy with a decrease in adverse sequelae. This article details the author's experience with CO2 laser resurfacing and promotes the use of sequential CO2/Er:YAG laser resurfacing.

  14. THE INFLUENCE OF CO2 ON WELL CEMENT

    Directory of Open Access Journals (Sweden)

    Nediljka Gaurina-Međimurec

    2010-12-01

    Full Text Available Carbon capture and storage is one way to reduce emissions of greenhouse gases in the atmosphere. Underground gas storage operations and CO2 sequestration in aquifers relay on both the proper wellbore construction and sealing properties of the cap rock. CO2 injection candidates may be new wells or old wells. In both cases, the long-term wellbore integrity (up to 1 000 years is one of the key performance criteria in the geological storage of CO2. The potential leakage paths are the migration CO2 along the wellbore due to poor cementation and flow through the cap rock. The permeability and integrity of the set cement will determine how effective it is in preventing the leakage. The integrity of the cap rock is assured by an adequate fracture gradient and by sufficient set cement around the casing across the cap rock and without a micro-annulus. CO2 storage in underground formations has revived the researc of long term influence of the injected CO2 on Portland cements and methods for improving the long term efficiency of the wellbore sealant. Some researchers predicted that set cement will fail when exposed to CO2 leading to potential leakage to the atmosphere or into underground formations that may contain potable water. Other researchers show set cement samples from 30 to 50 year-old wells (CO2 EOR projects that have maintained sealing integrity and prevented CO2 leakage, in spite of some degree of carbonation. One of reasons for the discrepancy between certain research lab tests and actual field performance measurements is the absence of standard protocol for CO2 resistance-testing devices, conditions, or procedures. This paper presents potential flow paths along the wellbore, CO2 behaviour under reservoir conditions, and geochemical alteration of hydrated Portland cement due to supercritical CO2 injection.

  15. System-level modeling for geological storage of CO2

    OpenAIRE

    Zhang, Yingqi; Oldenburg, Curtis M.; Finsterle, Stefan; Bodvarsson, Gudmundur S.

    2006-01-01

    One way to reduce the effects of anthropogenic greenhouse gases on climate is to inject carbon dioxide (CO2) from industrial sources into deep geological formations such as brine formations or depleted oil or gas reservoirs. Research has and is being conducted to improve understanding of factors affecting particular aspects of geological CO2 storage, such as performance, capacity, and health, safety and environmental (HSE) issues, as well as to lower the cost of CO2 capture and related p...

  16. Myths about nutrition in pregnancy.

    Science.gov (United States)

    Guggino, Alice; Barbero, Sara; Ponzo, Valentina; Viora, Elsa; Durazzo, Marilena; Bo, Simona

    2016-10-01

    Many women have incorrect knowledge about nutrition in pregnancy owing to false beliefs derived from popular practices. More than 90% of our cohort of pregnant women during early pregnancy (myths about nutrition in pregnancy. Education was inversely associated with the percentage of incorrect answers, and the lowest percentage of any mistakes was found in the small number of women who received nutritional information by a dietician. In conclusion, the usual sources of information about nutrition in pregnancy are not adequate to overcome the false beliefs acquired by traditions.

  17. Synergistic effects of hypoxia and increasing CO2 on benthic invertebrates of the central Chilean coast

    KAUST Repository

    Steckbauer, Alexandra

    2015-07-10

    Ocean acidification (OA) and hypoxic events are an increasing worldwide problem, but the synergetic effects of these factors are seldom explored. However, this synergetic occurrence of stressors is prevalent. The coastline of Chile not only suffers from coastal hypoxia but the cold, oxygen-poor waters in upwelling events are also supersaturated in CO2, a study site to explore the combined effect of OA and hypoxia. We experimentally evaluated the metabolic response of different invertebrate species (2 anthozoans, 9 molluscs, 4 crustaceans, 2 echinoderms) of the coastline of central Chile (33°30′S, 71°37′W) to hypoxia and OA within predicted levels and in a full factorial design. Organisms were exposed to 4 different treatments (ambient, low oxygen, high CO2, and the combination of low oxygen and high CO2) and metabolism was measured after 3 and 6 days. We show that the combination of hypoxia and increased pCO2 reduces the respiration significantly, compared to a single stressor. The evaluation of synergistic pressures, a more realistic scenario than single stressors, is crucial to evaluate the effect of future changes for coastal species and our results provide the first insight on what might happen in the next 100 years.

  18. Synergistic effects of hypoxia and increasing CO2 on benthic invertebrates of the central Chilean coast

    Directory of Open Access Journals (Sweden)

    Alexandra eSteckbauer

    2015-07-01

    Full Text Available Ocean acidification and hypoxic events are an increasing worldwide problem, but the synergetic effects of these factors are seldom explored. However, this synergetic occurrence of stressors is prevalent. The coastline of Chile not only suffers from coastal hypoxia but the cold, oxygen-poor waters in upwelling events are also supersaturated in CO2, a study site to explore the combined effect of ocean acidification and hypoxia. We experimentally evaluated the metabolic response of different invertebrate species (2 anthozoans, 9 molluscs, 4 crustaceans, 2 echinoderms of the coastline of central Chile (33°30’S, 71°37’W to hypoxia and ocean acidification within predicted levels and in a full factorial design. Organisms were exposed to 4 different treatments (ambient, low oxygen, high CO2, and the combination of low oxygen and high CO2 and metabolism was measured after 3 and 6 days. We show that the combination of hypoxia and increased pCO2 reduces the respiration significantly, compared to a single stressor. The evaluation of synergistic pressures, a more realistic scenario than single stressors, is crucial to evaluate the effect of future changes for coastal species and our results provide the first insight on what might happen in the next 100 years.

  19. Activation of CO2 by supported Cu clusters.

    Science.gov (United States)

    Iyemperumal, Satish Kumar; Deskins, N Aaron

    2017-11-01

    Catalytic reduction of carbon dioxide to useful chemicals is a potent way to mitigate this greenhouse gas, but the challenge lies in finding active reduction catalysts. Using density functional theory we studied CO2 activation over TiO2-supported Cu clusters of size 1-4 atoms. The linear to bent transformation of CO2 is necessary for activation, and we found that all the clusters stabilized bent CO2, along with a significant gain of electrons on the CO2 (indicative of activation). On all the TiO2 supported Cu clusters, the interfacial sites were found to stabilize the bent CO2 adsorption, where the active site of adsorption on Cu dimer, trimer and tetramer was on the Cu atom farthest away from the TiO2 surface. Particularly, the Cu dimer stabilized bent CO2 very strongly, although this species was found to be unstable on the surface. A synthesis technique that could stabilize the Cu dimer could therefore lead to a very active catalyst. Furthermore we found (using vibrational and charge analysis) that the active sites for the CO2 activation predominantly had 0 and +1 oxidation states; the oxidation state of Cu is known to directly affect CO2 reduction activity. Our study shows TiO2-supported small Cu clusters can be active catalysts for CO2 reduction and also provides further motivation for theoretical and experimental studies of metal clusters.

  20. Investigation of CO2precursors in roasted coffee.

    Science.gov (United States)

    Wang, Xiuju; Lim, Loong-Tak

    2017-03-15

    Two CO 2 formation pathways (chlorogenic acid (CGA) degradation and Maillard reaction) during coffee roasting were investigated. CGA is shown not a major contributor to CO 2 formation, as heating of this compound under typical roasting conditions did not release a large quantity of CO 2 . However, heating of a CGA moiety, caffeic acid, resulted in high yield of CO 2 (>98%), suggesting that CGA hydrolysis could be the rate limiting step for CO 2 formation from CGA. A large amount of CO 2 was detected from glycine-sucrose model system under coffee roasting conditions, implying the importance of Maillard reactions in CO 2 formation. Further studies on the heating of various components isolated from green coffee beans showed that CO 2 was generated from various green coffee components, including water insoluble proteins and polysaccharides. Around 50% of CO 2 was formed from thermal reactions of lower molecular weight compounds that represent ∼25% by weight in green coffee. Copyright © 2016 Elsevier Ltd. All rights reserved.

  1. CO2 Emissions From Fuel Combustion. Highlights. 2013 Edition

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2013-07-01

    In the lead-up to the UN climate negotiations in Warsaw, the latest information on the level and growth of CO2 emissions, their source and geographic distribution will be essential to lay the foundation for a global agreement. To provide input to and support for the UN process, the IEA is making available for free download the ''Highlights'' version of CO2 Emissions from Fuel Combustion now for sale on IEA Bookshop. This annual publication contains, for more than 140 countries and regions: estimates of CO2 emissions from 1971 to 2011; selected indicators such as CO2/GDP, CO2/capita, CO2/TPES and CO2/kWh; a decomposition of CO2 emissions into driving factors; and CO2emissions from international marine and aviation bunkers, key sources, and other relevant information. The nineteenth session of the Conference of the Parties to the Climate Change Convention (COP-19), in conjunction with the ninth meeting of the Parties to the Kyoto Protocol (CMP 9), met in Warsaw, Poland from 11 to 22 November 2013. This volume of ''Highlights'', drawn from the full-scale study, was specially designed for delegations and observers of the meeting in Warsaw.

  2. CO2 emissions from German drinking water reservoirs.

    Science.gov (United States)

    Saidi, Helmi; Koschorreck, Matthias

    2017-03-01

    Globally, reservoirs are a significant source of atmospheric CO2. However, precise quantification of greenhouse gas emissions from drinking water reservoirs on the regional or national scale is still challenging. We calculated CO2 fluxes for 39 German drinking water reservoirs during a period of 22years (1991-2013) using routine monitoring data in order to quantify total emission of CO2 from drinking water reservoirs in Germany and to identify major drivers. All reservoirs were a net CO2 source with a median flux of 167gCm-2y-1, which makes gaseous emissions a relevant process for the carbon budget of each reservoir. Fluxes varied seasonally with median fluxes of 13, 48, and 201gCm-2y-1 in spring, summer, and autumn respectively. Differences between reservoirs appeared to be primarily caused by the concentration of CO2 in the surface water rather than by the physical gas transfer coefficient. Consideration of short term fluctuations of the gas transfer coefficient due to varying wind speed had only a minor effect on the annual budgets. High CO2 emissions only occurred in reservoirs with pHemissions correlated exponentially with pH but not with dissolved organic carbon (DOC). There was significant correlation between land use in the catchment and CO2 emissions. In total, German drinking water reservoirs emit 44000t of CO2 annually, which makes them a negligible CO2 source (emissions) in Germany. Copyright © 2017 Elsevier B.V. All rights reserved.

  3. Atmospheric CO2 Variability Observed From ASCENDS Flight Campaigns

    Science.gov (United States)

    Lin, Bing; Browell, Edward; Campbell, Joel; Choi, Yonghoon; Dobler, Jeremy; Fan, Tai-Fang; Harrison, F. Wallace; Kooi, Susan; Liu, Zhaoyan; Meadows, Byron; hide

    2015-01-01

    Significant atmospheric CO2 variations on various spatiotemporal scales were observed during ASCENDS flight campaigns. For example, around 10-ppm CO2 changes were found within free troposphere in a region of about 200x300 sq km over Iowa during a summer 2014 flight. Even over extended forests, about 2-ppm CO2 column variability was measured within about 500-km distance. For winter times, especially over snow covered ground, relatively less horizontal CO2 variability was observed, likely owing to minimal interactions between the atmosphere and land surface. Inter-annual variations of CO2 drawdown over cornfields in the Mid-West were found to be larger than 5 ppm due to slight differences in the corn growing phase and meteorological conditions even in the same time period of a year. Furthermore, considerable differences in atmospheric CO2 profiles were found during winter and summer campaigns. In the winter CO2 was found to decrease from about 400 ppm in the atmospheric boundary layer (ABL) to about 392 ppm above 10 km, while in the summer CO2 increased from 386 ppm in the ABL to about 396 ppm in free troposphere. These and other CO2 observations are discussed in this presentation.

  4. A practical CO2 flux remote sensing technique

    Science.gov (United States)

    Queisser, Manuel; Burton, Mike

    2017-04-01

    An accurate quantification of CO2 flux from both natural and anthropogenic sources is of great interest in various areas of the Earth, environmental and atmospheric sciences. As emitted excess CO2 quickly dilutes into the 400 ppm ambient CO2 concentration and degassing often occurs diffusively, measuring CO2 fluxes is challenging. Therefore, fluxes are usually derived from grids of in-situ measurements, which are labour intensive measurements. Other than a safe measurement distance, remote sensing offers quick, spatially integrated and thus a more thorough measurement of gas fluxes. Active remote sensing combines these merits with operation independent of sunlight or clear sky conditions. Due to their weight and size, active remote sensing platforms for CO2, such as LIDAR, cannot easily be applied in the field or transported overseas. Moreover, their complexity requires a rather lengthy setup procedure to be undertaken by skilled personal. To meet the need for a rugged, practical CO2 remote sensing technique to scan volcanic plumes, we have developed the CO2 LIDAR. It measures 1-D column densities of CO2 with sufficient sensitivity to reveal the contribution of magmatic CO2. The CO2 LIDAR has been mounted inside a small aircraft and used to measure atmospheric column CO2 concentrations between the aircraft and the ground. It was further employed on the ground, measuring CO2 emissions from mud volcanism. During the measurement campaign the CO2 LIDAR demonstrated reliability, portability, quick set-up time (10 to 15 min) and platform independence. This new technique opens the possibility of rapid, comprehensive surveys of point source, open-vent CO2 emissions, as well as emissions from more diffuse sources such as lakes and fumarole fields. Currently, within the proof-of-concept ERC project CarbSens, a further reduction in size, weight and operational complexity is underway with the goal to commercialize the platform. Areas of potential applications include fugitive

  5. Efficient electrochemical CO2 conversion powered by renewable energy.

    Science.gov (United States)

    Kauffman, Douglas R; Thakkar, Jay; Siva, Rajan; Matranga, Christopher; Ohodnicki, Paul R; Zeng, Chenjie; Jin, Rongchao

    2015-07-22

    The catalytic conversion of CO2 into industrially relevant chemicals is one strategy for mitigating greenhouse gas emissions. Along these lines, electrochemical CO2 conversion technologies are attractive because they can operate with high reaction rates at ambient conditions. However, electrochemical systems require electricity, and CO2 conversion processes must integrate with carbon-free, renewable-energy sources to be viable on larger scales. We utilize Au25 nanoclusters as renewably powered CO2 conversion electrocatalysts with CO2 → CO reaction rates between 400 and 800 L of CO2 per gram of catalytic metal per hour and product selectivities between 80 and 95%. These performance metrics correspond to conversion rates approaching 0.8-1.6 kg of CO2 per gram of catalytic metal per hour. We also present data showing CO2 conversion rates and product selectivity strongly depend on catalyst loading. Optimized systems demonstrate stable operation and reaction turnover numbers (TONs) approaching 6 × 10(6) molCO2 molcatalyst(-1) during a multiday (36 h total hours) CO2 electrolysis experiment containing multiple start/stop cycles. TONs between 1 × 10(6) and 4 × 10(6) molCO2 molcatalyst(-1) were obtained when our system was powered by consumer-grade renewable-energy sources. Daytime photovoltaic-powered CO2 conversion was demonstrated for 12 h and we mimicked low-light or nighttime operation for 24 h with a solar-rechargeable battery. This proof-of-principle study provides some of the initial performance data necessary for assessing the scalability and technical viability of electrochemical CO2 conversion technologies. Specifically, we show the following: (1) all electrochemical CO2 conversion systems will produce a net increase in CO2 emissions if they do not integrate with renewable-energy sources, (2) catalyst loading vs activity trends can be used to tune process rates and product distributions, and (3) state-of-the-art renewable-energy technologies are sufficient

  6. Supported Catalysts for CO2 Methanation: A Review

    Directory of Open Access Journals (Sweden)

    Patrizia Frontera

    2017-02-01

    Full Text Available CO2 methanation is a well-known reaction that is of interest as a capture and storage (CCS process and as a renewable energy storage system based on a power-to-gas conversion process by substitute or synthetic natural gas (SNG production. Integrating water electrolysis and CO2 methanation is a highly effective way to store energy produced by renewables sources. The conversion of electricity into methane takes place via two steps: hydrogen is produced by electrolysis and converted to methane by CO2 methanation. The effectiveness and efficiency of power-to-gas plants strongly depend on the CO2 methanation process. For this reason, research on CO2 methanation has intensified over the last 10 years. The rise of active, selective, and stable catalysts is the core of the CO2 methanation process. Novel, heterogeneous catalysts have been tested and tuned such that the CO2 methanation process increases their productivity. The present work aims to give a critical overview of CO2 methanation catalyst production and research carried out in the last 50 years. The fundamentals of reaction mechanism, catalyst deactivation, and catalyst promoters, as well as a discussion of current and future developments in CO2 methanation, are also included.

  7. Cerebrovascular CO2 reactivity in normotensive and hypertensive man

    DEFF Research Database (Denmark)

    Tominaga, S; Strandgaard, S; Uemura, K

    1976-01-01

    Cerebrovascular reactivity to CO2 inhalation and voluntary hyperventilation was studied in seven normotensive subjects and nine hypertensive patients without clinical or angiographical signs of arteriosclerosis. Cerebral blood flow (CBF) was measured by the intracarotid 133Xe clearance method...... and calculated as the initial slope index. Three to five CBF measurements were made in each patient in the PaCO2 range of 20 to 55 mm Hg. No difference was observed in reactivity between hypertensive and normotensive patients, either during CO2 inhalation or during hyperventilation. The shape of the CBF:PaCO2...

  8. Reducing of CO2 emissions and its depositing into underground

    Directory of Open Access Journals (Sweden)

    Jaroslava Koudelková

    2005-11-01

    Full Text Available Increasing CO2 emissions caused especially by the combustion of fossil fuels rises a question of how this can be problem solved in the long term. There is several solutions which differ technically and financially. This paper deals with the CO2 capture from combustion processes or power plant processes, (CO2 can be captured from the flue gas, after combustion in oxygen and recirculated flue gas or from a synthesis gas before combustion. This paper presents possibilities of CO2 storagex captured in this way into underground (deep ocean, oil and gas fields, coal bed, aquifers.

  9. Enhanced Oil Recovery with CO2 Capture and Sequestration

    Energy Technology Data Exchange (ETDEWEB)

    Andrei, Maria; De Simoni, Michela; Delbianco, Alberto; Cazzani, Piero; Zanibelli, Laura

    2010-09-15

    This paper presents the results of a feasibility study aimed at extending the production life of a small oilfield in Italy through EOR, employing the CO2 captured from the flue gas streams of the refinery nearby. The EOR operation allows the recovery of additional reserves while a consistent amount of the CO2 injected remains permanently stored into the reservoir. The screening process selection for EOR-CO2 and the main elements of the pilot project for the proper upstream-downstream integration will be described. Evaluation of EOR-CO2 extension to other oilfields and its effect on oil production and project's economics will be reported.

  10. A Global Perspective of Atmospheric CO2 Concentrations

    Science.gov (United States)

    Putman, William M.; Ott, Lesley; Darmenov, Anton; daSilva, Arlindo

    2016-01-01

    Carbon dioxide (CO2) is the most important greenhouse gas affected by human activity. About half of the CO2 emitted from fossil fuel combustion remains in the atmosphere, contributing to rising temperatures, while the other half is absorbed by natural land and ocean carbon reservoirs. Despite the importance of CO2, many questions remain regarding the processes that control these fluxes and how they may change in response to a changing climate. The Orbiting Carbon Observatory-2 (OCO-2), launched on July 2, 2014, is NASA's first satellite mission designed to provide the global view of atmospheric CO2 needed to better understand both human emissions and natural fluxes. This visualization shows how column CO2 mixing ratio, the quantity observed by OCO-2, varies throughout the year. By observing spatial and temporal gradients in CO2 like those shown, OCO-2 data will improve our understanding of carbon flux estimates. But, CO2 observations can't do that alone. This visualization also shows that column CO2 mixing ratios are strongly affected by large-scale weather systems. In order to fully understand carbon flux processes, OCO-2 observations and atmospheric models will work closely together to determine when and where observed CO2 came from. Together, the combination of high-resolution data and models will guide climate models towards more reliable predictions of future conditions.

  11. Fabry-Perot Interferometer for Column CO2: Airborne

    Science.gov (United States)

    Kawa, S. R.; Heaps, W. S.; Mao, J.; Andrews, A. E.; Burris, J. F.; Miodek, M.; Georgieva, E.

    2002-01-01

    Global atmospheric CO2 measurements are essential to resolving significant discrepancies in our understanding of the global carbon budget and, hence, humankind's role in global climate change. The science measurement requirements for CO2 are, however, extremely demanding (precision approximately 0.3%). We are developing a novel application of a Fabry-Perot interferometer to detect spectral absorption of reflected sunlight by CO2 and O2 in the atmosphere that should be able to achieve sufficient sensitivity and signal-to-noise to measure column CO2 at the target specification. We are currently constructing a prototype instrument for deployment on aircraft. The aircraft version will measure total column CO2 and CO2 below the aircraft as well as O2, which allows normalization of CO2 column amounts for varying surface height and pressure. This instrument will be a valuable asset in carbon budget field studies as well as a useful tool for evaluating existing and future space-based CO2 measurements. We will present the instrument concept, sensitivity calculations, and the results of testing a bench system in the laboratory and outdoors on the ground. We will also discuss our plan for deployment on the aircraft and potential flight applications to the CO2 budget problem.

  12. Electrochemical CO2 concentration for the Space Station Program

    Science.gov (United States)

    Lance, N.; Schwartz, M.; Boyda, R. B.

    1985-01-01

    Under the sponsorship of NASA, Electrochemical Carbon Dioxide (CO2) Concentration EDC technology has been developed that removes CO2 continuously or cyclically from low CO2 partial pressure (400 Pa) atmospheres with the performance and operating characteristics required for Space Station applications. The most recent advancement of this technology is the development of an advanced preprototype subsystem, the CS-3A, to remove the metabolic CO2 produced by three persons from the projected Space Station atmosphere. This paper provides an overview of EDC technology, shows how it is ideally suited for Space Station application, and presents technology enhancements that will be demonstrated by the CS-3A subsystem development program.

  13. Positive feedback between increasing atmospheric CO2 and ecosystem productivity

    Science.gov (United States)

    Gelfand, I.; Hamilton, S. K.; Robertson, G. P.

    2009-12-01

    Increasing atmospheric CO2 will likely affect both the hydrologic cycle and ecosystem productivity. Current assumptions that increasing CO2 will lead to increased ecosystem productivity and plant water use efficiency (WUE) are driving optimistic predictions of higher crop yields as well as greater availability of freshwater resources due to a decrease in evapotranspiration. The plant physiological response that drives these effects is believed to be an increase in carbon uptake either by (a) stronger CO2 gradient between the stomata and the atmosphere, or by (b) reduced CO2 limitation of enzymatic carboxylation within the leaf. The (a) scenario will lead to increased water use efficiency (WUE) in plants. However, evidence for increased WUE is mostly based on modeling studies, and experiments producing a short duration or step-wise increase in CO2 concentration (e.g. free-air CO2 enrichment). We hypothesize that the increase in atmospheric CO2 concentration is having a positive effect on ecosystem productivity and WUE. To investigate this hypothesis, we analyzed meteorological, ANPP, and soil CO2 flux datasets together with carbon isotopic ratio (13C/12C) of archived plant samples from the long term ecological research (LTER) program at Kellogg Biological Station. The datasets were collected between 1989 and 2007 (corresponding to an increase in atmospheric CO2 concentration of ~33 ppmv at Mauna Loa). Wheat (Triticum aestivum) samples taken from 1989 and 2007 show a significant decrease in the C isotope discrimination factor (Δ) over time. Stomatal conductance is directly related to Δ, and thus Δ is inversely related to plant intrinsic WUE (iWUE). Historical changes in the 13C/12C ratio (δ13C) in samples of a perennial forb, Canada goldenrod (Solidago canadensis), taken from adjacent successional fields, indicate changes in Δ upon uptake of CO2 as well. These temporal trends in Δ suggest a positive feedback between the increasing CO2 concentration in the

  14. CO2 Sink/Source in the Indonesian Seas

    KAUST Repository

    Kartadikaria, Aditya R.

    2015-04-01

    Two distinct CO2 sink/source characteristics appeared from the compiled observed data 1984-2013 in the tropical Indonesian seas. The western part persistently emits CO2 to the atmosphere, while the eastern is rather dynamic which emits and absorbs smaller amount of CO2 to and from atmosphere, respectively. The segregation is proximal to the virtual Wallace line, where in the continental shelf is located. Lower salinity and higher silicate condition in the western part influenced the higher pCO2 condition in Java Sea. Temperature is found to have a limited influence to control different characteristic in the west and east, but SST change of 2.0 0C during La Ninã condition effectively reduced the source amount of CO2 by 50% compared to Normal year condition. Yet, during La Ninã, higher wind speed increases CO2 flux twice compared to Normal year. In the continental shelf area where CO2 sink area is found, 29 years data showed that pCO2 trend is increasing ±0.6-3.8 μatm/year. From this study, the overall areas have a significant source of CO2 of approximately 10 - 24 μatm.

  15. Updating soil CO2 emission experiments to assess climate change effects and extracellular soil respiration

    Science.gov (United States)

    Vidal Vazquez, Eva; Paz Ferreiro, Jorge

    2014-05-01

    Experimental work is an essential component in training future soil scientists. Soil CO2 emission is a key issue because of the potential impacts of this process on the greenhouse effect. The amount of organic carbon stored in soils worldwide is about 1600 gigatons (Gt) compared to 750 Gt in the atmosphere mostly in the form of CO2. Thus, if soil respiration increased slightly so that just 10% of the soil carbon pool was converted to CO2, atmospheric CO2 concentrations in the atmosphere could increase by one-fifth. General circulation model predictions indicate atmosphere warming between 2 and 5°C (IPCC 2007) and precipitation changes ranging from about -15 to +30%. Traditionally, release of CO2 was thought to occur only in an intracellular environment; however, recently CO2 emissions have been in irradiated soil, in the absence of microorganisms (Maire et al., 2013). Moreover, soil plays a role in the stabilization of respiration enzymes promoting CO2 release after microorganism death. Here, we propose to improve CO2 emission experiments commonly used in soil biology to investigate: 1) effects of climatic factors on soil CO2 emissions, and 2) rates of extracellular respiration in soils and how these rates are affected by environmental factors. Experiment designed to assess the effect of climate change can be conducted either in field conditions under different ecosystems (forest, grassland, cropland) or in a greenhouse using simple soil chambers. The interactions of climate change in CO2 emissions are investigated using climate-manipulation experiment that can be adapted to field or greenhouse conditions (e.g. Mc Daniel et al., 2013). The experimental design includes a control plot (without soil temperature and rain manipulation) a warming treatment as well as wetting and/or drying treatments. Plots are warmed to the target temperature by procedures such as infrared heaters (field) or radiant cable (greenhouse). To analyze extracellular respiration, rates of CO2

  16. Direct Air Capture of CO2 with an Amine Resin: A Molecular Modeling Study of the CO2 Capturing Process.

    Science.gov (United States)

    Buijs, Wim; de Flart, Stijn

    2017-11-01

    Several reactions, known from other amine systems for CO2 capture, have been proposed for Lewatit R VP OC 1065. The aim of this molecular modeling study is to elucidate the CO2 capture process: the physisorption process prior to the CO2-capture and the reactions. Molecular modeling yields that the resin has a structure with benzyl amine groups on alternating positions in close vicinity of each other. Based on this structure, the preferred adsorption mode of CO2 and H2O was established. Next, using standard Density Functional Theory two catalytic reactions responsible for the actual CO2 capture were identified: direct amine and amine-H2O catalyzed formation of carbamic acid. The latter is a new type of catalysis. Other reactions are unlikely. Quantitative verification of the molecular modeling results with known experimental CO2 adsorption isotherms, applying a dual site Langmuir adsorption isotherm model, further supports all results of this molecular modeling study.

  17. Comparison of Surface and Column Variations of CO2 Over Urban Areas for Future Active Remote CO2 Sensors

    Science.gov (United States)

    Choi, Yonghoon; Yang, Melissa; Kooi, Susan; Browell, Edward

    2015-01-01

    High resolution in-situ CO2 measurements were recorded onboard the NASA P-3B during the DISCOVER-AQ (Deriving Information on Surface Conditions from Column and Vertically Resolved Observations Relevant to Air Quality) Field Campaign, to investigate the ability of space-based observations to accurately assess near surface conditions related to air quality. This campaign includes, Washington DC/Baltimore, MD (July 2011), San Joaquin Valley, CA (January - February 2013), Houston, TX (September 2013), and Denver, CO (July-August 2014). Each of these campaigns consisted of missed approaches and approximately two hundred vertical soundings of CO2 within the lower troposphere (surface to about 5 km). In this study, surface (0 - 1 km) and column-averaged (0 - 3.5 km) CO2 mixing ratio values from the vertical soundings in the four geographically different urban areas are used to investigate the temporal and spatial variability of CO2 within the different urban atmospheric emission environments. Tracers such as CO, CH2O, NOx, and NMHCs are used to identify the source of CO2 variations in the urban sites. Additionally, we apply nominal CO2 column weighting functions for potential future active remote CO2 sensors operating in the 1.57-microns and 2.05-microns measurement regions to convert the in situ CO2 vertical mixing ratio profiles to variations in CO2 column optical depths, which is what the active remote sensors actually measure. Using statistics calculated from the optical depths at each urban site measured during the DISCOVER-AQ field campaign and for each nominal weighting function, we investigate the natural variability of CO2 columns in the lower troposphere; relate the CO2 column variability to the urban surface emissions; and show the measurement requirements for the future ASCENDS (Active Sensing of CO2 Emissions over Nights, Days, and Seasons) in the continental U.S. urban areas.

  18. Selected Issues on CO2 in Compression Systems

    Energy Technology Data Exchange (ETDEWEB)

    Aarlien, R.

    2004-05-15

    Carbon Dioxide (CO2) has shown promising results as an alternative working fluid compared to the CFCs, HFCs and HCFCs. CO2 provides an environmental friendly alternative in a number of heat pump applications, in automobile air conditioning, and as a secondary fluid in refrigeration systems. The physical and the thermodynamic properties of CO2 differ considerably from the more conventional working fluids and offer new possibilities as well as design challenges for systems and components. On this background IEA Heat Pump Programme's Annex 27 was established. The main objective of the Annex has been to bring the CO2 heat pump technology closer to commercialization, by addressing critical issues of both basic and applied character. The scope of the work under this Annex includes compression heat pump, refrigeration and air-conditioning systems and components, with the main emphasis on heat pumps, using CO2 as working fluid. The term 'compression heat pump' covers vapor compression circuits with phase change. The term 'system' includes all the components used in a heating/cooling system from the heat pump to the inside unit, controls included. Results from 12 different research projects together with an extensive literature survey are presented. The projects are carried out as independent research projects, and the findings and the results are the sole responsibility of the authors. The following projects are presented: 1) Feasibility of transcritical CO2 systems for mobile space conditioning applications. 2) Use of CO2- and propane thermosyphons in combination with compact cooler in domestic freeze. 3) Heat transfer of carbon dioxide in an evaporator. 4) Correlating the heat transfer coefficient during in-tube cooling of turbulent supercritical CO2. 5) Heat transfer and pressure drop characteristics of super-critical CO2 in microchannel tubes under cooling. 6) Flow vaporization of CO2 in microchannel tubes. 7) Two-phase flow patterns during

  19. Chemical reactions occurring during direct solar reduction of CO2.

    Science.gov (United States)

    Lyma, J L; Jensen, R J

    2001-09-28

    At high temperatures carbon dioxide may absorb solar radiation and react to form carbon monoxide and molecular oxygen. The CO, so produced, may be converted by well-established means to a combustible fuel, such as methanol. We intend to make a future demonstration of the solar reduction of CO2 based on these processes. This paper, however, addresses only the problem of preserving, or even enhancing, the initial photolytic CO by quenching the hot gas with colder H2O or CO2. We present model calculations with a reaction mechanism used extensively in other calculations. If a CO2 gas stream is heated and photolyzed by intense solar radiation and then allowed to cool slowly, it will react back to the initial CO2 by a series of elementary chemical reactions. The back reaction to CO2 can be terminated with the rapid addition of CO2, water, or a mixture. Calculations show that a three-fold quench with pure CO2 will stop the reactions and preserve over 90% of the initial photolytic CO. We find that water has one of two effects. It can either increase the CO level, or it can catalyze the recombination of O and CO to CO2. The gas temperature is the determining factor. If the quench gas is not sufficient to keep the temperature below approximately 1100 K, a chain-branching reaction dominates and the reaction to CO2 occurs. If the temperature stays below that level a chain terminating reaction dominates and the CO is increased. The former case occurs below approximately a fourfold quench with a water/CO2 mixture. The later case occurs when the quench is greater than fourfold. We conclude that CO2, H2O, or a mixture may quench the hot gas stream photolyzed by solar radiation and preserve the photolytic CO.

  20. Crystal structures and dynamical properties of dense CO2

    Science.gov (United States)

    Yong, Xue; Liu, Hanyu; Wu, Min; Yao, Yansun; Tse, John S.; Dias, Ranga; Yoo, Choong-Shik

    2016-01-01

    Structural polymorphism in dense carbon dioxide (CO2) has attracted significant attention in high-pressure physics and chemistry for the past two decades. Here, we have performed high-pressure experiments and first-principles theoretical calculations to investigate the stability, structure, and dynamical properties of dense CO2. We found evidence that CO2-V with the 4-coordinated extended structure can be quenched to ambient pressure below 200 K—the melting temperature of CO2-I. CO2-V is a fully coordinated structure formed from a molecular solid at high pressure and recovered at ambient pressure. Apart from confirming the metastability of CO2-V (I-42d) at ambient pressure at low temperature, results of ab initio molecular dynamics and metadynamics (MD) simulations provided insights into the transformation processes and structural relationship from the molecular to the extended phases. In addition, the simulation also predicted a phase V′(Pna21) in the stability region of CO2-V with a diffraction pattern similar to that previously assigned to the CO2-V (P212121) structure. Both CO2-V and -V′ are predicted to be recoverable and hard with a Vicker hardness of ∼20 GPa. Significantly, MD simulations found that the CO2 in phase IV exhibits large-amplitude bending motions at finite temperatures and high pressures. This finding helps to explain the discrepancy between earlier predicted static structures and experiments. MD simulations clearly indicate temperature effects are critical to understanding the high-pressure behaviors of dense CO2 structures—highlighting the significance of chemical kinetics associated with the transformations. PMID:27647887

  1. Carbon-14 based biomass fraction detection in power plant flue gas CO2: validation and results

    Science.gov (United States)

    Palstra, S. W. L.; Meijer, H. A. J.

    2009-04-01

    Replacing non-renewable fossil fuels by renewable fuels like biomass-based ones is one of the tools to combat increasing atmospheric CO2 concentrations. In order to promote biofuel-based electricity generation, a tool must be available to reliably quantify the bio-based CO2 fraction in the flue gas of a power plant. For traditional power plants, such as coal-fired ones to which wood is added, the calculation can be performed -albeit with considerable uncertainty- based on the weight and substance of the fuels. For e.g. waste incineration plants, however, such an approach is virtually impossible. The carbon-14 method (also called radiocarbon or 14C) is the most direct, and therefore most powerful method to discriminate fossil from bio-mass CO2, as fossil fuel CO2 is virtually 14C-free, while biomass CO2 contains the present-day "natural" amount of 14C. Therefore, the carbon-14 we measure in a CO2 sample can be directly related to the fraction of biomass carbon in the specific sample. The carbon-14 method is such is well established, and routinely applied in an appreciable number of laboratories world-wide. The project we conducted, in co-operation with the electricity generation company Essent, had two goals: (1) To demonstrate the applicability of the carbon-14 method, and to validate its result for the biomass fraction against fuel-based data and (2)To use the method for a waste incineration plant. All 14C-determinations have been performed in our laboratory, using our Accelerator Mass Spectrometer (AMS) facility. At the coal- and wood-fired "Amercentrale" we measured biomass CO2 rates to be just above 10% on the first sampling day and 5% on the second sampling day. The results for both days compared very well to those based on fuel input data. The 14C-based data, however, are potentially more accurate. Subsequently, we determined the biomass fraction of the waste incineration plant "Moerdijk" to be on average 50.3 ± 1.5% during the sampling period (in total 10

  2. Continuous monitoring of diffuse CO2 degassing at Taal volcano, Philippines

    Science.gov (United States)

    Padron, E.; Hernandez Perez, P. A.; Arcilla, C. A.; Lagmay, A. M. A.; Perez, N. M.; Quina, G.; Padilla, G.; Barrancos, J.; Cótchico, M. A.; Melián, G.

    2016-12-01

    Observing changes in the composition and discharge rates of volcanic gases is an important part of volcanic monitoring programs, because some gases released by progressive depressurization of magma during ascent are highly mobile and reach the surface well before their parental magma. Among volcanic gases, CO2 is widely used in volcano studies and monitoring because it is one of the earliest released gas species from ascending magma, and it is considered conservative. Taal Volcano in Southwest Luzon, Philippines, lies between a volcanic arc front (facing the subduction zone along the Manila Trench) and a volcanic field formed from extension beyond the arc front. Taal Volcano Island is formed by a main tuff cone surrounded by several smaller tuff cones, tuff rings and scoria cones. This island is located in the center of the 30 km wide Taal Caldera, now filled by Taal Lake. To monitor the volcanic activity of Taal volcano is a priority task in the Philippines, because several million people live within a 20-km radius of Taal's caldera rim. In the period from 2010-2011, during a period of volcanic unrest, the main crater lake of Taal volcano released the highest diffuse CO2 emission rates reported to date by volcanic lakes worldwide. The maximum CO2 emission rate measured in the study period occurred two months before the strongest seismic activity recorded during the unrest period (Arpa et al., 2013, Bull Volcanol 75:747). In the light of the excellent results obtained through diffuse degassing studies, an automatic geochemical station to monitor in a continuous mode the diffuse CO2 degassing in a selected location of Taal, was installed in January 2016 to improve the early warning system at the volcano. The station is located at Daang Kastila, at the northern portion of the main crater rim. It measures hourly the diffuse CO2 efflux, atmospheric CO2 concentration, soil water content and temperature, wind speed and direction, air temperature and humidity, rainfall

  3. Identification of Robust Models for co2 xcEhange at Canopy Scale

    Science.gov (United States)

    Horn, J.; Schulz, K.

    2008-12-01

    Nonstationary and nonlinear dynamic time series analysis tools are applied to numerous sites and years of eddy covariance and meteorological measurements provided by the worldwide network FLUXNET with the intention to identify robust models for the CO2 exchange at canopy scale. The analysis tools based on Kalman filtering and smoothing techniques help to extract the dominant behaviour of daily gross photosynthesis and respiration in relation to their principally modulating drivers. Based on these findings semi-parametric models are formulated and optimized against over one hundred FLUXNET site-years. The only input variables are soil temperature, insolation and precipitation or evaporative fraction as moisture availability measure. The resulting well-defined parameters are analyzed for patterns that relate the parameters to site characteristics as vegetation and climate class. Despite their simplicity the retrieved model structures fit the measured data well and provide reliable annual CO2 budgets for forests and grasslands.

  4. A sulfur hexafluoride sensor using quantum cascade and CO2 laser-based photoacoustic spectroscopy.

    Science.gov (United States)

    Rocha, Mila; Sthel, Marcelo; Lima, Guilherme; da Silva, Marcelo; Schramm, Delson; Miklós, András; Vargas, Helion

    2010-01-01

    The increase in greenhouse gas emissions is a serious environmental problem and has stimulated the scientific community to pay attention to the need for detection and monitoring of gases released into the atmosphere. In this regard, the development of sensitive and selective gas sensors has been the subject of several research programs. An important greenhouse gas is sulphur hexafluoride, an almost non-reactive gas widely employed in industrial processes worldwide. Indeed it is estimated that it has a radiative forcing of 0.52 W/m(2). This work compares two photoacoustic spectrometers, one coupled to a CO(2) laser and another one coupled to a Quantum Cascade (QC) laser, for the detection of SF(6). The laser photoacoustic spectrometers described in this work have been developed for gas detection at small concentrations. Detection limits of 20 ppbv for CO(2) laser and 50 ppbv for quantum cascade laser were obtained.

  5. A Review of the Role of Vegetal Ecosystems in CO2 Capture

    Directory of Open Access Journals (Sweden)

    Giuseppe Di Vita

    2017-10-01

    Full Text Available The reduction of carbon emissions is a worldwide global challenge and represents the objective of many scientists that are trying to modify the role of carbon, turning a problem into an opportunity. The potential of CO2 capture and storage by vegetal species is significant because of their capacity to absorb exceeding carbon emission. The purpose of the present paper is to draw a picture of the role of vegetal ecosystems on carbon fixation by identifying the most significant scientific contributions related to the absorption by vegetal species. In particular the aim of this paper is to examine different forms of CO2 sequestration made by plants and crops involved in reducing greenhouse gas (GHG emission. Results highlight the important role played by agricultural soils, forests, perennial plants, and algae, looking at the overall reduction of carbon emissions. In addition, results show that some bioenergy crops allow substantial storage of carbon dioxide, providing a significant contribution to climate change mitigation.

  6. Disinformation squared: was the HIV-from-Fort-Detrick myth a Stasi success?

    Science.gov (United States)

    Geissler, Erhard; Sprinkle, Robert Hunt

    2013-01-01

    When in May 1983 the acquired immunodeficiency syndrome (AIDS) was first securely attributed to a virus, eventually called the human immunodeficiency virus (HIV), many controversies arose. Among these was one centering on HIV's origin. A startling hypothesis, called here the "HIV-from-Fort-Detrick myth," asserted that HIV had been a product, accidental or intentional, of bioweaponry research. While its earliest identifiable contributors were in the West, this myth's most dynamic propagators were in the East. The Soviet security service, the KGB, took "active measures" to create and disseminate AIDS disinformation beginning no later than July 1983 and ending no earlier than October 1987. The East German security service, a complex bureaucracy popularly known as "the Stasi," was involved, too, but how early, how deeply, how uniformly, how ably, and how successfully has not been clear. Following German reunification, claims arose attributing to the Stasi the masterful execution of ingenious elements in a disinformation campaign they helped shape and soon came to dominate. We have tested these claims. Was the HIV-from-Fort-Detrick myth a Stasi success? Primary sources were documents and photographs assembled by the Ministry of State Security (MfS) of the German Democratic Republic (GDR or East Germany), the Ministry of Interior of the People's Republic of Bulgaria, and the United States Department of State; the estate of myth principals Jakob and Lilli Segal; the "AIDS box" in the estate of East German literary figure Stefan Heym; participant-observer recollections, interviews, and correspondence; and expert interviews. We examined secondary sources in light of primary sources. The HIV-from-Fort-Detrick myth had debuted in print in India in 1983 and had been described in publications worldwide prior to 1986, the earliest year for which we found any Stasi document mentioning the myth in any context. Many of the myth's exponents were seemingly independent conspiracy

  7. Simulasi Numeris Karakteristik Pembakaran CH4/CO2/Udara dan CH4/CO2/O2 pada Counterflow Premixed Burner

    Directory of Open Access Journals (Sweden)

    Hangga Wicaksono

    2017-08-01

    Full Text Available The high amount of CO2 produced in a conventional biogas reactor needs to be considered. A further analysis is needed in order to investigate the effect of CO2 addition especially in thermal and chemical kinetics aspect. This numerical study has been held to analyze the effect of CO2 in CH4/CO2/O­2 and CH4/CO2/Air premixed combustion. In this study one dimensional analisys in a counterflow burner has been performed. The volume fraction of CO2 used in this study was 0%-40% from CH4’s volume fraction, according to the amount of CO2 in general phenomenon. Based on the flammability limits data, the volume fraction of CH4 used was 5-61% in O2 environment and 5-15% in air environment. The results showed a decreasing temperature along with the increasing percentage of CO2 in each mixtures, but the effect was quite smaller especially in stoichiometric and lean mixture. CO2 could affects thermally (by absorbing heat due to its high Cp and also made the production of unburnt fuel species such as CO relatively higher.

  8. CO2 footprint 2008 District Oud-Zuid, Amsterdam, Netherlands; CO2-voetafdruk 2008 Stadsdeel Oud-Zuid [Amsterdam

    Energy Technology Data Exchange (ETDEWEB)

    Hanekamp, E.; Van Merksteijn, C. [Partners for Innovation, Amsterdam (Netherlands)

    2009-06-15

    The district 'Oud-Zuid' in Amsterdam, Netherlands, plans to become CO2 neutral in 2015. For this purpose, the CO2 footprint of the district is determined and a plan of action developed. By means of scenarios, the district council can make choices for climate investments [Dutch] Stadsdeel Oud-Zuid van de gemeente Amsterdam wil CO2-neutraal zijn in 2015. Daartoe is de CO2-voetafdruk van Oud-Zuid bepaald en een plan van aanpak uitgewerkt. Met behulp van scenario's zal de stadsdeelraad keuzes kunnen maken over haar klimaatinvesteringen.

  9. Influence of travel behavior on global CO2 emissions

    NARCIS (Netherlands)

    Girod, B.; Vuuren, D.P. van; Vries, B. de

    2013-01-01

    Travel demand is rising steeply and its contribution to global CO2 emissions is increasing. Different studies have shown possible mitigation through technological options, but so far few studies have evaluated the implications of changing travel behavior on global travel demand, energy use and CO2

  10. Mechanochemical synthesis and characterization of pure Co2B ...

    Indian Academy of Sciences (India)

    Cobalt boride (Co 2 B) is a significant transition metal boride having a wide range of usage area due to its high oxidation, abrasion and corrosion resistance as well as its superior electrochemical, magnetic and anisotropicproperties. In this study, pure Co2B nanocrystals were synthesized with Co, B 2 O 3 and Mg as starting ...

  11. Selective Electrocatalytic CO2 Conversion on Metal Surfaces

    NARCIS (Netherlands)

    Ma, M.

    2017-01-01

    The electrocatalytic conversion of CO2 into fuel and valuable chemicals by coupling with a renewable electricity source is a promising strategy for closing the anthropogenic carbon cycle. The critical step for achieving this practical CO2 utilization is to find a suitable electrocatalyst that is

  12. CO2 sorption by supported amino acid ionic liquids

    DEFF Research Database (Denmark)

    2014-01-01

    The present invention concerns the absorption and desorption behaviour of carbon dioxide (CO2) using ionic liquids derived from amino acids adsorbed on porous carrier materials.......The present invention concerns the absorption and desorption behaviour of carbon dioxide (CO2) using ionic liquids derived from amino acids adsorbed on porous carrier materials....

  13. CO2 emissions from soil incubated with sugarcane straw and ...

    African Journals Online (AJOL)

    SAM

    2014-08-13

    CO2 until the 79th. DAI) and initial accumulated respiration (Σ-CO2 until the 5th DAI). Analytical procedures. At the 80th DAI, the incubated soils were sieved (2 mm opening) to remove the remaining crop residue from the soil.

  14. AMESCO General Study Environmental Impacts CO2-storage. Public summary

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2007-07-15

    The AMESCO study aims to supply environmental background information on CO2-storage in the Netherlands for the broad group of initiators and other stakeholders. By bringing together the information from the scientific world, companies and authorities and by analysing relevant policies it is intended to eludicate: which are the possible environmental effects of CO2-injection and storage; which are the possibilities for risk reduction or mitigation; which existing legislation is of relevance for CO2-storage in the deep surface; where are the gaps in knowledge and legislation with regard to CO2-storage. The report produced during the AMESCO study should be seen as a broad answer to the four questions mentioned above. In specific projects the report can be used as a background document during permitting procedures. This background information has to be supplemented with location specific information. The report can also be used as input for an environmental impact assessment (EIA). For practical reasons the AMESCO study was performed with the following scope limitations: (1) Focus on potential impacts and risks resulting from the storage of CO2; (2) Only consider CO2-storage in gas reservoirs; (3) Only consider onshore projects; (4) Only consider permanent storage; (5) Consider alternative options for CO2-storage in gas reservoirs; but not other forms of CO2-emission reduction. The scope is limited to depleted gas fields, from which the economically recoverable resources have already been taken.

  15. New methodologies for integrating algae with CO2 capture

    NARCIS (Netherlands)

    Hernandez Mireles, I.; Stel, R.W. van der; Goetheer, E.L.V.

    2014-01-01

    It is generally recognized, that algae could be an interesting option for reducing CO2 emissions. Based on light and CO2, algae can be used for the production various economically interesting products. Current algae cultivation techniques, however, still present a number of limitations. Efficient

  16. Costs, safety and uncertainties of CO2 infrastructure development

    NARCIS (Netherlands)

    Knoope, M.M.J.|info:eu-repo/dai/nl/364248149

    2015-01-01

    To avoid drastic climate change, strong reductions in CO2 emissions are required. Carbon capture and storage (CCS) is a potential mitigation measure. With CCS, CO2 from industrial and energy related sources is captured from flue gases and subsequently transported with pipelines and / or ships to

  17. CO2-Philic polymer membrane with extremely high separation performance

    KAUST Repository

    Yave, Wilfredo

    2010-01-12

    Polymeric membranes are attractive for CO2 separation and concentration from different gas streams because of their versatility and energy efficiency; they can compete with, and they may even replace, traditional absorption processes. Here we describe a simple and powerful method for developing nanostructured and CO2-philic polymer membranes for CO2 separation. A poly(ethylene oxide)-poly(butylene terephthalate) multiblock copolymer is used as membrane material. Smart additives such as polyethylene glycol dibutyl ether are incorporated as spacers or fillers for producing nanostructured materials. The addition of these specific additives produces CO2-philic membranes and increases the CO2 permeability (750 barrer) up to five-fold without the loss of selectivity. The membranes present outstanding performance for CO2 separation, and the measured CO2 flux is extremely high ( > 2 m3 m -2 h-1 bar-1) with selectivity over H2 and N2 of 10 and 40, respectively, making them attractive for CO 2 capture. © 2009 American Chemical Society.

  18. CO2 dissolution and its impact on reservoir pressure behavior

    NARCIS (Netherlands)

    Peters, E.; Egberts, P.J.P.; Loeve, D.; Hofstee, C.

    2015-01-01

    Geological storage of CO2 in large, saline aquifers needs to be monitored for safety purposes. In particular the observation of the pressure behavior of a storage site is relevant for the indication of CO2 leakage. However, interpretation of observed pressure is not straightforward in these systems,

  19. A Quantitative Investigation of CO2 Sequestration by Mineral Carbonation

    CERN Document Server

    Mohammad, Muneer

    2015-01-01

    Anthropogenic activities have led to a substantial increase in carbon dioxide (CO2), a greenhouse gas (GHG), contributing to heightened concerns of global warming. In the last decade alone CO2 emissions increased by 2.0 ppm/yr. globally. In the year 2009, United States and China contributed up to 43.4% of global CO2 emissions. CO2 capture and sequestration have been recognized as promising solutions to mitigate CO2 emissions from fossil fuel based power plants. Typical techniques for carbon capture include post-combustion capture, pre-combustion capture and oxy-combustion capture, which are under active research globally. Mineral carbonation has been investigated as a suitable technique for long term storage of CO2. Sequestration is a highly energy intensive process and the additional energy is typically supplied by the power plant itself. This leads to a reduction in net amount of CO2 captured because of extra CO2 emitted. This paper presents a quantitative analysis of the energy consumption during sequestra...

  20. Target atmospheric CO2: Where should humanity aim?

    CERN Document Server

    Hansen, J; Kharecha, P; Beerling, D; Masson-Delmotte, V; Pagani, M; Raymo, M; Royer, D L; Zachos, J C

    2008-01-01

    Paleoclimate data show that climate sensitivity is ~3 deg-C for doubled CO2, including only fast feedback processes. Equilibrium sensitivity, including slower surface albedo feedbacks, is ~6 deg-C for doubled CO2 for the range of climate states between glacial conditions and ice-free Antarctica. Decreasing CO2 was the main cause of a cooling trend that began 50 million years ago, large scale glaciation occurring when CO2 fell to 425 +/- 75 ppm, a level that will be exceeded within decades, barring prompt policy changes. If humanity wishes to preserve a planet similar to that on which civilization developed and to which life on Earth is adapted, paleoclimate evidence and ongoing climate change suggest that CO2 will need to be reduced from its current 385 ppm to at most 350 ppm. The largest uncertainty in the target arises from possible changes of non-CO2 forcings. An initial 350 ppm CO2 target may be achievable by phasing out coal use except where CO2 is captured and adopting agricultural and forestry practice...

  1. CO2-emissiehandel in 2020 : betekenis voor de Nederlandse glastuinbouw

    NARCIS (Netherlands)

    Bunte, F.H.J.; Dijkxhoorn, Y.

    2009-01-01

    Het rapport bepaalt de impact van de EU-richtlijn voor de handel in CO2-emissierechten voor de Nederlandse glastuinbouw. Het rapport berekent de kosten die de richtlijn met zich meebrengt voor de sector en bepaalt het effect op de CO2- uitstoot door de sector. Verder bepaalt het rapport het effect

  2. CO2 as a smart gelator for Pluronic aqueous solutions.

    Science.gov (United States)

    Liu, Chengcheng; Mei, Qingqing; Zhang, Jianling; Kang, Xinchen; Peng, Li; Han, Buxing; Xue, Zhimin; Sang, Xinxin; Yang, Xiaogan; Wu, Zhonghua; Li, Zhihong; Mo, Guang

    2014-11-25

    It was found that CO2 could induce the gelation of Pluronic aqueous solutions, during which the microstructure of the solution transforms from randomly dispersed spherical micelles to cubic close packed micelles. The gelation switched by compressed CO2 has many advantages and can be applied in the synthesis of porous materials.

  3. Resolving CO2 and methane hydrate formation kinetics

    NARCIS (Netherlands)

    Golombok, M.; Ineke, E.; Luzardo, J.C.R.; He, Y.Y.; Zitha, P.

    2008-01-01

    We analyse the kinetics of CO2 and methane hydrate formation. The characteristic formation times are associated with different steps of the formation process. Conditions for minimising these rate times are identified while maintaining a regime where CO2 hydrate is formed and methane remains

  4. Vesicularity and CO2 in mid-ocean ridge basalt

    Science.gov (United States)

    Moore, J.G.

    1979-01-01

    Vesicles and included CO2are enriched in deep-sea basalts that are also enriched in light rare earth and incompatible elements. This enrichment probably results from a unique deep mantle origin of such melts but may have been modified by CO2 bubbles rising in shallow magma chambers. ?? 1979 Nature Publishing Group.

  5. Geothermal energy combined with CO2 sequestration : An additional benefit

    NARCIS (Netherlands)

    Salimi, H.; Wolf, K.H.A.A.; Bruining, J.

    2012-01-01

    In this transition period from a fossil-fuel based society to a sustainable-energy society, it is expected that CO2 capture and subsequent sequestration in geological formations plays a major role in reducing greenhouse gas emissions. An alternative for CO2 emission reduction is to partially replace

  6. Adsorption and Dissociation of CO2 on Ru

    NARCIS (Netherlands)

    Pachecka, Malgorzata; Sturm, Jacobus Marinus; Lee, Christopher James; Bijkerk, Frederik

    2017-01-01

    The adsorption and dissociation of carbon dioxide on a Ru(0001) single crystal surface was investigated by reflection–absorption infrared spectroscopy (RAIRS) and temperature-programmed desorption (TPD) spectroscopy for CO2 adsorbed at 85 K. RAIRS spectroscopy shows that the adsorption of CO2 on a

  7. Fractional CO2 laser resurfacing for atrophic acne scars

    DEFF Research Database (Denmark)

    Hedelund, Lene; Haak, Christina Skovbølling; Togsverd-Bo, Katrine

    2012-01-01

    The treatment of acne scars with fractional CO(2) lasers is gaining increasing impact, but has so far not been compared side-by-side to untreated control skin.......The treatment of acne scars with fractional CO(2) lasers is gaining increasing impact, but has so far not been compared side-by-side to untreated control skin....

  8. Extra CO2 kan nuttig zijn bij snij-anthurium

    NARCIS (Netherlands)

    Garcia Victoria, N.

    2011-01-01

    Bij de snij-anthurium Midori zijn in een proef van WUR Glastuinbouw 10% meer bloemen geoogst door extra CO2 toe te dienen. Tropical reageerde met grotere bloemdiameters. Grotere bloemen brengen meestal meer op. Extra CO2 is dus voor deze cultivars economisch interessant.

  9. A role for atmospheric CO2 in preindustrial climate forcing

    NARCIS (Netherlands)

    Hoof, T.B. van; Wagner-Cremer, F.; Kürschner, W.M.; Visscher, H.

    2008-01-01

    Complementary to measurements in Antarctic ice cores, stomatal frequency analysis of leaves of land plants preserved in peat and lake deposits can provide a proxy record of preindustrial atmospheric CO2 concentration. CO2 trends based on leaf remains of Quercus robur (English oak) from the

  10. Transient nature of CO2 fertilization in arctic tundra

    Science.gov (United States)

    Walter C. Oechel; Sid Cowles; Nancy Grulke; Steven J. Hastings; Bill Lawrence; Tom Prudhomme; George Riechers; Boyd Strain; David Tissue; George. Vourlitis

    1994-01-01

    There has been much debate about the effect of increased atmospheric CO2 concentrations on plant net primary production1,3 and on net ecosystem CO2 flux3–10. Apparently conflicting experimental findings could be the result of differences in genetic potential11–15...

  11. Ni–Fe–S Cubanes in CO2 Reduction Electrocatalysis

    DEFF Research Database (Denmark)

    Varley, J. B.; Hansen, H. A.; Ammitzbøll, Nadia Luciw

    2013-01-01

    In this work, we perform extensive mechanistic studies of CO2 (electro)reduction by analogs to the active sites of carbon monoxide dehydrogenase (CODH) enzymes. We explore structure–property relationships for different cluster compositions and interpret the results with a model for CO2...

  12. Hydrogel-based sensor for CO2 measurements

    NARCIS (Netherlands)

    Herber, S.; Olthuis, Wouter; Bergveld, Piet; van den Berg, Albert

    2004-01-01

    A hydrogel-based sensor is presented for CO2 measurements. The sensor consists of a pressure sensor and porous silicon cover. A pH-sensitive hydrogel is confined between the two parts. Furthermore the porous cover contains a bicarbonate solution and a gaspermeable membrane. CO2 reacts with the

  13. Aquaporins and membrane diffusion of CO2 in living organisms.

    Science.gov (United States)

    Kaldenhoff, Ralf; Kai, Lei; Uehlein, Norbert

    2014-05-01

    Determination of CO2 diffusion rates in living cells revealed inconsistencies with existing models about the mechanisms of membrane gas transport. Mainly, these discrepancies exist in the determined CO2 diffusion rates of bio-membranes, which were orders of magnitudes below those for pure lipid bilayers or theoretical considerations as well as in the observation that membrane insertion of specific aquaporins was rescuing high CO2 transport rates. This effect was confirmed by functional aquaporin protein analysis in heterologous expression systems as well as in bacteria, plants and partly in mammals. This review summarizes the arguments in favor of and against aquaporin facilitated membrane diffusion of CO2 and reports about its importance for the physiology of living organisms. Most likely, the aquaporin tetramer forming an additional fifth pore is required for CO2 diffusion facilitation. Aquaporin tetramer formation, membrane integration and disintegration could provide a mechanism for regulation of cellular CO2 exchange. The physiological importance of aquaporin mediated CO2 membrane diffusion could be shown for plants and cyanobacteria and partly for mammals. Taking the mentioned results into account, consequences for our current picture of cell membrane transport emerge. It appears that in some or many instances, membranes might not be as permeable as it was suggested by current bio-membrane models, opening an additional way of controlling the cellular influx or efflux of volatile substances like CO2. This article is part of a Special Issue entitled Aquaporins. © 2013.

  14. A 10 cm aperture, high quality TEA CO2 laser

    NARCIS (Netherlands)

    Ernst, G.J.

    1982-01-01

    Experiments have been performed on a corona preionization type 10 cm aperture TEA CO2 laser. For a CO2:N2:He=1: 1: 7: mixture an output energy of 34 joule per liter and for a 1 : 1 : 10 mixture 40 joule per liter could be obtained. The overall efficiency is about 18%. The time behaviour of the

  15. CO2 absorption characteristics of monoethanol amine aqueous solution and recovery of CO2 from marine engine exhaust; Monoethanol amine suiyoeki no CO2 kyushu tokusei to hakuyo kikan no CO2 kaishu

    Energy Technology Data Exchange (ETDEWEB)

    Ikame, M.; Suga, S.; Hiraoka, K.; Kumakura, T. [Ship Research Inst., Tokyo (Japan)

    1994-04-13

    Investigations were made on characteristics of CO2 absorption into monoethanol amine aqueous solution under normal pressure as a method of recovering CO2, the CO2 concentration and effect of the accompanying gases. Furthermore, assuming a large marine diesel engine using methanol as a fuel, the experimental result was used to discuss a size of the CO2 absorbing device. Assuming exhaust gases from a methanol-fueled diesel engine and steam reformed gas of methanol, from which CO2 is to be recovered, the experiment used two kinds of accompanying gases, N2 and H2, and the CO2 concentrations of 5% to 25% by volume. The relationship between the CO2 material balance and the substance movement between gas and liquid based on the double boundary film theory was put into order to derive an experiment equation. This equation was capable of expression with an error of less than {plus_minus}35%. This paper indicates by using the experimental result a method to derive the size of an absorbing and filling layer for CO2 in exhaust gases from a methanol fueled marine diesel engine. Given an example, the volume of the filling layer in the absorption column is required to be about 12% of the engine volume of 770m{sup 3}, and the absorption flow rate to be 65.4kg/s. 4 refs., 6 figs., 1 tab.

  16. Tuning of CO2 Reduction Selectivity on Metal Electrocatalysts.

    Science.gov (United States)

    Wang, Yuhang; Liu, Junlang; Wang, Yifei; Al-Enizi, Abdullah M; Zheng, Gengfeng

    2017-11-01

    Climate change, caused by heavy CO2 emissions, is driving new demands to alleviate the rising concentration of atmospheric CO2 levels. Enlightened by the photosynthesis of green plants, photo(electro)chemical catalysis of CO2 reduction, also known as artificial photosynthesis, is emerged as a promising candidate to address these demands and is widely investigated during the past decade. Among various artificial photosynthetic systems, solar-driven electrochemical CO2 reduction is widely recognized to possess high efficiencies and potentials for practical application. The efficient and selective electroreduction of CO2 is the key to the overall solar-to-chemical efficiency of artificial photosynthesis. Recent studies show that various metallic materials possess the capability to play as electrocatalysts for CO2 reduction. In order to achieve high selectivity for CO2 reduction products, various efforts are made including studies on electrolytes, crystal facets, oxide-derived catalysts, electronic and geometric structures, nanostructures, and mesoscale phenomena. In this Review, these methods for tuning the selectivity of CO2 electrochemical reduction of metallic catalysts are summarized. The challenges and perspectives in this field are also discussed. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  17. CO2 reduction strategies for the Northern Netherlands

    NARCIS (Netherlands)

    Benders, Rene; Moll, Henk; Noorman, Klaas Jan; Wiersma, Gerwin

    2011-01-01

    The concern about global warming initiated ambitious CO2 reduction goals in cities and regions in the Netherlands. This article describes a study of such a local initiative for the Northern Netherlands. The research aimed to develop CO2 reduction scenarios for 2035 with national and international

  18. Enhanced cerebral CO2 reactivity during strenuous exercise in man

    DEFF Research Database (Denmark)

    Rasmussen, Peter; Stie, Henrik; Nielsen, Bodil

    2006-01-01

    subjects by the administration of CO(2) as well as by voluntary hypo- and hyperventilation at rest and during exercise with and without hyperthermia. At rest, P(a)CO(2) was 5.1 +/- 0.2 kPa (mean +/- SEM) and MCA V(mean) 50.7 +/- 3.8 cm s(-1) and the relationship between MCA V(mean) and P(a)CO(2 )was linear...... (double-log slope 1.1 +/- 0.1). However, the relationship became curvilinear during exercise (slope 1.8 +/- 0.1; P exercise with hyperthermia (slope 2.3 +/- 0.3; P exercise). Accordingly, the cerebral CO(2) reactivity increased from 30.5 +/- 2.7% kPa(-1...... be accounted for by the reduction in the arterial CO(2) tension (P(a)CO(2)). This study evaluated whether the apparently large reduction in MCA V(mean) at the end of exhaustive exercise relates to an enhanced cerebrovascular CO(2) reactivity. The CO(2) reactivity was evaluated in six young healthy male...

  19. Autotrophic and heterotrophic soil respiration determined with trenching, soil CO2 fluxes and 13CO2/12CO2 concentration gradients in a boreal forest ecosystem

    Science.gov (United States)

    Pumpanen, Jukka; Shurpali, Narasinha; Kulmala, Liisa; Kolari, Pasi; Heinonsalo, Jussi

    2017-04-01

    Soil CO2 efflux forms a substantial part of the ecosystem carbon balance, and it can contribute more than half of the annual ecosystem respiration. Recently assimilated carbon which has been fixed in photosynthesis during the previous days plays an important role in soil CO2 efflux, and its contribution is seasonally variable. Moreover, the recently assimilated C has been shown to stimulate the decomposition of recalcitrant C in soil and increase the mineralization of nitrogen, the most important macronutrient limiting gross primary productivity (GPP) in boreal ecosystems. Podzolic soils, typical in boreal zone, have distinctive layers with different biological and chemical properties. The biological activity in different soil layers has large seasonal variation due to vertical gradient in temperature, soil organic matter and root biomass. Thus, the source of CO2 and its components have a vertical gradient which is seasonally variable. The contribution of recently assimilated C and its seasonal as well as spatial variation in soil are difficult to assess without disturbing the system. The most common method of partitioning soil respiration into its components is trenching which entails the roots being cut or girdling where the flow of carbohydrates from the canopy to roots has been isolated by cutting of the phloem. Other methods for determining the contribution of autotrophic (Ra) and heterotrophic (Rh) respiration components in soil CO2 efflux are pulse labelling with 13CO2 or 14CO2 or the natural abundance of 13C and/or 14C isotopes. Also differences in seasonal and short-term temperature response of soil respiration have been used to separate Ra and Rh. We compared the seasonal variation in Ra and Rh using the trenching method and differences between seasonal and short-term temperature responses of soil respiration. I addition, we estimated the vertical variation in soil biological activity using soil CO2 concentration and the natural abundance of 13C and 12C

  20. Natural CO2 Releases Providing Messages For Stakeholders

    Science.gov (United States)

    Dixon, T.; Romanak, K.; Camps, A. P.

    2011-12-01

    Stakeholder viewpoints and beliefs about geologic carbon storage are not always accurate, yet they may affect the future of carbon capture and storage (CCS). Gaps in stakeholder understanding and perspectives must be addressed, and natural systems that release CO2 can be valuable tools for communicating difficult scientific concepts because they provide tangible examples of geologic principles at work. Stakeholder perceptions commonly involve a misunderstanding of geologic scale and mechanisms, and can be charged with emotions fueled by media coverage of natural disasters. One example of an event widely cited by stakeholders is the CO2 release at Lake Nyos in Cameroon in August 1986 that killed 1700 people. This event is commonly thought by stakeholders to be an analogue for a release from a CO2 storage site; however, this release occurred under a rare combination of circumstances (a 208-m-deep volcanic crater lake) not analogous to an engineered CO2 storage site. Stakeholders therefore gravitate towards natural systems to form concepts and opinions of how CO2 might behave in a geological environment, but they often choose systems that are not true analogues but that gain attention through the media because they are associated with a disaster. When chosen correctly, natural releases of CO2 may create a level of clarity for stakeholders by providing tangible concrete examples that explain difficult scientific principles and provide familiar reference points to adapt different viewpoints. We present suggestions and examples presented by scientists at an IEAGHG Workshop Natural Releases of CO2: Building Knowledge for CO2 Storage Environmental Impact Assessments', held at Maria Laach, Germany, November 2010 which brought together researchers from the EU, North America, Japan, and Australia. It also included field observations of natural CO2 releases around the Laacher See caldera lake, CO2 springs, and the Wallenborn CO2 geyser. New information from international

  1. Achieving Negative CO2 Emissions by Protecting Ocean Chemistry

    Science.gov (United States)

    Cannara, A.

    2016-12-01

    Industrial Age CO2 added 1.8 trillion tons to the atmosphere. About ¼ has dissolved in seas. The rest still dissolves, bolstered by present emissions of >30 gigatons/year. Airborne & oceanic CO2 have induced sea warming & ocean acidification*. This paper suggests a way to induce a negative CO2-emissions environment for climate & oceans - preserve the planet`s dominant CO2-sequestration system ( 1 gigaton/year via calcifying sea life**) by promptly protecting ocean chemistry via expansion of clean power for both lime production & replacement of CO2-emitting sources. Provide natural alkali (CaO, MgO…) to oceans to maintain average pH above 8.0, as indicated by marine biologists. That alkali (lime) is available from past calcifying life's limestone deposits, so can be returned safely to seas once its CO2 is removed & permanently sequestered (Carbfix, BSCP, etc.***). Limestone is a dense source of CO2 - efficient processing per mole sequestered. Distribution of enough lime is possible via cargo-ship transits - 10,000 tons lime/transit, 1 million transits/year. New Panamax ships carry 120,000 tons. Just 10,000/transit allows gradual reduction of present & past CO2 emissions effects, if coupled with combustion-power reductions. CO2 separation from limestone, as in cement plants, consumes 400kWHrs of thermal energy per ton of output lime (or CO2). To combat yearly CO2 dissolution in seas, we must produce & distribute about 10gigatons of lime/year. Only nuclear power produces the clean energy (thousands of terawatt hours) to meet this need - 1000 dedicated 1GWe reactors, processing 12 cubic miles of limestone/year & sequestering CO2 into a similar mass of basalt. Basalt is common in the world. Researchers*** report it provides good, mineralized CO2 sequestration. The numbers above allow gradual CO2 reduction in air and seas, if we return to President Kennedy's energy path: http://tinyurl.com/6xgpkfa We're on an environmental precipice due to failure to eliminate

  2. Liberation of microbial substrates from macromolecular organic matter by non-supercritical CO2

    Science.gov (United States)

    Sauer, P.; Glombitza, C.; Kallmeyer, J.

    2012-12-01

    The worldwide search for suitable underground storage formations for CO2 also considers coal-bearing strata. CO2 is already injected into coal seams for enhanced recovery of coal bed methane. However, the geochemical and microbiological effects of increased CO2 concentrations on organic matter rich formations are rarely investigated. The injected CO2 will dissolve in the pore water, causing a decrease in pH and resulting in acidic formation waters. Low molecular weight organic acids (LMWOAs) are chemically bound to the macromolecular matrix of sedimentary organic matter and may be liberated by hydrolysis, which is enhanced under acidic conditions. Recent investigations outlined the importance of LMWOAs as a feedstock for subsurface microbial life [1]. Therefore, injection of CO2 into coal formations may result in enhanced nutrient supply for subsurface microbes. To investigate the effects of highly CO2-saturated waters on the release of LMWOAs from coal, we developed an inexpensive high-pressure-high-temperature system that allows manipulating the concentration of dissolved gases up to 60 MPa and 120°C, respectively. The sample is placed in a flexible, gas-tight and inert PVDF sleeve, separating it from the pressure fluid and allowing for subsampling without loss of pressure. Lignite samples from the DEBITS-1 well, Waikato Basin, NZ and the Welzow-Süd open-cast mine, Niederlausitz, Germany, were extracted at 90° C and 5 MPa, with either pure water, CO2-saturated water, CO2/NO2 or CO2/SO2-saturated water. Subsamples were taken at different time points during the 72 hrs. long extraction. Extraction of LMWOAs from coal samples with our pressurised system resulted in yields that were up to four times higher than those reported for Soxhlet extraction [2]. These higher yields may be explained by the fact that during Soxhlet extraction the sample only gets into contact with freshly distilled water, whereas in our system the extraction fluid is circulated, resulting in

  3. Quantifying the magnitude, spatiotemporal variation and age of aquatic CO2 fluxes in western Greenland

    Science.gov (United States)

    Long, Hazel; Waldron, Susan; Hoey, Trevor; Garnett, Mark; Newton, Jason

    2015-04-01

    High latitude regions are experiencing accelerated atmospheric warming, and understanding the terrestrial response to this is of crucial importance as: a) permafrost soils hold vast amounts (1672 Pg; Tarnocai et al., 2009) of carbon (C) which may be released and feedback to climate change; and, b) ice sheet melt in this region is accelerating, and whilst this will cause albedo and heat flux changes, the role of this in atmospheric gas release is poorly known. To understand how sensitive arctic environments may respond to future warming, we need measurements that document current C flux rates and help to understand C cycling pathways. Although it has been widely hypothesised that Arctic regions may become increasingly significant C sources, the contribution of aquatic C fluxes which integrate catchment-wide sources has been little studied. Using a floating chamber method we directly measured CO2 fluxes from spatially distributed freshwaters (ice sheet melt, permafrost melt, and lakes/ponds) in the Kangerlussuaq region of western Greenland during the early part of the summer 2014 melt season. Fluxes from freshwaters with permafrost sources were in the range -3.15 to +1.28 μmol CO2 m-2 s-1. Fluxes from a river draining the ice sheet and the Russell Glacier were between -2.19 and +4.31 μmol CO2 m-2 s-1. These ranges show the systems can be both sources (efflux) and sinks (influx) of CO2. Much freshwater data worldwide shows CO2 efflux, and recording river/stream systems being a CO2 sink is unusual. Analysis of dissolved inorganic carbon (DIC) concentrations of the water sources revealed higher concentrations of DIC in the meltwater of permafrost systems (0.66-1.92 mmol) than the ice melt system (0.07 to 0.17 mmol), as well as differences in the carbon stable isotope ratio ranges (δ13C permafrost-melt, -9.5 to -1.2 permil; δ13C ice-melt, -11.7 to 7.3 permil). Where we recorded CO2 efflux we collected effluxed CO2 for radiocarbon analysis, and here we will present

  4. CO2 emissions from Super-light Structures

    DEFF Research Database (Denmark)

    Hertz, Kristian Dahl; Bagger, Anne

    2011-01-01

    CO2 emission from the construction of buildings is seldom taken into account because focus is primarily on building operation. New technologies have therefore mainly been developed to reduce the energy consumption connected to operation. Super-light technology is a new structural principle giving...... rise to a substantial reduction of the CO2 emission in the construction phase. The present paper describes how the CO2 emission is reduced when using Super-light technology instead of traditional structural components. Estimations of the CO2 emissions from a number of projects using various...... construction methods suggest that building with Super-light structures may cut the CO2 emission in half, compared to traditional concrete structures, and reduce it to 25% compared to traditional steel structures....

  5. Sustainable DME synthesis-design with CO2 utilization

    DEFF Research Database (Denmark)

    Prasertsri, Weeranut; Frauzem, Rebecca; Suriyapraphadilok, Uthaiporn

    Minimizing CO2 emission, while achieving economic feasibility in CO2 utilization for producing valuable chemicals is a challenging problem, as reported in recent studies.Due to its high Cetane number, clean-burning, and non-toxic, DME is a promising fuel alternative, and therefore, potentially...... valuable chemical that can be produced via thermochemical CO2 conversion reactions. The aim of this study is to identify the most promising processing route for sustainable production of DME in terms of CO2 emission, economic indicators and sustainable indicators. The three processing routes are generated......: (A) dry reforming step, methanol synthesis step, and methanoldehydration step; (B) CO2 hydrogenation step followed by methanol dehydration step;and (C) dry reforming step followed by direct DME synthesis step. Starting with a base-case design, the process flow sheets for the three routes are studied...

  6. Modeling of CO2 absorber using an AMP solution

    DEFF Research Database (Denmark)

    Gabrielsen, Jostein; Michelsen, Michael Locht; Stenby, Erling Halfdan

    2006-01-01

    Abstract: An explicit model for carbon dioxide (CO2) solubility in an aqueous solution of 2-amino-2-methyl-1-propanol (AMP) has been proposed and an expression for the heat of absorption of CO2 has been developed as a function of loading and temperature. A rate-based steady-state model for CO2...... absorption into an AMP solution has been proposed, using both the proposed expression for the CO2 solubility and the expression for the heat of absorption along with an expression for the enhancement factor and physicochemical data from the literature. The proposed model has successfully been applied...... to absorption of CO2 into an AMP solution in a packed tower and validated against pilot-plant data from the literature. (c) 2006 American Institute of Chemical Engineers....

  7. Effects of explicit atmospheric convection at high CO2.

    Science.gov (United States)

    Arnold, Nathan P; Branson, Mark; Burt, Melissa A; Abbot, Dorian S; Kuang, Zhiming; Randall, David A; Tziperman, Eli

    2014-07-29

    The effect of clouds on climate remains the largest uncertainty in climate change predictions, due to the inability of global climate models (GCMs) to resolve essential small-scale cloud and convection processes. We compare preindustrial and quadrupled CO2 simulations between a conventional GCM in which convection is parameterized and a "superparameterized" model in which convection is explicitly simulated with a cloud-permitting model in each grid cell. We find that the global responses of the two models to increased CO2 are broadly similar: both simulate ice-free Arctic summers, wintertime Arctic convection, and enhanced Madden-Julian oscillation (MJO) activity. Superparameterization produces significant differences at both CO2 levels, including greater Arctic cloud cover, further reduced sea ice area at high CO2, and a stronger increase with CO2 of the MJO.

  8. Interfacial phenomena at the compressed co2-water interface

    Directory of Open Access Journals (Sweden)

    B. Bharatwaj

    2006-06-01

    Full Text Available Compressed CO2 is considered to be a viable alternative to toxic volatile organic solvents with potential applications in areas including separation reactions, and materials formation processes. Thus an interest in CO2 stems from the fact that it is very inexpensive, has low toxicity, and is not a regulated. However, compressed CO2 has a zero dipole moment and weak van der Waals forces and thus is a poor solvent for both polar and most high molecular weight solutes, characteristics that severely restrict its applicability. In order to overcome this inherent inability, surfactant-stabilized organic and aqueous dispersions in CO2 have been proposed. This work will discuss fundamentals and recent advances in the design of amphiphiles for the novel CO2-water interface.

  9. Feedbacks and the coevolution of plants and atmospheric CO2.

    Science.gov (United States)

    Beerling, David J; Berner, Robert A

    2005-02-01

    The coupled evolution of land plants, CO2, and climate over the last half billion years has maintained atmospheric CO2 concentrations within finite limits, indicating the involvement of a complex network of geophysiological feedbacks. But insight into this important regulatory network is extremely limited. Here we present a systems analysis of the physiological and geochemical processes involved, identifying new positive and negative feedbacks between plants and CO2 on geological time scales. Positive feedbacks accelerated falling CO2 concentrations during the evolution and diversification of terrestrial ecosystems in the Paleozoic and enhanced rising CO2 concentrations across the Triassic-Jurassic boundary during flood basalt eruptions. The existence of positive feedbacks reveals the unexpected destabilizing influence of the biota in climate regulation that led to environmental modifications accelerating rates of terrestrial plant and animal evolution in the Paleozoic.

  10. Compensation of CO2 emissions by air travels: an example

    Directory of Open Access Journals (Sweden)

    Lombardi F

    2011-05-01

    Full Text Available In recent years, several aircraft companies launched awareness campaigns, offering to their passenger the opportunity to known and also calculate their own per-capita CO2 emissions related to the flight they are going to make. Such campaigns permits to the passenger to pay a volunteer contribution in order to compensate their CO2 emissions. In this short communication, some programs undertaken by airline companies are showed. These initiatives are all characterized by a common denominator: the achievement of concrete, proved and verifiable results to compensate the aircraft CO2 emissions. Moreover, also a concrete case is reported as example: it is useful to show which is the per capita CO2 emission for a sample flight in Europe and, quantitatively, the amount of compensation measurements. Finally, this communication highlights on how the estimates of such measurements are usually miscalculated, considering that the capability of forest ecosystems to store CO2 are often underestimated.

  11. PSO 7171 - Oxyfuel Combustion for below zero CO2 emissions

    DEFF Research Database (Denmark)

    Toftegaard, Maja Bøg; Brix, Jacob; Hansen, Brian Brun

    are sought which will enable a significant reduction of the anthropogenic CO2 emissions during the transformation period from the use of fossil fuels to renewable sources of energy. Carbon capture and storage (CCS) has the potential to significantly reduce CO2 emissions from power stations while allowing...... conventional combustion in air by using a mixture of pure oxygen and recirculated flue gas as the combustion medium thereby creating a flue gas highly concentrated in CO2 making the capture process economically more feasible compared to technologies with capture from more dilute CO2 streams. This project has......, and the perspectives for the implementation of oxyfuel combustion s a CO2 sequestration solution in the Danish power production system. Regarding the fundamental combustion characteristics (combustion, emissions, and ash), the project has not identified any disqualifying characteristics. On the contrary, oxyfuel has...

  12. Synthesis and Design of a Sustainable CO2 Utilization Network

    DEFF Research Database (Denmark)

    Frauzem, Rebecca; Gani, Rafiqul

    In response to increasing regulations and concern about the impact of greenhouse gases on the environment, carbon dioxide (CO2) emissions are targeted for reduction. One method is the conversion of CO2 to useful compounds via chemical reactions. However, conversion is still in its infancy...... processing block. CO2 conversion processes show promise as an additional method for the sustainable reduction of CO2 emissions....... a superstructure-based approach a network of utilization alternatives is created linking CO2 and other raw materials with various products using processing blocks. This will then be optimized and verified for sustainability. Detailed design has also been performed for a case study on the methanol synthesis...

  13. [Model study on CO2 removal by photobioreactor].

    Science.gov (United States)

    Cheng, Gui-Lin; Cheng, Li-Hua; Zhou, Cheng-Xu; Zhang, Lin; Chen, Huan-Lin

    2006-09-01

    The key point of study on CO2 removal by microalgae cultured in a photobioreactor is to improve CO2 removal capability. In this paper, a model of air-lift photobioreactor was developed by combination of conditions including the velocity of flow, the degree of mixing, the gas-liquid mass transfer and the rate of photosynthesis, and two corresponding simplified methods, such as time discretization and lumped parameters were put forward. Using a method of lumped parameters, the model for simulation of time course of DO, pH in the column air-lift photobioreactor and prediction of CO2, O2 concentrations in the outlet gas under different CO2 concentration in the aeration gas was thoroughly discussed. Experimental data were also used to verify the model which could potentially be applied to rational design of the photobioreactor, high-density culture of microalgae and efficient removal of CO2.

  14. CO2 leakage monitoring and analysis to understand the variation of CO2 concentration in vadose zone by natural effects

    Science.gov (United States)

    Joun, Won-Tak; Ha, Seung-Wook; Kim, Hyun Jung; Ju, YeoJin; Lee, Sung-Sun; Lee, Kang-Kun

    2017-04-01

    Controlled ex-situ experiments and continuous CO2 monitoring in the field are significant implications for detecting and monitoring potential leakage from CO2 sequestration reservoir. However, it is difficult to understand the observed parameters because the natural disturbance will fluctuate the signal of detections in given local system. To identify the original source leaking from sequestration reservoir and to distinguish the camouflaged signal of CO2 concentration, the artificial leakage test was conducted in shallow groundwater environment and long-term monitoring have been performed. The monitoring system included several parameters such as pH, temperature, groundwater level, CO2 gas concentration, wind speed and direction, atmospheric pressure, borehole pressure, and rainfall event etc. Especially in this study, focused on understanding a relationship among the CO2 concentration, wind speed, rainfall and pressure difference. The results represent that changes of CO2 concentration in vadose zone could be influenced by physical parameters and this reason is helpful in identifying the camouflaged signal of CO2 concentrations. The 1-D column laboratory experiment also was conducted to understand the sparking-peak as shown in observed data plot. The results showed a similar peak plot and could consider two assumptions why the sparking-peak was shown. First, the trapped CO2 gas was escaped when the water table was changed. Second, the pressure equivalence between CO2 gas and water was broken when the water table was changed. These field data analysis and laboratory experiment need to advance due to comprehensively quantify local long-term dynamics of the artificial CO2 leaking aquifer. Acknowledgement Financial support was provided by the "R&D Project on Environmental Management of Geologic CO2 Storage" from the KEITI (Project Number: 2014001810003)

  15. Mineral CO2 Sequestration into Basalt: The Carbfix Project

    Science.gov (United States)

    Gislason, S. R.; Broecker, W. S.; Oelkers, E. H.; Gunnlaugsson, E.; Stefansson, A.; Wolff-Boenisch, D.; Matter, J.; Björnsson, G.

    2008-12-01

    The reduction of industrial CO2 emissions is considered one of the main challenges of this century. Among commonly proposed CO2 storage techniques, the injection of anthropogenic CO2 into deep geological formations is quite promising due their large potential storage capacity and geographic ubiquity. Finding a storage solution that is long lasting, thermodynamically stable and environmentally benign would be ideal. Storage of CO2, as solid calcium magnesium iron carbonate, in basaltic rocks may provide such a long lasting, thermodynamically stable and environmentally benign solution. In nature, the carbonization of basaltic rocks occurs in a variety of well-documented settings, such as the hydrothermal alteration in geothermal systems and in deep ocean vent systems. The goal of this research project is to optimize industrial methods for storing CO2 in basaltic rocks through a combined program consisting of, field scale injection of CO2 charged waters into basaltic rocks, laboratory based experiments, study of natural CO2 waters as natural analogue and state of the art geochemical modelling. A second and equally important goal of this research project is to generate the human capital and expertise to apply the advances made in this project in the future. Towards this goal the bulk of the research is to be performed by graduate student and post-doctoral trainees. At the Hellisheidi Iceland site, the hot gases released from geothermal energy production will be processed to separate the CO2. It will then be dissolved in water at about 25 bar pressure and pumped into the porous basalt at 400 to 700 m depth, at the rate of 30 000 tonnes per year. Model simulations, natural analogues and experimental work suggest that the CO2 charged waters will reacts with the basalt and form carbonate minerals such as FeCO3 - MgCO3 solid solutions and CaCO3. By this method the fixed CO2 will remain trapped as mineral for millions of years.

  16. Increasing stomatal conductance in response to rising atmospheric CO2.

    Science.gov (United States)

    Purcell, C; Batke, S P; Yiotis, C; Caballero, R; Soh, W K; Murray, M; McElwain, J C

    2018-01-31

    Studies have indicated that plant stomatal conductance (gs) decreases in response to elevated atmospheric CO2, a phenomenon of significance for the global hydrological cycle. However, gs increases across certain CO2 ranges have been predicted by optimization models. The aim of this work was to demonstrate that under certain environmental conditions, gs can increase in response to elevated CO2. Using (1) an extensive, up-to-date synthesis of gs responses in free air CO2 enrichment (FACE)experiments, (2) in situ measurements across four biomes showing dynamic gs responses to a CO2 rise of ~50 ppm (characterizing the change in this greenhouse gas over the past three decades) and (3) a photosynthesis-stomatal conductance model, it is demonstrated that gs can in some cases increase in response to increasing atmospheric CO2. Field observations are corroborated by an extensive synthesis of gs responses in FACE experiments showing that 11.8 % of gs responses under experimentally elevated CO2 are positive. They are further supported by a strong data-model fit (r2 = 0.607) using a stomatal optimization model applied to the field gs dataset. A parameter space identified in the Farquhar-Ball-Berry photosynthesis-stomatal conductance model confirms field observations of increasing gs under elevated CO2 in hot dry conditions. Contrary to the general assumption, positive gs responses to elevated CO2, although relatively rare, are a feature of woody taxa adapted to warm, low-humidity conditions, and this response is also demonstrated in global simulations using the Community Land Model (CLM4). The results contradict the over-simplistic notion that global vegetation always responds with decreasing gs to elevated CO2, a finding that has important implications for predicting future vegetation feedbacks on the hydrological cycle at the regional level.

  17. CO2 on the International Space Station: An Operations Update

    Science.gov (United States)

    Law, Jennifer; Alexander, David

    2016-01-01

    PROBLEM STATEMENT: We describe CO2 symptoms that have been reported recently by crewmembers on the International Space Station and our continuing efforts to control CO2 to lower levels than historically accepted. BACKGROUND: Throughout the International Space Station (ISS) program, anecdotal reports have suggested that crewmembers develop CO2-related symptoms at lower CO2 levels than would be expected terrestrially. Since 2010, operational limits have controlled the 24-hour average CO2 to 4.0 mm Hg, or below as driven by crew symptomatology. In recent years, largely due to increasing awareness by crew and ground team, there have been increased reports of crew symptoms. The aim of this presentation is to discuss recent observations and operational impacts to lower CO2 levels on the ISS. CASE PRESENTATION: Crewmembers are routinely asked about CO2 symptoms in their weekly private medical conferences with their crew surgeons. In recent ISS expeditions, crewmembers have noted symptoms attributable to CO2 starting at 2.3 mmHg. Between 2.3 - 2.7 mm Hg, fatigue and full-headedness have been reported. Between 2.7 - 3.0 mm Hg, there have been self-reports of procedure missed steps or procedures going long. Above 3.0 - 3.4 mm Hg, headaches have been reported. A wide range of inter- and intra-individual variability in sensitivity to CO2 have been noted. OPERATIONAL / CLINICAL RELEVANCE: These preliminary data provide semi-quantitative ranges that have been used to inform a new operational limit of 3.0 mmHg as a compromise between systems capabilities and the recognition that there are human health and performance impacts at recent ISS CO2 levels. Current evidence would suggest that an operational limit between 0.5 and 2.0 mm Hg may maintain health and performance. Future work is needed to establish long-term ISS and future vehicle operational limits.

  18. Transient nature of CO2 fertilization in Arctic tundra

    Science.gov (United States)

    Oechel, Walter C.; Cowles, Sid; Grulke, Nancy; Hastings, Steven J.; Lawrence, Bill; Prudhomme, Tom; Riechers, George; Strain, Boyd; Tissue, David; Vourlitis, George

    1994-10-01

    THERE has been much debate about the effect of increased atmospheric CO2 concentrations on plant net primary production1,3 and on net ecosystem CO2 flux3-10. Apparently conflicting experimental findings could be the result of differences in genetic potential11-15 and resource availability16-20, different experimental conditions21-24 and the fact that many studies have focused on individual components of the system2,21,25-27 rather than the whole ecosystem. Here we present results of an in situ experiment on the response of an intact native ecosystem to elevated CO2. An undisturbed patch of tussock tundra at Toolik Lake, Alaska, was enclosed in greenhouses in which the CO2 level, moisture and temperature could be controlled28, and was subjected to ambient (340 p.p.m.) and elevated (680 p.p.m.) levels of CO2 and temperature (+4 °C). Air humidity, precipitation and soil water table were maintained at ambient control levels. For a doubled CO2 level alone, complete homeostasis of the CO2 flux was re-established within three years, whereas the regions exposed to a combination of higher temperatures and doubled CO2 showed persistent fertilization effect on net ecosystem carbon sequestration over this time. This difference may be due to enhanced sink activity from the direct effects of higher temperatures on growth16,29-33 and to indirect effects from enhanced nutrient supply caused by increased mineralization10,11,19,27,34. These results indicate that the responses of native ecosystems to elevated CO2 may not always be positive, and are unlikely to be straightforward. Clearly, CO2 fertilization effects must always be considered in the context of genetic limitation, resource availability and other such factors.

  19. CuZn Alloy- Based Electrocatalyst for CO2 Reduction

    KAUST Repository

    Alazmi, Amira

    2014-06-01

    ABSTRACT CuZn Alloy- Based Electrocatalyst for CO2 Reduction Amira Alazmi Carbon dioxide (CO2) is one of the major greenhouse gases and its emission is a significant threat to global economy and sustainability. Efficient CO2 conversion leads to utilization of CO2 as a carbon feedstock, but activating the most stable carbon-based molecule, CO2, is a challenging task. Electrochemical conversion of CO2 is considered to be the beneficial approach to generate carbon-containing fuels directly from CO2, especially when the electronic energy is derived from renewable energies, such as solar, wind, geo-thermal and tidal. To achieve this goal, the development of an efficient electrocatalyst for CO2 reduction is essential. In this thesis, studies on CuZn alloys with heat treatments at different temperatures have been evaluated as electrocatalysts for CO2 reduction. It was found that the catalytic activity of these electrodes was strongly dependent on the thermal oxidation temperature before their use for electrochemical measurements. The polycrystalline CuZn electrode without thermal treatment shows the Faradaic efficiency for CO formation of only 30% at applied potential ~−1.0 V vs. RHE with current density of ~−2.55 mA cm−2. In contrast, the reduction of oxide-based CuZn alloy electrode exhibits 65% Faradaic efficiency for CO at lower applied potential about −1.0 V vs. RHE with current density of −2.55 mA cm−2. Furthermore, stable activity was achieved over several hours of the reduction reaction at the modified electrodes. Based on electrokinetic studies, this improvement could be attributed to further stabilization of the CO2•− on the oxide-based Cu-Zn alloy surface.

  20. Weight-Loss and Nutrition Myths

    Science.gov (United States)

    ... D—cereals or soy-based beverages Myth: “Going vegetarian” will help you lose weight and be healthier. Some research shows that a healthy vegetarian eating plan may be linked to lower obesity ...

  1. Myth from a Psychological Point of View

    Directory of Open Access Journals (Sweden)

    Mozhgan Yahyazade

    2013-06-01

    Full Text Available One of the most mysterious phenomena in the world that engage the human's curious mind for long time is to discover the unknown world of myth. Believes and costumes of every nation is like a very strong and big tree. That has rooted in myth and their result has appeared in art and literature; and now we can understand the importance of myth. In this study we have tried to consider myth and theory's about collective subcontinent and dream and to make clear relationship be literature's notion with psychology and its branches and whatever that analysis in this interfiled research is cases that show the importance of relation between different fields that with more and penalized investigation we can find new information that maybe with more consideration and more attention to relation of these sciences; we can discover the hidden and unknown aspect of human's life and his behaviors.

  2. Isaac Newton: Man, Myth, and Mathematics.

    Science.gov (United States)

    Rickey, V. Frederick

    1987-01-01

    This article was written in part to celebrate the anniversaries of landmark mathematical works by Newton and Descartes. It's other purpose is to dispel some myths about Sir Isaac Newton and to encourage readers to read Newton's works. (PK)

  3. Competence in Management Development: Challenging the Myths.

    Science.gov (United States)

    Jubb, Richard; Robotham, David

    1997-01-01

    Counters the following myths: competence has been defined; managerial effectiveness can be identified; management is generic; effectiveness can be measured; management is composed of skills, behaviors, or traits; and only maximum performance counts. (SK)

  4. The Myth of the Black Matriarchy.

    Science.gov (United States)

    Staples, Robert

    1981-01-01

    Reprint of a 1970 article that describes the oppression of Blacks and the distortion of Black family life throughout United States history. Holds that the myth of Black matriarchy sets back the struggle for Black liberation. (GC)

  5. Myths, presumptions, and facts about obesity

    DEFF Research Database (Denmark)

    Casazza, Krista; Fontaine, Kevin R; Astrup, Arne

    2013-01-01

    Many beliefs about obesity persist in the absence of supporting scientific evidence (presumptions); some persist despite contradicting evidence (myths). The promulgation of unsupported beliefs may yield poorly informed policy decisions, inaccurate clinical and public health recommendations...

  6. BADUY PLURALISM: FROM MYTH TO REALITY

    Directory of Open Access Journals (Sweden)

    Abdurrahman Misno Bambang Prawiro

    2013-06-01

    Full Text Available Indonesia is a land of many tribes, with each tribe having different customs. However they have a bond in the form of the state motto, Bhineka Tunggal Ika. This motto is based on a philosophy embraced by every tribe in the form of the teachings passed down from the ancestors such as pantun (Malay poetic form, rhyme, guguritan (Sundanese literary works, history and myths. Myths here are stories about things that happened in the past in the form of the history of the origins of man and nature, or the origin of a nation. Myths as a local wisdom are believed to be the truth by every member of the tribe applied in everyday life. This includes the myth that tells about human cultural diversity (plurality, and the community will implement its content. What about the Baduy community in Banten, do they have myths and apply the myths that deal with pluralism in their life? The Baduy are one of the ethnic groups in Indonesia who have myths about the creation of the universe, human origins, and even myths about the events that will occur. The myth about the origin of humans in the Baduy community begins with the creation of Adam as the first human, and then he had children that gave birth to the whole nation in the world. Because every human in the world is the great-grandsons of Adam, the Baduy believe that all humanity is dulur (brother despite differences in customs and religion. The reality of social life of the Baduy community, either Baduy Dalam (inner baduy or Baduy Luar (outer baduy is that they greatly respect all mankind despite the different cultures and religions. Prohibition to enter the Baduy traditional village for foreigners is because of historical factors, namely the agreement made by their ancestors with the Dutch. This research concluded that the Baduy society is a society that understands the plurality of cultures; it is based on a myth that they believe and apply in their life about tolerance of other religions. Key Word: Pluralism

  7. Symbols and Myths in European Integration

    DEFF Research Database (Denmark)

    Lynggaard, Kennet; Manners, Ian James; Søby, Christine

    2013-01-01

    The study of symbols and myths in European integration is crucial to our understanding of both how the European Union (EU) becomes constituted as a political reality and how the integration process itself occurs. By drawing on the study of symbols and myths from political science, humanities...... and cultural studies to the analysis of European integration, this paper will set out a project to provide a better understanding of how symbolic and substantial processes interact in European society....

  8. Photosynthetic responses to elevated CO(2) and O(3) in Quercus ilex leaves at a natural CO(2) spring.

    Science.gov (United States)

    Paoletti, E; Seufert, G; Della Rocca, G; Thomsen, H

    2007-06-01

    Photosynthetic stimulation and stomatal conductance (Gs) depression in Quercus ilex leaves at a CO(2) spring suggested no down-regulation. The insensitivity of Gs to a CO(2) increase (from ambient 1500 to 2000 micromol mol(-1)) suggested stomatal acclimation. Both responses are likely adaptations to the special environment of CO(2) springs. At the CO(2)-enriched site, not at the control site, photosynthesis decreased 9% in leaves exposed to 2x ambient O(3) concentrations in branch enclosures, compared to controls in charcoal-filtered air. The stomatal density reduction at high CO(2) was one-third lower than the concomitant Gs reduction, so that the O(3) uptake per single stoma was lower than at ambient CO(2). No significant variation in monoterpene emission was measured. Higher trichome and mesophyll density were recorded at the CO(2)-enriched site, accounting for lower O(3) sensitivity. A long-term exposure to H(2)S, reflected by higher foliar S-content, and CO(2) might depress the antioxidant capacity of leaves close to the vent and increase their O(3) sensitivity.

  9. Elevated CO2 and nitrogen effects on soil CO2 flux from a pasture upon return to cultivation

    Science.gov (United States)

    Soil CO2 efflux patterns associated with converting pastures back to row crop production remain understudied in the Southeastern U.S. A 10-year study of bahiagrass (Paspalum notatum Flüggé) response to elevated CO2 was conducted using open top field chambers on a Blanton loamy sand (loamy siliceous,...

  10. Effects of atmospheric CO2 enrichment on soil CO2 efflux in a young longleaf pine system

    Science.gov (United States)

    G. Brett Runion; John R. Butnor; S. A. Prior; R. J. Mitchell; H. H. Rogers

    2012-01-01

    The southeastern landscape is composed of agricultural and forest systems that can store carbon (C) in standing biomass and soil. Research is needed to quantify the effects of elevated atmospheric carbon dioxide (CO2) on terrestrial C dynamics including CO2 release back to the atmosphere and soil sequestration. Longleaf...

  11. Membrane-assisted CO2 liquefaction: performance modelling of CO2 capture from flue gas in cement production

    NARCIS (Netherlands)

    Bouma, R.H.B.; Vercauteren, F.F.; Os, P.J. van; Goetheer, E.L.V.; Berstad, D.; Anantharaman, R.

    2017-01-01

    CEMCAP is an international R&D project under the Horizon 2020 Programme preparing the ground for the large-scale implementation of CO2 capture in the European cement industry. This paper concerns the performance modeling of membraneassisted CO2 liquefaction as a possible retrofit application for

  12. CO2 Fixation into Novel CO2 Storage Materials Composed of 1,2-Ethanediamine and Ethylene Glycol Derivatives.

    Science.gov (United States)

    Zhao, Tianxiang; Guo, Bo; Han, Limin; Zhu, Ning; Gao, Fei; Li, Qiang; Li, Lihua; Zhang, Jianbin

    2015-07-20

    A new CO2 fixation process into solid CO2 -storage materials (CO2 SMs) under mild conditions has been developed. The novel application of amine-glycol systems to the capture, storage, and utilization of CO2 with readily available 1,2-ethanediamine (EDA) and ethylene glycol derivatives (EGs) was demonstrated. Typically, the CO2 SMs were isolated in 28.9-47.5 % yields, followed by extensive characterization using (13) C NMR, XRD, and FTIR. We found that especially the resulting poly-ethylene-glycol-300-based CO2 SM (PCO2 SM) product could be processed into stable tablets for CO2 storage; the aqueous PCO2 SM solution exhibited remarkable CO2 capturing and releasing capabilities after multiple cycles. Most importantly, the EDA and PEG 300 released from PCO2 SM were found to act as facilitative surfactants for the multiple preparation of CaCO3 microparticles with nano-layer structure. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  13. Characterization of CO2 and mixed methane/CO2 hydrates intercalated in smectites by means of atomistic calculations.

    Science.gov (United States)

    Martos-Villa, Rubén; Mata, M Pilar; Sainz-Díaz, C Ignacio

    2014-04-01

    The recent increase in anthropogenic CO2 gas released to the atmosphere and its contribution to global warming make necessary to investigate new ways of CO2 storage. Injecting CO2 into subsurface CH4 hydrate reservoirs would displace some of the CH4 in the hydrate crystal lattice, converting simple CH4 hydrates into either simple CO2 hydrates or mixed CH4CO2 hydrates. Molecular simulations were performed to determine the structure and behavior of CO2 and mixed hydrate complexes in the interlayer of Na-rich montmorillonite and beidellite smectite. Molecular Dynamics (MD) simulations used NPT ensembles in a 4×4×1 supercell comprised of montmorillonite or beidellite with CO2 or mixed CH4/CO2 hydrate complexes in the interlayer. The smectite 2:1 layer surface helps provide a stabilizing influence on the formation of gas hydrate complexes. The type of smectite affects the stability of the smectite-hydrate complexes, where high charge located on the tetrahedral layer of the smectites disfavor the formation of hydrate complexes. Copyright © 2014 Elsevier Inc. All rights reserved.

  14. Ab initio studies on [bmim][PF6]–CO2 mixture and CO2 clusters

    Indian Academy of Sciences (India)

    Wintec

    on CO2 clusters reveals the greater tendency of the clusters with more CO2 units, to deviate from the linear geometry. Keywords. Ionic liquids; supercritical carbon dioxide; ab initio; molecular dynamics. 1. Introduction. The increase in the pollution level due to the solvents used currently in industries demands alternative ...

  15. An estimate of monthly global emissions of anthropogenic CO2: Impact on the seasonal cycle of atmospheric CO2

    Energy Technology Data Exchange (ETDEWEB)

    Erickson, D [Oak Ridge National Laboratory (ORNL); Mills, R [Oak Ridge National Laboratory (ORNL); Gregg, J [University of Maryland; Blasing, T J [ORNL; Hoffman, F [Oak Ridge National Laboratory (ORNL); Andres, Robert Joseph [ORNL; Devries, M [Oak Ridge National Laboratory (ORNL); Zhu, Z [NASA Goddard Space Flight Center; Kawa, S [NASA Goddard Space Flight Center

    2008-01-01

    Monthly estimates of the global emissions of anthropogenic CO2 are presented. Approximating the seasonal CO2 emission cycle using a 2-harmonic Fourier series with coefficients as a function of latitude, the annual fluxes are decomposed into monthly flux estimates based on data for the United States and applied globally. These monthly anthropogenic CO2 flux estimates are then used to model atmospheric CO2 concentrations using meteorological fields from the NASA GEOS-4 data assimilation system. We find that the use of monthly resolved fluxes makes a significant difference in the seasonal cycle of atmospheric CO2 in and near those regions where anthropogenic CO2 is released to the atmosphere. Local variations of 2-6 ppmv CO2 in the seasonal cycle amplitude are simulated; larger variations would be expected if smaller source-receptor distances could be more precisely specified using a more refined spatial resolution. We also find that in the midlatitudes near the sources, synoptic scale atmospheric circulations are important in the winter and that boundary layer venting and diurnal rectifier effects are more important in the summer. These findings have implications for inverse-modeling efforts that attempt to estimate surface source/sink regions especially when the surface sinks are colocated with regions of strong anthropogenic CO2 emissions.

  16. Lipid content and fatty acid composition of Porosira glacialis and Attheya longicornis in response to carbon dioxide (CO2 aeration.

    Directory of Open Access Journals (Sweden)

    E Y Artamonova

    Full Text Available In the current study two novel psychrophilic diatoms Porosira glacialis and Attheya longicornis were tested for suitability to CO2 mitigation coupled with production of the physiologically requisite omega- 3 fatty acids. This study is in line with the worldwide conducted research aimed at applying biorefinery concept to heavy polluting industries. Since the production of algal high value compounds, i.e. essential fatty acids, relies on utilization of residual CO2 emissions coming from industry, the costs of such production maybe substantially reduced. Besides, the ecological benefits of the biorefinery concept being implemented are obvious, since CO2 is one of the major greenhouse gases. The current research has shown that one of the tested microalgal species, the diatom P. glacialis showed good tolerance to high (20-25% levels of CO2 and maintained growth rates comparable to controls. The total lipid content in the CO2 aerated culture increased from 8.91 to 10.57% in cell dry mass. Additionally, the content of docosahexaenoic acid (DHA increased from 3.90 to 5.75%, while the concentration of eicosapentaenoic acid (EPA decreased from 26.59 to 23.66%. In contrast, A. longicornis did not demonstrate any significant increase in total lipid content. Besides, its growth was hampered by high levels of CO2 aeration.

  17. Lessons Learned From Recent Research on Internal CO2 Transport in Trees. Part I, CO2 Efflux and Respiration

    Science.gov (United States)

    McGuire, M. A.; Bloemen, J.; Aubrey, D. P.; Steppe, K.; Teskey, R. O.

    2016-12-01

    Currently, the most pressing problem regarding respiration in trees is determining the rate of respiration in woody tissues. In stems and roots, barriers to diffusion promote the buildup of CO2 from respiration to high concentrations, often in the range of 3 to 10% and sometimes exceeding 20%, substantially higher than that of the atmosphere ( 0.04%). A substantial portion of this internal CO2 released from respiring cells in roots and stems can dissolve in xylem sap and move upward in the xylem stream, resulting in internal transport of respired CO2 that rivals the efflux of respired CO2from woody tissues. The importance of such internal CO2 transport for the assessment of above- and below-ground respiration has gained increasing interest and here we will synthesize the latest research. The most important recent finding has been that in tree roots, a large fraction of respired CO2 remains within the root system rather than diffusing into the soil. This CO2 is transported in xylem sap into the shoot, and because respiration is almost always measured as the flux of CO2 into the atmosphere from plant tissues, it represents an unaccounted- for component of tree root metabolism. In Populus deltoides trees, for which xylem CO2 transport and soil CO2 efflux near the tree was measured, twice the amount of CO2 derived from below-ground autotrophic respiration entered the xylem stream as diffused into the soil environment. For both Eucalyptus and Quercus, up to 24 and 19% of root-respired CO2 was transported via the transpiration stream, respectively, illustrating that a significant internal transport of root-respired CO2 is present across a wide range of plant families. These findings suggest that root and soil respiration can be substantially underestimated by "soil-centric" measurements. Moreover, internal transport of respired CO2, which has only recently been recognized and measured, has important implications for our understanding of carbon dynamics at both plant and

  18. CO2 with Mechanical Subcooling vs. CO2 Cascade Cycles for Medium Temperature Commercial Refrigeration Applications Thermodynamic Analysis

    Directory of Open Access Journals (Sweden)

    Laura Nebot-Andrés

    2017-09-01

    Full Text Available A recent trend to spread the use of CO2 refrigeration cycles in warm regions of the world is to combine a CO2 cycle with another one using a high performance refrigerant. Two alternatives are being considered: cascade and mechanical subcooling systems. Both respond to a similar configuration of the refrigeration cycle, they being based on the use of two compressors and same number of heat exchangers. However, the compressor, heat exchanger sizes and energy performance differ a lot between them. This work, using experimental relations for CO2 and R1234yf semi-hermetic compressors analyzes in depth both alternatives under the warm climate of Spain. In general, it was concluded that the CO2 refrigeration solution with mechanical subcooling would cover all the conditions with high overall energy efficiency, thus it being recommended for further extension of the CO2 refrigeration applications.

  19. Measurement of total CO2 in microliter samples of urine and other biological fluids using infrared detection of CO2.

    Science.gov (United States)

    Trepiccione, Francesco; Iena, Francesco Maria; Catalini, Laura; Carpi, Francesco Martino; Koed, Mogens; Frische, Sebastian

    2017-06-05

    The purpose of this study is to describe a low-cost and simply made instrument capable of measuring the total CO2 content of microliter volumes of biological fluids utilizing a commercially available CO2 sensor based on a NDIR detector. The described instrument is based on transformation of dissolved HCO3- to CO2 by acidification and subsequent measurement of the produced CO2. The instrument has a linear response in the range 0.025-10 μmol HCO3-, which enables measurements in fresh urine and plasma samples down to 5 μl. The values from plasma were compared to measurements made on 65 μl whole blood in an automatic blood gas analyzer and found not to differ significantly. Compared to currently commercially available instruments applying the same principles to measure total CO2, this study provides a simple and robust alternative which even can be used on smaller sample volumes.

  20. Improving soil CO2 efflux estimates from in-situ soil CO2 sensors with gas transport measurements

    Science.gov (United States)

    Sanchez-Canete, E. P.; Barron-Gafford, G.; Van Haren, J. L. M.; Scott, R. L.

    2015-12-01

    Correctly estimating soil carbon dioxide (CO2) fluxes emitted to the atmosphere is essential because they are a large component of the ecosystem carbon balance. Continuous estimates of soil CO2 flux, especially when paired with eddy covariance measurements of whole-ecosystem CO­2 exchange, help to disaggregate net ecosystem CO2 exchange. Most researchers estimate soil CO2 fluxes by applying the gradient method; however, this is only appropriate in the absence of advective or convective processes. Given the rarity of such static states, we must move toward measurement techniques that will allow us to quantify the dynamic soil efflux system with gas transport by convective, advective and molecular diffusion processes. Convective processes are mainly relevant in caves, where values of relative humidity, temperature and CO2 molar fraction determine the buoyancy of the external-internal air masses. These convective processes also are important in large fractures when temperature differences between surface and depth can generate convection, transporting CO2 from deep layers to the atmosphere. Advective processes occur both in caves and in soils, and the CO2 exchanges are mainly due to three factors: wind, changes in atmospheric pressure, and changes in the water table. Molecular diffusion processes are being widely applied in the determination of soil-atmosphere gas exchanges by applying the gradient method. However, the use of the gradient method can yield inappropriate flux estimates due to the uncertainties mainly associated with the inappropriate determination of the soil diffusion coefficient. Therefore, in-situ methods to determine diffusion coefficient are necessary to obtain accurate CO2 fluxes. If this is resolved, the gradient method has great potential to become the most used technique to monitor atmosphere-soil CO2 exchanges within the next few years. Here we review the state of the science and describe a series of field measurements for significantly