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Sample records for water reducing agents

  1. The preparation of solid acid and acid water reducing agent for slag is prepared by adsorption method

    Science.gov (United States)

    Zhao, Su; Wang, Jinpeng; Zhu, Xitong

    2018-03-01

    Solid polycarboxylate superplasticizer can not only solve the problems caused by water reducing agent in storage and transportation, but also meet the needs of some special projects. We can choose to use the mineral slag, which is larger than surface area and has stronger adsorption, as adsorbent to absorb liquid polycarboxylate superplasticizer and absorb its moisture, and then makes solid polycarboxylate superplasticizer after drying. It determines the solid-liquid ratio to prepare the solid polycarboxylate superplasticizer to be 3:1. The temperature change within 100°C will not cause changes in the functional group and structure of the water reducing agent molecule. The application of the solid polycarboxylate superplasticizer was basically unchanged compared with its liquid water reducing agent.

  2. Research on the Preparation and Performance of Binary Modified Maltodextrin Water-Reducing Agent

    Directory of Open Access Journals (Sweden)

    Jingzhi Wu

    2016-01-01

    Full Text Available Using maltodextrin (MD of different dextrose equivalent (DE values, 1,3-propanesultone, and maleic anhydride as raw materials, a novel binary modified maltodextrin (BMMD was synthesized and further applied as a water-reducing agent. Its structure was characterized by Fourier transform infrared (FT-IR and UV. The rheological behavior of the sample solution and strengths for concrete were also determined and the adsorption was tested by TOC. The influence of the process parameters to degree of substitution (DS and the dosage on the fluidity of cement paste were investigated. The results show that the optimal conditions of sulfonation were the MD of DE 15, m (sulfonated agent/m (MD of 1.4, the catalyst amount of 1% by mass MD, and the reaction time of 12 h; the optimal conditions of esterification were m (esterified agent/m (SMD of 0.6, the reaction temperature of 90°C, and the reaction time of 4 h. The optimal dosages of sulfonated maltodextrin (SMD and BMMD were 0.475% and 0.45%, respectively. In this dosage, the main dispersion capacity of BMMD attributes to two kinds of anchoring groups (SO3-  &  COO- and the appropriate molecular weight of MD.

  3. An Agent-based Modeling of Water-Food Nexus towards Sustainable Management of Urban Water Resources

    Science.gov (United States)

    Esmaeili, N.; Kanta, L.

    2017-12-01

    Growing population, urbanization, and climate change have put tremendous stress on water systems in many regions. A shortage in water system not only affects water users of a municipality but also that of food system. About 70% of global water is withdrawn for agriculture; livestock and dairy productions are also dependent on water availability. Although researchers and policy makers have identified and emphasized the water-food (WF) nexus in recent decade, most existing WF models offer strategies to reduce trade-offs and to generate benefits without considering feedback loops and adaptations between those systems. Feedback loops between water and food system can help understand long-term behavioral trends between water users of the integrated WF system which, in turn, can help manage water resources sustainably. An Agent-based modeling approach is applied here to develop a conceptual framework of WF systems. All water users in this system are modeled as agents, who are capable of making decisions and can adapt new behavior based on inputs from other agents in a shared environment through a set of logical and mathematical rules. Residential and commercial/industrial consumers are represented as municipal agents; crop, livestock, and dairy farmers are represented as food agents; and water management officials are represented as policy agent. During the period of water shortage, policy agent will propose/impose various water conservation measures, such as adapting water-efficient technologies, banning outdoor irrigation, implementing supplemental irrigation, using recycled water for livestock/dairy production, among others. Municipal and food agents may adapt conservation strategies and will update their demand accordingly. Emergent properties of the WF nexus will arise through dynamic interactions between various actors of water and food system. This model will be implemented to a case study for resource allocation and future policy development.

  4. Study of Ascorbic Acid as Iron(III Reducing Agent for Spectrophotometric Iron Speciation

    Directory of Open Access Journals (Sweden)

    Antesar Elmagirbi

    2012-10-01

    Full Text Available The study of ascorbic acid as a reducing agent for iron(III has been investigated in order to obtain an alternative carcinogenic reducing agent, hydroxylamine, used in spectrophotometric standard method based on the formation of a red-orange complex of Fe(II-o-phenanthroline. The study was optimised with regards to ascorbic acid concentration as well as pH solution. The results showed that ascorbic acid showed maximum capacity as reducing agent of iron(III under concentration of 4.46.10-4 M and pH solution of 1-4.Under these conditions, ascorbic acid reduced iron(III proportionally and performed similarly to that of hydroxylamine.  The method gave result to linear calibration over the range of 0.2-2 mg/L withhigh accuracy of 97 % and relative standard deviation of less than 2 %. This method was successfully applied to assay iron speciation in water samples.

  5. Natural Ferrihydrite as an Agent for Reducing Turbidity Caused by Suspended Clays

    Science.gov (United States)

    The turbidity of water can be reduced by the addition of positively charged compounds which coagulate negatively charged clay particles in suspension causing them to flocculate. This research was conducted to determine the effectiveness of the Fe oxide mineral ferrihydrite as a flocculating agent fo...

  6. Catalytic properties of graphene–metal nanoparticle hybrid prepared using an aromatic amino acid as the reducing agent

    International Nuclear Information System (INIS)

    Adhikari, Bimalendu; Banerjee, Arindam

    2013-01-01

    An easy and single step process of making reduced graphene oxide nanosheet from graphene oxide (GO) in water medium has been demonstrated by using a naturally occurring non-proteinaceous amino acid (2,4-dihydroxy phenyl alanine, Dopa) as a new reducing agent and stabilizing agent. This amino acid has also been used to reduce the noble metal salt (AuCl 3 /AgNO 3 ) to produce the corresponding noble metal nanoparticles (MNP) without using any external reducing and stabilizing agents. So, this amino acid has been used to reduce simultaneously GO to RGO and noble metal salts to produce corresponding MNP to form RGO–MNP nanohybrid system in a single step in water medium and also in absence of any external toxic reducing and stabilizing agents. Different techniques UV–Visible absorption spectroscopy, X-ray diffraction, transmission electron microscopy, atomic force microscopy and others have been used to characterize the reduction of GO to RGO, metal salts to produce corresponding MNPs and the formation of RGO–MNP nanohybrid systems. Moreover, this metal nanoparticle containing RGO–MNP nanohybrid system acts as a potential catalyst for the reduction of aromatic nitro to aromatic amino group. - Graphical abstract: This study demonstrates an easy, single step and eco-friendly method to make RGO and Au/AgNP simultaneously from respective precursors to form a RGO–Au/AgNP nanohybrid system using an aromatic amino acid (2,4-dihydroxy phenyl alanine, Dopa) as a new reducing agent as well as stabilizing agent in water medium. Highlights: ► Synthesis of reduced graphene oxide (RGO) nanosheet using an amino acid. ► The amino acid (Dopa) can reduce noble metal salt (Au 3+ /Ag + ) to metal nanoparticle (MNP). ► Single step and eco-friendly synthesis of RGO-MNP nanohybrid using Dopa. ► Characterization of RGO, MNP and RGO–MNP nanohybrid. ► RGO-MNP nanohybrid acts as a catalyst for the reduction of aromatic nitro

  7. An overview of advanced reduction processes for bromate removal from drinking water: Reducing agents, activation methods, applications and mechanisms.

    Science.gov (United States)

    Xiao, Qian; Yu, Shuili; Li, Lei; Wang, Ting; Liao, Xinlei; Ye, Yubing

    2017-02-15

    Bromate (BrO 3 - ) is a possible human carcinogen regulated at a strict standard of 10μg/L in drinking water. Various techniques to eliminate BrO 3 - usually fall into three main categories: reducing bromide (Br - ) prior to formation of BrO 3 - , minimizing BrO 3 - formation during the ozonation process, and removing BrO 3 - from post-ozonation waters. However, the first two approaches exhibit low degradation efficiency and high treatment cost. The third workaround has obvious advantages, such as high reduction efficiency, more stable performance and easier combination with UV disinfection, and has therefore been widely implemented in water treatment. Recently, advanced reduction processes (ARPs), the photocatalysis of BrO 3 - , have attracted much attention due to improved performance. To increase the feasibility of photocatalytic systems, the focus of this work concerns new technological developments, followed by a summary of reducing agents, activation methods, operational parameters, and applications. The reaction mechanisms of two typical processes involving UV/sulfite homogeneous photocatalysis and UV/titanium dioxide heterogeneous photocatalysis are further summarized. The future research needs for ARPs to reach full-scale potential in drinking water treatment are suggested accordingly. Copyright © 2016. Published by Elsevier B.V.

  8. Activation of aluminum as an effective reducing agent by pitting corrosion for wet-chemical synthesis.

    Science.gov (United States)

    Li, Wei; Cochell, Thomas; Manthiram, Arumugam

    2013-01-01

    Metallic aluminum (Al) is of interest as a reducing agent because of its low standard reduction potential. However, its surface is invariably covered with a dense aluminum oxide film, which prevents its effective use as a reducing agent in wet-chemical synthesis. Pitting corrosion, known as an undesired reaction destroying Al and is enhanced by anions such as F⁻, Cl⁻, and Br⁻ in aqueous solutions, is applied here for the first time to activate Al as a reducing agent for wet-chemical synthesis of a diverse array of metals and alloys. Specifically, we demonstrate the synthesis of highly dispersed palladium nanoparticles on carbon black with stabilizers and the intermetallic Cu₂Sb/C, which are promising candidates, respectively, for fuel cell catalysts and lithium-ion battery anodes. Atomic hydrogen, an intermediate during the pitting corrosion of Al in protonic solvents (e.g., water and ethylene glycol), is validated as the actual reducing agent.

  9. Multi-agent Water Resources Management

    Science.gov (United States)

    Castelletti, A.; Giuliani, M.

    2011-12-01

    Increasing environmental awareness and emerging trends such as water trading, energy market, deregulation and democratization of water-related services are challenging integrated water resources planning and management worldwide. The traditional approach to water management design based on sector-by-sector optimization has to be reshaped to account for multiple interrelated decision-makers and many stakeholders with increasing decision power. Centralized management, though interesting from a conceptual point of view, is unfeasible in most of the modern social and institutional contexts, and often economically inefficient. Coordinated management, where different actors interact within a full open trust exchange paradigm under some institutional supervision is a promising alternative to the ideal centralized solution and the actual uncoordinated practices. This is a significant issue in most of the Southern Alps regulated lakes, where upstream hydropower reservoirs maximize their benefit independently form downstream users; it becomes even more relevant in the case of transboundary systems, where water management upstream affects water availability downstream (e.g. the River Zambesi flowing through Zambia, Zimbabwe and Mozambique or the Red River flowing from South-Western China through Northern Vietnam. In this study we apply Multi-Agent Systems (MAS) theory to design an optimal management in a decentralized way, considering a set of multiple autonomous agents acting in the same environment and taking into account the pay-off of individual water users, which are inherently distributed along the river and need to coordinate to jointly reach their objectives. In this way each real-world actor, representing the decision-making entity (e.g. the operator of a reservoir or a diversion dam) can be represented one-to-one by a computer agent, defined as a computer system that is situated in some environment and that is capable of autonomous action in this environment in

  10. An Agent Based Model of Household Water Use

    Directory of Open Access Journals (Sweden)

    Clinton J. Andrews

    2013-07-01

    Full Text Available Households consume a significant fraction of total potable water production. Strategies to improve the efficiency of water use tend to emphasize technological interventions to reduce or shift water demand. Behavioral water use reduction strategies can also play an important role, but a flexible framework for exploring the “what-ifs” has not been available. This paper introduces such a framework, presenting an agent-based model of household water-consuming behavior. The model simulates hourly water-using activities of household members within a rich technological and behavioral context, calibrated with appropriate data. Illustrative experiments compare the resulting water usage of U.S. and Dutch households and their associated water-using technologies, different household types (singles, families with children, and retired couples, different water metering regimes, and educational campaigns. All else equal, Dutch and metered households use less water. Retired households use more water because they are more often at home. Water-saving educational campaigns are effective for the part of the population that is receptive. Important interactions among these factors, both technological and behavioral, highlight the value of this framework for integrated analysis of the human-technology-water system.

  11. Reducing Interaction Costs for Self-interested Agents

    Science.gov (United States)

    Zhang, Yunqi; Larson, Kate

    In many multiagent systems, agents are not able to freely interact with each other or with a centralized mechanism. They may be limited in their interactions by cost or by the inherent structure of the system. Using a combinatorial auction application as motivation, we study the impact of interaction costs and structure on the strategic behaviour of self-interested agents. We present a particular model of costly agent-interaction, and argue that self-interested agents may wish to coordinate their actions with their neighbours so as to reduce their individual costs. We highlight the issues that arise in such a setting, propose a cost-sharing mechanism that agents can use, and discuss group coordination procedures. Experimental work validates our model.

  12. Evaluation of nitrogen containing reducing agents for the corrosion control of materials relevant to nuclear reactors

    Energy Technology Data Exchange (ETDEWEB)

    Kumar, Padma S. [Water and Steam Chemistry Division, BARC Facilities, Kalpakkam, Tamilnadu (India); Mohan, D. [Department of Chemistry, Anna University, Chennai, Tamilnadu (India); Chandran, Sinu; Rajesh, Puspalata; Rangarajan, S. [Water and Steam Chemistry Division, BARC Facilities, Kalpakkam, Tamilnadu (India); Velmurugan, S., E-mail: svelu@igcar.gov.in [Water and Steam Chemistry Division, BARC Facilities, Kalpakkam, Tamilnadu (India)

    2017-02-01

    Materials undergo enhanced corrosion in the presence of oxidants in aqueous media. Usually, hydrogen gas or water soluble reducing agents are used for inhibiting corrosion. In the present study, the feasibility of using alternate reducing agents such as hydrazine, aqueous ammonia, and hydroxylamine that can stay in the liquid phase was investigated. A comparative study of corrosion behavior of the structural materials of the nuclear reactor viz. carbon steel (CS), stainless steel (SS-304 LN), monel-400 and incoloy-800 in the oxidizing and reducing conditions was also made. In nuclear industry, the presence of radiation field adds to the corrosion problems. The radiolysis products of water such as oxygen and hydrogen peroxide create an oxidizing environment that enhances the corrosion. Electrochemical studies at 90 °C showed that the reducing agents investigated were efficient in controlling corrosion processes in the presence of oxygen and hydrogen peroxide. Evaluation of thermal stability of hydrazine and its effect on corrosion potential of SS-304 LN were also investigated in the temperature range of 200–280 °C. The results showed that the thermal decomposition of hydrazine followed a first order kinetics. Besides, a change in electrochemical corrosion potential (ECP) was observed from −0.4 V (Vs SHE) to −0.67 V (Vs SHE) on addition of 5 ppm of hydrazine at 240 °C. Investigations were also made to understand the distribution behavior of hydrogen peroxide and hydrazine in water-steam phases and it was found that both the phases showed identical behavior. - Highlights: • Hydrazine was found to be a promising reducing agent for oxidant control. • In presence of hydrazine corrosion potential of SS304 LN was well below −230 mV. • SS304LN could be protected from IGSCC by hydrazine addition. • Thermal and radiation stability of hydrazine at 285 °C was found satisfactory.

  13. Evaluating Water Demand Using Agent-Based Modeling

    Science.gov (United States)

    Lowry, T. S.

    2004-12-01

    The supply and demand of water resources are functions of complex, inter-related systems including hydrology, climate, demographics, economics, and policy. To assess the safety and sustainability of water resources, planners often rely on complex numerical models that relate some or all of these systems using mathematical abstractions. The accuracy of these models relies on how well the abstractions capture the true nature of the systems interactions. Typically, these abstractions are based on analyses of observations and/or experiments that account only for the statistical mean behavior of each system. This limits the approach in two important ways: 1) It cannot capture cross-system disruptive events, such as major drought, significant policy change, or terrorist attack, and 2) it cannot resolve sub-system level responses. To overcome these limitations, we are developing an agent-based water resources model that includes the systems of hydrology, climate, demographics, economics, and policy, to examine water demand during normal and extraordinary conditions. Agent-based modeling (ABM) develops functional relationships between systems by modeling the interaction between individuals (agents), who behave according to a probabilistic set of rules. ABM is a "bottom-up" modeling approach in that it defines macro-system behavior by modeling the micro-behavior of individual agents. While each agent's behavior is often simple and predictable, the aggregate behavior of all agents in each system can be complex, unpredictable, and different than behaviors observed in mean-behavior models. Furthermore, the ABM approach creates a virtual laboratory where the effects of policy changes and/or extraordinary events can be simulated. Our model, which is based on the demographics and hydrology of the Middle Rio Grande Basin in the state of New Mexico, includes agent groups of residential, agricultural, and industrial users. Each agent within each group determines its water usage

  14. Radiodiagnostic complexes employing fluorine-containing tin reducing agents

    International Nuclear Information System (INIS)

    Hill, B.K.; Kubik, V.M.

    1977-01-01

    Radiodiagnostic agents for use in mammalian bodies comprising a radiocomplex which is the reaction product of Tc99m-pertechnetate ion, a diagnostic ligand and a tin (II) reducing agent selected from the group consisting of SnF 2 , MSnF 3 , MSn 2 F 5 and mixtures thereof, wherein M is NH 4 , Na, K, Li, Rb or Cs. Radiocomplex precursor compositions and methods of making the radiocomplex and radiodiagnostic agents are described

  15. Effect of reducing agents on wheat gluten and quality characteristics of flour and cookies

    Directory of Open Access Journals (Sweden)

    Naveen KUMAR

    2013-12-01

    Full Text Available The aim of the present study was to determine the effect of reducing agents (Lcystine, glutathione and proteases on wheat gluten recovery and quality characteristics of dough and cookies. PBW-343 and RAJ-3765 wheat varieties were analysed for physico-chemical properties which indicated that wheat variety RAJ-3765 had superior quality characteristics in comparison to PBW-343. Wet gluten and dry gluten %yields were reduced with addition of reducing agents. As the concentration of reducing agents increased gluten, yield decreased further. The dough strength (resistance to extension decreased, whereas extension of dough increased significantly with the addition of reducing agents. Upon addition of reducing agents, spread factor increased, whereas hardness decreased. Glutathione was found to be the most effective reducing agent out of the three reducing agents used in this study.

  16. Evolutionary Agent-based Models to design distributed water management strategies

    Science.gov (United States)

    Giuliani, M.; Castelletti, A.; Reed, P. M.

    2012-12-01

    There is growing awareness in the scientific community that the traditional centralized approach to water resources management, as described in much of the water resources literature, provides an ideal optimal solution, which is certainly useful to quantify the best physically achievable performance, but is generally inapplicable. Most real world water resources management problems are indeed characterized by the presence of multiple, distributed and institutionally-independent decision-makers. Multi-Agent Systems provide a potentially more realistic alternative framework to model multiple and self-interested decision-makers in a credible context. Each decision-maker can be represented by an agent who, being self-interested, acts according to local objective functions and produces negative externalities on system level objectives. Different levels of coordination can potentially be included in the framework by designing coordination mechanisms to drive the current decision-making structure toward the global system efficiency. Yet, the identification of effective coordination strategies can be particularly complex in modern institutional contexts and current practice is dependent on largely ad-hoc coordination strategies. In this work we propose a novel Evolutionary Agent-based Modeling (EAM) framework that enables a mapping of fully uncoordinated and centrally coordinated solutions into their relative "many-objective" tradeoffs using multiobjective evolutionary algorithms. Then, by analysing the conflicts between local individual agent and global system level objectives it is possible to more fully understand the causes, consequences, and potential solution strategies for coordination failures. Game-theoretic criteria have value for identifying the most interesting alternatives from a policy making point of view as well as the coordination mechanisms that can be applied to obtain these interesting solutions. The proposed approach is numerically tested on a

  17. Wax solidification of drying agents containing tritiated water

    International Nuclear Information System (INIS)

    Mishikawa, M.; Kido, H.

    1984-01-01

    It is necessary to immobilize the tritium not to give any impact on the environmental biosphere because tritium may give profound effects in the metabolic pathway. One of the most probable methods of immobilizing tritium would be incorporation of tritiated water in solid forms. Any drying or dehydration technique would be effective in a tritium cleanup system for off-gas streams containing tritium or tritiated water. Commonly used drying agents such as activated alumina, silica gel, molecular sieves and calcium sulfate are of value for removal of water vapour from air or other gases. For long term tritium storage, however, these adsorptive materials should be enveloped to prevent contact with water or water vapour because the rate of leaching, evaporation or diffusion of tritium from these porous materials is so large. The beeswax solidification method of the packed bed of drying agents adsorbing tritiated water is developed in this study, where the wax solidification procedure is performed by pouring the melt of wax into the void space of the packed bed of the drying agents and successive gradual cooling. The observed values of diffusivity or permeability of tritium in the wax solidified materials are about one-thousandth of those obtained for the cement block. Effect of coating on the rate of leaching is also discussed

  18. The Removal of Cu (II) from Aqueous Solution using Sodium Borohydride as a Reducing Agent

    Science.gov (United States)

    Sithole, N. T.; Ntuli, F.; Mashifana, T.

    2018-03-01

    The removal and recovery of metals from wastewater has been a subject of significant importance due the negative impact these toxic metals have on human health and the environment as a result of water and soil pollution. Increased use of the metals and chemicals in the process industries has resulted in generation of large quantity of effluents that contains high level of toxic metals and other pollutants. The objective of this work was to recover of Cu in its elemental form as metallic powder from aqueous solution using NaBH4 as a reducing agent. Reductive precipitation was achieved in a batch reactor at 65°C using Cu powder as a seeding material. This study also investigated the effect of concentration of sodium borohydride (NaBH4) as a reducing agent. The amount of NaBH4 was varied based on mole ratios which are 1:1, 1:0.25 and 1:0.1 to recover Cu from synthetic wastewater. The results obtained showed that sodium borohydride is an effective reducing agent to recover Cu from wastewater. The optimum concentration of NaBH4 that gives the best results the 1:1 molar ratio with over 99% Cu removal.

  19. Evaluating Outdoor Water Use Demand under Changing Climatic and Demographic Conditions: An Agent-based Modeling Approach

    Science.gov (United States)

    Kanta, L.; Berglund, E. Z.; Soh, M. H.

    2017-12-01

    Outdoor water-use for landscape and irrigation constitutes a significant end-use in total residential water demand. In periods of water shortages, utilities may reduce garden demands by implementing irrigation system audits, rebate programs, local ordinances, and voluntary or mandatory water-use restrictions. Because utilities do not typically record outdoor and indoor water-uses separately, the effects of policies for reducing garden demands cannot be readily calculated. The volume of water required to meet garden demands depends on the housing density, lawn size, type of vegetation, climatic conditions, efficiency of garden irrigation systems, and consumer water-use behaviors. Many existing outdoor demand estimation methods are deterministic and do not include consumer responses to conservation campaigns. In addition, mandatory restrictions may have a substantial impact on reducing outdoor demands, but the effectiveness of mandatory restrictions depends on the timing and the frequency of restrictions, in addition to the distribution of housing density and consumer types within a community. This research investigates a garden end-use model by coupling an agent-based modeling approach and a mechanistic-stochastic water demand model to create a methodology for estimating garden demand and evaluating demand reduction policies. The garden demand model is developed for two water utilities, using a diverse data sets, including residential customer billing records, outdoor conservation programs, frequency and type of mandatory water-use restrictions, lot size distribution, population growth, and climatic data. A set of garden irrigation parameter values, which are based on the efficiency of irrigation systems and irrigation habits of consumers, are determined for a set of conservation ordinances and restrictions. The model parameters are then validated using customer water usage data from the participating water utilities. A sensitivity analysis is conducted for garden

  20. Tissue-based water quality biosensors for detecting chemical warfare agents

    Science.gov (United States)

    Greenbaum, Elias [Oak Ridge, TN; Sanders, Charlene A [Knoxville, TN

    2003-05-27

    A water quality sensor for detecting the presence of at least one chemical or biological warfare agent includes: a cell; apparatus for introducing water into the cell and discharging water from the cell adapted for analyzing photosynthetic activity of naturally occurring, free-living, indigenous photosynthetic organisms in water; a fluorometer for measuring photosynthetic activity of naturally occurring, free-living, indigenous photosynthetic organisms drawn into the cell; and an electronics package that analyzes raw data from the fluorometer and emits a signal indicating the presence of at least one chemical or biological warfare agent in the water.

  1. Radiographic scintiscanning agent

    International Nuclear Information System (INIS)

    Bevan, J.A.

    1979-01-01

    A new technetium-based scintiscanning agent has been prepared comprising a water soluble sup(99m)Tc-methanehydroxydiphosphonate in combination with a reducing agent selected from stannous, ferrous, chromous and titanous salts. As an additional stabilizer salts and esters of gentisic or ascorbic acids have been used. (E.G.)

  2. Orange juice substantially reduces the bioavailability of the beta-adrenergic-blocking agent celiprolol.

    Science.gov (United States)

    Lilja, Jari J; Juntti-Patinen, Laura; Neuvonen, Pertti J

    2004-03-01

    Grapefruit juice was recently found to decrease plasma concentrations of the beta-adrenergic receptor-blocking agent celiprolol. Our objective was to investigate the effect of orange juice on the pharmacokinetics of celiprolol in healthy subjects. In a randomized crossover study with 2 phases and a washout of 2 weeks, 10 healthy volunteers ingested either 200 mL normal-strength orange juice or water 3 times a day for 2 days. On the morning of day 3, 1 hour after ingestion of 200 mL orange juice or water, each subject ingested 100 mg celiprolol with either 200 mL orange juice or water. In addition, 200 mL orange juice or water was ingested at 4, 10, 22, and 27 hours after celiprolol intake. The concentrations of celiprolol in plasma and its excretion into urine were measured up to 33 hours after its dosing. Systolic and diastolic blood pressures and heart rate were recorded up to 10 hours. Orange juice reduced the mean peak plasma concentration of celiprolol by 89% (P orange juice. Orange juice reduced the urinary excretion of celiprolol by 77% (P Orange juice substantially reduces the bioavailability of celiprolol, but the mechanism of this interaction remains to be resolved. For example, modulation of intestinal pH and of function of transporters implicated in the absorption of celiprolol may be involved. Because of the great extent of the orange juice-celiprolol interaction and a wide use of orange juice, this interaction is likely to have clinical importance in some patients, although hemodynamic consequences were not seen in young healthy subjects.

  3. Properties of experimental titanium cast investment mixing with water reducing agent solution.

    Science.gov (United States)

    Zhang, Zutai; Ding, Ning; Tamaki, Yukimichi; Hotta, Yasuhiro; Han-Cheol, Cho; Miyazaki, Takashi

    2012-01-01

    This study aimed to develop a dental investment for titanium casting. ZrO(2) and Al(2)O(3) were selected as refractory materials to prepare three investments (Codes: A-C) according to the quantity of Zr. Al(2)O(3) cement was used as a binder at a ratio of 15%, they were mixed with special mixing liquid. B1 was used as a control mixed with water. Fundamental examinations were statistically evaluated. A casting test was performed with investment B. Fluidities, setting times, and green strengths showed no remarkable differences; however, they were significantly different from those of B1. Expansion values for A, B, C, and B1 at 850°C were 1.03%±0.08%, 1.96%±0.17%, 4.35%±0.23%, and 1.50%±0.28%, respectively. Castings were covered by only small amounts of mold materials. The hardness test showed no significant differences between castings from B and the ones from commercial investments. The experimental special mixing liquid effectively reduced the water/powder ratio and improved the strength and thermal expansion.

  4. Effects of dicarbonyl trapping agents, antioxidants, and reducing agents on the formation of furan and other volatile components in canned-coffee model systems.

    Science.gov (United States)

    Zheng, Li Wei; Chung, Hyun; Kim, Young-Suk

    2015-09-01

    The formation of furan and certain volatiles related to furan formation mechanisms was studied using gas chromatography-mass spectrometry combined with solid-phase micro extraction after adding dicarbonyl trapping agents [epicatechin (EC), epigallocatechin gallate (EGCG), and catechin], water-soluble antioxidants (Trolox, caffeic acid, ferulic acid, and chlorogenic acid), fat-soluble antioxidants (α-tocopherol, BHT, and β-carotene), and reducing agents (glutathione and sodium sulfite) to canned-coffee model systems (CMS). The level of furan formation decreased significantly following the addition of EC (by 65.3%), EGCG (by 60.0%), and catechin (by 44.7%). In addition, the formation of Maillard reaction products, including furan derivatives (furfural and 5-methylfurfural), Strecker aldehyde (2-methylbutanal), pyrazines (2,6-dimethylpyrazine), and lipid oxidation products (including hexanal and 2-pentylfuran) was suppressed when any of the dicarbonyl trapping agents was added. Among the water-soluble antioxidants studied, chlorogenic acid most significantly decreased the furan level, by 67.0%, followed by ferulic acid (57.6%), Trolox (50.1%), and caffeic acid (48.2%) in the CMS. Chlorogenic acid also reduced the formation of furfural and lipid oxidation products. However, the addition of caffeic acid, ferulic acid, and chlorogenic acid decreased the generation of key coffee aroma components, such as Strecker aldehydes (2-methylpropanal and 2-methylbutanal), 5-methylfurfural, and pyrazines (2,6-dimethylpyrazine and 2-ethyl-5-methylpyrazine). Among the fat-soluble antioxidants, BHT and α-tocopherol decreased the furan level by 49.3% and 39.3%, respectively, while β-carotene increased the furan level by 34.8%. The addition of sodium sulfite and glutathione to CMS also led to considerable reductions in furan, of 64.1% and 44.9%, respectively. Copyright © 2015 Elsevier Ltd. All rights reserved.

  5. Research on environmental impact of water-based fire extinguishing agents

    Science.gov (United States)

    Wang, Shuai

    2018-02-01

    This paper offers current status of application of water-based fire extinguishing agents, the environmental and research considerations of the need for the study of toxicity research. This paper also offers systematic review of test methods of toxicity and environmental impact of water-based fire extinguishing agents currently available, illustrate the main requirements and relevant test methods, and offer some research findings for future research considerations. The paper also offers limitations of current study.

  6. A water market simulator considering pair-wise trades between agents

    Science.gov (United States)

    Huskova, I.; Erfani, T.; Harou, J. J.

    2012-04-01

    In many basins in England no further water abstraction licences are available. Trading water between water rights holders has been recognized as a potentially effective and economically efficient strategy to mitigate increasing scarcity. A screening tool that could assess the potential for trade through realistic simulation of individual water rights holders would help assess the solution's potential contribution to local water management. We propose an optimisation-driven water market simulator that predicts pair-wise trade in a catchment and represents its interaction with natural hydrology and engineered infrastructure. A model is used to emulate licence-holders' willingness to engage in short-term trade transactions. In their simplest form agents are represented using an economic benefit function. The working hypothesis is that trading behaviour can be partially predicted based on differences in marginal values of water over space and time and estimates of transaction costs on pair-wise trades. We discuss the further possibility of embedding rules, norms and preferences of the different water user sectors to more realistically represent the behaviours, motives and constraints of individual licence holders. The potential benefits and limitations of such a social simulation (agent-based) approach is contrasted with our simulator where agents are driven by economic optimization. A case study based on the Dove River Basin (UK) demonstrates model inputs and outputs. The ability of the model to suggest impacts of water rights policy reforms on trading is discussed.

  7. Research on monitoring system of water resources in irrigation region based on multi-agent

    International Nuclear Information System (INIS)

    Zhao, T H; Wang, D S

    2012-01-01

    Irrigation agriculture is the basis of agriculture and rural economic development in China. Realizing the water resource information of irrigated area will make full use of existing water resource and increase benefit of irrigation agriculture greatly. However, the water resource information system of many irrigated areas in our country is not still very sound at present, it lead to the wasting of a lot of water resources. This paper has analyzed the existing water resource monitoring system of irrigated areas, introduced the Multi-Agent theories, and set up a water resource monitoring system of irrigated area based on multi-Agent. This system is composed of monitoring multi-Agent federal, telemetry multi-Agent federal, and the Communication Network GSM between them. It can make full use of good intelligence and communication coordination in the multi-Agent federation interior, improve the dynamic monitoring and controlling timeliness of water resource of irrigated area greatly, provide information service for the sustainable development of irrigated area, and lay a foundation for realizing high information of water resource of irrigated area.

  8. An agent-based model for water management and planning in the Lake Naivasha basin, Kenya

    Science.gov (United States)

    van Oel, Pieter; Mulatu, Dawit; Odongo, Vincent; Onyando, Japheth; Becht, Robert; van der Veen, Anne

    2013-04-01

    A variety of human and natural processes influence the ecological and economic state of the Lake Naivasha basin. The ecological wealth and recent economic developments in the area are strongly connected to Lake Naivasha which supports a rich variety of flora, mammal and bird species. Many human activities depend on clean freshwater from the lake whereas recently the freshwater availability of good quality is seriously influenced by water abstractions and the use of fertilizers in agriculture. Management alternatives include those aiming at limiting water abstractions and fertilizer use. A possible way to achieve reduced use of water and fertilizers is the introduction of Payment for Environmental Services (PES) schemes. As the Lake Naivasha basin and its population have experienced increasing pressures various disputes and disagreements have arisen about the processes responsible for the problems experienced, and the effectively of management alternatives. Beside conflicts of interest and disagreements on responsibilities there are serious factual disagreements. To share scientific knowledge on the effects of the socio-ecological system processes on the Lake Naivasha basin, tools may be used that expose information at temporal and spatial scales that are meaningful to stakeholders. In this study we use a spatially-explicit agent-based modelling (ABM) approach to depict the interactions between socio-economic and natural subsystems for supporting a more sustainable governance of the river basin resources. Agents consider alternative livelihood strategies and decide to go for the one they perceive as likely to be most profitable. Agents may predict and sense the availability of resources and also can observe economic performance achieved by neighbouring agents. Results are presented at the basin and subbasin level to provide relevant knowledge to Water Resources Users Associations which are important collective forums for water management through which PES schemes

  9. Effect of Gum Arabic Karroo as a water-reducing admixture in cement mortar

    Directory of Open Access Journals (Sweden)

    Rose Mbugua

    2016-12-01

    Full Text Available The aim of this study was to develop Gum Acacia Karroo (GAK as set retarding-water reducing admixture in cement mortars. Retarding admixtures are used to counter effect the accelerated hydration of cement at elevated temperatures by slowing down the retarding process especially during the day when concreting work is done. However most retarding admixtures available in the market are expensive, thereby making them out of reach for small consumers of concrete in Africa are expensive and not readily available. GAK, which contains soluble sugars, was investigated as a set-retarding water reducing-admixture. Setting time was measured in cement pastes with different dosages of GAK and a commercial retarding agent (Tard CE. Compressive strength, bleeding and flow test were investigated on cement mortars with the control being cement mortar without admixture. GAK was found to increase final setting time by 6 h above control. Compressive strength increased when water cement ratio was reduced from 0.5 to 0.4. Thermogravimetric analysis revealed increased dosage of GAK reduced hydration rate.

  10. An agent-based hydroeconomic model to evaluate water policies in Jordan

    Science.gov (United States)

    Yoon, J.; Gorelick, S.

    2014-12-01

    Modern water systems can be characterized by a complex network of institutional and private actors that represent competing sectors and interests. Identifying solutions to enhance water security in such systems calls for analysis that can adequately account for this level of complexity and interaction. Our work focuses on the development of a hierarchical, multi-agent, hydroeconomic model that attempts to realistically represent complex interactions between hydrologic and multi-faceted human systems. The model is applied to Jordan, one of the most water-poor countries in the world. In recent years, the water crisis in Jordan has escalated due to an ongoing drought and influx of refugees from regional conflicts. We adopt a modular approach in which biophysical modules simulate natural and engineering phenomena, and human modules represent behavior at multiple scales of decision making. The human modules employ agent-based modeling, in which agents act as autonomous decision makers at the transboundary, state, organizational, and user levels. A systematic nomenclature and conceptual framework is used to characterize model agents and modules. Concepts from the Unified Modeling Language (UML) are adopted to promote clear conceptualization of model classes and process sequencing, establishing a foundation for full deployment of the integrated model in a scalable object-oriented programming environment. Although the framework is applied to the Jordanian water context, it is generalizable to other regional human-natural freshwater supply systems.

  11. Grafted natural polymer as new drag reducing agent: An experimental approach

    Directory of Open Access Journals (Sweden)

    Abdulbari Hayder A.

    2012-01-01

    Full Text Available The present investigation introduces a new natural drag reducing agent which has the ability to improve the flow in pipelines carrying aqueous or hydrocarbon liquids in turbulent flow. Okra (Abelmoschus esculentus mucilage drag reduction performance was tested in water and hydrocarbon (gas-oil media after grafting. The drag reduction test was conducted in a buildup closed loop liquid circulation system consists of two pipes 0.0127 and 0.0381 m Inside Diameter (ID, four testing sections in each pipe (0.5 to 2.0 m, tank, pump and pressure transmitters. Reynolds number (Re, additive concentration and the transported media type (water and gas-oil, were the major drag reduction variables investigated. The experimental results show that, new additive drag reduction ability is high with maximum percentage of drag reduction (%Dr up to 60% was achieved. The experimental results showed that the drag reduction ability increased by increasing the additive concentration. The %Dr was found to increase by increasing the Re by using the water-soluble additive while it was found to decrease by increasing the Re when using the oil-soluble additive. The %Dr was higher in the 0.0381 m ID pipe. Finally, the grafted and natural mucilage showed high resistance to shear forces when circulated continuously for 200 seconds in the closed-loop system.

  12. Ginkgo biloba: a natural reducing agent for the synthesis of cytocompatible graphene

    Directory of Open Access Journals (Sweden)

    Gurunathan S

    2014-01-01

    Full Text Available Sangiliyandi Gurunathan, Jae Woong Han, Jung Hyun Park, Vasuki Eppakayala, Jin-Hoi Kim Department of Animal Biotechnology, Konkuk University, Seoul, South Korea Background: Graphene is a novel two-dimensional planar nanocomposite material consisting of rings of carbon atoms with a hexagonal lattice structure. Graphene exhibits unique physical, chemical, mechanical, electrical, elasticity, and cytocompatible properties that lead to many potential biomedical applications. Nevertheless, the water-insoluble property of graphene restricts its application in various aspects of biomedical fields. Therefore, the objective of this work was to find a novel biological approach for an efficient method to synthesize water-soluble and cytocompatible graphene using Ginkgo biloba extract (GbE as a reducing and stabilizing agent. In addition, we investigated the biocompatibility effects of graphene in MDA-MB-231 human breast cancer cells. Materials and methods: Synthesized graphene oxide (GO and GbE-reduced GO (Gb-rGO were characterized using various sequences of techniques: ultraviolet-visible (UV-vis spectroscopy, Fourier-transform infrared spectroscopy (FTIR, dynamic light scattering (DLS, scanning electron microscopy (SEM, atomic force microscopy (AFM, and Raman spectroscopy. Biocompatibility of GO and Gb-rGO was assessed in human breast cancer cells using a series of assays, including cell viability, apoptosis, and alkaline phosphatase (ALP activity. Results: The successful synthesis of graphene was confirmed by UV-vis spectroscopy and FTIR. DLS analysis was performed to determine the average size of GO and Gb-rGO. X-ray diffraction studies confirmed the crystalline nature of graphene. SEM was used to investigate the surface morphologies of GO and Gb-rGO. AFM was employed to investigate the morphologies of prepared graphene and the height profile of GO and Gb-rGO. The formation of defects in Gb-rGO was confirmed by Raman spectroscopy. The biocompatibility

  13. Formamidine sulfinic acid as reducing agent in technetium-99m rhenium sulfide labelling

    Energy Technology Data Exchange (ETDEWEB)

    Neves, M; Patricio, L [Laboratorio Nacional de Engenharia e Technologia Industrial, Sacavem (Portugal). Dept. de Radioisotopes; Ferronha, H [Laboratorio Nacional de Investigacao Veterinaria, Lisboa (Portugal)

    1989-08-01

    Labelling kinetic studies, radiochemical characterization and particle size evaluation of {sup 99m}Tc rhenium sulfide colloid using formamidine sulfinic acid as reducing agent are described. Comparison with the same colloid which makes use of Sn-sodium pyrophosphate complex as reducing agent showed higher labelling yields, simplification of labelling procedure and a longer shelf life when formamidine sulfinic acid was used. (author) 15 refs.; 7 figs.

  14. Development and Performance Assessment of the High-Performance Shrinkage Reducing Agent for Concrete

    Directory of Open Access Journals (Sweden)

    Hyung Sub Han

    2016-01-01

    Full Text Available To develop a high-performance shrinkage reducing agent, this study investigated several shrinkage reducing materials and supplements for those materials. Fluidity and air content were satisfactory for the various shrinkage reducing materials. The decrease in viscosity was the lowest for glycol-based materials. The decrease in drying shrinkage was most prominent for mixtures containing glycol-based materials. In particular, mixtures containing G2 achieved a 40% decrease in the amount of drying shrinkage. Most shrinkage reducing materials had weaker level of compressive strength than that of the plain mixture. When 3% triethanolamine was used for early strength improvement, the strength was enhanced by 158% compared to that of the plain mixture on day 1; enhancement values were 135% on day 7 and 113% on day 28. To assess the performance of the developed high-performance shrinkage reducing agent and to determine the optimal amount, 2.0% shrinkage reducing agent was set as 40% of the value of the plain mixture. While the effect was more prominent at higher amounts, to prevent deterioration of the compressive strength and the other physical properties, the recommended amount is less than 2.0%.

  15. Thickening agent for flood water in secondary recovery of oil and for other aqueous salt solutions

    Energy Technology Data Exchange (ETDEWEB)

    Roth, H H

    1966-04-14

    Alkenyl-aromatic polymer sulfonates are good thickeners for some aqueous solutions, but addition of salts to such solutions reduces the desirable viscosity. High-molecular, water-soluble alkenyl-aromatic polymers which carry sulfonic acid or sulfonate groups substituted at the aromatic nuclei yield thickened solutions (e.g., for waterflooding) which are not influenced by the presence of water-soluble salts. Such polymers are derivatives of polyvinyltoluene, alone or in combination with about 5% acrylonitrile. It was also found that such thickening agents are less adsorbed on the rock matrix in a waterflood formation. (1 claim)

  16. Integrating the simulation of domestic water demand behaviour to an urban water model using agent based modelling

    Science.gov (United States)

    Koutiva, Ifigeneia; Makropoulos, Christos

    2015-04-01

    The urban water system's sustainable evolution requires tools that can analyse and simulate the complete cycle including both physical and cultural environments. One of the main challenges, in this regard, is the design and development of tools that are able to simulate the society's water demand behaviour and the way policy measures affect it. The effects of these policy measures are a function of personal opinions that subsequently lead to the formation of people's attitudes. These attitudes will eventually form behaviours. This work presents the design of an ABM tool for addressing the social dimension of the urban water system. The created tool, called Urban Water Agents' Behaviour (UWAB) model, was implemented, using the NetLogo agent programming language. The main aim of the UWAB model is to capture the effects of policies and environmental pressures to water conservation behaviour of urban households. The model consists of agents representing urban households that are linked to each other creating a social network that influences the water conservation behaviour of its members. Household agents are influenced as well by policies and environmental pressures, such as drought. The UWAB model simulates behaviour resulting in the evolution of water conservation within an urban population. The final outcome of the model is the evolution of the distribution of different conservation levels (no, low, high) to the selected urban population. In addition, UWAB is implemented in combination with an existing urban water management simulation tool, the Urban Water Optioneering Tool (UWOT) in order to create a modelling platform aiming to facilitate an adaptive approach of water resources management. For the purposes of this proposed modelling platform, UWOT is used in a twofold manner: (1) to simulate domestic water demand evolution and (2) to simulate the response of the water system to the domestic water demand evolution. The main advantage of the UWAB - UWOT model

  17. Limonene and tetrahydrofurfuryl alcohol cleaning agent

    Science.gov (United States)

    Bohnert, George W.; Carter, Richard D.; Hand, Thomas E.; Powers, Michael T.

    1996-05-07

    The present invention is a tetrahydrofurfuryl alcohol and limonene or terpineol cleaning agent and method for formulating and/or using the cleaning agent. This cleaning agent effectively removes both polar and nonpolar contaminants from various electrical and mechanical parts and is readily used without surfactants, thereby reducing the need for additional cleaning operations. The cleaning agent is warm water rinsable without the use of surfactants. The cleaning agent can be azeotropic, enhancing ease of use in cleaning operations and ease of recycling.

  18. Limonene and tetrahydrofurfurly alcohol cleaning agent

    Science.gov (United States)

    Bohnert, George W.; Carter, Richard D.; Hand, Thomas E.; Powers, Michael T.

    1997-10-21

    The present invention is a tetrahydrofurfuryl alcohol and limonene cleaning agent and method for formulating and/or using the cleaning agent. This cleaning agent effectively removes both polar and nonpolar contaminants from various electrical and mechanical parts and is readily used without surfactants, thereby reducing the need for additional cleaning operations. The cleaning agent is warm water rinsable without the use of surfactants. The cleaning agent can be azeotropic, enhancing ease of use in cleaning operations and ease of recycling.

  19. Effects of Shrinkage Reducing Agent and Expansive Admixture on the Volume Deformation of Ultrahigh Performance Concrete

    OpenAIRE

    Anshuang, Su; Ling, Qin; Shoujie, Zhang; Jiayang, Zhang; Zhaoyu, Li

    2017-01-01

    This paper investigated the influences of shrinkage reducing agent and expansive admixture on autogenous and drying shrinkage of ultrahigh performance concrete (UHPC) containing antifoaming admixture. The shrinkage reducing agent was used at dosage of 0.5%, 1%, and 2% and the expansive admixture was used at dosage of 2% to 4% by mass of cementitious material. The results show that the air content of UHPC increases with the higher addition of shrinkage reducing agent and expansive admixtures. ...

  20. The combination of sodium perborate and water as intracoronal teeth bleaching agent

    Directory of Open Access Journals (Sweden)

    Ananta Tantri Budi

    2008-12-01

    Full Text Available Background: The color change on post-endodontic treated teeth can be overcome by intracoronal tooth bleaching using walking bleach. Some agents used in walking bleach are combination of sodium peroxide and hydrogen peroxide, and combination of sodium perborate and water. Purpose: The objective of this review is to provide information and consideration of using safe and effective bleaching agents in the field of dentistry. Reviews: On one side, the use of sodium perborate and water combination does not cause the reduction of dentin hardness, enamel decay, and root resorbtion. On the other side, the use of sodium perborate and 30% hydrogen peroxide combination indicates that it takes longer time in yielding the proper color of teeth. Conclusion: The use of sodium perborate and water combination as bleaching agents is effective and safe.

  1. Alkalisation agent measurement with differential conductivity method in secondary water system

    International Nuclear Information System (INIS)

    Wuhrmann, Peter; Lendi, Marco

    2012-09-01

    Besides ammonia hydroxide, also morpholine and ethanol-amine (ETA) are mainly used as a pH regulating agent on the secondary water side [1]. The concentration of the alkalisation agent can only be calculated if the chemical composition in the sample is known [2]. Therefore, for a reliable alkalisation agent measurement, there are three major steps to take: A reliable specific and (degassed) acid conductivity measurement, pH calculation and the selection of the chemical model for concentration calculation of the alkalisation agent (authors)

  2. Design of a multi-agent hydroeconomic model to simulate a complex human-water system: Early insights from the Jordan Water Project

    Science.gov (United States)

    Yoon, J.; Klassert, C. J. A.; Lachaut, T.; Selby, P. D.; Knox, S.; Gorelick, S.; Rajsekhar, D.; Tilmant, A.; Avisse, N.; Harou, J. J.; Gawel, E.; Klauer, B.; Mustafa, D.; Talozi, S.; Sigel, K.

    2015-12-01

    Our work focuses on development of a multi-agent, hydroeconomic model for purposes of water policy evaluation in Jordan. The model adopts a modular approach, integrating biophysical modules that simulate natural and engineered phenomena with human modules that represent behavior at multiple levels of decision making. The hydrologic modules are developed using spatially-distributed groundwater and surface water models, which are translated into compact simulators for efficient integration into the multi-agent model. For the groundwater model, we adopt a response matrix method approach in which a 3-dimensional MODFLOW model of a complex regional groundwater system is converted into a linear simulator of groundwater response by pre-processing drawdown results from several hundred numerical simulation runs. Surface water models for each major surface water basin in the country are developed in SWAT and similarly translated into simple rainfall-runoff functions for integration with the multi-agent model. The approach balances physically-based, spatially-explicit representation of hydrologic systems with the efficiency required for integration into a complex multi-agent model that is computationally amenable to robust scenario analysis. For the multi-agent model, we explicitly represent human agency at multiple levels of decision making, with agents representing riparian, management, supplier, and water user groups. The agents' decision making models incorporate both rule-based heuristics as well as economic optimization. The model is programmed in Python using Pynsim, a generalizable, open-source object-oriented code framework for modeling network-based water resource systems. The Jordan model is one of the first applications of Pynsim to a real-world water management case study. Preliminary results from a tanker market scenario run through year 2050 are presented in which several salient features of the water system are investigated: competition between urban and

  3. Decontamination of chemical agents from drinking water infrastructure: a literature review and summary.

    Science.gov (United States)

    Szabo, Jeff; Minamyer, Scott

    2014-11-01

    This report summarizes the current state of knowledge on the persistence of chemical contamination on drinking water infrastructure (such as pipes) along with information on decontamination should persistence occur. Decontamination options for drinking water infrastructure have been explored for some chemical contaminants, but important data gaps remain. In general, data on chemical persistence on drinking water infrastructure is available for inorganics such as arsenic and mercury, as well as select organics such as petroleum products, pesticides and rodenticides. Data specific to chemical warfare agents and pharmaceuticals was not found and data on toxins is scant. Future research suggestions focus on expanding the available chemical persistence data to other common drinking water infrastructure materials. Decontaminating agents that successfully removed persistent contamination from one infrastructure material should be used in further studies. Methods for sampling or extracting chemical agents from water infrastructure surfaces are needed. Published by Elsevier Ltd.

  4. Research on monitoring system of water resources in Shiyang River Basin based on Multi-agent

    Science.gov (United States)

    Zhao, T. H.; Yin, Z.; Song, Y. Z.

    2012-11-01

    The Shiyang River Basin is the most populous, economy relatively develop, the highest degree of development and utilization of water resources, water conflicts the most prominent, ecological environment problems of the worst hit areas in Hexi inland river basin in Gansu province. the contradiction between people and water is aggravated constantly in the basin. This text combines multi-Agent technology with monitoring system of water resource, the establishment of a management center, telemetry Agent Federation, as well as the communication network between the composition of the Shiyang River Basin water resources monitoring system. By taking advantage of multi-agent system intelligence and communications coordination to improve the timeliness of the basin water resources monitoring.

  5. Research on monitoring system of water resources in Shiyang River Basin based on Multi-agent

    International Nuclear Information System (INIS)

    Zhao, T h; Yin, Z; Song, Y Z

    2012-01-01

    The Shiyang River Basin is the most populous, economy relatively develop, the highest degree of development and utilization of water resources, water conflicts the most prominent, ecological environment problems of the worst hit areas in Hexi inland river basin in Gansu province. the contradiction between people and water is aggravated constantly in the basin. This text combines multi-Agent technology with monitoring system of water resource, the establishment of a management center, telemetry Agent Federation, as well as the communication network between the composition of the Shiyang River Basin water resources monitoring system. By taking advantage of multi-agent system intelligence and communications coordination to improve the timeliness of the basin water resources monitoring.

  6. Evaluation of water security in Jordan using a multi-agent, hydroeconomic model: Initial model results from the Jordan Water Project

    Science.gov (United States)

    Yoon, J.; Klassert, C. J. A.; Lachaut, T.; Selby, P. D.; Knox, S.; Gorelick, S.; Rajsekhar, D.; Tilmant, A.; Avisse, N.; Harou, J. J.; Medellin-Azuara, J.; Gawel, E.; Klauer, B.; Mustafa, D.; Talozi, S.; Sigel, K.; Zhang, H.

    2016-12-01

    Our work focuses on development of a multi-agent, hydroeconomic model for water policy evaluation in Jordan. Jordan ranks among the most water-scarce countries in the world, a situation exacerbated due to a recent influx of refugees escaping the ongoing civil war in neighboring Syria. The modular, multi-agent model is used to evaluate interventions for enhancing Jordan's water security, integrating biophysical modules that simulate natural and engineered phenomena with human modules that represent behavior at multiple levels of decision making. The hydrologic modules are developed using spatially-distributed groundwater and surface water models, which are translated into compact simulators for efficient integration into the multi-agent model. For the multi-agent model, we explicitly account for human agency at multiple levels of decision making, with agents representing riparian, management, supplier, and water user groups. Human agents are implemented as autonomous entities in the model that make decisions in relation to one another and in response to hydrologic and socioeconomic conditions. The integrated model is programmed in Python using Pynsim, a generalizable, open-source object-oriented software framework for modeling network-based water resource systems. The modeling time periods include historical (2006-2014) and future (present-2050) time spans. For the historical runs, the model performance is validated against historical data for several observations that reflect the interacting dynamics of both the hydrologic and human components of the system. A historical counterfactual scenario is also constructed to isolate and identify the impacts of the recent Syrian civil war and refugee crisis on Jordan's water system. For the future period, model runs are conducted to evaluate potential supply, demand, and institutional interventions over a wide range of plausible climate and socioeconomic scenarios. In addition, model sensitivity analysis is conducted

  7. Color stabilization of porcine hemoglobin during spray-drying and powder storage by combining chelating and reducing agents.

    Science.gov (United States)

    Salvador, P; Toldrà, M; Parés, D; Carretero, C; Saguer, E

    2009-10-01

    This work focuses on the effects of adding a chelating agent - such as nicotinic acid (NA, 2% w/v) or nicotinamide (Nam, 2.5% w/v) - along with glucose as a reducing agent (G, 10% w/v) to fresh porcine hemoglobin in order to stabilize its red color during spray-drying and powder storage at room temperature. Correlations between the CIELAB color parameters and the relative percentages of the different hemoglobin derivatives (liganded and deliganded ferrohemoglobin, and methemoglobin) were analyzed. The results indicate that, although little effects could be observed for any of the combined treatments on fresh hemoglobin, they were effective against pigment autoxidation during dehydration and subsequent storage. From the results, it can also be concluded that glucose was the main contributor to the color stabilization of the hemoglobin powder, probably due to its high water retention capacity.

  8. Lipoxygenase independent hexanal formation in isolated soy proteins induced by reducing agents.

    Science.gov (United States)

    Lei, Q; Boatright, W L

    2008-08-01

    Compared to corresponding controls, 6.5 mM dithiothreitol (DTT) elevated headspace hexanal level over aqueous slurries of both commercial isolated soy proteins (ISP) and laboratory ISP prepared with 80 degrees C treatment. Further analysis revealed that lipoxygenase (LOX) activity was not detected from these ISP, indicating that LOX is not involved in the observed hexanal increase. Levels of the induced headspace hexanal over the ISP aqueous slurries were proportional to the amount of DTT added in the range of 0 to 65 mM. Subsequent systematic investigations with model systems revealed that iron was required for the reducing agent-induced hexanal formation from linoleic acid. Erythorbate, another reducing agent, can also induce hexanal formation in both ISP and model systems. As a comparison, the LOX activity and hexanal synthesis in defatted soy flour were examined. The corresponding results showed that defatted soy flour maintained high LOX activities and that hexanal synthesis in such sample was significantly inhibited by high concentration DTT (above 130 mM). Data from the current investigation demonstrate the existence of LOX independent hexanal formation induced by reducing agents in ISP and the potential requirement of iron as a catalyst.

  9. Decontamination of radiological agents from drinking water infrastructure: a literature review and summary.

    Science.gov (United States)

    Szabo, Jeff; Minamyer, Scott

    2014-11-01

    This report summarizes the current state of knowledge on the persistence of radiological agents on drinking water infrastructure (such as pipes) along with information on decontamination should persistence occur. Decontamination options for drinking water infrastructure have been explored for some important radiological agents (cesium, strontium and cobalt), but important data gaps remain. Although some targeted experiments have been published on cesium, strontium and cobalt persistence on drinking water infrastructure, most of the data comes from nuclear clean-up sites. Furthermore, the studies focused on drinking water systems use non-radioactive surrogates. Non-radioactive cobalt was shown to be persistent on iron due to oxidation with free chlorine in drinking water and precipitation on the iron surface. Decontamination with acidification was an effective removal method. Strontium persistence on iron was transient in tap water, but adherence to cement-mortar has been demonstrated and should be further explored. Cesium persistence on iron water infrastructure was observed when flow was stagnant, but not with water flow present. Future research suggestions focus on expanding the available cesium, strontium and cobalt persistence data to other common infrastructure materials, specifically cement-mortar. Further exploration chelating agents and low pH treatment is recommended for future decontamination studies. Published by Elsevier Ltd.

  10. PVA stabilized gold nanoparticles by use of unexplored albeit conventional reducing agent

    Energy Technology Data Exchange (ETDEWEB)

    Khanna, P K [Nanomaterials Laboratory, Centre for Materials for Electronics Technology (C-MET), Panchwati, Off Pashan Road, Pune 411008 (India); Gokhale, R [Nanomaterials Laboratory, Centre for Materials for Electronics Technology (C-MET), Panchwati, Off Pashan Road, Pune 411008 (India); Subbarao, V V.V.S. [Nanomaterials Laboratory, Centre for Materials for Electronics Technology (C-MET), Panchwati, Off Pashan Road, Pune 411008 (India); Vishwanath, A Kasi [Nanomaterials Laboratory, Centre for Materials for Electronics Technology (C-MET), Panchwati, Off Pashan Road, Pune 411008 (India); Das, B K [Nanomaterials Laboratory, Centre for Materials for Electronics Technology (C-MET), Panchwati, Off Pashan Road, Pune 411008 (India); Satyanarayana, C V.V. [National Chemical Laboratory, Pashan Road, Pune 41108 (India)

    2005-07-15

    Poly(vinyl alcohol) (PVA) stabilized gold nanoparticles have been prepared in aqueous medium using two different reducing viz.; hydrazine hydrate, a stronger reducing agent and sodium formaldehydesulfoxylate (SFS), a slightly weaker reducing agent. SFS is used for first ever time for reduction of gold metal salt. The PVA stabilized gold nanoparticles solutions are wine red to blood red coloured and are stable over a long period of time with no indication of aggregation. The solution shows strong visible light absorptions in the range of 520-540 nm, characteristics of gold nanoparticles. Powder X-ray diffraction patterns of freshly prepared films containing gold nanoparticles indicated particles size to be about 15 nm. Transmission electron microscopy (TEM) of a more than two-week-old sample revealed well-defined non-agglomerated spherical particles of about 50 nm diameter in solutions.

  11. PVA stabilized gold nanoparticles by use of unexplored albeit conventional reducing agent

    International Nuclear Information System (INIS)

    Khanna, P.K.; Gokhale, R.; Subbarao, V.V.V.S.; Vishwanath, A. Kasi; Das, B.K.; Satyanarayana, C.V.V.

    2005-01-01

    Poly(vinyl alcohol) (PVA) stabilized gold nanoparticles have been prepared in aqueous medium using two different reducing viz.; hydrazine hydrate, a stronger reducing agent and sodium formaldehydesulfoxylate (SFS), a slightly weaker reducing agent. SFS is used for first ever time for reduction of gold metal salt. The PVA stabilized gold nanoparticles solutions are wine red to blood red coloured and are stable over a long period of time with no indication of aggregation. The solution shows strong visible light absorptions in the range of 520-540 nm, characteristics of gold nanoparticles. Powder X-ray diffraction patterns of freshly prepared films containing gold nanoparticles indicated particles size to be about 15 nm. Transmission electron microscopy (TEM) of a more than two-week-old sample revealed well-defined non-agglomerated spherical particles of about 50 nm diameter in solutions

  12. Evaluation of policy measures and methods to reduce diffuse water pollution

    Energy Technology Data Exchange (ETDEWEB)

    Lange, Ute; Doehler, Helmut; Eurich-Menden, Brigitte; Goemann, Horst; Jaeger, Peter; Kreins, Peter; Moeller, Christine; Prigge, Achim; Ristenpart, Erik; Schultheiss, Ute

    2006-11-15

    After considerable improvements of wastewater treatment, the loads of nutrients and plant protection agents, deriving from agriculture and heavy metals from urban drainages effluents as well as from erosion of agricultural soils are the main sources of nutrients and harmful substances in the loads of water bodies. The targets of the project were on the one hand the analysis of the political and legislative framework of both policy fields and on the other hand the evaluation of several, selected water protection measures with regard to their contribution to reduce water pollution, their economical effects as well as their political enforceability. The focus was laid on diffuse water pollution caused by agriculture. As main reasons for the diffuse water pollution stagnating at high level, the analysis of the political framework identified a lack of implementation discipline of water law, followed by the fragmented and insufficient water protection legislation itself and the previous design of the common agricultural policy slanted towards increasing productivity. For the future co-operation of agricultural and water authorities in implementation of their reforms and better definition of 'Good Farming Practice' are recommended. The second investigation level focuses on the analysis and assessment of selected measures to reduce the input of nutrients and plant protection agents. This part was done with help of calculation models focussing on the specific cost/benefit ratios for water protection. In detail the following measures have been analysed: decoupling of direct payments, coupling of livestock farming to areas, tax on mineral nitrogen, pesticide levy, buffer stripes alongside of watercourses, all season crop cover on arable land, soil cultivation procedures, changing the use of arable land, optimisation of animal nutrition, optimisation of manure storage and application, co-operative agreements, education and training. Co-operations and water protection

  13. Effect of reducing agent strength on the growth and thermoelectric performance of nanocrystalline bismuth telluride

    Science.gov (United States)

    Nour, Asmaa; Hassan, Nazly; Refaat, Heba M.; Soliman, Hesham M. A.; El-Dissouky, A.

    2018-03-01

    A novel combination of Trizma, as an environmentally friendly chelating agent, with either weak or strong reducing agent was used to produce n-type bismuth telluride (Bi2Te3) nanocrystals via water-based chemical route. The synthesized powders were consolidated into pellets utilizing spark plasma sintering (SPS). The sintered n-type pellets exhibited potentially high electrical conductivities (5.29 × 105 and 5.23 × 105 S.m‑1) and low lattice thermal conductivities (0.12 and 0.25 Wm‑1K‑1) respectively. These thermoelectric (TE) properties suggested that the partially coherent boundaries permitted significant phonons scattering and electrons transfer. These led to an enhanced figure-of-merit (ZT) values (0.52 and 0.97), which are considered to be significant among the reported ZT values at room-temperature for the undoped synthesized n-type Bi2Te3 nanoparticles. Therefore, the current investigation displayed an efficient method to improve ZT of TE materials via nanostructure orchestrating, resulting in a worthy candidate n-type nanostructured Bi2Te3 for room-temperature TE applications.

  14. Effectiveness Of Different House-Hold Hand Washing Agents On ...

    African Journals Online (AJOL)

    Hand hygiene is a very important procedure in infection control. Washing agents commonly in use were investigated for their effectiveness in reducing hand floral and cotton towel was used as drying agent. Agents studied include; water alone, carex soap, dettol, and imperial leather. The hands were inoculated (deliberate ...

  15. Surface water flood risk and management strategies for London: An Agent-Based Model approach

    Directory of Open Access Journals (Sweden)

    Jenkins Katie

    2016-01-01

    Full Text Available Flooding is recognised as one of the most common and costliest natural disasters in England. Flooding in urban areas during heavy rainfall is known as ‘surface water flooding’, considered to be the most likely cause of flood events and one of the greatest short-term climate risks for London. In this paper we present results from a novel Agent-Based Model designed to assess the interplay between different adaptation options, different agents, and the role of flood insurance and the flood insurance pool, Flood Re, in the context of climate change. The model illustrates how investment in adaptation options could reduce London’s surface water flood risk, today and in the future. However, benefits can be outweighed by continued development in high risk areas and the effects of climate change. Flood Re is beneficial in its function to provide affordable insurance, even under climate change. However, it offers no additional benefits in terms of overall risk reduction, and will face increasing pressure due to rising surface water flood risk in the future. The modelling approach and findings are highly relevant for reviewing the proposed Flood Re scheme, as well as for wider discussions on the potential of insurance schemes, and broader multi-sectoral partnerships, to incentivise flood risk management in the UK and internationally.

  16. Lixiviation of plutonium contaminated solid wastes by aqueous solution of electro-generated reducing agents

    International Nuclear Information System (INIS)

    Agarande, Michelle

    1991-01-01

    This study concerns the development of the new concept for the decontamination of plutonium bearing solid wastes, based on the lixiviation of the wastes using electro-generated reducing agents. First, a comparative study of the kinetics of the dissolution of pure PuO 2 (prepared by calcination of Pu (IV) oxalate at 450 C) in sulfuric acid media, with different reducing agents, was realized. Qualitatively these reagents can be sorted in three groups: 1 / fast kinetics for Cr(II), V(II) and U(III); 2 / slow kinetics for Ti(III); 3 / very slow kinetics for V(III) and U(VI). In order to contribute to the design of an electrochemical reactor for the generation of the reducing agents usable for the lixiviation of plutonium bearing solid wastes, the study of the diffusion coefficients of both oxidized and reduced forms of different redox couples, at different temperatures, was undertaken. The results of this study also permits, from the knowledge of the diffusional activation energy of the ions, to conclude that the dissolution of pure plutonium dioxide under the action of these reducing agents is not diffusion limited. The feasibility of the plutonium decontamination treatment of synthetic or real solid wastes was then studied at laboratory scale using electro-generated V(II), which is with Cr(II) among the best reagents. The efficiency of the treatment was good, (80 pc Pu solubilisation yield), especially in the case of cellulosic or miscellaneous organic wastes. (author) [fr

  17. Impact of bleaching agents on water sorption and solubility of resin luting cements.

    Science.gov (United States)

    Torabi Ardakani, Mahshid; Atashkar, Berivan; Bagheri, Rafat; Burrow, Michael F

    2017-08-01

    The aim of the present study was to evaluate the effect of distilled water and home and office bleaching agents on the sorption and solubility of resin luting cements. A total of 18 disc-shaped specimens were prepared from each of four resin cements: G-CEM LinkAce, Panavia F, Rely X Unicem, and seT. Specimens were cured according to the manufacturers' instructions and randomly divided into three groups of six, where they were treated with either an office or home bleaching agent or immersed in distilled water (control). Water sorption and solubility were measured by weighing the specimens before and after immersion and desiccation. Data were analyzed using Pearson correlation coefficient, two-way analysis of variance (ANOVA) and Tukey's test. There was a significant, positive correlation between sorption and solubility. Two-way anova showed significant differences among all resin cements tested for either sorption or solubility. Water sorption and solubility of all cements were affected significantly by office bleaching, and even more by home bleaching agents. Sorption and solubility behavior of the studied cements were highly correlated and significantly affected by applying either office or home bleaching agents; seT showed the highest sorption and solubility, whereas Rely X Unicem revealed the lowest. © 2016 John Wiley & Sons Australia, Ltd.

  18. Partial Reduction of Esters to Aldehydes Using a Novel Modified Red-Al Reducing Agent

    Energy Technology Data Exchange (ETDEWEB)

    Shin, Won Kyu; Kang, Daehoon; An, Duk Keun [Kangwon National Univ., Chunchon (Korea, Republic of)

    2014-07-15

    We have developed a convenient alternative method for the synthesis of aldehydes from both aromatic and aliphatic esters in very good to excellent yields in the absence of any additives using a modified Red-Al that was easily prepared by reacting commercially available Red-Al with cis-2,6-dimethyl morpholine. The advantages of the present methodology are as follows: simple preparation procedure of the reducing agent, improved product yields, convenient reaction temperature, and short reaction times. Therefore, the new reagent has great potential to be a useful alternative partial reducing agent for the synthesis of aldehydes from esters in organic synthesis. Aldehydes are valuable building blocks and reactive intermediates in organic synthesis. The general and classical syntheses of aldehydes from esters involve reduction-oxidation and partial reduction using efficient partial reducing agents. Obviously, one-step partial reduction methods are more useful than two-step reduction-oxidation methods owing to their simplicity, and generality in organic synthesis.

  19. Sorbitol as an efficient reducing agent for laser-induced copper deposition

    Science.gov (United States)

    Kochemirovsky, V. A.; Logunov, L. S.; Safonov, S. V.; Tumkin, I. I.; Tver'yanovich, Yu. S.; Menchikov, L. G.

    2012-10-01

    We have pioneered in revealing the fact that sorbitol may be used as an efficient reducing agent in the process of laser-induced copper deposition from solutions; in this case, it is possible to obtain copper lines much higher quality than by using conventional formalin.

  20. Hydrodynamics and mass transfer deaeration of water on thermal power plants when used natural gas as a desorbing agent

    Science.gov (United States)

    Sharapov, V. I.; Kudryavtseva, E. V.

    2017-11-01

    The technology of low-temperature deaeration of water in thermal power plants was developed. It is proposed to use natural gas supplied to the furnace as desorbing agent in the deaerator instead steam or superheated water. Natural gas has low, often - negative temperature after reducing installs. At the same time, it contains virtually no corrosive gases, oxygen and carbon dioxide, thereby successfully may be used as a stripping agent in water deaeration. The calculation of the energy efficiency of the technology for a typical unit of CHP has shown that achieved a significant annual saving of fuel equivalent in the transition from the traditional method of deaeration of water in the low temperature deaeration. Hydrodynamic and mass transfer indicators were determined for the deaerator thermal power plants using as stripping medium natural gas supplied to the boiler burners. Theoretically required amount and the real specific consumption of natural gas were estimated for deaeration of water standard quality. The calculation of the hydrodynamic characteristics was presented for jet-bubbling atmospheric deaerator with undescended perforated plate when operating on natural gas. The calculation shows the possibility of using commercially available atmospheric deaerators for the application of the new low-temperature water deaeration technology.

  1. Effect of color removal agent on textiles waste water

    International Nuclear Information System (INIS)

    Khomsaton Abu Bakar; Selambakknu, Sarala; Jamaliah Shariff; Ting, Teo Ming; Khairul Zaman Dahlan

    2010-01-01

    The effect of color removal agent (CRA) on textile waste water has been studied. The aim of this work is to determine the optimum condition for CRA to react on the textile waste water and to see the effect of CRA on waste water with different Chemical Oxygen Demand. 8 ml CRA was used to treat 800 mls of sample with various COD ranging between 2500 mg/ l-500 mg/ l. The results showed that CRA totally remove the colour of textile waste water at pH ranging from 6 to 8. At an optimum condition CRA works efficiently on waste water with COD 2300 mg/ l for reduction of suspended solid and turbidity. It also observed, sludge accumulation was depended on COD concentration. Color removal curves for different initial COD concentration also obtained. (author)

  2. Improvement of water treatment pilot plant with Moringa oleifera extract as flocculant agent.

    Science.gov (United States)

    Beltrán-Heredia, J; Sánchez-Martín, J

    2009-05-01

    Moringa oleifera extract is a high-capacity flocculant agent for turbidity removal in surface water treatment. A complete study of a pilot-plant installation has been carried out. Because of flocculent sedimentability of treated water, a residual turbidity occured in the pilot plant (around 30 NTU), which could not be reduced just by a coagulation-flocculation-sedimentation process. Because of this limitation, the pilot plant (excluded filtration) achieved a turbidity removal up to 70%. A slow sand filter was put in as a complement to installation. A clogging process was characterized, according to Carman-Kozeny's hydraulic hypothesis. Kozeny's k parameter was found to be 4.18. Through fouling stages, this k parameter was found to be up to 6.36. The obtained data are relevant for the design of a real filter in a continuous-feeding pilot plant. Slow sand filtration is highly recommended owing to its low cost, easy-handling and low maintenance, so it is a very good complement to Moringa water treatment in developing countries.

  3. The effects of water soluble contrast agents on the respiratory tract

    International Nuclear Information System (INIS)

    Lovett, I.; Donchey, S.; Doust, B.; Branson, J.; Munro, V.

    1989-01-01

    The water soluble contrast agents Gastrografin R (Sodium diatrizoate and meglumine diatrizoate, Schering, Berlin), Iopamiro 300 R (Iopamidol, Schering, Berlin), and Dionosil Aqueous R (propyliodone BP, Glaxo, England) were instilled into the tracheobronchial tree of rats in doses of either 0.1 ml and 0.25 ml. Rats being used as controls, underwent sham operations with the instillation of air instead of contrast agent. In all, 85 rats were used. All rats that had not already died from the effects of contrast agent were sacrificed 30 minutes after instillation. The relative effects of the contrast agents were measured by comparing: survival time; radiographic effects of the contrast agents on the lungs; and pathological changes as estimated by post mortem lung section and microscopy. The least toxic agent was the one with the lowest osmotic activity, namely Aqueous Dionosil. It is therefore recommended that Aqueous Dionosil be used in preference to Gastrografin or Iopamidol for studies of the oesophagus whenever there is a danger of aspiration of contrast agent into the tracheobronchial tree. 11 refs., 3 figs., 5 tabs

  4. Role of tin as a reducing agent in iron containing heat absorbing ...

    Indian Academy of Sciences (India)

    Unknown

    infrared region and a narrow weak band for Fe3+ ion at its λmax at around 380 nm was observed in the silicate glass. ... Tin reducing agent; iron heat absorption; silicate glass. 1. ... ing point of aluminium metal is far below than the glass.

  5. The church: asset and agent in achieving sustainable water supply ...

    African Journals Online (AJOL)

    Journal of Religion and Human Relations ... argues that the church as both asset and agent is most useful in conscientizing and transforming people to adopt a new mindset- a behavioral attitude required to halt the progression of environmental degradation in general and specifically improve urban water supply in Nigeria.

  6. System and method for regeneration and recirculation of a reducing agent using highly exothermic reactions induced by mixed industrial slags

    Science.gov (United States)

    Nakano, Jinichiro; Bennett, James P.; Nakano, Anna

    2017-12-12

    Embodiments relate to systems and methods for regenerating and recirculating a CO, H.sub.2 or combinations thereof utilized for metal oxide reduction in a reduction furnace. The reduction furnace receives the reducing agent, reduces the metal oxide, and generates an exhaust of the oxidized product. The oxidized product is transferred to a mixing vessel, where the oxidized product, a calcium oxide, and a vanadium oxide interact to regenerate the reducing agent from the oxidized product. The regenerated reducing agent is transferred back to the reduction furnace for continued metal oxide reductions.

  7. Labelling and Organ Distrbution Characterisics of 99mTc Galacturonate Complex Using Dithionite as Reducing Agent

    International Nuclear Information System (INIS)

    Al Hilli, A.M.; Mirza, K.S.; Al Noori, T.H.J.

    2000-01-01

    The labelling conditions of 99m T c-galacturonate complex using dithionite as reducing agent for periechnetate have been described. GCS-method has been applied for radiochemical determination of the labelled complex. At a constant amount of the ligand (50mg) in the preparation, high labelling of 99m Tc -galacturonate complex was obtained in the presence of the reducing agent. The effect of pH on the labelling yield have show that labelling occurs only at near neutral to slightly alkaline pH. The organ distribution results of 99m Tc -galacturonate complex as a function of the reducing agent concentration was achieved in rats. On using 8mg of dithionite as reducing agent,the activity uptake in the kindneys was significantly low, while in the bones was higher, but decreased after 1 hr. of injection. This,however is due to the instability of the labelled complex releasing pertechnetate which was evident by the increase of activity in the stomach. The organ distribution picture of the complex has been reversed by increasing the concentration of dithionite(16 mg) in the preparation,where the activity uptake in the kidnys was increased to higher level and in the bones was decreased.The activity in the stomach was rather low indicating a more stable complex towards oxidation or decomposition

  8. Can agent based models effectively reduce fisheries management implementation uncertainty?

    Science.gov (United States)

    Drexler, M.

    2016-02-01

    Uncertainty is an inherent feature of fisheries management. Implementation uncertainty remains a challenge to quantify often due to unintended responses of users to management interventions. This problem will continue to plague both single species and ecosystem based fisheries management advice unless the mechanisms driving these behaviors are properly understood. Equilibrium models, where each actor in the system is treated as uniform and predictable, are not well suited to forecast the unintended behaviors of individual fishers. Alternatively, agent based models (AMBs) can simulate the behaviors of each individual actor driven by differing incentives and constraints. This study evaluated the feasibility of using AMBs to capture macro scale behaviors of the US West Coast Groundfish fleet. Agent behavior was specified at the vessel level. Agents made daily fishing decisions using knowledge of their own cost structure, catch history, and the histories of catch and quota markets. By adding only a relatively small number of incentives, the model was able to reproduce highly realistic macro patterns of expected outcomes in response to management policies (catch restrictions, MPAs, ITQs) while preserving vessel heterogeneity. These simulations indicate that agent based modeling approaches hold much promise for simulating fisher behaviors and reducing implementation uncertainty. Additional processes affecting behavior, informed by surveys, are continually being added to the fisher behavior model. Further coupling of the fisher behavior model to a spatial ecosystem model will provide a fully integrated social, ecological, and economic model capable of performing management strategy evaluations to properly consider implementation uncertainty in fisheries management.

  9. The influence of reducing agents on the composition of technetium-99 complexes: implications for technetium-99m radiopharmaceutical preparation

    International Nuclear Information System (INIS)

    Baldas, J.; Bonnyman, J.; Pojer, P.M.; Williams, G.A.

    1981-05-01

    The use of hydrazine or formamidine sulphinic acid as reducing agents in the presence of 99 Tc-pertechnetate anion and the diethyldithiocarbamate ligand has been found to yield complexes containing Tc triple bond N and Tc=CO bonds respectively. The nitrido nitrogen atom and the carbon monoxide incorporated in these complexes as ligands originate from the reducing agents themselves. It is apparent that when reducing agents such as hydrazine or formamidine sulphinic acid are used in the preparation of Tc-99m-radiopharmaceuticals, the possibility of the formation of complexes structurally different to those obtained by use of stannous chloride must be considered

  10. Carbon quantum dots prepared with polyethyleneimine as both reducing agent and stabilizer for synthesis of Ag/CQDs composite for Hg{sup 2+} ions detection

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Ting; Dong, Jiang Xue; Liu, Shi Gang; Li, Na; Lin, Shu Min; Fan, Yu Zhu [Key Laboratory of Eco-environments in Three Gorges Reservoir Region (Ministry of Education), School of Chemistry and Chemical Engineering, Southwest University, No.2 Tiansheng Road, BeiBei District, Chongqing 400715 (China); Lei, Jing Lie [School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044 (China); Luo, Hong Qun, E-mail: luohq@swu.edu.cn [Key Laboratory of Eco-environments in Three Gorges Reservoir Region (Ministry of Education), School of Chemistry and Chemical Engineering, Southwest University, No.2 Tiansheng Road, BeiBei District, Chongqing 400715 (China); Li, Nian Bing, E-mail: linb@swu.edu.cn [Key Laboratory of Eco-environments in Three Gorges Reservoir Region (Ministry of Education), School of Chemistry and Chemical Engineering, Southwest University, No.2 Tiansheng Road, BeiBei District, Chongqing 400715 (China)

    2017-01-15

    Highlights: • The carbon quantum dots (CQDs) synthesized with PEI showed an extraordinary reducibility. • The Ag/CQDs composite was prepared by using CQDs as reducing and stabilizing agent. • A simple Ag/CQDs composite-based dual-signal probe was provided for Hg{sup 2+} detection. • The proposed strategy shows a potential for detecting Hg{sup 2+} in real water samples. - Abstract: A stable silver nanoparticles/carbon quantum dots (Ag/CQDs) composite was prepared by using CQDs as reducing and stabilizing agent. The CQDs synthesized with polyethyleneimine (PEI) showed an extraordinary reducibility. When Hg{sup 2+} was presented in the Ag/CQDs composite solution, a color change from yellow to colorless was observed, accompanied by a shift of surface plasmon resonance (SPR) band and decrease in absorbance of the Ag/CQDs composite. On the basis of the further studies on TEM, XPS and XRD analysis, the possible mechanism is attributed to the formation of a silver-mercury amalgam. Hence, a two dimensional sensing platform for Hg{sup 2+} detection was constructed upon the Ag/CQDs composite. Based on the change of absorbance, a good linear relationship was obtained from 0.5 to 50 μM for Hg{sup 2+}. And the limit of detection for Hg{sup 2+} was as low as 85 nM, representing high sensitivity to Hg{sup 2+}. More importantly, the proposed method also exhibits a good selectivity toward Hg{sup 2+} over other metal ions. Besides, this strategy demonstrates practicability for the detection of Hg{sup 2+} in real water samples with satisfactory results.

  11. Improving mine-mill water network design by reducing water and energy requirements

    Energy Technology Data Exchange (ETDEWEB)

    Gunson, A.J.; Klein, B.; Veiga, M. [British Columbia Univ., Vancouver, BC (Canada). Norman B. Keevil Inst. of Mining Engineering

    2010-07-01

    Mining is an energy-intensive industry, and most processing mills use wet processes to separate minerals from ore. This paper discussed water reduction, reuse and recycling options for a mining and mill operation network. A mine water network design was then proposed in order to identify and reduce water and system energy requirements. This included (1) a description of site water balance, (2) a description of potential water sources, (3) a description of water consumers, (4) the construction of energy requirement matrices, and (5) the use of linear programming to reduce energy requirements. The design was used to determine a site water balance as well as to specify major water consumers during mining and mill processes. Potential water supply combinations, water metering technologies, and recycling options were evaluated in order to identify the most efficient energy and water use combinations. The method was used to highlight potential energy savings from the integration of heating and cooling systems with plant water systems. 43 refs., 4 tabs., 3 figs.

  12. Breaking the Barrier to Slow Water Exchange Rates for Optimal Magnetic Resonance Detection of paraCEST Agents.

    Science.gov (United States)

    Fernando, W Shirangi; Martins, André F; Zhao, Piyu; Wu, Yunkou; Kiefer, Garry E; Platas-Iglesias, Carlos; Sherry, A Dean

    2016-03-21

    EuDOTA-tetraamide complexes as paraCEST agents offer an attractive platform for designing biological sensors and responsive agents. The early versions of these agents showed low sensitivity at temperature and power levels suitable for in vivo applications partly due to non-optimal water exchange rates. Here we report two new EuDOTA derivatives having glutamyl-phosphonate side arms that display the slowest water exchange rates of any other paraCEST agent reported so far. The advantages of such systems are demonstrated experimentally both in vitro and in vivo and DFT calculations were performed to help understand the physical-chemical reasons for this interesting behavior.

  13. Reinforcement Learning Multi-Agent Modeling of Decision-Making Agents for the Study of Transboundary Surface Water Conflicts with Application to the Syr Darya River Basin

    Science.gov (United States)

    Riegels, N.; Siegfried, T.; Pereira Cardenal, S. J.; Jensen, R. A.; Bauer-Gottwein, P.

    2008-12-01

    In most economics--driven approaches to optimizing water use at the river basin scale, the system is modelled deterministically with the goal of maximizing overall benefits. However, actual operation and allocation decisions must be made under hydrologic and economic uncertainty. In addition, river basins often cross political boundaries, and different states may not be motivated to cooperate so as to maximize basin- scale benefits. Even within states, competing agents such as irrigation districts, municipal water agencies, and large industrial users may not have incentives to cooperate to realize efficiency gains identified in basin- level studies. More traditional simulation--optimization approaches assume pre-commitment by individual agents and stakeholders and unconditional compliance on each side. While this can help determine attainable gains and tradeoffs from efficient management, such hardwired policies do not account for dynamic feedback between agents themselves or between agents and their environments (e.g. due to climate change etc.). In reality however, we are dealing with an out-of-equilibrium multi-agent system, where there is neither global knowledge nor global control, but rather continuous strategic interaction between decision making agents. Based on the theory of stochastic games, we present a computational framework that allows for studying the dynamic feedback between decision--making agents themselves and an inherently uncertain environment in a spatially and temporally distributed manner. Agents with decision-making control over water allocation such as countries, irrigation districts, and municipalities are represented by reinforcement learning agents and coupled to a detailed hydrologic--economic model. This approach emphasizes learning by agents from their continuous interaction with other agents and the environment. It provides a convenient framework for the solution of the problem of dynamic decision-making in a mixed cooperative / non

  14. Water cooler towers and other man-made aquatic systems as environmental collection systems for agents of concern

    Science.gov (United States)

    Brigmon, Robin; Kingsley, Mark T.

    2018-04-03

    An apparatus and process of using existing process water sources such as cooling towers, fountains, and waterfalls is provided in which the water sources are utilized as monitoring system for the detection of environmental agents which may be present in the environment. The process water is associated with structures and have an inherent filtering or absorbing capability available in the materials and therefore can be used as a rapid screening tool for quality and quantitative assessment of environmental agents.

  15. A framework for identifying water management typologies for agent based modeling of water resources and its application in the Boise River Basin, USA.

    Science.gov (United States)

    Kaiser, K. E.; Flores, A. N.; Hillis, V.; Moroney, J.; Schneider, J.

    2017-12-01

    Modeling the management of water resources necessitates incorporation of complex social and hydrologic dynamics. Simulation of these socio-ecological systems requires characterization of the decision-making process of relevant actors, the mechanisms through which they exert control on the biophysical system, their ability to react and adapt to regional environmental conditions, and the plausible behaviors in response to changes in those conditions. Agent based models (ABMs) are a useful tool in simulating these complex adaptive systems because they can dynamically couple hydrological models and the behavior of decision making actors. ABMs can provide a flexible, integrated framework that can represent multi-scale interactions, and the heterogeneity of information networks and sources. However, the variability in behavior of water management actors across systems makes characterizing agent behaviors and relationships challenging. Agent typologies, or agent functional types (AFTs), group together individuals and/or agencies with similar functional roles, management objectives, and decision-making strategies. AFTs have been used to represent archetypal land managers in the agricultural and forestry sectors in large-scale socio-economic system models. A similar typology of water actors could simplify the representation of water management across river basins, and increase transferability and scaling of resulting ABMs. Here, we present a framework for identifying and classifying major water actors and show how we will link an ABM of water management to a regional hydrologic model in a western river basin. The Boise River Basin in southwest Idaho is an interesting setting to apply our AFT framework because of the diverse stakeholders and associated management objectives which include managing urban growth pressures and water supply in the face of climate change. Precipitation in the upper basin supplies 90% of the surface water used in the basin, thus managers of the

  16. Enhancement effects of reducing agents on the degradation of tetrachloroethene in the Fe(II)/Fe(III) catalyzed percarbonate system

    International Nuclear Information System (INIS)

    Miao, Zhouwei; Gu, Xiaogang; Lu, Shuguang; Brusseau, Mark L.; Yan, Ni; Qiu, Zhaofu; Sui, Qian

    2015-01-01

    Highlights: • PCE degradation by reducing-agent modified Fe-catalyzed percarbonate was studied. • The addition of reducing agents significantly increased PCE degradation. • Hydroxylamine hydrochloride showed the best effect on enhancing PCE degradation. • The primary PCE degradation mechanism was oxidation by hydroxyl radical. • O_2·"− participated in the degradation of PCE in reducing-agent modified system. - Abstract: In this study, the effects of reducing agents on the degradation of tetrachloroethene (PCE) were investigated in the Fe(II)/Fe(III) catalyzed sodium percarbonate (SPC) system. The addition of reducing agents, including hydroxylamine hydrochloride, sodium sulfite, ascorbic acid and sodium ascorbate, accelerated the Fe(III)/Fe(II) redox cycle, leading to a relatively steady Fe(II) concentration and higher production of free radicals. This, in turn, resulted in enhanced PCE oxidation by SPC, with almost complete PCE removal obtained for appropriate Fe and SPC concentrations. The chemical probe tests, using nitrobenzene and carbon tetrachloride, demonstrated that HO· was the predominant radical in the system and that O_2·"− played a minor role, which was further confirmed by the results of electron spin resonance measurements. PCE degradation decreased significantly with the addition of isopropanol, a HO· scavenger, supporting the hypothesis that HO· was primarily responsible for PCE degradation. It is noteworthy that Cl"− release was slightly delayed in the first 20 min, indicating that intermediate products were produced. However, these intermediates were further degraded, resulting in the complete conversion of PCE to CO_2. In conclusion, the use of reducing agents to enhance Fe(II)/Fe(III) catalyzed SPC oxidation appears to be a promising approach for the rapid degradation of organic contaminants in groundwater.

  17. Enhancement effects of reducing agents on the degradation of tetrachloroethene in the Fe(II)/Fe(III) catalyzed percarbonate system

    Energy Technology Data Exchange (ETDEWEB)

    Miao, Zhouwei [State Environmental Protection Key Laboratory of Environmental Risk Assessment and Control on Chemical Process, East China University of Science and Technology, Shanghai 200237 (China); Soil, Water and Environmental Science Department, School of Earth and Environmental Sciences, The University of Arizona, 429 Shantz Building, Tucson, AZ 85721 (United States); Gu, Xiaogang [State Environmental Protection Key Laboratory of Environmental Risk Assessment and Control on Chemical Process, East China University of Science and Technology, Shanghai 200237 (China); Lu, Shuguang, E-mail: lvshuguang@ecust.edu.cn [State Environmental Protection Key Laboratory of Environmental Risk Assessment and Control on Chemical Process, East China University of Science and Technology, Shanghai 200237 (China); Brusseau, Mark L. [Soil, Water and Environmental Science Department, School of Earth and Environmental Sciences, The University of Arizona, 429 Shantz Building, Tucson, AZ 85721 (United States); Yan, Ni [Hydrology and Water Resources Department, School of Earth and Environmental Sciences, University of Arizona, 429 Shantz Building, Tucson, AZ 85721 (United States); Qiu, Zhaofu; Sui, Qian [State Environmental Protection Key Laboratory of Environmental Risk Assessment and Control on Chemical Process, East China University of Science and Technology, Shanghai 200237 (China)

    2015-12-30

    Highlights: • PCE degradation by reducing-agent modified Fe-catalyzed percarbonate was studied. • The addition of reducing agents significantly increased PCE degradation. • Hydroxylamine hydrochloride showed the best effect on enhancing PCE degradation. • The primary PCE degradation mechanism was oxidation by hydroxyl radical. • O{sub 2}·{sup −} participated in the degradation of PCE in reducing-agent modified system. - Abstract: In this study, the effects of reducing agents on the degradation of tetrachloroethene (PCE) were investigated in the Fe(II)/Fe(III) catalyzed sodium percarbonate (SPC) system. The addition of reducing agents, including hydroxylamine hydrochloride, sodium sulfite, ascorbic acid and sodium ascorbate, accelerated the Fe(III)/Fe(II) redox cycle, leading to a relatively steady Fe(II) concentration and higher production of free radicals. This, in turn, resulted in enhanced PCE oxidation by SPC, with almost complete PCE removal obtained for appropriate Fe and SPC concentrations. The chemical probe tests, using nitrobenzene and carbon tetrachloride, demonstrated that HO· was the predominant radical in the system and that O{sub 2}·{sup −} played a minor role, which was further confirmed by the results of electron spin resonance measurements. PCE degradation decreased significantly with the addition of isopropanol, a HO· scavenger, supporting the hypothesis that HO· was primarily responsible for PCE degradation. It is noteworthy that Cl{sup −} release was slightly delayed in the first 20 min, indicating that intermediate products were produced. However, these intermediates were further degraded, resulting in the complete conversion of PCE to CO{sub 2}. In conclusion, the use of reducing agents to enhance Fe(II)/Fe(III) catalyzed SPC oxidation appears to be a promising approach for the rapid degradation of organic contaminants in groundwater.

  18. Reducing Mortality from Terrorist Releases of Chemical and Biological Agents: I. Filtration for Ventilation Systems in Commercial Building

    Energy Technology Data Exchange (ETDEWEB)

    Thatcher, Tracy L.; Daisey, Joan M.

    1999-09-01

    There is growing concern about potential terrorist attacks involving releases of chemical and/or biological (CB) agents, such as sarin or anthrax, in and around buildings. For an external release, the CB agent can enter the building through the air intakes of a building's mechanical ventilation system and by infiltration through the building envelope. For an interior release in a single room, the mechanical ventilation system, which often recirculates some fraction of the air within a building, may distribute the released CB agent throughout the building. For both cases, installing building systems that remove chemical and biological agents may be the most effective way to protect building occupants. Filtration systems installed in the heating, ventilating and air-conditioning (HVAC) systems of buildings can significantly reduce exposures of building occupants in the event of a release, whether the release is outdoors or indoors. Reduced exposures can reduce the number of deaths from a terrorist attack. The purpose of this report is to provide information and examples of the design of filtration systems to help building engineers retrofit HVAC systems. The report also provides background information on the physical nature of CB agents and brief overviews of the basic principles of particle and vapor filtration.

  19. Novel Cleanup Agents Designed Exclusively for Oil Field Membrane Filtration Systems Low Cost Field Demonstrations of Cleanup Agents in Controlled Experimental Environments

    Energy Technology Data Exchange (ETDEWEB)

    David Burnett; Harold Vance

    2007-08-31

    The goal of our project is to develop innovative processes and novel cleaning agents for water treatment facilities designed to remove fouling materials and restore micro-filter and reverse osmosis (RO) membrane performance. This project is part of Texas A&M University's comprehensive study of the treatment and reuse of oilfield brine for beneficial purposes. Before waste water can be used for any beneficial purpose, it must be processed to remove contaminants, including oily wastes such as residual petroleum hydrocarbons. An effective way of removing petroleum from brines is the use of membrane filters to separate oily waste from the brine. Texas A&M and its partners have developed highly efficient membrane treatment and RO desalination for waste water including oil field produced water. We have also developed novel and new cleaning agents for membrane filters utilizing environmentally friendly materials so that the water from the treatment process will meet U.S. EPA drinking water standards. Prototype micellar cleaning agents perform better and use less clean water than alternate systems. While not yet optimized, the new system restores essentially complete membrane flux and separation efficiency after cleaning. Significantly the amount of desalinated water that is required to clean the membranes is reduced by more than 75%.

  20. Cooperative water network system to reduce carbon footprint.

    Science.gov (United States)

    Lim, Seong-Rin; Park, Jong Moon

    2008-08-15

    Much effort has been made in reducing the carbon footprint to mitigate climate change. However, water network synthesis has been focused on reducing the consumption and cost of freshwater within each industrial plant. The objective of this study is to illustrate the necessity of the cooperation of industrial plants to reduce the total carbon footprint of their water supply systems. A mathematical optimization model to minimize global warming potentials is developed to synthesize (1) a cooperative water network system (WNS) integrated over two plants and (2) an individual WNS consisting of two WNSs separated for each plant. The cooperative WNS is compared to the individual WNS. The cooperation reduces their carbon footprint and is economically feasible and profitable. A strategy for implementing the cooperation is suggested for the fair distribution of costs and benefits. As a consequence, industrial plants should cooperate with their neighbor plants to further reduce the carbon footprint.

  1. Design of a unit to produce hot distilled water for the same power consumption as a water heater

    Science.gov (United States)

    Bambenek, R. A.; Nuccio, P. P.

    1973-01-01

    Unit recovers 97% of water contained in pretreated waste water. Some factors are: cleansing agent prevents fouling of heat transfer surface by highly concentrated waste; absence of dynamic seals reduces required purge gas flow rate; and recycle loop maintains constant flushing process to carry cleansing agent across evaporation surface.

  2. Skin decontamination of G, V, H L agents by Canadian reactive skin decontaminant lotion

    Energy Technology Data Exchange (ETDEWEB)

    Bide, R.W.; Sawyer, T.W.; DiNinno, V.L.; Armour, S.J.; Risk, D.J.

    1993-05-13

    The Canadian Reactive Skin Decontaminant Lotion (RSDL) is a reactive solution designed to be applied directly to skin for the decontamination and destruction of the classical chemical warfare agents. The solvent of the RSDL is very effective in dissolving liquid agents from the skin surface and the differential solubility of agents in the RSDL and the skin strongly favors retention of agents in the lotion. The active ingredient in the RSDL reacts rapidly and completely with G-agents, V-agents, mustard Lewisite producing relatively nontoxic products. The RSDL will dissolve and destroy agent thickened with acrylate polymers. The lotion is water soluble and readily removed from the skin. Since the RSDL is water soluble, it is active against water soluble agents even at high dilutions. For water insoluble agents, the activity is reduced as the water content rises above abrasive 50% due to insolubility of the agents. Skin and eye irritancy trials indicate that the RSDL is only a mild irritant to the eyes (equivalent to a chlorinated swimming pool) and to abraded skin. Acute toxicity trials showed that large oral and intraperitoneal doses were essentially non-toxic. The RSDL was fielded by the Canadian Forces for the Gulf Conflict. The RSDL may be used in open wounds for short periods. Wound decontamination and irrigation with RSDL diluted 1:1 with isotonic saline was recommended for the Gulf conflict.

  3. Seed-mediated synthesis of gold nanorods: control of the aspect ratio by variation of the reducing agent

    International Nuclear Information System (INIS)

    Koeppl, Susanne; Ghielmetti, Nico; Caseri, Walter; Spolenak, Ralph

    2013-01-01

    Seed-mediated growth methods involving reduction of tetrachloroaurate(III) with ascorbic acid are common for the synthesis of gold nanorods. This study shows, however, that simply by appropriate choice of the reducing agent a drastic influence on the aspect ratio can be attained. Weaker reducing agents, such as dihydroxybenzene isomers (hydroquinone, catechol or resorcinol) or glucose can increase the aspect ratio of the nanorods by an order of magnitude, up to values as high as 100 (nanowires). The increase in aspect ratio is mainly a consequence of an increase in length of the particles (up to 1–3 μm). This effect is probably associated with a decrease in the reduction rate of gold(III) species by dihydroxybenzenes or glucose compared to ascorbic acid. The reduction potential of the reducing agents strongly depends on the pH value, and related effects on the dimensions of the nanoparticles are also reflected in this study. The nanorods exhibited penta-twinned nature without noteworthy defects (e.g. stacking faults and dislocations).

  4. Occurrence and profiles of organic sun-blocking agents in surface waters and sediments in Japanese rivers and lakes

    International Nuclear Information System (INIS)

    Kameda, Yutaka; Kimura, Kumiko; Miyazaki, Motonobu

    2011-01-01

    Sun-blocking agents including eight UV filters (UVF) and 10 UV light stabilizers (UVLS) were measured in water and sediment collected from 22 rivers, four sewage treatment plant effluents (STPE) and three lakes in Japan. Total sun blocking agents levels ranged from N.D. to 4928 ng/L and from 2.0 to 3422 μg/kg dry wt in surface water and in sediment, respectively. Benzyl salicylate, benzophenone-3, 2-ethyl hexyl-4-methoxycinnamte (EHMC) and octyl salicylate were dominant in surface water receiving wastewater effluents and STPE, although UV-328, benzophenone and EHMC were dominant in other surface water except background sites. Three UVF and nine UVLS were observed from all sediment and their compositions showed similar patterns with UV-328 and UV-234 as the most prevalent compounds. Homosalate, octocrylene, UV-326, UV-327, UV-328 and UV-234 were significantly correlated with Galaxolide in sediments. Concentrations of UV-327 and UV-328 also had strong correlation between those of UV-326 in sediment. - Highlights: → Total sun-blocking agents levels ranged from N.D. to 4928 ng/L in surface water from 29 sampling sites. → The maximum concentration of total sun-blocking agents was 3422 μg/kg dry wt. in sediment. → Residential wastewaters and STPE were considered to be potential sources of UVLS in river and lakes. → Most of sun-blocking agents in sediment were significantly correlated with HHCB. → UV-326 had a strong linear correlation between UV-327 as well as UV-328 in all sediment. - Occurrence of eight UV filters and 10 UV light stabilizers in surface water and sediment were investigated and characterized their compositions in water and sediment.

  5. Method of solution mining subsurface orebodies to reduce restoration activities

    Energy Technology Data Exchange (ETDEWEB)

    Hartman, G.J.

    1984-01-24

    A method of solution mining is claimed wherein a lixiviant containing both leaching and oxidizing agents is injected into the subsurface orebody. The composition of the lixiviant is changed by reducing the level of oxidizing agent to zero so that soluble species continue to be removed from the subsurface environment. This reduces the uranium level of the ground water aquifer after termination of the lixiviant injection.

  6. The utilization of microbes as a fermentation agent to reduce saponin in Trembesi leaves (Sammanea saman)

    Science.gov (United States)

    Sariri, A. K.; Mulyono, A. M. W.; Tari, A. I. N.

    2018-03-01

    This objective of this research was to observe the utilization of microbes as a fermentation agent of trembesi leaves that can increase the quality of trembesi leaves as ruminants feed. Before fermentation, trembesi leaves were divided into three treatments. They were control = non-agentic in fermentation, D-An = the addition of Aspergillus niger as fermentation agent, and D-Lp = the addition of Lactobacillus plantarum as fermentation agent. Each treatment experienced five repetitions. The experimental design used a randomized direct pattern group design. The analysis included proximate analysis consisting of water content, crude protein content, crude fiber content, lipid content, mineral content (ash) and saponin content after fermentation. It could be concluded that the utilization of Aspergillus niger and Lactobacillus plantarum in fermentation could decrease saponin content and could increase the nutrient content of trembesi leaves by increasing crude protein content otherwise by decreasing crude fiber content of trembesi leaves.

  7. Bactericide for sulfate-reducing bacteria

    Energy Technology Data Exchange (ETDEWEB)

    Shklyar, T F; Anoshina, G M; Blokhin, V Ye; Kisarrev, Ye L; Novikovsa, G M

    1981-01-01

    The aim of the invention is to find a bactericide for sulfate-reducing bacteria of oil fields in Western Siberia in order to suppress the biocorrosive activity on oil industry equipment. This goal is achieved by using M-nitroacetanylide as the bactericide of sulfate-reducing bacteria. This agent suppresses the activity of a stored culture of sulfate-reducing bacteria that comes from industrial waste waters injection wells of the Smotlor oil field.

  8. Reduced weight decontamination formulation for neutralization of chemical and biological warfare agents

    Science.gov (United States)

    Tucker, Mark D.

    2014-06-03

    A reduced weight DF-200 decontamination formulation that is stable under high temperature storage conditions. The formulation can be pre-packed as an all-dry (i.e., no water) or nearly-dry (i.e., minimal water) three-part kit, with make-up water (the fourth part) being added later in the field at the point of use.

  9. Hydrothermal synthesis of magnetic reduced graphene oxide sheets

    International Nuclear Information System (INIS)

    Shen, Jianfeng; Shi, Min; Ma, Hongwei; Yan, Bo; Li, Na; Ye, Mingxin

    2011-01-01

    Graphical abstract: An environmental friendly and efficient route for preparation of magnetic reduced graphene oxide composite with a one-step hydrothermal method was demonstrated. The reducing process was accompanied by generation of magnetic nanoparticles. Highlights: → A one-step hydrothermal method for preparation of MN-CCG was demonstrated. → Glucose was used as the 'green' reducing agent. → The reducing process was accompanied by generation of magnetic nanoparticles. → The prepared MN-CCG is highly water suspendable and sensitive to magnetic field. -- Abstract: We demonstrated an environmental friendly and efficient route for preparation of magnetic reduced graphene oxide composite (MN-CCG). Glucose was used as the reducing agent in this one-step hydrothermal method. The reducing process was accompanied by generation of magnetic nanoparticles. The structure and composition of the nanocomposite was confirmed by Fourier transform infrared spectroscopy, Raman spectroscopy, X-ray diffraction, thermal gravimetric analysis, atomic force microscopy and transmission electron microscopy. It was found that the prepared MN-CCG is highly water suspendable and sensitive to magnetic field.

  10. Effects of Electron Acceptors, Reducing Agents, and Toxic Metabolites on Anaerobic Degradation of Heterocyclic Compounds

    DEFF Research Database (Denmark)

    Licht, Dorthe; Ahring, Birgitte Kiær; Arvin, Erik

    1996-01-01

    Degradation of four heterocyclic compounds was examined under nitrate-reducing, sulphate-reducing and methanogenic conditions. Soil samples from a creosote-polluted site in Denmark were used as inoculum. Indole and quinoline were degraded under all redox conditions with the highest degradation...... of quinoline under sulphate-reducing conditions which was inhibited by sulphide at concentrations above 0.8 mM. Degradation of quinoline under methanogenic conditions was also inhibited by 3.2 mM sulphide used as a reducing agent, but sulphide had no inhibitory effect on the degradation of indole...... in methanogenic and sulphate-reducing soil slurries...

  11. Water-driven micromotors for rapid photocatalytic degradation of biological and chemical warfare agents.

    Science.gov (United States)

    Li, Jinxing; Singh, Virendra V; Sattayasamitsathit, Sirilak; Orozco, Jahir; Kaufmann, Kevin; Dong, Renfeng; Gao, Wei; Jurado-Sanchez, Beatriz; Fedorak, Yuri; Wang, Joseph

    2014-11-25

    Threats of chemical and biological warfare agents (CBWA) represent a serious global concern and require rapid and efficient neutralization methods. We present a highly effective micromotor strategy for photocatalytic degradation of CBWA based on light-activated TiO2/Au/Mg microspheres that propel autonomously in natural water and obviate the need for external fuel, decontaminating reagent, or mechanical agitation. The activated TiO2/Au/Mg micromotors generate highly reactive oxygen species responsible for the efficient destruction of the cell membranes of the anthrax simulant Bacillus globigii spore, as well as rapid and complete in situ mineralization of the highly persistent organophosphate nerve agents into nonharmful products. The water-driven propulsion of the TiO2/Au/Mg micromotors facilitates efficient fluid transport and dispersion of the photogenerated reactive oxidative species and their interaction with the CBWA. Coupling of the photocatalytic surface of the micromotors and their autonomous water-driven propulsion thus leads to a reagent-free operation which holds a considerable promise for diverse "green" defense and environmental applications.

  12. Effect of reducing agents on low-temperature synthesis of nanostructured LiFePO4

    Science.gov (United States)

    Kulka, Andrzej; Walczak, Katarzyna; Zając, Wojciech; Molenda, Janina

    2017-09-01

    Simple co-precipitation synthesis procedure yielding nanometric LiFePO4 with enhanced electrochemical properties without any post-synthesis heat treatment is presented. XRD, SEM and TEM analysis of the obtained powders revealed platelet crystallites and well crystalized bulk structure. Effective way of decreasing amount of Fe3+ containing phases by addition of reducing agents (KI, (NH4)2S2O3, glucose and the atmosphere of 5%H2-95%Ar) during low-temperature (107 °C) synthesis is described. The traditional analytical chemistry methods or the Mӧssbauer spectroscopy methods revealed that utilization of selected reducing agents diminished Fe3+ concentration from 25 to 12 at%. The constructed cells with optimized LiFePO4 as a cathode material showed superior electrochemical performances, including high reversible capacity up to 162 mAh/g at C/10 current discharge rate, flat voltage plateau with a value close to 3.45 V vs. Li0/+.

  13. Diet change—a solution to reduce water use?

    International Nuclear Information System (INIS)

    Jalava, M; Kummu, M; Porkka, M; Varis, O; Siebert, S

    2014-01-01

    Water and land resources are under increasing pressure in many parts of the globe. Diet change has been suggested as a measure to contribute to adequate food security for the growing population. This paper assesses the impact of diet change on the blue and green water footprints of food consumption. We first compare the water consumption of the current diets with that of a scenario where dietary guidelines are followed. Then, we assess these footprints by applying four scenarios in which we gradually limit the amount of protein from animal products to 50%, 25%, 12.5% and finally 0% of the total protein intake. We find that the current water use at the global scale would be sufficient to secure a recommended diet and worldwide energy intake. Reducing the animal product contribution in the diet would decrease global green water consumption by 6%, 11%, 15% and 21% within the four applied scenarios, while for blue water, the reductions would be 4%, 6%, 9% and 14%. In Latin America, Europe, Central and Eastern Asia and Sub-Saharan Africa, diet change mainly reduces green water use, while in the Middle East region, North America, Australia and Oceania, both blue and green water footprints decrease considerably. At the same time, in South and Southeast Asia, diet change does not result in decreased water use. Our results show that reducing animal products in the human diet offers the potential to save water resources, up to the amount currently required to feed 1.8 billion additional people globally; however, our results show that the adjustments should be considered on a local level. (letter)

  14. Effects of Shrinkage Reducing Agent and Expansive Additive on Mortar Properties

    OpenAIRE

    Treesuwan, Sarapon; Maleesee, Komsan

    2017-01-01

    This research is to study the effect of mortar mixed with shrinkage reducing agent (polyoxyalkylene alkyl ether type), expansive additive (CaO type), and fly ash (hereinafter “SRA,” “EX,” and “FA,” resp.). Moreover, steam curing was studied to improve the properties of mortar. The plastic shrinkage test was conducted by using the strain gauge embedded at 0.5 cm from the surface according to the ASTM C1579-06 standard within early age followed by the total shrinkage test and compressive streng...

  15. The effect of temperature and addition of reducing agent on sodium stannate preparation from cassiterite by the alkaline roasting process

    Science.gov (United States)

    Lalasari, Latifa Hanum; Andriyah, Lia; Arini, Tri; Firdiyono, F.

    2018-04-01

    Sodium stannate is an intermediate compound with the formula Na2SnO3. This compound is easily dissolved in water and has many applications in the electroplating industry, tin alloy production, and catalysts for organic synthesis. In this occasion was investigated the effect of temperature and the addition of reducing agent on making of sodium stannate phase from cassiterite by an alkaline roasting process using sodium carbonate (Na2CO3). Firstly, cassiterite was roasted at 700 °C for 3 hours and continued leaching process using 10% HCl solution at 110 °C for 2 hours. The cassiterite residue than was dried at 110 °C and mixed homogenously with a Na2CO3 decomposer at a mass ratio Na2CO3/cassiterite as 5:3 for the decomposition process. It was done by variation temperatures (300 °C, 700 °C, 800 °C, 870 °C, 900 °C) for 3 hours, variation times (3, 4, 5 hours) at a roasting temperature of 700 °C and addition of reducing agent such as sub-bituminous coal. The result of the experiment shows that cassiterite prepared by roasting and acid leaching process has the chemical composition as follows: 59.98% Sn, 22.58% O, 3.20% Ce, 3.15% La, 2.57% Nd, 1.67% Ti, 1.56% Fe, 1.24% P, 0.62% Ca and others. The Na2SnO3 phase begins to form at a roasting temperature of 870 °C for 3 hours. Although the roasting times was extended from 3 hours to 5 hours at 700 °C, the Na2SnO3 phase also has not yet formed. In other conditions, the addition of coal reducing agent to the roasting process would cause formations of Sn metal besides Na2SnO3 phase at 870 °C. At temperatures lower than 870 °C, the addition of coal only forms Sn metal, whereas the sodium stannate phase is not formed.

  16. TIC-Tox: A preliminary discussion on identifying the forcing agents of DBP-mediated toxicity of disinfected water.

    Science.gov (United States)

    Plewa, Michael J; Wagner, Elizabeth D; Richardson, Susan D

    2017-08-01

    The disinfection of drinking water is a major public health achievement; however, an unintended consequence of disinfection is the generation of disinfection by-products (DBPs). Many of the identified DBPs exhibit in vitro and in vivo toxicity, generate a diversity of adverse biological effects, and may be hazards to the public health and the environment. Only a few DBPs are regulated by several national and international agencies and it is not clear if these regulated DBPs are the forcing agents that drive the observed toxicity and their associated health effects. In this study, we combine analytical chemical and biological data to resolve the forcing agents associated with mammalian cell cytotoxicity of drinking water samples from three cities. These data suggest that the trihalomethanes (THMs) and haloacetic acids may be a small component of the overall cytotoxicity of the organic material isolated from disinfected drinking water. Chemical classes of nitrogen-containing DBPs, such as the haloacetonitriles and haloacetamides, appear to be the major forcing agents of toxicity in these samples. These findings may have important implications for the design of epidemiological studies that primarily rely on the levels of THMs to define DBP exposure among populations. The TIC-Tox approach constitutes a beginning step in the process of identifying the forcing agents of toxicity in disinfected water. Copyright © 2017. Published by Elsevier B.V.

  17. Reducing phosphorus loading of surface water using iron-coated sand

    NARCIS (Netherlands)

    Groenenberg, J.E.; Chardon, W.J.; Koopmans, G.F.

    2013-01-01

    Phosphorus losses from agricultural soils is an important source of P in surface waters leading to surface water quality impairment. In addition to reducing P inputs, mitigation measures are needed to reduce P enrichment of surface waters. Because drainage of agricultural land by pipe drainage is an

  18. Estimated general population control limits for unitary agents in drinking water, milk, soil, and unprocessed food items

    Energy Technology Data Exchange (ETDEWEB)

    Watson, A.P.; Adams, J.D.; Cerar, R.J.; Hess, T.L.; Kistner, S.L.; Leffingwell, S.S.; MacIntosh, R.G.; Ward, J.R.

    1992-01-01

    In the event of an unplanned release of chemical agent during any stage of the Chemical Stockpile Disposal Program (CSDP), the potential exists for contamination of drinking water, forage crops, grains, garden produce, and livestock. Persistent agents such as VX or sulfur mustard pose the greatest human health concern for reentry. This White Paper has been prepared to provide technical bases for these decisions by developing working estimates of agent control limits in selected environmental media considered principal sources of potential human exposure. To date, control limits for public exposure to unitary agents have been established for atmospheric concentrations only. The current analysis builds on previous work to calculate working estimates of control limits for ingestion and dermal exposure to potentially contaminated drinking water, milk, soil, and unprocessed food items such as garden produce. Information characterizing agent desorption from, and detection on or in, contaminated porous media are presently too developed to permit reasonable estimation of dermal exposure from this source. Thus, dermal contact with potentially contaminated porous surfaces is not considered in this document.

  19. On-load chelating agent treatments for conventional and nuclear power stations

    International Nuclear Information System (INIS)

    Turner, D.J.

    1978-01-01

    The paper is concerned with the application of on-load chelating agent treatments to those types of water circuit for which they are not currently available: high pressure drum boilers, sub-critical once-through boilers and water reactors. An attempt was made to see whether the most thermally stable types of chelating agent are likely to be sufficiently strong chelating agents either to dissolve established Fe 3 O 4 deposits or to prevent their precipitation from solution. It seems likely that they are strong enough to prevent Fe 3 O 4 depositing in a once-through boiler, through some may require that mildly reducing conditions are maintained. They would not be effective in a high pressure drum boiler (at 350 0 C) unless much more strongly reducing conditions could be maintained. For such boilers it would probably be better to seek multidentate ligands of less than maximum thermal stability. There are some indications that chelating agents based on carbon chains are more stable than NTA or EDTA so that citric acid or some of the unidentified chelating agents recently found to be produced radiolytically may have potential in the treatment of high pressure drum boilers. The prospects for periodic full-load cleaning seem less good for both types of boiler. There may also be a role for radiolytically produced chelating agents in alleviating some of the problems caused by the deposition of radioactive corrosion products in water reactor circuits. The chances for successful development fall from quite good to very low down the series SGHWR moderator circuit, PWR primary circuit, ammonia dosed BWR, neutral chemistry BWR (including SGHWR). (author)

  20. A multi-agent architecture for sharing knowledge and experimental data about waste water treatment plants through the Internet

    International Nuclear Information System (INIS)

    Abu Yaman, I. R.; Kerckhoffs, J. E.

    1998-01-01

    In this paper, we present a first prototype of a local multi-agent architecture for the sharing of knowledge and experimental data about waste water treatment plants through the Internet, or more specifically the WWW. Applying a net browser such as nets cape, a user can have access to a CLIPS expert system (advising on waste water cleaning technologies) and experimental data files. The discussed local prototype is part of proposed global agent architecture. (authors)

  1. Reducing agent-free synthesis of curcumin-loaded albumin nanoparticles by self-assembly at room temperature.

    Science.gov (United States)

    Safavi, Maryam Sadat; Shojaosadati, Seyed Abbas; Yang, Hye Gyeong; Kim, Yejin; Park, Eun Ji; Lee, Kang Choon; Na, Dong Hee

    2017-08-30

    The purpose of this study was to prepare curcumin-loaded bovine serum albumin nanoparticles (CCM-BSA-NPs) by reducing agent-free self-assembly at room temperature. A 2 4 factorial design approach was used to investigate the CCM-BSA-NP preparation process at different pH values, temperatures, dithiothreitol amounts, and CCM/BSA mass ratios. Increasing the ionic strength enabled preparation of CCM-BSA-NPs at 25°C without reducing agent. CCM-BSA-NPs prepared under the optimized conditions at 25°C showed a particle size of 110±6nm, yield of 88.5%, and drug loading of 7.1%. The CCM-BSA-NPs showed strong antioxidant activity and neuroprotective effects in glutamate-induced mouse hippocampal neuronal HT22 cells. This study suggests that ionic strength can be a key parameter affecting the preparation of albumin-based NPs. Copyright © 2017 Elsevier B.V. All rights reserved.

  2. Study of the leaching of heavy metals from waste water sludge and incinerator's ash, using coupled thermostated columns and DTPA as complex agent

    International Nuclear Information System (INIS)

    Vite T, J.; Vite T, M.; Guerrero D, J.; Carreno de Leon, M.C.

    2000-01-01

    We studied the metallic composition from waste water sludge and incinerators ashes of an incinerator located in Toluca, Mexico, the qualitative studies were made using the Activation Analysis technique, and fluorescence X-ray techniques. The quantitative analysis of heavy metals in the wastes were made using Inductively coupled plasma atomic emission spectrometry (Icp-Aes). For leaching the samples, we used four coupled thermostated columns, each one had a p H of 2,5, 7 and 10. The flux of the air was of 1600 cc/min. The temperature was maintain constant in 60 Centigrade using a thermostated system. For this study we used 100 g of wastes mixed with mineral acid or sodium hydroxide to reach p H 2,5,7 and 10. We added a reducing and tensoactive agents and finally DTPA as complex agent. With this method, we obtain a better leaching efficiency using a complex agent. However the high DTPA cost, make this process expansive that is why we recommend to work with another classes of complex agents, that be cheaper to leach metals of different chemistry matrix. (Author)

  3. Water enema CT examination of rectum cancer by reduced amount of water

    International Nuclear Information System (INIS)

    Palko, A.; Gyulai, Cs.; Fedinecz, N.; Balogh, A.; Nagy, F.

    2000-01-01

    To define whether volume of water, administered during water enema CT (WE-CT) for local staging of rectal cancer, may be reduced without compromising the diagnostic value of the examination. Materials and Methods: 29 patients with rectum cancer underwent preoperative WE-CT. Contrast-enhanced CT (equilibrium phase) measurements were performed after i.v. injection of smooth muscle relaxant and rectal administration of 400 - 500 ml lukewarm tap water. Quality of the obtained scans was evaluated and the images were analyzed for depth of tumor invasion. Results of the CT examinations were compared to findings at surgery. Results: Despite reduced dose of water enema, 19/29 examinations were of excellent quality, 6/29 good, and 4/29 poor, but still diagnostic. We achieved sensitivity (90.1), specificity (70.1) and accuracy (86.2) in differentiating tumors confined to the bowel wall from those extending beyond it. Conclusion: Large volume of water enema administered during CT examination of the rectum may cause complaints and increases the risk of complications. Our results prove that using lower amount of water does not impair the quality of examination and accuracy of local staging of rectum carcinomas. (orig.) [de

  4. The influence of water disposal method on the property of chemical oil-displacement agent--taking Guan 109-1 area of Dagang oilfield as example

    Directory of Open Access Journals (Sweden)

    Shengwang Yuan

    2018-03-01

    Full Text Available Aiming at the actual demand of Guan 109-1 block in Dagang oilfield, by means of instrumental analysis, chemical analysis, modern physical simulation, viewing polymer viscosity and seepage characteristic as evaluation index, the experimental research on the influence of water disposal method on the property of chemical oil-displacement agent was carried out. Results showed that through adding scaling agent, scale was formed because of the reaction between scaling agent and Ca2+, Mg2+ in the flooding water, which could enhance the viscosity of polymer solution. Through comparing the resistance factor and residual resistance factor of polymer solution which was respectively prepared with flooding water, softened water and scale, the resistance factor and residual resistance factor of polymer solution with scale was the largest, that of polymer solution prepared with softened water was second and that of polymer solution prepared with flooding water came last. Furthermore, scaling agent weakened the gelling effect between cross-linking agent Cr3+ and polymer molecule chains. The earlier the cross-linking agent Cr3+ was added, the larger the polymer viscosity, resistance factor and residual resistance factor of Cr3+ polymer were.

  5. Have Chinese water pricing reforms reduced urban residential water demand?

    Science.gov (United States)

    Zhang, B.; Fang, K. H.; Baerenklau, K. A.

    2017-06-01

    China continues to deal with severe levels of water scarcity and water pollution. To help address this situation, the Chinese central government initiated urban water pricing reforms in 2002 that emphasized the adoption of increasing block rate (IBR) price structures in place of existing uniform rate structures. By combining urban water use records with microlevel data from the Chinese Urban Household Survey, this research investigates the effectiveness of this national policy reform. Specifically, we compare household water consumption in 28 cities that adopted IBR pricing structures during 2002-2009, with that of 110 cities that had not yet done so. Based on difference-in-differences models, our results show that the policy reform reduced annual residential water demand by 3-4% in the short run and 5% in the longer run. These relatively modest reductions are consistent with the generous nature of the IBR pricing structures that Chinese cities have typically chosen to implement. Our results imply that more efforts are needed to address China's persistent urban water scarcity challenges.

  6. Polyvinylpyrrolidone Matrix as an Effective Reducing Agent and Stabilizer during Reception of Silver Nanoparticles in Composites

    OpenAIRE

    Semenyuk, Nataliya; Kostiv, Ulyana; Dudok, Galyna; Nechay, Jaroslav; Skorokhoda, Volodymyr

    2013-01-01

    The use of polyvinylpyrrolidone matrix as an effective reducing agent and stabilizer during reception of silver nanoparticles in composites is substantiated. The influence of various factors on patterns of obtaining silver nanoparticles and their size.

  7. Hierarchically porous, ultra-strong reduced graphene oxide-cellulose nanocrystal sponges for exceptional adsorption of water contaminants

    DEFF Research Database (Denmark)

    Yousefi, Nariman; Wong, Kerwin K.W.; Hosseinidoust, Zeinab

    2018-01-01

    Self-assembly of graphene oxide (GO) nanosheets into porous 3D sponges is a promising approach to exploit their capacity to adsorb contaminants while facilitating the recovery of the nanosheets from treated water. Yet, forming mechanically robust sponges with suitable adsorption properties presents...... a significant challenge. Ultra-strong and highly porous 3D sponges are formed using GO, vitamin C (VC), and cellulose nanocrystals (CNCs) - natural nanorods isolated from wood pulp. CNCs provide a robust scaffold for the partially reduced GO (rGO) nanosheets resulting in an exceptionally stiff nanohybrid....... The concentration of VC as a reducing agent plays a critical role in tailoring the pore architecture of the sponges. By using excess amounts of VC, a unique hierarchical pore structure is achieved, where VC grains act as soft templates for forming millimeter-sized pores, the walls of which are also porous...

  8. Drops of energy: conserving urban water to reduce greenhouse gas emissions.

    Science.gov (United States)

    Zhou, Yuanchun; Zhang, Bing; Wang, Haikun; Bi, Jun

    2013-10-01

    Water and energy are two essential resources of modern civilization and are inherently linked. Indeed, the optimization of the water supply system would reduce energy demands and greenhouse gas emissions in the municipal water sector. This research measured the climatic cobenefit of water conservation based on a water flow analysis. The results showed that the estimated energy consumption of the total water system in Changzhou, China, reached approximately 10% of the city's total energy consumption, whereas the industrial sector was found to be more energy intensive than other sectors within the entire water system, accounting for nearly 70% of the total energy use of the water system. In addition, four sustainable water management scenarios would bring the cobenefit of reducing the total energy use of the water system by 13.9%, and 77% of the energy savings through water conservation was indirect. To promote sustainable water management and reduce greenhouse gas emissions, China would require its water price system, both for freshwater and recycled water, to be reformed.

  9. On-bead combinatorial synthesis and imaging of chemical exchange saturation transfer magnetic resonance imaging agents to identify factors that influence water exchange.

    Science.gov (United States)

    Napolitano, Roberta; Soesbe, Todd C; De León-Rodríguez, Luis M; Sherry, A Dean; Udugamasooriya, D Gomika

    2011-08-24

    The sensitivity of magnetic resonance imaging (MRI) contrast agents is highly dependent on the rate of water exchange between the inner sphere of a paramagnetic ion and bulk water. Normally, identifying a paramagnetic complex that has optimal water exchange kinetics is done by synthesizing and testing one compound at a time. We report here a rapid, economical on-bead combinatorial synthesis of a library of imaging agents. Eighty different 1,4,7,10-tetraazacyclododecan-1,4,7,10-tetraacetic acid (DOTA)-tetraamide peptoid derivatives were prepared on beads using a variety of charged, uncharged but polar, hydrophobic, and variably sized primary amines. A single chemical exchange saturation transfer image of the on-bead library easily distinguished those compounds having the most favorable water exchange kinetics. This combinatorial approach will allow rapid screening of libraries of imaging agents to identify the chemical characteristics of a ligand that yield the most sensitive imaging agents. This technique could be automated and readily adapted to other types of MRI or magnetic resonance/positron emission tomography agents as well.

  10. Alternative Agents to Prevent Fogging in Head and Neck Endoscopy

    Directory of Open Access Journals (Sweden)

    Patorn Piromchai

    2011-01-01

    Full Text Available Background The essential factor for diagnosis and treatment of diseases in head and neck endoscopy is the visibility of the image. An anti-fogging agent can reduce this problem by minimizing surface tension to prevent the condensation of water in the form of small droplets on a surface. There is no report on the use of hibiscrub ® or baby shampoo to reduce fogging in the literature. The objective of this study was to compare the efficacy between commercial anti-fogging agent, hibiscrub ® and baby shampoo to reduce fogging for the use in head and neck endoscopy. Methods The study was conducted at the Department of Otorhinolaryngology, Faculty of Medicine, Khon Kaen University in August 2010. Commercial anti-fogging agent, baby shampoo and hibiscrub ® were applied on rigid endoscope lens before putting them into a mist generator. The images were taken at baseline, 15 seconds, 30 seconds and 1 minute. The images' identifiers were removed before they were sent to two evaluators. A visual analogue scale (VAS was used to rate the image quality from 0 to 10. Results The difference in mean VAS score between anti-fogging agent, baby shampoo and hibiscrub ® versus no agent were 5.46, 4.45 and 2.1 respectively. The commercial anti-fogging agent and baby shampoo had most protective benefit and performed significantly better than no agent ( P < 0.05. Conclusions Baby shampoo is an effective agent to prevent fogging during head and neck endoscopy and compares favourably with commercial anti-fogging agent.

  11. The effects of high-Ca hardness water treatment for secondary cooling water in HANARO

    International Nuclear Information System (INIS)

    Kang, T. J.; Park, Y. C.; Hwang, S. R.; Lim, I. C.; Choi, H. Y.

    2003-01-01

    Water-quality control of the second cooling system in HANARO has been altered from low Ca-hardness treatment to high Ca-hardness treatment since March, 2001. High Ca-hardness water treatment in HANARO is to maintain the calcium hardness around 12 by minimizing the blowdown of secondary cooling water. This paper describes the effect of cost reduction after change of water-quility treatment method. The result shows that the cost of the water could be reduced by 25% using the pond water in KAERI. The amount and cost for the chemical agent could be reduced by 40% and 10% respectively

  12. Water Pricing as an Economic Justification for Reducing Non-Revenue Water (NRW Projects

    Directory of Open Access Journals (Sweden)

    Massoud Tabesh

    2017-03-01

    Full Text Available Management of water demand and modification of consumption patterns are becoming increasingly essential due to the increasingly limited precipitation and the growing population which have led to both severe restrictions on renewable water resources and increasing demands for water in Iran. The most important consumption management measures involve reducing Non-Revenue Water (NRW and decreasing water losses in the water supply system. Non-revenue water is defined as the difference between the total inflow and the metered consumption in the supply system. The losses may be divided into the two components of apparent and real losses. Achieving reductions in non-revenue water calls for the careful study and evaluation of the operational procedures proposed in each case since reductions will be economical only when accurate and realistic values are considered in water pricing. The present study draws upon the data obtained from non-revenue water projects implemented in District 4 of Tehran Water and Wastewater Company, the measures proposed by the project consultant, and the economic justifications claimed for all the costs associated with the measures to eliminate water losses. The cost of the proposed measures are calculated for two different economic values of water proposed to ensure benefits, and under four different interest rates. Results confirm the profitability of the non-revenue water solutions based on the finished cost of water even at subsidized rates of public funds. However, project profitability will be in question if the economic price of water is assumed to be equivalent to the total trade price of water and if both real and apparent losses are to be reduced.

  13. Cold water recovery reduces anaerobic performance.

    Science.gov (United States)

    Crowe, M J; O'Connor, D; Rudd, D

    2007-12-01

    This study investigated the effects of cold water immersion on recovery from anaerobic cycling. Seventeen (13 male, 4 female) active subjects underwent a crossover, randomised design involving two testing sessions 2 - 6 d apart. Testing involved two 30-s maximal cycling efforts separated by a one-hour recovery period of 10-min cycling warm-down followed by either passive rest or 15-min cold water immersion (13 - 14 degrees C) with passive rest. Peak power, total work and postexercise blood lactate were significantly reduced following cold water immersion compared to the first exercise test and the control condition. These variables did not differ significantly between the control tests. Peak exercise heart rate was significantly lower after cold water immersion compared to the control. Time to peak power, rating of perceived exertion, and blood pH were not affected by cold water immersion compared to the control. Core temperature rose significantly (0.3 degrees C) during ice bath immersion but a similar increase also occurred in the control condition. Therefore, cold water immersion caused a significant decrease in sprint cycling performance with one-hour recovery between tests.

  14. In situ generation of silver nanoparticles in poly(vinyl alcohol)/poly(acrylic acid) polymer membranes in the absence of reducing agent and their effect on pervaporation of a water/acetic acid mixture

    International Nuclear Information System (INIS)

    Chaudhard, Shvshankar; Kwon, Yong Sung; Moon, MyungJun; Shon, Min Young; Park, You In; Nam, Seung Eun

    2016-01-01

    The in situ generation of silver nanoparticles in a poly(vinyl alcohol)/poly(acrylic acid) (PVA/PAA) polymer matrix in the absence of any additional reducing agent is reported and tends to the membrane fabrication using solution-casting. Its effect on the separation of a water/acetic acid mixture by pervaporation is described. The results of UV spectroscopy, scanning electron microscopy, and scanning electron microscopy/energy-dispersive X-ray spectroscopy analyses showed that the silver nanoparticles were successfully prepared and well dispersed in the polymer matrix. The increased hydrophilicity of the PVA/PAA membrane due to the presence of silver nanoparticles was confirmed by Fourier transform infrared spectroscopy, contact angle measurements, and membrane absorption studies. Pervaporation data for composite membranes showed a three-fold increase in the flux value, while the initially decreased separation factor subsequently showed a constant value. Overall, the pervaporation data suggested that the presence of silver nanoparticles benefited the dehydration process

  15. In situ generation of silver nanoparticles in poly(vinyl alcohol)/poly(acrylic acid) polymer membranes in the absence of reducing agent and their effect on pervaporation of a water/acetic acid mixture

    Energy Technology Data Exchange (ETDEWEB)

    Chaudhard, Shvshankar; Kwon, Yong Sung; Moon, MyungJun; Shon, Min Young [Dept. of Industrial Chemistry, Pukyong National University, Busan (Korea, Republic of); Park, You In; Nam, Seung Eun [Center for membranes, Korea Research Institute of Chemical Technology, Daejeon (Korea, Republic of)

    2016-12-15

    The in situ generation of silver nanoparticles in a poly(vinyl alcohol)/poly(acrylic acid) (PVA/PAA) polymer matrix in the absence of any additional reducing agent is reported and tends to the membrane fabrication using solution-casting. Its effect on the separation of a water/acetic acid mixture by pervaporation is described. The results of UV spectroscopy, scanning electron microscopy, and scanning electron microscopy/energy-dispersive X-ray spectroscopy analyses showed that the silver nanoparticles were successfully prepared and well dispersed in the polymer matrix. The increased hydrophilicity of the PVA/PAA membrane due to the presence of silver nanoparticles was confirmed by Fourier transform infrared spectroscopy, contact angle measurements, and membrane absorption studies. Pervaporation data for composite membranes showed a three-fold increase in the flux value, while the initially decreased separation factor subsequently showed a constant value. Overall, the pervaporation data suggested that the presence of silver nanoparticles benefited the dehydration process.

  16. Advantages of paramagnetic chemical exchange saturation transfer (CEST) complexes having slow to intermediate water exchange properties as responsive MRI agents.

    Science.gov (United States)

    Soesbe, Todd C; Wu, Yunkou; Dean Sherry, A

    2013-07-01

    Paramagnetic chemical exchange saturation transfer (PARACEST) complexes are exogenous contrast agents that have great potential to further extend the functional and molecular imaging capabilities of magnetic resonance. As a result of the presence of a central paramagnetic lanthanide ion (Ln(3+) ≠ La(3+) , Gd(3+) , Lu(3+) ) within the chelate, the resonance frequencies of exchangeable protons bound to the PARACEST agent are shifted far away from the bulk water frequency. This large chemical shift, combined with an extreme sensitivity to the chemical exchange rate, make PARACEST agents ideally suited for the reporting of significant biological metrics, such as temperature, pH and the presence of metabolites. In addition, the ability to turn PARACEST agents 'off' and 'on' using a frequency-selective saturation pulse gives them a distinct advantage over Gd(3+) -based contrast agents. A current challenge for PARACEST research is the translation of the promising in vitro results into in vivo systems. This short review article first describes the basic theory behind PARACEST contrast agents, their benefits over other contrast agents and their applications to MRI. It then describes some of the recent PARACEST research results: specifically, pH measurements using water molecule exchange rate modulation, T2 exchange contrast caused by water molecule exchange, the use of ultrashort TEs (TE < 10 µs) to overcome T2 exchange line broadening and the potential application of T2 exchange as a new contrast mechanism for MRI. Copyright © 2012 John Wiley & Sons, Ltd.

  17. Improved methods for water shutoff. Annual report, October 1, 1996--September 30, 1997

    Energy Technology Data Exchange (ETDEWEB)

    Seright, R.S.

    1997-11-01

    In the US, more than 20 billion barrels of water are produced each year during oilfield operations. There is a tremendous economic incentive to reduce water production if that can be accomplished without significantly sacrificing hydrocarbon production. In an earlier project, the authors determined that the ability of blocking agents to reduce permeability to water much more than that to oil is critical to the success of these blocking treatments in production wells if zones are not protected during placement of the blocking agent. This research project has three objectives: (1) to identify chemical blocking agents that will during placement, flow readily through fractures without penetrating significantly into porous rock and without screening out or developing excessive pressure gradients and at a predictable and controllable time, become immobile and resist breakdown upon exposure to moderate to high pressure gradients; (2) to identify schemes that optimize placement of blocking agents; and (3) to explain why gels and other chemical blocking agents reduce permeability to one phase (e.g., water) more than that of another phase (e.g., oil or gas). Chapter 2 examines the validity of using water/oil ratio plots to distinguish between coning and channeling water production mechanisms. Chapter 3 develops a method to size gelant treatments in hydraulically fractured production wells. Chapter 4 identifies characteristics of naturally fractured reservoirs where gel treatments have the greatest potential. Chapter 5 reports experimental results from studies of gel properties in fractures. Finally, Chapter 6, the authors investigate the mechanism responsible for gels reducing the permeability to water more than that to oil.

  18. Influence of quenching agent on microstructure, properties and thermal stress of SiC{sub p}/2009 composites

    Energy Technology Data Exchange (ETDEWEB)

    He, Tianbing, E-mail: tianbing_1988@sina.com [Beijing Institute of Aeronautic Materials, Beijing 100095 (China); Beijing Engineering Research Center of Advanced Aluminum Alloys and Application, Beijing 100095 (China); Li, Huiqu; Tang, Pengjun; He, Xiaolei; Li, Peiyong [Beijing Institute of Aeronautic Materials, Beijing 100095 (China); Beijing Engineering Research Center of Advanced Aluminum Alloys and Application, Beijing 100095 (China)

    2016-08-15

    15% vol. SiC{sub p}/2009 composites prepared by powder metallurgy were quenched in room temperature water and 20% polyethylene glycol (PEG) solution respectively, then aged naturally. The influence of quenching agent on microstructure, properties and thermal stress of SiC{sub p}/2009 composites were investigated by means of scanning/transmission electron microscope, hardness and tensile test. The results showed that the number of precipitated phase in water quenched composites increased, with much finer in size and more homogeneous in distribution compared with 20% PEG quenched one. Meanwhile, the density of dislocation in composites by water quenching was also much higher. Intergranular corrosion did not occur with the two quenching agents. The 20% PEG quenched composites exhibited slight lower hardness and higher electrical conductivity than that of water quenched one. The two quenched composites showed same level in tensile strength, but the yield strength of water-quenched composites was higher (8 MPa, 3%). The usage of 20% PEG reduced thermal stress and minimized warping deformation of the parts, it is a more suitable quenching agent for SiC{sub p}/2009 composites in engineering application fields. - Highlights: •SiC{sub p}/2009 composites quenched by water and 20% PEG solution were investigated. •Aging precipitation behavior of SiC{sub p}/2009 composites is sensitive to quenchant. •Influence of quenching agent on properties of SiC{sub p}/2009 composites are minimal. •Quenching with 20% PEG reduces thermal stress of SiC{sub p}/2009 composites remarkably. •20% PEG is a more suitable quenching agent for SiC{sub p}/2009 composites than water.

  19. Rapid and efficient synthesis of soluble graphene nanosheets using N-methyl-p-aminophenol sulfate as a reducing agent

    International Nuclear Information System (INIS)

    Wang Xialie; Wen Xiaohong; Liu Zhanpeng; Tan Yi; Yuan Ye; Zhang Ping

    2012-01-01

    Mass production of soluble graphene still remains a challenge, although several methodologies have been proposed. Here we report a rapid and efficient method for the synthesis of soluble graphene nanosheets (GNSs) with long-term dispersion stability in both aqueous and common organic solvents. Within only 12 min at 95 °C, exfoliated graphite oxide in ammonia solution (pH 10) was reduced to soluble GNSs using N-methyl-p-aminophenol sulfate (metol) as a reducing agent without external stabilizers. The prepared GNSs were characterized by different techniques and a comparison of metol and hydrazine hydrate as reducing agents was made. The results indicated that, with the advantages of being rapid, efficient, inexpensive and relatively environmentally friendly, the reduction of graphite oxide into soluble GNSs by metol is a promising substitute for hydrazine hydrate in the mass production of soluble GNSs. (paper)

  20. Bioleached sludge composting drastically reducing ammonia volatilization as well as decreasing bulking agent dosage and improving compost quality: A case study.

    Science.gov (United States)

    Hu, Weitong; Zheng, Guanyu; Fang, Di; Cui, Chunhong; Liang, Jianru; Zhou, Lixiang

    2015-10-01

    Sludge bioleaching technology with Acidithiobacillus species has been commercially adopted for improving advanced dewatering of sludge in China since 2010. However, up to now, little information on bioleached dewatered sludge (BS) composting is available. Here, we report the changes of physicochemical and biological properties in BS composting and evaluate compost product quality compared to conventional dewatered sludge (CS) composting in an engineering scale composting facility. The results showed that the amount of bulking agents required in BS composting was only about 10% of CS composting to obtain optimum moisture content, reducing about 700 kg bulking agents per ton fresh sludge. pH of BS composting mixture was slightly lower consistently by about 0.2-0.3 pH units than that in CS mixture in the first 30 days. Organic matter biodegradation in BS system mainly occurred in the first 9 days of composting. In spite of higher content of NH4(+)-N was found in BS mixture in related to CS mixture; unexpectedly the cumulative ammonia volatilization in the former was only 51% of the latter, indicating that BS composting drastically reduced nitrogen loss. Compared to CS composting system, the relative lower pH, the higher intensity of microbial assimilation, and the presence of water soluble Fe in BS system might jointly reduce ammonia volatilization. Consequently, BS compost product exhibited higher fertilizer values (N+P2O5+K2O=8.38%) as well as lower heavy metal levels due to the solubilization of sludge-borne heavy metals during bioleaching process. Therefore, composting of BS possesses more advantages over the CS composting process. Copyright © 2015 Elsevier Ltd. All rights reserved.

  1. Agarwood Waste as A New Fluid Loss Control Agent in Water-based Drilling Fluid

    Directory of Open Access Journals (Sweden)

    Azlinda Azizi

    2013-10-01

    Full Text Available Normal 0 false false false IN X-NONE X-NONE MicrosoftInternetExplorer4 Agarwood has been used widely in various ways, including traditional medicine and art. The usage of agarwood has grown broader in modern times include in therapeutic medicines and perfumery. In this paper the agarwood waste has been explored to be used as a fluid loss control agent to control fluid loss without affecting the drilling fluid rheological properties which are density, pH, viscosity, yield point and gel strength. Agarwood waste was used as an additive in the drilling fluid system due to its unique characteristic. Rheological and filtration measurements were performed on the formulated water-based drilling fluid. Formulations of a base solution of fresh water, sodium hydroxide, bentonite, barite, and xanthan gum were presented. The performance of the agarwood waste as the fluid loss control agent was compared with based fluid formulation and water-based drilling fluid with treating with conventional fluid loss control agent (starch. The filtrate volume of drilling fluid with agarwood waste was about 13 ml while for drilling fluid with conventional fluid loss control agent, starch gave 12 ml of filtrate volume after undergoing filtration test by using LPLT filter press. The performance of drilling fluid with agarwood was efficient as drilling fluid with starch. /* Style Definitions */ table.MsoNormalTable {mso-style-name:"Table Normal"; mso-tstyle-rowband-size:0; mso-tstyle-colband-size:0; mso-style-noshow:yes; mso-style-priority:99; mso-style-qformat:yes; mso-style-parent:""; mso-padding-alt:0cm 5.4pt 0cm 5.4pt; mso-para-margin:0cm; mso-para-margin-bottom:.0001pt; mso-pagination:widow-orphan; font-size:11.0pt; font-family:"Calibri","sans-serif"; mso-ascii-font-family:Calibri; mso-ascii-theme-font:minor-latin; mso-fareast-font-family:"Times New Roman"; mso-fareast-theme-font:minor-fareast; mso-hansi-font-family:Calibri; mso-hansi-theme-font:minor-latin; mso

  2. An effective way to reduce water absorption to terahertz

    Science.gov (United States)

    Wu, Yaxiong; Su, Bo; He, Jingsuo; Zhang, Cong; Zhang, Hongfei; Zhang, Shengbo; Zhang, Cunlin

    2018-01-01

    Since many vibrations and rotational levels of biomolecules fall within the THz band, THz spectroscopy can be used to identify biological samples. In addition, most biomolecules need to maintain their biological activity in a liquid environment, but water as polar substance has strong absorption to the THz wave. Thus, it is difficult to detect the sample information in aqueous solution using THz wave. In order to prevent the information of biological samples were masked in the solution, many research methods were used to explore how to reduce the water absorption of terahertz. In this paper, we have developed a real-time chemical methodology through transmission Terahertz time-domain spectroscopy (THz-TDS) system. The material of Zeonor 1020r is used as substrate and cover plate, and PDMS as channel interlayer. The transmission of the empty microfluidic chip is more than 80% in the range of 0.2-2.6 THz by THz-TDS system. Then, experiments were carried out using chips, which were filled with different volumes of 1, 2- propanediol, and it has been proved that the microfluidic chip could reduce the water absorption of terahertz. Finally, in order to further explore the reduction of terahertz to water absorption, we inject different concentrations of electrolyte to the chip. The results show that with the addition of different electrolytes, terahertz transmission line has evident changes. It can be taken into account that the electrolyte has different effects about the hydrogen bonds in the aqueous solution. Some of them can promote water molecules clusters, while others destroy them. Based on the basis of microfluidic chip, the discovery of this phenomenon can provide a way that reduces water absorption of terahertz. This work has laid a solid foundation for the subsequent study in reducing water absorption of terahertz.

  3. Effect of Dolomite as Expansive Agent and Shrinkage Reducing Admixture in Self-Compacting Shrinkage – Compensating Concrete

    OpenAIRE

    Qosai Sahib Radi Marshdi; Ahlam Hamid Jasim; Haider Abass Obeed

    2018-01-01

    The principle of using expansive agents has been recommended to manufacture shrinkage compensating concrete provided that an adequate wet curing is carried out. On the other hand, shrinkage-reducing admixture (SRA) in the concrete mixes, has been more recently suggested to reduce the risk of cracking in concrete structures caused by drying shrinkage. This paper is devoted to the study of the influence of complex modifier in the form of superplasticizer, shrinkage reducing admixture and e...

  4. Sodium metabisulfite: a new reducer agent for direct labelling of immunoglobulins with 99mTc

    International Nuclear Information System (INIS)

    Zayas, F.; Hernandez, T.; Rodriguez, M.E.; Perera, A.; Hernandez, L.; Valdes, M.

    1998-01-01

    A method for direct labeling of antibodies with 99mTc is described. Sodium Metabisulfite (SMB) was evaluated as a new reducing agent of disulfide bridges of the IgG molecule. Under selected experimental conditions, radiochemical purities of the label higher than 90.0% were achieved in most of the experiments. On the basis of the obtained yields an empiric equation which describes the system was computed as: Y=93.6+2.1X5 - 1.36X6+0.9X7. The absence of X4 indicated that the purification on Sephadex of the reduced IgG was not relevant to the labeling process. The most important variables were tin ion concentration (X5), the volume of Tin-Tartrate solution (X6) and the incubating time between reduced IgG and Tin-Tartrate solution (X7). A low aggregation and fragmentation of the IgG molecule was obtained when a SMB/IgG molar relation of 750/1 was used. The stability of the 99mTc-IgG was assessed by DTPA, HSA and L-Cysteine challenge studies. An acceptable level of dissociation was observed in presence of DTPA and L-Cysteine, when the Tartrate anion was used. However the transchelation level for HSA was about 80.0 per cent. These preliminary results showed that SMB could be a useful reducing agent for direct labeling of IgG. Further studies are needed to correctly evaluate it. (author)

  5. Synthesis of Silver-Chitosan Nanocomposites Colloidal by Glucose as Reducing Agent

    Directory of Open Access Journals (Sweden)

    Endang Susilowati

    2015-03-01

    Full Text Available Silver-chitosan nanocomposites colloidal was successfully performed by chemical reduction method at room temperature using glucose as reducing agent, sodium hydroxide (NaOH as accelerator reagent, silver nitrate (AgNO3 as metal precursor and chitosan as stabilizing agent. Compared to other synthetic methods, this work is green and simple. The effect of the amount of NaOH, molar ratio of AgNO3 to glucose and AgNO3 concentration towards Localized Surface Plasmon Resonance (LSPR absorption band of silver nanoparticles was investigated using UV-Vis spectrophotometer. The stability of the colloid was also studied for the first 16 weeks of storage at ambient temperature. The formation of silver nanoparticles was confirmed by the appearance of LSPR absorption peak at 402.4–414.5 nm. It is also shown that the absorption peak of LSPR were affected by NaOH amount, ratio molar AgNO3/glucose and concentration of AgNO3. The produced silver nanoparticles were spherical with dominant size range of 6 to 18 nm as shown by TEM images. All colloidals were stable without any aggregation for 16 weeks after preparation. The newly prepared silver-chitosan nanocomposites colloidal may have potential for antibacterial applications.

  6. Maintenance of water uptake and reduced water loss contribute to water stress tolerance of Spiraea alba Du Roi and Spiraea tomentosa L.

    Science.gov (United States)

    Stanton, Kelly M; Mickelbart, Michael V

    2014-01-01

    Two primarily eastern US native shrubs, Spiraea alba Du Roi and Spiraea tomentosa L., are typically found growing in wet areas, often with standing water. Both species have potential for use in the landscape, but little is known of their environmental requirements, including their adaptation to water stress. Two geographic accessions of each species were evaluated for their response to water stress under greenhouse conditions. Above-ground biomass, water relations and gas exchange were measured in well-watered and water stress treatments. In both species, water stress resulted in reduced growth, transpiration and pre-dawn water potential. However, both species also exhibited the ability to osmotically adjust to lower soil water content, resulting in maintained midday leaf turgor potential in all accessions. Net CO2 assimilation was reduced only in one accession of S. alba, primarily due to large reductions in stomatal conductance. S. tomentosa lost a larger proportion of leaves than S. alba in response to water stress. The primary water stress tolerance strategies of S. alba and S. tomentosa appear to be the maintenance of water uptake and reduced water loss.

  7. A multi-agent design for a pressurized water reactor (P.W.R.) control system

    International Nuclear Information System (INIS)

    Aimar-Lichtenberger, M.

    1999-01-01

    This PhD work is in keeping with the complex industrial process control. The starting point is the analysis of control principles in a Pressurized Water Reactor (P.W.R). In order to cope with the limits of the present control procedures, a new control organisation by objectives and means is defined. This functional organisation is based on the state approach and is characterized by the parallel management of control functions to ensure the continuous control of the installation essential variables. With regard to this complex system problematic, we search the most adapted computer modeling. We show that a multi-agent system approach brings an interesting answer to manage the distribution and parallelism of control decisions and tasks. We present a synthetic study of multi-agent systems and their application fields.The choice of a multi-agent approach proceeds with the design of an agent model. This model gains experiences from other applications. This model is implemented in a computer environment which combines the mechanisms of an object language with Prolog. We propose in this frame a multi-agent modeling of the control system where each function is represented by an agent. The agents are structured in a hierarchical organisation and deal with different abstraction levers of the problem. Following a prototype process, the validation is realized by an implementation and by a coupling to a reactor simulator. The essential contributions of an agent approach turn on the mastery of the system complexity, the openness, the robustness and the potentialities of human-machine cooperation. (author)

  8. Advances in Nuclear Power Plant Water Chemistry in Reducing Radiation Exposure

    International Nuclear Information System (INIS)

    Febrianto

    2005-01-01

    Water quality in light water reactor in Pressurized Water Reactor as well as in Boiling Water Reactor has being gradually improved since the beginning, to reduce corrosion risk and radiation exposure level. Corrosion problem which occurred to both type of reactors can reduce the plants availability, increase the operation and maintenance cost and increase the radiation exposure. Corrosion and radiation exposure risk in both reactor rare different. BWR type reactor has more experiences in corrosion problem because at the type of reactor lets water to boil in the core, while at PWR type reactor, water is kept not to boil. The BWR reactor has also higher radiation exposure rather than the PWR one. Many collaborative efforts of plants manufacturers and plant operator utilities have been done to reduce the radiation exposure level and corrosion risk. (author)

  9. Effect of different bulking agents on water variation and thermal balance and their respective contribution to bio-generated heat during long-term storage sludge biodrying process.

    Science.gov (United States)

    Liu, Tiantian; Cui, Chongwei; He, Junguo; Tang, Jian

    2018-04-17

    Biodrying was first used for the post-treatment of long-term storage sludge with vinasse as bulking agents. The effect of different bulking agents on water and heat variation and their respective contributions to bio-generated heat during storage sludge biodrying were investigated. Three different bulking agents (beer lees and distillers grains, with conventional straw used for comparison) were mixed with storage sludge for biodrying for an 18-day period. The results revealed the treatment with beer lees as bulking agent achieved the best performance with the highest water removal capacity (658 g kg -1 initial water). The extent of organic degradation in the mixture was related to the degradation ability of the bulking agents. The degradation of C- and H-containing materials (e.g., carboxylic acid) accounted for volatile solids (VS) loss. Water and thermal analyses showed that evaporation was the main way of water loss (accounting for 90%), while evaporation heat was the main component of heat consumption (accounting for 56.67-60.62%).The biodegradation of bulking agents contributed a high proportion of the bio-generated heat consumed by water evaporation (82.35-86.67%).

  10. In-situ methylation of strongly polar organic acids in natural waters supported by ion-pairing agents for headspace GC-MSD analysis

    Energy Technology Data Exchange (ETDEWEB)

    Neitzel, P.L.; Walther, W. [Dresden University of Technology, Institute for Groundwater Managemant, Dresden (Germany); Nestler, W. [Institute for Technology and Economics, Department of Civil Engineering and Architecture, Dresden (Germany)

    1998-06-01

    Strongly polar organic substances like halogenated acetic acids have been analyzed in surface water and groundwater in the catchment area of the upper Elbe river in Saxony since 1992. Coming directly from anthropogenic sources like industry, agriculture and indirectly by rainfall, their concentrations can increase up to 100 {mu}g/L in the aquatic environment of this catchment area. A new static headspace GC-MSD method without a manual pre-concentration step is presented to analyze the chlorinated acetic acids relevant to the Elbe river as their volatile methyl esters. Using an ion-pairing agent as modifier for the in-situ methylation of the analytes by dimethylsulfate, a minimal detection limit of 1 {mu}g/L can be achieved. Problems like the thermal degradation of chlorinated acetic acids to halogenated hydrocarbons and changing reaction yields during the headspace methylation, could be effectively reduced. The method has been successfully applied to monitoring bank infiltrate, surface water, groundwater and water works pumped raw water according to health provision principles. (orig.) With 3 figs., 2 tabs., 29 refs.

  11. Conceptual designing of reduced-moderation water reactor with heavy water coolant

    Energy Technology Data Exchange (ETDEWEB)

    Hibi, Kohki; Shimada, Shoichiro; Okubo, Tsutomu E-mail: okubo@hems.jaeri.go.jp; Iwamura, Takamichi; Wada, Shigeyuki

    2001-12-01

    The conceptual designing of reduced-moderation water reactors, i.e. advanced water-cooled reactors using plutonium mixed-oxide fuel with high conversion ratios more than 1.0 and negative void reactivity coefficients, has been carried out. The core is designed on the concept of a pressurized water reactor with a heavy water coolant and a triangular tight lattice fuel pin arrangement. The seed fuel assembly has an internal blanket region inside the seed fuel region as well as upper and lower blanket regions (i.e. an axial heterogeneous core). The radial blanket fuel assemblies are introduced in a checkerboard pattern among the seed fuel assemblies (i.e. a radial heterogeneous core). The radial blanket region is shorter than the seed fuel region. This study shows that the heavy water moderated core can achieve negative void reactivity coefficients and conversion ratios of 1.06-1.11.

  12. Sensitivity Analysis in Agent-Based Models of Socio-Ecological Systems: An Example in Agricultural Land Conservation for Lake Water Quality Improvement

    Science.gov (United States)

    Ligmann-Zielinska, A.; Kramer, D. B.; Spence Cheruvelil, K.; Soranno, P.

    2012-12-01

    Socio-ecological systems are dynamic and nonlinear. To account for this complexity, we employ agent-based models (ABMs) to study macro-scale phenomena resulting from micro-scale interactions among system components. Because ABMs typically have many parameters, it is challenging to identify which parameters contribute to the emerging macro-scale patterns. In this paper, we address the following question: What is the extent of participation in agricultural land conservation programs given heterogeneous landscape, economic, social, and individual decision making criteria in complex lakesheds? To answer this question, we: [1] built an ABM for our model system; [2] simulated land use change resulting from agent decision making, [3] estimated the uncertainty of the model output, decomposed it and apportioned it to each of the parameters in the model. Our model system is a freshwater socio-ecological system - that of farmland and lake water quality within a region containing a large number of lakes and high proportions of agricultural lands. Our study focuses on examining how agricultural land conversion from active to fallow reduces freshwater nutrient loading and improves water quality. Consequently, our ABM is composed of farmer agents who make decisions related to participation in a government-sponsored Conservation Reserve Program (CRP) managed by the Farm Service Agency (FSA). We also include an FSA agent, who selects enrollment offers made by farmers and announces the signup results leading to land use change. The model is executed in a Monte Carlo simulation framework to generate a distribution of maps of fallow lands that are used for calculating nutrient loading to lakes. What follows is a variance-based sensitivity analysis of the results. We compute sensitivity indices for individual parameters and their combinations, allowing for identification of the most influential as well as the insignificant inputs. In the case study, we observe that farmland

  13. Chemical nickel plating in tartrate solutions with borohydride reducing agent

    International Nuclear Information System (INIS)

    Plokhov, V.A.

    1986-01-01

    The authors investigate the influence of various factors on the rate of chemical nickel plating in strongly alkaline tartrate solutions with a borohydride reducing agent. After 30 min of the process of nickel plating, the final concentration of sodium borohydride decreases to 0.26 g/liter, leading to stoppage of the process. The nickel plating process can be intensified by increasing the concentration of sodium hydroxide in the solution, suppressing hydrolysis of borohydride, and also by introducing additives which suppress hydrolysis of borohydride. For chemical deposition of nickel-boron coatings from tartrate solutions the authors recommend the following composition (g/liter): nickel chloride 15-25, Rochelle salt 450-550, sodium hydroxide 140-160, sodium borohydride 0.8-1.0, thallium nitrate 0.003-0.008. The process temperature is 92-95 C, and the deposition rate is 4-6 um/h

  14. Exploring Tradeoffs in Demand-Side and Supply-Side Management of Urban Water Resources Using Agent-Based Modeling and Evolutionary Computation

    Directory of Open Access Journals (Sweden)

    Lufthansa Kanta

    2015-11-01

    Full Text Available Urban water supply systems may be managed through supply-side and demand-side strategies, which focus on water source expansion and demand reductions, respectively. Supply-side strategies bear infrastructure and energy costs, while demand-side strategies bear costs of implementation and inconvenience to consumers. To evaluate the performance of demand-side strategies, the participation and water use adaptations of consumers should be simulated. In this study, a Complex Adaptive Systems (CAS framework is developed to simulate consumer agents that change their consumption to affect the withdrawal from the water supply system, which, in turn influences operational policies and long-term resource planning. Agent-based models are encoded to represent consumers and a policy maker agent and are coupled with water resources system simulation models. The CAS framework is coupled with an evolutionary computation-based multi-objective methodology to explore tradeoffs in cost, inconvenience to consumers, and environmental impacts for both supply-side and demand-side strategies. Decisions are identified to specify storage levels in a reservoir that trigger: (1 increases in the volume of water pumped through inter-basin transfers from an external reservoir; and (2 drought stages, which restrict the volume of water that is allowed for residential outdoor uses. The proposed methodology is demonstrated for Arlington, Texas, water supply system to identify non-dominated strategies for an historic drought decade. Results demonstrate that pumping costs associated with maximizing environmental reliability exceed pumping costs associated with minimizing restrictions on consumer water use.

  15. Feedback mechanisms between water availability and water use in a semi-arid river basin: a geographically explicit multi-agent simulation approach

    NARCIS (Netherlands)

    van Oel, P.R.; Krol, Martinus S.; Hoekstra, Arjen Ysbert; Taddei, Renzo R.

    2010-01-01

    Understanding the processes responsible for the distribution of water availability over space and time is of great importance to spatial planning in a semi-arid river basin. In this study the usefulness of a multi-agent simulation (MAS) approach for representing these processes is discussed. A MAS

  16. Optimizing contrast agents with respect to reducing beam hardening in nonmedical X-ray computed tomography experiments.

    Science.gov (United States)

    Nakashima, Yoshito; Nakano, Tsukasa

    2014-01-01

    Iodine is commonly used as a contrast agent in nonmedical science and engineering, for example, to visualize Darcy flow in porous geological media using X-ray computed tomography (CT). Undesirable beam hardening artifacts occur when a polychromatic X-ray source is used, which makes the quantitative analysis of CT images difficult. To optimize the chemistry of a contrast agent in terms of the beam hardening reduction, we performed computer simulations and generated synthetic CT images of a homogeneous cylindrical sand-pack (diameter, 28 or 56 mm; porosity, 39 vol.% saturated with aqueous suspensions of heavy elements assuming the use of a polychromatic medical CT scanner. The degree of cupping derived from the beam hardening was assessed using the reconstructed CT images to find the chemistry of the suspension that induced the least cupping. The results showed that (i) the degree of cupping depended on the position of the K absorption edge of the heavy element relative to peak of the polychromatic incident X-ray spectrum, (ii) (53)I was not an ideal contrast agent because it causes marked cupping, and (iii) a single element much heavier than (53)I ((64)Gd to (79)Au) reduced the cupping artifact significantly, and a four-heavy-element mixture of elements from (64)Gd to (79)Au reduced the artifact most significantly.

  17. Water-soluble organo-building blocks of aminoclay as a soil-flushing agent for heavy metal contaminated soil

    International Nuclear Information System (INIS)

    Lee, Young-Chul; Kim, Eun Jung; Ko, Dong Ah; Yang, Ji-Won

    2011-01-01

    Highlights: ► Aminoclays have synthesized using centered metals with aminopropyl silane. ► Developed aminoclay has unique nano-sized and water-soluble properties. ► Aminoclay showed high heavy metal capacity with metal ions and its less toxicity. ► Aminoclay could be used to remediate heavy metals from soils an alternative soil-flushing agent. - Abstract: We demonstrated that water-soluble aminopropyl magnesium functionalized phyllosilicate could be used as a soil-flushing agent for heavy metal contaminated soils. Soil flushing has been an attractive means to remediate heavy metal contamination because it is less disruptive to the soil environment after the treatment was performed. However, development of efficient and non-toxic soil-flushing agents is still required. We have synthesized aminoclays with three different central metal ions such as magnesium, aluminum, and ferric ions and investigated applicability of aminoclays as soil flushing agents. Among them, magnesium (Mg)-centered aminoclay showed the smallest size distribution and superior water solubility, up to 100 mg/mL. Mg aminoclay exhibited cadmium and lead binding capacity of 26.50 and 91.31 mg/g of Mg clay, respectively, at near neutral pH, but it showed negligible binding affinity to metals in acidic conditions. For soil flushing with Mg clay at neutral pH showed cadmium and lead were efficiently extracted from soils by Mg clay, suggesting strong binding ability of Mg clay with cadmium and lead. As the organic matter and clay compositions increased in the soil, the removal efficiency by Mg clay decreased and the operation time increased.

  18. Synergistic Effects of Bacillus amyloliquefaciens (GB03) and Water Retaining Agent on Drought Tolerance of Perennial Ryegrass.

    Science.gov (United States)

    Su, An-Yu; Niu, Shu-Qi; Liu, Yuan-Zheng; He, Ao-Lei; Zhao, Qi; Paré, Paul W; Li, Meng-Fei; Han, Qing-Qing; Ali Khan, Sardar; Zhang, Jin-Lin

    2017-12-11

    Water retaining agent (WRA) is widely used for soil erosion control and agricultural water saving. Here, we evaluated the effects of the combination of beneficial soil bacterium Bacillus amyloliquefaciens strain GB03 and WRA (the compound is super absorbent hydrogels) on drought tolerance of perennial ryegrass ( Lolium perenne L.). Seedlings were subjected to natural drought for maximum 20 days by stopping watering and then rewatered for seven days. Plant survival rate, biomass, photosynthesis, water status and leaf cell membrane integrity were measured. The results showed that under severe drought stress (20-day natural drought), compared to control, GB03, WRA and GB03+WRA all significantly improved shoot fresh weight, dry weight, relative water content (RWC) and chlorophyll content and decreased leaf relative electric conductivity (REC) and leaf malondialdehyde (MDA) content; GB03+WRA significantly enhanced chlorophyll content compared to control and other two treatments. Seven days after rewatering, GB03, WRA and GB03+WRA all significantly enhanced plant survival rate, biomass, RWC and maintained chlorophyll content compared to control; GB03+WRA significantly enhanced plant survival rate, biomass and chlorophyll content compared to control and other two treatments. The results established that GB03 together with water retaining agent promotes ryegrass growth under drought conditions by improving survival rate and maintaining chlorophyll content.

  19. Sunlight-assisted synthesis of colloidal silver nanoparticles using chitosan as reducing agent

    Science.gov (United States)

    Susilowati, E.; Maryani; Ashadi

    2018-04-01

    The present study we explore an environmentally friendly colloidal silver nanoparticles preparation using chitosan as reducing agent and stabilizer. It develops a new strategy on preparation of silver nanoparticles through the gel phase using sodium hydroxide (NaOH) as accelerator reagent. Sunlight irradiation was employed to assisted reducing process of silver ions to silver nanoparticles. Localized surface plasmon resonance (LSPR) phenomenon of silver nanoparticles was investigated using UV-Vis spectrophotometer. The shape and size of silver particles were analyzed using TEM. The formation of silver nanoparticles was confirmed by the appearance of LSPR absorption peak at 396.0–412.0 nm. The absorption peak of LSPR were affected by NaOH amount, time of sulight irradiation and concentration of AgNO3. The produced silver nanoparticles were spherical with dominant size range of 5 to 8 nm as shown by TEM images. All colloidals were stable without any aggregation for 30 days after preparation.

  20. Preparation of glucoheptonate - sup(99m) Tc using stannous ascorbate as reducing agent for TcO-4 ion

    International Nuclear Information System (INIS)

    Barboza, M.R.F.F. de; Silva, C.P.G. da.

    1983-12-01

    A preparation procedure of stannous ascorbate in lyophilized form is presented. This reducing agent was employed for the preparation of kits of calcium glucoheptonate (GHA) to be labelled with sup(99m) Tc for use in kidney scintigraphy. Comparative studies between kits prepared with stannous ascorbate and those prepared with stannous chloride as reducing agent were made. The labelling yield during 18 hours after the addition of sup(99m) TcO - 4 was higher when stannous ascorbate was used. The stability of kits of calcium glucoheptonate - sup(99m) Tc containing stannous ascorbate was studied during five months after its preparation in the lyophilized form. On the fifth month the labelling yield of GHA - sup(99m) Tc was 89-95%, being therefore suitable for kidney scintigraphy. (Author) [pt

  1. Water conservation benefits of urban heat mitigation: can cooling strategies reduce water consumption in California?

    Science.gov (United States)

    Vahmani, P.; Jones, A. D.

    2017-12-01

    Urban areas are at the forefront of climate mitigation and adaptation efforts given their high concentration of people, industry, and infrastructure. Many cities globally are seeking strategies to counter the consequences of both a hotter and drier climate. While urban heat mitigation strategies have been shown to have beneficial effects on health, energy consumption, and greenhouse gas emissions, their implications for water conservation have not been widely examined. Here we show that broad implementation of cool roofs, an urban heat mitigation strategy, not only results in significant cooling of air temperature, but also meaningfully decreases outdoor water consumption by reducing evaporative and irrigation water demands. Based on a suite of satellite-supported, multiyear regional climate simulations, we find that cool roof adoption has the potential to reduce outdoor water consumption across the major metropolitan areas in California by up to 9%. Irrigation water savings per capita, induced by cool roofs, range from 1.8 to 15.4 gallons per day across 18 counties examined. Total water savings in Los Angeles county alone is about 83 million gallons per day. While this effect is robust across the 15 years examined (2001-2015), including both drought and non-drought years, we find that cool roofs are most effective during the hottest days of the year, indicating that they could play an even greater role in reducing outdoor water use in a hotter future climate. We further show that this synergistic relationship between heat mitigation and water conservation is asymmetrical - policies that encourage direct reductions in irrigation water use can lead to substantial regional warming, potentially conflicting with heat mitigation efforts designed to counter the effects of the projected warming climate.

  2. Algal bloom sedimentation induces variable control of lake eutrophication by phosphorus inactivating agents

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Changhui [State Key Laboratory of Lake Science and Environment, Nanjing Institute of Geography and Limnology, Chinese Academy of Sciences, Nanjing 210008 (China); Bai, Leilei [State Key Laboratory of Lake Science and Environment, Nanjing Institute of Geography and Limnology, Chinese Academy of Sciences, Nanjing 210008 (China); Graduate University of Chinese Academy of Sciences (China); Jiang, He-Long, E-mail: hljiang@niglas.ac.cn [State Key Laboratory of Lake Science and Environment, Nanjing Institute of Geography and Limnology, Chinese Academy of Sciences, Nanjing 210008 (China); Xu, Huacheng [State Key Laboratory of Lake Science and Environment, Nanjing Institute of Geography and Limnology, Chinese Academy of Sciences, Nanjing 210008 (China)

    2016-07-01

    Lake eutrophication typically occurs with a syndrome of algae breeding and biomass accumulation (e.g., algal blooms). Therefore, the effect of algal bloom sedimentation on eutrophication control by phosphorus (P) inactivating agents was assessed herein. Three commercial products, including aluminum (Al) sulfate, iron (Fe) sulfate, and a lanthanum-modified clay (Phoslock®), as well as one easily available by-product, drinking water treatment residue (DWTR), were selected. The most important finding was that during algae sedimentation, P immobilization from the overlying water by Al, Phoslock®, and DWTR was dominated by a long-term slow phase (> 150 d), while Fe has limited effectiveness on the immobilization. Further analysis indicated that the algae sedimentation effect was mainly due to the slow release of P from algae, leading to relatively limited P available for the inactivating agents. Then, a more unfavorable effect on the P immobilization capability of inactivating agents was caused by the induced anaerobic conditions, the released organic matter from algae, and the increased sulfide in the overlying water and sediments during sedimentation. Overall, algae sedimentation induced variable control of eutrophication by P inactivating agents. Accordingly, recommendations for future works about algal lake restoration were also proposed. - Highlights: • A long-term P immobilization by Phoslock®, DWTR, and Al was observed. • Fe had limited effectiveness on P pollution control for overlying water. • Al and Fe enhanced sulfur reduction, while DWTR and Phoslock® had minor effect. • The sedimentation reduced Al and La release from agents, but enhanced Fe release. • The agents changed organic matter compositions and structures in water columns.

  3. Algal bloom sedimentation induces variable control of lake eutrophication by phosphorus inactivating agents

    International Nuclear Information System (INIS)

    Wang, Changhui; Bai, Leilei; Jiang, He-Long; Xu, Huacheng

    2016-01-01

    Lake eutrophication typically occurs with a syndrome of algae breeding and biomass accumulation (e.g., algal blooms). Therefore, the effect of algal bloom sedimentation on eutrophication control by phosphorus (P) inactivating agents was assessed herein. Three commercial products, including aluminum (Al) sulfate, iron (Fe) sulfate, and a lanthanum-modified clay (Phoslock®), as well as one easily available by-product, drinking water treatment residue (DWTR), were selected. The most important finding was that during algae sedimentation, P immobilization from the overlying water by Al, Phoslock®, and DWTR was dominated by a long-term slow phase (> 150 d), while Fe has limited effectiveness on the immobilization. Further analysis indicated that the algae sedimentation effect was mainly due to the slow release of P from algae, leading to relatively limited P available for the inactivating agents. Then, a more unfavorable effect on the P immobilization capability of inactivating agents was caused by the induced anaerobic conditions, the released organic matter from algae, and the increased sulfide in the overlying water and sediments during sedimentation. Overall, algae sedimentation induced variable control of eutrophication by P inactivating agents. Accordingly, recommendations for future works about algal lake restoration were also proposed. - Highlights: • A long-term P immobilization by Phoslock®, DWTR, and Al was observed. • Fe had limited effectiveness on P pollution control for overlying water. • Al and Fe enhanced sulfur reduction, while DWTR and Phoslock® had minor effect. • The sedimentation reduced Al and La release from agents, but enhanced Fe release. • The agents changed organic matter compositions and structures in water columns.

  4. [Interference for Various Quench Agents of Chemical Disinfectants on Detection of Endotoxin Activities in Water].

    Science.gov (United States)

    Zhang, Can; Liu, Wen-jun; Shi, Yun; An, Dai-zhi; Bai, Miao; Xu, Wen

    2015-05-01

    The quenching agents such as histidine, glycine, ascorbic acid, Tween-80, sodium sulfite and sodium hyposulfite are commonly used for quenching the residual disinfectant in water. In this paper, in order to select the optimal type and concentration range of quenching agents prior to the Limulus assays, the interference effects of each quenching agent at different concentrations on endotoxin detection were investigated by the Limulus assays of kinetic-turbidity. Our results identified that, as for 0-1.0% concentration of histidine, ascorbic acid, Tween-80, sodium sulfite (pH unadjusted and pH neutral), interference on the Limulus assays was existed. Hence, these quenching agents could not be applied as neutralizers prior to Limulus assays. Although, there was no interference on endotoxin detection for the glycine, a yellow color, developed by the quenching products of glycine and glutaric dialdehyde, contributed to false positive results. Hence, glycine should not be used as quenching agents in Limulus assays for samples containing glutaric dialdehyde. Compared with other quenching agents as histidine, glycine, ascorbic acid, Tween-80, sodium sulfite, 0-1.0% concentration of sodium hyposulfite elicited no obvious interference, while 1.0%-5.0% concentration of sodium hyposulfite illustrated exhibition effect for endotoxin detection. All in all, compared with other quenching agents as histidine, glycine, ascorbic acid, Tween-80 and sodium sulfite, sodium hyposulfite is suitable for quenching chemicals prior to endotoxin detection and less than 0.5% of concentration is allowable.

  5. Water hammer reduces fouling during natural water ultrafiltration.

    Science.gov (United States)

    Broens, F; Menne, D; Pothof, I; Blankert, B; Roesink, H D W; Futselaar, H; Lammertink, R G H; Wessling, M

    2012-03-15

    Today's ultrafiltration processes use permeate flow reversal to remove fouling deposits on the feed side of ultrafiltration membranes. We report an as effective method: the opening and rapid closing of a valve on the permeate side of an ultrafiltration module. The sudden valve closure generates pressure fluctuations due to fluid inertia and is commonly known as "water hammer". Surface water was filtrated in hollow fiber ultrafiltration membranes with a small (5%) crossflow. Filtration experiments above sustainable flux levels (>125 l (m2h)(-1)) show that a periodic closure of a valve on the permeate side improves filtration performance as a consequence of reduced fouling. It was shown that this effect depends on flux and actuation frequency of the valve. The time period that the valve was closed proved to have no effect on filtration performance. The pressure fluctuations generated by the sudden stop in fluid motion due to the valve closure are responsible for the effect of fouling reduction. High frequency recording of the dynamic pressure evolution shows water hammer related pressure fluctuations to occur in the order of 0.1 bar. The pressure fluctuations were higher at higher fluxes (higher velocities) which is in agreement with the theory. They were also more effective at higher fluxes with respect to fouling mitigation. Copyright © 2011 Elsevier Ltd. All rights reserved.

  6. Studies on silicone based antifoaming agents to be used in G.S. (Girlder sulfide) heavy water plants

    International Nuclear Information System (INIS)

    Delfino, C.A.

    1986-01-01

    In Girlder sulfide (G.S.) heavy water plants hydrogen sulfide-water systems are inherentely foaming, so the adding of antifoaming materials is of great importance. These may be of high volatility, pyrolizable or chemically unstable in plant operation conditions (water and hydrogen sulfide at 2MPa, up to 230 deg C). Six commercial silicone based antifoaming agents were studied from the point of view of their chemical and thermical stability in order to select the most suitable. (Author) [es

  7. Efficiency of Composite Binders with Antifreezing Agents

    Science.gov (United States)

    Ogurtsova, Y. N.; Zhernovsky, I. V.; Botsman, L. N.

    2017-11-01

    One of the non-heating methods of cold-weather concreting is using concretes hardening at negative temperatures. This method consists in using chemical additives which reduce the freezing temperature of the liquid phase and provide for concrete hardening at negative temperatures. The non-heating cold-weather concreting, due to antifreezing agents, allows saving heat and electric energy at the more flexible work performance technology. At selecting the antifreezing components, the possibility of concreting at temperatures up to minus 20 °C and combination with a plasticizer contained in the composite binder were taken into account. The optimal proportions of antifreezing and complex agents produced by MC-Bauchemie Russia for fine-grained concretes were determined. So, the introduction of antifreezing and complex agents allows obtaining a structure of composite characteristic for cement stone in the conditions of below zero temperatures at using different binders; the hydration of such composite proceeded naturally. Low-water-demand binders (LWDB) based composites are characterized by a higher density and homogeneity due to a high dispersity of a binder and its complicated surface providing for a lot of crystallization centers. LWDB contains small pores keeping water in a liquid form and promoting a more complete hydration process.

  8. Role of reducing agent in extraction of arsenic and heavy metals from soils by use of EDTA.

    Science.gov (United States)

    Kim, Eun Jung; Jeon, Eun-Ki; Baek, Kitae

    2016-06-01

    Although many metal-contaminated sites contain both anionic arsenic and cationic heavy metals, the current remediation technologies are not effective for the simultaneous removal of both anionic and cationic elements from the contaminated sites due to their different characteristics. In this study, the role of reducing agent in simultaneous extraction of As, Cu, Pb, and Zn from contaminated soils was investigated using EDTA. The addition of reducing agents, which includes sodium oxalate (Na2C2O4), ascorbic acid (C6H8O6) and sodium dithionite (Na2S2O4), greatly enhanced the EDTA extraction of both As and heavy metals from the contaminated soils due to the increased mobility of the metals under the reduced conditions. The extent of the enhancement of the EDTA extraction was greatly affected by the reducing conditions. Strong reducing conditions (0.1 M of dithionite) were required for the extraction of metals strongly bound to the soil, while weak reducing conditions (0.01 M of dithionite or 0.1 M of oxalate/ascorbic acid) were sufficient for extraction of metals that were relatively weakly bound to the soil. An almost 90% extraction efficiency of total metals (As, Cu, Zn, and Pb) was obtained from the contaminated soils using the combination of dithionite and EDTA. Our results clearly showed that the combination of dithionite and EDTA can effectively extract As and heavy metals simultaneously from soils under a wide range of pH conditions. Copyright © 2016 Elsevier Ltd. All rights reserved.

  9. Quantifying human behavior uncertainties in a coupled agent-based model for water resources management

    Science.gov (United States)

    Hyun, J. Y.; Yang, Y. C. E.; Tidwell, V. C.; Macknick, J.

    2017-12-01

    Modeling human behaviors and decisions in water resources management is a challenging issue due to its complexity and uncertain characteristics that affected by both internal (such as stakeholder's beliefs on any external information) and external factors (such as future policies and weather/climate forecast). Stakeholders' decision regarding how much water they need is usually not entirely rational in the real-world cases, so it is not quite suitable to model their decisions with a centralized (top-down) approach that assume everyone in a watershed follow the same order or pursue the same objective. Agent-based modeling (ABM) uses a decentralized approach (bottom-up) that allow each stakeholder to make his/her own decision based on his/her own objective and the belief of information acquired. In this study, we develop an ABM which incorporates the psychological human decision process by the theory of risk perception. The theory of risk perception quantifies human behaviors and decisions uncertainties using two sequential methodologies: the Bayesian Inference and the Cost-Loss Problem. The developed ABM is coupled with a regulation-based water system model: Riverware (RW) to evaluate different human decision uncertainties in water resources management. The San Juan River Basin in New Mexico (Figure 1) is chosen as a case study area, while we define 19 major irrigation districts as water use agents and their primary decision is to decide the irrigated area on an annual basis. This decision will be affected by three external factors: 1) upstream precipitation forecast (potential amount of water availability), 2) violation of the downstream minimum flow (required to support ecosystems), and 3) enforcement of a shortage sharing plan (a policy that is currently undertaken in the region for drought years). Three beliefs (as internal factors) that correspond to these three external factors will also be considered in the modeling framework. The objective of this study is

  10. Water-soluble organo-building blocks of aminoclay as a soil-flushing agent for heavy metal contaminated soil

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Young-Chul [Department of Chemical and Biomolecular Engineering (BK21 program), KAIST, 335 Gwahak-ro, Yuseong-gu, Daejeon 305-701 (Korea, Republic of); Kim, Eun Jung [Advanced Biomass R and D Center, KAIST, 291 Daehakno, Yuseong-gu, Daejeon 305-701 (Korea, Republic of); Ko, Dong Ah [Department of Chemical and Biomolecular Engineering (BK21 program), KAIST, 335 Gwahak-ro, Yuseong-gu, Daejeon 305-701 (Korea, Republic of); Yang, Ji-Won, E-mail: jiwonyang@kaist.ac.kr [Department of Chemical and Biomolecular Engineering (BK21 program), KAIST, 335 Gwahak-ro, Yuseong-gu, Daejeon 305-701 (Korea, Republic of); Advanced Biomass R and D Center, KAIST, 291 Daehakno, Yuseong-gu, Daejeon 305-701 (Korea, Republic of)

    2011-11-30

    Highlights: Black-Right-Pointing-Pointer Aminoclays have synthesized using centered metals with aminopropyl silane. Black-Right-Pointing-Pointer Developed aminoclay has unique nano-sized and water-soluble properties. Black-Right-Pointing-Pointer Aminoclay showed high heavy metal capacity with metal ions and its less toxicity. Black-Right-Pointing-Pointer Aminoclay could be used to remediate heavy metals from soils an alternative soil-flushing agent. - Abstract: We demonstrated that water-soluble aminopropyl magnesium functionalized phyllosilicate could be used as a soil-flushing agent for heavy metal contaminated soils. Soil flushing has been an attractive means to remediate heavy metal contamination because it is less disruptive to the soil environment after the treatment was performed. However, development of efficient and non-toxic soil-flushing agents is still required. We have synthesized aminoclays with three different central metal ions such as magnesium, aluminum, and ferric ions and investigated applicability of aminoclays as soil flushing agents. Among them, magnesium (Mg)-centered aminoclay showed the smallest size distribution and superior water solubility, up to 100 mg/mL. Mg aminoclay exhibited cadmium and lead binding capacity of 26.50 and 91.31 mg/g of Mg clay, respectively, at near neutral pH, but it showed negligible binding affinity to metals in acidic conditions. For soil flushing with Mg clay at neutral pH showed cadmium and lead were efficiently extracted from soils by Mg clay, suggesting strong binding ability of Mg clay with cadmium and lead. As the organic matter and clay compositions increased in the soil, the removal efficiency by Mg clay decreased and the operation time increased.

  11. Effect and Removal Mechanisms of 6 Different Washing Agents for Building Wastes Containing Chromium

    Directory of Open Access Journals (Sweden)

    Wang Xing-run

    2012-01-01

    Full Text Available With the building wastes contaminated by chromium in Haibei Chemical Plan in China as objects, we studied the contents of total Cr and Cr (VI of different sizes, analyzed the effect of 6 different washing agents, discussed the removal mechanisms of 6 different washing agents for Cr in various forms, and finally selected applicable washing agent. As per the results, particle size had little impact on the contents of total Cr and Cr (VI; after one washing with water, the removal rate of total Cr and Cr (VI was 75% and 78%, respectively, and after the second washing with 6 agents, the removal rate of citric acid was the highest, above 90% for total Cr and above 99% for hexavalent chromium; the pH of building wastes were reduced by citric acid, and under acid condition, hexavalent chromium was reduced to trivalent chromium spontaneously by organic acid, which led to better removal rate of acid soluble Cr and reducible Cr; due to the complexing action, citric acid had best removal rate for oxidizable trivalent chromium. In conclusion, citric acid is the most applicable second washing agent for building wastes.

  12. Synergistic Effects of Bacillus amyloliquefaciens (GB03 and Water Retaining Agent on Drought Tolerance of Perennial Ryegrass

    Directory of Open Access Journals (Sweden)

    An-Yu Su

    2017-12-01

    Full Text Available Water retaining agent (WRA is widely used for soil erosion control and agricultural water saving. Here, we evaluated the effects of the combination of beneficial soil bacterium Bacillus amyloliquefaciens strain GB03 and WRA (the compound is super absorbent hydrogels on drought tolerance of perennial ryegrass (Lolium perenne L.. Seedlings were subjected to natural drought for maximum 20 days by stopping watering and then rewatered for seven days. Plant survival rate, biomass, photosynthesis, water status and leaf cell membrane integrity were measured. The results showed that under severe drought stress (20-day natural drought, compared to control, GB03, WRA and GB03+WRA all significantly improved shoot fresh weight, dry weight, relative water content (RWC and chlorophyll content and decreased leaf relative electric conductivity (REC and leaf malondialdehyde (MDA content; GB03+WRA significantly enhanced chlorophyll content compared to control and other two treatments. Seven days after rewatering, GB03, WRA and GB03+WRA all significantly enhanced plant survival rate, biomass, RWC and maintained chlorophyll content compared to control; GB03+WRA significantly enhanced plant survival rate, biomass and chlorophyll content compared to control and other two treatments. The results established that GB03 together with water retaining agent promotes ryegrass growth under drought conditions by improving survival rate and maintaining chlorophyll content.

  13. Deficit irrigation of peach trees to reduce water consumption

    Science.gov (United States)

    Lack of water is a major limiting factor for production tree fruits such as peaches in the San Joaquin Valley of California and many other arid- or semi-arid regions in the world. Deficit irrigation can be used in some cropping systems as a water resource management strategy to reduce non-productiv...

  14. Improved methods for water shutoff. Semi-annual report, May 1, 1996--September 30, 1996

    Energy Technology Data Exchange (ETDEWEB)

    Seright, R.S.

    1997-08-01

    In the United States, more than 20 billion barrels of water are produced each year during oilfield operations. Today, the cost of water disposal is typically between $0.25 and $0.50 per bbl for pipeline transport and $1.50 per bbl for trucked water. Therefore, there is a tremendous economic incentive to reduce water production if that can be accomplished without significantly sacrificing hydrocarbon production. For each 1% reduction in water production, the cost-savings to the oil industry could be between $50,000,000 and $100,000,000 per year. Reduced water production would result directly in improved oil recovery (IOR) efficiency in addition to reduced oil-production costs. A substantial positive environmental impact could also be realized if significant reductions are achieved in the amount of water produced during oilfield operations. In an earlier project, we identified fractures (either naturally or artificially induced) as a major factor that causes excess water production and reduced oil recovery efficiency, especially during waterfloods and IOR projects. We also found fractures to be a channeling and water-production problem that has a high potential for successful treatment by gels and certain other chemical blocking agents. By analogy, these blocking materials also have a high potential for treating narrow channels behind pipe and small casing leaks. We also determined that the ability of blocking agents to reduce permeability to water much more than that to oil is critical to the success of these blocking treatments in production wells if zones are not isolated during placement of the blocking agents.

  15. Investigating the role of water in the Diffusion of Cholera using Agent-Based simulation

    Science.gov (United States)

    Augustijn, Ellen-Wien; Doldersum, Tom; Augustijn, Denie

    2014-05-01

    Traditionally, cholera was considered to be a waterborne disease. Currently we know that many other factors can contribute to the spread of this disease including human mobility and human behavior. However, the hydrological component in cholera diffusion is significant. The interplay between cholera and water includes bacteria (V. cholera) that survive in the aquatic environment, the possibility that run-off water from dumpsites carries the bacteria to surface water (rivers and lakes), and when the bacteria reach streams they can be carried downstream to infect new locations. Modelling is a very important tool to build theory on the interplay between different types of transmission mechanisms that together are responsible for the spread of Cholera. Agent-based simulation models are very suitable to incorporate behavior at individual level and to reproduce emergence. However, it is more difficult to incorporate the hydrological components in this type of model. In this research we present the hydrological component of an Agent-Based Cholera model developed to study a Cholera epidemic in Kumasi (Ghana) in 2005. The model was calibrated on the relative contribution of each community to the distributed pattern of cholera rather than the absolute number of incidences. Analysis of the results shows that water plays an important role in the diffusion of cholera: 75% of the cholera cases were infected via river water that was contaminated by runoff from the dumpsites. To initiate infections upstream, the probability of environment-to-human transmission seemed to be overestimated compared to what may be expected from literature. Scenario analyses show that there is a strong relation between the epidemic curve and the rainfall. Removing dumpsites that are situated close to the river resulted in a strong decrease in the number of cholera cases. Results are sensitive to the scheduling of the daily activities and the survival time of the cholera bacteria.

  16. Efficacy of reducing agent and surfactant contacting pattern on the performance characteristics of nickel electroless plating baths coupled with and without ultrasound.

    Science.gov (United States)

    Agarwal, Amrita; Pujari, Murali; Uppaluri, Ramgopal; Verma, Anil

    2014-07-01

    This article addresses furthering the role of sonication for the optimal fabrication of nickel ceramic composite membranes using electroless plating. Deliberating upon process modifications for surfactant induced electroless plating (SIEP) and combined surfactant and sonication induced electroless plating (SSOEP), this article highlights a novel method of contacting of the reducing agent and surfactant to the conventional electroless nickel plating baths. Rigorous experimental investigations indicated that the combination of ultrasound (in degas mode), surfactant and reducing agent pattern had a profound influence in altering the combinatorial plating characteristics. For comparison purpose, purely surfactant induced nickel ELP baths have also been investigated. These novel insights consolidate newer research horizons for the role of ultrasound to achieve dense metal ceramic composite membranes in a shorter span of total plating time. Surface and physical characterizations were carried out using BET, FTIR, XRD, FESEM and nitrogen permeation experiments. It has been analyzed that the SSOEP baths provided maximum ratio of percent pore densification per unit metal film thickness (PPDδ) and hold the key for further fine tuning of the associated degrees of freedom. On the other hand SIEP baths provided lower (PPDδ) ratio but higher PPD. For SSOEP baths with dropwise reducing agent and bulk surfactant, the PPD and metal film thickness values were 73.4% and 8.4 μm which varied to 66.9% and 13.3 μm for dropwise reducing agent and drop surfactant case. Copyright © 2014 Elsevier B.V. All rights reserved.

  17. Spatial analysis of private tanker water markets in Jordan: Using a hydroeconomic multi-agent model to simulate non-observed water transfers

    Science.gov (United States)

    Klassert, Christian; Yoon, Jim; Gawel, Erik; Sigel, Katja; Klauer, Bernd; Talozi, Samer; Lachaut, Thibaut; Selby, Philip; Knox, Stephen; Gorelick, Steven; Tilmant, Amaury; Harou, Julien; Mustafa, Daanish; Medellin-Azuara, Josue; Rajsekhar, Deepthi; Avisse, Nicolas; Zhang, Hua

    2017-04-01

    The country of Jordan is characterized by severe water scarcity and deficient public water supply networks. To address these issues, Jordan's water sector authorities have adopted a water rationing scheme implemented by interrupting piped water supply for several days per week. As in many arid countries around the world, this has led to the emergence of private markets of small-scale providers, delivering water via tanker trucks. On the one hand, these markets play a crucial role in meeting residential and commercial water demands by balancing the shortcomings of the public supply system. On the other hand, providers partially rely on illegal abstractions from rural ground and surface water sources, thereby circumventing regulatory efforts to conserve these resources. Private tanker water markets, therefore, provide a substantial contribution to consumer welfare while jeopardizing freshwater resource sustainability. Thus, a better understanding of these markets is of great importance for the formulation of policy interventions pursuing freshwater sustainability in a socially acceptable manner. Direct assessments of the size of these markets or their responses to policy interventions are, however, impeded by their partially illegal nature and the resulting lack of available information. To overcome this data collection challenge, we use a hydroeconomic multi-agent model developed in the Jordan Water Project to indirectly simulate country-wide tanker water market activities on the basis of demand and supply estimates. The demand for tanker water is conceptualized as a residual demand, remaining after a water user has depleted all available cheap and qualitatively reliable piped water. It is derived from residential and commercial demand functions on the basis of survey data. Tanker water supply is determined by farm simulation models calculating the groundwater pumping cost and the agricultural opportunity cost of tanker water. Finally, a spatial market algorithm

  18. Removal of sulphates from waste waters by sulphate-reducing bacteria

    Directory of Open Access Journals (Sweden)

    Luptáková Alena

    2002-03-01

    Full Text Available are present in almost all types of water, usually as a simple anion SO42-. The sulphates together with hydrogencarbonates and chlorides are principal anions in natural waters. In typical underground and surface waters, the concentration of sulphates is in the range from ten to hundreds milligrams per litre.Nowadays, the importance of the control of sulphate concentration in waste waters increases. According to the Slovak legislation the limit concentration of sulphates in surface and drinking waters is 250 mg.l-1 . In rivers the contents of sulphates increases mainly by the discharge of waste waters, which are coming mainly from chemical, textile, metallurgical, pharmaceutical, paper and mining industry. The concentration of sulphates in these waters is in the order of grams per litre.Many technologies for the sulphates removal from waste waters exist, including biologico-chemical processes. The principle of one of these methods is the reduction of sulphates by sulphate-reducing bacteria to hydrogen-sulphide.The objective of this work was to study the effect of initial sulphates concentration on the activity of anaerobic sulphate reducers as well as the kinetics of the anaerobic sulphate reduction. The batch reactor was used at temperature of 30°C and pH 7,5. Lactate was used as the carbon source.

  19. Automatic spectral imaging protocol selection and iterative reconstruction in abdominal CT with reduced contrast agent dose: initial experience

    Energy Technology Data Exchange (ETDEWEB)

    Lv, Peijie; Liu, Jie; Chai, Yaru; Yan, Xiaopeng; Gao, Jianbo; Dong, Junqiang [The First Affiliated Hospital of Zhengzhou University, Department of Radiology, Zhengzhou, Henan Province (China)

    2017-01-15

    To evaluate the feasibility, image quality, and radiation dose of automatic spectral imaging protocol selection (ASIS) and adaptive statistical iterative reconstruction (ASIR) with reduced contrast agent dose in abdominal multiphase CT. One hundred and sixty patients were randomly divided into two scan protocols (n = 80) each; protocol A, 120 kVp/450 mgI/kg, filtered back projection algorithm (FBP); protocol B, spectral CT imaging with ASIS and 40 to 70 keV monochromatic images generated per 300 mgI/kg, ASIR algorithm. Quantitative parameters (image noise and contrast-to-noise ratios [CNRs]) and qualitative visual parameters (image noise, small structures, organ enhancement, and overall image quality) were compared. Monochromatic images at 50 keV and 60 keV provided similar or lower image noise, but higher contrast and overall image quality as compared with 120-kVp images. Despite the higher image noise, 40-keV images showed similar overall image quality compared to 120-kVp images. Radiation dose did not differ between the two protocols, while contrast agent dose in protocol B was reduced by 33 %. Application of ASIR and ASIS to monochromatic imaging from 40 to 60 keV allowed contrast agent dose reduction with adequate image quality and without increasing radiation dose compared to 120 kVp with FBP. (orig.)

  20. Automatic spectral imaging protocol selection and iterative reconstruction in abdominal CT with reduced contrast agent dose: initial experience

    International Nuclear Information System (INIS)

    Lv, Peijie; Liu, Jie; Chai, Yaru; Yan, Xiaopeng; Gao, Jianbo; Dong, Junqiang

    2017-01-01

    To evaluate the feasibility, image quality, and radiation dose of automatic spectral imaging protocol selection (ASIS) and adaptive statistical iterative reconstruction (ASIR) with reduced contrast agent dose in abdominal multiphase CT. One hundred and sixty patients were randomly divided into two scan protocols (n = 80) each; protocol A, 120 kVp/450 mgI/kg, filtered back projection algorithm (FBP); protocol B, spectral CT imaging with ASIS and 40 to 70 keV monochromatic images generated per 300 mgI/kg, ASIR algorithm. Quantitative parameters (image noise and contrast-to-noise ratios [CNRs]) and qualitative visual parameters (image noise, small structures, organ enhancement, and overall image quality) were compared. Monochromatic images at 50 keV and 60 keV provided similar or lower image noise, but higher contrast and overall image quality as compared with 120-kVp images. Despite the higher image noise, 40-keV images showed similar overall image quality compared to 120-kVp images. Radiation dose did not differ between the two protocols, while contrast agent dose in protocol B was reduced by 33 %. Application of ASIR and ASIS to monochromatic imaging from 40 to 60 keV allowed contrast agent dose reduction with adequate image quality and without increasing radiation dose compared to 120 kVp with FBP. (orig.)

  1. Double agents and secret agents: the emerging fields of exogenous chemical exchange saturation transfer and T2-exchange magnetic resonance imaging contrast agents for molecular imaging.

    Science.gov (United States)

    Daryaei, Iman; Pagel, Mark D

    2015-01-01

    Two relatively new types of exogenous magnetic resonance imaging contrast agents may provide greater impact for molecular imaging by providing greater specificity for detecting molecular imaging biomarkers. Exogenous chemical exchange saturation transfer (CEST) agents rely on the selective saturation of the magnetization of a proton on an agent, followed by chemical exchange of a proton from the agent to water. The selective detection of a biomarker-responsive CEST signal and an unresponsive CEST signal, followed by the ratiometric comparison of these signals, can improve biomarker specificity. We refer to this improvement as a "double-agent" approach to molecular imaging. Exogenous T 2 -exchange agents also rely on chemical exchange of protons between the agent and water, especially with an intermediate rate that lies between the slow exchange rates of CEST agents and the fast exchange rates of traditional T 1 and T 2 agents. Because of this intermediate exchange rate, these agents have been relatively unknown and have acted as "secret agents" in the contrast agent research field. This review exposes these secret agents and describes the merits of double agents through examples of exogenous agents that detect enzyme activity, nucleic acids and gene expression, metabolites, ions, redox state, temperature, and pH. Future directions are also provided for improving both types of contrast agents for improved molecular imaging and clinical translation. Therefore, this review provides an overview of two new types of exogenous contrast agents that are becoming useful tools within the armamentarium of molecular imaging.

  2. The role of natural indigo dye in alleviation of genotoxicity of sodium dithionite as a reducing agent.

    Science.gov (United States)

    Bektaş, İdris; Karaman, Şengül; Dıraz, Emel; Çelik, Mustafa

    2016-12-01

    Indigo blue is a natural dye used for thousands of years by civilizations to dye fabric blue and it is naturally obtained from Isatis tinctoria. I. tinctoria is not only used for extraction of indigo blue color but also used medicinally in Traditional Chinese Medicine because of its active compounds. Sodium dithionite (Na 2 S 2 O 4 ) is used in dye bath for indigo blue extraction, but this reducing agent and its derivatives are major pollutants of textile industry and subsequently have hazardous influences on public health. Herein, the present study was designed to obtain the high yield of natural indigo dye but with low possible toxic effect. In this context, genotoxic effects of particular combinations of natural dye solutions obtained from Isatis tinctoria subsp. tomentolla with Na 2 S 2 O 4 as reducing agent were investigated. Dye solutions were obtained using two different pH levels (pH 9 and 11) and three different concentrations of Na 2 S 2 O 4 (2.5, 5 and 10 mg/ml). In addition to the dye solutions and reducing agent, aqueous extracts of I. tinctoria were assessed for their genotoxicity on human lymphocytes. For in vitro testing of genotoxicity, chromosomal aberrations (CAs), sister chromatid exchanges (SCEs) and mitotic indexes (MI) assays were used. Accordingly, Na 2 S 2 O 4 caused significant increases in CA and SCE as well decrease in MI but the genotoxic effects of sodium dithionite were reduced with natural indigo dye. As a result, aqueous extracts of Isatis leaves removed the toxic effects of sodium dithionite and showed anti-genotoxic effect. For the optimal and desired quality but with less toxic effects of natural dye, 2.5 mg/ml (for wool yarn) and 5 mg/ml (for cotton yarn) of Na 2 S 2 O 4 doses were found to be the best doses for reduction in the dye bath at Ph 9.

  3. Automatic spectral imaging protocol selection and iterative reconstruction in abdominal CT with reduced contrast agent dose: initial experience.

    Science.gov (United States)

    Lv, Peijie; Liu, Jie; Chai, Yaru; Yan, Xiaopeng; Gao, Jianbo; Dong, Junqiang

    2017-01-01

    To evaluate the feasibility, image quality, and radiation dose of automatic spectral imaging protocol selection (ASIS) and adaptive statistical iterative reconstruction (ASIR) with reduced contrast agent dose in abdominal multiphase CT. One hundred and sixty patients were randomly divided into two scan protocols (n = 80 each; protocol A, 120 kVp/450 mgI/kg, filtered back projection algorithm (FBP); protocol B, spectral CT imaging with ASIS and 40 to 70 keV monochromatic images generated per 300 mgI/kg, ASIR algorithm. Quantitative parameters (image noise and contrast-to-noise ratios [CNRs]) and qualitative visual parameters (image noise, small structures, organ enhancement, and overall image quality) were compared. Monochromatic images at 50 keV and 60 keV provided similar or lower image noise, but higher contrast and overall image quality as compared with 120-kVp images. Despite the higher image noise, 40-keV images showed similar overall image quality compared to 120-kVp images. Radiation dose did not differ between the two protocols, while contrast agent dose in protocol B was reduced by 33 %. Application of ASIR and ASIS to monochromatic imaging from 40 to 60 keV allowed contrast agent dose reduction with adequate image quality and without increasing radiation dose compared to 120 kVp with FBP. • Automatic spectral imaging protocol selection provides appropriate scan protocols. • Abdominal CT is feasible using spectral imaging and 300 mgI/kg contrast agent. • 50-keV monochromatic images with 50 % ASIR provide optimal image quality.

  4. Facile Fabrication of a Hierarchical Superhydrophobic Coating with Aluminate Coupling Agent Modified Kaolin

    Directory of Open Access Journals (Sweden)

    Hui Li

    2013-01-01

    Full Text Available A superhydrophobic coating was fabricated from the dispersion of unmodified kaolin particles and aluminate coupling agent in anhydrous ethanol. Through surface modification, water contact angle of the coating prepared by modified kaolin particles increased dramatically from 0° to 152°, and the sliding angle decreased from 90° to 3°. Scanning electron microscopy was used to examine the surface morphology. A structure composed of micro-nano hierarchical component, combined with the surface modification by aluminate coupling agent which reduced the surface energy greatly, was found to be responsible for the superhydrophobicity. The method adopted is relatively simple, facile, and cost-effective and can potentially be applied to large water-repellent surface coatings.

  5. Assessing surface water flood risk and management strategies under future climate change: Insights from an Agent-Based Model.

    Science.gov (United States)

    Jenkins, K; Surminski, S; Hall, J; Crick, F

    2017-10-01

    Climate change and increasing urbanization are projected to result in an increase in surface water flooding and consequential damages in the future. In this paper, we present insights from a novel Agent Based Model (ABM), applied to a London case study of surface water flood risk, designed to assess the interplay between different adaptation options; how risk reduction could be achieved by homeowners and government; and the role of flood insurance and the new flood insurance pool, Flood Re, in the context of climate change. The analysis highlights that while combined investment in property-level flood protection and sustainable urban drainage systems reduce surface water flood risk, the benefits can be outweighed by continued development in high risk areas and the effects of climate change. In our simulations, Flood Re is beneficial in its function to provide affordable insurance, even under climate change. However, the scheme does face increasing financial pressure due to rising surface water flood damages. If the intended transition to risk-based pricing is to take place then a determined and coordinated strategy will be needed to manage flood risk, which utilises insurance incentives, limits new development, and supports resilience measures. Our modelling approach and findings are highly relevant for the ongoing regulatory and political approval process for Flood Re as well as for wider discussions on the potential of insurance schemes to incentivise flood risk management and climate adaptation in the UK and internationally. Copyright © 2017 Elsevier B.V. All rights reserved.

  6. One-step synthesis and antibacterial property of water-soluble silver nanoparticles by CGJ bio-template

    International Nuclear Information System (INIS)

    Zhu Zichun; Wu Qingsheng; Chen Ping; Yang Xiaohong

    2011-01-01

    In this article, a new synthetic method of nanoparticles with fresh Chinese gooseberry juice (CGJ) as bio-template was developed. One-step synthesis of highly water-soluble silver nanoparticles at room temperature without using any harmful reducing agents and special capping agent was fulfilled with this method. In the process, the products were obtained by adding AgNO 3 to CGJ, which was used as reducing agent, capping agent, and the bio-template. The products of silver nanoparticles with diameter of 10–30 nm have strong water solubility and excellent antibiotic function. With the same concentration 0.047 μg mL −1 , the antibacterial effect of water-soluble silver particles by fresh CGJ was 53%, whereas only 27% for silver nanoparticles synthesized using the template method of fresh onion inner squama coat (OISC). The excellent water solubility of the products would enable them have better applications in the bio-medical field. The synthetic method would also have potential application in preparing other highly water-soluble particles, because of its simple apparatus, high yield, mild conditions, and facile operation.

  7. A waterproofing agent

    Energy Technology Data Exchange (ETDEWEB)

    Shchipanov, A.I.; Bass, U.M.; Belousov, E.D.; Chernova, S.P.; Gioev, K.A.; Perlin, L.M.; Shapiro, B.O.; Silantev, U.R.

    1979-12-25

    A waterproofing agent is proposed with improved physiomechanical properties. The agent contains (by parts): bitumens: 100; emulsifier: .6-5; polyvinylpyrrolidone: .4-8; synthetic latex: 5.24; a corrosion inhibitor: .2-10; SPL methyl methacrylate with chloroprene: 2.24; hydrochlorinated amine of adduct diethylene triamine with diglycidyl diamine: 2-10, water: 118-220. The agent is prepared using either periodic or continuous action in emulsifying dispersion machines. The bitumen is dispersed in the machine in an aqueous emulsifying solution in which polyvinylpyrrolidone and the corrosion inihibitor are first introduced. Then a synthetic latex solution is introduced into the bitumen emulsion while being mixed in rotor-type turbulent mixers; a solution and a hydrochlorinated amine of adduct diethylene triamine with diglycidyl diamine solution until a homogeneous mixture is obtained. Example: a waterproofing agent is obtained in parts: bitumen 100, emulsifyer (oxidized petrolatum): .6; polyvinylpyrrolidone: .4; synthetic latex (nitrile): 5; corrosion inhibitor (guanidine chromate): .2, SPL:2; and water 118. The properties of the proposed composition are better than the properties of the composition currently used.

  8. Blue Planet dialysis: novel water-sparing strategies for reducing dialysate flow.

    Science.gov (United States)

    Molano-Triviño, Alejandra; Wancjer, Benjamin; Neri, Mauro M; Karopadi, Akash N; Rosner, Mitchell; Ronco, Claudio

    2017-11-08

    Hemodialysis (HD) is an expensive therapy in economic and in ecological terms, owing to a high carbon footprint and significant consumption of natural sources, especially water. Our aim was to review strategies to diminish waste of water in maintenance dialysis, exploring previously described water reuse trends and less known strategies for reducing the dialysate flow. We conducted a systematic review of water-sparing strategies, including the reuse of reverse osmosis rejected water and the reduction of dialysate flux. We performed a search in Medline, Pubmed, Scielo, OVID and Biblioteca Redentor, using key words: Dialysate flow rate, Dialysate flux, and decrease; excluding: online, peritoneal, continuous, blood access, needle, hemodiafiltration, acute, pharmacokinetics, increase. We limited our search to adult humans or in vitro trials in English, Spanish, Italian and Portuguese, between January 1980 and June 2017. We found 816 trials. 37 articles were retrieved for review, and 11 articles were analyzed. Conservation of water in chronic HD should be considered an important responsibility of healthcare practitioners all over the world. We present a wider usage of dialysate flow rates, considering that it would lead to significant water conservation without much compromise on dialysis efficacy in small patients. We believe that further investigation into the utility of reduced dialysate flux in different populations is needed to broaden our understanding of how we can use these techniques in order to significantly reduce water consumption during chronic HD while still ensuring optimum efficacy and efficiency of the therapy.

  9. Do coxibs reduce prescription of gastroprotective agents? Results of a record linkage study

    Directory of Open Access Journals (Sweden)

    Violante Andrea

    2006-03-01

    Full Text Available Abstract Background Coxibs are claimed to be cost-effective drugs and reduced prescription of gastroprotective agents is assumed to be one of their major benefits. Real life prescription of these drugs may be substantially different than that considered in pharmacoeconomic analyses or claimed by drug companies, yet. Our objective was to evaluate whether coxibs were associated with reduced prescription of gastro-protective agents (GPAs, specifically proton pump inhibitors, H2 blockers and misoprostol compared to non selective NSAIDs. Methods A record-linkage study was performed using 2001 outpatient prescription data from the province of Modena (about 632,000 inhabitants, in Northern Italy. Logistic regression was used to calculate the odds ratio of GPA prescription for coxib and non-selective NSAID adult users (> 14 years. Three categories of users were further investigated: "acute", "chronic and "incident or new". Main outcome measures were same-day co-prescription and 30 days prescription of GPAs in coxibs and non selective NSAIDs users. To limit selection bias, data were adjusted for age, sex, DDD of coxibs and non selective NSAIDs received during 2001, DDD of GPAs and (for non-incident users DDD of NSAIDs received during the previous 4 years Results Same day co-prescription rates were similar considering the overall population and "acute" users. Chronic coxibs users instead showed higher co-prescription rates than chronic NSAIDs users (OR = 1.2, p Conclusion Assumptions made in pharmacoeconomic analyses on coxibs (lower GPA prescription associated with coxibs use may be overly optimistic. Claims made through cost-effectiveness data should be carefully interpreted, and mechanisms for attributing drug prices revised accordingly.

  10. Study on core design for reduced-moderation water reactors

    International Nuclear Information System (INIS)

    Okubo, Tsutomu

    2002-01-01

    The Reduced-Moderation Water Reactor (RMWR) is a water-cooled reactor with the harder neutron spectrum comparing with the LWR, resulting from low neutron moderation due to reduced water volume fraction. Based on the difference from the spectrum from the LWR, the conversion from U-238 to Pu-239 is promoted and the new cores preferable to effective utilization of uranium resource can be possible Design study of the RMWR core started in 1997 and new four core concepts (three BWR cores and one PWR core) are recently evaluated in terms of control rod worths, plutonium multiple recycle, high burnup and void coefficient. Comparative evaluations show needed incorporation of control rod programming and simplified PUREX process as well as development of new fuel cans for high burnup of 100 GW-d/t. Final choice of design specifications will be made at the next step aiming at realization of the RMWR. (T. Tanaka)

  11. Study on core design for reduced-moderation water reactors

    Energy Technology Data Exchange (ETDEWEB)

    Okubo, Tsutomu [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment

    2002-12-01

    The Reduced-Moderation Water Reactor (RMWR) is a water-cooled reactor with the harder neutron spectrum comparing with the LWR, resulting from low neutron moderation due to reduced water volume fraction. Based on the difference from the spectrum from the LWR, the conversion from U-238 to Pu-239 is promoted and the new cores preferable to effective utilization of uranium resource can be possible Design study of the RMWR core started in 1997 and new four core concepts (three BWR cores and one PWR core) are recently evaluated in terms of control rod worths, plutonium multiple recycle, high burnup and void coefficient. Comparative evaluations show needed incorporation of control rod programming and simplified PUREX process as well as development of new fuel cans for high burnup of 100 GW-d/t. Final choice of design specifications will be made at the next step aiming at realization of the RMWR. (T. Tanaka)

  12. Evaluation of potential gastrointestinal contrast agents for echoplanar MR imaging

    International Nuclear Information System (INIS)

    Reimer, P.; Schmitt, F.; Ladebeck, R.; Graessner, J.; Schaffer, B.

    1993-01-01

    The purpose of this study was to investigate approved aqueous gastrointestinal contrast agents for use in abdominal EPI. Conventional and echoplanar MR imaging experiments were performed with 1.0 Tesla whole body systems. Phantom measurements of Gastrografin, barium sulfate suspension, oral gadopentetate dimeglumine, water, and saline were performed. Signal intensity (SI) of aqueous oral barium sulfate and iodine based CT contrast agents was lower on conventional spin-echo (SE), Flash, and Turbo-Flush images than on EP images. The contrast agents exhibited higher SI on T2-weighted SE PE images and TI-time dependence on inversion recovery EP-images. The barium sulfate suspension was administered in volunteers to obtain information about bowel lumen enhancement and susceptibility artifacts. Oral administration of the aqueous barium sulfate suspension increased bowel lumen signal and reduced susceptibility artifacts. (orig.)

  13. Fines stabilizing agent reduces production decline rates in steam injected wells

    Energy Technology Data Exchange (ETDEWEB)

    Castillo de Castillo, Milagros; Fernandez Andrades, Jarvi [PDVSA - Petroleos de Venezuela S.A., Caracas (Venezuela); Navarro Cornejo, Willian; Curtis, James [BJ Services do Brasil Ltda., RJ (Brazil)

    2004-07-01

    The Bachaquero Lago heavy oil field, located in Lake Maracaibo, Venezuela, with an area of 9800 ha, in which more than 1800 wells have been drilled. The Lagunillas formation in this field is a mature, clastic, unconsolidated sandstone of Miocene age with good permeability. Clays are present, in laminated form or dispersed within the productive sandstones. Heavy oil, less than 12 deg API, is produced by cyclic steam injection. Wells are completed with cased-hole gravel packs to prevent sand and fines production. Rapid production decline rates are typically observed after the steam injection cycles, due to fines migration and plugging of the reservoir and gravel pack. This paper describes the methodology used to treat the wells with a fines stabilizing agent during the steam injection cycles in order to successfully reduce the subsequent production decline rate. Results from a multi-well pilot project are presented and analyzed. (author)

  14. Status of research and development on reduced-moderation water reactors

    International Nuclear Information System (INIS)

    Iwamura, Takamichi

    2002-01-01

    To improve uranium utilization, a design study of the Reduced-Moderation Water Reactor (RMWR) has been carried out intensively since 1998 at the Japan Atomic Energy Research Institute (JAERI). In this reactor, the nuclear fission reaction is designed to be realized mainly by high energy neutrons. To achieve this, the volume of water used to cool the fuel rods is decreased by reducing the gap width between the fuel rods. Conversion ratio greater than 1.0 is expected whether the core i-s cooled by boiling water or pressurized water and whether the core size is small or large. Status of the RMWR design is reviewed and planning of R and D for future deployment of this reactor after 20-20 is presented. To improve economics of this reactor, development of fuel cans for high burnup and low-cost reprocessing technology of mixed oxide spect fuels are highly needed. R and D has been conducted under the cooperation with utilities, industry, research organization and academia. (T. Tanaka)

  15. Status of research and development on reduced-moderation water reactors

    Energy Technology Data Exchange (ETDEWEB)

    Iwamura, Takamichi [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment

    2002-12-01

    To improve uranium utilization, a design study of the Reduced-Moderation Water Reactor (RMWR) has been carried out intensively since 1998 at the Japan Atomic Energy Research Institute (JAERI). In this reactor, the nuclear fission reaction is designed to be realized mainly by high energy neutrons. To achieve this, the volume of water used to cool the fuel rods is decreased by reducing the gap width between the fuel rods. Conversion ratio greater than 1.0 is expected whether the core i-s cooled by boiling water or pressurized water and whether the core size is small or large. Status of the RMWR design is reviewed and planning of R and D for future deployment of this reactor after 20-20 is presented. To improve economics of this reactor, development of fuel cans for high burnup and low-cost reprocessing technology of mixed oxide spect fuels are highly needed. R and D has been conducted under the cooperation with utilities, industry, research organization and academia. (T. Tanaka)

  16. Reducing Agricultural Water Footprints at the Farm Scale: A Case Study in the Beijing Region

    Directory of Open Access Journals (Sweden)

    Jing Huang

    2015-12-01

    Full Text Available Beijing is one of the most water-stressed regions in the world. Reducing agricultural water use has long been the basis of local policy for sustainable water use. In this article, the potential to reduce the life cycle (cradle to gate water footprints of wheat and maize that contribute to 94% of the local cereal production was assessed. Following ISO 14046, consumptive and degradative water use for the wheat-maize rotation system was modeled under different irrigation and nitrogen (N application options. Reducing irrigation water volume by 33.3% compared to current practice did not cause a significant yield decline, but the water scarcity footprint and water eutrophication footprint were decreased by 27.5% and 23.9%, respectively. Similarly, reducing the N application rate by 33.3% from current practice did not cause a significant yield decline, but led to a 52.3% reduction in water eutrophication footprint while maintaining a similar water scarcity footprint. These results demonstrate that improving water and fertilizer management has great potential for reducing the crop water footprints at the farm scale. This situation in Beijing is likely to be representative of the challenge facing many of the water-stressed regions in China, where a sustainable means of agricultural production must be found.

  17. Preparation of fluidized catalytic cracking slurry oil-in-water emulsion as anti-collapse agent for drilling fluids

    Directory of Open Access Journals (Sweden)

    Zhengqiang Xiong

    2016-12-01

    Full Text Available Fluidized catalytic cracking slurry oil-in-water emulsion (FCCSE was prepared by using interfacial complexes generation method that was simple and versatile. The critical factors influencing the sample preparation process were optimized, for instance, the optimum value of the mixed hydrophile-lipophile balance of compound emulsifier was 11.36, the content of compound emulsifier was 4 wt%, the emulsification temperature was 75 °C, the agitation speed was 200 rpm, and the emulsification time was 30–45 min. The performance as a drilling fluid additive was also investigated with respect to rheological properties, filtration loss and inhibition of FCCSE. Experimental results showed that FCCSE was favorable to inhibiting clay expansion and dispersion and reducing fluid loss. Furthermore, it had good compatibility with other additives and did not affect the rheological properties of drilling fluids. FCCSE exhibited better performance than the available emulsified asphalt. It has a promising application as anti-collapse agent in petroleum and natural gas drilling.

  18. Reducing Moose-Vehicle Collisions through Salt Pool Removal and Displacement: an Agent-Based Modeling Approach

    OpenAIRE

    Paul D. Grosman; Jochen A. G. Jaeger; Pascale M. Biron; Christian Dussault; Jean-Pierre Ouellet

    2009-01-01

    Between 1990 and 2002, more than 200 moose-vehicle collisions occurred each year in Quebec, including about 50/yr in the Laurentides Wildlife Reserve. One cause is the presence of roadside salt pools that attract moose near roads in the spring and summer. Using the computer simulation technique of agent-based modeling, this study investigated whether salt pool removal and displacement, i.e., a compensatory salt pool set up 100 to 1500 m away from the road shoulder, would reduce the number of ...

  19. Reducing phosphorus loss in tile water with managed drainage in a claypan soil.

    Science.gov (United States)

    Nash, Patrick R; Nelson, Kelly A; Motavalli, Peter P; Nathan, Manjula; Dudenhoeffer, Chris

    2015-03-01

    Installing subsurface tile drain systems in poorly drained claypan soils to improve corn ( L.) yields could potentially increase environmental phosphorus (P) loss through the tile drainage system. The objectives of the study were to quantify the average concentration and loss of ortho-P in tile drain water from a claypan soil and to determine whether managed subsurface drainage (MD) could reduce ortho-P loss in tile water compared with free subsurface drainage (FD). Flow-weighted ortho-P concentration in the tile water was significantly lower with MD (0.09 mg L) compared with that of FD (0.15 mg L). Ortho-P loss in the tile water of this study was reduced with MD (36 g ha) by 80% compared with FD (180 g ha). Contrary to previous research, reduced ortho-P loss observed over the 4-yr study was not solely due to the reduced amount of water drained annually (63%) with MD compared with FD. During the spring period, when flow was similar between MD and FD, the concentration of ortho-P in the tile water generally was lower with MD compared with FD, which resulted in significantly less ortho-P loss with MD. We speculate that MD's ability to conserve water during the dry summer months increased corn's uptake of water and P, which reduced the amount of P available for leaching loss in the subsequent springs. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

  20. Study of the leaching of heavy metals from waste water sludge and incinerator's ash, using coupled thermostated columns and DTPA as complex agent; Estudio de la extraccion de metales pesados de lodos y cenizas de aguas residuales usando columnas termostatizadas acopladas y DTPA como agente complejante

    Energy Technology Data Exchange (ETDEWEB)

    Vite T, J.; Vite T, M.; Guerrero D, J.; Carreno de Leon, M.C. [Departamento de Estudios del Ambiente, Instituto Nacional de Investigaciones Nucleares, A.P. 18-1027, 11801 Mexico D.F. (Mexico)

    2000-07-01

    We studied the metallic composition from waste water sludge and incinerators ashes of an incinerator located in Toluca, Mexico, the qualitative studies were made using the Activation Analysis technique, and fluorescence X-ray techniques. The quantitative analysis of heavy metals in the wastes were made using Inductively coupled plasma atomic emission spectrometry (Icp-Aes). For leaching the samples, we used four coupled thermostated columns, each one had a p H of 2,5, 7 and 10. The flux of the air was of 1600 cc/min. The temperature was maintain constant in 60 Centigrade using a thermostated system. For this study we used 100 g of wastes mixed with mineral acid or sodium hydroxide to reach p H 2,5,7 and 10. We added a reducing and tensoactive agents and finally DTPA as complex agent. With this method, we obtain a better leaching efficiency using a complex agent. However the high DTPA cost, make this process expansive that is why we recommend to work with another classes of complex agents, that be cheaper to leach metals of different chemistry matrix. (Author)

  1. Anti-Inflammatory Agent Indomethacin Reduces Invasion and Alters Metabolism in a Human Breast Cancer Cell Line

    Directory of Open Access Journals (Sweden)

    Ellen Ackerstaff

    2007-03-01

    Full Text Available Hostile physiological environments such as hypoxia and acidic extracellular pH, which exist in solid tumors, may promote invasion and metastasis through inflammatory responses and formation of eicosanoids. Here, we have investigated the effects of the antiinflammatory agent indomethacin on the invasion and metabolism of the human breast cancer cell line MDAMB-435 in Dulbecco's Modified Eagles (DME-based or Roswell Park Memorial Institute (RPMI-based cell medium, using a magnetic resonance-compatible invasion assay. Indomethacin treatment significantly reduced the invasion of MDA-MB-435 cells independent of the culture and perfusion conditions examined. Significant changes were detected in levels of intracellular choline phospholipid metabolites and in triglyceride (TG concentrations of these cells, depending on indomethacin treatment and basal cell medium used. Additionally, genetic profiling of breast cancer cells, grown and treated with low-dose indomethacin in cell culture using an RPMI-based medium, revealed the upregulation of several genes implicating cyclooxygenaseindependent targets of indomethacin. These data confirm the ability of an anti-inflammatory agent to reduce breast cancer invasion and demonstrate, depending on cell culture and perfusion conditions, that the indomethacin-induced decrease in invasion is associated with changes in choline phospholipid metabolism, TG metabolism, and gene expression.

  2. Effects of Shrinkage Reducing Agent and Expansive Additive on Mortar Properties

    Directory of Open Access Journals (Sweden)

    Sarapon Treesuwan

    2017-01-01

    Full Text Available This research is to study the effect of mortar mixed with shrinkage reducing agent (polyoxyalkylene alkyl ether type, expansive additive (CaO type, and fly ash (hereinafter “SRA,” “EX,” and “FA,” resp.. Moreover, steam curing was studied to improve the properties of mortar. The plastic shrinkage test was conducted by using the strain gauge embedded at 0.5 cm from the surface according to the ASTM C1579-06 standard within early age followed by the total shrinkage test and compressive strength test. The test results showed that mixing both the EX and SRA increases the plastic enlargement of the mortar during the early age more than using either the EX or SRA solely. The steam curing helps to reduce the plastic shrinkage when the mortar is added with the FA and SRA while adding the EX increases the enlargement compared to the normal curing. When the EX, SRA, and FA are all added to the mortar mixing, great attention should be paid due to the increase of greater enlargement. For the compressive strength view, the steam curing increases the compressive strength in all types of mixture. The steam curing significantly helps increasing the compressive strength of mortar with combination of EX, SRA, and FA. Nevertheless, the XRD and SEM tests explain such enlargement accordingly.

  3. Effect of electrolyzed reduced water on malondialdehyde levels and ...

    African Journals Online (AJOL)

    Purpose: To evaluate the effects of electrolyzed reduced water (ERW) on .... dehydrated and cleared with alcohol. ... assay tubes were incubated at a temperature of ... oxygen-dependent and oxygen-independent .... Oxidative Medicine and.

  4. Reducing and verifying haloacetic acids in treated drinking water using a biological filter system.

    Science.gov (United States)

    Lou, Jie C; Chan, Hung Y; Yang, Chih Y; Tseng, Wei B; Han, Jia Y

    2014-01-01

    This study focused on reducing the haloacetic acid (HAA) concentrations in treated drinking water. HAA has been thought to be one possible nutrient supporting heterotrophic bacteria regrowth in drinking water. In this study, experiments were conducted using a pilot-scale system to evaluate the efficiency of biological filters (BF) for reducing excess HAA concentrations in water. The BF system reduced the total HAA concentration and the concentrations of five HAA species in the water. Dichloroacetic acid (DCAA), monobromoacetic acid (MBAA) and dibromoacetic acid (DBAA) were the three main HAA5 species that were present in the treated drinking water in this investigation. Combined, these three species represent approximately 77% of the HAA5 in the finished water after BF. The verification of the empirical HAA equation for the outlet in the BF system indicated linear relationships with high correlation coefficients. The empirical equation for the HAA5 concentrations in the finished water was established by examining other nutrients (e.g., dissolved organic carbon (DOC), ultraviolet absorbance at 254 nm wavelength (UV254), and ammonia nitrogen) that can reduce pathogenic contamination. These findings may be useful for designing advanced processes for conventional water treatment plants or for managing water treatment and distribution systems for providing high-quality drinking water.

  5. An Empirical Agent-Based Model to Simulate the Adoption of Water Reuse Using the Social Amplification of Risk Framework.

    Science.gov (United States)

    Kandiah, Venu; Binder, Andrew R; Berglund, Emily Z

    2017-10-01

    Water reuse can serve as a sustainable alternative water source for urban areas. However, the successful implementation of large-scale water reuse projects depends on community acceptance. Because of the negative perceptions that are traditionally associated with reclaimed water, water reuse is often not considered in the development of urban water management plans. This study develops a simulation model for understanding community opinion dynamics surrounding the issue of water reuse, and how individual perceptions evolve within that context, which can help in the planning and decision-making process. Based on the social amplification of risk framework, our agent-based model simulates consumer perceptions, discussion patterns, and their adoption or rejection of water reuse. The model is based on the "risk publics" model, an empirical approach that uses the concept of belief clusters to explain the adoption of new technology. Each household is represented as an agent, and parameters that define their behavior and attributes are defined from survey data. Community-level parameters-including social groups, relationships, and communication variables, also from survey data-are encoded to simulate the social processes that influence community opinion. The model demonstrates its capabilities to simulate opinion dynamics and consumer adoption of water reuse. In addition, based on empirical data, the model is applied to investigate water reuse behavior in different regions of the United States. Importantly, our results reveal that public opinion dynamics emerge differently based on membership in opinion clusters, frequency of discussion, and the structure of social networks. © 2017 Society for Risk Analysis.

  6. Preparation of Shrinkage Compensating Concrete with HCSA Expansive Agent

    Science.gov (United States)

    Li, Changcheng; Jia, Fujia

    2017-10-01

    Shrinkage compensating concrete (SCC) has become one of the best effective methods of preventing and reducing concrete cracking. SCC is prepared by HCSA high performance expansive agent for concrete which restrained expansion rate is optimized by 0.057%. Slump, compressive strength, restrained expansion rate and cracking resistance test were carried out on SCC. The results show that the initial slump of fresh SCC was about 220mm-230mm, while slump after 2 hours was 180mm-200mm. The restrained expansion rate of SCC increased with the mixing amount of expansive agent. After cured in water for 14 days, the restrained expansion rate of C35 and C40 SCC were 0.020%-0.032%. With the dosage of expansive agent increasing, restrained expansion rate of SCC increased, maximum compressive stress and cracking stress improved, cracking temperature fell, thus cracking resistance got effectively improvement.

  7. Effect of new soil metal immobilizing agents on metal toxicity to terrestrial invertebrates

    Energy Technology Data Exchange (ETDEWEB)

    Lock, K.; Janssen, C.R

    2003-01-01

    Organisms with different exposure routes should be used to simultaneously assess risks of metals in soils. - Application of 5% (w:w) novel metal immobilizing agent reduced the water soluble, the calcium chloride extracted as well as the pore water concentration of zinc in soils from Maatheide, a metal contaminated site in the northeast of Belgium. Addition of the metal immobilizing agents also eliminated acute toxicity to the potworm Enchytraeus albidus and the earthworm Eisenia fetida and chronic toxicity to the springtail Folsomia candida. Cocoon production by E. fetida, however, was still adversely affected. These differences may be explained by the species dependent routes of metal uptake: F. candida is probably mainly exposed via pore water while in E. fetida dietary exposure is probably also important. From these results it is clear that organisms with different exposure routes should be used simultaneously to assess the environmental risk of metal contaminated soils.

  8. Stable agents for imaging investigations

    International Nuclear Information System (INIS)

    Tofe, A.J.

    1976-01-01

    This invention concerns highly stable compounds useful in preparing technetium 99m based scintiscanning exploration agents. The compounds of this invention include a pertechnetate reducing agent or a solution of oxidized pertechnetate and an efficient proportion, sufficient to stabilize the compounds in the presence of oxygen and of radiolysis products, of ascorbic acid or a pharmaceutically acceptable salt or ester of this acid. The invention also concerns a perfected process for preparing a technetium based exploration agent, consisting in codissolving the ascorbic acid or a pharmaceutically acceptable salt or ester of such an acid and a pertechnetate reducing agent in a solution of oxidized pertechnetate [fr

  9. Potential Effects of a Water Market on Enhancing Water Productivity and Reducing Water-Related Conflicts in Fars Province, Iran

    Directory of Open Access Journals (Sweden)

    Mansour Zibaei

    2017-03-01

    Full Text Available The growing demand for water and the declining trend in renewable water resources in most regions has led to serious limitations on water availability calling for the sustainable management of the harvestable resources. This has, in turn, encouraged most planners in the water sector to focus on demand management. A number of tools are already available for realizing water demand management goals; one such tool is establishing a water market. The present study is designed and implemented in two stages to investigate the role of a water market in water resources management. In the first stage, the creation of a water market at the farm and basin levels is simulated using a mathematical planning model. The second stage involves the investigation of the combined effects of the water market and water extraction rationing policies. It is found that rationing policies lead to reduced extractions from groundwater resources. The two-stage random cluster sampling method is used to collect the required data. Pilot villages are selected based on the data obtained from the first sampling stage. Pilot farms are then selected in the second stage based on water availability in each place. The input-output data, quantities of available water, and any other data required are finally collected through interviews with local farmers. Results reveal that the volume of exchanged water accounts for 9.5% of the total water consumed and the average improvement gained in farmers’ income ranges from 15 to as high as 42%. This clearly provides enough incentives for the farmers to enter the water market. Like all other water saving policies and measures, establishing a water market might increase consumption, contrary to the national objectives, in the absence of proper supplementary preventive measures. Thus, a second scenario is designed to investigate the combined effects of both water extraction rationing and water marketing. According to this scenario, the total

  10. Effects of contrast agents on the fallopian tube in a rabbit model

    International Nuclear Information System (INIS)

    Moore, D.E.

    1989-01-01

    Selection of the optimal contrast agent for hysterosalpingography was the focus of this study. The authors have evaluated the effect of different iodinated contrast agents on the fallopian tube of a rabbit. Ethiodol (oil-soluble contrast agent), methylglucamine iothalomate (water-soluble ionic agent) 30% and 60%, and Ioxilan (water-soluble monionic contrast agent) were compared. The agents were introduced by fallopian tube catheterization. Findings suggested that nonionic water-soluble contrast agents were the least detrimental to the fallopian tube and surrounding tissue. Iothalomate 60% resulted in mild inflammatory changes. Oil-soluble contrast agents caused granulomatous reaction and fibrinous adhesions

  11. Study on spraying water soluble resin to reduce pollution for Fukushima daiichi NPP accident

    International Nuclear Information System (INIS)

    Zhang Qiong; Guo Ruiping; Zhang Chunming; Han Fujuan; Hua Jie; Zhang Jiankui

    2012-01-01

    After Fukushima nuclear accident, Tokyo electric power company used the method of spraying water soluble resin synthesis at the scene of the accident, to restrain and control the spread of the radioactive dust, by forming consolidation layer in pollution area surface. This paper briefly introduced the accident, motivation of spraying water soluble resin, spraying range and implementation process. According to the relevant report on Fukushima nuclear accident, the effect of spraying water soluble resin for reducing pollution was analyzed. The mechanism of reducing pollution for water soluble resin and the application prospect were discussed. Spraying water soluble resin for fixing radioactive dust has reasonable reducing pollution effect. It is worth to use as reference and study in China. (authors)

  12. Estimated general population control limits for unitary agents in drinking water, milk, soil, and unprocessed food items. For use in reentry decision-making

    Energy Technology Data Exchange (ETDEWEB)

    Watson, A.P.; Adams, J.D.; Cerar, R.J.; Hess, T.L.; Kistner, S.L.; Leffingwell, S.S.; MacIntosh, R.G.; Ward, J.R.

    1992-01-01

    In the event of an unplanned release of chemical agent during any stage of the Chemical Stockpile Disposal Program (CSDP), the potential exists for contamination of drinking water, forage crops, grains, garden produce, and livestock. Persistent agents such as VX or sulfur mustard pose the greatest human health concern for reentry. This White Paper has been prepared to provide technical bases for these decisions by developing working estimates of agent control limits in selected environmental media considered principal sources of potential human exposure. To date, control limits for public exposure to unitary agents have been established for atmospheric concentrations only. The current analysis builds on previous work to calculate working estimates of control limits for ingestion and dermal exposure to potentially contaminated drinking water, milk, soil, and unprocessed food items such as garden produce. Information characterizing agent desorption from, and detection on or in, contaminated porous media are presently too developed to permit reasonable estimation of dermal exposure from this source. Thus, dermal contact with potentially contaminated porous surfaces is not considered in this document.

  13. Humans running in place on water at simulated reduced gravity.

    Directory of Open Access Journals (Sweden)

    Alberto E Minetti

    Full Text Available BACKGROUND: On Earth only a few legged species, such as water strider insects, some aquatic birds and lizards, can run on water. For most other species, including humans, this is precluded by body size and proportions, lack of appropriate appendages, and limited muscle power. However, if gravity is reduced to less than Earth's gravity, running on water should require less muscle power. Here we use a hydrodynamic model to predict the gravity levels at which humans should be able to run on water. We test these predictions in the laboratory using a reduced gravity simulator. METHODOLOGY/PRINCIPAL FINDINGS: We adapted a model equation, previously used by Glasheen and McMahon to explain the dynamics of Basilisk lizard, to predict the body mass, stride frequency and gravity necessary for a person to run on water. Progressive body-weight unloading of a person running in place on a wading pool confirmed the theoretical predictions that a person could run on water, at lunar (or lower gravity levels using relatively small rigid fins. Three-dimensional motion capture of reflective markers on major joint centers showed that humans, similarly to the Basilisk Lizard and to the Western Grebe, keep the head-trunk segment at a nearly constant height, despite the high stride frequency and the intensive locomotor effort. Trunk stabilization at a nearly constant height differentiates running on water from other, more usual human gaits. CONCLUSIONS/SIGNIFICANCE: The results showed that a hydrodynamic model of lizards running on water can also be applied to humans, despite the enormous difference in body size and morphology.

  14. Reducing Lead in Drinking Water: A Manual for Minnesota's Schools.

    Science.gov (United States)

    Minnesota State Dept. of Health, St. Paul.

    This manual was designed to assist Minnesota's schools in minimizing the consumption of lead in drinking water by students and staff. It offers step-by-step instructions for testing and reducing lead in drinking water. The manual answers: Why is lead a health concern? How are children exposed to lead? Why is lead a special concern for schools? How…

  15. Gastric stromal tumor: two-phase dynamic CT findings with water as oral contrast agents

    International Nuclear Information System (INIS)

    Lee, Se Hyo; Cho, June Sik; Shin, Kyung Sook; Jeong, Ki Ho; Park, Jin Yong; Yu, Ho Jun; Kim, Young Min; Jeon, Kwang Jin

    2000-01-01

    To evaluate two-phase dynamic CT with water as oral contrast agents in the CT diagnosis of gastric stromal tumors. We retrospectively reviewed the CT findings in 21 patients with pathologically proven gastric stromal tumors. Six were found to be benign, twelve were malignant, and there were three cases of STUMP (stromal tumor uncertain malignant potential). Two-phase dynamic CT scans with water as oral contrast agents were obtained 60-70 secs (portal phase) and 3 mins (equilibrium phase) after the start of IV contrast administration. We determined the size, growth pattern, and enhancement pattern of the tumors and overlying mucosa, the presence or absence of ulceration and necrosis, tumor extent, and lymph nod and distant metastasis. The CT and pathologic findings were correlated. All six benign tumors and three STUMP were less than 5.5 cm in size, and during the portal phase showed round endogastric masses with highly enhanced, intact overlying mucosa. Twelve malignant tumors were 4.5-15.5 cm in size (mean, 11.5 cm); an endogastric mass was seen in three cases, an exogastric mass in one, and a mixed pattern in eight. On portal phase images the tumors were not significantly enhanced, but highly enhanced feeding vessels were noted in five larger tumors (greater than 10 cm). All 12 malignant tumors showed ulceration and necrosis, and interruption of overlying mucosa was clearly seen during the portal phase. We were readily able to evaluate tumor extent during this phase, and in ten malignant tumors there was no invasion of adjacent organs. Seven malignant tumors showed air density within their necrotic portion (p less than 0.05). On equilibrium phase images, all malignant tumors showed heterogeneous enhancement due to necrosis, and poorly enhanced overlying mucosa. Dynamic CT during the portal phase with water as oral contrast agents was useful for depicting the submucosal origin of gastric stromal tumors and for evaluating the extent of malignant stromal tumors. Our

  16. Summary of the 4th workshop on the reduced-moderation water reactor

    International Nuclear Information System (INIS)

    Nakatsuka, Toru; Ishikawa, Nobuyuki; Iwamura, Takamichi

    2001-09-01

    The research on Reduced-Moderation Water Reactors (RMWRs) has been performed in JAERI for the development of future innovative reactors. The workshop on the RMWRs has been held every year since fiscal 1997 aimed at information exchange between JAERI and other organizations such as universities, laboratories, utilities and vendors. The 4th workshop was held on March 2, 2001 under the joint auspices of JAERI and North Kanto branch of Atomic Energy Society of Japan. The workshop began with three lectures on recent research activities in JAERI entitled 'Recent Situation of Research on Reduced-Moderation Water Reactor', 'Analysis on Electricity Generation Costs of Reduced Moderation Water Reactors' and 'Reprocessing Technology for Spent Mixed-Oxides Fuel from LWR'. Then five lectures followed: 'Micro Reactor Physics of MOX Fueled LWR' which shows the recent results of reactor physics, Fast Reactor Cooled by Supercritical Light Water' which is another type of reduced-moderation reactor, 'Phase 1 of Feasibility Studies on Commercialized Fast Breeder Reactor Cycle System' mainly conducted by Japan Nuclear Cycle Development Institute (JNC), 'Integral Type Small PWR with Stand-alone Safety' which is intended to suit for the future consumers' needs, and Utilization of Plutonium in Reduced-Moderation Water Reactors' which dictates benefits of plutonium utilization with RMWRs. This report includes the original papers presented at the workshop and summaries of the questions and answers for each lecture, as well as presentation handouts, program and participant list as appendixes. The 8 of the presented papers are indexed individually. (J.P.N.)

  17. Removal of chromium (VI) from water by micro-alloyed aluminium ...

    African Journals Online (AJOL)

    This paper deals with Cr(VI) ion removal from water, by micro-alloyed aluminium composite (MAlC), under flow conditions. In a water environment the MAlC acts as a strong reducing agent. Dissolving it in water is accompanied by the generation of Al(III) ions and reduction of water to H2, with OH- ions. The final product is ...

  18. Reduced weight decontamination formulation utilizing a solid peracid compound for neutralization of chemical and biological warfare agents

    Science.gov (United States)

    Tucker, Mark D [Albuquerque, NM

    2011-09-20

    A reduced weight decontamination formulation that utilizes a solid peracid compound (sodium borate peracetate) and a cationic surfactant (dodecyltrimethylammonium chloride) that can be packaged with all water removed. This reduces the packaged weight of the decontamination formulation by .about.80% (as compared to the "all-liquid" DF-200 formulation) and significantly lowers the logistics burden on the warfighter. Water (freshwater or saltwater) is added to the new decontamination formulation at the time of use from a local source.

  19. Nitric oxide reduces oxidative damage induced by water stress in sunflower plants

    Directory of Open Access Journals (Sweden)

    Inês Cechin

    2015-06-01

    Full Text Available Drought is one of the main environmental constraints that can reduce plant yield. Nitric oxide (NO is a signal molecule involved in plant responses to several environmental stresses. The objective of this study was to investigate the cytoprotective effect of a single foliar application of 0, 1, 10 or 100 µM of the NO donor sodium nitroprusside (SNP in sunflower plants under water stress. Water stressed plants treated with 1μM SNP showed an increase in the relative water content compared with 0 μM SNP. Drought reduced the shoot dry weight but SNP applications did not result in alleviation of drought effects. Neither drought nor water stress plus SNP applications altered the content of photosynthetic pigments. Stomatal conductance was reduced by drought and this reduction was accompanied by a significant reduction in intercellular CO2 concentration and photosynthesis. Treatment with SNP did not reverse the effect of drought on the gas exchange characteristics. Drought increased the level of malondialdehyde (MDA and proline and reduced pirogalol peroxidase (PG-POD activity, but did not affect the activity of superoxide dismutase (SOD. When the water stressed plants were treated with 10 μM SNP, the activity of PG-POD and the content of proline were increased and the level of MDA was decreased. The results show that the adverse effects of water stress on sunflower plants are dependent on the external NO concentration. The action of NO may be explained by its ability to increase the levels of antioxidant compounds and the activity of ROS-scavenging enzymes.

  20. [ManNAc, a new therapeutic agent to reduce Angptl4-induced proteinuria in MCD].

    Science.gov (United States)

    Clément, Lionel; Macé, Camille

    2016-01-01

    Current therapies used in minimal change disease (MCD) were originally designed to cure other diseases. They are only partially efficient, and present inconvenient side effects. Therefore, understanding the molecular mechanisms implicated in the pathogenesis of proteinuria in MCD could lead to new therapeutic strategies. A new experimental transgenic rat model of human MCD was generated. These NPHS2-Angptl4 transgenic rats over-express two different forms of the glycoprotein Angptl4 from the podocyte. The majority of the protein shows a lack of sialylation that is implicated in the pathogenesis of proteinuria. Supplementation of ManNAc, a precursor of sialic acid, significantly reduces albuminuria in those rats by increasing sialylation of the hyposialylated form of Angptl4. After treatment of the first episode of MCD with glucocorticoids in patients, ManNAc could be used as a maintenance drug, especially to reduce the frequency and intensity of relapse. ManNAc is a promising therapeutic agent for patients with MCD. © 2016 médecine/sciences – Inserm.

  1. The use of Powdered Activated Carbon in reducing the Doc in water treatment plants

    International Nuclear Information System (INIS)

    Nikravesh, S. H.; Etemad-Shahidi, A.; Razeghi, N.

    2003-01-01

    Today as the technology improves and the application of energy and chemicals enhances, the organic pollutants increases in surface waters in which waste waters are discharged into. In order to reduce water-born diseases, necessary actions should be taken to decrease the pollutants. Common methods of surface water treatment are not sufficient anymore. Therefore complementary methods like using activated carbon, aeration, oxidation and reverse osmosis should be used. In this paper the use of powdered activated carbon, Total organic carbon test and jar test in reducing the concentration of organic carbons in water treatment is investigated. Initial experimental results showed large errors in total organic carbon evaluation so dissolved organic carbon was measured instead. The results showed that using the powdered activated carbon in addition to conventional treatment method using ferric chloride, greatly reduces organic pollutants. Adding about 60 mg/lit of powdered activated carbon may reduce dissolved organic carbon up to 90% in optimum conditions. However, different factors like the quality of surface water, experimental errors, instrumental errors and tool errors can influence the experimental results

  2. Pathogenic agents in freshwater resources

    Science.gov (United States)

    Geldreich, Edwin E.

    1996-02-01

    Numerous pathogenic agents have been found in freshwaters used as sources for water supplies, recreational bathing and irrigation. These agents include bacterial pathogens, enteric viruses, several protozoans and parasitic worms more common to tropical waters. Although infected humans are a major source of pathogens, farm animals (cattle, sheep, pigs), animal pets (dogs, cats) and wildlife serve as significant reservoirs and should not be ignored. The range of infected individuals within a given warm-blooded animal group (humans included) may range from 1 to 25%. Survival times for pathogens in the water environment may range from a few days to as much as a year (Ascaris, Taenia eggs), with infective dose levels varying from one viable cell for several primary pathogenic agents to many thousands of cells for a given opportunistic pathogen.As pathogen detection in water is complex and not readily incorporated into routine monitoring, a surrogate is necessary. In general, indicators of faecal contamination provide a positive correlation with intestinal pathogen occurrences only when appropriate sample volumes are examined by sensitive methodology.Pathways by which pathogens reach susceptible water users include ingestion of contaminated water, body contact with polluted recreational waters and consumption of salad crops irrigated by polluted freshwaters. Major contributors to the spread of various water-borne pathogens are sewage, polluted surface waters and stormwater runoff. All of these contributions are intensified during periods of major floods. Several water-borne case histories are cited as examples of breakdowns in public health protection related to water supply, recreational waters and the consumption of contaminated salad crops. In the long term, water resource management must focus on pollution prevention from point sources of waste discharges and the spread of pathogens in watershed stormwater runoff.

  3. Ongoing Research on Herding Agents for In Situ Burning in Arctic Waters: Studies on Fate and Effects

    DEFF Research Database (Denmark)

    Fritt-Rasmussen, Janne; Gustavson, Kim; Wegeberg, Susse

    Research on the fate and effects of herding agents used to contain and thicken oil slicks for in situ burning in Arctic waters continues under the auspices of the International Association of Oil and Gas Producers Arctic Oil Spill Response Technology – Joint Industry Program (JIP). In 2014/2015 l...

  4. Usage of pumice as bulking agent in sewage sludge composting.

    Science.gov (United States)

    Wu, Chuandong; Li, Weiguang; Wang, Ke; Li, Yunbei

    2015-08-01

    In this study, the impacts of reused and sucrose-decorated pumice as bulking agents on the composting of sewage sludge were evaluated in the lab-scale reactor. The variations of temperature, pH, NH3 and CO2 emission rate, moisture content (MC), volatile solid, dissolved organic carbon, C/N and the water absorption characteristics of pumice were detected during the 25days composting. The MC of pumice achieved 65.23% of the 24h water absorptivity within the first 2h at the mass ratio of 0.6:1 (pumice:sewage sludge). Reused pumice increased 23.68% of CO2 production and reduced 21.25% of NH3 emission. The sucrose-decorated pumice reduced 43.37% of nitrogen loss. These results suggested that adding pumice and sucrose-decorated pumice in sludge composting matrix could not only adjust the MC of materials, but also improve the degradation of organic matters and reduce nitrogen loss. Copyright © 2015 Elsevier Ltd. All rights reserved.

  5. Reduced abrasion drilling fluid

    NARCIS (Netherlands)

    2010-01-01

    A reduced abrasion drilling fluid system and method of drilling a borehole by circulating the reduced abrasion drilling fluid through the borehole is disclosed. The reduced abrasion drilling fluid comprises a drilling fluid, a first additive and a weighting agent, wherein the weighting agent has a

  6. Reduced abrasion drilling fluid

    NARCIS (Netherlands)

    2012-01-01

    A reduced abrasion drilling fluid system and method of drilling a borehole by circulating the reduced abrasion drilling fluid through the borehole is disclosed. The reduced abrasion drilling fluid comprises a drilling fluid, a first additive and a weighting agent, wherein the weighting agent has a

  7. Evaluation of gloves as a water bag coupling agent for therapeutic ultrasound

    Directory of Open Access Journals (Sweden)

    Lúcio Salustiano de Lima

    2017-03-01

    Full Text Available Abstract Introduction Therapeutic ultrasound (TUS is a widespread modality in physiotherapy, and the water bag technique is a coupling method employed in the presence of anatomical irregularities in the treatment area. The aim of the present study is to evaluate the acoustic attenuation of the water bag and its effectiveness as a TUS coupling agent. Methods The rated output powers (ROPs of the TUS equipment were evaluated based on IEC 61689. Then, a radiation force balance was used to measure ROP with and without a water bag (latex and nitrile gloves filled with deionized water between a TUS transducer and the cone-shaped target of the balance. Each experiment was performed five times for each nominal power (0.5, 1.0, 2.0, 3.0, 4.0, 5.0, 6.0, and 7.0 W and in the following configurations: without the water bag (A, with nitrile gloves and with (B and without (C a height controller, and latex gloves with (D and without (E height controller. ROPs obtained in different media were compared. Results The highest relative error of ROP was 16.72% for 0.5 W. Although the power values of the equipment were within the range recommended by IEC, there was a significant difference between the ROP values measured with A and with B, C and D. Conclusion As intensity differences below 0.5 W/cm2 are considered clinically not relevant, conditions A, B, C, D, or E can be used interchangeably.

  8. A multi-agent design for a pressurized water reactor (P.W.R.) control system; Modelisation multi-agents pour la conduite d'un reacteur a eau sous pression (REP)

    Energy Technology Data Exchange (ETDEWEB)

    Aimar-Lichtenberger, M. [Paris-11 Univ., 91 - Orsay (France)

    1999-01-01

    This PhD work is in keeping with the complex industrial process control. The starting point is the analysis of control principles in a Pressurized Water Reactor (P.W.R). In order to cope with the limits of the present control procedures, a new control organisation by objectives and means is defined. This functional organisation is based on the state approach and is characterized by the parallel management of control functions to ensure the continuous control of the installation essential variables. With regard to this complex system problematic, we search the most adapted computer modeling. We show that a multi-agent system approach brings an interesting answer to manage the distribution and parallelism of control decisions and tasks. We present a synthetic study of multi-agent systems and their application fields.The choice of a multi-agent approach proceeds with the design of an agent model. This model gains experiences from other applications. This model is implemented in a computer environment which combines the mechanisms of an object language with Prolog. We propose in this frame a multi-agent modeling of the control system where each function is represented by an agent. The agents are structured in a hierarchical organisation and deal with different abstraction levers of the problem. Following a prototype process, the validation is realized by an implementation and by a coupling to a reactor simulator. The essential contributions of an agent approach turn on the mastery of the system complexity, the openness, the robustness and the potentialities of human-machine cooperation. (author)

  9. Summary of the 3rd workshop on the reduced-moderation water reactor

    International Nuclear Information System (INIS)

    Ishikawa, Nobuyuki; Nakatsuka, Tohru; Iwamura, Takamichi

    2000-06-01

    The research activities of a Reduced-Moderation Water Reactor (RMWR) are being performed for a development of the next generation water-cooled reactor. A workshop on the RMWR was held on March 3rd 2000 aiming to exchange information between JAERI and other organizations such as universities, laboratories, utilities and vendors. This report summarizes the contents of lectures and discussions on the workshop. The 1st workshop was held on March 1998 focusing on the review of the research activities and future research plan. The succeeding 2nd workshop was held on March 1999 focusing on the topics of the plutonium utilization in water-cooled reactors. The 3rd workshop was held on March 3rd 2000, which was attended by 77 participants. The workshop began with a lecture titled 'Recent Situation Related to Reduced-Moderation Water Reactor (RMWR)', followed by 'Program on MOX Fuel Utilization in Light Water Reactors' which is the mainstream scenario of plutonium utilization by utilities, and 'Feasibility Studies on Commercialized Fast Breeder Reactor Cycle System' mainly conducted by Japan Nuclear Cycle Development Institute (JNC). Also, following lectures were given as the recent research activities in JAERI: 'Progress in Design Study on Reduced-Moderation Water Reactors', 'Long-Term Scenarios of Power Reactors and Fuel Cycle Development and the Role of Reduced Moderation Water Reactors', 'Experimental and Analytical Study on Thermal Hydraulics' and Reactor Physics Experiment Plan using TCA'. At the end of the workshop, a general discussion was performed about the research and development of the RMWR. This report includes the original papers presented at the workshop and summaries of the questions and answers for each lecture and general discussion, as well as presentation viewgraphs, program and participant list as appendixes. The 7 of the presented papers are indexed individually. (J.P.N.)

  10. Summary of the 3rd workshop on the reduced-moderation water reactor

    Energy Technology Data Exchange (ETDEWEB)

    Ishikawa, Nobuyuki; Nakatsuka, Tohru; Iwamura, Takamichi [eds.

    2000-06-01

    The research activities of a Reduced-Moderation Water Reactor (RMWR) are being performed for a development of the next generation water-cooled reactor. A workshop on the RMWR was held on March 3rd 2000 aiming to exchange information between JAERI and other organizations such as universities, laboratories, utilities and vendors. This report summarizes the contents of lectures and discussions on the workshop. The 1st workshop was held on March 1998 focusing on the review of the research activities and future research plan. The succeeding 2nd workshop was held on March 1999 focusing on the topics of the plutonium utilization in water-cooled reactors. The 3rd workshop was held on March 3rd 2000, which was attended by 77 participants. The workshop began with a lecture titled 'Recent Situation Related to Reduced-Moderation Water Reactor (RMWR)', followed by 'Program on MOX Fuel Utilization in Light Water Reactors' which is the mainstream scenario of plutonium utilization by utilities, and 'Feasibility Studies on Commercialized Fast Breeder Reactor Cycle System' mainly conducted by Japan Nuclear Cycle Development Institute (JNC). Also, following lectures were given as the recent research activities in JAERI: 'Progress in Design Study on Reduced-Moderation Water Reactors', 'Long-Term Scenarios of Power Reactors and Fuel Cycle Development and the Role of Reduced Moderation Water Reactors', 'Experimental and Analytical Study on Thermal Hydraulics' and Reactor Physics Experiment Plan using TCA'. At the end of the workshop, a general discussion was performed about the research and development of the RMWR. This report includes the original papers presented at the workshop and summaries of the questions and answers for each lecture and general discussion, as well as presentation viewgraphs, program and participant list as appendixes. The 7 of the presented papers are indexed individually. (J.P.N.)

  11. Summary of the 4th workshop on the reduced-moderation water reactor

    Energy Technology Data Exchange (ETDEWEB)

    Nakatsuka, Toru; Ishikawa, Nobuyuki; Iwamura, Takamichi (eds.) [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment

    2001-09-01

    The research on Reduced-Moderation Water Reactors (RMWRs) has been performed in JAERI for the development of future innovative reactors. The workshop on the RMWRs has been held every year since fiscal 1997 aimed at information exchange between JAERI and other organizations such as universities, laboratories, utilities and vendors. The 4th workshop was held on March 2, 2001 under the joint auspices of JAERI and North Kanto branch of Atomic Energy Society of Japan. The workshop began with three lectures on recent research activities in JAERI entitled 'Recent Situation of Research on Reduced-Moderation Water Reactor', 'Analysis on Electricity Generation Costs of Reduced Moderation Water Reactors' and 'Reprocessing Technology for Spent Mixed-Oxides Fuel from LWR'. Then five lectures followed: 'Micro Reactor Physics of MOX Fueled LWR' which shows the recent results of reactor physics, Fast Reactor Cooled by Supercritical Light Water' which is another type of reduced-moderation reactor, 'Phase 1 of Feasibility Studies on Commercialized Fast Breeder Reactor Cycle System' mainly conducted by Japan Nuclear Cycle Development Institute (JNC), 'Integral Type Small PWR with Stand-alone Safety' which is intended to suit for the future consumers' needs, and Utilization of Plutonium in Reduced-Moderation Water Reactors' which dictates benefits of plutonium utilization with RMWRs. This report includes the original papers presented at the workshop and summaries of the questions and answers for each lecture, as well as presentation handouts, program and participant list as appendixes. The 8 of the presented papers are indexed individually. (J.P.N.)

  12. Gd-HOPO Based High Relaxivity MRI Contrast Agents

    Energy Technology Data Exchange (ETDEWEB)

    Datta, Ankona; Raymond, Kenneth

    2008-11-06

    Tris-bidentate HOPO-based ligands developed in our laboratory were designed to complement the coordination preferences of Gd{sup 3+}, especially its oxophilicity. The HOPO ligands provide a hexadentate coordination environment for Gd{sup 3+} in which all he donor atoms are oxygen. Because Gd{sup 3+} favors eight or nine coordination, this design provides two to three open sites for inner-sphere water molecules. These water molecules rapidly exchange with bulk solution, hence affecting the relaxation rates of bulk water olecules. The parameters affecting the efficiency of these contrast agents have been tuned to improve contrast while still maintaining a high thermodynamic stability for Gd{sup 3+} binding. The Gd- HOPO-based contrast agents surpass current commercially available agents ecause of a higher number of inner-sphere water molecules, rapid exchange of inner-sphere water molecules via an associative mechanism, and a long electronic relaxation time. The contrast enhancement provided by these agents is at least twice that of commercial contrast gents, which are based on polyaminocarboxylate ligands.

  13. Stabilized radiographic scanning agents

    International Nuclear Information System (INIS)

    Fawzi, M.B.

    1982-01-01

    Stable compositions useful as technetium 99m-based scintigraphic agents comprise gentisic acid or a pharmaceutically-acceptable salt or ester thereof in combination with a pertechnetate reducing agent or dissolved in pertechnetate-99m (sup(99m)TcOsub(4)sup(-)) solution. The compositions are especially useful in combination with a phosphate or phosphonate material that carries the radionuclide to bone, thus providing a skeletal imaging agent

  14. Multi-agent agro-economic simulation of irrigation water demand with climate services for climate change adaptation

    Directory of Open Access Journals (Sweden)

    Stefano Balbi

    2013-09-01

    Full Text Available Farmers’ irrigation practices play a crucial role in the sustainability of crop production and water consumption, and in the way they deal with the current and future effects of climate change. In this study, a system dynamic multi-agent model adopting the soil water balance provided by the Food and Agriculture Organization (FAO Irrigation and Drainage Paper 56 was developed to explore how farmers’ decision making may affect future water needs and use with a focus on the role of climate services, i.e. forecasts and insurance. A climatic projection record representing the down-scaled A1B market scenario (a balance across all sources of the assessment report of the Intergovernmental Panel on Climate Change (IPCC is used to produce future daily data about relative humidity, precipitation, temperature and wind speed. Two types of meteorological services are made available: i a bi-weekly bulletin; and ii seasonal forecasts. The precision of these services was altered to represent different conditions, from perfect knowledge to poor forecasts. Using the available forecasts, farming agents take adaptation decisions concerning crop allocation and irrigation management on the basis of their own risk attitudes. Farmers’ attitudes are characterized by fuzzy classifications depending on age, relative income and crop profitability. Farming agents’ adaptation decisions directly affect the crop and irrigation parameters, which in turn affect future water needs on a territorial level. By incorporating available and future meteorological services, the model allows the farmer’s decision making-process to be explored together with the consequent future irrigation water demand for the period 2015 to 2030. The model prototype is applied to a data set of the Venice Lagoon Watershed, an area of 2038 km2 in north-east Italy, for a preliminary test of its performance and to design future development objectives.

  15. Processing method for discharged radioactive laundry water waste

    International Nuclear Information System (INIS)

    Izumida, Tatsuo; Kitsukawa, Ryozo; Tsuchiya, Hiroyuki; Kiuchi, Yoshimasa; Hattori, Yasuo.

    1995-01-01

    In order to process discharged radioactive laundry water wastes safely and decrease radioactive wastes, bubbling of a surface active agent in a detergent which causes a problem upon its condensation is suppressed, so that the liquid condensate are continuously and easily dried into a powder. A nonionic surface active agent is used against the bubbling of the surface active agent. In addition, the bubbling in an the evaporation can is reduced, and the powderization is facilitated by adding an appropriate inorganic builder. (T.M.)

  16. Reducing nitrate loss in tile drainage water with cover crops and water-table management systems.

    Science.gov (United States)

    Drury, C F; Tan, C S; Welacky, T W; Reynolds, W D; Zhang, T Q; Oloya, T O; McLaughlin, N B; Gaynor, J D

    2014-03-01

    Nitrate lost from agricultural soils is an economic cost to producers, an environmental concern when it enters rivers and lakes, and a health risk when it enters wells and aquifers used for drinking water. Planting a winter wheat cover crop (CC) and/or use of controlled tile drainage-subirrigation (CDS) may reduce losses of nitrate (NO) relative to no cover crop (NCC) and/or traditional unrestricted tile drainage (UTD). A 6-yr (1999-2005) corn-soybean study was conducted to determine the effectiveness of CC+CDS, CC+UTD, NCC+CDS, and NCC+UTD treatments for reducing NO loss. Flow volume and NO concentration in surface runoff and tile drainage were measured continuously, and CC reduced the 5-yr flow-weighted mean (FWM) NO concentration in tile drainage water by 21 to 38% and cumulative NO loss by 14 to 16% relative to NCC. Controlled tile drainage-subirrigation reduced FWM NO concentration by 15 to 33% and cumulative NO loss by 38 to 39% relative to UTD. When CC and CDS were combined, 5-yr cumulative FWM NO concentrations and loss in tile drainage were decreased by 47% (from 9.45 to 4.99 mg N L and from 102 to 53.6 kg N ha) relative to NCC+UTD. The reductions in runoff and concomitant increases in tile drainage under CC occurred primarily because of increases in near-surface soil hydraulic conductivity. Cover crops increased corn grain yields by 4 to 7% in 2004 increased 3-yr average soybean yields by 8 to 15%, whereas CDS did not affect corn or soybean yields over the 6 yr. The combined use of a cover crop and water-table management system was highly effective for reducing NO loss from cool, humid agricultural soils. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

  17. Integrating Agent Models of Subsistence Farming With Dynamic Models of Water Distribution

    Science.gov (United States)

    Bithell, M.; Brasington, J.

    2004-12-01

    Subsistence farming communities are dependent on the landscape to provide the resource base upon which their societies can be built. A key component of this is the role of climate, and the feedback between rainfall, crop growth and land clearance, and their coupling to the hydrological cycle. Temporal fluctuations in rainfall on timescales from annual through to decadal and longer, and the associated changes in in the spatial distribution of water availability mediated by the soil-type, slope and landcover determine the locations within the landscape that can support agriculture, and control sustainability of farming practices. We seek to make an integrated modelling system to represent land use change by coupling an agent based model of subsistence farming, and the associated exploitation of natural resources, to a realistic representation of the hydrology at the catchment scale, using TOPMODEL to map the spatial distribution of crop water stress for given time-series of rainfall. In this way we can, for example, investigate how demographic changes and associated removal of forest cover influence the possibilities for field locations within the catchment, through changes in ground water availability. The framework for this modelling exercise will be presented and preliminary results from this system will be discussed.

  18. Amount of leachant and water absorption levels of wood treated with borates and water repellents.

    Science.gov (United States)

    Baysal, Ergun; Sonmez, Abdullah; Colak, Mehmet; Toker, Hilmi

    2006-12-01

    Wood protection efficacy of borates against biological agents, flame retardancy, and suitability to the environment is well known. Since borates can be applied to timber as water based solutions, they are preferred economically as well. Even though they are highly mobile in wood, boron compounds are widely used in timber preservation. Borates migrate in liquid and increase the hygroscopicity of wood in damp conditions. This study deals with the physical restriction of water access in wood by impregnating water repellent agents into wood to limit amount of leachant and water absorption levels of wood after boron treatment. Borates were incorporated with polyethylene glycol-400 (PEG-400) their bulking effect in wood was considered. Results indicated that the amount of leachates from wood treated with borates in PEG-400 was remarkably higher compared to those of wood treated with the aqueous solutions of borates. Water absorption (WA) levels of wood treated with aqueous solutions of borates were higher than those of their treated samples with the solutions in PEG-400. Secondary treatments of wood with the water repellent (WR) chemicals following borate impregnation reduced the leaching of chemicals from wood in water and also WA of the specimens were less than those of the wood treated with only borates from aqueous and PEG solutions. Styrene (St) was the most effective monomer among the other agents used in terms of immobility effect on borates and WA.

  19. Gelation of galactomannan containing water-bearing explosives

    Energy Technology Data Exchange (ETDEWEB)

    Lyerly, W.M.

    1969-05-20

    The rate of gelling in aqueous compositions consisting of a galactomannan cross-linked by chromium ions provided by a soluble chromate is accelerated by the addition of a soluble-reducing agent to a hydrosol (colloidal solution) comprising the hydrate galactomannan prior to addition of the cross-linking agent. The accelerated cross-linking system is particularly suitable for use in blasting compositions comprising water, inorganic oxidizing salt, and one or more fuels and/or sensitizers. Accelerating the rate of cross-linking finds special utility in the on-site formulation and mixing of these compositions, particularly in equipment such as water gel trucks or slurry trucks. (7 claims)

  20. Innovative methods to reduce salt water intrusion in harbours

    Science.gov (United States)

    Groenenboom, J.; Uittenbogaard, R.; Hulsen, L.; van der Kaaij, T.; Kielen, N.

    2017-12-01

    The availability of fresh water in densely populated estuarine environments will in the future more often be threatened due to both human (e.g. channel deepening) and natural (sea-level rise, storm surges, extremely low river discharges) causes. Here, the salt water intrusion into the New Waterway, the main navigation channel of the port of Rotterdam, is used as a case study to elaborate on two innovative ways to mitigate the effects of salt water intrusion. The first method is based on the concept that vertical mixing of a salt wedge reduces its intrusion length. The idea is to equip a vessel with cranes that hold perforated tubes close to the bed alongside the vessel. By connecting compressors to the perforated tubes, a bubble screen with an adjustable vertical location can be created. Since the horizontal location of the bubble screens is not fixed, the vessel can sail in the vicinity of the moving salt wedge therewith increasing the effectiveness of the method. Another advantage of this intervention is that it can be deployed temporarily when the urgency for the prevention of salt water intrusion is high. The second method originates from the Port of Rotterdam Authority and is inspired by a small bypass that is present between two parallel channels (New Waterway and Caland Canal) connecting the North Sea to the Port of Rotterdam. Due to the different hydrodynamic characteristics of the hinterland of both channels, a difference in salinity and water level is present between both ends of the bypass. As a result, a lateral inflow of water into the New Waterway occurs at the same moment that the flood velocities transport saline water landwards. The lateral inflow of water into this channel has no momentum in the landward direction and therefore decreases the landward flow velocity and therewith the salt water intrusion. In addition, the inflow drives a vertical circulation that mixes the water column close to the bypass. Similar to the bubble screens mentioned

  1. Effect of electrolyzed reduced water on malondialdehyde levels and ...

    African Journals Online (AJOL)

    Purpose: To evaluate the effects of electrolyzed reduced water (ERW) on malondialdehyde (MDA) levels and neutrophil cells in Wistar rats suffering from aggressive periodontitis. Methods: Wistar rats (Rattus norvegicus) were infected with A. actinomycetemcomitans before being divided into a control group and a treatment ...

  2. Development of a soil water dispersion index (SOWADIN) for testing the effectiveness of a soil-wetting agent

    International Nuclear Information System (INIS)

    Sawada, Y.; Aylmore, L.A.G.; Hainsworth, J.M.

    1989-01-01

    Computer-assisted tomography (CAT) applied to gamma-ray attenuation measurement has been used to develop an index termed the soil water dispersion index (SOWADIN), which describes quantitatively the amount and distribution of water in soil columns. The index, which is determined by classifying pixels in a scanned slice into three categories according to their attenuation coefficients, contains two numerical values. The first value corresponds to the water content of the scanned slice and the second value is a measure of the dispersion of the water throughout the slice. Artificially wetted zones were created in soil columns to give one-third of the scanned layer wetted with various patterns of wetted-area distribution. The SOWADIN values obtained accurately reflected the differences in water distribution associated with the different patterns. Application of SOWADIN to columns of a water-repellent sand before and after treatment with a soil-wetting agent clearly illustrates both the increase in water content and improvement in water distribution in the soil column following treatment. 33 refs., 3 figs., 2 tabs

  3. Three-dimensional distributions of sewage markers in Tokyo Bay water-fluorescent whitening agents (FWAs)

    International Nuclear Information System (INIS)

    Managaki, Satoshi; Takada, Hideshige; Kim, Dong-Myung; Horiguchi, Toshihiro; Shiraishi, Hiroaki

    2006-01-01

    Three-dimensional distributions of fluorescent whitening agents (FWAs: more specifically, DSBP and DAS1), which are sewage-derived water-soluble markers, were observed in Tokyo Bay water through multi-layer sampling of water at 20 locations. In summer, FWAs predominated in the surface layers, with trace but significant concentration of FWAs in bottom water due to stratification of seawater. In winter, on the other hand, FWAs were extensively mixed into the bottom layers because of the vertical mixing of seawater. In the surface layer, FWA concentrations and the DSBP/DAS1 ratio (the concentration ratio of DSBP to DAS1) were lower in summer than in winter, suggesting more efficient photodegradation of FWAs in euphotic zones during the summer due to stronger solar radiation. Horizontally, FWAs were widely distributed over the surface layer of Tokyo Bay. Surface water with DSBP concentrations above 50 ng/L, corresponding to <200 times dilution of sewage effluent, was found to have spread up to 10 km from the coastline. In addition, an offshore decline in FWA concentrations was observed, showing a half-distance of 10-20 km. The decrease was caused by dilution by seawater of fresh water containing FWAs. The eastern part of the bay was different with respect to surface layers, with higher concentrations seen in northeastern parts. Furthermore, dispersion of combined sewer overflow (CSO)-derived water mass was observed in Tokyo Bay after heavy rain

  4. Waffle production: influence of batter ingredients on sticking of waffles at baking plates-Part II: effect of fat, leavening agent, and water.

    Science.gov (United States)

    Huber, Regina; Schoenlechner, Regine

    2017-05-01

    Fresh egg waffles are continuously baked in tunnel baking ovens in industrial scale. Waffles that partly or fully stick to the baking plates cause significant product loss and increased costs. The aim of this study was, therefore, to investigate the effect of different recipe ingredients on the sticking behavior of waffles. In this second part, ingredients investigated were different leavening agents (sodium acid pyrophosphate, ammonium bicarbonate, magnesium hydroxide carbonate, or monocalcium phosphate), different fat sources (rapeseed oil, cocos fat, butter, or margarine), and different water sources (tap water 12°dH and distilled water). Within the different types of fats, solid fats with high amount of short-chain fatty acids (cocos fat or butter) decreased the number of sticking waffles compared to liquid oils (rapeseed oil). Regarding leavening agents, magnesium hydroxide carbonate and ammonium bicarbonate were superior to sodium acid pyrophosphate or monocalcium phosphate. Between the two water sources, effects were small.

  5. Extinguishing agent for combustible metal fires

    Science.gov (United States)

    Riley, John F.; Stauffer, Edgar Eugene

    1976-10-12

    A low chloride extinguishing agent for combustible metal fires comprising from substantially 75 to substantially 94 weight percent of sodium carbonate as the basic fire extinguishing material, from substantially 1 to substantially 5 weight percent of a water-repellent agent such as a metal stearate, from substantially 2 to substantially 10 weight percent of a flow promoting agent such as attapulgus clay, and from substantially 3 to substantially 15 weight percent of a polyamide resin as a crusting agent.

  6. Modelling mitigation options to reduce diffuse nitrogen water pollution from agriculture.

    Science.gov (United States)

    Bouraoui, Fayçal; Grizzetti, Bruna

    2014-01-15

    Agriculture is responsible for large scale water quality degradation and is estimated to contribute around 55% of the nitrogen entering the European Seas. The key policy instrument for protecting inland, transitional and coastal water resources is the Water Framework Directive (WFD). Reducing nutrient losses from agriculture is crucial to the successful implementation of the WFD. There are several mitigation measures that can be implemented to reduce nitrogen losses from agricultural areas to surface and ground waters. For the selection of appropriate measures, models are useful for quantifying the expected impacts and the associated costs. In this article we review some of the models used in Europe to assess the effectiveness of nitrogen mitigation measures, ranging from fertilizer management to the construction of riparian areas and wetlands. We highlight how the complexity of models is correlated with the type of scenarios that can be tested, with conceptual models mostly used to evaluate the impact of reduced fertilizer application, and the physically-based models used to evaluate the timing and location of mitigation options and the response times. We underline the importance of considering the lag time between the implementation of measures and effects on water quality. Models can be effective tools for targeting mitigation measures (identifying critical areas and timing), for evaluating their cost effectiveness, for taking into consideration pollution swapping and considering potential trade-offs in contrasting environmental objectives. Models are also useful for involving stakeholders during the development of catchments mitigation plans, increasing their acceptability. © 2013.

  7. Using microbial desalination cells to reduce water salinity prior to reverse osmosis

    KAUST Repository

    Mehanna, Maha

    2010-01-01

    A microbial desalination cell (MDC) is a new method to reduce the salinity of one solution while generating electrical power from organic matter and bacteria in another (anode) solution. Substantial reductions in the salinity can require much larger volumes of the anode solution than the saline water, but any reduction of salinity will benefit the energy efficiency of a downstream reverse osmosis (RO) desalination system. We investigated here the use of an MDC as an RO pre-treatment method using a new type of air-cathode MDC containing three equally sized chambers. A single cycle of operation using a 1 g L -1 acetate solution reduced the conductivity of salt water (5 g L-1 NaCl) by 43 ± 6%, and produced a maximum power density of 480 mW m-2 with a coulombic efficiency of 68 ± 11%. A higher concentration of acetate (2 g L-1) reduced solution conductivity by 60 ± 7%, and a higher salt concentration (20 g L-1 NaCl) reduced solution conductivity by 50 ± 7%. The use of membranes with increased ion exchange capacities further decreased the solution conductivity by 63 ± 2% (20 g L-1 NaCl). These results demonstrate substantial (43-67%) desalination of water is possible using equal volumes of anode solution and salt water. These results show that MDC treatment could be used to substantially reduce salt concentrations and thus energy demands for downstream RO processing, while at the same time producing electrical power. © 2010 The Royal Society of Chemistry.

  8. Reducing water freshwater consumption at coal-fired power plants : approaches used outside the United States.

    Energy Technology Data Exchange (ETDEWEB)

    Elcock, D. (Environmental Science Division)

    2011-05-09

    Coal-fired power plants consume huge quantities of water, and in some water-stressed areas, power plants compete with other users for limited supplies. Extensive use of coal to generate electricity is projected to continue for many years. Faced with increasing power demands and questionable future supplies, industries and governments are seeking ways to reduce freshwater consumption at coal-fired power plants. As the United States investigates various freshwater savings approaches (e.g., the use of alternative water sources), other countries are also researching and implementing approaches to address similar - and in many cases, more challenging - water supply and demand issues. Information about these non-U.S. approaches can be used to help direct near- and mid-term water-consumption research and development (R&D) activities in the United States. This report summarizes the research, development, and deployment (RD&D) status of several approaches used for reducing freshwater consumption by coal-fired power plants in other countries, many of which could be applied, or applied more aggressively, at coal-fired power plants in the United States. Information contained in this report is derived from literature and Internet searches, in some cases supplemented by communication with the researchers, authors, or equipment providers. Because there are few technical, peer-reviewed articles on this topic, much of the information in this report comes from the trade press and other non-peer-reviewed references. Reducing freshwater consumption at coal-fired power plants can occur directly or indirectly. Direct approaches are aimed specifically at reducing water consumption, and they include dry cooling, dry bottom ash handling, low-water-consuming emissions-control technologies, water metering and monitoring, reclaiming water from in-plant operations (e.g., recovery of cooling tower water for boiler makeup water, reclaiming water from flue gas desulfurization [FGD] systems), and

  9. An agent-based model of farmer decision-making and water quality impacts at the watershed scale under markets for carbon allowances and a second-generation biofuel crop

    Science.gov (United States)

    Ng, Tze Ling; Eheart, J. Wayland; Cai, Ximing; Braden, John B.

    2011-09-01

    An agent-based model of farmers' crop and best management practice (BMP) decisions is developed and linked to a hydrologic-agronomic model of a watershed, to examine farmer behavior, and the attendant effects on stream nitrate load, under the influence of markets for conventional crops, carbon allowances, and a second-generation biofuel crop. The agent-based approach introduces interactions among farmers about new technologies and market opportunities, and includes the updating of forecast expectations and uncertainties using Bayesian inference. The model is applied to a semi-hypothetical example case of farmers in the Salt Creek Watershed in Central Illinois, and a sensitivity analysis is performed to effect a first-order assessment of the plausibility of the results. The results show that the most influential factors affecting farmers' decisions are crop prices, production costs, and yields. The results also show that different farmer behavioral profiles can lead to different predictions of farmer decisions. The farmers who are predicted to be more likely to adopt new practices are those who interact more with other farmers, are less risk averse, quick to adjust their expectations, and slow to reduce their forecast confidence. The decisions of farmers have direct water quality consequences, especially those pertaining to the adoption of the second-generation biofuel crop, which are estimated to lead to reductions in stream nitrate load. The results, though empirically untested, appear plausible and consistent with general farmer behavior. The results demonstrate the usefulness of the coupled agent-based and hydrologic-agronomic models for normative research on watershed management on the water-energy nexus.

  10. Preparation of Nano-Scale Biopolymer Extracted from Coconut Residue and Its Performance as Drag Reducing Agent (DRA

    Directory of Open Access Journals (Sweden)

    Hasan Muhammad Luqman Bin

    2017-01-01

    Full Text Available Drag or frictional force is defined as force that acts opposite to the object’s relative motion through a fluid which then will cause frictional pressure loss in the pipeline. Drag Reducing Agent (DRA is used to solve this issue and most of the DRAs are synthetic polymers but has some environmental issues. Therefore for this study, biopolymer known as Coconut Residue (CR is selected as the candidate to replace synthetic polymers DRA. The objective of this study is to evaluate the effectiveness of Nano-scale biopolymer DRA on the application of water injection system. Carboxymethyl cellulose (CMC is extracted by synthesizing the cellulose extracted from CR under the alkali-catalyzed reaction using monochloroacetic acid. The synthesize process is held in controlled condition whereby the concentration of NaOH is kept at 60%wt, 60 °C temperature and the reaction time is 4 hours. For every 25 g of dried CR used, the mass of synthesized CMC yield is at an average of 23.8 g. The synthesized CMC is then grinded in controlled parameters using the ball milling machine to get the Nano-scale size. The particle size obtained from this is 43.32 Nm which is in range of Nano size. This study proved that Nano-size CMC has higher percentage of drag reduction (%DR and flow increase (%FI if compared to normal-size CMC when tested in high and low flow rate; 44% to 48% increase in %DR and %FI when tested in low flow rate, and 16% to 18% increase in %DR and %FI when tested in high flow rate. The success of this research shows that Nano-scale DRA can be considered to be used to have better performance in reducing drag.

  11. Study of Water-Oil Emulsion Breaking by Stabilized Solution Consisting of Anionic Surface Acting Agent - Soda Ash - Polymer (ASP)

    Science.gov (United States)

    Kulichkov, S. V.; Avtomonov, E. G.; Andreeva, L. V.; Solomennik, S. F.; Nikitina, A. V.

    2018-01-01

    The paper provides a laboratory research of breaking natural water-oil emulsions: - by non-stabilized ASP; by stabilized ASP; by mixture of stabilized and non-stabilized ASP in different proportions and production of refinery water of the required quality with the use of IronGuard 2495 as flocculant. Oil-in-water emulsion is stable. Classic methods are not suitable for residual water treatment: sediment gravity flow; filtration; centrifuge test. Microemulsion formed after ASP application has low boundary tension and high pH. It contributes to transfer of oil phase into a water one, forming oil-in-water emulsion. Alkaline condition has adverse effect on demulsifying ability of agents, flocculation and boundary tension. For breaking of water-oil emulsion at EBU before the interchanger water or water-oil emulsion from the wells that were not APS-treated in ratio of 1:9 shall be delivered. Residual water after EBU must be prepared in water tanks by dilution in great volume.

  12. Can Mobile-Enabled Payment Methods Reduce Petty Corruption in Urban Water Provision?

    Directory of Open Access Journals (Sweden)

    Aaron Krolikowski

    2014-02-01

    Full Text Available Corruption in the urban water sector constrains economic growth and human development in low-income countries. This paper empirically evaluates the ability of novel mobile-enabled payment methods to reduce information asymmetries and mitigate petty corruption in the urban water sector’s billing and payment processes. Overcoming these barriers may promote improved governance and water service delivery. The case of Dar es Salaam is used to explore the role of mobile-enabled payment instruments through the use of a stratified random sample of 1097 water utility customers and 42 interviews with representatives from the water sector, the telecommunications industry, civil society, and banking institutions. Results show that mobile-enabled payment methods can reduce information asymmetries and the incidence of petty corruption to promote improved financial management by making payment data more transparent and limiting the availability of economic rents in the billing and payment process. Implications for African urban water services include wider availability and more effective use of human and financial resources. These can be used to enhance water service delivery and citizen participation in the production of urban water supplies. The use of mobile-enabled payment methods in the urban water sector represents an application of mobile communication technologies in a low-income country with proven potential for scalability that simultaneously supports the achievement of development objectives.

  13. Electrospun alginate nanofibres as potential bio-sorption agent of heavy metals in water treatment

    CSIR Research Space (South Africa)

    Mokhena, Teboho C

    2017-03-01

    Full Text Available nanofibres as potential bio-sorption agent of heavy metals in water treatment T.C. Mokhena1,2, N.V Jacobs1,3, A.S. Luyt4* 1 CSIR Materials Science and Manufacturing, Polymers and Composites, Port Elizabeth, South Africa 2 Department of Chemistry...-303 (2011). http://dx.doi.org/10.1016/j.jare.2011.01.008 [2] Taha A.A., Wu Y.-N., Wang H., Li F.: Preparation and application of functionalized cellulose acetate/silica composite nanofibrous membrane via electrospinning for Cr (VI) ion removal from...

  14. Life cycle assessment of central softening of very hard drinking water

    DEFF Research Database (Denmark)

    Godskesen, Berit; Hauschild, Michael Zwicky; Rygaard, Martin

    2012-01-01

    Life Cycle Assessment (LCA) to quantify the environmental impacts of central softening of drinking water considering both the negative effects at the waterworks and the positive effects imposed by the changed water quality in the households. The LCA modeling considered central softening of drinking......Many consumers prefer softened water due to convenience issues such as avoidance of removing limescale deposits from household appliances and surfaces, and to reduce consumption of cleaning agents and laundry detergents leading to lower household expenses. Even though central softening of drinking...... water entailed an increased use of energy, sand and chemicals at the waterworks, the distributed and softened drinking water supported a decrease in consumption of energy and chemical agents in the households along with a prolonged service life of household appliances which heat water. This study used...

  15. Can aquatic macrophytes be biofilters for gadolinium based contrasting agents?

    Science.gov (United States)

    Braun, Mihály; Zavanyi, Györgyi; Laczovics, Attila; Berényi, Ervin; Szabó, Sándor

    2018-05-15

    The use of gadolinium-based contrasting agents (GBCA) is increasing because of the intensive usage of these agents in magnetic resonance imaging (MRI). Waste-water treatment does not reduce anthropogenic Gd-concentration significantly. Anomalous Gd-concentration in surface waters have been reported worldwide. However, removal of GBCA-s by aquatic macrophytes has still hardly been investigated. Four aquatic plant species (Lemna gibba, Ceratophyllum demersum, Elodea nuttallii, E. canadensis) were investigated as potential biological filters for removal of commonly used but structurally different GBCA-s (Omniscan, Dotarem) from water. These plant species are known to accumulate heavy metals and are used for removing pollutants in constructed wetlands. The Gd uptake and release of the plants was examined under laboratory conditions. Concentration-dependent infiltration of Gd into the body of the macrophytes was measured, however significant bioaccumulation was not observed. The tissue concentration of Gd reached its maximum value between day one and four in L. gibba and C. demersum, respectively, and its volume was significantly higher in C. demersum than in L. gibba. In C. demersum, the open-chain ligand Omniscan causes two-times higher tissue Gd concentration than the macrocyclic ligand Dotarem. Gadolinium was released from Gd-treated duckweeds into the water as they were grown further in Gd-free nutrient solution. Tissue Gd concentration dropped by 50% in duckweed treated by Omniscan and by Dotarem within 1.9 and 2.9 days respectively. None of the macrophytes had a significant impact on the Gd concentration of water in low and medium concentration levels (1-256 μg L -1 ). Biofiltration of GBCA-s by common macrophytes could not be detected in our experiments. Therefore it seems that in constructed wetlands, aquatic plants are not able to reduce the concentration of GBCA-s in the water. Furthermore there is a low risk that these plants cause the

  16. Water neutral: reducing and ofsetting water footprints

    NARCIS (Netherlands)

    Hoekstra, Arjen Ysbert

    2008-01-01

    During the past few years the concept of the ‘water footprint’ has started to receive recognition within governments, non-governmental organizations, businesses and media as a useful indicator of water use. The increased interest in the water-footprint concept has prompted the question about what

  17. The efficacy of targeted health agents education to reduce the duration of untreated psychosis in a rural population.

    Science.gov (United States)

    Padilla, Eduardo; Molina, Juan; Kamis, Danielle; Calvo, Maria; Stratton, Lee; Strejilevich, Sergio; Aleman, Gabriela Gonzalez; Guerrero, Gonzalo; Bourdieu, Mercedes; Conesa, Horacio A; Escobar, Javier I; de Erausquin, Gabriel A

    2015-02-01

    The duration of untreated psychosis (DUP) is a key determinant in the severity of symptoms in patients with schizophrenia. DUP is a modifiable factor that if reduced can improve patient outcome and treatment response. We sought to decrease DUP in rural Argentina by instituting annual training of local health agents to better identify signs of mental illness and offer earlier intervention. DUP was estimated using Schedules of Clinical Assessment in Neuropsychiatry (SCAN). Ongoing training was correlated with a reduction in DUP. Reducing DUP through better screening can decrease the psychosocial burden of disease and improve the trajectory of psychosis. Copyright © 2014 Elsevier B.V. All rights reserved.

  18. Multi-agent modelling framework for water, energy and other resource networks

    Science.gov (United States)

    Knox, S.; Selby, P. D.; Meier, P.; Harou, J. J.; Yoon, J.; Lachaut, T.; Klassert, C. J. A.; Avisse, N.; Mohamed, K.; Tomlinson, J.; Khadem, M.; Tilmant, A.; Gorelick, S.

    2015-12-01

    Bespoke modelling tools are often needed when planning future engineered interventions in the context of various climate, socio-economic and geopolitical futures. Such tools can help improve system operating policies or assess infrastructure upgrades and their risks. A frequently used approach is to simulate and/or optimise the impact of interventions in engineered systems. Modelling complex infrastructure systems can involve incorporating multiple aspects into a single model, for example physical, economic and political. This presents the challenge of combining research from diverse areas into a single system effectively. We present the Pynsim 'Python Network Simulator' framework, a library for building simulation models capable of representing, the physical, institutional and economic aspects of an engineered resources system. Pynsim is an open source, object oriented code aiming to promote integration of different modelling processes through a single code library. We present two case studies that demonstrate important features of Pynsim's design. The first is a large interdisciplinary project of a national water system in the Middle East with modellers from fields including water resources, economics, hydrology and geography each considering different facets of a multi agent system. It includes: modelling water supply and demand for households and farms; a water tanker market with transfer of water between farms and households, and policy decisions made by government institutions at district, national and international level. This study demonstrates that a well-structured library of code can provide a hub for development and act as a catalyst for integrating models. The second focuses on optimising the location of new run-of-river hydropower plants. Using a multi-objective evolutionary algorithm, this study analyses different network configurations to identify the optimal placement of new power plants within a river network. This demonstrates that Pynsim can be

  19. Developing Automatic Water Table Control System for Reducing Greenhouse Gas Emissions from Paddy Fields

    Science.gov (United States)

    Arif, C.; Fauzan, M. I.; Satyanto, K. S.; Budi, I. S.; Masaru, M.

    2018-05-01

    Water table in rice fields play important role to mitigate greenhouse gas (GHG) emissions from paddy fields. Continuous flooding by maintenance water table 2-5 cm above soil surface is not effective and release more GHG emissions. System of Rice Intensification (SRI) as alternative rice farming apply intermittent irrigation by maintaining lower water table is proven can reduce GHG emissions reducing productivity significantly. The objectives of this study were to develop automatic water table control system for SRI application and then evaluate the performances. The control system was developed based on fuzzy logic algorithms using the mini PC of Raspberry Pi. Based on laboratory and field tests, the developed system was working well as indicated by lower MAPE (mean absolute percentage error) values. MAPE values for simulation and field tests were 16.88% and 15.80%, respectively. This system can save irrigation water up to 42.54% without reducing productivity significantly when compared to manual irrigation systems.

  20. RSDL decontamination of human skin contaminated with the nerve agent VX.

    Science.gov (United States)

    Thors, L; Lindberg, S; Johansson, S; Koch, B; Koch, M; Hägglund, L; Bucht, A

    2017-03-05

    Dermal exposure to low volatile organophosphorus compounds (OPC) may lead to penetration through the skin and uptake in the blood circulation. Skin decontamination of toxic OPCs, such as pesticides and chemical warfare nerve agents, might therefore be crucial for mitigating the systemic toxicity following dermal exposure. Reactive skin decontamination lotion (RSDL) has been shown to reduce toxic effects in animals dermally exposed to the nerve agent VX. In the present study, an in vitro flow-through diffusion cell was utilized to evaluate the efficacy of RSDL for decontamination of VX exposed to human epidermis. In particular, the impact of timing in the initiation of decontamination and agent dilution in water was studied. The impact of the lipophilic properties of VX in the RSDL decontamination was additionally addressed by comparing chemical degradation in RSDL and decontamination efficacy between the VX and the hydrophilic OPC triethyl phosphonoacetate (TEPA). The epidermal membrane was exposed to 20, 75 or 90% OPC diluted in deionized water and the decontamination was initiated 5, 10, 30, 60 or 120min post-exposure. Early decontamination of VX with RSDL, initiated 5-10min after skin exposure, was very effective. Delayed decontamination initiated 30-60min post-exposure was less effective but still the amount of penetrated agent was significantly reduced, while further delayed start of decontamination to 120min resulted in very low efficacy. Comparing RSDL decontamination of VX with that of TEPA showed that the decontamination efficacy at high agent concentrations was higher for VX. The degradation mechanism of VX and TEPA during decontamination was dissected by 31 P NMR spectroscopy of the OPCs following reactions with RSDL and its three nucleophile components. The degradation rate was clearly associated with the high pH of the specific solution investigated; i.e. increased pH resulted in a more rapid degradation. In addition, the solubility of the OPC in RSDL

  1. An intelligent agent for optimal river-reservoir system management

    Science.gov (United States)

    Rieker, Jeffrey D.; Labadie, John W.

    2012-09-01

    A generalized software package is presented for developing an intelligent agent for stochastic optimization of complex river-reservoir system management and operations. Reinforcement learning is an approach to artificial intelligence for developing a decision-making agent that learns the best operational policies without the need for explicit probabilistic models of hydrologic system behavior. The agent learns these strategies experientially in a Markov decision process through observational interaction with the environment and simulation of the river-reservoir system using well-calibrated models. The graphical user interface for the reinforcement learning process controller includes numerous learning method options and dynamic displays for visualizing the adaptive behavior of the agent. As a case study, the generalized reinforcement learning software is applied to developing an intelligent agent for optimal management of water stored in the Truckee river-reservoir system of California and Nevada for the purpose of streamflow augmentation for water quality enhancement. The intelligent agent successfully learns long-term reservoir operational policies that specifically focus on mitigating water temperature extremes during persistent drought periods that jeopardize the survival of threatened and endangered fish species.

  2. Destruction of chemical agent simulants in a supercritical water oxidation bench-scale reactor

    Energy Technology Data Exchange (ETDEWEB)

    Veriansyah, Bambang [Supercritical Fluid Research Laboratory, Clean Technology Research Center, Korea Institute of Science and Technology (KIST), 39-1 Hawolgok-dong, Seongbuk-gu, Seoul 136-791 (Korea, Republic of) and Department of Green Process and System Engineering, University of Science and Technology, 39-1 Hawolgok-dong, Seongbuk-gu, Seoul 136-791 (Korea, Republic of)]. E-mail: vaveri@kist.re.kr; Kim, Jae-Duck [Supercritical Fluid Research Laboratory, Clean Technology Research Center, Korea Institute of Science and Technology (KIST), 39-1 Hawolgok-dong, Seongbuk-gu, Seoul 136-791 (Korea, Republic of) and Department of Green Process and System Engineering, University of Science and Technology, 39-1 Hawolgok-dong, Seongbuk-gu, Seoul 136-791 (Korea, Republic of)]. E-mail: jdkim@kist.re.kr; Lee, Jong-Chol [Agency for Defense Development (ADD), P.O. Box 35-1, Yuseong-gu, Daejeon (Korea, Republic of)]. E-mail: jcleeadd@hanafos.com

    2007-08-17

    A new design of supercritical water oxidation (SCWO) bench-scale reactor has been developed to handle high-risk wastes resulting from munitions demilitarization. The reactor consists of a concentric vertical double wall in which SCWO reaction takes place inside an inner tube (titanium grade 2, non-porous) whereas pressure resistance is ensured by a Hastelloy C-276 external vessel. The performances of this reactor were investigated with two different kinds of chemical warfare agent simulants: OPA (a mixture of isopropyl amine and isopropyl alcohol) as the binary precursor for nerve agent of sarin and thiodiglycol [TDG (HOC{sub 2}H{sub 4}){sub 2}S] as the model organic sulfur heteroatom. High destruction rates based on total organic carbon (TOC) were achieved (>99.99%) without production of chars or undesired gases such as carbon monoxide and methane. The carbon-containing product was carbon dioxide whereas the nitrogen-containing products were nitrogen and nitrous oxide. Sulfur was totally recovered in the aqueous effluent as sulfuric acid. No corrosion was noticed in the reactor after a cumulative operation time of more than 250 h. The titanium tube shielded successfully the pressure vessel from corrosion.

  3. Improving performance of HVAC systems to reduce exposure to aerosolized infectious agents in buildings; recommendations to reduce risks posed by biological attacks.

    Science.gov (United States)

    Hitchcock, Penny J; Mair, Michael; Inglesby, Thomas V; Gross, Jonathan; Henderson, D A; O'Toole, Tara; Ahern-Seronde, Joa; Bahnfleth, William P; Brennan, Terry; Burroughs, H E Barney; Davidson, Cliff; Delp, William; Ensor, David S; Gomory, Ralph; Olsiewski, Paula; Samet, Jonathan M; Smith, William M; Streifel, Andrew J; White, Ronald H; Woods, James E

    2006-01-01

    The prospect of biological attacks is a growing strategic threat. Covert aerosol attacks inside a building are of particular concern. In the summer of 2005, the Center for Biosecurity of the University of Pittsburgh Medical Center convened a Working Group to determine what steps could be taken to reduce the risk of exposure of building occupants after an aerosol release of a biological weapon. The Working Group was composed of subject matter experts in air filtration, building ventilation and pressurization, air conditioning and air distribution, biosecurity, building design and operation, building decontamination and restoration, economics, medicine, public health, and public policy. The group focused on functions of the heating, ventilation, and air conditioning systems in commercial or public buildings that could reduce the risk of exposure to deleterious aerosols following biological attacks. The Working Group's recommendations for building owners are based on the use of currently available, off-the-shelf technologies. These recommendations are modest in expense and could be implemented immediately. It is also the Working Group's judgment that the commitment and stewardship of a lead government agency is essential to secure the necessary financial and human resources and to plan and build a comprehensive, effective program to reduce exposure to aerosolized infectious agents in buildings.

  4. Reducing water losses via intelligent pressure management; Reduzierung von Wasserverlusten durch intelligentes Druckmanagement

    Energy Technology Data Exchange (ETDEWEB)

    Oppinger, Peter [VAG-Armaturen GmbH, Mannheim (Germany). Marketing

    2008-03-15

    Leaks in water pipes and leaking municipal water-transmission and piping systems, particularly in developing and threshold countries account for water-losses of up to 50% of the water supplied by the waterworks. This article examines three different solutions for effective pressure management on the basis of an intelligent control system, by means of which water-losses can be reduced to a stable and economically rational level. (orig.)

  5. Stable radiographic scanning agents

    International Nuclear Information System (INIS)

    1976-01-01

    Stable compositions which are useful in the preparation of Technetium-99m-based scintigraphic agents are discussed. They are comprised of ascorbic acid or a pharmaceutically acceptable salt or ester thereof in combination with a pertechnetate reducing agent or dissolved in oxidized pertechnetate-99m (sup(99m)TcO 4 - ) solution

  6. The effect of reducing agents on the electronic, magnetic and electrocatalytic properties of thiol-capped Pt/Co and Pt/Ni nanoparticles

    CSIR Research Space (South Africa)

    Mathe, NR

    2015-05-01

    Full Text Available The electronic, magnetic and electrocatalytic properties of bimetallic thiol-capped Pt/Co and Pt/Ni nanoparticles were synthesised using two reducing agents, NaBH(sub4) and N(sub2)H(sub4). X-ray diffraction analysis of the nanoparticles showed Pt...

  7. Estabilishing requirements for the next generation of pressurized water reactors--reducing the uncertainty

    International Nuclear Information System (INIS)

    Chernock, W.P.; Corcoran, W.R.; Rasin, W.H.; Stahlkopf, K.E.

    1987-01-01

    The Electric Power Research Institute is managing a major effort to establish requirements for the next generation of U.S. light water reactors. This effort is the vital first step in preserving the viability of the nuclear option to contribute to meet U.S. national electric power capacity needs in the next century. Combustion Engineering, Inc. and Duke Power Company formed a team to participate in the EPRI program which is guided by a Utility Steering committee consisting of experienced utility technical executives. A major thrust of the program is to reduce the uncertainties which would be faced by the utility executives in choosing the nuclear option. The uncertainties to be reduced include those related to safety, economic, operational, and regulatory aspects of advanced light water reactors. This paper overviews the Requirements Document program as it relates to the U.S. Advanced Light Water Reactor (ALWR) effort in reducing these uncertainties and reports the status of efforts to establish requirements for the next generation of pressurized water reactors. It concentrates on progress made in reducing the uncertainties which would deter selection of the nuclear option for contributing to U.S. national electric power capacity needs in the next century and updates previous reports in the same area. (author)

  8. Levels of Organisation in agent-based modelling for renewable resources management. Agricultural water management collective rules enforcement in the French Drome River Valley Case Study

    International Nuclear Information System (INIS)

    Abrami, G.

    2004-11-01

    Levels of Organisation in agent-based modelling for renewable resources management. Agricultural water management collective rules enforcement in the French Dr me River Valley Case Study. In the context of Agent-Based Modelling for participative renewable resources management, this thesis is concerned with representing multiple tangled levels of organisation of a system. The Agent-Group-Role (AGR) formalism is borrowed from computer science research. It has been conceptually specified to handle levels of organisation, and behaviours within levels of organisation. A design methodology dedicated to AGR modelling has been developed, together with an implementation of the formalism over a multi-agent platform. AGR models of agricultural water management in the French Dr me River Valley have been built and tested. This experiment demonstrates the AGR formalism ability to (1) clarify usually implicit hypothesis on action modes, scales or viewpoints (2) facilitate the definition of scenarios with various collective rules, and various rules in enforcement behaviours (3) generate bricks for generic irrigated catchment models. (author)

  9. Hydrogen as a New Class of Radioprotective Agent

    Science.gov (United States)

    Qian, Liren; Shen, Jianliang; Chuai, Yunhai; Cai, Jianming

    2013-01-01

    It is well known that most of the ionizing radiation-induced damage is caused by hydroxyl radicals (·OH) follows radiolysis of H2O. Molecular hydrogen (H2) has antioxidant activities by selectively reducing ·OH and peroxynitrite(ONOO-). We firstly hypothesized and demonstrated the radioprotective effect of H2 in vitro and in vivo, which was also repeated on different experimental animal models by different departments. A randomized, placebo-controlled study showed that consumption of hydrogen-rich water reduces the biological reaction to radiation-induced oxidative stress without compromising anti-tumor effects. These encouraging results suggested that H2 represents a potentially novel preventative strategy for radiation-induced oxidative injuries. H2 is explosive. Therefore, administration of hydrogen-rich solution (physiological saline/pure water/other solutions saturated with H2) may be more practical in daily life and more suitable for daily consumption. This review focuses on major scientific and clinical advances of hydrogen-rich solution/H2 as a new class of radioprotective agent. PMID:24155664

  10. High spatial resolution and high contrast visualization of brain arteries and veins. Impact of blood pool contrast agent and water-selective excitation imaging at 3T

    International Nuclear Information System (INIS)

    Spuentrup, E.; Jacobs, J.E.; Kleimann, J.F.

    2010-01-01

    Purpose: To investigate a blood pool contrast agent and water-selective excitation imaging at 3 T for high spatial and high contrast imaging of brain vessels including the veins. Methods and Results: 48 clinical patients (47 ± 18 years old) were included. Based on clinical findings, twenty-four patients received a single dose of standard extracellular Gadoterate-meglumine (Dotarem registered ) and 24 received the blood pool contrast agent Gadofosveset (Vasovist registered ). After finishing routine MR protocols, all patients were investigated with two high spatial resolution (0.15 mm 3 voxel size) gradient echo sequences in random order in the equilibrium phase (steady-state) as approved by the review board: A standard RF-spoiled gradient-echo sequence (HR-SS, TR/TE 5.1 / 2.3 msec, FA 30 ) and a fat-suppressed gradient-echo sequence with water-selective excitation (HR-FS, 1331 binominal-pulse, TR/TE 8.8 / 3.8 msec, FA 30 ). The images were subjectively assessed (image quality with vessel contrast, artifacts, depiction of lesions) by two investigators and contrast-to-noise ratios (CNR) were compared using the Student's t-test. The image quality and CNR in the HR-FS were significantly superior compared to the HR-SS for both contrast agents (p < 0.05). The CNR was also improved when using the blood pool agent but only to a minor extent while the subjective image quality was similar for both contrast agents. Conclusion: The utilized sequence with water-selective excitation improved image quality and CNR properties in high spatial resolution imaging of brain arteries and veins. The used blood pool contrast agent improved the CNR only to a minor extent over the extracellular contrast agent. (orig.)

  11. Water cycle and its management for plant habitats at reduced pressures

    Science.gov (United States)

    Rygalov, Vadim Y.; Fowler, Philip A.; Wheeler, Raymond M.; Bucklin, Ray A.

    2004-01-01

    Experimental and mathematical models were developed for describing and testing temperature and humidity parameters for plant production in bioregenerative life support systems. A factor was included for analyzing systems operating at low (10-101.3 kPa) pressure to reduce gas leakage and structural mass (e.g., inflatable greenhouses for space application). The expected close relationship between temperature and relative humidity was observed, along with the importance of heat exchanger coil temperature and air circulation rate. The presence of plants in closed habitats results in increased water flux through the system. Changes in pressure affect gas diffusion rates and surface boundary layers, and change convective transfer capabilities and water evaporation rates. A consistent observation from studies with plants at reduced pressures is increased evapotranspiration rates, even at constant vapor pressure deficits. This suggests that plant water status is a critical factor for managing low-pressure production systems. The approach suggested should help space mission planners design artificial environments in closed habitats.

  12. Method and container for reducing pertechnetate

    International Nuclear Information System (INIS)

    Ruddock, C.F.

    1980-01-01

    A method of reducing the pertechnetate in TcO 4 - comprises mixing together an aqueous solution of pertechnetate, e.g. the eluant from a technetium generator, metallic tin or an alloy thereof as a reducing agent for the pertechnetate, and a soluble salt of a metal below tin in the electrochemical series, e.g. copper, as an activator for the tin metal reducing agent. A complexing agent for the reduced technetium or a colloid stabiliser may also be included. The pH is preferably 3 to 12. Also claimed is a closed container containing the tin reducing agent, the activator, and the complexant or colloid stabiliser if used, preferably in a freeze-dried sterile state, to which the pertechnetate solution may be added. (author)

  13. Radioactive scanning agents with stabilizer

    International Nuclear Information System (INIS)

    Fawzi, M.B.

    1982-01-01

    Stable compositions useful as technetium 99-based scintigraphic agents comprise gentisyl alcohol or a pharmaceutically-acceptable salt or ester thereof in combination with a pertechnetate reducing agent or dissolved in pertechnetate-99m (sup(99m)TcOsub(4)sup(-)) solution. The compositions are especially useful in combination with a phosphate or phosphonate material that carries the radionuclide to bone, thus providing a skeletal imaging agent

  14. Research on Reduced-Moderation Water Reactor (RMWR)

    International Nuclear Information System (INIS)

    Iwamura, Takamichi; Okubo, Tsutomu; Shimada, Shoichiro

    1999-11-01

    The Reduced-Moderation Water Reactor (RMWR) is a next generation water-cooled reactor which aims at effective utilization of uranium resource, high burn-up and long operation cycle, and plutonium multi-recycle. These characteristics can be achieved by the high conversion ratio from 238 U to 239 Pu resulted from the higher neutron energy spectrum in comparison to conventional light water reactors. Considering the extension of LWR utilization, Japan Atomic Energy Research Institute (JAERI) started the research on it in 1997 and then started a collaboration in the conceptual design study with the Japan Atomic Power Company (JAPCO) in 1998. In the core design study of the RMWR, negative void reactivity coefficient is required from a viewpoint of safety as well as establishing hard neutron spectrum. In order to achieve the above trade-off characteristics simultaneously, several basic core design ideas should be combined, such as a tight lattice fuel assembly, a flat core, a blanket effect, a streaming effect and so on. Up to now, five core concepts have been created for the RMWR as follows: a high conversion BWR with high void fraction and super-flat core, a long operation cycle BWR using void channels, a high conversion BWR without blankets, a high conversion PWR using heavy water as a coolant, and a PWR for plutonium multi-recycle using seed-blanket type fuel assemblies. The present report summarizes the objectives, domestic and international trends, principles and characteristics, core conceptual designs and future R and D plans of the RMWR. (J.P.N.)

  15. Research on Reduced-Moderation Water Reactor (RMWR)

    Energy Technology Data Exchange (ETDEWEB)

    Iwamura, Takamichi; Okubo, Tsutomu; Shimada, Shoichiro [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment] [and others

    1999-11-01

    The Reduced-Moderation Water Reactor (RMWR) is a next generation water-cooled reactor which aims at effective utilization of uranium resource, high burn-up and long operation cycle, and plutonium multi-recycle. These characteristics can be achieved by the high conversion ratio from {sup 238}U to {sup 239}Pu resulted from the higher neutron energy spectrum in comparison to conventional light water reactors. Considering the extension of LWR utilization, Japan Atomic Energy Research Institute (JAERI) started the research on it in 1997 and then started a collaboration in the conceptual design study with the Japan Atomic Power Company (JAPCO) in 1998. In the core design study of the RMWR, negative void reactivity coefficient is required from a viewpoint of safety as well as establishing hard neutron spectrum. In order to achieve the above trade-off characteristics simultaneously, several basic core design ideas should be combined, such as a tight lattice fuel assembly, a flat core, a blanket effect, a streaming effect and so on. Up to now, five core concepts have been created for the RMWR as follows: a high conversion BWR with high void fraction and super-flat core, a long operation cycle BWR using void channels, a high conversion BWR without blankets, a high conversion PWR using heavy water as a coolant, and a PWR for plutonium multi-recycle using seed-blanket type fuel assemblies. The present report summarizes the objectives, domestic and international trends, principles and characteristics, core conceptual designs and future R and D plans of the RMWR. (J.P.N.)

  16. Transport behavior of surrogate biological warfare agents in a simulated landfill: Effect of leachate recirculation and water infiltration

    KAUST Repository

    Saikaly, Pascal

    2010-11-15

    An understanding of the transport behavior of biological warfare (BW) agents in landfills is required to evaluate the suitability of landfills for the disposal of building decontamination residue (BDR) following a bioterrorist attack on a building. Surrogate BW agents, Bacillus atrophaeus spores and Serratia marcescens, were spiked into simulated landfill reactors that were filled with synthetic building debris (SBD) and operated for 4 months with leachate recirculation or water infiltration. Quantitative polymerase chain reaction (Q-PCR) was used to monitor surrogate transport. In the leachate recirculation reactors, <10% of spiked surrogates were eluted in leachate over 4 months. In contrast, 45% and 31% of spiked S. marcescens and B. atrophaeus spores were eluted in leachate in the water infiltration reactors. At the termination of the experiment, the number of retained cells and spores in SBD was measured over the depth of the reactor. Less than 3% of the total spiked S. marcescens cells and no B. atrophaeus spores were detected in SBD. These results suggest that significant fractions of the spiked surrogates were strongly attached to SBD. © 2010 American Chemical Society.

  17. Transport behavior of surrogate biological warfare agents in a simulated landfill: Effect of leachate recirculation and water infiltration

    KAUST Repository

    Saikaly, Pascal; Hicks, Kristin A.; Barlaz, Morton A.; De Los Reyes, Francis Delos De Los

    2010-01-01

    An understanding of the transport behavior of biological warfare (BW) agents in landfills is required to evaluate the suitability of landfills for the disposal of building decontamination residue (BDR) following a bioterrorist attack on a building. Surrogate BW agents, Bacillus atrophaeus spores and Serratia marcescens, were spiked into simulated landfill reactors that were filled with synthetic building debris (SBD) and operated for 4 months with leachate recirculation or water infiltration. Quantitative polymerase chain reaction (Q-PCR) was used to monitor surrogate transport. In the leachate recirculation reactors, <10% of spiked surrogates were eluted in leachate over 4 months. In contrast, 45% and 31% of spiked S. marcescens and B. atrophaeus spores were eluted in leachate in the water infiltration reactors. At the termination of the experiment, the number of retained cells and spores in SBD was measured over the depth of the reactor. Less than 3% of the total spiked S. marcescens cells and no B. atrophaeus spores were detected in SBD. These results suggest that significant fractions of the spiked surrogates were strongly attached to SBD. © 2010 American Chemical Society.

  18. Flotation of agent for breach of emulsion oil/water aiming treatment of water produced for the industry petroleum; Agente de flotacao (Tanfloc) para quebra de emulsao oleo/agua visando tratamento de aguas produzidas pela industria do petroleo

    Energy Technology Data Exchange (ETDEWEB)

    Miranda, A.C. de; Andrade, J.M. de; Melo, M.A.A.; Melo, D.M.A. [Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN (Brazil)

    2008-07-01

    This work was studied the action of an agent of flotation TanFloc broken emulsion in oil / water when its concentration varies and salinity. This material is used by Petroleum brazilian for removal of turbidity in the water from the petroleum industry. For the test set up a bench in the laboratory of the Environmental Technology UFRN for simulation of tests made on the field. To do so, was studied the concentration of TanFloc and it was found that the best concentration for removal of turbidity was 11ppm such material. It was found that the level of salinity affects particularly the results of turbidity therefore this was also one of the parameters studied. (author)

  19. Experimental and Numerical Study of Water Entry Supercavity Influenced by Turbulent Drag-Reducing Additives

    Directory of Open Access Journals (Sweden)

    Chen-Xing Jiang

    2014-04-01

    Full Text Available The configurational and dynamic characteristics of water entry supercavities influenced by turbulent drag-reducing additives were studied through supercavitating projectile approach, experimentally and numerically. The projectile was projected vertically into water and aqueous solution of CTAC with weight concentrations of 100, 500, and 1000 ppm, respectively, using a pneumatic nail gun. The trajectories of the projectile and the supercavity configuration were recorded by a high-speed CCD camera. Besides, water entry supercavities in water and CTAC solution were numerically simulated based on unsteady RANS scheme, together with application of VOF multiphase model. The Cross viscosity model was adopted to represent the fluid property of CTAC solution. It was obtained that the numerical simulation results are in consistence with experimental data. Numerical and experimental results all show that the length and diameter of supercavity in drag-reducing solution are larger than those in water, and the drag coefficient is smaller than that in water; the maintaining time of supercavity is longer in solution as well. The surface tension plays an important role in maintaining the cavity. Turbulent drag-reducing additives have the potential in enhancement of supercavitation and drag reduction.

  20. Morphological plasticity of root growth under mild water stress increases water use efficiency without reducing yield in maize

    Science.gov (United States)

    Cai, Qian; Zhang, Yulong; Sun, Zhanxiang; Zheng, Jiaming; Bai, Wei; Zhang, Yue; Liu, Yang; Feng, Liangshan; Feng, Chen; Zhang, Zhe; Yang, Ning; Evers, Jochem B.; Zhang, Lizhen

    2017-08-01

    A large yield gap exists in rain-fed maize (Zea mays L.) production in semi-arid regions, mainly caused by frequent droughts halfway through the crop-growing period due to uneven distribution of rainfall. It is questionable whether irrigation systems are economically required in such a region since the total amount of rainfall does generally meet crop requirements. This study aimed to quantitatively determine the effects of water stress from jointing to grain filling on root and shoot growth and the consequences for maize grain yield, above- and below-ground dry matter, water uptake (WU) and water use efficiency (WUE). Pot experiments were conducted in 2014 and 2015 with a mobile rain shelter to achieve conditions of no, mild or severe water stress. Maize yield was not affected by mild water stress over 2 years, while severe stress reduced yield by 56 %. Both water stress levels decreased root biomass slightly but shoot biomass substantially. Mild water stress decreased root length but increased root diameter, resulting in no effect on root surface area. Due to the morphological plasticity in root growth and the increase in root / shoot ratio, WU under water stress was decreased, and overall WUE for both above-ground dry matter and grain yield increased. Our results demonstrate that an irrigation system might be not economically and ecologically necessary because the frequently occurring mild water stress did not reduce crop yield much. The study helps us to understand crop responses to water stress during a critical water-sensitive period (middle of the crop-growing season) and to mitigate drought risk in dry-land agriculture.

  1. Morphological plasticity of root growth under mild water stress increases water use efficiency without reducing yield in maize

    Directory of Open Access Journals (Sweden)

    Q. Cai

    2017-08-01

    Full Text Available A large yield gap exists in rain-fed maize (Zea mays L. production in semi-arid regions, mainly caused by frequent droughts halfway through the crop-growing period due to uneven distribution of rainfall. It is questionable whether irrigation systems are economically required in such a region since the total amount of rainfall does generally meet crop requirements. This study aimed to quantitatively determine the effects of water stress from jointing to grain filling on root and shoot growth and the consequences for maize grain yield, above- and below-ground dry matter, water uptake (WU and water use efficiency (WUE. Pot experiments were conducted in 2014 and 2015 with a mobile rain shelter to achieve conditions of no, mild or severe water stress. Maize yield was not affected by mild water stress over 2 years, while severe stress reduced yield by 56 %. Both water stress levels decreased root biomass slightly but shoot biomass substantially. Mild water stress decreased root length but increased root diameter, resulting in no effect on root surface area. Due to the morphological plasticity in root growth and the increase in root ∕ shoot ratio, WU under water stress was decreased, and overall WUE for both above-ground dry matter and grain yield increased. Our results demonstrate that an irrigation system might be not economically and ecologically necessary because the frequently occurring mild water stress did not reduce crop yield much. The study helps us to understand crop responses to water stress during a critical water-sensitive period (middle of the crop-growing season and to mitigate drought risk in dry-land agriculture.

  2. Prevention of strong stench for stocked radioisotope sewerage using total water treatment agent for small-sized cooling towers

    International Nuclear Information System (INIS)

    Aoki, Katsumi; Nishimaki, Toshiyuki; Furuse, Yuko; Shinozuka, Akiko

    1996-01-01

    In general, the sewerage at radioisotope laboratories has very strong stench. We treated the sewerage with a total water treatment agent (Tachileslegi, Nippon Nouyaku Co., Ltd. ) that is widely used for prevention of slime, scale, corrosion in cooling towers. As the result, the stench was decreased to about two thirds to that of control estimated by odor-test. (author)

  3. Blasting agent package

    Energy Technology Data Exchange (ETDEWEB)

    Fox, R.

    1971-03-17

    A protected preassembled package for blasting agents susceptible to desensitization by water consists of, in combination: (1) an inner rigid and self-supporting tube, the upper end of which is suited to be connected, or attached, to the discharge end of a loading hose for a blasting agent and the lower end of which is open; and (2) a flexible tubular liner made of water-resistant film, having a diameter greater than that of the inner tube and a length at least equal to the desired depth of its insertion into the borehole, the liner being sleeved over the length of the inner tube, the upper end of the liner being attached to the inner tube and the lower end of the liner being closed so as to prevent substantial discharge of the explosive mixture therefrom when the latter is pumped into it. (24 claims)

  4. Reducing Moose-Vehicle Collisions through Salt Pool Removal and Displacement: an Agent-Based Modeling Approach

    Directory of Open Access Journals (Sweden)

    Paul D. Grosman

    2009-12-01

    Full Text Available Between 1990 and 2002, more than 200 moose-vehicle collisions occurred each year in Quebec, including about 50/yr in the Laurentides Wildlife Reserve. One cause is the presence of roadside salt pools that attract moose near roads in the spring and summer. Using the computer simulation technique of agent-based modeling, this study investigated whether salt pool removal and displacement, i.e., a compensatory salt pool set up 100 to 1500 m away from the road shoulder, would reduce the number of moose-vehicle collisions. Moose road crossings were used as a proxy measure. A GPS telemetry data set consisting of approximately 200,000 locations of 47 moose over 2 yr in the Laurentides Wildlife Reserve was used as an empirical basis for the model. Twelve moose were selected from this data set and programmed in the model to forage and travel in the study area. Five parameters with an additional application of stochasticity were used to determine moose movement between forest polygons. These included food quality; cover quality, i.e., protection from predators and thermal stress; proximity to salt pools; proximity to water; and slope. There was a significant reduction in road crossings when either all or two thirds of the roadside salt pools were removed, with and/or without salt pool displacement. With 100% salt pool removal, the reduction was greater (49% without compensatory salt pools than with them (18%. When two thirds of the salt pools were removed, the reduction was the same with and without compensatory salt pools (16%. Although moose-vehicle collisions are not a significant mortality factor for the moose population in the Laurentides Wildlife Reserve, in areas with higher road densities, hunting pressure, and/or predator densities it could mean the difference between a stable and a declining population, and salt pool removal could be part of a good mitigation plan to halt population declines. This model can be used, with improvements such as

  5. An upper-bound assessment of the benefits of reducing perchlorate in drinking water.

    Science.gov (United States)

    Lutter, Randall

    2014-10-01

    The Environmental Protection Agency plans to issue new federal regulations to limit drinking water concentrations of perchlorate, which occurs naturally and results from the combustion of rocket fuel. This article presents an upper-bound estimate of the potential benefits of alternative maximum contaminant levels for perchlorate in drinking water. The results suggest that the economic benefits of reducing perchlorate concentrations in drinking water are likely to be low, i.e., under $2.9 million per year nationally, for several reasons. First, the prevalence of detectable perchlorate in public drinking water systems is low. Second, the population especially sensitive to effects of perchlorate, pregnant women who are moderately iodide deficient, represents a minority of all pregnant women. Third, and perhaps most importantly, reducing exposure to perchlorate in drinking water is a relatively ineffective way of increasing iodide uptake, a crucial step linking perchlorate to health effects of concern. © 2014 Society for Risk Analysis.

  6. The effect of sodium hydroxide on drag reduction using banana peel as a drag reduction agent

    Science.gov (United States)

    Kaur, H.; Jaafar, A.

    2018-02-01

    Drag reduction is observed as reduced frictional pressure losses under turbulent flow conditions. Drag reduction agent such as polymers can be introduced to increase the flowrate of water flowing and reduce the water accumulation in the system. Currently used polymers are synthetic polymers, which will harm our environment in excessive use of accumulation. A more environmentally-friendly drag reduction agent such as the polymer derived from natural sources or biopolymer, is then required for such purpose. As opposed to the synthetic polymers, the potential of biopolymers as drag reduction agents, especially those derived from a local plant source are not extensively explored. The drag reduction of a polymer produced from a local plant source within the turbulent regime was explored and assessed in this study using a rheometer, where a reduced a torque produced was perceived as a reduction of drag. This method proposed is less time consuming and is more practical which is producing carboxymethylcellulose from the banana peel. The cellulose powder was converted to carboxymethylcellulose (CMC) by etherification process. The carboxymethylation reaction during the synthesizing process was then optimized against the reaction temperature, reaction time and solubility. The biopolymers were then rheologically characterized, where the viscoelastic effects and the normal stresses produced by these biopolymers were utilized to further relate and explain the drag reduction phenomena. The research was structured to focus on producing the biopolymer and to assess the drag reduction ability of the biopolymer produced. The rheological behavior of the biopolymers was then analyzed based on the ability of reducing drag. The results are intended to expand the currently extremely limited experimental database. Based on the results, the biopolymer works as a good DRA.

  7. Investigating Mechanisms of Alkalinization for Reducing Primary Breast Tumor Invasion

    Directory of Open Access Journals (Sweden)

    Ian F. Robey

    2013-01-01

    Full Text Available The extracellular pH (pHe of many solid tumors is acidic as a result of glycolytic metabolism and poor perfusion. Acidity promotes invasion and enhances metastatic potential. Tumor acidity can be buffered by systemic administration of an alkaline agent such as sodium bicarbonate. Tumor-bearing mice maintained on sodium bicarbonate drinking water exhibit fewer metastases and survive longer than untreated controls. We predict this effect is due to inhibition of tumor invasion. Reducing tumor invasion should result in fewer circulating tumor cells (CTCs. We report that bicarbonate-treated MDA-MB-231 tumor-bearing mice exhibited significantly lower numbers of CTCs than untreated mice (. Tumor pHe buffering may reduce optimal conditions for enzymes involved in tumor invasion such as cathepsins and matrix metalloproteases (MMPs. To address this, we tested the effect of transient alkalinization on cathepsin and MMP activity using enzyme activatable fluorescence agents in mice bearing MDA-MB-231 mammary xenografts. Transient alkalinization significantly reduced the fluorescent signal of protease-specific activatable agents in vivo (. Alkalinization, however, did not affect expression of carbonic anhydrase IX (CAIX. The findings suggest a possible mechanism in a live model system for breast cancer where systemic alkalinization slows the rate of invasion.

  8. Report of the NATO/CCMS drinking water pilot study on health aspects of drinking water contaminants

    Energy Technology Data Exchange (ETDEWEB)

    Borzelleca, J F

    1981-04-01

    Various methods of disinfection are being successfully used to control water borne diseases due to biological contaminants in water (viruses, bacteria, protozoa). These methods of chemical control are adding chemical contaminants to the drinking water. For example, trihalomethanes may be formed by the interaction of chlorine with humic and/or fulvic acids. In addition, chemical contaminants may arise from natural, agricultural, industrial or distributional sources. Acute or chronic exposures to these chemicals may result in adverse health effects that are immediate or delayed, reversible or irreversible. Since these contaminants rarely occur singly, chemical interactions (additives, synergistic, antagonistic) must be considered. The nature of the adverse health effects can usually be determined from properly designed and executed animal experiments and/or human epidemiological studies. Potentially toxic agents may also be identified by the use of short term or in vitro tests. Other methods of identification of potentially toxic agents include chemical similarity with known toxicants. Attempts should be made to reduce the number of potentially toxic chemical contaminants but the microbiological quality of drinking water must not be compromised.

  9. Radioactive scanning agents with hydroquinone stabilizer

    International Nuclear Information System (INIS)

    Whitehouse, H.S.

    1982-01-01

    Stable compositions useful as technetium 99m-based scintigraphic agents comprise hydroquinone in combination with a pertechnetate reducing agent or dissolved in pertechnetate-99m (sup(99m)TcOsub(4)sup(-)) solution. The compositions are especially useful in combination with a phosphate or phosphonate material which carries the radionuclide to bone, thus providing a skeletal imaging agent

  10. Screening and Monitoring Response to Treatment Using Subsecond Molecular Imaging and Hyperpolarized Contrast Agents

    Science.gov (United States)

    2013-05-01

    DCE-MRI analysis typically involves the application of various pharmacokinetic equations to model the movement of contrast agent molecules between...position over a short time interval due to random, thermally-induced motion (ie, Brownian motion). DW-MRI exploits applied gradients of the main...intracel- lular organelles tend to restrict or hinder the free movement of water.47,48 Moreover, cancerous tissues often show sig- nificantly reduced ADC

  11. Application and appreciation of chemical sand fixing agent-poly (aspartic acid) and its composites

    Energy Technology Data Exchange (ETDEWEB)

    Yang Jun; Cao Hui; Wang Fang [Beijing Key Laboratory of Bioprocess, Beijing University of Chemical Technology, Beijing 100029 (China); Tan Tianwei [Beijing Key Laboratory of Bioprocess, Beijing University of Chemical Technology, Beijing 100029 (China)], E-mail: twtan@mail.buct.edu.cn

    2007-12-15

    The sand fixing agent-poly (aspartic acid) (PASP) and its composites were applied in the field by two forms (spraying around by PASP solution and PASP powder directly). It was found that the sand fixing effect in powder form was not as good as in solution form, but it was more practical in dry region. It needed 9, 6 and 7 days for PASP, xanthan gum-PASP (X2) and ethyl cellulose-PASP (E3) to attain the maximal mechanical strength after they were applied, respectively. The sand fixing effect decreased when the material was subjected to repeated hydration-dehydration cycles and the material had no negative influence on plant growth. The PASP and its composites had water-retaining ability and could reduce the water evaporation. - The sand fixing agent was applied in powder form and it had no negative influence on plant growth.

  12. Bio-corrosion of water pipeline by sulphate-reducing bacteria in a ...

    African Journals Online (AJOL)

    esiri

    2013-11-13

    Nov 13, 2013 ... Key words: Sulphate-reducing bacteria, corrosion, water pipeline, biocide. INTRODUCTION ... small amount of organic material required to produce biomass):. )1(. 3. 2 .... Oil, gas and shipping industries are seriously affected.

  13. High protein flexibility and reduced hydration water dynamics are key pressure adaptive strategies in prokaryotes

    KAUST Repository

    Martinez, N.

    2016-09-06

    Water and protein dynamics on a nanometer scale were measured by quasi-elastic neutron scattering in the piezophile archaeon Thermococcus barophilus and the closely related pressure-sensitive Thermococcus kodakarensis, at 0.1 and 40 MPa. We show that cells of the pressure sensitive organism exhibit higher intrinsic stability. Both the hydration water dynamics and the fast protein and lipid dynamics are reduced under pressure. In contrast, the proteome of T. barophilus is more pressure sensitive than that of T. kodakarensis. The diffusion coefficient of hydration water is reduced, while the fast protein and lipid dynamics are slightly enhanced with increasing pressure. These findings show that the coupling between hydration water and cellular constituents might not be simply a master-slave relationship. We propose that the high flexibility of the T. barophilus proteome associated with reduced hydration water may be the keys to the molecular adaptation of the cells to high hydrostatic pressure.

  14. High protein flexibility and reduced hydration water dynamics are key pressure adaptive strategies in prokaryotes

    KAUST Repository

    Martinez, N.; Michoud, Gregoire; Cario, A.; Ollivier, J.; Franzetti, B.; Jebbar, M.; Oger, P.; Peters, J.

    2016-01-01

    Water and protein dynamics on a nanometer scale were measured by quasi-elastic neutron scattering in the piezophile archaeon Thermococcus barophilus and the closely related pressure-sensitive Thermococcus kodakarensis, at 0.1 and 40 MPa. We show that cells of the pressure sensitive organism exhibit higher intrinsic stability. Both the hydration water dynamics and the fast protein and lipid dynamics are reduced under pressure. In contrast, the proteome of T. barophilus is more pressure sensitive than that of T. kodakarensis. The diffusion coefficient of hydration water is reduced, while the fast protein and lipid dynamics are slightly enhanced with increasing pressure. These findings show that the coupling between hydration water and cellular constituents might not be simply a master-slave relationship. We propose that the high flexibility of the T. barophilus proteome associated with reduced hydration water may be the keys to the molecular adaptation of the cells to high hydrostatic pressure.

  15. Preparation of reduced graphene oxide/gelatin composite films with reinforced mechanical strength

    International Nuclear Information System (INIS)

    Wang, Wenchao; Wang, Zhipeng; Liu, Yu; Li, Nan; Wang, Wei; Gao, Jianping

    2012-01-01

    Highlights: ► We used and compared different proportion of gelatin and chitosan as reducing agents. ► The mechanical properties of the films are investigated, especially the wet films. ► The cell toxicity of the composite films as biomaterial is carried out. ► The water absorption capabilities of the composite films also studied. -- Abstract: Graphene oxide (GO) was reduced by chitosan/gelatin solution and added to gelatin (Gel) to fabricate reduced graphene oxide/gelatin (RGO/Gel) films by a solvent-casting method using genipin as cross-linking agent. The structure and properties of the films were characterized by scanning electron microscopy (SEM), X-ray powder diffraction (XRD), thermogravimetric analysis (TGA) and UV–vis spectroscopy. The addition of RGO increased the tensile strength of the RGO/Gel films in both dry and wet states, but decreased their elongation at break. The incorperation of RGO also decreased the swelling ability of the films in water. Cell cultures were carried out in order to test the cytotoxicity of the films. The cells grew and reproduced well on the RGO/Gel films, indicating that the addition of RGO has no negative effect on the compatibility of the gelatin. Therefore, the reduced graphene oxide/gelatin composite is a promising biomaterial with excellent mechanical properties and good cell compatibility.

  16. Comparison of the white-nose syndrome agent Pseudogymnoascus destructans to cave-dwelling relatives suggests reduced saprotrophic enzyme activity.

    Science.gov (United States)

    Reynolds, Hannah T; Barton, Hazel A

    2014-01-01

    White-nose Syndrome (WNS) is an emerging infectious mycosis that has impacted multiple species of North American bats since its initial discovery in 2006, yet the physiology of the causal agent, the psychrophilic fungus Pseudogymnoascus destructans ( = Geomyces destructans), is not well understood. We investigated the ability of P. destructans to secrete enzymes that could permit environmental growth or affect pathogenesis and compared enzyme activity across several Pseudogymnoascus species isolated from both hibernating bats and cave sediments. We found that P. destructans produced enzymes that could be beneficial in either a pathogenic or saprotrophic context, such as lipases, hemolysins, and urease, as well as chitinase and cellulases, which could aid in saprotrophic growth. The WNS pathogen showed significantly lower activity for urease and endoglucanase compared to con-generic species (Pseudogymnoascus), which may indicate a shift in selective pressure to the detriment of P. destructans' saprotrophic ability. Based on the positive function of multiple saprotrophic enzymes, the causal agent of White-nose Syndrome shows potential for environmental growth on a variety of substrates found in caves, albeit at a reduced level compared to environmental strains. Our data suggest that if P. destructans emerged as an opportunistic infection from an environmental source, co-evolution with its host may have led to a reduced capacity for saprotrophic growth.

  17. Comparison of the white-nose syndrome agent Pseudogymnoascus destructans to cave-dwelling relatives suggests reduced saprotrophic enzyme activity.

    Directory of Open Access Journals (Sweden)

    Hannah T Reynolds

    Full Text Available White-nose Syndrome (WNS is an emerging infectious mycosis that has impacted multiple species of North American bats since its initial discovery in 2006, yet the physiology of the causal agent, the psychrophilic fungus Pseudogymnoascus destructans ( = Geomyces destructans, is not well understood. We investigated the ability of P. destructans to secrete enzymes that could permit environmental growth or affect pathogenesis and compared enzyme activity across several Pseudogymnoascus species isolated from both hibernating bats and cave sediments. We found that P. destructans produced enzymes that could be beneficial in either a pathogenic or saprotrophic context, such as lipases, hemolysins, and urease, as well as chitinase and cellulases, which could aid in saprotrophic growth. The WNS pathogen showed significantly lower activity for urease and endoglucanase compared to con-generic species (Pseudogymnoascus, which may indicate a shift in selective pressure to the detriment of P. destructans' saprotrophic ability. Based on the positive function of multiple saprotrophic enzymes, the causal agent of White-nose Syndrome shows potential for environmental growth on a variety of substrates found in caves, albeit at a reduced level compared to environmental strains. Our data suggest that if P. destructans emerged as an opportunistic infection from an environmental source, co-evolution with its host may have led to a reduced capacity for saprotrophic growth.

  18. MASS TRANSFER COEFFICIENTS FOR A NON-NEWTONIAN FLUID AND WATER WITH AND WITHOUT ANTI-FOAM AGENTS

    Energy Technology Data Exchange (ETDEWEB)

    Leishear, R.

    2009-09-09

    Mass transfer rates were measured in a large scale system, which consisted of an 8.4 meter tall by 0.76 meter diameter column containing one of three fluids: water with an anti-foam agent, water without an anti-foam agent, and AZ101 simulant, which simulated a non-Newtonian nuclear waste. The testing contributed to the evaluation of large scale mass transfer of hydrogen in nuclear waste tanks. Due to its radioactivity, the waste was chemically simulated, and due to flammability concerns oxygen was used in lieu of hydrogen. Different liquids were used to better understand the mass transfer processes, where each of the fluids was saturated with oxygen, and the oxygen was then removed from solution as air bubbled up, or sparged, through the solution from the bottom of the column. Air sparging was supplied by a single tube which was co-axial to the column, the decrease in oxygen concentration was recorded, and oxygen measurements were then used to determine the mass transfer coefficients to describe the rate of oxygen transfer from solution. Superficial, average, sparging velocities of 2, 5, and 10 mm/second were applied to each of the liquids at three different column fill levels, and mass transfer coefficient test results are presented here for combinations of superficial velocities and fluid levels.

  19. MASS TRANSFER COEFFICIENTS FOR A NON-NEWTONIAN FLUID AND WATER WITH AND WITHOUT ANTI-FOAM AGENTS

    International Nuclear Information System (INIS)

    Leishear, R.

    2009-01-01

    Mass transfer rates were measured in a large scale system, which consisted of an 8.4 meter tall by 0.76 meter diameter column containing one of three fluids: water with an anti-foam agent, water without an anti-foam agent, and AZ101 simulant, which simulated a non-Newtonian nuclear waste. The testing contributed to the evaluation of large scale mass transfer of hydrogen in nuclear waste tanks. Due to its radioactivity, the waste was chemically simulated, and due to flammability concerns oxygen was used in lieu of hydrogen. Different liquids were used to better understand the mass transfer processes, where each of the fluids was saturated with oxygen, and the oxygen was then removed from solution as air bubbled up, or sparged, through the solution from the bottom of the column. Air sparging was supplied by a single tube which was co-axial to the column, the decrease in oxygen concentration was recorded, and oxygen measurements were then used to determine the mass transfer coefficients to describe the rate of oxygen transfer from solution. Superficial, average, sparging velocities of 2, 5, and 10 mm/second were applied to each of the liquids at three different column fill levels, and mass transfer coefficient test results are presented here for combinations of superficial velocities and fluid levels

  20. Determination and validation of six sunscreen agents in suncare products by UPLC and HPLC.

    Science.gov (United States)

    Lee, So-Mi; Jeong, Hye-Jin; Chang, Ih Seop

    2008-01-01

    Methylene bis-benzotriazolyl tetramethyl butylphenol and bis-ethylhexyloxy phenol methoxyphenyl triazine are sunscreen agents that have hydrophobic behaviors in common. They were not normally assayed with the following four sunscreen agents that have hydrophilic behaviors in a single chromatographic run: ethylhexyl methoxycinnamate, isoamyl p-methoxycinnamate, ethylhexyl salicylate, and ethylhexyl triazone. For that reason, methylene bis-benzotriazolyl tetramethyl butylphenol and bis-ethylhexyloxy phenol methoxyphenyl triazine require much time in order to assay products with those materials. A rapid, selective, and reproducible determination method needs to be developed for the simultaneous examination of methylene bis-benzotriazolyl tetramethyl butylphenol and bis-ethylhexyloxy phenol methoxyphenyl triazine with the sunscreen agents, ethylhexyl methoxycinnamate, isoamyl p-methoxycinnamate, ethylhexyl salicylate, and ethylhexyl triazone. This new technique could reduce time in examining the sunscreen agents and be effective for quality control of suncare products. In this paper, the HPLC and UPLC system is used for developing the determination of the sunscreen agents. Several evaluations of some mixtures of eluents and columns were obtained for the optimal condition of separation. In HPLC, the optimal peak resolution was obtained through ethanol-water gradient elution and a 75-mm C18 column with a 3.5-microm-sized particle on a flow rate of 1.0 ml/min. In UPLC, the most distinctive peak resolution was obtained through methanol-water gradient elution and a 50-mm C18 column with a 1.7-microm-sized particle on a flow rate 0.4 ml/min. Both of those chromatographic determination methods could be used in the examination of six types of sunscreen agents without any interference from other product excipients in the agents. The proposed determination methods were validated for specificity, linearity, repeatability, system stability, intermediate precision, and accuracy

  1. In-situ leaching of crownpoint, NM, uranium ore: Part 7 - Laboratory study of chemical agents for molybdenum restoration

    International Nuclear Information System (INIS)

    Strom, E.T.; Vogt, T.C.

    1987-01-01

    One possible drawback to the use of an in-situ leaching to recover uranium is the potential release of previously insoluble chemical species into the formation water. Before a pilot test of in-situ uranium leaching at Crownpoint, NM, was begun, extensive laboratory studies were undertaken to develop chemical methods for treating one possible contaminant, molybdenum (Mo). New Mexico regulations restrict the amount of Mo permissable in formation waters after leaching to less than 1 ppm. Two techniques to restore Mo after leaching were studied with core and pack tests. These studies suggest that if Mo restoration problems occur in the field, the use of precipitating agents such as Ca/sup 2+/ or reducing agents such as Fe/sup 2+/ may be helpful in ameliorating such problems

  2. Chronic water stress reduces tree growth and the carbon sink of deciduous hardwood forests.

    Science.gov (United States)

    Brzostek, Edward R; Dragoni, Danilo; Schmid, Hans Peter; Rahman, Abdullah F; Sims, Daniel; Wayson, Craig A; Johnson, Daniel J; Phillips, Richard P

    2014-08-01

    Predicted decreases in water availability across the temperate forest biome have the potential to offset gains in carbon (C) uptake from phenology trends, rising atmospheric CO2 , and nitrogen deposition. While it is well established that severe droughts reduce the C sink of forests by inducing tree mortality, the impacts of mild but chronic water stress on forest phenology and physiology are largely unknown. We quantified the C consequences of chronic water stress using a 13-year record of tree growth (n = 200 trees), soil moisture, and ecosystem C balance at the Morgan-Monroe State Forest (MMSF) in Indiana, and a regional 11-year record of tree growth (n > 300 000 trees) and water availability for the 20 most dominant deciduous broadleaf tree species across the eastern and midwestern USA. We show that despite ~26 more days of C assimilation by trees at the MMSF, increasing water stress decreased the number of days of wood production by ~42 days over the same period, reducing the annual accrual of C in woody biomass by 41%. Across the deciduous forest region, water stress induced similar declines in tree growth, particularly for water-demanding 'mesophytic' tree species. Given the current replacement of water-stress adapted 'xerophytic' tree species by mesophytic tree species, we estimate that chronic water stress has the potential to decrease the C sink of deciduous forests by up to 17% (0.04 Pg C yr(-1) ) in the coming decades. This reduction in the C sink due to mesophication and chronic water stress is equivalent to an additional 1-3 days of global C emissions from fossil fuel burning each year. Collectively, our results indicate that regional declines in water availability may offset the growth-enhancing effects of other global changes and reduce the extent to which forests ameliorate climate warming. © 2014 John Wiley & Sons Ltd.

  3. Effect of water hyacinth on distribution of sulphate-reducing bacteria ...

    African Journals Online (AJOL)

    The effect of the water hyacinth, Eichhornia crassipes (Mart.) Solms-Laub, on the distribution of populations of sulphate-reducing bacteria (SRB) in sediments from various stations on the shores of Lake Victoria around Mwanza Municipality, Tanzania, was studied. Lactate-utilising SRB were observed to be the dominant ...

  4. Cooking rice in excess water reduces both arsenic and enriched vitamins in the cooked grain.

    Science.gov (United States)

    Gray, Patrick J; Conklin, Sean D; Todorov, Todor I; Kasko, Sasha M

    2016-01-01

    This paper reports the effects of rinsing rice and cooking it in variable amounts of water on total arsenic, inorganic arsenic, iron, cadmium, manganese, folate, thiamin and niacin in the cooked grain. We prepared multiple rice varietals both rinsed and unrinsed and with varying amounts of cooking water. Rinsing rice before cooking has a minimal effect on the arsenic (As) content of the cooked grain, but washes enriched iron, folate, thiamin and niacin from polished and parboiled rice. Cooking rice in excess water efficiently reduces the amount of As in the cooked grain. Excess water cooking reduces average inorganic As by 40% from long grain polished, 60% from parboiled and 50% from brown rice. Iron, folate, niacin and thiamin are reduced by 50-70% for enriched polished and parboiled rice, but significantly less so for brown rice, which is not enriched.

  5. Effectiveness testing of spill-treating agents

    International Nuclear Information System (INIS)

    Fingas, M.F.; Stoodley, R.; Laroche, N.

    1990-01-01

    Laboratory effectiveness tests are described for four classes of spill-treating agents: solidifiers, demulsifying agents, surface-washing agents and dispersants. Many treating agents in these four categories have been tested for effectiveness and the results are presented. Solidifiers or gelling agents solidify oil, requiring a large amount of agent to solidify oil-ranging between 16% by weight, to over 200%. Emulsion breakers prevent or reverse the formation of water-in-oil emulsions. A newly-developed effectiveness test shows that only one product is highly effective; however, many products will work, but require large amounts of spill-treating agent. Surfactant--containing materials are of two types, surface-washing agents and dispersants. Testing has shown that an agent that is a good dispersant is conversely a poor surface-washing agent, and vice versa. Tests of surface-washing agents show that only a few agents have effectiveness of 25-40%, where this effectiveness is the percentage of heavy oil removed from a test surface. Results using the 'swirling flask' test for dispersant effectiveness are reported. Heavy oils show effectiveness values of about 1%, medium crudes of about 10%, light crude oils of about 30% and very light oils of about 90%. (author)

  6. Numerical study of water entry supercavitating flow around a vertical circular cylinder influenced by turbulent drag-reducing additives

    International Nuclear Information System (INIS)

    Jiang, C X; Cheng, J P; Li, F C

    2015-01-01

    This paper attempts to introduce a numerical simulation procedure to simulate water-entry problems influenced by turbulent drag-reducing additives in a viscous incompressible medium. Firstly we performed a numerical investigation on water-entry supercavities in water and turbulent drag-reducing solution at the impact velocity of 28.4 m/s to confirm the accuracy of the numerical method. Based on the verification, projectile entering water and turbulent drag-reducing solution at relatively high velocity of 142.7 m/s (phase transition is considered) is simulated. The cross viscosity equation was adopted to represent the shear-thinning characteristic of aqueous solution of drag-reducing additives. The configuration and dynamic characteristics of water entry supercavity, flow resistance were discussed respectively. It was obtained that the numerical simulation results are in consistence with experimental data. Numerical results show that the supercavity length in drag-reducing solution is larger than one in water and the velocity attenuates faster at high velocity than at low velocity; the influence of drag-reducing solution is more obvious at high impact velocity. Turbulent drag-reducing additives have the great potential for enhancement of supercavity

  7. Comparison of Binding Affinities of Water-Soluble Calixarenes with the Organophosphorus Nerve Agent Soman (GD and Commonly-Used Nerve Agent Simulants

    Directory of Open Access Journals (Sweden)

    Jayne A. Ede

    2018-01-01

    Full Text Available The formation of inclusion complexes of the water-soluble p-sulfonatocalix[n]arenes, where n = 4 or 6, with the Chemical Warfare Agent (CWA GD, or Soman, and commonly used dialkyl methylphosphonate simulants has been studied by experimental solution NMR methods and by Molecular Mechanics (MMFF and semi-empirical (PM6 calculations. Complex formation in non-buffered and buffered solutions is driven by the hydrophobic effect, and complex stoichiometry determined as 1:1 for all host:guest pairs. Low affinity complexes (Kassoc < 100 M−1 are observed for all guests, attributed to poor host–guest complementarity and the role of buffer cation species accounts for the low affinity of the complexes. Comparison of CWA and simulant behavior adds to understanding of CWA–simulant correlations and the challenges of simulant selection.

  8. Achieving reduced fouling of cooling water exchangers with stainless steel tubes

    International Nuclear Information System (INIS)

    Iftikhar, A.; Mir, N.

    2010-01-01

    Good performance of cooling water heat exchangers plays a vital role in the over all energy efficiency of a chemical plant. Heavy fouling on carbon steel tubes of the cooling water exchangers was causing poor performance and frequent cleaning requirement. The carbon steel tubes were replaced with stainless steel tubes. Improved performance was achieved and cleaning frequency reduced. The paper covers the details of study and methodology applied for the above changes along with summary of results. (author)

  9. The effect of increasing water temperatures on Schistosoma mansoni transmission and Biomphalaria pfeifferi population dynamics: an agent-based modelling study.

    Directory of Open Access Journals (Sweden)

    Nicky McCreesh

    Full Text Available There is increasing interest in the control and elimination of schistosomiasis. Little is known, however, about the likely effects of increasing water-body temperatures on transmission.We have developed an agent-based model of the temperature-sensitive stages of the Schistosoma and intermediate host snail life-cycles, parameterised using data from S. mansoni and Biomphalaria pfeifferi laboratory and field-based observations. Infection risk is calculated as the number of cercariae in the model, adjusted for their probability of causing infection.The number of snails in the model is approximately constant between 15-31°C. Outside this range, snail numbers drop sharply, and the snail population cannot survive outside the range 14-32°C. Mean snail generation time decreases with increasing temperature from 176 days at 14°C to 46 days at 26°C. Human infection risk is highest between 16-18°C and 1pm and 6-10pm in calm water, and 20-25°C and 12-4pm in flowing water. Infection risk increases sharply when temperatures increase above the minimum necessary for sustained transmission.The model suggests that, in areas where S. mansoni is already endemic, warming of the water at transmission sites will have differential effects on both snails and parasites depending on abiotic properties of the water-body. Snail generation times will decrease in most areas, meaning that snail populations will recover faster from natural population reductions and from snail-control efforts. We suggest a link between the ecological properties of transmission sites and infection risk which could significantly affect the outcomes of interventions designed to alter water contact behaviour--proposing that such interventions are more likely to reduce infection levels at river locations than lakes, where infection risk remains high for longer. In cooler areas where snails are currently found, increasing temperatures may significantly increase infection risk, potentially leading

  10. Advanced technology heavy water monitors offering reduced implementation costs

    International Nuclear Information System (INIS)

    Kalechstein, W.; Hippola, K.B.

    1984-10-01

    The development of second generation heavy water monitors for use at CANDU power stations and heavy water plants has been completed and the instruments brought to the stage of commercial availability. Applications of advanced technology and reduced utilization of custom manufactured components have together resulted in instruments that are less expensive to produce than the original monitors and do not require costly station services. The design has been tested on two prototypes and fully documented, including the inspection and test procedures required for manufacture to the CSA Z299.3 quality verfication program standard. Production of the new monitors by a commercial vendor (Barringer Research Ltd.) has begun and the first instrument is scheduled for delivery to CRNL's NRU reactor in late 1984

  11. Increased water intake to reduce headache: learning from a critical appraisal.

    Science.gov (United States)

    Price, Amy; Burls, Amanda

    2015-12-01

    Water intake is a cost effective, non-invasive and low-risk intervention to reduce or prevent headache pain. Chronic mild dehydration may trigger headache. Increased water intake could help. A small trial shows modest benefit; however, a larger methodologically sound randomized controlled trial is needed to confirm efficacy. Spigt, M., Weerkamp, N., Troost, J., van Schayck, C. P., & Knottnerus, J. A. (2012). 'A randomized trial on the effects of regular water intake in patients with recurrent headaches.' Family practice, 29(4), 370-5. Doi: 10.1093/fampra/cmr112 CLINICAL SCENARIO: Patients from primary care registered as 'headache', 'tension headache' and/or 'migraine' for more than one year who suffer at least two episodes of moderately intense headache or more than four mildly intense episodes of headache per month with a daily fluid intake of less than 2.5 litres per day. Patient/Problem = Headache > 1 year with 2 moderately intense or 4 mildly intense episodes per month Intervention = 1.5 litres water per day + stress control and sleep hygiene Comparison/Control = stress control and sleep hygiene Outcome = Reduce or eliminate headache Methodology = Therapy RCT Table 1: Final Search Terms TRIP Data Base: hits = 517 used filter Extended Primary research 4 found 1 paper applicable 'Water intake '[MeSH Terms] AND 'Headache '[All Fields]' Best match to PICO, (2012) RCT SELECTION CRITERION AND OVERALL RESULTS: 102 headache patients in16 primary care clinics were randomized into control (n = 50) and intervention groups (n = 52) Inclusion criteria = two > episodes of moderately intense headache or five > mildly intense headaches per month and total fluid intake > 2.5 litres per day, Follow-up @ 3 months. 79% intervention and 66% of controls completed RCT. Drinking more water resulted in a statistically significant improvement of 4.5 (confidence interval: 1.3-7.8) points on Migraine-Specific Quality of Life (MSQOL

  12. A critical review of measures to reduce radioactive doses from drinking water and consumption of freshwater foodstuffs

    International Nuclear Information System (INIS)

    Smith, J.T.; Voitsekhovitch, O.V.; Haakanson, L.; Hilton, J.

    2001-01-01

    Following a radioactive fallout event, there are a number of possible intervention measures to reduce radioactive doses to the public via the surface water pathway. We have critically reviewed the options available to decision-makers in the event of radioactive contamination of surface waters. We believe that the most effective and viable measures to reduce radioactivity in drinking water are those which operate at the water treatment and distribution stage. Intervention measures to reduce concentrations of radioactivity in rivers and reservoirs are expected to be much less viable and efficient at reducing doses via the drinking water pathway. Bans on consumption of freshwater fish can be effective, but there are few viable measures to reduce radioactivity in fish prior to the preparation stage. Lake liming and biomanipulation have been found to be ineffective for radiocaesium, although the addition of potassium to lakewaters appears promising in some situations. Lake liming may be effective in reducing radiostrontium in fish, though this has not, to our knowledge, been tested. De-boning fish contaminated by strontium is probably the most effective food preparation measure, but salting and freezing can also reduce radiocaesium concentrations in fish. The provision of accurate information to the public is highlighted as a key element of countermeasure implementation

  13. Interspecific variation in physiological and foliar metabolic responses to reduced soil water availability

    Science.gov (United States)

    Climatic uncertainty, particularly in regard to water resources, may alter irrigation management of rice, an essential cereal grain acknowledged as the primary food source for more than half the world’s population. To reduce water use, an alternate wetting and drying (AWD) system has been developed...

  14. Evaluating the Performance of a Surface Barrier on Reducing Soil-Water Flow

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Z. F.; Strickland, Christopher E.; Field, Jim G.; Parker, Danny L.; Clayton, Ray E.

    2012-08-31

    One of the most common effective techniques for contaminant remediation in the vadose zone is to use a surface barrier to reduce or eliminate soil-water flow to reduce the contaminant flux to the underlying groundwater. Confirming the reduction of the soil-water flux rate is challenging because of the difficulty of determining the very low soil-water flux beneath the barrier. We propose a hydraulic-conductivity factor, fK, as a conservative indicator for quantifying the reduction of soil-water flow. The factor can be calculated using the measured soil-water content or pressure but does not require the knowledge of the saturated hydraulic conductivity or the hydraulic gradient. The formulas were tested by comparing with changes in hydraulic conductivity, K, from a drainage experiment. The pressure-based formula was further applied to evaluate the performance of the interim surface barrier at T Tank Farm on Hanford Site. Three years after barrier emplacement, the hydraulic conductivity decreased by a factor between 3.8 and 13.0 at the 1-, 2- and 5-m depths. The difference between the conductivity-reduction factor and the flux-rate-reduction factor, fq, was quantified with a numerical simulation. With the calculated fK, the numerically determined fK/fq ratio, and the assumed pre-barrier soil-water flux rate of 100 mm yr-1, the estimated soil-water flux rate 3 years after barrier emplacement was no more than 8.5 mm yr-1 at or above the 5-m depth.

  15. Innovative Water Management Technology to Reduce Environment Impacts of Produced Water

    Energy Technology Data Exchange (ETDEWEB)

    Castle, James; Rodgers, John; Alley, Bethany; Coffey, Ruthanne; Jurinko, Kristen; Pardue, Michael; Ritter, Tina; Spacil, Michael

    2013-05-15

    -reverse osmosis produced water was designed to promote oxidizing conditions within the first wetland cell for nitrification of ammonia, and the subsequent three cells were designed to promote reducing conditions for denitrification of nitrate. By incorporating multiple wetland cells in a CWTS, the conditions within each cell can be modified for removal of specific COCs. In addition, a CWTS designed with multiple cells allows for convenient sample collection points so that biogeochemical conditions of individual cells can be monitored and performance evaluated. Removal rate coefficients determined from the pilot-scale CWTS experiments and confirmed by the demonstration system can be used to calculate HRTs required to treat COCs in full-scale CWTSs. The calculated HRTs can then be used to determine the surface area or footprint of a full-size CWTS for a given inflow rate of produced water.

  16. Innovative Water Management Technology to Reduce Environmental Impacts of Produced Water

    Energy Technology Data Exchange (ETDEWEB)

    Castle, James; Rodgers, John; Alley, Bethany; Beebe, Alex; Coffey, Ruthanne; Jurinko, Kristen; Pardue, Michael; Ritter, Tina; Spacil, Michael

    2013-05-15

    -reverse osmosis produced water was designed to promote oxidizing conditions within the first wetland cell for nitrification of ammonia, and the subsequent three cells were designed to promote reducing conditions for denitrification of nitrate. By incorporating multiple wetland cells in a CWTS, the conditions within each cell can be modified for removal of specific COCs. In addition, a CWTS designed with multiple cells allows for convenient sample collection points so that biogeochemical conditions of individual cells can be monitored and performance evaluated. Removal rate coefficients determined from the pilot-scale CWTS experiments and confirmed by the demonstration system can be used to calculate HRTs required to treat COCs in full-scale CWTSs. The calculated HRTs can then be used to determine the surface area or ?footprint? of a full-size CWTS for a given inflow rate of produced water.

  17. Innovative Water Management Technology to Reduce Environment Impacts of Produced Water

    Energy Technology Data Exchange (ETDEWEB)

    Castle, James W. [Clemson Univ., SC (United States); Rodgers, John H. [Clemson Univ., SC (United States); Alley, Bethany [Clemson Univ., SC (United States); Beebe, Alex [Clemson Univ., SC (United States); Coffey, Ruthanne [Clemson Univ., SC (United States); Jurinko, Kristen [Clemson Univ., SC (United States); Pardue, Michael [Clemson Univ., SC (United States); Ritter, Tina [Clemson Univ., SC (United States); Spacil, Michael M. [Clemson Univ., SC (United States)

    2013-08-08

    -reverse osmosis produced water was designed to promote oxidizing conditions within the first wetland cell for nitrification of ammonia, and the subsequent three cells were designed to promote reducing conditions for denitrification of nitrate. By incorporating multiple wetland cells in a CWTS, the conditions within each cell can be modified for removal of specific COCs. In addition, a CWTS designed with multiple cells allows for convenient sample collection points so that biogeochemical conditions of individual cells can be monitored and performance evaluated. Removal rate coefficients determined from the pilot-scale CWTS experiments and confirmed by the demonstration system can be used to calculate HRTs required to treat COCs in full-scale CWTSs. The calculated HRTs can then be used to determine the surface area or footprint of a full-size CWTS for a given inflow rate of produced water.

  18. Evaluation of clot formation in blood-contrast agent mixture: experimental study on ionic/nonionic contrast agents and plastic/ glass syringes

    International Nuclear Information System (INIS)

    Shim, Hyung Jin; Lee, Jong Beum; Lee, Yong Chul; Lee, Kwan Seh; Kim, Kun Sang

    1991-01-01

    Recent introduction of low-osmolar nonionic contrast agents has allowed the performance of angiography with certain advantages such as reduced pain, reduced osmotic load and other potential advantages, over high osmolar ionic contrast agents. But the potential thrombogenic risk of nonionic contrast agent has been debate because of their weak anticoagulation effect. Several reports have recently documented the formation of thrombi in catheters and syringes containing nonionic contrast agent, and thromboembolic episodes have been noted during angiographic procedures. We have also been experienced blood clotting within blood mixed contrast agent syringe during angiography. Thus, we have studied with blood mixed ionic (Diatrizoate, Ioglicate) agents and nonionic (Iopamidol, Iopromide) agents, that used usually in our hospital, and saline in plastic and glass syringes. Each syringes were checked the clot formation on 10,30,60,90 minutes. Total 340 samples were obtained from 8 adults before angiography. Our data showed that nonionic contrast agents had significantly lesser anticoagulation effect than ionic contrast agents (ρ < 0.0001) on Chi-square test), both in plastic and glass syringes. And formation of clotting in glass syringes were significantly greater than that in plastic syringes (ρ < 0.0001). Thus meticulous technique is required to prevent thrombosis during angiographic procedure using nonionic contrast agents

  19. The interaction of MRI contrast agents with phospholipids

    International Nuclear Information System (INIS)

    Jendrasiak, Gordon L.; Smith, Ralph L.; Ribeiro, Anthony A.

    2000-01-01

    The molecular interactions of three clinically used MRI contrast agents with lipid vesicles, consisting of egg phosphatidylcholine (EPC), have been studied using high-field NMR techniques. At a molar ratio of one contrast agent molecule to five phospholipid molecules, a significant increase in the proton resonance line width occurred for certain lipid head group moieties. A large decrease in the T 1 relaxation times for the head group moieties was also observed. These two effects occurred regardless of the ionic status and the chelate structure of the three contrast agents. The structure of the contrast agents did, however, affect the magnitude of the two NMR parameter changes. These NMR effects also differed in magnitude amongst the various head group entities. The NMR effects were greatest for the head group moieties at or near the vesicle-water interface. The results are discussed in terms of the structure of the phospholipid-water interface. Since the use of contrast agents has become routine in clinical MRI, our results are of importance in terms of the interaction of the agents with physiological surfaces, many of which contain phospholipids. The understanding of such interactions should be of value not only for improved diagnostics, but also in the development of new contrast agents. (author)

  20. Methods and means for reducing pressure in systems for fire fighting and water spraying in mines

    Energy Technology Data Exchange (ETDEWEB)

    Kozlyuk, A I; Grin' , G V; Yushchenko, Yu N

    1986-01-01

    Valves are evaluated used in water systems for fire fighting and dust suppression in underground black coal mines in the USSR. Specifications of the KR-2, the KR-3 and the R-86 pressure-reducing valves used in deep mines are analyzed. The valves are characterized by low reliability, low capacity and low pressure reducing range. Therefore groups (parallel arrangement) of pressure-reducing valves are used. Using valve groups increases equipment cost. The pressure-reducing systems should consist of no more than 2 valves. The VNIIGD Institute developed the RKGD pressure-reducing valve with the following specifications: inlet pressure 6.87 MPa, outlet pressure from 0.98 to 2.45 MPa, water discharge 100 m/sup 3//h). The RKGD valves are characterized by high reliability but extremely high weight. Therefore, the VNIIGD Institute developed a modified version of pressure-reducing valve, called the PRK (with maximum inlet pressure of 5 MPa, outlet pressure ranging from 0.5 to 1.5 MPa, water discharge 80 m/sup 3//h and weighing 5 kg). Design of the PRK pressure-reducing valve is shown.

  1. Research on removing reservoir core water sensitivity using the method of ultrasound-chemical agent for enhanced oil recovery.

    Science.gov (United States)

    Wang, Zhenjun; Huang, Jiehao

    2018-04-01

    The phenomenon of water sensitivity often occurs in the oil reservoir core during the process of crude oil production, which seriously affects the efficiency of oil extraction. In recent years, near-well ultrasonic processing technology attaches more attention due to its safety and energy efficient. In this paper, the comparison of removing core water sensitivity by ultrasonic wave, chemical injection and ultrasound-chemical combination technique are investigated through experiments. Results show that: lower ultrasonic frequency and higher power can improve the efficiency of core water sensitivity removal; the effects of removing core water sensitivity under ultrasonic treatment get better with increase of core initial permeability; the effect of removing core water sensitivity using ultrasonic treatment won't get better over time. Ultrasonic treatment time should be controlled in a reasonable range; the effect of removing core water sensitivity using chemical agent alone is slightly better than that using ultrasonic treatment, however, chemical injection could be replaced by ultrasonic treatment for removing core water sensitivity from the viewpoint of oil reservoir protection and the sustainable development of oil field; ultrasound-chemical combination technique has the best effect for water sensitivity removal than using ultrasonic treatment or chemical injection alone. Copyright © 2017 Elsevier B.V. All rights reserved.

  2. Rapid synthesis of gold and silver nanoparticles using tryptone as a reducing and capping agent

    Science.gov (United States)

    Mehta, Sourabh M.; Sequeira, Marilyn P.; Muthurajana, Harries; D'Souza, Jacinta S.

    2018-02-01

    Due to its eco-friendliness, recent times have seen an immense interest in the green synthesis of metallic nanoparticles. We present here, a protocol for the rapid and cheap synthesis of Au and Ag nanoparticles (NPs) using 1 mg/ml tryptone (trypsinized casein) as a reducing and capping agent. These nanoparticles are spherical, 10 nm in diameter and relatively monodispersed. The atoms of these NPs are arranged in face-centered cubic fashion. Further, when tested for their cytotoxic property against HeLa and VERO cell lines, gold nanoparticles were more lethal than silver nanoparticles, with a more or less similar trend observed against both Gram-positive and Gram-negative bacteria. On the other hand, the NPs were least cytotoxic against a unicellular alga, Chlamydomonas reinhardtii implying their eco-friendly property.

  3. Shape control of the magnetic iron oxide nanoparticles under different chain length of reducing agents

    International Nuclear Information System (INIS)

    Ngoi, Kuan Hoon; Chia, Chin-Hua; Zakaria, Sarani; Chiu, Wee Siong

    2015-01-01

    We report on the effect of using reducing agents with different chain-length on the synthesis of iron oxide nanoparticles by thermal decomposition of iron (III) acetylacetonate in 1-octadecene. This modification allows us to control the shape of nanoparticles into spherical and cubic iron oxide nanoparticles. The highly monodisperse 14 nm spherical nanoparticles are obtained under 1,2-dodecanediol and average 14 nm edge-length cubic iron oxide nanoparticles are obtained under 1,2-tetradecanediol. The structural characterization such as transmission electron microscope (TEM) and X-ray diffraction (XRD) shows similar properties between two particles with different shapes. The vibrating sample magnetometer (VSM) shows no significant difference between spherical and cubic nanoparticles, which are 36 emu/g and 37 emu/g respectively and superparamagnetic in nature

  4. Shape control of the magnetic iron oxide nanoparticles under different chain length of reducing agents

    Energy Technology Data Exchange (ETDEWEB)

    Ngoi, Kuan Hoon; Chia, Chin-Hua, E-mail: chia@ukm.edu.my; Zakaria, Sarani [School of Applied Physics, Faculty Science and Technology, University Kebangsaan Malaysia 43600 UKM Bangi, Selangor (Malaysia); Chiu, Wee Siong [Low Dimensional Materials Research Centre, Department of Physics, Faculty of Science, University of Malaya, 50603 Lembah Pantai, Kuala Lumpur (Malaysia)

    2015-09-25

    We report on the effect of using reducing agents with different chain-length on the synthesis of iron oxide nanoparticles by thermal decomposition of iron (III) acetylacetonate in 1-octadecene. This modification allows us to control the shape of nanoparticles into spherical and cubic iron oxide nanoparticles. The highly monodisperse 14 nm spherical nanoparticles are obtained under 1,2-dodecanediol and average 14 nm edge-length cubic iron oxide nanoparticles are obtained under 1,2-tetradecanediol. The structural characterization such as transmission electron microscope (TEM) and X-ray diffraction (XRD) shows similar properties between two particles with different shapes. The vibrating sample magnetometer (VSM) shows no significant difference between spherical and cubic nanoparticles, which are 36 emu/g and 37 emu/g respectively and superparamagnetic in nature.

  5. QSPR modeling of octanol/water partition coefficient of antineoplastic agents by balance of correlations.

    Science.gov (United States)

    Toropov, Andrey A; Toropova, Alla P; Raska, Ivan; Benfenati, Emilio

    2010-04-01

    Three different splits into the subtraining set (n = 22), the set of calibration (n = 21), and the test set (n = 12) of 55 antineoplastic agents have been examined. By the correlation balance of SMILES-based optimal descriptors quite satisfactory models for the octanol/water partition coefficient have been obtained on all three splits. The correlation balance is the optimization of a one-variable model with a target function that provides both the maximal values of the correlation coefficient for the subtraining and calibration set and the minimum of the difference between the above-mentioned correlation coefficients. Thus, the calibration set is a preliminary test set. Copyright (c) 2009 Elsevier Masson SAS. All rights reserved.

  6. Process for encapsulating active agents in gels

    NARCIS (Netherlands)

    Yilmaz, G.; Jongboom, R.O.J.; Oosterhaven, J.

    2001-01-01

    The present invention relates to a process for encapsulating an active agent in a biopolymer in the form of a gel, comprising the steps of: a) forming a dispersion or solution of the biopolymer in water; and b) adding the active agent to the dispersion or solution obtained in step a); wherein the

  7. Overview of shoreline cleaning agents

    International Nuclear Information System (INIS)

    Clayton, J.

    1992-01-01

    Chemical cleaning agents may be used to promote release of stranded oil from shorelines for reasons including biological sensitivity of indigenous fauna and flora to the oil, amenity considerations of the shoreline, or concern about refloating of the oil and subsequent stranding on adjacent shorelines. While use of chemical cleaning agents may be appropriate under proper toxic responses in circumstances, certain limitations should be recognized. The potential for toxic responses in indigenous fauna and flora to the cleaning agents must be considered. Enhanced penetration of oil into permeable shorelines following treatment with chemical cleaning agents also is not desirable. However, if conditions related to toxicity and substrate permeability are determined to be acceptable, the use of chemical cleaning agents for treatment of stranded oil can be considered. Chemical agents for cleaning oiled shorelines can be grouped into three categories: (1) non-surfactant-based solvents, (2) chemical dispersants, and (3) formulations especially designed to release stranded oil from shoreline substrates (i.e., shoreline-cleaning-agents). Depending on the specific circumstances present on an oiled shoreline, it is generally desirable that chemical agents used for cleaning will release oil from shoreline substrate(s) to surface waters. Recovery of the oil can then be accomplished by mechanical procedures such as booming and skimming operations

  8. Synthesis of Pt/rGO catalysts with two different reducing agents and their methanol electrooxidation activity

    Energy Technology Data Exchange (ETDEWEB)

    Vu, Thu Ha Thi, E-mail: ptntd2004@yahoo.fr [Key Laboratory for Petrochemical and Refinery Technologies, 2 Pham Ngu Lao street, Hanoi (Viet Nam); Tran, Thanh Thuy Thi, E-mail: tranthithanhthuygl@gmail.com [Key Laboratory for Petrochemical and Refinery Technologies, 2 Pham Ngu Lao street, Hanoi (Viet Nam); Le, Hong Ngan Thi; Tran, Lien Thi; Nguyen, Phuong Hoa Thi; Nguyen, Minh Dang [Key Laboratory for Petrochemical and Refinery Technologies, 2 Pham Ngu Lao street, Hanoi (Viet Nam); Quynh, Bui Ngoc [Institut de recherches sur la catalyse et l’environnement de Lyon, UMR5256, 2 avenue Albert Einstein, 69626 Villeurbanne cedex (France)

    2016-01-15

    Highlights: • Pt/rGO catalysts were successfully synthesized using either NaBH{sub 4} or ethylene glycol. • Synthesis using NaBH{sub 4} could improve electrocatalytic towards methanol oxidation of Pt/rGO catalyst. • 40%Pt/rGO synthesized using NaBH{sub 4} showed the best electrocatalytic performance. - Abstract: The synthesis processes of Platinum (Pt) on reduced graphene oxide (rGO) catalysts from graphene oxide (GO) using two reducing agents including sodium borohydride and ethylene glycol is reported. Structure and morphology of Pt/rGO catalysts are characterized by X-ray powder diffraction, transmission electron microscopy, Raman spectroscopy, and X-ray photoelectron spectroscopy. Electrocatalytic methanol oxidation properties of these catalysts are evaluated by cyclic voltammetry and chronoamperometry. The results show that catalyst synthesized using sodium borohydride has a higher metallic Pt content and an improved catalytic performance in comparison to catalyst synthesized using ethylene glycol. Moreover, effect of Pt loading amount on electrocatalytic methanol oxidation performance of catalysts synthesized using sodium borohydride is systematically investigated. The optimal Pt loading amount on graphene is determined to be 40%.

  9. Biological control reduces growth, and alters water relations of the saltcedar tree (Tamarix spp.) in western Nevada, USA

    Science.gov (United States)

    R.R. Pattison; C.M. D' Antonio; T.L. Dudley

    2011-01-01

    We monitored the impacts of a biological control agent, the saltcedar leaf beetle (Diorhabda carinulata), on the saltcedar tree (Tamarix spp.) at two sites (Humboldt and Walker rivers) in Nevada, USA. At the Humboldt site trees that had experienced three to four defoliation events had more negative water potentials and lower...

  10. One-pot high-yield synthesis of single-crystalline gold nanorods using glycerol as a low-cost and eco-friendly reducing agent

    Energy Technology Data Exchange (ETDEWEB)

    Parveen, Rashida [University of São Paulo, Institute of Chemistry of São Carlos (Brazil); Gomes, Janaina F. [Universidade Federal de São Carlos, Departamento de Engenharia Química (Brazil); Ullah, Sajjad [University of São Paulo, Institute of Chemistry of São Carlos (Brazil); Acuña, José J. S. [Universidade Federal do ABC, Centro de Ciências Naturais e Humanas (Brazil); Tremiliosi-Filho, Germano, E-mail: germano@iqsc.usp.br [University of São Paulo, Institute of Chemistry of São Carlos (Brazil)

    2015-10-15

    The formation of gold nanorods (AuNRs) has recently attracted great attention due to their shape-dependent optical properties that are important for many applications. The development of simpler and safer methods for the high-yield synthesis of AuNRs employing low-cost and easily handled reagents is thus of great importance. Here, we introduce, for the first time, a one-pot seedless method for the preparation of single-crystalline AuNRs in almost 100 % yield based on the use of glycerol in alkaline medium as an eco-friendly, low-cost and pH-tunable reducing agent. The synthesized AuNRs were characterized by UV–Vis–NIR spectroscopy, FEG–SEM and HRTEM. The effect of the presence of capping agent (CTAB) and the concentration of reactants (glycerol, NaOH and AgNO{sub 3}) on the yield and aspect ratio (AR) of AuNRs is discussed. The AR and yield of AuNRs showed a clear dependence on the pH and temperature of the reaction mixture as well as on the concentration of AgNO{sub 3} added as an auxiliary reagent. The longitudinal plasmon resonance band of the resulting AuNRs can be tuned between 620 and 1200 nm by varying the reaction conditions. AuNRs with an aspect ratio (AR) of around 4 were obtained in almost 100 % yield at room temperature and under mild reducing environment. The formation of AuNRs is faster at higher pH (>11) and higher temperature (>30 °C), but the AuNR yield is smaller (<70 %). Variation in the pH of the reaction mixture in the range 12–13.5 results in the formation of AuNRs with different ARs and in different yields (27–99 %). Detailed study of the AuNRs crystallography by HRTEM showed that the AuNRs grow in [001] direction and have a perfect single-crystalline fcc structure, free from structural faults or dislocations. The present green method, which introduces glycerol as a tunable reducing agent with a pH-dependent reducing power, can provide a more general strategy for the preparation of a wide range of metallic nanoparticles.

  11. Application of multi-agent simulation to evaluate the influence of reservoir operation strategies on the distribution of water availability in the semi-arid Jaguaribe basin, Brazil

    NARCIS (Netherlands)

    van Oel, P.R.; Krol, Martinus S.; Hoekstra, Arjen Ysbert

    2012-01-01

    Studying the processes responsible for the distribution of water resources in a river basin over space and time is of great importance for spatial planning. In this study a multi-agent simulation approach is applied for exploring the influence of alternative reservoir operation strategies on water

  12. An environment-friendly route to synthesize reduced graphene oxide as a supercapacitor electrode material

    International Nuclear Information System (INIS)

    Zhang Dacheng; Zhang Xiong; Chen Yao; Wang Changhui; Ma Yanwei

    2012-01-01

    A large-scale, environment-friendly method to produce water-soluble reduced graphene oxide by using glutathione as a reducing and stabilization agent has been developed. The results of UV–visible absorption spectroscopy, X-ray photoelectron spectroscopy, atomic force microscopy, and transmission electron microscopy indicate that graphene oxide is reduced to graphene nanosheets which are single-layers and exhibit good dispersion in water. A reaction mechanism is proposed. The electrochemical properties of the graphene nanosheets as electrode materials for supercapacitors are studied by cyclic voltammetry and galvanostatic charge/discharge tests. A maximum specific capacitance of 238 F g −1 in a 1 M H 2 SO 4 electrolyte has been obtained. Meanwhile, the material shows excellent long-term cycle stability along with the retention of 97% for specific capacitance after 1000 cycle tests.

  13. Red tea leaves infusion as a reducing and stabilizing agent in silver nanoparticles synthesis

    Science.gov (United States)

    Pluta, K.; Tryba, A. M.; Malina, D.; Sobczak-Kupiec, A.

    2017-12-01

    Due to the unique properties of silver nanoparticles there is growing interest in their applications. Current trends in nanotechnology are focused on developing a new technique to synthesize nanoparticles using biological methods associated with the use of plant extracts, fungi, bacteria or essential oils. These methods are a promising alternative to conventional approaches which can minimize the use of hazardous substances. The silver nanoparticles synthesis using red tea infusion as a reducing and stabilizing agent and their characteristics have been described. Total antioxidant capacity using DPPH radical and total content of phenolic compounds by Folin-Ciocalteau method were measured in tea infusion. Synthesis of silver nanoparticles was carried out using chemical reduction at various temperatures. Furthermore, the effect of tea infusion volume added to reaction mixture on nanoparticles’ properties was investigated. Finally, nanosilver suspensions were characterized by UV-vis spectrophotometer, dynamic light scattering (DLS) scanning electron microscope (SEM) and transmission electron microscope (TEM). Moreover, phytotoxicity of silver nanoparticles was determined using Phytotestkit microbiotest.

  14. In Vitro Dissolution of Fluconazole and Dipyridamole in Gastrointestinal Simulator (GIS), Predicting in Vivo Dissolution and Drug-Drug Interaction Caused by Acid-Reducing Agents.

    Science.gov (United States)

    Matsui, Kazuki; Tsume, Yasuhiro; Amidon, Gregory E; Amidon, Gordon L

    2015-07-06

    Weakly basic drugs typically exhibit pH-dependent solubility in the physiological pH range, displaying supersaturation or precipitation along the gastrointestinal tract. Additionally, their oral bioavailabilities may be affected by coadministration of acid-reducing agents that elevate gastric pH. The purpose of this study was to assess the feasibility of a multicompartmental in vitro dissolution apparatus, Gastrointestinal Simulator (GIS), in predicting in vivo dissolution of certain oral medications. In vitro dissolution studies of fluconazole, a BCS class I, and dipyridamole, a BCS class II weak bases (class IIb), were performed in the GIS as well as United States Pharmacopeia (USP) apparatus II and compared with the results of clinical drug-drug interaction (DDI) studies. In both USP apparatus II and GIS, fluconazole completely dissolved within 60 min regardless of pH, reflecting no DDI between fluconazole and acid-reducing agents in a clinical study. On the other hand, seven-fold and 15-fold higher concentrations of dipyridamole than saturation solubility were observed in the intestinal compartments in GIS with gastric pH 2.0. Precipitation of dipyridamole was also observed in the GIS, and the percentage of dipyridamole in solution was 45.2 ± 7.0%. In GIS with gastric pH 6.0, mimicking the coadministration of acid-reducing agents, the concentration of dipyridamole was equal to its saturation solubility, and the percentage of drug in solution was 9.3 ± 2.7%. These results are consistent with the clinical DDI study of dipyridamole with famotidine, which significantly reduced the Cmax and area under the curve. An In situ mouse infusion study combined with GIS revealed that high concentration of dipyridamole in the GIS enhanced oral drug absorption, which confirmed the supersaturation of dipyridamole. In conclusion, GIS was shown to be a useful apparatus to predict in vivo dissolution for BCS class IIb drugs.

  15. Use of Moringa oleifera seed extracts to reduce helminth egg numbers and turbidity in irrigation water.

    Science.gov (United States)

    Sengupta, Mita E; Keraita, Bernard; Olsen, Annette; Boateng, Osei K; Thamsborg, Stig M; Pálsdóttir, Guðný R; Dalsgaard, Anders

    2012-07-01

    Water from wastewater-polluted streams and dug-outs is the most commonly used water source for irrigation in urban farming in Ghana, but helminth parasite eggs in the water represent health risks when used for crop production. Conventional water treatment is expensive, requires advanced technology and often breaks down in less developed countries so low cost interventions are needed. Field and laboratory based trials were carried out in order to investigate the effect of the natural coagulant Moringa oleifera (MO) seed extracts in reducing helminh eggs and turbidity in irrigation water, turbid water, wastewater and tap water. In medium to high turbid water MO extracts were effective in reducing the number of helminth eggs by 94-99.5% to 1-2 eggs per litre and the turbidity to 7-11 NTU which is an 85-96% reduction. MO is readily available in many tropical countries and can be used by farmers to treat high turbid water for irrigation, however, additional improvements of water quality, e.g. by sand filtration, is suggested to meet the guideline value of ≤ 1 helminth egg per litre and a turbidity of ≤ 2 NTU as recommended by the World Health Organization and the U.S. Environmental Protection Agency for water intended for irrigation. A positive correlation was established between reduction in turbidity and helminth eggs in irrigation water, turbid water and wastewater treated with MO. This indicates that helminth eggs attach to suspended particles and/or flocs facilitated by MO in the water, and that turbidity and helminth eggs are reduced with the settling flocs. However, more experiments with water samples containing naturally occurring helminth eggs are needed to establish whether turbidity can be used as a proxy for helminth eggs. Copyright © 2012 Elsevier Ltd. All rights reserved.

  16. Reducing nitrogen leaching from fertilizers to surface waters: catchment specific indicators of economic benefits

    DEFF Research Database (Denmark)

    Andersen, Mikael Skou; Levin, Gregor; Odgaard, Mette Vestergaard

    2018-01-01

    We explore with impact pathway methodology the economic benefits of reducing nitrogen leaching to transitional surface waters, as expected for a proportionality test under the EU’s Water Framework Directive article 4. Ten different catchments is analyzed for a policy scenario where downstream dis...

  17. Glyoxylate as a reducing agent for manganese(III) in salen scaffold ...

    Indian Academy of Sciences (India)

    being the monohydrate gem-diol forms) followed by the slow electron transfer ... stress and implicated as possible therapeutic agents .... excess HGl at different pHs (1.8–2.5) were set aside ...... sion (UGC), New Delhi in terms of a Teacher Fel-.

  18. Intelligent Pressure Management to Reduce Leakage in Urban Water Supply Networks, A Case Study of Sarafrazan District, Mashhad

    Directory of Open Access Journals (Sweden)

    Mohammad Soltani Asl

    2009-09-01

    Full Text Available Water losses are inevitable in urban water distribution systems. The two approaches adopted nowadays to combat this problem include management of hydraulic parameters such as pressure and leakage detection in the network. Intellitgent pressure management is a suitable technique for controlling leakage and reducing damages due to high operating pressures in a network. This paper aims to investigate the effects of pressure reduction on leakage. The EPANET 2.10 software is used to simulate the water distribution network in the Sarafrazan District,Mashhad, assuming leakage from network nodes. The results are then used to develop a pressure variation program based on the patterns obtained from the simulation, which is applied to the pressure reducing valve. The results show that pressure management can reduce nightly leakage by up to 35% while maintaining a more uniform pressure distribution. Implementation of the time-dependent pressure pattern by applying programmable pressure reducing valves in a real urban water distribution network is feasible and plays a key role in reducing water losses to leakage.

  19. Agent-Supported Mission Operations Teamwork

    Science.gov (United States)

    Malin, Jane T.

    2003-01-01

    This slide presentation reviews the development of software agents to support of mission operations teamwork. The goals of the work was to make automation by agents easy to use, supervise and direct, manage information and communication to decrease distraction, interruptions, workload and errors, reduce mission impact of off-nominal situations and increase morale and decrease turnover. The accomplishments or the project are: 1. Collaborative agents - mixed initiative and creation of instructions for mediating agent 2. Methods for prototyping, evaluating and evolving socio-technical systems 3. Technology infusion: teamwork tools in mISSIons 4. Demonstrations in simulation testbed An example of the use of agent is given, the use of an agent to monitor a N2 tank leak. An incomplete instruction to the agent is handled with mediating assistants, or Intelligent Briefing and Response Assistant (IBRA). The IBRA Engine also watches data stream for triggers and executes Act-Whenever actions. There is also a Briefing and Response Instruction (BRI) which is easy for a discipline specialist to create through a BRI editor.

  20. Reduced irrigation increases the water use efficiency and productivity of winter wheat-summer maize rotation on the North China Plain.

    Science.gov (United States)

    Wang, Yunqi; Zhang, Yinghua; Zhang, Rui; Li, Jinpeng; Zhang, Meng; Zhou, Shunli; Wang, Zhimin

    2018-03-15

    The groundwater table has fallen sharply over the last 30years on the North China Plain, resulting in a shortage of water for winter wheat irrigation. Reducing irrigation may be an important strategy to maintain agricultural sustainability in the region; however, few studies have evaluated the transition from conventional irrigation management practices to reduced irrigation management practices in the winter wheat-summer maize rotation system. Here, we compare the yield, water consumption, and water use efficiency of winter wheat-summer maize rotation under conventional irrigation and reduced irrigation on the North China Plain from 2012 to 2015. Reducing irrigation decreased the yield but increased the water use efficiency and significantly advanced the harvest date of winter wheat. As a result, the summer maize sowing date advanced significantly, and the flowering date subsequently advanced 2-8days, thus extending the summer maize grain-filling stage. Therefore, the yield and water use efficiency of summer maize were higher under reduced irrigation than conventional irrigation, which compensated for the winter wheat yield loss under reduced irrigation. In addition, under reduced irrigation from 2012 to 2015, the yield and water use efficiency advantage of the winter wheat-summer maize rotation ranged from 0.0 to 9.7% and from 4.1 to 14.7%, respectively, and water consumption and irrigated water decreased by 20-61mm and 150mm, respectively, compared to conventional irrigation. Overall, the reduced irrigation management practice involving no irrigation after sowing winter wheat, and sowing summer maize on June 7 produced the most favorable grain yield with superb water use efficiency in the winter wheat-summer maize rotation. This study indicates that reducing irrigation could be an efficient means to cope with water resource shortages while maintaining crop production sustainability on the North China Plain. Copyright © 2017. Published by Elsevier B.V.

  1. German standard methods for the examination of water, waste water and sludge: Anions (group D), determination of phosphorus compounds (D 11)

    International Nuclear Information System (INIS)

    1982-01-01

    The following method for the determination of phosphorus compounds in water and waste water is proposed. In acid solutions phosphate ions form with molybdate and antimony ions an antimonylphosphorusmolybdate-complex which is reduced to phosphorusmolybdenumblue by ascorbic acid. The intensity of the colour is determined by photometric methods. Polyphosphates and some organic phosphorus compounds are hydrolysed to orthophosphate by cooking in strong acid solutions. Other stable phosphorus compounds are decomposed by strong oxidizing agents (potassiumperoxidisulfate or nitric acid). (VG) [de

  2. Integrated Modeling of the Human-Natural System to Improve Local Water Management and Planning

    Science.gov (United States)

    Gutowski, W. J., Jr.; Dziubanski, D.; Franz, K.; Goodwin, J.; Rehmann, C. R.; Simpkins, W. W.; Tesfastion, L.; Wanamaker, A. D.; Jie, Y.

    2015-12-01

    Communities across the world are experiencing the effects of unsustainable water management practices. Whether the problem is a lack of water, too much water, or water of degraded quality, finding acceptable solutions requires community-level efforts that integrate sound science with local needs and values. Our project develops both a software technology (agent-based hydrological modeling) and a social technology (a participatory approach to model development) that will allow communities to comprehensively address local water challenges. Using agent-based modeling (ABM), we are building a modeling system that includes a semi-distributed hydrologic process model coupled with agent (stakeholder) models. Information from the hydrologic model is conveyed to the agent models, which, along with economic information, determine appropriate agent actions that subsequently affect hydrology within the model. The iterative participatory modeling (IPM) process will assist with the continual development of the agent models. Further, IPM creates a learning environment in which all participants, including researchers, are co-exploring relevant data, possible scenarios and solutions, and viewpoints through continuous interactions. Our initial work focuses on the impact of flood mitigation and conservation efforts on reducing flooding in an urban area. We are applying all research elements above to the Squaw Creek watershed that flows through parts of four counties in central Iowa. The watershed offers many of the typical tensions encountered in Iowa, such as different perspectives on water management between upstream farmers and downstream urban areas, competition for various types of recreational services, and increasing absentee land ownership that may conflict with community values. Ultimately, climate change scenarios will be incorporated into the model to determine long term patterns that may develop within the social or natural system.

  3. Analisis Kuat Tekan Beton Dengan Bahan Tambah Reduced Water Dan Accelerated Admixture

    OpenAIRE

    Rahmat, Rahmat; Hendriyani, Irna; Anwar, Moh. Syaiful

    2016-01-01

    Concrete consist of: cement mortar, coarse aggregate, fine aggregate, water, and addictive materials. The main ingredient in manufacturing of concrete: rock material that called as aggregates. Aggregate has an important role on the quality of the concrete. Various types and trademarks for admixture of concrete that can be used as addictive of the concrete mix with specific purpose. The study aims to determine the effect of the added material of Reduced Water and Accelerated Admixture (Bestmit...

  4. Raspberry Extract as Both a Stabilizer and a Reducing Agent in Environmentally Friendly Process of Receiving Colloidal Silver

    Directory of Open Access Journals (Sweden)

    Jolanta Pulit

    2013-01-01

    Full Text Available An ecofriendly method of nanosilver obtaining has been studied. The process involves the chemical reduction method carried out in aqueous environment. Silver nitrate (V was applied as a silver ions source. Raspberry extract was used as a natural source of both reducing and stabilizing agents. The total amount of phenolic compounds was determined by the Folin-Ciocalteu method. Obtained nanoparticles were analyzed by the dynamic light scattering technique so as to determine the particles size and suspension stability which was characterized by an electrokinetic potential. The results confirmed that the size of some nanoparticles was under 100 nm.

  5. Enhanced monitor system for water protection

    Science.gov (United States)

    Hill, David E [Knoxville, TN; Rodriquez, Jr., Miguel [Oak Ridge, TN; Greenbaum, Elias [Knoxville, TN

    2009-09-22

    An automatic, self-contained device for detecting toxic agents in a water supply includes an analyzer for detecting at least one toxic agent in a water sample, introducing a means for introducing a water sample into the analyzer and discharging the water sample from the analyzer, holding means for holding a water sample for a pre-selected period of time before the water sample is introduced into the analyzer, and an electronics package that analyzes raw data from the analyzer and emits a signal indicating the presence of at least one toxic agent in the water sample.

  6. Strategies to Reduce Water Footprint in Palm Oil Production: A Case of PTP Mitra Ogan, Baturaja, South Sumatra

    Directory of Open Access Journals (Sweden)

    Dara Kospa Herda Sabriyah

    2017-01-01

    Full Text Available The massive expansion of palm oil industry in Indonesia has triggered environmental issues including water-related problems which have become an important concern. Regarding the issues, sustainable practice standard has been set up as a requirement for palm oil to enter global market. Inevitably, water consumption in this sector is very crucial to be analyzed. One of the methods that can be used as a tool for sustainable appropriation of fresh water resources is water footprint analysis. The primary aim of this study was to formulate the strategies to reduce the water footprint in the palm oil production based on the best practice criteria. Both quantitative and qualitative research was conducted to get the value blue water (volume of surface or groundwater evaporated and grey water (dilution volume to dilute pollutants according to agreed water quality standards. The values of water footprint in palm oil production obtained were used to represent the existing water use and were utilized as the basis for formulating strategies in reducing water use in the palm oil milling processes which was compared with the best practice criteria. The result showed that the blue water of CPO was 109.6 m3/ton and the grey water was 537.7 m3/ton, while the blue water of palm kernel was 62,4 m3/ton and grey water was 306,2 m3/ton. The value indicated that there was an inefficient use of water in the production of palm oil. The use of steam accumulator has been proposed to reduce the use of blue water by optimizing the steam supply. Besides, the reuse of water from fat-pit pond for pressing purposes, or recovery of condensate water as dilution water in the press unit which will affect the amount of wastewater discharged can be done as the strategies in reducing both blue and grey water, as well as reuse of cooling water turbines.

  7. Bifunctional polymer hydrogel layers as forward osmosis draw agents for continuous production of fresh water using solar energy.

    Science.gov (United States)

    Razmjou, Amir; Liu, Qi; Simon, George P; Wang, Huanting

    2013-11-19

    The feasibility of bilayer polymer hydrogels as draw agent in forward osmosis process has been investigated. The dual-functionality hydrogels consist of a water-absorptive layer (particles of a copolymer of sodium acrylate and N-isopropylacrylamide) to provide osmotic pressure, and a dewatering layer (particles of N-isopropylacrylamide) to allow the ready release of the water absorbed during the FO drawing process at lower critical solution temperature (32 °C). The use of solar concentrated energy as the source of heat resulted in a significant increase in the dewatering rate as the temperature of dewatering layer increased to its LSCT more rapidly. Dewatering flux rose from 10 to 25 LMH when the solar concentrator increased the input energy from 0.5 to 2 kW/m(2). Thermodynamic analysis was also performed to find out the minimum energy requirement of such a bilayer hydrogel-driven FO process. This study represents a significant step forward toward the commercial implementation of hydrogel-driven FO system for continuous production of fresh water from saline water or wastewaters.

  8. NAD+ and SIRT3 control microtubule dynamics and reduce susceptibility to antimicrotubule agents

    Science.gov (United States)

    Harkcom, William T.; Ghosh, Ananda K.; Sung, Matthew S.; Matov, Alexandre; Brown, Kevin D.; Giannakakou, Paraskevi; Jaffrey, Samie R.

    2014-01-01

    Nicotinamide adenine dinucleotide (NAD+) is an endogenous enzyme cofactor and cosubstrate that has effects on diverse cellular and physiologic processes, including reactive oxygen species generation, mitochondrial function, apoptosis, and axonal degeneration. A major goal is to identify the NAD+-regulated cellular pathways that may mediate these effects. Here we show that the dynamic assembly and disassembly of microtubules is markedly altered by NAD+. Furthermore, we show that the disassembly of microtubule polymers elicited by microtubule depolymerizing agents is blocked by increasing intracellular NAD+ levels. We find that these effects of NAD+ are mediated by the activation of the mitochondrial sirtuin sirtuin-3 (SIRT3). Overexpression of SIRT3 prevents microtubule disassembly and apoptosis elicited by antimicrotubule agents and knockdown of SIRT3 prevents the protective effects of NAD+ on microtubule polymers. Taken together, these data demonstrate that NAD+ and SIRT3 regulate microtubule polymerization and the efficacy of antimicrotubule agents. PMID:24889606

  9. Irrigation with oxygen-nanobubble water can reduce methane emission and arsenic dissolution in a flooded rice paddy

    International Nuclear Information System (INIS)

    Minamikawa, Kazunori; Makino, Tomoyuki; Tago, Kanako; Hayatsu, Masahito; Takahashi, Masayoshi

    2015-01-01

    A remarkable feature of nanobubbles (<10 –6 m in diameter) is their long lifetime in water. Supplying oxygen-nanobubbles (NBs) to continuously flooded paddy soil may retard the development of reductive conditions, thereby reducing the emission of methane (CH 4 ), a potent greenhouse gas, and dissolution of arsenic, an environmental load. We tested this hypothesis by performing a pot experiment and measuring redox-related variables. The NBs were introduced into control water (with properties similar to those of river water) using a commercially available generator. Rice (Oryza sativa L.) growth did not differ between plants irrigated with NB water and those irrigated with control water, but NB water significantly (p < 0.05) reduced cumulative CH 4 emission during the rice-growing season by 21%. The amounts of iron, manganese, and arsenic that leached into the drainage water before full rice heading were also reduced by the NB water. Regardless of the water type, weekly-measured CH 4 flux was linearly correlated with the leached iron concentration during the rice-growing season (r = 0.74, p < 0.001). At the end of the experiment, the NB water significantly lowered the soil pH in the 0–5 cm layer, probably because of the raised redox potential. The population of methanogenic Archaea (mcrA copy number) in the 0–5 cm layer was significantly increased by the NB water, but we found no correlation between the mcrA copy number and the cumulative CH 4 emission (r = –0.08, p = 0.85). In pots without rice plants, soil reduction was not enhanced, regardless of the water type. The results indicate that NB water reduced CH 4 emission and arsenic dissolution through an oxidative shift of the redox conditions in the flooded soil. We propose the use of NB water as a tool for controlling redox conditions in flooded paddy soils. (letter)

  10. Thickened water-based hydraulic fluid with reduced dependence of viscosity on temperature

    Energy Technology Data Exchange (ETDEWEB)

    Deck, C. F.

    1985-01-01

    Improved hydraulic fluids or metalworking lubricants, utilizing mixtures of water, metal lubricants, metal corrosion inhibitors, and an associative polyether thickener, have reduced dependence of the viscosity on temperature achieved by the incorporation therein of an ethoxylated polyether surfactant.

  11. Simple sol-gel synthesis and characterization of new CoTiO3/CoFe2O4 nanocomposite by using liquid glucose, maltose and starch as fuel, capping and reducing agents.

    Science.gov (United States)

    Ansari, Fatemeh; Sobhani, Azam; Salavati-Niasari, Masoud

    2018-03-15

    The sol-gel auto-combustion technique is an effective method for the synthesis of the composites. In this research for the first time, CoTiO 3 /CoFe 2 O 4 nanocomposites are successfully synthesized via a new sol-gel auto-combustion technique. The glucose, maltose and starch are used as fuel, capping and reducing agents, also the optimal reducing agent is chosen. The effects of quantity of reducing agent, molar ratio of Ti:Co, calcination temperature and time on the morphology, particle size, magnetic property, purity and phase of the nanocomposites are investigated. XRD patterns show formation of CoTiO 3 /CoFe 2 O 4 spherical nanoparticles with nearly evenly distribution, when the molar ratio of Co/Ti is 1:1. EDS analysis confirm results of XRD. The magnetic behavior of the nanocomposites is studied by VSM. The nanocomposites exhibit a high coercivity at room temperature. Copyright © 2017 Elsevier Inc. All rights reserved.

  12. Water Chemistry Control in Reducing Corrosion and Radiation Exposure at PWR Reactor

    International Nuclear Information System (INIS)

    Febrianto

    2006-01-01

    Water chemistry control plays an important role in relation to plant availability, reliability and occupational radiation exposures. Radiation exposures of nuclear plant workers are determined by the radiation rate dose and by the amount maintenance and repair work time Water chemistry has always been, from beginning of operation of power Pressurized Water Reactor, an important factor in determining the integrity of reactor components, fuel cladding integrity and minimize out of core radiation exposures. For primary system, the parameters to control the quality of water chemistry have been subject to change in time. Reactor water coolant pH need to be optimally controlled and be operated in range pH 6.9 to 7.4. At pH lower than 6.9, cause increasing the radiation exposure level and increasing coolant water pH higher than 7.4 will decrease radiation exposure level but increasing risk to fuel cladding and steam generator tube. Since beginning 90 decade, PWR water coolant pH tend to be operated at pH 7.4. This paper will discuss concerning water chemistry development in reducing corrosion and radiation exposure dose in PWR reactor. (author)

  13. Measuring SPIO and Gd contrast agent magnetization using 3 T MRI

    Science.gov (United States)

    Cantillon-Murphy, Pádraig; Wald, Lawrence L.; Zahn, Markus; Adalsteinsson, Elfar

    2011-01-01

    Traditional methods of measuring magnetization in magnetic fluid samples, such as vibrating sample magnetometry (VSM), are typically limited to maximum field strengths of about 1 T. This work demonstrates the ability of MRI to measure the magnetization associated with two commercial MRI contrast agents at 3 T by comparing analytical solutions to experimental imaging results for the field pattern associated with agents in cylindrical vials. The results of the VSM and fitted MRI data match closely. The method represents an improvement over VSM measurements since results are attainable at imaging field strengths. The agents investigated are Feridex, a superparamagnetic iron oxide suspension used primarily for liver imaging, and Magnevist, a paramagnetic, gadolinium-based compound used for tumors, inflammation and vascular lesions. MR imaging of the agents took place in sealed cylindrical vials in the presence of a surrounding volume of deionized water where the effects of the contrast agents had a measurable effect on the water's magnetization in the vicinity of the compartment of contrast agent. A pair of phase images were used to reconstruct a B0 fieldmap. The resultant B0 maps in the water region, corrected for shimming and container edge effects, were used to predict the agent's magnetization at 3 T. The results were compared with the results from VSM measurements up to 1.2 T and close correlation was observed. The technique should be of interest to those seeking quantification of the magnetization associated with magnetic suspensions beyond the traditional scope of VSM. The magnetization needs to be sufficiently strong (Ms≳50 Am2/kg Fe for Feridex and χm≳5 × 10−5 m3/kg Gd for Magnevist) for a measurable dipole field in the surrounding water. For this reason, the technique is mostly suitable for undiluted agents. PMID:19588450

  14. A Watershed-Scale Agent-Based Model Incorporating Agent Learning and Interaction of Farmers' Decisions Subject to Carbon and Miscanthus Prices

    Science.gov (United States)

    Ng, T.; Eheart, J.; Cai, X.; Braden, J. B.

    2010-12-01

    Agricultural watersheds are coupled human-natural systems where the land use decisions of human agents (farmers) affect surface water quality, and in turn, are affected by the weather and yields. The reliable modeling of such systems requires an approach that considers both the human and natural aspects. Agent-based modeling (ABM), representing the human aspect, coupled with hydrologic modeling, representing the natural aspect, is one such approach. ABM is a relatively new modeling paradigm that formulates the system from the perspectives of the individual agents, i.e., each agent is modeled as a discrete autonomous entity with distinct goals and actions. The primary objective of this study is to demonstrate the applicability of this approach to agricultural watershed management. This is done using a semi-hypothetical case study of farmers in the Salt Creek watershed in East-Central Illinois under the influence markets for carbon and second-generation bioenergy crop (specifically, miscanthus). An agent-based model of the system is developed and linked to a hydrologic model of the watershed. The former is based on fundamental economic and mathematical programming principles, while the latter is based on the Soil and Water Assessment Tool (SWAT). Carbon and second-generation bioenergy crop markets are of interest here due to climate change and energy independence concerns. The agent-based model is applied to fifty hypothetical heterogeneous farmers. The farmers' decisions depend on their perceptions of future conditions. Those perceptions are updated, according to a pre-defined algorithm, as the farmers make new observations of prices, costs, yields and the weather with time. The perceptions are also updated as the farmers interact with each other as they share new information on initially unfamiliar activities (e.g., carbon trading, miscanthus cultivation). The updating algorithm is set differently for different farmers such that each is unique in his processing of

  15. Application of Titanium Compounds to Reduce Fluoride Ion in Water Resources with High Fluoride Ion Contents

    Directory of Open Access Journals (Sweden)

    Fariborz Riahi

    2005-06-01

    Full Text Available The present work describes studies on the sorption of fluoride ions from water by titanium compounds used in water treatment to reduce fluoride content in water resources. There are different methods of reducing fluoride ion in water, each associated with specific problems such as secondary contamination, environmental contamination, high costs, or the need for primary and secondary treatment. In this study, application of titanium sulfate and Metatitanic acid produced from titanium ore concentrate (ileminite is investigated in the removal of fluoride ion and the possibility of complete purification of fluorine containing wastewater is examined to determine the optimal conditions. Metatitanic acid has a great sorption property for fluoride ion. Also titanium sulfate is a suitable and more effective material for this purpose. Efficiency of this material in reducing fluoride ion content is 99.9% and it is possible to refresh sorbet material for reuse without problems arising from Ti+4 ion contamination.

  16. Improved methods for water shutoff. Final technical progress report, October 1, 1997--September 30, 1998

    Energy Technology Data Exchange (ETDEWEB)

    Seright, R.S.; Liang, J.T.; Schrader, R.; Hagstrom, J. II; Liu, J.; Wavrik, K.

    1998-10-01

    In the United States, more than 20 billion barrels of salt water are produced each year during oilfield operations. A tremendous economic incentive exists to reduce water production if that can be accomplished without significantly sacrificing hydrocarbon production. This three-year research project had three objectives. The first objective was to identify chemical blocking agents that will (a) during placement, flow readily through fractures without penetrating significantly into porous rock and with screening out or developing excessive pressure gradients and (b) at a predictable and controllable time, become immobile and resistant breakdown upon exposure to moderate to high pressure gradients. The second objective was to identify schemes that optimize placement of the above blocking agents. The third objective was to explain why gels and other chemical blocking agents reduce permeability to one phase (e.g., water) more than that to another phase (e.g., oil or gas). The authors also wanted to identify conditions that maximize this phenomenon. This project consisted of three tasks, each of which addressed one of the above objectives. This report describes work performed during the third and final period of the project. During this three-year project, they: (1) Developed a procedure and software for sizing gelant treatments in hydraulically fractured production wells; (2) Developed a method (based on interwell tracer results) to determine the potential for applying gel treatments in naturally fractured reservoirs; (3) Characterized gel properties during extrusion through fractures; (4) Developed a method to predict gel placement in naturally fractured reservoirs; (5) Made progress in elucidating the mechanism for why some gels can reduce permeability to water more than that to oil; (6) Demonstrated the limitations of using water/oil ratio diagnostic plots to distinguish between channeling and coning; and (7) Proposed a philosophy for diagnosing and attacking water

  17. Comparative effectiveness of skin antiseptic agents in reducing surgical site infections: a report from the Washington State Surgical Care and Outcomes Assessment Program.

    Science.gov (United States)

    Hakkarainen, Timo W; Dellinger, E Patchen; Evans, Heather L; Farjah, Farhood; Farrokhi, Ellen; Steele, Scott R; Thirlby, Richard; Flum, David R

    2014-03-01

    Surgical site infections (SSI) are an important source of morbidity and mortality. Chlorhexidine in isopropyl alcohol is effective in preventing central venous-catheter associated infections, but its effectiveness in reducing SSI in clean-contaminated procedures is uncertain. Surgical studies to date have had contradictory results. We aimed to further evaluate the relationship of commonly used antiseptic agents and SSI, and to determine if isopropyl alcohol has a unique effect. We performed a prospective cohort analysis to evaluate the relationship of commonly used skin antiseptic agents and SSI for patients undergoing mostly clean-contaminated surgery from January 2011 through June 2012. Multivariate regression modeling predicted expected rates of SSI. Risk adjusted event rates (RAERs) of SSI were compared across groups using proportionality testing. Among 7,669 patients, the rate of SSI was 4.6%. The RAERs were 0.85 (p = 0.28) for chlorhexidine (CHG), 1.10 (p = 0.06) for chlorhexidine in isopropyl alcohol (CHG+IPA), 0.98 (p = 0.96) for povidone-iodine (PVI), and 0.93 (p = 0.51) for iodine-povacrylex in isopropyl alcohol (IPC+IPA). The RAERs were 0.91 (p = 0.39) for the non-IPA group and 1.10 (p = 0.07) for the IPA group. Among elective colorectal patients, the RAERs were 0.90 (p = 0.48) for CHG, 1.04 (p = 0.67) for CHG+IPA, 1.04 (p = 0.85) for PVI, and 1.00 (p = 0.99) for IPC+IPA. For clean-contaminated surgical cases, this large-scale state cohort study did not demonstrate superiority of any commonly used skin antiseptic agent in reducing the risk of SSI, nor did it find any unique effect of isopropyl alcohol. These results do not support the use of more expensive skin preparation agents. Copyright © 2014 American College of Surgeons. Published by Elsevier Inc. All rights reserved.

  18. The institutional stance in agent-based simulations

    NARCIS (Netherlands)

    Sileno, G.; Boer, A.; van Engers, T.; Filipe, J.; Fred, A.L.N.

    2013-01-01

    This paper presents a multi-agent framework intended to animate scenarios of compliance and non-compliance in a normative system. With the purpose of describing social human behaviour, we choose to reduce social complexity by creating models of the involved agents starting from stories, and

  19. Effect of Gum Arabic karroo as a Water-Reducing Admixture in Concrete.

    Science.gov (United States)

    Mbugua, Rose; Salim, Ramadhan; Ndambuki, Julius

    2016-01-28

    Concrete is one of the most popular construction materials in the world. Chemical admixtures are ingredients added to concrete to enhance its properties. However, most chemical admixtures on the market today are expensive, thereby making them out of reach for small consumers of concrete. In Africa, use of chemical admixtures is rare despite the harsh weather conditions. In the current study, Gum from Acacia karroo (GAK) was used as a water-reducing admixture in concrete. A slump test, density and compressive strength were studied using different dosages of GAK while neat concrete was the control. Results showed that slump increased by 200% at a 2% dosage of GAK. This enabled reduction of water-to-binder (w/b) ratio from 0.61 to 0.48 for samples with a 3% dosage. Reduction in w/b resulted in increased compressive strength of 37.03% above the control after 180 days of curing for a 3% dosage. XRD studies also showed a decreased rate of hydration in the presence of GAK in concrete. It was concluded that GAK can be used in concrete as a water-reducing admixture, which is environmentally-friendly, thus producing sustainable and greener concrete.

  20. Effect of Gum Arabic karroo as a Water-Reducing Admixture in Concrete

    Science.gov (United States)

    Mbugua, Rose; Salim, Ramadhan; Ndambuki, Julius

    2016-01-01

    Concrete is one of the most popular construction materials in the world. Chemical admixtures are ingredients added to concrete to enhance its properties. However, most chemical admixtures on the market today are expensive, thereby making them out of reach for small consumers of concrete. In Africa, use of chemical admixtures is rare despite the harsh weather conditions. In the current study, Gum from Acacia karroo (GAK) was used as a water-reducing admixture in concrete. A slump test, density and compressive strength were studied using different dosages of GAK while neat concrete was the control. Results showed that slump increased by 200% at a 2% dosage of GAK. This enabled reduction of water-to-binder (w/b) ratio from 0.61 to 0.48 for samples with a 3% dosage. Reduction in w/b resulted in increased compressive strength of 37.03% above the control after 180 days of curing for a 3% dosage. XRD studies also showed a decreased rate of hydration in the presence of GAK in concrete. It was concluded that GAK can be used in concrete as a water-reducing admixture, which is environmentally-friendly, thus producing sustainable and greener concrete. PMID:28787879

  1. Sugar and hexokinase suppress expression of PIP aquaporins and reduce leaf hydraulics that preserves leaf water potential.

    Science.gov (United States)

    Kelly, Gilor; Sade, Nir; Doron-Faigenboim, Adi; Lerner, Stephen; Shatil-Cohen, Arava; Yeselson, Yelena; Egbaria, Aiman; Kottapalli, Jayaram; Schaffer, Arthur A; Moshelion, Menachem; Granot, David

    2017-07-01

    Sugars affect central aspects of plant physiology, including photosynthesis, stomatal behavior and the loss of water through the stomata. Yet, the potential effects of sugars on plant aquaporins (AQPs) and water conductance have not been examined. We used database and transcriptional analyses, as well as cellular and whole-plant functional techniques to examine the link between sugar-related genes and AQPs. Database analyses revealed a high level of correlation between the expression of AQPs and that of sugar-related genes, including the Arabidopsis hexokinases 1 (AtHXK1). Increased expression of AtHXK1, as well as the addition of its primary substrate, glucose (Glc), repressed the expression of 10 AQPs from the plasma membrane-intrinsic proteins (PIP) subfamily (PIP-AQPs) and induced the expression of two stress-related PIP-AQPs. The osmotic water permeability of mesophyll protoplasts of AtHXK1-expressing plants and the leaf hydraulic conductance of those plants were significantly reduced, in line with the decreased expression of PIP-AQPs. Conversely, hxk1 mutants demonstrated a higher level of hydraulic conductance, with increased water potential in their leaves. In addition, the presence of Glc reduced leaf water potential, as compared with an osmotic control, indicating that Glc reduces the movement of water from the xylem into the mesophyll. The production of sugars entails a significant loss of water and these results suggest that sugars and AtHXK1 affect the expression of AQP genes and reduce leaf water conductance, to coordinate sugar levels with the loss of water through transpiration. © 2017 The Authors The Plant Journal © 2017 John Wiley & Sons Ltd.

  2. Radiation protective agents possessing anti-oxidative properties

    Energy Technology Data Exchange (ETDEWEB)

    Anzai, Kazunori; Ueno, Emi; Yoshida, Akira; Furuse, Masako; Ikota, Nobuo [National Inst. of Radiological Sciences, Research Center for Radiation Safety, Chiba, Chiba (Japan)

    2005-11-15

    The purpose of studies is to see mechanisms of radiation protection of agents possessing anti-oxidative properties because the initial step resulting in radiation hazard is the formation of radicals by water radiolysis. Agents were commercially available or synthesized proxyl derivatives (spin prove agents), commercially available spin-trapping agents, edaravone and TMG (a tocopherol glycoside). Mice and cultured cells were X-irradiated by Shimadzu Pantak HF-320 or 320S. Survivals of cells were determined by colony assay and of mice, to which the agents were given intraperitoneally before or after X-irradiation, within 30 days post irradiation. Plasma and marrow concentrations of proxyls were estimated by electron spin resonance (ESR) spectrometry. Mechanisms of their radiation protective effects were shown different from agent to agent. TMG was found effective even post irradiation, which suggests a possibility for a new drug development. Some (spin trapping agents and TMG), virtually ineffective at the cell level, were found effective in the whole body, suggesting the necessity of studies on their disposition and metabolism. (S.I.)

  3. Radiation protective agents possessing anti-oxidative properties

    International Nuclear Information System (INIS)

    Anzai, Kazunori; Ueno, Emi; Yoshida, Akira; Furuse, Masako; Ikota, Nobuo

    2005-01-01

    The purpose of studies is to see mechanisms of radiation protection of agents possessing anti-oxidative properties because the initial step resulting in radiation hazard is the formation of radicals by water radiolysis. Agents were commercially available or synthesized proxyl derivatives (spin prove agents), commercially available spin-trapping agents, edaravone and TMG (a tocopherol glycoside). Mice and cultured cells were X-irradiated by Shimadzu Pantak HF-320 or 320S. Survivals of cells were determined by colony assay and of mice, to which the agents were given intraperitoneally before or after X-irradiation, within 30 days post irradiation. Plasma and marrow concentrations of proxyls were estimated by electron spin resonance (ESR) spectrometry. Mechanisms of their radiation protective effects were shown different from agent to agent. TMG was found effective even post irradiation, which suggests a possibility for a new drug development. Some (spin trapping agents and TMG), virtually ineffective at the cell level, were found effective in the whole body, suggesting the necessity of studies on their disposition and metabolism. (S.I.)

  4. Process for encapsulating active agents obtaining a gel

    NARCIS (Netherlands)

    Yilmaz, G.; Jongboom, R.O.J.

    2001-01-01

    The present invention relates to a process for encapsulating an active agent in a biopolymer in the form of a gel, comprising the steps of: a) forming a dispersion or solution of the biopolymer in water; and b) adding the active agent to the dispersion or solution obtained in step a); wherein the

  5. Operation Clean Feather: Reducing oil pollution in Newfoundland waters

    International Nuclear Information System (INIS)

    Chardine, J.W.; Pelly, G.

    1994-01-01

    Oil pollution of marine waters around Newfoundland, and particularly in the vicinity of Placentia Bay, is a frequent occurrence. Many oiled seabirds are found on beaches in the bay, particularly in winter. The most likely pollution sources are ship operators who dump waste oils from bilges and slop tanks. In an effort to reduce the chronic discharge of waste oil into Placentia Bay, and thus the incidence of bird oiling, Operation Clean Feather was launched in 1991-92 and consisted of weekly surveys of Placentia Bay beaches, sampling of oil from vessels using the bay and from oiled birds and beaches, and experimentation to determine possible recovery rates of birds oiled at sea. The operation was considered a success at a number of levels. Significant reductions in numbers of oiled birds were noted in both 1991 and 1992 compared to 1989 or 1990. Estimated oil-related mortality was reduced to ca 25% of levels seen in the two years prior to the operation. The operation also provided the opportunity to test and refine an organizational framework designed to deal with the problem of chronic oil pollution reports. Communication efforts heightened the awareness of the oil pollution problem in Newfoundland waters. These efforts included distribution of pamphlets in various languages to ship operators, describing the seriousness of oil-related marine bird mortality and warning of the substantial fines that can be imposed under the Canada Shipping Act. 6 refs., 3 figs., 1 tab

  6. Mine water treatment in Donbass

    Energy Technology Data Exchange (ETDEWEB)

    Azarenkov, P A; Anisimov, V M; Krol, V A

    1980-10-01

    About 2,000,000 m$SUP$3 of mine water are discharged by coal mines yearly to surface waters in the Donbass. Mine water in the region is rich in mineral salts and suspended matter (coal and rock particles). The DonUGI Institute developed a system of mine water treatment which permits the percentage of suspended matter to be reduced to 1.5 mg/l. The treated mine water can be used in fire fighting and in dust suppression systems in coal mines. A scheme of the water treatment system is shown. It consists of the following stages: reservoir of untreated mine water, chamber where mine water is mixed with reagents, primary sedimentation tanks, sand filters, and chlorination. Aluminium sulphate is used as a coagulation agent. To intensify coagulation polyacrylamide is added. Technical specifications of surface structures in which water treatment is carried out are discussed. Standardized mine water treatment systems with capacities of 600 m$SUP$3/h, with 900, 1200, 1500, 1800 and 2100 m$SUP$3/h capacities are used. (In Russian)

  7. The necessary burden of involving stakeholders in agent-based modelling for education and decision-making

    Science.gov (United States)

    Bommel, P.; Bautista Solís, P.; Leclerc, G.

    2016-12-01

    We implemented a participatory process with water stakeholders for improving resilience to drought at watershed scale, and for reducing water pollution disputes in drought prone Northwestern Costa Rica. The purpose is to facilitate co-management in a rural watershed impacted by recurrent droughts related to ENSO. The process involved designing "ContaMiCuenca", a hybrid agent-based model where users can specify the decisions of their agents. We followed a Companion Modeling approach (www.commod.org) and organized 10 workshops that included research techniques such as participatory diagnostics, actor-resources-interaction and UML diagrams, multi-agents model design, and interactive simulation sessions. We collectively assessed the main water issues in the watershed, prioritized their importance, defined the objectives of the process, and pilot-tested ContaMiCuenca for environmental education with adults and children. Simulation sessions resulted in debates about the need to improve the model accuracy, arguably more relevant for decision-making. This helped identify sensible knowledge gaps in the groundwater pollution and aquifer dynamics that need to be addressed in order to improve our collective learning. Significant mismatches among participants expectations, objectives, and agendas considerably slowed down the participatory process. The main issue may originate in participants expecting technical solutions from a positivist science, as constantly promoted in the region by dole-out initiatives, which is incompatible with the constructivist stance of participatory modellers. This requires much closer interaction of community members with modellers, which may be hard to attain in the current research practice and institutional context. Nevertheless, overcoming these constraints is necessary for a true involvement of water stakeholders to achieve community-based decisions that facilitate integrated water management. Our findings provide significant guidance for

  8. Bitter taste masking of enzyme-treated soy protein in water and bread.

    Science.gov (United States)

    Bertelsen, Anne S; Laursen, Anne; Knudsen, Tine A; Møller, Stine; Kidmose, Ulla

    2018-08-01

    Bioactive protein hydrolysates are often very bitter. To overcome this challenge, xylitol, sucrose, α-cyclodextrin, maltodextrin and combinations of these were tested systematically as bitter-masking agents of an enzyme-treated soy protein in an aqueous model and in a bread model. Sensory descriptive analysis was used to reveal the bitter-masking effect of the taste-masking blends on the enzyme-treated soy protein. In water, xylitol, sucrose and maltodextrin reduced bitterness significantly, whereas α-cyclodextrin did not. No significant difference was observed in bitterness reduction between xylitol and sucrose. Both reduced bitterness significantly more than maltodextrin. No interactions between the taste-masking agents affecting bitterness reduction were found. Clearer bitter-masking effects were seen in the aqueous model compared with the bread model. The bitter-masking effects of α-cyclodextrin and maltodextrin were similar between water and bread. The effect of xylitol and sucrose on bitterness suppression varied between the systems. In water, bitterness was negatively correlated with sweetness. In bread, bitterness was negatively correlated with freshness, and maltodextrin significantly reduced bitterness of the enzyme-treated soy protein and increased freshness. Bitter-masking effects were generally more discernible in the aqueous model compared with the bread model. © 2018 Society of Chemical Industry. © 2018 Society of Chemical Industry.

  9. (Pyridine)(tetrahydroborato)zinc complex, (Zn(BH4)2(py)), as a new stable, efficient and chemoselective reducing agent for reduction of carbonyl compounds

    International Nuclear Information System (INIS)

    Zeynizadeh, Behzad; Faraji, Fariba

    2003-01-01

    (Pyridine)(tetrahydroborato)zinc complex, (Zn(BH 4 ) 2 (py)), as a stable white solid, was prepared quantitatively by complexation of an equimolar amount of zinc tetrahydroborate and pyridine at room temperature. This reagent can easily reduce variety of carbonyl compounds such as aldehydes, ketones, acyloins, α-diketones and α,β-unsaturated carbonyl compounds to their corresponding alcohols in good to excellent yields. Reduction reactions were performed in ether or THF at room temperature or under reflux conditions. In addition, the chemoselective reduction of aldehydes over ketones was accomplished successfully with this reducing agent

  10. Climate variability and change in the United States: potential impacts on water- and foodborne diseases caused by microbiologic agents.

    Science.gov (United States)

    Rose, J B; Epstein, P R; Lipp, E K; Sherman, B H; Bernard, S M; Patz, J A

    2001-05-01

    Exposure to waterborne and foodborne pathogens can occur via drinking water (associated with fecal contamination), seafood (due to natural microbial hazards, toxins, or wastewater disposal) or fresh produce (irrigated or processed with contaminated water). Weather influences the transport and dissemination of these microbial agents via rainfall and runoff and the survival and/or growth through such factors as temperature. Federal and state laws and regulatory programs protect much of the U.S. population from waterborne disease; however, if climate variability increases, current and future deficiencies in areas such as watershed protection, infrastructure, and storm drainage systems will probably increase the risk of contamination events. Knowledge about transport processes and the fate of microbial pollutants associated with rainfall and snowmelt is key to predicting risks from a change in weather variability. Although recent studies identified links between climate variability and occurrence of microbial agents in water, the relationships need further quantification in the context of other stresses. In the marine environment as well, there are few studies that adequately address the potential health effects of climate variability in combination with other stresses such as overfishing, introduced species, and rise in sea level. Advances in monitoring are necessary to enhance early-warning and prevention capabilities. Application of existing technologies, such as molecular fingerprinting to track contaminant sources or satellite remote sensing to detect coastal algal blooms, could be expanded. This assessment recommends incorporating a range of future scenarios of improvement plans for current deficiencies in the public health infrastructure to achieve more realistic risk assessments.

  11. Irrigation with oxygen-nanobubble water can reduce methane emission and arsenic dissolution in a flooded rice paddy

    Science.gov (United States)

    Minamikawa, Kazunori; Takahashi, Masayoshi; Makino, Tomoyuki; Tago, Kanako; Hayatsu, Masahito

    2015-08-01

    A remarkable feature of nanobubbles (pot experiment and measuring redox-related variables. The NBs were introduced into control water (with properties similar to those of river water) using a commercially available generator. Rice (Oryza sativa L.) growth did not differ between plants irrigated with NB water and those irrigated with control water, but NB water significantly (p rice-growing season by 21%. The amounts of iron, manganese, and arsenic that leached into the drainage water before full rice heading were also reduced by the NB water. Regardless of the water type, weekly-measured CH4 flux was linearly correlated with the leached iron concentration during the rice-growing season (r = 0.74, p pots without rice plants, soil reduction was not enhanced, regardless of the water type. The results indicate that NB water reduced CH4 emission and arsenic dissolution through an oxidative shift of the redox conditions in the flooded soil. We propose the use of NB water as a tool for controlling redox conditions in flooded paddy soils.

  12. Cellulose nanocomposite films with in situ generated silver nanoparticles using Cassia alata leaf extract as a reducing agent.

    Science.gov (United States)

    Sivaranjana, P; Nagarajan, E R; Rajini, N; Jawaid, M; Rajulu, A Varada

    2017-06-01

    Cotton linters were dissolved in aq. (8% LiOH+15% urea) that was pre-cooled to -12.5°C. Using this solution cellulose gel films were prepared by regeneration method with ethyl alcohol as a coagulant. These wet films were diffused with 10wt% Cassia alata leaf extract that acted as a reducing agent. The leaf extract diffused cellulose wet films were used as the matrix. The wet matrix films were dipped individually in lower concentrated 1-5mM aq.AgNO 3 source solutions in the presence of sunlight and allowed the solutions to react with the diffused leaf extract reducing agent which in situ generated the silver nanoparticles (AgNPs) inside the films as well as in the source solution. The AgNPs formed in the source solution were observed by transmission electron microscope (TEM) and scanning electron microscope (SEM) while those formed in situ the films were observed by SEM and the particle size distribution was determined. The cellulose/AgNP composite films showed good antibacterial activity against Escherichia coli bacteria. These nanocomposite films were also characterized by Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD), thermogravimetric analysis (TGA) and tensile tests. At temperatures below 300°C, the thermal stability of the nanocomposite films was lower than that of the matrix due to the catalytic effect of AgNPs. The nanocomposite films also possessed good tensile properties. The ecofriendly cellulose/AgNP composite films with good antibacterial activity and tensile properties can be considered for medical applications like dressing materials. Copyright © 2017 Elsevier B.V. All rights reserved.

  13. Effects of reduced water quality on coral reefs in and out of no-take marine reserves.

    Science.gov (United States)

    Wenger, Amelia S; Williamson, David H; da Silva, Eduardo T; Ceccarelli, Daniela M; Browne, Nicola K; Petus, Caroline; Devlin, Michelle J

    2016-02-01

    Near-shore marine environments are increasingly subjected to reduced water quality, and their ability to withstand it is critical to their persistence. The potential role marine reserves may play in mitigating the effects of reduced water quality has received little attention. We investigated the spatial and temporal variability in live coral and macro-algal cover and water quality during moderate and major flooding events of the Fitzroy River within the Keppel Bay region of the Great Barrier Reef Marine Park from 2007 to 2013. We used 7 years of remote sensing data on water quality and data from long-term monitoring of coral reefs to quantify exposure of coral reefs to flood plumes. We used a distance linear model to partition the contribution of abiotic and biotic factors, including zoning, as drivers of the observed changes in coral and macro-algae cover. Moderate flood plumes from 2007 to 2009 did not affect coral cover on reefs in the Keppel Islands, suggesting the reef has intrinsic resistance against short-term exposure to reduced water quality. However, from 2009 to 2013, live coral cover declined by ∼ 50% following several weeks of exposure to turbid, low salinity water from major flood plume events in 2011 and subsequent moderate events in 2012 and 2013. Although the flooding events in 2012 and 2013 were smaller than the flooding events between 2007 to 2009, the ability of the reefs to withstand these moderate floods was lost, as evidenced by a ∼ 20% decline in coral cover between 2011 to 2013. Although zoning (no-take reserve or fished) was identified a significant driver of coral cover, we recorded consistently lower coral cover on reserve reefs than on fished reefs throughout the study period and significantly lower cover in 2011. Our findings suggest that even reefs with an inherent resistance to reduced water quality are not able to withstand repeated disturbance events. The limitations of reserves in mitigating the effects of reduced water

  14. Water Table Management Reduces Tile Nitrate Loss in Continuous Corn and in a Soybean-Corn Rotation

    Directory of Open Access Journals (Sweden)

    Craig F. Drury

    2001-01-01

    Full Text Available Water table management systems can be designed to alleviate soil water excesses and deficits, as well as reduce nitrate leaching losses in tile discharge. With this in mind, a standard tile drainage (DR system was compared over 8 years (1991 to 1999 to a controlled tile drainage/subirrigation (CDS system on a low-slope (0.05 to 0.1% Brookston clay loam soil (Typic Argiaquoll in southwestern Ontario, Canada. In the CDS system, tile discharge was controlled to prevent excessive drainage, and water was pumped back up the tile lines (subirrigation to replenish the crop root zone during water deficit periods. In the first phase of the study (1991 to 1994, continuous corn (Zea mays, L. was grown with annual nitrogen (N fertilizer inputs as per local soil test recommendations. In the second phase (1995 to 1999, a soybean (Glycine max L., Merr.-corn rotation was used with N fertilizer added only during the two corn years. In Phase 1 when continuous corn was grown, CDS reduced total tile discharge by 26% and total nitrate loss in tile discharge by 55%, compared to DR. In addition, the 4-year flow weighted mean (FWM nitrate concentration in tile discharge exceeded the Canadian drinking water guideline (10 mg N l–1 under DR (11.4 mg N l–1, but not under CDS (7.0 mg N l–1. In Phase 2 during the soybean-corn rotation, CDS reduced total tile discharge by 38% and total nitrate loss in tile discharge by 66%, relative to DR. The 4-year FWM nitrate concentration during Phase 2 in tile discharge was below the drinking water guideline for both DR (7.3 mg N l–1 and CDS (4.0 mg N l–1. During both phases of the experiment, the CDS treatment caused only minor increases in nitrate loss in surface runoff relative to DR. Hence CDS decreased FWM nitrate concentrations, total drainage water loss, and total nitrate loss in tile discharge relative to DR. In addition, soybean-corn rotation reduced FWM nitrate concentrations and total nitrate loss in tile discharge

  15. Decontamination of Water Containing Radiological Warfare Agents

    Science.gov (United States)

    1975-03-01

    soil or air, dissolved minerals in water, or mnaterials of construction of thie’ hob n its•llf. So--called "rigged boiihbs" or "salted bo nits...Carbion 2-10 In regard to tire diatomite filter, the coagulated water passes throtugh the filter cake to the interior of each filter clenrnn. Thre filtrale...data indicate the following: a. Nuclear bomb debris from a silicious soil , being essentially insoluble in water, is easily removed by coagulation and

  16. Geo-inspired model: Agents vectors naturals inspired by the environmental management (AVNG of water tributaries

    Directory of Open Access Journals (Sweden)

    Edwin Eduardo Millán Rojas

    2018-02-01

    Full Text Available Context: Management to care for the environment and the Earth (geo can be source of inspiration for developing models that allow addressing complexity issues; the objective of this research was to develop an additional aspect of the inspired models. The geoinspired model has two features, the first covering aspects related to environmental management and the behavior of natural resources, and the second has a component of spatial location associated with existing objects on the Earth's surface. Method: The approach developed in the research is descriptive and its main objective is the representation or characterization of a case study within a particular context. Results: The result was the design of a model to emulate the natural behavior of the water tributaries of the Amazon foothills, in order to extend the application of the inspired models and allow the use of elements such as geo-referencing and environmental management. The proposed geoinspired model is called “natural vectors agents inspired in environmental management”. Conclusions: The agents vectors naturals inspired by the environmental are polyform elements that can assume the behavior of environmental entities, which makes it possible to achieve progress in other fields of environmental management (use of soil, climate, flora, fauna, and link environmental issues with the structure of the proposed model.

  17. Decision-making support system based on MAS for emergency response to nuclear accidents of marine pressurized-water reactor

    International Nuclear Information System (INIS)

    Chen Dengke; Zhang Dafa; Jiang Wei; Chen Yonghong

    2007-01-01

    Emergency decision-making to Marine Pressurized-Water Reactor (MPWR) was severely restricted by the complex environment. To enhance the emergency decision-making ability of MPWR, reducing the effect of emergencies, an emergency Decision-making Support System (DSS) which based on Multi-agent System (MAS) was presented. In the system, the HLA/RTI was used as the support environment, and the structure and the Control Agent (SCA), Analyse Agent (AA), Countermeasure Agent (CA), Evaluation Agent (EVA) and Environment Agent (ENA) were designed. The MAS were with the characteristics of autonomy, reactivity and initiative, which were fully used in the system to make effective decision for emergencies. (authors)

  18. The effectiveness testing of oil spill-treating agents

    International Nuclear Information System (INIS)

    Fingas, M.F.; Kyle, D.A.; Laroche, N.; Fieldhouse, B.; Sergy, G.; Stoodley, G.

    1995-01-01

    Laboratory effectiveness tests have been developed for four classes of oil spill treating agents: solidifiers, demulsifying agents, surface-washing agents and dispersants. Several treating agent products in these four categories have been tested for effectiveness. The aquatic toxicity of these agents is an important factor and has been measured for many products. These results are presented. Solidifiers or gelling agents solidify oil. Test results show that solidifiers require between 16% and 200% of agent by weight compared to the oil. De-emulsifying agents or emulsion breakers prevent the formation of or break water-in-oil emulsions. Surfactant-containing materials are of two types, surface-washing agents and dispersants. Testing has shown that effectiveness is orthogonal for these two types of treating agents. Tests of surface washing agents show that only a few agents have effectiveness of 25 to 55%, where this is defined as the percentage of oil removed from a test surface. Dispersant effectiveness results using the swirling flask test are reported. Heavy oils show effectiveness values of about 1%, medium crudes of about 10%, light crude oils of about 30% and very light oils of about 90%

  19. Planning of Autonomous Multi-agent Intersection

    Directory of Open Access Journals (Sweden)

    Viksnin Ilya I.

    2016-01-01

    Full Text Available In this paper, we propose a traffic management system with agents acting on behalf autonomous vehicle at the crossroads. Alternatively to existing solutions based on usage of semiautonomous control systems with the control unit, proposed in this paper algorithm apply the principles of decentralized multi-agent control. Agents during their collaboration generate intersection plan and determinate the optimal order of road intersection for a given criterion based on the exchange of information about them and their environment. The paper contains optimization criteria for possible routes selection and experiments that perform in order to estimate the proposed model. Experiment results show that this model can significantly reduce traffic density compared to the traditional traffic management systems. Moreover, the proposed algorithm efficiency increases with road traffic density. Furthermore, the availability of control unit in the system significantly reduces the negative impact of possible failures and hacker attacks.

  20. A preliminary study on the reduction of limonite ore by using rice husk as a reducing agent

    Science.gov (United States)

    Maksum, Ahmad; Husein, Michael Kelvin E.; Permana, Sulaksana; Rustandi, Andi; Wahyuadi Soedarsono, Johny

    2018-03-01

    The abundant of rice husk in Indonesia has encouraged researchers to study the feasibility of rice husk for substituting material that is more expensive or dangerous. In previous study, silica with a purity of 99.9% has been obtained from rice husk with calcinations process. Nevertheless, the gases resulting from the process were not used and left useless. Therefore, in this study, those gases derived from rice husk calcinations process were used as reducing agents during the ferronickel (Fe-Ni) production through a direct reduction process. The objective of this study was to investigate the effect of the amount of rice husk in the pellets on the increase of nickel content in the limonite reduction process. The limonite ore were crushed to the size of less than 150 mesh using disc-mill, and then were mixed with rice husk powder (10, 20, 30 in wt % mass) before being pelletized using bentonite as a binder. The resulted pellets were roasted at 500°C for 60 minutes and then quenched in water media. After drying process, the reduction process of 40g pellets was conducted at 1000°C for 90 minutes with 20g rice husk in furnace. The effects of additional rice husk on the direct reduction of limonite ore pellets were qualitatively analyzed by using X-ray powder diffraction (XRD) and quantitatively by Atomic absorption spectroscopy (AAS). Both analysis results showed that the reduction process followed the reaction scheme: Fe2O3→Fe3O4→FeO and NiO phase was detected in the sample with 20% rice husk addition. The optimum concentration of Ni 1.23% was obtained for 20% rice husk addition.

  1. Use of Atmospheric Budget to Reduce Uncertainty in Estimated Water Availability over South Asia from Different Reanalyses

    Science.gov (United States)

    Sebastian, Dawn Emil; Pathak, Amey; Ghosh, Subimal

    2016-07-01

    Disagreements across different reanalyses over South Asia result into uncertainty in assessment of water availability, which is computed as the difference between Precipitation and Evapotranspiration (P-E). Here, we compute P-E directly from atmospheric budget with divergence of moisture flux for different reanalyses and find improved correlation with observed values of P-E, acquired from station and satellite data. We also find reduced closure terms for water cycle computed with atmospheric budget, analysed over South Asian landmass, when compared to that obtained with individual values of P and E. The P-E value derived with atmospheric budget is more consistent with energy budget, when we use top-of-atmosphere radiation for the same. For analysing water cycle, we use runoff from Global Land Data Assimilation System, and water storage from Gravity Recovery and Climate Experiment. We find improvements in agreements across different reanalyses, in terms of inter-annual cross correlation when atmospheric budget is used to estimate P-E and hence, emphasize to use the same for estimations of water availability in South Asia to reduce uncertainty. Our results on water availability with reduced uncertainty over highly populated monsoon driven South Asia will be useful for water management and agricultural decision making.

  2. Use of Atmospheric Budget to Reduce Uncertainty in Estimated Water Availability over South Asia from Different Reanalyses.

    Science.gov (United States)

    Sebastian, Dawn Emil; Pathak, Amey; Ghosh, Subimal

    2016-07-08

    Disagreements across different reanalyses over South Asia result into uncertainty in assessment of water availability, which is computed as the difference between Precipitation and Evapotranspiration (P-E). Here, we compute P-E directly from atmospheric budget with divergence of moisture flux for different reanalyses and find improved correlation with observed values of P-E, acquired from station and satellite data. We also find reduced closure terms for water cycle computed with atmospheric budget, analysed over South Asian landmass, when compared to that obtained with individual values of P and E. The P-E value derived with atmospheric budget is more consistent with energy budget, when we use top-of-atmosphere radiation for the same. For analysing water cycle, we use runoff from Global Land Data Assimilation System, and water storage from Gravity Recovery and Climate Experiment. We find improvements in agreements across different reanalyses, in terms of inter-annual cross correlation when atmospheric budget is used to estimate P-E and hence, emphasize to use the same for estimations of water availability in South Asia to reduce uncertainty. Our results on water availability with reduced uncertainty over highly populated monsoon driven South Asia will be useful for water management and agricultural decision making.

  3. Phase change of iron ore reduction process using EFB as reducing agent at 900-1200°C

    Science.gov (United States)

    Purwanto, H.; Salleh, H. M.; Rozhan, A. N.; Mohamad, A. S.; Zakiyuddin, A.

    2018-04-01

    Treatment of low grade iron ore involved reduction of oxygen in iron oxide by using reductant such as carbon monoxide or hydrogen gas. Presently, carboneous materials such as coke/coal are widely used as a source to provide reducing gas, but some problem arises from this material as the gas can harm the environments. Therefore, empty fruit bunch biomass from oil palm becomes an alternative to replace the usage of coke/coal as their major composition is carbon and hydrogen. The idea of replacing coke with biomass will reduce the amount of carbon dioxide release as biomass is a carbon neutral and renewable source, and at the same time abundance of waste from oil palm industries can be overcome. Therefore, the aim of this research is to upgrade the low grade iron with reducibility more than 50% being used in iron and steel making. In this research, low grade iron ore are mixed together with EFB then is making into composite pellet before being reduced at certain parameter chosen. The variables involved in this research is composition EFB (10%, 30% and 50%), temperature (1000°C, 1100°C and 1200°C) and reduction time is fixed with 30 minutes. From the experiment conducted, the highest reducibility achieved is 76.37% at temperature 1200°C. While XRD analysis shows the existence of metallic iron phase started to form at 1000°C with composition of 30% of EFB. Meanwhile, from magnetization test show that at 1200°C the highest magnetic susceptibility is achieved as the dominance phase at 1200°C is metallic phase. Therefore it is an interesting alternative to replace coke with biomass for reducing agent in upgrading low grade iron into workable ores.

  4. The potential for energy savings when reducing the water consumption in a kraft pulp mill

    Energy Technology Data Exchange (ETDEWEB)

    Wising, Ulrika; Berntsson, Thore [Chalmers Univ. of Technology, Goeteborg (Sweden). Dept. of Chemical Engineering and Environmental Science; Stuart, Paul [Ecole Polytechnique, Montreal (Canada). Dept. of Chemical Engineering

    2004-05-01

    In this paper an existing pulp and paper mill has been studied in a systematic way regarding the reduction of water consumption, and the resulting increased potential for energy integration. It has been found that when the mill's hot water consumption is decreased, the live steam demand for the mill also decreases. Also when decreasing the hot water consumption, the quantity and temperature of available excess heat increases. This excess heat can be used for evaporation, thereby reducing the live steam demand further by up to 1.5 GJ/t. A pinch analysis was performed at an existing mill and it was found that if pinch violations are removed, the hot water consumption is not an important factor any more. Removing all the pinch violations and using the remaining excess heat for evaporation yields a significantly larger energy savings for the mill (4.0 GJ/t). From an economic optimum perspective it is probably most profitable to do a combination of reducing water consumption, removing pinch violations, and use the remaining excess heat for evaporation.

  5. Advanced concept of reduced-moderation water reactor (RMWR) for plutonium multiple recycling

    International Nuclear Information System (INIS)

    Okubo, T.; Iwamura, T.; Takeda, R.; Yamamoto, K.; Okada, H.

    2001-01-01

    An advanced water-cooled reactor concept named the Reduced-Moderation Water Reactor (RMWR) has been proposed to attain a high conversion ratio more than 1.0 and to achieve the negative void reactivity coefficient. At present, several types of design concepts satisfying both the design targets have been proposed based on the evaluation for the fuel without fission products and minor actinides. In this paper, the feasibility of the RMWR core is investigated for the plutonium multiple recycling under advanced reprocessing schemes with low decontamination factors as proposed for the FBR fuel cycle. (author)

  6. Scopolamine provocation-based pharmacological MRI model for testing procognitive agents.

    Science.gov (United States)

    Hegedűs, Nikolett; Laszy, Judit; Gyertyán, István; Kocsis, Pál; Gajári, Dávid; Dávid, Szabolcs; Deli, Levente; Pozsgay, Zsófia; Tihanyi, Károly

    2015-04-01

    There is a huge unmet need to understand and treat pathological cognitive impairment. The development of disease modifying cognitive enhancers is hindered by the lack of correct pathomechanism and suitable animal models. Most animal models to study cognition and pathology do not fulfil either the predictive validity, face validity or construct validity criteria, and also outcome measures greatly differ from those of human trials. Fortunately, some pharmacological agents such as scopolamine evoke similar effects on cognition and cerebral circulation in rodents and humans and functional MRI enables us to compare cognitive agents directly in different species. In this paper we report the validation of a scopolamine based rodent pharmacological MRI provocation model. The effects of deemed procognitive agents (donepezil, vinpocetine, piracetam, alpha 7 selective cholinergic compounds EVP-6124, PNU-120596) were compared on the blood-oxygen-level dependent responses and also linked to rodent cognitive models. These drugs revealed significant effect on scopolamine induced blood-oxygen-level dependent change except for piracetam. In the water labyrinth test only PNU-120596 did not show a significant effect. This provocational model is suitable for testing procognitive compounds. These functional MR imaging experiments can be paralleled with human studies, which may help reduce the number of false cognitive clinical trials. © The Author(s) 2015.

  7. Life cycle assessment of central softening of very hard drinking water.

    Science.gov (United States)

    Godskesen, B; Hauschild, M; Rygaard, M; Zambrano, K; Albrechtsen, H-J

    2012-08-30

    Many consumers prefer softened water due to convenience issues such as avoidance of removing limescale deposits from household appliances and surfaces, and to reduce consumption of cleaning agents and laundry detergents leading to lower household expenses. Even though central softening of drinking water entailed an increased use of energy, sand and chemicals at the waterworks, the distributed and softened drinking water supported a decrease in consumption of energy and chemical agents in the households along with a prolonged service life of household appliances which heat water. This study used Life Cycle Assessment (LCA) to quantify the environmental impacts of central softening of drinking water considering both the negative effects at the waterworks and the positive effects imposed by the changed water quality in the households. The LCA modeling considered central softening of drinking water from the initial hardness of the region of study (Copenhagen, Denmark) which is 362 mg/L as CaCO(3) to a final hardness as CaCO(3) of 254 (a softening depth of 108) mg/L or 145 (a softening depth of 217) mg/L. Our study showed that the consumer preference can be met together with reducing the impact on the environment and the resource consumption. Environmental impacts decreased by up to 3 mPET (milli Personal Equivalent Targeted) and the break-even point from where central softening becomes environmentally beneficial was reached at a softening depth of only 22 mg/L as CaCO(3). Both energy-related and chemically related environmental impacts were reduced as well as the consumption of resources. Based on scarcity criteria, nickel was identified as the most problematic non-renewable resource in the system, and savings of up to 8 mPR (milli Person Reserve) were found. Copyright © 2012 Elsevier Ltd. All rights reserved.

  8. Reductive Leaching Kinetics of Low Grade Manganese Deposits in H2SO4 Solution Using Malonic Acid as Reducing Agent

    OpenAIRE

    Taysser Lasheen; S. A. Abu Elenein; W. A. Saleh; A. H Orabi; D. A Ismaiel

    2014-01-01

    A leaching process was developed to extract manganese and metal values from Alloga manganese concentrate. The preferential leaching process was achieved through reductive leaching in dilute sulfuric acid medium with malonic acid as the reducing agent. Leaching parameters were optimized as 1.0 M H2SO4, 10% malonic acid in solid/liquid ratio 1:10 for 90 min at 80 C and using ore ground to – 74 µm. Under these conditions, the leaching efficiency of manganese reaches 97%, whilst iron dissolution ...

  9. Measures to reduce the impact of anti-icing agents on the environment and on the work of wastewater treatment facilities

    Directory of Open Access Journals (Sweden)

    Voronov Yuriy Viktorovich

    2014-09-01

    Full Text Available This article analyses the impact of the excess of chemical agents in the snow on the environment and on the working waste water treatment facilities. The article presents some suggestions for improvement of regulatory requirements concerning design engineering of snow melting facilities in the water disposal system. This suggestion was substantiated to assess snow as waste disposed from road surface, and to register snow mass delivered to snow melting facilities in equivalent units. It is assumed that snow melting stations are facilities designed for waste treatment, and this is why the project documentation for construction of these facilities has to undergo a state expertise for Environmental Impact Assessment. Completed studies provide estimates of the receipted snow, its pollution, etc. But at the same time these studies serve as the basis for approving the necessity of developing a unified system for monitoring the city's snow-melting plants to ensure the reliability.

  10. Preliminary assessment of the interaction of introduced biological agents with biofilms in water distribution systems.

    Energy Technology Data Exchange (ETDEWEB)

    Sinclair, Michael B.; Caldwell, Sara; Jones, Howland D. T.; Altman, Susan Jeanne; Souza, Caroline Ann; McGrath, Lucas K.

    2005-12-01

    Basic research is needed to better understand the potential risk of dangerous biological agents that are unintentionally or intentionally introduced into a water distribution system. We report on our capabilities to conduct such studies and our preliminary investigations. In 2004, the Biofilms Laboratory was initiated for the purpose of conducting applied research related to biofilms with a focus on application, application testing and system-scale research. Capabilities within the laboratory are the ability to grow biofilms formed from known bacteria or biofilms from drinking water. Biofilms can be grown quickly in drip-flow reactors or under conditions more analogous to drinking-water distribution systems in annular reactors. Biofilms can be assessed through standard microbiological techniques (i .e, aerobic plate counts) or with various visualization techniques including epifluorescent and confocal laser scanning microscopy and confocal fluorescence hyperspectral imaging with multivariate analysis. We have demonstrated the ability to grow reproducible Pseudomonas fluorescens biofilms in the annular reactor with plate counts on the order of 10{sup 5} and 10{sup 6} CFU/cm{sup 2}. Stationary phase growth is typically reached 5 to 10 days after inoculation. We have also conducted a series of pathogen-introduction experiments, where we have observed that both polystyrene microspheres and Bacillus cereus (as a surrogate for B. anthracis) stay incorporated in the biofilms for the duration of our experiments, which lasted as long as 36 days. These results indicated that biofilms may act as a safe harbor for bio-pathogens in drinking water systems, making it difficult to decontaminate the systems.

  11. Removal heavy metals and sulphate from waste waters by sulphate-reducing bacteria

    Directory of Open Access Journals (Sweden)

    Kušnierová Mária

    2000-09-01

    Full Text Available This article is devoted to the process of bacterial sulphate reduction, which is used to removal of heavy metals and sulphate ions from waste waters.The life of animals and plants depends on the existence of microscopic organisms – microorganisms (MO, which play an important role in cycle changes of biogenic elements on the earth. The sulphur cycle in the nature is considered as one of the oldest and most significant biological systems (Fig. 1. The sulphate-reducing bacteria (SRB miss the assimilatory part of the cycle and produce sulphides. The microbial population of this dissimilatory part is called “sulfuretum”. The SRB can be found in anaerobic mud and sediments of freshwater, thermal or non-thermal sulphur springs, mining waters from sulphide deposits, oil deposits, sea and ocean beds, and in the gastrointestinal tract of man and animals. The SRB represent a group of chemoorganotrophic, strictly anaerobic and gramnegative bacteria, which exhibit a great morphological and physiological diversity. Despite of their considerable morphological variety, they have one property in common, which is the ability to utilise preferentially sulphates (occasionally sulphites, thiosulphates, tetrathionates as electron acceptors, which are reduced to sulphides, during anaerobic respiration. The electron donors in these processes are simple organic compounds as lactate, malate, etc.,(heterotrophically reduction or gaseous hydrogen (autotrophically reduction. SRB can produce a considerable amount of hydrogen sulphide, which reacts easily in aqueous solution with the cations of heavy metals, forming metal sulphides that have low solubility. The bacterial sulphate reduction can be used for the treatment of acid mine drainage waters, which is considered to be the major problem associated with mining activities.In order to remove heavy metals from waste waters, e.g., from galvanizing plants, mine waters (Smolnik, Šobov locality and metallurgic plants (works

  12. Physiological response of Pseudomonas putida S12 subjected to reduced water activity.

    NARCIS (Netherlands)

    Kets, E.P.W.; Bont, de J.A.M.; Heipieper, H.J.

    1996-01-01

    The effect of osmotic stress, given as decreased water activity (aw), on growth and the accumulation of potassium and the compatible solute betaine by Pseudomonas putida S12 was investigated. Reduced aw was imposed by addition of sodium chloride, sucrose, glycerol or polyethylene glycol to the

  13. Benchmarking Water Quality from Wastewater to Drinking Waters Using Reduced Transcriptome of Human Cells.

    Science.gov (United States)

    Xia, Pu; Zhang, Xiaowei; Zhang, Hanxin; Wang, Pingping; Tian, Mingming; Yu, Hongxia

    2017-08-15

    One of the major challenges in environmental science is monitoring and assessing the risk of complex environmental mixtures. In vitro bioassays with limited key toxicological end points have been shown to be suitable to evaluate mixtures of organic pollutants in wastewater and recycled water. Omics approaches such as transcriptomics can monitor biological effects at the genome scale. However, few studies have applied omics approach in the assessment of mixtures of organic micropollutants. Here, an omics approach was developed for profiling bioactivity of 10 water samples ranging from wastewater to drinking water in human cells by a reduced human transcriptome (RHT) approach and dose-response modeling. Transcriptional expression of 1200 selected genes were measured by an Ampliseq technology in two cell lines, HepG2 and MCF7, that were exposed to eight serial dilutions of each sample. Concentration-effect models were used to identify differentially expressed genes (DEGs) and to calculate effect concentrations (ECs) of DEGs, which could be ranked to investigate low dose response. Furthermore, molecular pathways disrupted by different samples were evaluated by Gene Ontology (GO) enrichment analysis. The ability of RHT for representing bioactivity utilizing both HepG2 and MCF7 was shown to be comparable to the results of previous in vitro bioassays. Finally, the relative potencies of the mixtures indicated by RHT analysis were consistent with the chemical profiles of the samples. RHT analysis with human cells provides an efficient and cost-effective approach to benchmarking mixture of micropollutants and may offer novel insight into the assessment of mixture toxicity in water.

  14. 国内外银镜还原剂对比试验%Comparative Trial of Reducing Agent for Silver-mirror Production at Home and Abroad

    Institute of Scientific and Technical Information of China (English)

    杨晨; 徐卫民; 梁中生

    2011-01-01

    Comparative trial of percent silver-conversion with home and abroad reducing agent was carried out on automatic silver-coating line under identical production parameters . The silver content on unit area was determined by titration and the conversion rate of silver nitrate with different reducing agent was evaluated.%在各项工艺参数基本相同的情况下,将国内外银镜还原剂在自动化镀银生产线上进行了银转化率对比试验,用滴定法测定镜子单位面积银的含量,分析了还原剂对硝酸银的转化率,结果表明,德国还原剂对银的转换效率为813%,英国还原剂对银的转换效率为70.8%。

  15. Corrosion of bismuth-based superconductor wires by some atmospheric agents

    International Nuclear Information System (INIS)

    Ben Azzouz, F.; M'chirgui, A.; Ben Salem, M.; Yangui, B.; Lamine, C.; Nitsche, S.; Boulesteix, C.

    2000-01-01

    Superconducting wires (SWs) were previously prepared in our group by heat treatment of bismuth-based superconductor coatings on a metal core. This paper presents an analysis of the corrosion process by some atmospheric agents on the SWs. SWs with different concentrations of a (Bi, Pb)-2223 phase have been exposed to water vapour saturated air, to pure water vapour or to dry carbon dioxide. Each of these atmospheric agents was found to act differently on the SWs. However, all the studied corrosion processes present a high sensitivity to the concentration of the (Bi, Pb)-2223 phase. For a higher concentration of this phase, the SWs are less sensitive to atmospheric agents. (author)

  16. Effects of NOx-inhibitor agent on fuel properties of three-phase biodiesel emulsions

    International Nuclear Information System (INIS)

    Lin, Cherng-Yuan; Lin, Hsiu-An

    2008-01-01

    Biodiesel is one of the more promising alternative clean fuels to fossil fuel, which can reduce the emissions of fossil fuel burning, and possibly resolve the energy crisis caused by the exhaustion of petroleum resources in the near future. The burning of biodiesel emits much less gaseous emissions and particulate matter primarily because of its dominant combustion efficiency. However, the high oxygen content in biodiesel not only promotes the burning process but also enhances NO x formation when biodiesel is used as fuel. Biodiesel emulsion and the additive of NO x -inhibitor agent are considered to reduce levels of NO x emissions in this experimental study. The biodiesel was produced by transesterification reaction accompanied with peroxidation process. A three-phase biodiesel emulsion of oil-in water drops-in oil (O/W/O) and an O/W/O biodiesel emulsion containing aqueous ammonia were prepared afterwards. The effect of the existence of NO x -inhibitor agent on the fuel properties and the emulsion characteristics of the O/W/O biodiesel emulsions were investigated. The experimental results show that the burning of the O/W/O biodiesel emulsion and the O/W/O biodiesel emulsion containing aqueous ammonia had larger fraction of fuel burnt and thus larger heat release than the neat biodiesel if water content is not considered for the calculation of heating value. The addition of aqueous ammonia within the dispersed phase of the O/W/O biodiesel emulsion appeared to deteriorate the emulsification characteristics. A smaller quantity of emulsion and greater kinematic viscosity were formed while a larger carbon residue and actual reaction-heat release also appeared for this O/W/O biodiesel emulsion. Aqueous ammonia in the O/W/O biodiesel emulsion produces a higher pH value as well. In addition, the number as well as the volumetric fraction of the dispersed water droplets is reduced for the O/W/O biodiesel emulsion that contains aqueous ammonia. (author)

  17. Reducing Traffic Congestions by Introducing CACC-Vehicles on a Multi-Lane Highway Using Agent-Based Approach

    Science.gov (United States)

    Arnaout, Georges M.; Bowling, Shannon R.

    2011-01-01

    Traffic congestion is an ongoing problem of great interest to researchers from different areas in academia. With the emerging technology for inter-vehicle communication, vehicles have the ability to exchange information with predecessors by wireless communication. In this paper, we present an agent-based model of traffic congestion and examine the impact of having CACC (Cooperative Adaptive Cruise Control) embedded vehicle(s) on a highway system consisting of 4 traffic lanes without overtaking. In our model, CACC vehicles adapt their acceleration/deceleration according to vehicle-to-vehicle inter-communication. We analyze the average speed of the cars, the shockwaves, and the evolution of traffic congestion throughout the lifecycle of the model. The study identifies how CACC vehicles affect the dynamics of traffic flow on a complex network and reduce the oscillatory behavior (stop and go) resulting from the acceleration/deceleration of the vehicles.

  18. Increased food production and reduced water use through optimized crop distribution

    Science.gov (United States)

    Davis, Kyle Frankel; Rulli, Maria Cristina; Seveso, Antonio; D'Odorico, Paolo

    2017-12-01

    Growing demand for agricultural commodities for food, fuel and other uses is expected to be met through an intensification of production on lands that are currently under cultivation. Intensification typically entails investments in modern technology — such as irrigation or fertilizers — and increases in cropping frequency in regions suitable for multiple growing seasons. Here we combine a process-based crop water model with maps of spatially interpolated yields for 14 major food crops to identify potential differences in food production and water use between current and optimized crop distributions. We find that the current distribution of crops around the world neither attains maximum production nor minimum water use. We identify possible alternative configurations of the agricultural landscape that, by reshaping the global distribution of crops within current rainfed and irrigated croplands based on total water consumption, would feed an additional 825 million people while reducing the consumptive use of rainwater and irrigation water by 14% and 12%, respectively. Such an optimization process does not entail a loss of crop diversity, cropland expansion or impacts on nutrient and feed availability. It also does not necessarily invoke massive investments in modern technology that in many regions would require a switch from smallholder farming to large-scale commercial agriculture with important impacts on rural livelihoods.

  19. Reduced Graphene Oxide Membranes: Applications in Fog Collection and Water Purification

    KAUST Repository

    Tang, Bo

    2017-05-01

    Reduced graphene oxide (rGO) has attracted considerable interest recently as the low cost and chemical stable derivative of pristine graphene with application in many applications such as energy storage, water purification and electronic devices. This dissertation thoroughly investigated stacked rGO membrane fabrication process by vacuum-driven filtration, discovered asymmetry of the two surfaces of the rGO membrane, explored application perspectives of the asymmetric rGO membrane in fog collection and microstructure patterning, and disclosed membrane compaction issue during water filtration and species rejection. In more details, this dissertation revealed that, with suitable pore size, the filtration membrane substrate would leave its physical imprint on the bottom surface of the rGO membrane in the form of surface microstructures, which result in asymmetric dynamic water wettability properties of the two surfaces of the rGO membrane. The asymmetric wettability of the rGO membrane would lead to contrasting fog harvesting behavior of its two surfaces. The physical imprint mechanism was further extended to engineering pre-designed patterns selectively on the bottom surface of the rGO membrane. This dissertation, for the first time, reported the water flux and rejection kinetics, which was related to the compaction of the rGO membrane under pressure in the process of water filtration.

  20. Combining Bayesian Networks and Agent Based Modeling to develop a decision-support model in Vietnam

    Science.gov (United States)

    Nong, Bao Anh; Ertsen, Maurits; Schoups, Gerrit

    2016-04-01

    Complexity and uncertainty in natural resources management have been focus themes in recent years. Within these debates, with the aim to define an approach feasible for water management practice, we are developing an integrated conceptual modeling framework for simulating decision-making processes of citizens, in our case in the Day river area, Vietnam. The model combines Bayesian Networks (BNs) and Agent-Based Modeling (ABM). BNs are able to combine both qualitative data from consultants / experts / stakeholders, and quantitative data from observations on different phenomena or outcomes from other models. Further strengths of BNs are that the relationship between variables in the system is presented in a graphical interface, and that components of uncertainty are explicitly related to their probabilistic dependencies. A disadvantage is that BNs cannot easily identify the feedback of agents in the system once changes appear. Hence, ABM was adopted to represent the reaction among stakeholders under changes. The modeling framework is developed as an attempt to gain better understanding about citizen's behavior and factors influencing their decisions in order to reduce uncertainty in the implementation of water management policy.

  1. Antimicrobial Agents Used in Endodontic Treatment

    Directory of Open Access Journals (Sweden)

    Marina George Kudiyirickal

    2008-01-01

    Full Text Available Biomechanical preparation alone does not completely eradicate microorganisms from the root canal, hence the next logical step is to perform root canal procedures in conjunction with antimicrobials. The use of an antimicrobial agent improves the efficacy and prognosis of endodontic treatment. This review enumerates the most widely used antimicrobial agents, their mechanism of action and their potential use in reducing the microbial load.

  2. Direct oxide reducing method

    International Nuclear Information System (INIS)

    Tokiwai, Moriyasu.

    1995-01-01

    Calcium oxides and magnetic oxides as wastes generated upon direct reduction are subjected to molten salt electrolysis, and reduced metallic calcium and magnesium are separated and recovered. Then calcium and magnesium are used recyclically as the reducing agent upon conducting direct oxide reduction. Even calcium oxides and magnesium oxides, which have high melting points and difficult to be melted usually, can be melted in molten salts of mixed fluorides or chlorides by molten-salt electrolysis. Oxides are decomposed by electrolysis, and oxygen is removed in the form of carbon monoxide, while the reduced metallic calcium and magnesium rise above the molten salts on the side of a cathode, and then separated. Since only carbon monoxide is generated as radioactive wastes upon molten salt electrolysis, the amount of radioactive wastes can be greatly reduced, and the amount of the reducing agent used can also be decreased remarkably. (N.H.)

  3. Development of organic MRI contrast agents

    International Nuclear Information System (INIS)

    Hayashi, Hiroyuki; Sato, Yuichiro; Karasawa, Satoru; Koga, Noboru

    2008-01-01

    Described are trends of the development in the title since those agents with target properties are awaited for specific organ and regional MRI. The contrast agents alter the relaxation time of water proton to yield the enhanced contrast between organs and tissues with different water volumes. Nowadays Gd-complexes and nano-particle of superparamagnetic iron oxide (Fe(III)) are widely used for enhancing in clinic. Among organic compounds with paramagnetic spin, those possessing nitroxide radical like TEMPO- and PROXYL-radicals have been subject to development by their derivatization. High spin molecules conceivably affect the relaxivity, which, however, is found smaller per spin of synthesized triplet complexes than doublet ones. This has lead to basic approach for molecules restricting water movement due to their hydrogen bond like DNA as a model, for introducing many radicals in high molecular weight compounds, and their polymer, as one of which authors have developed a derivative of hyperbranched polymer (HPS)-TEMPO having the similar relaxivity to gadolinium-diethylenetiamine pentaacetid acid (Gd-DTPA) (R.T.)

  4. UV disinfection and flocculation-chlorination sachets to reduce hepatitis E virus in drinking water.

    Science.gov (United States)

    Guerrero-Latorre, Laura; Gonzales-Gustavson, Eloy; Hundesa, Ayalkibet; Sommer, Regina; Rosina, Girones

    2016-07-01

    Hepatitis E Virus (HEV) is a major cause of waterborne outbreaks in areas with poor sanitation. As safe water supplies are the keystone for preventing HEV outbreaks, data on the efficacy of disinfection treatments are urgently needed. Here, we evaluated the ability of UV radiation and flocculation-chlorination sachets (FCSs) to reduce HEV in water matrices. The HEV-p6-kernow strain was replicated in the HepG2/C3A cell line, and we quantified genome number using qRT-PCR and infectivity using an immunofluorescence assay (IFA). UV irradiation tests using low-pressure radiation showed inactivation kinetics for HEV of 99.99% with a UV fluence of 232J/m(2) (IC 95%, 195,02-269,18). Moreover, the FCSs preparations significantly reduced viral concentrations in both water matrices, although the inactivation results were under the baseline of reduction (4.5 LRV) proposed by WHO guidelines. Copyright © 2016 Elsevier GmbH. All rights reserved.

  5. The behaviour of a floating water bridge under reduced gravity conditions

    International Nuclear Information System (INIS)

    Fuchs, Elmar C; Agostinho, Luewton L F; Wexler, Adam; Wagterveld, R Martijn; Tuinstra, Jan; Woisetschlaeger, Jakob

    2011-01-01

    When high voltage is applied to pure water filled into two beakers close to each other, a connection forms spontaneously, giving the impression of a floating water bridge (Armstrong 1893 The Electrical Engineer pp 154-45, Uhlig W 2005 personal communication, Fuchs et al 2007 J. Phys. D: Appl. Phys. 40 6112-4, Fuchs et al 2008 J. Phys. D: Appl. Phys. 41 185502, Fuchs et al 2009 J. Phys. D: Appl. Phys. 42 065502, Fuchs et al 2010 J. Phys. D: Appl. Phys. 43 105502, Woisetschlaeger et al 2010 Exp. Fluids 48 121-31, Nishiumi and Honda 2009 Res. Lett. Phys. Chem. 2009 371650). This phenomenon is of special interest, since it comprises a number of phenomena currently tackled in modern water science. In this work, the behaviour of this phenomenon under reduced gravity conditions during a parabolic flight is presented by the means of high speed imaging with fringe projection. An analysis of the behaviour is presented and compared with theoretical considerations.

  6. The behaviour of a floating water bridge under reduced gravity conditions

    Energy Technology Data Exchange (ETDEWEB)

    Fuchs, Elmar C; Agostinho, Luewton L F; Wexler, Adam; Wagterveld, R Martijn; Tuinstra, Jan [Wetsus, Center of Excellence for Sustainable Water Technology, Agora 1, 8900 CC Leeuwarden (Netherlands); Woisetschlaeger, Jakob, E-mail: elmar.fuchs@wetsus.nl [Institute for Thermal Turbomachinery and Machine Dynamics, Graz University of Technology, Inffeldgasse 25A, Graz (Austria)

    2011-01-19

    When high voltage is applied to pure water filled into two beakers close to each other, a connection forms spontaneously, giving the impression of a floating water bridge (Armstrong 1893 The Electrical Engineer pp 154-45, Uhlig W 2005 personal communication, Fuchs et al 2007 J. Phys. D: Appl. Phys. 40 6112-4, Fuchs et al 2008 J. Phys. D: Appl. Phys. 41 185502, Fuchs et al 2009 J. Phys. D: Appl. Phys. 42 065502, Fuchs et al 2010 J. Phys. D: Appl. Phys. 43 105502, Woisetschlaeger et al 2010 Exp. Fluids 48 121-31, Nishiumi and Honda 2009 Res. Lett. Phys. Chem. 2009 371650). This phenomenon is of special interest, since it comprises a number of phenomena currently tackled in modern water science. In this work, the behaviour of this phenomenon under reduced gravity conditions during a parabolic flight is presented by the means of high speed imaging with fringe projection. An analysis of the behaviour is presented and compared with theoretical considerations.

  7. The behaviour of a floating water bridge under reduced gravity conditions

    Science.gov (United States)

    Fuchs, Elmar C.; Agostinho, Luewton L. F.; Wexler, Adam; Wagterveld, R. Martijn; Tuinstra, Jan; Woisetschläger, Jakob

    2011-01-01

    When high voltage is applied to pure water filled into two beakers close to each other, a connection forms spontaneously, giving the impression of a floating water bridge (Armstrong 1893 The Electrical Engineer pp 154-45, Uhlig W 2005 personal communication, Fuchs et al 2007 J. Phys. D: Appl. Phys. 40 6112-4, Fuchs et al 2008 J. Phys. D: Appl. Phys. 41 185502, Fuchs et al 2009 J. Phys. D: Appl. Phys. 42 065502, Fuchs et al 2010 J. Phys. D: Appl. Phys. 43 105502, Woisetschläger et al 2010 Exp. Fluids 48 121-31, Nishiumi and Honda 2009 Res. Lett. Phys. Chem. 2009 371650). This phenomenon is of special interest, since it comprises a number of phenomena currently tackled in modern water science. In this work, the behaviour of this phenomenon under reduced gravity conditions during a parabolic flight is presented by the means of high speed imaging with fringe projection. An analysis of the behaviour is presented and compared with theoretical considerations.

  8. DEFICIT IRRIGATION TECHNIQUE FOR REDUCING WATER USE OF TOMATO UNDER POLYTUNNEL CONDITIONS

    Directory of Open Access Journals (Sweden)

    Sladjana SAVIC

    2012-01-01

    Full Text Available The aim of paper was to asses the use of regulated deficit irrigation (RDI for production of two tomato cultivars (Cedrico and Abellus in polytunnels in Serbia. RDI plants received 60% of the water that was applied to FI plants and significant saving of water for irrigation and increased in irrigation water use efficiency (IWUE were achieved. Yield data for Cedrico cultivar showed no differences between RDI and FI, while due to the bigger sensitivity to drought, yield of Abellus was reduced under RDI. In general, fruit quality (soluble solids, titrable acidity was sustained or improved in both cultivars under RDI. Economic analyses showed that due to the current low prices of water and electricity in Serbia, the profit increase of Cedrico, similarly to the previously trialed cultivar Amati, was not high under RDI comparing to FI. Reduction of yield and consequent profit for Abellus, indicated that for future commercial growing of tomato under RDI should be used drought resistant cultivars.

  9. Mechanisms of Resilience in Common-pool Resource Management Systems: an Agent-based Model of Water Use in a River Basin

    Directory of Open Access Journals (Sweden)

    Maja Schlüter

    2007-12-01

    Full Text Available The concept of resilience is widely promoted as a promising notion to guide new approaches to ecosystem and resource management that try to enhance a system's capacity to cope with change. A variety of mechanisms of resilience specific for different systems have been proposed. In the context of resource management those include but are not limited to the diversity of response options and flexibility of the social system to adaptively respond to changes on an adequate scale. However, implementation of resilience-based management in specific real-world systems has often proven difficult because of a limited understanding of suitable interventions and their impact on the resilience of the coupled social-ecological system. We propose an agent-based modeling approach to explore system characteristics and mechanisms of resilience in a complex resource management system, based on a case study of water use in the Amudarya River, which is a semiarid river basin. Water resources in its delta are used to sustain irrigated agriculture as well as aquatic ecosystems that provide fish and other ecosystem services. The three subsystems of the social-ecological system, i.e., the social system, the irrigation system, and an aquatic ecosystem, are linked by resource flows and the allocation decision making of actors on different levels. Simulation experiments are carried out to compare the resilience of different institutional settings of water management to changes in the variability and uncertainty of water availability. The aim is to investigate the influence of (1 the organizational structure of water management, (2 information on water availability, and (3 the diversity of water uses on the resilience of the system to short and long-term water scarcity. In this paper, the model concept and first simulation results are presented. As a first illustration of the approach the performances of a centralized and a decentralized regime are compared under different

  10. Environmental assessment for the natural fluctuation of water level in Par Pond and reduced water flow in Steel Creek below L-Lake at the Savannah River Site

    International Nuclear Information System (INIS)

    1995-08-01

    The Savannah River Operations Office Strategic Plan directs Savannah River Site (SRS) to find ways to reduce operating costs, and to determine what site infrastructure must be maintained and what infrastructure is surplus. Because of the mission change, L-Lake, Par Pond, and the river water system are no longer needed to support current missions and therefore provide an opportunity for operating cost reduction. If SRS determines that L-Lake, Par Pond, and the river water system are no longer needed to support future missions and are considered surplus, appropriate NEPA documentation will be prepared. The purpose of the proposed action in this Environmental Assessment is to begin an examination of the need for the Site's river water system by (1) developing data needed to evaluate the potential environmental impacts of further reducing or eliminating the flow demands from the Site's river water system and; (2) evaluating the potential of reducing operating costs by allowing the water level in Par Pond to fluctuate naturally through reduced pumping. This action also includes reducing the current flow rates from L-Lake to Steel Creek to natural stream flows while maintaining full pool. The recently approved Par Pond CERCLA Interim Action Proposed Plan (IAPP) committed to evaluate in a NEPA document the environmental consequences of this proposed action. This document evaluated the remediation of human health and ecological risks associated with the three year drawdown of Par Pond. Should any of the parameters sampled in the reservoir and streams (e.g., water quality, biota, etc.) exceed established threshold levels during the implementation of the proposed action, water would again be pumped into the reservoir to minimize any impacts by bringing the water level back to an appropriate level about 58.2 m (195 ft)

  11. Environmental assessment for the natural fluctuation of water level in Par Pond and reduced water flow in Steel Creek below L-Lake at the Savannah River Site

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-08-01

    The Savannah River Operations Office Strategic Plan directs Savannah River Site (SRS) to find ways to reduce operating costs, and to determine what site infrastructure must be maintained and what infrastructure is surplus. Because of the mission change, L-Lake, Par Pond, and the river water system are no longer needed to support current missions and therefore provide an opportunity for operating cost reduction. If SRS determines that L-Lake, Par Pond, and the river water system are no longer needed to support future missions and are considered surplus, appropriate NEPA documentation will be prepared. The purpose of the proposed action in this Environmental Assessment is to begin an examination of the need for the Site`s river water system by (1) developing data needed to evaluate the potential environmental impacts of further reducing or eliminating the flow demands from the Site`s river water system and; (2) evaluating the potential of reducing operating costs by allowing the water level in Par Pond to fluctuate naturally through reduced pumping. This action also includes reducing the current flow rates from L-Lake to Steel Creek to natural stream flows while maintaining full pool. The recently approved Par Pond CERCLA Interim Action Proposed Plan (IAPP) committed to evaluate in a NEPA document the environmental consequences of this proposed action. This document evaluated the remediation of human health and ecological risks associated with the three year drawdown of Par Pond. Should any of the parameters sampled in the reservoir and streams (e.g., water quality, biota, etc.) exceed established threshold levels during the implementation of the proposed action, water would again be pumped into the reservoir to minimize any impacts by bringing the water level back to an appropriate level about 58.2 m (195 ft).

  12. Control Strategies to Reduce the Energy Consumption of Central Domestic Hot Water Systems

    Energy Technology Data Exchange (ETDEWEB)

    Dentz, Jordan [The Levy Partnership, Inc., New York, NY (United States). Advanced Residential Integrated Energy Solutions; Ansanelli, Eric [The Levy Partnership, Inc., New York, NY (United States). Advanced Residential Integrated Energy Solutions; Henderson, Hugh [The Levy Partnership, Inc., New York, NY (United States). Advanced Residential Integrated Energy Solutions; Varshney, Kapil [The Levy Partnership, Inc., New York, NY (United States). Advanced Residential Integrated Energy Solutions

    2016-06-23

    Domestic hot water (DHW) heating is the second largest energy end use in U.S. buildings, exceeded only by space conditioning. Recirculation systems consisting of a pump and piping loop(s) are commonly used in multifamily buildings to reduce wait time for hot water at faucets; however, constant pumping increases energy consumption by exposing supply and return line piping to continuous heat loss, even during periods when there is no demand for hot water. In this study, ARIES installed and tested two types of recirculation controls in a pair of buildings in order to evaluate their energy savings potential. Demand control, temperature modulation controls, and the simultaneous operation of both were compared to the baseline case of constant recirculation. Additionally, interactive effects between DHW control fuel reductions and space conditioning (heating and cooling) were estimated in order to make more realistic predictions of the payback and financial viability of retrofitting DHW systems with these controls. Results showed that DHW fuel consumption reduced by 7% after implementing the demand control technique, 2% after implementing temperature modulation, and 15% after implementing demand control and temperature modulation techniques simultaneously; recirculation pump runtime was reduced to 14 minutes or less per day. With space heating and cooling interactions included, the estimated annual cost savings were 8%, 1%, and 14% for the respective control techniques. Possible complications in the installation, commissioning and operation of the controls were identified and solutions offered.

  13. Control Strategies to Reduce the Energy Consumption of Central Domestic Hot Water Systems

    Energy Technology Data Exchange (ETDEWEB)

    Dentz, Jordan; Ansanelli, Eric; Henderson, Hugh; Varshney, Kapil

    2016-06-03

    Domestic hot water (DHW) heating is the second largest energy end use in U.S. buildings, exceeded only by space conditioning. Recirculation systems consisting of a pump and piping loop(s) are commonly used in multifamily buildings to reduce wait time for hot water at faucets; however, constant pumping increases energy consumption by exposing supply and return line piping to continuous heat loss, even during periods when there is no demand for hot water. In this study, ARIES installed and tested two types of recirculation controls in a pair of buildings in order to evaluate their energy savings potential. Demand control, temperature modulation controls, and the simultaneous operation of both were compared to the baseline case of constant recirculation. Additionally, interactive effects between DHW control fuel reductions and space conditioning (heating and cooling) were estimated in order to make more realistic predictions of the payback and financial viability of retrofitting DHW systems with these controls. Results showed that DHW fuel consumption reduced by 7% after implementing the demand control technique, 2% after implementing temperature modulation, and 15% after implementing demand control and temperature modulation techniques simultaneously; recirculation pump runtime was reduced to 14 minutes or less per day. With space heating and cooling interactions included, the estimated annual cost savings were 8%, 1%, and 14% for the respective control techniques. Possible complications in the installation, commissioning and operation of the controls were identified and solutions offered.

  14. Competition-Induced Reductions in Soil Water Availability Reduced Pine Root Extension Rates

    Science.gov (United States)

    K.H. Ludovici; L.A. Morris

    1997-01-01

    The relationship between soil water availability, root extension, and shoot growth of loblolly pine seedlings (Pinus taeda L.) was evaluated in a rhizotron sand mixture in the absence and presence of crabgrass (Digitaria spp.) competition. Heights and diameters of seedlings grown with crabgrass were reduced 33 and SO%, respectively, compared with...

  15. Open Software Tools Applied to Jordan's National Multi-Agent Water Management Model

    Science.gov (United States)

    Knox, Stephen; Meier, Philipp; Harou, Julien; Yoon, Jim; Selby, Philip; Lachaut, Thibaut; Klassert, Christian; Avisse, Nicolas; Khadem, Majed; Tilmant, Amaury; Gorelick, Steven

    2016-04-01

    Jordan is the fourth most water scarce country in the world, where demand exceeds supply in a politically and demographically unstable context. The Jordan Water Project (JWP) aims to perform policy evaluation by modelling the hydrology, economics, and governance of Jordan's water resource system. The multidisciplinary nature of the project requires a modelling software system capable of integrating submodels from multiple disciplines into a single decision making process and communicating results to stakeholders. This requires a tool for building an integrated model and a system where diverse data sets can be managed and visualised. The integrated Jordan model is built using Pynsim, an open-source multi-agent simulation framework implemented in Python. Pynsim operates on network structures of nodes and links and supports institutional hierarchies, where an institution represents a grouping of nodes, links or other institutions. At each time step, code within each node, link and institution can executed independently, allowing for their fully autonomous behaviour. Additionally, engines (sub-models) perform actions over the entire network or on a subset of the network, such as taking a decision on a set of nodes. Pynsim is modular in design, allowing distinct modules to be modified easily without affecting others. Data management and visualisation is performed using Hydra (www.hydraplatform.org), an open software platform allowing users to manage network structure and data. The Hydra data manager connects to Pynsim, providing necessary input parameters for the integrated model. By providing a high-level portal to the model, Hydra removes a barrier between the users of the model (researchers, stakeholders, planners etc) and the model itself, allowing them to manage data, run the model and visualise results all through a single user interface. Pynsim's ability to represent institutional hierarchies, inter-network communication and the separation of node, link and

  16. Completely green synthesis of dextrose reduced silver nanoparticles, its antimicrobial and sensing properties.

    Science.gov (United States)

    Mohan, Sneha; Oluwafemi, Oluwatobi S; George, Soney C; Jayachandran, V P; Lewu, Francis B; Songca, Sandile P; Kalarikkal, Nandakumar; Thomas, Sabu

    2014-06-15

    We herein report the green synthesis of highly monodispersed, water soluble, stable and smaller sized dextrose reduced gelatin capped-silver nanoparticles (Ag-NPs) via an eco-friendly, completely green method. The synthesis involves the use of silver nitrate, gelatin, dextrose and water as the silver precursor, stabilizing agent, reducing agent and solvent respectively. By varying the reaction time, the temporal evolution of the growth, optical, antimicrobial and sensing properties of the as-synthesised Ag-NPs were investigated. The nanoparticles were characterized using UV-vis absorption spectroscopy, Fourier transform infra-red spectroscopy (FT-IR), X-ray diffraction (XRD), transmission electron microscopy (TEM) and high resolution transmission electron microscopy (HR-TEM). The absorption maxima of the as-synthesized materials at different reaction time showed characteristic silver surface plasmon resonance (SPR) peak. The as-synthesised Ag-NPs show better antibacterial efficacy than the antibiotics; ciproflaxin and imipenem against Pseudomonas aeruginosa with minimum inhibition concentration (MIC) of 6 μg/mL, and better efficacy than imipenem against Escherichia coli with MIC of 10 μg/mL. The minimum bactericidal concentration (MBC) of the as-synthesised Ag-NPs is 12.5 μg/mL. The sensitivity of the dextrose reduced gelatin-capped Ag-NPs towards hydrogen peroxide indicated that the sensor has a very good sensitivity and a linear response over wide concentration range of 10(-1)-10(-6)M H2O2. Copyright © 2014 Elsevier Ltd. All rights reserved.

  17. Toward the Prediction of Water Exchange Rates in Magnetic Resonance Imaging Contrast Agents: A Density Functional Theory Study.

    Science.gov (United States)

    Regueiro-Figueroa, Martín; Platas-Iglesias, Carlos

    2015-06-18

    We present a theoretical investigation of Gd-Owater bonds in different complexes relevant as contrast agents in magnetic resonance imaging (MRI). The analysis of the Ln-Owater distances, electron density (ρBCP), and electron localization function (ELF) at the bond critical points of [Ln(DOTA)(H2O)](-) and [Ln(DTPA-BMA)(H2O)] indicates that the strength of the Ln-Owater bonds follows the order DTPA-BMA > DOTA (M isomer) > DOTA (m isomer). The ELF values decrease along the 4f period as the Ln-Owater bonds get shorter, in line with the labile capping bond phenomenon. Extension of these calculations to other Gd(3+) complexes allowed us to correlate the experimentally observed water exchange rates and the calculated ρBCP and ELF values. The water exchange reaction becomes faster as the Gd-Owater bonds are weakened, which is reflected in longer bond distances and lower values of ρBCP and ELF. DKH2 calculations show that the two coordinated water molecules may also have significantly different (17)O hyperfine coupling constants (HFCCs).

  18. Progress in design study on reduced-moderation water reactors

    Energy Technology Data Exchange (ETDEWEB)

    Okubo, Tsutomu; Kugo, Teruhiko; Shimada, Shoichiro; Shirakawa, Toshihisa; Iwamura, Takamichi [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment; Takeda, Renzo [Hitachi Ltd., Tokyo (Japan); Yokoyama, Tsugio [Toshiba Corp., Kawasaki, Kanagawa (Japan); Hibi, Koki [Mitsubishi Heavy Industries Ltd., Tokyo (Japan); Wada, Shigeyuki [Japan Atomic Power Co., Tokyo (Japan)

    2000-06-01

    The Reduced-Moderation Water Reactor (RMWR) is a next generation water-cooled reactor which aims at effective utilization of uranium resource, high burn-up and long operation cycle, and plutonium multi-recycle. These characteristics can be achieved by the high conversion ratio from {sup 238}U to {sup 239}Pu resulted from the higher neutron energy spectrum in comparison to conventional light water reactors. Considering the extension of LWR utilization, Japan Atomic Energy Research Institute (JAERI) started the research on it in 1997 and then started a collaboration in the conceptual design study with the Japan Atomic Power Company (JAPC) in 1998, under technical cooperation with three Japanese reactor vendors. In the core design study of the RMWR, negative void reactivity coefficient is required from a viewpoint of safety as well as establishing hard neutron spectrum. In order to achieve the above trade-off characteristics simultaneously, several basic core design ideas should be combined, such as a tight-lattice fuel assembly, a flat core, a blanket effect, a streaming effect and so on. Up to now, five core concepts have been created for the RMWR as follows: a high conversion BWR type core with high void fraction and super-flat core, a long operation cycle BWR type core using void tube assembly, a high conversion BWR type core without blankets, a high conversion PWR type core using heavy water as a coolant, and a PWR type core for plutonium multi-recycle using seed-blanket type fuel assemblies. Detailed feasibility studies for the RMWR have been continued on core design study. The present report summarizes the recent progress in the design study for the RMWR. (author)

  19. Optimising the design of paramagnetic MRI contrast agents: influence of backbone substitution on the water exchange rate of Gd-DTPA derivatives.

    Science.gov (United States)

    Laurent, S; Botteman, F; Vander Elst, L; Muller, R N

    2004-04-01

    Among other factors influencing the residence time of the coordinated water (tauM) of paramagnetic contrast agents, the steric hindrance around the gadolinium ion seems to play a beneficial role. Such a crowding can be achieved by substituting the Gd-DTPA backbone on the C4 position. Several Gd-DTPA complexes carrying diverse groups at this position have thus been synthesised and characterised: GdS-C4-Me-DTPA, GdS-C4-n-Bu-DTPA, GdS-C4-iBu-DTPA, GdS-C4-iPr-DTPA, and Gd-C4-diMe-DTPA. TauM has been measured through the evolution of the water oxygen-17 transverse relaxation rate as a function of the temperature. The data show a reduction of tauM of GdS-C4-Me-DTPA, GdS-C4-n-Bu-DTPA, GdS-C4-iBu-DTPA, GdS-C4-iPr-DTPA, and Gd-C4-diMe-DTPA (tauM310 = 91,82, 108,98, and 57 ns respectively, as compared to Gd-DTPA (tauM310 = 143 ns)). At 310 K, the nuclear magnetic dispersion relaxation profiles of water protons are very similar for the five complexes which present longitudinal relaxivities slightly higher than those of Gd-DTPA. Regarding zinc transmetallation, C4-monosubstituted derivatives are more stable than Gd-DTPA. These results confirm that a judicious substitution of the DTPA skeleton allows for an acceleration of the coordinated water exchange rate. This observation can be useful for the design of vectorised contrast agents for molecular imaging. Copyright 2004 ESMRMB

  20. Self-curing concrete with different self-curing agents

    Science.gov (United States)

    Gopala krishna sastry, K. V. S.; manoj kumar, Putturu

    2018-03-01

    Concrete is recognised as a versatile construction material globally. Properties of concrete depend upon, to a greater extent, the hydration of cement and microstructure of hydrated cement. Congenial atmosphere would aid the hydration of cement and hence curing of concrete becomes essential, till a major portion of the hydration process is completed. But in areas of water inadequacy and concreting works at considerable heights, curing is problematic. Self-Curing or Internal Curing technique overcomes these problems. It supplies redundant moisture, for more than sufficient hydration of cement and diminish self-desiccation. Self-Curing agents substantially help in the conservation of water in concrete, by bringing down the evaporation during the hydration of Concrete. The present study focuses on the impact of self-curing agents such as Poly Ethylene Glycol (PEG), Poly Vinyl Alcohol (PVA) and Super Absorbent Polymer (SAP) on the concrete mix of M25 grade (reference mix). The effect of these agents on strength properties of Concrete such as compressive strength, split tensile strength and flexural strength was observed on a comparative basis which revealed that PEG 4000 was the most effective among all the agents.

  1. Development of an Agent Based Model to Estimate and Reduce Time to Restoration of Storm Induced Power Outages

    Science.gov (United States)

    Walsh, T.; Layton, T.; Mellor, J. E.

    2017-12-01

    Storm damage to the electric grid impacts 23 million electric utility customers and costs US consumers $119 billion annually. Current restoration techniques rely on the past experiences of emergency managers. There are few analytical simulation and prediction tools available for utility managers to optimize storm recovery and decrease consumer cost, lost revenue and restoration time. We developed an agent based model (ABM) for storm recovery in Connecticut. An ABM is a computer modeling technique comprised of agents who are given certain behavioral rules and operate in a given environment. It allows the user to simulate complex systems by varying user-defined parameters to study emergent, unpredicted behavior. The ABM incorporates the road network and electric utility grid for the state, is validated using actual storm event recoveries and utilizes the Dijkstra routing algorithm to determine the best path for repair crews to travel between outages. The ABM has benefits for both researchers and utility managers. It can simulate complex system dynamics, rank variable importance, find tipping points that could significantly reduce restoration time or costs and test a broad range of scenarios. It is a modular, scalable and adaptable technique that can simulate scenarios in silico to inform emergency managers before and during storm events to optimize restoration strategies and better manage expectations of when power will be restored. Results indicate that total restoration time is strongly dependent on the number of crews. However, there is a threshold whereby more crews will not decrease the restoration time, which depends on the total number of outages. The addition of outside crews is more beneficial for storms with a higher number of outages. The time to restoration increases linearly with increasing repair time, while the travel speed has little overall effect on total restoration time. Crews traveling to the nearest outage reduces the total restoration time

  2. Using microbial desalination cells to reduce water salinity prior to reverse osmosis

    KAUST Repository

    Mehanna, Maha; Saito, Tomonori; Yan, Jingling; Hickner, Michael; Cao, Xiaoxin; Huang, Xia; Logan, Bruce E.

    2010-01-01

    type of air-cathode MDC containing three equally sized chambers. A single cycle of operation using a 1 g L -1 acetate solution reduced the conductivity of salt water (5 g L-1 NaCl) by 43 ± 6%, and produced a maximum power density of 480 mW m-2 with a

  3. Prevalence of acid-reducing agents (ARA) in cancer populations and ARA drug-drug interaction potential for molecular targeted agents in clinical development.

    Science.gov (United States)

    Smelick, Gillian S; Heffron, Timothy P; Chu, Laura; Dean, Brian; West, David A; Duvall, Scott L; Lum, Bert L; Budha, Nageshwar; Holden, Scott N; Benet, Leslie Z; Frymoyer, Adam; Dresser, Mark J; Ware, Joseph A

    2013-11-04

    Acid-reducing agents (ARAs) are the most commonly prescribed medications in North America and Western Europe. There are currently no data describing the prevalence of their use among cancer patients. However, this is a paramount question due to the potential for significant drug-drug interactions (DDIs) between ARAs, most commonly proton pump inhibitors (PPIs), and orally administered cancer therapeutics that display pH-dependent solubility, which may lead to decreased drug absorption and decreased therapeutic benefit. Of recently approved orally administered cancer therapeutics, >50% are characterized as having pH-dependent solubility, but there are currently no data describing the potential for this ARA-DDI liability among targeted agents currently in clinical development. The objectives of this study were to (1) determine the prevalence of ARA use among different cancer populations and (2) investigate the prevalence of orally administered cancer therapeutics currently in development that may be liable for an ARA-DDI. To address the question of ARA use among cancer patients, a retrospective cross-sectional analysis was performed using two large healthcare databases: Thomson Reuters MarketScan (N = 1,776,443) and the U.S. Department of Veterans Affairs (VA, N = 1,171,833). Among all cancer patients, the total prevalence proportion of ARA use (no. of cancer patients receiving an ARA/total no. of cancer patients) was 20% and 33% for the MarketScan and VA databases, respectively. PPIs were the most commonly prescribed agent, comprising 79% and 65% of all cancer patients receiving a prescription for an ARA (no. of cancer patients receiving a PPI /no. of cancer patients receiving an ARA) for the MarketScan and VA databases, respectively. To estimate the ARA-DDI liability of orally administered molecular targeted cancer therapeutics currently in development, two publicly available databases, (1) Kinase SARfari and (2) canSAR, were examined. For those orally administered

  4. TTFields alone and in combination with chemotherapeutic agents effectively reduce the viability of MDR cell sub-lines that over-express ABC transporters

    International Nuclear Information System (INIS)

    Schneiderman, Rosa S; Shmueli, Esther; Kirson, Eilon D; Palti, Yoram

    2010-01-01

    Exposure of cancer cells to chemotherapeutic agents may result in reduced sensitivity to structurally unrelated agents, a phenomenon known as multidrug resistance, MDR. The purpose of this study is to investigate cell growth inhibition of wild type and the corresponding MDR cells by Tumor Treating Fields - TTFields, a new cancer treatment modality that is free of systemic toxicity. The TTFields were applied alone and in combination with paclitaxel and doxorubicin. Three pairs of wild type/MDR cell lines, having resistivity resulting from over-expression of ABC transporters, were studied: a clonal derivative (C11) of parental Chinese hamster ovary AA8 cells and their emetine-resistant sub-line Emt R1 ; human breast cancer cells MCF-7 and their mitoxantrone-resistant sub lines MCF-7/Mx and human breast cancer cells MDA-MB-231 and their doxorubicin resistant MDA-MB-231/Dox cells. TTFields were applied for 72 hours with and without the chemotherapeutic agents. The numbers of viable cells in the treated cultures and the untreated control groups were determined using the XTT assay. Student t-test was applied to asses the significance of the differences between results obtained for each of the three cell pairs. TTFields caused a similar reduction in the number of viable cells of wild type and MDR cells. Treatments by TTFields/drug combinations resulted in a similar increased reduction in cell survival of wild type and MDR cells. TTFields had no effect on intracellular doxorubicin accumulation in both wild type and MDR cells. The results indicate that TTFields alone and in combination with paclitaxel and doxorubicin effectively reduce the viability of both wild type and MDR cell sub-lines and thus can potentially be used as an effective treatment of drug resistant tumors

  5. Reduced Susceptibility to Rifampicin and Resistance to Multiple Antimicrobial Agents among Brucella abortus Isolates from Cattle in Brazil.

    Science.gov (United States)

    Barbosa Pauletti, Rebeca; Reinato Stynen, Ana Paula; Pinto da Silva Mol, Juliana; Seles Dorneles, Elaine Maria; Alves, Telma Maria; de Sousa Moura Souto, Monalisa; Minharro, Silvia; Heinemann, Marcos Bryan; Lage, Andrey Pereira

    2015-01-01

    This study aimed to determine the susceptibility profile of Brazilian Brucella abortus isolates from cattle to eight antimicrobial agents that are recommended for the treatment of human brucellosis and to correlate the susceptibility patterns with origin, biotype and MLVA16-genotype of the strains. Screening of 147 B. abortus strains showed 100% sensitivity to doxycycline and ofloxacin, one (0.68%) strain resistant to ciprofloxacin, two strains (1.36%) resistant to streptomycin, two strains (1.36%) resistant to trimethoprim-sulfamethoxazole and five strains (3.40%) resistant to gentamicin. For rifampicin, three strains (2.04%) were resistant and 54 strains (36.73%) showed reduced sensitivity. Two strains were considered multidrug resistant. In conclusion, the majority of B. abortus strains isolated from cattle in Brazil were sensitive to the antimicrobials commonly used for the treatment of human brucellosis; however, a considerable proportion of strains showed reduced susceptibility to rifampicin and two strains were considered multidrug resistant. Moreover, there was no correlation among the drug susceptibility pattern, origin, biotype and MLVA16-genotypes of these strains.

  6. Fluorescent discrimination between traces of chemical warfare agents and their mimics.

    Science.gov (United States)

    Díaz de Greñu, Borja; Moreno, Daniel; Torroba, Tomás; Berg, Alexander; Gunnars, Johan; Nilsson, Tobias; Nyman, Rasmus; Persson, Milton; Pettersson, Johannes; Eklind, Ida; Wästerby, Pär

    2014-03-19

    An array of fluorogenic probes is able to discriminate between nerve agents, sarin, soman, tabun, VX and their mimics, in water or organic solvent, by qualitative fluorescence patterns and quantitative multivariate analysis, thus making the system suitable for the in-the-field detection of traces of chemical warfare agents as well as to differentiate between the real nerve agents and other related compounds.

  7. Environmental response nanosilica for reducing the pressure of water injection in ultra-low permeability reservoirs

    Science.gov (United States)

    Liu, Peisong; Niu, Liyong; Li, Xiaohong; Zhang, Zhijun

    2017-12-01

    The super-hydrophobic silica nanoparticles are applied to alter the wettability of rock surface from water-wet to oil-wet. The aim of this is to reduce injection pressure so as to enhance water injection efficiency in low permeability reservoirs. Therefore, a new type of environmentally responsive nanosilica (denote as ERS) is modified with organic compound containing hydrophobic groups and "pinning" groups by covalent bond and then covered with a layer of hydrophilic organic compound by chemical adsorption to achieve excellent water dispersibility. Resultant ERS is homogeneously dispersed in water with a size of about 4-8 nm like a micro-emulsion system and can be easily injected into the macro or nano channels of ultra-low permeability reservoirs. The hydrophobic nanosilica core can be released from the aqueous delivery system owing to its strong dependence on the environmental variation from normal condition to injection wells (such as pH and salinity). Then the exposed silica nanoparticles form a thin layer on the surface of narrow pore throat, leading to the wettability from water-wet to oil-wet. More importantly, the two rock cores with different permeability were surface treated with ERS dispersion with a concentration of 2 g/L, exhibit great reduce of water injection pressure by 57.4 and 39.6%, respectively, which shows great potential for exploitation of crude oil from ultra-low permeability reservoirs during water flooding. [Figure not available: see fulltext.

  8. Further Screening of Entomopathogenic Fungi and Nematodes as Control Agents for Drosophila suzukii

    Directory of Open Access Journals (Sweden)

    Andrew G. S. Cuthbertson

    2016-06-01

    Full Text Available Drosophila suzukii populations remain low in the UK. To date, there have been no reports of widespread damage. Previous research demonstrated that various species of entomopathogenic fungi and nematodes could potentially suppress D. suzukii population development under laboratory trials. However, none of the given species was concluded to be specifically efficient in suppressing D. suzukii. Therefore, there is a need to screen further species to determine their efficacy. The following entomopathogenic agents were evaluated for their potential to act as control agents for D. suzukii: Metarhizium anisopliae; Isaria fumosorosea; a non-commercial coded fungal product (Coded B; Steinernema feltiae, S. carpocapsae, S. kraussei and Heterorhabditis bacteriophora. The fungi were screened for efficacy against the fly on fruit while the nematodes were evaluated for the potential to be applied as soil drenches targeting larvae and pupal life-stages. All three fungi species screened reduced D. suzukii populations developing from infested berries. Isaria fumosorosea significantly (p < 0.001 reduced population development of D. suzukii from infested berries. All nematodes significantly reduced adult emergence from pupal cases compared to the water control. Larvae proved more susceptible to nematode infection. Heterorhabditis bacteriophora proved the best from the four nematodes investigated; readily emerging from punctured larvae and causing 95% mortality. The potential of the entomopathogens to suppress D. suzukii populations is discussed.

  9. [Decontamination of chemical and biological warfare agents].

    Science.gov (United States)

    Seto, Yasuo

    2009-01-01

    Chemical and biological warfare agents (CBWA's) are diverse in nature; volatile acute low-molecular-weight toxic compounds, chemical warfare agents (CWA's, gaseous choking and blood agents, volatile nerve gases and blister agents, nonvolatile vomit agents and lacrymators), biological toxins (nonvolatile low-molecular-weight toxins, proteinous toxins) and microbes (bacteria, viruses, rickettsiae). In the consequence management against chemical and biological terrorism, speedy decontamination of victims, facilities and equipment is required for the minimization of the damage. In the present situation, washing victims and contaminated materials with large volumes of water is the basic way, and additionally hypochlorite salt solution is used for decomposition of CWA's. However, it still remains unsolved how to dispose large volumes of waste water, and the decontamination reagents have serious limitation of high toxicity, despoiling nature against the environments, long finishing time and non-durability in effective decontamination. Namely, the existing decontamination system is not effective, nonspecifically affecting the surrounding non-target materials. Therefore, it is the urgent matter to build up the usable decontamination system surpassing the present technologies. The symposiast presents the on-going joint project of research and development of the novel decontamination system against CBWA's, in the purpose of realizing nontoxic, fast, specific, effective and economical terrorism on-site decontamination. The projects consists of (1) establishment of the decontamination evaluation methods and verification of the existing technologies and adaptation of bacterial organophosphorus hydrolase, (2) development of adsorptive elimination technologies using molecular recognition tools, and (4) development of deactivation technologies using photocatalysis.

  10. Agricultural implications of reduced water supplies in the Green and Upper Yellowstone River Basins

    Energy Technology Data Exchange (ETDEWEB)

    Lansford, R. R.; Roach, F.; Gollehon, N. R.; Creel, B. J.

    1982-02-01

    The growth of the energy sector in the energy-rich but water-restricted Western US has presented a potential conflict with the irrigated agricultural sector. This study measures the direct impacts on farm income and employment resulting from the transfer of water from agriculture to energy in two specific geographical areas - the Green and Upper Yellowstone River Basins. We used a linear programming model to evaluate the impacts of reduced water supplies. Through the use of regional multipliers, we expanded our analysis to include regional impacts. Volume I provides the major analysis of these impacts. Volume II provides further technical data.

  11. Calcification of the cold-water coral Lophelia pertusa, under ambient and reduced pH

    Directory of Open Access Journals (Sweden)

    J.-P. Gattuso

    2009-08-01

    Full Text Available The cold-water coral Lophelia pertusa is one of the few species able to build reef-like structures and a 3-dimensional coral framework in the deep oceans. Furthermore, deep cold-water coral bioherms may be among the first marine ecosystems to be affected by ocean acidification. Colonies of L. pertusa were collected during a cruise in 2006 to cold-water coral bioherms of the Mingulay reef complex (Hebrides, North Atlantic. Shortly after sample collection onboard these corals were labelled with calcium-45. The same experimental approach was used to assess calcification rates and how those changed due to reduced pH during a cruise to the Skagerrak (North Sea in 2007. The highest calcification rates were found in youngest polyps with up to 1% d−1 new skeletal growth and average rates of 0.11±0.02% d−1±S.E.. Lowering pH by 0.15 and 0.3 units relative to the ambient level resulted in calcification being reduced by 30 and 56%. Lower pH reduced calcification more in fast growing, young polyps (59% reduction than in older polyps (40% reduction. Thus skeletal growth of young and fast calcifying corallites suffered more from ocean acidification. Nevertheless, L. pertusa exhibited positive net calcification (as measured by 45Ca incorporation even at an aragonite saturation state (Ωa below 1.

  12. The Use of Water-filled Bags to Reduce the Effects of Explosives

    Science.gov (United States)

    1994-08-01

    of Water-filled Bags to Reduce the Effects of Explosives. 5a. CONTRACT NUMBER 5b. GRANT NUMBER 5c. PROGRAM ELEMENT NUMBER 6. AUTHOR(S) 5d. PROJECT...Heery inc (and designed at Edinburgh University by Matthew Rea) is already in operation not far from here in the Disneyland ’Typhoon Lagoon’ at Orlando

  13. Investigation of sewage sludge gasification with use of flue gas as a gasifying agent

    Directory of Open Access Journals (Sweden)

    Maj Izabella

    2017-01-01

    Full Text Available The paper presents results of investigation of low-temperature sewage sludge gasification with use of flue gas as a gasifying agent. Tests were conducted in a laboratory stand, equipped with a gasification reactor designed and constructed specifically for this purpose. During presented tests, gas mixture with a composition of typical flue gases was used as a gasifying agent. The measuring system ensures online measurements of syngas composition: CO, CO2, H2, CH4. As a result of gasification process a syngas with combustible components has been obtained. The aim of the research was to determine the usability of sewage sludge for indirect cofiring in power boilers with the use of flue gas from the boiler as a gasifying agent and recirculating the syngas to the boiler’s combustion chamber. Results of presented investigation will be used as a knowledge base for industrial-scale sewage sludge gasification process. Furthermore, toxicity of solid products of the process has been determined by the use of Microtox bioassay. Before tests, solid post-gasification residues have been ground to two particle size fractions and extracted into Milli-Q water. The response of test organisms (bioluminescent Aliivibrio fischeri bacteria in reference to a control sample (bacteria exposed to 2% NaCl solution was measured after 5 and 15 minutes of exposure. The obtained toxicity results proved that thermal treatment of sewage sludge by their gasification reduces their toxicity relative to water organisms.

  14. An experimental study on tissue reaction of various contrast agents on endometrium, tuber mucosa, and peritoneum

    International Nuclear Information System (INIS)

    Kim, Jae Seung; Kim, Seung Hyup; Park, In Ae; Park, Jae Hyung; Yoon, Dae Young; Yeon, Kyung Mo

    1994-01-01

    To compare the tissue reactions of various water-soluble and oil-based contrast agents on the endometrium, salpingeal mumosa, and peritoneum. Thirty-three rabbits were used for evaluating the histologic reactions of uterine endometrium, salpinx, and peritoneum. Hysterosalpingography(HSG) was underwent in these rabbits by used Lipiodol, Hexabrix, Rayvist. Ultravist-300, Ultravist-370, and normal saline. Pathologic results were obtained in each of the six groups from the uterine endometrium, salpingeal mucosa, and peritoneum without knowledge of the contrast agent used and time interval from HSG. Mild inflammations were observed in the endometrium, salpingeal mucosa, and peritoneum during the first week of HSG in all rabbits in which water-soluble contrast agents were used. Although there was no significant difference in the degree of inflammation among the groups using various contrast agents, the group with oil-based contrast agent(Lipiodol) showed delayed absorption of contrast agent in the peritoneum, frequent intravasation, fat granuloma, peritoneal adhesion, or uterine infarction. Our results suggest that water-soluble contrast agents can be used safely for HSG, but the use of oil-based contrast agent is questional in safety and should be avoid in patients with tubal obstruction, salpingitis, or endometritis

  15. Agricultural pathogen decontamination technology-reducing the threat of infectious agent spread.

    Energy Technology Data Exchange (ETDEWEB)

    Betty, Rita G.; Bieker, Jill Marie; Tucker, Mark David

    2005-10-01

    Outbreaks of infectious agricultural diseases, whether natural occurring or introduced intentionally, could have catastrophic impacts on the U.S. economy. Examples of such agricultural pathogens include foot and mouth disease (FMD), avian influenza (AI), citrus canker, wheat and soy rust, etc. Current approaches to mitigate the spread of agricultural pathogens include quarantine, development of vaccines for animal diseases, and development of pathogen resistant crop strains in the case of plant diseases. None of these approaches is rapid, and none address the potential persistence of the pathogen in the environment, which could lead to further spread of the agent and damage after quarantine is lifted. Pathogen spread in agricultural environments commonly occurs via transfer on agricultural equipment (transportation trailers, tractors, trucks, combines, etc.), having components made from a broad range of materials (galvanized and painted steel, rubber tires, glass and Plexiglas shields, etc), and under conditions of heavy organic load (mud, soil, feces, litter, etc). A key element of stemming the spread of an outbreak is to ensure complete inactivation of the pathogens in the agricultural environment and on the equipment used in those environments. Through the combination of enhanced agricultural pathogen decontamination chemistry and a validated inactivation verification methodology, important technologies for incorporation as components of a robust response capability will be enabled. Because of the potentially devastating economic impact that could result from the spread of infectious agricultural diseases, the proposed capability components will promote critical infrastructure protection and greater border and food supply security. We investigated and developed agricultural pathogen decontamination technologies to reduce the threat of infectious-agent spread, and thus enhance agricultural biosecurity. Specifically, enhanced detergency versions of the patented

  16. Diarrhea caused by circulating agents.

    Science.gov (United States)

    Fabian, Elisabeth; Kump, Patrizia; Krejs, Guenter J

    2012-09-01

    Circulating agents cause intestinal secretion or changes in motility with decreased intestinal transit time, resulting in secretory-type diarrhea. Secretory diarrhea as opposed to osmotic diarrhea is characterized by large-volume, watery stools, often more than 1 L per day; by persistence of diarrhea when patients fast; and by the fact that on analysis of stool-water, measured osmolarity is identical to that calculated from the electrolytes present. Although sodium plays the main role in water and electrolyte absorption, chloride is the major ion involved in secretion. Copyright © 2012 Elsevier Inc. All rights reserved.

  17. (Pyridine)(tetrahydroborato)zinc complex, (Zn(BH{sub 4}){sub 2}(py)), as a new stable, efficient and chemoselective reducing agent for reduction of carbonyl compounds

    Energy Technology Data Exchange (ETDEWEB)

    Zeynizadeh, Behzad; Faraji, Fariba [Urima Univ., Urima (Iran, Islamic Republic of)

    2003-04-01

    (Pyridine)(tetrahydroborato)zinc complex, (Zn(BH{sub 4}){sub 2}(py)), as a stable white solid, was prepared quantitatively by complexation of an equimolar amount of zinc tetrahydroborate and pyridine at room temperature. This reagent can easily reduce variety of carbonyl compounds such as aldehydes, ketones, acyloins, {alpha}-diketones and {alpha},{beta}-unsaturated carbonyl compounds to their corresponding alcohols in good to excellent yields. Reduction reactions were performed in ether or THF at room temperature or under reflux conditions. In addition, the chemoselective reduction of aldehydes over ketones was accomplished successfully with this reducing agent.

  18. method and container for production of diagnostic scanning agents

    International Nuclear Information System (INIS)

    Ruddock, C.F.

    1979-01-01

    The pertechnetate ion containing the technetium-99m isotope has limited applications in diagnostic scanning because it does not readily form complexes with materials which locate in specific parts of the body. Stannous salts have been widely used to reduce the pertechnetate to a form which readily complexes with materials. In the present invention, both a container and a more suitable metal reducing agent are discussed for transforming the technetium in pertechnetate for diagnostic scanning use. The vessel contains tin or a tin-containing alloy as a reducing agent for the pertechnetate and a complexant for the reduced technetium; all contents are sterile and dry. The present invention is advantageous over the stannous salts method since (1) problems of stannous salt instability during production, storage and after labelling are eliminated; (2) production procedures are simplified; (3) it is not essential to nitrogen purge vials before sterilisation; (4) it reduces toxicity; (5) the shelf life of diagnostic scanning kits may be dramatically improved; (6) the metal reducing agent may be sterilised by γ-irradiation without deteriorating; (7) the labelling technique can be performed over a wide pH range; and (8) the technique should be unaffected by technetium-99 in the technetium-99m. (U.K.)

  19. Technetium-99m labeled radiodiagnostic agents and method of preparation

    International Nuclear Information System (INIS)

    Molinski, V.J.; Wilczewski, J.A.

    1977-01-01

    A method of preparing improved technetium-99m labeled radiodiagnostic agents by reducing technetium-99m with stannous tartrate is described. Such radiodiagnostic agents are useful in scintigraphic examinations of the bone and lung

  20. An Agent-Based Model of Farmer Decision Making in Jordan

    Science.gov (United States)

    Selby, Philip; Medellin-Azuara, Josue; Harou, Julien; Klassert, Christian; Yoon, Jim

    2016-04-01

    We describe an agent based hydro-economic model of groundwater irrigated agriculture in the Jordan Highlands. The model employs a Multi-Agent-Simulation (MAS) framework and is designed to evaluate direct and indirect outcomes of climate change scenarios and policy interventions on farmer decision making, including annual land use, groundwater use for irrigation, and water sales to a water tanker market. Land use and water use decisions are simulated for groups of farms grouped by location and their behavioural and economic similarities. Decreasing groundwater levels, and the associated increase in pumping costs, are important drivers for change within Jordan'S agricultural sector. We describe how this is considered by coupling of agricultural and groundwater models. The agricultural production model employs Positive Mathematical Programming (PMP), a method for calibrating agricultural production functions to observed planted areas. PMP has successfully been used with disaggregate models for policy analysis. We adapt the PMP approach to allow explicit evaluation of the impact of pumping costs, groundwater purchase fees and a water tanker market. The work demonstrates the applicability of agent-based agricultural decision making assessment in the Jordan Highlands and its integration with agricultural model calibration methods. The proposed approach is designed and implemented with software such that it could be used to evaluate a variety of physical and human influences on decision making in agricultural water management.

  1. Water disinfection agents and disinfection by-products

    Science.gov (United States)

    Ilavský, J.; Barloková, D.; Kapusta, O.; Kunštek, M.

    2017-10-01

    The aim of this work is to describe factors of water quality change in the distribution network and legislative requirements in Slovakia for disinfectants and disinfection byproducts (DBPs). In the experimental part, the time dependence of the application of the chlorine dioxide and sodium hypochlorite on the formation of some by-products of disinfection for drinking water from WTP Hriňová is studied. We monitored trihalomethanes, free chlorine, chlorine dioxide and chlorites.

  2. Fullerene-reduced graphene oxide composites obtained by ultrashort laser ablation of fullerite in water

    Energy Technology Data Exchange (ETDEWEB)

    De Bonis, A., E-mail: angela.debonis@unibas.it [Dipartimento di Scienze, Università degli Studi della Basilicata, Viale dell’Ateneo Lucano, 10-85100, Potenza (Italy); Curcio, M. [Dipartimento di Scienze, Università degli Studi della Basilicata, Viale dell’Ateneo Lucano, 10-85100, Potenza (Italy); Santagata, A. [CNR-ISM, U.O.S. Tito Scalo, Zona Industriale, 85050, Tito Scalo (PZ) (Italy); Rau, J.V. [CNR-ISM, Via del Fosso del Cavaliere, 100-00133, Rome (Italy); Galasso, A.; Teghil, R. [Dipartimento di Scienze, Università degli Studi della Basilicata, Viale dell’Ateneo Lucano, 10-85100, Potenza (Italy)

    2015-05-01

    Highlights: • Laser ablation of a fullerite target in water performed by an ultra-short laser source has been reported. • The formation of reduced graphene oxide has been described considering the laser ablation in liquid mechanism. • Fullerene-reduced graphene oxide composite, in the form of self assembled microtubes, has been described. - Abstract: The laser ablation in liquid of carbon-based solid targets is of particular interest thanks to the possibility of obtaining different carbon allotropes by varying the experimental parameters employed. The ablation of a fullerite target in water using a frequency-doubled Nd:glass laser source with a pulse duration of 250 fs and a frequency repetition rate of 10 Hz is presented. The obtained products have been characterized by transmission electron and atomic force microscopies and by X-ray photoelectron and micro-Raman spectroscopies. During the femtosecond laser ablation, the collapse of fullerene cages has been considered with the consequent formation of graphene oxide (GO) and its successive hydrogenation. The process of self-assembling in microtube structures of the formed reduced graphene oxide-fullerene composites has then been reported.

  3. Chemistry of paramagnetic and diamagnetic contrast agents for Magnetic Resonance Imaging and Spectroscopy

    International Nuclear Information System (INIS)

    Perez-Mayoral, Elena; Negri, Viviana; Soler-Padros, Jordi; Cerdan, Sebastian; Ballesteros, Paloma

    2008-01-01

    We provide a brief overview of the chemistry and most relevant properties of paramagnetic and diamagnetic contrast agents (CAs) for Magnetic Resonance Imaging and Magnetic Resonance Spectroscopic Imaging. Paramagnetic CAs for MRI consist mainly of Gd(III) complexes from linear or macrocyclic polyaminopolycarboxylates. These agents reduce, the relaxation times T 1 and T 2 of the water protons in a concentration dependent manner, increasing selectively MRI contrast in those regions in which they accumulate. In most instances they provide anatomical information on the localization of lesions and in some specific cases they may allow to estimate some physiological properties of tissues including mainly vascular performance. Because of its ability to discriminate easily between normal and diseased tissue, extracellular pH (pH e ) has been added recently, to the battery of variables amenable to MRI investigation. A variety of Gd(III) containing macrocycles sensitive to pH, endogenous or exogenous polypeptides or even liposomes have been investigated for this purpose, using the pH dependence of their relaxivity or magnetization transfer rate constant (chemical exchange saturation transfer, CEST). Many environmental circumstances in addition to pH affect, however, relaxivity or magnetization transfer rate constants of these agents, making the results of pH measurements by MRI difficult to interpret. To overcome these limitations, our laboratory synthesized and developed a novel series of diamagnetic CAs for Magnetic Resonance Spectroscopic Imaging, a new family of monomeric and dimeric imidazolic derivatives able to provide unambiguous measurements of pH e , independent of water relaxivity, diffusion or exchange

  4. Chemistry of paramagnetic and diamagnetic contrast agents for Magnetic Resonance Imaging and Spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Perez-Mayoral, Elena [Laboratorio de Sintesis Organica e Imagen Molecular por Resonancia Magnetica, Facultad de Ciencias, UNED, Paseo Senda del Rey 9, E-28040 Madrid (Spain); Departamento de Quimica Inorganica y Quimica Tecnica, Facultad de Ciencias, UNED, Paseo Senda del Rey 9, E-28040 Madrid (Spain); Negri, Viviana; Soler-Padros, Jordi [Laboratorio de Sintesis Organica e Imagen Molecular por Resonancia Magnetica, Facultad de Ciencias, UNED, Paseo Senda del Rey 9, E-28040 Madrid (Spain); Cerdan, Sebastian [Laboratorio de Imagen Espectroscopica por Resonancia Magnetica (LIERM), Instituto de Investigaciones Biomedicas ' Alberto Sols' , CSIC/UAM, c/Arturo Duperier 4, E-28029 Madrid (Spain); Ballesteros, Paloma [Laboratorio de Sintesis Organica e Imagen Molecular por Resonancia Magnetica, Facultad de Ciencias, UNED, Paseo Senda del Rey 9, E-28040 Madrid (Spain)], E-mail: pballesteros@ccia.uned.es

    2008-09-15

    We provide a brief overview of the chemistry and most relevant properties of paramagnetic and diamagnetic contrast agents (CAs) for Magnetic Resonance Imaging and Magnetic Resonance Spectroscopic Imaging. Paramagnetic CAs for MRI consist mainly of Gd(III) complexes from linear or macrocyclic polyaminopolycarboxylates. These agents reduce, the relaxation times T{sub 1} and T{sub 2} of the water protons in a concentration dependent manner, increasing selectively MRI contrast in those regions in which they accumulate. In most instances they provide anatomical information on the localization of lesions and in some specific cases they may allow to estimate some physiological properties of tissues including mainly vascular performance. Because of its ability to discriminate easily between normal and diseased tissue, extracellular pH (pH{sub e}) has been added recently, to the battery of variables amenable to MRI investigation. A variety of Gd(III) containing macrocycles sensitive to pH, endogenous or exogenous polypeptides or even liposomes have been investigated for this purpose, using the pH dependence of their relaxivity or magnetization transfer rate constant (chemical exchange saturation transfer, CEST). Many environmental circumstances in addition to pH affect, however, relaxivity or magnetization transfer rate constants of these agents, making the results of pH measurements by MRI difficult to interpret. To overcome these limitations, our laboratory synthesized and developed a novel series of diamagnetic CAs for Magnetic Resonance Spectroscopic Imaging, a new family of monomeric and dimeric imidazolic derivatives able to provide unambiguous measurements of pH{sub e}, independent of water relaxivity, diffusion or exchange.

  5. Water-in-oil-in-water double emulsion for the delivery of starter cultures in reduced-salt moromi fermentation of soy sauce.

    Science.gov (United States)

    Devanthi, Putu Virgina Partha; Linforth, Robert; El Kadri, Hani; Gkatzionis, Konstantinos

    2018-08-15

    This study investigated the application of water-oil-water (W 1 /O/W 2 ) double emulsions (DE) for yeast encapsulation and sequential inoculation of Zygosaccharomyces rouxii and Tetragenococcus halophilus in moromi stage of soy sauce fermentation with reduced NaCl and/or substitution with KCl. Z. rouxii and T. halophilus were incorporated in the internal W 1 and external W 2 phase of DE, respectively. NaCl reduction and substitution promoted T. halophilus growth to 8.88 log CFU/mL, accompanied with faster sugar depletion and enhanced lactic acid production. Reducing NaCl without substitution increased the final pH (5.49) and decreased alcohols, acids, esters, furan and phenol content. However, the application of DE resulted in moromi with similar microbiological and physicochemical characteristics to that of high-salt. Principal component analysis of GC-MS data demonstrated that the reduced-salt moromi had identical aroma profile to that obtained in the standard one, indicating the feasibility of producing low-salt soy sauce without compromising its quality. Copyright © 2018 Elsevier Ltd. All rights reserved.

  6. Pharmacoeconomics of inhaled anesthetic agents: considerations for the pharmacist.

    Science.gov (United States)

    Chernin, Eric L

    2004-10-15

    Types of economic analyses used for inhaled anesthetic agents, factors to consider in calculating the cost of inhaled anesthetics, limitations of pharmacoeconomic studies of these agents, and strategies for controlling inhaled anesthetic costs are discussed. Inhaled anesthetic agents comprise a substantial component of drug budgets. Calculation of the cost of administering an inhaled anesthetic should take into consideration the cost per mL, potency, waste, concentration and duration of gas delivery, fresh gas flow rate, molecular weight, and density. The use of newer inhaled anesthetic agents with low solubility in blood and tissue provides a more rapid recovery from anesthesia than older, more soluble agents, and also provides the same level of control of depth of anesthesia at a lower fresh gas flow rate and possibly a lower cost than older agents at a higher fresh gas flow rate. A more rapid recovery may facilitate fast-track recovery and yield cost savings if it allows the completion of additional surgical cases or allows a reduction in personnel overtime expenses. Interpretation of pharmacoeconomic studies of inhaled anesthetics requires an appreciation of the limitations in methodology and ability to extrapolate results from one setting to another. Pharmacists' efforts to reduce anesthetic waste and collaborate with anesthesiologists to improve the use of these agents can help contain costs, but improving scheduling and efficiency in the operating room has a greater potential to reduce operating room costs. Much can be done to control costs of anesthetic agents without compromising availability of these agents and patient care.

  7. Capillary gas chromatographic analysis of nerve agents using large volume injections

    NARCIS (Netherlands)

    Degenhardt, C.E.A.M.; Kientz, C.E.

    1996-01-01

    The use of large volume injections has been studied for the verification of intact organophosphorus chemical warfare agents in water samples. As the use of ethyl acetate caused severe detection problems new potential solvents were evaluated. With the developed procedure, the nerve agents sarin,

  8. The use of desorbing agents in electrodialytic remediation of harbour sediment

    DEFF Research Database (Denmark)

    Nystrøm, Gunvor Marie; Pedersen, Anne Juul; Ottosen, Lisbeth M.

    2006-01-01

    Electrodialytic removal of Cu, Zn, Pb and Cd from contaminated harbour sediment was made with the emphasis of testing the effectiveness of different desorbing agents: HCl, NaCl, citric acid, lactic acid, ammonium citrate and distilled water. Extraction experiments with the desorbing agents were...

  9. Agent Based Modeling Applications for Geosciences

    Science.gov (United States)

    Stein, J. S.

    2004-12-01

    Agent-based modeling techniques have successfully been applied to systems in which complex behaviors or outcomes arise from varied interactions between individuals in the system. Each individual interacts with its environment, as well as with other individuals, by following a set of relatively simple rules. Traditionally this "bottom-up" modeling approach has been applied to problems in the fields of economics and sociology, but more recently has been introduced to various disciplines in the geosciences. This technique can help explain the origin of complex processes from a relatively simple set of rules, incorporate large and detailed datasets when they exist, and simulate the effects of extreme events on system-wide behavior. Some of the challenges associated with this modeling method include: significant computational requirements in order to keep track of thousands to millions of agents, methods and strategies of model validation are lacking, as is a formal methodology for evaluating model uncertainty. Challenges specific to the geosciences, include how to define agents that control water, contaminant fluxes, climate forcing and other physical processes and how to link these "geo-agents" into larger agent-based simulations that include social systems such as demographics economics and regulations. Effective management of limited natural resources (such as water, hydrocarbons, or land) requires an understanding of what factors influence the demand for these resources on a regional and temporal scale. Agent-based models can be used to simulate this demand across a variety of sectors under a range of conditions and determine effective and robust management policies and monitoring strategies. The recent focus on the role of biological processes in the geosciences is another example of an area that could benefit from agent-based applications. A typical approach to modeling the effect of biological processes in geologic media has been to represent these processes in

  10. Newly Synthesized Water Soluble Cholinium-Purpurin Photosensitizers and Their Stabilized Gold Nanoparticles as Promising Anticancer Agents

    Directory of Open Access Journals (Sweden)

    Young Key Shim

    2008-05-01

    Full Text Available For possible future use in Photodynamic Therapy (PDT and/or Photothermal Therapy (PTT of cancer and screening of cancer cells a new type of ionic liquid photosensitizer –Cholinium-Purpurin-18 (Chol-Pu-18 – was synthesized and small gold (Au nanoparticles, stabilized by this photosensitizer were prepared without adding any particular reducing agents and CTAB. UV-Vis spectroscopy and Transmission Electron Microscopy (TEM were used for characterization of the nanoparticles and FAB-MS and NMR of the ionic liquid choline hydroxide, purpurin carboxylate and their ionic liquid type of photosensitizer were obtained.

  11. Preparation of protein based surfactants from leather waste fleshings and their reutilization in leather as a water resisting agent

    International Nuclear Information System (INIS)

    Nawaz, H.; Nadeem, U.; Solangi, B.; Hany, O.E.

    2012-01-01

    Summary: Tanneries generate a huge amount of highly polluting solid and liquid wastes during leather processing at different stages such as fleshings, shavings, tanning, finishing etc. approximately, 250 kg of finished leather product is obtained from 1 ton of raw salted hide while other protein goes into wastes. leather fleshings are about 50-60% of the total solid waste generated in leather processing. three different surfactants have been prepared from soft wax, long chain fatty acid chlorides and leather waste protein isolated from alkaline hydrolysis of fleshings. products are milky in color and have been applied in goat leathers as a replacement of fat liquor and water resisting agent .the resulted crust leathers have been characterized for various physical parameters such as tensile strength, thickness, softness, tear strength, bursting load, water absorption etc, as per their standard test methods. leathers have also been evaluated for grain smoothness, fullness and feeling. leathers have shown satisfactory results as per international requirement specially for water resisting. thus a leather waste protein is converted into a useful product and reutilized in leather making. (author)

  12. Reducing water consumption of an industrial plant cooling unit using hybrid cooling tower

    International Nuclear Information System (INIS)

    Rezaei, Ebrahim; Shafiei, Sirous; Abdollahnezhad, Aydin

    2010-01-01

    Water consumption is an important problem in dry zones and poor water supply areas. For these areas use of a combination of wet and dry cooling towers (hybrid cooling) has been suggested in order to reduce water consumption. In this work, wet and dry sections of a hybrid cooling tower for the estimation of water loss was modeled. A computer code was also written to simulate such hybrid cooling tower. To test the result of this simulation, a pilot hybrid tower containing a wet tower and 12 compact air cooled heat exchangers was designed and constructed. Pilot data were compared with simulation data and a correction factor was added to the simulation. Ensuring that the simulation represents the actual data, it was applied to a real industrial case and the effect of using a dry tower on water loss reduction of this plant cooling unit was investigated. Finally feasibility study was carried out to choose the best operating conditions for the hybrid cooling tower configuration proposed for this cooling unit.

  13. Reduced nighttime transpiration is a relevant breeding target for high water-use efficiency in grapevine.

    Science.gov (United States)

    Coupel-Ledru, Aude; Lebon, Eric; Christophe, Angélique; Gallo, Agustina; Gago, Pilar; Pantin, Florent; Doligez, Agnès; Simonneau, Thierry

    2016-08-09

    Increasing water scarcity challenges crop sustainability in many regions. As a consequence, the enhancement of transpiration efficiency (TE)-that is, the biomass produced per unit of water transpired-has become crucial in breeding programs. This could be achieved by reducing plant transpiration through a better closure of the stomatal pores at the leaf surface. However, this strategy generally also lowers growth, as stomatal opening is necessary for the capture of atmospheric CO2 that feeds daytime photosynthesis. Here, we considered the reduction in transpiration rate at night (En) as a possible strategy to limit water use without altering growth. For this purpose, we carried out a genetic analysis for En and TE in grapevine, a major crop in drought-prone areas. Using recently developed phenotyping facilities, potted plants of a cross between Syrah and Grenache cultivars were screened for 2 y under well-watered and moderate soil water deficit scenarios. High genetic variability was found for En under both scenarios and was primarily associated with residual diffusion through the stomata. Five quantitative trait loci (QTLs) were detected that underlay genetic variability in En Interestingly, four of them colocalized with QTLs for TE. Moreover, genotypes with favorable alleles on these common QTLs exhibited reduced En without altered growth. These results demonstrate the interest of breeding grapevine for lower water loss at night and pave the way to breeding other crops with this underexploited trait for higher TE.

  14. Ecosystem services, efficiency, sustainability and equity: South Africa's Working for Water Programme

    CSIR Research Space (South Africa)

    Van Wilgen, BW

    1998-09-01

    Full Text Available implications for the forest industry, which in essence farms with invasive trees and will have to avoid penalties for water use as a result of alien plant spread. The in- dustry will also need to absorb the im- pacts of biological control agents should... resources. Second, biological control (using species- specific insects and pathogens from the invader’s country of origin) offers hope for reducing clearing costs. By ignoring non- water users and introducing biological control, clearing costs could...

  15. TANDEM: A Trust-Based Agent Framework for Networked Decision Making

    Science.gov (United States)

    2015-09-10

    selective (20–80 %), while the rest are good citizens, trust acts as a method to isolate misbehaving agents. If the majority of the agents have high...competence and low selectivity, then they can use trust to isolate route information around the misbehaving agents, improving Comm and Steps. The impact is...more dramatic when only 20–40 % of the agents are misbehaving . However, using trust results in reduced SA as the information available at the

  16. Impact of reducing and oxidizing agents on the infectivity of Qβ phage and the overall structure of its capsid.

    Science.gov (United States)

    Loison, Pauline; Majou, Didier; Gelhaye, Eric; Boudaud, Nicolas; Gantzer, Christophe

    2016-11-01

    Qβ phages infect Escherichia coli in the human gut by recognizing F-pili as receptors. Infection therefore occurs under reducing conditions induced by physiological agents (e.g. glutathione) or the intestinal bacterial flora. After excretion in the environment, phage particles are exposed to oxidizing conditions and sometimes disinfection. If inactivation does not occur, the phage may infect new hosts in the human gut through the oral route. During such a life cycle, we demonstrated that, outside the human gut, cysteines of the major protein capsid of Qβ phage form disulfide bonds. Disinfection with NaClO does not allow overoxidation to occur. Such oxidation induces inactivation rather by irreversible damage to the minor proteins. In the presence of glutathione, most disulfide bonds are reduced, which slightly increases the capacity of the phage to infect E. coli in vitro Such reduction is reversible and barely alters infectivity of the phage. Reduction of all disulfide bonds by dithiothreitol leads to complete capsid destabilization. These data provide new insights into how the phages are impacted by oxidizing-reducing conditions outside their host cell and raises the possibility of the intervention of the redox during life cycle of the phage. © FEMS 2016. All rights reserved. For permissions, please e-mail: journals.permissions@oup.com.

  17. The antiendotoxin agent taurolidine potentially reduces ischemia/reperfusion injury through its metabolite taurine.

    LENUS (Irish Health Repository)

    Doddakula, Kishore K

    2010-09-01

    Cardiopulmonary bypass results in ischemia\\/reperfusion (I\\/R)-induced endotoxemia. We conducted a prospective randomized trial to investigate the effect of taurolidine, an antiendotoxin agent with antioxidant and membrane-stabilizing properties, on patients undergoing coronary artery bypass grafting (CABG).

  18. Mesquite Gum as a Novel Reducing and Stabilizing Agent for Modified Tollens Synthesis of Highly Concentrated Ag Nanoparticles

    Directory of Open Access Journals (Sweden)

    Maira Berenice Moreno‐Trejo

    2016-10-01

    Full Text Available The synthesis that is described in this study is for the preparation of silver nanoparticles of sizes ranging from 10 nm to 30 nm with a defined shape (globular, confirmed by UV-vis, SEM, STEM and DLS analysis. This simple and favorable one-step modified Tollens reaction does not require any special equipment or other stabilizing or reducing agent except for a solution of purified mesquite gum, and it produces aqueous colloidal dispersions of silver nanoparticles with a stability thatexceeds three months, a relatively narrow size distribution, a low tendency to aggregate and a yield of at least 95% for all cases. Reaction times are between 15 min and 60 min to obtain silver nanoparticles in concentrations ranging from 0.1 g to 3 g of Ag per 100 g of reaction mixture. The proposed synthetic method presents a high potential for scale-up, since its production capacity is rather high and the methodology is simple.The synthesis that is described in this study is for the preparation of silver nanoparticles of sizes ranging from 10 nm to 30 nm with a defined shape (globular, confirmed by UV-vis, SEM, STEM and DLS analysis. This simple and favorable one-step modified Tollens reaction does not require any special equipment or other stabilizing or reducing agent except for a solution of purified mesquite gum, and it produces aqueous colloidal dispersions of silver nanoparticles with a stability thatexceeds three months, a relatively narrow size distribution, a low tendency to aggregate and a yield of at least 95% for all cases. Reaction times are between 15 min and 60 min to obtain silver nanoparticles in concentrations ranging from 0.1 g to 3 g of Ag per 100 g of reaction mixture. The proposed synthetic method presents a high potential for scale-up, since its production capacity is rather high and the methodology is simple.

  19. The methods of cesium-137 determination in sea water

    International Nuclear Information System (INIS)

    Gedeonov, L.I.; Krylov, V.N.; Stepanov, A.V.

    1978-01-01

    New express procedures of Cs-137 determination in sea water using selective sorbents are described. One of them is based on the use of natural radioactive potassium-40 as internal standard. Another one allows to perform Cs-137 determination without use of any standards, by pumping a certain amount of water through several successive identical cells filled with sorbent. The positive feature of the procedures consists in that it is no longer necessary chemical treatment of samples in Cs-133 determination in the sorbent and sea water. The danger of polution of samples by alkali metals which can be introduced with reactive agents in the process of chemical treatment is reduced to minimum

  20. Impact of reducing and oxidising agents on the wheat flour dough dynamic rheological properties

    Directory of Open Access Journals (Sweden)

    Pavlína Pečivová

    2011-01-01

    Full Text Available Dynamic measurements with an oscillatory rheometer were made to study the rheological properties of wheat flour doughs and to examine how they are related to the composition of dough (the addition of oxidising and reducing agents.It was found that L-cysteine hydrochloride monohydrate (0.6 × 10−2 − 4.0 × 10−2 wt.%, L-cysteine p. a. (0.6 × 10−2 − 1.4 × 10−2 wt.% and glutathione-inactivated dry yeast (1.8 × 10−2 − 14.0 × 10−2 wt.% show softening effects. An interesting phenomenon was observed from the concentration of 2.4 × 10−2 wt.% of L-cysteine p. a., where proces of weakening was decelerated. L-cysteine start making cystine by reaction of two cysteine molecules and proces of weakening was decelerated. L-threonine, L-tryptophan within the concentration range of 2.0 × 10−2 − 14.0 × 10−2 wt.% and L-tyrosine, especially at concentrations 10.0 × 10−2 − 14.0 × 10−2 wt.%, have strengthening effects. L-cysteine hydrochloride monohydrate exhibited the strongest softening effect while L-tryptophan had the strongest stiffening effect on the gluten network.

  1. Development of Polymer Gel Systems to Improve Volumetric Sweep and Reduce Producing Water/Oil Ratios

    Energy Technology Data Exchange (ETDEWEB)

    G. Paul Willhite; Stan McCool; Don W. Green; Min Cheng; Feiyan Chen

    2005-12-31

    Gelled polymer treatments are applied to oil reservoirs to increase oil production and to reduce water production by altering the fluid movement within the reservoir. This report describes the results of a 42-month research program that focused on the understanding of gelation chemistry and the fundamental mechanisms that alter the flows of oil and water in reservoir rocks after a gel treatment. Work was conducted on a widely applied system in the field, the partially hydrolyzed polyacrylamide-chromium acetate gel. Gelation occurs by network formation through the crosslinking of polyacrylamide molecules as a result of reaction with chromium acetate. Pre-gel aggregates form and grow as reactions between chromium acetate and polyacrylamide proceed. A rate equation that describes the reaction between chromium acetate and polymer molecules was regressed from experimental data. A mathematical model that describes the crosslinking reaction between two polymer molecules as a function of time was derived. The model was based on probability concepts and provides molecular-weight averages and molecular-weight distributions of the pre-gel aggregates as a function of time and initial system conditions. Average molecular weights of pre-gel aggregates were measured as a function of time and were comparable to model simulations. Experimental methods to determine molecular weight distributions of pre-gel aggregates were unsuccessful. Dissolution of carbonate minerals during the injection of gelants causes the pH of the gelant to increase. Chromium precipitates from solution at the higher pH values robbing the gelant of crosslinker. Experimental data on the transport of chromium acetate solutions through dolomite cores were obtained. A mathematical model that describes the transport of brine and chromium acetate solutions through rocks containing carbonate minerals was used to simulate the experimental results and data from literature. Gel treatments usually reduce the permeability

  2. 1-Hexadecylamine as both reducing agent and stabilizer to synthesize Au and Ag nanoparticles and their SERS application

    International Nuclear Information System (INIS)

    Hou Xiaomiao; Zhan, Xiaoling; Fang Yan; Chen Shutang; Li Na; Zhou Qi

    2011-01-01

    1-Hexadecylamine (HDA)-capped Au and Ag nanoparticles (NPs) have been successfully prepared by a one-pot solution growth method. The HDA is used as both reducing agent and stabilizer in the synthetic process is favorable for investigating the capping mechanism of Au and Ag NPs’ surface. The growth process and characterization of Au and Ag NPs are determined by Ultraviolet–visible (UV–vis) spectroscopy, transmission electron microscopy (TEM), and X-ray diffraction (XRD). Experimental results demonstrate that the HDA-capped Au and Ag NPs are highly crystalline and have good optical properties. Furthermore, surface-enhanced Raman scattering (SERS) spectra of 2-thionaphthol are obtained on the Au and Ag NPs modified glass surface, respectively, indicating that the as-synthesized noble metal NPs have potentially high sensitive optical detection application.

  3. 1-Hexadecylamine as both reducing agent and stabilizer to synthesize Au and Ag nanoparticles and their SERS application

    Energy Technology Data Exchange (ETDEWEB)

    Hou Xiaomiao; Zhan, Xiaoling, E-mail: zhangxl@bit.edu.cn [Beijing Institute of Technology, Department of Chemistry, School of Science (China); Fang Yan, E-mail: fangyan@mail.cnu.edu.cn [Capital Normal University, Beijing Key Lab for Nano-Photonics and Nano-Structure (NPNS), Department of Physics (China); Chen Shutang; Li Na; Zhou Qi [Beijing Institute of Technology, Department of Chemistry, School of Science (China)

    2011-05-15

    1-Hexadecylamine (HDA)-capped Au and Ag nanoparticles (NPs) have been successfully prepared by a one-pot solution growth method. The HDA is used as both reducing agent and stabilizer in the synthetic process is favorable for investigating the capping mechanism of Au and Ag NPs' surface. The growth process and characterization of Au and Ag NPs are determined by Ultraviolet-visible (UV-vis) spectroscopy, transmission electron microscopy (TEM), and X-ray diffraction (XRD). Experimental results demonstrate that the HDA-capped Au and Ag NPs are highly crystalline and have good optical properties. Furthermore, surface-enhanced Raman scattering (SERS) spectra of 2-thionaphthol are obtained on the Au and Ag NPs modified glass surface, respectively, indicating that the as-synthesized noble metal NPs have potentially high sensitive optical detection application.

  4. In vivo antimicrobial activity of silver nanoparticles produced via a green chemistry synthesis using Acacia rigidula as a reducing and capping agent.

    Science.gov (United States)

    Escárcega-González, Carlos Enrique; Garza-Cervantes, J A; Vázquez-Rodríguez, A; Montelongo-Peralta, Liliana Zulem; Treviño-González, M T; Díaz Barriga Castro, E; Saucedo-Salazar, E M; Chávez Morales, R M; Regalado Soto, D I; Treviño González, F M; Carrazco Rosales, J L; Cruz, Rocío Villalobos; Morones-Ramírez, José Rubén

    2018-01-01

    One of the main issues in the medical field and clinical practice is the development of novel and effective treatments against infections caused by antibiotic-resistant bacteria. One avenue that has been approached to develop effective antimicrobials is the use of silver nanoparticles (Ag-NPs), since they have been found to exhibit an efficient and wide spectrum of antimicrobial properties. Among the main drawbacks of using Ag-NPs are their potential cytotoxicity against eukaryotic cells and the latent environmental toxicity of their synthesis methods. Therefore, diverse green synthesis methods, which involve the use of environmentally friendly plant extracts as reductive and capping agents, have become attractive to synthesize Ag-NPs that exhibit antimicrobial effects against resistant bacteria at concentrations below toxicity thresholds for eukaryotic cells. In this study, we report a green one-pot synthesis method that uses Acacia rigidula extract as a reducing and capping agent, to produce Ag-NPs with applications as therapeutic agents to treat infections in vivo. The Ag-NPs were characterized using transmission electron microscopy (TEM), high-resolution TEM, selected area electron diffraction, energy-dispersive spectroscopy, ultraviolet-visible, and Fourier transform infrared. We show that Ag-NPs are spherical with a narrow size distribution. The Ag-NPs show antimicrobial activities in vitro against Gram-negative ( Escherichia coli , Pseudomonas aeruginosa , and a clinical multidrug-resistant strain of P. aeruginosa ) and Gram-positive ( Bacillus subtilis ) bacteria. Moreover, antimicrobial effects of the Ag-NPs, against a resistant P. aeruginosa clinical strain, were tested in a murine skin infection model. The results demonstrate that the Ag-NPs reported in this work are capable of eradicating pathogenic resistant bacteria in an infection in vivo. In addition, skin, liver, and kidney damage profiles were monitored in the murine infection model, and the

  5. Further Screening of Entomopathogenic Fungi and Nematodes as Control Agents for Drosophila suzukii.

    Science.gov (United States)

    Cuthbertson, Andrew G S; Audsley, Neil

    2016-06-09

    Drosophila suzukii populations remain low in the UK. To date, there have been no reports of widespread damage. Previous research demonstrated that various species of entomopathogenic fungi and nematodes could potentially suppress D. suzukii population development under laboratory trials. However, none of the given species was concluded to be specifically efficient in suppressing D. suzukii. Therefore, there is a need to screen further species to determine their efficacy. The following entomopathogenic agents were evaluated for their potential to act as control agents for D. suzukii: Metarhizium anisopliae; Isaria fumosorosea; a non-commercial coded fungal product (Coded B); Steinernema feltiae, S. carpocapsae, S. kraussei and Heterorhabditis bacteriophora. The fungi were screened for efficacy against the fly on fruit while the nematodes were evaluated for the potential to be applied as soil drenches targeting larvae and pupal life-stages. All three fungi species screened reduced D. suzukii populations developing from infested berries. Isaria fumosorosea significantly (p nematodes significantly reduced adult emergence from pupal cases compared to the water control. Larvae proved more susceptible to nematode infection. Heterorhabditis bacteriophora proved the best from the four nematodes investigated; readily emerging from punctured larvae and causing 95% mortality. The potential of the entomopathogens to suppress D. suzukii populations is discussed.

  6. Radiographic scanning agent

    International Nuclear Information System (INIS)

    Bevan, J.A.

    1983-01-01

    The invention is on the water-soluble composition of matter selected from the group consisting of sup(99m)Tc-methanehydroxydiphosphonate, sup(99m)Tc-methanehydroxydiphosphonate-tin, sup(99m)Tc-methanehydroxydiphosphonate-iron, sup(99m)Tc-methanehydroxydiphosphonate-chromium and sup(99m)Tc-methanehydroxydiphosphonate-titanium. Another aspect of the invention is a process for preparing a water-soluble salt of methanehydroxydiphosphonic acid and a heavy metal selected from the group consisting of tin, iron, chromium and titanium, the heavy metal being in a reduced valence state. The process consists of reacting methanehydroxydiphosphonic acid or a water-soluble alkali metal, ammonium, alkylammonium, alkanolammonium salt or an ester of the acid which hydrolyses under use to the free acid or anion form of the acid, with a water-soluble salt of the heavy metal in a reduced valence state

  7. Improved Concrete Materials with Hydrogel-Based Internal Curing Agents

    Directory of Open Access Journals (Sweden)

    Matthew J. Krafcik

    2017-11-01

    Full Text Available This research article will describe the design and use of polyelectrolyte hydrogel particles as internal curing agents in concrete and present new results on relevant hydrogel-ion interactions. When incorporated into concrete, hydrogel particles release their stored water to fuel the curing reaction, resulting in reduced volumetric shrinkage and cracking and thus increasing concrete service life. The hydrogel’s swelling performance and mechanical properties are strongly sensitive to multivalent cations that are naturally present in concrete mixtures, including calcium and aluminum. Model poly(acrylic acid(AA-acrylamide(AM-based hydrogel particles with different chemical compositions (AA:AM monomer ratio were synthesized and immersed in sodium, calcium, and aluminum salt solutions. The presence of multivalent cations resulted in decreased swelling capacity and altered swelling kinetics to the point where some hydrogel compositions displayed rapid deswelling behavior and the formation of a mechanically stiff shell. Interestingly, when incorporated into mortar, hydrogel particles reduced mixture shrinkage while encouraging the formation of specific inorganic phases (calcium hydroxide and calcium silicate hydrate within the void space previously occupied by the swollen particle.

  8. Shark Spotters: Successfully reducing spatial overlap between white sharks (Carcharodon carcharias) and recreational water users in False Bay, South Africa.

    Science.gov (United States)

    Engelbrecht, Tamlyn; Kock, Alison; Waries, Sarah; O'Riain, M Justin

    2017-01-01

    White sharks (Carcharodon carcharias) are apex predators that play an important role in the structure and stability of marine ecosystems. Despite their ecological importance and protected status, white sharks are still subject to lethal control to reduce the risk of shark bites for recreational water users. The Shark Spotters program, pioneered in Cape Town, South Africa, provides a non-lethal alternative for reducing the risk of human-shark conflict. In this study we assessed the efficacy of the Shark Spotters program in reducing overlap between water users and white sharks at two popular beaches in False Bay, South Africa. We investigated seasonal and diel patterns in water use and shark presence at each beach, and thereafter quantified the impact of different shark warnings from shark spotters on water user abundance. We also assessed the impact of a fatal shark incident on patterns of water use. Our results revealed striking diel and seasonal overlap between white sharks and water users at both beaches. Despite this, there was a low rate of shark-human incidents (0.5/annum) which we attribute partly to the success of the Shark Spotters program. Shark spotters use visual (coloured flags) and auditory (siren) cues to inform water users of risk associated with white shark presence in the surf zone. Our results showed that the highest risk category (denoted by a white flag and accompanying siren) caused a significant reduction in water user abundance; however the secondary risk category (denoted by a red flag with no siren) had no significant effect on water users. A fatal shark incident was shown to negatively impact the number of water users present for at least three months following the incident. Our results indicate that the Shark Spotters program effectively reduces spatial overlap between white sharks and water users when the risk of conflict is highest.

  9. Environmentally friendly inhibition of pathogenic bacteria and algae propagation due phthalocyanine agents

    International Nuclear Information System (INIS)

    Rihova Ambrozova, J.; Bezdekova, E.; Louckova, E.; Nekovarova, J.

    2007-01-01

    From 2004, in the laboratory of The Institute of Chemical Technology in Prague is being solved the project FT-TA/034 'Environmentally friendly inhibition of pathogenic bacteria and algae propagation in the circulatory cooling systems of nuclear power stations and in other similar technological facilities' to determine effects of phthalocyanine agents. The project bearer is VUOS, Inc. in Rybitvi (Research Institute for Organic Synthesis Inc.), where are the new phthalocyanines synthesized. The aimed goal of the research is environmentally friendly liquidation of bacteria and algae by means of photodynamic generated singlet oxygen through impact of solar radiation in the circulation cooling waters of various technical and technological systems. The principle of the problem outlined is the applying of phthalocyanine agents on samples of pure bacterial, anabaenas and algae cultures to estimate the inhibition effect on the organism exposed. In the course of solution, it is assumed that in such way conducted inhibition of bacteria, anabaenas and algae as well of their proliferation would replace routinely used bactericidal and algicidal preparations, which demand permanent dosing into circulating waters or perhaps from time to time an application of shocking doses. The particular algicidal and bactericidal agents represents in this case in situ emerging singlet oxygen, that is harmless to water biocenoses and whose presence in the water is no reason to ban the outflow of waters treated in such a way into water streams. The goal should be also a direct estimation of the effect those agents on cooling waters samples e. g. from the nuclear power plant systems. The purpose of the tests performance is also elimination of filamentous green algae, emerging in the systems cooling towers. The applied preparations are not toxic and do not burden the living environment, they contain no substances interacting with surface materials of structures in the circulatory cooling circuit

  10. 75 FR 28232 - Availability of an Environmental Assessment for a Biological Control Agent for Hemlock Woolly...

    Science.gov (United States)

    2010-05-20

    ...] Availability of an Environmental Assessment for a Biological Control Agent for Hemlock Woolly Adelgid AGENCY..., into the continental United States for use as a biological control agent to reduce the severity of... biological control agent to reduce the severity of hemlock woolly adelgid (HWA) infestations. HWA, an...

  11. Agent Collaborative Target Localization and Classification in Wireless Sensor Networks

    Directory of Open Access Journals (Sweden)

    Sheng Wang

    2007-07-01

    Full Text Available Wireless sensor networks (WSNs are autonomous networks that have beenfrequently deployed to collaboratively perform target localization and classification tasks.Their autonomous and collaborative features resemble the characteristics of agents. Suchsimilarities inspire the development of heterogeneous agent architecture for WSN in thispaper. The proposed agent architecture views WSN as multi-agent systems and mobileagents are employed to reduce in-network communication. According to the architecture,an energy based acoustic localization algorithm is proposed. In localization, estimate oftarget location is obtained by steepest descent search. The search algorithm adapts tomeasurement environments by dynamically adjusting its termination condition. With theagent architecture, target classification is accomplished by distributed support vectormachine (SVM. Mobile agents are employed for feature extraction and distributed SVMlearning to reduce communication load. Desirable learning performance is guaranteed bycombining support vectors and convex hull vectors. Fusion algorithms are designed tomerge SVM classification decisions made from various modalities. Real world experimentswith MICAz sensor nodes are conducted for vehicle localization and classification.Experimental results show the proposed agent architecture remarkably facilitates WSNdesigns and algorithm implementation. The localization and classification algorithms alsoprove to be accurate and energy efficient.

  12. Contrast agent choice for intravenous coronary angiography

    International Nuclear Information System (INIS)

    Zeman, H.D.; Siddons, D.P.

    1989-01-01

    The screening of the general population for coronary artery disease would be practical if a method existed for visualizing the extent of occlusion after an intravenous injection of contrast agent. Measurements performed with monochromatic synchrotron radiation x-rays and an iodine containing contrast agent at the Stanford Synchrotron Radiation Laboratory have shown that such an intravenous angiography procedure would be possible with an adequately intense monochromatic x-ray source. Because of the size and cost of synchrotron radiation facilities it would be desirable to make the most efficient use of the intensity available, while reducing as much as possible the radiation dose experienced by the patient. By choosing contrast agents containing elements with a higher atomic number than iodine, it is possible to both improve the image quality and reduce the patient radiation dose, while using the same synchrotron source. By using Si monochromator crystals with a small mosaic spread, it is possible to increase the x-ray flux available for imaging by over an order of magnitude, without any changes in the storage ring or wiggler magnet. The most critical imaging task for intravenous coronary angiography utilizing synchrotron radiation x-rays is visualizing a coronary artery through the left ventricle or aorta which also contains a contrast agent. Calculations have been made of the signal to noise ratio expected for this imaging task for various contrast agents with atomic numbers between that of iodine and bismuth

  13. Water-equivalent oral contrast agents in dual-modality PET/computed tomography scanning: does a little barium make the difference?

    Science.gov (United States)

    Kinner, Sonja; Veit-Haibach, Patrick; Lauenstein, Thomas C; Bockisch, Andreas; Antoch, Gerald

    2009-03-01

    To retrospectively evaluate the performance of two water-equivalent oral contrast agents [locust bean gum (LBG)-mannitol and VoLumen] concerning their potential to distend the bowel while avoiding contrast-associated artifacts in PET/computed tomography. PET/computed tomography examinations of 30 patients with two different oral contrast agents were reviewed. Bowel distension, intraluminal density, and potential contrast-associated artifacts were assessed for stomach, jejunum, and ileum. Statistical significance was tested by Student's t-test. Distension was slightly better in the stomach with VoLumen as compared with LBG-mannitol whereas LBG-mannitol was found to slightly better distend the small bowel. This difference proved to be statistically significant for the jejunum. A statistically significant difference was detected for intraluminal density with higher densities for VoLumen. This difference, however, did not result in a higher incidence of PET artifacts with VoLumen. LBG-mannitol provides excellent bowel distension, thereby avoiding contrast-associated PET artifacts. If this solution is not available, VoLumen provides a satisfactory alternative for bowel distension without relevant PET artifacts.

  14. Effect of some stabilizing agents on globule characteristics and ...

    African Journals Online (AJOL)

    This study investigated the effects of some stabilizing agents (cassava, maize and bentonite mucilages) on globule characteristics and rheological properties of oil in water emulsions. Emulsions were prepared by mixing varying proportions of the mucilages with Arachis oil in the ratio of 60:40 (oil: water) with the aid of a ...

  15. Wash water waste pretreatment system

    Science.gov (United States)

    1977-01-01

    Investigations were completed on wash waters based on each candidate personal cleansing agent. Evaluations of coagulants, antifoam agents, and the effect of promising antifoams on the chemical precipitation were included. Based on these evaluations two candidate soaps as well as their companion antifoam agents were selected for further work. Operating parameters included the effect of soap concentration, ferric chloride concentration, duration of mixing, and pore size of depth filters on the degree of soap removal. The effect of pressure on water flow through filter cartridges and on the rate of decline of water flow was also investigated. The culmination of the program was the recommendation of a pretreatment concept based on chemical precipitation followed by pressure filtration.

  16. Water-bearing explosive compositions

    Energy Technology Data Exchange (ETDEWEB)

    Gay, G M

    1970-12-21

    An explosive water-bearing composition, with high detonation velocity, comprises a mixture of (1) an inorganic oxidizer salt; (2) nitroglycerine; (3) nitrocellulose; (4) water; and (5) a water thickening agent. (11 claims)

  17. Irrigation System through Intelligent Agents Implemented with Arduino Technology

    Directory of Open Access Journals (Sweden)

    Rodolfo SALAZAR

    2013-11-01

    Full Text Available The water has become in recent years a valuable and increasingly scarce. Its proper use in agriculture has demanded incorporate new technologies, mainly in the area of ICT. In this paper we present a smart irrigation system based on multi-agent architecture using fuzzy logic. The architecture incorporates different types of intelligent agents that an autonomous way monitor and are responsible for deciding if required enable / disable the irrigation system. This project proposes a real and innovative solution to the problem of inadequate water use with current irrigation systems employed in agricultural projects. This article presents the different technologies used, their adaptation to the solution of the problem and briefly discusses the first results obtained.

  18. Extrudates of starch-xanthan gum mixtures as affected by chemical agents and irradiation

    International Nuclear Information System (INIS)

    Hanna, M.A.; Chinnaswamy, R.; Gray, D.R.; Miladinov, V.D.

    1997-01-01

    Mixtures of starch, xanthan gum and either polyvinyl alcohol, epichlorohydrin, valeric acid or adipoyl chloride were extruded. Properties of extrudates including apparent viscosity, water solubility, water absorption indices and extrudate expansion were measured for different proportions of xanthan gum, 70% amylose starch (with or without irradiation) and chemical agents. Extrusion with chemical agents and irradiation changed physical properties of both starch and xanthan gum. Expansions of extrudates were higher than that of starch. Viscosity of extrudates increased with xanthan gum concentration. The addition of 1% (w/w) polyvinyl alcohol had the greatest effect of the chemical agents. Irradiation increased the apparent viscosity of starch-xanthan gum mixtures

  19. Plasma membrane ordering agent pluronic F-68 (PF-68) reduces neurotransmitter uptake and release and produces learning and memory deficits in rats

    Science.gov (United States)

    Clarke, M. S.; Prendergast, M. A.; Terry, A. V. Jr

    1999-01-01

    A substantial body of evidence indicates that aged-related changes in the fluidity and lipid composition of the plasma membrane contribute to cellular dysfunction in humans and other mammalian species. In the CNS, reductions in neuronal plasma membrane order (PMO) (i.e., increased plasma membrane fluidity) have been attributed to age as well as the presence of the beta-amyloid peptide-25-35, known to play an important role in the neuropathology of Alzheimer's disease (AD). These PMO increases may influence neurotransmitter synthesis, receptor binding, and second messenger systems as well as signal transduction pathways. The effects of neuronal PMO on learning and memory processes have not been adequately investigated, however. Based on the hypothesis that an increase in PMO may alter a number of aspects of synaptic transmission, we investigated several neurochemical and behavioral effects of the membrane ordering agent, PF-68. In cell culture, PF-68 (nmoles/mg SDS extractable protein) reduced [3H]norepinephrine (NE) uptake into differentiated PC-12 cells as well as reduced nicotine stimulated [3H]NE release. The compound (800-2400 microg/kg, i.p., resulting in nmoles/mg SDS extractable protein in the brain) decreased step-through latencies and increased the frequencies of crossing into the unsafe side of the chamber in inhibitory avoidance training. In the Morris water maze, PF-68 increased the latencies and swim distances required to locate a hidden platform and reduced the time spent and distance swam in the previous target quadrant during transfer (probe) trials. PF-68 did not impair performance of a well-learned working memory task, the rat delayed stimulus discrimination task (DSDT), however. Studies with 14C-labeled PF-68 indicated that significant (pmoles/mg wet tissue) levels of the compound entered the brain from peripheral (i.p.) injection. No PF-68 related changes were observed in swim speeds or in visual acuity tests in water maze experiments, rotorod

  20. FACT : forgiving agent comfort technology

    NARCIS (Netherlands)

    Zeiler, W.; Wortel, W.; Kamphuis, I.G.; Akkermans, Hans; Jelsma, J.; Bakker, L.

    2005-01-01

    To further reduce energy consumption of office buildings, a new control technology is needed in which the end-user behaviour is integrated. Improvement of the energy consumption is offered by agent-based systems for energy management in buildings, as well as possibilities for enhancing the comfort

  1. Minimizing Erosion and Agro-Pollutants Transport from Furrow Irrigated Fields to the Nearby Water Body Using Spatially-Explicit Agent Based Model and Decision Optimization Platform

    Science.gov (United States)

    Ghoveisi, H.; Al Dughaishi, U.; Kiker, G.

    2017-12-01

    Maintaining water quality in agricultural watersheds is a worldwide challenge, especially where furrow irrigation is being practiced. The Yakima River Basin watershed in south central Washington State, (USA) is an example of these impacted areas with elevated load of sediments and other agricultural products due to runoff from furrow-irrigated fields. Within the Yakima basin, the Granger Drain watershed (area of 75 km2) is particularly challenged in this regard with more than 400 flood-irrigated individual parcels (area of 21 km2) growing a variety of crops from maize to grapes. Alternatives for improving water quality from furrow-irrigated parcels include vegetated filter strip (VFS) implementation, furrow water application efficiency, polyacrylamide (PAM) application and irrigation scheduling. These alternatives were simulated separately and in combinations to explore potential Best Management Practices (BMPs) for runoff-related-pollution reduction in a spatially explicit, agent based modeling system (QnD:GrangerDrain). Two regulatory scenarios were tested to BMP adoption within individual parcels. A blanket-style regulatory scenario simulated a total of 60 BMP combinations implemented in all 409 furrow-irrigated parcels. A second regulatory scenario simulated the BMPs in 119 furrow-irrigated parcels designated as "hotspots" based on a standard 12 Mg ha-1 seasonal sediment load. The simulated cumulative runoff and sediment loading from all BMP alternatives were ranked using Multiple Criteria Decision Analysis (MCDA), specifically the Stochastic Multi-Attribute Acceptability Analysis (SMAA) method. Several BMP combinations proved successful in reducing loads below a 25 NTU (91 mg L-1) regulatory sediment concentration. The QnD:GrangerDrain simulations and subsequent MCDA ranking revealed that the BMP combinations of 5 m-VFS and high furrow water efficiency were highly ranked alternatives for both the blanket and hotspot scenarios.

  2. A new approach in the preparation of dendrimer-based bifunctional diethylenetriaminepentaacetic acid MR contrast agent derivatives.

    Science.gov (United States)

    Nwe, Kido; Xu, Heng; Regino, Celeste Aida S; Bernardo, Marcelino; Ileva, Lilia; Riffle, Lisa; Wong, Karen J; Brechbiel, Martin W

    2009-07-01

    In this paper, we report a new method to prepare and characterize a contrast agent based on a fourth-generation (G4) polyamidoamine (PAMAM) dendrimer conjugated to the gadolinium complex of the bifunctional diethylenetriamine pentaacetic acid derivative (1B4M-DTPA). The method involves preforming the metal-ligand chelate in alcohol prior to conjugation to the dendrimer. The dendrimer-based agent was purified by a Sephadex G-25 column and characterized by elemental analysis. The analysis and SE-HPLC data gave a chelate to dendrimer ratio of 30:1 suggesting conjugation at approximately every other amine terminal on the dendrimer. Molar relaxivity of the agent measured at pH 7.4 displayed a higher value than that of the analogous G4 dendrimer based agent prepared by the postmetal incorporation method (r(1) = 26.9 vs 13.9 mM(-1) s(-1) at 3 T and 22 degrees C). This is hypothesized to be due to the higher hydrophobicity of this conjugate and the lack of available charged carboxylate groups from noncomplexed free ligands that might coordinate to the metal and thus also reduce water exchange sites. Additionally, the distribution populations of compounds that result from the postmetal incorporation route are eliminated from the current product simplifying characterization as quality control issues pertaining to the production of such agents for clinical use as MR contrast agents. In vivo imaging in mice showed a reasonably fast clearance (t(1/2) = 24 min) suggesting a viable agent for use in clinical application.

  3. Water-based binary polyol process for the controllable synthesis of silver nanoparticles inhibiting human and foodborne pathogenic bacteria

    Science.gov (United States)

    The polyol process is a widely used strategy for producing nanoparticles from various reducible metallic precursors; however it requires a bulk polyol liquid reaction with additional protective agents at high temperatures. Here, we report a water-based binary polyol process using low concentrations ...

  4. [Decorporation agents for internal radioactive contamination].

    Science.gov (United States)

    Ohmachi, Yasushi

    2015-01-01

    When radionuclides are accidentally ingested or inhaled, blood circulation or tissue/organ deposition of the radionuclides causes systemic or local radiation effects. In such cases, decorporation therapy is used to reduce the health risks due to their intake. Decorporation therapy includes reduction and/or inhibition of absorption from the gastrointestinal tract, isotopic dilution, and the use of diuretics, adsorbents, and chelating agents. For example, penicillamine is recommended as a chelating agent for copper contamination, and diethylene triamine pentaacetic acid is approved for the treatment of internal contamination with plutonium. During chelation therapy, the removal effect of the drugs should be monitored using a whole-body counter and/or bioassay. Some authorities, such as the National Council on Radiation Protection and Measurements and International Atomic Energy Agency, have reported recommended decorporation agents for each radionuclide. However, few drugs are approved by the US Food and Drug Administration, and many are off-label-use agents. Because many decontamination agents are drugs that have been available for a long time and have limited efficacy, the development of new, higher-efficacy drugs has been carried out mainly in the USA and France. In this article, in addition to an outline of decorporation agents for internal radioactive contamination, an outline of our research on decorporation agents for actinide (uranium and plutonium) contamination and for radio-cesium contamination is also presented.

  5. The Reclamation of Industrial Wastes Inclusive Sulphates by Sulphate-Reducing Bacteria

    Directory of Open Access Journals (Sweden)

    Mária Kušnierová

    2004-12-01

    Full Text Available The objective of our study was to verify experimentally the possibility of using coal mine drainage and gypsum from the „stabilizate“ (the final product from the combustion desulphurisation as the source of sulphate for the cultivation of SRB with the prospect of: purging of mine waste waters inclusive sulphates, recycling of desulphurisation agent (limestone and production of elemental sulphur from hydrogen sulphide. The results confirmed the theoretical assumptions on the use of gypsum, which forms the substantial component of „stabilizate“, as the source of sulphate for sulphate-reducing bacteria, which produce hydrogen sulphide in the process of bacterial reduction of sulphates. They also showed the possibility of recycling the desulphurisation agent – limestone, as well as the realistic alternative of using „stabilizate“ in the production of elemental sulphur which still represents an important raw material needed in chemical, paper or other industries.

  6. Exchanges across land-water-scape boundaries in urban systems: strategies for reducing nitrate pollution.

    Science.gov (United States)

    Cadenasso, M L; Pickett, S T A; Groffman, P M; Band, L E; Brush, G S; Galvin, M F; Grove, J M; Hagar, G; Marshall, V; McGrath, B P; O'Neil-Dunne, J P M; Stack, W P; Troy, A R

    2008-01-01

    Conservation in urban areas typically focuses on biodiversity and large green spaces. However, opportunities exist throughout urban areas to enhance ecological functions. An important function of urban landscapes is retaining nitrogen thereby reducing nitrate pollution to streams and coastal waters. Control of nonpoint nitrate pollution in urban areas was originally based on the documented importance of riparian zones in agricultural and forested ecosystems. The watershed and boundary frameworks have been used to guide stream research and a riparian conservation strategy to reduce nitrate pollution in urban streams. But is stream restoration and riparian-zone conservation enough? Data from the Baltimore Ecosystem Study and other urban stream research indicate that urban riparian zones do not necessarily prevent nitrate from entering, nor remove nitrate from, streams. Based on this insight, policy makers in Baltimore extended the conservation strategy throughout larger watersheds, attempting to restore functions that no longer took place in riparian boundaries. Two urban revitalization projects are presented as examples aimed at reducing nitrate pollution to stormwater, streams, and the Chesapeake Bay. An adaptive cycle of ecological urban design synthesizes the insights from the watershed and boundary frameworks, from new data, and from the conservation concerns of agencies and local communities. This urban example of conservation based on ameliorating nitrate water pollution extends the initial watershed-boundary approach along three dimensions: 1) from riparian to urban land-water-scapes; 2) from discrete engineering solutions to ecological design approaches; and 3) from structural solutions to inclusion of individual, household, and institutional behavior.

  7. Fast and low-temperature sintering of silver complex using oximes as a potential reducing agent for solution-processible, highly conductive electrodes

    International Nuclear Information System (INIS)

    Yoo, Ji Hoon; Park, Su Bin; Kim, Ji Man; Han, Dae Sang; Chae, Jangwoo; Kwak, Jeonghun

    2014-01-01

    Highly conductive, solution-processed silver thin-films were obtained at a low sintering temperature of 100 °C in a short sintering time of 10 min by introducing oximes as a potential reductant for silver complex. The thermal properties and reducibility of three kinds of oximes, acetone oxime, 2-butanone oxime, and one dimethylglyoxime, were investigated as a reducing agent, and we found that the thermal decomposition product of oximes (ketones) accelerated the conversion of silver complex into highly conductive silver at low sintering temperature in a short time. Using the acetone oxime, the silver thin-film exhibited the lowest surface resistance (0.91 Ω sq −1 ) compared to those sing other oximes. The silver thin-film also showed a high reflectance of 97.8%, which is comparable to evaporated silver films. We also demonstrated inkjet printed silver patterns with the oxime-added silver complex inks. (paper)

  8. Water-Based Automobile Paints Potentially Reduce the Exposure of Refinish Painters to Toxic Metals

    Directory of Open Access Journals (Sweden)

    Der-Jen Hsu

    2018-05-01

    Full Text Available Exposure to lead-containing dusts is a global public health concern. This work addresses an important issue of whether eco-friendly water-based paints reduce the exposure potential of auto-repainting workers to metals. With this aim, metal levels in automobile paints and worker metal exposure were measured using both solvent- and water-based paints. The levels of metals, and particularly Pb, Cr (total, Fe, and Cu, in solvent-based paints varied greatly among colors and brands. Lead concentrations ranged from below the detection limit (~0.25 μg/g to 107,928 μg/g (dry film across all samples. In water-based paints, the concentrations of Pb and Cr (total were generally two to three orders of magnitude lower, but the concentrations of Al and Cu exceeded those in some solvent-based paints. The personal short-term exposure of workers who applied water-based paints of popular colors, such as black and white, were generally low, with Pb levels of less than <4 µg/m3 and Cr (total levels of less than 1 µg/m3. Conversely, mean short-term exposure to Pb during the painting of a yellow cab using solvent-based paints were 2028 µg/m3, which was ~14 times the Taiwan short-term permissible exposure limit, while the mean level of exposure to Cr (total was 290 µg/m3, which was well below the exposure limit. This study demonstrates that water-based paints reduce the exposure potential to lead, and highlights the importance of source control in limiting the toxic metals in paints.

  9. Core design study on reduced-moderation water reactors

    International Nuclear Information System (INIS)

    Hiroshi, Akie; Yoshihiro, Nakano; Toshihisa, Shirakawa; Tsutomu, Okubo; Takamichi, Iwamura

    2002-01-01

    The conceptual core design study of reduced-moderation water reactors (RMWRs) with tight-pitched MOX-fuelled lattice has been carried out at JAERI. Several different RMWR core concepts based on both BWR and PWR have been proposed. All the core concepts meet with the aim to achieve both a conversion ratio of 1.0 or larger and negative void reactivity coefficient. As one of these RMWR concepts, the ABWR compatible core is also proposed. Although the conversion ratio of this core is 1.0 and the void coefficient is negative, the discharge burn-up of the fuel was about 25 GWd/t. By adopting a triangular fuel pin lattice for the reduction of moderator volume fraction and modifying axial Pu enrichment distribution, it was aimed to extend the discharge burn-up of ABWR compatible type RMWR. By using a triangular fuel lattice of smaller moderator volume fraction, discharge burn-up of 40 GWd/t seems achievable, keeping the high conversion ratio and the negative void coefficient. (authors)

  10. Reduced chemical warfare agent sorption in polyurethane-painted surfaces via plasma-enhanced chemical vapor deposition of perfluoroalkanes.

    Science.gov (United States)

    Gordon, Wesley O; Peterson, Gregory W; Durke, Erin M

    2015-04-01

    Perfluoralkalation via plasma chemical vapor deposition has been used to improve hydrophobicity of surfaces. We have investigated this technique to improve the resistance of commercial polyurethane coatings to chemicals, such as chemical warfare agents. The reported results indicate the surface treatment minimizes the spread of agent droplets and the sorption of agent into the coating. The improvement in resistance is likely due to reduction of the coating's surface free energy via fluorine incorporation, but may also have contributing effects from surface morphology changes. The data indicates that plasma-based surface modifications may have utility in improving chemical resistance of commercial coatings.

  11. Importance of pressure reducing valves (PRVs) in water supply networks.

    Science.gov (United States)

    Signoreti, R. O. S.; Camargo, R. Z.; Canno, L. M.; Pires, M. S. G.; Ribeiro, L. C. L. J.

    2016-08-01

    Challenged with the high rate of leakage from water supply systems, these managers are committed to identify control mechanisms. In order to standardize and control the pressure Pressure Reducing Valves (VRP) are installed in the supply network, shown to be more effective and provide a faster return for the actual loss control measures. It is known that the control pressure is while controlling the occurrence of leakage. Usually the network is sectored in areas defined by pressure levels according to its topography, once inserted the VRP in the same system will limit the downstream pressure. This work aims to show the importance of VRP as loss reduction for tool.

  12. Uso de agentes microbianos e químico para o controle de Meloidogyne incognita em soja = Use of microbial and chemical agents to control Meloidogyne incognita in soybean

    Directory of Open Access Journals (Sweden)

    Henrique Teixeira Nunes

    2010-07-01

    -emergence only, and two controls. All treatments were inoculated with the nematode, except for a blank control where only water was applied. One control-only treated with the nematode was also included. Aldicarb could reduce the number of eggs and juveniles in the roots. P. lilacinus showed the bestperformance among the biological control agents, reducing the number of eggs and increasing dry root weight. Nemix, a Bacillus sp. based commercial product and P. chlamydosporia could only reduce significantly the number of eggs of the nematode. In this work, it was possible to conclude that the chemical and biological agents showed a moderate activity in the control of M. incognita in soybean.

  13. Radioprotection in E. coli by an agent from M. radiodurans

    Energy Technology Data Exchange (ETDEWEB)

    Goldstein, L S; Gersten, D M; Bruce, A K [State Univ. of New York, Buffalo (USA). Dept. of Biology

    1978-10-01

    An agent extracted from the radioresistant bacterium M. radiodurans was found to protect several strains of E. coli from X-radiation. Optimal radioprotection was observed when the repair-proficient B/r strain was irradiated in the presence of the agent under hypoxic conditions. It is proposed that this agent acts to modify damage incurred in the presence of reduced oxygen concentrations so that this damage might be subsequently repaired.

  14. Magnetic hydrophilic-lipophilic balance sorbent for efficient extraction of chemical warfare agents from water samples.

    Science.gov (United States)

    Singh, Varoon; Purohit, Ajay Kumar; Chinthakindi, Sridhar; Goud D, Raghavender; Tak, Vijay; Pardasani, Deepak; Shrivastava, Anchal Roy; Dubey, Devendra Kumar

    2016-02-19

    Magnetic hydrophilic-lipophilic balance (MHLB) hybrid resin was prepared by precipitation polymerization using N-vinylpyrrolidone (PVP) and divinylbenzene (DVB) as monomers and Fe2O3 nanoparticles as magnetic material. These resins were successfully applied for the extraction of chemical warfare agents (CWAs) and their markers from water samples through magnetic dispersive solid-phase extraction (MDSPE). By varying the ratios of monomers, resin with desired hydrophilic-lipophilic balance was prepared for the extraction of CWAs and related esters of varying polarities. Amongst different composites Fe2O3 nanoparticles coated with 10% PVP+90% DVB exhibited the best recoveries varying between 70.32 and 97.67%. Parameters affecting the extraction efficiencies, such as extraction time, desorption time, nature and volume of desorption solvent, amount of extraction sorbent and the effect of salts on extraction were investigated. Under the optimized conditions, linearity was obtained in the range of 0.5-500 ng mL(-1) with correlation ranging from 0.9911-0.9980. Limits of detection and limits of quantification were 0.5-1.0 and 3.0-5.0 ng mL(-1) respectively with RSDs varying from 4.88-11.32% for markers of CWAs. Finally, the developed MDSPE method was employed for extraction of analytes from water samples of various sources and the OPCW proficiency test samples. Copyright © 2016 Elsevier B.V. All rights reserved.

  15. Evaluation of tumor invasion in gastric carcinoma with CT using water as an oral contrast agent in prone position

    International Nuclear Information System (INIS)

    Chung, Jin Il; Lee, Jong Tae; Yoo, Hyung Sik; Lee, Byung Hee; Bae, Jong Yup

    1994-01-01

    To evaluate the accuracy of CT using water as an oral contrast material in a prone position in determining the depth of tumor invasion in gastric cancer patients. Thirty three patients(19 male, 14 female) with surgically confirmed gastric cancer were studied. We performed CT in a prone position after ingestion of 1 liter of pure water. CT findings were classified into 4 groups by the morphologic appearance of infiltrates in the perigastric fat plane: normal perigastric fat(S0), fine mottled densities(S1), irregular aggregated or liner densities(S2) and direct extension and invasion of tumor into contiguous structures(S3). Also we prospectively compared the CT staging with pathologic T staging according to the TNM systems. The overall accuracy of CT staging in determining the pathologic T factor was 69.6%. As we regarded T1 and T2 lesions as one group on CT, the accuracy of CT staging was increased to 80.2% because of a limitation of CT for distinguishing T1 from T2 lesions. Prone position CT using water as an oral contrast agent is quite accurate in determining the T staging of gastric carcinoma

  16. Forage Options for Dairy Farms with Reduced Water Availability in the Southern Murray Darling Basin of Australia

    Directory of Open Access Journals (Sweden)

    Mary-Jane Rogers

    2017-12-01

    Full Text Available The dairy industry in the southern Murray Darling Basin region of Australia is a major consumer of irrigation water because rainfall is low relative to evapotranspiration and the industrys relies heavily on irrigated temperate pastures and fodder crops. Water reforms, and potential climate change scenarios for this region suggest that there will be an overall decline in rainfall and water available for irrigation in the future. For the irrigated dairy industry to remain economically viable, there is a need for dairy farmers to improve the water productivity (WP of their forage systems and to be able to respond to year-to-year, and within year, variation in water availability. Researchers and dairy farmers are evaluating strategies to increase WP. These include: (i selecting better-adapted species for current and predicted climatic conditions; (ii using species that can survive and still be productive under reduced irrigation and then recover when full irrigation is restored; (iii modifying irrigation strategies to reduce water use whilst maintaining WP; and (iv grazing management strategies that facilitate the survival during, and recovery after, periods of moisture stress. This review will examine these strategies and discusses their potential to optimise forage production from irrigation water inputs so that the dairy industry in the southern Murray Darling Basin remains viable in the future.

  17. Capillary gas chromatographic analysis of nerve agents using large volume injections. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Deinum, T.; Nieuwenhuy, C.

    1994-11-01

    The procedure developed at TNO-Prins Maurits Laboratory (TNO-PML) for the verification of intact organophosphorus chemical warfare agents in water samples was improved. The last step in this procedure, the laborious and non-reproducible transfer of an ethyl acetate extract onto a Tenax-adsorption tube followed by thermal desorption of the Tenax-tube, was replaced by large volume injection of the extract onto a capillary gas chromatographic system. The parameters controlling the injection of a large volume of an extract (200 ul) were investigated and optimized. As ethyl acetate caused severe problems, potential new solvents were evaluated. With the improved procedure, the nerve agents sarin, tabun, soman, diisopropyl fluorophosphate (DFP) and VX could be determined in freshly prepared water samples at pg/ml (ppt) levels. The fate of the nerve agents under study in water at two pH`s (4.8 and 6) was investigated. For VX, the pH should be adjusted before extraction. Moreover, it is worthwhile to acidify water samples to diminish hydrolysis.

  18. Agent-Based Modelling of Agricultural Water Abstraction in Response to Climate, Policy, and Demand Changes: Results from East Anglia, UK

    Science.gov (United States)

    Swinscoe, T. H. A.; Knoeri, C.; Fleskens, L.; Barrett, J.

    2014-12-01

    Freshwater is a vital natural resource for multiple needs, such as drinking water for the public, industrial processes, hydropower for energy companies, and irrigation for agriculture. In the UK, crop production is the largest in East Anglia, while at the same time the region is also the driest, with average annual rainfall between 560 and 720 mm (1971 to 2000). Many water catchments of East Anglia are reported as over licensed or over abstracted. Therefore, freshwater available for agricultural irrigation abstraction in this region is becoming both increasingly scarce due to competing demands, and increasingly variable and uncertain due to climate and policy changes. It is vital for water users and policy makers to understand how these factors will affect individual abstractors and water resource management at the system level. We present first results of an Agent-based Model that captures the complexity of this system as individual abstractors interact, learn and adapt to these internal and external changes. The purpose of this model is to simulate what patterns of water resource management emerge on the system level based on local interactions, adaptations and behaviours, and what policies lead to a sustainable water resource management system. The model is based on an irrigation abstractor typology derived from a survey in the study area, to capture individual behavioural intentions under a range of water availability scenarios, in addition to farm attributes, and demographics. Regional climate change scenarios, current and new abstraction licence reforms by the UK regulator, such as water trading and water shares, and estimated demand increases from other sectors were used as additional input data. Findings from the integrated model provide new understanding of the patterns of water resource management likely to emerge at the system level.

  19. Water contamination reduces the tolerance of coral larvae to thermal stress.

    Directory of Open Access Journals (Sweden)

    Andrew P Negri

    Full Text Available Coral reefs are highly susceptible to climate change, with elevated sea surface temperatures (SST posing one of the main threats to coral survival. Successful recruitment of new colonies is important for the recovery of degraded reefs following mortality events. Coral larvae require relatively uncontaminated substratum on which to metamorphose into sessile polyps, and the increasing pollution of coastal waters therefore constitutes an additional threat to reef resilience. Here we develop and analyse a model of larval metamorphosis success for two common coral species to quantify the interactive effects of water pollution (copper contamination and SST. We identify thresholds of temperature and pollution that prevent larval metamorphosis, and evaluate synergistic interactions between these stressors. Our analyses show that halving the concentration of Cu can protect corals from the negative effects of a 2-3°C increase in SST. These results demonstrate that effective mitigation of local impacts can reduce negative effects of global stressors.

  20. EPR and DNP Properties of Certain Novel Single Electron Contrast Agents Intended for Oximetric Imaging

    DEFF Research Database (Denmark)

    Ardenkjær-Larsen, J. H.; Laursen, I; Leunbach, I.

    1998-01-01

    Parameters of relevance to oximetry with Overhauser magnetic resonance imaging (OMRI) have been measured for three single electron contrast agents of the triphenylmethyl type. The single electron contrast agents are stable and water soluble. Magnetic resonance properties of the agents have been...... examined with electron paramagnetic resonance (EPR), nuclear magnetic resonance (NMR), and dynamic nuclear polarization (DNP) at 9.5 mT in water, isotonic saline, plasma, and blood at 23 and 37°C. The relaxivities of the agents are about 0.2–0.4 mM−1s−1and the DNP enhancements extrapolate close...... to the dipolar limit. The agents have a single, narrow EPR line, which is analyzed as a Voigt function. The linewidth is measured as a function of the agent concentration and the oxygen concentration. The concentration broadenings are about 1–3 μT/mM and the Lorentzian linewidths at infinite dilution are less...

  1. Contrast agent choice for intravenous coronary angiography

    International Nuclear Information System (INIS)

    Zeman, H.D.; Siddons, D.P.

    1990-01-01

    The screening of the general population for coronary artery disease would be practical if a method existed for visualizing the extent of occlusion after an intravenous injection of contrast agent. Measurements performed with monochromatic synchrotron radiation X-rays and an iodine-containing contrast agent at the Stanford Synchrotron Radiation Laboratory have shown that such an intravenous angiography procedure would be possible with an adequately intense monochromatic X-ray source. Because of the size and cost of synchrotron radiation facilities it would be desirable to make the most efficient use of the intensity available, while reducing as much as possible the radiation dose experienced by the patient. By choosing contrast agents containing elements with a higher atomic number than iodine, it is possible to both improve the image quality and reduce the patient radiation dose, while using the same synchrotron radiation source. By using Si monochromator crystals with a small mosaic spread, it is possible to increase the X-ray flux available for imaging by over an order of magnitude, without any changes in the storage ring or wiggler magnet. The most critical imaging task for intravenous coronary angiography utilizing synchrotron radiation X-rays is visualizing a coronary artery through the left ventricle or aorta which also contain contrast agent. Calculations have been made of the signal to noise ratio expected for this imaging task for various contrast agents with atomic numbers between that of iodine and bismuth. The X-ray energy spectrum of the X-17 superconduction wiggler beam line at the National Synchrotron Light Source at Brookhaven National Laboratory has been used for these calculations. Both perfect Si crystals and Si crystals with a small mosaic spread are considered as monochromators. Contrast agents containing Gd or Yb seem to have about the optimal calculated signal to noise ratio. (orig./HSI)

  2. Diagnostic agents containing albumin and methods for making same

    International Nuclear Information System (INIS)

    Saklad, E.L.; Layne, W.W.

    1981-01-01

    This patent specification outlines a method for providing a diagnostic agent for use in radiological testing, comprising the production of an admixture of a source of radionuclide ion (sup(99m)Tc), a reducing agent (source of stannous ions at a pH below 7) and a stabilized, defatted human albumin being sufficiently purified for an aqueous solution not to become cloudy for at least an hour at a pH of 4 or below. Other aspects of the patent provide for a method of producing a radiodiagnostic kit of the above components, packaged in a sealed sterile non-pyrogenic container, and also a method of concentrating sup(99m)Tc in vivo in a target mammalian tissue, by intravenous administration of a mixture of sup(99m)Tc, a reducing agent, and delipidized serum albumin. (U.K.)

  3. Analytical control of reducing agents on uranium/plutonium partitioning at purex process

    International Nuclear Information System (INIS)

    Araujo, Izilda da Cruz de

    1995-01-01

    Spectrophotometric methods for uranium (IV), hydrazine (N 2 H 4 ) and its decomposition product hydrazoic acid(HN 3 ), and hydroxylamine (NH 2 OH) determinations were developed aiming their applications for the process control of CELESTE I installation at IPEN/CNEN-SP. These compounds are normally present in the U/Pu partitioning phase of the spent nuclear treatment via PUREX process. The direct spectrophotometry was used for uranium (IV) analysis in nitric acid-hydrazine solutions based on the absorption measurement at 648 nm. The azomethine compound formed by reaction of hydrazine and p-dimethylamine benzaldehyde with maximum absorption at 457 nm was the basis for the specific analytical method for hydrazine determination. The hydrazoic acid analysis was performed indirectly by its conversion into ferric azide complex with maximum absorption at 465 nm. The hydroxylamine detection was accomplished based on its selective oxidation to nitrous acid which is easily analyzed by the reaction with Griess reagent. The resulted azocompound gas a maximum absorption at 520 nm. The sensibility of 1,4x10 -6 M for U(IV) with 0,8% of precision, 1,6x10 -6 M for hydrazine with 0,8% of precision, 2,3x10 -6 M hydrazoic acid with 0,9% of precision and 2,5x10 -6 M for hydroxylamine with 0,8% of precision were achieved. The interference studies have shown that each reducing agent can be determined in the presence of each other without any interference. Uranium(VI) and plutonium have also shown no interference in these analysis. The established methods were adapted to run inside glove-boxes by using an optical fiber colorimetry and applied to process control of the CELESTE I installation. The results pointed out that the methods are reliable and safety in order to provide just-in-time information about process conditions. (author)

  4. Influence of Bleaching Agents on Color and Translucency of Aged Resin Composites.

    Science.gov (United States)

    Lago, Maristela; Mozzaquatro, Lisandra R; Rodrigues, Camila; Kaizer, Marina R; Mallmann, André; Jacques, Letícia B

    2017-09-01

    Evaluate the influence of two bleaching agents (16% carbamide peroxide-CP and 35% hydrogen peroxide-HP) on color and translucency of one resin composite (Filtek Z350 XT) in two opacities (enamel and dentin) previously aged in deionized water or red wine. Sixty specimens of each material were divided in two groups (n = 30): aged in water or red wine for 14 days. Then the specimens were divided in three subgroups (n = 10): control/no treatment, treated with 16% carbamide peroxide (Mix Night), treated with 35% hydrogen peroxide (Mix One). Color readings were performed 24 hours after polishing (baseline); after the 14 days of aging; and after bleaching treatment. Color coordinates CIE L*a*b* were measured using a spectrophotometer (SP60 X-Rite). Color change (CIEDE2000) and translucency parameter were calculated. Data were analyzed with repeated measures two-way ANOVA, and Student-Newman-Keuls tests (5%). Bleaching decreased color change in stained resin composites (aged in red wine), whereas increased it in non-stained enamel resin composites (aged in water). CP had better bleaching results with stained resin composites than HP. Translucency of non-stained dentin resin composite decreased with aging, but did not change with bleaching. For stained resin composites, aging caused reduced translucency, whereas bleaching increased it. Effective bleaching of discolored resin composites aged in an acidic and alcoholic media rich in staining agents was achieved, improving color and translucency. Carbamide peroxide showed better performance than hydrogen peroxide for the bleaching of stained resin composites. (J Esthet Restor Dent 29:368-377, 2017). © 2016 Wiley Periodicals, Inc.

  5. Superparamagnetic nanoparticle-inclusion microbubbles for ultrasound contrast agents

    International Nuclear Information System (INIS)

    Yang Fang; Li Yixin; Chen Zhongping; Gu Ning; Li Ling; Wu Junru

    2008-01-01

    We have developed a new type of ultrasound (US) contrast agent, consisting of a gas core, a layer of superparamagnetic iron oxide Fe 3 O 4 nanoparticles (SPIO) and an oil in water outermost layer. The newly developed US contrast agent microbubbles have a mean diameter of 760 nm with a polydisperity index (PI) of 0.699. Our in vitro and in vivo experiments have shown that they have the following advantages compared to gas-encapsulated microbbubbles without SPIO inclusion: (1) they provide better contrast for US images; (2) the SPIO-inclusion microbubbles generate a higher backscattering signal; the mean grey scale is 97.9, which is 38.6 higher than that of microbubbles without SPIO; and (3) since SPIO can also serve as a contrast agent of magnetic resonance images (MRI) in vitro, they can be potentially used as contrast agents for double-modality (MRI and US) clinical studies.

  6. Incomplete water securitization in coupled hydro-human production sytems

    Science.gov (United States)

    van den Boom, B.; Pande, S.

    2012-04-01

    Due to the dynamics, the externalities and the contingencies involved in managing local water resource for production, the water allocation at basin-level is a subtle balance between laws of nature (gravity; flux) and laws of economics (price; productivity). We study this balance by looking at inter-temporal basin-level water resource allocations in which subbasins enjoy a certain degree of autonomy. Each subbasin is represented as an economic agent i, following a gravity ordering with i=1 representing the most upstream area and i=I the downstream boundary. The water allocation is modeled as a decentralized equilibrium in a coupled conceptual hydro-human production system. Agents i=1,2,...,I in the basin produce a composite good according to a technology that requires water as a main input and that is specific to the subbasin. Agent i manages her use Xi and her storage Si, conceptualizing surface and subsurface water, of water with the purpose of maximizing the utility derived from consumption Ci of the composite good, where Ci is a scalar and Xi and Si are vectors which are composed of one element for each time period and for each contingency. A natural way to consume the good would be to absorb the own production. Yet, the agent may have two more option, namely, she might get a social transfer from other agents or she could use an income from trading water securities with her contiguous neighbors. To study these options, we compare water allocations (Ci, Xi, Si) all i=1,2,...,I for three different settings. We look at allocations without water securitization (water autarky equilibrium EA) first. Next, we describe the imaginary case of full securitization (contingent water markets equilibrium ECM) and, in between, we study limited securitization (incomplete water security equilibrium EWS). We show that allocations under contingent water markets ECM are efficient in the sense that, for the prevailing production technologies, no other allocation exists that is at

  7. Effectiveness of oat and rye cover crops in reducing nitrate losses in drainage water

    Science.gov (United States)

    A significant portion of the NO3 from agricultural fields that contaminates surface waters in the Midwest Corn Belt is transported to streams or rivers by subsurface drainage systems or “tiles”. Previous research has shown that N fertilizer management alone is not sufficient for reducing NO3 concent...

  8. Distinct germination response of endangered and common arable weeds to reduced water potential.

    Science.gov (United States)

    Rühl, A T; Eckstein, R L; Otte, A; Donath, T W

    2016-01-01

    Arable weeds are one of the most endangered species groups in Europe. Modern agriculture and intensive land-use management are the main causes of their dramatic decline. However, besides the changes in land use, climate change may further challenge the adaptability of arable weeds. Therefore, we investigated the response pattern of arable weeds to different water potential and temperature regimes during the phase of germination. We expected that endangered arable weeds would be more sensitive to differences in water availability and temperature than common arable weeds. To this end, we set up a climate chamber experiment where we exposed seeds of five familial pairs of common and endangered arable weed species to different temperatures (5/15, 10/20 °C) and water potentials (0.0 to -1.2 MPa). The results revealed a significant relationship between the reaction of arable weed species to water availability and their Red List status. The effects of reduced water availability on total germination, mean germination time and synchrony were significantly stronger in endangered than in common arable weeds. Therefore, global climate change may present a further threat to the survival of endangered arable weed species. © 2015 German Botanical Society and The Royal Botanical Society of the Netherlands.

  9. Chemical water shutoff profile research status and development trends

    Science.gov (United States)

    Xu, L. T.

    2017-08-01

    Excess water production is now a common problem encountered in almost every water flooding mature oilfield. The exploitation of oil field is faced with great challenge because of the decrease of oil field production. For the development of high water cut rare the status quo chemical water shutoff profile control technology is an important solution to solve this problem. Oilfield chemical water shutoff has important application prospects. This paper analyzes the water shutoff profile control and water shutoff profile control agent currently oilfield applications, moreover the use and development of blocking agent profile technology is to improve reservoir recovery and propose solutions. With the constant increase in water cut, profile technology should be simple, efficient, practical and profile control agent of development should be economic, environmental, and long period

  10. A Skeleton Based Programming Paradigm for Mobile Multi-Agents on Distributed Systems and Its Realization within the MAGDA Mobile Agents Platform

    Directory of Open Access Journals (Sweden)

    R. Aversa

    2008-01-01

    Full Text Available Parallel programming effort can be reduced by using high level constructs such as algorithmic skeletons. Within the MAGDA toolset, supporting programming and execution of mobile agent based distributed applications, we provide a skeleton-based parallel programming environment, based on specialization of Algorithmic Skeleton Java interfaces and classes. Their implementation include mobile agent features for execution on heterogeneous systems, such as clusters of WSs and PCs, and support reliability and dynamic workload balancing. The user can thus develop a parallel, mobile agent based application by simply specialising a given set of classes and methods and using a set of added functionalities.

  11. Systematic review and meta-analysis of the effectiveness of antiseptic agents for meatal cleaning in the prevention of catheter-associated urinary tract infections.

    Science.gov (United States)

    Fasugba, O; Koerner, J; Mitchell, B G; Gardner, A

    2017-03-01

    Catheter-associated urinary tract infections (CAUTIs) are among the most common healthcare-associated infections. Antiseptic cleaning of the meatal area before and during catheter use may reduce the risk of CAUTIs. To undertake a systematic review of the literature and meta-analysis of studies investigating the effectiveness of antiseptic cleaning before urinary catheter insertion and during catheter use for prevention of CAUTIs. Electronic databases were searched to identify randomized controlled trials. Pooled odds ratios (ORs) and 95% confidence intervals (CIs) were calculated and compared across intervention and control groups using DerSimonian-Laird random-effects model. Subgroup analyses were performed. Heterogeneity was estimated using the I 2 statistic. In total, 2665 potential papers were identified; of these, 14 studies were eligible for inclusion. There was no difference in the incidence of CAUTIs when comparing antiseptic and non-antiseptic agents (pooled OR 0.90, 95% CI 0.73-1.10; P=0.31), or when comparing different agents: povidone-iodine vs routine care; povidone-iodine vs soap and water; chlorhexidine vs water; povidone-iodine vs saline; povidone-iodine vs water; and green soap and water vs routine care (P>0.05 for all). Comparison of an antibacterial agent with routine care indicated near significance (P=0.06). There was no evidence of heterogeneity (I 2 =0%; P>0.05). Subgroup analyses showed no difference in the incidence of CAUTIs in terms of country, setting, risk of bias, sex and frequency of administration. There were no differences in CAUTI rates, although methodological issues hamper generalizability of this finding. Antibacterial agents may prove to be significant in a well-conducted study. The present results provide good evidence to inform infection control guidelines in catheter management. Copyright © 2016 The Healthcare Infection Society. Published by Elsevier Ltd. All rights reserved.

  12. Use of a charge reducing agent to enable intact mass analysis of cysteine-linked antibody-drug-conjugates by native mass spectrometry

    Directory of Open Access Journals (Sweden)

    Kamila J. Pacholarz

    2016-06-01

    Full Text Available Antibody-drug-conjugates (ADC are a growing class of anticancer biopharmaceuticals. Conjugation of cysteine linked ADCs, requires initial reduction of mAb inter-chain disulfide bonds, as the drugs are attached via thiol chemistry. This results in the active mAb moiety being transformed from a covalently linked tetramer to non-covalently linked complexes, which hinders precise determination of drug load with LC–MS. Here, we show how the addition of the charge reducing agent triethylammonium acetate (TEAA preserves the intact mAb structure, is well suited to the study of cysteine linked conjugates and facilitates easy drug load determination by direct infusion native MS.

  13. A green and efficient method to produce graphene for electrochemical capacitors from graphene oxide using sodium carbonate as a reducing agent

    Science.gov (United States)

    Jin, Yuhong; Huang, Shuo; Zhang, Mei; Jia, Mengqiu; Hu, Dong

    2013-03-01

    The green and efficient synthesis of graphene using sodium carbonate (Na2CO3) as a chemical reducing agent was studied. Extensive characterization confirmed the formation of graphene from graphene oxide using a Na2CO3 solution. The C/O atomic ratio of the as-prepared graphene has increased from 2.48 to 8.15 after reduction as determined by X-ray photoelectron spectroscopy. The conductivity of as-prepared graphene sheets is as high as 10 S m-1. After electrochemical measurements, gravimetric capacitances of 228 and 166 F g-1 at current densities of 5 and 25 mA cm-2, respectively, were obtained with KOH electrolyte.

  14. Liposomes as carriers of imaging agents

    International Nuclear Information System (INIS)

    Caride, V.J.

    1985-01-01

    This review discusses the utilization of liposomes as imaging agents or as vehicles for contrast materials. The initial approach was the use of radiolabeled liposomes for scintigraphy. To this end liposomes were either labeled in the lipid membrane or aqueous radiotracers were incorporated inside the lipid vesicles. The lipid labeling provides a more stable association of the radioactive tracer and the lipid vesicles, while the use of water-soluble radiotracers provides a wider selection of compounds. Early attempts at selective tumor imaging using radiolabeled liposomes were unsuccessful. The use of monoclonal antibodies attached to liposomes offers new hopes. Several strategies have been proposed in this respect and several others can be envisioned. The use of liposomes permits the use of several administration routes for imaging agents. Of particular interest is the subcutaneous administration for lymph node visualization. Liposomes offer clear advantages over most radiocontrast agents for prolonged hepatosplenic contrast enhancement. This is particularly relevant in the diagnostic evaluation of the abdomen with computed tomography. Important research efforts are being conducted in this area. Two different approaches have been advanced: the incorporation of contrast agents into liposomes and the preparation of radiopaque liposomes from radiodense lipids. Nuclear magnetic resonance imaging can also benefit from contrast agents. Several centers are investigating this exciting field using liposomes loaded with paramagnetic elements.152 references

  15. Subsurface watering resulted in reduced soil N2O and CO2 emissions and their global warming potentials than surface watering

    Science.gov (United States)

    Wei, Qi; Xu, Junzeng; Yang, Shihong; Liao, Linxian; Jin, Guangqiu; Li, Yawei; Hameed, Fazli

    2018-01-01

    Water management is an important practice with significant effect on greenhouse gases (GHG) emission from soils. Nitrous oxide (N2O) and carbon dioxide (CO2) emissions and their global warming potentials (GWPs) from subsurface watering soil (SUW) were investigated, with surface watering (SW) as a control. Results indicated that the N2O and CO2 emissions from SUW soils were somewhat different to those from SW soil, with the peak N2O and CO2 fluxes from SUW soil reduced by 28.9% and 19.4%, and appeared 72 h and 168 h later compared with SW. The fluxes of N2O and CO2 from SUW soils were lower than those from SW soil in both pulse and post-pulse periods, and the reduction was significantly (p0.1) lower that from SW soil. Moreover, N2O and CO2 fluxes from both watering treatments increased exponentially with increase of soil water-filled pore space (WFPS) and temperature. Our results suggest that watering soil from subsurface could significantly reduce the integrative greenhouse effect caused by N2O and CO2 and is a promising strategy for soil greenhouse gases (GHGs) mitigation. And the pulse period, contributed most to the reduction in emissions of N2O and CO2 from soils between SW and SUW, should be a key period for mitigating GHGs emissions. Response of N2O and CO2 emissions to soil WFPS and temperature illustrated that moisture was the dominant parameters that triggering GHG pulse emissions (especially for N2O), and temperature had a greater effect on the soil microorganism activity than moisture in drier soil. Avoiding moisture and temperature are appropriate for GHG emission at the same time is essential for GHGs mitigation, because peak N2O and CO2 emission were observed only when moisture and temperature are both appropriate.

  16. Agent-specific learning signals for self-other distinction during mentalising.

    Directory of Open Access Journals (Sweden)

    Sam Ereira

    2018-04-01

    Full Text Available Humans have a remarkable ability to simulate the minds of others. How the brain distinguishes between mental states attributed to self and mental states attributed to someone else is unknown. Here, we investigated how fundamental neural learning signals are selectively attributed to different agents. Specifically, we asked whether learning signals are encoded in agent-specific neural patterns or whether a self-other distinction depends on encoding agent identity separately from this learning signal. To examine this, we tasked subjects to learn continuously 2 models of the same environment, such that one was selectively attributed to self and the other was selectively attributed to another agent. Combining computational modelling with magnetoencephalography (MEG enabled us to track neural representations of prediction errors (PEs and beliefs attributed to self, and of simulated PEs and beliefs attributed to another agent. We found that the representational pattern of a PE reliably predicts the identity of the agent to whom the signal is attributed, consistent with a neural self-other distinction implemented via agent-specific learning signals. Strikingly, subjects exhibiting a weaker neural self-other distinction also had a reduced behavioural capacity for self-other distinction and displayed more marked subclinical psychopathological traits. The neural self-other distinction was also modulated by social context, evidenced in a significantly reduced decoding of agent identity in a nonsocial control task. Thus, we show that self-other distinction is realised through an encoding of agent identity intrinsic to fundamental learning signals. The observation that the fidelity of this encoding predicts psychopathological traits is of interest as a potential neurocomputational psychiatric biomarker.

  17. Towards MRI T2 contrast agents of increased efficiency

    Energy Technology Data Exchange (ETDEWEB)

    Branca, Marlène [CNRS, LCC (Laboratoire de Chimie de Coordination), 205, route de Narbonne, F-31077 Toulouse (France); Université de Toulouse, UPS, INPT, LCC, F-31077 Toulouse (France); Marciello, Marzia, E-mail: marziamarciello@icmm.csic.es [Instituto de Ciencia de Materiales de Madrid (ICMM-CSIC), Sor Juana Inés de la Cruz, 3, Cantoblanco, 28049 Madrid (Spain); Ciuculescu-Pradines, Diana [CNRS, LCC (Laboratoire de Chimie de Coordination), 205, route de Narbonne, F-31077 Toulouse (France); Université de Toulouse, UPS, INPT, LCC, F-31077 Toulouse (France); Respaud, Marc [LPCNO, INSA, 135 Avenue de Rangueil, 31077 Toulouse Cedex 4 (France); Morales, Maria del Puerto [Instituto de Ciencia de Materiales de Madrid (ICMM-CSIC), Sor Juana Inés de la Cruz, 3, Cantoblanco, 28049 Madrid (Spain); Serra, Raphael; Casanove, Marie-José [CNRS, CEMES (Centre d' Elaboration des Matériaux et d' Etudes Structurales) (France); Amiens, Catherine, E-mail: catherine.amiens@lcc-toulouse.fr [CNRS, LCC (Laboratoire de Chimie de Coordination), 205, route de Narbonne, F-31077 Toulouse (France); Université de Toulouse, UPS, INPT, LCC, F-31077 Toulouse (France)

    2015-03-01

    Magnetic nanoparticles can be efficient contrast agents for T2 weighted magnetic resonance imaging (MRI) after tuning of some key parameters such as size, surface state, colloidal stability and magnetization, thus motivating the development of new synthetic pathways. In this paper we report the effects of surface coating on the efficiency of two different types of iron based nanoparticles (NPs) as MRI contrast agents. Starting from well-defined hydrophobic iron oxide nanospheres and iron nanocubes of 13 nm size, we have used three methods to increase their hydrophilicity and transfer them into water: surface ligand modification, ligand exchange or encapsulation. The NPs obtained have been characterized by dynamic light scattering and transmission electron microscopy, and the relaxivities of their stable colloidal solutions in water have been determined. Among all samples prepared, iron nanocubes coated by silica display the highest relaxivity (r{sub 2}) value: 628 s{sup −1} mM{sup −1}. - Highlights: • Surface coating effect on the efficiency of iron based nanoparticles (NPs) as MRI contrast agents. • Synthesis of 2 different types of hydrophobic iron based NPs: iron oxide nanospheres and iron nanocubes (13 nm). • Development of three different procedures to stabilize iron based NPs in water. • Iron nanocubes coated by silica displayed the highest r{sub 2} value (628 s{sup −1} mM{sup −1})

  18. CARNAUBA WAX USED AS AN HYDROPHOBIC AGENT FOR EXPANDED VERMICULITE

    Directory of Open Access Journals (Sweden)

    M.A.F. Melo

    1998-03-01

    Full Text Available This work deals with the use of carnauba wax as an expansion and hydrophobicity agent for vermiculite, to be utilized in the sorption process of oil in water. Evaluation of the system (oil-water-hydrophobic vermiculite submersion percentage was considered in assessing the performance of vermiculite in comparison to a Mexican turf. Carnauba wax seems to be more efficient in both fresh and salt waters.

  19. Portable Solid Phase Micro-Extraction Coupled with Ion Mobility Spectrometry System for On-Site Analysis of Chemical Warfare Agents and Simulants in Water Samples

    Science.gov (United States)

    Yang, Liu; Han, Qiang; Cao, Shuya; Yang, Jie; Yang, Junchao; Ding, Mingyu

    2014-01-01

    On-site analysis is an efficient approach to facilitate analysis at the location of the system under investigation as it can result in more accurate, more precise and quickly available analytical data. In our work, a novel self-made thermal desorption based interface was fabricated to couple solid-phase microextraction with ion mobility spectrometry for on-site water analysis. The portable interface can be connected with the front-end of an ion mobility spectrometer directly without other modifications. The analytical performance was evaluated via the extraction of chemical warfare agents and simulants in water samples. Several parameters including ionic strength and extraction time have been investigated in detail. The application of the developed method afforded satisfactory recoveries ranging from 72.9% to 114.4% when applied to the analysis of real water samples. PMID:25384006

  20. Investigation of oil recovery improvement by coupling an interfacial tension agent and a mobility control agent in light oil reservoirs. Second annual report, October 1993--September 1994

    Energy Technology Data Exchange (ETDEWEB)

    Pitts, M.J.

    1995-04-01

    {open_quotes}Investigation of Oil Recovery Improvement by Coupling an Interfacial Tension Agent and a Mobility Control Agent in Light Oil Reservoirs{close_quotes} is studying two major areas concerning co-injecting an interfacial tension reduction agent(s) and a mobility control agent. The first area defines the interactions of alkaline agents, surfactants, and polymers on a fluid-fluid and a fluid-rock basis. The second area concerns the economic improvement of the combined technology. This report continues the fluid-fluid interaction evaluations and begins the fluid-rock studies. Fluid-fluid interfacial tension work determined that replacing sodium ion with either potassium or ammonium ion in solutions with interfacial tension reduction up to 19,600 fold was detrimental and had little or no effect on alkali-surfactant solutions with interfacial tension reduction of 100 to 200 fold. Reservoir brine increases interfacial tension between crude oil and alkaline-surfactant solutions. Na{sub 2}CO{sub 3}-surfactant solutions maintained ultra low and low interfacial tension values better than NaOH-surfactant solutions. The initial phase of the fluid-rock investigations was adsorption studies. Surfactant adsorption is reduced when co-dissolved with alkali. Na{sub 2}CO{sub 3} and Na{sub 3}PO{sub 4} are more efficient at reducing surfactant adsorption than NaOH. When polymer is added to the surfactant solution, surfactant adsorption is reduced as well. When both polymer and alkali are added, polymer is the dominate component, reducing the Na{sub 2}CO{sub 3} and NaOH effect on adsorption. Substituting sodium ion with potassium or ammonium ion increased or decreased surfactant adsorption depending on surfactant structure with alkali having a less significant effect. No consistent change of surfactant adsorption with increasing salinity was observed in the presence or absence of alkali or polymer.