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Sample records for widespread tephra layer

  1. Holocene eruption history in Iceland - Eruption frequency vs. Tephra layer frequency

    Science.gov (United States)

    Oladottir, B. A.; Larsen, G.

    2012-12-01

    Volcanic deposits of all kinds are used to reconstruct eruption history of volcanoes and volcanic zones. In Iceland tephra is the ideal volcanic deposit to study eruption history as two out of every three eruptions taking place there during the last 11 centuries have been explosive, leaving tephra as their only product. If eruptions producing both lava and tephra are included three out of every four eruptions have produced tephra. Tephra dispersal and deposition depends on factors such as eruption magnitude, eruption cloud height, duration of eruption and prevailing wind directions at the time of eruption. Several outcrops around a particular volcano must therefore be measured to obtain optimal information of its eruption history. Vegetation in the area of deposition is also of great importance for its preservation. Tephra deposited on un-vegetated land is rapidly eroded by wind and water, and deposits up to few tens of cm thickness may be lost from the record. Such tephra deposited on grassy or forested land is at least partly sheltered from the wind after deposition. Soon after tephra deposition (how soon depends on tephra thickness) the root system of the vegetation creates an even better shelter for the tephra and when this stage is reached the tephra is preserved in the soil for millennia, given that no soil erosion takes place. Vegetation is often boosted in the first years after tephra deposition which in turn helps tephra preservation. A setback of using soil sections for reconstructing Holocene eruption history is the lack of soil at the beginning of the era but for that time period tephra records in lake and marine sediments can be used. When tephra stratigraphy in soil sections is measured to study eruption history and eruption frequency of a volcano it must be kept in mind that what is seen is in fact the tephra layer frequency. One section only shows tephra layers deposited in that location and more importantly only the layers preserved there. The

  2. Detection of Lateglacial distal tephra layers in the Netherlands

    NARCIS (Netherlands)

    Davies, S.M.; Hoek, W.Z.; Bohncke, S.J.P.; Lowe, J.; Pyne O'Donnle, S.; Turney, C.S.M.

    2005-01-01

    Three distal tephra layers or cryptotephras have been detected within a sedimentary sequence from the Netherlands that spans the last glacial-interglacial transition. Geochemical analyses identify one as the Vedde Ash, which represents the southernmost discovery of this mid-Younger Dryas tephra so

  3. Geochemical fingerprints by activation analysis of tephra layers in Lake Van sediments, Turkey

    Energy Technology Data Exchange (ETDEWEB)

    Landmann, Guenter [Technische Universitaet Darmstadt, Institut fuer Angewandte Geowissenschaften, Schnittspahnstr. 9, 64287 Darmstadt (Germany); Steinhauser, Georg; Sterba, Johannes H. [Vienna University of Technology, Atominstitut, Stadionallee 2, 1020 Vienna (Austria); Kempe, Stephan [Technische Universitaet Darmstadt, Institut fuer Angewandte Geowissenschaften, Schnittspahnstr. 9, 64287 Darmstadt (Germany); Bichler, Max, E-mail: bichler@ati.ac.a [Vienna University of Technology, Atominstitut, Stadionallee 2, 1020 Vienna (Austria)

    2011-07-15

    We discuss geochemical and sedimentological characteristics of 12 tephra layers, intercalated within the finely laminated sediments of Lake Van. Within the about 15 kyr long sediment record studied, volcanic activity concentrated in the periods 2.6-7.2 and 11.9-12.9 kyr B.P. Concentrations of 25 elements provide the geochemical fingerprint of each tephra layer and allow comparison to literature values of potential source volcanoes such as Mts. Nemrut and Suephan. The youngest two tephra layers (and probably also the other three ashes from the 2.6-7.2 kyr B.P. eruptions) originate from the Nemrut volcano. The source of the older tephra (11.9-12.9 kyr B.P.), however, remains unidentified.

  4. Grain size and shape analysis of the AD 1226 tephra layer, Reykjanes volcanic system

    Science.gov (United States)

    Ösp Magnúsdóttir, Agnes; Höskuldsson, Ármann; Larsen, Guðrún; Tumi Guðmunsson, Magnús; Sigurgeirsson, Magnús Á.

    2014-05-01

    Recent explosive eruptions in Iceland have drawn attention to long range tephra transport in the atmosphere. In Iceland tephra forming explosion eruptions are frequent, due to abundance of water. However, the volcanism on the island is principally basaltic. Volcanism along the Reykjanes Peninsula is divided into five distinct volcanic systems. Volcano-tectonic activity within these systems is periodic, with recurrence intervals in the range of 1 ka. Last volcano-tectonic sequence began around AD 940, shortly after settlement of Iceland, and lasted through AD 1340. During this period activity was characterized by basaltic fissure eruptions. Furthermore, this activity period on the Reykjanes peninsula began within the eastern most volcanic system and gradually moved towards the west across the peninsula. The 1226 eruption was a basaltic fissure eruption with in the Reykjanes volcanic system. The eruption began on land and gradually progressed towards the SW until the volcanic fissure extended into the sea. Water-magma interaction changed the eruption from effusive into explosive forming the largest tephra layer on the peninsula. Due to its close proximity to the Keflavik international airport and that of the capital of Iceland it is important to get an insight into, the characteristics, generation and distribution of such tephra deposits. In this eruption the tephra produced had an approximate volume of 0.1 km3 and covered an area of some 3500 km2 within the 0.5 cm isopach. Total grain size distribution of this tephra layer will be presented along with analysis of principal grain shapes of the finer portion of the tephra layer as a function of distance from the source. The tephra grain size is dominated by particles finer than 1 millimeter with an almost complete absence of large grains independent of distance from the source. Comprehensive understanding of the characteristics of tephra generated in this eruption can help us to understand hazards posed by future

  5. Geochemical Characterization of Late Pleistocene and Holocene Tephra Layers from the Basin of Mexico, Central Mexico

    Science.gov (United States)

    Ortega-Guerrero, Beatriz; Newton, Anthony J.

    1998-07-01

    In order to aid palaeoenvironmental research of Late Pleistocene and Holocene deposits of central Mexico, tephra layers collected from the sediments of the Texcoco and Chalco sub-basins, in the southern part of the Basin of Mexico, are geochemically characterized and used as stratigraphic markers. The tephra layers range in composition from basaltic andesites to rhyolites and are calc-alkaline. The tephras range in age from >34,000 to ca. 2600 14C yr B.P. New names are used informally to designate correlated tephras. The Tlahuac tephra is present in Chalco, at a depth of 18 m; in the southeastern part of Texcoco, at a depth of around 10 m; and at the Tlapacoya archaeological site, where it had been mistakenly described as basaltic. This basalt-andesite tephra is dated to at least 34,000 14C yr B.P. The Tlapacoya 1 tephra is dated to between 15,020 ± 450 and 14,430 ± 190 yr B.P. and is present in all Chalco sections. The Tlapacoya 2 tephra corresponds to the previously described "pomez gruesa con fragmentos de andesita" (ca. 14,400 yr B.P.) and is present in all Chalco and Texcoco sections. The likely source of these three tephras is the volcano Popocatepetl. Tephra II at Chalco dates to 12,520 ± 135 yr B.P. and correlates with the Upper Toluca Pumice from Nevado de Toluca volcano. These represent the first geochemical glass-shard analysis of tephras from the Basin of Mexico, and so further research is necessary before a reliable tephrochronology can be established.

  6. Radiocarbon Ages and Environments of Deposition of the Wono and Trego Hot Springs Tephra Layers in the Pyramid Lake Subbasin, Nevada

    Science.gov (United States)

    Benson, L.V.; Smoot, J.P.; Kashgarian, Michaele; Sarna-Wojcicki, A.; Burdett, J.W.

    1997-01-01

    Uncalibrated radiocarbon data from core PLC92B taken from Wizards Cove in the Pyramid Lake subbasin indicate that the Trego Hot Springs and Wono tephra layers were deposited 23,200 ?? 300 and 27,300 ??300 14C yr B.P. (uncorrected for reservoir effect). Sedimentological data from sites in the Pyramid Lake and Smoke Creek-Black Rock Desert subbasins indicate that the Trego Hot Springs tephra layer was deposited during a relatively dry period when Pyramid Lake was at or below its spill point (1177 m) to the Winnemucca Lake subbasin. The Wono tephra layer was deposited when lake depth was controlled by spill across Emerson Pass sill (1207 m) to the Smoke Creek-Black Rock Desert subbasin. 18O data from core PLC92B also support the concept that the Trego Hot Springs tephra fell into a relatively shallow Pyramid Lake and that the Wono tephra fell into a deeper spilling lake. ?? 1997 University of Washington.

  7. Tephrostratigraphy and Provenance From IODP Expedition 352, Izu-Bonin Arc: Tracing Tephra Sources and Volumes From the Oligocene to Recent

    Science.gov (United States)

    Kutterolf, S.; Schindlbeck, J. C.; Robertson, A. H. F.; Avery, A.; Baxter, A. T.; Petronotis, K.; Wang, K.-L.

    2018-01-01

    Provenance studies of widely distributed tephras, integrated within a well-defined temporal framework, are important to deduce systematic changes in the source, scale, distribution, and changes in regional explosive volcanism. Here, we establish a robust tephrochronostratigraphy for a total of 157 marine tephra layers collected during IODP Expedition 352. We infer at least three major phases of highly explosive volcanism during Oligocene to Pleistocene time. Provenance analysis based on glass composition assigns 56 of the tephras to a Japan source, including correlations with 12 major and widespread tephra layers resulting from individual eruptions in Kyushu, Central Japan, and North Japan between 115 ka and 3.5 Ma. The remaining 101 tephras are assigned to four source regions along the Izu-Bonin arc. One, exclusively assigned to the Oligocene age, is proximal to the Bonin Ridge islands; two reflect eruptions within the volcanic front and back-arc of the central Izu-Bonin arc, and a fourth region corresponds to the Northern Izu-Bonin arc source. First-order volume estimates imply eruptive magnitudes ranging from 6.3 to 7.6 for Japan-related eruptions and between 5.5 and 6.5 for IBM eruptions. Our results suggest tephras between 30 and 22 Ma reflect a subtly different Izu-Bonin chemical signature compared to the recent arc. After a ˜9 Ma gap in eruption, tephra supply from the Izu-Bonin arc predominated from 15 to 5 Ma, and finally a subequal mixture of tephra sources from the (palaeo)Honshu and Izu-Bonin arcs occured within the last ˜5 Ma.

  8. Modeled tephra ages from lake sediments, base of Redoubt Volcano, Alaska

    Energy Technology Data Exchange (ETDEWEB)

    Schiff, C J; Kaufman, D S; Wallace, K L; Werner, A; Ku, T L; Brown, T A

    2007-02-25

    A 5.6-m-long lake sediment core from Bear Lake, Alaska, located 22 km southeast of Redoubt Volcano, contains 67 tephra layers deposited over the last 8750 cal yr, comprising 15% of the total thickness of recovered sediment. Using 12 AMS {sup 14}C ages, along with the {sup 137}Cs and {sup 210}Pb activities of recent sediment, we evaluated different models to determine the age-depth relation of sediment, and to determine the age of each tephra deposit. The age model is based on a cubic smooth spline function that was passed through the adjusted tephra-free depth of each dated layer. The estimated age uncertainty of the 67 tephras averages {+-} 105 yr (1{sigma}). Tephra-fall frequency at Bear Lake was among the highest during the past 500 yr, with eight tephras deposited compared to an average of 3.7 per 500 yr over the last 8500 yr. Other periods of increased tephra fall occurred 2500-3500, 4500-5000, and 7000-7500 cal yr. Our record suggests that Bear Lake experienced extended periods (1000-2000 yr) of increased tephra fall separated by shorter periods (500-1000 yr) of apparent quiescence. The Bear Lake sediment core affords the most comprehensive tephrochronology from the base of the Redoubt Volcano to date, with an average tephra-fall frequency of once every 130 yr.

  9. The ELSA tephra stack: Volcanic activity in the Eifel during the last 500,000 years

    Science.gov (United States)

    Förster, Michael W.; Sirocko, Frank

    2016-07-01

    Tephra layers of individual volcanic eruptions are traced in several cores from Eifel maar lakes, drilled between 1998 and 2014 by the Eifel Laminated Sediment Archive (ELSA). All sediment cores are dated by 14C and tuned to the Greenland interstadial succession. Tephra layers were characterized by the petrographic composition of basement rock fragments, glass shards and characteristic volcanic minerals. 10 marker tephra, including the well-established Laacher See Tephra and Dümpelmaar Tephra can be identified in the cores spanning the last glacial cycle. Older cores down to the beginning of the Elsterian, show numerous tephra sourced from Strombolian and phreatomagmatic eruptions, including the 40Ar/39Ar dated differentiated tephra from Glees and Hüttenberg. In total, at least 91 individual tephra can be identified since the onset of the Eifel volcanic activity at about 500,000 b2k, which marks the end of the ELSA tephra stack with 35 Strombolian, 48 phreatomagmatic and 8 tephra layers of evolved magma composition. Many eruptions cluster near timings of the global climate transitions at 140,000, 110,000 and 60,000 b2k. In total, the eruptions show a pattern, which resembles timing of phases of global sea level and continental ice sheet changes, indicating a relation between endogenic and exogenic processes.

  10. Holocene tephra deposits in the northern Okinawa Trough

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    The mineralogical and geochemical characteristics of sediments of Core CSH1, which was collected from the northern Okinawa Trough, indicate that large amounts of volcanic materials have deposited in the northern Okinawa Trough during the Holocene. On the basis of down-core variations in mineral and element contents of sediments, two layers in the uppermost section of Core CSH1 characterized by high quartz, Na2O, MnO, K2O, uranium contents and low contents of clay minerals, volatiles, Fe2O3, MgO, CaO and strontium, have been identified as the tephra deposits. Systematic grain-size measurements also suggest that sediments from the northern Okinawa Trough are made up of terrigenous materials and volcanic ashes with different proportion during the Holocene. The sediments of tephra layers in Core CSH1 show bi-modal patterns in grain-size distribution with modal grain-sizes of 74.3 and 7.81 μm,respectively. According to the radiocarbon dating on shells of zooplankton foraminifera, two tephra layers in Core CSH1, formed at 7 250 and 10 870 a BP (cal), approximately correspond to the K-Ah tephra [7 300 a BP (cal)] and the eruption of Kuju Volcano (12~10 ka BP), respectively.

  11. The Mount Edgecumbe tephra deposits, a marker horizon in southeastern Alaska near the Pleistocene-Holocene boundary

    Science.gov (United States)

    Riehle, J.R.; Mann, D.H.; Peteet, D.M.; Engstrom, D.R.; Brew, D.A.; Meyer, C.E.

    1992-01-01

    Late Pleistocene tephra deposits found from Sitka to Juneau and Lituya Bay are assigned to a source at the Mount Edgecumbe volcanic field, based on similarity of glass compositions to nearvent deposits and on thinning away from Kruzof Island. The sequence of near-vent layers is basaltic andesite and andesite at the base, rhyolite, and mixed dacite and rhyolite on top. The only breaks in the tephra sequence are two 1-mm-thick silt partings in a lake-sediment core, indicating a depositional interval from basaltic andesite to dacite of no more than about a millennium. Tephra deposits at sites >30 km from the vent are solely dacite and rhyolite and are 10,600 to 11,400 14C yr old based on interpretation of 18 radiocarbon ages, including 5 by accelerator mass spectrometry (AMS). Basaltic andesite and andesite deposits nearer the vent are as much as 12,000 yr old. Discrepancy among radiocarbon ages of upland tephra deposits provisionally correlated as the same grainfall is resolvable within ??2 ?? of analytical uncertainty. Comparison of bulk and AMS ages in one sediment core indicates a systematic bias of +600 to +1100 yr for the bulk ages; correlation of tephra deposits among upland and lacustrine sites implies an additional discrepancy of 200-400 yr between upland (relatively too young) and lacustrine ages. In any case, the Mount Edgecumbe tephra deposits are a widespread, latest Pleistocene stratigraphic marker that serves to emphasize the uncertainty in dating biogenic material from southeastern Alaska. ?? 1992.

  12. Improvements in the chronology, geochemistry and correlation techniques of tephra in Antarctic ice

    Science.gov (United States)

    Iverson, N. A.; Dunbar, N. W.; McIntosh, W. C.; Pearce, N. J.; Kyle, P. R.

    2013-12-01

    Visible and crypto tephra layers found in West Antarctic ice provide an excellent record of Antarctic volcanism over the past 100ka. Tephra layers are deposited almost instantaneously across wide areas creating horizons that, if found in several locations, provide 'pinning points' to adjust ice time scales that may otherwise be lacking detailed chronology. Individual tephra layers can have distinct chemical fingerprints allowing them to correlate over great distances. Advances in sample preparation, geochemical analyses (major and trace elements) of fine grained tephra and higher precision 40Ar/39Ar dating of young (typically too small to be directly dated by 40Ar/39Ar method, making it very important to geochemically correlate these layers to proximal deposits where more and larger feldspar can be sampled. The correlation of WDC06A-2767.117 to the coarse, proximal BIT-152 provides one such link. The New Mexico Geochronology Research Lab (NMGRL) has two new multi-collector ARGUS VI mass spectrometers that can provide single crystal laser fusion ages that are approximately an order of magnitude more precise than the previous determinations. With these advancements in analytical technology, we hope to improve precision on 'pinning points' in the deep ice cores where annual layer counting becomes less precise.

  13. The eruption history of the quaternary Eifel volcanic fields: Implications from the ELSA - Tephra - Stack

    Science.gov (United States)

    Förster, Michael; Sirocko, Frank

    2015-04-01

    Numerous tephra layers occur in maar sediments in the quaternary Eifel volcanic fields. The sediments were systematically drilled and cored since 1998 by the Eifel Laminated Sediment Archive project (ELSA) (Sirocko et al. 2013). These maar sediments are laminated and the tephra is easily recognizeable by a coarser grain size. Additionaly, tephra layers appear dark grey to black in color. The ashes were sieved to a fraction of 250 - 100 µm and sorted into grains of: reddish and greyish sandstone, quartz, amphibole, pyroxene, scoria and pumice, sanidine, leucite and biotite. A minimum of 100 grains for each tephra layer were used for a sediment petrographic tephra characterisation (SPTC). The grain counts resemble the vol. -% of each grain species. Three types of tephra could be identified by their distinctive grain pattern: (1) phreatomagmatic tephra, rich in basement rocks like greyish/reddish sandstone and quartz. (2) Strombolian tephra, rich in scoria and mafic minerals like pyroxene. (3) evolved tephra, rich in sanidine and pumice. 16 drill-cores, covering the last 500 000 years have been examined. Younger cores were dated by 14C ages and older cores by optical stimulated luminescence. Independently from this datings, the drill-cores were cross-correlated by pollen and the occurences of specific marker-tephra layers, comprising characteristic grain-types. These marker-tephra layers are especially thick and of evolved composition with a significant abundance of sanidine and pumice. The most prominent tephra layers of this type are the Laacher See tephra, dated to 12 900 b2k by Zolitschka (1998), the 40Ar/39Ar dated tephra layers of Dümpelmaar, Glees and Hüttenberg, dated to 116 000 b2k, 151 000 b2k and 215 000 b2k by van den Bogaard & Schmincke (1990), van den Bogaard et al. (1989). These datings set the time-frame for the eruption-phases of the quaternary Eifel Volcanic Fields. Our study refines these findings and shows that phases of activity are very

  14. Geochemical signatures of tephras from Quaternary Antarctic Peninsula volcanoes

    OpenAIRE

    Kraus,Stefan; Kurbatov,Andrei; Yates,Martin

    2013-01-01

    In the northern Antarctic Peninsula area, at least 12 Late Plelstocene-Holocene volcanic centers could be potential sources of tephra layers in the region. We present unique geochemical fingerprints for ten of these volcanoes using major, trace, rare earth element, and isotope data from 95 samples of tephra and other eruption products. The volcanoes have predominantly basaltic and basaltic andesitic compositions. The Nb/Y ratio proves useful to distinguish between volcanic centers located on ...

  15. Eruptive history and magmatic stability of Erebus volcano, Antarctica: Insights from englacial tephra

    Science.gov (United States)

    Iverson, N. A.; Kyle, P. R.; Dunbar, N. W.; Pearce, N. J.

    2012-12-01

    Erebus is the most active volcano in Antarctica and hosts a persistent convecting and degassing phonolite lava lake in its summit crater. Small Strombolian eruptions occasionally eject volcanic bombs onto the crater rim and floor. 40 years of observations, during the austral summer, show that ash eruptions are rare, but extensive records of small tephra (volcanic ash) layers are found embedded in ablating blue ice areas on the flanks of the volcano. Most tephra are deposited within 15km of the summit, although 3 Erebus phonolite tephra have been located over 200km away. The tephra provide a stratigraphic eruptive sequence of Erebus and gives insight into its explosive history. There is very little age control on the eruptions but based on their phonolitic composition they likely span the past 10-40ka. SEM images and Image Particle Analysis (IPA) of tephra were used to determine shard morphology and shape parameters, respectively. The tephra layers characterized by Pele's hair, glass spheres and budding ash are interpreted to be from Strombolian eruptions. In contrast, layers that are dominated by chemical pitting, quenched textures, mossy and adhering particles are mostly likely from phreatomagmatic eruptions. IPA parameters are characterized by rectangularity, compactness, elongation and circularity. Strombolian particles have larger elongation and circularity values exhibited by their stretched and irregular shape and lower rectangularity and compactness values. Phreatomagmatic tephra are more blocky and have higher rectangularity and compactness values and lower elongation and circularity values than Strombolian particles. Based on imagery, many Erebus tephra layers appear to contain a mixture of Strombolian and phreatomagmatic fragments. These mixed eruptions would likely start as phreatomagmatic and transition into magmatic Strombolian eruptions as the water source is exhausted. Major and trace element analyses of the glass shards were measured by electron

  16. Tools and techniques for developing tephra stratigraphies in lake cores: A case study from the basaltic Auckland Volcanic Field, New Zealand

    Science.gov (United States)

    Hopkins, Jenni L.; Millet, Marc-Alban; Timm, Christian; Wilson, Colin J. N.; Leonard, Graham S.; Palin, J. Michael; Neil, Helen

    2015-09-01

    Probabilistic hazard forecasting for a volcanic region relies on understanding and reconstructing the eruptive record (derived potentially from proximal as well as distal volcanoes). Tephrostratigraphy is commonly used as a reconstructive tool by cross-correlating tephra deposits to create a stratigraphic framework that can be used to assess magnitude-frequency relationships for eruptive histories. When applied to widespread rhyolitic deposits, tephra identifications and correlations have been successful; however, the identification and correlation of basaltic tephras are more problematic. Here, using tephras in drill cores from six maars in the Auckland Volcanic Field (AVF), New Zealand, we show how X-ray density scanning coupled with magnetic susceptibility analysis can be used to accurately and reliably identify basaltic glass shard-bearing horizons in lacustrine sediments and which, when combined with the major and trace element signatures of the tephras, can be used to distinguish primary from reworked layers. After reliably identifying primary vs. reworked basaltic horizons within the cores, we detail an improved method for cross-core correlation based on stratigraphy and geochemical fingerprinting. We present major and trace element data for individual glass shards from 57 separate basaltic horizons identified within the cores. Our results suggest that in cases where major element compositions (SiO2, CaO, Al2O3, FeO, MgO) do not provide unambiguous correlations, trace elements (e.g. La, Gd, Yb, Zr, Nb, Nd) and trace element ratios (e.g. [La/Yb]N, [Gd/Yb]N, [Zr/Yb]N) are successful in improving the compositional distinction between the AVF basaltic tephra horizons, thereby allowing an improved eruptive history of the AVF to be reconstructed.

  17. New accelerator mass spectrometry radiocarbon ages for the Mazama tephra layer from Kootenay National Park, British Columbia, Canada

    International Nuclear Information System (INIS)

    Hallett, D.J.; Hills, L.V.; Clague, J.J.

    1997-01-01

    Charcoal fragments recovered from the Mazama air-fall tephra layer in cores from Dog and Cobb lakes, Kootenay National Park, British Columbia, yielded accelerator mass spectrometry ages of 6720 ± 70 and 6760 ± 70 14 C years BP, respectively. These two new ages, together with other previously published radiocarbon ages on charcoal and twig fragments from Mazama air-fall deposits, indicate that the climatic eruption of Mount Mazama occurred 6730 ± 40 14 C years BP. (author)

  18. Best-practice checklists for tephra collection, analysis and reporting - a draft consensus from the Tephra 2014 workshop

    Science.gov (United States)

    Wallace, K.; Bursik, M. I.; Kuehn, S. C.

    2015-12-01

    The Tephra 2014 Workshop (3-7 August 2014) discussed major developments, best practices, future directions, and critical needs in tephra studies from both volcanological and tephrochronological perspectives. In a consensus-seeking session held at the end of the workshop, the international group of over 70 tephra scientists focused on two complementary themes: (A) the need for common best practices in tephra data collection and reporting among different scientific disciplines, and (B) the need to establish common, accessible mechanisms for tephra data archiving and retrieval. Tephra is the focus of a wide range of research in volcanology, petrology, tephrochronology and tephrostratigraphy (with applications in studies of environmental/climate change, surface processes, paleolimnology, etc.), ash dispersion and fallout modeling, and archaeology, paleoanthropology, and human origins. Researchers in each field have specific objectives that may or may not overlap. The focus on best practices is a first step towards standardized protocols for the collection, analysis and reporting of tephra data across and within disciplines. Such uniformity will facilitate the development and population of useful tephra databases. Current initiatives include the development of best practice checklists as a starting point for ensuring uniformity and completeness. The goals of the checklists are to: 1) ensure consistency among tephra scientists, regardless of research focus, 2) provide basic, comprehensible, metadata requirements, especially those who collect tephra as a peripheral part of their research, 3) help train students, and 4) help journal editors to know which essential metadata should be included in published works. Consistency in tephra sample collection, analysis, and reporting attained by use of these checklists should ultimately aid in improving correlation of tephras across geographically large areas, and facilitate collaborative tephra research. Current and future

  19. Rootless tephra stratigraphy and emplacement processes

    Science.gov (United States)

    Hamilton, Christopher W.; Fitch, Erin P.; Fagents, Sarah A.; Thordarson, Thorvaldur

    2017-01-01

    Volcanic rootless cones are the products of thermohydraulic explosions involving rapid heat transfer from active lava (fuel) to external sources of water (coolant). Rootless eruptions are attributed to molten fuel-coolant interactions (MFCIs), but previous studies have not performed systematic investigations of rootless tephrostratigraphy and grain-size distributions to establish a baseline for evaluating relationships between environmental factors, MFCI efficiency, fragmentation, and patterns of tephra dispersal. This study examines a 13.55-m-thick vertical section through an archetypal rootless tephra sequence, which includes a rhythmic succession of 28 bed pairs. Each bed pair is interpreted to be the result of a discrete explosion cycle, with fine-grained basal material emplaced dominantly as tephra fall during an energetic opening phase, followed by the deposition of coarser-grained material mainly as ballistic ejecta during a weaker coda phase. Nine additional layers are interleaved throughout the stratigraphy and are interpreted to be dilute pyroclastic density current (PDC) deposits. Overall, the stratigraphy divides into four units: unit 1 contains the largest number of sediment-rich PDC deposits, units 2 and 3 are dominated by a rhythmic succession of bed pairs, and unit 4 includes welded layers. This pattern is consistent with a general decrease in MFCI efficiency due to the depletion of locally available coolant (i.e., groundwater or wet sediments). Changing conduit/vent geometries, mixing conditions, coolant and melt temperatures, and/or coolant impurities may also have affected MFCI efficiency, but the rhythmic nature of the bed pairs implies a periodic explosion process, which can be explained by temporary increases in the water-to-lava mass ratio during cycles of groundwater recharge.

  20. The 1845 Hekla eruption: Grain-size characteristics of a tephra layer

    Science.gov (United States)

    Gudnason, Jonas; Thordarson, Thor; Houghton, Bruce F.; Larsen, Gudrun

    2018-01-01

    The 1845 eruption is commonly viewed as a typical Hekla eruption. It is a key event in the eruptive history of the volcano, as it is one of the best documented Hekla eruptions, in terms of contemporary accounts and observations. The eruption started on 2 September 1845 with an intense, hour long explosive Plinian phase that passed into effusive activity, ending on the 16 March 1846. The amount of tephra produced in the opening phase was 0.13 km3/7.5 × 1010 kg. The total grain-size distribution of the deposit is bimodal with a dominant coarse mode at - 2.5 φ (5.6 mm) and a broad finer mode at 3 to 4.5 φ (0.125 to 0.045 mm). At individual sites, the grain-size distribution of the tephra from the Plinian opening phase is also commonly (not always) bimodal. Deconvolved grain-size distributions exhibit distinctly different sedimentation patterns of the coarse and fine subpopulations. The lapilli-dominated subpopulation fines rapidly with transport, while the ash-dominated subpopulation shows less changes with distance, indicating premature sedimentation of fines by aggregation from the 1845 volcanic plume. Tephra deposition was to the ESE of the volcano from a 19 km (a.s.l.) high eruption plume. The plume front travelled at speeds of 16-19 m s- 1. Reports of ash deposition onto ships near the Faroe and Shetland Islands, 700 to 1100 km away from Hekla, demonstrate that even moderate-sized Hekla eruptions can affect very large parts of European air-space.

  1. Tephra Fallout Hazard Assessment for VEI5 Plinian Eruption at Kuju Volcano, Japan, Using TEPHRA2

    Science.gov (United States)

    Tsuji, Tomohiro; Ikeda, Michiharu; Kishimoto, Hiroshi; Fujita, Koji; Nishizaka, Naoki; Onishi, Kozo

    2017-06-01

    Tephra fallout has a potential impact on engineered structures and systems at nuclear power plants. We provide the first report estimating potential accumulations of tephra fallout as big as VEI5 eruption from Kuju Volcano and calculated hazard curves at the Ikata Power Plant, using the TEPHRA2 computer program. We reconstructed the eruptive parameters of Kj-P1 tephra fallout deposit based on geological survey and literature review. A series of parameter studies were carried out to determine the best values of empirical parameters, such as diffusion coefficient and the fall time threshold. Based on such a reconstruction, we represent probabilistic analyses which assess the variation in meteorological condition, using wind profiles extracted from a 22 year long wind dataset. The obtained hazard curves and probability maps of tephra fallout associated to a Plinian eruption were used to discuss the exceeding probability at the site and the implications of such a severe eruption scenario.

  2. Disruption of tephra fall deposits caused by lava flows during basaltic eruptions

    Science.gov (United States)

    Brown, R. J.; Thordarson, T.; Self, S.; Blake, S.

    2015-10-01

    Observations in the USA, Iceland and Tenerife, Canary Islands reveal how processes occurring during basaltic eruptions can result in complex physical and stratigraphic relationships between lava and proximal tephra fall deposits around vents. Observations illustrate how basaltic lavas can disrupt, dissect (spatially and temporally) and alter sheet-form fall deposits. Complexity arises through synchronous and alternating effusive and explosive activity that results in intercalated lavas and tephra deposits. Tephra deposits can become disrupted into mounds and ridges by lateral and vertical displacement caused by movement (including inflation) of underlying pāhoehoe lavas and clastogenic lavas. Mounds of tephra can be rafted away over distances of 100 s to 1,000 s m from proximal pyroclastic constructs on top of lava flows. Draping of irregular topography by fall deposits and subsequent partial burial of topographic depressions by later lavas can result in apparent complexity of tephra layers. These processes, deduced from field relationships, have resulted in considerable stratigraphic complexity in the studied proximal regions where fallout was synchronous or alternated with inflation of subjacent lava sheets. These mechanisms may lead to diachronous contact relationships between fall deposits and lava flows. Such complexities may remain cryptic due to textural and geochemical quasi-homogeneity within sequences of interbedded basaltic fall deposits and lavas. The net effect of these processes may be to reduce the usefulness of data collected from proximal fall deposits for reconstructing basaltic eruption dynamics.

  3. Connecting with tephras: principles, functioning, and applications of tephrochronology in Quaternary science

    International Nuclear Information System (INIS)

    Lowe, D.J.

    2014-01-01

    Tephrochronology is a unique method for linking and dating geological, palaeoecological, palaeoclimatic or archaeological sequences or events. The method relies firstly and fundamentally on stratigraphy and the law of superposition, which apply in any study that connects or correlates deposits from one place to another. Secondly, it relies on characterising and hence identifying or 'fingerprinting' tephra layers using either physical properties evident in the field or those obtained from laboratory analysis, including mineralogical examination by optical microscopy or geochemical analysis of glass shards or crystals (e.g. Fe-Ti oxides, ferromagnesian minerals) using the electron microprobe and other tools. Thirdly, the method is enhanced when a numerical age is obtained for a tephra layer by (1) radiometric methods such as radiocarbon, fission-track, U-series, or Ar/Ar dating, (2) incremental dating methods including dendrochronology or varved sediments or layering in ice cores, or (3) age-equivalent methods such as palaeomagnetism or correlation with marine oxygen isotope stages or palynostratigraphy. Once known, that age can be transferred from one site to the next using stratigraphic methods and by matching compositional characteristics, i.e. comparing 'fingerprints' from each layer. Used this way, tephrochronology is an age-equivalent dating method. (author)

  4. Ages of 24 widespread tephras erupted since 30,000 years ago in New Zealand, with re-evaluation of the timing and palaeoclimatic implications of the Lateglacial cool episode recorded at Kaipo bog

    Science.gov (United States)

    Lowe, David J.; Blaauw, Maarten; Hogg, Alan G.; Newnham, Rewi M.

    2013-08-01

    Tephras are important for the NZ-INTIMATE project because they link all three records comprising the composite inter-regional stratotype developed for the New Zealand climate event stratigraphy (NZ-CES). Here we firstly report new calendar ages for 24 widespread marker tephras erupted since 30,000 calendar (cal.) years ago in New Zealand to help facilitate their use as chronostratigraphic dating tools for the NZ-CES and for other palaeoenvironmental and geological applications. The selected tephras comprise 12 rhyolitic tephras from Taupo, nine rhyolitic tephras from Okataina, one peralkaline rhyolitic tephra from Tuhua, and one andesitic tephra each from Tongariro and Egmont/Taranaki volcanic centres. Age models for the tephras were obtained using three methods: (i) 14C-based wiggle-match dating of wood from trees killed by volcanic eruptions (these dates published previously); (ii) flexible depositional modelling of a high-resolution 14C-dated age-depth sequence at Kaipo bog using two Bayesian-based modelling programs, Bacon and OxCal's P_Sequence function, and the IntCal09 data set (with SH offset correction -44 ± 17 yr); and (iii) calibration of 14C ages using OxCal's Tau_Boundary function and the SHCal04 and IntCal09 data sets. Our preferred dates or calibrated ages for the 24 tephras are as follows (youngest to oldest, all mid-point or mean ages of 95% probability ranges): Kaharoa AD 1314 ± 12; Taupo (Unit Y) AD 232 ± 10; Mapara (Unit X) 2059 ± 118 cal. yr BP; Whakaipo (Unit V) 2800 ± 60 cal. yr BP; Waimihia (Unit S) 3401 ± 108 cal. yr BP; Stent (Unit Q) 4322 ± 112 cal. yr BP; Unit K 5111 ± 210 cal. yr BP; Whakatane 5526 ± 145 cal. yr BP; Tuhua 6577 ± 547 cal. yr BP; Mamaku 7940 ± 257 cal. yr BP; Rotoma 9423 ± 120 cal. yr BP; Opepe (Unit E) 9991 ± 160 cal. yr BP; Poronui (Unit C) 11,170 ± 115 cal. yr BP; Karapiti (Unit B) 11,460 ± 172 cal. yr BP; Okupata 11,767 ± 192 cal. yr BP; Konini (bed b) 11,880 ± 183 cal. yr BP; Waiohau 14,009 ± 155

  5. Fate and agricultural consequences of leachable elements added to the environment from the 2011 Cordón Caulle tephra fall

    Science.gov (United States)

    Stewart, Carol; Craig, Heather M.; Gaw, Sally; Wilson, Thomas; Villarosa, Gustavo; Outes, Valeria; Cronin, Shane; Oze, Christopher

    2016-11-01

    The June 2011 eruption of Cordón Caulle volcano, Chile, dispersed tephra over 350,000 km2, including productive agricultural land. This resulted in the death of nearly one million livestock. Two distinct environments were affected: a proximal temperate Andean setting, and the semi-arid Argentine steppe farther from the volcano. The purpose of this study was to better understand the fate and agricultural consequences of leachable elements added to the environment by this large silicic tephra fall. Tephra, soil and surface water samples across the depositional area were collected both immediately after the eruption (tephra and water) and nine months afterwards (tephra, soil and water). Tephra samples were analysed following a new hazard assessment protocol developed by the International Volcanic Health Hazard Network (IVHHN). Water-extractable element concentrations in freshly-collected tephra were very low to low compared to other eruptions, and showed no trends with distance from the volcano. Surface water analyses suggested short-term changes to water composition due to the release of elements from tephra. No effect on the fertility of soils underlying tephra was apparent after nine months. Water-extractable fluorine (F) in freshly-collected tephra ranged from 12 to 167 mg/kg, with a median value of 67 mg/kg. Based on parallels with the 11-12 October 1995 eruption of Ruapehu volcano, New Zealand, we conclude that F toxicity was a possible contributing factor to the large-scale livestock deaths as well as to chronic fluorosis widely reported in wild deer populations across the Cordón Caulle tephra depositional area. Finally, we recommend that effective response to widespread tephra fall over agricultural areas should include: (1) rapid, statistically representative field sampling of tephra, soils, surface water supplies and forage crops; (2) analysis using appropriate and reliable laboratory methods; (3) modelling both short and long-term impacts on the ecosystem

  6. Connecting with tephras : principles, functioning, and applications of tephrochronology in Quaternary science

    International Nuclear Information System (INIS)

    Lowe, D.J.

    2013-01-01

    Tephrochronology is a unique method for linking and dating geological, palaeoecological, palaeoclimatic or archaeological sequences or events. The method relies firstly and fundamentally on stratigraphy and the law of superposition, which apply in any study that connects or correlates deposits from one place to another. Secondly, it relies on characterising and hence identifying or 'fingerprinting' tephra layers using either physical properties evident in the field or those obtained from laboratory analysis, including mineralogical examination by optical microscopy or geochemical analysis of glass shards or crystals (e.g. Fe-Ti oxides, ferromagnesian minerals) using the electron microprobe and other tools. Thirdly, the method is enhanced when a numerical age is obtained for a tephra layer by (1) radiometric methods such as radiocarbon, fission-track, U-series, or Ar/Ar dating, (2) incremental dating methods including dendrochronology or varved sediments or layering in ice cores, or (3) age-equivalent methods such as palaeomagnetism or correlation with marine oxygen isotope stages or palynostratigraphy. Once known, that age can be transferred from one site to the next using stratigraphic methods and by matching compositional characteristics, i.e. comparing 'fingerprints' from each layer. Used this way, tephrochronology is an age-equivalent dating method. (author). 150 refs., 13 figs., 5 tabs.

  7. First identification and characterization of Borrobol-type tephra in the Greenland ice cores

    DEFF Research Database (Denmark)

    Cook, Eliza; Davies, Siwan M.; Guðmundsdóttir, Esther R.

    2018-01-01

    in the ice-cores or that it relates to just one of the ice-core events. A firm correlation cannot be established at present due to their strong geochemical similarities. The older tephra horizon, found within all three ice-cores and dated to 17326 ± 319 a b2k, can be correlated to a known layer within marine....... The older deposit is consistent with BT age estimates derived from Scottish sites, while the younger deposit overlaps with both BT and PT age estimates. We suggest that either the BT in Northern European terrestrial sequences represents an amalgamation of tephra from both of the GI-1e events identified...

  8. Connecting the records: exploiting tephra deposits to help understand abrupt climate change

    Science.gov (United States)

    Davies, S. M.; Abbott, P. M.; Bourne, A. J.; Chapman, M.; Pearce, N. J. G.; Griggs, A. J.; Cook, E.

    2016-12-01

    The causal mechanism of abrupt climate change during the last glacial period remains a key challenge. Although these events are well-documented in a wide range of proxy records, the triggers and drivers remain poorly understood, largely due to the dating uncertainties that prevent the integration of different archives. Unravelling the lead/lag responses (hence cause and effect) between the Earth's climate components is limited by the challenges of synchronising palaeoclimate records on a common timescale. Here we present the potential and the challenges of optimising the use of cryptotephra deposits to precisely correlate the Greenland ice-cores with North Atlantic marine records. A series of new cryptotephra deposits have been identified in Greenland, increasing the scope of identifying coeval isochrons in the marine environment. This new framework, however, brings new challenges in the search for unique and robust geochemical fingerprints for unequivocal tephra correlations. As such, some tephra deposits are proposed to be more valuable than others and underpin key snapshots in time during the last glacial period. The North Atlantic Ash Zone II, for instance, represents the most widespread isochron and constrains the cooling of GI-15. Some tephra deposits in the ice-core record originate from ultra-distal sources beyond the North Atlantic region and we also explore the potential for establishing North Pacific linkages.

  9. Analysis of volcanic tephra as a material of environment

    Science.gov (United States)

    Sitek, J.; Dekan, J.; Fang, X.; Xiaoli, P.; Chmielewská, E.

    2012-10-01

    Tephra is a fragmental material produced by volcanic eruption. Here, volcanic tephra deposit from the northeast of China was used for our study. Samples of unaltered tephra are usually composed of feldspar, glass, pyroxene, and olivine. Moreover, these volcanic alteration products also contain Fe oxides, phylosilicates, sulfates, and amorphous Al-Si-bearing material. Six different samples of tephra obtained were analyzed by Mössbauer spectroscopy. A typical Mössbauer spectrum of tephra consists of magnetic and non-magnetic components (magnetic component represents about 11% and non-magnetic component about 89% of spectral area). According to the structural composition, it may be supposed that the magnetic component can be assigned to titanomagnetite. Non-magnetic components contain two quadrupole doublets (Fe2+ species) and one doublet containing Fe3+. According to the measured values of Mössbauer spectra, the first two doublets are very similar with pyroxene, olivine and the third to phylosilicate, aluminosilicate or iron oxide of FeO type. Recently, volcanic tephra was applied as an ecological substance. Special solution was proposed for tephra utilization, especially for phosphate removal from contaminated water.

  10. Thermoluminescence dating of a tephra level from Baume Moula-Guercy (Soyons, Ardeche, France)

    International Nuclear Information System (INIS)

    Sanzelle, S.; Montret, M.; Pilleyre, T.; Miallier, D.; Fain, J.

    1998-01-01

    The Baume Moula-Guercy site (Ardeche, France) is a cave that overhangs the Rhone river valley at a hundred meters height. Since its discovery, it has been assimilated as a shelter with an upper part opened towards the sky. It contains an upper Pleistocene sequence inside which a 2-3 cm localized volcanic layer has been identified. This layer is attributed to an important phreato-magmatic emission from the Vivarais region located at about 50 km SW of the site. The filling of this cave contains neanderthalian remains in a lower level and middle Paleolithic lithic industries in a upper level. Thus, the dating of the tephra level would be of great archaeological importance as it could be used as a chronostratigraphic reference. An estimation of the age obtained by thermoluminescence dating has been requested. This report presents the dating procedure performed on quartz samples extracted from the tephra level and the estimation of the site dosimetry. (J.S.)

  11. Connecting, synchronising, and dating with tephras : principles and applications of tephrochronology in Quaternary research

    International Nuclear Information System (INIS)

    Lowe, D.J.

    2017-01-01

    Tephrochronology is a unique method for linking and dating geological, palaeoecological, palaeoclimatic or archaeological sequences or events. The method relies firstly and fundamentally on stratigraphy and the law of superposition, which apply in any study that connects or correlates deposits from one place to another. Secondly, it relies on characterising and hence identifying or 'fingerprinting' tephra layers using either physical properties evident in the field or those obtained from laboratory analysis, including mineralogical examination by optical microscopy or geochemical analysis of glass shards or crystals (e.g. Fe-Ti oxides, ferromagnesian minerals) using the electron microprobe and other tools. Thirdly, the method is enhanced when a numerical age is obtained for a tephra layer by (1) radiometric methods such as radiocarbon, fission-track, U-series, or Ar/Ar dating, (2) incremental dating methods including dendrochronology or varved sediments or layering in ice cores, or (3) age-equivalent methods such as palaeomagnetism or correlation with marine oxygen isotope stages or palynostratigraphy. Once known, that age can be transferred from one site to the next using stratigraphic methods and by matching compositional characteristics, i.e. comparing 'fingerprints' from each layer. Used this way, tephrochronology is an age-equivalent dating method. (author).

  12. The Disruption of Tephra Fall Deposits by Basaltic Lava Flows

    Science.gov (United States)

    Brown, R. J.; Thordarson, T.; Self, S.; Blake, S.

    2010-12-01

    Complex physical and stratigraphic relationships between lava and proximal tephra fall deposits around vents of the Roza Member in the Columbia River Basalt Province, (CRBP), USA, illustrate how basaltic lavas can disrupt, dissect (spatially and temporally) and alter tephra fall deposits. Thin pahoehoe lobes and sheet lobes occur intercalated with tephra deposits and provide evidence for synchronous effusive and explosive activity. Tephra that accumulated on the tops of inflating pahoehoe flows became disrupted by tumuli, which dissected the overlying sheet into a series of mounds. During inflation of subjacent tumuli tephra percolated down into the clefts and rubble at the top of the lava, and in some cases came into contact with lava hot enough to thermally alter it. Lava breakouts from the tumuli intruded up through the overlying tephra deposit and fed pahoehoe flows that spread across the surface of the aggrading tephra fall deposit. Non-welded scoria fall deposits were compacted and welded to a depth of ~50 cm underneath thick sheet lobes. These processes, deduced from the field relationships, have resulted in considerable stratigraphic complexity in proximal regions. We also demonstrate that, when the advance of lava and the fallout of tephra are synchronous, the contacts of some tephra sheets can be diachronous across their extent. The net effect is to reduce the usefulness of pyroclastic deposits in reconstructing eruption dynamics.

  13. Connecting, synchronising, and dating with tephras : principles and applications of tephrochronology in Quaternary research

    International Nuclear Information System (INIS)

    Lowe, D.J.

    2016-01-01

    Tephrochronology is a unique method for linking and dating geological, palaeoecological, palaeoclimatic or archaeological sequences or events. The method relies firstly and fundamentally on stratigraphy and the law of superposition, which apply in any study that connects or correlates deposits from one place to another. Secondly, it relies on characterising and hence identifying or 'fingerprinting' tephra layers using either physical properties evident in the field or those obtained from laboratory analysis, including mineralogical examination by optical microscopy or geochemical analysis of glass shards or crystals (e.g. Fe-Ti oxides, ferromagnesian minerals) using the electron microprobe and other tools. Thirdly, the method is enhanced when a numerical age is obtained for a tephra layer by (1) radiometric methods such as radiocarbon, fission-track, U-series, or Ar/Ar dating, (2) incremental dating methods including dendrochronology or varved sediments or layering in ice cores, or (3) age-equivalent methods such as palaeomagnetism or correlation with marine oxygen isotope stages or palynostratigraphy. Once known, that age can be transferred from one site to the next using stratigraphic methods and by matching compositional characteristics, i.e. comparing 'fingerprints' from each layer. Used this way, tephrochronology is an age-equivalent dating method. (author).

  14. Stratigraphy, age and correlation of middle Pleistocene silicic tephras in the Auckland region, New Zealand : a prolific distal record of Taupo Volcanic Zone volcanism

    International Nuclear Information System (INIS)

    Alloway, B.V.; Westgate, J.; Pillans, B.; Pearce, N.; Newnham, R.; Byrami, M.; Aarburg, S.

    2004-01-01

    Coastal sections in the Auckland region reveal highly carbonaceous and/or highly weathered clay-dominated cover-bed successions with numerous discrete distal volcanic ash (tephra) layers, fluvially reworked siliciclastic (tephric) deposits, and two widely distributed pyroclastic density current (PDC) deposits generated from explosive silicic volcanism within the Taupo Volcanic Zone (TVZ). The younger of the two PDC deposits (informally named Waiuku tephra) is glass-isothermal plateau fission-track (ITPFT) dated at 1.00 ± 0.03 Ma and occurs in a normal polarity interval interpreted as the Jaramillo Subchron. Waiuku tephra is correlated with Unit E sourced from the Mangakino Volcanic Centre of the TVZ. Waiuku tephra can be subdivided into two distinctive units enabling unequivocal field correlation: a lower stratified unit (dominantly pyroclastic surge with fall component) and an upper massive to weakly stratified unit (pyroclastic flow). At many sites in south Auckland, Waiuku tephra retains basal 'surge-like' beds (<1.4 m thickness). This provides clear evidence for primary emplacement and is an exceptional feature considering the c. 200 km this PDC has travelled from its TVZ source area. However, at many other Auckland sites, Waiuku tephra displays transitional sedimentary characteristics indicating lateral transformation from hot, gas-supported flow/surge into water-supported mass flow and hyperconcentrated flow (HCF) deposits. The older PDC deposit is dated at 1.21 ± 0.09 Ma, is enveloped by tephras that are ITPFT-dated at 1.14 ± 0.06 Ma (above) and 1.21 ± 0.06 Ma (below), respectively, and occurs below a short normal polarity interval (Cobb Mountain Subchron) at c. 1.19 Ma. This PDC deposit, correlated with Ongatiti Ignimbrite sourced from the Mangakino Volcanic Centre of TVZ, has laterally transformed from a gas-supported, fine-grained pyroclastic flow deposit at Oruarangi, Port Waikato, into a water-supported volcaniclastic mass flow deposit farther north

  15. High-MgO Vitric Ash in Upper Kulanaokuaiki Tephra, Kilauea Volcano, Hawai`i: A Preliminary Description

    Science.gov (United States)

    Rose, T. R.; Fiske, R. S.; Swanson, D.

    2011-12-01

    Small, well-formed Pele's tears containing anomalously high values of MgO were recently discovered in outcrops of the upper Kulanaokuaiki Tephra at and near the base of Uwekahuna Bluff, the western wall of Kilauea Caldera. Electron microprobe analyses of more than 60 high-MgO tears, which are 1-3 mm in diameter, show that most contain 11 to 12 wt. % MgO with a few approaching 13 % MgO. Separate microprobe analyses for sulfur and chlorine of 20 grains revealed no appreciable amounts of either, indicating the magma was largely degassed. Polished-section studies employing an analytical scanning electron microscope show most tears are composed of pure microvesicular glass with scattered skeletal olivine crystals and rare chromite. The abundance of skeletal olivine appears to increase with decreasing MgO content of the glass. These tears contain among the highest known MgO values of any material erupted subaerially from Kilauea. The high-MgO tears occur in a 1-6 cm thick layer of medium-coarse lithic-crystal-vitric ash. The top of this layer consists of 2-3 mm of very fine lithic-crystal ash. The lithics and many of the olivine crystals in this layer are highly oxidized. This deposit is at the top of a sequence of several lithic beds that are interspersed with thinner vitric units totaling about 75 cm in thickness. It is overlain by 9-13 cm of medium pumice lapilli and coarse vitric ash at the top of the "Bluff base" and "mid-Bluff" tephra sections described by Fiske et al. (2009). This high-MgO glass layer has been found thus far in only one other locality, a 2 m-deep soils study pit within Kipuka Puaulu, 3.5 km northwest of the caldera. Based upon stratigraphic relationships and preliminary microprobe data, a few other likely exposures of the high-MgO deposit have been identified north and west of the caldera. The high-MgO vitric ash in the upper Kulanaokuaiki Tephra has a primitive composition that suggests little if any shallow level storage of magma. Instead, the

  16. Tephra, tephrochronology and archaeology

    DEFF Research Database (Denmark)

    Riede, Felix; Thastrup, Mads

    2013-01-01

    increased areas, the overall potential of tephrochronology as a major dating tool for both palaeoenvironmental scientists and archaeologists is greatly expanded. The aim of this paper is not to be comprehensive, but to provide a brief and timely general review of tephra studies and their methodologies......Volcanic eruptions are often, although by no means always, associated with a profuse output of fine pyroclastic material, tephra. While residence time in the atmosphere of the very finest of these particles can be substantial, the deposition of the bulk of volcanic ejecta can be considered...... only act as a useful chronostratigraphic marker, but can also play a role in changing patterns of environmental and cultural change at the level of the site or the region. In order to move towards such integration, a series of methodological challenges have to be met. We outline some of these...

  17. Implications of S1 tephra findings in Dead Sea and Tayma palaeolake sediments for marine reservoir age estimation and palaeoclimate synchronisation

    Science.gov (United States)

    Neugebauer, Ina; Wulf, Sabine; Schwab, Markus J.; Serb, Johanna; Plessen, Birgit; Appelt, Oona; Brauer, Achim

    2017-08-01

    Here we report on the first findings of a cryptotephra in the Holocene lacustrine sediment records of the Dead Sea and Tayma palaeolake (NW Arabian Peninsula). The major element glass composition of this rhyolitic tephra is identical to the distal 'S1' tephra layer identified in the Yammoûneh palaeolake (Lebanon), in a marine sediment record from the SE Levantine basin and in the Sodmein Cave archaeological site in Egypt. The S1 tephra corresponds to the early Holocene 'Dikkartın' dome eruption of the Erciyes Dağ volcano in central Anatolia (Turkey) and has been dated in the marine record at 8830 ± 140 cal yr BP. We present new age estimates of the S1 tephra based on radiocarbon dating of terrestrial plant remains and pollen concentrates revealing ages of 8939 ± 83 cal yr BP in the Dead Sea sediments and 9041 ± 254 cal yr BP in Tayma. The precise date from the Dead Sea allows refining the early Holocene marine reservoir age in the SE Levantine Sea to ca. 320 ± 50 years. Synchronisation of marine and terrestrial palaeoclimate records in the eastern Mediterranean region using the S1 tephra further suggests a time-transgressive expansion of the early Holocene humid period.

  18. Revised tephra volumes for Cascade Range volcanoes

    Science.gov (United States)

    Nathenson, Manuel

    2017-01-01

    Isopach maps from tephra eruptions from Mount St. Helens were reported in Carey et al. (1995) and for tephra eruptions from Glacier Peak in Gardner et al. (1998). For exponential thinning, the isopach data only define a single slope on a log thickness versus square root of area plot. Carey et al. (1995) proposed a model that was used to estimate a second slope, and volumes were presented in both studies using this model. A study by Sulpizio (2005) for estimating the second slope and square root of area where the lines intersect involves a systematic analysis of many eruptions to provide correlation equations. The purpose of this paper is to recalculate the volumes of Cascades eruptions and compare results from the two methods. In order to gain some perspective on the methods for estimating the second slope, we use data for thickness versus distance beyond the last isopach that are available for some of the larger eruptions in the Cascades. The thickness versus square root of area method is extended to thickness versus distance by developing an approximate relation between the two assuming elliptical isopachs with the source at one of the foci. Based on the comparisons made between the Carey et al. (1995) and Sulpizio (2005) methods, it is felt that the later method provides a better estimate of the second slope. For Mount St. Helens, the estimates of total volume using the Sulpizio (2005) method are generally smaller than those using the Carey et al. (1995) method. For the volume estimates of Carey et al. (1995), the volume of the May 18, 1980, eruption of Mount St. Helens is smaller than six of the eight previous eruptions. With the new volumes using the Sulpizio (2005) method, the 1980 eruption is smaller in volume than the upper end of the range for only three of the layers (Wn, Ye, and Yn) and is the same size as layer We. Thus the 1980 eruption becomes representative of the mid-range of volumes rather than being in the lower range.

  19. Spatial variation in pollen and charcoal records in relation to the 665 yr BP Kaharoa tephra at Harataonga Bay, Great Barrier Island, northern New Zealand : preliminary results

    International Nuclear Information System (INIS)

    Horrocks, M.; Nichol, S.L.; Jones, M.D.; Shane, P.A.; Sutton, D.G.

    2001-01-01

    We present preliminary results of a pollen study examining spatial variability using the 665 14 C yr BP Kaharoa tephra as the key stratigraphic marker. Our aim is to highlight potential differences in pollen and charcoal profiles from adjacent sites, and to point out the implications of these differences for the interpretation of pollen records. Three sediment cores were taken from swampy ground behind foredunes at Harataonga Bay, a small catchment on Great Barrier Island. Core 1 provides a c. 5000 14 C yr record of the swamp and is typical of northern New Zealand pollen profiles in that the deforestation signal appears immediately after Kaharoa tephra. Cores 2 and 3, however, show this signal at least 1 m below the tephra layer. Also, artefact pollen of gourd Lagenaria, an introduced Polynesian cultigen, was found 80 cm below the tephra layer in Core 2. This apparent difference in the timing of the human signal may be explained by the occurrence of small-scale, highly localised fires that are not recorded at adjacent sites. This has implications for inferring date of human presence in extensive areas, such as regions or large catchments, from a small number of pollen cores taken from within those areas. An alternative explanation is that sediments in cores 2 and 3 have been reworked to a much greater extent than those in Core 1. This has implications for the use of tephra as critical data for events, particularly when using recent tephra such as Kaharoa for dating human presence when the necessary resolution is to decades or centuries rather than millenia. (author). 18 refs., 6 figs., 2 tabs

  20. Tephra and cryptotephra in a 60,000-year-old lacustrine sequence from the Fucino Basin: new insights into the major explosive events in Italy

    Science.gov (United States)

    Di Roberto, Alessio; Smedile, Alessandra; Del Carlo, Paola; De Martini, Paolo Marco; Iorio, Marina; Petrelli, Maurizio; Pantosti, Daniela; Pinzi, Stefania; Todrani, Alessandro

    2018-03-01

    Two cores were sampled in the Fucino Basin (central Apennines, Italy), which represents an extensional intramountain basin filled by Pliocene to Quaternary continental alluvial and lacustrine deposits. The cores were investigated for tephra content and five visible tephras with thickness ranging from 1 to 8 cm were identified. Six additional cryptotephra were identified during the inspection of significant peaks of the magnetic susceptibility curve. Texture and mineralogy of five tephra and six cryptotephra layers were analyzed by means of scanning electron microscope coupled with energy-dispersive X-ray spectrometry system (SEM-EDS) and geochemical measurements were performed by an electron microprobe (EPMA) equipped with five wavelength-dispersive spectrometers (WDS) and using a laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) system on single glass shards. The results allowed us to assign tephra and cryptotephra to ten known volcanic eruptions that occurred over the last ca. 60 ka in the Campanian Province (Phlegrean Fields and Ischia Island), the Alban Hills volcanic complex, and Lipari island. In particular, we recognized the deposits of the Monte Epomeo Green Tuff and the Piroclastiti di Catavola eruptions of Ischia, the pre-Campanian Ignimbrite Tlc, the Campanian Ignimbrite and the Neapolitan Yellow Tuff eruptions of the Phlegrean Fields, the Gabellotto-Fiume Bianco eruption of Lipari, and all the four explosive events belonging to the last cycle of volcanic activity of Albano maar (Albano 4-7). Deposits from five of these identified events (i.e., Piroclastiti di Catavola, Gabellotto-Fiume Bianco, Albano 5 and 6 eruptions, and Campanian Ignimbrite) were previously un-reported in the Fucino basin. These findings add new tephra layers to the list of possible tephrochronologic markers in the region and highlight that a comprehensive tephra record may be constructed when the study of cryptotephra layers is included. Moreover, results

  1. Tephrostratigraphy and potassium-argon age determinations of seven volcanic ash layers in the Muddy Creek formation of southern Nevada

    International Nuclear Information System (INIS)

    Metcalf, L.A.

    1982-04-01

    Seven silicic tephra layers occur in alluvial deposits of the Muddy Creek and equivalent formations at three localities in southern Nevada. Chemical and petrographic characterization indicate the tephra were derived from seven different volcanic eruptions and do not represent any previously known tephra layers. K-Ar age determinations on minerals or glass from each layer yielded 6 to 12 m.y. ages. Discordant ages were obtained on multiple mineral phases due to incorporation of detrital contaminants. The tephra are sufficiently distinctive to constitute stratigraphic marker horizons in the Muddy Creek and equivalent formations. Derivation from the southwestern Nevada volcanic field, active 16 to 6 m.y., is highly likely for some of the tephra. The K-Ar results suggest substantial parts of the Muddy Creek Formation and equivalent basin-fill are 6 to 12 m.y., indicating basin-range faulting began prior to 12 m.y. Little tectonic deformation or physiographic change has occurrred in the past 6 m.y

  2. Stratigraphy and chronology of a 15 ka sequence of multi-sourced silicic tephras in a montane peat bog, eastern North Island, New Zealand

    International Nuclear Information System (INIS)

    Lowe, D.J.; Newnham, R.M.; Ward, C.M.

    1999-01-01

    We document the stratigraphy, composition, and chronology of a succession of 16 distal, silicic tephra layers interbedded with lateglacial and Holocene peats and muds up to c. 15 000 radiocarbon years (c. 18 000 calendar years) old at a montane site (Kaipo Bog) in eastern North Island, New Zealand. Aged from 665 + or - 15 to 14 700 + or - 95 14 C yr BP, the tephras are derived from six volcanic centres in North Island, three of which are rhyolitic (Okataina, Taupo, Maroa), one peralkaline (Tuhua), and two andesitic (Tongariro, Egmont). Correlations are based on multiple criteria: field properties and stratigraphic interrelationships, ferromagnesian silicate mineral assemblages, glass-shard major element composition (from electron microprobe analysis), and radiocarbon dating. We extend the known distribution of tephras in eastern North Island and provide compositional data that add to their potential usefulness as isochronous markers. The chronostratigraphic framework established for the Kaipo sequence, based on both site-specific and independently derived tephra-based radiocarbon ages, provides the basis for fine-resolution paleoenvironmental studies at a climatically sensitive terrestrial site from the mid latitudes of the Southern Hemisphere. Tephras identified as especially useful paleoenvironmental markers include Rerewhakaaitu and Waiohau (lateglacial), Konini (late-glacial-early Holocene), Tuhua (middle Holocene), and Taupo and Kaharoa (late Holocene). (author). 102 refs., 3 tabs., 3 figs

  3. Volcanic Cyclicities in the Pacific Northwest: Insights from the Marine Tephra Record from IODP Expedition 350, Izu Bonin Arc

    Science.gov (United States)

    Straub, S. M.; Schindlbeck, J. C.; Jegen, M. D.; Corry-Saavedra, K.; Murayama, M.; Woodhead, J. D.; Kutterolf, S.; Vautravers, M. J.; Wang, K. L.

    2016-12-01

    While the influences of orbital cycles on the ocean-atmosphere system are well documented, it remains largely unknown whether Earth's interior processes are similarly connected to orbital cycles. Recent studies of cyclic deposition in ash fallout from arc volcanism suggest that global climate changes in the form of variable glacial and water load are inversely related to magma production and/or volcanic eruption rate. However, a rigorous test of this hypotheses requires a temporally precise record of past volcanism which spans multiple glacial cycles at high resolution. The marine ash record of explosive volcanism provides such records readily. Here we undertake a detailed chemical study of discrete and disperse tephra deposits in cores from IODP Holes U1437B and U1436A drilled near the Izu Bonin arc in the northwestern Pacific. These locations combine a high background sedimentation rate (>10 m/Ma) of biogenic carbonate and Asian-derived dust with frequent emplacement of tephra fallout from the nearby Izu Bonin and Japan arcs. δ18O analyses record thirteen climatic cycles in the carbonate mud of the uppermost 120 m of Hole U1437B and eleven cycles in the uppermost 70 m of Hole U1436C. Strikingly, the distribution of 134 primary ash layers in Hole U1437B seems to be synchronous with glacial cycles, with a distinct increase in eruption occurrences at either the transitions of glacial/interglacial or at the early interglacials. This is confirmed by first results of a frequency analysis of the ash-time series that indicate a dominance of a 100 ka cycle. The question, which remains to be answered, is whether deglaciation drives volcanism or volcanism drives deglaciation? We also investigate the distribution of `dispersed ash' in this sequence, which is not visible to the naked eye but is volumetrically significant and thus also critical in testing time-cause relationships between arc volcanism and glacial cycles. Major questions we address are: 1) do we see the same

  4. Geochemical characterization of mid-distal Nisyros tephra on Datça peninsula (southwestern Anatolia)

    Science.gov (United States)

    Gençalioğlu-Kuşcu, Gonca; Uslular, Göksu

    2018-04-01

    We present new distal records of tephra deposits that overly the Kos ignimbrite in seven locations of Datça peninsula. Tephra in one of these locations were previously associated with Nisyros Kyra sub-unit based only on the field characteristics. We use different proxies such as field observations, petrography, mineral, glass, and whole-rock chemistry in order to characterize and correlate the previously and recently identified pumice fall deposits on Datça. The total thickness of the fall deposit reaches to 3.5 m. The size of the pumice clasts is generally within the range of lapilli, and they have vitrophyric texture consisting mainly of plagioclase (andesine to labradorite) with scarce clinopyroxene (diopside to augite), olivine (Fo48-50), amphibole (magnesio-hastingsite), and biotite crystals. Amphibole is a ubiquitous phenocryst in all Datça tephra units and used as a criterion for the correlation. Glass major element analyses by EMPA reveal two different groups with andesitic and dacitic compositions. Difference in silica content (up to ca. 4 wt%) detected in the same specimen also designates the heterogeneity in pumice glass. This heterogeneity in glass composition is also supported by the frequent occurrence of banded pumice clasts in Datça tephra. Whole-rock composition of the pumice is mainly andesitic with calc-alkaline affinity. Multi-element patterns on primitive-mantle normalized diagram display typical arc-magmatism signature (i.e. depletion in Nb, Ta, Ti, and P). In order to check and eliminate the potential alternatives, we compared the distal deposits on Datça not only with Kyra, but also with other Nisyros tephra units. Yet, Kyra is the only unit that has comparable depositional characteristics, calcic amphibole crystals, andesitic-dacitic glass and whole-rock chemistry, and distal tephra deposits on neighboring islands (Tilos and Chalki). Therefore, we associate Datça tephra deposits with some proximal Kyra subunits of intermediate

  5. Exploring Links Between Global Climate and Explosive Arc Volcanism in Tephra-Rich Quaternary Sediments: A Pilot Study from IODP Expedition 350 Site 1437B, Izu Bonin Rear-Arc Region

    Science.gov (United States)

    Corry-Saavedra, K.; Straub, S. M.; Bolge, L.; Schindlbeck, J. C.; Kutterolf, S.; Woodhead, J. D.

    2015-12-01

    Fallout tephra in marine sediment provide an excellent archive of explosive arc volcanism that can be directly related to the other parameters of climate change, such as ice volume data, IRD (ice-rafted debris) input, etc. Current studies are based on 'discrete' tephra beds, which are produced by major eruptions and visible with the naked eye. Yet the more common, but less explosive arc eruptions that are more continuous through time produce 'disperse' tephra, which is concealed by the non-volcanic host sediment and invisible to the eye. The proportion of disperse tephra in marine sediments is known to be significant and may be critical in elucidating potential synchronicity between arc volcanism and glacial cycles. We conducted a pilot study in young sediments of IODP Hole 1437B drilled at 31°47.3911'N and 139°01.5788'E at the rear-arc of the Izu Bonin volcanic arc. By means of δ18O (Vautravers, in revision), eleven climatic cycles are recorded in uppermost 120 meter of carbonate mud that is interspersed by cm-thick tephra fallout layers. We selected six tephra layers, ranging from 0.2 to 1.16 million years in age, and sampled those vertically, starting from carbonate mud below the basal contact throughout the typical gradational top into the carbonate mud above. From each tephra bed, volcanic particles (>125 micrometer) were handpicked. All other samples were powdered and leached in buffered acetic acid and hydroxylamine hydrochloride to remove the carbonate and authigenous fraction, respectively. Major and trace element abundances (except for SiO2) from all samples were determined by ICP-MS and ICP-OES methods. Strong binary mixing trends are revealed between the pure tephra end member, and detrital sediment component. The tephra is derived from the Izu Bonin volcanic front and rear-arc, while the sediment component is presumably transported by ocean surface currents from the East China Sea. Our data show that mixing proportions change systematically with

  6. A Tephra Database With an Intelligent Correlation System, Mono-Inyo Volcanic Chain, CA

    Science.gov (United States)

    Bursik, M.; Rogova, G.

    2004-12-01

    We are assembling a web-accessible, relational database of information on past eruptions of the Mono-Inyo volcanic chain, eastern California. The PostgreSQL database structure follows the North American Data Model and CordLink. The database allows us to extract the features diagnostic of particular pyroclastic layers, as well as lava domes and flows. The features include depth in the section, layer thickness and internal stratigraphy, mineral assemblage, major and trace element composition, tephra componentry and granulometry, and radiocarbon age. Our working hypotheses are that 1) the database will prove useful for unraveling the complex recent volcanic history of the Mono-Inyo chain 2) aided by the use of an intelligent correlation system integrated into the database system. The Mono-Inyo chain consists of domes, craters and flows that stretch for 50 km north-south, subparallel to the Sierran range front fault system. Almost all eruptions within the chain probably occurred less than 50,000 years ago. Because of the variety of magma and eruption types, and the migration of source regions in time and space, it is nontrivial to discern patterns of behaviour. We have explored the use of multiple artificial neural networks combined within the framework of the Dempster-Shafer theory of evidence to construct a hybrid information processing system as an aid in the correlation of Mono-Inyo pyroclastic layers. It is hoped that such a system could provide information useful to discerning eruptive patterns that would otherwise be difficult to sort and categorize. In a test case on tephra layers at known sites, the intelligent correlation system was able to categorize observations correctly 96% of the time. In a test case with layers at one unknown site, and using a pairwise comparison of the unknown site with the known sites, a one-to-one correlation between the unknown site and the known sites was found to sometimes be poor. Such a result could be used to aid a

  7. ERUPTION TO DOSE: COUPLING A TEPHRA DISPERSAL MODEL WITHIN A PERFORMANCE ASSESSMENT FRAMEWORK

    International Nuclear Information System (INIS)

    G. N. Keating, J. Pelletier

    2005-01-01

    The tephra dispersal model used by the Yucca Mountain Project (YMP) to evaluate the potential consequences of a volcanic eruption through the waste repository must incorporate simplifications in order to function within a large Monte-Carlo style performance assessment framework. That is, the explicit physics of the conduit, vent, and eruption column processes are abstracted to a 2-D, steady-state advection-dispersion model (ASHPLUME) that can be run quickly over thousands of realizations of the overall system model. Given the continuous development of tephra dispersal modeling techniques in the last few years, we evaluated the adequacy of this simplified model for its intended purpose within the YMP total system performance assessment (TSPA) model. We evaluated uncertainties inherent in model simplifications including (1) instantaneous, steady-state vs. unsteady eruption, which affects column height, (2) constant wind conditions, and (3) power-law distribution of the tephra blanket; comparisons were made to other models and published ash distributions. Spatial statistics are useful for evaluating differences in these model output vs. results using more complex wind, column height, and tephra deposition patterns. However, in order to assess the adequacy of the model for its intended use in TSPA, we evaluated the propagation of these uncertainties through FAR, the YMP ash redistribution model, which utilizes ASHPLUME tephra deposition results to calculate the concentration of nuclear waste-contaminated tephra at a dose-receptor population as a result of sedimentary transport and mixing processes on the landscape. Questions we sought to answer include: (1) what conditions of unsteadiness, wind variability, or departure from simplified tephra distribution result in significant effects on waste concentration (related to dose calculated for the receptor population)? (2) What criteria can be established for the adequacy of a tephra dispersal model within the TSPA

  8. Stratigraphy and tephra of the Kibish Formation, southwestern Ethiopia.

    Science.gov (United States)

    Brown, Francis H; Fuller, Chad R

    2008-09-01

    The Kibish Formation in southwestern Ethiopia, with an aggregate thickness of approximately 105 m, consists of lacustrine, marginal lacustrine, and deltaic deposits. It is divided into four members numbered I to IV on the basis of erosion surfaces (disconformities) between the strata of each member. It overlies the Mursi and Nkalabong formations, the latter of which is here shown to correlate with the Shungura Formation. Tephra layers in each member allow for secure correlation between geographically separated sections on the basis of the composition of their volcanic glass. Members I, III, and IV of the Kibish Formation appear to have been deposited at the same times as sapropels S7 (197 ka), S4 (104 ka), and S1 (8 ka) in the eastern Mediterranean Sea, respectively. We correlate the KHS Tuff of the Kibish Formation with a >154-kyr-old unnamed tuff in the Konso Formation. Tephra in Member IV may derive from Mount Wenchi, a volcano situated on the divide between the Omo and Blue Nile drainage basins. Thin-bedded sedimentary layers probably represent annual deposition reflecting rapid sedimentation (approximately 30 m/kyr) of parts of the formation. This conclusion is supported by variation in paleomagnetic inclination through a sequence of these layers at KHS. Two fossils of early Homo sapiens (Omo I and Omo II) derive from Member I. Their stratigraphic placement is confirmed by analysis of the KHS Tuff in the lower part of Member II at both fossil sites. The KHS Tuff lies above a disconformity, which itself lies above the fossils at both sites. (40)Ar/(39)Ar dates provide an estimated age of approximately 195 kyr for these fossils. Omo III, a third fossil H. sapiens, probably also derives from Member I of the Kibish Formation and is of similar age. Hominin fossils from AHS, a new site, also derive from Member I. Hominin fossils from CHS can only be placed between 104 ka and 10 ka, the H. sapiens specimen from JHS is most likely 9-13 kyr in age, and a partial

  9. Tephras in lacustrine sediments of the Sarliève marsh (French Massif Central): age and preservation

    Science.gov (United States)

    Fourmont, Agathe; Macaire, Jean-Jacques; Bréhéret, Jean-Gabriel; Argant, Jacqueline; Prat, Béatrice; Vernet, Gérard

    2006-12-01

    The Sarliève marsh sediments (Massif Central, France) contain two tephras. The first tephra [ 13.7±0.4ka(2δ), ca. 12 000 BP], regionally well known, enables to date the beginning of lacustrine infill to the Lateglacial. The second tephra, the 'tephra de Sarliève', the emitting volcano of which is unknown, would be dated to around the Early Subboreal from pollen data. This occurrence, after the discovery of the 'tephra de Beaunit', emphasizes that volcanic eruption(s) occurred in the 'Chaîne des Puys' or in the volcanic Cézallier more than 1000 years after the last known eruption (Pavin) in the 'Chaîne des Puys' at around 6.6/6.7 ka (5800/5900 BP). In the Sarliève piles, these tephras, well preserved in thick and more silicated deposits of deltas, were not observed in carbonated basin sediments where they were altered. The abundance of authigenic zeolites formed during the Lateglacial in restricted depocentre lacustrine waters allows us to detect initial CF1 tephra occurrence. To cite this article: A. Fourmont et al., C. R. Geoscience 338 (2006).

  10. Promise and pitfalls for characterizing and correlating the zeolitically altered tephra of the Pleistocene Peninj Group, Tanzania

    Science.gov (United States)

    McHenry, Lindsay J.; Luque, Luis; Gómez, José Ángel; Diez-Martín, Fernando

    2011-05-01

    The Pleistocene Humbu and Moinik formations of the Peninj Group in northern Tanzania preserve an important archaeological and paleontological record, in addition to a record of local volcanism in the form of tephra and lavas. Samples of the major Humbu and Moinik formations' basaltic and trachytic tephra were collected and characterized using phenocryst composition and both primary and authigenic mineral assemblage, since the volcanic glass was completely altered to zeolite. Some tephra are distinguishable solely using phenocrysts, but some are too similar in mineral composition or too poor in phenocrysts to definitively "fingerprint" without glass. Titanomagnetite phenocrysts were mostly altered; characterization was thus limited to feldspar, augite, and hornblende compositions for most tephra. Phenocryst compositions were compared to Olduvai tephra compositions to see if any regional tephra could be identified that could help correlate the sites. Augite or hornblende composition rules out potential correlations of Olduvai Bed I Tuff IF and the Bed II Bird Print Tuff or Tuff IID to otherwise similar Peninj Group tephra. Despite their overlap in age and locations at less than ~ 80 km from the Ngorongoro Volcanic Highlands, Peninj and Olduvai have different tephra records, which limits the possibilities for establishing a regional tephrostratigraphic framework.

  11. Occurrence of tephra/volcanic tuff in the tertiary sediments of Himachal Himalaya from Tileli area, Mandi district, H.P.: implication for stratigraphy and uranium mineralization

    International Nuclear Information System (INIS)

    Pandey, Pradeep; Chabbra, Jyotsana; Joshi, G.B.; Parihar, P.S.

    2014-01-01

    Presence of Early Tertiary pyroclastic material (tephra) has been documented petrographically, for the first time, in the Mandi-Bilaspur Sector from Tileli area, Dharamsala basin of Himachal Pradesh. The tephra is reported from the red shale, identified as tuffaceous siltstone belonging to lower Dharamsala Formation that lies above the uraniferous sandstone body and occurs as thin layers of over 300m along the strike, close to the contact of lower and upper Dharamsala formations. The tuffaceous material shows crude but preferred orientation of minerals like biotite, muscovite, chlorite, clay, hematite and specularite. Various features indicating presence of tephra are, glass shards altered to clay but retaining 'U' shaped outline, spindle-shaped hematite with preferred orientation, spherical to sub-spherical clay and altered Fe oxide rich balls, clay groundmass with flow pattern, flaky minerals in association with clast depicting asymmetrical ramp structure. A zone of approximately 300 m length containing tuffaceous material has been established at Tileli overlying the uraniferous sandstone body. Identification of tephra at Tileli has significant implications as it enabled in demarcating the boundary between the upper and lower Dharamsala formations in central part of the basin in Bilaspur-Mandi Sector of HP Himalaya and also in guiding the uranium exploration programme in the lower Dharamsala Formation. (author)

  12. Tephrostratigraphy and geochemical fingerprinting of the Mangaone Subgroup tephra beds, Okataina Volcanic Centre, New Zealand

    International Nuclear Information System (INIS)

    Smith, V.C.; Shane, P.; Smith, I.E.M.

    2002-01-01

    The Mangaone Subgroup is a sequence of 14 plinian tephra beds erupted from the Okataina Volcanic Centre in North Island, New Zealand, that are bracketed between the regional marker beds of Rotoehu Tephra (50-60 ka) and Oruanui Tephra (26 ka). The Mangaone Subgroup tephra beds are separated by thin paleosols in ascending stratigraphic order: unit A, unit B, unit C, Pupuwharau Tephra (new), Pongakawa Tephra (new), Maketu, Te Mahoe, Hauparu, unit G, unit H, Mangaone, Awakeri, Omataroa, and unit L. Geochemical fingerprinting of the glass and phenocryst phases allows clear subdivision of the Mangaone Subgroup into two stratigraphic intervals. Units A-G are rhyodacites and low-SiO 2 rhyolites (71-75.5 wt% SiO 2 glass; 68-71 wt% SiO 2 whole rock), clinopyroxene bearing, with calcic plagioclase (An 40-60 ) and magnesian orthopyroxene (En 60-70 ), and they display high eruption temperatures (870-940 degrees C) and oxygen fugacities (-log f O 2 11.66-10.40). Some of these units are compositionally heterogeneous in the glass phase (SiO 2 range up to 8 wt%), especially unit A, Ngamotu, Te Mahoe, and Hauparu tephra beds. Units A-G can easily be distinguished from other Taupo Volcanic Zone tephra erupted in the last c. 60 000 yr. Units H-L are high SiO 2 rhyolites (76-78 wt% SiO 2 glass; 71.5-75 wt% SiO 2 whole rock), which contain sodic plagioclase (An 30-40 ), low-Mg orthopyroxene (En 50-60 ), and display lower eruption temperatures (755-830 degrees C) and oxygen fugacities (-log f O 2 = 14.7-12.93). Compositional differences in titanomagnetite and ilmenite can also be used to distinguish them from older units. The two compositional groups also form distinct T-f O 2 trends. The shift in chemical affinity follows the large volume Hauparu eruption, and coincides with the likely geographic shift in vent location to the eastern margin of the caldera complex. Tephra beds that both predate and postdate the Mangaone Subgroup also reflect changes in magma type and vent location. The

  13. A critical evaluation of the evidence for multiple Late Pleistocene eruptions of Laacher See Volcano

    DEFF Research Database (Denmark)

    Zernack, Anke Verena; Hoggard, Christian Steven; Sauer, Florian Rudolf

    The c. 12,900 BP Plinian eruption of Laacher See Volcano is one of the largest known volcanic events of the Late Pleistocene in the Northern Hemisphere. It buried proximal areas under tens of meters of pyroclastic flow, surge and fallout deposits and deposited a widespread tephra layer across much...... of dispersal of the products from varying eruptive stages and some sites even report two distinct Laacher See Tephra layers that have been interpreted as evidence of a precursor eruption. In order to assess the potential for multiple Late Pleistocene eruptions of Laacher See Volcano, we have compiled...

  14. Automated statistical matching of multiple tephra records exemplified using five long maar sequences younger than 75 ka, Auckland, New Zealand

    Science.gov (United States)

    Green, Rebecca M.; Bebbington, Mark S.; Cronin, Shane J.; Jones, Geoff

    2014-09-01

    Detailed tephrochronologies are built to underpin probabilistic volcanic hazard forecasting, and to understand the dynamics and history of diverse geomorphic, climatic, soil-forming and environmental processes. Complicating factors include highly variable tephra distribution over time; difficulty in correlating tephras from site to site based on physical and chemical properties; and uncertain age determinations. Multiple sites permit construction of more accurate composite tephra records, but correctly merging individual site records by recognizing common events and site-specific gaps is complex. We present an automated procedure for matching tephra sequences between multiple deposition sites using stochastic local optimization techniques. If individual tephra age determinations are not significantly different between sites, they are matched and a more precise age is assigned. Known stratigraphy and mineralogical or geochemical compositions are used to constrain tephra matches. We apply this method to match tephra records from five long sediment cores (≤ 75 cal ka BP) in Auckland, New Zealand. Sediments at these sites preserve basaltic tephras from local eruptions of the Auckland Volcanic Field as well as distal rhyolitic and andesitic tephras from Okataina, Taupo, Egmont, Tongariro, and Tuhua (Mayor Island) volcanic centers. The new correlated record compiled is statistically more likely than previously published arrangements from this area.

  15. A tephra lattice for Greenland and a reconstruction of volcanic events spanning 25-45 ka b2k

    Science.gov (United States)

    Bourne, A. J.; Cook, E.; Abbott, P. M.; Seierstad, I. K.; Steffensen, J. P.; Svensson, A.; Fischer, H.; Schüpbach, S.; Davies, S. M.

    2015-06-01

    Tephra layers preserved within the Greenland ice-cores are crucial for the independent synchronisation of these high-resolution records to other palaeoclimatic archives. Here we present a new and detailed tephrochronological framework for the time period 25,000-45,000 a b2k that brings together results from 4 deep Greenland ice-cores. In total, 99 tephra deposits, the majority of which are preserved as cryptotephra, are described from the NGRIP, NEEM, GRIP and DYE-3 records. The major element signatures of single glass shards within these deposits indicate that 93 are basaltic in composition all originating from Iceland. Specifically, 43 originate from Grimsvötn, 20 are thought to be sourced from the Katla volcanic system and 17 show affinity to the Kverkfjöll system. Robust geochemical characterisations, independent ages derived from the GICC05 ice-core chronology, and the stratigraphic positions of these deposits relative to the Dansgaard-Oeschger climate events represent a key framework that provides new information on the frequency and nature of volcanic events in the North Atlantic region between GS-3 and GI-12. Of particular importance are 19 tephra deposits that lie on the rapid climatic transitions that punctuate the last glacial period. This framework of well-constrained, time-synchronous tie-lines represents an important step towards the independent synchronisation of marine, terrestrial and ice-core records from the North Atlantic region, in order to assess the phasing of rapid climatic changes during the last glacial period.

  16. Character, mass, distribution, and origin of tephra-fall deposits of the 1989-1990 eruption of redoubt volcano, south-central Alaska

    Science.gov (United States)

    Scott, W.E.; McGimsey, R.G.

    1994-01-01

    The 1989-1990 eruption of Redoubt Volcano spawned about 20 areally significant tephra-fall deposits between December 14, 1989 and April 26, 1990. Tephra plumes rose to altitudes of 7 to more than 10 km and were carried mainly northward and eastward by prevailing winds, where they substantially impacted air travel, commerce, and other activities. In comparison to notable eruptions of the recent past, the Redoubt events produced a modest amount of tephra-fall deposits - 6 ?? 107 to 5 ?? 1010 kg for individual events and a total volume (dense-rock equivalent) of about 3-5 ?? 107 m3 of andesite and dacite. Two contrasting tephra types were generated by these events. Pumiceous tephra-fall deposits of December 14 and 15 were followed on December 16 and all later events by fine-grained lithic-crystal tephra deposits, much of which fell as particle aggregates. The change in the character of the tephra-fall deposits reflects their fundamentally different modes of origin. The pumiceous deposits were produced by magmatically driven explosions. The finegrained lithic-crystal deposits were generated by two processes. Hydrovolcanic vent explosions generated tephrafall deposits of December 16 and 19. Such explosions continued as a tephra source, but apparently with diminishing importance, during events of January and February. Ash clouds of lithic pyroclastic flows generated by collapse of actively growing lava domes probably contributed to tephra-fall deposits of all events from January 2 to April 26, and were the sole source of tephra fall for at least the last 4 deposits. ?? 1994.

  17. Mass Flux of Tephra Sampled Frequently During the Ongoing Halema`uma`u Eruption (Invited)

    Science.gov (United States)

    Swanson, D.; Wooten, K.; Orr, T. R.

    2009-12-01

    The ongoing summit eruption of Kilauea provides an unparalleled opportunity to track, almost daily, the production of tephra. The eruption began on 19 March 2008, and tephra has been erupted every day since then to the end of August 2009. Most of the time, tephra is ejected quasi-continuously from the vent accompanied by a light gray to white gas plume, occasionally broken by a more vigorous pulse (“brown plume”) richer in ejecta. In early April 2008, an array of 10 plastic buckets was placed within 400 m of the new vent in Halema`uma`u down the prevailing NE wind direction. The configuration of the array, spanning an area of about 73,000 m2, has not changed since then. Buckets are emptied frequently, initially every day and, since summer 2008, on all weekdays. The contents are dried and weighed, and an “average network accumulation rate” is calculated in g/m2/hour. In addition, componentry analyses are made of the >0.5-mm size fraction from a bucket near the vent, in order to categorize the tephra into juvenile and lithic fractions. To estimate the total mass of tephra ejected from the vent for a given collection, we first drew isomass contours for several daily collections and plotted isomass versus square root of area to obtain the total mass of the deposit. From this, we developed an empirical multiplication factor that allows us to estimate, within ~25 percent, the total ejected mass per day in kilograms from the total collected mass in grams. The tephra is a mix of vitric and lithic pyroclasts, mostly ash in size. The vitric clasts, interpreted as juvenile, include Pele’s hair and tears, hollow spherules, dumbbells, pumice, and bits of coarsely vesicular glass. All these clasts were probably produced by weak spattering at the top of the lava column, which has rarely been seen. Especially since fall 2008, some vitric clasts are partly coated with secondary minerals or rock dust. We interpret such clasts as recycled, first erupted during spattering

  18. Tephra-Producing Eruptions of Holocene Age at Akutan Volcano, Alaska; Frequency, Magnitude, and Hazards

    Science.gov (United States)

    Waythomas, C. F.; Wallace, K. L.; Schwaiger, H.

    2012-12-01

    Akutan Volcano in the eastern Aleutian Islands of Alaska is one of the most historically active volcanoes in the Aleutian arc (43 eruptions in about the past 250 years). Explosive eruptions pose major hazards to aircraft flying north Pacific air routes and to local infrastructure on Akutan and neighboring Unalaska Island. Air travel, infrastructure, and population in the region have steadily increased during the past several decades, and thus it is important to better understand the frequency, magnitude, and characteristics of tephra-producing eruptions. The most recent eruption was a VEI 2 event on March 8-May 21, 1992 that resulted in minor ash emissions and trace amounts of proximal fallout. Nearly continuous low-level emission of ash and steam is typical of historical eruptions, and most of the historical events have been similar in magnitude to the 1992 event. The most recent major eruption occurred about 1600 yr. B.P. and likely produced the ca. 2-km diameter summit caldera and inundated valleys that head on the volcano with pyroclastic-flow and lahar deposits that are tens of meters thick. The 1600 yr. B.P. eruption covered most of Akutan Island with up to 2.5 m of coarse scoriaceous tephra fall, including deposits 0.5-1 m thick near the City of Akutan. Tephra-fall deposits associated with this eruption exhibit a continuous sequence of black, fine to coarse scoriaceous lapilli overlain by a lithic-rich facies and finally a muddy aggregate-rich facies indicating water involvement during the latter stages of the eruption. Other tephra deposits of Holocene age on Akutan Island include more than a dozen discrete fine to coarse ash beds and 3-6 beds of scoriaceous, coarse lapilli tephra indicating that there have been several additional major eruptions (>VEI 3) of Akutan Volcano during the Holocene. Radiocarbon dates on these events are pending. In addition to tephra falls from Akutan, other fine ash deposits are found on the island that originated from other

  19. Multiple Magma Batches Recorded in Tephra Deposits from the Toba Complex, Sumatra.

    Science.gov (United States)

    Pearce, N. J. G.; Westgate, J.; Gatti, E.

    2015-12-01

    The Toba Caldera Complex is the largest Quaternary caldera on Earth, and has generated three voluminous and compositionally similar rhyolitic tuffs, viz. the Oldest (OTT, 800 ka), Middle (MTT, ~500 ka) and Youngest Toba Tuffs (YTT, 75 ka). These tephra deposits are widespread across Indonesia, Malaysia, South China Sea, Sea of Bengal, India and Indian Ocean and provide useful stratigraphic markers in oceanic, lacustrine and terrestrial environments. Single shard trace element analysis of these deposits reveals the changing availability of different batches of magma through time, with Sr, Ba and Y contents defining 5 discrete magma populations in YTT, 4 populations in MTT and only a single, low Ba population in OTT. Within an individual eruption these populations are clearly distinct, but between eruptions (e.g. MTT and YTT) some of these populations overlap while others do not, indicating both the longevity (and/or continuous supply of fresh material) and evolution of these magma batches in the Toba Complex. Major element compositions of the different groups show equilibration at different pressures (based on Q'-Ab'-Or'), with the equilibration of low Ba populations at ~160 MPa, increasing to depths of ~210 MPa for the highest Ba population. The proportions of different populations of glass in distal YTT shows that relatively little of the high Ba population makes it into the distal record across India, and that this population appears to be over-represented in the proximal free glass and pumice from the caldera walls. This data may shed light on magma availability and tephra dispersal during the YTT eruption. Similarly, the glass composition of individual pumices from proximal deposits record regional, compositional and temporal differences in the erupted products. These show, for example, the apparent mingling of some of the magma batches and also that the high Ba population appears early (i.e. stratigraphically lower) in the northern caldera wall.

  20. Testing Proposed Correlations Between Olduvai Gorge and Laetoli, Tanzania Using Tephra Composition

    Science.gov (United States)

    McHenry, L. J.

    2006-12-01

    Olduvai Gorge and Laetoli are well-known Plio-Pleistocene archaeological sites located 30 km apart in Tanzania. Both received volcanic input from the nearby Ngorongoro Volcanic Highlands (NVH), and together provide a sedimentary and volcanic record from about 4.3 Ma to the Holocene. Previous researchers have proposed likely temporal correlations between the two sites, using both faunal and volcanic evidence. Direct tephra correlation between these sites could create a regional stratigraphic framework for their fossil and paleoecological records. Here, one of the proposed correlations is tested using geochemical fingerprinting. The fossiliferous Laetolil and Ndolanya beds of Laetoli predate the deposition of the Olduvai Beds, however recent 39Ar/40Ar SCLF age dating has shown potential temporal overlap between the Naibadad (2.23-1.93 +/- 0.02; Mangea, 1993) and Olpiro Beds (2.06-2.01 +/- 0.03; Manega 1993) at Laetoli with the Naabi Ignimbrite (2.029 +/- 0.005 Ma, Walter et al. 1992) and lower Bed I at Olduvai. Both the Naibadad bed and lower Bed I also contain fresh quartz-bearing tephra, which can be used for geochemical correlation. Three Naibadad tuffs and five lower Bed I tuffs (Naabi Ignimbrite, coarse feldspar crystal tuff (CFCT), Tuff IA, and two ignimbrites near Ngorongoro) were analyzed by electron microprobe for phenocryst and glass composition and compared to test for possible correlations. Certain mineralogical features made such a correlation unlikely. None of the lower Bed I tuffs analyzed contain significant plagioclase, which is present in all of the Naibadad tuffs analyzed. One Naibadad tuff has a bimodal glass composition indistinguishable from the CFCT, however the CFCT is rich in hornblende, while this Naibadad tuff contains none. This mineralogical difference highlights the need for mineralogical in addition to glass geochemical data for tephra correlation. Ngorongoro crater is the likely source for the Naibadad and lower Bed I tuffs because it

  1. Seasonality of the late Pleistocene Dawson tephra and exceptional preservation of a buried riparian surface in central Yukon Territory, Canada

    Science.gov (United States)

    Froese, Duane G.; Zazula, Grant D.; Reyes, Alberto V.

    2006-07-01

    The late Pleistocene Dawson tephra was deposited by one of the largest Quaternary eruptions in northwestern North America. Its distribution is known sparsely from sites near the source area in southwestern Alaska and central Yukon Territory, where more than 20 occurrences are documented in the Klondike region. Dawson tephra erupted about 25,300C yr BP, near the onset of the last glaciation, and provides a stratigraphic marker across Eastern Beringia. We report radiocarbon ages, paleobotanical data, and cryostratigraphic observations from a new Dawson tephra locale at Goldbottom Creek, in the Klondike region of Yukon Territory, which collectively indicate that the eruption occurred in the late winter or early spring. Multiple, fining-upward tephra-rich ice beds are interpreted as remnants of surface icings, which presently are common in the region during spring. A buried in situ riparian meadow, preserved below the icing and tephra, consists of abundant tufted hair grass ( Deschampsia caespitosa), with interspersed horsetails ( Equisetum cf. palustre) and mosses. Detrital plant remains and preserved in situ grass inflorescences entombed in the icing had expelled their fruits, consistent with a late season surface when the icing was active. The extraordinary thickness of Dawson tephra in central Yukon likely reflects reworking of a winter-deposited tephra by snow melt in the spring following the eruption, indicating that the primary thickness may be overestimated at valley-bottom sites. Winter deposition of the tephra may have, in part, minimized the terrestrial ecological impacts of the eruption on zonal "steppe-tundra" vegetation through the retransportation of tephra from hillslopes to the riparian areas, where the tephra became incorporated into local fluvial systems.

  2. Emplacement of Widespread Fe/Mg Phyllosilicate Layer in West Margaritifer Terra, Mars

    Science.gov (United States)

    Seelos, K. D.; Maxwell, R. E.; Seelos, F. P.; Buczkowski, D.; Viviano-Beck, C. E.

    2017-12-01

    West Margaritifer Terra is located at the eastern end of Valles Marineris at the complex intersection of chaos terrains, cratered highlands, and multiple generations of outflow channels. Adjacent regions host layered phyllosilicates thought to indicate early Mars pedogenic and/or ground water-based alteration (e.g., Le Deit et al., 2012), and indeed, hydrologic modeling supports prolonged aqueous activity in the Noachian and Hesperian eras (Andrews-Hanna and Lewis, 2011). The remnant high-standing plateaus in West Margaritifer (0-15°S, 325-345°E) host numerous phyllosilicate-bearing outcrops as well and are the focus of this study. Here, we performed a systematic mapping and characterization of mineralogy and morphology of these deposits in order to assess similarity to other layered phyllosilicates and evaluate potential formation mechanisms. Utilizing multiple remote sensing datasets, we identified three types of phyllosilicate exposures distributed throughout the region: 1) along upper chaos fracture walls, 2) in erosional windows on the plains, and 3) in crater walls and ejecta. Outcrops are spectrally indicative of Fe/Mg smectite (most similar to saponite) and only rare, isolated occurrences of Al-phyllosilicate were observed. Morphologically, the layer is a few to 10 m thick, light-toned, polygonally fractured at decameter scales, and vertical subparallel banding is evident in places. These characteristics were used along with spatial distribution, elevation, and geologic context to evaluate 4 potential formation mechanisms: fluvio-lacustrine, pedogenesis, diagenesis, and hydrothermal alteration. We find that the widespread distribution and spectral homogeneity of the layer favors formation via groundwater alteration and/or pedogenic weathering. This is consistent with interpretations of similar layered phyllosilicates in NW Noachis Terra and the Valles Marineris plains to the west, and significantly extends the area over which these aqueous processes

  3. Buckets of ash track tephra flux from Halema'uma'u Crater, Hawai'i

    Science.gov (United States)

    Swanson, Don; Wooten, Kelly M.; Orr, Tim R.

    2009-01-01

    The 2008–2009 eruption at Kīlauea Volcano's summit made news because of its eight small discrete explosive eruptions and noxious volcanic smog (vog) created from outgassing sulfur dioxide. Less appreciated is the ongoing, weak, but continuous output of tephra, primarily ash, from the new open vent in Halema'uma'u Crater. This tephra holds clues to processes causing the eruption and forming the new crater-in-a-crater, and its flux is important to hazard evaluations.The setting of the vent–easily accessible from the Hawaiian Volcano Observatory (HVO)—is unusually favorable for neardaily tracking of tephra mass flux during this small prolonged basaltic eruption. Recognizing this, scientists from HVO are collecting ash and documenting how ejection masses, components, and chemical compositions vary through time.

  4. Late Miocene marine tephra beds : recorders of rhyolitic volcanism in North Island, New Zealand

    International Nuclear Information System (INIS)

    Shane, P.; Black, T.; Eggins, S.; Westgate, J.

    1998-01-01

    A deep-sea sequence of 72 rhyolitic tephra beds, now exposed at Mahia Peninsula in the Hawke's Bay region of the east coast, North Island, New Zealand, provides a record of Late Miocene volcanism of the Coromandel Volcanic Zone (CVZ): the precursor to large-scale explosive volcanism of the Quaternary Taupo Volcanic Zone (TVZ). The geochemical signature of the glasses in the Miocene tephra has been protected from hydrothermal alteration and prolonged subaerial exposure that have affected proximal CVZ deposits. The tephra beds are primarily eruption-driven sediment gravity flows that have been emplaced into a trench-slope basin, some 300 km from active volcanoes. Their occurrence is consistent with long-distance fluvial transport followed by a point-source discharge into the deep-sea environment, and has no implications for the paleogeographic location of the basins relative to the volcanic arc. The tephra beds are calc-alkaline rhyolites with SiO 2 contents in the range 72-78 wt% (recalculated on a volatile-free basis), and are broadly similar to glassy rocks of the CVZ. Their major oxide, trace element, and REE compositions are indistinguishable from glasses of TVZ rhyolites. The trace element and REE compositional variability in the Late Miocene tephra beds, which were erupted over an estimated duration of c. 0.5-2.4 m.y. is no greater than that of large silicic eruptives of the last 350 ka, and is suggestive of a long-lived source and/or similar magmatic processes. However, the individual tephra beds are products of discrete homogeneous magma batches. New fission track ages of the Miocene tephra beds suggest the main period of volcaniclastic deposition occurred in the interval c. 9-7 Ma. This corresponds well with the initiation of rhyolitic volcanism in the CVZ at c. 10 Ma, and a major period of caldera formation that took place to c. 7 Ma. The ages suggest a sediment accumulation rate of between 0.23 and 1.2 m/ka (av. 0.4 m/ka), and a frequency of eruption of

  5. Correlation of Plio Pleistocene Tephra in Ethiopian and Kenyan rift basins: Temporal calibration of geological features and hominid fossil records

    Science.gov (United States)

    WoldeGabriel, Giday; Hart, William K.; Katoh, Shigehiro; Beyene, Yonas; Suwa, Gen

    2005-10-01

    The 200-m-thick fossiliferous Konso Formation and overlying terrace deposits, which crop out at the end of the southern sector of the Main Ethiopian Rift (MER), contain more than 30 distal tephra layers. Local and regional tephra correlations of more than 20 tephra units were established using major and trace element data of discrete and purified bulk glass samples within the Konso study area. Eleven correlative marker tuffs were recognized in stratigraphic sections of both the Konso Formation and the Omo-Turkana Basin sediments in southern Ethiopia and northern Kenya. The Turoha, Hope, Ivory, Bright White, and Boleshe Tuffs in the Konso Formation, and the Upper White Tuff in the overlying terrace deposits are securely correlated with the KBS, Akait, Lokapetamoi, Chari, Lower Nariokotome, and Silbo Tuffs of the Omo-Turkana Basin, using least mobile major elements (CaO, Fe 2O 3*, and TiO 2) and geochronology. Preliminary correlations are also suggested between the Konso Formation distal tephra and proximal units of the Quaternary caldera-forming silicic centers in the central sector of the MER. The strongly peralkaline tuffs of the Konso Formation are compositionally similar to proximal eruptions mostly located along the Quaternary axial rift zone of the southern, central, and northern sectors of the MER. The tephra correlation provides information about the temporal and spatial features of the volcanic and tectonic processes recorded in the evolving basins. Thickness and sedimentation rate were determined for both the Konso Formation and the Omo-Turkana Basin sections, measured between the Turoha (=KBS; 1.91 ± 0.03 Ma) and the Bright White (=Chari; 1.40 ± 0.02 Ma) Tuffs. Although the lithostratigraphic sequence at the Konso study area is younger, sedimentation rate within the Konso Formation was comparable to that of the Koobi Fora Formation, higher in the Nachukui Formation, and lower in the Shungura Formation. Local and regional differences in thickness and

  6. Thermoluminescence dating of a tephra deposit of the ''Toya'' volcano (Hokkaido, Japan)

    International Nuclear Information System (INIS)

    Sanzelle, S.; Pilleyre, Th.; Miallier, D.; Fain, J.; Ganzawa, Y.

    2000-01-01

    Toya caldera which has a diameter of about 10 km and a hexagonal form is situated in the southern part of Hokkaido, northern Japan. The water level of the caldera lake is 84 m and the highest altitude of the central dome in the lake, Nakajima is 454 m. The volcanic activity is divided into 4 stages of the Toya Pyroclastic Flow Deposits 1 to 4. This tephra is composed of rhyolitic ash which is rich in glass and associated with hornblende, pyroxene and quartz. In a previous work, the age of eruption was estimated by utilising several dating methods and the stratigraphical correlation with other tephra. The ages which resulted from FT (Fission Tracks) dating and TL (Thermoluminescence) dating indicated 130±30 ka and 103-134 ka, respectively. The overall estimated age, received from other information such as the environmental change of mineral marine deposits, has been accepted as 100-120 ka by Quaternary Researchers. Because this tephra can be found widely in the Quaternary field, many researchers can use it as an appropriate age indicator of the 5c or 5d Isotope Stage, the middle age of the Last Internal Glacial Age. A new dating program was initiated, using the red TL of quartz grains extracted from the tephra. The samples studied in the present work came from the southern part of the deposits, around 15 km away from the centre of the caldera. The TL measurements, using the red signal of xenolithic quartz grains from the tephra, were made at Aubiere. Three distinct sets of samples were measured. The first two differ from each other by grain size, 250-350 μm (TOYA2, Aset2) and 150-250 μm (TOYA1,Bset3), and were irradiated in Japan and the third one, 250-350 μm (TOYA2, Cset2) was irradiated at Aubiere. The annual dose rate experienced by the samples during burial was estimated from a compilation of radionuclide contents evaluated in Japan using NAA and in France, using low level gamma spectroscopy (Aubiere) and ICPMS (CRPG, Nancy). In situ water content (as dug

  7. Electron microprobe analyses of glasses from Kīlauea tephra units, Kīlauea Volcano, Hawaii

    Science.gov (United States)

    Helz, Rosalind L.; Clague, David A.; Mastin, Larry G.; Rose, Timothy R.

    2014-01-01

    This report presents approximately 2,100 glass analyses from three tephra units of Kīlauea Volcano: the Keanakākoʻi Tephra, the Kulanaokuaiki Tephra, and the Pāhala Ash. It also includes some new analyses obtained as part of a re-evaluation of the MgO contents of glasses in two of the three original datasets; this re-evaluation was conducted to improve the consistency of glass MgO contents among the three datasets. The glass data are a principal focus of Helz and others (in press), which will appear in the AGU Monograph Hawaiian Volcanoes—From Source to Surface. The report is intended to support this publication, in addition to making the data available to the scientific community.

  8. New zircon (U-Th)/He and U/Pb eruption age for the Rockland tephra, western USA

    Science.gov (United States)

    Coble, Matthew A.; Burgess, Seth D.; Klemetti, Erik W.

    2017-09-01

    Eruption ages of a number of prominent Quaternary volcanic deposits remain inaccurately and/or imprecisely constrained, despite their importance as regional stratigraphic markers in paleo-environment reconstruction and as evidence of climate-altering eruptions. Accurately dating volcanic deposits presents challenging analytical considerations, including poor radiogenic yield, scarcity of datable minerals, and contamination of crystal populations by magma, eruption, and transport processes. One prominent example is the Rockland tephra, which erupted from the Lassen Volcanic Center in the southern Cascade arc. Despite a range in published eruption ages from 0.40 to 0.63 Ma, the Rockland tephra is extensively used as a marker bed across the western United States. To more accurately and precisely constrain the age of the Rockland tephra-producing eruption, we report U/Pb crystallization dates from the outermost ∼2 μm of zircon crystal faces (surfaces) using secondary ion mass spectrometry (SIMS). Our new weighted mean 238U/206Pb age for Rockland tephra zircon surfaces is 0.598 ± 0.013 Ma (2σ) and MSWD = 1.11 (mean square weighted deviation). As an independent test of the accuracy of this age, we obtained new (U-Th)/He dates from individual zircon grains from the Rockland tephra, which yielded a weighted mean age of 0.599 ± 0.012 Ma (2σ, MSWD = 5.13). We also obtained a (U-Th)/He age of 0.628 ± 0.014 Ma (MSWD = 1.19) for the Lava Creek Tuff member B, which was analyzed as a secondary standard to test the accuracy of the (U-Th)/He technique for Quaternary tephras, and to evaluate assumptions made in the model-age calculation. Concordance of new U/Pb and (U-Th)/He zircon ages reinforces the accuracy of our preferred Rockland tephra eruption age, and confirms that zircon surface dates sample zircon growth up to the time of eruption. We demonstrate the broad applicability of coupled U/Pb zircon-surface and single-grain zircon (U-Th)/He geochronology to accurate

  9. Using Spectroscopy to Infer the Eruption Style and Volatile History of Volcanic Tephras

    Science.gov (United States)

    McBride, M. J.; Horgan, B. H. N.; Rowe, M. C.; Wall, K. T.; Oxley, B. M.

    2017-12-01

    The interaction between volatiles and magma strongly influences volcanic eruption styles, and results in an increase in the glass component of volcanic tephra. On Earth, both phreatomagmatic and magmatic explosive eruptions create glassy tephras. Phreatomagmatic eruptions form abundant glass by quickly quenching lava through interaction with meteoric water while magmatic eruptions create less glass through slower cooling within larger pyroclasts or eruption columns. Wall et al. (2014) used X-ray diffraction (XRD) of diverse tephra samples to show that glass content correlates with eruption style, as magmatic samples contain less glass than phreatomagmatic samples. While use of XRD is limited to Earth and the Curiosity rover on Mars, orbital spectroscopy is much a more common technique in the exploration of terrestrial bodies. In this study, we evaluate whether or not spectroscopy can be used to infer eruption style and thus volatile history. Visible/near-infrared (VNIR) and thermal-infrared (TIR) spectra were collected of the Wall et al. (2014) tephra samples, and were analyzed for trends related to glass content and thus eruption style. VNIR spectra can detect glass at high abundances as well as hydrothermal alteration minerals produced during interactions with meteoric water. Using TIR, glass abundances can be derived by deconvolving the spectra with a standard spectral library; however, due to the non-unique spectral shape of glass, intermediate to high glass abundances in tephras are difficult to differentiate using TIR alone. Synthetic mixtures of glass and crystalline minerals verify these results. Therefore, the most effective method for determining glass abundance and thus eruption style from volcanic deposits is a combination of VNIR and TIR spectral analysis. Using standard planetary remote sensing instrumentation to infer eruption styles will provide a new window into the volcanic and volatile histories of terrestrial bodies.

  10. A volcanic event forecasting model for multiple tephra records, demonstrated on Mt. Taranaki, New Zealand

    Science.gov (United States)

    Damaschke, Magret; Cronin, Shane J.; Bebbington, Mark S.

    2018-01-01

    Robust time-varying volcanic hazard assessments are difficult to develop, because they depend upon having a complete and extensive eruptive activity record. Missing events in eruption records are endemic, due to poor preservation or erosion of tephra and other volcanic deposits. Even with many stratigraphic studies, underestimation or overestimation of eruption numbers is possible due to mis-matching tephras with similar chemical compositions or problematic age models. It is also common to have gaps in event coverage due to sedimentary records not being available in all directions from the volcano, especially downwind. Here, we examine the sensitivity of probabilistic hazard estimates using a suite of four new and two existing high-resolution tephra records located around Mt. Taranaki, New Zealand. Previous estimates were made using only single, or two correlated, tephra records. In this study, tephra data from six individual sites in lake and peat bogs covering an arc of 120° downwind of the volcano provided an excellent temporal high-resolution event record. The new data confirm a previously identified semi-regular pattern of variable eruption frequency at Mt. Taranaki. Eruption intervals exhibit a bimodal distribution, with eruptions being an average of 65 years apart, and in 2% of cases, centuries separate eruptions. The long intervals are less common than seen in earlier studies, but they have not disappeared with the inclusion of our comprehensive new dataset. Hence, the latest long interval of quiescence, since AD 1800, is unusual, but not out of character with the volcano. The new data also suggest that one of the tephra records (Lake Rotokare) used in earlier work had an old carbon effect on age determinations. This shifted ages of the affected tephras so that they were not correlated to other sites, leading to an artificially high eruption frequency in the previous combined record. New modelled time-varying frequency estimates suggest a 33

  11. Does Thermal Granulation Drive Tephra Jets?

    Science.gov (United States)

    White, J. D.; Zimanowski, B.; Buettner, R.; Sonder, I.; Dellino, P.

    2011-12-01

    Surtseyan tephra jets, also called cypressoid or cock's tail plumes, comprise a characteristic mixture of ash with bombs travelling roughly ballistic paths that tip the individual fingers of the projecting jet. Jets of similar form but smaller scale are generated by littoral magma-water interactions, confirming the general inference that surtseyan tephra jets are a characteristic product of explosive magma-water interaction, and suggesting that magmatic volatiles play a subsidiary role, if any, in their formation. Surtseyan jets have been inferred to result from both intense fuel-coolant interactions, and from simple boiling of water entrained into rising magma, and little new information has become available to test these two positions since they were clearly developed in the 1980s. Recent experiments in which magma is poured into standing water have produced vigorous jetting of hot water as melt solidifies and undergoes extensive thermal granulation. We present high-resolution hi-speed video of these jets, which we see as having the following origin. As thermal granulation takes place, a fracture network advances into the melt/glass body, and water invading the cracks at the rate of propagation is heated nearly instantaneously. Vapor produced at the contact expands and drives outward through cooled cracks, condensing as it moves to the exterior of the magma body where it is emitted as a jet of hot water. In ocean ridge hydrothermal systems a diffuse crack network inducts cold water, which is heated and expelled in focused jets. Focusing of hot outflow in experiments is inferred to result, as suggested for ridge hydrothermal systems, from thermoelastic closure of cracks near the one(s) feeding the jet. From the cooled products of our experimental runs, we know that thermal contraction produces a network of curved cracks with modal spacing of 1-2 mm, which separate domains of unbroken glass. It is during growth of this crack network that cold water enters, is

  12. Modulation of glacier ablation by tephra coverage from Eyjafjallajökull and Grímsvötn volcanoes, Iceland: an automated field experiment

    Science.gov (United States)

    Möller, Rebecca; Möller, Marco; Kukla, Peter A.; Schneider, Christoph

    2018-01-01

    We report results from a field experiment investigating the influence of volcanic tephra coverage on glacier ablation. These influences are known to be significantly different from those of moraine debris on glaciers due to the contrasting grain size distribution and thermal conductivity. Thus far, the influences of tephra deposits on glacier ablation have rarely been studied. For the experiment, artificial plots of two different tephra types from Eyjafjallajökull and Grímsvötn volcanoes were installed on a snow-covered glacier surface of Vatnajökull ice cap, Iceland. Snow-surface lowering and atmospheric conditions were monitored in summer 2015 and compared to a tephra-free reference site. For each of the two volcanic tephra types, three plots of variable thickness ( ˜ 1.5, ˜ 8.5 and ˜ 80 mm) were monitored. After limiting the records to a period of reliable measurements, a 50-day data set of hourly records was obtained, which can be downloaded from the Pangaea data repository (pangaea.de" target="_blank">https://www.pangaea.de; doi:10.1594/PANGAEA.876656). The experiment shows a substantial increase in snow-surface lowering rates under the ˜ 1.5 and ˜ 8.5 mm tephra plots when compared to uncovered conditions. Under the thick tephra cover some insulating effects could be observed. These results are in contrast to other studies which depicted insulating effects for much thinner tephra coverage on bare-ice glacier surfaces. Differences between the influences of the two different petrological types of tephra exist but are negligible compared to the effect of tephra coverage overall.

  13. Multi-criteria correlation of tephra deposits to source centres applied in the Auckland Volcanic Field, New Zealand

    Science.gov (United States)

    Hopkins, Jenni L.; Wilson, Colin J. N.; Millet, Marc-Alban; Leonard, Graham S.; Timm, Christian; McGee, Lucy E.; Smith, Ian E. M.; Smith, Euan G. C.

    2017-07-01

    Linking tephras back to their source centre(s) in volcanic fields is crucial not only to reconstruct the eruptive history of the volcanic field but also to understand tephra dispersal patterns and thus the potential hazards posed by a future eruption. Here we present a multi-disciplinary approach to correlate distal basaltic tephra deposits from the Auckland Volcanic Field (AVF) to their source centres using proximal whole-rock geochemical signatures. In order to achieve these correlations, major and trace element tephra-derived glass compositions are compared with published and newly obtained whole-rock geochemical data for the entire field. The results show that incompatible trace element ratios (e.g. (Gd/Yb)N, (La/Yb)N, (Zr/Yb)N) vary widely across the AVF (e.g. (La/Yb)N = 5 to 40) but show a more restricted range within samples from a single volcanic centre (e.g. (La/Yb)N = 5 to 10). These ratios are also the least affected by fractional crystallisation and are therefore the most appropriate geochemical tools for correlation between tephra and whole-rock samples. However, findings for the AVF suggest that each volcanic centre does not have a unique geochemical signature in the field as a whole, thus preventing unambiguous correlation of tephras to source centre using geochemistry alone. A number of additional criteria are therefore combined to further constrain the source centres of the distal tephras including age, eruption scale, and location (of centres, and sites where tephra were sampled). The combination of tephrostratigraphy, 40Ar/39Ar dating and morphostratigraphic constraints allow, for the first time, the relative and absolute ordering of 48 of 53 volcanic centres of the Auckland Volcanic Field to be resolved. Eruption frequencies are shown to vary between 0.13 and 1.5 eruptions/kyr and repose periods between individual eruptions vary from <0.1 to 13 kyr, with 23 of the 48 centres shown to have pre-eruptive repose periods of <1000 years. No spatial

  14. physical volcanology of pyroclastic tephra deposit at batoke mt.

    African Journals Online (AJOL)

    Home

    2013-04-16

    Apr 16, 2013 ... In the deposit three facies types; which are the lava flow, the lapilli and ash ... flow flanked by the tephra pile, the lack of accidental clasts, and the ..... Origin of the Lethal gas ... eruption behaviour and petrochemistry of lava.

  15. Tephra stratification of volcanic ash soils in Nothern Ecuador

    NARCIS (Netherlands)

    Tonneijck, F.H.; Hageman, J.A.; Sevink, J.; Verstraten, J.M.

    2008-01-01

    We combined proxies traditionally used in stratigraphic research (mineral assemblages, grain size distribution, and element ratios) with soil organic carbon contents and radiocarbon dating both at a high vertical resolution, to unravel the tephra stratigraphy in volcanic ash soils. Our results show

  16. Stratigraphic and compositional complexities of the late Quaternary Lethe tephra in South-central Alaska

    Science.gov (United States)

    Riehle, J.R.; Ager, T.A.; Reger, R.D.; Pinney, D.S.; Kaufman, D.S.

    2008-01-01

    Recently discovered Lethe tephra has been proposed as a latest Pleistocene marker bed in Bristol Bay lowland NE to the Cook Inlet region, Alaska, on the basis of correlations involving a single "Lethe average" glass composition. Type deposits in the Valley of Ten Thousand Smokes, however, are chemically heterogeneous-individual lapilli as well as aggregate ash deposits have glass compositions that range from the average mode to much higher SiO2 and K2O. Moreover, a lake-sediment core from the Cook Inlet region contains one ash deposit similar to "Lethe average" and other, closely underlying deposits that resemble a mixture of the average mode and high-Si high-K mode of proximal deposits. Synthesis of previously published radiocarbon ages indicates a major eruption mainly of "Lethe average" mode about 13,000 14C yr BP. As many as six deposits in the Cook Inlet region-five chiefly "Lethe average" mode-range from about 13,000 to 15-16,000 14C yr BP, and an early Holocene deposit in the Bristol Bay lowland extends the minimum age range of Lethe tephra throughout this region to 8000 14C yr BP. Because of the appearance of "Lethe average" composition in multiple deposits spanning thousands of years, we urge caution when using a Lethe-like composition as a basis for inferring a latest Pleistocene age of a tephra deposit in south-central Alaska. Linear variation plots suggest that magma mixing caused the Lethe heterogeneity; multiple magmas were involved as well in other large pyroclastic eruptions such as Katmai (Alaska) and Rotorua (New Zealand). Lethe is an example of a heterogeneous tephra that may be better compared with other tephras by use of plots of individual analytical points rather than by calculating similarity coefficients based on edited data. ?? 2006 Elsevier Ltd and INQUA.

  17. Holocene vegetation, environment, and tephra recorded from Lake Pupuke, Auckland, New Zealand

    International Nuclear Information System (INIS)

    Horrocks, M.; Augustinus, P.; Deng, Y.; Shane, P.; Andersson, S.

    2005-01-01

    Lake Pupuke provides a near-complete, high-resolution environmental record of the Holocene from northern New Zealand. Tephra beds constrain the timing of a range of proxy indicators of environmental change, and demonstrate errors in a radiocarbon chronology. Agathis australis forest progressively increases from c. 7000 yr BP and, in conjunction with indicators of reduced biomass productivity, support a model of long-term climate change to drier conditions over the Holocene. However, except for Agathis, conifer-hardwood forest dominated mainly by Dacrydium cupressinum shows little change throughout the pre-human Holocene, suggesting environmental stability. Dramatic vegetation change occurred only within the last millennium as a result of large-scale Polynesian deforestation by fire. This happened a short time before the local eruption of c. 638 cal. yr BP Rangitoto Tephra. The identification of two eruptions of tephra from Rangitoto volcano has implications for future hazard planning in the Auckland region, because the volcanoes were previously considered single event centres. Changes in atmospheric circulation since the Late Glacial, possibly causing lower frequency of distal ashfall in Auckland during the Holocene, complicates the use of long-term records in hazard frequency assessment. (author). 39 refs., 7 figs., 2 tabs

  18. A quantitative X-ray diffraction inventory of the tephra and volcanic glass inputs into the Holocene marine sediment archives off Iceland: A contribution to V.A.S.T.

    Science.gov (United States)

    Andrews, John T.; Kristjansdottir, Greta B.; Eberl, Dennis D.; Jennings, Anne E.

    2013-01-01

    This paper re-evaluates how well quantitative x-ray diffraction (qXRD) can be used as an exploratory method of the weight percentage (wt%) of volcaniclastic sediment, and to identify tephra events in marine cores. In the widely used RockJock v6 software programme, qXRD tephra and glass standards include the rhyodacite White River tephra (Alaska), a rhyolitic tephra (Hekla-4) and the basaltic Saksunarvatn tephra. Experiments of adding known wt% of tephra to felsic bedrock samples indicated that additions ≥10 wt% are accurately detected, but reliable estimates of lesser amounts are masked by amorphous material produced by milling. Volcaniclastic inputs range between 20 and 50 wt%. Primary tephra events are identified as peaks in residual qXRD glass wt% from fourth-order polynomial fits. In cores where tephras have been identified by shard counts in the > 150 µm fraction, there is a positive correlation (validation) with peaks in the wt% glass estimated by qXRD. Geochemistry of tephra shards confirms the presence of several Hekla-sourced tephras in cores B997-317PC1 and -319PC2 on the northern Iceland shelf. In core B997-338 (north-west Iceland), there are two rhyolitic tephras separated by ca. 100 cm with uncorrected radiocarbon dates on articulated shells of around 13 000 yr B.P. These tephras may be correlatives of the Borrobol and Penifiler tephras found in Scotland. The number of Holocene tephra events per 1000 yr was estimated from qXRD on 16 cores and showed a bimodal distribution with an increased number of events in both the late and early Holocene.

  19. Tulelake, California: The last 3 million years

    Science.gov (United States)

    Adam, D.P.; Sarna-Wojcicki, A. M.; Rieck, Hugh J.; Bradbury, J.P.; Dean, W.E.; Forester, R.M.

    1989-01-01

    The Tulelake basin, formed by east-west extension and faulting during the past several million years, contains at least 550 m of lacustrine sediment. Interdisciplinary studies of a 334 m-long cored section from the town of Tulelake, California, near the center of the basin, document a 3-m.y. record of environmental changes. The core consists of a thick sequence of diatomaceous clayey, silty, and marly lacustrine sediments interbedded with numerous tephra layers. Paleomagnetic study puts the base of the core at about 3.0 Ma. Twelve widespread silicic tephra units provide correlations with other areas and complement age control provided by magnetostratigraphy; mafic and silicic tephra units erupted from local sources are also common in the core. Widespread tephra units include the Llao Rock pumice (=Tsoyawata, 7 ka), the Trego Hot Springs Bed (23 ka), and the Rockland (0.40 Ma), Lava Creek (0.62 Ma), and Rio Dell (1.5 Ma) ash beds, as well as several ash beds also found at Summer Lake, Oregon, and an ash bed originally recognized in DSDP hole 173 in the northeastern Pacific. Several tephra layers found in the core also occur in lacustrine beds exposed around the margins of the basin and elsewhere in the ancestral lacustrine system. Diatoms are present throughout the section. Pollen is present in most of the section, but some barren zones are found in the interval between 50 and 140 m; the greatest change in behavior of the pollen record takes place just above the top of the Olduvai Normal-Polarity Subchronozone. Ostracodes are present only in high-carbonate (>10% CaCO3) intervals. Evolutionary changes are found in the diatom and ostracode records. Bulk geochemical analyses show significant changes in elemental composition of the sediment through time. ?? 1989.

  20. Remarkably preserved tephra from the 3430 Ma Strelley Pool Formation, Western Australia: Implications for the interpretation of Precambrian microfossils

    Science.gov (United States)

    Wacey, David; Saunders, Martin; Kong, Charlie

    2018-04-01

    The ∼3430 Ma Strelley Pool Formation (SPF), Pilbara, Western Australia contains some of the most diverse microfossil evidence for early life on Earth. Here we report an assemblage of tephra (scoria, tubular pumice, plus vesicular and non-vesicular volcanic glass shards) from two stratigraphic levels in the SPF, including morphotypes that closely resemble previously described microfossils from this unit and elsewhere. Clasts of scoria are characterised by numerous spheroidal vesicles, with subordinate eye- and lens-shaped morphotypes, commonly lined with anatase (TiO2) and small amounts of organic material. Their diameters range from 5-180 μm with 80% in the 10-50 μm range. Fragments of tubular pumice are also lined with anatase + / - carbon and have tube diameters of 5-15 μm. Other volcanic ejecta particles include a multitude of sub-angular shard particles with or without vesicles, plus more rounded vase-shaped, eye-shaped, and hair-like morphologies; once again, most of these are coated by anatase + / - carbon and are several tens of micrometres in size. Many of the tephra fragments are now entirely silicified with no compositional difference between the former volcanic glass, the vesicle infill and the clast matrix. However, some examples retain a partial aluminosilicate composition, either as a vesicle infilling phase or as isolated lath-like grains within the formerly glassy groundmass. Isolated occurrences of some of these tephra morphotypes strongly resemble simple microbial morphologies including pairs and clusters of cells (cf. scoria), filamentous microbes (cf. tubular pumice) and larger sheaths/cysts (cf. sub-rounded glass shards). Furthermore, some tephra-containing clasts occur in a SPF sandstone unit that hosts previously described microfossils, while others are interbedded with chert layers from which microfossils have also been described. In light of our new volcanogenic data, we evaluate the robustness of previous microfossil evidence from the

  1. Introducing Geoscience Students to Numerical Modeling of Volcanic Hazards: The example of Tephra2 on VHub.org

    Directory of Open Access Journals (Sweden)

    Leah M. Courtland

    2012-07-01

    Full Text Available The Tephra2 numerical model for tephra fallout from explosive volcanic eruptions is specifically designed to enable students to probe ideas in model literacy, including code validation and verification, the role of simplifying assumptions, and the concepts of uncertainty and forecasting. This numerical model is implemented on the VHub.org website, a venture in cyberinfrastructure that brings together volcanological models and educational materials. The VHub.org resource provides students with the ability to explore and execute sophisticated numerical models like Tephra2. We present a strategy for using this model to introduce university students to key concepts in the use and evaluation of Tephra2 for probabilistic forecasting of volcanic hazards. Through this critical examination students are encouraged to develop a deeper understanding of the applicability and limitations of hazard models. Although the model and applications are intended for use in both introductory and advanced geoscience courses, they could easily be adapted to work in other disciplines, such as astronomy, physics, computational methods, data analysis, or computer science.

  2. Classifying the Sizes of Explosive Eruptions using Tephra Deposits: The Advantages of a Numerical Inversion Approach

    Science.gov (United States)

    Connor, C.; Connor, L.; White, J.

    2015-12-01

    Explosive volcanic eruptions are often classified by deposit mass and eruption column height. How well are these eruption parameters determined in older deposits, and how well can we reduce uncertainty using robust numerical and statistical methods? We describe an efficient and effective inversion and uncertainty quantification approach for estimating eruption parameters given a dataset of tephra deposit thickness and granulometry. The inversion and uncertainty quantification is implemented using the open-source PEST++ code. Inversion with PEST++ can be used with a variety of forward models and here is applied using Tephra2, a code that simulates advective and dispersive tephra transport and deposition. The Levenburg-Marquardt algorithm is combined with formal Tikhonov and subspace regularization to invert eruption parameters; a linear equation for conditional uncertainty propagation is used to estimate posterior parameter uncertainty. Both the inversion and uncertainty analysis support simultaneous analysis of the full eruption and wind-field parameterization. The combined inversion/uncertainty-quantification approach is applied to the 1992 eruption of Cerro Negro (Nicaragua), the 2011 Kirishima-Shinmoedake (Japan), and the 1913 Colima (Mexico) eruptions. These examples show that although eruption mass uncertainty is reduced by inversion against tephra isomass data, considerable uncertainty remains for many eruption and wind-field parameters, such as eruption column height. Supplementing the inversion dataset with tephra granulometry data is shown to further reduce the uncertainty of most eruption and wind-field parameters. We think the use of such robust models provides a better understanding of uncertainty in eruption parameters, and hence eruption classification, than is possible with more qualitative methods that are widely used.

  3. Tephra from the 1979 soufriere explosive eruption.

    Science.gov (United States)

    Sigurdsson, H

    1982-06-04

    The explosive phase of the 1979 Soufriere eruption produced 37.5 x 10(6) cubic meters (dense-rock equivalent) of tephra, consisting of about 40 percent juvenile basaltic andesite and 60 percent of a nonjuvenile component derived from the fragmentation of the 1971-1972 lava island during phreatomagmatic explosions. The unusually fine grain size, poor sorting, and bimodality of the land deposit are attributed to particle aggregation and the formation of accretionary lapilli in a wet eruption column.

  4. Probabilistic tephra hazard maps for the Neapolitan area: Quantitative volcanological study of Campi Flegrei eruptions

    Science.gov (United States)

    Mastrolorenzo, G.; Pappalardo, L.; Troise, C.; Panizza, A.; de Natale, G.

    2008-07-01

    Tephra fall is a relevant hazard of Campi Flegrei caldera (Southern Italy), due to the high vulnerability of Naples metropolitan area to such an event. Here, tephra derive from magmatic as well as phreatomagmatic activity. On the basis of both new and literature data on known, past eruptions (Volcanic Explosivity Index (VEI), grain size parameters, velocity at the vent, column heights and erupted mass), and factors controlling tephra dispersion (wind velocity and direction), 2D numerical simulations of fallout dispersion and deposition have been performed for a large number of case events. A bayesian inversion has been applied to retrieve the best values of critical parameters (e.g., vertical mass distribution, diffusion coefficients, velocity at the vent), not directly inferable by volcanological study. Simulations are run in parallel on multiple processors to allow a fully probabilistic analysis, on a very large catalogue preserving the statistical proprieties of past eruptive history. Using simulation results, hazard maps have been computed for different scenarios: upper limit scenario (worst-expected scenario), eruption-range scenario, and whole-eruption scenario. Results indicate that although high hazard characterizes the Campi Flegrei caldera, the territory to the east of the caldera center, including the whole district of Naples, is exposed to high hazard values due to the dominant westerly winds. Consistently with the stratigraphic evidence of nature of past eruptions, our numerical simulations reveal that even in the case of a subplinian eruption (VEI = 3), Naples is exposed to tephra fall thicknesses of some decimeters, thereby exceeding the critical limit for roof collapse. Because of the total number of people living in Campi Flegrei and the city of Naples (ca. two million of inhabitants), the tephra fallout risk related to a plinian eruption of Campi Flegrei largely matches or exceeds the risk related to a similar eruption at Vesuvius.

  5. Tephrochronology of the Brooks River Archaeological District, Katmai National Park and Preserve, Alaska: What can and cannot be done with tephra deposits

    Science.gov (United States)

    Riehle, J.R.; Dumond, D.E.; Meyer, C.E.; Schaaf, J.M.

    2000-01-01

    The Brooks River Archaeological District (BRAD) in Katmai National Park and Preserve is a classical site for the study of early humans in Alaska. Because of proximity to the active Aleutian volcanic arc, there are numerous tephra deposits in the BRAD, which are potentially useful for correlating among sites of archaeological investigations. Microprobe analyses of glass separates show, however, that most of these tephra deposits are heterogeneous mixtures of multiple glass populations. Some glasses are highly similar to pyroclasts of Aniakchak Crater (160 km to the south), others are similar to pyroclasts in the nearby Valley of Ten Thousand Smokes, and some are similar to no other tephra samples from the Alaska Peninsula. Moreover, tephra deposits in any one archaeological study site are not always similar to those from nearby sites, indicating inconsistent preservation of these mainly thin, fine-grained deposits. At least 15, late Holocene tephra deposits are inferred at the BRAD. Their heterogeneity is the result of either eruptions of mixed or heterogeneous magmas, like the 1912 Katmai eruption, or secondary mixing of closely succeeding tephra deposits. Because most cannot be reliably distinguished from one another on the basis of megascopic properties, their utility for correlations is limited. At least one deposit can be reliably identified because of its thickness (10 cm) and colour stratification. Early humans seem not to have been significantly affected by these tephra falls, which is not surprising in view of the resilience exhibited by both plants and animals following the 1912 Katmai eruption.

  6. Assessing the long-term probabilistic volcanic hazard for tephra fallout in Reykjavik, Iceland: a preliminary multi-source analysis

    Science.gov (United States)

    Tonini, Roberto; Barsotti, Sara; Sandri, Laura; Tumi Guðmundsson, Magnús

    2015-04-01

    Icelandic volcanism is largely dominated by basaltic magma. Nevertheless the presence of glaciers over many Icelandic volcanic systems results in frequent phreatomagmatic eruptions and associated tephra production, making explosive eruptions the most common type of volcanic activity. Jökulhlaups are commonly considered as major volcanic hazard in Iceland for their high frequency and potentially very devastating local impact. Tephra fallout is also frequent and can impact larger areas. It is driven by the wind direction that can change with both altitude and season, making impossible to predict a priori where the tephra will be deposited during the next eruptions. Most of the volcanic activity in Iceland occurs in the central eastern part, over 100 km to the east of the main population centre around the capital Reykjavík. Therefore, the hazard from tephra fallout in Reykjavík is expected to be smaller than for communities settled near the main volcanic systems. However, within the framework of quantitative hazard and risk analyses, less frequent and/or less intense phenomena should not be neglected, since their risk evaluation depends on the effects suffered by the selected target. This is particularly true if the target is highly vulnerable, as large urban areas or important infrastructures. In this work we present the preliminary analysis aiming to perform a Probabilistic Volcanic Hazard Assessment (PVHA) for tephra fallout focused on the target area which includes the municipality of Reykjavík and the Keflavík international airport. This approach reverts the more common perspective where the hazard analysis is focused on the source (the volcanic system) and it follows a multi-source approach: indeed, the idea is to quantify, homogeneously, the hazard due to the main hazardous volcanoes that could pose a tephra fallout threat for the municipality of Reykjavík and the Keflavík airport. PVHA for each volcanic system is calculated independently and the results

  7. Refining and augmenting Central Mediterranean Tephrochronologies using visible and non-visible distal ash layers from the Upper Pleistocene

    Science.gov (United States)

    Bourne, A.; Trincardi, F.; Blockley, S. P. E.; Lowe, J. J.

    2009-04-01

    The development of long and well dated regional records of environmental change is essential if we are to understand the long term working of the environmental system. The application of volcanic ash layers as time-parallel markers is developing as a tool to link archaeological and geological sequences. This presentation will make a key contribution to the PROMESS 1 European Project - PROfiles across Mediterranean Sedimentary System (http://promess1.pangaea.de/ ). The project aims to understand the sediment systems of Continental Margins by investigating changes in sea level, oceanographic regime and sediment flux. The precise and robust chronological control that is required to address these issues is frequently unavailable using traditional chronological techniques. Tephrochronology offers the potential of isochronous marker horizons that can provide independent age estimates and be used to correlate terrestrial and marine sequences over several glacial-interglacial cycles. Here we will summarise new tephrochronological results for the PROMESS-1 marine core PRAD 1-2, obtained from a water depth of 184m in the central Adriatic. The recovered sediment sequence is 71m long, spans at least 3 glacial-interglacial cycles and analysis of foraminiferal assemblages suggests the sequence extends back to Marine Isotope Stage 10. Current Central Mediterranean tephrochronology schemes are largely or entirely based on analysis of visible tephra layers. Density separation extraction techniques have been developed (Turney 1998; Blockley et al, 2005) which demonstrate that many more non-visible tephra layers exist than have previously been recognised in Mediterranean sequences, greatly enhancing the potential of tephrochronology as an independent dating method. A detailed Adriatic tephrochronology for the last 100kyr will be presented which indicates a more complicated eruptive history than visible tephra layers have previously suggested. 24 discrete and undisturbed non

  8. Inferring the effects of compositional boundary layers on crystal nucleation, growth textures, and mineral chemistry in natural volcanic tephras through submicron-resolution imaging

    Directory of Open Access Journals (Sweden)

    Georg F. Zellmer

    2016-09-01

    Full Text Available Crystal nucleation and growth are first order processes captured in volcanic rocks and record important information about the rates of magmatic processes and chemical evolution of magmas during their ascent and eruption. We have studied glass-rich andesitic tephras from the Central Plateau of the Southern Taupo Volcanic Zone by electron- and ion-microbeam imaging techniques to investigate down to sub-micrometre scale the potential effects of compositional boundary layers (CBLs of melt around crystals on the nucleation and growth of mineral phases and the chemistry of crystal growth zones. We find that CBLs may influence the types of mineral phases nucleating and growing, and growth textures such as the development of swallowtails. The chemistry of the CBLs also has the capacity to trigger intermittent overgrowths of nanometre-scale bands of different phases in rapidly growing crystals, resulting in what we refer to as cryptic phase zoning. The existence of cryptic phase zoning has implications for the interpretation of microprobe compositional data, and the resulting inferences made on the conditions of magmatic evolution. Identification of cryptic phase zoning may in future lead to more accurate thermobarometric estimates and thus geospeedometric constraints. In future, a more quantitative characterization of CBL formation and its effects on crystal nucleation and growth may contribute to a better understanding of melt rheology and magma ascent processes at the onset of explosive volcanic eruptions, and will likely be of benefit to hazard mitigation efforts.

  9. Atmospheric Despersal and Disposition of Tephra From a Potential Volcanic Eruption at Yucca Mountain, Nevada

    International Nuclear Information System (INIS)

    G. Keating; W.Statham

    2004-01-01

    The purpose of this model report is to provide documentation of the conceptual and mathematical model (ASHPLUME) for atmospheric dispersal and subsequent deposition of ash on the land surface from a potential volcanic eruption at Yucca Mountain, Nevada. This report also documents the ash (tephra) redistribution conceptual model. The ASHPLUME conceptual model accounts for incorporation and entrainment of waste fuel particles associated with a hypothetical volcanic eruption through the Yucca Mountain repository and downwind transport of contaminated tephra. The ASHPLUME mathematical model describes the conceptual model in mathematical terms to allow for prediction of radioactive waste/ash deposition on the ground surface given that the hypothetical eruptive event occurs. This model report also describes the conceptual model for tephra redistribution from a basaltic cinder cone. Sensitivity analyses and model validation activities for the ash dispersal and redistribution models are also presented. Analyses documented in this model report will improve and clarify the previous documentation of the ASHPLUME mathematical model and its application to the Total System Performance Assessment (TSPA) for the License Application (TSPA-LA) igneous scenarios. This model report also documents the redistribution model product outputs based on analyses to support the conceptual model

  10. Atmospheric Dispersal and Dispostion of Tephra From a Potential Volcanic Eruption at Yucca Mountain, Nevada

    Energy Technology Data Exchange (ETDEWEB)

    G. Keating; W.Statham

    2004-02-12

    The purpose of this model report is to provide documentation of the conceptual and mathematical model (ASHPLUME) for atmospheric dispersal and subsequent deposition of ash on the land surface from a potential volcanic eruption at Yucca Mountain, Nevada. This report also documents the ash (tephra) redistribution conceptual model. The ASHPLUME conceptual model accounts for incorporation and entrainment of waste fuel particles associated with a hypothetical volcanic eruption through the Yucca Mountain repository and downwind transport of contaminated tephra. The ASHPLUME mathematical model describes the conceptual model in mathematical terms to allow for prediction of radioactive waste/ash deposition on the ground surface given that the hypothetical eruptive event occurs. This model report also describes the conceptual model for tephra redistribution from a basaltic cinder cone. Sensitivity analyses and model validation activities for the ash dispersal and redistribution models are also presented. Analyses documented in this model report will improve and clarify the previous documentation of the ASHPLUME mathematical model and its application to the Total System Performance Assessment (TSPA) for the License Application (TSPA-LA) igneous scenarios. This model report also documents the redistribution model product outputs based on analyses to support the conceptual model.

  11. Kulanaokuaiki Tephra (ca, A.D. 400-1000): Newly recognized evidence for highly explosive eruptions at Kilauea Volcano, Hawai'i

    Science.gov (United States)

    Fiske, R.S.; Rose, T.R.; Swanson, D.A.; Champion, D.E.; McGeehin, J.P.

    2009-01-01

    K??lauea may be one of the world's most intensively monitored volcanoes, but its eruptive history over the past several thousand years remains rather poorly known. Our study has revealed the vestiges of thin basaltic tephra deposits, overlooked by previous workers, that originally blanketed wide, near-summit areas and extended more than 17 km to the south coast of Hawai'i. These deposits, correlative with parts of tephra units at the summit and at sites farther north and northwest, show that K??lauea, commonly regarded as a gentle volcano, was the site of energetic pyroclastic eruptions and indicate the volcano is significantly more hazardous than previously realized. Seventeen new calibrated accelerator mass spectrometry (AMS) radiocarbon ages suggest these deposits, here named the Kulanaokuaiki Tephra, were emplaced ca. A.D. 400-1000, a time of no previously known pyroclastic activity at the volcano. Tephra correlations are based chiefly on a marker unit that contains unusually high values of TiO2 and K2O and on paleomagnetic signatures of associated lava flows, which show that the Kulanaokuaiki deposits are the time-stratigraphic equivalent of the upper part of a newly exhumed section of the Uw??kahuna Ash in the volcano's northwest caldera wall. This section, thought to have been permanently buried by rockfalls in 1983, is thicker and more complete than the previously accepted type Uw??kahuna at the base of the caldera wall. Collectively, these findings justify the elevation of the Uw??kahuna Ash to formation status; the newly recognized Kulanaokuaiki Tephra to the south, the chief focus of this study, is defined as a member of the Uw??kahuna Ash. The Kulanaokuaiki Tephra is the product of energetic pyroclastic falls; no surge- or pyroclastic-flow deposits were identified with certainty, despite recent interpretations that Uw??kahuna surges extended 10-20 km from K??lauea's summit. ?? 2009 Geological Society of America.

  12. Keanakākoʻi Tephra produced by 300 years of explosive eruptions following collapse of Kīlauea's caldera in about 1500 CE

    Science.gov (United States)

    Swanson, Donald A.; Rose, Timothy R.; Fiske, Richard S.; McGeehin, John P.

    2012-01-01

    The Keanakākoʻi Tephra at Kīlauea Volcano has previously been interpreted by some as the product of a caldera-forming eruption in 1790 CE. Our study, however, finds stratigraphic and 14C evidence that the tephra instead results from numerous eruptions throughout a 300-year period between about 1500 and 1800. The stratigraphic evidence includes: (1) as many as six pure lithic ash beds interleaved in sand dunes made of earlier Keanakākoʻi vitric ash, (2) three lava flows from Kīlauea and Mauna Loa interbedded with the tephra, (3) buried syneruptive cultural structures, (4) numerous intraformational water-cut gullies, and (5) abundant organic layers rich in charcoal within the tephra section. Interpretation of 97 new accelerator mass spectrometry (AMS) 14C ages and 4 previous conventional ages suggests that explosive eruptions began in 1470–1510 CE, and that explosive activity continued episodically until the early 1800s, probably with two periods of quiescence lasting several decades. Kīlauea's caldera, rather than forming in 1790, predates the first eruption of the Keanakākoʻi and collapsed in 1470–1510, immediately following, and perhaps causing, the end of the 60-year-long, 4–6 km3 ʻAilāʻau eruption from the east side of Kīlauea's summit area. The caldera was several hundred meters deep when the Keanakākoʻi began erupting, consistent with oral tradition, and probably had a volume of 4–6 km3. The caldera formed by collapse, but no eruption of lava coincided with its formation. A large volume of magma may have quickly drained from the summit reservoir and intruded into the east rift zone, perhaps in response to a major south-flank slip event, leading to summit collapse. Alternatively, magma may have slowly drained from the reservoir during the prolonged ʻAilāʻau eruption, causing episodic collapses before the final, largest downdrop took place. Two prolonged periods of episodic explosive eruptions are known at Kīlauea, the Keanak

  13. Keanakākoʻi Tephra produced by 300 years of explosive eruptions following collapse of Kīlauea's caldera in about 1500 CE

    Science.gov (United States)

    Swanson, Donald A.; Rose, Timothy R.; Fiske, Richard S.; McGeehin, John P.

    2012-01-01

    The Keanakākoʻi Tephra at Kīlauea Volcano has previously been interpreted by some as the product of a caldera-forming eruption in 1790 CE. Our study, however, finds stratigraphic and 14C evidence that the tephra instead results from numerous eruptions throughout a 300-year period between about 1500 and 1800. The stratigraphic evidence includes: (1) as many as six pure lithic ash beds interleaved in sand dunes made of earlier Keanakākoʻi vitric ash, (2) three lava flows from Kīlauea and Mauna Loa interbedded with the tephra, (3) buried syneruptive cultural structures, (4) numerous intraformational water-cut gullies, and (5) abundant organic layers rich in charcoal within the tephra section. Interpretation of 97 new accelerator mass spectrometry (AMS) 14C ages and 4 previous conventional ages suggests that explosive eruptions began in 1470–1510 CE, and that explosive activity continued episodically until the early 1800s, probably with two periods of quiescence lasting several decades. Kīlauea's caldera, rather than forming in 1790, predates the first eruption of the Keanakākoʻi and collapsed in 1470–1510, immediately following, and perhaps causing, the end of the 60-year-long, 4–6 km3 ʻAilāʻau eruption from the east side of Kīlauea's summit area. The caldera was several hundred meters deep when the Keanakākoʻi began erupting, consistent with oral tradition, and probably had a volume of 4–6 km3. The caldera formed by collapse, but no eruption of lava coincided with its formation. A large volume of magma may have quickly drained from the summit reservoir and intruded into the east rift zone, perhaps in response to a major south-flank slip event, leading to summit collapse. Alternatively, magma may have slowly drained from the reservoir during the prolonged ʻAilāʻau eruption, causing episodic collapses before the final, largest downdrop took place. Two prolonged periods of episodic explosive eruptions are known at Kīlauea, the Keanak

  14. Tephra compositions from Late Quaternary volcanoes around the Antarctic Peninsula

    Science.gov (United States)

    Kraus, S.

    2009-12-01

    /Hf ratios lower than N-MORB, all other volcanoes including the Larsen Rift centers display Zr/Hf higher than N-MORB. It is expected that the correlation of the new data with published data from tephra layers found in ice, lake and marine sediment cores will contribute to a better constrained timing of individual climatic events identified in the northern Antarctic Peninsula area. Late Quaternary volcanoes around the northern Antarctic Peninsula.

  15. The RESET project: constructing a European tephra lattice for refined synchronisation of environmental and archaeological events during the last c. 100 ka

    Czech Academy of Sciences Publication Activity Database

    Lowe, J. J.; Ramsey, C. B.; Housley, R. A.; Lane, C. S.; Tomlinson, E. L.; Stringer, C.; Davies, W.; Barton, N.; Pollard, M.; Gamble, C.; Menzies, M.; Rohling, E.; Roberts, A.; Blockley, S.; Cullen, V.; Grant, K.; Lewis, M.; MacLeod, A.; White, D.; Albert, P.; Hardiman, M.; Lee, S.; Oh, A.; Satow, C.; Cross, J. K.; Bramham Law, C.; Todman, A.; Bourne, A.; Matthews, I.; Müller, W.; Smith, V.; Wulf, S.; Anghelinu, M.; Antl-Weiser, W.; Bar-Yosef, O.; Borić, D.; Boscato, P.; Ronchitelli, A.; Chabai, V.; Veselsky, A.; Uthmeier, T.; Farrand, W.; Gjipali, I.; Ruka, R.; Güleç, E.; Karavanić, I.; Karkanas, P.; King, T.; Komšo, D.; Koumouzelis, M.; Kyparissi, N.; Lengyel, G.; Mester, Z.; Neruda, P.; Nigst, P.; Haesaerts, P.; Panagopoulou, E.; Shalamanov-Korobar, L.; Tolevski, I.; Sinitsyn, A.; Sirakov, N.; Guadelli, A.; Guadelli, J.-L.; Ferrier, C.; Škrdla, Petr; Slimak, L.; Soler, N.; Soller, J.; Soressi, M.; Tushabramishvilii, N.; Zilhão, J.; Angelucci, D.; Cullen, V. L.; Lincoln, P.; Staff, R.; Flower, K.; Aouadi-Abdeljaouad, N.; Belhouchet, L.; Barker, G.; Bouzouggar, A.; Van Peer, P.; Kindermann, K.; Gerken, K.; Niemann, H.; Tipping, R.; Saville, A.; Ward, T.; Clausen, I.; Weber, M.-J.; Kaiser, K.; Torksdorf, J. F.; Turner, F.; Veil, S.; Nygaard, N.; Pyne-O'Donnel, S. D. F.; Masojć, M.; Nalepka, D.; Jurochnik, A.; Kabaciński, J.; Antoine, P.; Olive, M.; Christensen, M.; Bodu, P.; Debout, G.; Orliac, M.; De Bie, M.; Van Gils, M.; Paulissen, E.; Brou, L.; Leesch, D.; Hadorn, P.; Thew, N.; Riede, F.; Heinen, M.; Joris, O.; Richter, J.; Knipping, M.; Stika, H.-P.; Friedrich, M.; Conard, N. J.; Malina, M.; Kind, C.-J.; Beutelspacher, T.; Mortensen, M. F.; Burdukiewicz, J. M.; Szynkiewicz, A.; Połtowicz-Bobak, M.; Bobak, D.; Wiśniewski, A.; Przeździecki, M.; Valde-Nowak, P.; Muzyczuk, A.; Davies, L.; Morgan, P.; Aydar, E.; Çubukçu, E.; Brown, R.; Coltelli, M.; Lo Castro, D.; Cioni, R.; DeRosa, R.; Donato, P.; Di Roberto, A.; Gertisser, R.; Giordano, G.; Branney, M.; Jordan, N.; Keller, J.; Kinvig, H.; Gottsman, J.; Blundy, J.; Marani, M.; Orsi, G.; Civetta, L.; Arienzo, I.; Carandente, A.; Rosi, M.; Zanchetta, G.; Seghedi, I.; Szakacs, A.; Sulpizio, R.; Thordarson, T.; Trincardi, F.; Vigliotti, L.; Asioli, A.; Piva, A.; Andrič, M.; Brauer, A.; de Klerk, P.; Filippi, M.-L.; Finsinger, W.; Galović, L.; Jones, T.; Lotter, A.; Müller, U.; Pross, J.; Mangerud, J.; Lohne, Ø.; Pyne-O'Donnell, S.; Markovic, S.; Pini, R.; Ravazzi, C.; Theuerkauf, M.; Tzedakis, C.; Margari, V.; Veres, D.; Wastegård, S.; Ortiz, J. E.; Torres, T.; Díaz-Bautista, A.; Moreno, A.; Valero-Garcés, B.; Lowick, S.; Ottolini, L.

    2015-01-01

    Roč. 118, 15 June 2015 (2015), s. 1-17 ISSN 0277-3791 Institutional support: RVO:68081758 Keywords : Last Glacial stage * Dansgaard-Oeschger and Heinrich events * Abrupt environmental transitions (AETs) * Middle to Upper Palaeolithic * Volcanic ash isochrons * Tephra geochemistry * Tephra database Subject RIV: AC - Archeology, Anthropology, Ethnology Impact factor: 4.521, year: 2015

  16. Integrating the Holocene tephrostratigraphy for East Asia using a high-resolution cryptotephra study from Lake Suigetsu (SG14 core), central Japan

    Science.gov (United States)

    McLean, Danielle; Albert, Paul G.; Nakagawa, Takeshi; Suzuki, Takehiko; Staff, Richard A.; Yamada, Keitaro; Kitaba, Ikuko; Haraguchi, Tsuyoshi; Kitagawa, Junko; Smith, Victoria C.; SG14 Project Members

    2018-03-01

    Tephra (volcanic ash) layers have the potential to synchronise disparate palaeoenvironmental archives on regional to hemispheric scales. Highly productive arc regions, like those in East Asia, offer a considerable number of widespread isochrons, but before records can be confidently correlated using these layers, a refined and integrated framework of these eruptive events is required. Here we present the first high-resolution Holocene cryptotephra study in East Asia, using the Lake Suigetsu sedimentary archive in central Japan. The Holocene tephrostratigraphy has been extended from four to twenty ash layers using cryptotephra extraction techniques, which integrates the deposits from explosive eruptions from North Korea/China, South Korea and along the Japanese arc. This Lake Suigetsu tephrostratigraphy is now the most comprehensive record of East Asian volcanism, and the linchpin site for correlating sequences across this region. Major element glass geochemical compositions are presented for the tephra layers in the sequence, which have been compared to proximal datasets to correlate them to their volcanic source and specific eruptions. This study has significantly extended the ash dispersal of many key Holocene marker layers, and has identified the first distal occurrence of isochrons from Ulleungdo and Changbaishan volcanoes. Utilising the high-precision Lake Suigetsu chronology, we are able to provide constrained eruption ages for the tephra layers, which can be transferred into other site-specific age models containing these markers. This new framework indicates that several isochrons stratigraphically bracket abrupt climate intervals in Japan, and could be used to precisely assess the regional and hemispheric synchronicity of these events.

  17. Volatile-induced magma differentiation in the plumbing system of Mt. Etna volcano (Italy): evidence from glass in tephra of the 2001 eruption

    Science.gov (United States)

    Ferlito, Carmelo; Viccaro, Marco; Cristofolini, Renato

    2008-02-01

    Mount Etna volcano was shaken during the summer 2001 by one of the most singular eruptive episodes of the last centuries. For about 3 weeks, several eruptive fractures developed, emitting lava flows and tephra that significantly modified the landscape of the southern flank of the volcano. This event stimulated the attention of the scientific community especially for the simultaneous emission of petrologically distinct magmas, recognized as coming from different segments of the plumbing system. A stratigraphically controlled sampling of tephra layers was performed at the most active vents of the eruption, in particular at the 2,100 m (CAL) and at the 2,550 m (LAG) scoria cones. Detailed scanning electron microscope and energy dispersive x-ray spectrometer (SEM-EDS) analyses performed on glasses found in tephra and comparison with lava whole rock compositions indicate an anomalous increase in Ti, Fe, P, and particularly of K and Cl in the upper layers of the LAG sequence. Mass balance and thermodynamic calculations have shown that this enrichment cannot be accounted for by “classical” differentiation processes, such as crystal fractionation and magma mixing. The analysis of petrological features of the magmas involved in the event, integrated with the volcanological evolution, has evidenced the role played by volatiles in controlling the magmatic evolution within the crustal portion of the plumbing system. Volatiles, constituted of H2O, CO2, and Cl-complexes, originated from a deeply seated magma body (DBM). Their upward migration occurred through a fracture network possibly developed by the seismic swarms during the period preceding the event. In the upper portion of the plumbing system, a shallower residing magma body (ABT) had chemical and physical conditions to receive migrating volatiles, which hence dissolved the mobilized elements producing the observed selective enrichment. This volatile-induced differentiation involved exclusively the lowest erupted

  18. Correlating tephras and cryptotephras using glass compositional analyses and numerical and statistical methods: Review and evaluation

    Science.gov (United States)

    Lowe, David J.; Pearce, Nicholas J. G.; Jorgensen, Murray A.; Kuehn, Stephen C.; Tryon, Christian A.; Hayward, Chris L.

    2017-11-01

    We define tephras and cryptotephras and their components (mainly ash-sized particles of glass ± crystals in distal deposits) and summarize the basis of tephrochronology as a chronostratigraphic correlational and dating tool for palaeoenvironmental, geological, and archaeological research. We then document and appraise recent advances in analytical methods used to determine the major, minor, and trace elements of individual glass shards from tephra or cryptotephra deposits to aid their correlation and application. Protocols developed recently for the electron probe microanalysis of major elements in individual glass shards help to improve data quality and standardize reporting procedures. A narrow electron beam (diameter ∼3-5 μm) can now be used to analyze smaller glass shards than previously attainable. Reliable analyses of 'microshards' (defined here as glass shards T2 test). Randomization tests can be used where distributional assumptions such as multivariate normality underlying parametric tests are doubtful. Compositional data may be transformed and scaled before being subjected to multivariate statistical procedures including calculation of distance matrices, hierarchical cluster analysis, and PCA. Such transformations may make the assumption of multivariate normality more appropriate. A sequential procedure using Mahalanobis distance and the Hotelling two-sample T2 test is illustrated using glass major element data from trachytic to phonolitic Kenyan tephras. All these methods require a broad range of high-quality compositional data which can be used to compare 'unknowns' with reference (training) sets that are sufficiently complete to account for all possible correlatives, including tephras with heterogeneous glasses that contain multiple compositional groups. Currently, incomplete databases are tending to limit correlation efficacy. The development of an open, online global database to facilitate progress towards integrated, high

  19. Petrography and geochemistry of achnelithic tephra from Las Herrerías Volcano (Calatrava volcanic field, Spain): Formation of nephelinitic achneliths and post-depositional glass alteration

    Science.gov (United States)

    Carracedo-Sánchez, M.; Sarrionandia, F.; Arostegui, J.; Errandonea-Martin, J.; Gil-Ibarguchi, J. I.

    2016-11-01

    We present the results of a petrographic and geochemical study carried out on a layer of achnelithic tephra outcropping at the base of the volcanic cone of Las Herrerías (Miocene-Quaternary volcanic region of Campo de Calatrava, Spain). The tephra, with a composition of nephelinite and ash (Pele's tears), achnelith fragments and rare welded achneliths. The achneliths at Las Herrerías were generated in a gas-rich fire fountain that fragmented the magma into micro- to nanometre particles. The low viscosity of the nephelinitic blebs (< 1235 Pa.s) inside the hottest (ca. 900 °C), inner zone of the fountain allowed the development of the characteristic fluidal shapes of these pyroclasts and their welding above the glass transition temperature (533-669 °C). The sideromelane glass of the achneliths, also nephelinitic in composition, is variably altered to palagonite. The palagonitization was isovolumetric and took place in a near closed system at the achnelith scale. Palagonitization involved depletion in the concentration (g/cm3) of all major elements and notable increase in H2O content. The elements liberated by this process formed smectite with an average structural formula comprised between those of beidellite and nontronite end terms: (Na0.01K0.03Ca0.18) (Mg0.22Fe0.16)2 + (Fe0.48Al1.02)3 + (Ti0.18)4 + (Si3.58Al0.42) O10(OH)2. The degree of palagonitization in each achnelith was likely related to the amount of water incorporated by individual clasts at the moment of their deposition in a volcanic maar lake. Afterwards, there was no more water circulation through the achnelithic tephra, which was sealed from water by overlying hydrovolcanic tuff deposits. It was this isolation that made possible the preservation of glass to the present day.

  20. Distribution and mass of tephra-fall deposits from volcanic eruptions of Sakurajima Volcano based on posteruption surveys

    Science.gov (United States)

    Oishi, Masayuki; Nishiki, Kuniaki; Geshi, Nobuo; Furukawa, Ryuta; Ishizuka, Yoshihiro; Oikawa, Teruki; Yamamoto, Takahiro; Nanayama, Futoshi; Tanaka, Akiko; Hirota, Akinari; Miwa, Takahiro; Miyabuchi, Yasuo

    2018-04-01

    We estimate the total mass of ash fall deposits for individual eruptions of Sakurajima Volcano, southwest Japan based on distribution maps of the tephra fallout. Five ash-sampling campaigns were performed between 2011 and 2015, during which time Sakurajima continued to emit ash from frequent Vulcanian explosions. During each survey, between 29 and 53 ash samplers were installed in a zone 2.2-43 km downwind of the source crater. Total masses of erupted tephra were estimated using several empirical methods based on the relationship between the area surrounded by a given isopleth and the thickness of ash fall within each isopleth. We obtained 70-40,520 t (4.7 × 10-8-2.7 × 10-5-km3 DRE) as the minimum estimated mass of erupted materials for each eruption period. The minimum erupted mass of tephra produced during the recorded events was calculated as being 890-5140 t (5.9 × 10-7-3.6 × 10-6-km3 DRE). This calculation was based on the total mass of tephra collected during any one eruptive period and the number of eruptions during that period. These values may thus also include the contribution of continuous weak ash emissions before and after prominent eruptions. We analyzed the meteorological effects on ash fall distribution patterns and concluded that the width of distribution area of an ash fall is strongly controlled by the near-ground wind speed. The direction of the isopleth axis for larger masses is affected by the local wind direction at ground level. Furthermore, the wind direction influences the direction of the isopleth axes more at higher altitude. While a second maximum of ash fall can appear, the influence of rain might only affect the finer particles in distal areas.

  1. Changes in Mass Flux of Tephra from the Lava Lake in Overlook Crater, Kīlauea Volcano, Hawai`i

    Science.gov (United States)

    Swanson, D. A.; Orr, T. R.; Patrick, M. R.

    2016-12-01

    The mass flux of tephra (mostly Pele's hair and tears, hollow spherules, and lithic clasts) from the lava lake in Overlook crater varies on short (seconds-minutes), intermediate (hours-days), and long (months) time scales. The tephra is collected almost daily from a network of 10 buckets within 400 m of, and 100-150 m above, the lava lake; bucket locations have not changed during the eruption. A mass accumulation rate (AR) is calculated for the network; since April 2008, the AR averages 0.17 g/m2/h ( 5×10-8 kg/m2/s). The tephra forms during almost constant spattering at the SE sink (the main downwelling site) and ephemeral sites along the crater wall, as well as from sporadic, rockfall-induced violent outgassing that can eject decimeter-size spatter clots onto the crater rim; the average AR excludes these violent events. The rockfalls, and nearly constant raveling from the crater wall, introduce lithic clasts into the tephra. The lithic content of the tephra has decreased with time, reflecting both greater wall stability and higher lake level, and was usually 7 m/s). At intermediate and long time scales, juvenile AR shows no correlation with measured SO2 output and only weak or no correlation with wind speed, but it often tracks the elevation of the lake surface—higher when lava is nearer the buckets. For example, both lava level and juvenile AR were unusually high in January-July 2016. Before 2016, however, 7-9 periods of heightened juvenile production (see figure below), each lasting several months, show no correlation with other monitored parameters—lake level, SO2, wind speed and direction, or downwelling location. Often AR gradually increased to a peak before falling off, sometimes to nearly zero. We speculate that such long-term variations result from changes in magma supply rate, gas concentration, or rise frequency of decoupled gas slugs. These changes may be too small or slow to detect by current geodetic and gas monitoring. They suggest a slowly

  2. Tocuila Mammoths, Basin of Mexico: Late Pleistocene-Early Holocene stratigraphy and the geological context of the bone accumulation

    Science.gov (United States)

    Gonzalez, Silvia; Huddart, David; Israde-Alcántara, Isabel; Dominguez-Vazquez, Gabriela; Bischoff, James

    2014-07-01

    We report new stratigraphic, tephrochronology and dating results from the Tocuila Mammoth site in the Basin of Mexico. At the site there is evidence for a thin meteorite airburst layer dated between 10,878 and 10,707 cal BC at the onset of the Younger Dryas (YD) cool period. The Upper Toluca Pumice (UTP) tephra marker, caused by a Plinian eruption of the Nevado de Toluca volcano, dated from 10,666 to 10,612 cal BC, is above that layer. The eruption must have caused widespread environmental disruption in the region with evidence of extensive reworking and channelling by the Lake Texcoco shoreline and contributed to the widespread death and/or extinction of megafaunal populations, as suggested by earlier authors, but the new work reinforces the view that both catastrophic events must have caused large environmental disruption in a short time period of around two hundred years. There is no evidence for megafauna (mammoths, sabre toothed cats, camels, bison, glyptodonts) after the UTP volcanic event and subsequent lahars in the Basin of Mexico. At Tocuila, although there are some in situ tephra markers in nearshore lake sediments, such as the Great Basaltic Ash (GBA) and the UTP Ash, there is evidence of much reworking of several tephra populations in various combinations. The mammoth bone accumulation is reworked in a lahar sequence (volcanic mudflow) derived from several source sediments but associated with the major UTP Plinian eruption. Paleoindian populations were also present in the Basin of Mexico during the YD period, where several Paleoindian skeletons were found associated with the UTP ash deposits, e.g. Metro Man, Chimalhuacan Man and Tlapacoya Man.

  3. The 3.6 ka Aniakchak tephra in the Arctic Ocean: a constraint on the Holocene radiocarbon reservoir age in the Chukchi Sea

    Science.gov (United States)

    Pearce, Christof; Varhelyi, Aron; Wastegård, Stefan; Muschitiello, Francesco; Barrientos, Natalia; O'Regan, Matt; Cronin, Thomas M.; Gemery, Laura; Semiletov, Igor; Backman, Jan; Jakobsson, Martin

    2017-04-01

    The caldera-forming eruption of the Aniakchak volcano in the Aleutian Range on the Alaskan Peninsula at 3.6 cal kyr BP was one of the largest Holocene eruptions worldwide. The resulting ash is found as a visible sediment layer in several Alaskan sites and as a cryptotephra on Newfoundland and Greenland. This large geographic distribution, combined with the fact that the eruption is relatively well constrained in time using radiocarbon dating of lake sediments and annual layer counts in ice cores, makes it an excellent stratigraphic marker for dating and correlating mid-late Holocene sediment and paleoclimate records. This study presents the outcome of a targeted search for the Aniakchak tephra in a marine sediment core from the Arctic Ocean, namely Core SWERUS-L2-2-PC1 (2PC), raised from 57 m water depth in Herald Canyon, western Chukchi Sea. High concentrations of tephra shards, with a geochemical signature matching that of Aniakchak ash, were observed across a more than 1.5 m long sediment sequence. Since the primary input of volcanic ash is through atmospheric transport, and assuming that bioturbation can account for mixing up to ca. 10 cm of the marine sediment deposited at the coring site, the broad signal is interpreted as sustained reworking at the sediment source input. The isochron is therefore placed at the base of the sudden increase in tephra concentrations rather than at the maximum concentration. This interpretation of major reworking is strengthened by analysis of grain size distribution which points to ice rafting as an important secondary transport mechanism of volcanic ash. Combined with radiocarbon dates on mollusks in the same sediment core, the volcanic marker is used to calculate a marine radiocarbon reservoir age offset ΔR = 477 ± 60 years. This relatively high value may be explained by the major influence of typically carbon-old Pacific waters, and it agrees well with recent estimates of ΔR along the northwest Alaskan coast, possibly

  4. Correlation of tephra layers by trace elements abundances in glass shards

    Energy Technology Data Exchange (ETDEWEB)

    Fukuoka, Takaaki

    1988-10-01

    For identifying volcanic ash layer, a method was explained by analyzing minor elements contained in glassy material of volcanic ash. Based upon the understanding that glassy material in volcanic ash was formed by the quenching of magma and that composition of it reflected the composition of magma at the time of deposition, identification of volcanic ash layer was conducted by applying such consideration that minor elements were concentrated in the magma during the deposition process and that distribution coefficient was characteristic of every minor element. For the analysis, apparatus of irradiated neutron was applied. As the result of analysis, variation of the data was approximately 5% among the ashes belong to the same volcano. distribution map of volcanic ash in Japan was prepared by using the result. By this, it was understood that the ashes obtained from the volcanos in the middle part of Japan were different from other but those from Kyushu district were mostly identical among them. For further study of volcano, necessity of such analysis of volcanic ash in the sea bottom mud was explained. 3 references, 2 figures, 1 table.

  5. Collaborative Cyber-infrastructures for the Management of the UNESCO-IGCP Research Project "Forecast of tephra fallout"

    Science.gov (United States)

    Folch, A.; Costa, A.; Cordoba, G.

    2009-04-01

    Tephra fallout following explosive volcanic eruptions produces several hazardous effects on inhabitants, infrastructure, and property and represents a serious threat for communities located around active volcanoes. In order to mitigate the effects on the surrounding areas, scientists and civil decision-making authorities need reliable short-term forecasts during episodes of eruptive crisis and long-term probabilistic maps to plan territorial policies and land use. Modelling, together with field studies and volcano monitoring, constitutes an indispensable tool to achieve these objectives. The UNESCO-IGCP research project proposal "Forecast of tephra fallout" has the aim to produce a series of tools capable to elaborate both short-term forecasts and long-term hazard assessments using the cutting-edge models for tephra transport and sedimentation. A special project website will be designed to supply a set of models, procedures and expertise to several Latino-American Institutes based in countries seriously threatened by this geo-hazard (Argentina, Chile, Colombia, Ecuador, Mexico, and Nicaragua). This will proportionate to the final users a tool to elaborate short-term forecasts of tephra deposition on the ground, and determine airborne ash concentrations (a quantity of special relevance for aerial navigation safety) during eruptions and emergencies. The project web-site will have a public section and a password-protected area to exchange information and data among participants and, eventually, to allow remote execution of high-resolution mesoscale meteorological forecasts at the BSC facilities. The public website section will be updated periodically and will include sections describing the project objectives and achievements as well as the hazard maps for the investigated volcanoes, and will be linked to other relevant websites such as IAVCEI, IGCP, IUGS and UNESCO homepages. A part of the public section of the website will be devoted to disseminate achieved

  6. Automatized near-real-time short-term Probabilistic Volcanic Hazard Assessment of tephra dispersion before eruptions: BET_VHst for Vesuvius and Campi Flegrei during recent exercises

    Science.gov (United States)

    Selva, Jacopo; Costa, Antonio; Sandri, Laura; Rouwet, Dmtri; Tonini, Roberto; Macedonio, Giovanni; Marzocchi, Warner

    2015-04-01

    Probabilistic Volcanic Hazard Assessment (PVHA) represents the most complete scientific contribution for planning rational strategies aimed at mitigating the risk posed by volcanic activity at different time scales. The definition of the space-time window for PVHA is related to the kind of risk mitigation actions that are under consideration. Short temporal intervals (days to weeks) are important for short-term risk mitigation actions like the evacuation of a volcanic area. During volcanic unrest episodes or eruptions, it is of primary importance to produce short-term tephra fallout forecast, and frequently update it to account for the rapidly evolving situation. This information is obviously crucial for crisis management, since tephra may heavily affect building stability, public health, transportations and evacuation routes (airports, trains, road traffic) and lifelines (electric power supply). In this study, we propose a methodology named BET_VHst (Selva et al. 2014) for short-term PVHA of volcanic tephra dispersal based on automatic interpretation of measures from the monitoring system and physical models of tephra dispersal from all possible vent positions and eruptive sizes based on frequently updated meteorological forecasts. The large uncertainty at all the steps required for the analysis, both aleatory and epistemic, is treated by means of Bayesian inference and statistical mixing of long- and short-term analyses. The BET_VHst model is here presented through its implementation during two exercises organized for volcanoes in the Neapolitan area: MESIMEX for Mt. Vesuvius, and VUELCO for Campi Flegrei. References Selva J., Costa A., Sandri L., Macedonio G., Marzocchi W. (2014) Probabilistic short-term volcanic hazard in phases of unrest: a case study for tephra fallout, J. Geophys. Res., 119, doi: 10.1002/2014JB011252

  7. Geothermal flux through palagonitized tephra, Surtsey, Iceland - The Surtsey temperature-data-relay experiment via Landsat-1

    Science.gov (United States)

    Friedman, J. D.; Preble, D. M.; Jakobsson, S.

    1976-01-01

    The net geothermal flux through palagonitized basaltic tephra rims of the Surtur I and Surtur II craters at Surtsey, Iceland, in 1972, is estimated at 780 plus or minus 325 microcal/sq cm/s, indicating a decline since 1969 when a flux of 1500 microcal/sq cm/s was estimated. Heat flux in this range characterizes the postvolcanic environment on Surtsey in which the subaerial polagonitization of basaltic tephra is associated with mass transfer of hydrothermal vapor, either of meteoric or sea-water origin, only a few years after cessation of eruptive activity. The flux estimation is the result of the Surtsey data-relay experiment via Landsat-1 which was carried out in several phases. Temperature data were transmitted for a 38-day period in November and December 1972. A near-surface vertical gradient of 69.4 C/m was obtained, suggesting a mixed mechanism of heat transfer, partitioned between conduction and convection.

  8. The marine isotope stage 1-5 cryptotephra record of Tenaghi Philippon, Greece: Towards a detailed tephrostratigraphic framework for the Eastern Mediterranean region

    Science.gov (United States)

    Wulf, Sabine; Hardiman, Mark J.; Staff, Richard A.; Koutsodendris, Andreas; Appelt, Oona; Blockley, Simon P. E.; Lowe, J. John; Manning, Christina J.; Ottolini, Luisa; Schmitt, Axel K.; Smith, Victoria C.; Tomlinson, Emma L.; Vakhrameeva, Polina; Knipping, Maria; Kotthoff, Ulrich; Milner, Alice M.; Müller, Ulrich C.; Christanis, Kimon; Kalaitzidis, Stavros; Tzedakis, Polychronis C.; Schmiedl, Gerhard; Pross, Jörg

    2018-04-01

    The iconic climate archive of Tenaghi Philippon (TP), NE Greece, allows the study of short-term palaeoclimatic and environmental change throughout the past 1.3 Ma. To provide high-quality age control for detailed palaeoclimate reconstructions based on the TP archive, (crypto)tephra studies of a peat core 'TP-2005' have been carried out for the 0-130 ka interval. The results show that the TP basin is ideally positioned to receive tephra fall from both the Italian and Aegean Arc volcanic provinces. Two visible tephra layers, the Santorini Cape Riva/Y-2 (c. 22 ka) and the Campanian Ignimbrite (CI)/Y-5 (c. 39.8 ka) tephras, and six primary cryptotephra layers, namely the early Holocene E1 tephra from the Aeolian Islands (c. 8.3 ka), the Campanian Y-3 (c. 29 ka) and X-6 tephras (c. 109.5 ka), as well as counterpart tephras TM-18-1d (c. 40.4 ka), TM-23-11 (c. 92.4 ka) and TM-33-1a (c. 116.7 ka) from the Lago Grande di Monticchio sequence (southern Italy), were identified along with repeatedly redeposited Y-2 and CI tephra material. Bayesian modelling of the ages of seven of the primary tephra layers, 60 radiocarbon measurements and 20 palynological control points have been applied to markedly improve the chronology of the TP archive. This revised chronology constrains the age of tephra TM-18-1d to 40.90-41.66 cal ka BP (95.4% range). Several tephra layers identified in the TP record form important isochrons for correlating this archive with other terrestrial (e.g., Lago Grande di Monticchio, Sulmona Basin and Lake Ohrid) and marine (e.g., Adriatic Sea core PRAD 1-2 and Aegean Sea core LC21) palaeoclimate records in the Mediterranean region.

  9. A new ELSA time series of tephra layers and paleobotanical evidence from laminated Eifel maar sediments covering the entire last 120,000 years

    Science.gov (United States)

    Sirocko, Frank; Knapp, Hannes; Klee, Marlies; Rothacker, Leo; Kromer, Bernd

    2014-05-01

    The ELSA Project has drilled a total of 50 sediment cores (2000 m of laminated lake sediment) from Eifel maar lakes and dry maar structures during the last 15 years. These records have been dated using 7 different methods, including 370 14C dates. Ten records reveal the established palynological succession of trees during the Holocene down to the Laacher See Tephra, which is used for synchronization with seven more recently drilled laminated sediment cores, which all are 14C-dated too and analyzed for tephra, pollen and paleobotanical macroremains. The seven newly established records reveal a continuous MIS2 section with mosses, ostracods and characea oogonia. They show that the 28.000 - 40.000 BP has witnessed an open landscape dominated by grass, but with rhythmic spread of conifer trees following the Greenland interstadial/succession. Seeds of Ranunculae provide excellent material for 14C dating. Even deciduous trees are present in small amounts until 28.000 BP. The time from 48.000 to 40.000 BP is characterized by a pronounced transition from the open landscape to an early MIS3 spruce (Picea) dominated forest during Greenland Interstadial GI17-14. Modern man apparently arrived at the end of this principal vegetation change near 40,000 BP. Volcanic activity in the Eifel had a stable and pronounced recurrence from 55,000 - 30,000 BP every 4000 years, but commenced with the beginning of MIS2. This landscape evolution with a forested early MIS3 is quite different to peat and sediment records from Netherlands/ Northern Germany/Scandinavia/ Poland, but is similar to conditions in parts of Switzerland. We address the early MIS3 forest to the nearby continuously moist soils and warm conditions in the nearby Mosel valley, i.e. on those stands where wine is growing today, and which most likely had served as a local refugia even for deciduous trees during MIS4 and MIS3. The MIS5 sections of the presented ELSA records reach down at least to the beginning of MIS5d near 118

  10. The effect of wind and eruption source parameter variations on tephra fallout hazard assessment: an example from Vesuvio (Italy)

    Science.gov (United States)

    Macedonio, Giovanni; Costa, Antonio; Scollo, Simona; Neri, Augusto

    2015-04-01

    Uncertainty in the tephra fallout hazard assessment may depend on different meteorological datasets and eruptive source parameters used in the modelling. We present a statistical study to analyze this uncertainty in the case of a sub-Plinian eruption of Vesuvius of VEI = 4, column height of 18 km and total erupted mass of 5 × 1011 kg. The hazard assessment for tephra fallout is performed using the advection-diffusion model Hazmap. Firstly, we analyze statistically different meteorological datasets: i) from the daily atmospheric soundings of the stations located in Brindisi (Italy) between 1962 and 1976 and between 1996 and 2012, and in Pratica di Mare (Rome, Italy) between 1996 and 2012; ii) from numerical weather prediction models of the National Oceanic and Atmospheric Administration and of the European Centre for Medium-Range Weather Forecasts. Furthermore, we modify the total mass, the total grain-size distribution, the eruption column height, and the diffusion coefficient. Then, we quantify the impact that different datasets and model input parameters have on the probability maps. Results shows that the parameter that mostly affects the tephra fallout probability maps, keeping constant the total mass, is the particle terminal settling velocity, which is a function of the total grain-size distribution, particle density and shape. Differently, the evaluation of the hazard assessment weakly depends on the use of different meteorological datasets, column height and diffusion coefficient.

  11. TRACEing Last Glacial Period (25-80 ka b2k) tephra horizons within North Atlantic marine cores and exploring links to the Greenland ice-cores

    Science.gov (United States)

    Abbott, P. M.; Davies, S. M.; Griggs, A. J.; Bourne, A. J.; Cook, E.; Pearce, N. J. G.; Austin, W. E. N.; Chapman, M.; Hall, I. R.; Purcell, C. S.; Scourse, J. D.; Rasmussen, T. L.

    2015-12-01

    Tephrochronology is a powerful technique for the correlation and synchronisation of disparate palaeoclimatic records from different depositional environments and has considerable potential for testing climatic phasing. For example, the relative timing of atmospheric and marine changes caused by the abrupt climatic events that punctuated the last glacial period within the North Atlantic region. Here we report on efforts to establish a framework of tephra horizons within North Atlantic marine sequences that can correlate these records and if traced in the Greenland ice-cores can act as isochronous tie-lines. Investigations have been conducted on a network of marine cores from a number of sites across the North Atlantic. Tephra horizons have been identified using cryptotephra extraction techniques more commonly applied to the study of terrestrial sequences. There are two main challenges with assessing cryptotephras in the glacial North Atlantic; i) determining the transportation processes and ii) assessing the influence of secondary reworking processes and the stratigraphic integrity of the isochrons. These processes and their influence are investigated for each cryptotephra using shard size variations, major element heterogeneity and co-variance of IRD input for some cores. Numerous Icelandic cryptophras have been successfully identified in the marine records and we will discuss the integration of a number of these with an isochronous nature into a marine tephra framework and how potential correlations to the Greenland ice-core tephra framework are determined. Spatial patterns in the nature of tephra records that are emerging from the core network will be highlighted to outline some of the key areas that could be explored in the future. In addition, the synchronisation of multiple North Atlantic records to the Greenland ice-cores using the North Atlantic Ash Zone II to test the synchroneity of an abrupt cooling in the North Atlantic will be discussed.

  12. The role of tephra studies in African paleoanthropology as exemplified by the Sidi Hakoma Tuff

    Science.gov (United States)

    WoldeGabriel, Giday; Endale, Tamrat; White, Tim D.; Thouveny, Nicolas; Hart, William K.; Renne, Paul R.; Asfaw, Berhane

    2013-01-01

    Beginning in the 1960s, geological and paleoanthropological exploration of the Ethiopian rift system's basins have led to the discovery and assembly of the most comprehensive record of human biological and technological change during the last 6 million years. The hominid fossils, including partial skeletons, were primarily discovered in the Afar Rift, the Main Ethiopian Rift, and in the Omo Basin of the broadly rifted zone of SW Ethiopia. The paleoanthropological research areas within the SW Afar Rift that have yielded many diverse hominid species and the oldest stone tools are, from north to south, Woranso-Mille (aff. Ardipithecus and Au. afarensis), Hadar (Au. afarensis, Homo sp.), Dikika (Au. afarensis), Gona (Ar. kadabba, Ar. ramidus, H. erectus, and oldest stone tools), Middle Awash (Ar. kadabba, Ar. ramidus, Au. anamensis, Au. afarensis, Au. garhi, H. erectus, H. rhodesiensis, H. sapiens idaltu, and the oldest paleo-butchery locality), and Galili (Au. afarensis). Additional hominid remains were discovered at Melka Kunture on the banks of the Awash River near its source along the western margin of the central part of the Main Ethiopian Rift (H. erectus), at Konso (H. erectus and A. boisei), and at the southern end of the MER, and in the Omo Basin (Au. anamensis, Au. afarensis, Au. aethiopicus, Au. boisei, H. habilis, and H. erectus). Distal and sometimes proximal tephra units interbedded within fossilifeous sedimentary deposits have become key elements in this work by providing chronological and correlative control and depositional contexts. Several regional tephra markers have been identified within the northern half of the eastern African rift valley in Ethiopia and Kenya, and in marine sediments of the Gulf of Aden Rift and the NW Indian Ocean. Out of the many regional tephra stratigraphic markers that range in age from the early Pliocene (3.97 Ma) to the late Pleistocene (0.16 Ma), the Sidi Hakoma Tuff (SHT) has been more widely identified and thoroughly

  13. Character, mass, distribution, and origin of tephra-fall deposits from the 2009 eruption of Redoubt Volcano, Alaska: highlighting the significance of particle aggregation

    Science.gov (United States)

    Wallace, Kristi; Coombs, Michelle L; Schaefer, Janet R.

    2013-01-01

    The 2009 eruption of Redoubt Volcano included 20 tephra-producing explosions between March 15, 2009 and April 4, 2009 (UTC). Next-Generation radar (NEXRAD) data show that plumes reached heights between 4.6 km and 19 km asl and were distributed downwind along nearly all azimuths of the volcano. Explosions lasted between 0.8 mm thick), including communities along the Kenai Peninsula (80–100 km) and the city of Anchorage (170 km). Trace ash (mass of tephra-fall deposits at 54.6 × 109 kg with a total DRE volume of 20.6 × 106 m3.

  14. Historical volcanic eruptions in the Canary Islands, tephra composition, and insights into the crystal cargo of basaltic magmas

    Science.gov (United States)

    Longpre, M. A.; Muller, J.; Beaudry, P.; Andronikides, A.; Felpeto, A.

    2017-12-01

    Since the 16th century, at least 13 volcanic eruptions have occurred in the Canary Islands that formed monogenetic cinder cones and lava flow fields: 2 on Lanzarote, 4 on Tenerife, 6 on La Palma, and 1 on the submarine flank of El Hierro. Here we present a comprehensive new dataset of tephra composition for all 13 eruptions, comprising major and trace element data for bulk rocks and matrix glasses, as well as vesicularity and crystallinity measurements. In addition, we compile available volcanological and petrological information for specific eruptions, including estimates of lava flow area and volume. All lapilli samples show a vesicularity of 40-50 vol% and a vesicle-free crystallinity (crystals ≥ 250 µm) of 5-15 vol%. Modal mineralogy varies significantly between samples, typically consisting of olivine ± clinopyroxene ± Fe-Ti oxide ± plagioclase ± amphibole in different proportions. All but 2 tephras have basanite-tephrite bulk rock compositions. Lapilli from vents of the AD 1730-1736 Timanfaya eruption, Lanzarote, largely are basaltic, whereas the AD 1798 Chahorra eruption, Tenerife, produced phonotephrite tephra. These results are in agreement with published bulk lava flow data. Unsurprisingly, glass compositions are more evolved than bulk rocks and MgOglass is weakly positively correlated to MgObulk (MgOglass = 0.30*MgObulk + 2.11, R2 = 0.54). Both bulk rocks and glasses show strikingly similar multi-element diagram patterns, with strong enrichment relative to the bulk-silicate Earth and marked positive Nb and Ta and negative Pb anomalies — typical for ocean island basalts. Glass/bulk rock elemental ratios reveal systematic differences between samples that relate to their mineralogy; for example, Lanzarote tephras that lack significant clinopyroxene and Fe-Ti oxide crystals have higher Scglass/Scbulk and Vglass/Vbulk than Tenerife, La Palma and El Hierro samples that typically contain these minerals. Among all elements, K and P display the greatest

  15. ATMOSPHERIC DISPERSAL AND DEPOSITION OF TEPHRA FROM A POTENTIAL VOLCANIC ERUPTION AT YUCCA MOUNTAIN, NEVADA

    International Nuclear Information System (INIS)

    C. Harrington

    2004-01-01

    The purpose of this model report is to provide documentation of the conceptual and mathematical model (Ashplume) for atmospheric dispersal and subsequent deposition of ash on the land surface from a potential volcanic eruption at Yucca Mountain, Nevada. This report also documents the ash (tephra) redistribution conceptual model. These aspects of volcanism-related dose calculation are described in the context of the entire igneous disruptive events conceptual model in ''Characterize Framework for Igneous Activity'' (BSC 2004 [DIRS 169989], Section 6.1.1). The Ashplume conceptual model accounts for incorporation and entrainment of waste fuel particles associated with a hypothetical volcanic eruption through the Yucca Mountain repository and downwind transport of contaminated tephra. The Ashplume mathematical model describes the conceptual model in mathematical terms to allow for prediction of radioactive waste/ash deposition on the ground surface given that the hypothetical eruptive event occurs. This model report also describes the conceptual model for tephra redistribution from a basaltic cinder cone. Sensitivity analyses and model validation activities for the ash dispersal and redistribution models are also presented. Analyses documented in this model report update the previous documentation of the Ashplume mathematical model and its application to the Total System Performance Assessment (TSPA) for the License Application (TSPA-LA) igneous scenarios. This model report also documents the redistribution model product outputs based on analyses to support the conceptual model. In this report, ''Ashplume'' is used when referring to the atmospheric dispersal model and ''ASHPLUME'' is used when referencing the code of that model. Two analysis and model reports provide direct inputs to this model report, namely ''Characterize Eruptive Processes at Yucca Mountain, Nevada and Number of Waste Packages Hit by Igneous Intrusion''. This model report provides direct inputs to

  16. Tephra Sedimentation from a Short-term Wind-affected Volcanic Plume of the 8 October 2016 Aso Nakadake Eruption, Japan

    Science.gov (United States)

    Tsuji, T.; Nishizaka, N.; Onishi, K.

    2017-12-01

    Sedimentation processes during explosive volcanic eruptions can be constrained based on detailed analysis of grain-size variation of tephra deposits. Especially, an accurate description of the amount of fine particles has also significant implications for the assessment of specific tephra hazards. Grain size studies for single short-term eruption has advantage to contribute understanding the sedimentation processes because it is simple compared to long-lasting eruption. The 2016 Aso Nakadake eruption, Japan represents an ideal for the study of short-term eruptions thanks to an accurate investigation. Then, we investigate the grain size variation with distance from the vent and sedimentological features of the deposit to discuss the sedimentation processes of the tephra fragments. The eruption provided pyroclastic flow deposit and fallout tephra which distributed NE to ENE direction from the vent. The deposits between 4 and 20 km from vent consist of fine-coated lapilli to coarse ash, ash pellet and mud droplet in ascending degree. The samples are lapilli-bearing within 20 km from vent and those outside of 20 km mainly consist of ash particles. Detailed analyses of individual samples highlight a rapid decay of maximum and mean grain size for the deposit from proximal to distal. The decay trend of maximum grain-size is approximated by three segments of exponential curves with two breaks-in-slope at 10 and 40 km from vent. Most of the sampled deposits are characterized by bimodal grain-size distributions, with the modes of the coarse subpopulation decreasing with distance from vent and those of the fine subpopulation being mostly stable. The fine subpopulation has been interpreted as being mostly associated with size-selective sedimentation processes (e.g., particle aggregation) confirmed by the existence of fine-coated particles, ash pellet and mud droplet. As the fine-coated particles generally have a higher terminal velocity than the individual constituent

  17. Surface Ocean Radiocarbon Reservoir Ages From Land-Sea Tephra Correlation Constrains Deglacial Chronology and Ocean Circulation in the Southeast Bering Sea

    Science.gov (United States)

    Cook, M. S.; Miller, R.; White-Nockleby, C.; Chapman, A.; Mix, A. C.

    2017-12-01

    Radiocarbon estimates of the past ocean are valuable because unlike passive tracers, radiocarbon has the potential to trace both the distribution and rate of transport of water masses. Most studies using paired radiocarbon measurements on planktonic and benthic foraminifera assume that the surface reservoir age was constant at the preindustrial value, which if incorrect, can strongly bias radiocarbon reconstructions. The subarctic Pacific is ringed by volcanic arcs, and there is great potential to use tephrochronology as a stratigraphic tool in sediments from the last glacial and deglaciation, and assign calendar ages to the marine sediment without relying on calibrated planktonic radiocarbon ages. In this study, we use major and trace element analysis of volcanic glass to match tephras between radiocarbon-dated lake cores from Sanak Island in the eastern Aleutians to marine cores from Umnak Plateau in the southeast Bering Sea. There are numerous thin tephras preserved in laminated sediments from the Bolling-Allerod and early Holocene in marine cores from depths (1000-1500 m) within the modern oxygen minimum zone. We find that trace elements are crucial in distinguishing tephras from individual eruptions. Our preliminary radiocarbon measurements suggest that the benthic-atmosphere radiocarbon differences and marine surface reservoir ages in the Bolling-Allerod are similar to pre-industrial values, supporting previously published radiocarbon reconstructions from the region.

  18. Trace Element Geochemistry of Basaltic Tephra in Maar Cores; Implications for Centre Correlation, Field Evolution, and Mantle Source Characteristics of the Auckland Volcanic Field, New Zealand

    Science.gov (United States)

    Hopkins, J. L.; Leonard, G.; Timm, C.; Wilson, C. J. N.; Neil, H.; Millet, M. A.

    2014-12-01

    Establishing volcanic hazard and risk management strategies hinges on a detailed understanding of the type, timing and tephra dispersal of past eruptions. In order to unravel the pyroclastic eruption history of a volcanic field, genetic links between the deposits and eruption source centre need to be established. The Auckland Volcanic Field (AVF; New Zealand) has been active for ca. 200 kyr and comprises ca. 53 individual centres covering an area of ca. 360km2. These centres show a range of sizes and eruptive styles from maar craters and tuff rings, to scoria cones and lava flows consistent with both phreatomagmatic and magmatic eruptions. Superimposition of the metropolitan area of Auckland (ca. 1.4 million inhabitants) on the volcanic field makes it critically important to assess the characteristics of the volcanic activity, on which to base assessment and management of the consequent hazards. Here we present a geochemical approach for correlating tephra deposits to their source centres. To acquire the most complete stratigraphic record of pyroclastic events, maar crater cores from different locations, covering various depths and thus ages across the field were selected. Magnetic susceptibility and x-ray density scanning of the cores was used to identify the basaltic tephra horizons, which were sampled and in-situ analysis of individual shards undertaken for major and trace elements using EPMA and LA-ICP-MS techniques, respectively. Our results show that tephra shard trace element ratios are comparable and complementary to the AVF whole rock database. The use of specific trace element ratios (e.g. Gd/Yb vs. Zr/Yb) allows us to fingerprint and cross correlate tephra horizons between cores and, when coupled with newly acquired 40Ar-39Ar age dating and eruption size estimates, correlate horizons to their source centres. This integrated style of study can provide valuable information to help volcanic hazard management and forecasting, and mitigation of related risks.

  19. Operational short-term Probabilistic Volcanic Hazard Assessment of tephra fallout: an example from the 1982-1984 unrest at Campi Flegrei

    Science.gov (United States)

    Sandri, Laura; Selva, Jacopo; Costa, Antonio; Macedonio, Giovanni; Marzocchi, Warner

    2014-05-01

    Probabilistic Volcanic Hazard Assessment (PVHA) represents the most complete scientific contribution for planning rational strategies aimed at mitigating the risk posed by volcanic activity at different time scales. The definition of the space-time window for PVHA is related to the kind of risk mitigation actions that are under consideration. Short intervals (days to weeks) are important for short-term risk mitigation actions like the evacuation of a volcanic area. During volcanic unrest episodes or eruptions, it is of primary importance to produce short-term tephra fallout forecast, and frequently update it to account for the rapidly evolving situation. This information is obviously crucial for crisis management, since tephra may heavily affect building stability, public health, transportations and evacuation routes (airports, trains, road traffic) and lifelines (electric power supply). In this study, we propose a methodology for the short-term PVHA and its operational implementation, based on the model BET_EF, in which measures from the monitoring system are used to routinely update the forecast of some parameters related to the eruption dynamics, that is, the probabilities of eruption, of every possible vent position and every possible eruption size. Then, considering all possible vent positions and eruptive sizes, tephra dispersal models are coupled with frequently updated meteorological forecasts. Finally, these results are merged through a Bayesian procedure, accounting for epistemic uncertainties at all the considered steps. As case study we retrospectively study some stages of the volcanic unrest that took place in Campi Flegrei (CF) in 1982-1984. In particular, we aim at presenting a practical example of possible operational tephra fall PVHA on a daily basis, in the surroundings of CF at different stages of the 1982-84 unrest. Tephra dispersal is simulated using the analytical HAZMAP code. We consider three possible eruptive sizes (a low, a medium and a

  20. Leaching of lava and tephra from the Oldoinyo Lengai volcano (Tanzania): Remobilization of fluorine and other potentially toxic elements into surface waters of the Gregory Rift

    Science.gov (United States)

    Bosshard-Stadlin, Sonja A.; Mattsson, Hannes B.; Stewart, Carol; Reusser, Eric

    2017-02-01

    Volcanic ash leachate studies have been conducted on various volcanoes on Earth, but few have been done on African volcanoes until now. Tephra emissions may affect the environment and the health of people living in this area, and therefore we conducted a first tephra (ash and lapilli sized) leachate study on the Oldoinyo Lengai volcano, situated in northern Tanzania. The recent explosive eruption in 2007-2008 provided us with fresh samples from the first three weeks of the eruption which were used for this study. In addition, we also used a natrocarbonatitic sample from the activity prior to the explosive eruption, as the major activity at Oldoinyo Lengai is natrocarbonatitic. To compare the leaching process affecting the natrocarbonatitic lavas and the tephras from Oldoinyo Lengai, the 2006 natrocarbonatitic lava flow was resampled 5 years after the emplacement and compared to the initial, unaltered composition. Special interest was given to the element fluorine (F), since it is potentially toxic to both humans and animals. A daily intake of fluoride (F-) in drinking water of > 1.5 mg/l can lead to dental fluorosis, and higher concentrations lead to skeletal fluorosis. For this reason, a guideline value for fluoride in drinking water was set by the WHO (2011) to 1.5 mg/l. However, surface waters and groundwaters in the Gregory Rift have elevated fluoride levels of up to 9.12 mg/l, and as a consequence, an interim guideline value for Tanzania has been set at 8 mg/l. The total concentration of fluorine in the samples from the natrocarbonatitic lava flow is high (3.2 wt%), whereas we observed a significant decrease of the fluorine concentration (between 1.7 and 0.5 wt%) in the samples collected three days and three weeks after the onset of the explosive 2007-08 eruption. However, the total amount of water-extractable fluoride is lower in the natrocarbonatitic lavas (319 mg/l) than in the nephelinitic tephra (573-895 mg/l). This is due to the solubility of the

  1. ATMOSPHERIC DISPERSAL AND DEPOSITION OF TEPHRA FROM A POTENTIAL VOLCANIC ERUPTION AT YUCCA MOUNTAIN, NEVADA

    Energy Technology Data Exchange (ETDEWEB)

    C. Harrington

    2004-10-25

    The purpose of this model report is to provide documentation of the conceptual and mathematical model (Ashplume) for atmospheric dispersal and subsequent deposition of ash on the land surface from a potential volcanic eruption at Yucca Mountain, Nevada. This report also documents the ash (tephra) redistribution conceptual model. These aspects of volcanism-related dose calculation are described in the context of the entire igneous disruptive events conceptual model in ''Characterize Framework for Igneous Activity'' (BSC 2004 [DIRS 169989], Section 6.1.1). The Ashplume conceptual model accounts for incorporation and entrainment of waste fuel particles associated with a hypothetical volcanic eruption through the Yucca Mountain repository and downwind transport of contaminated tephra. The Ashplume mathematical model describes the conceptual model in mathematical terms to allow for prediction of radioactive waste/ash deposition on the ground surface given that the hypothetical eruptive event occurs. This model report also describes the conceptual model for tephra redistribution from a basaltic cinder cone. Sensitivity analyses and model validation activities for the ash dispersal and redistribution models are also presented. Analyses documented in this model report update the previous documentation of the Ashplume mathematical model and its application to the Total System Performance Assessment (TSPA) for the License Application (TSPA-LA) igneous scenarios. This model report also documents the redistribution model product outputs based on analyses to support the conceptual model. In this report, ''Ashplume'' is used when referring to the atmospheric dispersal model and ''ASHPLUME'' is used when referencing the code of that model. Two analysis and model reports provide direct inputs to this model report, namely ''Characterize Eruptive Processes at Yucca Mountain, Nevada and Number of Waste Packages Hit

  2. Hazard assessment of long-range tephra dispersal for a Plinian eruptive scenario at Popocatépetl volcano (Mexico). Inplications on civil aviation

    Science.gov (United States)

    Bonasia, R.; Scaini, C.; Capra, L.; Nathenson, M.; Siebe, C.; Arana-Salinas, L.; Folch, A.

    2013-12-01

    Popocatépetl is one of the most active volcanoes in Mexico threatening a densely populated area that includes Mexico City with more than 20 million inhabitants. The destructive potential of this volcano is demonstrated by its Late Pleistocene-Holocene eruptive activity, which has been characterized by recurrent Plinian eruptions of large magnitude. The current volcanic hazards map, reconstructed after the crisis occurred in 1994, considers the potential occurrence of different volcanic phenomena, including pyroclastic density currents and lahars. However, no quantitative assessment of the tephra dispersal hazard, especially related to atmospheric dispersal, has been performed. Given the high number of important airports in the surroundings of Popocatépetl volcano and considering the potential threat posed to civil aviation in Mexico and adjacent regions in case of a Plinian eruption, a hazard assessment for tephra dispersal is strongly required. In this work we present the first probabilistic tephra dispersal hazard assessment for Popocatépetl volcano. We compute probabilistic hazard maps for critical thresholds of airborne ash concentrations at different flight levels. Tephra dispersal modelling is performed using the FALL3D numerical model. Probabilistic hazard maps are built for a Plinian eruptive scenario defined on the basis of geological field data for the 'Ochre Pumice' Plinian eruption (4965 14C yrBP). FALL3D model input eruptive parameters are constrained through an inversion method carried out with the semi-analytical HAZMAP model and are varied sampling them on the base of a Probability Density Function. We analyze the influence of seasonal variations on ash dispersal and estimate the average persistence of critical ash concentrations at relevant locations and airports. This study assesses the impact that a Plinian eruption similar to the Ochre Pumice eruption would have on the main airports of Mexico and adjacent areas. The hazard maps presented here

  3. Reply to Comment on "Zircon U-Th-Pb dating using LA-ICP-MS: Simultaneous U-Pb and U-Th dating on the 0.1 Ma Toya Tephra, Japan"

    Science.gov (United States)

    Ito, Hisatoshi

    2015-04-01

    Guillong et al. (2015) mentioned that corrections for abundance sensitivity for 232Th and molecular zirconium sesquioxide ions (Zr2O3+) are critical for reliable determination of 230Th abundances in zircon for LA-ICP-MS analyses. There is no denying that more rigorous treatments are necessary to obtain more reliable ages than those in Ito (2014). However, as shown in Fig. 2 in Guillong et al. (2015), the uncorrected (230Th)/(238U) for reference zircons except for Mud Tank are only 5-20% higher than unity. Since U abundance of Toya Tephra zircons that have U-Pb ages Ito (2014) obtained U-Th ages of the Toya Tephra by comparison with Fish Canyon Tuff (FCT) data. Because both the FCT and the Toya Tephra have similar trends of overestimation of 230Th, the effect of overestimation of 230Th to cause overestimation of U-Th age should be cancelled out or negligible. Therefore the pivotal conclusion in Ito (2014) that simultaneous U-Pb and U-Th dating using LA-ICP-MS is possible and useful for Quaternary zircons holds true.

  4. Spores of coprophilous fungi from under the Dawson tephra (25,300 14C years BP), Yukon Territory, northwestern Canada

    NARCIS (Netherlands)

    van Geel, B.; Zazula, G.D.; Schweger, C.E.

    2007-01-01

    Based on the analysis of pollen and macrofossils Zazula et al. [Zazula, G.D., Froesne, D.G., Elias, S.A., Kuzmina, S., la Farge, C., Reyes, A.V., Sanborn, P.T., Schweger, C.E., Smith, C.A.S., Mathewes, R.W., 2006. Vegetation buried under Dawson tephra (25,300 14C yr BP) and locally diverse late

  5. Sub-Transport Layer Coding

    DEFF Research Database (Denmark)

    Hansen, Jonas; Krigslund, Jeppe; Roetter, Daniel Enrique Lucani

    2014-01-01

    Packet losses in wireless networks dramatically curbs the performance of TCP. This paper introduces a simple coding shim that aids IP-layer traffic in lossy environments while being transparent to transport layer protocols. The proposed coding approach enables erasure correction while being...... oblivious to the congestion control algorithms of the utilised transport layer protocol. Although our coding shim is indifferent towards the transport layer protocol, we focus on the performance of TCP when ran on top of our proposed coding mechanism due to its widespread use. The coding shim provides gains...

  6. Stratigraphy and depositional environments of the upper Pleistocene Chemehuevi Formation along the lower Colorado River

    Science.gov (United States)

    Malmon, Daniel V.; Howard, Keith A.; House, P. Kyle; Lundstrom, Scott C.; Pearthree, Philip A.; Sarna-Wojcicki, Andrei M.; Wan, Elmira; Wahl, David B.

    2011-01-01

    about 111±2 and 57±2 ka and was most active in the later part of this time interval, during Marine Oxygen Isotope (MOI) stage 4 (between 74 and 59 ka ago). Chemically similar tephra in cores from Owens Lake and Walker Lake are approximately 70 and 74 ky old, based on age models of those cores. Other lines of stratigraphic evidence from nine tephra-containing sections in the Basin and Range are also consistent with an age assignment for the Monkey Rock tephra of ~72 ky, near the beginning of MOI stage 4. We propose to designate the Chemehuevi Formation as a formal lithostratigraphic unit, and propose as the type section a well exposed outcrop near the ranger station at Katherine Landing, Arizona, in the Lake Mead National Recreation Area. This exposure shows the two dominant facies, an example of one of the four known tephra layers, and interbedded lenses of locally derived gravel. In the type section, as in many of the other examples of the formation, the sand facies overlies the mud facies on a conspicuous, abrupt erosional surface; however, nearby is a contiguous section demonstrating that the mud and sand facies interfinger. In addition to the type section, measured reference sections compiled here illustrate other important lithologic and stratigraphic features of the formation. Our preferred interpretation of the Chemehuevi Formation is that it contains the remnants of deposits formed during a single major episode of fluvial aggradation, during which the Colorado River filled its valley with a great volume of dominantly sand-size sediment. This would reflect an increase in the supply of sand-size sediment, and(or) a reduction in transport capacity below the mouth of Grand Canyon. The most likely cause for the aggradation is an extraordinary increase in sand supply, likely due to widespread climatic change. However, other explanations have not been ruled out. Other aggradation events predated the Chemehuevi Formation, and some smaller events may have postdated the

  7. A micromorphological study of pedogenic processes in an evolutionary soil sequence formed in late quaternary rhyolitic tephra deposits, North Island, New Zealand.

    NARCIS (Netherlands)

    Bakker, L.; Lowe, D.J.; Jongmans, A.G.

    1996-01-01

    The influence of time as a soil forming factor was studied on an evolutionary sequence of five soils (1850 radiocarbo years BP-ca. 120,000 BP) developed in rhyolitic tephra deposits in New Zealand. New micromorphological observations were combined with existing macromorphological, chemical,

  8. Compositional Variations of Paleogene and Neogene Tephra From the Northern Izu-Bonin-Mariana Arc

    Science.gov (United States)

    Tepley, F. J., III; Barth, A. P.; Brandl, P. A.; Hickey-Vargas, R.; Jiang, F.; Kanayama, K.; Kusano, Y.; Li, H.; Marsaglia, K. M.; McCarthy, A.; Meffre, S.; Savov, I. P.; Yogodzinski, G. M.

    2014-12-01

    A primary objective of IODP Expedition 351 was to evaluate arc initiation processes of the Izu-Bonin-Mariana (IBM) volcanic arc and its compositional evolution through time. To this end, a single thick section of sediment overlying oceanic crust was cored in the Amami Sankaku Basin where a complete sediment record of arc inception and evolution is preserved. This sediment record includes ash and pyroclasts, deposited in fore-arc, arc, and back-arc settings, likely associated with both the ~49-25 Ma emergent IBM volcanic arc and the evolving Ryukyu-Kyushu volcanic arc. Our goal was to assess the major element evolution of the nascent and evolving IBM system using the temporally constrained record of the early and developing system. In all, more than 100 ash and tuff layers, and pyroclastic fragments were selected from temporally resolved portions of the core, and from representative fractions of the overall core ("core catcher"). The samples were prepared to determine major and minor element compositions via electron microprobe analyses. This ash and pyroclast record will allow us to 1) resolve the Paleogene evolutionary history of the northern IBM arc in greater detail; 2) determine compositional variations of this portion of the IBM arc through time; 3) compare the acquired data to an extensive whole rock and tephra dataset from other segments of the IBM arc; 4) test hypotheses of northern IBM arc evolution and the involvement of different source reservoirs; and 5) mark important stratigraphic markers associated with the Neogene volcanic history of the adjacent evolving Ryukyu-Kyushu arc.

  9. Adjusting particle-size distributions to account for aggregation in tephra-deposit model forecasts

    Science.gov (United States)

    Mastin, Larry G.; Van Eaton, Alexa; Durant, A.J.

    2016-01-01

    Volcanic ash transport and dispersion (VATD) models are used to forecast tephra deposition during volcanic eruptions. Model accuracy is limited by the fact that fine-ash aggregates (clumps into clusters), thus altering patterns of deposition. In most models this is accounted for by ad hoc changes to model input, representing fine ash as aggregates with density ρagg, and a log-normal size distribution with median μagg and standard deviation σagg. Optimal values may vary between eruptions. To test the variance, we used the Ash3d tephra model to simulate four deposits: 18 May 1980 Mount St. Helens; 16–17 September 1992 Crater Peak (Mount Spurr); 17 June 1996 Ruapehu; and 23 March 2009 Mount Redoubt. In 192 simulations, we systematically varied μagg and σagg, holding ρagg constant at 600 kg m−3. We evaluated the fit using three indices that compare modeled versus measured (1) mass load at sample locations; (2) mass load versus distance along the dispersal axis; and (3) isomass area. For all deposits, under these inputs, the best-fit value of μagg ranged narrowly between  ∼  2.3 and 2.7φ (0.20–0.15 mm), despite large variations in erupted mass (0.25–50 Tg), plume height (8.5–25 km), mass fraction of fine ( discrete process that is insensitive to eruptive style or magnitude. This result offers the potential for a simple, computationally efficient parameterization scheme for use in operational model forecasts. Further research may indicate whether this narrow range also reflects physical constraints on processes in the evolving cloud.

  10. The 3.6 ka Aniakchak tephra in the Arctic Ocean: a constraint on the Holocene radiocarbon reservoir age in the Chukchi Sea

    DEFF Research Database (Denmark)

    Pearce, C.; Varhelyi, A.; Wastegård, S.

    2016-01-01

    is interpreted as sustained reworking at the sediment source input. The isochron is therefore placed at the base of the sudden increase in tephra concentrations rather than at the maximum concentration. This interpretation of major reworking is strengthened by analysis of grain size distribution which points...

  11. Holocene tephra-fall deposits of southern and austral Andes volcanic zones (33-54oS): eruption recurrence

    International Nuclear Information System (INIS)

    Naranjo, J.A.; Polanco, E.; Lara, L; Moreno, H; Stern, C.R

    2001-01-01

    Radiometric 14 C dating is a very useful tool to study the chronostratigraphy of pyroclastic deposits. In addition, 14 C ages are essential parameters for the estimation of the recurrence time of the explosive volcanic activity. The origin, distribution and relative age of mappable Holocene tephra-fall deposits of the Southern Andes Volcanic Zone (SVZ) and Austral Andes Volcanic Zone (AVZ) from 33 o S-54 o S, were studied and their recurrence period is analysed (au)

  12. Tephrostratigraphy of the late Quaternary record from Lake Chalco, central México

    Science.gov (United States)

    Ortega-Guerrero, Beatriz; Caballero García, Lizeth; Linares-López, Carlos

    2018-01-01

    Lacustrine sequences in active volcanic settings preserve the record of fall-out products (tephras) from explosive volcanic activity from both proximal and distal sources. Sediments of Lake Chalco, located in the western part of the Trans Mexican Volcanic Belt, offer the opportunity to develop a detailed tephrostratigraphy of proximal and distal sources, and to provide stratigraphic marker horizons for the correlation of paleoclimate records. Here, we present major oxide glass and pumice data from 18 tephra layers interbedded in the lacustrine sediments of Chalco, from 11.5 to 31.3 cal ka BP. Tephra glass compositions range from basaltic trachyandesitic to rhyolitic. Two tephras were successfully correlated with the Tutti Frutti Plinian Eruption of Popocatépetl volcano; and two tephra layers from the Nevado de Toluca Plinian activity: the Upper Toluca Pumice and the Lower Toluca Pumice. Although the source of most of the tephras analyzed is unknown, their geochemical characterization, coupled with a robust chronology, contributes to establish a detailed tephrostratigraphy for the region. This tephra record also contributes to improving the estimated frequency of explosive volcanic activity for future hazards in the Basin of México and surrounding areas, where more than 29 million people live. Our findings estimate a recurrence interval of volcanic activity of ca. 1100 years in the interval between ca. 32 and 11.5 cal ka BP, shorter than previously estimated.

  13. Widespread hematogenous metastases and Trousseau's syndrome in gastric adenocarcinoma

    Directory of Open Access Journals (Sweden)

    Santos Vitorino Modesto dos

    2001-01-01

    Full Text Available A case of widespread hematogenous metastases and Trousseau's syndrome is reported in a 40 year-old white housewife with gastric cancer, presenting subdural hematoma, ecchymoses, epistaxis, stomach and uterine bleeding. After undergoing hematoma drainage, she was unsuccessfully treated with platelets, red blood cells, plasma cryoprecipitate transfusions, and antibiotics. Necropsy disclosed gastric ring-signet adenocarcinoma invading the serous layer, with massive disseminated intravascular coagulation and systemic neoplastic embolism. Multiple old and recent hyaline (rich in fibrin and platelets microthrombi, and tumor emboli were observed in the bone marrow, meninges, liver, lungs, kidneys, lymph nodes, adrenals, thyroid, heart, pancreas, and ovaries (Krukenberg tumor.

  14. Constructing a reference tephrochronology for Augustine Volcano, Alaska

    Science.gov (United States)

    Wallace, Kristi; Coombs, Michelle L.

    2013-01-01

    Augustine Volcano is the most historically active volcano in Alaska's populous Cook Inlet region. Past on-island work on pre-historic tephra deposits mainly focused on using tephra layers as markers to help distinguish among prevalent debris-avalanche deposits on the island (Waitt and Beget, 2009, USGS Prof Paper 1762), or as source material for petrogenetic studies. No comprehensive reference study of tephra fall from Augustine Volcano previously existed. Numerous workers have identified Holocene-age tephra layers in the region surrounding Augustine Island, but without well-characterized reference deposits, correlation back to the source volcano is difficult. The purpose of this detailed tephra study is to provide a record of eruption frequency and magnitude, as well as to elucidate physical and chemical characteristics for use as reference standards for comparison with regionally distributed Augustine tephra layers. Whole rock major- and trace-element geochemistry, deposit componentry, and field context are used to correlate tephra units on the island where deposits are coarse grained. Major-element glass geochemistry was collected for use in correlating to unknown regional tephra. Due to the small size of the volcanic island (9 by 11 km in diameter) and frequent eruptive activity, on-island exposures of tephra deposits older than a couple thousand years are sparse, and the lettered Tephras B, M, C, H, I, and G of Waitt and Beget (2009) range in age from 370-2200 yrs B.P. There are, however, a few exposures on the south side of the volcano, within about 2 km of the vent, where stratigraphic sections that extend back to the late Pleistocene glaciation include coarse pumice-fall deposits. We have linked the letter-named tephras from the coast to these higher exposures on the south side using physical and chemical characteristics of the deposits. In addition, these exposures preserve at least 5 older major post-glacial eruptions of Augustine. These ultra

  15. Sedimentation rates of lake Haruna in the past 200 years as revealed by tephrochronology, 210Pb and 137Cs methods

    International Nuclear Information System (INIS)

    Ishiwatari, Ryoshi; Uchida, Kuniko; Nagasaka, Hiromitsu; Tsukamoto, Sumiko

    2010-01-01

    A 90 cm sediment core (HAR 99A) from Lake Haruna, Gumma Prefecture, Japan was dated by tephrochronology, lead-210 and cesium-137 methods and was compared stratigraphically with the cores obtained in 1966 (HAR 96B) and 1971 (HAR 71). For the HAR 99A core, the 24-26 cm depth layer was estimated to be AD 1963 by 137 Cs. The tephra layer in 62-66 cm depth was identified to be volcanic ashes from Asama volcano eruption (Asama-A tephra: As-A) in AD 1783. Average mass sedimentation rate (AMSR) for 1963 to 1999 (0-26 cm depth) is 0.050 g cm -2 yr -1 and that for 1783 to 1963 (25-62 cm depth) is 0.033 g cm -2 yr -1 . AMSR for the 0-62 cm depth obtained by 210 Pb ranges between 0.052 and 0.058 g cm -2 yr -1 . In addition, it is proposed that the previous assignment of As-B (AD 1108) for a tephra layer at 40-50 cm depth of the HAR 71 core should be changed to As-A tephra (AD 1783). (author)

  16. High-resolution magnetostratigraphic and biostratigraphic study of Ethiopian traps-related products in Oligocene sediments from the Indian Ocean

    Science.gov (United States)

    Touchard, Yannick; Rochette, Pierre; Aubry, Marie Pierre; Michard, Annie

    2003-02-01

    Volcanic traps correspond typically to aerial emissions of more than 10 6 km 3 of magma over 1 Myr periods. The potential global impact of such emissions makes the precise correlation of traps with the global magnetobiochronologic timescale an important task. Our study is focused on the Ethiopian traps which correspond to the birth of the Afar hotspot at the triple junction between the Red Sea, Aden Gulf and East-African rift. The Ethiopian traps have a significant acidic component (about 10% of the traps by volume) which enables more efficient stratospheric aerosol diffusion than for the main basaltic eruptions. Furthermore, a magnetostratigraphy is well established for the traps: traps activity began in Chron C11r.2r and ended in Chron C11r.1r or C10r, with well clustered 40Ar/ 39Ar ages at 30±0.5 Ma. Four tephra layers, marked by prominent magnetic susceptibility peaks, occur in Oligocene sections of sites from Ocean Drilling Program Leg 115, drilled in the southern Indian Ocean near Madingley Rise, 2600 km away from the Ethiopian traps. In order to demonstrate that these tephra layers are related to the Ethiopian traps, a high-resolution study of sites 709 and 711 was undertaken, involving magnetostratigraphy and nannofossil stratigraphy, together with isotopic and geochemical characterization of the tephra. Geochemical analyses and isotope ratios of the glass shards indicate the same acid continental source for these tephras which is compatible with the Ethiopian signature. Moreover, Hole 711A provides a reliable magnetostratigraphy for the Oligocene (Chrons 13-9). The tephra layers occur in the interval spanning Chrons C11n.2n-C11n.1n which agrees with the positions of acidic layers in the traps. Calcareous nannofossil stratigraphy confirms the magnetostratigraphic interpretation, with the NP23/24 zonal boundary occurring within the interval containing the tephra layers. Hole 709B supports the results from Hole 711A. Thus, the Ethiopian traps can be

  17. Astronomical calibration of the first Toba super-eruption from deep-sea sediments

    Science.gov (United States)

    Lee, M.; Chen, C.; Wei, K.; Iizuka, Y.

    2003-04-01

    Correlations between tephra layers interbedded within deep-sea cores and radiometrically dated volcanic eruptions provide an independent means of verifying dating techniques developed for sediment cores. Alternatively, the chronostratigraphic framework developed from marine sediments can be used to calibrate ages of land-base eruptions, if geochemical correlations can be established. In this study, we examined three deep-sea cores along an east-west transection across the South China Sea, with a distance of ~1800 to 2500 km away from the Toba caldera. The occurrence of the Oldest Toba Tuff was recognized on the basis of its geochemical characteristics, such as a high-silicate, high-potassium content and a distinct strontium isotope composition. The correlative tephra layer occurs slightly above the Australasian microtektite layer and below the Brunhes/Matuyama boundary, which in constitute three time-parallel markers for correlation and dating of Quaternary stratigraphic records. Against the astronomically tuned oxygen isotope chronostratigraphy, the rhyolitic ignimbrite erupted during the transition from marine isotope stage 20 (glacial) to stage 19 (interglacial) with an estimated age of 788 ka. The refined age is in good agreement with the radiometric age of 800+20 ka for Layer D of ODP Site 758 (Hall and Farrell, 1995), but significantly younger than the commonly referred age of 840+30 ka (Diehl et al., 1987). The mid-Pleistocene eruption expelled at least 800-1000 km3 dense-rock-equivalent of rhyolitic magma taking into account the widespread ashfall deposits in the Indian Ocean and the South China Sea basins. In spite of its exceptional magnitude, the timing of the first Toba super-eruption disputes a possible causal linkage between a major volcanic eruption and a long-term global climatic deterioration.

  18. Beyond eruptive scenarios: assessing tephra fallout hazard from Neapolitan volcanoes.

    Science.gov (United States)

    Sandri, Laura; Costa, Antonio; Selva, Jacopo; Tonini, Roberto; Macedonio, Giovanni; Folch, Arnau; Sulpizio, Roberto

    2016-04-12

    Assessment of volcanic hazards is necessary for risk mitigation. Typically, hazard assessment is based on one or a few, subjectively chosen representative eruptive scenarios, which use a specific combination of eruptive sizes and intensities to represent a particular size class of eruption. While such eruptive scenarios use a range of representative members to capture a range of eruptive sizes and intensities in order to reflect a wider size class, a scenario approach neglects to account for the intrinsic variability of volcanic eruptions, and implicitly assumes that inter-class size variability (i.e. size difference between different eruptive size classes) dominates over intra-class size variability (i.e. size difference within an eruptive size class), the latter of which is treated as negligible. So far, no quantitative study has been undertaken to verify such an assumption. Here, we adopt a novel Probabilistic Volcanic Hazard Analysis (PVHA) strategy, which accounts for intrinsic eruptive variabilities, to quantify the tephra fallout hazard in the Campania area. We compare the results of the new probabilistic approach with the classical scenario approach. The results allow for determining whether a simplified scenario approach can be considered valid, and for quantifying the bias which arises when full variability is not accounted for.

  19. Resolving the age of Wilson Creek Formation tephras and the Mono Lake excursion using high-resolution SIMS dating of allanite and zircon rims

    Science.gov (United States)

    Vazquez, J. A.; Lidzbarski, M. I.

    2012-12-01

    Sediments of the Wilson Creek Formation surrounding Mono Lake preserve a high-resolution archive of glacial and pluvial responses along the eastern Sierra Nevada due to late Pleistocene climate change. An absolute chronology for the Wilson Creek stratigraphy is critical for correlating the paleoclimate record to other archives in the western U.S. and the North Atlantic region. However, multiple attempts to date the Wilson Creek stratigraphy using carbonates and interbedded rhyolitic tephras yield discordant 14C and 40Ar/39Ar results due to open-system effects, carbon reservoir uncertainties, as well as abundant xenocrysts entrained during eruption. Ion microprobe (SIMS) 238U-230Th dating of the final increments of crystallization recorded by allanite and zircon autocrysts from juvenile pyroclasts yields ages that effectively date eruption of key tephra beds and resolve age uncertainties about the Wilson Creek stratigraphy. To date the final several micrometers of crystal growth, individual allanite and zircon crystals were embedded in soft indium to allow sampling of unpolished rims. Isochron ages derived from rims on coexisting allanite and zircon (± glass) from hand-selected pumiceous pyroclasts delimit the timing of Wilson Creek sedimentation between Ashes 7 and 19 (numbering of Lajoie, 1968) to the interval between ca. 27 to ca. 62 ka. The interiors of individual allanite and zircon crystals sectioned in standard SIMS mounts yield model 238U-230Th ages that are mostly hydrologic responses in the Sierra Nevada and Mono Basin to climate change, with intervals of lake filling and glacial-snowpack melting that are in phase with peaks in spring insolation. Moreover, the results demonstrate that high-spatial resolution SIMS dating of accessory mineral rims is an alternative and promising approach for resolving the depositional ages of silicic tephras containing minerals that crystallized over protracted intervals or that are plagued by incorporation of xenocrysts

  20. Probabilistic short-term volcanic hazard in phases of unrest: A case study for tephra fallout

    Science.gov (United States)

    Selva, Jacopo; Costa, Antonio; Sandri, Laura; Macedonio, Giovanni; Marzocchi, Warner

    2014-12-01

    During volcanic crises, volcanologists estimate the impact of possible imminent eruptions usually through deterministic modeling of the effects of one or a few preestablished scenarios. Despite such an approach may bring an important information to the decision makers, the sole use of deterministic scenarios does not allow scientists to properly take into consideration all uncertainties, and it cannot be used to assess quantitatively the risk because the latter unavoidably requires a probabilistic approach. We present a model based on the concept of Bayesian event tree (hereinafter named BET_VH_ST, standing for Bayesian event tree for short-term volcanic hazard), for short-term near-real-time probabilistic volcanic hazard analysis formulated for any potential hazardous phenomenon accompanying an eruption. The specific goal of BET_VH_ST is to produce a quantitative assessment of the probability of exceedance of any potential level of intensity for a given volcanic hazard due to eruptions within restricted time windows (hours to days) in any area surrounding the volcano, accounting for all natural and epistemic uncertainties. BET_VH_ST properly assesses the conditional probability at each level of the event tree accounting for any relevant information derived from the monitoring system, theoretical models, and the past history of the volcano, propagating any relevant epistemic uncertainty underlying these assessments. As an application example of the model, we apply BET_VH_ST to assess short-term volcanic hazard related to tephra loading during Major Emergency Simulation Exercise, a major exercise at Mount Vesuvius that took place from 19 to 23 October 2006, consisting in a blind simulation of Vesuvius reactivation, from the early warning phase up to the final eruption, including the evacuation of a sample of about 2000 people from the area at risk. The results show that BET_VH_ST is able to produce short-term forecasts of the impact of tephra fall during a rapidly

  1. Luminescence property of volcanic quartz and the use of red isothermal TL for dating tephras

    International Nuclear Information System (INIS)

    Tsukamoto, S.; Murray, A.S.; Huot, S.; Watanuki, T.; Denby, P.M.; Botter-Jensen, L.

    2007-01-01

    An optically stimulated luminescence (OSL) age obtained from a Japanese tephra using quartz phenocrysts severely underestimated the known age. The characteristics of the OSL signals were investigated in order to understand the cause of the underestimation; the main OSL component of volcanic quartz has a thermodynamic lifetime of about 1700 years at room temperature, and it also seems to fade anomalously (i.e. athermally). Measurement of conventional red thermoluminescence (RTL) using a Ga-As photomultiplier tube was difficult due to the presence of a strong thermal background, although RTL gave an age consistent with the independent age. Furthermore, red isothermal TL (RITL) at 380 deg. C allowed the RTL signal to be separated from to the thermal background, and RITL ages of three volcanic quartz samples show good agreement with independent ages

  2. Toward a Last Interglacial Compilation Using a Tephra-based Chronology: a Future Reference For Model-data Comparison

    Science.gov (United States)

    Bazin, L.; Govin, A.; Capron, E.; Nomade, S.; Lemieux-Dudon, B.; Landais, A.

    2017-12-01

    The Last Interglacial (LIG, 129-116 ka) is a key period to decipher the interactions between the different components of the climate system under warmer-than-preindustrial conditions. Modelling the LIG climate is now part of the CMIP6/PMIP4 targeted simulations. As a result, recent efforts have been made to propose surface temperature compilations focusing on the spatio-temporal evolution of the LIG climate, and not only on its peak warmth as previously proposed. However, the major limitation of these compilations remains in the climatic alignment of records (e.g. temperature, foraminiferal δ18O) that is performed to define the sites' chronologies. Such methods prevent the proper discussion of phase relationship between the different sites. Thanks to recent developments of the Bayesian Datice dating tool, we are now able to build coherent multi-archive chronologies with a proper propagation of the associated uncertainties. We make the best use of common tephra layers identified in well-dated continental archives and marine sediment cores of the Mediterranean region to propose a coherent chronological framework for the LIG independent of any climatic assumption. We then extend this precise chronological context to the North Atlantic as a first step toward a global coherent compilation of surface temperature and stable isotope records. Based on this synthesis, we propose guidelines for the interpretation of different proxies measured from different archives that will be compared with climate model parameters. Finally, we present time-slices (e.g. 127 ka) of the preliminary regional synthesis of temperature reconstructions and stable isotopes to serve as reference for future model-data comparison of the up-coming CMIP6/PMIP4 LIG simulations.

  3. How 210Pb dating gives information about volcanic radionuclides

    International Nuclear Information System (INIS)

    Whitehead, N.E.

    1998-01-01

    In lake sediments from the Taupo Volcanic Zone, the 1886 Tarawera tephra is often observed. The tephra contains unsupported 210 Pb which corresponds to its stratigraphic age, and shows that the 210 Pb has been adsorbed in its passage through the air, but not from the volatiles in the volcano itself which would be expected to contain the radionuclide. It is shown that only a small portion of the available 210 Pb in normal air was scavenged by the tephra. Sedimentation rates derived using the tephra were similar to those from 210 Pb dating. Some lakes showed excess 210 Pb inventories, ascribed to lake-bed geothermal activity. Contrary to expectation of increased erosion following deposition of an ash layer, sedimentation rates were less

  4. Occurrence of Somma-Vesuvio fine ashes in the tephrostratigraphic record of Panarea, Aeolian Islands

    Science.gov (United States)

    Donatella, De Rita; Daniela, Dolfi; Corrado, Cimarelli

    2008-10-01

    Ash-rich tephra layers interbedded in the pyroclastic successions of Panarea island (Aeolian archipelago, Southern Italy) have been analyzed and related to their original volcanic sources. One of these tephra layers is particularly important as it can be correlated by its chemical and morphoscopic characteristics to the explosive activity of Somma-Vesuvio. Correlation with the Pomici di Base eruption, that is considered one of the largest explosive events causing the demolition of the Somma stratovolcano, seems the most probable. The occurrence on Panarea island of fine ashes related to this eruption is of great importance for several reasons: 1) it allows to better constrain the time stratigraphy of the Panarea volcano; 2) it provides a useful tool for tephrochronological studies in southern Italy and finally 3) it allows to improve our knowledge on the distribution of the products of the Pomici di Base eruption giving new insights on the dispersion trajectories of fine ashes from plinian plumes. Other exotic tephra layers interbedded in the Panarea pyroclastic successions have also been found. Chemical and sedimentological characteristics of these layers allow their correlation with local vents from the Aeolian Islands thus constraining the late explosive activity of Panarea dome.

  5. Geological and Seismological Analysis of the 13 February 2001 Mw 6.6 El Salvador Earthquake: Evidence for Surface Rupture and Implications for Seismic Hazard

    OpenAIRE

    Canora Catalán, Carolina; Martínez Díaz, José J.; Villamor Pérez, María Pilar; Berryman, K.R.; Álvarez Gómez, José Antonio; Pullinger, Carlos; Capote del Villar, Ramón

    2010-01-01

    The El Salvador earthquake of 13 February 2001 (Mw 6.6) caused tectonic rupture on the El Salvador fault zone (ESFZ). Right-lateral strike-slip surface rupture of the east–west trending fault zone had a maximum surface displacement of 0.60 m. No vertical component was observed. The earthquake resulted in widespread landslides in the epicentral area, where bedrock is composed of volcanic sediments, tephra, and weak ignimbrites. In the aftermath of the earthquake, widespread dama...

  6. The effect of the sea on hazard assessment for tephra fallout at Campi Flegrei: a preliminary approach through the use of pyPHaz, an open tool to analyze and visualize probabilistic hazards

    Science.gov (United States)

    Tonini, Roberto; Sandri, Laura; Costa, Antonio; Selva, Jacopo

    2014-05-01

    Campi Flegrei (CF) is a large volcanic field located west of the Gulf of Naples, characterized by a wide and almost circular caldera which is partially submerged beneath the Gulf of Pozzuoli. It is known that the magma-water interaction is a key element to determine the character of submarine eruptions and their impact on the surrounding areas, but this phenomenon is still not well understood and it is rarely considered in hazard assessment. The aim of the present work is to present a preliminary study of the effect of the sea on the tephra fall hazard from CF on the municipality of Naples, by introducing a variability in the probability of tephra production according to the eruptive scale (defined on the basis of the erupted volume) and the depth of the opening submerged vents. Four different Probabilistic Volcanic Hazard Assessment (PVHA) models have been defined through the application of the model BET_VH at CF, by accounting for different modeling procedures and assumptions for the submerged part of the caldera. In particular, we take into account: 1) the effect of the sea as null, i.e. as if the water were not present; 2) the effect of the sea as a cap that totally blocks the explosivity of eruptions and consequently the tephra production; 3) an ensemble model between the two models described at the previous points 1) and 2); 4) a variable probability of tephra production depending on the depth of the submerged vent. The PVHA models are then input to pyPHaz, a tool developed and designed at INGV to visualize, analyze and merge into ensemble models PVHA's results and, potentially, any other kind of probabilistic hazard assessment, both natural and anthropic, in order to evaluate the importance of considering a variability among subaerial and submerged vents on tephra fallout hazard from CF in Naples. The analysis is preliminary and does not pretend to be exhaustive, but on one hand it represents a starting point for future works; on the other hand, it is a good

  7. Widespread pain: is an improved classification possible?

    Science.gov (United States)

    MacFarlane, G J; Croft, P R; Schollum, J; Silman, A J

    1996-09-01

    The classification of widespread pain, proposed by the American College of Rheumatology (ACR) for use in the clinic as a screen for fibromyalgia, as described, does not require truly widespread pain. Studies considering the epidemiology of widespread pain per se may therefore require a definition with greater face validity, which might also show enhanced associations with other physical and psychological measures. We aimed to develop a more coherent definition of widespread pain for use in epidemiological studies and to compare performance in identifying individuals with significant morbidity. A group of 172 subjects who had participated in a community based study on the occurrence of pain were identified and categorized by their pain experience as indicated on line drawings of the body according to ACR definition and to a new, more stringent definition that required the presence of more diffuse limb pain. A number of other clinical and psychological measures were recorded for these individuals and the association between their pain status measures and these other variables was assessed and compared. Persons satisfying the newly proposed definition for chronic widespread pain, in comparison with those who satisfied only the present ACR definition, had a significantly higher score on the General Health Questionnaire [median difference (MD) 7.95% CI 1.13], a higher score on the Health and Fatigue Questionnaire (MD 10.95% CI 0.15), and greater problems with sleep (sleep problem score MD 4.95% CI 0.9). Those satisfying the new definition also had a greater number of tender points on examination (MD 3.95% CI -1.7). The morbidity of those satisfying only the present ACR definition was closer to persons who had regional pain. A redefinition of widespread pain has produced a group of subjects whose pain is (a) likely to be more "widespread" and (b) is associated more strongly with factors such as psychological disturbance, fatigue, sleep problems, and tender points, and

  8. Personality disparity in chronic regional and widespread pain.

    Science.gov (United States)

    Chang, Mei-Chung; Chen, Po-Fei; Lung, For-Wey

    2017-08-01

    Chronic pain has high comorbidity with psychiatric disorders, therefore, better understanding of the relationship between chronic pain and mental illness is needed. This study aimed to investigate the pathway relationships among parental attachment, personality characteristics, alexithymic trait and mental health in patients with chronic widespread pain, those with chronic regional pain, and controls. Two hundred and thirty participants were recruited. The parental Bonding Inventory, Eysenck Personality Inventory (EPI), 20-item Toronto Alexithymia Scale (TAS-20), Chinese Health Questionnaire, and Short-Form 36 were filled out. The pathway relationships revealed that patients of mothers who were more protective were more neurotic, had more difficulty identifying feelings (DIF), worse mental health, and a higher association with chronic widespread pain. No differences were found between patients with chronic regional pain and the controls. The predisposing factors for chronic widespread pain, when compared with chronic regional pain, may be more closely related to psychiatric disorders. The pathways to chronic regional pain and chronic widespread pain differ, with neuroticism and the alexithymic DIF trait being the main factors defining chronic widespread pain. Therefore, besides therapies targeting pain symptoms, psychiatric consultation, medication and psychotherapy are also recommended for those with chronic widespread pain to alleviate their mental health conditions. Copyright © 2017 Elsevier Ireland Ltd. All rights reserved.

  9. The Alleret Maar lacustrine sequence (French Massif Central): a 150 ka long early-middle Pleistocene continental paleoenvironmental record.

    Science.gov (United States)

    Nomade, S.; Pastre, J.; Guillou, H.; Gauthier, A.; Scaillet, S.

    2008-12-01

    Lacustrine maar sequences of the French Massif Central are of great interest for paleoclimatic and paleoenvironmental reconstructions of mid-latitudes Quaternary continental environments. In particular, the western Velay region yields exceptional sequences spanning the last 450 ka (Reille et al., J. Quat. Sci. 2000). However, older sequences remain largely unknown despite the presence of interbedded alkaline tephras allowing precise absolute radiochronological control of many lacustrine squences. The Alleret maar is a 1500 m wide phreatomagmatic crater that provides a long lacustrine sequence (41 m). The upper part of this sequence (AL2 core, 14.6 m) was studied between 2005 and 2006 (Pastre et al., C. R. Acad Sci, 2007). A 39Ar/40Ar date (557 ± 5ka) obtained from an interbedded tephra layer located at 7m as well as the associated pollen data attribute the beginning of this sequence to the MIS 15. Thanks to the AL3 core recovered in 2005 (40.6 m, CNRS Meudon) several new tephra layers were discovered in the bottom part of this lacustrine sequence. Three new 39Ar/40Ar ages (single crystal analyses) from trachytic tephra layers were obtained at the LSCE Argon Laboratory (France). These layers are located at -30.2, -36.2 and -39.2m. Ages obtained relative to the ACR-2 flux standard (1,201Ma, Kuiper et al., Science, 2008) range from 692 ± 6 ka (MSWD: 2.3, n=18) for the youngest (-30.2m) to 726 ± 9Ka Ka (MSWD: 2.2, n=12) for the lowest tephra located at -39.2m. These new dates indicate a relatively homogeneous deposition rate of 3.5cm/ka and that the last 10 meters cover the MIS 17-MIS18 period. According to these current radiochronological data the complete lacustrine sequence last more than 150ka. Ongoing sedimentary and pollen studies will allow to extend the paleoenvironmental and paleoclimatic records of the French Massif Central towards the beginning of the early middle Pleistocene.

  10. American West Tephras – Geomagnetic polarity events redefined through calibration of radio-isotopic and astronomical time

    DEFF Research Database (Denmark)

    Rivera, Tiffany; Storey, Michael

    calibration. Although this geomagnetic event is not part of the most recent geologic timescale, refined ages on short-lived excursions could hold importance to understanding time scales for the wavering nature of Earth’s magnetic field. We propose a new 40Ar/39Ar age for the Quaternary mineral dating standard......The foundation of the EARTHTIME/GTSnext initiative seeks to construct an internally consistent geologic timescale based on astronomical and radio-isotopic geochronology. American west tephras offer a prime opportunity to integrate these two independent timescales with the geomagnetic timescale....... Using an astronomically calibrated age for the monitor mineral Fish Canyon sanidine (FCs;28.201 ± 0.046 Ma, Kuiper, et al., 2008), ages of Pleistocene geomagnetic polarity events are reexamined. Of particular interest, the Quaternary mineral dating standard Alder Creek sandine (ACs) is the type locality...

  11. Parts of the Whole: Hands On Statistics

    Directory of Open Access Journals (Sweden)

    Dorothy Wallace

    2018-01-01

    Full Text Available In this column we describe a hands-on data collection lab for an introductory statistics course. The exercise elicits issues of normality, sampling, and sample mean comparisons. Based on volcanology models of tephra dispersion, this lab leads students to question the accuracy of some assumptions made in the model, particularly regarding the normality of the dispersal of tephra of identical size in a given atmospheric layer.

  12. Increased rates of large‐magnitude explosive eruptions in Japan in the late Neogene and Quaternary

    Science.gov (United States)

    Sparks, R. S. J.; Wallace, L. M.; Engwell, S. L.; Scourse, E. M.; Barnard, N. H.; Kandlbauer, J.; Brown, S. K.

    2016-01-01

    Abstract Tephra layers in marine sediment cores from scientific ocean drilling largely record high‐magnitude silicic explosive eruptions in the Japan arc for up to the last 20 million years. Analysis of the thickness variation with distance of 180 tephra layers from a global data set suggests that the majority of the visible tephra layers used in this study are the products of caldera‐forming eruptions with magnitude (M) > 6, considering their distances at the respective drilling sites to their likely volcanic sources. Frequency of visible tephra layers in cores indicates a marked increase in rates of large magnitude explosive eruptions at ∼8 Ma, 6–4 Ma, and further increase after ∼2 Ma. These changes are attributed to major changes in tectonic plate interactions. Lower rates of large magnitude explosive volcanism in the Miocene are related to a strike‐slip‐dominated boundary (and temporary cessation or deceleration of subduction) between the Philippine Sea Plate and southwest Japan, combined with the possibility that much of the arc in northern Japan was submerged beneath sea level partly due to previous tectonic extension of northern Honshu related to formation of the Sea of Japan. Changes in plate motions and subduction dynamics during the ∼8 Ma to present period led to (1) increased arc‐normal subduction in southwest Japan (and resumption of arc volcanism) and (2) shift from extension to compression of the upper plate in northeast Japan, leading to uplift, crustal thickening and favorable conditions for accumulation of the large volumes of silicic magma needed for explosive caldera‐forming eruptions. PMID:27656115

  13. Geochemistry of tephra from Bed I, Olduvai Gorge, Tanzania: Stratigraphic correlations and implications for magmatic evolution

    Science.gov (United States)

    McHenry, L.

    2003-04-01

    At least 10 predominantly trachytic and rhyolitic tuffs are preserved interbedded in volcaniclastic sediments of Plio-Pleistocene Bed I, Olduvai Gorge, Tanzania. Physical correlation of the tuffs is complicated by faulting and variation in preservation and lithofacies. Differences in the degree and type of tephra alteration (clay, zeolitic, none) and preservation of glass shards within the various depositional environments (saline-alkaline lake, lake margin, wetlands, alluvial fan) make correlation by conventional glass chemistry methods impossible. However, variations in overall mineralogy and chemical compositions of co-magmatic phenocrysts (feldspar, augite, titanomagnetite, amphibole) have proven useful to uniquely characterize the tuffs for correlation purposes. Samples of 10 major tuffs in the Olduvai Bed I sequence were collected from various depostional and preservational environments situated up to 15 km apart. Thin sections and mineral separates (10-60 grains of each type of phenocryst/ sample, 2-3 samples/ tuff) were analyzed by electron microprobe for major and minor elements. The lower Bed I tuffs are rhyolitic and easily distinguished from the upper tuffs by the presence of quartz and high-Fe augite. Feldspar composition has been previously found to separate all of the upper tuffs (1B-1F) except the two trachyandesitic tuffs (1D and the "unnamed" tuff between 1E and 1F). Mn and Ti concentrations in the titanomagnetites separate the upper tuffs (MnO%: 1B=1.5-2, 1C=1.3-1.6, 1D=1.1-1.4, 1E=1.5-1.7, unnamed= 0.9-1.2, 1F=1.6-2; TiO2%: 1B, 1E=23-26, 1C=18-22, 1D=25-27, unnamed=20-21, 1F= 12-20). Tuffs 1B, unnamed, and 1F contain abundant amphibole, 1D contains none. Mn and Fe concentrations in the augites also separate the tuffs (MnO%: 1B=1.2-1.5, 1C=0.9-1.2, 1D=0.6-0.9, 1E=0.9-1.1, unnamed=0.5-0.7, 1F=variable; FeO%: 1B=19-21, 1C=15-19, 1D=12-16, 1E=13-16, unnamed=11-14, 1F=variable). Results of these findings provide new widespread markers in the Olduvai

  14. Linking Volcanism and Gas Release from the North East Atlantic Volcanic Province to the PETM: Challenges and Updates

    Science.gov (United States)

    Svensen, H.; Jones, M. T.; Jerram, D. A.; Planke, S.; Kjoberg, S.; Schmid, D. W.; Iyer, K.; Tegner, C.

    2016-12-01

    The main phase of the development of the North East Atlantic Volcanic Province took place about 56 Ma and coincides with the Paleocene Eocene Thermal Maximum (PETM). The volcanic activity was characterized by voluminous flood basalts, large plutonic complexes, sub-marine eruptions, widespread tephra deposition, and emplacement of sills and dikes along the continental margins of Norway, Greenland, Ireland, and the UK. Here we review the style and tempo of volcanism during this important period of Earth's history and discuss the sources and volumes of the carbon gases emitted to the ocean and atmosphere. Moreover, we present new data and models from 1) West Greenland showing the impact on sill intrusions on gas generation from heated Cretaceous mudstones, 2) a 3D seismic survey of gas release structures offshore Norway, and 3) Paleocene-Eocene tephra layers from Svalbard and Denmark. Gas migrated out of the contact aureoles by either explosive venting or by slower seepage towards the seafloor as demonstrated by 3D seismic data. Some of the gas was permanently trapped (dry gas and CO2-rich gas) in the source rocks and aureoles. Combined with high-precision zircon ages and a time model for the PETM, our approach may give robust fluxes that can explain both the onset and the body of the PETM.

  15. Late Pleistocene Hansel Valley basaltic ash, northern Lake Bonneville, Utah, USA

    Science.gov (United States)

    Miller, D.M.; Oviatt, Charles G.; Nash, B.P.

    2008-01-01

    The Hansel Valley ash bed lies within 5 cm of the base of deposits of Lake Bonneville (???28 ka) in the vicinity of Great Salt Lake and provides a useful stratigraphic marker for this area of the lake basin. However, it has not been matched to an eruptive edifice, presumably because such an edifice was eroded by waves of Lake Bonneville. We present data for the chemical composition of the tephra and for possible matching lavas and tephras of the region, as well as grain size data for the tephra in an attempt to identify the location of the eruption. Matches with other tephras are negative, but lavas near the coarsest ash deposits match well with the distinctive high values of TiO2 and P2O5 of the ash. Neither chemistry nor grain size data points uniquely to a source area, but an area near the northwest shore of Great Salt Lake and within Curlew Valley is most likely. The Hansel Valley ash is an example of an ash that has no direct numerical date from proximal deposits, despite considerable study, yet nonetheless is useful for stratigraphic studies by virtue of its known stratigraphic position and approximate age. Basaltic tephras commonly are not as widespread as their rhyolitic counterparts, and in some cases apparently are produced by eruptive sources that are short lived and whose edifices are not persistent. ?? 2007 Elsevier Ltd and INQUA.

  16. Tephrostratigraphy of Changbaishan volcano, northeast China, since the mid-Holocene

    Science.gov (United States)

    Sun, Chunqing; Liu, Jiaqi; You, Haitao; Nemeth, Karoly

    2017-12-01

    A detailed tephrostratigraphy of an active volcano is essential for evaluating its eruptive history, forecasting future eruptions and correlation with distal tephra records. Changbaishan volcano is known for its Millennium eruption (ME, AD 940s; VEI 7) and the ME tephra has been detected in Greenland ice cores ∼9000 km from the vent. However, the pre-Millennium (pre-ME) and post-Millennium (post-ME) eruptions are still poorly characterized. In this study, we present a detailed late Holocene eruptive sequence of Changbaishan volcano based on single glass shard compositions from tephra samples collected from around the caldera rim and flanks. Tephra ages are constrained by optically stimulated luminescence (OSL) and AMS 14C dates. Tephra from the mid-Holocene pre-ME eruption can be divided into two pyroclastic fall subunits, and it cannot be correlated with any known Changbaishan-sourced tephra recorded in the Japan Sea based on major element composition of glass shards, such as the B-J (Baegdusan-Japan Basin) and B-V (Baegdusan-Vladivostok-oki) tephras. ME pyroclastic fall deposits from the caldera rims and volcanic flanks can be correlated to the juvenile pumice lapilli or blocks within the pyroclastic density current (PDC) deposits deposited in the valleys around the volcano based on glass shard compositions. Our results indicate that the glass shard compositions of proximal ME tephra are more varied than previously thought and can be correlated with distal ME tephra. In addition, widely-dispersed mafic scoria was ejected by the ME Plinian column and deposited on the western and southern summits and the eastern flank of the volcano. Data for glass from post-ME eruptions, such as the historically-documented AD 1403, AD 1668 and AD 1702 eruptions, are reported here for the first time. Except for the ME, other Holocene eruptions, including pre-ME and post-ME eruptions, had the potential to form widely-distributed tephra layers around northeast Asia, and our dataset

  17. South Aegean volcanic glass. Separation and analysis by INAA and EPMA

    International Nuclear Information System (INIS)

    Saminger, S.; Peltz, C.; Bichler, M.

    2000-01-01

    Pumice from the major volcanic sources (Milos, Nisyros, Yali, Kos and Santorini) in the South Aegean region was investigated to reveal the differences between the composition of the bulk material, which contains a certain percentage of crystallites, and the pure glass phase, which is the main constituent. The knowledge of these differences is important for the identification of vitric tephra layers found in the Eastern Mediterranean region in archaeological context, in deep sea drilling cores and lake sediments. Eruption products, deposited at some distance, show not only a decrease in their grain size, but also have usually lost their crystalline fraction due to gravity separation and consist only of glass shards. Major element distributions in such layers and in pumiceous glass are not sufficient for a reliable identification of the volcanic source, as several eruptions are known to have produced chemically very similar tephra layers in this region. Trace element data, especially of the rather immobile rare earth elements (REEs), can provide greater information on tephra originating from different volcanic eruptions. Therefore, a technique has been developed to separate the glass phase from different primary pumices to reveal differences in their trace element distributions. The concentrations of the major constituents, in particular Al, Ca, Fe, Mg, Mn, Na, Si, and Ti were determined by electron probe microanalysis (EPMA), those of Al, As, Ba, Ca, Ce, Co, Cr, Cs, Dy, Eu, Fe, Hf, K, La, Lu, Mn, Na, Nd, Rb, Sb, Sc, Sm, Ta, Th, Ti, U, V, Yb and Zr by instrumental neutron activation analysis. Subtle differences between the compositions of the glass phase and the bulk material are explained by differentiation during partial crystallization. Their applicability to the classification of tephra layers is demonstrated. (author)

  18. Geochemical signatures of tephras from Quaternary Antarctic Peninsula volcanoes Geoquímica de tefras de volcanes Cuaternarios de la Península Antártica

    Directory of Open Access Journals (Sweden)

    Stefan Kraus

    2013-01-01

    Full Text Available In the northern Antarctic Peninsula area, at least 12 Late Plelstocene-Holocene volcanic centers could be potential sources of tephra layers in the region. We present unique geochemical fingerprints for ten of these volcanoes using major, trace, rare earth element, and isotope data from 95 samples of tephra and other eruption products. The volcanoes have predominantly basaltic and basaltic andesitic compositions. The Nb/Y ratio proves useful to distinguish between volcanic centers located on the eastern (Larsen Rift and those situated on the western side (Bransfield Rift of the Antarctic Peninsula. In addition, the Sr/Nb ratio (for samples with SiO2 En la parte norte de la Península Antártica existen, por lo menos, 12 centros volcánicos del Pleistoceno Tardío-Holoceno que podrían representar las fuentes de horizontes de tefra reconocidos en la región. Se reportan aquí análisis químicos de 10 de estos volcanes, que incluyen análisis de elementos mayores, trazas, tierras raras y composición isotópica de 95 muestras de tefra u otros productos eruptivos. Los volcanes tienen, en su mayoría, composición basáltica a basáltico-andesítica. Las razones Nb/Y resultan útiles para distinguir entre centros volcánicos ubicados al lado oriental (Larsen Rift de aquellos ubicados al lado occidental (Bransfield Rift de la Península Antártica. Adicionalmente, las razones Sr/Nb (para muestras con SiO2 <63 wt%, Sr/Y, Ba/La, Zr/Hf y Th/Nb sirven para caracterizar los productos generados por cada centro volcánico. Análisis de microsonda en vidrio muestran que las rocas estudiadas tienen bajos contenidos de K2O, y que vidrios de rocas provenientes de volcanes ubicados en el rift de Bransfield son ricos en SiO2, mientras que las de volcanes del rift de Larsen tienden hacía contenidos elevados de álcalis. Se propone un algoritmo para la identificación del volcán de origen de un horizonte de tefra cualquiera, basado en las distintivas

  19. Heterogeneous distribution of pelagic sediments incoming the Japan Trench possibly controlling slip propagation on shallow plate boundary fault

    Science.gov (United States)

    Yamaguchi, A.; Nakamura, Y.; Fukuchi, R.; Kurano, H.; Ikehara, K.; Kanamatsu, T.; Arai, K.; Usami, K.; Ashi, J.

    2017-12-01

    Catastrophic tsunami of the 2011 Tohoku Earthquake was triggered by large coseismic slip reached to the Japan Trench axis (e.g. Fujiwara et al., 2011, Science; Kodaira et al., 2012, Nature Geoscience). Results of the IODP Expedition 343 (JFAST) suggest that small friction of smectite-rich pelagic clay caused slip propagation on shallow plate boundary fault (Ujiie et al., 2013, Science; Kameda et al., 2015, Geology; Moore et al., 2015, Geosphere). On the other hand, JAMSTEC high-resolution seismic profiles show that incoming sediments have large heterogeneities in thicknesses, and two areas of extremely thin sediments on the Pacific Plate (thickness less than 100 m) were found at around 39°N (Nakamura et al., AGU 2017, this session). To reconcile whether the smectite-rich pelagic clay even exists in these areas, we sampled surface sediments during the R/V Shinsei Maru KS-15-3 cruise. Seven piston cores were retrieved from seaward trench slope, horst, graben, and graben edge. Core lithologies are mainly diatomaceous ooze/clay including tephra layers, not resemble to pelagic clays discovered in JFAST. Ages of tephra layers were estimated by correlating mineral assemblages and refractive indices of volcanic glasses to Japanese widespread tephras. Averaged sedimentation rates of seaward trench slope, horst, graben, and graben edge are estimated to be 25-30, 6.5-20, 45, 0.9 cm/kyr, respectively. These sedimentation rates imply that sediments on seaward trench slope and horst have been deposited in the last 160-500 kyr, suggesting that entire pelagic sediments, including smectite-rich pelagic clay, have been removed by some reasons in the last 0.5 million years. Possible reason for such modification of sediment is near-trench igneous activity known as petit-spot volcanism (Hirano et al., 2006, Science). The lack of smectite-rich pelagic clay near 39°N of the Japan Trench is consistent with results of tsunami inversions proposing shallow large coseismic slip propagated

  20. Ash resuspension related to the 2011-2012 Cordón Caulle eruption, Chile, in a rural community of Patagonia, Argentina

    Science.gov (United States)

    Forte, Pablo; Domínguez, Lucia; Bonadonna, Costanza; Gregg, Chris E.; Bran, Donaldo; Bird, Deanne; Castro, Jonathan M.

    2018-01-01

    The 2011-2012 Cordón Caulle eruption emitted about 1 km3 of rhyodacitic tephra. Dominant westerly winds in the region caused most of the primary tephra to deposit in neighboring Argentina. In addition to the impact of widespread dispersal and fallout of primary tephra during the eruption, Argentina was also significantly affected by remobilization of the primary ash even several years after the climactic phase of the eruption. In this mixed methods study, we combine aspects of natural and social sciences to characterize the ash resuspension events associated with the 2011-2012 Cordón Caulle deposits and assess the impacts on the Argentinian farming community of Ingeniero Jacobacci in the Patagonian Steppe. Our findings show the primary importance of wind, rainfall and ash availability in controlling the occurrence and persistence of ash resuspension events. The role played by these variables was also reflected in the seasonal distribution of events observed. Regarding the impacts, our results complement those of earlier studies and demonstrate that ash resuspension events can exacerbate the negative impact of primary tephra fallout events from the time of deposition to many years after the eruption. Only after five years has the environment and the farming community begun to show signs of recovery. Our findings also highlight the importance of assessing ash resuspension events in multi-hazard scenarios involving volcanic and hydrometeorologic hazards.

  1. Layered distributed architecture for plant automation

    International Nuclear Information System (INIS)

    Aravamuthan, G.; Verma, Yachika; Ranjan, Jyoti; Chachondia, Alka S.; Ganesh, G.

    2005-01-01

    The development of plant automation system and associated software remains one of the greatest challenges to the widespread implementation of highly adaptive re-configurable automation technology. This paper presents a layered distributed architecture for a plant automation system designed to support rapid reconfiguration and redeployment of automation components. The paper first presents evolution of automation architecture and their associated environment in the past few decades and then presents the concept of layered system architecture and the use of automation components to support the construction of a wide variety of automation system. It also highlights the role of standards and technology, which can be used in the development of automation components. We have attempted to adhere to open standards and technology for the development of automation component at a various layers. It also highlights the application of this concept in the development of an Operator Information System (OIS) for Advanced Heavy Water Reactor (AHWR). (author)

  2. Holocene tephrostratigraphy of southern Chiloé Continental (Andean southern volcanic zone; ~43°S), Chile

    Science.gov (United States)

    Lachowycz, S.; Smith, V. C.; Pyle, D. M.; Mather, T. A.

    2012-12-01

    The eruptive history of the volcanoes in the southern part of the Andean Southern Volcanic Zone (42.5-45°S) is very poorly constrained: only several late Quaternary eruptions have been identified, mostly from study of sparse roadcuts [1]. In this study, we further constrain the Holocene explosive eruption history around 43°S by identifying and analysing tephra layers preserved in a ~3.25m long peat core from Cuesta Moraga [2], ~35km east of Yanteles volcano. Cryptotephra was extracted following the method of [3], in addition to macrotephra; owing to the vicinity of the sampling site to the tephra sources, cryptotephra was found throughout the core stratigraphy, but was sufficiently variable in concentration that discrete layers were identifiable and attributed to specific eruptions. Chemical analysis of the glass by electron microprobe shows that the tephra layers originate from a number of volcanoes in the region. This new tephrostratigraphy improves our knowledge of the important history of explosive volcanism in this area, potentially tying the tephrostratigraphies of surrounding areas (e.g., [4]) and allowing improved evaluation of regional volcanic risk. [1] Naranjo, J.A.., and C. R. Stern, 2004. Holocene tephrochronology of the southernmost part (42°30'-45°S) of the Andean Southern Volcanic Zone. Revista geológica de Chile, 31, pp. 225-240. [2] Heusser, C.J., et al., 1992. Paleoecology of late Quaterary deposits in Chiloé Continental, Chile. Revista Chilena de Historia Natural, 65, pp. 235-245. [3] Blockley, S.P.E., et al., 2005. A new and less destructive laboratory procedure for the physical separation of distal glass tephra shards from sediments. Quaternary Science Reviews, 24, pp. 1952-1960. [4] Watt, S.F.L., et al., 2011. Holocene tephrochronology of the Hualaihue region (Andean southern volcanic zone, ~42°S), southern Chile. Quaternary International, 246, pp. 324-343.

  3. Acoustic and tephra records of explosive eruptions at West Mata submarine volcano, NE Lau Basin

    Science.gov (United States)

    Dziak, R. P.; Bohnenstiehl, D. R.; Baker, E. T.; Matsumoto, H.; Caplan-Auerbach, J.; Mack, C. J.; Embley, R. W.; Merle, S. G.; Walker, S. L.; Lau, T. A.

    2013-12-01

    West Mata is a 1200 m deep submarine volcano where explosive boninite eruptions were directly observed in May 2009. Here we present long-term acoustic and tephra records of West Mata explosion activity from three deployments of hydrophone and particle sensor moorings beginning on 8 January 2009. These records provide insights into the character of explosive magma degassing occurring at the volcano's summit vent until the decline and eventual cessation of the eruption during late 2010 and early 2011. The detailed acoustic records show three types of volcanic signals, 1) discrete explosions, 2) diffuse explosions, and 3) volcanic tremor. Discrete explosions are short duration, high amplitude broad-band signals caused by rapid gas bubble release. Diffuse signals are likely a result of 'trap-door' explosions where a quench cap of cooled lava forms over the magmatic vent but gas pressure builds underneath the cap. This pressure eventually causes the cap to breach and gas is explosively released until pressure reduces and the cap once again forms. Volcanic tremor is typified by narrow-band, long-duration signals with overtones, as well as narrow-band tones that vary frequency over time between 60-100 Hz. The harmonic tremor is thought to be caused by modulation of rapid, short duration gas explosion pulses and not a magma resonance phenomenon. The variable frequency tones may be caused by focused degassing or hydrothermal fluid flow from a narrow volcanic vent or conduit. High frequency (>30 Hz) tremor-like bands of energy are a result of interference caused by multipath wide-band signals, including sea-surface reflected acoustic phases, that arrive at the hydrophone with small time delays. Acoustic data suggest that eruption velocities for a single explosion range from 4-50 m s-1, although synchronous arrival of explosion signals has complicated our efforts to estimate long-term gas flux. Single explosions exhibit ~4-40 m3 s-1 of total volume flux (gas and rock) but

  4. Are neonicotinoid insecticides driving declines of widespread butterflies?

    Directory of Open Access Journals (Sweden)

    Andre S. Gilburn

    2015-11-01

    Full Text Available There has been widespread concern that neonicotinoid pesticides may be adversely impacting wild and managed bees for some years, but recently attention has shifted to examining broader effects they may be having on biodiversity. For example in the Netherlands, declines in insectivorous birds are positively associated with levels of neonicotinoid pollution in surface water. In England, the total abundance of widespread butterfly species declined by 58% on farmed land between 2000 and 2009 despite both a doubling in conservation spending in the UK, and predictions that climate change should benefit most species. Here we build models of the UK population indices from 1985 to 2012 for 17 widespread butterfly species that commonly occur at farmland sites. Of the factors we tested, three correlated significantly with butterfly populations. Summer temperature and the index for a species the previous year are both positively associated with butterfly indices. By contrast, the number of hectares of farmland where neonicotinoid pesticides are used is negatively associated with butterfly indices. Indices for 15 of the 17 species show negative associations with neonicotinoid usage. The declines in butterflies have largely occurred in England, where neonicotinoid usage is at its highest. In Scotland, where neonicotinoid usage is comparatively low, butterfly numbers are stable. Further research is needed urgently to show whether there is a causal link between neonicotinoid usage and the decline of widespread butterflies or whether it simply represents a proxy for other environmental factors associated with intensive agriculture.

  5. Gas solubilities widespread applications

    CERN Document Server

    Gerrard, William

    1980-01-01

    Gas Solubilities: Widespread Applications discusses several topics concerning the various applications of gas solubilities. The first chapter of the book reviews Henr's law, while the second chapter covers the effect of temperature on gas solubility. The third chapter discusses the various gases used by Horiuti, and the following chapters evaluate the data on sulfur dioxide, chlorine data, and solubility data for hydrogen sulfide. Chapter 7 concerns itself with solubility of radon, thoron, and actinon. Chapter 8 tackles the solubilities of diborane and the gaseous hydrides of groups IV, V, and

  6. Occurrence of an unknown Atlantic eruption in the Chaîne des Puys volcanic field (Massif Central, France)

    Science.gov (United States)

    Jouannic, G.; Walter-Simonnet, A. V.; Bossuet, G.; Cubizolle, H.; Boivin, P.; Devidal, J. L.; Oberlin, C.

    2014-08-01

    A volcanic ash layer, called MF1, was recently identified in Holocene sediments from the Gourgon and Molhiac peat bogs (Monts du Forez, French Massif Central). This ash layer consists of colorless shards with a heterogeneous trachytic to rhyolitic composition. The trace elements analyzed by Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS) attest to a local origin. Radiocarbon dating of peat samples taken within and below the ash layer indicates the best age at 6339 ± 61 cal yr BP, i.e. an age contemporaneous with the volcanic activity of Montchal, Montcineyre and Pavin volcanoes from the Chaîne des Puys volcanic field. These volcanoes are characterized by basaltic and trachytic products, thus the rhyolitic composition of MF1 tephra suggests that it is likely originated from an unknown eruption. These results again confirm the interest of studying the distal volcanic ash fallouts in order to establish or specify records of past eruptions of volcanic fields. Identification of this new tephra layer also provides an additional tephrochronological marker for Eastern French Massif Central.

  7. Thermal Non-equilibrium Consistent with Widespread Cooling

    Science.gov (United States)

    Winebarger, A.; Lionello, R.; Mikic, Z.; Linker, J.; Mok, Y.

    2014-01-01

    Time correlation analysis has been used to show widespread cooling in the solar corona; this cooling has been interpreted as a result of impulsive (nanoflare) heating. In this work, we investigate wide-spread cooling using a 3D model for a solar active region which has been heated with highly stratified heating. This type of heating drives thermal non-equilibrium solutions, meaning that though the heating is effectively steady, the density and temperature in the solution are not. We simulate the expected observations in narrowband EUV images and apply the time correlation analysis. We find that the results of this analysis are qualitatively similar to the observed data. We discuss additional diagnostics that may be applied to differentiate between these two heating scenarios.

  8. Volcanic Tephra ejected in south eastern Asia is the sole cause of all historic ENSO events. This natural aerosol plume has been intensified by an anthropogenic plume in the same region in recent decades which has intensified some ENSO events and altered the Southern Oscillation Index characteristics

    Science.gov (United States)

    Potts, K. A.

    2017-12-01

    ENSO events are the most significant perturbation of the climate system. Previous attempts to link ENSO with volcanic eruptions typically failed because only large eruptions across the globe which eject tephra into the stratosphere were considered. I analyse all volcanic eruptions in South Eastern (SE) Asia (10ºS to 10ºN and from 90ºE to 160ºE) the most volcanically active area in the world with over 23% of all eruptions in the Global Volcanism Program database occurring here and with 5 volcanoes stated to have erupted nearly continuously for 30 years. SE Asia is also the region where the convective arm of the thermally direct Walker Circulation occurs driven by the intense equatorial solar radiation which creates the high surface temperature. The volcanic tephra plume intercepts some of the solar radiation by absorption/reflection which cools the surface and heats the atmosphere creating a temperature inversion compared to periods without the plume. This reduces convection and causes the Walker Cell and Trade Winds to weaken. This reduced wind speed causes the central Pacific Ocean to warm which creates convection there which further weakens the Walker Cell. With the reduced wind stress the western Pacific warm pool migrates east. This creates an ENSO event which continues until the tephra plume reduces, typically when the SE Asian monsoon commences, and convection is re-established over SE Asia and the Pacific warm pool migrates back to the west. Correlations of SE Asian tephra and the ENSO indices are typically over 0.80 at p indices. If two events A and B correlate 5 options are available: 1. A causes B; 2. B causes A; 3. C, another event, causes A &B simultaneously; 4. It's a coincidence; and 5. The relationship is complex with feedback. The volcanic correlations only allow options 1 or 4 as ENSO cannot cause volcanoes to erupt and are backed up by several independent satellite datasets. I conclude volcanic and anthropogenic aerosols over SE Asia are the

  9. Holocene volcanic geology, volcanic hazard, and risk on Taveuni, Fiji

    International Nuclear Information System (INIS)

    Cronin, S.J.; Neall, V.E.

    2001-01-01

    The Holocene volcanic geology of Taveuni has been mapped in order to produce a volcanic hazard and risk assessment for the island. Taveuni is the third-largest island of the Fiji group and home to 14,500 people. At least cubic km 2.7 of olivine-alkali-basalt magma was erupted from over 100 events throughout the Holocene. Vents are concentrated along a northeast-striking rift zone that is parallel to other regional structural trends. There is an overall trend of younging southward along the rift. Holocene lavas and tephras are grouped within six newly defined eruptive periods, established on a basis of radiocarbon dating. Within these periods, 14 tephra layers, useful as local marker horizons, are recognised. At least 58% of Holocene eruptions produced lava flows, while almost all produced some tephra. Individual eruption event volumes ranged between 0.001 and cubic km 0.20 (dense rock equivalent). Many eruptions involved at least some phases of phreatic and/or phreato-magmatic activity, although dominant hydrovolcanic activity was limited to only a few events. A volcanic hazard map is presented, based on the Holocene geology map and statistical analyses of eruption recurrence. The highest levels of ground-based and near-vent hazards are concentrated along the southern portion of the island's rift axis, with the paths of initial lava flows predicted from present topography. Tephra fall hazards are based on eruption parameters interpreted from mapped Holocene tephra layers. Hawaiian explosive-style eruptions appear to be a dominant eruptive process, with prevailing low-level (<3 km) southeasterly winds dispersing most tephra to the northwestern quadrant. Vulnerable elements (population centres, infrastructure, and economy) on Taveuni have been considered in deriving a volcanic risk assessment for the island. A number of infrastructural and subdivision developments are either under way or planned for the island, driven by its highly fertile soils and availability of

  10. The violent Strombolian eruption of 10 ka Pelado shield volcano, Sierra Chichinautzin, Central Mexico

    Science.gov (United States)

    Lorenzo-Merino, A.; Guilbaud, M.-N.; Roberge, J.

    2018-03-01

    Pelado volcano is a typical example of an andesitic Mexican shield with a summital scoria cone. It erupted ca. 10 ka in the central part of an elevated plateau in what is today the southern part of Mexico City. The volcano forms a roughly circular, 10-km wide lava shield with two summital cones, surrounded by up to 2.7-m thick tephra deposits preserved up to a distance of 3 km beyond the shield. New cartographic, stratigraphic, granulometric, and componentry data indicate that Pelado volcano was the product of a single, continuous eruption marked by three stages. In the early stage, a > 1.5-km long fissure opened and was active with mild explosive activity. Intermediate and late stages were mostly effusive and associated with the formation of a 250-m high lava shield. Nevertheless, during these stages, the emission of lava alternated and/or coexisted with highly explosive events that deposited a widespread tephra blanket. In the intermediate stage, multiple vents were active along the fissure, but activity was centered at the main cone during the late stage. The final activity was purely effusive. The volcano emitted > 0.9 km3 dense-rock equivalent (DRE) of tephra and up to 5.6 km3 DRE of lavas. Pelado shares various features with documented "violent Strombolian" eruptions, including a high fragmentation index, large dispersal area, occurrence of plate tephra, high eruptive column, and simultaneous explosive and effusive activity. Our results suggest that the associated hazards (mostly tephra fallout and emplacement of lava) would seriously affect areas located up to 25 km from the vent for fallout and 5 km from the vent for lava, an important issue for large cities built near or on potentially active zones, such as Mexico City.

  11. Thin Film Catalyst Layers for Direct Methanol Fuel Cells

    Science.gov (United States)

    Witham, C. K.; Chun, W.; Ruiz, R.; Valdez, T. I.; Narayanan, S. R.

    2000-01-01

    One of the primary obstacles to the widespread use of the direct methanol fuel cell (DMFC) is the high cost of the catalyst. Therefore, reducing the catalyst loading well below the current level of 8-12 mg/cm 2 would be important to commercialization. The current methods for preparation of catalyst layers consisting of catalyst, ionomer and sometimes a hydrophobic additive are applied by either painting, spraying, decal transfer or screen printing processes. Sputter deposition is a coating technique widely used in manufacturing and therefore particularly attractive. In this study we have begun to explore sputtering as a method for catalyst deposition. Present experiments focus on Pt-Ru catalyst layers for the anode.

  12. Multifunctional high-reflective and antireflective layer systems with easy-to-clean properties

    International Nuclear Information System (INIS)

    Gloess, D.; Frach, P.; Gottfried, C.; Klinkenberg, S.; Liebig, J.-S.; Hentsch, W.; Liepack, H.; Krug, M.

    2008-01-01

    High-reflective (HR) and even more antireflective (AR) layer systems are in use for widespread applications. Multifunctional layer systems providing high optical functionality with an easy-to-clean or a self-cleaning behaviour would be preferable for many applications to avoid soiling of the surface. In this paper, the feasibility of fabrication by highly productive pulse magnetron sputtering in an in-line coating plant is investigated. Easy-to-clean properties are achieved by a top layer of photocatalytic and photoinduced hydrophilic TiO 2 . Multifunctional HR layer systems were successfully deposited on glass and polyethylene terephthalate (PET) substrates at a low deposition temperature of 150 deg. C, demonstrating the possibility of coating certain polymer materials. Double-sided multifunctional AR layer systems with a single-sided photoinduced hydrophilic TiO 2 top coating have a resulting reflectivity of about 3% and transmittance of about 97% in the visible range of light

  13. The Tephra Layer From the Plinian Eruption in ™r‘faj”kull 1362, Southeast Iceland

    Science.gov (United States)

    Selbekk, R. S.

    2002-12-01

    eruption proceeded in three successive phases. An initial explosion produced phreatomagmatic debris associated with up to 35% of lithic fragments. In distal facies of the fallout, the initial phase is recognised as pale brownish base of the otherwise white glassy layer. The material ejection proceeded in two largely similar phases. These phases are separated only by a transition in grain size distribution indicating a temporary lowering in the effusion rate.

  14. An 18,000 year-long eruptive record from Volcán Chaitén, northwestern Patagonia: Paleoenvironmental and hazard-assessment implications

    Science.gov (United States)

    Alloway, Brent V.; Pearce, Nick J. G.; Moreno, Patricio I.; Villarosa, Gustavo; Jara, Ignacio; De Pol-Holz, Ricardo; Outes, Valeria

    2017-07-01

    The 2008 eruption of Volcán Chaitén (VCha) in northwestern Patagonia was the first explosive rhyolitic eruption to have occurred within a century and provided an unprecedented scientific opportunity to examine all facets of the eruption ranging from magma rheology/ascent rates to ash-fall effects on biota and infrastructure. Up to very recently it was thought that the latest eruption prior to the 2008 event occurred c. 9750 cal. a BP. Although a number of researchers have recognised additional eruptive products, but their stratigraphy, age, and geochemical attributes have not been systematically described and/or recorded. In this study, we provide a detailed examination of andic cover-beds and tephra-bearing lake sequences located both proximally and distally to VCha, which record a series of hitherto unknown rhyolitic eruptive products and place all previous observations firmly within a coherent stratigraphic framework. Through major- and trace-element glass shard geochemistry we are able to confidently verify eruptive source. A total of 20 discrete tephra beds are recognised, with at least 10 having widespread areal distributions and/or depositional imprints broadly comparable to, or greater than, the 2008-tephra event. This record indicates that VCha has been continuously but intermittently active as far back as the end of the Last Glacial Maximum (c. 18,000 cal a BP) with two dominant, genetically related magma types and an intermediary 'mixed' type. Before this the eruptive record has been largely obscured and/or erased by widespread Andean piedmont glaciation. However, based on the tempo of VCha activity over the last c. 18,000 years, older VCha eruptives can be anticipated to occur as well as future hazardous explosive events. The new eruptive inventory will ultimately be useful for correlating equivalent-aged sequences and refining long-term eruptive tempo as well as corresponding temporal changes in magmatic evolution.

  15. Compressibility of the fouling layer formed by membrane bioreactor sludge and supernatant

    DEFF Research Database (Denmark)

    Jørgensen, Mads Koustrup; Poorasgari, Eskandar; Christensen, Morten Lykkegaard

    Membrane bioreactors (MBR) are increasingly used for wastewater treatment as they give high effluent quality, low footprint and efficient sludge degradation. However, the accumulation and deposition of sludge components on and within the membrane (fouling) limits the widespread application of MBR....... Compressibility of the gel layer was studied in a dead-end filtration system, whereas the compressibility of a fouling layer formed by MBR sludge was studied in a submerged system hollow sheet membrane by TMP stepping. It was shown that the fouling layer formed by the MBR sludge was highly compressible within....... Hence, for MBR systems operated at constant flux mode, the applied pressure should be increased over time, to compensate for the lower permeability. Increasing applied pressure causes compression of the fouling layer and results in a more severe permeability decline [1]. In a general view, the fouling...

  16. Volcanology and hazards of phreatomagmatic basaltic eruptions

    DEFF Research Database (Denmark)

    Schmith, Johanne

    Iceland is one of the most active terrestrial volcanic regions on Earth with an average of more than 20 eruptions per century. Around 80% of all events are tephra generating explosive eruptions, but less than 10 % of all known tephra layers have been mapped. Recent hazard assessment models show...... that the two key parameters for hazard assessment modeling are total grain size distribution (TGSD) and eruptive style. These two parameters have been determined for even fewer eruptive events in Iceland. One of the most hazardous volcanoes in Iceland is Katla and no data set of TGSD or other eruptive...... parameters exist. Katla has not erupted for 99 years, but at least 2 of the 20 eruptions since the settlement of Iceland in 871 have reached Northern Europe as visible tephra fall. These eruptions occurred in 1755 and 1625 and remain enigmatic both in terms of actual size and eruption dynamics. This work...

  17. Widespread marrow necrosis during pregnancy

    International Nuclear Information System (INIS)

    Knickerbocker, W.J.; Quenville, N.F.

    1982-01-01

    Recently, a 22-year-old Caucasian female was referred to our Hospital two days post-partum. She had been feeling unwell during the last few days of her pregnancy and complained of multiple aches and pains, worst in the abdomen and lower back. Her admission platelet count was severely depressed and a bone biopsy showed extensive marrow necrosis with viable bony trabeculae. There was no evidence of vasculitis, vascular thrombosis, or malignancy. Widespread marrow necrosis in pregnancy followed by recovery, to our knowledge, has not been previously reported. (orig.)

  18. Engineering Seismic Base Layer for Defining Design Earthquake Motion

    International Nuclear Information System (INIS)

    Yoshida, Nozomu

    2008-01-01

    Engineer's common sense that incident wave is common in a widespread area at the engineering seismic base layer is shown not to be correct. An exhibiting example is first shown, which indicates that earthquake motion at the ground surface evaluated by the analysis considering the ground from a seismic bedrock to a ground surface simultaneously (continuous analysis) is different from the one by the analysis in which the ground is separated at the engineering seismic base layer and analyzed separately (separate analysis). The reason is investigated by several approaches. Investigation based on eigen value problem indicates that the first predominant period in the continuous analysis cannot be found in the separate analysis, and predominant period at higher order does not match in the upper and lower ground in the separate analysis. The earthquake response analysis indicates that reflected wave at the engineering seismic base layer is not zero, which indicates that conventional engineering seismic base layer does not work as expected by the term ''base''. All these results indicate that wave that goes down to the deep depths after reflecting in the surface layer and again reflects at the seismic bedrock cannot be neglected in evaluating the response at the ground surface. In other words, interaction between the surface layer and/or layers between seismic bedrock and engineering seismic base layer cannot be neglected in evaluating the earthquake motion at the ground surface

  19. Geological Development of the Izu-Bonin Forearc Since the Eocene Based on Biostratigraphic, Rock Magnetic, and Sediment Provenance Observations from IODP Expedition 352 Drill Cores

    Science.gov (United States)

    Petronotis, K. E.; Robertson, A.; Kutterolf, S.; Avery, A.; Baxter, A.; Schindlbeck, J. C.; Wang, K. L.; Acton, G.

    2016-12-01

    International Ocean Discovery Program (IODP) Expedition 352 recovered early Oligocene to recent sediments above Eocene igneous basement at 4 sites in the Izu-Bonin Forearc. The sites were selected to investigate the forearc region since subduction initiation in the Eocene, with Sites U1439 and U1442 being cored into the upper trench slope and Sites U1440 and U1441 into the lower trench slope. Postcruise studies of biostratigraphy, sediment chemistry, tephra composition and chronology and magnetic properties, along with observations from prior coring help constrain the regional geological development. Volcanic activity in the area, as inferred from its influence on sediment composition, has varied between long periods of activity and quiescence. Combined whole-rock sediment chemistry and tephra compositions suggest that during the Oligocene to earliest Miocene ( 30-22 Ma) tuffaceous input of predominantly dacitic composition was mainly derived from the intra-oceanic Izu-Bonin Arc. The early Miocene interval ( 22-15 Ma) lacks tuffaceous input, as supported by rock magnetic data. During this period, the forearc subsided beneath the carbonate compensation depth (CCD), as evidenced by radiolarian-bearing mud and metal-rich silty clay. This was followed by input of tephra with bimodal felsic and mafic compositions from the Izu-Bonin Arc from 15 to 5 Ma. Middle Miocene to Quaternary time was characterized by increased carbonate preservation, coupled with abundant, predominantly felsic tephra input, which is chemically indicative of a Japan continental arc source (Honshu), with additional chemically distinctive input from the Izu-Bonin Arc. Extending back to 32 Ma, tephra layers can be correlated between the upper-slope sites, extrapolated to the less well-dated lower-slope sites, and further correlated with onland Japanese tephra (Kutterolf et al., 2016; Goldschmidt Conference). Overall, the new results provide an improved understanding of the regional tectonic evolution.

  20. Monogenetic origin of Ubehebe Crater maar volcano, Death Valley, California: Paleomagnetic and stratigraphic evidence

    Science.gov (United States)

    Champion, Duane E.; Cyr, Andy; Fierstein, Judy; Hildreth, Wes

    2018-04-01

    Paleomagnetic data for samples collected from outcrops of basaltic spatter at the Ubehebe Crater cluster, Death Valley National Park, California, record a single direction of remanent magnetization indicating that these materials were emplaced during a short duration, monogenetic eruption sequence 2100 years ago. This conclusion is supported by geochemical data encompassing a narrow range of oxide variation, by detailed stratigraphic studies of conformable phreatomagmatic tephra deposits showing no evidence of erosion between layers, by draping of sharp rimmed craters by later tephra falls, and by oxidation of later tephra layers by the remaining heat of earlier spatter. This model is also supported through a reinterpretation and recalculation of the published 10Be age results (Sasnett et al., 2012) from an innovative and bold exposure-age study on very young materials. Their conclusion of multiple and protracted eruptions at Ubehebe Crater cluster is here modified through the understanding that some of their quartz-bearing clasts inherited 10Be from previous exposure on the fan surface (too old), and that other clasts were only exposed at the surface by wind and/or water erosion centuries after their eruption (too young). Ubehebe Crater cluster is a well preserved example of young monogenetic maar type volcanism protected within a National Park, and it represents neither a protracted eruption sequence as previously thought, nor a continuing volcanic hazard near its location.

  1. Discovery of chemical oscillatory layering in adarce from Rehai, Tengchong, Yunnan and its genetic mechanism

    International Nuclear Information System (INIS)

    Wang Jianghai; Dong Jinquan

    1994-01-01

    Based on characteristics of mineral assemblages and compositions of sinter in several typical region, Western Yunnan, it is recognized that rhythmic compositional layering is widespread in sinter. According to self-organization theory and fluid dynamic experiments completed by predecessors, the authors have studied dynamic features of fluids in thermo-chamber; and concluded that in which double-diffusive convection layering would imperatively take place on the basis of estimation of dynamic parameters and determination of differences between RT and R0. Finally, a two-stage genetic model has been put forward for explaining the rhythmic layering in sinter, i.e. :1) double-diffusive convection of fluid in chambers was induced by the gradients of temperature and concentration; and 2) the rising of layered fluids and the precipitation of the chemical material occurred. Obviously, rhythmic layering in sinter is a typical self-organizational phenomenon

  2. Interdisciplinary rehabilitation of patients with chronic widespread pain:

    DEFF Research Database (Denmark)

    Amris, Kirstine; Wæhrens, Eva E; Christensen, Robin

    2014-01-01

    This study examined the functional and psychological outcomes of a 2-week, group-based multicomponent treatment course that targeted patients with chronic widespread pain. Patients (192 included in the intention-to-treat population), all fulfilling the 1990 American College of Rheumatology...

  3. Tephrostratigraphy the DEEP site record, Lake Ohrid

    Science.gov (United States)

    Leicher, N.; Zanchetta, G.; Sulpizio, R.; Giaccio, B.; Wagner, B.; Francke, A.

    2016-12-01

    In the central Mediterranean region, tephrostratigraphy has been proofed to be a suitable and powerful tool for dating and correlating marine and terrestrial records. However, for the period older 200 ka, tephrostratigraphy is incomplete and restricted to some Italian continental basins (e.g. Sulmona, Acerno, Mercure), and continuous records downwind of the Italian volcanoes are rare. Lake Ohrid (Macedonia/Albania) in the eastern Mediterranean region fits this requisite and is assumed to be the oldest continuously existing lake of Europe. A continous record (DEEP) was recovered within the scope of the ICDP deep-drilling campaign SCOPSCO (Scientific Collaboration on Past Speciation Conditions in Lake Ohrid). In the uppermost 450 meters of the record, covering more than 1.2 Myrs of Italian volcanism, 54 tephra layers were identified during core-opening and description. A first tephrostratigraphic record was established for the uppermost 248 m ( 637 ka). Major element analyses (EDS/WDS) were carried out on juvenile glass fragments and 15 out of 35 tephra layers have been identified and correlated with known and dated eruptions of Italian volcanoes. Existing 40Ar/39Ar ages were re-calculated by using the same flux standard and used as first order tie points to develop a robust chronology for the DEEP site succession. Between 248 and 450 m of the DEEP site record, another 19 tephra horizons were identified and are subject of ongoing work. These deposits, once correlated with known and dated tephra, will hopefully enable dating this part of the succession, likely supported by major paleomagnetic events, such as the Brunhes-Matuyama boundary, or the Cobb-Mountain or the Jaramillo excursions. This makes the Lake Ohrid record a unique continuous, distal record of Italian volcanic activity, which is candidate to become the template for the central Mediterranean tephrostratigraphy, especially for the hitherto poorly known and explored lower Middle Pleistocene period.

  4. Intra-arterial cis-diamminedichloroplatinum infusion treatment for widespread hepatocellular carcinoma

    International Nuclear Information System (INIS)

    Park, Sung Il; Yang, Hee Chul; Lee, Do Yon; Shim, Yong Woon; Kim, Sang Heum; Kim, Myeong Jin; Lee, Jong Tae; Yoo, Hyung Sik

    1997-01-01

    The purpose of this study is to evaluate the therapeutic efficacy of intra-arterial infusion of Cis-diamminedichloroplatinum (C-DDP) for the treatment of hepatocellular carcinomas with widespread involvement. We retrospectively analyzed 22 patients who between July 1994 and June 1996 had undergone intra-arterial c-DDP infusion therapy for the treatment of hepatocellular carcinomas with widespread involvement. The hepatomas involved both lobes in ten, portal venous obstructions in fourteen, arterio-portal shunts in nine, and arterio-venous shunts in two. Proper hepatic artery was selected for infusion of 100 mg/BSA of C-DDP. The same procedure was repeated every 3 to 4 weeks, and the total number of infusions was 65. On the basis of WHO criteria, response was classified as complete remission, partial remission, stable, or progression of the disease. Six-month and one-year survival rates were estimated, and adverse reactions were evaluated. Although the response rate is not high, intra-arterial C-DDP infusion therapy can be used as an alternative treatment for hepatocellular carcinomas with widespread involvement; adverse reactions are tolerable. (author). 16 refs., 3 figs

  5. isoenzyme analysis of five endemic and one widespread kniphofia ...

    African Journals Online (AJOL)

    Preferred Customer

    ISOENZYME ANALYSIS OF FIVE ENDEMIC AND ONE WIDESPREAD ... plants. The over all mean inbreeding coefficient (F) was positive indicating slight deficiency in the number of ...... populations, indicates rather recent speciation.

  6. Thinking critically about the occurrence of widespread participation in poor nursing care.

    Science.gov (United States)

    Roberts, Marc; Ion, Robin

    2015-04-01

    A discussion of how Arendt's work can be productively re-contextualized to provide a critical analysis of the occurrence of widespread participation in poor nursing care and what the implications of this are for the providers of nursing education. While the recent participation of nurses in healthcare failings, such as that detailed in the Francis report, has been universally condemned, there has been an absence of critical analyses in the literature that attempt to understand the occurrence of such widespread participation in poor nursing care. This is a significant omission in so far as such analyses will form an integral part of the strategy to limit the occurrence of such widespread participation of nurses in future healthcare failings. Discussion paper. Arendt's 'Eichmann in Jerusalem: A Report on the Banality of Evil' and 'Thinking and Moral Considerations: A Lecture'. In addition, a literature search was conducted and articles published in English relating to the terms care, compassion, ethics, judgement and thinking between 2004-2014 were included. It is anticipated that this discussion will stimulate further critical debate about the role of Arendt's work for an understanding of the occurrence of poor nursing care, and encouraging additional detailed analyses of the widespread participation of nurses in healthcare failings more generally. This article provides a challenging analysis of the widespread participation of nurses in poor care and discusses the opportunities confronting the providers of nursing education in limiting future healthcare failings. © 2014 John Wiley & Sons Ltd.

  7. Geological Evidences for a Large Tsunami Generated by the 7.3 ka Kikai Caldera Eruption, Southern Japan

    Science.gov (United States)

    Yamada, M.; Fujino, S.; Satake, K.

    2017-12-01

    The 7.3 ka eruption of Kikai volcano, southern Kyushu, Japan, is one of the largest caldera-forming eruption in the world. Given that a huge caldera was formed in shallow sea area during the eruption, a tsunami must have been generated by a sea-level change associated. Pyroclastic flow and tsunami deposits by the eruption have been studied around the caldera, but they are not enough to evaluate the tsunami size. The goal of this study is to unravel sizes of tsunami and triggering caldera collapse by numerical simulations based on a widely-distributed tsunami deposit associated with the eruption. In this presentation, we will provide an initial data on distribution of the 7.3 ka tsunami deposit contained in sediment cores taken at three coastal lowlands in Wakayama, Tokushima, and Oita prefectures (560 km, 520 km, and 310 km north-east from the caldera, respectively). A volcanic ash from the eruption (Kikai Akahoya tephra: K-Ah) is evident in organic-rich muddy sedimentary sequence in all sediment cores. Up to 6-cm-thick sand layer, characterized by a grading structure and sharp bed boundary with lower mud, is observed immediately beneath the K-Ah tephra in all study sites. These sedimentary characteristics and broad distribution indicate that the sand layer was most likely deposited by a tsunami which can propagate to a wide area, but not by a local storm surge. Furthermore, the stratigraphic relationship implies that the study sites must have been inundated by the tsunami prior to the ash fall. A sand layer is also evident within the K-Ah tephra layer, suggesting that the sand layer was probably formed by a subsequent tsunami wave during the ash fall. These geological evidences for the 7.3 ka tsunami inundation will contribute to a better understanding of the caldera collapse and the resultant tsunami, but also of the tsunami generating system in the eruptive process.

  8. Ultraviolet vision may be widespread in bats

    Science.gov (United States)

    Gorresen, P. Marcos; Cryan, Paul; Dalton, David C.; Wolf, Sandy; Bonaccorso, Frank

    2015-01-01

    Insectivorous bats are well known for their abilities to find and pursue flying insect prey at close range using echolocation, but they also rely heavily on vision. For example, at night bats use vision to orient across landscapes, avoid large obstacles, and locate roosts. Although lacking sharp visual acuity, the eyes of bats evolved to function at very low levels of illumination. Recent evidence based on genetics, immunohistochemistry, and laboratory behavioral trials indicated that many bats can see ultraviolet light (UV), at least at illumination levels similar to or brighter than those before twilight. Despite this growing evidence for potentially widespread UV vision in bats, the prevalence of UV vision among bats remains unknown and has not been studied outside of the laboratory. We used a Y-maze to test whether wild-caught bats could see reflected UV light and whether such UV vision functions at the dim lighting conditions typically experienced by night-flying bats. Seven insectivorous species of bats, representing five genera and three families, showed a statistically significant ‘escape-toward-the-light’ behavior when placed in the Y-maze. Our results provide compelling evidence of widespread dim-light UV vision in bats.

  9. Intelligence in childhood and chronic widespread pain in middle age: the National Child Development Survey.

    Science.gov (United States)

    Gale, Catharine R; Deary, Ian J; Cooper, Cyrus; Batty, G David

    2012-12-01

    Psychological factors are thought to play a part in the aetiology of chronic widespread pain. We investigated the relationship between intelligence in childhood and risk of chronic widespread pain in adulthood in 6902 men and women from the National Child Development Survey (1958 British Birth Cohort). Participants took a test of general cognitive ability at age 11 years; and chronic widespread pain, defined according to the American College of Rheumatology criteria, was assessed at age 45 years. Risk ratios (RRs) and 95% confidence intervals (CIs) were estimated using log-binomial regression, adjusting for sex and potential confounding or mediating factors. Risk of chronic widespread pain, defined according to the American College of Rheumatology criteria, rose in a stepwise fashion as intelligence fell (P for linear trend intelligence quotient, the RR of chronic widespread pain was 1.26 (95% CI 1.17-1.35). In multivariate backwards stepwise regression, lower childhood intelligence remained as an independent predictor of chronic widespread pain (RR 1.10; 95% CI 1.01-1.19), along with social class, educational attainment, body mass index, smoking status, and psychological distress. Part of the effect of lower childhood intelligence on risk of chronic widespread pain in midlife was significantly mediated through greater body mass index and more disadvantaged socioeconomic position. Men and women with higher intelligence in childhood are less likely as adults to report chronic widespread pain. Copyright © 2012 International Association for the Study of Pain. Published by Elsevier B.V. All rights reserved.

  10. Tephrostratigraphic studies on a sediment core from Lake Prespa in the Balkans

    Directory of Open Access Journals (Sweden)

    M. Damaschke

    2013-01-01

    Full Text Available A detailed tephrostratigraphic record, which dates back to Marine Isotope Stage (MIS 5b (ca. 91 kyr, has been established from a 17.76 m long core (Co1215 from Lake Prespa (Macedonia, Albania and Greece. A total of eleven tephra and cryptotephra layers (PT0915-1 to PT0915-11 were identified, using XRF scanning, magnetic susceptibility measurements, and macro- and microscopic inspection of the sediments. The major element composition of glass shards and/or micro-pumice fragments indicates that the tephras and cryptotephras originate from the explosive volcanism of Italy. Eight tephra and cryptotephra layers were correlated with specific volcanic eruptions: the AD 512 eruption of Somma-Vesuvius (1438 cal yr BP, the Mercato eruption of Somma-Vesuvius (8890 ± 90 cal yr BP, the Tufi Biancastri/LN1-LN2 eruption of the Campi Flegrei (14 749 ± 523 cal yr BP and 15 551 ± 621 cal yr BP, the SMP1-e/Y-3 eruption of the Campi Flegrei (30 000–31 000 cal yr BP, the Campanian Ignimbrite/Y-5 eruption of the Campi Flegrei (39 280 ± 110 cal yr BP, the SMP1-a event of Ischia Island (around 44 000 cal yr BP and the Green Tuff/Y-6 eruption of Pantelleria Island (around 45 000 cal yr BP. One tephra could be attributed to the volcanic activity of Mount Etna, but probably represents an unknown eruption at ca. 60 000 cal yr BP. Cryptotephras PT0915-6 and PT0915-10 remain unclassified so far, but according to the presented age-depth model these would have been deposited around 35 000 and 48 500 cal yr BP, respectively. Some of the tephras and cryptotephras are recognised for the first time in the Balkan region. The tephrostratigraphic work provides important information about ash dispersal and explosion patterns of source volcanoes and can be used to correlate and date geographically distant paleoenvironmental and archaeological archives in the central Mediterranean region. Moreover, the tephrostratigraphic work in combination with radiocarbon and electron spin

  11. New insight on the Toba volcano super eruption (Sumatra Island, Indonesia) from BAR-9425 core.

    Science.gov (United States)

    Caron, B.; del Manzo, G.; Moreno, E.; Annachiara, B.; Baudin, F.; Bassinot, F. C.; Villemant, B.

    2017-12-01

    The famous 73 ka Toba eruption has produced about 2800 km3 of magma and is considered as one of the largest known eruptions during the Quaternary (Rose and Chesner, 1990). The BAR-9425 piston core collected during the 1994 joint French-Indonesian BARAT Cruise in the north Sumatra Island has recorded the volcano history of Toba from 60 to 100 ka (including the 73 ka Young Toba Tuff (YTT)). Tephra layers within this sediment core have been systematically studied using a combined analysis including stable isotope (δ18O, van der Kaars et al., 2012), high resolution tephrostratigraphic, morphological and a major-trace element studies. Our preliminary results show that not only one major eruption occurred between 60 and 100 ka but probably 11 distinct eruptions occurred. The 11 eruptions display an homogeneous major element composition. The oldest tephra with an estimated age of 101 ka, have a rhyolitic composition and 30% of relative abundance of volcanic glass shards. The other eruptive phases are dated at: 91,5-89,2 ka with a maximum of 16% of volcanic tephra; 85,7-84,8 ka with 64%; 81,8 ka with 22%; 74,4 ka with 43%, 72,3 ka with 89%, 71,4 ka with 92%; 68,9% with 96%; 66,5 ka with 94%; 65,2 ka with 75% and 63,1-60,3 ka with a maximum of 96% of volcanic tephra respectively (ages were calculated with a constant sediment rate of 4,3 cm/ka from data from van der Kaars et al., 2012). Some of these eruptions have had direct effect on regional vegetation as suggested by Van der Kaars et al. (2012) who propose that the gradual expansion of pine cover for the 7000 years following the eruption, is a consequence of the ash deposit from the 89 ka eruption. Our detailed tephrostratigraphy study of Toba eruptions will help to understand the impact on the ecosystems of northern Sumatra and on global climate change. Moreover, we expect to correlate the new tephra layers of Toba volcano to other sites by using AL-ICP-MS traces analyses and to use it as chronological makers.

  12. Lateglacial and holocene tephrostratigraphy in Denmark

    DEFF Research Database (Denmark)

    Larsen, Jeppe Joel

    the Eyjafjallajökull 2010 eruption. The observations of the Hässeldalen Tephra and Fosen Tephra expand the previously known depositional extent of these two tephra horizons. At Hallegård on Bornholm a distinct horizon of Laacher See-like tephra is registered c. 60 cm below the Laacher See Tephra. The tephra, here...

  13. Microwave Photonics: current challenges towards widespread application.

    Science.gov (United States)

    Capmany, José; Li, Guifang; Lim, Christina; Yao, Jianping

    2013-09-23

    Microwave Photonics, a symbiotic field of research that brings together the worlds of optics and radio frequency is currently facing several challenges in its transition from a niche to a truly widespread technology essential to support the ever-increasing values for speed, bandwidth, processing capability and dynamic range that will be required in next generation hybrid access networks. We outline these challenges, which are the subject of the contributions to this focus issue.

  14. Widespread plant species: natives vs. aliens in our changing world

    Science.gov (United States)

    Stohlgren, Thomas J.; Pyšek, Petr; Kartesz, John; Nishino, Misako; Pauchard, Aníbal; Winter, Marten; Pino, Joan; Richardson, David M.; Wilson, John R.U.; Murray, Brad R.; Phillips, Megan L.; Ming-yang, Li; Celesti-Grapow, Laura; Font, Xavier

    2011-01-01

    Estimates of the level of invasion for a region are traditionally based on relative numbers of native and alien species. However, alien species differ dramatically in the size of their invasive ranges. Here we present the first study to quantify the level of invasion for several regions of the world in terms of the most widely distributed plant species (natives vs. aliens). Aliens accounted for 51.3% of the 120 most widely distributed plant species in North America, 43.3% in New South Wales (Australia), 34.2% in Chile, 29.7% in Argentina, and 22.5% in the Republic of South Africa. However, Europe had only 1% of alien species among the most widespread species of the flora. Across regions, alien species relative to native species were either as well-distributed (10 comparisons) or more widely distributed (5 comparisons). These striking patterns highlight the profound contribution that widespread invasive alien plants make to floristic dominance patterns across different regions. Many of the most widespread species are alien plants, and, in particular, Europe and Asia appear as major contributors to the homogenization of the floras in the Americas. We recommend that spatial extent of invasion should be explicitly incorporated in assessments of invasibility, globalization, and risk assessments.

  15. Widespread plant species: Natives versus aliens in our changing world

    Science.gov (United States)

    Stohlgren, T.J.; Pysek, P.; Kartesz, J.; Nishino, M.; Pauchard, A.; Winter, M.; Pino, J.; Richardson, D.M.; Wilson, J.R.U.; Murray, B.R.; Phillips, M.L.; Ming-yang, L.; Celesti-Grapow, L.; Font, X.

    2011-01-01

    Estimates of the level of invasion for a region are traditionally based on relative numbers of native and alien species. However, alien species differ dramatically in the size of their invasive ranges. Here we present the first study to quantify the level of invasion for several regions of the world in terms of the most widely distributed plant species (natives vs. aliens). Aliens accounted for 51.3% of the 120 most widely distributed plant species in North America, 43.3% in New South Wales (Australia), 34.2% in Chile, 29.7% in Argentina, and 22.5% in the Republic of South Africa. However, Europe had only 1% of alien species among the most widespread species of the flora. Across regions, alien species relative to native species were either as well-distributed (10 comparisons) or more widely distributed (5 comparisons). These striking patterns highlight the profound contribution that widespread invasive alien plants make to floristic dominance patterns across different regions. Many of the most widespread species are alien plants, and, in particular, Europe and Asia appear as major contributors to the homogenization of the floras in the Americas. We recommend that spatial extent of invasion should be explicitly incorporated in assessments of invasibility, globalization, and risk assessments. ?? 2011 Springer Science+Business Media B.V.

  16. The Campanian Ignimbrite Eruption: New Data on Volcanic Ash Dispersal and Its Potential Impact on Human Evolution

    Science.gov (United States)

    Fitzsimmons, Kathryn E.; Hambach, Ulrich; Veres, Daniel; Iovita, Radu

    2013-01-01

    The Campanian Ignimbrite (CI) volcanic eruption was the most explosive in Europe in the last 200,000 years. The event coincided with the onset of an extremely cold climatic phase known as Heinrich Event 4 (HE4) approximately 40,000 years ago. Their combined effect may have exacerbated the severity of the climate through positive feedbacks across Europe and possibly globally. The CI event is of particular interest not only to investigate the role of volcanism on climate forcing and palaeoenvironments, but also because its timing coincides with the arrival into Europe of anatomically modern humans, the demise of Neanderthals, and an associated major shift in lithic technology. At this stage, however, the degree of interaction between these factors is poorly known, based on fragmentary and widely dispersed data points. In this study we provide important new data from Eastern Europe which indicate that the magnitude of the CI eruption and impact of associated distal ash (tephra) deposits may have been substantially greater than existing models suggest. The scale of the eruption is modelled by tephra distribution and thickness, supported by local data points. CI ashfall extends as far as the Russian Plain, Eastern Mediterranean and northern Africa. However, modelling input is limited by very few data points in Eastern Europe. Here we investigate an unexpectedly thick CI tephra deposit in the southeast Romanian loess steppe, positively identified using geochemical and geochronological analyses. We establish the tephra as a widespread primary deposit, which blanketed the topography both thickly and rapidly, with potentially catastrophic impacts on local ecosystems. Our discovery not only highlights the need to reassess models for the magnitude of the eruption and its role in climatic transition, but also suggests that it may have substantially influenced hominin population and subsistence dynamics in a region strategic for human migration into Europe. PMID:23799050

  17. Reanalyzing Head et al. (2015): investigating the robustness of widespread p-hacking.

    Science.gov (United States)

    Hartgerink, Chris H J

    2017-01-01

    Head et al. (2015) provided a large collection of p -values that, from their perspective, indicates widespread statistical significance seeking (i.e., p -hacking). This paper inspects this result for robustness. Theoretically, the p -value distribution should be a smooth, decreasing function, but the distribution of reported p -values shows systematically more reported p -values for .01, .02, .03, .04, and .05 than p -values reported to three decimal places, due to apparent tendencies to round p -values to two decimal places. Head et al. (2015) correctly argue that an aggregate p -value distribution could show a bump below .05 when left-skew p -hacking occurs frequently. Moreover, the elimination of p  = .045 and p  = .05, as done in the original paper, is debatable. Given that eliminating p  = .045 is a result of the need for symmetric bins and systematically more p -values are reported to two decimal places than to three decimal places, I did not exclude p  = .045 and p  = .05. I conducted Fisher's method .04 hacking remains when we look at the entire range between .04 hacking is widespread. Given the far-reaching implications of supposed widespread p -hacking throughout the sciences Head et al. (2015), it is important that these findings are robust to data analysis choices if the conclusion is to be considered unequivocal. Although no evidence of widespread left-skew p -hacking is found in this reanalysis, this does not mean that there is no p -hacking at all. These results nuance the conclusion by Head et al. (2015), indicating that the results are not robust and that the evidence for widespread left-skew p -hacking is ambiguous at best.

  18. Infrequent widespread microsatellite instability in hepatocellular carcinomas.

    Science.gov (United States)

    Yamamoto, H; Itoh, F; Fukushima, H; Kaneto, H; Sasaki, S; Ohmura, T; Satoh, T; Karino, Y; Endo, T; Toyota, J; Imai, K

    2000-03-01

    Widespread or high-frequency microsatellite instability (MSI) due to the defective DNA mismatch repair (MMR) occurs in the majority of hereditary non-polyposis colorectal cancer and a subset of sporadic malignant tumors. The incidence of MSI and underlying DNA MMR defects have been well characterized in gastrointestinal carcinogenesis, but not in hepatocarcinogenesis. To address the issue, we analyzed 55 Japanese hepatocellular carcinomas using several indicators of DNA MMR defects, such as microsatellite analysis, loss of heterozygosity (LOH) and mutation analysis of MMR genes, methylation of hMLH1 promoter, and frameshift mutations of mononucleotide repeat sequences within possible target genes. Mutation of beta2-microglobulin gene, which is presumably involved in MSI-positive tumor cell escape from immune surveillance was also examined. Some of these analyses were also carried out in 9 human liver cancer cell lines. None of the 3 quasi-monomorphic mononucleotide markers sensitive for MSI, BAT26, BAT25, and BAT34C4 presented shortened unstable alleles in any of the carcinoma, cirrhosis, chronic hepatitis tissues, or cell lines. LOH at MMR genes was infrequent (4.4 approximately 7.1%), and no mutations were detected. Neither hMLH1 hypermethylation nor frameshift mutation in the target genes was detected. No mutations were found in beta2-microglobulin. Widespread MSI due to the defective DNA MMR appears to play little if any part in Japanese hepatocarcinogenesis.

  19. Seven climatic cycles in New Zealand during the last half-million years

    International Nuclear Information System (INIS)

    Te Punga, M.T.

    1984-01-01

    At Upper Hutt, New Zealand (Lat. 41 deg 07' S) there is a sequence of seven loess/soil pairs that represents seven climatic cycles spanning the last half-million years (Fig. 1). Each loess layer accumulated in a dry, cool, possibly periglacial environment with an average temperature about 4 deg C to 6 deg C lower than at present. The five oldest soils (paleosols) are red and each was probably formed in a seasonally humid climate with a hot dry period, with a mean annual temperature above 15.5 deg C and an annual rainfall of more than 1000 mm. Although the present soil and the youngest paleosol are not red at Upper Hutt both are strongly coloured. The sequence, known to be of Brunhes age, is divided by the Mangaroa Ash (340,000 yr B.P.), the Mt Curl Tephra (230,000 yr B.P.) and the Aokautere Ash (Kawakawa Tephra) (20,600 yr B.P.). Correlation with the delta oxygen isotope stages of deep-sea cores indicates that the Aokautere Ash was deposited in ''glacial'' stage 2, the Mt Curl Tephra in ''interglacial'' stage 7,l and the Mangaroa Ash probably near the beginning of ''interglacial'' stage 9. The oldest loess layer is correlated with ''glacial'' stage 14 that began 517,000 years ago; the younger six loess layers are assigned to ''glacical'' stages 12, 10, 8, 6, 4 and 2 respectively, and the six paleosols are assigned to ''interglacial'' stages 13, 11, 9, 7, 5 and 3; the present day soil is assigned to ''interglacial'' stage 1 (Fig. 1). The seven cyclic climatic changes recorded in the Upper Hutt sequence apparently indicate a response to cyclic changes in the earth's orbital parameters and the alternating climatic regime at Wellington supports the suggestion that cyclic climatic changes have been globally synchronous for the past 500,000 years

  20. Air-quality implications of widespread adoption of cool roofs on ozone and particulate matter in southern California

    Science.gov (United States)

    Ban-Weiss, G. A.; Lee, S. M.; Katzenstein, A. S.; Carreras-Sospedra, M.; Zhang, X.; Farina, S.; Vahmani, P.; Fine, P.; Epstein, S. A.

    2017-12-01

    The installation of roofing materials with increased solar reflectance (i.e., "cool roofs") can mitigate the urban heat island effect and reduce energy use. In addition, meteorological changes, along with the possibility of enhanced UV reflection from these surfaces, can have complex impacts on ozone and PM2.5 concentrations. We aim to evaluate the air-quality impacts of widespread cool-roof installations prescribed by building energy efficiency standards within the heavily populated and polluted South Coast Air Basin (SoCAB) in Southern California. Development of a comprehensive rooftop area database and evaluation of spectral reflectance measurements of roofing materials allows us to predict potential future changes in solar and UV reflectance for simulations using the Weather Research Forecast and Community Multiscale Air Quality (CMAQ) models. Meteorological simulations indicate a decrease in daily maximum temperatures, daily maximum boundary layer heights, and ventilation coefficients throughout the SoCAB upon widespread installation of cool roofs. CMAQ simulations show significant increases in PM2.5 concentrations and policy-relevant design values. Changes in 8-h ozone concentrations depend on the potential change in UV reflectance, ranging from a decrease in population-weighted concentrations when UV reflectance remains unchanged to an increase when changes in UV reflectance are at an upper bound. However, 8-h policy-relevant ozone design values increase in all cases. Although the other benefits of cool roofs could outweigh small air-quality penalties, UV reflectance standards for cool roofing materials could mitigate these negative consequences. Results of this study motivate the careful consideration of future rooftop and pavement solar reflectance modification policies.

  1. New Layered Materials and Functional Nanoelectronic Devices

    Science.gov (United States)

    Yu, Jaeeun

    This thesis introduces functional nanomaterials including superatoms and carbon nanotubes (CNTs) for new layered solids and molecular devices. Chapters 1-3 present how we incorporate superatoms into two-dimensional (2D) materials. Chapter 1 describes a new and simple approach to dope transition metal dichalcogenides (TMDCs) using the superatom Co6Se8(PEt3)6 as the electron dopant. Doping is an effective method to modulate the electrical properties of materials, and we demonstrate an electron-rich cluster can be used as a tunable and controllable surface dopant for semiconducting TMDCs via charge transfer. As a demonstration of the concept, we make a p-n junction by patterning on specific areas of TMDC films. Chapter 2 and Chapter 3 introduce new 2D materials by molecular design of superatoms. Traditional atomic van der Waals materials such as graphene, hexagonal boron-nitride, and TMDCs have received widespread attention due to the wealth of unusual physical and chemical behaviors that arise when charges, spins, and vibrations are confined to a plane. Though not as widespread as their atomic counterparts, molecule-based layered solids offer significant benefits; their structural flexibility will enable the development of materials with tunable properties. Chapter 2 describes a layered van der Waals solid self-assembled from a structure-directing building block and C60 fullerene. The resulting crystalline solid contains a corrugated monolayer of neutral fullerenes and can be mechanically exfoliated. Chapter 3 describes a new method to functionalize electroactive superatoms with groups that can direct their assembly into covalent and non-covalent multi-dimensional frameworks. We synthesized Co6Se8[PEt2(4-C6H4COOH)]6 and found that it forms two types of crystalline assemblies with Zn(NO3)2, one is a three-dimensional solid and the other consists of stacked layers of two-dimensional sheets. The dimensionality is controlled by subtle changes in reaction conditions. CNT

  2. Hematite Spherules in Basaltic Tephra Altered Under Aqueous, Acid-Sulfate Conditions on Mauna Kea Volcano, Hawaii: Possible Clues for the Occurrence of Hematite-Rich Spherules in the Burns Formation at Meridiani Planum, Mars

    Science.gov (United States)

    Morris, R. V.; Ming, D. W.; Graff, T. G.; Arvidson, R. E.; Bell, J. F., III; Squyres, S. W.; Mertzman, S. A.; Gruener, J. E.; Golden, D. C.; Robinson, G. A.

    2005-01-01

    Iron-rich spherules (>90% Fe2O3 from electron microprobe analyses) approx.10-100 microns in diameter are found within sulfate-rich rocks formed by aqueous, acid-sulfate alteration of basaltic tephra on Mauna Kea volcano, Hawaii. Although some spherules are nearly pure Fe, most have two concentric compositional zones, with the core having a higher Fe/Al ratio than the rim. Oxide totals less than 100% (93-99%) suggest structural H2O and/or /OH. The transmission Moessbauer spectrum of a spherule-rich separate is dominated by a hematite (alpha-Fe2O3) sextet whose peaks are skewed toward zero velocity. Skewing is consistent with Al(3+) for Fe(3+) substitution and structural H2O and/or /OH. The grey color of the spherules implies specular hematite. Whole-rock powder X-ray diffraction spectra are dominated by peaks from smectite and the hydroxy sulfate mineral natroalunite as alteration products and plagioclase feldspar that was present in the precursor basaltic tephra. Whether spherule formation proceeded directly from basaltic material in one event (dissolution of basaltic material and precipitation of hematite spherules) or whether spherule formation required more than one event (formation of Fe-bearing sulfate rock and subsequent hydrolysis to hematite) is not currently constrained. By analogy, a formation pathway for the hematite spherules in sulfate-rich outcrops at Meridiani Planum on Mars (the Burns formation) is aqueous alteration of basaltic precursor material under acid-sulfate conditions. Although hydrothermal conditions are present on Mauna Kea, such conditions may not be required for spherule formation on Mars if the time interval for hydrolysis at lower temperatures is sufficiently long.

  3. Internet-of-Things – A Layered Model for Business Environment

    Directory of Open Access Journals (Sweden)

    Logica BANICA

    2017-12-01

    Full Text Available The new concept of Internet of Things (IoT will increase the pace of globalization in business, overcoming spatial and temporal barriers, language and economic development. But, as any new concept emerged, it still has no widespread functional models and standards and, moreover, companies are not ready to accept all the changes proposed by IoT in the business environment. In this paper, as a case study, we propose an IoT model, based on collaboration between Fog/Edge and Cloud Computing, for developing a business in distribution and retail domain, with a multi-stores and multi-warehouses structures. The entire system is monitored by a hierarchical synchronization model, having the master clock server placed in the Cloud layer, and then, in subordinate relation, to the next level, the Fog/Edge layer, from which start signals simultaneously to the servers in the warehouses and to stores.

  4. Late Pleistocene to Holocene tephrostratigraphy of the Lonquimay Volcano, South Central Chile

    Science.gov (United States)

    Gilbert, D.; Freundt, A.; Kutterolf, S.; Burkert, C.

    2010-12-01

    The Lonquimay Volcanic Complex (LVC) in South Central Chile (38.38°S, 71.58°W) is part of the Southern Volcanic Zone of the Andes, which formed in response to the subduction of the Nazca Plate beneath the South American Plate. During the course of its magmatic evolution, the LVC produced explosive eruptions documented in the succession of widespread tephra deposits, as well as large lava flows that originated from the main edifice and several adjacent minor eruptive centers. The last eruptive phase in Lonquimays volcanic evolution occurred from 1988-1990. It led to the formation of the Navidad cinder cone with its associated 10.2 km long lava flow, and a widely distributed tephra blanket of andesitic composition (Moreno and Gardeweg, 1989). During recent field work we reinvestigated and complemented the LVC tephrostratigraphy as originally established by Polanco (1998)by detailed logging of 22 outcrops and collecting 126 stratigraphically controlled samples that were analyzed for their matrix glass, mineral and bulk rock compositions. This data set allows us to verify and extend the field-based correlations, and to establish a tephrostratigraphy for the LVC that comprises 15 stratigraphic units (LQA-LQO) and provides a framework for ongoing investigations of the petrogenetic evolution of the LVC. The stratigraphic record identifies at least 13 explosive eruptions of VEI > 3 that occurred since the last glaciation period (17150 a BP, McCulloch et al. 2000). Magmatic compositions of the tephra deposits range from basaltic scoriae (51wt% SiO2) to evolved dacitic pumice lapilli layers (67wt% SiO2), and thus have a wider compositional range than the chemically distinct andesitic lavas (57-63wt%) of the LVC. The vertical succession of tephra compositions reflects four periods of progressive magmatic differentiation, each successively tapped by several eruptions. The maximum degree of fractionation reached during these periods increases to younger ages. The

  5. A quantitative x-ray diffraction inventory of volcaniclastic inputs into the marine sediment archives off Iceland: a contribution to the Volcanoes in the Arctic System programme

    Directory of Open Access Journals (Sweden)

    Dennis D. Eberl

    2013-02-01

    Full Text Available This paper re-evaluates how well quantitative x-ray diffraction (qXRD can be used as an exploratory method of the weight percentage (wt% of volcaniclastic sediment, and to identify tephra events in marine cores. In the widely used RockJock v6 software programme, qXRD tephra and glass standards include the rhyodacite White River tephra (Alaska, a rhyolitic tephra (Hekla-4 and the basaltic Saksunarvatn tephra. Experiments of adding known wt% of tephra to felsic bedrock samples indicated that additions ≥10 wt% are accurately detected, but reliable estimates of lesser amounts are masked by amorphous material produced by milling. Volcaniclastic inputs range between 20 and 50 wt%. Primary tephra events are identified as peaks in residual qXRD glass wt% from fourth-order polynomial fits. In cores where tephras have been identified by shard counts in the >150 µm fraction, there is a positive correlation (validation with peaks in the wt% glass estimated by qXRD. Geochemistry of tephra shards confirms the presence of several Hekla-sourced tephras in cores B997-317PC1 and -319PC2 on the northern Iceland shelf. In core B997-338 (north-west Iceland, there are two rhyolitic tephras separated by ca. 100 cm with uncorrected radiocarbon dates on articulated shells of around 13 000 yr B.P. These tephras may be correlatives of the Borrobol and Penifiler tephras found in Scotland. The number of Holocene tephra events per 1000 yr was estimated from qXRD on 16 cores and showed a bimodal distribution with an increased number of events in both the late and early Holocene.

  6. A widespread allergic reaction to black tattoo ink caused by laser treatment.

    Science.gov (United States)

    Bernstein, Eric F

    2015-02-01

    This is the first reported case of a local and widespread reaction in a 39 year old woman, to black tattoo ink, induced by Q-switched laser treatment. A 39 year old woman was treated with the Q-switched Nd:YAG laser for removal of a decorative tattoo of her lower back. Subsequent to laser treatment, a severe, widespread allergic reaction developed within and surrounding the treated tattoo. Tattoo reactions subsequent to laser treatment should be considered in addition to reactions to topical antibiotics or wound dressings, following laser treatment of tattoos. © 2015 Wiley Periodicals, Inc.

  7. Subjects with Knee Osteoarthritis Exhibit Widespread Hyperalgesia to Pressure and Cold.

    Directory of Open Access Journals (Sweden)

    Penny Moss

    Full Text Available Hyperalgesia to mechanical and thermal stimuli are characteristics of a range of disorders such as tennis elbow, whiplash and fibromyalgia. This study evaluated the presence of local and widespread mechanical and thermal hyperalgesia in individuals with knee osteoarthritis, compared to healthy control subjects. Twenty-three subjects with knee osteoarthritis and 23 healthy controls, matched for age, gender and body mass index, were recruited for the study. Volunteers with any additional chronic pain conditions were excluded. Pain thresholds to pressure, cold and heat were tested at the knee, ipsilateral heel and ipsilateral elbow, in randomized order, using standardised methodology. Significant between-groups differences for pressure pain and cold pain thresholds were found with osteoarthritic subjects demonstrating significantly increased sensitivity to both pressure (p = .018 and cold (p = .003 stimuli, compared with controls. A similar pattern of results extended to the pain-free ipsilateral ankle and elbow indicating widespread pressure and cold hyperalgesia. No significant differences were found between groups for heat pain threshold, although correlations showed that subjects with greater sensitivity to pressure pain were also likely to be more sensitive to both cold pain and heat pain. This study found widespread elevated pain thresholds in subjects with painful knee osteoarthritis, suggesting that altered nociceptive system processing may play a role in ongoing arthritic pain for some patients.

  8. Climate change and forest fires synergistically drive widespread melt events of the Greenland Ice Sheet.

    Science.gov (United States)

    Keegan, Kaitlin M; Albert, Mary R; McConnell, Joseph R; Baker, Ian

    2014-06-03

    In July 2012, over 97% of the Greenland Ice Sheet experienced surface melt, the first widespread melt during the era of satellite remote sensing. Analysis of six Greenland shallow firn cores from the dry snow region confirms that the most recent prior widespread melt occurred in 1889. A firn core from the center of the ice sheet demonstrated that exceptionally warm temperatures combined with black carbon sediments from Northern Hemisphere forest fires reduced albedo below a critical threshold in the dry snow region, and caused the melting events in both 1889 and 2012. We use these data to project the frequency of widespread melt into the year 2100. Since Arctic temperatures and the frequency of forest fires are both expected to rise with climate change, our results suggest that widespread melt events on the Greenland Ice Sheet may begin to occur almost annually by the end of century. These events are likely to alter the surface mass balance of the ice sheet, leaving the surface susceptible to further melting.

  9. Widespread Wolbachia infection in terrestrial isopods and other crustaceans

    Directory of Open Access Journals (Sweden)

    Richard Cordaux

    2012-03-01

    Full Text Available Wolbachia bacteria are obligate intracellular alpha-Proteobacteria of arthropods and nematodes. Although widespread among isopod crustaceans, they have seldom been found in non-isopod crustacean species. Here, we report Wolbachia infection in fourteen new crustacean species. Our results extend the range of Wolbachia infections in terrestrial isopods and amphipods (class Malacostraca. We report the occurrence of two different Wolbachia strains in two host species (a terrestrial isopod and an amphipod. Moreover, the discovery of Wolbachia in the goose barnacle Lepas anatifera (subclass Thecostraca establishes Wolbachia infection in class Maxillopoda. The new bacterial strains are closely related to B-supergroup Wolbachia strains previously reported from crustacean hosts. Our results suggest that Wolbachia infection may be much more widespread in crustaceans than previously thought. The presence of related Wolbachia strains in highly divergent crustacean hosts suggests that Wolbachia endosymbionts can naturally adapt to a wide range of crustacean hosts. Given the ability of isopod Wolbachia strains to induce feminization of genetic males or cytoplasmic incompatibility, we speculate that manipulation of crustacean-borne Wolbachia bacteria might represent potential tools for controlling crustacean species of commercial interest and crustacean or insect disease vectors.

  10. Comparative phylogeography of two widespread magpies

    DEFF Research Database (Denmark)

    Zhang, Ruiying; Song, Gang; Qu, Yanhua

    2012-01-01

    Historical geological events and climatic changes are believed to have played important roles in shaping the current distribution of species. However, sympatric species may have responded in different ways to such climatic fluctuations. Here we compared genetic structures of two corvid species......, the Azure-winged Magpie Cyanopica cyanus and the Eurasian Magpie Pica pica, both widespread but with different habitat dependence and some aspects of breeding behavior. Three mitochondrial genes and two nuclear introns were used to examine their co-distributed populations in East China and the Iberian...... Peninsula. Both species showed deep divergences between these two regions that were dated to the late Pliocene/early Pleistocene. In the East Chinese clade of C. cyanus, populations were subdivided between Northeast China and Central China, probably since the early to mid-Pleistocene, and the Central...

  11. Vitamin D inadequacy is widespread in Tunisian active boys and is ...

    African Journals Online (AJOL)

    Vitamin D inadequacy is widespread in Tunisian active boys and is related to diet but not to adiposity or insulin resistance. Ikram Bezrati, Mohamed Kacem Ben Fradj, Nejmeddine Ouerghi, Moncef Feki, Anis Chaouachi, Naziha Kaabachi ...

  12. Ages of tuff beds at East African early hominid sites and sediments in the Gulf of Aden

    Science.gov (United States)

    Sarna-Wojcicki, A. M.; Meyer, C.E.; Roth, P.H.; Brown, F.H.

    1985-01-01

    The early hominids of East Africa were dated by determining the ages of tuff beds at the sites. Despite much research using palaeomagnetic and K/Ar-dating techniques, some of those ages are still controversial 1,2. To obtain independent age estimates for these tephra layers, we have examined cores from DSDP Sites 231 and 232 in the Gulf of Aden (Fig. 1a) which consist mainly of calcareous nannofossil ooze, but also contain rare tephra horizons3 dated by interpolation from the established nannofossil stratigraphy (Fig. 1b). Chemical analysis confirms that the identity and sequence of these horizons is the same as that at the East African sites. We conclude that the age of the Tulu Bor Tuff is <3.4 Myr and hence that the Hadar hominid specimens are also

  13. Prevalence of widespread pain and associations with work status: a population study

    Directory of Open Access Journals (Sweden)

    Henriksson KG

    2008-07-01

    Full Text Available Abstract Background This population study based on a representative sample from a Swedish county investigates the prevalence, duration, and determinants of widespread pain (WSP in the population using two constructs and estimates how WSP affects work status. In addition, this study investigates the prevalence of widespread pain and its relationship to pain intensity, gender, age, income, work status, citizenship, civil status, urban residence, and health care seeking. Methods A cross-sectional survey using a postal questionnaire was sent to a representative sample (n = 9952 of the target population (284,073 people, 18–74 years in a county (Östergötland in the southern Sweden. The questionnaire was mailed and followed by two postal reminders when necessary. Results The participation rate was 76.7% (n = 7637; the non-participants were on the average younger, earned less money, and male. Women had higher prevalences of pain in 10 different predetermined anatomical regions. WSP was generally chronic (90–94% and depending on definition of WSP the prevalence varied between 4.8–7.4% in the population. Women had significantly higher prevalence of WSP than men and the age effect appeared to be stronger in women than in men. WSP was a significant negative factor – together with age 50–64 years, low annual income, and non-Nordic citizen – for work status in the community and in the group with chronic pain. Chronic pain but not the spreading of pain was related to health care seeking in the population. Conclusion This study confirms earlier studies that report high prevalences of widespread pain in the population and especially among females and with increasing age. Widespread pain is associated with prominent effects on work status.

  14. The origin of widespread species in a poor dispersing lineage (diving beetle genus Deronectes

    Directory of Open Access Journals (Sweden)

    David García-Vázquez

    2016-09-01

    Full Text Available In most lineages, most species have restricted geographic ranges, with only few reaching widespread distributions. How these widespread species reached their current ranges is an intriguing biogeographic and evolutionary question, especially in groups known to be poor dispersers. We reconstructed the biogeographic and temporal origin of the widespread species in a lineage with particularly poor dispersal capabilities, the diving beetle genus Deronectes (Dytiscidae. Most of the ca. 60 described species of Deronectes have narrow ranges in the Mediterranean area, with only four species with widespread European distributions. We sequenced four mitochondrial and two nuclear genes of 297 specimens of 109 different populations covering the entire distribution of the four lineages of Deronectes, including widespread species. Using Bayesian probabilities with an a priori evolutionary rate, we performed (1 a global phylogeny/phylogeography to estimate the relationships of the main lineages within each group and root them, and (2 demographic analyses of the best population coalescent model for each species group, including a reconstruction of the geographical history estimated from the distribution of the sampled localities. We also selected 56 specimens to test for the presence of Wolbachia, a maternally transmitted parasite that can alter the patterns of mtDNA variability. All species of the four studied groups originated in the southern Mediterranean peninsulas and were estimated to be of Pleistocene origin. In three of the four widespread species, the central and northern European populations were nested within those in the northern areas of the Anatolian, Balkan and Iberian peninsulas respectively, suggesting a range expansion at the edge of the southern refugia. In the Mediterranean peninsulas the widespread European species were replaced by vicariant taxa of recent origin. The fourth species (D. moestus was proven to be a composite of unrecognised

  15. Correlation and stratigraphic eruption age of the pyroclastic flow deposits and wide spread volcanic ashes intercalated in the Pliocene-Pleistocene strata, central Japan

    International Nuclear Information System (INIS)

    Nagahashi, Yoshitaka; Satoguchi, Yasufumi; Yoshikawa, Shusaku

    2000-01-01

    Three pyroclastic flow deposits in the Takayama and Omine area, central Honshu, are correlated to the distal widespread volcanic ashes intercalated in the Plio-Pleistocene boundary strata in central Japan. The correlation is based on these stratigraphic relationships, facies, magnetostratigraphy, petrographic properties such as mineral assemblage, refractive index and chemical composition of the volcanic glasses and orthopyroxene. As the result of these correlation, the eruption age of the proximal pyroclastic flow deposits have become clear. And precise correlation between proximal eruption units and distal depositional units is now possible. Ho-Kd 39 Tephra erupted at about 1.76 Ma, forming a co-ignimbrite ash, which deposited in the Kanto sedimentary basin. Eb-Fukuda Tephra erupted at about 1.75 Ma, and distal volcaniclastic deposit sedimented in the Kinki, Niigata and Kanto sedimentary basins. The eruptional and depositional phase are divided into the stage 1, stage 2 (early), stage 2 (late) and stage 3. Stage 1 is phreato-plinian type eruption phase, forming distal ash fall deposit. Stage 2 (early) is plinian pumice fall, intra-plinian pyroclastic flow and plinian pumice fall eruption phase, forming distal ash fall. Stage 2 (late) is final eruptional phase of the biggest pyroclastic flow of the Eb-Fukuda Tephra, forming a co-ignimbrite ash fall. Stage 3 is resedimented stage after the end of the explosive eruption. It is notable that resedimented volcaniclastic deposit reached Osaka sedimentary basin 300 km away from the eruption center. Om-SK110 Tephra erupted at about 1.65 Ma, divided into the stage 1, stage 2 and stage 3. Stage 1 is eruption phase of the plinian pumice fall and first pyroclastic flow. Stage 2 is pauses in eruption activity. Stage 3 is second pyroclastic flow phase, it is inferred that the pyroclastic flow of the stage 3 directly entered the Niigata sedimentary basin and simultaneously formed a co-ignimbrite ash. (author)

  16. Historical and paleo-tsunami deposits on Kamchatka, Russia: long-term chronologies and long-distance correlations

    Directory of Open Access Journals (Sweden)

    T. K. Pinegina

    2001-01-01

    Full Text Available Along the eastern coast of Kamchatka, at a number of localities, we have identified and attempted to assign ages to deposits of both historic and prehistoric (paleo- tsunamis. These deposits are dated and correlated using tephrochronology from Holocene marker tephra and local volcanic ash layers. Because the historical record of earthquakes and tsunamis on Kamchatka is so short, these investigations can make important contributions to evaluating tsunami hazards. Moreover, because even the historical record is spotty, our work helps add to and evaluate tsunami catalogues for Kamchatka. Furthermore, tsunami deposits provide a proxy record for large earthquakes and thus are important paleoseismological tools. The combined, preserved record of tsunami deposits and of numerous marker tephra on Kamchatka offers an unprecedented opportunity to study tsunami frequency. Using combined stratigraphic sections, we can examine both the average frequency of events for each locality, and also changes in frequency through time. Moreover, using key marker tephra as time lines, we can compare tsunami frequency and intensity records along the Kamchatka subduction zone. Preliminary results suggest real variations in frequency on a millennial time scale, with the period from about 0 to 1000 A.D. being particularly active at some localities.

  17. Widespread decline of Congo rainforest greenness in the past decade.

    Science.gov (United States)

    Zhou, Liming; Tian, Yuhong; Myneni, Ranga B; Ciais, Philippe; Saatchi, Sassan; Liu, Yi Y; Piao, Shilong; Chen, Haishan; Vermote, Eric F; Song, Conghe; Hwang, Taehee

    2014-05-01

    Tropical forests are global epicentres of biodiversity and important modulators of climate change, and are mainly constrained by rainfall patterns. The severe short-term droughts that occurred recently in Amazonia have drawn attention to the vulnerability of tropical forests to climatic disturbances. The central African rainforests, the second-largest on Earth, have experienced a long-term drying trend whose impacts on vegetation dynamics remain mostly unknown because in situ observations are very limited. The Congolese forest, with its drier conditions and higher percentage of semi-evergreen trees, may be more tolerant to short-term rainfall reduction than are wetter tropical forests, but for a long-term drought there may be critical thresholds of water availability below which higher-biomass, closed-canopy forests transition to more open, lower-biomass forests. Here we present observational evidence for a widespread decline in forest greenness over the past decade based on analyses of satellite data (optical, thermal, microwave and gravity) from several independent sensors over the Congo basin. This decline in vegetation greenness, particularly in the northern Congolese forest, is generally consistent with decreases in rainfall, terrestrial water storage, water content in aboveground woody and leaf biomass, and the canopy backscatter anomaly caused by changes in structure and moisture in upper forest layers. It is also consistent with increases in photosynthetically active radiation and land surface temperature. These multiple lines of evidence indicate that this large-scale vegetation browning, or loss of photosynthetic capacity, may be partially attributable to the long-term drying trend. Our results suggest that a continued gradual decline of photosynthetic capacity and moisture content driven by the persistent drying trend could alter the composition and structure of the Congolese forest to favour the spread of drought-tolerant species.

  18. Reanalyzing Head et al. (2015: investigating the robustness of widespread p-hacking

    Directory of Open Access Journals (Sweden)

    Chris H.J. Hartgerink

    2017-03-01

    Full Text Available Head et al. (2015 provided a large collection of p-values that, from their perspective, indicates widespread statistical significance seeking (i.e., p-hacking. This paper inspects this result for robustness. Theoretically, the p-value distribution should be a smooth, decreasing function, but the distribution of reported p-values shows systematically more reported p-values for .01, .02, .03, .04, and .05 than p-values reported to three decimal places, due to apparent tendencies to round p-values to two decimal places. Head et al. (2015 correctly argue that an aggregate p-value distribution could show a bump below .05 when left-skew p-hacking occurs frequently. Moreover, the elimination of p = .045 and p = .05, as done in the original paper, is debatable. Given that eliminating p = .045 is a result of the need for symmetric bins and systematically more p-values are reported to two decimal places than to three decimal places, I did not exclude p = .045 and p = .05. I conducted Fisher’s method .04 < p < .05 and reanalyzed the data by adjusting the bin selection to .03875 < p ≤ .04 versus .04875 < p ≤ .05. Results of the reanalysis indicate that no evidence for left-skew p-hacking remains when we look at the entire range between .04 < p < .05 or when we inspect the second-decimal. Taking into account reporting tendencies when selecting the bins to compare is especially important because this dataset does not allow for the recalculation of the p-values. Moreover, inspecting the bins that include two-decimal reported p-values potentially increases sensitivity if strategic rounding down of p-values as a form of p-hacking is widespread. Given the far-reaching implications of supposed widespread p-hacking throughout the sciences Head et al. (2015, it is important that these findings are robust to data analysis choices if the conclusion is to be considered unequivocal. Although no evidence of widespread left-skew p

  19. The relative frequencies of causes of widespread ground-glass opacity: A retrospective cohort

    International Nuclear Information System (INIS)

    Hewitt, Michael G.; Miller, Wallace T.; Reilly, Thomas J.; Simpson, Scott

    2014-01-01

    Highlights: • The most common cause of widespread ground-glass opacities is hydrostatic pulmonary edema. • Associated findings such as air-trapping and centrilobular nodules are highly specific for hypersensitivity pneumonitis. • The clinical setting (outpatient versus inpatient) will alter the order of the differential diagnosis. - Abstract: Purpose: The purpose of our study was to determine the relative frequencies of causes of widespread ground-glass opacity (GGO) in an unselected, consecutive patient population and to identify any associated imaging findings that can narrow or reorganize the differential. Materials and methods: The study was approved by the center's IRB and is HIPPA compliant. Cases with widespread GGO in the radiology report were identified by searching the Radiology Information System. Medical records and CT scan examinations were reviewed for the causes of widespread GGO. Associations between a less dominant imaging finding and a particular diagnosis were analyzed with the chi square test. Our study group consisted of 234 examinations with 124 women and 110 men and a mean age of 53.7 years. Results: A cause was established in 204 (87.2%) cases. Hydrostatic pulmonary edema was most common with 131 cases (56%). Interstitial lung diseases (ILD) were the next most common, most often hypersensitivity pneumonitis (HP) (n = 12, 5%) and connective tissue disease related ILD (n = 7, 3%). Infection accounted for 5% (12 cases). A few miscellaneous diseases accounted for 5 cases (2.1%). The combination of septal thickening and pleural effusions had a specificity of 0.91 for hydrostatic pulmonary edema (P < .001) while centrilobular nodules and air trapping had a specificity of 1.0 for HP. In 24 (10.2%) patients, increased opacification from expiration was incorrectly interpreted as representing widespread ground glass opacity. The relative frequency of disease dramatically changed according to the setting. In the inpatient setting, diffuse

  20. The relative frequencies of causes of widespread ground-glass opacity: A retrospective cohort

    Energy Technology Data Exchange (ETDEWEB)

    Hewitt, Michael G., E-mail: Mike_hewitt@me.com; Miller, Wallace T., E-mail: Wallace.miller@uphs.upenn.edu; Reilly, Thomas J., E-mail: thomasjreilly@comcast.net; Simpson, Scott, E-mail: Simpson80@gmail.com

    2014-10-15

    Highlights: • The most common cause of widespread ground-glass opacities is hydrostatic pulmonary edema. • Associated findings such as air-trapping and centrilobular nodules are highly specific for hypersensitivity pneumonitis. • The clinical setting (outpatient versus inpatient) will alter the order of the differential diagnosis. - Abstract: Purpose: The purpose of our study was to determine the relative frequencies of causes of widespread ground-glass opacity (GGO) in an unselected, consecutive patient population and to identify any associated imaging findings that can narrow or reorganize the differential. Materials and methods: The study was approved by the center's IRB and is HIPPA compliant. Cases with widespread GGO in the radiology report were identified by searching the Radiology Information System. Medical records and CT scan examinations were reviewed for the causes of widespread GGO. Associations between a less dominant imaging finding and a particular diagnosis were analyzed with the chi square test. Our study group consisted of 234 examinations with 124 women and 110 men and a mean age of 53.7 years. Results: A cause was established in 204 (87.2%) cases. Hydrostatic pulmonary edema was most common with 131 cases (56%). Interstitial lung diseases (ILD) were the next most common, most often hypersensitivity pneumonitis (HP) (n = 12, 5%) and connective tissue disease related ILD (n = 7, 3%). Infection accounted for 5% (12 cases). A few miscellaneous diseases accounted for 5 cases (2.1%). The combination of septal thickening and pleural effusions had a specificity of 0.91 for hydrostatic pulmonary edema (P < .001) while centrilobular nodules and air trapping had a specificity of 1.0 for HP. In 24 (10.2%) patients, increased opacification from expiration was incorrectly interpreted as representing widespread ground glass opacity. The relative frequency of disease dramatically changed according to the setting. In the inpatient setting, diffuse

  1. International arrivals: widespread bioinvasions in European Seas.

    Science.gov (United States)

    Galil, B S; Marchini, A; Occhipinti-Ambrogi, A; Minchin, D; Narščius, A; Ojaveer, H; Olenin, S

    2014-04-01

    The European Union lacks a comprehensive framework to address the threats posed by the introduction and spread of marine non-indigenous species (NIS). Current efforts are fragmented and suffer substantial gaps in coverage. In this paper we identify and discuss issues relating to the assessment of spatial and temporal patterns of introductions in European Seas (ES), based on a scientifically validated information system of aquatic non-indigenous and cryptogenic species, AquaNIS. While recognizing the limitations of the existing data, we extract information that can be used to assess the relative risk of introductions for different taxonomic groups, geographic regions and likely vectors. The dataset comprises 879 multicellular NIS. We applied a country-based approach to assess patterns of NIS richness in ES, and identify the principal introduction routes and vectors, the most widespread NIS and their spatial and temporal spread patterns. Between 1970 and 2013, the number of recorded NIS has grown by 86, 173 and 204% in the Baltic, Western European margin and the Mediterranean, respectively; 52 of the 879 NIS were recorded in 10 or more countries, and 25 NIS first recorded in European seas since 1990 have since been reported in five or more countries. Our results highlight the ever-rising role of shipping (commercial and recreational) as a vector for the widespread and recently spread NIS. The Suez Canal, a corridor unique to the Mediterranean, is responsible for the increased introduction of new thermophilic NIS into this warming sea. The 2020 goal of the EU Biodiversity Strategy concerning marine Invasive Alien Species may not be fully attainable. The setting of a new target date should be accompanied by scientifically robust, sensible and pragmatic plans to minimize introductions of marine NIS and to study those present.

  2. Added value of second biopsy target in screen-detected widespread suspicious breast calcifications.

    Science.gov (United States)

    Falkner, Nathalie M; Hince, Dana; Porter, Gareth; Dessauvagie, Ben; Jeganathan, Sanjay; Bulsara, Max; Lo, Glen

    2018-06-01

    There is controversy on the optimal work-up of screen-detected widespread breast calcifications: whether to biopsy a single target or multiple targets. This study evaluates agreement between multiple biopsy targets within the same screen-detected widespread (≥25 mm) breast calcification to determine if the second biopsy adds value. Retrospective observational study of women screened in a statewide general population risk breast cancer mammographic screening program from 2009 to 2016. Screening episodes recalled for widespread calcifications where further views indicated biopsy, and two or more separate target areas were sampled within the same lesion were included. Percentage agreement and Cohen's Kappa were calculated. A total of 293317 women were screened during 761124 separate episodes with recalls for widespread calcifications in 2355 episodes. In 171 women, a second target was biopsied within the same lesion. In 149 (86%) cases, the second target biopsy result agreed with the first biopsy (κ = 0.6768). Agreement increased with increasing mammography score (85%, 86% and 92% for score 3, 4 and 5 lesions). Same day multiple biopsied lesions were three times more likely to yield concordant results compared to post-hoc second target biopsy cases. While a single target biopsy is sufficient to discriminate a benign vs. malignant diagnosis in most cases, in 14% there is added value in performing a second target biopsy. Biopsies performed prospectively are more likely to yield concordant results compared to post-hoc second target biopsy cases, suggesting a single prospective biopsy may be sufficient when results are radiological-pathological concordant; discordance still requires repeat sampling. © 2018 The Royal Australian and New Zealand College of Radiologists.

  3. Reanalyzing Head et al. : Investigating the robustness of widespread p-hacking

    NARCIS (Netherlands)

    Hartgerink, C.H.J.

    2017-01-01

    Head et al. (2015) provided a large collection of p-values that, from their perspective, indicates widespread statistical significance seeking (i.e., p-hacking). This paper inspects this result for robustness. Theoretically, the p-value distribution should be a smooth, decreasing function, but the

  4. Prevalence and risk factors of vitamin D deficiency in patients with widespread musculoskeletal pain

    Directory of Open Access Journals (Sweden)

    Muharrem Çidem

    2013-12-01

    Full Text Available Objective: Vitamin D deficiency is a worldwide common health problems. Vitamin D deficiency in adults has been associated with proximal muscle weakness, skeletal mineralization defect, and an increased risk of falling. Patients with vitamin D deficiency commonly complain of widespread pain in the body. The aim of this study was to examine the prevalence and risk factors of 25-hydroxyvitamin D deficiency in patients complaining of widespread musculoskeletal pain. Methods: In this cross-sectional study, 8457 patients with widespread musculoskeletal pain (7772 females, 685 males, aged 46.7 (range 20-100 years were included. Serum 25-hydroxyvitamin D was measured with ELISA method. Patients were classified into two groups: 1 Patients with vitamin D deficiency (20 ng/ml. Results: Prevalence of vitamin D deficiency was found to be 71.7%. A binary logistic regression model showed that low 25(OHVit D level was associated with gender, age and month in which 25(OH hypovitaminosis was determined. The risk of low 25(OH Vit D was found to be 2.15 times higher in female patients and 1.52 times higher on March and 1.55 times higher on April. Conclusion: This study indicates that Vitamin D deficiency should be taken into consideration in patients with widespread musculoskeletal pain, and some precautions such as sunbathe during summer should be recommended patients having risk of vitamin D deficiency. J Clin Exp Invest 2013; 4 (4: 48-491

  5. Diagenesis in tephra-rich sediments from the Lesser Antilles Volcanic Arc: Pore fluid constraints

    Science.gov (United States)

    Murray, Natalie A.; McManus, James; Palmer, Martin R.; Haley, Brian; Manners, Hayley

    2018-05-01

    expected given the high abundance of tephra in these sediments. Part of this carbonate buffering, at this site as well as throughout the region, derives from the fact that the Sr concentration in the non-carbonate fraction is generally low (<200 ppm), whereas the carbonate fraction has Sr concentrations approaching ∼1000 ppm.

  6. Environmental change during the last glacial maximum (c. 25,000-16,500 years BP) at Mt Richmond, Auckland Isthmus, New Zealand

    International Nuclear Information System (INIS)

    Sandiford, A.; Horrocks, M.; Newnham, R.; Ogden, J.; Alloway, B.V.

    2002-01-01

    A 2 m section at the base of Mt Richmond contains a palynological record of the last glacial maximum (LGM) (c. 25,000-c. 16,500 14 C years BP) vegetation of the Auckland Isthmus. Three silicic tephra layers derived from the Taupo Volcanic Centre (Okaia Tephra c. 23,500 14 C years BP, Kawakawa Tephra c. 22,500 14 C years BP) and the Okataina Volcanic Centre (Okareka Tephra c. 18,000 14 C years BP), both centres lying within the Taupo Volcanic Zone, provide the basis of the chronology supported by radiocarbon dates. The pollen diagram is divided into two pollen zones separated by the deposition of a locally derived basaltic ash. From c. 25,000-23,000 14 C years BP the site was initially a eutrophic lake fringed by Leptospermum and Typha, which altered to a Cyperaceae/Leptospermum-dominated swamp. The regional vegetation at the time was beech-dominated forest; canopy conifers were present but formed a minor part of the local forest. From c. 23,000-16,500 14 C years BP regional forest was further restricted to local patches in extensive shrubland/grassland. Temperatures may have been depressed by more than 4-5 degrees C. The eruption of a local volcano dammed the swamp outlet resulting in a return to lacustrine conditions. Local volcanism may have accelerated vegetation change already under way as a result of climate change to cooler conditions. This record provides a view of LGM vegetation of the Auckland Isthmus and a template for earlier cold stages of the Quaternary. (author). 39 refs., 3 figs., 1 tab

  7. Diversity of two widespread Indo-Pacific demosponge species revisited

    OpenAIRE

    Erpenbeck, D.; Aryasari, R.; Benning, S.; Debitus, Cécile; Kaltenbacher, E.; Al-Aidaroos, A. M.; Schupp, P.; Hall, K.; Hooper, J. N. A.; Voigt, O.; de Voogd, N. J.; Worheide, G.

    2017-01-01

    The Indo-Pacific is the world's largest marine biogeographic region, covering the tropical and subtropical waters from the Red Sea in the Western Indian Ocean to the Easter Islands in the Pacific. It is characterized by a vast degree of biogeographic connectivity in particular in its marine realm. So far, usage of molecular tools rejected the presence of cosmopolitan or very widespread sponge species in several cases, supporting hypotheses on a higher level of endemism among marine invertebra...

  8. Chronic widespread pain in spondyloarthritis

    Directory of Open Access Journals (Sweden)

    F. Atzeni

    2014-06-01

    Full Text Available The pain associated with spondyloarthritis (SpA can be intense, persistent and disabling. It frequently has a multifactorial, simultaneously central and peripheral origin, and may be due to currently active inflammation, or joint damage and tissue destruction arising from a previous inflammatory condition. Inflammatory pain symptoms can be reduced by non-steroidal anti-inflammatory drugs, but many patients continue to experience moderate pain due to alterations in the mechanisms that regulate central pain, as in the case of the chronic widespread pain (CWP that characterises fibromyalgia (FM. The importance of distinguishing SpA and FM is underlined by the fact that SpA is currently treated with costly drugs such as tumour necrosis factor (TNF inhibitors, and direct costs are higher in patients with concomitant CWP or FM than in those with FM or SpA alone. Optimal treatment needs to take into account symptoms such as fatigue, mood, sleep, and the overall quality of life, and is based on the use of tricyclic antidepressants or selective serotonin reuptake inhibitors such as fluoxetine, rather than adjustments in the dose of anti-TNF agents or disease-modifying drugs.

  9. INAA of Aegaean pumices for the classification of archaeological findings

    International Nuclear Information System (INIS)

    Peltz, C.; Schmid, P.; Bichler, M.

    1999-01-01

    Instrumental neutron activation analysis (INAA) was used to determine 29 elements in pumice from several volcanic sources (Milos, Nisyros, Yali, Kos and Thera) in the Aegean Sea, Greece, to establish a data basis for the identification of pumice and tephra layers found in archaeological context. The widespread products of the 'Minoan Eruption' of the Thera volcano can now be distinguished clearly from all other sources and will be used to establish a datumline in the Eastern Mediterranean Region in the second millenium B.C. The elements Al, As, Ba, Ca, Ce, Co, Cr, Cs, Dy, Eu, Fe, Hf, K, La, Lu, Mn, Na, Nd, Rb, Sb, Sc, Sm, Ta, Ti, Th, U, V, Yb and Zr were determined in 14 samples from Milos, 25 samples from Nisyros, 7 samples from Kos and 17 samples from Thera. Two cycles of irradiation and four measurement runs were applied. The results were compared and suitable groups, typical for each island, were classified. Due to insufficiently comparable data sets, the criteria for distinguishing the different sources have not been revealed by previous studies. This basic knowledge was used to relate pumice from excavations in Tell-el-Dab'a (Egypt) and Bronze Age Knossos to their specific volcanic origin. (author)

  10. Widespread after-effects of nuclear war

    International Nuclear Information System (INIS)

    Teller, E.

    1984-01-01

    Radioactive fallout and depletion of the ozone layer, once believed catastrophic consequences of nuclear war, are now proved unimportant in comparison to immediate war damage. Today, ''nuclear winter'' is claimed to have apocalyptic effects. Uncertainties in massive smoke production and in meteorological phenomena give reason to doubt this conclusion. (author)

  11. Chronological evidence fails to support claim of an isochronous widespread layer of cosmic impact indicators dated to 12,800 years ago

    Science.gov (United States)

    Meltzer, David J.; Holliday, Vance T.; Cannon, Michael D.; Miller, D. Shane

    2014-05-01

    According to the Younger Dryas Impact Hypothesis (YDIH), ∼12,800 calendar years before present, North America experienced an extraterrestrial impact that triggered the Younger Dryas and devastated human populations and biotic communities on this continent and elsewhere. This supposed event is reportedly marked by multiple impact indicators, but critics have challenged this evidence, and considerable controversy now surrounds the YDIH. Proponents of the YDIH state that a key test of the hypothesis is whether those indicators are isochronous and securely dated to the Younger Dryas onset. They are not. We have examined the age basis of the supposed Younger Dryas boundary layer at the 29 sites and regions in North and South America, Europe, and the Middle East in which proponents report its occurrence. Several of the sites lack any age control, others have radiometric ages that are chronologically irrelevant, nearly a dozen have ages inferred by statistically and chronologically flawed age-depth interpolations, and in several the ages directly on the supposed impact layer are older or younger than ∼12,800 calendar years ago. Only 3 of the 29 sites fall within the temporal window of the YD onset as defined by YDIH proponents. The YDIH fails the critical chronological test of an isochronous event at the YD onset, which, coupled with the many published concerns about the extraterrestrial origin of the purported impact markers, renders the YDIH unsupported. There is no reason or compelling evidence to accept the claim that a cosmic impact occurred ∼12,800 y ago and caused the Younger Dryas.

  12. 500,000 Years of Environmental History in Eastern Anatolia: The PALEOVAN Drilling Project

    Directory of Open Access Journals (Sweden)

    Clemens Glombitza, and Jens Kallmeyer

    2012-09-01

    Full Text Available International Continental Scientific Drilling Program (ICDP drilled a complete succession of the lacustrine sediment sequence deposited during the last ~500,000 years in Lake Van, Eastern Anatolia (Turkey. Based on a detailed seismic site survey, two sites at a water depth of up to 360 m were drilled in summer 2010, and cores were retrieved from sub-lake-floor depths of 140 m (Northern Basin and 220 m (Ahlat Ridge. To obtain a complete sedimentary section, the two sites were multiple-cored in order to investigate the paleoclimate history of a sensitive semi-arid region between theBlack, Caspian, and Mediterranean seas. Further scientific goals of the PALEOVAN project are the reconstruction of earthquake activity, as well as the temporal, spatial, and compositional evolution of volcanism as reflected in the deposition of tephra layers. The sediments host organic matter from different sources and hence composition, which will be unravelled using biomarkers. Pathways for migration of continental and mantle-derived noble gases will be analyzed in pore waters. Preliminary 40Ar/39Ar single crystal dating of tephra layers and pollen analyses suggest that the AhlatRidge record encompasses more than half a million years of paleoclimate and volcanic/geodynamic history, providing the longest continental record in the entire Near East to date.

  13. Preoperative widespread pain sensitization and chronic pain after hip and knee replacement: a cohort analysis

    Science.gov (United States)

    Wylde, Vikki; Sayers, Adrian; Lenguerrand, Erik; Gooberman-Hill, Rachael; Pyke, Mark; Beswick, Andrew D.; Dieppe, Paul; Blom, Ashley W.

    2015-01-01

    Abstract Chronic pain after joint replacement is common, affecting approximately 10% of patients after total hip replacement (THR) and 20% of patients after total knee replacement (TKR). Heightened generalized sensitivity to nociceptive input could be a risk factor for the development of this pain. The primary aim of this study was to investigate whether preoperative widespread pain sensitivity was associated with chronic pain after joint replacement. Data were analyzed from 254 patients receiving THR and 239 patients receiving TKR. Pain was assessed preoperatively and at 12 months after surgery using the Western Ontario and McMaster Universities Osteoarthritis Pain Scale. Preoperative widespread pain sensitivity was assessed through measurement of pressure pain thresholds (PPTs) at the forearm using an algometer. Statistical analysis was conducted using linear regression and linear mixed models, and adjustments were made for confounding variables. In both the THR and TKR cohort, lower PPTs (heightened widespread pain sensitivity) were significantly associated with higher preoperative pain severity. Lower PPTs were also significantly associated with higher pain severity at 12 months after surgery in the THR cohort. However, PPTs were not associated with the change in pain severity from preoperative to 12 months postoperative in either the TKR or THR cohort. These findings suggest that although preoperative widespread pressure pain sensitivity is associated with pain severity before and after joint replacement, it is not a predictor of the amount of pain relief that patients gain from joint replacement surgery, independent of preoperative pain severity. PMID:25599300

  14. Evidence of small-fiber polyneuropathy in unexplained, juvenile-onset, widespread pain syndromes.

    Science.gov (United States)

    Oaklander, Anne Louise; Klein, Max M

    2013-04-01

    We tested the hypothesis that acquired small-fiber polyneuropathy (SFPN), previously uncharacterized in children, contributes to unexplained pediatric widespread pain syndromes. Forty-one consecutive patients evaluated for unexplained widespread pain beginning before age 21 had medical records comprehensively analyzed regarding objective diagnostic testing for SFPN (neurodiagnostic skin biopsy, nerve biopsy, and autonomic function testing), plus histories, symptoms, signs, other tests, and treatments. Healthy, demographically matched volunteers provided normal controls for SFPN tests. Age at illness onset averaged 12.3 ± 5.7 years; 73% among this poly-ethnic sample were female (P = .001). Sixty-eight percent were chronically disabled, and 68% had hospitalizations. Objective testing diagnosed definite SFPN in 59%, probable SFPN in 17%, and possible SFPN in 22%. Only 1 of 41 had entirely normal SFPN test results. Ninety-eight percent of patients had other somatic complaints consistent with SFPN dysautonomia (90% cardiovascular, 82% gastrointestinal, and 34% urologic), 83% reported chronic fatigue, and 63% had chronic headache. Neurologic examinations identified reduced sensation in 68% and vasomotor abnormalities in 55%, including 23% with erythromelalgia. Exhaustive investigations for SFPN causality identified only history of autoimmune illnesses in 33% and serologic markers of disordered immunity in 89%. Treatment with corticosteroids and/or intravenous immune globulin objectively and subjectively benefited 80% of patients (12/15). More than half among a large series of patients with childhood-onset, unexplained chronic widespread pain met rigorous, multitest, diagnostic criteria for SFPN, which extends the age range of acquired SFPN into early childhood. Some cases appeared immune-mediated and improved with immunomodulatory therapies.

  15. Regional pest suppression associated with widespread Bt maize adoption benefits vegetable growers.

    Science.gov (United States)

    Dively, Galen P; Venugopal, P Dilip; Bean, Dick; Whalen, Joanne; Holmstrom, Kristian; Kuhar, Thomas P; Doughty, Hélène B; Patton, Terry; Cissel, William; Hutchison, William D

    2018-03-27

    Transgenic crops containing the bacterium Bacillus thuringiensis (Bt) genes reduce pests and insecticide usage, promote biocontrol services, and economically benefit growers. Area-wide Bt adoption suppresses pests regionally, with declines expanding beyond the planted Bt crops into other non-Bt crop fields. However, the offsite benefits to growers of other crops from such regional suppression remain uncertain. With data spanning 1976-2016, we demonstrate that vegetable growers benefit via decreased crop damage and insecticide applications in relation to pest suppression in the Mid-Atlantic United States. We provide evidence for the regional suppression of Ostrinia nubilalis (Hübner), European corn borer, and Helicoverpa zea (Boddie), corn earworm, populations in association with widespread Bt maize adoption (1996-2016) and decreased economic levels for injury in vegetable crops [peppers ( Capsicum annuum L.), green beans ( Phaseolus vulgaris L.), and sweet corn ( Zea mays L., convar. saccharata )] compared with the pre-Bt period (1976-1995). Moth populations of both species significantly declined in association with widespread Bt maize (field corn) adoption, even as increased temperatures buffered the population reduction. We show marked decreases in the number of recommended insecticidal applications, insecticides applied, and O. nubilalis damage in vegetable crops in association with widespread Bt maize adoption. These offsite benefits to vegetable growers in the agricultural landscape have not been previously documented, and the positive impacts identified here expand on the reported ecological effects of Bt adoption. Our results also underscore the need to account for offsite economic benefits of pest suppression, in addition to the direct economic benefits of Bt crops.

  16. Becker muscular dystrophy with widespread muscle hypertrophy and a non-sense mutation of exon 2

    DEFF Research Database (Denmark)

    Witting, Nanna; Duno, M; Vissing, J

    2013-01-01

    Becker muscular dystrophy features progressive proximal weakness, wasting and often focal hypertrophy. We present a patient with pain and cramps from adolescence. Widespread muscle hypertrophy, preserved muscle strength and a 10-20-fold raised CPK were noted. Muscle biopsy was dystrophic......, and Western blot showed a 95% reduction of dystrophin levels. Genetic analyses revealed a non-sense mutation in exon 2 of the dystrophin gene. This mutation is predicted to result in a Duchenne phenotype, but resulted in a mild Becker muscular dystrophy with widespread muscle hypertrophy. We suggest...

  17. Widespread epigenomic, transcriptomic and proteomic differences between hip osteophytic and articular chondrocytes in osteoarthritis.

    Science.gov (United States)

    Steinberg, Julia; Brooks, Roger A; Southam, Lorraine; Bhatnagar, Sahir; Roumeliotis, Theodoros I; Hatzikotoulas, Konstantinos; Zengini, Eleni; Wilkinson, J Mark; Choudhary, Jyoti S; McCaskie, Andrew W; Zeggini, Eleftheria

    2018-05-08

    To identify molecular differences between chondrocytes from osteophytic and articular cartilage tissue from OA patients. We investigated genes and pathways by combining genome-wide DNA methylation, RNA sequencing and quantitative proteomics in isolated primary chondrocytes from the cartilaginous layer of osteophytes and matched areas of low- and high-grade articular cartilage across nine patients with OA undergoing hip replacement surgery. Chondrocytes from osteophytic cartilage showed widespread differences to low-grade articular cartilage chondrocytes. These differences were similar to, but more pronounced than, differences between chondrocytes from osteophytic and high-grade articular cartilage, and more pronounced than differences between high- and low-grade articular cartilage. We identified 56 genes with significant differences between osteophytic chondrocytes and low-grade articular cartilage chondrocytes on all three omics levels. Several of these genes have known roles in OA, including ALDH1A2 and cartilage oligomeric matrix protein, which have functional genetic variants associated with OA from genome-wide association studies. An integrative gene ontology enrichment analysis showed that differences between osteophytic and low-grade articular cartilage chondrocytes are associated with extracellular matrix organization, skeletal system development, platelet aggregation and regulation of ERK1 and ERK2 cascade. We present a first comprehensive view of the molecular landscape of chondrocytes from osteophytic cartilage as compared with articular cartilage chondrocytes from the same joints in OA. We found robust changes at genes relevant to chondrocyte function, providing insight into biological processes involved in osteophyte development and thus OA progression.

  18. Transient widespread cortical and splenial lesions in acute encephalitis/encephalopathy associated with primary Epstein–Barr virus infection

    Directory of Open Access Journals (Sweden)

    Shuo Zhang

    2016-01-01

    Full Text Available Infection with Epstein–Barr virus (EBV is very common and usually occurs in childhood or early adulthood. Encephalitis/encephalopathy is an uncommon but serious neurological complication of EBV. A case of EBV-associated encephalitis/encephalopathy with involvement of reversible widespread cortical and splenial lesions is presented herein. An 8-year-old Chinese girl who presented with fever and headache, followed by seizures and drowsiness, was admitted to the hospital. Magnetic resonance imaging revealed high signal intensities on diffusion-weighted imaging in widespread cortical and splenial lesions. The clinical and laboratory examination results together with the unusual radiology findings suggested acute encephalitis/encephalopathy due to primary EBV infection. After methylprednisolone pulse therapy together with ganciclovir, the patient made a full recovery without any brain lesions. The hallmark clinical–radiological features of this patient included severe encephalitis/encephalopathy at onset, the prompt and complete recovery, and rapidly reversible widespread involvement of the cortex and splenium. Patients with EBV encephalitis/encephalopathy who have multiple lesions, even with the widespread involvement of cortex and splenium of the corpus callosum, may have a favorable outcome with complete disappearance of all brain lesions.

  19. Widespread Inhibition of Posttranscriptional Splicing Shapes the Cellular Transcriptome following Heat Shock

    Directory of Open Access Journals (Sweden)

    Reut Shalgi

    2014-06-01

    Full Text Available During heat shock and other proteotoxic stresses, cells regulate multiple steps in gene expression in order to globally repress protein synthesis and selectively upregulate stress response proteins. Splicing of several mRNAs is known to be inhibited during heat stress, often meditated by SRp38, but the extent and specificity of this effect have remained unclear. Here, we examined splicing regulation genome-wide during heat shock in mouse fibroblasts. We observed widespread retention of introns in transcripts from ∼1,700 genes, which were enriched for tRNA synthetase, nuclear pore, and spliceosome functions. Transcripts with retained introns were largely nuclear and untranslated. However, a group of 580+ genes biased for oxidation reduction and protein folding functions continued to be efficiently spliced. Interestingly, these unaffected transcripts are mostly cotranscriptionally spliced under both normal and stress conditions, whereas splicing-inhibited transcripts are mostly spliced posttranscriptionally. Altogether, our data demonstrate widespread repression of splicing in the mammalian heat stress response, disproportionately affecting posttranscriptionally spliced genes.

  20. Disposal of radioactive waste into clay layers the most natural option

    International Nuclear Information System (INIS)

    Baetsle, L.H.; Bonne, A.

    1990-01-01

    Among the geological formations suitable for the disposal of radioactive waste, the clay formations provide outstanding opportunities : impermeable for water, self-healing, strongly absorbing for ions, widespread in nature. The self-healing properties of large clay deposits have been demonstrated by their auto-sealing and plastic response to tectonic stress and magmatic intrusion. The discovery of fossil trees preserved after geologic periods of burial in clay is one of the most dramatic illustrations of their entombment ability. The physicochemical and hydrologic characteristics of the Boom clay are very favorable for the confinement of migrating radionuclides within the layer. Except for the extremely long half-lives ( 237 Np, 129 I,...) no radionuclide can escape from the clay body. The effects of heat, metal corrosion, material interaction and biochemical degradation on the natural properties of the clay layer are discussed in some detail and related to the natural properties of the clay formation which have to stay unaltered for geologic periods. The first Safety Assessment Report, established by NIRAS-ONDRAF in close collaboration with SCK-CEN, has been submitted to a multi-disciplinary task force which is to advise the Belgian Government on the suitability of the Boom clay layer below the Nuclear Research site of Mol as a potential host formation for nuclear waste coming from the electronuclear program. 13 refs., 2 figs., 1 tab

  1. Is temporomandibular pain in chronic whiplash-associated disorders part of a more widespread pain syndrome?

    Science.gov (United States)

    Visscher, Corine; Hofman, Nico; Mes, Carola; Lousberg, Richel; Naeije, Machiel

    2005-01-01

    The prevalence of temporomandibular disorders in patients with chronic whiplash-associated disorder is a controversial issue that may be influenced by the widespread pain character and psychologic distress frequently observed in patients with chronic pain. The aim of this study was to determine the prevalence of temporomandibular disorder pain, widespread pain, and psychologic distress in persons with chronic whiplash-associated disorder pain, using a controlled, single blind study design. The prevalence of temporomandibular disorder pain in the chronic whiplash-associated disorder pain group was compared with 2 control groups: a chronic neck pain group and a no neck pain group. From 65 persons, a standardized oral history was taken, a physical examination of the neck and the masticatory system was performed, widespread pain was investigated by tender point palpation, and psychologic distress was measured with a questionnaire (SCL-90). Because the recognition of temporomandibular disorder pain and neck pain remains a matter of debate, 3 well-defined classification systems were used: one based on the oral history, a second on a combination of oral history and pain on active movements and palpation, and a third one based on a combination of oral history and function tests. Irrespective of the classification system used, the chronic whiplash-associated disorder pain group more often suffered from temporomandibular disorder pain (0.001neck pain group. Moreover, patients with whiplash-associated disorder showed more psychologic distress (0.000disorder suggests that the higher prevalence of temporomandibular disorder pain in these patients is part of a more widespread chronic pain disorder.

  2. Multimodal and widespread somatosensory abnormalities in persistent shoulder pain in the first 6 months after stroke: an exploratory study

    NARCIS (Netherlands)

    Roosink, M.; van Dongen, R.T.; Buitenweg, J.R.; Renzenbrink, G.J.; Geurts, A.C.H.; IJzerman, M.J.

    2012-01-01

    Roosink M, Van Dongen RT, Buitenweg JR, Renzenbrink GJ, Geurts AC, IJzerman MJ. Multimodal and widespread somatosensory abnormalities in persistent shoulder pain in the first 6 months after stroke: an exploratory study. OBJECTIVE: To explore the role of multimodal and widespread somatosensory

  3. Layering and Ordering in Electrochemical Double Layers

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Yihua [Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439, United States; Kawaguchi, Tomoya [Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439, United States; Pierce, Michael S. [Rochester Institute of Technology, School of Physics and Astronomy, Rochester, New York 14623, United States; Komanicky, Vladimir [Faculty of Science, Safarik University, 041 54 Kosice, Slovakia; You, Hoydoo [Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439, United States

    2018-02-26

    Electrochemical double layers (EDL) form at electrified interfaces. While Gouy-Chapman model describes moderately charged EDL, formation of Stern layers was predicted for highly charged EDL. Our results provide structural evidence for a Stern layer of cations, at potentials close to hydrogen evolution in alkali fluoride and chloride electrolytes. Layering was observed by x-ray crystal truncation rods and atomic-scale recoil responses of Pt(111) surface layers. Ordering in the layer is confirmed by glancing-incidence in-plane diffraction measurements.

  4. Predictors of outcome of multidisciplinary treatment in chronic widespread pain: an observational study

    NARCIS (Netherlands)

    de Rooij, A.; van der Leeden, M.; Roorda, L.D.; Steultjens, M.P.M.; Dekker, J.

    2013-01-01

    Background: The effectiveness of multidisciplinary treatment in chronic widespread pain (CWP) is limited. The considerable heterogeneity among patients is a likely explanation. Knowledge on predictors of the outcome of multidisciplinary treatment can help to optimize treatment effectiveness. The

  5. The tad locus: postcards from the widespread colonization island.

    Science.gov (United States)

    Tomich, Mladen; Planet, Paul J; Figurski, David H

    2007-05-01

    The Tad (tight adherence) macromolecular transport system, which is present in many bacterial and archaeal species, represents an ancient and major new subtype of type II secretion. The tad genes are present on a genomic island named the widespread colonization island (WCI), and encode the machinery that is required for the assembly of adhesive Flp (fimbrial low-molecular-weight protein) pili. The tad genes are essential for biofilm formation, colonization and pathogenesis in the genera Aggregatibacter (Actinobacillus), Haemophilus, Pasteurella, Pseudomonas, Yersinia, Caulobacter and perhaps others. Here we review the structure, function and evolution of the Tad secretion system.

  6. Patterns of volcanism, weathering, and climate history from high-resolution geochemistry of the BINGO core, Mono Lake, California, USA

    Science.gov (United States)

    Zimmerman, S. R.; Starratt, S.; Hemming, S. R.

    2012-12-01

    Mono Lake, California is a closed-basin lake on the east side of the Sierra Nevada, and inflow from snowmelt dominates the modern hydrology. Changes in wetness during the last glacial period (>12,000 years ago) and over the last 2,000 years have been extensively described, but are poorly known for the intervening period. We have recovered a 6.25 m-long core from ~3 m of water in the western embayment of Mono Lake, which is shown by initial radiocarbon dates to cover at least the last 10,000 years. The sediments of the core are variable, ranging from black to gray silts near the base, laminated olive-green silt through the center, to layers of peach-colored carbonate nodules interbedded with gray and olive silts and pea-green organic ooze. Volcanic tephras from Bodie and Adobe Hills to the north, east, and south. The rhyolitic tephras of the Mono-Inyo Craters are much lower in TiO2 than the bedrock (10,000 calibrated years before present (cal yr BP) higher in the core, and significant disruption of the fine layers, this interval likely indicates a relatively deep lake persisting into the early Holocene, after the initial dramatic regression from late Pleistocene levels. The finely laminated olive-green silt of the period ~10,700 to ~7500 cal yr BP is very homogenous chemically, probably indicating a stable, stratified lake and a relatively wet climate. This section merits mm-scale scanning and petrographic examination in the future. The upper boundary of the laminated section shows rising Ca/K and decreasing Ti and Si/K, marking the appearance of authigenic carbonate layers. After ~7500 cal yr BP, the sediment in BINGO becomes highly variable, with increased occurrence of tephra layers and carbonate, indicating a lower and more variable lake level. A short interval of olive-green, laminated fine sand/silt just above a radiocarbon date of 3870 ± 360 cal yr BP may record the Dechambeau Ranch highstand of Stine (1990; PPP v. 78 pp 333-381), and is marked by a distinct

  7. Was the extreme and wide-spread marine oil-snow sedimentation and flocculent accumulation (MOSSFA) event during the Deepwater Horizon blow-out unique?

    Science.gov (United States)

    Vonk, Sophie M; Hollander, David J; Murk, AlberTinka J

    2015-11-15

    During the Deepwater Horizon blowout, thick layers of oiled material were deposited on the deep seafloor. This large scale benthic concentration of oil is suggested to have occurred via the process of Marine Oil Snow Sedimentation and Flocculent Accumulation (MOSSFA). This meta-analysis investigates whether MOSSFA occurred in other large oil spills and identifies the main drivers of oil sedimentation. MOSSFA was found to have occurred during the IXTOC I blowout and possibly during the Santa Barbara blowout. Unfortunately, benthic effects were not sufficiently studied for the 52 spills we reviewed. However, based on the current understanding of drivers involved, we conclude that MOSSFA and related benthic contamination may be widespread. We suggest to collect and analyze sediment cores at specific spill locations, as improved understanding of the MOSSFA process will allow better informed spill responses in the future, taking into account possible massive oil sedimentation and smothering of (deep) benthic ecosystems. Copyright © 2015 Elsevier Ltd. All rights reserved.

  8. Predicting drought propagation within peat layers using a three dimensionally explicit voxel based model

    Science.gov (United States)

    Condro, A. A.; Pawitan, H.; Risdiyanto, I.

    2018-05-01

    Peatlands are very vulnerable to widespread fires during dry seasons, due to availability of aboveground fuel biomass on the surface and belowground fuel biomass on the sub-surface. Hence, understanding drought propagation occurring within peat layers is crucial with regards to disaster mitigation activities on peatlands. Using a three dimensionally explicit voxel-based model of peatland hydrology, this study predicted drought propagation time lags into sub-surface peat layers after drought events occurrence on the surface of about 1 month during La-Nina and 2.5 months during El-Nino. The study was carried out on a high-conservation-value area of oil palm plantation in West Kalimantan. Validity of the model was evaluated and its applicability for disaster mitigation was discussed. The animations of simulated voxels are available at: goo.gl/HDRMYN (El-Nino 2015 episode) and goo.gl/g1sXPl (La-Nina 2016 episode). The model is available at: goo.gl/RiuMQz.

  9. Multi-Shaped Ag Nanoparticles in the Plasmonic Layer of Dye-Sensitized Solar Cells for Increased Power Conversion Efficiency

    Directory of Open Access Journals (Sweden)

    Da Hyun Song

    2017-06-01

    Full Text Available The use of dye-sensitized solar cells (DSSCs is widespread owing to their high power conversion efficiency (PCE and low cost of manufacturing. We prepared multi-shaped Ag nanoparticles (NPs and introduced them into DSSCs to further enhance their PCE. The maximum absorption wavelength of the multi-shaped Ag NPs is 420 nm, including the shoulder with a full width at half maximum (FWHM of 121 nm. This is a broad absorption wavelength compared to spherical Ag NPs, which have a maximum absorption wavelength of 400 nm without the shoulder of 61 nm FWHM. Therefore, when multi-shaped Ag NPs with a broader plasmon-enhanced absorption were coated on a mesoporous TiO2 layer on a layer-by-layer structure in DSSCs, the PCE increased from 8.44% to 10.22%, equivalent to an improvement of 21.09% compared to DSSCs without a plasmonic layer. To confirm the plasmon-enhanced effect on the composite film structure in DSSCs, the PCE of DSSCs based on the composite film structure with multi-shaped Ag NPs increased from 8.58% to 10.34%, equivalent to an improvement of 20.51% compared to DSSCs without a plasmonic layer. This concept can be applied to perovskite solar cells, hybrid solar cells, and other solar cells devices.

  10. Widespread Usutu virus outbreak in birds in the Netherlands, 2016

    Science.gov (United States)

    Rijks, JM; Kik, ML; Slaterus, R; Foppen, RPB; Stroo, A; IJzer, J; Stahl, J; Gröne, A; Koopmans, MGP; van der Jeugd, HP; Reusken, CBEM

    2016-01-01

    We report a widespread Usutu virus outbreak in birds in the Netherlands. Viral presence had been detected through targeted surveillance as early as April 2016 and increased mortality in common blackbirds and captive great grey owls was noticed from August 2016 onwards. Usutu virus infection was confirmed by post-mortem examination and RT-PCR. Extensive Usutu virus activity in the Netherlands in 2016 underlines the need to monitor mosquito activity and mosquito-borne infections in 2017 and beyond. PMID:27918257

  11. Applying ecological concepts to the management of widespread grass invasions [Chapter 7

    Science.gov (United States)

    Carla M. D' Antonio; Jeanne C. Chambers; Rhonda Loh; J. Tim Tunison

    2009-01-01

    The management of plant invasions has typically focused on the removal of invading populations or control of existing widespread species to unspecified but lower levels. Invasive plant management typically has not involved active restoration of background vegetation to reduce the likelihood of invader reestablishment. Here, we argue that land managers could benefit...

  12. Determination of radiocarbon reservoir age of Lake Van by mineral magnetic and geochemical analysis

    Science.gov (United States)

    Makaroglu, Ozlem; Namik Cagatay, M.; Pesonen, Lauri J.; Orbay, Naci

    2017-04-01

    Lake Van is the largest soda lake in the world, located on the east Anatolian Plateau in Turkey. Its varved sediments provide an excellent archive of high-resolution paleoclimate record for the Near East. Varve counting and radiocarbon methods are therefore important dating techniques for investigating the Lake Van sedimentary paleoclimate record. In here we present detailed magnetic and geochemical record of Lake Van. We have studied 4.56 m (core VP0801) and 4.70 m (core VP0807) long cores recovered from 80 m and 65 m water depths located in SE and SW of Lake Van, respectively. Here, we have benefited from magnetic properties with associated remanent magnetization of the sediments from Lake Van to correlate the cores which contain of tephra layers. The cores cover the last 8.4 ka and lithologically include three laminated sedimentary units. From top to the bottom, the units were dated 4.2 ka BP-present, 5.4-4.2 ka BP and older than 5.4 ka BP. We identified tephra layers previously dated by varve counting, and used the varve ages to obtain age models for the cores. We also obtained a total of eight Accelerator Mass Spectrometry (AMS) 14C dates from total organic carbon (TOC) in the two cores, close to the tephra layers. Comparison of the varve ages of the AMS 14C dated samples with their corresponding AMS 14C dates indicates large differences, suggesting significant reservoir ages that range from 2.8 to 2.5 ka for 3.0-2.4 varve ka BP and from 2.8 to 3.3 ka for 8.0-5.9 varve ka BP. The results suggest that the reservoir age of the organic matter increases with the varve age of the sediments. This increase is mainly related to the rate of supply of "dead" carbon from the old carbonate rocks in the watershed of Lake Van, which was relatively higher during 8.4-5.9 ka than during 3.0-2.4 ka BP because of the higher atmospheric precipitation and higher rate of biochemical weathering during the former period.

  13. Macular Choroidal Small-Vessel Layer, Sattler's Layer and Haller's Layer Thicknesses: The Beijing Eye Study.

    Science.gov (United States)

    Zhao, Jing; Wang, Ya Xing; Zhang, Qi; Wei, Wen Bin; Xu, Liang; Jonas, Jost B

    2018-03-13

    To study macular choroidal layer thickness, 3187 study participants from the population-based Beijing Eye Study underwent spectral-domain optical coherence tomography with enhanced depth imaging for thickness measurements of the macular small-vessel layer, including the choriocapillaris, medium-sized choroidal vessel layer (Sattler's layer) and large choroidal vessel layer (Haller's layer). In multivariate analysis, greater thickness of all three choroidal layers was associated (all P  0.05) associated with the prevalence of open-angle glaucoma or diabetic retinopathy. There was a tendency (0.07 > P > 0.02) toward thinner choroidal layers in chronic angle-closure glaucoma. The ratio of small-vessel layer thickness to total choroidal thickness increased (P layer and Haller's layer thickness to total choroidal thickness decreased. A higher ratio of small-vessel layer thickness to total choroidal thickness was significantly associated with a lower prevalence of AMD (early type, intermediate type, late geographic type). Axial elongation-associated and aging-associated choroidal thinning affected Haller's and Sattler's layers more markedly than the small-vessel layer. Non-exudative and exudative AMD, except for geographic atrophy, was associated with slightly increased choroidal thickness.

  14. Analysis of the Younger Dryas Impact Layer

    Energy Technology Data Exchange (ETDEWEB)

    Firestone, Richard B.; West, Allen; Revay, Zsolt; Hagstrum, Jonathon T,; Belgya, Thomas; Hee, Shane S. Que; Smith, Alan R.

    2010-02-27

    We have uncovered a thin layer of magnetic grains and microspherules, carbon spherules, and glass-like carbon at nine sites across North America, a site in Belgium, and throughout the rims of 16 Carolina Bays. It is consistent with the ejecta layer from an impact event and has been dated to 12.9 ka BP coinciding with the onset of Younger Dryas (YD) cooling and widespread megafaunal extinctions in North America. At many locations the impact layer is directly below a black mat marking the sudden disappearance of the megafauna and Clovis people. The distribution pattern of the Younger Dryas boundary (YDB) ejecta layer is consistent with an impact near the Great Lakes that deposited terrestrial-like ejecta near the impact site and unusual, titanium-rich projectile-like ejecta further away. High water content associated with the ejecta, up to 28 at. percent hydrogen (H), suggests the impact occurred over the Laurentide Ice Sheet. YDB microspherules and magnetic grains are highly enriched in TiO{sub 2}. Magnetic grains from several sites are enriched in iridium (Ir), up to 117 ppb. The TiO{sub 2}/FeO, K/Th, TiO{sub 2}/Zr, Al{sub 2}O{sub 3}/FeO+MgO, CaO/Al{sub 2}O{sub 3}, REE/ chondrite, FeO/MnO ratios and SiO{sub 2}, Na{sub 2}O, K{sub 2}O, Cr{sub 2}O{sub 3}, Ni, Co, U, Th and other trace element abundances are inconsistent with all terrestrial and extraterrestrial (ET) sources except for KREEP, a lunar igneous rock rich in potassium (K), rare-earth elements (REE), phosphorus (P), and other incompatible elements including U and Th. Normal Fe, Ti, and {sup 238}U/{sup 235}U isotopic abundances were found in the magnetic grains, but {sup 234}U was enriched over equilibrium values by 50 percent in Murray Springs and by 130 percent in Belgium. 40K abundance is enriched by up to 100 percent in YDB sediments and Clovis chert artifacts. Highly vesicular carbon spherules containing nanodiamonds, glass-like carbon, charcoal and soot found in large quantities in the YDB layer are

  15. Achieving Widespread, Democratic Education in the United States Today: Dewey's Ideas Reconsidered

    Science.gov (United States)

    Meadows, Elizabeth; Blatchford, Katherine

    2009-01-01

    Excellent, democratic education that furthers each person's potential, success and happiness for her own and others' well-being is not yet widespread in the U.S. today. Dewey's The Public and Its Problems has much to say about the possibilities and challenges of achieving this goal. This paper examines Dewey's ideas about how a public for…

  16. Effects of chronic widespread pain on the health status and quality of life of women after breast cancer surgery

    Directory of Open Access Journals (Sweden)

    Jones Kim D

    2005-04-01

    Full Text Available Abstract Background Most research and treatment of post-breast cancer chronic pain has focused on local or regional pain problems in the operated area. The purpose of this pilot study was to compare and contrast the pain characteristics, symptom impact, health status, and quality of life of post-breast cancer surgery women with regional chronic pain versus those with widespread chronic pain. Methods A cross-sectional, descriptive design compared two groups of women with chronic pain that began after surgery: regional pain (n = 11 and widespread pain (n = 12. Demographics, characteristics of the surgery, as well as standardized questionnaires that measured pain (Brief Pain Inventory (BPI, Short Form McGill Pain Questionnaire (MPQ-SF, disease impact (Fibromyalgia Impact Questionnaire (FIQ, Functional Assessment of Cancer Therapy-Breast (FACT-B, health status (Medical Outcomes Short Form (SF-36 and quality of life (Quality of Life Scale (QOLS were gathered. Results There were no significant differences between the groups on any demographic or type of surgery variable. A majority of both groups described their pain as aching, tender, and sharp on the MPQ-SF. On the BPI, intensity of pain and pain interference were significantly higher in the widespread pain group. Differences between the two groups reached statistical significance on the FIQ total score as well as the FACT-B physical well-being, emotional well-being and breast concerns subscales. The SF-36 physical function, physical role, and body pain subscales were significantly lower in the widespread pain group. QOLS scores were lower in the widespread pain group, but did not reach statistical significance. Conclusion This preliminary work suggests that the women in this study who experienced widespread pain after breast cancer surgery had significantly more severity of pain, pain impact and lower physical health status than those with regional pain.

  17. New Perspectives on Blowing Snow Transport, Sublimation, and Layer Thermodynamic Structure over Antarctica

    Science.gov (United States)

    Palm, Steve; Kayetha, Vinay; Yang, Yuekui; Pauly, Rebecca M.

    2017-01-01

    Blowing snow over Antarctica is a widespread and frequent event. Satellite remote sensing using lidar has shown that blowing snow occurs over 70% of the time over large areas of Antarctica in winter. The transport and sublimation of blowing snow are important terms in the ice sheet mass balance equation and the latter is also an important part of the hydrological cycle. Until now the only way to estimate the magnitude of these processes was through model parameterization. We present a technique that uses direct satellite observations of blowing snow and model (MERRA-2) temperature and humidity fields to compute both transport and sublimation of blowing snow over Antarctica for the period 2006 to 2016. The results show a larger annual continent-wide integrated sublimation than current published estimates and a significant transport of snow from continent to ocean. The talk will also include the lidar backscatter structure of blowing snow layers that often reach heights of 200 to 300 m as well as the first dropsonde measurements of temperature, moisture and wind through blowing snow layers.

  18. Becker muscular dystrophy with widespread muscle hypertrophy and a non-sense mutation of exon 2.

    Science.gov (United States)

    Witting, N; Duno, M; Vissing, J

    2013-01-01

    Becker muscular dystrophy features progressive proximal weakness, wasting and often focal hypertrophy. We present a patient with pain and cramps from adolescence. Widespread muscle hypertrophy, preserved muscle strength and a 10-20-fold raised CPK were noted. Muscle biopsy was dystrophic, and Western blot showed a 95% reduction of dystrophin levels. Genetic analyses revealed a non-sense mutation in exon 2 of the dystrophin gene. This mutation is predicted to result in a Duchenne phenotype, but resulted in a mild Becker muscular dystrophy with widespread muscle hypertrophy. We suggest that this unusual phenotype is caused by translation re-initiation downstream from the mutation site. Copyright © 2012 Elsevier B.V. All rights reserved.

  19. Analysis of the Barriers to Widespread Adoption of Electric Vehicles in Shenzhen China

    Directory of Open Access Journals (Sweden)

    Fa-Ping Wang

    2017-03-01

    Full Text Available China promoted the large-scale adoption of Electric Vehicles (EVs in its 13th five-year plan; however, this target faces many obstacles. This paper analyzes the main barriers to widespread adoption of EVs through a survey in Shenzhen, which has the biggest EVs market share out of China’s major cities. Based on previous research, this paper conducted a new study using 406 approved questionnaires among 500 participants. Our study proposed five hypotheses to examine the main barriers to widespread adoption of EVs. The analysis was conducted using statistical method that included two-way frequency tables, chi-square test, and factor analysis. The results indicated that perception of advantages of EVs and access to recharging EVs remained the main barriers in large-scale penetration. Furthermore, our study revealed that a drop in financial incentives would not cause a significant decline in the future adoption of EVs. The study provides suggestions to car manufacturers and government policy advisors based on our analysis and discussion.

  20. HIV Drug Resistance Surveillance in Honduras after a Decade of Widespread Antiretroviral Therapy.

    Science.gov (United States)

    Avila-Ríos, Santiago; García-Morales, Claudia; Tapia-Trejo, Daniela; Meza, Rita I; Nuñez, Sandra M; Parham, Leda; Flores, Norma A; Valladares, Diana; Pineda, Luisa M; Flores, Dixiana; Motiño, Roxana; Umanzor, Víctor; Carbajal, Candy; Murillo, Wendy; Lorenzana, Ivette; Palou, Elsa Y; Reyes-Terán, Gustavo

    2015-01-01

    We assessed HIV drug resistance (DR) in individuals failing ART (acquired DR, ADR) and in ART-naïve individuals (pre-ART DR, PDR) in Honduras, after 10 years of widespread availability of ART. 365 HIV-infected, ART-naïve, and 381 ART-experienced Honduran individuals were enrolled in 5 reference centres in Tegucigalpa, San Pedro Sula, La Ceiba, and Choluteca between April 2013 and April 2015. Plasma HIV protease-RT sequences were obtained. HIVDR was assessed using the WHO HIVDR mutation list and the Stanford algorithm. Recently infected (RI) individuals were identified using a multi-assay algorithm. PDR to any ARV drug was 11.5% (95% CI 8.4-15.2%). NNRTI PDR prevalence (8.2%) was higher than NRTI (2.2%) and PI (1.9%, p500 vs. Honduras remains at the intermediate level, after 10 years of widespread availability of ART. Evidence of ADR influencing the presence of PDR was observed by phylogenetic analyses and ADR/PDR mutation frequency correlations.

  1. Kosovo : Poverty assessment, Volume 1. Accelerating Inclusive Growth to Reduce Widespread Poverty

    OpenAIRE

    World Bank

    2007-01-01

    Poverty in Kosovo is widespread and has remained persistent in the first half of this decade. The evidence suggests that poverty is higher among those who live in families that are large, have many unemployed members, and have low education levels. The poor are also geographically concentrated in rural areas and a few regions. The main message of this report is that the slow and volatile g...

  2. Barrier layer arrangement for conductive layers on silicon substrates

    International Nuclear Information System (INIS)

    Hung, L.S.; Agostinelli, J.A.

    1990-01-01

    This patent describes a circuit element comprised of a silicon substrate and a conductive layer located on the substrate. It is characterized in that the conductive layer consists essentially of a rare earth alkaline earth copper oxide and a barrier layer triad is interposed between the silicon substrate and the conductive layer comprised of a first triad layer located adjacent the silicon substrate consisting essentially of silica, a third triad layer remote from the silicon substrate consisting essentially of a least one Group 4 heavy metal oxide, and a second triad layer interposed between the first and third triad layers consisting essentially of a mixture of silica and at lease one Group 4 heavy metal oxide

  3. 14C ages for the ejecta from Kutcharo and Mashu calderas, eastern Hokkaido, Japan

    International Nuclear Information System (INIS)

    Yamamoto, Takahiro; Ito, Jun-ichi; Nakagawa, Mitsuhiro; Hasegawa, Takeshi; Kishimoto, Hiroshi

    2010-01-01

    Eruption ages of the ejecta from Kutcharo and Mashu calderas were systematically determined by 14 C dating. 16 charred samples were newly obtained from the Mashu and Nakashumbetsu Tephra Formations around the calderas and dated by AMS and β-counting methods. Examined units are Ma-d, Ma-e, Ma-f, Ma-j, Ma-k, Ma-l and Ml-a in the Mashu ejecta and 6 Nakashumbetsu tephra layers including Kutcharo Pumice Flow Deposit I (KpI), which is the youngest caldera-forming product from Kutcharo caldera. Results of the 14 C dating range from 3,660 ±40 yBP to 36,080±1,300 yBP, and are consistent with the tephrostratigraphy. Calendar age for KpI was newly calculated at almost 40 ka and this age shows there was about 70,000 years recurrence interval between KpI and KpIV caldera-forming eruptions. Mashu caldera has appeared on the eastern part of Kutcharo caldera immediately after the KpI eruption, and calendar age for its main caldera-forming eruption were determined at ca. BC 5,600. (author)

  4. The Effects of Disturbance History on Ground-Layer Plant Community Composition in British Columbia

    Directory of Open Access Journals (Sweden)

    Michael Ton

    2016-05-01

    Full Text Available Plant communities are sensitive to perturbations and may display alternative recovery pathways depending on disturbance history. In sub-boreal lodgepole pine forests of central interior British Columbia, Canada, fire and logging are two widespread landscape disturbances that overlap in many regions. We asked whether cumulative, short-interval disturbance from logging and fire resulted in different ground-layer plant communities than resulted from fire alone. Using field-collected data, we compared the taxonomic composition and functional traits of 3-year old plant communities that were either harvested 6-to-13 years prior, or not harvested prior to being burned in a large stand-replacing fire. The taxonomic composition diverged between the two treatments, driven primarily by differences in a few key indicator species such as Petasites frigidus and Vaccinium membranaceum. Analysis of individual species’ morphological traits indicated that only a few species vary in size in relation to disturbance history. Our data suggest that a history of forest harvest leaves a subtle footprint on post-fire ground-layer plant communities at early stages of succession.

  5. Bilateral widespread mechanical pain hypersensitivity as sign of central sensitization in patients with cluster headache.

    Science.gov (United States)

    Fernández-de-Las-Peñas, César; Ortega-Santiago, Ricardo; Cuadrado, María L; López-de-Silanes, Carlos; Pareja, Juan A

    2011-03-01

    To investigate bilateral widespread pressure pain hyperalgesia in deep tissues over symptomatic (trigemino-cervical) and nonsymptomatic (distant pain-free) regions in patients with cluster headache (CH). Central sensitization is claimed to play a relevant role in CH. No study has previously searched for widespread pressure hyperalgesia in deep tissues over both symptomatic (trigemino-cervical) and nonsymptomatic (distant pain-free) regions in patients with CH. Sixteen men (mean age: 43 ± 11 years) with CH in a remission phase and 16 matched controls were recruited. Pressure pain thresholds (PPTs) were bilaterally measured over the supra-orbital (V1), infra-orbital (V2), mental (V3), median (C5), radial (C6), and ulnar (C7) nerves, C5-C6 zygapophyseal joint, mastoid process, and tibialis anterior muscle by an assessor blinded to the subjects' condition. The results showed that PPT levels were significantly decreased bilaterally in patients with CH as compared with healthy controls (all sites, P < .001). A greater degree of sensitization over the mastoid process (P < .001) and a lower degree of sensitization over the tibialis anterior muscle (P < .01) was found. Our findings revealed bilateral widespread pressure pain hypersensitivity in patients with CH confirming the presence of central sensitization mechanisms in this headache condition. © 2010 American Headache Society.

  6. Hydraulic Stability of Single-Layer Dolos and Accropode Armour Layers

    DEFF Research Database (Denmark)

    Christensen, M.; Burcharth, H. F.

    1995-01-01

    A new design for Dolos breakwater armour layers is presented: Dolos armour units are placed in a selected geometric pattern in a single layer. A series of model tests have been performed in order to determine the stability of such single-layer Dolos armour layers. The test results are presented...... and compared to the stability formula for the traditional double-layer, randomly placed Dolos armour layer design presented by Burcharth (1992). The results of a series of stability tests performed with Accropode® armour layers is presented and compared to the test results obtained with single-layer Dolos...... armour layers. Run-up and reflection are presented for both single-layer Dolos armour and Accropode armour....

  7. Low-temperature atomic layer epitaxy of AlN ultrathin films by layer-by-layer, in-situ atomic layer annealing.

    Science.gov (United States)

    Shih, Huan-Yu; Lee, Wei-Hao; Kao, Wei-Chung; Chuang, Yung-Chuan; Lin, Ray-Ming; Lin, Hsin-Chih; Shiojiri, Makoto; Chen, Miin-Jang

    2017-01-03

    Low-temperature epitaxial growth of AlN ultrathin films was realized by atomic layer deposition (ALD) together with the layer-by-layer, in-situ atomic layer annealing (ALA), instead of a high growth temperature which is needed in conventional epitaxial growth techniques. By applying the ALA with the Ar plasma treatment in each ALD cycle, the AlN thin film was converted dramatically from the amorphous phase to a single-crystalline epitaxial layer, at a low deposition temperature of 300 °C. The energy transferred from plasma not only provides the crystallization energy but also enhances the migration of adatoms and the removal of ligands, which significantly improve the crystallinity of the epitaxial layer. The X-ray diffraction reveals that the full width at half-maximum of the AlN (0002) rocking curve is only 144 arcsec in the AlN ultrathin epilayer with a thickness of only a few tens of nm. The high-resolution transmission electron microscopy also indicates the high-quality single-crystal hexagonal phase of the AlN epitaxial layer on the sapphire substrate. The result opens a window for further extension of the ALD applications from amorphous thin films to the high-quality low-temperature atomic layer epitaxy, which can be exploited in a variety of fields and applications in the near future.

  8. Strontium-89 in palliative treatment of widespread painful bone metastases: Response rate and duration

    International Nuclear Information System (INIS)

    Haddad, Peiman; Ghadiri, Farhad

    2005-01-01

    Full text: Intravenous injection of Strontium-89 (Sr-89) is an accepted palliative treatment for bone metastases. We evaluated the pain relief achieved with this radiopharmaceutical in patients with widespread painful bone metastases from prostate and breast cancers. Pain intensity on a 9-grade scale and use of narcotics was recorded before and after Sr-89 injection, and the ensuing palliative effect was divided into complete, partial and no response. The duration of response was also recorded. Thirty-five patients with widespread painful bone metastases were treated with Sr-89, of whom 22 had prostate and 13 breast cancers. Mean follow-up was 227 days, during which death was recorded for 32 patients. Fourteen patients (40%) had a complete response, 9 (26%) partial and 12 (34%) no response. In the 23 responding patients, mean duration of response was 6 months. In 17 patients the response was present until death. There was no significant relationship between pain response and patients' age or type of primary cancer. No side effects were recorded other than mild and temporary drop in white blood cell and platelet counts. Three patients with a complete response had a second injection of Sr-89 after progression of pain. One of these patients had a second partial response; the other 2 did not show a response to the second injection. The use of Sr-89 for treatment of widespread painful bone metastases from prostate and breast cancers in our department showed a 66% rate of response and a mean response duration of 6 months, with no significant side effects. (author)

  9. Widespread changes in white matter microstructure after a day of waking and sleep deprivation.

    Directory of Open Access Journals (Sweden)

    Torbjørn Elvsåshagen

    Full Text Available Elucidating the neurobiological effects of sleep and waking remains an important goal of the neurosciences. Recently, animal studies indicated that sleep is important for cell membrane and myelin maintenance in the brain and that these structures are particularly susceptible to insufficient sleep. Here, we tested the hypothesis that a day of waking and sleep deprivation would be associated with changes in diffusion tensor imaging (DTI indices of white matter microstructure sensitive to axonal membrane and myelin alterations.Twenty-one healthy adult males underwent DTI in the morning [7:30AM; time point (TP1], after 14 hours of waking (TP2, and then after another 9 hours of waking (TP3. Whole brain voxel-wise analysis was performed with tract based spatial statistics.A day of waking was associated with widespread increases in white matter fractional anisotropy, which were mainly driven by radial diffusivity reductions, and sleep deprivation was associated with widespread fractional anisotropy decreases, which were mainly explained by reductions in axial diffusivity. In addition, larger decreases in axial diffusivity after sleep deprivation were associated with greater sleepiness. All DTI changes remained significant after adjusting for hydration measures.This is the first DTI study of sleep deprivation in humans. Although previous studies have observed localized changes in DTI indices of cerebral microstructure over the course of a few hours, further studies are needed to confirm widespread DTI changes within hours of waking and to clarify whether such changes in white matter microstructure serve as neurobiological substrates of sleepiness.

  10. The significance of volcanic ash in Greenland ice cores during the Common Era

    Science.gov (United States)

    Plunkett, G.; Pilcher, J. R.; McConnell, J. R.; Sigl, M.; Chellman, N.

    2017-12-01

    Volcanic forcing is now widely regarded as a leading natural factor in short-term climate variability. Polar ice cores provide an unrivalled and continuous record of past volcanism through their chemical and particulate content. With an almost annual precision for the Common Era, the ice core volcanic record can be combined with historical data to investigate the climate and social impacts of the eruptions. The sulfate signature in ice cores is critical for determining the possible climate effectiveness of an eruption, but the presence and characterization of volcanic ash (tephra) in the ice is requisite for establishing the source eruption so that location and eruptive style can be better factored in to climate models. Here, we review the Greenland tephra record for the Common Era, and present the results of targeted sampling for tephra of volcanic events that are of interest either because of their suspected climate and societal impacts or because of their potential as isochrons in paleoenvironmental (including ice core) archives. The majority of identifiable tephras derive from Northern Hemisphere mid- to high latitude eruptions, demonstrating the significance of northern extra-tropical volcanic regions as a source of sulfates in Greenland. A number of targets are represented by sparse or no tephra, or shards that cannot be firmly correlated with a source. We consider the challenges faced in isolating and characterizing tephra from low latitude eruptions, and the implications for accurately modelling climate response to large, tropical events. Finally, we compare the ice core tephra record with terrestrial tephrostratigraphies in the circum-North Atlantic area to evaluate the potential for intercontinental tephra linkages and the refinement of volcanic histories.

  11. Total grain-size distribution of four subplinian-Plinian tephras from Hekla volcano, Iceland: Implications for sedimentation dynamics and eruption source parameters

    Science.gov (United States)

    Janebo, Maria H.; Houghton, Bruce F.; Thordarson, Thorvaldur; Bonadonna, Costanza; Carey, Rebecca J.

    2018-05-01

    The size distribution of the population of particles injected into the atmosphere during a volcanic explosive eruption, i.e., the total grain-size distribution (TGSD), can provide important insights into fragmentation efficiency and is a fundamental source parameter for models of tephra dispersal and sedimentation. Recent volcanic crisis (e.g. Eyjafjallajökull 2010, Iceland and Córdon Caulle 2011, Chile) and the ensuing economic losses, highlighted the need for a better constraint of eruption source parameters to be used in real-time forecasting of ash dispersal (e.g., mass eruption rate, plume height, particle features), with a special focus on the scarcity of published TGSD in the scientific literature. Here we present TGSD data associated with Hekla volcano, which has been very active in the last few thousands of years and is located on critical aviation routes. In particular, we have reconstructed the TGSD of the initial subplinian-Plinian phases of four historical eruptions, covering a range of magma composition (andesite to rhyolite), eruption intensity (VEI 4 to 5), and erupted volume (0.2 to 1 km3). All four eruptions have bimodal TGSDs with mass fraction of fine ash (primary fragmentation. Due to differences in plume height, this contrast is not seen in samples from individual sites, especially in the near field, where lapilli have a wider spatial coverage in the Plinian deposits. The distribution of pyroclast sizes in Plinian versus subplinian falls reflects competing influences of more efficient fragmentation (e.g., producing larger amounts of fine ash) versus more efficient particle transport related to higher and more vigorous plumes, displacing relatively coarse lapilli farther down the dispersal axis.

  12. THE WIDESPREAD OF Fe(III)-REDUCING BACTERIA IN NATURAL ECOSYSTEMS OF ECUADOR.

    Science.gov (United States)

    Tashyrev, O B; Govorukha, V M

    2015-01-01

    The widespread of Fe(III)-reducing microorganisms in natural ecosystems of Ecuador of La Favorita, Tungurahua volcano and Papallacta areas was experimentally proved. High efficiency of microbial precipitation of soluble iron compounds was also demonstrated. Obtained results indicate the potential ability of Fe(III)-reducing microorganisms to influence the formation of carbon and iron vector fluxes in ecosystems, as well as development of effective biotechnologies of water purification from iron compounds.

  13. On the occurrence of a widespread contamination by herbicides of coral reef biota in French Polynesia.

    Science.gov (United States)

    Salvat, Bernard; Roche, Hélène; Ramade, François

    2016-01-01

    Research has been conducted within the framework of the French Initiative for Coral Reefs (IFRECOR) to assess pesticide pollution levels in the coral reef trophic webs in French Polynesia. Unexpected widespread contamination by herbicides was found in algae, fishes and macro-invertebrates located at various levels of the reef trophic web. Concentrations in organisms investigated were for the majority below the lowest observable effect level and do not pose a dietary risk to native population who subsist on these fish. However, the widespread contamination may affect the reef ecosystem in the future as coral symbiotic algae, Symbidinium sp. (Dinophyta) are particularly sensitive to photosystem II herbicides, particularly the substituted urea and triazine derivatives.

  14. Molecular Simulations of Graphene-Based Electric Double-Layer Capacitors

    Science.gov (United States)

    Kalluri, Raja K.; Konatham, Deepthi; Striolo, Alberto

    2011-03-01

    Towards deploying renewable energy sources it is crucial to develop efficient and cost-effective technologies to store electricity. Traditional batteries are plagued by a number of practical problems that at present limit their widespread applicability. One possible solution is represented by electric double-layer capacitors (EDLCs). To deploy EDLCs at the large scale it is necessary to better understand how electrolytes pack and diffuse within narrow charged pores. We present here simulation results for the concentrated aqueous solutions of NaCl, CsCl, and NaI confined within charged graphene-based porous materials. We discuss how the structure of confined water, the salt concentration, the ions size, and the surface charge density determine the accumulation of electrolytes within the porous network. Our results, compared to data available for bulk systems, are critical for relating macroscopic observations to molecular-level properties of the confined working fluids. Research supported by the Department of Energy.

  15. Electrolyte bi-layering strategy to improve the performance of an intermediate temperature solid oxide fuel cell: A review

    Science.gov (United States)

    Shri Prakash, B.; Pavitra, R.; Senthil Kumar, S.; Aruna, S. T.

    2018-03-01

    Lowering of operation temperature has become one of the primary goals of solid oxide fuel (SOFC) research as reduced temperature improves the prospects for widespread commercialization of this energy system. Reduced operational temperature also mitigates the issues associated with high temperature SOFCs and paves way not only for the large scale stationary power generation but also makes SOFCs viable for portable and transport applications. However, there are issues with electrolyte and cathode materials at low temperatures, individually as well as in association with other components, which makes the performance of the SOFCs less satisfactory than expected at lowered temperatures. Bi-layering of electrolytes and impregnation of cathodes have emerged as two important strategies to overcome these issues and achieve higher performance at low temperatures. This review article provides the perspective on the strategy of bi-layering of electrolyte to achieve the desired high performance from SOFC at low to intermediate temperatures.

  16. Insights into the Toba Super-Eruption using SEM Analysis of Ash Deposits

    Science.gov (United States)

    Gatti, E.; Achyuthan, H.; Durant, A. J.; Gibbard, P.; Mokhtar, S.; Oppenheimer, C.; Raj, R.; Shridar, A.

    2010-12-01

    The ~74 ka Youngest Toba Tuff (YTT) super-eruption of Toba volcano, Northern Sumatra, was the largest eruption of the Quaternary (magnitude M= 8.8) and injected massive quantities of volcanic gases and ash into the stratosphere. YTT deposits covered at least 40,000,000 km2 of Southeast Asia and are preserved in river valleys across peninsular India and Malaysia, and in deep-sea tephra layers in the Indian Ocean, Bay of Bengal and South China Sea. Initial studies hypothesized the eruption caused immediate and substantial global cooling during the ~ 1 kyr between Dansgaard-Oeschger events 19 and 20 which devastated ecosystems and hominid populations. A more recent review argues against severe post-YTT climatic deterioration and cannot find clear evidence for considerable impacts on ecosystems or bio-diversity. The determination of the eruptive parameters is crucial in this issue to document the eruption and understand the potential impacts from future super-volcanic eruptions. Volcanic ash deposits can offer dramatic insights into key eruptive parameters, including magnitude, duration and plume height. The composition and shape of volcanic ashes can be used to interpret physical properties of an erupting magma and tephra transport, while textural characteristics such as grain roughness and surface vescicularity can provide insights into degassing history, volatile content and explosive activity of the volcano. We present a stratigraphic and sedimentological analysis of YTT deposits in stratified contexts at three localities in India, at two sites in Peninsular Malaysia, and at several localities around Lake Toba and on Samosir Island, Sumatra. These sites offer excellent constraints on the spatial distribution of YTT deposits which can be used to infer dispersal directions of the cloud, and provide insights into environmental controls on preservation of tephra beds. The research aims at a systematic interpretation of the Toba tephra to understand the volcanic

  17. Crystallization and Melt Removal at Arenal Volcano, Polytopic Vector Analysis

    Science.gov (United States)

    Hidalgo, P. J.; Vogel, T. A.; Bolge, L. L.; Ehrlich, R.; Alvarado, G. E.

    2007-12-01

    Tephra sequences ET3 and ET4 from Arenal volcano in Costa Rica have recently been interpreted to be a product of crystal fractionation by Bolge and coworkers in a series of papers (2004, 2006). The two tephra units are part of a sequence of 22 tephra units that represent a 7000 year span of the Arenal volcano activity. The tephro- stratigraphy has been described extensively by Melson (1982; 1994). The ET3 and ET4 tephras were interpreted (based on major- and trace-element, isotopic analyses of whole rocks and microchemical analyses of individual phases) as clear evidence of crystal separation by gravity settling (Bolge et al., 2004, 2006). The lower ET4 tephra sequence (andesitic and crystal poor) and the upper ET3 tephra (basaltic and crystal rich) represent an inverted snapshot of the magma chamber with contrasting geochemical properties. The ET3 sequence (deeper part of the magma chamber) has nearly constant composition with only a few elements varying stratigraphically (best represented by CaO). This is consistent with gradually decreasing amounts of melt in the upper part of ET3. The lower ET4 tephra (upper part of the magma chamber) contains large chemical gradients in both incompatible and compatible elements. In the present study we use whole-rock geochemical data from the recent tephra sequences ET3 and ET4 as inputs to Polytopic Vector Analysis (PVA) (for a review of this method see Vogel and coworkers, in press). With this method we produce a three end member solution that is consistent with crystallization of Olivine, plagioclase and pyroxene from the most mafic end member (EM1) resulting in a crystal rich mush zone. As crystallization progresses the compositions of the liquids are driven towards an intermediate end member (EM3), which has an intermediate composition liquid. At EM3 composition, rapid depletion of FeO, MgO and TiO2 by crystallization of Fe-Ti oxides, rapidly drives the liquid composition towards the silicic EM1 (incompatible element

  18. Processes for multi-layer devices utilizing layer transfer

    Science.gov (United States)

    Nielson, Gregory N; Sanchez, Carlos Anthony; Tauke-Pedretti, Anna; Kim, Bongsang; Cederberg, Jeffrey; Okandan, Murat; Cruz-Campa, Jose Luis; Resnick, Paul J

    2015-02-03

    A method includes forming a release layer over a donor substrate. A plurality of devices made of a first semiconductor material are formed over the release layer. A first dielectric layer is formed over the plurality of devices such that all exposed surfaces of the plurality of devices are covered by the first dielectric layer. The plurality of devices are chemically attached to a receiving device made of a second semiconductor material different than the first semiconductor material, the receiving device having a receiving substrate attached to a surface of the receiving device opposite the plurality of devices. The release layer is etched to release the donor substrate from the plurality of devices. A second dielectric layer is applied over the plurality of devices and the receiving device to mechanically attach the plurality of devices to the receiving device.

  19. Widespread rape does not directly appear to increase the overall HIV prevalence in conflict-affected countries: so now what?

    Directory of Open Access Journals (Sweden)

    Mills Edward

    2008-07-01

    Full Text Available Abstract Background Sub-Saharan Africa (SSA is severely affected by HIV/AIDS and conflict. Sexual violence as a weapon of war has been associated with concerns about heightened HIV incidence among women. Widespread rape by combatants has been documented in Burundi, Sierra Leone, Rwanda, Democratic Republic of Congo, Liberia, Sudan and Uganda. To examine the assertion that widespread rape may not directly increase HIV prevalence at the population level, we built a model to determine the potential impact of varying scenarios of widespread rape on HIV prevalence in the above seven African countries. Discussion Our findings show that even in the most extreme situations, where 15% of the female population was raped, where HIV prevalence among assailants was 8 times the country population prevalence, and where the HIV transmission rate was highest at 4 times the average high rate, widespread rape increased the absolute HIV prevalence of these countries by only 0.023%. These projections support the finding that widespread rape in conflict-affected countries in SSA has not incurred a major direct population-level change in HIV prevalence. However, this must not be interpreted to say that widespread rape does not pose serious problems to women's acquisition of HIV on an individual basis or in specific settings. Furthermore, direct and indirect consequences of sexual violence, such as physical and psychosocial trauma, unwanted pregnancies, and stigma and discrimination cannot be understated. Summary The conclusions of this article do not significantly change current practices in the field from an operational perspective. Proper care and treatment must be provided to every survivor of rape regardless of the epidemiological effects of HIV transmission at the population level. Sexual violence must be treated as a protection issue and not solely a reproductive health and psychosocial issue. It is worth publishing data and conclusions that could be

  20. Prevalence and Characterization of Motile Salmonella in Commercial Layer Poultry Farms in Bangladesh

    Science.gov (United States)

    Barua, Himel; Biswas, Paritosh K.; Olsen, Katharina E. P.; Christensen, Jens P.

    2012-01-01

    Salmonella is a globally widespread food-borne pathogen having major impact on public health. All motile serovars of Salmonella enterica of poultry origin are zoonotic, and contaminated meat and raw eggs are an important source to human infections. Information on the prevalence of Salmonella at farm/holding level, and the zoonotic serovars circulating in layer poultry in the South and South-East Asian countries including Bangladesh, where small-scale commercial farms are predominant, is limited. To investigate the prevalence of Salmonella at layer farm level, and to identify the prevalent serovars we conducted a cross-sectional survey by randomly selecting 500 commercial layer poultry farms in Bangladesh. Faecal samples from the selected farms were collected following standard procedure, and examined for the presence of Salmonella using conventional bacteriological procedures. Thirty isolates were randomly selected, from the ninety obtained from the survey, for serotyping and characterized further by plasmid profiling and pulsed-field gel electrophoresis (PFGE). Results of the survey showed that the prevalence of motile Salmonella at layer farm level was 18% (95% confidence interval 15–21%), and Salmonella Kentucky was identified to be the only serovar circulating in the study population. Plasmid analysis of the S. Kentucky and non-serotyped isolates revealed two distinct profiles with a variation of two different sizes (2.7 and 4.8 kb). PFGE of the 30 S. Kentucky and 30 non-serotyped isolates showed that all of them were clonally related because only one genotype and three subtypes were determined based on the variation in two or three bands. This is also the first report on the presence of any specific serovar of Salmonella enterica in poultry in Bangladesh. PMID:22558269

  1. 14C ages and activity for the past 50 ka at Volcán Galeras, Colombia

    Science.gov (United States)

    Banks, N.G.; Calvache, V.M.L.; Williams, S.N.

    1997-01-01

    Volcán Galeras is the southernmost Colombian volcano with well-recorded historic activity. The volcano is part of a large and complex volcanic center upon which 400,000 people live. Historic activity has centered on a small-volume cone inside the youngest of several large amphitheaters that breach the west flank of the volcano, away from the city of Pasto (population 300,000). Lava flows (SiO2 between 54.6 and 64.7 wt.%) have dominated activity for more than 1 Ma, but explosive events have also occurred. Joint studies by volcanologists from Colombia, Ecuador, Peru, Bolivia, Argentina, and the United States produced 24 new14C ages and more than 100 stratigraphic sections to interpret the past 50 ka of activity at Galeras, including sector collapse events. The youngest collapse event truncated 12.8 ka lava flows and may have occurred as recently as 8 to 10 ka. Tephra-fall material rapidly thins and becomes finer away from the vent area. The only widespread marker in the < 10 ka section is a biotite-bearing tephra deposited between 4.1 and 4.5 ka from a source south of Galeras. It separates cryoturbated from largely undisturbed layers on Galeras, and thus dates a stratigraphic horizon which is useful in the interpretation of other volcanoes and geotectonics in the equatorial Andes. Pyroclastic flows during the past 50 ka have been small to moderate in volume, but they have left numerous thin deposits on the north and east flanks where lava flows have been impeded by crater and amphitheater walls. Many of the pyroclastic-flow deposits are lithic rich, with fines and clasts so strongly altered by hydrothermal action before eruption that they, as well as the sector collapse deposits, resemble waste dumps of leached cappings from disseminated sulfide deposits more than volcanogenic deposits. This evidence of a long-lived hydrothermal system indicates susceptibility to mass failure and explosive events higher than expected for a volcano built largely by lava flows and

  2. Single-unit-cell layer established Bi 2 WO 6 3D hierarchical architectures: Efficient adsorption, photocatalysis and dye-sensitized photoelectrochemical performance

    Energy Technology Data Exchange (ETDEWEB)

    Huang, Hongwei; Cao, Ranran; Yu, Shixin; Xu, Kang; Hao, Weichang; Wang, Yonggang; Dong, Fan; Zhang, Tierui; Zhang, Yihe

    2017-12-01

    Single-layer catalysis sparks huge interests and gains widespread attention owing to its high activity. Simultaneously, three-dimensional (3D) hierarchical structure can afford large surface area and abundant reactive sites, contributing to high efficiency. Herein, we report an absorbing single-unit-cell layer established Bi2WO6 3D hierarchical architecture fabricated by a sodium dodecyl benzene sulfonate (SDBS)-assisted assembled strategy. The DBS- long chains can adsorb on the (Bi2O2)2+ layers and hence impede stacking of the layers, resulting in the single-unit-cell layer. We also uncovered that SDS with a shorter chain is less effective than SDBS. Due to the sufficient exposure of surface O atoms, single-unit-cell layer 3D Bi2WO6 shows strong selectivity for adsorption on multiform organic dyes with different charges. Remarkably, the single-unit-cell layer 3D Bi2WO6 casts profoundly enhanced photodegradation activity and especially a superior photocatalytic H2 evolution rate, which is 14-fold increase in contrast to the bulk Bi2WO6. Systematic photoelectrochemical characterizations disclose that the substantially elevated carrier density and charge separation efficiency take responsibility for the strengthened photocatalytic performance. Additionally, the possibility of single-unit-cell layer 3D Bi2WO6 as dye-sensitized solar cells (DSSC) has also been attempted and it was manifested to be a promising dye-sensitized photoanode for oxygen evolution reaction (ORR). Our work not only furnish an insight into designing single-layer assembled 3D hierarchical architecture, but also offer a multi-functional material for environmental and energy applications.

  3. S-Layer Based Bio-Imprinting - Synthetic S-Layer Polymers

    Science.gov (United States)

    2015-07-09

    AFRL-OSR-VA-TR-2015-0161 S-Layer Based Bio- Imprinting - Synthetic S-Layer Polymers Dietmar Pum ZENTRUM FUER NANOBIOTECHNOLOGIE Final Report 07/09...COVERED (From - To)      01-06-2012 to 31-05-2015 4.  TITLE AND SUBTITLE S-Layer Based Bio- Imprinting - Synthetic S-Layer Polymers 5a.  CONTRACT...technology for the fabrication of nano patterned thin film imprints by using functional S-layer protein arrays as templates. The unique feature of

  4. The Application of Layer Theory to Design: The Control Layer

    Science.gov (United States)

    Gibbons, Andrew S.; Langton, Matthew B.

    2016-01-01

    A theory of design layers proposed by Gibbons ("An Architectural Approach to Instructional Design." Routledge, New York, 2014) asserts that each layer of an instructional design is related to a body of theory closely associated with the concerns of that particular layer. This study focuses on one layer, the control layer, examining…

  5. Widespread osteolytic lesions of the long bones in basal cell nevus syndrome

    International Nuclear Information System (INIS)

    Blinder, G.; Barki, Y.; Bar-Ziv, J.; Pezt, M.

    1984-01-01

    Three members of a family, father, daughter, and son, with the basal cell nevus syndrome are presented. A very unusual manifestation of widespread cyst-like osteolytic lesions in all the tubular bones was observed in the father, together with osteoblastic spotty 'osteopoikilotic' lesions in the skull and the mandible of the same patient. Cyst-like osteolytic lesions have been described previously in this syndrome, mainly in the phalanges. We believe that such lesions can occur in any bone. (orig.)

  6. Layer-by-layer cell membrane assembly

    Science.gov (United States)

    Matosevic, Sandro; Paegel, Brian M.

    2013-11-01

    Eukaryotic subcellular membrane systems, such as the nuclear envelope or endoplasmic reticulum, present a rich array of architecturally and compositionally complex supramolecular targets that are as yet inaccessible. Here we describe layer-by-layer phospholipid membrane assembly on microfluidic droplets, a route to structures with defined compositional asymmetry and lamellarity. Starting with phospholipid-stabilized water-in-oil droplets trapped in a static droplet array, lipid monolayer deposition proceeds as oil/water-phase boundaries pass over the droplets. Unilamellar vesicles assembled layer-by-layer support functional insertion both of purified and of in situ expressed membrane proteins. Synthesis and chemical probing of asymmetric unilamellar and double-bilayer vesicles demonstrate the programmability of both membrane lamellarity and lipid-leaflet composition during assembly. The immobilized vesicle arrays are a pragmatic experimental platform for biophysical studies of membranes and their associated proteins, particularly complexes that assemble and function in multilamellar contexts in vivo.

  7. Assembly of 1D nanofibers into a 2D bi-layered composite nanofibrous film with different functionalities at the two layers via layer-by-layer electrospinning.

    Science.gov (United States)

    Wang, Zijiao; Ma, Qianli; Dong, Xiangting; Li, Dan; Xi, Xue; Yu, Wensheng; Wang, Jinxian; Liu, Guixia

    2016-12-21

    A two-dimensional (2D) bi-layered composite nanofibrous film assembled by one-dimensional (1D) nanofibers with trifunctionality of electrical conduction, magnetism and photoluminescence has been successfully fabricated by layer-by-layer electrospinning. The composite film consists of a polyaniline (PANI)/Fe 3 O 4 nanoparticle (NP)/polyacrylonitrile (PAN) tuned electrical-magnetic bifunctional layer on one side and a Tb(TTA) 3 (TPPO) 2 /polyvinylpyrrolidone (PVP) photoluminescent layer on the other side, and the two layers are tightly combined face-to-face together into the novel bi-layered composite film of trifunctionality. The brand-new film has totally different characteristics at the double layers. The electrical conductivity and magnetism of the electrical-magnetic bifunctional layer can be, respectively, tunable via modulating the PANI and Fe 3 O 4 NP contents, and the highest electrical conductivity can reach up to the order of 10 -2 S cm -1 , and predominant intense green emission at 545 nm is obviously observed in the photoluminescent layer under the excitation of 357 nm single-wavelength ultraviolet light. More importantly, the luminescence intensity of the photoluminescent layer remains almost unaffected by the electrical-magnetic bifunctional layer because the photoluminescent materials have been successfully isolated from dark-colored PANI and Fe 3 O 4 NPs. By comparing with the counterpart single-layered composite nanofibrous film, it is found that the bi-layered composite nanofibrous film has better performance. The novel bi-layered composite nanofibrous film with trifunctionality has potential in the fields of nanodevices, molecular electronics and biomedicine. Furthermore, the design conception and fabrication technique for the bi-layered multifunctional film provide a new and facile strategy towards other films of multifunctionality.

  8. Diet, Lifestyle and Chronic Widespread Pain: Results from the 1958 British Birth Cohort Study

    Directory of Open Access Journals (Sweden)

    Elizabeth G VanDenKerkhof

    2011-01-01

    Full Text Available OBJECTIVES: To examine the relationship between diet and lifestyle, and chronic widespread pain (CWP. If persons with CWP have dietary and lifestyle habits consistent with an increased risk of cancer or cardiovascular disease, it may partially explain evidence in the literature suggesting an association between CWP and these diseases.

  9. Sacrococcygeal chordomas with wide-spread metastases: report of two cases and review of literature

    Energy Technology Data Exchange (ETDEWEB)

    Suh, Hyun Suk; Shin, Young Ju; Joo, Mee; Kim, Byung Jik [College of Medicine, Inje Univ., Pusan (Korea, Republic of)

    1999-03-01

    Chordomas are rare tumors arising from the primitive notochord. The commonest affected segment is the sacrum and these chordomas frequently follow a progressive course with multiple recurrences and metastases and eventual death due to tumor. This report describes two cases of sacrococcygeal chordomas with widespread metastases treated by surgery and adjuvant radiation therapy.

  10. Sacrococcygeal chordomas with wide-spread metastases: report of two cases and review of literature

    International Nuclear Information System (INIS)

    Suh, Hyun Suk; Shin, Young Ju; Joo, Mee; Kim, Byung Jik

    1999-01-01

    Chordomas are rare tumors arising from the primitive notochord. The commonest affected segment is the sacrum and these chordomas frequently follow a progressive course with multiple recurrences and metastases and eventual death due to tumor. This report describes two cases of sacrococcygeal chordomas with widespread metastases treated by surgery and adjuvant radiation therapy

  11. Bilateral widespread mechanical pain sensitivity in carpal tunnel syndrome: evidence of central processing in unilateral neuropathy.

    Science.gov (United States)

    Fernández-de-las-Peñas, César; de la Llave-Rincón, Ana Isabel; Fernández-Carnero, Josué; Cuadrado, María Luz; Arendt-Nielsen, Lars; Pareja, Juan A

    2009-06-01

    The aim of this study was to investigate whether bilateral widespread pressure hypersensitivity exists in patients with unilateral carpal tunnel syndrome. A total of 20 females with carpal tunnel syndrome (aged 22-60 years), and 20 healthy matched females (aged 21-60 years old) were recruited. Pressure pain thresholds were assessed bilaterally over median, ulnar, and radial nerve trunks, the C5-C6 zygapophyseal joint, the carpal tunnel and the tibialis anterior muscle in a blinded design. The results showed that pressure pain threshold levels were significantly decreased bilaterally over the median, ulnar, and radial nerve trunks, the carpal tunnel, the C5-C6 zygapophyseal joint, and the tibialis anterior muscle in patients with unilateral carpal tunnel syndrome as compared to healthy controls (all, P < 0.001). Pressure pain threshold was negatively correlated to both hand pain intensity and duration of symptoms (all, P < 0.001). Our findings revealed bilateral widespread pressure hypersensitivity in subjects with carpal tunnel syndrome, which suggest that widespread central sensitization is involved in patients with unilateral carpal tunnel syndrome. The generalized decrease in pressure pain thresholds associated with pain intensity and duration of symptoms supports a role of the peripheral drive to initiate and maintain central sensitization. Nevertheless, both central and peripheral sensitization mechanisms are probably involved at the same time in carpal tunnel syndrome.

  12. Gastroesophageal anastomosis: single-layer versus double-layer technique

    International Nuclear Information System (INIS)

    Aslam, V.A.; Bilal, A.; Khan, A.; Ahmed, M.

    2008-01-01

    Considerable controversy exists regarding the optimum technique for gastroesophageal anastomosis. Double layer technique has long been considered important for safe healing but there is evidence that single layer technique is also safe and can be performed in much shorter time. The purpose of this study was to compare the outcome of single layer and double layer techniques for gastroesophageal anastomosis. A prospective randomized study was conducted in cardiothoracic unit, Lady Reading Hospital from Jan 2006 to Jan 2008. Fifty patients with oesophageal carcinoma undergoing subtotal oesophagectomy were randomized to have the anastomosis by single layer continuous or double layer continuous technique (group A (n=24) and B (n=26) respectively). The demographic data, operative and anastomosis time, postoperative complications and hospital mortality were recorded on a proforma and analyzed on SPSS 10. There was no significant difference between group A and B in terms of age, gender, postoperative complications and duration of hospital stay. Anastomotic leak occurred in 4.2% patients in group A and 7.7% in group B (p=NS). Mean anastomosis time was 10.04 minutes in group A and 19.2 minutes in group B (p=0.0001). Mean operative time was 163.83 minutes and 170.96 minutes in group A and B respectively. Overall hospital mortality was 2%; no deaths occurred due to anastomotic leak. Single layer continuous technique is equally safe and can be performed in shorter time and at a lower cost than the double layer technique. (author)

  13. Diurnal adjustment in ultraviolet sunscreen protection is widespread among higher plants.

    Science.gov (United States)

    Barnes, Paul W; Flint, Stephan D; Tobler, Mark A; Ryel, Ronald J

    2016-05-01

    The accumulation of ultraviolet (UV)-absorbing compounds (flavonoids and related phenylpropanoids) in the epidermis of higher plants reduces the penetration of solar UV radiation to underlying tissues and is a primary mechanism of acclimation to changing UV conditions resulting from ozone depletion and climate change. Previously we reported that several herbaceous plant species were capable of rapid, diurnal adjustments in epidermal UV transmittance (T UV), but how widespread this phenomenon is among plants has been unknown. In the present study, we tested the generality of this response by screening 37 species of various cultivated and wild plants growing in four locations spanning a gradient of ambient solar UV and climate (Hawaii, Utah, Idaho and Louisiana). Non-destructive measurements of adaxial T UV indicated that statistically significant midday decreases in T UV occurred in 49 % of the species tested, including both herbaceous and woody growth forms, and there was substantial interspecific variation in the magnitude of these changes. In general, plants in Louisiana exhibited larger diurnal changes in T UV than those in the other locations. Moreover, across all taxa, the magnitude of these changes was positively correlated with minimum daily air temperatures but not daily UV irradiances. Results indicate that diurnal changes in UV shielding are widespread among higher plants, vary both within and among species and tend to be greatest in herbaceous plants growing in warm environments. These findings suggest that plant species differ in their UV protection "strategies" though the functional and ecological significance of this variation in UV sunscreen protection remains unclear at present.

  14. Spintharus flavidus in the Caribbean-a 30 million year biogeographical history and radiation of a 'widespread species'.

    Science.gov (United States)

    Dziki, Austin; Binford, Greta J; Coddington, Jonathan A; Agnarsson, Ingi

    2015-01-01

    The Caribbean island biota is characterized by high levels of endemism, the result of an interplay between colonization opportunities on islands and effective oceanic barriers among them. A relatively small percentage of the biota is represented by 'widespread species,' presumably taxa for which oceanic barriers are ineffective. Few studies have explored in detail the genetic structure of widespread Caribbean taxa. The cobweb spider Spintharus flavidus Hentz, 1850 (Theridiidae) is one of two described Spintharus species and is unique in being widely distributed from northern N. America to Brazil and throughout the Caribbean. As a taxonomic hypothesis, Spintharus "flavidus" predicts maintenance of gene flow among Caribbean islands, a prediction that seems contradicted by known S. flavidus biology, which suggests limited dispersal ability. As part of an extensive survey of Caribbean arachnids (project CarBio), we conducted the first molecular phylogenetic analysis of S. flavidus with the primary goal of testing the 'widespread species' hypothesis. Our results, while limited to three molecular loci, reject the hypothesis of a single widespread species. Instead this lineage seems to represent a radiation with at least 16 species in the Caribbean region. Nearly all are short range endemics with several distinct mainland groups and others are single island endemics. While limited taxon sampling, with a single specimen from S. America, constrains what we can infer about the biogeographical history of the lineage, clear patterns still emerge. Consistent with limited overwater dispersal, we find evidence for a single colonization of the Caribbean about 30 million years ago, coinciding with the timing of the GAARLandia landbridge hypothesis. In sum, S. "flavidus" is not a single species capable of frequent overwater dispersal, but rather a 30 my old radiation of single island endemics that provides preliminary support for a complex and contested geological hypothesis.

  15. Repeated and Widespread Evolution of Bioluminescence in Marine Fishes.

    Directory of Open Access Journals (Sweden)

    Matthew P Davis

    Full Text Available Bioluminescence is primarily a marine phenomenon with 80% of metazoan bioluminescent genera occurring in the world's oceans. Here we show that bioluminescence has evolved repeatedly and is phylogenetically widespread across ray-finned fishes. We recover 27 independent evolutionary events of bioluminescence, all among marine fish lineages. This finding indicates that bioluminescence has evolved many more times than previously hypothesized across fishes and the tree of life. Our exploration of the macroevolutionary patterns of bioluminescent lineages indicates that the present day diversity of some inshore and deep-sea bioluminescent fish lineages that use bioluminescence for communication, feeding, and reproduction exhibit exceptional species richness given clade age. We show that exceptional species richness occurs particularly in deep-sea fishes with intrinsic bioluminescent systems and both shallow water and deep-sea lineages with luminescent systems used for communication.

  16. Performance-based assessment of activities of daily living (ADL) ability among women with chronic widespread pain

    DEFF Research Database (Denmark)

    Wæhrens, Eva Ejlersen; Amris, Kirstine; Fisher, Anne G

    2010-01-01

    . The investigated psychometric properties of the AMPS included discrimination between a sample of healthy women and those with chronic widespread pain, as well as stability when no intervention was provided and sensitivity to change following intervention. Data were obtained based on a repeated measures design......-report and performance-based assessment of ADL offer distinct but complementary information about ability. The present study, therefore, investigated the applicability of a performance-based measure of ADL ability, the Assessment of Motor and Process Skills (AMPS), among 50 women with chronic widespread pain...... performing AMPS evaluations twice pre- and twice post-rehabilitation. Results indicated that the ADL motor ability measures of the participants were significantly lower than those of healthy women of same age, the ADL motor and ADL process ability measures remained stable when no intervention was provided...

  17. Local trauma in human patellar tendon leads to widespread changes in the tendon gene expression

    DEFF Research Database (Denmark)

    Heinemeier, Katja Maria; Lorentzen, Marc P; Kildevang Jensen, Jacob

    2016-01-01

    Low cellular activity and slow tissue turnover in human tendon may prolong resolution of tendinopathy. This may be stimulated by moderate localized traumas such as needle penetrations, but whether this results in a widespread cellular response in tendons is unknown. In an initial hypothesis-gener...

  18. Widespread reductions of white matter integrity in patients with long-term remission of Cushing's disease

    Directory of Open Access Journals (Sweden)

    Steven J.A. van der Werff

    2014-01-01

    Conclusion: Patients with a history of endogenous hypercortisolism in present remission show widespread changes of white matter integrity in the brain, with abnormalities in the integrity of the uncinate fasciculus being related to the severity of depressive symptoms, suggesting persistent structural effects of hypercortisolism.

  19. Evaluation of white matter hyperintensities and retinal fiber layer, ganglion cell layer, inner-plexiform layer, and choroidal layer in migraine patients.

    Science.gov (United States)

    Tak, Ali Zeynel Abidin; Sengul, Yıldızhan; Bilak, Şemsettin

    2018-03-01

    The aim of our study is to assess retinal nerve fiber layer (RNFL), the ganglion cell layer (GCL), inner-plexiform layer (IPL), and choroidal layer in migraine patients with white matter lesion (WML) or without WML, using spectral domain optical coherence tomography (OCT). To our study, 77 migraine patients who are diagnosed with migraine in accordance to the International Classification of Headache Disorders (ICHD)-3 beta and 43 healthy control are included. In accordance to cranial MRI, migraine patients are divided into two groups as those who have white matter lesions (39 patients), and those who do not have a lesion (38 patients). OCT was performed for participants. The average age of participants was comparable. The RNFL average thickness parameter in the migraine group was significantly lower than in the control group (p layer measuring scales. The proofs showing that affected retinal nerve fiber layer are increased in migraine patients. However, it is not known whether this may affect other layers of retina, or whether there is a correlation between affected retinal structures and white matter lesions. In our study, we found thinner RNFL in migraine patients when we compared with controls but IPL, GCL, and choroid layer values were similar between each patient groups and controls. Also, all parameters were similar between patients with WML and without WML. Studies in this regard are required.

  20. Widespread abundance of functional bacterial amyloid in Mycolata and other Gram-positive bacteria

    DEFF Research Database (Denmark)

    Jordal, Peter Bruun; Dueholm, Morten Simonsen; Larsen, Poul

    2009-01-01

    extracellular fibrils were also produced. In three cases, FuBA was only revealed after extensive removal of extracellular material by saponification, indicating an integrated attachment within the cellular envelope. Spores from species within the genera Streptomyces, Bacillus and Nocardia were all coated...... analysis. We conclude that amyloid is widespread among Gram-positive bacteria and may in many species constitute a hitherto overlooked integral part of the spores and the cellular envelope....

  1. A North Atlantic tephrostratigraphical framework for 130-60 ka b2k

    DEFF Research Database (Denmark)

    Siwan M., Davis; Peter M., Abbott; Rhian H., Meara

    2014-01-01

    . Major, minor and trace element results are presented for the new NGRIP horizons together with age estimates based on their position within the ice-core record. Basaltic tephras of Icelandic origin dominate the framework with only eight tephras of rhyolitic composition found. New results from marine core...... of tephrochronology. Further investigations, however, are required, that combine robust geochemical fingerprinting and a rigorous assessment of tephra depositional processes, in order to trace coeval events between the two depositional realms...

  2. Widespread EEG changes precede focal seizures.

    Directory of Open Access Journals (Sweden)

    Piero Perucca

    Full Text Available The process by which the brain transitions into an epileptic seizure is unknown. In this study, we investigated whether the transition to seizure is associated with changes in brain dynamics detectable in the wideband EEG, and whether differences exist across underlying pathologies. Depth electrode ictal EEG recordings from 40 consecutive patients with pharmacoresistant lesional focal epilepsy were low-pass filtered at 500 Hz and sampled at 2,000 Hz. Predefined EEG sections were selected immediately before (immediate preictal, and 30 seconds before the earliest EEG sign suggestive of seizure activity (baseline. Spectral analysis, visual inspection and discrete wavelet transform were used to detect standard (delta, theta, alpha, beta and gamma and high-frequency bands (ripples and fast ripples. At the group level, each EEG frequency band activity increased significantly from baseline to the immediate preictal section, mostly in a progressive manner and independently of any modification in the state of vigilance. Preictal increases in each frequency band activity were widespread, being observed in the seizure-onset zone and lesional tissue, as well as in remote regions. These changes occurred in all the investigated pathologies (mesial temporal atrophy/sclerosis, local/regional cortical atrophy, and malformations of cortical development, but were more pronounced in mesial temporal atrophy/sclerosis. Our findings indicate that a brain state change with distinctive features, in the form of unidirectional changes across the entire EEG bandwidth, occurs immediately prior to seizure onset. We postulate that these changes might reflect a facilitating state of the brain which enables a susceptible region to generate seizures.

  3. Widespread microplastic ingestion by fish assemblages in tropical estuaries subjected to anthropogenic pressures

    International Nuclear Information System (INIS)

    Vendel, A.L.; Bessa, F.; Alves, V.E.N.; Amorim, A.L.A.; Patrício, J.; Palma, A.R.T.

    2017-01-01

    Our aim was to quantify microplastic ingestion by fish assemblages in two tropical Brazilian estuaries and to evaluate whether biological and ecological factors influence the ingestion of microplastics by fish species. Of 2233 fish from both estuaries (from 69 species) examined in this study, 9% of the individuals (24 species) had microplastics in their gut contents. Microplastic ingestion occurred irrespective of fish size and functional group. The diet of fish species was analyzed based on prey items identified in the fish's full stomach contents and five feeding guilds were defined. Microplastics were common throughout all feeding guilds. Low (average ingestion values 1.06 ± 0.30 items/total fish) but widespread occurrence among estuaries also indicates proliferation of microplastic pollution. Our findings highlight the need to focus on assemblage level studies to understand the real magnitude of the problem and emphasize the urgency of mitigation measures directed at microplastic pollution in estuarine ecosystems. - Highlights: • We analyzed microplastic ingestion in 69 fish species collected along two estuaries. • Microplastic ingestion was widespread in fish assemblages in two tropical estuaries. • Microplastic ingestion was independent of fish size and fish functional groups. • Microplastics were observed in fish from five different feeding guilds. • The level of anthropogenic pressures did not influence microplastic ingestion.

  4. A localized flare of dermatitis may render patch tests uninterpretable in some patients with recently controlled widespread dermatitis.

    Science.gov (United States)

    Magembe, Anna J; Davis, Mark D P; Richardson, Donna M

    2009-01-01

    Patch testing rarely is confounded by localized dermatitis induced in the area being tested (usually the back). Its occurrence renders the interpretation of patch tests impossible. To review our experience of the circumstances in which this phenomenon occurs during patch testing. We retrospectively reviewed patients with this phenomenon who underwent patch testing from January 1, 2002, through June 30, 2006. Of the 3,569 patients tested, 12 (0.34% [9 men and 3 women]) had development of this phenomenon. All patients previously had recent widespread dermatitis that was suppressed temporarily with topical corticosteroids and wet dressings at the time of patch testing. The period between control of the dermatitis and the initiation of patch testing was less than 1 week for all patients. Three patients (25%) had recently discontinued therapy with systemic corticosteroids (less than 1 week earlier). In patients with irritable skin either immediately after widespread dermatitis is controlled or after the cessation of systemic corticosteroid treatment, a flare of dermatitis induced by patch testing may render patch tests unreadable and therefore uninterpretable. To avoid this confounding occurrence, a waiting period between control of widespread dermatitis and initiation of patch testing is advised.

  5. δD values of hydrated volcanic glass : a potential record of ancient meteoric water and climate in New Zealand

    International Nuclear Information System (INIS)

    Shane, P.; Ingraham, N.

    2002-01-01

    Tephra beds that are well drained and have been buried by thin paleosols become hydrated within 2-3000 yr on reaction with meteoric waters. Hence, the absorbed water within silicic volcanic glass shards provides a potential record of δD values of ancient meteoric water. Such isotopic records have previously received little investigation. We demonstrate that 1.5-2 m thick tephra beds in central North Island, New Zealand, display uniform δD values vertically through their profiles and laterally up to 250 m in outcrop. Reproducibility is not influenced by grain size or age of the tephra. We obtained an average δD value of -48 ± 3 permille for water within the 1.8 ka Taupo Tephra. This is similar to the composition of present-day surface waters. δD values of -73 ± 2 and -60 ± 2 permille for the 25 ka Kawakawa and 30 ka Mangaone Tephra beds are significantly lower than present waters, indicating that they have been hydrated under different surficial conditions. This is consistent with other proxy paleoclimatic indicators that suggest a cooler, drier, and windier climate at the time of their eruption. Tephra beds are a potential source of paleoclimatic data in terrestrial environments that otherwise may lack proxy records. (author). 17 refs., 5 figs., 3 tabs

  6. Isolation of polymorphic microsatellite markers and tests of cross-amplification in four widespread European calcicole ferns

    NARCIS (Netherlands)

    Groot, de G.A.; Korpelainen, H.; Wubs, E.R.J.; Erkens, R.H.J.

    2011-01-01

    Premise of the study: Studies on the biogeography and population genetics of the widespread European rock ferns Asplenium scolopendrium , A. trichomanes subsp. quadrivalens , Polystichum setiferum , and P. aculeatum would potentially yield interesting new insights into the colonization capacities of

  7. Layer-dependent band alignment and work function of few-layer phosphorene.

    Science.gov (United States)

    Cai, Yongqing; Zhang, Gang; Zhang, Yong-Wei

    2014-10-20

    Using first-principles calculations, we study the electronic properties of few-layer phosphorene focusing on layer-dependent behavior of band gap, work function band alignment and carrier effective mass. It is found that few-layer phosphorene shows a robust direct band gap character, and its band gap decreases with the number of layers following a power law. The work function decreases rapidly from monolayer (5.16 eV) to trilayer (4.56 eV), and then slowly upon further increasing the layer number. Compared to monolayer phosphorene, there is a drastic decrease of hole effective mass along the ridge (zigzag) direction for bilayer phosphorene, indicating a strong interlayer coupling and screening effect. Our study suggests that 1). Few-layer phosphorene with a layer-dependent band gap and a robust direct band gap character is promising for efficient solar energy harvest. 2). Few-layer phosphorene outperforms monolayer counterpart in terms of a lighter carrier effective mass, a higher carrier density and a weaker scattering due to enhanced screening. 3). The layer-dependent band edges and work functions of few-layer phosphorene allow for modification of Schottky barrier with enhanced carrier injection efficiency. It is expected that few-layer phosphorene will present abundant opportunities for a plethora of new electronic applications.

  8. Natural melanin composites by layer-by-layer assembly

    Science.gov (United States)

    Eom, Taesik; Shim, Bong Sub

    2015-04-01

    Melanin is an electrically conductive and biocompatible material, because their conjugated backbone structures provide conducting pathways from human skin, eyes, brain, and beyond. So there is a potential of using as materials for the neural interfaces and the implantable devices. Extracted from Sepia officinalis ink, our natural melanin was uniformly dispersed in mostly polar solvents such as water and alcohols. Then, the dispersed melanin was further fabricated to nano-thin layered composites by the layer-by-layer (LBL) assembly technique. Combined with polyvinyl alcohol (PVA), the melanin nanoparticles behave as an LBL counterpart to from finely tuned nanostructured films. The LBL process can adjust the smart performances of the composites by varying the layering conditions and sandwich thickness. We further demonstrated the melanin loading degree of stacked layers, combination nanostructures, electrical properties, and biocompatibility of the resulting composites by UV-vis spectrophotometer, scanning electron microscope (SEM), multimeter, and in-vitro cell test of PC12, respectively.

  9. Inside the volcano: The how and why of Thrihnukagigur volcano, Iceland

    Science.gov (United States)

    LaFemina, Peter; Hudak, Michael; Feineman, Maureen; Geirsson, Halldor; Normandeau, Jim; Furman, Tanya

    2015-04-01

    The Thrihnukagigur volcano, located in the Brennisteinsfjöll fissure swarm on the Reykjanes Peninsula, Iceland, offers a unique exposure of the upper magmatic plumbing system of a monogenetic volcano. The volcano formed during a dike-fed strombolian eruption ~3500 BP with flow-back leaving an evacuated conduit, elongated parallel to the regional maximum horizontal stress. At least two vents were formed above the dike, as well as several small hornitos south-southwest of the main vent. In addition to the evacuated conduit, a cave exists 120 m below the vent. The cave exposes stacked lava flows and a buried cinder cone. The unconsolidated tephra of the cone is cross-cut by a NNE-trending dike, which runs across the ceiling of this cave to the vent that produced lava and tephra during the ~3500 BP fissure eruption. We present geochemical, petrologic and geologic observations, including a high-resolution three-dimensional scan of the system that indicate the dike intersected, eroded and assimilated unconsolidated tephra from the buried cinder cone, thus excavating a region along the dike, allowing for future slumping and cave formation. Two petrographically distinct populations of plagioclase phenocrysts are present in the system: a population of smaller (maximum length 1 mm) acicular phenocrysts and a population of larger (maximum length 10 mm) tabular phenocrysts that is commonly broken and displays disequilibrium sieve textures. The acicular plagioclase crystals are present in the dike and lavas while the tabular crystals are in these units and the buried tephra. An intrusion that appears not to have interacted with the tephra has only acicular plagioclase. This suggests that a magma crystallizing a single acicular population of plagioclase intruded the cinder cone and rapidly assimilated the tephra, incorporating the tabular population of phenocrysts from the cone. Petrographic thin-sections of lavas sampled near the vent show undigested fragments of tephra from

  10. A New Approach for Severity Estimation of Transversal Cracks in Multi-layered Beams

    Directory of Open Access Journals (Sweden)

    Gilbert-Rainer Gillich

    Full Text Available Abstract Nowadays, the damage severity evaluation in mechanical structures is mostly performed by analyzing the natural frequency shift. The non-isotropic materials, as the multi-layered ones, are wide-spread in industrial applications, due to their interesting physic-mechanical properties. Thus, a deeper approach of multi-layered beams becomes an important request in the research domain. This paper introduces a damage severity estimator by expressing the crack evolution as a function of stored energy. It is well known that the energy stored in a beam without damage is greater than the energy of that damaged beam. As a consequence, the beam deflection can be related to the stored energy. In this regard, the possibility to split the damage localization and the damage severity assessment has been proven, and also the graphical evolution of the natural frequency shift has been achieved as a function of the crack depth. The results achieved by the finite element method (FEM and experimental tests are given in tables and graphics. For the first five vibration modes, a comparison was made between frequencies accomplished by analytical, numerical and experimental analyses, in order to give more credibility to the accuracy of the research data presented in this paper.

  11. Shallow vent architecture of Puyehue Cordón-Caulle, as revealed by direct observation of explosive activity

    Science.gov (United States)

    Schipper, C. I.; Tuffen, H.; Castro, J. M.

    2012-04-01

    On June 4, 2011, an explosive eruption of rhyodacitic magma began at the Puyehue Cordón-Caulle volcanic complex (PCCVC), southern Chile. Initial Plinian phases of the eruption produced tephra plumes reaching > 14 km high, the ash from which quickly circumnavigated the globe to cause widespread disruption to air traffic in the Southern Hemisphere. Within two weeks, the continuing explosive eruption was joined by synchronous effusion of lava. We present observations of complex vent activity made 7 months after the eruption onset, on January 4th and 10th, 2012, when explosive activity from PCCVC continued at a lower level of intensity. Fortuitous climatic conditions permitted direct, ground-based observation and video recording of transient vent dynamics within the asymmetrical tephra cone around the main eruptive vent complex and site of lava effusion, as well as real-time collection of juvenile ash as it rained out directly from the active plume. On Jan. 4, explosive activity was semi-continuous ash jetting punctuated by Vulcanian-like blasts. In the ~50m-diameter sub-circular base of the ~400 m-wide, asymmetrical tephra cone, near-continuous ash jetting was observed from two primary point sources. The northerly source was clearly visible, with time-averaged diameter of ~10 m, and the apparently larger southerly source was mostly obscured from view by the ash plume. Activity was at all times somewhat erratic, but followed a rough cyclicity on 30-45 s timescales, consisting of: (1) restriction of the point source into a focused ash jet up to ~50 m high, producing coarse ash dominated by tube pumice (with minor free pyroxene crystals); followed by (2) Vulcanian-like failure of the region around the point source, producing incandescent ballistic bombs thrown up to 100-200 m from the vent. Jetting from the two main point sources combined in the crater to produce a low gas-thrust region and sustained buoyant plume. Directed ash plumes that climbed and breached the inner

  12. Widespread ground motion distribution caused by rupture directivity during the 2015 Gorkha, Nepal earthquake

    Science.gov (United States)

    Koketsu, Kazuki; Miyake, Hiroe; Guo, Yujia; Kobayashi, Hiroaki; Masuda, Tetsu; Davuluri, Srinagesh; Bhattarai, Mukunda; Adhikari, Lok Bijaya; Sapkota, Soma Nath

    2016-06-01

    The ground motion and damage caused by the 2015 Gorkha, Nepal earthquake can be characterized by their widespread distributions to the east. Evidence from strong ground motions, regional acceleration duration, and teleseismic waveforms indicate that rupture directivity contributed significantly to these distributions. This phenomenon has been thought to occur only if a strike-slip or dip-slip rupture propagates to a site in the along-strike or updip direction, respectively. However, even though the earthquake was a dip-slip faulting event and its source fault strike was nearly eastward, evidence for rupture directivity is found in the eastward direction. Here, we explore the reasons for this apparent inconsistency by performing a joint source inversion of seismic and geodetic datasets, and conducting ground motion simulations. The results indicate that the earthquake occurred on the underthrusting Indian lithosphere, with a low dip angle, and that the fault rupture propagated in the along-strike direction at a velocity just slightly below the S-wave velocity. This low dip angle and fast rupture velocity produced rupture directivity in the along-strike direction, which caused widespread ground motion distribution and significant damage extending far eastwards, from central Nepal to Mount Everest.

  13. Widespread Natural Occurrence of Hydroxyurea in Animals.

    Directory of Open Access Journals (Sweden)

    David I Fraser

    Full Text Available Here we report the widespread natural occurrence of a known antibiotic and antineoplastic compound, hydroxyurea in animals from many taxonomic groups. Hydroxyurea occurs in all the organisms we have examined including invertebrates (molluscs and crustaceans, fishes from several major groups, amphibians and mammals. The species with highest concentrations was an elasmobranch (sharks, skates and rays, the little skate Leucoraja erinacea with levels up to 250 μM, high enough to have antiviral, antimicrobial and antineoplastic effects based on in vitro studies. Embryos of L. erinacea showed increasing levels of hydroxyurea with development, indicating the capacity for hydroxyurea synthesis. Certain tissues of other organisms (e.g. skin of the frog (64 μM, intestine of lobster (138 μM gills of the surf clam (100 μM had levels high enough to have antiviral effects based on in vitro studies. Hydroxyurea is widely used clinically in the treatment of certain human cancers, sickle cell anemia, psoriasis, myeloproliferative diseases, and has been investigated as a potential treatment of HIV infection and its presence at high levels in tissues of elasmobranchs and other organisms suggests a novel mechanism for fighting disease that may explain the disease resistance of some groups. In light of the known production of nitric oxide from exogenously applied hydroxyurea, endogenous hydoxyurea may play a hitherto unknown role in nitric oxide dynamics.

  14. Widespread Natural Occurrence of Hydroxyurea in Animals.

    Science.gov (United States)

    Fraser, David I; Liu, Kyle T; Reid, Bryan J; Hawkins, Emily; Sevier, Andrew; Pyle, Michelle; Robinson, Jacob W; Ouellette, Pierre H R; Ballantyne, James S

    2015-01-01

    Here we report the widespread natural occurrence of a known antibiotic and antineoplastic compound, hydroxyurea in animals from many taxonomic groups. Hydroxyurea occurs in all the organisms we have examined including invertebrates (molluscs and crustaceans), fishes from several major groups, amphibians and mammals. The species with highest concentrations was an elasmobranch (sharks, skates and rays), the little skate Leucoraja erinacea with levels up to 250 μM, high enough to have antiviral, antimicrobial and antineoplastic effects based on in vitro studies. Embryos of L. erinacea showed increasing levels of hydroxyurea with development, indicating the capacity for hydroxyurea synthesis. Certain tissues of other organisms (e.g. skin of the frog (64 μM), intestine of lobster (138 μM) gills of the surf clam (100 μM)) had levels high enough to have antiviral effects based on in vitro studies. Hydroxyurea is widely used clinically in the treatment of certain human cancers, sickle cell anemia, psoriasis, myeloproliferative diseases, and has been investigated as a potential treatment of HIV infection and its presence at high levels in tissues of elasmobranchs and other organisms suggests a novel mechanism for fighting disease that may explain the disease resistance of some groups. In light of the known production of nitric oxide from exogenously applied hydroxyurea, endogenous hydoxyurea may play a hitherto unknown role in nitric oxide dynamics.

  15. High resolution analysis of northern Patagonia lake sediments

    Science.gov (United States)

    Jarvis, S. W.; Croudace, I. W.; Langdon, P. G.; Rindby, A.

    2009-04-01

    activity in the catchment. Variation of elemental composition of these ‘glacial' layers is also clear from the Itrax data. It therefore appears that there have been significant reglaciation events in the catchment since the last glacial maximum. Many cores contain tephra layers, identified both visually and from the Itrax scans. Some of these have been confirmed as volcanic ash from the 1991 eruption of Mt Hudson, which at 45°54'S, 72°58'W is the southern-most volcano in the Chilean Andes and only 140km from the study area. Further work is underway to confirm and identify the source and age of other suspected tephra layers. Sediment accumulation rates in the upper parts of the cores are of the order of 1mm/yr (as determined by lead-210, caesium-137 dating and the 1991 Hudson tephra). Given XRF scan resolutions of up to 200μm there is thus the potential for investigation of sub-annual variability. Funding has been obtained to determine carbon-14 dates for the lower parts of the longer cores. The reproducibility and accuracy of the Itrax data has been validated using conventional WD-XRF spectrometry and the work presented will also include geochemical interpretation of the XRF data and comparison with recorded and proxy-inferred climate data for the region.

  16. Developing a Scenario for widespread use: Best practices, lessons learned

    Science.gov (United States)

    Perry, S.; Jones, L.; Cox, D.

    2011-01-01

    The ShakeOut Scenario is probably the most widely known and used earthquake scenario created to date. Much of the credit for its widespread dissemination and application lies with scenario development criteria that focused on the needs and involvement of end users and with a suite of products that tailored communication of the results to varied end users, who ranged from emergency managers to the general public, from corporations to grassroots organizations. Products were most effective when they were highly visual, when they emphasized the findings of social scientists, and when they communicated the experience of living through the earthquake. This paper summarizes the development criteria and the products that made the ShakeOut Scenario so widely known and used, and it provides some suggestions for future improvements. ?? 2011, Earthquake Engineering Research Institute.

  17. Widespread episodic thiamine deficiency in Northern Hemisphere wildlife

    Science.gov (United States)

    Balk, Lennart; Hägerroth, Per-Åke; Gustavsson, Hanna; Sigg, Lisa; Åkerman, Gun; Ruiz Muñoz, Yolanda; Honeyfield, Dale C.; Tjärnlund, Ulla; Oliveira, Kenneth; Ström, Karin; McCormick, Stephen D.; Karlsson, Simon; Ström, Marika; van Manen, Mathijs; Berg, Anna-Lena; Halldórsson, Halldór P.; Strömquist, Jennie; Collier, Tracy K.; Börjeson, Hans; Mörner, Torsten; Hansson, Tomas

    2016-12-01

    Many wildlife populations are declining at rates higher than can be explained by known threats to biodiversity. Recently, thiamine (vitamin B1) deficiency has emerged as a possible contributing cause. Here, thiamine status was systematically investigated in three animal classes: bivalves, ray-finned fishes, and birds. Thiamine diphosphate is required as a cofactor in at least five life-sustaining enzymes that are required for basic cellular metabolism. Analysis of different phosphorylated forms of thiamine, as well as of activities and amount of holoenzyme and apoenzyme forms of thiamine-dependent enzymes, revealed episodically occurring thiamine deficiency in all three animal classes. These biochemical effects were also linked to secondary effects on growth, condition, liver size, blood chemistry and composition, histopathology, swimming behaviour and endurance, parasite infestation, and reproduction. It is unlikely that the thiamine deficiency is caused by impaired phosphorylation within the cells. Rather, the results point towards insufficient amounts of thiamine in the food. By investigating a large geographic area, by extending the focus from lethal to sublethal thiamine deficiency, and by linking biochemical alterations to secondary effects, we demonstrate that the problem of thiamine deficiency is considerably more widespread and severe than previously reported.

  18. Widespread episodic thiamine deficiency in Northern Hemisphere wildlife

    Science.gov (United States)

    Balk, Lennart; Hägerroth, Per-Åke; Gustavsson, Hanna; Sigg, Lisa; Akerman, Gun; Ruiz Muñoz, Yolanda; Honeyfield, Dale C.; Tjarnlund, Ulla; Oliveira, Kenneth; Strom, Karin; McCormick, Stephen D.; Karlsson, Simon; Strom, Marika; van Manen, Mathijs; Berg, Anna-Lena; Halldórsson, Halldór P.; Stromquist, Jennie; Collier, Tracy K.; Borjeson, Hans; Morner, Torsten; Hansson, Tomas

    2016-01-01

    Many wildlife populations are declining at rates higher than can be explained by known threats to biodiversity. Recently, thiamine (vitamin B1) deficiency has emerged as a possible contributing cause. Here, thiamine status was systematically investigated in three animal classes: bivalves, ray-finned fishes, and birds. Thiamine diphosphate is required as a cofactor in at least five life-sustaining enzymes that are required for basic cellular metabolism. Analysis of different phosphorylated forms of thiamine, as well as of activities and amount of holoenzyme and apoenzyme forms of thiamine-dependent enzymes, revealed episodically occurring thiamine deficiency in all three animal classes. These biochemical effects were also linked to secondary effects on growth, condition, liver size, blood chemistry and composition, histopathology, swimming behaviour and endurance, parasite infestation, and reproduction. It is unlikely that the thiamine deficiency is caused by impaired phosphorylation within the cells. Rather, the results point towards insufficient amounts of thiamine in the food. By investigating a large geographic area, by extending the focus from lethal to sublethal thiamine deficiency, and by linking biochemical alterations to secondary effects, we demonstrate that the problem of thiamine deficiency is considerably more widespread and severe than previously reported.

  19. Geophysical evidence for widespread reversely magnetised pyroclastics in the western Taupo Volcanic Zone (New Zealand)

    International Nuclear Information System (INIS)

    Soengkono, S.; Hochstein, M.P.; Smith, I.E.M.; Itaya, T.

    1992-01-01

    Low-altitude aeromagnetic data show that negative residual anomalies are widespread over the western Taupo Volcanic Zone, New Zealand. Paleomagnetic study of eight rhyolitic ignimbrite units and two lava flows which are exposed in this area, together with new K-Ar dates of four of the ignimbrite units, indicate that the two lava units and seven of the ignimbrite units were erupted during the Matuyama geomagnetic epoch (>0.73 Ma B.P.) and suggest that rhyolitic volcanism in the western Taupo Volcanic Zone began as early as 1.6 Ma B.P. These results provide the basis for an interpretation of our aeromagnetic data which confirms the hypothesis that the magnetic anomalies observed in the western Taupo Volcanic Zone are caused by widespread, thick, reversely magnetised pyroclastic and lava flows. Magnetic modelling also allows thickness estimates of the younger, normally magnetised cover rocks which reach a maximum thickness of the order of 0.5 km in the Mangakino area. The magnetic structure of these volcanic rocks defines approximately the lateral extent of the Mangakino Volcanic Centre. (author). 41 refs., 2 figs., 3 tabs

  20. Layer-by-layer strippable Ag multilayer films fabricated by modular assembly.

    Science.gov (United States)

    Li, Yan; Chen, Xiaoyan; Li, Qianqian; Song, Kai; Wang, Shihui; Chen, Xiaoyan; Zhang, Kai; Fu, Yu; Jiao, Yong-Hua; Sun, Ting; Liu, Fu-Chun; Han, En-Hou

    2014-01-21

    We have developed a new method to fabricate multilayer films, which uses prepared thin films as modular blocks and transfer as operation mode to build up multilayer structures. In order to distinguish it from the in situ fabrication manner, this method is called modular assembly in this study. On the basis of such concept, we have fabricated a multilayer film using the silver mirror film as the modular block and poly(lactic acid) as the transfer tool. Due to the special double-layer structure of the silver mirror film, the resulting multilayer film had a well-defined stratified architecture with alternate porous/compact layers. As a consequence of the distinct structure, the interaction between the adjacent layers was so weak that the multilayer film could be layer-by-layer stripped. In addition, the top layer in the film could provide an effective protection on the morphology and surface property of the underlying layers. This suggests that if the surface of the film was deteriorated, the top layer could be peeled off and the freshly exposed surface would still maintain the original function. The successful preparation of the layer-by-layer strippable silver multilayer demonstrates that modular assembly is a feasible and effective method to build up multilayer films capable of creating novel and attractive micro/nanostructures, having great potential in the fabrication of nanodevices and coatings.

  1. The double layers in the plasma sheet boundary layer during magnetic reconnection

    Science.gov (United States)

    Guo, J.; Yu, B.

    2014-11-01

    We studied the evolutions of double layers which appear after the magnetic reconnection through two-dimensional electromagnetic particle-in-cell simulation. The simulation results show that the double layers are formed in the plasma sheet boundary layer after magnetic reconnection. At first, the double layers which have unipolar structures are formed. And then the double layers turn into bipolar structures, which will couple with another new weak bipolar structure. Thus a new double layer or tripolar structure comes into being. The double layers found in our work are about several ten Debye lengths, which accords with the observation results. It is suggested that the electron beam formed during the magnetic reconnection is responsible for the production of the double layers.

  2. Reconstructing an Explosive Basaltic Eruption in the Pinacate Volcanic Field, NW Sonora, Mexico

    Science.gov (United States)

    Zawacki, E. E.; Clarke, A. B.; Arrowsmith, R.; Lynch, D. J.

    2017-12-01

    Tephra deposits from explosive volcanic eruptions provide a means to reconstruct eruption characteristics, such as column height and erupted volume. Parameters like these are essential in assessing the explosivity of past eruptions and associated volcanic hazards. We applied such methods to a basaltic tephra deposit from one of the youngest eruptions in the Pinacate volcanic field (NW Sonora, Mexico). This roughly circular tephra blanket extends 13 km E-W and 13 km N-S, and covers an area of at least 135 km2. The source vent of this eruption is hypothesized to be the Tecolote volcano (lat 31.877, long -113.362), which is dated to 27 ± 6 ka (40Ar/39Ar). Fifty-three pits were dug across the extent of the tephra deposit to measure its thickness, record stratigraphy, characterize grain size distribution, and determine maximum clast size. Isopleth and isopach maps were created from these data to determine the column height (>9 km), estimate mass eruption rate (>2.1x106 kg/s), and calculate the erupted volume (>4.2x10-2 km3). Stratigraphic descriptions support two distinct episodes of tephra production. Unit A is dispersed in an approximately circular pattern ( 6.5 km radius) with its center shifted to the east of the vent. The distribution of Unit B is oblate ( 9.5 km major axis, 4.5 km minor axis) and trends to the southeast of the vent. Lava samples were collected from each of the seven Tecolote flows for XRF and ICP-MS geochemical analyses. These samples were compared to geochemical signatures from a Tecolote bomb, tephra from Units A and B, and cinder from the La Laja cone, which is the youngest dated cone in the field at 12 ± 4 ka (40Ar/39Ar). The La Laja sample is geochemically distinct from all Tecolote samples, confirming that it did not contribute to the two tephra units. Tephra from Unit A and Unit B have distinct signatures and fit within the geochemical evolution of the Tecolote lavas, supporting two explosive episodes from the Tecolote volcano, which has

  3. The SHOCT domain: a widespread domain under-represented in model organisms.

    Directory of Open Access Journals (Sweden)

    Ruth Y Eberhardt

    Full Text Available We have identified a new protein domain, which we have named the SHOCT domain (Short C-terminal domain. This domain is widespread in bacteria with over a thousand examples. But we found it is missing from the most commonly studied model organisms, despite being present in closely related species. It's predominantly C-terminal location, co-occurrence with numerous other domains and short size is reminiscent of the Gram-positive anchor motif, however it is present in a much wider range of species. We suggest several hypotheses about the function of SHOCT, including oligomerisation and nucleic acid binding. Our initial experiments do not support its role as an oligomerisation domain.

  4. Relationships between widespread pain and thresholds pain tolerance on tender points in Portuguese women with fibromyalgia: impact on daily life.

    Directory of Open Access Journals (Sweden)

    Pablo Tomas-Carus

    2015-07-01

    Full Text Available Objectives: to establish a relationship between widespread pain subjectively perceived and threshold pain tolerance on tender points, and to determine whether there are differences in threshold pain tolerance on tender points between the upper and lower body, as well as between the dominant and non-dominant side, and whether these differences have an impact on the daily life of Portuguese women with fibromyalgia (FM. Material e Methods: thirty-one women with FM aged between 34 and 67 years volunteered for the study. Threshold pain tolerance was assessed at critical points using a digital algometer pressure; the widespread pain index (WPI was constructed by the addition of 19 painful body regions; and the impact on the daily life assessed by the Portuguese version of the Fibromyalgia Impact Questionnaire (FIQ, with individual interviews. Results: significant differences between the percentage of threshold pain tolerance of the whole body and the scales of widespread pain subjectively perceived were observed, showing that the widespread pain subjectively perceived by patients was between +25.9% and +27.5%. Also, significant differences between threshold pain tolerance of tender points located on the upper and lower body (1.9 ± 0.5 kg/cm2 vs. 2.6 ± 0.7 kg/cm2; respectively were observed. However, no significant differences were found between threshold pain tolerance of tender points located on dominant and non-dominant sides (2.1 ± 0.5 kg/cm2 e 2.1 ± 0.6 kg/cm2; respectively. Additionally, the analysis showed significant correlations between pain and patient`s daily life in: FIQ total score, physical function, feel good, job ability and fatigue. Conclusions: the women with FM show higher widespread pain subjectively perceived than threshold pain tolerance on tender points. Furthermore, the pain suffered by the patients with FM, especially that located on the upper body, either on the dominant or on the non-dominant side, has a negative

  5. Registered report: Widespread potential for growth-factor-driven resistance to anticancer kinase inhibitors2

    OpenAIRE

    sprotocols

    2015-01-01

    Authors: Edward Greenfield, Erin Griner, The Reproducibility Project: Cancer Biology† ### Abstract The [Reproducibility Project: Cancer Biology](https://osf.io/e81xl/wiki/home/) seeks to address growing concerns about reproducibility in scientific research by conducting replications of 50 papers in the field of cancer biology published between 2010 and 2012. This Registered Report describes the proposed replication plan of key experiments from “Widespread potential for growth-factor-d...

  6. Widespread osteonecrosis of the foot in systemic lupus erythematosus: Radiographic and gross pathologic correlation

    Energy Technology Data Exchange (ETDEWEB)

    Resnick, D; Pineda, C; Trudell, D

    1985-01-01

    A patient with systemic lupus erythematosus required an amputation of the foot related to the presence of vascular disease and infection. Radiographs obtained prior to amputation revealed osteonecrosis in virtually every bone of the foot. Radiographic-pathologic correlation documented this widespread osseous involvement. Although ischemic necrosis of bone is a well-known feature of systemic lupus erythematosus, its localization in the small bones of the foot is rare.

  7. Widespread osteonecrosis of the foot in systemic lupus erythematosus: Radiographic and gross pathologic correlation

    International Nuclear Information System (INIS)

    Resnick, D.; Pineda, C.; Trudell, D.; California Univ., San Diego, La Jolla

    1985-01-01

    A patient with systemic lupus erythematosus required an amputation of the foot related to the presence of vascular disease and infection. Radiographs obtained prior to amputation revealed osteonecrosis in virtually every bone of the foot. Radiographic-pathologic correlation documented this widespread osseous involvement. Although ischemic necrosis of bone is a well-known feature of systemic lupus erythematosus, its localization in the small bones of the foot is rare. (orig.)

  8. Synthesis and study of photovoltaic performance on various photoelectrode materials for DSSCs: Optimization of compact layer on nanometer thickness

    Science.gov (United States)

    Surya, Subramanian; Thangamuthu, Rangasamy; Senthil Kumar, Sakkarapalayam Murugesan; Murugadoss, Govindhasamy

    2017-02-01

    Dye-sensitized solar cells (DSSCs) have gained widespread attention in recent years because of their low production costs, ease of fabrication process and tuneable optical properties, such as colour and transparency. In this work, we explored a strategy wherein nanoparticles of pure TiO2, TiO2sbnd SnO2 nanocomposite, Sn (10%) doped TiO2 and SnO2 synthesized by the simple chemical precipitation method were employed as photoelectrodes to enhance the photovoltaic conversion efficiency of solar cells. The nanoparticles were characterized by different characterization techniques such as X-ray diffraction (XRD), scanning electron microscopy (SEM with EDX), transmission electron microscopy (TEM), high resolution electron microscopy (HR-TEM), UV-Visible absorbance (UV-vis), photoluminescence (PL), thermal gravimetric analysis (TGA) and X-ray photoelectron spectroscopy (XPS) measurements. Moreover, we also demonstrated the effect of thin compact layer in DSSCs by architecture with various precursor materials of different concentrations. We found that the optimized compact layer material TDIP (titanium diisopropoxide) with a concentration of 0.3 M % is produced the highest efficiency of 2.25% for Sn (10%) doped TiO2 electron transport material (ETM) and 4.38% was achieved for pure TiO2 ETM using SnCl2 compact layer with 0.1 M concentrations.

  9. The compositionally zoned eruption of 1912 in the Valley of Ten Thousand Smokes, Katmai National Park, Alaska

    Science.gov (United States)

    Hildreth, W.

    1983-01-01

    On June 6-8, 1912, ??? 15 km3 of magma erupted from the Novarupta caldera at the head of the Valley of Ten Thousand Smokes (VTTS), producing ??? 20 km3 of air-fall tephra and 11-15 km3 of ash-flow tuff within ??? 60 hours. Three discrete periods of ash-fall at Kodiak correlate, respectively, with Plinian tephra layers designated A, CD, and FG by Curtis (1968) in the VTTS. The ash-flow sequence overlapped with but outlasted pumice fall A, terminating within 20 hours of the initial outbreak and prior to pumice fall C. Layers E and H consist mostly of vitric dust that settled during lulls, and Layer B is the feather edge of the ash flow. The fall units filled and obscured the caldera, but arcuate and radial fissures outline a 6-km2 depression. The Novarupta lava dome and its ejecta ring were emplaced later within the depression. At Mt. Katmai, 10 km east of the 1912 vent, a 600-m-deep caldera of similar area also collapsed at about this time, probably owing to hydraulic connection with the venting magma system; but all known ejecta are thought to have erupted at Novarupta. Mingling of three distinctive magmas during the eruption produced an abundance of banded pumice, and mechanical mixing of chilled ejecta resulted in deposits with a wide range of bulk composition. Pumice in the initial fall unit (A) is 100% rhyolite, but fall units atop the ash flow are > 98% dacite; black andesitic scoria is common only in the ash flows and in near-vent air-fall tephra. Pumice counts show the first half of the ash-flow deposit to be 91-98% rhyolite, but progressive increases of dacite and andesite eventually reduced the rhyolitic component to 20 km to the lowermost VTTS, and deposited 1-8 m of debris there. Rhyolitic ejecta contain only 1-2% phenocrysts but andesite and dacite have 30-45%. Quartz is present and augite absent only in the rhyolite, but all ejecta contain plagioclase, orthopyroxene, titanomagnetite, ilmenite, apatite, and pyrrhotite; rare olivine occurs in the

  10. Position-dependent termination and widespread obligatory frameshifting in Euplotes translation

    Energy Technology Data Exchange (ETDEWEB)

    Lobanov, Alexei V.; Heaphy, Stephen M.; Turanov, Anton A.; Gerashchenko, Maxim V.; Pucciarelli, Sandra; Devaraj, Raghul R.; Xie, Fang; Petyuk, Vladislav A.; Smith, Richard D.; Klobutcher, Lawrence A.; Atkins, John F.; Miceli, Cristina; Hatfield, Dolph L.; Baranov, Pavel V.; Gladyshev, Vadim N.

    2016-11-21

    The ribosome can change its reading frame during translation in a process known as programmed ribosomal frameshifting. These rare events are supported by complex mRNA signals. However, we found that the ciliates Euplotes crassus and Euplotes focardii exhibit widespread frameshifting at stop codons. 47 different codons preceding stop signals resulted in either +1 or +2 frameshifts, and +1 frameshifting at AAA was the most frequent. The frameshifts showed unusual plasticity and rapid evolution, and had little influence on translation rates. The proximity of a stop codon to the 3' mRNA end, rather than its occurrence or sequence context, appeared to designate termination. Thus, a ‘stop codon’ is not a sufficient signal for translation termination, and the default function of stop codons in Euplotes is frameshifting, whereas termination is specific to certain mRNA positions and probably requires additional factors.

  11. Layer-by-layer assembled biopolymer microcapsule with separate layer cavities generated by gas-liquid microfluidic approach.

    Science.gov (United States)

    Wang, Yifeng; Zhou, Jing; Guo, Xuecheng; Hu, Qian; Qin, Chaoran; Liu, Hui; Dong, Meng; Chen, Yanjun

    2017-12-01

    In this work, a layer-by-layer (LbL) assembled biopolymer microcapsule with separate layer cavities is generated by a novel and convenient gas-liquid microfluidic approach. This approach exhibits combined advantages of microfluidic approach and LbL assembly method, and it can straightforwardly build LbL-assembled capsules in mild aqueous environments at room temperature. In particular, using this approach we can build the polyelectrolyte multilayer capsule with favorable cavities in each layer, and without the need for organic solvent, emulsifying agent, or sacrificial template. Various components (e.g., drugs, proteins, fluorescent dyes, and nanoparticles) can be respectively encapsulated in the separate layer cavities of the LbL-assembled capsules. Moreover, the encapsulated capsules present the ability as colorimetric sensors, and they also exhibit the interesting release behavior. Therefore, the LbL-assembled biopolymer capsule is a promising candidate for biomedical applications in targeted delivery, controlled release, and bio-detection. Copyright © 2017 Elsevier B.V. All rights reserved.

  12. Amphibian Chytrid Fungus in Madagascar neither Shows Widespread Presence nor Signs of Certain Establishment.

    Science.gov (United States)

    Kolby, Jonathan E; Skerratt, Lee F

    2015-01-01

    The global spread of amphibian chytrid fungus (Batrachochytrium dendrobatidis, Bd) is associated with amphibian mass mortality, population decline, and extinction. Over the past decade, concern has been expressed for the potential introduction of Bd to Madagascar, a global hotspot of amphibian biodiversity. Following years without detection, widespread Bd presence in Madagascar has now been reported (Bletz et al. 2015a), raising international conservation concern. Before reacting to this finding with a significant management response, the accuracy and context of the data warrant cautious review. Re-examination of a 10-year dataset together with results from more recent surveillance (Kolby et al. 2015) does not yet demonstrate widespread Bd presence. Detection of Bd at "positive" locations in Madagascar has been inconsistent for unknown reasons. Whether Bd is established in Madagascar (i.e. populations are self-sustaining) or instead requires continued introduction to persist also remains uncertain. The deployment of emergency conservation rescue initiatives is expected to target areas where the distribution of Bd and the risk of chytridiomycosis endangering amphibians is believed to overlap. Thus, erroneous description of Bd presence would misdirect limited conservation resources. Standardized surveillance and confirmatory surveys are now imperative to reliably characterize the distribution, potential spread, virulence and overall risk of Bd to amphibians in Madagascar.

  13. Amphibian Chytrid Fungus in Madagascar neither Shows Widespread Presence nor Signs of Certain Establishment.

    Directory of Open Access Journals (Sweden)

    Jonathan E Kolby

    Full Text Available The global spread of amphibian chytrid fungus (Batrachochytrium dendrobatidis, Bd is associated with amphibian mass mortality, population decline, and extinction. Over the past decade, concern has been expressed for the potential introduction of Bd to Madagascar, a global hotspot of amphibian biodiversity. Following years without detection, widespread Bd presence in Madagascar has now been reported (Bletz et al. 2015a, raising international conservation concern. Before reacting to this finding with a significant management response, the accuracy and context of the data warrant cautious review. Re-examination of a 10-year dataset together with results from more recent surveillance (Kolby et al. 2015 does not yet demonstrate widespread Bd presence. Detection of Bd at "positive" locations in Madagascar has been inconsistent for unknown reasons. Whether Bd is established in Madagascar (i.e. populations are self-sustaining or instead requires continued introduction to persist also remains uncertain. The deployment of emergency conservation rescue initiatives is expected to target areas where the distribution of Bd and the risk of chytridiomycosis endangering amphibians is believed to overlap. Thus, erroneous description of Bd presence would misdirect limited conservation resources. Standardized surveillance and confirmatory surveys are now imperative to reliably characterize the distribution, potential spread, virulence and overall risk of Bd to amphibians in Madagascar.

  14. ON Cone Bipolar Cell Axonal Synapses in the OFF Inner Plexiform Layer of the Rabbit Retina

    Science.gov (United States)

    Lauritzen, J. Scott; Anderson, James R.; Jones, Bryan W.; Watt, Carl B.; Mohammed, Shoeb; Hoang, John V.; Marc, Robert E.

    2012-01-01

    Analysis of the rabbit retinal connectome RC1 reveals that the division between the ON and OFF inner plexiform layer (IPL) is not structurally absolute. ON cone bipolar cells make non-canonical axonal synapses onto specific targets and receive amacrine cell synapses in the nominal OFF layer, creating novel motifs, including inhibitory crossover networks. Automated transmission electron microscope (ATEM) imaging, molecular tagging, tracing, and rendering of ≈ 400 bipolar cells reveals axonal ribbons in 36% of ON cone bipolar cells, throughout the OFF IPL. The targets include GABA-positive amacrine cells (γACs), glycine-positive amacrine cells (GACs) and ganglion cells. Most ON cone bipolar cell axonal contacts target GACs driven by OFF cone bipolar cells, forming new architectures for generating ON-OFF amacrine cells. Many of these ON-OFF GACs target ON cone bipolar cell axons, ON γACs and/or ON-OFF ganglion cells, representing widespread mechanisms for OFF to ON crossover inhibition. Other targets include OFF γACs presynaptic to OFF bipolar cells, forming γAC-mediated crossover motifs. ON cone bipolar cell axonal ribbons drive bistratified ON-OFF ganglion cells in the OFF layer and provide ON drive to polarity-appropriate targets such as bistratified diving ganglion cells (bsdGCs). The targeting precision of ON cone bipolar cell axonal synapses shows that this drive incidence is necessarily a joint distribution of cone bipolar cell axonal frequency and target cell trajectories through a given volume of the OFF layer. Such joint distribution sampling is likely common when targets are sparser than sources and when sources are coupled, as are ON cone bipolar cells. PMID:23042441

  15. Reconstruction of Ancestral Hydrothermal Systems on Mount Rainier Using Hydrothermally Altered Rocks in Holocene Debris Flows and Tephras

    Science.gov (United States)

    John, D. A.; Breit, G. N.; Sisson, T. W.; Vallance, J. W.; Rye, R. O.

    2005-12-01

    Mount Rainier is the result of episodic stages of edifice growth during periods of high eruptive activity and edifice destruction during periods of relative magmatic quiescence over the past 500 kyr. Edifice destruction occurred both by slow erosion and by catastrophic collapses, some of which were strongly influenced by hydrothermal alteration. Several large-volume Holocene debris-flow deposits contain abundant clasts of hydrothermally altered rocks, most notably the 4-km3 clay-rich Osceola Mudflow which formed by collapse of the northeast side and upper 1000+ m of the edifice about 5600 ya and flowed >120 km downstream into Puget Sound. Mineral assemblages and stable isotope data of hydrothermal alteration products in Holocene debris-flow deposits indicate formation in distinct hydrothermal environments, including magmatic-hydrothermal, steam-heated (including a large fumarolic component), magmatic steam (including a possible fumarolic component), and supergene. The Osceola Mudflow and phreatic components of coeval tephras contain the highest-temperature and inferred most deeply formed alteration minerals; assemblages include magmatic-hydrothermal quartz-alunite, quartz-topaz, quartz-pyrophyllite and quartz-illite (all +pyrite), in addition to steam-heated opal-alunite-kaolinite and abundant smectite-pyrite. In contrast, the Paradise lahar, which formed by a collapse of the surficial upper south side of the edifice, contains only steam-heated assemblages including those formed largely above the water table from condensation of fumarolic vapor (opal-alunite-jarosite). Younger debris-flow deposits on the west side of the volcano (Round Pass lahar and Electron Mudflow) contain only smectite-pyrite alteration, whereas an early 20th century rock avalanche on Tahoma Glacier also contains magmatic-hydrothermal alteration that is exposed in the avalanche headwall of Sunset Amphitheater. Mineralogy and isotopic composition of the alteration phases, geologic and

  16. Characterizing permafrost active layer dynamics and sensitivity to landscape spatial heterogeneity in Alaska

    Science.gov (United States)

    Yi, Yonghong; Kimball, John S.; Chen, Richard H.; Moghaddam, Mahta; Reichle, Rolf H.; Mishra, Umakant; Zona, Donatella; Oechel, Walter C.

    2018-01-01

    An important feature of the Arctic is large spatial heterogeneity in active layer conditions, which is generally poorly represented by global models and can lead to large uncertainties in predicting regional ecosystem responses and climate feedbacks. In this study, we developed a spatially integrated modeling and analysis framework combining field observations, local-scale ( ˜ 50 m resolution) active layer thickness (ALT) and soil moisture maps derived from low-frequency (L + P-band) airborne radar measurements, and global satellite environmental observations to investigate the ALT sensitivity to recent climate trends and landscape heterogeneity in Alaska. Modeled ALT results show good correspondence with in situ measurements in higher-permafrost-probability (PP ≥ 70 %) areas (n = 33; R = 0.60; mean bias = 1.58 cm; RMSE = 20.32 cm), but with larger uncertainty in sporadic and discontinuous permafrost areas. The model results also reveal widespread ALT deepening since 2001, with smaller ALT increases in northern Alaska (mean trend = 0.32±1.18 cm yr-1) and much larger increases (> 3 cm yr-1) across interior and southern Alaska. The positive ALT trend coincides with regional warming and a longer snow-free season (R = 0.60 ± 0.32). A spatially integrated analysis of the radar retrievals and model sensitivity simulations demonstrated that uncertainty in the spatial and vertical distribution of soil organic carbon (SOC) was the largest factor affecting modeled ALT accuracy, while soil moisture played a secondary role. Potential improvements in characterizing SOC heterogeneity, including better spatial sampling of soil conditions and advances in remote sensing of SOC and soil moisture, will enable more accurate predictions of active layer conditions and refinement of the modeling framework across a larger domain.

  17. Layered-Double-Hydroxide Nanosheets as Efficient Visible-Light-Driven Photocatalysts for Dinitrogen Fixation.

    Science.gov (United States)

    Zhao, Yufei; Zhao, Yunxuan; Waterhouse, Geoffrey I N; Zheng, Lirong; Cao, Xingzong; Teng, Fei; Wu, Li-Zhu; Tung, Chen-Ho; O'Hare, Dermot; Zhang, Tierui

    2017-11-01

    Semiconductor photocatalysis attracts widespread interest in water splitting, CO 2 reduction, and N 2 fixation. N 2 reduction to NH 3 is essential to the chemical industry and to the Earth's nitrogen cycle. Industrially, NH 3 is synthesized by the Haber-Bosch process under extreme conditions (400-500 °C, 200-250 bar), stimulating research into the development of sustainable technologies for NH 3 production. Herein, this study demonstrates that ultrathin layered-double-hydroxide (LDH) photocatalysts, in particular CuCr-LDH nanosheets, possess remarkable photocatalytic activity for the photoreduction of N 2 to NH 3 in water at 25 °C under visible-light irradiation. The excellent activity can be attributed to the severely distorted structure and compressive strain in the LDH nanosheets, which significantly enhances N 2 chemisorption and thereby promotes NH 3 formation. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  18. Multi-layers castings

    Directory of Open Access Journals (Sweden)

    J. Szajnar

    2010-01-01

    Full Text Available In paper is presented the possibility of making of multi-layers cast steel castings in result of connection of casting and welding coating technologies. First layer was composite surface layer on the basis of Fe-Cr-C alloy, which was put directly in founding process of cast carbon steel 200–450 with use of preparation of mould cavity method. Second layer were padding welds, which were put with use of TIG – Tungsten Inert Gas surfacing by welding technology with filler on Ni matrix, Ni and Co matrix with wolfram carbides WC and on the basis on Fe-Cr-C alloy, which has the same chemical composition with alloy, which was used for making of composite surface layer. Usability for industrial applications of surface layers of castings were estimated by criterion of hardness and abrasive wear resistance of type metal-mineral.

  19. Holocene Tsunami Deposits From Large Tsunamis Along the Kuril Subduction Zone, Northeast Japan

    Science.gov (United States)

    Nanayama, F.; Furukawa, R.; Satake, K.; Soeda, Y.; Shigeno, K.

    2003-12-01

    Holocene tsunami deposits in eastern Hokkaido between Nemuro and Tokachi show that the Kuril subduction zone repeatedly produced earthquakes and tsunamis larger than those recorded in this region since AD 1804 (Nanayama et al., Nature, 424, 660-663, 2003). Twenty-two postulated tsunami sand layers from the past 9500 years are preserved on lake bottom near Kushiro City, and about ten postulated tsunami sand layers from the past 3000 years are preserved in peat layers on the coastal marsh of Kiritappu. We dated these ten tsunami deposits (named Ts1 to Ts10 from shallower to deeper) in peat layers by radiocarbon and tephrochronology, correlated them with historical earthquakes and tsunamis, and surveyed their spatial distribution to estimate the tsunamisO inland inundation limits. Ts10 and Ts9 are under regional tephra Ta-c2 (ca. 2.5 ka) and represent prehistorical events. Ts8 to Ts5 are between two regional tephra layers Ta-c2 and B-Tm (ca. 9th century). In particular, Ts5 is found just below B-Tm, so it is dated 9th century (Heian era). Ts4 is dated ca 13th century (Kamakura era), while Ts3, found just below Us-b and Ta-b (AD 1667-1663), is dated 17th century (Edo era). Ts2 is dated 19th century (Edo era) and may correspond to the AD 1843 Tempo Tokachi-oki earthquake (Mt 8.0) recorded in a historical document Nikkanki of Kokutai-ji temple at Akkeshi. Ts1 is inferred 20th century and may correspond to the tsunami from the AD 1960 Chilean earthquake (M 9.5) or the AD 1952 Tokachi-oki earthquake (Mt 8.2). Our detailed surveys indicate that Ts3 and Ts4 can be traced more than 3 km from the present coast line in Kirittapu marsh, much longer than the limits (< 1 km) of recent deposits Ts1 and Ts2 or documented inundation of the 19th and 20th century tsunamis. The recurrence intervals of great tsunami inundation are about 400 to 500 years, longer than that of typical interplate earthquakes along the Kuril subduction zone. The longer interval and the apparent large tsunami

  20. Palynostratigraphy and paleoenvironments of Wellington, New Zealand, during the last 80 ka, based on palynology of drillholes

    International Nuclear Information System (INIS)

    Mildenhall, D.C.

    1994-01-01

    About 20 pollen profiles from the Wellington area are correlated and zoned according to their pollen characteristics. Sequences from many of the larger sedimentary deposits are shown to contain little or no sediment of late Last Glacial and early Postglacial age, while late Postglacial sedimentation is restricted to a few localities. Sediments of middle and early Last Glacial age are well represented and widespread over the Wellington area. Pollen diagrams from Last Glacial and Postglacial sediments are zoned as follows: Zone A, 80,000-60,000 yr B.P. (lower end of range more likely) and provisionally correlated with oxygen isotope stages 5a and basal 4; Zone B, 70,000-50,000 yr B.P. (lower end of range more likely), provisionally correlated with upper oxygen isotope stages 4 and basal stage 3; Zone C, a short zone just beyond the range of radiocarbon dating at the top of Zone B of 60,000-50,000 yr B.P., correlated with the middle of oxygen isotope stage 3; Zone D, 50,000-10,000 yr B.P., with a major period of nondeposition or erosion between c. 18,000 and 10,000 yr B.P., correlated with the upper part of oxygen isotope stages 3 and all of 2; Zone E, 10,000-1000 yr B.P. (Postglacial); Zone F, last 1000 years (human occupation zone). During this time the vegetation changed from a beech forest (Zone A1) to a shrub/grassland, with pollen from the dominant tree taxa being Nothofagus fusca type (Zone A2), N. menziesii with Phyllocladus (Zones B, C), Phyllocladus with N. menziesii (Zone D), Dacrydium cupressinum (Zone E), and Nothofagus fusca with D. cupressinum (Zone F). Climatic conditions during the Last Glaciation were generally colder, drier, and stormier relative to the present day. The virtual absence of sediment of this age suggests widespread nondeposition or erosion under unstable conditions. Zones B-D represent the harshest conditions, with temperatures averaging up to 5 degrees C less than the present day. Basal Postglacial conditions were the reverse, with

  1. [Do volcanic eruptions and wide-spread fires affect our climate?].

    Science.gov (United States)

    Primault, B

    1992-03-31

    During the first half of 1991, the press, radio and TV have often reported about large fires (Kuwait, forest fires in Portugal) or volcanic eruptions (Mount Unzen, Pinatubo). Starting with the facts, the author investigates first the kind of particles constituting such smoke clouds and in particular their size. He places the main cloud in the atmosphere and asks; the cloud remains near the soil, whether it reaches the upper layers of the troposphere or it breaks out into the stratosphere? The transport of the cloud depends on particle-size and of the winds blowing in the reached layer. All these clouds have an impact on the weather. The author analyses finally the credible influence of such clouds on weather elements: radiation and temperature as well as the extent of these effects. He corroborates his analysis by visual observations or measurements.

  2. Widespread local chronic stressors in Caribbean coastal habitats.

    Science.gov (United States)

    Chollett, Iliana; Collin, Rachel; Bastidas, Carolina; Cróquer, Aldo; Gayle, Peter M H; Jordán-Dahlgren, Eric; Koltes, Karen; Oxenford, Hazel; Rodriguez-Ramirez, Alberto; Weil, Ernesto; Alemu, Jahson; Bone, David; Buchan, Kenneth C; Creary Ford, Marcia; Escalante-Mancera, Edgar; Garzón-Ferreira, Jaime; Guzmán, Hector M; Kjerfve, Björn; Klein, Eduardo; McCoy, Croy; Potts, Arthur C; Ruíz-Rentería, Francisco; Smith, Struan R; Tschirky, John; Cortés, Jorge

    2017-01-01

    Coastal ecosystems and the livelihoods they support are threatened by stressors acting at global and local scales. Here we used the data produced by the Caribbean Coastal Marine Productivity program (CARICOMP), the longest, largest monitoring program in the wider Caribbean, to evidence local-scale (decreases in water quality) and global-scale (increases in temperature) stressors across the basin. Trend analyses showed that visibility decreased at 42% of the stations, indicating that local-scale chronic stressors are widespread. On the other hand, only 18% of the stations showed increases in water temperature that would be expected from global warming, partially reflecting the limits in detecting trends due to inherent natural variability of temperature data. Decreases in visibility were associated with increased human density. However, this link can be decoupled by environmental factors, with conditions that increase the flush of water, dampening the effects of human influence. Besides documenting environmental stressors throughout the basin, our results can be used to inform future monitoring programs, if the desire is to identify stations that provide early warning signals of anthropogenic impacts. All CARICOMP environmental data are now available, providing an invaluable baseline that can be used to strengthen research, conservation, and management of coastal ecosystems in the Caribbean basin.

  3. Automatic settlement analysis of single-layer armour layers

    NARCIS (Netherlands)

    Hofland, B.; van gent, Marcel

    2016-01-01

    A method to quantify, analyse, and present the settlement of single-layer concrete armour layers of coastal structures is presented. The use of the image processing technique for settlement analysis is discussed based on various modelling
    studies performed over the years. The accuracy of the

  4. Influences of volcanism on coal quality - Examples from the western United States

    International Nuclear Information System (INIS)

    Hildebrand, R.T.; Affolter, R.H.

    1986-01-01

    Several small Tertiary coal deposits in Idaho, Nevada, and Washington formed in fresh-water basins located near active continental (salic) volcanic centers. Metastable glassy material (tephra) ejected during volcanic eruptions was introduced into the coal-forming environment of these basins as ash falls. This tephra contributed to the high ash content of many of the coal beds, formed laterally persistent partings (''tonsteins'') in the coal, and constitutes a large part of the strata enclosing the deposits. In order to study the possible relationships between the presence of tephra and coal quality, chemical data for 65 coal samples from 12 of these deposits were compiled and statistically analyzed. The results indicate that, in addition to the high ash content, coal from Tertiary deposits containing appreciable amounts of tephra generally is enriched in many elements compared to 460 coal samples from 11 deposits of similar ages remote from volcanic activity

  5. Phytophthora capsici - Loss of Heterozygosity (LOH): A Widespread Mechanism for Rapid Adaptation (7th Annual SFAF Meeting, 2012)

    Energy Technology Data Exchange (ETDEWEB)

    Mudge, Joanne

    2012-06-01

    Joanne Mudge on "Phytophthora capsici - Loss of Heterozygosity (LOH): A Widespread Mechanism for Rapid Mutation" at the 2012 Sequencing, Finishing, Analysis in the Future Meeting held June 5-7, 2012 in Santa Fe, New Mexico.

  6. Novel Electrospun Dual-Layered Composite Nanofibrous Membrane Endowed with Electricity-Magnetism Bifunctionality at One Layer and Photoluminescence at the Other Layer.

    Science.gov (United States)

    Wang, Zijiao; Ma, Qianli; Dong, Xiangting; Li, Dan; Xi, Xue; Yu, Wensheng; Wang, Jinxian; Liu, Guixia

    2016-10-05

    Dual-layered composite nanofibrous membrane equipped with electrical conduction, magnetism and photoluminescence trifunctionality is constructed via electrospinning. The composite membrane consists of a polyaniline (PANI)/Fe 3 O 4 nanoparticles (NPs)/polyacrylonitrile (PAN) tuned electrical-magnetic bifunctional nanofibrous layer at one side and a Eu(TTA) 3 (TPPO) 2 /polyvinylpyrrolidone (PVP) photoluminescent nanofibrous layer at the other side, and the two layers are tightly combined face-to-face together into the novel dual-layered composite membrane with trifunctionality. The electric conductivity and magnetism of electrical-magnetic bifunctionality can be respectively tunable via modulating the respective PANI and Fe 3 O 4 NPs contents, and the highest electric conductivity approaches the order of 1 × 10 -2 S cm -1 . Predominant red emission at 615 nm can be obviously observed in the photoluminescent layer under 366 nm excitation. Moreover, the luminescent intensity of photoluminescent layer is almost unaffected by the electrical-magnetic bifunctional layer because of the fact that the photoluminescent materials have been successfully isolated from dark-colored PANI and Fe 3 O 4 NPs. The novel dual-layered composite nanofibrous membrane with trifunctionality has potentials in many fields. Furthermore, the design philosophy and fabrication method for the dual-layered multifunctional membrane provide a new and facile strategy toward other membranes with multifunctionality.

  7. Layer-by-Layer-Assembled High-Performance Broadband Antireflection Coatings

    KAUST Repository

    Shimomura, Hiroomi; Gemici, Zekeriyya; Cohen, Robert E.; Rubner, Michael F.

    2010-01-01

    uniformity, thickness control, roughness control, mechanical durability, and incorporation of a diverse set of functional organic molecules into nanoparticle thin films are major challenges. We have used the electrostatic layer-by-layer assembly technique

  8. Characteristics of the magnetospheric boundary layer and magnetopause layer as observed by Imp 6

    International Nuclear Information System (INIS)

    Eastman, T.E.; Hones, E.W. Jr.

    1979-01-01

    Imp 6 observations of the low-latitude magnetospheric boundary layer indicate that the plasma within it is supplied primarily by direct entry of magnetosheath plasma across the magnetopause layer. We define the magnetopause layer as the current layer (separating the magnetosheath from the boundary layer) through which the magnetic field shifts in direction. High temporal resolution (3-s average) data reveal that in a majority of Imp 6 magnetopause crossing, no distinct changes in electron density or energry spectra are observed at the magne opause layer. In all Imp 6 crossings, some magnetosheathlike plasma is observed earthward of the magnetopause layer, implying the existence of a boundary layer. Boundary layer electron energy spectra are often virtually indistinguishable from the adjacent magnetosheath spectra. Low-latitude boundary layer bulk plasma flow as observed by Imp 6 almost always has an antisunward component and often has a significant cross-field component. The boundary layer thickness is highly variable and is generally much larger than the magnetopause layer thickness. Energetic electron pitch angle distributions indicate that the low-latitude boundary layers is normally on closed field lines. We conclude that diffusive as well as nondiffusive processes probably contribute to the entry of magnetosheath plasma into the boundary layer

  9. Single Layered Versus Double Layered Intestinal Anastomosis: A Randomized Controlled Trial

    Science.gov (United States)

    Mohapatra, Vandana; Singh, Surendra; Rath, Pratap Kumar; Behera, Tapas Ranjan

    2017-01-01

    Introduction Gastrointestinal anastomosis is one of the most common procedures being performed in oesophagogastric, hepatobiliary, bariatric, small bowel and colorectal surgery; however, the safety and efficacy of single layer or double layer anastomotic technique is still unclear. Aim To assess and compare the efficacy, safety and cost effectiveness of single layered versus double layered intestinal anastomosis. Materials and Methods This prospective, double-blind, randomized controlled comparative study comprised of patients who underwent intestinal resection and anastomosis. They were randomly assigned to undergo either single layered extra-mucosal anastomosis (Group-A) or double layered intestinal anastomosis (Group-B). Primary outcome measures included average time taken for anastomosis, postoperative complications, mean duration of hospital stay and cost of suture material used; secondary outcome measures assessed the postoperative return of bowel function. Statistical analysis was done by Chi-square test and student t-test. Results A total of 97 participants were randomized. Fifty patients were allocated to single layered extramucosal continuous anastomosis (Group-A) and 47 patients to double layered anastomosis (Group-B). The patients in each group were well matched for age, sex and diagnosis. The mean time taken for anastomosis (15.12±2.27 minutes in Group-A versus 24.38±2.26 minutes in Group-B) and the length of hospital stay (5.90±1.43 days in Group-A versus 7.29±1.89 days in Group-B) was significantly shorter in Group-A {p-value anastomosis. However, there was no significant difference in the complication rates between the two groups. Conclusion It can be concluded that single layered extramucosal continuous intestinal anastomosis is equally safe and perhaps more cost effective than the conventional double layered method and may represent the optimal choice for routine surgical practice. PMID:28764239

  10. Semiconductor Three-Dimensional Photonic Crystals with Novel Layer-by-Layer Structures

    Directory of Open Access Journals (Sweden)

    Satoshi Iwamoto

    2016-05-01

    Full Text Available Three-dimensional photonic crystals (3D PhCs are a fascinating platform for manipulating photons and controlling their interactions with matter. One widely investigated structure is the layer-by-layer woodpile structure, which possesses a complete photonic bandgap. On the other hand, other types of 3D PhC structures also offer various possibilities for controlling light by utilizing the three dimensional nature of structures. In this article, we discuss our recent research into novel types of layer-by-layer structures, including the experimental demonstration of a 3D PhC nanocavity formed in a <110>-layered diamond structure and the realization of artificial optical activity in rotationally stacked woodpile structures.

  11. Thermal Tolerance in Widespread and Tropical Drosophila Species: Does Phenotypic Plasticity Increase with Latitude?

    DEFF Research Database (Denmark)

    Overgaard, Johannes; Kristensen, Torsten Nygård; Mitchell, Katherin A

    2011-01-01

    The distribution of insects can often be related to variation in their response to thermal extremes, which in turn may reflect differences in plastic responses or innate variation in resistance. Species with widespread distributions are expected to have evolved higher levels of plasticity than....... The results do not support the hypothesis that widely distributed species have larger phenotypic plasticity for thermal tolerance limits, and Drosophila species distributions are therefore more closely linked to differences in innate thermal tolerance limits....

  12. Optical properties of single-layer, double-layer, and bulk MoS2

    Energy Technology Data Exchange (ETDEWEB)

    Molina-Sanchez, Alejandro; Wirtz, Ludger [University of Luxembourg (Luxembourg); Hummer, Kerstin [University of Vienna, Vienna (Austria)

    2013-07-01

    The rise of graphene has brought attention also to other layered materials that can complement graphene or that can be an alternative in applications as transistors. Single-layer MoS{sub 2} has shown interesting electronic and optical properties such as as high electron mobility at room temperature and an optical bandgap of 1.8 eV. This makes the material suitable for transistors or optoelectronic devices. We present a theoretical study of the optical absorption and photoluminescence spectra of single-layer, double-layer and bulk MoS{sub 2}. The excitonic states have been calculated in the framework of the Bethe-Salpeter equation, taking into account the electron-hole interaction via the screened Coulomb potential. In addition to the step-function like behaviour that is typical for the joint-density of states of 2D materials with parabolic band dispersion, we find a bound excitonic peak that is dominating the luminescence spectra. The peak is split due to spin-orbit coupling for the single-layer and split due to layer-layer interaction for few-layer and bulk MoS{sub 2}. We discuss the changes of the optical bandgap and of the exciton binding energy with the number of layers, comparing our results with the reported experimental data.

  13. Drought's legacy: multiyear hydraulic deterioration underlies widespread aspen forest die-off and portends increased future risk.

    Science.gov (United States)

    Anderegg, William R L; Plavcová, Lenka; Anderegg, Leander D L; Hacke, Uwe G; Berry, Joseph A; Field, Christopher B

    2013-04-01

    Forest mortality constitutes a major uncertainty in projections of climate impacts on terrestrial ecosystems and carbon-cycle feedbacks. Recent drought-induced, widespread forest die-offs highlight that climate change could accelerate forest mortality with its diverse and potentially severe consequences for the global carbon cycle, ecosystem services, and biodiversity. How trees die during drought over multiple years remains largely unknown and precludes mechanistic modeling and prediction of forest die-off with climate change. Here, we examine the physiological basis of a recent multiyear widespread die-off of trembling aspen (Populus tremuloides) across much of western North America. Using observations from both native trees while they are dying and a rainfall exclusion experiment on mature trees, we measure hydraulic performance over multiple seasons and years and assess pathways of accumulated hydraulic damage. We test whether accumulated hydraulic damage can predict the probability of tree survival over 2 years. We find that hydraulic damage persisted and increased in dying trees over multiple years and exhibited few signs of repair. This accumulated hydraulic deterioration is largely mediated by increased vulnerability to cavitation, a process known as cavitation fatigue. Furthermore, this hydraulic damage predicts the probability of interyear stem mortality. Contrary to the expectation that surviving trees have weathered severe drought, the hydraulic deterioration demonstrated here reveals that surviving regions of these forests are actually more vulnerable to future droughts due to accumulated xylem damage. As the most widespread tree species in North America, increasing vulnerability to drought in these forests has important ramifications for ecosystem stability, biodiversity, and ecosystem carbon balance. Our results provide a foundation for incorporating accumulated drought impacts into climate-vegetation models. Finally, our findings highlight the

  14. Formation of double layers

    International Nuclear Information System (INIS)

    Leung, P.; Wong, A.Y.; Quon, B.H.

    1981-01-01

    Experiments on both stationary and propagating double layers and a related analytical model are described. Stationary double layers were produced in a multiple plasma device, in which an electron drift current was present. An investigation of the plasma parameters for the stable double layer condition is described. The particle distribution in the stable double layer establishes a potential profile, which creates electron and ion beams that excite plasma instabilities. The measured characteristics of the instabilities are consistent with the existence of the double layer. Propagating double layers are formed when the initial electron drift current is large. Ths slopes of the transition region increase as they propagate. A physical model for the formation of a double layer in the experimental device is described. This model explains the formation of the low potential region on the basis of the space charge. This space charge is created by the electron drift current. The model also accounts for the role of ions in double layer formation and explains the formation of moving double layers. (Auth.)

  15. Effect of layer-by-layer polyelectrolyte method on encapsulation of vanillin.

    Science.gov (United States)

    Noshad, Mohammad; Mohebbi, Mohebbat; Shahidi, Fakhri; Koocheki, Arash

    2015-11-01

    The objective of this work was to microencapsulate vanillin by multilayer emulsion followed by spray drying, aiming to protect it and control its release. An electrostatic layer-by-layer deposition method was used to create the multilayered interfacial membranes around microcapsules with different compositions: (i) one-layer (soy protein isolate); (ii) two-layer (soy protein isolate - OSA starch); (iii) three-layer (soy protein isolate - OSA starch - Chitosan). The morphology of the microcapsules was analyzed by scanning electronic microscopy. The hygroscopicity, solubility, particle size, encapsulation efficiency, Fourier transform infrared spectroscopy and release into water (37°C and 80°C) were also examined. FTIR confirmed the interaction between the wall materials. All microcapsules were not very water-soluble or hygroscopic while three-layer microcapsules compared to one and two layer microcapsules have lower moisture content and predominantly shriveled surfaces. The results indicated it was possible to encapsulate vanillin with the techniques employed and that these protected the vanillin even at 80°C. The reduced solubility and low release rates indicated the enormous potential of the vehicle developed in controlling the release of the vanillin into the food and pharmaceuticals. Copyright © 2015 Elsevier B.V. All rights reserved.

  16. Spontaneous layering of porous silicon layers formed at high current densities

    Energy Technology Data Exchange (ETDEWEB)

    Parkhutik, Vitali; Curiel-Esparza, Jorge; Millan, Mari-Carmen [R and D Center MTM, Technical University of Valencia, Valencia (Spain); Albella, Jose [Institute of Materials Science (ICMM CSIC) Madrid (Spain)

    2005-06-01

    We report here a curious effect of spontaneous fracturing of the silicon layers formed in galvanostatic conditions at medium and high current densities. Instead of formation of homogeneous p-Si layer as at low currents, a stack of thin layers is formed. Each layer is nearly separated from others and possesses rather flat interfaces. The effects is observed using p{sup +}-Si wafers for the p-Si formation and starts being noticeable at above 100 mA/cm{sup 2}. We interpret these results in terms of the porous silicon growth model where generation of dynamic mechanical stress during the p-Si growth causes sharp changes in Si dissolution mechanism from anisotropic etching of individual needle-like pores in silicon to their branching and isotropic etching. At this moment p-Si layer loses its adhesion to the surface of Si wafer and another p-Si layer starts growing. One of the mechanisms triggering on the separation of p-Si layers from one another is a fluctuation of local anodic current in the pore bottoms associated with gas bubble evolution during the p-Si formation. (copyright 2005 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  17. Turbulent current layer equilibrium and current layer of the Earth magnetotail

    International Nuclear Information System (INIS)

    Antonova, E.E.; Ovchinnikov, I.L.

    1996-01-01

    Analysis of distribution of plasma and magnetic field concentration in the unidimensional current layer under the condition of equality of the current inflowing into the layer and the counter diffusion current by various dependences of the regular velocity and the turbulent diffusion coefficient on the magnetic field. Corresponding two-dimensional solutions are obtained in the tail approximation. Comparison of the model turbulent current layer with characteristics of the plasma layer of the Earth magnetosphere tail is carried out. 16 refs., 3 figs

  18. Phreatic eruption clouds: the activity of La Soufriere de Guadeloupe, F. W. I. , August-October, 1976

    Energy Technology Data Exchange (ETDEWEB)

    Heiken, G.; Crowe, B.; McGetchin, T.; West, F.; Eichelberger, J.; Bartram, D.; Peterson, R.; Wohletz, K.

    1980-01-01

    From August to October, 1976, La Soufriere de Guadeloupe was observed, and recorded with an automated sequence camera and numerous handheld cameras. During the period of observation, the nature of volcanic activity ranged from mild steam emission to moderately energetic phraetic eruptions. The concurrent growth of clouds from separate vents (summit and flank) implies a common source. Simultaneous eruption of tephra-free and tephra-laden clouds from the same vent is puzzling and implies: (i) lateral changes in the degree of alteration of dome rocks along the elongate vent, hence erodability of the dome lavas, or (ii) differences in the gas velocities. These mixed clouds moved westward, downwind and downslope as a density current, with an approximate velocity of 10 to 25 m/sec. Upon reaching the sea the clouds continued to move forward, but at a decreased velocity, and spread laterally, having left behind the restrictions of valley walls. A thin gray veneer of moist tephra, ranging from several cm thick near the dome to less than 1 mm thick several km downwind, was deposited along a narrow corridor southwest of the summit. Tephra from the phreatic eruptions consisted mostly of hydrothermally altered lithic, mineral, and glass fragments derived from dome lavas; no fresh (juvenile) pyroclasts were present in the tephra.

  19. Widespread ectopic expression of olfactory receptor genes

    Directory of Open Access Journals (Sweden)

    Yanai Itai

    2006-05-01

    Full Text Available Abstract Background Olfactory receptors (ORs are the largest gene family in the human genome. Although they are expected to be expressed specifically in olfactory tissues, some ectopic expression has been reported, with special emphasis on sperm and testis. The present study systematically explores the expression patterns of OR genes in a large number of tissues and assesses the potential functional implication of such ectopic expression. Results We analyzed the expression of hundreds of human and mouse OR transcripts, via EST and microarray data, in several dozens of human and mouse tissues. Different tissues had specific, relatively small OR gene subsets which had particularly high expression levels. In testis, average expression was not particularly high, and very few highly expressed genes were found, none corresponding to ORs previously implicated in sperm chemotaxis. Higher expression levels were more common for genes with a non-OR genomic neighbor. Importantly, no correlation in expression levels was detected for human-mouse orthologous pairs. Also, no significant difference in expression levels was seen between intact and pseudogenized ORs, except for the pseudogenes of subfamily 7E which has undergone a human-specific expansion. Conclusion The OR superfamily as a whole, show widespread, locus-dependent and heterogeneous expression, in agreement with a neutral or near neutral evolutionary model for transcription control. These results cannot reject the possibility that small OR subsets might play functional roles in different tissues, however considerable care should be exerted when offering a functional interpretation for ectopic OR expression based only on transcription information.

  20. Energy efficient three-layer panels and elastic compliance of their middle layer

    Directory of Open Access Journals (Sweden)

    Petrov Stanislav

    2017-01-01

    Full Text Available Three-layer panels are referred to light weight energy efficient building envelopes. According to current trends, mineral wool from basalt fiber is preferable to be used as panels middle layer. All three-layers of the construction together account for mechanical properties, though these layers taken separately have very different mechanical properties. The work of such a composite design has a number of features that require careful consideration when calculating the panels for strength. Thus, it has not yet been described how squeeze reduction of a relatively soft middle layer affects the load bearing capacity of a panel. When panels are exposed to external loads, their middle layer is squeezed thus changing the characteristics of the panel. This effect is particularly evident in supporting structures. Besides, squeeze reduction of the middle layer changes its elastic-plastic propeties. The purpose of this work is to study the effect of the middle layer of an energy efficient panel squeeze reduction on its load bearing capacity. When solving this task, the authors worked out a methodology which takes into account squeeze reduction of a middle layer and its effect on load bearing capacity of the panel. The researches introduced an algorithm for solving this task and created a tool that allows to easily receive the exact solution. The paper presents this methodology and describes a computer program for calculating three-layer panels with account of changing elastic compliance of a middle layer. The main result of the work is an extended methodology of calculation of the panels and an obtained engineering tool that allows to quickly obtain an extended solution.

  1. ASH REDISTRIBUTION FOLLOWING A POTENTIAL VOLCANIC ERUPTION AT YUCCA MOUNTAIN

    International Nuclear Information System (INIS)

    J. Pelletier; S. deLong; M.L. Cline; C. Harrington; G. Keating

    2005-01-01

    The redistribution of contaminated tephra by hillslope, fluvial, and pedologic processes is a poorly-constrained but important aspect of evaluating the radiological dose from an unlikely volcanic eruption at Yucca Mountain (YM). To better evaluate this hazard, we developed a spatially distributed, numerical model of tephra redistribution that integrates contaminated tephra from hill slopes and active channels, mixes it with clean sediment in the channel system, distributes it on the fan, and migrates it into the soil column. The model is coupled with an atmospheric dispersion model that predicts the deposition of radioactive waste-contaminated tephra at specified grid points. The redistribution model begins in the upper Fortymile Wash drainage basin where it integrates the tephra deposited on steep slopes and active channel beds within a GIS framework. The Fortymile Wash drainage basin is the focus of this model because tephra from only this basin reaches the Fortymile Wash alluvial fan by fluvial processes, and it is on this fan where the radiological dose to a hypothetical individual is compared to the regulatory standard (via additional biosphere models). The dilution effect of flood scour, mixing, and re-deposition within the upper basin is modeled using a dilution-mixing model widely used in the contaminant-transport literature. The accuracy of this model is established by comparing the model prediction with tephra concentrations measured in channels draining the Lathrop Wells volcanic center. The model combines the contaminated tephra transported from the upper basin with the tephra deposited directly on the fan as primary fallout. On the Fortymile Wash fan, channels and interchannel-divide areas are divided on the basis of soil-geomorphic mapping according to whether they are Holocene or Pleistocene in age. This approach allows the model to incorporate the effects of channel migration on the fan within the past 10,000 yr. The model treats the redistribution

  2. Electronic energy loss spectra from mono-layer to few layers of phosphorene

    International Nuclear Information System (INIS)

    Mohan, Brij; Thakur, Rajesh; Ahluwalia, P. K.

    2016-01-01

    Using first principles calculations, electronic and optical properties of few-layers phosphorene has been investigated. Electronic band structure show a moderate band gap of 0.9 eV in monolayer phosphorene which decreases with increasing number of layers. Optical properties of few-layers of phosphorene in infrared and visible region shows tunability with number of layers. Electron energy loss function has been plotted and huge red shift in plasmonic behaviours is found. These tunable electronic and optical properties of few-layers of phosphorene can be useful for the applications of optoelectronic devices.

  3. Electronic energy loss spectra from mono-layer to few layers of phosphorene

    Energy Technology Data Exchange (ETDEWEB)

    Mohan, Brij, E-mail: brijmohanhpu@yahoo.com; Thakur, Rajesh; Ahluwalia, P. K. [Department of Physics, Himachal Pradesh University, Shimla (HP) India 171005 (India)

    2016-05-23

    Using first principles calculations, electronic and optical properties of few-layers phosphorene has been investigated. Electronic band structure show a moderate band gap of 0.9 eV in monolayer phosphorene which decreases with increasing number of layers. Optical properties of few-layers of phosphorene in infrared and visible region shows tunability with number of layers. Electron energy loss function has been plotted and huge red shift in plasmonic behaviours is found. These tunable electronic and optical properties of few-layers of phosphorene can be useful for the applications of optoelectronic devices.

  4. Chronic Widespread Pain after Motor Vehicle Collision Typically Occurs via Immediate Development and Non-Recovery: Results of an Emergency Department-Based Cohort Study

    Science.gov (United States)

    JunMei, Hu; Andrey V, Bortsov; Lauren, Ballina; Danielle C, Orrey; Robert A, Swor; David, Peak; Jeffrey, Jones; Niels, Rathlev; David C, Lee; Robert, Domeier; Phyllis, Hendry; Blair A, Parry; Samuel A, McLean

    2016-01-01

    Motor vehicle collision (MVC) can trigger chronic widespread pain (CWP) development in vulnerable individuals. Whether such CWP typically develops via the evolution of pain from regional to widespread or via the early development of widespread pain with non-recovery is currently unknown. We evaluated the trajectory of CWP development (American College of Rheumatology criteria) among 948 European-American individuals who presented to the emergency department (ED) for care in the early aftermath of MVC. Pain extent was assessed in the ED and 6 weeks, 6 months, and 1 year after MVC on 100%, 91%, 89%, and 91% of participants, respectively. Individuals who reported prior CWP at the time of ED evaluation (n = 53) were excluded. Trajectory modeling identified a two-group solution as optimal, with the Bayes Factor value (138) indicating strong model selection. Linear solution plots supported a non-recovery model. While the number of body regions with pain in the non-CWP group steadily declined, the number of body regions with pain in the CWP trajectory group (192/895, 22%) remained relatively constant over time. These data support the hypothesis that individuals who develop CWP after MVC develop widespread pain in the early aftermath of MVC which does not remit. PMID:26808013

  5. CHARGE-TRANSFER BETWEEN LAYERS IN MISFIT LAYER COMPOUNDS

    NARCIS (Netherlands)

    WIEGERS, GA

    1995-01-01

    Electron donation from MX double layers to TX(2) sandwiches, the interlayer bonding and the localization of conduction electrons in misfit layer compounds (MX)(p)(TX(2))(n) (M=Sn, Pb, Sb, Bi, rare earth metals; T=Ti, V, Cr, Nb, Ta; X=S, Se; 1.08

  6. 3D anatomy of Heinrich Layer 2

    Science.gov (United States)

    van Rooij, D.; Zaazi, N.; Fagel, N.; Boone, M.; Cnudde, V.; Dewanckele, J.; Pirlet, H.; Rohl, U.; Blamart, D.; Henriet, J.-P.; Jacobs, P.; Houbrechts, H.; Duyck, P.; Swennen, R.

    2009-04-01

    Heinrich Layers are found in the North Atlantic Ocean as well-constrained markers of catastrophic iceberg surges from the Pan-Atlantic ice sheets during the last glacial cycle. Their physical and geochemical characteristics allow for relatively fast diagnostics using the state-of-the-art core scanners such as a Multi-Sensor Core Logger and an XRF core scanner. The nature of these characteristics are predominantly due to the source sediments of the ice-rafted debris (IRD) on the one hand (magnetic susceptibility, color, carbonate content) and the response of the palaeo-environment on the other hand (carbonate content, foraminiferal assemblage). However, changes in (gamma) bulk density of the sediment within a Heinrich Layer cannot solely be explained due to the higher content of IRD. Sediment cores in the Porcupine Seabight (West off Ireland) have shown the presence of Heinrich Events without the diagnostic changes in magnetic susceptibility (MS), suggesting a more drastic change in oceanography which could cause widespread diagenesis on the seabed during Heinrich Events. In order to better understand the physical behavior of a Heinrich Layer, 2 cores were studied taken from the northern Porcupine Seabight by R/V Marion Dufresne campaign MD123 in September 2001. More specifically HL2 was studied since it carries the most typical HL signature. The main anatomical information, with a resolution of 0.5 mm, was obtained by means of medical computed tomography of half-core sections of 50 cm length from the Ghent University Hospital. This information was used for detailed sampling for mineralogy, grainsize measurements and palaeoenvironmental analyses. On one core section, XRF core scanning was performed at a 0.5 cm interval. Higher-resolution information was obtained from five 8 cc subsamples which underwent µCT scanning and cold-cathode luminescence microscopy. The results of this unique approach show a rather surprising 3D view of a Heinrich Layer. As expected, the

  7. Oxygen inhibition layer of composite resins: effects of layer thickness and surface layer treatment on the interlayer bond strength.

    Science.gov (United States)

    Bijelic-Donova, Jasmina; Garoushi, Sufyan; Lassila, Lippo V J; Vallittu, Pekka K

    2015-02-01

    An oxygen inhibition layer develops on surfaces exposed to air during polymerization of particulate filling composite. This study assessed the thickness of the oxygen inhibition layer of short-fiber-reinforced composite in comparison with conventional particulate filling composites. The effect of an oxygen inhibition layer on the shear bond strength of incrementally placed particulate filling composite layers was also evaluated. Four different restorative composites were selected: everX Posterior (a short-fiber-reinforced composite), Z250, SupremeXT, and Silorane. All composites were evaluated regarding the thickness of the oxygen inhibition layer and for shear bond strength. An equal amount of each composite was polymerized in air between two glass plates and the thickness of the oxygen inhibition layer was measured using a stereomicroscope. Cylindrical-shaped specimens were prepared for measurement of shear bond strength by placing incrementally two layers of the same composite material. Before applying the second composite layer, the first increment's bonding site was treated as follows: grinding with 1,000-grit silicon-carbide (SiC) abrasive paper, or treatment with ethanol or with water-spray. The inhibition depth was lowest (11.6 μm) for water-sprayed Silorane and greatest (22.9 μm) for the water-sprayed short-fiber-reinforced composite. The shear bond strength ranged from 5.8 MPa (ground Silorane) to 36.4 MPa (water-sprayed SupremeXT). The presence of an oxygen inhibition layer enhanced the interlayer shear bond strength of all investigated materials, but its absence resulted in cohesive and mixed failures only with the short-fiber-reinforced composite. Thus, more durable adhesion with short-fiber-reinforced composite is expected. © 2014 Eur J Oral Sci.

  8. Volcanic ash deposition and long-term vegetation change on Subantarctic Marion Island

    NARCIS (Netherlands)

    Yeloff, D.; Mauquoy, D.S.; Barber, K.; Way, S.; van Geel, B.; Turney, C.S.M.

    2007-01-01

    A c. 5500 year record of peatland development and vegetation change was generated from a core recovered from an Agrostis magellanica peat bog on subantarctic Marion Island, using palynomorph, plant macrofossil, and tephra analyses. Two tephra horizons (both 17 cm thick) were identified and dated to

  9. Weathering-related origin of widespread monazite in S-type granites

    Energy Technology Data Exchange (ETDEWEB)

    Sawka, W N; Banfield, J F; Chappell, B W

    1986-01-01

    The S-type granite suites comprising more than a quarter of the extensively developed granites in the Lachlan Fold Belt, Australia, contain monazite which may be related to the chemical weathering of the sedimentary source rocks. We report a process whereby chemical weathering fixes mobile rare-earth elements (REE) in hydrous phosphate phases such as florencite and rhabdophane. This material contains up to 50 wt.% LREE and occurs as very small particles (approx. 3 ..mu..m). Dehydration of these hydrous REE phases during anatexis directly yields monazite. The low solubility of phosphorus in S-type granite melts inhibits dissolution of both monazite and apatite. Refractory monazite may be thus entrained and transported in S-type granites in a manner similar to processes resulting in inherited zircon. Since both Th and the light REE are major components in monazite, materials containing this minute phase may be of widespread geochemical significance in both granites and metamorphic rocks.

  10. Selective layer disordering in III-nitrides with a capping layer

    Science.gov (United States)

    Wierer, Jr., Jonathan J.; Allerman, Andrew A.

    2016-06-14

    Selective layer disordering in a doped III-nitride superlattice can be achieved by depositing a dielectric capping layer on a portion of the surface of the superlattice and annealing the superlattice to induce disorder of the layer interfaces under the uncapped portion and suppress disorder of the interfaces under the capped portion. The method can be used to create devices, such as optical waveguides, light-emitting diodes, photodetectors, solar cells, modulators, laser, and amplifiers.

  11. Layer-by-layer-assembled healable antifouling films.

    Science.gov (United States)

    Chen, Dongdong; Wu, Mingda; Li, Bochao; Ren, Kefeng; Cheng, Zhongkai; Ji, Jian; Li, Yang; Sun, Junqi

    2015-10-21

    Healable antifouling films are fabricated by the exponential layer-by-layer assembly of PEGylated branched poly(ethylenimine) and hyaluronic acid followed by post-crosslinking. The antifouling function originates from the grafted PEG and the extremely soft nature of the films. The rapid and multiple healing of damaged antifouling functions caused by cuts and scratches can be readily achieved by immersing the films in normal saline solution. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  12. The Middle to Upper Paleolithic transition: dating, stratigraphy, and isochronous markers.

    Science.gov (United States)

    Blockley, S P E; Ramsey, C Bronk; Higham, T F G

    2008-11-01

    Accurate and precise dating is vital to our understanding of the Middle to Upper Paleolithic transition. There are, however, a number of uncertainties in the chronologies currently available for this period. We attempt to examine these uncertainties by utilizing a number of recent developments in the field. These include: the precise dating of the Campanian Ignimbrite (CI) tephra by 40Ar/39Ar; the tracing of this tephra to a number of deposits that are radiocarbon dated; the publication of revised radiocarbon calibration data for the period, showing a much better convergence with other available data than during the recent IntCal comparison; and a layer-counted ice-core chronology extending beyond 40,000cal BP. Our data comparisons suggest that a reasonable overall convergence between calibrated radiocarbon ages and calendar dates is possible using the new curves. Additionally, we suggest that charcoal-based radiocarbon ages, as well as bone-based radiocarbon determinations, require cautious interpretation in this period. Potentially, these issues extend far beyond the sites in this study and should be of serious concern to archaeologists studying the Middle to Upper Paleolithic. We conclude by outlining a strategy for moving the science forward by a closer integration of archaeology, chronology, and stratigraphy.

  13. The role of cryptotephra in refining the chronology of Late Pleistocene human evolution and cultural change in North Africa

    Science.gov (United States)

    Barton, R. N. E.; Lane, C. S.; Albert, P. G.; White, D.; Collcutt, S. N.; Bouzouggar, A.; Ditchfield, P.; Farr, L.; Oh, A.; Ottolini, L.; Smith, V. C.; Van Peer, P.; Kindermann, K.

    2015-06-01

    Sites in North Africa hold key information for dating the presence of Homo sapiens and the distribution of Middle Stone Age (MSA), Middle Palaeolithic (MP) and Later Stone Age (LSA) cultural activity in the Late Pleistocene. Here we present new and review recently published tephrochronological evidence for five cave sites in North Africa with long MSA/MP and LSA cultural sequences. Four tephra horizons have been identified at the Haua Fteah (Cyrenaica, Libya). They include cryptotephra evidence for the Campanian Ignimbrite (CI) eruption dating to ˜39 ka that allows correlation with other Palaeolithic sequences in the eastern Mediterranean and as far north as Russia. Cryptotephra have also been recorded from the Moroccan sites of Taforalt, Rhafas and Dar es-Soltane 1. At Taforalt the geochemical composition suggests a provenance in the Azores, while examples from Sodmein (Egypt) appear to derive from central Anatolia and another unknown source. In these latter examples chemical compositional data from relevant proximal volcanic centres is currently lacking so the identification of tephra in layers of known age and cultural association provides the first reliable age determinations for distal volcanic events and their geographical extent. The future potential for tephrochronological research in North Africa is also discussed.

  14. The Layer 1 / Layer 2 readout upgrade for the ATLAS Pixel Detector

    CERN Document Server

    Mullier, Geoffrey; The ATLAS collaboration

    2016-01-01

    The Pixel Detector of the ATLAS experiment has shown excellent performance during the whole Run-1 of the Large Hadron Collider (LHC). The increase of instantaneous luminosity foreseen during the LHC Run 2, will lead to an increased detector occupancy that is expected to saturate the readout links of the outermost layers of the pixel detector: Layers 1 and 2. To ensure a smooth data taking under such conditions, the read out system of the recently installed fourth innermost pixel layer, the Insertable B-Layer, was modified to accomodate the needs of the older detector. The Layer 2 upgrade installation took place during the 2015 winter shutdown, with the Layer 1 installation scheduled for 2016. A report of the successful installation, together with the design of novel dedicated optical to electrical converters and the software and firmware updates will be presented.

  15. Classification of archaeologically stratified pumice by INAA

    International Nuclear Information System (INIS)

    Peltz, C.; Bichler, M.

    2001-01-01

    In the framework of the research program 'Synchronization of Civilization in the Eastern Mediterranean Region in the 2nd Millenium B.C.' instrumental neutron activation analysis (INAA) was used to determine 30 elements in pumice from archaeological excavations to reveal their specific volcanic origin. The widespread pumiceous products of several eruptions in the Aegean region were used as abrasive tools and were therefore popular trade objects. A remarkable quantity of pumice and pumiceous tephra (several km 3 ) was produced by the 'Minoan eruption' of Thera (Santorini), which is assumed to have happened between 1450 and 1650 B.C. Thus the discovery of the primary fallout of 'Minoan' tephra in archaeologically stratified locations can be used as a relative time mark. Additionally, pumice lumps used as abrasive can serve for dating by first appearance. Essential to an identification of the primary volcanic source is the knowledge that pumices from the Aegean region can easily be distinguished by their trace element distribution patterns, as previous work has shown. The elements Al, Ba, Ca, Ce, Co, Cr, Cs, Dy, Eu, Fe, Hf, K, La, Lu, Mn, Na, Nd, Rb, Sb, Sc, Sm, Ta, Tb, Th, Ti, U, V, Yb, Zn and Zr were determined in 16 samples of pumice lumps from excavations in Tell-el-Dab'a and Tell-el-Herr (Egypt). Two irradiation cycles and five measurement runs were applied. A reliable identification of the samples is achieved by comparing these results to the database compiled in previous studies. (author)

  16. Chaparrastique (San Mighel) Volcano Eruptions since Dec. 29th, 2013, El Salvador

    Science.gov (United States)

    Martinez-Hackert, B.; Bajo, J. V.; Escobar, D.; Gutierrez, E.

    2015-12-01

    The December 29th, 2013 eruption of Chaparrastique (San Miguel) volcano in El Salvador came as a surprise and was the first of several small eruptions in the past two years. They came after many years of preceeding earthquake swarms and significant degassing. Being the second volcano to erupt in El Salvador in less than ten years, it caused grave concern for the population of the country. Although they were not large eruptions (VEI 2), the materials were widespread and caused deposits of volcanic tephra as far at the capital San Salvador and closed the airports in the vecinity for a couple of days. This is a summary of the research, mitigation and services that were done days after the first eruption on December 29, 2013 and the follwing months. In conjunction with the team of the Direccion General del Observatorio Ambiental from the Ministerio de Medio Ambiente y Recursos Naturales possible first response strategies were discussed and decided to obtain results that could be quickly put in place to mitigate and decide on actions such as evacuations or relocations of people living in volcano related high-risk hazard areas. Collection of samples, mapping and measurements of the volcanic tephra in the field together with Digital Globe and areal photography after the event, allowed identification of four different volcanic products that can be correlated to the opening of the vent and ending in the eruption of juvenile materials of basaltic to trachybasaltic composition, and the production of a lahar hazard map based on LaharZ.

  17. Chitosan-Recombinamer Layer-by-Layer Coatings for Multifunctional Implants

    Directory of Open Access Journals (Sweden)

    Jeevan Prasaad Govindharajulu

    2017-02-01

    Full Text Available The main clinical problems for dental implants are (1 formation of biofilm around the implant—a condition known as peri-implantitis and (2 inadequate bone formation around the implant—lack of osseointegration. Therefore, developing an implant to overcome these problems is of significant interest to the dental community. Chitosan has been reported to have good biocompatibility and anti-bacterial activity. An osseo-inductive recombinant elastin-like biopolymer (P-HAP, that contains a peptide derived from the protein statherin, has been reported to induce biomineralization and osteoblast differentiation. In this study, chitosan/P-HAP bi-layers were built on a titanium surface using a layer-by-layer (LbL assembly technique. The difference in the water contact angle between consecutive layers, the representative peaks in diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS, X-ray photoelectron spectroscopy (XPS, and the changes in the topography between surfaces with a different number of bi-layers observed using atomic force microscopy (AFM, all indicated the successful establishment of chitosan/P-HAP LbL assembly on the titanium surface. The LbL-modified surfaces showed increased biomineralization, an appropriate mouse pre-osteoblastic cell response, and significant anti-bacterial activity against Streptococcus gordonii, a primary colonizer of tissues in the oral environment

  18. Widespread abnormalities of radiocolloid distribution in patients with mucopolysaccharidoses

    International Nuclear Information System (INIS)

    Klingensmith, W.C. III; Eikman, E.A.; Maumenee, I.; Wagner, H.N. Jr.

    1975-01-01

    Mucopolysaccharidoses (MPS) are inherited disorders of lysosomal enzymes. We have examined the sites of accumulation of intravenously injected /sup 99m/Tc-sulfur colloid in order to assess the regional distribution of phagocytic function in ten patients with MPS: three with Type I (Hurler), five with Type II (Hunter), one with Type III (Sanfilippo), and one with Type VI (Maroteaux-Lamy). Increased lung uptake was observed in 22 of 40 studies (55 percent) on the five patients with MPS Type II but in none of the 38 studies on patients with other MPS types. All MPS patients had diffuse recticuloendothelial (RE) marrow hypoplasia, despite normal or nearly normal hematocrits and hemoglobin levels, suggesting dissociation of the phagocytic and erythropoietic elements of the marrow. The eight patients with MPS Types I and II all had hepatomegaly and increased splenic uptake. Seven of these patients also had splenomegaly. The two patients with MPS Types III and VI did not have hepatosplenomegaly. These studies indicate that the lysosomal enzymic defect of MPS results in widespread abnormalities of the distribution of phagocytic function in the liver, spleen, bone marrow, and probably the lung as well

  19. Assessing biological invasions in European Seas: Biological traits of the most widespread non-indigenous species

    Science.gov (United States)

    Cardeccia, Alice; Marchini, Agnese; Occhipinti-Ambrogi, Anna; Galil, Bella; Gollasch, Stephan; Minchin, Dan; Narščius, Aleksas; Olenin, Sergej; Ojaveer, Henn

    2018-02-01

    The biological traits of the sixty-eight most widespread multicellular non-indigenous species (MWNIS) in European Seas: Baltic Sea, Western European Margin of the Atlantic Ocean and the Mediterranean Sea were examined. Data for nine biological traits was analyzed, and a total of 41 separate categories were used to describe the biological and ecological functions of these NIS. Our findings show that high dispersal ability, high reproductive rate and ecological generalization are the biological traits commonly associated with MWNIS. The functional groups that describe most of the 68 MWNIS are: photoautotrophic, zoobenthic (both sessile and motile) and nektonic predatory species. However, these 'most widespread' species comprise a wide range of taxa and biological trait profiles; thereby a clear "identikit of a perfect invader" for marine and brackish environments is difficult to define. Some traits, for example: "life form", "feeding method" and "mobility", feature multiple behaviours and strategies. Even species introduced by a single pathway, e.g. vessels, feature diverse biological trait profiles. MWNIS likely to impact community organization, structure and diversity are often associated with brackish environments. For many traits ("life form", "sociability", "reproductive type", "reproductive frequency", "haploid and diploid dispersal" and "mobility"), the categories mostly expressed by the impact-causing MWNIS do not differ substantially from the whole set of MWNIS.

  20. Current face of acute otitis media: microbiology and prevalence resulting from widespread use of heptavalent pneumococcal conjugate vaccine.

    Science.gov (United States)

    Brunton, Stephen

    2006-01-01

    Many causes can be proposed for a change in the microbiologic makeup of a specific disease state. However, when viewed through the scope of recent events, only one is likely to be the true cause of a change in the microbiology of acute otitis media (AOM): the release and widespread use of heptavalent pneumococcal conjugate vaccine (PCV-7). The aim of this report was to review the microbiology and prevalence of AOM before and after the release and widespread use of PCV-7. For this brief review, we used a MEDLINE search to identify English-language literature related to the microbiology of AOM before and after the release of PCV-7 in 2000 in the United States (key terms: acute otitis media, AOM, Haemophilus influenzae, H influenzae, Streptococcus pneumoniae, and S pneumoniae; years: 1980-2005). Studies using tympanocentesis to identify the pathogen in recurrent or persistent AOM were examined; US studies reporting AOM microbiology before and after the release of PCV-7 in the same population were considered for the post-PCV-7 analysis. Following the release of PCV-7, a decrease in the overall rates of AOM was noted. This decrease brings into question the resultant effect on the microbiology of AOM. Our literature search revealed 2 studies that examined the microbiology of AOM before and after the release of PCV-7 in the United States. These 2 studies, conducted in dispersed geographic regions (rural Kentucky and Rochester, New York), illustrated a change in the predominant causative pathogen in AOM, from S pneumoniae to H influenzae in the population of children 7 to 24 months of age with recurrent AOM. Given the time period of the change, these shifts could be related to the release and widespread use of PCV-7. Since the 1990s, the predominant causative pathogen in recurrent AOM changed from S pneumoniae to H influenzae, possibly as a result of the release and widespread use of PCV 7. Although PCV-7 use was slowed from August 2001 to May 2003 and again from February

  1. Design and installation of a hot water layer system at the Tehran research reactor

    Directory of Open Access Journals (Sweden)

    Mirmohammadi Sayedeh Leila

    2013-01-01

    Full Text Available A hot water layer system (HWLS is a novel system for reducing radioactivity under research reactor containment. This system is particularly useful in pool-type research reactors or other light water reactors with an open pool surface. The main purpose of a HWLS is to provide more protection for operators and reactor personnel against undesired doses due to the radio- activity of the primary loop. This radioactivity originates mainly from the induced radioactivity contained within the cooling water or probable minute leaks of fuel elements. More importantly, the bothersome radioactivity is progressively proportional to reactor power and, thus, the HWLS is a partial solution for mitigating such problems when power upgrading is planned. Following a series of tests and checks for different parameters, a HWLS has been built and put into operation at the Tehran research reactor in 2009. It underwent a series of comprehensive tests for a period of 6 months. Within this time-frame, it was realized that the HWLS could provide a better protection for reactor personnel against prevailing radiation under containment. The system is especially suitable in cases of abnormality, e. g. the spread of fission products due to fuel failure, because it prevents the mixing of pollutants developed deep in the pool with the upper layer and thus mitigates widespread leakage of radioactivity.

  2. Asymmetric temporal integration of layer 4 and layer 2/3 inputs in visual cortex.

    Science.gov (United States)

    Hang, Giao B; Dan, Yang

    2011-01-01

    Neocortical neurons in vivo receive concurrent synaptic inputs from multiple sources, including feedforward, horizontal, and feedback pathways. Layer 2/3 of the visual cortex receives feedforward input from layer 4 and horizontal input from layer 2/3. Firing of the pyramidal neurons, which carries the output to higher cortical areas, depends critically on the interaction of these pathways. Here we examined synaptic integration of inputs from layer 4 and layer 2/3 in rat visual cortical slices. We found that the integration is sublinear and temporally asymmetric, with larger responses if layer 2/3 input preceded layer 4 input. The sublinearity depended on inhibition, and the asymmetry was largely attributable to the difference between the two inhibitory inputs. Interestingly, the asymmetric integration was specific to pyramidal neurons, and it strongly affected their spiking output. Thus via cortical inhibition, the temporal order of activation of layer 2/3 and layer 4 pathways can exert powerful control of cortical output during visual processing.

  3. Hybrid inorganic–organic superlattice structures with atomic layer deposition/molecular layer deposition

    Energy Technology Data Exchange (ETDEWEB)

    Tynell, Tommi; Yamauchi, Hisao; Karppinen, Maarit, E-mail: maarit.karppinen@aalto.fi [Department of Chemistry, Aalto University, FI-00076 Aalto (Finland)

    2014-01-15

    A combination of the atomic layer deposition (ALD) and molecular layer deposition (MLD) techniques is successfully employed to fabricate thin films incorporating superlattice structures that consist of single layers of organic molecules between thicker layers of ZnO. Diethyl zinc and water are used as precursors for the deposition of ZnO by ALD, while three different organic precursors are investigated for the MLD part: hydroquinone, 4-aminophenol and 4,4′-oxydianiline. The successful superlattice formation with all the organic precursors is verified through x-ray reflectivity studies. The effects of the interspersed organic layers/superlattice structure on the electrical and thermoelectric properties of ZnO are investigated through resistivity and Seebeck coefficient measurements at room temperature. The results suggest an increase in carrier concentration for small concentrations of organic layers, while higher concentrations seem to lead to rather large reductions in carrier concentration.

  4. Layer-specific morphological and molecular differences in neocortical astrocytes and their dependence on neuronal layers.

    Science.gov (United States)

    Lanjakornsiripan, Darin; Pior, Baek-Jun; Kawaguchi, Daichi; Furutachi, Shohei; Tahara, Tomoaki; Katsuyama, Yu; Suzuki, Yutaka; Fukazawa, Yugo; Gotoh, Yukiko

    2018-04-24

    Non-pial neocortical astrocytes have historically been thought to comprise largely a nondiverse population of protoplasmic astrocytes. Here we show that astrocytes of the mouse somatosensory cortex manifest layer-specific morphological and molecular differences. Two- and three-dimensional observations revealed that astrocytes in the different layers possess distinct morphologies as reflected by differences in cell orientation, territorial volume, and arborization. The extent of ensheathment of synaptic clefts by astrocytes in layer II/III was greater than that by those in layer VI. Moreover, differences in gene expression were observed between upper-layer and deep-layer astrocytes. Importantly, layer-specific differences in astrocyte properties were abrogated in reeler and Dab1 conditional knockout mice, in which neuronal layers are disturbed, suggesting that neuronal layers are a prerequisite for the observed morphological and molecular differences of neocortical astrocytes. This study thus demonstrates the existence of layer-specific interactions between neurons and astrocytes, which may underlie their layer-specific functions.

  5. Boosting water oxidation layer-by-layer.

    Science.gov (United States)

    Hidalgo-Acosta, Jonnathan C; Scanlon, Micheál D; Méndez, Manuel A; Amstutz, Véronique; Vrubel, Heron; Opallo, Marcin; Girault, Hubert H

    2016-04-07

    Electrocatalysis of water oxidation was achieved using fluorinated tin oxide (FTO) electrodes modified with layer-by-layer deposited films consisting of bilayers of negatively charged citrate-stabilized IrO2 NPs and positively charged poly(diallyldimethylammonium chloride) (PDDA) polymer. The IrO2 NP surface coverage can be fine-tuned by controlling the number of bilayers. The IrO2 NP films were amorphous, with the NPs therein being well-dispersed and retaining their as-synthesized shape and sizes. UV/vis spectroscopic and spectro-electrochemical studies confirmed that the total surface coverage and electrochemically addressable surface coverage of IrO2 NPs increased linearly with the number of bilayers up to 10 bilayers. The voltammetry of the modified electrode was that of hydrous iridium oxide films (HIROFs) with an observed super-Nernstian pH response of the Ir(III)/Ir(IV) and Ir(IV)-Ir(IV)/Ir(IV)-Ir(V) redox transitions and Nernstian shift of the oxygen evolution onset potential. The overpotential of the oxygen evolution reaction (OER) was essentially pH independent, varying only from 0.22 V to 0.28 V (at a current density of 0.1 mA cm(-2)), moving from acidic to alkaline conditions. Bulk electrolysis experiments revealed that the IrO2/PDDA films were stable and adherent under acidic and neutral conditions but degraded in alkaline solutions. Oxygen was evolved with Faradaic efficiencies approaching 100% under acidic (pH 1) and neutral (pH 7) conditions, and 88% in alkaline solutions (pH 13). This layer-by-layer approach forms the basis of future large-scale OER electrode development using ink-jet printing technology.

  6. Pyroclast/snow interactions and thermally driven slurry formation. Part 2: Experiments and theoretical extension to polydisperse tephra

    Science.gov (United States)

    Walder, J.S.

    2000-01-01

    Erosion of snow by pyroclastic flows and surges presumably involves mechanical scour, but there may be thermally driven phenomena involved as well. To investigate this possibility, layers of hot (up to 400??C), uniformly sized, fine- to medium-grained sand were emplaced vertically onto finely shaved ice ('snow'); thus there was no relative shear motion between sand and snow and no purely mechanical scour. In some cases large vapor bubbles, commonly more than 10 mm across, rose through the sand layer, burst at the surface, and caused complete convective overturn of the sand, which then scoured and mixed with snow and transformed into a slurry. In other cases no bubbling occurred and the sand passively melted its way downward into the snow as a wetting front moved upward into the sand. A continuum of behaviors between these two cases was observed. Vigorous bubbling and convection were generally favored by high temperature, small grain size, and small layer thickness. A physically based theory of heat- and mass transfer at the pyroclast/snow interface, developed in Part 1 of this paper, does a good job of explaining the observations as a manifestation of unstable vapor-driven fluidization. The theory, when extrapolated to the behavior of actual, poorly sorted pyroclastic flow sediments, leads to the prediction that the observed 'thermal-scour' phenomenon should also occur for many real pyroclastic flows passing over snow. 'Thermal scour' is therefore likely to be involved in the generation of lahars.

  7. Layer-by-layer self-assembly of polyimide precursor/layered double hydroxide ultrathin films

    International Nuclear Information System (INIS)

    Chen Dan; Huang Shu; Zhang Chao; Wang Weizhi; Liu Tianxi

    2010-01-01

    The layer-by-layer (LBL) self-assembly has been extensively used as a simple and effective method for the preparation of polyelectrolyte multilayer films. In this work, we utilized this unique method to prepare polyimide precursor/layered double hydroxide (LDH) ultrathin films. Well-crystallized Co-Al-CO 3 LDH and subsequent anion exchanged Co-Al-NO 3 LDH were prepared and characterized by scanning electron microscopy and X-ray diffraction (XRD). By vigorous shaking of the as-prepared Co-Al-NO 3 LDH, positively charged and exfoliated LDH nanosheets were obtained. Atomic force microscopy and XRD investigations indicated the delamination of LDH nanosheets. The precursor of polyimide, poly(amic acid) tertiary amine salt (PAS) was prepared by the polycondensation of dianhydride and diamine, and subsequent amine salt formation. By using the LBL method, heterogeneous ultrathin films of PAS and LDH were prepared. The formation of the ordered nanostructured assemblies was confirmed by the progressive enhancement of UV absorbance and the XRD results.

  8. Double layers in space

    International Nuclear Information System (INIS)

    Carlqvist, P.

    1982-07-01

    For more than a decade it has been realised that electrostatic double layers are likely to occur in space. We briefly discuss the theoretical background of such double layers. Most of the paper is devoted to an account of the observational evidence for double layers in the ionosphere and magnetosphere of the Earth. Several different experiments are reviewed including rocket and satellite measurements and ground based observations. It is concluded that the observational evidence for double layers in space is very strong. The experimental results indicate that double layers with widely different properties may exist in space. (Author)

  9. Double layers in space

    International Nuclear Information System (INIS)

    Carlqvist, P.

    1982-01-01

    For more than a decade it has been realised that electrostatic double layers are likely to occur in space. The author briefly discusses the theoretical background of such double layers. Most of the paper is devoted to an account of the observational evidence for double layers in the ionosphere and magnetosphere of the Earth. Several different experiments are reviewed including rocket and satellite measurements and ground based observations. It is concluded that the observational evidence for double layers in space is very strong. The experimental results indicate that double layers with widely different properties may exist in space. (Auth.)

  10. Topotactic condensation of layer silicates with ferrierite-type layers forming porous tectosilicates.

    Science.gov (United States)

    Marler, B; Wang, Y; Song, J; Gies, H

    2014-07-21

    Five different hydrous layer silicates (HLSs) containing fer layers (ferrierite-type layers) were obtained by hydrothermal syntheses from mixtures of silicic acid, water and tetraalkylammonium/tetraalkylphosphonium hydroxides. The organic cations had been added as structure directing agents (SDA). A characteristic feature of the structures is the presence of strong to medium strong hydrogen bonds between the terminal silanol/siloxy groups of neighbouring layers. The five-layered silicates differ chemically only with respect to the organic cations. Structurally, they differ with respect to the arrangement of the fer layers relative to each other, which is distinct for every SDA-fer-layer system. RUB-20 (containing tetramethylammonium) and RUB-40 (tetramethylphosphonium) are monoclinic with stacking sequence AAA and shift vectors between successive layers 1a0 + 0b0 + 0.19c0 and 1a0 + 0b0 + 0.24c0, respectively. RUB-36 (diethyldimethylammonium), RUB-38 (methyltriethylammonium) and RUB-48 (trimethylisopropylammonium) are orthorhombic with stacking sequence ABAB and shift vectors 0.5a0 + 0b0± 0.36c0, 0.5a0 + 0b0 + 0.5c0 and 0.5a0 + 0b0± 0.39c0, respectively. Unprecedented among the HLSs, two monoclinic materials are made up of fer layers which possess a significant amount of ordered defects within the layer. The ordered defects involve one particular Si-O-Si bridge which is, to a fraction of ca. 50%, hydrolyzed to form nests of two ≡Si-OH groups. When heated to 500-600 °C in air, the HLSs condense to form framework silicates. Although all layered precursors were moderately to well ordered, the resulting framework structures were of quite different crystallinity. The orthorhombic materials RUB-36, -38 and -48, general formula SDA4Si36O72(OH)4, which possess very strong hydrogen bonds (d[O···O] ≈ 2.4 Å), transform into a fairly or well ordered CDO-type silica zeolite RUB-37. The monoclinic materials RUB-20 and -40, general formula SDA2Si18O36(OH)2OH, possessing

  11. Hybrid window layer for photovoltaic cells

    Science.gov (United States)

    Deng, Xunming

    2010-02-23

    A novel photovoltaic solar cell and method of making the same are disclosed. The solar cell includes: at least one absorber layer which could either be a lightly doped layer or an undoped layer, and at least a doped window-layers which comprise at least two sub-window-layers. The first sub-window-layer, which is next to the absorber-layer, is deposited to form desirable junction with the absorber-layer. The second sub-window-layer, which is next to the first sub-window-layer, but not in direct contact with the absorber-layer, is deposited in order to have transmission higher than the first-sub-window-layer.

  12. Gravel sediment routing from widespread, low-intensity landscape disturbance, Current River basin, Missouri

    Science.gov (United States)

    Jacobson, Robert B.; Gran, K.B.

    1999-01-01

    During the last 160 years, land-use changes in the Ozarks have had the potential to cause widespread, low-intensity delivery of excess amounts of gravel-sized sediment to stream channels. Previous studies have indicated that this excess gravel bedload is moving in wave-like forms through Ozarks drainage basins. The longitudinal, areal distribution of gravel bars along 160 km of the Current River, Missouri, was evaluated to determine the relative effects of valley-scale controls, tributary basin characteristics, and lagged sediment transport in creating areas of gravel accumulations. The longitudinal distribution of gravel-bar area shows a broad scale wave-like form with increases in gravel-bar area weakly associated with tributary junctions. Secondary peaks of gravel area with 1·8–4·1 km spacing (disturbance reaches) are superimposed on the broad form. Variations in valley width explain some, but not all, of the short-spacing variation in gravel-bar area. Among variables describing tributary drainage basin morphometry, present-day land use and geologic characteristics, only drainage area and road density relate even weakly to gravel-bar areal inventories. A simple, channel network-based sediment routing model shows that many of the features of the observed longitudinal gravel distribution can be replicated by uniform transport of sediment from widespread disturbances through a channel network. These results indicate that lagged sediment transport may have a dominant effect on the synoptic spatial distribution of gravel in Ozarks streams; present-day land uses are only weakly associated with present-day gravel inventories; and valley-scale characteristics have secondary controls on gravel accumulations in disturbance reaches.

  13. Effect of p-layer properties on nanocrystalline absorber layer and thin film silicon solar cells

    International Nuclear Information System (INIS)

    Chowdhury, Amartya; Adhikary, Koel; Mukhopadhyay, Sumita; Ray, Swati

    2008-01-01

    The influence of the p-layer on the crystallinity of the absorber layer and nanocrystalline silicon thin film solar cells has been studied. Boron doped Si : H p-layers of different crystallinities have been prepared under different power pressure conditions using the plasma enhanced chemical vapour deposition method. The crystalline volume fraction of p-layers increases with the increase in deposition power. Optical absorption of the p-layer reduces as the crystalline volume fraction increases. Structural studies at the p/i interface have been done by Raman scattering studies. The crystalline volume fraction of the i-layer increases as that of the p-layer increases, the effect being more prominent near the p/i interface. Grain sizes of the absorber layer decrease from 9.2 to 7.2 nm and the density of crystallites increases as the crystalline volume fraction of the p-layer increases and its grain size decreases. With increasing crystalline volume fraction of the p-layer solar cell efficiency increases

  14. City of Camden, New Jersey Program offering widespread energy recovery (power): Final report

    Energy Technology Data Exchange (ETDEWEB)

    Witkowski, Stanley [City of Camden, NJ (United States). Dept. of Development and Planning Bureau of Housing Services

    2013-12-31

    The Camden Residential POWER Program, Program Offering Widespread Energy Recovery, is a program designed to benefit Camden homeowners, stabilize neighborhoods and put local contractors to work. Camden POWER granted up to $18,600 to fund energy efficient home improvements and necessary life/safety rehabilitation repairs. The program was designed as a self-sustaining, neighborhood approach to bringing long-term energy and financial savings to the community. Valuable home upgrades were completed, including high-efficiency furnaces, hot water heaters, insulation, insulated roofs and blower door guided air-sealing. The goal of all improvements were to reduce energy consumption, lower utility bills, improve property values and promote neighborhood stabilization.

  15. Dysregulation of the autonomic nervous system and its association with the presence and intensity of chronic widespread pain

    NARCIS (Netherlands)

    Barakat, A.; Vogelzangs, N.; Licht, C.M.M.; Geenen, R.; Macfarlane, G.J.; de Geus, E.J.C.; Smit, J.H.; Penninx, B.W.J.H.; Dekker, J.

    2012-01-01

    Objective To test the hypotheses that dysregulation of the autonomic nervous system (ANS) is associated with the presence of chronic widespread pain (CWP), and that dysregulation of the ANS is associated with higher pain intensity in CWP. Methods Cross-sectional data were obtained from 1,574

  16. Dysregulation of the Autonomic Nervous System and Its Association With the Presence and Intensity of Chronic Widespread Pain

    NARCIS (Netherlands)

    Barakat, Ansam; Vogelzangs, Nicole; Licht, Carmilla M. M.; Geenen, Rinie; Macfarlane, Gary J.; de Geus, Eco J. C.; Smit, Johannes H.; Penninx, Brenda W. J. H.; Dekker, Joost

    Objective. To test the hypotheses that dysregulation of the autonomic nervous system (ANS) is associated with the presence of chronic widespread pain (CWP), and that dysregulation of the ANS is associated with higher pain intensity in CWP. Methods. Cross-sectional data were obtained from 1,574

  17. The role of the East Asian active margin in widespread extensional and strike-slip deformation in East Asia

    NARCIS (Netherlands)

    Schellart, Wouter P.; Lister, G. S.

    2005-01-01

    East Asia is a region of widespread deformation, dominated by normal and strike-slip faults. Deformation has been interpreted to result from extrusion tectonics related to the India-Eurasia collision, which started in the Early Eocene. In East and SE China, however, deformation started earlier than

  18. Factors influencing observed and self-reported functional ability in women with chronic widespread pain: A cross-sectional study

    DEFF Research Database (Denmark)

    Amris, Kirstine; Wæhrens, Eva Ejlersen; Stockmarr, Anders

    2014-01-01

    -sectional with systematic data collection in a clinical setting. Subjects: A total of 257 consecutively enrolled women with chronic widespread pain. Methods: Multidimensional assessment using self-report and observation-based assessment tools identified to cover ICF categories included in the brief ICF Core Set for chronic...

  19. Layer-by-layer assembly of thin film oxygen barrier

    International Nuclear Information System (INIS)

    Jang, Woo-Sik; Rawson, Ian; Grunlan, Jaime C.

    2008-01-01

    Thin films of sodium montmorillonite clay and cationic polyacrylamide were grown on a polyethylene terephthalate film using layer-by-layer assembly. After 30 clay-polymer layers are deposited, with a thickness of 571 nm, the resulting transparent film has an oxygen transmission rate (OTR) below the detection limit of commercial instrumentation ( 2 /day/atm). This low OTR, which is unprecedented for a clay-filled polymer composite, is believed to be due to a brick wall nanostructure comprised of completely exfoliated clay in polymeric mortar. With an optical transparency greater than 90% and potential for microwaveability, this thin composite is a good candidate for foil replacement in food packaging and may also be useful for flexible electronics packaging

  20. Timescales of mixing and storage for Keanakāko`i Tephra magmas (1500-1820 C.E.), Kīlauea Volcano, Hawai`i

    Science.gov (United States)

    Lynn, Kendra J.; Garcia, Michael O.; Shea, Thomas; Costa, Fidel; Swanson, Donald A.

    2017-09-01

    The last 2500 years of activity at Kīlauea Volcano (Hawai`i) have been characterized by centuries-long periods dominated by either effusive or explosive eruptions. The most recent period of explosive activity produced the Keanakāko`i Tephra (KT; ca. 1500-1820 C.E.) and occurred after the collapse of the summit caldera (1470-1510 C.E.). Previous studies suggest that KT magmas may have ascended rapidly to the surface, bypassing storage in crustal reservoirs. The storage conditions and rapid ascent hypothesis are tested here using chemical zoning in olivine crystals and thermodynamic modeling. Forsterite contents (Fo; [Mg/(Mg + Fe) × 100]) of olivine core and rim populations are used to identify melt components in Kīlauea's prehistoric (i.e., pre-1823) plumbing system. Primitive (≥Fo88) cores occur throughout the 300+ years of the KT period; they originated from mantle-derived magmas that were first mixed and stored in a deep crustal reservoir. Bimodal olivine populations (≥Fo88 and Fo83-84) record repeated mixing of primitive magmas and more differentiated reservoir components shallower in the system, producing a hybrid composition (Fo85-87). Phase equilibria modeling using MELTS shows that liquidus olivine is not stable at depths >17 km. Thus, calculated timescales likely record mixing and storage within the crust. Modeling of Fe-Mg and Ni zoning patterns (normal, reverse, complex) reveal that KT magmas were mixed and stored for a few weeks to several years before eruption, illustrating a more complex storage history than direct and rapid ascent from the mantle as previously inferred for KT magmas. Complexly zoned crystals also have smoothed compositional reversals in the outer 5-20 µm rims that are out of Fe-Mg equilibrium with surrounding glasses. Diffusion models suggest that these rims formed within a few hours to a few days, indicating that at least one additional, late-stage mixing event may have occurred shortly prior to eruption. Our study

  1. The Transient Intermediate Plexiform Layer, a Plexiform Layer-like Structure Temporarily Existing in the Inner Nuclear Layer in Developing Rat Retina.

    Science.gov (United States)

    Park, Hyung Wook; Kim, Hong-Lim; Park, Yong Soo; Kim, In-Beom

    2018-02-01

    The retina is a highly specialised part of the brain responsible for visual processing. It is well-laminated; three layers containing five different types of neurons are compartmentalised by two synaptic layers. Among the retinal layers, the inner nuclear layer (INL) is composed of horizontal, bipolar, and amacrine cell types. Bipolar cells form one sublayer in the distal half of the IPL, while amacrine cells form another sublayer in the proximal half, without any border-like structure. Here, we report that a plexiform layer-like structure exists temporarily in the border between the bipolar and amacrine sublayers in the INL in the rat retina during retinal development. This transient intermediate plexiform layer (TIPL) appeared at postnatal day (PD) 7 and then disappeared around PD 12. Most apoptotic cells in the INL were found near the TIPL. These results suggest that the TIPL may contribute to the formation of sublayers and the cell number limit in the INL.

  2. Layer-by-layer modification of thin-film metal-semiconductor multilayers with ultrashort laser pulses

    Science.gov (United States)

    Romashevskiy, S. A.; Tsygankov, P. A.; Ashitkov, S. I.; Agranat, M. B.

    2018-05-01

    The surface modifications in a multilayer thin-film structure (50-nm alternating layers of Si and Al) induced by a single Gaussian-shaped femtosecond laser pulse (350 fs, 1028 nm) in the air are investigated by means of atomic-force microscopy (AFM), scanning electron microscopy (SEM), and optical microscopy (OM). Depending on the laser fluence, various modifications of nanometer-scale metal and semiconductor layers, including localized formation of silicon/aluminum nanofoams and layer-by-layer removal, are found. While the nanofoams with cell sizes in the range of tens to hundreds of nanometers are produced only in the two top layers, layer-by-layer removal is observed for the four top layers under single pulse irradiation. The 50-nm films of the multilayer structure are found to be separated at their interfaces, resulting in a selective removal of several top layers (up to 4) in the form of step-like (concentric) craters. The observed phenomenon is associated with a thermo-mechanical ablation mechanism that results in splitting off at film-film interface, where the adhesion force is less than the bulk strength of the used materials, revealing linear dependence of threshold fluences on the film thickness.

  3. Asymmetric Temporal Integration of Layer 4 and Layer 2/3 Inputs in Visual Cortex

    OpenAIRE

    Hang, Giao B.; Dan, Yang

    2010-01-01

    Neocortical neurons in vivo receive concurrent synaptic inputs from multiple sources, including feedforward, horizontal, and feedback pathways. Layer 2/3 of the visual cortex receives feedforward input from layer 4 and horizontal input from layer 2/3. Firing of the pyramidal neurons, which carries the output to higher cortical areas, depends critically on the interaction of these pathways. Here we examined synaptic integration of inputs from layer 4 and layer 2/3 in rat visual cortical slices...

  4. Bacterial Leaf Scorch of Amenity Trees a Wide-Spread Problem of Economic Significance to the Urban Forest

    Science.gov (United States)

    James Lashomb; Alan Iskra; Ann Brooks Gould; George Hamilton

    2003-01-01

    Bacterial leaf scorch (BLS) of amenity trees is caused by the bacterium Xylella fastidiosa, a xylem-limited pathogen that causes water stress resulting in leaf scorch, decline, and eventual death of affected trees. Recent surveys indicate that BLS is widespread throughout the eastern half of the United States. In New Jersey, BLS primarily affects red and pin oaks...

  5. Widespread erosion on high plateaus during recent glaciations in Scandinavia

    DEFF Research Database (Denmark)

    Andersen, Jane L.; Egholm, David L.; Knudsen, Mads F.

    2018-01-01

    Glaciers create some of Earth's steepest topography; yet, many areas that were repeatedly overridden by ice sheets in the last few million years include extensive plateaus. The distinct geomorphic contrast between plateaus and the glacial troughs that dissect them has sustained two long-held hypo......Glaciers create some of Earth's steepest topography; yet, many areas that were repeatedly overridden by ice sheets in the last few million years include extensive plateaus. The distinct geomorphic contrast between plateaus and the glacial troughs that dissect them has sustained two long......-held hypotheses: first, that ice sheets perform insignificant erosion beyond glacial troughs, and, second, that the plateaus represent ancient pre-glacial landforms bearing information of tectonic and geomorphic history prior to Pliocene-Pleistocene global cooling (similar to 3.5 Myr ago). Here we show...... that the Fennoscandian ice sheets drove widespread erosion across plateaus far beyond glacial troughs. We apply inverse modelling to 118 new cosmogenic Be-10 and Al-26 measurements to quantify ice sheet erosion on the plateaus fringing the Sognefjorden glacial trough in western Norway. Our findings demonstrate...

  6. A study on effective thermal conductivity of crystalline layers in layer melt crystallization

    International Nuclear Information System (INIS)

    Kim, Kwang-Joo; Ulrich, Joachim

    2002-01-01

    An effective thermal conductivity in layer melt crystallization was explored based on a model considering inclusions inside a crystalline layer during crystal growth, molecular diffusion of inclusions migration due to temperature gradient and heat generation due to recrystallization of inclusions in the crystalline layer. The effective thermal conductivity increases with time, in general, as a result of compactness of the layer. Lower cooling temperature, i.e. greater supercooling, results in a more porous layer with lower effective thermal conductivity. A similar result is seen for the parameter of melt temperature, but less pronounced. A high concentration of the melt results in a high effective thermal conductivity while low concentration yields low effective thermal conductivity. At higher impurity levels in the melt phase, constitutional supercooling becomes more pronounced and unstable growth morphologies occur more easily. Cooling rate and Reynolds number also affect the effective thermal conductivity. The predictions of an effective thermal conductivity agree with the experimental data. The model was applied to estimate the thermal conductivities of the crystalline layer during layer melt crystallization. (author)

  7. Layered plasma polymer composite membranes

    Science.gov (United States)

    Babcock, Walter C.

    1994-01-01

    Layered plasma polymer composite fluid separation membranes are disclosed, which comprise alternating selective and permeable layers for a total of at least 2n layers, where n is .gtoreq.2 and is the number of selective layers.

  8. 14C ages of Omuroyama volcano, Izu Peninsula

    International Nuclear Information System (INIS)

    Saito, Toshihito; Takahashi, Shuichi; Wada, Hideki

    2003-01-01

    A partly carbonized wood trunk was discovered below the Omuroyama tephra covered by a lava, and it was dated to be 3,700±100 y. B.P., by the benzene liquid scintillation method for radiocarbon age determination. We have investigated the circumstance of the discovery of the wood sample based on an interview of the person who collected the sample during his operation of building construction. According to him, the wood specimen was found at 1.5-2 m depth beneath the ground level when the operator removed the massive blackish lava block. This specimen was laid down covered by black sandy pebbles. The size of the wood trunk was 105 cm long and 45 cm and 35 cm along wide and short diameter, respectively. We also revealed the burial environment of the wood to be related with the Omuroyama tephras and lava flow, based on our volcanostratigraphic observation of the surrounding area. The tephras covering the trunk were identified as the Omuroyama tephra B, C, and D, which were defined by Koyano et al. (1996) around this area, and these tephras were covered by the Omuroyama lava flow II (Koyano et al., 1996). The wood trunk was mostly fresh and only its branch was burned. It can be estimated that the trunk has been preserved surrounded by ground water, since several tons of ground water gushed out when the aquifer was opened for construction. On this context, this trunk was buried at the early stage of the volcanism of Omuroyama volcano covered by the tephras, and later also covered by the Omuroyama lava II. We can not conclude that the burned branch is ascribed to direct burning by the Omuroyama lava flow II but this 14 C dating resultant is also concordant all archaeological evidences reported. (author)

  9. Effects of volcanic and hydrologic processes on forest vegetation: Chaitén Volcano, Chile

    Science.gov (United States)

    Frederick J. Swanson; Julia A. Jones; Charles M. Crisafulli; Antonio. Lara

    2013-01-01

    The 2008-2009 eruption of Chaiten Volcano (Chile) involved a variety of volcanic and associated hydrologic processes that damaged nearby forests. These processes included coarse (gravel) and fine (silt to sand) tephra fall, a laterally directed blast, fluvial deposition of remobilized tephra, a variety of low-temperature mass-movement processes, and a pyroclastic flow...

  10. Widespread occurrence of (per)chlorate in the Solar System

    Science.gov (United States)

    Jackson, W. Andrew; Davila, Alfonso F; Sears, Derek W. G.; Coates, John D.; McKay, Christopher P.; Brundrett, Meaghan; Estrada, Nubia; Böhlke, John Karl

    2015-01-01

    Perchlorate (ClO− 4 ) and chlorate (ClO− 3 ) are ubiquitous on Earth and ClO− 4 has also been found on Mars. These species can play important roles in geochemical processes such as oxidation of organic matter and as biological electron acceptors, and are also indicators of important photochemical reactions involving oxyanions; on Mars they could be relevant for human habitability both in terms of in situ resource utilization and potential human health effects. For the first time, we extracted, detected and quantified ClO− 4 and ClO− 3 in extraterrestrial, non-planetary samples: regolith and rock samples from the Moon, and two chondrite meteorites (Murchison and Fayetteville). Lunar samples were collected by astronauts during the Apollo program, and meteorite samples were recovered immediately after their fall. This fact, together with the heterogeneous distribution of ClO− 4 and ClO− 3 within some of the samples, and their relative abundance with respect to other soluble species (e.g., NO− 3 ) are consistent with an extraterrestrial origin of the oxychlorine species. Our results, combined with the previously reported widespread occurrence on Earth and Mars, indicate that ClO− 4 and ClO− 3 could be present throughout the Solar System.

  11. Electric-double-layer potential distribution in multiple-layer immiscible electrolytes

    NARCIS (Netherlands)

    Das, S.; Hardt, Steffen

    2011-01-01

    In this Brief Report, we calculate the electric-double-layer (EDL) electrostatic potential in a system of several layers of immiscible electrolytes. Verwey-Niessen theory predicts that at the interface between two immiscible electrolytes back-to-back EDLs are formed. The present analysis extends

  12. A Highly Expressed High-Molecular-Weight S-Layer Complex of Pelosinus sp. Strain UFO1 Binds Uranium

    Energy Technology Data Exchange (ETDEWEB)

    Thorgersen, Michael P. [Univ. of Georgia, Athens, GA (United States). Dept. of Biochemistry and Molecular Biology; Lancaster, W. Andrew [Univ. of Georgia, Athens, GA (United States). Dept. of Biochemistry and Molecular Biology; Rajeev, Lara [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Biological Systems and Engineering Division; Ge, Xiaoxuan [Univ. of Georgia, Athens, GA (United States). Dept. of Biochemistry and Molecular Biology; Vaccaro, Brian J. [Univ. of Georgia, Athens, GA (United States). Dept. of Biochemistry and Molecular Biology; Poole, Farris L. [Univ. of Georgia, Athens, GA (United States). Dept. of Biochemistry and Molecular Biology; Arkin, Adam P. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Biological Systems and Engineering Division; Mukhopadhyay, Aindrila [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Biological Systems and Engineering Division; Adams, Michael W. W. [Univ. of Georgia, Athens, GA (United States). Dept. of Biochemistry and Molecular Biology

    2016-12-02

    Cell suspensions of Pelosinus sp. strain UFO1 were previously shown, using spectroscopic analysis, to sequester uranium as U(IV) complexed with carboxyl and phosphoryl group ligands on proteins. The goal of our present study was to characterize the proteins involved in uranium binding. Virtually all of the uranium in UFO1 cells was associated with a heterodimeric protein, which was termed the uranium-binding complex (UBC). The UBC was composed of two S-layer domain proteins encoded by UFO1_4202 and UFO1_4203. Samples of UBC purified from the membrane fraction contained 3.3 U atoms/heterodimer, but significant amounts of phosphate were not detected. The UBC had an estimated molecular mass by gel filtration chromatography of 15 MDa, and it was proposed to contain 150 heterodimers (UFO1_4203 and UFO1_4202) and about 500 uranium atoms. The UBC was also the dominant extracellular protein, but when purified from the growth medium, it contained only 0.3 U atoms/heterodimer. The two genes encoding the UBC were among the most highly expressed genes within the UFO1 genome, and their expressions were unchanged by the presence or absence of uranium. Therefore, the UBC appears to be constitutively expressed and is the first line of defense against uranium, including by secretion into the extracellular medium. Although S-layer proteins were previously shown to bind U(VI), here we showed that U(IV) binds to S-layer proteins, we identified the proteins involved, and we quantitated the amount of uranium bound. Widespread uranium contamination from industrial sources poses hazards to human health and to the environment. Here in this paper, we identified a highly abundant uranium-binding complex (UBC) from Pelosinus sp. strain UFO1. The complex makes up the primary protein component of the S-layer of strain UFO1 and binds 3.3 atoms of U(IV) per heterodimer. Finally, while other bacteria have been shown to bind U(VI) on their S-layer, we demonstrate here an example of U(IV) bound by

  13. Layer-by-layer thinning of MoSe_2 by soft and reactive plasma etching

    International Nuclear Information System (INIS)

    Sha, Yunfei; Xiao, Shaoqing; Zhang, Xiumei; Qin, Fang; Gu, Xiaofeng

    2017-01-01

    Highlights: • Soft plasma etching technique using SF_6 + N_2 as precursors for layer-by-layer thinning of MoSe_2 was adopted in this work. • Optical microscopy, Raman, photoluminescence and atomic force microscopy measurements were used to confirm the thickness change. • Layer-dependent vibrational and photoluminescence spectra of the etched MoSe_2 were also demonstrated. • Equal numbers of MoSe_2 layers can be removed uniformly without affecting the underlying SiO_2 substrate and the remaining MoSe_2 layers. - Abstract: Two-dimensional (2D) transition metal dichalcogenides (TMDs) like molybdenum diselenide (MoSe_2) have recently gained considerable interest since their properties are complementary to those of graphene. Unlike gapless graphene, the band structure of MoSe_2 can be changed from the indirect band gap to the direct band gap when MoSe_2 changed from bulk material to monolayer. This transition from multilayer to monolayer requires atomic-layer-precision thining of thick MoSe_2 layers without damaging the remaining layers. Here, we present atomic-layer-precision thinning of MoSe_2 nanaosheets down to monolayer by using SF_6 + N_2 plasmas, which has been demonstrated to be soft, selective and high-throughput. Optical microscopy, atomic force microscopy, Raman and photoluminescence spectra suggest that equal numbers of MoSe_2 layers can be removed uniformly regardless of their initial thickness, without affecting the underlying SiO_2 substrate and the remaining MoSe_2 layers. By adjusting the etching rates we can achieve complete MoSe_2 removal and any disired number of MoSe_2 layers including monolayer. This soft plasma etching method is highly reliable and compatible with the semiconductor manufacturing processes, thereby holding great promise for various 2D materials and TMD-based devices.

  14. Kapitza Resistance between Few-Layer Graphene and Water: Liquid Layering Effects

    DEFF Research Database (Denmark)

    Alexeev, Dmitry; Chen, Jie; Walther, Jens Honore

    2015-01-01

    difference in the phonon mean free path between the FLG and water. Remarkably, RK is strongly dependent on the layering of water adjacent to the FLG, exhibiting an inverse proportionality relationship to the peak density of the first water layer, which is consistent with better acoustic phonon matching...... between FLG and water. These findings suggest novel ways to engineer the thermal transport properties of solid−liquidinterfaces by controlling and regulating the liquid layering at the interface....

  15. Flood, Seismic or Volcanic Deposits? New Insights from X-Ray Computed Tomography

    Science.gov (United States)

    Van Daele, M. E.; Moernaut, J.; Vermassen, F.; Llurba, M.; Praet, N.; Strupler, M. M.; Anselmetti, F.; Cnudde, V.; Haeussler, P. J.; Pino, M.; Urrutia, R.; De Batist, M. A. O.

    2014-12-01

    Event deposits, such as e.g. turbidites incorporated in marine or lacustrine sediment sequences, may be caused by a wide range of possible triggering processes: failure of underwater slopes - either spontaneous or in response to earthquake shaking, hyperpycnal flows and floods, volcanic processes, etc. Determining the exact triggering process remains, however, a major challenge. Especially when studying the event deposits on sediment cores, which typically have diameters of only a few cm, only a small spatial window is available to analyze diagnostic textural and facies characteristics. We have performed X-ray CT scans on sediment cores from Chilean, Alaskan and Swiss lakes. Even when using relatively low-resolution CT scans (0.6 mm voxel size), many sedimentary structures and fabrics that are not visible by eye, are revealed. For example, the CT scans allow to distinguish tephra layers that are deposited by fall-out, from those that reached the basin by river transport or mud flows and from tephra layers that have been reworked and re-deposited by turbidity currents. The 3D data generated by the CT scans also allow to examine relative orientations of sedimentary structures (e.g. convolute lamination) and fabrics (e.g. imbricated mud clasts), which can be used to reconstruct flow directions. Such relative flow directions allow to determine whether a deposit (e.g. a turbidite) had one or several source areas, the latter being typical for seismically triggered turbidites. When the sediment core can be oriented (e.g. using geomagnetic properties), absolute flow directions can be reconstructed. X-ray CT scanning, at different resolution, is thus becoming an increasingly important tool for discriminating the exact origin of EDs, as it can help determining whether e.g. an ash layer was deposited as fall out from an ash cloud or fluvially washed into the lake, or whether a turbidite was triggered by an earthquake or a flood.

  16. Exposure to widespread environmental endocrine disrupting chemicals and human sperm sex ratio

    International Nuclear Information System (INIS)

    Jurewicz, Joanna; Radwan, Michał; Sobala, Wojciech; Radwan, Paweł; Jakubowski, Lucjusz; Wielgomas, Bartosz; Ligocka, Danuta; Brzeźnicki, Sławomir; Hanke, Wojciech

    2016-01-01

    In recent years, a trend toward a declining proportion of male births has been noted in several, but not all, industrialized countries. The underlying reason for the drop in the sex ratio is unclear, but one theory states that widespread environmental endocrine disrupting chemicals affecting the male reproductive system in a negative manner could be part of the explanation. The present study was designed to investigate whether the urinary phthalate, pyrethroids and polycyclic aromatic hydrocarbons metabolites concentrations were associated with sperm Y:X ratio. The study population consisted of 194 men aged under 45 years of age who attended infertility clinic in Lodz, Poland for diagnostic purposes with normal semen concentration of 20–300 mln/ml or with slight oligozoospermia (semen concentration of 15–20 mln/ml) (WHO, 1999). The Y:X ratio was assessed by fluorescent in situ hybridization. Urinary concentrations of 1-hydroxypyrene were measured by high performance liquid chromatography, phthalate metabolites were analyzed using a procedure based on the LC-MS/MS methods and metabolites of synthetic pyrethroids were assessed by gas chromatography ion-tap mass spectrometry method. After adjustment for potential confounders (past diseases, age, abstinence, smoking, alcohol consumption, sperm concentration, motility, morphology) 5OH MEHP, CDCCA to TDCCA and 1-OHP was negatively related to Y:X sperm chromosome ratio (p = 0.033, p < 0.001, p = 0.047 respectively). As this is the first study to elucidate the association between the level of metabolites of widespread environmental endocrine disrupting chemicals (phthalates, synthetic pyrethroids, polycyclic aromatic hydrocarbons) on sex chromosome ratio in sperm therefore, these findings require further replication in other populations. - Highlights: • Urinary phthalate metabolites levels were significantly associated with a decrease in Y/X chromosome bearing sperm. • The levels of 1-hydroxypyrene in urine

  17. Layer-by-layer films for biomedical applications

    CERN Document Server

    Picart, Catherine; Voegel, Jean-Claude

    2015-01-01

    The layer-by-layer (LbL) deposition technique is a versatile approach for preparing nanoscale multimaterial films: the fabrication of multicomposite films by the LbL procedure allows the combination of literally hundreds of different materials with nanometer thickness in a single device to obtain novel or superior performance. In the last 15 years the LbL technique has seen considerable developments and has now reached a point where it is beginning to find applications in bioengineering and biomedical engineering. The book gives a thorough overview of applications of the LbL technique in the c

  18. Cross-Layer Protocol as a Better Option in Wireless Mesh Network with Respect to Layered-Protocol

    OpenAIRE

    Ahmed Abdulwahab Al-Ahdal; Dr. V. P. Pawar; G. N. Shinde

    2014-01-01

    The Optimal way to improve Wireless Mesh Networks (WMNs) performance is to use a better network protocol, but whether layered-protocol design or cross-layer design is a better option to optimize protocol performance in WMNs is still an on-going research topic. In this paper, we focus on cross-layer protocol as a better option with respect to layered-protocol. The layered protocol architecture (OSI) model divides networking tasks into layers and defines a pocket of services for each layer to b...

  19. Strength of the Three Layer Beam with Two Binding Layers

    Directory of Open Access Journals (Sweden)

    Smyczyński M. J.

    2016-09-01

    Full Text Available The paper is devoted to the strength analysis of a simply supported three layer beam. The sandwich beam consists of: two metal facings, the metal foam core and two binding layers between the faces and the core. In consequence, the beam is a five layer beam. The main goal of the study is to elaborate a mathematical model of this beam, analytical description and a solution of the three-point bending problem. The beam is subjected to a transverse load. The nonlinear hypothesis of the deformation of the cross section of the beam is formulated. Based on the principle of the stationary potential energy the system of four equations of equilibrium is derived. Then deflections and stresses are determined. The influence of the binding layers is considered. The results of the solutions of the bending problem analysis are shown in the tables and figures. The analytical model is verified numerically using the finite element analysis, as well as experimentally.

  20. Linking global climate and temperature variability to widespread amphibian declines putatively caused by disease.

    Science.gov (United States)

    Rohr, Jason R; Raffel, Thomas R

    2010-05-04

    The role of global climate change in the decline of biodiversity and the emergence of infectious diseases remains controversial, and the effect of climatic variability, in particular, has largely been ignored. For instance, it was recently revealed that the proposed link between climate change and widespread amphibian declines, putatively caused by the chytrid fungus Batrachochytrium dendrobatidis (Bd), was tenuous because it was based on a temporally confounded correlation. Here we provide temporally unconfounded evidence that global El Niño climatic events drive widespread amphibian losses in genus Atelopus via increased regional temperature variability, which can reduce amphibian defenses against pathogens. Of 26 climate variables tested, only factors associated with temperature variability could account for the spatiotemporal patterns of declines thought to be associated with Bd. Climatic predictors of declines became significant only after controlling for a pattern consistent with epidemic spread (by temporally detrending the data). This presumed spread accounted for 59% of the temporal variation in amphibian losses, whereas El Niño accounted for 59% of the remaining variation. Hence, we could account for 83% of the variation in declines with these two variables alone. Given that global climate change seems to increase temperature variability, extreme climatic events, and the strength of Central Pacific El Niño episodes, climate change might exacerbate worldwide enigmatic declines of amphibians, presumably by increasing susceptibility to disease. These results suggest that changes to temperature variability associated with climate change might be as significant to biodiversity losses and disease emergence as changes to mean temperature.

  1. Multimodal and widespread somatosensory abnormalities in persistent shoulder pain in the first 6 months efter stroke: An exploratory study

    NARCIS (Netherlands)

    Roosink, M.; van Dongen, Robert T.; Buitenweg, Jan R.; Renzenbrink, Gerbert J.; Geurts, Alexander C.; IJzerman, Maarten Joost

    2012-01-01

    Objective: To explore the role of multimodal and widespread somatosensory abnormalities in the development of persistent poststroke shoulder pain (pPSSP) in the first 6 months after stroke. Design: Prospective inception cohort study. Setting: Stroke units of 2 teaching hospitals. Participants: The

  2. Microcapsule production by an hybrid colloidosome-layer-by-layer technique

    NARCIS (Netherlands)

    Rossier Miranda, F.J.; Schroën, C.G.P.H.; Boom, R.M.

    2012-01-01

    Although many different methods for microencapsulation are known only some of them had been applied at industrial scale, due to complexity, lack of mechanical strength of the resulting capsules, and the costs related to their production. One of such methods is the electrostatic layer-by-layer (LbL)

  3. Ozone Layer Protection

    Science.gov (United States)

    ... and Research Centers Contact Us Share Ozone Layer Protection The stratospheric ozone layer is Earth’s “sunscreen” – protecting ... GreenChill Partnership Responsible Appliance Disposal (RAD) Program Ozone Protection vs. Ozone Pollution This website addresses stratospheric ozone ...

  4. Tephrochronology as a tool to constrain radiocarbon reservoir age in the deglacial Bering Sea

    Science.gov (United States)

    Chapman, A. U.; White-Nockleby, C.; de Konkoly Thege, P. A.; Rubel, J. N.; Cook, M. S.; Mix, A. C.; Addison, J. A.

    2015-12-01

    In order to accurately calendar date marine carbon, it is necessary to constrain surface reservoir age, the apparent 14C age difference between the atmosphere and surface ocean that results from incomplete equilibration of 14C across the air-sea interface. Surface reservoir age is generally assumed to be constant at the preindustrial value, but evidence suggests it has varied through time by up to 1000 years. In this study we use tephrochronology, a method of correlating tephras across different environments, to identify equivalent strata, as a tool to quantify reservoir age in the Bering Sea during the transition between the Oldest Dryas and Bolling-Allerod (14.7 kcal BP). With frequent volcanic eruptions that allow for possibility of high-resolution reservoir age reconstructions, the Bering Sea/Aleutian Islands region is uniquely positioned to provide insight into the hypothesis that dense water formed in the North Pacific during the last deglaciation. We compare a massive tephra found in three deep-sea sediment cores from Umnak Plateau in the southeast Bering Sea (HLY02-02-55JPC, HLY-02-02-51JPC, and IODP Site U1339) to a tephra dated to 14.8 kcal BP from Deep Lake, Sanak Island in the Eastern Aleutians. For both the Umnak and Sanak tephras, volcanic glass shards are geochemically matched using major and trace elements from electron microprobe and laser-ablation inductively-coupled-plasma mass spectrometry. We compare 14C ages of foraminiferal species Uvigerina peregrina and Neogloboquadrina pachyderma (sinistral) from just above the tephra in HLY-02-02-51JPC (1467 m) to 14C age of the corresponding tephra at Sanak Island from terrestrial plant macrofossils. The surface reservoir age found (930 ± 160 14C y) is similar to the average preindustrial value in the region (790 ± 130 14C y). Benthic-atmosphere age difference (1860 ± 200 14C y) is also comparable to the preindustrial value (2030 ± 60 14C y). These results and future work on additional tephras from

  5. Atomic layer deposited oxide films as protective interface layers for integrated graphene transfer

    Science.gov (United States)

    Cabrero-Vilatela, A.; Alexander-Webber, J. A.; Sagade, A. A.; Aria, A. I.; Braeuninger-Weimer, P.; Martin, M.-B.; Weatherup, R. S.; Hofmann, S.

    2017-12-01

    The transfer of chemical vapour deposited graphene from its parent growth catalyst has become a bottleneck for many of its emerging applications. The sacrificial polymer layers that are typically deposited onto graphene for mechanical support during transfer are challenging to remove completely and hence leave graphene and subsequent device interfaces contaminated. Here, we report on the use of atomic layer deposited (ALD) oxide films as protective interface and support layers during graphene transfer. The method avoids any direct contact of the graphene with polymers and through the use of thicker ALD layers (≥100 nm), polymers can be eliminated from the transfer-process altogether. The ALD film can be kept as a functional device layer, facilitating integrated device manufacturing. We demonstrate back-gated field effect devices based on single-layer graphene transferred with a protective Al2O3 film onto SiO2 that show significantly reduced charge trap and residual carrier densities. We critically discuss the advantages and challenges of processing graphene/ALD bilayer structures.

  6. Fabrication of planar, layered nanoparticles using tri-layer resist templates.

    Science.gov (United States)

    Hu, Wei; Zhang, Mingliang; Wilson, Robert J; Koh, Ai Leen; Wi, Jung-Sub; Tang, Mary; Sinclair, Robert; Wang, Shan X

    2011-05-06

    A simple and universal pathway to produce free multilayer synthetic nanoparticles is developed based on lithography, vapor phase deposition and a tri-layer resist lift-off and release process. The fabrication method presented in this work is ideal for production of a broad range of nanoparticles, either free in solution or still attached to an intact release layer, with unique magnetic, optical, radioactive, electronic and catalytic properties. Multi-modal capabilities are implicit in the layered architecture. As an example, directly fabricated magnetic nanoparticles are evaluated to illustrate the structural integrity of thin internal multilayers and the nanoparticle stability in aggressive biological environments, which is highly desired for biomedical applications.

  7. Properties of Love waves in a piezoelectric layered structure with a viscoelastic guiding layer

    International Nuclear Information System (INIS)

    Liu, Jiansheng; Wang, Lijun; Lu, Yanyan; He, Shitang

    2013-01-01

    A theoretical method is developed for analyzing Love waves in a structure with a viscoelastic guiding layer bounded on a piezoelectric substrate. The dispersion equation previously derived for piezoelectric Love waves propagating in the layered structure with an elastic layer is adopted for analyzing a structure with a viscoelastic layer. A Maxwell–Weichert model is introduced to describe the shear stiffness of a polymeric material. Newton’s method is employed for the numerical calculation. The dispersion equation for piezoelectric–elastic Love waves is proved suitable for solving a structure with a viscoelastic layer on a piezoelectric substrate. The theoretical results indicate that the propagation velocity of the Love wave is mainly decided by the shear stiffness of the guiding layer, whereas the propagation loss is approximately proportional to its viscosity. A detailed experimental study was conducted on a Love wave delay line fabricated on an ST-90° X quartz substrate and overlaid with various thicknesses of SU-8 guiding layers. A tail-raising caused by the viscosity of the guiding layer existed in both the calculated and the measured propagation velocities. The calculated insertion loss of the Love wave delay lines was in good agreement with the measured results. The method and the results presented in this paper are beneficial to the design of Love wave sensors with a viscoelastic guiding layer. (paper)

  8. S-layer architectures : extending the morphogenetic potential of S-layer protein self-assembly

    International Nuclear Information System (INIS)

    Schuster, D.

    2013-01-01

    Self-assembly of molecular building blocks is a common principle for bottom up based building principles in nature. One example are crystalline bacterial surface layers, termed S-layers, which are the most commonly observed cell surface structures in prokaryotic organisms. They recrystallize into highly ordered, porous protein meshworks with unit cell sizes of 3 to 30 nm and pore sizes of 2 to 8 nm. In this work, S-layers were self-assembled on various three dimensional scaffolds in order to fabricate novel S-layer architectures. Exploiting the stabilizing effect of silica deposited on the S-layer protein meshwork led to the construction of hollow S-layer nano-containers derived from coated liposomes. Transmission electron microscopy (TEM) techniques and release experiments with fluorescent dyes confirmed the dissolution of the supporting lipids. Silica deposition on different spherical particles in solution, as well as on planar S-layer coated surfaces, could be monitored by measuring the ζ-potential, the decline of monosilicic acid in solution, by using scanning electron microscopy (SEM) with energy dispersive X-ray (EDX) analysis or by quartz crystal microbalance with dissipation monitoring (QCM-D). Both, ζ-potential and release experiments showed differences between silicified plain liposomes and silicified S-layer coated liposomes. In addition, nanocapsules with calcium carbonate cores served as another template for the construction of silica supported S-layer architectures. These were investigated by SEM and fluorescence microscopy after fluorescence labeling. Additional coating with polyelectrolytes increased the stability of the nanocapsules. Their mechanical properties were characterized by atomic force microscopy (AFM). The influence of silica deposition was investigated by AFM and SEM. Further on, emulsomes and gas filled lipid supported microbubbles may serve as other templates for the design of spherical protein constructs although extraction of the

  9. Development of boundary layers

    International Nuclear Information System (INIS)

    Herbst, R.

    1980-01-01

    Boundary layers develop along the blade surfaces on both the pressure and the suction side in a non-stationary flow field. This is due to the fact that there is a strongly fluctuating flow on the downstream blade row, especially as a result of the wakes of the upstream blade row. The author investigates the formation of boundary layers under non-stationary flow conditions and tries to establish a model describing the non-stationary boundary layer. For this purpose, plate boundary layers are measured, at constant flow rates but different interferent frequency and variable pressure gradients. By introducing the sample technique, measurements of the non-stationary boundary layer become possible, and the flow rate fluctuation can be divided in its components, i.e. stochastic turbulence and periodical fluctuation. (GL) [de

  10. Spontaneous and Widespread Electricity Generation in Natural Deep-Sea Hydrothermal Fields.

    Science.gov (United States)

    Yamamoto, Masahiro; Nakamura, Ryuhei; Kasaya, Takafumi; Kumagai, Hidenori; Suzuki, Katsuhiko; Takai, Ken

    2017-05-15

    Deep-sea hydrothermal vents discharge abundant reductive energy into oxidative seawater. Herein, we demonstrated that in situ measurements of redox potentials on the surfaces of active hydrothermal mineral deposits were more negative than the surrounding seawater potential, driving electrical current generation. We also demonstrated that negative potentials in the surface of minerals were widespread in the hydrothermal fields, regardless of the proximity to hydrothermal fluid discharges. Lab experiments verified that the negative potential of the mineral surface was induced by a distant electron transfer from the hydrothermal fluid through the metallic and catalytic properties of minerals. These results indicate that electric current is spontaneously and widely generated in natural mineral deposits in deep-sea hydrothermal fields. Our discovery provides important insights into the microbial communities that are supported by extracellular electron transfer and the prebiotic chemical and metabolic evolution of the ocean hydrothermal systems. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  11. CoCr double-layered media with NiFe and CoZrNb soft-magnetic layers (invited)

    International Nuclear Information System (INIS)

    Bernards, J.P.C.; Schrauwen, C.P.G.; Zieren, V.; Luitjens, S.B.

    1988-01-01

    The magnetic, structural, and recording properties of CoCr double-layered media are investigated. The underlayer materials NiFe (crystalline) and CoZrNb (amorphous) were combined with two different kinds of intermediate layers: Ti (crystalline) and Ge (amorphous). Applying a bias voltage during sputtering of NiFe results in a low coercivity of the NiFe layer and in a high coercivity of the CoCr layer. The structure of the NiFe layer influences the structure of the CoCr layer. A Ti layer between the NiFe and CoCr layers decreases the in-plane remanence of the CoCr layer. The coercivity of all CoZrNb layers is low, independent of the application of a bias voltage. The orientation and structure of CoCr on CoZrNb can be improved by using a Ge intermediate layer, which results in a low coercivity of the CoCr. A Ti intermediate layer increases the coercivity. Ring heads show a dependence of spike noise on the underlayer coercivity and on the applied normal force. A probe-type head shows a dependence of its output on the CoCr coercivity, which may be understood in terms of demagnetization and writing depth

  12. A non-magnetic spacer layer effect on spin layers (7/2,3) in a bi-layer ferromagnetic dendrimer structure: Monte Carlo study

    Science.gov (United States)

    Jabar, A.; Tahiri, N.; Bahmad, L.; Benyoussef, A.

    2016-11-01

    A bi-layer system consisting of layers of spins (7/2, 3) in a ferromagnetic dendrimer structure, separated by a non-magnetic spacer, is studied by Monte Carlo simulations. The effect of the RKKY interactions is investigated and discussed for such system. It is shown that the magnetic properties in the two magnetic layers depend strongly on the thickness of the magnetic and non-magnetic layers. The total magnetizations and susceptibilities are studied as a function of the reduced temperature. The effect of the reduced exchange interactions as well as the reduced crystal field is outlined. On other hand, the critical temperature is discussed as a function of the magnetic layer values. To complete this study we presented and discussed the magnetic hysteresis cycles.

  13. Layer-by-Layer Assembly for Preparation of High-Performance Forward Osmosis Membrane

    Science.gov (United States)

    Yang, Libin; Zhang, Jinglong; Song, Peng; Wang, Zhan

    2018-01-01

    Forward osmosis (FO) membrane with high separation performance is needed to promote its practical applications. Herein, layer-by-layer (LbL) approach was used to prepare a thin and highly cross-linked polyamide layer on a polyacrylonitrile substrate surface to prepare a thin-film composite forward osmosis (TFC-FO) membrane with enhanced FO performance. The effects of monomer concentrations and assembly cycles on the performance of the TFC-FO membranes were systematically investigated. Under the optimal preparation condition, TFC-FO membrane achieved the best performance, exhibiting the water flux of 14.4/6.9 LMH and reverse salt flux of 7.7/3.8 gMH under the pressure retarded osmosis/forward osmosis (PRO/FO) mode using 1M NaCl as the draw against a DI-water feed, and a rejection of 96.1% for 2000 mg/L NaCl aqueous solution. The result indicated that layer-by-layer method was a potential method to regulate the structure and performance of the TFC-FO membrane.

  14. Towards a super-strainable paper using the Layer-by-Layer technique.

    Science.gov (United States)

    Marais, Andrew; Utsel, Simon; Gustafsson, Emil; Wågberg, Lars

    2014-01-16

    The Layer-by-Layer technique was used to build a polyelectrolyte multilayer on the surface of pulp fibres. The treated fibres were then used to prepare paper sheets and the mechanical properties of these sheets were evaluated as a function of the number of bi-layers on the fibres. Two different systems were studied: polyethyleneimine (PEI)/nanofibrillated cellulose (NFC), and polyallylamine hydrochloride (PAH)/hyaluronic acid (HA). Model experiments using dual polarization interferometry and SiO₂ surfaces showed that the two systems gave different thicknesses for a given number of layers. The outer layer was found to be a key parameter in the PEI/NFC system, whereas it was less important in the PAH/HA system. The mechanical properties of the sheets made from the PAH/HA treated fibres were significantly greater than those made from untreated fibres, reaching 70 Nm/g in tensile index and 6.5% in strain at break. Such a modification could be very useful for 3D forming of paper, opening new perspectives in for example the packaging industry, with a renewable and biodegradable product as a potential substitute for some of the traditional oil-based plastics. Copyright © 2013 Elsevier Ltd. All rights reserved.

  15. On the modeling of electrical boundary layer (electrode layer) and ...

    Indian Academy of Sciences (India)

    In the first part of the paper, equations and methodology are discussed and in the second, we discuss results. 2. Methodology. In the atmospheric electricity, the earth's surface is one electrode and electrode layer or electrical boundary layer is a region near the surface of the earth in which profiles of atmospheric electrical.

  16. Nitrite reduction on a multimetallic porphyrin/polyoxotungstate layer-by-layer modified electrodes

    International Nuclear Information System (INIS)

    García, Macarena; Honores, Jessica; Quezada, Diego; Díaz, Carlos; Dreyse, Paulina; Celis, Freddy; Kubiak, Clifford P.; Canzi, Gabriele; Guzmán, Fernando

    2016-01-01

    Electro and photoelectrochemical reduction of nitrite in aqueous solution was studied using a multielectrocatalysts modified ITO electrode. ITO modification was carried out using the layer-by-layer (LBL) method, where sequential electrostatic assemblies were formed using a μ-(meso-5,10,15,20-tetra(pirydil)porphyrin)tetrakis{bis(bipyridine)chloride ruthenium (II)} [MTRP] n+ , coordinated in its central cavity with Mn(III), Zn(II) or Ni(II) as a cationic layer, and polyoxotungstate [SiW 12 O 40 ] 4− as the anionic layer. Electrochemical measurements and UV–vis spectroscopy were used to monitor the modification process. Optimal results were obtained when three layers were deposited onto the ITO surface and were stable in aqueous solution. The order of the multilayer formation was explored by comparing a modified electrode where [Zn(II)TRP] 4+ was the outermost layer with an electrode where [SiW 12 O 40 ] 4− was the outer layer. Results show that the best performing electrode is one with [SiW 12 O 40 ] 4− as the outer layer. Nitrite reduction on these electrode surfaces was studied in dark conditions and under light irradiation. Potential controlled electrolysis experiments were also performed, finding hydroxylamine, hydrazine and ammonia as the reduction products in dark conditions. Under light irradiation, only hydrazine and ammonia were found and, we observed an increase in the amount of obtained product. In this case, the electrolysis was carried out 150 mV less and half of time than in dark conditions. These results show that the combination of light and potential give rise to an improvement in the electrocatalytic properties of the modified electrodes. Continuous photolysis and IR spectroelectrochemical experiments were carried out to determinate the nature of this phenomena, evidencing the formation of an intermediary species between nitrite and [Mn(III)TRP] 5+.

  17. Analysis of turbulent boundary layers

    CERN Document Server

    Cebeci, Tuncer

    1974-01-01

    Analysis of Turbulent Boundary Layers focuses on turbulent flows meeting the requirements for the boundary-layer or thin-shear-layer approximations. Its approach is devising relatively fundamental, and often subtle, empirical engineering correlations, which are then introduced into various forms of describing equations for final solution. After introducing the topic on turbulence, the book examines the conservation equations for compressible turbulent flows, boundary-layer equations, and general behavior of turbulent boundary layers. The latter chapters describe the CS method for calculati

  18. Elastodynamic behavior of the three dimensional layer-by-layer metamaterial structure

    International Nuclear Information System (INIS)

    Aravantinos-Zafiris, N.; Sigalas, M. M.; Economou, E. N.

    2014-01-01

    In this work, we numerically investigate for the first time the elastodynamic behavior of a three dimensional layer-by-layer rod structure, which is easy to fabricate and has already proved to be very efficient as a photonic crystal. The Finite Difference Time Domain method was used for the numerical calculations. For the rods, several materials were examined and the effects of all the geometric parameters of the structure were also numerically investigated. Additionally, two modifications of the structure were included in our calculations. The results obtained here (for certain geometric parameters), exhibiting a high ratio of longitudinal over transverse sound velocity and therefore a close approach to ideal pentamode behavior over a frequency range, clearly show that the layer-by-layer rod structure, besides being an efficient photonic crystal, is a very serious contender as an elastodynamic metamaterial.

  19. The importance of proper crystal-chemical and geometrical reasoning demonstrated using layered single and double hydroxides

    International Nuclear Information System (INIS)

    Richardson, Ian G.

    2013-01-01

    The importance and utility of proper crystal-chemical and geometrical reasoning in structural studies is demonstrated through the consideration of layered single and double hydroxides. New yet fundamental information is provided and it is evident that the crystal chemistry of the double hydroxide phases is much more straightforward than is apparent from the literature. Atomistic modelling techniques and Rietveld refinement of X-ray powder diffraction data are widely used but often result in crystal structures that are not realistic, presumably because the authors neglect to check the crystal-chemical plausibility of their structure. The purpose of this paper is to reinforce the importance and utility of proper crystal-chemical and geometrical reasoning in structural studies. It is achieved by using such reasoning to generate new yet fundamental information about layered double hydroxides (LDH), a large, much-studied family of compounds. LDH phases are derived from layered single hydroxides by the substitution of a fraction (x) of the divalent cations by trivalent. Equations are derived that enable calculation of x from the a parameter of the unit cell and vice versa, which can be expected to be of widespread utility as a sanity test for extant and future structure determinations and computer simulation studies. The phase at x = 0 is shown to be an α form of divalent metal hydroxide rather than the β polymorph. Crystal-chemically sensible model structures are provided for β-Zn(OH) 2 and Ni- and Mg-based carbonate LDH phases that have any trivalent cation and any value of x, including x = 0 [i.e. for α-M(OH) 2 ·mH 2 O phases

  20. Role of residual layer and large-scale phenomena on the evolution of the boundary layer

    NARCIS (Netherlands)

    Blay, E.; Pino, D.; Vilà-Guerau de Arellano, J.; Boer, van de A.; Coster, de O.; Faloona, I.; Garrouste, O.; Hartogensis, O.K.

    2012-01-01

    Mixed-layer theory and large-eddy simulations are used to analyze the dynamics of the boundary layer on two intensive operational periods during the Boundary Layer Late Afternoon and Sunset Turbulence (BLLAST) campaign: 1st and 2nd of July 2011, when convective boundary layers (CBLs) were observed.

  1. Widespread promoter methylation of synaptic plasticity genes in long-term potentiation in the adult brain in vivo.

    Science.gov (United States)

    Maag, Jesper L V; Kaczorowski, Dominik C; Panja, Debabrata; Peters, Timothy J; Bramham, Clive R; Wibrand, Karin; Dinger, Marcel E

    2017-03-23

    DNA methylation is a key modulator of gene expression in mammalian development and cellular differentiation, including neurons. To date, the role of DNA modifications in long-term potentiation (LTP) has not been explored. To investigate the occurrence of DNA methylation changes in LTP, we undertook the first detailed study to describe the methylation status of all known LTP-associated genes during LTP induction in the dentate gyrus of live rats. Using a methylated DNA immunoprecipitation (MeDIP)-array, together with previously published matched RNA-seq and public histone modification data, we discover widespread changes in methylation status of LTP-genes. We further show that the expression of many LTP-genes is correlated with their methylation status. We show that these correlated genes are enriched for RNA-processing, active histone marks, and specific transcription factors. These data reveal that the synaptic activity-evoked methylation changes correlates with pre-existing activation of the chromatin landscape. Finally, we show that methylation of Brain-derived neurotrophic factor (Bdnf) CpG-islands correlates with isoform switching from transcripts containing exon IV to exon I. Together, these data provide the first evidence of widespread regulation of methylation status in LTP-associated genes.

  2. Electroless atomic layer deposition

    Science.gov (United States)

    Robinson, David Bruce; Cappillino, Patrick J.; Sheridan, Leah B.; Stickney, John L.; Benson, David M.

    2017-10-31

    A method of electroless atomic layer deposition is described. The method electrolessly generates a layer of sacrificial material on a surface of a first material. The method adds doses of a solution of a second material to the substrate. The method performs a galvanic exchange reaction to oxidize away the layer of the sacrificial material and deposit a layer of the second material on the surface of the first material. The method can be repeated for a plurality of iterations in order to deposit a desired thickness of the second material on the surface of the first material.

  3. Inter-Layer Energy Transfer through Wetting-Layer States in Bi-layer InGaAs/GaAs Quantum-Dot Structures with Thick Barriers

    DEFF Research Database (Denmark)

    Xu, Zhang-Cheng; Zhang, Ya-Ting; Hvam, Jørn Märcher

    2009-01-01

    The inter-layer energy transfer in a bi-layer InGaAs/GaAs quantum dot structure with a thick GaAs barrier is studied using temperature-dependent photoluminescence. The abnormal enhancement of the photoluminescence of the QDs in the layer with a larger amount of coverage at 110K is observed, which...

  4. Adhesion Between Poly(dimethylsiloxane) Layers

    DEFF Research Database (Denmark)

    Yu, Liyun; Daugaard, Anders Egede; Skov, Anne Ladegaard

    Different adhesion methods of poly(dimethylsiloxane) (PDMS) layers were studied with respect to adhesional force and the resulting rheology of the two-layered PDMS films were investigated. The role of adhesion between PDMS layers on the performances of two-layer structures was studied with peel...... strength test and by SEM pictures. The rheology of the double-layered compared to the monolayer films changed in some cases which indicates that the adhesion process needs to be carefully introduced in order not to alter the final properties....

  5. Conserved S-Layer-Associated Proteins Revealed by Exoproteomic Survey of S-Layer-Forming Lactobacilli

    Science.gov (United States)

    Johnson, Brant R.; Hymes, Jeffrey; Sanozky-Dawes, Rosemary; Henriksen, Emily DeCrescenzo

    2015-01-01

    The Lactobacillus acidophilus homology group comprises Gram-positive species that include L. acidophilus, L. helveticus, L. crispatus, L. amylovorus, L. gallinarum, L. delbrueckii subsp. bulgaricus, L. gasseri, and L. johnsonii. While these bacteria are closely related, they have varied ecological lifestyles as dairy and food fermenters, allochthonous probiotics, or autochthonous commensals of the host gastrointestinal tract. Bacterial cell surface components play a critical role in the molecular dialogue between bacteria and interaction signaling with the intestinal mucosa. Notably, the L. acidophilus complex is distinguished in two clades by the presence or absence of S-layers, which are semiporous crystalline arrays of self-assembling proteinaceous subunits found as the outermost layer of the bacterial cell wall. In this study, S-layer-associated proteins (SLAPs) in the exoproteomes of various S-layer-forming Lactobacillus species were proteomically identified, genomically compared, and transcriptionally analyzed. Four gene regions encoding six putative SLAPs were conserved in the S-layer-forming Lactobacillus species but not identified in the extracts of the closely related progenitor, L. delbrueckii subsp. bulgaricus, which does not produce an S-layer. Therefore, the presence or absence of an S-layer has a clear impact on the exoproteomic composition of Lactobacillus species. This proteomic complexity and differences in the cell surface properties between S-layer- and non-S-layer-forming lactobacilli reveal the potential for SLAPs to mediate intimate probiotic interactions and signaling with the host intestinal mucosa. PMID:26475115

  6. Mapping the layer count of few-layer hexagonal boron nitride at high lateral spatial resolutions

    Science.gov (United States)

    Mohsin, Ali; Cross, Nicholas G.; Liu, Lei; Watanabe, Kenji; Taniguchi, Takashi; Duscher, Gerd; Gu, Gong

    2018-01-01

    Layer count control and uniformity of two dimensional (2D) layered materials are critical to the investigation of their properties and to their electronic device applications, but methods to map 2D material layer count at nanometer-level lateral spatial resolutions have been lacking. Here, we demonstrate a method based on two complementary techniques widely available in transmission electron microscopes (TEMs) to map the layer count of multilayer hexagonal boron nitride (h-BN) films. The mass-thickness contrast in high-angle annular dark-field (HAADF) imaging in the scanning transmission electron microscope (STEM) mode allows for thickness determination in atomically clean regions with high spatial resolution (sub-nanometer), but is limited by surface contamination. To complement, another technique based on the boron K ionization edge in the electron energy loss spectroscopy spectrum (EELS) of h-BN is developed to quantify the layer count so that surface contamination does not cause an overestimate, albeit at a lower spatial resolution (nanometers). The two techniques agree remarkably well in atomically clean regions with discrepancies within  ±1 layer. For the first time, the layer count uniformity on the scale of nanometers is quantified for a 2D material. The methodology is applicable to layer count mapping of other 2D layered materials, paving the way toward the synthesis of multilayer 2D materials with homogeneous layer count.

  7. Local electromagnetic waves in layered superconductors

    International Nuclear Information System (INIS)

    Gvozdikov, V.M.; Vega-Monroy, R.

    1999-01-01

    A dispersion equation for electromagnetic waves localized on a defect layer of a layered superconductor is obtained in the frame of a model which neglects electron hopping between layers but assumes an arbitrary current-current response function within the layers. The defect layer differs from the rest of the layers by density and mass of charge carriers. It is shown that near the critical temperature in the London limit the local mode lies within the superconducting gap and has a wave vector threshold depending on the layered crystal and defect layer parameters. In the case of highly anisotropic layered superconductors, like Bi- or Tl-based high-T c cuprates, the local mode exists within a narrow range of positive variations of the mass and charge carriers. (author)

  8. Spin-Assisted Layer-by-Layer Assembly: Variation of Stratification as Studied with Neutron Reflectivity

    International Nuclear Information System (INIS)

    Kharlampieva, Eugenia; Kozlovskaya, Veronika; Chan, Jennifer; Ankner, John Francis; Tsukruk, Vladimir V.

    2009-01-01

    We apply neutron reflectivity to probe the internal structure of spin-assisted layer-by-layer (LbL) films composed of electrostatically assembled polyelectrolytes. We find that the level of stratification and the degree of layer intermixing can be controlled by varying the type and concentration of salt during LbL assembly. We observe well-defined layer structure in spin-assisted LbL films when deposited from salt-free solutions. These films feature 2-nm-thick bilayers, which are ∼3-fold thicker than those in dipped LbL films assembled under similar conditions. Addition of a 10mM phosphate buffer promotes progressive layer inter-diffusion with increasing distance from the substrate. However, adding 0.1M NaCl to the phosphate buffer solution restores the layer stratification. We also find that spin-assisted LbL films obtained from buffer solutions are more highly stratified as compared to the highly intermixed layers seen in dipped LbL films assembled from buffer. Our results yield new insight into the mechanism of spin-assisted LbL assembly that should prove useful for biotechnological applications.

  9. Freestanding films of crosslinked gold nanoparticles prepared via layer-by-layer spin-coating

    Science.gov (United States)

    Schlicke, Hendrik; Schröder, Jan H.; Trebbin, Martin; Petrov, Alexey; Ijeh, Michael; Weller, Horst; Vossmeyer, Tobias

    2011-07-01

    A new, extremely efficient method for the fabrication of films comprised of gold nanoparticles (GNPs) crosslinked by organic dithiols is presented in this paper. The method is based on layer-by-layer spin-coating of both components, GNPs and crosslinker, and enables the deposition of films several tens of nanometers in thickness within a few minutes. X-ray diffraction and conductance measurements reveal the proper adjustment concentration of the crosslinker solution of the critical is in order to prevent the destabilization and coalescence of particles. UV/vis spectroscopy, atomic force microscopy, and conductivity measurements indicate that films prepared via layer-by-layer spin-coating are of comparable quality to coatings prepared via laborious layer-by-layer self-assembly using immersion baths. Because spin-coated films are not bound chemically to the substrate, they can be lifted-off by alkaline underetching and transferred onto 3d-electrodes to produce electrically addressable, freely suspended films. Comparative measurements of the sheet resistances indicate that the transfer process does not compromise the film quality.

  10. Freestanding films of crosslinked gold nanoparticles prepared via layer-by-layer spin-coating

    International Nuclear Information System (INIS)

    Schlicke, Hendrik; Schroeder, Jan H; Trebbin, Martin; Petrov, Alexey; Ijeh, Michael; Weller, Horst; Vossmeyer, Tobias

    2011-01-01

    A new, extremely efficient method for the fabrication of films comprised of gold nanoparticles (GNPs) crosslinked by organic dithiols is presented in this paper. The method is based on layer-by-layer spin-coating of both components, GNPs and crosslinker, and enables the deposition of films several tens of nanometers in thickness within a few minutes. X-ray diffraction and conductance measurements reveal the proper adjustment concentration of the crosslinker solution of the critical is in order to prevent the destabilization and coalescence of particles. UV/vis spectroscopy, atomic force microscopy, and conductivity measurements indicate that films prepared via layer-by-layer spin-coating are of comparable quality to coatings prepared via laborious layer-by-layer self-assembly using immersion baths. Because spin-coated films are not bound chemically to the substrate, they can be lifted-off by alkaline underetching and transferred onto 3d-electrodes to produce electrically addressable, freely suspended films. Comparative measurements of the sheet resistances indicate that the transfer process does not compromise the film quality.

  11. Cellulose fiber-enzyme composites fabricated through layer-by-layer nanoassembly.

    Science.gov (United States)

    Xing, Qi; Eadula, Sandeep R; Lvov, Yuri M

    2007-06-01

    Cellulose microfibers were coated with enzymes, laccase and urease, through layer-by-layer assembly by alternate adsorption with oppositely charged polycations. The formation of organized polyelectrolyte and enzyme multilayer films of 15-20 nm thickness was demonstrated by quartz crystal microbalance, zeta-potential analysis, and confocal laser scanning microscopy. These biocomposites retained enzymatic catalytic activity, which was proportional to the number of coated enzyme layers. For laccase-fiber composites, around 50% of its initial activity was retained after 2 weeks of storage at 4 degrees C. The synthesis of calcium carbonate microparticles on urease-fiber composites confirmed urease functionality and demonstrated its possible applications. This strategy could be employed to fabricate fiber-based composites with novel biological functions.

  12. Simulation of Natural Convection in the Oxide Layer of Three-Layer Corium Pool in an IVR

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Su-Hyeon; Park, Hae-Kyun; Chung, Bum-Jin [Kyung Hee University, Yongin (Korea, Republic of)

    2016-10-15

    This paper describes the three-layer phenomena and preliminary plan to simulate the oxide layer experimentally. We will perform the mass transfer experiments using a copper sulfate-sulfuric acid (CuSO{sub 4}-H{sub 2}SO{sub 4}) electroplating system based on the heat and mass transfer analogy concept. By performing the mass transfer experiments, we can achieve the high buoyancy condition with small facilities. The test facility is semicircular whose bottom is chopped, simulating the oxide pool above the heavy metal layer in a three-layer configuration. We will measure the heat flux at the top plate, side wall and bottom plate, and compare these results with those for a two-layer pool. In a three-layer configuration, the upper light metal layer becomes thinner, increasing the focusing effect. Thus, it is important to evaluate the heat flux from the oxide pool to the upper metallic layer. However, there is few heat transfer studies for a three-layer configuration. This paper is to discuss and to make a plan for the heat transfer experiments of oxide pool in a three- layer system. We will perform the mass transfer experiments based on the heat and mass transfer analogy concept. The test results will be analyzed phenomenologically and compared with two-layer results.

  13. Reducing interface recombination for Cu(In,Ga)Se{sub 2} by atomic layer deposited buffer layers

    Energy Technology Data Exchange (ETDEWEB)

    Hultqvist, Adam; Bent, Stacey F. [Department of Chemical Engineering, Stanford University, Stanford, California 94305 (United States); Li, Jian V.; Kuciauskas, Darius; Dippo, Patricia; Contreras, Miguel A.; Levi, Dean H. [National Renewable Energy Laboratory, Golden, Colorado 80401 (United States)

    2015-07-20

    Partial CuInGaSe{sub 2} (CIGS) solar cell stacks with different atomic layer deposited buffer layers and pretreatments were analyzed by photoluminescence (PL) and capacitance voltage (CV) measurements to investigate the buffer layer/CIGS interface. Atomic layer deposited ZnS, ZnO, and SnO{sub x} buffer layers were compared with chemical bath deposited CdS buffer layers. Band bending, charge density, and interface state density were extracted from the CV measurement using an analysis technique new to CIGS. The surface recombination velocity calculated from the density of interface traps for a ZnS/CIGS stack shows a remarkably low value of 810 cm/s, approaching the range of single crystalline II–VI systems. Both the PL spectra and its lifetime depend on the buffer layer; thus, these measurements are not only sensitive to the absorber but also to the absorber/buffer layer system. Pretreatment of the CIGS prior to the buffer layer deposition plays a significant role on the electrical properties for the same buffer layer/CIGS stack, further illuminating the importance of good interface formation. Finally, ZnS is found to be the best performing buffer layer in this study, especially if the CIGS surface is pretreated with potassium cyanide.

  14. The importance of proper crystal-chemical and geometrical reasoning demonstrated using layered single and double hydroxides

    Science.gov (United States)

    Richardson, Ian G.

    2013-01-01

    Atomistic modelling techniques and Rietveld refinement of X-ray powder diffraction data are widely used but often result in crystal structures that are not realistic, presumably because the authors neglect to check the crystal-chemical plausibility of their structure. The purpose of this paper is to reinforce the importance and utility of proper crystal-chemical and geometrical reasoning in structural studies. It is achieved by using such reasoning to generate new yet fundamental information about layered double hydroxides (LDH), a large, much-studied family of compounds. LDH phases are derived from layered single hydroxides by the substitution of a fraction (x) of the divalent cations by trivalent. Equations are derived that enable calculation of x from the a parameter of the unit cell and vice versa, which can be expected to be of widespread utility as a sanity test for extant and future structure determinations and computer simulation studies. The phase at x = 0 is shown to be an α form of divalent metal hydroxide rather than the β polymorph. Crystal-chemically sensible model structures are provided for β-Zn(OH)2 and Ni- and Mg-based carbonate LDH phases that have any trivalent cation and any value of x, including x = 0 [i.e. for α-M(OH)2·mH2O phases]. PMID:23719702

  15. Skin layer mechanics

    NARCIS (Netherlands)

    Geerligs, M.

    2010-01-01

    The human skin is composed of several layers, each with an unique structure and function. Knowledge about the mechanical behavior of these skin layers is important for clinical and cosmetic research, such as the development of personal care products and the understanding of skin diseases. Until

  16. Layered materials

    Science.gov (United States)

    Johnson, David; Clarke, Simon; Wiley, John; Koumoto, Kunihito

    2014-06-01

    Layered compounds, materials with a large anisotropy to their bonding, electrical and/or magnetic properties, have been important in the development of solid state chemistry, physics and engineering applications. Layered materials were the initial test bed where chemists developed intercalation chemistry that evolved into the field of topochemical reactions where researchers are able to perform sequential steps to arrive at kinetically stable products that cannot be directly prepared by other approaches. Physicists have used layered compounds to discover and understand novel phenomena made more apparent through reduced dimensionality. The discovery of charge and spin density waves and more recently the remarkable discovery in condensed matter physics of the two-dimensional topological insulating state were discovered in two-dimensional materials. The understanding developed in two-dimensional materials enabled subsequent extension of these and other phenomena into three-dimensional materials. Layered compounds have also been used in many technologies as engineers and scientists used their unique properties to solve challenging technical problems (low temperature ion conduction for batteries, easy shear planes for lubrication in vacuum, edge decorated catalyst sites for catalytic removal of sulfur from oil, etc). The articles that are published in this issue provide an excellent overview of the spectrum of activities that are being pursued, as well as an introduction to some of the most established achievements in the field. Clusters of papers discussing thermoelectric properties, electronic structure and transport properties, growth of single two-dimensional layers, intercalation and more extensive topochemical reactions and the interleaving of two structures to form new materials highlight the breadth of current research in this area. These papers will hopefully serve as a useful guideline for the interested reader to different important aspects in this field and

  17. Observation-based assessment of functional ability in patients with chronic widespread pain

    DEFF Research Database (Denmark)

    Amris, Kirstine; Wæhrens, Eva Ejlersen; Jespersen, Anders

    2011-01-01

    Knowledge about functional ability, including activities of daily living (ADL), in patients with chronic widespread pain (CWP) and fibromyalgia (FMS) is largely based on self-report. The purpose of this study was to assess functional ability by using standardised, observation-based assessment...... of ADL performance and to examine the relationship between self-reported and observation-based measures of disability. A total of 257 women with CWP, 199 (77%) fulfilling the American College of Rheumatology tender point criteria for FMS, were evaluated with the Assessment of Motor and Process Skills...... (AMPS), an observation-based assessment providing linear measures of ADL motor and ADL process skill ability (unit: logits). A cutoff for effortless and independent ADL task performance is set at 2.0 for the motor scale and 1.0 for the process scale. A total of 248 (96.5%) had ability measures below...

  18. Neocortical layer 6, a review

    Directory of Open Access Journals (Sweden)

    Alex M Thomson

    2010-03-01

    Full Text Available This review attempts to summarise some of the major areas of neocortical research as it pertains to layer 6. After a brief summary of the development of this intriguing layer, the major pyramidal cell classes to be found in layer 6 are described and compared. The connections made and received by these different classes of neurones are then discussed and the possible functions of these connections, with particular reference to the shaping of responses in visual cortex and thalamus. Inhibition in layer 6 is discussed where appropriate, but not in great detail. Many types of interneurones are to be found in each cortical layer and layer 6 is no exception, but the functions of each type remain to be elucidated.

  19. Monitoring layer-by-layer assembly of polyelectrolyte multi-layers using high-order cladding mode in long-period fiber gratings

    Czech Academy of Sciences Publication Activity Database

    Tian, F.; Kaňka, Jiří; Li, X.; Du, H.

    -, č. 196 (2014), s. 475-479 ISSN 0925-4005 R&D Projects: GA MŠk(CZ) LH11038 Institutional support: RVO:67985882 Keywords : Layer-by-layer assembly * Polyelectrolyte * Cladding mode Subject RIV: JA - Electronics ; Optoelectronics, Electrical Engineering Impact factor: 4.097, year: 2014

  20. Layer-by-Layer Enabled Nanomaterials for Chemical Sensing and Energy Conversion

    Science.gov (United States)

    Paterno, Leonardo G.; Soler, Maria A. G.

    2013-06-01

    The layer-by-layer (LbL) technique is a wet chemical method for the assembly of ultrathin films, with thicknesses up to 100 nm. This method is based on the successive transfer of molecular layers to a solid substrate that is dipped into cationic and anionic solutions in an alternating fashion. The adsorption is mainly driven by electrostatic interactions so that many molecular and nanomaterial systems can be engineered under this method. Moreover, it is inexpensive, can be easily performed, and does not demand sophisticated equipment or clean rooms. The most explored use of the LbL technique is to build up molecular devices for chemical sensing and energy conversion. Both applications require ultrathin films where specific elements must be organized with high control of thickness and spatial distribution, preferably in the nanolength and mesolength scales. In chemical sensors, the LbL technique is employed to assemble specific sensoactive materials such as conjugated polymers, enzymes, and immunological elements onto appropriated electrodes. Molecular recognition events are thus transduced by the assembled sensoactive layer. In energy-conversion devices, the LbL technique can be employed to fabricate different device's parts including electrodes, active layers, and auxiliary layers. In both applications, the devices' performance can be fully modulated and improved by simply varying film thickness and molecular architecture. The present review article highlights the main features of the LbL technique and provides a brief description of different (bio)chemical sensors, solar cells, and organic light-emitting diodes enabled by the LbL approach.

  1. Improved electron transport layer

    DEFF Research Database (Denmark)

    2012-01-01

    The present invention provides: a method of preparing a coating ink for forming a zinc oxide electron transport layer, comprising mixing zinc acetate and a wetting agent in water or methanol; a coating ink comprising zinc acetate and a wetting agent in aqueous solution or methanolic solution......; a method of preparing a zinc oxide electron transporting layer, which method comprises: i) coating a substrate with the coating ink of the present invention to form a film; ii) drying the film; and iii) heating the dry film to convert the zinc acetate substantially to ZnO; a method of preparing an organic...... photovoltaic device or an organic LED having a zinc oxide electron transport layer, the method comprising, in this order: a) providing a substrate bearing a first electrode layer; b) forming an electron transport layer according to the following method: i) coating a coating ink comprising an ink according...

  2. The importance of safety in achieving the widespread use of hydrogen as a fuel

    Energy Technology Data Exchange (ETDEWEB)

    Edeskuty, F.J.

    1997-09-01

    The advantages of hydrogen fuel have been adequately demonstrated on numerous occasions. However, two major disadvantages have prevented any significant amount of corresponding development. These disadvantages have been in the economics of producing sufficient quantities of hydrogen and in the safety (both real and perceived) of its use. To date work has mostly been properly centered on solving the economic problems. However, a greater effort on the safety of new hydrogen systems now being proposed also deserves consideration. To achieve the greatest safety in the expansion of the use of hydrogen into its wide-spread use as a fuel, attention must be given to four considerations. These are, obtaining knowledge of all the physical principles involved in the new uses, having in place the regulations that allow the safe interfacing of the new systems, designing and constructing the new systems with safety in mind, and the training of the large number of people that will become the handlers of the hydrogen. Existing organizations that produce, transport, or use hydrogen on a large scale have an excellent safety record. This safety record comes as a consequence of dedicated attention to the above-mentioned principles. However, where these principles were not closely followed, accidents have resulted. Some examples can be cited. As the use of hydrogen becomes more widespread, there must be a mechanism for assuring the universal application of these principles. Larger and more numerous fleet operations with hydrogen fuel may be the best way to begin the indoctrination of the general public to the more general use of hydrogen fuel. Demonstrated safe operation with hydrogen is vital to its final acceptance as the fuel of choice.

  3. Effect of layer thickness on the thermal release from Be-D co-deposited layers

    Science.gov (United States)

    Baldwin, M. J.; Doerner, R. P.

    2014-08-01

    The results of previous work (Baldwin et al 2013 J. Nucl. Mater. 438 S967-70 and Baldwin et al 2014 Nucl. Fusion 54 073005) are extended to explore the influence of layer thickness on the thermal D2 release from co-deposited Be-(0.05)D layers produced at ˜323 K. Bake desorption of layers of thickness 0.2-0.7 µm are explored with a view to examine the influence of layer thickness on the efficacy of the proposed ITER bake procedure, to be carried out at the fixed temperatures of 513 K on the first wall and 623 K in the divertor. The results of experiment and modelling with the TMAP-7 hydrogen transport code, show that thicker Be-D co-deposited layers are relatively more difficult to desorb (time-wise) than thinner layers with the same concentrations of intrinsic traps and retained hydrogen isotope fraction.

  4. On the applicability of the layered sine-Gordon model for Josephson-coupled high-Tc layered superconductors

    International Nuclear Information System (INIS)

    Nandori, I; Jentschura, U D; Nagy, S; Sailer, K; Vad, K; Meszaros, S

    2007-01-01

    We find a mapping of the layered sine-Gordon model to an equivalent gas of topological excitations and determine the long-range interaction potentials of the topological defects. This enables us to make a detailed comparison to the so-called layered vortex gas, which can be obtained from the layered Ginzburg-Landau model. The layered sine-Gordon model has been proposed in the literature as a candidate field-theoretical model for Josephson-coupled high-T c superconductors, and the implications of our analysis for the applicability of the layered sine-Gordon model to high-T c superconductors are discussed. We are led to the conjecture that the layered sine-Gordon and the layered vortex gas models belong to different universality classes. The determination of the critical temperature of the layered sine-Gordon model is based on a renormalization-group analysis

  5. Ash production by attrition in volcanic conduits and plumes.

    Science.gov (United States)

    Jones, T J; Russell, J K

    2017-07-17

    Tephra deposits result from explosive volcanic eruption and serve as indirect probes into fragmentation processes operating in subsurface volcanic conduits. Primary magmatic fragmentation creates a population of pyroclasts through volatile-driven decompression during conduit ascent. In this study, we explore the role that secondary fragmentation, specifically attrition, has in transforming primary pyroclasts upon transport in volcanic conduits and plumes. We utilize total grain size distributions from a suite of natural and experimentally produced tephra to show that attrition is likely to occur in all explosive volcanic eruptions. Our experimental results indicate that fine ash production and surface area generation is fast (eruption column stability, tephra dispersal, aggregation, volcanic lightening generation, and has concomitant effects on aviation safety and Earth's climate.

  6. Layer-by-layer self-assembled active electrodes for hybrid photovoltaic cells

    Energy Technology Data Exchange (ETDEWEB)

    Kniprath, Rolf

    2008-11-18

    Solar cells based on thin organic/inorganic heterofilms are currently in the focus of research, since they represent promising candidates for cost-efficient photovoltaic energy conversion. In this type of cells, charges are separated at a heterointerface between dissimilar electrode materials. These materials either absorb light themselves, or they are sensitized by an additional absorber layer at the interface. The present work investigates photovoltaic cells which are composed of nanoporous TiO{sub 2} combined with conjugated polymers and semiconductor quantum dots (QDs). The method of layer-by-layer self-assembly of oppositely charged nanoparticles and polymers is used for the fabrication of such devices. This method allows to fabricate nanoporous films with controlled thicknesses in the range of a few hundred nanometers to several micrometers. Investigations with scanning electron (SEM) and atomic force microscopy (AFM) reveal that the surface morphology of the films depends only on the chemical structure of the polyions used in the production process, and not on their molecular weight or conformation. From dye adsorption at the internal surface of the electrodes one can estimate that the internal surface area of a 1 {mu}m thick film is up to 120 times larger than the projection plane. X-ray photoelectron spectroscopy (XPS) is used to demonstrate that during the layer-by-layer self-assembly at least 40% of the TiO{sub 2} surface is covered with polymers. This feature allows to incorporate polythiophene derivatives into the films and to use them as sensitizers for TiO{sub 2}. Further, electrodes containing CdSe or CdTe quantum dots (QDs) as sensitizers are fabricated. For the fabrication of photovoltaic cells the layer-by-layer grown films are coated with an additional polymer layer, and Au back electrodes are evaporated on top. The cells are illuminated through transparent doped SnO{sub 2} front electrodes. The I/V curves of all fabricated cells show diode

  7. Economical Atomic Layer Deposition

    Science.gov (United States)

    Wyman, Richard; Davis, Robert; Linford, Matthew

    2010-10-01

    Atomic Layer Deposition is a self limiting deposition process that can produce films at a user specified height. At BYU we have designed a low cost and automated atomic layer deposition system. We have used the system to deposit silicon dioxide at room temperature using silicon tetrachloride and tetramethyl orthosilicate. Basics of atomic layer deposition, the system set up, automation techniques and our system's characterization are discussed.

  8. Spacer layer effect and microstructure on multi-layer [NdFeB/Nb]n films

    International Nuclear Information System (INIS)

    Tsai, J.-L.; Yao, Y.-D.; Chin, T.-S.; Kronmueller, H.

    2002-01-01

    Spacer layer effect on multi-layer [NdFeB/Nb] n films has been investigated from the variation of magnetic properties and microstructure of the films. From a HRTEM cross-section view observation, the average grain size of [NdFeB/Nb] n multi-layers was controlled by both annealing temperature and thickness of NdFeB layer. Selected area diffraction pattern indicated that the structure of Nb spacer layer was amorphous. The grain size and coercivity of [NdFeB x /Nb] n films change from 50 nm and 16.7 kOe to 167 nm and 9 kOe for films with x=40 nm, n=10 and x=200 nm, n=2, respectively