WorldWideScience

Sample records for water desalination complexes

  1. Complex admixtures of clathrate hydrates in a water desalination method

    Science.gov (United States)

    Simmons, Blake A [San Francisco, CA; Bradshaw, Robert W [Livermore, CA; Dedrick, Daniel E [Berkeley, CA; Anderson, David W [Riverbank, CA

    2009-07-14

    Disclosed is a method that achieves water desalination by utilizing and optimizing clathrate hydrate phenomena. Clathrate hydrates are crystalline compounds of gas and water that desalinate water by excluding salt molecules during crystallization. Contacting a hydrate forming gaseous species with water will spontaneously form hydrates at specific temperatures and pressures through the extraction of water molecules from the bulk phase followed by crystallite nucleation. Subsequent dissociation of pure hydrates yields fresh water and, if operated correctly, allows the hydrate-forming gas to be efficiently recycled into the process stream.

  2. Stacked microbial desalination cells to enhance water desalination efficiency.

    Science.gov (United States)

    Chen, Xi; Xia, Xue; Liang, Peng; Cao, Xiaoxin; Sun, Haotian; Huang, Xia

    2011-03-15

    Microbial desalination cell (MDC) is a new method to obtain clean water from brackish water using electricity generated from organic matters by exoelectrogenic bacteria. Anions and cations, derived from salt solution filled in the desalination chamber between the anode and cathode, move to the anode and cathode chambers under the force of electrical field, respectively. On the basis of the primitive single-desalination-chambered MDC, stacked microbial desalination cells (SMDCs) were developed in order to promote the desalination rate in the present study. The effects of desalination chamber number and external resistance were investigated. Results showed that a remarkable increase in the total desalination rate (TDR) could be obtained by means of increasing the desalination cell number and reducing the external resistance, which caused the charge transfer efficiency increased since the SMDCs enabled more pairs of ions separated while one electron passed through the external circuit. The maximum TDR of 0.0252 g/h was obtained using a two-desalination-chambered SMDC with an external resistance of 10 Ω, which was 1.4 times that of single-desalination-chambered MDC. SMDCs proved to be an effective approach to increase the total water desalination rate if provided a proper desalination chamber number and external resistance.

  3. Water Desalination using geothermal energy

    KAUST Repository

    Goosen, M.

    2010-08-03

    The paper provides a critical overview of water desalination using geothermal resources. Specific case studies are presented, as well as an assessment of environmental risks and market potential and barriers to growth. The availability and suitability of low and high temperature geothermal energy in comparison to other renewable energy resources for desalination is also discussed. Analysis will show, for example, that the use of geothermal energy for thermal desalination can be justified only in the presence of cheap geothermal reservoirs or in decentralized applications focusing on small-scale water supplies in coastal regions, provided that society is able and willing to pay for desalting. 2010 by the authors; licensee MDPI, Basel, Switzerland.

  4. Water Desalination Using Geothermal Energy

    Directory of Open Access Journals (Sweden)

    Noreddine Ghaffour

    2010-08-01

    Full Text Available The paper provides a critical overview of water desalination using geothermal resources. Specific case studies are presented, as well as an assessment of environmental risks and market potential and barriers to growth. The availability and suitability of low and high temperature geothermal energy in comparison to other renewable energy resources for desalination is also discussed. Analysis will show, for example, that the use of geothermal energy for thermal desalination can be justified only in the presence of cheap geothermal reservoirs or in decentralized applications focusing on small-scale water supplies in coastal regions, provided that society is able and willing to pay for desalting.

  5. Nanostructured materials for water desalination

    Science.gov (United States)

    Humplik, T.; Lee, J.; O'Hern, S. C.; Fellman, B. A.; Baig, M. A.; Hassan, S. F.; Atieh, M. A.; Rahman, F.; Laoui, T.; Karnik, R.; Wang, E. N.

    2011-07-01

    Desalination of seawater and brackish water is becoming an increasingly important means to address the scarcity of fresh water resources in the world. Decreasing the energy requirements and infrastructure costs of existing desalination technologies remains a challenge. By enabling the manipulation of matter and control of transport at nanometer length scales, the emergence of nanotechnology offers new opportunities to advance water desalination technologies. This review focuses on nanostructured materials that are directly involved in the separation of water from salt as opposed to mitigating issues such as fouling. We discuss separation mechanisms and novel transport phenomena in materials including zeolites, carbon nanotubes, and graphene with potential applications to reverse osmosis, capacitive deionization, and multi-stage flash, among others. Such nanostructured materials can potentially enable the development of next-generation desalination systems with increased efficiency and capacity.

  6. A New Method for Water Desalination Using Microbial Desalination Cells

    KAUST Repository

    Cao, Xiaoxin

    2009-09-15

    Current water desalination techniques are energy intensive and some use membranes operated at high pressures. It is shownhere that water desalination can be accomplished without electrical energy input or high water pressure by using a source of organic matter as the fuel to desalinate water. A microbial fuel cell was modified by placing two membranes between the anode and cathode, creating a middle chamber for water desalination between the membranes. An anion exchange membrane was placed adjacent to the anode, and a cation exchange membrane was positioned next to the cathode. When current was produced by bacteria on the anode, ionic species in the middle chamber were transferred into the two electrode chambers, desalinating the water in the middle chamber. Proof-of-concept experiments for this approach, using what we call a microbial desalination cell (MDC), was demonstrated using water at different initial salt concentrations (5, 20, and 35 g/L) with acetate used as the substrate for the bacteria. The MDC produced a maximum of 2 W/m2 (31 W/m3) while at the same time removing about 90% of the salt in a single desalination cycle. As the salt was removed from the middle chamber the ohmic resistance of the MDC (measured using electrochemical impedance spectroscopy) increased from 25 Ω to 970 Ω at the end of the cycle. This increased resistance was reflected by a continuous decrease in the voltage produced over the cycle. These results demonstrate for the first time the possibility for a new method for water desalination and power production that uses only a source of biodegradable organic matter and bacteria. © 2009 American Chemical Society.

  7. Desalination

    Science.gov (United States)

    To cope with the rising demand for fresh water, desalination of brackish groundwater and seawater is increasingly being viewed as a pragmatic option for augmenting fresh water supplies. The large scale deployment of desalination is likely to demonstrably increase electricity use,...

  8. Multilayer Nanoporous Graphene Membranes for Water Desalination.

    Science.gov (United States)

    Cohen-Tanugi, David; Lin, Li-Chiang; Grossman, Jeffrey C

    2016-02-10

    While single-layer nanoporous graphene (NPG) has shown promise as a reverse osmosis (RO) desalination membrane, multilayer graphene membranes can be synthesized more economically than the single-layer material. In this work, we build upon the knowledge gained to date toward single-layer graphene to explore how multilayer NPG might serve as a RO membrane in water desalination using classical molecular dynamic simulations. We show that, while multilayer NPG exhibits similarly promising desalination properties to single-layer membranes, their separation performance can be designed by manipulating various configurational variables in the multilayer case. This work establishes an atomic-level understanding of the effects of additional NPG layers, layer separation, and pore alignment on desalination performance, providing useful guidelines for the design of multilayer NPG membranes.

  9. On fuzzy control of water desalination plants

    Energy Technology Data Exchange (ETDEWEB)

    Titli, A. [Centre National de la Recherche Scientifique (CNRS), 31 - Toulouse (France); Jamshidi, M. [New Mexico Univ., Albuquerque, NM (United States); Olafsson, F. [Institute of Technology, Norway (Norway)

    1995-12-31

    In this report we have chosen a sub-system of an MSF water desalination plant, the brine heater, for analysis, synthesis, and simulation. This system has been modelled and implemented on computer. A fuzzy logic controller (FLC) for the top brine temperature control loop has been designed and implemented on the computer. The performance of the proposed FLC is compared with three other conventional control strategies: PID, cascade and disturbance rejection control. One major concern on FLC`s has been the lack of stability criteria. An up to-date survey of stability of fuzzy control systems is given. We have shown stability of the proposed FLC using the Sinusoidal Input Describing Functions (SIDF) method. The potential applications of fuzzy controllers for complex and large-scale systems through hierarchy of rule sets and hybridization with conventional approaches are also investigated. (authors)

  10. Submerged membrane distillation for desalination of water

    KAUST Repository

    Francis, Lijo

    2016-10-27

    Submerged membrane modules for use for desalination of water are disclosed. In one or more aspects, the membrane modules can be submerged either in a feed solution tank or the feed solution can pass through the lumen side of the membrane submerged within the tank. The feed solution can be a water-based feed stream containing an amount of salt.

  11. Water Desalination Systems Powered by Solar Energy

    Science.gov (United States)

    Barseghyan, A.

    2015-12-01

    The supply of potable water from polluted rivers, lakes, unsafe wells, etc. is a problem of high priority. One of the most effective methods to obtain low cost drinking water is desalination. Advanced water treatment system powered by Solar Energy and based on electrodialysis for water desalination and purification, is suggested. Technological and economic evaluations and the benefits of the suggested system are discussed. The Advanced Water Treatment System proposed clears water not only from different salts, but also from some infections, thus decreasing the count of diseases which are caused by the usage of non-clear water. Using Solar Energy makes the system stand alone which is convenient to use in places where power supply is problem.

  12. Understanding transport in model water desalination membranes

    Science.gov (United States)

    Chan, Edwin

    Polyamide based thin film composites represent the the state-of-the-art nanofiltration and reverse osmosis membranes used in water desalination. The performance of these membranes is enabled by the ultrathin (~100 nm) crosslinked polyamide film in facilitating the selective transport of water over salt ions. While these materials have been refined over the last several decades, understanding the relationships between polyamide structure and membrane performance remains a challenge because of the complex and heterogeneous nature of the polyamide film. In this contribution, we present our approach to addressing this challenge by studying the transport properties of model polyamide membranes synthesized via molecular layer-by-layer (mLbL) assembly. First, we demonstrate that mLbL can successfully construct polyamide membranes with well-defined nanoscale thickness and roughness using a variety of monomer formulations. Next, we present measurement tools for characterizing the network structure and transport of these model polyamide membranes. Specifically, we used X-ray and neutron scattering techniques to characterize their structure as well as a recently-developed indentation based poromechanics approach to extrapolate their water diffusion coefficient. Finally, we illustrate how these measurements can provide insight into the original problem by linking the key polyamide network properties, i.e. water-polyamide interaction parameter and characteristic network mesh size, to the membrane performance.

  13. LOW-WASTE TECHNOLOGY FOR WATER DESALINATION

    OpenAIRE

    Макаренко, Ірина Миколаївна

    2015-01-01

    Processes of reagent, ion-exchange and nanofiltration water desalination have been studied. Using reagents based on sodium hydroxoaluminate at reagent softening, it is possible to reduce residual hardness to 0.1–0.5 mg-eq/dm3 that allows to significantly decreasing reagents consumption for ion-exchange water demineralization. The application of weak-acid cationite in acid form at the first stage of cation exchange promotes this process. At the reagent softening with sodium hydroxoaluminate, a...

  14. Microbial desalination cells packed with ion-exchange resin to enhance water desalination rate.

    Science.gov (United States)

    Morel, Alexandre; Zuo, Kuichang; Xia, Xue; Wei, Jincheng; Luo, Xi; Liang, Peng; Huang, Xia

    2012-08-01

    A novel configuration of microbial desalination cell (MDC) packed with ion-exchange resin (R-MDC) was proposed to enhance water desalination rate. Compared with classic MDC (C-MDC), an obvious increase in desalination rate (DR) was obtained by R-MDC. With relatively low concentration (10-2 g/L NaCl) influents, the DR values of R-MDC were about 1.5-8 times those of C-MDC. Ion-exchange resins packed in the desalination chamber worked as conductor and thus counteracted the increase in ohmic resistance during treatment of low concentration salt water. Ohmic resistances of R-MDC stabilized at 3.0-4.7 Ω. By contrast, the ohmic resistances of C-MDC ranged from 5.5 to 12.7 Ω, which were 55-272% higher than those of R-MDC. Remarkable improvement in desalination rate helped improve charge efficiency for desalination in R-MDC. The results first showed the potential of R-MDC in the desalination of water with low salinity. Copyright © 2012 Elsevier Ltd. All rights reserved.

  15. Provision of Desalinated Irrigation Water by the Desalination of Groundwater within a Saline Aquifer

    Directory of Open Access Journals (Sweden)

    David D. J. Antia

    2016-12-01

    Full Text Available Irrigated land accounts for 70% of global water usage and 30% of global agricultural production. Forty percent of this water is derived from groundwater. Approximately 20%–30% of the groundwater sources are saline and 20%–50% of global irrigation water is salinized. Salinization reduces crop yields and the number of crop varieties which can be grown on an arable holding. Structured ZVI (zero valent iron, Fe0 pellets desalinate water by storing the removed ions as halite (NaCl within their porosity. This allows an “Aquifer Treatment Zone” to be created within an aquifer, (penetrated by a number of wells (containing ZVI pellets. This zone is used to supply partially desalinated water directly from a saline aquifer. A modeled reconfigured aquifer producing a continuous flow (e.g., 20 m3/day, 7300 m3/a of partially desalinated irrigation water is used to illustrate the impact of porosity, permeability, aquifer heterogeneity, abstraction rate, Aquifer Treatment Zone size, aquifer thickness, optional reinjection, leakage and flow by-pass on the product water salinity. This desalination approach has no operating costs (other than abstraction costs (and ZVI regeneration and may potentially be able to deliver a continuous flow of partially desalinated water (30%–80% NaCl reduction for $0.05–0.5/m3.

  16. Science Communication and Desalination Research: Water Experts' Views

    Science.gov (United States)

    Schibeci, R. A.; Williams, A. J.

    2014-01-01

    Access to clean drinking water is a major problem for many people across the world. Desalination is being increasingly used in many countries to provide this important resource. Desalination technology has received varying degrees of support in the communities in which this technology has been adopted. Productive communication suggests we…

  17. Water recycling and desalination by air gap membrane distillation

    NARCIS (Netherlands)

    Meindersma, G.W.; Guijt, C.M.; de Haan, A.B.

    2005-01-01

    Because salt and other small components are the most common compounds in wastewater from the process industry, desalination techniques are likely to be suitable as treatment processes in many cases. Although membrane distillation (MD) is a well-known technology for desalination and water treatment,

  18. Desalination and Water Recycling by Air Gap Membrane Distillation

    NARCIS (Netherlands)

    Meindersma, G.W.; Guijt, C.M.; de Haan, A.B.

    2006-01-01

    Membrane distillation (MD) is an emerging technology for desalination. Membrane distillation differs from other membrane technologies in that the driving force for desalination is the difference in vapour pressure of water across the membrane, rather than total pressure. The membranes for MD are

  19. Drinking water in Cuba and seawater desalination

    Energy Technology Data Exchange (ETDEWEB)

    Meneses-Ruiz, E. [CUBAENERGIA, Playa, Havana (Cuba)]. E-mail: emeneses@cien.energia.inf.cu; Turtos-Carbonell, L.M.; Oviedo-Rivero, I. [CUBAENERGIA, Playa, Havana (Cuba)

    2004-07-01

    The lack of drinking water has become a problem at world level because, in many places, supplies are very limited and, in other places, their reserves have been drained. At the present time there are estimated to be around two thousand million people that don't have drinking water for several reasons, such as drought, contamination and the presence of saline waters not suitable for human consumption. Because of the human need for water, they have always taken residence in areas where the supply was guaranteed, sometimes impeding the exploitation of other areas that can be economically very interesting. However, this resource is usually very close and in abundance in the form of seawater but its salinity makes it unusable for many basic requirements. Humanity has been forced, therefore, to take into consideration the possibilities of the economic treatment of seawater. Cuba has regions where the supplies of drinking water are scarce and others where the lack of this resource limits economic exploitation. The present work is approached with regard to the situation of hydro resources in Cuba, it includes: a description of the main hydrographic basins of the country; the contamination levels of the waters and the measures for mitigation; analysis of the supplies and demand for drinking water and its quality; regulatory aspects. The state of seawater desalination in Cuba is also included and the possibility of its realisation using nuclear energy and the advantages that this would bring is evaluated. (author)

  20. Water quality assessment of solar-assisted adsorption desalination cycle

    KAUST Repository

    Kim, Youngdeuk

    2014-07-01

    This study focuses on the water quality assessment (feed, product and brine) of the pilot adsorption desalination (AD) plant. Seawater from the Red Sea is used as feed to the AD plant. Water quality tests are evaluated by complying the Environmental Protection Agency (EPA) standards with major primary and secondary inorganic drinking water pollutants and other commonly tested water quality parameters. Chemical testing of desalinated water at the post desalination stage confirms the high quality of produced fresh water. Test results have shown that the adsorption desalination process is very effective in eliminating all forms of salts, as evidenced by the significant reduction of the TDS levels from approximately 40,000. ppm in feed seawater to less than 10. ppm. Test results exhibit extremely low levels of parameters which are generally abundant in feed seawater. The compositions of seawater and process related parameters such as chloride, sodium, bromide, sulfate, calcium, magnesium, and silicate in desalinated water exhibit values of less than 0.1. ppm. Reported conductivity measurements of desalinated water are comparable to distilled water conductivity levels and ranged between 2 and 6. μS/cm while TOC and TIC levels are also extremely low and its value is less than 0.5. ppm. © 2014 Elsevier B.V.

  1. Rotating carbon nanotube membrane filter for water desalination

    Science.gov (United States)

    Tu, Qingsong; Yang, Qiang; Wang, Hualin; Li, Shaofan

    2016-01-01

    We have designed a porous nanofluidic desalination device, a rotating carbon nanotube membrane filter (RCNT-MF), for the reverse osmosis desalination that can turn salt water into fresh water. The concept as well as design strategy of RCNT-MF is modeled, and demonstrated by using molecular dynamics simulation. It has been shown that the RCNT-MF device may significantly improve desalination efficiency by combining the centrifugal force propelled reverse osmosis process and the porous CNT-based fine scale selective separation technology. PMID:27188982

  2. Improvement of water desalination technologies in reverse osmosis plants

    Science.gov (United States)

    Vysotskii, S. P.; Konoval'chik, M. V.; Gul'ko, S. E.

    2017-07-01

    The strengthening of requirements for the protection of surface-water sources and increases in the cost of reagents lead to the necessity of using membrane (especially, reverse osmosis) technologies of water desalination as an alternative to ion-exchange technologies. The peculiarities of using reverse osmosis technologies in the desalination of waters with an increased salinity have been discussed. An analogy has been made between the dependence of the adsorptive capacity of ion-exchange resins on the reagent consumption during ion exchange and the dependence of the specific ion flux on the voltage in the electrodialysis and productivity of membrane elements on the excess of the pressure of source water over the osmotic pressure in reverse osmosis. It has been proposed to regulate the number of water desalination steps in reverse osmosis plants, which makes it possible to flexibly change the productivity of equipment and the level of desalinization, depending on the requirements for the technological process. It is shown that the selectivity of reverse osmotic membranes with respect to bivalent ions (calcium, magnesium, and sulfates) is approximately four times higher than the selectivity with respect to monovalent ions (sodium and chlorine). The process of desalination in reverse osmosis plants depends on operation factors, such as the salt content and ion composition of source water, the salt content of the concentrate, and the temperatures of solution and operating pressure, and the design features of devices, such as the length of the motion of the desalination water flux, the distance between membranes, and types of membranes and turbulators (spacers). To assess the influence of separate parameters on the process of reverse osmosis desalination of water solutions, we derived criteria equations by compiling problem solution matrices on the basis of the dimensional method, taking into account the Huntley complement. The operation of membrane elements was

  3. Reverse osmosis desalination: water sources, technology, and today's challenges.

    Science.gov (United States)

    Greenlee, Lauren F; Lawler, Desmond F; Freeman, Benny D; Marrot, Benoit; Moulin, Philippe

    2009-05-01

    Reverse osmosis membrane technology has developed over the past 40 years to a 44% share in world desalting production capacity, and an 80% share in the total number of desalination plants installed worldwide. The use of membrane desalination has increased as materials have improved and costs have decreased. Today, reverse osmosis membranes are the leading technology for new desalination installations, and they are applied to a variety of salt water resources using tailored pretreatment and membrane system design. Two distinct branches of reverse osmosis desalination have emerged: seawater reverse osmosis and brackish water reverse osmosis. Differences between the two water sources, including foulants, salinity, waste brine (concentrate) disposal options, and plant location, have created significant differences in process development, implementation, and key technical problems. Pretreatment options are similar for both types of reverse osmosis and depend on the specific components of the water source. Both brackish water and seawater reverse osmosis (RO) will continue to be used worldwide; new technology in energy recovery and renewable energy, as well as innovative plant design, will allow greater use of desalination for inland and rural communities, while providing more affordable water for large coastal cities. A wide variety of research and general information on RO desalination is available; however, a direct comparison of seawater and brackish water RO systems is necessary to highlight similarities and differences in process development. This article brings to light key parameters of an RO process and process modifications due to feed water characteristics.

  4. Desalination plant aids Australian water shortage

    Energy Technology Data Exchange (ETDEWEB)

    Stocking, A.W.

    2010-09-15

    This article described a reverse-osmosis desalination plant that was commissioned for Adelaide, South Australia, which operates under permanent water restrictions. The plant will supplement the freshwater supply, reduce the pressure on the existing rainwater catchment system, and allow water levels to regenerate. The company that won the bid on the project used 3-dimensional modelling to get accurate cost estimates and visualize the plant impact on the environment, the community, and a culturally important site. A detailed diffusion plan was devised to mitigate the effects of saline concentrate release. As reverse osmosis is so energy intensive that it can be difficult to justify a plant on sustainability grounds. Energy recovery devices were included in the process building and outfall shaft, and solar energy panels will be installed on the process building roof. The energy recovery devices use energy stored in the brine to increase the output of the high-pressure pumps that feed the reverse osmosis units. Energy recovery units in the outfall shaft will produce electricity and provide power to the grid for the process plant to use. The 3-dimensional model was credited as a key factor in winning the bid, and the many advantages of 3-dimensional modelling were described. 3 figs.

  5. Emerging desalination technologies for water treatment: a critical review.

    Science.gov (United States)

    Subramani, Arun; Jacangelo, Joseph G

    2015-05-15

    In this paper, a review of emerging desalination technologies is presented. Several technologies for desalination of municipal and industrial wastewater have been proposed and evaluated, but only certain technologies have been commercialized or are close to commercialization. This review consists of membrane-based, thermal-based and alternative technologies. Membranes based on incorporation of nanoparticles, carbon nanotubes or graphene-based ones show promise as innovative desalination technologies with superior performance in terms of water permeability and salt rejection. However, only nanocomposite membranes have been commercialized while others are still under fundamental developmental stages. Among the thermal-based technologies, membrane distillation and adsorption desalination show the most promise for enhanced performance with the availability of a waste heat source. Several alternative technologies have also been developed recently; those based on capacitive deionization have shown considerable improvements in their salt removal capacity and feed water recovery. In the same category, microbial desalination cells have been shown to desalinate high salinity water without any external energy source, but to date, scale up of the process has not been methodically evaluated. In this paper, advantages and drawbacks of each technology is discussed along with a comparison of performance, water quality and energy consumption. Copyright © 2015 Elsevier Ltd. All rights reserved.

  6. Exploiting interfacial water properties for desalination and purification applications.

    Energy Technology Data Exchange (ETDEWEB)

    Xu, Hongwu (Los Alamos National Laboratory, Los Alamos, NM); Varma, Sameer; Nyman, May Devan; Alam, Todd Michael; Thuermer, Konrad; Holland, Gregory P.; Leung, Kevin; Liu, Nanguo (University of New Mexico Albuquerque, NM); Xomeritakis, George K. (University of New Mexico Albuquerque, NM); Frankamp, Benjamin L.; Siepmann, J. Ilja (University of Minnesota, Minneapolis, MN); Cygan, Randall Timothy; Hartl, Monika A. (Los Alamos National Laboratory, Los Alamos, NM); Travesset, Alex (Iowa State University, Ames, IA); Anderson, Joshua A. (Iowa State University, Ames, IA); Huber, Dale L.; Kissel, David J. (University of New Mexico Albuquerque, NM); Bunker, Bruce Conrad; Lorenz, Christian Douglas; Major, Ryan C. (University of Minnesota, Minneapolis, MN); McGrath, Matthew J. (University of Minnesota, Minneapolis, MN); Farrow, Darcie; Cecchi, Joseph L. (University of New Mexico Albuquerque, NM); van Swol, Frank B.; Singh, Seema; Rempe, Susan B.; Brinker, C. Jeffrey; Clawson, Jacalyn S.; Feibelman, Peter Julian; Houston, Jack E.; Crozier, Paul Stewart; Criscenti, Louise Jacqueline; Chen, Zhu (University of New Mexico Albuquerque, NM); Zhu, Xiaoyang (University of Minnesota, Minneapolis, MN); Dunphy, Darren Robert (University of New Mexico Albuquerque, NM); Orendorff, Christopher J.; Pless, Jason D.; Daemen, Luke L. (Los Alamos National Laboratory, Los Alamos, NM); Gerung, Henry (University of New Mexico Albuquerque, NM); Ockwig, Nathan W.; Nenoff, Tina Maria; Jiang, Ying-Bing; Stevens, Mark Jackson

    2008-09-01

    A molecular-scale interpretation of interfacial processes is often downplayed in the analysis of traditional water treatment methods. However, such an approach is critical for the development of enhanced performance in traditional desalination and water treatments. Water confined between surfaces, within channels, or in pores is ubiquitous in technology and nature. Its physical and chemical properties in such environments are unpredictably different from bulk water. As a result, advances in water desalination and purification methods may be accomplished through an improved analysis of water behavior in these challenging environments using state-of-the-art microscopy, spectroscopy, experimental, and computational methods.

  7. Integrated experimental investigation and mathematical modeling of brackish water desalination and wastewater treatment in microbial desalination cells.

    Science.gov (United States)

    Ping, Qingyun; Huang, Zuyi; Dosoretz, Carlos; He, Zhen

    2015-06-15

    Desalination of brackish water can provide freshwater for potable use or non potable applications such as agricultural irrigation. Brackish water desalination is especially attractive to microbial desalination cells (MDCs) because of its low salinity, but this has not been well studied before. Herein, three brackish waters prepared according to the compositions of actual brackish water in three locations in Israel were examined with domestic wastewater as an electron source in a bench-scale MDC. All three brackish waters could be effectively desalinated with simultaneous wastewater treatment. The MDC achieved the highest salt removal rate of 1.2 g L(-1) d(-1) with an initial salinity of 5.9 g L(-1) and a hydraulic retention time (HRT) of 0.8 d. The desalinated brackish water could meet the irrigation standard of both salinity (450 mg L(-1) TDS) and the concentrations of major ionic species, given a sufficient HRT. The MDC also accomplished nearly 70% removal of organic compounds in wastewater with Coulombic efficiency varied between 5 and 10%. A previously developed MDC model was improved for brackish water desalination, and could well predict salinity variation and the concentrations of individual ions. The model also simulated a staged operation mode with improved desalination performance. This integrated experiment and mathematical modeling approach provides an effective method to understand the key factors in brackish water desalination by MDCs towards further system development. Copyright © 2015 Elsevier Ltd. All rights reserved.

  8. Economics of Renewable Energy for Water Desalination in Developing Countries

    Directory of Open Access Journals (Sweden)

    Enas R. Shouman

    2015-12-01

    Full Text Available The aim of this study is to investigate the economics of renewable energy- powered desalination, as applied to water supply for remote coastal and desert communities in developing countries. In this paper, the issue of integration of desalination technologies and renewable energy from specified sources is addressed. The features of Photovoltaic (PV system combined with reverse osmosis desalination technology, which represents the most commonly applied integration between renewable energy and desalination technology, are analyzed. Further, a case study for conceptual seawater reverse osmosis (SW-RO desalination plant with 1000 m3 /d capacity is presented, based on PV and conventional generators powered with fossil fuel to be installed in a remote coastal area in Egypt, as a typical developing country. The estimated water cost for desalination with PV/ SW-RO system is about $1.25 m3 , while ranging between $1.22-1.59 for SW-RO powered with conventional generator powered with fossil fuel. Analysis of the economical, technical and environmental factors depicts the merits of using large scale integrated PV/RO system as an economically feasible water supply relying upon a renewable energy source.

  9. DESALINATION AND WATER TREATMENT RESEARCH AT SANDIA NATIONAL LABORATORIES.

    Energy Technology Data Exchange (ETDEWEB)

    Rigali, Mark J. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Miller, James E. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Altman, Susan J. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Biedermann, Laura [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Brady, Patrick Vane. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Kuzio, Stephanie P. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Nenoff, Tina M. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Rempe, Susan [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2016-11-01

    Water is the backbone of our economy - safe and adequate supplies of water are vital for agriculture, industry, recreation, and human consumption. While our supply of water today is largely safe and adequate, we as a nation face increasing water supply challenges in the form of extended droughts, demand growth due to population increase, more stringent health-based regulation, and competing demands from a variety of users. To meet these challenges in the coming decades, water treatment technologies, including desalination, will contribute substantially to ensuring a safe, sustainable, affordable, and adequate water supply for the United States. This overview documents Sandia National Laboratories' (SNL, or Sandia) Water Treatment Program which focused on the development and demonstration of advanced water purification technologies as part of the larger Sandia Water Initiative. Projects under the Water Treatment Program include: (1) the development of desalination research roadmaps (2) our efforts to accelerate the commercialization of new desalination and water treatment technologies (known as the 'Jump-Start Program),' (3) long range (high risk, early stage) desalination research (known as the 'Long Range Research Program'), (4) treatment research projects under the Joint Water Reuse & Desalination Task Force, (5) the Arsenic Water Technology Partnership Program, (6) water treatment projects funded under the New Mexico Small Business Administration, (7) water treatment projects for the National Energy Technology Laboratory (NETL) and the National Renewable Energy Laboratory (NREL), (8) Sandia- developed contaminant-selective treatment technologies, and finally (9) current Laboratory Directed Research and Development (LDRD) funded desalination projects.

  10. Strategies for merging microbial fuel cell technologies in water desalination processes: Start-up protocol and desalination efficiency assessment

    Science.gov (United States)

    Borjas, Zulema; Esteve-Núñez, Abraham; Ortiz, Juan Manuel

    2017-07-01

    Microbial Desalination Cells constitute an innovative technology where microbial fuel cell and electrodialysis merge in the same device for obtaining fresh water from saline water with no energy-associated cost for the user. In this work, an anodic biofilm of the electroactive bacteria Geobacter sulfurreducens was able to efficiently convert the acetate present in synthetic waste water into electric current (j = 0.32 mA cm-2) able to desalinate water. .Moreover, we implemented an efficient start-up protocol where desalination up to 90% occurred in a desalination cycle (water production:0.308 L m-2 h-1, initial salinity: 9 mS cm-1, final salinity: process or as a pre-treatment method combined with other well established desalination technologies such as reverse osmosis (RO) or reverse electrodialysis.

  11. Desalination Technologies: Hellenic Experience

    Directory of Open Access Journals (Sweden)

    Konstantinos Zotalis

    2014-04-01

    Full Text Available Beyond doubt, desalination is growing rapidly worldwide. However, there are still obstacles to its wider implementation and acceptance such as: (a high costs and energy use for fresh water production; (b environmental impacts from concentrate disposal; (c a complex, convoluted and time-consuming project permitting process; and (d limited public understanding of the role, importance, benefits and environmental challenges of desalination. In this paper, a short review of desalination in Greece is being made. Data on the cost of desalination shows a decrease in the future and the potential of water desalination in Greece. The paper summarizes the current status in southeastern Greece (e.g., Aegean islands and Crete, and investigates the possibility of production of desalinated water from brackish water.

  12. Application of a Hybrid Uf-Ro Process to Geothermal Water Desalination. Concentrate Disposal and Cost Analysis

    National Research Council Canada - National Science Library

    Barbara Tomaszewska; Leszek Pająk; Michał Bodzek

    2014-01-01

    M embrane-based water desalination processes and hybrid technologies are often considered as a technologically and economically viable alternative for desalination of geothermal waters. This has been...

  13. Ozone-cathode microbial desalination cell; An innovative option to bioelectricity generation and water desalination.

    Science.gov (United States)

    Gholizadeh, Abdolmajid; Ebrahimi, Ali Asghar; Salmani, Mohammad Hossein; Ehrampoush, Mohammad Hassan

    2017-12-01

    Microbial desalination cell (MDC) is a new approach of water desalination methods, which is based on ionic species removal from water in proportion to the electric current generated by bacteria. However, the low current generation and insufficient deionization in this technology have created challenges to improve the process. Here, the performance of MDC using ozone as a new electron acceptor (O3-MDC) was evaluated versus another operated independently with oxygen (O2-MDC). Results showed the maximum open-circuit voltages of 628 and 1331 mV for 20 g L-1 NaCl desalination in O2-MDC and O3-MDC, respectively. The O3-MDC produced a maximum power density of 4.06 W m-2 (about 11 times higher than O2-MDC) while at the same time was able to remove about 74% of salt (55.58% in the O2-MDC). Each cycle of O2-MDC and O3-MDC operation lasted about 66 and 94 h, respectively, indicating a more stable current profile in the O3-MDC. Moreover, sequencing test based on 16S rRNA gene showed that the anode biofilm had more diverse microbial community than anolyte sample. Proteobacteria, Firmicutes and Acidobacteria were from dominant microbial communities in anode biofilm sample. Accordingly, the results revealed that ozone can enhance MDC performance either as a desalination process or as a pre-treatment reactor for downstream desalination processes. Copyright © 2017 Elsevier Ltd. All rights reserved.

  14. Indirect economic impacts in water supplies augmented with desalinated water

    DEFF Research Database (Denmark)

    Rygaard, Martin; Arvin, Erik; Binning, Philip John

    2010-01-01

    softeners. This paper describes potential economic consequences of diluting Copenhagen's drinking water with desalinated water. With a mineral content at 50% of current levels, dental caries and cardiovascular diseases are expected to increase by 51 and 23% respectively. Meanwhile, the number of dish......Several goals can be considered when optimizing blends from multiple water resources for urban water supplies. Concentration-response relationships from the literature indicate that a changed water quality can cause impacts on health, lifetime of consumer goods and use of water additives like...... and clothes washer replacements is expected to decrease by 14%. In economic terms these changes are equal to 24–85% of water production costs in 2005. Our calculations further indicate that the economic impact from changing the water quality can be at least as significant as the change in operating costs...

  15. Energy-water-environment nexus underpinning future desalination sustainability

    KAUST Repository

    Shahzad, Muhammad Wakil

    2017-03-11

    Energy-water-environment nexus is very important to attain COP21 goal, maintaining environment temperature increase below 2°C, but unfortunately two third share of CO2 emission has already been used and the remaining will be exhausted by 2050. A number of technological developments in power and desalination sectors improved their efficiencies to save energy and carbon emission but still they are operating at 35% and 10% of their thermodynamic limits. Research in desalination processes contributing to fuel World population for their improved living standard and to reduce specific energy consumption and to protect environment. Recently developed highly efficient nature-inspired membranes (aquaporin & graphene) and trend in thermally driven cycle\\'s hybridization could potentially lower then energy requirement for water purification. This paper presents a state of art review on energy, water and environment interconnection and future energy efficient desalination possibilities to save energy and protect environment.

  16. Water Desalination Using Capacitive Deionization with Microporous Carbon Electrodes

    NARCIS (Netherlands)

    Porada, S.; Weinstein, L.; Dash, R.; Wal, van der A.F.; Bryjak, M.; Gogotsi, Y.; Biesheuvel, P.M.

    2012-01-01

    Capacitive deionization (CDI) is a water desalination technology in which salt ions are removed from brackish water by flowing through a spacer channel with porous electrodes on each side. Upon applying a voltage difference between the two electrodes, cations move to and are accumulated in

  17. ZVI (Fe0 Desalination: Stability of Product Water

    Directory of Open Access Journals (Sweden)

    David D. J. Antia

    2016-03-01

    Full Text Available A batch-operated ZVI (zero valent iron desalination reactor will be able to partially desalinate water. This water can be stored in an impoundment, reservoir or tank, prior to use for irrigation. Commercial development of this technology requires assurance that the partially-desalinated product water will not resalinate, while it is in storage. This study has used direct ion analyses to confirm that the product water from a gas-pressured ZVI desalination reactor maintains a stable salinity in storage over a period of 1–2.5 years. Two-point-three-litre samples of the feed water (2–10.68 g (Na+ + Cl−·L−1 and product water (0.1–5.02 g (Na+ + Cl−·L−1 from 21 trials were placed in storage at ambient (non-isothermal temperatures (which fluctuated between −10 and 25 °C, for a period of 1–2.5 years. The ion concentrations (Na+ and Cl− of the stored feed water and product water were then reanalysed. The ion analyses of the stored water samples demonstrated: (i that the product water salinity (Na+ and Cl− remains unchanged in storage; and (ii the Na:Cl molar ratios can be lower in the product water than the feed water. The significance of the results is discussed in terms of the various potential desalination routes. These trial data are supplemented with the results from 122 trials to demonstrate that: (i reactivity does not decline with successive batches; (ii the process is catalytic; and (iii the process involves a number of steps.

  18. Enhancing forward osmosis water recovery from landfill leachate by desalinating brine and recovering ammonia in a microbial desalination cell.

    Science.gov (United States)

    Iskander, Syeed Md; Novak, John T; He, Zhen

    2018-01-31

    In this work, a microbial desalination cell (MDC) was employed to desalinate the FO treated leachate for reduction of both salinity and chemical oxygen demand (COD). The FO recovered 51.5% water from a raw leachate and the recovery increased to 83.5% from the concentrated leachate after desalination in the MDC fed with either acetate or another leachate as an electron source and at a different hydraulic retention time (HRT). Easily-degraded substrate like acetate and a long HRT resulted in a low conductivity desalinated effluent. Ammonia was also recovered in the MDC cathode with a recovery efficiency varying from 11 to 64%, affected by current generation and HRT. Significant COD reduction, as high as 65.4%, was observed in the desalination chamber and attributed to the decrease of both organic and inorganic compounds via diffusion and electricity-driven movement. Copyright © 2018 Elsevier Ltd. All rights reserved.

  19. Model-based Extracted Water Desalination System for Carbon Sequestration

    Energy Technology Data Exchange (ETDEWEB)

    Gettings, Rachel; Dees, Elizabeth

    2017-03-23

    The focus of this research effort centered around water recovery from high Total Dissolved Solids (TDS) extracted waters (180,000 mg/L) using a combination of water recovery (partial desalination) technologies. The research goals of this project were as follows: 1. Define the scope and test location for pilot-scale implementation of the desalination system, 2.Define a scalable, multi-stage extracted water desalination system that yields clean water, concentrated brine, and, salt from saline brines, and 3. Validate overall system performance with field-sourced water using GE pre-pilot lab facilities. Conventional falling film-mechanical vapor recompression (FF-MVR) technology was established as a baseline desalination process. A quality function deployment (QFD) method was used to compare alternate high TDS desalination technologies to the base case FF-MVR technology, including but not limited to: membrane distillation (MD), forward osmosis (FO), and high pressure reverse osmosis (HPRO). Technoeconomic analysis of high pressure reverse osmosis (HPRO) was performed comparing the following two cases: 1. a hybrid seawater RO (SWRO) plus HPRO system and 2. 2x standard seawater RO system, to achieve the same total pure water recovery rate. Pre-pilot-scale tests were conducted using field production water to validate key process steps for extracted water pretreatment. Approximately 5,000 gallons of field produced water was processed through, microfiltration, ultrafiltration, and steam regenerable sorbent operations. Improvements in membrane materials of construction were considered as necessary next steps to achieving further improvement in element performance at high pressure. Several modifications showed promising results in their ability to withstand close to 5,000 PSI without gross failure.

  20. Design of a process for supercritical water desalination with zero liquid discharge

    NARCIS (Netherlands)

    Odu, Samuel Obarinu; van der Ham, Aloysius G.J.; Metz, S.; Kersten, Sascha R.A.

    2015-01-01

    Conventional desalination methods have a major drawback; the production of a liquid waste stream which must be disposed. The treatment of this waste stream has always presented technical, economic, and environmental challenges. The supercritical water desalination (SCWD) process meets these

  1. Knowledge, attitudes and practice of desalinated water among professionals in health and water departments in Shengsi, China: a qualitative study.

    Directory of Open Access Journals (Sweden)

    Tao Chen

    Full Text Available Desalination has been considered as an essential way to solve water stress all over the world. Most of previous studies focused on its environmental impacts, energy consumption and desalination technologies rather than human health. However, the safety of desalinated water remains unclear. This study was undertaken to investigate the knowledge, attitude and practice (KAP of the residents in an island county in eastern China to desalinated water. Seventeen people working in medical and water industries were recruited, and focus group discussion and in-depth interview were conducted among them. Our results showed that the majority of people interviewed knew the definition and local supply pattern of desalinated water, while some of them showed some concern about the safety and nutrition of desalinated water. Current drinking water standard has no specific item for desalination, so we strongly suggest issuing a standard for desalinated water.

  2. Porous organic cage membranes for water desalination: a simulation exploration.

    Science.gov (United States)

    Kong, Xian; Jiang, Jianwen

    2017-07-19

    Porous organic cages (POCs) have emerged as a new class of porous materials and received considerable interest for their potential applications. Herein we report the first proof-of-concept simulation study on POC membranes for water desalination. Five [4+6] POCs (CC1, CC2, CC3, CC16, and CC17) are considered with similar crystal structures, but different periphery groups and pore morphologies. CC1 is found to be impermeable to water due to disconnected pores. With an interconnected tetrahedral pore network, CC3 and CC16 have an intermediate water permeability of 1-5 × 10-7 kg m (m2 h bar)-1. CC2 and CC17 contain straight pores and a widely open pore network, respectively, thus exhibit a high water permeability of 2-3 × 10-6 kg m (m2 h bar)-1; nevertheless, salt rejection in CC17 is only 89%. Among the five POC membranes, CC2 is the best for water desalination with performance superior to other membranes reported in the literature. The membrane flexibility is revealed to have a weak effect on water permeation. To provide further microscopic understanding, the permeation duration, diffusion and hydrogen bonding of water in the POC membranes are quantitatively analyzed. From this simulation study, the key factors governing water permeation in the POC membranes are unraveled and CC2 is identified to be an interesting candidate for water desalination.

  3. Nanotechnology applications to desalination : a report for the joint water reuse & desalination task force.

    Energy Technology Data Exchange (ETDEWEB)

    Brady, Patrick Vane; Mayer, Tom; Cygan, Randall Timothy

    2011-01-01

    Nanomaterials and nanotechnology methods have been an integral part of international research over the past decade. Because many traditional water treatment technologies (e.g. membrane filtration, biofouling, scale inhibition, etc.) depend on nanoscale processes, it is reasonable to expect one outcome of nanotechnology research to be better, nano-engineered water treatment approaches. The most immediate, and possibly greatest, impact of nanotechnology on desalination methods will likely be the development of membranes engineered at the near-molecular level. Aquaporin proteins that channel water across cell membranes with very low energy inputs point to the potential for dramatically improved performance. Aquaporin-laced polymer membranes and aquaporin-mimicking carbon nanotubes and metal oxide membranes developed in the lab support this. A critical limitation to widespread use of nanoengineered desalination membranes will be their scalability to industrial fabrication processes. Subsequent, long-term improvements in nanoengineered membranes may result in self-healing membranes that ideally are (1) more resistant to biofouling, (2) have biocidal properties, and/or (3) selectively target trace contaminants.

  4. Model-Based Extracted Water Desalination System for Carbon Sequestration

    Energy Technology Data Exchange (ETDEWEB)

    Dees, Elizabeth M. [General Electric Global Research Center, Niskayuna, NY (United States); Moore, David Roger [General Electric Global Research Center, Niskayuna, NY (United States); Li, Li [Pennsylvania State Univ., University Park, PA (United States); Kumar, Manish [Pennsylvania State Univ., University Park, PA (United States)

    2017-05-28

    Over the last 1.5 years, GE Global Research and Pennsylvania State University defined a model-based, scalable, and multi-stage extracted water desalination system that yields clean water, concentrated brine, and, optionally, salt. The team explored saline brines that ranged across the expected range for extracted water for carbon sequestration reservoirs (40,000 up to 220,000 ppm total dissolved solids, TDS). In addition, the validated the system performance at pilot scale with field-sourced water using GE’s pre-pilot and lab facilities. This project encompassed four principal tasks, in addition to Project Management and Planning: 1) identify a deep saline formation carbon sequestration site and a partner that are suitable for supplying extracted water; 2) conduct a techno-economic assessment and down-selection of pre-treatment and desalination technologies to identify a cost-effective system for extracted water recovery; 3) validate the downselected processes at the lab/pre-pilot scale; and 4) define the scope of the pilot desalination project. Highlights from each task are described below: Deep saline formation characterization The deep saline formations associated with the five DOE NETL 1260 Phase 1 projects were characterized with respect to their mineralogy and formation water composition. Sources of high TDS feed water other than extracted water were explored for high TDS desalination applications, including unconventional oil and gas and seawater reverse osmosis concentrate. Technoeconomic analysis of desalination technologies Techno-economic evaluations of alternate brine concentration technologies, including humidification-dehumidification (HDH), membrane distillation (MD), forward osmosis (FO), turboexpander-freeze, solvent extraction and high pressure reverse osmosis (HPRO), were conducted. These technologies were evaluated against conventional falling film-mechanical vapor recompression (FF-MVR) as a baseline desalination process. Furthermore, a

  5. A framework for planning sustainable seawater desalination water supply.

    Science.gov (United States)

    Shahabi, Maedeh P; McHugh, Adam; Anda, Martin; Ho, Goen

    2017-01-01

    A quantitative framework for sustainable desalination planning in metropolitan areas, which integrates the tools of mixed integer linear programming and life cycle assessment, is presented. The life cycle optimisation framework allows for optimal desalination planning by considering choices over intake type, staging and location of the infrastructure under different land-use, environmental and economic policies. Optimality is defined by the decision maker's selected objective function, being either an environmental impact or a levelised cost indicator. The framework was tested for future desalination planning scenarios in the northern metropolitan area of Perth, Western Australia. Results indicate that multi-staged construction and decentralised planning solutions may produce lower life cycle environmental impacts (58%) and at a lower levelised cost (24%) than a centralised desalination solution currently being considered by Western Australian water planners. Sensitivity analysis results suggest that the better environmental and economic performance of decentralised planning over centralised planning is highly sensitive to the proportion of land that can be made available for the siting of decentralised plants near the demand zone. Insight into land use policies is a critical factor to the initiation and success of decentralised solution in developed metropolitan areas. Copyright © 2016 Elsevier B.V. All rights reserved.

  6. Computer simulation of water desalination through boron nitride nanotubes.

    Science.gov (United States)

    Liang, Lijun; Li, Jia-Chen; Zhang, Li; Zhang, Zhisen; Shen, Jia-Wei; Li, Lihua; Wu, Jianyang

    2017-11-15

    Development of high-efficiency and low-cost seawater desalination technologies is critical to solving the global water crisis. Herein we report a fast water filtering method with high salt rejection by boron nitride nanotubes (BNNTs). The effect of the radius of BNNTs on water filtering and salt rejection was investigated by molecular dynamics (MD) simulation. Our simulation results demonstrate that fast water permeation and high salt rejection could be achieved by BNNT(7,7) under both high pressure and low pressure. The potential of mean force (PMF) of Na+ ion and water molecule through BNNT(7,7) further revealed the mechanism of seawater desalination by BNNT(7,7). Using BNNT(7,7) array, a 10 cm2 nanotube membrane with 1.5 × 1013 pores per cm2 will produce freshwater with a flow rate of 98 L per day per MPa under 100 MPa. Our study shows the potential application of BNNTs membrane for fast and efficient desalination.

  7. Tunable C2N Membrane for High Efficient Water Desalination

    Science.gov (United States)

    Yang, Yanmei; Li, Weifeng; Zhou, Hongcai; Zhang, Xiaoming; Zhao, Mingwen

    2016-01-01

    Water scarcity represents one of the most serious global problems of our time and challenges the advancements in desalination techniques. Although water-filtering architectures based on graphene have greatly advanced the approach to high performance desalination membranes, the controlled-generation of nanopores with particular diameter is tricky and has stunted its wide applications. Here, through molecular dynamic simulations and first-principles calculations, we propose that the recently reported graphene-like carbon nitride (g-C2N) monolayer can serve as high efficient filters for water desalination. Taking the advantages of the intrisic nanoporous structure and excellent mechanical properties of g-C2N, high water transparency and strong salt filtering capability have been demonstrated in our simulations. More importantly, the “open” and “closed” states of the g-C2N filter can be precisely regulated by tensile strain. It is found that the water permeability of g-C2N is significantly higher than that reported for graphene filters by almost one order of magnitude. In the light of the abundant family of graphene-like carbon nitride monolayered materials, our results thus offer a promising approach to the design of high efficient filteration architectures. PMID:27384666

  8. High performance hydrophilic pervaporation composite membranes for water desalination

    KAUST Repository

    Liang, Bin

    2014-08-01

    A three-layer thin film nanofibrous pervaporation composite (TFNPVC) membrane was prepared by sequential deposition using electrospraying/electrospinning. The poly(vinyl alcohol) (PVA) top barrier layer was first electrosprayed on aluminum foil and its thickness can be easily controlled by adjusting the collecting time. Next a polyacrylonitrile (PAN) nanofibrous scaffold was deposited by electrospinning as a mid-layer support. A nonwoven PET layer is used to complete the composite membrane. The pervaporation desalination performance of TFNPVC membranes was tested using NaCl solutions at 100. Pa and at room temperature. The TFNPVC membranes show excellent desalination performance (high water flux and salt rejection >. 99.5%) for different salt concentrations with virtually no change in performance after 50. h of operation. © 2014 Elsevier B.V.

  9. Forward osmosis :a new approach to water purification and desalination.

    Energy Technology Data Exchange (ETDEWEB)

    Miller, James Edward; Evans, Lindsey R.

    2006-07-01

    Fresh, potable water is an essential human need and thus looming water shortages threaten the world's peace and prosperity. Waste water, brackish water, and seawater have great potential to fill the coming requirements. Unfortunately, the ability to exploit these resources is currently limited in many parts of the world by both the cost of the energy and the investment in equipment required for purification/desalination. Forward (or direct) osmosis is an emerging process for dewatering aqueous streams that might one day help resolve this problem. In FO, water from one solution selectively passes through a membrane to a second solution based solely on the difference in the chemical potential (concentration) of the two solutions. The process is spontaneous, and can be accomplished with very little energy expenditure. Thus, FO can be used, in effect, to exchange one solute for a different solute, specifically chosen for its chemical or physical properties. For desalination applications, the salts in the feed stream could be exchanged for an osmotic agent specifically chosen for its ease of removal, e.g. by precipitation. This report summarizes work performed at Sandia National Laboratories in the area of FO and reviews the status of the technology for desalination applications. At its current state of development, FO will not replace reverse osmosis (RO) as the most favored desalination technology, particularly for routine waters. However, a future role for FO is not out of the question. The ability to treat waters with high solids content or fouling potential is particularly attractive. Although our analysis indicates that FO is not cost effective as a pretreatment for conventional BWRO, water scarcity will likely drive societies to recover potable water from increasingly marginal resources, for example gray water and then sewage. In this context, FO may be an attractive pretreatment alternative. To move the technology forward, continued improvement and

  10. Mild desalination of various raw water streams

    NARCIS (Netherlands)

    Groot, C.K.; Broek, W.B.P. van den; Loewenberg, J.; Koeman-Stein-N.E.; Heidekamp, M.; Schepper, W. de

    2015-01-01

    For chemical industries, fresh water availability is a pre-requisite for sustainable operation. However, in many delta areas around the world, fresh water is scarce. Therefore, the E4Water project (http://www.e4water.eu) comprises a case study at the Dow site in Terneuzen, The Netherlands, which is

  11. Procedures of water desalination with solar energy and f-chart method

    Directory of Open Access Journals (Sweden)

    Petrović Andrija A.

    2015-01-01

    Full Text Available Due to rapid population growth, and climate change caused by environmental pollution needs for drinking water are increasing while amount of freshwater are decreasing. However possible solution for freshwater scarcity can be found in water desalination procedures. In this article three representative water desalination solar powered plants are described. Except explanation of processes it is also mentioned basic advantages and disadvantages of humidification, reverse osmosis and desalination evaporation by using solar energy. Simulation of the solar desalination system is analyzed with f-chart method monthly, located on located 42 degrees north latitude.

  12. Optimizing Nanopore Surface Properties for High-Efficiency Water Desalination

    Science.gov (United States)

    Cohen-Tanugi, David; Grossman, Jeffrey

    2011-03-01

    As water resources worldwide become rapidly scarcer, it is becoming increasingly important to devise new techniques to obtain clean water from seawater. At present, water purification technologies are limited by costly energy requirements relative to the theoretical thermodynamic limit and by insufficient understanding of the physical processes underlying ion filtration and fluid transport at the molecular scale. New advances in computational materials science offer a promising way to deepen our understanding of these physical phenomena. In this presentation, we describe a new approach for high-efficiency water desalination based on surface-engineered porous materials. This approach is especially relevant for promising technologies such as nanofiltration and membrane distillation, which offers promising advantages over traditional desalination technologies using mesoporous membranes that are only permeable to pure water vapor. More accurate molecular modeling of mesoporous and nanoporous materials represents a key step towards efficient large-scale treatment of seawater. Results regarding the effect of pore properties (surface texture, morphology, density, tortuosity) on desired performance characteristics such as ion selectivity, maximal water flux and energy requirements will be presented.

  13. Evaluation of hydroacid complex in the forward osmosis–membrane distillation (FO–MD) system for desalination

    KAUST Repository

    Wang, Peng

    2015-11-01

    The incorporation of membrane distillation (MD) into forward osmosis (FO) provides process sustainability to regenerate the draw solution and to produce clean water simultaneously. However, the reverse salt flux is the major hurdle in the FO-MD system because it not only reduces the effective osmotic driving force across the membrane but also increases the replenishment cost and scaling issue. For the first time, a hydroacid complex with abundant hydrophilic groups and ionic species is evaluated as the draw solutes in the hybrid FO-MD system consisting of multi-bore PVDF MD membranes for seawater/brackish desalination. In order to evaluate the practicality of the hydroacid complex in the FO-MD system, FO and MD experiments were conducted at elevated temperatures and concentrations. The hydroacid complex has displayed desired properties such as high solubility, low viscosity, excellent thermal stability and minimal reverse salt flux suitable for FO and MD operations. FO-MD desalination process was demonstrated with a highest seawater desalination flux of 6/32 LMH (FO/MD). This study may open up the prospective of employing the hydroacid complex as the draw solute in FO-MD hybrid systems for seawater /brackish desalination. © 2015 Elsevier B.V.

  14. Inorganic Membranes: Preparation and Application for Water Treatment and Desalination

    Science.gov (United States)

    McKay, Gordon; Buekenhoudt, Anita; Motmans, Filip; Khraisheh, Marwan; Atieh, Muataz

    2018-01-01

    Inorganic membrane science and technology is an attractive field of membrane separation technology, which has been dominated by polymer membranes. Recently, the inorganic membrane has been undergoing rapid development and innovation. Inorganic membranes have the advantage of resisting harsh chemical cleaning, high temperature and wear resistance, high chemical stability, long lifetime, and autoclavable. All of these outstanding properties made inorganic membranes good candidates to be used for water treatment and desalination applications. This paper is a state of the art review on the synthesis, development, and application of different inorganic membranes for water and wastewater treatment. The inorganic membranes reviewed in this paper include liquid membranes, dynamic membranes, various ceramic membranes, carbon based membranes, silica membranes, and zeolite membranes. A brief description of the different synthesis routes for the development of inorganic membranes for application in water industry is given and each synthesis rout is critically reviewed and compared. Thereafter, the recent studies on different application of inorganic membrane and their properties for water treatment and desalination in literature are critically summarized. It was reported that inorganic membranes despite their high synthesis cost, showed very promising results with high flux, full salt rejection, and very low or no fouling. PMID:29304024

  15. Inorganic Membranes: Preparation and Application for Water Treatment and Desalination

    Directory of Open Access Journals (Sweden)

    Ahmad Kayvani Fard

    2018-01-01

    Full Text Available Inorganic membrane science and technology is an attractive field of membrane separation technology, which has been dominated by polymer membranes. Recently, the inorganic membrane has been undergoing rapid development and innovation. Inorganic membranes have the advantage of resisting harsh chemical cleaning, high temperature and wear resistance, high chemical stability, long lifetime, and autoclavable. All of these outstanding properties made inorganic membranes good candidates to be used for water treatment and desalination applications. This paper is a state of the art review on the synthesis, development, and application of different inorganic membranes for water and wastewater treatment. The inorganic membranes reviewed in this paper include liquid membranes, dynamic membranes, various ceramic membranes, carbon based membranes, silica membranes, and zeolite membranes. A brief description of the different synthesis routes for the development of inorganic membranes for application in water industry is given and each synthesis rout is critically reviewed and compared. Thereafter, the recent studies on different application of inorganic membrane and their properties for water treatment and desalination in literature are critically summarized. It was reported that inorganic membranes despite their high synthesis cost, showed very promising results with high flux, full salt rejection, and very low or no fouling.

  16. BELL PEPPER CULTIVATION WITH BRINE FROM BRACKISH WATER DESALINATION

    Directory of Open Access Journals (Sweden)

    CARLOS EDUARDO DE MOURA ARRUDA

    2011-01-01

    Full Text Available In desalination process, besides the potable water, highly salty and pollutant water (brine is generated, which can be used for producing crops since it is carefully monitored. In order to test this hypothesis, bell pepper plants, cv. 'Margarita', were grown in coconut fiber substrate under greenhouse and were irrigated with nutrient solutions prepared with tap water, brine from desalination plant, and its dilution with tap water at 75, 50 and 25%, giving a range of electrical conductivities of the nutrient solution (ECs of 2.6, 3.1, 6.6, 10.0 and 12.2 dS m-1 after the dilutions and fertilizers addition. Completely randomized blocks design was used with 5 treatments (salinity levels of the nutrient solutions and six replications. Leaf area, number of marketable fruit, total and marketable yield were reduced with ECs increase. The marketable yield of bell pepper 'Margarita' reduced 6.3% for each unitary increase of ECs above 2.6 dS m-1 (threshold salinity and the results suggest that in hydroponic system, the reduction of marketable yield with increasing ECs is promoted by reduction of the number of fruits per plant instead of a reduction of fruit mean weight.

  17. Quantized Water Transport: Ideal Desalination through Graphyne-4 Membrane

    Science.gov (United States)

    Zhu, Chongqin; Li, Hui; Zeng, Xiao Cheng; Wang, E. G.; Meng, Sheng

    2013-01-01

    Graphyne sheet exhibits promising potential for nanoscale desalination to achieve both high water permeability and salt rejection rate. Extensive molecular dynamics simulations on pore-size effects suggest that γ-graphyne-4, with 4 acetylene bonds between two adjacent phenyl rings, has the best performance with 100% salt rejection and an unprecedented water permeability, to our knowledge, of ~13 L/cm2/day/MPa, 3 orders of magnitude higher than prevailing commercial membranes based on reverse osmosis, and ~10 times higher than the state-of-the-art nanoporous graphene. Strikingly, water permeability across graphyne exhibits unexpected nonlinear dependence on the pore size. This counter-intuitive behavior is attributed to the quantized nature of water flow at the nanoscale, which has wide implications in controlling nanoscale water transport and designing highly effective membranes. PMID:24196437

  18. Drivers of an urban community's acceptance of a large desalination scheme for drinking water

    Science.gov (United States)

    Gibson, Fiona L.; Tapsuwan, Sorada; Walker, Iain; Randrema, Elodie

    2015-09-01

    Changing climates and growing populations have prompted policy makers to shift to more climate resilient, technology-driven water sources, such as seawater desalination. Desalination is a prominent water resource in the Middle East but countries in other parts of the world with similar scarcity issues and good access to sea water, such as Australia, have been comparatively slow to adopt it. This paper explores attitudes to desalination in Perth, Western Australia, and the factors that influence its acceptance. We compared individuals' acceptance of desalination over two time periods by using identical surveys administered in 2007 and 2012. We then examined the attitudinal factors - attitudes towards desalination and attitudes towards the environment - that influence acceptance. Acceptance of desalination was reasonably high and stable at both times (74% and 73% in 2007 and 2012 respectively). We found that respondents' attitudes to perceived outcomes and benefits, fairness, environmental obligation and risk were important predictors of their acceptance of desalination in both surveys. However the weight given to these aspects varied over time. The findings show that there is still mixed community sentiment towards desalination, which helps to explain why acceptance has not increased since desalination was introduced in 2006.

  19. Study on solar sea water desalination; Studie ueber solare Meerwasserentsalzung

    Energy Technology Data Exchange (ETDEWEB)

    Hartmann, G.K.

    1995-09-01

    The state of the art of solar sea water desalination is discussed based on the example of simple solar distillation. Reasons are given for the relatively reserved use of this technique in the past. The increasing shortage of fresh water (drinking water) due to increasing water consumption, the deforestation of (rain) forests, and increasing environmental pollution reveals the urgency of sea water desalination. However, the fossil energy sources that are needed for desalination cause a further increase in carbon dioxide emissions and aggravate the global-warming problem. This study suggests to multiply the relatively low economic efficiency and low cost efficiency of simple solar distillers by vacuum-controlled ground cooling and to operate pumps that convey sea water and distilled water by means of solar energy or solar cogeneration. Model calculations and a pilot project are recommended for a closer quantification of the data. General intercultural and socioeconomic aspects that must be considered when installing solar sea water (waste water) distillation plants, e.g. in Africa, are discussed. (orig.) [Deutsch] In dieser Studie wird der Stand der Technik der solaren Wasserentsalzung, basierend auf der einfachen solaren Destillation, untersucht sowie die Gruende fuer den bisher relativ geringen Einsatz dieser Technik erlaeutert. Die zunehmende Verknappung von Suesswasser (Trinkwasser), durch steigenden Wasserverbrauch, durch die Abholzung von (Regen)-Waeldern und durch die zunehmende Umweltverschmutzung ruecken aber die Notwendigkeit der Meerwasserentsalzung immer staerker in den Vordergrund. Der hohe Energiebedarf dafuer traegt aber bei der Verwendung von fossiler Primaerenergie zu einer weiteren Verstaerkung des CO{sub 2}-Ausstosses und damit zur weiteren Verschaerfung der Klimaproblematik bei. Deshalb wird hier nicht nur vorgeschlagen, den relativ geringen Wirkungsgrad und die relativ geringe Kosteneffizienz einfacher solarer Destillatoren durch

  20. Geophysical remote sensing of water reservoirs suitable for desalinization.

    Energy Technology Data Exchange (ETDEWEB)

    Aldridge, David Franklin; Bartel, Lewis Clark; Bonal, Nedra; Engler, Bruce Phillip

    2009-12-01

    In many parts of the United States, as well as other regions of the world, competing demands for fresh water or water suitable for desalination are outstripping sustainable supplies. In these areas, new water supplies are necessary to sustain economic development and agricultural uses, as well as support expanding populations, particularly in the Southwestern United States. Increasing the supply of water will more than likely come through desalinization of water reservoirs that are not suitable for present use. Surface-deployed seismic and electromagnetic (EM) methods have the potential for addressing these critical issues within large volumes of an aquifer at a lower cost than drilling and sampling. However, for detailed analysis of the water quality, some sampling utilizing boreholes would be required with geophysical methods being employed to extrapolate these sampled results to non-sampled regions of the aquifer. The research in this report addresses using seismic and EM methods in two complimentary ways to aid in the identification of water reservoirs that are suitable for desalinization. The first method uses the seismic data to constrain the earth structure so that detailed EM modeling can estimate the pore water conductivity, and hence the salinity. The second method utilizes the coupling of seismic and EM waves through the seismo-electric (conversion of seismic energy to electrical energy) and the electro-seismic (conversion of electrical energy to seismic energy) to estimate the salinity of the target aquifer. Analytic 1D solutions to coupled pressure and electric wave propagation demonstrate the types of waves one expects when using a seismic or electric source. A 2D seismo-electric/electro-seismic is developed to demonstrate the coupled seismic and EM system. For finite-difference modeling, the seismic and EM wave propagation algorithms are on different spatial and temporal scales. We present a method to solve multiple, finite-difference physics

  1. Graphene oxide-based efficient and scalable solar desalination under one sun with a confined 2D water path

    National Research Council Canada - National Science Library

    Li, Xiuqiang; Xu, Weichao; Tang, Mingyao; Zhou, Lin; Zhu, Bin; Zhu, Shining; Zhu, Jia

    2016-01-01

      Because it is able to produce desalinated water directly using solar energy with minimum carbon footprint, solar steam generation and desalination is considered one of the most important technologies...

  2. Treatment and desalination of domestic wastewater for water reuse in a four-chamber microbial desalination cell.

    Science.gov (United States)

    Lu, Yaobin; Abu-Reesh, Ibrahim M; He, Zhen

    2016-09-01

    Microbial desalination cells (MDCs) have been studied for contaminant removal from wastewater and salinity reduction in saline water. However, in an MDC wastewater treatment and desalination occurs in different streams, and high salinity of the treated wastewater creates challenges for wastewater reuse. Herein, a single-stream MDC (SMDC) with four chambers was developed for simultaneous organic removal and desalination in the same synthetic wastewater. This SMDC could achieve a desalination rate of 12.2-31.5 mg L(-1) h(-1) and remove more than 90 % of the organics and 75 % of NH4 (+)-N; the pH imbalance between the anode and cathode chambers was also reduced. Several strategies such as controlling catholyte pH, increasing influent COD concentration, adopting the batch mode, applying external voltage, and increasing the alkalinity of wastewater were investigated for improving the SMDC performance. Under a condition of 0.4 V external voltage, anolyte pH adjustment, and a batch mode, the SMDC decreased the wastewater salinity from 1.45 to below 0.75 mS cm(-1), which met the salinity standard of wastewater for irrigation. Those results encourage further development of the SMDC technology for sustainable wastewater treatment and reuse.

  3. Desalination and reuse of high-salinity shale gas produced water: drivers, technologies, and future directions.

    Science.gov (United States)

    Shaffer, Devin L; Arias Chavez, Laura H; Ben-Sasson, Moshe; Romero-Vargas Castrillón, Santiago; Yip, Ngai Yin; Elimelech, Menachem

    2013-09-03

    In the rapidly developing shale gas industry, managing produced water is a major challenge for maintaining the profitability of shale gas extraction while protecting public health and the environment. We review the current state of practice for produced water management across the United States and discuss the interrelated regulatory, infrastructure, and economic drivers for produced water reuse. Within this framework, we examine the Marcellus shale play, a region in the eastern United States where produced water is currently reused without desalination. In the Marcellus region, and in other shale plays worldwide with similar constraints, contraction of current reuse opportunities within the shale gas industry and growing restrictions on produced water disposal will provide strong incentives for produced water desalination for reuse outside the industry. The most challenging scenarios for the selection of desalination for reuse over other management strategies will be those involving high-salinity produced water, which must be desalinated with thermal separation processes. We explore desalination technologies for treatment of high-salinity shale gas produced water, and we critically review mechanical vapor compression (MVC), membrane distillation (MD), and forward osmosis (FO) as the technologies best suited for desalination of high-salinity produced water for reuse outside the shale gas industry. The advantages and challenges of applying MVC, MD, and FO technologies to produced water desalination are discussed, and directions for future research and development are identified. We find that desalination for reuse of produced water is technically feasible and can be economically relevant. However, because produced water management is primarily an economic decision, expanding desalination for reuse is dependent on process and material improvements to reduce capital and operating costs.

  4. Advanced Control Synthesis for Reverse Osmosis Water Desalination Processes.

    Science.gov (United States)

    Phuc, Bui Duc Hong; You, Sam-Sang; Choi, Hyeung-Six; Jeong, Seok-Kwon

    2017-11-01

      In this study, robust control synthesis has been applied to a reverse osmosis desalination plant whose product water flow and salinity are chosen as two controlled variables. The reverse osmosis process has been selected to study since it typically uses less energy than thermal distillation. The aim of the robust design is to overcome the limitation of classical controllers in dealing with large parametric uncertainties, external disturbances, sensor noises, and unmodeled process dynamics. The analyzed desalination process is modeled as a multi-input multi-output (MIMO) system with varying parameters. The control system is decoupled using a feed forward decoupling method to reduce the interactions between control channels. Both nominal and perturbed reverse osmosis systems have been analyzed using structured singular values for their stabilities and performances. Simulation results show that the system responses meet all the control requirements against various uncertainties. Finally the reduced order controller provides excellent robust performance, with achieving decoupling, disturbance attenuation, and noise rejection. It can help to reduce the membrane cleanings, increase the robustness against uncertainties, and lower the energy consumption for process monitoring.

  5. Cellulose Derived Graphenic Fibers for Capacitive Desalination of Brackish Water.

    Science.gov (United States)

    Pugazhenthiran, Nalenthiran; Sen Gupta, Soujit; Prabhath, Anupama; Manikandan, Muthu; Swathy, Jakka Ravindran; Raman, V Kalyan; Pradeep, Thalappil

    2015-09-16

    We describe a simple and inexpensive cellulose-derived and layer-by-layer stacked carbon fiber network electrode for capacitive deionization (CDI) of brackish water. The microstructure and chemical composition were characterized using spectroscopic and microscopic techniques; electrochemical/electrical performance was evaluated by cyclic voltammetry and 4-probe electrical conductivity and surface area by Brunauer-Emmett-Teller analysis, respectively. The desalination performance was investigated using a laboratory batch model CDI unit, under fixed applied voltage and varying salt concentrations. Electro-adsorption of NaCl on the graphite reinforced-cellulose (GrC) electrode reached equilibrium quickly (within 90 min) and the adsorbed salts were released swiftly (in 40 min) back into the solution, during reversal of applied potential. X-ray photoelectron spectroscopic studies clearly illustrate that sodium and chloride ions were physisorbed on the negative and positive electrodes, respectively during electro-adsorption. This GrC electrode showed an electro-adsorption capacity of 13.1 mg/g of the electrode at a cell potential of 1.2 V, with excellent recyclability and complete regeneration. The electrode has a high tendency for removal of specific anions, such as fluoride, nitrate, chloride, and sulfate from water in the following order: Cl->NO3->F->SO4(2-). GrC electrodes also showed resistance to biofouling with negligible biofilm formation even after 5 days of incubation in Pseudomonas putida bacterial culture. Our unique cost-effective methodology of layer-by-layer stacking of carbon nanofibers and concurrent reinforcement using graphite provides uniform conductivity throughout the electrode with fast electro-adsorption, rapid desorption, and extended reuse, making the electrode affordable for capacitive desalination of brackish water.

  6. Effectiveness of Water Desalination by Membrane Distillation Process

    Science.gov (United States)

    Gryta, Marek

    2012-01-01

    The membrane distillation process constitutes one of the possibilities for a new method for water desalination. Four kinds of polypropylene membranes with different diameters of capillaries and pores, as well as wall thicknesses were used in studied. The morphology of the membrane used and the operating parameters significantly influenced process efficiency. It was found that the membranes with lower wall thickness and a larger pore size resulted in the higher yields. Increasing both feed flow rate and temperature increases the permeate flux and simultaneously the process efficiency. However, the use of higher flow rates also enhanced heat losses by conduction, which decreases the thermal efficiency. This efficiency also decreases when the salt concentration in the feed was enhanced. The influence of fouling on the process efficiency was considered. PMID:24958289

  7. Effectiveness of Water Desalination by Membrane Distillation Process

    Directory of Open Access Journals (Sweden)

    Marek Gryta

    2012-07-01

    Full Text Available The membrane distillation process constitutes one of the possibilities for a new method for water desalination. Four kinds of polypropylene membranes with different diameters of capillaries and pores, as well as wall thicknesses were used in studied. The morphology of the membrane used and the operating parameters significantly influenced process efficiency. It was found that the membranes with lower wall thickness and a larger pore size resulted in the higher yields. Increasing both feed flow rate and temperature increases the permeate flux and simultaneously the process efficiency. However, the use of higher flow rates also enhanced heat losses by conduction, which decreases the thermal efficiency. This efficiency also decreases when the salt concentration in the feed was enhanced. The influence of fouling on the process efficiency was considered.

  8. A combined microbial desalination cell and electrodialysis system for copper-containing wastewater treatment and high-salinity-water desalination.

    Science.gov (United States)

    Dong, Yue; Liu, Junfeng; Sui, Mingrui; Qu, Youpeng; Ambuchi, John J; Wang, Haiman; Feng, Yujie

    2017-01-05

    A new concept for heavy metal removal by forming hydroxide precipitation using alkalinity produced by microbial desalination cell (MDC) was proposed. Four five-chamber MDCs were hydraulically connected to concurrently produce alkalinity to treat synthetic copper-containing wastewater and salt removal. There was nearly complete removal of copper, with a maximum removal rate of 5.07kg/(m3d) under the initial copper concentration of 5000mg/L (final pH of 7). The final copper concentration met the emission standard for electroplating of China (0.5mg/L, GB 21900-2008). XRD analysis indicated copper was precipitated as Cu2Cl(OH)3. The best performance of MDCs in terms of average power density, salt removal and COD removal rate achieved in stage 3 were 737.3±201.1mW/m2, 53.6±0.8kg/(m3d), and 1.84±0.05 kgCOD/(m3d) respectively. For purposes of water recovery, an electrodialysis (ED) system was presented based on in-situ utilization of generated electricity by MDCs as post-desalination treatment for salt effluent after sedimentation. The maximum discharging voltage of 12.75±1.26V at switching time (Ts) of 15min using a capacitor-based circuit produced a maximum desalination efficiency of 30.4±2.6%. These results indicated that this combined system holds great promise for real-world treatment of copper-containing wastewater and deep desalination of high-salinity-water. Copyright © 2016 Elsevier B.V. All rights reserved.

  9. Desalination of brackish water and concentration of industrial effluents by electrodialysis

    Directory of Open Access Journals (Sweden)

    J. J. Schoeman

    1983-03-01

    Full Text Available Electrodialysis (ED is, at present, used mainly for the desalination of brackish drinking-water. Brackish water with a high scaling potential can be successfully treated, using the electrodialysis reversal (EDR process without the addition of chemicals. The reliability of the ED process makes it very attractive for water treatment. Although used mainly for brackish water desalination, ED also has certain industrial applications. Plating wash waters, cooling tower recirculation water and glass etching effluents have been treated successfully with ED for water recovery and effluent volume reduction, while ED treatment of nickel plating wash waters is an established industrial process.

  10. Adsorption characteristics of water vapor on ferroaluminophosphate for desalination cycle

    KAUST Repository

    Kim, Youngdeuk

    2014-07-01

    The adsorption characteristics of microporous ferroaluminophosphate adsorbent (FAM-Z01, Mitsubishi Plastics) are evaluated for possible application in adsorption desalination and cooling (AD) cycles. A particular interest is its water vapor uptake behavior at assorted adsorption temperatures and pressures whilst comparing them to the commercial silica gels of AD plants. The surface characteristics are first carried out using N2 gas adsorption followed by the water vapor uptake analysis for temperature ranging from 20°C to 80°C. We propose a hybrid isotherm model, composing of the Henry and the Sips isotherms, which can be integrated to satisfactorily fit the experimental data of water adsorption on the FAM-Z01. The hybrid model is selected to fit the unusual isotherm shapes, that is, a low adsorption in the initial section and followed by a rapid vapor uptake leading to a likely micropore volume filling by hydrogen bonding and cooperative interaction in micropores. It is shown that the equilibrium adsorption capacity of FAM-Z01 can be up to 5 folds higher than that of conventional silica gels. Owing to the quantum increase in the adsorbate uptake, the FAM-Z01 has the potential to significantly reduce the footprint of an existing AD plant for the same output capacity. © 2014 Elsevier B.V.

  11. Solar Energy Supported Desalination Processes for Desalting of Sea Water

    OpenAIRE

    , M.E. Argun

    2010-01-01

    This study is a review of solar energy supported desalination processes. Although the sun light captured by earth excessively meets of world’s need, we can use a few amount of this source. Solar energy supported desalination is one of the method developed for desalination. Solar energy usage will also decrease CO2 emission which is responsible of global warming. A lot of studies to improve the efficiency of solar energy systems have been carried out during last years. Solar energy can be used...

  12. Desalination of sea water with aquatic lily (Eichhornia crassipes).

    Science.gov (United States)

    Arámburo-Miranda, Isela Victoria; Ruelas-Ramírez, Emmanuel Hammurabi

    2017-11-01

    During the last decades, methods of halo conditioning have been developed to increase the tolerance to salinity in glucophyta crops. Some experiments have carried out the application of hydrogen peroxide (H2O2), in support to the modification of cell tolerance in saline medium. The first objective of this study was to evaluate the effects of the incorporation of H2O2 in salinity tolerance development of the aquatic lily (Eichhornia crassipes). Results showed that the incorporation of 0.03 % H2O2 salinity tolerance developed in salt concentrations similar to seawater. Saline stress tolerance in aquatic lily was shown by the excretion of salts in its leaves; this process helped also in removing salt from seawater. At the same time, the reproduction of the lily is intimately linked to the content of nitrogen (N) and phosphorus (P) (nutrients) in water. This reason is important to control the concentrations of these elements in the water. This will allow maintaining a control in the dissemination of the lily. Considering the mentioned above, the second objective was to continue development of the adaptation of the aquatic lily in seawater, using H2O2 and the required amount of nutrients. This paper points out the importance of considering a biological process for the treatments in the desalination of seawater, making the process more sustainable.

  13. Economic and Policy Drivers of Agricultural Water Desalination in California's Central Valley

    Science.gov (United States)

    Welle, P.; Medellin-Azuara, J.; Viers, J. H.; Mauter, M.

    2016-12-01

    Agriculture in arid regions is threatened by the twin stresses of soil salinity and uncertain water availability. Recently, water desalination has been a proposed solution for mitigating the effects of drought, soil salinization, and the ecological impacts of agricultural drainage. In this study, we combine data from earth observing systems with auxiliary information on prices, yields, and farmer behavior in order to create a decision framework which assesses the public and private costs and benefits of distributed desalination in the Central Valley (CV) of California. The use of remotely sensed crop classifiers allows us to resolve our analysis at the 30m pixel scale across the CV, a feature that allows us to characterize regional differences in technology effectiveness. We employ environmental and economic modeling to estimate the value of lower salinity irrigation water; the value of augmented water supply under present and future climate scenarios; and the human health, environmental, and climate change damages associated with generating power to desalinate water. We find that water desalination is only likely to be profitable in 4% of the CV during periods of severe drought, and that current costs would need to decrease by 70-90% for adoption to occur on the median acre. Fossil-fuel powered desalination technologies also generate air emissions that impose significant public costs in the form of human health and climate change damages, although these damages vary greatly depending on technology. The ecosystem service benefits of reduced agricultural drainage would need to be valued between 800 and 1200 per acre-foot, or nearly the full capital and operational costs of water desalination, for the net benefits of water desalination to be positive from a societal perspective.

  14. Potential drawbacks associated with agricultural irrigation with treated wastewaters from desalinated water origin and possible remedies.

    Science.gov (United States)

    Lahav, Ori; Kochva, Malka; Tarchitzky, Jorge

    2010-01-01

    Over 90% of the water supplied in the coastal region in Israel in 2013 (600 Mm(3) y(-1)) will be from desalination plants. The wastewater generated from this water (>400 Mm(3) y(-1)) is planned, after proper treatment, to be reused for agricultural irrigation, making this low-salinity water the main agricultural-sector future water source. In this respect both the Mg(2 + ) concentration and the Sodium Adsorption Ratio value of the water are of concern. We show that the typical Na(+) concentration addition to wastewater (between approximately 100 and approximately 165 mg L(-1)) is much higher than the combined addition of Ca(2 + ) and Mg(2 + ) (between 0 and several mg L(-1)). Since desalinated water is typically supplied with low Ca(2 + ) and Mg(2 + ) concentrations ( approximately 35 and 0 mg L(-1) respectively), the treated wastewater is characterized by very low Mg(2 + ) concentrations, low salinity and very high SAR values, typically >6 and up to 10 (meq L(-1))(0.5). SAR values can be lowered by adding either Ca(2 + ) or Mg(2 + ) to desalinated water. Adding Mg(2 + ) is preferable from both health (minimizing cardiovascular disease hazards) and agriculture (inexpensive Mg fertilization) aspects. The low cost of Mg(2 + ) addition at the post-treatment stage of desalination plants corroborates the request for Mg(2 + ) addition in regions where treated wastewater from desalinated water origin is planned to be reused for irrigation.

  15. Economic Investigation of Different Configurations of Inclined Solar Water Desalination Systems

    Directory of Open Access Journals (Sweden)

    O. Phillips Agboola

    2014-02-01

    Full Text Available This study empirically investigated the performance of four configurations of inclined solar water desalination (ISWD system for parameters such as daily production, efficiency, system cost, and distilled water production cost. The empirical findings show that in terms of daily productivity improved inclined solar water desalination (IISWD performed best with 6.41 kg/m2/day while improved inclined solar water desalination with wire mesh (IISWDWM produced the least with 3.0 kg/m2/day. In terms of cost price of the systems, the control system inclined solar water desalination (ISWD is the cheapest while IISWDWM is the most expensive system. Distilled water cost price ranges from 0.059 TL/kg, for IISWDW, to 0.134 TL/kg, for IISWDWM system. All the systems are economically and technically feasible as a solar desalination system for potable water in northern Cyprus. Potable water from vendors/hawkers ranges from 0.2 to 0.3 TL/kg.

  16. An Interactive Computer Tool for Teaching About Desalination and Managing Water Demand in the US

    Science.gov (United States)

    Ziolkowska, J. R.; Reyes, R.

    2016-12-01

    This paper presents an interactive tool to geospatially and temporally analyze desalination developments and trends in the US in the time span 1950-2013, its current contribution to satisfying water demands and its future potentials. The computer tool is open access and can be used by any user with Internet connection, thus facilitating interactive learning about water resources. The tool can also be used by stakeholders and policy makers for decision-making support and with designing sustainable water management strategies. Desalination technology has been acknowledged as a solution to a sustainable water demand management stemming from many sectors, including municipalities, industry, agriculture, power generation, and other users. Desalination has been applied successfully in the US and many countries around the world since 1950s. As of 2013, around 1,336 desalination plants were operating in the US alone, with a daily production capacity of 2 BGD (billion gallons per day) (GWI, 2013). Despite a steady increase in the number of new desalination plants and growing production capacity, in many regions, the costs of desalination are still prohibitive. At the same time, the technology offers a tremendous potential for `enormous supply expansion that exceeds all likely demands' (Chowdhury et al., 2013). The model and tool are based on data from Global Water Intelligence (GWI, 2013). The analysis shows that more than 90% of all the plants in the US are small-scale plants with the capacity below 4.31 MGD. Most of the plants (and especially larger plants) are located on the US East Coast, as well as in California, Texas, Oklahoma, and Florida. The models and the tool provide information about economic feasibility of potential new desalination plants based on the access to feed water, energy sources, water demand, and experiences of other plants in that region.

  17. Can the Adoption of Desalination Technology Lead to Aquifer Preservation? A Case Study of a Sociotechnical Water System in Baja California Sur, Mexico

    Directory of Open Access Journals (Sweden)

    Jamie McEvoy

    2015-09-01

    Full Text Available There is growing concern about the sustainability of groundwater supplies worldwide. In many regions, desalination—the conversion of saline water to freshwater—is viewed as a way to increase water supplies and reduce pressure on overdrawn aquifers. Using data from reports, articles, interviews, a survey, and a focus group, this paper examines if, and how, the adoption of desalination technology can lead to aquifer preservation in Baja California Sur (BCS, Mexico. The paper outlines existing institutional arrangements (i.e., laws, rules, norms, or organizations surrounding desalination in BCS and concludes that there are currently no effective mechanisms to ensure aquifer preservation. Four mechanisms that could be implemented to improve groundwater management are identified, including: 1 integrated water-and land-use planning; 2 creation of an institute responsible for coordinated and consistent planning; 3 improved groundwater monitoring; and 4 implementation of water conservation measures prior to the adoption of desalination technology. This paper concludes that viewing water technologies, including desalination, as sociotechnical systems—i.e., a set of technological components that are embedded in complex social, political, and economic contexts—has the potential to create a more sustainable human–environment–technology relationship. By assessing desalination technology as a sociotechnical system, this study highlights the need to focus on institutional development and capacity building, especially within local water utilities and urban planning agencies.

  18. Desalination of Red Sea water using both electrodialysis and reverse osmosis as complementary methods

    Directory of Open Access Journals (Sweden)

    E.A. Abdel-Aal

    2015-03-01

    Full Text Available Desalination process separates nearly salt free water from sea or brackish water. So, desalination process is becoming a solution for water scarcity all over the world. Two membrane methods of water desalination namely electrodialysis (ED and reverse osmosis (RO are used in this study as complementary methods. The results show that both ED and RO can be used as integrated system. This system is economic and cost effective compared with each individual method provided using the ED system before the RO. In this study, it was approved that seawater can be used as it is an electrolyte. TDS of Red Sea water was decreased from 42070 ppm to 2177 ppm achieving 94.8% removal efficiency using ED for half of its optimum time. Total removal efficiency of 99.4% can be obtained using the combined system of ED and RO.

  19. Performance Study of Reverse Osmosis Plants for Water Desalination in Bandar-Lengeh, Iran

    Directory of Open Access Journals (Sweden)

    Alireza Zirakrad

    2013-04-01

    Full Text Available Introduction: Reverse osmosis (RO is best known for its use in desalination (removing the salt from seawater to get fresh water, but since the early 1970s it has also been used to purify fresh water for medical, industrial, and domestic applications. The aim of this research was the performance study of reverse osmosis plants for water desalination in Bandar-Lengeh, Iran. Materials and Methods: In this study the concentrations of a number of physical, chemical and biological quality parameters in raw and treated water of Bandar-Lengeh water Desalination Plants were determined and Performance of RO plants for seawater and costal groundwater desalination were studied. There are two desalination plants in Bandar-Lengeh. Water from these plants are used for municipal supply. Total production capacity of the two RO desalination plants is 8000 m3/d. Results: The results of this study showed average values of TDS, Sodium, Chloride, Sulfate, diatomaceous and Nematodes in seawater were 37749 mg/l; 9715 mg/l; 22020 mg/l; 3067 mg/l; 24337 N/100ml and 5 N/100ml and in treated water were 1233 mg/l; 436 mg/l; 710 mg/l; 58 mg/l, 0 N/100ml and 0 N/100ml, respectively. Also the results showed average values of TDS, Sodium, Chloride and Sulfate in coastal ground water were 37131 mg/l; 9303 mg/l; 21072 mg/l; 3745 mg/l; and in treated water were 687mg/l; 253 mg/l; 389 mg/l; 19 mg/l, respectively. Conclusion: The results showed the quality of feed water and pretreatment plays an extremely important role in operational problems such as fouling of RO systems.

  20. IRIS Reactor a Suitable Option to Provide Energy and Water Desalination for the Mexican Northwest Region

    Energy Technology Data Exchange (ETDEWEB)

    Alonso, G.; Ramirez, R.; Gomez, C.; Viais, J.

    2004-10-03

    The Northwest region of Mexico has a deficit of potable water, along this necessity is the region growth, which requires of additional energy capacity. The IRIS reactor offers a very suitable source of energy given its modular size of 300 MWe and it can be coupled with a desalination plant to provide the potable water for human consumption, agriculture and industry. The present paper assess the water and energy requirements for the Northwest region of Mexico and how the deployment of the IRIS reactor can satisfy those necessities. The possible sites for deployment of Nuclear Reactors are considered given the seismic constraints and the closeness of the sea for external cooling. And in the other hand, the size of the desalination plant and the type of desalination process are assessed accordingly with the water deficit of the region.

  1. Water desalination by membrane technology (RO in southern Iran (Jask city

    Directory of Open Access Journals (Sweden)

    Zabihollah Yousefi

    2014-11-01

    Full Text Available Background: Reverse Osmosis (RO is an increasingly common method of desalination. A full scale water desalination system by membrane technology (RO evaluated in a southern city (Jask in Iran. Methods: First, data collection on water supply and network were performed. Analysis on most of the water quality parameters (Turbidity, pH, EC, Cl-, Na+, Alkalinity, Ca, Na, K, No3, No2, Fe, Mg, Mn, NH4, Po4, HCo3-, So42- etc. was performed as standard methods. The membranes of the RO in the desalination system were Poly-Amid (CSM type. Results: The efficiency of the RO water desalination system was 94.16, 84.12, 92.00, and 96.17% respectively for Turbidity, Na+, Mg2+, So42-. The result shows a significant difference between influent and effluent water of the RO system. The produced water is in agreement with national standard of drinking water. Furthermore, water exited from the RO system for TDS, Ca+2, and Mg2+ was less than minimum limit of the guideline. Conclusion: The quality parameters of the water resource (EC, TDS, Cl-, Na+ etc. were higher than Iranian drinking water standards. The RO technology modified the quality of the water parameters.

  2. Combined desalination, water reuse, and aquifer storage and recovery to meet water supply demands in the GCC/MENA region

    KAUST Repository

    Ghaffour, Noreddine

    2013-01-01

    Desalination is no longer considered as a nonconventional resource to supply potable water in several countries, especially in the Gulf Corporation Countries (GCC) and Middle East and North Africa (MENA) region as most of the big cities rely almost 100% on desalinated water for their supply. Due to the continuous increase in water demand, more large-scale plants are expected to be constructed in the region. However, most of the large cities in these countries have very limited water storage capacity, ranging from hours to a few days only and their groundwater capacity is very limited. The growing need for fresh water has led to significant cost reduction, because of technological improvements of desalination technologies which makes it an attractive option for water supply even in countries where desalination was unthinkable in the past. In the GCC/MENA region, operating records show that water demand is relatively constant during the year, while power demand varies considerably with a high peak in the summer season. However, desalination and power plants are economically and technically efficient only if they are fully operated at close to full capacity. In addition, desalination plants are exposed to external constraints leading to unexpected shutdowns (e.g. red tides). Hybridization of different technologies, including reverse osmosis and thermal-based plants, is used to balance the power to water mismatch in the demand by using the idle power from co-generation systems during low power demand periods. This has led to consideration of storage of additional desalinated water to allow for maximum production and stability in operation. Aquifer storage and recovery (ASR) would then be a good option to store the surplus of desalinated water which could be used when water demand is high or during unexpected shutdowns of desalination plants. In addition, increased reuse of treated wastewater could bring an integrated approach to water resources management. In this

  3. Microbial mediated desalination for ground water softening with simultaneous power generation.

    Science.gov (United States)

    Hemalatha, Manupati; Butti, Sai Kishore; Velvizhi, G; Venkata Mohan, S

    2017-10-01

    A novel three-chambered microbial desalination cell (MDC) was designed for evaluating desalination of synthetic ground water with simultaneous energy generation and resource recovery. The specific design enabled efficient interelectrode communication by reducing the distance of separation and also maintained an appropriate surface area to volume ratio. MDC were evaluated in different circuitry modes (open and closed) to assess the desalination efficiency, bioelectricity generation, resource recovery, substrate utilization and bioelectrokinetics. The closed circuit operation has showed efficient desalination efficiency (51.5%) and substrate utilization (70%). Owing to the effective electron transfer kinetics, closed circuit mode of operation showed effective desalination of the synthetic ground water with simultaneous power production (0.35W/m2). Circuitry specific biocatalyst activity was observed with higher peak currents (10.1mA; -5.98mA) in closed circuit mode. MDC can function as sustainable and alternative solution for ground and surface water treatment with power productivity and resource recovery. Copyright © 2017 Elsevier Ltd. All rights reserved.

  4. Analysis the Existence of Heterotrophic Bacteria in Active Water Desalination Plant Output of Kashan City, Iran

    Directory of Open Access Journals (Sweden)

    Hosseindoost Gh. MSc,

    2015-12-01

    Full Text Available Aims One of the consequences of taking ground water into surface is changing its chemical quality, specially increasing the concentration of dissolved salts. This research was performed in order to analyze growth possibility of heterotrophic bacteria in the membrane of active desalination plants in Kashan City, Iran. Instrument & Methods This descriptive cross-sectional study was done on water output of 20 active desalination plants in 2013 in Kashan City, Iran and 200 specimens of input and output water was randomly extracted from desalination plants. Awareness and education level of system operators, filter changing intervals, HPC of input and output water and chlorine concentration of input and output water were measured and recorded. Obtained data were analyzed statistically with SPSS 18 software using one-way ANOVA, Chi-square, McNemar and one-sample T tests. Findings There was a significant relation between the interval time and output HPC level of the plants (p0.05. The mean concentration of chlorine in samples of 20 desalination plants was 0.76±0.44mg/l in input water and 0.64±0.52mg/l in output water (p>0.05. Level of awareness had significant relation with the output water pollution with HPC (p0.05. Conclusion The mean level of HPC

  5. Theory of pH changes in water desalination by capacitive deionization

    NARCIS (Netherlands)

    Dykstra, J.E.; Keesman, K.J.; Biesheuvel, P.M.; Wal, van der A.

    2017-01-01

    In electrochemical water desalination, a large difference in pH can develop between feed and effluent water. These pH changes can affect the long-term stability of membranes and electrodes. Often Faradaic reactions are implicated to explain these pH changes. However, quantitative theory has not

  6. Review on the science and technology of water desalination by capacitive deionization

    NARCIS (Netherlands)

    Porada, S.; Zhao, R.; Wal, van der A.; Presser, V.; Biesheuvel, P.M.

    2013-01-01

    Porous carbon electrodes have significant potential for energy-efficient water desalination using a promising technology called Capacitive Deionization (CDI). In CDI, salt ions are removed from brackish water upon applying an electrical voltage difference between two porous electrodes, in which the

  7. Optimizing desalinated sea water blending with other sources to meet magnesium requirements for potable and irrigation waters.

    Science.gov (United States)

    Avni, Noa; Eben-Chaime, Moshe; Oron, Gideon

    2013-05-01

    Sea water desalination provides fresh water that typically lacks minerals essential to human health and to agricultural productivity. Thus the rising proportion of desalinated sea water consumed by both the domestic and agricultural sectors constitutes a public health risk. Research on low-magnesium water irrigation showed that crops developed magnesium deficiency symptoms that could lead to plant death, and tomato yields were reduced by 10-15%. The World Health Organization (WHO) reported on a relationship between sudden cardiac death rates and magnesium intake deficits. An optimization model, developed and tested to provide recommendations for Water Distribution System (WDS) quality control in terms of meeting optimal water quality requirements, was run in computational experiments based on an actual regional WDS. The expected magnesium deficit due to the operation of a large Sea Water Desalination Plant (SWDP) was simulated, and an optimal operation policy, in which remineralization at the SWDP was combined with blending desalinated and natural water to achieve the required quality, was generated. The effects of remineralization costs and WDS physical layout on the optimal policy were examined by sensitivity analysis. As part of the sensitivity blending natural and desalinated water near the treatment plants will be feasible up to 16.2 US cents/m(3), considering all expenses. Additional chemical injection was used to meet quality criteria when blending was not feasible. Crown Copyright © 2013. Published by Elsevier Ltd. All rights reserved.

  8. Investigating the Potential of Single-Walled Aluminosilicate Nanotubes in Water Desalination.

    Science.gov (United States)

    Liou, Kai-Hsin; Kang, Dun-Yen; Lin, Li-Chiang

    2017-01-18

    Water shortage has become a critical issue. To facilitate the large-scale deployment of reverse-osmosis water desalination to produce fresh water, discovering novel membranes is essential. Here, we computationally demonstrate the great potential of single-walled aluminosilicate nanotubes (AlSiNTs), materials that can be synthesized through scalable methods, in desalination. State-of-the-art molecular dynamics simulations were employed to investigate the desalination performance and structure-performance relationship of AlSiNTs. Free energy profiles, passage time distribution, and water density map were also analyzed to further understand the dependence of transport properties on diameter and water dynamics in the nanotubes. AlSiNTs with an inner diameter of 0.86 nm were found to fully reject NaCl ions while allowing orders of magnitude higher water fluxes compared to currently available reverse osmosis membranes, providing opportunities in water desalination. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  9. High Recovery Desalination of Brackish Water by Chemically-Enhanced Seeded Precipitation

    OpenAIRE

    McCool, Brian Carey

    2012-01-01

    Various regions around the world are confronted with dwindling water supplies and thus the need for exploiting non-traditional inland brackish water resource, as well as reclamation and reuse of municipal wastewater and agricultural drainage (AD) water. Reverse osmosis (RO) membrane desalination is the primary technology for inland brackish water desalting. However, successful implementation of RO technology requires operation at high product water recovery (>85%) in order to minimize the vol...

  10. Tunable, Strain-Controlled Nanoporous MoS₂ Filter for Water Desalination.

    Science.gov (United States)

    Li, Weifeng; Yang, Yanmei; Weber, Jeffrey K; Zhang, Gang; Zhou, Ruhong

    2016-02-23

    The deteriorating state of global fresh water resources represents one of the most serious challenges that scientists and policymakers currently face. Desalination technologies, which are designed to extract potable water from the planet's bountiful stores of seawater, could serve to alleviate much of the stress that presently plagues fresh water supplies. In recent decades, desalination methods have improved via water-filtering architectures based on nanoporous graphene filters and artificial membranes integrated with biological water channels. Here, we report the auspicious performance (in simulations) of an alternative nanoporous desalination filter constructed from a MoS2 nanosheet. In striking contrast to graphene-based filters, we find that the "open" and "closed" states of the MoS2 filter can be regulated by the introduction of mechanical strain, yielding a highly tunable nanopore interface. By applying lateral strain to the MoS2 filter in our simulations, we see that the transition point between "open" and "closed" states occurs under tension that induces about 6% cross-sectional expansion in the membrane (6% strain); the open state of the MoS2 filter demonstrates high water transparency and a strong salt filtering capability even under 12% strain. Our results thus demonstrate the promise of a controllable nanoporous MoS2 desalination filter, wherein the morphology and size of the central nanopore can be precisely regulated by tensile strain. These findings support the design and proliferation of tunable nanodevices for filtration and other applications.

  11. Microbial Electrodialysis Cell for Simultaneous Water Desalination and Hydrogen Gas Production

    KAUST Repository

    Mehanna, Maha

    2010-12-15

    A new approach to water desalination is to use exoelectrogenic bacteria to generate electrical power from the biodegradation of organic matter, moving charged ions from a middle chamber between two membranes in a type of microbial fuel cell called a microbial desalination cell. Desalination efficiency using this approach is limited by the voltage produced by the bacteria. Here we examine an alternative strategy based on boosting the voltage produced by the bacteria to achieve hydrogen gas evolution from the cathode using a three-chambered system we refer to as a microbial electrodialysis cell (MEDC). We examined the use of the MEDC process using two different initial NaCl concentrations of 5 g/L and 20 g/L. Conductivity in the desalination chamber was reduced by up to 68 ± 3% in a single fed-batch cycle, with electrical energy efficiencies reaching 231 ± 59%, and maximum hydrogen production rates of 0.16 ± 0.05 m3 H2/m3 d obtained at an applied voltage of 0.55 V. The advantage of this system compared to a microbial fuel cell approach is that the potentials between the electrodes can be better controlled, and the hydrogen gas that is produced can be used to recover energy to make the desalination process self-sustaining with respect to electrical power requirements. © 2010 American Chemical Society.

  12. Theory of pH changes in water desalination by capacitive deionization.

    Science.gov (United States)

    Dykstra, J E; Keesman, K J; Biesheuvel, P M; van der Wal, A

    2017-08-01

    In electrochemical water desalination, a large difference in pH can develop between feed and effluent water. These pH changes can affect the long-term stability of membranes and electrodes. Often Faradaic reactions are implicated to explain these pH changes. However, quantitative theory has not been developed yet to underpin these considerations. We develop a theory for electrochemical water desalination which includes not only Faradaic reactions but also the fact that all ions in the water have different mobilities (diffusion coefficients). We quantify the latter effect by microscopic physics-based modeling of pH changes in Membrane Capacitive Deionization (MCDI), a water desalination technology employing porous carbon electrodes and ion-exchange membranes. We derive a dynamic model and include the following phenomena: I) different mobilities of various ions, combined with acid-base equilibrium reactions; II) chemical surface charge groups in the micropores of the porous carbon electrodes, where electrical double layers are formed; and III) Faradaic reactions in the micropores. The theory predicts small pH changes during desalination cycles in MCDI if we only consider phenomena I) and II), but predicts that these pH changes can be much stronger if we consider phenomenon III) as well, which is in line with earlier statements in the literature on the relevance of Faradaic reactions to explain pH fluctuations. Copyright © 2017 Elsevier Ltd. All rights reserved.

  13. Implementation of Brackish Groundwater Desalination Using Wind-Generated Electricity: A Case Study of the Energy-Water Nexus in Texas

    OpenAIRE

    Mary E. Clayton; Ashlynn S. Stillwell; Michael E. Webber

    2014-01-01

    Growing populations and periodic drought conditions have exacerbated water stress in many areas worldwide. In response, some municipalities have considered desalination of saline water as a freshwater supply. Unfortunately, desalination requires a sizeable energy investment. However, renewable energy technologies can be paired with desalination to mitigate concern over the environmental impacts of increased energy use. At the same time, desalination can be operated in an intermittent way to m...

  14. The Physical, Chemical and Microbial Quality of Treated Water in Qom s Desalination Plants

    Directory of Open Access Journals (Sweden)

    A. R. Yari

    2007-04-01

    Full Text Available Background and objectivesWater is the basis of life and health. The health of food and water supply plays an important role in human health. One of the methods of water desalination is membrane filter reverse osmosis method. This method is used for desalination of drinking water supply in Qom.MethodsThis is a descriptive, cross-sectional study designed to determine the quality of treated water in Qom desalination plant in year 2002. Inlet and outlet water samples of this plant were examined by the standard examination methods and the collected data were compared with national and international standards. Excel software was used for statistical analysis.ResultsThe results showed that the residual chlorine concentration, total hardness and fluoride concentration were lower than the minimum standard limit set for drinking water. The pH was also lower than the minimum standard limit. Microbial contamination was detected in 6% of samples.ConclusionThe results show that the acidity of water was lower than standard in whole plant. This gives corrosive properties to the water and increases the dissolution of materials, which are in contact with this water. In order to eliminate the secondary contamination, the concentration of residual chlorine should be 1 mg/l. But, none of the measurements showed a concentration as high as this value. As fluoride is an important element for health and growth of bone and teeth, especially in growing children, fluoride should be added to the drinking water. As the relationship between hardness of water and cardiovascular diseases has been established, it can be concluded that this drinking water supply can increase the risk of cardiovascular diseases in long time. Dilution of this water is recommended to adjust various factors to the standard limits and keep the total dissolved solids low.Keywords: Qom ;Water; Reverse Osmosis; Desalination Plant; Water Quality

  15. Predictive Control Applied to a Solar Desalination Plant Connected to a Greenhouse with Daily Variation of Irrigation Water Demand

    Directory of Open Access Journals (Sweden)

    Lidia Roca

    2016-03-01

    Full Text Available The water deficit in the Mediterranean area is a known matter severely affecting agriculture. One way to avoid the aquifers’ exploitation is to supply water to crops by using thermal desalination processes. Moreover, in order to guarantee long-term sustainability, the required thermal energy for the desalination process can be provided by solar energy. This paper shows simulations for a case study in which a solar multi-effect distillation plant produces water for irrigation purposes. Detailed models of the involved systems are the base of a predictive controller to operate the desalination plant and fulfil the water demanded by the crops.

  16. An investigation of desalination by nanofiltration, reverse osmosis and integrated (hybrid NF/RO) membranes employed in brackish water treatment

    OpenAIRE

    Talaeipour, M.; J.Nouri; Hassani, A. H.; A. H. Mahvi

    2017-01-01

    Background As an appropriate tool, membrane process is used for desalination of brackish water, in the production of drinking water. The present study aims to investigate desalination processes of brackish water of Qom Province in Iran. Methods This study was carried out at the central laboratory of Water and Wastewater Company of the studied area. To this aim, membrane processes, including nanofiltration (NF) and reverse osmosis (RO), separately and also their hybrid process were applied. Mo...

  17. Desalinated and blended water in Saudi Arabia: human exposure and risk analysis from disinfection byproducts

    Directory of Open Access Journals (Sweden)

    Chowdhury Imran Rahman

    2017-01-01

    Full Text Available Saudi Arabia produces the largest amount of desalinated water as a single country. The desalinated water is typically blended with treated groundwater, pH adjusted and chlorinated prior to supply to the communities. The desalinated seawater and/or blended water contains various types of disinfection byproducts (DBPs, some of which may induce cancer risks to human through lifetime exposure. In this study, occurrences of trihalomethanes (THMs in desalinated and blended water in Saudi Arabia were investigated and their exposure and risks were predicted. The chronic daily intakes of CHCl3, BDCM, DBCM and CHBr3 were estimated to be 8.38×10−5, 7.57×10−5, 2.54×10−5 and 4.32×10−4 mg/kg-day respectively. The overall cancer risk was 1.78×10−5 with the range of 7.40×10−7 – 9.26×10−5 and the average hazard index was 3.49×10−2 with the range of 1.20×10−3 – 2.34×10−1. The loss of disability adjusted life years (DALY were estimated to be 25.1 per year and the average cancer risk had 8.48×10−7 DALY per person per year. The financial burden was estimated to be US$2.72 million with the range of US$2.52–2.91 million. The findings may assist in better understanding and reducing cancer risks from DBPs in desalinated and blended water.

  18. Technical review and evaluation of the economics of water desalination: Current and future challenges for better water supply sustainability

    KAUST Repository

    Ghaffour, Noreddine

    2013-01-01

    Desalination capacity has rapidly increased in the last decade because of the increase in water demand and a significant reduction in desalination cost as a result of significant technological advances, especially in the reverse osmosis process. The cost of desalinated seawater has fallen below US$0.50/m3 for a large scale seawater reverse osmosis plant at a specific location and conditions while in other locations the cost is 50% higher (US$1.00/m3) for a similar facility. In addition to capital and operating costs, other parameters such as local incentives or subsidies may also contribute to the large difference in desalted water cost between regions and facilities. Plant suppliers and consultants have their own cost calculation methodologies, but they are confidential and provide water costs with different accuracies. The few existing costing methodologies and software packages such as WTCost© and DEEP provide an estimated cost with different accuracies and their applications are limited to specific conditions. Most of the available cost estimation tools are of the black box type, which provide few details concerning the parameters and methodologies applied for local conditions. Many desalination plants built recently have greater desalinated water delivery costs caused by special circumstances, such as plant remediation or upgrades, local variation in energy costs, and site-specific issues in raw materials costs (e.g., tariffs and transportation). Therefore, the availability of a more transparent and unique methodology for estimating the cost will help in selecting an appropriate desalination technology suitable for specific locations with consideration of all the parameters influencing the cost. A techno-economic evaluation and review of the costing aspects and the main parameters influencing the total water cost produced by different desalination technologies are herein presented in detail. Some recent developments, such as the increase of unit capacity

  19. Indirect desalination of Red Sea water with forward osmosis and low pressure reverse osmosis for water reuse

    KAUST Repository

    Yangali-Quintanilla, Victor

    2011-10-01

    The use of energy still remains the main component of the costs of desalting water. Forward osmosis (FO) can help to reduce the costs of desalination, and extracting water from impaired sources can be beneficial in this regard. Experiments with FO membranes using a secondary wastewater effluent as a feed water and Red Sea water as a draw solution demonstrated that the technology is promising. FO coupled with low pressure reverse osmosis (LPRO) was implemented for indirect desalination. The system consumes only 50% (~1.5 kWh/m3) of the energy used for high pressure seawater RO (SWRO) desalination (2.5-4 kWh/m3), and produces a good quality water extracted from the impaired feed water. Fouling of the FO membranes was not a major issue during long-term experiments over 14 days. After 10 days of continuous FO operation, the initial flux declined by 28%. Cleaning the FO membranes with air scouring and clean water recovered the initial flux by 98.8%. A cost analysis revealed FO per se as viable technology. However, a minimum average FO flux of 10.5 L/m2-h is needed to compete with water reuse using UF-LPRO, and 5.5 L/m2-h is needed to recover and desalinate water at less cost than SWRO. © 2011 Elsevier B.V.

  20. Super square carbon nanotube network: a new promising water desalination membrane

    Science.gov (United States)

    Sun, Ligang; He, Xiaoqiao; Lu, Jian

    2016-04-01

    Super square (SS) carbon nanotube (CNT) networks, acting as a new kind of nanoporous membrane, manifest excellent water desalination performance. Nanopores in SS CNT network can efficiently filter NaCl from water. The water desalination ability of such nanoporous membranes critically depends on the pore diameter, permitting water molecule permeatration while salt ion obstruction. On the basis of the systematical analysis on the interaction among water permeability, salt concentration limit and pressure on the membranes, an empirical formula is developed to describe the relationship between pressure and concentration limit. In the meantime, the nonlinear relationship between pressure and water permeability is examined. Hence, by controlling pressure, optimal plan can be easily made to efficiently filter the saltwater. Moreover, steered molecular dynamics (MD) method uncovers bending and local buckling of SS CNT network that leads to salt ions passing through membranes. These important mechanical behaviours are neglected in most MD simulations, which may overestimate the filtration ability. Overall, water permeability of such material is several orders of magnitude higher than the conventional reverse osmosis membranes and several times higher than nanoporous graphene membranes. SS CNT networks may act as a new kind of membrane developed for water desalination with excellent filtration ability.

  1. Particulate-free porous silicon networks for efficient capacitive deionization water desalination

    Science.gov (United States)

    Metke, Thomas; Westover, Andrew S.; Carter, Rachel; Oakes, Landon; Douglas, Anna; Pint, Cary L.

    2016-01-01

    Energy efficient water desalination processes employing low-cost and earth-abundant materials is a critical step to sustainably manage future human needs for clean water resources. Here we demonstrate that porous silicon – a material harnessing earth abundance, cost, and environmental/biological compatibility is a candidate material for water desalination. With appropriate surface passivation of the porous silicon material to prevent surface corrosion in aqueous environments, we show that porous silicon templates can enable salt removal in capacitive deionization (CDI) ranging from 0.36% by mass at the onset from fresh to brackish water (10 mM, or 0.06% salinity) to 0.52% in ocean water salt concentrations (500 mM, or ~0.3% salinity). This is on par with reports of most carbon nanomaterial based CDI systems based on particulate electrodes and covers the full salinity range required of a CDI system with a total ocean-to-fresh water required energy input of ~1.45 Wh/L. The use of porous silicon for CDI enables new routes to directly couple water desalination technology with microfluidic systems and photovoltaics that natively use silicon materials, while mitigating adverse effects of water contamination occurring from nanoparticulate-based CDI electrodes. PMID:27101809

  2. Reserve osmosis and its application in water desalination; Osmosis inversa y su aplicacion en la desalacion de las aguas

    Energy Technology Data Exchange (ETDEWEB)

    Lazaro, I. [Departamento de Ingenieria Aplicada, EPS Universidad Murcia, Cartagena (Spain); Almela, L. [Departamento de Quimica Agricola, Universidad de Murcia, Murcia (Spain); Huete, J.

    1996-08-01

    The limited availability of water resources raises two fundamental issues: those of restructuring traditional irrigated land and scarching for new resources to alleviate water shortage. Among the diverse methods that can be utilized for the desalination of water, reverse osmosis is now of great importance. One the advantages of this techniques is that it can be applied equally to big installations as to smaller rural holdings. This paper briefly describes the different methods of desalination, placing emphasis on reverse osmosis. (Author) 8 refs.

  3. Graphene oxide-based efficient and scalable solar desalination under one sun with a confined 2D water path.

    Science.gov (United States)

    Li, Xiuqiang; Xu, Weichao; Tang, Mingyao; Zhou, Lin; Zhu, Bin; Zhu, Shining; Zhu, Jia

    2016-12-06

    Because it is able to produce desalinated water directly using solar energy with minimum carbon footprint, solar steam generation and desalination is considered one of the most important technologies to address the increasingly pressing global water scarcity. Despite tremendous progress in the past few years, efficient solar steam generation and desalination can only be achieved for rather limited water quantity with the assistance of concentrators and thermal insulation, not feasible for large-scale applications. The fundamental paradox is that the conventional design of direct absorber-bulk water contact ensures efficient energy transfer and water supply but also has intrinsic thermal loss through bulk water. Here, enabled by a confined 2D water path, we report an efficient (80% under one-sun illumination) and effective (four orders salinity decrement) solar desalination device. More strikingly, because of minimized heat loss, high efficiency of solar desalination is independent of the water quantity and can be maintained without thermal insulation of the container. A foldable graphene oxide film, fabricated by a scalable process, serves as efficient solar absorbers (>94%), vapor channels, and thermal insulators. With unique structure designs fabricated by scalable processes and high and stable efficiency achieved under normal solar illumination independent of water quantity without any supporting systems, our device represents a concrete step for solar desalination to emerge as a complementary portable and personalized clean water solution.

  4. Potential effects of desalinated water quality on the operation stability of wastewater treatment plants.

    Science.gov (United States)

    Lew, Beni; Cochva, Malka; Lahav, Ori

    2009-03-15

    Desalinated water is expected to become the major source of drinking water in many places in the near future, and thus the major source of wastewater to arrive at wastewater treatment plants. The paper examines the effect of the alkalinity value with which the water is released from the desalination plant on the alkalinity value that would develop within the wastewater treatment process under various nitrification-denitrification operational scenarios. The main hypothesis was that the difference in the alkalinity value between tap water and domestic wastewater is almost exclusively a result of the hydrolysis of urea (NH(2)CONH(2), excreted in the human urine) to ammonia (NH(3)), regardless of the question what fraction of NH(3(aq)) is transformed to NH(4)(+). Results from a field study show that the ratio between the alkalinity added to tap water when raw wastewater is formed (in meq/l units) and the TAN (total ammonia nitrogen, mole/l) concentration in the raw wastewater is almost 1:1 in purely domestic sewage and close to 1:1 in domestic wastewater streams mixed with light industry wastewaters. Having established the relationship between TAN and total alkalinity in raw wastewater the paper examines three theoretical nitrification-denitrification treatment scenarios in the wastewater treatment plant (WWTP). The conclusion is that if low-alkalinity desalinated water constitutes the major water source arriving at the WWTP, external alkalinity will have to be added in order to avoid pH drop and maintain process stability. The results lead to the conclusion that supplying desalinated water with a high alkalinity value (e.g. > or =100 mg/l as CaCO(3)) would likely prevent the need to add costly basic chemicals in the WWTP, while, in addition, it would improve the chemical and biological stability of the drinking water in the distribution system.

  5. THE USE OF SOLAR ENERGY IN THE DESALINATION SEA WATER IN AGRICULTURAL GREENHOUSE

    Directory of Open Access Journals (Sweden)

    T. Tahri

    2015-08-01

    Full Text Available The limited resources of fresh water in arid areas like the Middle East and North Africa MENA have led to the use of poor quality water in irrigation agriculture. These can reduce crop yield and environmental damage. Agriculture accounts for 70% of overall consumption in freshwater. Given the evaporation phenomena that occur in arid regions, this figure rises to 90%. This study focuses on the concept of combining the greenhouse with the desalination of seawater This concept is intended for small scale applications in remote areas where only saline water and solar energy are available.  The main objective of this research work is to analyze the production of fresh water using solar energy in the desalination of sea water in the greenhouse. This operating system is in need of thorough study of evaporators, condensers and design of the greenhouse. Desalination, combining the greenhouse to the use of sea water while exploiting the phenomenon of condensation of water vapor in the air, seems to respond positively to the needs of agricultural irrigation.

  6. Adsorption Characteristics of Water and Silica Gel System for Desalination Cycle

    KAUST Repository

    Cevallos, Oscar R.

    2012-07-01

    An adsorbent suitable for adsorption desalination cycles is essentially characterized by a hydrophilic and porous structure with high surface area where water molecules are adsorbed via hydrogen bonding mechanism. Silica gel type A++ possesses the highest surface area and exhibits the highest equilibrium uptake from all the silica gels available in the market, therefore being suitable for water desalination cycles; where adsorbent’s adsorption characteristics and water vapor uptake capacity are key parameters in the compactness of the system; translated as feasibility of water desalination through adsorption technologies. The adsorption characteristics of water vapor onto silica gel type A++ over a temperature range of 30 oC to 60 oC are investigated in this research. This is done using water vapor adsorption analyzer utilizing a constant volume and variable pressure method, namely the Hydrosorb-1000 instrument by Quantachrome. The experimental uptake data is studied using numerous isotherm models, i. e. the Langmuir, Tóth, generalized Dubinin-Astakhov (D-A), Dubinin-Astakhov based on pore size distribution (PSD) and Dubinin-Serpinski (D-Se) isotherm for the whole pressure range, and for a pressure range below 10 kPa, proper for desalination cycles; isotherms type V of the International Union of Pure and Applied Chemistry (IUPAC) classification were exhibited. It is observed that the D-A based on PSD and the D-Se isotherm models describe the best fitting of the experimental uptake data for desalination cycles within a regression error of 2% and 6% respectively. All isotherm models, except the D-A based on PSD, have failed to describe the obtained experimental uptake data; an empirical isotherm model is proposed by observing the behavior of Tóth and D-A isotherm models. The new empirical model describes the water adsorption onto silica gel type A++ within a regression error of 3%. This will aid to describe the advantages of silica gel type A++ for the design of

  7. Integrating desalination to reservoir operation to increase redundancy for more secure water supply

    Science.gov (United States)

    Bhushan, Rashi; Ng, Tze Ling

    2016-08-01

    We investigate the potential of integrating desalination to existing reservoir systems to mitigate supply uncertainty. Desalinated seawater and wastewater are relatively reliable but expensive. Water from natural resources like reservoirs is generally cheaper but climate sensitive. We propose combining the operation of a reservoir and seawater and wastewater desalination plants for an overall system that is less vulnerable to scarcity and uncertainty, while constraining total cost. The joint system is modeled as a multiobjective optimization problem with the double objectives of minimizing risk and vulnerability, subject to a minimum limit on resilience. The joint model is applied to two cases, one based on the climate and demands of a location in India and the other of a location in California. The results for the Indian case indicate that it is possible for the joint system to reduce risk and vulnerability to zero given a budget increase of 20-120% under current climate conditions and 30-150% under projected future conditions. For the Californian case, this would require budget increases of 20-80% and 30-140% under current and future conditions, respectively. Further, our analysis shows a two-way interaction between the reservoir and desalination plants where the optimal operation of the former is just as much affected by the latter as the latter by the former. This highlights the importance of an integrated management approach. This study contributes to a greater quantitative understanding of desalination as a redundancy measure for adapting water supply infrastructures for a future of greater scarcity and uncertainty.

  8. Water recovery from brines and salt-saturated solutions: operability and thermodynamic efficiency considerations for desalination technologies

    Science.gov (United States)

    This review provides an overview of desalination technologies and discusses the thermodynamic efficiencies and operational issues associated with the various technologies particularly with regard to high salinity streams. When water is recovered from a saline source, a brine conc...

  9. Use of drinking water treatment solids for arsenate removal from desalination concentrate.

    Science.gov (United States)

    Xu, Xuesong; Lin, Lu; Papelis, Charalambos; Myint, Maung; Cath, Tzahi Y; Xu, Pei

    2015-05-01

    Desalination of impaired water can be hindered by the limited options for concentrate disposal. Selective removal of specific contaminants using inexpensive adsorbents is an attractive option to address the challenges of concentrate management. In this study, two types of ferric-based drinking water treatment solids (DWTS) were examined for arsenate removal from reverse osmosis concentrate during continuous-flow once-through column experiments. Arsenate sorption was investigated under different operating conditions including pH, arsenate concentration, hydraulic retention time, loading rate, temperature, and moisture content of the DWTS. Arsenate removal by the DWTS was affected primarily by surface complexation, electrostatic interactions, and arsenate speciation. Results indicated that arsenate sorption was highly dependent on initial pH and initial arsenate concentration. Acidic conditions enhanced arsenate sorption as a result of weaker electrostatic repulsion between predominantly monovalent H2AsO4(-) and negatively charged particles in the DWTS. High initial arsenate concentration increased the driving force for arsenate sorption to the DWTS surface. Tests revealed that the potential risks associated with the use of DWTS include the leaching of organic contaminants and ammonia, which can be alleviated by using wet DWTS or discarding the initially treated effluent that contains high organic concentration. Copyright © 2015 Elsevier Inc. All rights reserved.

  10. The effect of flow and chemical corrosion in reverse osmosis over desalinated water

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Young Jae [Chunnam National Univ., Gwangju (Korea, Republic of); Pak, Byung Gu [Doosan Heavy Industry Co., Tongyoung (Korea, Republic of)

    2015-12-15

    Desalinated water produced by a reverse osmosis (RO) filtering method forms about 22% of total production of desalinated water in the world. However, the RO environment is very corrosive due to the presence of various chemicals for water treatment and the flow of sand particles leading to corrosion. Recently, there has been much effort to substitute cheaper and more corrosion resistant stainless steels for copper based alloys as a valve material in RO. Nevertheless, the effects of chemicals and particles on the corrosion of stainless steels have rarely been studied. Erosion phenomenon was detected under the condition with the flow rate of more than 8ms{sup -1} in spite of the absence of sand particles. In seawater containing sand particles, the erosion in stainless steels was accelerated further.

  11. Toward high permeability, selectivity and controllability of water desalination with FePc nanopores.

    Science.gov (United States)

    Deng, Qingming; Pan, Jun; Yin, Xiaohui; Wang, Xiaofeng; Zhao, Lina; Kang, Seung-gu; Jimenez-Cruz, Camilo A; Zhou, Ruhong; Li, Jingyuan

    2016-03-21

    Nanoporous materials exhibit promising potential in water transportation applications, especially in ocean water desalination. It is highly desired to have great permeability, selectivity and controllability in the desalination performance of these nanopores. However, it is still a challenge to achieve all three features in one material or device. Here, we demonstrate efficient and controllable water desalination with a nanoporous 2D Fe phthalocyanine (FePc) membrane using molecular dynamics simulations. We find the FePc membrane not only conducts fast water flow, but it also suppresses ion permeation. The selectivity is attributed to a mechanism distinct from the traditional steric exclusion: cations are excluded due to electrostatic repulsion, whereas anions can be trapped in the nanopore and induce the reorganization of ions in the vicinity of the nanopore, which in turn creates a tendency for the trapped anions to move back into the saline reservoir. More interestingly, we find such mechanism is largely due to the sufficiently strong electrostatic interaction of the charged nanopore region with ions and is not restricted to the FePc nanopore. In addition, the number of protonated nitrogen atoms in FePc pores can be modulated by adjusting the pH value of the solution. The extent of the anion occupancy can thus be regulated, giving rise to control of the water flow. Taken together, great permeability, selectivity and controllability can be achieved with this nanosheet system. Moreover, our study suggests there is an alternative mechanism of water desalination which may be realized by intrinsically nanoporous materials such as FePc membranes.

  12. Shale gas produced water treatment using innovative microbial capacitive desalination cell.

    Science.gov (United States)

    Stoll, Zachary A; Forrestal, Casey; Ren, Zhiyong Jason; Xu, Pei

    2015-01-01

    The rapid development of unconventional oil and gas production has generated large amounts of wastewater for disposal, raising significant environmental and public health concerns. Treatment and beneficial use of produced water presents many challenges due to its high concentrations of petroleum hydrocarbons and salinity. The objectives of this study were to investigate the feasibility of treating actual shale gas produced water using a bioelectrochemical system integrated with capacitive deionization-a microbial capacitive desalination cell (MCDC). Microbial degradation of organic compounds in the anode generated an electric potential that drove the desalination of produced water. Sorption and biodegradation resulted in a combined organic removal rate of 6.4 mg dissolved organic carbon per hour in the reactor, and the MCDC removed 36 mg salt per gram of carbon electrode per hour from produced water. This study is a proof-of-concept that the MCDC can be used to combine organic degradation with desalination of contaminated water without external energy input. Copyright © 2014 Elsevier B.V. All rights reserved.

  13. Economic Analysis of a Brackish Water Photovoltaic-Operated (BWRO-PV) Desalination System: Preprint

    Energy Technology Data Exchange (ETDEWEB)

    Al-Karaghouli, A.; Kazmerski, L. L.

    2010-10-01

    The photovoltaic (PV)-powered reverse-osmosis (RO) desalination system is considered one of the most promising technologies in producing fresh water from both brackish and sea water, especially for small systems located in remote areas. We analyze the economic viability of a small PV-operated RO system with a capacity of 5 m3/day used to desalinate brackish water of 4000 ppm total dissolve solids, which is proposed to be installed in a remote area of the Babylon governorate in the middle of Iraq; this area possesses excellent insolation throughout the year. Our analysis predicts very good economic and environmental benefits of using this system. The lowest cost of fresh water achieved from using this system is US $3.98/ m3, which is very reasonable compared with the water cost reported by small-sized desalination plants installed in rural areas in other parts of the world. Our analysis shows that using this small system will prevent the release annually of 8,170 kg of CO2, 20.2 kg of CO, 2.23 kg of CH, 1.52 kg of particulate matter, 16.41 kg of SO2, and 180 kg of NOx.

  14. A framework for investigating the interactions between climate, dust, solar power generation and water desalination processes in Desert Climate

    Science.gov (United States)

    Siam, M. S.; Alqatari, S.; Ibrahim, H. D.; AlAloula, R. A.; Alrished, M.; AlSaati, A.; Eltahir, E. A. B.

    2016-12-01

    Increasing water demand in Saudi Arabia due to rapid population growth has forced the rapid expansion of seawater desalination plants in order to meet both current and future freshwater needs. Saudi Arabia has a huge potential for solar energy, hence, solar-powered desalination plants provide an opportunity to sustainably address the freshwater demand in the kingdom without relying on fossil fuels energy. However, the desert climate of Saudi Arabia and limited access to the open ocean imposes several challenges to the expansion and sustainability of solar-powered desalination plants. For example, the frequent and intense dust storms that occur in the region can degrade solar panels and significantly reduce their efficiency. Moreover, the high salinity Arabian Gulf is both the source of feedwater and sink of hypersaline discharge (brine) for many plants in the east of the Kingdom, and the brine may alter the salinity, temperature and movement of the water thereby reducing the quality of the feedwater to the desalination plants. Here, we propose a framework to investigate the different interactions between climate, dust, solar power generation and seawater desalination in order to identify optimal parameters such as locations of solar panels and seawater intake for sustainable implementation of solar-powered desalination plants. This framework integrates several numerical models including regional climate, hydrodynamics, Photovoltaics (PV) and Photovoltaic-Reverse Osmosis (PV-RO) models that are used to investigate these interactions for a solar-powered desalination plant at AlKhafji on the Northeastern coast of Saudi Arabia.

  15. Bioelectrochemical systems-driven directional ion transport enables low-energy water desalination, pollutant removal, and resource recovery.

    Science.gov (United States)

    Chen, Xi; Liang, Peng; Zhang, Xiaoyuan; Huang, Xia

    2016-09-01

    Bioelectrochemical systems (BESs) are integrated water treatment technologies that generate electricity using organic matter in wastewater. In situ use of bioelectricity can direct the migration of ionic substances in a BES, thereby enabling water desalination, resource recovery, and valuable substance production. Recently, much attention has been placed on the microbial desalination cells in BESs to drive water desalination, and various configurations have optimized electricity generation and desalination performance and also coupled hydrogen production, heavy metal reduction, and other reactions. In addition, directional transport of other types of charged ions can remediate polluted groundwater, recover nutrient, and produce valuable substances. To better promote the practical application, the use of BESs as directional drivers of ionic substances requires further optimization to improve energy use efficiency and treatment efficacy. This article reviews existing researches on BES-driven directional ion transport to treat wastewater and identifies a few key factors involved in efficiency optimization. Copyright © 2016 Elsevier Ltd. All rights reserved.

  16. The Physical, Chemical and Microbial Quality of Treated Water in Qom s Desalination Plants

    Directory of Open Access Journals (Sweden)

    A.R Yari

    2012-05-01

    Full Text Available

    Background and objectives

    Water is the basis of life and health. The health of food and water supply plays an important role in human health. One of the methods of water desalination is membrane filter reverse osmosis method. This method is used for desalination of drinking water supply in Qom.

    Methods

    This is a descriptive, cross-sectional study designed to determine the quality of treated water in Qom desalination plant in year 2002. Inlet and outlet water samples of this plant were examined by the standard examination methods and the collected data were compared with national and international standards. Excel software was used for statistical analysis.

    Results

    The results showed that the residual chlorine concentration, total hardness and fluoride concentration were lower than the minimum standard limit set for drinking water. The pH was also lower than the minimum standard limit. Microbial contamination was detected in 6% of samples.

    Conclusion

    The results show that the acidity of water was lower than standard in whole plant. This gives corrosive properties to the water and increases the dissolution of materials, which are in contact with this water. In order to eliminate the secondary contamination, the concentration of residual chlorine should be 1 mg/l. But, none of the measurements showed a concentration as high as this value. As fluoride is an important element for health and growth of bone and teeth, especially in growing children, fluoride should be added to the drinking water. As the relationship between hardness of water and cardiovascular diseases has been established, it can be concluded that this drinking water supply can increase the risk of cardiovascular diseases in long time. Dilution of this water is recommended to adjust various factors to the standard limits and keep the total dissolved solids low.

  17. Volume 1: Survey of Available Information in Support of the Energy-Water Bandwidth Study of Desalination Systems

    Energy Technology Data Exchange (ETDEWEB)

    Rao, Prakash [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Aghajanzadeh, Arian [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Sheaffer, Paul [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Morrow, William R. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Brueske, Sabine [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Dollinger, Caroline [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Price, Kevin [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Sarker, Prateeti [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Ward, Nicholas [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Cresko, Joe [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

    2016-10-01

    The U.S. Department of Energy (DOE) has set a goal to reduce the cost of seawater desalination systems to $0.50/ cubic meter (m3) through the development of technology pathways to reduce energy, capital, operating, soft, and system integration costs.1 In support of this goal and to evaluate the technology pathways to lower the energy and carbon intensity of desalination while also reducing the total water cost, DOE is undertaking a comprehensive study of the energy consumption and carbon dioxide (CO2) emissions for desalination technologies and systems. This study is being undertaken in two phases. Phase 1, Survey of Available Information in Support of the Energy-Water Bandwidth Study of Desalination Systems, collected the background information that will underpin Phase 2, the Energy Water Bandwidth Study for Desalination Systems. This report (Volume 1) summarizes the results from Phase 1. The results from Phase 2 will be summarized in Volume 2: Energy Water Bandwidth Study for Desalination Systems (Volume 2). The analysis effort for Phase 2 will utilize similar methods as other industry-specific Energy Bandwidth Studies developed by DOE,2 which has provided a framework to evaluate and compare energy savings potentials within and across manufacturing sectors at the macroscale. Volume 2 will assess the current state of desalination energy intensity and reduction potential through the use of advanced and emerging technologies. For the purpose of both phases of study, energy intensity is defined as the amount of energy required per unit of product water output (for example, kilowatt-hours per cubic meter of water produced). These studies will expand the scope of previous sectorial bandwidth studies by also evaluating CO2 intensity and reduction opportunities and informing a techno-economic analysis of desalination systems. Volume 2 is expected to be completed in 2017.

  18. Indirect contact freeze water desalination for an ice maker machine - CFD simulation

    Science.gov (United States)

    Jayakody, Harith; Al-Dadah, Raya; Mahmoud, Saad

    2017-11-01

    To offer for potable water shortages, sea water desalination is a potential solution for the global rising demand for fresh water. The latent heat of fusion is about one-seventh the latent heat of vaporisation, thus indicating the benefit of lower energy consumption for the freeze desalination process. Limited literature is reported on computational fluid dynamics (CFD) on freeze desalination. Therefore, analysing and investigating thermodynamic processes are easily conducted by the powerful tool of CFD. A single unit of ice formation in an ice maker machine was modelled using ANSYS Fluent software three-dimensionally. Energy, species transport and solidification/melting modules were used in building the CFD model. Parametric analysis was conducted using the established CFD model to predict the effects of freezing temperature and the geometry of the ice maker machine; on ice production and the freezing time. Lower freezing temperatures allowed more ice production and faster freezing. Increasing the diameter and the length of the freezing tube enabled more ice to be produced.

  19. Fertiliser drawn forward osmosis process: Pilot-scale desalination of mine impaired water for fertigation

    KAUST Repository

    Phuntsho, Sherub

    2016-02-20

    The pilot-scale fertiliser driven forward osmosis (FDFO) and nanofiltration (NF) system was operated in the field for about six months for the desalination of saline groundwater from the coal mining activities. Long-term operation of the FDFO-NF system indicates that simple hydraulic cleaning could effectively restore the water flux with minimal chemical cleaning frequency. No fouling/scaling issues were encountered with the NF post-treatment process. The study indicates that, FDFO-NF desalination system can produce water quality that meets fertigation standard. This study also however shows that, the diffusion of solutes (both feed and draw) through the cellulose triacetate (CTA) FO membrane could be one of the major issues. The FO feed brine failed to meet the effluent discharge standard for NH4+ and SO42+ (reverse diffusion) and their concentrations are expected to further increase at higher feed recovery rates. Low rejection of feed salts (Na+, Cl−) by FO membrane may result in their gradual build-up in the fertiliser draw solution (DS) in a closed FDFO-NF system eventually affecting the final water quality unless it is balanced by adequate bleeding from the system through NF and re-reverse diffusion towards the FO feed brine. Therefore, FO membrane with higher reverse flux selectivity than the CTA-FO membrane used in this study is necessary for the application of the FDFO desalination process.

  20. The sea water desalination by the nuclear reactors; Le dessalement de l'eau de mer par les reacteurs nucleaires

    Energy Technology Data Exchange (ETDEWEB)

    Nisan, S. [CEA Cadarache, Dir. du Developpement et de l' Innovation Nucleares DDIN, 13 - Saint-Paul-lez-Durance (France)

    2002-07-01

    This document underlines the importance of water shortage in many areas in the world in the future. The water sea desalination can be a efficient solution to this problem. The desalination methods are presented. In this context the desalination reactors appear as a competitive solution, facing the fossil energies systems not only for the simultaneous electric power and drinking water production, but also for the minimization of greenhouse gases. (A.L.B.)

  1. Feasibility study of an electrodialysis system for in-home water desalination in urban India

    Directory of Open Access Journals (Sweden)

    Kishor G. Nayar

    Full Text Available Poor quality of drinking water delivered to homes by state utilities, and a large reliance on brackish ground water resources in parts of urban India, has resulted in the adoption of in-home water treatment solutions. The only existing in-home water treatment solution capable of desalination is reverse osmosis (RO. However, existing RO products can recover only 25–50% of the feed water supplied as usable product water. In this study, an alternative solution that relies on electrodialysis (ED was designed and experimentally shown to achieve a recovery of 80%, producing 12 L/h of water at the desired salinity of 350 ppm from a feed salinity of 3000 ppm. The cost and size of the proposed system were also found to be comparable to existing in-home RO systems. In-home ED water treatment systems could compete with existing RO products while providing the advantage of improved water-conservation in water-stressed India. Keywords: Electrodialysis, Desalination, Reverse osmosis, Brackish water

  2. Desalination of Produced Water via Gas Hydrate Formation and Post Treatment

    OpenAIRE

    Niu, Jing

    2012-01-01

    This study presents a two-step desalination process, in which produced water is cleaned by forming gas hydrate in it and subsequently dewatering the hydrate to remove the residual produced water trapped in between the hydrate crystals. All experiments were performed with pressure in the range of 450 to 800psi and temperature in the range of -1 to 1°C using CO? as guest molecule for the hydrate crystals. The experiments were conducted using artificial produced waters containing different amoun...

  3. Impact of seawater-quality and water treatment procedures on the active bacterial assemblages at two desalination sites.

    Science.gov (United States)

    Manes, C-L de O; Barbe, C; West, N J; Rapenne, S; Lebaron, P

    2011-07-15

    Inorganic and organic compounds, particles and microorganisms in intake waters are mainly responsible for fouling of reverse osmosis membranes, which reduces the efficiency of the desalination process. The characterization of seawater quality to better predict its fouling potential remains a challenge for the desalination field and little is known about the seasonal variability of water quality parameters in the coastal waters used to supply desalination plants. In this study, standard water quality methods were combined with flow cytometry and molecular methods (16S rRNA sequencing and fingerprinting) to assess in parallel, the physicochemical properties, the microbial abundance and the active microbial community composition of the intake waters and their associated pretreated waters at two desalination sites from July 2007 to July 2008. The overall assessment of quality parameters revealed that microfiltration followed by slow sand filtration were the most efficient in removing microorganisms than the conventional dual media filtration routinely used in full-scale desalination plants, and that all treatments were inefficient for organic matter reduction. Temporal variation of the environmental parameters such as temperature, turbidity and silt density index only moderately affected the bacterial community structure in raw waters, but that interestingly, water treatment compartments changed the composition and diversity of the metabolically active bacterial populations and thus create distinct ecological post-treatment niches.

  4. Microfluidic desalination techniques and their potential applications

    NARCIS (Netherlands)

    Roelofs, Susan Helena; van den Berg, Albert; Odijk, Mathieu

    2015-01-01

    In this review we discuss recent developments in the emerging research field of miniaturized desalination. Traditionally desalination is performed to convert salt water into potable water and research is focused on improving performance of large-scale desalination plants. Microfluidic desalination

  5. Source water quality shaping different fouling scenarios in a full-scale desalination plant at the Red Sea

    KAUST Repository

    Khan, Muhammad

    2013-02-01

    The complexity of Reverse Osmosis (RO) membrane fouling phenomenon has been widely studied and several factors influencing it have been reported by many researchers. This original study involves the investigation of two different fouling profiles produced at a seawater RO desalination plant installed on a floating mobile barge. The plant was moved along the coastline of the Red Sea in Saudi Arabia. The two locations where the barge was anchored showed different water quality. At the second location, two modules were harvested. One of the modules was pre-fouled by inorganics during plant operation at the previous site while the other was installed at the second site. Fouled membranes were subjected to a wide range of chemical and microbiological characterization procedures. Drastically different fouling patterns were observed in the two membranes which indicates the influence of source water quality on membrane surface modification and on fouling of RO membranes. © 2012 Elsevier Ltd.

  6. Enhanced water desalination efficiency in an air-cathode stacked microbial electrodeionization cell (SMEDIC)

    KAUST Repository

    Chehab, Noura A.

    2014-11-01

    A microbial desalination cell was developed that contained a stack of membranes packed with ion exchange resins between the membranes to reduce ohmic resistances and improve performance. This new configuration, called a stacked microbial electro-deionization cell (SMEDIC), was compared to a control reactor (SMDC) lacking the resins. The SMEDIC+S reactors contained both a spacer and 1.4±0.2. mL of ion exchange resin (IER) per membrane channel, while the spacer was omitted in the SMEDIC-S reactors and so a larger volume of resin (2.4±0.2. mL) was used. The overall extent of desalination using the SMEDIC with a moderate (brackish water) salt concentration (13. g/L) was 90-94%, compared to only 60% for the SMDC after 7 fed-batch cycles of the anode. At a higher (seawater) salt concentration of 35. g/L, the extent of desalination reached 61-72% (after 10 cycles) for the SMEDIC, compared to 43% for the SMDC. The improved performance was shown to be due to the reduction in ohmic resistances, which were 130. Ω (SMEDIC-S) and 180. Ω (SMEDIC+S) at the high salt concentration, compared to 210. Ω without resin (SMDC). These results show that IERs can improve performance of stacked membranes for both moderate and high initial salt concentrations. © 2014 Elsevier B.V.

  7. Ab Initio Density Functional Theory Investigation of the Interaction between Carbon Nanotubes and Water Molecules during Water Desalination Process

    Directory of Open Access Journals (Sweden)

    Loay A. Elalfy

    2013-01-01

    Full Text Available Density functional theory calculations using B3LYP/3-21G level of theory have been implemented on 6 carbon nanotubes (CNTs structures (3 zigzag and 3 armchair CNTs to study the energetics of the reverse osmosis during water desalination process. Calculations of the band gap, interaction energy, highest occupied molecular orbital, lowest unoccupied molecular orbital, electronegativity, hardness, and pressure of the system are discussed. The calculations showed that the water molecule that exists inside the CNT is about 2-3 Å away from its wall. The calculations have proven that the zigzag CNTs are more efficient for reverse osmosis water desalination process than armchair CNTs as the reverse osmosis process requires pressure of approximately 200 MPa for armchair CNTs, which is consistent with the values used in molecular dynamics simulations, while that needed when using zigzag CNTs was in the order of 60 MPa.

  8. Improving the performance of water desalination through ultra-permeable functionalized nanoporous graphene oxide membrane

    Science.gov (United States)

    Hosseini, Mostafa; Azamat, Jafar; Erfan-Niya, Hamid

    2018-01-01

    Molecular dynamics simulations were performed to investigate the water desalination performance of nanoporous graphene oxide (NPGO) membranes. The simulated systems consist of a NPGO as a membrane with a functionalized pore in its center immersed in an aqueous ionic solution and a graphene sheet as a barrier. The considered NPGO membranes are involved four types of pore with different size and chemistry. The results indicated that the NPGO membrane has effective efficiency in salt rejection as well as high performance in water flux. For all types of pore with the radius size of 2.9-4.5 Å, the NPGO shows salt rejection of >89%. Functional groups on the surface and edge of pores have a great effect on water flux. To precisely understand the effect of functional groups on the surface of nanostructured membranes, nanoporous graphene was simulated under the same condition for comparison. Hydrophilic groups on the surface make the NPGO as an ultra-permeable membrane. As a result, the obtained water flux for NPGO was about 77% greater than graphene. Also, it was found that the water flux of NPGO is 2-5 orders of magnitude greater than other existing reverse osmosis membranes. Therefore, the investigated systems can be recommended as a model for the water desalination.

  9. Water and Salt Transport Properties of Triptycene-Containing Sulfonated Polysulfone Materials for Desalination Membrane Applications.

    Science.gov (United States)

    Luo, Hongxi; Aboki, Joseph; Ji, Yuanyuan; Guo, Ruilan; Geise, Geoffrey M

    2018-01-31

    A series of triptycene-containing sulfonated polysulfone (TRP-BP) materials was prepared via condensation polymerization, and the desalination membrane-relevant fundamental water and salt transport properties (i.e., sorption, diffusion, and permeability coefficients) of the polymers were characterized. Incorporating triptycene into sulfonated polysulfone increased the water content of the material compared to sulfonated polysulfone materials that do not contain triptycene. No significant difference in salt sorption was observed between TRP-BP membranes and other sulfonated polysulfone membranes, suggesting that the presence of triptycene in the polymer did not dramatically affect thermodynamic interactions between salt and the polymer. Both water and salt diffusion coefficients in the TRP-BP membranes were suppressed relative to other sulfonated polysulfone materials with comparable water content, and these phenomena may result from the influence of triptycene on polymer chain packing and/or free-volume distribution, which could increase the tortuosity of the transport pathways in the polymers. Enhanced water/salt diffusivity selectivity was observed for some of the TRP-BP membranes relative to those materials that did not contain triptycene, and correspondingly, incorporation of triptycene into sulfonated polysulfone resulted in an increase, particularly for acid counterion form TRP-BP materials, in water/salt permeability selectivity, which is favorable for desalination membrane applications.

  10. The Seminole Project: Renewable Energy for Municipal Water Desalination

    National Research Council Canada - National Science Library

    Rainwater, Ken; Nash, Phil; Song, Lianfa; Schroeder, John

    2013-01-01

    .... Financial support was from the City of Seminole, Department of Energy, Texas Water Development Board, Bureau of Reclamation, Texas Department of Agriculture, and State Energy Conservation Office...

  11. Desalination: a national perspective

    National Research Council Canada - National Science Library

    Committee on Advancing Desalination Technology; National Research Council

    2008-01-01

    ... States lags behind that of many other countries. Concerns have been raised that technological barriers and financial costs prohibit broader desalination implementation. The committee formed by the Water Science and Technology Board of the National Research Council (NRC) performed a critical analysis of current desalination technologies and the barriers to...

  12. Investigating geochemical aspects of managed aquifer recharge by column experiments with alternating desalinated water and groundwater.

    Science.gov (United States)

    Ronen-Eliraz, Gefen; Russak, Amos; Nitzan, Ido; Guttman, Joseph; Kurtzman, Daniel

    2017-01-01

    Managed aquifer recharge (MAR) events are occasionally carried out with surplus desalinated seawater that has been post-treated with CaCO 3 in infiltration ponds overlying the northern part of the Israeli Coastal Aquifer. This water's chemical characteristics differ from those of any other water recharged to the aquifer and of the natural groundwater. As the MAR events are short (hours to weeks), the sediment under the infiltration ponds will intermittently host desalinated and natural groundwater. As part of comprehensive research on the influence of those events, column experiments were designed to simulate the alternation of the two water types: post-treated desalinated seawater (PTDES) and natural groundwater (GW). Each experiment included three stages: (i) saturation with GW; (ii) inflow of PTDES; (iii) inflow of GW. Three runs were conducted, each with different sediments extracted from the field and representing a different layer below the infiltration pond: (i) sand (<1% CaCO 3 ), (ii) sand containing 7% CaCO 3 , and (iii) crushed calcareous sandstone (35% CaCO 3 ). The results from all columns showed enrichment of K + and Mg 2+ (up to 0.4meq/L for 20 pore volumes) when PTDES replaced GW, whereas an opposite trend of Ca 2+ depletion (up to 0.5meq/L) was observed only in the columns that contained a high percentage of CaCO 3 . When GW replaced PTDES, depletion of Mg 2+ and K + was noted. The results indicated that adsorption/desorption of cations are the main processes causing the observed enrichment/depletion. It was concluded that the high concentration of Ca 2+ (relative to the total concentration of cations) and the low concentration of Mg 2+ in the PTDES relative to natural GW are the factors controlling the main sediment-water interaction. The enrichment of PTDES with Mg 2+ may be viewed as an additional post-treatment. Copyright © 2016 Elsevier B.V. All rights reserved.

  13. Using microbial desalination cells to reduce water salinity prior to reverse osmosis

    KAUST Repository

    Mehanna, Maha

    2010-01-01

    A microbial desalination cell (MDC) is a new method to reduce the salinity of one solution while generating electrical power from organic matter and bacteria in another (anode) solution. Substantial reductions in the salinity can require much larger volumes of the anode solution than the saline water, but any reduction of salinity will benefit the energy efficiency of a downstream reverse osmosis (RO) desalination system. We investigated here the use of an MDC as an RO pre-treatment method using a new type of air-cathode MDC containing three equally sized chambers. A single cycle of operation using a 1 g L -1 acetate solution reduced the conductivity of salt water (5 g L-1 NaCl) by 43 ± 6%, and produced a maximum power density of 480 mW m-2 with a coulombic efficiency of 68 ± 11%. A higher concentration of acetate (2 g L-1) reduced solution conductivity by 60 ± 7%, and a higher salt concentration (20 g L-1 NaCl) reduced solution conductivity by 50 ± 7%. The use of membranes with increased ion exchange capacities further decreased the solution conductivity by 63 ± 2% (20 g L-1 NaCl). These results demonstrate substantial (43-67%) desalination of water is possible using equal volumes of anode solution and salt water. These results show that MDC treatment could be used to substantially reduce salt concentrations and thus energy demands for downstream RO processing, while at the same time producing electrical power. © 2010 The Royal Society of Chemistry.

  14. A Desalination Battery

    KAUST Repository

    Pasta, Mauro

    2012-02-08

    Water desalination is an important approach to provide fresh water around the world, although its high energy consumption, and thus high cost, call for new, efficient technology. Here, we demonstrate the novel concept of a "desalination battery", which operates by performing cycles in reverse on our previously reported mixing entropy battery. Rather than generating electricity from salinity differences, as in mixing entropy batteries, desalination batteries use an electrical energy input to extract sodium and chloride ions from seawater and to generate fresh water. The desalination battery is comprised by a Na 2-xMn 5O 10 nanorod positive electrode and Ag/AgCl negative electrode. Here, we demonstrate an energy consumption of 0.29 Wh l -1 for the removal of 25% salt using this novel desalination battery, which is promising when compared to reverse osmosis (∼ 0.2 Wh l -1), the most efficient technique presently available. © 2012 American Chemical Society.

  15. Water desalination with a single-layer MoS2 nanopore

    Science.gov (United States)

    Heiranian, Mohammad; Farimani, Amir Barati; Aluru, Narayana R.

    2015-01-01

    Efficient desalination of water continues to be a problem facing the society. Advances in nanotechnology have led to the development of a variety of nanoporous membranes for water purification. Here we show, by performing molecular dynamics simulations, that a nanopore in a single-layer molybdenum disulfide can effectively reject ions and allow transport of water at a high rate. More than 88% of ions are rejected by membranes having pore areas ranging from 20 to 60 Å2. Water flux is found to be two to five orders of magnitude greater than that of other known nanoporous membranes. Pore chemistry is shown to play a significant role in modulating the water flux. Pores with only molybdenum atoms on their edges lead to higher fluxes, which are ∼70% greater than that of graphene nanopores. These observations are explained by permeation coefficients, energy barriers, water density and velocity distributions in the pores. PMID:26465062

  16. Advances in Membrane Distillation for Water Desalination and Purification Applications

    Directory of Open Access Journals (Sweden)

    Juan Gomez

    2013-01-01

    Full Text Available Membrane distillation is a process that utilizes differences in vapor pressure to permeate water through a macro-porous membrane and reject other non-volatile constituents present in the influent water. This review considers the fundamental heat and mass transfer processes in membrane distillation, recent advances in membrane technology, module configurations, and the applications and economics of membrane distillation, and identifies areas that may lead to technological improvements in membrane distillation as well as the application characteristics required for commercial deployment.

  17. Exceptionally fast water desalination at complete salt rejection by pristine graphyne monolayers

    Science.gov (United States)

    Xue, Minmin; Qiu, Hu; Guo, Wanlin

    2013-12-01

    Desalination that produces clean freshwater from seawater holds the promise of solving the global water shortage for drinking, agriculture and industry. However, conventional desalination technologies such as reverse osmosis and thermal distillation involve large amounts of energy consumption, and the semipermeable membranes widely used in reverse osmosis face the challenge to provide a high throughput at high salt rejection. Here we find by comprehensive molecular dynamics simulations and first principles modeling that pristine graphyne, one of the graphene-like one-atom-thick carbon allotropes, can achieve 100% rejection of nearly all ions in seawater including Na+, Cl-, Mg2+, K+ and Ca2+, at an exceptionally high water permeability about two orders of magnitude higher than those for commercial state-of-the-art reverse osmosis membranes at a salt rejection of ˜98.5%. This complete ion rejection by graphyne, independent of the salt concentration and the operating pressure, is revealed to be originated from the significantly higher energy barriers for ions than for water. This intrinsic specialty of graphyne should provide a new possibility for the efforts to alleviate the global shortage of freshwater and other environmental problems.

  18. Omniphobic Polyvinylidene Fluoride (PVDF) Membrane for Desalination of Shale Gas Produced Water by Membrane Distillation.

    Science.gov (United States)

    Boo, Chanhee; Lee, Jongho; Elimelech, Menachem

    2016-11-15

    Microporous membranes fabricated from hydrophobic polymers such as polyvinylidene fluoride (PVDF) have been widely used for membrane distillation (MD). However, hydrophobic MD membranes are prone to wetting by low surface tension substances, thereby limiting their use in treating challenging industrial wastewaters, such as shale gas produced water. In this study, we present a facile and scalable approach for the fabrication of omniphobic polyvinylidene fluoride (PVDF) membranes that repel both water and oil. Positive surface charge was imparted to an alkaline-treated PVDF membrane by aminosilane functionalization, which enabled irreversible binding of negatively charged silica nanoparticles (SiNPs) to the membrane through electrostatic attraction. The membrane with grafted SiNPs was then coated with fluoroalkylsilane (perfluorodecyltrichlorosilane) to lower the membrane surface energy. Results from contact angle measurements with mineral oil and surfactant solution demonstrated that overlaying SiNPs with ultralow surface energy significantly enhanced the wetting resistance of the membrane against low surface tension liquids. We also evaluated desalination performance of the modified membrane in direct contact membrane distillation with a synthetic wastewater containing surfactant (sodium dodecyl sulfate) and mineral oil, as well as with shale gas produced water. The omniphobic membrane exhibited a stable MD performance, demonstrating its potential application for desalination of challenging industrial wastewaters containing diverse low surface tension contaminants.

  19. Integrating tunable anion exchange with reverse osmosis for enhanced recovery during inland brackish water desalination.

    Science.gov (United States)

    Smith, Ryan C; SenGupta, Arup K

    2015-05-05

    For inland brackish water desalination by reverse osmosis or RO, concentrate or reject disposal poses a major challenge. However, enhanced recovery and consequent reduction in the reject volume using RO processes is limited by the solubility of ions present in the feedwater. One of the most common and stubborn precipitate formed during desalination is calcium sulfate. Reducing or eliminating the presence of sulfate would allow the process to operate at higher recoveries without threat to membrane scaling. In this research, this goal is accomplished by using an appropriate mixture of self-regenerating anion exchange resins that selectively remove and replace sulfate by chloride prior to the RO unit. Most importantly, the mixed bed of anion exchange resins is self-regenerated with the reject brine from the RO process, thus requiring no addition of external chemicals. The current work demonstrates the reversibility of the hybrid ion exchange and RO (HIX-RO) process with 80% recovery for a brackish water composition representative of groundwater in San Joaquin Valley in California containing approximately 5200 mg/L of total dissolved solids or TDS. Consequently, the reject volume can be reduced by 50% without the threat of sulfate scaling and use of antiscaling chemicals can be eliminated altogether. By appropriately designing or tuning the mixed bed of anion exchange resins, the process can be extended to nearly any composition of brackish water for enhanced recovery and consequent reduction in the reject volume.

  20. Application of a Hybrid Uf-Ro Process to Geothermal Water Desalination. Concentrate Disposal and Cost Analysis

    Directory of Open Access Journals (Sweden)

    Tomaszewska Barbara

    2014-12-01

    Full Text Available M embrane-based water desalination processes and hybrid technologies are often considered as a technologically and economically viable alternative for desalination of geothermal waters. This has been confirmed by the results of pilot studies concerning the UF-RO desalination of geothermal waters extracted from various geological structures in Poland. The assessment of the feasibility of implementing the water desalination process analysed on an industrial scale is largely dependent on the method and possibility of disposing or utilising the concentrate. The analyses conducted in this respect have demonstrated that it is possible to use the solution obtained as a balneological product owing to its elevated metasilicic acid, fluorides and iodides ions content. Due to environmental considerations, injecting the concentrate back into the formation is the preferable solution. The energy efficiency and economic analysis conducted demonstrated that the cost effectiveness of implementing the UF-RO process in a geothermal system on an industrial scale largely depends on the factors related to its operation, including without limitation the amount of geothermal water extracted, water salinity, the absorption parameters of the wells used to inject water back into the formation, the scale of problems related to the disposal of cooled water, local demand for drinking and household water, etc. The decrease in the pressure required to inject water into the formation as well as the reduction in the stream of the water injected are among the key cost-effectiveness factors. Ensuring favourable desalinated water sale terms (price/quantity is also a very important consideration owing to the electrical power required to conduct the UF-RO process.

  1. Sea Water Characterization at Ujung Kulon Coastal Depth as Raw Water Source for Desalination and Potential Energy

    Directory of Open Access Journals (Sweden)

    Mugisidi Dan

    2018-01-01

    Full Text Available Fresh water is basic need for life while the source is limited. Therefore, sea water is used as fresh water through desalination process. Sea water has different physical and chemical properties ranging from the surface to the seabed. The energy potential that can be obtained from the hydrostatic pressure also changes according to the depth. As part of the research of the utilization of sea water into fresh water, the aim of this study is to know the characteristics of sea water in the depth that can be utilized as source of fresh water. The sea water samples were taken at 11km from Ujung Kulon beach with depth of 0m, 20m, 40m, 60m, 80m, and 100m under the surface. The results showed that the physical properties at every depth were below the maximum allowable drinking water except for the amount of dissolved solids. Chemical characteristics at any depth above allowable level were fluoride, hardness (CaCo3, chloride, sodium, sulphate, and (KMnO4. In addition to the properties, pressure is one of the considerations in this study to determine the depth of sea water as sources for desalination. Pressure increased by 36.11% as the depth of the sea increased.

  2. Simultaneous water desalination and electricity generation in a microbial desalination cell with electrolyte recirculation for pH control

    KAUST Repository

    Qu, Youpeng

    2012-02-01

    A recirculation microbial desalination cell (rMDC) was designed and operated to allow recirculation of solutions between the anode and cathode chambers. This recirculation avoided pH imbalances that could inhibit bacterial metabolism. The maximum power density was 931±29mW/m 2 with a 50mM phosphate buffer solution (PBS) and 776±30mW/m 2 with 25mM PBS. These power densities were higher than those obtained without recirculation of 698±10mW/m 2 (50mM PBS) and 508±11mW/m 2 (25mM PBS). The salt solution (20g/L NaCl) was reduced in salinity by 34±1% (50mM) and 37±2% (25mM) with recirculation (rMDC), and by 39±1% (50mM) and 25±3% (25mM) without recirculation (MDC). These results show that electrolyte recirculation using an rMDC is an effective method to increase power and achieve efficient desalination by eliminating pH imbalances. © 2011 Elsevier Ltd.

  3. An arduino based control system for a brackish water desalination plant

    Science.gov (United States)

    Caraballo, Ginna

    Water scarcity for agriculture is one of the most important challenges to improve food security worldwide. In this thesis we study the potential to develop a low-cost controller for a small scale brackish desalination plant that consists of proven water treatment technologies, reverse osmosis, cation exchange, and nanofiltration to treat groundwater into two final products: drinking water and irrigation water. The plant is powered by a combination of wind and solar power systems. The low-cost controller uses Arduino Mega, and Arduino DUE, which consist of ATmega2560 and Atmel SAM3X8E ARM Cortex-M3 CPU microcontrollers. These are widely used systems characterized for good performance and low cost. However, Arduino also requires drivers and interfaces to allow the control and monitoring of sensors and actuators. The thesis explains the process, as well as the hardware and software implemented.

  4. Performance Investigation of O-Ring Vacuum Membrane Distillation Module for Water Desalination

    Directory of Open Access Journals (Sweden)

    Adnan Alhathal Alanezi

    2016-01-01

    Full Text Available A new O-ring flat sheet membrane module design was used to investigate the performance of Vacuum Membrane Distillation (VMD for water desalination using two commercial polytetrafluoroethylene (PTFE and polyvinylidene fluoride (PVDF flat sheet hydrophobic membranes. The design of the membrane module proved its applicability for achieving a high heat transfer coefficient of the order of 103 (W/m2 K and a high Reynolds number (Re. VMD experiments were conducted to measure the heat and mass transfer coefficients within the membrane module. The effects of the process parameters, such as the feed temperature, feed flow rate, vacuum degree, and feed concentration, on the permeate flux have been investigated. The feed temperature, feed flow rate, and vacuum degree play an important role in enhancing the performance of the VMD process; therefore, optimizing all of these parameters is the best way to achieve a high permeate flux. The PTFE membrane showed better performance than the PVDF membrane in VMD desalination. The obtained water flux is relatively high compared to that reported in the literature, reaching 43.8 and 52.6 (kg/m2 h for PVDF and PTFE, respectively. The salt rejection of NaCl was higher than 99% for both membranes.

  5. Solar energy water desalination in the United States and Saudi Arabia

    Science.gov (United States)

    Luft, W.; William, J.

    1981-01-01

    Five solar energy water desalination systems were designed to deliver 6000 cubic m/day of desalted water from either seawater or brackish water. Two systems will be selected for pilot plant construction. The pilot plants will have capacities in the range of 100 to 400 m/day. Goals of the Project Agreement for Cooperation in the Field of Solar Energy, under the auspices of the United States-Saudi Arabian Joint Commission on Economic Cooperation, are to: (1) cooperate in the field of solar energy technology for the mutual benefit of the two countries, including the development and stimulation of solar industries within the two countries; (2) advance the development of solar energy technology in the two countries; and (3) facilitate the transfer between the two countries of technology developed under this agreement.

  6. Water Storage Instead of Energy Storage for Desalination Powered by Renewable Energy—King Island Case Study

    Directory of Open Access Journals (Sweden)

    Aya Tafech

    2016-10-01

    Full Text Available In this paper, we scrutinized the energy storage options used in mitigation of the intermittent nature of renewable energy resources for desalination process. In off-grid islands and remote areas, renewable energy is often combined with appropriate energy storage technologies (ESTs to provide a consistent and reliable electric power source. We demonstrated that in developing a renewable energy scheme for desalination purposes, product (water storage is a more reliable and techno-economic solution. For a King Island (Southeast Australia case-study, electric power production from renewable energy sources was sized under transient conditions to meet the dynamic demand of freshwater throughout the year. Among four proposed scenarios, we found the most economic option by sizing a 13 MW solar photovoltaic (PV field to instantly run a proportional RO desalination plant and generate immediate freshwater in diurnal times without the need for energy storage. The excess generated water was stored in 4 × 50 ML (mega liter storage tanks to meet the load in those solar deficit times. It was also demonstrated that integrating well-sized solar PV with wind power production shows more consistent energy/water profiles that harmonize the transient nature of energy sources with the water consumption dynamics, but that would have trivial economic penalties caused by larger desalination and water storage capacities.

  7. The Energy-Water Nexus: An Analysis and Comparison of Various Configurations Integrating Desalination with Renewable Power

    Directory of Open Access Journals (Sweden)

    Gary M. Gold

    2015-04-01

    Full Text Available This investigation studies desalination powered by wind and solar energy, including a study of a configuration using PVT solar panels. First, a water treatment was developed to estimate the power requirement for brackish groundwater reverse-osmosis (BWRO desalination. Next, an energy model was designed to (1 size a wind farm based on this power requirement and (2 size a solar farm to preheat water before reverse osmosis treatment. Finally, an integrated model was developed that combines results from the water treatment and energy models. The integrated model optimizes performances of the proposed facility to maximize daily operational profits. Results indicate that integrated facility can reduce grid-purchased electricity costs by 88% during summer months and 89% during winter when compared to a stand-alone desalination plant. Additionally, the model suggests that the integrated configuration can generate $574 during summer and $252 during winter from sales of wind- and solar-generated electricity to supplement revenue from water production. These results indicate that an integrated facility combining desalination, wind power, and solar power can potentially reduce reliance on grid-purchased electricity and advance the use of renewable power.

  8. Autonomous system without batteries for brackish water desalination; Sistema autonomo sem baterias para dessalinizacao de agua salobra

    Energy Technology Data Exchange (ETDEWEB)

    Andrade, Eduardo Henrique Pereira de; Bezerra, Luiz Daniel Santos; Antunes, Fernando Luiz Marcelo [Universidade Federal do Ceara (PPGEE/UFC), Fortaleza, CE (Brazil). Programa de Pos -Graduacao em Engenharia Eletrica

    2008-07-01

    Ones of the goods most precious of the humanity, in the current times, with certainty is the drinking waters. Each scarcer and basic time for survival. In everybody more than 6,000 children die every day victims of some type of illness provoked for contaminated water (WHO, 2003). The underground water for being free of contamination is a good alternative, however its exploration if it becomes each more expensive time, since the water of better quality, is located in deeper sheets. In the state of the Ceara, techniques to explore water of deep well are each more frequent time, however, present a great inconvenience, most of the excavated wells, present brackish water, improper for the human consumption. In the attempt to make possible these wells the water is treated by desalination process. This article presents the practical implementation of a desalination the reverse Osmosis, Pump high-pressure supplied by solar photovoltaic energy system. (author)

  9. EVALUATION OF A SOLAR DESALINATION SYSTEM, TYPE CYLINDRICAL PARABOLIC CONCENTRATOR FOR SEA WATER

    Directory of Open Access Journals (Sweden)

    Carolina Mercado

    2015-12-01

    Full Text Available In this work, the methodology for the design, construction and commissioning of a solar desalinator, based on a parabolic trough collector and a solar still occurs, is presented. The energy is supplied through the solar collector, which is connected to the distiller. The equipment was set up on the premises of the Universidad Católica del Norte. It is compact, modular, low cost, easy maintenance and long life, with an average production capacity of distilled water of 2.37 l / d, however, it has to be considered that this rate is directly related with weather conditions and sea water flow entering the system, generating an average percentage of 34.04% efficiency. The results obtained with the respective findings, conclusions and recommendations for future projects associated to renewable energy equipment designed analyzed.

  10. Desalination of underground brackish waters using an electrodialysis system powered directly by photovoltaic energy

    Energy Technology Data Exchange (ETDEWEB)

    Ortiz, J.M.; Exposito, E.; Gallud, F.; Garcia-Garcia, V.; Montiel, V.; Aldaz, A. [Grupo de Electroquimica Aplicada y Electrocatalisis, Departamento de Quimica Fisica and Instituto Universitario de Electroquimica, Universidad de Alicante, Ap. 99, 03080 Alicante (Spain)

    2008-12-15

    The aims of this paper are: to demonstrate the feasibility of the desalination of brackish water from aquifers (total dissolved solids=2300-5100 g m{sup -3}) by means of an electrodialysis system powered directly by photovoltaic solar panels, and improve the mathematical model developed in a previous work in order to apply it to real brackish waters. The application of this model allows to predict the behaviour of the electrodialysis-photovoltaic system under different operational and meteorological conditions, and the time required to reach a given final concentration. Finally, the cost of electrodialysis-photovoltaic systems for small applications in isolated locations with lack of electric grid has been estimated. (author)

  11. Graphene-Based Standalone Solar Energy Converter for Water Desalination and Purification.

    Science.gov (United States)

    Yang, Yang; Zhao, Ruiqi; Zhang, Tengfei; Zhao, Kai; Xiao, Peishuang; Ma, Yanfeng; Ajayan, Pulickel M; Shi, Gaoquan; Chen, Yongsheng

    2018-01-23

    Harvesting solar energy for desalination and sewage treatment has been considered as a promising solution to produce clean water. However, state-of-the-art technologies often require optical concentrators and complicated systems with multiple components, leading to poor efficiency and high cost. Here, we demonstrate an extremely simple and standalone solar energy converter consisting of only an as-prepared 3D cross-linked honeycomb graphene foam material without any other supporting components. This simple all-in-one material can act as an ideal solar thermal converter capable of capturing and converting sunlight into heat, which in turn can distill water from various water sources into steam and produce purified water under ambient conditions and low solar flux with very high efficiency. High specific water production rate of 2.6 kg h-1 m-2 g-1 was achieved with near ∼87% under 1 sun intensity and >80% efficiency even under ambient sunlight (<1 sun). This scalable sheet-like material was used to obtain pure drinkable water from both seawater and sewage water under ambient conditions. Our results demonstrate a competent monolithic material platform providing a paradigm change in water purification by using a simple, point of use, reusable, and low-cost solar thermal water purification system for a variety of environmental conditions.

  12. Substituting freshwater: Can ocean desalination and water recycling capacities substitute for groundwater depletion in California?

    Science.gov (United States)

    Badiuzzaman, Pierre; McLaughlin, Eoin; McCauley, Darren

    2017-12-01

    While the sustainability of resource depletion is a longstanding environmental concern, wider attention has recently been given to growing water scarcity and groundwater depletion. This study seeks to test the substitutability assumption embedded in weak sustainability indicators using a case study of Californian water supply. The volume of groundwater depletion is used as a proxy for unsustainable water consumption, and defined by synthesising existing research estimates into low, medium and high depletion baselines. These are compared against projected water supply increases from ocean desalination and water recycling by 2035, to determine whether new, drought-proof water sources can substitute for currently unsustainable groundwater consumption. Results show that the maximum projected supply of new water, 2.47 million acre-feet per year (MAF/yr), is sufficient to meet low depletion estimates of 2.02 MAF/yr, but fails to come near the high depletion estimate of 3.44 MAF/yr. This does not necessarily indicate physical limitations of substitutability, but more so socio-economic limitations influenced by high comparative costs. By including capacities in demand-substitutability via urban water conservation, maximum predicted capacities reach 5.57 MAF/yr, indicating wide room for substitution. Based on these results, investment in social and institutional capital is an important factor to enhance demand-side substitutability of water and other natural resources, which has been somewhat neglected by the literature on the substitutability of natural resources. Copyright © 2017 Elsevier Ltd. All rights reserved.

  13. Data on daily fluoride intake based on drinking water consumption prepared by household desalinators working by reverse osmosis process.

    Science.gov (United States)

    Karbasdehi, Vahid Noroozi; Dobaradaran, Sina; Esmaili, Abdolhamid; Mirahmadi, Roghayeh; Ghasemi, Fatemeh Faraji; Keshtkar, Mozhgan

    2016-09-01

    In this data article, we evaluated the daily fluoride contents in 20 household desalinators working by reverse osmosis (RO) process in Bushehr, Iran. The concentration levels of fluoride in inlet and outlet waters were determined by the standard SPADNS method using a spectrophotometer (M501 Single Beam Scanning UV/VIS, UK). The fluoride content in outlet waters were compared with EPA and WHO guidelines for drinking water.

  14. Data on daily fluoride intake based on drinking water consumption prepared by household desalinators working by reverse osmosis process

    Directory of Open Access Journals (Sweden)

    Vahid Noroozi Karbasdehi

    2016-09-01

    Full Text Available In this data article, we evaluated the daily fluoride contents in 20 household desalinators working by reverse osmosis (RO1 Reverse Osmosis. process in Bushehr, Iran. The concentration levels of fluoride in inlet and outlet waters were determined by the standard SPADNS method using a spectrophotometer (M501 Single Beam Scanning UV/VIS, UK. The fluoride content in outlet waters were compared with EPA and WHO guidelines for drinking water.

  15. Data on daily fluoride intake based on drinking water consumption prepared by household desalinators working by reverse osmosis process

    OpenAIRE

    Karbasdehi, Vahid Noroozi; Dobaradaran, Sina; Esmaili, Abdolhamid; Mirahmadi, Roghayeh; Ghasemi, Fatemeh Faraji; Keshtkar, Mozhgan

    2016-01-01

    In this data article, we evaluated the daily fluoride contents in 20 household desalinators working by reverse osmosis (RO)1 Reverse Osmosis. process in Bushehr, Iran. The concentration levels of fluoride in inlet and outlet waters were determined by the standard SPADNS method using a spectrophotometer (M501 Single Beam Scanning UV/VIS, UK). The fluoride content in outlet waters were compared with EPA and WHO guidelines for drinking water.

  16. Bacterial community structure and variation in a full-scale seawater desalination plant for drinking water production.

    Science.gov (United States)

    Belila, A; El-Chakhtoura, J; Otaibi, N; Muyzer, G; Gonzalez-Gil, G; Saikaly, P E; van Loosdrecht, M C M; Vrouwenvelder, J S

    2016-05-01

    Microbial processes inevitably play a role in membrane-based desalination plants, mainly recognized as membrane biofouling. We assessed the bacterial community structure and diversity during different treatment steps in a full-scale seawater desalination plant producing 40,000 m(3)/d of drinking water. Water samples were taken over the full treatment train consisting of chlorination, spruce media and cartridge filters, de-chlorination, first and second pass reverse osmosis (RO) membranes and final chlorine dosage for drinking water distribution. The water samples were analyzed for water quality parameters (total bacterial cell number, total organic carbon, conductivity, pH, etc.) and microbial community composition by 16S rRNA gene pyrosequencing. The planktonic microbial community was dominated by Proteobacteria (48.6%) followed by Bacteroidetes (15%), Firmicutes (9.3%) and Cyanobacteria (4.9%). During the pretreatment step, the spruce media filter did not impact the bacterial community composition dominated by Proteobacteria. In contrast, the RO and final chlorination treatment steps reduced the Proteobacterial relative abundance in the produced water where Firmicutes constituted the most dominant bacterial group. Shannon and Chao1 diversity indices showed that bacterial species richness and diversity decreased during the seawater desalination process. The two-stage RO filtration strongly reduced the water conductivity (>99%), TOC concentration (98.5%) and total bacterial cell number (>99%), albeit some bacterial DNA was found in the water after RO filtration. About 0.25% of the total bacterial operational taxonomic units (OTUs) were present in all stages of the desalination plant: the seawater, the RO permeates and the chlorinated drinking water, suggesting that these bacterial strains can survive in different environments such as high/low salt concentration and with/without residual disinfectant. These bacterial strains were not caused by contamination during

  17. Bacterial community structure and variation in a full-scale seawater desalination plant for drinking water production

    KAUST Repository

    Belila, Abdelaziz

    2016-02-18

    Microbial processes inevitably play a role in membrane-based desalination plants, mainly recognized as membrane biofouling. We assessed the bacterial community structure and diversity during different treatment steps in a full-scale seawater desalination plant producing 40,000 m3/d of drinking water. Water samples were taken over the full treatment train consisting of chlorination, spruce media and cartridge filters, de-chlorination, first and second pass reverse osmosis (RO) membranes and final chlorine dosage for drinking water distribution. The water samples were analyzed for water quality parameters (total bacterial cell number, total organic carbon, conductivity, pH, etc.) and microbial community composition by 16S rRNA gene pyrosequencing. The planktonic microbial community was dominated by Proteobacteria (48.6%) followed by Bacteroidetes (15%), Firmicutes (9.3%) and Cyanobacteria (4.9%). During the pretreatment step, the spruce media filter did not impact the bacterial community composition dominated by Proteobacteria. In contrast, the RO and final chlorination treatment steps reduced the Proteobacterial relative abundance in the produced water where Firmicutes constituted the most dominant bacterial group. Shannon and Chao1 diversity indices showed that bacterial species richness and diversity decreased during the seawater desalination process. The two-stage RO filtration strongly reduced the water conductivity (>99%), TOC concentration (98.5%) and total bacterial cell number (>99%), albeit some bacterial DNA was found in the water after RO filtration. About 0.25% of the total bacterial operational taxonomic units (OTUs) were present in all stages of the desalination plant: the seawater, the RO permeates and the chlorinated drinking water, suggesting that these bacterial strains can survive in different environments such as high/low salt concentration and with/without residual disinfectant. These bacterial strains were not caused by contamination during

  18. State of the art in the process design of large sea water desalination plants; Estado del arte en el diseno del proceso de plantas desaladoras de agua de mar de gran capacidad

    Energy Technology Data Exchange (ETDEWEB)

    Sanchez Sanchez, J. M.; Sanchez Castillo, N.; Sanchez Castillo, R.

    2008-07-01

    The desalination of seawater is used in commercial operations worldwide in order to obtain large quantities of proper water for population supply, irrigation or industrial uses. The designs of the processes which are involved in desalination are changing all the time. In this paper the evolution of the processes of seawater desalination plants will be discussed. It will focus on large Reverse Osmosis desalination plants: also it will discuss the reasons of this evolution. (Author) 8 refs.

  19. Efficiently Combining Water Reuse and Desalination through Forward Osmosis—Reverse Osmosis (FO-RO Hybrids: A Critical Review

    Directory of Open Access Journals (Sweden)

    Gaetan Blandin

    2016-07-01

    Full Text Available Forward osmosis (FO is a promising membrane technology to combine seawater desalination and water reuse. More specifically, in a FO-reverse osmosis (RO hybrid process, high quality water recovered from the wastewater stream is used to dilute seawater before RO treatment. As such, lower desalination energy needs and/or water augmentation can be obtained while delivering safe water for direct potable reuse thanks to the double dense membrane barrier protection. Typically, FO-RO hybrid can be a credible alternative to new desalination facilities or to implementation of stand-alone water reuse schemes. However, apart from the societal (public perception of water reuse for potable application and water management challenges (proximity of wastewater and desalination plants, FO-RO hybrid has to overcome technical limitation such as low FO permeation flux to become economically attractive. Recent developments (i.e., improved FO membranes, use of pressure assisted osmosis, PAO demonstrated significant improvement in water flux. However, flux improvement is associated with drawbacks, such as increased fouling behaviour, lower rejection of trace organic compounds (TrOCs in PAO operation, and limitation in FO membrane mechanical resistance, which need to be better considered. To support successful implementation of FO-RO hybrid in the industry, further work is required regarding up-scaling to apprehend full-scale challenges in term of mass transfer limitation, pressure drop, fouling and cleaning strategies on a module scale. In addition, refined economics assessment is expected to integrate fouling and other maintenance costs/savings of the FO/PAO-RO hybrid systems, as well as cost savings from any treatment step avoided in the water recycling.

  20. Efficiently Combining Water Reuse and Desalination through Forward Osmosis—Reverse Osmosis (FO-RO) Hybrids: A Critical Review

    Science.gov (United States)

    Blandin, Gaetan; Verliefde, Arne R.D.; Comas, Joaquim; Rodriguez-Roda, Ignasi; Le-Clech, Pierre

    2016-01-01

    Forward osmosis (FO) is a promising membrane technology to combine seawater desalination and water reuse. More specifically, in a FO-reverse osmosis (RO) hybrid process, high quality water recovered from the wastewater stream is used to dilute seawater before RO treatment. As such, lower desalination energy needs and/or water augmentation can be obtained while delivering safe water for direct potable reuse thanks to the double dense membrane barrier protection. Typically, FO-RO hybrid can be a credible alternative to new desalination facilities or to implementation of stand-alone water reuse schemes. However, apart from the societal (public perception of water reuse for potable application) and water management challenges (proximity of wastewater and desalination plants), FO-RO hybrid has to overcome technical limitation such as low FO permeation flux to become economically attractive. Recent developments (i.e., improved FO membranes, use of pressure assisted osmosis, PAO) demonstrated significant improvement in water flux. However, flux improvement is associated with drawbacks, such as increased fouling behaviour, lower rejection of trace organic compounds (TrOCs) in PAO operation, and limitation in FO membrane mechanical resistance, which need to be better considered. To support successful implementation of FO-RO hybrid in the industry, further work is required regarding up-scaling to apprehend full-scale challenges in term of mass transfer limitation, pressure drop, fouling and cleaning strategies on a module scale. In addition, refined economics assessment is expected to integrate fouling and other maintenance costs/savings of the FO/PAO-RO hybrid systems, as well as cost savings from any treatment step avoided in the water recycling. PMID:27376337

  1. Efficiently Combining Water Reuse and Desalination through Forward Osmosis-Reverse Osmosis (FO-RO) Hybrids: A Critical Review.

    Science.gov (United States)

    Blandin, Gaetan; Verliefde, Arne R D; Comas, Joaquim; Rodriguez-Roda, Ignasi; Le-Clech, Pierre

    2016-07-01

    Forward osmosis (FO) is a promising membrane technology to combine seawater desalination and water reuse. More specifically, in a FO-reverse osmosis (RO) hybrid process, high quality water recovered from the wastewater stream is used to dilute seawater before RO treatment. As such, lower desalination energy needs and/or water augmentation can be obtained while delivering safe water for direct potable reuse thanks to the double dense membrane barrier protection. Typically, FO-RO hybrid can be a credible alternative to new desalination facilities or to implementation of stand-alone water reuse schemes. However, apart from the societal (public perception of water reuse for potable application) and water management challenges (proximity of wastewater and desalination plants), FO-RO hybrid has to overcome technical limitation such as low FO permeation flux to become economically attractive. Recent developments (i.e., improved FO membranes, use of pressure assisted osmosis, PAO) demonstrated significant improvement in water flux. However, flux improvement is associated with drawbacks, such as increased fouling behaviour, lower rejection of trace organic compounds (TrOCs) in PAO operation, and limitation in FO membrane mechanical resistance, which need to be better considered. To support successful implementation of FO-RO hybrid in the industry, further work is required regarding up-scaling to apprehend full-scale challenges in term of mass transfer limitation, pressure drop, fouling and cleaning strategies on a module scale. In addition, refined economics assessment is expected to integrate fouling and other maintenance costs/savings of the FO/PAO-RO hybrid systems, as well as cost savings from any treatment step avoided in the water recycling.

  2. Recovery of Fresh Water Resources from Desalination of Brine Produced During Oil and Gas Production Operations

    Energy Technology Data Exchange (ETDEWEB)

    David B. Burnett; Mustafa Siddiqui

    2006-12-29

    for the removal of hydrocarbons from produced water. The results of these experiments show that hydrocarbons from produced water can be reduced from 200 ppm to below 29 ppm level. Experiments were also done to remove the dissolved solids (salts) from the pretreated produced water using desalination membranes. Produced water with up to 45,000 ppm total dissolved solids (TDS) can be treated to agricultural water quality water standards having less than 500 ppm TDS. The Report also discusses the results of field testing of various process trains to measure performance of the desalination process. Economic analysis based on field testing, including capital and operational costs, was done to predict the water treatment costs. Cost of treating produced water containing 15,000 ppm total dissolved solids and 200 ppm hydrocarbons to obtain agricultural water quality with less than 200 ppm TDS and 2 ppm hydrocarbons range between $0.5-1.5 /bbl. The contribution of fresh water resource from produced water will contribute enormously to the sustainable development of the communities where oil and gas is produced and fresh water is a scarce resource. This water can be used for many beneficial purposes such as agriculture, horticulture, rangeland and ecological restorations, and other environmental and industrial application.

  3. Monitoring trihalomethanes and nitrogenous disinfection by-products in blending desalinated waters using solid-phase microextraction and gas chromatography.

    Science.gov (United States)

    González-Hernández, Providencia; Hernández-Padrón, Manuel; Pino, Verónica; Afonso, Ana M; Ayala, Juan H

    2017-04-01

    A simple and efficient method has been developed for the extraction and determination of 16 common volatile halogenated disinfection by-products (DBPs) (four trihalomethanes, six haloacetonitriles, and six halonitromethanes) in blending desalinated waters, using headspace solid-phase microextraction and gas chromatography with flame ionization detector (HS-SPME/GC-FID). After the optimization using factorial designs of the HS-SPME parameters (optimum: carboxen/polydimethylsiloxane such as fiber, extraction time of 60 min at 30°C, pH 7, addition of 40% (w/v) of sodium chloride, and desorption time of 2 min at 250°C), quantification limits ranged from 3.03 to 40.8 µg L(-1), and relative standard deviation (inter-day) were lower than 9.7% for all the target DBPs. Adequate relative recoveries (with the exception of chloronitromethane) were obtained even when spiking waters at low levels (25 µg L(-1)), with values between 83.1% and 119% for ultrapure water, and between 87.4% and 115% for blending desalinated waters, supporting in this way the applicability of the method. The influence of various dechlorinating agents on the stability of 16 DBPs in water was evaluated, with ammonium chloride being the most suitable inhibitor of residual chlorine and carrying out the analytical determination of DBPs within 48 h after sampling. Different blending desalinated water samples collected in the South of Tenerife Island (Spain) were successfully analyzed.

  4. Massive arrival of desalinated seawater in a regional urban water cycle: A multi-isotope study (B, S, O, H).

    Science.gov (United States)

    Kloppmann, W; Negev, Ido; Guttman, Joseph; Goren, Orly; Gavrieli, Ittai; Guerrot, Catherine; Flehoc, Christine; Pettenati, Marie; Burg, Avihu

    2018-04-01

    "Man-made" or unconventional freshwater, like desalinated seawater or reclaimed effluents, is increasingly introduced into regional water cycles in arid or semi-arid countries. We show that the breakthrough of reverse osmosis-derived freshwater in the largely engineered water cycle of the greater Tel Aviv region (Dan Region) has profoundly changed previous isotope fingerprints. This new component can be traced throughout the system, from the drinking water supply, through sewage, treated effluents, and artificially recharged groundwater at the largest Soil-Aquifer Treatment system in the Middle East (Shafdan) collecting all the Dan region sewage. The arrival of the new water type (desalinated seawater) in 2007 and its predominance since 2010 constitutes an unplanned, large-scale, long-term tracer test and the monitoring of the breakthrough of desalination-specific fingerprints in the aquifer system of Shafdan allowed to get new insights on the water and solute flow and behavior in engineered groundwater systems. Our approach provides an investigation tool for the urban water cycle, allowing estimating the contribution of diverse freshwater sources, and an environmental tracing method for better constraining the long-term behavior and confinement of aquifer systems with managed recharge. Copyright © 2017. Published by Elsevier B.V.

  5. Desalination of Kashan City’s Water Using PEBA-Based Nanocomposite Membranes via Pervaporation

    Directory of Open Access Journals (Sweden)

    Soheill Azadikhah Marian

    2017-04-01

    Full Text Available In this work, performance of composite membranes was investigated for desalination of Kashan city’s water via pervaporation process. PEBA/PAN/PE, PEBA/PSF/PE and PEBA+NaX/PSF/PE composite membranes that used, was synthesized via a phase inversion route. For all experiments under 45◦C, salt rejection was too high and equals to 99.9% that this quantity dropped by increasing the temperature that cause membrane swelling in high temperatures. Water contact angle and water take-up were measured to evaluate the hydrophilicity of the membrane. Also the effect of operating conditions including feed temperature and permeate pressure on permeability and selectivity is discussed. A permeate flux of 4.93 kg/m2h with salt rejection of 99.9% could be achieved at a feed temperature of 50 °C and a vacuum of 0.04 bar. Apparent diffusion coefficients of water at various permeate pressure and feed temperature are calculated. The most effective parameter was feed temperature.

  6. Aquifer Treatment of Sea Water to Remove Natural Organic Matter Before Desalination

    KAUST Repository

    Dehwah, Abdullah

    2016-10-18

    An investigation of a sea water reverse osmosis desalination facility located in western Saudi Arabia has shown that aquifer treatment of the raw sea water provides a high degree of removal of natural organic matter (NOM) that causes membrane biofouling. The aquifer is a carbonate system that has a good hydraulic connection to the sea and 14 wells are used to induce sea water movement 400 to 450 m from the sea to the wells. During aquifer transport virtually all of the algae, over 90% of the bacteria, over 90% of the biopolymer fraction of NOM, and high percentages of the humic substance, building blocks, and some of the low molecular weight fractions of NOM are removed. Between 44 and over 90% of the transparent exopolymer particles (TEP) are removed with a corresponding significant reduction in concentration of the colloidal fraction of TEP. The removal rate for TEP appears to be greater in carbonate aquifers compared to siliciclastic systems. Although the production wells range in age from 4 months to 14 years, no significant difference in the degree of water treatment provided by the aquifer was found.

  7. Microfluidic desalination techniques and their potential applications.

    Science.gov (United States)

    Roelofs, S H; van den Berg, A; Odijk, M

    2015-09-07

    In this review we discuss recent developments in the emerging research field of miniaturized desalination. Traditionally desalination is performed to convert salt water into potable water and research is focused on improving performance of large-scale desalination plants. Microfluidic desalination offers several new opportunities in comparison to macro-scale desalination, such as providing a platform to increase fundamental knowledge of ion transport on the nano- and microfluidic scale and new microfluidic sample preparation methods. This approach has also lead to the development of new desalination techniques, based on micro/nanofluidic ion-transport phenomena, which are potential candidates for up-scaling to (portable) drinking water devices. This review assesses microfluidic desalination techniques on their applications and is meant to contribute to further implementation of microfluidic desalination techniques in the lab-on-chip community.

  8. Development of Ultrafiltration Membrane-Separation Technology for Energy-Efficient Water Treatment and Desalination Process

    Energy Technology Data Exchange (ETDEWEB)

    Yim, Woosoon [Univ. of Nevada, Las Vegas, NV (United States); Bae, Chulsung [Rensselaer Polytechnic Inst., Troy, NY (United States)

    2016-10-28

    The growing scarcity of fresh water is a major political and economic challenge in the 21st century. Compared to thermal-based distillation technique of water production, pressure driven membrane-based water purification process, such as ultrafiltration (UF), nanofiltration (NF) and reverse osmosis (RO), can offer more energy-efficient and environmentally friendly solution to clean water production. Potential applications also include removal of hazardous chemicals (i.e., arsenic, pesticides, organics) from water. Although those membrane-separation technologies have been used to produce drinking water from seawater (desalination) and non-traditional water (i.e., municipal wastewater and brackish groundwater) over the last decades, they still have problems in order to be applied in large-scale operations. Currently, a major huddle of membrane-based water purification technology for large-scale commercialization is membrane fouling and its resulting increases in pressure and energy cost of filtration process. Membrane cleaning methods, which can restore the membrane properties to some degree, usually cause irreversible damage to the membranes. Considering that electricity for creating of pressure constitutes a majority of cost (~50%) in membrane-based water purification process, the development of new nano-porous membranes that are more resistant to degradation and less subject to fouling is highly desired. Styrene-ethylene/butylene-styrene (SEBS) block copolymer is one of the best known block copolymers that induces well defined morphologies. Due to the polarity difference of aromatic styrene unit and saturated ethylene/butylene unit, these two polymer chains self-assemble each other and form different phase-separated morphologies depending on the ratios of two polymer chain lengths. Because the surface of SEBS is hydrophobic which easily causes fouling of membrane, incorporation of ionic group (e,g, sulfonate) to the polymer is necessary to reduces fouling

  9. Preparation and water desalination properties of POSS-polyamide nanocomposite reverse osmosis membranes

    KAUST Repository

    Duan, Jintang

    2015-01-01

    The application of nanotechnology to thin-film nanocomposites (TFN) is a new route to enhance membrane performance in water desalination. Here, the potential of polyhedral oligomeric silsesquioxane (POSS) as the nanofiller in polyamide (PA) reverse osmosis membranes was systematically investigated. Four POSS materials (P-8Phenyl, P-8NH3Cl, P-8NH2 and P-1NH2) were introduced into the selective layer by physical blending or chemical fixation during standard interfacial polymerization. Water flux and NaCl rejection were measured with 2000ppm NaCl solution under 15.5bar pressure, and SEM and TEM images of membrane selective layers were obtained. Membranes prepared without POSS showed water flux of 20.0±0.5L/m2·h and salt rejection of 98.0±0.2%. TFN membranes prepared with 0.4% (w/v) P-8Phenyl in the organic phase showed a 65% increase in water flux compared to the pristine PA membrane while maintaining high salt rejection. The selective layer of this membrane maintained the typical ridge-and-valley structure of aromatic PA. Results with P-8NH3Cl and P-8NH2 added to the organic phase were similar. TFN membranes prepared with monoamine P-1NH2 in the organic phase had poor water flux of 3.2L/m2·h, a smooth and more hydrophobic surface, and a much thicker (~400nm) selective layer. One of the four POSS compounds studied, P-8NH3Cl, is sufficiently soluble in water for incorporation into the selective layer via the aqueous phase. Membranes were prepared with P-8NH3Cl in the aqueous phase at varying reaction time, loading, and additive (triethylamine) concentration. With these parameters optimized, water flux increased to 35.4L/m2·h.

  10. Subsurface intake systems: Green choice for improving feed water quality at SWRO desalination plants, Jeddah, Saudi Arabia.

    Science.gov (United States)

    Dehwah, Abdullah H A; Missimer, Thomas M

    2016-01-01

    An investigation of three seawater reverse osmosis facilities located along the shoreline of the Red Sea of Saudi Arabia that use well intake systems showed that the pumping-induced flow of raw seawater through a coastal aquifer significantly improves feed water quality. A comparison between the surface seawater and the discharge from the wells shows that turbidity, algae, bacteria, total organic carbon, most fractions of natural organic matter (NOM), and particulate and colloidal transparent exopolymer particles (TEP) have significant reductions in concentration. Nearly all of the algae, up to 99% of the bacteria, between 84 and 100% of the biopolymer fraction of NOM, and a high percentage of the TEP were removed during transport. The data suggest that the flowpath length and hydraulic retention time in the aquifer play the most important roles in removal of the organic matter. Since the collective concentrations of bacteria, biopolymers, and TEP in the intake seawater play important roles in the biofouling of SWRO membranes, the observed reductions suggest that the desalination facilities that use well intakes systems will have a potentially lower fouling rate compared to open-ocean intake systems. Furthermore, well intake system intakes also reduce the need for chemical usage during complex pretreatment systems required for operation of SWRO facilities using open-ocean intakes and reduce environmental impacts. Copyright © 2015 Elsevier Ltd. All rights reserved.

  11. Subsurface intake systems: Green choice for improving feed water quality at SWRO desalination plants, Jeddah, Saudi Arabia

    KAUST Repository

    Dehwah, Abdullah

    2015-10-25

    An investigation of three seawater reverse osmosis facilities located along the shoreline of the Red Sea of Saudi Arabia that use well intake systems showed that the pumping-induced flow of raw seawater through a coastal aquifer significantly improves feed water quality. A comparison between the surface seawater and the discharge from the wells shows that turbidity, algae, bacteria, total organic carbon, most fractions of natural organic matter (NOM), and particulate and colloidal transparent exopolymer particles (TEP) have significant reductions in concentration. Nearly all of the algae, up to 99% of the bacteria, between 84 and 100% of the biopolymer fraction of NOM, and a high percentage of the TEP were removed during transport. The data suggest that the flowpath length and hydraulic retention time in the aquifer play the most important roles in removal of the organic matter. Since the collective concentrations of bacteria, biopolymers, and TEP in the intake seawater play important roles in the biofouling of SWRO membranes, the observed reductions suggest that the desalination facilities that use well intakes systems will have a potentially lower fouling rate compared to open-ocean intake systems. Furthermore, well intake system intakes also reduce the need for chemical usage during complex pretreatment systems required for operation of SWRO facilities using open-ocean intakes and reduce environmental impacts.

  12. Flexible 3D Nanoporous Graphene for Desalination and Bio-decontamination of Brackish Water via Asymmetric Capacitive Deionization.

    Science.gov (United States)

    El-Deen, Ahmed G; Boom, Remko M; Kim, Hak Yong; Duan, Hongwei; Chan-Park, Mary B; Choi, Jae-Hwan

    2016-09-28

    Nanoporous graphene based materials are a promising nanostructured carbon for energy storage and electrosorption applications. We present a novel and facile strategy for fabrication of asymmetrically functionalized microporous activated graphene electrodes for high performance capacitive desalination and disinfection of brackish water. Briefly, thiocarbohydrazide coated silica nanoparticles intercalated graphene sheets are used as a sacrificial material for creating mesoporous graphene followed by alkaline activation process. This fabrication procedure meets the ideal desalination pore diameter with ultrahigh specific surface area ∼ 2680 m(2) g(-1) of activated 3D graphene based micropores. The obtained activated graphene electrode is modified by carboxymethyl cellulose as negative charge (COO(-2)) and disinfectant quaternary ammonium cellulose with positively charged polyatomic ions of the structure (NR4(+)). Our novel asymmetric coated microporous activated 3D graphene employs nontoxic water-soluble binder which increases the surface wettability and decreases the interfacial resistance and moreover improves the electrode flexibility compared with organic binders. The desalination performance of the fabricated electrodes was evaluated by carrying out single pass mode experiment under various cell potentials with symmetric and asymmetric cells. The asymmetric charge coated microporous activated graphene exhibits exceptional electrosorption capacity of 18.43 mg g(-1) at a flow rate of 20 mL min(-1) upon applied cell potential of 1.4 V with initial NaCl concentration of 300 mg L(-1), high charge efficiency, excellent recyclability, and, moreover, good antibacterial behavior. The present strategy provides a new avenue for producing ultrapure water via green capacitive deionization technology.

  13. Desalination of water by vapor-phase transport through hydrophobic nanopores

    Science.gov (United States)

    Lee, Jongho; Karnik, Rohit

    2010-08-01

    We propose a new approach to desalination of water whereby a pressure difference across a vapor-trapping nanopore induces selective transport of water by isothermal evaporation and condensation across the pore. Transport of water through a nanopore with saline water on one side and pure water on the other side under a pressure difference was theoretically analyzed under the rarefied gas assumption using a probabilistic framework that accounts for diffuse scattering from the pore walls as well as reflection from the menisci. The analysis revealed that in addition to salinity, temperature, and pressure difference, the nanopore aspect ratio and the probability of condensation of a water molecule incident on a meniscus from the vapor phase, known as the condensation coefficient, are key determinants of flux. The effect of condensation coefficient on mass flux becomes critical when the aspect ratio is small. However, the mass flux becomes independent of the condensation coefficient as the pore aspect ratio increases, converging to the Knudsen flux for long nanopores. For design of a nanopore membrane that can trap vapor, a minimum aspect ratio is derived for which coalescence of the two interfaces on either side of the nanopore remains energetically unfavorable. Based on this design criterion, the analysis suggests that mass flux in the range of 20-70 g/m2 s may be feasible if the system is operated at temperatures in the range of 30-50 °C. The proposed approach further decouples transport properties from material properties of the membrane, which opens the possibility of engineering membranes with appropriate materials that may lead to reverse osmosis membranes with improved flux, better selectivity, and high chlorine resistance.

  14. Atom Resolved Electron Microscpe Images of Polyvinylidene Fluoride Nanofibers for Water Desalination

    Science.gov (United States)

    Liu, Suqi; Reneker, Darrell

    Ultra-thin nanofibers of polyvinylidene fluoride (PVDF), observed with an aberration corrected transmission electron microscope, in a through focus series of 50 images, revealed three-dimensional positions and motions of some molecular segments. The x,y positions of fluorine atoms in the PVDF segments were observed at high resolution as described in (DOI: 10.1039/c5nr01619c). The methods described in (DOI:10.1038/nature11074) were used to measure the positions of fluorine atoms along the observation direction of the microscope. PVDF is widely used to separate salt ions from water in reverse osmosis systems. The observed separation depends on the atomic scale positions and motions of segments of the PVDF molecules. Conformational changes and the associated changes in the directions of the dipole moments of PVDF segments distinguish the diffusion of dipolar water molecules from diffusion of salt ions to accomplish desalination. Authors thank Coalescence Filtration Nanofibers Consortium at The University of Akron for support.

  15. An investigation of desalination by nanofiltration, reverse osmosis and integrated (hybrid NF/RO) membranes employed in brackish water treatment.

    Science.gov (United States)

    Talaeipour, M; Nouri, J; Hassani, A H; Mahvi, A H

    2017-01-01

    As an appropriate tool, membrane process is used for desalination of brackish water, in the production of drinking water. The present study aims to investigate desalination processes of brackish water of Qom Province in Iran. This study was carried out at the central laboratory of Water and Wastewater Company of the studied area. To this aim, membrane processes, including nanofiltration (NF) and reverse osmosis (RO), separately and also their hybrid process were applied. Moreover, water physical and chemical parameters, including salinity, total dissolved solids (TDS), electric conductivity (EC), Na+1 and Cl-1 were also measured. Afterward, the rejection percent of each parameter was investigated and compared using nanofiltration and reverse osmosis separately and also by their hybrid process. The treatment process was performed by Luna domestic desalination device, which its membrane was replaced by two NF90 and TW30 membranes for nanofiltration and reverse osmosis processes, respectively. All collected brackish water samples were fed through membranes NF90-2540, TW30-1821-100(RO) and Hybrid (NF/RO) which were installed on desalination household scale pilot (Luna water 100GPD). Then, to study the effects of pressure on permeable quality of membranes, the simulation software model ROSA was applied. Results showed that percent of the salinity rejection was recorded as 50.21%; 72.82 and 78.56% in NF, RO and hybrid processes, respectively. During the study, in order to simulate the performance of nanofiltartion, reverse osmosis and hybrid by pressure drive, reverse osmosis system analysis (ROSA) model was applied. The experiments were conducted at performance three methods of desalination to remove physic-chemical parameters as percentage of rejections in the pilot plant are: in the NF system the salinity 50.21, TDS 43.41, EC 43.62, Cl 21.1, Na 36.15, and in the RO membrane the salinity 72.02, TDS 60.26, EC 60.33, Cl 43.08, Na 54.41. Also in case of the rejection in

  16. The Energy-Water Nexus: Spatially-Resolved Analysis of the Potential for Desalinating Brackish Groundwater by Use of Solar Energy

    Directory of Open Access Journals (Sweden)

    Jill B. Kjellsson

    2015-06-01

    Full Text Available This research looks at coupling desalination with renewable energy sources to create a high-value product (treated water from two low value resources (brackish groundwater and intermittent solar energy. Desalination of brackish groundwater is already being considered as a potential new water supply in Texas. This research uses Texas as a testbed for spatially-resolved analysis techniques while considering depth to brackish groundwater, water quality, and solar radiation across Texas to determine the locations with the best potential for integrating solar energy with brackish groundwater desalination. The framework presented herein can be useful for policymakers, regional planners, and project developers as they consider where to site desalination facilities coupled with solar photovoltaics. Results suggest that the northwestern region of Texas—with abundant sunshine and groundwater at relatively shallow depths and low salinity in areas with freshwater scarcity—has the highest potential for solar powered desalination. The range in capacity for solar photovoltaic powered reverse osmosis desalination was found to be 1.56 × 10—6 to 2.93 × 10—5 cubic meters of water per second per square meter of solar panel (m3/s/m2.

  17. Osmotically-assisted desalination method and system

    Science.gov (United States)

    Achilli, Andrea; Childress, Amy E.; Cath, Tzahi Y.

    2014-08-12

    Systems and methods for osmotically assisted desalination include using a pressurized concentrate from a pressure desalination process to pressurize a feed to the desalination process. The depressurized concentrate thereby produced is used as a draw solution for a pressure-retarded osmosis process. The pressure-retarded osmosis unit produces a pressurized draw solution stream that is used to pressurize another feed to the desalination process. In one example, the feed to the pressure-retarded osmosis process is impaired water.

  18. The nuclear energy in the seawater desalination; La energia nuclear en la desalacion de agua de mar

    Energy Technology Data Exchange (ETDEWEB)

    Moreno A, J.; Flores E, R.M. [ININ, 52045 Ocoyoacac, Estado de Mexico (Mexico)

    2004-07-01

    In general, the hydric resources of diverse regions of the world are insufficient for to satisfy the necessities of their inhabitants. Among the different technologies that are applied for the desalination of seawater are the distillation processes, the use of membranes and in particular recently in development the use of the nuclear energy (Nuclear Desalination; System to produce drinkable water starting from seawater in a complex integrated in that as much the nuclear reactor as the desalination system are in a common location, the facilities and pertinent services are shared, and the nuclear reactor produces the energy that is used for the desalination process). (Author)

  19. Review: Water recovery from brines and salt-saturated solutions: operability and thermodynamic efficiency considerations for desalination technologies.

    Science.gov (United States)

    Vane, Leland M

    2017-03-08

    When water is recovered from a saline source, a brine concentrate stream is produced. Management of the brine stream can be problematic, particularly in inland regions. An alternative to brine disposal is recovery of water and possibly salts from the concentrate. This review provides an overview of desalination technologies and discusses the thermodynamic efficiencies and operational issues associated with the various technologies particularly with regard to high salinity streams. Due to the high osmotic pressures of the brine concentrates, reverse osmosis, the most common desalination technology, is impractical. Mechanical vapor compression which, like reverse osmosis, utilizes mechanical work to operate, is reported to have the highest thermodynamic efficiency of the desalination technologies for treatment of salt-saturated brines. Thermally-driven processes, such as flash evaporation and distillation, are technically able to process saturated salt solutions, but suffer from low thermodynamic efficiencies. This inefficiency could be offset if an inexpensive source of waste or renewable heat could be used. Overarching issues posed by high salinity solutions include corrosion and the formation of scales/precipitates. These issues limit the materials, conditions, and unit operation designs that can be used.

  20. Continuous capacitive deionization-electrodialysis reversal through electrostatic shielding for desalination and deionization of water

    Energy Technology Data Exchange (ETDEWEB)

    Dermentzis, Konstantinos [Technological Education Institute, T.E.I. of Kavala, School of Technological Applications, Department of Science, Laboratory of Chemical Technology and Electrochemistry, Agios Loucas, 65404 Kavala (Greece); Ouzounis, Konstantinos [Democritus University of Thrace, School of Engineering, Department of Environmental Engineering, Laboratory of Environmental Chemistry, 67100 Xanthi (Greece)

    2008-10-15

    We report a new concept for capacitive deionization with simple and cheap porous bipolar intermediate graphite electrodes which is operated continuously by constant or alternating polarity without any down time for electrode saturation, regeneration and rinsing steps and certainly without any permselective ion exchange membranes. The proposed process utilizes the advantages of the classical electrodeionization technologies combining them all to a unified continuous capacitive deionization-continuous electrodeionization-electrodialysis-electrodialysis reversal process. Separate and unchanged diluate and concentrate compartments are created in two modes, first by periodical charging/discharging the bipolar intermediate electrodes through a pulsating electric field and second by simultaneous charging/discharging them through a constant or pulsating electric field and electrostatic shielding. Because of coion permeation and the convenience of alternating the polarity without any negative impact on the deionization process, the new technique is less affected by the known membrane associated limitation, such as concentration polarization, limiting current density or scaling. The new electrochemical deionization technique is suitable for regeneration of ion exchange resins and production of high purity deionized water, removal of heavy metal ions from industrial effluents and desalination of brackish or seawater. (author)

  1. The Dynamic Characteristic Analysis of the Water Lubricated Bearing-Rotor System in Seawater Desalination Pump

    Directory of Open Access Journals (Sweden)

    Xiaoyan Ye

    2014-05-01

    Full Text Available In order to study the water lubricated bearing-rotor system in seawater desalination pump, this paper is based on the coupling between the lubricating flow field and the rotor dynamics. The fluid-solid interaction (FSI method, Rigid Body, was adopted to study the journal orbit of the bearing-rotor system under the periodic unbalancing load. The influences of geometric and working parameter to the journal orbit were combined to analyze the stability and reliability of the bearing-rotor system. The result shows that increasing the rotating speed would increase the journal whirling amplitude and the system sensitivity to the external excitation and unbalancing load were promoted; increasing the aspect ratio would reduce the journal whirling amplitude and cause the system to be more unstable; increasing the inlet pressure would reduce the journal whirling amplitude and cause the system to be more unstable; increasing the unbalancing load would reduce the stability margin and the system is easy to be unstable if obstructed; increasing the radial clearance would reduce the journal whirling amplitude and cause the system to be more unstable. The attitude angle has no influence on the journal whirling amplitude but would influence the stability of system and the value of attitude angle should not be large.

  2. Efficient Desalination of Brackish Ground Water via a Novel Capacitive Deionization Cell Using Nanoporous Activated Carbon Cloth Electrodes

    Directory of Open Access Journals (Sweden)

    K. Laxman

    2015-12-01

    Full Text Available Sea water intrusion in ground water sources has made brackish water desalination a necessity in Oman. The application of capacitive deionization (CDI for the deionization of ground water samples from wells in Al-Musanaah Wilayat is proposed and demonstrated. A CDI cell is fabricated using nanoporous activated carbon cloth (ACC as the electrodes and is shown to be power efficient for desalting ground water samples with total dissolved solids (TDS of up to 4,000 mg/l. The CDI cell was able to remove up to 73% of the ionic scaling and fouling contaminants from brackish water samples. The power consumption for deionization of brackish water was estimated to be 1 kWh/m3 of desalinated water, which is much lower than the power required to process water with equivalent TDS by the reverse osmosis processes. The CDI process is elaborated, and observations and analysis of the ion adsorption characteristics and electrical properties of the capacitive cell are elucidated.

  3. Effects of high salinity from desalination brine on growth, photosynthesis, water relations and osmolyte concentrations of seagrass Posidonia australis.

    Science.gov (United States)

    Cambridge, M L; Zavala-Perez, A; Cawthray, G R; Mondon, J; Kendrick, G A

    2017-02-15

    Highly saline brines from desalination plants expose seagrass communities to salt stress. We examined effects of raised salinity (46 and 54psu) compared with seawater controls (37psu) over 6weeks on the seagrass, Posidonia australis, growing in tanks with the aim of separating effects of salinity from other potentially deleterious components of brine and determining appropriate bioindicators. Plants survived exposures of 2-4weeks at 54psu, the maximum salinity of brine released from a nearby desalination plant. Salinity significantly reduced maximum quantum yield of PSII (chlorophyll a fluorescence emissions). Leaf water potential (Ψw) and osmotic potential (Ψπ) were more negative at increased salinity, while turgor pressure (Ψp) was unaffected. Leaf concentrations of K+ and Ca2+ decreased, whereas concentrations of sugars (mainly sucrose) and amino acids increased. We recommend leaf osmolarity, ion, sugar and amino acid concentrations as bioindicators for salinity effects, associated with brine released in desalination plant outfalls. Copyright © 2016 Elsevier Ltd. All rights reserved.

  4. A computational assessment of the permeability and salt rejection of carbon nanotube membranes and their application to water desalination.

    Science.gov (United States)

    Thomas, Michael; Corry, Ben

    2016-02-13

    Membranes made from nanomaterials such as nanotubes and graphene have been suggested to have a range of applications in water filtration and desalination, but determining their suitability for these purposes requires an accurate assessment of the properties of these novel materials. In this study, we use molecular dynamics simulations to determine the permeability and salt rejection capabilities for membranes incorporating carbon nanotubes (CNTs) at a range of pore sizes, pressures and concentrations. We include the influence of osmotic gradients and concentration build up and simulate at realistic pressures to improve the reliability of estimated membrane transport properties. We find that salt rejection is highly dependent on the applied hydrostatic pressure, meaning high rejection can be achieved with wider tubes than previously thought; while membrane permeability depends on salt concentration. The ideal size of the CNTs for desalination applications yielding high permeability and high salt rejection is found to be around 1.1 nm diameter. While there are limited energy gains to be achieved in using ultra-permeable CNT membranes in desalination by reverse osmosis, such membranes may allow for smaller plants to be built as is required when size or weight must be minimized. There are diminishing returns in further increasing membrane permeability, so efforts should focus on the fabrication of membranes containing narrow or functionalized CNTs that yield the desired rejection or selection properties rather than trying to optimize pore densities. © 2015 The Authors.

  5. Photosynthetic microbial desalination cells (PMDCs) for clean energy, water and biomass production.

    Science.gov (United States)

    Kokabian, Bahareh; Gude, Veera Gnaneswar

    2013-12-01

    Current microbial desalination cell (MDC) performances are evaluated with chemical catalysts such as ferricyanide, platinum catalyzed air-cathodes or aerated cathodes. All of these methods improve power generation potential in MDCs, however, they are not preferable for large scale applications due to cost, energy and environmental toxicity issues. In this study, performance of microbial desalination cells with an air cathode and an algae biocathode (Photosynthetic MDC - PMDC) were evaluated, both under passive conditions (no mechanical aeration or mixing). The results indicate that passive algae biocathodes perform better than air cathodes and enhance COD removal and utilize treated wastewater as the growth medium to obtain valuable biomass for high value bioproducts. Maximum power densities of 84 mW m(-3) (anode volume) or 151 mW m(-3) (biocathode volume) and a desalination rate of 40% were measured with 0.9 : 1 : 0.5 volumetric ratios of anode, desalination and algae biocathode chambers respectively. This first proof-of-concept study proves that the passive mechanisms can be beneficial in enhancing the sustainability of microbial desalination cells.

  6. Identifying Economies of Size in Conventional Surface Water Treatment and Brackish-Groundwater Desalination: Case Study in the Rio Grande Valley of Texas

    OpenAIRE

    Boyer, Christopher N.; Rister, M. Edward; Sturdivant, Allen W.; Lacewell, Ronald D.; Harris, Bill L.

    2008-01-01

    Two primary potable water-treatment technologies used in South Texas include conventional surface-water and reverse-osmosis (RO) desalination of brackish-groundwater. As the region's population continues to grow, municipalities are searching for economical means to expand their water supplies. Economies of size for both technologies are an important consideration for future expansion decisions.

  7. ENERGY EFFICIENT DESALINATOR

    Directory of Open Access Journals (Sweden)

    T. A. Ismailov

    2017-01-01

    Full Text Available Objectives. The aim of the research is to develop a thin-film semiconductor thermoelectric heat pump of cylindrical shape for the desalination of sea water.Methods. To improve the efficiency of the desalination device, a  special thin-film semiconductor thermoelectric heat pump of  cylindrical shape is developed. The construction of the thin-film  semiconductor thermoelectric heat pump allows the flow rates of  incoming sea water and outflowing fresh water and brine to be  equalised by changing the geometric dimensions of the desalinator.  The cross-sectional area of the pipeline for incoming sea water is equal to the total area of outflowing fresh water and brine.Results. The use of thin-film semiconductor p- and n-type branches  in a thermo-module reduces their electrical resistance virtually to  zero and completely eliminates Joule's parasitic heat release. The  Peltier thermoelectric effect on heating and cooling is completely  preserved, bringing the efficiency of the heat pump to almost 100%, improving the energy-saving characteristics of the  desalinator as a whole. To further increase the efficiency of the  proposed desalinator, thermoelectric modules with radiation can be  used as thermoelectric devices.Conclusion. As a consequence of the creation of conditions of high rarefaction under which water will be converted to steam, which, at  20° C, is cold (as is the condensed distilled water, energy costs can  be reduced. In this case, the energy for heating and cooling is not  wasted; moreover, sterilisation is also achieved using the ultraviolet  radiation used in the thermoelectric devices, which, on the one hand, generate electromagnetic ultraviolet radiation, and, on the other, cooling. Such devices operate in optimal mode without heat  release. The desalination device can be used to produce fresh water and concentrated solutions from any aqueous solutions, including wastewater from industrial

  8. Supercritical water desalination (SCWD) : process development, design and pilot plant validation

    NARCIS (Netherlands)

    Odu, Samuel Obarinu

    2017-01-01

    Conventional desalination technologies such as reverse osmosis (RO), multi-stage flash distillation (MSF) and electro dialysis (ED) have a major drawback; the production of a liquid waste stream with an increased salinity (compared to the feed) that has to be disposed of. The treatment of this waste

  9. Fundamental measure theory for the electric double layer: implications for blue-energy harvesting and water desalination.

    Science.gov (United States)

    Härtel, Andreas; Janssen, Mathijs; Samin, Sela; van Roij, René

    2015-05-20

    Capacitive mixing (CAPMIX) and capacitive deionization (CDI) are promising candidates for harvesting clean, renewable energy and for the energy efficient production of potable water, respectively. Both CAPMIX and CDI involve water-immersed porous carbon (supercapacitors) electrodes at voltages of the order of hundreds of millivolts, such that counter-ionic packing is important for the electric double layer (EDL) which forms near the surfaces of these porous materials. Thus, we propose a density functional theory (DFT) to model the EDL, where the White-Bear mark II fundamental measure theory functional is combined with a mean-field Coulombic and a mean spherical approximation-type correction to describe the interplay between dense packing and electrostatics, in good agreement with molecular dynamics simulations. We discuss the concentration-dependent potential rise due to changes in the chemical potential in capacitors in the context of an over-ideal theoretical description and its impact on energy harvesting and water desalination. Compared to less elaborate mean-field models our DFT calculations reveal a higher work output for blue-energy cycles and a higher energy demand for desalination cycles.

  10. The potential of solar-driven humidification-dehumidification desalination for small-scale decentralized water production

    Energy Technology Data Exchange (ETDEWEB)

    Narayan, G. Prakash; Sharqawy, Mostafa H.; Summers, Edward K.; Lienhard, John H. [Department of Mechanical Engineering, Massachusetts Institute of Technology, Cambridge (United States); Zubair, Syed M.; Antar, M.A. [Department of Mechanical Engineering, King Fahd University of Petroleum and Minerals (Saudi Arabia)

    2010-05-15

    World-wide water scarcity, especially in the developing world, indicates a pressing need to develop inexpensive, decentralized small-scale desalination technologies which use renewable resources of energy. This paper provides a comprehensive review of the state-of-the-art in one of the most promising of these technologies, solar-driven humidification-dehumidification (HDH) desalination. Previous studies have investigated many different variations on the HDH cycle. In this paper, performance parameters which enable comparison of the various versions of the HDH cycle have been defined and evaluated. To better compare these cycles, each has been represented in psychometric coordinates. The principal components of the HDH system are also reviewed and compared, including the humidifier, solar heaters, and dehumidifiers. Particular attention is given to solar air heaters, for which design data is limited; and direct air heating is compared to direct water heating in the cycle assessments. Alternative processes based on the HDH concept are also reviewed and compared. Further, novel proposals for improvement of the HDH cycle are outlined. It is concluded that HDH technology has great promise for decentralized small-scale water production applications, although additional research and development is needed for improving system efficiency and reducing capital cost. (author)

  11. Needs and processes for the sea water desalination; Besoins et Procedes pour le dessalement de l'eau de mer

    Energy Technology Data Exchange (ETDEWEB)

    Livet, F. [Institut National Polytechnique (INPG-UJF), SIMaP, UMR CNRS 5266, 38 - Grenoble (France)

    2007-11-15

    The author shows the needs of the sea water desalination for the dry countries. The main technique is the reverse osmosis. It requires electricity and its development needs big electric power plants. For economical and ecological reasons, the nuclear energy seems well appropriate. Libya is for instance very interested in this technique, because of their water shortage problem. (A.L.B.)

  12. Adsorption Desalination: A Novel Method

    KAUST Repository

    Ng, Kim Choon

    2010-11-15

    The search for potable water for quenching global thirst remains a pressing concern throughout many regions of the world. The demand for new and sustainable sources and the associated technologies for producing fresh water are intrinsically linked to the solving of potable water availability and hitherto, innovative and energy efficient desalination methods seems to be the practical solutions. Quenching global thirst by adsorption desalination is a practical and inexpensive method of desalinating the saline and brackish water to produce fresh water for agriculture irrigation, industrial, and building applications. This chapter provides a general overview of the adsorption fundamentals in terms of adsorption isotherms, kinetics, and heat of adsorption. It is then being more focused on the principles of thermally driven adsorption desalination methods. The recent developments of adsorption desalination plants and the effect of operating conditions on the system performance in terms of specific daily water production and performance ratio are presented. Design of a large commercial adsorption desalination plant is also discussed herein.

  13. Observations on the quality of desalinated water in the Segura river basin. Irrigation and supply; Observaciones sobre la calidad del agua desalada en la Cuenca del Seguro. Riego y abastecimiento

    Energy Technology Data Exchange (ETDEWEB)

    Latorre Carrion, M.; Camara Zapata, J. M.

    2004-07-01

    Desalination of seawater by reverse osmosis (RO) is an unconventional water resource that could help to maintain irrigation crops in the Segura river basin. Its suitability for irrigation purposes needs to be studied to prevent the soil from being harmed and the quality and yield of the crops from falling. This article describes a simulation of the functioning of a RO desalination plant based on actual seawater data (Mazarron). The results show that desalinated water has an ionic balance giving rise to a high specific absorption rate of Na+ and low electrical conductivity, which means that its quality for agricultural purposes is deficient. The article sets out the requirements for irrigation water and the problems they pose for desalination plants. The suitability of desalinated water for agricultural purposes is ecaminaed, corrective measures proposed and the cost involved quantified. (Author) 5 refs.

  14. Generation of Electric Energy and Desalinating Water from Solar Energy and the Oceans Hydropower

    Science.gov (United States)

    Elfikky, Niazi

    will decrease or when the Solar thermal radiation of the Sun will increase, the efficiency of the Solar Voltiac Cells will nearly fully degrade at the ambient temperature 55C?(131Fahrenheit). As known, in the African countries near the Atlantic Ocean like Mauritania, Senegal, South Africa and Guinea ..etc, also the middle east countries like Moroco, Tuniz, Lybia, Algeria, Egypt, Sudan, Saudi Arabia, Kuwait, United Arab Emarates and Iraq etc. the range of the ambient temerature in the Summer seasons especially in the Desrt near the Atlantic Ocean, the Mediterranean Sea, Red Sea and the Persian Gulf is around (60-70)C? or (140F-158F). Similarly the majority of the Latin American countries with India and China. So, all the environments of the antecedent countries are not the suitable envuironment for generating electric energy from the Solar Voltiac cells in all seasons along the year. Characteristics of the Concentrated Solar Power (CSP). It uses half cylindrical mirrors to reflect with concentration the Solar thermal Radiation around a pipe to heat a special liquid. When the liquid will be heated it will pass through a water tank to exchange its heat in water tank to evaporate the water and create a steam to drive the Power Turbine for generating electricity. Also the capacity of the electric power generated by such technique is so much limited with respect to the wide area (3000 acres, about five miles end to end) occupied by the Concentrated Solar Power Plant . 3. The New Project Profile. Employing the water from the Oceans, Mediterranean Sea, Red Sea and Chinees sea to generate the bulky Hydraulic power capacity which will be deliverd directly to the electric power Grid without any inverters. The Salt water will be drawn for desalination after driving A Steam Power Turbine for genrating additional electric power. Invited Call, Speaker No.41445.

  15. Microbial desalination cells for energy production and desalination

    KAUST Repository

    Kim, Younggy

    2013-01-01

    Microbial desalination cells (MDCs) are a new, energy-sustainable method for using organic matter in wastewater as the energy source for desalination. The electric potential gradient created by exoelectrogenic bacteria desalinates water by driving ion transport through a series of ion-exchange membranes (IEMs). The specific MDC architecture and current conditions substantially affect the amount of wastewater needed to desalinate water. Other baseline conditions have varied among studies making comparisons of the effectiveness of different designs problematic. The extent of desalination is affected by water transport through IEMs by both osmosis and electroosmosis. Various methods have been used, such as electrolyte recirculation, to avoid low pH that can inhibit exoelectrogenic activity. The highest current density in an MDC to date is 8.4A/m2, which is lower than that produced in other bioelectrochemical systems. This implies that there is a room for substantial improvement in desalination rates and overall performance. We review here the state of the art in MDC design and performance, safety issues related to the use of MDCs with wastewater, and areas that need to be examined to achieve practical application of this new technology. © 2012 Elsevier B.V.

  16. Bounding the marginal cost of producing potable water including the use of seawater desalinization as a backstop potable water production technology

    Energy Technology Data Exchange (ETDEWEB)

    Dooley, James J.

    2014-04-01

    The analysis presented in this technical report should allow for the creation of high, medium, and low cost potable water prices for GCAM. Seawater reverse osmosis (SWRO) based desalinization should act as a backstop for the cost of producing potable water (i.e., the literature seems clear that SWRO should establish an upper bound for the plant gate cost of producing potable water). Transporting water over significant distances and having to lift water to higher elevations to reach end-users can also have a significant impact on the cost of producing water. The three potable fresh water scenarios describe in this technical report are: low cost water scenario ($0.10/m3); medium water cost scenario ($1.00/m3); and high water cost scenario ($2.50/m3).

  17. Energetic and economical evaluation of the geothermal water desalination by distillation; Evaluation energeco-economique du procede de dessalement de l'eau geothermale par distillation

    Energy Technology Data Exchange (ETDEWEB)

    Nasfi, N.; Hajji, N.; Benali, S.; Jeday, M.R. [Ecole Nationale d' Ingenieurs de Gabes, Lab. d' Energetique et d' Ingenierie, Gabes (Tunisia)

    2001-07-01

    This study is devoted to the energetic and economical performance of desalination units by geothermal water distillation, without and with vapor mechanical compression. The process and its block diagram are described. The obtained results allow the evaluation of the more economical process. (A.L.B.)

  18. Desalination and sustainability - An appraisal and current perspective.

    Science.gov (United States)

    Gude, Veera Gnaneswar

    2016-02-01

    Desalination technologies have evolved and advanced rapidly along with increasing water demands around the world since 1950s. Many reviews have focused on the techno-economic and environmental and ecological issues of the desalination technologies and emphasized the feasibility of desalination industry as an alternative to meet the water demands in many water scarce regions. Despite these efforts, many perceptions about desalination processes hinder their applications for potential water supplies. This article has two specific aims: 1) provide an overview of the desalination trends around the world and discuss the sustainability components of desalination processes in comparison with other water supply alternatives; and 2) discuss case studies for desalination, and drivers and factors that influence sustainable desalination and other alternative water sources for desalination to increase our current understanding on the sensitive and futuristic issues of water supply and resource management options for drought facing regions. Although some of the facts and recent developments discussed here show that desalination can be affordable and potentially sustainable, contributions that meaningfully address socio-economic and ecological and environmental issues of desalination processes are urgently required in this critical era of severe water stress for the present context and the future development of desalination technologies. Copyright © 2015 Elsevier Ltd. All rights reserved.

  19. Assessment of wind energy to power solar brackish water greenhouse desalination units. A case study from Algeria

    Energy Technology Data Exchange (ETDEWEB)

    Mahmoudi, Hacene [Laboratory of Water and Environment, Hassiba Ben Bouali University, Chlef, P.O. Box 151 (Algeria); Faculty of Sciences and Engineering Sciences, Hassiba Ben Bouali University, Chlef (Algeria); Spahis, Nawel [Faculty of Sciences and Engineering Sciences, Hassiba Ben Bouali University, Chlef (Algeria); Goosen, Mattheus F. [Alfaisal University, P.O. Box 50927, Riyadh 11533, KSA (Saudi Arabia); Sablani, Shyam [Biological Systems Engineering, Washington State University, Pullman, WA (United States); Abdul-wahab, Sabah A. [College of Engineering, P.O. Box 33, Sultan Qaboos University, Al-Khod 123, Muscat (Oman); Ghaffour, Noreddine [Middle East Desalination Research Center, P.O. Box 21, P.C. 133, Muscat (Oman); Drouiche, Nadjib [Silicon Technology Development Unit (UDTS), 2 Bd Frantz Fanon BP399 Algiers (Algeria)

    2009-10-15

    The Algerian desert dominates large parts of the country's vast territory, and Algeria is among the countries filling most of the world's largest desert. In fact the country is over 80% desert. Even though more than 80% of the population is located in the northern Mediterranean coastal zone, most of oil and gas fields are located in the country's vast southern desert called Sahara. Furthermore, the desert region is developed into a major tourist destination. This arid zone region is characterized by a lack of potable water. However, in addition to the abundant solar energy, the region is also endowed with important wind and brackish groundwater resources with different qualities. Therefore, a brackish water greenhouse desalination unit that is powered by wind energy is a good solution for desalting groundwater for irrigation purposes in this region. Brackish water can be used to cool the greenhouse, creating the proper climate to grow valuable crops. Moreover, at the same time the fresh water that is produced in this system may be sufficient for the irrigation of crops grown inside the unit. In this study, five typical regions in the Sahara were selected and investigated. These regions were selected since they were areas of traditional agriculture. The frequency distributions of wind speed data were collected from Surface Meteorology and Solar Energy (SSE) statistics developed by NASA and evaluated for a 10-year period. The distributions were used to determine the average wind speed and the available wind power for the five locations. The results indicated that the available wind energy is a suitable resource for power production and can be used to provide the required electricity for the brackish groundwater greenhouse desalination units. (author)

  20. Application of geothermal energy for heating and fresh water production in a brackish water greenhouse desalination unit. A case study from Algeria

    Energy Technology Data Exchange (ETDEWEB)

    Mahmoudi, Hacene [Laboratory of Water and Environment, Hassiba Ben Bouali University, Chlef, P.O. Box 151 (Algeria); Faculty of Sciences and Engineering Sciences, Hassiba Ben Bouali University, Chlef (Algeria); Spahis, Nawel [Faculty of Sciences and Engineering Sciences, Hassiba Ben Bouali University, Chlef (Algeria); Goosen, Mattheus F. [Office of Research and Graduate Studies, Alfaisal University, Riyadh (Saudi Arabia); Ghaffour, Noreddine [Middle East Desalination Research Center, P.O. Box 21, P.C. 133, Muscat (Oman); Drouiche, Nadjib [Silicon Technology Development Unit (UDTS), 2 Bd Frantz Fanon BP399, Algiers (Algeria); Ouagued, Abdellah [Laboratory of Water and Environment, Hassiba Ben Bouali University, Chlef, P.O. Box 151 (Algeria)

    2010-01-15

    The aim of this paper was to outline a proposed a new brackish water greenhouse desalination unit powered by geothermal energy for the development of arid and relatively cold regions, using Algeria as a case study. Countries which have abundant sea/brackish water resources and good geothermal conditions are ideal candidates for producing fresh water from sea/brackish water. The establishment of human habitats in these arid areas strongly depends on availability of fresh water. The main advantage of using geothermal energy to power brackish water greenhouse desalination units is that this renewable energy source can provide power 24 h a day. This resource is generally invariant with less intermittence problems compared to other renewable resources such as solar or wind energy. Geothermal resources can both be used to heat the greenhouses and to provide fresh water needed for irrigation of the crops cultivated inside the greenhouses. A review of the geothermal potential in the case study country is also outlined. (author)

  1. Evaluating the efficiency of different microfiltration and ultrafiltration membranes used as pretreatment for Red Sea water reverse osmosis desalination

    KAUST Repository

    Almashharawi, Samir

    2013-01-01

    Conventional processes are widely used as pretreatment for reverse osmosis (RO) desalination technology since its development. However, these processes require a large footprint and have some limitation issues such as difficulty to maintain a consistent silt density index, coagulation control at low total suspended solids, and management of higher waste sludge. Recently, there has been a rapid growth in the use of low-pressure membranes as pretreatment for RO systems replacing the conventional processes. However, despite the numerous advantages of using this integrated membrane system mainly providing good and stable water quality to RO membranes, many issues have to be addressed. The primary limitation is membrane fouling which reduces the permeate flux; therefore, higher pumping intensity is required to maintain a consistent volume of product. This paper aims to optimize the permeation flux and cleaning frequency by providing high permeate quality. Different low-pressure polyethersulfone membranes with different pore sizes ranging from 0.1 lm to 50 kDa were tested. Eight different filtration configurations have been applied including the variation of coagulant doses aiming to control membrane fouling. Results showed that all the configurations with/without coagulation, provided permeate with excellent water quality which improves the stability of RO performance. However, more stable fluxes with less-energy consumption were achieved by using the 0.1 lm and 100 kDa membranes with 1 mg/L FeCl3 coagulation. The use of UF membranes, having tight pores, without coagulation also proved to be an excellent option for Red Sea water RO pretreatment. © 2013 Desalination Publications.

  2. Performance of Potassium Bicarbonate and Calcium Chloride Draw Solutions for Desalination of Saline Water Using Forward Osmosis

    Directory of Open Access Journals (Sweden)

    M. Nematzadeh

    2015-01-01

    Full Text Available Forward osmosis (FO has recently drawn attention as a promising membrane based method for seawater and brackish water desalination. In this study, we focus on the use of calciun chloride (CaCl2 and potassium bicarbonate (KHCO3 as inorganic salt draw solution candidates due to their appropriate performance in water flux and reverse salt diffusion as well as reasonable cost. The experiments were carried at 25 °C and cross-flow rate of 3 L min−1.  At the same osmotic pressure, the water flux of CaCl2 draw solution tested against deionized feed water, showed 20% higher permeation than KHCO3, which it was attributed to the lower internal concentration polarization (ICP. The reverse diffusion of CaCl2 was found higher than KHCO3 solution which it would be related to the smaller ionic size and the higher permeation of this salt through the membrane. The water flux for both draw solutions against 0.33 M NaCl feed solution was about 2.8 times lower than deionized feed water because of ICP. Higher concentrations of draw solution is required for increasing the water permeation from saline water feed towards the draw side.

  3. Aquifer composition and the tendency toward scale-deposit formation during reverse osmosis desalination - Examples from saline ground water in New Mexico, USA

    Science.gov (United States)

    Huff, G.F.

    2006-01-01

    Desalination is expected to make a substantial contribution to water supply in the United States by 2020. Currently, reverse osmosis is one of the most cost effective and widely used desalination technologies. The tendency to form scale deposits during reverse osmosis is an important factor in determining the suitability of input waters for use in desalination. The tendency toward scale formation of samples of saline ground water from selected geologic units in New Mexico was assessed using simulated evaporation. All saline water samples showed a strong tendency to form CaCO3 scale deposits. Saline ground water samples from the Yeso Formation and the San Andres Limestone showed relatively stronger tendencies to form CaSO4 2H2O scale deposits and relatively weaker tendencies to form SiO2(a) scale deposits than saline ground water samples from the Rio Grande alluvium. Tendencies toward scale formation in saline ground water samples from the Dockum Group were highly variable. The tendencies toward scale formation of saline waters from the Yeso Formation, San Andres Limestone, and Rio Grande alluvium appear to correlate with the mineralogical composition of the geologic units, suggesting that scale-forming tendencies are governed by aquifer composition and water-rock interaction. ?? 2006 Elsevier B.V. All rights reserved.

  4. Renewable Energies and Water Security: Thermo Solar Energy as an Alternative for Seawater Desalination in North Africa and the Middle East

    Directory of Open Access Journals (Sweden)

    Luiz Enrique Vieira de Souza

    2016-04-01

    Full Text Available Climate change-related events, added to estimations about economical and population growth – tend to aggravate water scarcity, which is already affecting almost every country in the North of Africa and the Middle East. Based on a critical analysis of the “ACQUA-CSP” report, we discuss the initiatives devoted to the mitigation of water stress in these regions, with an emphasis on the seawater desalination processes. Since existing desalination plants are currently powered by fossil fuels, the use of thermo solar energy will be introduced as a sustainable strategy for the increase of water supply. We conclude that, in order to achieve the successful management of water resources, engineering and infrastructure solutions must be oriented by democratic institutions able to mediate conflicts over the allocation of water resources.

  5. Thermal desalination in GCC and possible development

    KAUST Repository

    Darwish, Mohamed Ali

    2013-06-28

    The Water Desalination and Reuse Center in King Abdulla University of Science and Technology, in Saudi Arabia, held a workshop on thermal desalination on the 11th and 12th of March, 2013. This paper was presented as part of a lecture at the workshop. It presents the status and possible developments of the two main thermal desalination systems processing large quantities of seawater in the Gulf Cooperation Council, multi-stage flash, and thermal vapor compression systems. Developments of these systems were presented to show how these systems are competing with the more energy-efficient seawater reverse osmosis desalting. © 2013 © 2013 Balaban Desalination Publications. All rights reserved.

  6. Bioluminescence-Based Method for Measuring Assimilable Organic Carbon in Pretreatment Water for Reverse Osmosis Membrane Desalination

    Science.gov (United States)

    Weinrich, Lauren A.; Schneider, Orren D.; LeChevallier, Mark W.

    2011-01-01

    A bioluminescence-based assimilable organic carbon (AOC) test was developed for determining the biological growth potential of seawater within the reverse osmosis desalination pretreatment process. The test uses Vibrio harveyi, a marine organism that exhibits constitutive luminescence and is nutritionally robust. AOC was measured in both a pilot plant and a full-scale desalination plant pretreatment. PMID:21148685

  7. Bacterial community structure and variation in a full-scale seawater desalination plant for drinking water production

    NARCIS (Netherlands)

    Belila, A.; El-Chakhtoura, J.; Otaibi, N.; Muyzer, G.; Gonzalez-Gil, G.; Saikaly, P.E.; van Loosdrecht, M.C.M.; Vrouwenvelder, J.S.

    2016-01-01

    Microbial processes inevitably play a role in membrane-based desalination plants, mainly recognized as membrane biofouling. We assessed the bacterial community structure and diversity during different treatment steps in a full-scale seawater desalination plant producing 40,000 m3/d of drinking

  8. High-flux water desalination with interfacial salt sieving effect in nanoporous carbon composite membranes

    CERN Document Server

    Chen, Wei; Zhang, Qiang; Fan, Zhongli; Huang, Kuo-Wei; Zhang, Xixiang; Lai, Zhiping; Sheng, Ping

    2016-01-01

    Nanoporous carbon composite membranes, comprising a layer of porous carbon fiber structures with an average channel width of 30-60 nm grown on a porous ceramic substrate, are found to exhibit robust desalination effect with high freshwater flux. In three different membrane processes of vacuum membrane distillation, reverse osmosis and forward osmosis, the carbon composite membrane showed 100% salt rejection with 3.5 to 20 times higher freshwater flux compared to existing polymeric membranes. Thermal accounting experiments found that at least 80% of the freshwater pass through the carbon composite membrane with no phase change. Molecular dynamics simulations revealed a unique salt rejection mechanism. When seawater is interfaced with either vapor or the surface of carbon, one to three interfacial atomic layers contain no salt ions. Below the liquid entry pressure, the salt solution is stopped at the openings to the porous channels and forms a meniscus, while the surface layer of freshwater can feed the surface...

  9. Can the Adoption of Desalination Technology Lead to Aquifer Preservation? A Case Study of a Sociotechnical Water System in Baja California Sur, Mexico

    OpenAIRE

    Jamie McEvoy

    2015-01-01

    There is growing concern about the sustainability of groundwater supplies worldwide. In many regions, desalination—the conversion of saline water to freshwater—is viewed as a way to increase water supplies and reduce pressure on overdrawn aquifers. Using data from reports, articles, interviews, a survey, and a focus group, this paper examines if, and how, the adoption of desalination technology can lead to aquifer preservation in Baja California Sur (BCS), Mexico. The paper outlines existing ...

  10. Evaporative processes for desalination of produced water; Processos evaporativos para dessalinizacao de agua produzida a fins de reuso

    Energy Technology Data Exchange (ETDEWEB)

    Andrade, Vivian T.; Dezotti, Marcia W. [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Coordenacao dos Programas de Pos-graduacao de Engenharia (COPPE). Programa de Engenharia Quimica; Schuhli, Juliana B.; Gomes, Marcia T.; Pereira Junior, Oswaldo A. [PETROBRAS S.A., Rio de Janeiro, RJ (Brazil)

    2008-07-01

    During the productive life of an oil well, it gets the moment when a big quantity of produced water comes together with the oil. It can achieve 99% in the end of its economical life. The thermal desalination of the formation water is one of the most common technologies for achieving its reuse. This way, it was constructed one 'Robert' evaporator. The tests used different sodium chloride concentrations from 2,000 mg/L to 80,000 mg/L simulating concentrations found in the produced water from PETROBRAS wells. The tests were conducted in three different vacuum pressures. It was observed, increasing the vacuum applied to the system, results in reduction of solution boiling point. The salt concentrations of the brine blowdown were influenced by the sodium chloride concentration at the feed flow, by the vacuum applied to the system and, consequently, by the solution boiling point and flow rates. The produced distillate water presented sodium chloride concentration lower than 2 mg/L, indicating that this system can produce water to reuse in irrigation. (author)

  11. Economical analysis of a solar desalination system

    DEFF Research Database (Denmark)

    Chen, Ziqian; Wang, Tie-Zhu; He, Xiao-Rong

    2012-01-01

    Based on the calculation of the single-factor impact values of the parameters of a triple stage tower-type of solar desalination unit by utilizing a single-factor analyzing method, the influences of the cost of solar heating system, the cost of hot water tank, the costs of desalination unit and y...

  12. Establishment of the Underlying Rationale and Description of a Cheap Nanofiltration-Based Method for Supplementing Desalinated Water with Magnesium Ions

    Directory of Open Access Journals (Sweden)

    Liat Birnhack

    2014-05-01

    Full Text Available The importance of supplying drinking water with a balanced mineral composition, including a minimal concentration of Mg(II ions, has been recently acknowledged by many publications, as well as in official WHO guidelines. The issue is relevant to naturally occurring soft waters and lately to the rapidly increasing volume of supplied desalinated water. This paper presents an enhancement of a recently developed nanofiltration-based method for the selective separation of soluble Mg(II species from seawater. The generated rich-Mg(II brine is demonstrated to be suitable for supplementing soft waters with magnesium ions. The brine, generated using a commercial membrane (DS-5 DL, Osmonics at various operational conditions is characterized by high Mg(II concentrations (~8.5 g/L and low Cl:Mg and Na:Mg molar concentration ratios (1.6 and 0.6, respectively, at 28-bar operation. A food-grade antiscalant is dosed to the feed seawater to prevent scaling; however, since the Mg(II concentration in the brine is high, for attaining 10 mg Mg/L of desalinated water, the dilution ratio with the desalinated water is ~1:850, resulting in maximal additional concentrations of 0.024 antiscalant, 34.9 Cl(−I, 12.9 Na(I, 0.05 Sr(II and 0.003 B (all concentrations in mg/L. The overall cost of 1 kg of Mg(II separated by the presented process amounts to between $0.05 and $0.07, i.e., much cheaper than the estimated costs of alternative processes for Mg(II addition to desalinated water.

  13. The future of seawater desalination: energy, technology, and the environment.

    Science.gov (United States)

    Elimelech, Menachem; Phillip, William A

    2011-08-05

    In recent years, numerous large-scale seawater desalination plants have been built in water-stressed countries to augment available water resources, and construction of new desalination plants is expected to increase in the near future. Despite major advancements in desalination technologies, seawater desalination is still more energy intensive compared to conventional technologies for the treatment of fresh water. There are also concerns about the potential environmental impacts of large-scale seawater desalination plants. Here, we review the possible reductions in energy demand by state-of-the-art seawater desalination technologies, the potential role of advanced materials and innovative technologies in improving performance, and the sustainability of desalination as a technological solution to global water shortages.

  14. State-of-art report on the seawater desalination process

    Energy Technology Data Exchange (ETDEWEB)

    Hwang, Young Dong; Kim, Young In; Lee, Doo Jung; Chang, Moon Hee

    2000-11-01

    Desalination technologies have been developed over the last 40 years and become a reliable industrial process for water production from sea or blackish water. At present, various desalination processes are available for the effective use of seawater or blackish water as valuable water resources. Since a large amount of energy is required for seawater desalination, the cost of energy is important for desalination. For the regions of severe water shortage, however, desalination is the most economical way of water supply compare to any other alternatives. Currently, water supply by seawater desalination is being increased in the areas of the Caribbean, North African and Middle East. Also, desalination of blackish water is being increased in the south-east region of USA. In general, the distillation process and the membrane technology are used for seawater esalination and the membrane and the electric-dialysis for blackish water. However, the selection of the desalination process is highly dependent on the use of produced water and the local environmental conditions where the desalination plant installed. The local condition is the most important parameters for the selection of the desalination process.

  15. Photocatalytic Treatment of Desalination Concentrate Using Optical Fibers Coated With Nanostructured Thin Films: Impact of Water Chemistry and Seasonal Climate Variations.

    Science.gov (United States)

    Lin, Lu; Wang, Huiyao; Luo, Hongmei; Xu, Pei

    2016-05-01

    Treatment of desalination concentrate can reduce concentrate volume for disposal, increase water recovery and convert waste to resource. However, concentrate treatment is costly and energy intensive due to high concentrations of salt and recalcitrant organic matter in concentrate. Photocatalytic oxidation provides a novel energy neutral technology for concentrate treatment by degrading organic contaminants. Polymer-assisted hydrothermal deposition method was used to synthesize innovative pure and Fe-doped TiO2 mixed-phase nanocomposite thin films on side-glowing optical fibers (SOFs). The properties of the photocatalysts-coated SOF were characterized by surface morphology, nanostructure, crystallite size and phase and zeta potential. Photodegradation efficiency and durability of the photocatalysts treating different types of desalination concentrate was studied under natural sunlight. Synthetic solutions and reverse osmosis (RO) concentrates from brackish water and municipal wastewater desalination facilities were tested to elucidate the impact of water chemistry, operating conditions and seasonal climate variations (solar irradiation intensity and temperature) on photocatalytic efficiency. High ionic strength and divalent electrolyte ions in RO concentrate accelerated photocatalytic process, whereas the presence of carbonate species and organic matter hindered photodegradation. Outdoor testing of immobilized continuous-flow photoreactors suggested that the catalyst-coated SOFs can utilize a wide spectrum of natural sunlight and achieved durable photocatalytic performance. © 2016 The American Society of Photobiology.

  16. Impact of elevated Ca(2+)/Mg(2+) concentrations of reverse osmosis membrane desalinated seawater on the stability of water pipe materials.

    Science.gov (United States)

    Liang, Juan; Deng, Anqi; Xie, Rongjing; Gomez, Mylene; Hu, Jiangyong; Zhang, Jufang; Ong, Choon Nam; Adin, Avner

    2014-03-01

    Hardness and alkalinity are known factors influencing the chemical stability of desalinated water. This study was carried out to investigate the effect of Ca(2+) and Mg(2+) on corrosion and/or scale formation on the surface of different water distribution pipe materials under tropical conditions. The corrosion rates of ductile iron, cast iron and cement-lined ductile iron coupons were examined in reverse osmosis (RO) membrane desalinated seawater which was remineralised using different concentrations of Ca(2+) and Mg(2+). The changes in water characteristics and the coupon corrosion rates were studied before and after the post-treatment. The corrosion mechanisms and corrosion products were examined using scanning electron microscope and X-ray diffraction, respectively. We found that the combination of Ca(2+) and Mg(2+) (60/40 mg/L as CaCO3) resulted in lower corrosion rates than all other treatments for the three types of pipe materials, suggesting that Ca(2+)/Mg(2+) combination improves the chemical stability of desalinated seawater rather than Ca(2+) only.

  17. Preliminary design of seawater and brackish water reverse osmosis desalination systems driven by low-temperature solar organic Rankine cycles (ORC)

    Energy Technology Data Exchange (ETDEWEB)

    Delgado-Torres, Agustin M. [Dpto. Fisica Fundamental y Experimental, Electronica y Sistemas, Escuela Tecnica Superior de Ingenieria Civil e Industrial, Universidad de La Laguna (ULL), Avda. Astrofisico Francisco Sanchez s/n. 38206 La Laguna (Tenerife) (Spain); Garcia-Rodriguez, Lourdes [Dpto. Ingenieria Energetica, Universidad de Sevilla Escuela Tecnica Superior de Ingenieros, Camino de los Descubrimientos, s/n 41092 Sevilla (Spain)

    2010-12-15

    In this paper, the coupling between the low-temperature solar organic Rankine cycle (ORC) and seawater and brackish water reverse osmosis desalination units has been carried out. Four substances have been considered as working fluids of the solar cycle (butane, isopentane, R245fa and R245ca). With these four fluids the volumetric flow of fresh water produced per unit of aperture area of stationary solar collector has been calculated. The former has been made with the optimized direct vapour generation (DVG) configuration and heat transfer fluid (HTF) configuration of the solar ORC. In the first one (DVG), working fluid of the ORC is directly heated inside the absorber of the solar collector. In the second one (HTF), a fluid different than the working fluid of the ORC (water in this paper) is heated without phase change inside the absorber of the solar collector. Once this fluid has been heated it is carried towards a heat exchanger where it is cooled. Thermal energy delivered in this cooling process is transferred to the working fluid of the ORC. Influence of condensation temperature of the ORC and regeneration's process effectiveness over productivity of the system has also been analysed. Finally, parameters of several preliminary designs of the low-temperature solar thermal driven RO desalination are supplied. R245fa is chosen as working fluid of the ORC in these preliminary designs. The information of the proposed preliminary designs can also be used, i.e., for the assessment of the use of thermal energy rejected by the solar cycle. Overall analysis of the efficiency of the solar thermal driven RO desalination technology is given with the results presented in this paper and the results obtained with the medium temperature solar thermal RO desalination system presented by the authors in previous papers. This work has been carried out within the framework of the OSMOSOL and POWERSOL projects. (author)

  18. Eukaryotic community diversity and spatial variation during drinking water production (by seawater desalination) and distribution in a full-scale network

    KAUST Repository

    Belila, Abdelaziz

    2016-12-01

    Eukaryotic microorganisms are naturally present in many water resources and can enter, grow and colonize water treatment and transport systems, including reservoirs, pipes and premise plumbing. In this study, we explored the eukaryotic microbial community structure in water during the (i) production of drinking water in a seawater desalination plant and (ii) transport of the drinking water in the distribution network. The desalination plant treatment involved pre-treatment (e.g. spruce filters), reverse osmosis (RO) membrane filtration and post-treatment steps (e.g. remineralization). 454 pyrosequencing analysis of the 18S rRNA gene revealed a highly diverse (35 phyla) and spatially variable eukaryotic community during water treatment and distribution. The desalination plant feed water contained a typical marine picoeukaryotic community dominated by Stramenopiles, Alveolates and Porifera. In the desalination plant Ascomycota was the most dominant phylum (15.5% relative abundance), followed by Alveolata (11.9%), unclassified fungi clade (10.9%) and Porifera (10.7%). In the drinking water distribution network, an uncultured fungi phylum was the major group (44.0%), followed by Chordata (17.0%), Ascomycota (11.0%) and Arthropoda (8.0%). Fungi constituted 40% of the total eukaryotic community in the treatment plant and the distribution network and their taxonomic composition was dominated by an uncultured fungi clade (55%). Comparing the plant effluent to the network samples, 84 OTUs (2.1%) formed the core eukaryotic community while 35 (8.4%) and 299 (71.5%) constituted unique OTUs in the produced water at the plant and combined tap water samples from the network, respectively. RO membrane filtration treatment significantly changed the water eukaryotic community composition and structure, highlighting the fact that (i) RO produced water is not sterile and (ii) the microbial community in the final tap water is influenced by the downstream distribution system. The study

  19. Energy analysis of a desalination process of sea water with nuclear energy; Analisis energetico de un proceso de desalinizacion de agua de mar con energia nuclear

    Energy Technology Data Exchange (ETDEWEB)

    Martinez L, G.; Valle H, J., E-mail: julfi_jg@yahoo.com.mx [Universidad Politecnica Metropolitana de Hidalgo, Boulevard acceso a Tolcayuca No. 1009, Ex-hacienda San Javier, 43860 Tolcayuca, Hidalgo (Mexico)

    2016-09-15

    In the present work, is theoretically proven that the residual heat, removed by the chillers in the stage prior to the compression of the recuperative Brayton cycle with which nuclear power plants operate with high temperature gas reactors (HTGR), can be used to produce stem and desalinate seawater. The desalination process selected for the analysis, based on its operating characteristics, is the Multi-Stage Distillation (Med). The Med process will use as energy source, for the flash evaporation process in the flash trap, the residual heat that the reactor coolant dissipates to the environment in order to increase the compression efficiency of the same; the energy dissipated depends on the operating conditions of the reactor. The Med distillation process requires saturated steam at low pressure which can be obtained by means of a heat exchanger, taking advantage of the residual heat, where the relative low temperatures with which the process operates make the nuclear plants with HTGR reactors ideal for desalination of sea water, because they do not require major modifications to their design of their operation. In this work the energy analysis of a six-stage Med module coupled to the chillers of an HTGR reactor of the Pebble Bed Modular Reactor type is presented. Mathematical modeling was obtained by differential equations of mass and energy balances in the system. The results of the analysis are presented in a table for each distillation stage, estimating the pure water obtained as a function of the heat supplied. (Author)

  20. Sorption of Arsenic from Desalination Concentrate onto Drinking Water Treatment Solids: Operating Conditions and Kinetics

    Directory of Open Access Journals (Sweden)

    Xuesong Xu

    2018-01-01

    Full Text Available Selective removal of arsenic from aqueous solutions with high salinity is required for safe disposal of the concentrate and protection of the environment. The use of drinking water treatment solids (DWTS to remove arsenic from reverse osmosis (RO concentrate was studied by batch sorption experiments. The impacts of solution chemistry, contact time, sorbent dosage, and arsenic concentration on sorption were investigated, and arsenic sorption kinetics and isotherms were modeled. The results indicated that DWTS were effective in removing arsenic from RO concentrate. The arsenic sorption process followed a pseudo-second-order kinetic model. Multilayer adsorption was simulated by Freundlich equation. The maximum sorption capacities were calculated to be 170 mg arsenic per gram of DWTS. Arsenic sorption was enhanced by surface precipitation onto the DWTS due to the high amount of calcium in the RO concentrate and the formation of ternary complexes between arsenic and natural organic matter (NOM bound by the polyvalent cations in DWTS. The interactions between arsenic and NOM in the solid phase and aqueous phase exhibited two-sided effects on arsenic sorption onto DWTS. NOM in aqueous solution hindered the arsenic sorption onto DWTS, while the high organic matter content in solid DWTS phase enhanced arsenic sorption.

  1. Adsorption desalination: An emerging low-cost thermal desalination method

    KAUST Repository

    Ng, K. C.

    2013-01-01

    Desalination, other than the natural water cycle, is hailed as the panacea to alleviate the problems of fresh water shortage in many water stressed countries. However, the main drawback of conventional desalination methods is that they are energy intensive. In many instances, they consumed electricity, chemicals for pre- and post-treatment of water. For each kWh of energy consumed, there is an unavoidable emission of Carbon Dioxide (CO2) at the power stations as well as the discharge of chemically-laden brine into the environment. Thus, there is a motivation to find new direction or methods of desalination that consumed less chemicals, thermal energy and electricity.This paper describes an emerging and yet low cost method of desalination that employs only low-temperature waste heat, which is available in abundance from either the renewable energy sources or exhaust of industrial processes. With only one heat input, the Adsorption Desalination (AD) cycle produces two useful effects, i.e., high grade potable water and cooling. In this article, a brief literature review, the theoretical framework for adsorption thermodynamics, a lumped-parameter model and the experimental tests for a wide range of operational conditions on the basic and the hybrid AD cycles are discussed. Predictions from the model are validated with measured performances from two pilot plants, i.e., a basic AD and the advanced AD cycles. The energetic efficiency of AD cycles has been compared against the conventional desalination methods. Owing to the unique features of AD cycle, i.e., the simultaneous production of dual useful effects, it is proposed that the life cycle cost (LCC) of AD is evaluated against the LCC of combined machines that are needed to deliver the same quantities of useful effects using a unified unit of $/MWh. In closing, an ideal desalination system with zero emission of CO2 is presented where geo-thermal heat is employed for powering a temperature-cascaded cogeneration plant.

  2. Energy system impacts of desalination in Jordan

    DEFF Research Database (Denmark)

    Østergaard, Poul Alberg; Lund, Henrik; Mathiesen, Brian Vad

    2014-01-01

    Climate change mitigation calls for energy systems minimising end-use demands, optimising the fuel efficiency of conversion systems, increasing the use of renewable energy sources and exploiting synergies wherever possible. In parallel, global fresh water resources are strained due to amongst...... others population and wealth increase and competitive water uses from agriculture and industry is causing many nations to turn to desalination technologies. This article investigates a Jordanian energy scenario with two different desalination technologies; reverse osmosis (RO) driven by electricity...

  3. Performance evaluation of reverse osmosis desalination plants for rural water supply in a developing country--a case study.

    Science.gov (United States)

    Kelkar, P S; Joshi, V A; Ansari, M H; Manivel, U

    2003-12-01

    Performance evaluation of two reverse osmosis (RO) desalination plants (DSP) at villages: Melasirupodhu (30 m3 day(-1)) and Sikkal (50 m3 day(-1)) in Ramanathpuram district, Tamil Nadu (India) were studied so as to bring out the state-of-art of their operation and maintenance (O&M). Detailed information on plant design and engineering, water quality, plant personnel, and cost of O&M was collected for a period of three years after commissioning of the two plants. Feed water was brackish, the TDS varied in the range of 6500-8500 mg L(-1) at Melasirupodhu and 5300-7100 mg L(-1) at Sikkal villages. The product water quality was observed to be gradually deteriorating as the salt rejection by the membranes decreased with time. The salt rejection was 97-99% at the time of commissioning of the plants, and came down to 89-90% at the end of 3 years of operation. Product water TDS soon after installation of the plants was excellent and within desirable limits of BIS. After three years of operation, few parameters exceeded the desirable limits, however, they were found to be within permissible limits of BIS. The analyses of the data showed that both plants were operated only at 30-36% of the design capacity. Plant shut-down due to inadequate and erratic power supply, and plant break-down and inherent delay in repairs due to lack of adequate infrastructure were found to be the major causes for the low utilization of the plants. Consequently the recurring cost of product water production enhanced to Rs. 25.0/m3 at Melasirupodhu and Rs. 17.5 m(-3) at Sikkal, as against the estimated cost of Rs. 15.0/m3 and Rs. 11.0/m3, respectively, as per the design. Over the years, the energy consumption for the product water output increased reflecting higher operational pressures needed with the aging of the membranes.

  4. International overview of seawater desalination plant by reverse osmosis technology

    OpenAIRE

    Kangwen, Shu

    2012-01-01

    Master's thesis in Environmental technology In a world faced with increased urbanization, population growth, climate change and degradation of water supplies, the importance of a reliable source of technology to provide fresh water emphasizes the importance of seawater desalination. Over the years a variety of seawater desalination methods have been developed throughout the world. The most common technologies available for desalination around the world are membrane reverse osmosis (RO),...

  5. International overview of seawater desalination plant by reverse osmosis technology

    OpenAIRE

    Kangwen, Shu

    2012-01-01

    In a world faced with increased urbanization, population growth, climate change and degradation of water supplies, the importance of a reliable source of technology to provide fresh water emphasizes the importance of seawater desalination. Over the years a variety of seawater desalination methods have been developed throughout the world. The most common technologies available for desalination around the world are membrane reverse osmosis (RO), thermal distillation (TD) and electrodialysis ...

  6. The Use of Solar Energy in the Desalination Sea Water in ...

    African Journals Online (AJOL)

    ... the use of sea water while exploiting the phenomenon of condensation of water vapor in the air, seems to respond positively to the needs of agricultural irrigation. Keywords: Seawater greenhouse; Condenser; dry bulb temperature; relative humidity; seawater temperature; humid air flux; seawater flux; Sultanate of Oman.

  7. Selection of inorganic-based fertilizers in forward osmosis for water desalination

    Directory of Open Access Journals (Sweden)

    Tripti Mishra

    2015-06-01

    Full Text Available The current study aims at the selection of an appropriate draw solute for forward osmosis process. Separation and recovery of the draw solute are the major criteria for the selection of draw solute for forward osmosis process. Therefore in this investigation six inorganic fertilizers draws solute were selected. The selections of inorganic fertilizers as draw solute eliminate the need of removal and recovery of draw solute from the final product. The final product water of forward osmosis process has direct application in agricultural as nutrient rich water for irrigation. These inorganic fertilizers were tested based on their water extraction (water flux capacity. This experimental water flux was compared with the observed water flux. It was noted that the observed water flux is much higher than the attained experimental water flux. The difference of these two fluxes was used to calculate the performance ratio of each selected fertilizer. Highest performance ratio was shown by low molecular weight compound ammonium nitrate (22.73 and potassium chloride (21.03 at 1 M concentration, whereas diammonium phosphate (DAP which has highest molecular weight among all the selected fertilizer show the lowest performance ratio (10.02 at 2 M concentration. DOI: http://dx.doi.org/10.3126/ije.v4i2.12660 International Journal of Environment Vol.4(2 2015: 319-329

  8. Wireless desalination using inductively powered porous carbon electrodes

    NARCIS (Netherlands)

    Kuipers, J.; Porada, S.

    2013-01-01

    Water desalination by capacitive deionization (CDI) uses electrochemical cell pairs formed of porous carbon electrodes, which are brought in contact with the water that must be desalinated. Upon applying a cell voltage or current between the electrodes, ions are electrosorbed and water is produced

  9. Sustainable urban water supply in south India: Desalination, efficiency improvement, or rainwater harvesting?

    National Research Council Canada - National Science Library

    Veena Srinivasan; Steven M. Gorelick; Lawrence Goulder

    2010-01-01

    ...; no Indian city provides 24/7 water supply. Current approaches to addressing the problem have been utility centric, overlooking the significance of decentralized activities by consumers, groundwater extraction via private wells, and aquifer...

  10. Disinfection by-product formation during seawater desalination: A review.

    Science.gov (United States)

    Kim, Daekyun; Amy, Gary L; Karanfil, Tanju

    2015-09-15

    Due to increased freshwater demand across the globe, seawater desalination has become the technology of choice in augmenting water supplies in many parts of the world. The use of chemical disinfection is necessary in desalination plants for pre-treatment to control both biofouling as well as the post-disinfection of desalinated water. Although chlorine is the most commonly used disinfectant in desalination plants, its reaction with organic matter produces various disinfection by-products (DBPs) (e.g., trihalomethanes [THMs], haloacetic acids [HAAs], and haloacetonitriles [HANs]), and some DBPs are regulated in many countries due to their potential risks to public health. To reduce the formation of chlorinated DBPs, alternative oxidants (disinfectants) such as chloramines, chlorine dioxide, and ozone can be considered, but they also produce other types of DBPs. In addition, due to high levels of bromide and iodide concentrations in seawater, highly cytotoxic and genotoxic DBP species (i.e., brominated and iodinated DBPs) may form in distribution systems, especially when desalinated water is blended with other source waters having higher levels of organic matter. This article reviews the knowledge accumulated in the last few decades on DBP formation during seawater desalination, and summarizes in detail, the occurrence of DBPs in various thermal and membrane plants involving different desalination processes. The review also identifies the current challenges and future research needs for controlling DBP formation in seawater desalination plants and to reduce the potential toxicity of desalinated water. Copyright © 2015 Elsevier Ltd. All rights reserved.

  11. The effect of intermittent operation on a wind-powered membrane system for brackish water desalination.

    Science.gov (United States)

    Park, G L; Schäfer, A I; Richards, B S

    2012-01-01

    Renewable energy powered membrane systems that are directly-connected must take account of both the inherent fluctuations and the intermittency of the energy resource. In order to determine the effect of intermittent operation, a membrane system was tested with variables of (i) amplitude from 60 to 300 W and (ii) length of time with no power from 0.5 to 3 min. This was performed over one hour periods with six on/off cycles to simulate the system operating under intermittent operation for short periods of time when directly-connected to a small wind turbine. The setup used a Filmtec BW30-4040 brackish water reverse osmosis membrane with feed waters of 2,750 mg/L and 5,500 mg/L NaCl. The results showed that the membrane system produced potable water under the majority of intermittency experiments performed. There was a relatively large increase in the average salt concentration of the permeate, especially when the system was off for shorter periods of time (0.5-1 min). Longer periods of no power (1-3 min) did not have as significant an effect on the average water quality. This is important when the need for energy buffering or short term storage is considered for these systems as it shows the potential for improving the overall flux and water quality using temporary energy storage.

  12. Sustainable urban water supply in south India: Desalination, efficiency improvement, or rainwater harvesting?

    Science.gov (United States)

    Srinivasan, Veena; Gorelick, Steven M.; Goulder, Lawrence

    2010-10-01

    Indian megacities face severe water supply problems owing to factors ranging from growing population to high municipal pipe leakage rates; no Indian city provides 24/7 water supply. Current approaches to addressing the problem have been "utility centric," overlooking the significance of decentralized activities by consumers, groundwater extraction via private wells, and aquifer recharge by rainwater harvesting. We propose a framework that makes it possible to evaluate a wider range of centralized and decentralized policies than previously considered. The framework was used to simulate water supply and demand in a simulation model of Chennai, India. Three very different policies, supply augmentation, efficiency improvement, and rainwater harvesting, were evaluated using the model. The model results showed that none of the three policies perfectly satisfied our criteria of efficiency, reliability, equity, financial viability, and revenue generation. Instead, a combination of rainwater harvesting and efficiency improvement best meets these criteria.

  13. Corrosion and Protection of Metal in the Seawater Desalination

    Science.gov (United States)

    Hou, Xiangyu; Gao, Lili; Cui, Zhendong; Yin, Jianhua

    2018-01-01

    Seawater desalination develops rapid for it can solve water scarcity efficiently. However, corrosion problem in the seawater desalination system is more serious than that in normal water. So, it is important to pay attention to the corrosion and protection of metal in seawater desalination. The corrosion characteristics and corrosion types of metal in the seawater desalination system are introduced in this paper; In addition, corrosion protect methods and main influencing factors are stated, the latest new technologies about anti-corrosion with quantum energy assisted and magnetic inhibitor are presented.

  14. Energy systems impacts of reverse osmosis and thermal desalination in Jordan

    DEFF Research Database (Denmark)

    Østergaard, Poul Alberg; Lund, Henrik; Mathiesen, Brian Vad

    2013-01-01

    others population and wealth increase and competitive water uses from agriculture and industry is causing many nations to turn to desalination technologies. This paper investigates a Jordanian energy scenario with two different desalination technologies; reverse osmosis (RO) driven by electricity...

  15. Desalination of salty water using vacuum spray dryer driven by solar energy

    KAUST Repository

    Hamawand, Ihsan

    2016-11-18

    This paper addresses evaporation under vacuum condition with the aid from solar energy and the recovered waste heat from the vacuum pump. It is a preliminary attempt to design an innovative solar-based evaporation system under vacuum. The design details, equipment required, theoretical background and work methodology are covered in this article. Theoretically, based on the energy provided by the sun during the day, the production rate of pure water can be around 15 kg/m2/day. Assumptions were made for the worst case scenario where only 30% of the latent heat of evaporation is recycled and the ability of the dark droplet to absorb sun energy is around 50%. Both the waste heat from the pump and the heat collected from the photovoltaic (PV) panels are proposed to raise the temperature of the inlet water to the system to its boiling point at the selected reduced pressure.

  16. Design of Anion Exchange Membranes and Electrodialysis Studies for Water Desalination

    Directory of Open Access Journals (Sweden)

    Muhammad Imran Khan

    2016-05-01

    Full Text Available Anion exchange membranes are highly versatile and nowadays have many applications, ranging from water treatment to sensing materials. The preparation of anion exchange membranes (AEMs from brominated poly(2,6-dimethyl-1,6-phenylene oxide (BPPO and methyl(diphenylphosphine (MDPP for electrodialysis was performed. The physiochemical properties and electrochemical performance of fabricated membranes can be measured by changing MDPP contents in the membrane matrix. The influence of a quaternary phosphonium group associated with the removal of NaCl from water is discussed. The prepared membranes have ion exchange capacities (IEC 1.09–1.52 mmol/g, water uptake (WR 17.14%–21.77%, linear expansion ratio (LER 7.96%–11.86%, tensile strength (TS 16.66–23.97 MPa and elongation at break (Eb 485.57%–647.98%. The prepared anion exchange membranes were employed for the electrodialytic removal of 0.1 M NaCl aqueous solution at a constant applied voltage. It is found that the reported membranes could be the promising candidate for NaCl removal via electrodialysis.

  17. Design of Anion Exchange Membranes and Electrodialysis Studies for Water Desalination

    Science.gov (United States)

    Khan, Muhammad Imran; Luque, Rafael; Akhtar, Shahbaz; Shaheen, Aqeela; Mehmood, Ashfaq; Idress, Sidra; Buzdar, Saeed Ahmad; ur Rehman, Aziz

    2016-01-01

    Anion exchange membranes are highly versatile and nowadays have many applications, ranging from water treatment to sensing materials. The preparation of anion exchange membranes (AEMs) from brominated poly(2,6-dimethyl-1,6-phenylene oxide) (BPPO) and methyl(diphenyl)phosphine (MDPP) for electrodialysis was performed. The physiochemical properties and electrochemical performance of fabricated membranes can be measured by changing MDPP contents in the membrane matrix. The influence of a quaternary phosphonium group associated with the removal of NaCl from water is discussed. The prepared membranes have ion exchange capacities (IEC) 1.09–1.52 mmol/g, water uptake (WR) 17.14%–21.77%, linear expansion ratio (LER) 7.96%–11.86%, tensile strength (TS) 16.66–23.97 MPa and elongation at break (Eb) 485.57%–647.98%. The prepared anion exchange membranes were employed for the electrodialytic removal of 0.1 M NaCl aqueous solution at a constant applied voltage. It is found that the reported membranes could be the promising candidate for NaCl removal via electrodialysis. PMID:28773487

  18. Identification of optimum outfall location for desalination plant in the coastal waters off Tuticorin, India

    Digital Repository Service at National Institute of Oceanography (India)

    DineshKumar, P.K.; NaveenKumar, K.R.; Muraleedharan, K.R.

    to the coastline. The upward angle of the port is required to allow the fluid to pass through relatively longer trajectory in order to get more initial dilution. As the effluent is heavier than the receiving water it would initially rise to 4 m due to jet.... The diffuser should be kept at a height of 0.5 m above bed level with the ports aligned parallel to the coastline. The upward angle of the port is required to allow the fluid to pass through relatively longer trajectory to achieve more initial dilution...

  19. Apparatus and method for improved desalination

    KAUST Repository

    Ng, Kim Choon

    2009-12-30

    A water desalination system comprising an evaporator for evaporating saline water to produce water vapor; a condenser for condensing the water vapor; wherein the evaporator and the condenser are in heat transfer communication such that heat used by the evaporator is at least in part derived from the condenser.

  20. Direct seawater desalination by ion concentration polarization.

    Science.gov (United States)

    Kim, Sung Jae; Ko, Sung Hee; Kang, Kwan Hyoung; Han, Jongyoon

    2010-04-01

    A shortage of fresh water is one of the acute challenges facing the world today. An energy-efficient approach to converting sea water into fresh water could be of substantial benefit, but current desalination methods require high power consumption and operating costs or large-scale infrastructures, which make them difficult to implement in resource-limited settings or in disaster scenarios. Here, we report a process for converting sea water (salinity approximately 500 mM or approximately 30,000 mg l(-1)) to fresh water (salinity desalination of sea water (approximately 99% salt rejection at 50% recovery rate) at a power consumption of less than 3.5 Wh l(-1), which is comparable to current state-of-the-art systems. Rather than competing with larger desalination plants, the method could be used to make small- or medium-scale systems, with the possibility of battery-powered operation.

  1. Development of polyelectrolyte multilayer thin film composite membrane for water desalination application

    KAUST Repository

    Fadhillah, F.

    2013-06-01

    Thin film composite membranes were fabricated via spin assisted layer by layer (SA-LbL) assembly by depositing alternate layers of poly(allyl amine hydrochloride) (PAH) and poly(acrylic acid) (PAA) on a polysulfone (PSF) ultrafiltration membrane as support. The suitability of these membranes for potential water purification applications was explored by testing the stability of the deposited thin films and their permeation characteristic using cross-flow permeation cell. Permeation test conducted at a pressure of 40bar, temperature of 25°C, pH of 6 and feed water concentration of 2000ppm NaCl demonstrated that the PAH/PAA multilayer film deposited on polysulfone support remained stable and intact under long-term test conditions. The 120 bilayers of PAH/PAA membrane tested at the above condition showed flux of 15L/m2.h and salt rejection of 65%. The membrane performance evaluation also revealed that SA-LbL PAH/PAA membrane follows the characteristics of the solution diffusion membrane. © 2013 Elsevier B.V.

  2. Series assembly of microbial desalination cells containing stacked electrodialysis cells for partial or complete seawater desalination.

    Science.gov (United States)

    Kim, Younggy; Logan, Bruce E

    2011-07-01

    A microbial desalination cell (MDC) is a new approach for desalinating water based on using the electrical current generated by exoelectrogenic bacteria. Previously developed MDCs have used only one or two desalination chambers with substantial internal resistance, and used low salinity catholytes containing a buffered or acid solution. Here we show that substantially improved MDC performance can be obtained even with a nonbuffered, saline catholyte, by using an electrodialysis stack consisting of 5 pairs of desalting and concentrating cells. When 4 stacked MDCs were used in series (20 total pairs of desalination chambers), the salinity of 0.06 L of synthetic seawater (35 g/L NaCl) was reduced by 44% using 0.12 L of anode solution (2:1). The resistive loss in the electrodialysis stack was negligible due to minimization of the intermembrane distances, and therefore the power densities produced by the MDC were similar to those produced by single chamber microbial fuel cells (MFCs) lacking desalination chambers. The observed current efficiency was 86%, indicating separation of 4.3 pairs of sodium and chloride ions for every electron transferred through the circuit. With two additional stages (total of 3.8 L of anolyte), desalination was increased to 98% salt removal, producing 0.3 L of fresh water (12.6:1). These results demonstrate that stacked MDCs can be used for efficient desalination of seawater while at the same time achieving power densities comparable to those obtained in MFCs.

  3. Series Assembly of Microbial Desalination Cells Containing Stacked Electrodialysis Cells for Partial or Complete Seawater Desalination

    KAUST Repository

    Kim, Younggy

    2011-07-01

    A microbial desalination cell (MDC) is a new approach for desalinating water based on using the electrical current generated by exoelectrogenic bacteria. Previously developed MDCs have used only one or two desalination chambers with substantial internal resistance, and used low salinity catholytes containing a buffered or acid solution. Here we show that substantially improved MDC performance can be obtained even with a nonbuffered, saline catholyte, by using an electrodialysis stack consisting of 5 pairs of desalting and concentrating cells. When 4 stacked MDCs were used in series (20 total pairs of desalination chambers), the salinity of 0.06 L of synthetic seawater (35 g/L NaCl) was reduced by 44% using 0.12 L of anode solution (2:1). The resistive loss in the electrodialysis stack was negligible due to minimization of the intermembrane distances, and therefore the power densities produced by the MDC were similar to those produced by single chamber microbial fuel cells (MFCs) lacking desalination chambers. The observed current efficiency was 86%, indicating separation of 4.3 pairs of sodium and chloride ions for every electron transferred through the circuit. With two additional stages (total of 3.8 L of anolyte), desalination was increased to 98% salt removal, producing 0.3 L of fresh water (12.6:1). These results demonstrate that stacked MDCs can be used for efficient desalination of seawater while at the same time achieving power densities comparable to those obtained in MFCs. © 2011 American Chemical Society.

  4. Role of Seawater Desalination in the Management of an Integrated Water and 100% Renewable Energy Based Power Sector in Saudi Arabia

    Directory of Open Access Journals (Sweden)

    Upeksha Caldera

    2017-12-01

    Full Text Available This work presents a pathway for Saudi Arabia to transition from the 2015 power structure to a 100% renewable energy-based system by 2050 and investigates the benefits of integrating the power sector with the growing desalination sector. Saudi Arabia can achieve 100% renewable energy power system by 2040 while meeting increasing water demand through seawater reverse osmosis (SWRO and multiple effect distillation (MED desalination plants. The dominating renewable energy sources are PV single-axis tracking and wind power plants with 243 GW and 83 GW, respectively. The levelised cost of electricity (LCOE of the 2040 system is 49 €/MWh and decreases to 41 €/MWh by 2050. Corresponding levelised cost of water (LCOW is found to be 0.8 €/m3 and 0.6 €/m3. PV single-axis tracking dominates the power sector. By 2050 solar PV accounts for 79% of total electricity generation. Battery storage accounts for 41% of total electricity demand. In the integrated scenario, due to flexibility provided by SWRO plants, there is a reduced demand for battery storage and power-to-gas (PtG plants as well as a reduction in curtailment. Thus, the annual levelised costs of the integrated scenario is found to be 1–3% less than the non-integrated scenario.

  5. Proposal of an Eco-Industrial Park based on the water desalination plant located inside the King Abdullah University of Science and Technology

    KAUST Repository

    Lopez Torres, Rodrigo

    2016-12-01

    This thesis project is a proposal of a scenario of an industrial collaboration that could become the basis for the development of an Eco-Industrial Park inside the King Abdullah University of Science and Technology using the water desalination plant as the foundation of this network. It is defined why the university is a suitable place for a development of this type; what industrial networks can be formed and what environmental, economic and social benefits could be achieved if the Kingdom of Saudi Arabia implemented this project around the country. An Eco-Industrial Park is a collaboration between industries where they share resources and create an exchange network of wastes and by-products with the objective of obtaining positive environmental, economic and social impacts. In the proposed scenario, the initial collaboration is between a PV solar plant and the water desalination located inside the university. With the use of solar energy there are savings of CO2 emissions, which turn into positive impacts on the environment. The idea is that this initial collaboration could be extended in the future to provide the entire energy consumption of the KAUST community. The project also provides an insight into how an industrial symbiosis could be formed taking as a base this industrial collaboration. However, further studies and analysis are required in order to provide more solid information regarding the development of an Eco-Industrial Park.

  6. Computational and experimental study of nanoporous membranes for water desalination and decontamination.

    Energy Technology Data Exchange (ETDEWEB)

    Hickner, Michael A. (Penn State University, University Park, PA); Chinn, Douglas Alan (Sandia National Laboratories, Albuquerque, NM); Adalsteinsson, Helgi; Long, Kevin R. (Texas Tech University, Lubbock, TX); Kent, Michael Stuart (Sandia National Laboratories, Albuquerque, NM); Debusschere, Bert J.; Zendejas, Frank J.; Tran, Huu M.; Najm, Habib N.; Simmons, Blake Alexander

    2008-11-01

    Fundamentals of ion transport in nanopores were studied through a joint experimental and computational effort. The study evaluated both nanoporous polymer membranes and track-etched nanoporous polycarbonate membranes. The track-etched membranes provide a geometrically well characterized platform, while the polymer membranes are more closely related to ion exchange systems currently deployed in RO and ED applications. The experimental effort explored transport properties of the different membrane materials. Poly(aniline) membranes showed that flux could be controlled by templating with molecules of defined size. Track-etched polycarbonate membranes were modified using oxygen plasma treatments, UV-ozone exposure, and UV-ozone with thermal grafting, providing an avenue to functionalized membranes, increased wettability, and improved surface characteristic lifetimes. The modeling effort resulted in a novel multiphysics multiscale simulation model for field-driven transport in nanopores. This model was applied to a parametric study of the effects of pore charge and field strength on ion transport and charge exclusion in a nanopore representative of a track-etched polycarbonate membrane. The goal of this research was to uncover the factors that control the flux of ions through a nanoporous material and to develop tools and capabilities for further studies. Continuation studies will build toward more specific applications, such as polymers with attached sulfonate groups, and complex modeling methods and geometries.

  7. Valorisation of Ca and Mg by-products from mining and seawater desalination brines for water treatment applications

    OpenAIRE

    Casas Garriga, Sandra; Aladjem, Carlos; Larrotcha, Enric; Gibert Agulló, Oriol; Valderrama Angel, César Alberto; Cortina Pallás, José Luís

    2014-01-01

    BACKGROUNDBrines from the drainage of potash mine tailings and from seawater reverse osmosis (SWRO) desalination were previously evaluated as sources of NaCl for the chlor-alkali industry. Valorisation of NaCl as raw material is required to meet the membrane electrolysis specifications of NaCl saturation and control of interferences (Ca, Mg and sulphate). Brines concentration in NaCl was previously achieved for SWRO brines using electrodialysis (ED). In this work, valorisation of Ca and Mg by...

  8. Comparison of commercial analytical techniques for measuring chlorine dioxide in urban desalinated drinking water.

    Science.gov (United States)

    Ammar, T A; Abid, K Y; El-Bindary, A A; El-Sonbati, A Z

    2015-12-01

    Most drinking water industries are closely examining options to maintain a certain level of disinfectant residual through the entire distribution system. Chlorine dioxide is one of the promising disinfectants that is usually used as a secondary disinfectant, whereas the selection of the proper monitoring analytical technique to ensure disinfection and regulatory compliance has been debated within the industry. This research endeavored to objectively compare the performance of commercially available analytical techniques used for chlorine dioxide measurements (namely, chronoamperometry, DPD (N,N-diethyl-p-phenylenediamine), Lissamine Green B (LGB WET) and amperometric titration), to determine the superior technique. The commonly available commercial analytical techniques were evaluated over a wide range of chlorine dioxide concentrations. In reference to pre-defined criteria, the superior analytical technique was determined. To discern the effectiveness of such superior technique, various factors, such as sample temperature, high ionic strength, and other interferences that might influence the performance were examined. Among the four techniques, chronoamperometry technique indicates a significant level of accuracy and precision. Furthermore, the various influencing factors studied did not diminish the technique's performance where it was fairly adequate in all matrices. This study is a step towards proper disinfection monitoring and it confidently assists engineers with chlorine dioxide disinfection system planning and management.

  9. DRINKING WATER FROM DESALINATION OF SEAWATER: OPTIMIZATION OF REVERSE OSMOSIS SYSTEM OPERATING PARAMETERS

    Directory of Open Access Journals (Sweden)

    MARWAN M. SHAMEL

    2006-12-01

    Full Text Available This paper reports on the use of pilot scale membrane separation system coupled with another pilot scale plate heat exchanger to investigate the possibilities of sweetening seawater from Telok Kalong Beach, Terengganu, Malaysia. Reverse osmosis (RO membrane of a surface area of 0.5 m2 was used during the experimental runs. Experiments were conducted at different transmembrane pressures (TMP ranged from 40 to 55 bars, operation temperature ranged from 35 to 45oC, feed concentration (TDS ranged from 34900 to 52500 ppm and cross flow velocities ranged from 1.4 to 2.1 m/s. The result show that the flux values increased linearly with TMP as well as sodium ion rejection. Permeate flux values increased proportionally with the temperature and the later effect was more significant at high pressures. The temperature changing has also influenced the rejection of sodium ion. The minerals content especially NaCl and total dissolved solid (TDS in the drinking water produced in this research are conforming to the standards of World Health Organization (WHO.

  10. Boron in reverse osmosis water desalination: current situational and applying technologies for its removal; El boro en las aguas desaladas por osmosis inversa: situacion actual y tecnologias aplicables para su eliminacion

    Energy Technology Data Exchange (ETDEWEB)

    Rodrigo Sanz, M.; Penate Suarez, B.

    2007-07-01

    In most of the seawater reverse osmosis desalination plants operating in one stage, the water produced presents values bordering or exceeding the limit established by the Spanish legislation for boron content of 1mg/l. As well as on the intrinsic features of the membrane elements, the boron removal in the desalination process depends on various factors. In this article the most relevant ones are described and a synopsis of the applied technologies and designs is introduced in order to fulfil current regulations. (Author)

  11. Implementation of the national desalination and water purification technology roadmap : structuring and directing the development of water supply solutions.

    Energy Technology Data Exchange (ETDEWEB)

    Price, Kevin M.; Dorsey, Zachary; Miller, G. Wade; Brady, Patrick Vane; Mulligan, Conrad; Rayburn, Chris

    2006-06-01

    In the United States, economic growth increasingly requires that greater volumes of freshwater be made available for new users, yet supplies of freshwater are already allocated to existing users. Currently, water for new users is made available through re-allocation of xisting water supplies-for example, by cities purchasing agricultural water rights. Water may also be made available through conservation efforts and, in some locales, through the development of ''new'' water from non-traditional sources such as the oceans, deep aquifer rackish groundwater, and water reuse.

  12. Performance of aeolian generators driven reverse osmosis under autonomous operation mode for brackish water desalination; Desempenho de instalacoes de osmose reversa acionadas por geradores eolicos em modo autonomo para dessalinizacao de agua salobra

    Energy Technology Data Exchange (ETDEWEB)

    Carvalho, Paulo; Freire, Cristiano [Ceara Univ., Fortaleza, CE (Brazil). Dept. de Engenharia Eletrica

    1999-07-01

    This work analyses the elements influencing the performance of brackish water desalination by aeolian generators driven reverse osmosis, operating under autonomous regime considering the recent experiences and new technologies. The aspects of reduction in energy consumption and operation with one energy source of variable character are considered.

  13. Thin Film Nanocomposite Membrane Filled with Metal-Organic Frameworks UiO-66 and MIL-125 Nanoparticles for Water Desalination.

    Science.gov (United States)

    Kadhom, Mohammed; Hu, Weiming; Deng, Baolin

    2017-06-14

    Knowing that the world is facing a shortage of fresh water, desalination, in its different forms including reverse osmosis, represents a practical approach to produce potable water from a saline source. In this report, two kinds of Metal-Organic Frameworks (MOFs) nanoparticles (NPs), UiO-66 (~100 nm) and MIL-125 (~100 nm), were embedded separately into thin-film composite membranes in different weight ratios, 0%, 0.05%, 0.1%, 0.15%, 0.2%, and 0.3%. The membranes were synthesized by the interfacial polymerization (IP) of m-phenylenediamine (MPD) in aqueous solution and trimesoyl chloride (TMC) in an organic phase. The as-prepared membranes were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), contact angle measurement, attenuated total reflection Fourier transform infrared (ATR FT-IR) spectroscopy, and salt rejection and water flux assessments. Results showed that both UiO-66 and MIL-125 could improve the membranes' performance and the impacts depended on the NPs loading. At the optimum NPs loadings, 0.15% for UiO-66 and 0.3% for MIL-125, the water flux increased from 62.5 L/m² h to 74.9 and 85.0 L/m² h, respectively. NaCl rejection was not significantly affected (UiO-66) or slightly improved (MIL-125) by embedding these NPs, always at >98.5% as tested at 2000 ppm salt concentration and 300 psi transmembrane pressure. The results from this study demonstrate that it is promising to apply MOFs NPs to enhance the TFC membrane performance for desalination.

  14. Thin Film Nanocomposite Membrane Filled with Metal-Organic Frameworks UiO-66 and MIL-125 Nanoparticles for Water Desalination

    Directory of Open Access Journals (Sweden)

    Mohammed Kadhom

    2017-06-01

    Full Text Available Knowing that the world is facing a shortage of fresh water, desalination, in its different forms including reverse osmosis, represents a practical approach to produce potable water from a saline source. In this report, two kinds of Metal-Organic Frameworks (MOFs nanoparticles (NPs, UiO-66 (~100 nm and MIL-125 (~100 nm, were embedded separately into thin-film composite membranes in different weight ratios, 0%, 0.05%, 0.1%, 0.15%, 0.2%, and 0.3%. The membranes were synthesized by the interfacial polymerization (IP of m-phenylenediamine (MPD in aqueous solution and trimesoyl chloride (TMC in an organic phase. The as-prepared membranes were characterized by scanning electron microscopy (SEM, transmission electron microscopy (TEM, contact angle measurement, attenuated total reflection Fourier transform infrared (ATR FT-IR spectroscopy, and salt rejection and water flux assessments. Results showed that both UiO-66 and MIL-125 could improve the membranes’ performance and the impacts depended on the NPs loading. At the optimum NPs loadings, 0.15% for UiO-66 and 0.3% for MIL-125, the water flux increased from 62.5 L/m2 h to 74.9 and 85.0 L/m2 h, respectively. NaCl rejection was not significantly affected (UiO-66 or slightly improved (MIL-125 by embedding these NPs, always at >98.5% as tested at 2000 ppm salt concentration and 300 psi transmembrane pressure. The results from this study demonstrate that it is promising to apply MOFs NPs to enhance the TFC membrane performance for desalination.

  15. Thin Film Nanocomposite Membrane Filled with Metal-Organic Frameworks UiO-66 and MIL-125 Nanoparticles for Water Desalination

    Science.gov (United States)

    Kadhom, Mohammed; Hu, Weiming; Deng, Baolin

    2017-01-01

    Knowing that the world is facing a shortage of fresh water, desalination, in its different forms including reverse osmosis, represents a practical approach to produce potable water from a saline source. In this report, two kinds of Metal-Organic Frameworks (MOFs) nanoparticles (NPs), UiO-66 (~100 nm) and MIL-125 (~100 nm), were embedded separately into thin-film composite membranes in different weight ratios, 0%, 0.05%, 0.1%, 0.15%, 0.2%, and 0.3%. The membranes were synthesized by the interfacial polymerization (IP) of m-phenylenediamine (MPD) in aqueous solution and trimesoyl chloride (TMC) in an organic phase. The as-prepared membranes were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), contact angle measurement, attenuated total reflection Fourier transform infrared (ATR FT-IR) spectroscopy, and salt rejection and water flux assessments. Results showed that both UiO-66 and MIL-125 could improve the membranes’ performance and the impacts depended on the NPs loading. At the optimum NPs loadings, 0.15% for UiO-66 and 0.3% for MIL-125, the water flux increased from 62.5 L/m2 h to 74.9 and 85.0 L/m2 h, respectively. NaCl rejection was not significantly affected (UiO-66) or slightly improved (MIL-125) by embedding these NPs, always at >98.5% as tested at 2000 ppm salt concentration and 300 psi transmembrane pressure. The results from this study demonstrate that it is promising to apply MOFs NPs to enhance the TFC membrane performance for desalination. PMID:28613247

  16. Use of geothermal energy for desalination in New Mexico: a feasibility study. Final report, January 1, 1977-May 30, 1979

    Energy Technology Data Exchange (ETDEWEB)

    Chaturvedi, L.; Keyes, C.G. Jr.; Swanberg, C.A.; Gupta, Y.F.; Davis, R.J.

    1979-06-01

    The water requirements and availability for New Mexico are described. The possibility of using geothermal resources for desalination of the state's saline water sources is discussed. The following aspects of the problem are covered: resource evaluation, geothermal desalination technology, potential geothermal desalination sites, saline and geothermal aquifer well fields design, geothermal desalination plant waste brine disposal, process water pumping and brine disposal unit costs, environmental considerations, and legal and institutional considerations. (MHR)

  17. Review of the desalinated water market in France for small units; Apercu sur le marche de l'eau dessalee en France pour de petites unites

    Energy Technology Data Exchange (ETDEWEB)

    Dutheil, F.; Malissen, M. [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1969-07-01

    On the initiative of and in close collaboration with the Commissariat a l'Energie Atomique, the Societe pour la Conversion et le Developpement Industriel (SODIC) has carried out a very general study of the coastal regions of France in which the short, medium and long-term prospects of the demand for water, and the cost of the necessary supplies, could possibly make desalination units of 3 000 to 10 000 m3/day competitive. So far this general enquiry, which went into detail on some particular aspects, has not revealed any very clear possibilities in this respect, except in the case of the small islands, and of units of much lower capacity, as well as that of large units on the coast, which would benefit from the size effect. However the probable difference between the cost of desalinated water and the high selling price already applying in a small number of coastal regions is relatively small. It might therefore be worthwhile and relatively inexpensive to install an experimental desalination unit in the near future. (author) [French] A l'initiative du Commissariat a l'Energie Atomique et en etroite liaison avec lui, la Societe pour la Conversion et le Developpement Industriel (SODIC) a effectue une etude tres generale des zones cotieres francaises dans lesquelles les perspectives de la demande d'eau a court, moyen et long terme et le cout des approvisionnements necessaires, pourraient eventuellement faire apparaitre comme competitives des unites de dessalement de 3 a 10 000 m{sup 3}/jour. Jusqu'ici, cette enquete generale, d'ailleurs approfondie sur quelques points particuliers, n'a pas fait apparaitre de possibilites tres nettes a cet egard. Le cas des petites iles, et pour des unites de bien plus faible capacite, demeure reserve ainsi que, sur les zones cotieres, celui de grandes unites qui beneficieraient de l'effet de taille. Toutefois, l'ecart probable entre le cout de l'eau dessalee et le prix de vente eleve

  18. Power surplus in an hybrid desalination plant

    Energy Technology Data Exchange (ETDEWEB)

    Ferreira, Eduardo Manfredini [Universidade Federal da Grande Dourados (UFGD), Dourados, MS (Brazil); Balestieri, Jose Antonio Perrela; Zanardi, Mauricio de Araujo [Universidade Estadual Paulista (UNESP), Guaratingueta, SP (Brazil)], Emails: perrela@feg.unesp.br, mzanardi@feg.unesp.br

    2010-07-01

    Desalination is a process to be considered in the water planning - its use is year by year worldwide and must be considered as an opportunity even for Brazil. Associated to the perspectives of implementing such technology, advances such as integrating energy generation systems to desalination processes in the so-called hybrid systems have been suggested to obtain a more efficient process. The power surplus generated by hybrid technologies is an interesting index to be considered in the context of produced fresh water. In this paper, several gas turbine systems were considered in a hybrid system; the power surplus of these configurations in a Brazilian case is presented and analyzed. (author)

  19. Low Energy Desalination Using Battery Electrode Deionization

    KAUST Repository

    Kim, Taeyoung

    2017-09-21

    New electrochemical technologies that use capacitive or battery electrodes are being developed to minimize energy requirements for desalinating brackish waters. When a pair of electrodes is charged in capacitive deionization (CDI) systems, cations bind to the cathode and anions bind to the anode, but high applied voltages (>1.2 V) result in parasitic reactions and irreversible electrode oxidation. In the battery electrode deionization (BDI) system developed here, two identical copper hexacyanoferrate (CuHCF) battery electrodes were used that release and bind cations, with anion separation occurring via an anion exchange membrane. The system used an applied voltage of 0.6 V, which avoided parasitic reactions, achieved high electrode desalination capacities (up to 100 mg-NaCl/g-electrode, 50 mM NaCl influent), and consumed less energy than CDI. Simultaneous production of desalinated and concentrated solutions in two channels avoided a two-cycle approach needed for CDI. Stacking additional membranes between CuHCF electrodes (up to three anion and two cation exchange membranes) reduced energy consumption to only 0.02 kWh/m3 (approximately an order of magnitude lower than values reported for CDI), for an influent desalination similar to CDI (25 mM decreased to 17 mM). These results show that BDI could be effective as a very low energy method for brackish water desalination.

  20. Conditions of competition between the production of water by desalination and natural resources; Les conditions de concurrence entre la production d'eau par dessalement et les ressources naturelles

    Energy Technology Data Exchange (ETDEWEB)

    Gaussens, J. [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1969-07-01

    A close examination of the local supply and demand for fresh water is involved when considering a sea water desalination plant in a given region. This examination makes it possible in most cases to undertake a thorough study of the natural resources, resulting in the use of desalination being rejected. After confirming this fact by precise examples, the authors consider that the preliminary study should be extended, taking into account the complementary character of natural resources and desalination systems: contribution to peak demand, contribution to base demand. This analysis results in a classification of the main user regions according to certain economic criteria defining their suitability for the use of desalination processes. (author) [French] Envisager une installation d'eau de mer dans une region donnee, entraine un examen attentif de l'offre et de la demande locale en eau douce. Cet examen permet de conduire dans la plupart des cas a une etude approfondie des ressources naturelles qui aboutit a ecarter le recours au dessalement. Apres avoir constate ce fait, par des exemples precis, les auteurs estiment que l'on doit pousser plus loin l'etude preliminaire en tenant compte de la complementarite entre les ressources naturelles et les systemes de dessalement: contribution a la demande de pointe, contribution a la demande de base. Cette analyse conduit a classer les regions utilisatrices essentielles selon certains criteres economiques definissant leur aptitude a l'utilisation des procedes de dessalement. (auteur)

  1. Environmental impact of seawater desalination plants.

    Science.gov (United States)

    Al-Mutaz, I S

    1991-01-01

    Enormous amounts of seawater are desalted everyday worldwide. The total world production of fresh water from the sea is about 2621 mgd (9.92 million m(3) day(-1) 1985 figures). Desalting processes are normally associated with the rejection of high concentration waste brine from the plant itself or from the pretreatment units as well as during the cleaning period. In thermal processes, mainly multistage flash (MSF) thermal pollution occurs. These pollutants increase the seawater temperature, salinity, water current and turbidity. They also harm the marine environment, causing fish to migrate while enhancing the presence of algae, nematods and tiny molluscus. Sometimes micro-elements and toxic materials appear in the discharged brine.This paper will discuss the impact of the effluents from the desalination plants on the seawater environment with particular reference to the Saudi desalination plants, since they account for about 50% of the world desalination capacity.

  2. Energy Implications of Seawater Desalination (Invited)

    Science.gov (United States)

    Cooley, H.; Heberger, M. G.

    2013-12-01

    Freshwater has traditionally come from rivers, lakes, streams, and groundwater aquifers. As demand increases and climate change alters the location and timing of water supply, these traditional sources are becoming unavailable, more difficult, or increasingly expensive to develop. As a result, many communities are switching to alternative sources of water. Interest in pursuing seawater desalination is high in many coastal communities. In California, for example, 17 plants are proposed for development along the California coast and two in Mexico. Water managers are pursing desalination because is a local supply that can help diversify the water supply portfolio. Additionally, it is a reliable supply, which can be especially valuable during a drought. But removing the salt from seawater is an energy-intensive process that consumes more energy per gallon than most other water supply and treatment options. These energy requirements are key factors that will impact the extent and success of desalination in California. Energy requirements for seawater desalination average about 4.0 kWh per cubic meter (m3) of water produced. By comparison, the least energy-intensive options of local sources of groundwater and surface water require 0 - 0.90 kWh per m3; wastewater reuse, depending on treatment levels, may require from 0.26 - 2.2 kWh per m3. Beyond the electricity required for the desalination facility itself, producing any new source of water, including through desalination, increases the amount of energy required to deliver and use the water produced as well as collect, treat, and dispose of the wastewater generated. Energy is the largest single variable cost for a desalination plant, varying from one-third to more than one-half the cost of produced water. Building a desalination plant may reduce a water utility's exposure to water reliability risks at the added expense of an increase in exposure to energy price risk. In dependent on hydropower, electricity prices tend to

  3. Solar powered desalination system using Fresnel lens

    Science.gov (United States)

    Sales, M. T. B. F.

    2016-11-01

    The Philippines is surrounded by coastal areas and these areas can be a potential source for potable water. This study aims to design and construct a solar powered desalination system using Fresnel lens. The experimental study was conducted using polluted salt water for the sample and desalination was carried out using the designed system. The desalination system was composed of the solar concentrator, solar still and the condenser system. The Fresnel lens was made of acrylic plastic and was an effective solar concentrator. Solar stills made of dark colored glass bottles were effective in absorbing the solar energy. The condenser system made of polybutylene and polystyrene were effective in condensing the vapor at ambient temperature. The shortest time of vaporization of the salt water was at 293 sec and the optimum angle of position of the lens was 36.42°. The amount of condensate collected was directly proportional to the amount of salt water in the solar still. The highest mean efficiency of the designed set-up was 34.82%. The water produced by the solar powered desalination system using Fresnel lens passed the standards set by WHO (World Health Organization) for drinking water.

  4. The economic feasibility of seawater desalination over the global scale: assessment of the production cost development and national water price until 2050

    Science.gov (United States)

    Gao, L.; Yoshikawa, S.; Iseri, Y.; Kanae, S.

    2016-12-01

    As many countries are suffering water scarcity due to the climate change and human activities, seawater desalination using reverse osmosis (SWRO) has shown to be a progressively promising countermeasure to satisfy the growing water demand. Therefore, the economic feasibility assessment of SWRO will be beneficial for the potential investors and policy-makers of government. In present study, it have proposed a systematic method to evaluate the economic feasibility of implementing SWRO in 140 counties and further estimated the potential future diffusion of SWRO over global scale by 2050. To the purpose, two models has been separately developed to simulate the production cost of SWRO and conventional water price, which are identified as the critical economic factors for feasibility evaluation of SWRO. These two models were firstly applied to historical validation in which proven to be able to well simulate both these two economic factors, and then were applied globally for future simulation over the period of 2015-2050 under three socioeconomic scenarios, i.e. SSP (Shared Socioeconomic Pathways) 1-3. Basin on the estimated production cost and water price, the economic feasibility of adopting SWRO coupling with its future potentialities were carefully evaluated. As a result, it indicated that SWRO was expected to be cost-effectively adopted in more countries by 2050, especially in these developing countries. The significant potential diffusion of SWRO in countries was mainly attributed to both the diminishing production cost and the increasing conventional water price as a result of income growth globally in three SSPs scenarios.

  5. Sustainable desalination using ocean thermocline energy

    KAUST Repository

    Ng, Kim Choon

    2017-09-22

    The conventional desalination processes are not only energy intensive but also environment un-friendly. They are operating far from thermodynamic limit, 10–12%, making them un-sustainable for future water supplies. An innovative desalination processes are required to meet future sustainable desalination goal and COP21 goal. In this paper, we proposed a multi-effect desalination system operated with ocean thermocline energy, thermal energy harnessed from seawater temperature gradient. It can exploit low temperature differential between surface hot water temperature and deep-sea cold-water temperature to produce fresh water. Detailed theoretical model was developed and simulation was conducted in FORTRAN using international mathematical and statistical library (IMSL). We presented four different cases with deep-sea cold water temperature varies from 5 to 13°C and MED stages varies from 3 to 6. It shows that the proposed cycle can achieve highest level of universal performance ratio, UPR = 158, achieving about 18.8% of the ideal limit. With the major energy input emanated from the renewable solar, the proposed cycle is truly a “green desalination” method of low global warming potential (GWP), best suited for tropical coastal shores having bathymetry depths up to 300m or more.

  6. Impact of socio-economic growth on desalination in the US.

    Science.gov (United States)

    Ziolkowska, Jadwiga R; Reyes, Reuben

    2016-02-01

    In 2013, around 1336 desalination plants in the United States (US) provided purified water mainly to municipalities, the industry sector and for power generation. In 2013 alone, ∼200 million m(3) of water were desalinated; the amount that could satisfy annual municipal water consumption of more than 1.5 million people in the US. Desalination has proven to be a reliable water supply source in many countries around the world, with the total global desalination capacity of ∼60 million m(3)/day in 2013. Desalination has been used to mitigate water scarcity and lessen the pressure on water resources. Currently, data and information about desalination are still limited, while extensive socio-economic analyses are missing. This paper presents an econometric model to fill this gap. It evaluates the impact of selected socio-economic variables on desalination development in the US in the time span 1970-2013. The results show that the GDP and population growth have significantly impacted the desalination sector over the analyzed time period. The insights into the economics of desalination provided with this paper can be used to further evaluate cost-effectiveness of desalination both in the US and in other countries around the world. Copyright © 2015 Elsevier Ltd. All rights reserved.

  7. Nanoporous Carbon Nitride: A High Efficient Filter for Seawater Desalination

    CERN Document Server

    Li, Weifeng; Zhou, Hongcai; Zhang, Xiaoming; Zhao, Mingwen

    2015-01-01

    The low efficiency of commercially-used reverse osmosis (RO) membranes has been the main obstacle in seawater desalination application. Here, we report the auspicious performance, through molecular dynamics simulations, of a seawater desalination filter based on the recently-synthesized graphene-like carbon nitride (g-C2N) [Nat. Commun., 2015, 6, 6486]. Taking advantage of the inherent nanopores and excellent mechanical properties of g-C2N filter, highly efficient seawater desalination can be achieved by modulating the nanopores under tensile strain. The water permeability can be improved by two orders of magnitude compared to RO membranes, which offers a promising approach to the global water shortage solution.

  8. Molecular Transporters for Desalination Applications

    Science.gov (United States)

    2014-08-02

    May-2009 17-Feb-2014 Approved for Public Release; Distribution Unlimited Molecular transporters for desalination applications The views, opinions and...12211 Research Triangle Park, NC 27709-2211 desalination biomimetric membranes activated chemical transport REPORT DOCUMENTATION PAGE 11. SPONSOR...ABSTRACT Molecular transporters for desalination applications Report Title The primary goal of the ‘Molecular Transporter’ program was to develop a precise

  9. Plant water status, ethylene evolution, N(2)-fixing efficiency, antioxidant activity and lipid peroxidation in Cicer arietinum L. nodules as affected by short-term salinization and desalinization.

    Science.gov (United States)

    Nandwal, Ajit Singh; Kukreja, Sarvjeet; Kumar, Neeraj; Sharma, Praveen Kumar; Jain, Monika; Mann, Anita; Singh, Sunder

    2007-09-01

    Salinity induced changes in ethylene evolution, antioxidant defense system, N(2)-fixing efficiency and membrane integrity in relation to water and mineral status in chickpea (Cicer arietinum L.) nodules were studied under screen house conditions. At vegetative stage (55-65 DAS) plants were exposed to single saline irrigation (Cl(-) dominated) of levels 0, 2.5, 5.0 and 10.0dSm(-1) and sampled after 3d. The other set of treated plants was desalinized by flooding and the plants were sampled after further 3d. Water potential (Psiw) of leaf and osmotic potential (Psis) of leaf and nodules significantly decreased from -0.44 to -0.56MPa and from -0.65 to -1.15MPa and from -0.75 to -1.77MPa, respectively upon salinization. RWC of leaf and nodules also reduced from 86.05% to 73.30% and 94.70% to 89.98%, respectively. The decline in Psis of nodules was due to accumulation of proline and total soluble sugar. In comparison to control, the increase in ethylene (C(2)H(4)) production was 35-108% higher and correspondingly increase in 1-aminocycloprane-1-carboxylic acid (ACC) content (37-126%) and ACC oxidase activity (31-118%) was also noticed. Similarly, marked increase in H(2)O(2) (25-139%) and thiobarbituric acid substances (TBRAS, 11-133%) contents was seen. N(2)-fixing efficiency i.e. N(2)-ase activity, leghemoglobin and N contents of nodules declined significantly after saline irrigation. The induction in specific activity of antioxidant enzymes was confirmed by the increase in activity of superoxide dismutase, peroxidase, ascorbate peroxidase, glutathione reductase and glutathione transferase, whereas reverse was true for catalase. These activated enzymes could not overcome the accumulation of H(2)O(2) in nodules. Ascorbic acid content also declined from 20 to 38%, whereas Na(+)/K(+) ratio and Cl(-) content were significantly enhanced. Upon desalinization, a partial recovery in all above metabolic processes and water relations parameters was noticed. It is suggested that

  10. Predicting the Specific Energy Consumption of Reverse Osmosis Desalination

    Directory of Open Access Journals (Sweden)

    Ashlynn S. Stillwell

    2016-12-01

    Full Text Available Desalination is often considered an approach for mitigating water stress. Despite the abundance of saline water worldwide, additional energy consumption and increased costs present barriers to widespread deployment of desalination as a municipal water supply. Specific energy consumption (SEC is a common measure of the energy use in desalination processes, and depends on many operational and water quality factors. We completed multiple linear regression and relative importance statistical analyses of factors affecting SEC using both small-scale meta-data and municipal-scale empirical data to predict the energy consumption of desalination. Statistically significant results show water quality and initial year of operations to be significant and important factors in estimating SEC, explaining over 80% of the variation in SEC. More recent initial year of operations, lower salinity raw water, and higher salinity product water accurately predict lower values of SEC. Economic analysis revealed a weak statistical relationship between SEC and cost of water production. Analysis of associated greenhouse gas (GHG emissions revealed important considerations of both electricity source and SEC in estimating the GHG-related sustainability of desalination. Results of our statistical analyses can aid decision-makers by predicting the SEC of desalination to a reasonable degree of accuracy with limited data.

  11. Desalination with carbon aerogel electrodes

    Energy Technology Data Exchange (ETDEWEB)

    Farmer, J.C.; Richardson, J.H.; Fix, D.V.

    1996-10-21

    An electrically regenerated electrosorption process known as carbon aerogel CDI was developed for continuously removing ionic impurities from aqueous streams. A salt solution flows in a channel formed by pairs of parallel carbon aerogel electrodes. Each electrode has a very high BET surface area and very low resistivity. After polarization, anions and cations are removed from electrolyte by the electric field and electrosorbed onto the carbon aerogel. The solution is thus separated into two streams, brine and water. Based on this, carbon aerogel CDI appears to be an energy-efficient alternative to evaporation, electrodialysis, and reverse osmosis. The energy required by this process is about QV/2, plus losses. Estimated energy requirement for sea water desalination is 18-27 Wh gal{sup -1}, depending on cell voltage and flow rate. The requirement for brackish water desalination is less, 1.2-2.5 Wh gal{sup -1} at 1600 ppM. This is assuming that stored electrical energy is reclaimed during regeneration.

  12. Nonlinear dynamics of capacitive charging and desalination by porous electrodes

    NARCIS (Netherlands)

    Biesheuvel, P.M.; Bazant, M.Z.

    2010-01-01

    The rapid and efficient exchange of ions between porous electrodes and aqueous solutions is important in many applications, such as electrical energy storage by supercapacitors, water desalination and purification by capacitive deionization, and capacitive extraction of renewable energy from a

  13. Technology development and application of solar energy in desalination: MEDRC contribution

    KAUST Repository

    Ghaffour, Noreddine

    2011-12-01

    Desalination has become one of the sources for water supply in several countries especially in the Middle East and North Africa region. There is a great potential to develop solar desalination technologies especially in this region where solar source is abundantly available. The success in implementing solar technologies in desalination at a commercial scale depends on the improvements to convert solar energy into electrical and/or thermal energies economically as desalination processes need these types of energies. Since desalination is energy intensive, the wider use of solar technologies in desalination will eventually increase the demand on these technologies, making it possible to go for mass production of photovoltaic (PV) cells, collectors and solar thermal power plants. This would ultimately lead to the reduction in the costs of these technologies. The energy consumed by desalination processes has been significantly reduced in the last decade meaning that, if solar technologies are to be used, less PV modules and area for collectors would be needed. The main aspects to be addressed to make solar desalination a viable option in remote location applications is to develop new materials or improve existing solar collectors and find the best combinations to couple the different desalination processes with appropriate solar collector. In the objective to promote solar desalination in MENA, the Middle East Desalination Research Center has concentrated on various aspects of solar desalination in the last twelve years by sponsoring 17 research projects on different technologies and Software packages development for coupling desalination and renewable energy systems to address the limitations of solar desalination and develop new desalination technologies and hybrid systems suitable for remote areas. A brief description of some of these projects is highlighted in this paper. The full details of all these projects are available the Centers website. © 2011 Elsevier

  14. A ten liter stacked microbial desalination cell packed with mixed ion-exchange resins for secondary effluent desalination.

    Science.gov (United States)

    Zuo, Kuichang; Cai, Jiaxiang; Liang, Shuai; Wu, Shijia; Zhang, Changyong; Liang, Peng; Huang, Xia

    2014-08-19

    The architecture and performance of microbial desalination cell (MDC) have been significantly improved in the past few years. However, the application of MDC is still limited in a scope of small-scale (milliliter) reactors and high-salinity-water desalination. In this study, a large-scale (>10 L) stacked MDC packed with mixed ion-exchange resins was fabricated and operated in the batch mode with a salt concentration of 0.5 g/L NaCl, a typical level of domestic wastewater. With circulation flow rate of 80 mL/min, the stacked resin-packed MDC (SR-MDC) achieved a desalination efficiency of 95.8% and a final effluent concentration of 0.02 g/L in 12 h, which is comparable with the effluent quality of reverse osmosis in terms of salinity. Moreover, the SR-MDC kept a stable desalination performance (>93%) when concentrate volume decreased from 2.4 to 0.1 L (diluate/concentrate volume ratio increased from 1:1 to 1:0.04), where only 0.875 L of nonfresh water was consumed to desalinate 1 L of saline water. In addition, the SR-MDC achieved a considerable desalination rate (95.4 mg/h), suggesting a promising application for secondary effluent desalination through deriving biochemical electricity from wastewater.

  15. Entropy Generation Analysis of Desalination Technologies

    Directory of Open Access Journals (Sweden)

    John H. Lienhard V

    2011-09-01

    Full Text Available Increasing global demand for fresh water is driving the development and implementation of a wide variety of seawater desalination technologies. Entropy generation analysis, and specifically, Second Law efficiency, is an important tool for illustrating the influence of irreversibilities within a system on the required energy input. When defining Second Law efficiency, the useful exergy output of the system must be properly defined. For desalination systems, this is the minimum least work of separation required to extract a unit of water from a feed stream of a given salinity. In order to evaluate the Second Law efficiency, entropy generation mechanisms present in a wide range of desalination processes are analyzed. In particular, entropy generated in the run down to equilibrium of discharge streams must be considered. Physical models are applied to estimate the magnitude of entropy generation by component and individual processes. These formulations are applied to calculate the total entropy generation in several desalination systems including multiple effect distillation, multistage flash, membrane distillation, mechanical vapor compression, reverse osmosis, and humidification-dehumidification. Within each technology, the relative importance of each source of entropy generation is discussed in order to determine which should be the target of entropy generation minimization. As given here, the correct application of Second Law efficiency shows which systems operate closest to the reversible limit and helps to indicate which systems have the greatest potential for improvement.

  16. Renewable energy-driven innovative energy-efficient desalination technologies

    KAUST Repository

    Ghaffour, Noreddine

    2014-04-13

    Globally, the Kingdom of Saudi Arabia (KSA) desalinates the largest capacity of seawater but through energy-intensive thermal processes such as multi-stage flash (MSF) distillation (>10 kW h per m3 of desalinated water, including electrical and thermal energies). In other regions where fossil energy is more expensive and not subsidized, seawater reverse osmosis (SWRO) is the most common desalination technology but it is still energy-intensive (3-4 kW h_e/m3). Both processes therefore lead to the emission of significant amounts of greenhouse gases (GHGs). Moreover, MSF and SWRO technologies are most often used for large desalination facilities serving urban centers with centralized water distribution systems and power grids. While renewable energy (RE) sources could be used to serve centralized systems in urban centers and thus provide an opportunity to make desalination greener, they are mostly used to serve rural communities off of the grid. In the KSA, solar and geothermal energy are of most relevance in terms of local conditions. Our group is focusing on developing new desalination processes, adsorption desalination (AD) and membrane distillation (MD), which can be driven by waste heat, geothermal or solar energy. A demonstration solar-powered AD facility has been constructed and a life cycle assessment showed that a specific energy consumption of <1.5 kW h_e/m3 is possible. An innovative hybrid approach has also been explored which would combine solar and geothermal energy using an alternating 12-h cycle to reduce the probability of depleting the heat source within the geothermal reservoir and provide the most effective use of RE without the need for energy storage. This paper highlights the use of RE for desalination in KSA with a focus on our group\\'s contribution in developing innovative low energy-driven desalination technologies. © 2014 Elsevier Ltd. All rights reserved.

  17. Solar-Powered Desalination: A Modelling and Experimental Study

    Science.gov (United States)

    Leblanc, Jimmy; Andrews, John

    2007-10-01

    Water shortage is becoming one of the major problems worldwide. As such, desalination technologies have been implemented to meet growing demands for fresh water. Among the desalination technologies, thermal desalination, including multi stage flash (MSF) and multi effect evaporation (MEE), is the current leading desalination process. Reverse osmosis (RO) is also being increasingly used. Despite technological improvements, thermal desalination and reverse osmosis continue to be intensive fossil-fuel consumers and contribute to increased levels of greenhouse gases. As energy costs rise, thermal desalination by solar energy and/or low cost waste heat is likely to become increasingly attractive. As part of a project investigating the productive use of saline land and the development of sustainable desalination systems, the feasibility of producing potable water from seawater or brackish water using desalination systems powered by renewable energy in the form of low-temperature solar-thermal sources has been studied. A salinity-gradient solar pond and an evacuated tube solar collector system have been used as heat sources. Solar ponds combine solar energy collection with long-term storage and can provide reliable thermal energy at temperature ranges from 50 to 90 °C. A visual basic computer model of the different multi-stage flash desalination processes coupled with a salinity-gradient solar pond was developed to determine which process is preferable in regards to performance and greenhouse impact. The governing mathematical equations are derived from mass balances, heat energy balances, and heat transfer characteristics. Using the results from the modelling, a small-scale solar-powered desalination system, capable of producing up to 500 litres of fresh water per day, was designed and manufactured. This single-stage flash system consists of two main units: the heat supply and storage system and the flash desalination unit. Two different condenser heat exchanger

  18. LCA of Drinking Water Supply

    DEFF Research Database (Denmark)

    Godskesen, Berit; Meron, Noa; Rygaard, Martin

    2017-01-01

    the potentials and reveal hotspots among the possible technologies and scenarios for water supplies of the future. LCA studies have been used to support decisions in the planning of urban water systems and some important findings include documentation of reduced environmental impact from desalination of brackish......Water supplies around the globe are growing complex and include more intense treatment methods than just decades ago. Now, desalination of seawater and wastewater reuse for both non-potable and potable water supply have become common practice in many places. LCA has been used to assess...... water over sea water, the significant impacts from changed drinking water quality and reduced environmental burden from wastewater reuse instead of desalination. Some of the main challenges in conducting LCAs of water supply systems are their complexity and diversity, requiring very large data...

  19. Capacity building strategies and policy for desalination using renewable energies in Algeria

    Energy Technology Data Exchange (ETDEWEB)

    Mahmoudi, Hacene; Abdellah, Ouagued [Laboratory of Water and Environment, Hassiba Ben Bouali University, Chlef, BP151 (Algeria); Ghaffour, Noreddine [Middle East Desalination Research Center, P.O. Box 21, P.C. 133, Muscat (Oman)

    2009-05-15

    The integration of renewable resources in desalination and water purification is becoming increasingly attractive. This is justified by the fact that areas of fresh water shortages have plenty of solar energy and these technologies have low operating and maintenance costs. In this paper, an overview of capacity building strategy and policy for desalination in Algeria is presented. Importance of training and education on renewable energies is also outlined. The contribution of the Middle East Desalination Research Center in capacity building and research and development in desalination in Algeria is also presented. (author)

  20. Future sustainable desalination using waste heat: kudos to thermodynamic synergy

    KAUST Repository

    Shahzad, Muhammad Wakil

    2015-12-02

    There has been a plethora of published literature on thermally-driven adsorption desalination (AD) cycles for seawater desalination due to their favorable environmentally friendly attributes, such as the ability to operate with low-temperature heat sources, from either the renewable or the exhaust gases, and having almost no major moving parts. We present an AD cycle for seawater desalination due to its unique ability to integrate higher water production yields with the existing desalination methods such as reverse osmosis (RO), multi-stage flashing (MSF) and multi-effect distillation (MED), etc. The hybrid cycles exploit the thermodynamic synergy between processes, leading to significant enhancement of the systems\\' performance ratio (PR). In this paper, we demonstrate experimentally the synergetic effect between the AD and MED cycles that results in quantum improvement in water production. The unique feature is in the internal latent heat recovery from the condenser unit of AD to the top-brine stage of MED, resulting in a combined, or simply termed as MEAD, cycle that requires no additional heat input other than the regeneration of an adsorbent. The batch-operated cycles are simple to implement and require low maintenance when compared with conventional desalination methods. Together, they offer a low energy and environmentally friendly desalination solution that addresses the major issues of the water-energy-environment nexus. © 2016 The Royal Society of Chemistry.

  1. Problems of pricing fresh water obtained from a sea water desalination plant; Problemes de tarification de l'eau douce obtenue a partir d'une installation de dessalement d'eau de mer

    Energy Technology Data Exchange (ETDEWEB)

    Gaussens, J. [Commissariat a l' Energie Atomique, (France). Centre d' Etudes Nucleaires

    1967-07-01

    Integrating a double-purpose desalination and electricity generating plant into a water supply system alters the conditions in which the other water and electricity sources are used, as the peak and the base load water and electricity demands have to be met at the least cost. This paper attempts to show how the problem of determining optimal water supply structures can be approached, in definite cases, but against a global economic back-ground. It becomes necessary to define the competition between classical resources and desalination plants, as these plants introduce into optimum studies new factors due to the peculiar shape of their production functions. These new factors (fixed and proportional costs structures, flow availabilities) are studied in relation to the production functions in various management cases (private monopoly, public monopoly). (author) [French] L'intervention d'une installation egalement productrice d'energie electrique dans l'alimentation en eau d'une zone modifie les conditions d'utilisation des autres ressources en eau et en electricite, compte tenu de la necessite d'assurer les pointes et la base des diagrammes de demande d'eau et d'electricite au moindre cout. Cet expose se propose de montrer comment on peut approcher le probleme de la determination des structures optimales d'approvisionnement en eau pour des cas precis, mais dans un cadre economique global, II devient en effet necessaire de situer la competition: ressources classiques/installation de dessalement; ces dernieres introduisent, dans les etudes d'optimum, des elements nouveaux dus a la forme particuliere de leurs fonctions de production. On etudie ces elements nouveaux (structures des couts fixes et des couts proportionnels, disponibilite des debits) en liaison avec les fonctions de production dans divers cas de gestion (monopole prive, monopole public). (auteur)

  2. Fundamental measure theory for the electric double layer : implications for blue-energy harvesting and water desalination

    NARCIS (Netherlands)

    Hartel, Andreas; Janssen, Mathijs; Samin, Sela; van Roij, Rene

    2015-01-01

    Capacitive mixing (CAPMIX) and capacitive deionization (CDI) are promising candidates for harvesting clean, renewable energy and for the energy efficient production of potable water, respectively. Both CAPMIX and CDI involve water-immersed porous carbon (supercapacitors) electrodes at voltages of

  3. Hybrid membrane system for desalination and wastewater treatment : Integrating forward osmosis and low pressure reverse osmosis

    NARCIS (Netherlands)

    Valladares Linares, R.

    2014-01-01

    Since more than 97% of the water in the world is seawater, desalination technologies have the potential to solve the fresh water crisis. The most used desalination technology nowadays is seawater reverse osmosis (SWRO), where a membrane is used as a physical barrier to separate the salts from the

  4. Offshore Desalination Using Wave Energy

    Directory of Open Access Journals (Sweden)

    Álvaro Serna

    2013-01-01

    Full Text Available This paper evaluates the design of an offshore desalination plant currently under preliminary development. The purpose is to test the feasibility of producing drinkable water using wave energy in out-of-sight installations, as an alternative for those locations where land use, civil engineering works, and/or environmental impact make a coast-based solution inadequate. After describing the components, a proposal for sizing them is studied, based on using buoy-measured data at the expected location and their mathematical models of the different sections of the plant. Finally, by using measured buoy data, the influence of sizing on the expected performance is studied for a specific location, and one of the designs is developed in detail.

  5. Produced Water Treatment Using the Switchable Polarity Solvent Forward Osmosis (SPS FO) Desalination Process: Preliminary Engineering Design Basis

    Energy Technology Data Exchange (ETDEWEB)

    Wendt, Daniel; Adhikari, Birendra; Orme, Christopher; Wilson, Aaron

    2016-05-01

    Switchable Polarity Solvent Forward Osmosis (SPS FO) is a semi-permeable membrane-based water treatment technology. INL is currently advancing SPS FO technology such that a prototype unit can be designed and demonstrated for the purification of produced water from oil and gas production operations. The SPS FO prototype unit will used the thermal energy in the produced water as a source of process heat, thereby reducing the external process energy demands. Treatment of the produced water stream will reduce the volume of saline wastewater requiring disposal via injection, an activity that is correlated with undesirable seismic events, as well as generate a purified product water stream with potential beneficial uses. This paper summarizes experimental data that has been collected in support of the SPS FO scale-up effort, and describes how this data will be used in the sizing of SPS FO process equipment. An estimate of produced water treatment costs using the SPS FO process is also provided.

  6. EXPERIMENTAL RESEARCH OF THE INFLUENCE OF VARIOUS TYPES OF SOLAR COLLECTORS FOR PERFORMANCE SOLAR DESALINATION PLANT

    Directory of Open Access Journals (Sweden)

    Rakhmatulin I.R.

    2014-04-01

    Full Text Available The article discusses the possibility of using renewable energy for water purification. Results of analysis of a preferred energy source for a water purification using installed in places where fresh water shortages and a lack of electrical energy. The possibility of desalination of salt water using solar energy for regions with temperate climate. Presented desalination plant working on energy vacuum solar collectors, principles of action developed by the desalination plant. The experimental results of a constructed distiller when working with vacuum glass tubes and vacuum tubes with copper core inside. Conclusions about the possibility of using solar collectors for water desalination, are tips and tricks to improve the performance of solar desalination plant.

  7. Ecotoxicological impact assessment of the brine discharges from a desalination plant in the marine waters of the Algerian west coast, using a multibiomarker approach in a limpet, Patella rustica.

    Science.gov (United States)

    Benaissa, Meriem; Rouane-Hacene, Omar; Boutiba, Zitouni; Guibbolini-Sabatier, Marielle E; Faverney, Christine Risso-De

    2017-11-01

    The aim of our study is to evaluate the impact of Bousfer desalination plant brine discharges on the Algerian west coast, on a natural population of the marine gastropod mollusc Patella rustica. The effects of a chronic exposure to such discharges are complex to understand due to the combined effects of environmental physico-chemical parameters (e.g., high salinity) and different pollutants that can modulate the physiological responses of this species to stress. In this context, we assessed the biological effects in a marine species P. rustica, by a multibiomarker approach that provided information on the health status of organisms in response to such an environmental stress. We measured biomarkers in the whole soft tissues of limpets as indicators of neurotoxicity (AChE activity), oxidative stress (CAT, SOD, GR, and GPx activities), biotransformation (GST), oxidative damage (LPO through TBARS levels), and genotoxicity (CSP 3-like activity). In parallel, hydrological parameters were measured in the Bay of Oran, at four selected sites: site H considered as a "hotspot," located at Bousfer desalination plant; two other sites E and W, at the east and the west of H respectively; finally, site R "reference" located in Madragh, which is considered as a remote clean site. Our analyses revealed that the activities of antioxidant defense enzymes reached the highest levels in P. rustica collected from site H. The activation of antioxidant defense system in these organisms translated the alteration of their status health, reflecting a level of environmental disruption generated by the desalination plant brine discharges and the high salinity in this area. We also observed that the tissues of limpets collected from site H as well as the two other sites, E and W, had undergone molecular damage, confirmed by the high levels of CSP 3-like activity. This damage resulted from chronic exposure to environmental conditions, potentially genotoxic, due to the desalination plant

  8. Desalination by biomimetic aquaporin membranes: Review of status and prospects

    DEFF Research Database (Denmark)

    Tang, C.Y.; Zhao, Y.; Wang, R.

    2013-01-01

    Based on their unique combination of offering high water permeability and high solute rejection aquaporin proteins have attracted considerable interest over the last years as functional building blocks of biomimetic membranes for water desalination and reuse. The purpose of this review is to prov......Based on their unique combination of offering high water permeability and high solute rejection aquaporin proteins have attracted considerable interest over the last years as functional building blocks of biomimetic membranes for water desalination and reuse. The purpose of this review......; including an overview of our own recent developments in aquaporin-based membranes. Finally we outline future prospects of aquaporin based biomimetic membrane for desalination and water reuse....

  9. Energy system impacts of desalination in Jordan

    Directory of Open Access Journals (Sweden)

    Poul Alberg Østergaard

    2014-02-01

    Full Text Available Climate change mitigation calls for energy systems minimising end-use demands, optimising the fuel efficiency of conversion systems, increasing the use of renewable energy sources and exploiting synergies wherever possible. In parallel, global fresh water resources are strained due to amongst others population and wealth increase and competitive water uses from agriculture and industry is causing many nations to turn to desalination technologies. This article investigates a Jordanian energy scenario with two different desalination technologies; reverse osmosis (RO driven by electricity and Multi Stage Flash (MSF desalination driven by Cogeneration of Heat and Power (CHP. The two systems impact the energy systems in different ways due to the technologies’ particular characteristics. The systems are analyses in the energy systems analysis model EnergyPLAN to determine the impacts on energy system performance. Results indicate that RO and MSF are similar in fuel use. While there is no use of waste heat from condensing mode plants, efficiencies for CHP and MSF are not sufficiently good to results in lower fuel usage than RO. The Jordanian energy system is somewhat inflexible giving cause to Critical Excess Electricity Production (CEEP even at relatively modest wind power penetrations. Here RO assists the energy system in decreasing CEEP – and even more if water storage is applied.

  10. Energy and Exergy Analyses of a New Combined Cycle for Producing Electricity and Desalinated Water Using Geothermal Energy

    Directory of Open Access Journals (Sweden)

    Mehri Akbari

    2014-04-01

    Full Text Available A new combined cogeneration system for producing electrical power and pure water is proposed and analyzed from the viewpoints of thermodynamics and economics. The system uses geothermal energy as a heat source and consists of a Kalina cycle, a LiBr/H2O heat transformer and a water purification system. A parametric study is carried out in order to investigate the effects on system performance of the turbine inlet pressure and the evaporator exit temperature. For the proposed system, the first and second law efficiencies are found to be in the ranges of 16%–18.2% and 61.9%–69.1%, respectively. For a geothermal water stream with a mass flow rate of 89 kg/s and a temperature of 124 °C, the maximum production rate for pure water is found to be 0.367 kg/s.

  11. An exergy approach to efficiency evaluation of desalination

    KAUST Repository

    Ng, Kim Choon

    2017-05-02

    This paper presents an evaluation process efficiency based on the consumption of primary energy for all types of practical desalination methods available hitherto. The conventional performance ratio has, thus far, been defined with respect to the consumption of derived energy, such as the electricity or steam, which are susceptible to the conversion losses of power plants and boilers that burned the input primary fuels. As derived energies are usually expressed by the units, either kWh or Joules, these units cannot differentiate the grade of energy supplied to the processes accurately. In this paper, the specific energy consumption is revisited for the efficacy of all large-scale desalination plants. In today\\'s combined production of electricity and desalinated water, accomplished with advanced cogeneration concept, the input exergy of fuels is utilized optimally and efficiently in a temperature cascaded manner. By discerning the exergy destruction successively in the turbines and desalination processes, the relative contribution of primary energy to the processes can be accurately apportioned to the input primary energy. Although efficiency is not a law of thermodynamics, however, a common platform for expressing the figures of merit explicit to the efficacy of desalination processes can be developed meaningfully that has the thermodynamic rigor up to the ideal or thermodynamic limit of seawater desalination for all scientists and engineers to aspire to.

  12. An exergy approach to efficiency evaluation of desalination

    Science.gov (United States)

    Ng, Kim Choon; Shahzad, Muhammad Wakil; Son, Hyuk Soo; Hamed, Osman A.

    2017-05-01

    This paper presents an evaluation process efficiency based on the consumption of primary energy for all types of practical desalination methods available hitherto. The conventional performance ratio has, thus far, been defined with respect to the consumption of derived energy, such as the electricity or steam, which are susceptible to the conversion losses of power plants and boilers that burned the input primary fuels. As derived energies are usually expressed by the units, either kWh or Joules, these units cannot differentiate the grade of energy supplied to the processes accurately. In this paper, the specific energy consumption is revisited for the efficacy of all large-scale desalination plants. In today's combined production of electricity and desalinated water, accomplished with advanced cogeneration concept, the input exergy of fuels is utilized optimally and efficiently in a temperature cascaded manner. By discerning the exergy destruction successively in the turbines and desalination processes, the relative contribution of primary energy to the processes can be accurately apportioned to the input primary energy. Although efficiency is not a law of thermodynamics, however, a common platform for expressing the figures of merit explicit to the efficacy of desalination processes can be developed meaningfully that has the thermodynamic rigor up to the ideal or thermodynamic limit of seawater desalination for all scientists and engineers to aspire to.

  13. Development of the microbial electrolysis desalination and chemical-production cell for desalination as well as acid and alkali productions.

    Science.gov (United States)

    Chen, Shanshan; Liu, Guangli; Zhang, Renduo; Qin, Bangyu; Luo, Yong

    2012-02-21

    By combining the microbial electrolysis cell and the microbial desalination cell, the microbial electrolysis desalination cell (MEDC) becomes a novel device to desalinate salty water. However, several factors, such as sharp pH decrease and Cl(-) accumulation in the anode chamber, limit the MEDC development. In this study, a microbial electrolysis desalination and chemical-production cell (MEDCC) was developed with four chambers using a bipolar membrane. Results showed that the pH in the anode chamber of the MEDCC always remained near 7.0, which greatly enhanced the microbial activities in the cell. With applied voltages of 0.3-1.0 V, 62%-97% of Coulombic efficiencies were achieved from the MEDCC, which were 1.5-2.0 times of those from the MEDC. With 10 mL of 10 g/L NaCl in the desalination chamber, desalination rates of the MEDCC reached 46%-86% within 18 h. Another unique feature of the MEDCC was the simultaneous production of HCl and NaOH in the cell. With 1.0 V applied voltage, the pH values at 18 h in the acid-production chamber and cathode chamber were 0.68 and 12.9, respectively. With the MEDCC, the problem with large pH changes in the anode chamber was resolved, and products of the acid and alkali were obtained.

  14. Saline Groundwater from Coastal Aquifers As a Source for Desalination.

    Science.gov (United States)

    Stein, Shaked; Russak, Amos; Sivan, Orit; Yechieli, Yoseph; Rahav, Eyal; Oren, Yoram; Kasher, Roni

    2016-02-16

    Reverse osmosis (RO) seawater desalination is currently a widespread means of closing the gap between supply and demand for potable water in arid regions. Currently, one of the main setbacks of RO operation is fouling, which hinders membrane performance and induces pressure loss, thereby reducing system efficiency. An alternative water source is saline groundwater with salinity close to seawater, pumped from beach wells in coastal aquifers which penetrate beneath the freshwater-seawater interface. In this research, we studied the potential use of saline groundwater of the coastal aquifer as feedwater for desalination in comparison to seawater using fieldwork and laboratory approaches. The chemistry, microbiology and physical properties of saline groundwater were characterized and compared with seawater. Additionally, reverse osmosis desalination experiments in a cross-flow system were performed, evaluating the permeate flux, salt rejection and fouling propensities of the different water types. Our results indicated that saline groundwater was significantly favored over seawater as a feed source in terms of chemical composition, microorganism content, silt density, and fouling potential, and exhibited better desalination performance with less flux decline. Saline groundwater may be a better water source for desalination by RO due to lower fouling potential, and reduced pretreatment costs.

  15. Desalination with carbon aerogel electrodes. Revision 1

    Energy Technology Data Exchange (ETDEWEB)

    Farmer, J.C.; Richardson, J.H.; Fix, D.V. [Lawrence Livermore National Lab., CA (United States); Thomson, S.L.; May, S.C. [Bechtel National, Inc., San Francisco, CA (United States)

    1996-12-04

    Electrically regenerated electrosorption process (carbon aerogel CDI) was developed by LLNL for continuously removing ionic impurities from aqueous streams. A salt solution flows in a channel formed by numerous pairs of parallel carbon aerogel electrodes. Each electrode has a very high BET surface area (2-5.4x10{sup 6}ft{sup 2}lb{sup -1} or 400-1100 m{sup 2}g{sup -1}) and very low electrical resistivity ({le}40 m{Omega}). Ions are removed from the electrolyte by the electric field and electrosorbed onto the carbon aerogel. It is concluded that carbon aerogel CDI may be an energy-efficient alternative to electrodialysis and reverse osmosis for desalination of brackish water ({le}5000 ppM). The intrinsic energy required by this process is about QV/2, where Q is the stored electrical charge and V is the voltage between the electrodes, plus losses. Estimated requirement for desalination of a 2000 ppM feed is -0.53-2.5 Wh/gal{sup -1} (0.5-2.4 kJ L{sup -1}), depending on voltage, flow rate, cell dimensions, aerogel density, recovery ratio, etc. This assumes that 50-70% of the stored electrical energy is reclaimed during regeneration (electrical discharge). Though the energy requirement for desalination of sea water is also low, this application will be much more difficult. Additional work will be required for desalination of streams that contain more than 5000 ppM total dissolved solids (2000 ppM will require electrochemical cells with extremely tight, demanding tolerances). At this present time, the process is best suited for streams with dilute impurities, as recently demonstrated during a field test at LLNL Treatment Facility C.

  16. Concurrent desalination and hydrogen generation using microbial electrolysis and desalination cells.

    Science.gov (United States)

    Luo, Haiping; Jenkins, Peter E; Ren, Zhiyong

    2011-01-01

    The versatility of bioelectrochemical systems (BESs) makes them promising for various applications, and good combinations could make the system more applicable and economically effective. An integrated BES called microbial electrolysis and desalination cell (MEDC) was developed to concurrently desalinate salt water, produce hydrogen gas, and potentially treat wastewater. The reactor is divided into three chambers by inserting a pair of ion exchange membranes, with each chamber serving one of the three functions. With an added voltage of 0.8 V, lab scale batch study shows the MEDC achieved the highest H(2) production rate of 1.5 m(3)/m(3) d (1.6 mL/h) from the cathode chamber, while also removing 98.8% of the 10 g/L NaCl from the middle chamber. The anode recirculation alleviated pH and high salinity inhibition on bacterial activity and further increased system current density from 87.2 to 140 A/m(3), leading to an improved desalination rate by 80% and H(2) production by 30%. Compared to slight changes in desalination, H(2) production was more significantly affected by the applied voltage and cathode buffer capacity, suggesting cathode reactions were likely affected by the external power supply in addition to the anode microbial activity.

  17. A detailed study of desalination exergy models and their application to a semi-conductor ultra-pure water plant

    OpenAIRE

    Fitzsimons, Lorna

    2011-01-01

    Ultra-Pure Water (UPW) is a high energy raw material used in the semiconductor manufacturing industry. However, to date, the production of UPW has received little focus in terms of energy consumption mitigation. Exergy analysis is perhaps the most powerful tool available in the search for industrial energy efficiency. The objective of this research was to develop an approach for the exergy analysis of Semiconductor UPW plants in an effort to characterise energy consumption. However, following...

  18. Y-12 National Security Complex Water Assessment

    Energy Technology Data Exchange (ETDEWEB)

    Elam, Shana E.; Bassett, P.; McMordie Stoughton, Kate

    2010-11-01

    The Department of Energy's Federal Energy Management Program (FEMP) sponsored a water assessment at the Y 12 National Security Complex (Y 12) located in Oak Ridge, Tennessee. Driven by mandated water reduction goals of Executive Orders 13423 and 13514, the objective of the water assessment is to develop a comprehensive understanding of the current water-consuming applications and equipment at Y 12 and to identify key areas for water efficiency improvements that could be applied not only at Y-12 but at other Federal facilities as well. FEMP selected Pacific Northwest National Laboratory to coordinate and manage the water assessment. PNNL contracted Water Savers, LLC to lead the technical aspects of the water assessment. Water Savers provided key technical expertise in water auditing, metering, and cooling systems. This is the report of that effort, which concluded that the Y-12 facility could realize considerable water savings by implementing the recommended water efficiency opportunities.

  19. Feasibilty study of renewable energy powered seawater desalination technology using natural vacuum technique

    Energy Technology Data Exchange (ETDEWEB)

    Ayhan, Teoman; Al Madani, Hussain [Mechanical Engineering Department, College of Engineering, University of Bahrain, P.O. box 32038, Isatown 32036 (Bahrain)

    2010-02-15

    With an ever-increasing population and rapid growth of industrialization, there is great demand for fresh water. Desalination has been a key proponent to meet the future challenges due to decreasing availability of fresh water. However, desalination uses significant amount of energy, today mostly from fossil fuels. It is, therefore, reasonable to rely on renewable energy sources such as solar energy, wind energy, ocean thermal energy, waste heat from the industry and other renewable sources. The present study deals with the energy-efficient seawater desalination system utilizing renewable energy sources and natural vacuum technique. A new desalination technology named Natural Vacuum Desalination is proposed. The novel desalination technique achieve remarkable energy efficiency through the evaporation of seawater under vacuum and will be described in sufficient detail to demonstrate that it requires much less electric energy compared to any conventional desalination plant of fresh water production of similar capacity. The discussion will highlight the main operative and maintenance features of the proposed natural vacuum seawater desalination technology which seems to have promising techno-economic potential providing also advantageous coupling with renewable energy sources. (author)

  20. LT-MED process for cogeneration and sea water desalination. El proceso LT-MED para cogeneracion y desalinizacion de Agua de mar

    Energy Technology Data Exchange (ETDEWEB)

    Ophir, A.; Gendel, A.; Kronenberg, G.

    1994-01-01

    The desalination plants at low temperature, with maximum temperatures of brine until 70 degree centigree , have low level of corrosion and fouling, the principal problem in conventional plants of high temperature distillation. More them 250 plants were developed by IDE Technologies Ltd. in the world. The first in Spain was in 1967. The plants use surface condensers of horizontal tubes and drown films in Vapor compression (LT-VC) and multi-effect distillation (LT-MED)

  1. Synergies of solar energy use in the desalination of seawater: A case study in northern Chile

    Science.gov (United States)

    Servert, Jorge F.; Cerrajero, Eduardo; Fuentealba, Edward L.

    2016-05-01

    The mining industry is a great consumer of water for hydrometallurgical processes. Despite the efforts in minimizing the use of fresh water through reuse, recycling and process intensification, water demand for mining is expected to rise a 40% from 2013 to 2020. For seawater to be an alternative to groundwater, it must be pumped up to the mine (thousands of meters uphill) and desalinated. These processes require intensive energy and investment in desalination and piping/pumping facilities. A conventional solution for this process would be desalination by reverse osmosis at sea level, powered by electricity from the grid, and further pumping of the desalinated water uphill. This paper compares the feasibility of two solar technologies versus the "conventional" option. LCOW (Levelized Cost of Water) was used as a comparative indicator among the studied solutions, with values for a lifetime of 10, 15, 20 and 25 years, calculated using a real discount rate equal to 12%. The LCOW is lower in all cases for the RO + grid solution. The cost of desalination, ignoring the contribution of pumping, is similar for the three technologies from twenty years of operation. The use of solar energy to desalinate sea water for consumption in the mines of the Atacama region is technically feasible. However, due to the extra costs from pumping whole seawater, and not just the desalinated water, solar solutions are less competitive than the conventional process.

  2. Economical analysis and study on a solar desalination unit

    DEFF Research Database (Denmark)

    Based on the calculation of the single-factor impact values of the parameters of a triple tower-type solar desalination unit on the cost of fresh water production by utilizing a single-factor analyzing method, the influences of the cost of solar heating system, the cost of hot water tank, the cos...

  3. Membrane-based seawater desalination: Present and future prospects

    KAUST Repository

    Amy, Gary L.

    2016-10-20

    Given increasing regional water scarcity and that almost half of the world\\'s population lives within 100 km of an ocean, seawater represents a virtually infinite water resource. However, its exploitation is presently limited by the significant specific energy consumption (kWh/m) required by conventional desalination technologies, further exasperated by high unit costs ($/m) and environmental impacts including GHG emissions (g CO-eq/m), organism impingement/entrainment through intakes, and brine disposal through outfalls. This paper explores the state-of-the-art in present seawater desalination practice, emphasizing membrane-based technologies, while identifying future opportunities in step improvements to conventional technologies and development of emerging, potentially disruptive, technologies through advances in material science, process engineering, and system integration. In this paper, seawater reverse osmosis (RO) serves as the baseline conventional technology. The discussion extends beyond desalting processes into membrane-based salinity gradient energy production processes, which can provide an energy offset to desalination process energy requirements. The future membrane landscape in membrane-based desalination and salinity gradient energy is projected to include ultrahigh permeability RO membranes, renewable-energy driven desalination, and emerging processes including closed-circuit RO, membrane distillation, forward osmosis, pressure retarded osmosis, and reverse electrodialysis according various niche applications and/or hybrids, operating separately or in conjunction with RO.

  4. Marine monitoring surveys for desalination plants-A critical review

    KAUST Repository

    Lattemann, Sabine

    2013-01-01

    Environmental impact assessment (EIA) studies are standard practice and a regulatory requirement for most new desalination projects today. However, most of the EIA studies are limited to predictive information; that is, they gather information on the project and the project\\'s environment before project implementation to make predictions about likely impacts. The EIAs may involve comprehensive studies, such as field monitoring, laboratory toxicity testing, and modeling studies. Consequently, the"surprising paucity of useful experimental data, either from laboratory tests or from field monitoring studies", which was observed by the US National Research Council in 2008, has been gradually decreasing. However, there is still a long-term research need on the site-specific effects of desalination plants after project commissioning has taken place. A main challenge of field research is the adequate design of the monitoring studies, which have to adequately distinguish the effects of the desalination project from natural processes over long periods of time. The existing monitoring studies have so far used a wide range of approaches and methods to investigate the environmental impacts of desalination plant discharges. Shortfalls are often that they are limited in scope, short-term, or localized. In essence, many studies fall short of recognizing the potentially synergetic effects of the single waste components of the discharges on marine organisms and the complexity of the potential responses by the ecosystem. While the possible risk of damage arising from the concentrate discharge to the marine environment in close proximity to the outfall is at hand, no conclusive evidence can yet be provided concerning the long-term impacts of desalination plant discharges, let alone the cumulative impacts on certain sea areas. This paper conducts a critical review of existing monitoring programs for desalination plants. Shortcomings of current practices are identified and relevant

  5. Reasons for the Fast Growing Seawater Desalination Capacity in Algeria

    KAUST Repository

    Drouiche, Nadjib

    2011-05-24

    Seawater/brackish water desalination has been widely adopted by the Algerian Government in the last few years to supply potable water to municipality for various purposes mainly for domestic and industrial uses especially in areas where demand is high due to shortage of fresh water resources, rapid population growth and development of industry and tourism. Ten years ago, desalination was confined to the industrial use only especially in oil and gas industry as the country was relying on rain water and other available sources to supply fresh water to municipalities. Due to chronic drought conditions, the Ministry of Water Resources reviewed the national water strategy and a strong option for desalination was adopted where an ambitious program was thus put into action. Sixteen mega-plants, with capacities ranging from 100,000 to 500,000 m3 per day, primarily based on Reverse Osmosis technology, were launched in the last few years making the Algerian desalination program one of the world\\'s fastest growing markets. Five desalination plants, including the Africa\\'s largest seawater reverse osmosis project with a total capacity of 200,000 m3 per day, are already in operation and the remaining projects are either under construction or in commissioning. An integrated water resources management was also adopted as additional option to cuter the increasing water demand as there is also a great potential for water reuse and conventional water treatment. An additional benefit of this would be reducing the volume of treated wastewater disposed into the environment. © 2011 Springer Science+Business Media B.V.

  6. Multi effect desalination and adsorption desalination (MEDAD): A hybrid desalination method

    KAUST Repository

    Shahzad, Muhammad Wakil

    2014-11-01

    This paper presents an advanced desalination cycle that hybridizes a conventional multi-effect distillation (MED) and an emerging yet low-energy adsorption cycle (AD). The hybridization of these cycles, known as MED + AD or MEDAD in short, extends the limited temperature range of the MED, typically from 65 °C at top-brine temperature (TBT) to a low-brine temperature (LBT) of 40 °C to a lower LBT of 5 °C, whilst the TBT remains the same. The integration of cycles is achieved by having vapor uptake by the adsorbent in AD cycle, extracting from the vapor emanating from last effect of MED. By increasing the range of temperature difference (DT) of a MEDAD, its design can accommodate additional condensation-evaporation stages that capitalize further the energy transfer potential of expanding steam. Numerical model for the proposed MEDAD cycle is presented and compared with the water production rates of conventional and hybridized MEDs. The improved MEDAD design permits the latter stages of MED to operate below the ambient temperature, scavenging heat from the ambient air. The increase recovery of water from the seawater feed may lead to higher solution concentration within the latter stages, but the lower saturation temperatures of these stages mitigate the scaling and fouling effects. © 2014 Elsevier Ltd. All rights reserved.

  7. Solar membrane distillation: desalination for the Navajo Nation.

    Science.gov (United States)

    Karanikola, Vasiliki; Corral, Andrea F; Mette, Patrick; Jiang, Hua; Arnoldand, Robert G; Ela, Wendell P

    2014-01-01

    Provision of clean water is among the most serious, long-term challenges in the world. To an ever increasing degree, sustainable water supply depends on the utilization of water of impaired initial quality. This is particularly true in developing nations and in water-stressed areas such as the American Southwest. One clear example is the Navajo Nation. The reservation covers 27,000 square miles, mainly in northeastern Arizona. Low population density coupled with water scarcity and impairment makes provision of clean water particularly challenging. The Navajos rely primarily on ground water, which is often present in deep aquifers or of brackish quality. Commonly, reverse osmosis (RO) is chosen to desalinate brackish ground water, since RO costs are competitive with those of thermal desalination, even for seawater applications. However, both conventional thermal distillation and RO are energy intensive, complex processes that discourage decentralized or rural implementation. In addition, both technologies demand technical experience for operation and maintenance, and are susceptible to scaling and fouling unless extensive feed pretreatment is employed. Membrane distillation (MD), driven by vapor pressure gradients, can potentially overcome many of these drawbacks. MD can operate using low-grade, sub-boiling sources of heat and does not require extensive operational experience. This presentation discusses a project on the Navajo Nation, Arizona (Native American tribal lands) that is designed to investigate and deploy an autonomous (off-grid) system to pump and treat brackish groundwater using solar energy. Βench-scale, hollow fiber MD experiment results showed permeate water fluxes from 21 L/m2·d can be achieved with transmembrane temperature differences between 40 and 80˚C. Tests run with various feed salt concentrations indicate that the permeate flux decreases only about 25% as the concentration increases from 0 to 14% (w/w), which is four times seawater salt

  8. Characterization of saline groundwater across the coastal aquifer of Israel as resource for desalination

    Science.gov (United States)

    Stein, Shaked; Russak, Amos; Sivan, Orit; Yechieli, Yospeh; Oren, Yoram; Kasher, Roni

    2015-04-01

    In arid countries with access to marine water seawater desalination is becoming an important water source in order to deal with the water scarcity and population growth. Seawater reverse osmosis (RO) facilities use open seawater intake, which requires pretreatment processes to remove particles in order to avoid fouling of the RO membrane. In small and medium size desalination facilities, an alternative water source can be saline groundwater in coastal aquifers. Using saline groundwater from boreholes near the shore as feed water may have the advantage of natural filtration and low organic content. It will also reduce operation costs of pretreatment. Another advantage of using groundwater is its availability in highly populated areas, where planning of large RO desalination plants is difficult and expensive due to real-estate prices. Pumping saline groundwater underneath the freshwater-seawater interface (FSI) might shift the interface towards the sea, thus rehabilitating the fresh water reservoirs in the aquifer. In this research, we tested the potential use of saline groundwater in the coastal aquifer of Israel as feed water for desalination using field work and desalination experiments. Specifically, we sampled the groundwater from a pumping well 100 m from the shore of Tel-Aviv and sea water from the desalination plant in Ashqelon, Israel. We used an RO cross flow system in a pilot plant in order to compare between the two water types in terms of permeate flux, permeate flux decline, salt rejection of the membrane and the fouling on the membrane. The feed, brine and fresh desalinated water from the outlet of the desalination system were chemically analyzed and compared. Field measurements of dissolved oxygen, temperature, pH and salinity were also conducted in situ. Additionally, SDI (silt density index), which is an important index for desalination, and total organic carbon that has a key role in organic fouling and development of biofouling, were measured and

  9. Efficiency improvement of seawater desalination processes: the case of the W.E.B. Aruba N.V. on the island of Aruba

    OpenAIRE

    Marchena, F.A.

    2013-01-01

    Seawater desalination is known worldwide as the most important source for the production of drinking water in arid areas where there are practically no natural water resources and consequently insufficient surface water or groundwater. However the desalination technology still remains a very costly process despite the many innovations it went through since its introduction to reduce water production cost. The island of Aruba has earned worldwide throughout its desalination history since 1932 ...

  10. Integrated processes for desalination and salt production: A mini-review

    Science.gov (United States)

    Wenten, I. Gede; Ariono, Danu; Purwasasmita, Mubiar; Khoirudin

    2017-03-01

    The scarcity of fresh water due to the rapid growth of population and industrial activities has increased attention on desalination process as an alternative freshwater supply. In desalination process, a large volume of saline water is treated to produce freshwater while a concentrated brine is discharged back into the environment. The concentrated brine contains a high concentration of salt and also chemicals used during desalination operations. Due to environmental impacts arising from improper treatment of the brine and more rigorous regulations of the pollution control, many efforts have been devoted to minimize, treat, or reuse the rejected brine. One of the most promising alternatives for brine handling is reusing the brine which can reduce pollution, minimize waste volume, and recover valuable salt. Integration of desalination and salt production can be implemented to reuse the brine by recovering water and the valuable salts. The integrated processes can achieve zero liquid discharge, increase water recovery, and produce the profitable salt which can reduce the overall desalination cost. This paper gives an overview of desalination processes and the brine impacts. The integrated processes, including their progress and advantages in dual-purpose desalination and salt production are discussed.

  11. Energy-positive wastewater treatment and desalination in an integrated microbial desalination cell (MDC)-microbial electrolysis cell (MEC)

    Science.gov (United States)

    Li, Yan; Styczynski, Jordyn; Huang, Yuankai; Xu, Zhiheng; McCutcheon, Jeffrey; Li, Baikun

    2017-07-01

    Simultaneous removal of nitrogen in municipal wastewater, metal in industrial wastewater and saline in seawater was achieved in an integrated microbial desalination cell-microbial electrolysis cell (MDC-MEC) system. Batch tests showed that more than 95.1% of nitrogen was oxidized by nitrification in the cathode of MDC and reduced by heterotrophic denitrification in the anode of MDC within 48 h, leading to the total nitrogen removal rate of 4.07 mg L-1 h-1. Combining of nitrogen removal and desalination in MDC effectively solved the problem of pH fluctuation in anode and cathode, and led to 63.7% of desalination. Power generation of MDC (293.7 mW m-2) was 2.9 times higher than the one without salt solution. The electric power of MDC was harvested by a capacitor circuit to supply metal reduction in a MEC, and 99.5% of lead (II) was removed within 48 h. A kinetic MDC model was developed to elucidate the correlation of voltage output and desalination efficiency. Ratio of wastewater and sea water was calculated for MDC optimal operation. Energy balance of nutrient removal, metal removal and desalination in the MDC-MEC system was positive (0.0267 kW h m-3), demonstrating the promise of utilizing low power output of MDCs.

  12. Modeling of electrokinetic desalination of bricks

    DEFF Research Database (Denmark)

    Paz-Garcia, Juan Manuel; Johannesson, Björn; Ottosen, Lisbeth M.

    2012-01-01

    A model for the reactive transport of matter through porous media induced by an externally applied electric field is discussed. The Nernst–Planck–Poisson system of equations is used for modeling multi-species electro-diffusion transport phenomena, assuming chemical equilibrium during the process....... The system of equations includes the transport of water and the resulting advective flow of the aqueous species. The model takes into account transient change in porosity and its impact on transport. Test examples were performed and compared to experimental data for electrokinetic desalination treatment...

  13. Overview of village scale, renewable energy powered desalination

    Energy Technology Data Exchange (ETDEWEB)

    Thomas, K.E.

    1997-04-01

    An overview of desalination technologies is presented, focusing on those technologies appropriate for use in remote villages, and how they can be powered using renewable energy. Technologies are compared on the basis of capital cost, lifecycle cost, operations and maintenance complexity, and energy requirements. Conclusions on the appropriateness of different technologies are drawn, and recommendations for future research are given.

  14. Solar desalination of seawater using double-dye-modified PTFE membrane.

    Science.gov (United States)

    Fujiwara, Masahiro; Kikuchi, Masaki

    2017-12-15

    The production of purified water by seawater desalination is now a significant countermeasure against recent severe water shortage. As the global warming is thought to be a dominant cause of the water scarcity problem, the energy employed for the desalination should be free from fossil fuels. We recently reported a simple membrane desalination combining the harvesting of solar energy and the membrane permeation of vaporized water. Water on a PTFE (polytetrafluoroethylene) membrane modified with disperse red 1 (DR1) as an azobenzene dye that photo-isomerizes with visible light permeates through it under visible light irradiation. The penetrated water was efficiently desalinated to produce purified water by membrane distillation mechanism, where water was evaporated by DR1 using solar energy. In this paper, we report that the aqueous solution of rhodamine B on non modified PTFE membrane permeated the membrane to be purified under visible light irradiation. This paper also reports that a PTFE membrane modified with disperse blue 14 (DB14) was active for the desalination. Thus, even these non-azobenzene dyes were revealed to be available for the light induce water permeation. When DR1 and DB14 were modified to PTFE membrane concurrently, a higher performance of seawater desalination using simulated sunlight was achieved by efficient absorption of the irradiated light with DR1 and DB14. Copyright © 2017 Elsevier Ltd. All rights reserved.

  15. Forward osmosis niches in seawater desalination and wastewater reuse

    KAUST Repository

    Valladares Linares, Rodrigo

    2014-12-01

    This review focuses on the present status of forward osmosis (FO) niches in two main areas: seawater desalination and wastewater reuse. Specific applications for desalination and impaired-quality water treatment and reuse are described, as well as the benefits, advantages, challenges, costs and knowledge gaps on FO hybrid systems are discussed. FO can play a role as a bridge to integrate upstream and downstream water treatment processes, to reduce the energy consumption of the entire desalination or water recovery and reuse processes, thus achieving a sustainable solution for the water-energy nexus. FO hybrid membrane systems showed to have advantages over traditional membrane process like high pressure reverse osmosis and nanofiltration for desalination and wastewater treatment: (i) chemical storage and feed water systems may be reduced for capital, operational and maintenance cost, (ii) water quality is improved, (iii) reduced process piping costs, (iv) more flexible treatment units, and (v) higher overall sustainability of the desalination and wastewater treatment process. Nevertheless, major challenges make FO systems not yet a commercially viable technology, the most critical being the development of a high flux membrane, capable of maintaining an elevated salt rejection and a reduced internal concentration polarization effect, and the availability of appropriate draw solutions (cost effective and non-toxic), which can be recirculated via an efficient recovery process. This review article highlights the features of hybrid FO systems and specifically provides the state-of-the-art applications in the water industry in a novel classification and based on the latest developments toward scaling up these systems.

  16. Forward osmosis niches in seawater desalination and wastewater reuse.

    Science.gov (United States)

    Valladares Linares, R; Li, Z; Sarp, S; Bucs, Sz S; Amy, G; Vrouwenvelder, J S

    2014-12-01

    This review focuses on the present status of forward osmosis (FO) niches in two main areas: seawater desalination and wastewater reuse. Specific applications for desalination and impaired-quality water treatment and reuse are described, as well as the benefits, advantages, challenges, costs and knowledge gaps on FO hybrid systems are discussed. FO can play a role as a bridge to integrate upstream and downstream water treatment processes, to reduce the energy consumption of the entire desalination or water recovery and reuse processes, thus achieving a sustainable solution for the water-energy nexus. FO hybrid membrane systems showed to have advantages over traditional membrane process like high pressure reverse osmosis and nanofiltration for desalination and wastewater treatment: (i) chemical storage and feed water systems may be reduced for capital, operational and maintenance cost, (ii) water quality is improved, (iii) reduced process piping costs, (iv) more flexible treatment units, and (v) higher overall sustainability of the desalination and wastewater treatment process. Nevertheless, major challenges make FO systems not yet a commercially viable technology, the most critical being the development of a high flux membrane, capable of maintaining an elevated salt rejection and a reduced internal concentration polarization effect, and the availability of appropriate draw solutions (cost effective and non-toxic), which can be recirculated via an efficient recovery process. This review article highlights the features of hybrid FO systems and specifically provides the state-of-the-art applications in the water industry in a novel classification and based on the latest developments toward scaling up these systems. Copyright © 2014 Elsevier Ltd. All rights reserved.

  17. Economic Analysis in Series-Distillation Desalination

    Directory of Open Access Journals (Sweden)

    Mirna Rahmah Lubis

    2010-06-01

    Full Text Available The ability to produce potable water economically is the primary purpose of seawater desalination research. Reverse osmosis (RO and multi-stage flash (MSF cost more than potable water produced from fresh water resources. Therefore, this research investigates a high-efficiency mechanical vapor-compression distillation system that employs an improved water flow arrangement. The incoming salt concentration was 0.15% salt for brackish water and 3.5% salt for seawater, whereas the outgoing salt concentration was 1.5% and 7%, respectively. Distillation was performed at 439 K and 722 kPa for both brackish water feed and seawater feed. Water costs of the various conditions were calculated for brackish water and seawater feeds using optimum conditions considered as 25 and 20 stages, respectively. For brackish water at a temperature difference of 0.96 K, the energy requirement is 2.0 kWh/m3. At this condition, the estimated water cost is $0.39/m3 achieved with 10,000,000 gal/day distillate, 30-year bond, 5% interest rate, and $0.05/kWh electricity. For seawater at a temperature difference of 0.44 K, the energy requirement is 3.97 kWh/m3 and the estimated water cost is $0.61/m3. Greater efficiency of the vapor compression system is achieved by connecting multiple evaporators in series, rather than the traditional parallel arrangement. The efficiency results from the gradual increase of salinity in each stage of the series arrangement in comparison to parallel. Calculations using various temperature differences between boiling brine and condensing steam show the series arrangement has the greatest improvement at lower temperature differences. Keywords: desalination, dropwise condensation, mechanical-vapor compression

  18. A bio-thermic seawater desalination system using halophytes

    NARCIS (Netherlands)

    Finck, C.

    2014-01-01

    A bio-thermic seawater desalination system using halophytes was developed and successfully tested. A greenhouse as part of a test rig, with different sorts of mangroves, was installed. Measurements showed promising results concerning fresh water relative yielding rates up to 1.4 kg/h/m2 (leaf

  19. Pre-desalination with electro-membranes for SWRO

    NARCIS (Netherlands)

    Post, J.W.; Huiting, H.; Cornelissen, E.R.; Hamelers, H.V.M.

    2011-01-01

    Although seawater reverse osmosis (SWRO) is currently the only non-thermal desalination process in practical use, its characteristics make it difficult to approach the ideal reversible process. SWRO has a low water recovery (determined by the osmotic pressure) and relatively high energy consumption.

  20. Comparison of Configurations for High-Recovery Inland Desalination Systems

    Directory of Open Access Journals (Sweden)

    Philip A. Davies

    2012-09-01

    Full Text Available Desalination of brackish groundwater (BW is an effective approach to augment water supply, especially for inland regions that are far from seawater resources. Brackish water reverse osmosis (BWRO desalination is still subject to intensive energy consumption compared to the theoretical minimum energy demand. Here, we review some of the BWRO plants with various system arrangements. We look at how to minimize energy demands, as these contribute considerably to the cost of desalinated water. Different configurations of BWRO system have been compared from the view point of normalized specific energy consumption (SEC. Analysis is made at theoretical limits. The SEC reduction of BWRO can be achieved by (i increasing number of stages, (ii using an energy recovery device (ERD, or (iii operating the BWRO in batch mode or closed circuit mode. Application of more stages not only reduces SEC but also improves water recovery. However, this improvement is less pronounced when the number of stages exceeds four. Alternatively and more favourably, the BWRO system can be operated in Closed Circuit Desalination (CCD mode and gives a comparative SEC to that of the 3-stage system with a recovery ratio of 80%. A further reduction of about 30% in SEC can be achieved through batch-RO operation. Moreover, the costly ERDs and booster pumps are avoided with both CCD and batch-RO, thus furthering the effectiveness of lowering the costs of these innovative approaches.

  1. Effect of the scale inhibitor on ion content in reverse osmosis system for seawater desalination

    Science.gov (United States)

    Gao, Yuhua; Liu, Zhenfa; Zhang, Lihui; Li, Haihua

    2017-09-01

    A scale inhibitor was synthesized from polysuccinimide with 2-aminoethanesulfonic acid and aspartic acid. The effect of scale inhibitor on ion content in reverse osmosis system for seawater desalination was studied. The results showed that the ion content of permeate water is lower with the scale inhibitor added in RO system for seawater desalination than without scale inhibitor. On the contrary, the ion content of concentrate water is higher when with scale inhibitor in RO system.

  2. Purification of High Salinity Brine by Multi-Stage Ion Concentration Polarization Desalination.

    Science.gov (United States)

    Kim, Bumjoo; Kwak, Rhokyun; Kwon, Hyukjin J; Pham, Van Sang; Kim, Minseok; Al-Anzi, Bader; Lim, Geunbae; Han, Jongyoon

    2016-08-22

    There is an increasing need for the desalination of high concentration brine (>TDS 35,000 ppm) efficiently and economically, either for the treatment of produced water from shale gas/oil development, or minimizing the environmental impact of brine from existing desalination plants. Yet, reverse osmosis (RO), which is the most widely used for desalination currently, is not practical for brine desalination. This paper demonstrates technical and economic feasibility of ICP (Ion Concentration Polarization) electrical desalination for the high saline water treatment, by adopting multi-stage operation with better energy efficiency. Optimized multi-staging configurations, dependent on the brine salinity values, can be designed based on experimental and numerical analysis. Such an optimization aims at achieving not just the energy efficiency but also (membrane) area efficiency, lowering the true cost of brine treatment. ICP electrical desalination is shown here to treat brine salinity up to 100,000 ppm of Total Dissolved Solids (TDS) with flexible salt rejection rate up to 70% which is promising in a various application treating brine waste. We also demonstrate that ICP desalination has advantage of removing both salts and diverse suspended solids simultaneously, and less susceptibility to membrane fouling/scaling, which is a significant challenge in the membrane processes.

  3. Self-Driven Desalination and Advanced Treatment of Wastewater in a Modularized Filtration Air Cathode Microbial Desalination Cell.

    Science.gov (United States)

    Zuo, Kuichang; Wang, Zhen; Chen, Xi; Zhang, Xiaoyuan; Zuo, Jiaolan; Liang, Peng; Huang, Xia

    2016-07-05

    Microbial desalination cells (MDCs) extract organic energy from wastewater for in situ desalination of saline water. However, to desalinate salt water, traditional MDCs often require an anolyte (wastewater) and a catholyte (other synthetic water) to produce electricity. Correspondingly, the traditional MDCs also produced anode effluent and cathode effluent, and may produce a concentrate solution, resulting in a low production of diluate. In this study, nitrogen-doped carbon nanotube membranes and Pt carbon cloths were utilized as filtration material and cathode to fabricate a modularized filtration air cathode MDC (F-MDC). With real wastewater flowing from anode to cathode, and finally to the middle membrane stack, the diluate volume production reached 82.4%, with the removal efficiency of salinity and chemical oxygen demand (COD) reached 93.6% and 97.3% respectively. The final diluate conductivity was 68 ± 12 μS/cm, and the turbidity was 0.41 NTU, which were sufficient for boiler supplementary or industrial cooling. The concentrate production was only 17.6%, and almost all the phosphorus and salt, and most of the nitrogen were recovered, potentially allowing the recovery of nutrients and other chemicals. These results show the potential utility of the modularized F-MDC in the application of municipal wastewater advanced treatment and self-driven desalination.

  4. The Desalination Process Driven by Wave Energy: A Challenge for the Future

    Directory of Open Access Journals (Sweden)

    Vincenzo Franzitta

    2016-12-01

    Full Text Available The correlation between water and energy is currently the focus of several investigations. In particular, desalination is a technological process characterized by high energy consumption; nevertheless, desalination represents the only practicable solution in several areas, where the availability of fresh water is limited but brackish water or seawater are present. These natural resources (energy and water are essential for each other; energy system conversion needs water, and electrical energy is necessary for water treatment or transport. Several interesting aspects include the study of saline desalination as an answer to freshwater needs and the application of renewable energy (RE devices to satisfy electrical energy requirement for the desalination process. A merge between renewable energy and desalination is beneficial in that it is a sustainable and challenging option for the future. This work investigates the possibility of using renewable energy sources to supply the desalination process. In particular, as a case study, we analyze the application of wave energy sources in the Sicilian context.

  5. Seawater desalination and serum magnesium concentrations in Israel.

    Science.gov (United States)

    Koren, Gideon; Shlezinger, Meital; Katz, Rachel; Shalev, Varda; Amitai, Yona

    2017-04-01

    With increasing shortage of fresh water globally, more countries are consuming desalinated seawater (DSW). In Israel >50% of drinking water is now derived from DSW. Desalination removes magnesium, and hypomagnesaemia has been associated with increased cardiac morbidity and mortality. Presently the impact of consuming DSW on body magnesium status has not been established. We quantified changes in serum magnesium in a large population based study (n = 66,764), before and after desalination in regions consuming DSW and in regions where DSW has not been used. In the communities that switched to DSW in 2013, the mean serum magnesium was 2.065 ± 0.19 mg/dl before desalination and fell to 2.057 ± 0.19 mg/dl thereafter (p < 0.0001). In these communities 1.62% of subjects exhibited serum magnesium concentrations ≤1.6 mg/dl between 2010 and 2013. This proportion increased by 24% between 2010-2013 and 2015-2016 to 2.01% (p = 0.0019). In contrast, no such changes were recorded in the communities that did not consume DSW. Due to the emerging evidence of increased cardiac morbidity and mortality associated with hypomagnesaemia, it is vital to consider re-introduction of magnesium to DSW.

  6. Operational strategy of adsorption desalination systems

    KAUST Repository

    Thu, Kyaw

    2009-03-01

    This paper presents the performances of an adsorption desalination (AD) system in two-bed and four-bed operational modes. The tested results are calculated in terms of key performance parameters namely, (i) specific daily water production (SDWP), (ii) cycle time, and (iii) performance ratio (PR) for various heat source temperatures, mass flow rates, cycle times along with a fixed heat sink temperature. The optimum input parameters such as driving heat source and cycle time of the AD cycle are also evaluated. It is found from the present experimental data that the maximum potable water production per tonne of adsorbent (silica gel) per day is about 10 m3 whilst the corresponding performance ratio is 0.61, and a longer cycle time is required to achieve maximum water production at lower heat source temperatures. This paper also provides a useful guideline for the operational strategy of the AD cycle. © 2008 Elsevier Ltd. All rights reserved.

  7. Desalination of painted brick vaults

    DEFF Research Database (Denmark)

    Larsen, Poul Klenz

    The subject of the thesis is salt and moisture movement that causes damage to wall paintings on church vaults. The deterioration was studied in the churches of Fanefjord, Kirkerup and Brarup. A desalination method was tested om location. The salt and moisture transfer was examined in detail...

  8. Desalination. LC Science Tracer Bullet.

    Science.gov (United States)

    Buydos, John F., Comp.

    This guide provides a review of the relevant literature on desalination within the collections of the Library of Congress. While not intended as a comprehensive bibliography, this guide is designed as a quick and ready reference source for the reader, and includes the following sections: (1) articles that provide introductions to the topic of…

  9. Efficiency improvement of seawater desalination processes: the case of the W.E.B. Aruba N.V. on the island of Aruba

    NARCIS (Netherlands)

    Marchena, F.A.

    2013-01-01

    Seawater desalination is known worldwide as the most important source for the production of drinking water in arid areas where there are practically no natural water resources and consequently insufficient surface water or groundwater. However the desalination technology still remains a very costly

  10. Constructing Black Titania with Unique Nanocage Structure for Solar Desalination.

    Science.gov (United States)

    Zhu, Guilian; Xu, Jijian; Zhao, Wenli; Huang, Fuqiang

    2016-11-23

    Solar desalination driven by solar radiation as heat source is freely available, however, hindered by low efficiency. Herein, we first design and synthesize black titania with a unique nanocage structure simultaneously with light trapping effect to enhance light harvesting, well-crystallized interconnected nanograins to accelerate the heat transfer from titania to water and with opening mesopores (4-10 nm) to facilitate the permeation of water vapor. Furthermore, the coated self-floating black titania nanocages film localizes the temperature increase at the water-air interface rather than uniformly heating the bulk of the water, which ultimately results in a solar-thermal conversion efficiency as high as 70.9% under a simulated solar light with an intensity of 1 kW m-2 (1 sun). This finding should inspire new black materials with rationally designed structure for superior solar desalination performance.

  11. Projected world market for seawater desalination equipment

    Energy Technology Data Exchange (ETDEWEB)

    1984-10-01

    A forecast is presented of the market for seawater desalination plants. The conclusions presented herein are based on a number of sources of information, of which the most important are: responses to questionnaires mailed to 300 cognizant water agencies in 61 countries; the published market growth trend over the period 1971 to 1983; and an analysis of the geography, rainfall, population, industrial growth, and energy availability in the respective countries. Analysis suggests the possibility that financing, although currently a major stumbling block to the purchase of desalting plants, may be effected by an exchange program in which the purchaser of plants will offer some exportable product(s) in exchange. The forecast suggests the likelihood that the seawater desalination market is becoming saturated. A plateau is expected to develop in new plant sales of additional capacity in the immediate future, followed by a downturn by the end of the century. This report, however, emphasizes the importance of the replacement market, which will involve substantial sales to replace worn-out and obsolescent equipment. The combined new-plus-replacement annual sales can be expected to reach 1.25 million m/sup 3//d (330 Mgd) by the year 2000. Seawater reverse osmosis (SWRO) is expected to represent 270,000 m/sup 3//d (70 Mgd) by the end of the century because of technological improvements in membrane systems and components.

  12. Efficient thermal desalination technologies with renewable energy systems: A state-of-the-art review

    Energy Technology Data Exchange (ETDEWEB)

    Esfahani, Iman Janghorban; Rashidi, Jouan; Ifaei, Pouya; Yoo, ChangKyoo [Center for Environmental Studies, Kyung Hee University, Yongin (Korea, Republic of)

    2016-02-15

    Due to the current fossil fuel crisis and associated adverse environmental impacts, renewable energy sources (RES) have drawn interest as alternatives to fossil fuels for powering water desalination systems. Over the last few decades the utility of renewable energy sources such as solar, geothermal, and wind to run desalination processes has been explored. However, the expansion of these technologies to larger scales is hampered by techno-economic and thermo-economic challenges. This paper reviews the state-of-the-art in the field of renewable energy-powered thermal desalination systems (RE-PTD) to compare their productivity and efficiency through thermodynamic, economic, and environmental analyses. We performed a comparative study using published data to classify RE-PTD systems technologies on the basis of the energy collection systems that they use. Among RE-PTD systems, solar energy powered-thermal desalination systems demonstrate high thermo-environ-economic efficiency to produce fresh water to meet various scales of demand.

  13. Use of simulated evaporation to assess the potential for scale formation during reverse osmosis desalination

    Science.gov (United States)

    Huff, G.F.

    2004-01-01

    The tendency of solutes in input water to precipitate efficiency lowering scale deposits on the membranes of reverse osmosis (RO) desalination systems is an important factor in determining the suitability of input water for desalination. Simulated input water evaporation can be used as a technique to quantitatively assess the potential for scale formation in RO desalination systems. The technique was demonstrated by simulating the increase in solute concentrations required to form calcite, gypsum, and amorphous silica scales at 25??C and 40??C from 23 desalination input waters taken from the literature. Simulation results could be used to quantitatively assess the potential of a given input water to form scale or to compare the potential of a number of input waters to form scale during RO desalination. Simulated evaporation of input waters cannot accurately predict the conditions under which scale will form owing to the effects of potentially stable supersaturated solutions, solution velocity, and residence time inside RO systems. However, the simulated scale-forming potential of proposed input waters could be compared with the simulated scale-forming potentials and actual scale-forming properties of input waters having documented operational histories in RO systems. This may provide a technique to estimate the actual performance and suitability of proposed input waters during RO.

  14. Precipitation softening: a pretreatment process for seawater desalination.

    Science.gov (United States)

    Ayoub, George M; Zayyat, Ramez M; Al-Hindi, Mahmoud

    2014-02-01

    Reduction of membrane fouling in reverse osmosis systems and elimination of scaling of heat transfer surfaces in thermal plants are a major challenge in the desalination of seawater. Precipitation softening has the potential of eliminating the major fouling and scaling species in seawater desalination plants, thus allowing thermal plants to operate at higher top brine temperatures and membrane plants to operate at a reduced risk of fouling, leading to lower desalinated water costs. This work evaluated the use of precipitation softening as a pretreatment step for seawater desalination. The effectiveness of the process in removing several scale-inducing materials such as calcium, magnesium, silica, and boron was investigated under variable conditions of temperature and pH. The treatment process was also applied to seawater spiked with other known fouling species such as iron and bacteria to determine the efficiency of removal. The results of this work show that precipitation softening at a pH of 11 leads to complete elimination of calcium, silica, and bacteria; to very high removal efficiencies of magnesium and iron (99.6 and 99.2 %, respectively); and to a reasonably good removal efficiency of boron (61 %).

  15. Economic evaluation of the integrated SMART desalination plant

    Energy Technology Data Exchange (ETDEWEB)

    Hwang, Young Dong; Lee, Man Kye; Yeo, Ji Won; Kim, Hee Chul; Chang, Moon Hee

    2001-04-01

    In this study, an economic evaluation methodology of the integrated SMART desalination plant was established and the economic evaluation of SMART was performed. The plant economics was evaluated with electricity generation costs calculated using approximate estimates of SMART cost data and the result was compared with the result calculated using the SMART design data and estimated bulk materials. In addition, a series of sensitivity studies on the power generation cost was performed for the main economic parameters of SMART Power credit method was used for the economic analysis of the integrated SMART desalination plant. Power credit method is a widely used economic analysis method for the cogeneration plant when the major portion of the energy is used for the electricity generation. In the case of using SMART fot power generation only, the result shows that the electricity generation cost of SMART is higher than that of the alternative power options. However, it can be competitive with the other power options in the limited cases, especially with the gas fired combined plant. In addition, an economic analysis of the integrated SMART desalination plant coupled with MED was performed. The calculated water production cost is in the range of 0.56 approx. 0.88($/m{sup 3}) for the plant availability of 80% or higher, which is close to the study results presented by the various other countries. This indicates that SMART can be considered as a competitive choice for desalination among various alternative energy sources.

  16. Use of a liter-scale microbial desalination cell as a platform to study bioelectrochemical desalination with salt solution or artificial seawater.

    Science.gov (United States)

    Jacobson, Kyle S; Drew, David M; He, Zhen

    2011-05-15

    Bioelectrochemical desalination is potentially advantageous because of bioenergy production and integrated wastewater treatment and desalination. In this work, the performance and energy benefits of a liter-scale upflow microbial desalination cell (UMDC) were evaluated. The UMDC desalinated both salt solution (NaCl) and artificial seawater, and the removal rate of total dissolved solid (TDS) increased with an increased hydraulic retention time, although TDS reduction in artificial seawater was lower than that in salt solution. Our analysis suggested that electricity generation was a predominant factor in removing TDS (more than 70%), and that other factors, like water osmosis and unknown processes, also contributed to TDS reduction. It was more favorable given the high energy efficiency, when treating salt solution, to operate the UMDC under the condition of high power output compared with that of high current generation because of the amount of energy production; while high current generation was more desired with seawater desalination because of lower salinity in the effluent. Under the condition of the high power output and the assumption of the UMDC as a predesalination in connection with a reversal osmosis (RO) system, the UMDC could produce electrical energy that might potentially account for 58.1% (salt solution) and 16.5% (artificial seawater) of the energy required by the downstream RO system. Our results demonstrated the great potential of bioelectrochemical desalination.

  17. Nuclear desalination for the northwest of Mexico; Desalacion nuclear para el noroeste de Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Ortega C, R. F. [Instituto de Ingenieria, UNAM, 04510 Mexico D.F. (Mexico)

    2008-07-01

    The IMPULSA project of the Engineering Institute of UNAM, it has dedicated from the year 2005 to the study and development of new desalination technologies of seawater with renewable energies. The objective is to form a group of expert engineers and investigators in the desalination topics able to transform their scientific knowledge in engineering solutions, with a high grade of knowledge of the environment and the renewable energies. In the middle of 2007 was took the initiative in the IMPULSA project to study the nuclear desalination topic. It is evident that before the high cost of the hydrocarbons and its high environmental impact, the nuclear generation alternative of energy becomes extremely attractive, mainly for desalination projects of seawater of great size. The Northwest of Mexico is particularly attractive as the appropriate site for one nuclear desalination plant of great size given its shortage of drink water and the quick growth of its population; as well as its level of tourist, agricultural and industrial activity. In this study was revised the state of the art of the nuclear desalination on the world and it is simulated some couplings and operation forms of nuclear reactors and desalination units, from the thermodynamic and economic viewpoint with the purpose of identifying the main peculiarities of this technology. The objective of the study was to characterize several types and sizes of nuclear reactors of the last generation that could be couple to a desalination technology as multi-stage distillation, type flash distillation or inverse osmosis. It is used for this effect the DEEP 3.1 program of the IAEA to simulate the coupling and to carry out an economic preliminary evaluation. Was found cost very competitive of 0.038-0.044 US$/kWh for the electric power production and 0.60 to 0.77 US$/m{sup 3} for the drink water produced, without including the water transport cost or the use of carbon certificates. (Author)

  18. A Grid-Connected Desalination Plant Operation

    Directory of Open Access Journals (Sweden)

    Won Ko

    2013-02-01

    Full Text Available In this paper, a grid-connected desalination plant operation approach is suggested. In desalination plant, large amount of energy is needed to operate pump and motor; hence most of energy is electricity. For this reason, the largest part of the operation cost is electricity charges. To demonstrate power usage, small size desalination measuring system mounted plant is used. Finally, to show the result of a grid-connected desalination plant operation, electric tariff rate of Korea is used. The result shows that total cost reduction rate is calculated about 1.6% of annual total electric plant operation cost.

  19. A new process for desalination and electrodeionization of water by means of electrostatic shielding zones – ionic current sinks. Study of optical sensors of the form Al/a-SiC:H/c-Si(n with high sensitivity.

    Directory of Open Access Journals (Sweden)

    A. Dermentzi

    2009-01-01

    Full Text Available We constructed electrostatic shielding zones made of electrode graphite powder and used them as a new type of ionic and electronic current sinks. Because of the local elimination of the applied electric field, voltage and current within the current sinks, ions are led inside them and accumulate there. The sinks become ion concentrating compartments whereas the adjacent compartments become ion depleting compartments. The proposed electrodeionization process uses no permselective ion exchange membranes. We implemented it in electrodialysis desalination of a synthetic brackish 0.03 M NaCl solution and obtained potable water with a NaCl concentration <500 mg L-1. Furthermore, we performed electrodialysis of 0.002 M NiSO4 and electrodeionization of 0.001 M NiSO4 solutions with simultaneous electrochemical regeneration of the used ion exchange resin beds. By the continuous mode of electrodeionization of the 0.001 M NiSO4 solution we obtained pure water with a Ni2+ ion concentration of less than 0.5 mg L-1 at a flow rate of 2.3 x10-4 L s-1 diluate stream

  20. Forward Osmosis in India: Status and Comparison with Other Desalination Technologies

    Science.gov (United States)

    2014-01-01

    With an increase in demand of freshwater and depleting water sources, it is imperative to switch to seawater as a regular source of water supply. However, due to the high total dissolved solid content, it has to be desalinated to make it drinkable. While desalination technologies have been used for many years, mass deployment of such technologies poses a number of challenges like high energy requirements as well as high negative environmental impact through side products and CO2 emissions. The purpose of this paper is to present a sustainable technology for desalination. Forward osmosis, an emerging technology, is compared with the other commonly used technologies worldwide, namely, multieffect distillation, multistage flash distillation, and reverse osmosis as well as other emerging technologies like vapour compression, solar humidification dehumidification, nanofiltration, and freezing desalination. As energy consumption and associated greenhouse gas emissions are one of the major concerns of desalination, this paper concludes that forward osmosis is an emerging sustainable technology for seawater desalination. This paper then presents the challenges involved in the application of forward osmosis in India and presents a plant setup. In the end, the cost comparison of a forward osmosis and reverse osmosis plant has been done and it was concluded that forward osmosis is economically better as well. PMID:27350984

  1. Forward Osmosis in India: Status and Comparison with Other Desalination Technologies.

    Science.gov (United States)

    Mehta, Dhruv; Gupta, Lovleen; Dhingra, Rijul

    2014-01-01

    With an increase in demand of freshwater and depleting water sources, it is imperative to switch to seawater as a regular source of water supply. However, due to the high total dissolved solid content, it has to be desalinated to make it drinkable. While desalination technologies have been used for many years, mass deployment of such technologies poses a number of challenges like high energy requirements as well as high negative environmental impact through side products and CO2 emissions. The purpose of this paper is to present a sustainable technology for desalination. Forward osmosis, an emerging technology, is compared with the other commonly used technologies worldwide, namely, multieffect distillation, multistage flash distillation, and reverse osmosis as well as other emerging technologies like vapour compression, solar humidification dehumidification, nanofiltration, and freezing desalination. As energy consumption and associated greenhouse gas emissions are one of the major concerns of desalination, this paper concludes that forward osmosis is an emerging sustainable technology for seawater desalination. This paper then presents the challenges involved in the application of forward osmosis in India and presents a plant setup. In the end, the cost comparison of a forward osmosis and reverse osmosis plant has been done and it was concluded that forward osmosis is economically better as well.

  2. Freeze desalination of seawater using LNG cold energy

    KAUST Repository

    Chang, Jian

    2016-06-23

    With the aid of cold energy from regasification of liquefied natural gas (LNG), freeze desalination (FD) is an emerging technology for seawater desalination because of its low energy characteristics and insensitivities to fouling problems. This work aims to investigate the major operating parameters of FD such as coolant temperature, freezing duration, supercooling, seeding, agitation, crystallizer material and subsequent washing procedure on ice production and water quality. It was found that the optimal freezing duration per batch was 1 h for an iron crystallizer and 1.5 h for a glass crystallizer. The optimal coolant temperature should be around −8 °C. The optimal amount of washing water to clean the raw ice was about 50 wt% of the raw ice. Over 50 wt% of the feed could be recovered as raw ice within 1 h, which means an overall ice recovery rate of higher than 25% (of the original seawater), considering the consumption of washing water. Both artificial and real seawater were tested under the optimized conditions. The total dissolved solid in the product ice was around 300 ppm, which met the World Health Organization (WHO) potable water salinity standard of 500 ppm. Therefore, the process parameters optimized in this study can be directly used for the freeze desalination of seawater.

  3. Freeze desalination of seawater using LNG cold energy.

    Science.gov (United States)

    Chang, Jian; Zuo, Jian; Lu, Kang-Jia; Chung, Tai-Shung

    2016-10-01

    With the aid of cold energy from regasification of liquefied natural gas (LNG), freeze desalination (FD) is an emerging technology for seawater desalination because of its low energy characteristics and insensitivities to fouling problems. This work aims to investigate the major operating parameters of FD such as coolant temperature, freezing duration, supercooling, seeding, agitation, crystallizer material and subsequent washing procedure on ice production and water quality. It was found that the optimal freezing duration per batch was 1 h for an iron crystallizer and 1.5 h for a glass crystallizer. The optimal coolant temperature should be around -8 °C. The optimal amount of washing water to clean the raw ice was about 50 wt% of the raw ice. Over 50 wt% of the feed could be recovered as raw ice within 1 h, which means an overall ice recovery rate of higher than 25% (of the original seawater), considering the consumption of washing water. Both artificial and real seawater were tested under the optimized conditions. The total dissolved solid in the product ice was around 300 ppm, which met the World Health Organization (WHO) potable water salinity standard of 500 ppm. Therefore, the process parameters optimized in this study can be directly used for the freeze desalination of seawater. Copyright © 2016 Elsevier Ltd. All rights reserved.

  4. Graphene membranes with nanoslits for seawater desalination via forward osmosis.

    Science.gov (United States)

    Dahanayaka, Madhavi; Liu, Bo; Hu, Zhongqiao; Pei, Qing-Xiang; Chen, Zhong; Law, Adrian Wing-Keung; Zhou, Kun

    2017-11-22

    Stacked graphene (GE) membranes with cascading nanoslits can be synthesized economically compared to monolayer nanoporous GE membranes, and have potential for molecular separation. This study focuses on investigating the seawater desalination performance of these stacked GE layers as forward osmosis (FO) membranes by using molecular dynamics simulations. The FO performance is evaluated in terms of water flux and salt rejection and is explained by analysing the water density distribution and radial distribution function. The water flow displays an Arrhenius type relation with temperature and the activation energy for the stacked GE membrane is estimated to be 8.02 kJ mol-1, a value much lower than that of commercially available FO membranes. The study reveals that the membrane characteristics including the pore width, offset, interlayer separation distance and number of layers have significant effects on the desalination performance. Unlike monolayer nanoporous GE membranes, at an optimum layer separation distance, the stacked GE membranes with large pore widths and completely misaligned pore configuration can retain complete ion rejection and maintain a high water flux. Findings from the present study are helpful in developing GE-based membranes for seawater desalination via FO.

  5. Deionization and desalination using electrostatic ion pumping

    Science.gov (United States)

    Bourcier, William L [Livermore, CA; Aines, Roger D [Livermore, CA; Haslam, Jeffery J [Livermore, CA; Schaldach, Charlene M [Pleasanton, CA; O'Brien, Kevin C [San Ramon, CA; Cussler, Edward [Edina, MN

    2011-07-19

    The present invention provides a new method and apparatus/system for purifying ionic solutions, such as, for example, desalinating water, using engineered charged surfaces to sorb ions from such solutions. Surface charge is applied externally, and is synchronized with oscillatory fluid movements between substantially parallel charged plates. Ions are held in place during fluid movement in one direction (because they are held in the electrical double layer), and released for transport during fluid movement in the opposite direction by removing the applied electric field. In this way the ions, such as salt, are "ratcheted" across the charged surface from the feed side to the concentrate side. The process itself is very simple and involves only pumps, charged surfaces, and manifolds for fluid collection.

  6. Conceptual design and economic evaluation about the coupling of high power PWRs and desalination system

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Sang Ho; Chang, Soon Heung [Korea Advanced Institute of Science and Technology, Daejeon (Korea, Republic of); Kim, Hyeon Min; Heo, Gyun Young [Kyung Hee Univ., Yongin (Korea, Republic of)

    2012-03-15

    Both electricity and fresh water become basic human needs in modern days. This paper describes the coupling methods of high power pressurized water reactors and desalination system, and evaluates the economics of coupling systems. OPR1000 designed by Korea was chosen for the reference reactor. Because MED (Mulct-Effect Distillation) with TVC (Thermal Vapor Compressor) have been evaluated as an effective desalination system for high power reactors, it was used for the reference desalination method in simulation. In order to simulate the secondary circuit of PWRs with heat exchangers for MED-TVC, PEPSE program which is normally used for performance evaluation of power system efficiencies was used. The coupling of OPR1000 and desalination systems were set under the restriction it had to make as small changes as possible. From the results PEPSE simulation, the economics of the coupling systems were calculates using equations form DEEP4.0 (Desalination Economic Evaluation Program) which was developed by IAEA because Deep simulates just two simple couplings which are back pressure and condensation/extraction. In the secondary circuit simulation seven coupling cases were set and outlet powers to heat exchanger for desalination were varied to be dependent on the thermohydraulic conditions on each part. The results of changed electrical power generation were calculated with the thermal outputs for desalination. It is concluded that two coupling method using the steam from high-pressure turbine have high performance and are economical among the simulated cases. The first one is to add a heat exchanger on the branch from high-pressure turbine into moisture separator and the other is on the branch into feedwater heating parts. It proves desalination plants can be added to current high power PWRs.

  7. Feasibility study of a dedicate nuclear desalination system: Low-pressure inherent heat sink nuclear desalination plant (LIND)

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Ho Sik; No, Hee Cheon; Jo, Yu Gwan; Wivisono, Andhika Feri; Park, Byung Ha; Choi, Jin Young; Lee, Jeong Ik; Jeong, Yong Hoon; Cho, Nam Zin [Dept. of Nuclear and Quantum Engineering, Korea Advanced Institute of Science and Technology, Daejeon (Korea, Republic of)

    2015-04-15

    In this paper, we suggest the conceptual design of a water-cooled reactor system for a low-pressure inherent heat sink nuclear desalination plant (LIND) that applies the safety-related design concepts of high temperature gas-cooled reactors to a water-cooled reactor for inherent and passive safety features. Through a scoping analysis, we found that the current LIND design satisfied several essential thermal-hydraulic and neutronic design requirements. In a thermal-hydraulic analysis using an analytical method based on the Wooton-Epstein correlation, we checked the possibility of safely removing decay heat through the steel containment even if all the active safety systems failed. In a neutronic analysis using the Monte Carlo N-particle transport code, we estimated a cycle length of approximately 6 years under 200 MW{sub th} and 4.5% enrichment. The very long cycle length and simple safety features minimize the burdens from the operation, maintenance, and spent-fuel management, with a positive impact on the economic feasibility. Finally, because a nuclear reactor should not be directly coupled to a desalination system to prevent the leakage of radioactive material into the desalinated water, three types of intermediate systems were studied: a steam producing system, a hot water system, and an organic Rankine cycle system.

  8. Feasibility study of a dedicated nuclear desalination system: Low-pressure Inherent heat sink Nuclear Desalination plant (LIND

    Directory of Open Access Journals (Sweden)

    Ho Sik Kim

    2015-04-01

    Full Text Available In this paper, we suggest the conceptual design of a water-cooled reactor system for a low-pressure inherent heat sink nuclear desalination plant (LIND that applies the safety-related design concepts of high temperature gas-cooled reactors to a water-cooled reactor for inherent and passive safety features. Through a scoping analysis, we found that the current LIND design satisfied several essential thermal–hydraulic and neutronic design requirements. In a thermal–hydraulic analysis using an analytical method based on the Wooton–Epstein correlation, we checked the possibility of safely removing decay heat through the steel containment even if all the active safety systems failed. In a neutronic analysis using the Monte Carlo N-particle transport code, we estimated a cycle length of approximately 6 years under 200 MWth and 4.5% enrichment. The very long cycle length and simple safety features minimize the burdens from the operation, maintenance, and spent-fuel management, with a positive impact on the economic feasibility. Finally, because a nuclear reactor should not be directly coupled to a desalination system to prevent the leakage of radioactive material into the desalinated water, three types of intermediate systems were studied: a steam producing system, a hot water system, and an organic Rankine cycle system.

  9. Design and optimization of desalination reverse osmosis plants driven by renewable energies using genetic algorithms

    Energy Technology Data Exchange (ETDEWEB)

    Bourouni, K.; Ben M' Barek, T. [Energetique des Batiments et Systeme Solaire, Ecole Nationale d' Ingenieurs de Tunis, BP 37, Le Belvedere 1002 Tunis (Tunisia); Al Taee, A. [University of Surrey, Guidford, Surrey (United Kingdom)

    2011-03-15

    Renewable energy sources (RES) for powering desalination processes is a promising option especially in remote and arid regions where the use of conventional energy is costly or unavailable. Reverse Osmosis (RO) is one of the most suitable desalination processes to be coupled with different renewable energy sources such as solar and wind. If RES/RO systems are optimally designed, some combinations can be cost effective and reliable. However, the design of such systems is complex because of uncertain renewable energy supplies, load demands and the non-linear characteristics of some components. In such system, different scenarios can be suggested; i.e combinations of PV panels, type and number of batteries, type and number of turbines, etc. Therefore, it is difficult to determine the optimal configuration with classical techniques. The development of a tool to integrate all parameters involved and compare between the possible scenarios is very important. This paper presents a new model based on the Genetic Algorithms allowing the generation of several individuals (possible solutions) for coupling small RO unit to RES. A particular interest is focused on the hybrid systems (PV/WIND/Batteries/RO). The objective function to minimize corresponds to the total water cost (Capital cost plus Operational costs). Finally, a case study of PV/RO unit, installed since 2007 in Ksar Ghilene village in southern Tunisia, is presented. (author)

  10. Recent developments in thermally-driven seawater desalination: Energy efficiency improvement by hybridization of the MED and AD cycles

    KAUST Repository

    Ng, Kim Choon

    2015-01-01

    The energy, water and environment nexus is a crucial factor when considering the future development of desalination plants or industry in the water-stressed economies. New generation of desalination processes or plants has to meet the stringent environment discharge requirements and yet the industry remains highly energy efficient and sustainable when producing good potable water. Water sources, either brackish or seawater, have become more contaminated as feed while the demand for desalination capacities increase around the world. One immediate solution for energy efficiency improvement comes from the hybridization of the proven desalination processes to the newer processes of desalination: For example, the integration of the available thermally-driven to adsorption desalination (AD) cycles where significant thermodynamic synergy can be attained when cycles are combined. For these hybrid cycles, a quantum improvement in energy efficiency as well as in increase in water production can be expected. The advent of MED with AD cycles, or simply called the MEDAD cycles, is one such example where seawater desalination can be pursued and operated in cogeneration with the electricity production plants: The hybrid desalination cycles utilize only the low exergy bled-steam at low temperatures, complemented with waste exhaust or renewable solar thermal heat at temperatures between 60 and 80. °C. In this paper, the authors have reported their pioneered research on aspects of AD and related hybrid MEDAD cycles, both at theoretical models and experimental pilots. Using the cogeneration of electricity and desalination concept, the authors examined the cost apportionment of fuel cost by the quality or exergy of working steam for such cogeneration configurations.

  11. Water Treatment Group

    Data.gov (United States)

    Federal Laboratory Consortium — This team researches and designs desalination, water treatment, and wastewater treatment systems. These systems remediate water containing hazardous c hemicals and...

  12. Tracing disinfection byproducts in full-scale desalination plants

    KAUST Repository

    Le Roux, Julien

    2015-03-01

    The aim of this study was to assess the formation and the behavior of halogenated byproducts (regulated THMs and HAAs, as well as nitrogenous, brominated and iodinated DBPs including the emerging iodo-THMs) along the treatment train of full-scale desalination plants. One thermal multi-stage flash distillation (MSF) plant and two reverse osmosis (RO) plants located on the Red Sea coast of Saudi Arabia. DBPs formed during the prechlorination step were efficiently removed along the treatment processes (MSF or RO). Desalination plants fed with good seawater quality and using intermittent chlorine injection did not show high DBP formation and discharge. One RO plant with a lower raw water quality and using continuous chlorination at the intake formed more DBPs. In this plant, some non-regulated DBPs (e.g., dibromoacetonitrile and iodo-THMs) reached the product water in low concentrations (< 1.5 μg/L). Regulated THMs and HAAs were far below their maximum contamination levels set by the US Environmental Protection Agency. Substantial amounts of DBPs are disposed to the sea; low concentrations of DBPs were indeed detected in the water on shore of the desalination plants.

  13. Electrokinetic desalination using honeycomb carbon nanotubes (HC-CNTs): a conceptual study by molecular simulation.

    Science.gov (United States)

    Chen, Qile; Kong, Xian; Li, Jipeng; Lu, Diannan; Liu, Zheng

    2014-09-21

    A new concept of electrokinetic desalination using a CNT honeycomb is presented through molecular dynamics simulation. The preferential translocation of ions towards the outlets near two electrodes was realized by applying an electric field perpendicular to bulk fluid flow in a CNT network, which, in the meantime, generated deionized water flux discharged from the central outlets. The effects of the major factors such as electric field strength, numbers of separation units, diameter of CNT, and ion concentration on the desalination were examined. It was shown that over 95% salt rejection and around 50% fresh water recovery were achieved by the presented module by applying an electric field of 0.8 V nm(-1). CNT diameter, which is critical to ion rejection without the electric field, had a marginal effect on the desalination of this new module when a strong electric field was applied. The desalination was also not sensitive to ion concentration, indicating its excellent workability for a wide range of water salinity, e.g. from brackish water to seawater. A potential of mean force profile revealed a free energy barrier as large as 2.0-6.0 kcal mol(-1) for ions to move opposite to the implemented electrical force. The simulation confirmed the high potential of the CNT honeycomb in water desalination.

  14. Electrokinetic desalination of glazed ceramic tiles

    DEFF Research Database (Denmark)

    Ottosen, Lisbeth M.; Ferreira, Celia; Christensen, Iben Vernegren

    2010-01-01

    Electrokinetic desalination is a method where an applied electric DC field is the driving force for removal of salts from porous building materials. In the present paper, the method is tested in laboratory scale for desalination of single ceramic tiles. In a model system, where a tile...... was contaminated with NaCl during submersion and subsequently desalinated by the method, the desalination was completed in that the high and problematic initial Cl(-) concentration was reduced to an unproblematic concentration. Further conductivity measurements showed a very low conductivity in the tile after...... renovation due to damage of the glazing from the presence of salts. These tiles were severely contaminated with both chlorides and nitrates, and one of the tiles also contained sulphates though at a low concentration. The charge transfer was too low in the experiments to obtain full desalination...

  15. The Complexities of Water Disaster Adaptation

    DEFF Research Database (Denmark)

    Buch-Hansen, Mogens; Luu Bich, Ngoc; Man Quang, Huy

    2015-01-01

    The article argues for an interdisciplinary approach to studying the complex circumstances that turn natural hazards into disasters. It takes on the ambitious task of combining a social sciences-inspired vulnerability and adaptation analysis with a natural science-based hydrological modelling...... analysis, and using both to investigate climaterelated water disasters in two communities in the Quang Binh Province, central Vietnam. The article shows how societal capacity, notably the adaptive capacities of individual households and local and provincial institutions pertaining to the two communities......, can mitigate the natural hazards. Despite differences in exposure and vulnerability, both communities have been forced to seek alternative income-generating activities. This has enhanced their socio-economic resilience but at the same time increased socio-economic differentiation and the vulnerability...

  16. Advanced adsorption cooling cum desalination cycle: A thermodynamic framework

    KAUST Repository

    Chakraborty, Anutosh

    2011-01-01

    We have developed a thermodynamic framework to calculate adsorption cooling cum desalination cycle performances as a function of pore widths and pore volumes of highly porous adsorbents, which are formulated from the rigor of thermodynamic property surfaces of adsorbent-adsorbate system and the adsorption interaction potential between them. Employing the proposed formulations, the coefficient of performance (COP) and overall performance ratio (OPR) of adsorption cycle are computed for various pore widths of solid adsorbents. These results are compared with experimental data for verifying the proposed thermodynamic formulations. It is found from the present analysis that the COP and OPR of adsorption cooling cum desalination cycle is influenced by (i) the physical characteristics of adsorbents, (ii) characteristics energy and (iii) the surface-structural heterogeneity factor of adsorbent-water system. The present study confirms that there exists a special type of adsorbents having optimal physical characteristics that allows us to obtain the best performance.

  17. Thermoeconomic Analysis and Multiobjective Optimization of a Solar Desalination Plant

    Directory of Open Access Journals (Sweden)

    Hamid Mokhtari

    2014-01-01

    Full Text Available A solar desalination plant consisting of solar parabolic collectors, steam generators, and MED unit was simulated technoeconomically and optimized using multiobjective genetic algorithm. A simulation code was developed using MATLAB language programming. Indirect steam generation using different thermal oils including THERMINOL VP1, THERMINOL66, and THERMINOL59 was also investigated. Objective function consisted of 17 essential parameters such as diameter of heat collector element, collector width, steam generator pinch, approach temperatures, and MED number of effects. Simulation results showed that THERMINOL VP1 had superior properties and produced more desalinated water than other heat transfer fluids. Performance of the plant was analyzed on four characteristic days of the year to show that multiobjective optimization technique can be used to obtain an optimized solution, in which the product flow rate increased, while total investment and O&M costs decreased compared to the base case.

  18. Low Temperature Geothermal Resource Assessment for Membrane Distillation Desalination in the United States: Preprint

    Energy Technology Data Exchange (ETDEWEB)

    Akar, Sertac; Turchi, Craig

    2016-10-01

    Substantial drought and declines in potable groundwater in the United States over the last decade has increased the demand for fresh water. Desalination of saline water such as brackish surface or groundwater, seawater, brines co-produced from oil and gas operations, industrial wastewater, blow-down water from power plant cooling towers, and agriculture drainage water can reduce the volume of water that requires disposal while providing a source of high-quality fresh water for industrial or commercial use. Membrane distillation (MD) is a developing technology that uses low-temperature thermal energy for desalination. Geothermal heat can be an ideal thermal-energy source for MD desalination technology, with a target range of $1/m3 to $2/m3 for desalinated water depending on the cost of heat. Three different cases were analyzed to estimate levelized cost of heat (LCOH) for integration of MD desalination technology with low-grade geothermal heat: (1) residual heat from injection brine at a geothermal power plant, (2) heat from existing underutilized low-temperature wells, and (3) drilling new wells for low-temperature resources. The Central and Western United States have important low-temperature (<90 degrees C) geothermal resource potential with wide geographic distribution, but these resources are highly underutilized because they are inefficient for power production. According to the USGS, there are 1,075 identified low temperature hydrothermal systems, 55 low temperature sedimentary systems and 248 identified medium to high temperature geothermal systems in the United States. The estimated total beneficial heat potential from identified low temperature hydrothermal geothermal systems and residual beneficial heat from medium to high temperature systems is estimated as 36,300 MWth, which could theoretically produce 1.4 to 7 million m3/day of potable water, depending on desalination efficiency.

  19. Low Temperature Geothermal Resource Assessment for Membrane Distillation Desalination in the United States

    Energy Technology Data Exchange (ETDEWEB)

    Akar, Sertac; Turchi, Craig

    2017-05-01

    Substantial drought and declines in potable groundwater in the United States over the last decade has increased the demand for fresh water. Desalination of saline water such as brackish surface or groundwater, seawater, brines co-produced from oil and gas operations, industrial wastewater, blow-down water from power plant cooling towers, and agriculture drainage water can reduce the volume of water that requires disposal while providing a source of high-quality fresh water for industrial or commercial use. Membrane distillation (MD) is a developing technology that uses low-temperature thermal energy for desalination. Geothermal heat can be an ideal thermal-energy source for MD desalination technology, with a target range of $1/m3 to $2/m3 for desalinated water depending on the cost of heat. Three different cases were analyzed to estimate levelized cost of heat (LCOH) for integration of MD desalination technology with low-grade geothermal heat: (1) residual heat from injection brine at a geothermal power plant, (2) heat from existing underutilized low-temperature wells, and (3) drilling new wells for low-temperature resources. The Central and Western United States have important low-temperature (<90 degrees C) geothermal resource potential with wide geographic distribution, but these resources are highly underutilized because they are inefficient for power production. According to the USGS, there are 1,075 identified low temperature hydrothermal systems, 55 low temperature sedimentary systems and 248 identified medium to high temperature geothermal systems in the United States. The estimated total beneficial heat potential from identified low temperature hydrothermal geothermal systems and residual beneficial heat from medium to high temperature systems is estimated as 36,300 MWth, which could theoretically produce 1.4 to 7 million m3/day of potable water, depending on desalination efficiency.

  20. A comparative life cycle assessment of hybrid osmotic dilution desalination and established seawater desalination and wastewater reclamation processes.

    Science.gov (United States)

    Hancock, Nathan T; Black, Nathan D; Cath, Tzahi Y

    2012-03-15

    The purpose of this study was to determine the comparative environmental impacts of coupled seawater desalination and water reclamation using a novel hybrid system that consist of an osmotically driven membrane process and established membrane desalination technologies. A comparative life cycle assessment methodology was used to differentiate between a novel hybrid process consisting of forward osmosis (FO) operated in osmotic dilution (ODN) mode and seawater reverse osmosis (SWRO), and two other processes: a stand alone conventional SWRO desalination system, and a combined SWRO and dual barrier impaired water purification system consisting of nanofiltration followed by reverse osmosis. Each process was evaluated using ten baseline impact categories. It was demonstrated that from a life cycle perspective two hurdles exist to further development of the ODN-SWRO process: module design of FO membranes and cleaning intensity of the FO membranes. System optimization analysis revealed that doubling FO membrane packing density, tripling FO membrane permeability, and optimizing system operation, all of which are technically feasible at the time of this publication, could reduce the environmental impact of the hybrid ODN-SWRO process compared to SWRO by more than 25%; yet, novel hybrid nanofiltration-RO treatment of seawater and wastewater can achieve almost similar levels of environmental impact. Copyright © 2011 Elsevier Ltd. All rights reserved.

  1. Geothermal electricity generation and desalination: an integrated process design to conserve latent heat with operational improvements

    KAUST Repository

    Missimer, Thomas M.

    2016-02-05

    A new process combination is proposed to link geothermal electricity generation with desalination. The concept involves maximizing the utilization of harvested latent heat by passing the turbine exhaust steam into a multiple effect distillation system and then into an adsorption desalination system. Processes are fully integrated to produce electricity, desalted water for consumer consumption, and make-up water for the geothermal extraction system. Further improvements in operational efficiency are achieved by adding a seawater reverse osmosis system to the site to utilize some of the generated electricity and using on-site aquifer storage and recovery to maximize water production with tailoring of seasonal capacity requirements and to meet facility maintenance requirements. The concept proposed conserves geothermally harvested latent heat and maximizes the economics of geothermal energy development. Development of a fully renewable energy electric generation-desalination-aquifer storage campus is introduced within the framework of geothermal energy development. © 2016 The Author(s). Published by Taylor & Francis

  2. COMPLEX USE OF RESOURCES IN THE REGIONAL WATER SUPPLY SYSTEMS

    OpenAIRE

    S. A. ALEXANDRESCU; F. TĂMĂŞANU

    2011-01-01

    Complex use of resources in the regional water supply systems. Regional water supply systems have expanded the range from county to regional level. These are complex works meant to serve the customers from several counties. Viable sources of underground water have become lower in number, quality and volume, due to pollution. Also, the quality indicators of surface water have downgraded because of the pollution. This paper will analyze a typical case of regional system, the water supply system...

  3. Integrated pretreatment and desalination by electrocoagulation (EC)-ion concentration polarization (ICP) hybrid.

    Science.gov (United States)

    Choi, Siwon; Kim, Bumjoo; Han, Jongyoon

    2017-06-13

    Conventional water treatment process is composed of multiple stages, including desalination (salt removal) and pre/post-treatment of desalination to remove particles, chemicals, and other potential foulants for desalination. In this work, we developed a microfluidic proof-of-concept for a single device water treatment system, which removes both salt ions and non-salt contaminants. Our system combines electrocoagulation (EC), a versatile contaminant removal process, and ion concentration polarization (ICP) desalination, which is an electromembrane desalination process. We demonstrated a continuous EC-ICP operation that removed >95% of suspended solids and reduced the salinity from brackish range (20 mM NaCl) to a potable level (<8.6 mM NaCl). We also demonstrated that our system is flexible in terms of the type and concentration of contaminants it can handle. Combining two different electrochemical processes into a single system, we can reduce unnecessary voltage drop by having a shared anode, and achieve both seamless integration and energy efficient operation. Our system will find applications as a small-scale water treatment system, if properly scaled up in the future.

  4. Economic feasibility of a solar still desalination system with enhanced productivity

    KAUST Repository

    Ayoub, George M.

    2014-02-01

    Solar still desalination systems offer sustainable tools for fresh water production. However, their widespread application is often hindered by their relatively low production rates compared to other desalination methods. In this study, a simple amendment, in the form of a slowly-rotating hollow cylinder, was introduced within the solar still, significantly increasing the evaporative surface area. This new modified still was analyzed in terms of both operation and economic feasibility. The introduced cylinder resulted in a 200-300% increase in water output relative to a control, which did not include the cylinder. The resulting percent improvement far exceeds that obtained by other modifications. Unit production cost estimates varied between 6 and 60$/m3 depending on discount rates, productivity, service lifetime and initial capital costs. These projections are well within reported cost ranges for renewable-based technologies. In order to evaluate the system\\'s feasibility in real market value, different scenarios that introduce carbon-trading schemes and environmental degradation costs for fuel-based desalination, were performed. Reported costs for fuel-based brackish water and seawater desalination were thus adjusted to include unaccounted-for costs related to environmental damage. This analysis yielded results that further justify the economic feasibility of the new modified solar still, particularly for seawater desalination. © 2013 Elsevier B.V.

  5. Solar Desalination by Humidification-Dehumidification of Air

    Directory of Open Access Journals (Sweden)

    Moumouh J.

    2018-01-01

    Full Text Available The importance of supplying potable water can hardly be overstressed. In many arid zones, coastal or inlands, seawater or brackish water desalination may be the only solution to the shortage of fresh water. The process based on humidification-dehumidification of air (HDH principle mimic the natural water cycle. HDH technique has been subjected to many studies in recent years due to the low temperature, renewable energy use, simplicity, low cost installation and operation. An experimental test set-up has been fabricated and assembled. The prototype equipped with appropriate measuring and controlling devices. Detailed experiments have been carried out at various operating conditions. The heat and mass transfer coefficients have been obtained experimentally. The results of the investigation have shown that the system productivity increases with the increase in the mass flow rate of water through the unit. Water temperature at condenser exit increases linearly with water temperature at humidifier inlet and it decreases as water flow rate increases. HDH desalination systems realised on also work at atmospheric pressure; hence they do not need mechanical energy except for circulation pumps and fans. These kinds of systems are suitable for developing countries. The system is modular, it is possible to increase productivity with additional solar collectors and additional HDH cycles.

  6. Renewable energy-driven desalination technologies: A comprehensive review on challenges and potential applications of integrated systems

    KAUST Repository

    Ghaffour, Noreddine

    2015-01-01

    Despite the tremendous improvements in conventional desalination technologies, its wide use is still limited due primarily to high energy requirements which are currently met with expensive fossil fuels. The use of alternative energy sources is essential to meet the growing demand for water desalination. In the last few decades a lot of effort has being directed in the use of different renewable energy (RE) sources to run desalination processes. However, the expansion of these efforts towards larger scale plants is hampered by several techno-economic challenges. Several medium-scale RE-driven desalination plants have been installed worldwide. Nevertheless, most of these plants are connected to the electrical grid to assure a continuous energy supply for stable operation. Furthermore, RE is mostly used to produce electric power which can be used to run desalination systems. This review paper focuses on an integrated approach in using RE-driven with an emphasis on solar and geothermal desalination technologies. Innovative and sustainable desalination processes which are suitable for integrated RE systems are presented. An assessment of the benefits of these technologies and their limitations are also discussed.

  7. Environmental assessment of desalination processes: Reverse osmosis and Memstill®

    NARCIS (Netherlands)

    Tarnacki, K.; Meneses, M.; Melin, T.; Medevoort, J. van; Jansen, A.

    2012-01-01

    Desalination becomes in many parts of the world and also in Europe a promising option to combat water stress in water scarce regions. However, also the question of sustainability and environmental impacts of this technology is in focus of numerous studies and discussions. Especially, the focus is

  8. Risk analysis of the sea desalination plant at the 5th refinery of south ...

    African Journals Online (AJOL)

    ... due to water flow shortage. Based on the HAZOP study results expressed here, the start-up procedure was also modified and problems associated with design, several mechanical parts and pipe lines installed were identified and adjusted. Keywords: HAZOP; hazard identity; sea water desalination unit; risk; gas refinery.

  9. Today's and future challenges in applications of renewable energy technologies for desalination

    KAUST Repository

    Goosen, Mattheus F A

    2013-08-28

    Recent trends and challenges in applications of renewable energy technologies for water desalination are critically reviewed with an emphasis on environmental concerns and sustainable development. After providing an overview of wind, wave, geothermal, and solar renewable energy technologies for fresh water production, hybrid systems are assessed. Then scale-up and economic factors are considered. This is followed with a section on regulatory factors, environmental concerns, and globalization, and a final segment on selecting the most suitable renewable energy technology for conventional and emerging desalination processes. © 2014 Copyright Taylor & Francis Group, LLC.

  10. Ruled-based control of off-grid desalination powered by renewable energies

    Directory of Open Access Journals (Sweden)

    Alvaro Serna

    2015-08-01

    Full Text Available A rule-based control is presented for desalination plants operating under variable, renewable power availability. This control algorithm is based on two sets of rules: first, a list that prioritizes the reverse osmosis (RO units of the plant is created, based on the current state and the expected water demand; secondly, the available energy is then dispatched to these units following this prioritized list. The selected strategy is tested on a specific case study: a reverse osmosis plant designed for the production of desalinated water powered by wind and wave energy. Simulation results illustrate the correct performance of the plant under this control.

  11. Fundamental and application aspects of adsorption cooling and desalination

    KAUST Repository

    Saha, Bidyut Baran

    2015-10-23

    Adsorption (AD) cycle is recently pioneered for cooling and desalination applications. For water treatment, the cycle can be used to treat highly concentrated feed water, ranging from seawater, ground water and chemically-laden waste water. This paper presents a review of the recent development of AD cycle and its hybridization with known conventional cycles such as the MED and MSF. We begin by looking at the basic sorption theory for different adsorbent-adsorbate pairs, namely (i) silica gel-water, (ii) the zeolite-water, (iii) parent Maxsorb III/ethanol, (iv) KOH-H2 surface treated Maxsorb III/ethanol, and (v) a metal organic framework (MOF) material namely, MIL-101Cr/ethanol. We also present the basic AD cycle for seawater desalination as well as its hybridization with known conventional thermally-driven cycles for efficiency improvement. We demonstrate the water production improvement by 2-3 folds by hybridization in a pilot comprising a 3-stage MED and AD plant and the top-brine temperature 50oC.

  12. Reverse osmosis desalination of chitosan cross-linked graphene oxide/titania hybrid lamellar membranes.

    Science.gov (United States)

    Deng, Hui; Sun, Penzhan; Zhang, Yingjiu; Zhu, Hongwei

    2016-07-08

    With excellent mass transport properties, graphene oxide (GO)-based lamellar membranes are believed to have great potential in water desalination. In order to quantify whether GO-based membranes are indeed suitable for reverse osmosis (RO) desalination, three sub-micrometer thick GO-based lamellar membranes: GO-only, reduced GO (RGO)/titania (TO) nanosheets and RGO/TO/chitosan (CTS) are prepared, and their RO desalination performances are evaluated in a home-made RO test apparatus. The photoreduction of GO by TO improves the salt rejection, which increases slowly with the membrane thickness. The RGO/TO/CTS hybrid membranes exhibit higher rejection rates of only about 30% (greater than threefold improvement compared with a GO-only membrane) which is still inferior compared to other commercial RO membranes. The low rejection rates mainly arise from the pressure-induced weakening of the ion-GO interlayer interactions. Despite the advantages of simple, low-cost preparation, high permeability and selectivity of GO-based lamellar membranes, as the current desalination performances are not high enough to afford practical application, there still remains a great challenge to realize high performance separation membranes for water desalination applications.

  13. Simultaneous Removal of Phenol and Dissolved Solids from Wastewater Using Multichambered Microbial Desalination Cell.

    Science.gov (United States)

    Pradhan, Harapriya; Jain, Sumat Chand; Ghangrekar, Makarand M

    2015-12-01

    Microbial desalination cell (MDC) has great potential toward direct electricity generation from wastewater and concurrent desalination through potential difference developed due to microbial activity. Degradation of phenol by isolate Pseudomonas aeruginosa in anodic chamber and simultaneous desalination of water in middle desalination chamber of multichamber MDC is demonstrated in this study. Performance of the MDCs with different anodic inoculum conditions, namely pure culture of P. aeruginosa (MDC-1), 50 % v/v mixture of P. aeruginosa and anaerobic mixed consortia (MDC-2) and anaerobic mixed consortia (MDC-3), was evaluated to compare the phenol degradation in anodic chamber, bioelectricity generation, and simultaneous total dissolved solids (TDS) removal from saline water in desalination chamber. Synergistic effect between P. aeruginosa and mixed anaerobic consortia as inoculum was evident in MDC-2 demonstrating phenol degradation of 90 %, TDS removal of 75 % in 72 h of reaction time along with higher power generation of 27.5 mW/m(2) as compared to MDC-1 (95 %, 64 %, 12.8 mW/m(2), respectively) and MDC-3 (58 %, 52 %, 4.8 mW/m(2), respectively). The results illustrate that the multichamber MDC-2 is effective for simultaneous removal of phenol and dissolved solids contained in industrial wastewaters.

  14. Enhancing biodegradation and energy generation via roughened surface graphite electrode in microbial desalination cell.

    Science.gov (United States)

    Ebrahimi, Atieh; Yousefi Kebria, Daryoush; Najafpour Darzi, Ghasem

    2017-09-01

    The microbial desalination cell (MDC) is known as a newly developed technology for water and wastewater treatment. In this study, desalination rate, organic matter removal and energy production in the reactors with and without desalination function were compared. Herein, a new design of plain graphite called roughened surface graphite (RSG) was used as the anode electrode in both microbial fuel cell (MFC) and MDC reactors for the first time. Among the three type of anode electrodes investigated in this study, RSG electrode produced the highest power density and salt removal rate of 10.81 W/m3 and 77.6%, respectively. Such a power density was 2.33 times higher than the MFC reactor due to the junction potential effect. In addition, adding the desalination function to the MFC reactor enhanced columbic efficiency from 21.8 to 31.4%. These results provided a proof-of-concept that the use of MDC instead of MFC would improve wastewater treatment efficiency and power generation, with an added benefit of water desalination. Furthermore, RSG can successfully be employed in an MDC or MFC, enhancing the bio-electricity generation and salt removal.

  15. Reverse osmosis desalination of chitosan cross-linked graphene oxide/titania hybrid lamellar membranes

    Science.gov (United States)

    Deng, Hui; Sun, Penzhan; Zhang, Yingjiu; Zhu, Hongwei

    2016-07-01

    With excellent mass transport properties, graphene oxide (GO)-based lamellar membranes are believed to have great potential in water desalination. In order to quantify whether GO-based membranes are indeed suitable for reverse osmosis (RO) desalination, three sub-micrometer thick GO-based lamellar membranes: GO-only, reduced GO (RGO)/titania (TO) nanosheets and RGO/TO/chitosan (CTS) are prepared, and their RO desalination performances are evaluated in a home-made RO test apparatus. The photoreduction of GO by TO improves the salt rejection, which increases slowly with the membrane thickness. The RGO/TO/CTS hybrid membranes exhibit higher rejection rates of only about 30% (greater than threefold improvement compared with a GO-only membrane) which is still inferior compared to other commercial RO membranes. The low rejection rates mainly arise from the pressure-induced weakening of the ion-GO interlayer interactions. Despite the advantages of simple, low-cost preparation, high permeability and selectivity of GO-based lamellar membranes, as the current desalination performances are not high enough to afford practical application, there still remains a great challenge to realize high performance separation membranes for water desalination applications.

  16. Submerged membrane distillation for seawater desalination

    KAUST Repository

    Francis, Lijo

    2014-08-11

    A submerged membrane distillation (SMD) process for fresh water production from Red Sea water using commercially available hollow fiber membranes has been successfully employed and compared with the conventional direct contact membrane distillation (DCMD) process. The hollow fiber membranes have been characterized for its morphology using field effect scanning electron microscope. In SMD process, a bunch of hollow fiber membranes are glued together at both ends to get a simplified open membrane module assembly submerged into the coolant tank equipped with a mechanical stirrer. Hot feed stream is allowed to pass through the lumen side of the membrane using a feed pump. Continuous stirring at the coolant side will reduce the temperature and concentration polarization. During the conventional DCMD process, using feed-coolant streams with co-current and counter-current flows has been tested and the results are compared in this study. In SMD process, a water vapor flux of 10.2 kg m-2 h-1 is achieved when using a feed inlet temperature of 80°C and coolant temperature of 20°C. Under the same conditions, during conventional DCMD process, a water vapor flux of 11.6 and 10.1 kg m-2 h-1 were observed during counter-current and co-current flow streams, respectively. Results show that the water production in the SMD process is comparable with the conventional DCMD process, while the feed-coolant flow streams are in the co-current direction. During conventional DCMD operation, a 15% increase in the water production is observed when feed-coolant streams are in the counter-current direction compared to the co-current direction. © 2014 © 2014 Balaban Desalination Publications. All rights reserved.

  17. Thermoresponsive magnetic nanoparticles for seawater desalination.

    Science.gov (United States)

    Zhao, Qipeng; Chen, Ningping; Zhao, Dieling; Lu, Xianmao

    2013-11-13

    Thermoresponsive magnetic nanoparticles (MNPs) as a class of smart materials that respond to a change in temperature may by used as a draw solute to extract water from brackish or seawater by forward osmosis (FO). A distinct advantage is the efficient regeneration of the draw solute and the recovery of water via heat-facilitated magnetic separation. However, the osmotic pressure attained by this type of draw solution is too low to counteract that of seawater. In this work, we have designed a FO draw solution based on multifunctional Fe3O4 nanoparticles grafted with copolymer poly(sodium styrene-4-sulfonate)-co-poly(N-isopropylacrylamide) (PSSS-PNIPAM). The resulting regenerable draw solution shows high osmotic pressure for seawater desalination. This is enabled by three essential functional components integrated within the nanostructure: (i) a Fe3O4 core that allows magnetic separation of the nanoparticles from the solvent, (ii) a thermoresponsive polymer, PNIPAM, that enables reversible clustering of the particles for further improved magnetic capturing at a temperature above its low critical solution temperature (LCST), and (iii) a polyelectrolyte, PSSS, that provides an osmotic pressure that is well above that of seawater.

  18. Managed Aquifer Recharge of Surplus Desalinated Seawater: a MARSOL Case Study from Israel

    Science.gov (United States)

    Kurtzman, Daniel; Ganot, Yonatan; Russak, Ammos; Nitzan, Ido; Bernstein, Anat; Katz, Yoram; Guttman, Yossi

    2015-04-01

    MARSOL is an EU-funded project on demonstrating managed aquifer recharge (MAR) as a solution to water scarcity and drought. Among other activities in MARSOL, 7 demo-sites in Mediterranean countries were chosen for research and demonstration of different types of MAR (e.g. soil aquifer treatment, river infiltration basins etc.). One of these demo sites is the Menashe infiltration basin (Israel) in which MAR of surplus desalinated sea water is demonstrated, monitored and investigated in the last year. Different operational circumstances create periods in which water from the Hadera seawater desalination plant cannot be distributed through the national water carrier to consumers. A solution was set in MAR of this water through sandy infiltration ponds to the Israeli coastal aquifer which is consisted mainly from calcareous sandstone. Hydrological and geochemical aspects are of interest in this MAR operation due to the high discharge rates of low-salinity chlorinated water to the infiltration pond. Monitoring of operational events, laboratory experiments, controlled field-experiments and modelling are carried out aiming at clarifying the following issues: infiltration rates - spatial and temporal variability; recharge and withdrawal operation; disinfection by-products due to infiltration of chlorinated water; changes in hydraulic properties due to dissolution/precipitation processes; and using MAR of desalinated water as a remineralization treatment. We will present some results concerning these aspects concentrating on the last one. Observations show that desalinated water dissolve carbonates relatively fast in the unsaturated zone and shallow groundwater of the infiltration site. This process which increases significantly the water's alkalinity also enriches the water with magnesium which its deficiency in desalinated seawater is an unsolved concern. Further increase in calcium and magnesium concentration requires flow in the aquifer through the calcareous

  19. Strategic Co-Location in a Hybrid Process Involving Desalination and Pressure Retarded Osmosis (PRO).

    Science.gov (United States)

    Sim, Victor S T; She, Qianhong; Chong, Tzyy Haur; Tang, Chuyang Y; Fane, Anthony G; Krantz, William B

    2013-07-04

    This paper focuses on a Hybrid Process that uses feed salinity dilution and osmotic power recovery from Pressure Retarded Osmosis (PRO) to achieve higher overall water recovery. This reduces the energy consumption and capital costs of conventional seawater desalination and water reuse processes. The Hybrid Process increases the amount of water recovered from the current 66.7% for conventional seawater desalination and water reuse processes to a potential 80% through the use of reclaimed water brine as an impaired water source. A reduction of up to 23% in energy consumption is projected via the Hybrid Process. The attractiveness is amplified by potential capital cost savings ranging from 8.7%-20% compared to conventional designs of seawater desalination plants. A decision matrix in the form of a customizable scorecard is introduced for evaluating a Hybrid Process based on the importance of land space, capital costs, energy consumption and membrane fouling. This study provides a new perspective, looking at processes not as individual systems but as a whole utilizing strategic co-location to unlock the synergies available in the water-energy nexus for more sustainable desalination.

  20. Strategic Co-Location in a Hybrid Process Involving Desalination and Pressure Retarded Osmosis (PRO)

    Science.gov (United States)

    Sim, Victor S.T.; She, Qianhong; Chong, Tzyy Haur; Tang, Chuyang Y.; Fane, Anthony G.; Krantz, William B.

    2013-01-01

    This paper focuses on a Hybrid Process that uses feed salinity dilution and osmotic power recovery from Pressure Retarded Osmosis (PRO) to achieve higher overall water recovery. This reduces the energy consumption and capital costs of conventional seawater desalination and water reuse processes. The Hybrid Process increases the amount of water recovered from the current 66.7% for conventional seawater desalination and water reuse processes to a potential 80% through the use of reclaimed water brine as an impaired water source. A reduction of up to 23% in energy consumption is projected via the Hybrid Process. The attractiveness is amplified by potential capital cost savings ranging from 8.7%–20% compared to conventional designs of seawater desalination plants. A decision matrix in the form of a customizable scorecard is introduced for evaluating a Hybrid Process based on the importance of land space, capital costs, energy consumption and membrane fouling. This study provides a new perspective, looking at processes not as individual systems but as a whole utilizing strategic co-location to unlock the synergies available in the water-energy nexus for more sustainable desalination. PMID:24956940

  1. Strategic Co-Location in a Hybrid Process Involving Desalination and Pressure Retarded Osmosis (PRO

    Directory of Open Access Journals (Sweden)

    William B. Krantz

    2013-07-01

    Full Text Available This paper focuses on a Hybrid Process that uses feed salinity dilution and osmotic power recovery from Pressure Retarded Osmosis (PRO to achieve higher overall water recovery. This reduces the energy consumption and capital costs of conventional seawater desalination and water reuse processes. The Hybrid Process increases the amount of water recovered from the current 66.7% for conventional seawater desalination and water reuse processes to a potential 80% through the use of reclaimed water brine as an impaired water source. A reduction of up to 23% in energy consumption is projected via the Hybrid Process. The attractiveness is amplified by potential capital cost savings ranging from 8.7%–20% compared to conventional designs of seawater desalination plants. A decision matrix in the form of a customizable scorecard is introduced for evaluating a Hybrid Process based on the importance of land space, capital costs, energy consumption and membrane fouling. This study provides a new perspective, looking at processes not as individual systems but as a whole utilizing strategic co-location to unlock the synergies available in the water-energy nexus for more sustainable desalination.

  2. New solar desalination system using humidification/ dehumidification process

    Energy Technology Data Exchange (ETDEWEB)

    Abdel Dayem, Adel M. [Mechanical Engineering Department, College of Engineering and Islamic Architecture, Umm Al-Qura University, 5555 Makah (Saudi Arabia)

    2013-07-01

    An innovative solar desalination system is successfully designed, manufactured and experimentally tested at Makkah, 21.4 °N. The system consists of 1.15 m2 flat-plate collector as a heat source and a desalination unit. The unit is about 400 liter vertical cylindrical insulated tank. It includes storage, evaporator and condenser of hot salt-water that is fed from the collector. The heated water in the collector is raised naturally to the unit bottom at which it is used as storage. A high pressure pump is used to inject the water vertically up through 1-mm three nozzles inside the unit. The hot salt-water is atomized inside the unit where the produced vapor is condensed on the inner surfaces of the unit outer walls to outside. The system was experimentally tested under different weather conditions. It is obtained that the system can produce about 9 liter a day per quadratic meter of collector surface area. By that it can produce about 1.6 liters per kWh of solar energy. Moreover the water temperature has a great effect on the system performance although the scaling possibility is becoming significant. By that way the cost of a liter water production is relatively high and is obtained as 0.5 US$.

  3. A desalination plant with solar and wind energy

    Science.gov (United States)

    Chen, H.; Ye, Z.; Gao, W.

    2013-12-01

    The shortage of freshwater resources has become a worldwide problem. China has a water shortage, although the total amount of water resources is the sixth in the world, the per capita water capacity is the 121th (a quarter of the world's per capita water capacity), and the United Nations considers China one of the poorest 13 countries in the world in terms of water. In order to increase the supply of fresh water, a realistic way is to make full use of China's long and narrow coastline for seawater desalination. This paper discusses a sea water desalination device, the device adopts distillation, uses the greenhouse effect principle and wind power heating principle, and the two-type start is used to solve the problem of vertical axis wind turbine self-starting. Thrust bearings are used to ensure the stability of the device, and to ensure absorbtion of wind energy and solar energy, and to collect evaporation of water to achieve desalination. The device can absorb solar and wind energy instead of input energy, so it can be used in ship, island and many kinds of environment. Due to the comprehensive utilization of wind power and solar power, the efficiency of the device is more than other passive sea water desalting plants, the initial investment and maintenance cost is lower than active sea water desalting plant. The main part of the device cannot only be used in offshore work, but can also be used in deep sea floating work, so the device can utilise deep sea energy. In order to prove the practicability of the device, the author has carried out theory of water production calculations. According to the principle of conservation of energy, the device ais bsorbing solar and wind power, except loose lost part which is used for water temperature rise and phase transition. Assume the inflow water temperature is 20 °C, outflow water temperature is 70 °C, the energy utilization is 60%, we can know that the water production quantity is 8 kg/ m2 per hour. Comparing with the

  4. Evaluating the Efficiency of Different Microfiltration and Ultrafiltration Membranes Used as Pre-treatment for Reverse Osmosis Desalination of Red Sea Water

    KAUST Repository

    AlMashharawi, Samer

    2011-07-01

    With the increase in population density throughout the world and the growing water demand, innovative methods of providing safe drinking water are of a very high priority. In 2002, the United Nations stated in their millennium declaration that one of their priority goals was “To reduce by half, by the year 2015, the proportion of people who are unable to reach or to afford safe drinking water” [1]. This goal was set with high standards and requires a great deal of water treatment related research in the coming years. Since 1990’s, drinking water treatment via membrane filtration has been widely accepted as a feasible alternative to conventional drinking water treatment. Nowadays, membrane processes are used for separation applications in many industrial applications. Over the past two decades, there has been a rapid growth in the use of low-pressure membrane for drinking water production. These membrane systems are increasingly being accepted as feasible and sustainable technologies for drinking water treatment. Like any innovative process, it has limitations; the primary limitation is membrane fouling, a phenomenon of particles accumulation on the membrane surface and inside its pores. It has the ability to reduce the permeate flux so that higher pumping intensity is required to maintain a consistent volume of product and increasing the cleaning frequency. This project has investigated the rate of reduction in the flux and the increase of pumping intensity using different membranes. Low pressure membranes with three different pore sizes (0.1μm MF, 100kDa UF, and 50kDa UF) have been tested. Eight different filtration configurations have been applied to the membranes including the variation of coagulant (FeCl3) addition aiming mitigation fouling impact in order to maintain consistent permeate flux, while monitoring several water quality parameters before and after treatment such as turbidity, SDI15, total organic carbon (TOC) and particle size distribution

  5. A review of environmental governance and its effects on concentrate discharge from desalination plants in the Kingdom of Saudi Arabia

    KAUST Repository

    Van Der Merwe, Riaan

    2013-01-01

    The most likely environmental impact of concentrate discharges (in most instances twice the concentration of the ambient environment) leaking from desalination plants on local marine ecosystems has been controversially discussed for many years. Increasing water demand and lack of renewable natural water resources in Saudi Arabia also result in greater dependence on desalination and consequently amplify the impact on marine environment and multifactorial ecosystems in near-field areas of desalination discharges. Accurate scientific baseline data should furnish information on various factors such as intake- and outfall locality, brine (concentrate) discharge and chemical characteristics (i.e. effluent concentration, mass flow rates (flux)), local effects, and even cumulative effects of desalination activities, at least on a regional and even on a national scale. Even if such data were available, in many cases they are non-transparent and are not even accessible, or tend to be overlooked as a result of ambiguous desalination-related policies. This paper focuses on national environmental regulations in the Kingdom of Saudi Arabia (KSA) and how such regulations help control the flow of concentrate discharge into the receiving waters. © 2013 Desalination Publications.

  6. High-performance sulfosuccinic acid cross-linked PVA composite pervaporation membrane for desalination.

    Science.gov (United States)

    Zhang, Rui; Liang, Bin; Qu, Ting; Cao, Bing; Li, Pei

    2017-10-25

    Pervaperation (PV), as a novel technology, has shown great promise in fresh water production from salty water. However, the low water flux of the present membranes hinders their practical applications. Here, a new type of PV composite membrane, consisting of a selective skin layer fabricated from poly(vinyl alcohol) (PVA) cross-linked by sulfosuccinic acid and a porous support layer using a commercial polyacrylonitrile (PAN) ultrafiltration membrane, was developed for applications in desalination. The separation performance of S-PVA/PAN composite PV membranes with different S-PVA layer thicknesses was tested in detail. The best result showed a water flux of 27.9 kg m-2 h-1 with a salt rejection of 99.8%, which was obtained at a vacuum of 100 Pa and temperature of 70°C when separating a 35,000 ppm NaCl solution. The S-PVA/PAN composite membranes could also be used for the desalination of high-concentration (100,000 ppm) NaCl solutions with a water flux of 11.2 kg m-2 h-1 with a salt rejection of 99.8%. Moreover, a stable desalination performance was obtained for a 120 h operation time. This study shows the possibility of using PV in desalination applications for seawater, brackish water and reverse osmosis concentrate treatment.

  7. Seawater desalination as an option to alleviate water scarcity in South Africa: the need for a strategic approach to planning and environmental decision-making

    CSIR Research Space (South Africa)

    Schreiner, GO

    2014-04-01

    Full Text Available /district municipalities and provincial authorities, are undertaking studies to explore the feasibility of SWRO to meet growing demand and relieve mounting pressure on current bulk water supply infrastructure. With this in mind, it is suggested that national strategic...

  8. Pushing desalination recovery to the maximum limit: Membrane and thermal processes integration

    KAUST Repository

    Shahzad, Muhammad Wakil

    2017-05-05

    The economics of seawater desalination processes has been continuously improving as a result of desalination market expansion. Presently, reverse osmosis (RO) processes are leading in global desalination with 53% share followed by thermally driven technologies 33%, but in Gulf Cooperation Council (GCC) countries their shares are 42% and 56% respectively due to severe feed water quality. In RO processes, intake, pretreatment and brine disposal cost 25% of total desalination cost at 30–35% recovery. We proposed a tri-hybrid system to enhance overall recovery up to 81%. The conditioned brine leaving from RO processes supplied to proposed multi-evaporator adsorption cycle driven by low temperature industrial waste heat sources or solar energy. RO membrane simulation has been performed using WinFlow and IMSDesign commercial softwares developed by GE and Nitto. Detailed mathematical model of overall system is developed and simulation has been conducted in FORTRAN. The final brine reject concentration from tri-hybrid cycle can vary from 166,000ppm to 222,000ppm if RO retentate concentration varies from 45,000ppm to 60,000ppm. We also conducted economic analysis and showed that the proposed tri-hybrid cycle can achieve highest recovery, 81%, and lowest energy consumption, 1.76kWhelec/m3, for desalination reported in the literature up till now.

  9. Thermodynamical research of using solar energy for desalination of seawater

    Directory of Open Access Journals (Sweden)

    Arsović Marjan R.

    2015-01-01

    Full Text Available Many regions of the world face the problem of saline water. Water desalination processes, which require significant energy consumption, are a common solution to produce drinking water. This study evaluated the influence of the following process operational parameters on the energy consumption of seawater RO systems: water salinity, permeate recovery ratio, membrane performance and feed water temperature. Optimal operational conditions for the theoretical minimum energy consumption were determined with experiments by varying water qualities and operational parameters. In order to further reduce energy consumption a RO system was integrated with a PV solar system and a pilot PVRO system was built and tested. The results obtained from this study indicated that even though a Solar PV system incurs a huge initial capital investment, it will yield significant benefits in the long run of the RO operational period.

  10. Wind energy and desalination in the context of Mauritania; Energie eolienne et dessalement dans le contexte mauritanien

    Energy Technology Data Exchange (ETDEWEB)

    Semega, B.M. [Nouakchott Univ., (Mauritania). Faculty of Science and Technology

    2008-04-15

    This article discussed the feasibility of using wind power for the desalination of sea water in the African country of Mauritania, where potable water is extremely scarce. Renewable energy, particularly solar and wind energy, may hold the solution to this developing country's economic and social development as well as its environmental concerns. Although wind power technology has developed rapidly in the past decade in Mauritania, the desalination process using wind power remains relatively unknown. Desalination of sea water can be performed by distillation or through reverse osmosis. From 1968 to 1974, Mauritania relied on the distillation process for its drinking water, but the procedure was then stopped because of maintenance problems and high energy costs. In 1984, the town of Guelb installed the first reverse osmosis facility. Many other desalination projects were subsequently installed to take advantage of sea water as a resource to produce drinking water. These other desalination processes which used solar or thermal energy are more costly than wind power. It was concluded that the combination of wind power and reverse osmosis could reduce the price of salt water by 30 per cent or more. 11 refs., 2 tabs., 4 figs.

  11. A portable and high energy efficient desalination/purification system by ion concentration polarization

    Science.gov (United States)

    Kim, Sung Jae; Kim, Bumjoo; Kwak, Rhokyun; Kim, Geunbae; Han, Jongyoon

    2012-10-01

    The shortage of fresh water is one of the acute challenges that the world is facing now and, thus, energy efficient desalination strategies can provide substantial answers for the water-crisis. Current desalination methods utilizing reverse-osmosis and electrodialysis mechanisms required high power consumptions/large-scale infrastructures which do not make them appropriate for disaster-stricken area or underdeveloped countries. In addition, groundwater contamination by heavy metal compounds, such as arsenic, cadmium and lead, poses significant public health challenges, especially in developing countries. Existing water purification strategies for heavy metal removal are not readily applicable due to technological, environmental, and economical barriers. This presentation elucidates a novel desalination/purification process, where a continuous contaminated stream is divided into filtered and concentrated stream by the ion concentration polarization. The key distinct feature is that both salts and larger particles (cells, viruses, and microorganisms) are pushed away from the membrane, in continuous flow operations, eliminating the membrane fouling that plagues the membrane filtration methods. The power consumption is less than 5Wh/L, comparable to any existing systems. The energy and removal efficiency, and low cost manufacturability hold strong promises for portable, self-powered water purification/desalination system that can have significant impacts on water shortage in developing/rural part of the world.

  12. Investigation of polyvinylchloride and cellulose acetate blend membranes for desalination

    Science.gov (United States)

    El-Gendi, Ayman; Abdallah, Heba; Amin, Ashraf; Amin, Shereen Kamel

    2017-10-01

    The pollution of water resources, severe climate changes, rapid population growth, increasing agricultural demands, and rapid industrialization insist the development of innovative technologies for generating potable water. Polyvinylchloride/cellulose acetate (PVC/CA) membranes were prepared using phase inversion technique for seawater reverse osmosis (SWRO). The membrane performance was investigated using Red Sea water (El-Ein El-Sokhna-Egypt). The membrane performance indicated that the prepared membranes were endowed to work under high pressure; increasing in feeding operating pressure led to increase permeate flux and rejection. Increasing feed operating pressure from zero to 40 bar led to increase in the salt rejection percent. Salt rejection percent reached to 99.99% at low feed concentration 5120 ppm and 99.95% for Red Sea water (38,528 ppm). The prepared membranes were characterized using scanning electron microscopy (SEM), Fourier transform infrared (FTIR) spectrophotometry, and mechanical properties. SEM, FTIR and mechanical results were used to distinguish the best membrane for desalination. According to characterization results, one prepared membrane was selected to run performance test in desalination testing unit. The membrane (M3) showed excellent performance and stability under different operating conditions and during the durability test for 36 days.

  13. Developments in solar still desalination systems: A critical review

    KAUST Repository

    Ayoub, George M.

    2012-10-01

    Solar still desalination uses a sustainable and pollution-free source to produce high-quality water. The main limitation is low productivity and this has been the focus of intensive research. A major concern while increasing productivity is to maintain economic feasibility and simplicity. The authors present a critical review of the research work conducted on solar stills development. Studies addressing each parameter of concern are grouped together and results compared. Novelty in design and newly introduced features are presented. Modeling efforts of flow circulation within the still and methods to estimate internal heat transfer coefficients are discussed and future research needs are outlined. © 2012 Taylor & Francis Group, LLC.

  14. Drinking desalinated seawater for a long time induces anomalies in the development of new-born albino rats

    Directory of Open Access Journals (Sweden)

    Ahmed A. Allam

    2017-09-01

    Full Text Available The present study aimed to elucidate the abnormalities in the development of rat brains, livers, kidney and behaviours after drinking desalinated seawater prenatally. Three types of drinking water were employed as an experimental probe (bottled water, filtered desalinated seawater and tap desalinated seawater to investigate neurobehavioral and morphological changes in the development of pup rats. Female rats from each group were administered water from their birth until gestation and lactation. The 1st and 2nd generation pups were divided into three groups: Group C, mothers and pups administered with bottled drinking water (the control group; Group F, mothers and pups administered with filtered drinking water; Group T, mothers and pups administered with unfiltered desalinated seawater (tap water. Morphological changes (CNS aberration and neurobehavioral changes were studied. The aberrations recorded in the tissues (brain, liver, kidney and spinal cord of rats from groups T and F may be due to oxidative stress in these tissues such as reduced glutathione, lipid peroxidation, peroxidase and super oxide dismutase. In conclusion, drinking desalinated seawater for a long time may cause teratogenic effects in the development of New-born rats.

  15. Minimizing the Environmental Impact of Sea Brine Disposal by Coupling Desalination Plants with Solar Saltworks: A Case Study for Greece

    Directory of Open Access Journals (Sweden)

    Stylianos Gialis

    2010-02-01

    Full Text Available The explosive increase in world population, along with the fast socio-economic development, have led to an increased water demand, making water shortage one of the greatest problems of modern society. Countries such as Greece, Saudi Arabia and Tunisia face serious water shortage issues and have resorted to solutions such as transporting water by ships from the mainland to islands, a practice that is expensive, energy-intensive and unsustainable. Desalination of sea-water is suitable for supplying arid regions with potable water, but extensive brine discharge may affect marine biota. To avoid this impact, we explore the option of directing the desalination effluent to a solar saltworks for brine concentration and salt production, in order to achieve a zero discharge desalination plant. In this context, we conducted a survey in order to evaluate the potential of transferring desalination brine to solar saltworks, so that its disposal to the sea is avoided. Our analysis showed that brine transfer by trucks is prohibitively expensive. In order to make the zero discharge desalination plant economically feasible, efforts should be directed into developing a more efficient technology that will result in the production of only a fraction of the brine that is produced from our systems today.

  16. A Plan to Develop a Red Tide Warning System for Seawater Desalination Process Management

    Science.gov (United States)

    Kim, Tae Woo; Yun, Hong Sik

    2017-04-01

    The holt of the seawater desalination process for fifty five days due to the eight-month long red tide in 2008 in the Persian Gulf, the Middle East, had lost about 10 billion KRW. The POSCO Seawater Desalination facility, located in Gwangyang Bay Area in the Southern Sea, has produced 30,000 tons of fresh water per day since 2014. Since there has been an incident of red time in the area for three months in August, 2012, it is necessary to establish a warning system for red tide that threatens the stable operation of the seawater desalination facility. A red tide warning system can offer the seawater desalination facility manager customized services on red tide information and potential red tide inflow to the water intake. This study aimed to develop a red tide warning system in Gwangyang Bay Area by combining RS, modeling and monitoring technologies, which provides red tide forecasting information with which to effectively control the seawater desalination process. Using the proposed system, the seawater desalination facility manager can take phased measures to cope with the inflow of red tide. ACKNOWLEDGMENTS This research was supported by a grant(16IFIP-C088924-03) from Industrial Facilities & Infrastructure Research Program funded by Ministry of Land, Infrastructure and Transport(MOLIT) of the Korea government and the Korea Agency for Infrastructure Technology Advancement (KAIA). This research was supported by Basic Science Research Program through the National Research Foundation of Korea(NRF) funded by the Ministry of Education(NRF-2014R1A1A2054975).

  17. Desalination by electrodialysis using a stack of charged hydrogels in a microfluidic platform

    NARCIS (Netherlands)

    Gümüscü, B.; Haase, A. Sander; Benneker, Anne Maria; van den Berg, Albert; Lammertink, Rob G.H.; Eijkel, Jan C.T.

    2016-01-01

    We show a new approach for desalinating water, using a stack of periodic hydrogel structures in a microfluidic platform. This technique utilizes alternating anion- (AEH) and cation-exchange hydrogels (CEH) locally fabricated in confined compartments by capillary line pinning. Parallel streams of

  18. Functionalized thermo-responsive microgels for high performance forward osmosis desalination.

    Science.gov (United States)

    Hartanto, Yusak; Yun, Seonho; Jin, Bo; Dai, Sheng

    2015-03-01

    Stimuli-responsive hydrogels were recently proposed for energy-saving forward osmosis (FO) process. However, their low water flux and dewatering ability for reuse make them less attractive for industrial desalination process. In this work, the co-polymer microgels of N-isopropylacrylamide and acrylic acid with different mixing ratios were synthesized using surfactant-free emulsion polymerization to produce submicron-size hydrogels with high surface area and fast swelling-deswelling response. The microgels were employed as draw agents in a laboratory scale FO desalination system. The microgel-based FO process performed a high water flux up to 23.8 LMH and high water recovery ability of 72.4%. In addition, we explored a new conductivity measurement method to online analyze water flux of the FO system. This on-line conductivity analysis approach appeared to be an accurate and efficient method for evaluating microgel-based FO desalination performance. Our experimental data revealed that the stimuli-responsive microgel was an efficient draw agent for FO desalination. Copyright © 2014 Elsevier Ltd. All rights reserved.

  19. Direct prediction of the desalination performance of porous carbon electrodes for capacitive deionization

    NARCIS (Netherlands)

    Porada, S.; Borchardt, D.; Oschatz, M.; Bryjak, M.; Atchison, J.S.; Keesman, K.J.; Kaskel, S.; Biesheuvel, P.M.; Presser, V.

    2013-01-01

    Desalination by capacitive deionization (CDI) is an emerging technology for the energy- and cost-efficient removal of ions from water by electrosorption in charged porous carbon electrodes. A variety of carbon materials, including activated carbons, templated carbons, carbon aerogels, and carbon

  20. Efficient photochemistry of coronene:water complexes

    Science.gov (United States)

    Noble, J. A.; Jouvet, C.; Aupetit, C.; Moudens, A.; Mascetti, J.

    2017-03-01

    The photochemistry of ices with polycyclic aromatic hydrocarbons (PAHs) has been extensively studied, but to date no investigation has been made of PAHs in interaction with low numbers (nPAH photoproducts, and we postulate a reaction mechanism via a charge transfer Rydberg state. This result suggests that oxygenated PAHs should be widely observed in regions of the ISM with sufficiently high water abundances, for example near the edges of molecular clouds where water molecules begin to form, but before icy layers are observed, that is at AVPAHs, additional destruction routes must be invoked.

  1. Biodegradation of complex bacteria on phenolic derivatives in river water.

    Science.gov (United States)

    Lu, Guang-Hua; Wang, Chao; Sun, Zhe

    2009-04-01

    To isolate, incubate, and identify 4-chlorophenol-degrading complex bacteria, determine the tolerance of these bacteria to phenolic derivatives and study their synergetic metabolism as well as the aboriginal micrpbes and co-metabolic degradation of mixed chlorophenols in river water. Microbial community of complex bacteria was identified by plate culture observation techniques and Gram stain method. Bacterial growth inhibition test was used to determine the tolerance of complex bacteria to toxicants. Biodegradability of phenolic derivatives was determined by adding 4-chlorophenol-degrading bacteria in river water. The complex bacteria were identified as Mycopiana, Alcaligenes, Pseudomonas, and Flavobacterium. The domesticated complex bacteria were more tolerant to phenolic derivatives than the aboriginal bacteria from Qinhuai River. The biodegradability of chlorophenols, dihydroxybenzenes and nitrophenols under various aquatic conditions was determined and compared. The complex bacteria exhibited a higher metabolic efficiency on chemicals than the aboriginal microbes, and the final removal rate of phenolic derivatives was increased at least by 55% when the complex bacteria were added into river water. The metabolic relationship between dominant mixed bacteria and river bacteria was studied. The complex bacteria domesticated by 4-chlorophenol can grow and be metabolized to take other chlorophenols, dihydroxybenzenes and nitrophenols as the sole carbon and energy source. There is a synergetic metabolism of most compounds between the aboriginal microbes in river water and the domesticated complex bacteria. 4-chlorophenol-degrading bacteria can co-metabolize various chlorophenols in river water.

  2. Harmful algae and their potential impacts on desalination operations off southern California.

    Science.gov (United States)

    Caron, David A; Garneau, Marie-Eve; Seubert, Erica; Howard, Meredith D A; Darjany, Lindsay; Schnetzer, Astrid; Cetinić, Ivona; Filteau, Gerry; Lauri, Phil; Jones, Burton; Trussell, Shane

    2010-01-01

    Seawater desalination by reverse osmosis (RO) is a reliable method for augmenting drinking water supplies. In recent years, the number and size of these water projects have increased dramatically. As freshwater resources become limited due to global climate change, rising demand, and exhausted local water supplies, seawater desalination will play an important role in the world's future water supply, reaching far beyond its deep roots in the Middle East. Emerging contaminants have been widely discussed with respect to wastewater and freshwater sources, but also must be considered for seawater desalination facilities to ensure the long-term safety and suitability of this emerging water supply. Harmful algal blooms, frequently referred to as 'red tides' due to their vibrant colors, are a concern for desalination plants due to the high biomass of microalgae present in ocean waters during these events, and a variety of substances that some of these algae produce. These compounds range from noxious substances to powerful neurotoxins that constitute significant public health risks if they are not effectively and completely removed by the RO membranes. Algal blooms can cause significant operational issues that result in increased chemical consumption, increased membrane fouling rates, and in extreme cases, a plant to be taken off-line. Early algal bloom detection by desalination facilities is essential so that operational adjustments can be made to ensure that production capacity remains unaffected. This review identifies the toxic substances, their known producers, and our present state of knowledge regarding the causes of toxic episodes, with a special focus on the Southern California Bight. (c) 2009 Elsevier Ltd. All rights reserved.

  3. The techno-economic optimization of a 100MWe CSP-desalination plant in Arandis, Namibia

    Science.gov (United States)

    Dall, Ernest P.; Hoffmann, Jaap E.

    2017-06-01

    Energy is a key factor responsible for a country's economic growth and prosperity. It is closely related to the main global challenges namely: poverty mitigation, global environmental change and food and water security [1.]. Concentrating solar power (CSP) is steadily gaining more market acceptance as the cost of electricity from CSP power plants progressively declines. The cogeneration of electricity and water is an attractive prospect for future CSP developments as the simultaneous production of power and potable water can have positive economic implications towards increasing the feasibility of CSP plant developments [2.]. The highest concentrations of direct normal irradiation are located relatively close to Western coastal and Middle-Eastern North-African regions. It is for this reason worthwhile investigating the possibility of CSP-desalination (CSP+D) plants as a future sustainable method for providing both electricity and water with significantly reduced carbon emissions and potential cost reductions. This study investigates the techno-economic feasibility of integrating a low-temperature thermal desalination plant to serve as the condenser as opposed to a conventional dry-cooled CSP plant in Arandis, Namibia. It outlines the possible benefits of the integration CSP+D in terms of overall cost of water and electricity. The high capital costs of thermal desalination heat exchangers as well as the pumping of seawater far inland is the most significant barrier in making this approach competitive against more conventional desalination methods such as reverse osmosis. The compromise between the lowest levelized cost of electricity and water depends on the sizing and the top brine temperature of the desalination plant.

  4. Life-cycle cost analysis of adsorption cycles for desalination

    KAUST Repository

    Thu, Kyaw

    2010-08-01

    This paper presents the thermo-economic analysis of the adsorption desalination (AD) cycle that is driven by low-temperature waste heat from exhaust of industrial processes or renewable sources. The AD cycle uses an adsorbent such as the silica gel to desalt the sea or brackish water. Based on an experimental prototype AD plant, the life-cycle cost analysis of AD plants of assorted water production capacities has been simulated and these predictions are translated into unit cost of water production. Our results show that the specific energy consumption of the AD cycle is 1.38 kWh/m3 which is the lowest ever reported. For a plant capacity of 1000 m3/d, the AD cycle offers a unit cost of $0.457/m3 as compared to more than $0.9 for the average RO plants. Besides being cost-effective, the AD cycle is also environment-friendly as it emits less CO2 emission per m3 generated, typically 85% less, by comparison to an RO process. © 2010 Desalination Publications.

  5. [Algolization of drinkable water basins in Nizhny Tagil industrial complex].

    Science.gov (United States)

    Kul'nev, V V; Pochechun, V A

    2016-01-01

    The article covers experience of biologic rehabilitation through correction of algocenosis (algolization) of drinkable water basins in Nizhny Tagil industrial complex. Biologic rehabilitation of Chernoistochnik and Verhne-Vyisky drinkable water basins in 2011-2012 considerably improved water quality in ecologic hydrochemical and hydrobiologic parameters--that was proved by absent water contamination with blue-green algae, lower saprobiont index. Results also are significant lower concentration of pollutants--heavy metals (ferrum, manganese, copper), oil products, decreased odor and and better water quality in hydrochemical parameters to second class according to water pollution index.

  6. Graphene-based Recyclable Photo-Absorbers for High-Efficiency Seawater Desalination.

    Science.gov (United States)

    Wang, Xiangqing; Ou, Gang; Wang, Ning; Wu, Hui

    2016-04-13

    Today's scientific advances in water desalination dramatically increase our ability to transform seawater into fresh water. As an important source of renewable energy, solar power holds great potential to drive the desalination of seawater. Previously, solar assisted evaporation systems usually relied on highly concentrated sunlight or were not suitable to treat seawater or wastewater, severely limiting the large scale application of solar evaporation technology. Thus, a new strategy is urgently required in order to overcome these problems. In this study, we developed a solar thermal evaporation system based on reduced graphene oxide (rGO) decorated with magnetic nanoparticles (MNPs). Because this material can absorb over 95% of sunlight, we achieved high evaporation efficiency up to 70% under only 1 kW m(-2) irradiation. Moreover, it could be separated from seawater under the action of magnetic force by decorated with MNPs. Thus, this system provides an advantage of recyclability, which can significantly reduce the material consumptions. Additionally, by using photoabsorbing bulk or layer materials, the deposition of solutes offen occurs in pores of materials during seawater desalination, leading to the decrease of efficiency. However, this problem can be easily solved by using MNPs, which suggests this system can be used in not only pure water system but also high-salinity wastewater system. This study shows good prospects of graphene-based materials for seawater desalination and high-salinity wastewater treatment.

  7. Novel Microbial Electrochemical Technologies and Microorganisms for Power Generation and Desalination

    KAUST Repository

    Chehab, Noura A.

    2014-12-01

    Global increases in water demand and decreases in both the quantity and quality of fresh water resources have served as the major driving forces to develop sustainable use of water resources. One viable alternative is to explore non-traditional (impaired quality) water sources such as wastewater and seawater. The current paradigm for wastewater treatment is based on technologies that are energy intensive and fail to recover the potential resources (water and energy) in wastewater. Also, conventional desalination technologies like reverse osmosis (RO) are energy intensive. Therefore, there is a need for the development of sustainable wastewater treatment and desalination technologies for practical applications. Processes based on microbial electrochemical technologies (METs) such as microbial fuel cells (MFCs), microbial electrolysis cells (MECs) and microbial desalination cells (MDCs) hold promise for the treatment of wastewater with recovery of the inherent energy, and MDCs could be used for both desalination of seawater and energy recovery. METs use anaerobic bacteria, referred to as exoelectrogens, that are capable of transferring electrons exogenously to convert soluble organic matter present in the wastewater directly into an electrical current to produce electrical power (MFC and MDC) or biogas (MEC). In my dissertation, I investigated the three types of METs mentioned above to: 1) have a better insight on the effect of 4 oxygen intrusion on the microbial community structure and performance of air-cathode MFCs; 2) improve the desalination efficiency of air-cathode MDCs using ion exchange resins (IXRs); and 3) enrich for extremophilic exoelectrogens from the Red Sea brine pool using MECs. The findings from these studies can shape further research aimed at developing more efficient air-cathode MFCs for practical applications, a more efficient integrated IXRMDC configuration that can be used as a pre-treatment to RO, and exploring extreme environments as a

  8. Development of a Desalination Membrane Bioinspired by Mangrove Roots for Spontaneous Filtration of Sodium Ions.

    Science.gov (United States)

    Kim, Kiwoong; Kim, Hyejeong; Lim, Jae Hong; Lee, Sang Joon

    2016-12-27

    The shortage of available fresh water is one of the global issues presently faced by humanity. To determine a solution to this problem, the survival strategies of plants have been examined. In this study, a nature-inspired membrane with a highly charged surface is proposed as an effective membrane for the filtration of saline water. To mimic the desalination characteristics of mangrove roots, a macroporous membrane based on polyethylene terephthalate is treated with polyelectrolytes using a layer-by-layer deposition method. The fabricated membrane surface has a highly negative charged ζ-potential value of -97.5 ± 4.3 mV, similar to that of the first layer of mangrove roots. Desalination of saline water using this membrane shows a high salt retention rate of 96.5%. The highly charged surface of the membrane may induce a relatively thick and stable ion depletion zone in front of the membrane. As a result, most co-ions are repelled from the membrane surface, and counterions are also rejected by virtue of their electroneutrality. The water permeability is found to be 7.60-7.69 L/m2·h, which is 10 times higher than that of the reverse osmosis desalination method. This nature-inspired filtration membrane exhibits steady desalination performance over 72 h of operation, successfully demonstrating the stable filtration of saline water. This nature-inspired membrane is applicable to the design of a small-scale, portable, and energy-free desalination device for use in third-world countries or small villages.

  9. Unintended Consequences of Water Legislation

    OpenAIRE

    Yow, Shauna

    2008-01-01

    The population of Texas is expected to double by 2060. The Texas Lower Rio Grande Valley is one area in which alternative water sources and potable treatment methods are being sought to support a rapid population growth. An emerging and promising approach to expanding potable water supplies is brackish groundwater desalination. Due to recent technology developments in desalination membranes and increasing prices of surface water rights, the economics of desalination have become competitive wi...

  10. Fair Water Allocation in Complex International River Systems

    Science.gov (United States)

    Beck, L.; Bernauer, T.

    2011-12-01

    Conflicts over water allocation in international freshwater systems are recurring phenomena, and climatic changes are likely to make existing problems worse in many parts of the world. Science-based proposals for water allocation frequently focus on allocating water to the economically most efficient purposes. In reality, allocation outcomes are often shaped by political and economic power, rather than considerations of economic efficiency. This paper develops a new approach to fair international water allocation in complex international freshwater systems. This approach covers both needs-based criteria - if acute water scarcity is present - and criteria for fair water allocation pertaining to relative gains in water-abundant situations. The usefulness of the approach is illustrated with a case study on the Zambezi River Basin (ZRB). Based on a hydrological model, and scenarios for water availability and demand in the ZRB until 2050, the paper shows how the waters of the ZRB could be allocated in a way that fairly distributes costs and benefits.

  11. Electrochemical desalination of bricks - Experimental and modeling

    DEFF Research Database (Denmark)

    Skibsted, Gry; Ottosen, Lisbeth M.; Jensen, Pernille Erland

    2015-01-01

    Chlorides, nitrates and sulfates play an important role in the salt-decay of porous materials in buildings and monuments. Electrochemical desalination is a technology able to remove salts from such porous materials in order to stop or prevent the decay. In this paper, experimental and numerical......-contaminated bricks with respect to the monovalent ions is discussed. Comparison between the experimental and the simulation results showed that the proposed numerical model is able to predict electrochemical desalination treatments with remarkable accuracy, and it can be used as a predictive tool...

  12. A conceptual demonstration of freeze desalination-membrane distillation (FD-MD) hybrid desalination process utilizing liquefied natural gas (LNG) cold energy.

    Science.gov (United States)

    Wang, Peng; Chung, Tai-Shung

    2012-09-01

    The severe global water scarcity and record-high fossil oil price have greatly stimulated the research interests on new desalination technologies which can be driven by renewable energy or waste energy. In this study, a hybrid desalination process comprising freeze desalination and membrane distillation (FD-MD) processes was developed and explored in an attempt to utilize the waste cold energy released from re-gasification of liquefied natural gas (LNG). The concept of this technology was demonstrated using indirect-contact freeze desalination (ICFD) and direct-contact membrane distillation (DCMD) configurations. By optimizing the ICFD operation parameters, namely, the usage of nucleate seeds, operation duration and feed concentration, high quality drinkable water with a low salinity ∼0.144 g/L was produced in the ICFD process. At the same time, using the optimized hollow fiber module length and packing density in the DCMD process, ultra pure water with a low salinity of 0.062 g/L was attained at a condition of high energy efficiency (EE). Overall, by combining FD and MD processes and adopting the optimized operation parameters, the hybrid FD-MD system has been successfully demonstrated. A high total water recovery of 71.5% was achieved, and the water quality obtained met the standard for drinkable water. In addition, with results from specific energy calculation, it was proven that the hybrid process is an energy-saving process and utilization of LNG cold energy could greatly reduce the total energy consumption. Copyright © 2012 Elsevier Ltd. All rights reserved.

  13. The calculation of desalination of mineralized porous ice at thawing

    Directory of Open Access Journals (Sweden)

    A. V. Sosnovsky

    2016-01-01

    Full Text Available The results obtained in this work demonstrate that dynamics of desalination of porous ice depends on a mobility of ions of salts, and the mobility is determined by the diffusion coefficient. The ice was made by freezing of mineralized water of different chemical composition. Model calculations of average mineralization of the porous ice at its thawing were made, and the ion concentrations of different salts were defined. Values of the diffusion coefficients of the salt ions in the film of brine ice pellets were obtained by means of comparison of results of measurements and calculations of dynamics of content of the salt ions in a porous ice at its thawing. The diffusion coefficient of ions Na+, Cl−, SO4 2− is by order of magnitude larger than that of Ca2+ and by two orders of magnitudethan HCO3 −. This results in that the content of ions Na+, Cl−, SO42− decreases in porous ice at its thawing 3 times faster than the content of the ions Ca2+. Basing on analysis of chemical composition of drainage water in some regions in Russia a possibility to desalinate the porous ice formed during the winter sprinkling is demonstrated.

  14. Effects of drinking desalinated seawater on cell viability and proliferation.

    Science.gov (United States)

    Macarrão, Camila Longhi; Bachi, André Luis Lacerda; Mariano, Mario; Abel, Lucia Jamli

    2017-06-01

    Desalination of seawater is becoming an important means to address the increasing scarcity of freshwater resources in the world. Seawater has been used as drinking water in the health, food, and medical fields and various beneficial effects have been suggested, although not confirmed. Given the presence of 63 minerals and trace elements in drinking desalinated seawater (63 DSW), we evaluated their effects on the behavior of tumorigenic and nontumorigenic cells through the 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyl tetrazolium bromide assay and annexin-V-fluorescein isothiocyanate/propidium iodide staining. Our results showed that cell viability and proliferation in the presence of 63 DSW were significantly greater than in mineral water and in the presence of fetal bovine serum in a dose-dependent manner. Furthermore, 63 DSW showed no toxic effect on murine embryonic fibroblast (NIH-3T3) and murine melanoma (B16-F10) cells. In another assay, we also showed that pre-treatment of non-adherent THP-1 cells with 63 DSW reduces apoptosis incidence, suggesting a protective effect against cell death. We conclude that cell viability and proliferation were improved by the mineral components of 63 DSW and this effect can guide further studies on health effects associated with DSW consumption.

  15. Life cycle cost of a hybrid forward osmosis – low pressure reverse osmosis system for seawater desalination and wastewater recovery

    KAUST Repository

    Valladares Linares, Rodrigo

    2015-10-19

    In recent years, forward osmosis (FO) hybrid membrane systems have been investigated as an alternative to conventional high-pressure membrane processes (i.e. reverse osmosis (RO)) for seawater desalination and wastewater treatment and recovery. Nevertheless, their economic advantage in comparison to conventional processes for seawater desalination and municipal wastewater treatment has not been clearly addressed. This work presents a detailed economic analysis on capital and operational expenses (CAPEX and OPEX) for: i) a hybrid forward osmosis – low-pressure reverse osmosis (FO-LPRO) process, ii) a conventional seawater reverse osmosis (SWRO) desalination process, and iii) a membrane bioreactor – reverse osmosis – advanced oxidation process (MBR-RO-AOP) for wastewater treatment and reuse. The most important variables affecting economic feasibility are obtained through a sensitivity analysis of a hybrid FO-LPRO system. The main parameters taken into account for the life cycle costs are the water quality characteristics (similar feed water and similar water produced), production capacity of 100,000 m3 d−1 of potable water, energy consumption, materials, maintenance, operation, RO and FO module costs, and chemicals. Compared to SWRO, the FO-LPRO systems have a 21% higher CAPEX and a 56% lower OPEX due to savings in energy consumption and fouling control. In terms of the total water cost per cubic meter of water produced, the hybrid FO-LPRO desalination system has a 16% cost reduction compared to the benchmark for desalination, mainly SWRO. Compared to the MBR-RO-AOP, the FO-LPRO systems have a 7% lower CAPEX and 9% higher OPEX, resulting in no significant cost reduction per m3 produced by FO-LPRO. Hybrid FO-LPRO membrane systems are shown to have an economic advantage compared to current available technology for desalination, and comparable costs with a wastewater treatment and recovery system. Based on development on FO membrane modules, packing density, and

  16. Ecotoxicology of waters under the influence of a petrochemical complex

    Energy Technology Data Exchange (ETDEWEB)

    Noll, R.; Zandonai, V.; Ries, M.A. [CORSAN-SITEL, Triunfo, RS (Brazil). Polo Petrquimico do Sul

    1993-12-31

    This work summarizes the regular monitoring and studies conducted by SITEL - The Integrated Wastewater Treatment System of South Petrochemical Complex (South Brazil) - in order to evaluate the full environmental impact on waters in the area of influence of the effluents of the above mentioned Complex. 8 refs., 1 fig., 5 tabs.

  17. Energy minimization strategies and renewable energy utilization for desalination: a review.

    Science.gov (United States)

    Subramani, Arun; Badruzzaman, Mohammad; Oppenheimer, Joan; Jacangelo, Joseph G

    2011-02-01

    Energy is a significant cost in the economics of desalinating waters, but water scarcity is driving the rapid expansion in global installed capacity of desalination facilities. Conventional fossil fuels have been utilized as their main energy source, but recent concerns over greenhouse gas (GHG) emissions have promoted global development and implementation of energy minimization strategies and cleaner energy supplies. In this paper, a comprehensive review of energy minimization strategies for membrane-based desalination processes and utilization of lower GHG emission renewable energy resources is presented. The review covers the utilization of energy efficient design, high efficiency pumping, energy recovery devices, advanced membrane materials (nanocomposite, nanotube, and biomimetic), innovative technologies (forward osmosis, ion concentration polarization, and capacitive deionization), and renewable energy resources (solar, wind, and geothermal). Utilization of energy efficient design combined with high efficiency pumping and energy recovery devices have proven effective in full-scale applications. Integration of advanced membrane materials and innovative technologies for desalination show promise but lack long-term operational data. Implementation of renewable energy resources depends upon geography-specific abundance, a feasible means of handling renewable energy power intermittency, and solving technological and economic scale-up and permitting issues. Copyright © 2011 Elsevier Ltd. All rights reserved.

  18. Improving bioelectricity generation and COD removal of sewage sludge in microbial desalination cell.

    Science.gov (United States)

    Ebrahimi, Atieh; Yousefi Kebria, Daryoush; Darzi, Ghasem Najafpour

    2017-05-11

    Improving wastewater treatment process and water desalination are two important solutions for increasing the available supply of fresh water. Microbial desalination cells (MDCs) with common electrolytes display relatively low organic matter removal and high cost. In this study, sewage sludge was used as the substrate in the Microbial desalination cell (MDC) under three different initial salt concentrations (5, 20 and 35 g.L-1) and the maximum salt removal rates of 50.6%, 64% and 69.6% were obtained under batch condition, respectively. The MDC also produced the maximum power density of 47.1 W m-3 and the averaged chemical oxygen demand (COD) removal of 58.2 ± 0.89% when the initial COD was 6610 ± 83 mg L-1. Employing treated sludge as catholyte enhanced COD removal and power density to 87.3% and 54.4 W m-3, respectively, with counterbalancing pH variation in treated effluent. These promising results showed, for the first time, that the excess sewage sludge obtained from biological wastewater treatment plants could be successfully used as anolyte and catholyte in MDC, achieving organic matter biodegradation along with salt removal and energy production. In addition, using treated sludge as catholyte will improve the performance of MDC and introduce a more effective method for both sludge treatment and desalination.

  19. Review of nuclear electricity generation and desalination plants and evaluation of SMART application

    Energy Technology Data Exchange (ETDEWEB)

    Kang, Han Ok; Kang, Hyung Suk; Cho, Bong Hyun; Yoon, Ju Hyeon; Kim, Hwan Yeol; Lee, Young Jin; Kim, Joo Pyung; Lee, Doo Jeong; Chang, Moon Hee

    1998-03-01

    KAERI are developing a new advanced integral reactor named SMART for dual application purpose of the electric power generation and seawater desalination. This report are describing the general desalting methods with its technology development and the coupling schemes between electricity generation system and desalting system. Though MSF takes the most part of currently operating seawater desalination plants, MED and RO has been preferred in the past decade. MED has a advantage over MSF with the view to investment costs and energy efficiency. The coupling between electricity generation system and desalination system can be realized by using one of back pressure cycle, extraction cycle, and multi-shaft cycle. New design and operating strategy has to be established for various environment and load conditions. To evaluate the candidate desalination systems of SMART and the coupling method of it with other secondary systems, the desalted water and electricity were calculated through the several options. The result shows that back pressure cycle is preferred at the high water/power ratio and extraction cycle at the low value. If energy efficiency are only considered, RO will be best choice. (author). 17 refs., 12 tabs., 31 figs

  20. Optimal Design of a Solar Desalination Unit with Heliostats

    Directory of Open Access Journals (Sweden)

    M. Abidi

    2017-01-01

    Full Text Available The objective is to improve the yield of a solar desalination cell using concentration of solar rays by means of automatically controlled heliostats. The vertical cell is orientated towards the north. It is mainly composed of two plates; the one being heated by the solar rays reflected by the mirrors is used for evaporation of a falling water film; the other one is used for water vapor condensation. Each heliostat consists of an altitude-azimuth mount having two degrees of freedom and supporting a plane mirror. The heliostat permanently follows the sun trajectory and reflects the solar rays on the cell by means of automatic control implemented in a control card based on a microcontroller. Model predictive control allows us to maximize the distilled water production.

  1. Desalination utilizing clathrate hydrates (LDRD final report).

    Energy Technology Data Exchange (ETDEWEB)

    Simmons, Blake Alexander; Bradshaw, Robert W.; Dedrick, Daniel E.; Cygan, Randall Timothy (Sandia National Laboratories, Albuquerque, NM); Greathouse, Jeffery A. (Sandia National Laboratories, Albuquerque, NM); Majzoub, Eric H. (University of Missouri, Columbia, MO)

    2008-01-01

    Advances are reported in several aspects of clathrate hydrate desalination fundamentals necessary to develop an economical means to produce municipal quantities of potable water from seawater or brackish feedstock. These aspects include the following, (1) advances in defining the most promising systems design based on new types of hydrate guest molecules, (2) selection of optimal multi-phase reactors and separation arrangements, and, (3) applicability of an inert heat exchange fluid to moderate hydrate growth, control the morphology of the solid hydrate material formed, and facilitate separation of hydrate solids from concentrated brine. The rate of R141b hydrate formation was determined and found to depend only on the degree of supercooling. The rate of R141b hydrate formation in the presence of a heat exchange fluid depended on the degree of supercooling according to the same rate equation as pure R141b with secondary dependence on salinity. Experiments demonstrated that a perfluorocarbon heat exchange fluid assisted separation of R141b hydrates from brine. Preliminary experiments using the guest species, difluoromethane, showed that hydrate formation rates were substantial at temperatures up to at least 12 C and demonstrated partial separation of water from brine. We present a detailed molecular picture of the structure and dynamics of R141b guest molecules within water cages, obtained from ab initio calculations, molecular dynamics simulations, and Raman spectroscopy. Density functional theory calculations were used to provide an energetic and molecular orbital description of R141b stability in both large and small cages in a structure II hydrate. Additionally, the hydrate of an isomer, 1,2-dichloro-1-fluoroethane, does not form at ambient conditions because of extensive overlap of electron density between guest and host. Classical molecular dynamics simulations and laboratory trials support the results for the isomer hydrate. Molecular dynamics simulations

  2. Perceptions and Acceptance of Desalinated Seawater for Irrigation: A Case Study in the Níjar District (Southeast Spain

    Directory of Open Access Journals (Sweden)

    José A. Aznar-Sánchez

    2017-06-01

    Full Text Available In the context of increasing demand for irrigation water—but, at the same time, with the constraints in the supply from traditional resources—desalinated seawater has been recognized as one of the alternative sources of water to increase the supply for agricultural irrigation. However, its use among farmers has not yet started to expand. Policy makers need to understand what is causing the low acceptance levels of farmers, and how their attitudes could be improved. This is the first study that has conducted an analysis of farmers’ perceptions and acceptance of the use of desalinated seawater for irrigation. The study is based on collected data from a survey completed by farmers in southeastern Spain who do not use desalinated seawater. The main results indicate that desalinated seawater as a water supply source has the lowest acceptance level for farmers. Barriers for its use are price, the need for additional fertilization, and the perception that it would negatively affect the yield and crop quality. The farmers’ general level of knowledge about the impact of using desalinated seawater in agriculture is extremely low. Furthermore, farmers consider it a priority that their startup investment should be subsidized and that water prices should be reduced. Based on the study findings, this paper makes recommendations for the decision-making process in order to improve farmers’ acceptance levels.

  3. Final Scientific/Technical Report for Program Title: Solar Powered Dewvaporation Desalination System

    Energy Technology Data Exchange (ETDEWEB)

    Ranganathan, Shashidhar [Polestar Technologies Inc., Needham Heights, MA (United States)

    2017-03-24

    Desalination technologies have been used increasingly throughout the world to produce the drinking water from the brackish ground and sea water for the past few decades. Among the commercially available desalination technologies, reverse osmosis (RO) and multi-stage flash distillation are the most widely used technologies globally. However, these technologies are difficult to be directly integrated with green energies without converting them to electricity. Dewvaporation, a desalination process, uses saturated steam as a carrier-gas to evaporate water from saline feeds and form pure condensate. It has the major technical benefit of reusing energy, released from vapor condensation, multiple times. The current proposal has been planned to address this issue. In Phase I, we have successfully demonstrated the feasibility of a new plasmonic nanoparticle based approach through fabrication and evaluation of a solar powered water vapor generation module. The water vapor generation module allows generation of high temperature plasmon on a fiber bundle end, where strong water and plasmon interaction occurs generating water vapor. Plasmon enhanced water evaporation has been realized on plasmonic nanoparticle immobilized substrate with an energy conversion efficiency of over 50%.

  4. A Cost Effective Desalination Plant Using a Solar Chimney with Recycled Aluminum Can Collector

    Directory of Open Access Journals (Sweden)

    Singuru Rajesh

    2016-01-01

    Full Text Available The main objective of the work was to use solar energy for desalination of water. A solar chimney desalination system, which includes the solar chimney, solar collector, evaporation system, and passive condenser, was designed and built. The air enters into collector and gets heated and released at the bottom of chimney. Due to draught effect dry air goes upward. The air is humidified by spraying salt water into the hot air stream using a mistifier at the middle of chimney. Then, the partial vapours contained in the air are condensed to give desalinated water. The performance of the integrated system including power and potable water production was estimated and the results were discussed. With a 3.4 m height setup, experimental test rig was capable of evaporating 3.77 L water daily condensing 2.3 L water. It is compact in nature as it is easy to assemble and dissemble. It can be used for purifying rain water in summer under rain water harvesting. Because of using country wood, recycled Al cans, and GI sheet in fabrication, it is lower in cost.

  5. Opportunities of integrating desalination to cogeneration for Brazilian conditions

    Energy Technology Data Exchange (ETDEWEB)

    Ferreira, E.M.; Balestieri, J.A.P.; Zanardi, M.A. [UNESP, Guaratingueta, SP (Brazil)]. E-mails: mfeduardo@uol.com.br; perrella@feg.unesp.br; mznardi@feg.unesp.br

    2006-06-15

    One of the major problems in this century refers to the availability of potable water, necessary to the survival of populations. The world population is continually increasing and natural resources are proportionally decreasing, and the development of potable water production techniques demands intensive efforts. Electric power requirement is also necessary to the development of nations. Desalination processes are widely used in countries with low offer of potable water. Technologies nowadays in use are multi-stage-flash distillation (MSF), multi-effect distillation (MED) and reverse osmosis (RO) process. In MSF and MED processes, the main technique is distillation. Reverse osmosis technique relies on the osmotic principle, in which a solvent passes through a membrane. Since the middle of 1950, these desalting techniques are widely used mainly in the Middle East countries, where water shortage is almost absolute. Although uncommonly conceived, discussing the implementation of desalination processes in association to cogeneration systems in Brazil is a necessary task for the long-term planning. In this way, this paper proposes to review the successful experiences presented in the literature as a way of establishing how electric power and fresh water production can be produced from seawater desalting processes in an optimized way. Another objective pursued in this paper is stimulating more attention to this matter, that deserves discussing the skill staff formation and the know-how of such technologies in the strategic planning to the water resource management, specially because these investments require a considerable time for human resources development and the knowledge of the most adequate technology to be implemented for the integration of desalting and cogeneration units. (author)

  6. Electrochemical desalination of historic Portuguese tiles

    DEFF Research Database (Denmark)

    Ottosen, Lisbeth M.; Dias-Ferreira, Celia; Ribeiro, Alexandra B.

    2015-01-01

    Soluble salts cause severe decay of historic Portuguese tiles. Treatment options for removal of the salts to stop the decay are few. The present paper deals with development of a method for electrochemical desalination, where an electric DC field is applied to the tiles. Laboratory experiments were...

  7. Algal blooms and Membrane Based Desalination Technology

    NARCIS (Netherlands)

    Villacorte, L.O.

    2014-01-01

    Seawater desalination is rapidly growing in terms of installed capacity (~80 million m3/day in 2013), plant size and global application. An emerging threat to this technology is the seasonal proliferation of microscopic algae in seawater known as algal blooms. Such blooms have caused operational

  8. Electrode placement during electro-desalination of

    DEFF Research Database (Denmark)

    Ottosen, Lisbeth M.; Andersson, Lovisa C. H.

    2017-01-01

    , where the most fragile parts thus can be desalinated without physically placing electrodes on them. The Cl removal rate was higher in the areas closest to the electrodes and slowest in the part, which was not placed directly between the electrodes. This is important to incorporate in the monitoring...

  9. Direct contact membrane distillation for nuclear desalination, Part II: experiments with radioactive solutions

    Energy Technology Data Exchange (ETDEWEB)

    Khayet, M. [Department of Applied Physics I, Faculty of Physics, University Complutense of Madrid, Madrid (Spain)]. E-mail: khayetm@fis.ucm.es; Mengual, J.I. [Department of Applied Physics I, Faculty of Physics, University Complutense of Madrid, Madrid (Spain)]. E-mail: mengual@fis.ucm.es; Zakrzewska-Trznadel, G. [Department of Nuclear Methods in Process Engineering, Institute of Nuclear Chemistry and Technology, Warsaw (Poland)]. E-mail: gzakrzew@orange.ichtj.waw.pl

    2006-07-01

    This paper proposes the application of Direct Contact Membrane Distillation (DCMD) coupled with a nuclear reactor for water desalination and for low- and medium-level radioactive liquid waste concentration. Both laboratory and pilot plant experiments were carried out using the membranes reviewed in Part I of this paper. The effects of process parameters on the productivity and quality of DCMD systems are discussed. Distilled water, non-active solutions of inorganic salts and solutions with admixtures of radionuclides and simulated and real radioactive waste samples were used as feed solutions. Employing DCMD for liquid low- and medium-level radioactive waste processing is an alternative to traditional methods used in nuclear technology. The combination of radioactive waste processing and water desalination creates an economical integrated system for water and wastewater management in nuclear power plants. (author)

  10. An experimental investigation on MEDAD hybrid desalination cycle

    KAUST Repository

    Shahzad, Muhammad Wakil

    2015-04-02

    This paper presents an advanced desalination cycle called "MEDAD" desalination which is a hybrid of the conventional multi-effect distillation (MED) and an adsorption cycle (AD). The combined cycles allow some of MED stages to operate below ambient temperature, as low as 5. °C in contrast to the conventional MED. The MEDAD cycle results in a quantum increase of distillate production at the same top-brine condition. Being lower than the ambient temperature for the bottom stages of hybrid cycle, ambient energy can now be scavenged by the MED processes whilst the AD cycle is powered by low temperature waste heat from exhaust or renewable sources. In this paper, we present the experiments of a 3-stage MED and MEDAD plants. These plants have been tested at assorted heat source temperatures from 15. °C to 70. °C and with portable water as a feed. All system states are monitored including the distillate production and power consumption and the measured results are expressed in terms of performance ratio (PR). It is observed that the synergetic matching of MEDAD cycle led to a quantum increase in distillate production, up to 2.5 to 3 folds vis-a-vis to a conventional MED of the same rating. © 2015 Elsevier Ltd.

  11. On the optimal design of forward osmosis desalination systems with NH3-CO2-H2O solutions

    NARCIS (Netherlands)

    Gazzani, Matteo; Pérez-Calvo, José Francisco; Sutter, Daniel; Mazzotti, Marco

    2017-01-01

    Membrane-based forward osmosis, especially when NH3-CO2-H2O mixtures are adopted as draw solutions, is a promising new process for clean water production, including seawater desalination and wastewater treatment. In such a process, water is first removed from the feed (e.g. seawater) by exploiting

  12. In Situ Spatially and Temporally Resolved Measurements of Salt Concentration between Charging Porous Electrodes for Desalination by Capacitive Deionization

    NARCIS (Netherlands)

    Suss, M.E.; Biesheuvel, P.M.; Baumann, T.E.; Stadermann, M.; Santiago, J.G.

    2014-01-01

    Capacitive deionization (CDI) is an emerging water desalination technique. In CDI, pairs of porous electrode capacitors are electrically charged to remove salt from brackish water present between the electrodes. We here present a novel experimental technique allowing measurement of spatially and

  13. Membrane distillation and reverse electrodialysis for near-zero liquid discharge and low energy seawater desalination

    OpenAIRE

    Tufa, R.; Curcio, E.; Brauns, E.; van Baak, W.; Fontananova, E.; Di Profio, G.

    2015-01-01

    With a total capacity of 70 million cubic meters per day, seawater desalination industry represents the most affordable source of drinking water for many people living in arid areas of the world. Seawater Reverse Osmosis (SWRO) technology, driven by the impressive development in membrane materials, modules and process design, currently shows an overall energy consumption of 3-4 kWh per m(3) of desalted water, substantially lower than thermal systems; however, the theoretical energy demand to ...

  14. Desalination with Carbon Aerogel Electrodes

    Science.gov (United States)

    1996-12-04

    classified as sea water (800-1500 psi), standard pressure (400-650 psi), low pressure (200-300 psi) and nanofiltration (45-150 psi) [3a,3b]. Estimates...Furthermore, RO membranes are susceptible to many of the chemicals used for water treatment . Note that polyamide has been found to be sensitive to attack...34Membrane Processes," Chapt. 11, Water Quality and Treatment . A Handbook of Community Water Supplies, 4th Ed., R. W. Pontius, Ed., American Water Works

  15. Rotational Spectrum and Structure of the Quinuclidine Water Complex

    Science.gov (United States)

    Consalvo, D.; Stahl, W.

    1995-12-01

    The rotational spectrum of the quinuclidine-water complex has been observed in the region 6-20 GHz using a pulsed molecular beam Fourier transform microwave (MB-FTMW) spectrometer. In order to obtain detailed structural information on the complex, spectra of quinuclidine, also called 1-azabicyclo[2.2.2]octane (ABCO), combined with both H2O and H218O were examined. The observation of a symmetric top spectrum is consistent with a complex in which water undergoes internal rotation. Using a reasonable model for the interaction potential, it has been possible to estimate the torsional barrier of water. Centrifugal distortion analysis yields a N-H bond stretching force constant of 12.3 N/m, corresponding to a stretching frequency of 116 cm-1for ABCO-H216O.

  16. Application of S-CO{sub 2} Cycle for Small Modular Reactor coupled with Desalination System

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Won Woong; Bae, Seong Jun; Lee, Jeong Ik [KAIST, Daejeon (Korea, Republic of)

    2016-10-15

    The Korean small modular reactor, SMART (System-integrated Modular Advanced ReacTor, 100MWe), is designed to achieve enhanced safety and improved economics through reliable passive safety systems, a system simplification and component modularization. SMART can generate electricity and provide water by seawater desalination. However, due to the desalination aspect of SMART, the total amount of net electricity generation is decreased from 100MWe to 90MWe. The authors suggest in this presentation that the reduction of electricity generation can be replenished by applying S-CO{sub 2} power cycle technology. The S-CO{sub 2} Brayton cycle, which is recently receiving significant attention as the next generation power conversion system, has some benefits such as high cycle efficiency, simple configuration, compactness and so on. In this study, the cycle performance analysis of the S-CO{sub 2} cycles for SMART with desalination system is conducted. The simple recuperated S-CO{sub 2} cycle is revised for coupling with desalination system. The three revised layout are proposed for the cycle performance comparison. In this results of the 3rd revised layout, the cycle efficiency reached 37.8%, which is higher than the efficiency of current SMART with the conventional power conversion system 30%.

  17. Membrane scaling and flux decline during fertiliser-drawn forward osmosis desalination of brackish groundwater.

    Science.gov (United States)

    Phuntsho, Sherub; Lotfi, Fezeh; Hong, Seungkwan; Shaffer, Devin L; Elimelech, Menachem; Shon, Ho Kyong

    2014-06-15

    Fertiliser-drawn forward osmosis (FDFO) desalination has been recently studied as one feasible application of forward osmosis (FO) for irrigation. In this study, the potential of membrane scaling in the FDFO process has been investigated during the desalination of brackish groundwater (BGW). While most fertilisers containing monovalent ions did not result in any scaling when used as an FO draw solution (DS), diammonium phosphate (DAP or (NH4)2HPO4) resulted in significant scaling, which contributed to severe flux decline. Membrane autopsy using scanning electron microscopy (SEM), energy-dispersive x-ray spectroscopy (EDS), and x-ray diffraction (XRD) analysis indicated that the reverse diffusion of DAP from the DS to the feed solution was primarily responsible for scale formation during the FDFO process. Physical cleaning of the membrane with deionised water at varying crossflow velocities was employed to evaluate the reversibility of membrane scaling and the extent of flux recovery. For the membrane scaled using DAP as DS, 80-90% of the original flux was recovered when the crossflow velocity for physical cleaning was the same as the crossflow velocity during FDFO desalination. However, when a higher crossflow velocity or Reynolds number was used, the flux was recovered almost completely, irrespective of the DS concentration used. This study underscores the importance of selecting a suitable fertiliser for FDFO desalination of brackish groundwater to avoid membrane scaling and severe flux decline. Copyright © 2014 Elsevier Ltd. All rights reserved.

  18. Reducing the environmental impacts of reverse osmosis desalination by using brackish groundwater resources.

    Science.gov (United States)

    Muñoz, Ivan; Fernández-Alba, Amadeo Rodríguez

    2008-02-01

    The aim of the present work is to find out whether or not, and to what extent, the environmental impacts of reverse osmosis desalination are reduced when brackish groundwater is used instead of sea water. In order to answer this question, the Life-Cycle Assessment (LCA) methodology is used, and two water production plants are compared. The brackish groundwater scenario is based on a plant located in Almería (southern Spain), while the sea water scenario is based on literature data. Four impact categories and two environmental indicators, one of them related to brine discharge, are included. The results show that the key life-cycle issue of brackish groundwater desalination is electricity consumption, and since this is substantially reduced with regard to using sea water, the life-cycle impacts are found to be almost 50% lower. An uncertainty analysis based on Monte-Carlo simulation shows that these environmental savings are significant for all impact categories. Potential local impacts provoked by brine discharge are also found to be lower, due to a reduced content of salts. It is concluded that, when and wherever possible, exploitation of brackish groundwater resources should be assigned priority to sea water resources as an input for reverse osmosis desalination, although it must be taken into account that groundwater, as opposed to sea water, is a limited resource.

  19. Mononuclear and Heterotrinuclear Ruthenium Complexes: Synthesis and Water Oxidation Activity

    OpenAIRE

    Mognon, Lorenzo

    2015-01-01

    Artificial photosynthesis constitutes an intriguing alternative to fossil fuels, and the water oxidation reaction is considered the bottleneck for the achievement of an efficient device to perform it. Extensive research has been carried out, and is still ongoing, to identify the properties and mechanisms that define a good water oxidation catalyst. Ruthenium complexes have shown to be valid candidates for this task. This work presents the synthesis and characterization of multiple mononuclear...

  20. Desalination of salt damaged Obernkirchen sandstone by an applied DC field

    DEFF Research Database (Denmark)

    Matyščák, Ondřej; Ottosen, Lisbeth M.; Rörig-Dalgaard, Inge

    2014-01-01

    as the outer surface was scaling due to salts.The focus of the work was on the effect of electrokinetic desalination for removal of unevenly distributed mixtures of salts. Previous reported studies were conducted with laboratory contaminated stones with single salts, which were relatively evenly distributed...... the treatment the water content was very low in the stones, between 1.3% and 2.1%. Electroosmotic water transport was observed in the clay poultices, however, there was no decrease of the water contents in the stones at the end of the experiments, so there was no indication of an electroosmotic effect......Soluble salts are considered as one of the most common causes for decay of building materials. In the present work, an electrokinetic method for desalination of sandstones from a historic warehouse was tested. The sandstones claddings were removed from the warehouse during a renovation action...

  1. Determination of the costs of the nuclear desalination using the DEEP code from IAEA; Determinacion de los costos de la desalacion nuclear utilizando el codigo DEEP del OIEA

    Energy Technology Data Exchange (ETDEWEB)

    Ramirez S, J.R.; Palacios H, J.C.; Alonso V, G. [ININ, 52045 Ocoyoacac, Estado de Mexico (Mexico)]. e-mail: jrrs@nuclear.inin.mx

    2005-07-01

    The desalination of seawater is being an important solution to satisfy the demands of drinking water to population's centers that have hydric resources very limited, like it is the case of some Arab countries and arid regions of the planet, in where they have settled desalination plants that use as energy source to those fossil fuels or nuclear energy plants. Taking into account that the desalination of seawater is a process that consumes a lot of thermal and/or electric energy, it is necessary to quantify the costs of the supply and that of the desalination plant for different options and technologies, looking for this way the but appropriate for the specific conditions of the region where it has planned the desalination of seawater. In this report the three technologies but promising for the desalination are described and by means of the DEEP code the costs of production of water and energy are evaluated, using as thermal source different types of power nuclear reactors. It was obtained according to DEEP that the costs of the electricity generation for the considered reactors are around 40 USD/MWh. With these costs of electric power generation and using the DEEP code is obtained that the costs of production of drinking water are around 1 USD/m{sup 3}. (Author)

  2. Microbial desalination cells for improved performance in wastewater treatment, electricity production, and desalination.

    Science.gov (United States)

    Luo, Haiping; Xu, Pei; Roane, Timberley M; Jenkins, Peter E; Ren, Zhiyong

    2012-02-01

    The low conductivity and alkalinity in municipal wastewater significantly limit power production from microbial fuel cells (MFCs). This study integrated desalination with wastewater treatment and electricity production in a microbial desalination cell (MDC) by utilizing the mutual benefits among the above functions. When using wastewater as the sole substrate, the power output from the MDC (8.01 W/m(3)) was four times higher than a control MFC without desalination function. In addition, the MDC removed 66% of the salts and improved COD removal by 52% and Coulombic efficiency by 131%. Desalination in MDCs improved wastewater characteristics by increasing the conductivity by 2.5 times and stabilizing anolyte pH, which therefore reduced system resistance and maintained microbial activity. Microbial community analysis revealed a more diverse anode microbial structure in the MDC than in the MFC. The results demonstrated that MDC can serve as a viable option for integrated wastewater treatment, energy production, and desalination. Copyright © 2011 Elsevier Ltd. All rights reserved.

  3. An Improved Multi-Evaporator Adsorption Desalination Cycle for GCC Countries

    KAUST Repository

    Shahzad, Muhammad Wakil

    2017-03-29

    In Gulf Cooperation Council (GCC) countries, cogeneration based desalination processes consume almost 25% of the total annual energy and it is increasing at 2.2% annually. The high fresh water demand is attributed to high gross domestic product (GDP) growth rate, 24%, and the high water languishes, more than 10%. Over the past two decades, GCC countries have spent tens of billion dollars to expand their present and planned desalination capacities. It is foreseeable that with business-as-usual scenario, the domestic oil consumption of Saudi Arabia may exceed its production capacity by 2040. Innovative and sustainable water production solutions are needed urgently for future water supplies without environment impact. In this paper, a hybrid desalination cycle is proposed by integrating multi cascaded-evaporators (CE) with an adsorption cycle (AD). In this new innovative cycle, AD desorbed vapors are supplied to the CE to exploit the latent condensation energy within the evaporators arranged in both pressures-temperatures cascaded manner to improves the performance ratio (PR) of the cycle. Hybrid cycle shows more than 10 folds water production improvement as compared to conventional AD cycle due to synergetic effect. This concept is demonstrated in a laboratory pilot plant using a 3 cascaded evaporators pilot and simulation of 8 evaporators hybrid cycle.

  4. Plasmonic heating from indium nanoparticles on a floating microporous membrane for enhanced solar seawater desalination.

    Science.gov (United States)

    Zhang, Lulu; Xing, Jun; Wen, Xinglin; Chai, Jianwei; Wang, Shijie; Xiong, Qihua

    2017-09-14

    Passive solar evaporation represents a promising and environmentally benign method of water purification/desalination. Plasmonic nanoparticles have been demonstrated as an effective approach for enhancing solar steam generation through a plasmonic heating effect, nonetheless the efficiency is constrained by unnecessary bulk heating of the entire liquid volume, while the noble metals commonly used are not cost-effective in terms of availability and their sophisticated preparation. Herein, a paper-like plasmonic device consisting of a microporous membrane and indium nanoparticles (In NPs/MPM) is fabricated through a simple thermal evaporation method. Due to the light-weight and porous nature of the device, the broadband light absorption properties, and theoretically the excellent plasmonic heating effect from In NP which could be even higher than gold, silver and aluminium nanoparticles, our device can effectively enhance solar water evaporation by floating on the water surface and its utility has been demonstrated in the solar desalination of a real seawater sample. The durability of the device in solar seawater desalination has also been investigated over multiple cycles with stable performances. This portable device could provide a solution for individuals to do water/seawater purification in under-developed areas with limited/no access to electricity or a centralized drinking water supply.

  5. Electro-desalination of glazed tile panels - discussion of possibilities

    DEFF Research Database (Denmark)

    Dias-Ferreira, Célia; Ottosen, Lisbeth M.; Ribeiro, Alexandra B.

    2016-01-01

    of the system. Single tiles, a variety of porous stones and the mortar on the back of a tile have all been electro-desalinated successfully in laboratory scale. Thus individually, all parts of the wall with tile panel can be electro-desalinated. The interface between mortar and tile can be problematic....... In the few experiments conducted on tiles with attached mortar, the mortar was desalinated to a higher degree than the biscuit and successful desalination of the biscuit through the mortar requires further research. In-situ pilot scale tests were performed on highly salt-contaminated walls without tiles...

  6. Coastal Residents Ocean Literacy about Seawater Desalination and its Impacts on Marine Ecosystems in the Monterey Bay

    Science.gov (United States)

    Faraola, S.; Heck, N.; Mirza Ordshahi, B.; Paytan, A.; Petersen, K. L.; Haddad, B.; Potts, D. C.

    2016-12-01

    The current lack of available freshwater in California has brought about the consideration of utilizing seawater desalination to provide a consistent drinking water source for local residents of coastal areas. Public literacy about this technology and its impacts on the ocean is vital to making informed policy decisions about marine resources and ecosystems, which may empower local communities to become more involved stewards of the ocean. Our study evaluates public literacy about seawater desalination and its impacts on the ocean. Data was collected using a questionnaire-based survey from a randomly selected sample of residents and marine stakeholders in coastal communities around Monterey Bay. The study explored (1) self-assessed and accurate knowledge about marine impacts from seawater desalination and (2) what shapes public literacy concerning pertinent ocean issues in communities near a National Marine Sanctuary. Our findings show to what extent the public is prepared to engage in meaningful discussions about marine issues and seawater desalination and if an understanding of the ocean shapes perceptions on saltwater desalination.

  7. Simulating the impact of brine from desalination plants on the salinity of the Persian/Arabian Gulf

    Science.gov (United States)

    Eltahir, E. A. B.; Ibrahim, H. D.

    2016-12-01

    The Middle East has an arid climate and very little freshwater from river runoff, which has forced a rapid expansion of desalination plants in the region in order to meet current and future freshwater demand due to rising population. The Gulf is the source of feedwater and sink of concentrated discharge (brine) for plants producing more than half of the world's desalination capacity. Moreover, the Gulf is one of the most saline water bodies in the world due to large evaporation that far exceeds the input of freshwater from precipitation and river runoff. An increase in salinity at the regional scale due to brine discharge may reduce the quality of feedwater to plants and efficiency of desalination, and at the basin scale, a rise in salinity may change the dynamics of water circulation and adversely impact the marine biota. Here we present modeling results from simulating the impact of desalination on the natural Gulf environment using a coupled Gulf-atmosphere regional model (GARM). GARM is the first two-way coupled model developed for the Gulf system. The hydrodynamic component of GARM is the unstructured grid finite volume coastal ocean model (FVCOM) and the atmosphere component of GARM is the MIT regional climate model (MRCM), both of which have been widely used in simulating regional ocean and atmospheric dynamics. Desalination activity is incorporated into GARM as a boundary condition and the Gulf system is simulated for a ten-year time period in order to quantify the impact of brine discharge both at regional and basin scales. These results will be useful for desalination plant design and planning for current and future water security in the region.

  8. Impacts of desalination plant discharges on the marine environment: A critical review of published studies.

    Science.gov (United States)

    Roberts, David A; Johnston, Emma L; Knott, Nathan A

    2010-10-01

    Desalination of seawater is an increasingly common means by which nations satisfy demand for water. Desalination has a long history in the Middle East and Mediterranean, but expanding capacities can be found in the United States, Europe and Australia. There is therefore increasing global interest in understanding the environmental impacts of desalination plants and their discharges on the marine environment. Here we review environmental, ecological and toxicological research in this arena including monitoring and assessment of water quality and ecological attributes in receiving environments. The greatest environmental and ecological impacts have occurred around older multi-stage flash (MSF) plants discharging to water bodies with little flushing. These discharge scenarios can lead to substantial increases in salinity and temperature, and the accumulation of metals, hydrocarbons and toxic anti-fouling compounds in receiving waters. Experiments in the field and laboratory clearly demonstrate the potential for acute and chronic toxicity, and small-scale alterations to community structure following exposures to environmentally realistic concentrations of desalination brines. A clear consensus across many of the reviewed articles is that discharge site selection is the primary factor that determines the extent of ecological impacts of desalination plants. Ecological monitoring studies have found variable effects ranging from no significant impacts to benthic communities, through to widespread alterations to community structure in seagrass, coral reef and soft-sediment ecosystems when discharges are released to poorly flushed environments. In most other cases environmental effects appear to be limited to within 10s of meters of outfalls. It must be noted that a large proportion of the published work is descriptive and provides little quantitative data that we could assess independently. Many of the monitoring studies lacked sufficient detail with respect to study design

  9. Algal blooms and Membrane Based Desalination Technology

    OpenAIRE

    Villacorte, L.O.

    2014-01-01

    Seawater desalination is rapidly growing in terms of installed capacity (~80 million m3/day in 2013), plant size and global application. An emerging threat to this technology is the seasonal proliferation of microscopic algae in seawater known as algal blooms. Such blooms have caused operational problems in seawater reverse osmosis (SWRO) plants due to clogging and poor effluent quality of the pre-treatment system which eventually forced the shutdown of the plant to avoid irreversible fouling...

  10. Desalination and hydrogen, chlorine, and sodium hydroxide production via electrophoretic ion exchange and precipitation.

    Science.gov (United States)

    Shkolnikov, Viktor; Bahga, Supreet S; Santiago, Juan G

    2012-08-28

    We demonstrate and analyze a novel desalination method which works by electrophoretically replacing sodium and chloride in feed salt water with a pair of ions, calcium and carbonate, that react and precipitate out. The resulting calcium carbonate precipitate is benign to health, and can be filtered or settled out, yielding low ionic strength product water. The ion exchange and precipitation employs self-sharpening interfaces induced by movement of multiple ions in an electric field to prevent contamination of the product water. Simultaneously, the electrolysis associated with the electromigration produces hydrogen gas, chlorine gas, and sodium hydroxide. We conducted an experimental study of this method's basic efficacy to desalinate salt water from 100 to 600 mol m(-3) sodium chloride. We also present physicochemical models of the process, and analyze replacement reagents consumption, permeate recovery ratio, and energy consumption. We hypothesize that the precipitate can be recycled back to replacement reagents using the well-known, commercially implemented Solvay process. We show that the method's permeate recovery ratio is 58% to 46%, which is on par with that of reverse osmosis. We show that the method's energy consumption requirement over and above that necessary to generate electrolysis is 3 to 10 W h l(-1), which is on par with the energy consumed by state-of-the-art desalination methods. Furthermore, the method operates at ambient temperature and pressure, and uses no specialized membranes. The process may be feasible as a part of a desalination-co-generation facility: generating fresh water, hydrogen and chlorine gas, and sodium hydroxide.

  11. INVESTIGATIONS ON LOW TEMPERATURE FLASH EVAPORATION DESALINATION FOR SMALL-SCALE APPLICATIONS

    OpenAIRE

    G. Jims John Wessley; P. Koshy Mathews

    2013-01-01

    This paper presents the experimental study of a flash evaporation based desalination system that can cater to the small-scale fresh water needs of coastal and arid areas. The proposed small-scalesystem consists of an evaporator, water-cooled condenser and a vacuum pump to produce the required vacuum in the evaporator. The effect of inlet brine water temperature at various flow rate and evaporator pressure on the fresh water yield is evaluated. A maximum fresh water yield of 4 l/h is obtained ...

  12. Microporous Silica Based Membranes for Desalination

    Directory of Open Access Journals (Sweden)

    João C. Diniz da Costa

    2012-09-01

    Full Text Available This review provides a global overview of microporous silica based membranes for desalination via pervaporation with a focus on membrane synthesis and processing, transport mechanisms and current state of the art membrane performance. Most importantly, the recent development and novel concepts for improving the hydro-stability and separating performance of silica membranes for desalination are critically examined. Research into silica based membranes for desalination has focussed on three primary methods for improving the hydro-stability. These include incorporating carbon templates into the microporous silica both as surfactants and hybrid organic-inorganic structures and incorporation of metal oxide nanoparticles into the silica matrix. The literature examined identified that only metal oxide silica membranes have demonstrated high salt rejections under a variety of feed concentrations, reasonable fluxes and unaltered performance over long-term operation. As this is an embryonic field of research several target areas for researchers were discussed including further improvement of the membrane materials, but also regarding the necessity of integrating waste or solar heat sources into the final process design to ensure cost competitiveness with conventional reverse osmosis processes.

  13. Desalination of seawater with nuclear power reactors in cogeneration; Desalacion de agua de mar con reactores nucleares de potencia en cogeneracion

    Energy Technology Data Exchange (ETDEWEB)

    Flores E, R.M

    2004-07-01

    The growing demand for energy and hydraulic resources for satisfy the domestic, industrial, agricultural activities, etc. has wakened up the interest to carry out concerning investigations to study the diverse technologies guided to increase the available hydraulic resources, as well as to the search of alternatives of electric power generation, economic and socially profitable. In this sense the possible use of the nuclear energy is examined in cogeneration to obtain electricity and drinkable water for desalination of seawater. The technologies are analysed involved in the nuclear cogeneration (desalination technology, nuclear and desalination-nuclear joining) available in the world. At the same time it is exemplified the coupling of a nuclear reactor and a process of hybrid desalination that today in day the adult offers and economic advantages. Finally, the nuclear desalination is presented as a technical and economically viable solution in regions where necessities of drinkable water are had for the urban, agricultural consumption and industrial in great scale and that for local situations it is possible to satisfy it desalinating seawater. (Author)

  14. PV-Li-ion-micropump membrane systems for portable personal desalination

    Directory of Open Access Journals (Sweden)

    Mark P. McHenry

    2016-03-01

    Full Text Available This research presents a technical simulation of theoretically portable desalination systems utilising low-energy and lightweight components that are either commercially available or currently in development. The commercially available components are small-scale flexible and portable photovoltaic (PV modules, Li-ion battery-converter units, and high pressure low voltage brushless DC motor-powered micropumps. The theoretical and conventional small-scale desalination membranes are compared against each other: low-pressure reverse osmosis (RO, nanofilters, graphene, graphene oxide, and graphyne technology. The systems were designed with the identical PV-Li-ion specifications and simulation data to quantify the energy available to power the theoretical energy demand for desalinating a saline water at 30,000–40,000 ppm total dissolved solid (TDS to reliably supply the minimum target of 3.5 L d−1 of freshwater for one theoretical year. The results demonstrate that modern portable commercially available PV-battery systems and new generations of energy-efficient membranes under development have the potential to enable users to sustainably procure daily drinking water needs from saline/contaminated water resources, with the system exhibiting a net reduction in weight than carrying water itself.

  15. Numerical simulation and performance investigation of an advanced adsorption desalination cycle

    KAUST Repository

    Thu, Kyaw

    2013-01-01

    Low temperature waste heat-driven adsorption desalination (AD) cycles offer high potential as one of the most economically viable and environmental-friendly desalination methods. This article presents the development of an advanced adsorption desalination cycle that employs internal heat recovery between the evaporator and the condenser, utilizing an encapsulated evaporator-condenser unit for effective heat transfer. A simulation model has been developed based on the actual sorption characteristics of the adsorbent-adsorbate pair, energy and mass balances applied to the components of the AD cycle. With an integrated design, the temperature in the evaporator and the vapor pressurization of the adsorber are raised due to the direct heat recovery from the condenser, resulting in the higher water production rates, typically improved by as much as three folds of the conventional AD cycle. In addition, the integrated design eliminates two pumps, namely, the condenser cooling water and the chilled water pumps, lowering the overall electricity consumption. The performance of the cycle is analyzed at assorted heat source and cooling water temperatures, and different cycle times as well as the transient heat transfer coefficients of the evaporation and condensation. © 2012 Elsevier B.V.

  16. Intakes and outfalls for seawater reverse-osmosis desalination facilities innovations and environmental impacts

    CERN Document Server

    Jones, Burton; Maliva, Robert

    2015-01-01

    The book assembles the latest research on new design techniques in water supplies using desalinated seawater. The authors examine the diverse issues related to the intakes and outfalls of these facilities. They clarify how and why these key components of the facilities impact the cost of operation and subsequently the cost of water supplied to the consumers. The book consists of contributed articles from a number of experts in the field who presented their findings at the “Desalination Intakes and Outfalls” workshop held at King Abdullah University of Science and Technology (KAUST) in Saudi Arabia in October, 2013. The book integrates coverage relevant to a wide variety of researchers and professionals in the general fields of environmental engineering and sustainable development.

  17. Solar Desalination System Model for Sizing of Photovoltaic Reverse Osmosis (PVRO)

    KAUST Repository

    Habib, Abdulelah

    2015-06-28

    The focus of this paper is to optimize the solar energy utilization in the water desalination process. Due to variable nature of solar energy, new system design is needed to address this challenge. Here, reverse osmosis units, as the electrical loads, are considered as an ON/OFF units to track these solar energy variations. Reverse osmosis units are different in sizes and numbers. Various combinations of reverse osmosis units in size and capacity provide different water desalination system performances. To assess each scenario of reverse osmosis units, the total capital cost and operation and maintenance (O&M) cost are considered. The implemented optimization algorithm search all of the possible scenarios to find the best solution. This paper deploys the solar irradiance data which is provided from west coast (Red Sea) of Saudi Arabia for model construction and optimization algorithm implementation.

  18. Circulatory osmotic desalination driven by a mild temperature gradient based on lower critical solution temperature (LCST) phase transition materials.

    Science.gov (United States)

    Mok, Yeongbong; Nakayama, Daichi; Noh, Minwoo; Jang, Sangmok; Kim, Taeho; Lee, Yan

    2013-11-28

    Abrupt changes in effective concentration and osmotic pressure of lower critical solution temperature (LCST) mixtures facilitate the design of a continuous desalination method driven by a mild temperature gradient. We propose a prototype desalination system by circulating LCST mixtures between low and high temperature (low T and high T) units. Water molecules could be drawn from a high-salt solution to the LCST mixture through a semipermeable membrane at a temperature lower than the phase transition temperature, at which the effective osmotic pressure of the LCST mixture is higher than the high-salt solution. After transfer of water to the high T unit where the LCST mixture is phase-separated, the water-rich phase could release the drawn water into a well-diluted solution through the second membrane due to the significant decrease in effective concentration. The solute-rich phase could be recovered in the low T unit via a circulation process. The molar mass, phase transition temperature, and aqueous solubility of the LCST solute could be tuneable for the circulatory osmotic desalination system in which drawing, transfer, release of water, and the separation and recovery of the solutes could proceed simultaneously. Development of a practical desalination system that draws water molecules directly from seawater and produces low-salt water with high purity by mild temperature gradients, possibly induced by sunlight or waste heat, could be attainable by a careful design of the molecular structure and combination of the circulatory desalination systems based on low- and high-molar-mass LCST draw solutes.

  19. Vapor transport through short hydrophobic nanopores for desalination

    Science.gov (United States)

    Lee, Jongho; O'Hern, Sean; Laoui, Tahar; Rahman, Faizur; Karnik, Rohit

    2011-11-01

    We propose a concept for desalination of water by reverse osmosis (RO) using a vapor-trapping membrane composed of short hydrophobic nanopores and separates the salt water (feed) and the fresh water (permeate) on each side. The feed water is vaporized by applied pressure and the water vapor condenses on the permeate side accompanied by recovery of latent heat. A probabilistic model based on rarified gas conditions predicted 3-5 times larger mass flux by the proposed membrane than conventional RO membranes at temperatures in the range of 30-50C. To realize the short hydrophobic nanopores, gold was deposited at the entrance of alumina pores followed by SAM formation. The fraction of leaking pores was confirmed to be less than 0.2% using a calcium ion indicator (Fluo-4). Finally, a microfluidic flow cell was fabricated for characterizing the transport properties of the membranes. The authors would like to thank the King Fahd University of Petroleum and Minerals in Dhahran, Saudi Arabia, for funding the research reported in this paper through the Center for Clean Water and Clean Energy at MIT and KFUPM.

  20. Book Review: Water Diplomacy: A Negotiated Approach to Managing Complex Water Networks

    Science.gov (United States)

    Hossain, Faisal

    2013-01-01

    All nations have built their economies around water that is naturally available. Almost all sectors of the economy depend on water. Yet there is conflict among various users for the finite amount of water that is available. Managers and practitioners have long held the notion that competition rather than collaboration is the solution when there is conflict. Water Diplomacy: A Negotiated Approach to Managing Complex Water Networks, by Shafiqul Islam and Lawrence Susskind, provides a refreshingly compelling alternative to overcoming water conflicts. The book argues that the dynamic sociopolitical and socioeconomic constraints of water resources are best addressed in a "diplomacy" framework. The book rebuts, using several case studies, the technically rigid competition approach of today's water sharing practice.

  1. Exceptional ion rejection ability of directional solvent for non-membrane desalination

    Science.gov (United States)

    Rish, Daniel; Luo, Shirui; Kurtz, Brien; Luo, Tengfei

    2014-01-01

    The recently demonstrated directional solvent extraction (DSE) is promising for very low temperature, membrane-free water desalination. In this paper, we combine atomistic simulations and experimental validation to demonstrate that the currently used directional solvent, decanoic acid, can reject all major salt ions in seawater, with very high rejection rates. The salinities of the DSE recovered water show that ion rejection rates are ˜98%-99%—similar to those of the best reverse osmosis membranes. Our test also shows that the DSE process can desalt seawater to produce fresh water that meets drinking water standards.

  2. Integrated Water Resource Management and Energy Requirements for Water Supply in the Copiapó River Basin, Chile

    Directory of Open Access Journals (Sweden)

    Francisco Suárez

    2014-08-01

    Full Text Available Population and industry growth in dry climates are fully tied to significant increase in water and energy demands. Because water affects many economic, social and environmental aspects, an interdisciplinary approach is needed to solve current and future water scarcity problems, and to minimize energy requirements in water production. Such a task requires integrated water modeling tools able to couple surface water and groundwater, which allow for managing complex basins where multiple stakeholders and water users face an intense competition for limited freshwater resources. This work develops an integrated water resource management model to investigate the water-energy nexus in reducing water stress in the Copiapó River basin, an arid, highly vulnerable basin in northern Chile. The model was utilized to characterize groundwater and surface water resources, and water demand and uses. Different management scenarios were evaluated to estimate future resource availability, and compared in terms of energy requirements and costs for desalinating seawater to eliminate the corresponding water deficit. Results show a basin facing a very complex future unless measures are adopted. When a 30% uniform reduction of water consumption is achieved, 70 GWh over the next 30 years are required to provide the energy needed to increase the available water through seawater desalination. In arid basins, this energy could be supplied by solar energy, thus addressing water shortage problems through integrated water resource management combined with new technologies of water production driven by renewable energy sources.

  3. Bioelectrochemical desalination and electricity generation in microbial desalination cell with dewatered sludge as fuel.

    Science.gov (United States)

    Meng, Fanyu; Jiang, Junqiu; Zhao, Qingliang; Wang, Kun; Zhang, Guodong; Fan, Qingxin; Wei, Liangliang; Ding, Jing; Zheng, Zhen

    2014-04-01

    Microbial desalination cells (MDCs) with common liquid anodic substrate exhibit a slow startup and destructive pH drop, and abiotic cathodes have high cost and low sustainability. A biocathode MDC with dewatered sludge as fuel was developed for synergistic desalination, electricity generation and sludge stabilization. Experimental results indicated that the startup period was reduced to 3d, anodic pH was maintained between 6.6 and 7.6, and high stability was shown under long-term operation (300d). When initial NaCl concentrations were 5 and 10g/L, the desalinization rates during stable operation were 46.37±1.14% and 40.74±0.89%, respectively. The maximum power output of 3.178W/m(3) with open circuit voltage (OCV) of 1.118V was produced on 130d. After 300d, 25.71±0.15% of organic matter was removed. These results demonstrated that dewatered sludge was an appropriate anodic substrate to enhance MDC stability for desalination and electricity generation. Copyright © 2014 Elsevier Ltd. All rights reserved.

  4. Bioelectricity inhibits back diffusion from the anolyte into the desalinated stream in microbial desalination cells.

    Science.gov (United States)

    Ping, Qingyun; Porat, Oded; Dosoretz, Carlos G; He, Zhen

    2016-01-01

    Microbial desalination cells (MDCs) taking advantage of energy in wastewater to drive desalination represent a promising approach for energy-efficient desalination, but concerns arise whether contaminants in wastewater could enter the desalinated stream across ion exchange membranes. Such back diffusion of contaminants from the anolyte into the desalinated stream could be controlled by two mechanisms, Donnan effect and molecule transport. This study attempted to understand those mechanisms for inorganic and organic compounds in MDCs through two independently conducted experiments. Donnan effect was found to be the dominant mechanism under the condition without current generation. Under open circuit condition, the MDC fed with 5 g L(-1) salt solution exhibited 1.9 ± 0.7%, 10.3 ± 1.3%, and 1.8 ± 1.2% back diffusion of acetic, phosphate, and sulfate ions, respectively. Current generation effectively suppressed Donnan effect from 68.2% to 7.2%, and then molecule transport became more responsible for back diffusion. A higher initial salt concentration (35 g L(-1)) and a shorter HRT (1.0 d) led to the highest concentration gradient, resulting in the most back diffusion of 7.1 ± 1.2% and 6.8 ± 3.1% of phosphate and sulfate ions, respectively. Three representative organic compounds were selected for test, and it was found that organic back diffusion was intensified with a higher salt concentration gradient and molecular weight played an important role in compound movement. Principal component analysis confirmed the negative correlation between Donnan effect and current, and the positive correlation between molecule transport and concentration gradient related conditions. Copyright © 2015 Elsevier Ltd. All rights reserved.

  5. Carbon Dioxide Nucleation as a Novel Cleaning Method for Sodium Alginate Fouling Removal from Reverse Osmosis Membranes desalination

    KAUST Repository

    Alnajjar, Heba

    2017-05-01

    The use of Reverse osmosis (RO) membranes have been significantly increasing in water desalination, and the main operational obstacle in RO desalination plants is membrane fouling. Among other solutes, dissolved biopolymers, such as polysaccharides can lead to severe membrane fouling especially with the addition of calcium ions because of the complexation formation between the surface of membrane and foulants materials. However, this complexation can also take place in the feed bulk, resulting in foulants aggregates formation. Although there are some physical techniques that can maintain the membrane performance without reducing its lifetime, only chemical cleanings are still commonly used in RO plants. In this study, a novel cleaning method is proposed to restore the membrane performance by removing the deposited foulants without reducing the membrane lifetime. The cleaning method is based on using water saturated with dissolved CO2 gas, and its principle is based on producing spontaneous CO2 bubbles due to local pressure difference leading to nucleation of bubbles throughout the membrane surface, especially at nucleation sites, which improve the cleaning efficiency. Alginic acid sodium salt was used as a model of polysaccharides foulants in presence of different concentrations of NaCl and calcium ions aiming to enhance membrane fouling, and then CO2 cleaning solution efficiency, in terms flux recovery (FR), was tested under different operating conditions and compared to other cleaning methods. Average FR of 20%±3, 25%±3 and 80%±3 for MilliQ water, a cleaning solution at pH4, and CO2 solution at 6 bar, 0.17 m/s, and 23 ̊C ±0.2 for 6 minutes were obtained, respectively. The efficiency of this novel cleaning method was also compared to direct osmosis overnight, and the average flux was comparable (about 60%±3), though that the cleaning time was significantly different. Various calcium concentrations (0-10 mM) were added in the alginate solution to study the

  6. Parametric theoretical study of a two-stage solar organic Rankine cycle for RO desalination

    Energy Technology Data Exchange (ETDEWEB)

    Kosmadakis, G.; Manolakos, D.; Papadakis, G. [Department of Natural Resources and Agricultural Engineering, Agricultural University of Athens, 75 Iera Odos Street, 11855 Athens (Greece)

    2010-05-15

    The present work concerns the parametric study of an autonomous, two-stage solar organic Rankine cycle for RO desalination. The main goal of the current simulation is to estimate the efficiency, as well as to calculate the annual mechanical energy available for desalination in the considered cases, in order to evaluate the influence of various parameters on the performance of the system. The parametric study concerns the variation of different parameters, without changing actually the baseline case. The effect of the collectors' slope and the total number of evacuated tube collectors used, have been extensively examined. The total cost is also taken into consideration and is calculated for the different cases examined, along with the specific fresh water cost (EUR/m{sup 3}). (author)

  7. Investigations of the Effects of Biocide Dosing and Chemical Cleaning on the Organic Carbon Removal in an Integrated Ultrafiltration - Nanofiltration Desalination Pilot Plant

    KAUST Repository

    Khojah, Bayan A.

    2017-12-01

    Membrane desalination has become one of the most important desalination technologies used in the world. It provides high water quality for numerous applications and it demonstrates excellent desalination efficiency. One of the most troubling drawbacks of membrane desalination is membrane fouling. It decreases the performance of the membranes and increases the energy requirement. Two of the most important causes of fouling are microbes and organic matter. Hence, to maintain an optimized desalination performance, routine inspection of microbial and organic contents of water is crucial for desalination plants. In this study, water samples were obtained from different treatment points in an ultrafiltration (UF)/nanofiltration (NF) seawater desalination pilot plant. This was performed to better understand how the water quality changes along the desalination scheme. The effect of fouling control techniques, including Chemically Enhanced Backwash (CEB), Cleaning in Place (CIP), and the addition of a biocide (DBNPA) was studied. Different analytical tools were applied, including Bactiquant, Total Organic Carbon (TOC), Assimilable Organic Carbon (AOC), and Liquid Chromatography for Organic Carbon Detection (LC-OCD). Out results showed that UF did not decrease TOC but it was sufficient in removing up to 99.7% of bacteria. Nanofiltration, removed up to 95% of TOC. However, NF permeate had a high increase in AOC as compared to the raw seawater sample. The LC-OCD results suggested that this might be due to the increased low molecular weight neutrals which were the most common organic species in the NF permeate. The fouling control techniques showed various effects on the desalination efficiency. Daily CEB did not cause a reduction in TOC or bacteria but decreased AOC in the UF filtrate. The biocide addition resulted in an adequate membranes protection from fouling and it did not affect the investigated water parameters. When the dosing of biocide was stopped, the water quality

  8. Observations and Prediction of Recovered Quality of Desalinated Seawater in the Strategic ASR Project in Liwa, Abu Dhabi

    Directory of Open Access Journals (Sweden)

    Pieter J. Stuyfzand

    2017-03-01

    Full Text Available To be able to overcome water shortages, Abu Dhabi Emirate started an Aquifer Storage and Recovery (ASR project with desalinated seawater (DSW as source water near Liwa. It is the largest DSW-ASR project in the world (stored volume ~10 Mm3/year, and should recover potable water for direct use. DSW is infiltrated into a desert dune sand aquifer using “sand-covered gravel-bed” recharge basins. In this study, we evaluate the hydrogeological and hydrogeochemical stratification of the (suboxic target aquifer, and water quality changes of DSW during trial infiltration runs. We predict water quality changes of DSW after 824 d of infiltration, during 90 d of intensive recovery (67% recovered without storage (scenario A, as well as after 10 years of storage (scenario B, with significant bubble drift. Monitoring of preceding trials revealed a lack of redox reactions; little carbonate dissolution and Ca/Na exchange; much SiO2 dissolution; a strong mobilization of natural AsO43−, B, Ba, F, CrO42−, Mo, Sr and V from the (suboxic aquifer; and immobilization of PO4, Al, Cu, Fe and Ni from DSW. The Easy-Leacher model was applied in forward and reverse mode including lateral bubble drift, to predict water quality of the recovered water. We show that hydrogeochemical modeling of a complex ASR-system can be relatively easy and straightforward, if aquifer reactivity is low and redox reactions can be ignored. The pilot observations and modeling results demonstrate that in scenario A recovered water quality still complies with Abu Dhabi’s drinking water standards (even up to 85% recovery. For scenario B, however, the recovery efficiency declines to 60% after which various drinking water standards are exceeded, especially the one for chromium.

  9. An integrated economic model of multiple types and uses of water

    Science.gov (United States)

    Luckmann, Jonas; Grethe, Harald; McDonald, Scott; Orlov, Anton; Siddig, Khalid

    2014-05-01

    Water scarcity is an increasing problem in many parts of the world and the management of water has become an important issue on the political economy agenda in many countries. As water is used in most economic activities and the allocation of water is often a complex problem involving different economic agents and sectors, Computable General Equilibrium (CGE) models have been proven useful to analyze water allocation problems, although their adaptation to include water is still relatively undeveloped. This paper provides a description of an integrated water-focused CGE model (STAGE_W) that includes multiple types and uses of water, and for the first time, the reclamation of wastewater as well as the provision of brackish groundwater as separate, independent activities with specific cost structures. The insights provided by the model are illustrated with an application to the Israeli water sector assuming that freshwater resources available to the economy are cut by 50%. We analyze how the Israeli economy copes with this shock if it reduces potable water supply compared with further investments in the desalination sector. The results demonstrate that the effects on the economy are slightly negative under both scenarios. Counter intuitively, the provision of additional potable water to the economy through desalination does not substantively reduce the negative outcomes. This is mainly due to the high costs of desalination, which are currently subsidized, with the distribution of the negative welfare effect over household groups dependent on how these subsidies are financed.

  10. Unravelling and Reconstructing the Nexus of Salinity, Electricity, and Microbial Ecology for Bioelectrochemical Desalination.

    Science.gov (United States)

    Yuan, Heyang; Sun, Shan; Abu-Reesh, Ibrahim M; Badgley, Brian D; He, Zhen

    2017-11-07

    Microbial desalination cells (MDCs) are an emerging concept for simultaneous water/wastewater treatment and energy recovery. The key to developing MDCs is to understand fundamental problems, such as the effects of salinity on system performance and the role of microbial community and functional dynamics. Herein, a tubular MDC was operated under a wide range of salt concentrations (0.05-4 M), and the salinity effects were comprehensively examined. The MDC generated higher current with higher salt concentrations in the desalination chamber. When fed with 4 M NaCl, the MDC achieve a current density of 300 A m-3 (anode volume), which was one of the highest among bioelectrochemical system studies. Community analysis and electrochemical measurements suggested that electrochemically active bacteria Pseudomonas and Acinetobacter transferred electrons extracellularly via electron shuttles, and the consequent ion migration led to high anode salinities and conductivity that favored their dominance. Predictive functional dynamics and Bayesian networks implied that the taxa putatively not capable of extracellular electron transfer (e.g., Bacteroidales and Clostridiales) might indirectly contribute to bioelectrochemical desalination. By integrating the Bayesian network with logistic regression, current production was successfully predicted from taxonomic data. This study has demonstrated uncompromised system performance under high salinity and thus has highlighted the potential of MDCs as an energy-efficient technology to address water-energy challenges. The statistical modeling approach developed in this study represents a significant step toward understating microbial communities and predicting system performance in engineered biological systems.

  11. Manganese-Schiff base complexes as catalysts for water photolysis.

    Science.gov (United States)

    González-Riopedre, Gustavo; Fernández-García, M Isabel; González-Noya, Ana M; Vázquez-Fernández, M Ángeles; Bermejo, Manuel R; Maneiro, Marcelino

    2011-10-28

    Four manganese(III)-Schiff base complexes (1-4) of formula [MnL(n)(H(2)O)(2)](2)(ClO(4))(2)·mH(2)O (n = 1-4; m = 0, 1) have been prepared. The multidentate H(2)L(n) Schiff base ligands consist of 3R,5R-substituted N,N'-bis(salicylidene)-1,2-diimino-2,2-dimethylethane, where R = OEt, OMe, Br or Cl. The complexes have been thoroughly characterized by elemental analysis, mass spectrometry, magnetic susceptibility measurements, IR, UV, paramagnetic (1)H NMR and EPR spectroscopies. Other properties, including redox studies and molar conductivity measurements, have also been assessed. The crystal structure of 1 was solved by X-ray diffraction, which revealed the dimeric nature of the compound through μ-aqua bridges. The ability of these complexes to split water has been studied by water photolysis experiments, with the oxygen evolution measured in aqueous media in the presence of a hydrogen acceptor (p-benzoquinone), the reduction of which was followed by UV-spectroscopy. The discussion of the photolytic behaviour includes advances in the knowledge of the structural motifs and the chemical activity of this type of complex, as revealed by the development of several characterization techniques in the last decade. Parallel-mode Mn(III) EPR shows that complexes 1-4 not only mimic reactivity but also share some structural characteristics from partially assembled natural OEC clusters. This journal is © the Owner Societies 2011

  12. Generalized Least Energy of Separation for Desalination and Other Chemical Separation Processes

    Directory of Open Access Journals (Sweden)

    Karan H. Mistry

    2013-05-01

    Full Text Available Increasing global demand for fresh water is driving the development and implementation of a wide variety of seawater desalination technologies driven by different combinations of heat, work, and chemical energy. This paper develops a consistent basis for comparing the energy consumption of such technologies using Second Law efficiency. The Second Law efficiency for a chemical separation process is defined in terms of the useful exergy output, which is the minimum least work of separation required to extract a unit of product from a feed stream of a given composition. For a desalination process, this is the minimum least work of separation for producing one kilogram of product water from feed of a given salinity. While definitions in terms of work and heat input have been proposed before, this work generalizes the Second Law efficiency to allow for systems that operate on a combination of energy inputs, including fuel. The generalized equation is then evaluated through a parametric study considering work input, heat inputs at various temperatures, and various chemical fuel inputs. Further, since most modern, large-scale desalination plants operate in cogeneration schemes, a methodology for correctly evaluating Second Law efficiency for the desalination plant based on primary energy inputs is demonstrated. It is shown that, from a strictly energetic point of view and based on currently available technology, cogeneration using electricity to power a reverse osmosis system is energetically superior to thermal systems such as multiple effect distillation and multistage flash distillation, despite the very low grade heat input normally applied in those systems.

  13. Modeling and PSO optimization of Humidifier-Dehumidifier desalination

    Directory of Open Access Journals (Sweden)

    Mohammad Hossein Ahmadi

    2018-02-01

    Full Text Available The aim of this study is modeling a solar-air heater humidification-dehumidification unit with applying particle swarm optimization to find out  the maximum gained output ratio with respect to the mass flow rate of water and air entering humidifier, mass flow rate of cooling water entering dehumidifier, width and length of solar air heater and terminal temperature difference (TTD of dehumidifier representing temperature difference of inlet cooling water and saturated air to dehumidifier as its decision variable. A sensitivity analysis, furthermore, is performed to distinguish the effect of operating parameters including mass flow rate and streams’ temperature. The results showed that the optimum productivity decreases by decreasing the ratio of mass flow rate of water entering humidifier to air ones. Article History: Received: July 12th 2017; Revised: December 15th 2017; Accepted: 2nd February 2018; Available online How to Cite This Article: Afshar, M.A., Naseri, A., Bidi, M., Ahmadi, M.H. and Hadiyanto, H. (2018 Modeling and PSO Optimization of Humidifier-Dehumidifier Desalination. International Journal of Renewable Energy Development, 7(1,59-64. https://doi.org/10.14710/ijred.7.1.59-64

  14. Importance of hydrogen bonds to stabilities of copper water complexes

    Science.gov (United States)

    Sukrat, Kanjarat; Parasuk, Vudhichai

    2007-10-01

    An investigation of structures and stabilization energies of copper-water complexes is presented. Possible cluster geometries of [Cu(H 2O) n] 2+ for n = 1-8 were optimized using HF/6-31G(d,p), and energies were determined at the MP2/6-31G(d,p) and B3LYP/6-31G(d,p) levels of theory. In addition, for n = 6, 7, and 8 geometry optimizations at MP2/6-311g(d,p) have been carried out. The basis set effect on stabilization energies was also considered by performing MP2 with 6-31++G(d,p), 6-311G(d,p) and 6-311G(2df,p) single point energy calculations. Only five- and six-fold coordination complexes were obtained with square pyramid (spy) and octahedral (oct) copper coordination as their most stable structures. The hydrogen bonds which form between water molecules in the first and second solvation shell play an important role for the stabilities of the complexes.

  15. Mild desalination demo pilot: New normalization approach to effectively evaluate electrodialysis reversal technology

    Directory of Open Access Journals (Sweden)

    Roel Bisselink

    2016-06-01

    Full Text Available Key performance indicators for characterization of nanofiltration performance are well developed, similar key performance indicators for electrodialysis reversal are however underdeveloped. Under the E4Water project Dow Benelux BV and Evides Industriewater BV operate a pilot facility to compare both technologies for their application to mildly desalinate a variety of brackish water streams. Normalized pressure drop, normalized current efficiency and normalized membrane resistance proved to be a useful tool to interpret process performance and to initiate a cleaning procedure if required. The availability of these normalized key performance indicators enables optimization and process monitoring and control of electrodialysis reversal independent of the continuously changing conditions of the feed water.

  16. Performance investigation of an advanced multi-effect adsorption desalination (MEAD) cycle

    KAUST Repository

    Thu, Kyaw

    2015-12-01

    This article presents the development of an advanced adsorption desalination system with quantum performance improvement. The proposed multi-effect adsorption desalination (MEAD) cycle utilizes a single heat source i.e., low-temperature hot water (as low as 55°C). Passive heating of the feed water (no direct heating) is adopted using total internal heat recovery from the kinetic energy of desorbed vapor and water vapor uptake potential of the adsorbent. Thus, the evaporation in the MEAD cycle ensues at low temperatures ranging from 35°C to 7°C yet providing significantly high performance ratio. The energy from the regenerated vapor is recovered for multiple evaporation/condensation of saline water by a water-run-around circuit between the top brine temperature (TBT) effect and the AD condenser. The adsorbent material is the hydrophilic mesoporous silica gel with high pore surface area. Numerical simulation for such a cycle is developed based on experimentally verified model extending to multi-effect cycle. The system is investigated under several operation conditions such as cycle time allocation, heat source temperature and the number of intermediate effects. It is observed that most of the evaporating-condensing effects operate at low temperature i.e., below 35°C as opposed to conventional multi-effect distillation (MED) cycle. For a MEAD cycle with 7 intermediate effects, the specific water production rate, the performance ratio and the gain output ratio are found to be 1.0m3/htonne of silica gel, 6.3 and 5.1, respectively. Low scaling and fouling potentials being evaporation at low temperatures yet high recovery ratio makes the cycle suitable for effectively and efficiently handling highly concentrated feed water such as produced water, brine rejected from other desalination plants and zero liquid discharge (ZLD) system. © 2015 Elsevier Ltd.

  17. A novel integrated thermal-/membrane-based solar energy-driven hybrid desalination system: Concept description and simulation results

    KAUST Repository

    Kim, Youngdeuk

    2016-05-03

    In this paper, a hybrid desalination system consisting of vacuum membrane distillation (VMD) and adsorption desalination (AD) units, designated as VMD-AD cycle, is proposed. The synergetic integration of the VMD and AD is demonstrated where a useful effect of the AD cycle is channelled to boost the operation of the VMD process, namely the low vacuum environment to maintain the high pressure gradient across the microporous hydrophobic membrane. A solar-assisted multi-stage VMD-AD hybrid desalination system with temperature modulating unit is first designed, and its performance is then examined with a mathematical model of each component in the system and compared with the VMD-only system with temperature modulating and heat recovery units. The total water production and water recovery ratio of a solar-assisted 24-stage VMD-AD hybrid system are found to be about 21% and 23% higher, respectively, as compared to the VMD-only system. For the solar-assisted 24-stage VMD-AD desalination system having 150 m2 of evacuated-tube collectors and 10 m3 seawater storage tanks, both annual collector efficiency and solar fraction are close to 60%.

  18. Permeability of uncharged organic molecules in reverse osmosis desalination membranes.

    Science.gov (United States)

    Dražević, Emil; Košutić, Krešimir; Svalina, Marin; Catalano, Jacopo

    2017-06-01

    Reverse osmosis (RO) membranes are primarily designed for removal of salts i.e. for desalination of brackish and seawater, but they have also found applications in removal of organic molecules. While it is clear that steric exclusion is the dominant removal mechanism, the fundamental explanation for how and why the separation occurs remains elusive. Until recently there was no strong microscopic evidences elucidating the structure of the active polyamide layers of RO membranes, and thus they have been conceived as "black boxes"; or as an array of straight capillaries with a distribution of radii; or as polymers with a small amount of polymer free domains. The knowledge of diffusion and sorption coefficients is a prerequisite for understanding the intrinsic permeability of any organic solute in any polymer. At the same time, it is technically challenging to accurately measure these two fundamental parameters in very thin (20-300 nm) water-swollen active layers. In this work we have measured partition and diffusion coefficients and RO permeabilities of ten organic solutes in water-swollen active layers of two types of RO membranes, low (SWC4+) and high flux (XLE). We deduced from our results and recent microscopic studies that the solute flux of organic molecules in polyamide layer of RO membranes occurs in two domains, dense polymer (the key barrier layer) and the water filled domains. Copyright © 2017 Elsevier Ltd. All rights reserved.

  19. Seawater reverse osmosis desalination and (harmful) algal blooms

    KAUST Repository

    Villacorte, Loreen O.

    2015-03-01

    This article reviews the occurrence of HABs in seawater, their effects on the operation of seawater reverse osmosis (SWRO) plants, the indicators for quantifying/predicting these effects, and the pretreatment strategies for mitigating operational issues during algal blooms. The potential issues in SWRO plants during HABs are particulate/organic fouling of pretreatment systems and biological fouling of RO membranes, mainly due to accumulation of algal organic matter (AOM). The presence of HAB toxins in desalinated water is also a potential concern but only at very low concentrations. Monitoring algal cell density, AOM concentrations and membrane fouling indices is a promising approach to assess the quality of SWRO feedwater and performance of the pretreatment system. When geological condition is favourable, subsurface intake can be a robust pretreatment for SWRO during HABs. Existing SWRO plants with open intake and are fitted with granular media filtration can improve performance in terms of capacity and product water quality, if preceded by dissolved air flotation or sedimentation. However, the application of advanced pretreatment using ultrafiltration membrane with in-line coagulation is often a better option as it is capable of maintaining stable operation and better RO feed water quality during algal bloom periods with significantly lower chemical consumption.

  20. Design concept and its requirements of the integrated SMART nuclear desalination plant

    Energy Technology Data Exchange (ETDEWEB)

    Hwang, Young Dong; Kim, Young In; Chon, Bong Hyun; Lee, Doo Jung; Chang, Moon Hee

    2001-02-01

    The integrated SMART desalination plant consists of four(4) units of Multi Effect Distillation Process combined with Thermal-Vapor Compressor(MED-TVC) and coupled with the extracted steam from turbine through the steam transformer. Steam transformer produces the main pressure steam and supplies to the MED-TVC unit. Each distillation unit has the production the capacity of 10,000 m3/day of distilled water per day at top brine temperature of 65 deg C using the seawater supplied at temperature of 33 deg C. MED-TVC was selected as a desalination process coupled with SMART, since the thermal vapor compression is very effective where the steam is available at high temperature and pressure conditions than required in the evaporator. The MED-TVC unit is consisted of the steam supply system, vapor and condensate system, seawater supply system, brine system and chemical dosing system. The standard design of the SMART desalination plant is under development as a part of the SMART project. This report describes design concept of these systems and their requirements.

  1. Optimal Operation Method for Microgrid with Wind/PV/Diesel Generator/Battery and Desalination

    Directory of Open Access Journals (Sweden)

    Qingfeng Tang

    2014-01-01

    Full Text Available The power supply mode of island microgrid with a variety of complementary energy resources is one of the most effective ways to solve the problem of future island power supply. Based on the characteristics of seawater desalination system and water demand of island residents, a power allocation strategy for seawater desalination load, storage batteries, and diesel generators is proposed with the overall consideration of the economic and environmental benefits of system operation. Furthermore, a multiobjective optimal operation model for the island microgrid with wind/photovoltaic/diesel/storage and seawater desalination load is also proposed. It first establishes the objective functions which include the life loss of storage batteries and the fuel cost of diesel generators. Finally, the model is solved by the nondominated sorting genetic algorithm (NSGA-II. The island microgrid in a certain district is taken as an example to verify the effectiveness of the proposed optimal method. The results provide the theoretical and technical basis for the optimal operation of island microgrid.

  2. USE OF REJECT BRINE FROM DESALINATION ON DIFFERENT DEVELOPMENT STAGES OF HYDROPONIC LETTUCE

    Directory of Open Access Journals (Sweden)

    NILDO DA SILVA DIAS

    2011-01-01

    Full Text Available In order to evaluated the impact of the high salinity reject brine from reverse osmosis desalination on hydroponics lettuce cultivated in greenhouse an investigation was carried out in Mossoro, Northeast of Brazil (5º11'S, 37º20'O and 18m above sea. Two lettuce cultivars ('Verônica' and 'Babá de verão' were cultivated with a basic nutrient solution with 1.1 dS m-1 (control during the crop cycle (1-28 days after transplanting - DAT - T0 and with basic nutrient solution containing 50% of the reject water from desalinization with 4.8 dS m-1 exposed during 1-7, 21-28, 7-14 e 1-28 DAT (T1, T2, T3 and T4, respectively. The addition of 50% of brine reject from desalination into the hydroponic nutrient solution allows grow only 'Verônica' lettuce with no reduction in fresh biomass. This lettuce cultivar shows to be more tolerant to salinity for all exposure time with reject brine in the nutrition solution, despite the fact that 'Babá de Verão' cultivar is more productive.

  3. Use of Low-Temperature Geothermal Energy for Desalination in the Western United States

    Energy Technology Data Exchange (ETDEWEB)

    Turchi, Craig S. [National Renewable Energy Lab. (NREL), Golden, CO (United States); Akar, Sertac [National Renewable Energy Lab. (NREL), Golden, CO (United States); Cath, Tzahi [Colorado School of Mines, Golden, CO (United States)