Corrosion behaviour of construction materials for high temperature water electrolysers

Energy Technology Data Exchange (ETDEWEB)

Nikiforov, A.; Petruchina, I.; Christensen, E.; Bjerrum, N.J.; Tomas-Garcya, A.L. [Technical Univ. of Denmark, Lyngby (Denmark). Dept. of Chemistry, Materials Science Group

2010-07-01

This presentation reported on a study in which the feasibility of using different corrosion resistant stainless steels as a possible metallic bipolar plate and construction material was evaluated in terms of corrosion resistance under conditions corresponding to the conditions in high temperature proton exchange membrane (PEM) water electrolysers (HTPEMWE). PEM water electrolysis technology has been touted as an effective alternative to more conventional alkaline water electrolysis. Although the energy efficiency of this technology can be increased considerably at temperatures above 100 degrees C, this increases the demands to all the used materials with respect to corrosion stability and thermal stability. In this study, Ni-based alloys as well as titanium and tantalum samples were exposed to anodic polarization in 85 per cent phosphoric acid electrolyte solution. Tests were performed at 80 and 120 degrees C to determine the dependence of corrosion speed and working temperature. Platinum and gold plates were also tested for a comparative evaluation. Steady-state voltammetry was used along with scanning electron microscopy and energy-dispersive X-ray spectroscopy. Titanium showed the poorest corrosion resistance, while Ni-based alloys showed the highest corrosion resistance, with Inconel R 625 being the most promising alloy for the bipolar plate of an HTPEMWE. 3 refs., 1 tab., 2 figs.

Temperature measurements in a wall stabilized steady flame using CARS

KAUST Repository

Sesha Giri, Krishna

2017-01-05

Flame quenching by heat loss to a surface continues to be an active area of combustion research. Close wall temperature measurements in an isothermal wall-stabilized flame are reported in this work. Conventional N-vibrational Coherent Anti-Stokes Raman Scattering (CARS) thermometry as close as 275 μm to a convex wall cooled with water has been carried out. The standard deviation of mean temperatures is observed to be ~6.5% for high temperatures (>2000K) and ~14% in the lower range (<500K). Methane/air and ethylene/air stoichiometric flames for various global strain rates based on exit bulk velocities are plotted and compared. CH* chemiluminescence is employed to determine the flame location relative to the wall. Flame locations are shown to move closer to the wall with increasing strain rates in addition to higher near-wall temperatures. Peak temperatures for ethylene are considerably higher (~250-300K) than peak temperatures for methane. Preheat zone profiles are similar for different strain rates across fuels. This work demonstrates close wall precise temperature measurments using CARS.

Temperature stabilization of injection lasers

International Nuclear Information System (INIS)

Albanese, A.

1987-01-01

Apparatus which stabilizes the temperature, and thereby the output wavelength, of an injection laser. Means monitor the laser terminal voltage across a laser and derive a voltage therefrom which is proportional to the junction voltage of the laser. Means compares the voltage to a reference value from source and a temperature controller adjusts the laser temperature in response to the results of the comparison. Further embodiments of the present invention vary the output wavelength of the laser by varying the reference value from source against which the laser junction voltage is compared. (author)

Synthesis of high-temperature viscosity stabilizer used in drilling fluid

Science.gov (United States)

Zhang, Yanna; Luo, Huaidong; Shi, Libao; Huang, Hongjun

2018-02-01

Abstract For a well performance drilling fluid, when it operates in deep wells under high temperature, the most important property required is the thermal stability. The drilling fluid properties under high temperature can be controlled by proper selection of viscosity stabilizer, which can capture oxygen to protect polymer agent in the drilling fluid. In this paper a viscosity stabilizer PB-854 is described, which was synthesized by 4-phenoxybutyl bromide, paraformaldehyde, and phloroglucinol using etherification method and condensation reaction. We studied the effect of catalyst dosage, temperature, time, and stirring rate on the synthetic yield. Under this condition: molar ratio of 2-tert-Butylphenol, paraformaldehyde and phloroglucinol of 2:1:2.5, reacting temperature of 100 °C, stirring rate of 100 r min-1, and mass content of catalyst of 15 %, char yield of 5-bromine-3-tert-butyl salicylaldehyde reached 86 %. Under this condition: molar ratio of 5-bromine-3-tert-butyl salicylaldehyde and phloroglucinol of 4, reacting temperature of 60 °C, reacting time of 30 min, volume content of sulphuric acid of 80 %, char yield of the target product viscosity stabilizer PB-854 is 86%. Finally, in this paper, infrared spectroscopy is adopted to analyse the structure of the synthetic product PB-854.The improvement in the stability of drilling fluid was further shown after adding the viscosity stabilizer in the common polymer drilling fluid under high temperature conditions of 120 °C ˜ 180 °C. The results show significant change in terms of fluid stability in the presence of this new stabilizer as it provides better stability.

Dynamic Stabilization of Metal Oxide–Water Interfaces

Energy Technology Data Exchange (ETDEWEB)

McBriarty, Martin E.; von Rudorff, Guido Falk; Stubbs, Joanne E.; Eng, Peter J.; Blumberger, Jochen; Rosso, Kevin M.

2017-02-08

The interaction of water with metal oxide surfaces plays a crucial role in the catalytic and geochemical behavior of metal oxides. In a vast majority of studies, the interfacial structure is assumed to arise from a relatively static lowest energy configuration of atoms, even at room temperature. Using hematite (α-Fe2O3) as a model oxide, we show through a direct comparison of in situ synchrotron X-ray scattering with density functional theory-based molecular dynamics simulations that the structure of the (1102) termination is dynamically stabilized by picosecond water exchange. Simulations show frequent exchanges between terminal aquo groups and adsorbed water in locations and with partial residence times consistent with experimentally determined atomic sites and fractional occupancies. Frequent water exchange occurs even for an ultrathin adsorbed water film persisting on the surface under a dry atmosphere. The resulting time-averaged interfacial structure consists of a ridged lateral arrangement of adsorbed water molecules hydrogen bonded to terminal aquo groups. Surface pKa prediction based on bond valence analysis suggests that water exchange will influence the proton-transfer reactions underlying the acid/base reactivity at the interface. Our findings provide important new insights for understanding complex interfacial chemical processes at metal oxide–water interfaces.

Homogenization Pressure and Temperature Affect Protein Partitioning and Oxidative Stability of Emulsions

DEFF Research Database (Denmark)

Horn, Anna Frisenfeldt; Barouh, Nathalie; Nielsen, Nina Skall

2013-01-01

The oxidative stability of 10 % fish oil-in-water emulsions was investigated for emulsions prepared under different homogenization conditions. Homogenization was conducted at two different pressures (5 or 22.5 MPa), and at two different temperatures (22 and 72 °C). Milk proteins were used...... prior to homogenization did not have any clear effect on lipid oxidation in either of the two types of emulsions....

Effect of sonochemical synthesized TiO2 nanoparticles and coagulation bath temperature on morphology, thermal stability and pure water flux of asymmetric cellulose acetate membranes prepared via phase inversion method

Directory of Open Access Journals (Sweden)

Abedini Reza

2012-01-01

Full Text Available In this study, asymmetric pure CA and CA/ TiO2 composite membranes were prepared via phase inversion by dispersing TiO2 nanopaticles in the CA casting solutions induced by immersion precipitation in water coagulation bath. TiO2 nanoparticles, which were synthesized by the sonochemical method, were added into the casting solution with different concentrations. Effects of TiO2 nanoparticles concentration (0 wt. %, 5wt.%, 10wt.%, 15wt.%, 20wt.% and 25wt.% and coagulation bath temperature (CBT= 25°C, 50°C and 75°C on morphology, thermal stability and pure water flux (PWF of the prepared membranes were studied and discussed. Increasing TiO2 concentration in the casting solution film along with higher CBT resulted in increasing the membrane thickness, water content (WC, membrane porosity and pure water flux (PWF, also these changes facilitate macrovoids formation. Thermal gravimetric analysis (TGA shows that thermal stability of the composite membranes were improved by the addition of TiO2 nanopaticles. Also TGA results indicated that increasing CBT in each TiO2 concentration leads to the decreasing of decomposition temperature (Td of hybrid membranes.

A new method to determine oxidative stability of vegetable fats and oils at simulated frying temperature

Directory of Open Access Journals (Sweden)

Gertz Christian

2001-01-01

Full Text Available A new procedure at simulated frying conditions in our laboratory was developed to monitor frying stability of fats and oils. Water-conditioned silica was prepared and added to the fresh vegetable oil, which was heated for two hours at 170°C. The oil stability at frying temperature was then evaluated by determining the amount of formed dimeric triglycerides The results obtained showed that the stability of the vegetable oils at frying temperature could not be explained by the fatty acid composition alone. Corn oil was observed to be more stable than soybean oil, and rapeseed oil was better than olive oil. It was also observed that crude, non-refined oils were found to have a better heat stability than refin-ed oils. To estimate the effectiveness of synthetic and naturally occurring antioxidants, namely various tocopherols, tocopherol acetate and phytosterol fractions, phenolic compounds like quercetin, oryzanol, ferulic acid, gallates, BHT, BHA and other compounds like ascorbic acid 6-palmitate and squalene were added to refined sunflower and rape seed oil, and their oxidative stability at elevated temperature (OSET values determined. Both linoleic and oleic rich oils gave comparable results for the activity of the various compounds. alpha-tocopherol, tocopherol esters and BHA had low effects on oil stability at frying temperature, while ascorbyl palmitate and some phytosterol fractions were found to have the most stabilizing activity under frying conditions.

Temperature effect on water absorption in an improved periwinkle ...

African Journals Online (AJOL)

Studies have been carried out on the water absorption of the improved periwinkle reinforced cement stabilized lateritic bricks. These bricks were produced at different cement to laterite to periwinkle ratio of 1:3:1, 2:3:1, 3:3:1, 3:2:1, 3:1:1, and fired at an elevated temperature of 10000C and 11500C, respectively. From the ...

Response of water temperatures and stratification to changing climate in three lakes with different morphometry

Science.gov (United States)

Magee, Madeline R.; Wu, Chin H.

2017-12-01

Water temperatures and stratification are important drivers for ecological and water quality processes within lake systems, and changes in these with increases in air temperature and changes to wind speeds may have significant ecological consequences. To properly manage these systems under changing climate, it is important to understand the effects of increasing air temperatures and wind speed changes in lakes of different depths and surface areas. In this study, we simulate three lakes that vary in depth and surface area to elucidate the effects of the observed increasing air temperatures and decreasing wind speeds on lake thermal variables (water temperature, stratification dates, strength of stratification, and surface heat fluxes) over a century (1911-2014). For all three lakes, simulations showed that epilimnetic temperatures increased, hypolimnetic temperatures decreased, the length of the stratified season increased due to earlier stratification onset and later fall overturn, stability increased, and longwave and sensible heat fluxes at the surface increased. Overall, lake depth influences the presence of stratification, Schmidt stability, and differences in surface heat flux, while lake surface area influences differences in hypolimnion temperature, hypolimnetic heating, variability of Schmidt stability, and stratification onset and fall overturn dates. Larger surface area lakes have greater wind mixing due to increased surface momentum. Climate perturbations indicate that our larger study lakes have more variability in temperature and stratification variables than the smaller lakes, and this variability increases with larger wind speeds. For all study lakes, Pearson correlations and climate perturbation scenarios indicate that wind speed has a large effect on temperature and stratification variables, sometimes greater than changes in air temperature, and wind can act to either amplify or mitigate the effect of warmer air temperatures on lake thermal

Analysis of the structural stability of the smectite submitted to high pressures and temperatures

International Nuclear Information System (INIS)

Alabarse, Frederico Gil

2009-10-01

The thermal stability of bentonite is of particular interest for containment barrier in nuclear waste disposal facilities. However, very little is known about the stability of smectite (principal component of bentonite) under high-pressure and high-temperature conditions (HPHT). The objective of this work was to investigate the stability of the smectite structure under HP-HT conditions. The HP-HT experiments were performed on toroidal chambers (TC) with pressure up 7.7 GPa and temperatures of 1000 deg C. The samples were characterized by X-ray diffraction after the HP-HT processing. Furthermore, one sample from the original material was analyzed using Fourier transformed infra-red (FTIR) in situ measurements on a diamond anvil cell (DAC) in experiments up to 12 GPa. The original sample of bentonite, calcium dioctahedral montmorillonite with small fraction of quartz, was characterized by FTIR, XRD, X-ray fluorescence (XRF), scanning electron microscopy (SEM), surface area, thermogravimetric analysis (TGA) and differential thermal analysis (DTA). In the experiment performed using the DAC up to 12 GPa, the FTIR in situ measurements analysis showed that the smectite structure is stable with a reversible deformation in the Si-O bond and that the smectite did not loose water. Experiments performed in TC at 7.7 GPa of pressure and 250 deg C of temperature, during 3.5 h showed, after analysis by XRD and FTIR, that the smectite structure is stable and did not loose water. Experiments performed in TC at 7.7 GPa of pressure and 1000 deg C of temperature, during 3.5 h showed, after analysis by XRD and SEM, the transformation of bentonite to the mineral assemblage: Coesite, Quartz, Kyanite and Pyrope. (author)

Stabilization of heavy oil-water emulsions using a bio/chemical emulsifier mixture

Energy Technology Data Exchange (ETDEWEB)

Farahbakhsh, A.; Taghizadeh, M.; Movagharnejad, K. [Chemical Engineering Department, Babol University of Technology, Babol (Iran, Islamic Republic of); Yakhchali, B. [National Institute of Genetic Engineering and Biotechnology, Tehran (Iran, Islamic Republic of)

2011-11-15

In this study, the viscosity reduction of heavy oil has been investigated through the formation of oil-water emulsion using a bio/chemical emulsifier mixture. Four bioemulsifiers from indigenous Rhodococcus ergthropolis and Bacillus licheniformis strains were used to stabilize a highly-viscous oil-in-water emulsion. The Taguchi method with an L{sub 9} orthogonal array design was used to investigate the effect of various control factors on the formation of the oil/water emulsions. An emulsion with lowest viscosity was formed using ACO4 strain. The substantial stability of the oil-in-water emulsion allows the heavy oil to be transported practically over long distances or remain stationary for a considerable period of time prior to utilization. As the result of Taguchi analysis, the temperature and concentration of the emulsifier had a significant influence on viscosity reduction of the emulsion. (Copyright copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

Chemical stability of high-temperature superconductors

Science.gov (United States)

Bansal, Narottam P.

1992-01-01

A review of the available studies on the chemical stability of the high temperature superconductors (HTS) in various environments was made. The La(1.8)Ba(0.2)CuO4 HTS is unstable in the presence of H2O, CO2, and CO. The YBa2Cu3O(7-x) superconductor is highly susceptible to degradation in different environments, especially water. The La(2-x)Ba(x)CuO4 and Bi-Sr-Ca-Cu-O HTS are relatively less reactive than the YBa2Cu3O(7-x). Processing of YBa2Cu3O(7-x) HTS in purified oxygen, rather than in air, using high purity noncarbon containing starting materials is recommended. Exposure of this HTS to the ambient atmosphere should also be avoided at all stages during processing and storage. Devices and components made out of these oxide superconductors would have to be protected with an impermeable coating of a polymer, glass, or metal to avoid deterioration during use.

Nanostructural studies on monoelaidin-water systems at low temperatures.

Science.gov (United States)

Kulkarni, Chandrashekhar V

2011-10-04

In recent years, lipid based nanostructures have increasingly been used as model membranes to study various complex biological processes. For better understanding of such phenomena, it is essential to gain as much information as possible for model lipid structures under physiological conditions. In this paper, we focus on one of such lipids--monoelaidin (ME)--for its polymorphic nanostructures under varying conditions of temperature and water content. In the recent contribution (Soft Matter, 2010, 6, 3191), we have reported the phase diagram of ME above 30 °C and compared with the phase behavior of other lipids including monoolein (MO), monovaccenin (MV), and monolinolein (ML). Remarkable phase behavior of ME, stabilizing three bicontinuous cubic phases, motivates its study at low temperatures. Current studies concentrate on the low-temperature (ME and subsequent reconstruction of its phase diagram over the entire temperature-water composition space (temperature, 0-76 °C; and water content, 0-70%). The polymorphs found for the monoelaidin-water system include three bicontinuous cubic phases, i.e., Ia3d, Pn3m, and Im3m, and lamellar phases which exhibit two crystalline (L(c1) and L(c0)), two gel (L(β) and L(β*)), and a fluid lamellar (L(α)) states. The fluid isotropic phase (L(2)) was observed only for lower hydrations (<20%), whereas hexagonal phase (H(2)) was not found under studied conditions. Nanostructural parameters of these phases as a function of temperature and water content are presented together with some molecular level calculations. This study might be crucial for perception of the lyotropic phase behavior as well as for designing nanostructural assemblies for potential applications. © 2011 American Chemical Society

Dynamics of a BWR with inclusion of boiling nonlinearity, clad temperature and void-dependent core power removal: Stability and bifurcation characteristics of advanced heavy water reactor (AHWR)

Energy Technology Data Exchange (ETDEWEB)

Verma, Dinkar, E-mail: dinkar@iitk.ac.in [Nuclear Engineering and Technology Program, Indian Institute of Technology Kanpur, Kanpur 208 016 (India); Kalra, Manjeet Singh, E-mail: drmanjeet.singh@dituniversity.edu.in [DIT University, Dehradun 248 009 (India); Wahi, Pankaj, E-mail: wahi@iitk.ac.in [Department of Mechanical Engineering, Indian Institute of Technology Kanpur, Kanpur 208 016 (India)

2016-11-15

Highlights: • Simplified models with inclusion of the clad temperature are considered. • Boiling nonlinearity and core power removal have been modeled. • Method of multiple time scales has been used for nonlinear analysis to get the nature and amplitude of oscillations. • Incorporation of modeling complexities enhances the stability of system. • We find that reactors with higher nominal power are more desirable from the point of view of global stability. - Abstract: We study the effect of including boiling nonlinearity, clad temperature and void-dependent power removal from the primary loop in the mathematical modeling of a boiling water reactor (BWR) on its dynamic characteristics. The advanced heavy water reactor (AHWR) is taken as a case study. Towards this end, we have analyzed two different simplified models with different handling of the clad temperature. Each of these models has the necessary modifications pertaining to boiling nonlinearity and power removal from the primary loop. These simplified models incorporate the neutronics and thermal–hydraulic coupling. The effect of successive changes in the modeling assumptions on the linear stability of the reactor has been studied and we find that incorporation of each of these complexities in the model increases the stable operating region of the reactor. Further, the method of multiple time scales (MMTS) is exploited to carry out the nonlinear analysis with a view to predict the bifurcation characteristics of the reactor. Both subcritical and supercritical Hopf bifurcations are present in each model depending on the choice of operating parameters. These analytical observations from MMTS have been verified against numerical simulations. A parametric study on the effect of changing the nominal reactor power on the regions in the parametric space of void coefficient of reactivity and fuel temperature coefficient of reactivity with sub- and super-critical Hopf bifurcations has been performed for all

Evaluation test on stability of high temperature strain gage

Energy Technology Data Exchange (ETDEWEB)

Sato, Toshimi (Kyowa Electronic Instruments Co. Ltd., Tokyo (Japan)); Ito, Haruhiko; Tanaka, Isao; Komori, Yoshihiro

1983-08-01

This report deals with the results on a stability test of high temperature strain gage which is utilized for development of the Stethoscope for OGL - 1 Components in Elevated Temperature Services (ab. SOCETS). The test has proved that the weldable strain gage (KHC - 20 - G5) exhibits excellent stability at 500/sup 0/C during 3000 to 4000 hours service and can be applied sufficiently to evaluate integrity of OGL - 1 high temperature pipings and others.

Evaluation test on stability of high temperature strain gage

International Nuclear Information System (INIS)

Sato, Toshimi; Ito, Haruhiko; Tanaka, Isao; Komori, Yoshihiro.

1983-01-01

This report deals with the results on a stability test of high temperature strain gage which is utilized for development of the Stethoscope for OGL - 1 Components in Elevated Temperature Services (ab. SOCETS). The test has proved that the weldable strain gage (KHC - 20 - G5) exhibits excellent stability at 500 0 C during 3000 to 4000 hours service and can be applied sufficiently to evaluate integrity of OGL - 1 high temperature pipings and others. (author)

Collisional stabilization efficiencies that control condensation flux rates in supersaturated vapors of n-alcohols and water

International Nuclear Information System (INIS)

Bauer, S.H.; Wilcox, C.F. Jr.

1994-01-01

Using J(S;T) values, magnitudes for a temperature-dependent stabilization factor, the size-dependent activation energy for evaporation from stabilized clusters, and the size-dependent heats of evaporation are derived. This kinetic derivation is carried out using data from supersaturated water and six n-alcohols obtained with the double-piston expansion technique. 30 refs., 5 figs., 1 tab

FEBEX bentonite colloid stability in ground water

Energy Technology Data Exchange (ETDEWEB)

Seher, H.; Schaefer, T.; Geckeis, H. [Inst. fuer Nukleare Entsorgung (INE), Forschungszentrum Karlsruhe, 76021 Karlsruhe (Germany)]. e-mail: holger.seher@ine.fzk .de; Fanghaenel, T. [Ruprecht-Karls-Univ. Heidelberg, Physikalisch-Chemisches In st., D-69120 Heidelberg (Germany)

2007-06-15

Coagulation experiments are accomplished to identify the geochemical conditions for the stability of Febex bentonite colloids in granite ground water. The experiments are carried out by varying pH, ionic strength and type of electrolyte. The dynamic light scattering technique (photon correlation spectroscopy) is used to measure the size evolution of the colloids with time. Agglomeration rates are higher in MgCl{sub 2} and CaCl{sub 2} than in NaCl solution. Relative agglomeration rates follow approximately the Schulze-Hardy rule. Increasing agglomeration rates at pH>8 are observed in experiments with MgCl{sub 2} and CaCl{sub 2} which are, however, caused by coprecipitation phenomena. Bentonite colloid stability fields derived from the colloid agglomeration experiments predict low colloid stabilization in granite ground water taken from Aespoe, Sweden, and relatively high colloid stability in Grimsel ground water (Switzerland)

Cluster temperature. Methods for its measurement and stabilization

International Nuclear Information System (INIS)

Makarov, G N

2008-01-01

Cluster temperature is an important material parameter essential to many physical and chemical processes involving clusters and cluster beams. Because of the diverse methods by which clusters can be produced, excited, and stabilized, and also because of the widely ranging values of atomic and molecular binding energies (approximately from 10 -5 to 10 eV) and numerous energy relaxation channels in clusters, cluster temperature (internal energy) ranges from 10 -3 to about 10 8 K. This paper reviews research on cluster temperature and describes methods for its measurement and stabilization. The role of cluster temperature in and its influence on physical and chemical processes is discussed. Results on the temperature dependence of cluster properties are presented. The way in which cluster temperature relates to cluster structure and to atomic and molecular interaction potentials in clusters is addressed. Methods for strong excitation of clusters and channels for their energy relaxation are discussed. Some applications of clusters and cluster beams are considered. (reviews of topical problems)

Temperature, heat content, mixing and stability in Lake Orta: a pluriannual investigation

Directory of Open Access Journals (Sweden)

Luigi BARBANTI

2001-02-01

Full Text Available This paper describes the overall state of some physical phenomena occurring in Lake Orta, such as thermal stratification and destratification, accumulation and release of heat, vertical winter mixing, and stability of the water mass. The historical series of temperature distribution along the water column in the period 1984-1999, from which the holo-oligomictic character of Lake Orta emerges, is analysed. The monthly evaluation of the heat contents metre by metre from 0 to 143 m depth reveals how the complete winter mixing occurs only when the energy present within the whole column is less than 1,675 MJ m-2; above this value the circulation is only partial, as in the other deep subalpine lakes. A water layer in the deep hypolimnion has been shown to contain a climatic memory, which has generally increased since 1981. Walker’s stability analysis has revealed that when at a depth below 90 metres there is a level where 0.07 J m-2 are exceeded, total mixing cannot take place. In contrast, the Birgean work identifies, during the heating phase, the layers of the lake where energy is stored or lost.

BWR stability: analysis of cladding temperature for high amplitude oscillations - 146

International Nuclear Information System (INIS)

Pohl, P.; Wehle, F.

2010-01-01

Power oscillations associated with density waves in boiling water reactors (BWRs) have been studied widely. Industrial research in this area is active since the invention of the first BWR. Stability measurements have been performed in various plants during commissioning phase but especially the magnitude and divergent nature of the oscillations during the LaSalle Unit 2 nuclear power plant event on March 9, 1988, renewed concern about the state of knowledge on BWR instabilities and possible consequences to fuel rod integrity. The objective of this paper is to present a simplified stability tool, applicable for stability analysis in the non-linear regime, which extends to high amplitude oscillations where inlet reverse flow occurs. In case of high amplitude oscillations a cyclical dryout and rewetting process at the fuel rod may take place, which leads in turn to rapid changes of the heat transfer from the fuel rod to the coolant. The application of this stability tool allows for a conservative determination of the fuel rod cladding temperature in case of high amplitude oscillations during the dryout / re-wet phase. Moreover, it reveals in good agreement to experimental findings the stabilizing effect of the reverse bundle inlet flow, which might be obtained for large oscillation amplitudes. (authors)

The stability of the water column in french ponds (limousin region by the calculation of the wedderburn number

Directory of Open Access Journals (Sweden)

TOUCHART L.

2014-03-01

Full Text Available Oxygenation and biological life in lakes, reservoirs and ponds depend on the stability of the water column and on the rhythms of stratification and mixing periods. Slight thermal stratification in ponds often is regarded as the same as instability in shallow lakes. Nevertheless fetch in ponds is very short, what reduces the mixing. Wedderburn number (quotient of the buoyancy by the mixing is used to quantify the stability in shallow water bodies. We calculate it for some ponds in French region Limousin, due to original hourly water temperature measurements in all depths and wind data of Météofrance stations. First results show that very high values (above 10 are frequent in summer and spring period (during 41% of the total time of 2 336 hours from May to July in three ponds. That is why we may consider Limousin ponds as stable stratified bodies of water despite their shallowness. Continuous measurements allow to calculate the diurnal cycle and other time scales of the Wedderburn number, with periods of weakening, when air temperatures and surface water temperatures decrease, wind speed increases and when the wind blows in the same direction with the length of the pond. The most complex variable is the depth of the thermocline; a light increase of the breeze thickens the upper warm layer and strengthens the stability, but an important increase of the wind tends to destroy the stratification.

The dynamics of Orimulsion in water with varying salinity and temperature

International Nuclear Information System (INIS)

Fingas, M.F.; Wang, Z.; Landriault, M.; Noonan, J.

2002-01-01

A study was conducted to determine the complex interaction between salinity, time and temperature when Orimulsion is spilled in a water column. Orimulsion is a surfactant-stabilized oil-in-water emulsion composed of 70 per cent bitumen and 30 per cent water. It behaves very differently from conventional fuel oils when spilled because of its composition. It behaves predictably in both salt and fresh water, but its behaviour is difficult to predict in brackish water (2 per cent salt). Temperature also has an influence on the behaviour of Orimulsion. This study focused on examining the behaviour of Orimulsion at various low temperatures (5 to 15 degrees C), and a wide range of salinity values from fresh to salt water (values ranging from 0.1 to 33 per cent). A total of 19 experiments were conducted. The objective was to determine depletion rates and characteristics of Orimulsion when it was added to a 300 L tank of water and by determining the concentration of bitumen and the particle size distribution over time. The bitumen which rose to the top of the tank was collected and weighed. Simple equations were then developed to explain and predict the concentration of bitumen in the water column as a function of time. Nomograms indicating the quantity of oil on the bottom and on the water surface were also presented. 6 refs., 4 tabs., 10 figs

Stability of water on Mars.

Science.gov (United States)

Sears, D. W. G.; Moore, S. R.

2004-11-01

In order to try to quantify some of the factors determining the evaporation rate of water on Mars, we have been measuring evaporation rates under simulated martian conditions in a large planetary environmental chamber. All of our experiments have been performed at 5.25 Torr (7 mb) total pressure, but we have varied the temperature of the water surface, atmosphere and walls of the chamber (the walls we assume to be somewhat analogous to surrounding surfaces on Mars). We have also monitored the partial pressure of water vapor in the atmosphere to investigate its effect on evaporation rate. Most importantly, we have attempted to model the effect of advection - physical removal of the water vapor by wind or other forms of atmospheric motion - by (1) placing a bag of dry ice in the chamber and (2) by installing a copper cold finger with circulating methanol/dry ice slurry next to the sample and pumping as necessary to maintain 5.25 Torr. As might be expected, the situation is complicated and not readily described theoretically, but several conclusions seem to be emerging. Evaporation rates under nonadvective conditions are 1.2 mm/h and decrease only by about 30% as water vapor builds up in the atmosphere to as much as 40 vol %. Wall temperature and water surface temperature do not appear to affect evaporation rates significantly, but a 20 C increase in atmospheric temperature causes a 40% increase in evaporation rate. The evaporation rate increases by a factor of two in the presence of advection and under advective conditions is not affected significantly by changes in water, air, or wall temperature, or water vapor pressure. These results suggest that atmospheric motion may be the dominant factor in determining water evaporation on Mars.

Protein stability and enzyme activity at extreme biological temperatures

International Nuclear Information System (INIS)

Feller, Georges

2010-01-01

Psychrophilic microorganisms thrive in permanently cold environments, even at subzero temperatures. To maintain metabolic rates compatible with sustained life, they have improved the dynamics of their protein structures, thereby enabling appropriate molecular motions required for biological activity at low temperatures. As a consequence of this structural flexibility, psychrophilic proteins are unstable and heat-labile. In the upper range of biological temperatures, thermophiles and hyperthermophiles grow at temperatures > 100 0 C and synthesize ultra-stable proteins. However, thermophilic enzymes are nearly inactive at room temperature as a result of their compactness and rigidity. At the molecular level, both types of extremophilic proteins have adapted the same structural factors, but in opposite directions, to address either activity at low temperatures or stability in hot environments. A model based on folding funnels is proposed accounting for the stability-activity relationships in extremophilic proteins. (topical review)

The stability of water- and fat-soluble vitamin in dentifrices according to pH level and storage type.

Science.gov (United States)

Park, Jung-Eun; Kim, Ki-Eun; Choi, Yong-Jun; Park, Yong-Duk; Kwon, Ha-Jeong

2016-02-01

The purpose of this study is to evaluate the vitamin stabilities in dentifrices by analyzing various vitamins according to the level and storage temperature. The stabilities of water- and fat-soluble vitamins were investigated in buffer solution at different pH values (4, 7, 8, 10 and 11) for 14 days and in dentifrices at different pH (7 and 10) for 5 months at two temperature conditions (room and refrigeration temperature) by analyzing the remaining amounts using HPLC methods. In the buffer solution, the stability of vitamins B1 , B6 and C was increased as the pH values increased. Vitamins E and K showed poor stability at pH 4, and vitamin B3 showed poor stability at pH 11. In dentifrices, the storage temperature highly influenced vitamin stability, especially vitamins C and E, but the stabilities of vitamins B1 and C according to pH values did not correspond to the buffer solution tests. Vitamin B group was relatively stable in dentifrices, but vitamin C completely disappeared after 5 months. Vitamin K showed the least initial preservation rates. Vitamins were not detected in commercial dentifrices for adults and detected amounts were less than the advertised contents in dentifrices for children. Copyright © 2015 John Wiley & Sons, Ltd.

Effect of triethanolamine on the stability of furfurol at elevated temperatures

Energy Technology Data Exchange (ETDEWEB)

Baiburskaya, E.L.; Kalenik, G.S.; Levchenko, E.S.; Martynenko, A.G.; Okhrimenko, N.V.; Shiryaeva, G.P.

1982-01-01

The effect of triethanolamine (I) on the stability of furfurol under the conditions of oil purification was studied. It was shown that (I) shows a stabilizing effect at a temperature of 200/sup 0/, which is considerably weakened on heating the furfurol in the presence of air (at atmospheric pressure). At a temperature of 230/sup 0/ (I) is not a stabilizer for furfurol.

Long-time aging in 3 mol.% yttria-stabilized tetragonal zirconia polycrystals at human body temperature.

Science.gov (United States)

Keuper, Melanie; Berthold, Christoph; Nickel, Klaus Georg

2014-02-01

We present new findings on the low-temperature degradation of yttria-stabilized zirconia at 37°C over several years and at high and low partial pressures of water. With the aid of focused ion beam cross-section confirmation studies we are able to show an extensive linear, continuous degradation without retardation, even at low temperatures and low water pressures. The characteristic layer growth and its inferred rate constant imply a lifetime of tens of years under simple tension and open the possibility of studying the longevity of these ceramics more rigorously. In addition, we show reproducibility complications of accelerated aging tests by the use of different autoclaves and possible implications for standardized procedures. Copyright © 2013 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

Micro-scale heterogeneity in water temperature | Dallas | Water SA

African Journals Online (AJOL)

Micro-scale heterogeneity in water temperature was examined in 6 upland sites in the Western Cape, South Africa. Hourly water temperature data converted to daily data showed that greatest differences were apparent in daily maximum temperatures between shallow- and deep-water biotopes during the warmest period of ...

Moessbauer study of small amounts of iron in graphite, around the diamond-graphite pressure-temperature stability region

International Nuclear Information System (INIS)

Oliveira, C.L.S. de; Silva, M.T.X.; Vasquez, A.; Jornada, J.A.H. da

1991-01-01

An exploratory Moessbauer spectroscopy study of the Fe-C system in the C rich region, prepared by high pressure-high temperature treatment near the graphite-diamond stability line, was made. The results obtained for the different processing conditions give no evidence of Fe intercalation in graphite. The presence of some water in the cell produced hydrated Fe complexes, which can explain the deleterious effect of water or hydrogen in the high pressure diamond synthesis. (orig.)

Clay facial masks: physicochemical stability at different storage temperatures.

Science.gov (United States)

Zague, Vivian; de Almeida Silva, Diego; Baby, André Rolim; Kaneko, Telma Mary; Velasco, Maria Valéria Robles

2007-01-01

Clay facial masks--formulations that contain a high percentage of solids dispersed in a liquid vehicle--have become of special interest due to specific properties presented by clays, such as particle size, cooling index, high adsorption capacity, and plasticity. Although most of the physicochemical properties of clay dispersions have been studied, specific aspects concerning the physicochemical stability of clay mask products remain unclear. This work aimed at investigating the accelerated physicochemical stability of clay mask formulations stored at different temperatures. Formulations were subjected to centrifuge testing and to thermal treatment for 15 days, during which temperature was varied from -5.0 degrees to 45.0 degrees C. The apparent viscosity and visual aspect (homogeneity) of all formulations were affected by temperature variation, whereas color, odor, and pH value remained unaltered. These results, besides the estimation of physicochemical stability under aging, can be useful in determining the best storage conditions for clay-based formulations.

Temperature Stabilized Characterization of High Voltage Power Supplies

CERN Document Server

Krarup, Ole

2017-01-01

High precision measurements of the masses of nuclear ions in the ISOLTRAP experiment relies on an MR-ToF. A major source of noise and drift is the instability of the high voltage power supplies employed. Electrical noise and temperature changes can broaden peaks in time-of-flight spectra and shift the position of peaks between runs. In this report we investigate how the noise and drift of high-voltage power supplies can be characterized. Results indicate that analog power supplies generally have better relative stability than digitally controlled ones, and that the high temperature coefficients of all power supplies merit efforts to stabilize them.

Radiolytic stability of gibbsite and boehmite with adsorbed water

Energy Technology Data Exchange (ETDEWEB)

Huestis, Patricia; Pearce, Carolyn I.; Zhang, X.; N' Diaye, Alpha T.; Rosso, Kevin M.; LaVerne, Jay A.

2018-04-01

Aluminum oxyhydroxide (boehmite, AlOOH) and aluminum hydroxide (gibbsite, Al(OH)3) powders with adsorbed water were irradiated with -rays and 5 MeV He ions (α-particles) in order to determine overall radiation stability and chemical modification to the surface. No variation in overall phase or crystallinity due to radiolysis was observed with X-ray diffraction (XRD) and Raman spectroscopy for doses up to 2 MGy with -rays and 175 MGy with α-particles. Temperature programed desorption (TPD) of the water from the surface to the gas phase indicated that the water was chemisorbed and strongly bound. Water adsorption sites are of similar energy for both gibbsite and boehmite. Observation of the water adsorbed on the surface of gibbsite and boehmite with diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) showed broad peaks at 3100-3600 cm-1 due to OH stretching that slowly decreased on heating to 500oC, which corresponds well with the water vapor evolution observed with TPD. Both materials were found to be amorphous following heating to 500oC. X-ray photoelectron spectroscopy (XPS) indicated surface reduction of Al(III) to Al metal on radiolysis with α-particles. Complete loss of chemisorbed water and the formation of bulk O atoms was observed following radiolysis with α-particles.

Low-temperature technique for thick film resist stabilization and curing

Science.gov (United States)

Minter, Jason P.; Wong, Selmer S.; Marlowe, Trey; Ross, Matthew F.; Narcy, Mark E.; Livesay, William R.

1999-06-01

For a range of thick film photoresist applications, including MeV ion implant processing, thin film head manufacturing, and microelectromechanical systems processing, there is a need for a low-temperature method for resist stabilization and curing. Traditional methods of stabilizing or curing resist films have relied on thermal cycling, which may not be desirable due to device temperature limitations or thermally-induced distortion of the resist features.

Stability of the Hartree-Fock model with temperature

OpenAIRE

Dolbeault, Jean; Felmer, Patricio; Lewin, Mathieu

2008-01-01

This paper is devoted to the Hartree-Fock model with temperature in the euclidean space. For large classes of free energy functionals, minimizers are obtained as long as the total charge of the system does not exceed a threshold which depends on the temperature. The usual Hartree-Fock model is recovered in the zero temperature limit. An orbital stability result for the Cauchy problem is deduced from the variational approach.

Temperature stabilization near Tsub(lambda) in liquid helium

International Nuclear Information System (INIS)

Francois, M.; Lhuillier, D.

1975-01-01

The study of He I and II equilibrium properties near the lambda transition requires a very performant temperature stabilisation. A system using second or fourth sound and which offers a stability better than 10 -8 0 K/hour in the temperature range 1.8 0 K-2.2 0 K is presented. (Auth.)

Room temperature synthesis of PbSe quantum dots in aqueous solution: Stabilization by interactions with ligands

Science.gov (United States)

Primera-Pedrozo, Oliva M.; Arslan, Zikri; Rasulev, Bakhtiyor; Leszczynski, Jerzy

2011-01-01

An aqueous route of synthesis is described for rapid synthesis of lead selenide quantum dots (PbSe QDs) at room temperature in an attempt to produce water-soluble and stable nanocrystals. Several thiol-ligands, including thioglycolic acid (TGA), thioglycerol (TGC), 3-mercaptopropionic acid (MPA), 2-mercaptoethyleamine hydrochloride (MEA), 6-mercaptohexanoic acid (MHA), and L-cysteine (L-cys), were used for capping/stabilization of PbSe QDs. The effects of the ligands on the stability of PbSe QDs were evaluated for a period of two months at room temperature under normal light conditions and at 4 °C in dark. The TGA- and MEA-capped QDs exhibited the highest stability prior to purification, almost two months when kept in dark at 4 °C. However, the stability of TGA-capped QDs was reduced substantially after purification to about 5 days under same conditions, while MEA-capped QDs did not show any significant instability. The stabilization energies of Pb-thiolate complexes determined by theoretical DFT simulations supported the experimental results. The PbSe QDs capped with TGA, MPA and MEA were successfully purified and re-dispersed in water, while those stabilized with TGC, MHA and L-cys aggregated during purification attempts. The purified PbSe QDs possess very susceptible surface resulting in poor stability for about 30 – 45 min after re-dispersion in water. In the presence of an excess of free ligand, the stability increased up to 5 days for TGA-capped QDs at pH 7.19, 9 –12 days for MPA-capped QDs at pH 7.3–7.5 and 45–47 days for MEA-capped QDs at pH 7.35. X-Ray Diffraction (XRD) results showed that the QDs possess a cubic rock salt structure with the most intense peaks located at 2θ = 25.3° (200) and 2θ = 29.2° (100). TEM images showed that the size of the QDs ranges between 5 and 10 nm. ICP-MS results revealed that Pb:Se ratio was 1.26, 1.28, 3.85, 1.18, and 1.31 for the QDs capped with TGA, MPA, MEA, L-Cys, and TGC, respectively. The proposed method

Low temperature stabilization process for production of carbon fiber having structural order

Science.gov (United States)

Rios, Orlando; McGuire, Michael Alan; More, Karren Leslie; Tenhaeff, Wyatt Evan; Menchhofer, Paul A.; Paulauskas, Felix Leonard

2017-08-15

A method for producing a carbon fiber, the method comprising: (i) subjecting a continuous carbon fiber precursor having a polymeric matrix in which strength-enhancing particles are incorporated to a stabilization process during which the carbon fiber precursor is heated to within a temperature range ranging from the glass transition temperature to no less than 20.degree. C. below the glass transition temperature of the polymeric matrix, wherein the maximum temperature employed in the stabilization process is below 400.degree. C., for a processing time within said temperature range of at least 1 hour in the presence of oxygen and in the presence of a magnetic field of at least 1 Tesla, while said carbon fiber precursor is held under an applied axial tension; and (ii) subjecting the stabilized carbon fiber precursor, following step (i), to a carbonization process. The stabilized carbon fiber precursor, resulting carbon fiber, and articles made thereof are also described.

Thermodynamic modelling of clay dehydration, stability and compositional evolution with temperature, pressure and H2O activity

International Nuclear Information System (INIS)

Vidal, O.; Dubacq, B.

2010-01-01

Document available in extended abstract form only. Full text of publication follows: The evaluation of the performance of clay-rich barrier considered for the disposal of radioactive waste and a reliable prediction of the impact of repository-induced disturbances upon the confinement properties of clay-rich geological formations requires reliable thermodynamic models for clay minerals. Such models have to take into account the variation of the hydration state of smectite as a function of temperature, pressure and water activity. We propose the first macroscopic thermodynamic model that account for the stepwise dehydration with increasing temperature or decreasing H 2 O activity of K, Na, Ca and Mg-smectite. The model relies on the relative stability of the different solid-solutions that describe the hydration of di- or tri-octahedral-smectites containing 0, 1, 2 or 3 interlayer water layers. The inclusion of anhydrous mica end-members makes it possible to cover, with the same solid-solution model, the entire range of composition from low-charge to high-charge smectite, through illite to mica. Non-ideal Margules parameters were used to describe the non-ideality of the solid solutions between the hydrated and dehydrated smectite end-members. Standard state properties of all smectite end-members as well as Ca- and Mg-muscovite and -phlogopite were initially estimated by oxide summation. These values were then refined and the other non-ideal interactions were estimated on the basis of different experimental data. The stepwise dehydration of smectite, and its stability and compatibility relations were calculated by Gibbs free energy minimizing. Our results account for the progressive evolution of smectite to inter-layered illite/smectite and then to mica, as observed in nature and experiments, and our model provides an explanation for the thermodynamic stability of smectite and illite/ smectite compared to mica + kaolinite or pyrophyllite assemblages. The results

Temperature distributions in trapezoidal built in storage solar water heaters with/without phase change materials

International Nuclear Information System (INIS)

Tarhan, Sefa; Sari, Ahmet; Yardim, M. Hakan

2006-01-01

Built in storage solar water heaters (BSSWHs) have been recognized for their more compact constructions and faster solar gain than conventional solar water heaters, however, their water temperatures quickly go down during the cooling period. A trapezoidal BSSWH without PCM storage unit was used as the control heater (reference) to investigate the effect of two differently configured PCM storage units on the temperature distributions in water tanks. In the first design, myristic acid was filled into the PCM storage tank, which also served as an absorbing plate. In the second design, lauric acid was filled into the PCM storage tank, which also served as a baffle plate. The water temperature changes were followed by five thermocouples placed evenly and longitudinally into each of the three BSSWHs. The effects of the PCMs on the water temperature distributions depended on the configuration of the PCM storage unit and the longitudinal position in the water tanks. The use of lauric acid lowered the values of the peak temperatures by 15% compared to the control heater at the upper portion of the water tanks because of the low melting temperature of lauric acid, but it did not have any consistent effect on the retention of the water temperatures during the cooling period. The ability of the myristic acid storage unit to retain the water temperatures got more remarkable, especially at the middle portion of the water tank. The myristic acid storage increased the dip temperatures by approximately 8.8% compared to the control heater. In conclusion, lauric acid storage can be used to stabilize the water temperature during the day time, while the myristic acid storage unit can be used as a thermal barrier against heat loss during the night time because of its relatively high melting temperature and low heat conduction coefficient in its solid phase. The experimental results have also indicated that the thermal characteristics of the PCM and the configuration of the PCM storage

Water-stabilized plasma generators

Czech Academy of Sciences Publication Activity Database

Hrabovský, Milan

1998-01-01

Roč. 70, č. 6 (1998), s. 1157-1162 ISSN 0033-4545 R&D Projects: GA ČR GA102/95/0592; GA ČR GV106/96/K245 Institutional research plan: CEZ:AV0Z2043910 Keywords : thermal plasma, plasma torch, water-stabilized plasma Subject RIV: BL - Plasma and Gas Discharge Physics Impact factor: 1.677, year: 1998

The dynamics of Orimulsion in water with varying energy, salinity and temperature

International Nuclear Information System (INIS)

Fingas, M.F.; Fieldhouse, B.; Wang, Z.; Environment Canada, Ottawa, ON

2004-01-01

Orimulsion is a surfactant-stabilized oil-in-water emulsion composed of 70 per cent bitumen and 30 per cent water. Its unique composition causes it to behave differently from conventional fuel oils when spilled at sea. Earlier studies have shown that Orimulsion is driven by buoyancy to rise in salt water and sink in fresh water. This study conducted 11 experiments at lower temperature and salinity values to obtain new information on the behaviour of Orimulsion in salt, fresh and brackish water. The applied rotational field was adjusted to vary the energy. A time-series of samples of Orimulsion in a 300 litre tank of water were taken to determine depletion rates and characteristics. Oil on the surface was quantified and the concentration of bitumen and particle size distribution was determined. The study also measured changes in bitumen concentration and particle size distribution as a function of time. The data was used to develop simple equations that predict concentrations of bitumen resurfacing and remaining in the water column as a function of time. It was concluded that there is a complex interaction between salinity, time, energy and temperature. 9 refs., 5 tabs., 8 figs

A stability identification system for boiling water nuclear reactors

International Nuclear Information System (INIS)

Belblidia, L.A.; Chevrier, A.

1994-01-01

Boiling water reactors are subject to instabilities under low-flow, high-power operating conditions. These instabilities are a safety concern and it is therefore important to determine stability margins. This paper describes a method to estimate a measure of stability margin, called the decay ratio, from autoregressive modelling of time series data. A phenomenological model of a boiling water reactor with known stability characteristics is used to generate time series to validate the program. The program is then applied to signals from local power range monitors from the cycle 7 stability tests at the Leibstadt plant. (author) 7 figs., 2 tabs., 12 refs

Viscoelastic diamine surfactant for stable carbon dioxide/water foams over a wide range in salinity and temperature.

Science.gov (United States)

Elhag, Amro S; Da, Chang; Chen, Yunshen; Mukherjee, Nayan; Noguera, Jose A; Alzobaidi, Shehab; Reddy, Prathima P; AlSumaiti, Ali M; Hirasaki, George J; Biswal, Sibani L; Nguyen, Quoc P; Johnston, Keith P

2018-07-15

The viscosity and stability of CO 2 /water foams at elevated temperature can be increased significantly with highly viscoelastic aqueous lamellae. The slow thinning of these viscoelastic lamellae leads to greater foam stability upon slowing down Ostwald ripening and coalescence. In the aqueous phase, the viscoelasticity may be increased by increasing the surfactant tail length to form more entangled micelles even at high temperatures and salinity. Systematic measurements of the steady state shear viscosity of aqueous solutions of the diamine surfactant (C 16-18 N(CH 3 )C 3 N(CH 3 ) 2 ) were conducted at varying surfactant concentrations and salinity to determine the parameters for formation of entangled wormlike micelles. The apparent viscosity and stability of CO 2 /water foams were compared for systems with viscoelastic entangled micellar aqueous phases relative to those with much less viscous spherical micelles. We demonstrated for the first time stable CO 2 /water foams at temperatures up to 120 °C and CO 2 volumetric fractions up to 0.98 with a single diamine surfactant, C 16-18 N(CH 3 )C 3 N(CH 3 ) 2 . The foam stability was increased by increasing the packing parameter of the surfactant with a long tail and methyl substitution on the amine to form entangled viscoelastic wormlike micelles in the aqueous phase. The foam was more viscous and stable compared to foams with spherical micelles in the aqueous lamellae as seen with C 12-14 N(EO) 2 and C 16-18 N(EO)C 3 N(EO) 2 . Copyright © 2018. Published by Elsevier Inc.

The Impact of Temperatures on the Stability of Rocks Surrounding a Single Fracture

Science.gov (United States)

Zhang, Yan; Li, Ning; Dai, Jun

2018-05-01

Research on the influence of temperature and the accompanying stress on the stability of the rocks surrounding an underground tunnel has become ever more important. This paper constructs a geometric model of a single-fracture tunnel by combining a high-temperature underground tunnel as the object of study with an example that uses a high-temperature tunnel segment in the water diversion tunnel of a hydropower station in Xinjiang. Based on the relevant theoretical analysis, with the consideration of different working conditions, a numerical experimental analysis was conducted to determine the two-dimensional transient temperature field distribution of the tunnel rock mass by using a numerical analysis software. The experimental data was consistent with the measured data. The calculated results show the following: a. when the temperature difference is greater, the stress concentration is higher near the fracture of the surrounding rock; b. the degree of the stress concentration in the crack tip region is not positively correlated to the distance, and there is a sensitive region where the stress varies.

Stability of people exposed to water flows

Directory of Open Access Journals (Sweden)

E. Martínez-Gomariz

2016-01-01

Full Text Available Our cities are formed by several elements which are exposed to floods of a magnitude according to the importance of the rainfall event and the design of the urban drainage system. The most important components in the cities are the pedestrians who develop various activities during rain events. Focusing on pedestrians, the research on their stability when they are exposed to water flows provides the necessary knowledge to understand and manage the associated hazard for them. In this research, several experiments with humans were carried out in order to determine the stability limits to pedestrians crossing through a water flow in a real scale platform. The results obtained and by comparing those with human stability criteria proposed by other authors and guidelines provide a more restrictive criterion.

Aerobic stability of distillers wet grains as influenced by temperature.

Science.gov (United States)

Lehman, R Michael; Rosentrater, Kurt A

2013-02-01

The storability of distillers wet grains (DWG) influences the economic, energetic, and carbon balances of fuel ethanol production, yet there are limited published data on the deterioration of DWG following its production. We used biogenic CO(2) production to assess the aerobic stability of DWG incubated at three temperatures (12 °C, 22 °C, 32 °C) and compared CO(2) production over time to the appearance of mold and changes in DWG color parameters. CO(2) production and mold colonization indicate that at temperatures near 12 °C, the aerobic stability of DWG was high and that it can be stored for at least a 10-day period. At temperatures close to 22 °C, the onset of increased microbial activity and visible mold colonization occurred between 4 and 7 days and both activity and mold ratings were very high by the ninth day in all three experiments. At 32 °C, 2 days may be a more appropriate limit for storage. Temperature and time interact in a nonlinear fashion that permits the prediction of DWG stability boundaries. The simple visual appearance of mold appears to be a reasonable indicator that correlates well (r = 0.694) with CO(2) production, a measure of the aerobic stability of DWG. Published 2012 by John Wiley & Sons, Ltd.

Influence of temperature on the anaerobic stabilization of organic ...

African Journals Online (AJOL)

This study was aimed at determining the effect of temperature on the stabilization of organic solid waste conjugated with sewage sludge in anaerobic batch ... It is concluded that anaerobic digestion at ambient temperature represents an economical and environmentally viable strategy for the disposal of municipal solid ...

Viscosity of the oil-in-water Pickering emulsion stabilized by surfactant-polymer and nanoparticle-surfactant-polymer system

Science.gov (United States)

Sharma, Tushar; Kumar, G. Suresh; Chon, Bo Hyun; Sangwai, Jitendra S.

2014-11-01

Information on the viscosity of Pickering emulsion is required for their successful application in upstream oil and gas industry to understand their stability at extreme environment. In this work, a novel formulation of oil-in-water (o/w) Pickering emulsion stabilized using nanoparticle-surfactant-polymer (polyacrylamide) system as formulated in our earlier work (Sharma et al., Journal of Industrial and Engineering Chemistry, 2014) is investigated for rheological stability at high pressure and high temperature (HPHT) conditions using a controlled-strain rheometer. The nanoparticle (SiO2 and clay) concentration is varied from 1.0 to 5.0 wt%. The results are compared with the rheological behavior of simple o/w emulsion stabilized by surfactant-polymer system. Both the emulsions exhibit non-Newtonian shear thinning behavior. A positive shift in this behavior is observed for surfactant-polymer stabilized emulsion at high pressure conditions. Yield stress is observed to increase with pressure for surfactant-polymer emulsion. In addition, increase in temperature has an adverse effect on the viscosity of emulsion stabilized by surfactant-polymer system. In case of nanoparticle-surfactant-polymer stabilized o/w emulsion system, the viscosity and yield stress are predominantly constant for varying pressure and temperature conditions. The viscosity data for both o/w emulsion systems are fitted by the Herschel-Bulkley model and found to be satisfactory. In general, the study indicates that the Pickering emulsion stabilized by nanoparticle-surfactant-polymer system shows improved and stable rheological properties as compared to conventional emulsion stabilized by surfactant-polymer system indicating their successful application for HPHT environment in upstream oil and gas industry.

Effect of insulin phase state in water on its radiation stability

Energy Technology Data Exchange (ETDEWEB)

Soboleva, N N; Ivanova, A I; Tal' roze, V L; Trofimov, V I; Fedotov, V P [Nauchno-Issledovatel' skij Inst. po Biologicheskim Ispytaniyam Khimicheskikh Soedinenij (USSR); AN SSSR, Moscow. Inst. Khimicheskoj Fiziki; Akademiya Meditsinskikh Nauk SSSR, Moscow. Inst. Ehksperimental' noj Ehndokrinologii i Khimii Gormonov)

1980-01-01

Radiation stability of the aqueous solution and the insulin suspension is investigated. The degree of radiation transformations is determined by means of chromatography on paper and with the method of cramp reaction in mice. ..gamma..-irradiation is carried out at room temperature, at dose rate of 0.75 M rad/h. The data obtained prove the earlier suggested hypothesis of a phase division of a biologically active compound, personally medicinal substance and water (for example, in the case of which permits to prolong the preservation of medicine in the case of irradiation.

Physical stability, microstructure and micro-rheological properties of water-in-oil-in-water (W/O/W) emulsions stabilized by porcine gelatin.

Science.gov (United States)

Zhu, Qiaomei; Qiu, Shuang; Zhang, Hongwei; Cheng, Yongqiang; Yin, Lijun

2018-07-01

Water-in-oil-in-water (W/O/W) emulsions could be utilized for fat-reduced food formulation and delivery of bioactive nutrients. However, due to thermodynamic instability, it is difficult to prepare stable double emulsions. The purpose of this study was to improve the stability of W/O/W double emulsions containing 2.0 M MgCl 2 by adding porcine gelatin in the inner water phase. The impact of gelatin on the physical stability, microstructure and micro-rheological properties of W/O/W emulsions was investigated. It was found that, when the concentration of porcine gelatin exceeded 4.0 wt%, the stability of emulsions was improved, due to increased viscoelasticity of emulsion droplets. When MgCl 2 concentration increased to 2.0 M, the particle size of emulsions increased, due to the osmotic pressure gradient, and the presence of gelatin further increased the droplet size. Confocal microscopy results showed that the presence of gelatin could improve the stability of W/O/W emulsions against coalescence。. Copyright © 2018. Published by Elsevier Ltd.

Stability analysis of high temperature superconducting coil in liquid hydrogen

International Nuclear Information System (INIS)

Nakayama, T.; Yagai, T.; Tsuda, M.; Hamajima, T.

2007-01-01

Recently, it is expected that hydrogen plays an important role in energy source including electric power in near future. Liquid hydrogen has high potential for cooling down superconducting coil wound with high temperature superconductors (HTS), such as BSCCO, YBCO. In this paper, we study stabilities of the coils wound with BSCCO tapes, which are immersed in the liquid hydrogen, and compare stability results with those cooled by liquid helium. We treat a minimum propagation zone (MPZ) theory to evaluate the coil stability considering boiling heat flux of the liquid hydrogen, and specific heat, heat conduction and resistivity of HTS materials as a function of temperature. It is found that the coil cooled by the liquid hydrogen has higher stability margin than that cooled by the liquid helium. We compare the stability margins of both coils wound with Bi-2223/Ag tape and Bi-2212/Ag tape in liquid hydrogen. As a result, it is found that the stability of Bi-2212 coil is equivalent to that of Bi-2223 coil in low and high magnetic field, while the maximum current of Bi-2212 coil exceeds a little bit that of Bi-2223 coil in both magnetic fields

High temperature water chemistry monitoring

International Nuclear Information System (INIS)

Aaltonen, P.

1992-01-01

Almost all corrosion phenomena in nuclear power plants can be prevented or at least damped by water chemistry control or by the change of water chemistry control or by the change of water chemistry. Successful water chemistry control needs regular and continuous monitoring of such water chemistry parameters like dissolved oxygen content, pH, conductivity and impurity contents. Conventionally the monitoring is carried out at low pressures and temperatures, which method, however, has some shortcomings. Recently electrodes have been developed which enables the direct monitoring at operating pressures and temperatures. (author). 2 refs, 5 figs

Reduction and Analysis of Low Temperature Shift Heterogeneous Catalyst for Water Gas Reaction in Ammonia Production

Directory of Open Access Journals (Sweden)

Zečević, N.

2013-09-01

Full Text Available In order to obtain additional quantities of hydrogen after the reforming reactions of natural gas and protect the ammonia synthesis catalyst, it is crucial to achieve and maintain maximum possible activity, selectivity and stability of the low temperature shift catalyst for conversion of water gas reaction during its lifetime. Whereas the heterogeneous catalyst comes in oxidized form, it is of the utmost importance to conduct the reduction procedure properly. The proper reduction procedure and continuous analysis of its performance would ensure the required activity, selectivity and stability throughout the catalyst’s service time. For the proper reduction procedure ofthe low temperature shift catalyst, in addition to process equipment, also necessary is a reliable and realistic system for temperature measurements, which will be effective for monitoring the exothermal temperature curves through all catalyst bed layers. For efficiency evaluation of low shift temperature catalyst reduction and its optimization, it is necessary to determine at regular time intervals the temperature approach to equilibrium and temperature profiles of individual layers by means of "S" and "die off" temperature exothermal curves. Based on the obtained data, the optimum inlet temperature could be determined, in order to maximally extend the service life of the heterogeneous catalyst as much as possible, and achieve the optimum equilibrium for conversion of the water gas. This paper presents the methodology for in situ reduction of the low temperature shift heterogeneous catalyst and the developed system for monitoring its individual layers to achieve the minimum possible content of carbon monoxide at the exit of the reactor. The developed system for temperature monitoring through heterogeneous catalyst layers provides the proper procedure for reduction and adjustment of optimum process working conditions for the catalyst by the continuous increase of reactor inlet

Cooling-water amounts, temperature, and the environment

International Nuclear Information System (INIS)

Koops, F.B.J.; Donze, M.; Hadderingh, R.H.

1979-01-01

The release of heat from power plants into a water can take place with relative small quantities of cooling water, highly warmed up accordingly, or with large quantities of cooling water slightly warmed up. The utilization of cooling water is bound to certain guidelines established by the authorities. With the intention to protect the environment, the admissable temperatures and warming-up have been strictly limited by the authorities. In the Netherlands, we have presently temporary cooling water guidelines which allow a max. temperature of the cooling water in the cooling cycle of 30 0 C and a maximum admissible temperature rise in the condenser between 7 0 C during summer and 15 0 C during winter. It has also been determined in these requirements how much cooling water at least has to be used to discharge a specified quantity of heat. Plankton, spawn and young fish are dragged with the cooling water. Harm to these organisms can be caused mechanically by pumps, sieves and the condenser or they can be harmed by the temperature rise in the condenser. Investigations showed that mechanical harm to spawn and young fish in the cooling water flow should not be ignored, and that detectable harm to plankton organisms takes place only at water temperatures above 32 0 C. The cooling water consumption can therefore be optimised as follows: The solution of a greater temperature increase and a slightly higher value for the temperature maximum can reduce the cooling water quantity. This reduction of the cooling water quantity reduces the destruction of the fish quantity, which gets into the cooling water system, especially during the summer. If the temperature rise and the temperature itself are not selected too high, the destruction of fish may be reduced without causing serious damage to the plankton. (orig.) [de

Modelling global fresh surface water temperature

NARCIS (Netherlands)

Beek, L.P.H. van; Eikelboom, T.; Vliet, M.T.H. van; Bierkens, M.F.P.

2011-01-01

Temperature directly determines a range of water physical properties including vapour pressure, surface tension, density and viscosity, and the solubility of oxygen and other gases. Indirectly water temperature acts as a strong control on fresh water biogeochemistry, influencing sediment

Pressure pressure-balanced pH sensing system for high temperature and high pressure water

International Nuclear Information System (INIS)

Tachibana, Koji

1995-01-01

As for the pH measurement system for high temperature, high pressure water, there have been the circumstances that first the reference electrodes for monitoring corrosion potential were developed, and subsequently, it was developed for the purpose of maintaining the soundness of metallic materials in high temperature, high pressure water in nuclear power generation. In the process of developing the reference electrodes for high temperature water, it was clarified that the occurrence of stress corrosion cracking in BWRs is closely related to the corrosion potential determined by dissolved oxygen concentration. As the types of pH electrodes, there are metal-hydrogen electrodes, glass electrodes, ZrO 2 diaphragm electrodes and TiO 2 semiconductor electrodes. The principle of pH measurement using ZrO 2 diaphragms is explained. The pH measuring system is composed of YSZ element, pressure-balanced type external reference electrode, pressure balancer and compressed air vessel. The stability and pH response of YSZ elements are reported. (K.I.)

Identify the dominant variables to predict stream water temperature

Science.gov (United States)

Chien, H.; Flagler, J.

2016-12-01

Stream water temperature is a critical variable controlling water quality and the health of aquatic ecosystems. Accurate prediction of water temperature and the assessment of the impacts of environmental variables on water temperature variation are critical for water resources management, particularly in the context of water quality and aquatic ecosystem sustainability. The objective of this study is to measure stream water temperature and air temperature and to examine the importance of streamflow on stream water temperature prediction. The measured stream water temperature and air temperature will be used to test two hypotheses: 1) streamflow is a relatively more important factor than air temperature in regulating water temperature, and 2) by combining air temperature and streamflow data stream water temperature can be more accurately estimated. Water and air temperature data loggers are placed at two USGS stream gauge stations #01362357and #01362370, located in the upper Esopus Creek watershed in Phonecia, NY. The ARIMA (autoregressive integrated moving average) time series model is used to analyze the measured water temperature data, identify the dominant environmental variables, and predict the water temperature with identified dominant variable. The preliminary results show that streamflow is not a significant variable in predicting stream water temperature at both USGS gauge stations. Daily mean air temperature is sufficient to predict stream water temperature at this site scale.

Microstructure and elevated temperature stability of 9-12% Cr steels

Energy Technology Data Exchange (ETDEWEB)

Dogan, Omer N.; Hawk, Jeffrey A.

2005-02-01

Medium Cr steels have been used in fossil fired power plants for many years because of their excellent high temperature stability and mechanical properties. As the desire to increase the efficiency of power plants continues, the operating temperature (>650C) continues to go up. Currently available low and medium Cr containing steels will not withstand the new operating temperature and must be reassessed in terms of their solid-solution and precipitation strengthening schemes. Three medium Cr steels were developed to investigate high temperature alloy strengthening strategies: 0.08C-(9-12)Cr-1.2Ni-0.7Mo-3.0Cu-3.0Co-0.5Ti. The microstructure of the alloy will be described in the as-cast and thermo-mechanically worked states. In addition, the effect on microstructure from long-term high temperature exposure will also be discussed. Finally, the overall stability of these steels will be compared against currently available power plant steels.

TOPICAL REVIEW: Protein stability and enzyme activity at extreme biological temperatures

Science.gov (United States)

Feller, Georges

2010-08-01

Psychrophilic microorganisms thrive in permanently cold environments, even at subzero temperatures. To maintain metabolic rates compatible with sustained life, they have improved the dynamics of their protein structures, thereby enabling appropriate molecular motions required for biological activity at low temperatures. As a consequence of this structural flexibility, psychrophilic proteins are unstable and heat-labile. In the upper range of biological temperatures, thermophiles and hyperthermophiles grow at temperatures > 100 °C and synthesize ultra-stable proteins. However, thermophilic enzymes are nearly inactive at room temperature as a result of their compactness and rigidity. At the molecular level, both types of extremophilic proteins have adapted the same structural factors, but in opposite directions, to address either activity at low temperatures or stability in hot environments. A model based on folding funnels is proposed accounting for the stability-activity relationships in extremophilic proteins.

Interfacial transport phenomena and stability in liquid-metal/water systems: scaling considerations

International Nuclear Information System (INIS)

Abdulla, S.; Liu, X.; Anderson, M.; Bonazza, R.; Corradini, M.; Cho, D.

2001-01-01

One concept being considered for steam generation in innovative nuclear reactor applications, involves water coming into direct contact with a circulating molten metal. The vigorous agitation of the two fluids, the direct liquid-liquid contact and the consequent large interfacial area give rise to very high heat transfer coefficients and rapid steam generation. For an optimum design of such direct contact heat exchange and vaporization systems, detailed knowledge is necessary of the various flow regimes, interfacial transport phenomena, heat transfer and operational stability. In this paper we describe current results from the first year of this research that studies the transport phenomena involved with the injection of water into molten metals (e.g., lead alloys). In particular, this work discusses scaling considerations related to direct contact heat exchange, our experimental plans for investigation and a test plan for the important experimental parameters; i.e., the water and liquid metal mass flow rates, the liquid metal pool temperature and the ambient pressure of the direct contact heat exchanger. Past experimental work and initial scaling results suggest that our experiments can directly represent the proper liquid metal pool temperature and the water subcooling. The experimental variation in water and liquid metal flow rates and system pressure (1-10 bar), although smaller than the current conceptual system designs, is sufficient to verify the expected scale effects to demonstrate the phenomena. (authors)

Phase stability of TiH{sub 2} under high pressure and temperatures

Energy Technology Data Exchange (ETDEWEB)

Selva Vennila, R.; Durygin, A.; Saxena, S.K. [Center for Study of Matter at Extreme Conditions (CeSMEC), Florida International University, VH-150, University Park, Miami, FL 33199 (United States); Merlini, Marco [European Synchrotron Radiation Facility (ESRF), Grenoble 38043 (France); Wang, Zhongwu [Cornell High Energy Synchrotron Source (CHESS), Wilson Laboratory, Cornell University, Ithaca, NY 14853 (United States)

2008-11-15

Phase stability of titanium hydride (TiH{sub 2}) was studied at high pressure-high temperature conditions using synchrotron radiation under non-hydrostatic conditions. Resistive heating method was used to heat the sample to a maximum temperature of 873 K in a diamond anvil cell (DAC) under pressure up to 12 GPa. Pressure-temperature behavior was studied by varying the temperature upto 823 K in steps of 50 K with pressure variations within 3 GPa. Structural phase transformation from tetragonal (I4/mmm) to cubic (Fm-3 m) was observed with increase in temperature. Tetragonal phase was found to be stabilized when the sample was subjected to pressure and temperature cycle. (author)

Soil-Water Characteristic Curves of Red Clay treated by Ionic Soil Stabilizer

Science.gov (United States)

Cui, D.; Xiang, W.

2009-12-01

The relationship of red clay particle with water is an important factor to produce geological disaster and environmental damage. In order to reduce the role of adsorbed water of red clay in WuHan, Ionic Soil Stabilizer (ISS) was used to treat the red clay. Soil Moisture Equipment made in U.S.A was used to measure soil-water characteristic curve of red clay both in natural and stabilized conditions in the suction range of 0-500kPa. The SWCC results were used to interpret the red clay behavior due to stabilizer treatment. In addition, relationship were compared between the basic soil and stabilizer properties such as water content, dry density, liquid limit, plastic limit, moisture absorption rate and stabilizer dosages. The analysis showed that the particle density and specific surface area increase, the dehydration rate slows and the thickness of water film thins after treatment with Ionic Soil Stabilizer. After treatment with the ISS, the geological disasters caused by the adsorbed water of red clay can be effectively inhibited.

Selection for Protein Kinetic Stability Connects Denaturation Temperatures to Organismal Temperatures and Provides Clues to Archaean Life.

Directory of Open Access Journals (Sweden)

M Luisa Romero-Romero

Full Text Available The relationship between the denaturation temperatures of proteins (Tm values and the living temperatures of their host organisms (environmental temperatures: TENV values is poorly understood. Since different proteins in the same organism may show widely different Tm's, no simple universal relationship between Tm and TENV should hold, other than Tm≥TENV. Yet, when analyzing a set of homologous proteins from different hosts, Tm's are oftentimes found to correlate with TENV's but this correlation is shifted upward on the Tm axis. Supporting this trend, we recently reported Tm's for resurrected Precambrian thioredoxins that mirror a proposed environmental cooling over long geological time, while remaining a shocking ~50°C above the proposed ancestral ocean temperatures. Here, we show that natural selection for protein kinetic stability (denaturation rate can produce a Tm↔TENV correlation with a large upward shift in Tm. A model for protein stability evolution suggests a link between the Tm shift and the in vivo lifetime of a protein and, more specifically, allows us to estimate ancestral environmental temperatures from experimental denaturation rates for resurrected Precambrian thioredoxins. The TENV values thus obtained match the proposed ancestral ocean cooling, support comparatively high Archaean temperatures, and are consistent with a recent proposal for the environmental temperature (above 75°C that hosted the last universal common ancestor. More generally, this work provides a framework for understanding how features of protein stability reflect the environmental temperatures of the host organisms.

Temperature stability and electrical properties in La-doped KNN-based ceramics

KAUST Repository

Lv, Xiang; Wu, Jiagang; Zhu, Jianguo; Xiao, Dingquan; Zhang, Xixiang

2018-01-01

To improve the temperature stability and electrical properties of KNN‐based ceramics, we simultaneously consider the phase boundary and the addition of rare earth element (La), 0.96K0.5Na0.5Nb0.96Sb0.04O3‐0.04(Bi1‐xLax)0.5Na0.5ZrO3 (0 ≤ x ≤ 1.0) ceramics. More specifically, we investigate how the phase boundary and the addition of La3+ affect the phase structure, electrical properties, and temperature stability of the ceramic. We show that increasing the La3+ content leads to a change in phase structure, from a rhombohedral‐tetragonal (R‐T) phase coexistence to a cubic phase. More importantly, we show that the appropriate addition of La3+ (x = 0.2) can simultaneously improve the unipolar strain (from 0.127% to 0.147%) and the temperature stability (i.e., the unipolar strain of 0.147% remains unchanged when T is increased from 25 to 80°C). In addition, we find that the ceramics with x = 0.2 exhibit a large piezoelectric constant (d33) of ~430 pC/N, a high Curie temperature (TC) of ~240°C and a fatigue‐free behavior (after 106 electric cycles). The enhanced electrical properties mostly originate from the easy domain switching, whereas the improved temperature stability can be attributed to the R‐T phase boundary and the appropriate addition of La3+.

Temperature stability and electrical properties in La-doped KNN-based ceramics

KAUST Repository

Lv, Xiang

2018-04-16

To improve the temperature stability and electrical properties of KNN‐based ceramics, we simultaneously consider the phase boundary and the addition of rare earth element (La), 0.96K0.5Na0.5Nb0.96Sb0.04O3‐0.04(Bi1‐xLax)0.5Na0.5ZrO3 (0 ≤ x ≤ 1.0) ceramics. More specifically, we investigate how the phase boundary and the addition of La3+ affect the phase structure, electrical properties, and temperature stability of the ceramic. We show that increasing the La3+ content leads to a change in phase structure, from a rhombohedral‐tetragonal (R‐T) phase coexistence to a cubic phase. More importantly, we show that the appropriate addition of La3+ (x = 0.2) can simultaneously improve the unipolar strain (from 0.127% to 0.147%) and the temperature stability (i.e., the unipolar strain of 0.147% remains unchanged when T is increased from 25 to 80°C). In addition, we find that the ceramics with x = 0.2 exhibit a large piezoelectric constant (d33) of ~430 pC/N, a high Curie temperature (TC) of ~240°C and a fatigue‐free behavior (after 106 electric cycles). The enhanced electrical properties mostly originate from the easy domain switching, whereas the improved temperature stability can be attributed to the R‐T phase boundary and the appropriate addition of La3+.

Effects of air temperature and discharge on Upper Mississippi River summer water temperatures

Science.gov (United States)

Gray, Brian R.; Robertson, Dale M.; Rogala, James T.

2018-01-01

Recent interest in the potential effects of climate change has prompted studies of air temperature and precipitation associations with water temperatures in rivers and streams. We examined associations between summer surface water temperatures and both air temperature and discharge for 5 reaches of the Upper Mississippi River during 1994–2011. Water–air temperature associations at a given reach approximated 1:1 when estimated under an assumption of reach independence but declined to approximately 1:2 when water temperatures were permitted to covary among reaches and were also adjusted for upstream air temperatures. Estimated water temperature–discharge associations were weak. An apparently novel feature of this study is that of addressing changes in associations between water and air temperatures when both are correlated among reaches.

Estimation of paddy water temperature during crop development

International Nuclear Information System (INIS)

Centeno, H.G.S.; Horie, T.

1996-01-01

The crop meristem is in direct contact with paddy water during crop's vegetative stage. Ambient air temperature becomes an important factor in crop development only when internodes elongate sufficiently for the meristem to rise above the water surface. This does not occur until after panicle initiation. Crop growth at vegetative stage is affected more by water temperature than the most commonly measured air temperature. During transplanting in 1992 dry season, the maximum paddy water temperature was 10 deg C higher than the maximum air temperature. For rice crop models, the development of a submodel to estimate water temperature is important to account the effect of paddy water temperature on plant growth. Paddy water temperature is estimated from mean air temperature, solar radiation, and crop canopy. The parameters of the model were derived using the simplex method on data from the 1993 wet- and dry-season field experiments at IRRI

Improvements in X-band transmitter phase stability through Klystron body temperature regulation

Science.gov (United States)

Perez, R. M.

1992-01-01

This article describes the techniques used and experimental results obtained in improving transmitter stability by control of the klystron body temperature. Related work in the measurement of klystron phase control parameters (pushing factors) is also discussed. The contribution of wave guide temperature excursions to uplink phase stability is presented. Suggestions are made as to the direction of future work in this area.

Sensing disks for slug-type calorimeters have higher temperature stability

Science.gov (United States)

1967-01-01

Graphite sensing disk for slug-type radiation calorimeters exhibits better performance at high temperatures than copper and nickel disks. The graphite is heat-soaked to stabilize its emittance and the thermocouple is protected from the graphite so repeated temperature cycling does not change its sensitivity.

Pickering emulsions stabilized by paraffin wax and Laponite clay particles.

Science.gov (United States)

Li, Caifu; Liu, Qian; Mei, Zhen; Wang, Jun; Xu, Jian; Sun, Dejun

2009-08-01

Emulsions containing wax in dispersed droplets stabilized by disc-like Laponite clay particles are prepared. Properties of the emulsions prepared at different temperatures are examined using stability, microscopy and droplet-size analysis. At low temperature, the wax crystals in the oil droplets can protrude through the interface, leading to droplet coalescence. But at higher temperatures, the droplet size decreases with wax concentration. Considering the viscosity of the oil phase and the interfacial tension, we conclude that the wax is liquid-like during the high temperature emulsification process, but during cooling wax crystals appear around the oil/water interface and stabilize the droplets. The oil/water ratio has minimal effect on the emulsions between ratios of 3:7 and 7:3. The Laponite is believed to stabilize the emulsions by increasing the viscosity of the continuous phase and also by adsorbing at the oil/water interface, thus providing a physical barrier to coalescence.

Stability monitoring of a natural-circulation-cooled boiling water reactor

International Nuclear Information System (INIS)

Hagen, T.H.J.J. van der.

1989-01-01

Methods for monitoring the stability of a boiling water reactor (BWR) are discussed. Surveillance of BWR stability is of importance as problems were encountered in several large reactors. Moreover, surveying stability allows plant owners to operate at high power with acceptable stability margins. The results of experiments performed on the Dodewaard BWR (the Netherlands) are reported. This type reactor is cooled by natural circulation, a cooling principle that is also being considered for new reactor designs. The stability of this reactor was studied both with deterministic methods and by noise analysis. Three types of stability are distinguished and were investigated separately: reactor-kinetic stability, thermal-hydraulic stability and total-plant stability. It is shown that the Dodewaard reactor has very large stability margins. A simple yet reliable stability criterion is introduced. It can be derived on-line from thhe noise signal of ex-vessel neutron detectors during normal operation. The sensitivity of neutron detectors to in-core flux perturbations - reflected in the field-of-view of the detector - was calculated in order to insure proper stability surveillance. A novel technique is presented which enables the determination of variations of the in-core coolant velocity by noise correlation. The velocity measured was interpreted on the basis of experiments performed on the air/water flow in a model of a BWR coolant channel. It appeared from this analysis that the velocity measured was much higher than the volume-averaged water and air velocities and the volumetric flux. The applicability of the above-mentioned technique to monitoring of local channel-flow stability was tested. It was observed that stability effects on the coolant velocity are masked by other effects originating from the local flow pattern. Experimental and theoretical studies show a shorter effective fuel time constant in a BWR than was assumed. (author). 118 refs.; 73 figs.; 21 tabs

Pronounced microheterogeneity in a sorbitol-water mixture observed through variable temperature neutron scattering.

Science.gov (United States)

Chou, Shin G; Soper, Alan K; Khodadadi, Sheila; Curtis, Joseph E; Krueger, Susan; Cicerone, Marcus T; Fitch, Andrew N; Shalaev, Evgenyi Y

2012-04-19

structure of aqueous glasses over a broad temperature and length scale, leading to an improved understanding of the mechanisms of temperature- and water-induced (de)stabilization of various systems, including proteins, pharmaceuticals, and biological objects.

Microprocessor system for temperature regulation and stabilization

International Nuclear Information System (INIS)

Nguyen Nhi Dien; Rodionov, K.G.

1989-01-01

Microprocessor based system for temperature regulation and stabilization of an operation external object is described. The system has the direct current amplifier working according to modulator-demodulator principle. The overal gain is 100, 1000, 2000. The maximum output signal is ±10 V. The power amplifier is a thyristor one and its line voltage is 220 V, 50 Hz. The output power is 0-2 kVA. The microcontroller has a remote display terminal. Data input is 8 and data output is one. Input and output voltage is ±(0-10) V. The preselection time for stabilization is within 1 s - 18 h. The program algorithm is given. 5 figs.; 1 tab

Correlation of high-temperature stability of alpha-chymotrypsin with 'salting-in' properties of solution.

Science.gov (United States)

Levitsky VYu; Panova, A A; Mozhaev, V V

1994-01-15

A correlation between the stability of alpha-chymotrypsin against irreversible thermal inactivation at high temperatures (long-term stability) and the coefficient of Setchenov equation as a measure of salting-in/out efficiency of solutes in the Hofmeister series has been found. An increase in the concentration of salting-in solutes (KSCN, urea, guanidinium chloride, formamide) leads to a many-fold decrease of the inactivation rate of the enzyme. In contrast, addition of salting-out solutes has a small effect on the long-term stability of alpha-chymotrypsin at high temperatures. The effects of solutes are additive with respect to their salting-in/out capacities; the stabilizing action of the solutes is determined by the calculated Setchenov coefficient of solution. The correlation is explained by a solute-driven shift of the conformational equilibrium between the 'low-temperature' native and the 'high-temperature' denatured forms of the enzyme within the range of the kinetic scheme put forward in the preceding paper in this journal: irreversible inactivation of the high-temperature form proceeds much more slowly compared with the low-temperature form.

A Water Temperature Simulation Model for Rice Paddies With Variable Water Depths

Science.gov (United States)

Maruyama, Atsushi; Nemoto, Manabu; Hamasaki, Takahiro; Ishida, Sachinobu; Kuwagata, Tsuneo

2017-12-01

A water temperature simulation model was developed to estimate the effects of water management on the thermal environment in rice paddies. The model was based on two energy balance equations: for the ground and for the vegetation, and considered the water layer and changes in the aerodynamic properties of its surface with water depth. The model was examined with field experiments for water depths of 0 mm (drained conditions) and 100 mm (flooded condition) at two locations. Daily mean water temperatures in the flooded condition were mostly higher than in the drained condition in both locations, and the maximum difference reached 2.6°C. This difference was mainly caused by the difference in surface roughness of the ground. Heat exchange by free convection played an important role in determining water temperature. From the model simulation, the temperature difference between drained and flooded conditions was more apparent under low air temperature and small leaf area index conditions; the maximum difference reached 3°C. Most of this difference occurred when the range of water depth was lower than 50 mm. The season-long variation in modeled water temperature showed good agreement with an observation data set from rice paddies with various rice-growing seasons, for a diverse range of water depths (root mean square error of 0.8-1.0°C). The proposed model can estimate water temperature for a given water depth, irrigation, and drainage conditions, which will improve our understanding of the effect of water management on plant growth and greenhouse gas emissions through the thermal environment of rice paddies.

Furnace System Testing to Support Lower-Temperature Stabilization of High Chloride Plutonium Oxide Items at the Hanford Plutonium Finishing Plant

International Nuclear Information System (INIS)

Schmidt, Andrew J.; Gerber, Mark A.; Fischer, Christopher M.; Elmore, Monte R.

2003-01-01

High chloride content plutonium (HCP) oxides are impure plutonium oxide scrap which contains NaCl, KCl, MgCl2 and/or CaCl2 salts at potentially high concentrations and must be stabilized at 950 C per the DOE Standard, DOE-STD-3013-2000. The chlorides pose challenges to stabilization because volatile chloride salts and decomposition products can corrode furnace heating elements and downstream ventilation components. Thermal stabilization of HCP items at 750 C (without water washing) is being investigated as an alternative method for meeting the intent of DOE STD 3013-2000. This report presents the results from a series of furnace tests conducted to develop material balance and system operability data for supporting the evaluation of lower-temperature thermal stabilization

Characterization of hydrolytic degradation of polylactic acid/rice hulls composites in water at different temperatures

Directory of Open Access Journals (Sweden)

2011-02-01

Full Text Available Hydrolytic degradations of polylactic acid/rice hulls (PLA/RH composites with various rice hulls contents due to water absorptions at 23, 51 and 69°C were investigated by studying the thermal properties, chemical composition, molecular weight, and morphology of the degraded products. The results have attested that the stability of PLA/RH composites in water depends slightly on rice hulls contents but it is significantly influenced by water temperature. Water absorption in 30 days at 23°C was between 0.87 and 9.25% depending on rice hull contents. However, at thermophilic temperatures, the water absorption and degradation of these products were increased significantly. Saturations were achieved in less than 25 and 9 days at 51°C and 69°C, respectively, while hydrolytic degradation was demonstrated by an increase in fragility and development of crystallinity. At 69°C, there were significant reductions of the decomposition and glass transition temperatures of the polymer by 13°C. These changes were associated with the reduction of the molecular weight of PLA from 153.1 kDa to ~10.7 kDa due to hydrolysis of its ester group.

Enhanced Stability of a Protein with Increasing Temperature

DEFF Research Database (Denmark)

Vinther, Joachim Møllesøe; Kristensen, Søren M; Led, Jens J

2010-01-01

The unusual stability of a structured but locally flexible protein, human growth hormone (hGH) at pH 2.7, was investigated using the temperature dependence of the nanosecond-picosecond dynamics of the backbone amide groups obtained from (15)N NMR relaxation data. It is found that the flexibility ...

Physical and oxidative stability of fish oil-in-water emulsions stabilized with beta-lactoglobulin and pectin.

Science.gov (United States)

Katsuda, Marly S; McClements, D J; Miglioranza, Lucia H S; Decker, Eric A

2008-07-23

The oxidation of fatty acids can be inhibited by engineering the surface of oil-in-water emulsion droplets to decrease interactions between aqueous phase prooxidants and lipids. The objective of this research was to evaluate whether emulsions stabilized by a multilayer emulsifier systems consisting of beta-lactoglobulin and citrus or sugar beet pectin could produce fish oil-in-water emulsions that had good physical and oxidative stability. Sugar beet pectin was compared to citrus pectin because the sugar beet pectin contains the known antioxidant, ferulic acid. A primary Menhaden oil-in-water emulsion was prepared with beta-lactoglobulin upon which the pectins were electrostatically deposited at pH 3.5. Emulsions prepared with 1% oil, 0.05% beta-lactoglobulin, and 0.06% pectins were physically stable for up to 16 days. As determined by monitoring lipid hydroperoxide and headspace propanal formation, emulsions prepared with the multilayer system of beta-lactoglobulin and citrus pectin were more stable than emulsions stabilized with beta-lactoglobulin alone. Emulsions prepared with the multilayer system of beta-lactoglobulin and sugar beet pectin were less stable than emulsions stabilized with beta-lactoglobulin alone despite the presence of ferulic acid in the sugar beet pectin. The lower oxidative stability of the emulsions with the sugar beet pectin could be due to its higher iron and copper concentrations which would produce oxidative stress that would overcome the antioxidant capacity of ferulic acid. These data suggest that the oxidative stability of oil-in-water emulsions containing omega-3 fatty acids could be improved by the use of multilayer emulsion systems containing pectins with low metal concentrations.

Structure and stability of spiro-cyclic water clusters

Indian Academy of Sciences (India)

Administrator

Abstract. The structure and stability of spiro-cyclic water clusters containing up to 32 water molecules have been ... due to its importance in various real life systems. 1–8. High level ... It is well-known from the crystal structure data- base that the ...

Stability and uniformity of extemporaneous preparations of voriconazole in two liquid suspension vehicles at two storage temperatures.

Science.gov (United States)

Nguyen, Kyvan Q; Hawkins, Michelle G; Taylor, Ian T; Wiebe, Valerie J; Tell, Lisa A

2009-07-01

To determine the stability and distribution of voriconazole in 2 extemporaneously prepared (compounded) suspensions stored for 30 days at 2 temperatures. Voriconazole suspensions (40 mg/mL) compounded from commercially available 200-mg tablets suspended in 1 of 2 vehicles. One vehicle contained a commercially available suspending agent and a sweetening syrup in a 1:1 mixture (SASS). The other vehicle contained the suspending agent with deionized water in a 3:1 mixture (SADI). Voriconazole suspensions (40 mg/mL in 40-mL volumes) were compounded on day 0 and stored at room temperature (approx 21 degrees C) or refrigerated (approx 5 degrees C). To evaluate distribution, room-temperature aliquots of voriconazole were measured immediately after preparation. Refrigerated aliquots were measured after 3 hours of refrigeration. To evaluate stability, aliquots from each suspension were measured at approximately 7-day intervals for up to 30 days. Voriconazole concentration, color, odor, opacity, and pH were measured, and aerobic and anaerobic bacterial cultures were performed at various points. Drug distribution was uniform (coefficient of variation, suspensions. On day 0, 87.8% to 93.0% of voriconazole was recovered; percentage recovery increased to between 95.1% and 100.8% by day 7. On subsequent days, up to day 30, percentage recovery was stable (> 90%) for all suspensions. The pH of each suspension did not differ significantly throughout the 30-day period. Storage temperature did not affect drug concentrations at any time, nor was bacterial growth obtained. Extemporaneously prepared voriconazole in SASS and SADI resulted in suspensions that remained stable for at least 30 days. Refrigerated versus room-temperature storage of the suspensions had no effect on drug stability.

Power distribution effects on boiling water reactor stability

International Nuclear Information System (INIS)

Damiano, B.; March-Leuba, J.

1989-01-01

The work presented in this paper deals with the effects of spatial power distributions on the stability of boiling water reactors (BWRs). It is shown that a conservative power distribution exists for which the stability is minimal. These results are relevant because they imply that bounding stability calculations are possible and, thus, a worst-possible scenario may be defined for a particular BWR geometry. These bounding calculations may, then, be used to determine the maximum expected limit-cycle peak powers

STABILIZATION OF TEMPERATURE REGIMES WHILE SYNTHESIZING DIAMOND POWDERS

Directory of Open Access Journals (Sweden)

A. I. Dudiak

2012-01-01

Full Text Available The paper considers peculiar features of artificial diamond powder synthesis process and also direct and indirect methods for temperature measurement in a reaction cell of high-pressure apparatus. Differences in temperature regimes of diamond synthesis associated with time fixation of strain and heating power have been analyzed in the paper. The paper  reveals their impracticability.Theoretical methodology for temperature correction in the reaction cell has been proposed in the paper. An algorithm controlling cell material heating has been developed on the basis of a microcontroller and it makes it possible to stabilize temperature in the reaction mixture that permits to improve quality and strength characteristics of the obtained diamond powders. The paper contains a graphic interpretation of calculation results with the help of the proposed algorithm. 

Thermal stability and high temperature polymorphism of topochemically-prepared Dion–Jacobson triple-layered perovskites

Energy Technology Data Exchange (ETDEWEB)

Guertin, Stephen L.; Josepha, Elisha A.; Montasserasadi, Dariush; Wiley, John B., E-mail: jwiley@uno.edu

2015-10-25

The thermal stability of six Dion–Jacobson-related triple layered perovskites, ACa{sub 2}Nb{sub 3}O{sub 10} (A = H, NH{sub 4}, Li, Na, K, CuCl), was explored to 1000 °C. Each compound was produced topochemically by low-temperature (<500 °C) ion exchange from RbCa{sub 2}Nb{sub 3}O{sub 10}. The thermal behavior of the series was examined by variable temperature X-ray powder diffraction experiments in tandem with thermogravimetric analysis and differential scanning calorimetry. Five of the species were found to be low temperature/metastable phases, decomposing below 900 °C, where the stability of the series decreased with decreasing interlayer cation size. The compounds, A = Li, Na, K, exhibited high temperature polymorphism, with a completely reversible transition evident for KCa{sub 2}Nb{sub 3}O{sub 10}. - Highlights: • Thermal stability of topochemically prepared triple-layered perovskites studied. • Clear correlation seen between stability and identity of interlayer cation. • Several in ACa{sub 2}Nb{sub 3}O{sub 10} series (A = Li, Na, K) exhibit high temperature polymorphism.

Elevated temperature drives kelp microbiome dysbiosis, while elevated carbon dioxide induces water microbiome disruption.

Directory of Open Access Journals (Sweden)

Jeremiah J Minich

Full Text Available Global climate change includes rising temperatures and increased pCO2 concentrations in the ocean, with potential deleterious impacts on marine organisms. In this case study we conducted a four-week climate change incubation experiment, and tested the independent and combined effects of increased temperature and partial pressure of carbon dioxide (pCO2, on the microbiomes of a foundation species, the giant kelp Macrocystis pyrifera, and the surrounding water column. The water and kelp microbiome responded differently to each of the climate stressors. In the water microbiome, each condition caused an increase in a distinct microbial order, whereas the kelp microbiome exhibited a reduction in the dominant kelp-associated order, Alteromondales. The water column microbiomes were most disrupted by elevated pCO2, with a 7.3 fold increase in Rhizobiales. The kelp microbiome was most influenced by elevated temperature and elevated temperature in combination with elevated pCO2. Kelp growth was negatively associated with elevated temperature, and the kelp microbiome showed a 5.3 fold increase Flavobacteriales and a 2.2 fold increase alginate degrading enzymes and sulfated polysaccharides. In contrast, kelp growth was positively associated with the combination of high temperature and high pCO2 'future conditions', with a 12.5 fold increase in Planctomycetales and 4.8 fold increase in Rhodobacteriales. Therefore, the water and kelp microbiomes acted as distinct communities, where the kelp was stabilizing the microbiome under changing pCO2 conditions, but lost control at high temperature. Under future conditions, a new equilibrium between the kelp and the microbiome was potentially reached, where the kelp grew rapidly and the commensal microbes responded to an increase in mucus production.

Effect of yttria addition on the stability of porous chromium oxide ceramics in supercritical water

International Nuclear Information System (INIS)

Dong Ziqiang; Chen Weixing; Zheng Wenyue; Guzonas, Dave

2013-01-01

Porous chromium oxide (Cr 2 O 3 ) ceramics were prepared by oxidizing highly porous chromium carbides that were obtained by a reactive sintering method, and were evaluated at temperatures ranging from 375 °C to 625 °C in supercritical water (SCW) environments with a fixed pressure of 25–30 MPa. Reactive element yttrium was introduced to the porous oxide ceramic by adding various amounts of yttria of 5, 10 and 20 wt.%, respectively, prior to reactive sintering. The exposure in SCW shows that the porous chromium oxide is quite stable in SCW at 375 °C. However, the stability decreased with increasing temperature. It is well known that chromium oxide can be oxidized to soluble chromium (VI) species in SCW when oxygen is present. Adding yttria increases the stability of chromium oxide in SCW environments. However, adding yttria higher than 5 wt.% increased the weight loss of porous chromium oxide samples because of the direct dissociation of Y 2 O 3 in SCW.

Stability analysis of supercritical-pressure light water-cooled reactor in constant pressure operation

International Nuclear Information System (INIS)

Suhwan, JI; Shirahama, H.; Koshizuka, S.; Oka, Y.

2001-01-01

The purpose of this study is to evaluate the thermal-hydraulic and the thermal-nuclear coupled stabilities of a supercritical pressure light water-cooled reactor. A stability analysis code at supercritical pressure is developed. Using this code, stabilities of full and partial-power reactor operating at supercritical pressure are investigated by the frequency-domain analysis. Two types of SCRs are analyzed; a supercritical light water reactor (SCLWR) and a supercritical water-cooled fast reactor (SCFR). The same stability criteria as Boiling Water Reactor are applied. The thermal-hydraulic stability of SCLWR and SCFR satisfies the criteria with a reasonable orifice loss coefficient. The decay ratio of the thermal-nuclear coupled stability in SCFR is almost zero because of a small coolant density coefficient of the fast reactor. The evaluated decay ratio of the thermal-nuclear coupled stability is 3,41 ∼ 10 -V at 100% power in SCFR and 0,028 at 100% power in SCLWR. The sensitivity is investigated. It is found that the thermal-hydraulic stability is sensitive to the mass flow rate strongly and the thermal-nuclear coupled stability to the coolant density coefficient. The bottom power peak distribution makes the thermal-nuclear stability worse and the thermal-nuclear stability better. (author)

Influence of dump voltage and allowable temperature rise on stabilizer requirements in superconducting coils

International Nuclear Information System (INIS)

Schwenterly, S.W.

1988-01-01

A superconducting winding must have enough stabilizer to satisfy two sets of criteria. During normal operation, the amount of stabilizer must be large enough either to make the coil unconditionally stable or to give a certain desired stability margin. Once a dump occurs, the amount of stabilizer must be large enough to carry the current without generating excessive dump voltages or allowing the winding to exceed a certain maximum temperature (and maximum pressure, in the case of force-cooled coils). The voltage criterion often dominates for very large coil systems, but it is frequently ignored in initial design studies. This paper gives some simple relations between the dump voltage and the stored energy, temperature rise, and coil geometry that are useful in scooping the required amount of stabilizer. Comparison with some recently proposed fusion magnet system designs indicates that excessive dump voltages could result in some cases. High-temperature superconductors may require more stabilizer than the conventional alloys. Calculations with simple model coil systems indicate how trade-offs between various coil parameters affect the dump voltage. 12 refs., 1 fig., 1 tab

Effect of dialysate temperature on hemodynamic stability among hemodialysis patients

International Nuclear Information System (INIS)

Azar, Ahmad Taher

2009-01-01

Cooling the dialysate below 36.5 degree C is an important factor that contributes to hemody-namic stability in patients during hemodialysis (HD). In this study, the effect of dialysate tempe-rature on hemodynamic stability, patients' perception of dialysis discomfort and post dialysis fatigue were assessed in a group of patients on HD. A total of 50 patients, all of whom were on 3-times-perweek dialysis regimen, were studied. Patients were assessed during six dialysis sessions; in three sessions, the dialysate temperature was normal (37 degree C) and in three other sessions, the dialysate temperature was low (35 degree C). Specific scale questionnaires were used in each dialysis session, to evaluate the symptoms during the dialysis procedure as well as post-dialysis fatigue, and respective scores were noted. The results showed that usage of low dialysate temperature was associated with the following: higher post dialysis systolic blood pressure (P< 0.05) and lower post dialysis heart rate (P<0.01), with similar ultrafiltration rates, better intra-dialysis symptoms score and post-dialysis fatigue scores (P< 0.001, and P<0.001, respectively), shorter post-dialysis fatigue period (P<0.001) as well as higher urea removal (P< 00001) and Kt/V (P< 0.0001). Patients' perceptions were measured by a questionnaire, which showed that 76% of them felt more energetic after dialysis with cool dialysate and requested to be always dialyzed with cool dialysate. Low temperature dialysate is particularly beneficial for highly symptomatic patients, improves tolerance to dialysis in hypotensive patients and helps increase ultrafiltration while maintaining hemodynamic stability during and after dialysis. (author)

BELINDA: Broadband Emission Lidar with Narrowband Determination of Absorption. A new concept for measuring water vapor and temperature profiles

Science.gov (United States)

Theopold, F. A.; Weitkamp, C.; Michaelis, W.

1992-01-01

We present a new concept for differential absorption lidar measurements of water vapor and temperature profiles. The idea is to use one broadband emission laser and a narrowband filter system for separation of the 'online' and 'offline' return signals. It is shown that BELINDA offers improvements as to laser emission shape and stability requirements, background suppression, and last and most important a significant reduction of the influence of Rayleigh scattering. A suitably designed system based on this concept is presented, capable of measuring water vapor or temperature profiles throughout the planetary boundary layer.

Stabilization of metastable tetragonal zirconia nanocrystallites by surface modification

DEFF Research Database (Denmark)

Nielsen, Mette Skovgaard; Almdal, Kristoffer; Lelieveld, A. van

2011-01-01

Metastable tetragonal zirconia nanocrystallites were studied in humid air and in water at room temperature (RT). A stabilizing effect of different surfactants on the tetragonal phase was observed. Furthermore, the phase stability of silanized metastable tetragonal zirconia nanocrystallites was te...... exposure to humidity. Only silanes and phosphate esters of these were able to stabilize the tetragonal phase in water. Even as small amounts of silanes as 0.25 silane molecule per nm2 are able to stabilize the tetragonal phase in water at RT. Aminopropyl trimethoxy silane and γ...

The role of water in the behaviour of concretes at high temperature

International Nuclear Information System (INIS)

Feraille-Fresnet, A.

2000-01-01

Since 1996, three fires have been counted in tunnels in Europe. During each of these accidents. the temperature reached by the structure has been estimated between 800 deg C and 1200 deg C. Beside these spectacular accidental situations, there are many other situations in which concrete structures are submitted to high temperatures during their regular use. Several research work has been undertaken for a better understanding of the behaviour of concrete submitted to high temperatures and the physical phenomena involved. This PhD Thesis takes down as part of this research work and develops, more particularly, the role of water in the material submitted to heating up to high temperatures. At first, we are interested in the role of water inside a material crack, during heating. We have established an original analytical solution giving the liquid-vapour repartition and the stress intensity factor, as functions of crack's length, water molecules contained in the inner of the crack and temperature. Then, we are able to study the crack stability. In the second part, we propose to approach the studied phenomena using the non saturated porous media theory. We present a thermo-hydro-chemical model which permits to describe the concrete behaviour under thermal loading. The material microstructure is defined using a 'porosimetric surface'. Each pore is characterised by two radii: the pore radius and the access radius into the pore. With this description, the zone of pores saturated by liquid is a state variable. We also introduce the concept of kinetic dehydration, clearly lighted by experimental studies. An hypothesis of erosion of the solid phase by dehydration permits to link the evolution of microstructure and of the zone of pores saturated by liquid to the mass of water created by dehydration. (author)

Peltier Effect Based Temperature Controlled System for Dielectric Spectroscopy

Science.gov (United States)

Mukda, T.; Jantaratana, P.

2017-09-01

The temperature control system was designed and built for application in dielectric spectroscopy. It is based on the dual-stage Peltier element that decreases electrical power and no cryogenic fluids are required. A proportional integral derivative controller was used to keep the temperature stability of the system. A Pt100 temperature sensor was used to measure temperature of the sample mounting stage. Effect of vacuum isolation and water-cooling on accuracy and stability of the system were also studied. With the incorporation of vacuum isolation and water-cooling at 18 °C, the temperature of the sample under test can be controlled in the range of -40 °C to 150 °C with temperature stability ± 0.025 °C.

Biological stability of drinking water : Controlling factors, methods, and challenges

NARCIS (Netherlands)

Prest, E.I.E.D.; Hammes, F.; Van Loosdrecht, M.C.M.; Vrouwenvelder, J.S.

2016-01-01

Biological stability of drinking water refers to the concept of providing consumers with drinking water of same microbial quality at the tap as produced at the water treatment facility. However, uncontrolled growth of bacteria can occur during distribution in water mains and premise plumbing, and

Preparation and Application of Water-in-Oil Emulsions Stabilized by Modified Graphene Oxide

Directory of Open Access Journals (Sweden)

Xiaoma Fei

2016-08-01

Full Text Available A series of alkyl chain modified graphene oxides (AmGO with different alkyl chain length and content was fabricated using a reducing reaction between graphene oxide (GO and alkyl amine. Then AmGO was used as a graphene-based particle emulsifier to stabilize Pickering emulsion. Compared with the emulsion stabilized by GO, which was oil-in-water type, all the emulsions stabilized by AmGO were water-in-oil type. The effects of alkyl chain length and alkyl chain content on the emulsion properties of AmGO were investigated. The emulsions stabilized by AmGO showed good stability within a wide range of pH (from pH = 1 to pH = 13 and salt concentrations (from 0.1 to 1000 mM. In addition, the application of water-in-oil emulsions stabilized by AmGO was investigated. AmGO/polyaniline nanocomposite (AmGO/PANi was prepared through an emulsion approach, and its supercapacitor performance was investigated. This research broadens the application of AmGO as a water-in-oil type emulsion stabilizer and in preparing graphene-based functional materials.

21 CFR 880.5560 - Temperature regulated water mattress.

Science.gov (United States)

2010-04-01

... 21 Food and Drugs 8 2010-04-01 2010-04-01 false Temperature regulated water mattress. 880.5560... Therapeutic Devices § 880.5560 Temperature regulated water mattress. (a) Identification. A temperature regulated water mattress is a device intended for medical purposes that consists of a mattress of suitable...

Water temperature issues in the 90's and beyond

International Nuclear Information System (INIS)

Railsback, S.F.

1993-01-01

Water temperature issues are expected to receive increasing attention in the 1990s. Temperature impacts are among the most common and most expensive environmental issues requiring mitigation at water projects, but few changes in mitigation technologies and little research have occurred in the past decade. Water projects alter water temperatures because the heat balances in reservoirs and in streams with altered flows are significantly different from natural. Several emerging environmental and regulatory concerns and issues are likely to focus additional attention on temperature. Climate change, should it occur as predicted, can be expected to worsen many water temperature problems and complicate the determination of appropriate mitigation for water projects. The purposes of this paper are to review current water temperature issues and mitigation methods, to identify new and future temperature issues, and to identify research needs

Intensity and frequency stabilization of a laser diode by simultaneously controlling its temperature and current

Science.gov (United States)

Mu, Weiwei; Hu, Zhaohui; Wang, Jing; Zhou, Binquan

2017-10-01

Nuclear magnetic resonance gyroscope (NMRG) detects the angular velocity of the vehicle utilizing the interaction between the laser beam and the alkali metal atoms along with the noble gas atoms in the alkali vapor cell. In order to reach high precision inertial measurement target, semiconductor laser in NMRG should have good intensity and frequency stability. Generally, laser intensity and frequency are stabilized separately. In this paper, a new method to stabilize laser intensity and frequency simultaneously with double-loop feedback control is presented. Laser intensity is stabilized to the setpoint value by feedback control of laser diode's temperature. Laser frequency is stabilized to the Doppler absorption peak by feedback control of laser diode's current. The feedback control of current is a quick loop, hence the laser frequency stabilize quickly. The feedback control of temperature is a slow loop, hence the laser intensity stabilize slowly. With the feedback control of current and temperature, the laser intensity and frequency are stabilized finally. Additionally, the dependence of laser intensity and frequency on laser diode's current and temperature are analyzed, which contributes to choose suitable operating range for the laser diode. The advantage of our method is that the alkali vapor cell used for stabilizing laser frequency is the same one as the cell used for NMRG to operate, which helps to miniaturize the size of NMRG prototype. In an 8-hour continuous measurement, the long-term stability of laser intensity and frequency increased by two orders of magnitude and one order of magnitude respectively.

Experiences in stability testing of boiling water reactors

International Nuclear Information System (INIS)

March-Leuba, J.; Otaduy, P.J.

1986-01-01

The purpose of this paper is to summarize experiences with boiling water reactor (BWR) stability testing using noise analysis techniques. These techniques have been studied over an extended period of time, but it has been only recently that they have been well established and generally accepted. This paper contains first a review of the problem of BWR neutronic stability, focusing on its physical causes and its effects on reactor operation. The paper also describes the main techniques used to quantify, from noise measurements, the reactor's stability in terms of a decay ratio. Finally, the main results and experiences obtained from the stability tests performed at the Dresden and the Browns Ferry reactors using noise analysis techniques are summarized

Integrated collector storage solar water heater: Temperature stratification

International Nuclear Information System (INIS)

Garnier, C.; Currie, J.; Muneer, T.

2009-01-01

An analysis of the temperature stratification inside an Integrated Collector Storage Solar Water Heater (ICS-SWH) was carried out. The system takes the form of a rectangular-shaped box incorporating the solar collector and storage tank into a single unit and was optimised for simulation in Scottish weather conditions. A 3-month experimental study on the ICS-SWH was undertaken in order to provide empirical data for comparison with the computed results. Using a previously developed macro model; a number of improvements were made. The initial macro model was able to generate corresponding water bulk temperature in the collector with a given hourly incident solar radiation, ambient temperature and inlet water temperature and therefore able to predict ICS-SWH performance. The new model was able to compute the bulk water temperature variation in different SWH collectors for a given aspect ratio and the water temperature along the height of the collector (temperature stratification). Computed longitudinal temperature stratification results obtained were found to be in close agreement with the experimental data.

Experimental investigation of the stability of the floating water bridge

Science.gov (United States)

Montazeri Namin, Reza; Azizpour Lindi, Shiva; Amjadi, Ahmad; Jafari, Nima; Irajizad, Peyman

2013-09-01

When a high voltage is applied between two beakers filled with deionized water, a floating bridge of water is formed in between exceeding the length of 2 cm when the beakers are pulled apart. Currently two theories regarding the stability of the floating water bridge exist, one suggesting that the tension caused by electric field in the dielectric medium is holding the bridge and the other suggesting surface tension to be responsible for the vertical equilibrium. We construct experiments in which the electric field and the geometry of the bridge are measured and compared with predictions of theories of the floating water bridge stability. We use a numerical simulation for estimation of the electric field. Our results indicate that the two forces of dielectric and surface tensions hold the bridge against gravity simultaneously and, having the same order of magnitude, neither of the two forces are negligible. In bridges with larger diameters, the effect of dielectric tension is slightly more in the vertical equilibrium than surface tension. Results show that the stability can be explained by macroscopic forces, regardless of the microscopic changes in the water structure.

High-temperature stability of the hydrate shell of a Na+ cation in a flat nanopore with hydrophobic walls

Science.gov (United States)

Shevkunov, S. V.

2017-11-01

The effect of elevated temperature has on the hydrate shell of a singly charged sodium cation inside a flat nanopore with smooth walls is studied using the Monte Carlo method. The free energy and the entropy of vapor molecule attachment are calculated by means of a bicanonical statistical ensemble using a detailed model of interactions. The nanopore has a stabilizing effect on the hydrate shell with respect to fluctuations and a destabilizing effect with respect to complete evaporation. At the boiling point of water, behavior is observed that is qualitatively similar to behavior at room temperature, but with a substantial shift in the vapor pressure and shell size.

Biological stability in drinking water distribution systems : A novel approach for systematic microbial water quality monitoring

NARCIS (Netherlands)

Prest, E.I.E.D.

2015-01-01

Challenges to achieve biological stability in drinking water distribution systems Drinking water is distributed from the treatment facility to consumers through extended man-made piping systems. The World Health Organization drinking water guidelines (2006) stated that “Water entering the

Porosity and water activity effects on stability of crystalline β-carotene in freeze-dried solids.

Science.gov (United States)

Harnkarnsujarit, Nathdanai; Charoenrein, Sanguansri; Roos, Yrjö H

2012-11-01

Stability of entrapped crystalline β-carotene as affected by water activity, solids microstructure, and composition of freeze-dried systems was investigated. Aliquots (1000 mm(3) , 20% w/w solids) of solutions of maltodextrins of various dextrose equivalents (M040:DE6, M100:DE11, and M250:DE25.5), M100-sugars (1:1 glucose, fructose and sucrose), and agar for gelation with dispersed β-carotene were frozen at -20, -40, or -80 °C and freeze-dried. Glass transition and α-relaxation temperatures were determined with differential scanning calorimetry and dynamic mechanical analysis, respectively. β-Carotene contents were monitored spectrophotometrically. In the glassy solids, pore microstructure had a major effect on β-carotene stability. Small pores with thin walls and large surface area allowed β-carotene exposure to oxygen which led to a higher loss, whereas structural collapse enhanced stability of β-carotene by decreasing exposure to oxygen. As water plasticized matrices, an increase in molecular mobility in the matrix enhanced β-carotene degradation. Stability of dispersed β-carotene was highest at around 0.2 a(w) , but decreasing structural relaxation times above the glass transition correlated well with the rate of β-carotene degradation at higher a(w) . Microstructure, a(w) , and component mobility are important factors in the control of stability of β-carotene in freeze-dried solids. β-Carotene expresses various nutritional benefits; however, it is sensitive to oxygen and the degradation contributes to loss of nutritional values as well as product color. To increase stability of β-carotene in freeze-dried foods, the amount of oxygen penetration need to be limited. The modification of freeze-dried food structures, for example, porosity and structural collapse, components, and humidity effectively enhance the stability of dispersed β-carotene in freeze-dried solids. © 2012 Institute of Food Technologists®

Dihydrogen Phosphate Stabilized Ruthenium(0 Nanoparticles: Efficient Nanocatalyst for The Hydrolysis of Ammonia-Borane at Room Temperature

Directory of Open Access Journals (Sweden)

Feyyaz Durap

2015-07-01

Full Text Available Intensive efforts have been devoted to the development of new materials for safe and efficient hydrogen storage. Among them, ammonia-borane appears to be a promising candidate due to its high gravimetric hydrogen storage capacity. Ammonia-borane can release hydrogen on hydrolysis in aqueous solution under mild conditions in the presence of a suitable catalyst. Herein, we report the synthesis of ruthenium(0 nanoparticles stabilized by dihydrogenphosphate anions with an average particle size of 2.9 ± 0.9 nm acting as a water-dispersible nanocatalyst in the hydrolysis of ammonia-borane. They provide an initial turnover frequency (TOF value of 80 min−1 in hydrogen generation from the hydrolysis of ammonia-borane at room temperature. Moreover, the high stability of these ruthenium(0 nanoparticles makes them long-lived and reusable nanocatalysts for the hydrolysis of ammonia-borane. They provide 56,800 total turnovers and retain ~80% of their initial activity even at the fifth catalytic run in the hydrolysis of ammonia-borane at room temperature.

Dihydrogen Phosphate Stabilized Ruthenium(0) Nanoparticles: Efficient Nanocatalyst for The Hydrolysis of Ammonia-Borane at Room Temperature

Science.gov (United States)

Durap, Feyyaz; Caliskan, Salim; Özkar, Saim; Karakas, Kadir; Zahmakiran, Mehmet

2015-01-01

Intensive efforts have been devoted to the development of new materials for safe and efficient hydrogen storage. Among them, ammonia-borane appears to be a promising candidate due to its high gravimetric hydrogen storage capacity. Ammonia-borane can release hydrogen on hydrolysis in aqueous solution under mild conditions in the presence of a suitable catalyst. Herein, we report the synthesis of ruthenium(0) nanoparticles stabilized by dihydrogenphosphate anions with an average particle size of 2.9 ± 0.9 nm acting as a water-dispersible nanocatalyst in the hydrolysis of ammonia-borane. They provide an initial turnover frequency (TOF) value of 80 min−1 in hydrogen generation from the hydrolysis of ammonia-borane at room temperature. Moreover, the high stability of these ruthenium(0) nanoparticles makes them long-lived and reusable nanocatalysts for the hydrolysis of ammonia-borane. They provide 56,800 total turnovers and retain ~80% of their initial activity even at the fifth catalytic run in the hydrolysis of ammonia-borane at room temperature. PMID:28793435

Influence of Flow Regulation on Summer Water Temperature: Sauce Grande River, Argentina

Science.gov (United States)

Casado, A.; Hannah, D. M.; Peiry, J.; Campo, A. M.

2012-12-01

This study quantifies the effects of the Paso de las Piedras Dam on the thermal behaviour of the Sauce Grande River, Argentina, during a summer season. A 30-day data set of continuous hourly data was assembled for eight stream temperature gauging sites deployed above and below the impoundment. Time series span the hottest period recorded during summer 2009 to evaluate variations in river water temperature under strong meteorological influence. The methods include: (i) analysis of the time series by inspecting the absolute differences in daily data (magnitude, timing, frequency, duration and rate of change), (ii) classification of diurnal regimes by using a novel regime 'shape' and 'magnitude' classifying method (RSMC), and (ii) quantification of the sensitivity of water temperature regimes to air temperature by computation of a novel sensitivity index (SI). Results showed that fluctuations in daily water temperatures were linked to meteorological drivers; however, spatial variability in the shape and the magnitude of the thermographs revealed the effects of the impoundment in regulating the thermal behaviour of the river downstream. An immediate cooling effect below the dam was evident. Mean daily temperatures were reduced in up to 4 °C, and described a warming trend in the downstream direction over a distance of at least 15 km (up to +2.3 °C). Diurnal cycles were reduced in amplitude and delayed in timing, and revealed a dominance of regime magnitude stability and regime shape climatic insensitivity over a distance of 8 km downstream. These findings provide new information about the water quality of the Sauce Grande River and inform management of flows to maintain the ecological integrity of the river system. Also, they motivate further analysis of potential correlates under varying hydrological and meteorological conditions. The methods presented herein have wider applicability for quantifying river thermal regimes and their sensitivity to climate and other

Statistical evaluation of accelerated stability data obtained at a single temperature. I. Effect of experimental errors in evaluation of stability data obtained.

Science.gov (United States)

Yoshioka, S; Aso, Y; Takeda, Y

1990-06-01

Accelerated stability data obtained at a single temperature is statistically evaluated, and the utility of such data for assessment of stability is discussed focussing on the chemical stability of solution-state dosage forms. The probability that the drug content of a product is observed to be within the lower specification limit in the accelerated test is interpreted graphically. This probability depends on experimental errors in the assay and temperature control, as well as the true degradation rate and activation energy. Therefore, the observation that the drug content meets the specification in the accelerated testing can provide only limited information on the shelf-life of the drug, without the knowledge of the activation energy and the accuracy and precision of the assay and temperature control.

Temperature stability limits for an isothermal demagnetization refrigerator

Science.gov (United States)

Kittel, P.

1984-01-01

It is pointed out that magnetic refrigeration can provide additional cooling for infrared detectors on space missions, taking into account the Shuttle Infrared Telescope Facility (SIRTF) and the Large Deployable Reflector (LDR). From a temperature of 2 K provided by the primary cryogens, magnetic refrigerators could cool bolometers or pumped photoconductors to 0.1 K or below. Such a reduction in operating temperature would increase the sensitivity for bolometers, while the response at longer wavelengths for pumped photoconductors would be improved. Two types of magnetic refrigeration cycles have been proposed. One type uses a complete demagnetization. The present investigation is concerned with the second type, which uses a feedback-controlled isothermal demagnetization, taking into account the temperature stability limits. Attention is given to control system resolution, thermometer noise, reaction time, and thermal time constants.

Stability of cannabinoids in urine in three storage temperatures.

Science.gov (United States)

Golding Fraga, S; Díaz-Flores Estévez, J; Díaz Romero, C

1998-01-01

Stability of cannabinoid compounds in urine samples were evaluated using several storage temperatures. Appreciable losses (> 22.4 percent) were observed in some urine samples, after being stored at room temperature for 10 days. Lower losses (8.1 percent) were observed when the urine samples were refrigerated for 4 weeks. The behavior of urine samples depended on the analyzed urine. This could be due to the different stability of the cannabinoids present in each urine sample. Important losses of 8.0 +/- 10.6, 15.8 +/- 4.2, and 19.6 +/- 6.7 percent were found when the urine samples were frozen during 40 days, 1 year, and 3 years, respectively. Average losses (> > 5 percent) can be observed after one day which could mainly be due to the decrease of the solubility of 11-nor-U9-tetrahydrocannabinol-9-carboxylic acid (THC-COOH) or adsorption process of cannabinoid molecules to the plastic storage containers.

The Influence of pH and Temperature on the Stability of N-[(Piperidinemethylene]daunorubicin Hydrochloride and a Comparison of the Stability of Daunorubicin and Its Four New Amidine Derivatives in Aqueous Solutions

Directory of Open Access Journals (Sweden)

Mikołaj Piekarski

2014-01-01

Full Text Available The influence of pH and temperature on the stability of N-[(piperidinemethylene]daunorubicin hydrochloride (PPD was investigated. Degradation was studied using an HPLC method. Specific acid-base catalysis of PPD involves hydrolysis of protonated molecules of PPD catalyzed by hydrogen ions and spontaneous hydrolysis under the influence of water zwitterions, unprotonated molecules, and monoanions of PPD. The thermodynamic parameters of these reactions, energy, enthalpy, and entropy, were calculated. Also, the stability of daunorubicin and its new amidine derivatives (piperidine, morpholine, pyrrolidine, and hexahydroazepin-1-yl in aqueous solutions was compared and discussed.

46 CFR 178.340 - Stability standards for pontoon vessels on protected waters.

Science.gov (United States)

2010-10-01

... 46 Shipping 7 2010-10-01 2010-10-01 false Stability standards for pontoon vessels on protected waters. 178.340 Section 178.340 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) SMALL....340 Stability standards for pontoon vessels on protected waters. (a) The portion of the deck...

Manufacture and evaluation of integrated metal-oxide electrode prototype for corrosion monitoring in high temperature water

International Nuclear Information System (INIS)

Hashimoto, Yoshinori; Tani, Jun-ichi

2014-01-01

We have developed an integrated metal-oxide (M/O) electrode based on an yttria-stabilized-zirconia-(YSZ)-membrane M/O electrode, which was used as a reference electrode for corrosion monitoring in high temperature water. The YSZ-membrane M/O electrode can operate at high temperatures because of the conductivity of YSZ membrane tube. We cannot utilize it for long term monitoring at a wide range of temperatures. It also has a braze juncture between the YSZ membrane and metal tubes, which may corrode in high-temperature water. This corrosion should be prevented to improve the performance of the M/O electrode. An integrated M/O electrode was developed (i.e., integrated metal-oxide electrode, IMOE) to eliminate the braze juncture and increase the conductivity of YSZ. These issues should be overcome to improve the performance of M/O electrode. So we have developed two type of IMOE prototype with sputter - deposition or thermal oxidation. In this paper we will present and discuss the performance of our IMOEs in buffer solution at room temperature. (author)

Extreme temperature stability of thermally insulating graphene-mesoporous-silicon nanocomposite

Science.gov (United States)

Kolhatkar, Gitanjali; Boucherif, Abderraouf; Rahim Boucherif, Abderrahim; Dupuy, Arthur; Fréchette, Luc G.; Arès, Richard; Ruediger, Andreas

2018-04-01

We demonstrate the thermal stability and thermal insulation of graphene-mesoporous-silicon nanocomposites (GPSNC). By comparing the morphology of GPSNC carbonized at 650 °C as-formed to that after annealing, we show that this nanocomposite remains stable at temperatures as high as 1050 °C due to the presence of a few monolayers of graphene coating on the pore walls. This does not only make this material compatible with most thermal processes but also suggests applications in harsh high temperature environments. The thermal conductivity of GPSNCs carbonized at temperatures in the 500 °C-800 °C range is determined through Raman spectroscopy measurements. They indicate that the thermal conductivity of the composite is lower than that of silicon, with a value of 13 ± 1 W mK-1 at room temperature, and not affected by the thin graphene layer, suggesting a role of the high concentration of carbon related-defects as indicated by the high intensity of the D-band compared to G-band of the Raman spectra. This morphological stability at high temperature combined with a high thermal insulation make GPSNC a promising candidate for a broad range of applications including microelectromechanical systems and thermal effect microsystems such as flow sensors or IR detectors. Finally, at 120 °C, the thermal conductivity remains equal to that at room temperature, attesting to the potential of using our nanocomposite in devices that operate at high temperatures such as microreactors for distributed chemical conversion, solid oxide fuel cells, thermoelectric devices or thermal micromotors.

Historical Change of Equilibrium Water Temperature in Japan

Science.gov (United States)

Miyamoto, H.

2015-12-01

Changes in freshwater ecosystems due to a climate change have been great concern for sustainable river basin management both for water resources utilization and ecological conservation. However, their impact seems to be difficult to evaluate because of wide variety of basin characteristics along a river network both in nature and social environment. This presentation uses equilibrium water temperature as a simple criterion index for evaluating the long-term changes of stream thermal environment due to the historical climate change in Japan. It examines, at first, the relationship between the equilibrium water temperature and the stream temperature observed for 7 years at a lower reach in the Ibo River, Japan. It analyzes, then, the seasonal and regional trends of the equilibrium water temperature change for the last 50 years at 133 meteorological station sites throughout Japan, discussing their rising or falling characteristics. The correlation analysis at the local reach of the Ibo River shows that the equilibrium water temperature has similar trend of change as the stream temperature. However, its value tends to be higher than the stream temperature in summer, while lower in winter. The onset of the higher equilibrium water temperature fluctuates annually from mid February to early April. This onset fluctuation at each spring could be influenced by the different amount of snow at the antecedent winter. The rising or falling trends of the equilibrium water temperature are analyzed both annually and seasonally through the regression analysis of the 133 sites in Japan. Consequently, the trends of the temperature change could be categorized by 12 patterns. As for the seasonal analysis, the results shows that there are many sites indicating the falling trend in spring and summer, and rising trends in autumn and winter. In particular, winter has the strong rising tendency throughout Japan. As for the regional analysis, the result illustrates the precise rationality; e

Nano-silver in drinking water and drinking water sources: stability and influences on disinfection by-product formation.

Science.gov (United States)

Tugulea, A-M; Bérubé, D; Giddings, M; Lemieux, F; Hnatiw, J; Priem, J; Avramescu, M-L

2014-10-01

Nano-silver is increasingly used in consumer products from washing machines and refrigerators to devices marketed for the disinfection of drinking water or recreational water. The nano-silver in these products may be released, ending up in surface water bodies which may be used as drinking water sources. Little information is available about the stability of the nano-silver in sources of drinking water, its fate during drinking water disinfection processes, and its interaction with disinfection agents and disinfection by-products (DBPs). This study aims to investigate the stability of nano-silver in drinking water sources and in the finished drinking water when chlorine and chloramines are used for disinfection and to observe changes in the composition of DBPs formed when nano-silver is present in the source water. A dispersion of nano-silver particles (10 nm; PVP-coated) was used to spike untreated Ottawa River water, treated Ottawa River water, organic-free water, and a groundwater at concentrations of 5 mg/L. The diluted dispersions were kept under stirred and non-stirred conditions for up to 9 months and analyzed weekly using UV absorption to assess the stability of the nano-silver particles. In a separate experiment, Ottawa River water containing nano-silver particles (at 0.1 and 1 mg/L concentration, respectively) was disinfected by adding sodium hypochlorite (a chlorinating agent) in sufficient amounts to maintain a free chlorine residual of approximately 0.4 mg/L after 24 h. The disinfected drinking water was then quenched with ascorbic acid and analyzed for 34 neutral DBPs (trihalomethanes, haloacetonitriles, haloacetaldehydes, 1,1 dichloro-2-propanone, 1,1,1 trichloro-2-propanone, chloropicrin, and cyanogen chloride). The results were compared to the profile of DBPs obtained under the same conditions in the absence of nano-silver and in the presence of an equivalent concentration of Ag(+) ions (as AgNO3). The stability of the nano-silver dispersions in

Low-Temperature Bainite: A Thermal Stability Study

Science.gov (United States)

Santajuana, Miguel A.; Rementeria, Rosalia; Kuntz, Matthias; Jimenez, Jose A.; Caballero, Francisca G.; Garcia-Mateo, Carlos

2018-06-01

The thermal stability of nanobainitic structures obtained by heat treating two different high-carbon high-silicon steels at temperatures between 200 °C and 600 °C has been investigated by means of three complementary techniques, i.e., field emission gun-scanning electron microscopy, X-ray diffraction, and high-resolution dilatometry. Three main stages have been established, each of them characterized by a distinctive microstructure. Furthermore, the nanocrystalline structure generated by the bainite reaction confers the steel with an extraordinary tempering resistance.

Decisive role of nuclear quantum effects on surface mediated water dissociation at finite temperature

Science.gov (United States)

Litman, Yair; Donadio, Davide; Ceriotti, Michele; Rossi, Mariana

2018-03-01

Water molecules adsorbed on inorganic substrates play an important role in several technological applications. In the presence of light atoms in adsorbates, nuclear quantum effects (NQEs) influence the structural stability and the dynamical properties of these systems. In this work, we explore the impact of NQEs on the dissociation of water wires on stepped Pt(221) surfaces. By performing ab initio molecular dynamics simulations with van der Waals corrected density functional theory, we note that several competing minima for both intact and dissociated structures are accessible at finite temperatures, making it important to assess whether harmonic estimates of the quantum free energy are sufficient to determine the relative stability of the different states. We thus perform ab initio path integral molecular dynamics (PIMD) in order to calculate these contributions taking into account the conformational entropy and anharmonicities at finite temperatures. We propose that when adsorption is weak and NQEs on the substrate are negligible, PIMD simulations can be performed through a simple partition of the system, resulting in considerable computational savings. We then calculate the full contribution of NQEs to the free energies, including also anharmonic terms. We find that they result in an increase of up to 20% of the quantum contribution to the dissociation free energy compared with the harmonic estimates. We also find that the dissociation process has a negligible contribution from tunneling but is dominated by zero point energies, which can enhance the rate of dissociation by three orders of magnitude. Finally we highlight how both temperature and NQEs indirectly impact dipoles and the redistribution of electron density, causing work function changes of up to 0.4 eV with respect to static estimates. This quantitative determination of the change in the work function provides a possible approach to determine experimentally the most stable configurations of water

High temperature pressure water's blowdown into water. Experimental results

International Nuclear Information System (INIS)

Ishida, Toshihisa; Kusunoki, Tsuyoshi; Kasahara, Yoshiyuki; Iida, Hiromasa

1994-01-01

The purpose of the present experimental study is to clarify the phenomena in blowdown of high temperature and pressure water in pressure vessel into the containment water for evaluation of design of an advanced marine reactor(MRX). The water blown into the containment water flushed and formed steam jet plume. The steam jet condensed in the water, but some stream penetrated to gas phase of containment and contributed to increase of containment pressure. (author)

Global temperature stability by rule induction: An interdisciplinary bridge

International Nuclear Information System (INIS)

Gunn, J.D.; Grzymala-Busse, J.W.

1994-01-01

Rules incorporating influences on global temperature, an estimate of radiation balance, were induced from astronomical, geophysical, and anthropogenic variables. During periods of intermediate global temperatures (generally like the present century), the influences assume canceling roles; influences cancel the effects of extreme states potentially imposed by other influences because they are, in aggregate, most likely to be assuming opposite values. This imparts an overall stability to the global temperature. To achieve cold or hot global temperature, influences assume reinforcing roles. CO 2 is an active influence on global temperature. By virtue of its constancy in the atmosphere, it can be expected to sponsor frequent hot years in combination with the other influences as they cycle through their periods. If measures were implemented to maintain warm or cool global temperatures, it could retain the status quo of present global agricultural regions. They are probably more productive than hot world regions would be because of narrow storm tracks

Strontium Zirconate TBC Sprayed by a High Feed-Rate Water-Stabilized Plasma Torch

Science.gov (United States)

Ctibor, P.; Nevrla, B.; Cizek, J.; Lukac, F.

2017-12-01

A novel thermal barrier coating (TBC) material, strontium zirconate SrZrO3, was sprayed by a high feed-rate water-stabilized plasma torch WSP 500. Stainless steel coupons were used as substrates. Coatings with a thickness of about 1.2 mm were produced, whereas the substrates were preheated over 450 °C. The torch worked at 150 kW power and was able to spray SrZrO3 with a high spray rate over 10 kg per hour. Microstructure and microhardness, phase composition, adhesion, thermal conductivity and thermal expansion were evaluated. The coating has low thermal conductivity under 1 W/m K in the interval from room temperature up to 1200 °C. Its crystallite size is slightly over 400 nm and thermal expansion 12.3 µm K-1 in the similar temperature range.

Performance on Water Stability of Cement-Foamed Asphalt Cold Recycled Mixture

Directory of Open Access Journals (Sweden)

Li Junxiao

2018-01-01

Full Text Available Through designing the mixture proportion of foamed asphalt cold in-place recycled mixture combined with the water stability experiment, it shows that the addition of cement can obviously improve foamed asphalt mixture’s water stability and the best cement admixture is between 1% ~ 2%; Using digital imaging microscope and SEM technology, the mechanism of increasing on the intensity of foamed asphalt mixture resulted by adding cement was analyzed. It revealed that the cement hydration products contained in the foamed asphalt mixture hydrolyzed into space mesh structure and wrapped up the aggregate particle, this is the main reason that the cement can enhance the mixture’s intensity as well as the water stability. This research provides reference for cement admixture’s formulation in the designing of foamed asphalt cold in-place recycled mixture.

Hydraulic loading, stability and water quality of Nakivubo wetland ...

African Journals Online (AJOL)

Nakivubo wetland, which has performed tertiary water treatment for Kampala city for the past 40 years, is ecologically stressed by agricultural and infrastructural developments. Field studies were carried out to assess the hydraulic loading, pollution profile, stability and water quality of this wetland. The upper and lower ...

SCC Initiation Testing of Alloy 600 in High Temperature Water

Science.gov (United States)

Etien, Robert A.; Richey, Edward; Morton, David S.; Eager, Julie

Stress corrosion cracking (SCC) initiation tests have been conducted on Alloy 600 at temperatures from 304 to 367°C. Tests were conducted with in-situ monitored smooth tensile specimens under a constant load in hydrogenated environments. A reversing direct current electric potential drop (EPD) system was used for all of the tests to detect SCC initiation. Tests were conducted to examine the effects of stress (and strain), coolant hydrogen, and temperature on SCC initiation time. The thermal activation energy of SCC initiation was measured as 103 ± 18 kJ/mol in hydrogenated water, which is similar to the thermal activation energy for SCC growth. Results suggest that the fundamental mechanical parameter which controls SCC initiation is plastic strain not stress. SCC initiation was shown to have a different sensitivity than SCC growth to dissolved hydrogen level. Specifically, SCC initiation time appears to be relatively insensitive to hydrogen level in the nickel stability region.

Density Gradient Stabilization of Electron Temperature Gradient Driven Turbulence in a Spherical Tokamak

International Nuclear Information System (INIS)

Ren, Y.; Kaye, S.M.; Mazzucato, E.; Guttenfelder, W.; Bell, R.E.; Domier, C.W.; LeBlanc, B.P.; Lee, K.C.; Luhmann, N.C. Jr.; Smith, D.R.; Yuh, H.

2011-01-01

In this letter we report the first clear experimental observation of density gradient stabilization of electron temperature gradient driven turbulence in a fusion plasma. It is observed that longer wavelength modes, k (perpendicular) ρ s ∼< 10, are most stabilized by density gradient, and the stabilization is accompanied by about a factor of two decrease in the plasma effective thermal diffusivity.

Magnetic fluids stabilized by polypropylene glycol

Energy Technology Data Exchange (ETDEWEB)

Lebedev, A.V., E-mail: lav@icmm.r [Institute of Continuous Media Mechanics, UB RAS, Academic Korolev Str. 1, Perm 614013 (Russian Federation); Lysenko, S.N. [Institute of Technical Chemistry, UB RAS, Academic Korolev Str. 3, Perm 614013 (Russian Federation)

2011-05-15

A series of samples of magnetic fluids stabilized with low-molecular weight polypropylene glycol (PPG) of different molecular masses were synthesized. The use of PPG allowed the maximum extension of the carrier fluid range to include ethyl- and butyl-acetate, ethanol, butanol, acetone, carbon tetrachloride, toluene, kerosene and PPG itself. Magnetic and rheological properties of the samples were investigated. Based on the results of investigation it has been concluded that magnetic nanoparticles are covered by a monolayer of surfactant molecules. At low temperatures the propanol-based sample preserves fluidity up to -115 {sup o}C. Measurement of critical temperatures of other base fluids showed that alcohols are the best carrier medium. Coagulation stability of the ethanol-based ferrocolloid with respect to water and kerosene was explored. It has been found that kerosene, whose fraction by weight exceeds 22.5%, does not mix with the colloid. This effect can be used to produce magneto-controllable extractors of ethyl alcohol. Under the action of water the colloid coagulates, which allows one to substitute the carrier fluid and to separate the colloid into fractions. - Research highlights: PPG stabilizes the magnetic particles in the polar and non-polar media. The minimum operating temperature reaches -115 {sup o}C. Alcohols are the best environment for PPG-stabilized particles. PPG magnetic fluids can be used as magnetic extractors of alcohol. PPG MF can be divided into fractions by partial coagulation with water.

Effects of temperature distribution on boundary layer stability for a circular cone at Mach 10

Science.gov (United States)

Rigney, Jeffrey M.

A CFD analysis was conducted on a circular cone at 3 degrees angle of attack at Mach 10 using US3D and STABL 3D to determine the effect of wall temperature on the stability characteristics that lead to laminar-to-turbulent transition. Wall temperature distributions were manipulated while all other flow inputs and geometric qualities were held constant. Laminar-to-turbulent transition was analyzed for isothermal and adiabatic wall conditions, a simulated short-duration wind tunnel case, and several hot-nose temperature distributions. For this study, stability characteristics include maximum N-factor growth and the corresponding frequency range, disturbance spatial amplification rate and the corresponding modal frequency, and stability neutral point location. STABL 3D analysis indicates that temperature distributions typical of those in short-duration hypersonic wind tunnels do not result in any significant difference on the stability characteristics, as compared to an isothermal wall boundary condition. Hypothetical distributions of much greater temperatures at and past the nose tip do show a trend of dampening of second-mode disturbances, most notably on the leeward ray. The most pronounced differences existed between the isothermal and adiabatic cases.

Studies of the corrosion and cracking behavior of steels in high temperature water by electrochemical techniques

International Nuclear Information System (INIS)

Cheng, Y.F.; Bullerwell, J.; Steward, F.R.

2003-01-01

Electrochemical methods were used to study the corrosion and cracking behavior of five Fe-Cr alloy steels and 304L stainless steel in high temperature water. A layer of magnetite film forms on the metal surface, which decreases the corrosion rate in high temperature water. Passivity can be achieved on A-106 B carbon steel with a small content of chromium, which cannot be passivated at room temperature. The formation rate and the stability of the passive film (magnetite film) increased with increasing Cr-content in the steels. A mechanistic model was developed to simulate the corrosion and cracking processes of steels in high temperature water. The crack growth rate on steels was calculated from the maximum current of the repassivation current curves according to the slip-oxidation model. The highest crack growth rate was found for 304L stainless steel in high temperature water. Of the four Fe-Cr alloys, the crack growth rate was lower on 0.236% Cr- and 0.33% Cr-steels than on 0.406% Cr-steel and 2.5% Cr-1% Mo steel. The crack growth rate on 0.33% Cr-steel was the smallest over the tested potential range. A higher temperature of the electrolyte led to a higher rate of electrochemical dissolution of steel and a higher susceptibility of steel to cracking, as shown by the positive increase of the electrochemical potential. An increase in Cr-content in the steel is predicted to reduce the corrosion rate of steel at high temperatures. However, this increase in Cr-content is predicted not to reduce the susceptibility of steel to cracking at high temperatures. (author)

Water-Mediated Photochemical Treatments for Low-Temperature Passivation of Metal-Oxide Thin-Film Transistors.

Science.gov (United States)

Heo, Jae Sang; Jo, Jeong-Wan; Kang, Jingu; Jeong, Chan-Yong; Jeong, Hu Young; Kim, Sung Kyu; Kim, Kwanpyo; Kwon, Hyuck-In; Kim, Jaekyun; Kim, Yong-Hoon; Kim, Myung-Gil; Park, Sung Kyu

2016-04-27

The low-temperature electrical passivation of an amorphous oxide semiconductor (AOS) thin-film transistor (TFT) is achieved by a deep ultraviolet (DUV) light irradiation-water treatment-DUV irradiation (DWD) method. The water treatment of the first DUV-annealed amorphous indium-gallium-zinc-oxide (a-IGZO) thin film is likely to induce the preferred adsorption of water molecules at the oxygen vacancies and leads to subsequent hydroxide formation in the bulk a-IGZO films. Although the water treatment initially degraded the electrical performance of the a-IGZO TFTs, the second DUV irradiation on the water-treated devices may enable a more complete metal-oxygen-metal lattice formation while maintaining low oxygen vacancies in the oxide films. Overall, the stable and dense metal-oxygen-metal (M-O-M) network formation could be easily achieved at low temperatures (below 150 °C). The successful passivation of structural imperfections in the a-IGZO TFTs, such as hydroxyl group (OH-) and oxygen vacancies, mainly results in the enhanced electrical performances of the DWD-processed a-IGZO TFTs (on/off current ratio of 8.65 × 10(9), subthreshold slope of 0.16 V/decade, an average mobility of >6.94 cm(2) V(-1) s(-1), and a bias stability of ΔVTH IGZO TFTs.

Phase Stability Diagrams for High Temperature Corrosion Processes

Directory of Open Access Journals (Sweden)

J. J. Ramos-Hernandez

2013-01-01

Full Text Available Corrosion phenomena of metals by fused salts depend on chemical composition of the melt and environmental conditions of the system. Detail knowledge of chemistry and thermodynamic of aggressive species formed during the corrosion process is essential for a better understanding of materials degradation exposed to high temperature. When there is a lack of kinetic data for the corrosion processes, an alternative to understand the thermodynamic behavior of chemical species is to utilize phase stability diagrams. Nowadays, there are several specialized software programs to calculate phase stability diagrams. These programs are based on thermodynamics of chemical reactions. Using a thermodynamic data base allows the calculation of different types of phase diagrams. However, sometimes it is difficult to have access to such data bases. In this work, an alternative way to calculate phase stability diagrams is presented. The work is exemplified in the Na-V-S-O and Al-Na-V-S-O systems. This system was chosen because vanadium salts is one of the more aggressive system for all engineering alloys, especially in those processes where fossil fuels are used.

A self-adaptive thermal switch array for rapid temperature stabilization under various thermal power inputs

International Nuclear Information System (INIS)

Geng, Xiaobao; Patel, Pragnesh; Narain, Amitabh; Meng, Dennis Desheng

2011-01-01

A self-adaptive thermal switch array (TSA) based on actuation by low-melting-point alloy droplets is reported to stabilize the temperature of a heat-generating microelectromechanical system (MEMS) device at a predetermined range (i.e. the optimal working temperature of the device) with neither a control circuit nor electrical power consumption. When the temperature is below this range, the TSA stays off and works as a thermal insulator. Therefore, the MEMS device can quickly heat itself up to its optimal working temperature during startup. Once this temperature is reached, TSA is automatically turned on to increase the thermal conductance, working as an effective thermal spreader. As a result, the MEMS device tends to stay at its optimal working temperature without complex thermal management components and the associated parasitic power loss. A prototype TSA was fabricated and characterized to prove the concept. The stabilization temperatures under various power inputs have been studied both experimentally and theoretically. Under the increment of power input from 3.8 to 5.8 W, the temperature of the device increased only by 2.5 °C due to the stabilization effect of TSA

Investigation on flow stability of supercritical water cooled systems

International Nuclear Information System (INIS)

Cheng, X.; Kuang, B.

2006-01-01

Research activities are ongoing worldwide to develop nuclear power plants with supercritical water cooled reactor (SCWR) with the purpose to achieve a high thermal efficiency and to improve their economical competitiveness. However, the strong variation of the thermal-physical properties of water in the vicinity of the pseudo-critical line results in challenging tasks in various fields, e.g. thermal-hydraulic design of a SCWR. One of the challenging tasks is to understand and to predict the dynamic behavior of supercritical water cooled systems. Although many thermal-hydraulic research activities were carried out worldwide in the past as well as in the near present, studies on dynamic behavior and flow stability of SC water cooled systems are scare. Due to the strong density variation, flow stability is expected to be one of the key items which need to be taken into account in the design of a SCWR. In the present work, the dynamic behavior and flow stability of SC water cooled systems are investigated using both numerical and theoretical approaches. For this purpose a new computer code SASC was developed, which can be applied to analysis the dynamic behavior of systems cooled by supercritical fluids. In addition, based on the assumptions of a simplified system, a theoretical model was derived for the prediction of the onset of flow instability. A comparison was made between the results obtained using the theoretical model and those from the SASC code. A good agreement was achieved. This gives the first evidence of the reliability of both the SASC code and the theoretical model

Temperature range extension of an organically crosslinked polymer system and its successful field application for water and gas shutoff

Energy Technology Data Exchange (ETDEWEB)

Vasquez, Julio; Eoff, Larry; Dalrymple, Dwyann [Halliburton, Rio de Janeiro. RJ (Brazil)

2008-07-01

Excessive water production from hydrocarbon reservoirs is one of the most serious problems in the oil industry. Water production greatly affects the economic life of producing wells and brings along secondary problems such as sand production, corrosion, and tubular scale. Remediation techniques for controlling water production, generally referred to as conformance control, include the use of polymer systems to reduce or plug permeability to water. This paper presents the laboratory evaluation of an organically crosslinked polymer (OCP) system used as a sealant for water control problems in hydrocarbon wells. Originally, the OCP system had a limited working temperature range (140 deg to 260 deg F). Recently, an alternative base polymer (for low temperatures) and a retarder (for high temperatures) have been introduced to expand the temperature range of applicability of the OCP system from 70 deg F to 350 deg F without compromising its effectiveness or thermal stability. More than 400 jobs have been performed with the OCP system around the world to address conformance problems such as water coning/cresting, high-permeability streaks, gravel pack isolation, fracture shutoff, and casing leak repairs. This paper presents an overview of case histories that used the OCP system in various regions of the world for a wide variety of applications. (author)

High-temperature grain size stabilization of nanocrystalline Fe–Cr alloys with Hf additions

Energy Technology Data Exchange (ETDEWEB)

Li, Lulu, E-mail: lli18@ncsu.edu; Saber, Mostafa; Xu, Weizong; Zhu, Yuntian; Koch, Carl C.; Scattergood, Ronald O.

2014-09-08

The influence of 1–4 at% Hf additions on the thermal stability of mechanically alloyed nanocrystalline Fe–14Cr alloys was studied in this work. XRD-calculated grain size and microhardness results were reported versus isochronal annealing treatments up to 1100 °C. Microstructural evolution was investigated using channeling contrast FIB imaging and TEM. Grain size of samples with 4 at% Hf was found to be maintained in the nanoscale range at temperatures up to 1000 °C. Zener pinning was considered as a major source of high temperature grain size stabilization. By comparing the Orowan strengthening contribution to the total hardness, the deviation of grain size predictions from the actual grain size in Fe–14Cr–4Hf suggests the presence of thermodynamic stabilization by the solute segregation to grain boundaries (GBs). A predictive thermodynamic model indicates that the thermodynamic stabilization can be expected.

Passive Temperature Stabilization of Silicon Photonic Devices Using Liquid Crystals

Directory of Open Access Journals (Sweden)

Joanna Ptasinski

2014-03-01

Full Text Available In this work we explore the negative thermo-optic properties of liquid crystal claddings for passive temperature stabilization of silicon photonic integrated circuits. Photonic circuits are playing an increasing role in communications and computing, but they suffer from temperature dependent performance variation. Most existing techniques aimed at compensation of thermal effects rely on power hungry Joule heating. We show that integrating a liquid crystal cladding helps to minimize the effects of a temperature dependent drift. The advantage of liquid crystals lies in their high negative thermo-optic coefficients in addition to low absorption at the infrared wavelengths.

Development of Low-Toxicity Wastewater Stabilization for Spacecraft Water Recovery Systems

Science.gov (United States)

Adam, Niklas; Mitchell, Julie; Pickering, Karen; Carrier, Chris; Vega, Letty; Muirhead, Dean

2014-01-01

Wastewater stabilization was an essential component of the spacecraft water cycle. The purpose of stabilizing wastewater was two-fold. First, stabilization prevents the breakdown of urea into ammonia, a toxic gas at high concentrations. Second, it prevents the growth of microorganisms, thereby mitigating hardware and water quality issues due to due biofilm and planktonic growth. Current stabilization techniques involve oxidizers and strong acids (pH=2) such as chromic and sulfuric acid, which are highly toxic and pose a risk to crew health. The purpose of this effort was to explore less toxic stabilization techniques, such as food-grade and commercial care preservatives. Additionally, certain preservatives were tested in the presence of a low-toxicity organic acid. Triplicate 300-mL volumes of urine were dosed with a predetermined quantity of stabilizer and stored for two weeks. During that time, pH, total organic carbon (TOC), ammonia, and turbidity were monitored. Those preservatives that showed the lowest visible microbial growth and stable pH were further tested in a six-month stability study. The results of the six-month study are also included in this paper.

Performance on Water Stability of Cement-Foamed Asphalt Cold Recycled Mixture

OpenAIRE

Li Junxiao; Fu Wei; Zang Hechao

2018-01-01

Through designing the mixture proportion of foamed asphalt cold in-place recycled mixture combined with the water stability experiment, it shows that the addition of cement can obviously improve foamed asphalt mixture’s water stability and the best cement admixture is between 1% ~ 2%; Using digital imaging microscope and SEM technology, the mechanism of increasing on the intensity of foamed asphalt mixture resulted by adding cement was analyzed. It revealed that the cement hydration products ...

Bifurcation analysis of the simplified models of boiling water reactor and identification of global stability boundary

Energy Technology Data Exchange (ETDEWEB)

Pandey, Vikas; Singh, Suneet, E-mail: suneet.singh@iitb.ac.in

2017-04-15

Highlights: • Non-linear stability analysis of nuclear reactor is carried out. • Global and local stability boundaries are drawn in the parameter space. • Globally stable, bi-stable, and unstable regions have been demarcated. • The identification of the regions is verified by numerical simulations. - Abstract: Nonlinear stability study of the neutron coupled thermal hydraulics instability has been carried out by several researchers for boiling water reactors (BWRs). The focus of these studies has been to identify subcritical and supercritical Hopf bifurcations. Supercritical Hopf bifurcation are soft or safe due to the fact that stable limit cycles arise in linearly unstable region; linear and global stability boundaries are same for this bifurcation. It is well known that the subcritical bifurcations can be considered as hard or dangerous due to the fact that unstable limit cycles (nonlinear phenomena) exist in the (linearly) stable region. The linear stability leads to a stable equilibrium in such regions, only for infinitesimally small perturbations. However, finite perturbations lead to instability due to the presence of unstable limit cycles. Therefore, it is evident that the linear stability analysis is not sufficient to understand the exact stability characteristics of BWRs. However, the effect of these bifurcations on the stability boundaries has been rarely discussed. In the present work, the identification of global stability boundary is demonstrated using simplified models. Here, five different models with different thermal hydraulics feedback have been investigated. In comparison to the earlier works, current models also include the impact of adding the rate of change in temperature on void reactivity as well as effect of void reactivity on rate of change of temperature. Using the bifurcation analysis of these models the globally stable region in the parameter space has been identified. The globally stable region has only stable solutions and

Bifurcation analysis of the simplified models of boiling water reactor and identification of global stability boundary

International Nuclear Information System (INIS)

Pandey, Vikas; Singh, Suneet

2017-01-01

Highlights: • Non-linear stability analysis of nuclear reactor is carried out. • Global and local stability boundaries are drawn in the parameter space. • Globally stable, bi-stable, and unstable regions have been demarcated. • The identification of the regions is verified by numerical simulations. - Abstract: Nonlinear stability study of the neutron coupled thermal hydraulics instability has been carried out by several researchers for boiling water reactors (BWRs). The focus of these studies has been to identify subcritical and supercritical Hopf bifurcations. Supercritical Hopf bifurcation are soft or safe due to the fact that stable limit cycles arise in linearly unstable region; linear and global stability boundaries are same for this bifurcation. It is well known that the subcritical bifurcations can be considered as hard or dangerous due to the fact that unstable limit cycles (nonlinear phenomena) exist in the (linearly) stable region. The linear stability leads to a stable equilibrium in such regions, only for infinitesimally small perturbations. However, finite perturbations lead to instability due to the presence of unstable limit cycles. Therefore, it is evident that the linear stability analysis is not sufficient to understand the exact stability characteristics of BWRs. However, the effect of these bifurcations on the stability boundaries has been rarely discussed. In the present work, the identification of global stability boundary is demonstrated using simplified models. Here, five different models with different thermal hydraulics feedback have been investigated. In comparison to the earlier works, current models also include the impact of adding the rate of change in temperature on void reactivity as well as effect of void reactivity on rate of change of temperature. Using the bifurcation analysis of these models the globally stable region in the parameter space has been identified. The globally stable region has only stable solutions and

Quicklime (CaO) Stabilization of fine-grained marine sediments in low temperature areas

DEFF Research Database (Denmark)

Skels, Peteris; Ingeman-Nielsen, Thomas; Jørgensen, Anders Stuhr

2011-01-01

This study presents laboratory testing on quicklime (CaO) stabilization of fine-grained marine sediments in low temperature areas. The soil was sampled on the Fossil Plain in Kangerlussuaq, Greenland, and analyzed in the laboratory at Technical University of Denmark (DTU). The optimum CaO content...... curing temperatures, comparing stabilization effectiveness between low and normal soil temperature conditions....... in a soil-CaO mixture was determined using a number of laboratory methods, such as pH test, consistency limit analysis, degree of compaction, and short term California Bearing Ratio (CBR) values. The study also numerically demonstrates a long term strength development of the soil-CaO mixture at 1°C and 10°C...

Evaluation of the effect of temperature on the stability of metal soaps ...

African Journals Online (AJOL)

The thermal stability of calcium and zinc dicarboxylates was studied. The kinetics of the decomposition was studied thermogravimetrically at various temperatures. The rates of the first stage decomposition were used to assess the effect of temperature on the susceptibility of the metal soaps of dicarboxylic acids to ...

Thermal infrared remote sensing of water temperature in riverine landscapes

Science.gov (United States)

Handcock, Rebecca N.; Torgersen, Christian E.; Cherkauer, Keith A.; Gillespie, Alan R.; Klement, Tockner; Faux, Russell N.; Tan, Jing; Carbonneau, Patrice E.; Piégay, Hervé

2012-01-01

Water temperature in riverine landscapes is an important regional indicator of water quality that is influenced by both ground- and surface-water inputs, and indirectly by land use in the surrounding watershed (Brown and Krygier, 1970; Beschta et al., 1987; Chen et al., 1998; Poole and Berman, 2001).Coldwater fishes such as salmon and trout are sensitive to elevated water temperature; therefore, water temperature must meet management guidelines and quality standards, which aim to create a healthy environment for endangered populations (McCullough et al., 2009). For example, in the USA, the Environmental Protection Agency (EPA) has established water quality standards to identify specific temperature criteria to protect coldwater fishes (Environmental Protection Agency, 2003). Trout and salmon can survive in cool-water refugia even when temperatures at other measurement locations are at or above the recommended maximums (Ebersole et al., 2001; Baird and Krueger, 2003; High et al., 2006). Spatially extensive measurements of water temperature are necessary to locate these refugia, to identify the location of ground- and surface-water inputs to the river channel, and to identify thermal pollution sources. Regional assessment of water temperature in streams and rivers has been limited by sparse sampling in both space and time. Water temperature has typically been measured using a network of widely distributed instream gages, which record the temporal change of the bulk, or kinetic, temperature of the water (Tk) at specific locations. For example, the State of Washington (USA) recorded water quality conditions at 76 stations within the Puget Lowlands eco region, which contains 12,721 km of streams and rivers (Washington Department of Ecology, 1998). Such gages are sparsely distributed, are typically located only in larger streams and rivers, and give limited information about the spatial distribution of water temperature.

Gelation Behavior Study of a Resorcinol–Hexamethyleneteramine Crosslinked Polymer Gel for Water Shut-Off Treatment in Low Temperature and High Salinity Reservoirs

Directory of Open Access Journals (Sweden)

Yongpeng Sun

2017-07-01

Full Text Available Mature oilfields usually encounter the problem of high watercut. It is practical to use chemical methods for water-shutoff in production wells, however conventional water-shutoff agents have problems of long gelation time, low gel strength, and poor stability under low temperature and high salinity conditions. In this work a novel polymer gel for low temperature and high salinity reservoirs was developed. This water-shutoff agent had controllable gelation time, adjustable gel strength and good stability performance. The crosslinking process of this polymer gel was studied by rheological experiments. The process could be divided into an induction period, a fast crosslinking period, and a stable period. Its gelation behaviors were investigated in detail. According to the Gel Strength Code (GSC and vacuum breakthrough method, the gel strength was displayed in contour maps. The composition of the polymer gel was optimized to 0.25~0.3% YG100 + 0.6~0.9% resorcinol + 0.2~0.4% hexamethylenetetramine (HMTA + 0.08~0.27% conditioner (oxalic acid. With the concentration increase of the polymer gel and temperature, the decrease of pH, the induction period became shorter and the crosslinking was more efficient, resulting in better stability performance. Various factors of the gelation behavior which have an impact on the crosslinking reaction process were examined. The relationships between each impact factor and the initial crosslinking time were described with mathematical equations.

Stable solid state reference electrodes for high temperature water chemistry

International Nuclear Information System (INIS)

Jayaweera, P.; Millett, P.J.

1995-01-01

A solid state electrode capable of providing a stable reference potential under a wide range of temperatures and chemical conditions has been demonstrated. The electrode consists of a zirconia or yttria-stabilized zirconia tube packed with an inorganic polymer electrolyte and a silver/silver chloride sensing element. The sensing element is maintained near room temperature by a passive cooling heat sink. The electrode stability was demonstrated by testing it in high temperature (280 C) aqueous solutions over extended periods of time. This reference electrode is useful in many applications, particularly for monitoring the chemistry in nuclear and fossil power plants

Micelle-stabilized room-temperature phosphorescence with synchronous scanning

International Nuclear Information System (INIS)

Femia, R.A.; Love, L.J.C.

1984-01-01

The experimental requirements for synchronous wavelength scanning micelle-stabilized room temperature phosphorescence and the factors affecting peak resolution are presented and compared with those for synchronous wavelength scanning fluorescence. Identification of individual compounds in a four-component mixture is illustrated, and criteria to identify and minimize triplet state energy transfer are given. Considerable improvement in resolution of the synchronous peaks is obtained via second derivative spectra. 20 references, 7 figures, 2 tables

The effect of cool water pack preparation on vaccine vial temperatures in refrigerators.

Science.gov (United States)

Goldwood, Geneva; Diesburg, Steven

2018-01-02

Cool water packs are a useful alternative to ice packs for preventing unintentional freezing of vaccines during outreach in some situations. Current guidelines recommend the use of a separate refrigerator for cooling water packs from ambient temperatures to prevent possible heat degradation of adjacent vaccine vials. To investigate whether this additional equipment is necessary, we measured the temperatures that vaccine vials were exposed to when warm water packs were placed next to vials in a refrigerator. We then calculated the effect of repeated vial exposure to those temperatures on vaccine vial monitor status to estimate the impact to the vaccine. Vials were tested in a variety of configurations, varying the number and locations of vials and water packs in the refrigerator. The calculated average percentage life lost during a month of repeated warming ranged from 20.0% to 30.3% for a category 2 (least stable) vaccine vial monitor and from 3.8% to 6.0% for a category 7 (moderate stability) vaccine vial monitor, compared to 17.0% for category 2 vaccine vial monitors and 3.1% for category 7 vaccine vial monitors at a constant 5 °C. The number of vials, number of water packs, and locations of each impacted vial warming and therefore percentage life lost, but the vaccine vial monitor category had a higher impact on the average percentage life lost than any of the other parameters. The results suggest that damage to vaccines from repeated warming over the course of a month is not certain and that cooling water packs in a refrigerator where vaccines are being stored may be a useful practice if safe procedures are established. Copyright © 2017 The Author(s). Published by Elsevier Ltd.. All rights reserved.

Wettability Control of Gold Surfaces Modified with Benzenethiol Derivatives: Water Contact Angle and Thermal Stability.

Science.gov (United States)

Tatara, Shingo; Kuzumoto, Yasutaka; Kitamura, Masatoshi

2016-04-01

The water wettability of Au surfaces has been controlled using various benzenethiol derivatives including 4-methylbenzenethiol, pentafluorobenzenethiol, 4-flubrobenzenethiol, 4-methoxy-benzenethiol, 4-nitrobenzenethiol, and 4-hydroxybenzenethiol. The water contact angle of the Au surface modified with the benzenethiol derivative was found to vary in the wide range of 30.9° to 88.3°. The contact angle of the modified Au films annealed was also measured in order to investigate their thermal stability. The change in the contact angle indicated that the modified surface is stable at temperatures below about 400 K. Meanwhile, the activation energy of desorption from the modified surface was estimated from the change in the contact angle. The modified Au surface was also examined using X-ray photoelectron spectroscopy.

Mechanism of high-temperature resistant water-base mud

Energy Technology Data Exchange (ETDEWEB)

Luo, P

1981-01-01

Based on experiments, the causes and laws governing the changes in the performance of water-base mud under high temperature are analyzed, and the requisites and mechanism of treating agents resisting high temperature are discussed. Ways and means are sought for inhibiting, delaying and making use of the effect of high temperature on the performance of mud, while new ideas and systematic views have been expressed on the preparation of treating agents and set-up of a high temperature resistant water-base mud system. High temperature dispersion and high temperature surface inactivation of clay in the mud, as well as their effect and method of utilization are reviewed. Subjects also touched upon include degradation and cross-linking of the high-temperature resistant treating agents, their use and effect. Based on the above, the preparation of a water-base and system capable of resisting 180 to 250/sup 0/C is recommended.

An observational study on the temperature rising effects in water warming canal and water warming pond

Energy Technology Data Exchange (ETDEWEB)

Hong, J. B.; Hong, S. B. [Rural Development Cooperation, Seoul (Korea, Republic of)

1990-09-15

The power water flowed out from the multipurpose darn influences the ecosystem approximately because of the low water temperature. An appropriate counter measure to the rising water temperature is needed for growing crops especially when the temperature is below 18°C in the source of the irrigation water This observational study is practiced in Yong-Doo water warming canal and pond in the down stream of Choong-Ju multipurpose dam and is practiced for analyse and compare the rising effects in actural water temperature by actual measurement with the rising effects of planned water temperatuer by the basic theoritical method and for the help to present the direction in plan establishment through investigate the results afterwards. The results are as follows. 1. The degree of the rise of the water temperature can be decided by θ{sub x} = θ{sub 0} + K (L/(v * h)) * (T - θ{sub 0}) Then, K values of a factor representing the characteristics of the water warming canal were 0.00002043 for the type I. and 0.0000173 for the type II. respectively. 2. A variation of water temperature which produced by the difference effective temperature and water temperature in the water warming canal was θ{sub x1} = 16.5 + 15.9 (1-e{sup -0.00018x}), θ{sub x2} = 18.8 + 8.4(1-e{sup -0.000298x}) for the type I. and θ{sub x} = 19.6 + 12.8 (1-e{sup -0.00041x}) for the type II. 3. It was shown that the effects of the rise of water temperature for the type I. water warming canal were greater than that of type II. as a resultes of broadening the surface of the canal compared with the depth of water, coloring the surface of water canal and installing the resistance block. 4. In case of the type I. water warming canal, the equation between the air temperature and the degree of the rise of water temprature could be made; Y = 0.4134X + 7.728 In addition, in case of the type II. water warming canal, the correlation was very low. 5. A monthly variation of the water temperature in the water warming

Stress corrosion cracking susceptibilities of various stainless steels in high temperature water

International Nuclear Information System (INIS)

Shoji, Saburo; Ohnaka, Noriyuki; Kikuchi, Eiji; Minato, Akira; Tanno, Kazuo.

1980-01-01

The intergranular stress corrosion cracking (IGSCC) behaviors of several austenitic stainless steels in high temperature water were evaluated using three types of SCC tests, i.e., single U-bend test in chloride containing water, uniaxial constant load and constant extension rate tests (CERT) in pure water. The steels used were SUS 304, 304L, 316, 316L, 321 and 347 and several heats of them to examine heat to heat variations. The three test methods gave the same relative ranking of the steels. The CERT is the most sensitive method to detect the relative IGSCC susceptibilities. The CERT result for relative ranking from poor to good is: SUS 304 - 0.07% C, 304 - 0.06% C, 304L - 0.028% C, 316 - 0.07% C. The IGSCC susceptibilities of SUS 304L - 0.020% C, 316L - 0.023% C, 321 and 347 were not detected. These test results suggest that the use of the low carbon, molybdenum bearing, or stabilized austenitic stainless steel is beneficial for eliminating the IGSCC problem in boiling water reactor environment. (author)

Regulation of Silk Material Structure by Temperature-Controlled Water Vapor Annealing

Science.gov (United States)

Hu, Xiao; Shmelev, Karen; Sun, Lin; Gil, Eun-Seok; Park, Sang-Hyug; Cebe, Peggy; Kaplan, David L.

2011-01-01

We present a simple and effective method to obtain refined control of the molecular structure of silk biomaterials through physical temperature-controlled water vapor annealing (TCWVA). The silk materials can be prepared with control of crystallinity, from a low content using conditions at 4°C (alpha-helix dominated silk I structure), to highest content of ~60% crystallinity at 100°C (beta-sheet dominated silk II structure). This new physical approach covers the range of structures previously reported to govern crystallization during the fabrication of silk materials, yet offers a simpler, green chemistry, approach with tight control of reproducibility. The transition kinetics, thermal, mechanical, and biodegradation properties of the silk films prepared at different temperatures were investigated and compared by Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), uniaxial tensile studies, and enzymatic degradation studies. The results revealed that this new physical processing method accurately controls structure, in turn providing control of mechanical properties, thermal stability, enzyme degradation rate, and human mesenchymal stem cell interactions. The mechanistic basis for the control is through the temperature controlled regulation of water vapor, to control crystallization. Control of silk structure via TCWVA represents a significant improvement in the fabrication of silk-based biomaterials, where control of structure-property relationships is key to regulating material properties. This new approach to control crystallization also provides an entirely new green approach, avoiding common methods which use organic solvents (methanol, ethanol) or organic acids. The method described here for silk proteins would also be universal for many other structural proteins (and likely other biopolymers), where water controls chain interactions related to material properties. PMID:21425769

Salinity and temperature variations around Peninsula Malaysia coastal waters

International Nuclear Information System (INIS)

Abdul Kadir Ishak; Jeremy Andy Anak Dominic; Nazrul Hizam Yusof; Mohd Rafaei Murtadza

2004-01-01

Vertical profiles of salinity and temperature were measured at several offshore stations along east and west coast of Peninsula Malaysia coastal waters. The measurements which covered South China Sea and Straits of Malacca were made during sampling cruises for Marine Database Project for Peninsula Malaysia, and during an IAEA regional training course for Marine Pollution Project. The results show that the water temperature is highest at the surface and minimum at bottom, while the salinity is lowest at the surface and highest at the bottom. In Malacca Straits, the highest surface water temperature was 30.6 degree C and the lowest bottom water temperature was 20.4 degree C, recorded at a station located in Andaman Sea. The same station also recorded the highest surface and bottom salinity i.e. 31.3 ppt and 34.4 ppt, respectively. For South China Sea, the maximum surface water temperature was 30.4 degree C and the minimum bottom temperature was 25.9 degree C, while the highest surface salinity was 33.2 ppt and the highest bottom salinity was 34.1 ppt. The water in South China Sea also showed some degrees of stratifications with thermocline zones located between 10-40 m water depths. In Malacca Straits, stronger thermocline develops at higher latitude, while at lower latitude the water is more readily mixed. Beside the spatial variations, the seawater temperature and salinity around Peninsula Malaysia also subjected to temporal variation as seawater. (Author)

Structure, electrical characteristics, and high-temperature stability of aerosol jet printed silver nanoparticle films

Energy Technology Data Exchange (ETDEWEB)

Rahman, Md Taibur; McCloy, John; Panat, Rahul, E-mail: rahul.panat@wsu.edu, E-mail: rvchintalapalle@utep.edu [School of Mechanical and Materials Engineering, Washington State University, Pullman, Washington 99163 (United States); Ramana, C. V., E-mail: rahul.panat@wsu.edu, E-mail: rvchintalapalle@utep.edu [Department of Mechanical Engineering, University of Texas at El Paso, El Paso, Texas 79968 (United States)

2016-08-21

Printed electronics has emerged as a versatile eco-friendly fabrication technique to create sintered nanoparticle (NP) films on arbitrary surfaces with an excellent control over the film microstructure. While applicability of such films for high-temperature applications is not explored previously, herein we report the high-temperature electrical stability of silver (Ag) metal NP films fabricated using an Aerosol Jet based printing technique and demonstrate that this behavior is dictated by changes in the film microstructure. In-situ high temperature (24–500 °C) impedance spectroscopy measurements show that the real part of the impedance increases with increasing temperature up to 150 °C, at which point a decreasing trend prevails until 300 °C, followed again by an increase in impedance. The electrical behavior is correlated with the in-situ grain growth of the Ag NP films, as observed afterwards by scanning electron microscopy and X-ray diffraction (XRD), and could be tailored by controlling the initial microstructure through sintering conditions. Using combined diffraction and spectroscopic analytical methods, it is demonstrated the Aerosol Jet printed Ag NP films exhibit enhanced thermal stability and oxidation resistance. In addition to establishing the conditions for stability of Ag NP films, the results provide a fundamental understanding of the effect of grain growth and reduction in grain boundary area on the electrical stability of sintered NP films.

Structure, electrical characteristics, and high-temperature stability of aerosol jet printed silver nanoparticle films

International Nuclear Information System (INIS)

Rahman, Md Taibur; McCloy, John; Panat, Rahul; Ramana, C. V.

2016-01-01

Printed electronics has emerged as a versatile eco-friendly fabrication technique to create sintered nanoparticle (NP) films on arbitrary surfaces with an excellent control over the film microstructure. While applicability of such films for high-temperature applications is not explored previously, herein we report the high-temperature electrical stability of silver (Ag) metal NP films fabricated using an Aerosol Jet based printing technique and demonstrate that this behavior is dictated by changes in the film microstructure. In-situ high temperature (24–500 °C) impedance spectroscopy measurements show that the real part of the impedance increases with increasing temperature up to 150 °C, at which point a decreasing trend prevails until 300 °C, followed again by an increase in impedance. The electrical behavior is correlated with the in-situ grain growth of the Ag NP films, as observed afterwards by scanning electron microscopy and X-ray diffraction (XRD), and could be tailored by controlling the initial microstructure through sintering conditions. Using combined diffraction and spectroscopic analytical methods, it is demonstrated the Aerosol Jet printed Ag NP films exhibit enhanced thermal stability and oxidation resistance. In addition to establishing the conditions for stability of Ag NP films, the results provide a fundamental understanding of the effect of grain growth and reduction in grain boundary area on the electrical stability of sintered NP films.

Structure, electrical characteristics, and high-temperature stability of aerosol jet printed silver nanoparticle films

Science.gov (United States)

Rahman, Md Taibur; McCloy, John; Ramana, C. V.; Panat, Rahul

2016-08-01

Printed electronics has emerged as a versatile eco-friendly fabrication technique to create sintered nanoparticle (NP) films on arbitrary surfaces with an excellent control over the film microstructure. While applicability of such films for high-temperature applications is not explored previously, herein we report the high-temperature electrical stability of silver (Ag) metal NP films fabricated using an Aerosol Jet based printing technique and demonstrate that this behavior is dictated by changes in the film microstructure. In-situ high temperature (24-500 °C) impedance spectroscopy measurements show that the real part of the impedance increases with increasing temperature up to 150 °C, at which point a decreasing trend prevails until 300 °C, followed again by an increase in impedance. The electrical behavior is correlated with the in-situ grain growth of the Ag NP films, as observed afterwards by scanning electron microscopy and X-ray diffraction (XRD), and could be tailored by controlling the initial microstructure through sintering conditions. Using combined diffraction and spectroscopic analytical methods, it is demonstrated the Aerosol Jet printed Ag NP films exhibit enhanced thermal stability and oxidation resistance. In addition to establishing the conditions for stability of Ag NP films, the results provide a fundamental understanding of the effect of grain growth and reduction in grain boundary area on the electrical stability of sintered NP films.

Nolinear stability analysis of nuclear reactors : expansion methods for stability domains

International Nuclear Information System (INIS)

Yang, Chae Yong

1992-02-01

Two constructive methods for estimating asymptotic stability domains of nonlinear reactor models are developed in this study: an improved Chang and Thorp's method based on expansion of a Lyapunov function and a new method based on expansion of any positive definite function. The methods are established on the concept of stability definitions of Lyapunov itself. The first method provides a sequence of stability regions that eventually approaches the exact stability domain, but requires many expansions in order to obtain the entire stability region because the starting Lyapunov function usually corresponds to a small stability region and because most dynamic systems are stiff. The second method (new method) requires only a positive definite function and thus it is easy to come up with a starting region. From a large starting region, the entire stability region is estimated effectively after sufficient iterations. It is particularly useful for stiff systems. The methods are applied to several nonlinear reactor models known in the literature: one-temperature feedback model, two-temperature feedback model, and xenon dynamics model, and the results are compared. A reactor feedback model for a pressurized water reactor (PWR) considering fuel and moderator temperature effects is developed and the nonlinear stability regions are estimated for the various values of design parameters by using the new method. The steady-state properties of the nonlinear reactor system are analyzed via bifurcation theory. The analysis of nonlinear phenomena is carried out for the various forms of reactivity feedback coefficients that are both temperature- (or power-) independent and dependent. If one of two temperature coefficients is positive, unstable limit cycles or multiplicity of the steady-state solutions appear when the other temperature coefficient exceeds a certain critical value. As an example, even though the fuel temperature coefficient is negative, if the moderator temperature

From Space to the Rocky Intertidal: Using NASA MODIS Sea Surface Temperature and NOAA Water Temperature to Predict Intertidal Logger Temperature

Directory of Open Access Journals (Sweden)

Jessica R. P. Sutton

2017-02-01

Full Text Available The development of satellite-derived datasets has greatly facilitated large-scale ecological studies, as in situ observations are spatially sparse and expensive undertakings. We tested the efficacy of using satellite sea surface temperature (SST collected by NASA’s Moderate Resolution Imaging Spectroradiometer (MODIS and local water temperature collected from NOAA buoys and onshore stations to estimate submerged intertidal mussel logger temperatures. Daily SST and local water temperatures were compared to mussel logger temperatures at five study sites located along the Oregon coastline. We found that satellite-derived SSTs and local water temperatures were similarly correlated to the submerged mussel logger temperatures. This finding suggests that satellite-derived SSTs may be used in conjunction with local water temperatures to understand the temporal and spatial variation of mussel logger temperatures. While there are limitations to using satellite-derived temperature for ecological studies, including issues with temporal and spatial resolution, our results are promising.

Reconstructing bottom water temperatures from measurements of temperature and thermal diffusivity in marine sediments

Science.gov (United States)

Miesner, F.; Lechleiter, A.; Müller, C.

2015-07-01

Continuous monitoring of oceanic bottom water temperatures is a complicated task, even in relatively easy-to-access basins like the North or Baltic seas. Here, a method to determine annual bottom water temperature variations from inverse modeling of instantaneous measurements of temperatures and sediment thermal properties is presented. This concept is similar to climate reconstructions over several thousand years from deep borehole data. However, in contrast, the presented method aims at reconstructing the recent temperature history of the last year from sediment thermal properties and temperatures from only a few meters depth. For solving the heat equation, a commonly used forward model is introduced and analyzed: knowing the bottom water temperature variations for the preceding years and the thermal properties of the sediments, the forward model determines the sediment temperature field. The bottom water temperature variation is modeled as an annual cosine defined by the mean temperature, the amplitude and a phase shift. As the forward model operator is non-linear but low-dimensional, common inversion schemes such as the Newton algorithm can be utilized. The algorithms are tested for artificial data with different noise levels and for two measured data sets: from the North Sea and from the Davis Strait. Both algorithms used show stable and satisfying results with reconstruction errors in the same magnitude as the initial data error. In particular, the artificial data sets are reproduced with accuracy within the bounds of the artificial noise level. Furthermore, the results for the measured North Sea data show small variances and resemble the bottom water temperature variations recorded from a nearby monitoring site with relative errors smaller than 1 % in all parameters.

Accelerated Physical Stability Testing of Amorphous Dispersions.

Science.gov (United States)

Mehta, Mehak; Suryanarayanan, Raj

2016-08-01

The goal was to develop an accelerated physical stability testing method of amorphous dispersions. Water sorption is known to cause plasticization and may accelerate drug crystallization. In an earlier investigation, it was observed that both the increase in mobility and decrease in stability in amorphous dispersions was explained by the "plasticization" effect of water (Mehta et al. Mol. Pharmaceutics 2016, 13 (4), 1339-1346). In this work, the influence of water concentration (up to 1.8% w/w) on the correlation between mobility and crystallization in felodipine dispersions was investigated. With an increase in water content, the α-relaxation time as well as the time for 1% w/w felodipine crystallization decreased. The relaxation times of the systems, obtained with different water concentration, overlapped when the temperature was scaled (Tg/T). The temperature dependencies of the α-relaxation time as well as the crystallization time were unaffected by the water concentration. Thus, the value of the coupling coefficient, up to a water concentration of 1.8% w/w, was approximately constant. Based on these findings, the use of "water sorption" is proposed to build predictive models for crystallization in slow crystallizing dispersions.

Time and Temperature Test Results for PFP Thermal Stabilization Furnaces

International Nuclear Information System (INIS)

COMPTON, J.A.

2000-01-01

The national standard for plutonium storage acceptability (standard DOE-STD-3013-99, generally known as ''the 3013 standard'') has been revised to clarify the requirement for processes that will produce acceptable storage materials. The 3013 standard (Reference 1) now states that ''Oxides shall be stabilized by heating the material in an oxidizing atmosphere to a Material Temperature of at least 950 C (1742 F) for not less than 2 hours.'' The process currently in use for producing stable oxides for storage at the Plutonium Finishing Plant (PFP) heats a furnace atmosphere to 1000 C and holds it there for 2 hours. The temperature of the material being stabilized is not measured directly during this process. The Plutonium Process Support Laboratories (PPSL) were requested to demonstrate that the process currently in use at PFP is an acceptable method of producing stable plutonium dioxide consistently. A spare furnace identical to the production furnaces was set up and tested under varying conditions with non-radioactive surrogate materials. Reference 2 was issued to guide the testing program. The process currently in use at the PFP for stabilizing plutonium-bearing powders was shown to heat all the material in the furnace to at least 950 C for at least 2 hours. The current process will work for (1) relatively pure plutonium dioxide, (2) dioxide powders mixed with up to 20 weight percent magnesium oxide, and (3) dioxide powders with up to 11 weight percent magnesium oxide and 20 weight percent magnesium nitrate hexahydrate. Time and temperature data were also consistent with a successful demonstration for a mixture containing 10 weight percent each of sodium and potassium chloride; however, the molten chloride salts destroyed the thermocouples in the powder and temperature data were unavailable for part of that run. These results assume that the current operating limits of no more than 2500 grams per furnace charge and a powder height of no more than 1.5 inches remain

Modeling Nitrogen Decrease in Water Lettuce Ponds from Waste Stabilization Ponds

Science.gov (United States)

Putri, Gitta Agnes; Sunarsih

2018-02-01

This paper presents about the dynamic modeling of the Water Lettuce ponds as a form of improvement from the Water Hyacinth ponds. The purpose of this paper is to predict nitrogen decrease and nitrogen transformation in Water Lettuce ponds integrated with Waste Stabilization Ponds. The model consists of 4 mass balances, namely Dissolved Organic Nitrogen (DON), Particulate Organic Nitrogen (PON), ammonium (NH4+), Nitrate and Nitrite (NOx). The process of nitrogen transformation which considered in a Water Lettuce ponds, namely hydrolysis, mineralization, nitrification, denitrification, plant and bacterial uptake processes. Numerical simulations are performed by giving the values of parameters and the initial values of nitrogen compounds based on a review of previous studies. Numerical results show that the rate of change in the concentration of nitrogen compounds in the integration ponds of waste stabilization and water lettuce decreases and reaches stable at different times.

Stabilizing local boundary conditions for two-dimensional shallow water equations

KAUST Repository

Dia, Ben Mansour

2018-03-27

In this article, we present a sub-critical two-dimensional shallow water flow regulation. From the energy estimate of a set of one-dimensional boundary stabilization problems, we obtain a set of polynomial equations with respect to the boundary values as a requirement for the energy decrease. Using the Riemann invariant analysis, we build stabilizing local boundary conditions that guarantee the stability of the hydrodynamical state around a given steady state. Numerical results for the controller applied to the nonlinear problem demonstrate the performance of the method.

Conductometric method for determining water stability and nutrient leaching of extruded fish feed

Directory of Open Access Journals (Sweden)

Banjac Vojislav V.

2017-01-01

Full Text Available Water stability of eight samples of extruded salmon feeds was first determined by applying two gravimetric methods developed by the authors: gravimetric static and wet sieving method. Then, the conductometric method, primarily developed for investigation of nutrient leaching of feed into the water by the authors, was used for each sample. The aim of this study was to evaluate the potential of the conductometric measurement as a technique for determining water stability of extruded fish feed. In order to find any correlation between the results of two gravimetric tests and conductometric method, correlation analysis was employed. The results of static and wet sieving method were expressed as water stability index, which was expressed as the percent of remained dry matter of sample after being disintegrated in the water. The results of conductometric method were shown as conductivity curves for each sample, giving the insight in rate of nutrient leaching during the time. The obtained values of water conductivity showed no significant (p < 0.05 correlation with the results of static water method, while there was a negative significant (p < 0.05 correlation with the results of wet sieving method during first four hours of pellets soaking in water. The highest correlation coefficients were obtained within the first hour of conductivity measurement, demonstrating that proposed conductometric method had a potential to be applied as a rapid and simple method for determination and relative comparison of salmon feed water stability.[ Project of the Serbian Ministry of Education, Science and Technological Development, Grant no. III46012 and Grant no. TR31011

Stability of the barium–benzo-15-crown-5 complex in nitrobenzene saturated with water

Directory of Open Access Journals (Sweden)

E. MAKRLÍK

2006-11-01

Full Text Available From extraction experiments and g-activity measurements, the exchange extraction constant corresponding to the equilibrium Ba2+(aq + SrL22+(nb D BaL22+(nb + Sr2+(aq occurring in the two-phase water–nitrobenzene system (L =benzo-15-crown-5; aq = aqueous phase, nb = nitrobenzene phase was evaluated as log Kex (Ba2+, SrL22+ = 0.3 ± 0.1. Furthermore, the stability constant of the benzo-15-crown-5–barium complex in nitrobenzene saturated with water was calculated for the temperature of 25 °C: log bnb (BaL22+=13.3±0.1.

Design of Water Temperature Control System Based on Single Chip Microcomputer

Science.gov (United States)

Tan, Hanhong; Yan, Qiyan

2017-12-01

In this paper, we mainly introduce a multi-function water temperature controller designed with 51 single-chip microcomputer. This controller has automatic and manual water, set the water temperature, real-time display of water and temperature and alarm function, and has a simple structure, high reliability, low cost. The current water temperature controller on the market basically use bimetal temperature control, temperature control accuracy is low, poor reliability, a single function. With the development of microelectronics technology, monolithic microprocessor function is increasing, the price is low, in all aspects of widely used. In the water temperature controller in the application of single-chip, with a simple design, high reliability, easy to expand the advantages of the function. Is based on the appeal background, so this paper focuses on the temperature controller in the intelligent control of the discussion.

Formulation and stability of topical water in oil emulsion containing ...

African Journals Online (AJOL)

Purpose: To formulate the water in oil (W/O) emulsion of corn silk (CS) extract and to evaluate its stability at various storage conditions. Methods: Ethanol CS extract was prepared using maceration (cold) technique. A 4 % CS emulsion was prepared using varying concentrations of liquid paraffin, ABIL EM90 and water.

Hydrogen production by high-temperature electrolysis of water vapor steam. Test results obtained with an electrolysis tube

International Nuclear Information System (INIS)

Hino, Ryutaro; Miyamoto, Yoshiaki

1995-01-01

High-temperature electrolysis of water vapor steam is an advanced hydrogen production process decomposing high temperature steam up to 1,000degC, which applies an electro-chemical reaction reverse to the solid oxide fuel cell. At Japan Atomic Energy Research Institute, laboratory-scale experiments have been conducted using a practical electrolysis tube with 12 electrolysis cells in order to develop heat utilization systems for high-temperature gas-cooled reactors. The electrolysis cells of which electrolyte was yttria-stabilized zirconia were formed on a porous ceramic tube in series by plasma spraying. In the experiments, water steam mixed with argon carrier gas was supplied into the electrolysis tube heated at a constant temperature regulated in the range from 850degC to 950degC, and electrolysis power was supplied by a DC power source. Hydrogen production rate increased with applied voltage and electrolysis temperature; the maximum production rate was 6.9Nl/h at 950degC. Hydrogen production rate was correlated with applied current densities on the basis of experimental data. High energy efficiency was achieved under the applied current density ranging from 80 to 100 mA/cm 2 . (author)

Behavior of tungsten carbide in water stabilized plasma

Czech Academy of Sciences Publication Activity Database

Brožek, Vlastimil; Matějíček, Jiří; Neufuss, Karel

2007-01-01

Roč. 7, č. 4 (2007), s. 213-220 ISSN 1335-8987 R&D Projects: GA ČR(CZ) GA104/05/0540 Institutional research plan: CEZ:AV0Z20430508 Keywords : water stabilized plasma * tungsten carbide * tungsten hemicarbide * decarburization Subject RIV: BL - Plasma and Gas Discharge Physics

Water temperature impacts water consumption by range cattle in winter

Science.gov (United States)

Water consumption and DMI have been found to be positively correlated, which may interact with ingestion of cold water or grazed frozen forage due to transitory reductions in temperature of ruminal contents. The hypothesis underpinning the study explores the potential that cows provided warm drinkin...

Stabilization of temperature during magnetic hyperthermia by Ce substituted magnetite nanoparticles

Energy Technology Data Exchange (ETDEWEB)

Shaw, S.K.; Alla, S.K. [Department of Metallurgical Engineering, Indian Institute of Technology (Banaras Hindu University), Varanasi 221005 (India); Meena, S.S. [Solid State Physics Division, Bhabha Atomic Research Centre, Mumbai 400085 (India); Mandal, R.K. [Department of Metallurgical Engineering, Indian Institute of Technology (Banaras Hindu University), Varanasi 221005 (India); Prasad, N.K., E-mail: nandkp.met@iitbhu.ac.in [Department of Metallurgical Engineering, Indian Institute of Technology (Banaras Hindu University), Varanasi 221005 (India)

2017-07-15

Highlights: • Ce{sub x}Fe{sub 3−x}O{sub 4} (0.01 ≤ x ≤ 0.5) nanoparticles below 15 nm were synthesized by microwave refluxing method. • The saturation magnetization decreased with increased Ce concentration. • The sample displayed stabilization of temperature near 42 °C during magnetic hyperthermia. - Abstract: We report here magnetic hyperthermia using nanoparticles of Ce{sub x}Fe{sub 3−x}O{sub 4} (x = 0.01, 0.05, 0.1, 0.3 and 0.5) during which temperature was found to be stabilizing near 42 °C. This happens despite of their high saturation magnetization (M{sub S}) and Curie temperature (T{sub C}) values. It was observed that by selecting an appropriate magnetic field the temperature can be rose exactly near the therapeutic temperature and thus it will help to selectively kill the cancerous cells leaving normal cells unaffected. These nanoparticles (size around 8–15 nm) were produced by single step microwave refluxing technique. X-ray diffraction (XRD) analysis demonstrates that samples were essentially single phase except for x = 0.5 sample. The X-ray photoelectron spectroscopy (XPS) study for the samples demonstrated that Ce was present in both Ce{sup 3+} and Ce{sup 4+} states. The saturation magnetization value of the samples decreased sharply from 62 Am{sup 2}/kg for x = 0.01 to 19 Am{sup 2}/kg for x = 0.1. This value further decreased with increased Ce doping.

Water Recycling removal using temperature-sensitive hydronen

Energy Technology Data Exchange (ETDEWEB)

Rana B. Gupta

2002-10-30

The overall objective of this project was to study the proposed Water Recycling/Removal Using Temperature-Sensitive Hydrogels. The main element of this technology is the design of a suitable hydrogel that can perform needed water separation for pulp and paper industry. The specific topics studied are to answer following questions: (a) Can water be removed using hydrogel from large molecules such as lignin? (b) Can the rate of separation be made faster? (c) What are the molecular interactions with hydrogel surface? (d) Can a hydrogel be designed for a high ionic strength and high temperature? Summary of the specific results are given.

Hydraulic Properties of Porous Media Saturated with Nanoparticle-Stabilized Air-Water Foam

Directory of Open Access Journals (Sweden)

Xianglei Zheng

2016-12-01

Full Text Available The foam generated by the mixture of air and water has a much higher viscosity and lower mobility than those of pure water or gas that constitutes the air-water foam. The possibility of using the air-water foam as a flow barrier for the purpose of groundwater and soil remediation is explored in this paper. A nanoparticle-stabilized air-water foam was fabricated by vigorously stirring the nano-fluid in pressurized condition. The foam bubble size distribution was analyzed with a microscope. The viscosities of foams generated with the solutions with several nanoparticle concentrations were measured as a function of time. The breakthrough pressure of foam-saturated microfluidic chips and sand columns were obtained. The hydraulic conductivity of a foam-filled sand column was measured after foam breakthrough. The results show that: (1 bubble coalescence and the Ostwald ripening are believed to be the reason of bubble size distribution change; (2 the viscosity of nanoparticle-stabilized foam and the breakthrough pressures decreased with time once the foam was generated; (3 the hydraulic conductivity of the foam-filled sand column was almost two orders of magnitude lower than that of a water-saturated sand column even after the foam-breakthrough. Based on the results in this study, the nanoparticle-stabilized air-water foam could be injected into contaminated soils to generate vertical barriers for temporary hydraulic conductivity reduction.

Reaction of PFCs in water stabilized plasma

Czech Academy of Sciences Publication Activity Database

Mastný, L.; Horníček, J.; Živný, Oldřich; Brožek, Vlastimil; Sember, Viktor

2017-01-01

Roč. 13, č. 1 (2017), s. 161 ISSN 1336-7242. [Zjazd chemikov /69./. 11.09.2017-15.09.2017, Horný Smokovec] R&D Projects: GA ČR(CZ) GC17-10246J Institutional support: RVO:61389021 Keywords : Water stabilized plasma * tetrafluoromethane * corrosion resistance * boron nitride * titanium nitride Subject RIV: BL - Plasma and Gas Discharge Physics OBOR OECD: Fluids and plasma physics (including surface physics)

Soil Water and Temperature System (SWATS) Instrument Handbook

Energy Technology Data Exchange (ETDEWEB)

Cook, David R. [Argonne National Lab. (ANL), Argonne, IL (United States)

2016-04-01

The soil water and temperature system (SWATS) provides vertical profiles of soil temperature, soil-water potential, and soil moisture as a function of depth below the ground surface at hourly intervals. The temperature profiles are measured directly by in situ sensors at the Central Facility and many of the extended facilities of the U.S. Department of Energy (DOE)’s Atmospheric Radiation Measurement (ARM) Climate Research Facility Southern Great Plains (SGP) site. The soil-water potential and soil moisture profiles are derived from measurements of soil temperature rise in response to small inputs of heat. Atmospheric scientists use the data in climate models to determine boundary conditions and to estimate the surface energy flux. The data are also useful to hydrologists, soil scientists, and agricultural scientists for determining the state of the soil.

Organic acid formation in steam–water cycles: Influence of temperature, retention time, heating rate and O2

International Nuclear Information System (INIS)

Moed, D.H.; Verliefde, A.R.D.; Heijman, S.G.J.; Rietveld, L.C.

2014-01-01

Organic carbon breaks down in boilers by hydrothermolysis, leading to the formation of organic acid anions, which are suspected to cause corrosion of steam–water cycle components. Prediction of the identity and quantity of these anions, based on feedwater organic carbon concentrations, has not been attempted, making it hard to establish a well-founded organic carbon guideline. By using a batch-reactor and flow reactor, the influence of temperature (276–352 °C), retention time (1–25 min), concentration (150–2400 ppb) and an oxygen scavenger (carbohydrazide) on organic acid anion formation from organic carbon was investigated. By comparing this to data gathered at a case-study site, the validity of setups was tested as well. The flow reactor provided results more representative for steam–water cycles than the batch reactor. It was found that lower heating rates give more organic acid anions as degradation products of organic carbon, both in quantity and species variety. The thermal stability of the organic acid anions is key. As boiler temperature increases, acetate becomes the dominant degradation product, due to its thermal stability. Shorter retention times lead to more variety and quantity of organic acid anions, due to a lack of time for the thermally less stable ones to degrade. Reducing conditions (or the absence of oxygen) increase the thermal stability of organic acid anions. As the feedwater organic carbon concentration decreases, there are relatively more organic acid anions formed. - Highlights: •Formation of organic acids from hydrothermolysis of organic carbon has been investigated. •The lower the temperature, the higher the variety of organic acid anions. •At the higher tested temperatures (331–352 °C) acetate is the dominant degradation product. •At longer retention times acetate is the dominant degradation product. •There is no linear relation between the organic carbon concentration and formed organic acids

A method to stabilize the temperature dependent performance of G-APD arrays

Energy Technology Data Exchange (ETDEWEB)

Huh, Yoonsuk [Molecular Imaging Research and Education (MiRe) Laboratory, Department of Electronic Engineering, Sogang University, Seoul (Korea, Republic of); Sungkyunkwan University, School of Medicine, Seoul (Korea, Republic of); Choi, Yong; Ho Jung, Jin; Jung, Jiwoong [Molecular Imaging Research and Education (MiRe) Laboratory, Department of Electronic Engineering, Sogang University, Seoul (Korea, Republic of)

2015-02-01

This paper presents a compensation method to stabilize the temperature dependent performance of Geiger-mode Avalanche Photodiode (G-APD) arrays for Positron Emission Tomography (PET). The compensation method is used to identify the bias voltage range that provides stable performance even at different temperatures using the G-APD’s characteristics, and to control the photo-peak variation as a function of temperature using the preamplifier gain within the identified bias voltage range. A pair of G-APD detectors and temperature sensors were located in the temperature chamber and the preamplifiers which can control the gain of the detectors using the digital potentiometer were positioned outside the chamber. The performance of the G-APD detector, especially energy resolution and coincidence timing resolution, was characterized as a function of bias voltage at different temperatures from 20 °C to 40 °C at 5 °C increments; the energy resolution, coincidence timing resolution, and photo-peak position of all channels of G-APD PET detectors before and after the preamplifier gain correction were then measured and compared. The results of this study demonstrated that the optimal bias voltage range providing the good energy and coincidence timing resolution, 12.1±1.2% and 1.30±0.09 ns, respectively, could be identified at the temperature range and the photo-peak variation and the performance at different temperatures could be stabilized by adjusting the preamplifier gain within the identified bias voltage range. We concluded the proposed method to be reliable and useful for the development of the PET system using G-APD arrays.

Dynamic Stabilization of Metal Oxide–Water Interfaces

Energy Technology Data Exchange (ETDEWEB)

McBriarty, Martin E.; von Rudorff, Guido Falk; Stubbs, Joanne; Eng, Peter; Blumberger, Jochen; Rosso, Kevin M.

2017-02-08

Metal oxide growth, dissolution, and redox reactivity depend on the structure and dynamics at the interface with aqueous solution. We present the most definitive analysis to date of the hydrated naturally abundant r-cut (11$\\bar{0}$2) termination of the iron oxide hematite (α-Fe₂O₃). In situ synchrotron X-ray scattering analysis reveals a ridged lateral arrangement of adsorbed water molecules hydrogen bonded to terminal aquo groups. Large-scale hybrid-functional density functional theory-based molecular dynamics (DFT-MD) simulations show how this structure is dynamically stabilized by picosecond exchange between aquo groups and adsorbed water, even under nominally dry conditions. Surface pKa prediction based on bond valence analysis suggests that water exchange may influence the proton transfer reactions associated with acid/base reactivity at the interface. Our findings rectify inconsistencies between existing models and may be extended to resolving more complex electrochemical phenomena at metal oxide-water interfaces.

Silicon photomultiplier's gain stabilization by bias correction for compensation of the temperature fluctuations

International Nuclear Information System (INIS)

Dorosz, P.; Baszczyk, M.; Glab, S.; Kucewicz, W.; Mik, L.; Sapor, M.

2013-01-01

Gain of the silicon photomultiplier is strongly dependent on the value of bias voltage and temperature. This paper proposes a method for gain stabilization just by compensation of temperature fluctuations by bias correction. It has been confirmed that this approach gives good results and the gain can be kept very stable

Advances in high temperature water chemistry and future issues

International Nuclear Information System (INIS)

Millett, P.J.

2005-01-01

This paper traces the development of advances in high temperature water chemistry with emphasis in the field of nuclear power. Many of the water chemistry technologies used in plants throughout the world today would not have been possible without the underlying scientific advances made in this field. In recent years, optimization of water chemistry has been accomplished by the availability of high temperature water chemistry codes such as MULTEQ. These tools have made the science of high temperature chemistry readily accessible for engineering purposes. The paper closes with a discussion of what additional scientific data and insights must be pursued in order to support the further development of water chemistry technologies for the nuclear industry. (orig.)

Water temperature in irrigation return flow from the Upper Snake Rock watershed

Science.gov (United States)

Water returning to a river from an irrigated watershed could increase the water temperature in the river. The objective of this study was to compare the temperature of irrigation return flow water with the temperature of the diverted irrigation water. Water temperature was measured weekly in the mai...

Structural stability of high entropy alloys under pressure and temperature

DEFF Research Database (Denmark)

Ahmad, Azkar S.; Su, Y.; Liu, S. Y.

2017-01-01

The stability of high-entropy alloys (HEAs) is a key issue before their selection for industrial applications. In this study, in-situ high-pressure and high-temperature synchrotron radiation X-ray diffraction experiments have been performed on three typical HEAs Ni20Co20Fe20Mn20Cr20, Hf25Nb25Zr25Ti...

Temperature dependence of water-water and ion-water correlations in bulk water and electrolyte solutions probed by femtosecond elastic second harmonic scattering

Science.gov (United States)

Chen, Yixing; Dupertuis, Nathan; Okur, Halil I.; Roke, Sylvie

2018-06-01

The temperature dependence of the femtosecond elastic second harmonic scattering (fs-ESHS) response of bulk light and heavy water and their electrolyte solutions is presented. We observe clear temperature dependent changes in the hydrogen (H)-bond network of water that show a decrease in the orientational order of water with increasing temperature. Although D2O has a more structured H-bond network (giving rise to more fs-ESHS intensity), the relative temperature dependence is larger in H2O. The changes are interpreted in terms of the symmetry of H-bonds and are indicators of nuclear quantum effects. Increasing the temperature in electrolyte solutions decreases the influence of the total electrostatic field from ions on the water-water correlations, as expected from Debye-Hückel theory, since the Debye length becomes longer. The effects are, however, 1.9 times (6.3 times) larger than those predicted for H2O (D2O). Since fs-ESHS responses can be computed from known molecular coordinates, our observations provide a unique opportunity to refine quantum mechanical models of water.

The study of stability, combustion characteristics and performance of water in diesel emulsion fuel

Directory of Open Access Journals (Sweden)

Syafiq Zulkifli

2017-01-01

Full Text Available A single cylinder diesel engine study of water in diesel emulsions was conducted to investigate the stability effect of emulsion fuel on three different fuel blends and the water emulsification effect on the engine performance. Emulsified fuels contained 2% of surfactant including Span 80 Tween 80 and tested 10 HLB number. The blends also varied of 5%, 10% and 15% of water in diesel ratios namely as BSW5, BSW10 and BSW15. The fuel blends performance was tested using a single cylinder, direct injection diesel engine, operating at 1860 rpm. The results on stability reveal that high shear homogenizer yields more stability on emulsion fuel than mechanical stirrer and ultrasonic water bath. The engine performance results show that the ignition delay and peak pressure increase with the increment of water percentage up to 15%. However, the results indicate the increment of water percentage is also shows a significant decrease in engine power.

Water-stability of soil aggregates in relation to selected properties

International Nuclear Information System (INIS)

Mbagwu, J.S.C.; Bazzoffi, P.; Unamba Oparah, I.

1995-03-01

The stability of soil aggregates in water is an important soil physical property for evaluating the potential of agricultural soils to erode and elucidating the mechanisms of soil erosion. In this study we used aggregates from 15 surface soil samples in Italy to evaluate the influence of intrinsic soil physical, chemical and mineralogical properties on aggregates stability (AS). The aim was to develop a model for predicting AS from a subset of these soil properties. The index of stability used is the mean-weight diameter of water-stable aggregates (MWD). The model developed with soil physical properties alone explained just 42% of variance in MWD and predicted AS in only 20% of test soils. The model developed with mineralogical properties alone explained 70% of variance in MWD and predicted AS in 60% of the test soils. The chemical properties - based model explained 90% of variance in MWD and predicted AS in 80% of the test soils. The best-fit model was developed with soil properties from the physical, chemical and mineralogical subsets. It explained 98% of variance in MWD and predicted AS in 100% of the test soils. This model shows that the most important soil properties which influence the AS of these soils include ratio of total sand to clay, concentrations of iron oxide, magnesium oxide, organic matter, silica/alumina ratio, chlorite, feldspar and muscovite. This indicates that fairly good estimates of the relative stability of these aggregates in water and hence of their potential to erode, requires a knowledge of the physico-chemical and mineralogical properties. (author). 40 refs, 4 tabs

The sublethal effects of zinc at different water temperatures on ...

African Journals Online (AJOL)

The sublethal effects of zinc at different water temperatures on selected ... of 96h at different water temperatures representing the seasonal temperatures in the ... are mobilised to meet increased energy demands during periods of stress.

Analysis of the structural stability of the smectite submitted to high pressures and temperatures; Analise da estabilidade estrutural da esmectita sob altas pressoes e altas temperaturas

Energy Technology Data Exchange (ETDEWEB)

Alabarse, Frederico Gil

2009-10-15

The thermal stability of bentonite is of particular interest for containment barrier in nuclear waste disposal facilities. However, very little is known about the stability of smectite (principal component of bentonite) under high-pressure and high-temperature conditions (HPHT). The objective of this work was to investigate the stability of the smectite structure under HP-HT conditions. The HP-HT experiments were performed on toroidal chambers (TC) with pressure up 7.7 GPa and temperatures of 1000 deg C. The samples were characterized by X-ray diffraction after the HP-HT processing. Furthermore, one sample from the original material was analyzed using Fourier transformed infra-red (FTIR) in situ measurements on a diamond anvil cell (DAC) in experiments up to 12 GPa. The original sample of bentonite, calcium dioctahedral montmorillonite with small fraction of quartz, was characterized by FTIR, XRD, X-ray fluorescence (XRF), scanning electron microscopy (SEM), surface area, thermogravimetric analysis (TGA) and differential thermal analysis (DTA). In the experiment performed using the DAC up to 12 GPa, the FTIR in situ measurements analysis showed that the smectite structure is stable with a reversible deformation in the Si-O bond and that the smectite did not loose water. Experiments performed in TC at 7.7 GPa of pressure and 250 deg C of temperature, during 3.5 h showed, after analysis by XRD and FTIR, that the smectite structure is stable and did not loose water. Experiments performed in TC at 7.7 GPa of pressure and 1000 deg C of temperature, during 3.5 h showed, after analysis by XRD and SEM, the transformation of bentonite to the mineral assemblage: Coesite, Quartz, Kyanite and Pyrope. (author)

The effect of water temperature and water hardness on reproductive indicators Hemichromis lifalili

Directory of Open Access Journals (Sweden)

Ján Kopecký

2014-05-01

Full Text Available In this work we investigated the effect of temperature and water hardness on reproductive indicators Hemichromis lifalili in aquarium conditions. From bred individuals we have compiled three breeding pairs, which we placed in aquariums with different temperature and water hardness. In experimental pairs, we evaluated these reproductive variables: number of spawning eggs, the number of hatched, dead and bred individuals. Experiments showed that 28 °C, and 8 °N water hardness increased the reproductive activity of fish and the quantity of fish hatched. Decreasing temperature in the tanks was proportionally increased the number of unhatched individuals, and the mortality. The mortality was 88 pieces per swab at 25 °C. Water at 28 °C and 8 °N hardness was reached swab to 1200 eggs pieces.

Wellbore stability in shales considering chemo-poroelastic effects

Energy Technology Data Exchange (ETDEWEB)

Araujo, Ewerton M.P.; Pastor, Jorge A.S.C.; Fontoura, Sergio A.B.; Rabe, Claudio [Pontificia Univ. Catolica do Rio de Janeiro (PUC-Rio), RJ (Brazil). Dept. de Engenharia Civil. Grupo de Tecnologia e Engenharia de Petroleo

2004-07-01

Under compaction and low geothermal gradients are deep water characteristics. Both under compaction and low geothermal gradients generate considerable thickness of smectite-rich shales. These rocks are the major source of wellbore stability problems, because they are susceptible to adverse physico-chemical reactions when in contact with inadequate drilling fluids. Due shales are low permeability rocks diffusion processes dominate the changes of pore pressure around wellbore. Diffusion of fluids, ions and temperature occurs in shales during drilling and demand a fully coupled modelling taking account these factors. Despite temperature importance, in this paper wellbore stability in shales is analyzed through a model that considers only the coupling between poroelastic and physico-chemical effects. The coupled equations are solved analytically and have been implemented in a computational simulator with user-friendly interface. Time-dependent simulations of wellbore stability in shales are presented for a typical deep water scenario. The results show that physico-chemical effects change pore pressure around wellbore and have high impact on the wellbore stability. (author)

Stability of niclosamide in water under local conditions

International Nuclear Information System (INIS)

El Hindi, A.M.; Sidra, M.S.

1986-01-01

The stability of 14 C-labelled niclosamide was studied in distilled water at two different pH values and in canal water. 2 mg/1 niclosamide solutions were exposed to direct atmospheric conditions. The activity was followed by radioassay and the concentration of niclosamide was determined by GLC. The total activity was found to decrease to 46.0% in weakly acidic solution (pH 6.5), 45% in neutral solution (pH 7.0) and 16.7% in filtered canal water after three weeks. GLC analysis showed that niclosamide concentration had dropped to 0.05, 0.06 and 0.03 mg/1 in weakly acidic, neutral medium and canal water after the same period. GLC analysis as compared to radioassay indicated the presence of increasing amounts of degradation product(s), in the chloroform extracts of water with time, which were not detected by GLC

Thermal and stability considerations for a supercritical water-cooled fast reactor during power-raising phase of plant startup

International Nuclear Information System (INIS)

Cai, Jiejin; Ishiwatari, Yuki; Oka, Yoshiaki; Ikejiri, Satoshi

2009-01-01

This paper describes thermal analyses and linear stability analyses of the Supercritical Water-cooled Fast Reactor with 'two-path' flow scheme during the power-raising phase of plant startup. For thermal consideration, the same criterion of the maximum cladding surface temperature (MCST) as applied to the normal operating condition is used. For thermal-hydraulic stability consideration, the decay ratio of 0.5 is applied, which is taken from BWRs. Firstly, we calculated the flow rate distribution among the parallel flow paths from the reactor vessel inlet nozzles to the mixing plenum below the core using a system analysis code. The parallel flow paths consist of the seed fuel assemblies cooled by downward flow, the blanket fuel assemblies cooled by downward flow and the downcomer. Then, the MCSTs are estimated for various reactor powers and feedwater flow rates with system analyses. The decay ratios are estimated with linear stability analyses. The available range of the reactor power and feedwater flow rate to satisfy the thermal and stability criteria is obtained. (author)

Thermal Stability and Proton Conductivity of Rare Earth Orthophosphate Hydrates

DEFF Research Database (Denmark)

Anfimova, Tatiana; Li, Qingfeng; Jensen, Jens Oluf

2014-01-01

as the rhabdophane structure is preserved. The bound hydrate water is accommodated in the rhabdophane structure and is stable at temperatures of up to 650 oC. The thermal stability of the hydrate water and the phosphate structure are of significance for the proton conductivity. The LaPO4·0.6H2O and NdPO4•0.5H2O......Hydrated orthophosphate powders of three rare earth metals, lanthanum, neodymium and gadolinium, were prepared and studied as potential proton conducting materials for intermediate temperature electrochemical applications. The phosphates undergo a transformation from the rhabdophane structure...... to the monazite structure upon dehydration. The thermal stability of the hydrate is studied and found to contain water of two types, physically adsorbed and structurally bound hydrate water. The adsorbed water is correlated to the specific surface area and can be reversibly recovered when dehydrated as long...

Microstructure and high temperature stability of age hardenable AA2219 aluminium alloy modified by Sc, Mg and Zr additions

Energy Technology Data Exchange (ETDEWEB)

Naga Raju, P. [Metallurgical and Materials Engineering Department, IIT-Madras, Chennai 600036 (India)], E-mail: puvvala_nagaraju@yahoo.com; Srinivasa Rao, K. [Metallurgical Engineering Department, Andhra University, Visakapatnam 530003 (India); Reddy, G.M. [Defence Metallurgical Research Laboratory, Hyderabad 500258 (India); Kamaraj, M.; Prasad Rao, K. [Metallurgical and Materials Engineering Department, IIT-Madras, Chennai 600036 (India)

2007-08-25

The present work pertains to the improvement of high temperature stability of age hardenable AA2219 aluminium-copper (6.3%) alloy. Addition of scandium, magnesium and zirconium to the base metal AA2219 was adopted to improve this high temperature stability. These additions were systematically varied by preparing alloys of different composition using gas tungsten arc melting. Long time ageing studies and impression creep technique were used to study the high temperature stability of the alloys. These modified compositions of the alloy resulted in fine equiaxed grains, refined eutectics, large number of high temperature stable and finer precipitates. Among all the compositions, 0.8% Sc + 0.45% Mg + 0.2% Zr addition was found to be significant in improving the high temperature stability of AA2219 alloy. This may be attributed to the possible microstructural changes, solute enrichment of the matrix and pinning of the grain boundaries by the finer precipitates.

Method for stabilizing low-level mixed wastes at room temperature

Science.gov (United States)

Wagh, Arun S.; Singh, Dileep

1997-01-01

A method to stabilize solid and liquid waste at room temperature is provided comprising combining solid waste with a starter oxide to obtain a powder, contacting the powder with an acid solution to create a slurry, said acid solution containing the liquid waste, shaping the now-mixed slurry into a predetermined form, and allowing the now-formed slurry to set. The invention also provides for a method to encapsulate and stabilize waste containing cesium comprising combining the waste with Zr(OH).sub.4 to create a solid-phase mixture, mixing phosphoric acid with the solid-phase mixture to create a slurry, subjecting the slurry to pressure; and allowing the now pressurized slurry to set. Lastly, the invention provides for a method to stabilize liquid waste, comprising supplying a powder containing magnesium, sodium and phosphate in predetermined proportions, mixing said powder with the liquid waste, such as tritium, and allowing the resulting slurry to set.

Temperature measurements in a wall stabilized steady flame using CARS

KAUST Repository

Sesha Giri, Krishna; Lacoste, Deanna; Damazo, Jason; Kwon, Eddie; Roberts, William L.

2017-01-01

-Stokes Raman Scattering (CARS) thermometry as close as 275 μm to a convex wall cooled with water has been carried out. The standard deviation of mean temperatures is observed to be ~6.5% for high temperatures (>2000K) and ~14% in the lower range (<500K

Negative feedback mechanism for the long-term stabilization of earth's surface temperature

International Nuclear Information System (INIS)

Walker, J.C.G.; Hays, P.B.; Kasting, J.F.

1981-01-01

We suggest that the partial pressure of carbon dioxide in the atmosphere is buffered, over geological time scales, by a negative feedback mechanism in which the rate of weathering of silicate minerals (followed by deposition of carbonate minerals) depends on surface temperature, and surface temperature, in turn, depends on carbon dioxide partial pressure through the green effect. Although the quantitative details of this mechanism are speculative, it appears able partially to stabilize earth's surface temperature against the steady increase of solar luminosity believed to have occured since the origin of the solar system

Water-temperature data acquisition activities in the United States

Science.gov (United States)

Pauszek, F.H.

1972-01-01

Along with the growing interest in water quality during the last decade, the need for data on all types of water-quality parameters has also increased. One parameter of particular interest, because of its many ramifications, is temperature. It influences many of the chemical and physical processes that take place in water. The solubility of gases--for example, oxygen and carbon dioxide--and the solution of mineral matter in water are functions of temperature. Such physical properties as density and viscosity vary with temperature. Oxidation of organic materials, as well as algal and bacterial growth, is promoted or retarded by favorable or unfavorable temperatures. Further, temperature bears on the utility of water: as a source of public water supplies; for industrial use, particularly if the water is used for cooling; and in the field of recreation involving contact sports, fishing, and fish culture. In recent years, temperature changes resulting from inflow of heated industrial waste, particularly effluent from power generating plants, have increased the need for temperature data to determine the degree of change, its effect on ecology, and the effect of any remedial action. Thus, because of the many extensive and intensive effects, a large amount of temperature data is collected on surface and ground waters by many agencies throughout the country. Moreover, because of its importance, there is a widespread interest in temperature even by those who are not active collectors of the data themselves. The industrialist, the manager, the public official, and others at one time or another may have need for temperature data and may well raise the questions: Who is collecting temperature data? What is the extent of the activity? Where are the data being collected? The purpose of this report is to answer these questions. The information in the report is confined to the activities of Federal and non-Federal agencies. It is based on information furnished to the Office of

Stability of the ammonium-p-tert-butylcalix[4]arene-tetrakis (N,N-diethylacetamide) complex in nitrobenzene saturated with water

International Nuclear Information System (INIS)

Makrlik, E.

2006-01-01

From extraction experiments and γ-activity measurements, the extraction constant corresponding to the equilibrium NH 4 + (aq)+NaL + (nb) ↔ NH 4 L + (nb)+Na + (aq) taking place in the two-phase water-nitrobenzene system (L = p-tert-butylcalix[4]arene-tetrakis (N,N-diethylacetamide); aq = aqueous phase, nb = nitrobenzene phase) was evaluated as logK ex (NH 4 + ,NaL + ) = -1.8. Further, the stability constant of the p-tert-butylcalix[4]arene-tetrakis (N,N-diethylacetamide)-ammonium complex in nitrobenzene saturated with water was calculated for a temperature of 25 deg C: logβ nb (NH 4 L + ) = 6.7. (author)

Carbon exchange in biological soil crust communities under differential temperatures and soil water contents: implications for global change

Science.gov (United States)

Grote, Edmund E.; Belnap, Jayne; Housman, David C.; Sparks, Jed P.

2010-01-01

Biological soil crusts (biocrusts) are an integral part of the soil system in arid regions worldwide, stabilizing soil surfaces, aiding vascular plant establishment, and are significant sources of ecosystem nitrogen and carbon. Hydration and temperature primarily control ecosystem CO2 flux in these systems. Using constructed mesocosms for incubations under controlled laboratory conditions, we examined the effect of temperature (5-35 1C) and water content (WC, 20-100%) on CO2 exchange in light cyanobacterially dominated) and dark cyanobacteria/lichen and moss dominated) biocrusts of the cool Colorado Plateau Desert in Utah and the hot Chihuahuan Desert in New Mexico. In light crusts from both Utah and New Mexico, net photosynthesis was highest at temperatures 430 1C. Net photosynthesis in light crusts from Utah was relatively insensitive to changes in soil moisture. In contrast, light crusts from New Mexico tended to exhibit higher rates of net photosynthesis at higher soil moisture. Dark crusts originating from both sites exhibited the greatest net photosynthesis at intermediate soil water content (40-60%). Declines in net photosynthesis were observed in dark crusts with crusts from Utah showing declines at temperatures 425 1C and those originating from New Mexico showing declines at temperatures 435 1C. Maximum net photosynthesis in all crust types from all locations were strongly influenced by offsets in the optimal temperature and water content for gross photosynthesis compared with dark respiration. Gross photosynthesis tended to be maximized at some intermediate value of temperature and water content and dark respiration tended to increase linearly. The results of this study suggest biocrusts are capable of CO2 exchange under a wide range of conditions. However, significant changes in the magnitude of this exchange should be expected for the temperature and precipitation changes suggested by current climate models.

Effects of sodium caseinate concentration and storage conditions on the oxidative stability of oil-in-water emulsions.

Science.gov (United States)

O' Dwyer, Sandra P; O' Beirne, David; Eidhin, Deirdre Ní; O' Kennedy, Brendan T

2013-06-01

The oxidative stability of various oils (sunflower, camelina and fish) and 20% oil-in-water (O/W) emulsions, were examined. The mean particle size decreased from 1179 to 325 nm as sodium caseinate (emulsifier) concentration was increased from 0.25% to 3% in O/W emulsions (Psodium caseinate concentration increased, and similarly decreased as microfluidisation pressure increased (P<0.05). Increasing storage temperature of the emulsions from 5 to 60°C, resulted in lower detectable lipid oxidation products during storage (P<0.05). Copyright © 2012 Elsevier Ltd. All rights reserved.

Radiation synthesis of a water-soluble temperature sensitive polymer, activated copolymer and applications in immobilization of proteins

International Nuclear Information System (INIS)

Zhai Maolin; Ha Hongfei; Wu Jilan

1993-01-01

In this work the radiation polymerization of N-isopropylacrylamide (NIPAAM) in aqueous solutions has been carried out and a water-soluble, temperature sensitive polymer and copolymer were obtained by using γ-rays from Co-60 source at room temperature. We have gained the optimum dose and dose-rate of radiation synthesis of linear polyNIPAAM through determining conversion yield and viscosity. In order to immobilize protein (BSA) and enzyme (HRP) into this water-soluble polymer, we prepared an activated copolymer, poly(N-isopropylacrylamide-co-N-acryloxysuccinimide). The BSA and HRP has been immobilized onto the activated copolymer. The BSA (HRP)/copolymer conjugates still kept the original thermally sensitive properties of the linear polyNIPAAM. The conjugation yield of BSA to the activated copolymer decreased with increasing dose. Immobilized HRP was stable at 0 o C for a long time and has, at least, 4 days stability at room temperature. Immobilized HRP activity was lowered when the temperature was raised. This phenomenon was reversible and the immobilized HRP regained activity. The optimum pH of the immobilized HRP shifted from ca.5 upward to ca. 7. (author)

A Microfluidic Method to Assess Emulsion Stability in Crude-Oil/Water Separators

NARCIS (Netherlands)

Krebs, T.; Schroën, C.G.P.H.; Boom, R.M.

2011-01-01

The control of emulsion stability and droplet size is of crucial importance for oil production, especially for the processes of crude/oil water separation and cleanup of produced water. To recover pure oil and water, coalescence between droplets needs to take place, the extent of which will depend

Measurements of hot water service consumptions: temperature influence

Energy Technology Data Exchange (ETDEWEB)

Secchi, R.; Vallat, D.; Cyssau, R. (COSTIC, Saint Remy-les-Chevreuse (France))

This article presents a campaign of measurements of which the aim is the observation of consumptions, for individual installations equiped with a hot water tank. The study takes an interest in the temperature of the water in the tank and the instantaneous power of the generator. The instrumentation, the installations and the results of this campaign are presented in this paper. The conclusion is the ''economic'' temperature of hot sanitary water is below 60/sup 0/C but above 55/sup 0/C.

Low temperature barrier wellbores formed using water flushing

Science.gov (United States)

McKinzie, II; John, Billy [Houston, TX; Keltner, Thomas Joseph [Spring, TX

2009-03-10

A method of forming an opening for a low temperature well is described. The method includes drilling an opening in a formation. Water is introduced into the opening to displace drilling fluid or indigenous gas in the formation adjacent to a portion of the opening. Water is produced from the opening. A low temperature fluid is applied to the opening.

Development of solid electrolytes for water electrolysis at intermediate temperatures. Task 3 report; Annual report

Energy Technology Data Exchange (ETDEWEB)

Linkous, C.A.; Anderson, R.; Kopitzke, R.W.

1995-12-01

This project is an attempt to synthesize and fabricate proton exchange membranes for hydrogen production via water electrolysis that can take advantage of the better kinetic and thermodynamic conditions that exist at higher temperatures. Current PEM technology is limited to the 125--150 C range. Based on previous work evaluating thermohydrolytic stability, some 5 families of polymers were chosen as viable candidates: polyether ketones, polyether sulfones, fluorinated polyimides, polybenzimidazoles, and polyphenyl quinoxalines. Several of these have been converted into ionomers via sulfonation and fashioned into membranes for evaluation. In particular, the sulfonated polyetheretherketone, or SPEEK, was tested for water uptake, thermo-conductimetric analysis, and performance as the solid electrolyte material in an electrolysis cell. Results comparable to commercial perfluorocarbon sulfonates were obtained.

Temperature dependence on sodium-water chemical reaction

International Nuclear Information System (INIS)

Tamura, Kenta; Deguchi, Yoshihiro; Suzuki, Koichi; Takata, Takashi; Yamaguchi, Akira; Kikuchi, Shin; Ohshima, Hiroyuki

2012-01-01

In a sodium-cooled fast reactor (SFR), liquid sodium is used as a heat transfer fluid because of its excellent heat transport capability. On the other hand, it has strong chemical reactivity with water vapor. One of the design basis accidents of the SFR is the water leakage into the liquid sodium flow by a breach of heat transfer tubes. This process ends up damages on the heat transport equipment in the SFR. Therefore, the study on sodium-water chemical reactions is of paramount importance for security reasons. This study aims to clarify the sodium-water reaction mechanisms using laser diagnostics. A quasi one-dimensional flame model is also applied to a sodium-water counter-flow reaction field. Temperature, H 2 , H 2 O, OH, Na and Particulate matter were measured using laser induced fluorescence and CARS in the counter-flow reaction field. The temperature of the reaction field was also modified to reduce the condensation of Na in the reaction zone. (author)

Stability of colloidal silver nanoparticles trapped in lipid bilayer: effect of lecithin concentration and applied temperature.

Science.gov (United States)

Barani, Hossein; Montazer, Majid; Braun, Hans-Georg; Dutschk, Victoria

2014-12-01

The use of silver nanoparticle on various substrates has been widespread because of its good antibacterial properties that directly depend on the stability of the silver nanoparticles in a colloidal suspension. In this study, the colloidal solutions of the silver nanoparticles were synthesised by a simple and safe method by using lecithin as a stabilising agent and their stability was examined at various temperatures. The effect of the lecithin concentrations on the stability of the synthesised silver nanoparticles was examined from 25 to 80°C at 5°C intervals, by recording the changes in the UV-vis absorption spectra, the hydrodynamic diameter and the light scattering intensity of the silver nanoparticles. In addition, the morphology of the synthesised silver nanoparticles was investigated with the low-voltage scanning electron microscopy and transmission electron microscopy. The results indicated that increasing temperature caused different changes in the size of the stabilised and the unstabilised silver nanoparticles. The size of the stabilised silver nanoparticles reduced from 38 to 36 nm during increasing temperature, which confirmed good stability.

SU-E-T-410: Fringe Stability and Phase Shift Measurements in a Michelson Interferometer for Optical Calorimetry

International Nuclear Information System (INIS)

Flores-Martinez, E; Malin, M; DeWerd, L

2014-01-01

Purpose: To identify the variables limiting the resolution of a Michelson interferometer used to measure phase shifts (PS) in water as part of a radiometric calorimeter. Methods: We investigated the output stability of a He-Ne laser and a laser diode. The short and long term stability of the fringe pattern in a Michelson interferometer was tested with different types of lasers, thermal insulation arrangements, damping systems and optical mounts to optimize system performance. PS were induced by electrically heating water in a 1 cm quartz cuvette located in one of the interferometer arms. The PS was calculated from fringe intensity changes and compared to a calculated PS using thermocouple-measured temperature changes in the water. Results: The intensity of the laser diode is more stable, but the gas laser’s profile is more suitable for fringe analysis and has better temporal coherence. The laser requires a warm-up time of 4 hours before its output is stabilized (SNR>95). The fringe’s stability strongly depends on the thermal insulation. When the interferometer is exposed to ambient temperature swings of 0.7 K, it is not possible to stabilize the fringe pattern. Enclosing the system in a 2.5 cm-thick Styrofoam box improves the SNR, but further insulation will be needed to increase the SNR above 50. High frequency noise is significantly reduced by damping the system.Inducing a temperature rise in water, starting at 299 K, the average temperature increase for a 2π PS is 0.29 ± 0.02 K and the proportionality constant is -21.1 ± 0.8 radians/K. This is 5.8% lower than the calculated value using the thermocouple. Conclusion: Interferometric PS measurements of temperature may provide an alternative to thermistors for water calorimetry. The resolution of the current prototype is limited by ambient temperature stability. Calculated and measured thermally-induced PS in water agreed to within 5.8%

Transducer-based fiber Bragg grating high-temperature sensor with enhanced range and stability

Science.gov (United States)

Mamidi, Venkata Reddy; Kamineni, Srimannarayana; Ravinuthala, Lakshmi Narayana Sai Prasad; Tumu, Venkatappa Rao

2017-09-01

Fiber Bragg grating (FBG)-based high-temperature sensor with enhanced-temperature range and stability has been developed and tested. The sensor consists of an FBG and a mechanical transducer, which furnishes a linear temperature-dependent tensile strain on FBG by means of differential linear thermal expansion of two different ceramic materials. The designed sensor is tested over a range: 20°C to 1160°C and is expected to measure up to 1500°C.

Water Plume Temperature Measurements by an Unmanned Aerial System (UAS).

Science.gov (United States)

DeMario, Anthony; Lopez, Pete; Plewka, Eli; Wix, Ryan; Xia, Hai; Zamora, Emily; Gessler, Dan; Yalin, Azer P

2017-02-07

We report on the development and testing of a proof of principle water temperature measurement system deployed on an unmanned aerial system (UAS), for field measurements of thermal discharges into water. The primary elements of the system include a quad-copter UAS to which has been integrated, for the first time, both a thermal imaging infrared (IR) camera and an immersible probe that can be dipped below the water surface to obtain vertical water temperature profiles. The IR camera is used to take images of the overall water surface to geo-locate the plume, while the immersible probe provides quantitative temperature depth profiles at specific locations. The full system has been tested including the navigation of the UAS, its ability to safely carry the sensor payload, and the performance of both the IR camera and the temperature probe. Finally, the UAS sensor system was successfully deployed in a pilot field study at a coal burning power plant, and obtained images and temperature profiles of the thermal effluent.

Stability of retained austenite arising at low temperatures in low carbon steels with copper using TRIP effect

International Nuclear Information System (INIS)

Michta, G.; Pietrzyk, J.; Osuch, W.; Kruk, A.

2003-01-01

The magnetometric measurement results of decomposition of retained austenite arising during low temperature bainite transformation, obtained structure and mechanical properties are presented. Presented results demonstrate that the low temperature bainite transformation leads to formation of two kinds of retained austenite with different stability. Decomposition of low stability retained austenite was observed during cooling to -196 o C, the second with high stability was decomposed only during heating up to 560 o C. The first one was observed in microstructure as big grains and the second more refinement in structure was localised between bainitic regions. (author)

Stabilization and anomalous hydration of collagen fibril under heating.

Directory of Open Access Journals (Sweden)

Sasun G Gevorkian

Full Text Available BACKGROUND: Type I collagen is the most common protein among higher vertebrates. It forms the basis of fibrous connective tissues (tendon, chord, skin, bones and ensures mechanical stability and strength of these tissues. It is known, however, that separate triple-helical collagen macromolecules are unstable at physiological temperatures. We want to understand the mechanism of collagen stability at the intermolecular level. To this end, we study the collagen fibril, an intermediate level in the collagen hierarchy between triple-helical macromolecule and tendon. METHODOLOGY/PRINCIPAL FINDING: When heating a native fibril sample, its Young's modulus decreases in temperature range 20-58°C due to partial denaturation of triple-helices, but it is approximately constant at 58-75°C, because of stabilization by inter-molecular interactions. The stabilization temperature range 58-75°C has two further important features: here the fibril absorbs water under heating and the internal friction displays a peak. We relate these experimental findings to restructuring of collagen triple-helices in fibril. A theoretical description of the experimental results is provided via a generalization of the standard Zimm-Bragg model for the helix-coil transition. It takes into account intermolecular interactions of collagen triple-helices in fibril and describes water adsorption via the Langmuir mechanism. CONCLUSION/SIGNIFICANCE: We uncovered an inter-molecular mechanism that stabilizes the fibril made of unstable collagen macromolecules. This mechanism can be relevant for explaining stability of collagen.

Influence of Ti in the β-Zr(Fe) phase stability at ambient temperature

International Nuclear Information System (INIS)

Coelho, J.S.

1980-12-01

Investigations of the Fe-Ti-Zr alloy system with concentrations ranging from 1 at.% Ti to 20 at.% Ti and with a fixed concentration of 4 at.% Fe were performed using X-Ray diffraction, Mossbauer Spectroscopy and Optical and Electronic Metallographies. The alloys were melted in arc furnace in argon atmosphere and after being homogenized, they were quenched from the beta field into cold water in order to retain the high temperature β-Zr(Fe)-Ti phase. The obtained results show that the beta phase was partially retained until the concentration of 7 at.% Ti and was completely retained at the concentration equal to or higher than 8 at.% Ti. It is assumed in Moessbauer Spectroscopy a doublet for the beta phase and a singlet for the supersatured α'-Zr(Fe)-Ti phase resulting from the martensitic transformation. The relative amount of each phase detected by Moessbauer Spectroscopy was measured by the relative area of the each spectral line. The stability of the beta phase at room temperature was discussed in terms of short-range ordering caused by the Fe-Ti bonds. Some related properties were discussed through the changing of the lattice parameter, isomer shift and quadrupole splitting. (Author) [pt

Oxidative stability during storage of fish oil from filleting by-products of rainbow trout (Oncorhynchus mykiss) is largely independent of the processing and production temperature

DEFF Research Database (Denmark)

Honold, Philipp; Nouard, Marie-Louise; Jacobsen, Charlotte

2016-01-01

Rainbow trout (Oncorhynchus mykiss) is the main fish species produced in Danish fresh water farming. Large amounts of fileting by-products like heads, bones, tails (HBT), and intestines are produced when rainbow trout is processed to smoked rainbow trout filets. The filleting by-products can...... be used to produce high quality fish oil. In this study, the oxidative stability of fish oil produced from filleting by-products was evaluated. The oil was produced from conventional or organic fish (low and high omega-3 fatty acid content) at different temperatures (70 and 90°C). The oxidative stability...

Stability analysis on natural circulation boiling water reactors

International Nuclear Information System (INIS)

Metz, Peter

1999-05-01

The purpose of the study is a stability analysis of the simplified boiling water reactor concept. A fluid dynamics code, DYNOS, was developed and successfully validated against FRIGG and DESIRE data and a stability benchmark on the Ringhals 1 forced circulation BWR. Three simplified desings were considered in the analysis: The SWRIOOO by Siemens and the SBWR and ESBWR from the General Electric Co. For all three design operational characteristics, i.e. power versus flow rate maps, were calculated. The effects which different geometric and operational parameters, such as the riser height, inlet subcooling etc., have on the characteristics have been investigated. Dynamic simulations on the three simplified design revealed the geysering and the natural circulation oscillations modes only. They were, however, only encountered at pressure below 0.6 MPa. Stability maps for all tree simplified BWRs were calculated and plotted. The study concluded that a fast pressurisation of the reactor vessel is necessary to eliminate the possibility of geysering or natural circulation oscillations mode instability. (au)

Sensing the water content of honey from temperature-dependent electrical conductivity

International Nuclear Information System (INIS)

Guo, Wenchuan; Liu, Yi; Zhu, Xinhua; Zhuang, Hong

2011-01-01

In order to predict the water content in honey, electrical conductivity was measured on blossom honey types milk-vetch, jujube and yellow-locust with the water content of 18–37% between 5 and 40 °C. The regression models of electrical conductivity were developed as functions of water content and temperature. The results showed that increases in either water content or temperature resulted in an increase in the electrical conductivity of honey with greater changes at higher water content and/or higher temperature. The linear terms of water content and temperature, a quadratic term of water content, and the interaction effect of water content and temperature had significant influence on the electrical conductivity of honey (p < 0.0001). Regardless of blossom honey type, the linear coefficient of the determination of measured and calculated electrical conductivities was 0.998 and the range error ratio was larger than 100. These results suggest that the electrical conductivity of honey might be used to develop a detector for rapidly predicting the water content in blossom honey

Application of linearized model to the stability analysis of the pressurized water reactor

International Nuclear Information System (INIS)

Li Haipeng; Huang Xiaojin; Zhang Liangju

2008-01-01

A Linear Time-Invariant model of the Pressurized Water Reactor is formulated through the linearization of the nonlinear model. The model simulation results show that the linearized model agrees well with the nonlinear model under small perturbation. Based upon the Lyapunov's First Method, the linearized model is applied to the stability analysis of the Pressurized Water Reactor. The calculation results show that the methodology of linearization to stability analysis is conveniently feasible. (authors)

Improved temperature regulation of APS linac RF components

International Nuclear Information System (INIS)

Dortwegt, R.

1998-01-01

The temperature of the APS S-Band linac's high-power rf components is regulated by water from individual closed-loop deionized (DI) water systems. The rf components are all made of oxygen-free high-conductivity copper and respond quickly to temperature changes. The SLED cavities are especially temperature-sensitive and cause beam energy instabilities when the temperature is not well regulated. Temperature regulation better than ± 0.1 F is required to achieve good energy stability. Improvements in the closed-loop water systems have enabled them to achieve a regulation of ± 0.05 F over long periods. Regulation philosophy and equipment are discussed and numerical results are presented

Stability of gold cages (Au16 and Au17) at finite temperature

Indian Academy of Sciences (India)

We have employed ab initio molecular dynamics to investigate the stability of the smallest ... total simulation time is of the order of 2.4 ns for each cluster. .... energies are relevant to the finite temperature analysis, we have analysed about 50.

Influence of fine water droplets to temperature and humidity

Science.gov (United States)

Hafidzal, M. H. M.; Hamzah, A.; Manaf, M. Z. A.; Saadun, M. N. A.; Zakaria, M. S.; Roslizar, A.; Jumaidin, R.

2015-05-01

Excessively dry air can cause dry skin, dry eyes and exacerbation of medical conditions. Therefore, many researches have been done in order to increase humidity in our environment. One of the ways is by using water droplets. Nowadays, it is well known in market stand fan equipped with water mister in order to increase the humidity of certain area. In this study, the same concept is applied to the ceiling fan. This study uses a model that combines a humidifier which functions as cooler, ceiling fan and scaled down model of house. The objective of this study is to analyze the influence of ceiling fan humidifier to the temperature and humidity in a house. The mechanism of this small model uses batteries as the power source, connected to the fan and the humidifier. The small water tank's function is to store and supply water to the humidifier. The humidifier is used to cool the room by changing water phase to fine water droplets. Fine water droplets are created from mechanism of the humidifier, which is by increasing the kinetic energy of water molecule using high frequency vibration that overcome the holding force between water molecules. Thus, the molecule of water will change to state of gas or mist. The fan is used to spread out the mist of water to surrounding of the room in order to enhance the humidity. Thermocouple and humidity meter are used to measure temperature and humidity in some period of times. The result shows that humidity increases and temperature decreases with time. This application of water droplet can be applied in the vehicles and engine in order to decrease the temperature.

The stability of high-Tc BSCCO/Ag superconducting microcomposites in water, some inorganic solutions and organic solvents

International Nuclear Information System (INIS)

Gao, W.; Chen, J.; Yang, C.O.; McNabb, D.; Sande, J. vander

1992-01-01

Bi(Pb)-Sr-Ca-Cu-O/Ag (BSCCO/Ag) superconducting microcomposites with zero-resistance temperatures from 102 to 108 K and critical current densities of ∝600 A/cm 2 at 77 K were produced by oxidation and annealling of metallic precursor alloys. The stabilities and degradation behavior of BSCCO/Ag specimens in various environments were studied by a combination of mass loss measurement, electrical transport measurement and microstructural observation. The environmental conditions used in the present work were moist air, distilled water, aqueous solutions of NaCl, NaOH and acetic acid, and organic solvents methanol and acetone. Although there is a general tendency toward a decrease in critical current density after a long exposure to most of the testing conditions, the specimens containing a high percent of Ag (≥70 wt.%) showed very little decrease in Tc and J c up to 200 days of exposure in moist air and distilled water, and up to 20 days in NaCl solution, methanol and acetone. It was found that the superconducting ''2223'' phase is stable in water, neutral solutions and the organic solvents, reacts very slowly with basic solutions, and dissolves rapidly in acidic solutions. Some non-superconducting Ca-rich oxides dissolve in water and neutral and basic solutions and therefore damage the connection of the superconducting grains in low-Ag containing specimens. The excellent stability of the BSCCO/Ag superconducting microcomposites containing high Ag provides an important advantage for their potential industrial application. (orig.)

Water stability of soil aggregates in different systems of Chernozem tillage

Directory of Open Access Journals (Sweden)

Jaroslava Bartlová

2011-01-01

Full Text Available Effects of various agrotechnical measures on macrostructural changes in the ploughing layer and subsoil were studied within the period of 2008–2010. Soil macrostructure was evaluated on the base of water stability of soil aggregates. Altogether three variants of soil tillage were established, viz. ploughing to the depth of 0.22 m (Variant 1, deep soil loosening to the depth of 0.35–0.40 m (Variant 2, and shallow tillage to the depth of 0.15 m (Variant 3. Experiments were established on a field with Modal Chernozem in the locality Hrušovany nad Jevišovkou (maize-growing region, altitude of 210 m, average annual sum of precipitation 461 mm. In the first experimental year, winter rape was the cultivated crop and it was followed by winter wheat, maize and spring wheat in subsequent years. The aim of this study was to evaluate effects of different methods of tillage on water stability of soil aggregates and on yields of individual crops. An overall analysis of results revealed a positive effect of cultivation without ploughing on water stability of soil aggregates. In the variant with ploughing was found out a statistically significant decrease of this stability. At the same time it was also found out that both minimum tillage and deep soil loosening showed a positive effect on yields of crops under study (above all of maize and winter wheat.

Thermal infrared remote sensing of water temperature in riverine landscapes: Chapter 5

Science.gov (United States)

Carbonneau, Rebecca N.; Piégay, Hervé; Handcock, R.N; Torgersen, Christian E.; Cherkauer, K.A; Gillespie, A.R; Tockner, K; Faux, R. N.; Tan, Jing

2012-01-01

Water temperature in riverine landscapes is an important regional indicator of water quality that is influenced by both ground- and surface-water inputs, and indirectly by land use in the surrounding watershed (Brown and Krygier, 1970; Beschta et al., 1987; Chen et al., 1998; Poole and Berman, 2001). Coldwater fishes such as salmon and trout are sensitive to elevated water temperature; therefore, water temperature must meet management guidelines and quality standards, which aim to create a healthy environment for endangered populations (McCullough et al., 2009). For example, in the USA, the Environmental Protection Agency (EPA) has established water quality standards to identify specific temperature criteria to protect coldwater fishes (Environmental Protection Agency, 2003). Trout and salmon can survive in cool-water refugia even when temperatures at other measurement locations are at or above the recommended maximums (Ebersole et al., 2001; Baird and Krueger, 2003; High et al., 2006). Spatially extensive measurements of water temperature are necessary to locate these refugia, to identify the location of ground- and surface-water inputs to the river channel, and to identify thermal pollution sources. Regional assessment of water temperature in streams and rivers has been limited by sparse sampling in both space and time. Water temperature has typically been measured using a network of widely distributed instream gages, which record the temporal change of the bulk, or kinetic, temperature of the water (Tk) at specific locations. For example, the State of Washington (USA) recorded water quality conditions at 76 stations within the Puget Lowlands eco region, which contains 12,721 km of streams and rivers (Washington Department of Ecology, 1998). Such gages are sparsely distributed, are typically located only in larger streams and rivers, and give limited information about the spatial distribution of water temperature (Cherkauer et al., 2005).

Relationship between water temperature predictability and aquatic ...

African Journals Online (AJOL)

Macroinvertebrate taxonomic turnover across seasons was higher for sites having lower water temperature predictability values than for sites with higher predictability, while temporal partitioning was greater at sites with greater temperature variability. Macroinvertebrate taxa responded in a predictable manner to changes in ...

Supercooling of natural water, heavy water and of the blends H2O-D2O

International Nuclear Information System (INIS)

Lafargue, C.; Babin, L.; Clausse, D.; Lere-Porte, M.; Broto, F.

1975-01-01

It is shown that the coherency of the results of various measurements on water freezing temperatures proves that freezing temperatures must be dependent on the structure of the supercooled liquid. Recent experiments that confirm this interpretation are described: study of the stability of supercooled water as a function of time at fixed temperature, study of the influence of various thermal treatments on the behavior of supercooled water, study of the supercooling of heavy water and of D 2 O-H 2 O blends [fr

Optimum hot water temperature for absorption solar cooling

Energy Technology Data Exchange (ETDEWEB)

Lecuona, A.; Ventas, R.; Venegas, M.; Salgado, R. [Dpto. Ingenieria Termica y de Fluidos, Universidad Carlos III de Madrid, Avda. Universidad 30, 28911 Leganes, Madrid (Spain); Zacarias, A. [ESIME UPA, IPN, Av. de las Granjas 682, Col. Santa Catarina, 02550, D.F. Mexico (Mexico)

2009-10-15

The hot water temperature that maximizes the overall instantaneous efficiency of a solar cooling facility is determined. A modified characteristic equation model is used and applied to single-effect lithium bromide-water absorption chillers. This model is based on the characteristic temperature difference and serves to empirically calculate the performance of real chillers. This paper provides an explicit equation for the optimum temperature of vapor generation, in terms of only the external temperatures of the chiller. The additional data required are the four performance parameters of the chiller and essentially a modified stagnation temperature from the detailed model of the thermal collector operation. This paper presents and discusses the results for small capacity machines for air conditioning of homes and small buildings. The discussion highlights the influence of the relevant parameters. (author)

A new kind of shape-stabilized PCMs with positive temperature coefficient (PTC) effect

International Nuclear Information System (INIS)

Cheng, Wen-long; Wu, Wan-fan; Song, Jia-liang; Liu, Yi; Yuan, Shuai; Liu, Na

2014-01-01

Highlights: • A new kind of shape-stabilized PCMs with PTC effect is first prepared. • It provides a potential means for the thermal control of the electronic devices. • The switching temperature of the materials is about 25 °C. • The most appropriate component of the material is found out by experimental study. • The NTC effect of the new PCMs is eliminated effectively by heat treatment. - Abstract: A new kind of shape-stabilized phase change materials (PCMs) with positive temperature coefficient (PTC) effect was prepared in this paper. The materials were prepared by adding graphite powder (GP) to the paraffin/low density polyethylene (LDPE) composite and the PTC characteristic was found by adjusting the component ratio of the material. Then the physical structures and thermal properties of the materials were investigated and the effect of various GP mass fractions and paraffin/LDPE mass proportions on the PTC behavior of the materials was studied experimentally. The results showed that the switching temperature of the materials was about 25 °C (room temperature) which approached to the first phase change temperature of paraffin dispersed in the materials. The PTC behavior of the materials was the best when the GP mass fraction and the mass proportion of LDPE/paraffin were 40 wt% and 30:70, respectively. Furthermore, the negative temperature coefficient (NTC) effect of the materials could be eliminated effectively with heat treatment. This new kind of materials is different from the former PTC materials which the switching temperatures focus on high temperature ranges. It makes up for the defect of previous materials that the switching temperatures only range in high temperature rather than room temperature and provides a potential means for the thermal control of the electronic devices or other room temperature thermal control applications

Measurements of water temperature in fountains as an indicator of potential secondary water pollution caused by Legionella bacteria

Directory of Open Access Journals (Sweden)

Bąk Joanna

2018-01-01

Full Text Available At high air temperatures persisting for a long time, water temperature in the fountains may also increase significantly. This can cause a sudden and significant increase in Legionella bacteria, which results in secondary water contamination. This phenomenon with water – air aerosol generated by fountains can be very dangerous for people. During the test, water temperature measurements in fountains in Poland were made. These research tests was conducted in the spring and summer. The research was conducted in order to determine whether there is a possibility of growth of Legionella bacteria. One of the aims of the study was to determine what temperature range occurs in the fountains and how the temperature changes in the basin of the fountain and when the highest temperature occurs. Single temperature measurements were made and also the temperature distribution was measured during daylight hours. The water temperature in most cases was greater than 20°C, but in no case exceed 26°C. The paper presents also the review about the effect of water temperature on the presence and bacterial growth. The study confirmed the existence of the risk of increasing the number of bacteria of the genus Legionella in the water in the fountains.

Measurements of water temperature in fountains as an indicator of potential secondary water pollution caused by Legionella bacteria

Science.gov (United States)

Bąk, Joanna

2018-02-01

At high air temperatures persisting for a long time, water temperature in the fountains may also increase significantly. This can cause a sudden and significant increase in Legionella bacteria, which results in secondary water contamination. This phenomenon with water - air aerosol generated by fountains can be very dangerous for people. During the test, water temperature measurements in fountains in Poland were made. These research tests was conducted in the spring and summer. The research was conducted in order to determine whether there is a possibility of growth of Legionella bacteria. One of the aims of the study was to determine what temperature range occurs in the fountains and how the temperature changes in the basin of the fountain and when the highest temperature occurs. Single temperature measurements were made and also the temperature distribution was measured during daylight hours. The water temperature in most cases was greater than 20°C, but in no case exceed 26°C. The paper presents also the review about the effect of water temperature on the presence and bacterial growth. The study confirmed the existence of the risk of increasing the number of bacteria of the genus Legionella in the water in the fountains.

Copper-chromium compounds formed in the preparation of a low-temperature water gas shift catalyst

Energy Technology Data Exchange (ETDEWEB)

Sharkina, V I; Salomatin, G I; Boevskaya, E A

1978-12-01

IR and X-ray phase analyses of commercial water gas shift catalyst samples prepared by mixing solid chromic anhydride, basic copper carbonate (malachite), aluminum hydroxide, and water at 70/sup 0/-100/sup 0/C and 0.35:1 to 1.2:1 ratio of water to solid components (R) showed the formation of a basic copper chromate (BCC) CuCrO/sub 4/-2CuO-2H/sub 2/O at 80/sup 0/C (any R) and at 100/sup 0/C and R Vertical Bar3: 1.2:1, but at 100/sup 0/C and lower R (especially at R 0.7:1), a different, unidentified phase was formed. The samples containing these two phases had different colors; the high-temperature, low-water phase showed lower thermal stability but higher catalytic activity than the BCC. The BCC catalyst samples contained less unreacted malachite and their IR spectra contained a 3100-3200/cm band characteristic of hydroxyls associated by hydrogen bonds, and more molecular water, suggesting the formation of a hydroxo-polymeric structured system.

A comprehensive study of temperature stability of Silicon PhotoMultiplier

International Nuclear Information System (INIS)

Ferri, A; Acerbi, F; Gola, A; Paternoster, G; Piemonte, C; Zorzi, N

2014-01-01

The temperature stability of the SiPM signal output can be a crucial aspect in many applications. In a typical scenario where the detector is biased at a constant voltage, a temperature fluctuation determines a change in the breakdown voltage and consequently in the applied over-voltage. The latter impacts on all the parameters that determine the output signal such as gain, PDE and correlated noise probability. In this paper we show a detailed analysis of the dependence of these parameters versus the temperature. In particular, we analyze two cases in which the quantity of interest is the integrated charge or the signal amplitude, respectively. The model is applied to a 1 × 1 mm 2 FBK RGB SiPM with 50 × 50 μm 2 cells showing a good agreement with the experimental data

Prediction of water temperature metrics using spatial modelling in ...

African Journals Online (AJOL)

Water temperature regime dynamics should be viewed regionally, where regional divisions have an inherent underpinning by an understanding of natural thermal variability. The aim of this research was to link key water temperature metrics to readily-mapped environmental surrogates, and to produce spatial images of ...

Heat Sinking, Cross Talk, and Temperature Stability for Large, Close-Packed Arrays of Microcalorimeters

Science.gov (United States)

Imoto, Naoko; Bandler, SImon; Brekosky, Regis; Chervenak, James; Figueroa-Felicano, Enectali; Finkbeiner, Frederick; Kelley, Richard; Kilbourne, Caroline; Porter, Frederick; Sadleir, Jack;

Water-in-oil Pickering emulsions stabilized by stearoylated microcrystalline cellulose.

Science.gov (United States)

Pang, Bo; Liu, Huan; Liu, Peiwen; Peng, Xinwen; Zhang, Kai

2018-03-01

Hydrophobic particles with static water contact angles larger than 90° are more like to stabilize W/O Pickering emulsions. In particular, high internal phase Pickering emulsions (HIPEs) are of great interest for diverse applications. However, W/O HIPEs have rarely been realized using sustainable biopolymers. Herein, we used stearoylated microcrystalline cellulose (SMCC) to stabilize W/O Pickering emulsions and especially, W/O HIPEs. Moreover, these W/O HIPEs can be further used as platforms for the preparation of porous materials, such as porous foams. Stearoylated microcrystalline cellulose (SMCC) was prepared by modifying MCC with stearoyl chloride under heterogeneous conditions. Using SMCC as emulsifiers, W/O medium and high internal phase Pickering emulsions (MIPEs and HIPEs) with various organic solvents as continuous phases were prepared using one-step and two-step methods, respectively. Polystyrene (PS) foams were prepared after polymerization of oil phase using HIPEs as templates and their oil/water separation capacity were studied. SMCC could efficiently stabilize W/O Pickering emulsions and HIPEs could only be prepared via the two-step method. The internal phase volume fraction of the SMCC-stabilized HIPEs reached as high as 89%. Diverse internal phase volume fractions led to distinct inner structures of foams with closed or open cells. These macroporous polystyrene (PS) foams demonstrated great potential for the effective absorption of organic solvents from underwater. Copyright © 2017 Elsevier Inc. All rights reserved.

Determination of the potentiostatic stability of PEMFC electro catalysts at elevated temperatures

NARCIS (Netherlands)

Dam, V.A.T.; Jayasayee, K.; Bruijn, de F.A.

2009-01-01

The electrochemical stability of platinum on carbon catalyst (Hispec TM 4000, Johnson Matthey) has been investigated predominantly at constant potentials ranging from 0.95 to 1.25 V at elevated temperatures. By combining a quartz crystal microbalance (QCM) with electrochemical techniques, dynamic

Perspectives on Temperature in the Pacific Northwest's Fresh Waters

Energy Technology Data Exchange (ETDEWEB)

Coutant, C.C.

1999-06-01

This report provides a perspective on environmental water temperatures in the Pacific Northwest as they relate to the establishment of water temperature standards by the state and their review by the US Environmental Protection Agency. It is a companion to other detailed reviews of the literature on thermal effects on organisms important to the region. Many factors, both natural and anthropogenic, affect water temperatures in the region. Different environmental zones have characteristic temperatures and mechanisms that affect them. There are specific biotic adaptations to environmental temperatures. Life-cycle strategies of salmonids, in particular, are attuned to annual temperature patterns. Physiological and behavioral requirements on key species form the basis of present water temperature criteria, but may need to be augmented with more concern for environmental settings. There are many issues in the setting of standards, and these are discussed. There are also issues in compliance. Alternative temperature-regulating mechanisms are discussed, as are examples of actions to control water temperatures in the environment. Standards-setting is a social process for which this report should provide background and outline options, alternatives, limitations, and other points for discussion by those in the region.

High temperature measurement of water vapor absorption

Science.gov (United States)

Keefer, Dennis; Lewis, J. W. L.; Eskridge, Richard

1985-01-01

An investigation was undertaken to measure the absorption coefficient, at a wavelength of 10.6 microns, for mixtures of water vapor and a diluent gas at high temperature and pressure. The experimental concept was to create the desired conditions of temperature and pressure in a laser absorption wave, similar to that which would be created in a laser propulsion system. A simplified numerical model was developed to predict the characteristics of the absorption wave and to estimate the laser intensity threshold for initiation. A non-intrusive method for temperature measurement utilizing optical laser-beam deflection (OLD) and optical spark breakdown produced by an excimer laser, was thoroughly investigated and found suitable for the non-equilibrium conditions expected in the wave. Experiments were performed to verify the temperature measurement technique, to screen possible materials for surface initiation of the laser absorption wave and to attempt to initiate an absorption wave using the 1.5 kW carbon dioxide laser. The OLD technique was proven for air and for argon, but spark breakdown could not be produced in helium. It was not possible to initiate a laser absorption wave in mixtures of water and helium or water and argon using the 1.5 kW laser, a result which was consistent with the model prediction.

The influence of increased temperature of waters from Cernavoda NPP on underground water sources

International Nuclear Information System (INIS)

Isbasoiu, Eugen Constantin; Marinov, Anca Mariana; Moraru, Carina Nicoleta; Rizescu, Gheorghe

1997-01-01

The operation of Cernavoda NPP implies the change of thermal regime of waters in the Danube-Black Sea channel zone. The Danube water is used to cool the NPP systems before being delivered into channel and used in irrigations. The temperature increase of water in Cernavoda NPP installations is between 7 and 12 deg. C. The negative effects of this warming are: 1. limitation of water use for irrigations; 2. occurrence and persistence of fog in channel area; 3. thermal pollution of underground waters and limitation of underground potable water supply. The paper presents a general approach of thermal pollution problems of an aquifer and a mathematical model of forecasting the underground water temperature variation in Danube-Black Sea channel area. (authors)

Stability of stearic acid monolayers on artificial sea water

NARCIS (Netherlands)

Brzozowska, A.M.; Duits, Michael H.G.; Mugele, Friedrich Gunther

2012-01-01

We studied the formation and stability of stearic acid (SA) based films on aqueous sub-phases via Langmuir trough and imaging ellipsometry experiments. The aqueous phase was based on Artificial Sea Water (ASW), a multicomponent salt solution with a total molarity of 0.53. The composition of this

Improved ferroelectric/piezoelectric properties and bright green/UC red emission in (Li,Ho)-doped CaBi4Ti4O15 multifunctional ceramics with excellent temperature stability and superior water-resistance performance.

Science.gov (United States)

Xiao, Ping; Guo, Yongquan; Tian, Mijie; Zheng, Qiaoji; Jiang, Na; Wu, Xiaochun; Xia, Zhiguo; Lin, Dunmin

2015-10-21

Multifunctional materials based on rare earth ion doped ferro/piezoelectrics have attracted considerable attention in recent years. In this work, new lead-free multifunctional ceramics of Ca1-x(LiHo)x/2Bi4Ti4O15 were prepared by a conventional solid-state reaction method. The great multi-improvement in ferroelectricity/piezoelectricity, down/up-conversion luminescence and temperature stability of the multifunctional properties is induced by the partial substitution of (Li0.5Ho0.5)(2+) for Ca(2+) ions in CaBi4Ti4O15. All the ceramics possess a bismuth-layer structure, and the crystal structure of the ceramics is changed from a four layered bismuth-layer structure to a three-layered structure with the level of (Li0.5Ho0.5)(2+) increasing. The ceramic with x = 0.1 exhibits simultaneously, high resistivity (R = 4.51 × 10(11)Ω cm), good piezoelectricity (d33 = 10.2 pC N(-1)), high Curie temperature (TC = 814 °C), strong ferroelectricity (Pr = 9.03 μC cm(-2)) and enhanced luminescence. These behaviours are greatly associated with the contribution of (Li0.5Ho0.5)(2+) in the ceramics. Under the excitation of 451 nm light, the ceramic with x = 0.1 exhibits a strong green emission peak centered at 545 nm, corresponding to the transition of the (5)S2→(5)I8 level in Ho(3+) ions, while a strong red up-conversion emission band located at 660 nm is observed under the near-infrared excitation of 980 nm at room temperature, arising from the transition of (5)F5→(5)I8 levels in Ho(3+) ions. Surprisingly, the excellent temperature stability of ferroelectricity/piezoelectricity/luminescence and superior water-resistance behaviors of piezoelectricity/luminescence are also obtained in the ceramic with x = 0.1. Our study suggests that the present ceramics may have potential applications in advanced multifunctional devices at high temperature.

Water Plume Temperature Measurements by an Unmanned Aerial System (UAS

Directory of Open Access Journals (Sweden)

Anthony DeMario

2017-02-01

Full Text Available We report on the development and testing of a proof of principle water temperature measurement system deployed on an unmanned aerial system (UAS, for field measurements of thermal discharges into water. The primary elements of the system include a quad-copter UAS to which has been integrated, for the first time, both a thermal imaging infrared (IR camera and an immersible probe that can be dipped below the water surface to obtain vertical water temperature profiles. The IR camera is used to take images of the overall water surface to geo-locate the plume, while the immersible probe provides quantitative temperature depth profiles at specific locations. The full system has been tested including the navigation of the UAS, its ability to safely carry the sensor payload, and the performance of both the IR camera and the temperature probe. Finally, the UAS sensor system was successfully deployed in a pilot field study at a coal burning power plant, and obtained images and temperature profiles of the thermal effluent.

Is it real or apparent increased aggregate stability sometimes found in burned soils?

Directory of Open Access Journals (Sweden)

V. Arcenegui

2013-05-01

Full Text Available The increase in soil aggregate stability observed in many cases after burning is discussed in this paper. Soil samples under pine forest from two Mediterranean areas were collected for this experiment: acid soils from El Algibe Range (Los Alcornocales Natural Park, Cádiz, Southern Spain and calcareous soils of Sierra de la Grana (Alicante, Eastern Spain. In each case, soil aggregates (2 to 0.25 mm were selected and exposed to temperatures of 200, 250, 300, 500 and 700 oC during a 20-minutes period. In both cases weight loss after volatilization of substances and a significant destruction of aggregates with increasing temperature were observed. For acid soils, where organic matter is the main cementing agent, destruction of aggregates with temperature was more intense. Water repellency induced by combustion increased between 200 and 250 oC, also the remaining aggregates remaining increased within the initial size fraction after heating, increasing its stability. For temperatures above 300 oC, water repellency disappeared, although an increase in aggregate stability was observed, possibly due to changes in the mineral soil fraction. Therefore, it is concluded that burning may destroy part of the aggregates by combustion of organic matter, so selecting stable aggregates. Water repellency and transformations of soil minerals contribute to increased stability in selected aggregates.

Data on corrosion and scaling potential of drinking water resources using stability indices in Jolfa, East Azerbaijan, Iran

Directory of Open Access Journals (Sweden)

Mahmood Yousefi

2018-02-01

Full Text Available This cross-sectional study was conducted on the drinking water resources of the city of Jolfa (East Azerbaijan province, Iran from samples taken from 30 wells. Calcium hardness, pH, total alkalinity, TDS, temperature and other chemical parameters were measured using standard methods. The Langelier, Rayzner, Puckhorius and aggressive indices were calculated. The results showed that the Langelier, Reynar, Puckorius, Larson-skold and aggressive indices were 1.15 (± 0.43, 6.92 (± 0.54, 6.42 (± 0.9, 0.85 (± 0.72 and 12.79 (± 0.47, respectively. In terms of water classification, 30% of samples fell into the NaCl category and 26.6% in the NaHCO3 category and 43.4% samples in the CaHCO3, MgHCO3 and MgCl category. The sedimentation indices indicated that the water of the wells could be considered as corrosive. Keywords: Corrosion and scaling potential, Stability indices, Ground water, Jolfa

Stabilization of arsenic and chromium polluted soils using water treatment residues

DEFF Research Database (Denmark)

Nielsen, Sanne Skov

water and can be used as a soil amendment to decrease the mobility of CCA in contaminated soil. Stabilization with Fe-WTR was tested at the Collstrop site in Hillerød, Denmark. The site has been polluted with a wide range of wood impregnation agents including CCA during 40 years of wood impregnating...... of contaminants. Arsenic, chromium and copper cannot be degraded and existing methods for cleaning the soil are rarely used as they are expensive and technically demanding. Chemical stabilization of polluted soil is an alternative method for soil remediation, especially metal contamination, and consists in adding...... or other sorbents. Iron water treatment residues mainly consist of ferrihydrite, an oxidized iron oxy-hydroxide with a high reactivity and a large specific surface area with a high capacity for adsorption. Iron water treatment residues (Fe-WTR) are a by-product from treatment of groundwater to drinking...

Concurrent temporal stability of the apparent electrical conductivity and soil water content

Science.gov (United States)

Knowledge of spatio-temporal soil water content (SWC) variability within agricultural fields is useful to improve crop management. Spatial patterns of soil water contents can be characterized using the temporal stability analysis, however high density sampling is required. Soil apparent electrical c...

Mathematical modeling of photoinitiated coating degradation: Effects of coating glass transition temperature and light stabilizers

DEFF Research Database (Denmark)

Kiil, Søren; G.de With, R.A.T.M.Van Benthem

2013-01-01

A mathematical model, describing coating degradation mechanisms of thermoset coatings exposed to ultraviolet radiation and humidity at constant temperature, was extended to simulate the behavior of a coating with a low glass transition temperature. The effects of adding light stabilizers (a UV...

Geothermal data-base study: mine-water temperatures. Final report

Energy Technology Data Exchange (ETDEWEB)

Lawson, D.C.; Sonderegger, J.L.

1978-07-01

Investigation of about 1,600 mines and prospects for perennial discharge resulted in the measurement of temperature, pH, specific conductance, and discharge at 80 sites to provide information for a geothermal data base. Measurements were made in the fall, winter, and late spring or early summer to provide information about seasonal variability. None of the temperatures measured exceeded the mean annual air temperature by 15/sup 0/F, but three areas were noted where discharges were anomalously warm, based upon high temperatures, slight temperature variation, and quantity of discharge. The most promising area, at the Gold Bug mine in the Little Rockies, discharges water averaging 7.3/sup 0/C (12.1/sup 0/F) above the mean annual air temperature. The discharge may represent water heated during circulation within the syenite intrusive body. If the syenite is enriched in uranium and thorium, an abnormal amount of heat would be produced by radioactive decay. Alternatively, the water may move through deep permeable sedimentary strata, such as the Madison Group, and be discharged to the surface through fractures in the pluton.

CFD results for temperature dependence water cooling pump NPSH calculations - 15425

International Nuclear Information System (INIS)

Strongin, M.P.

2015-01-01

In this work the possibility to model the pump for water cooling reactors behavior in the critical situation was considered for cases when water temperature suddenly increases. In cases like this, cavitation effects may cause pump shutoff and consequently stop the reactor cooling. Centrifugal pump was modeled. The calculations demonstrate strong dependence of NPSH (net-positive-suction-head) on the water temperature on the pump inlet. The water temperature on the inlet lies between 25 and 180 C. degrees. The pump head performance curve has a step-like slope below NPSH point. Therefore, if the pressure on the pump inlet is below than NPSH, it leads to the pump shutoff. For high water temperature on the pump inlet, NPSH follows the vapor saturated pressure for given temperature with some offset. The results clearly show that in case of accidental increase of temperature in the cooling loop, special measures are needed to support the pressure on the pump inlet to prevent pump shutoff. (author)

Genetic Programming and Standardization in Water Temperature Modelling

Directory of Open Access Journals (Sweden)

Maritza Arganis

2009-01-01

Full Text Available An application of Genetic Programming (an evolutionary computational tool without and with standardization data is presented with the aim of modeling the behavior of the water temperature in a river in terms of meteorological variables that are easily measured, to explore their explanatory power and to emphasize the utility of the standardization of variables in order to reduce the effect of those with large variance. Recorded data corresponding to the water temperature behavior at the Ebro River, Spain, are used as analysis case, showing a performance improvement on the developed model when data are standardized. This improvement is reflected in a reduction of the mean square error. Finally, the models obtained in this document were applied to estimate the water temperature in 2004, in order to provide evidence about their applicability to forecasting purposes.

Electrical properties and temperature stability of a new kind of lead-free piezoelectric ceramics

International Nuclear Information System (INIS)

Wang Yuanyu; Wu Jiagang; Xiao Dingquan; Zhang Bin; Wu Wenjuan; Shi Wei; Zhu Jianguo

2008-01-01

0.995[(K 0.50 Na 0.50 ) 0.94 Li 0.06 ]NbO 3 -0.005AETiO 3 (AE=Ca, Sr, Mg, Ba) lead-free piezoelectric ceramics were prepared by normal sintering. The effects of the AETiO 3 and poling temperature on the electrical properties of the ceramics were carefully studied, and the temperature stability of the electrical properties of the ceramics was also investigated. The experimental results show that the ceramics with Li and CaTiO 3 possess the pure phase, Li and AETiO 3 improves the electrical properties of the pure (K 0.50 Na 0.50 )NbO 3 ceramics, the poling temperature near tetragonal and orthorhombic phase transition will enhance the piezoelectric properties of the ceramics and the KNLN-CT ceramics exhibit good temperature stability of electrical properties for tetragonal and orthorhombic phase transition below room temperature. The KNLN-CT ceramics exhibit relatively good properties: d 33 = 172 pC N -1 , k p = 0.43, tan δ = 0.032, ε r = 771 and T c = 465 deg. C. As a result, the KNLN-CT ceramic is promising candidate material for piezoelectric devices.

Zirconium phosphate waste forms for low-temperature stabilization of cesium-137-containing waste streams

International Nuclear Information System (INIS)

Singh, D.; Wagh, A.S.; Tlustochowicz.

1996-04-01

Novel chemically bonded phosphate ceramics are being developed and fabricated for low-temperature stabilization and solidification of waste streams that are not amenable to conventional high-temperature stabilization processes because volatiles are present in the wastes. A composite of zirconium-magnesium phosphate has been developed and shown to stabilize ash waste contaminated with a radioactive surrogate of 137 Cs. Excellent retainment of cesium in the phosphate matrix system was observed in Toxicity Characteristic Leaching Procedure tests. This was attributed to the capture of cesium in the layered zirconium phosphate structure by intercalation ion-exchange reaction. But because zirconium phosphate has low strength, a novel zirconium/magnesium phosphate composite waste form system was developed. The performance of these final waste forms, as indicated by compression strength and durability in aqueous environments, satisfy the regulatory criteria. Test results indicate that zirconium-magnesium-phosphate-based final waste forms present a viable technology for treatment and solidification of cesium-contaminated wastes

Ultrasound- and Temperature-Induced Gelation of Gluconosemicarbazide Gelator in DMSO and Water Mixtures

Directory of Open Access Journals (Sweden)

Mothukunta Himabindu

2017-04-01

Full Text Available We have developed amphiphilic supramolecular gelators carrying glucose moiety that could gel a mixture of dimethyl sulfoxide (DMSO and water upon heating as well as ultrasound treatment. When the suspension of gluconosemicarbazide was subjected to ultrasound treatment, gelation took place at much lower concentrations compared to thermal treatment, and the gels transformed into a solution state at higher temperatures compared to temperature-induced gels. The morphology was found to be influenced by the nature of the stimulus and presence of salts such as KCl, NaCl, CaCl2 and surfactant (sodium dodecyl sulphate at a concentration of 0.05 M. The gel exhibited impressive tolerance to these additives, revealing the stability and strength of the gels. Fourier transform infrared spectroscopy (FTIR revealed the presence of the intermolecular hydrogen bonding interactions while differential scanning calorimetry (DSC and rheological studies supported better mechanical strength of ultrasound-induced (UI gels over thermally-induced (TI gels.

Stabilizing local boundary conditions for two-dimensional shallow water equations

KAUST Repository

Dia, Ben Mansour; Oppelstrup, Jesper

2018-01-01

In this article, we present a sub-critical two-dimensional shallow water flow regulation. From the energy estimate of a set of one-dimensional boundary stabilization problems, we obtain a set of polynomial equations with respect to the boundary

Analysis of microseismic signals and temperature recordings for rock slope stability investigations in high mountain areas

Directory of Open Access Journals (Sweden)

C. Occhiena

2012-07-01

Full Text Available The permafrost degradation is a probable cause for the increase of rock instabilities and rock falls observed in recent years in high mountain areas, particularly in the Alpine region. The phenomenon causes the thaw of the ice filling rock discontinuities; the water deriving from it subsequently freezes again inducing stresses in the rock mass that may lead, in the long term, to rock falls. To investigate these processes, a monitoring system composed by geophones and thermometers was installed in 2007 at the Carrel hut (3829 m a.s.l., Matterhorn, NW Alps. In 2010, in the framework of the Interreg 2007–2013 Alcotra project no. 56 MASSA, the monitoring system has been empowered and renovated in order to meet project needs.

In this paper, the data recorded by this renewed system between 6 October 2010 and 5 October 2011 are presented and 329 selected microseismic events are analysed. The data processing has concerned the classification of the recorded signals, the analysis of their distribution in time and the identification of the most important trace characteristics in time and frequency domain. The interpretation of the results has evidenced a possible correlation between the temperature trend and the event occurrence.

The research is still in progress and the data recording and interpretation are planned for a longer period to better investigate the spatial-temporal distribution of microseismic activity in the rock mass, with specific attention to the relation of microseismic activity with temperatures. The overall goal is to verify the possibility to set up an effective monitoring system for investigating the stability of a rock mass under permafrost conditions, in order to supply the researchers with useful data to better understand the relationship between temperature and rock mass stability and, possibly, the technicians with a valid tool for decision-making.

[Evaluation of the influence of humidity and temperature on the drug stability by initial average rate experiment].

Science.gov (United States)

He, Ning; Sun, Hechun; Dai, Miaomiao

2014-05-01

To evaluate the influence of temperature and humidity on the drug stability by initial average rate experiment, and to obtained the kinetic parameters. The effect of concentration error, drug degradation extent, humidity and temperature numbers, humidity and temperature range, and average humidity and temperature on the accuracy and precision of kinetic parameters in the initial average rate experiment was explored. The stability of vitamin C, as a solid state model, was investigated by an initial average rate experiment. Under the same experimental conditions, the kinetic parameters obtained from this proposed method were comparable to those from classical isothermal experiment at constant humidity. The estimates were more accurate and precise by controlling the extent of drug degradation, changing humidity and temperature range, or by setting the average temperature closer to room temperature. Compared with isothermal experiments at constant humidity, our proposed method saves time, labor, and materials.

Water loss at normal enamel histological points during air drying at room temperature.

Science.gov (United States)

De Medeiros, R C G; De Lima, T A S; Gouveia, C R; De Sousa, F B

2013-06-01

This in vitro study aimed to quantify water loss at histological points in ground sections of normal enamel during air drying at room temperature (25°C) and relative humidity of 50%. From each of 10 ground sections of erupted permanent human normal enamel, three histological points (n = 30) located at 100, 300 and 500 μm from enamel surface and along a transversal following prisms paths were characterized regarding the mineral, organic and water volumes. Water loss during air drying was from 0 to 48 h. Drying occurred with both falling and constant-drying rates, and drying stabilization times (Teq ) ranged from 0.5 to 11 h with a mean 0.26 (±0.12)% weight loss. In some samples (n = 5; 15 points), Teq increased as a function of the distance from the enamel surface, and drying occurred at an apparent diffusion rate of 3.47 × 10⁻⁸ cm² s⁻¹. Our data provide evidence of air drying resulting in air replacing enamel's loosely bound water in prisms sheaths following a unidirectional water diffusion rate of 3.47 × 10⁻⁸ cm² s⁻¹ (from the original enamel surface inward), not necessarily resulting in water evaporating directly into air, with important implications for transport processes and optical and mechanical properties. © 2013 The Authors Journal of Microscopy © 2013 Royal Microscopical Society.

Upgrade of the cooling water temperature measures system for HLS

International Nuclear Information System (INIS)

Guo Weiqun; Liu Gongfa; Bao Xun; Jiang Siyuan; Li Weimin; He Duohui

2007-01-01

The cooling water temperature measures system for HLS (Hefei Light Source) adopts EPICS to the developing platform and takes the intelligence temperature cruise instrument for the front control instrument. Data of temperatures are required by IOCs through Serial Port Communication, archived and searched by Channel Archiver. The system can monitor the real-time temperatures of many channels cooling water and has the function of history data storage, and data network search. (authors)

Stability analysis of the high temperature thermal pebble bed nuclear reactor concept

International Nuclear Information System (INIS)

Vondy, D.R.

1981-02-01

A study was made of the stability of the high temperature gas-cooled pebble bed core against xenon-driven oscillation. This generic study indicated that a core as large as 3000 MW(t) could be stable. Several aspects present a challenge to analysis including the void space above the pebble bed, the effects of possible control rod configurations, and the temperature feedback contribution. Special methods of analysis were developed in this effort. Of considerable utility was the scheme of including an azimuthal buckling loss term in the neturon balance equations admitting direct solution of the first azimuthal harmonic for a core having azimuthal symmetry. This technique allows the linear stability analysis to be done solving two-dimensional (RZ) problems instead of three-dimensional problems. A scheme for removing the fundamental source contribution was also implemented to allow direct iteration toward the dominant harmonic solution, treating up to three dimensions with diffusion theory

Stability analysis on natural circulation boiling water reactors

Energy Technology Data Exchange (ETDEWEB)

Metz, Peter

1999-05-01

The purpose of the study is a stability analysis of the simplified boiling water reactor concept. A fluid dynamics code, DYNOS, was developed and successfully validated against FRIGG and DESIRE data and a stability benchmark on the Ringhals 1 forced circulation BWR. Three simplified desings were considered in the analysis: The SWRIOOO by Siemens and the SBWR and ESBWR from the General Electric Co. For all three design operational characteristics, i.e. power versus flow rate maps, were calculated. The effects which different geometric and operational parameters, such as the riser height, inlet subcooling etc., have on the characteristics have been investigated. Dynamic simulations on the three simplified design revealed the geysering and the natural circulation oscillations modes only. They were, however, only encountered at pressure below 0.6 MPa. Stability maps for all tree simplified BWRs were calculated and plotted. The study concluded that a fast pressurisation of the reactor vessel is necessary to eliminate the possibility of geysering or natural circulation oscillations mode instability. (au) 26 tabs., 88 ills.

Study of Water-Oil Emulsion Breaking by Stabilized Solution Consisting of Anionic Surface Acting Agent - Soda Ash - Polymer (ASP)

Science.gov (United States)

Kulichkov, S. V.; Avtomonov, E. G.; Andreeva, L. V.; Solomennik, S. F.; Nikitina, A. V.

2018-01-01

The paper provides a laboratory research of breaking natural water-oil emulsions: - by non-stabilized ASP; by stabilized ASP; by mixture of stabilized and non-stabilized ASP in different proportions and production of refinery water of the required quality with the use of IronGuard 2495 as flocculant. Oil-in-water emulsion is stable. Classic methods are not suitable for residual water treatment: sediment gravity flow; filtration; centrifuge test. Microemulsion formed after ASP application has low boundary tension and high pH. It contributes to transfer of oil phase into a water one, forming oil-in-water emulsion. Alkaline condition has adverse effect on demulsifying ability of agents, flocculation and boundary tension. For breaking of water-oil emulsion at EBU before the interchanger water or water-oil emulsion from the wells that were not APS-treated in ratio of 1:9 shall be delivered. Residual water after EBU must be prepared in water tanks by dilution in great volume.

High-resolution gulf water skin temperature estimation using TIR/ASTER

Digital Repository Service at National Institute of Oceanography (India)

Kunte, P.D.; ManiMurali, R.; Mahender, K.

to separate geomorphic features. It is demonstrated that high resolution water skin temperature of small water bodies can be determined correctly, economically and less laboriously using space-based TIR/ASTER and that estimated temperature can be effectively...

Effect of Pouring Time and Storage Temperature on Dimensional Stability of Casts Made from Irreversible Hydrocolloid

Directory of Open Access Journals (Sweden)

M. Farzin

2010-12-01

Full Text Available Objective: The aim of this study was to evaluate the dimensional stability of casts made from an alginate impression material poured immediately and stored after specific periods.Materials and Methods: The common alginate used in Iran (Super; Iralgin, Golchai Co.,Tehran, Iran was tested. A master model was mounted on a special device and used to obtain the impressions. These impressions were stored at 23°C (SD=1 and 4°C (SD=1 in100% relative humidity, then poured with gypsum immediately and again after 12, 25, 45 and 60 minutes. The casts were measured with a traveling microscope with the precision of 0.5 micrometer.Results: The dimensional stability of the alginate and impressions were both significantly time and temperature dependent. The impressions were dimensionally stable significantly until 12 minutes of storage at room temperature and until 45 minutes of storage at 4°C(SD=1.Conclusion: The dimensional stability of the alginate impressions was influenced by the storage time and environment temperature, but a humid environment and 4°C (SD=1temperature may delay the pouring.

Low-Temperature Superionic Conductivity in Strained Yttria-Stabilized Zirconia

DEFF Research Database (Denmark)

Sillassen, Michael; Eklund, Per; Pryds, Nini

2010-01-01

Very high lateral ionic conductivities in epitaxial cubic yttria-stabilized zirconia (YSZ) synthesized on single-crystal SrTiO3 and MgO substrates by reactive direct current magnetron sputtering are reported. Superionic conductivities (i.e., ionic conductivities of the order 1 -1cm-1) are observed...... at 500 °C for 58-nm-thick films on MgO. The results indicate a superposition of two parallel contributions - one due to bulk conductivity and one attributable to conduction along the film-substrate interface. Interfacial effects dominate the conductivity at low temperatures (...

Rapid and controlled transformation of nitrate in water and brine by stabilized iron nanoparticles

International Nuclear Information System (INIS)

Xiong Zhong; Zhao Dongye; Pan Gang

2009-01-01

Highly reactive zero-valent iron (ZVI) nanoparticles stabilized with carboxymethyl cellulose (CMC) were tested for reduction of nitrate in fresh water and brine. Batch kinetic tests showed that the pseudo first-order rate constant (k obs ) with the stabilized nanoparticles was five times greater than that for non-stabilized counterparts. The stabilizer not only increased the specific surface area of the nanoparticles, but also increased the reactive particle surface. The allocation between the two reduction products, NH 4 + and N 2 , can be manipulated by varying the ZVI-to-nitrate molar ratio and/or applying a Cu-Pd bimetallic catalyst. Greater CMC-to-ZVI ratios lead to faster nitrate reduction. Application of a 0.05 M HEPES buffer increased the k obs value by 15 times compared to that without pH control. Although the presence of 6% NaCl decreased k obs by 30%, 100% nitrate was transformed within 2 h in the saline water. The technology provides a powerful alternative for treating water with concentrated nitrate such as ion exchange brine.

Surf Zone Hydrodynamics and its Utilization in Biotechnical Stabilization of Water Reservoir Banks

Directory of Open Access Journals (Sweden)

Petr Pelikán

2014-01-01

Full Text Available The water reservoir banks are eroded mainly by two factors. The first one is wave action (i.e. wave abrasion affecting the bank in direction from the reservoir. The second one is the influence of water flowing downward over the bank surface in direction from land into the reservoir (e.g. rainfall. The determination of regular altitudinal emplacement of proper designed particular biotechnical stabilization elements is the most important factor on which the right functionality of whole construction depends. Surf zone hydrodynamics solves the wave and water level changes inside the region extending from the wave breaking point to the limit of wave up-rush. The paper is focused on the utilization of piece of knowledge from a part of sea coast hydrodynamics and new approach in its application in the conditions of inland water bodies when designing the biotechnical stabilization elements along the shorelines. The “reinforced grass carpets” as a type of biotechnical method of bank stabilization are presented in the paper; whether the growth of grass root system is dependent on presence or absence of geomats in the soil structure and proceeding of their establishment on the shorelines.

Osmolyte Effects on Monoclonal Antibody Stability and Concentration-Dependent Protein Interactions with Water and Common Osmolytes.

Science.gov (United States)

Barnett, Gregory V; Razinkov, Vladimir I; Kerwin, Bruce A; Blake, Steven; Qi, Wei; Curtis, Robin A; Roberts, Christopher J

2016-04-07

Preferential interactions of proteins with water and osmolytes play a major role in controlling the thermodynamics of protein solutions. While changes in protein stability and shifts in phase behavior are often reported with the addition of osmolytes, the underlying protein interactions with water and/or osmolytes are typically inferred rather than measured directly. In this work, Kirkwood-Buff integrals for protein-water interactions (G12) and protein-osmolyte interactions (G23) were determined as a function of osmolyte concentration from density measurements of antistreptavidin immunoglobulin gamma-1 (AS-IgG1) in ternary aqueous solutions for a set of common neutral osmolytes: sucrose, trehalose, sorbitol, and poly(ethylene glycol) (PEG). For sucrose and PEG solutions, both protein-water and protein-osmolyte interactions depend strongly on osmolyte concentrations (c3). Strikingly, both osmolytes change from being preferentially excluded to preferentially accumulated with increasing c3. In contrast, sorbitol and trehalose solutions do not show large enough preferential interactions to be detected by densimetry. G12 and G23 values are used to estimate the transfer free energy for native AS-IgG1 (Δμ2N) and compared with existing models. AS-IgG1 unfolding via calorimetry shows a linear increase in midpoint temperatures as a function of trehalose, sucrose, and sorbitol concentrations, but the opposite behavior for PEG. Together, the results highlight limitations of existing models and common assumptions regarding the mechanisms of protein stabilization by osmolytes. Finally, PEG preferential interactions destabilize the Fab regions of AS-IgG1 more so than the CH2 or CH3 domains, illustrating preferential interactions can be specific to different protein domains.

A hierarchical bayesian model to quantify uncertainty of stream water temperature forecasts.

Directory of Open Access Journals (Sweden)

Guillaume Bal

Full Text Available Providing generic and cost effective modelling approaches to reconstruct and forecast freshwater temperature using predictors as air temperature and water discharge is a prerequisite to understanding ecological processes underlying the impact of water temperature and of global warming on continental aquatic ecosystems. Using air temperature as a simple linear predictor of water temperature can lead to significant bias in forecasts as it does not disentangle seasonality and long term trends in the signal. Here, we develop an alternative approach based on hierarchical Bayesian statistical time series modelling of water temperature, air temperature and water discharge using seasonal sinusoidal periodic signals and time varying means and amplitudes. Fitting and forecasting performances of this approach are compared with that of simple linear regression between water and air temperatures using i an emotive simulated example, ii application to three French coastal streams with contrasting bio-geographical conditions and sizes. The time series modelling approach better fit data and does not exhibit forecasting bias in long term trends contrary to the linear regression. This new model also allows for more accurate forecasts of water temperature than linear regression together with a fair assessment of the uncertainty around forecasting. Warming of water temperature forecast by our hierarchical Bayesian model was slower and more uncertain than that expected with the classical regression approach. These new forecasts are in a form that is readily usable in further ecological analyses and will allow weighting of outcomes from different scenarios to manage climate change impacts on freshwater wildlife.

Effects of ion temperature fluctuations on the stability of resistive ballooning modes

International Nuclear Information System (INIS)

Singh, R.; Nordman, H.; Jarmen, A.; Weiland, J.

1996-01-01

The influence of ion temperature fluctuations on the stability of resistive drift- and ballooning-modes is investigated using a two-fluid model. The Eigenmode equations are derived and solved analytically in a low beta model equilibrium. Parameters relevant to L-mode edge plasmas from the Texas Experimental Tokamak are used. The resistive modes are found to be destabilized by ion temperature fluctuations over a broad range of mode numbers. The scaling of the growth rate with magnetic shear and mode number is elucidated. 13 refs, 4 figs

Increasing Water Temperature Triggers Dominance of Small Freshwater Plankton.

Science.gov (United States)

Rasconi, Serena; Gall, Andrea; Winter, Katharina; Kainz, Martin J

2015-01-01

Climate change scenarios predict that lake water temperatures will increase up to 4°C and rainfall events will become more intense and frequent by the end of this century. Concurrently, supply of humic substances from terrestrial runoff is expected to increase, resulting in darker watercolor ("brownification") of aquatic ecosystems. Using a multi-seasonal, low trophic state mesocosm experiment, we investigated how higher water temperature and brownification affect plankton community composition, phenology, and functioning. We tested the hypothesis that higher water temperature (+3°C) and brownification will, a) cause plankton community composition to shift toward small sized phytoplankton and cyanobacteria, and, b) extend the length of the growing season entailing higher phytoplankton production later in the season. We demonstrate that the 3°C increase of water temperature favored the growth of heterotrophic bacteria and small sized autotrophic picophytoplankton cells with significantly higher primary production during warmer fall periods. However, 3X darker water (effect of brownification) caused no significant changes in the plankton community composition or functioning relative to control conditions. Our findings reveal that increased temperature change plankton community structure by favoring smaller sized species proliferation (autotrophic phytoplankton and small size cladocerans), and increase primary productivity and community turnover. Finally, results of this multi-seasonal experiment suggest that warming by 3°C in aquatic ecosystems of low trophic state may cause planktonic food web functioning to become more dominated by fast growing, r-trait species (i.e., small sizes and rapid development).

Temperature-dependent photoluminescence of water-soluble quantum dots for a bioprobe

International Nuclear Information System (INIS)

Liu Tiancai; Huang Zhenli; Wang Haiqiao; Wang Jianhao; Li Xiuqing; Zhao Yuandi; Luo Qingming

2006-01-01

The photoluminescence of water-soluble CdSe/ZnS core/shell quantum dots is found to be temperature-dependent: as temperature arising from 280 K to 351 K, the photoluminescence declines with emission peak shifting towards the red at a rate of ∼0.11 nm K -1 . And the studies show that the photoluminescence of water-soluble CdSe/ZnS quantum dots with core capped by a thinner ZnS shell is more sensitive to temperature than that of ones with core capped by a thicker one. That is, with 50% decrement of the quantum yield the temperature of the former need to arise from 280 K to 295 K, while the latter requires much higher temperature (315.6 K), which means that the integrality of shell coverage is a very important factor on temperature-sensitivity to for the photoluminescence of water-soluble CdSe/ZnS quantum dots. Moreover, it is found that the water-soluble CdSe quantum dots with different core sizes, whose cores are capped by thicker ZnS shells, possess almost the same sensitivity to the temperature. All of the studies about photoluminescence temperature-dependence of water-soluble CdSe/ZnS core/shell quantum dots show an indispensable proof for their applications in life science

Temperature-dependent photoluminescence of water-soluble quantum dots for a bioprobe

Energy Technology Data Exchange (ETDEWEB)

Liu Tiancai [Key Laboratory of Biomedical Photonics of Ministry of Education - Hubei Bioinformatics and Molecular Imaging Key Laboratory, Huazhong University of Science and Technology, Wuhan, Hubei 430074 (China); Huang Zhenli [Key Laboratory of Biomedical Photonics of Ministry of Education - Hubei Bioinformatics and Molecular Imaging Key Laboratory, Huazhong University of Science and Technology, Wuhan, Hubei 430074 (China); Wang Haiqiao [Key Laboratory of Biomedical Photonics of Ministry of Education - Hubei Bioinformatics and Molecular Imaging Key Laboratory, Huazhong University of Science and Technology, Wuhan, Hubei 430074 (China); Wang Jianhao [Key Laboratory of Biomedical Photonics of Ministry of Education - Hubei Bioinformatics and Molecular Imaging Key Laboratory, Huazhong University of Science and Technology, Wuhan, Hubei 430074 (China); Li Xiuqing [Key Laboratory of Biomedical Photonics of Ministry of Education - Hubei Bioinformatics and Molecular Imaging Key Laboratory, Huazhong University of Science and Technology, Wuhan, Hubei 430074 (China); Zhao Yuandi [Key Laboratory of Biomedical Photonics of Ministry of Education - Hubei Bioinformatics and Molecular Imaging Key Laboratory, Huazhong University of Science and Technology, Wuhan, Hubei 430074 (China)]. E-mail: zydi@mail.hust.edu.cn; Luo Qingming [Key Laboratory of Biomedical Photonics of Ministry of Education - Hubei Bioinformatics and Molecular Imaging Key Laboratory, Huazhong University of Science and Technology, Wuhan, Hubei 430074 (China)

2006-02-10

The photoluminescence of water-soluble CdSe/ZnS core/shell quantum dots is found to be temperature-dependent: as temperature arising from 280 K to 351 K, the photoluminescence declines with emission peak shifting towards the red at a rate of {approx}0.11 nm K{sup -1}. And the studies show that the photoluminescence of water-soluble CdSe/ZnS quantum dots with core capped by a thinner ZnS shell is more sensitive to temperature than that of ones with core capped by a thicker one. That is, with 50% decrement of the quantum yield the temperature of the former need to arise from 280 K to 295 K, while the latter requires much higher temperature (315.6 K), which means that the integrality of shell coverage is a very important factor on temperature-sensitivity to for the photoluminescence of water-soluble CdSe/ZnS quantum dots. Moreover, it is found that the water-soluble CdSe quantum dots with different core sizes, whose cores are capped by thicker ZnS shells, possess almost the same sensitivity to the temperature. All of the studies about photoluminescence temperature-dependence of water-soluble CdSe/ZnS core/shell quantum dots show an indispensable proof for their applications in life science.

Feasibility of active solar water heating systems with evacuated tube collector at different operational water temperatures

International Nuclear Information System (INIS)

Mazarrón, Fernando R.; Porras-Prieto, Carlos Javier; García, José Luis; Benavente, Rosa María

2016-01-01

Highlights: • Analysis of the feasibility of an active solar water-heating system. • Profitability decreases as the required water temperature increases. • The number of collectors that maximizes profitability depends on the required temperature. • Investment in a properly sized system generates savings between 23% and 15%. • Fuel consumption can be reduced by 70%. - Abstract: With rapid advancements in society, higher water temperatures are needed in a number of applications. The demand for hot water presents a great variability with water required at different temperatures. In this study, the design, installation, and evaluation of a solar water heating system with evacuated tube collector and active circulation has been carried out. The main objective is to analyze how the required tank water temperature affects the useful energy that the system is capable of delivering, and consequently its profitability. The results show how the energy that is collected and delivered to the tank decreases with increasing the required temperature due to a lower performance of the collector and losses in the pipes. The annual system efficiency reaches average values of 66%, 64%, 61%, 56%, and 55% for required temperatures of 40 °C, 50 °C, 60 °C, 70 °C, and 80 °C. As a result, profitability decreases as temperature increases. The useful energy, and therefore the profitability, will decrease if the demand is not distributed throughout the day or focused on the end of the day. The system’s profitability was determined in two cases: considering maximum profitability of the system, assuming 100% utilization of useful energy (scenario 1); assuming a particular demand, considering that on many days all the useful energy the system can supply is not used (scenario 2). The analysis shows that through proper sizing of the system, optimizing the number of solar collectors, the investment in the solar system can be profitable with similar profitability values in the two

Spatial and temporal stability of temperature in the first-level basins of China during 1951-2013

Science.gov (United States)

Cheng, Yuting; Li, Peng; Xu, Guoce; Li, Zhanbin; Cheng, Shengdong; Wang, Bin; Zhao, Binhua

2018-05-01

In recent years, global warming has attracted great attention around the world. Temperature change is not only involved in global climate change but also closely linked to economic development, the ecological environment, and agricultural production. In this study, based on temperature data recorded by 756 meteorological stations in China during 1951-2013, the spatial and temporal stability characteristics of annual temperature in China and its first-level basins were investigated using the rank correlation coefficient method, the relative difference method, rescaled range (R/S) analysis, and wavelet transforms. The results showed that during 1951-2013, the spatial variation of annual temperature belonged to moderate variability in the national level. Among the first-level basins, the largest variation coefficient was 114% in the Songhuajiang basin and the smallest variation coefficient was 10% in the Huaihe basin. During 1951-2013, the spatial distribution pattern of annual temperature presented extremely strong spatial and temporal stability characteristics in the national level. The variation range of Spearman's rank correlation coefficient was 0.97-0.99, and the spatial distribution pattern of annual temperature showed an increasing trend. In the national level, the Liaohe basin, the rivers in the southwestern region, the Haihe basin, the Yellow River basin, the Yangtze River basin, the Huaihe basin, the rivers in the southeastern region, and the Pearl River basin all had representative meteorological stations for annual temperature. In the Songhuajiang basin and the rivers in the northwestern region, there was no representative meteorological station. R/S analysis, the Mann-Kendall test, and the Morlet wavelet analysis of annual temperature showed that the best representative meteorological station could reflect the variation trend and the main periodic changes of annual temperature in the region. Therefore, strong temporal stability characteristics exist for

Feasibility of suspension spraying of yttria-stabilized zirconia with water-stabilized plasma torch

Czech Academy of Sciences Publication Activity Database

Mušálek, Radek; Bertolissi, Gabriele; Medřický, J.; Kotlan, Jiří; Pala, Zdeněk; Curry, N.

2015-01-01

Roč. 268, April (2015), s. 58-62 ISSN 0257-8972. [Rencontres Internationales de la Projection Thermique/6./. Limoges, 11.12.2013-13.12.2013] R&D Projects: GA ČR(CZ) GPP108/12/P552 Institutional support: RVO:61389021 Keywords : Thermal spray coating * Suspension spray ing * Thermal barrier coating * Water-stabilized plasma * High enthalpy plasma Subject RIV: JK - Corrosion ; Surface Treatment of Materials Impact factor: 2.139, year: 2015 http://www.sciencedirect.com/science/article/pii/S025789721400680X

Whole body cooling by immersion in water at moderate temperatures.

Science.gov (United States)

Marino, F; Booth, J

1998-06-01

This study investigated the potential use of whole body cooling by water immersion for lowering body temperatures prior to endurance exercise. Rectal temperature (Tre), mean skin temperature (Tsk), oxygen consumption (VO2), and ventilation (VE) were measured in 7 male and 3 female subjects who were immersed in a water bath for up to 60 min. Initial water temperature was 28.8+/-1.5 degrees C and decreased to 23.8+/-1.1 degrees C by the end of immersion. Pre-immersion Tre of 37.34+/-0.36 degrees C was not altered by 60 min water immersion but decreased to 36.64+/-0.34 degrees C at 3 min post immersion (p immersion. Reductions in Tre and Tsk resulted in reduced body heat content (Hc) of approximately 545 kJ (p immersion. VO2 and VE increased from pre-immersion values of 0.34+/-0.08 L x min(-1) and 6.2+/-1.4 L x min(-1) to 0.54+/-0.09 L x min(-) and 11.5+/-5.4 L x min(-1) at the end of immersion, respectively. Heart rate remained unchanged throughout immersion. These results indicate that whole body immersion in moderately cold water temperatures is an effective cooling maneuver for lowering body temperatures and body Hc in the absence of severe physiological responses generally associated with sudden cold stress.

High temperature stability of surfactant capped CoFe2O4 nanoparticles

International Nuclear Information System (INIS)

Ayyappan, S.; Panneerselvam, G.; Antony, M.P.; Philip, John

2011-01-01

Highlights: → Self-assembled molecular layers of surfactant on nanoparticles are often used to modify surface properties. → We demonstrate that a surfactant nanolayer on CoFe 2 O 4 nanoparticles can act as a strong reducing agent under high temperature vacuum annealing. → We propose a possible reduction mechanism of CoFe 2 O 4 nanoparticles under air and vacuum annealing. → Our results are important in the understanding of the stability of nanoparticles at high temperatures. - Abstract: We investigate the effect of adsorbed surfactant on the structural stability of CoFe 2 O 4 nanoparticles during vacuum thermal annealing. In-situ high temperature X-ray diffraction studies show a reduction of oleic acid coated CoFe 2 O 4 nanoparticles into α-Fe and CoO under annealing at 800 deg. C. On the contrary, the uncoated CoFe 2 O 4 nanoparticles remains stable, with its cubic phase intact, even at 1000 deg. C. Thermo-gravimetric analysis coupled mass spectra reveals that the evolved carbon from the surfactant aids the removal of oxygen atom from CoFe 2 O 4 lattice thereby reducing it to α-Fe and CoO phases. These results are important in tailoring stable CoFe 2 O 4 nanostructures for various applications.

Stability of ‘mangaba’ pulp powder obtained by freeze drying

Directory of Open Access Journals (Sweden)

Juliana Conegero

Full Text Available ABSTRACT This work examined the stability of lyophilized ‘mangaba’ pulp powder, rolled and packaged in plastic containers, with and without vacuum during 90 days of storage under room temperature, with evaluation of the parameters every 15 days. Analyses of ascorbic acid concentration, pH, color and water activity were carried out. It was found that ascorbic acid remained in accordance with the standards specified for daily consumption according to the Brazilian legislation in all analyzed packages, with preservation of stability in the laminated package with vacuum, which was also effective in maintaining water activity, which contributes to better stability of the product.

Composite cathode based on yttria stabilized bismuth oxide for low-temperature solid oxide fuel cells

International Nuclear Information System (INIS)

Xia Changrong; Zhang Yuelan; Liu Meilin

2003-01-01

Composites consisting of silver and yttria stabilized bismuth oxide (YSB) have been investigated as cathodes for low-temperature honeycomb solid oxide fuel cells with stabilized zirconia as electrolytes. At 600 deg. C, the interfacial polarization resistances of a porous YSB-Ag cathode is about 0.3 Ω cm 2 , more than one order of magnitude smaller than those of other reported cathodes on stabilized zirconia. For example, the interfacial resistances of a traditional YSZ-lanthanum maganites composite cathode is about 11.4 Ω cm 2 at 600 deg. C. Impedance analysis indicated that the performance of an YSB-Ag composite cathode fired at 850 deg. C for 2 h is severely limited by gas transport due to insufficient porosity. The high performance of the YSB-Ag cathodes is very encouraging for developing honeycomb fuel cells to be operated at temperatures below 600 deg. C

Investigation on Synthesis, Stability, and Thermal Conductivity Properties of Water-Based SnO2/Reduced Graphene Oxide Nanofluids

Science.gov (United States)

Yu, Xiaofen; Wu, Qibai; Zhang, Haiyan; Zeng, Guoxun; Li, Wenwu; Qian, Yannan; Li, Yang; Yang, Guoqiang; Chen, Muyu

2017-01-01

With the rapid development of industry, heat removal and management is a major concern for any technology. Heat transfer plays a critically important role in many sectors of engineering; nowadays utilizing nanofluids is one of the relatively optimized techniques to enhance heat transfer. In the present work, a facile low-temperature solvothermal method was employed to fabricate the SnO2/reduced graphene oxide (rGO) nanocomposite. X-ray diffraction (XRD), thermogravimetric analysis (TGA), X-ray photoelectron spectroscope (XPS), Raman spectroscopy, and transmission electron microscopy (TEM) have been performed to characterize the SnO2/rGO nanocomposite. Numerous ultrasmall SnO2 nanoparticles with average diameters of 3–5 nm were anchored on the surface of rGO, which contain partial hydrophilic functional groups. Water-based SnO2/rGO nanofluids were prepared with various weight concentrations by using an ultrasonic probe without adding any surfactants. The zeta potential was measured to investigate the stability of the as-prepared nanofluid which exhibited great dispersion stability after quiescence for 60 days. A thermal properties analyzer was employed to measure thermal conductivity of water-based SnO2/rGO nanofluids, and the results showed that the enhancement of thermal conductivity could reach up to 31% at 60 °C under the mass fraction of 0.1 wt %, compared to deionized water. PMID:29280972

Investigation on Synthesis, Stability, and Thermal Conductivity Properties of Water-Based SnO2/Reduced Graphene Oxide Nanofluids

Directory of Open Access Journals (Sweden)

Xiaofen Yu

2017-12-01

Full Text Available With the rapid development of industry, heat removal and management is a major concern for any technology. Heat transfer plays a critically important role in many sectors of engineering; nowadays utilizing nanofluids is one of the relatively optimized techniques to enhance heat transfer. In the present work, a facile low-temperature solvothermal method was employed to fabricate the SnO2/reduced graphene oxide (rGO nanocomposite. X-ray diffraction (XRD, thermogravimetric analysis (TGA, X-ray photoelectron spectroscope (XPS, Raman spectroscopy, and transmission electron microscopy (TEM have been performed to characterize the SnO2/rGO nanocomposite. Numerous ultrasmall SnO2 nanoparticles with average diameters of 3–5 nm were anchored on the surface of rGO, which contain partial hydrophilic functional groups. Water-based SnO2/rGO nanofluids were prepared with various weight concentrations by using an ultrasonic probe without adding any surfactants. The zeta potential was measured to investigate the stability of the as-prepared nanofluid which exhibited great dispersion stability after quiescence for 60 days. A thermal properties analyzer was employed to measure thermal conductivity of water-based SnO2/rGO nanofluids, and the results showed that the enhancement of thermal conductivity could reach up to 31% at 60 °C under the mass fraction of 0.1 wt %, compared to deionized water.

Changes in soil aggregate stability under different irrigation doses of waste water

Science.gov (United States)

Morugán, Alicia; García-Orenes, Fuensanta; Mataix-Solera, Jorge; Arcenegui, Victoria; Bárcenas, Gema

2010-05-01

Freshwater availability and soil degradation are two of the most important environmental problems in the Mediterranean area acerbated by incorrect agricultural use of irrigation in which organic matter is not correctly managed, the use of low quality water for irrigation, and the inefficiency of dose irrigation. For these reasons strategies for saving water and for the restoration of the mean properties of soil are necessary. The use of treated waste water for the irrigation of agricultural land could be a good solution to these problems, as it reduces the utilization of fresh water and could potentially improve key soil properties. In this work we have been studying, for more than three years, the effects on soil properties of different doses of irrigation with waste water. Here we show the results on aggregate stability. The study is located in an agricultural area at Biar (Alicante, SE of Spain), with a crop of grape (Vitis labrusca). Three types of waters are being used in the irrigation of the soil: fresh water (control) (TC), and treated waste water from secondary (T2) and tertiary treatment (T3). Three different doses of irrigation have been applied to fit the efficiency of the irrigation to the crop and soil type: D10 (10 L m-2 every week during 17 months), D50 (50 L m-2 every fifteen days during 14 moths) and D30 (30 L m-2 every week during 6 months up to present day). The results showed a clear decrease of aggregate stability during the period we used the second dose (D50) independent of the type of water used. That dose of irrigation and frequency produced strong wetting and drying cycles (WD) in the soil, and this is suspected to be the main factor responsible for the results. When we changed the dose of irrigation to D30, reducing the quantity per event and increasing the frequency, the soil aggregate stability started to improve. This dose avoids strong drying periods between irrigation events and the aggregate stability is confirmed to be slowly

Coupling Meteorological, Land Surface and Water Temperature Models in the Mississippi River Basin

Science.gov (United States)

Tang, C.; Cooter, E. J.

2017-12-01

Water temperature is a significant factor influencing of the stream ecosystem and water management especially under climate change. In this study, we demonstrate a physically based semi-Lagrangian water temperature model (RBM) coupled with the Variable Infiltration Capacity (VIC) hydrology model and Weather Research & Forecasting Model (WRF) in the Mississippi River Basin (MRB). The results of this coupling compare favorably with observed water temperature data at river gages throughout the MRB. Further sensitivity analysis shows that mean water temperatures increase by 1.3°C, 1.5°C, and 1.8°C in northern, central and southern MRB zones, respectively, under a hypothetical uniform air temperature increase of 3°C. If air temperatures increase uniformly by 6°C in this scenario, then water temperatures are projected to increase by 3.3°C, 3.5°C and 4.0°C. Lastly, downscaled air temperatures from a global climate model are used to drive the coupled VIC and RBM model from 2020 to 2099. Average stream temperatures from 2020 to 2099 increase by 1°C to 8°C above 1950 to 2010 average water temperatures, with non-uniform increases along the river. In some portions of the MRB, stream temperatures could increase above survival thresholds for several native fish species, which are critical components of the stream ecosystem. The increased water temperature accelerates harmful algal blooming which results in a larger dead zone in the Gulf of Mexico.

Water and sediment temperature dynamics in shallow tidal environments: The role of the heat flux at the sediment-water interface

Science.gov (United States)

Pivato, M.; Carniello, L.; Gardner, J.; Silvestri, S.; Marani, M.

2018-03-01

In the present study, we investigate the energy flux at the sediment-water interface and the relevance of the heat exchanged between water and sediment for the water temperature dynamics in shallow coastal environments. Water and sediment temperature data collected in the Venice lagoon show that, in shallow, temperate lagoons, temperature is uniform within the water column, and enabled us to estimate the net heat flux at the sediment-water interface. We modeled this flux as the sum of a conductive component and of the solar radiation reaching the bottom, finding the latter being negligible. We developed a "point" model to describe the temperature dynamics of the sediment-water continuum driven by vertical energy transfer. We applied the model considering conditions characterized by negligible advection, obtaining satisfactory results. We found that the heat exchange between water and sediment is crucial for describing sediment temperature but plays a minor role on the water temperature.

Silicon photomultiplier's gain stabilization by bias correction for compensation of the temperature fluctuations

Energy Technology Data Exchange (ETDEWEB)

Dorosz, P., E-mail: pdorosz@agh.edu.pl [AGH University of Science and Technology, Faculty of Electrical Engineering, Automatics, Computer Science and Electronics, Department of Electronics, 30-059 Krakow (Poland); Baszczyk, M.; Glab, S. [AGH University of Science and Technology, Faculty of Electrical Engineering, Automatics, Computer Science and Electronics, Department of Electronics, 30-059 Krakow (Poland); Kucewicz, W., E-mail: kucewicz@agh.edu.pl [AGH University of Science and Technology, Faculty of Electrical Engineering, Automatics, Computer Science and Electronics, Department of Electronics, 30-059 Krakow (Poland); Mik, L.; Sapor, M. [AGH University of Science and Technology, Faculty of Electrical Engineering, Automatics, Computer Science and Electronics, Department of Electronics, 30-059 Krakow (Poland)

2013-08-01

Gain of the silicon photomultiplier is strongly dependent on the value of bias voltage and temperature. This paper proposes a method for gain stabilization just by compensation of temperature fluctuations by bias correction. It has been confirmed that this approach gives good results and the gain can be kept very stable.

The exploration of stability of two-dimensional nanocrystalline metallic composites depending on temperature

International Nuclear Information System (INIS)

Poletayev, G.M.; Starostenkov, M.D.; Popova, G.V.; Skakov, M.K.

2004-01-01

Full text: In nanocrystalline compositional materials the borders of phase separation play special role. The detection of stability of the borders of phase separation depending on external conditions, such pressure, temperature of alloying is the important task in the case of nanocrystalline materials. In the current paper the stability of two-dimensional nanocrystal, composite on the basis of Ni-Al system, depending on the structure of compositional material and vacancy availability is studied. Atomic packing in two-dimensional crystal corresponds to the plane (111) of fee crystal structure, or the plane (111) of superstructure L1 2 of intermetallide system Ni-Al. The interaction between atoms is set by pair potential functions of Morse, that consider interatomic bonding in the first six coordinate spheres. The calculated block was expressed in atomic packing in the cell 40x40. Beyond the bounds of the calculated block crystal is repeated with the help of periodical border conditions. Computer modeling is performed according to the method of molecular dynamics, when speeds of atom dislocations depending on temperature are set in accidental way, according to Boltzmann allocation. Two-dimensional material was represented by different packs of phases, clean Ni, Al and intermetallic superstructure NiAl in accordance with concentrations, structures and forms. It was understood that when the concentration in composite of phase of clean Al increases, or when the number of Al atoms in intermetallide rises, the initial temperature of thermo activated diffusing destruction of interphase borders turns out to be very low. On the other hand, when the part of clean nickel increases or when the concentration of clean Ni atoms in the structure (L1 2 ) rises, diffusion stability of interphase borders is observes right up to high temperatures. According to the results, basic diffusion processes take place right on interphase borders

Dynamic behaviour of bubbles of water vapour at a temperature lower than the boiling temperature

International Nuclear Information System (INIS)

Jansen, Franz

1966-01-01

This research thesis reports the study of the theoretical movement of the wall of vapour water bubbles in a sub-saturated boiling regime, i.e. with an average water temperature lower than the boiling temperature. While assuming that bubbles have an initial translational speed at the beginning of their condensation, the author shows that their shrinkage should result in an accelerated displacement in a direction normal to the wall and inward the liquid. Layers of hot water initially close to the wall would therefore be quickly transported towards cold water areas. Experiments allowed, in some cases, the acceleration of bubbles during their condensation to be noticed: for low sub-saturations in still water and for high sub-saturations in water in forced convection, even though, in this last case, the determination of accelerations is more delicate [fr

Process for stabilizing dimensions of duplex stainless steels for service at elevated temperatures

Science.gov (United States)

Hull, Frederick C.; Tobin, John C.

1981-01-01

Duplex stainless steel materials containing austenite plus delta ferrite, are dimensionally stabilized by heating the material to a reaction temperature between about 1050.degree.-1450.degree. F. (566.degree.-788.degree. C.), holding it at this temperature during transformation of delta ferrite to austenite plus sigma phase, and subsequently heating to a reversion temperature between about 1625.degree.-1750.degree. F. (885.degree.-954.degree. C.), whereby the sigma phase transforms back to ferrite, but the austenite remains dispersed in the ferrite phase. Final controlled cooling permits transformation of ferrite to austenite plus sigma and, later, precipitation of carbides.

Effect of copper additions in tin molten pool on stability temperature and critical current of Nb3Sn

International Nuclear Information System (INIS)

Kruzliak, J.; Hutka, P.; Tomasich, M.

1979-01-01

Tested is the effect of 55 at% copper addition into the tin bath on the stability temperature and crytical current of Nb 3 Sn, prepared by the diffusion method. It is shown that copper presence in the tin bath transfers the stability temperature of NbSn 2 and Nb 6 Sn 5 phases below the annealing temperature of 700 deg C. It results in Nb 3 Sn appearance at the annealing temperatures above 600 deg C. The critical current increase is explained as follows: lower Nb 3 Sn appearance temperatures provide fine-grained structure of superconducting Nb 3 Sn layer with greater density of binning centers and with higher critical current in accordance with NbSn prepared by the diffusion of pure tin into niobium

Ceramic stabilization of hazardous wastes: a high performance room temperature process

International Nuclear Information System (INIS)

Maloney, M.D.

1996-01-01

ANL has developed a room-temperature process for converting hazardous materials to a ceramic structure. It is similar to vitrification but is achieved at low cost, similar to conventional cement stabilization. The waste constituents are both chemically stabilized and physically encapsulated, producing very low leaching levels and the potential for delisting. The process, which is pH-insensitive, is ideal for inorganic sludges and liquids, as well as mixed chemical-radioactive wastes, but can also handle significant percentages of salts and even halogenated organics. High waste loadings are possible and densification occurs,so that volumes are only slightly increased and in some cases (eg, incinerator ash) are reduced. The ceramic product has strength and weathering properties far superior to cement products

Increasing Water Temperature Triggers Dominance of Small Freshwater Plankton.

Directory of Open Access Journals (Sweden)

Serena Rasconi

Full Text Available Climate change scenarios predict that lake water temperatures will increase up to 4°C and rainfall events will become more intense and frequent by the end of this century. Concurrently, supply of humic substances from terrestrial runoff is expected to increase, resulting in darker watercolor ("brownification" of aquatic ecosystems. Using a multi-seasonal, low trophic state mesocosm experiment, we investigated how higher water temperature and brownification affect plankton community composition, phenology, and functioning. We tested the hypothesis that higher water temperature (+3°C and brownification will, a cause plankton community composition to shift toward small sized phytoplankton and cyanobacteria, and, b extend the length of the growing season entailing higher phytoplankton production later in the season. We demonstrate that the 3°C increase of water temperature favored the growth of heterotrophic bacteria and small sized autotrophic picophytoplankton cells with significantly higher primary production during warmer fall periods. However, 3X darker water (effect of brownification caused no significant changes in the plankton community composition or functioning relative to control conditions. Our findings reveal that increased temperature change plankton community structure by favoring smaller sized species proliferation (autotrophic phytoplankton and small size cladocerans, and increase primary productivity and community turnover. Finally, results of this multi-seasonal experiment suggest that warming by 3°C in aquatic ecosystems of low trophic state may cause planktonic food web functioning to become more dominated by fast growing, r-trait species (i.e., small sizes and rapid development.

Temperature dependence of HU values for various water equivalent phantom materials

International Nuclear Information System (INIS)

Homolka, P.; Nowotny, R.; Gahleitner, A.

2002-01-01

The temperature dependence of water equivalent phantom materials used in radiotherapy and diagnostic imaging has been investigated. Samples of phantom materials based on epoxy resin, polyethylene, a polystyrene-polypropylene mixture and commercially available phantom materials (Solid Water TM , Gammex RMI and Plastic Water TM , Nuclear Associates) were scanned at temperatures from 15 to 40 deg. C and HU values determined. At a reference temperature of 20 deg. C materials optimized for CT applications give HU values close to zero while the commercial materials show an offset of 119.77 HU (Plastic Water) and 27.69 HU (Solid Water). Temperature dependence was lowest for epoxy-based materials (EPX-W: -0.23 HU deg. C -1 ; Solid Water: -0.25 HU deg. C -1 ) and highest for a polyethylene-based material (X0: -0.72 HU deg. C -1 ). A material based on a mixture of polystyrene and polypropylene (PSPP1: -0.27 HU deg. C -1 ) is comparable to epoxy-based materials and water (-0.29 HU deg. C -1 ). (author)

Structural stability of the smectite-doped lanthanum under high pressures and high temperatures

International Nuclear Information System (INIS)

Stefani, Vicente Fiorini

2012-01-01

Smectites are phyllosilicates that have a tetrahedron: octahedron structure ratio of 2:1, with high cation exchange capacity (CEC) in the interlayers. For these and other features, smectites have been used in many parts of the world as secondary barriers with the goal of containing a possible leak of radioactive elements in final disposal facilities for radioactive waste through cation exchange. Our aim in this work is to reach the cation exchange in calcium montmorillonite (smectite dioctahedral) by lanthanum to simulate trivalent radionuclides and to study the stability of this structure under high pressure and high temperature. To achieve high pressure it was used two different technique: DAC (Diamond Anvil Cell), achieving pressures up to 12GPa at room temperature and hydraulic press with a toroidal chamber profile to achieve pressures up to 7,7GPa and temperatures up to 900 degree C. The heating is achieved simultaneously by an electric system coupled in the hydraulic press. The outcomes show that the smectite structure doped with lanthanum remains stable under 12GPa at room temperature and 2.5GPa at 200 degree C. However, above 300 degree C at 2.5GPa the structure becomes a new phase of muscovite-like, rich of La, where it loses its interlayer water and turns out to be irreversible. Furthermore, it is important to point out that the higher temperature the better ordered is the structure and it is still stable under 7.7GPa and 900 degree C. Moreover, after all experiments the structure continues being dioctahedral. The new phase of muscovite-like, rich of La, in contact with a calcium solution remains partially unchanged, whereas the other part returns to the original structure (montmorillonite-Ca). The following analyses were performed: X-ray diffraction (XRD) for evaluating the spatial structure; Fourier transform infrared spectroscopy (FTIR) for getting information about the vibrational modes; scanning electron microscopy with dispersive Xray spectroscopy

Size and temperature dependent stability and phase transformation in single-crystal zirconium nanowire

International Nuclear Information System (INIS)

Sutrakar, Vijay Kumar; Roy Mahapatra, D.

2011-01-01

A novel size dependent FCC (face-centered-cubic) → HCP (hexagonally-closed-pack) phase transformation and stability of an initial FCC zirconium nanowire are studied. FCC zirconium nanowires with cross-sectional dimensions 20 Å, in which surface stresses are not enough to drive the phase transformation, show meta-stability. In such a case, an external kinetic energy in the form of thermal heating is required to overcome the energy barrier and achieve FCC → HCP phase transformation. The FCC-HCP transition pathway is also studied using Nudged Elastic Band (NEB) method, to further confirm the size dependent stability/metastability of Zr nanowires. We also show size dependent critical temperature, which is required for complete phase transformation of a metastable-FCC nanowire.

Dispersion Stability of O/W Emulsions with Different Oil Contents Under Various Freezing and Thawing Conditions.

Science.gov (United States)

Katsuki, Kazutaka; Miyagawa, Yayoi; Nakagawa, Kyuya; Adachi, Shuji

2017-07-01

Freezing and thawing of oil-in-water (O/W) emulsion-type foods bring about oil-water separation and deterioration; hence, the effects of freezing and thawing conditions on the destabilization of O/W emulsions were examined. The freezing rate and thawing temperature hardly affected the stability of the O/W emulsion. O/W emulsions having different oil fractions were stored at temperatures ranging from -30 to -20 °C and then thawed. The stability after thawing depended on the storage temperature, irrespective of the oil fraction of the emulsion. A good correlation was found between the time at which the stability began to decrease and the time taken for the oil to crystalize. These results indicated that the dominant cause for the destabilization of the O/W emulsion during freezing and thawing is the crystallization of the oil phase and that the effects of the freezing and thawing rates on the stability are insignificant. © 2017 Institute of Food Technologists®.

[Influence of an elevation of the temperature of water on the digestibility of dry matter, nitrogen and energy of food distributed to the rainbow trout (Salmo gairdneri Rich)].

Science.gov (United States)

Choubert, G; Fauconneau, B; Luquet, P

1982-01-01

Rainbow trout adapted to a water temperature of 10 degrees C were subjected to an abrupt rise in temperature (from 10 to 18 degrees C) in a 24-h period. Fish maintained in recirculated water were fed to satiation twice a day and their feed intakes were recorded. Changes in dry matter, nitrogen and energy digestibility were measured each day at 10 degrees C and during the course of acclimatation to 18 degrees C. Low water temperature (10 degrees C) was characterized by a feed intake of 1.84 g (DM)/fish/day; digestibility values were as follows: dry matter 62.15 p. 100, nitrogen 86.91 p. 100, energy 70.60 p. 100. High water temperature (18 degrees C) was characterized by a feed intake of 3.75 g (DM)/fish/day; digestibility values were as follows: dry matter 66.08 p. 100, nitrogen 89.57 p. 100, energy 73.52 p. 100. The daily patterns in digestibility were affected by the rise in temperature. The digestibility values were stabilized by day 7 after the positive thermal shock.

Adiabatic flame temperature of sodium combustion and sodium-water reaction

International Nuclear Information System (INIS)

Okano, Y.; Yamaguchi, A.

2001-01-01

In this paper, background information of sodium fire and sodium-water reaction accidents of LMFBR (liquid metal fast breeder reactor) is mentioned at first. Next, numerical analysis method of GENESYS is described in detail. Next, adiabatic flame temperature and composition of sodium combustion are analyzed, and affect of reactant composition, such oxygen and moisture, is discussed. Finally, adiabatic reaction zone temperature and composition of sodium-water reaction are calculated, and affects of reactant composition, sodium vaporization, and pressure are stated. Chemical equilibrium calculation program for generic chemical system (GENESYS) is developed in this study for the research on adiabatic flame temperature of sodium combustion and adiabatic reaction zone temperature of sodium-water reaction. The maximum flame temperature of the sodium combustion is 1,950 K at the standard atmospheric condition, and is not affected by the existence of moisture. The main reaction product is Na 2 O (l) , and in combustion in moist air, with NaOH (g) . The maximum reaction zone temperature of the sodium-water reaction is 1,600 K, and increases with the system pressure. The main products are NaOH (g) , NaOH (l) and H2 (g) . Sodium evaporation should be considered in the cases of sodium-rich and high pressure above 10 bar

Fissures in rock under water pressure, implications on stability : 3 unusual cases

Energy Technology Data Exchange (ETDEWEB)

Helwig, P.C. [Helwig Hydrotechnique Ltd., St. John' s, NL (Canada)

2006-07-01

The presence of water in rock joints has important implications on the stability of rock foundations. Appropriate analyses are needed to assess the stability of dam foundations, abutments and rock walls. This paper presented 3 case studies in which the freezing of seepage flows in rock joints and transient pressure in rock walls were investigated: (1) an assessment of the effects of freezing water in rock joints at the Paradise River arch dam in Newfoundland; (2) stability of rock walls in the unlined power tunnel of the Cat Arm hydroelectric development in Newfoundland due to transient pressures; and (3) assessing the influence of fluctuating water pressures in a stilling basin excavated in rock. After an investigation of the Paradise River canyon walls, a drainage system comprised of peripheral drain holes was drilled into the foundation and walls at regular intervals to intercept seepage flows and to relieve uplift water pressures. However, no special treatment was found for the potential freezing of water in the joints of the dam walls and foundation. The Cat Arm tunnel was used to study the depth at which significant transient pressures can be used to assess rock stability. Rock properties, typical fracture apertures and spacing were assumed and joint deformability was taken into account. An axisymmetric solution was obtained by considering the continuity and flow through an annular element of the rock wall. A finite difference method was used to solve the resulting nonlinear differential equation. In the final case study, blast-damaged rock was undermining the toe of a spillway. A cut-off wall was constructed as a series of drilled, cast-in-place concrete caisson piles. Criteria for the design included extending the cut-off wall to a depth beyond the effects of fluctuating surface pressures. Depth was assessed by considering the transient behaviour of water penetrating a sub-vertical joint subject exposed to fluctuating pressures. Results of the calculations

Climate-induced changes in river water temperature in North Iberian Peninsula

Science.gov (United States)

Soto, Benedicto

2017-06-01

This study evaluates the effects of climate change on the thermal regime of 12 rivers in the Northern Iberian Peninsula by using a non-linear regression model that employs air temperature as the only input variable. Prediction of future air temperature was obtained from five regional climate models (RCMs) under emission scenario Special Report on Emissions Scenarios A1B. Prior to simulation of water temperature, air temperature was bias-corrected (B-C) by means of variance scaling (VS) method. This procedure allows an improvement of fit between observed and estimated air temperature for all climate models. The simulation of water temperature for the period 1990-2100 shows an increasing trend, which is higher for the period of June-August (summer) and September-November (autumn) (0.0275 and 0.0281 °C/year) than that of winter (December-February) and spring (March-May) (0.0181 and 0.0218 °C/year). In the high air temperature range, daily water temperature is projected to increase on average by 2.2-3.1 °C for 2061-2090 relative to 1961-1990. During the coldest days, the increment of water temperature would range between 1.0 and 1.7 °C. In fact, employing the numbers of days that water temperature exceeded the upper incipient lethal temperature (UILT) for brown trout (24.7 °C) has been noted that this threshold is exceeded 14.5 days per year in 2061-2090 while in 1961-1990, this values was exceeded 2.6 days per year of mean and 3.6 days per year in observation period (2000-2014).

Bio-lubricants derived from waste cooking oil with improved oxidation stability and low-temperature properties.

Science.gov (United States)

Li, Weimin; Wang, Xiaobo

2015-01-01

Waste cooking oil (WCO) was chemically modified via epoxidation using H2O2 followed by transesterification with methanol and branched alcohols (isooctanol, isotridecanol and isooctadecanol) to produce bio-lubricants with improved oxidative stability and low temperature properties. Physicochemical properties of synthesized bio-lubricants such as pour point (PP), cloud point (CP), viscosity, viscosity index (VI), oxidative stability, and corrosion resistant property were determined according to standard methods. The synthesized bio-lubricants showed improved low temperature flow performances compared with WCO, which can be attributing to the introduction of branched chains in their molecular structures. What's more, the oxidation stability of the WCO showed more than 10 folds improvement due to the elimination of -C=C-bonds in the WCO molecule. Tribological performances of these bio-lubricants were also investigated using four-ball friction and wear tester. Experimental results showed that derivatives of WCO exhibited favorable physicochemical properties and tribological performances which making them good candidates in formulating eco-friendly lubricants.

Effect of aluminum doping on the high-temperature stability and piezoresistive response of indium tin oxide strain sensors

International Nuclear Information System (INIS)

Gregory, Otto J.; You, Tao; Crisman, Everett E.

2005-01-01

Ceramic strain sensors based on reactively sputtered indium tin oxide (ITO) thin films doped with aluminum are being considered to improve the high-temperature stability and response. Ceramic strain sensors were developed to monitor the structural integrity of components employed in aerospace propulsion systems operating at temperatures in excess of 1500 deg C. Earlier studies using electron spectroscopy for chemical analysis (ESCA) studies indicated that interfacial reactions between ITO and aluminum oxide increase the stability of ITO at elevated temperature. The resulting ESCA depth files showed the presence of two new indium-indium peaks at 448.85 and 456.40 eV, corresponding to the indium 3d5 and 3d3 binding energies. These binding energies are significantly higher than those associated with stoichiometric indium oxide. Based on these studies, a combinatorial chemistry approach was used to screen large numbers of possible concentrations to optimize the stability and performance of Al-doped ceramic strain sensors. Scanning electron microscopy was used to analyze the combinatorial libraries in which varying amounts of aluminum were incorporated into ITO films formed by cosputtering from multiple targets. Electrical stability and piezoresistive response of these films were compared to undoped ITO films over the same temperature range

Ground-water temperature of the Wyoming quadrangle in central Delaware : with application to ground-water-source heat pumps

Science.gov (United States)

Hodges, Arthur L.

1982-01-01

Ground-water temperature was measured during a one-year period (1980-81) in 20 wells in the Wyoming Quadrangle in central Delaware. Data from thermistors set at fixed depths in two wells were collected twice each week, and vertical temperature profiles of the remaining 18 wells were made monthly. Ground-water temperature at 8 feet below land surface in well Jc55-1 ranged from 45.0 degrees F in February to 70.1 degrees F in September. Temperature at 35 feet below land surface in the same well reached a minimum of 56.0 degrees F in August, and a maximum of 57.8 degrees F in February. Average annual temperature of ground water at 25 feet below land surface in all wells ranged from 54.6 degrees F to 57.8 degrees F. Variations of average temperature probably reflect the presence or absence of forestation in the recharge areas of the wells. Ground-water-source heat pumps supplied with water from wells 30 or more feet below land surface will operate more efficiently in both heating and cooling modes than those supplied with water from shallower depths. (USGS)

Improvement of temperature-stability in a quantum well laser with asymmetric barrier layers

DEFF Research Database (Denmark)

Zhukov, Alexey E.; Kryzhanovskaya, Natalia V.; Zubov, Fedor I.

2012-01-01

We fabricated and tested a quantum well laser with asymmetric barrier layers. Such a laser has been proposed earlier to suppress bipolar carrier population in the optical confinement layer and thus to improve temperature-stability of the threshold current. As compared to the conventional reference...

Modeling Air Temperature/Water Temperature Relations Along a Small Mountain Stream Under Increasing Urban Influence

Science.gov (United States)

Fedders, E. R.; Anderson, W. P., Jr.; Hengst, A. M.; Gu, C.

2017-12-01

Boone Creek is a headwater stream of low to moderate gradient located in Boone, North Carolina, USA. Total impervious surface coverage in the 5.2 km2 catchment drained by the 1.9 km study reach increases from 13.4% in the upstream half of the reach to 24.3% in the downstream half. Other markers of urbanization, including culverting, lack of riparian shade vegetation, and bank armoring also increase downstream. Previous studies have shown the stream to be prone to temperature surges on short timescales (minutes to hours) caused by summer runoff from the urban hardscaping. This study investigates the effects of urbanization on the stream's thermal regime at daily to yearly timescales. To do this, we developed an analytical model of daily average stream temperatures based on daily average air temperatures. We utilized a two-part model comprising annual and biannual components and a daily component consisting of a 3rd-order Markov process in order to fit the thermal dynamics of our small, gaining stream. Optimizing this model at each of our study sites in each studied year (78 total site-years of data) yielded annual thermal exchange coefficients (K) for each site. These K values quantify the strength of the relationship between stream and air temperature, or inverse thermal stability. In a uniform, pristine catchment environment, K values are expected to decrease downstream as the stream gains discharge volume and, therefore, thermal inertia. Interannual average K values for our study reach, however, show an overall increase from 0.112 furthest upstream to 0.149 furthest downstream, despite a near doubling of stream discharge between these monitoring points. K values increase only slightly in the upstream, less urban, half of the reach. A line of best fit through these points on a plot of reach distance versus K value has a slope of 2E-6. But the K values of downstream, more urbanized sites increase at a rate of 2E-5 per meter of reach distance, an order of magnitude

Effect of water temperature on biofouling development in reverse osmosis membrane systems

KAUST Repository

Farhat, Nadia

2016-07-14

Understanding the factors that determine the spatial and temporal biofilm development is a key to formulate effective control strategies in reverse osmosis membrane systems for desalination and wastewater reuse. In this study, biofilm development was investigated at different water temperatures (10, 20, and 30 °C) inside a membrane fouling simulator (MFS) flow cell. The MFS studies were done at the same crossflow velocity with the same type of membrane and spacer materials, and the same feed water type and nutrient concentration, differing only in water temperature. Spatially resolved biofilm parameters such as oxygen decrease rate, biovolume, biofilm spatial distribution, thickness and composition were measured using in-situ imaging techniques. Pressure drop (PD) increase in time was used as a benchmark as to when to stop the experiments. Biofilm measurements were performed daily, and experiments were stopped once the average PD increased to 40 mbar/cm. The results of the biofouling study showed that with increasing feed water temperature (i) the biofilm activity developed faster, (ii) the pressure drop increased faster, while (iii) the biofilm thickness decreased. At an average pressure drop increase of 40 mbar/cm over the MFS for the different feed water temperatures, different biofilm activities, structures, and quantities were found, indicating that diagnosis of biofouling of membranes operated at different or varying (seasonal) feed water temperatures may be challenging. Membrane installations with a high temperature feed water are more susceptible to biofouling than installations fed with low temperature feed water.

Incorporation of the equilibrium temperature approach in a Soil and Water Assessment Tool hydroclimatological stream temperature model

Science.gov (United States)

Du, Xinzhong; Shrestha, Narayan Kumar; Ficklin, Darren L.; Wang, Junye

2018-04-01

Stream temperature is an important indicator for biodiversity and sustainability in aquatic ecosystems. The stream temperature model currently in the Soil and Water Assessment Tool (SWAT) only considers the impact of air temperature on stream temperature, while the hydroclimatological stream temperature model developed within the SWAT model considers hydrology and the impact of air temperature in simulating the water-air heat transfer process. In this study, we modified the hydroclimatological model by including the equilibrium temperature approach to model heat transfer processes at the water-air interface, which reflects the influences of air temperature, solar radiation, wind speed and streamflow conditions on the heat transfer process. The thermal capacity of the streamflow is modeled by the variation of the stream water depth. An advantage of this equilibrium temperature model is the simple parameterization, with only two parameters added to model the heat transfer processes. The equilibrium temperature model proposed in this study is applied and tested in the Athabasca River basin (ARB) in Alberta, Canada. The model is calibrated and validated at five stations throughout different parts of the ARB, where close to monthly samplings of stream temperatures are available. The results indicate that the equilibrium temperature model proposed in this study provided better and more consistent performances for the different regions of the ARB with the values of the Nash-Sutcliffe Efficiency coefficient (NSE) greater than those of the original SWAT model and the hydroclimatological model. To test the model performance for different hydrological and environmental conditions, the equilibrium temperature model was also applied to the North Fork Tolt River Watershed in Washington, United States. The results indicate a reasonable simulation of stream temperature using the model proposed in this study, with minimum relative error values compared to the other two models

Biodegradation of Toluene Under Seasonal and Diurnal Fluctuations of Soil-Water Temperature.

KAUST Repository

Yadav, Brijesh K; Shrestha, Shristi R; Hassanizadeh, S Majid

2012-01-01

An increasing interest in bioremediation of hydrocarbon polluted sites raises the question of the influence of seasonal and diurnal changes on soil-water temperature on biodegradation of BTEX, a widespread group of (sub)-surface contaminants. Therefore, we investigated the impact of a wide range of varying soil-water temperature on biodegradation of toluene under aerobic conditions. To see the seasonal impact of temperature, three sets of batch experiments were conducted at three different constant temperatures: 10°C, 21°C, and 30°C. These conditions were considered to represent (1) winter, (2) spring and/or autumn, and (3) summer seasons, respectively, at many polluted sites. Three additional sets of batch experiments were performed under fluctuating soil-water temperature cases (21<>10°C, 30<>21°C, and 10<>30°C) to mimic the day-night temperature patterns expected during the year. The batches were put at two different temperatures alternatively to represent the day (high-temperature) and night (low-temperature) times. The results of constant- and fluctuating-temperature experiments show that toluene degradation is strongly dependent on soil-water temperature level. An almost two-fold increase in toluene degradation time was observed for every 10°C decrease in temperature for constant-temperature cases. Under fluctuating-temperature conditions, toluene degraders were able to overcome the temperature stress and continued thriving during all considered weather scenarios. However, a slightly longer time was taken compared to the corresponding time at daily mean temperature conditions. The findings of this study are directly useful for bioremediation of hydrocarbon-polluted sites having significant diurnal and seasonal variations of soil-water temperature.

Biodegradation of Toluene Under Seasonal and Diurnal Fluctuations of Soil-Water Temperature.

Science.gov (United States)

Yadav, Brijesh K; Shrestha, Shristi R; Hassanizadeh, S Majid

2012-09-01

An increasing interest in bioremediation of hydrocarbon polluted sites raises the question of the influence of seasonal and diurnal changes on soil-water temperature on biodegradation of BTEX, a widespread group of (sub)-surface contaminants. Therefore, we investigated the impact of a wide range of varying soil-water temperature on biodegradation of toluene under aerobic conditions. To see the seasonal impact of temperature, three sets of batch experiments were conducted at three different constant temperatures: 10°C, 21°C, and 30°C. These conditions were considered to represent (1) winter, (2) spring and/or autumn, and (3) summer seasons, respectively, at many polluted sites. Three additional sets of batch experiments were performed under fluctuating soil-water temperature cases (2110°C, 3021°C, and 1030°C) to mimic the day-night temperature patterns expected during the year. The batches were put at two different temperatures alternatively to represent the day (high-temperature) and night (low-temperature) times. The results of constant- and fluctuating-temperature experiments show that toluene degradation is strongly dependent on soil-water temperature level. An almost two-fold increase in toluene degradation time was observed for every 10°C decrease in temperature for constant-temperature cases. Under fluctuating-temperature conditions, toluene degraders were able to overcome the temperature stress and continued thriving during all considered weather scenarios. However, a slightly longer time was taken compared to the corresponding time at daily mean temperature conditions. The findings of this study are directly useful for bioremediation of hydrocarbon-polluted sites having significant diurnal and seasonal variations of soil-water temperature.

Biodegradation of Toluene Under Seasonal and Diurnal Fluctuations of Soil-Water Temperature.

KAUST Repository

Yadav, Brijesh K

2012-05-12

An increasing interest in bioremediation of hydrocarbon polluted sites raises the question of the influence of seasonal and diurnal changes on soil-water temperature on biodegradation of BTEX, a widespread group of (sub)-surface contaminants. Therefore, we investigated the impact of a wide range of varying soil-water temperature on biodegradation of toluene under aerobic conditions. To see the seasonal impact of temperature, three sets of batch experiments were conducted at three different constant temperatures: 10°C, 21°C, and 30°C. These conditions were considered to represent (1) winter, (2) spring and/or autumn, and (3) summer seasons, respectively, at many polluted sites. Three additional sets of batch experiments were performed under fluctuating soil-water temperature cases (21<>10°C, 30<>21°C, and 10<>30°C) to mimic the day-night temperature patterns expected during the year. The batches were put at two different temperatures alternatively to represent the day (high-temperature) and night (low-temperature) times. The results of constant- and fluctuating-temperature experiments show that toluene degradation is strongly dependent on soil-water temperature level. An almost two-fold increase in toluene degradation time was observed for every 10°C decrease in temperature for constant-temperature cases. Under fluctuating-temperature conditions, toluene degraders were able to overcome the temperature stress and continued thriving during all considered weather scenarios. However, a slightly longer time was taken compared to the corresponding time at daily mean temperature conditions. The findings of this study are directly useful for bioremediation of hydrocarbon-polluted sites having significant diurnal and seasonal variations of soil-water temperature.

Water temperature forecasting and estimation using fourier series and communication theory techniques

International Nuclear Information System (INIS)

Long, L.L.

1976-01-01

Fourier series and statistical communication theory techniques are utilized in the estimation of river water temperature increases caused by external thermal inputs. An example estimate assuming a constant thermal input is demonstrated. A regression fit of the Fourier series approximation of temperature is then used to forecast daily average water temperatures. Also, a 60-day prediction of daily average water temperature is made with the aid of the Fourier regression fit by using significant Fourier components

Tradeoffs between water requirements and yield stability in annual vs. perennial crops

Science.gov (United States)

Vico, Giulia; Brunsell, Nathaniel A.

2018-02-01

Population growth and changes in climate and diets will likely further increase the pressure on agriculture and water resources globally. Currently, staple crops are obtained from annuals plants. A shift towards perennial crops may enhance many ecosystem services, but at the cost of higher water requirements and lower yields. It is still unclear when the advantages of perennial crops overcome their disadvantages and perennial crops are thus a sustainable solution. Here we combine a probabilistic description of the soil water balance and crop development with an extensive dataset of traits of congeneric annuals and perennials to identify the conditions for which perennial crops are more viable than annual ones with reference to yield, yield stability, and effective use of water. We show that the larger and more developed roots of perennial crops allow a better exploitation of soil water resources and a reduction of yield variability with respect to annual species, but their yields remain lower when considering grain crops. Furthermore, perennial crops have higher and more variable irrigation requirements and lower water productivity. These results are important to understand the potential consequences for yield, its stability, and water resource use of a shift from annual to perennial crops and, more generally, if perennial crops may be more resilient than annual crops in the face of climatic fluctuations.

Elevated-temperature mechanical stability and transformation behavior of retained austenite in a quenching and partitioning steel

Energy Technology Data Exchange (ETDEWEB)

Min, Junying, E-mail: junying.min@gmail.com [Chair of Production Systems, Ruhr-University Bochum, Bochum 44780 (Germany); Hector, Louis G. [General Motors Research & Development, Warren, MI 48095-9055 (United States); Zhang, Ling; Lin, Jianping [School of Mechanical Engineering, Tongji University, Shanghai 201804 (China); Carsley, John E. [General Motors Research & Development, Warren, MI 48095-9055 (United States); Sun, Li [General Motors China Science Lab, Shanghai 201206 (China)

2016-09-15

The mechanical stability and transformation behavior of both film and blocky retained austenite (RA) in a quenching and partitioning steel are investigated at 293 K, 423 K and 573 K with X-ray diffraction measurements and transmission electron microscopy. Blocky RA both completely and incompletely transforms to twinned martensite during deformation at 293 K and 423 K, respectively, and completely transforms to lath martensite during deformation at 573 K. At 293 K and 423 K, only the film RA with widths larger than ~70 nm transforms to twinned martensite. However, film RA incompletely transforms to lath martensite at 573 K. Hence, RA transformation is non-monotonic with temperature. Significant carbide formation at 573 K, and therefore less carbon to stabilize RA, overcomes the increase in austenite stability due to the decrease in the temperature-dependent chemical driving force for the martensite transformation.

High speed machining of aluminium gear box without temperature stabilization

Directory of Open Access Journals (Sweden)

Abilio P. SILVA

2010-01-01

Full Text Available At the present time both clutch and mechanism housings, which are the main components from automotive gear boxes, are made of special aluminium alloys. These alloys are extremely light when compared with steel, making them a perfect choice to mitigate the cars weight and machining costs. Nonetheless they possess a high thermal expansion coefficient, which can be considered a major disadvantage since it makes necessary to pay extraordinary attention to dimensional variations during the production cycle due to temperature deviations. High speed machining of precision components made of aluminium requests thus their temperature to become previously stable. This procedure is the only way to force dimensions to stay inside its tolerance intervals. The main purpose of the present work was to assess the possibility to avoid the use of special ovens to make the clutch housing temperature become stable prior to machining. The dimensional stabilization of 40 sample parts, pre-heated at three temperature levels, was accomplished through the use of this system. The achieved results were made possible by analysing the part’s temperature at the machine’s entrance, the machine’s interior temperature, 35 measured dimensions and their tolerance intervals as well as the average temperature deviations of each of the five considered batches. By analysing the obtained results in detail it was possible to determine which dimensions show high sensitiveness to temperature (high correlation between dimension’s variation and temperature. Among these dimensions we can point out the ones related with depth, since they display the highest deviations due to temperature. Being a work with practical application it was possible to confirm the benefit of using this methodology by achieving significant enhancements on production efficiency, energy savings and reduction on maintenance costs, through the application of small adjustments to the machining sequence and by

Potential uses of high gradient magnetic filtration for high-temperature water purification in boiling water reactors

International Nuclear Information System (INIS)

Elliott, H.H.; Holloway, J.H.; Abbott, D.G.

1979-01-01

Studies of various high-temperature filter devices indicate a potentially positive impact for high gradient magnetic filtration on boiling water reactor radiation level reduction. Test results on in-plant water composition and impurity crystallography are presented for several typical boiling water reactors (BWRs) on plant streams where high-temperature filtration may be particularly beneficial. An experimental model on the removal of red iron oxide (hematite) from simulated reactor water with a high gradient magnetic filter is presented, as well as the scale-up parameters used to predict the filtration efficiency on various high temperature, in-plant streams. Numerical examples are given to illustrate the crud removal potential of high gradient magnetic filters installed at alternative stream locations under typical, steady-state, plant operating conditions

Sea water desalination utilizing waste heat by low temperature evaporation

International Nuclear Information System (INIS)

Raha, A.; Srivastava, A.; Rao, I.S.; Majumdar, M.; Srivastava, V.K.; Tewari, P.K.

2007-01-01

Economics of a process is controlled by management of energy and resources. Fresh water has become most valued resource in industries. Desalination is a process by which fresh water resource is generated from sea water or brackish water, but it is an energy intensive process. The energy cost contributes around 25-40% to the total cost of the desalted water. Utilization of waste heat from industrial streams is one of the ecofriendly ways to produce low cost desalted water. Keeping this in mind Low Temperature Evaporation (LTE) desalination technology utilizing low quality waste heat in the form of hot water (as low as 50 deg C) or low pressure steam (0.13 bar) has been developed for offshore and land based applications to produce high purity water (conductivity < 2μS/cm) from sea water. The probability of the scale formation is practically eliminated by operating it at low temperature and controlling the brine concentration. It also does not require elaborate chemical pretreatment of sea water except chlorination, so it has no environmental impact. LTE technology has found major applications in nuclear reactors where large quantity of low quality waste heat is available to produce high quality desalted water for make up water requirement replacing conventional ion exchange process. Successful continuous operation of 30 Te/day LTE desalination plant utilizing waste heat from nuclear research reactor has demonstrated the safety, reliability, extreme plant availability and economics of nuclear desalination by LTE technology. It is also proposed to utilize waste heat from Main Heat Transport (MHT) purification circuit of Advanced Heavy Water Reactor (AHWR) to produce about 250 Te/ day high quality desalinated water by Low Temperature Evaporation (LTE) process for the reactor make up and plant utilization. Recently we have commissioned a 50 Te/day 2-effect low temperature desalination plant with cooling tower where the specific energy and cooling water requirement are

Stability with temperature of mixed uranium plutonium monocarbides

International Nuclear Information System (INIS)

Riglet-Martial, Ch.; Dumas, J.C.; Piron, J.P.; Gueneau, Ch.

2008-01-01

Full text: Among the different advanced fuel materials of concern for Generation IV systems, the mixed carbide of uranium and plutonium fuel is considered as one of the key materials for Gas Fast Reactors (GFR) systems. For purposes of optimising its fabrication process as well as its performances in various operating conditions, the losses of gaseous plutonium specially at elevated temperatures have to be controlled and minimized. The paper is therefore concerned with a parametric analysis of the stability with temperature of mixed carbides of uranium and plutonium. Previous published experimental studies have shown that mixed (U ,Pu) carbides undergo a highly incongruent sublimation at high temperatures: the vapour phase in equilibrium with the solid is mainly composed of gaseous plutonium (P Pu /P total > 99 % ) while the contribution of gaseous U and C remains very low. The composition of the system U 1-z Pu z C 1+x ' (z =Pu/(U+Pu) and x C/(U+Pu)), the temperature (T) and the expansion volume (V) of the gas are the main parameters in the loss of gaseous Pu. The calculations are carried out using the SAGE (Solgasmix Advanced Gibbs Energy) software, by assuming ideal solid solutions between UC and PuC, as well as between U 2 C 3 and Pu 2 C 3 . The validity of the model is previously tested using published equilibrium vapour pressure data. This work gives rise to a large description of the variations of Pu losses from mixed uranium plutonium carbides and leads to some basic recommendations in connection with the use of this advanced fuel materials

Novel room-temperature-setting phosphate ceramics for stabilizing combustion products and low-level mixed wastes

International Nuclear Information System (INIS)

Wagh, A.S.; Singh, D.

1994-01-01

Argonne National Laboratory, with support from the Office of Technology in the US Department of Energy (DOE), has developed a new process employing novel, chemically bonded ceramic materials to stabilize secondary waste streams. Such waste streams result from the thermal processes used to stabilize low-level, mixed wastes. The process will help the electric power industry treat its combustion and low-level mixed wastes. The ceramic materials are strong, dense, leach-resistant, and inexpensive to fabricate. The room-temperature-setting process allows stabilization of volatile components containing lead, mercury, cadmium, chromium, and nickel. The process also provides effective stabilization of fossil fuel combustion products. It is most suitable for treating fly and bottom ashes

Study on elastic-plastic fracture toughness test in high temperature water

International Nuclear Information System (INIS)

Miura, Yasufumi

2016-01-01

Structural integrity of internal components in light water reactors is important for the safety of operation and service lifetime. Fracture toughness is important parameter for structural integrity assessment of nuclear power plant. In general, fracture toughness of materials which compose the components in light water reactor is obtained with fracture toughness tests in air although some components are subjected to high temperature water because of the difficulty of fracture toughness test in high temperature water. However, the effects of high temperature water and hydrogen on fracture behavior of the structural materials in nuclear power plant such as low alloy steel, cast austenitic stainless steel, and Ni base alloy are concerned recently. In this study, elastic-plastic fracture toughness test of low alloy steel in simulated BWR water environment was studied. Fracture toughness test in high temperature water with original clip gage and normalization data reduction technique was established. The difference of fracture toughness J_Q tested in air between using elastic unload compliance method and normalization data reduction technique was also discussed. As a result, obtained value with normalization data reduction technique tended to be higher than the value with elastic unload compliance. (author)

A real-time BWR [boiling water reactor] stability measurement system

International Nuclear Information System (INIS)

March-Leuba, J.; King, W.T.

1987-01-01

This paper describes the characteristics of a portable, real-time system used for nonperturbational measurements of stability in boiling water reactors. The algorithm used in this system estimates the closed-loop asymptotic decay ratio using only the naturally occurring neutron noise and it is based on the univariate autoregressive methodology

Inland Water Temperature: An Ideal Indicator for the National Climate Assessment

Science.gov (United States)

Hook, S. J.; Lenters, J. D.; O'Reilly, C.; Healey, N. C.

2014-12-01

NASA is a significant contributor to the U.S. National Climate Assessment (NCA), which is a central component of the 2012-2022 U.S. Global Change Research Program Strategic Plan. The NCA has identified the need for indicators that provide a clear, concise way of communicating to NCA audiences about not only the status and trends of physical drivers of the climate system, but also the ecological and socioeconomic impacts, vulnerabilities, and responses to those drivers. We are using thermal infrared satellite data in conjunction with in situ measurements to produce water temperatures for all the large inland water bodies in North America for potential use as an indicator for the NCA. Recent studies have revealed significant warming of inland waters throughout the world. The observed rate of warming is - in many cases - greater than that of the ambient air temperature. These rapid, unprecedented changes in inland water temperatures have profound implications for lake hydrodynamics, productivity, and biotic communities. Scientists are just beginning to understand the global extent, regional patterns, physical mechanisms, and ecological consequences of lake warming. As part of our earlier studies we have collected thermal infrared satellite data from those satellite sensors that provide long-term and frequent spaceborne thermal infrared measurements of inland waters including ATSR, AVHRR, and MODIS and used these to examine trends in water surface temperature for approximately 100 of the largest inland water bodies in the world. We are now extending this work to generate temperature time-series of all North American inland water bodies that are sufficiently large to be studied using 1km resolution satellite data for the last 3 decades. These data are then being related to changes in the surface air temperature and compared with regional trends in water surface temperature derived from CMIP5/IPCC model simulations/projections to better predict future temperature changes

Effect of Storage Time and Temperature on Dimensional Stability of Impressions Made with Zinc Oxide Impression Paste

Directory of Open Access Journals (Sweden)

Sareh Habibzadeh

2016-10-01

Full Text Available Objectives: This study aimed to assess the effect of storage time and temperature on dimensional stability of impressions made with Cavex Outline zinc oxide impression paste.Materials and Methods: A round stainless steel mold with five grooves (three horizontal and two vertical was used in this in-vitro experimental study. Cavex Outline impression paste was prepared according to the manufacturer’s instructions and applied to the mold. The mold was placed on a block and stored at 35°C and 100% humidity for setting. The impressions were poured with stone immediately and also after 30, 120, 240 and 420 minutes and 24 hours. The distance between the vertical lines on the casts was measured and compared with that in the immediately poured cast.Results: Storage in a refrigerator and at room temperature for zero to seven hours had no significant effect on dimensional stability of the impressions; however, 24 hours of storage in a refrigerator or at room temperature decreased the dimensional stability of Cavex Outline (P=0.001. Also, a significant association was found between dimensional changes following 24 hours of storage in a refrigerator (4°C and at room temperature (23°C; P<0.01.Conclusions: The optimal pouring time of Cavex Outline impressions with stone is between zero to seven hours, and 24 hours of storage significantly decreases the dimensional stability.Keywords: Dental Impression Materials; Zinc Oxide; Cavex

SU-F-T-492: The Impact of Water Temperature On Absolute Dose Calibration

Energy Technology Data Exchange (ETDEWEB)

Islam, N [State University of New York at Buffalo, Buffalo, NY (United States); Podgorsak, M [State University of New York at Buffalo, Buffalo, NY (United States); Roswell Park Cancer Institute, Buffalo, NY (United States)

2016-06-15

Purpose: The Task Group 51 (TG 51) protocol prescribes that dose calibration of photon beams be done by irradiating an ionization chamber in a water tank at pre-defined depths. Methodologies are provided to account for variations in measurement conditions by applying correction factors. However, the protocol does not completely account for the impact of water temperature. It is well established that water temperature will influence the density of air in the ion chamber collecting volume. Water temperature, however, will also influence the size of the collecting volume via thermal expansion of the cavity wall and the density of the water in the tank. In this work the overall effect of water temperature on absolute dosimetry has been investigated. Methods: Dose measurements were made using a Farmer-type ion chamber for 6 and 23 MV photon beams with water temperatures ranging from 10 to 40°C. A reference ion chamber was used to account for fluctuations in beam output between successive measurements. Results: For the same beam output, the dose determined using TG 51 was dependent on the temperature of the water in the tank. A linear regression of the data suggests that the dependence is statistically significant with p-values of the slope equal to 0.003 and 0.01 for 6 and 23 MV beams, respectively. For a 10 degree increase in water phantom temperature, the absolute dose determined with TG 51 increased by 0.27% and 0.31% for 6 and 23 MV beams, respectively. Conclusion: There is a measurable effect of water temperature on absolute dose calibration. To account for this effect, a reference temperature can be defined and a correction factor applied to account for deviations from this reference temperature during beam calibration. Such a factor is expected to be of similar magnitude to most of the existing TG 51 correction factors.

SU-F-T-492: The Impact of Water Temperature On Absolute Dose Calibration

International Nuclear Information System (INIS)

Islam, N; Podgorsak, M

2016-01-01

Purpose: The Task Group 51 (TG 51) protocol prescribes that dose calibration of photon beams be done by irradiating an ionization chamber in a water tank at pre-defined depths. Methodologies are provided to account for variations in measurement conditions by applying correction factors. However, the protocol does not completely account for the impact of water temperature. It is well established that water temperature will influence the density of air in the ion chamber collecting volume. Water temperature, however, will also influence the size of the collecting volume via thermal expansion of the cavity wall and the density of the water in the tank. In this work the overall effect of water temperature on absolute dosimetry has been investigated. Methods: Dose measurements were made using a Farmer-type ion chamber for 6 and 23 MV photon beams with water temperatures ranging from 10 to 40°C. A reference ion chamber was used to account for fluctuations in beam output between successive measurements. Results: For the same beam output, the dose determined using TG 51 was dependent on the temperature of the water in the tank. A linear regression of the data suggests that the dependence is statistically significant with p-values of the slope equal to 0.003 and 0.01 for 6 and 23 MV beams, respectively. For a 10 degree increase in water phantom temperature, the absolute dose determined with TG 51 increased by 0.27% and 0.31% for 6 and 23 MV beams, respectively. Conclusion: There is a measurable effect of water temperature on absolute dose calibration. To account for this effect, a reference temperature can be defined and a correction factor applied to account for deviations from this reference temperature during beam calibration. Such a factor is expected to be of similar magnitude to most of the existing TG 51 correction factors.

Suspensions Plasma Spraying of Ceramics with Hybrid Water-Stabilized Plasma Technology

Czech Academy of Sciences Publication Activity Database

Mušálek, Radek; Medřický, Jan; Tesař, T.; Kotlan, Jiří; Pala, Zdeněk; Lukáč, František; Chráska, Tomáš; Curry, N.

2017-01-01

Roč. 26, 1-2 (2017), s. 37-46 ISSN 1059-9630. [ISTC 2016: International Thermal Spray Conference. Shanghai, 10.05.2016-12.05.2016] R&D Projects: GA ČR GA15-12145S Institutional support: RVO:61389021 Keywords : alumina * ceramics * dense * hybrid plasma torch * suspension plasma spraying * water-stabilized plasma * yttria-stabilized zirconia (YSZ) Subject RIV: JK - Corrosion ; Surface Treatment of Materials OBOR OECD: Coating and films Impact factor: 1.488, year: 2016 http://link.springer.com/article/10.1007/s11666-016-0493-6

Study on Modified Water Glass Used in High Temperature Protective Glass Coating for Ti-6Al-4V Titanium Alloy

Directory of Open Access Journals (Sweden)

Shuang Yang

2018-04-01

Full Text Available Sodium silicate water glass was modified with sodium polyacrylate as the binder, the composite slurry used for high-temperature oxidation-resistant coating was prepared by mixing glass powder with good lubrication properties in the binder. The properties of the modified binder and high-temperature oxidation resistance of Ti-6Al-4V titanium alloy coated with composite glass coating were studied by XRD, SEM, EDS, TG-DSC and so on. Results showed that sodium polyacrylate modified water glass could obviously improve the suspension stability of the binder, the pyrolytic carbon in the binder at high temperature could increase the surface tension in the molten glass system, and the composite glass coating could be smooth and dense after heating. Pyrolytic carbon diffused and combined with oxygen in the coating under the heating process to protect the titanium alloy from oxidation. The thickness of the oxide layer was reduced 51% after applying the high-temperature oxidation-resistant coating. The coating also showed a nearly 30% reduction in friction coefficient due to the boundary lubricant regime. During cooling, the coating could be peeled off easily because of the mismatched CTE between the coating and substrate.

Assessing the Effects of Water Right Purchases on Stream Temperatures and Fish Habitat

Science.gov (United States)

Elmore, L.; Null, S. E.

2012-12-01

Warm stream temperature and low flow conditions are limiting factors for native trout species in Nevada's Walker River. Water rights purchases are being considered to increase instream flow and improve habitat conditions. However, the effect of water rights purchases on stream temperatures and fish habitat have yet to be assessed. Manipulating flow conditions affect stream temperatures by altering water depth, velocity, and thermal mass. This study uses the River Modeling System (RMSv4), an hourly, physically-based hydrodynamic and water quality model, to estimate flows and stream temperatures in the Walker River. The model is developed for two wet years (2010-2011). Study results highlight reaches with cold-water habitat that is suitable for native trout species. Previous research on the Walker River has evaluated instream flow changes with water rights purchases. This study incorporates stream temperatures as a proxy for trout habitat, and thus explicitly incorporates water quality and fish habitat into decision-making regarding water rights purchases. Walker River

Stability analysis of a heated channel cooled by supercritical water

International Nuclear Information System (INIS)

Magni, M. C.; Delmastro, D. F; Marcel, C. P

2009-01-01

A simple model to study thermal-hydraulic stability of a heated cannel under supercritical conditions is presented. Single cannel stability analysis for the SCWR (Supercritical Water Cooled Reactor) design was performed. The drastic change of fluid density in the reactor core of a SCWR may induce DWO (Density Wave Oscillations) similar to those observed in BWRs. Due to the similarities between subcritical and supercritical systems we may treat the supercritical fluid as a pseudo two-phase system. Thus, we may extend the modeling approach often used for boiling flow stability analysis to supercritical pressure operation conditions. The model developed in this work take into account three regions: a heavy fluid region, similar to an incompressible liquid; a zone where a heavy fluid and a light fluid coexist, similar to two-phase mixture; and a light fluid region which behaves like superheated steam. It was used the homogeneous equilibrium model (HEM) for the pseudo boiling zone, and the ideal gas model for the pseudo superheated steam zone. System stability maps were obtained using linear stability analysis in the frequency domain. Two possible instability mechanisms are observed: DWO and excursive Ledinegg instabilities. Also, a sensitivity analysis showed that frictions in pseudo superheated steam zone, together with acceleration effect, are the most destabilizing effects. On the other hand, frictions in pseudo liquid zone are the most important stabilizing effect. [es

An experimental study on the influence of water stagnation and temperature change on water quality in a full-scale domestic drinking water system.

Science.gov (United States)

Zlatanović, Lj; van der Hoek, J P; Vreeburg, J H G

2017-10-15

The drinking water quality changes during the transport through distribution systems. Domestic drinking water systems (DDWSs), which include the plumbing between the water meter and consumer's taps, are the most critical points in which water quality may be affected. In distribution networks, the drinking water temperature and water residence time are regarded as indicators of the drinking water quality. This paper describes an experimental research on the influence of stagnation time and temperature change on drinking water quality in a full-scale DDWS. Two sets of stagnation experiments, during winter and summer months, with various stagnation intervals (up to 168 h of stagnation) were carried out. Water and biofilms were sampled at two different taps, a kitchen and a shower tap. Results from this study indicate that temperature and water stagnation affect both chemical and microbial quality in DDWSs, whereas microbial parameters in stagnant water appear to be driven by the temperature of fresh water. Biofilm formed in the shower pipe contained more total and intact cells than the kitchen pipe biofilm. Alphaproteobacteria were found to dominate in the shower biofilm (78% of all Proteobacteria), while in the kitchen tap biofilm Alphaproteobacteria, Betaproteobacteria and Gammaproteobacteria were evenly distributed. Copyright © 2017 The Authors. Published by Elsevier Ltd.. All rights reserved.

Stability Proxies for Water-in-Oil Emulsions and Implications in Aqueous-based Enhanced Oil Recovery

Directory of Open Access Journals (Sweden)

Mehrnoosh Moradi

2011-07-01

Full Text Available Several researchers have proposed that mobility control mechanisms can positively contribute to oil recovery in the case of emulsions generated in Enhanced-Oil Recovery (EOR operations. Chemical EOR techniques that use alkaline components or/and surfactants are known to produce undesirable emulsions that create operational problems and are difficult to break. Other water-based methods have been less studied in this sense. EOR processes such as polymer flooding and LoSalTM injection require adjustments of water chemistry, mainly by lowering the ionic strength of the solution or by decreasing hardness. The decreased ionic strength of EOR solutions can give rise to more stable water-in-oil emulsions, which are speculated to improve mobility ratio between the injectant and the displaced oil. The first step toward understanding the connection between the emulsions and EOR mechanisms is to show that EOR conditions, such as salinity and hardness requirements, among others, are conducive to stabilizing emulsions. In order to do this, adequate stability proxies are required. This paper reviews commonly used emulsion stability proxies and explains the advantages and disadvantage of methods reviewed. This paper also reviews aqueous-based EOR processes with focus on heavy oil to contextualize in-situ emulsion stabilization conditions. This context sets the basis for comparison of emulsion stability proxies.

Multiple sample setup for testing the hydrothermal stability of adsorbents in thermal energy storage applications

International Nuclear Information System (INIS)

Fischer, Fabian; Laevemann, Eberhard

2015-01-01

Thermal energy storage based on adsorption and desorption of water on an adsorbent can achieve high energy storage densities. Many adsorbents lose adsorption capacity when operated under unfavourable hydrothermal conditions during adsorption and desorption. The stability of an adsorbent against stressing hydrothermal conditions is a key issue for its usability in adsorption thermal energy storage. We built an experimental setup that simultaneously controls the hydrothermal conditions of 16 samples arranged in a matrix of four temperatures and four water vapour pressures. This setup allows the testing of potential adsorbents between temperatures of 50 °C and 350 °C and water vapour pressures of up to 32 kPa. A measurement procedure that allows the detection of the hydrothermal stability of an adsorbent after defined time spans has been designed. We verified the functionality of the multiple sample measurements with a microporous adsorbent, a zeolite NaMSX. The hydrothermal stability of this zeolite is tested by water uptake measurements. A standard deviation lower than 1% of the 16 samples for detecting the hydrothermal stability enables setting different conditions in each sample cell. Further, we compared the water uptake measurements by measuring their adsorption isotherms with the volumetric device BELSORP Aqua 3 from Bel Japan. (paper)

Influence of aliphatic amides on the temperature of maximum density of water

International Nuclear Information System (INIS)

Torres, Andrés Felipe; Romero, Carmen M.

2017-01-01

Highlights: • The addition of amides decreases the temperature of maximum density of water suggesting a disruptive effect on water structure. • The amides in aqueous solution do not follow the Despretz equation in the concentration range considered. • The temperature shift Δθ as a function of molality is represented by a second order equation. • The Despretz constants were determined considering the dilute concentration region for each amide solution. • Solute disrupting effect of amides becomes smaller as its hydrophobic character increases. - Abstract: The influence of dissolved substances on the temperature of the maximum density of water has been studied in relation to their effect on water structure as they can change the equilibrium between structured and unstructured species of water. However, most work has been performed using salts and the studies with small organic solutes such as amides are scarce. In this work, the effect of acetamide, propionamide and butyramide on the temperature of maximum density of water was determined from density measurements using a magnetic float densimeter. Densities of aqueous solutions were measured within the temperature range from T = (275.65–278.65) K at intervals of 0.50 K in the concentration range between (0.10000 and 0.80000) mol·kg −1 . The temperature of maximum density was determined from the experimental results. The effect of the three amides is to decrease the temperature of maximum density of water and the change does not follow the Despretz equation. The results are discussed in terms of solute-water interactions and the disrupting effect of amides on water structure.

Effect of water temperature on biofouling development in reverse osmosis membrane systems.

Science.gov (United States)

Farhat, N M; Vrouwenvelder, J S; Van Loosdrecht, M C M; Bucs, Sz S; Staal, M

2016-10-15

Understanding the factors that determine the spatial and temporal biofilm development is a key to formulate effective control strategies in reverse osmosis membrane systems for desalination and wastewater reuse. In this study, biofilm development was investigated at different water temperatures (10, 20, and 30 °C) inside a membrane fouling simulator (MFS) flow cell. The MFS studies were done at the same crossflow velocity with the same type of membrane and spacer materials, and the same feed water type and nutrient concentration, differing only in water temperature. Spatially resolved biofilm parameters such as oxygen decrease rate, biovolume, biofilm spatial distribution, thickness and composition were measured using in-situ imaging techniques. Pressure drop (PD) increase in time was used as a benchmark as to when to stop the experiments. Biofilm measurements were performed daily, and experiments were stopped once the average PD increased to 40 mbar/cm. The results of the biofouling study showed that with increasing feed water temperature (i) the biofilm activity developed faster, (ii) the pressure drop increased faster, while (iii) the biofilm thickness decreased. At an average pressure drop increase of 40 mbar/cm over the MFS for the different feed water temperatures, different biofilm activities, structures, and quantities were found, indicating that diagnosis of biofouling of membranes operated at different or varying (seasonal) feed water temperatures may be challenging. Membrane installations with a high temperature feed water are more susceptible to biofouling than installations fed with low temperature feed water. Copyright © 2016 Elsevier Ltd. All rights reserved.

Ionization of water clusters by fast Highly Charged Ions: Stability, fragmentation, energetics and charge mobility

International Nuclear Information System (INIS)

Legendre, S; Maisonny, R; Capron, M; Bernigaud, V; Cassimi, A; Gervais, B; Grandin, J-P; Huber, B A; Manil, B; Rousseau, P; Tarisien, M; Adoui, L; Lopez-Tarifa, P; AlcamI, M; MartIn, F; Politis, M-F; Penhoat, M A Herve du; Vuilleumier, R; Gaigeot, M-P; Tavernelli, I

2009-01-01

We study dissociative ionization of water clusters by impact of fast Ni ions. Cold Target Recoil Ion Momentum Spectroscopy (COLTRIMS) is used to obtain information about stability, energetics and charge mobility of the ionized clusters. An unusual stability of the (H 2 O) 4 H ''+ ion is observed, which could be the signature of the so called ''Eigen'' structure in gas phase water clusters. High charge mobility, responsible for the formation of protonated water clusters that dominate the mass spectrum, is evidenced. These results are supported by CPMD and TDDFT simulations, which also reveal the mechanisms of such mobility.

Using high thermal stability flexible thin film thermoelectric generator at moderate temperature

Science.gov (United States)

Zheng, Zhuang-Hao; Luo, Jing-Ting; Chen, Tian-Bao; Zhang, Xiang-Hua; Liang, Guang-Xing; Fan, Ping

2018-04-01

Flexible thin film thermoelectric devices are extensively used in the microscale industry for powering wearable electronics. In this study, comprehensive optimization was conducted in materials and connection design for fabricating a high thermal stability flexible thin film thermoelectric generator. First, the thin films in the generator, including the electrodes, were prepared by magnetron sputtering deposition. The "NiCu-Cu-NiCu" multilayer electrode structure was applied to ensure the thermal stability of the device used at moderate temperature in an air atmosphere. A design with metal layer bonding and series accordant connection was then employed. The maximum efficiency of a single PN thermocouple generator is >11%, and the output power loss of the generator is <10% after integration.

Temperature and coverage effects on the stability of epitaxial silicene on Ag(111) surfaces

Energy Technology Data Exchange (ETDEWEB)

Liu, Hongsheng; Han, Nannan; Zhao, Jijun, E-mail: zhao_jijun@hotmail.com

2017-07-01

Highlights: • Chemical potential phase diagrams of silicene/Ag(111) at varied temperatures. • The priorities of various silicene phases in experiments are explained. • A proper experimental condition to obtain homogeneous 4 × 4 silicene is recommended. - Abstract: Silicene, the single layer of silicon atoms arranged in a honeycomb lattice, has been synthesized in recent experiments and attracted significant attentions. Silicene is promising in future nanoelectronic devices due to its outstanding electronic properties. In experiments, however, different silicene superstructures coexist on Ag(111) substrate. For the device applications, homogenous silicene sheet with large scale and high quality is highly desired. Here, for the first time, we investigate both the temperature and the coverage effects on the thermal stability of epitaxial silicene on Ag(111) surface by ab initio molecular dynamics simulations. The relationship between the stability of various silicene superstructures and the growth conditions, including temperature and coverage of silicon atoms, is revealed by plotting the chemical potential phase diagram of silicene on Ag(111) surfaces at different temperatures. Our results are helpful for understanding the observed diversity of silicene phases on Ag(111) surfaces and provide some useful guidance for the synthesis of homogenous silicene phase in experiments.

Changes in Stream Water Temperatures in the Chesapeake Bay Region, 1960-2014

Science.gov (United States)

This map shows the changes in stream water temperatures in the Chesapeake Bay region from 1960 to 2014. Blue circles represent cooling trends in stream water temperatures, and red circles represent warming trends in stream water temperatures. Data were analyzed by Mike Kolian of EPA in partnership with John Jastram and Karen Rice of the U.S. Geological Survey. For more information: www.epa.gov/climatechange/science/indicators

Structure and stability of triglyceride monolayers on water and mica surfaces

NARCIS (Netherlands)

Zdravkova, A.N.; van der Eerden, J.P.J.M.

2007-01-01

The structure and the stability of tripalmitin (PPP), tristearin (SSS), and triarachidin (AAA) monolayers at the air-water interface are investigated with the Langmuir method. The Langmuir-Blodgett (LB) layers obtained by deposition on mica were investigated with atomic force microscopy (AFM). Our

Characterization of a Compact Water Vapor Radiometer

Science.gov (United States)

Gill, Ajay; Selina, Rob

2018-01-01

We report on laboratory test results of the Compact Water Vapor Radiometer (CWVR) prototype for the Karl G. Jansky Very Large Array (VLA), a five-channel design centered around the 22 GHz water vapor line. Fluctuations in perceptible water vapor cause fluctuations in atmospheric brightness emission, which are assumed to be proportional to phase fluctuations of the astronomical signal seen by an antenna. The design is intended to support empirical radiometric phase corrections for each baseline in the array.The dynamic range, channel isolation, and gain stability of the device were characterized. The device has a useful dynamic range of order 18 dB after calibration, and the CWVR channel isolation requirement of test, the diode detectors were operated in the square-law region, and a K-band noise diode was used as the broadband input power source to the CWVR over a period of 64 hours. Results indicate that the fluctuations in output counts are negatively correlated to the CWVR enclosure ambient temperature, with a change of ~ 405 counts per 1° C change in temperature.A correction for the CWVR ambient temperature makes a considerable improvement in stability for τ > 102.6 sec. With temperature corrections, the single channel and channel difference gain stability per channel is test results indicate that the CWVR meets required specifications for dynamic range, channel isolation, and gain stability in order to proceed with testing on a pair of VLA antennas.

Evaporation of nanoscale water on a uniformly complete wetting surface at different temperatures.

Science.gov (United States)

Guo, Yuwei; Wan, Rongzheng

2018-05-03

The evaporation of nanoscale water films on surfaces affects many processes in nature and industry. Using molecular dynamics (MD) simulations, we show the evaporation of a nanoscale water film on a uniformly complete wetting surface at different temperatures. With the increase in temperature, the growth of the water evaporation rate becomes slow. Analyses show that the hydrogen bond (H-bond) lifetimes and orientational autocorrelation times of the outermost water film decrease slowly with the increase in temperature. Compared to a thicker water film, the H-bond lifetimes and orientational autocorrelation times of a monolayer water film are much slower. This suggests that the lower evaporation rate of the monolayer water film on a uniformly complete wetting surface may be caused by the constriction of the water rotation due to the substrate. This finding may be helpful for controlling nanoscale water evaporation within a certain range of temperatures.

Thermal Stability of Hexamethyldisiloxane (MM for High-Temperature Organic Rankine Cycle (ORC

Directory of Open Access Journals (Sweden)

Markus Preißinger

2016-03-01

Full Text Available The design of efficient Organic Rankine Cycle (ORC units for the usage of industrial waste heat at high temperatures requires direct contact evaporators without intermediate thermal oil circuits. Therefore, the thermal stability of high-temperature working fluids gains importance. In this study, the thermal degradation of hexamethyldisiloxane (MM is investigated in an electrically heated tube. Qualitative results concerning remarks on degradation products as well as quantitative results like the annual degradation rate are presented. It is shown that MM is stable up to a temperature of 300 °C with annual degradation rates of less than 3.5%. Furthermore, the break of a silicon–carbon bond can be a main chemical reaction that influences the thermal degradation. Finally, it is discussed how the results may impact the future design of ORC units.

Effects of Temperature and Growing Seasons on Crop Water ...

African Journals Online (AJOL)

PROF HORSFALL

The crop water requirement (CWR) depends on several factors including temperature and ...... infrastructure for collection, treatment and recycling of wastewater (MOEP, 2010 .... blue and grey water footprint of crops and derived crop products ...

Experimental research of "microcable in a microconduct" system stability to effect of freezing water

Science.gov (United States)

Andreev, Vladimir A.; Burdin, Vladimir A.; Nikulina, Tatiana G.; Alekhin, Ivan N.; Gavryushin, Sergey A.; Nikulin, Aleksey G.; Praporshchikov, Denis E.

2011-12-01

Results of experimental researches of "optical microcable in a microduct" system stability to effect of freezing water are presented. It is shown this system is steadier to water freezing in comparison to lighten optical cable in protective polymer tube.

A high-stability non-contact dilatometer for low-amplitude temperature-modulated measurements

Energy Technology Data Exchange (ETDEWEB)

Luckabauer, Martin; Sprengel, Wolfgang; Würschum, Roland [Institute of Materials Physics, Graz University of Technology, A-8010 Graz (Austria)

2016-07-15

Temperature modulated thermophysical measurements can deliver valuable insights into the phase transformation behavior of many different materials. While especially for non-metallic systems at low temperatures numerous powerful methods exist, no high-temperature device suitable for modulated measurements of bulk metallic alloy samples is available for routine use. In this work a dilatometer for temperature modulated isothermal and non-isothermal measurements in the temperature range from room temperature to 1300 K is presented. The length measuring system is based on a two-beam Michelson laser interferometer with an incremental resolution of 20 pm. The non-contact measurement principle allows for resolving sinusoidal length change signals with amplitudes in the sub-500 nm range and physically decouples the length measuring system from the temperature modulation and heating control. To demonstrate the low-amplitude capabilities, results for the thermal expansion of nickel for two different modulation frequencies are presented. These results prove that the novel method can be used to routinely resolve length-change signals of metallic samples with temperature amplitudes well below 1 K. This high resolution in combination with the non-contact measurement principle significantly extends the application range of modulated dilatometry towards high-stability phase transformation measurements on complex alloys.

Effect of seasonal changes in use patterns and cold inlet water temperature on water-heating loads

Energy Technology Data Exchange (ETDEWEB)

Abrams, D.W.; Shedd, A.C. [D.W. Abrams, P.E. and Associates, Atlanta, GA (United States)

1996-11-01

This paper presents long-term test data obtained in 20 commercial buildings and 16 residential sites. The information illustrates the effects of variations in hot water load determinants and the effect on energy use. It also is useful as a supplement to the load profiles presented in the ASHRAE Handbooks and other design references. The commercial facilities include supermarkets, fast-food restaurants, full-service restaurants, commercial kitchens, a motel, a nursing home, a hospital, a bakery, and laundry facilities. The residential sites ere selected to provide test sites with higher-than-average hot water use. They include 13 single-family detached residences, one 14-unit apartment building, and two apartment laundries. Test data are available at measurement intervals of 1 minute for the residential sites and 15 minutes for the commercial sites. Summary data in tabular and graphical form are presented for average daily volumetric hot water use and cold inlet water temperature. Measured cold inlet water temperature and volumetric hot water use figures are compared to values typically used for design and analysis. Conclusions are offered regarding the effect of cold water inlet temperature and variations in hot water use on water-heating load and energy use. Recommendations for the use of the information presented in water-heating system design, performance optimization, and performance analysis conclude the paper.

Temperature stability of static and dynamic properties of 1.55 µm quantum dot lasers.

Science.gov (United States)

Abdollahinia, A; Banyoudeh, S; Rippien, A; Schnabel, F; Eyal, O; Cestier, I; Kalifa, I; Mentovich, E; Eisenstein, G; Reithmaier, J P

2018-03-05

Static and dynamic properties of InP-based 1.55 µm quantum dot (QD) lasers were investigated. Due to the reduced size inhomogeneity and a high dot density of the newest generation of 1.55 µm QD gain materials, ridge waveguide lasers (RWG) exhibit improved temperature stability and record-high modulation characteristics. Detailed results are shown for the temperature dependence of static properties including threshold current, voltage-current characteristics, external differential efficiency and emission wavelength. Similarly, small and large signal modulations were found to have only minor dependences on temperature. Moreover, we show the impact of the active region design and the cavity length on the temperature stability. Measurements were performed in pulsed and continuous wave operation. High characteristic temperatures for the threshold current were obtained with T 0 values of 144 K (15 - 60 °C), 101 K (60 - 110 °C) and 70 K up to 180 °C for a 900-µm-long RWG laser comprising 8 QD layers. The slope efficiency in these lasers is nearly independent of temperature showing a T 1 value of more than 900 K up to 110 °C. Due to the high modal gain, lasers with a cavity length of 340 µm reached new record modulation bandwidths of 17.5 GHz at 20 °C and 9 GHz at 80 °C, respectively. These lasers were modulated at 26 GBit/s in the non-return to zero format at 80 °C and at 25 GBaud using a four-level pulse amplitude format at 21 °C.

IMPACT OF WATER TEMPERATURE ON ZEBRA MUSSEL MORTALITY

Energy Technology Data Exchange (ETDEWEB)

Daniel P. Molloy

2002-08-07

These tests conducted this past quarter have indicated that the bacterium Pseudomonas fluorescens strain CL0145A is effective at killing zebra mussels at water temperatures ranging from 7 to 23 C. Percent kill will likely be somewhat lower at very low temperatures, e.g., 7 C, but even at such low temperatures high mussel kill can still be achieved (>70% kill). This is significant because the development of a zebra mussel control method that is efficacious in such a wide range of temperatures broadens its usefulness as a potential commercial product.

WATER TEMPERATURE, VOLUNTARY DRINKING AND FLUID BALANCE IN DEHYDRATED TAEKWONDO ATHLETES

Directory of Open Access Journals (Sweden)

Saeed Khamnei

2011-12-01

Full Text Available Voluntary drinking is one of the major determiners of rehydration, especially as regards exercise or workout in the heat. The present study undertakes to search for the effect of voluntary intake of water with different temperatures on fluid balance in Taekwondo athletes. Six young healthy male Taekwondo athletes were dehydrated by moderate exercise in a chamber with ambient temperature at 38-40°C and relative humidity between 20-30%. On four separate days they were allowed to drink ad libitum plane water with the four temperatures of 5, 16, 26, and 58°C, after dehydration. The volume of voluntary drinking and weight change was measured; then the primary percentage of dehydration, sweat loss, fluid deficit and involuntary dehydration were calculated. Voluntary drinking of water proved to be statistically different in the presented temperatures. Water at 16°C involved the greatest intake, while fluid deficit and involuntary dehydration were the lowest. Intake of water in the 5°C trial significantly correlated with the subject's plasma osmolality change after dehydration, yet it showed no significant correlation with weight loss. In conclusion, by way of achieving more voluntary intake of water and better fluid state, recommending cool water (~16°C for athletes is in order. Unlike the publicly held view, drinking cold water (~5°C does not improve voluntary drinking and hydration status.

Enhancing the water stability of Al-MIL-101-NH2 via postsynthetic modification.

Science.gov (United States)

Wittmann, Thomas; Siegel, Renée; Reimer, Nele; Milius, Wolfgang; Stock, Norbert; Senker, Jürgen

2015-01-02

The resistance of metal-organic frameworks towards water is a very critical issue concerning their practical use. Recently, it was shown for microporous MOFs that the water stability could be increased by introducing hydrophobic pendant groups. Here, we demonstrate a remarkable stabilisation of the mesoporous MOF Al-MIL-101-NH2 by postsynthetic modification with phenyl isocyanate. In this process 86 % of the amino groups were converted into phenylurea units. As a consequence, the long-term stability of Al-MIL-101-URPh in liquid water could be extended beyond a week. In water saturated atmospheres Al-MIL-101-URPh decomposed at least 12-times slower than the unfunctionalised analogue. To study the underlying processes both materials were characterised by Ar, N2 and H2 O sorption measurements, powder X-ray diffraction, thermogravimetric and chemical analysis as well as solid-state NMR and IR spectroscopy. Postsynthetic modification decreased the BET equivalent surface area from 3363 to 1555 m(2)  g(-1) for Al-MIL-101-URPh and reduced the mean diameters of the mesopores by 0.6 nm without degrading the structure significantly and reducing thermal stability. In spite of similar water uptake capacities, the relative humidity-dependent uptake of Al-MIL-101-URPh is slowed and occurs at higher relative humidity values. In combination with (1) H-(27) Al D-HMQC NMR spectroscopy experiments this favours a shielding mechanism of the Al clusters by the pendant phenyl groups and rules out pore blocking. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Corrosion behavior in high-temperature pressurized water of Zircaloy-4 joints brazed with Zr-Cu-based amorphous filler alloys

Energy Technology Data Exchange (ETDEWEB)

Lee, Jung Gu, E-mail: jglee88@ulsan.ac.kr [School of Materials Science and Engineering, University of Ulsan, Ulsan 44610 (Korea, Republic of); Lee, Gyoung-Ja; Park, Jin-Ju [Nuclear Materials Development Division, Korea Atomic Energy Research Institute (KAERI), Yuseong, Daejeon 34057 (Korea, Republic of); Lee, Min-Ku, E-mail: leeminku@kaeri.re.kr [Nuclear Materials Development Division, Korea Atomic Energy Research Institute (KAERI), Yuseong, Daejeon 34057 (Korea, Republic of)

2017-05-15

The compositional effects of ternary Zr-Cu-X (X: Al, Fe) amorphous filler alloys on galvanic corrosion susceptibility in high-temperature pressurized water were investigated for Zircaloy-4 brazed joints. Through an Al-induced microgalvanic reaction that deteriorated the overall nobility of the joint, application of the Zr-Cu-Al filler alloy caused galvanic coupling to develop readily between the Al-bearing joint and the Al-free base metal, finally leading to massive localized corrosion of the joint. Contrastingly, joints prepared with a Zr-Cu-Fe filler alloy showed excellent corrosion resistance comparable to that of the Zircaloy-4 base metal, since the Cu and Fe elements forming fine intermetallic particles with Zr did not influence the electrochemical stability of the resultant joints. The present results demonstrate that Fe is a more suitable alloying element than Al for brazing filler alloys subjected to high-temperature corrosive environments. - Highlights: •Corrosion of Zircaloy-4 joints brazed with Zr-Cu-X filler alloys was investigated. •Alloyed Al deteriorated the overall nobility of joints by microgalvanic reaction. •Compositional gradient of Al in joints was the driving force for galvanic corrosion. •Cu and Fe did not influence the electrochemical stability of joints. •Zr-Cu-Fe filler alloy yielded excellent high-temperature corrosion resistance.

Corrosion behavior in high-temperature pressurized water of Zircaloy-4 joints brazed with Zr-Cu-based amorphous filler alloys

International Nuclear Information System (INIS)

Lee, Jung Gu; Lee, Gyoung-Ja; Park, Jin-Ju; Lee, Min-Ku

2017-01-01

The compositional effects of ternary Zr-Cu-X (X: Al, Fe) amorphous filler alloys on galvanic corrosion susceptibility in high-temperature pressurized water were investigated for Zircaloy-4 brazed joints. Through an Al-induced microgalvanic reaction that deteriorated the overall nobility of the joint, application of the Zr-Cu-Al filler alloy caused galvanic coupling to develop readily between the Al-bearing joint and the Al-free base metal, finally leading to massive localized corrosion of the joint. Contrastingly, joints prepared with a Zr-Cu-Fe filler alloy showed excellent corrosion resistance comparable to that of the Zircaloy-4 base metal, since the Cu and Fe elements forming fine intermetallic particles with Zr did not influence the electrochemical stability of the resultant joints. The present results demonstrate that Fe is a more suitable alloying element than Al for brazing filler alloys subjected to high-temperature corrosive environments. - Highlights: •Corrosion of Zircaloy-4 joints brazed with Zr-Cu-X filler alloys was investigated. •Alloyed Al deteriorated the overall nobility of joints by microgalvanic reaction. •Compositional gradient of Al in joints was the driving force for galvanic corrosion. •Cu and Fe did not influence the electrochemical stability of joints. •Zr-Cu-Fe filler alloy yielded excellent high-temperature corrosion resistance.

Influence of scandium addition on the high-temperature grain size stabilization of oxide-dispersion-strengthened (ODS) ferritic alloy

Energy Technology Data Exchange (ETDEWEB)

Li, Lulu, E-mail: lli18@ncsu.edu; Xu, Weizong; Saber, Mostafa; Zhu, Yuntian; Koch, Carl C.; Scattergood, Ronald O.

2015-06-11

The influence of 1–4 at% Sc addition on the thermal stability of mechanically alloyed ODS ferritic alloy was studied in this work. Sc addition was found to significantly stabilize grain size and microhardness at high temperatures. Grain sizes of samples with 1 and 4 at% Sc was found maintained in the nanoscale range at temperatures up to 1000 °C with hardness maintained at 5.6 and 6.7 GPa, respectively. The detailed microstructure was also investigated from EDS elemental mapping, where nanofeatures [ScTiO] were observed, while nanosized [YTiO] particles were rarely seen. This is probably due to the concentration difference between Sc and Y, leading to the formation of [ScTiO] favoring that of [YTiO]. Precipitation was considered as the major source for the observed high temperature stabilization. In addition, 14YT–Sc alloys without large second phases such as Ti-oxide can exhibit better performance compared to conventional ODS materials.

Operational efficiency of ballast water biocides at low water temperatures

NARCIS (Netherlands)

Kaag, N.H.B.M.; Sneekes, A.C.

2015-01-01