WorldWideScience

Sample records for water chemical composition

  1. Public Health Risk Conditioned by Chemical Composition of Ground Water

    Science.gov (United States)

    Yankovich, E.; Osipova, N.; Yankovich, K.; Matveenko, I.

    2016-03-01

    The article studies the public health potential risk originated from water consumption and estimated on the basis of the groundwater chemical composition. We have processed the results of chemical groundwater analysis in different aquifers of Tomsk district (Tomsk Oblast, Russia). More than 8400 samples of chemical groundwater analyses were taken during long-term observation period. Human health risk assessment of exposure to contaminants in drinking water was performed in accordance with the risk assessment guidance for public health concerning chemical pollution of the environment (Russian reference number: 2.1.10.1920-04-M, 2004). Identified potential risks were estimated for consuming water of each aquifer. The comparative analysis of water quality of different aquifers was performed on the basis of the risk coefficient of the total non-carcinogenic effects. The non-carcinogenic risk for the health of the Tomsk district population due to groundwater consumption without prior sanitary treatment was admitted acceptable. A rather similar picture is observed for all aquifers, although deeper aquifers show lower hazard coefficients.

  2. Fog water chemical composition in different geographic regions of Poland

    Science.gov (United States)

    Błaś, Marek; Polkowska, Żaneta; Sobik, Mieczysław; Klimaszewska, Kamila; Nowiński, Kamil; Namieśnik, Jacek

    2010-03-01

    The fog water samples were collected with the use of both passive and active fog collectors during 2005-2006 at 3 sites: lowland in northern Poland (Borucino; 186 m a.s.l.), valley basin in southern Poland (Zakopane; 911 m a.s.l.) and mountain top (Szrenica Mt.; 1330 m a.s.l.) in south-western Poland. For all daily samples (Borucino—25; Zakopane—4 and Szrenica—155), electric conductivity, pH, and concentrations of some anions: Cl -, F -, Br -, NO 2-, NO 3-, SO 42-, PO 43-and cations: NH 4+, Ca 2+, K +, Na + and Mg 2+ were measured. The selected ions were determined using ion suppressed chromatography (IC). Fog consists of a specific type of atmospheric phenomena. Results obtained on the basis of analysis of suitable fog samples can be treated as a source of valuable information on the chemistry of the atmosphere. Statistical analysis revealed significant differences depending on region, altitude, local morphology and, last but not least, fog origin. A distinct contrast is evident in the concentration and chemical composition between lowland radiation fog (represents lower layers of the atmosphere which are more influenced by continental emissions) versus orographic slope fog represented by a summit station, Mt Szrenica. It is partly induced by a distinction in weather conditions favouring fog existence, height of fog formation and its microphysical parameters. Acidity was associated with high concentrations of excess sulphate and nitrate in the fog water samples. Ammonium and calcium concentrations represent the most important neutralizing inputs. Collected cloud water at Szrenica Mt. includes solute contributions from emission sources located at much larger upwind distances. The fact that 95% of fog/cloud deposition is concentrated during SW-W-NW-N-NE, atmospheric circulation exerts an influence on the environmental quality of montane forests in the Sudety Mts. At numerous conspicuous convex landforms, where fog/cloud deposition becomes at least as important

  3. Chemical composition of water from roofs in Gdansk, Poland

    Energy Technology Data Exchange (ETDEWEB)

    Tsakovski, Stefan, E-mail: stsakovski@chem.uni-sofia.b [Chair of Physical Chemistry, Faculty of Chemistry, University of Sofia, J Bourchier Blvd. 1, 1164 Sofia (Bulgaria); Tobiszewski, Marek [Department of Analytical Chemistry, Chemical Faculty, Gdansk University of Technology (GUT), 11/12 G. Narutowicza St., 80-952 Gdansk (Poland); Simeonov, Vasil, E-mail: vsimeonov@chem.uni-sofia.b [Chair of Analytical Chemistry, Faculty of Chemistry, University of Sofia, 1164 Sofia (Bulgaria); Polkowska, Zaneta [Department of Analytical Chemistry, Chemical Faculty, Gdansk University of Technology (GUT), 11/12 G. Narutowicza St., 80-952 Gdansk (Poland); Namiesnik, Jacek, E-mail: chemanal@pg.gda.p [Department of Analytical Chemistry, Chemical Faculty, Gdansk University of Technology (GUT), 11/12 G. Narutowicza St., 80-952 Gdansk (Poland)

    2010-01-15

    This study deals with the assessment of roof runoff waters from the region of Gdansk collected during the winter season (2007/2008). The chemical analysis includes 16 chemical variables: major ions, PAHs and PCBs measured at 3 sampling sites for 6-14 rain events. Although the data set is of limited volume the statistical data treatment using self-organizing maps (SOM) reveals the main factors controlling roof runoff water quality even for a data set with small dimension. This effort for explanation of the identified factors by the possible emission sources of the urban environment and air-particulate formation seems to be very reliable. Additionally to the roof runoff water quality factors the rain events patterns are found: 'background' group of events and groups formally named 'PAHs', 'PCBs' and 'air-borne particles' - dominated events. The SOM classification results give an opportunity to uncover the role of roof 'impact' on the runoff waters. Rain runoff water quality is described by four latent factors and the 'roof' impact is uncovered. - Identification of the urban roof runoff water quality factors and 'roof' impact by self-organizing map classification.

  4. The chemical composition and biological properties of coconut (Cocos nucifera L.) water.

    Science.gov (United States)

    Yong, Jean W H; Ge, Liya; Ng, Yan Fei; Tan, Swee Ngin

    2009-12-09

    Coconut water (coconut liquid endosperm), with its many applications, is one of the world's most versatile natural product. This refreshing beverage is consumed worldwide as it is nutritious and beneficial for health. There is increasing scientific evidence that supports the role of coconut water in health and medicinal applications. Coconut water is traditionally used as a growth supplement in plant tissue culture/micropropagation. The wide applications of coconut water can be justified by its unique chemical composition of sugars, vitamins, minerals, amino acids and phytohormones. This review attempts to summarise and evaluate the chemical composition and biological properties of coconut water.

  5. The Chemical Compositions of Thermal Waters at Ciarinem and Cilayu, Pameungpeuk, West Java - Indonesia

    Directory of Open Access Journals (Sweden)

    N.R. Herdianita

    2008-03-01

    Full Text Available Thermal waters at Ciarinem and Cilayu, Pameungpeuk, West Java, Indonesia have different characteristics: Ciarinem water is a steam heated sulfate type and occurs as hot springs, whereas Cilayu water discharges as hot pools and is a chloride water type. Their chemical compositions indicate that the thermal waters are outflows of a volcanic–magmatic associated geothermal system. The solute geothermometers calculate that the subsurface reservoir temperatures range from 150o to 200ºC.

  6. Chemical composition of runoff water in Raipur city, central India

    Science.gov (United States)

    Ambade, Balram

    2015-03-01

    Runoff water is an important transporting medium for various pollutants from land to surface water. Several mobiles and stationary sources such as vehicles, steel cement and thermal power plants, cooking, street, construction debris, etc. are emitting effluents in the environment of the central India. The rain runoff water washes out the air as well as land pollutants and flushes out into water bodies. Therefore, rain runoff water pollution in most urbanized and industrialized city of central India, i.e., Raipur during rainy season (May-September 2012) is analyzed statistically using cluster and principal component analysis to assess sources. The cluster analysis grouped runoff water samples into two clusters based on the similarity of runoff water quality characteristics of the total variance. The factor analysis differentiated the diffused sources of runoff water contaminants. The enrichment factors and runoff fluxes of the contaminants are discussed.

  7. Chemical composition of groundwater/drinking water and oncological disease mortality in Slovak Republic.

    Science.gov (United States)

    Rapant, S; Cvečková, V; Fajčíková, K; Dietzová, Z; Stehlíková, B

    2017-02-01

    This study deals with the analysis of relationship between chemical composition of the groundwater/drinking water and the data on mortality from oncological diseases (MOD) in the Slovak Republic. Primary data consist of the Slovak national database of groundwater analyses (20,339 chemical analyses, 34 chemical elements/compounds) and data on MOD (17 health indicators) collected for the 10-year period (1994-2003). The chemical and health data were unified in the same form and expressed as the mean values for each of 2883 municipalities within the Slovak Republic. Pearson and Spearman correlation as well as artificial neural network (ANN) methods were used for analysis of the relationship between chemical composition of groundwater/drinking water and MOD. The most significant chemical elements having influence on MOD were identified together with their limit values (limit and optimal contents). Based on the results of calculations, made through the neural networks, the following eight chemical elements/parameters in the groundwater were defined as the most significant for MOD: Ca + Mg (mmol l(-1)), Ca, Mg, TDS, Cl, HCO3, SO4 and NO3. The results document the highest relationship between MOD and groundwater contents of Ca + Mg (mmol l(-1)), Ca and Mg. We observe increased MOD with low (deficit) contents of these three parameters of groundwater/drinking water. The following limit values were set for the most significant groundwater chemicals/parameters: Ca + Mg 1.73-5.85 mmol l(-1), Ca 60.5-196.8 mg l(-1) and Mg 25.6-35.8 mg l(-1). At these concentration ranges, the mortality for oncological diseases in the Slovak Republic is at the lowest levels. These limit values are about twice higher in comparison with the current Slovak valid guideline values for the drinking water.

  8. Assessment of Water and Sediment Physical-Chemical Composition in the West Coast of Maracaibo Lake

    Directory of Open Access Journals (Sweden)

    Jorge Moronta-Riera

    2016-05-01

    Full Text Available The objective of this investigation was to determine the physical and chemical composition of the water streams and sediments of the Maracaibo Lake in three sampling areas located in Tía Juana, Lagunillas and Ceuta in order to know the level of contamination and assess water quality based on permissible values established by the 883 Decree. The results indicate that the overall hydrocarbon concentrations in the water and sediments are above permissible levels. It is concluded that petroleum prospection is the root cause of the lake contamination.

  9. Estimation of aerosol water and chemical composition from AERONET at Cabauw, the Netherlands

    Directory of Open Access Journals (Sweden)

    A. J. van Beelen

    2013-06-01

    Full Text Available Remote sensing of aerosols provides important information on the atmospheric aerosol abundance. However, due to the hygroscopic nature of aerosol particles observed aerosol optical properties are influenced by atmospheric humidity, and the measurements do not unambiguously characterize the aerosol dry mass and composition which complicates the comparison with aerosol models. In this study we derive aerosol water and chemical composition by a modeling approach that combines individual measurements of remotely sensed aerosol properties (e.g. optical thickness, single scattering albedo, refractive index and size distribution from an AERONET (Aerosol Robotic Network sun-photometer with radiosonde measurements of relative humidity. The model simulates water uptake by aerosols based on the chemical composition and size distribution. A minimization method is used to calculate aerosol composition and concentration, which are then compared to in situ measurements from the Intensive Measurement Campaign At the Cabauw Tower (IMPACT, May 2008, the Netherlands. Computed concentrations show reasonable agreement with surface observations and follow the day-to-day variability in observations. Total dry mass (33 ± 12 μg m−3 and black carbon concentrations (0.7 ± 0.3 μg m−3 are generally accurately computed. The uncertainty in the AERONET (real refractive index (0.025–0.05 introduces larger uncertainty in the modeled aerosol composition (e.g. sulfates, ammonium nitrate or organic matter and leads to an uncertainty of 0.1–0.25 in aerosol water volume fraction. Water volume fraction is highly variable depending on composition, up to >0.5 at 70–80% and <0.1 at 40% relative humidity.

  10. Forming chemical composition of surface waters in the Arctic. Case study of Lake Inari and the River Paz

    Directory of Open Access Journals (Sweden)

    Mazukhina S. I.

    2017-03-01

    Full Text Available Questions of studying the formation of surface and ground waters, their interaction with rocks, development of the basics of their rational use and protection are of great fundamental and practical importance. The influence of the northern Fennoscandian (Baltic Shield rock composition on forming surface waters' chemical composition in the border area of Finland – Russia – Norway (Lake Inari, the River Paz using physical-chemical modeling (Selector software package has been evaluated. For the physical-chemical modeling there have been made two samples of chemical analyses of the most widespread rocks forming the catchment area, with their percentage ratio taken into consideration. Since the catchment area of the prevailing majority of streams feeding Lake Inari is composed of rocks of the Lapland granulite belt (LGB and its framing, it will be the main sample (conditional influence of their composition on the chemical composition of waters is about 80 %. The second sample includes gneisses, migmatites, granite-gneisses, granites and quartz diorites typical for Inari terrane (conventional influence of their composition on the chemical composition of waters is about 20 %. It has been found that the chemical composition of the surface waters is formed by interaction of precipitation with intrusive, metamorphic and sedimentary rocks of northern Fennoskandia containing Clarke concentrations of S, C, F, Zn, Ni, Pb, Cu. It has been shown that due to interactions in the water – rock system the chemical composition of Lake Inari waters as well as upper and middle flow of the River Paz is formed by weathering of granulites of the Lapland granulite belt and Inari terrane granitoids of the northern Fennoscandia. The chemical composition of waters in the River Paz downstream is formed by weathering of metamorphosed volcanic and sedimentary rocks of the Pechenga structure and the impact of industrial pollution

  11. Characterizing the variability in chemical composition of flowback and produced waters - results from lab and field studies

    Science.gov (United States)

    Vieth-Hillebrand, Andrea; Wilke, Franziska D. H.; Schmid, Franziska E.; Zhu, Yaling; Lipińska, Olga; Konieczyńska, Monika

    2017-04-01

    The huge volumes and unknown composition of flowback and produced waters cause major public concerns about the environmental and social compatibility of hydraulic fracturing and the exploitation of gas from unconventional reservoirs. Flowback and produced waters contain not only residues of fracking additives but also chemical species that are dissolved from the target shales themselves. Shales are a heterogeneous mixture of minerals, organic matter, and formation water and little is actually understood about the fluid-rock interactions occurring during hydraulic fracturing of the shales and their effects on the chemical composition of flowback and produced water. To overcome this knowledge gap, interactions of different shales with different artificial stimulation fluids were studied in lab experiments under ambient and elevated temperature and pressure conditions. These lab experiments showed clearly that fluid-rock interactions change the chemical composition of the initial stimulation fluid and that geochemistry of the fractured shale is relevant for understanding flowback water composition. In addition, flowback water samples were taken after hydraulic fracturing of one horizontal well in Pomeranian region, Poland and investigated for their chemical composition. With this presentation, results from lab and field studies will be presented and compared to decipher possible controls on chemical compositions of flowback and produced water.

  12. The effects of saline irrigation water and cobalt on growth and chemical composition in Nigella sativa

    Directory of Open Access Journals (Sweden)

    KHALID A. KHALID

    2014-11-01

    Full Text Available Khalid KA, Shedeed MR. 2014. The effects of saline irrigation water and cobalt on growth and chemical composition in Nigella sativa.Nusantara Bioscience 6: 146-151. Increasing plant salinity tolerance is a focus of research and industry since salinity and yield are of major concern to maximize medicinal and aromatic plant production in arid and semi-arid areas. Therefore, the present study aimed to decrease the harmful effect of salinity on Nigella sativa L plants by adapting them to saline soil stress through the use of Cobalt. The effects of saline irrigation water and cobalt on the vegetative growth characters [plant height (cm, leaf number (plant-1, branch number (plant-1, capsule number (plant1, herb dry weight (plant-1 and seed yield (plant-1] and content of fixed oil, soluble sugars, proline, N,P,K and protein of black seed (Nigella sativa L. plants were investigated. In these experiments, two factors were considered: saline irrigation water and Cobalt. The experimental design followed a complete random block design. The averages of data were statistically analyzed using 2-way analysis of variance (ANOVA-2 and the values of least significant difference (LSD at 5%. Saline irrigation water decreased certain growth characters, fixed oil, protein and mineral content (N, P and K as saline irrigation water level increased. Saline irrigation water promoted the accumulation of soluble sugars and proline contents. The plants treated with saline irrigation water containing cobalt resulted in higher plant growth characters and chemical constituent’s values than those treated with saline irrigation water alone.

  13. RECOGNITION OF MAIN PROCESSES FORMING CHEMICAL COMPOSITION OF THE SUPRAŚL RIVER WATER

    Directory of Open Access Journals (Sweden)

    Mirosław Skorbiłowicz

    2016-01-01

    Full Text Available The aim of the study was to identify and define the processes that affect the variability of the chemical composition of Supraśl river water at selected measuring points. One of the recognized multivariate statistical methods was used for identification. The research area covered the Suprasl river. Four measuring points were selected on the river – Michałowo, Gródek, Nowodworce, Dzikie. The measuring points were selected in such a way to take into account the impact of the most intense interaction located along the river. Changes in concentration were determined on the basis of monthly analyzes of water samples collected from the Supraśl river in 2003–2012 by the Regional Inspectorate for Environmental Protection (RIEP in Białystok. The analyses were performed in the RIEP laboratory in Bialystok, which has implemented and maintained a management system that meets the requirements of the norm PN-EN ISO/IEC 17025 + Ap.1:2007 approved by the certificate AB 165. The water samples were subject to determinations of dissolved oxygen concentration, BOD5, CODMn, CODCr, NH3, N-NH4+, NKieldahl, NO3-, N-NO3-, NO2-, N-NO2-, Ntot., PO43-, Ptot and electrical conductivity value. The monthly sum of precipitation was read based on data from the Weather Service “IMGW-PIB Monitor”. The research and analysis results allowed to identify the self-cleaning, nitrification, and de-nitrification processes, as well as enrichment affecting the variability of the chemical composition of the Supraśl river water. The results from the factor analysis showed some prevailing of enrichment processes over internal changes in the aquatic environment of the Supraśl river.

  14. Estimation of aerosol water and chemical composition from AERONET at Cabauw, the Netherlands, Atmos. Chem. Phys. Discuss., 13, ,

    NARCIS (Netherlands)

    Beelen, A.J. van; Roelofs, G.J.H.; Hasekamp, O.P.; Henzing, J.S.; Röckmann, T.

    2013-01-01

    This study is of our particular interest as the quality of our chemical transport model Lotos-Euros can be improved by our understanding of the aerosol-light interaction. In this study we derive aerosol water and chemical composition by a modeling approach that combines in situ measured and remotely

  15. Formation of the chemical composition of water in channel head in postglacial areas (West Pomerania, Poland)

    Science.gov (United States)

    Mazurek, Małgorzata; Kruszyk, Robert; Szpikowska, Grażyna

    2016-04-01

    The channel head is a zone of hydrological changes determining the hydrochemical features of water in the final stage of groundwater flow and the start of the surface cycle. The chemistry of water flowing out of a channel head reflects not only the characteristics of groundwater feeding the zone, but also changes it undergoes in this area during the organisation of channel flow. Groundwater interacts with surface water in the hyporheic zone where water from different environments is mixed and exchanged due to high hydraulic and chemical gradients. The goal of this study was to assess spatial differences in the concentrations of nutrients and compounds produced by chemical weathering in a channel head and to establish the role of the hyporheic zone in the transformation of the chemical composition of groundwater supplying a 1st-order stream. The research area was the channel head Żarnowo, located on the southern slope of the upper Parsęta valley. Three hydrochemical mappings were conducted in the headwater alcove consisting of three parts developed in a glaciofluvial plain and an erosional-accumulative alluvial terrace. Water was sampled in places of groundwater outflow in the footslope zone (9 sites), the hyporheic zone (14 sites), and outflows in the individual alcove parts and the rivulet they formed (5 sites). Water temperature, pH, and electrical conductivity were measured in the field. Concentrations of K, Ca, Mg, Na, Fe, Mn, HCO3, Cl, NO3, PO4, SO4 and SiO2 were determined in the laboratory. The chemical composition of ground- and surface water shows the concentration of geogenic components like K, Ca, Mg, Na, HCO3, and SiO2 to be an effect of chemical weathering and the leaching of its products taking place in a zero-discharge catchment. Those ions display little spatial variability and a stability of concentration in individual measurement periods, while the greatest disproportions in their concentrations among the alcove parts were recorded for Cl, NO3

  16. CASTOR BEAN PRODUCTION AND CHEMICAL ATTRIBUTES OF SOIL IRRIGATED WITH WATER WITH VARIOUS CATIONIC COMPOSITIONS

    Directory of Open Access Journals (Sweden)

    GEOVANI SOARES DE LIMA

    2016-01-01

    Full Text Available This study aimed to evaluate the production of castor beans, cv. „BRS Energia‟, in terms of soil chemical composition as a function of the cationic nature, and salinity levels, of the irrigation water. The experiment was carried out using lysimeters in a controlled environment at the Center of Technology and Natural Resources of the Federal University of Campina Grande, from November 2013 to February 2014. The treatments consisted of six types of salinity (S 1 - Control; S 2 - Na + ; S 3 - Ca 2+ ; S 4 - Na + + Ca 2+ ; S 5 - K + , and S 6 - Na + + Ca 2+ + Mg 2+ , distributed in randomized blocks with four replicates; each plot consisted of five plants for evaluation, totaling 120 experimental plots. Plants in the control treatment (S 1 were irrigated with water with an electrical conductivity (ECw of 0.6 dS m - 1 , and the other treatments (S 2 ; S 3 ; S 4 ; S 5 and S 6 with ECw of 4.5 dS m - 1 , but with (a different cation(s. Water salinity of 4.5 dS m - 1 hampers castor bean production, regardless of the cationic nature of the water; castor bean „BRS Energia‟ was more sensitive to salinity caused by the presence of potassium salts in the irrigation water; the mass of seeds in the primary raceme is the most sensitive variable to salinity and the cationic nature of the irrigation water; the adopted leaching fraction (0.10 was not sufficient to avoid salt accumulation in the soil; irrigation with low ECw promoted the lowest value of exchangeable sodium percentage.

  17. Chemical Composition and Water Permeability of Fruit and Leaf Cuticles of Olea europaea L.

    Science.gov (United States)

    Huang, Hua; Burghardt, Markus; Schuster, Ann-Christin; Leide, Jana; Lara, Isabel; Riederer, Markus

    2017-10-03

    The plant cuticle, protecting against uncontrolled water loss, covers olive (Olea europaea) fruits and leaves. The present study describes the organ-specific chemical composition of the cuticular waxes and the cutin and compares three developmental stages of fruits (green, turning, and black) with the leaf surface. Numerous organ-specific differences, such as the total coverage of cutin monomeric components (1034.4 μg cm(-2) and 630.5 μg cm(-2)) and the cuticular waxes (201.6 μg cm(-2) and 320.4 μg cm(-2)) among all three fruit stages and leaves, respectively, were detected. Water permeability as the main cuticular function was 5-fold lower in adaxial leaf cuticles (2.1 × 10(-5) m s(-1)) in comparison to all three fruit stages (9.5 × 10(-5) m s(-1)). The three fruit developmental stages have the same cuticular water permeability. It is hypothesized that a higher weighted average chain length of the acyclic cuticular components leads to a considerably lower permeability of the leaf as compared to the fruit cuticle.

  18. Salinity variations and chemical compositions of waters in the Frio Formation, Texas Gulf Coast. Annual report

    Energy Technology Data Exchange (ETDEWEB)

    Morton, R.A.; Garrett, C.M. Jr.; Posey, J.S.; Han, J.H.; Jirik, L.A.

    1981-11-01

    Waters produced from sandstone reservoirs of the deep Frio Formation exhibit spatial variations in chemical composition that roughly coincide with the major tectonic elements (Houston and Rio Grande Embayments, San Marcos Arch) and corresponding depositional systems (Houston and Norias deltas, Greta-Carancahua barrier/strandplain system) that were respectively active along the upper, lower, and middle Texas Coast during Frio deposition. Within an area, salinities are usually depth dependent, and primary trends closely correspond to pore pressure gradients and thermal gradients. Where data are available (mainly in Brazoria County) the increases in TDS and calcium with depth coincide with the zone of albitization, smectite-illite transition, and calcite decrease in shales. Waters have fairly uniform salinities when produced from the same sandstone reservoir within a fault block or adjacent fault blocks with minor displacement. In contrast, stratigraphically equivalent sandstones separated by faults with large displacement usually yield waters with substantially different salinities owing to the markedly different thermal and pressure gradients across the faults that act as barriers to fluid movement.

  19. New composite sorbents of water and ammonia for chemical and adsorption heat pumps

    Science.gov (United States)

    Aristov, Yu. I.; Vasiliev, L. L.

    2006-11-01

    New sorbents of water and ammonia — “salt in porous matrix” composites and “salt on fiber” composites — have been reviewed. The possibility of “constructing” the sorption properties of the composites at the nanophase level by varying their composition, the size of the host-matrix pores, and synthesis conditions has been shown. The application of the new materials in adsorption refrigerating devices has been considered.

  20. Impact of chemical treatments on the mechanical and water absorption properties of coconut fibre (Cocos nucifera reinforced polypropylene composites

    Directory of Open Access Journals (Sweden)

    Isiaka O. OLADELE

    2016-07-01

    Full Text Available In this work, chemically treated coconut fibres were used to reinforce Homopolymer Polypropylene in order to ascertain the effect of the treatments on the mechanical and water absorption properties of the composites produced. Coconut fibre was first extracted from its husk by soaking it in water and was dried before it was cut into 10 mm lengths. It was then chemically treated in alkali solution of sodium hydroxide (NaOH and potassium hydroxide (KOH in a shaker water bath. The treated coconut fibres were used as reinforcements in polypropylene matrix to produce composites of varied fibre weight contents; 2, 4, 6, 8 and 10 wt.%. Tensile and flexural properties were investigated using universal testing machine while water absorption test was carried out on the samples for 7 days. It was observed from the results that, NaOH treated samples gave the best tensile properties while KOH treated samples gave the best flexural and water repellent properties.

  1. Dispersion and toxicity of selected manufactured nanomaterials in natural river water samples: effects of water chemical composition.

    Science.gov (United States)

    Gao, Jie; Youn, Sejin; Hovsepyan, Anna; Llaneza, Veronica L; Wang, Yu; Bitton, Gabriel; Bonzongo, Jean-Claude J

    2009-05-01

    Experimental conditions that mimic likely scenarios of manufactured nanomaterials (MNs) introduction to aquatic systems were used to assessthe effect of nanoparticle dispersion/solubility and water chemical composition on MN-toxicity. Aqueous suspensions of fullerenes (C60), nanosilver (nAg), and nanocopper (nCu) were prepared in both deionized water and filtered (0.45 microm) natural river water samples collected from the Suwannee River basin, to emphasize differences in dissolved organic carbon (DOC) concentrations and solution ionic strengths (I). Two toxicity tests, the Ceriodaphnia dubia and MetPLATE bioassays were used. Results obtained from exposure studies show that water chemistry affects the suspension/solubility of MNs as well as the particle size distribution, resulting in a wide range of biological responses depending on the type of toxicity test used. Under experimental conditions used in this study, C60 exhibited no toxicity even when suspended concentrations exceeded 3 mg L(-1). MetPLATE results showed that the toxicity of aqueous suspensions of nCu tends to increase with increasing DOC concentrations, while increasing I reduces nCu toxicity. The use of the aquatic invertebrate C. dubia on the other hand showed a tendency for decreased mortality with increasing DOC and I. MetPLATE results for nAg showed decreasing trends in toxicity with increasing DOC concentrations and I. However, C. dubia exhibited contrasting biological responses, in that increasing DOC concentrations reduced toxicity, while the latter increased with increasing I. Overall, our results show that laboratory experiments that use DI-water and drastic MN-suspension methods may not be realistic as MN-dispersion and suspension in natural waters vary significantly with water chemistry and the reactivity of MNs.

  2. Relating the Chemical Composition of Dissolved Organic Matter Draining Permafrost Soils to its Photochemical Degradation in Arctic Surface Waters.

    Science.gov (United States)

    Ward, C.; Cory, R. M.

    2015-12-01

    Thawing permafrost soils are expected to shift the chemical composition of DOM exported to and degraded in arctic surface waters. While DOM photo-degradation is an important component of the freshwater C cycle in the Arctic, the molecular controls on DOM photo-degradation remain poorly understood, making it difficult to predict how shifting chemical composition may alter DOM photo-degradation in arctic surface waters. To address this knowledge gap, we quantified the susceptibility of DOM draining the shallow organic mat and the deeper permafrost layer to complete photo-oxidation to CO₂ and partial photo-oxidation to compounds that remain in the DOM pool, and investigated changes in DOM chemical composition following sunlight exposure. DOM leached from the organic mat contained higher molecular weight, more oxidized and unsaturated aromatic species compared to permafrost DOM. Despite significant differences in initial chemical composition, permafrost and organic mat DOM had similar susceptibilities to complete photo-oxidation to CO₂. Concurrent losses of carboxyl moieties and shifts in chemical composition during photo-degradation indicated that carboxyl-rich tannin-like compounds in both DOM sources were likely photo-decarboxylated to CO₂. Permafrost DOM had a higher susceptibility to partial photo-oxidation compared to organic mat DOM, potentially due to a lower abundance of phenolic compounds that act as "antioxidants" and slow the oxidation of DOM. These results demonstrated how chemical composition controls the photo-degradation of DOM in arctic surface waters, and that DOM photo-degradation will likely remain an important component of the freshwater C budget in the Arctic with increased export of permafrost DOM to surface waters.

  3. The Chemical Composition of Surface Waters of Technogenically Affected Geo-Systems in the Eastern Donbas Region

    Directory of Open Access Journals (Sweden)

    Olga S. Reshetnyak

    2014-11-01

    Full Text Available Based on an analysis of literary data and the author’s own research findings, the paper assesses the factors in the formation of the chemical composition of surface and subterranean waters and the variability of the chemical composition and quality of river waters in the eastern Donbas region. The author illustrates that the major negative effect of the impact of technogenic waters on river waters is salinization. The paper points up a high level of pollution in river waters with a broad spectrum of metal compounds, among which the biggest threat comes from Fegen, Al, Mn, Cu, and Sr, which is of a steady nature. The quality of water in the majority of rivers in the eastern Donbas region is evaluated as Quality Class 4 – dirty and/or very dirty. The findings can be used in resolving a whole array of scientific and applied objectives related to assessing the migration of chemical substances and the level of pollution in surface and subterranean waters and forecasting the condition of water sites and the quality of water, as well as in carrying out water-protection activities in the region.

  4. Chemical Composition of Apricot Pit Shells and Effect of Hot-Water Extraction

    Directory of Open Access Journals (Sweden)

    Derek B. Corbett

    2015-09-01

    Full Text Available Agricultural residues, such as corn stover, wheat straw, and nut shells show promise as feedstocks for lignocellulosic biorefinery due to their relatively high polysaccharide content and low or no nutritional value for human consumption. Apricot pit shells (APS were studied in this work to assess their potential for use in a biorefinery. Hot water extraction (HWE; 160 °C, 2 h, proposed to remove easily accessible hemicelluloses, was performed to evaluate the susceptibility of APS to this mild pretreatment process. The chemical composition of APS before and after HWE (EAPS was analyzed by standard methods and 1H-NMR. A low yield of the remaining HW-extracted APS (~59% indicated that APS are highly susceptible to this pretreatment method. 1H-NMR analysis of EAPS revealed that ~77% of xylan present in raw APS was removed along with ~24% of lignin. The energy of combustion of APS was measured before and after HWE showing a slight increase due to HWE (1.61% increase. Near infrared radiation spectroscopy (NIRS, proposed as a quick non-invasive method of biomass analysis, was performed. NIRS corroborated results of traditional analysis and 1H-NMR. Determination of antioxidizing activity (AOA of APS extracts was also undertaken. AOA of organic APS extracts were shown to be more than 20 times higher than that of a synthetic antioxidizing agent.

  5. The influence of chemical composition on vaporisation of LNG and LPG on unconfined water surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Conrado, C.; Vesovic, V. [Imperial College of Science, Technology and Medicine, London (United Kingdom). T.H. Huxley School of Environment, Earth Sciences and Engineering

    2000-07-01

    A model is proposed for estimating the rate of vaporisation of LNG and LPG cryogen mixtures spreading on unconfined water surfaces. The model is used to examine the influence of chemical composition on the vaporisation rate of LNG and LPG during spreading. Calculations have been performed whereby the vaporisation rate of the LNG and LPG mixtures has been compared to the vaporisation of pure methane and propane, respectively, under the same initial conditions. The detailed results indicate that the vaporisation rate of LNG mixture is markedly different to that of pure methane, while the vaporisation rate of LPG mixture is similar to that of pure propane. The difference can be attributed primarily to the contributions of the direct and indirect component of the total, different, isobaric latent heat to the boiling process. For LNG, as the liquid mixture gets rich in ethane, the total, differential, isobaric latent heat increases rapidly, leading to a large decrease in the vaporisation of LNG compared to pure methane. For LPG, because of the shape of the phase envelope, only a small increase of the total latent heat and the boiling temperature is observed and consequently the change in the vaporisation is marginal. The overall results suggest that treating an LNG spill as a pure methane spill results in underestimation of the total spillage time of the order of 10-15% and in qualitatively wrong dynamics of the rate of vapour formation: thus warranting a full treatment of the thermodynamics of the mixture. (Author)

  6. Chemical composition of natural waters of contaminated area: The case for the Imandra Lake catchment (the Kola Peninsula)

    Science.gov (United States)

    Evtyugina, Z. A.; Guseva, N. V.; Kopylova, J. G.; A, Vorobeva D.

    2016-03-01

    The study of the current chemical composition of natural waters in the eastern and western parts of the Imandra Lake catchment was performed using ion chromatography, potentiometry and inductively coupled plasma mass spectrometry. It was found that the content of trace elements in the surface water is considerably higher than that in the groundwater. The nickel and copper concentrations exceed the background levels over 19 and 2 times respectively in groundwater, and 175 and 61 times in the surface waters. These data show that the Severonikel influences negatively air and surface water.

  7. The Influence of Element Diffusion at the Sediment—Water Interface on the Basic Chemical Composition of Overlying Water Mass in Lake Lugu,China

    Institute of Scientific and Technical Information of China (English)

    吴丰昌; 万国江; 等

    1996-01-01

    Little work has been done on the influence of seiments on the basic chemical composition of overlying water mass.This paper deals with the vertical profile of the basic constituents such as Ca+,K+,Na+,and HCO3-,as well as of pH in the overlying water mass and sediment porewater of Lake Lugu-a semi-closed,deep lake in Yunnan Province.The reand sediment porewater of Lake Lugu- a semi-closed,deep lake in Yunnan Province.The results revealed that those basic constituents may diffuse and transport from bottom sediments to overlying water mass through porewater.In the paper are also quantitatively evaluated the diffusive fluxes and the extent of their influence on overlying water mass,indicating that the lake sediment-water interface diffusion plays an important role in controlling the basic chemical composition of water in the whole lake.

  8. Chemical composition of water buffalo milk and its low-fat symbiotic yogurt development

    Directory of Open Access Journals (Sweden)

    Xue Han

    2012-04-01

    Full Text Available Background: Water buffalos are the second most widely available milk source in countries around the world. While typical average milk compositions are readily available, information on seasonal variation in chemical composition of buffalo milk is limited -especially in the Northeastern region of the United States. Data collected in this study can be useful for the manufacture of a wide variety of specialty dairy products such as symbiotic buffalo milk yogurt. To analyze functionality, symbiotic low fat buffalo milk yogurt prototypes (plain and blueberry were developed using a commercial starter containing probiotics. Methods: During a one-year cycle, physicochemical and mineral contents of buffalo milk were analyzed. Prototype yogurts were manufactured commercially and samples of the yogurt prototypes were analyzed for physicochemical and microbiological properties and for the survivability of probiotics during ten weeks of storage.Results: Average contents of total solids, fat, lactose, crude protein, ash, specific gravity, and conjugated linoleic acid in the milk ranged from 16.39-18.48%, 6.57-7.97%, 4.49-4.73%, 4.59-5.37%, 0.91-0.92%, 1.0317-1.0380%, and 4.4-7.6 mg/g fat, respectively. The average mineral contents of calcium, phosphorous, potassium, magnesium, sodium, and zinc in the milk were 1798.89, 1216.76, 843.72, 337.20 and 7.48 mg/kg, respectively, and remained steady throughout the year. The symbiotic low fat buffalo milk yogurts evaluated in this study contained higher amounts of protein, carbohydrates, and calcium than similar yogurts manufactured with cows’ milk. During refrigerated storage, the probiotic Lactobacillus acidophilus was viable (>1×106CFU/g for the first two weeks, while Bifidobacterium spp.Functional Foods in Health and Disease 2012, 2(4:86-106 and Lactobacillus casei remained viable during the entire ten weeks. Reducing the acidity and enhancing the flavor of the yogurts could improve the overall acceptability

  9. Forming chemical composition of surface waters in the Arctic as "water - rock" interaction. Case study of lake Inari and river Paz

    Science.gov (United States)

    Mazukhina, Svetlana; Sandimirov, Sergey; Pozhilenko, Vladimir; Ivanov, Stanislav; Maksimova, Viktoriia

    2017-04-01

    Due to the depletion of fresh water supplies and the deterioration of their quality as a result of anthropogenic impact on the Arctic ecosystems, the research questions of forming surface and ground waters, their interactions with the rocks, development of the foundations for their rational use and protection are of great fundamental and practical importance. The aim of the work is to evaluate the influence of the chemical composition of rocks of the northern part of the Fennoscandian (Baltic) shield on forming surface waters chemical composition (Lake Inari, river Paz) using physical-chemical modeling (Chudnenko, 2010, Selector software package). River Paz (Paatsjoki) is the largest river in North Fennoscandia and flows through the territory of three countries - Finland, Russia and Norway. It originates from Lake Inari, which a large number of streams and rivers flow into, coming from the mountain range of the northern Finland (Maanselkä hill). Within the catchment of inflows feeding the lake Inari and river Paz in its upper flow there are mainly diverse early Precambrian metamorphic and intrusive rocks of the Lapland granulite belt and its framing, and to a lesser extent - various gneisses and migmatites with relicts of amphibolites, granitic gneisses, plagioclase and plagio- and plagiomicrocline granites, and quartz diorites of Inari terrane (Meriläinen, 1976, fig 1; Hörmann et al, 1980, fig 1; Geologicalmap, 2001). Basing on the techniques developed earlier (Mazukhina, 2012), and the data of monitoring of the chemical composition of surface waters and investigation of the chemical composition of the rocks, physical-chemical modeling (FCM) (Selector software package) was carried out. FCM includes 34 independent components (Al-B-Br-Ar-He-Ne-C-Ca-Cl-F-Fe-K-Mg-Mn-N-Na-P-S-Si-Sr-Cu-Zn-Ni-Pb-V-Ba-Co-Cr-Hg-As-Cd-H-O-e), 996 dependent components, of them 369 in aqueous solution, 76 in the gas phase, 111 liquid hydrocarbons, and 440 solid phases, organic and mineral

  10. Physical and chemical composition of swamp and water buffalo milk: a comparative study

    Directory of Open Access Journals (Sweden)

    M. S. R. Siddiki

    2010-02-01

    Full Text Available The research was carried out to compare the physical and chemical parameters of Swamp and Water buffalo milk collected from Senbari village in Trishal Upazila under Mymensingh district of Bangladesh. Results revealed that average color, flavor and taste score of Swamp and Water buffalo milk differed significantly (P0.05 with Water buffalo milk. Texture of all samples was normal. It was observed that average fat, total solids (TS, solids-not-fat (SNF and protein content differed significantly (P0.05 were found among, acidity, water. From these results, it may be inferred that the quality of Swamp buffalo milk is superior to that of Water buffalo milk.

  11. Effects of different water storage procedures on the dissolved Fe concentration and isotopic composition of chemically contrasted waters from the Amazon River Basin.

    Science.gov (United States)

    Mulholland, Daniel S; Poitrasson, Franck; Boaventura, Geraldo R

    2015-11-15

    Although recent studies have investigated the Fe isotopic composition of dissolved, colloidal and particulate phases from continental and oceanic natural waters, few efforts have been made to evaluate whether water sample storage and the separation of different pore-size fractions through filtration can cause any change to the Fe isotopic compositions. The present study investigates the possible biases introduced by different water storage conditions on the dissolved Fe concentration and isotopic composition of chemically different waters. Water samples were collected from an organic-rich river and from mineral particulate-rich rivers. Filtered and unfiltered water samples were stored either at room temperature or frozen at -18°C in order to assess possible biases due to (i) different water storage temperature, and (ii) storage of bulk (unfiltered) vs filtered water. Iron isotope measurements were performed by Multicollector Inductively Coupled Plasma Mass Spectrometry with a Thermo Electron Neptune instrument, after Fe purification using anion-exchange resins. Our data reveal that bulk water storage at room temperature without filtration produces minor changes in the dissolved Fe isotopic composition of mineral particulate-rich waters, but significant isotopic composition changes in organic-rich waters. In both cases, however, the impact of the different procedures on the Fe concentrations was strong. On the other hand, the bulk water stored frozen without filtration produced more limited changes in the dissolved Fe concentrations, and also on isotopic compositions, relative to the samples filtered in the field. The largest effect was again observed for the organic-rich waters. These findings suggest that a time lag between water collection and filtration may cause isotopic exchanges between the dissolved and particulate Fe fractions. When it is not possible to filter the samples in the field immediately after collection, the less detrimental approach is to

  12. Investigations of microphysical and chemical composition of aerosol in near-water layer of the atmosphere over the White Sea

    Science.gov (United States)

    Panchenko, Mikhail V.; Kozlov, Valerii S.; Pol'kin, Victor V.; Golobokova, Lyudmila P.; Pogodaeva, Tatyana V.; Khodzher, Tamara V.; Lisitzin, Alexander P.; Shevchenko, Vladimir P.

    2006-11-01

    The peculiarities of spatial-temporal variability of the submicron aerosol number density N Σ (cm -3), particle size distribution in the diameter range 0.4 to 10 μm, mass concentration of submicron aerosol Ma (μg/m 3) and the mass concentration of black carbon (soot, BC) Ms (μg/m 3), as well as chemical composition of particles (ion composition of aerosol soluble fraction) in different regions of White Sea are considered in this paper. The effect of continental and marine sources on formation of the near-water aerosol characteristics is estimated.

  13. Study of Water Binding Capacity, pH, Chemical Composition and Microstructure of Livestock Meat and Poultry

    OpenAIRE

    Eleonora Okuskhanova; Maksim Rebezov; Zhanibek Yessimbekov; Anuarbek Suychinov; Natalya Semenova; Yaroslav Rebezov; Olga Gorelik; Oksana Zinina

    2017-01-01

    This paper shows the results of analysis of chemical composition, water binding capacity, pH and microstructure of maral meat, goat meat, lamb, and turkey meat. From the analysis, the high content of protein and ash is observed in turkey meat, fat prevails in lamb, and less amount in maral meat and goat meat. pH value lies between 5.7 (turkey white meat) and 6.4 (goat meat). Low value of water binding capacity is detected in turkey meat (58.2% in red meat, 59.2% in white meat) and high value ...

  14. Chemical Composition of Sea Fog Water Along the South China Sea

    Science.gov (United States)

    Yue, Yanyu; Niu, Shengjie; Zhao, Lijuan; Zhang, Yu; Xu, Feng

    2012-12-01

    The chemical and microphysical properties of sea fog were measured during a field experiment on Donghai Island, Zhanjiang of China from March 15 to April 18, 2010. The average pH and electrical conductivity (EC) value of the six sea fog cases during the experiment was 5.2 and 1,884 μS/cm. The observed total ion concentration of sea fog was four orders of magnitude higher than those in the North Pacific and other sea areas of China. The dominant anion and cation in all sea fog water samples were Cl- and Na+, respectively. From backward trajectory analysis and ion loading computation, it can be concluded that the ions in the samples were transported either from pollutants in distant industrial cities or from local ion deposition processes. The concentration of Ca2+ in the sea fog water samples in Case 2 suggested that a dust storm in the Inner Mongolia, a northern region of China several thousand kilometers away, could reach the South China Sea. The data also showed that the sea fog droplet spectrum over the South China Sea is unimodal. Through relationship analysis, it is illustrated that the evolution of microphysics (such as droplet concentration, diameter, and liquid water content) during fog process could affect the chemical properties of sea fog.

  15. Chemical and isotopic compositions of minerals and waters from the Campi Flegrei volcanic system, Naples, Italy

    Science.gov (United States)

    Valentino, G. M.; Cortecci, G.; Franco, E.; Stanzione, D.

    1999-08-01

    Based on their δ 34S signature, sulfate minerals and native sulfur around fumaroles and hot water pools from the Campi Flegrei volcanic area derive from supergenic oxidation of volcanic H 2S. Their mean δ 34S value (-0.2±1.7‰) matches with that of fumarolic H 2S at Solfatara (-0.3±0.3‰), as well as with the δ 34S of +1.4‰ obtained for total sulfur in fresh trachyte from the area. All δ 34S values indicate a mostly deep-seated origin for sulfur. Thermal waters were analysed for major and minor chemistry and for oxygen, hydrogen and sulfur isotope compositions. Pools at Pisciarelli are filled with evaporated meteoric water heated by rising (magmatic) gases. The water δ 18O (+3.8±1.3‰) and δ 2H (+6.5±2.2‰) values in these steam-heated waters are controlled by mixing and evaporation effects, and the δ 34S value of dissolved sulfate (-1.3±0.3‰) basically agrees with supergenic oxidation of deep-seated H 2S as the major source of sulfur. Instead, water from thermal springs and wells elsewhere in the Campi Flegrei appears to be a mixture between dilute meteoric and saline marine components. The latter may be local seawater from the bay of Pozzuoli. The δ 18O and δ 2H values of waters sampled during 1993-1994 range from -5.6 to +0.3‰ and from -33 to -3.4‰, respectively. The δ 34S values of dissolved sulfate range between -0.1 and +19.5‰. In general, sulfate is probably derived essentially from two sources, both within the volcanic cover, i.e., oxidation/dissolution of pyrite and anhydrite, and marine water. An occasional source of water and sulfate is represented by (magmatic) gases, which directly interact with shallow meteoric water as in the case of the Hotel Tennis well yielding steam-heated water with δ 18O=-1.5±0.2‰, δ 2H=-17±1‰ and δ 34S=-0.1‰.

  16. Water/Rock Interactions and Changes in Chemical Composition During Zeolite Mineralization

    Institute of Scientific and Technical Information of China (English)

    张寿庭; 赵鹏大; 徐旃章; 郑明华

    2001-01-01

    Systematic analysis and comparative study of the chemical compositions of rocks and ores from the main types of zeolite deposits in the surroundings of the Songliao Basin have shown that the process of formation of zeolite from volcanic and pyroclastic rocks is generally characterized by the relative purification of SiO2, i.e., SiO2/A12O3 ratios tend to increase, al kali earth elements (CaO + MgO) and H2O are relatively enriched, and the alkali metals (K2O + Na2O) are depleted in their total amount. The alkali metals K and Na follow different rules of migration and enrichment during the formation of mordenite and clinoptilolite. In the pro cess of formation of mordenite more Na+ will be imported and K+ will be lost remarkably. On the contrary, in the process of formation clinoptilolite more K+ will be incorporated and Na+will become obviously depleted.

  17. Graphene composites containing chemically bonded metal oxides

    Indian Academy of Sciences (India)

    K Pramoda; S Suresh; H S S Ramakrishna Matte; A Govindaraj

    2013-08-01

    Composites of graphene involving chemically bonded nano films of metal oxides have been prepared by reacting graphene containing surface oxygen functionalities with metal halide vapours followed by exposure to water vapour. The composites have been characterized by electron microscopy, atomic force microscopy and other techniques. Magnetite particles chemically bonded to graphene dispersible in various solvents have been prepared and they exhibit fairly high magnetization.

  18. Intracellular water exchange for measuring the dry mass, water mass and changes in chemical composition of living cells.

    Directory of Open Access Journals (Sweden)

    Francisco Feijó Delgado

    Full Text Available We present a method for direct non-optical quantification of dry mass, dry density and water mass of single living cells in suspension. Dry mass and dry density are obtained simultaneously by measuring a cell's buoyant mass sequentially in an H2O-based fluid and a D2O-based fluid. Rapid exchange of intracellular H2O for D2O renders the cell's water content neutrally buoyant in both measurements, and thus the paired measurements yield the mass and density of the cell's dry material alone. Utilizing this same property of rapid water exchange, we also demonstrate the quantification of intracellular water mass. In a population of E. coli, we paired these measurements to estimate the percent dry weight by mass and volume. We then focused on cellular dry density - the average density of all cellular biomolecules, weighted by their relative abundances. Given that densities vary across biomolecule types (RNA, DNA, protein, we investigated whether we could detect changes in biomolecular composition in bacteria, fungi, and mammalian cells. In E. coli, and S. cerevisiae, dry density increases from stationary to exponential phase, consistent with previously known increases in the RNA/protein ratio from up-regulated ribosome production. For mammalian cells, changes in growth conditions cause substantial shifts in dry density, suggesting concurrent changes in the protein, nucleic acid and lipid content of the cell.

  19. The influence of water management and environmental conditions on the chemical composition and beverage quality of coffee beans

    OpenAIRE

    Silva,Emerson A da; MAZZAFERA, Paulo; Brunini,Orivaldo; Sakai,Emílio; Flávio B. Arruda; Mattoso,Luiz Henrique C.; Carvalho, Cássia R. L.; Pires, Regina Célia M.

    2005-01-01

    The influence of environmental conditions and irrigation on the chemical composition of green coffee beans and the relationship of these parameters to the quality of the beverage were investigated in coffee plantations in the regions of Adamantina, Mococa and Campinas, in the state of São Paulo, Brazil. The chemical composition and physical aspects of green coffee beans produced in the three regions were related through Principal Component Analyses (PCA) to the quality of beverage, as determi...

  20. Chemical Composition, in vitro Digestibility and Fermentative Gas Production of Kochia scoparia Irrigated by Water Containing Different Level of Salinity

    Directory of Open Access Journals (Sweden)

    reza valizadeh

    2016-11-01

    Full Text Available Introduction Shortage of feedstuff is one of the important problems of animal nutrition in Iran. Salinity is a global problem worldwide in particular in arid and semi-arid zones such as Iran. Salinity is an important factor in the growth of plants. Its initial effect to plants is through its effect in the availability of water to plants. Halophytes have good ability to draw water from soils of low water potential due to their ability to maintain a salt balance comparable to the salt in the soil they are growing. Lands in high irrigation districts are susceptible to soil salinization. Soil salinization is the primary cause of productivity decline in highly developed and irrigated land schemes While the increase in soil and water salinity in many agricultural areas of the world has created major challenges in the production of food crops, it has also presented some new prospects for livestock agriculture. There are plants that grow under saline conditions, and historically, they have been opportunistically used as fodder for grazing livestock or as components of mixed rations to replace roughage. Using of seawater for irrigation of this plant because of shortage of sweet water and for higher production of these plants was necessary for feedstuff. The aim of this study was evaluation of Chemical composition, In vitro digestibility and gas production of Kochia scoparia under six level of salinity including 10, 20, 30, 40, 50, 60 ds/m. Materials and Methods The Kochia scoparia was irrigated by normal tap water (the control and water containing 6 levels of salinity including 10, 20, 30, 40, 50, 60 deci Siemens per meter (ds/m. The salinity was applied gradually in accordance with the plant growth advancement (2 ds/m increment per each irrigation period. Oven dried (65◦C for 48 h chopped samples were ground to pass through a 1-mm screen. The samples were analyzed according to the standard procedures for chemical composition (AOAC 2000, Van-Soest et

  1. Chemical composition and geologic history of saline waters in Aux Vases and Cypress Formations, Illinois Basin

    Science.gov (United States)

    Demir, I.; Seyler, B.

    1999-01-01

    Seventy-six samples of formation waters were collected from oil wells producing from the Aux Vases or Cypress Formations in the Illinois Basin. Forty core samples of the reservoir rocks were also collected from the two formations. Analyses of the samples indicated that the total dissolved solids content (TDS) of the waters ranged from 43,300 to 151,400 mg/L, far exceeding the 35,400 mg/mL of TDS found in typical seawater. Cl-Br relations suggested that high salinities in the Aux Vases and Cypress formation waters resulted from the evaporation of original seawater and subsequent mixing of the evaporated seawater with concentrated halite solutions. Mixing with the halite solutions increased Na and Cl concentrations and diluted the concentration of other ions in the formation waters. The elemental concentrations were influenced further by diagenetic reactions with silicate and carbonate minerals. Diagenetic signatures revealed by fluid chemistry and rock mineralogy delineated the water-rock interactions that took place in the Aux Vases and Cypress sandstones. Dissolution of K-feldspar released K into the solution, leading to the formation of authigenic illite and mixed-layered illite/smectite. Some Mg was removed from the solution by the formation of authigenic chlorite and dolomite. Dolomitization, calcite recrystallization, and contribution from clay minerals raised Sr levels significantly in the formation waters. The trend of increasing TDS of the saline formation waters with depth can be explained with density stratification. But, it is difficult to explain the combination of the increasing TDS and increasing Ca/Na ratio with depth without invoking the controversial 'ion filtration' mechanism.

  2. The influences of macro- and microphysical characteristics of sea-fog on fog-water chemical composition

    Science.gov (United States)

    Yue, Yanyu; Niu, Shengjie; Zhao, Lijuan; Zhang, Yu; Xu, Feng

    2014-05-01

    During a sea-fog field observation campaign on Donghai Island in the spring of 2011, fog-water, visibility, meteorological elements, and fog droplet spectra were measured. The main cations and anions in 191 fog-water samples were Na+, NH{4/+}, H+, NO{3/-}, Cl- and SO{4/2-}, and the average concentrations of cations and anions were 2630 and 2970 μeq L-1, respectively. The concentrations of Na+ and Cl- originated from the ocean were high. The enhancement of anthropogenic pollution might have contributed to the high concentration of NH{4/+}, H+, and NO{3/-}. The average values of pH and electrical conductivity (EC) were 3.34 and 505 μS cm-1, respectively, with a negative correlation between them. Cold fronts associated with cyclonic circulations promoted the decline of ion loadings. Air masses from coastal areas had the highest ion loadings, contrary to those from the sea. The ranges of wind speed, wind direction and temperature corresponding to the maximum total ion concentration (TIC) were 3.5-4 m s-1, 79°-90° and 21°C-22°C, respectively. In view of the low correlation coefficients, a new parameter Lr was proposed as a predictive parameter for TIC and the correlation coefficient increased to 0.74. Based on aerosol concentrations during the sea-fog cases in 2010, we confirmed that fog-water chemical composition also depended on the species and sizes of aerosol particles. When a dust storm passed through Donghai Island, the number concentration of large aerosol particles (with diameter > 1 μm) increased. This caused the ratio of Ca2+/Na+ in fog-water to increase significantly.

  3. Comparing molecular composition of dissolved organic matter in soil and stream water: Influence of land use and chemical characteristics.

    Science.gov (United States)

    Seifert, Anne-Gret; Roth, Vanessa-Nina; Dittmar, Thorsten; Gleixner, Gerd; Breuer, Lutz; Houska, Tobias; Marxsen, Jürgen

    2016-11-15

    Electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI-FT-ICR-MS) was used to examine the molecular composition of dissolved organic matter (DOM) from soils under different land use regimes and how the DOM composition in the catchment is reflected in adjacent streams. The study was carried out in a small area of the Schwingbach catchment, an anthropogenic-influenced landscape in central Germany. We investigated 30 different soil water samples from 4 sites and different depths (managed meadow (0-5cm, 40-50cm), deciduous forest (0-5cm), mixed-coniferous forest (0-5cm) and agricultural land (0-5cm, 40-50cm)) and 8 stream samples. 6194 molecular formulae and their magnitude-weighted parameters ((O/C)w, (H/C)w, (N/C)w, (AI-mod)w, (DBE/C)w, (DBE/O)w, (DBE-O)w, (C#)w, (MW)w) were used to describe the molecular composition of the samples. The samples can be roughly divided in three groups. Group 1 contains samples from managed meadow 40-50cm and stream water, which are characterized by high saturation compared to samples from group 2 including agricultural samples and samples from the surface meadow (0-5cm), which held more nitrogen containing and aromatic compounds. Samples from both forested sites (group 3) are characterized by higher molecular weight and O/C ratio. Environmental parameters vary between sites and among these parameters pH and nitrate significantly affect chemical composition of DOM. Results indicate that most DOM in streams is of terrestrial origin. However, 120 molecular formulae were detected only in streams and not in any of the soil samples. These compounds share molecular formulae with peptides, unsaturated aliphatics and saturated FA-CHO/FA-CHOX. Compounds only found in soil samples are much more aromatic, have more double bonds and a much lower H/C ratio but higher oxygen content, which indicates the availability of fresh plant material and less microbial processed material compared to stream samples. Copyright

  4. Chemical composition, properties, and antimicrobial activity of the water-soluble pigments from Castanea mollissima shells.

    Science.gov (United States)

    You, Ting-Ting; Zhou, Su-Kun; Wen, Jia-Long; Ma, Chao; Xu, Feng

    2014-02-26

    Agricultural residues Castanea mollissima shells represent a promising resource for natural pigments for the food industry. This study provides a comprehensive and systematic evaluation of water-soluble pigments (CSP) from C. mollissima shells, which were obtained by 50% ethanol with microwave-assisted extraction. Spectroscopic techniques (UV, FT-IR, (13)C NMR), elemental analysis, and chromatographic techniques (HPAEC, GPC) revealed that the main components in the CSP were flavonoids procyanidin B3 (condensed tannin), quercetin-3-O-glycoside, and steroidal sapogenins. As a consequence, CSP was water-soluble and presented significant DPPH scavenge capacity (EC50 value was 0.057 mg/mL). Specially, CSP gave excellent antibacterial activity, and even better than 5% aqueous phenol in some case. Moreover, CSP was practically nontoxic and exhibited good stability with temperature, natural light, and metal ions. These outstanding properties will enlarge the application of CSP for natural food additives production.

  5. Chemical composition of interstellar dust

    Science.gov (United States)

    Das, Ankan; Chakrabarti, Sandip Kumar; Majumdar, Liton; Sahu, Dipen

    Study of chemical evolution of interstellar medium is well recognized to be a challenging task. Interstellar medium (ISM) is a rich reservoir of complex molecules. So far, around 180 gas phase molecules and around 20 molecular species on the interstellar dust have been detected in various regions of ISM, especially in regions of star formation. In last decade, it was well established that gas phase reactions alone cannot explain molecular abundances in ISM. Chemical reactions which occur on interstellar dust grains are essential to explain formation of several molecules especially hydrogenated species including simplest and most abundant molecule H2. Interstellar grains provide surface for accreted species to meet and react. Therefore, an understanding of formation of molecules on grain surfaces is of prime importance. We concentrate mainly on water, methanol, carbon dioxide, which constitute nearly 90% of the grain mantle. These molecules are detected on grain surface due to their strong absorption bands arising out of multiple vibrational modes. Water is the most abundant species (with a surface coverage >60% ) on a grain in dense interstellar medium. CO2 is second most abundant molecule in interstellar medium with an abundance of around 20% with respect to H2O. However, this can vary from cloud to cloud. In clouds like W 33A it could be even less than 5% of water abundance. The next most abundant molecule is CO, which is well studied ice with an abundance varying between 2%\\ to 15% of water. Methanol (CH3OH) is also very abundant having abundance 2% to 30% of water. Measurement of water deuterium fractionation is a relevant tool for understanding mechanisms of water formation and evolution from prestellar phase to formation of planets and comets. We are also considering deuterated species in our simulation. We use Monte Carlo method (considering multilayer regime) to mimic the exact scenario. We study chemical evolution of interstellar grain mantle by varying

  6. [The sanitary status of natural waters on the territory of Moscow (according to the results of the examination of chemical and radionuclide composition)].

    Science.gov (United States)

    Klimenko, I A; Poliakov, V A; Sokolovskiĭ, L G; Aksenova, O I; Skvortsova, O Iu; Okhrimenko, S E

    2003-01-01

    The paper presents the results of examination of the chemical and radionuclide composition of natural waters and snow cover in Moscow. Areas with abnormal contents of tritium are found in the underground and surface waters and snow cover. The high concentrations of strontium, boron, fluorine, and barium are ascertained to be associated with natural factors. Areas of technogenically polluted underground waters are identified. Recommendations are given for further studies. Particular emphasis is laid on that the artesian wells that are a reservoir source of water supply under emergency are to be revised.

  7. Methods used to characterize the chemical composition and biological activity of environmental waters throughout the United States, 2012-14

    Science.gov (United States)

    Romanok, Kristin M.; Reilly, Timothy J.; Barber, Larry B.; Boone, J. Scott; Buxton, Herbert T.; Foreman, William T.; Furlong, Edward T.; Hladik, Michelle; Iwanowicz, Luke R.; Journey, Celeste; Kolpin, Dana W.; Kuivila, Kathryn; Loftin, Keith A.; Mills, Marc A.; Meyer, Michael T.; Orlando, James L.; Smalling, Kelly L.; Villeneuve, Daniel L.; Bradley, Paul M.

    2017-03-22

    A vast array of chemical compounds are in wide commercial use in the United States, and the potential ecological and human-health effect of exposure to chemical mixtures has been identified as a high priority in environment health science. Awareness of the potential effects of low-level chemical exposures is rising. The U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency, conducted a study in which samples were collected from 38 streams in 25 States to provide an overview of contaminants found in stream water across the Nation. Additionally, biological screening assays were used to help determine any potential ecological and human-health effects of these chemical mixtures and to prioritize target chemicals for future toxicological studies. This report describes the site locations and the sampling and analytical methods and quality-assurance procedures used in the study.

  8. Method of forming a chemical composition

    Science.gov (United States)

    Bingham, Dennis N.; Wilding, Bruce M.; Klingler, Kerry M.; Zollinger, William T.; Wendt, Kraig M.

    2007-10-09

    A method of forming a chemical composition such as a chemical hydride is described and which includes the steps of selecting a composition having chemical bonds and which is capable of forming a chemical hydride; providing a source of hydrogen; and exposing the selected composition to an amount of ionizing radiation to encourage the changing of the chemical bonds of the selected composition, and chemically reacting the selected composition with the source of hydrogen to facilitate the formation of a chemical hydride.

  9. Chemical and Isotopic Composition of Waters and Dissolved Gases in Some Thermal Springs of Sicily and Adjacent Volcanic Islands, Italy

    Science.gov (United States)

    Grassa, Fausto; Capasso, Giorgio; Favara, Rocco; Inguaggiato, Salvatore

    2006-04-01

    Hydrochemical (major and some minor constituents), stable isotope ([InlineMediaObject not available: see fulltext.] and [InlineMediaObject not available: see fulltext.], δ13CTDIC total dissolved inorganic carbon) and dissolved gas composition have been determined on 33 thermal discharges located throughout Sicily (Italy) and its adjacent islands. On the basis of major ion contents, four main water types have been distinguished: (1) a Na-Cl type; (2) a Ca-Mg > Na-SO4-Cl type; (3) a Ca-Mg-HCO3 type and (4) a Na-HCO3 type water. Most waters are meteoric in origin or resulting from mixing between meteoric water and heavy-isotope end members. In some samples, δ 18O values reflect the effects of equilibrium processes between thermal waters and rocks (positive 18O-shift) or thermal waters and CO2 (negative 18O-shift). Dissolved gas composition indicates the occurrence of gas/water interaction processes in thermal aquifers. N2/O2 ratios higher than air-saturated water (ASW), suggest the presence of geochemical processes responsible for dissolved oxygen consumption. High CO2 contents (more than 3000 cc/litre STP) dissolved in the thermal waters indicate the presence of an external source of carbon dioxide-rich gas. TDIC content and δ 13C TDIC show very large ranges from 4.6 to 145.3 mmol/Kg and from 10.0‰ and 2.8‰, respectively. Calculated values indicate the significant contribution from a deep source of carbon dioxide inorganic in origin. Interaction with Mediterranean magmatic CO2 characterized by heavier carbon isotope ratios ([InlineMediaObject not available: see fulltext.] value from -3 to 0‰ vs V-PDB (CAPASSO et al., 1997, GIAMMANCO et al., 1998; INGUAGGIATO et al., 2000) with respect to MORB value and/or input of CO2-derived from thermal decomposition of marine carbonates have been inferred.

  10. Water-soluble main ions in precipitation over the southeastern Adriatic region: chemical composition and long-range transport.

    Science.gov (United States)

    Dorđević, Dragana S; Tosić, Ivana; Unkasević, Miroslava; Durasković, Pavle

    2010-11-01

    (+), Cl(-), Mg(2+)) are significantly correlated, except for air masses originating from the northern and eastern European regions. Significant correlations between SO(4)(2-) and NO(3)(-) are found in air masses coming from the western Europe and North Africa, over the Mediterranean. The highest volume-weighted mean (VWM) of: SO(4)(2-), NH(4)(+) and Mg(2+) are for precipitation from EE-NE while the highest values of VWM of Cl(-) are from WM and of K(+) are from WE-CE. Long-range transport of Sahara dust is confirmed. For better estimation of origins of water-soluble ions in precipitation expanding list of analysis on anions of organic acids, such as HCOO(-), CH(3)COO(-), and C(2)H(2)COO(-), could be indicative of volatile organic compounds emitted by vegetation but also traffic. The chemical composition of precipitation together with a study of air backward trajectories is the proper tool for tracking the long-range transport of water-soluble ions and estimating transboundary pollution.

  11. The Chemical Composition of Honey

    Science.gov (United States)

    Ball, David W.

    2007-01-01

    Honey is a supersaturated sugar solution, created by bees, and used by human beings as a sweetener. However, honey is more than just a supersaturated sugar solution; it also contains acids, minerals, vitamins, and amino acids in varying quantities. In this article, we will briefly explore the chemical composition of honey. (Contains 2 figures and…

  12. Chemical recycling of scrap composites

    Science.gov (United States)

    Allred, Ronald E.; Salas, Richard M.

    1994-01-01

    There are no well-developed technologies for recycling composite materials other than grinding to produce fillers. New approaches are needed to reclaim these valuable resources. Chemical or tertiary recycling, conversion of polymers into low molecular weight hydrocarbons for reuse as chemicals or fuels, is emerging as the most practical means for obtaining value from waste plastics and composites. Adherent Technologies is exploring a low-temperature catalytic process for recycling plastics and composites. Laboratory results show that all types of plastics, thermosets as well as thermoplastics, can be converted in high yields to valuable hydrocarbon products. This novel catalytic process runs at 200 C, conversion times are rapid, the process is closed and, thus, nonpolluting, and no highly toxic gas or liquid products have been observed so no negative environmental impact will result from its implementation. Tests on reclamation of composite materials show that epoxy, imide, and engineering thermoplastic matrices can be converted to low molecular weight hydrocarbons leaving behind the reinforcing fibers for reuse as composite reinforcements in secondary, lower-performance applications. Chemical recycling is also a means to dispose of sensitive or classified organic materials without incineration and provides a means to eliminate or reduce mixed hazardous wastes containing organic materials.

  13. Relationship between the inorganic chemical composition of water, precipitation and evaporation in the basin of Rio Grande, Chone, Ecuador

    Directory of Open Access Journals (Sweden)

    David Carrera

    2015-03-01

    Full Text Available (Received: 2015/01/19 - Accepted: 2015/03/25In the Rio Grande basin, the Chone Multi-Purpose dam (PMCH is built with an investment of approximately $66 million, to irrigate over 7000ha. The marked differences in precipitation could impair the quality of water; therefore the aim of this study was to establish the relationship between the ions and their location in the graph: relationship of ions and mechanisms of chemical processes, water behavior and trend setting. The study was a non-experimental, cross-sectional and descriptive research. 111 samples were collected in the group of channels that form the Rio Grande basin, in 2013 and 2014 during times of drought and rain. The parameters were measured in the sample anions and cations. The processes that control the chemistry of surface water in the studied area during the rainy season have a predisposition to mineralization in equilibrium with rocks. However, in the time of drought, water movement was observed towards the area where evaporation with respect to precipitation predominates, increasing the inorganic chemistry of the waters that, in time, could be extended.

  14. Effect of water treatment additives on lime softening residual trace chemical composition--implications for disposal and reuse.

    Science.gov (United States)

    Cheng, Weizhi; Roessler, Justin; Blaisi, Nawaf I; Townsend, Timothy G

    2014-12-01

    Drinking water treatment residues (WTR) offer potential benefits when recycled through land application. The current guidance in Florida, US allows for unrestricted land application of lime softening WTR; alum and ferric WTR require additional evaluation of total and leachable concentrations of select trace metals prior to land application. In some cases a mixed WTR is produced when lime softening is accompanied by the addition of a coagulant or other treatment chemical; applicability of the current guidance is unclear. The objective of this research was to characterize the total and leachable chemical content of WTR from Florida facilities that utilize multiple treatment chemicals. Lime and mixed lime WTR samples were collected from 18 water treatment facilities in Florida. Total and leachable concentrations of the WTR were measured. To assess the potential for disposal of mixed WTR as clean fill below the water table, leaching tests were conducted at multiple liquid to solid ratios and under reducing conditions. The results were compared to risk-based soil and groundwater contamination thresholds. Total metal concentrations of WTR were found to be below Florida soil contaminant thresholds with Fe found in the highest abundance at a concentration of 3600 mg/kg-dry. Aluminum was the only element that exceeded the Florida groundwater contaminant thresholds using SPLP (95% UCL = 0.23 mg/L; risk threshold = 0.2 mg/L). Tests under reducing conditions showed elevated concentrations of Fe and Mn, ranging from 1 to 3 orders of magnitude higher than SPLP leachates. Mixed lime WTR concentrations (total and leachable) were lower than the ferric and alum WTR concentrations, supporting that mixed WTR are appropriately represented as lime WTR. Testing of WTR under reducing conditions demonstrated the potential for release of certain trace metals (Fe, Al, Mn) above applicable regulatory thresholds; additional evaluation is needed to assess management options where

  15. Chemical composition of drinking water as a possible environment-specific factor modifying the thyroid risk in the areas subjected to radioiodine contamination

    Science.gov (United States)

    Kolmykova, Lyudmila; Korobova, Elena; Ryzhenko, Boris

    2015-04-01

    Water is one of the main natural agents providing chemical elements' migration in the environment and food chains. In our opinion a study of spatial variation of the essential trace elements in local drinking water is worth considering as the factor that may contribute to variation of the health risk in areas contaminated by radionuclides and radioiodine in particular. Radioiodine was proved to increase the risk of thyroid cancer among children who lived in areas contaminated during the Chernobyl accident. It was also shown that low stable iodine status of the contaminated area and population also contributed to the risk of this disease in case of radionuclide contamination. The goal of the study was to investigate chemical composition of the drinking water in rural settlements of the Bryansk oblast' subjected to radioiodine contamination and to evaluate speciation of stable I and Se on the basis of their total concentration and chemical composition of the real water samples with the help of thermodynamic modelling. Water samples were collected from different aquifers discharging at different depths (dug wells, local private bore holes and water pipes) in rural settlements located in areas with contrasting soil iodine status. Thermodynamic modelling was performed using original software (HCh code of Y.Shvarov, Moscow State University, RUSSIA) incorporating the measured pH, Corg and elements' concentration values. Performed modelling showed possibility of formation of complex CaI+ ion in aqueous phase, I sorption by goethite and transfer of Se to solid phase as FeSe in the observed pH-Eh conditions. It helped to identify environmental conditions providing high I and Se mobility and their depletion from natural waters. Both the experimental data and modeling showed that I and Se migration and deficiency in natural water is closely connected to pH, Eh conditions and the concentration of typomorphic chemical elements (Ca, Mg, Fe) defining the class of water migration

  16. Chemical and isotopic composition of the Monfortinho thermal water (Portugal): contribution to the aquifer conceptual model and resource evaluation

    Science.gov (United States)

    do Rosário Carvalho, Maria; Martins Carvalho, José

    2015-04-01

    Groundwaters from quartzite aquifers are usually cold waters with very low mineralization as consequence of circulation in fractured aquifers and rocks with very low solubility. In the Monfortinho, Beira Baixa region in Portugal, a thermal water occurs associated to a Ordovician quartzite syncline, the Penha Garcia syncline (Sequeira et al., 1999). The thermal water is used for balneology and supplies a thermal Spa trough boreholes discharging about 36 l/s. The syncline of Penha Garcia has NW-SE axis and is fractured by a NE-SW fault, where the valley of Ponsul river is developed. The natural discharge of the thermal aquifer occur at the SE edge of the syncline. The Monfortinho thermal water has temperature around 30 °C, pH of 5.45, very low mineralization, with electric conductivity about 35 uS/cm; the main dissolved specie is the SiO2 that reaches 24 mg/L, corresponding to 53% of the total dissolved solids. The chemical facies is of Na-HCO3 type. The d18O and d2H diagram indicates that Monfortinho water is derived from the local meteoric waters. The δ18O and δ2H content also pointed out a recharge area of the thermal aquifer above 400 m of elevation, with a isotopic gradient value of -0.15‰ d18O/100m. This elevation corresponds to the top of the eastern block of the syncline, suggesting that Ponsul fault is a negative barrier to groundwater flow and the thermal aquifer is developed only in eastern block of the syncline. The groundwater flows at about 600-700 m depth along the syncline base toward SE. The average rainfall in the region is 790 mm/year and the estimated recharge is about 17% (Carvalho, 2001) of the precipitation, corresponding to 134 mm/year and 4x105 m3/ano of hydrothermal resource. References: Carvalho, JM (2001). A Hidrogeologia das águas minerais naturais de Monfortinho. Geonovas, Rev. Assoc. Portg. Geólogos, Lisboa, v15, pp. 61-70 (in portuguese). Sequeira, AF, Cunha, PP, Ribeiro, ML (1999). Notícia Explicativa da Folha 25-B Salvaterra

  17. Metagenomic Insights into Effects of Chemical Pollutants on Microbial Community Composition and Function in Estuarine Sediments Receiving Polluted River Water.

    Science.gov (United States)

    Lu, Xiao-Ming; Chen, Chang; Zheng, Tian-Ling

    2016-10-15

    Pyrosequencing and metagenomic profiling were used to assess the phylogenetic and functional characteristics of microbial communities residing in sediments collected from the estuaries of Rivers Oujiang (OS) and Jiaojiang (JS) in the western region of the East China Sea. Another sediment sample was obtained from near the shore far from estuaries, used for contrast (CS). Characterization of estuary sediment bacterial communities showed that toxic chemicals potentially reduced the natural variability in microbial communities, while they increased the microbial metabolic enzymes and pathways. Polycyclic aromatic hydrocarbons (PAHs) and nitrobenzene were negatively correlated with the bacterial community variation. The dominant class in the sediments was Gammaproteobacteria. According to Kyoto Encyclopedia of Genes and Genomes (KEGG) enzyme profiles, dominant enzymes were found in estuarine sediments, which increased greatly, such as 2-oxoglutarate synthase, acetolactate synthase, inorganic diphosphatase, and aconitate hydratase. In KEGG pathway profiles, most of the pathways were also dominated by specific metabolism in these sediments and showed a marked increase, for instance alanine, aspartate, and glutamate metabolism, carbon fixation pathways in prokaryotes, and aminoacyl-tRNA biosynthesis. The estuarine sediment bacterial diversity varied with the polluted river water inputs. In the estuary receiving river water from the more seriously polluted River Oujiang, the sediment bacterial community function was more severely affected.

  18. Review of Knowledge on the Occurrence, Chemical Composition, and Potential Use for Desalination of Saline Ground Water in Arizona, New Mexico, and Texas with a Discussion of Potential Future Study Needs

    Science.gov (United States)

    Huff, G.F.

    2004-01-01

    Increasing demand on the limited supplies of freshwater in the desert Southwest, as well as other parts of the United States, has increased the level of interest in saline-water resources. Saline ground water has long been recognized as a potentially important contributor to water supply in the Southwest, as demonstrated by the number of hydrologic, geologic, and engineering studies on the distribution of saline water and the feasibility of desalination. Potential future study needs include investigating and documenting the three-dimensional distribution of salinity and chemical composition of saline-water resources and the hydraulic properties of aquifers containing these saline-water resources, assessing the chemical suitability of saline water for use with existing and anticipated desalination technologies, simulating the effect of withdrawal of saline ground water on water levels and water composition in saline and adjoining or overlying freshwater aquifers, and determining the suitability of target geologic formations for injection of desalination-generated waste.

  19. Assessment of morphology, topography and chemical composition of water-repellent films based on polystyrene/titanium dioxide nanocomposites

    Science.gov (United States)

    Bolvardi, Beleta; Seyfi, Javad; Hejazi, Iman; Otadi, Maryam; Khonakdar, Hossein Ali; Drechsler, Astrid; Holzschuh, Matthias

    2017-02-01

    In this study, polystyrene (PS)/titanium dioxide (TiO2) films were fabricated through simple solution casting technique via a modified phase separation process. The presented approach resulted in a remarkable reduction in the required amount of nanoparticles for achieving superhydrophobicity. Scanning electron microscopy (SEM) and 3D confocal microscopy were utilized to characterize surface morphology and topography of samples, respectively. An attempt was made to give an in-depth analysis on the surface rough structure using 3D roughness profiles. It was found that high inclusions of non-solvent and nanoparticles resulted in a stable self-cleaning behavior due to the strong presence of hydrophobic TiO2 nanoparticles on the surface. Quite unexpectedly, low inclusions of nanoparticles and non-solvent also resulted in superhydrophobic property mainly due to the proper level of induced surface roughness. XPS analysis was also utilized to determine the chemical composition of the films' surfaces. The results of falling drop experiments showed that the sample containing a higher level of nanoparticles had a much lower mechanical resistance against the induced harsh conditions. All in all, the presented method has shown promising potential in fabrication of superhydrophobic surfaces with self-cleaning behavior using the lowest content of nanoparticles.

  20. Chemical composition, antioxidant potential and phenolic profile of oil mill waste water from Tunisian olive varieties (Chetoui and Chemlali

    Directory of Open Access Journals (Sweden)

    Maissa Khemakhem Sellami

    2016-07-01

    Full Text Available Oil mill waste water (OMWW is of great interest due to the presence of valuable resources such as biophenols that can be recovered as food additives and pharmaceuticals. The aim of this study is to investigate the variation of physicochemical composition of OMWW from Chetoui and Chemlali varieties, to evaluate phenolic composition, antioxidant potential and phenolic profile of OMWW extracts under native and acidified conditions. Liquid-liquid extraction was performed for the extraction of polyphenols. Antioxidant activity was investigated by DPPH•, ABTS•+ and FRAP tests. Phenolic compounds content was determined by HPLC-DAD method. OMWW from Chetoui variety has been shown to contain an important amount of K, Ca and Na whereas Chemlali cultivar was rich in Mg. Phenolic extract from Chetoui fruit (COCt has been  shown to contain the highest amount of polyphenols (2.48 ± 0.21 g L-1 as well as an appreciable content of flavonoids (9.39 ± 0.32 g L-1. However, phenolic extract from Chemlali fruit (COCm has been shown to have the highest content of proanthocyanidins (0.39 ± 0.00 g L-1. Acidification treatment improved polyphenol recovery of extracts from both varieties. COCt was more active using DPPH (EC50 of 7.5 mg L-1 and FRAP tests. However, COCt and COCm exhibited the same activity using ABTS test. In general, acidification treatment decreased antioxidant activity of extracts. COCt has been shown to contain higher amount of hydroxytyrosol when compared to COCm (157.16 ± 0.820 and 23.440 ± 0.440 mg g-1 D.W. of extract, respectively as revealed by HPLC-DAD analysis. 

  1. Influence of Chemical Composition on Microbial Communities in Deep Water Plumes After the Deepwater Horizon Oil Spill

    Science.gov (United States)

    Redmond, M. C.; Valentine, D. L.

    2012-12-01

    After the Deepwater Horizon oil spill, large amounts of natural gas and oil remained dissolved or suspended in the deep Gulf of Mexico. These deep water plumes were preferentially enriched in soluble hydrocarbons, including methane, ethane, propane, cyclohexane, benzene, toluene, and xylenes. Microbial communities responded rapidly to the influx of hydrocarbons, and were initially dominated by a novel group of Oceanospirillales. As the summer progressed, Colwellia and Cycloclasticus became more abundant, followed by an increase in methanotrophs and methylotrophs. DNA stable isotope probing experiments showed that Colwellia spp. were the primary bacteria assimilating carbon from ethane and propane, suggesting that the presence of natural gas had a significant effect on the microbes that responded to the spill. Additional incubation experiments suggested that Colwellia could also consume benzene and other hydrocarbons in crude oil, but it was unclear whether the presence of natural gas stimulated or inhibited the consumption of other hydrocarbons. In order to determine the effect of natural gas on microbial community composition and the degradation of petroleum hydrocarbons, we conducted a series of incubation experiments with seawater from the deep Gulf of Mexico. We also conducted experiments to determine the effect of individual hydrocarbon compounds on the microbial community response. We will present results from both sets of experiments.

  2. The features of the chemical and mineralogical composition and the formation conditions of sediments in the filters and filtrational zones of the oil wells in the Velizhansk water inlet

    Energy Technology Data Exchange (ETDEWEB)

    Lobachev, A.D.; Drydin, V.M.; Sidorenkov, A.I.

    1979-01-01

    Based on a study of the chemical composition of the silt sediment taken from the filters of operational oil wells in the Velizhansk water inlet located in the Tyumen region, where iron hydroxide and calcium carbonate are the primary compounds, the silt deposition conditions are determined. Hydrochloric acid treatment is recommended for cleaning the filters, based on the feature of the chemicals and mineralogical composition of the silt sediment.

  3. Changes in growth, physiological parameters and the hormonal status of Myrtus communis L. plants irrigated with water with different chemical compositions.

    Science.gov (United States)

    Acosta-Motos, José Ramón; Ortuño, María Fernanda; Álvarez, Sara; López-Climent, María Fernanda; Gómez-Cadenas, Aurelio; Sánchez-Blanco, María Jesús

    2016-02-01

    Myrtus communis, an important Mediterranean ornamental shrub, was used to study the effect of irrigation water with different chemical compositions in the plant response. A treatment with NaCl was used to establish the plant resistance to high salinity at long term. Plants were subjected to four irrigation treatments with drainage for three months: Control (0.8 dS m(-1)); two treatments using reclaimed water (RWs): RW1 (2.0 dS m(-1)) and RW2 (5.0 dS m(-1)); and NaCl (10.0 dS m(-1)). High levels of electric conductivity of RWs not affected plant growth, while NaCl decreased leaf dry weight. Coinciding with the accumulation of Na(+) and Cl(-) in the roots, soil water potential decreased, which hinders the mobilization of water to the leaves, decreasing leaf water potential. The osmotic adjustment in the NaCl treatment was due to Na(+) and Cl(-) ions, although the proline could contribute as an Osmo compatible solute, increasing the turgor plants. Also changes in cell walls rigidity minimize the negative effects on the water balance; however, a higher lipid peroxidation was observed in these plants. Stomatal closure was associated with a decrease in K(+) and an increase in abscisic acid. NaCl produced an increase in salicylic acid and did not affect jasmonic acid contents at the end of the experiment. Similar behavior in soil and leaf water potentials, although less pronounced than in NaCl, was shown in RW2 plants. The abscisic acid increased in the RW2 with respect to the control and a decrease in stomatal conductance was observed at the end of the experiment. Plants irrigated with RW1 behaved similarly to the control.

  4. Chemical composition of Pechora Sea crude oil

    Directory of Open Access Journals (Sweden)

    Derkach S. R.

    2017-03-01

    Full Text Available The physicochemical properties of the Pechora Sea shelf oil and its chemical composition have been studied using the methods of refractometry, titrimetry, viscometry, rheometry and standard methods for the analysis of oil and petroleum products. The fractionation of oil is held at atmospheric pressure, some fractions boiling at the temperature below and above 211 °C have been received. Chemical structural-group composition of oil and its components has been investigated using a Fourier infrared (IR spectroscopy method. The density of oil has been obtained, it is equal to 24.2 API. The chemical composition analysis shows that water content in the investigated oil sample is about 0.03 % (by weight. The oil sample contains hydrocarbons (including alkanes, naphthenes, arenes and asphaltenes with resins; their content is equal to 89 and 10 % (by weight respectively. Alkane content is about 66 %, including alkanes of normal structure – about 37 %. The solidification temperature of oil sample is equal to –43 °C. This low temperature testifies obliquely low content of solid alkanes (paraffin. Bearing in mind the content of asphaltenes with resins we can refer the investigated oil sample to resinous oils. On the other hand spectral coefficient values (aromaticity quotient and aliphaticity quotient show that oil sample belongs to naphthenic oils. According to the data of Fourier IR spectroscopy contents of naphthenes and arenes are 5.9 and 17.8 % respectively. Thus, the obtained data of chemical structural-group composition of crude oil and its fractions indicate that this oil belongs to the heavy resinous naphthenic oils. The rheological parameters obtained at the shear deformation conditions characterize the crude oil as a visco-plastic medium.

  5. Physical, chemical, and mineralogical data from surficial deposits, groundwater levels, and water composition in the area of Franklin Lake playa and Ash Meadows, California and Nevada

    Science.gov (United States)

    Goldstein, Harland L.; Breit, George N.; Yount, James C.; Reynolds, Richard L.; Reheis, Marith C.; Skipp, Gary L.; Fisher, Eric M.; Lamothe, Paul J.

    2011-01-01

    This report presents data and describes the methods used to determine the physical attributes, as well as the chemical and mineralogical composition of surficial deposits; groundwater levels; and water composition in the area of Franklin Lake playa and Ash Meadows, California and Nevada. The results support studies that examine (1) the interaction between groundwater and the ground surface, and the transport of solutes through the unsaturated zone; (2) the potential for the accumulation of metals and metalloids in surface crusts; (3) emission of dust from metal-rich salt crust; and (4) the effects of metal-rich dusts on human and ecosystem health. The evaporation of shallow (salt in the subsurface and (or) the formation of salt crusts at the ground surface. Ground-surface characteristics such as hardness, electrical conductivity, and mineralogy depend on the types and forms of these salt crusts. In the study area, salt crusts range from hard and bedded to soft and loose (Reynolds and others, 2009). Depending on various factors such as the depth and composition of groundwater and sediment characteristics of the unsaturated zone, salt crusts may accumulate relatively high contents of trace elements. Soft, loose salt crusts are highly vulnerable to wind erosion and transport. These vulnerable crusts, which may contain high contents of potentially toxic trace elements, can travel as atmospheric dust and affect human and ecosystem health at local to regional scales.

  6. CLEAN CHEMICAL SYNTHESIS IN WATER

    Science.gov (United States)

    Newer green chemistry approach to accomplish chemical synthesis in water is summarized. Recent global developments pertaining to C-C bond forming reactions using metallic reagents and direct use of the renewable materials such as carbohydrates without derivatization are described...

  7. Minero-chemical composition as environmental quality assessment tool of an artificial water reservoir: the case of the "Pietra del Pertusillo" lake (Basilicata, Italia)

    Science.gov (United States)

    fortunato, elisabetta; mongelli, giovanni; paternoster, michele; sinisi, rosa

    2016-04-01

    C for subsequent chemical and mineralogical analysis. Further, in order to assess the provenance effects on the composition of lake sediments, the bedrock (Meso-Cenozoic rocks and Quaternary fluvial-lacustrine deposits) and the stream sediments of the main "Pietra del Pertusillo" tributaries, close to the detrital supply entry points of Pietra del Pertusillo lake were also sampled. The mineralogical composition was obtained from randomly oriented powders by XRPD. Chemistry (major, minor, and trace elements) was performed on powdered samples by ICP-MS technique after a four acids digestion and lithium metaborate/tetraborate fusion to facilitate the destruction of possible resistate minerals. Preliminary data related to the stream sediments show that both major and minor elements (including heavy metals, barium and arsenic) have a minor variability and are close to the median values of the bedrock. The mineralogical composition of the analysed samples can explain the elemental relationships,thus excluding any anthropogenic input. The mineralogical composition of the lacustrine samples is made of quartz, carbonates, feldspars, muscovite/illite, chlorite, and interstratified clay minerals, and it is constant throughout the cores. Finally, as further step ot he research plan, we are processing 20 of all lake samples with the highest peaks of interstratified clay minerals, which likely represent the most reactive phases in our sediment-water system.

  8. Regularities in changes of chemical composition of waters from the tenth zone of Bibieibat field during the development period

    Energy Technology Data Exchange (ETDEWEB)

    Markarova, O.A.

    1967-01-01

    While the tenth zone of Bibieibat oilfield was being flooded with seawater, advance of the flood front was determined by mineral analysis of produced water from several wells. Connate water had considerably greater mineral content than the injected seawater. Chloride content of produced water was determined before and during injection of seawater, and from these data the distribution of floodwater in the field is shown in 3 maps. The data show that floodwater did not advance uniformly everywhere. In most areas floodwater advanced at rates of 2 to 25 m per month; in some places advances of 40 m per month were found. Such nonuniformity in rates is caused by unequal pressure drops from place to place and by rock heterogeneity.

  9. Effects of mineral water differing in chemical composition on the post-radiation restorative processes of tissues

    Energy Technology Data Exchange (ETDEWEB)

    Zubkova, S.M.; Bulyakova, N.V.; Azarova, V.S.; Popova, M.F.; Korolev, Yu.N.; Nikulina, L.A.; Panova, L.N. [Russian Research Center for Rehabilitation and Physiotherapy, Moscow (Russian Federation)]|[Severtsov Institute of Evolutionary Morphology and Animal Ecology, Moscow (Russian Federation)

    1994-11-01

    Experiments have show that natural and manufactured water containing arsenic and iodine may alter radiosensitivity in rats. This effect is associated with the ability of certain concentrations of iodine and arsenic ions to decrease respiration and stimulate phosphorylation in rat liver mintochondria, with resulting tissue hypoxia. Combination of iodine and calcium produced a protective effect after 21 days of daily administration to rats that absorbed radiation. In particular the survival rate of the rates increased to 67% in comparison with a 36% survival rate in rats that received only calcium and a 100% death rate in rats which were left untreated. In addition to increased energization of rat liver mitochondria, the treatment produced an inhibition of renal parenchyma clacification caused by radiation. 6 refs., 2 figs., 2 tabs.

  10. The Effect of Vermicompost on Reducing the Adverse Effects of Water Stress on Growth and Chemical Composition of Corn in a Calcareous Soil

    Directory of Open Access Journals (Sweden)

    leila zare

    2017-01-01

    Full Text Available Introduction: Vermicompost is one of the important bio-fertilizer which is the product of the process of composting different organic wastes such as manures and crop residues using different earthworms. Vermicomposts, especially those are derived from animal wastes,contain the large amounts of nutrients compaired with the composts prepared from crop residues. Vermicomposts contain plant available form of nutrients such as nitrate nitrogen, exchangeable phosphorus and potassium, calcium and magnesium. Nowadays, the use of vermicompost in sustainable agriculture to improve the growth and quality of fruits and crops is very common. Drought occurs when the amount of moisture in soil and water resources and rainfall is less than what plants need for normal growth and function. Two thirds of farm lands in Iran have been located in arid and semi-arid regions with annual rainfall less than150 mm that has been distributed irregularly and unpredictable during growth season imposing water stress in most crops. It indicates the importance of water management and proposing different strategies for mitigating detrimental effect of water stress in croplands. Due to the fact that crops nutrient management under drought and water stress using organic fertilizers is an effective method in reaching to high yields in sustainable agriculture, the objective of the present study was to investigate the influence of vermicompost application on reducing the adverse effects of water stress on the growth and chemical composition of corn in a calcareous soil. Materials and Methods: In order to study the influence of water stress and application of vermicompost on corn dry matter yield and nutrients concentration of corn shoot, a greenhouse factorial experiment (4×3 in completely randomized design with three replications was conducted in college of agriculture, Shiraz university, Shiraz, Iran. The factors consisted of four vermicompost levels (0, 10, 20 and30g kg-1soil

  11. Chemical composition and mutagenic assessment of petrochemical ...

    African Journals Online (AJOL)

    Aghomotsegin

    their chemical composition and genotoxic effects on cell reproduction. Two petrochemicals, air liquid ... some potentially mutagenic heavy metals. The effects of the ... shows good correlation with mammalian test systems. (Fiskesjö, 1985a).

  12. Chemical composition of Earth-like planets

    CERN Document Server

    Ronco, M P; Marboeuf, U; Alibert, Y; de Elía, G C; Guilera, O M

    2015-01-01

    Models of planet formation are mainly focused on the accretion and dynamical processes of the planets, neglecting their chemical composition. In this work, we calculate the condensation sequence of the different chemical elements for a low-mass protoplanetary disk around a solar-type star. We incorporate this sequence of chemical elements (refractory and volatile elements) in our semi-analytical model of planet formation which calculates the formation of a planetary system during its gaseous phase. The results of the semi-analytical model (final distributions of embryos and planetesimals) are used as initial conditions to develope N-body simulations that compute the post-oligarchic formation of terrestrial-type planets. The results of our simulations show that the chemical composition of the planets that remain in the habitable zone has similar characteristics to the chemical composition of the Earth. However, exist differences that can be associated to the dynamical environment in which they were formed.

  13. Chemical contamination of water supplies

    Energy Technology Data Exchange (ETDEWEB)

    Shy, C.M.

    1985-10-01

    Man-made organic chemicals have been found in drinking water for many years. Their numbers and varieties increase as our analytical capabilities improve. The identified chemicals comprise 10 to 20% of the total organic matter present. These are volatile or low molecular weight compounds which are easily identified. Many of them are carcinogenic or mutagenic. Chlorinated compounds have been found in untreated well water at levels up to 21,300 micrograms/L and are generally present at higher levels in chlorine-treated water than in untreated water. Aggregate risk studies for cancer are summarized. The most common sites are: bladder, stomach, colon, and rectum. Such studies cannot be linked to individual cases. However, they are useful for identifying exposed populations for epidemiologic studies. Five case-control studies were reviewed, and significant associations with water quality were found for: bladder cancer in two studies, colon cancer in three and rectal cancer in four. A large study by the National Cancer Institute found that there had been a change in the source of raw water for 50% of the persons in one area between the years 1955 and 1975. Such flaws in the data may preclude finding a causal relation between cancer and contaminants in drinking water. Large case-control and cohort studies are needed because of the low frequency of the marker diseases, bladder and rectal cancer. Cohort studies may be precluded by variations in the kinds of water contaminants. Definitive questions about these issues are posed for cooperative effort and resolution by water chemists, engineers, and epidemiologists.

  14. Influence of African Dust and Volcanic Ash on the Chemical Composition of Cloud/Rain Water Collected in a Tropical Montane Cloud Forest in Puerto Rico

    Science.gov (United States)

    Reyes-Rodríguez, G. J.; Gioda, A.; Mayol-Bracero, O. L.; Collett, J.

    2007-12-01

    Some organic compounds present in aerosols are surface active and their presence in cloud condensation nuclei can affect the surface tension of cloud droplets. The nature of these surface active compounds in clouds and rainwater is not well understood and there is very little information about their content in remote tropical environments. Therefore, our study focuses on the chemical characterization of the organic component of cloud and rainwater samples collected in a tropical montane cloud forest on the island of Puerto Rico. Samples were collected during periods of varying air mass origin, including periods of influence by African dust and by volcanic ash. Cloud samples were collected using a compact version of the single-stage Caltech Active Strand Cloudwater Collector. Rain samples were collected using a passive collector. The organic fraction of collected samples was characterized using a total organic carbon and total nitrogen analyzer (TOC/TN) and nuclear magnetic resonance (1H-NMR) spectroscopy. Elemental and organic carbon (EC, OC) were determined for suspended particles contained in collected cloud and rainwater samples. These particles were also analyzed using scanning electron microscopy-energy dispersive spectrometry (SEM-EDS) to determine their elemental compositions. Preliminary results indicate that average concentrations of cloud water TOC ranged from 0.9 to 1.2 mg/L. Lower concentrations were observed in rainwater, 0.3 to 0.7 mg/L. TN concentrations were higher than TOC in cloud water samples when air masses came from the African continent. The suspended aerosol particles had a content of 2.0 µg of OC per mL of cloud water, but EC was not detected. Suspended particle analysis by SEM-EDS showed Si, Al, and Fe, which have crustal origin, as the predominant species. The 1H-NMR spectra showed alcohols in large quantities, suggesting the presence of biogenic material or polyols when air masses arrived from the African continent. A more complete set

  15. Chemical composition of Achatina fulica

    Directory of Open Access Journals (Sweden)

    Aboua, F.

    1990-01-01

    Full Text Available Proximate composition and mineral content were determined in snail without and with shell and shell atone from Achatina fulica. This snail has high protein (above 40 %, low fat (less than 3 % and is a relatively good source of macrominerals, including calcium, phosphorus, magnesium, potassium and sodium. Achatina fulica is an excellent source of iron but is poor in copper, zinc and manganese. The snail is very rich in calcium but very poor in phosphorus, potassium and magnesium.

  16. Reliability of chemical analyses of water samples

    Energy Technology Data Exchange (ETDEWEB)

    Beardon, R.

    1989-11-01

    Ground-water quality investigations require reliable chemical analyses of water samples. Unfortunately, laboratory analytical results are often unreliable. The Uranium Mill Tailings Remedial Action (UMTRA) Project`s solution to this problem was to establish a two phase quality assurance program for the analysis of water samples. In the first phase, eight laboratories analyzed three solutions of known composition. The analytical accuracy of each laboratory was ranked and three laboratories were awarded contracts. The second phase consists of on-going monitoring of the reliability of the selected laboratories. The following conclusions are based on two years experience with the UMTRA Project`s Quality Assurance Program. The reliability of laboratory analyses should not be taken for granted. Analytical reliability may be independent of the prices charged by laboratories. Quality assurance programs benefit both the customer and the laboratory.

  17. Reliability of chemical analyses of water samples

    Energy Technology Data Exchange (ETDEWEB)

    Beardon, R.

    1989-11-01

    Ground-water quality investigations require reliable chemical analyses of water samples. Unfortunately, laboratory analytical results are often unreliable. The Uranium Mill Tailings Remedial Action (UMTRA) Project`s solution to this problem was to establish a two phase quality assurance program for the analysis of water samples. In the first phase, eight laboratories analyzed three solutions of known composition. The analytical accuracy of each laboratory was ranked and three laboratories were awarded contracts. The second phase consists of on-going monitoring of the reliability of the selected laboratories. The following conclusions are based on two years experience with the UMTRA Project`s Quality Assurance Program. The reliability of laboratory analyses should not be taken for granted. Analytical reliability may be independent of the prices charged by laboratories. Quality assurance programs benefit both the customer and the laboratory.

  18. Depth profiles of the inorganic chemical composition of soil water in the unsaturated zone; Tiefenprofile der anorganisch-chemischen Zusammensetzung von Bodenwasser in der ungesaettigten Zone

    Energy Technology Data Exchange (ETDEWEB)

    Hoess, J.

    1992-04-01

    Soil water up to a depth of 4 m below ground surface was analysed for its inorganic-chemical composition. It was obtained as `soil solution` by centrifuging original moist soil samples. The analysis provides depth profiles of the concentration of the major inorganic ions in soil water of well evidence. The studies were made on the environmental research test site called `Horkheimer Insel`, 70 km north of Stuttgart, which is a joint research site within the project `Wasser-Abfall-Boden` of the country of Baden-Wuerttemberg. Samples were collected mainly on two parts of the test site, one being operated by `conventional` farming techniques, the other by `sustainable` techniques, i.e. lower quantities of agrochemical and reduced tillage. The nitrat content of soil water in 4 m depth under the field of sustainable argriculture during the three tested years of cultivation was on an average only 30% of the concentration under the field of conventional agriculture. This means, the amount of nitrat, which is carried in groundwater, could be reduced to the same extend by the chosen way of sustainable agriculture. In respect to the overall salt content of soil water the analysis showed, that it is already very high in the upper soil layer (0 - 25 cm) and does not increase with increasing depth. It can be concluded, that it is determined by processes within this zone of the plant roots and of main microbiological activity. Percolation through the layers beneath this zone only provides a change in the proportion of cation or anion concentrations. (orig.). [Deutsch] Bodenwasser bis zu einer Tiefe von 4 m Flurabstand wurde auf seine anorganisch-chemische Zusammensetzung hin untersucht. Es wurde durch Zentrifugieren original feuchter Bodenproben als `Bodenloesung` gewonnen. Die Untersuchung liefert aussagekraeftige Konzentrationsprofile der anorganischen Ionen im Bodenwasser. Die Probenahme erfolgte auf dem Naturmessfeld `Horkheimer Insel`, 70 km noerdlich von Stuttgart, einem

  19. Binary stars: Mass transfer and chemical composition

    Science.gov (United States)

    Lambert, D. L.

    1982-01-01

    It is noted that mass exchange (and mass loss) within a binary system should produce observable changes in the surface chemical composition of both the mass losing and mass gaining stars as a stellar interior exposed to nucleosyntheses is uncovered. Three topics relating mass exchange and/or mass loss to nucleosynthesis are sketched: the chemical composition of Algol systems; the accretion disk of a cataclysmic variable fed by mass from a dwarf secondary star; and the hypothesis that classical Ba II giants result from mass transfer from a more evolved companion now present as a white dwarf.

  20. Chemical and stable isotopic composition of water and gas in the Fort Union Formation of the Powder River Basin, Wyoming and Montana: Evidence for water/rock interaction and the biogenic origin of coalbed natural gas

    Science.gov (United States)

    Rice, Cynthia A.; Flores, Romeo M.; Stricker, Gary D.; Ellis, Margaret S.

    2008-01-01

    Significant amounts (> 36 million m3/day) of coalbed methane (CBM) are currently being extracted from coal beds in the Paleocene Fort Union Formation of the Powder River Basin of Wyoming and Montana. Information on processes that generate methane in these coalbed reservoirs is important for developing methods that will stimulate additional production. The chemical and isotopic compositions of gas and ground water from CBM wells throughout the basin reflect generation processes as well as those that affect water/rock interaction. Our study included analyses of water samples collected from 228 CBM wells. Major cations and anions were measured for all samples, δDH2O and δ18OH2O were measured for 199 of the samples, and δDCH4 of gas co-produced with water was measured for 100 of the samples. Results show that (1) water from Fort Union Formation coal beds is exclusively Na–HCO3-type water with low dissolved SO4 content (median < 1 mg/L) and little or no dissolved oxygen (< 0.15 mg/L), whereas shallow groundwater (depth generally < 120 m) is a mixed Ca–Mg–Na–SO4–HCO3 type; (2) water/rock interactions, such as cation exchange on clay minerals and precipitation/dissolution of CaCO3 and SO4 minerals, account for the accumulation of dissolved Na and depletion of Ca and Mg; (3) bacterially-mediated oxidation–reduction reactions account for high HCO3 (270–3310 mg/L) and low SO4 (median < 0.15 mg/L) values; (4) fractionation between δDCH4 (− 283 to − 328 per mil) and δDH2O (− 121 to − 167 per mil) indicates that the production of methane is primarily by biogenic CO2 reduction; and (5) values of δDH2O and δ18OH2O (− 16 to − 22 per mil) have a wide range of values and plot near or above the global meteoric water line, indicating that the original meteoric water has been influenced by methanogenesis and by being mixed with surface and shallow groundwater.

  1. 水对液相氧化处理聚乙烯木塑复合材胶接性能的影响%Effect of water on bonding properties for liquidoid chemical oxidation treated wood/PE composites

    Institute of Scientific and Technical Information of China (English)

    滕晓磊; 邸明伟

    2011-01-01

    The surface of wood/polyethylene (PE) composites was treated by liquidoid chemical oxidation to improve its adhesion properties.The water-resistance of treated wood/PE composites bonding joint was studied and the failure mechanism at soaking in water for the bonding joint was investigated by using analysis of contact angle,scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FT-IR) through effect of water on the surface properties of treated wood/PE composites in soaking experiments.The results showed that the untreated wood/PE composites were hard to be adhered due to the polyethylene component gathered on the surface of composites, and the bonding strength and water-resistance for wood/PE composites bonding joint were improved after liquidoid chemical oxidation treatment.Water showed a remarkable effect on the surface properties for oxidation treated wood/PE composites,the surface structure changed and the crack appeared on the surface due to the moisture absorption and expansion of the wood fiber within composites under soaking in water,which resulted in the failure of bonding joint for wood/PE composites.%采用液相氧化方法对木粉/聚乙烯木塑复合材料进行表面处理以改善其胶接性能研究了氧化处理后木塑复合材料胶接接头的耐水性,并利用接触角测试、SEM、FT-IR等分析手段,探讨了木塑复合材料胶接接头在水环境下的老化失效原因 结果表明,未处理的聚乙烯木塑复合材料难以胶接,经过液相氧化处理后,不但可以提高聚乙烯木塑复合材料的胶接强度,还可改善木塑复合材料胶接接头的耐水性 在水的作用下,液相氧化处理聚乙烯木塑复合材的表面结构会发生改变,复合材料中木质纤维的吸水膨胀也会导致材料表面出现裂纹,致使胶接接头失效.

  2. Chemical Composition of Ceramic Tile Glazes

    Science.gov (United States)

    Anufrik, S. S.; Kurian, N. N.; Zhukova, I. I.; Znosko, K. F.; Belkov, M. V.

    2016-11-01

    We have carried out laser emission and x-ray fluorescence spectral analysis of glaze before and after its application to ceramic tile produced by Keramin JSC (Belarus). We have studied the internal microstructure of the ceramic samples. It was established that on the surface and within the bulk interior of all the samples, there are micropores of sizes ranging from a few micrometers to tens of micrometers and microcracks as long as several hundred micrometers. The presence of micropores on the surface of the ceramic tile leads to an increase in the water absorption level and a decrease in frost resistance. It was found that a decrease in the surface tension of ceramic tile coatings is promoted by substitution of sodium by potassium, silica by boric anhydride, magnesium and barium by calcium, CaO by sodium oxide, and SiO2 by chromium oxide. We carried out a comparative analysis of the chemical composition of glaze samples using S4 Pioneer and ElvaX x-ray fluorescence spectrometers and also an LIBS laser emission analyzer.

  3. Sensory properties and chemical composition of Sharri cheese from Kosovo

    Directory of Open Access Journals (Sweden)

    Agim Rysha

    2014-11-01

    Full Text Available Food sensory properties, analyses and chemical composition are very important because they provide information about product quality and end-user acceptance or preferences. An assessment of sensory characteristics and chemical composition of mountain sheep and cow’s-milk cheese from shepherd’s huts and industrial manufacturers in Kosovo was carried out. Consumer-oriented tests using a 9 point hedonic scale were conducted in order to determine Sharri cheese acceptability. Chemical parameters (fat content, fat content of dry matter, acidity, protein, dry matter, mineral and water content and sodium chloride content of 45-day brine cheese samples were also analyzed. Chemical and sensory assessment demonstrated large property differences. A recommendation stems from the results showing that the standardization of both artisanal and industrial production of Sharri cheese is required.

  4. Potential Impacts of Spilled Hydraulic Fracturing Fluid Chemicals on Water Resources: Types, volumes, and physical-chemical properties of chemicals

    Science.gov (United States)

    Hydraulic fracturing (HF) fluid chemicals spilled on-site may impact drinking water resources. While chemicals generally make up <2% of the total injected fluid composition by mass, spills may have undiluted concentrations. HF fluids typically consist of a mixture of base flui...

  5. Chemical composition of selected Saudi medicinal plants

    Directory of Open Access Journals (Sweden)

    Ihsanullah Daur

    2015-05-01

    Full Text Available Medicinal plants are important in traditional medicine and modern pharmaceutical drugs; therefore, the interest in the analysis of their chemical composition is increasing. In this study, selected medicinal plants including Achillea fragrantissima (Forssk Sch., Amaranthus viridis L., Asteriscus graveolens (Forssk. Less., Chenopodium album L., and Conyza bonariensis (L. Cronquist were collected from the rangeland of western regions (Bahra and Hada areas of Saudi Arabia to study their chemical composition. Eight minerals (Mg, Ca, Cr, Mn, Fe, Co, Cu, and Zn, total phenolic contents, antioxidant activity, and free-radical scavenging ability were examined in order to evaluate the medicinal potential of these plants. All the plants were found to be rich sources of minerals and antioxidants, although there were significant differences (p < 0.05 in their chemical composition, which may provide a rationale for generating custom extracts from specific plants depending on the application. The findings of this study will thus facilitate herbalists in their efforts to incorporate these plants into various formulations based on their chemical composition.

  6. Chemical composition, true metabolisable energy content and ...

    African Journals Online (AJOL)

    aneldavh

    narrow leaf lupins (Lupinus angustifolius; n = 8), faba beans (Vicia faba; ... characteristics (thousand seed and hectolitre mass), chemical composition ... therefore, that the nutritional potential of alternative plant protein feeds, such as ... (L. luteus, L. albus and L. angustifolius), faba beans and narbon beans for ..... Food Agric.

  7. [Investigation of chemical composition of propolis extract].

    Science.gov (United States)

    Majiene, Daiva; Trumbeckaite, Sonata; Grūnoviene, Danguole; Ivanauskas, Liudas; Gendrolis, Antanas

    2004-01-01

    Propolis is a natural product, produced by bees and containing exudates from plants, mixed with bee wax. Propolis and its ethanolic extract are usually used for treatment and prevention of different diseases. Propolis has antibacterial, antiviral, antifungal, anti-inflammatory, anesthetic and immunomodulating properties. Till now there is no data about chemical composition of Lithuanian propolis. Thus, the aim of our work was to investigate the chemical composition of Lithuanian propolis and its ethanolic extract by using gas chromatography / mass spectrometry. We found, that the main structural types of compounds were terpenoids, aromatic and aliphatic acid esters. The most of terpenoids were mono- and sesquiterpens: azulene, alpha-bisabolol, citral, valerenol, etc. Thus, our data show, that the composition of propolis is various and depends on the origin of plants, from where propolis was collected.

  8. Influence of the presence of carbon dioxide on chemical composition of water in contact with mining waste

    Directory of Open Access Journals (Sweden)

    Magdalena Cempa-Balewicz

    2015-01-01

    Full Text Available Nowadays post mining areas are often reclaimed and used housing areas, sports areas and recreational areas. Mining waste weathering is a significant factor influencing the condition of the surrounding water and soil environment. It is necessary then to evaluate susceptibility of the waste to weathering in given conditions and predict the rate of the processes. The paper presents initial results of an experimental study evaluating the influence of the presence of CO2 on the composition of leachate obtained when mining waste is exposed to water. The results of the experiments confirm the importance of the oxidation of pyrite and dissolution of carbonate minerals in changing the pH of water interacting with the waste.

  9. [Chemical composition and daily variation of melt water during ablation season in monsoonal temperate Glacier region: a case study of Baishui Glacier No. 1].

    Science.gov (United States)

    Zhu, Guo-Feng; Pu, Tao; He, Yuan-Qing; Wang, Pei-Zhen; Kong, Jian-Long; Zhang, Ning-Ning; Xin, Hui-Juan

    2012-12-01

    Melt water samples collected continuously from 29 August to 3 September 2009 in the Baishui Glacier No. 1 at elevation of 4750 m were analyzed for pH, conductivity, delta18O and inorganic ions. The results showed that the pH had obvious diurnal variations and was increased slightly by the influence of precipitation. The dissolution of alkaline soluble salts in the dust was the main reason for the increase of melt water conductivity; the value of delta18O was relatively low in strong ablation period and high in slight ablation period. Different from other research areas, the concentrations of Na+, K+, which were influenced by lithological and marine water vapor, were higher than that of Mg2+ in the study area; HCO3- and Ca2+ accounted for more than 80% of total ions in snow and ice melt water, indicating that the ions mainly came from limestone and the melt water was a typical carbonate solution; The content of melt water had an obvious daily change with temperature change, but the response amplitudes were different; Monsoon transport, local rock lithology, human industrial and agricultural activities were the main sources of inorganic ions and the deciding factors of the ion composition in the Baishui Glacier No. 1.

  10. Chemical Composition and Potential Environmental Impacts of Water-Soluble Polar Crude Oil Components Inferred from ESI FT-ICR MS.

    Science.gov (United States)

    Liu, Yina; Kujawinski, Elizabeth B

    2015-01-01

    Polar petroleum components enter marine environments through oil spills and natural seepages each year. Lately, they are receiving increased attention due to their potential toxicity to marine organisms and persistence in the environment. We conducted a laboratory experiment and employed state-of-the-art Fourier-transform ion cyclotron resonance mass spectrometry (FT-ICR-MS) to characterize the polar petroleum components within two operationally-defined seawater fractions: the water-soluble fraction (WSF), which includes only water-soluble molecules, and the water-accommodated fraction (WAF), which includes WSF and microscopic oil droplets. Our results show that compounds with higher heteroatom (N, S, O) to carbon ratios (NSO:C) than the parent oil were selectively partitioned into seawater in both fractions, reflecting the influence of polarity on aqueous solubility. WAF and WSF were compositionally distinct, with unique distributions of compounds across a range of hydrophobicity. These compositional differences will likely result in disparate impacts on environmental health and organismal toxicity, and thus highlight the need to distinguish between these often-interchangeable terminologies in toxicology studies. We use an empirical model to estimate hydrophobicity character for individual molecules within these complex mixtures and provide an estimate of the potential environmental impacts of different crude oil components.

  11. Chemical Composition and Potential Environmental Impacts of Water-Soluble Polar Crude Oil Components Inferred from ESI FT-ICR MS.

    Directory of Open Access Journals (Sweden)

    Yina Liu

    Full Text Available Polar petroleum components enter marine environments through oil spills and natural seepages each year. Lately, they are receiving increased attention due to their potential toxicity to marine organisms and persistence in the environment. We conducted a laboratory experiment and employed state-of-the-art Fourier-transform ion cyclotron resonance mass spectrometry (FT-ICR-MS to characterize the polar petroleum components within two operationally-defined seawater fractions: the water-soluble fraction (WSF, which includes only water-soluble molecules, and the water-accommodated fraction (WAF, which includes WSF and microscopic oil droplets. Our results show that compounds with higher heteroatom (N, S, O to carbon ratios (NSO:C than the parent oil were selectively partitioned into seawater in both fractions, reflecting the influence of polarity on aqueous solubility. WAF and WSF were compositionally distinct, with unique distributions of compounds across a range of hydrophobicity. These compositional differences will likely result in disparate impacts on environmental health and organismal toxicity, and thus highlight the need to distinguish between these often-interchangeable terminologies in toxicology studies. We use an empirical model to estimate hydrophobicity character for individual molecules within these complex mixtures and provide an estimate of the potential environmental impacts of different crude oil components.

  12. Water in Biological and Chemical Processes

    Science.gov (United States)

    Bagchi, Biman

    2013-11-01

    Part I. Bulk Water: 1. Uniqueness of water; 2. Anomalies of water; 3. Dynamics of water: molecular motions and hydrogen bond breaking kinetics; 4. Inherent structures of liquid water; 5. pH of water; Part II. Water in Biology: Dynamical View and Function: 6. Biological water; 7. Explicit role of water in biological functions; 8. Hydration of proteins; 9. Can we understand protein hydration layer: lessons from computer simulations; 10. Water in and around DNA and RNA; 11. Role of water in protein-DNA interaction; 12. Water surrounding lipid bilayers; 13. Water in Darwin's world; Part III. Water in Complex Chemical Systems: 14. Hydrophilic effects; 15. Hydrophobic effects; 16. Aqueous binary mixtures: amphiphilic effect; 17. Water in and around micelles, reverse micelles and microemulsions; 18. Water in carbon nanotubes; Part IV. Bulk Water: Advanced Topics: 19. Entropy of water; 20. Freezing of water into ice; 21. Supercritical water; 22. Microscopic approaches to understand water anomalies.

  13. Compositional, physical and chemical modification of polylactide

    Directory of Open Access Journals (Sweden)

    M. Żenkiewicz

    2010-11-01

    Full Text Available Purpose: The purpose of this article was to review some of the modification methods applied to improve mechanical, barrier and/or surface properties of polylactide (PLA.Design/methodology/approach: The presented modification methods were classified into three groups due to the dominant role of compositional, physical or chemical factor effecting the most PLA properties.Findings: It was found that incorporation of small amounts of montmorillonite up to 5% leads to formation of a nanocomposite with enhanced tensile strength and improved barrier properties. Corona treatment of pure PLA and PLA contained MMT nanofiller causes a significant decrease in the water contact angle and does not essentially affect the diiodomethane contact angle. This treatment leads to an increase in surface free energy that is much more significant for pure PLA than for PLA containing MMT nanofiller. It was also found that with increasing number up to 1000 of laser pulses of energies 5 mJ/cm2 an increase in surface free energy was observed, while the next laser pulses caused decrease of this energy. The determination and comparison of the influence of 3 wt.% of trimethylopropane trimethacylate (TMPTA and 3 wt.% of trially isocyanurate (TAIC crosslinking agents on the thermomechanical properties of electron beam irradiated PLA was reported.Research limitations/implications: A number of various modification methods are widely reported in literature. In this article a review of only such modification methods is presented, which are in line with the newest trends in polymer industry and science.Practical implications: There are a number of PLA properties, which need to be improved to satisfy specific application conditions. For that reasons researches are leading to find suitable modification methods to improve selected properties of PLA.Originality/value: This article presents some of modification methods, which are in line with the newest trends in polymer industry and

  14. Seasonal variation in the chemical composition of two tropical seaweeds.

    Science.gov (United States)

    Marinho-Soriano, E; Fonseca, P C; Carneiro, M A A; Moreira, W S C

    2006-12-01

    The chemical composition of red seaweed Gracilaria cervicornis and brown seaweed Sargassum vulgare from Brazil was investigated. In this study, the relationship between the nutritive components of each species and the environment was established. Protein content varied from 23.05+/-3.04% to 15.97+/-3.04%. The highest value was found in G. cervicornis. The protein levels were positively correlated with nitrogen content and negatively with water temperature and salinity. Carbohydrate contents of both species varied significantly (prelated to environment.

  15. Impact of oil on groundwater chemical composition

    Science.gov (United States)

    Brakorenko, N. N.

    2015-11-01

    The objective of the paper is to characterize the chemical composition of groundwater samples from the monitoring wells drilled in the petrol station areas within the vicinity of Tomsk. The level of contamination has increased since many macro - and microcomponent concentrations (such as petroleum products, chlorine, sulphates, carbon dioxide and lead, etc.) in groundwater samples of the present study is higher than that in previous period samples.

  16. Reinforced polypropylene composites: effects of chemical compositions and particle size.

    Science.gov (United States)

    Ashori, Alireza; Nourbakhsh, Amir

    2010-04-01

    In this work, the effects of wood species, particle sizes and hot-water treatment on some physical and mechanical properties of wood-plastic composites were studied. Composites of thermoplastic reinforced with oak (Quercus castaneifolia) and pine (Pinus eldarica) wood were prepared. Polypropylene (PP) and maleic anhydride grafted polypropylene (MAPP) were used as the polymer matrix and coupling agent, respectively. The results showed that pine fiber had significant effect on the mechanical properties considered in this study. This effect is explained by the higher fiber length and aspect ratio of pine compared to the oak fiber. The hot-water treated (extractive-free) samples, in both wood species, improved the tensile, flexural and impact properties, but increased the water absorption for 24h. This work clearly showed that lignocellulosic materials in both forms of fiber and flour could be effectively used as reinforcing elements in PP matrix. Furthermore, extractives have marked effects on the mechanical and physical properties.

  17. Composition and placement process for oil field chemicals

    Energy Technology Data Exchange (ETDEWEB)

    Cantu, L.A.; Yost, M.E.

    1991-01-22

    This patent describes a process for the continuous release of an oil field chemical within a subterranean hydrocarbon bearing formation or wellbore penetrating such formation. It comprises placing the oil field chemical in a polymeric microcapsule; dispersing such polymeric microcapsules; introducing the wellbore fluid containing the microcapsules into a well bore or subterranean formation through a wellbore; then allowing water and temperature at formation conditions to degrade; continuously releasing the chemical from the degraded microcapsules. This patent describes a composition comprising an oil field chemical incorporated in a polymeric microcapsule comprising the condensation product of hydroxyacetic acid monomer or hydroxyacetic acid co-condensed with up to 15 percent by weight of other hydroxy-, carboxylic acid-, or hydroxycarboxylic acid- containing moieties. The product has a number average molecular weight of from about 200 to about 4000.

  18. Physico-chemical water characteristics and aquatic ...

    African Journals Online (AJOL)

    Physico-chemical water characteristics and aquatic macroinvertebrates of Lake ... Saline lakes are known to be amongst the most productive ecosystems in the world. ... birds, knowledge of its water characteristics and aquatic biota is scarce.

  19. The Chemical Composition of the Sun

    Science.gov (United States)

    Asplund, Martin; Grevesse, Nicolas; Sauval, A. Jacques; Scott, Pat

    2009-09-01

    The solar chemical composition is an important ingredient in our understanding of the formation, structure, and evolution of both the Sun and our Solar System. Furthermore, it is an essential reference standard against which the elemental contents of other astronomical objects are compared. In this review, we evaluate the current understanding of the solar photospheric composition. In particular, we present a redetermination of the abundances of nearly all available elements, using a realistic new three-dimensional (3D), time-dependent hydrodynamical model of the solar atmosphere. We have carefully considered the atomic input data and selection of spectral lines, and accounted for departures from local thermodynamic equilibrium (LTE) whenever possible. The end result is a comprehensive and homogeneous compilation of the solar elemental abundances. Particularly noteworthy findings are significantly lower abundances of C, N, O, and Ne compared to the widely used values of a decade ago. The new solar chemical composition is supported by a high degree of internal consistency between available abundance indicators, and by agreement with values obtained in the Solar Neighborhood and from the most pristine meteorites. There is, however, a stark conflict with standard models of the solar interior according to helioseismology, a discrepancy that has yet to find a satisfactory resolution.

  20. Study and interpretation of the chemical characteristics of natural water

    Science.gov (United States)

    Hem, John David

    1985-01-01

    The chemical composition of natural water is derived from many different sources of solutes, including gases and aerosols from the atmosphere, weathering and erosion of rocks and soil, solution or precipitation reactions occurring below the land surface, and cultural effects resulting from human activities. Broad interrelationships among these processes and their effects can be discerned by application of principles of chemical thermodynamics. Some of the processes of solution or precipitation of minerals can be closely evaluated by means of principles of chemical equilibrium, including the law of mass action and the Nernst equation. Other processes are irreversible and require consideration of reaction mechanisms and rates. The chemical composition of the crustal rocks of the Earth and the composition of the ocean and the atmosphere are significant in evaluating sources of solutes in natural freshwater.

  1. Separation of tritiated water from water using composite membranes

    Energy Technology Data Exchange (ETDEWEB)

    Duncan, J.; Nelson, D.

    1996-10-01

    Polymeric composite membranes are being developed to remove tritium from contaminated water at DOE sites. Industrial membrane systems are being developed that have proven to be energy efficient, and membrane technologies such as reverse-osmosis have been well developed for desalination and other industrial/municipal applications. Aromatic polyphosphazene membranes are being investigated because they have excellent radiological, thermal, and chemical stability. The FY 1996 effort is directed toward delineating a potential mechanism, providing a statistical approach to data acquisition, refining a mass balance, and designing a staged array module.

  2. Chemical Composition of Different Varieties of Linseed

    Directory of Open Access Journals (Sweden)

    M. Laiq Khan*, M. Sharif, M. Sarwar, Sameea1 and M. Ameen

    2010-04-01

    Full Text Available The present study was conducted to investigate chemical composition of six varieties of linseed (Chandni, LS-29, LS-49, LS-70, LS-75 and LS-76. Proximate composition, mineral profile and cyanogenic glycosides (linamarin were determined. Average proximate composition values for linseed i.e. crude protein, ether extract, crude fiber, ash and nitrogen free extract were 24.18, 37.77, 4.78, 3.50 and 25.86%, respectively. Higher values of crude protein, ether extract, crude fiber and nitrogen free extract were observed in varieties LS-49, LS-70, LS-29 and Chandni, respectively. Average mineral contents in linseed i.e. Ca, Mg, K, Na, Cl, P, Cu, Fe, Mn and Zn were 0.39, 0.09, 1.41, 0.05, 0.08, 0.89, 4.67, 50.56, 8.29 and 13.55 ppm, respectively. Among micro minerals, varieties LS-29 and LS-70 were higher in Cu contents; LS-75 was higher in Fe content, while LS-49 was higher in Mn and Zn contents. Among macro minerals, level of Ca was higher in LS-70, levels of Mg, K and Na were higher in Chandni, while P was higher in LS-49. Average amount of linamarin in linseed was 31.05mg/100 gm DM. The variety LS-75 had the highest (35.22 mg/100 gm linamarin content, while variety LS-70 had least (26.22 mg/100 gm amount of linamarin. In conclusion, there is significant difference in chemical composition among linseed varieties. The varieties LS-49 showed higher crude protein content, LS-70 showed greater oil content, while LS-75 had higher content of linamarin.

  3. Features of a chemical composition of dry leaves of Steviavebaudiana

    Directory of Open Access Journals (Sweden)

    Irina Borisovna Krasina

    2016-05-01

    Full Text Available This work is dedicated to the study of a chemical composition of dry leaves of Stevia. Dry leaves of Stevia contain diterpene glycosides that contribute to their sweet taste, which makes possible the use of Stevia as a sugar substitute in a production of flour confectionery products. The evaluation of amino acid composition of dried leaves of Stevia showed that their composition includes 7 essential amino acids, among them the limiting amino acid is valine.During experimental researches it was established that they are containing in a sufficient quantity water-soluble and fat-soluble vitamins in their composition. We have studied the effect of processing conditions on the degree of milling of dry leaves of Stevia. It was revealed that the pressure of 5 MPa in the contact zone of the working elements do not guarantee a product with a desired degree of milling. Milling of dried leaves of Stevia at a pressure equal to 10 MPa, allows achieving a high degree of size reduction with a simultaneous formation of the main physical and chemical characteristics of amilledproduct. It was established that granulometric composition of dry leaves of Stevia, obtained by milling in a rotor-roller disintegrator, presents the highest content of particles with a size from 5 to 30 μm, ensuring high consumer properties of the obtained biologically active additives (BAA.

  4. On the chemical composition of Titan's dry lakebed evaporites

    CERN Document Server

    Cordier, Daniel; Ferreira, Abel

    2013-01-01

    Titan, the main satellite of Saturn, has an active cycle of methane in its troposphere. Among other evidence for a mechanism of evaporation at work on the ground, dry lakebeds have been discovered. Recent Cassini infrared observations of these empty lakes have revealed a surface composition poor in water ice compared to that of the surrounding terrains --- suggesting the existence of organic evaporites deposits. The chemical composition of these possible evaporites is unknown. In this paper, we study evaporite composition using a model that treats both organic solids dissolution and solvent evaporation. Our results suggest the possibility of large abundances of butane and acetylene in the lake evaporites. However, due to uncertainties of the employed theory, these determinations have to be confirmed by laboratory experiments.

  5. Cometary Coma Chemical Composition (C4) Mission

    Science.gov (United States)

    Carle, Glenn C.; Clark, Benton C.; Knocke, Philip C.; OHara, Bonnie J.; Adams, Larry; Niemann, Hasso B.; Alexander, Merle; Veverka, Joseph; Goldstein, Raymond; Huebner, Walter; Morrison, David (Technical Monitor)

    1994-01-01

    Cometary exploration remains of great importance to virtually all of space science. Because comets are presumed to be remnants of the early solar nebula, they are expected to provide fundamental knowledge as to the origin and development of the solar system as well as to be key to understanding of the source of volatiles and even life itself in the inner solar system. Clearly the time for a detailed study of the composition of these apparent messages from the past has come. A comet rendezvous mission, the Cometary Coma Chemical Composition (C4) Mission, is now being studied as a candidate for the new Discovery program. This mission is a highly-focussed and usefully-limited subset of the Cometary Rendezvous Asteroid Flyby (CRAF) Mission. The C4 mission will concentrate on measurements that will produce an understanding of the composition and physical makeup of a cometary nucleus. The core science goals of the C4 mission are 1) to determine the chemical, elemental, and isotopic composition of a cometary nucleus and 2) to characterize the chemical and isotopic nature of its atmosphere. A related goal is to obtain temporal information about the development of the cometary coma as a function of time and orbital position. The four short-period comets -- Tempel 1, Tempel 2, Churyumov-Gerasimenko, and Wirtanen -which all appear to have acceptable dust production rates, were identified as candidate targets. Mission opportunities have been identified beginning as early as 1998. Tempel I with a launch in 1999, however, remains the baseline comet for studies of and planning the C4 mission. The C4 mission incorporates two science instruments and two engineering instruments in the payload to obtain the desired measurements. The science instruments include an advanced version of the Cometary Ice and Dust Experiment (CIDEX), a mini-CIDEX with a sample collection system, an X-ray Fluorescence Spectrometer and a Pyrolysis-Gas Chromatograph, and a simplified version of the Neutral

  6. CHEMICAL QUALITY CHARACTERISTICS OF TEHRAN GROUND WATER

    Directory of Open Access Journals (Sweden)

    K. Imandel

    1994-06-01

    Full Text Available For better understanding of Tehran ground water, samples were taken randomly from 340 out of 655 deep & semi deep wells in 1993, which dug by Tehran Water Supply and Sewage Engineering Company. 260 Water specimens were examined chemically and physically and compared with the 1993 World Health Organization (WHO and Food and Agriculture Organization (FAO criteria and analyzed statistically. Logarithmic diagram of arithmetic mean of 53 deep wells which are now connected to Tehran water supply system showed Sodium- Sulphate category. Main chemical components of water are closely adjusted to the international standards and no overdoses were observed in any cases. Logarithmic diagram of arithmetic mean of 72 deep wells, which were rsed for the Tehran’s orbital town's drinking water, showed that chemical components of the water were Calcic-Chloride category and there were not observed any increases within the other compounds.

  7. Water Absorption Behavior of Hemp Hurds Composites

    OpenAIRE

    Nadezda Stevulova; Julia Cigasova; Pavol Purcz; Ivana Schwarzova; Frantisek Kacik; Anton Geffert

    2015-01-01

    In this paper, water sorption behavior of 28 days hardened composites based on hemp hurds and inorganic binder was studied. Two kinds of absorption tests on dried cube specimens in deionized water bath at laboratory temperature were performed. Short-term (after one hour water immersion) and long-term (up to 180 days) water absorption tests were carried out to study their durability. Short-term water sorption behavior of original hemp hurds composites depends on mean particle length of hemp an...

  8. Review of Wildfire Effects on Chemical Water Quality

    Energy Technology Data Exchange (ETDEWEB)

    Kelly Bitner; Bruce Gallaher; Ken Mullen

    2001-05-01

    The Cerro Grande Fire of May 2000 burned almost 43,000 acres of forested land within the Pajarito Plateau watershed in northern New Mexico. Runoff events after the fire were monitored and sampled by Los Alamos National Laboratory. Changes in the composition of runoff water were noted when compared to runoff water composition of the previous 20 years. In order to understand the chemical water quality changes noted in runoff water after the Cerro Grande Fire, a summary of the reported effects of fire on runoff water chemistry and on soils that contribute to runoff water chemistry was compiled. The focus of this report is chemical water quality, so it does not address changes in sediment transport or water quantity associated with fires. Within the general inorganic parameters, increases of dissolved calcium, magnesium, nitrogen, phosphorus, and potassium and pH in runoff water have been observed as a result of fire. However, the dissolved sodium, carbon, and sulfate have been observed to increase and decrease as a result of fire. Metals have been much less studied, but manganese, copper, zinc, and cesium-137 have been observed to increase as a result of fire.

  9. Impact of the changes in the chemical composition of pore water on chemical and physical stability of natural clays. A review of natural cases and related laboratory experiments and the ideas on natural analogues for bentonite erosion/non-erosion

    Energy Technology Data Exchange (ETDEWEB)

    Puura, Erik (Eridicon OUe, Tartu (Estonia)); Kirsimaee, Kalle (Univ. of Tartu, Inst. of Ecology and Earth Sciences, Tartu (Estonia))

    2010-01-15

    A scientific literature survey was compiled with the specific objective to find information for smectite mobilization and/or retention in natural clay formations caused by contact with water with low ionic concentrations such as can be expected during and after an ice age. Evidence was sought if smectite particles are lost from the clay to the water and if accessory minerals that remain could form a growing filter slowing down or stopping further loss of smectite. Bentonites are present in geological layers for hundreds of millions of years. There is limited exchange with surrounding layers, eg K transported into the bentonite layer from surrounding shale layers leading to the increased illite % in smectite-illite of the bentonite. Another process is silicification of surrounding layers leading to lowered permeability of surrounding rocks. Geological literature data on historical bentonites do not consider colloid formation in low ionic strength water as relevant mechanism for smectite mobilization. However there are no studied cases where this could be a relevant mechanism (as proposed by colloid release scenario). Soil researchers have studied the mechanism of colloid release in laboratory experiments and have found that there has to be an abrupt change in infiltrating water quality leading to 'osmotic explosion'. Clogging the pores in the lower part of the soil column has followed, leading to dramatic decrease of hydraulic conductivity in vertical profile and increased surface runoff. So, although limited, there are literature evidences of clay colloids release from bentonites/smectites caused by low-ionic circumneutral water. The geological settings to look for natural analogue studies include (1) Bentonite/smectite similar to what is used in repository. (2) Water similar to the composition of glacial meltwater. (3) Scenario similar to what is proposed in the bentonite erosion project. The problem related to the study of historical bentonite profiles

  10. Chemical Composition and Antibacterial Effects of

    Directory of Open Access Journals (Sweden)

    SS Saei Dehkordi

    2009-10-01

    Full Text Available Introduction & Objective: Rosmarinus officinalis L. as a member of the Lamiaceae family and lysozyme as a natural antibacterial agent is important in food microbiology, because of its characteristics. The aim of the present study was to determine the chemical composition and anti-listerial activity of Rosmarinus officinalis essential oil (REO alone and in combination with lysozyme for enhancement of anti-listerial activity of both substances. Materials & Methods: Rosmarinus officinalis L. was purchased from a local grocery store at Shahrekord and was identified by the Institute of Medicinal Plants, ACECR. The air-dried aerial parts were subjected to hydrodistillation using a Clevenger apparatus to obtain essential oil and yielded oil was analyzed by GC/MS. Antibacterial activity (on basis of Minimum Inhibitory Concentration (MIC of REO was studied separately and in combination with unheated lysozyme (L and heat-treated lysozyme (HTL on Listeria monocytogenes at different pH (5, 6 and 7 by a micro-broth dilution assay. The collected data were analyzed by SPSS software. Results: In the current study, 98.05% of constituents of the essential oil were identified. The major components were α-pinene (14.06%, 1,8-cineole (13.62%, verbenone (11.2%, camphor (10.51%, borneol (7.3%, 3-octanone (7.02%, camphene (5.46% and linalool (5.07%. The inhibitory action of REO was stronger at lower pH especially 5 (MIC=225 μg/mL. Inhibition by L at pH 5 was 640 μg/mL but no inhibition was seen at pH 7. HTL resulted in more effective inhibition than L, especially at pH 5 and heat-treatment 80˚C (MIC: 160 μg/mL. Conclusion: Combination of L + REO and particularly HTL + REO was led to enhancement of bacterial inhibition. It was concluded that REO by the identified chemical composition was effective alone or in combination with L or HTL on Listeria monocytogenes as a food-borne pathogen.

  11. On-line chemical composition analyzer development

    Energy Technology Data Exchange (ETDEWEB)

    Roberts, M.J.; Garrison, A.A.; Muly, E.C.; Moore, C.F.

    1992-02-01

    The energy consumed in distillation processes in the United States represents nearly three percent of the total national energy consumption. If effective control of distillation columns can be accomplished, it has been estimated that it would result in a reduction in the national energy consumption of 0.3%. Real-time control based on mixture composition could achieve these savings. However, the major distillation processes represent diverse applications and at present there does not exist a proven on-line chemical composition sensor technology which can be used to control these diverse processes in real-time. This report presents a summary of the findings of the second phase of a three phase effort undertaken to develop an on-line real-time measurement and control system utilizing Raman spectroscopy. A prototype instrument system has been constructed utilizing a Perkin Elmer 1700 Spectrometer, a diode pumped YAG laser, two three axis positioning systems, a process sample cell land a personal computer. This system has been successfully tested using industrially supplied process samples to establish its performance. Also, continued application development was undertaken during this Phase of the program using both the spontaneous Raman and Surface-enhanced Raman modes of operation. The study was performed for the US Department of Energy, Office of Industrial Technologies, whose mission is to conduct cost-shared R D for new high-risk, high-payoff industrial energy conservation technologies. Although this document contains references to individual manufacturers and their products, the opinions expressed on the products reported do not necessarily reflect the position of the Department of Energy.

  12. Polyfluorinated chemicals in European surface waters, ground- and drinking waters

    NARCIS (Netherlands)

    Eschauzier, C.; de Voogt, P.; Brauch, H.-J.; Lange, F.T.; Knepper, T.P.; Lange, F.T.

    2012-01-01

    Polyfluorinated chemicals (PFCs), especially short chain fluorinated alkyl sulfonates and carboxylates, are ubiquitously found in the environment. This chapter aims at giving an overview of PFC concentrations found in European surface, ground- and drinking waters and their behavior during convention

  13. Polyfluorinated chemicals in European surface waters, ground- and drinking waters

    NARCIS (Netherlands)

    Eschauzier, C.; de Voogt, P.; Brauch, H.-J.; Lange, F.T.; Knepper, T.P.; Lange, F.T.

    2012-01-01

    Polyfluorinated chemicals (PFCs), especially short chain fluorinated alkyl sulfonates and carboxylates, are ubiquitously found in the environment. This chapter aims at giving an overview of PFC concentrations found in European surface, ground- and drinking waters and their behavior during

  14. Chemical compositions of four barium stars

    CERN Document Server

    Liang, Y C; Chen, Y Q; Qiu, H M; Zhang, B

    2003-01-01

    Chemical compositions of four barium stars HD 26886, HD 27271, HD 50082 and HD 98839 are studied based on high resolution, high signal-to-noise Echelle spectra. Results show that all of them are disk stars. Their \\alpha and iron peak elements are similar to the solar abundances. The neutron-capture process elements are overabundant relative to the Solar. The heavy-element abundances of the strong Ba star HD 50082 are higher than those of other three mild Ba stars. Its mass is 1.32Msun (+0.28,-0.22Msun), and is consistent with the average mass of strong Ba stars (1.5Msun). For mild Ba star HD 27271 and HD 26886, the derived masses are 1.90Msun (+0.25,-0.20Msun) and 2.78Msun (+0.75,-0.78M_sun), respectively, which are consistent with the average mass of mild Ba stars. We also calculate the theoretical abundances of Ba stars by combining the AGB stars nucleosynthesis and wind accretion formation scenario of Ba binary systems. The comparisons between the observed abundance patterns of the sample stars with the th...

  15. Measurement of cosmic ray chemical composition at Mt. Chacaltaya

    Energy Technology Data Exchange (ETDEWEB)

    Ogio, S.; Kakimoto, F.; Harada, D.; Tokunou, H.; Burgoa, O.; Tsunesada, Y. [Institute of Technology, Dept. of Physics, Tokuo (Japan); Shirasaki, Y. [National Space Development Agency of Japan, Tsukuba (Japan); Gotoh, E.; Nakatani, H.; Shimoda, S.; Nishi, K.; Tajima, N.; Yamada, Y. [The Institute of Physical and Chemical Research, Wako, Saitama (Japan); Kaneko, T. [Okayama University, Dept. of Physics, Oakayama (Japan); Matsubara, Y. [Nagoya University, Solar-Terrestrial Environment Laboratory, Nagoya, Aichi (Japan); Miranda, P.; Velarde, A. [Universidad Mayor de San Andres, Institute de Investigaciones Fisicas, La Paz (Bolivia); Mizumoto, T. [National Astronomical Observatory, Mitaka, Tokyo (Japan); Yoshii, H.; Morizawa, A. [Ehime University, Dept. of Physics, Matsuyama, Ehime (Japan); Murakami, K. [Nagoya University of Foreign Studies, Nissin, Aichi (Japan); Toyoda, Y. [Fukui University of Technology, Faculty of General Education, Fukui (Japan)

    2001-10-01

    BASJE group has measured the chemical composition of primary cosmic rays with energies around the knee with several methods. These measurements show that the averaged mass number of cosmic ray particles increases with energy up to the knee. In order to measure the chemical composition in much wider energy range, it was started a new experiment at Mt. Chacaltaya in 2000.

  16. Chemical migration in drinking water stored in polyethylene terephthalate (PET) bottles: a source of controversy

    OpenAIRE

    Bach, Cristina; Dauchy, Xavier; Chagnon, Marie-Christine; Etienne, Serge

    2012-01-01

    International audience; Due to its chemical inertness and physical properties PET is particularly suitable for food packaging applications, especially for drinking water. More bottled water is consumed than other bottled beverages. This article is a survey and toxicological investigation of chemical compounds, which are able to diffuse from PET bottles to water. The exact detailed chemical composition of plastic materials is known only from information provided by manufacturers. A declaration...

  17. Dynamics of the chemical composition of rainwater throughout Hurricane Irene

    Directory of Open Access Journals (Sweden)

    K. M. Mullaugh

    2013-03-01

    Full Text Available Sequential sampling of rainwater from Hurricane Irene was carried out in Wilmington, NC, USA on 26 and 27 August 2011. Eleven samples were analyzed for pH, major ions (Cl−, NO3−, SO42−, Na+, K+, Mg2+, Ca2+, NH4+, dissolved organic carbon (DOC and hydrogen peroxide (H2O2. Hurricane Irene contributed 16% of the total rainwater and 18% of the total chloride wet deposition received in Wilmington NC during all of 2011. This work highlights the main physical factors influencing the chemical composition of tropical storm rainwater: wind speed, wind direction, back trajectory and vertical mixing, time of day and total rain volume. Samples collected early in the storm, when winds blew out of the east, contained dissolved components indicative of marine sources (salts from sea spray and low DOC. The sea-salt components in the samples had two maxima in concentration during the storm the first of which occurred before the volume of rain had sufficiently washed out sea salt from the atmosphere and the second when back trajectories showed large volumes of marine surface air were lifted. As the storm progressed and winds shifted to a westerly direction, the chemical composition of the rainwater became characteristic of terrestrial storms (high DOC and NH4+ and low sea salt. This work demonstrates that tropical storms are not only responsible for significant wet deposition of marine components to land, but terrestrial components can also become entrained in rainwater, which can then be delivered to coastal waters via wet deposition. This study also underscores why analysis of one composite sample can lead to an incomplete interpretation of the factors that influence the chemically divergent analytes in rainwater during extreme weather events.

  18. THE STUDY OF CHEMICAL COMPOSITION FOR ANIMAL FATS DURING STORAGE

    OpenAIRE

    Flavia Pop; Cornel Laslo

    2009-01-01

    In this article the chemical composition for 3 types of animal fats (pork fat, beef tallow and buffalo tallow), following the variation of saturated and unsaturated fatty acids proportion during freezing storage was studied. Determination of chemical composition of animal fats is important in establishing organoleptic and physico-chemical parameters, the variation of them in time, nature and proportion of fatty acids conferring specific characteristics to them. For pork fat was determined the...

  19. Physico-chemical, microbiological and pharmacological stability of therapeutic mineral WATERs

    Directory of Open Access Journals (Sweden)

    Cosmoiu Madalina

    2012-09-01

    Full Text Available For a natural mineral water to be bottled and then sold as table water, besides some physicochemical characteristics that define it, must come from a natural source (spring, well, borehole with a high purity biological and microbiology.Most chemical compounds, expressed major elements, trace elements, gases, some undissociated compounds closely correlated with water temperature and pH they have a role in assessing qualitative characterization and classification of mineral waters.Variety composition of mineral water generated their many uses in both the therapeutic and the water table.Physico-chemical composition and microbiological indicators values for drinking must belong to a high degree of stability for certain periods of time.Degree of physical and chemical stability of mineral waters in general is closely related to chemical equilibrium achieved naturally when water does not undergo any transformation (being bottled just by adding carbon dioxide, or may undergo significant changes technological processes (deferizare, desulfurization, degassing, etc.

  20. Propolis chemical composition and honeybee resistance against Varroa destructor.

    Science.gov (United States)

    Popova, M; Reyes, M; Le Conte, Y; Bankova, V

    2014-01-01

    Propolis is known as honeybee chemical defence against infections and parasites. Its chemical composition is variable and depends on the specificity of the local flora. However, there are no data concerning the relationship between propolis chemical composition and honeybee colony health. We tried to answer this question, studying the chemical composition of propolis of bee colonies from an apiary near Avignon, which are tolerant to Varroa destructor, comparing it with colonies from the same apiary which are non-tolerant to the mites. The results indicated that non-tolerant colonies collected more resin than the tolerant ones. The percentage of four biologically active compounds - caffeic acid and pentenyl caffeates - was higher in propolis from tolerant colonies. The results of this study pave the way to understanding the effect of propolis in individual and social immunity of the honeybees. Further studies are needed to clarify the relationship between propolis chemical composition and honeybee colony health.

  1. Effect of chemical composition of sheep’s milk on the chemical composition of Livno and Travnik cheese

    Directory of Open Access Journals (Sweden)

    Amina Hrković

    2011-06-01

    Full Text Available Bosnia and Herzegovina has a centuries-old tradition in the family dairy products, among which 2-3 types of cheeses dominate. Well known dairy products in BiH are indigenous Livno and Travnik cheese, a group of cheeses produced from thermally untreated raw sheep milk. The aim of this study was assessing the effects of certain parameters on the chemical composition of the milk composition of indigenous cheeses - Livno and Travnik. Two manufacturers within two different locations (Livno and Travnik during summer grazing of sheep, were selected for this research. The study included 117sheep (Livno 57 sheep, Travnik 60 sheep. The cheese milk was used for determination of fat, protein and lactose content. Six samples were taken from obtained cheeses: 3 samples of Livno and 3samples of Travnik cheese, which means one for each sampling period. In cheese dry matter content, water, fat, fat in dry matter and acidity (pH were determined, and then correlation between the constituents of milk and cheese ingredients content was set. The most common causes of such phenomenon is non-standard production, storage and ripening. On Travnik area, the content of fat and milk protein varied according to sampling period, which can be attributed to the already mentioned diet and stage of lactation. At the same time the protein content decreased mainly by the end of lactating period. Lactose content has proven to be the most stable parameter of milk. In both investigated cheese samples slightly higher water content was found compared to normal values for these two local cheese, while the proportion of fat and dry matter varied within the sampling period. Variation of certain parameters of the chemical composition of investigated samples of Livno and Travnik cheese, as well as their correlation with parameters of milk is primarily a consequence of changing the chemical composition of milk as the basic raw materials and/or significant variations in technology that could

  2. Low-cost composites based on porous titania–apatite surfaces for the removal of patent blue V from water: Effect of chemical structure of dye

    Directory of Open Access Journals (Sweden)

    C. El Bekkali

    2016-11-01

    Full Text Available Hydroxyapatite/titania nanocomposites (TiHAp were synthesized from a mixture of a titanium alkoxide solution and dissolution products of a Moroccan natural phosphate. The simultaneous gelation and precipitation processes occurring at room temperature led to the formation of TiHAp nanocomposites. X-ray diffraction results indicated that hydroxyapatite and anatase (TiO2 were the major crystalline phases. The specific surface area of the nanocomposites increased with the TiO2 content. Resulting TiHAp powders were assessed for the removal of the patent blue V dye from water. Kinetic experiments suggested that a sequence of adsorption and photodegradation is responsible for discoloration of dye solutions. These results suggest that such hydroxyapatite/titania nanocomposites constitute attractive low-cost materials for the removal of dyes from industrial textile effluent.

  3. Rapid fabrication of ceramic composite tubes using chemical vapor infiltration

    Energy Technology Data Exchange (ETDEWEB)

    Starr, T.L.; Chiang, D. [Georgia Inst. of Tech., Atlanta, GA (United States). School of Materials Science and Engineering; Besmann, T.M.; Stinton, D.P.; McLaughlin, J.C.; Matlin, W.M. [Oak Ridge National Lab., TN (United States)

    1996-06-01

    Ceramic composite tubes can be fabricated with silicon carbide matrix and Nicalon fiber reinforcement using forced flow-thermal gradient chemical vapor infiltration (FCVI). The process model GTCVI is used to design the equipment configuration and to identify conditions for rapid, uniform densification. The initial injector and mandrel design produced radial and longitudinal temperature gradients too large for uniform densification. Improved designs have been evaluated with the model. The most favorable approach utilizes a free-standing preform and an insulated water-cooled gas injector. Selected process conditions are based on the temperature limit of the fiber, matrix stoichiometry and reagent utilization efficiency. Model runs for a tube 12 inches long, 4 inches OD and 1/4 inch wall thickness show uniform densification in approximately 15 hours.

  4. CHEMICAL COMPOSITION FROM THE DNIESTER RIVER TRIBUTARIES

    Directory of Open Access Journals (Sweden)

    V. Gladchi

    2013-06-01

    Full Text Available This article presents the results obtained in the framework of the project 09.832.08.06A. The role of the tributaries on formation of the Dniester river water and the study of the waters quality of sources / fountains in the catchment area of the Dniester river as sources of water supply and for irrigation in the State Program, Scientific Researches and of the management of waters quality.

  5. Super water repellent finishing technology by simulating bio-structures. Improvement of chemical durability by super water repellent finishing of hydroxy- apatite/titan composite films prepared by high-frequency plasma arc spraying; Seibutsu no kozo wo mohoshita chohassuika gijutsu. Koshuha plasma yoshaho ni yori sakuseishita suisan apataito/chitan fukugo himaku no chohassuika ni yoru kagakuteki taikyusei no kojo

    Energy Technology Data Exchange (ETDEWEB)

    Hozumi, A.; Inagaki, M.; Okuderaa, H.; Nishizawa, K.; Nagata, F.; Teraoka, H.; Yokogawa, Y.; Kameyama, T. [National Industrial Research Institute of Nagoya, Nagoya (Japan)

    2000-08-25

    Artificial joint and tooth root produced by coating hydroxy- apatite (HA) onto Ti alloy base surface by DC plasma torch arc spraying in commercially available in Europe, and have been used for persons not less than 100,000 since 1985. However, peeling and dissolution of coats after implant have been reported as a serious problem. The long-term stability of coats is dependent on the chemical durability of coats. Paying attention to physical structure of HA/Ti composite film surface. this study attempted super water repellent finishing of the surface through reduction of surface energy by chemical modification of the surface in a molecular level. Self-organization single-molecule film of organic silane compound with perfluoroalkyl group was formed by CVD on the HA/Ti composite film surface prepared on Ti alloy by high- frequency plasma arc spraying. The extremely hydrophobic HA/Ti composite film with a contact angle ranging 130-160 degrees was thus obtained from the highly hydrophilic coat. This sample showed a very high chemical durability as compared with conventional ones. (NEDO)

  6. WATER-BLOWN POLYURETHANE RIGID FOAMS MODIFIED BY CHEMICAL PLASTICATION

    Institute of Scientific and Technical Information of China (English)

    YU Ming; XU Qiang

    2006-01-01

    Water-blown polyurethane rigid foams are getting more and more attention, because the traditional blowing agent HCFC141b has already been abolished to prevent the ozone layer from destruction. However, the polyurethane rigid foams blown by water have serious defects, i.e. friability and resulting lower adhesion strength. Thus, the purpose of this study is to resolve the problems by chemical plastication. The maleate was added to polyol-premix containing water or to polyisocyanate,with both of which maleate does not react. To prove the reaction when polyol-premix and polyisocyanate were mixed, the model composite was synthesized and analyzed by IR, NMR and ESI (MS). Furthermore, a series of water-blown polyurethane rigid foams added different amount maleate were successfully prepared. By testing impact strength and adhesion strength of the foams, the actual effect of adding maleate was obtained.

  7. The relation between water fluoride and other chemical composition i n water of Nan-shui-bei-diao middle line areas in Hebei province%河北省南水北调饮水含氟量及化学成分的调查

    Institute of Scientific and Technical Information of China (English)

    马景; 陶跃华; 乔淑田; 章和平; 梁索理; 王海森; 姚光俊; 董振军; 程溆; 李桂云; 师贵文

    2001-01-01

    目的 探讨河北省南水北调中 线供水区饮水氟含量与水质其它化学成分的关系及对地氟病的影响。方法 按南水北调中线供水区地方性氟中毒调查实施方案 要求,对51个重点村采集的近、中、远水样进行水氟含量与水总硬度、水总碱度、pH、水碘等化学成分的测定分析。 结果 南水北调中线供水区水氟含量与水的硬度呈负相关,与水的总碱度、水碘含量呈正相关。结论 南水北调中线供水区水氟与水质中其它化学成分有关,对地氟病有一定影响。%Objective To study the relation between water fluoride and other chemical composition in water of Nan-shui-bei-diao middle line areas in Hebei and the effect to the endemic fluorosis. Methods Collected specimen of water in region of Nan-s hui-bei-diao to detect water fluoride,total hardness in water,total alkalinity in water and pH with chemical experiments.Results There is a positive correlation between the con centration of water fluoride and that of the total alkalinity and a negative cor relation between the water fluoride and the total hardness and water iodine. Conclusions The results showed that in the Nan-shui-b ei-diao middle line areas the water fluoride and other chemical composition have acertain effect on endemic fluorosis.

  8. Physio-chemical, mineral composition and antioxidant properties of ...

    African Journals Online (AJOL)

    Physio-chemical, mineral composition and antioxidant properties of Roselle ... The roselle extract has a unique red colour, good flavour, low sugar and high acidic ... human body from several diseases attributed to the reactions of free radicals.

  9. Chemical composition and antioxidant activity of essential oil ...

    African Journals Online (AJOL)

    LACPREENE

    2012-08-12

    Aug 12, 2012 ... The chemical composition of C. ladanifer essential oil was characterized by high ... Analysis of essential oils was carried out by GC–MS using a .... with literature shows important qualitative and quantita- tive differences in ...

  10. Chemical composition and antifungal activity of essential oils of ...

    African Journals Online (AJOL)

    patrick

    2015-03-25

    Mar 25, 2015 ... chemical composition of the species of Algerian citrus. (Baaliouamer, 1987). ... Osbeck), Bigaradier (Citrus aurantium), lemon (Citrus limonum) and ..... The fungi anti capacities of essential oils of the Algerian citrus proved to ...

  11. Mechanical and Chemical Properties of Bamboo/Glass Fibers Reinforced Polyester Composites

    Directory of Open Access Journals (Sweden)

    K.Sudha Madhuri,

    2016-01-01

    Full Text Available The chemical resistance of Bamboo/Glass reinforced Polyester hybrid composites to acetic acid, Nitric acid, Hydrochloric acid, Sodium hydroxide, Sodium carbonate, Benzene, Toluene, Carbon tetrachloride and Water was studied. The tensile and impact properties of these composites were also studied. The effect of alkali treatment of bamboo fibers on these properties was studied. It was observed that the tensile and impact properties of the hybrid composites increase with glass fiber content. The author investigated the interfacial bonding between Glsss/Bamboo fiber composites by SEM. These properties found to be higher when alkali treated bamboo fibers were used in hybrid composites. The hybrid fiber composites showed better resistance to the chemicals mentioned above. The elimination of amorphous hemi-cellulose with alkali treatment leading to higher crystallinity of the bamboo fibers with alkali treatment may be responsible for these observations.

  12. Chemical composition of upper crust in eastern China

    Institute of Scientific and Technical Information of China (English)

    鄢明才; 迟清华; 顾铁新; 王春书

    1997-01-01

    In an area of 3. 3 ×106 km" within eastern China, 28 253 rock samples were collected systematically and combined into 2 718 composite samples which were analyzed by 15 reliable methods using national preliminary certified reference materials (CRMs) for data quality monitoring. The average chemical compositions of the exposed crust, the sedimentary cover and the exposed basement as well as the upper crust for 76 chemical elements in eastern China are given.

  13. Honey: Chemical composition, stability and authenticity.

    Science.gov (United States)

    da Silva, Priscila Missio; Gauche, Cony; Gonzaga, Luciano Valdemiro; Costa, Ana Carolina Oliveira; Fett, Roseane

    2016-04-01

    The aim of this review is to describe the chemical characteristics of compounds present in honey, their stability when heated or stored for long periods of time and the parameters of identity and quality. Therefore, the chemical characteristics of these compounds were examined, such as sugars, proteins, amino acids, enzymes, organic acids, vitamins, minerals, phenolic and volatile compounds present in honey. The stability of these compounds in relation to the chemical reactions that occur by heating or prolonged storage were also discussed, with increased understanding of the behavior regarding the common processing of honey that may compromise its quality. In addition, the identity and quality standards were described, such as sugars, moisture, acidity, ash and electrical conductivity, color, 5-HMF and diastase activity, along with the minimum and maximum limits established by the Codex Alimentarius.

  14. Software for analysis of chemical mixtures--composition, occurrence, distribution, and possible toxicity

    Science.gov (United States)

    Scott, Jonathon C.; Skach, Kenneth A.; Toccalino, Patricia L.

    2013-01-01

    The composition, occurrence, distribution, and possible toxicity of chemical mixtures in the environment are research concerns of the U.S. Geological Survey and others. The presence of specific chemical mixtures may serve as indicators of natural phenomena or human-caused events. Chemical mixtures may also have ecological, industrial, geochemical, or toxicological effects. Chemical-mixture occurrences vary by analyte composition and concentration. Four related computer programs have been developed by the National Water-Quality Assessment Program of the U.S. Geological Survey for research of chemical-mixture compositions, occurrences, distributions, and possible toxicities. The compositions and occurrences are identified for the user-supplied data, and therefore the resultant counts are constrained by the user’s choices for the selection of chemicals, reporting limits for the analytical methods, spatial coverage, and time span for the data supplied. The distribution of chemical mixtures may be spatial, temporal, and (or) related to some other variable, such as chemical usage. Possible toxicities optionally are estimated from user-supplied benchmark data. The software for the analysis of chemical mixtures described in this report is designed to work with chemical-analysis data files retrieved from the U.S. Geological Survey National Water Information System but can also be used with appropriately formatted data from other sources. Installation and usage of the mixture software are documented. This mixture software was designed to function with minimal changes on a variety of computer-operating systems. To obtain the software described herein and other U.S. Geological Survey software, visit http://water.usgs.gov/software/.

  15. Chemical changes associated with lotus and water lily natto production

    Science.gov (United States)

    Lestari, S. D.; Fatimah, N.; Nopianti, R.

    2017-04-01

    Natto is a traditional Japanese food made by fermenting whole soybean seeds with pure culture of Bacillus subtilis subsp. natto. The purpose of this study was to investigate the suitability of lotus (Nelumbo nucifera) and water lily (Nymphaea stellata) seeds as the raw materials for natto production. Chemical (proximate, amino acids and minerals) changes were observed on raw, steamed and fermented seeds. Proximate compositions of all samples were calculated in both wet basis and dry basis. In wet basis calculation, steaming and fermentation tended to lower the carbohydrates, ashes, fats and protein content which were attributed to the increase of moisture. The total amino acid, iron and magnesium contents of raw lotus seeds were 24.29%, 5.08 mg 100g-1 and 174.23 mg 100g-1 dry matter, respectively. After a 24h-fermentation at 40°C, the total amino acids decreased while iron and magnesium contents increased significantly reaching, in respective order, 9.9 mg 100g-1 and 411.36 mg 100g-1 dry matter. Changes in chemical composition after fermentation were more pronounced in lotus seeds than water lily seeds indicating that their nutrient composition were more suitable to support Bacillus subtilis growth.

  16. Chemical composition of the early universe

    NARCIS (Netherlands)

    Harwit, M; Spaans, M

    2003-01-01

    A prediction of standard inflationary cosmology is that the elemental composition of the medium out of which the earliest stars and galaxies condensed consisted primarily of hydrogen and helium (4)He, with small admixtures of deuterium, lithium (7)Li, and (3)He. The most redshifted quasars,

  17. The chemical composition of the Galileian satellites

    CERN Document Server

    Celebonovic, V

    1998-01-01

    Using the semiclassical theory of dense matter proposed by P.Savic and R.Kasanin,the mean molecular masses of the Galilean satellites of Jupiter are determined.The calculated values are fitted by plausible combinations of chemical elements,and the results are in good agreement with the observations by "Galileo".Possible cosmogonical explanations are briefly discussed.

  18. Numerical modeling of a compositional flow for chemical EOR and its stability analysis

    NARCIS (Netherlands)

    Druetta, P.; Yue, J.; Tesi, P.; De Persis, C.; Picchioni, F.

    A new two-dimensional surfactant flooding simulator for a three-component (water, petroleum, chemical), two-phase (aqueous, oleous) system in porous media is developed and analyzed. The compositional physical model is governed by a system of non-linear partial differential equations composed of

  19. Numerical modeling of a compositional flow for chemical EOR and its stability analysis

    NARCIS (Netherlands)

    Druetta, P.; Yue, J.; Tesi, P.; De Persis, C.; Picchioni, F.

    2017-01-01

    A new two-dimensional surfactant flooding simulator for a three-component (water, petroleum, chemical), two-phase (aqueous, oleous) system in porous media is developed and analyzed. The compositional physical model is governed by a system of non-linear partial differential equations composed of Darc

  20. Chemical modification of flax reinforced polypropylene composites

    CSIR Research Space (South Africa)

    Jacob John, Maya

    2009-04-01

    Full Text Available ) and ∆Ea is the activation energy for the relaxation. The slope of Arrhenius plot obtained by plotting log f versus 1/T will give the activation energy for that process. Table 3 presents the activation energy of the composites and it can be observed... at the temperature where the loss modulus is maximum indicating a relaxation phenomenon. The increase in loss modulus is attributed to the increase in energy absorption caused by the addition of fibres. 5.4.1.3 Mechanical damping factor (tan δ) Page 9 of 26...

  1. Cometary coma chemical composition (C4) mission. [Abstract only

    Science.gov (United States)

    Carle, G. C.; Clark, B. C.; Niemann, H. B.; Alexander, M.; Knocke, P. C.; O'Hara, B. J.

    1994-01-01

    Cometary missions are of enormous fundamental importance for many different space science disciplines, including exobiology. Comets are presumed relics of the earliest, most primitive material in the solar nebula and are related to the planetesimals. They undoubtedly provided a general enrichment of volatiles to the inner solar system (contributing to atmospheres and oceans) and may have been key to the origin of life. A Discovery class, comet rendezvous mission, the Cometary Coma Chemical Composition (C4) Mission, was selected for further study by NASA earlier this year. The C4 Mission is a highly focused and usefully-limited subset of the Cometary Rendezvous Asteroid Flyby (CRAF) Mission, concentrating exclusively on measurements which will lead to an understanding of the chemical composition and make-up of the cometary nucleus. The scientific goals of the Cometary Coma Chemical Composition (C4) Mission are to rendezvous with a short-period comet and (1) to determine the elemental, chemical, and isotopic composition of the nucleus and (2) to characterize the chemical and isotopic nature of its atmosphere. Further, it is a goal to obtain preliminary data on the development of the coma (dust and gas composition) as a function of time and orbital position.

  2. Chemical composition of Hanford Tank SY-102

    Energy Technology Data Exchange (ETDEWEB)

    Birnbaum, E.; Agnew, S.; Jarvinen, G.; Yarbro, S.

    1993-12-01

    The US Department of Energy established the Tank Waste Remediation System (TWRS) to safely manage and dispose of the radioactive waste, both current and future, stored in double-shell and single-shell tanks at the Hanford sites. One major program element in TWRS is pretreatment which was established to process the waste prior to disposal using the Hanford Waste Vitrification Plant. In support of this program, Los Alamos National Laboratory has developed a conceptual process flow sheet which will remediate the entire contents of a selected double-shelled underground waste tank, including supernatant and sludge, into forms that allow storage and final disposal in a safe, cost-effective and environmentally sound manner. The specific tank selected for remediation is 241-SY-102 located in the 200 West Area. As part of the flow sheet development effort, the composition of the tank was defined and documented. This database was built by examining the history of liquid waste transfers to the tank and by performing careful analysis of all of the analytical data that have been gathered during the tank`s lifetime. In order to more completely understand the variances in analytical results, material and charge balances were done to help define the chemistry of the various components in the tank. This methodology of defining the tank composition and the final results are documented in this report.

  3. Passive sampling of perfluorinated chemicals in water: Flow rate effects on chemical uptake

    NARCIS (Netherlands)

    Kaserzon, S.L.; Vermeirssen, E.L.M.; Hawker, D.W.; Kennedy, K.; Bentley, C.; Thompson, J.; Booij, K.; Mueller, J.F.

    2013-01-01

    A recently developed modified polar organic chemical integrative sampler (POCIS) provides a means for monitoring perfluorinated chemicals (PFCs) in water. However, changes in external flow rates may alter POCIS sampling behaviour and consequently affect estimated water concentrations of analytes. In

  4. The chemical composition of mineral trioxide aggregate

    Directory of Open Access Journals (Sweden)

    Camilleri Josette

    2008-01-01

    Full Text Available Mineral trioxide aggregate (MTA is composed of Portland cement, with 4:1 addition of bismuth oxide added so that the material can be detected on a radiograph. The cement is made up of calcium, silicon and aluminium. The main constituent phases are tricalcium and dicalcium silicate and tricalcium aluminate. There are two commercial forms of MTA, namely the grey and the white. The difference between the grey and the white materials is the presence of iron in the grey material, which makes up the phase tetracalcium alumino-ferrite. This phase is absent in white MTA. Hydration of MTA occurs in two stages. The initial reaction between tricalcium aluminate and water in the presence of calcium sulphate results in the production of ettringite. Tricalcium and dicalcium silicate react with water to produce calcium silicate hydrate and calcium hydroxide, which is leached out of the cement with time.

  5. Inorganic chemical composition and chemical reactivity of settled dust generated by the World Trade Center building collapse: Chapter 12

    Science.gov (United States)

    Plumlee, Geoffrey S.; Hageman, Philip L.; Lamothe, Paul J.; Ziegler, Thomas L.; Meeker, Gregory P.; Theodorakos, Peter M.; Brownfield, Isabelle; Adams, Monique G.; Swayze, Gregg A.; Hoefen, Todd M.; Taggart, Joseph E.; Clark, Roger N.; Wilson, S.; Sutley, Stephen J.

    2009-01-01

    Samples of dust deposited around lower Manhattan by the September 11, 2001, World Trade Center (WTC) collapse have inorganic chemical compositions that result in part from the variable chemical contributions of concrete, gypsum wallboard, glass fibers, window glass, and other materials contained in the buildings. The dust deposits were also modified chemically by variable interactions with rain water or water used in street washing and fire fighting. Chemical leach tests using deionized water as the extraction fluid show the dust samples can be quite alkaline, due primarily to reactions with calcium hydroxide in concrete particles. Calcium and sulfate are the most soluble components in the dust, but many other elements are also readily leached, including metals such as Al, Sb, Mo Cr, Cu, and Zn. Indoor dust samples produce leachates with higher pH, alkalinity, and dissolved solids than outdoor dust samples, suggesting most outdoor dust had reacted with water and atmospheric carbon dioxide prior to sample collection. Leach tests using simulated lung fluids as the extracting fluid suggest that the dust might also be quite reactive in fluids lining the respiratory tract, resulting in dissolution of some particles and possible precipitation of new phases such as phosphates, carbonates, and silicates. Results of these chemical characterization studies can be used by health scientists as they continue to track and interpret health effects resulting from the short-term exposure to the initial dust cloud and the longer-term exposure to dusts resuspended during cleanup.

  6. Inorganic chemical composition and chemical reactivity of settled dust generated by the World Trade Center building collapse

    Science.gov (United States)

    Plumlee, Geoffrey S.; Hageman, Philip L.; Lamothe, Paul J.; Ziegler, Thomas L.; Meeker, Gregory P.; Theodorakos, Peter M.; Brownfield, Isabelle; Adams, Monique G.; Swayze, Gregg A.; Hoefen, Todd M.; Taggart, Joseph E.; Clark, Roger N.; Wilson, S.; Sutley, Stephen J.

    2009-01-01

    Samples of dust deposited around lower Manhattan by the September 11, 2001, World Trade Center (WTC) collapse have inorganic chemical compositions that result in part from the variable chemical contributions of concrete, gypsum wallboard, glass fibers, window glass, and other materials contained in the buildings. The dust deposits were also modified chemically by variable interactions with rain water or water used in street washing and fire fighting. Chemical leach tests using deionized water as the extraction fluid show the dust samples can be quite alkaline, due primarily to reactions with calcium hydroxide in concrete particles. Calcium and sulfate are the most soluble components in the dust, but many other elements are also readily leached, including metals such as Al, Sb, Mo Cr, Cu, and Zn. Indoor dust samples produce leachates with higher pH, alkalinity, and dissolved solids than outdoor dust samples, suggesting most outdoor dust had reacted with water and atmospheric carbon dioxide prior to sample collection. Leach tests using simulated lung fluids as the extracting fluid suggest that the dust might also be quite reactive in fluids lining the respiratory tract, resulting in dissolution of some particles and possible precipitation of new phases such as phosphates, carbonates, and silicates. Results of these chemical characterization studies can be used by health scientists as they continue to track and interpret health effects resulting from the short-term exposure to the initial dust cloud and the longer-term exposure to dusts resuspended during cleanup.

  7. Chemical composition and functional properties of starch extracted from the pejibaye fruit (Bactris gasepaes Kunth.

    Directory of Open Access Journals (Sweden)

    Biano Alves de Melo Neto

    2015-01-01

    Full Text Available This study aimed to establish the chemical composition and functional properties of the starch extracted from the pejibaye fruit (Bactris gasepaes Kunth.. The chemical characterization was evaluated from the determination of starch, amylose, amylopectin, total lipid, protein, ash, moisture and water activity. The water absorption index and the water solubility index were calculated for temperatures between 25 and 90ºC. Low contents of ash and protein were found. The studied starch has 14% moisture, according to the established by law. The water activity value was 0.55, which ensures its microbiological stability. A range of gelatinization between 65 to 70ºC was observed, close to the one of commercial starches. The solubility rate in water was 0.6119% and the absorption rate in water was 1.8252%. These results demonstrated that the starch from the pejibaye fruit has important characteristics for use in the food industry.

  8. Composição quali-quantitativa da produção de 'Syrah' cultivada sob estresse hídrico transiente Composition and chemical-sensorial profile of 'Syrah' cultivated under transient water stress

    Directory of Open Access Journals (Sweden)

    Antonio O. Santos

    2009-06-01

    Full Text Available A produção de vinho de qualidade requer o cultivo de uvas de padrão superior, com características químicas e físicas favoráveis, resultantes das condições micrometeorológicas locais, da variedade e do manejo do solo e da cultura. A composição quantitativa e qualitativa do rendimento da videira pode ser responsiva à variação na lâmina de irrigação e ao sistema de poda utilizado. Doravante, a interação entre os dois fatores citados e o meio físico circundante foi mostrada ser influente na qualidade do vinho. Um experimento foi conduzido com uva vinífera nas estações de crescimento de 2003 a 2005; cujo objetivo foi determinar a melhor combinação entre sistemas de poda (manual e mecânica e manejo da água, para a produção de vinho de 'Syrah' (Vitis vinifera L. cultivada em condições de microclima quente e seco. Os resultados mostraram que a composição do rendimento foi consistentemente afetada pelo sistema de poda, enquanto o melhor perfil aromático foi observado para 'Syrah', cultivada sob poda mecânica e estresse hídrico baixo a moderado.The production of a quality wine depends on the cultivation of high quality grapes with favorable chemical and physical characteristics, which result from the submitted micrometeorological regime, variety and soil-plant management. Grape yield and quality performance can be responsive to varying levels of water depth and the pruning system. The interaction between these two factors and the surrounding environment has been proved to be influential upon the wine quality. An experiment was carried out with wine grapes through the growing seasons of 2003 to 2005. The objective was to determine the best combination of pruning (manual and mechanized and irrigation practices on 'Syrah' (Vitis vinifera L. envisaging wine quality achievement, under a hot and dry microclimate. Results showed that the grape composition was consistently affected by the pruning system whereas the best aroma

  9. Major element chemical compositions of chondrules in unequilibrated chondrites

    Science.gov (United States)

    Ikeda, Y.

    1984-01-01

    The chemical compositions (except for metals and sulfides in chondrules) of more than 500 chondrules from unequilibrated E, H, L, LL, and C chondrites were measured using a broad beam of an electron-probe microanalyzer. The compositions of chondrules can be represented by various mixtures of normative compositions of olivine, low-Ca pyroxene, plagioclase, and high-Ca pyroxene with minor amounts of spinel, feldspathoid, SiO2-minerals, etc., indicating that the chondrule precursor materials consisted of aggregates of these minerals. The Al, Na, and K contents of most chondrules reflect the compositions of the ternary feldspar (An-Ab-Kf) of the chondrule precursor materials, and chemical types of chondrules (KF, SP, IP, and CP) are defined on the basis of the atomic proportion of Al, Na, and K.

  10. Chemical composition analysis and authentication of whisky.

    Science.gov (United States)

    Wiśniewska, Paulina; Dymerski, Tomasz; Wardencki, Waldemar; Namieśnik, Jacek

    2015-08-30

    Whisky (whiskey) is one of the most popular spirit-based drinks made from malted or saccharified grains, which should mature for at least 3 years in wooden barrels. High popularity of products usually causes a potential risk of adulteration. Thus authenticity assessment is one of the key elements of food product marketing. Authentication of whisky is based on comparing the composition of this alcohol with other spirit drinks. The present review summarizes all information about the comparison of whisky and other alcoholic beverages, the identification of type of whisky or the assessment of its quality and finally the authentication of whisky. The article also presents the various techniques used for analyzing whisky, such as gas and liquid chromatography with different types of detectors (FID, AED, UV-Vis), electronic nose, atomic absorption spectroscopy and mass spectrometry. In some cases the application of chemometric methods is also described, namely PCA, DFA, LDA, ANOVA, SIMCA, PNN, k-NN and CA, as well as preparation techniques such SPME or SPE.

  11. The importance of water quality and haemodialysis fluid composition.

    Science.gov (United States)

    Hoenich, Nicholas A; Ronco, Claudio; Levin, Robert

    2006-01-01

    Treatment of renal failure by haemodialysis uses dialysis fluid to facilitate the normalization of electrolyte and acid base abnormalities and the removal of low molecular weight uraemic compounds present in the plasma such as urea. The dialysis fluid is a continuously produced blend of treated tap water and a concentrated solution containing electrolytes, buffer, and glucose. The water used originates as drinking water but undergoes additional treatment. Recent surveys have indicated that the chemical and microbiological content of such water frequently fails to meet the requirements of established standards, and its bacterial content arising from the presence of a biofilm in the water distribution network or the hydraulic circuit of the dialysis machine is a contributory factor to the chronic inflammatory state in patients undergoing regular dialysis. The composition of the dialysis fluid plays an important role in the modulation of complications associated with end-stage renal disease, as well as those associated with the treatment itself. The avoidance of complications arising from water contaminants requires a constant and vigorous attention to water quality, whilst with the composition of electrolytes and buffer there is a trend towards greater individualization to provide a high degree of treatment tolerance.

  12. Fuel options from microalgae with representative chemical compositions

    Energy Technology Data Exchange (ETDEWEB)

    Feinberg, D. A.

    1984-07-01

    Representative species of microalgae are examined with respect to their reported chemical compositions. Each species is analyzed under a variety of culture conditions, with the objective being to characterize an optimum mixture of fuel products (e.g., methane, ethanol, methylester) which should be produced by the particular species. Historically the emphasis has been on the entire algal cell mass. Using the reported chemical composition for the representative species under specific sets of growth conditions, some conclusions can be drawn about the preferred fuel product conversion routes that could be employed. 10 references, 7 figures, 12 tables.

  13. Porosity prediction of calcium phosphate cements based on chemical composition.

    Science.gov (United States)

    Öhman, Caroline; Unosson, Johanna; Carlsson, Elin; Ginebra, Maria Pau; Persson, Cecilia; Engqvist, Håkan

    2015-07-01

    The porosity of calcium phosphate cements has an impact on several important parameters, such as strength, resorbability and bioactivity. A model to predict the porosity for biomedical cements would hence be a useful tool. At the moment such a model only exists for Portland cements. The aim of this study was to develop and validate a first porosity prediction model for calcium phosphate cements. On the basis of chemical reaction, molar weight and density of components, a volume-based model was developed and validated using calcium phosphate cement as model material. 60 mol% β-tricalcium phosphate and 40 mol% monocalcium phosphate monohydrate were mixed with deionized water, at different liquid-to-powder ratios. Samples were set for 24 h at 37°C and 100% relative humidity. Thereafter, samples were dried either under vacuum at room temperature for 24 h or in air at 37 °C for 7 days. Porosity and phase composition were determined. It was found that the two drying protocols led to the formation of brushite and monetite, respectively. The model was found to predict well the experimental values and also data reported in the literature for apatite cements, as deduced from the small absolute average residual errors (brushite, monetite and apatite cements. The model gives a good estimate of the final porosity and has the potential to be used as a porosity prediction tool in the biomedical cement field.

  14. Chemical compositions of precipitation and scavenging of particles in Beijing

    Institute of Scientific and Technical Information of China (English)

    HU Min; ZHANG Jing; WU Zhijun

    2005-01-01

    Totally 23 precipitation samples were collected in Beijing from May to November in 2003. In order to investigate the chemical composition of precipitation samples, pH, conductivity, concentrations of water-soluble ions and organic acids were analyzed. The average pH of precipitations is 6.18, belonging to the neutral range; the average conductivity is 52.23 (S/cm, which indicates that precipitations in Beijing are obviously polluted; are the most abundant anions with the average concentrations of 521 and 174 μeq·L-1, respectively; the average equivalent ratio is 3.1, which decreases by about 15% compared with the result of 1994; and Ca2+ are the most abundant cations with the average concentrations of 376 and 397 μeq·L-1, respectively; formic acid, acetic acid and oxalic acid are the main organic acids with the average concentrations of 4.62, 4.60 and 1.17 μeq·L-1, respectively, accounting for 2% of the overall anions. Obvious differences between concentrations before and after precipitation are also observed by SJAC (Steam Jet Aerosol Collector), which shows the removal of particles from the atmosphere by precipitation.

  15. Probabilistic thermo-chemical analysis of a pultruded composite rod

    NARCIS (Netherlands)

    Baran, Ismet; Tutum, Cem C.; Hattel, Jesper H.

    2012-01-01

    In the present study the deterministic thermo-chemical pultrusion simulation of a composite rod taken from the literature [7] is used as a validation case. The predicted centerline temperature and cure degree profiles of the rod match well with those in the literature [7]. Following the validation c

  16. Probabilistic thermo-chemical analysis of a pultruded composite rod

    DEFF Research Database (Denmark)

    Baran, Ismet; Tutum, Cem Celal; Hattel, Jesper Henri

    2012-01-01

    In the present study the deterministic thermo-chemical pultrusion simulation of a composite rod taken from the literature [7] is used as a validation case. The predicted centerline temperature and cure degree profiles of the rod match well with those in the literature [7]. Following the validation...

  17. An investigation into the chemical composition of alternative invertebrate prey

    NARCIS (Netherlands)

    Oonincx, D.G.A.B.; Dierenfeld, E.S.

    2012-01-01

    The aim of this study was to determine the chemical composition of eight invertebrate species and evaluate their suitability as alternative prey. The species selected were rusty red cockroaches (Blatta lateralis), six-spotted cockroaches (Eublaberus distanti), Madagascar hissing cockroaches (Grompha

  18. Composition and Thermodynamic Properties of Air in Chemical Equilibrium

    Science.gov (United States)

    Moeckel, W E; Weston, Kenneth C

    1958-01-01

    Charts have been prepared relating the thermodynamic properties of air in chemical equilibrium for temperatures to 15,000 degrees k and for pressures 10(-5) to 10 (plus 4) atmospheres. Also included are charts showing the composition of air, the isentropic exponent, and the speed of sound. These charts are based on thermodynamic data calculated by the National Bureau of Standards.

  19. Physico-Chemical, Functional and Rheological Characterization of Biodegradable Pellets and Composite Sheets

    Directory of Open Access Journals (Sweden)

    Jan Kulsum

    2016-01-01

    Full Text Available Deoiled rice bran, paddy husk, cashew nut shell liquid and glycerol were extruded into pellets and further pressed into composites. Processing and plasticizer type had significant effect on physico-chemical, functional, rheological and morphological properties of pellets and composites. Specific mechanical energy of the pellets containing cashew nut shell liquid as plasticizer was higher than those containing glycerol. The maximum hardness and bulk density were obtained for pellets prepared from cashew nut shell liquid. Water binding capacity and water solubility index of both pellets and composites were highest for samples containing glycerol as plasticizer. A significant change in functional properties during processing was observed among raw materials, pellets and the final product (composite sheets.

  20. Determination of the chemical composition of human renal stones with MDCT: influence of the surrounding media

    Science.gov (United States)

    Grosjean, Romain; Sauer, Benoît; Guerra, Rui; Kermarrec, Isabelle; Ponvianne, Yannick; Winninger, Daniel; Daudon, Michel; Blum, Alain; Felblinger, Jacques; Hubert, Jacques

    2007-03-01

    The selection of the optimal treatment method for urinary stones diseases depends on the chemical composition of the stone and its corresponding fragility. MDCT has become the most used modality to determine rapidly and accurately the presence of stones when evaluating urinary lithiasis treatment. That is why several studies have tempted to determine the chemical composition of the stones based on the stone X-ray attenuation in-vitro and invivo. However, in-vitro studies did not reproduce the normal abdominal wall and fat, making uncertain the standardization of the obtained values. The aim of this study is to obtain X-ray attenuation values (in Hounsfield Units) of the six more frequent types of human renal stones (n=217) and to analyze the influence of the surrounding media on these values. The stones were first placed in a jelly, which X-ray attenuation is similar to that of the human kidney (30 HU at 120 kV). They were then stuck on a grid, scanned in a water tank and finally scanned in the air. Significant differences in CT-attenuation values were obtained with the three different surrounding media (jelly, water, air). Furthermore there was an influence of the surrounding media and consequently discrepancies in determination of the chemical composition of the renal stones. Consequently, CT-attenuation values found in in-vitro studies cannot really be considered as a reference for the determination of the chemical composition except if the used phantom is an anthropomorphic one.

  1. Interpreting chemical compositions of small scale basaltic systems: A review

    Science.gov (United States)

    McGee, Lucy E.; Smith, Ian E. M.

    2016-10-01

    Small scale basaltic magmatic systems occur in all of the major tectonic environments of planet Earth and are characteristically expressed at the Earth's surface as fields of small monogenetic cones. The chemical compositions of the materials that make up these cones reflect processes of magma generation and differentiation that occur in their plumbing system. The volumes of magmas involved are very small and significantly their compositional ranges reveal remarkably complex processes which are overwhelmed or homogenized in larger scale systems. Commonly, compositions are basaltic, alkalic and enriched in light rare earth elements and large ion lithophile elements, although the spectrum extends from highly enriched nephelinites to subalkalic and tholeiitic basalts. Isotopic analyses of rocks from volcanic fields almost always display compositions which can only be explained by the interaction of two or more mantle sources. Ultimately their basaltic magmas originate by small scale melting of mantle sources. Compositional variety is testament to melting processes at different depths, a range of melting proportions, a heterogeneous source and fractionation, magma mixing and assimilation within the plumbing system that brings magmas to the surface. The fact that such a variety of compositions is preserved in a single field shows that isolation of individual melting events and their ascent is an important and possibly defining feature of monogenetic volcanism, as well as the window their chemical behavior provides into the complex process of melt generation and extraction in the Earth's upper mantle.

  2. A facile TiO2/PVDF composite membrane synthesis and their application in water purification

    Science.gov (United States)

    Zhang, Wei; Zhang, Yiming; Fan, Rong; Lewis, Rosmala

    2016-01-01

    In this work, we have demonstrated a facile wet chemical method to synthesise TiO2/PVDF composite membranes as alternative water purification method to traditional polymer-based membrane. For the first time, hydrothermally grown TiO2 nanofibers under alkali conditions were successfully inserted into PVDF membranes matrix. The structure, permeability and anti-fouling performance of as-prepared PVDF/TiO2 composite membranes were studied systematically. The TiO2/PVDF composite membranes prepared in this work promise great potential uses in water purification applications as microfiltration membranes due to its excellent physical/chemical resistance, anti-fouling and mechanical properties.

  3. Surface chemical composition analysis of heat-treated bamboo

    Science.gov (United States)

    Meng, Fan-dan; Yu, Yang-lun; Zhang, Ya-mei; Yu, Wen-ji; Gao, Jian-min

    2016-05-01

    In this study, the effect of heat treatment on the chemical composition of bamboo slivers was studied. The chemical properties of the samples were examined by chemical analysis. Results showed a decrease in the contents of holocellulose and α-cellulose, as well as an increase in the contents of lignin and extractives. Changes in the chemical structure of bamboo components were analyzed by Fourier transform infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS). FTIR spectroscopy results indicated that hemicellulose contents decrease, whereas lignin contents increase after heat treatment. Ester formation linked to lignin decreased the hygroscopicity of the bamboo samples and consequently improved their dimensional stability and durability. XPS spectroscopy results showed that hemicelluloses and celluloses are relatively more sensitive to the heating process than lignin. As a consequence, hemicellulose and cellulose contents decreased, whereas lignin contents increased during heat treatment. The results obtained in this study provide useful information for the future utilization of heat-treated bamboo.

  4. Date fruit: chemical composition, nutritional and medicinal values, products.

    Science.gov (United States)

    Tang, Zhen-Xing; Shi, Lu-E; Aleid, Salah M

    2013-08-15

    Date fruit has served as a staple food in the Arab world for centuries. Worldwide production of date fruit has increased almost threefold over the last 40 years, reaching 7.68 million tons in 2010. Date fruit can provide many essential nutrients and potential health benefits to the consumer. Date fruit goes through four ripening stages named kimri, khalal, rutab and tamer. The main chemical components of date fruit include carbohydrates, dietary fibre, enzymes, protein, fat, minerals, vitamins, phenolic acids and carotenoids. The chemical composition of date fruit varies according to ripening stage, cultivar, growing environment, postharvest conditions, etc. The nutritional and medicinal activities of date fruit are related to its chemical composition. Many studies have shown that date fruit has antioxidant, antimutagenic, anti-inflammatory, gastroprotective, hepatoprotective, nephroprotective, anticancer and immunostimulant activities. Various date fruit-based products such as date syrup, date paste, date juice and their derived products are available. Date by-products can be used as raw materials for the production of value-added products such as organic acids, exopolysaccharides, antibiotics, date-flavoured probiotic-fermented dairy produce, bakery yeasts, etc. In this paper the chemical composition and nutritional and medicinal values of date fruit as well as date fruit-based products are reviewed.

  5. Surface chemical composition analysis of heat-treated bamboo

    Energy Technology Data Exchange (ETDEWEB)

    Meng, Fan-dan, E-mail: fandan_meng@163.com [MOE Key Laboratory of Wooden Material Science and Application, Beijing Forestry University, 35 Qinghua East Road, Haidian District, Beijing 100083 (China); Yu, Yang-lun, E-mail: yuyanglun@caf.ac.cn [Research Institute of Wood Industry, Chinese Academy of Forestry, No 1 Dongxiaofu, Haidian District, Beijing 100091 (China); Zhang, Ya-mei, E-mail: zhangyamei@caf.ac.cn [Research Institute of Wood Industry, Chinese Academy of Forestry, No 1 Dongxiaofu, Haidian District, Beijing 100091 (China); Yu, Wen-ji, E-mail: yuwenji@caf.ac.cn [Research Institute of Wood Industry, Chinese Academy of Forestry, No 1 Dongxiaofu, Haidian District, Beijing 100091 (China); Gao, Jian-min, E-mail: gaojm@bjfu.edu.cn [MOE Key Laboratory of Wooden Material Science and Application, Beijing Forestry University, 35 Qinghua East Road, Haidian District, Beijing 100083 (China)

    2016-05-15

    Highlights: • Investigate the detailed chemical components contents change of bamboo due to heating. • Chemical analysis of bamboo main components during heating. • Identify the connection between the oxygen to carbon atomic ratio changes and chemical degradation. - Abstract: In this study, the effect of heat treatment on the chemical composition of bamboo slivers was studied. The chemical properties of the samples were examined by chemical analysis. Results showed a decrease in the contents of holocellulose and α-cellulose, as well as an increase in the contents of lignin and extractives. Changes in the chemical structure of bamboo components were analyzed by Fourier transform infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS). FTIR spectroscopy results indicated that hemicellulose contents decrease, whereas lignin contents increase after heat treatment. Ester formation linked to lignin decreased the hygroscopicity of the bamboo samples and consequently improved their dimensional stability and durability. XPS spectroscopy results showed that hemicelluloses and celluloses are relatively more sensitive to the heating process than lignin. As a consequence, hemicellulose and cellulose contents decreased, whereas lignin contents increased during heat treatment. The results obtained in this study provide useful information for the future utilization of heat-treated bamboo.

  6. Microbiological and chemical assessment of spring water from a ...

    African Journals Online (AJOL)

    GREG

    2013-06-20

    Jun 20, 2013 ... 1Environmental Microbiology and Biotechnology Unit, Department of Microbiology, ... Physico-chemical properties of the spring waters were mostly within ..... Standard methods for Examination of water and wastewater.

  7. Chemical composition of material fractions in Danish household waste

    DEFF Research Database (Denmark)

    Riber, Christian; Petersen, Claus; Christensen, Thomas Højlund

    2009-01-01

    The chemical composition of Danish household waste was determined by two approaches: a direct method where the chemical composition (61 substances) of 48 material fractions was determined after hand sorting of about 20 tonnes of waste collected from 2200 households; and an indirect method where...... batches of 80-1200 tonnes of unsorted household waste was incinerated and the content of the waste determined from the content of the outputs from the incinerator. The indirect method is believed to better represent the small but highly contaminated material fractions (e,g., batteries) than the direct...... method, because of the larger quantities included and the more homogenous material to sample from. Differences between the direct and the direct methods led to corrections in the of heavy metal concentration of a few fractions. The majority of the energy content of the waste originates from organic waste...

  8. Chemical Composition and Bioactive Compounds of Some Wild Edible Mushrooms

    Directory of Open Access Journals (Sweden)

    Melinda NAGY

    2017-05-01

    Full Text Available Over the last decades, the consumption of mushrooms has significantly increased due to the scientific evidence of their ability to help the organism in the combat and prevention of several diseases (Kalac, 2009. Fruiting bodies of mushrooms are consumed as a delicacy for their texture and flavour, but also for their nutritional properties that makes them even more attractable (Heleno S. 2015. In this paper data were collected from several scientific studies with the aim to characterize the chemical composition and content of bioactive compounds of various mushrooms species: Agaricus bisporus, Boletus edulis, Cantharellus cibarius, Pleurotus ostreatus, Lactarius piperatus. The chemical composition of 5 wild edible studied mushrooms, including moisture, ash, total carbohydrates, total sugars, crude fat, crude protein and energy were determined according to AOAC procedures.

  9. Parboiled rice: chemical composition and the occurrence of mycotoxins

    Directory of Open Access Journals (Sweden)

    Giniani Carla Dors

    2011-03-01

    Full Text Available The objective of this work was to evaluate the incidence of aflatoxin B1 (AFB B1, deoxynivalenol (DON, ochratoxin A (OTA, and zearalenone (ZEA in parboiled rice with respect to its chemical composition. Eight lots from five different brands of parboiled rice were collected in four samplings, at different seasons, until the amount of 32 lots. It was observed that: DON was present in 22% of the samples (from 180 to 400 ppb; ZEA in 19% (from 317 to 396 ppb; OTA in 12.5% (from 13 and 26 ppb; and AFB B1 in 9% (from 11 to 74 ppb. The results of the chemical composition were not different from those previously mentioned in the literature concerning parboiled rice. The ash and phenol levels in the contaminated parboiled rice samples suggested that those compounds had a relation to the occurrence of OTA, DON and ZEA mycotoxins.

  10. Chemical Composition of Essential Oil from Marrubium Vulgare L. Leaves

    OpenAIRE

    Bayir, Burcu; Gündüz, Hatice; Usta, Tuba; Şahin, Esma; Özdemir, Zeynep; Kayır, Ömer; Sen, Özkan; Akşit, Hüseyin; Elmastaş, Mahfuz; Erenler, Ramazan

    2014-01-01

    – The essential oils are significant for pharmaceutical, food and cosmetic industries. Marrubium vulgare L. has been used as a traditional medicine to treat the various illnesses. The chemical composition of the essential oil from leaves of Marrubium vulgare L.was obtained by steam distillation using the Clevenger apparatus. The oil was analyzed by gas chromatography and mass spectrometry (GC-MS). The main constituent of the oil was α-pinene (28.85%)

  11. Chemical composition and biological activity of the plum seed extract

    OpenAIRE

    Savić, Ivan M.; Nikolić, Vesna D.; Savić-Gajić, Ivana M.; Kundaković, Tatjana D.; Stanojković, Tatjana P.; Najman, Stevo J.; id_orcid 0000-0002-2411-9802

    2016-01-01

    The aim of this paper was to estimate the biological activity of the plum seed extract and to define the chemical composition by using the ESI-MS method. During the investigation of the antioxidant activity, the extract showed a better ability to inhibit DPPH radicals compared with amygdalin standard. The results of the antimicrobial study indicate that the extract has a greater effect on Gram-negative bacteria compared with amygdalin. Gram-positive bacteria and fungi remained resistant in bo...

  12. The chemical composition at a galactocentric distance of 13 KPC

    Science.gov (United States)

    Rolleston, W. R. J.; Dufton, P. L.; Fitzsimmons, A.

    1994-04-01

    High-resolution observations of two very sharp-lined, main-sequence B-type stars, associated with the H II region S 285, have been obtained using the ISIS spectrograph on the William Herschel Telescope. The spectroscopic data have been analysed using local thermodynamic equilibrium (LTE) model-atmosphere techniques to derive the stellar atmospheric parameters, chemical compositions and a mean distance of 4.3 kpc. As the lifetimes for these stars were calculated to be less than 6 Myrs, their photospheric abundances should reflect that of their natal interstellar material. Individual element abundances deduced for both stars were generally in excellent agreement (differing on average by less than 0.1 dex), although there is some evidence to suggest that the stars formed from material which had different nitrogen abundances. Both stars appear to have chemical compositions similar to that found in the solar neighborhood, which is consistent with a zero abundance gradient over these galactocentric distances. The chemical compositions of the stars associated with S 285 have also been compared with three other clusters at similar galactocentric distances (Bochum 1, NGC 1893 and Dolidze 25). From a differential analysis, Dolidze 25 appears to have a mean metal deficiency of approximately 0.7 dex, with oxygen being less underabundant, while the other two clusters have similar abundances to S 285. We conclude that these results are inconsistent with the concept of a linear galactic abundance gradient, that the chemical composition is not unique and that there are significant abundance variations over distance scales of 1 kpc at these large galactocentric distances.

  13. Chemical composition of silica-based biocidal modifier

    Directory of Open Access Journals (Sweden)

    Grishina Anna Nikolaevna

    2016-11-01

    Full Text Available Increase of the amount of fungi spores and micotixines causes the increase in the number of different diseases. Because of this, ensuring the biological safety in buildings is becoming more and more important today. The preferred way to guarantee the biological safety of a building is to employ modern building materials that prevent the settlement of the fungi colonies on the inner surfaces of walls. Such building materials can be produced using novel biocidal modifiers that allow controlling the number of microorganisms on the surface and in the bulk of a composite construction. The precipitation product of zinc hydrosilicates and sodium sulfate is one of the mentioned modifiers. Till now, the exact chemical composition of such precipitation product is controversial; it is obvious, though, that the efficacy of the biocidal modifier is mostly determined by the type of the copper compounds. In the present work an integrated approach is used for the investigation of the chemical composition of the biocidal modifier. Such an approach consists in the examination of the modifier’s composition by means of different, yet complementary, research methods: X-ray diffraction, infrared spectroscopy and DTA. It is shown that the chemical composition of the modifier mainly depends on the amount of precipitant. X-ray diffraction reveals that the major part of the modifier is represented by amorphous phase. Along with the increase of the precipitant’s amount the crystalline phase Zn4SO4(OH6•xH2O formation takes place. Such a crystalline phase is not appropriate as a component of the biocidal modifier. Another two methods - DTA and IR spectroscopy - reveal that the amorphous phase consists essentially of zinc hydrosilicates.

  14. Chemical composition and surface charge properties of montmorillonite

    Institute of Scientific and Technical Information of China (English)

    LIU Xiao-wen; HU Min; HU Yue-hua

    2008-01-01

    The effects of the cell parameter and chemical composition on the surface charge properties of five kinds of different colour montmorillonites were studied. The results indicate that the surface isoelectric point(IEP) of the montmorillonite shows positive correlation with the mass fractions of Fe2O3 and K20, but it has little relation to the mass fractions of other chemical compositions. At around pH=6.8, the surface zeta potential of the montmorillonite shows the negative relationship with the mass fractions of Fe2O3 and MgO, but it does not linearly correlate to the mass fractions of other chemical compositions. Cell parameter(b0) of the montmofillonite expresses negative linear relationship with mass fractions of K2O and Na2O, so does c0sinβ with mass fractions of SiO2 and Fe2O3. And there is no specific relationship between bo and IEP of different montmori Uonites, but there is positive correlation between c0sinβ and IEP of different montmorillonite samples.

  15. Interfacial studies of chemical-vapor-infiltrated ceramic matrix composites

    Energy Technology Data Exchange (ETDEWEB)

    Brennan, J.J. (United Technologies Research Center, East Hartford, CT (USA))

    1990-06-15

    The objective of this program was to investigate the fiber-matrix interfacial chemistry in chemical-vapor-infiltrated SiC matrix composites utilizing NICALON SiC and Nextel 400 mullite fibers and how this interface influences composite properties such as strength, toughness and environmental stability. The SiC matrix was deposited using three different reactants: methyldichlorosilane, methyltrichlorosilane and dimethyldichlorosilane. It was found that by varying the reactant gas flow rates, the ratio of carrier gas to reactant gas, the type of carrier gas (hydrogen or argon), the flushing gas used in the reactor prior to deposition (hydrogen or argon) or the type of silane reactant gas used, the composition of the deposited SiC could be varied from very silicon rich (75 at.%) to carbon rich (60%) to almost pure carbon. Stoichiometric SiC was found to bond very strongly to both NICALON and Nextel fibers, resulting in a weak and brittle composite. A thin carbon interfacial layer deposited either deliberately by the decomposition of methane or inadvertently by the introduction of argon into the reactor prior to silane flow resulted in a weakly bonded fiber-matrix interface and strong and tough composites. However, composites with this type of interface were not oxidatively stable. Preliminary results point ot the use of a carbon-rich SiC (mixture of carbon plus SiC) interfacial zone to achieve a relatively weak, crack-deflecting fiber-matrix bond but also exhibiting oxidative stability. (orig.).

  16. Chemical composition of the clays as indicator raw material sources

    Directory of Open Access Journals (Sweden)

    Khramchenkova Rezida Kh

    2014-06-01

    Full Text Available The paper presents the results of study on the chemical composition of unglazed pottery from the excavations of the Bulgar fortified settlement site and the clay, selected from the modern deposits of ceramic raw materials located near the medieval settlement sites. Significant differences in macro- and microelement composition of different groups of ceramics have been revealed. The difference in the macroelemental composition is largely determined by the ceramic fabric recipe. Thus, the high calcium content corresponds to the addition of river shells, the high content of silicon results from sand addition. A more interesting picture has been revealed in the course of studies of the so-called “trace elements” (microelements. Nine groups of ceramics with different elemental set have been distinguished. The first two groups consist of imported ceramics; other groups have demonstrated a rather pronounced elemental composition. The most notable variations are observed in chromium, vanadium and nickel content. Similar microelement composition variety has been observed in clays from deposits of different localization, while the concentration of the mentioned elements in a variety of clays also differs considerably. Therefore, marker elements typical of different clays have been identified. A comparative analysis of the data obtained for clay raw materials and ceramics has been conducted. The results demonstrate the potential of studying the elemental composition in order to determine the localization of the raw material sources for ceramic production.

  17. Preliminary study of chemical compositional data from Amazon ceramics

    Energy Technology Data Exchange (ETDEWEB)

    Toyota, Rosimeiri G.; Munita, Casimiro S.; Luz, Fabio A. [Instituto de Pesquisas Energeticas e Nucleares (IPEN), Sao Paulo, SP (Brazil)]. E-mail: rosimeiritoy@yahoo.com.br; Neves, Eduardo G. [Museu de Arqueologia e Etnolgia, Sao Paulo, SP (Brazil)]. E-mail: egneves@usp.br; Oliveira, Paulo M.S. [Sao Paulo Univ., SP (Brazil). Escola Politecnica. Inst. de Matematica e Estatistica]. E-mail: poliver@usp.br

    2005-07-01

    Eighty seven ceramic samples from Acutuba, Lago Grande and Osvaldo archaeological sites located in the confluence of the rivers Negro and Solimoes were submitted to chemical analysis using instrumental neutron activation analysis to determine As, Ba, Ce, Co, Cr, Cs, Eu, Fe, Hf, K, La, Lu, Rb, Na, Nd, Sb, Sc, Sm, Ta, Tb, Th, Yb, Zn, and U. The database were studied using the Mahalanobis distance, and discriminant analysis. The results showed that the ceramics of each site differ from each other in chemical composition and that they form three different groups. Chemical classification of the ceramics suggests that vessels were made locally, as only ceramics from the same area show homogeneity of data. (author)

  18. Review on Chemical treatment of Industrial Waste Water | Sahu ...

    African Journals Online (AJOL)

    Review on Chemical treatment of Industrial Waste Water. ... used and lot of wastewater generated from industries due their processes and washing purpose. A large number of chemicals are used for the production of potable water and ... powdered activated carbon (PAC) can remove taste and odour compounds and micro ...

  19. Peculiarities of chemical composition of sainfoin seeds powder

    Directory of Open Access Journals (Sweden)

    Natalia Aleksandrovna Tarasenko

    2015-09-01

    Full Text Available This paper is devoted to studying chemical composition of the powder of the seeds of non-traditional legume, sainfoin. The experimental studies showed that crushed seeds of sainfoin make a flowing fine powder of light brown color with a pleasant unpronounced specific smell with floral notes. The taste is grassy with the after-taste typical for legumes. The chemical composition of sainfoin seeds is dominated by proteins and fiber, and fat content does not exceed 8%. The total content of amino-acids is 26.94/100 g of the product, with the share of indispensable ones being 37.85%. The limiting amino acid is tryptophan (48.0 %. By the composition of essential amino acids, proteins of sainfoin seeds are slightly inferior to the proteins of soybean seeds, but are better than the proteins of peanut seeds. The composition of fatty acid of the lipid complex of sainfoin seeds is dominated by (over 40% of the total linolenic ω-3 acid with sufficiently low (less than 20% of the total content of linoleic ω-6 acid. The lipid composition of sainfoin seeds, along with triacylglycerols, contains about 40% of related lipids, which are dominated by sterols, aliphatic alcohols, phospholipids and tocopherols. All this makes the lipid complex of sainfoin seed a promising means of adjusting fatty acids composition in food products of functional and specialized purpose, dietary supplements, and a valuable raw material for creating pharmaceutical substances and preparations. Adding sainfoin seeds powder into the nutritive medium has no inhibitory effect on development of the tested organism. At the same time, 58% of the organism's physiological need for protein is satifsied, as compared to caseine.

  20. Bioactive carbon-PEEK composites prepared by chemical surface treatment.

    Science.gov (United States)

    Miyazaki, Toshiki; Matsunami, Chisato; Shirosaki, Yuki

    2017-01-01

    Polyetheretherketone (PEEK) has attracted much attention as an artificial intervertebral spacer for spinal reconstruction. Furthermore, PEEK plastic reinforced with carbon fiber has twice the bending strength of pure PEEK. However, the PEEK-based materials do not show ability for direct bone bonding, i.e., bioactivity. Although several trials have been conducted for enabling PEEK with bioactivity, few studies have reported on bioactive surface modification of carbon-PEEK composites. In the present study, we attempted the preparation of bioactive carbon-PEEK composites by chemical treatments with H2SO4 and CaCl2. Bioactivity was evaluated by in vitro apatite formation in simulated body fluid (SBF). The apatite formation on the carbon-PEEK composite was compared with that of pure PEEK. Both pure PEEK and carbon-PEEK composite formed the apatite in SBF when they were treated with H2SO4 and CaCl2; the latter showed higher apatite-forming ability than the former. It is conjectured that many functional groups able to induce the apatite nucleation, such as sulfo and carboxyl groups, are incorporated into the dispersed carbon phase in the carbon-PEEK composites.

  1. SEPARATION OF WATER VAPORS FROM AIR BY SORPTION ON SOME COMPOSITE MATERIALS

    Directory of Open Access Journals (Sweden)

    OANA HAUTĂ

    2014-01-01

    Full Text Available This work presents an experimental investigation of the kinetics of water vapor sorption on two composites synthesized by impregnating activated carbon and activated alumina respectively with lithium bromide (named as MCA2 and MCC2 respectively. The obtained results showed an increase in water amount adsorbed on both composite materials. Due to different chemical natures of the host matrices, the water sorption kinetics on MCC2 is faster compared to that of MCA2. The presence of calcium chloride instead of lithium bromide in alumina pores will determine a shorter breakthrough time and a higher adsorption rate of water vapors.

  2. [Impact of the mineral composition of drinking water on children's health].

    Science.gov (United States)

    Rylova, N V

    2009-01-01

    The purpose of this investigation was to evaluate the effect of highly mineralized drinking water on children's health. To reveal a relationship of children's health to the chemical composition of portable water, two Kazan districts differing in the conditions of water supply and the mineral composition of the water were selected. A total of 833 schoolchildren aged 7-9 years underwent a questionnaire survey and their objective status was examined. Special methods were used to determine the urinary content of trace elements, such as copper, zinc, cadmium, and gross elements, such as calcium and magnesium, by performing atomic absorption spectrophotometry on an AAS-SA 10 MP apparatus.

  3. Microbiological composition of river waters in the Ob’ basin (West Siberia) and its associations with hydrochemical indices

    Science.gov (United States)

    Savichev, O. G.; Tokarenko, O. G.; Pasechnik, E. Yu; Nalivaiko, N. G.; Ivanova, E. A.; Nadeina, L. V.

    2015-11-01

    Chemical and microbiological composition of the Mid-Ob’ and its feeders’ waters has been studied. Swampiness of the area is the cause of significant organic and biogenic substance content in streams, and it is also responsible for a large variety of organotrophic microflora. Microbiological composition of studied streams characterizes them as contaminated. Settlements are the main sources of the investigated area water pollution.

  4. A bootstrap estimation scheme for chemical compositional data with nondetects

    Science.gov (United States)

    Palarea-Albaladejo, J; Martín-Fernández, J.A; Olea, Ricardo A.

    2014-01-01

    The bootstrap method is commonly used to estimate the distribution of estimators and their associated uncertainty when explicit analytic expressions are not available or are difficult to obtain. It has been widely applied in environmental and geochemical studies, where the data generated often represent parts of whole, typically chemical concentrations. This kind of constrained data is generically called compositional data, and they require specialised statistical methods to properly account for their particular covariance structure. On the other hand, it is not unusual in practice that those data contain labels denoting nondetects, that is, concentrations falling below detection limits. Nondetects impede the implementation of the bootstrap and represent an additional source of uncertainty that must be taken into account. In this work, a bootstrap scheme is devised that handles nondetects by adding an imputation step within the resampling process and conveniently propagates their associated uncertainly. In doing so, it considers the constrained relationships between chemical concentrations originated from their compositional nature. Bootstrap estimates using a range of imputation methods, including new stochastic proposals, are compared across scenarios of increasing difficulty. They are formulated to meet compositional principles following the log-ratio approach, and an adjustment is introduced in the multivariate case to deal with nonclosed samples. Results suggest that nondetect bootstrap based on model-based imputation is generally preferable. A robust approach based on isometric log-ratio transformations appears to be particularly suited in this context. Computer routines in the R statistical programming language are provided. 

  5. Chemical composition of the sediment from Lake 20 (Antarctica

    Directory of Open Access Journals (Sweden)

    Daria ROSSI

    2000-02-01

    Full Text Available Lake 20 (19,000 m2 is located on the coast of the Ross Sea, in the North-Central part of Victoria Land, and its surface is ice-free between the end of December and early February. Within the framework of the Italian National Research Programme in Antarctica, a study was made of the chemical composition of sediments from the lake, with the intention of using this information to contribute to a better understanding of the processes involved in the long range transport of pollutants and their role in global changes. A sediment core from Lake 20 (Antarctica, 18 cm long, was collected in 1994, sliced into 2 cm sections and analysed using X Ray fluorescence spectrometry for 17 elements (Si, Al, Ca, K, Fe, Mg, Ti, S, P, Pb, Zn, Cu, Ni, Mn, Cr, Na, Cl, by CHN Elemental Analyser for C and N, by Flameless Atomic Absorption Spectrometry for As, and by Cold Vapour Atomic Absorption Spectrometry for Hg. The chemical composition of the sediments is consistent with the known geochemical characteristics of the drainage basin. While the chemical analyses reveal that sedimentation in Lake 20 has changed through time, the variations along the core are most probably related to the climatic evolution of the area, to the consequent changes in weathering processes, and possibly to an increase in the primary productivity of the lake, rather than to anthropogenic influences on the biogeochemical cycles of the elements.

  6. Wear and transfer characteristics of carbon fiber reinforced polymer composites under water lubrication

    Institute of Scientific and Technical Information of China (English)

    JIA Jun-hong; CHEN Jian-min; ZHOU Hui-di; CHEN Lei

    2004-01-01

    The tribological characteristics of carbon fiber reinforced polymer composites under distilled-water-lubricated-sliding and dry-sliding against stainless steel were comparatively investigated. Scanning electron microscopy (SEM) was utilized to examine composite microstructures and modes of failure. The typical chemical states of elements of the transfer film on the stainless steel were examined with X-ray photoelectron spectroscopy (XPS). Wear testing and SEM analysis show that all the composites hold the lowered friction coefficient and show much better wear resistance under water lubricated sliding against stainless steel than those under dry sliding. The wear of composites is characterized by plastic deformation, scuffing, micro cracking, and spalling under both dry-sliding and water lubricated conditions. Plastic deformation, scuffing, micro cracking, and spalling, however, are significantly abated under water-lubricated condition. XPS analysis conforms that none of the materials produces transfer films on the stainless steel counterface with the type familiar from dry sliding, and the transfer of composites onto the counterpart ring surface is significantly hindered while the oxidation of the stainless steel is speeded under water lubrication. The composites hinder transfer onto the steel surface and the boundary lubricating action of water accounts for the much smaller wear rate under water lubrication compared with that under dry sliding. The easier transfer of the composite onto the counterpart steel surface accounts for the larger wear rate of the polymer composite under dry sliding.

  7. Mineral and inorganic chemical composition of the Pernik coal, Bulgaria

    Energy Technology Data Exchange (ETDEWEB)

    Yossifova, Mariana G. [Geological Institute, Acad. G. Bonchev Str., Bl.24, Bulgarian Academy of Sciences, 1113 Sofia (Bulgaria)

    2007-11-22

    The mineral and inorganic chemical composition of five types of samples from the Pernik subbituminous coals and their products generated from the Pernik preparation plant were studied. They include feed coal, low-grade coal, high-grade coal, coal slime, and host rock. The mineral matter of the coals contains 44 species that belong mainly to silicates, carbonates, sulphates, sulphides, and oxides/hydroxides, and to a lesser extent, chlorides, biogenic minerals, and organic minerals. The detrital minerals are quartz, kaolinite, micas, feldspars, magnetite, cristobalite, spessartine, and amphibole. The authigenic minerals include various sulphides, silicates, oxihydroxides, sulphates, and carbonates. Several stages and substages of formation were identified during the syngenetic and epigenetic mineral precipitations of these coals. The authigenic minerals show the greatest diversity of mineral species as the epigenetic mineralization (mostly sulphides, carbonates, and sulphates) dominates qualitatively and quantitatively. The epigenetic mineralization was a result of complex processes occurring mostly during the late development of the Pernik basin. These processes indicate intensive tectonic, hydrothermal and volcanic activities accompanied by a change from fresh to marine sedimentation environment. Thermally altered organic matter due to some of the above processes was also identified in the basin. Most of the trace elements in the Pernik coals (Mo, Be, S, Zr, Y, Cl, Ba, Sc, Ga, Ag, V, P, Br, Ni, Co, Pb, Ca, and Ti) show an affinity to OM and phases intimately associated with OM. Some of the trace elements (Sr, Ti, Mn, Ba, Pb, Cu, Zn, Co, Cr, Ni, As, Ag, Yb, Sn, Ga, Ge, etc.) are impurities in authigenic and accessory minerals, while other trace elements (La, Ba, Cu, Ce, Sb, Bi, Zn, Pb, Cd, Nd, etc.) occur as discrete phases. Elements such as Sc, Be, Y, Ba, V, Zr, S, Mo, Ti, and Ga exceed Clarke concentrations in all of the coal types studied. It was also found that

  8. Which chemicals drive biological effects in wastewater and recycled water?

    Science.gov (United States)

    Tang, Janet Y M; Busetti, Francesco; Charrois, Jeffrey W A; Escher, Beate I

    2014-09-01

    Removal of organic micropollutants from wastewater during secondary treatment followed by reverse osmosis and UV disinfection was evaluated by a combination of four in-vitro cell-based bioassays and chemical analysis of 299 organic compounds. Concentrations detected in recycled water were below the Australian Guidelines for Water Recycling. Thus the detected chemicals were considered not to pose any health risk. The detected pesticides in the wastewater treatment plant effluent and partially advanced treated water explained all observed effects on photosynthesis inhibition. In contrast, mixture toxicity experiments with designed mixtures containing all detected chemicals at their measured concentrations demonstrated that the known chemicals explained less than 3% of the observed cytotoxicity and less than 1% of the oxidative stress response. Pesticides followed by pharmaceuticals and personal care products dominated the observed mixture effects. The detected chemicals were not related to the observed genotoxicity. The large proportion of unknown toxicity calls for effect monitoring complementary to chemical monitoring.

  9. Advances in chemical technologies for water and wastewater treatment: preface

    Institute of Scientific and Technical Information of China (English)

    Xiaochang WANG

    2009-01-01

    @@ Chemical technologies have been applied for water and wastewater treatment since more than 150 year ago, and are still playing the leading role in this field. With the fast development of sciences and technologies especially in the last two decades, chemical technologies which are applicable for solving water quality and water environmental problems underwent a great development not only in traditional areas such as coagulation, solid/liquid separation, oxidation, adsorption etc., but also in the emerging multidisciplinary fields. Nowadays, an increasing number of chemists and chemical engineers has broadened research interests. Biochemical/biological technologies, ecological technologies and process modeling and simulation have become important branches of chemical technologies. Such a tendency has been well reflected in the activities of the Group of Chemists for Water and Wastewater Treatment (GCWWT), a subdivision of Chinese Chemical Society (CCS).

  10. Treatment Process Requirements for Waters Containing Hydraulic Fracturing Chemicals

    Science.gov (United States)

    Stringfellow, W. T.; Camarillo, M. K.; Domen, J. K.; Sandelin, W.; Varadharajan, C.; Cooley, H.; Jordan, P. D.; Heberger, M. G.; Reagan, M. T.; Houseworth, J. E.; Birkholzer, J. T.

    2015-12-01

    A wide variety of chemical additives are used as part of the hydraulic fracturing (HyF) process. There is concern that HyF chemicals will be released into the environment and contaminate drinking water, agricultural water, or other water used for beneficial purposes. There is also interest in using produced water (water extracted from the subsurface during oil and gas production) for irrigation and other beneficial purposes, especially in the arid Southwest US. Reuse of produced water is not speculative: produced water can be low in salts and is being used in California for irrigation after minimal treatment. In this study, we identified chemicals that are used for hydraulic fracturing in California and conducted an analysis to determine if those chemicals would be removed by a variety of technically available treatment processes, including oil/water separation, air stripping, a variety of sorption media, advanced oxidation, biological treatment, and a variety of membrane treatment systems. The approach taken was to establish major physiochemical properties for individual chemicals (log Koc, Henry's constant, biodegradability, etc.), group chemicals by function (e.g corrosion inhibition, biocides), and use those properties to predict the fate of chemical additives in a treatment process. Results from this analysis is interpreted in the context of what is known about existing systems for the treatment of produced water before beneficial reuse, which includes a range of treatment systems from oil/water separators (the most common treatment) to sophisticated treatment trains used for purifying produced water for groundwater recharge. The results show that most HyF chemical additives will not be removed in existing treatment systems, but that more sophisticated treatment trains can be designed to remove additives before beneficial reuse.

  11. Moisture Absorption Model of Composites Considering Water Temperature Effect

    Directory of Open Access Journals (Sweden)

    HUI Li

    2016-11-01

    Full Text Available The influence of water temperature on composite moisture absorption parameters was investigated in temperature-controlled water bath. Experiments of carbon fiber/bismaleimide resin composites immersed in water of 60℃, 70℃and 80℃ were developed respectively. According to the moisture content-time curves obtained from the experimental results, the diffusion coefficient and the balanced moisture content of the composites immersed in different water temperature could be calculated. What's more, the effect of water temperature on the diffusion coefficient and the balanced moisture content were discussed too. According to the Arrhenius equation and the law of Fick, a moisture absorption model was proposed to simulate the hygroscopic behaviour of the composite laminates immersed in different water temperature which can predict the absorption rate of water of the composites immersed in distilled water of 95℃ at any time precisely and can calculate how long it will take to reach the specific absorption rate.

  12. Wood Chemical Composition in Species of Cactaceae: The Relationship between Lignification and Stem Morphology

    Science.gov (United States)

    Canché-Escamilla, Gonzalo; Soto-Hernández, Marcos

    2015-01-01

    In Cactaceae, wood anatomy is related to stem morphology in terms of the conferred support. In species of cacti with dimorphic wood, a unique process occurs in which the cambium stops producing wide-band tracheids (WBTs) and produces fibers; this is associated with the aging of individuals and increases in size. Stem support and lignification have only been studied in fibrous tree-like species, and studies in species with WBTs or dimorphic wood are lacking. In this study, we approach this process with a chemical focus, emphasizing the role of wood lignification. We hypothesized that the degree of wood lignification in Cactaceae increases with height of the species and that its chemical composition varies with wood anatomy. To test this, we studied the chemical composition (cellulose, hemicellulose, and lignin content) in 13 species (2 WBTs wood, 3 dimorphic, and 8 fibrous) with contrasting growth forms. We also analyzed lignification in dimorphic and fibrous species to determine the chemical features of WBTs and fibers and their relationship with stem support. The lignin contents were characterized by Fourier transform infrared spectroscopy and high performance liquid chromatography. We found that 11 species have a higher percentage (>35%) of lignin in their wood than other angiosperms or gymnosperms. The lignin chemical composition in fibrous species is similar to that of other dicots, but it is markedly heterogeneous in non-fibrous species where WBTs are abundant. The lignification in WBTs is associated with the resistance to high water pressure within cells rather than the contribution to mechanical support. Dimorphic wood species are usually richer in syringyl lignin, and tree-like species with lignified rays have more guaiacyl lignin. The results suggest that wood anatomy and lignin distribution play an important role in the chemical composition of wood, and further research is needed at the cellular level. PMID:25880223

  13. Wood chemical composition in species of Cactaceae: the relationship between lignification and stem morphology.

    Directory of Open Access Journals (Sweden)

    Jorge Reyes-Rivera

    Full Text Available In Cactaceae, wood anatomy is related to stem morphology in terms of the conferred support. In species of cacti with dimorphic wood, a unique process occurs in which the cambium stops producing wide-band tracheids (WBTs and produces fibers; this is associated with the aging of individuals and increases in size. Stem support and lignification have only been studied in fibrous tree-like species, and studies in species with WBTs or dimorphic wood are lacking. In this study, we approach this process with a chemical focus, emphasizing the role of wood lignification. We hypothesized that the degree of wood lignification in Cactaceae increases with height of the species and that its chemical composition varies with wood anatomy. To test this, we studied the chemical composition (cellulose, hemicellulose, and lignin content in 13 species (2 WBTs wood, 3 dimorphic, and 8 fibrous with contrasting growth forms. We also analyzed lignification in dimorphic and fibrous species to determine the chemical features of WBTs and fibers and their relationship with stem support. The lignin contents were characterized by Fourier transform infrared spectroscopy and high performance liquid chromatography. We found that 11 species have a higher percentage (>35% of lignin in their wood than other angiosperms or gymnosperms. The lignin chemical composition in fibrous species is similar to that of other dicots, but it is markedly heterogeneous in non-fibrous species where WBTs are abundant. The lignification in WBTs is associated with the resistance to high water pressure within cells rather than the contribution to mechanical support. Dimorphic wood species are usually richer in syringyl lignin, and tree-like species with lignified rays have more guaiacyl lignin. The results suggest that wood anatomy and lignin distribution play an important role in the chemical composition of wood, and further research is needed at the cellular level.

  14. Wood chemical composition in species of Cactaceae: the relationship between lignification and stem morphology.

    Science.gov (United States)

    Reyes-Rivera, Jorge; Canché-Escamilla, Gonzalo; Soto-Hernández, Marcos; Terrazas, Teresa

    2015-01-01

    In Cactaceae, wood anatomy is related to stem morphology in terms of the conferred support. In species of cacti with dimorphic wood, a unique process occurs in which the cambium stops producing wide-band tracheids (WBTs) and produces fibers; this is associated with the aging of individuals and increases in size. Stem support and lignification have only been studied in fibrous tree-like species, and studies in species with WBTs or dimorphic wood are lacking. In this study, we approach this process with a chemical focus, emphasizing the role of wood lignification. We hypothesized that the degree of wood lignification in Cactaceae increases with height of the species and that its chemical composition varies with wood anatomy. To test this, we studied the chemical composition (cellulose, hemicellulose, and lignin content) in 13 species (2 WBTs wood, 3 dimorphic, and 8 fibrous) with contrasting growth forms. We also analyzed lignification in dimorphic and fibrous species to determine the chemical features of WBTs and fibers and their relationship with stem support. The lignin contents were characterized by Fourier transform infrared spectroscopy and high performance liquid chromatography. We found that 11 species have a higher percentage (>35%) of lignin in their wood than other angiosperms or gymnosperms. The lignin chemical composition in fibrous species is similar to that of other dicots, but it is markedly heterogeneous in non-fibrous species where WBTs are abundant. The lignification in WBTs is associated with the resistance to high water pressure within cells rather than the contribution to mechanical support. Dimorphic wood species are usually richer in syringyl lignin, and tree-like species with lignified rays have more guaiacyl lignin. The results suggest that wood anatomy and lignin distribution play an important role in the chemical composition of wood, and further research is needed at the cellular level.

  15. Chemical composition of overland flow produced on soils covered with vegetative ash

    Directory of Open Access Journals (Sweden)

    M.B. Bodí

    2013-05-01

    Full Text Available The objective of this study was to ascertain the differences between the soluble elements of ash obtained under laboratory conditions and the dissolved in overland flow from soils covered with a layer of ash. The overland flow was obtained during series of rainfall simulations over soils covered with two different types of ash. This study indicates that the soluble elements released from ash can modify water quality increasing its pH, electrical conductivity and especially cation content. The nutrients solubilised are not necessarily the same as the elemental composition of ash itself. Runoff composition depends on the volume of water produced, on the solubility of the ash components and on the chemical interactions with water from rainfall and soil. After the first intense rain event, most of the elements are solubilised and lixiviated or washed out, however, some of them may increase in the runoff or soil water some weeks later due to chemical interactions with water from rainfall and soil nutrients.

  16. Chemical, isotopic, and gas compositions of selected thermal springs in Arizona, New Mexico, and Utah

    Science.gov (United States)

    Mariner, R.H.; Presser, T.S.; Evans, William C.

    1977-01-01

    Twenty-seven thermal springs in Arizona, New Mexico, and Utah were sampled for detailed chemical and isotopic analysis. The springs issue sodium chloride, sodium bicarbonate, or sodium mixed-anion waters of near neutral (6.2) to alkaline (9.2) pH. High concentrations of fluoride, more than 8 milligrams per liter, occur in Arizona in waters from Gillard Hot Springs, Castle Hot Springs, and the unnamed spring of Eagle Creek, and in New Mexico from springs along the Gila River. Deuterium compositions of the thermal waters cover the same range as those expected for meteoric waters in the respective areas. The chemical compositions of the thermal waters indicate that Thermo Hot Springs in Utah and Gillard Hot Springs in Arizona represent hydrothermal systems which are at temperatures higher than 125 deg C. Estimates of subsurface temperature based on the quartz and Na-K-Ca geothermometer differ by up to 60 deg C for Monroe, Joseph, Red Hill, and Crater hot springs in Utah. Similar conflicting estimates of aquifer temperature occur for Verde Hot Springs, the springs near Clifton and Coolidge Dam, in Arizona; and the warm springs near San Ysidro, Radium Hot Springs, and San Francisco Hot Springs, in New Mexico. Such disparities could result from mixing, precipitation of calcium carbonate, or perhaps appreciable concentrations of magnesium. (Woodard-USGS)

  17. Introducing Water-Treatment Subjects into Chemical Engineering Education.

    Science.gov (United States)

    Caceres, L.; And Others

    1992-01-01

    Proposes that inclusion of waste water treatment subjects within the chemical engineering curriculum can provide students with direct access to environmental issues from both a biotechnological and an ethical perspective. The descriptive details of water recycling at a copper plant and waste water stabilization ponds exemplify this approach from…

  18. Assessment of kidney stone and prevalence of its chemical compositions.

    Science.gov (United States)

    Pandeya, A; Prajapati, R; Panta, P; Regmi, A

    2010-09-01

    Kidney stone analysis is the test done on the stone which cause problems when they block the flow of urine through or out of the kidneys. The stones cause severe pain and are also associated with morbidity and renal damage. There is also no clear understanding on the relative metabolic composition of renal calculi. Hence, the study is aimed to find out the chemical composition of it which can guide treatment and give information that may prevent more stones from forming. The study was carried out on the stones that had been sent to the department of Biochemistry (n = 99; M = 61; F = 38; Mean age: 33.6 +/- 14.4 years) Approximately 98.9% of stones were composed of oxalate, 95.9% of Calcium, 85.8% of phosphate, 62.6% of Urate, 46.4% of Ammonium and very few percentages of Carbonate.

  19. Chemical composition of lipophilic extractives from grey alder (Alnus incana

    Directory of Open Access Journals (Sweden)

    Oskars Bikovens

    2013-02-01

    Full Text Available The chemical composition of the lipophilic extractives in the hexane extracts from grey alder bark, knotwood, and cones has been investigated by gas chromatography and gas chromatography-mass spectrometry. The efficiency of two extraction methods was compared. The highest amount of lipophilic extractives (about 9% of o.d. material was observed in grey alder cone, while the lowest (about 3% was found in knotwood. The three different morphological parts of alder showed significant differences not only in the content but also in composition of extractives, namely fatty acids, triglycerides, and triterpenes. The main identified compounds were triterpenoids (lupen-3-one, lupeol, betulone, betulinol, and betulinic acid in bark, and triglycerides in cones. The major group in knotwood was free fatty acids (mainly linoleic acid, 18:2.

  20. Chemical composition and health effects of Tartary buckwheat.

    Science.gov (United States)

    Zhu, Fan

    2016-07-15

    Tartary buckwheat (Fagopyrum tataricum) contains a range of nutrients including bioactive carbohydrates and proteins, polyphenols, phytosterols, vitamins, carotenoids, and minerals. The unique composition of Tartary buckwheat contributes to their various health benefits such as anti-oxidative, anti-cancer, anti-hypertension, anti-diabetic, cholesterol-lowering, and cognition-improving. Compared with the more widely cultivated and utilised common buckwheat (F. esculentum), Tartary buckwheat tends to contain higher amounts of certain bioactive components such as rutin, therefore, showing higher efficiency in preventing/treating various disorders. This review summarises the current knowledge of the chemical composition of Tartary buckwheat, and their bio-functions as studied by both in vitro and in vivo models. Tartary buckwheat can be further developed as a sustainable crop for functional food production to improve human health.

  1. Analysis of chemical composition of high viscous oils

    Directory of Open Access Journals (Sweden)

    Irina Germanovna Yashchenko

    2014-07-01

    Full Text Available The spatial distribution of viscous oils which are considered as an important reserve for oil-production in future were studied on base of information from global database on oil physical and chemical properties. Changes in chemical composition of viscous oils in different basins and continents were analyzed as well. It is shown, on average, viscous oils are sulfur-bearing, low paraffin, highly resinous oils with an average content of asphaltenes and low content of the fraction boiling at 200 C. Study results of viscous oils peculiarities of Canada, Russia and Venezuela are given. The analysis results can be used to determine the optimal layouts and conditions of oil transportation, to improve the search methods of geochemical exploration, and to solve other problems in the oil chemistry.

  2. [Chemical composition of seeds and testa of Vicia faba L].

    Science.gov (United States)

    Vetter, J

    1995-03-01

    Different chemical components were analysed in the seeds and in testa of Vicia faba. The seeds contain a relatively high crude protein (27.5%), a low crude fat (3.36%) content; and the lignin concentration is low (2.65%). The testa of the seeds has a very high fibre concentration and is a significant Ca-source (1.86 g/kg). The higher macroelement concentrations in the seeds were measured from K, P and Mg. The main microelements (Fe, Mn, Cu, Zn) have significant higher concentrations in the seed than in the testa. The amino acid composition of seeds is positive (compared to data of white lupine), the rate of essential amino acids is good. The concentrations of the examined antinutritive organic constituents, especially of alkaloids, are low. On the basis of chemical analysis, the production and utilisation of seeds of Vicia faba is recommended.

  3. Nepheline structural and chemical dependence on melt composition

    Energy Technology Data Exchange (ETDEWEB)

    Marcial, José; Crum, Jarrod; Neill, Owen; McCloy, John

    2016-02-01

    Nepheline crystallizes upon slow-cooling in some melts concentrated in Na2O and Al2O3, which can result in a residual glass phase of low chemical durability. Nepheline can incorporate many components often found in high-level waste radioactive borosilicate glass, including glass network ions (e.g., Si, Al, Fe), alkali metals (e.g., Cs, K, Na, and possibly Li), alkaline-earth metals (e.g., Ba, Sr, Ca, Mg), and transition metals (e.g., Mn, and possibly Cr, Zn, Ni). When crystallized from melts of different compositions, nepheline chemistry varies as a function of starting glass composition. Five simulated high level nuclear waste borosilicate glasses shown to crystallize large fractions of nepheline on slow cooling, were selected for study. These melts constituted a range of Al2O3, B2O3, CaO, Na2O, K2O, Fe2O3, and SiO2 compositions. Compositional analyses of nepheline crystals in glass by electron probe micro-analysis (EPMA) indicate that boron is unlikely to be present in any significant concentration, if at all, in nepheline. Also, several models are presented for calculating the fraction of vacancies in the nepheline structure.

  4. Chemical Composition and Fatty Acids of Glodok Fish by High Thermal Processing

    Directory of Open Access Journals (Sweden)

    Sri Purwaningsih

    2014-11-01

    Full Text Available Glodok is an economically underrated fish with a high nutrient content. The research aims to study the changes on chemical composition, fatty acids, omega-6 and omega-3 ratio in glodok muscle after processing with different methods of boiling, steaming, and boiling with addition of salt (3%. The results showed that the treatment (boiling, steaming, and boiling with addition of salt gives a significant effect (α=0.05 in water content, ash, lipid content, nervonat acid, linoleic acid, arachidonic acid, EPA, and DHA. The best processing method was steaming. The ratio of omega-3 and omega-6 in fresh glodok fish was 2,1:1, which is higher than WHO recommendation of 0,6:1,7.Keywords: chemical composition, fatty acid, glodok fish, processing

  5. Stevia rebaudiana Bertoni - chemical composition and functional properties.

    Science.gov (United States)

    Marcinek, Katarzyna; Krejpcio, Zbigniew

    2015-01-01

    Sweetleaf (Stevia rebaudiana Bertoni), currently investigated by many researchers, has been known and used for more than a thousand years indigenous tribes of South America, who called it "kaa-hee" ("sweet herb"). Thanks to its chemical composition and processability sweetleaf may be an alternative for synthetic sweeteners. Nutritional and health-promoting aspects of Stevia rebaudiana are presently being studied in many research centres. The aim of this study is to present nutritional and health-promoting value of the still-little known sweetleaf.

  6. Chemical composition and quality of sweet sorghum and maize silages

    OpenAIRE

    Zbigniew PODKÓWKA; Lucyna PODKÓWKA

    2011-01-01

    Sweet sorghum (Sorghum saccharatum) silage, maize (Zea mays) silage, and sorghum and maize (1:1) silage were investigated. The silages were analysed for chemical composition, quality and aerobic stability. Dry matter was the lowest (20.88%) in sorghum silage and the highest (37.45%) in maize silage. In sorghum silage, the concentration of crude ash and crude fibre was higher, and that of crude protein, crude fat and N-free extractives lower compared to maize silage. Neutral detergent fibre an...

  7. Chemical composition and fatty acid contents in farmed freshwater prawns

    Directory of Open Access Journals (Sweden)

    Carolina de Gasperi Portella

    2013-08-01

    Full Text Available The objective of this work was to evaluate the chemical composition and fatty acid contents of Amazonian and giant river prawns. After four-month farming, with the same diet for both species, palmitic and stearic acids were the main saturated fatty acids. Oleic acid was the main monounsatured fatty acid, and the eicosapentaenoic and docosahexaenoic acids were the most abundant polyunsaturated acids. Amazonian prawn has higher levels of protein and polyunsaturated fatty acids than those of the giant river prawn, which shows its potential for aquaculture.

  8. The Influence of Chemical Composition on LNG Pool Vaporization

    Directory of Open Access Journals (Sweden)

    Yu Zhidong

    2017-01-01

    Full Text Available A model is used to examine the influence of chemical composition on the vaporization rate of LNG during spreading. Calculations have been performed whereby the vaporization rate of the LNG mixtures has been compared to the vaporization of pure methane under the initial conditions. The detailed results indicate that the vaporization rate LNG mixture is different to that of pure methane. LNG as the liquid mixture gets rich in ethane and isobaric latent heat increases rapidly, leading to the rate vaporization of LNG decrease in compared to pure methane.

  9. Stevia rebaudiana Bertoni – chemical composition and functional properties

    Directory of Open Access Journals (Sweden)

    Katarzyna Marcinek

    2015-06-01

    Full Text Available Sweetleaf (Stevia rebaudiana Bertoni, currently investigated by many researchers, has been known and used for more than a thousand years indigenous tribes of South America, who called it “kaa-hee” (“sweet herb”. Thanks to its chemical composition and processability sweetleaf may be an alternative for synthetic sweeteners. Nutritional and health-promoting aspects of Stevia rebaudiana are presently being studied in many research centres. The aim of this study is to present nutritional and health-promoting value of the still-little known sweetleaf.

  10. Chemical vapor deposited fiber coatings and chemical vapor infiltrated ceramic matrix composites

    Energy Technology Data Exchange (ETDEWEB)

    Kmetz, M.A.

    1992-01-01

    Conventional Chemical Vapor Deposition (CVD) and Organometallic Chemical Vapor Deposition (MOCVD) were employed to deposit a series of interfacial coatings on SiC and carbon yarn. Molybdenum, tungsten and chromium hexacarbonyls were utilized as precursors in a low temperature (350[degrees]C) MOCVD process to coat SiC yarn with Mo, W and Cr oxycarbides. Annealing studies performed on the MoOC and WOC coated SiC yarns in N[sub 2] to 1,000[degrees]C establish that further decomposition of the oxycarbides occurred, culminating in the formation of the metals. These metals were then found to react with Si to form Mo and W disilicide coatings. In the Cr system, heating in N[sub 2] above 800[degrees]C resulted in the formation of a mixture of carbides and oxides. Convention CVD was also employed to coat SiC and carbon yarn with C, Bn and a new interface designated BC (a carbon-boron alloy). The coated tows were then infiltrated with SiC, TiO[sub 2], SiO[sub 2] and B[sub 4]C by a chemical vapor infiltration process. The B-C coatings were found to provide advantageous interfacial properties over carbon and BN coatings in several different composite systems. The effectiveness of these different coatings to act as a chemically inert barrier layer and their relationship to the degree of interfacial debonding on the mechanical properties of the composites were examined. The effects of thermal stability and strength of the coated fibers and composites were also determined for several difference atmospheres. In addition, a new method for determining the tensile strength of the as-received and coated yarns was also developed. The coated fibers and composites were further characterized by AES, SEM, XPS, IR and X-ray diffraction analysis.

  11. Some considerations on flow, heat and chemical composition of Italian hot springs

    Directory of Open Access Journals (Sweden)

    K. YUHARA

    1963-06-01

    Full Text Available Tlie flow, the temperature and the chemical composition
    of Italian hot springs are eonsidered from the geopliysical and geochemical
    points of view. At Guardia Piemontese, the spring temperature deereases in
    the rainy season while the flow increases, the phase lag of this variation from
    tlie rain being about two months. This may suggest that the precipitation
    aliments the source of the hot spring itself or it causes an increase of groundwater
    mixing to tlie hot spring.
    In Italy, the hot water output of each hot spring is generally less
    than the quantity of corresponding recharged water from the precipitation
    in the basili, and tliis relation is also kept in the geothermal steam fleld
    of Larderello. The annual tliermal outputs of Italian hot springs are
    of order of IO14 cai at maximum. We can extraet geochemically some
    groups of water from the Italian minerai waters: thev are a high saline water
    being regarded as fossil or oil-field water, a water being similar to the sea
    water, a water of which main soluble component is CaS04, and a middle
    type between last two waters.

  12. Inorganic Chemical Composition of Swimming Pools in Amman-Jordan

    Directory of Open Access Journals (Sweden)

    Bety Saqarat

    2012-10-01

    Full Text Available Monitoring was carried out during summer 2011 in three types of swimming pools in Amman-Jordan. Thirty six water samples, collected from three users type of swimming pools (adults, family and infants, were examined for its major ionic composition (HCO3-, Cl-, NO3-, SO4=, Ca+2, Mg+2, Na+, K+ and PO4+4 in addition to its BOD and COD content. All of the examined samples from the swimming pools water were acceptable according to the local and WHO standards. The type and number of users as well as the maintenance of the swimming pool water influenced the water quality. The results showed that there was a noticeable increase in NO3, PO4 and Cl than other ions. All of the examined samples from the swimming pools water were acceptable according to the local and WHO standards and although the water of the infant’s users changed frequently, it showed the highest concentration of most of the parameters and Adults’ pool showed the lowest.

  13. Assessment of physico-chemical characteristics of water in Tamilnadu.

    Science.gov (United States)

    Udhayakumar, R; Manivannan, P; Raghu, K; Vaideki, S

    2016-12-01

    Water is an important component to human life. The major aims of the present work are to assess the quality of the ground water and its impact in Villupuram District of Tamilnadu. The present study focus to bring an awareness among the people about the quality of ground water by taking water samples from various locations for Physico - Chemical analysis of the ground water. This analysis result was compared with the WHO, ICMR, USPH and European standards of drinking water quality parameters with the following water quality parameters namely pH, Electrical conductivity, Cl, , Na, K, Ca , Mg, Total dissolved solids, Total hardness, Dissolved oxygen, Fluoride etc. Various chemical methods have been employed to investigate the extent level of pollution in ground water. Copyright © 2016 Elsevier Inc. All rights reserved.

  14. Produced water challenges : influence of production chemicals on flocculation

    OpenAIRE

    Zangaeva, Elmara

    2010-01-01

    Produced water is the largest volume waste from offshore oil and gas exploration and production processes. Water in varying quantities is always produced along with oil, and has to be separated from the oil. The quantity of “produced water” generally increases substantially with the age of the oil field. Produced water handling tactic depends on the composition of produced water, location, quantity and the availability of resources. This thesis describes practical, economical, technologica...

  15. Distribution of Complex Chemicals in Oil-Water Systems

    DEFF Research Database (Denmark)

    Riaz, Muhammad

    . In order to inhibit gas hydrate formation in subsea pipelines monoethylene glycol (MEG) and methanol are injected in large amounts. It is important to know the distribution of these chemicals in oil and water systems for economical operation of a production facility and to evaluate their impact on marine...... life. Furthermore distribution of chemicals is important information for downstream processing of oil and gas. The purpose of this project is the experimental measurement and the thermodynamic modeling of distribution of these complex chemicals in oil-water systems. Traditionally distribution...... and limited information about the molecular structure of production chemicals the correlation could only be obtained for few families like alcohols, glycols and alkanolamines with varying degree of reliability. In order to develop a thermodynamic model for the distribution of chemicals in oil-water systems...

  16. Physical/chemical closed-loop water-recycling

    Science.gov (United States)

    Herrmann, Cal C.; Wydeven, Theodore

    1991-01-01

    Water needs, water sources, and means for recycling water are examined in terms appropriate to the water quality requirements of a small crew and spacecraft intended for long duration exploration missions. Inorganic, organic, and biological hazards are estimated for waste water sources. Sensitivities to these hazards for human uses are estimated. The water recycling processes considered are humidity condensation, carbon dioxide reduction, waste oxidation, distillation, reverse osmosis, pervaporation, electrodialysis, ion exchange, carbon sorption, and electrochemical oxidation. Limitations and applications of these processes are evaluated in terms of water quality objectives. Computerized simulation of some of these chemical processes is examined. Recommendations are made for development of new water recycling technology and improvement of existing technology for near term application to life support systems for humans in space. The technological developments are equally applicable to water needs on Earth, in regions where extensive water recycling is needed or where advanced water treatment is essential to meet EPA health standards.

  17. Chemical composition and larvicidal activity of Rollinia leptopetala (Annonaceae)

    Energy Technology Data Exchange (ETDEWEB)

    Feitosa, Edinilza M.A.; Arriaga, Angela M.C.; Lemos, Telma L.G.; Oliveira, M. Conceicao F. de; Vasnconcelos, Jackson Nunes e; Lima, Jefferson Q.; Malcher, Grazielle T. [Universidade Federal do Ceara (UFC), Fortaleza, CE (Brazil). Dept. de Quimica Organica e Inorganica]. E-mail: angelamcarriaga@yahoo.com.br; Santiago, Gilvandete M.P. [Universidade Federal do Ceara (UFC), Fortaleza, CE (Brazil). Dept. de Farmacia; Nascimento, Ronaldo F. do [Universidade Federal do Ceara (UFC), Fortaleza, CE (Brazil). Dept. de Quimica Analitica e Fisico-Quimica; Braz-Filho, Raimundo [Universidade Estadual do Norte Fluminense (UENF), Campos dos Goytacases, RJ (Brazil). Setor de Quimica de Produtos Naturais. Lab. de Ciencias Quimicas

    2009-07-01

    The aim of present study was to describe the chemical composition of the essential oils from the leaf and stem of Rollinia leptopetala R. E. Fries (Annonaceae) and to evaluate the larvicidal activities of these essential oils, of the methanol extract from roots of this plant and of the oxoaporphine alkaloid, liriodenine (1) against the third-instar of Aedes aegypti larvae. The methanol extract from the roots showed larvicidal activity with LC{sub 50} 64.6 {+-} 1.5 ppm. Higher activity was observed for the isolated alkaloid liriodenine (1), LC{sub 50} 3.6 {+-} 0.4 ppm. The essential oils from the leaves and stems, also exhibited larvicidal activity with LC{sub 50} 104.7 {+-} 0.2 and 34.7 {+-} 0.3 ppm, respectively. These results suggest R. leptopetala as a source of natural larvicidal compounds. This is the first report about the chemical composition and larvicidal activity of the leaf and stem essential oils of R. leptopetala. (author)

  18. THE MINERALISATION DEGREE AND CHEMICAL COMPOSITION OF THE LAKES IN THE TRANSYLVANIAN PLAIN

    Directory of Open Access Journals (Sweden)

    Victor SOROCOVSCHI

    2009-06-01

    Full Text Available The article was compiled from the processing of chemical analysis performed on samples taken during the campaign carried out in April 2004 by members of the group of hydrology from the Faculty of Geography, Cluj-Napoca, and the results published by a small number of specialists from various areas. After analyzing the factors that determine the chemical features of Transylvanian fresh water lakes it was the degree of mineralization that distinguished lakes without leakage from the lakes with drainage. Finally, based on analysis of ionic composition of lake water we determined the specific types of lakes in Transylvania Plain, which ranged from pure magnesian bicarbonate (Cătina the prevalence of magnesium bicarbonate mixed in sulphated-magnesium bicarbonate and chloride mixed with predominance - sulfated mixed with sodium predominance.

  19. physico-chemical properties of well water samples from some ...

    African Journals Online (AJOL)

    Administrator

    Physico-Chemical Analysis: Water samples collected were analyzed by both classical and .... This and some other factors may be responsible for the ... Diatom (Bacillariophyta) diversity of an open access lagoon in. Lagos, Nigeria. Journal ...

  20. Physical-chemical evaluation of hydraulic fracturing chemicals in the context of produced water treatment.

    Science.gov (United States)

    Camarillo, Mary Kay; Domen, Jeremy K; Stringfellow, William T

    2016-12-01

    Produced water is a significant waste stream that can be treated and reused; however, the removal of production chemicals-such as those added in hydraulic fracturing-must be addressed. One motivation for treating and reusing produced water is that current disposal methods-typically consisting of deep well injection and percolation in infiltration pits-are being limited. Furthermore, oil and gas production often occurs in arid regions where there is demand for new water sources. In this paper, hydraulic fracturing chemical additive data from California are used as a case study where physical-chemical and biodegradation data are summarized and used to screen for appropriate produced water treatment technologies. The data indicate that hydraulic fracturing chemicals are largely treatable; however, data are missing for 24 of the 193 chemical additives identified. More than one-third of organic chemicals have data indicating biodegradability, suggesting biological treatment would be effective. Adsorption-based methods and partitioning of chemicals into oil for subsequent separation is expected to be effective for approximately one-third of chemicals. Volatilization-based treatment methods (e.g. air stripping) will only be effective for approximately 10% of chemicals. Reverse osmosis is a good catch-all with over 70% of organic chemicals expected to be removed efficiently. Other technologies such as electrocoagulation and advanced oxidation are promising but lack demonstration. Chemicals of most concern due to prevalence, toxicity, and lack of data include propargyl alcohol, 2-mercaptoethyl alcohol, tetrakis hydroxymethyl-phosphonium sulfate, thioglycolic acid, 2-bromo-3-nitrilopropionamide, formaldehyde polymers, polymers of acrylic acid, quaternary ammonium compounds, and surfactants (e.g. ethoxylated alcohols). Future studies should examine the fate of hydraulic fracturing chemicals in produced water treatment trains to demonstrate removal and clarify interactions

  1. Chemical Composition of the Essential Oil from Chaerophyllum temulum (Apiaceae).

    Science.gov (United States)

    Stamenković, Jelena G; Stojanović, Gordana S; Radojković, Ivana R; Petrović, Goran M; Zlatković, Bojan K

    2015-08-01

    The present study reports the chemical composition on the essential oil obtained from fresh roots, stems, inflorescences and fruits of Chaerophyllum temulum. In all samples, except the roots, the most dominant components were sesquiterpene hydrocarbons. (Z)-Falcarinol was the principal constituent of the root essential oils (61.7% at the flowering stage and 62.3% at the fruiting stage). The blossom oil was dominated by (Z,E)-α-famesene (23.4%), (E)-β-farnesene (9.0%) and germacrene D-4-ol (9%), whereas the oil from the fruit had germacrene D-4-ol (27.6%) as its main compound, accompanied by (Z,E)-α-famesene (13.4%). Germacrene D was the most abundant component of the stem essential oil (38.4% at the flowering stage and 32.5% at the fruiting stage). The obtained results show that the qualitative composition of the oil depends on the part of the plant which is analyzed, while the quantitative composition of the main components depends on the growing stage of the plant.

  2. Chemical composition of the circumstellar disk around AB Aurigae

    CERN Document Server

    Pacheco-Vázquez, S; Agúndez, M; Pinte, C; Alonso-Albi, T; Neri, R; Cernicharo, J; Goicoechea, J R; Berné, O; Wiesenfeld, L; Bachiller, R; Lefloch, B

    2015-01-01

    Aims. Our goal is to determine the molecular composition of the circumstellar disk around AB Aurigae (hereafter, AB Aur). AB Aur is a prototypical Herbig Ae star and the understanding of its disk chemistry is of paramount importance to understand the chemical evolution of the gas in warm disks. Methods. We used the IRAM 30-m telescope to perform a sensitive search for molecular lines in AB Aur as part of the IRAM Large program ASAI (A Chemical Survey of Sun-like Star-forming Regions). These data were complemented with interferometric observations of the HCO+ 1-0 and C17O 1-0 lines using the IRAM Plateau de Bure Interferometer (PdBI). Single-dish and interferometric data were used to constrain chemical models. Results. Throughout the survey, several lines of CO and its isotopologues, HCO+, H2CO, HCN, CN and CS, were detected. In addition, we detected the SO 54-33 and 56-45 lines, confirming the previous tentative detection. Comparing to other T Tauri's and Herbig Ae disks, AB Aur presents low HCN 3-2/HCO+ 3-2 ...

  3. Water Uptake Behavior and Young Modulus Prediction of Composites Based on Treated Sisal Fibers and Poly(Lactic Acid

    Directory of Open Access Journals (Sweden)

    Ander Orue

    2016-05-01

    Full Text Available The main aim of this work was to study the effect of sisal fiber surface treatments on water uptake behavior of composites based on untreated and treated fibers. For this purpose, sisal fibers were treated with different chemical treatments. All surface treatments delayed the water absorption of fibers only for a short time of period. No significant differences were observed in water uptake profiles of composites based on fibers with different surface treatments. After water uptake period, tensile strength and Young modulus values of sisal fiber/poly(lactic acid (PLA composites were decreased. On the other hand, composites based on NaOH + silane treated fibers showed the lowest diffusion coefficient values, suggesting that this treatment seemed to be the most effective treatment to reduce water diffusion rate into the composites. Finally, Young modulus values of composites, before water uptake period, were predicted using different micromechanical models and were compared with experimental data.

  4. Use of chemical and isotopic tracers to characterize the interactions between ground water and surface water in mantled karst

    Science.gov (United States)

    Katz, B.G.; Coplen, T.B.; Bullen, T.D.; Hal, Davis J.

    1997-01-01

    In the mantled karst terrane of northern Florida, the water quality of the Upper Floridan aquifer is influenced by the degree of connectivity between the aquifer and the surface. Chemical and isotopic analyses [18O/16O (??18O), 2H/1H (??D), 13C/12C (??13C), tritium(3H), and strontium-87/strontium-86(87Sr/86Sr)]along with geochemical mass-balance modeling were used to identify the dominant hydrochemical processes that control the composition of ground water as it evolves downgradient in two systems. In one system, surface water enters the Upper Floridan aquifer through a sinkhole located in the Northern Highlands physiographic unit. In the other system, surface water enters the aquifer through a sinkhole lake (Lake Bradford) in the Woodville Karst Plain. Differences in the composition of water isotopes (??18O and ??D) in rainfall, ground water, and surface water were used to develop mixing models of surface water (leakage of water to the Upper Floridan aquifer from a sinkhole lake and a sinkhole) and ground water. Using mass-balance calculations, based on differences in ??18O and ??D, the proportion of lake water that mixed with meteoric water ranged from 7 to 86% in water from wells located in close proximity to Lake Bradford. In deeper parts of the Upper Floridan aquifer, water enriched in 18O and D from five of 12 sampled municipal wells indicated that recharge from a sinkhole (1 to 24%) and surface water with an evaporated isotopic signature (2 to 32%) was mixing with ground water. The solute isotopes, ??13C and 87Sr/86Sr, were used to test the sensitivity of binary and ternary mixing models, and to estimate the amount of mass transfer of carbon and other dissolved species in geochemical reactions. In ground water downgradient from Lake Bradford, the dominant processes controlling carbon cycling in ground water were dissolution of carbonate minerals, aerobic degradation of organic matter, and hydrolysis of silicate minerals. In the deeper parts of the Upper

  5. Copper ions removal from water using functionalized carbon nanotubes–mullite composite as adsorbent

    Energy Technology Data Exchange (ETDEWEB)

    Tofighy, Maryam Ahmadzadeh; Mohammadi, Toraj, E-mail: torajmohammadi@iust.ac.ir

    2015-08-15

    Highlights: • CNTs–mullite composite was prepared via chemical vapor deposition (CVD) method. • The prepared composite was modified with concentrated nitric acid and chitosan. • The modified CNTs–mullite composites were used as novel adsorbents. • Copper ion removal from water by the prepared adsorbents was performed. • Langmuir and Freundlich isotherms and two kinetic models were applied to fit the experimental data. - Abstract: Carbon nanotubes–mullite composite was synthesized by direct growth of carbon nanotubes on mullite particles via chemical vapor deposition method using cyclohexanol and ferrocene as carbon precursor and catalyst, respectively. The carbon nanotubes–mullite composite was oxidized with concentrated nitric acid and functionalized with chitosan and then used as a novel adsorbent for copper ions removal from water. The results demonstrated that modification with concentrated nitric acid and chitosan improves copper ions adsorption capacity of the prepared composite, significantly. Langmuir and Freundlich isotherms and two kinetic models were applied to fit the experimental data. The carbon nanotubes growth on mullite particles to form the carbon nanotubes–mullite composite with further modification is an inherently safe approach for many promising environmental applications to avoid some concerns regarding environment, health and safety. It was found that the modified carbon nanotubes–mullite composite can be considered as an excellent adsorbent for copper ions removal from water.

  6. On the cluster composition of supercritical water combining molecular modeling and vibrational spectroscopic data.

    Science.gov (United States)

    Tassaing, T; Garrain, P A; Bégué, D; Baraille, I

    2010-07-21

    The present study is aimed at a detailed analysis of supercritical water structure based on the combination of experimental vibrational spectra as well as molecular modeling calculations of isolated water clusters. We propose an equilibrium cluster composition model where supercritical water is considered as an ideal mixture of small water clusters (n=1-3) at the chemical equilibrium and the vibrational spectra are expected to result from the superposition of the spectra of the individual clusters, Thus, it was possible to extract from the decomposition of the midinfrared spectra the evolution of the partition of clusters in supercritical water as a function of density. The cluster composition predicted by this model was found to be quantitatively consistent with the near infrared and Raman spectra of supercritical water analyzed using the same procedure. We emphasize that such methodology could be applied to determine the portion of cluster in water in a wider thermodynamic range as well as in more complex aqueous supercritical solutions.

  7. Chemical composition and amino acid profile of differently processed feather meal

    Directory of Open Access Journals (Sweden)

    Adejumo Oluseun Isaac

    2016-01-01

    Full Text Available Feather wastes represent potential alternative ingredients for animal feedstuffs which can ameliorate the protein shortage for food and feed. Previous attempts to provide information about the nutrient composition of feather meal are either too complicated for rural livestock farmers in developing countries or they provided incomplete information on chemical composition. Washed feathers were subjected to different processing techniques such as pre-soaking in distilled water, wood ash, 0.3M NaOH, a mixture of wood ash and 0.3M NaOH, incubated at 37°C and boiled at 150°C for 60 minutes. Treated feather meals were analysed for chemical composition and amino acid profile. The overall result showed that feather meal pre-soaked with wood ash for 24 hr boiled at 150oC for 60 minutes, those pre-soaked with 0.3M NaOH and wood ash incubated at 37°C for 24 hr boiled at 150°C for 60 minutes and raw feather meal pre-soaked in distilled water for 24 hr boiled at 150°C for 60 minutes gave better results. Wood ash and 0.3M NaOH and their mixture could enhance the nutritional value of feather meal.

  8. Hot water extracted wood fiber for production of wood plastic composites (WPCs)

    Science.gov (United States)

    Manuel Raul Pelaez-Samaniego; Vikram Yadama; Eini Lowell; Thomas E. Amidon; Timothy L. Chaffee

    2013-01-01

    Undebarked ponderosa pine chips were treated by hot water extraction to modify the chemical composition. In the treated pine (TP) , the mass was reduced by approximately 20%, and the extract was composed mainly of degradation products of hemicelluloses. Wood flour produced from TP and unextracted chips (untreated pine, UP) was blended with high-density polyethylene (...

  9. Beebread from Apis mellifera and Apis dorsata. Comparative Chemical Composition and Bioactivity

    Directory of Open Access Journals (Sweden)

    Otilia BOBIS

    2017-05-01

    Full Text Available Beebread is a valuable bee product, both for bee nutrition and for humans. The high nutritional and bioactive properties of beebread were evaluated by chemical composition analysis of beebread from Apis mellifera and Apis dorsata. Bee bread harvested from Romania and India, coming from Apis mellifera and Apis dorsata bees, were evaluated for their chemical composition. Analyses were made in APHIS Laboratory from USAMV Cluj, using validated methods for bee products. Lipids were determined by the Soxhlet extraction method, total protein content was determined by Kjehldahl method, sugar spectrum was determined by high performance liquid chromatography with refractive index detection (HPLC-IR. Water content of beebread samples were situated between 11.45 and 16.46%, total protein content between 16.84 and 19.19% and total lipids between 6.36 and 13.47%.  Beebread has high bioactive properties which can be expressed as antioxidant and/or antibacterial activity. Chemical composition and bioactive properties of beebread is influenced by floral origin of the pollen which the bees collect and place in combs for fermentation. Also the climatic conditions have an important role in developing different fermentation compounds, that may act as antioxidants or antibacterial agents.

  10. Chemical composition and antioxidant activity of a Lebanese plant Euphorbia macroclada schyzoceras

    Institute of Scientific and Technical Information of China (English)

    Hussein Farhan; Hassan Rammal; Akram Hijazi; Ahmad Daher; Mohamad Reda; Hussein Annan; Ali Chokr; Ali Bassal; Bassam Badran

    2013-01-01

    Objective:To determine the chemical composition, total phenolic and total flavonoid contents of the crude extracts from leaves and stems of a Lebanese plant Euphorbia macroclada schyzoceras (E. macroclada), and to evaluate their antioxidant potential using DPPH, H2O2, and chelating of ferrous ions tests. Methods:Quantification of the total phenolic and total flavonoid contents of the crude extracts from leaves and stems and the antioxidant activities were evaluated using spectrophotometric analyses. The chemical composition has been estimated using different techniques such as IR, LC/MS and NMR. Results:Ethanolic extract from leaves of E. macroclada was better than aqueous extract and showed higher content in total phenolic and total flavonoid than found in the stems. On the other hand, using DPPH and H2O2 tests, this extract from leaves showed higher antioxidant capacity than aqueous extract. However, using the chelating of ferrous ions test, the antioxidant activity of the aqueous extract of both stems and leaves was stronger than that of ethanolic once. The chemical composition of the whole plant showed the presence of some aromatic compounds and fatty acids. Conclusions:Both ethanolic and water extracts from both parts of this plant are effective and have good antioxidant power. So, this plant can be used in the prevention of a number of diseases related to oxidative stress.

  11. Composition and Physico-Chemical Properties of Meat from Capons Fed Cereals

    Institute of Scientific and Technical Information of China (English)

    Olga Díaz; Luisana Rodríguez; Alexandr Torres; Ángel Cobos

    2013-01-01

    Chemical composition, physico-chemical properties and fatty acid composition of breast and drumstick meat from capons (castrated male cockerels) fed cereals were studied. Three groups of capons were reared. One group was fed ad libitum the same commercial diet until the 4th mon of life. The last month of its life, the capons of this group were fed corn. The second and third group of capons were fed the same diet from caponization. The second group was fed mixture of corn (50%) and wheat (50%). The third group of capons was fed 2/3 corn and 1/3 mixture of corn (50%) and barley (50%). Capons were reared under free-range conditions and slaughtered at 150 d of age. Caponization was performed at 48 d. No signiifcant effects of feeding in chemical composition, pH, water holding capacity, drip and cooking losses and texture of the meat were observed. The meat of the third group (capons fed 83%corn) was more yellow and showed higher content of C18:2 than that of the other capons.

  12. The impact of physico-chemical water quality parameters on ...

    African Journals Online (AJOL)

    from water samples and PCR amplified using universal bacterial primer pairs. PCR products ... riorated due to constant disposal of industrial and domestic waste into the river. Salinisation .... to 16S rRNA sequences in the National Center of Biotechnology ..... composition in Central European running waters examined by.

  13. Chemical Composition of Atmospheric Aerosols in Iowa City

    Science.gov (United States)

    Jayarathne, T. S.; Stone, E.

    2013-12-01

    In this study, the seasonal and spatial variability of chemical components in atmospheric PM2.5 were investigated in Iowa City, Iowa for the first time. Daily PM samples were collected from 25 August to 10 November 2011 at two sites in Iowa City (West and East) that were separated by approximately four miles. During this time, daily average PM2.5 mass concentrations ranged from 3 - 26 μg m-3, within attainment of EPA National Ambient Air Quality Standard of 35 μg m-3. The average PM2.5 concentration was 11.2×4.9 μg m-3 (arithmetic mean × one standard deviation for n = 72). Carbonaceous aerosol (elemental carbon and organic matter) was the dominant component of PM2.5, contributing 40% of PM2.5 mass. Another 30% was due to water soluble inorganic ions (SO42-, NO3-, Cl-, Na+, NH4+, K+, Mg2+, Ca2+) with major contributions from SO42- (13%), NO3- (6%), NH4+ (6%) and Ca2+ (3%). Among the inorganic ions, SO42- exhibited the highest individual ion concentration at both sites with an average concentration of 1.5×1.2 μg m-3 at West Site and 1.5×1.3 μg m-3 at East Site. The average NO3- concentrations for this period were 0.5×0.4 μg m-3 and 0.7×0.5 μg m-3 at West and East Sites, respectively. Comparison of aerosol composition data from the two sites indicated that concentrations of SO42-, NO3-, NH4+ and organic carbon were not statistically different at the 95% confidence interval, indicating that these species were primarily influenced by regional atmospheric processes. Meanwhile, Ca2+ and elemental carbon concentrations were statistically different across the two study sites, indicating the influence of local PM sources. Unlike other ions, Ca2+ concentrations were significantly elevated at both sites in October, during the agricultural harvest, showing that re-suspended soil dust is a temporally-variable source of fine particles that peaks during the agricultural harvest season. Several episodes of elevated PM2.5 occurred in late August to early October, with

  14. [Hygienic, chemical and ecotoxicological aspects of the disinfection of biologically treated waste water by ozone and UV light].

    Science.gov (United States)

    Iske, U; Nelle, T; Oberg, C; Rudolph, K U; Zander-Hauck, S

    1996-02-01

    Biologically treated waste water from two different municipal treatment plants with mainly domestic waste water on the one hand and industrial influenced waste water on the other hand was disinfected by UV-irradiation and ozonation. Hygienic, chemical and eco-toxic effects of the disinfection step were examined. It was found that by ozonation as well as by UV-irradiation the required guide and imperative values for fecal and total coliform bacteria were fulfilled. The UV-irradiation induces no changes concerning chemical waste water quality and toxic effects. In contrast to these results ozonation can lead to alterations in chemistry and toxicity depending on the waste water composition.

  15. Chemical composition of Chenopodium botrys L. (Chenopodiaceae essential oil

    Directory of Open Access Journals (Sweden)

    Ljubica Adji Andov

    2014-08-01

    Full Text Available Chemical composition of essential oil isolated from aerial parts of Chenopodium botrys L. (Chenopodiaceae collected from five different locations in the Republic of Macedonia was analysed by GC/FID/MS. Seventy five compounds were identified representing 90.02- 91.24% of the oil. The analysis has shown that the oils were rich in sesquiterpenе components (83.18-87.54% comprising elemol acetat (9.88%-21.98%, seline-11-en-4α-ol (9.81%-13.5%, selina-3,11-dien-6α-ol (6.42%-9.71% and elemol (5.57%-9.49% as major oxygen containing sesquiterpenes, followed by lower content of α-eudesmol acetat (3.24%-4.11%, α-chenopodiol (2.42%-5.43%, botrydiol (1.87-5.73% and α-chenopodiol-6-acetat (1.9%-4.73%.

  16. Thymus vulgaris essential oil: chemical composition and antimicrobial activity.

    Science.gov (United States)

    Borugă, O; Jianu, C; Mişcă, C; Goleţ, I; Gruia, A T; Horhat, F G

    2014-01-01

    The study was designed to determine the chemical composition and antimicrobial properties of the essential oil of Thymus vulgaris cultivated in Romania. The essential oil was isolated in a yield of 1.25% by steam distillation from the aerial part of the plant and subsequently analyzed by GC-MS. The major components were p-cymene (8.41%), γ-terpinene (30.90%) and thymol (47.59%). Its antimicrobial activity was evaluated on 7 common food-related bacteria and fungus by using the disk diffusion method. The results demonstrate that the Thymus vulgaris essential oil tested possesses strong antimicrobial properties, and may in the future represent a new source of natural antiseptics with applications in the pharmaceutical and food industry.

  17. Chemical vapor infiltration of TiB{sub 2} composites

    Energy Technology Data Exchange (ETDEWEB)

    Besmann, T.M. [Oak Ridge National Laboratory, TN (United States)

    1995-05-01

    This program is designed to develop a Hall-Heroult aluminum smelting cathode with substantially improved properties. The carbon cathodes in current use require significant anode-to-cathode spacing in order to prevent shorting, causing significant electrical inefficiencies. This is due to the non-wettability of carbon by aluminum which causes instability in the cathodic aluminum pad. It is suggested that a fiber reinforced-TiB{sub 2} matrix composite would have the requisite wettability, strength, strain-to-failure, cost, and lifetime to solve this problem. The approach selected to fabricate such a cathode material is chemical vapor infiltration (CVI). This program is designed to evaluate potential fiber reinforcements, fabricate test specimens, and test the materials in a static bath and lab-scale Hall cell.

  18. Antimicrobial activity of Iranian propolis and its chemical composition

    Directory of Open Access Journals (Sweden)

    Yaghoubi M.J.

    2007-04-01

    Full Text Available The objective of this study was to investigate the antimicrobial activity of ethanol extract of Iranian propolis on some microorganisms using disc diffusion method. The chemical composition of the propolis was also investigated using thin layer chromatography and spectrophotometric methods. Ethanol extract of propolis showed activity only against Gram-positives and fungi, whereas no activity was observed against Gram-negatives. Thin layer chromatography screening revealed the presence of pinocembrine, caffeic acid, kaempferol, phenethyl caffeate, chrysin, and galangin in Iranian propolis. The total flavonoid and phenolic contents were 7.3% and 36%, respectively, which suggests that the strong antimicrobial activity of Iranian propolis may be due to high levels of phenolic and flavonoid compounds.

  19. Regulating continent growth and composition by chemical weathering.

    Science.gov (United States)

    Lee, Cin-Ty Aeolus; Morton, Douglas M; Little, Mark G; Kistler, Ronald; Horodyskyj, Ulyana N; Leeman, William P; Agranier, Arnaud

    2008-04-01

    Continents ride high above the ocean floor because they are underlain by thick, low-density, Si-rich, and Mg-poor crust. However, the parental magmas of continents were basaltic, which means they must have lost Mg relative to Si during their maturation into continents. Igneous differentiation followed by lower crustal delamination and chemical weathering followed by subduction recycling are possible solutions, but the relative magnitudes of each process have never been quantitatively constrained because of the lack of appropriate data. Here, we show that the relative contributions of these processes can be obtained by simultaneous examination of Mg and Li (an analog for Mg) on the regional and global scales in arcs, delaminated lower crust, and river waters. At least 20% of Mg is lost from continents by weathering, which translates into >20% of continental mass lost by weathering (40% by delamination). Chemical weathering leaves behind a more Si-rich and Mg-poor crust, which is less dense and hence decreases the probability of crustal recycling by subduction. Net continental growth is thus modulated by chemical weathering and likely influenced by secular changes in weathering mechanisms.

  20. Chemical quality and regulatory compliance of drinking water in Iceland.

    Science.gov (United States)

    Gunnarsdottir, Maria J; Gardarsson, Sigurdur M; Jonsson, Gunnar St; Bartram, Jamie

    2016-11-01

    Assuring sufficient quality of drinking water is of great importance for public wellbeing and prosperity. Nations have developed regulatory system with the aim of providing drinking water of sufficient quality and to minimize the risk of contamination of the water supply in the first place. In this study the chemical quality of Icelandic drinking water was evaluated by systematically analyzing results from audit monitoring where 53 parameters were assessed for 345 samples from 79 aquifers, serving 74 water supply systems. Compliance to the Icelandic Drinking Water Regulation (IDWR) was evaluated with regard to parametric values, minimum requirement of sampling, and limit of detection. Water quality compliance was divided according to health-related chemicals and indicators, and analyzed according to size. Samples from few individual locations were benchmarked against natural background levels (NBLs) in order to identify potential pollution sources. The results show that drinking compliance was 99.97% in health-related chemicals and 99.44% in indicator parameters indicating that Icelandic groundwater abstracted for drinking water supply is generally of high quality with no expected health risks. In 10 water supply systems, of the 74 tested, there was an indication of anthropogenic chemical pollution, either at the source or in the network, and in another 6 water supplies there was a need to improve the water intake to prevent surface water intrusion. Benchmarking against the NBLs proved to be useful in tracing potential pollution sources, providing a useful tool for identifying pollution at an early stage. Copyright © 2016 Elsevier GmbH. All rights reserved.

  1. Engineering Characteristics of Chemically Treated Water-Repellent Kaolin

    OpenAIRE

    Youngmin Choi; Hyunwook Choo; Tae Sup Yun; Changho Lee; Woojin Lee

    2016-01-01

    Water-repellent soils have a potential as alternative construction materials that will improve conventional geotechnical structures. In this study, the potential of chemically treated water-repellent kaolin clay as a landfill cover material is explored by examining its characteristics including hydraulic and mechanical properties. In order to provide water repellency to the kaolin clay, the surface of clay particle is modified with organosilanes in concentrations (CO) ranging from 0.5% to 10%...

  2. Yield and chemical composition of fractions from fermented shrimp biowaste.

    Science.gov (United States)

    Narayan, Bhaskar; Velappan, Suresh Puthanveetil; Zituji, Sakhare Patiram; Manjabhatta, Sachindra Nakkerike; Gowda, Lalitha Ramakrishna

    2010-01-01

    Chemical composition of chitinous residue and fermentation liquor fractions, obtained from fermented shrimp biowaste, was evaluated in order to explore their potential for further utilization. Lyophilization of the liquor fraction obtained after fermentation resulted in a powder rich in both protein (30%) and carotenoids (217.18 +/- 2.89 microg/g). The yield of chitinous residue was 44% (w/w) whereas the yield of lyophilized powder was >25% (w/v). About 69% of total carotenoids were recovered by fermentation. Fermentation resulted in the removal of both protein as well as ash content from the shrimp biowaste, as indicated by approximately 92% deproteination and >76% demineralization, respectively. Post fermentation, the residue had a chitin content of >90%. The lyophilized liquor fraction had all the essential amino acids (except threonine) in quantities comparable to Food & Agriculture Organization/World Health Organization reference protein. The composition of fermentation liquor is indicative of its potential for application as an amino acid supplement in aquaculture feed formulations.

  3. [Chemical composition and biological quality of defatted hazelnut flour].

    Science.gov (United States)

    Villarroel, M; Biolley, E; Schneeberger, R; Ballester, D; Santibáñez, S

    1989-06-01

    The results of the chemical composition and biological quality of deffated hazel nut flour are shown. The samples analyzed contained significant amounts of proteins (19%) comparable to legume flour, higher than cereals and lower than deffated oleaginous flours. The oil extracted from the seed was analyzed and the average results obtained were the following: Refraction index, 1.47; saponification No. 184.8; iodine No. 85.0. The average composition of the fatty acids obtained by gas liquid chromatography was: Palmitic acid 2.3% Palmitoleic acid 37.0% Stearic acid 0.5% Oleic acid 39.5% Linoleic acid 6.9% Linolenic acid 1.1% Eicosanoic acid 2.3% Eicosaenoic acid 4.6% Docosenoic acid 3.4% Tetraeicosanoic acid 0.3% These results indicate a good-quality oil due to the low content of linolenic acid. The nutritive value of the deffated meal measured in the rats gave a net protein ratio (NPR) of 3.58, lower than the corresponding casein value (4.10). The true protein digestibility measured in the rat gave a value of 7.3%, compared to 95% for casein. The amounts of iron and phosphorous are comparatively lower than those reported for rape-seed meal and sunflower meal.

  4. Chemical Composition of Iran's Pistacia atlantica Cold-Pressed Oil

    Directory of Open Access Journals (Sweden)

    M. Saber-Tehrani

    2013-01-01

    Full Text Available The lipid fraction of Pistacia atlantica seeds was extracted for the first time by means of cold-press technique and analyzed for its chemical composition. The fatty acids, sterols, triacylglycerols (TAG, tocopherols, polyphenols, and pigments were identified and their concentrations were determined by means of reversed-phase high-performance liquid chromatography (RP-HPLC and gas chromatography (GC. Because of its high content of unsaturated fatty acids, it might prove to be of value in diets and it may be used as edible cooking or salad oils or for margarine manufacture. Pistacia atlantica seed oil has the unique sterols and tocopherols content providing source of natural antioxidants. The main triacylglycerols were SLL + PLO, SOL + POO, OOLn + PLL, OOO, and SOO. This paper examined the phenolic fraction of Pistacia atlantica seed oil. Moreover, caffeic acid followed by cinnamic acid, pinoresinol, vanillin, p-Coumaric acid, ferulic acid, and o-Coumaric acid was also determined. This paper presents the first investigation of chlorophyll's and carotene's composition in Pistacia atlantica seed oil. Furthermore, pheophytin a was the major component, followed by luteoxanthin, neoxanthin, violaxanthin, lutein, lutein isomers, chlorophyll a, chlorophyll a′, and pheophytin a′ were also determined.

  5. Chemical Composition and Antioxidant Capacity of Three Plum Cultivars

    Directory of Open Access Journals (Sweden)

    Sandra Voća

    2009-12-01

    Full Text Available The aim of this study was to determine the chemical composition and antioxidants capacity of three plum cultivars, namely ‘Top’, ‘Elena’ and ‘Bistrica’. Fruits were harvested and following parameters were determined: dry matter, total acids (TA, total soluble solids (TSS, pH, vitamin C, total phenols, nonflavonoids and antioxidant capacity. Differences between cultivars for most of the chemical parameters were observed. The cultivar ‘Bistrica’ showed higher values of dry matter, TSS, vitamin C and pH value, while ‘Top’ had higher total acids value and lowest TSS, dry matter, vitamin C and pH. Total phenolics content varied from 157.70 mg in ‘Elena’ to 344.10 mg in ‘Bistrica’, expressed as gallic acid equivalents (GAE, on fresh weight basis. ‘Top’ contains the highest amount of non-flavonoids among cultivars studied. Therefore, ‘Bistrica’ and ‘Top’ show the highest antioxidant capacity, as well. There were significant differences between total phenolics and non-flavonoids content between ‘Elena’ and other two cultivars, while antioxidant capacity showed no significant difference (p ≤ 0.05. Total antioxidant capacity of fruits ranged from 3.10 mmol/kg in ‘Elena’ to 3.17 mmol/kg in ‘Top’ and ‘Bistrica’.

  6. Chemical Composition Measurements of LAWA44 Glass Samples

    Energy Technology Data Exchange (ETDEWEB)

    Fox, K. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Edwards, T. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Riley, W. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2016-11-15

    The U.S. Department of Energy (DOE) Office of River Protection (ORP) has requested that the Savannah River National Laboratory (SRNL) provide expert evaluation and experimental work in support of the River Protection Project vitrification technology development. DOE is building the Hanford Tank Waste Treatment and Immobilization Plant (WTP) at the Hanford Site in Washington to remediate 55 million gallons of radioactive waste that is temporarily stored in 177 underground tanks. The low-activity waste (LAW) fraction will be partitioned from the high-level waste (HLW). Both the LAW and HLW will then be vitrified into borosilicate glass using Joule-heated ceramic melters. Efforts are being made to increase the loading of Hanford tank wastes in the glass while conforming to processing requirements and product quality regulations. DOE-ORP has requested that SRNL support the advancement of glass formulations and process control strategies in key technical areas, as defined in the Task Technical and Quality Assurance Plan (TTQAP). One of these areas is enhancing waste glass composition/property models and broadening the compositional regions over which those models are applicable. In this report, SRNL provides chemical analysis results for several samples of a simulated LAW glass, designated LAWA44, provided by Pacific Northwest National Laboratory (PNNL) as part of an ongoing development task. The objective of the PNNL task is to determine the durability of this glass using EPA Method 1313, which will include test participants at Vanderbilt University and the University of Sheffield. A report on the compositions of similar glasses (referred to as the EPA-series glasses) was issued in March 2016.

  7. Chemical and plasma surface modification of lignocellulose coconut waste for the preparation of advanced biobased composite materials.

    Science.gov (United States)

    Kocaman, Suheyla; Karaman, Mustafa; Gursoy, Mehmet; Ahmetli, Gulnare

    2017-03-01

    In this study, surface-modified grinded coconut waste (CW) particles were used as bio-fillers to prepare polymeric composite materials with enhanced properties. Epoxy resin modified with acrylated and epoxidized soybean oil (AESO) was used as the polymer matrix. Two different strategies, namely chemical treatment and plasma enhanced chemical vapor deposition (PECVD) were utilized to modify the surface of CW particles for using them as compatible bio-fillers in composite preparation. Chemical modification involved the treatment of CW particles in a highly alkali NaOH solution, while PECVD modification involved coating of a thin film of hydrophobic poly(hexafluorobutyl acrylate) (PHFBA) around individual CW particle surfaces. Untreated and surface-modified CW particles were used in 10-50wt% for preparation of epoxy composites. FTIR analysis was performed to study the effect of modification on the structures of particles and as-prepared composites. The composite morphologies were investigated by XRD and SE. TGA test was conducted to study the thermal behavior of the composites. Also, the effects of CW particle surface modification on the mechanical and water sorption properties of epoxy resin composites were investigated in detail. It was observed that PECVD-treated CW particles had much more positive effects on the thermal, mechanical, wettability and flammability properties of composites. Copyright © 2016 Elsevier Ltd. All rights reserved.

  8. Proposed human stratum corneum water domain in chemical absorption.

    Science.gov (United States)

    Zhu, Hanjiang; Jung, Eui-Chang; Hui, Xiaoying; Maibach, Howard

    2016-08-01

    Compounds with varying physical and chemical properties may have different affinities to the stratum corneum (SC) and/or its intercellular lipids, keratin protein, and possible water domains. To better understand the mechanism of percutaneous absorption, we utilized 21 carbon-14 labeled chemicals, with wide hydrophilicity (log P = -0.05 to 6.17), and quantified their absorption/adsorption properties for a short incubation time (15 min) with regards to intact SC membrane, delipidized SC membrane and SC lipid. A facile method was developed for SC/lipid absorption, providing a more equivalent procedure and comparable data. SC lipid absorption of chemical solutes positively correlated with the octanol/water partition coefficient (log P). Differences between the percent dose of chemical absorption to intact SC and the total percent dose contributed by the protein and lipid domains suggest the possibility and significance of a water domain. Absorption rate experiments showed a longer lag time for intact SC than for delipidized SC or SC lipid, suggesting that the water domain may delay chemical binding to protein and lipid domains, and may be a factor in the resistance of many chemicals to current decontamination methods. Copyright © 2015 John Wiley & Sons, Ltd.

  9. A study on natural and anthropogenic changes of chemical compositions in the Nakdong river in Korea

    Science.gov (United States)

    Kim, J.; Choi, H. B.; Choi, U. K.; Lee, J.

    2016-12-01

    The Nakdong river is the longest river in South Korea and about sixty metalliferous mines have been operated since the 1930s. So, the environmental issues have occurred due to mine tailings, which were derived from mining activities located in the basin. In this study, thirty three river samples were collected from branches affected by tailings of each eleven-mine and main stream that meets the branches. Field parameters were measured in situ and major cations, anions, trace elements and water isotopes were determined at the Korea Basic Science Institute. The purpose of this study was, thus, to evaluate whether the mines positioned upper catchment affect on chemical variations of the Nakdong river where bedrocks mostly consist of quartize. Most water samples that dominantly were influenced by chemical weathering are on a weathering line [HCO3+2 SO4 : 2 (Ca + Mg) = 1:1]. However, six samples have shown excess sulfate that were below the 1:1 line and these samples were mostly from the streams around the Seokpo refinery and Sambo mine branch, which were consistent with the results by principle component analysis (PCA). Also, three samples near farmlands can be separated into a group by PCA because of high concentrations of nitrate. Based on the chemical and PCA results, we believe that the chemical compositions of the river have been affected by the mine tailings and agricultural contaminants. However, it is necessary to understand how the contaminants were derived from other inputs, such as synthetic fertilizer, soil, and atmospheric deposition.

  10. A New Mathematical Formulation of the Governing Equations for the Chemical Compositional Simulation

    CERN Document Server

    Bekbauov, Bakhbergen E; Berdyshev, Abdumauvlen

    2015-01-01

    It is the purpose of this work to develop new approach for chemical compositional reservoir simulation, which may be regarded as a sequential method. The development process can be roughly divided into the following two stages: (1) development of a new mathematical formulation for the sequential chemical compositional reservoir simulation, (2) implementation of a sequential solution approach for chemical compositional reservoir simulation based on the formulation described in this paper. This paper addresses the first stage of the development process by presenting a new mathematical formulation of the chemical compositional reservoir flow equations for the sequential simulation. The newly developed mathematical formulation is extended from the model formulation used in existing chemical compositional simulators. During the model development process, it was discovered that the currently used chemical compositional model estimates the adsorption effect on the transport of a component reasonably well but it viol...

  11. Chemical composition, functional and sensory characteristics of wheat-taro composite flours and biscuits.

    Science.gov (United States)

    Himeda, Makhlouf; Njintang Yanou, Nicolas; Fombang, Edith; Facho, Balaam; Kitissou, Pierre; Mbofung, Carl M F; Scher, Joel

    2014-09-01

    The physicochemical, alveographic and sensory characteristics of precooked taro-wheat composite flours and their biscuits were investigated. A 2x7 factorial design consisting of two varieties of taro flour (Red Ibo Ngaoundere, RIN, and egg-like varieties) and 7 levels of wheat substitutions (0, 5, 10, 15, 20, 25 and 30 %) was used for this purpose. It was observed that water absorption capacity (range 95-152 g/100 g), water solubility index (range 18.8-29.5 g/100 g) and swelling capacity (range 125.4-204.6 mL/100 g) of composite flours significantly (p < 0.05) increased with increase in taro level. Conversely the dough elasticity index (range 59.8-0 %), extensibility (78-22 mm) and strength (range 281-139 × 10(-4) joules) significantly (p < 0.05) diminished with increase in wheat substitution. Up to 10 % substitution with RIN taro flour and 15 % with egg-like taro flour, the composite taro-wheat dough exhibited elasticity indices acceptable for the production of baking products, whereas at all levels of taro substitution, the composite biscuits samples were either acceptable as or better (5-10 % substitution with RIN flour) than 100 % wheat biscuit.

  12. Chemical composition of atmospheric aerosols resolved via positive matrix factorization

    Science.gov (United States)

    Äijälä, Mikko; Junninen, Heikki; Heikkinen, Liine; Petäjä, Tuukka; Kulmala, Markku; Worsnop, Douglas; Ehn, Mikael

    2017-04-01

    Atmospheric particulate matter is a complex mixture of various chemical species such as organic compounds, sulfates, nitrates, ammonia, chlorides, black carbon and sea salt. As aerosol chemical composition strongly influences aerosol climate effects (via cloud condensation nucleus activation, hygroscopic properties, aerosol optics, volatility and condensation) as well as health effects (toxicity, carcinogenicity, particle morphology), detailed understanding of atmospheric fine particle composition is widely beneficial for understanding these interactions. Unfortunately the comprehensive, detailed measurement of aerosol chemistry remains difficult due to the wide range of compounds present in the atmosphere as well as for the miniscule mass of the particles themselves compared to their carrier gas. Aerosol mass spectrometer (AMS; Canagaratna et al., 2007) is an instrument often used for characterization of non-refractive aerosol types: the near-universal vaporization and ionisation technique allows for measurement of most atmospheric-relevant compounds (with the notable exception of refractory matter such as sea salt, black carbon, metals and crustal matter). The downside of the hard ionisation applied is extensive fragmentation of sample molecules. However, the apparent loss of information in fragmentation can be partly offset by applying advanced statistical methods to extract information from the fragmentation patterns. In aerosol mass spectrometry statistical analysis methods, such as positive matrix factorization (PMF; Paatero, 1999) are usually applied for aerosol organic component only, to keep the number of factors to be resolved manageable, to retain the inorganic components for solution validation via correlation analysis, and to avoid inorganic species dominating the factor model. However, this practice smears out the interactions between organic and inorganic chemical components, and hinders the understanding of the connections between primary and

  13. Mechanical properties of uniaxial natural fabric Grewia tilifolia reinforced epoxy based composites: Effects of chemical treatment

    CSIR Research Space (South Africa)

    Jayaramudu, J

    2014-07-01

    Full Text Available The effects of chemical treatment on the mechanical, morphological, and chemical resistance properties of uniaxial natural fabrics, Grewia tilifolia/epoxy composites, were studied. In order to enhance the interfacial bonding between the epoxy matrix...

  14. Chemical composition of olive oils of the cultivar Colombaia

    Directory of Open Access Journals (Sweden)

    Zunin, P.

    2005-12-01

    Full Text Available The chemical composition of monovarietal olive oils from the cultivar Colombaia was studied. Free acidity, peroxide value and UV absorbance attested to the good quality of the analyzed oils. Their fatty acid composition appeared to be quite different from the typical fatty acid profile of olive oils from Liguria but met the limits reported in the EC Regulations for olive oils. On the contrary, the amounts of Δ7-stigmastenol were often higher than the 0.5 % limit set by EC Regulations and total ß-sitosterol was below the minimum 93 % limit. The composition of polar compounds and of the volatile fraction was representative of the peculiar organoleptic character of these oils. Thus, the anomalous sterol composition of the monovarietal oils from the cultivar Colombaia calls for blending with other oils. Moreover, the use of these oils for the production of PDO oils “Riviera Ligure” must also be carefully controlled because it changes their nutritional and sensorial featuresEn este trabajo se ha estudiado la composición química de aceites de oliva mono-varietales de la variedad Colombaia. La acidez libre, el índice de peróxidos y la absorción UV confirmaron la buena calidad de los aceites analizados. Su composición en ácidos grasos resultó bastante diferente del perfil típico de ácidos grasos de los aceites de oliva virgen de la región de Liguria, pero se mantuvo dentro de los límites establecidos por los Reglamentos EC para aceites de oliva. Por otro lado, las cantidades de Δ7-estigmastenol resultaron normalmente superiores al 0.5 % del límite fijado por los Reglamentos EC y el ß-sitosterol total fue inferior al 93 % del límite mínimo. La composición en compuestos polares y de la fracción volátil confirmó las características organolépticas peculiares de estos aceites. Por tanto, la composición esterólica anómala de los aceites mono-varietales de la variedad Colombaia hace necesaria una mezcla con otros

  15. Trace organic chemicals contamination in ground water recharge.

    Science.gov (United States)

    Díaz-Cruz, M Silvia; Barceló, Damià

    2008-06-01

    Population growth and unpredictable climate changes will pose high demands on water resources in the future. Even at present, surface water is certainly not enough to cope with the water requirement for agricultural, industrial, recreational and drinking purposes. In this context, the usage of ground water has become essential, therefore, their quality and quantity has to be carefully managed. Regarding quantity, artificial recharge can guarantee a sustainable level of ground water, whilst the strict quality control of the waters intended for recharge will minimize contamination of both the ground water and aquifer area. However, all water resources in the planet are threatened by multiple sources of contamination coming from the extended use of chemicals worldwide. In this respect, the environmental occurrence of organic micropollutants such as pesticides, pharmaceuticals, industrial chemicals and their metabolites has experienced fast growing interest. In this paper an overview of the priority and emerging organic micropollutants in the different source waters used for artificial aquifer recharge purposes and in the recovered water is presented. Besides, some considerations regarding fate and removal of such compounds are also addressed.

  16. Chemical analysis of selected pothole water sources in Southwestern National Parks, Monuments, and Recreation Areas

    Energy Technology Data Exchange (ETDEWEB)

    Gladney, E.S.; Ferenbaugh, R.W.; Bell, M.G.; Burns, C.; Morgan, J.D.; Nickell, E.J. [Los Alamos National Lab., NM (United States); Graham, T. [US Department of the Interior, National Park Service (United States)

    1993-10-01

    Environmental data related to the evaluation of inorganic air pollution input to pothole ecosystems in the desert Southwest have been collected over the past several years. Chemical composition of pothole waters and associated sediments are reported. The enrichment factor approach has been applied to the sediments in an effort to identify elemental levels that diverge from mean crustal abundances. These data provide a baseline for determining changes in elemental concentration and enrichment status in the future.

  17. Characterization of hollow chemical garden fibers from metal salts and water glass

    OpenAIRE

    Balköse, Devrim; Çakıcıoğlu Özkan, Seher Fehime; Köktürk, Uğur; Ulutan, Sevgi; Ülkü, Semra; Nişli, Gürel

    2002-01-01

    Hollow fibers formed from water glass and metal salts of IIA(Ca), VIIB(Fe, Co, Ni) and IB(Cu) groups were characterised in this study. Fragile fibres obtained herein broke down into small pieces during isolation and drying. Quantitative information about morphology, chemical composition and surface structure of the fibres were obtained. The diameter and wall thickness of the fibers were around 50 μ and 3 μ. respectively. They had particulate inner and smooth outer surfaces. Fibers had variabl...

  18. Chemical composition, carbohydrate digestibility, and antioxidant capacity of cooked black bean, chickpea, and lentil Mexican varieties

    National Research Council Canada - National Science Library

    Silva-Cristobal, L; Osorio-Díaz, P; Tovar, J; Bello-Pérez, L. A

    2010-01-01

    .... The cooked seeds of three Mexican pulses (black bean, chickpea, and lentil) were evaluated regarding their chemical composition, in vitro starch digestibility, polyphenols content and antioxidant capacity...

  19. Chemical composition of the circumstellar disk around AB Aurigae

    Science.gov (United States)

    Pacheco-Vázquez, S.; Fuente, A.; Agúndez, M.; Pinte, C.; Alonso-Albi, T.; Neri, R.; Cernicharo, J.; Goicoechea, J. R.; Berné, O.; Wiesenfeld, L.; Bachiller, R.; Lefloch, B.

    2015-06-01

    Aims: Our goal is to determine the molecular composition of the circumstellar disk around AB Aurigae (hereafter, AB Aur). AB Aur is a prototypical Herbig Ae star and the understanding of its disk chemistry is paramount for understanding the chemical evolution of the gas in warm disks. Methods: We used the IRAM 30-m telescope to perform a sensitive search for molecular lines in AB Aur as part of the IRAM Large program ASAI (a chemical survey of Sun-like star-forming regions). These data were complemented with interferometric observations of the HCO+ 1→0 and C17O 1→0 lines using the IRAM Plateau de Bure Interferometer (PdBI). Single-dish and interferometric data were used to constrain chemical models. Results: Throughout the survey, several lines of CO and its isotopologues, HCO+, H2CO, HCN, CN, and CS, were detected. In addition, we detected the SO 54→33 and 56→45 lines, confirming the previously tentative detection. Compared to other T Tauri and Herbig Ae disks, AB Aur presents low HCN 3→2/HCO+ 3→2 and CN 2→1/HCN 3→2 line intensity ratios, similar to other transition disks. AB Aur is the only protoplanetary disk detected in SO thus far, and its detection is consistent with interpretation of this disk being younger than those associated with T Tauri stars. Conclusions: We modeled the line profiles using a chemical model and a radiative transfer 3D code. Our model assumes a flared disk in hydrostatic equilibrium. The best agreement with observations was obtained for a disk with a mass of 0.01 M⊙, Rin = 110 AU, Rout = 550 AU, a surface density radial index of 1.5, and an inclination of 27°. The intensities and line profiles were reproduced within a factor of ˜2 for most lines. This agreement is reasonable considering the simplicity of our model that neglects any structure within the disk. However, the HCN 3→2 and CN 2→1 line intensities were predicted to be more intense by a factor of >10. We discuss several scenarios to explain this

  20. Quantification of aerosol chemical composition using continuous single particle measurements

    Science.gov (United States)

    Jeong, C.-H.; McGuire, M. L.; Godri, K. J.; Slowik, J. G.; Rehbein, P. J. G.; Evans, G. J.

    2011-07-01

    Mass concentrations of sulphate, nitrate, ammonium, organic carbon (OC), elemental carbon (EC) were determined from real time single particle data in the size range 0.1-3.0 μm measured by an Aerosol Time-of-Flight Mass Spectrometer (ATOFMS) at urban and rural sites in Canada. To quantify chemical species within individual particles measured by an ATOFMS, ion peak intensity of m/z -97 for sulphate, -62 for nitrate, +18 for ammonium, +43 for OC, and +36 for EC were scaled using the number and size distribution data by an Aerodynamic Particle Sizer (APS) and a Fast Mobility Particle Sizer (FMPS). Hourly quantified chemical species from ATOFMS single-particle analysis were compared with collocated fine particulate matter (aerodynamic diameter PM2.5) chemical composition measurements by an Aerosol Mass Spectrometer (AMS) at a rural site, a Gas-Particle Ion Chromatograph (GPIC) at an urban site, and a Sunset Lab field OCEC analyzer at both sites. The highest correlation was found for nitrate, with correlation coefficients (Pearson r) of 0.89 (ATOFMS vs. GPIC) and 0.85 (ATOFMS vs. AMS). ATOFMS mass calibration factors, determined for the urban site, were used to calculate mass concentrations of the major PM2.5 chemical components at the rural site near the US border in southern Ontario. Mass reconstruction using the ATOFMS mass calibration factors agreed very well with the PM2.5 mass concentrations measured by a Tapered Element Oscillating Microbalance (TEOM, r = 0.86) at the urban site and a light scattering monitor (DustTrak, r = 0.87) at the rural site. In the urban area nitrate was the largest contributor to PM2.5 mass in the winter, while organics and sulphate contributed ~64 % of the summer PM2.5 in the rural area, suggesting a strong influence of regional/trans-boundary pollution. The mass concentrations of five major species in ten size-resolved particle-types and aerosol acidity of each particle-type were determined for the rural site. On a mass basis sulphate

  1. The Relationship of Culture Media Composition and Chemical Composition on Spirulina sp for Metal Ion Adsorbent

    Directory of Open Access Journals (Sweden)

    Hilda Zulkifli

    2016-12-01

    Full Text Available The analysis relationship of Spirulina sp medium with chemical composition has been conducted. Chemical analysis was performed using X-Ray Fluorescence analysis. Furthermore, potention of Spirulina sp as adsorbent of metal ions was analyzed using FTIR spectroscopy. The results showed that metals such as Zn, Fe, Mn, Ca, Cu, and Mo were mainly metals in Spirulina sp. These metals were not correlated with cultivated medium of Spirulina sp. Analysis of potention Spirulina sp as metal ions adsorbent showed that Spirulina sp has functional groups –C=O and –OH as ligand. Intercation of metal ions Cu(II and Cr(III with Spirulina sp indicated that metal ions bond to –C=O functional group.

  2. Improved prediction of vegetation composition in NW European softwater lakes by combining location, water and sediment chemistry

    DEFF Research Database (Denmark)

    Pulido Pérez, Cristina; Jensen, Kaj Sand; Lucassen, Esther C.H.E.T.;

    2012-01-01

    composition. This complex analysis can also account for high sediment variability in the littoral zone of individual lakes, by using site-specific physico-chemical sediment factors, and offer better predictions of vegetation composition when lake water chemistry is relatively homogeneous among lakes within...

  3. CHEMICAL REACTIONS SIMULATED BY GROUND-WATER-QUALITY MODELS.

    Science.gov (United States)

    Grove, David B.; Stollenwerk, Kenneth G.

    1987-01-01

    Recent literature concerning the modeling of chemical reactions during transport in ground water is examined with emphasis on sorption reactions. The theory of transport and reactions in porous media has been well documented. Numerous equations have been developed from this theory, to provide both continuous and sequential or multistep models, with the water phase considered for both mobile and immobile phases. Chemical reactions can be either equilibrium or non-equilibrium, and can be quantified in linear or non-linear mathematical forms. Non-equilibrium reactions can be separated into kinetic and diffusional rate-limiting mechanisms. Solutions to the equations are available by either analytical expressions or numerical techniques. Saturated and unsaturated batch, column, and field studies are discussed with one-dimensional, laboratory-column experiments predominating. A summary table is presented that references the various kinds of models studied and their applications in predicting chemical concentrations in ground waters.

  4. Changes of Chemical Composition and Crystalline of Compressed Chinese Fir Wood in Heating Fixation

    Institute of Scientific and Technical Information of China (English)

    Tang Xiaoshu; Zhao Guangjie; Nakao Tetsuya

    2004-01-01

    The changes in relative crystalline, chemical composition and internal structure of compressed Chinese fir wood after different heating fixations were found strictly related to fixation conditions. The compressed wood powders were fixed either by heating at different temperatures all resulting in a 10% recovery, or by incubating at 180 °C for different periods with subsequent recovery levels. Both X-ray diffraction and infrared absorption of those samples have been measured. Relative crystalline increases at early stage of heating fixation, and then decreased gradually. Hemicellulose and lignin decomposition were induced by the fixation process, especially at 180 °C, and lignin was degraded actively. Furthermore, absorbed water was lost after heating, but cellulose did not change markedly. Although different fixation pathways can result in the same recovery level, the major chemical reactions underlying them vary, which is consistent with the difference of fixation mechanisms.

  5. Chemical and Physical Indicators in Drinking Water and Water Sources of Boroujerd Using Principal Components Analysis

    Directory of Open Access Journals (Sweden)

    Darabi , M. (MSC

    2014-05-01

    Full Text Available Background and Objective: Quality control of drinking water is important for maintaining health and safety of consumers, and the first step is to study the water quality variables. This study aimed to evaluate the chemical and physical indicators, water quality variables and qualitative classification of drinking water stations and water sources in Boroujerd. Material and Methods: This descriptive-cross sectional study was conducted on 70 samples of drinking water and 10 samples from sources in 2011-2012. Nine Water quality variables were measured and coded using STATISTICA10 Software. Principal component analysis (PCA was performed for qualitative classification of water samples and determination of water quality variables. Results: Based on PCA, chemical variables such as fluoride, nitrate, total hardness and iron, and physical variables such as pH and TDS were paramount importance to water quality. According to T-test, the average concentration of fluoride and iron, and the turbidity in all samples were significantly less than the standard. But other variables were up to standard. Conclusion: For the large water quality data, the use of PCA to identify the main qualitative variables and to classify physical and chemical variables can be used as an effective way in water quality management. Keywords: Physical and Chemical Indicators, Drinking Water and Sources, Boroujerd, Principal Component Analysis

  6. [Formation mechanism and chemical safety of nonintentional chemical substances present in chlorinated drinking water and wastewater].

    Science.gov (United States)

    Onodera, Sukeo

    2010-09-01

    This paper reviews the formation mechanism and chemical safety of nonintentional chemical substances (NICS) present in chlorine-treated water containing organic contaminants. Undesirable compounds, i.e., NICS, may be formed under certain conditions when chlorine reacts with organic matter. The rate and extent of chlorine consumption with organics are strongly dependent on their chemical structures, particularly whether double bonds or sulfur and nitrogen atoms occur in the molecules. Organothiophosphorus pesticides (P=S type) are easily oxidized to their phosphorus compounds (P=O type) in chlorinated water containing HOCl as little as 0.5 mg/l, resulting in an increase in cholinesterase-inhibitory activity. Chlorination of phenols in water also produces a series of highly chlorinated compounds, including chlorophenols, chloroquinones, chlorinated carboxylic acids, and polychlorinated phenoxyphenols (PCPPs). In some of these chloroquinones, 2,6-dichloroalkylsemiquinones exhibit a strong mutagenic response as do positive controls used in the Ames test. 2-phenoxyphenols in these PCPPs are particularly interesting, as they are present in the chlorine-treated phenol solution and they are also precursors (predioxins) of the highly toxic chlorinated dioxins. Polynuclear aromatic hydrocarbons (PAHs) were found to undergo chemical changes due to hypochlorite reactions to give chloro-substituted PAHs, oxygenated (quinones) and hydroxylated (phenols) compounds, but they exhibit a lower mutagenic response. In addition, field work was performed in river water and drinking water to obtain information on chemical distribution and their safety, and the results are compared with those obtained in the model chlorination experiments.

  7. Chemical composition and its origin in spring rainwater over Taihu Lake

    Institute of Scientific and Technical Information of China (English)

    WANG Xuemei; YANG Longyuan; QIN Boqiang; JI Lingling

    2006-01-01

    Chemical compositions of rainwater collected in three stations in Taihu Lake in Jiangsu Province, China between March and May 2003 were analyzed through numerical simulations and field observation data. In terms of average ion deposition rate in spring at the air/water interface, of all anions,that of so2-4 was the largest followed by NO-3, whereas among all cations, Ca2+ concentration and the rate was the largest, and then NH4+ was the next. The correlation of ion concentration indicated that the catchment of the lake has been artificially polluted considerably. Using backward trajectory analysis, the raining water in the stations in Taihu Lake was classified. In spring, marine-originated rain is the main contribution to this area, counting for 92.7% of the total precipitation, in which SO2-4, NO-3 and NH+4 contributed 89.2%, 88.1%, and 88.3% respectively to the total spring-rain chemicals, whereas land-originated rains contributed in a small amount. However, the ion concentration in the land-originated rain was higher and acidic, causing considerable harm to local ecosystem. The analysis of backward trajectory analysis shows that three types of air masses influenced the chemical composition of the lake water, namely, air mass from NE direction, air mass from SW direct ion, and local air mass. Although the local air masses often produced small rainfall amount, but the nature of high ion concentration and high acidity impacted the local ecosystem remarkably. The ion concentration and rainfall from long-distance boreal air mass are clearly greater than those in austral air.

  8. Chemical composition and antioxidant activities of Broussonetia papyrifera fruits.

    Directory of Open Access Journals (Sweden)

    Jie Sun

    Full Text Available Fruits of Broussonetia papyrifera from South China were analyzed for their total chemical composition, and antioxidant activities in ethanol and aqueous extracts. In the fruit of this plant, the crude protein, crude fat and carbohydrates was 7.08%, 3.72% and 64.73% of dry weight, respectively. The crude protein, crude fat and carbohydrates were 15.71%, 20.51% and 36.09% of dry weight, respectively. Fatty acid and amino acid composition of the fruit were analyzed. Unsaturated fatty acid concentration was 70.6% of the total fatty acids. The percentage of the essential amino acids (EAAs was 40.60% of the total amino acids. Furthermore, B. papyrifera fruit are rich in many mineral elements and vitamins. Total phenolic content was assessed using the Folin-Ciocalteau assay, whereas antioxidant activities were assessed by measuring the ability of the two extracts to scavenge DPPH radicals, inhibit peroxidation, and chelate ferric ions. Their reducing power was also assessed. Results indicated that the aqueous extract of B. papyrifera was a more potent reducing agent and radical-scavenger than the ethanol extract. GC-MS analysis of the ethanol extract showed the presence of some acid-containing compounds. The changes in total phenolic content and antioxidant capacity in B. papyrifera from four different regions grown under normal conditions were assessed. The antioxidant activity of different extracts was positively associated with their total phenolic content. These results suggest that the fruit of B. papyrifera could be used in dietary supplement preparations, or as a food additive, for nutritional gain, or to prevent oxidation in food products.

  9. Potential Chemical Effects of Changes in the Source of Water Supply for the Albuquerque Bernalillo County Water Utility Authority

    Science.gov (United States)

    Bexfield, Laura M.; Anderholm, Scott K.

    2008-01-01

    Chemical modeling was used by the U.S. Geological Survey, in cooperation with the Albuquerque Bernalillo County Water Utility Authority (henceforth, Authority), to gain insight into the potential chemical effects that could occur in the Authority's water distribution system as a result of changing the source of water used for municipal and industrial supply from ground water to surface water, or to some mixture of the two sources. From historical data, representative samples of ground-water and surface-water chemistry were selected for modeling under a range of environmental conditions anticipated to be present in the distribution system. Mineral phases calculated to have the potential to precipitate from ground water were compared with the compositions of precipitate samples collected from the current water distribution system and with mineral phases calculated to have the potential to precipitate from surface water and ground-water/surface-water mixtures. Several minerals that were calculated to have the potential to precipitate from ground water in the current distribution system were identified in precipitate samples from pipes, reservoirs, and water heaters. These minerals were the calcium carbonates aragonite and calcite, and the iron oxides/hydroxides goethite, hematite, and lepidocrocite. Several other minerals that were indicated by modeling to have the potential to precipitate were not found in precipitate samples. For most of these minerals, either the kinetics of formation were known to be unfavorable under conditions present in the distribution system or the minerals typically are not formed through direct precipitation from aqueous solutions. The minerals with potential to precipitate as simulated for surface-water samples and ground-water/surface-water mixtures were quite similar to the minerals with potential to precipitate from ground-water samples. Based on the modeling results along with kinetic considerations, minerals that appear most likely to

  10. Chemical Composition of Urban Street Sediments and Its Sources

    Institute of Scientific and Technical Information of China (English)

    Cen Kuang; Hou Min; Thomas Neumann; Stefan Norra; Doris Stüben

    2004-01-01

    The distribution and the concentrations of various chemical elements in street sediments were investigated along a rural-urban boundary in Beijing, China. The statistical factor analysis of the data concerned identifies two anthropogenic sources responsible for the contamination of Beijing air. The first source is a steel factory in the western part of Beijing. From this source, Mn, Fe and Ti were emitted into the atmosphere through chimneys and by wind from coal heaps used as the primary energy source for the factory. The second source is a combination of traffic, domestic heating and some small factories in the center of Beijing urban area discharging Cu, Pb, Zn and Sn. Grain-size analyses show that most of the metals in the road dust have higher concentrations in the small grain-size fraction <0.125 mm, which is the severest case because these small particles with larger specific surface area and high heavy metal contents fly up easily and float in the air for a long time. Besides the anthropogenic contamination, such elements as Y, Zr, Nb, Ce and Rb are derived mainly both from natural soils and from the deserts. This is supported by mineral-phase analysis, which shows a clear imprint of materials in road dusts coming from the west China deserts. Our results clearly show that the chemical compositions of the urban road dusts can be used to identify distinctive sources responsible for the contamination mentioned above. The study shows that the chemistry of road dusts is an important monitor to assess the contamination in the urban environment.

  11. Reservoir sediments: a sink or source of chemicals at the surface water-groundwater interface.

    Science.gov (United States)

    Ammar, Rawaa; Kazpard, Véronique; Wazne, Mahmoud; El Samrani, Antoine G; Amacha, Nabil; Saad, Zeinab; Chou, Lei

    2015-09-01

    This study delineates the physical, chemical, and biological effects resulting from anthropogenic and endogenic activities in a sensitive dammed reservoir situated in a semi-arid region. The reservoir is characterized by two major flow regimes: a wet fill hydrologic regime and a dry spill one. A seasonal sampling campaign was carried out over a period of 2 years (2011-2013) where water samples were collected across the water column and from piezometers just outside the perimeter of the reservoir. Similarly, sediments were collected from the corresponding areas beneath the water column. The water samples were analyzed for environmental isotopic ratios, elemental composition, and physical, biological and chemical parameters, whereas the sediment and algal samples were subjected to physical, mineralogical, spectroscopic, and microscopic analyses. This investigation indicated that the dam had resulted in the alteration of the biogeochemical cycle of nutrients as well as the degradation of the sediment and water quality. The hydrological and biogeochemical processes were found to induce vertical downward transport of chemicals towards the fine grained calcareous sediments during the fill mode, whereas the sediments acted as a source of a chemical flux upward through the water column and downward towards the groundwater during the spill mode. The geomorphological characteristics of the reservoir enhanced the strong hydrological connectivity between the surface water and the groundwater where the reservoir responded quickly to natural and anthropogenic changes in the upper watershed. The water and sediments in the sensitive spill mode were of poor quality and should receive more attention due to the potential hazard for the associated hydro-project and the sustainability of the agricultural soil in the long term. Thus, a safe water and sediment management plan should be implemented in order to improve the dam functionality and to safeguard the precious water resources.

  12. Study of morphology, chemical, and amino acid composition of red deer meat

    Directory of Open Access Journals (Sweden)

    Eleonora Okuskhanova

    2017-06-01

    Full Text Available Aim: The aim of this study was to evaluate red deer (maral meat quality based on chemical composition, pH, water-binding capacity (WBC, and amino acid content. Materials and Methods: Maral meat surface morphology measurements were obtained by scanning electron microscopy. Active acidity (pH was determined by potentiometry. Samples were analyzed for WBC by exudation of moisture to a filter paper by the application of pressure. Chemical composition (moisture, protein, fat, and ash fractions was obtained by drying at 150°C and by extraction, using ethylic ether, and ashing at 500-600°C. The amino acid composition was obtained by liquid chromatography. Results: Maral meat, with a pH of 5.85 and an average moisture content of 76.82%, was found to be low in fat (2.26%. Its protein content was 18.71% while its ash content was 2.21%. The amino acid composition showed that lysine (9.85 g/100 g, threonine (5.38 g/100 g, and valine (5.84 g/100 g predominated in maral meat, while phenylalanine (4.08 g/100 g, methionine (3.29 g/100 g, and tryptophan (0.94 g/100 g were relatively low in maral meat compared to other meats. The average WBC was found to be 65.82% and WBC was found to inversely correlate with moisture content. Conclusion: Low-fat content, high mineral content, and balanced amino-acid composition qualify maral meat as a worthy dietary and functional food.

  13. Evaluation of the performance of four chemical transport models in predicting the aerosol chemical composition in Europe in 2005

    NARCIS (Netherlands)

    Prank, M.; Sofiev, M.; Tsyro, S.; Hendriks, C.; Semeena, V.; Francis, X.V.; Butler, T.; Gon, H.D. van der; Friedrich, R.; Hendricks, J.; Kong, X.; Lawrence, M.; Righi, M.; Samaras, Z.; Sausen, R.; Kukkonen, J.; Sokhi, R.

    2016-01-01

    Four regional chemistry transport models were applied to simulate the concentration and composition of particulate matter (PM) in Europe for 2005 with horizontal resolution 20 km. The modelled concentrations were compared with the measurements of PM chemical composition by the European Monitoring

  14. Stable isotope and chemical compositions of European and Australasian ciders as a guide to authenticity.

    Science.gov (United States)

    Carter, James F; Yates, Hans S A; Tinggi, Ujang

    2015-01-28

    This paper presents a data set derived from the analysis of bottled and canned ciders that may be used for comparison with suspected counterfeit or substitute products. Isotopic analysis of the solid residues from ciders (predominantly sugar) provided a means to determine the addition of C4 plant sugars. The added sugars were found to comprise cane sugar, high-fructose corn syrup, glucose, or combinations. The majority of ciders from Australia and New Zealand were found to contain significant amounts of added sugar, which provided a limited means to distinguish these ciders from European ciders. The hydrogen and oxygen isotopic compositions of the whole ciders (predominantly water) were shown to be controlled by two factors, the water available to the parent plant and evaporation. Analysis of data derived from both isotopic and chemical analysis of ciders provided a means to discriminate between regions and countries of manufacture.

  15. Compositions and methods for removing arsenic in water

    Science.gov (United States)

    Gadgil, Ashok Jagannth [El Cerrito, CA

    2011-02-22

    Compositions and methods and for contaminants from water are provided. The compositions comprise ferric hydroxide and ferric oxyhydride coated substrates for use in removing the contaminant from the water. Contacting water bearing the contaminant with the substrates can substantially reduce contaminant levels therein. Methods of oxidizing the contaminants in water to facilitate their removal by the ferric hydroxide and ferric oxyhydride coated substrates are also provided. The contaminants include, but are not limited to, arsenic, selenium, uranium, lead, cadmium, nickel, copper, zinc, chromium and vanadium, their oxides and soluble salts thereof.

  16. Soursop (Annona muricata) vinegar production and its chemical compositions

    Science.gov (United States)

    Ho, Chin Wai; Lazim, Azwan Mat; Fazry, Shazrul; Zaki, Umi Kalsum Hj Hussain; Lim, Seng Joe

    2016-11-01

    Vinegar is a liquid product that undergoes double fermentations, which are alcoholic and acetous fermentation. Sugar source was converted to ethanol in alcoholic fermentation, meanwhile ethanol was oxidised to acetic acid during acetous fermentation. Soursop (Annona muricata) was the starting material in this study, as it is easily available in Malaysia. Its highly aromatic, juicy and distinctive flavours enables the production of high quality vinegar. The objective of this research is to produce good quality soursop vinegar as an innovative method to preserve and utilise the soursop fruit in Malaysia and to determine its chemical compositions. It was found that the sugar content reduces over time, and it is inversely proportional to the ethanol concentration, due to the production of ethanol from sugar. Acetic acid was also found to increase with increasing fermentation time. pH showed no significant difference (p>0.05) in the reduction of sugar and the production of ethanol. However, significantly higher (p 0.05) in Vitamin C contents in all soursop vinegar samples produced using different treatments.

  17. Pereskia aculeata Muller (Cactaceae Leaves: Chemical Composition and Biological Activities

    Directory of Open Access Journals (Sweden)

    Lucèia Fàtima Souza

    2016-09-01

    Full Text Available The aims of this work were to study the chemical composition of the essential oil from the leaves of Pereskia aculeata and to evaluate some biological activities of three leaf extracts. The phenolic content, antioxidant activity, and in vitro antimicrobial and antifungal activities were determined. The methanol extract showed antioxidant activity (EC50 7.09 mg/mL and high polyphenols content (15.04 ± 0.31 mg gallic acid equivalents (GAE/g. The petroleum ether extract exhibited potent antibacterial activity against Escherichia coli, whereas the chloroform extract showed inhibitory activity against Bacillus cereus and Staphylococcus aureus. The petroleum ether and methanol extracts were more effective in inhibiting the growth of Aspergillus versicolor. The possible cytotoxicity of extracts on neuroblastoma SH-SY5Y cancer cell line and the influence on adenylate cyclase (ADCY expression was also studied. P. aculeata chloroform extract showed antiproliferative activity with an IC50 value of 262.83 µg/mL. Treatments of SH-SY5Y neuroblastoma cells with 100 µg/mL of methanol extract significantly reduced ADCY1 expression.

  18. Chemical compositions of two different Thymus species essential oils

    Directory of Open Access Journals (Sweden)

    Samira Jaberi

    2015-06-01

    Full Text Available Thymus is one of the most important members of Lamiaceae family. Aerial parts of the plant have been widely used in medicine. It has been reported that most of these effects are related to phenolic compounds especially thymol and carvacrol in Thymus essential oil. In this study, aerial parts of Thymus daenensis and Thymus lancifolius were collected from Kohgiluyeh and Boyer-Ahmad, Iran. Essential oils of aerial parts of these plants were gained by the hydrodistillation method and the chemical compositions were analyzed by gas chromatography/ Mass spectrometry (GC/MS. The major components of the essential oil of T. daenensis were thymol (39.91%, carvacrol (29.93%, linalool (5.55%, caryophyllene (3.5% and geraniol (3.09%, whereas the major components of the essential oil of T. lancifolius were: carvacrol (25.55%, thymol (20.79%, linalool (16.8%, α-terpineol (6.34%, borneol (4.00%, caryophyllene (3.98%, p-cymene (3.38% and cis-linalool oxide (3.21%. Linalool was reported as another major component in T. lancifolius

  19. Chemical composition and quality of sweet sorghum and maize silages

    Directory of Open Access Journals (Sweden)

    Zbigniew PODKÓWKA

    2011-10-01

    Full Text Available Sweet sorghum (Sorghum saccharatum silage, maize (Zea mays silage, and sorghum and maize (1:1 silage were investigated. The silages were analysed for chemical composition, quality and aerobic stability. Dry matter was the lowest (20.88% in sorghum silage and the highest (37.45% in maize silage. In sorghum silage, the concentration of crude ash and crude fibre was higher, and that of crude protein, crude fat and N-free extractives lower compared to maize silage. Neutral detergent fibre and acid detergent fibre were the highest in sorghum silage and the lowest in maize silage. The silages were dominated by lactic acid, with trace amounts of butyric acid. Maize silage was higher lactic acid and higher total acids than others. All silages were of very good quality according to Flieg-Zimmer scale. Silage pH ranged from 4.20 to 4.31. Sorghum silage was characterized by higher aerobic stability (81h compared to the other silages from maize (74h and sorghum and maize 1:1 (69h.

  20. Reducing chemical vapour infiltration time for ceramic matrix composites.

    Science.gov (United States)

    Timms, L. A.; Westby, W.; Prentice, C.; Jaglin, D.; Shatwell, R. A.; Binner, J. G. P.

    2001-02-01

    Conventional routes to producing ceramic matrix composites (CMCs) require the use of high temperatures to sinter the individual ceramic particles of the matrix together. Sintering temperatures are typically much higher than the upper temperature limits of the fibres. This paper details preliminary work carried out on producing a CMC via chemical vapour infiltration (CVI), a process that involves lower processing temperatures, thus avoiding fibre degradation. The CVI process has been modified and supplemented in an attempt to reduce the CVI process time and to lower the cost of this typically expensive process. To this end microwave-enhanced CVI (MECVI) has been chosen, along with two alternative pre-infiltration steps: electrophoretic infiltration and vacuum bagging. The system under investigation is based on silicon carbide fibres within a silicon carbide matrix (SiCf/SiC). The results demonstrate that both approaches result in an enhanced initial density and a consequent significant reduction in the time required for the MECVI processing step. Dual energy X-ray absorptiometry was used as a non-destructive, density evaluation technique. Initial results indicate that the presence of the SiC powder in the pre-form changes the deposition profile during the MECVI process.

  1. Chemical composition of biomass from tall perennial tropical grasses

    Energy Technology Data Exchange (ETDEWEB)

    Prine, G.M. [Univ. of Florida, Gainesville, FL (United States); Stricker, J.A. [Polk County Extension Office, Bartow, FL (United States); Anderson, D.L. [Everglades Research and Education Center, Belle Glade, FL (United States)] [and others

    1995-11-01

    The tall perennial tropical grasses, elephantgrass (Pennisetum purpureum Schum.), sugarcane and energycane (Saccharum sp.) and erianthus (Erianthus arundenaceum (Retz) Jesw.) have given very high oven dry biomass yields in Florida and the warm Lower South USA. No good complete analyses of the chemical composition of these grasses for planning potential energy use was available. We sampled treatments of several tall grass demonstrations and experiments containing high-biomass yielding genotypes of the above tall grass crops at several locations in Florida over the two growing seasons, 1992 and 1993. These samples were analyzed for crude protein, NDF, ADF, cellulose, hemicellulose, lignin, and IVDMD or IVOMD. The analysis for the above constituents are reported, along with biomass yields where available, for the tall grass accessions in the various demonstrations and experiments. Particular attention is given to values obtained from the high-yielding tall grasses grown on phosphatic clays in Polk County, FL, the area targeted by a NREL grant to help commercialize bioenergy use from these crops.

  2. Chemical composition and antibacterial activity of Gongronema latifolium

    Institute of Scientific and Technical Information of China (English)

    ELEYINMI Afolabi F.

    2007-01-01

    Chemical composition of Gongronema latifolium leaves was determined using standard methods. Aqueous and methanol G. latifolium extracts were tested against thirteen pathogenic bacterial isolates. Crude protein, lipid extract, ash, crude fibre and nitrogen free extractives obtained are: 27.2%, 6.07%, 11.6%, 10.8% and 44.3% dry matter respectively. Potassium,sodium, calcium, phosphorus and cobalt contents are 332, 110, 115, 125 and 116 mg/kg respectively. Dominant essential amino acids are leucine, valine and phenylalanine. Aspartic acid, glutamic acid and glycine are 13.8%, 11.9% and 10.3% respectively of total amino acid. Saturated and unsaturated fatty acids are 50.2% and 39.4% of the oil respectively. Palmitic acid makes up 36% of the total fatty acid. Extracts show no activity against E. faecalis, Y. enterolytica, E. aerogenes, B. cereus and E. agglomerans.Methanol extracts were active against S. enteritidis, S. cholerasius ser typhimurium and P. aeruginosa (minimum inhibitory concentration (MIC) 1 mg; zone of growth inhibition 7, 6.5 and 7 mm respectively). Aqueous extracts show activity against E. coli (MIC 5 mg) and P. aeruginosa (MIC 1 mg) while methanol extracts are active against P. aeruginosa and L. monocytogenes. G.latifolium has potential food and antibacterial uses.

  3. Tea tree oil: contact allergy and chemical composition.

    Science.gov (United States)

    de Groot, Anton C; Schmidt, Erich

    2016-09-01

    In this article, contact allergy to, and the chemical composition of, tea tree oil (TTO) are reviewed. This essential oil is a popular remedy for many skin diseases, and may be used as neat oil or be present in cosmetics, topical pharmaceuticals and household products. Of all essential oils, TTO has caused most (published) allergic reactions since the first cases were reported in 1991. In routine testing, prevalences of positive patch test reactions have ranged from 0.1% to 3.5%. Nearly 100 allergic patients have been described in case reports and case series. The major constituents of commercial TTO are terpinen-4-ol, γ-terpinene, 1,8-cineole, α-terpinene, α-terpineol, p-cymene, and α-pinene. Fresh TTO is a weak to moderate sensitizer, but oxidation increases its allergenic potency. The major sensitizers appear to be ascaridole, terpinolene, α-terpinene, 1,2,4-trihydroxymenthane, α-phellandrene, and limonene. The clinical picture of allergic contact dermatitis caused by TTO depends on the products used. Most reactions are caused by the application of pure oil; cosmetics are the culprits in a minority of cases. Patch testing may be performed with 5% oxidized TTO. Co-reactivity to turpentine oil is frequent, and there is an overrepresentation of reactions to fragrance mix I, Myroxylon pereirae, colophonium, and other essential oils.

  4. Chemical composition and antigenotoxic properties of Lippia alba essential oils

    Directory of Open Access Journals (Sweden)

    Molkary Andrea López

    2011-01-01

    Full Text Available The present work evaluated the chemical composition and the DNA protective effect of the essential oils (EOs from Lippia alba against bleomycin-induced genotoxicity. EO constituents were determined by Gas Chromatography/Mass Spectrometric (GC-MS analysis. The major compounds encountered being citral (33% geranial and 25% neral, geraniol (7% and trans-β-caryophyllene (7% for L. alba specimen COL512077, and carvone (38%, limonene (33% and bicyclosesquiphellandrene (8% for the other, COL512078. The genotoxicity and antigenotoxicity of EO and the compounds citral, carvone and limonene, were assayed using the SOS Chromotest in Escherichia coli. The EOs were not genotoxic in the SOS chromotest, but one of the major compound (limonene showed genotoxicity at doses between 97 and 1549 mM. Both EOs protected bacterial cells against bleomycin-induced genotoxicity. Antigenotoxicity in the two L. alba chemotypes was related to the major compounds, citral and carvone, respectively. The results were discussed in relation to the chemopreventive potential of L. alba EOs and its major compounds.

  5. Brazilian kefir: structure, microbial communities and chemical composition

    Directory of Open Access Journals (Sweden)

    Karina Teixeira Magalhães

    2011-06-01

    Full Text Available Microbial ecology and chemical composition of Brazilian kefir beverage was performed. The microorganisms associated with Brazilian kefir were investigated using a combination of phenotypic and genotypic methods. A total of 359 microbial isolates were identified. Lactic acid bacteria (60.5% were the major isolated group identified, followed by yeasts (30.6% and acetic acid bacteria (8.9%. Lactobacillus paracasei (89 isolates, Lactobacillus parabuchneri (41 isolates, Lactobacillus casei (32 isolates, Lactobacillus kefiri (31 isolates, Lactococcus lactis (24 isolates, Acetobacter lovaniensis (32 isolates, Kluyveromyces lactis (31 isolates, Kazachstania aerobia (23 isolates, Saccharomyces cerevisiae (41 isolates and Lachancea meyersii (15 isolates were the microbial species isolated. Scanning electron microscopy showed that the microbiota was dominated by bacilli (short and curved long cells growing in close association with lemon-shaped yeasts cells. During the 24 h of fermentation, the protein content increased, while lactose and fat content decreased. The concentration of lactic acid ranged from 1.4 to 17.4 mg/ml, and that of acetic acid increased from 2.1 to 2.73 mg/ml. The production of ethanol was limited, reaching a final mean value of 0.5 mg/ml.

  6. Pereskia aculeata Muller (Cactaceae) Leaves: Chemical Composition and Biological Activities.

    Science.gov (United States)

    Souza, Lucèia Fàtima; Caputo, Lucia; Inchausti De Barros, Ingrid Bergman; Fratianni, Florinda; Nazzaro, Filomena; De Feo, Vincenzo

    2016-09-03

    The aims of this work were to study the chemical composition of the essential oil from the leaves of Pereskia aculeata and to evaluate some biological activities of three leaf extracts. The phenolic content, antioxidant activity, and in vitro antimicrobial and antifungal activities were determined. The methanol extract showed antioxidant activity (EC50 7.09 mg/mL) and high polyphenols content (15.04 ± 0.31 mg gallic acid equivalents (GAE)/g). The petroleum ether extract exhibited potent antibacterial activity against Escherichia coli, whereas the chloroform extract showed inhibitory activity against Bacillus cereus and Staphylococcus aureus. The petroleum ether and methanol extracts were more effective in inhibiting the growth of Aspergillus versicolor. The possible cytotoxicity of extracts on neuroblastoma SH-SY5Y cancer cell line and the influence on adenylate cyclase (ADCY) expression was also studied. P. aculeata chloroform extract showed antiproliferative activity with an IC50 value of 262.83 µg/mL. Treatments of SH-SY5Y neuroblastoma cells with 100 µg/mL of methanol extract significantly reduced ADCY1 expression.

  7. Anisotropy vs chemical composition at ultra-high energies

    CERN Document Server

    Lemoine, Martin

    2009-01-01

    This paper proposes and discusses a test of the chemical composition of ultra-high energy cosmic rays that relies on the anisotropy patterns measured as a function of energy. In particular, we show that if one records an anisotropy signal produced by heavy nuclei of charge Z above an energy E_{thr}, one should record an even stronger (possibly much stronger) anisotropy at energies >E_{thr}/Z due to the proton component that is expected to be associated with the sources of the heavy nuclei. This conclusion remains robust with respect to the parameters characterizing the sources and it does not depend at all on the modelling of astrophysical magnetic fields. As a concrete example, we apply this test to the most recent data of the Pierre Auger Observatory. Assuming that the anisotropy reported above 55EeV is not a statistical accident, and that no significant anisotropy has been observed at energies 10^{45}Z^{-2}erg/s. Using this bound in conjunction with the above conclusions, we argue that the current PAO data...

  8. Brazilian kefir: structure, microbial communities and chemical composition

    Science.gov (United States)

    Magalhães, Karina Teixeira; de Melo Pereira, Gilberto Vinícius; Campos, Cássia Roberta; Dragone, Giuliano; Schwan, Rosane Freitas

    2011-01-01

    Microbial ecology and chemical composition of Brazilian kefir beverage was performed. The microorganisms associated with Brazilian kefir were investigated using a combination of phenotypic and genotypic methods. A total of 359 microbial isolates were identified. Lactic acid bacteria (60.5%) were the major isolated group identified, followed by yeasts (30.6%) and acetic acid bacteria (8.9%). Lactobacillus paracasei (89 isolates), Lactobacillus parabuchneri (41 isolates), Lactobacillus casei (32 isolates), Lactobacillus kefiri (31 isolates), Lactococcus lactis (24 isolates), Acetobacter lovaniensis (32 isolates), Kluyveromyces lactis (31 isolates), Kazachstania aerobia (23 isolates), Saccharomyces cerevisiae (41 isolates) and Lachancea meyersii (15 isolates) were the microbial species isolated. Scanning electron microscopy showed that the microbiota was dominated by bacilli (short and curved long) cells growing in close association with lemon-shaped yeasts cells. During the 24 h of fermentation, the protein content increased, while lactose and fat content decreased. The concentration of lactic acid ranged from 1.4 to 17.4 mg/ml, and that of acetic acid increased from 2.1 to 2.73 mg/ml. The production of ethanol was limited, reaching a final mean value of 0.5 mg/ml. PMID:24031681

  9. Study of Aerosol Chemical Composition Based on Aerosol Optical Properties

    Science.gov (United States)

    Berry, Austin; Aryal, Rudra

    2015-03-01

    We investigated the variation of aerosol absorption optical properties obtained from the CIMEL Sun-Photometer measurements over three years (2012-2014) at three AERONET sites GSFC; MD Science_Center and Tudor Hill, Bermuda. These sites were chosen based on the availability of data and locations that can receive different types of aerosols from land and ocean. These absorption properties, mainly the aerosol absorption angstrom exponent, were analyzed to examine the corresponding aerosol chemical composition. We observed that the retrieved absorption angstrom exponents over the two sites, GSFC and MD Science Center, are near 1 (the theoretical value for black carbon) and with low single scattering albedo values during summer seasons indicating presence of black carbon. Strong variability of aerosol absorption properties were observed over Tudor Hill and will be analyzed based on the air mass embedded from ocean side and land side. We will also present the seasonal variability of these properties based on long-range air mass sources at these three sites. Brent Holben, NASA GSFC, AERONET, Jon Rodriguez.

  10. Chemical Composition, Antifungal and Insecticidal Activities of Hedychium Essential Oils

    Directory of Open Access Journals (Sweden)

    Kanniah Rajasekaran

    2013-04-01

    Full Text Available The antimicrobial properties of essential oils have been documented, and their use as “biocides” is gaining popularity. The aims of this study were to analyze the chemical composition and assess the biological activities of Hedychium essential oils. Oils from 19 Hedychium species and cultivars were analyzed by gas chromatography (GC and gas chromatography-mass spectrometry (GC-MS techniques. The antifungal and insecticidal activities of these oils were tested against Colletotrichum acutatum, C. fragariae, and C. gloeosporioides, and three insects, the azalea lace bug (Stephanitis pyrioides, the yellow fever mosquito (Aedes aegypti, and the red imported fire ant (Solenopsis invicta. Hedychium oils were rich in monoterpenes and sesquiterpenes, especially 1,8-cineole (0.1%–42%, linalool (<0.1%–56%, a-pinene (3%–17%, b-pinene (4%–31%, and (E-nerolidol (0.1%–20%. Hedychium oils had no antifungal effect on C. gloeosporioides, C. fragariae, and C. acutatum, but most Hedychium oils effectively killed azalea lace bugs. The oils also show promise as an adult mosquito repellent, but they would make rather poor larvicides or adulticides for mosquito control. Hedychium oils acted either as a fire ant repellent or attractant, depending on plant genotype and oil concentration.

  11. Microbial population, chemical composition and silage fermentation of cassava residues.

    Science.gov (United States)

    Napasirth, Viengsakoun; Napasirth, Pattaya; Sulinthone, Tue; Phommachanh, Kham; Cai, Yimin

    2015-09-01

    In order to effectively use the cassava (Manihot esculenta Crantz) residues, including cassava leaves, peel and pulp for livestock diets, the chemical and microbiological composition, silage preparation and the effects of lactic acid bacteria (LAB) inoculants on silage fermentation of cassava residues were studied. These residues contained 10(4) to 10(5) LAB and yeasts, 10(3) to 10(4) coliform bacteria and 10(4) aerobic bacteria in colony forming units (cfu) on a fresh matter (FM) basis. The molds were consistently at or below the detectable level (10(2) cfu of FM) in three kinds of cassava residues. Dry matter (DM), crude protein (CP) and neutral detergent fiber (NDF) content of cassava residues were 17.50-30.95%, 1.30-16.41% and 25.40-52.90% on a DM basis, respectively. The silage treatments were designed as control silage without additive (CO) or with LAB inoculants Chikuso-1 (CH, Lactobacillus plantarum) and Snow Lacto (SN, Lactobacillus rhamnosus) at a rate of 5 mg/kg of FM basis. All silages were well preserved with a low pH (below 4.0) value and when cassava residues silage treated with inoculants CH and SN improved fermentation quality with a lower pH, butyric acid and higher lactic acid than control silage.

  12. Chemical composition and antigenotoxic properties of Lippia alba essential oils.

    Science.gov (United States)

    López, Molkary Andrea; Stashenko, Elena E; Fuentes, Jorge Luis

    2011-07-01

    The present work evaluated the chemical composition and the DNA protective effect of the essential oils (EOs) from Lippia alba against bleomycin-induced genotoxicity. EO constituents were determined by Gas Chromatography/Mass Spectrometric (GC-MS) analysis. The major compounds encountered being citral (33% geranial and 25% neral), geraniol (7%) and trans-β-caryophyllene (7%) for L. alba specimen COL512077, and carvone (38%), limonene (33%) and bicyclosesquiphellandrene (8%) for the other, COL512078. The genotoxicity and antigenotoxicity of EO and the compounds citral, carvone and limonene, were assayed using the SOS Chromotest in Escherichia coli. The EOs were not genotoxic in the SOS chromotest, but one of the major compound (limonene) showed genotoxicity at doses between 97 and 1549 mM. Both EOs protected bacterial cells against bleomycin-induced genotoxicity. Antigenotoxicity in the two L. alba chemotypes was related to the major compounds, citral and carvone, respectively. The results were discussed in relation to the chemopreventive potential of L. alba EOs and its major compounds.

  13. Influence of silane content and filler distribution on chemical-mechanical properties of resin composites

    Directory of Open Access Journals (Sweden)

    Tathy Aparecida XAVIER

    2015-01-01

    Full Text Available This study investigated the influence of silane concentration and filler size distribution on the chemical-mechanical properties of experimental composites. Experimental composites with silane contents of 0%, 1% and 3% (in relation to filler mass and composites with mixtures of barium glass particles (median size = 0.4, 1 and 2 μm and nanometric silica were prepared for silane and filler analyses, respectively. The degree of conversion (DC was analyzed by FTIR. Biaxial flexural strength (BFS was tested after 24-h or 90-d storage in water, and fracture toughness, after 24 h. The data were subjected to ANOVA and Tukey’s test (p = 0.05. The DC was not significantly affected by the silane content or filler distribution. The 0% silane group had the lowest immediate BFS, and the 90-d storage time reduced the strength of the 0% and 3% groups. BFS was not affected by filler distribution, and aging decreased the BFS of all the groups. Silanization increased the fracture toughness of both the 1% and 3% groups, similarly. Significantly higher fracture toughness was observed for mixtures with 2 μm glass particles. Based on the results, 3% silane content boosted the initial strength, but was more prone to degradation after water storage. Variations in the filler distribution did not affect BFS, but fracture toughness was significantly improved by increasing the filler size.

  14. Optical density and chemical composition of microfilled and microhybrid composite resins

    Directory of Open Access Journals (Sweden)

    Ana Paula Braun

    2008-04-01

    Full Text Available This study evaluated the optical density of two microfilled and two microhybrid resins, as well as the composition of these materials with regard to their optical density. Cavities prepared in 12 2-mm- or 4-mm-thick acrylic plastic plates were filled with Z250 (3M-ESPE, A110 (3M-ESPE, Charisma (Heraeus-Kulzer and DurafillVS (Heraeus-Kulzer. The resin increments (2-mm-thick were light-cured for 40 s. Three 0.12-s radiographic exposures were made of each #2 acrylic plastic plate. DenOptix system optical plates were used to obtain the digital images. Three readings of the composite resin surface were made in each radiograph, totalizing 216 readings. The mean of highest and lowest grey-scale values was obtained. Two specimens of each composite resin were prepared for SEM analysis of the chemical elements related to optical density, using energy dispersive x-ray analysis (EDX. The results were subjected to Shapiro-Wilk's test, ANOVA, Tukey's test at 1% level of significance and Pearson's correlation. The mean grey-scale values at 2 mm and 4 mm were: Z250 = 154.27a and 185.33w; A110 = 46.77b and 63.05y; Charisma = 163.40c and 200.46z; DurafillVS = 43.92b and 58.99x, respectively. Pearson's test did not show any positive correlation between optical density and percentage weight of optical density chemical elements. It was concluded that the microhybrid resins had higher optical density means than the microfilled resins; among the evaluated resins, Charisma had the highest optical density means.

  15. Simulation of the isotopic composition of stratospheric water vapour - Part 2: Investigation of HDO/H2O variations

    OpenAIRE

    Eichinger, Roland; Jöckel, Patrick; Lossow, Stefan

    2015-01-01

    Studying the isotopic composition of water vapour in the lower stratosphere can reveal the driving mechanisms of changes in the stratospheric water vapour budget and therefore help to explain the trends and variations of stratospheric water vapour during recent decades. We equipped a global chemistry climate model with a description of the water isotopologue HDO, comprising its physical and chemical fractionation effects throughout the hydrological cycle. We use this m...

  16. Simulation of the isotopic composition of stratospheric water vapour – Part 2: Investigation of HDO / H2O variations

    OpenAIRE

    R. Eichinger; Jöckel, P.; S. Lossow

    2015-01-01

    Studying the isotopic composition of water vapour in the lower stratosphere can reveal the driving mechanisms of changes in the stratospheric water vapour budget and therefore help to explain the trends and variations of stratospheric water vapour during recent decades. We equipped a global chemistry climate model with a description of the water isotopologue HDO, comprising its physical and chemical fractionation effects throughout the hydrological cycle. We use this mode...

  17. REMOVAL OF MERCURY FROM WATER USING POLYPYRROLE AND ITS COMPOSITES

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    One of the suitable methods for removing heavy metals from water is by using surface adsorption process. In this paper, the preparation of polypyrrole and its composites as adsorbents are discussed and the capability of separating mercury from water is investigated. The results indicated that the polypyrrole and its composites are able to remove mercury from aqueous media. Furthermore the adsorption percentage is related to the surface morphology, type of additives and its concentration.

  18. Water aging reverses residual stresses in hydrophilic dental composites.

    Science.gov (United States)

    Park, J W; Ferracane, J L

    2014-02-01

    Dental composites develop residual stresses during polymerization due to shrinkage. These stresses may change with time because of relaxation and water sorption in the oral environment. This phenomenon is likely dependent on the composition of the materials, specifically their hydrophilic characteristics, and could result in deleterious stresses on restorative materials and tooth structure. The purpose of this experiment was to use the thin ring-slitting method to compare the residual stress generated within composite materials of varying hydrophilicity when aged in wet and dry conditions after polymerization. Water sorption, solubility, elastic modulus, and residual stresses were measured in 6 commercial composites/cements aged in water and dry conditions. The self-adhesive resin cement showed the highest water sorption and solubility. All composites showed initial residual contraction stresses, which were maintained when aged dry. Residual stresses in 2 of the self-adhesive cements and the polyacid-modified composite aged in wet conditions resulted in a net expansion. This experiment verified that residual shrinkage stresses in dental composites can be reversed during aging in water, resulting in a net expansion, with the effect directly related to their hydrophilic properties.

  19. Seminar for hydrocarbon detection with composite geophysical/geo-chemical techniques

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    “Seminar for hydrocarbon detection with composite geophy sical/geo-chemical techniques”,jointly organized by China petroleum Exploration & Production Company and Exploration Geophysical Committee of CGS and supported by the Composite Geophysical/geo-chemical Departement of Oriental Geophysical Company and China Exploration&Development Research Instiute,

  20. Chemical composition analysis of simulated waste glass T10-G-16A

    Energy Technology Data Exchange (ETDEWEB)

    Fox, K. M. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2015-08-01

    In this report, SRNL provides chemical composition analyses of a simulated LAW glass designated T10-G-16A.The measured chemical composition data are reported and compared with the targeted values for each component. No issues were identified in reviewing the analytical data.

  1. A NOVEL DESIGN OF COMPOSITE WATER TURBINE USING CFD

    Institute of Scientific and Technical Information of China (English)

    WANG Ji-feng; PIECHNA Janusz; M(U)LLER Norbert

    2012-01-01

    This paper presents computational investigation of a novel design of composite material axial water turbine using Computational Fluid Dynamics (CFD).Based on three-dimensional numerical flow analysis,the flow characteristics through the water turbine with nozzle,wheel and diffuser are predicted.The extract power and torque of a composite water turbine at different rotating speeds were calculated and analyzed for a specific flow speed.The simulation results show that using nozzle and diffuser can increase the pressure drop across the turbine and extract more power from available water energy.These results provide a fundamental understanding of the composite water turbine,and this design and analysis method is used in the design process.

  2. Chemical composition and metal capacity of magmatic gases of Gorelyi volcano, Kamchatka

    Science.gov (United States)

    Chaplygin, I. V.; Taran, Yu. A.; Dubinina, E. O.; Shapar, V. N.; Timofeeva, I. F.

    2015-07-01

    The high-temperature (865°C according to data of an IR-camera) gases and the crater lake water of Gorelyi volcano were sampled in September 2011. The gas and condensate were collected from the active crater in bocca, which was formed in June 2010. The chemical composition and the δ18O and δD values of the condensate and lake water were analyzed. In comparison with the isotopic data on volcanic condensates of the adjacent Mutnovskii volcano, the data points of samples from Gorelyi volcano fall to the mixing line of meteoric and magmatic water. The isotopic characteristics of the water component of the fluid mostly correspond to the high-temperature equilibrium with silicate rocks or melts; the portion of local meteoric water is ~25%. The high metal content of gases of the volcano is determined. The total removal of Cu, Zn, Pb, Mo, Cd, In, Sn, Tl, and Bi by gases of Gorelyi volcano (~30 t/year) comparable to that of the Kudryavyi volcano (20-80 t/year) indicates the high ore-bearing capacity of the volcanic gas fluids.

  3. Physical and Chemical Characterization Of Greater Yam (Dioscorea Alata) And Jack Bean (Canavalia Ensiformis) - Based Composite Flour

    Science.gov (United States)

    Affandi, D. R.; Praseptiangga, D.; Nirmala, F. S.; Sigit Amanto, B.; Atmaka, W.

    2017-04-01

    Indonesia is a tropical country that has great potential in agriculture. Tubers and legumes as examples of the potential commodities are needed to be more developed. Flour production is one of the best alternatives to be chosen as the downstream stage of the tubers and legumes utilization. Greater yam (Dioscorea alata) and jack bean (Canavalia ensiformis) were used in this study. This study was conducted to determine best formula of composite flour based on physical, chemical, and functional characterization of composite flour produced. Variations of formula used was the ratio of greater yam flour and jack bean flour, which were 85:15 (F1), 70:30 (F2), 55:45 (F3), respectively, and this study was conducted using completely randomized design (CRD). The formula variations didn’t show any significant effect on the water absorption capability, water holding capacity (WHC), oil holding capacity (OHC), swelling power, and starch content of the composite flour. However, the formula variations had a significant influence on the colour, proximate parameters, amylose and amylopectin content, resistant starch content, dietary fibre, total phenol, and antioxidant activity of the composite flour produced. Considering the results of physical, chemical, and functional characteristics of composite flour, formula (F1) was selected as the best composite flour developed from greater yam and jack bean flours.

  4. CHEMICAL COMPOSITION OF MUSCLE AFTER POLLEN APPLICATION IN NUTRITION OF BROILER CHICKENS

    Directory of Open Access Journals (Sweden)

    Vladimíra Kňazovická

    2012-04-01

    Full Text Available Normal 0 21 false false false SK X-NONE X-NONE Principle purpose of this study was to monitor the chemical composition of breast and thigh muscular part of chickens of hybrid combination Ross 308 and to verify the differences due to use of pollen extract in feed mixture at a dose of 400 and 800 mg.kg-1 during the feeding of 42 days. We did not find significant differences (P≥0.05 in followed chemical compounds of thigh muscle with the skin and subcutaneous fat between the groups with and without application of pollen extract: in contents of water (68.49-70.12 g.100g-1, protein (18.82-18.98 g.100g-1, fat (9.96-11.53 g.100g-1 and in energy value (692.20-752.36 kJ.100g-1. Significant differences (P≤0.05 were found only in protein content of breast muscle between the control group (23.96 g.100g-1 and experimental group I (23.28 g.100g-1. Values of water content (73.97-74.32 g.100g-1, fat content (1.07-1.40 g.100g-1 and energy (441.65-446.64 kJ.100g-1 in breast muscle between the evaluated groups were balanced (P≥0.05. The results show that pollen extract at the concentration used in feed mixture did not effect basic chemical composition of the most valuable parts of the chicken Ross 308 carcass and we can apply it in their nutrition. Application at a dose of 800 mg.kg-1 seems to be more positive.doi:10.5219/190

  5. RESEARCH REGARDING THE CHEMICAL COMPOSITION AT VINEGAR TYPES

    OpenAIRE

    Liviu Giurgiulescu; Olimpia Mihaela Hoban

    2009-01-01

    In this article are presented some physico-chemical applied vinegar, to see some chemical properties of vinegar suchas total acidity, volatile and fixed, by colorimetric determination of iron content in the vinegar, the extract andresidue determination dry.

  6. Brazilian Propolis: Correlation between Chemical Composition and Antimicrobial Activity

    Directory of Open Access Journals (Sweden)

    Kelly Salomão

    2008-01-01

    Full Text Available The chemical composition of ethanol extracts from samples of Brazilian propolis (EEPs determined by HPLC and their activity against Trypanosoma cruzi, Staphylococcus aureus, Streptococcus pneumoniae, Klebisiella pneumoniae, Candida albicans, Sporothrix schenckii and Paracoccidioides brasiliensis were determined. Based on the predominant botanical origin in the region of samples' collection, the 10 extracts were separated into three groups: A (B. dracunculifolia + Auraucaria spp, B (B. dracunculifolia and C (Araucaria spp. Analysis by the multiple regression of all the extracts together showed a positive correlation, higher concentrations leading to higher biological effect, of S. aureus with p-coumaric acid (PCUM and 3-(4-hydroxy-3-(oxo-butenyl-phenylacrylic acid (DHCA1 and of trypomastigotes of T. cruzi with 3,5-diprenyl-4-hydroxycinnamic acid derivative 4 (DHCA4 and 2,2-dimethyl-6-carboxyethenyl-2H-1-benzopyran (DCBEN. When the same approach was employed for each group, due to the small number of observations, the statistical test gave unreliable results. However, an overall analysis revealed for group A an association of S. aureus with caffeic acid (CAF and dicaffeoylquinic acid 3 (CAFQ3, of S. pneumoniae with CAFQ3 and monocaffeoylquinic acid 2 (CAFQ2 and of T. cruzi also with CAFQ3. For group B, a higher activity against S. pneumoniae was associated DCBEN and for T. cruzi with CAF. For group C no association was observed between the anitmicrobial effect and any component of the extracts. The present study reinforces the relevance of PCUM and derivatives, especially prenylated ones and also of caffeolyquinic acids, on the biological activity of Brazilian propolis.

  7. Chemical composition and leishmanicidal activity of Pulicaria gnaphalodes essential oil

    Directory of Open Access Journals (Sweden)

    G. Asghari

    2014-10-01

    Full Text Available Background and objectives: Several natural compounds have been identified for the treatment ofleishmaniasis. Due to a few safe drugs and the side effects caused by available chemotherapy, some new drugs for treatment of leishmaniasis are requested.  The genus Pulicaria (Asteraceae is represented in the flora of Iran by five species. Phytochemical studies on Pulicaria species have revealed some flavonoids and terpenoids with leishmanicidal activity. In the present investigation chemical composition and leishmanicidal activity of Pulicaria gnaphalodes essential oil have been studied. Methods: The essential oil of the aerial parts of the plant was obtained by Clevenger apparatus and was analyzed by GC/MS. Antileishmanil activity was assessed against promastigoes of Leishmania major. Results:The major components from P. gnaphalodes essential oil have been reported to be geraniol, 1,8-cineole, chrysanthenone, α-pinene, chrystanthenone, α-terpineol and filifolone. The alcohol monoterpenes with contribution of 25.04% constituted the major portion of the essential oil, while hydrocarbon monoterpenes and hydrocarbon sesquiterpenes with contribution of 7.08% and 2.38%, respectively occupied the next rates.In the present experiment the essential oil of P. gnaphalodes progressively inhibited Leishmania major growth in concentrations ranging from 0.125 to 50 µL/mL (parasite culture in 24 h. The essential oil at 50 µL/mL eliminated the promastigotes at the beginning of treatment. It showed antileishmanial activity in concentration of 1.06 µL/mL and destroyed all parasits in 24 h.  Conclusion: Pulicaria gnaphalodes antileishmanial activity, could suggest the species and constituents as possible lead structures for antileishmanial drug discovery.

  8. Chemical composition and antioxidant activity of berry fruits

    Directory of Open Access Journals (Sweden)

    Stajčić Slađana M.

    2012-01-01

    Full Text Available The main chemical composition, contents of total phenolic (TPh, total flavonoid (TF, and total monomeric anthocyianin (TMA, as well as the antioxidant activity of two raspberry cultivars (Meeker and Willamette, two blackberry cultivars (Čačanska bestrna and Thornfree and wild bilberry were studied. The raspberry cultivars had the highest total solids among fruits investigated. Bilberry fruits had the highest sugar-to-acid ratio. Blackberry fruits were richer in crude fibers (cellulose in comparison to raspberry and bilberry fruits. The content of pectic substances was highest in the bilberry. Also, bilberry had a highest content of TPh (808.12 mg GAE/100 g FW, TF (716.31 mg RE/100 g FW and TMA (447.83 mg CGE/100 g FW. The antioxidant activity was evaluated spectrophotometrically, using 2,2-diphenyl-1-picrylhydrazyl (DPPH radical scavenging activity assay. The DPPH free radical scavenging activity, expressed as the EC50 value (in mg of fresh weight of berry fruit per ml of the reaction mixture, of bilberry (0.3157 ± 0.0145 mg/ml was the highest. These results also showed that the antioxidant value of 100 g FW bilberry, raspberry - Willamette, raspberry - Meeker, blackberry - Čačanska bestrna and blackberry - Thornfree is equivalent to 576.50 mg, 282.74 mg, 191.58 mg, 222.28 mg and 272.01 mg of vitamin C, respectively. There was a significant positive correlation between the antioxidant activities and content of total phenolics (RTPh 2=0.9627, flavonoids (RTF 2=0.9598 and anthocyanins (RTMA 2=0.9496 in berry fruits. [Projekat Ministarstva nauke Republike Srbije, br. TR 31044

  9. Chemical composition of buckwheat plant parts and selected buckwheat products

    Directory of Open Access Journals (Sweden)

    Petra Vojtíšková

    2014-11-01

    Full Text Available Chemical composition plant parts (roots, stalks, leaves, blossoms of common buckwheat (Fagopyrum esculentum Moench and selected products made from its seeds (peels, whole seed, wholemeal flour, broken seeds, crunchy products Natural and Cocoa, flour, and pasta was determined. Samples were dried and ground to a fine powder. All analyses were performed according to the Commission Regulation no. 152/2009, while rutin concentration was determined by the modified HPLC method. The lowest content of moisture was found in roots (4.3% and in peels (almost 8% and the highest moisture (nearly 11% was discovered in seeds. The lowest amount of crude protein (3.5% was found in peels, the highest crude protein amount (>13% in both flours and leaves (23%. The starch content (>50% in dry matter differs from one sample to another. Only in peels the content of starch was about 3.5%. From all examined samples, the lowest content of fat was found in crunchy products Cocoa, 1.7%. The lowest amount of histidine was determined in all studied samples, except peels, the highest content of glutamic acid was determined in almost all samples, except peels. Whole-meal flour is very rich source of Ca and Fe. The content of these elements was 1172 mg.kg-1 and 45.9 mg.kg-1, respectively. On the other hand, the highest content of Pb (>1 mg.kg-1 was found in broken seeds. The greatest concentration of rutin was determined in blossoms and leaves (83.6 and 69.9 mg.g-1, respectively. On the other hand, the lowest concentrations of rutin were found in buckwheat products (generally less then 1 mg.g-1, i.e. in wholemeal flour, 702 μg.kg-1, the lowest almost 10 μg.kg-1 in pasta.

  10. ON THE MORPHOLOGY AND CHEMICAL COMPOSITION OF THE HR 4796A DEBRIS DISK

    Energy Technology Data Exchange (ETDEWEB)

    Rodigas, Timothy J.; Weinberger, Alycia [Department of Terrestrial Magnetism, Carnegie Institution of Washington, 5241 Broad Branch Road, NW, Washington, DC 20015 (United States); Stark, Christopher C. [NASA Goddard Space Flight Center, Exoplanets and Stellar Astrophysics Laboratory, Code 667, Greenbelt, MD 20771 (United States); Debes, John H.; Chen, Christine [Space Telescope Science Institute, Baltimore, MD 21218 (United States); Hinz, Philip M.; Close, Laird; Smith, Paul S.; Males, Jared R.; Skemer, Andrew J.; Follette, Katherine B.; Morzinski, Katie; Wu, Ya-Lin; Schneider, Glenn [Steward Observatory, The University of Arizona, 933 North Cherry Avenue, Tucson, AZ 85721 (United States); Puglisi, Alfio; Briguglio, Runa; Esposito, Simone; Pinna, Enrico; Riccardi, Armando; Xompero, Marco, E-mail: trodigas@carnegiescience.edu [INAF-Osservatorio Astrofisico di Arcetri, Largo E. Fermi 5, I-50125, Firenze (Italy)

    2015-01-10

    We present resolved images of the HR 4796A debris disk using the Magellan adaptive optics system paired with Clio-2 and VisAO. We detect the disk at 0.77 μm, 0.91 μm, 0.99 μm, 2.15 μm, 3.1 μm, 3.3 μm, and 3.8 μm. We find that the deprojected center of the ring is offset from the star by 4.76 ± 1.6 AU and that the deprojected eccentricity is 0.06 ± 0.02, in general agreement with previous studies. We find that the average width of the ring is 14{sub −2}{sup +3}% (11.1{sub −1.6}{sup +2.4} AU), also comparable to previous measurements. Combining our new scattered light data with archival Hubble Space Telescope images at ∼0.5-2 μm, along with previously unpublished Spitzer/MIPS thermal emission data and all other literature thermal data, we set out to constrain the chemical composition of the dust grains. After testing 19 individual root compositions and more than 8400 unique mixtures of these compositions, we find that good fits to the scattered light alone and thermal emission alone are discrepant, suggesting that caution should be exercised if fitting to only one or the other. When we fit to both data sets simultaneously, we find that silicates and organics are generally the most favored, while large abundances of water ice are usually not favored. These results suggest the HR 4796A dust grains are similar to interstellar dust and solar system comets, though improved modeling is necessary to place better constraints on the exact chemical composition of the dust.

  11. Primary and secondary particles chemical composition of marine emissions from Mediterranean seawaters

    Science.gov (United States)

    D'Anna, Barbara; Meme, Aurelie; Rmili, Badr; Pey, Jorge; Marchand, Nicolas; Schwier, Allison; Sellegri, Karine; Charriere, Bruno; Sempere, Richard; Mas, Sebastien; Parin, David

    2015-04-01

    Marine emissions are among the largest source of both primary particles and do highly contribute secondary organic aerosols (SOA) at a global scale. Whereas physical processes control the primary production of marine aerosols, biological activity is responsible for most of the organic fraction released from marine sources, potentially transformed into SOA when exposed to atmospheric oxidants. The Mediterranean atmosphere displays important concentrations of SOA, especially in summer, when atmospheric oxidants and photochemical activity are at their maximum. The origin of these elevated concentrations of SOA remain unclear. Here we present the results from a mesocosms study in a remote location in Corsica and a chamber study (using fresh sea water from Western Mediterranean) as part of the Source of marine Aerosol particles in the Mediterranean atmosphere (SAM) project. The mesocosm study was conducted at the Oceanographic and Marine Station STARESO (Corsica) in May 2013. One mesocosm was used as a control (with no enrichment) and the other two were enriched with nitrate and phosphate respecting Redfield ratio (N:P = 16) in order to produce a bloom of biological activity. Physical and chemical properties of the enclosed water samples together with their surrounding atmosphere were monitored during 20 days by a multi-instrumental high-time resolution set-up. In parallel, numerous additional measurements were conducted including water temperature, incident light, pH, conductivity, chemical and biological analyses, fluorescence of chlorophyll, dissolved oxygen concentration. The chamber studies were performed in a Teflon chamber of 1. 5m3 that accommodates a pyrex-container for the fresh sea-water samples. After injection of sea-water in the pyrex-container, the system is allowed to stabilize to 20-30 minutes, then it was exposed to 60-100ppbv of ozone and/or UV-A irradiation. Aerosol concentrations and their physical characteristics were followed by means of Scanning

  12. Chemical composition of aerosol in the atmospheric surface layer of the East Antarctica coastal zone

    Directory of Open Access Journals (Sweden)

    L. P. Golobokova

    2016-01-01

    contributions of the continental and maritime factors to formation of the aerosol chemical composition revealed higher enrichment ratios for K+, Ca2+, SO4 2− (K = 3.6÷13.0. This reflects not only influence of the natural sources, but the intensity of human activities on the Antarctic continent as well. The elemental composition of solid aerosols was also analyzed. The largest concentrations were determined for Zn, Al and Fe. The ratio of concentration of the elements in both the soluble and insoluble phases of the aerosol showed that 84.1% of the total amount of the elements was contained in a water-insoluble state. Fractional relation between the element concentrations changed in different phases from 16 to 98%. High enrichment of the aerosol particles by Zn, Cu, Cr, Ba, Pb, Ni,Se, As, Cd (the enrichment factors = 27÷26 445 had been revealed. The content of dominant chemical components (Na+, Cl−, Zn, Fe, factors and coefficients of the element enrichment in the aerosols as well as in fresh snow of the coastal zone of East Antarctica are indicative of the identity of sources where their composition is formed.

  13. Permafrost conditions in peatlands regulate magnitude, timing, and chemical composition of catchment dissolved organic carbon export.

    Science.gov (United States)

    Olefeldt, David; Roulet, Nigel T

    2014-10-01

    Permafrost thaw in peatlands has the potential to alter catchment export of dissolved organic carbon (DOC) and thus influence downstream aquatic C cycling. Subarctic peatlands are often mosaics of different peatland types, where permafrost conditions regulate the hydrological setting of each type. We show that hydrological setting is key to observed differences in magnitude, timing, and chemical composition of DOC export between permafrost and nonpermafrost peatland types, and that these differences influence the export of DOC of larger catchments even when peatlands are minor catchment components. In many aspects, DOC export from a studied peatland permafrost plateau was similar to that of a forested upland catchment. Similarities included low annual export (2-3 g C m(-2) ) dominated by the snow melt period (~70%), and how substantial DOC export following storms required wet antecedent conditions. Conversely, nonpermafrost fens had higher DOC export (7 g C m(-2) ), resulting from sustained hydrological connectivity during summer. Chemical composition of catchment DOC export arose from the mixing of highly aromatic DOC from organic soils from permafrost plateau soil water and upland forest surface horizons with nonaromatic DOC from mineral soil groundwater, but was further modulated by fens. Increasing aromaticity from fen inflow to outlet was substantial and depended on both water residence time and water temperature. The role of fens as catchment biogeochemical hotspots was further emphasized by their capacity for sulfate retention. As a result of fen characteristics, a 4% fen cover in a mixed catchment was responsible for 34% higher DOC export, 50% higher DOC concentrations and ~10% higher DOC aromaticity at the catchment outlet during summer compared to a nonpeatland upland catchment. Expansion of fens due to thaw thus has potential to influence landscape C cycling by increasing fen capacity to act as biogeochemical hotspots, amplifying aquatic C cycling, and

  14. Microstructure, chemical composition and mucilage exudation of chia (Salvia hispanica L.) nutlets from Argentina.

    Science.gov (United States)

    Capitani, Marianela I; Ixtaina, Vanesa Y; Nolasco, Susana M; Tomás, Mabel C

    2013-12-01

    The micromorphology and anatomy of nutlets, myxocarpy (mucilage exudation) and mucilage structure of Argentinean chia were described using scanning electron microscopy (SEM). The proximal composition of nutlets and mucilage was also studied. Chia nutlets are made up of a true seed and a pericarp enclosing the seed; they are small, glabrous, elliptic and apically rounded. The pericarp has cuticle, exocarp, mesocarp and bone cells vertically arranged and endocarp. The myxocarpy was carefully recorded by SEM. After 5 min in contact with water, the cuticle of nutlets is broken and the exocarp cell content gradually surrounds the rest of the nutlet. The proximal composition of chia nutlets was studied; fat is the major component (327 ± 8.0 g kg(-1)) followed by protein (293 ± 4.0 g kg(-1)) and fiber (276 ± 1.0 g kg(-1)). Extractions of chia nutlets with water at room temperature yielded 38 ± 1.0 g kg(-1) (dry basis) of mucilage. The fresh mucilage structure was similar to a network of open pores. The freeze-dried crude mucilage contained more ash, residual fat and protein than commercial guar and locust bean gum. The solubility of 10.0 g L(-1) w/v solution of chia freeze-dried crude mucilage in water increased with temperature, being maximal at 60 °C (870 g kg(-1)). The results obtained show a fast exudation of chia mucilage when nutlets are in contact with water. The freeze-dried crude mucilage hydrates easily in water, even at low temperatures. Chia nutlets have mucilaginous substances, with interesting functional properties from a technological and physiological point of view. © 2013 Society of Chemical Industry.

  15. Chemical treatment of slime in industrial cooling water systems

    Energy Technology Data Exchange (ETDEWEB)

    Sato, Noriyuki

    1987-07-01

    Chemical suppression test was made for slime produced in pipes of the industrial water cooling systems. The 3 month chemical slime treatment test in 1984 proved to be effective, and the test has been carried out since July, 1985. The objective was to suppress the generation of slime by decreasing the number of general bacteria by slime treatment agent (fungicide of chloride group). The number of bacteria in the supplied water was compared for the time and day of the week when samples were collected. It was found that there was no regular rule in the variation of the number of bacteria, with measured result of 30-10/sup 6/ variation range. From the variation in the number of bacteria and the sticking conditions of slime on the test board, it became clear that suppression was possible by drastically decreasing the bacteria number in cooling water in the early stage of chemical supply, followed by resupply of treatment agent in a week when the bacteria would be restored to its original amount by supplied water. However, the method is to suppress the slime generation, and is unable to stop the generation completely. (9 figs, 3 tabs)

  16. Canna edulis Ker by-product: chemical composition and characteristics of the dietary fiber.

    Science.gov (United States)

    Juan Zhang; Wang, Zheng-Wu; Shi, Xian-Ming

    2010-08-01

    Canna edulis Ker by-product was recycled and utilized after starch extraction. The chemical composition, physical properties and antioxidant activity of the by-product were investigated. The by-product was mainly composed of dietary fiber (54.84% measured by AOAC method), and the insoluble dietary fiber constituted the major fraction. Then, the chemical composition of dietary fiber was tested using modified AOAC and Englyst methods. The results showed that dietary fiber was comprised of cellulose, hemicelluloses (including xyloglucans, arabinoxylans and glucuronoxylans), pectin and lignin. Moreover, the by-product contained relatively high content of phenolic compounds and exhibited a moderate antioxidant activity. In addition, the by-product showed both high water-holding capacity (12.5 mL/g) and oil-holding capacity (14 mL/g), and its suspension exhibited controllable viscosity. Therefore, the by-product from C. edulis is not only a source of dietary fiber but also a functional ingredient for food industry.

  17. CHEMICAL WATER QUALITY INDICATORS IN BASIN FOREST PARCZEW

    Directory of Open Access Journals (Sweden)

    Antoni Grzywna

    2014-10-01

    Full Text Available This paper presents the characteristics of the chemistry of surface and ground water in the bottom of the river valley reclaimed Ochoza. Drained grassland accounts for 20% of the total catchment area and are located on organic soils in the valley Tyśmienica classified to the Natura 2000 sites. Analysis of physico-chemical properties of water are to assess the effects of anthropogenic transformation and identify factors that influence water quality in the study area. Water samples were collected in the years 2011–2012 in several points. The walls were characterized by surface water stagnant in the trenches, in July, blueberry plantation. Characterized by the highest quality of surface water runoff river with the test object. Occurring here throughout the growing season water flow reed growing on the bed and temporary impoundment of water contribute to the self-cleaning effect of water. Conducted at different times of the growing season (winter, spring, summer, autumn of water chemistry analysis allows to assess the impact of vegetation on the process of self-purification of water. Based on the survey it was found that the river is reduced by 26% BOD 5, COD by 37%, 12% phosphate and potassium by 13%. Concurrently, an increase in the content of nitrogen compounds – ammonia at 27% and 15% nitrate. The increase in the content of nitrogen compounds is particularly evident in the bottom of the object, which is probably associated with the deep trench causing excessive drying of the soil. The highest values of pollutants were recorded mostly in the spring probably due to the outflow of water from the drans.

  18. Alternative Processes for Water Reclamation and Solid Waste Processing in a Physical/chemical Bioregenerative Life Support System

    Science.gov (United States)

    Rogers, Tom D.

    1990-01-01

    Viewgraphs on alternative processes for water reclamation and solid waste processing in a physical/chemical-bioregenerative life support system are presented. The main objective is to focus attention on emerging influences of secondary factors (i.e., waste composition, type and level of chemical contaminants, and effects of microorganisms, primarily bacteria) and to constructively address these issues by discussing approaches which attack them in a direct manner.

  19. Water-soluble polymers and compositions thereof

    Science.gov (United States)

    Smith, B.F.; Robison, T.W.; Gohdes, J.W.

    1999-04-06

    Water-soluble polymers including functionalization from the group of amino groups, carboxylic acid groups, phosphonic acid groups, phosphonic ester groups, acylpyrazolone groups, hydroxamic acid groups, aza crown ether groups, oxy crown ethers groups, guanidinium groups, amide groups, ester groups, aminodicarboxylic groups, permethylated polyvinylpyridine groups, permethylated amine groups, mercaptosuccinic acid groups, alkyl thiol groups, and N-alkylthiourea groups are disclosed.

  20. The granulometric composition of solid dispersions of secondary water and oil emulsions

    Energy Technology Data Exchange (ETDEWEB)

    Abashev, R.G.

    1983-01-01

    An evaluation is made of the chemical and granulometric composition of solid dispersions in stratum waters and intermediate emulsion layers from settlers for commercial preparation of oil. The probable sources of the solid dispersions and their role in the destabilization of the modes for preparing conditioned oil are indicated, along with the need to consider factors which cause the manifestation of a high content of mechanical admixtures, development of technical and technological measures for their complete are partial prevention in well production.

  1. Modeling relations between the composition and properties of French light water reactor waste containment glass

    Energy Technology Data Exchange (ETDEWEB)

    Ghaleb, D.; Dussossoy, J.L.; Fillet, C.; Pacaud, F.; Jacquet-Francillon, N.

    1994-12-31

    Models have been developed to calculate the density, molten-state viscosity and initial corrosion rate according to the chemical composition of glass formulations used to vitrify high-level fission product solutions from reprocessed light water reactor fuel. Developed from other published work, these models have been adapted to allow for the effects of platinoid (Ru, Pd, Rh) inclusions on the molten glass rheology. (authors). 15 refs., 10 figs., 1 tab.

  2. Vegetation change impacts on soil organic carbon chemical composition in subtropical forests

    Science.gov (United States)

    Guo, Xiaoping; Meng, Miaojing; Zhang, Jinchi; Chen, Han Y. H.

    2016-07-01

    Changes in the chemical composition of soil organic carbon (SOC) might strongly affect the global carbon cycle as it controls the SOC decomposition rate. Vegetation change associated with long-term land use changes is known to strongly impact the chemical composition of SOC; however, data on the impacts of vegetation change following disturbance events of short durations and succession that occur frequently in forest ecosystems via diverse management objectives on SOC chemical composition are negligible. Here we examined the impacts of vegetation changes on the chemical composition of SOC by sampling soils of native broad-leaved forests, planted mixed broad-leaved and coniferous forests, and tea gardens in eastern China. We used nuclear magnetic resonance spectroscopy to quantify SOC chemical composition. We found that among all components of SOC chemical composition, alkyl carbon (C) and aryl C were more liable to change with vegetation than other SOC components. Soil pH was negatively correlated to the relative abundances of alkyl C and N-alkyl C, and Shannon’s index of overstory plant species was positively correlated to the relative abundances of phenolic C and aromaticity. Our results suggest that vegetation changes following short disturbance events and succession may strongly alter SOC chemical composition in forest ecosystems.

  3. Supercritical Water Process for the Chemical Recycling of Waste Plastics

    Science.gov (United States)

    Goto, Motonobu

    2010-11-01

    The development of chemical recycling of waste plastics by decomposition reactions in sub- and supercritical water is reviewed. Decomposition reactions proceed rapidly and selectively using supercritical fluids compared to conventional processes. Condensation polymerization plastics such as PET, nylon, and polyurethane, are relatively easily depolymerized to their monomers in supercritical water. The monomer components are recovered in high yield. Addition polymerization plastics such as phenol resin, epoxy resin, and polyethylene, are also decomposed to monomer components with or without catalysts. Recycling process of fiber reinforced plastics has been studied. Pilot scale or commercial scale plants have been developed and are operating with sub- and supercritical fluids.

  4. Theoretical Chemical Thermometry on Geothermal Waters: Problems and Methods

    Science.gov (United States)

    Pang, Zhong-He; Reed, Mark

    1998-03-01

    Using a synthetic geothermal water, we examine the effect of errors in Al analyses on theoretical chemical geothermometry based on multicomponent chemical equilibrium calculations of mineral equilibria. A new approach named FixAl that entails the construction of a modified Q/K graph eliminates problems with water analyses lacking Al or with erroneous analyses of Al. This is made possible by forcing the water to be at equilibrium with a selected Al-bearing mineral, such as microcline. In a FixAl graph, a modified Q/K value is plotted against temperature for Al-bearing minerals. Saturation indices of nonaluminous minerals are plotted in the same way as in an ordinary Q/K graph. In addition to Al concentration errors, degassing of CO 2 and dilution of reservoir water interfere with computed equilibrium geothermometry. These effects can be distinguished in a Q/K graph by comparing curves for nonaluminous minerals to those of aluminous minerals then correcting for CO 2 loss and dilution by a trial and error method. Example geothermal waters from China, Iceland, and the USA that are used to demonstrate the methods show that errors in Al concentrations are common, and some are severe. The FixAl approach has proved useful for chemical geothermometry for geothermal waters lacking Al analysis and for waters with an incorrect Al analysis. The equilibrium temperatures estimated by the FixAl approach agree well with quartz, chalcedony, and isotopic geothermometers. The best choice of mineral for forced equilibrium depends on pH. For most neutral pH waters, microcline and albite work well; for more acidic waters, kaolinite or illite are good choices. Measured pH plays a critical role in computed equilibria, and we find that the best pH to use is the one to which the reported carbonate also applies. Commonly this is the laboratory pH instead of field pH, but the field pH is still necessary to constrain CO 2 degassing. Calculations on numerous waters in the 80-180°C reservoir

  5. ANALYSIS OF SOLUBLE CHEMICAL TRANSFER BY RUNOFF WATER IN FIELD

    Institute of Scientific and Technical Information of China (English)

    TONG Ju-xiu; YANG Jin-zhong

    2008-01-01

    In order to determine the main factors influencing soluble chemical transfer and corresponding techniques for reducing fertilizer loss caused by runoff in irrigated fields, a physically based two-layer model was developed with incomplete mixing theory. Different forms of incomplete mixing parameters were introduced in the model, which was successfully verified with previous published experimental data. According to comparison, the chemicals loss of fertilizer is very sensitive to the runoff-related parameter while it is not sensitive to the infiltration-related parameter. The calculated results show that the chemicals in infiltration water play an important role in the early time of rainfall even with saturated soil, and it is mainly in the runoff flow in the late rainfall. Therefore, prevention of shallow subsurface drainage in the early rainfall is an effective way to reduce fertilizer loss, and the coverage on soil surface is another effective way.

  6. Stress corrosion crack initiation of alloy 182 weld metal in primary coolant - Influence of chemical composition

    Energy Technology Data Exchange (ETDEWEB)

    Calonne, O.; Foucault, M.; Steltzlen, F. [AREVA (France); Amzallag, C. [EDF SEPTEN (France)

    2011-07-01

    Nickel-base alloys 182 and 82 have been used extensively for dissimilar metal welds. Typical applications are the J-groove welds of alloy 600 vessel head penetrations, pressurizer penetrations, heater sleeves and bottom mounted instrumented nozzles as well as some safe end butt welds. While the overall performance of these weld metals has been good, during the last decade, an increasing number of cases of stress corrosion cracking of Alloy 182 weld metal have been reported in PWRs. In this context, the role of weld defects has to be examined. Their contribution in the crack initiation mechanism requires laboratory investigations with small scale characterizations. In this study, the influence of both alloy composition and weld defects on PWSCC (Stress Corrosion Cracking in Primary Water) initiation was investigated using U-bend specimens in simulated primary water at 320 C. The main results are the following: -) the chemical compositions of the weld deposits leading to a large propensity to hot cracking are not the most susceptible to PWSCC initiation, -) macroscopically, superficial defects did not evolve during successive exposures. They can be included in large corrosion cracks but their role as 'precursors' is not yet established. (authors)

  7. Salinity effect on nutritional value, chemical composition and bioactive compounds content of Cichorium spinosum L.

    Science.gov (United States)

    Petropoulos, Spyridon A; Levizou, Efi; Ntatsi, Georgia; Fernandes, Ângela; Petrotos, Konstantinos; Akoumianakis, Konstantinos; Barros, Lillian; Ferreira, Isabel C F R

    2017-01-01

    Soil salinization is an increasing problem for many areas throughout the world that renders prohibitive vegetables and crop production in general. In the present study, Cichorium spinosum L. plants were grown under saline conditions in order to evaluate chemical composition and bioactive compounds content of their leaves. Salinity increase resulted in significant changes of macro and micro-nutrients content (nutritional value, sugars, fatty acids, minerals, ascorbic acid and tocopherols), whereas the concentration of phenolic compounds was not significantly affected. Chicoric and 5-O-caffeoylquinic acid were the most abundant phenolic acids. In contrast, antioxidant activity and mineral composition were beneficially affected by mid-to-high and high salinity levels. In conclusion, C. spinosum can be cultivated under saline conditions without compromising the quality of the final product, especially in semi-arid areas where irrigation water is scarce and/or of low quality due to high content of NaCl (coastal areas or areas where underground water is saline).

  8. Activation of "synthetic ambient" aerosols - Relation to chemical composition of particles <100 nm

    Science.gov (United States)

    Burkart, J.; Hitzenberger, R.; Reischl, G.; Bauer, H.; Leder, K.; Puxbaum, H.

    2012-07-01

    Cloud condensation nuclei (CCN) are an important fraction of atmospheric aerosols because of their role in cloud formation. Experimental studies focus either on direct field measurements of complex ambient aerosols or laboratory investigations on well defined aerosols produced from single substances or substance mixtures. In this study, we focussed on the ultrafine aerosol because in terms of number concentration, the majority of the CCN are expected to have sizes in this range. A field study was performed from July 2007 to October 2008 to investigate the activation behaviour of the atmospheric aerosol in Vienna (Burkart et al., 2011). Filter samples of the aerosol aerosol in a nebulizer. Chemical analyses of the ultrafine water soluble material were also performed. The CCN properties of the "synthetic ambient" aerosol were obtained using the University of Vienna CCN counter (Giebl et al., 2002; Dusek et al., 2006b) at a nominal supersaturation (SS) of 0.5%. Activation diameters dact ranged from 54.5 nm to 66 nm, were larger than dact of typical single inorganic salts and showed no seasonal pattern in contrast to the fraction of water soluble organic carbon (WSOC), which ranged from 44% in spring to 15% in winter. The average hygroscopicity parameter κ (Petters and Kreidenweis, 2007) obtained from the activation curves ranged from 0.20 to 0.30 (average 0.24), which was significantly lower than κchem calculated from the chemical composition (0.43 ± 0.07).

  9. [Composition, physico-chemical properties and molecular superstructure of dietary fiber preparations of the cellan type].

    Science.gov (United States)

    Dongowski, G; Frigge, K; Zenke, I

    1995-07-01

    Dietary fiber preparations of "cellan" type were prepared from apples, white cabbage, sugar beet pulp, soy hulls and wheat bran by treatment with amylolytic and proteolytic enzymes as well as by chemical extractions. Scanning electron microscopic examinations show different morphological structures of the preparations and a high maintenance of native biomolecular superstructure. The content of pectin, protein, polysaccharide-hexoses and -pentoses and the composition of monosaccharides (also after their treatment with 4 or 8% sodium hydroxide) were determined. The cellans possess waterbinding capacities (WBC) between 25 g H2O/g and waterholding capacities between 50 g H2O/g. The WBC is related to the internal surface; it diminishes after treatment with NaOH. The interactions between the cellans and the adsorbed water were characterized by NMR-spin-lattice relaxation time T1. The molecular mobility increases as the water content grows. The T1-values of dried cellans decreased with increasing degree of moisture before drying. The supermolecular structure is comparatively disordered. Only in case of soy cellan a crystalline cellulose-I-modification could be identified by X-ray-diffraction pattern, esp. after NaOH treatment. The low degree of order of cellans was observed in the 13C-NMR spectra, too. Only the soy hull preparation resulted in a spectrum corresponding to well-ordered cellulose. The botanic source has an essential influence on the physico-chemical properties of dietary fiber preparations of cellan type.

  10. Physical-chemical determinant properties of biological communities in continental semi-arid waters.

    Science.gov (United States)

    da Rocha, Francisco Cleiton; de Andrade, Eunice Maia; Lopes, Fernando Bezerra; de Paula Filho, Francisco José; Filho, José Hamilton Costa; da Silva, Merivalda Doroteu

    2016-08-01

    Throughout human history, water has undergone changes in quality. This problem is more serious in dry areas, where there is a natural water deficit due to climatic factors. The aims of this study, therefore, were (i) to verify correlations between physical attributes, chemical attributes and biological metrics and (ii) from the biological attributes, to verify the similarity between different points of a body of water in a tropical semi-arid region. Samples were collected every 2 months, from July 2009 to July 2011, at seven points. Four physical attributes, five chemical attributes and four biological metrics were investigated. To identify the correlations between the physicochemical properties and the biological metrics, hierarchical cluster analysis (HCA) and canonical correlation analysis (CCA) were applied. Nine classes of phytoplankton were identified, with the predominance of species of cyanobacteria, and ten families of macroinvertebrates. The use of HCA resulted in the formation of three similar groups, showing that it was possible to reduce the number of sampling points when monitoring water quality with a consequent reduction in cost. Group I was formed from the waters at the high end of the reservoir (points P1, P2 and P3), group II by the waters from the middle third (points P4 and P5), and group III by the waters from the lower part of the reservoir (points P6 and P7). Richness of the phytoplanktons Cyanophyceae, Chorophyceae and Bacillariophyceae was the attribute which determined dissimilarity in water quality. Using CCA, it was possible to identify the spatial variability of the physicochemical attributes (TSS, TKN, nitrate and total phosphorus) that most influence the metrics of the macroinvertebrates and phytoplankton present in the water. Low macroinvertebrate diversity, with a predominance of indicator families for deterioration in water quality, and the composition of phytoplankton showing a predominance of cyanobacteria, suggests greater

  11. Evolution of chemical composition of fogwater in winter in Chengdu, China

    Institute of Scientific and Technical Information of China (English)

    Hongling Yin; Zhixiang Ye; Yingchun Yang; Wei Yuan; Changyan Qiu; Huawei Yuan; Min Wang

    2013-01-01

    Two sampling sites representing the urban and suburban area of Chengdu,China were sampled and analyzed for selected chemicals to characterize the evolution of the chemical composition of fogwater.A trend of total organic carbon (TOC) > total nitrogen (TN) >total inorganic carbon (TIC) was observed for both sites.Variation of inorganic ions indicated that inorganic pollutants were not accumulated in the fog.Concentrations of n-alkanes (Cll-C37) at the urban site ranged from 7.58 to 27.75 ng/mL while at the suburban site concentrations were 2.57-21.55 ng/mL.The highest concentration of n-alkanes was observed in the mature period of fog (393.12 ng/mL) which was more than ten times that in the fog formation period (27.83 ng/mL) and the fog dissipation period (14.87 ng/mL).Concentrations ofΣ15PAHs were in the range of 7.27-38.52 ng/mL at the urban site and 2.59-22.69 ng/mL at the suburban site.Contents of PAHs in the mature period of fog (27.15 ng/mL) > fog dissipation period (11.59 ng/mL) > fog formation period (6.42 ng/mL).Concentrations of dicarboxylic acids (C5-C9) ranged from 10.92 to 40.78 ng/mL,with glutaric acid (C5) as the dominant dicarboxylic acid.These data provide strong indications of the accumulation of certain organic chemicals of environmental concern in fog and fog water,and provide additional insights about processes in urban and suburban air acting on organic chemicals with similar physical chemical properties.

  12. Biosorption of heavy metal ions from aqueous solutions by short hemp fibers: Effect of chemical composition.

    Science.gov (United States)

    Pejic, Biljana; Vukcevic, Marija; Kostic, Mirjana; Skundric, Petar

    2009-05-15

    Sorption potential of waste short hemp fibers for Pb(2+), Cd(2+) and Zn(2+) ions from aqueous media was explored. In order to assess the influence of hemp fiber chemical composition on their heavy metals sorption potential, lignin and hemicelluloses were removed selectively by chemical modification. The degree of fiber swelling and water retention value were determined in order to evaluate the change in accessibility of the cell wall components to aqueous solutions due to the fiber modification. The effects of initial ion concentration, contact time and cosorption were studied in batch sorption experiments. The obtained results show that when the content of either lignin or hemicelluloses is progressively reduced by chemical treatment, the sorption properties of hemp fibers are improved. Short hemp fibers are capable of sorbing metal ions (Pb(2+), Cd(2+) and Zn(2+)) from single as well as from ternary metal ion solutions. The maximum total uptake capacities for Pb(2+), Cd(2+) and Zn(2+) ions from single solutions are the same, i.e. 0.078mmol/g, and from ternary mixture 0.074, 0.035 and 0.035mmol/g, respectively.

  13. Importance of the H2 abundance in protoplanetary disk ices for the molecular layer chemical composition

    CERN Document Server

    Wakelam, V; Hersant, F; Dutrey, A; Semenov, D; Majumdar, L; Guilloteau, S

    2016-01-01

    Protoplanetary disks are the target of many chemical studies (both observational and theoretical) as they contain the building material for planets. Their large vertical and radial gradients in density and temperature make them challenging objects for chemical models. In the outer part of these disks, the large densities and low temperatures provide a particular environment where the binding of species onto the dust grains can be very efficient and can affect the gas-phase chemical composition. We attempt to quantify to what extent the vertical abundance profiles and the integrated column densities of molecules predicted by a detailed gas-grain code are affected by the treatment of the molecular hydrogen physisorption at the surface of the grains. We performed three different models using the Nautilus gas-grain code. One model uses a H2 binding energy on the surface of water (440 K) and produces strong sticking of H2. Another model uses a small binding energy of 23 K (as if there were already a monolayer of H...

  14. The effect of water on thermal stresses in polymer composites

    Science.gov (United States)

    Sullivan, Roy M.

    1994-01-01

    The fundamentals of the thermodynamic theory of mixtures and continuum thermochemistry are reviewed for a mixture of condensed water and polymer. A specific mixture which is mechanically elastic with temperature and water concentration gradients present is considered. An expression for the partial pressure of water in the mixture is obtained based on certain assumptions regarding the thermodynamic state of the water in the mixture. Along with a simple diffusion equation, this partial pressure expression may be used to simulate the thermostructural behavior of polymer composite materials due to water in the free volumes of the polymer. These equations are applied to a specific polymer composite material during isothermal heating conditions. The thermal stresses obtained by the application of the theory are compared to measured results to verify the accuracy of the approach.

  15. Tracks FAQs: What Chemicals Are In My Drinking Water?

    Centers for Disease Control (CDC) Podcasts

    2011-08-10

    In this podcast, CDC Tracking experts discuss how you can use the Tracking Network to determine what chemicals are in your drinking water. Do you have a question for our Tracking experts? Please e-mail questions to trackingsupport@cdc.gov.  Created: 8/10/2011 by National Center for Environmental Health, Division of Environmental Hazards and Health Effects, Environmental Health Tracking Branch.   Date Released: 8/10/2011.

  16. Monitoring of endocrine disrupting chemicals in surface water

    CSIR Research Space (South Africa)

    Govender, S

    2008-06-01

    Full Text Available the surface. The chelated Pluronic-DMDDO ligand can be used for affinity purification of histidine tagged proteins. A regeneration formulation based on anionic SDS detergent desorbed pluronic modified polymeric membranes and the possibility of re... ingredients, household products and industrial chemicals. Surface waters are the main sink of said EDCs. Accurate EDC detection is usually via time consuming and costly ex situ LC-MS and GC-MS analysis. An important class of biosensors include those...

  17. Determination of Water Diffusion Coefficients and Dynamics in Adhesive/ Carbon Fiber Reinforced Epoxy Resin Composite Joints

    Institute of Scientific and Technical Information of China (English)

    WANG Chao; WANG Zhi; WANG Jing; SU Tao

    2007-01-01

    To determinate the water diffusion coefficients and dynamics in adhesive/carbon fiber reinforced epoxy resin composite joints, energy dispersive X-ray spectroscopy analysis(EDX) is used to establish the content change of oxygen in the adhesive in adhesive/carbon fiber reinforced epoxy resin composite joints. As water is made up of oxygen and hydrogen, the water diffusion coefficients and dynamics in adhesive/carbon fiber reinforced epoxy resin composite joints can be obtained from the change in the content of oxygen in the adhesive during humidity aging, via EDX analysis. The authors have calculated the water diffusion coefficients and dynamics in the adhesive/carbon fiber reinforced epoxy resin composite joints with the aid of both energy dispersive X-ray spectroscopy and elemental analysis. The determined results with EDX analysis are almost the same as those determined with elemental analysis and the results also show that the durability of the adhesive/carbon fiber reinforced epoxy resin composite joints subjected to silane coupling agent treatment is better than those subjected to sand paper burnishing treatment and chemical oxidation treatment.

  18. Water-dispersible magnetite-reduced graphene oxide composites for arsenic removal.

    Science.gov (United States)

    Chandra, Vimlesh; Park, Jaesung; Chun, Young; Lee, Jung Woo; Hwang, In-Chul; Kim, Kwang S

    2010-07-27

    Magnetite-graphene hybrids have been synthesized via a chemical reaction with a magnetite particle size of approximately 10 nm. The composites are superparamagnetic at room temperature and can be separated by an external magnetic field. As compared to bare magnetite particles, the hybrids show a high binding capacity for As(III) and As(V), whose presence in the drinking water in wide areas of South Asia has been a huge problem. Their high binding capacity is due to the increased adsorption sites in the M-RGO composite which occurs by reducing the aggregation of bare magnetite. Since the composites show near complete (over 99.9%) arsenic removal within 1 ppb, they are practically usable for arsenic separation from water.

  19. Grape Composition under Abiotic Constrains: Water Stress and Salinity.

    Science.gov (United States)

    Mirás-Avalos, José M; Intrigliolo, Diego S

    2017-01-01

    Water stress and increasing soil salt concentration represent the most common abiotic constrains that exert a negative impact on Mediterranean vineyards performance. However, several studies have proven that deficit irrigation strategies are able to improve grape composition. In contrast, irrigation with saline waters negatively affected yield and grape composition, although the magnitude of these effects depended on the cultivar, rootstock, phenological stage when water was applied, as well as on the salt concentration in the irrigation water. In this context, agronomic practices that minimize these effects on berry composition and, consequently, on wine quality must be achieved. In this paper, we briefly reviewed the main findings obtained regarding the effects of deficit irrigation strategies, as well as irrigation with saline water, on the berry composition of both red and white cultivars, as well as on the final wine. A meta-analysis was performed using published data for red and white varieties; a general liner model accounting for the effects of cultivar, rootstock, and midday stem water potential was able to explain up to 90% of the variability in the dataset, depending on the selected variable. In both red and white cultivars, berry weight, must titratable acidity and pH were fairly well simulated, whereas the goodness-of-fit for wine attributes was better for white cultivars.

  20. Grape Composition under Abiotic Constrains: Water Stress and Salinity

    Directory of Open Access Journals (Sweden)

    José M. Mirás-Avalos

    2017-05-01

    Full Text Available Water stress and increasing soil salt concentration represent the most common abiotic constrains that exert a negative impact on Mediterranean vineyards performance. However, several studies have proven that deficit irrigation strategies are able to improve grape composition. In contrast, irrigation with saline waters negatively affected yield and grape composition, although the magnitude of these effects depended on the cultivar, rootstock, phenological stage when water was applied, as well as on the salt concentration in the irrigation water. In this context, agronomic practices that minimize these effects on berry composition and, consequently, on wine quality must be achieved. In this paper, we briefly reviewed the main findings obtained regarding the effects of deficit irrigation strategies, as well as irrigation with saline water, on the berry composition of both red and white cultivars, as well as on the final wine. A meta-analysis was performed using published data for red and white varieties; a general liner model accounting for the effects of cultivar, rootstock, and midday stem water potential was able to explain up to 90% of the variability in the dataset, depending on the selected variable. In both red and white cultivars, berry weight, must titratable acidity and pH were fairly well simulated, whereas the goodness-of-fit for wine attributes was better for white cultivars.

  1. Chemical and isotopic data for water from thermal springs and wells of Oregon

    Energy Technology Data Exchange (ETDEWEB)

    Mariner, R.H.; Swanson, J.R.; Orris, G.J.; Presser, T.S.; Evans, W.C.

    1981-01-01

    The thermal springs of Oregon range in composition from dilute NaHCO/sub 3/ waters to moderately saline CO/sub 2/-charged NaCl-NaHCO/sub 3/ waters. Most of the thermal springs are located in southeastern or southcentral Oregon, with a few in northeastern Oregon and near the contact of the Western Cascades with the High Cascades. Thermal springs in the central and northern parts of the Cascades generally issue moderately saline NaCl waters. Farther south in the Cascades, the thermal waters are high in CO/sub 2/ as well as chloride. Most thermal springs in northeastern Oregon issue dilute NaHCO/sub 3/ waters of high pH (>8.5). These waters are similar to the thermal waters which issue from the Idaho batholith, farther east. Most of the remaining thermal waters are Na mixed-anion waters. Based on the chemical geothermometers, Mickey Srpings, Hot Borax Lake, Alvord Hot Springs, Neal Hot Springs, Vale Hot Springs, Crump Well, Hunters (Lakeview) Hot Springs, and perhaps some of the springs in the Cascades are associated with the highest temperature systems (>150/sup 0/C).

  2. How Soil Organic Matter Composition Controls Hexachlorobenzene-Soil-Interactions: Adsorption Isotherms and Quantum Chemical Modelling

    CERN Document Server

    Ahmed, Ashour; Kühn, Oliver

    2013-01-01

    Hazardous persistent organic pollutants (POPs) interact in soil with the soil organic matter (SOM) but this interaction is insufficiently understood at the molecular level. We investigated the adsorption of hexachlorobenzene (HCB) on soil samples with systematically modified SOM. These samples included the original soil, the soil modified by adding a hot water extract (HWE) fraction (soil+3 HWE and soil+6 HWE), and the pyrolyzed soil. The SOM contents increased in the order pyrolyzed soil < original soil < soil+3 HWE < soil+6 HWE. For the latter three samples this order was also valid for the HCB adsorption. The pyrolyzed soil adsorbed more HCB than the other samples at low initial concentrations, but at higher concentrations the HCB adsorption became weaker than in the samples with HWE addition. This adsorption behaviour combined with the differences in the chemical composition between the soil samples suggested that alkylated aromatic, phenol, and lignin monomer compounds contributed most to the HC...

  3. Chemical composition of lipopolysaccharides isolated from various endophytic nitrogen-fixing bacteria of the genus Herbaspirillum.

    Science.gov (United States)

    Serrato, R V; Sassaki, G L; Cruz, L M; Carlson, R W; Muszyński, A; Monteiro, R A; Pedrosa, F O; Souza, E M; Iacomini, M

    2010-04-01

    Bacteria from the genus Herbaspirillum are endophytes responsible for nitrogen fixation in gramineous plants of economic importance such as maize, sugarcane, sorghum, rice, and wheat. Some species are known to produce plant growth substances. In contrast, Herbaspirillum rubrisubalbicans strains are known to be mild plant pathogens. The molecular communication between the plant and the microbes might involve lipopolysaccharides present in the outer membrane of these gram-negative bacteria. Phenol-water extraction was used to obtain lipopolysaccharides from 7 strains of Herbaspirillum seropedicae (SmR1, Z67, Z78, ZA95, and M2) and H. rubrisubalbicans (M1 and M4). The electrophoretic profiles and chemical composition of the lipopolysaccharides obtained in the phenol and aqueous extracts were shown herein.

  4. Stable water isotopic composition of the Antarctic subglacial Lake Vostok: implications for understanding the lake's hydrology.

    Science.gov (United States)

    Ekaykin, Alexey A; Lipenkov, Vladimir Y; Kozachek, Anna V; Vladimirova, Diana O

    2016-01-01

    We estimated the stable isotopic composition of water from the subglacial Lake Vostok using two different sets of samples: (1) water frozen on the drill bit immediately after the first lake unsealing and (2) water frozen in the borehole after the unsealing and re-drilled one year later. The most reliable values of the water isotopic composition are: -59.0 ± 0.3 ‰ for oxygen-18, -455 ± 1 ‰ for deuterium and 17 ± 1 ‰ for d-excess. This result is also confirmed by the modelling of isotopic transformations in the water which froze in the borehole, and by a laboratory experiment simulating this process. A comparison of the newly obtained water isotopic composition with that of the lake ice (-56.2 ‰ for oxygen-18, -442.4 ‰ for deuterium and 7.2 ‰ for d-excess) leads to the conclusion that the lake ice is very likely formed in isotopic equilibrium with water. In turn, this means that ice is formed by a slow freezing without formation of frazil ice crystals and/or water pockets. This conclusion agrees well with the observed physical and chemical properties of the lake's accreted ice. However, our estimate of the water's isotopic composition is only valid for the upper water layer and may not be representative for the deeper layers of the lake, so further investigations are required.

  5. Analysis of physical and chemical parameters of bottled drinking water.

    Science.gov (United States)

    Mahajan, Rakesh Kumar; Walia, T P S; Lark, B S; Sumanjit

    2006-04-01

    Seventeen different brands of bottled drinking water, collected from different retail shops in Amritsar, were analyzed for different physical and chemical parameters to ascertain their compliability with the prescribed/recommended limits of the World Heath Organization (WHO) and the United States Environmental Protection Agency (USEPA). It was found that the majority of the brands tested were over-treated. Lower values of hardness, total dissolved solids (TDS) and conductance than the prescribed limits of WHO showed that water was deficient in essential minerals. Minerals like magnesium, potassium, calcium and fluoride were present in some cases in such a low concentration that water seemed to be as good as distilled water. Samples showing fluoride lesser than 0.5 mg/l warranted additional sources of fluoride for the people consuming only bottled water for drinking purposes. Zero values for chlorine demand as shown by all the bottled water samples showed that water samples were safe from micro-organisms. In case of heavy metals, only lead had been found to be greater than the limit of 0.015 mg/l as prescribed by WHO and USEPA, in seven out of 17 samples. Lead even at such a low concentration can pose a great health hazard.

  6. Engineering Characteristics of Chemically Treated Water-Repellent Kaolin.

    Science.gov (United States)

    Choi, Youngmin; Choo, Hyunwook; Yun, Tae Sup; Lee, Changho; Lee, Woojin

    2016-12-02

    Water-repellent soils have a potential as alternative construction materials that will improve conventional geotechnical structures. In this study, the potential of chemically treated water-repellent kaolin clay as a landfill cover material is explored by examining its characteristics including hydraulic and mechanical properties. In order to provide water repellency to the kaolin clay, the surface of clay particle is modified with organosilanes in concentrations (CO) ranging from 0.5% to 10% by weight. As the CO increases, the specific gravity of treated clay tends to decrease, whereas the total organic carbon content of the treated clay tends to increase. The soil-water contact angle increases with an increase in CO until CO = 2.5%, and then maintains an almost constant value (≈134.0°). Resistance to water infiltration is improved by organosilane treatment under low hydrostatic pressure. However, water infiltration resistance under high hydrostatic pressure is reduced or exacerbated to the level of untreated clay. The maximum compacted dry weight density decreases with increasing CO. As the CO increases, the small strain shear modulus increases, whereas the effect of organosilane treatment on the constrained modulus is minimal. The results indicate that water-repellent kaolin clay possesses excellent engineering characteristics for a landfill cover material.

  7. Engineering Characteristics of Chemically Treated Water-Repellent Kaolin

    Directory of Open Access Journals (Sweden)

    Youngmin Choi

    2016-12-01

    Full Text Available Water-repellent soils have a potential as alternative construction materials that will improve conventional geotechnical structures. In this study, the potential of chemically treated water-repellent kaolin clay as a landfill cover material is explored by examining its characteristics including hydraulic and mechanical properties. In order to provide water repellency to the kaolin clay, the surface of clay particle is modified with organosilanes in concentrations (CO ranging from 0.5% to 10% by weight. As the CO increases, the specific gravity of treated clay tends to decrease, whereas the total organic carbon content of the treated clay tends to increase. The soil-water contact angle increases with an increase in CO until CO = 2.5%, and then maintains an almost constant value (≈134.0°. Resistance to water infiltration is improved by organosilane treatment under low hydrostatic pressure. However, water infiltration resistance under high hydrostatic pressure is reduced or exacerbated to the level of untreated clay. The maximum compacted dry weight density decreases with increasing CO. As the CO increases, the small strain shear modulus increases, whereas the effect of organosilane treatment on the constrained modulus is minimal. The results indicate that water-repellent kaolin clay possesses excellent engineering characteristics for a landfill cover material.

  8. ISS Potable Water Sampling and Chemical Analysis Results for 2016

    Science.gov (United States)

    Straub, John E., II; Plumlee, Debrah K.; Wallace William T.; Alverson, James T.; Benoit, Mickie J.; Gillispie, Robert L.; Hunter, David; Kuo, Mike; Rutz, Jeffrey A.; Hudson, Edgar K.; Loh, Leslie J.; Gazda, Daniel B.

    2017-01-01

    This paper continues the annual tradition of summarizing at this conference the results of chemical analyses performed on archival potable water samples returned from the International Space Station (ISS). 2016 represented a banner year for life on board the ISS, including the successful conclusion for two crew members of a record one-year mission. Water reclaimed from urine and/or humidity condensate remained the primary source of potable water for the crew members of ISS Expeditions 46-50. The year 2016 was also marked by the end of a long-standing tradition of U.S. sampling and monitoring of Russian Segment potable water sources. Two water samples taken during Expedition 46 in February 2016 and returned on Soyuz 44, represented the final Russian Segment samples to be collected and analyzed by the U.S. side. Although anticipated for 2016, a rise in the total organic carbon (TOC) concentration of the product water from the U.S. water processor assembly due to breakthrough of organic contaminants from the system did not materialize, as evidenced by the onboard TOC analyzer and archive sample results.

  9. Designing water supplies: Optimizing drinking water composition for maximum economic benefit

    DEFF Research Database (Denmark)

    Rygaard, Martin; Arvin, Erik; Bath, A.

    2011-01-01

    .3 ± 0.2 per delivered m3 for Perth and €0.4(±0.2) for Copenhagen. Costs of remineralization and green house gas emission mitigation are minor when compared to the potential benefits of an optimum water composition. Finally, a set of optimum water quality criteria is proposed for the guidance of water...

  10. Microbiological water purification without the use of chemical disinfection.

    Science.gov (United States)

    Gerba, C P; Naranjo, J E

    2000-01-01

    Point-of-use (POU) water treatment systems are self-contained units that can be used by recreational enthusiasts who normally obtain drinking water from untreated sources (i.e., rivers, lakes, etc). Microbiological water purifier units are capable of removing all waterborne pathogens. The purpose of this study was to evaluate a new technology (Structured Matrix) capable of micro-biologically purifying the water without the use of chemical disinfectants or an external power requirement. Each of 3 identical portable water filtration units were evaluated for their ability to remove Klebsiella terrigena, poliovirus type 1, rotavirus SA-11, and Cryptosporidium parvum oocysts. Units were operated according to the manufacturer's instructions to process 378 L of water. Each unit was challenged with test organisms after 0, 94, 190, 227, 284, 340, and 378 L had passed through it. For the 227-L and 284-L challenges, a "worst-case" water quality (4 degrees C, pH 9, and turbidity 30 NTU) was used that contained 1500 mg/L dissolved solids and 10 mg/L humid acid. At 340-L and 378-L challenges, worst-case water quality was adjusted to pH 5.0. Units were tested after stagnation for 48 hours following passage of 190, 340, and 378 L of water. The geometric average removal exceeded 99.9999% for bacteria, 99.99% for viruses, and 99.9% for Cryptosporidium parvum oocysts. These units comply with the criteria guidelines for microbial removal under the United States Environmental Protection Agency's "Guide Standard and Protocol for Testing Microbiological Water Purifiers."

  11. Phytotoxic activity and chemical composition of aqueous volatile fractions from Eucalyptus species.

    Directory of Open Access Journals (Sweden)

    Jinbiao Zhang

    Full Text Available The essential oils from four Eucalyptus species (E. spathulata, E. salubris, E. brockwayii and E. dundasii have been previously confirmed to have stronger inhibitory effects on germination and seedling growth of silverleaf nightshade (Solanum elaeagnifolium Cav.. The aqueous volatile fractions (AVFs were the water soluble volatile fractions produced together with the essential oils (water insoluble fractions during the steam distillation process. The aim of this study was to further assess the phytotoxicity of AVFs from the four Eucalyptus species and their chemical composition. The fresh leaves of the four Eucalyptus species were used for the extraction of AVFs. The AVFs were tested for their phytotoxic effects on the perennial weed, silverleaf nightshade under laboratory conditions. The chemical compositions of the AVFs were determined by gas chromatograph-mass spectrometry (GC-MS. Our results showed that the AVFs had strong inhibition on the germination and seedling growth of silverleaf nightshade. The inhibition index increased with the increasing concentrations of AVFs. The inhibitory effects of the AVFs varied between different Eucalyptus species. The AVF from E. salubris demonstrated the highest inhibitory activity on the weed tested, with complete inhibition on germination and seedling growth at a concentration of 75%. The GC-MS analysis revealed that 1,8-cineole, isopentyl isovalerate, isomenthol, pinocarvone, trans-pinocarveol, alpha-terpineol and globulol were the main compounds in the AVFs. These results indicated that all AVFs tested had differential inhibition on the germination and seedling growth of silverleaf nightshade, which could be due to the joint effects of compounds present in the AVFs as these compounds were present in different quantities and ratio between Eucalyptus species.

  12. Phytotoxic activity and chemical composition of aqueous volatile fractions from Eucalyptus species.

    Science.gov (United States)

    Zhang, Jinbiao; An, Min; Wu, Hanwen; Liu, De Li; Stanton, Rex

    2014-01-01

    The essential oils from four Eucalyptus species (E. spathulata, E. salubris, E. brockwayii and E. dundasii) have been previously confirmed to have stronger inhibitory effects on germination and seedling growth of silverleaf nightshade (Solanum elaeagnifolium Cav.). The aqueous volatile fractions (AVFs) were the water soluble volatile fractions produced together with the essential oils (water insoluble fractions) during the steam distillation process. The aim of this study was to further assess the phytotoxicity of AVFs from the four Eucalyptus species and their chemical composition. The fresh leaves of the four Eucalyptus species were used for the extraction of AVFs. The AVFs were tested for their phytotoxic effects on the perennial weed, silverleaf nightshade under laboratory conditions. The chemical compositions of the AVFs were determined by gas chromatograph-mass spectrometry (GC-MS). Our results showed that the AVFs had strong inhibition on the germination and seedling growth of silverleaf nightshade. The inhibition index increased with the increasing concentrations of AVFs. The inhibitory effects of the AVFs varied between different Eucalyptus species. The AVF from E. salubris demonstrated the highest inhibitory activity on the weed tested, with complete inhibition on germination and seedling growth at a concentration of 75%. The GC-MS analysis revealed that 1,8-cineole, isopentyl isovalerate, isomenthol, pinocarvone, trans-pinocarveol, alpha-terpineol and globulol were the main compounds in the AVFs. These results indicated that all AVFs tested had differential inhibition on the germination and seedling growth of silverleaf nightshade, which could be due to the joint effects of compounds present in the AVFs as these compounds were present in different quantities and ratio between Eucalyptus species.

  13. The chemical durability of glass and graphite-glass composite doped with cesium oxide

    Energy Technology Data Exchange (ETDEWEB)

    Hamodi, Nasir H., E-mail: nasirhamodi@yahoo.co.uk [School of Mechanical, Aerospace and Civil Engineering (MACE)/University of Manchester, Pariser Building, F-floor, Manchester M13 9PL (United Kingdom); Abram, Timothy J. [School of Mechanical, Aerospace and Civil Engineering (MACE)/University of Manchester, Pariser Building, F-floor, Manchester M13 9PL (United Kingdom); Lowe, Tristan; Cernik, Robert J. [Henry Mosley Imaging Facility, Material Science Centre, University of Manchester, Manchester M13 9PL (United Kingdom); Lopez-Honorato, Eddie [Centro de Investigacion y Estudios Avanzados del IPN (CINVESTAV), Unidad Saltillo. Carretera Saltillo-Monterrey km 13.5, 25900 Ramos Arizpe, Coahuila (Mexico)

    2013-01-15

    The role of temperature in determining the chemical stability of a waste form, as well as its leach rate, is very complex. This is because the dissolution kinetics is dependent both on temperature and possibility of different rate-controlling mechanisms that appear at different temperature regions. The chemical durability of Alumina-Borosilicate Glass (ABG) and Glass-Graphite Composite (GGC), bearing Tristructural Isotropic (TRISO) fuel particles impregnated with cesium oxide, were compared using a static leach test. The purpose of this study is to examine the chemical durability of glass-graphite composite to encapsulate coated fuel particles, and as a possible alternative for recycling of irradiated graphite. The test was based on the ASTM C1220-98 methodology, where the leaching condition was set at a temperature varying from 298 K to 363 K for 28 days. The release of cesium from ABG was in the permissible limit and followed the Arrhenius's law of a surface controlled reaction; its activation energy (E{sub a}) was 65.6 {+-} 0.5 kJ/mol. Similar values of Ea were obtained for Boron (64.3 {+-} 0.5) and Silicon (69.6 {+-} 0.5 kJ/mol) as the main glass network formers. In contrast, the dissolution mechanism of cesium from GGC was a rapid release, with increasing temperature, and the activation energy of Cs (91.0 {+-} 5 kJ/mol) did not follow any model related to carbon kinetic dissolution in water. Microstructure analysis confirmed the formation of Crystobalite SiO{sub 2} as a gel layer and Cs{sup +1} valence state on the ABG surface.

  14. Chemical characteristics of pond waters within the debris area of Lirung Glacier in Nepal Himalaya

    Directory of Open Access Journals (Sweden)

    Nozomu TAKEUCHI

    2007-08-01

    Full Text Available Water samples were analyzed from ponds developed within the debris-covered area of Lirung Glacier (28º 12.9’N, 86º 39.9’E; 4000 m a.s.l. in the Himalayas of Nepal during the pre-monsoon to post-monsoon period of 1996. Major chemical species were classified into three groups based on their relationships relative to the sum of cations: conservative (SiO2, Ca2+, K+, and Alkalinity, semiconservative (Na+, Mg2+, and SO4 2- and non-conservative (NH4 +, NO3 - and Cl-. The dominant processes determining the chemical composition of glacier pond water were sulfide oxidation coupled with carbonate dissolution and chemical weathering of aluminosilicate as indicated by the conservative and semi-conservative species. Calcium and alkalinity appeared as the dominant cation and anion, respectively, among all samples within the basin. Compared to the discharge waters at the outlet of the glacier, most of these pond waters have lower major solutes as well as alkalinity. The availability of fresh reactive minerals at the base of the glacier, coupled with higher temperature in discharge waters than in the ponds, may be the prime factors resulting in higher concentrations of most solutes in the discharge waters than in the ponds. In the ponds, higher concentrations of major solutes as well as alkalinity were observed in the monsoon than the pre-monsoon and post-monsoon seasons, suggesting the role of hydrolysis condition in chemical weathering rates. Ponds within the debris area of Lirung glacier in central Nepal Himalaya are likely to increase in importance if global warming accelerates the rate of glacial melting.

  15. Areca Fiber Reinforced Epoxy Composites: Effect of Chemical Treatments on Impact Strength

    Directory of Open Access Journals (Sweden)

    S. Dhanalakshmi

    2015-06-01

    Full Text Available In this research work, impact strength of untreated, alkali treated, potassium permanganate treated, benzoyl chloride treated and acrylic acid treated areca fiber reinforced epoxy composites were studied under 40%, 50%, 60% and 70% fiber loadings. Impact strength increased with increase in fiber loading up to 60% and then showed a decline for all untreated and chemically treated areca fiber reinforced epoxy composites. The acrylic acid treated areca fiber reinforced epoxy composites with 60% fiber loading showed highest impact strength of 28.28 J/mm2 amongst all untreated and chemically treated areca/epoxy composites with same 60% fiber loading.

  16. Quantifying impacts of coupled chemical and physical heterogeneity on water quality evolution during Aquifer Storage and Recovery

    Science.gov (United States)

    Deng, H.; Descourvieres, C.; Seibert, S.; Harris, B.; Atteia, O.; Siade, A. J.; Prommer, H.

    2014-12-01

    Aquifer storage and recovery (ASR) is an important water management option in water-scarce regions. During wet periods surplus water is injected into suitable aquifers for storage and later recovery. ASR sites are, however, also ideal natural laboratories that provide opportunities for studying coupled physical and geochemical processes and water quality evolution at field-scale under well-controlled hydrological conditions. In this study, we use reactive transport modelling to assess the impacts of physical and chemical heterogeneities on the water quality evolution during the injection of oxic surface water into the anoxic, pyrite-bearing Leederville aquifer in Perth, Western Australia. Physical heterogeneity was identified from geophysical well logs and time lapse temperature logs. Those data were used to define the spatial, depth-varying alternation of three lithofacies (sandstone, siltstone and clay). Chemical heterogeneity was incorporated through distinct chemical zones, based on data derived from a comprehensive pre-trial geochemical characterization and from dedicated laboratory respirometer experiments. Calibration of flow and conservative transport parameters was constrained by the spatially varying measured chloride breakthrough behavior. Subsequent reactive transport modeling discerned the key geochemical processes that affected the water quality evolution during ASR. Clearly identified processes included oxidation of pyrite, mineralization of sedimentary organic carbon, ion exchange, dissolution of calcite and precipitation of ferrihydrite and siderite. We use the calibrated model to analyze the individual and the combined effects of the physical and chemical heterogeneities on the chemical composition of the recovered water during ASR.

  17. Stable isotopic composition of bottled mineral waters from Romania

    Science.gov (United States)

    Bădăluţă, Carmen; Nagavciuc, Viorica; Perșoiu, Aurel

    2015-04-01

    Romania has a high potential of mineral waters resources, featuring one of the largest mineral resources at European and global level. In the last decade, due to increased in consumption of bottled water, numerous brands have appeared on the market, with equally numerous and variable sources of provenance. In this study we have analyzed the isotopic composition of bottled mineral waters from Romania in order to determine their source and authenticity. We have analysed 32 carbonated and 24 non-carbonated mineral waters from Romania. and the results were analysed in comparison with stable isotope data from precipitation and river waters. Generally, the isotopic values of the mineral waters follow those in precipitation; however, differences occur in former volcanic regions (due to deep circulation of meteoric waters and increased exchange with host rock and volcanic CO2), as well as in mountainous regions, where high-altitude recharge occurs.

  18. Water effect on peroxy radical measurement by chemical amplification: Experimental determination and chemical mechanism

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    The water effect on peroxy radical measurement by chemical amplification was determined experimentally for HO2 and HO2+OH, respectively at room temperature (298±2) K and atmospheric pressure (1×105 Pa). No significant difference in water effect was observed with the type of radicals. A theoretical study of the reaction of HO2·H2O adduct with NO was performed using density functional theory at CCSD(T)/6-311 G(2d, 2p)//B3LYP/6-311 G(2d, 2p) level of theory. It was found that the primary reaction channel for the reaction is HO2·H2O+NO→HNO3+H2O (R4a). On the basis of the theoretical study, the rate constant for (R4a) was calculated using Polyrate Version 8.02 program. The fitted Arrenhnius equation for (R4a) is k = 5.49×107 T 1.03exp(?14798/T) between 200 and 2000 K. A chemical model incorporated with (R4a) was used to simulate the water effect. The water effect curve obtained by the model is in accordance with that of the experiment, suggesting that the water effect is probably caused mainly by (R4a).

  19. Water effect on peroxy radical measurement by chemical amplification: Experimental determination and chemical mechanism

    Institute of Scientific and Technical Information of China (English)

    QI Bin; LIU Lu; CHAO YuTao; WANG ZhuQing; YANG HongYan

    2008-01-01

    The water effect on peroxy radical measurement by chemical amplification was determined experi-mentally for HO2 and HO2+OH, respectively at room temperature (298+9) K and atmospheric pressure (1×105 Pa). No significant difference in water effect was observed with the type of radicals. A theoretical study of the reaction of HO2. H2O adduct with NO was performed using density functional theory at CCSD(T)/6-311 G(2d, 2p)//B3LYPI6-311 G(2d, 2p) level of theory. It was found that the primary reaction channel for the reaction is HO2. H2O+NO→HNO3+H2O (R4a). On the basis of the theoretical study, the rate constant for (R4a) was calculated using Polyrate Version 8.02 program. The fitted Arrenhnius equation for (R4a) is k=5.49×107 T1.03exp(-14798/T) between 200 and 2000 K. A chemical model in-corporated with (R4a) was used to simulate the water effect. The water effect curve obtained by the model is in accordance with that of the experiment, suggesting that the water effect is probably caused mainly by (R4a).

  20. Chemical composition of nanomodified composite binder with nano- and microsized barium silicate

    Directory of Open Access Journals (Sweden)

    KOROLEV Evgenij Valerjevich

    2014-08-01

    Full Text Available There are several possibilities to improve cement-based binders. In particular, many properties of cement stone can be enhanced by means of micro- and nanoscale modification. In a number of previous works we had shown that application of barium hydrosilicates leads to such improvement. The present article is devoted to the investigation of the chemical composition of the cement stone which is modified by means of addition of barium hydrosilicates. The modification was performed on different scales: micro- and nanoscale; the results of simultaneous multi-scale modification are also presented. The examination was carried out with help of different modern research techniques – FT IR spectroscopy, differential thermal analysis and X-ray phase analysis. Identification of the new phases and comparative quantitative assessment of their content are performed. It is found that the use of nano- and micro-sized barium hydrosilicates as additives leads to reduction of portlandite by 27...28%; by means of multi-scale modification it is possible to reduce the content of portlandite much more (by 83.3%. Due to addition of nano- and micro-sized barium-based modifiers both the amount of calcium hydrosilicates in reaction products is enlarged, and structure of the mentioned hydrosilicates is changed (the formation of a fine-grained structure of hydration products takes place. Micro-sized barium hydrosilicates are chemically active additives and promote the formation of an additional quantity of calcium hydrosilicates of type CSH (I. The use of nanoscale barium hydrosilicates promotes the formation of CSH (I and CSH (II calcium hydrosilicates, and also both riversidite and xonotlite. As a result of simultaneous application of nano- and micro-sized barium hydrosilicates the content of CSH (II increases. This can be confirmed by means of differential thermal and X-ray analysis. The amount of CSH (I, riversidite and various tobermorites is also increases. It is

  1. Composite resin susceptibility to red wine staining after water sorption

    OpenAIRE

    2013-01-01

    Color stability of restorative materials is essential for longevity of esthetic composite restoration over time. The aim of this investigation was assess the effect of prior water immersion on the color stability of a composite resin to red wine staining. Seventy disc-shaped specimens (6 mm x 1.5 mm) were carried out and randomized in 7 groups (n = 10), according to distilled water immersion time at 0 (control), 24, 48, 72,120,192, and 240 h. Baseline color was measured according to the CIE L...

  2. Human health effects of residual carbon nanotubes and traditional water treatment chemicals in drinking water.

    Science.gov (United States)

    Simate, Geoffrey S; Iyuke, Sunny E; Ndlovu, Sehliselo; Heydenrych, Mike; Walubita, Lubinda F

    2012-02-01

    The volume of industrial and domestic wastewater is increasing significantly year by year with the change in the lifestyle based on mass consumption and mass disposal brought about by the dramatic development of economies and industries. Therefore, effective advanced wastewater treatment is required because wastewater contains a variety of constituents such as particles, organic materials, and emulsion depending on the resource. However, residual chemicals that remain during the treatment of wastewaters form a variety of known and unknown by-products through reactions between the chemicals and some pollutants. Chronic exposure to these by-products or residual chemicals through the ingestion of drinking water, inhalation and dermal contact during regular indoor activities (e.g., showering, bathing, cooking) may pose cancer and non-cancer risks to human health. For example, residual aluminium salts in treated water may cause Alzheimer's disease (AD). As for carbon nanotubes (CNTs), despite their potential impacts on human health and the environment having been receiving more and more attention in the recent past, existing information on the toxicity of CNTs in drinking water is limited with many open questions. Furthermore, though general topics on the human health impacts of traditional water treatment chemicals have been studied, no comparative analysis has been done. Therefore, a qualitative comparison of the human health effects of both residual CNTs and traditional water treatment chemicals is given in this paper. In addition, it is also important to cover and compare the human health effects of CNTs to those of traditional water treatment chemicals together in one review because they are both used for water treatment and purification. Copyright © 2011 Elsevier Ltd. All rights reserved.

  3. Variations in Chemical Composition of Spring and Stream Water during Rain Events in a Karst Peak Cluster-Depression Catchmen t, Northwest Guangxi, China%桂西北峰丛洼地泉水和溪流在降雨过程中的水化学动态变化特征

    Institute of Scientific and Technical Information of China (English)

    丁虎; 郎赟超; 刘文景; 刘丛强

    2011-01-01

    A study was conducted on variations in chemical composition of surface and spring water in a typical karst peak cluster-depression catchment, Northwest Guangxi, during two rainfall events on Aug. 23 and Aug. 24, 2007. Both spring and surface waters displayed a quick response to the rainfall in terms of water chemistry. During the rainfall events, electronic conductivity (EC) and concentrations of both dominant cations and anions, carbonate saturation index (SI) and carbon dioxide pressure (pCO2) decreased in the surface water soon after rainfall, while those factors in the spring water generally showed opposite variation trends. The solutes transportation rates of spring and stream flows increased during the rainfall period, but didn't show a positive relationship with rainfall intensity during continuous rainfall, revealing that besides the rain dilution effect and soil CO2 effect, the pre-event water stored in the soil vadose zone, as well as the amounts of exchangeable ions may affect the transportation of ions of both spring and stream flows in the karst peak cluster-depression catchment during rainfall.%通过对中国科学院环江喀斯特农业生态系统观测研究站所在区域的泉水和溪流在降雨对的连续采集,发现二者的水亿学特征对降雨的响应较快,但交化却不同,降雨时泉水的pH值在降雨时降低,电导率和主要离子浓度升高,SI降低,pCO2升高,而溪流的电导率和主要离子浓度降低,碳酸盐矿物饱和指数(SI)降低,水中二氧化碳分压(pCO2)降低.降雨时泉水和溪流的溶质输移速率明显增加,但没有表现出在连续降雨中因为降雨强度大输移速率就高的现象,从而推断,除了雨水的稀释作用和"土壤CO2效应"外,土壤包气带的"前水"以及主壤中可交换态高子也影响了降雨时峰丛洼地水体中溶质的运移.

  4. Color changes of dental resin composites before and after polymerization and storage in water.

    Science.gov (United States)

    Çelık, Esra Uzer; Aladağ, Akin; Türkün, L Şebnem; Yilmaz, Gökhan

    2011-06-01

    The aims of this study were to: (1) evaluate the A2 shades of various types and brands of resin composites to determine if any color differences occurred before and after polymerization and after 1 month of storage in water and (2) examine the correlation among the color changes and changes in Commission internationale de l'éclairage L*, a*, and b* values after polymerization and after 1 month of storage in water. One submicron-hybrid (Spectrum TPH3, DENTSPLY DeTrey, Milford, DE, USA), one nano-filled (Filtek Supreme XT, 3 M ESPE, St. Paul, MN, USA), three micro-hybrid (Filtek Z250, 3 M ESPE; Esthet X, DENTSPLY DeTrey; and Gradia Direct, GC, Tokyo, Japan), and five nano-hybrid (Ceram X, DENTSPLY DeTrey; Clearfil Majesty Esthetics, Kuraray, Osaka, Japan; Premise, Kerr Corporation, Orange, CA, USA; Tetric Evo Ceram, Ivoclar Vivadent, Schaan, Liechtenstein and Tetric N Ceram, Ivoclar Vivadent) light-curing resin composites were tested. The specimens (N = 10 for each composite) were prepared as discs, 12 mm in diameter and 2 mm in thickness, using round molds. The measurements were performed "before polymerization,"after polymerization," and "after 1 month of storage in water" using a contact type dental spectrophotometer (Vita Easyshade, Vident, Brea, CA, USA). The range of ΔE* values after polymerization (ΔE*1) and storage in water (ΔE*2) were 4.59 to 14.13 and 1.26 to 6.29, respectively. Nested analysis of variance and post hoc tests revealed that the type of resin composites significantly affected Δa*1, Δa*2, Δb*1, Δb*2, ΔE*2-values, whereas the brand of resin composites affected the changes in all color parameters (p compositions and fillers of the contemporary composites, color changes after polymerization were perceptible in all resin composites. However, color changes after storage in water were in the acceptable ranges for all resin composites except Clearfil Majesty Esthetic and Gradia Direct. In spite of many improvements in chemical compositions

  5. Chemical and Isotope Compositions of Neogene Hippopotamidae Teeth From Lake Albert (Uganda): Implications for Environmental Change

    Science.gov (United States)

    Brugmann, G. E.; Brachert, T. C.; Ssemmanda, I.; Mertz, D. F.

    2008-12-01

    The Neogene was a period of long-term global cooling and increasing climatic variability on astronomical time scales. Lake systems strongly depend on rainfall patterns and size or geographical distribution of river networks. To unravel environmental change and watershed dynamics in the western branch of the East African Rift (Lake Albert, Uganda) during the Late Neogene, we use proxy data (trace elements, O, C and Sr isotopes) from Hippopotamidae teeth. Laser ablation ICPMS profiles in enamel measured from the outside rim towards the dentin show an asymmetric trace element distribution in that the concentrations continuously decrease by up to 5 orders of magnitude within a distance of about 1 mm until a minimum is reached (migration pathways and palaeoenvironmental changes. On geological time scales δ13C compositions reflect a transition from pure C3 browsers (-11 per mil PDB) at 5 to 6 Ma towards C4 dominated grazers (0 per mil PDB) at 2.0 to 2.5 Ma. The oxygen stable isotope (δ18O) composition of enamel rises from 26 per mil at 5 to 6 Ma to a maximum of 32 per mil SMOW at 2.3 Ma. Increasing δ18O values suggest enhanced evaporation of the lake due to rising aridity. This is in agreement with a synchronous spread of C4 vegetation in the reach of Hippopotamid populations. The Sr isotopic composition of enamel displays a large variation and 87Sr/86Sr is 0.714 about 5 Ma ago, reaches a maximum of 0.717 at about 2.3 Ma and decreases from there on to about 0.708. Thus, Sr and O isotopic compositions correlate with each other on the geological time scale. This is plausible if the Sr isotopic composition of Hippopotamid enamel dominantly reflects the changes of the water chemistry of the lake, and is therefore a powerful tool for tracing ancient hydrological networks. The large variation of the Sr isotope composition can be explained if the lake is fed by different sources: water draining Cenozoic volcanic terrains have low 87Sr/86Sr (~ 0.704), whereas Proterozoic

  6. Particle size distribution and physico-chemical composition of clay.

    African Journals Online (AJOL)

    HP USER

    obtained after acid digestion of clay samples were used in determining the elements by Atomic. Absorption ... ignition (LOI) reveal a general reduction in composition as particles sizes reduces. However, Mg .... Murray, H.H. Diagnostic Tests for.

  7. Level and Chemical Composition of Cryoglobulins in Schizophrenia

    Science.gov (United States)

    Khoyetsyan, Aren; Boyajyan, Anna; Melkumova, Maya

    The blood samples of 40 schizophrenic patients were tested for the presence of cryoglobulins (Cgs) and composition of Cgs was examined. The elevated levels of type III Cgs, containing complement components, were detected in all study subjects.

  8. Chemical composition, nutritional value, and antioxidant activities of eight mulberry cultivars from China

    National Research Council Canada - National Science Library

    Liang, Linghong; Wu, Xiangyang; Zhu, Maomao; Zhao, Weiguo; Li, Fang; Zou, Ye; Yang, Liuqing

    2012-01-01

    Mulberry (Morus, Moraceae) is widely distributed in the temperate, subtropical, or tropical regions of the world, while there are no conclusive reports on the chemical composition, nutritional value, and antioxidant properties...

  9. A study of the chemical composition of peat humic acids by adsorption liquid chromatography

    Energy Technology Data Exchange (ETDEWEB)

    Platonov, V.V.; Proskuryakov, V.A.; Surasinkha, S.; Platonova, M.V.; Taran, N.A. [Lev Tolstoi State Pedagogical University, Tula (Russian Federation)

    1998-12-01

    The chemical composition of peat humic acids was studied in detail by IR and UV spectroscopy, elemental, emission spectral X-ray fluorescence, and structural-group analyses, cryoscopy, and capillary gas chromatography.

  10. Chemical composition and antibacterial activity of essential oils against human pathogenic bacteria

    NARCIS (Netherlands)

    Sokovic, M.; Marin, P.D.; Brkic, D.; Griensven, van L.J.L.D.

    2008-01-01

    The chemical composition and antibacterial activity of essential oils from 10 aromatic plants Matricaria chamommilla, Mentha piperita, M. spicata, Lavandula angustifolia, Ocimum basilicum, Thymus vulgaris, Origanum vulgare, Salvia officinalis, Citrus limon and C. aurantium have been determined. Anti

  11. Chemical composition and antibacterial activity of essential oils against human pathogenic bacteria

    NARCIS (Netherlands)

    Sokovic, M.; Marin, P.D.; Brkic, D.; Griensven, van L.J.L.D.

    2008-01-01

    The chemical composition and antibacterial activity of essential oils from 10 aromatic plants Matricaria chamommilla, Mentha piperita, M. spicata, Lavandula angustifolia, Ocimum basilicum, Thymus vulgaris, Origanum vulgare, Salvia officinalis, Citrus limon and C. aurantium have been determined.

  12. Variation in size, morphology and chemical composition of polymetallic nodules from the Central Indian Ocean Basin

    Digital Repository Service at National Institute of Oceanography (India)

    Valsangkar, A.B.; Karisiddaiah, S.M.; Parthiban, G.

    Chemical composition of 613 polymetallic nodules from 150 stations in the Central Indian Ocean Basin (CIOB) are determined and variations in Mn, Fe, Cu, Ni, Co, Zn and moisture content are studied with respect to their size and surface texture...

  13. Effects of chemical composition on the corrosion of dental alloys

    OpenAIRE

    GALO, Rodrigo; RIBEIRO, Ricardo Faria; RODRIGUES, Renata Cristina Silveira; Rocha, Luís Augusto; Mattos,Maria da Glória Chiarello de

    2012-01-01

    The aim of this study was to determine the effect of the oral environment on the corrosion of dental alloys with different compositions, using electrochemical methods. The corrosion rates were obtained from the current-potential curves and electrochemical impedance spectroscopy (EIS). The effect of artificial saliva on the corrosion of dental alloys was dependent on alloy composition. Dissolution of the ions occurred in all tested dental alloys and the results were strongly dependent on the g...

  14. Variation in the chemical composition, physical characteristics and ...

    African Journals Online (AJOL)

    Mariaan Viljoen

    detergent fibre (ADF) and in vitro organic matter digestibility (IVOMD). .... Results pertaining to the chemical analyses, physical properties and energy values of ...... presented in this paper may be valuable, especially when specific cultivars are ...

  15. Chemical composition and volatile compounds in the artisanal ...

    African Journals Online (AJOL)

    Araceli

    2012-09-27

    Sep 27, 2012 ... ends, the fermented product is transferred to copper ..... Clostridium bacteria or Kloeckera spp. yeast .... Evolution of chemical compounds during fermentation of A. angustifolia musts with and without addition of ammonium ...

  16. Chemically and Thermally Stable High Energy Density Silicone Composites Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Thermal energy storage systems with 300 ? 1000 kJ/kg energy density through either phase changes or chemical heat absorption are sought by NASA. This proposed effort...

  17. Chemical composition and insecticidal properties of essential oil ...

    African Journals Online (AJOL)

    chromatography/mass spectrometry (GC/MS) analysis was performed, and the contact (topical application) ... Results: Thirty-nine chemical compounds were identified by GC-MS analysis of M. .... negative control, and pyrethrum extract (25 %.

  18. Optimal drinking water composition for caries control in populations

    DEFF Research Database (Denmark)

    Bruvo, M.; Ekstrand, K.; Arvin, Erik;

    2008-01-01

    Apart from the well-documented effect of fluoride in drinking water on dental caries, little is known about other chemical effects. Since other ions in drinking water may also theoretically influence caries, as well as binding of fluoride in the oral environment, we hypothesized that the effect...... of drinking water on caries may not be limited to fluoride only. Among 22 standard chemical variables, including 15 ions and trace elements as well as gases, organic compounds, and physical measures, iterative search and testing identified that calcium and fluoride together explained 45% of the variations...... in the numbers of decayed, filled, and missing tooth surfaces (DMF-S) among 52,057 15-year-old schoolchildren in 249 Danish municipalities. Both ions had reducing effects on DMF-S independently of each other, and could be used in combination for the design of optimal drinking water for caries control...

  19. Toxicity of chemicals to microalgae in river and in standard waters.

    Science.gov (United States)

    Graff, Lionel; Isnard, Pascal; Cellier, Pierre; Bastide, Jean; Cambon, Jean-Pierre; Narbonne, Jean-Francois; Budzinski, Helene; Vasseur, Paule

    2003-06-01

    The influence of the composition of natural waters on the toxicity of chemicals to microalgae was studied on samples representative of western European rivers. Effects of zinc, pentachlorophenol (PCP), 4-nonylphenol (4-NP), phosalone, and 2,4,5-trichloroaniline (TCA) on algal growth were tested in river waters without adding any nutrients or cosolvents, and in the International Standards Organization (ISO) medium for comparison. The mean values of effective concentrations reducing the algal growth by 50% (EC50s) after 72 h based on measured concentrations did not differ significantly in natural waters and in standard medium for 4-NP (0.5 mg/L) and phosalone (0.8-0.9 mg/L). These values were two or three times higher in rivers than in ISO medium for PCP (0.25 vs 0.1 mg/L), TCA (1.69 vs 0.73 mg/L), and zinc (0.20 vs 0.056 mg/L). Although the mean values were of the same order of magnitude, the distribution of the EC50 values ranged over 1.5 and 2 log concentrations in surface waters. Therefore, in view of a refined hazard assessment of a chemical on a local scale, it would be advisable to use the actual river water of the concerned aquatic environment in testing. Correlations between toxicity data and the physicochemical characteristics of the waters identified classic parameters such as water hardness or conductivity as factors that significantly influenced the toxicity of the ionizable compounds PCP and zinc. On the other hand, organic materials or suspended solids, but only at high levels, affected the toxicity of 4-NP, an organic chemical with high adsorption potential. No correlation could be drawn for phosalone and TCA.

  20. Differential effects of conifer and broadleaf litter inputs on soil organic carbon chemical composition through altered soil microbial community composition

    Science.gov (United States)

    Wang, Hui; Liu, Shi-Rong; Wang, Jing-Xin; Shi, Zuo-Min; Xu, Jia; Hong, Pi-Zheng; Ming, An-Gang; Yu, Hao-Long; Chen, Lin; Lu, Li-Hua; Cai, Dao-Xiong

    2016-06-01

    A strategic selection of tree species will shift the type and quality of litter input, and subsequently magnitude and composition of the soil organic carbon (SOC) through soil microbial community. We conducted a manipulative experiment in randomized block design with leaf litter inputs of four native subtropical tree species in a Pinus massoniana plantation in southern China and found that the chemical composition of SOC did not differ significantly among treatments until after 28 months of the experiment. Contrasting leaf litter inputs had significant impacts on the amounts of total microbial, Gram-positive bacterial, and actinomycic PLFAs, but not on the amounts of total bacterial, Gram-negative bacterial, and fungal PLFAs. There were significant differences in alkyl/O-alkyl C in soils among the leaf litter input treatments, but no apparent differences in the proportions of chemical compositions (alkyl, O-alkyl, aromatic, and carbonyl C) in SOC. Soil alkyl/O-alkyl C was significantly related to the amounts of total microbial, and Gram-positive bacterial PLFAs, but not to the chemical compositions of leaf litter. Our findings suggest that changes in forest leaf litter inputs could result in changes in chemical stability of SOC through the altered microbial community composition.

  1. Chemical composition and antibacterial activity of essential oils from the Tunisian Allium nigrum L.

    OpenAIRE

    Rouis-Soussi, Lamia Sakka; Ayeb-Zakhama, El Asma; Mahjoub, Aouni; Flamini, Guido; Jannet, Hichem Ben; Harzallah-Skhiri, Fethia

    2014-01-01

    The chemical composition of the essential oils of different Allium nigrum L. organs and the antibacterial activity were evaluated. The study is particularly interesting because hitherto there are no reports on the antibacterial screening of this species with specific chemical composition. Therefore, essential oils from different organs (flowers, stems, leaves and bulbs) obtained separately by hydrodistillation were analyzed using gas chromatography–mass spectrometry (GC–MS). The antibacterial...

  2. Water quality index calculated from biological, physical and chemical attributes.

    Science.gov (United States)

    Rocha, Francisco Cleiton; Andrade, Eunice Maia; Lopes, Fernando Bezerra

    2015-01-01

    To ensure a safe drinking water supply, it is necessary to protect water quality. To classify the suitability of the Orós Reservoir (Northeast of Brazil) water for human consumption, a Water Quality Index (WQI) was enhanced and refined through a Principal Component Analysis (PCA). Samples were collected bi-monthly at seven points (P1 - P7) from July 2009 to July 2011. Samples were analysed for 29 physico-chemical attributes and 4 macroinvertebrate metrics associated with the macrophytes Pistia stratiotes and Eichhornia crassipes. PCA allowed us to reduce the number of attributes from 33 to 12, and 85.32% of the variance was explained in five dimensions (C1 - C5). Components C1 and C3 were related to water-soluble salts and reflect the weathering process, while C2 was related to surface runoff. C4 was associated with macroinvertebrate diversity, represented by ten pollution-resistant families. C5 was related to the nutrient phosphorus, an indicator of the degree of eutrophication. The mean values for the WQIs ranged from 49 to 65 (rated as fair), indicating that water can be used for human consumption after treatment. The lowest values for the WQI were recorded at the entry points to the reservoir (P3, P1, P5, and P4), while the best WQIs were recorded at the exit points (P6 and P7), highlighting the reservoir's purification ability. The proposed WQI adequately expressed water quality, and can be used for monitoring surface water quality.

  3. Physical chemical properties of sludges of a chemical treatment of boilers feed water and ways of their utilization

    Directory of Open Access Journals (Sweden)

    T. Krasnenko

    2013-03-01

    Full Text Available Water is a necessary process for TPP power plant operation. To the power station, in the production of electricity and heat as a result of the preparation of large amounts of water to compensate for losses associated with the release of process steam for production, produce large quantities of waste water treatment - water treatment chemical sludge (WTCS.

  4. Chemical composition of PM2.5 from two tunnels with different vehicular fleet characteristics.

    Science.gov (United States)

    Cui, Min; Chen, Yingjun; Tian, Chongguo; Zhang, Fan; Yan, Caiqing; Zheng, Mei

    2016-04-15

    The chemical compositions of PM2.5 including OC, EC, water soluble ions, elements, and organic components such as polycyclic aromatic hydrocarbons (PAHs), hopanes, and steranes, emitted in Wuzushan (WZS) and Kuixinglou (KXL) tunnels were determined. WZS tunnel is a major route for diesel vehicles traveling, while KXL tunnel has limited to diesel vehicles. The results showed that the proportions of the different constituents of PM2.5 in the Wuzushan (WZS) tunnel were OC (27.7%), EC (32.1%), elements (13.9%), and water soluble ions (9.2%). Whereas the chemical profile of PM2.5 in the Kuixinglou (KXL) tunnel was OC (17.7%), EC (10.4%), elements (8.90%), and water soluble ions (8.87%). The emission factors (EFs) of PM2.5 and proportions of SO4(2-) and Pb were decreased by vehicle emission standards and fuel quality policy in China, and the higher molecular weight PAHs (4+5+6 rings) were more abundant than the lower molecular weight PAHs (2+3 rings) in the two tunnels. The proportions of 17A(H)-21B(H)-30-Norhopane and 17A(H)-21B(H)-Hopane in the hopane and sterane were not dependent on the vehicles types. In addition, specific composition profiles for PM2.5 from gasoline-fueled vehicles (GV) and diesel-fueled vehicles (DV) emissions were drafted, which indicated that OC (0.974mg·veh(-1)·km(-1)) was the most abundant component in PM2.5, followed by Fe, Cl(-), and Mg for GV. The relative proportions of the different constituents in the PM2.5 for DV were EC (35.9%), OC (27.2%), elements (12.8%), and water soluble ions (11.7%). Both the PM2.5 EFs and EC proportions in DV were higher than those in GV, and the HMW PAHs were the dominant PAHs for both GV and DV. The PM2.5 emissions from the vehicles in Yantai were 581±513tons to 1353±1197tons for GV, and 19,627±2477tons to 23,042±2887tons for DV, respectively.

  5. Physical, chemical and microbial analysis of bottled drinking water.

    Science.gov (United States)

    Sasikaran, S; Sritharan, K; Balakumar, S; Arasaratnam, V

    2012-09-01

    People rely on the quality of the bottled drinking water, expecting it to be free of microbial contamination and health hazards. To evaluate the quality of bottled drinking water sold in Jaffna peninsula by analysing the physical, chemical and microbial contents and comparing with the recommended Sri Lankan Standard (SLS) values. All bottled water samples sold in Jaffna peninsula were collected. Electrical conductivity, total dissolved solid, pH, calcium, nitrate, total aerobic and anaerobic count, coliform bacterial count and faecal contamination were checked. These are 22 brands of bottled drinking water sold in Jaffna peninsula. The sample had very low electrical conductivity when compared with SLS (750 μS/ cm) and varied from 19 to 253 μS/cm with the mean of 80.53 (±60.92) μS/cm. The pH values of the bottled drinking water brands varied from 4.11 to 7.58 with a mean of 6.2 (±0.75). The total dissolved solid content of the bottled drinking water brands varied from 9 to 123.67 mg/l with a mean of 39.5 (±30.23) mg/l. The calcium content of the bottled drinking water brands varied from 6.48 to 83.77 mg/l with a mean of 49.9 (±25.09) mg/l. The nitrate content of the bottled drinking water brands varied from 0.21 to 4.19 mg/l with the mean of 1.26 (±1.08) mg/l. Aerobic bacterial count varied from 0 to 800 colony forming unit per ml (cfu/ml) with a mean of 262.6 (±327.50) cfu/ml. Among the 22 drinking bottled water brands 14 and 9% of bottled drinking water brands showed fungal and coliform bacterial contaminants respectively. The water brands which contained faecal contamination had either Escherichia coli or Klebsiella spp. The bottled drinking water available for sale do not meet the standards stipulated by SLS.

  6. Designing water supplies: Optimizing drinking water composition for maximum economic benefit.

    Science.gov (United States)

    Rygaard, M; Arvin, E; Bath, A; Binning, P J

    2011-06-01

    It is possible to optimize drinking water composition based on a valuation of the impacts of changed water quality. This paper introduces a method for assessing the potential for designing an optimum drinking water composition by the use of membrane desalination and remineralization. The method includes modeling of possible water quality blends and an evaluation of corrosion indices. Based on concentration-response relationships a range of impacts on public health, material lifetimes and consumption of soap have been valued for Perth, Western Australia and Copenhagen, Denmark. In addition to water quality aspects, costs of water production, fresh water abstraction and CO(2)-emissions are integrated into a holistic economic assessment of the optimum share of desalinated water in water supplies. Results show that carefully designed desalination post-treatment can have net benefits up to €0.3 ± 0.2 per delivered m(3) for Perth and €0.4(±0.2) for Copenhagen. Costs of remineralization and green house gas emission mitigation are minor when compared to the potential benefits of an optimum water composition. Finally, a set of optimum water quality criteria is proposed for the guidance of water supply planning and management.

  7. Chitosan on Reducing Chemical Oxygen Demands in Laundry Waste Water

    Directory of Open Access Journals (Sweden)

    Tri Joko

    2016-09-01

    Full Text Available Laundry liquid waste contains several chemical substances in detergent raw materials such as phosphate, surfactants, ammonia, and total suspended solids. The existence of detergent in high concentrations and exceeds the quality standards that have been estabilished in a body of water can lead to cases of enviromental pollution in the form of increased turbidity an Chemical Oxygen Demands (COD levels. Therefore in order to maintain and to ensure the availabillity of water in terms of quality, it requires coagulation-flocculation process to laundry liquid waste before discharging into water bodies. This study aims to determine the decrease of COD levels and turbidity level in laundry liquid waste using chitosan coagulant in “X” laundry, Tembalang District, Semarang. The research is a quasi experimental study with pretest-posttest with control group research design with 6 times replication. The total samples are 60 in wich 24 tested for the levels of turbidity and 6 controls. The test results of Kruskal-Wallis with significance p-value < 0,05 indicates that dosage variation (p=0,000 gives different levels of COD and dosage variation (p=0,000 provide 755,97 mg/l and the advantage levels of turbidity before treatment was 516,20 NTU. The optimum dosage of chitosan coagulant is on the dose of 200 mg/l with the effectiveness decrease of COD levels and turbidity levels on 72,67% an 98,67% respectively.

  8. Excess chemical potential of small solutes across water--membrane and water--hexane interfaces

    Science.gov (United States)

    Pohorille, A.; Wilson, M. A.

    1996-01-01

    The excess chemical potentials of five small, structurally related solutes, CH4, CH3F, CH2F2, CHF3, and CF4, across the water-glycerol 1-monooleate bilayer and water-hexane interfaces were calculated at 300, 310, and 340 K using the particle insertion method. The excess chemical potentials of nonpolar molecules (CH4 and CF4) decrease monotonically or nearly monotonically from water to a nonpolar phase. In contrast, for molecules that possess permanent dipole moments (CH3F, CH2F, and CHF3), the excess chemical potentials exhibit an interfacial minimum that arises from superposition of two monotonically and oppositely changing contributions: electrostatic and nonelectrostatic. The nonelectrostatic term, dominated by the reversible work of creating a cavity that accommodates the solute, decreases, whereas the electrostatic term increases across the interface from water to the membrane interior. In water, the dependence of this term on the dipole moment is accurately described by second order perturbation theory. To achieve the same accuracy at the interface, third order terms must also be included. In the interfacial region, the molecular structure of the solvent influences both the excess chemical potential and solute orientations. The excess chemical potential across the interface increases with temperature, but this effect is rather small. Our analysis indicates that a broad range of small, moderately polar molecules should be surface active at the water-membrane and water-oil interfaces. The biological and medical significance of this result, especially in relation to the mechanism of anesthetic action, is discussed.

  9. Chemical composition of Artemisia annua L. leaves and antioxidant potential of extracts as a function of extraction solvents.

    Science.gov (United States)

    Iqbal, Shahid; Younas, Umer; Chan, Kim Wei; Zia-Ul-Haq, Muhammad; Ismail, Maznah

    2012-05-21

    This study was conducted to investigate the chemical and nutritional composition of Artemisia annua leaves in addition to determination of antioxidant potential of their extracts prepared in different solvents. Chemical composition was determined by quantifying fat, protein, carbohydrate, fiber, tocopherol, phytate, and tannin contents. Extraction of A. annua leaves, for antioxidant potential evaluation, was carried out using five solvents of different polarities, i.e., hexane, chloroform, ethyl acetate, methanol and water. Antioxidant potential was evaluated by estimating total phenolic (TPC), flavonoid (TFC) contents, ferric reducing antioxidant power (FRAP), Trolox equivalent antioxidant capacity (TEAC), DPPH radical scavenging activity and lipid peroxidation. Efficiency of different solvents was compared for the yield of antioxidant extracts from leaf samples and a clear variation was observed. The highest TPC, TFC, TEAC, DPPH radical scavenging and lowest lipid peroxidation were observed in MeOH extracts, whereas aqueous extract exhibited high ferric reducing antioxidant power; suggesting MeOH to be the most favorable extractant.

  10. Dynamic Adsorptive Removal of Toxic Chemicals for Purification of Water

    Directory of Open Access Journals (Sweden)

    Amit Saxena

    2005-04-01

    Full Text Available To determine the efficiency of carbon column for the removal of toxic chemicals from water, the adsorption of phenol in concentration range from 0.600 glt to 1.475 gll was studied on activecarbon of 80 CTC grade, 12 X 30 BSS particle size, 1280 m2/g surface area, and of coconut shell origin, under dynamic conditions at space velocity from 0.318 min-' to 4.24 min-' at 25 'C. The carbon column of 100 cm length and 2 cm diameter was found to be removing phenol from the aqueous solution of concentration 1.475 gll up to 84 min at 0.678 min-' space velocity at 5.0 ppm phenol breakthrough concentration. However, no phenol was observed in carbon-treated water after 80 min. The service life of carbon column (100 cm lengthX25 cm diameter was assessed through the water purification system developed at the Defence Laboratory, Jodhpur and was determined to be 4.095 days with twoas factor of safety for 10 ppm initial concentration of phenol at 0.678 min-' space velocity (corresponding to water flow rate. Effects of carbon bed length, water flow rate, and the phenol concentration were also studied.

  11. Sorption kinetics of ethanol/water solution by dimethacrylate-based dental resins and resin composites.

    Science.gov (United States)

    Sideridou, Irini D; Achilias, Dimitris S; Karabela, Maria M

    2007-04-01

    In the present investigation the sorption-desorption kinetics of 75 vol % ethanol/water solution by dimethacrylate-based dental resins and resin composites was studied in detail. The resins examined were made by light-curing of bisphenol A glycol dimethacrylate (Bis-GMA), triethylene glycol dimethacrylate (TEGDMA), urethane dimethacrylate (UDMA), bisphenol A ethoxylated dimethacrylate (Bis-EMA), and mixtures of these monomers. The resin composites were prepared from two commercial light-cured restorative materials (Z100 MP and Filtek Z250), the resin matrix of which is based on copolymers of the above-mentioned monomers. Ethanol/water sorption/desorption was examined in both equilibrium and dynamic conditions in two adjacent sorption-desorption cycles. For all the materials studied, it was found that the amount of ethanol/water sorbed or desorbed was always larger than the corresponding one reported in literature in case of water immersion. It was also observed that the chemical structure of the monomers used for the preparation of the resins directly affects the amount of solvent sorbed or desorbed, as well as sorption kinetics, while desorption rate was nearly unaffected. In the case of composites studied, it seems that the sorption/desorption process is not influenced much by the presence of filler. Furthermore, diffusion coefficients calculated for the resins were larger than those of the composites and were always higher during desorption than during sorption. Finally, an interesting finding concerning the rate of ethanol/water sorption was that all resins and composites followed Fickian diffusion kinetics during almost the whole sorption curve; however, during desorption the experimental data were overestimated by the theoretical model. Instead, it was found that a dual diffusion-relaxation model was able to accurately predict experimental data during the whole desorption curve. Kinetic relaxation parameters, together with diffusion coefficients, are reported

  12. Milk production and chemical composition of milk of Ukrainian mountain Carpathian sheep in pasture period

    OpenAIRE

    CHOKAN T.

    2011-01-01

    The comparative analysis of the milk chemical composition depending on milk productivity of Ukrainian Mountain Carpathian sheep during the pasture period were studied. It was found changes of milk composition (increasing of protein content, fat, dry matter and nutritive value) with a decrease of milk yield in the end period of lactation.

  13. Chemical erosion of different carbon composites under ITER-relevant plasma conditions

    NARCIS (Netherlands)

    Westerhout, J.; Borodin, D.; Al, R.S.; Brezinsek, S.; Hoen, Mhjt; Kirschner, A.; Lisgo, S.; van der Meiden, H. J.; Philipps, V.; van de Pol, M.J.; Shumack, A. E.; De Temmerman, G.; Vijvers, W. A. J.; Wright, G. M.; Cardozo, N. J. L.; Rapp, J.; van Rooij, G. J.

    2009-01-01

    We have studied the chemical erosion of different carbon composites in Pilot-PSI at ITER-relevant hydrogen plasma fluxes (similar to 10(24) m(-2) s(-1)) and low electron temperatures (T-e similar to 1 eV). Optical emission spectroscopy on the CH A-X band was used to characterize the chemical

  14. Effect of solvents on the chemical and physical properties of ionic polymer-metal composites

    Science.gov (United States)

    Nemat-Nasser, Sia; Zamani, Shahram; Tor, Yitzhak

    2006-05-01

    Ionic polymer-metal composites (IPMCs) consist of a perfluorinated ionomer membrane (usually Nafion® or Flemion®) plated on both faces with a noble metal such as gold or platinum and neutralized with a certain amount of counterions that balance the electrical charge of anions covalently fixed to the backbone ionomer. IPMCs are electroactive materials with potential applications as actuators and sensors. Their electrical-chemical-mechanical response is dependent on the cations used, the nature and the amount of solvent uptake, the morphology of the electrodes, the composition of the backbone ionomer, the geometry and boundary conditions of the composite element, and the magnitude and spatial and time variation of the applied potential. With water as the solvent, the applied electric potential must be limited to less than 1.3 V at room temperature, to avoid electrolysis. Moreover, water evaporation in open air presents additional problems. These and related factors limit the application of IPMCs with water as the solvent. We present the results of a series of tests on both Nafion- and Flemion-based IPMCs with ethylene glycol, glycerol, and crown ethers as solvents. IPMCs with these solvents have greater solvent uptake and can be subjected to relatively high voltages without electrolysis. They can be actuated in open air for rather long time periods, and at low temperatures. They may be good actuators when high-speed actuation is not necessary. In addition, their slow response in open air allows direct observation of the physical characteristics of the cathode and anode surfaces of a cantilever during actuations. This can provide additional clues for unraveling the underpinning micromechanisms of their actuation. Remarkably, solvents are found to have profound effects on the nature of the IPMCs' actuation. For example, Nafion-based IPMCs in Li+ form show very small back relaxation when hydrated, but extensive back relaxation with all other solvents that we have

  15. Effect of Chemical Treatment of Sesame Stover with NaOH and Urea on Chemical Composition and In vivo Rumen Digestion in Sheep

    Directory of Open Access Journals (Sweden)

    Mohammad MALEKKHAHI

    2014-03-01

    Full Text Available This study tested the effect of urea, urea sodium hydroxide (NaOH and NaOH + urea on chemical composition and total tract nutrition in sheep. Treated stovers were prepared by mixing stovers with aqueous solution of urea (SU, 3g in 100 ml water /100 g DM, NaOH (SN, 4g in 100 ml water /100g DM and urea + NaOH (SUN. Five male Balouchi sheep (30 ±1.4 kg were used in a change-over design. In vivo experimental diets were as follows: alfalfa hay (AH, alfalfa hay + S (AHS, alfalfa hay + SU (AH SU, alfalfa hay + SN (AHSN and alfalfa hay + SUN (AHSUN. The NDF content significantly (P0.05 in urea and NaOH. The urea caused a significant (P<0.05 increase in CP content of sesame stover. The digestibility coefficients of DM, OM, NDF and ADF increased with chemically treatment of sesame stover. Furthermore, rumen pH was not affected by the chemical treatment, while rumen NH3- N (P<0.05 concentration was enhanced by urea +NaOH treatment. These results suggest that digestibility of DM, OM, CP, NDF and ADF could be improved by chemical treatment with urea and NaOH.

  16. An Investigation on Physical and Chemical Quality of Spring Waters

    Directory of Open Access Journals (Sweden)

    Fesem BAŞARI

    2010-12-01

    Full Text Available Objective: The aim of this study was to analyse the chemical and physical qualities of spring water coming to Water Chemistry Laboratory of Adana Hygiene Institute in 2009. The water quality parameters analysed were colour, flavor, odour, turbidity, conductivity, pH, iron, aluminum, boron, manganese, arsenic, ammonia, ozone and bromate. Method: The spring water samples coming to the laboratory, colour in 59 samples, flavor in 22 samples, odour in 57 samples, turbidity and bromate in 61 samples, pH in 63 samples, conductivity in 62 samples, aluminum and iron in 30 samples, boron in 15 samples, arsenic and manganese in 18 samples, ammonia in 60 samples, ozone in 48 samples were studied. ISO (International Organization for Standardization, DIN (Deutsches Institut für Normung, TS (Turkish Standard methods were used for study. The results evaluated according to criterion of ‘‘Regulation on the Quality of Water Intended for Human Comsumption’’.Results: As a result of physical analysis of spring water, turbidity was assigned in just two (%3,2 of 61 samples. pH and conductivity were studied in 63 and in 62 samples respectively and all the values were appropriate. Higher concentrations than the regulation limits were found for bromate in three samples (4,9 % of 61, and in one sample of respectively boron (6,7 % out of 15, manganese (5,6 % out of 18 and arsenic (5,6% out of 18. Aluminum, ammonia, iron and ozone values in the analized samples were not found over the limits.Conclusion: Being found of bromate rates high was related to ozonize. And found of boron, manganese and arsenic was a symptom of dangerous pollution in terms of health. So, spring water pollution control essential for public health.

  17. Recent Advances in the Chemical Composition of Propolis

    Directory of Open Access Journals (Sweden)

    Shuai Huang

    2014-11-01

    Full Text Available Propolis is a honeybee product with broad clinical applications. Current literature describes that propolis is collected from plant resins. From a systematic database search, 241 compounds were identified in propolis for the first time between 2000 and 2012; and they belong to such diverse chemical classes as flavonoids, phenylpropanoids, terpenenes, stilbenes, lignans, coumarins, and their prenylated derivatives, showing a pattern consistent with around 300 previously reported compounds. The chemical characteristics of propolis are linked to the diversity of geographical location, plant sources and bee species.

  18. Pasta added with chickpea flour: chemical composition, In vitro starchdigestibility and predicted glycemic index

    OpenAIRE

    2008-01-01

    Pasta was prepared with of durum wheat flour mixed with chickpea flour at two different levels and its chemical composition, in vitro starch digestibility and predicted glycemic index were assessed. Protein, ash, lipid, and dietary fiber content increased while total starch decreased with the chickpea flour level in the composite pasta, all in accordance to the composition of the legume flour. Potentially available starch decreased and resistant starch (RS) increased by adding chickpea flour ...

  19. Chemical composition and yield of essential oil from three Croton species

    Directory of Open Access Journals (Sweden)

    Giuliane Sampaio de Souza

    Full Text Available ABSTRACT: Marmeleiros are popularly known for the medicinal properties ascribed to their essential oils. This research aimed to analyze the essential oil of leaves from three Croton species (Croton argyrophylloides, Croton jacobinensis, and Croton sincorensis, to verify whether the daily time and harvest season in the year may interfere with their essential oils performance and composition. From each species, 1,500g of green leaves were harvested in Viçosa do Ceará - CE, at 6am and 12pm, during both dry and rainy seasons. Essential oil extraction was conducted by the method of water vapor drag and chemical profile was analyzed by gas chromatography-mass spectrometry (GC/MS. The highest yield was obtained at 12pm in the dry season for C. argyrophylloides and C. jacobinensis, and at 6am in the rainy season for C. sincorensis. Bicyclogermacrene demonstrated higher relative abundance in C. argyrophylloides (28.09 to 30.59%, C. jacobinensis (25.2 to 30.14%, and C. sincorensis (23.86 and 21.71%, and the only exception was at 6am in C. sincorensis, where (E-caryophyllene was the most abundant compound (25.34%. The yield and composition of the studied species were influenced by rainfall, temperature, and sunlight, presenting statistical significant differences between the different periods studied. The species produce constituents with specific biological properties; and therefore, they can be used as a natural source.

  20. Chemical Composition, Antioxidant, Anti-Inflammatory, and Antiproliferative Activities of the Plant Lebanese Crataegus Azarolus L.

    Science.gov (United States)

    Kallassy, Hany; Fayyad-Kazan, Mohammad; Makki, Rawan; El-Makhour, Yolla; Hamade, Eva; Rammal, Hasan; Leger, David Y; Sol, Vincent; Fayyad-Kazan, Hussein; Liagre, Bertrand; Badran, Bassam

    2017-08-03

    BACKGROUND In the present study, phytochemical screening, antioxidant, anti-inflammatory, and antiproliferative capacities of 3 extracts from leaves of Lebanese Crataegus azarolus L. were evaluated. MATERIAL AND METHODS Fresh leaves were dissolved in 3 different solvents: distilled water, ethanol, and methanol. The chemical composition was determined using high-performance liquid chromatography (HPLC) and the content of essential oil of this plant was examined by gas chromatography (GC) coupled with mass spectrometry (MS). The antioxidant potential was evaluated using DPPH radical scavenging and Fe2+ chelating activity assays. Anti-inflammatory effect was investigated by measuring the secreted amounts of the proinflammatory mediator PGE2 using ELISA technique, as well as by assaying the mRNA levels of the proinflammatory cytokines (IL-α, IL-β, and Il-6), chemokines (CCL3 and CCL4) and inflammation-sensitive COX2 and iNOS enzymes using quantitative real-time PCR (qRT-PCR). The antiproliferative effect was evaluated using the XTT viability assay. RESULTS The obtained results show that alcohol (methanol and ethanol) extracts were rich in bioactive molecules with medical relevance and exerted substantial antioxidant, anti-inflammatory, and antiproliferative capacities. On the other hand, aqueous extract contained fewer chemical components and exhibited less therapeutic efficiency. CONCLUSIONS Our observations indicate that Crataegus azarolus L. could be used for treating diseases related to oxidative stress, inflammatory reactions, and uncontrolled cell growth.

  1. Chemical drinking water quality in Ghana: water costs and scope for advanced treatment.

    Science.gov (United States)

    Rossiter, Helfrid M A; Owusu, Peter A; Awuah, Esi; Macdonald, Alan M; Schäfer, Andrea I

    2010-05-01

    To reduce child mortality and improve health in Ghana boreholes and wells are being installed across the country by the private sector, NGO's and the Ghanaian government. Water quality is not generally monitored once a water source has been improved. Water supplies were sampled across Ghana from mostly boreholes, wells and rivers as well as some piped water from the different regions and analysed for the chemical quality. Chemical water quality was found to exceed the WHO guidelines in 38% of samples, while pH varied from 3.7 to 8.9. Excess levels of nitrate (NO(3)(-)) were found in 21% of the samples, manganese (Mn) and fluoride (F(-)) in 11% and 6.7%, respectively. Heavy metals such as lead (Pb), arsenic (As) and uranium (U) were localised to mining areas. Elements without health based guideline values such as aluminium (Al, 95%) and chloride (Cl, 5.7%) were found above the provisional guideline value. Economic information was gathered to identify water costs and ability to pay. Capital costs of wells and boreholes are about pound1200 and pound3800 respectively. The majority of installation costs are generally paid by the government or NGO's, while the maintenance is expected to be covered by the community. At least 58% of the communities had a water payment system in place, either an annual fee/one-off fee or "pay-as-you-fetch". The annual fee was between pound0.3-21, while the boreholes had a water collection fee of pound0.07-0.7/m(3), many wells were free. Interestingly, the most expensive water ( pound2.9-3.5/m(3)) was brought by truck. Many groundwater sources were not used due to poor chemical water quality. Considering the cost of unsuccessful borehole development, the potential for integrating suitable water treatment into the capital and maintenance costs of water sources is discussed. Additionally, many sources were not in use due to lack of water capacity, equipment malfunction or lack of economic resources to repair and maintain equipment. Those

  2. Chemical composition of acid precipitation in central Texas

    Science.gov (United States)

    Hal B. H., Jr. Cooper; Jerry M. Demo; Jose A. Lopez

    1976-01-01

    Studies were undertaken to determine factors affecting composition of acidic precipitation formation in the Austin area of Central Texas. The study was initiated to determine background levels of acid and alkalinity producing constituents in an area with elevated natural dust levels from nearby limestone rock formations. Results showed normal rainfall pH values of 6.5...

  3. On the Formation and Chemical Composition of Super Earths

    Science.gov (United States)

    Alessi, Matthew; Pudritz, Ralph E.; Cridland, Alex J.

    2016-09-01

    Super Earths are the largest population of exoplanets and are seen to exhibit a rich diversity of compositions as inferred through their mean densities. Here we present a model that combines equilibrium chemistry in evolving disks with core accretion that tracks materials accreted onto planets during their formation. In doing so, we aim to explain why super Earths form so frequently and how they acquire such a diverse range of compositions. A key feature of our model is disk inhomogeneities, or planet traps, that act as barriers to rapid type-I migration. The traps we include are the dead zone, which can be caused by either cosmic ray or X-ray ionization, the ice line, and the heat transition. We find that in disks with sufficiently long lifetimes (≳ 4 Myr), all traps produce Jovian planets. In these disks, planet formation in the heat transition and X-ray dead zone produces hot Jupiters while the ice line and cosmic ray dead zones produce Jupiters at roughly 1 AU. Super Earth formation takes place within short-lived disks (≲ 2 Myr), whereby the disks are photoevaporated while planets are in a slow phase of gas accretion. We find that super Earth compositions range from dry and rocky ( 30 % ice by mass). The traps play a crucial role in our results, as they dictate where in the disk particular planets can accrete from, and what compositions they are able to acquire.

  4. On the formation and chemical composition of super Earths

    Science.gov (United States)

    Alessi, Matthew; Pudritz, Ralph E.; Cridland, Alex J.

    2017-01-01

    Super Earths are the largest population of exoplanets and are seen to exhibit a rich diversity of compositions as inferred through their mean densities. Here we present a model that combines equilibrium chemistry in evolving discs with core accretion that tracks materials accreted on to planets during their formation. In doing so, we aim to explain why super Earths form so frequently and how they acquire such a diverse range of compositions. A key feature of our model is disc inhomogeneities, or planet traps, that act as barriers to rapid type-I migration. The traps we include are the dead zone, which can be caused by either cosmic ray or X-ray ionization, the ice line, and the heat transition. We find that in discs with sufficiently long lifetimes (≳4 Myr), all traps produce Jovian planets. In these discs, planet formation in the heat transition and X-ray dead zone produces hot Jupiters, while the ice line and cosmic ray dead zones produce Jupiters at roughly 1 au. Super Earth formation takes place within short-lived discs (≲2 Myr), whereby the discs are photoevaporated while planets are in a slow phase of gas accretion. We find that super Earth compositions range from dry and rocky (30 per cent ice by mass). The traps play a crucial role in our results, as they dictate where in the disc particular planets can accrete from, and what compositions they are able to acquire.

  5. Effect of Chemical and Mineralogical Composition of Rocks on the ...

    African Journals Online (AJOL)

    Ethiopian Journal of Environmental Studies and Management ... composition of rocks on the chemistry of the groundwater quality. ... The predominant cations trend in both the groundwater and rock samples the study ... Therefore, it is concluded that the local rock chemistry is seriously affecting the groundwater chemistry.

  6. MULTILAYER POROUS COMPOSITE FROM WASTE GLASS FOR WATER FILTRATION

    Directory of Open Access Journals (Sweden)

    M. P. Aji

    2015-07-01

    Full Text Available Multilayer porous composite have been produced through the heating process at temperature T=700oC for 2.5 h. Single layered porous composite was made with a varied mass percentage of from PEG polymer  1% to 10%. Double-layered porous composite were made by the arrangement of porosity (4:3%, (4:2% and (3:2%, while the three-layers porous composite have an arrangement (4:3:2%. Performance of multilayer porous composite for water filtration with pollutants of methylene blue 100 ppm was estimated from the absorbance spectrum. Rejection of methylene blue pollutants from single layered porous composite increases when the fraction of PEG polymer tend to be smaller in the matrix. Meanwhile, the double layered porous composite has a degradation of methylene blue pollutants are better than one layer. Triple layered porous composite have good performance for the water filtration where all the pollutants of methylene blue be able to be filtered.   Komposit pori berlapis telah dihasilkan dengan proses pemanasan pada temperatur T=700oC selama 2.5 jam. Komposit pori satu lapis dibuat dengan variasi persen massa polimer PEG 1% hingga 10%. Komposit pori dua lapis dibuat dengan susunan porositas (4:3%, (4:2% dan (3:2%, sedangkan komposit pori tiga lapis memiliki susunan porositas (4:3:2%. Kinerja komposit pori berlapis untuk filter air dengan polutan methylene blue 100 ppm diestimasi dari spektrum absorbansi. Rejeksi polutan methylene blue dari komposit pori satu lapis meningkat saat fraksi polimer PEG cenderung lebih kecil dalam matrik komposit. Sedangkan, komposit pori dua lapis memiliki kemampuan untuk degradasi polutan methylene blue yang lebih baik dari satu lapis. Komposit pori tiga lapis memiliki kinerja yang baik untuk filter air dimana seluruh polutan methylene blue mampu disaring. 

  7. Variation in global chemical composition of PM2.5: emerging results from SPARTAN

    Science.gov (United States)

    Snider, Graydon; Weagle, Crystal L.; Murdymootoo, Kalaivani K.; Ring, Amanda; Ritchie, Yvonne; Stone, Emily; Walsh, Ainsley; Akoshile, Clement; Anh, Nguyen Xuan; Balasubramanian, Rajasekhar; Brook, Jeff; Qonitan, Fatimah D.; Dong, Jinlu; Griffith, Derek; He, Kebin; Holben, Brent N.; Kahn, Ralph; Lagrosas, Nofel; Lestari, Puji; Ma, Zongwei; Misra, Amit; Norford, Leslie K.; Quel, Eduardo J.; Salam, Abdus; Schichtel, Bret; Segev, Lior; Tripathi, Sachchida; Wang, Chien; Yu, Chao; Zhang, Qiang; Zhang, Yuxuan; Brauer, Michael; Cohen, Aaron; Gibson, Mark D.; Liu, Yang; Vanderlei Martins, J.; Rudich, Yinon; Martin, Randall V.

    2016-08-01

    The Surface PARTiculate mAtter Network (SPARTAN) is a long-term project that includes characterization of chemical and physical attributes of aerosols from filter samples collected worldwide. This paper discusses the ongoing efforts of SPARTAN to define and quantify major ions and trace metals found in fine particulate matter (PM2.5). Our methods infer the spatial and temporal variability of PM2.5 in a cost-effective manner. Gravimetrically weighed filters represent multi-day averages of PM2.5, with a collocated nephelometer sampling air continuously. SPARTAN instruments are paired with AErosol RObotic NETwork (AERONET) sun photometers to better understand the relationship between ground-level PM2.5 and columnar aerosol optical depth (AOD).We have examined the chemical composition of PM2.5 at 12 globally dispersed, densely populated urban locations and a site at Mammoth Cave (US) National Park used as a background comparison. So far, each SPARTAN location has been active between the years 2013 and 2016 over periods of 2-26 months, with an average period of 12 months per site. These sites have collectively gathered over 10 years of quality aerosol data. The major PM2.5 constituents across all sites (relative contribution ± SD) are ammoniated sulfate (20 % ± 11 %), crustal material (13.4 % ± 9.9 %), equivalent black carbon (11.9 % ± 8.4 %), ammonium nitrate (4.7 % ± 3.0 %), sea salt (2.3 % ± 1.6 %), trace element oxides (1.0 % ± 1.1 %), water (7.2 % ± 3.3 %) at 35 % RH, and residual matter (40 % ± 24 %).Analysis of filter samples reveals that several PM2.5 chemical components varied by more than an order of magnitude between sites. Ammoniated sulfate ranges from 1.1 µg m-3 (Buenos Aires, Argentina) to 17 µg m-3 (Kanpur, India in the dry season). Ammonium nitrate ranged from 0.2 µg m-3 (Mammoth Cave, in summer) to 6.8 µg m-3 (Kanpur, dry season). Equivalent black carbon ranged from 0.7 µg m-3 (Mammoth Cave) to over 8 µg m-3 (Dhaka, Bangladesh and Kanpur

  8. Chemical composition and in vitro dry matter digestibility of lichens

    Directory of Open Access Journals (Sweden)

    Torstein H. Garmo

    1986-06-01

    Full Text Available The chemical composition and in vitro dry matter digestibility of 45 samples of different species of lichen are reported. Mean content (g/100 g dry matter of the main nutrients was: crude protein 4.2, crude fat 3.2, crude fibre 16.6, ash 1.9, Ca 0.15, P 0.09, Mg 0.05, K 0.13, Na 0.035, S 0.07. The content of microminerals (mg/kg dry matter was: Cu 2.5, Mo 0.11, Zn 27.2, Se 0.12, Fe 898, Mn 154. The mean in vitro dry matter digestibility was 35%. However, the in vitro method do underestimate the dry matter digestibility of lichens. Stereocaulon spp. showed higher levels of crude protein, P, S, Cu and Mo than Cetraria spp. and Cladonia spp. Cetraria nivalis showed higher digestibility and contained more NFE, ash, Ca, Mg, but less crude fibre than Cladonia stellaris. Lichens contained less amounts of most nutrients compared with grasses (Fig. 1, exept for crude fat, NFE, Se and Fe.Kjemisk innhald og in vitro fordøyelsesgrad av lav.Abstract in Norwegian / Samandrag: Kjemisk innhald og in vitro fordøyelsesgrad av tørrstoffet er bestemt i 45 prøver av beitelav frå to stader i Sør-Noreg. Middel innhald (g/100g tørrstoff av følgjande næringsstoff var: protein 4.2, feitt 3.2, trevlar 16.6, oske 1.9, kalsium 0.15, fosfor 0.09, magnesium 0.05, kalium 0.13, natrium 0.035, svovel 0.07. Innhaldet (mg/kg tørrstoff av mikronæringsstoffa var: kopar 2.5, molybden 0.11, sink 27.2, selen 0.12, jern 898 og mangan 154. Den midlare fordøyelsesgraden av tørrstoffet i lav-prøvene var 35%, men in vitro fordøyelsesanalyser undervurderer fordøyelsesgraden av lav. Det var ein stor variasjon mellom dei ulike lavartane for dei fleste næringsstoffa og fordøyelsesgraden. Stereocaulon spp. inneheldt meir protein, fosfor, svovel, kopar og molybden enn Cetraria spp. og Cladonia spp. Gulskinn hadde høgare fordøyelsesgrad, og innehaldet av NFE, oske, kalsium og magnesium var høgre enn i kvitkrull, medan trevleinnhaldet var størst i kvitkrull. Lav inneheldt

  9. The chemical composition and biological activities of essential oil ...

    African Journals Online (AJOL)

    PRECIOUS

    2009-12-15

    Dec 15, 2009 ... INTRODUCTION. Schinus terebinthifolius ... belongs to the Anacardiaceae family of plants (Manrique et al., 2008). ... among some of the ancient Chilean Amerindians. In ..... tation to a specific habitat, many plants produce chemical compounds ... London, U.K.: Crown Agents for Overseas Governments and.

  10. Chemical composition of essential oil of Psidium cattleianum var ...

    African Journals Online (AJOL)

    rajuc

    2012-04-24

    Apr 24, 2012 ... Research into plant essential oils have also gained momentum due to their fumigant .... 1 based on their chemical structures in which they are classified. The GC-MS ... It is also well known as a preservative in food, drugs and ...

  11. Chemical Composition, In Situ Degradability and In Vitro Gas ...

    African Journals Online (AJOL)

    forage harvested at different re-growth stages by measuring the chemical ... production was higher for leaves followed by branches with mean value of 43.7 ... degradability parameters help not only to be able to maximize the nutrient .... produced at time t, b the potential gas production and c the rate of gas ..... Wolf, B, 1982.

  12. Floral Scent in Wisteria: Chemical Composition, Emission Pattern and Regulation

    Science.gov (United States)

    Volatile chemicals emitted from the flowers of Chinese wisteria (Wisteria sinenesis) and Japanese wisteria (W. floribunda) were collected using a dynamic headspace technique and identified by a gas chromatography-mass spectrometry. About 30 and 22 compounds were detected from Chinese wisteria and Ja...

  13. Characterization of hydrolytic degradation of polylactic acid/rice hulls composites in water at different temperatures

    Directory of Open Access Journals (Sweden)

    2011-02-01

    Full Text Available Hydrolytic degradations of polylactic acid/rice hulls (PLA/RH composites with various rice hulls contents due to water absorptions at 23, 51 and 69°C were investigated by studying the thermal properties, chemical composition, molecular weight, and morphology of the degraded products. The results have attested that the stability of PLA/RH composites in water depends slightly on rice hulls contents but it is significantly influenced by water temperature. Water absorption in 30 days at 23°C was between 0.87 and 9.25% depending on rice hull contents. However, at thermophilic temperatures, the water absorption and degradation of these products were increased significantly. Saturations were achieved in less than 25 and 9 days at 51°C and 69°C, respectively, while hydrolytic degradation was demonstrated by an increase in fragility and development of crystallinity. At 69°C, there were significant reductions of the decomposition and glass transition temperatures of the polymer by 13°C. These changes were associated with the reduction of the molecular weight of PLA from 153.1 kDa to ~10.7 kDa due to hydrolysis of its ester group.

  14. THE CHANGE OF CHEMICAL QUALITY OF CARP POUNDS OUTGOING WATER IN RELATION TO INFLOW WATER

    Directory of Open Access Journals (Sweden)

    Krešimir Fašaić

    1996-03-01

    Full Text Available Carp pounds are considered one of the contaminators of open waters. Such situation was the motive for carrying out the research of changes in the outgoing water from a pond compared to the water flowing into ponds on the fish-farming »Jelas« near Slavonski Brod. The research was carried out in the period 1989-1995, in spring, summer and autumn on the fish production of 500-1000 kg/ha-1 and fish nutrition with cereals. Following chemical parameters were researched: 02, unbound C02, alkalinity (CaC03, CaHC03, pH, permanganat number (KMn04. BPK5, total dry waste, suspended substance, NH4+, N03- and PO43-. On the basis of received analytic values, it was concluded that the water may be categorized in I-II quality class according to the quantity if 02, consumption of KMn04, NH4+, N03-, PO43- and dry waste in the feeding and drainage canal and in the III-IV quality class according to the BPK5 and suspended substance. An occasional marked decrease of the quantity of 02, NH4+, N03- and PO43- and alkalinity of water was stated in the outgoding water compared to the inflow water. The BPK5 and suspended substance increased in the outgoing water compared to the inflow water. After the variant of the most important inflow and outgoing chemical parameters in the water was analyzed, it was stated that there emerged no significant changes (P>O.Ol, P>0.05. The changes of outgoing water from fish-farming “Jelas” were not significant in the research period and they had no significant influence on the change of the recipient water.

  15. The effect of Pleurotus spp. fungi on chemical composition and in vitro digestibility of rice straw.

    Science.gov (United States)

    Jafari, M A; Nikkhah, A; Sadeghi, A A; Chamani, M

    2007-08-01

    This study was carried out to test the potentially of using rice straw substrate for the cultivation of four Pleurotus species including Pleurotus florida, Pleurotus djamor, Pleurotus sajor-caju and Pleurotus ostreatus and the effect of these species on the chemical composition, cell wall degradation and digestibility of rice straw. Rice straw soaked in water for 24 h and then it was pasteurized at 100 degrees C for 6 h. Rice straw was inoculated with spawns of four Pleurotus fungi (Pleurotus florida, Pleurotus djamor, Pleurotus sajor-caju and Pleurotus ostreatus) and packed in the plastic bags and incubated in a fermentation chamber at 23-27 degrees C and 75-85% relative humidity. After 60th day, rice straw samples from all groups were taken and analyzed for chemical composition and in vitro digestibility. The data obtained were analyzed according to the complete randomized design model consisting of four treatments plus one control and four replicates. The results of this study showed that fungal treatment increased (pstraw but the hemicellulose, Organic Matter (OM), Acid Detergent Fiber (ADF), Neutral Detergent Fiber (NDF) and Acid Detergent Lignin (ADL) contents decreased. However, the ability of the fungi to degrade these components varied among the species. The ability of Pleurotus sajor-caju and Pleurotus ostreatus were higher than the other species in decreasing the hemicellulose, NDF, ADF and ADL contents. The highest Biological Efficiency (BE) was produced by sajor-caju species with 56.02 and the lowest was belong to Pleurotus djamor species with an average 51.17%. All species of fungi incubated on rice straw showed increased (pstraw treated with sajor-caju fungus had the highest in vitro dry matter digestibility (IVDMD) and in vitro organic matter digestibility (IVOMD) with 80.10 and 82.18%, respectively. In general this experiment cleared that treatment with sajor-caju can improve the quality of rice straw to be useful feed for ruminant nutrition.

  16. Effect of soil medium amendment on chemical composition and digestibility of Lolium multiflorum Lam.

    Directory of Open Access Journals (Sweden)

    Jacek Sosnowski

    2013-03-01

    Full Text Available The aim of this study was to determine the effect of used soil medium amendment on the background of mineral fertilizers and on the chemical composition, and digestibility of dry matter of Lolium multiflorum Lam. (‘Gaza’ variety. Experiment with the cultivation of this species was carried out in the rings of polyurethane, in four replications. For each of the pots, eight ryegrass seeds were sown. After seeds germination when seedlings reached the two-three leaf stage, negative selection was made by removing the four weakest plants and then experimental factors were introduced in the form of the following combinations: NPK – mineral fertilization in annual doses of 0.6 g N, 0.25 g P2O5 and 0.9 g of K2O per ring, B-NPK – without fertilization, UG – soil medium amendment in the form of 0.25% solution and a dose of 3.7 cm3 per ring, B-UG – without soil medium amendment. Nitrogen fertilization (34% ammonium nitrate and potassium (60% potassium salt were used in three doses, and phosphorus (46% TSP in a single dose in spring. The soil medium amendment solution was used for watering plants in a phase of shooting. The full period of this experiment was in 2009-2010. During this time, the analysis of chemical composition of dry matter yield was performed for all cuts at the Institute of Technology and Life Sciences in Falenty. The using of soil fertilizer in cultivation of ryegrass led to increase the crude ash content, expand the sugar-protein ratio and slight improvement of dry matter digestibility of the tested plant material.

  17. High-resolution chemical composition of geothermal scalings from Hungary: Preliminary results

    Science.gov (United States)

    Boch, Ronny; Dietzel, Martin; Deák, József; Leis, Albrecht; Mindszenty, Andrea; Demeny, Attila

    2015-04-01

    Geothermal fluids originating from several hundreds to thousands meters depth mostly hold a high potential for secondary mineral precipitation (scaling) due to high total dissolved solid contents at elevated temperature and pressure conditions. The precipitation of e.g. carbonates, sulfates, sulfides, and silica has shown to cause severe problems in geothermal heat and electric power production, when clogging of drill-holes, downhole pumps, pipes and heat exchangers occurs (e.g. deep geothermal doublet systems). Ongoing scaling reduces the efficiency in energy extraction and might even question the abandonment of installations in worst cases. In an attempt to study scaling processes both temporally and spatially we collected mineral precipitates from selected sites in Hungary (Bükfürdo, Szechenyi, Szentes, Igal, Hajduszoboszlo). The samples of up to 8 cm thickness were recovered from different positions of the geothermal systems and precipitated from waters of various temperatures (40-120 °C) and variable overall chemical composition. Most of these scalings show fine lamination patterns representing mineral deposition from weeks up to 45 years at our study sites. Solid-fluid interaction over time captured in the samples are investigated applying high-resolution analytical techniques such as laser-ablation mass-spectrometry and electron microprobe, micromill-sampling for stable isotope analysis, and micro-XRD combined with hydrogeochemical modeling. A detailed investigation of the processes determining the formation and growth of precipitates can help to elucidate the short-term versus long-term geothermal performance with regard to anthropogenic and natural reservoir and production dynamics. Changes in fluid chemistry, temperature, pressure, pH, degassing rate (CO2) and flow rate are reflected by the mineralogical, chemical and isotopic composition of the precipitates. Consequently, this high-resolution approach is intended as a contribution to decipher the

  18. Influence of Breed, Parity and Food Intake on Chemical Composition of First Colostrum in Cow

    Directory of Open Access Journals (Sweden)

    Simona Zarcula

    2010-05-01

    Full Text Available The aim of this research was to establish the influence of breed, parity and food intake on chemical composition of first colostrum. We observed that fat, proteins, lactose and dry matter were higher in cows from second and third lactation compared to those in fourth lactation. Cow's breed also influenced the colostrum composition, superior quality being obtained in case of Romanian White and Black comparing Holstein Friesian cows. The unbalanced energo-proteic ratio had a negative impact on chemical composition of first colostrum.

  19. Relationship between bacterial density and chemical composition of ...

    African Journals Online (AJOL)

    TUOYO

    ml as the sewage moved through the oxidation pond into the receiving stream. A similar decrease ... On the other hand, both the silica and dissolved oxygen content of the sewage gradually ... inorganic materials such as carbon dioxide, water,.

  20. Passive sampling of perfluorinated chemicals in water: flow rate effects on chemical uptake.

    Science.gov (United States)

    Kaserzon, Sarit L; Vermeirssen, Etiënne L M; Hawker, Darryl W; Kennedy, Karen; Bentley, Christie; Thompson, Jack; Booij, Kees; Mueller, Jochen F

    2013-06-01

    A recently developed modified polar organic chemical integrative sampler (POCIS) provides a means for monitoring perfluorinated chemicals (PFCs) in water. However, changes in external flow rates may alter POCIS sampling behaviour and consequently affect estimated water concentrations of analytes. In this work, uptake kinetics of selected PFCs, over 15 days, were investigated. A flow-through channel system was employed with spiked river water at flow rates between 0.02 and 0.34 m s(-1). PFC sampling rates (Rs) (0.09-0.29 L d(-1) depending on analyte and flow rate) increased from the lowest to highest flow rate employed for some PFCs (MW ≤ 464) but not for others (MW ≥ 500). Rs's for some of these smaller PFCs were increasingly less sensitive to flow rate as this increased within the range investigated. This device shows promise as a sampling tool to support monitoring efforts for PFCs in a range of flow rate conditions. Copyright © 2013 Elsevier Ltd. All rights reserved.

  1. On the chemical state of Co oxide electrocatalysts during alkaline water splitting.

    Science.gov (United States)

    Friebel, Daniel; Bajdich, Michal; Yeo, Boon Siang; Louie, Mary W; Miller, Daniel J; Sanchez Casalongue, Hernan; Mbuga, Felix; Weng, Tsu-Chien; Nordlund, Dennis; Sokaras, Dimosthenis; Alonso-Mori, Roberto; Bell, Alexis T; Nilsson, Anders

    2013-10-28

    Resonant inelastic X-ray scattering and high-resolution X-ray absorption spectroscopy were used to identify the chemical state of a Co electrocatalyst in situ during the oxygen evolution reaction. After anodic electrodeposition onto Au(111) from a Co(2+)-containing electrolyte, the chemical environment of Co can be identified to be almost identical to CoOOH. With increasing potentials, a subtle increase of the Co oxidation state is observed, indicating a non-stoichiometric composition of the working OER catalyst containing a small fraction of Co(4+) sites. In order to confirm this interpretation, we used density functional theory with a Hubbard-U correction approach to compute X-ray absorption spectra of model compounds, which agree well with the experimental spectra. In situ monitoring of catalyst local structure and bonding is essential in the development of structure-activity relationships that can guide the discovery of efficient and earth abundant water splitting catalysts.

  2. Grain characteristics, chemical composition, and functional properties of rye (Secale cereale L.) as influenced by genotype and harvest year.

    Science.gov (United States)

    Hansen, Hanne B; Møller, Birthe; Andersen, Sven B; Jørgensen, Johannes R; Hansen, Ase

    2004-04-21

    Grain characteristic, chemical composition, and functional properties of rye were measured in 19 different cultivars grown in one location in up to 3 years. The cultivars included 8 adapted hybrids, 7 adapted population cultivars, and 4 nonadapted population cultivars. The results showed a significant influence of both harvest year and genotype on grain characteristics, chemical composition, and functional properties of the grain. Multivariate data analysis confirmed that the variations in the data were explained by yearly and genotype differences. Calculations of variance components showed that the variations in plant height, harvest yield, and protein content were mainly due to genotype differences and to a lesser extent to differences among harvest years. The kernel weight, hardness index, and content of dietary fiber components, however, were more strongly influenced by the harvest year than by the genotype. Differences in starch properties measured by falling number (FN), amylograph peak viscosity, and temperature at peak viscosity were more strongly influenced by harvest year. The water absorption was strongly influenced by genotype effects, compared to yearly differences. FN and amylograph peak temperature were positively correlated (r = 0.94). No correlation was found between the water absorption and the relative proportion of water-extractable arabinoxylan (AX) compared to the total AX content. However, the degree of ferulic acid cross-linking showed a negative correlation (r = -0.70) with the water absorption.

  3. Water-soluble polyaniline/graphene composites as materials for energy storage applications

    Directory of Open Access Journals (Sweden)

    A. M. Solonaru

    2017-02-01

    Full Text Available Three water-dispersable composites have been synthesized by in situ chemical oxidative polymerization of aniline N-propanesulfonic acid (AnS in reduced graphene oxide (r-GO dispersion, in an ice bath at 0 °C and in the absence of any surfactant. The mass ratio between r-GO and aniline monomer have been established as (mr-GO:mAnS = 1:1, 1:2 and 1:5 while in the composites, the mass ratio between r-GO and polyaniline was found: 1:0.3, 1:0.5 and 1:1, respectively. The molecular structure, morphology, and optical properties of the composites were analyzed through Fourier transform infrared (FTIR, Raman and ultraviolet-visible (UV-Vis spectroscopy, X-ray diffraction (XRD, and scanning electron microscopy (SEM. Electrochemical performances for energy storage were evaluated by cyclic voltammetry and galvanostatic charge/discharge measurements with 1M H2SO4 as electrolyte in a three-electrode cell. The composite with the mass ratio (mr-GO:mPAnS = 1:1 has showed good capacitive behavior with a specific capacitance of 1019 F/g at scan rate of 1 mV/s calculated from integrated area of cyclic voltammogram curve and a retention life of 80% after 100 cycles. These results indicate that the composites prepared by chemical oxidative polymerization are promising materials for electrode supercapacitors.

  4. Relationship between chemical composition and in situ rumen degradation characteristics of maize silages in dairy cows.

    Science.gov (United States)

    Ali, M; van Duinkerken, G; Cone, J W; Klop, A; Blok, M C; Spek, J W; Bruinenberg, M H; Hendriks, W H

    2014-11-01

    Several in situ studies have been conducted on maize silages to determine the effect of individual factors such as maturity stage, chop length and ensiling of maize crop on the rumen degradation but the information on the relationship between chemical composition and in situ rumen degradation characteristics remains scarce. The objectives of this study were to determine and describe relationships between the chemical composition and the rumen degradation characteristics of dry matter (DM), organic matter (OM), CP, starch and aNDFom (NDF assayed with a heat stable amylase and expressed exclusive of residual ash) of maize silages. In all, 75 maize silage samples were selected, with a broad range in chemical composition and quality parameters. The samples were incubated in the rumen for 2, 4, 8, 16, 32, 72 and 336 h, using the nylon bag technique. Large range was found in the rumen degradable fractions of DM, OM, CP, starch and aNDFom because of the broad range in chemical composition and quality parameters. The new database with in situ rumen degradation characteristics of DM, OM, CP, starch and aNDFom of the maize silages was obtained under uniform experimental conditions; same cows, same incubation protocol and same chemical analysis procedures. Regression equations were developed with significant predictors (P<0.05) describing moderate and weak relationships between the chemical composition and the washout fraction, rumen undegradable fraction, potentially rumen degradable fraction, fractional degradation rate and effective rumen degradable fraction of DM, OM, CP, starch and aNDFom.

  5. Li isotopes reflect chemical weathering intensity in streams and ground waters draining basalts

    Science.gov (United States)

    Liu, X.; Rudnick, R. L.; McDonough, W. F.

    2013-12-01

    Chemical weathering has an important influence on continental crust evolution, as weathering of basalt preferentially removes soluble elements, such as Mg, and can shift the crust composition towards more andesitic compositions, thus helping to solve the crustal composition paradox [1]. The isotopic compositions of soluble elements (e.g., Li and Mg) provide a monitor of chemical weathering of the continents. Along with large isotopic fractionations [2], these elements are preferentially transferred to rivers during weathering, and are useful tracers of weathering processes. The chemical and isotopic compositions of streams and ground waters that reside entirely within the Columbia River Basalts (CRBs) reflect the processes associated with basalt weathering. In addition, stream samples from both west and east of the Cascades were collected during summer and late winter to evaluate seasonal changes in Li isotopic compositions. The Li concentrations ([Li]) vary from 0.2 to 4.7 μg/l in dissolved loads of streams for both sampling seasons; in ground waters, [Li] varies from 2 to 21 μg/l. δ7Li varies by up to 20‰ in streams and ground waters, demonstrating that lithology is not the only influence on water chemistry in the catchments. Calculated mineral saturation suggests that most streams and some ground waters were saturated with respect to most secondary minerals, implying that Li isotopic fractionation was influenced by the development of secondary minerals, such as kaolinite and hematite. The δ7Li and Li/Na in dissolved loads of streams are not sensitive to distance from the coast or climate, but likely reflect the local weathering intensity. The correlated variation in δ7Li and Li/Na ratios seem to have global significance, at least in streams that only drain basalts [3, 4, 5], suggesting that the streams within the CRBs cover a wide range of weathering intensity, with low δ7Li and high Li/Na corresponding to higher weathering intensity. In addition

  6. Direct Monte Carlo simulation of the chemical equilibrium composition of detonation products

    Energy Technology Data Exchange (ETDEWEB)

    Shaw, M.S.

    1993-06-01

    A new Monte Carlo simulation method has been developed by the author which gives the equilibrium chemical composition of a molecular fluid directly. The usual NPT ensemble (isothermal-isobaric) is implemented with N being the number of atoms instead of molecules. Changes in chemical composition are treated as correlated spatial moves of atoms. Given the interaction potentials between molecular products, ``exact`` EOS points including the equilibrium chemical composition can be determined from the simulations. This method is applied to detonation products at conditions in the region near the Chapman- Jouget state. For the example of NO, it is shown that the CJ detonation velocity can be determined to a few meters per second. A rather small change in cross potentials is shown to shift the chemical equilibrium and the CJ conditions significantly.

  7. Rapid Characterization of Woody Biomass Digestibility and Chemical Composition Using Near-infrared Spectroscopy

    Institute of Scientific and Technical Information of China (English)

    Shen Hou; Laigeng Li

    2011-01-01

    Rapid determination of the properties of lignocellulosic material is highly desirable for biomass production and utilization. In the present study, measurements of woody biomass digestibility and chemical composition using near-infrared reflectance (NIR) spectroscopy were calibrated. Poplar and eucalyptus materials were recorded in NIR spectrum as well as determined for their chemical compositions of Klason lignin, α-celluiose, holocellulose, lignin syringyl/guaiacyl (S/G) ratio and enzymatic digestibility. Fitting of the NIR information with chemical properties and digestibility by partial least-squares (PLS) regression generated a group of trained NIR models that were able to be used for rapid biomass measurement. Applying the models for woody biomass measurements led to a reliable evaluation of the chemical composition and digestibility, suggesting the feasibility of using NIR spectroscopy in the rapid characterization of biomass properties.

  8. Dual X-ray absorptiometry accurately predicts carcass composition from live sheep and chemical composition of live and dead sheep.

    Science.gov (United States)

    Pearce, K L; Ferguson, M; Gardner, G; Smith, N; Greef, J; Pethick, D W

    2009-01-01

    Fifty merino wethers (liveweight range from 44 to 81kg, average of 58.6kg) were lot fed for 42d and scanned through a dual X-ray absorptiometry (DXA) as both a live animal and whole carcass (carcass weight range from 15 to 32kg, average of 22.9kg) producing measures of total tissue, lean, fat and bone content. The carcasses were subsequently boned out into saleable cuts and the weights and yield of boned out muscle, fat and bone recorded. The relationship between chemical lean (protein+water) was highly correlated with DXA carcass lean (r(2)=0.90, RSD=0.674kg) and moderately with DXA live lean (r(2)=0.72, RSD=1.05kg). The relationship between the chemical fat was moderately correlated with DXA carcass fat (r(2)=0.86, RSD=0.42kg) and DXA live fat (r(2)=0.70, RSD=0.71kg). DXA carcass and live animal bone was not well correlated with chemical ash (both r(2)=0.38, RSD=0.3). DXA carcass lean was moderately well predicted from DXA live lean with the inclusion of bodyweight in the regression (r(2)=0.82, RSD=0.87kg). DXA carcass fat was well predicted from DXA live fat (r(2)=0.86, RSD=0.54kg). DXA carcass lean and DXA carcass fat with the inclusion of carcass weight in the regression significantly predicted boned out muscle (r(2)=0.97, RSD=0.32kg) and fat weight, respectively (r(2)=0.92, RSD=0.34kg). The use of DXA live lean and DXA live fat with the inclusion of bodyweight to predict boned out muscle (r(2)=0.83, RSD=0.75kg) and fat (r(2)=0.86, RSD=0.46kg) weight, respectively, was moderate. The use of DXA carcass and live lean and fat to predict boned out muscle and fat yield was not correlated as weight. The future for the DXA will exist in the determination of body composition in live animals and carcasses in research experiments but there is potential for the DXA to be used as an online carcass grading system.

  9. Chemical composition and droplet size distribution of cloud at the summit of Mount Tai, China

    Directory of Open Access Journals (Sweden)

    J. Li

    2017-08-01

    Full Text Available The chemical composition of 39 cloud samples and droplet size distributions in 24 cloud events were investigated at the summit of Mt. Tai from July to October 2014. Inorganic ions, organic acids, metals, HCHO, H2O2, sulfur(IV, organic carbon, and elemental carbon as well as pH and electrical conductivity were analyzed. The acidity of the cloud water significantly decreased from a reported value of pH 3.86 during 2007–2008 (Guo et al., 2012 to pH 5.87 in the present study. The concentrations of nitrate and ammonium were both increased since 2007–2008, but the overcompensation of ammonium led to an increase in the mean pH value. The microphysical properties showed that cloud droplets were smaller than 26.0 µm and most were in the range of 6.0–9.0 µm at Mt. Tai. The maximum droplet number concentration (Nd was associated with a droplet size of 7.0 µm. High liquid water content (LWC values could facilitate the formation of larger cloud droplets and broadened the droplet size distribution. Cloud droplets exhibited a strong interaction with atmospheric aerosols. Higher PM2. 5 levels resulted in higher concentrations of water-soluble ions and smaller sizes with increased numbers of cloud droplets. The lower pH values were likely to occur at higher PM2. 5 concentrations. Clouds were an important sink for soluble materials in the atmosphere. The dilution effect of cloud water should be considered when estimating concentrations of soluble components in the cloud phase.

  10. Cyanobacterial flora and the physico-chemical environment of six tropical fresh water lakes of Udaipur, India.

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    The cyanobacteria and physico-chemical environments of six tropical fresh water lakes of Udaipur, India were investigated. These lakes receive varying nutrient inputs from different sources. Altogether 51 species of cyanobacteria were recorded. Species composition varied between lakes and between seasons. Lake VI (Baghdara), which receives nutrients from natural sources only, differed considerably from the others in water chemistry and composition of dominant species. Lake II (Swaroop Sagar), eutrophied due to sewage inputs, was species poor. Non-diazotrophs, represented by 27 species, dominated during summer. With few exceptions, N2-fixing species, both heterocystous and unicellular diazotrophs (represented by 24 species), were dominant during winter. Microcystis aeruginosa, Phormidium sp. and Anabaena flos-aque were the dominant taxa of lakes characterized by sewage eutrophication. The study shows that both, species diversity and community composition were affected by water chemistry.

  11. The chemical composition of fine ambient aerosol particles in the Beijing area

    Science.gov (United States)

    Nekat, Bettina; van Pinxteren, Dominik; Iinuma, Yoshiteru; Gnauk, Thomas; Müller, Konrad; Herrmann, Hartmut

    2010-05-01

    The strong economical growth in China during the last few decades led to heavy air pollution caused by significantly increased particle emissions. The aerosol particles affect not only the regional air quality and visibility, but can also influence cloud formation processes and the radiative balance of the atmosphere by their optical and microphysical properties. The ability to act as Cloud Condensation Nuclei (CCN) is related to microphysical properties like the hygroscopic growth or the cloud droplet activation. The chemical composition of CCN plays an important role on these properties and varies strongly with the particle size and the time of day. Hygroscopic or surface active substances can increase the hygroscopicity and lower the surface tension of the particle liquid phase, respectively. The presence of such compounds may result in faster cloud droplet activation by faster water uptake. The DFG project HaChi (Haze in China) aimed at studying physical and chemical parameters of urban aerosol particles in the Beijing area in order to associate the chemical composition of aerosol particles with their ability to act as CCN. To this end, two measurement campaigns were performed at the Wuqing National Ordinary Meteorological Observing Station, which is a background site near Beijing. The winter campaign was realized in March 2009 and the summer campaign took place from mid July 2009 to mid August 2009. Fine particles with an aerodynamic diameter smaller than or equal 1 μm were continuously sampled for 24h over the two campaigns using a DIGITEL high volume sampler (DHA-80). The present contribution presents and discusses the results of the chemical characterization of the DIGITEL filters samples. The filters were analyzed for the mass concentration, inorganic ions and carbon sum parameters like elemental (EC), organic (OC) and water soluble organic carbon (WSOC). The WSOC fraction was further characterized for hygroscopic substances like low molecular

  12. Chemical modeling of water deuteration in IRAS16293-2422

    CERN Document Server

    Wakelam, V; Aikawa, Y; Coutens, A; Bottinelli, S; Caux, E

    2014-01-01

    IRAS 16293-2422 is a well studied low-mass protostar characterized by a strong level of deuterium fractionation. In the line of sight of the protostellar envelope, an additional absorption layer, rich in singly and doubly deuterated water has been discovered by a detailed multiline analysis of HDO. To model the chemistry in this source, the gas-grain chemical code Nautilus has been used with an extended deuterium network. For the protostellar envelope, we solve the chemical reaction network in infalling fluid parcels in a protostellar core model. For the foreground cloud, we explored several physical conditions (density, cosmic ionization rate, C/O ratio). The main results of the paper are that gas-phase abundances of H2O, HDO and D2O observed in the inner regions of IRAS16293-2422 are lower than those predicted by a 1D dynamical/chemical (hot corino) model in which the ices are fully evaporated. The abundance in the outer part of the envelope present chaotic profiles due to adsorption/evaporation competition...

  13. Chemical stability of seven years aged cement-PET composite waste form containing radioactive borate waste simulates

    Energy Technology Data Exchange (ETDEWEB)

    Saleh, H.M., E-mail: hosamsaleh70@yahoo.com [Radioisotope Department, Atomic Energy Authority, Dokki (Egypt); Tawfik, M.E. [Department of Polymers and Pigments, National Research Center, Dokki (Egypt); Bayoumi, T.A. [Radioisotope Department, Atomic Energy Authority, Dokki (Egypt)

    2011-04-15

    Different samples of radioactive borate waste simulate [originating from pressurized water reactors (PWR)] have been prepared and solidified after mixing with cement-water extended polyester composite (CPC). The polymer-cement composite samples were prepared from recycled poly (ethylene terephthalate) (PET) waste and cement paste (water/cement ratio of 40%). The prepared samples were left to set at room temperature (25 deg. C {+-} 5) under humid conditions. After 28 days curing time the obtained specimens were kept in their molds to age for 7 years under ambient conditions. Cement-polymer composite waste form specimens (CPCW) have been subjected to leach tests for both {sup 137}Cs and {sup 60}Co radionuclides according to the method proposed by the International Atomic Energy Agency (IAEA). Leaching tests were justified under various factors that may exist within the disposal site (e.g. type of leachant, surrounding temperature, leachant behavior, the leachant volume to CPCW surface area...). The obtained data after 260 days of leaching revealed that after 7 years of aging the candidate cement-polymer composite (CPC) containing radioactive borate waste samples are characterized by adequate chemical stability required for the long-term disposal process.

  14. Chemical stability of seven years aged cement-PET composite waste form containing radioactive borate waste simulates

    Science.gov (United States)

    Saleh, H. M.; Tawfik, M. E.; Bayoumi, T. A.

    2011-04-01

    Different samples of radioactive borate waste simulate [originating from pressurized water reactors (PWR)] have been prepared and solidified after mixing with cement-water extended polyester composite (CPC). The polymer-cement composite samples were prepared from recycled poly (ethylene terephthalate) (PET) waste and cement paste (water/cement ratio of 40%). The prepared samples were left to set at room temperature (25 °C ± 5) under humid conditions. After 28 days curing time the obtained specimens were kept in their molds to age for 7 years under ambient conditions. Cement-polymer composite waste form specimens (CPCW) have been subjected to leach tests for both 137Cs and 60Co radionuclides according to the method proposed by the International Atomic Energy Agency (IAEA). Leaching tests were justified under various factors that may exist within the disposal site (e.g. type of leachant, surrounding temperature, leachant behavior, the leachant volume to CPCW surface area…). The obtained data after 260 days of leaching revealed that after 7 years of aging the candidate cement-polymer composite (CPC) containing radioactive borate waste samples are characterized by adequate chemical stability required for the long-term disposal process.

  15. Mechanical behavior of chemically treated Jute/Polymer composites

    Directory of Open Access Journals (Sweden)

    Murali B

    2014-03-01

    Full Text Available Fiber which serves as a reinforcement in reinforced plastics may be synthetic or natural past studies show that only artificial fibers such as glass, carbon etc., have been used in fiber reinforced plastics. Although glass and other synthetic fiber reinforced plastics possess high specific strength, their fields of application are very limited because of their inherent higher cost of production. In this connection, an investigation has been carried out to make use of jute , a natural fiber abundantly available in India. Natural fibers are not only strong and lightweight but also relatively very cheap. In the present work, jute composites are developed and their mechanical properties are evaluated. Mechanical properties of jute/polymer and compared with glass fiber/epoxy. These results indicate that jute can be used as a potential reinforcing material for making low load bearing thermoplastic composites.

  16. Chemical Composition of PM2.5 at an Urban Site of Chengdu in Southwestern China

    Institute of Scientific and Technical Information of China (English)

    TAO Jun; CHENG Tiantao; ZHANG Renjian; CAO Junji; ZHU Lihua; WANG Qiyuan; LUO Lei

    2013-01-01

    PM2.5 aerosols were sampled in urban Chengdu from April 2009 to January 2010,and their chemical compositions were characterized in detail for elements,water soluble inorganic ions,and carbonaceous matter.The annual average of PM2.5 was 165 μg m-3,which is generally higher than measurements in other Chinese cities,suggesting serious particulate pollution issues in the city.Water soluble ions contributed 43.5% to the annual total PM2.5 mass,carbonaceous aerosols including elemental carbon and organic carbon contributed 32.0%,and trace elements contributed 13.8%.Distinct daily and seasonal variations were observed in the mass concentrations of PM2.5 and its components,reflecting the seasonal variations of different anthropogenic and natural sources.Weakly acidic to neutral particles were found for PM2.5.Major sources of PM2.5 identified from source apportionment analysis included coal combustion,traffic exhaust,biomass burning,soil dust,and construction dust emissions.The low nitrate:sulfate ratio suggested that stationary emissions were more important than vehicle emissions.The reconstructed masses of ammonium sulfate,ammonium nitrate,particulate carbonaceous matter,and fine soil accounted for 79% of the total measured PM2.5 mass; they also accounted for 92% of the total measured particle scattering.

  17. Fabrication of fiber-reinforced composites by chemical vapor infiltration

    Energy Technology Data Exchange (ETDEWEB)

    Besmann, T.M.; Stinton, D.P. [Oak Ridge National Lab., TN (United States); Matlin, W.M.; Liaw, P.K. [Univ. of Tennessee, Knoxville, TN (United States)

    1996-08-01

    Processing equipment for the infiltration of fiber-reinforced composite tubes is being designed that incorporates improvements over the equipment used to infiltrate disks. A computer-controlled machine-man interface is being developed to allow for total control of all processing variables. Additionally, several improvements are being made to the furnace that will reduce the complexity and cost of the process. These improvements include the incorporation of free standing preforms, cast mandrels, and simpler graphite heating elements.

  18. Fabrication of fiber-reinforced composites by chemical vapor infiltration

    Energy Technology Data Exchange (ETDEWEB)

    Besmann, T.M.; Matlin, W.M.; Stinton, D.P.; Liaw, P.K.

    1996-06-01

    Processing equipment for the infiltration of fiber-reinforced composite tubes is being designed that incorporates improvements over the equipment used to infiltrate disks. A computer-controlled machine-man interface is being developed to allow for total control of all processing variables. Additionally, several improvements are being made to the furnace that will reduce the complexity and cost of the process. These improvements include the incorporation of free standing preforms, cast mandrels, and simpler graphite heating elements.

  19. Chemical Composition of Ground Pearl (Eurhizococcus colombianus Cysts

    Directory of Open Access Journals (Sweden)

    Fernando Echeverri

    2008-01-01

    Full Text Available Ground pearl (Eurhizococcus colombianus is a crop pest in Colombia, withspecial impact on fig, grass, rubus and tomato plants. The insect is resistant to externalinsecticide application because it produces a thick waxy shell that isolates it from theenvironment. The composition of this shell was determined by NMR and MS as atriglyceride, whose fatty acid is transformed into other products with the metamorphosis ofthe insect. Additionally, several enzymatic inhibitors were assayed to control the insectwith negative results.

  20. Chemical characterization of high molecular weight dissolved organic matter in fresh and marine waters

    Science.gov (United States)

    Repeta, Daniel J.; Quan, Tracy M.; Aluwihare, Lihini I.; Accardi, AmyMarie

    2002-03-01

    The high molecular weight fraction of dissolved organic matter in a suite of lakes, rivers, seawater, and marine sediment interstitial water samples was collected by ultrafiltration and characterized by molecular level and spectroscopic techniques. Proton nuclear magnetic resonance spectra of all samples show a high degree of similarity, with major contributions from carbohydrates, bound acetate, and lipids. Molecular level analyses of neutral sugars show seven monosaccharides, rhamnose, fucose, arabinose, xylose, mannose, glucose, and galactose, to be abundant, and to occur in comparable relative amounts in each sample. Previous studies have emphasized the distinctive composition of dissolved humic substances in fresh and marine waters, and have attributed these differences to sources and transformations of organic matter unique to each environment. In contrast we find a large fraction of freshwater high molecular weight dissolved organic matter (HMWDOM; > 1kD) to be indistinguishable from marine HMWDOM in bulk and molecular-level chemical properties. Aquatic HMWDOM is similar in chemical composition to biologically derived acylated heteropolysaccharides isolated from marine algal cultures, suggesting a biological source for some fraction of persistent HMWDOM. High molecular weight DOC contributes 51 ± 26% of the total DOC, and monosaccharides 18 ± 8% of the total HMWDOC in our freshwater samples. These contributions are on average higher and more variable, but not significantly different than for surface seawater (30% and 16% respectively). Biogeochemical processes that produce, accumulate, and recycle DOM may therefore share important similarities and be broadly comparable across a range of environmental settings.

  1. Chemical composition of suspended sediments in World Rivers: New insights from a new database.

    Science.gov (United States)

    Viers, Jérôme; Dupré, Bernard; Gaillardet, Jérôme

    2009-01-01

    The aim of this paper is to present a new database on the chemical composition of suspended matter in World Rivers, together with the associated elemental fluxes. There is a lack of any recent attempt in the literature to update the pioneering work of Martin and Meybeck [Martin, J.-M., Meybeck, M., 1979. Elemental mass balance of material carried by major world rivers. Mar. Chem. 7, 173-206.] and Martin and Whitfield [Martin, J.-M., Whitfield, M., 1983. The significance of the river input of chemical elements to the ocean. Trace metals in sea water Wong, Boyle, Bruland, Burton, Goldberg (Eds) Plenum Publishing Corporation.] regarding the worldwide average major and trace element chemistry of riverine particulate matter. Apart from compiling a new database on particulate matter, this paper also aims to give a "snap-shot" of elemental fluxes for each continent. This approach should allow us to obtain new insights on weathering conditions in different environments and assess the influence of human activities on natural geochemical cycles. Finally, this study demonstrates the large uncertainties currently associated with estimating the flux of sediments transported by rivers. By comparing the riverine suspended sediment fluxes of some metals (Cd, Zn, Ni, Cu, Cr and Pb) given in this study with estimates of the anthropogenic fluxes of these metals to the atmosphere, soils and waters (natural ecosystems) [Nriagu, J.O., 1988. A silent epidemic of environmental poisoning. Environ. Pollut. 50, 139-161.], we can see that riverine fluxes are similar to anthropogenic fluxes. This casts light on the effect of human activities on the cycles of trace elements at the Earth's surface.

  2. Measurement of chemical composition and optical properties of PM2.5 at Rudong, China

    Science.gov (United States)

    Taketani, F.; Kanaya, Y.; Pan, X.; Irie, H.; Takashima, H.; Tanimoto, H.; Saito, S.; Akimoto, H.; Wang, Z.

    2013-12-01

    Intensive field campaign in Rudong(32.26 deg N, 121.37 deg E), located 100 km north of the city center of Shanghai, China, in May and June 2010 was carried out. To investigate chemical and optical property of aerosol particles, in this study, 9 or 14-hours PM2.5 samples were collected on the quartz filters using High-volume(500L/min) samplers. Using these filters, EC (elemental carbon) and OC(organic carbon), water-soluble ions(SO42-, NO3-, NH4+, Cl-, Ca2+, Mg2+, K+, and Na+) and metals(Al, Fe, Cu, Mn, Zn, Pb) were measured by Sunset lab EC/OC instrument, ion-chromatography, and ICP-AES, respectively. Furthermore, to monitor PM2.5 total mass, we employed SHARP monitor. During the campaign, total mass concentration monitored by SHARP instrument ranged from 3.2 to 172.1 ug/m3 with a mean of 55.3 ug/m3, and major components were sulfate, nitrate, and organics. The total mass concentration of PM2.5 monitored by the SHARP instrument was overestimated with sum of observed mass concentrations of each species. By taking into account the water amount in the particles measured by the SHARP instrument using thermodynamics model with the compositions on the filter and measured RH, we found mass closure should be achieved. We also performed particle source apportionment analysis using Positive Matrix Factorization (PMF) to investigate the source categories. Furthermore, scattering coefficient was reconstructed in an empirical manner by summing the contributions from various chemical species, which were calculated by multiplying observed mass concentrations of each species with empirical mass scattering coefficient. The reconstructed scattering coefficient had good correlation with directly measured coefficients by nephelometer at RH ambient scattering coefficient.

  3. Production of hydrogen using composite membrane in PEM water electrolysis

    Energy Technology Data Exchange (ETDEWEB)

    Santhi priya, E.L.; Mahender, C.; Mahesh, Naga; Himabindu, V. [Centre for Environment, Institute of Science and Technology, Jawaharlal Nehru Technological University Hyderabad, Kukatpally, Hyderabad-500 085, A.P (India); Anjaneyulu, Y. [Director, TLGVRC, JSU Box 18739, JSU, Jackson, MS 32917-0939 (United States)

    2012-07-01

    Electrolysis of water is the best known technology till today to produce hydrogen. The only practical way to produce hydrogen using renewable energy sources is by proton exchange membrane (PEM) water electrolysis. The most commonly used PEM membrane is Nafion. Composite membrane of TiO2 is synthesized by casting method using Nafion 5wt% solution. RuO2 is used as anode and 10 wt% Pd on activated carbon is used as cathode in the water electrolyser system. The performance of this Composite membrane is studied by varying voltage range 1.8 to 2.6V with respect to hydrogen yield and at current density 0.1, 0.2, 0.3, 0.4, and 0.5(A cm-2). This Composite membrane has been tested using in-house fabricated single cell PEM water electrolysis cell with 10cm2 active area at temperatures ranging from 30,45,65 850c and at 1 atmosphere pressure.

  4. Production of hydrogen using composite membrane in PEM water electrolysis

    Directory of Open Access Journals (Sweden)

    E.L.Santhi priya, C.Mahender, Naga Mahesh, V.Himabindu, Y.Anjaneyulu

    2012-01-01

    Full Text Available Electrolysis of water is the best known technology till today to produce hydrogen. The only practical way to produce hydrogen using renewable energy sources is by proton exchange membrane (PEM water electrolysis. The most commonly used PEM membrane is Nafion. Composite membrane of TiO2 is synthesized by casting method using Nafion 5wt% solution. RuO2 is used as anode and 10 wt% Pd on activated carbon is used as cathode in the water electrolyser system. The performance of this Composite membrane is studied by varying voltage range 1.8 to 2.6V with respect to hydrogen yield and at current density 0.1, 0.2, 0.3, 0.4, and 0.5(A cm-2. This Composite membrane has been tested using in-house fabricated single cell PEM water electrolysis cell with 10cm2 active area at temperatures ranging from 30,45,65 850c and at 1 atmosphere pressure.

  5. Isotopic composition of ground waters from Kufra (Lybia) as indicator for ground water formation

    Energy Technology Data Exchange (ETDEWEB)

    Swailem, F.M.; Hamza, M.S.; Aly, A.I.M. (Middle Eastern Regional Radioisotope Centre for the Arab Countries, Cairo (Egypt))

    1984-02-01

    The results of the isotopic composition of shallow and deep ground waters from the Kufra region indicate the fossil origin of these waters and that they are not recharged under the present climatic conditions. The virtual absence of tritium and the radiocarbon ages of these waters show that they were formed mainly in the past pluvial periods. Deuterium and oxygen-18 data indicate that the ground waters were recharged under cooler climatic conditions. These results may explain the origin of the large amounts of ground water which existed in the region.

  6. Composição química da solução de solo sob diferentes coberturas vegetais e análise de carbono orgânico solúvel no deflúvio de pequenos cursos de água Chemical composition of soil solution under different land cover and soluble organic carbon in water from small creeks

    Directory of Open Access Journals (Sweden)

    Josias Miranda

    2006-08-01

    Full Text Available O cultivo intensivo pode alterar a composição química da solução do solo, favorecendo a perda de solutos. Dessa forma, poderia mudar a composição química dos cursos de água. Foi realizado um estudo na fazenda da EPAMIG em Oratórios, Minas Gerais, de junho de 1996 a maio de 1997, para avaliar o efeito do manejo do solo na composição química da solução do solo, considerando as condições climáticas. O carbono orgânico solúvel também foi determinado na solução do solo e no deflúvio de pequenos cursos de água. Foram realizadas extrações mensais da solução do solo sob diferentes coberturas vegetais, nas camadas de 0-20, 20-40 e 40-100 cm de profundidade. A extração da solução do solo foi feita por centrifugação, a uma força centrífuga relativa correspondente a 900 g. Em acréscimo, foram feitas coletas semanais de deflúvio de quatro pequenos cursos de água com uso variado de suas respectivas áreas de drenagem. Foi observada uma ligeira elevação na concentração de íons em solução com o início do período chuvoso, sendo esse fato mais acentuado para o carbono orgânico solúvel na solução do solo e no deflúvio. A adubação mineral promoveu o deslocamento de íons trocáveis, em profundidade. A lixiviação foi favorecida, principalmente, no solo sem cobertura vegetal. A movimentação de carbono orgânico solúvel foi maior no solo sob pastagem, apesar do menor teor na solução do solo, em comparação aos outros solos. No curso de água drenado em área de pastagem, também foi encontrada a maior concentração de carbono orgânico solúvel.Intensive land use can change the chemical composition of the soil solution and cause solute losses. Thus, it can alter the chemical composition of water courses. A study was carried out in a farm of EPAMIG in Oratorios, state of Minas Gerais, Brazil, from June 1996 to May 1997, to evaluate the effect of soil management on the chemical composition of soil solution

  7. Chemical Composition and Biological Properties of Essential Oils of ...

    African Journals Online (AJOL)

    linoleic acid assays, peppermint oil showed superior antioxidant properties to chocolate mint oil. (4.45 - 19.86 μl/mL). ... hybrid of spearmint (M. spicata L.) and water mint (M. aquatica .... individually to 4.8 mL of the emulsion and this was then ...

  8. Chemical composition of Annona senegalensis from Nupe land ...

    African Journals Online (AJOL)

    USER

    2010-06-28

    Jun 28, 2010 ... carried out using standard methods of food analysis. The results of the ... increase use of foods rich in energy, proteins, iron and vitamins, most ... oxidation of some amino acids during hydrolysis). The ampoule was .... protein, chlorophylls, lipids and fatty acids of fresh water greens and blue green algae ...

  9. polypropylene-modified kaolinite composites: effect of chemical ...

    African Journals Online (AJOL)

    Meziane O, Bensedira A, Guessoum M and Haddaoui N

    2016-05-01

    May 1, 2016 ... Research Article ... variety of applications, including packaging, textiles, reusable containers of ..... C, with a residual mass around 5.5 %, which is .... [8] Frost R L, Kristof J, Horvath E, and Kloprogge J T. Effect of Water on the ...

  10. Elaboration of composite and chemically heterogeneous icephobic coatings

    Science.gov (United States)

    Arianpour, Faranak

    Atmospheric icing happens when the surfaces of exposed structures are subjected to contact with super-cooled water droplets or snow particles. Ice build-up on overhead transmission and distribution lines may lead to mechanical failure or insulator flashover, sometimes resulting in power outages with major socioeconomic consequences. The present study focused on the preparation of heterogeneous coatings (HCs) with hydro- and icephobic properties presenting a number of advantages, such as easy application, time-saving and low cost. The homo- and HCs were prepared by using different methods such as self-assembly, nanoparticles-based and Plasma-based techniques. Super-hydrophobic coatings with very low wetting hysteresis are also considered to be icephobic. However, even super-hydrophobic coatings can deteriorate during successive icing/de-icing cycles, and this can lead to ice mechanical anchoring since liquid water penetrates the porous surface. Additionally, the cost and complexity involved in the fabrication of such coatings as micro and nano roughness is created, constitute other hurdles. In this study HCs are considered as a coating including hydrocarbons and fluorocarbons, while purely hydrocarbons or fluorocarbons coatings are considered as the homogeneous coatings. It was shown by applying different functions (both C-F and C-H) the surface energy is decreased more compared to applying only one function (C-F or C-H alone). It should be noted that the water molecule orientations at the surfaces of the fluorocarbon and hydrocarbon groups were completely different. As a result, by inducing or creating various disparities (hydrocarbons and fluorocarbons) in terms of energy bonding, and water molecule orientation at the molecular level, the ice-solid interface is weakened. The wettability measurement of the HCs showed higher water contact angle (CA) values and smaller water contact angle hysteresis (CAH) values compared to homogeneous coatings. The most important

  11. Chemical composition of primary cosmic rays with IceCube

    Science.gov (United States)

    Xu, Chen

    Ground detector arrays have been used to measure high energy cosmic rays for decades to overcome their very low rate. IceCube is a special case with its 3D deployment and unique location---the South Pole. Although all 86 strings and 81 stations of IceCube were completed in 2011, IceCube began to take data in 2006, after the completion of the first 9 strings. In this thesis, experimental data taken in 2009 with 59 strings are used for composition analysis albeit some techniques are illustrated with the 40-string data. Simulation is essential in the composition work. Simulated data must be compared against the experimental data to find the right mix of cosmic ray components. However, because of limited computing resources and complexities of cosmic rays, the simulation in IceCube is well behind the experiment. The lower and upper bounds of primary energy in simulation for events that go through IceTop and the deep arrays of IceCube are 1014 eV and 1017 eV. However, since IceCube has a threshold energy about several hundred TeV, and an upper limit of 10 18 eV, the full energy range cannot be explored in this thesis. The approach taken to the composition problem in this thesis is a 2D Bayesian unfolding. It takes account of the measured IceTop and InIce energy spectrum and outputs the expected primary energy spectrum of different mass components. Studies of the uncertainties in the results are not complete because of limited simulation and understanding of the new detector and South Pole environment.

  12. Characterization of chemical composition of bee pollen in China.

    Science.gov (United States)

    Yang, Kai; Wu, Dan; Ye, Xingqian; Liu, Donghong; Chen, Jianchu; Sun, Peilong

    2013-01-23

    Bee pollen has been praised for its good nutrition and therapeutic values. China is the largest producer in the world. Twelve common varieties of monofloral bee pollen collected from China's main producing regions were selected for nutritional composition analysis, including proximate contents, dietary fibers, amino acid distribution, fatty acid composition, and mineral elements. The proximate compositions mostly met the specifications regulating pollen load quality of China. Proline and glutamic acids were found to be the predominant amino acids in the form of both total amino and free amino acids. Lysine was the relative limiting amino acid. The percentage of total essential amino acids (TEAA) to total amino acids (TAA) reached the nutrition recommendation of the Food and Agricultural Organization (FAO). The major fatty acids, presented as mean values, were C18:3 (25.1%), C16:0 (19.6%), C18:1 (17.3%), C18:2 (8.78%), C22:0 (4.07%), and C18:0 (2.96%) acids. The proportions of C18:3 were generally higher than those of C18:2, and the ratio of total unsaturated fatty acids (TUS) to total saturated fatty acids (TS) was >1.0, except for Nelumbo nucifera Gaertn. pollen for the characteristic absence of C18:3 acids. High levels of beneficial elements such as K, Ca, Mg, Zn, Fe, Mn. and Cu were observed in pollen samples. The contents of detrimental trace elements of Cd, Pb, and Hg were primarily lower or not detected. However, more attention should be paid to a large amount of Al, with a concentration of >100 mg/kg DW in most samples. There were some significant differences between samples. On the whole, the Chinese bee pollen was evaluated as a good complement to diet.

  13. Testing chemical composition of highest energy comic rays

    CERN Document Server

    Nosek, D; Noskova, J; Ebr, J

    2013-01-01

    We study basic characteristics of distributions of the depths of shower maximum in air showers caused by cosmic rays with the highest energies. The consistency between their average values and widths, and their energy dependences are discussed within a simple phenomenological model of shower development independently of assumptions about detailed features of high--energy interactions. It is shown that reliable information on primary species can be derived within a partition method. We present examples demonstrating implications for the changes in mass composition of primary cosmic rays.

  14. Chemical Composition And Nutritional Evaluation Of Leea Guineensis Seed

    OpenAIRE

    Ajiboye B.O; Oso A.O; Kobomoje O.S

    2014-01-01

    The proximate composition, minerals, fatty acids and amino acids profile of Leea guineensis seeds were investigated. The results of the proximate analysis revealed that Leea guineensis seeds have crude protein of 22.30 ±0.45%, crude fiber of 14.38±1.20% and ash of 6.96 ±0.16%. The results also shows that Leea guineensis seeds is a good sources of dietary minerals especially potassium, phosphorus, magnesium, manganese and copper. Fatty acids profile of the s...

  15. Pressure impact of autoclave treatment on water sorption and pectin composition of flax cellulosic-fibres.

    Science.gov (United States)

    Alix, S; Colasse, L; Morvan, C; Lebrun, L; Marais, S

    2014-02-15

    The tensile properties of flax fibres might permit them to be used in composites as reinforcement in organic resin, as long as their mechanical properties are reproducible and their water sorption are reduced. In this study, to minimise the variability of mechanical properties, several samples of flax fibres were blended as a non-woven fabric. In order to reduce the water absorption of this non-woven technical fibres, an autoclave treatment was performed which was expected to remove the pectins and then to reduce the water sorption on their negative charges. The impact of autoclave pressure (0.5, 1 and 2 bars) on water sorption was investigated by using a gravimetric static equilibrium method. The Park model based on the three sorption modes: Langmuir, Henry's law and clustering, was successfully used to simulate the experimental sorption data. The lowest pressure treatments impacted only the Langmuir contribution while the 2 bar autoclave-treatment positively impacted the water resistance in the core of fibres by reducing Henry's absorption rate. This was shown to be related to the chemical modifications at the surface and in the core of fibres. A schematic model is presented relating the water sorption and the pectic composition of the fabric. Copyright © 2013 Elsevier Ltd. All rights reserved.

  16. Simulation of aerosol chemical compositions in the Western Mediterranean Sea

    Science.gov (United States)

    Chrit, Mounir; Kata Sartelet, Karine; Sciare, Jean; Marchand, Nicolas; Pey, Jorge; Sellegri, Karine

    2016-04-01

    This work aims at evaluating the chemical transport model (CTM) Polair3d of the air-quality modelling platform Polyphemus during the ChArMex summer campaigns of 2013, using ground-based measurements performed at ERSA (Cape Corsica, France), and at determining the processes controlling organic aerosol concentrations at ERSA. Simulations are compared to measurements for concentrations of both organic and inorganic species, as well as the ratio of biogenic versus anthropogenic particles, and organic aerosol properties (oxidation state). For inorganics, the concentrations of sulphate, sodium, chloride, ammonium and nitrate are compared to measurements. Non-sea-salt sulphate and ammonium concentrations are well reproduced by the model. However, because of the geographic location of the measurement station at Cape Corsica which undergoes strong wind velocities and sea effects, sea-salt sulphate, sodium, chloride and nitrate concentrations are strongly influenced by the parameterizations used for sea-salt emissions. Different parameterizations are compared and a parameterization is chosen after comparison to sodium measurements. For organics, the concentrations are well modelled when compared to experimental values. Anthropogenic particles are influenced by emission of semi-volatile organic compounds (SVOC). Measurements allow us to refine the estimation of those emissions, which are currently missing in emission inventories. Although concentrations of biogenic particles are well simulated, the organic chemical compounds are not enough oxidised in the model. The observed oxidation state of organics shows that the oligomerisation of pinonaldehyde was over-estimated in Polyphemus. To improve the oxidation property of organics, the formation of extremely low volatile organic compounds from autoxidation of monoterpenes is added to Polyphemus, using recently published data from chamber experiments. These chemical compounds are highly oxygenated and are formed rapidly, as first

  17. Fabrication of fiber-reinforced composites by chemical vapor infiltration

    Energy Technology Data Exchange (ETDEWEB)

    Besmann, T.M.; McLaughlin, J.C. [Oak Ridge National Lab., TN (United States). Metals and Ceramics Div.; Probst, K.J.; Anderson, T.J. [Univ. of Florida, Gainesville, FL (United States). Dept. of Chemical Engineering; Starr, T.L. [Georgia Inst. of Tech., Atlanta, GA (United States). Dept. of Materials Science and Engineering

    1997-12-01

    Silicon carbide-based heat exchanger tubes are of interest to energy production and conversion systems due to their excellent high temperature properties. Fiber-reinforced SiC is of particular importance for these applications since it is substantially tougher than monolithic SiC, and therefore more damage and thermal shock tolerant. This paper reviews a program to develop a scaled-up system for the chemical vapor infiltration of tubular shapes of fiber-reinforced SiC. The efforts include producing a unique furnace design, extensive process and system modeling, and experimental efforts to demonstrate tube fabrication.

  18. Fabrication of fiber-reinforced composites by chemical vapor infiltration

    Energy Technology Data Exchange (ETDEWEB)

    Matlin, W.M. [Univ. of Tennessee, Knoxville, TN (United States); Stinton, D.P.; Besmann, T.M. [Oak Ridge National Lab., TN (United States)

    1995-08-01

    A two-step forced chemical vapor infiltration process was developed that reduced infiltration times for 4.45 cm dia. by 1.27 cm thick Nicalon{sup +} fiber preforms by two thirds while maintaining final densities near 90 %. In the first stage of the process, micro-voids within fiber bundles in the cloth were uniformly infiltrated throughout the preform. In the second stage, the deposition rate was increased to more rapidly fill the macro-voids between bundles within the cloth and between layers of cloth. By varying the thermal gradient across the preform uniform infiltration rates were maintained and high final densities achieved.

  19. Chemical composition of red Vranec wines from different locations

    OpenAIRE

    Neceva, Zaneta; Ivanova, Violeta

    2016-01-01

    In this study, red Vranec wines (vintage 2014) were produced from grapes grown at different locations: Barovo, Disan, Gradsko and Bitola. Wines were produced with same technology, applying traditional way of production. In addition, following chemical parameters which influence the wine quality were determined: total acidity, pH, volatile acidity, alcohol, SO2 (free and total) and reducing sugars. Wines contained total acids in range from 4.9 to 7.1 g/L and the volatile acidity was in range f...

  20. [Analysis of main chemical composition in hydrogenated rosin from Zhuzhou].

    Science.gov (United States)

    Duan, W G; Chen, X P; Wang, L L; Deng, S; Zhou, Y H; An, X N

    2001-01-01

    The acid fraction, the main part of the hydrogenated rosin produced by Zhuzhou Forest Chemicals Plant of China, was separated from neutral fraction by modified DEAE-Sephadex ion exchange chromatography and analyzed with GC-MS-DS technique by using DB-5 capillary column. Six dihydroabietic-type resin acids, four dihydropimaric/isopimaric-type resin acids and four tetrahydroabietic-type resin acids were identified. The hydrogenated rosin is composed mainly of 8-abietenoic acid, 18-abietanoic acid, 13-abietenoic acid, 8 alpha, 13 beta-abietanoic acid, 13 beta-8-abietenoic acid and 8-isopimarenoic acid etc.

  1. Composite reweighting with Imaginary Chemical Potentials in SU(3)

    CERN Document Server

    Crompton, P R

    2002-01-01

    We review the overlap pathology of the Glasgow reweighting method for finite density QCD, and discuss the sampling bias that effects the determination of the ensemble-averaged fugacity polynomial expansion coefficients that form the Grand Canonical Partition function. The expectation of the difference in free energies between canonical partition functions generated with different measures is presented as an indicator of a systematic quark number dependent biasing in the reweighting approach. The advantages of building up an unbiased polynomial expansion for the Grand Canonical Partition function through a series of parallel ensembles generated by reweighting with imaginary chemical potentials are then contrasted with addressing the overlap pathology through a secondary reweighting.

  2. Chemical-garden formation, morphology, and composition. I. Effect of the nature of the cations.

    Science.gov (United States)

    Cartwright, Julyan H E; Escribano, Bruno; Sainz-Daz, C Ignacio

    2011-04-05

    We have grown chemical gardens in different sodium silicate solutions from several metal-ion salts--calcium chloride, manganese chloride, cobalt chloride, and nickel sulfate--with cations from period 4 of the periodic table. We have studied their formation process using photography, examined the morphologies produced using scanning electron microscopy (SEM), and analyzed chemical compositions using X-ray powder diffraction (XRD) and energy dispersive X-ray analysis (EDX) to understand better the physical and chemical processes involved in the chemical-garden reaction. We have identified different growth regimes in these salts that are dependent on the concentration of silicate solution and the nature of the cations involved.

  3. Effects of water stress on the composition and immunoreactive properties of gliadins from two wheat cultivars: Nawra and Tonacja.

    Science.gov (United States)

    Brzozowski, Bartosz; Stasiewicz, Katarzyna

    2017-03-01

    Water shortage during wheat vegetation causes changes in the composition of gliadins in grains, which can lead to changes in their immunoreactive properties. The investigated wheat cultivars exposed to water stress accumulated significantly lower amounts (P Water shortage results in a decreased share of αβ and γ fractions in total gliadins. Grains of wheat cultivated under water stress contain significantly higher (P Water stress promotes an increase in the share of P and Q/E residues in gliadins. In protein samples R5 antibodies recognized increased amounts of gliadins matching the QQPFP sequence. Wheat proteins also reacted with IgE antibodies isolated from subjects allergic to gluten. Cultivation of wheat under conditions of water stress results in the qualitative and quantitative changes of gliadins by increasing their immunoreactivity. © 2016 Society of Chemical Industry. © 2016 Society of Chemical Industry.

  4. Study of Meat Physical-Chemical Composition of Three Trout Breeds Farmed in Salmonid Exploitations from Moldova

    Directory of Open Access Journals (Sweden)

    Cătălin Emilian NISTOR

    2014-11-01

    Full Text Available For all trout breeds, especially regarding brown trout, data from local and foreign literature consulted are less conclusive and sometimes controversial in terms of physical-chemical composition of trout meat, so our research represents a first for Romanian literature and aims to bring new information to enrich it.Our research aimed to evaluate the physical-chemical composition of the meat gathered from brook, rainbow and brown trout breed, by analyzing 50 individuals, 10 individuals in each batch (F1, F2, C1 C2 and I1, from two trout farms from Moldova, being determine the pH of meat, dry matter, content in proteins, lipids, ash and water/protein ratio for all three trout breeds. The obtained values for pH at warm ranged between 6.91 at batch F1, and 7.09 for batch I1. As regarding the pH at cold, this one had and descendant evolution ranging between: 6.78 for trout from batch F1 respectively a value of 6.88 for individuals from batch I1. The obtained values were between 23.95 and 27.12 for dry matter. Content in proteins recorded the best values (19.21% at individuals from batch F2, and content in lipids oscillated between 4.14% and 5.62%. The obtained values regarding physical-chemical composition highlighted that all trout breeds have a good nutritional value.

  5. Phosphorus dynamics in soils irrigated with reclaimed waste water or fresh water - A study using oxygen isotopic composition of phosphate

    Science.gov (United States)

    Zohar, I.; Shaviv, A.; Young, M.; Kendall, C.; Silva, S.; Paytan, A.

    2010-01-01

    Transformations of phosphate (Pi) in different soil fractions were tracked using the stable isotopic composition of oxygen in phosphate (??18Op) and Pi concentrations. Clay soil from Israel was treated with either reclaimed waste water (secondary, low grade) or with fresh water amended with a chemical fertilizer of a known isotopic signature. Changes of ??18Op and Pi within different soil fractions, during a month of incubation, elucidate biogeochemical processes in the soil, revealing the biological and the chemical transformation impacting the various P pools. P in the soil solution is affected primarily by enzymatic activity that yields isotopic equilibrium with the water molecules in the soil solution. The dissolved P interacts rapidly with the loosely bound P (extracted by bicarbonate). The oxides and mineral P fractions (extracted by NaOH and HCl, respectively), which are considered as relatively stable pools of P, also exhibited isotopic alterations in the first two weeks after P application, likely related to the activity of microbial populations associated with soil surfaces. Specifically, isotopic depletion which could result from organic P mineralization was followed by isotopic enrichment which could result from preferential biological uptake of depleted P from the mineralized pool. Similar transformations were observed in both soils although transformations related to biological activity were more pronounced in the soil treated with reclaimed waste water compared to the fertilizer treated soil. ?? 2010 Elsevier B.V.

  6. Chemical composition distribution analysis of photoresist copolymers and influence on ArF lithographic performance

    Science.gov (United States)

    Momose, Hikaru; Yasuda, Atsushi; Ueda, Akifumi; Iseki, Takayuki; Ute, Koichi; Nishimura, Takashi; Nakagawa, Ryo; Kitayama, Tatsuki

    2007-03-01

    For getting information about the distribution of chemical composition, several model polymers were prepared under different polymerization conditions and were measured by critical adsorption point-liquid chromatography (CAP-LC). In the copolymer system of 8- and 9- (4-oxatricyclo[5.2.1.0 2,6]decane-3-one) acrylate (OTDA) and 2-ethyl-2-adamantyl methacrylate (EAdMA), the peak shapes of the CAP-LC chromatogram varied according to the polymerization condition although they indicated same molecular weight and averaged chemical composition. The difference of the CAP-LC elution curves was related to the chemical composition distribution of copolymers for CAP-LC measurement combined with proton nuclear magnetic resonance (1H-NMR). The terpolymers consisted of α-hydroxy-γ-butyrolactone methacrylate (GBLMA), 2-methyl-2-adamantyl methacrylate (MAdMA) and 1-hydroxy-3-adamantyl methacrylate (HAdMA) were prepared under various polymerization conditions. In the terpolymer system that had same molecular weight and average chemical composition, the solubility parameter (δ) and the dissolution rate were measured. The δ value and the dissolution rate curve were different among these terpolymers. It was suggested that the δ value and the chemical composition distribution of these terpolymers have a significant influence on the lithographic performance.

  7. [Influence of specification on chemical composition of dissolution and hepatocytes toxicity of Polygonum multiflorum].

    Science.gov (United States)

    lI, Yu-Meng; Li, Rui-Yu; Niu, Ming; Li, Chun-Yu; Bai, Zhao-Fang; Feng, Wu-Wen; Zhang, Cong-En; Tan, Peng; Huang, Zhi-Pu; Ma, Wei-Guang; Wang, Jia-Bo; Xiao, Xiao-He

    2016-03-01

    According to different toxicities of various aqueous extracts of Polygonum multiflorum on hepatocyte, the impacts of chemical composition on the safety of P. multiforum was studied. In this study, 8 main chemical compositions in aqueous extracts of P. multiflorum were determined by the established HPLC method; at the same time, the inhibition ratios of different aqueous extracts of P. multiflorum on L02 cell were determined. Afterwards, the potential compounds related to the toxicity of P. multiforum were tentatively found through a multiple correlation analysis. The results showed that P. multiforum with different chemical compositions exhibited great differences in dissolution. The hepatocyte toxicity of P. multiflorum powder was much greater than P. multiflorum lumps. In addition, three constituents closely related to toxicity of P. multiflorum were found by multiple correlation analysis. The study revealed that chemical composition of P. multiflorum is closely related to the hepatotoxicity, and the hepatotoxicity of P. multiflorum powder is greater than that of other dosage forms. This study indicates that P. multiflorum with different chemical compositions show varying toxicity, which therefore shall be given high attention. Copyright© by the Chinese Pharmaceutical Association.

  8. Chemical and Oxygen Isotopic Composition of Roman and Late Antique Glass from Northern Greece

    Directory of Open Access Journals (Sweden)

    Alberta Silvestri

    2017-01-01

    Full Text Available The present paper emphasizes the importance of measuring the oxygen isotopic and chemical compositions of ancient glass, in order to constrain some features such as age, raw materials, and production technologies and to identify the “fingerprint” of local productions. In this context, thirty-nine Roman and late Antique glass samples and eight chert samples from northern Greece were selected and analysed for their oxygen isotopic and chemical compositions. Results show that the majority of glass samples are produced using natron as flux and have δ18O values of about 15.5‰, plus or minus a few tenths of one per mil, suggesting that raw materials probably come from Levantine area. Four samples are heavily enriched in 18O, and their chemical composition clearly shows that they were made with soda plant ash as flux. Isotopic and chemical data of Greek chert samples support the hypothesis of local production of the above samples. About half of the glass samples have chemical compositions, which allow their age to be constrained to the late Antique period. For the remaining glass, similarities with literature compositional groups are reported and discussed.

  9. Nanoscale chemical interaction enhances the physical properties of bioglass composites.

    Science.gov (United States)

    Ravarian, Roya; Zhong, Xia; Barbeck, Mike; Ghanaati, Shahram; Kirkpatrick, Charles James; Murphy, Ciara M; Schindeler, Aaron; Chrzanowski, Wojciech; Dehghani, Fariba

    2013-10-22

    Bioglasses are favorable biomaterials for bone tissue engineering; however, their applications are limited due to their brittleness. In addition, the early failure in the interface is a common problem of composites of bioglass and a polymer with high mechanical strength. This effect is due to the phase separation, nonhomogeneous mixture, nonuniform mechanical strength, and different degradation properties of two compounds. To address these issues, in this study a nanoscale interaction between poly(methyl methacrylate) (PMMA) and bioactive glass was formed via silane coupling agent (3-trimethoxysilyl)propyl methacrylate (MPMA). A monolith was produced at optimum composition from this hybrid by the sol-gel method at 50 °C with a rapid gelation time (hybrid. The in vivo studies in mice demonstrated that the integrity of the hybrids was maintained in subcutaneous implantation. They induced mainly a mononuclear phagocytic tissue reaction with a low level of inflammation, while bioglass provoked a tissue reaction with TRAP-positive multinucleated giant cells. These results demonstrated that the presence of a nanoscale interaction between bioglass and PMMA affects the properties of bioglass and broadens its potential applications for bone replacement.

  10. Chemical Composition and Antioxidant Capacity of Brazilian Passiflora Seed Oils.

    Science.gov (United States)

    de Santana, Fernanda Carvalho; Shinagawa, Fernanda Branco; Araujo, Elias da Silva; Costa, Ana Maria; Mancini-Filho, Jorge

    2015-12-01

    The seed oils of different varieties of 4 Passiflora species cultivated in Brazil were analyzed and compared regarding their physicochemical parameters, fatty acid composition and the presence of minor components, such as phytosterols, tocopherols, total carotenoids, and phenolic compounds. The antioxidant capacities of the oil extracts were determined using the 2,2'azinobis [3-ethylbenzothiazoline-6-sulfonic acid] and oxygen radical absorbance capacity methods. The results revealed that all studied Passiflora seed oils possessed similar physicochemical characteristics, except for color, and predominantly contained polyunsaturated fatty acids with a high percentage of linolenic acid (68.75% to 71.54%). Other than the total phytosterol content, the extracted oil from Passiflora setacea BRS Pérola do Cerrado seeds had higher quantities (% times higher than the average of all samples), of carotenoids (44%), phenolic compounds (282%) and vitamin E (215%, 56%, 398%, and 100% for the α-tocopherol, β-tocopherol, γ-tocopherol, and δ-tocopherol isomers, respectively). The methanolic extracts from Passiflora setacea BRS Pérola do Cerrado seed oil also showed higher antioxidant activity, which was positively correlated with the total phenolic, δ-tocopherol, and vitamin E contents. For the first time, these results indicate that Passiflora species have strong potential regarding the use of their seeds for oil extraction. Due to their interesting composition, the seed oils may be used as a raw material in manufacturing industries in addition to other widely used vegetable oils.

  11. On the Formation and Chemical Composition of Super Earths

    CERN Document Server

    Alessi, Matthew; Cridland, Alex J

    2016-01-01

    Super Earths are the largest population of exoplanets and are seen to exhibit a rich diversity of compositions as inferred through their mean densities. Here we present a model that combines equilibrium chemistry in evolving disks with core accretion that tracks materials accreted onto planets during their formation. In doing so, we aim to explain why super Earths form so frequently and how they acquire such a diverse range of compositions. A key feature of our model is disk inhomogeneities, or planet traps, that act as barriers to rapid type-I migration. The traps we include are the dead zone, which can be caused by either cosmic ray or X-ray ionization, the ice line, and the heat transition. We find that in disks with sufficiently long lifetimes ($\\gtrsim$ 4 Myr), all traps produce Jovian planets. In these disks, planet formation in the heat transition and X-ray dead zone produces hot Jupiters while the ice line and cosmic ray dead zones produce Jupiters at roughly 1 AU. Super Earth formation takes place wi...

  12. An estimate of the chemical composition of Titan's lakes

    CERN Document Server

    Cordier, D; Lunine, J -I; Lavvas, P; Vuitton, V

    2009-01-01

    Hundreds of radar-dark patches interpreted as lakes have been discovered in the north and south polar regions of Titan. We have estimated the composition of these lakes by using the direct abundance measurements from the Gas Chromatograph Mass Spectrometer (GCMS) aboard the Huygens probe and recent photochemical models based on the vertical temperature profile derived by the Huygens Atmospheric Structure Instrument (HASI). Thermodynamic equilibrium is assumed between the atmosphere and the lakes, which are also considered as nonideal solutions. We find that the main constituents of the lakes are ethane (C2H6) (~76-79%), propane (C3H8) (~7-8%), methane (CH4) (~5-10%), hydrogen cyanide (HCN) (~2-3%), butene (C4H8) (~1%), butane (C4H10) (~1%) and acetylene (C2H2) (~1%). The calculated composition of lakes is then substantially different from what has been expected from models elaborated prior to the exploration of Titan by the Cassini-Huygens spacecraft.

  13. Physico-chemical properties of perturbed water: facts and enigmas

    Directory of Open Access Journals (Sweden)

    Vittorio Elia

    2012-09-01

    Full Text Available Background The study of extremely diluted and agitated substances and solutions is strictly linked with the analysis of properties of water perturbed using different systems. This study is about the determination of the physical-chemical parameters of water, after the perturbations described. Methods The perturbed water was obtained using the three different protocols: · EDS (Extremely Diluted Solutions. Obtained through an iterative process of successive dilutions and agitations. · IFW (Iteratively Filtered Water. Obtained through an iterative process of successive filtrations through sintered glass filters. · INW (Iteratively Nafionized Water. Obtained through an iterative process of successive drying and wetting of the Nafion polymer. The parameters under study are: electrical conductivity, χ / μS cm-1; heat of mixing with acid (HCl, ΔQmixHCl / J Kg-1 or basic (NaOH solutions, ΔQmixNaOH / J Kg-1 and pH. χ increases of up to two orders of magnitude, ΔQmixNaOH / J Kg-1 is exothermic and increases as the electrical conductivity increases, with a roughly linear trend, up to one order of magnitude. The analogous ΔQmixHCl / J Kg-1, on the contrary, is found to be exothermic or null depending on the protocol used. For the two protocol (EDS or IFW the pH is alkaline while for the third one (INW is quite acid and shows a very good linear correlation with logχ. The linear correlations hint at a single cause for the variation of the three very different physical- chemical parameters. Results and discussion Each protocol produces water exhibiting its own peculiarities, to the point that they can be considered different, albeit with the common element of a variation of the super-molecular structure of the water solvent. These three procedures capable of affecting water can be grouped together by means of a common work

  14. Chemical composition of meat in two cyprinid species

    Directory of Open Access Journals (Sweden)

    Valerica Macovei

    2009-06-01

    Full Text Available The biochemical analyses of the meat were determined in two species of carps, respectively Cyprinus carpio and Ctenopharyngodon idella. We worked on four groups of 10 fishes each (two groups for C. carpio and two groups for Ct. idella. One group from both species was fed with special fodder, and the other two groups were fed with clover (Trifolium pratense and reeds (Phragmites communis for C. carpio and Ct. idella respectively. The determination was made in the laboratory of chemical analyses of the Faculty of Animal Sciences, University of Agricultural Sciences and Veterinary Medicine Iaşi and we determined the content of the meat in proteins, fat, dry substance and minerals. The characteristic chemicals of the meat were determined on the extracted sample from the lateral musculature of the body. Biochemical analysis of meat from the four carp lots shows that protein content of meat is higher in groups which received combined feed compared to group which individuals were fed with natural food. Therefore, in case of feeding fish with combined fodder the protein content of meat increases, which proves a good recovery of protein in feed. Fat content and minerals in cyprinid meat are both higher in individuals fed with combined feed compared to those fed with natural components. When fat content in meat is higher, the dry matter content in meat is higher.

  15. Influence of the chemical composition on steel casting performance

    Directory of Open Access Journals (Sweden)

    Roney Eduardo Lino

    2017-01-01

    Full Text Available Improving the quality of steel and the steelmaking process has been a matter of routine for metallurgical engineers and steelmaking companies in a demanding market for quality products at highly competitive price. The chemical and temperature adjustment are made during the secondary refining process, as well as the inclusion modification required to product quality, and also the demand for castability accuracy. Continuous casting process is the most used solidification casting process, in which the flow of pouring liquid metal through the submerged entry nozzle is assured by the correct temperature and the formation of liquid inclusion in the casting temperature. Thermocalc and CEQCSI were the software used in this work to assess the effect of carbon, silicon and sulphur in the castability window of the aluminium vs calcium phase diagrams. They have proved to be highly suitable and effective and the results showed that the chemical elements used directly affected the position of the castability window of carbon steel. An analysis of a 0.2%C billet sample using Scanning Electron Microscopy showed that there is a great heterogeneity of inclusions in aluminium-killed and calcium-treated steel.

  16. Chemical Compositions of Kinematically Selected Outer Halo Stars

    CERN Document Server

    Zhang, Lan; Aoki, Wako; Zhao, Gang; Chiba, Masashi

    2009-01-01

    Chemical abundances of 26 metal-poor dwarfs and giants are determined from high-resolution and high signal-to-noise ratio spectra obtained with Subaru/HDS. The sample is selected so that most of the objects have outer-halo kinematics. Self-consistent atmospheric parameters were determined by an iterative procedure based on spectroscopic analysis. Abundances of 13 elements, including $\\alpha$-elements (Mg, Si, Ca, Ti), odd-Z light elements (Na, Sc), iron-peak elements (Cr, Mn, Fe, Ni, Zn) and neutron-capture elements (Y, Ba), are determined by two independent data reduction and LTE analysis procedures, confirming the consistency of the stellar parameters and abundances results. We find a decreasing trend of [$\\alpha$/Fe] with increasing [Fe/H] for the range of $-3.5 <$ [Fe/H]$ < -1$, as found by Stephens and Boesgaard (2002). [Zn/Fe] values of most objects in our sample are slightly lower than the bulk of halo stars previously studied. These results are discussed as possible chemical properties of the ou...

  17. Chemical composition of fresh snowfalls at Palmer Station, Antarctica

    Science.gov (United States)

    DeFelice, T. P.

    A first time investigation was performed to establish a chemical baseline for snowfall at Palmer Station Antarctica (64°46'S, 64°05'W) since there was no such record. A chemical baseline for snow could be use to validate climate change studies based on ice core analyses. The snow samples contained (from high to low mass concentration) total organic carbon, chloride, inorganic carbon, sodium, sulfate, magnesium, calcium, potassium, fluoride, ammonium, and nitrate, excluding hydrogen and hydroxide. The pH of these samples ranged between 4.0-6.2. The relatively low nitrate and relatively high sulfate concentrations found in our samples are consistent with the results of other studies for this region of Antarctica. The ions and pH do not appear to favor a particular wind direction during this period. The total deposition of sulfate and flouride via snowfall between 10 January and 10 February is conservatively estimated to be 4.78 and 1.3 kg km -2, respectively.

  18. Analysis of changes in the chemical composition of the blast furnace coke at high temperatures

    Directory of Open Access Journals (Sweden)

    A. Konstanciak

    2012-12-01

    Full Text Available Purpose: The main purpose of this paper was to analyze the behavior of coke in the blast furnace. The analysis of changes in chemical composition of coke due to impact of inert gas and air at different temperatures was made. The impact of the application of the thermoabrasion coefficient on the porosity of coke was also analyzed.Design/methodology/approach: By applying the Computer Thermochemical Database of the TERMO system (REAKTOR1 and REAKTOR3 three groups of substances can be distinguished. The chemical composition of blast furnace coke and the results of calculations of changes of chemical composition of coke heat treated under certain conditions were compared. The structural studies of these materials were presented.Findings: The results of the analysis of ash produced from one of Polish cokes was taken for consideration. This is not the average composition of Polish coke ashes, nevertheless it is representative of most commonly occurring chemical compositions.Practical implications: Thanks to the thermochemical calculations it is possible to predict ash composition after the treatment in a blast furnace. Those information was crucial and had an actual impact on determining the coke quality.Originality/value: Presentation of the analytical methods which, according to author, can be very useful to evaluate and identify the heat treatment for blast furnaces cokes. The research pursued represents part of a larger project carried out within the framework of Department Extraction and Recycling of Metals, Czestochowa University of Technology.

  19. Water Group Composition Near the Orbit of Enceladus

    Science.gov (United States)

    Williams, J. D.; Delamere, P. A.; Bagenal, F.; Reisenfeld, D.; Fleshman, R.

    2008-12-01

    We present magnetospheric ion composition results from the Cassini CAPS IMS instrument. The data set is averaged over a four year period. Data from the equatorial plane are selected and binned into radial, local time and longitude bins with a focus on radial distances between 3-10 Saturn radii. The data analysis process necessitates fitting the instrument response functions to the raw data and so methods of assessment of data uncertainty are also presented. Water group ions (O+, OH+, H2O+, H3O+; or collectively W+), presented as mixing ratios dominate over H+ in this radial range and O+ is the dominant water group species. Temporal variations within the study period are presented. The energy distribution of the ion composition is also examined and the flow velocity is compared to the corotation velocity of the plasma.

  20. Effect of diet composition on water consumption in growing pigs.

    Science.gov (United States)

    Shaw, M I; Beaulieu, A D; Patience, J F

    2006-11-01

    Concerns relating to use of water resources by the livestock industry, combined with the rising cost of manure management, have resulted in greater interest in identifying ways to reduce drinking water utilization by pigs while maintaining animal well-being and achieving satisfactory growth performance. The objective of this experiment was to determine if increasing the dietary CP or mineral concentrations increases water intake and excretion and, conversely, if reducing the dietary CP content reduces water intake and excretion. Forty-eight barrows (34.3 +/- 4.6 kg of BW; 12/treatment) were given free access to diets containing a low protein (16.9% CP), high protein (20.9% CP), or excess protein (25.7% CP) level, or a diet with excess levels of Ca, P, Na, and Cl. Water was available to each pig on an ad libitum basis via dish drinkers that were determined to waste less than 3% of total water flow. The excess CP diet tended to increase average daily water intake (ADWI) and urinary excretion (P luxury intake is a significant experimental challenge. Because the impact of dietary treatment on water utilization was small, we conclude that factors other than dietary protein and mineral concentration and daily protein and mineral intake have a relatively large effect on water intake and excretion. Consequently, strategies to reduce water intake must recognize, understand, and manage these additional behavioral and physiological factors. Diet composition may be a part of strategies designed to reduce excessive water utilization by the pig industry but may have a limited effect if other important factors are ignored.

  1. Chemical Composition of Atmospheric Aerosols Above a Pristine South East Asian Rainforest

    Science.gov (United States)

    Robinson, N. H.; Allan, J. D.; Williams, P. I.; Coe, H.; Hamilton, J.; Chen, Q.; Martin, S.; Trembath, J.

    2009-04-01

    conjunction with a constant pressure inlet. The aerosols' chemical origins have been further investigated by comparing these spectra to chamber experiments, mass spectral libraries and data from comparable experiments in other locations. These data are also being analysed in conjunction with offline techniques applied to samples collected using filters and a Particle-Into-Liquid Sampler (PILS). Methods used include liquid chromatography and comprehensive two-dimensional gas chromatography coupled to time of flight mass spectrometry. These techniques provide a more detailed chemical characterisation of the SOA and water soluble organic carbon, allowing direct links back to gas phase precursors. In conjunction with the field measurements, a programme of chamber experiments is being carried out at Manchester as part of the ACES project. This will generate comparable SOA under controlled conditions and subjecting them to similar analysis.

  2. The chemical composition of organic nitrogen in marine rainwater and aerosols

    Science.gov (United States)

    Altieri, K. E.; Hastings, M. G.; Peters, A.; Sigman, D. M.

    2010-12-01

    The current state of knowledge on organic nitrogen in the atmosphere is very limited. Atmospheric water soluble organic nitrogen (WSON) is a subset of the complex water soluble organic matter measured in atmospheric aerosols and rainwater; as such, it impacts cloud condensation processes and aerosol chemical and optical properties. In marine and continental atmospheric deposition, the organic N fraction can be 20-80% of total N potentially influencing receiving ecosystems. Therefore, atmospheric WSON plays an important role in both atmospheric chemistry and the global biogeochemical N cycle. However, the sources (i.e., anthropogenic vs. terrestrial vs. marine), composition (e.g., reduced or oxidized N), potential connections to inorganic N (NO3- and NH4+), and spatio-temporal variability of atmospheric WSON are largely unknown. Samples were collected on or near the island of Bermuda (32.27°N, 64.87°W), which is located in the western North Atlantic and experiences seasonal changes in transport that allow for study of both anthropogenically and primarily marine influenced air masses. Rainwater samples (n=7) and aqueous extracted aerosol samples (n=4) were analyzed by positive ion ultra-high resolution electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI FT-ICR MS) to characterize the chemical composition of the water soluble organic N on a per compound level. We found ~ 800 N containing compounds in 8 compound classes. The CHON+ compound class contained the largest number of N compounds (~ 460). Compared to continental rainwater [Altieri et al., ES&T, 2009], the CHON+ compounds in the marine samples are as dominant in number, yet have less regular patterns and lower O:C ratios for comparable N:C ratios. In fact, average O:C ratios of all N containing compound classes were lower in the marine samples than in continental rainwater samples. No organosulfates or nitrooxy-organosulfates were detected in the marine samples, both of

  3. Chemical composition and structural characterization of contrasting colors of soybean seed coats

    Directory of Open Access Journals (Sweden)

    Carlos André Bahry

    2015-07-01

    Full Text Available Seed coats provide protection to seeds and present differential traits between soybean genotypes. The aim of this study was to determine the chemical composition and analyze the internal coat structure of soybean genotypes with contrasting seed coat color, as well as to evaluate the rate of water absorption by seeds. Four genotypes were tested: two genotypes with black seed coat (IAC and TP lines and two genotypes with yellow seed coat (BMX Potência RR and CD 202 cultivars.The seeds of the four genotypes were grown during the 2012/0213 crop season, in a greenhouse at the Embrapa Clima Temperado - Estação Experimental Terras Baixas. After the harvest, the seeds were stored in controlled conditions for five months. After this period, concentration of phenolic compounds, antioxidant potential, anthocyanins, carotenoids, and lignin in seed coats were determined at the Universidade Federal de Pelotas. Internal coat structure was examined on anatomical slides and documented with image capturing software using a microscope at the Escola Superior de Agricultura Luiz de Queiroz, Universidade de São Paulo. Finally, water absorption of contrasting seeds was evaluated at 42 hours of imbibition. Experimental design was completely randomized with five replicates. Data were subjected to analysis of variance and the means were compared by Tukey’s test, at 5% probability level. Coat structure was characterized by the image analysis. Imbibition data were subjected to regression analysis. The concentration of phenolic compounds, antioxidant potential, anthocyanins, carotenoids, and lignin are higher in black coated genotypes. Their palisade layer and hourglass cells are thicker and the former are more lignified in black seed coats compared to yellow seed coats. The water gain by the seeds is dependent on the conditions in which the seeds were formed and varied between genotypes, independent of coat coloration and lignin concentration.

  4. Chemical composition and food uses of teff (Eragrostis tef).

    Science.gov (United States)

    Zhu, Fan

    2018-01-15

    Teff (Eragrostis tef) is a cereal native to Ethiopia and Eritrea. It has an excellent adaptability to harsh environmental conditions and plays an important role in food security. In recent years, teff is becoming globally popular due to the attractive nutritional profile such as gluten free and high dietary fiber content. This review documents the recent advances in the genetic diversity, nutritional composition and food uses of teff grain. The attractive nutrients of teff include protein, dietary fiber, polyphenols, and certain minerals. Whole grain teff flour becomes increasingly important in healthy food market, and has been used to produce various gluten free food items such as pasta and bread. Efforts have been made to enhance the sensory quality of teff based products. There is great potential to adapt teff to the other parts of the world for healthy food and beverage production. Copyright © 2017 Elsevier Ltd. All rights reserved.

  5. An overview of a uranium acidic mining lake (Caldas, Brazil): composition of the zooplankton community and limno-chemical aspects

    Energy Technology Data Exchange (ETDEWEB)

    Nascimento, H.; Ferrari, C.; Roque, C.V.; Nascimento, M.R. [Brazilian Nuclear Energy Commission/Pocos de Caldas Laboratory (Brazil); Wisniewski, M.J. [Alfenas Federal University/Limnology Laboratory (Brazil); Rodgher, S. [Universidade Estadual Paulista Julio de Mesquita Filho/Science and Technology Laboratory (Brazil)

    2014-07-01

    This research represents an attempt to fill a gap in the information on the zooplankton composition and limno-chemical aspects of the uranium pit lake (Osamu Utsumi Pit, Brazil), affected by acid mine drainage. In the present study water samples were collected three-monthly, for a period of one year (2008-2009). The water samples from the uranium pit lake showed moderately acidic pH values (3.6 to 4.1), high values of the electrical conductivity, sulfate, uranium, fluoride, zinc, manganese and aluminum concentrations. The Rotifera cephalodella sp., Keratella americana, K. cochlearis, Bdelloidea order and the Cladocera Bosminopsis deitersi, Bosmina sp., were registered in the samples from the uranium pit lake with ADM. Of the species registered the Bdelloidea order was the most important in terms of density (17,500 - 77,778 ind m{sup -3}), since it occurred throughout the whole sampling period. In this study, probably the combined effect of moderately acid pH values and other potentially co-stressors factors, for example the high concentrations of stable and radioactive chemical species, could have influenced this richness and also the composition of the zooplankton species in the water samples from the uranium pit lake. Document available in abstract form only. (authors)

  6. Chemical composition and biological activities of the Agaricus mushrooms

    Directory of Open Access Journals (Sweden)

    L Munkhgerel

    2014-10-01

    Full Text Available Two species of Agaricus mushroom grown in Mongolia were analyzed for their element content. Biological activity and chemical components study of Agaricus, grown in the Mongolian flora has been investigated for the first time. The ethanol extracts of dried Agaricus sp. mushrooms were analyzed for antioxidant activity on 1,1-diphenyl-2- picrylhydrazyl (DPPH radicals and interferon-like activity. The ethanol extracts from Agaricus arvensis showed the most potent radical scavenging activity. The IC50 of A. silvaticus and A. arvensis were 216 and 17.75 g/ml respectively. Among the twenty three mushroom extracts, the extracts from A. silvatisus and A. arvensis have shown the interferon-like activity. DOI: http://dx.doi.org/10.5564/mjc.v14i0.197Mongolian Journal of Chemistry 14 (40, 2013, p41-45

  7. Chemical composition of umbu (Spondias tuberosa Arr. Cam seeds

    Directory of Open Access Journals (Sweden)

    Soraia Vilela Borges

    2007-02-01

    Full Text Available The umbu tree (Spondias tuberosa Arr. Cam is an important fruit tree the economy of the semi-arid northeastern region of Brazil. With the objective of finding use for the seeds, physical and chemical characterizations of the seeds from 2 cultivars in 2 maturation stages were carried out and their fatty acid and mineral profiles determined. The results showed no differences between the seeds analyzed. The yield was about 10% and the dimensions as follows: length from 1.48 to 2.11 cm and width from 0.76 to 1.16 cm. The average lipid content was 55% of which 69% was unsaturated and the average protein content was 24%. The seeds were a good source of the following minerals: P, K, Mg, Fe and Cu. The overall results indicated that the oil or the seeds could be used for food stuffs if no toxic agents were found.

  8. A New Reference Chemical Composition for TMC-1

    CERN Document Server

    Gratier, P; Ohishi, M; Roueff, E; Loison, J -C; Hickson, K M; Wakelam, V

    2016-01-01

    Recent detections of complex organic molecules in dark clouds have rekindled interest in the astrochemical modeling of these environments. Because of its relative closeness and rich molecular complexity, TMC-1 has been extensively observed to study the chemical processes taking place in dark clouds. We use local thermodynamical equilibrium radiative transfer modeling coupled with a Bayesian statistical method which takes into account outliers to analyze the data from the Nobeyama spectral survey of TMC-1 between 8 and 50 GHz. We compute the abundance relative to molecular hydrogen of 57 molecules, including 19 isotopologues in TMC-1 along with their associated uncertainty. The new results are in general agreement with previous abundance determination from Ohishi & Kaifu and the values reported in the review from Agundez & Wakelam. However, in some cases, large opacity and low signal to noise effects allow only upper or lower limits to be derived, respectively.

  9. A New Reference Chemical Composition for TMC-1

    Science.gov (United States)

    Gratier, P.; Majumdar, L.; Ohishi, M.; Roueff, E.; Loison, J. C.; Hickson, K. M.; Wakelam, V.

    2016-08-01

    Recent detections of complex organic molecules in dark clouds have rekindled interest in the astrochemical modeling of these environments. Because of its relative closeness and rich molecular complexity, TMC-1 has been extensively observed to study the chemical processes taking place in dark clouds. We use local thermodynamical equilibrium radiative transfer modeling coupled with a Bayesian statistical method which takes into account outliers to analyze the data from the Nobeyama spectral survey of TMC-1 between 8 and 50 GHz. We compute the abundance relative to molecular hydrogen of 57 molecules, including 19 isotopologues in TMC-1 along with their associated uncertainty. The new results are in general agreement with previous abundance determination from Ohishi & Kaifu and the values reported in the review from Agúndez & Wakelam. However, in some cases, large opacity and low signal to noise effects allow only upper or lower limits to be derived, respectively.

  10. CHEMICAL COMPOSITION AND ANTI-INFLAMMATORY ACTIVITY OF Roldana platanifolia

    Directory of Open Access Journals (Sweden)

    Amira Arciniegas

    2015-11-01

    Full Text Available The chemical study of Roldana platanifolia led to the isolation of β-caryophyllene, five eremophilanolides, chlorogenic acid, and a mixture of β-sitosterol-stigmasterol, β-sitosteryl glucopyranoside, and sucrose. The anti-inflammatory activities of the extracts and isolated products were tested using the 12-O-tetradecanoylphorbol-13-acetate (TPA model of induced acute inflammation. The acetone and methanol extracts showed dose dependent activities (ID50 0.21 and 0.32 mg/ear, respectively, while none of the isolated compounds exhibited relevant edema inhibition. The active extracts were also evaluated with the myeloperoxidase assay technique (MPO to determine their ability to prevent neutrophil infiltration. Results showed that the anti-inflammatory activity was related to the compound’s ability to inhibit pro-inflammatory mediators such as neutrophils.

  11. Can water quality of tubewells be assessed without chemical testing?

    Science.gov (United States)

    Hoque, Mohammad A.; Butler, Adrian P.

    2016-04-01

    Arsenic is one of the major pollutants found in aquifers on a global scale. The screening of tubewells for arsenic has helped many people to avoid drinking from highly polluted wells in the Bengal Delta (West Bengal and Bangladesh). However, there are still many millions of tubewells in Bangladesh yet to be tested, and a substantial proportion of these are likely to contain excessive arsenic. Due to the level of poverty and lack of infrastructure, it is unlikely that the rest of the tubewells will be tested quickly. However, water quality assessment without needing a chemical testing may be helpful in this case. Studies have found that qualitative factors, such as staining in the tubewell basement and/or on utensils, can indicate subsurface geology and water quality. The science behind this staining is well established, red staining is associated with iron reduction leading to release of arsenic whilst black staining is associated with manganese reduction (any release of arsenic due to manganese reduction is sorbed back on the, yet to be reduced, iron), whereas mixed staining may indicate overlapping manganese and iron reduction at the tubewell screen. Reduction is not uniform everywhere and hence chemical water quality including dissolved arsenic varies from place to place. This is why coupling existing tubewell arsenic information with user derived staining data could be useful in predicting the arsenic status at a particular site. Using well location, depth, along with colour of staining, an assessment of both good (nutrients) and bad (toxins and pathogens) substances in the tubewell could be provided. Social-network technology, combined with increasing use of smartphones, provides a powerful opportunity for both sharing and providing feedback to the user. Here we outline how a simple digital application can couple the reception both qualitative and quantitative tubewell data into a centralised interactive database and provide manipulated feedback to an

  12. A facile TiO{sub 2}/PVDF composite membrane synthesis and their application in water purification

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Wei, E-mail: wei.zhang@unisa.edu.au; Zhang, Yiming; Fan, Rong; Lewis, Rosmala [University of South Australia, Centre for Water Management and Reuse (Australia)

    2016-01-15

    In this work, we have demonstrated a facile wet chemical method to synthesise TiO{sub 2}/PVDF composite membranes as alternative water purification method to traditional polymer-based membrane. For the first time, hydrothermally grown TiO{sub 2} nanofibers under alkali conditions were successfully inserted into PVDF membranes matrix. The structure, permeability and anti-fouling performance of as-prepared PVDF/TiO{sub 2} composite membranes were studied systematically. The TiO{sub 2}/PVDF composite membranes prepared in this work promise great potential uses in water purification applications as microfiltration membranes due to its excellent physical/chemical resistance, anti-fouling and mechanical properties.

  13. Chemical Gradients in Crud on Boiling Water Reactor Fuel Elements

    Energy Technology Data Exchange (ETDEWEB)

    D. L. Porter; D. E. Janney

    2007-04-01

    Crud (radioactive corrosion products formed inside nuclear reactors is a major problem in commercial power-producing nuclear reactors. Although there are numerous studies of simulated (non-radioactive) crud, characteristics of crud from actual reactors are rarely studied. This study reports scanning electron microscope (SEM) studies of fragments of crud from a commercially operating boiling water reactor. Chemical analyses in the SEM indicated that the crud closest to the outer surfaces of the fuel pins in some areas had Fe:Zn ratios close to 2:1, which decreased away from the fuel pin in some of the fragments. In combination with transmission electron microsope analyses (published elsewhere), these results suggest that the innermost layer of crud in some areas may consist of franklinite (ZnFe2O4, also called zinc spinel), while outer layers in these areas may be predominantly iron oxides.

  14. Micro-dynamic Behavior and Self-adjusting Water Transmit Mechanism of Water-transferring Composite

    Institute of Scientific and Technical Information of China (English)

    ZHANG Zengzhi; XU Hongmei; MA Dandan; ZHAO Jin

    2011-01-01

    Constructional and micro-dynamic process of the water-transferring composite was analyzed.This composite can transmit water to soil with a self-adjustable speed to ensure the survival of seedlings in arid and semi-arid regions when it is embedded in soil around the roots of the seedlings.It is obtained from natural plant fiber coated with a colloid made by mixing a certain proportion of polyacrylamide and montmorillonite.The rules of water being transmitted to soil by the coating under different condition were tested by M-30 quick moisture measure instrument.The process of water-desorption of the coating material was investigated by a Perkin Elmer Diamond S Ⅱ thermal multi-analyzer.Moreover,the micro-dynamic behavior was detected by a FEIQuanta 2000 environment scanning electron microscope.The results demonstrate that montmorillonite has lower water-desorption energy barrier than polyacrylamide and can lose water more easily.montmorillonite particles bridge up to be the main water-transmit material at low water potential (when the soil relatively dry or when the temperature is high),and they break bridge at high water potential while the polyacrylamide acts as the main water-transmit material.

  15. The triple isotopic composition of oxygen in leaf water

    Science.gov (United States)

    Landais, A.; Barkan, E.; Yakir, D.; Luz, B.

    2006-08-01

    The isotopic composition of atmospheric O 2 depends on the rates of oxygen cycling in photosynthesis, respiration, photochemical reactions in the stratosphere and on δ17O and δ18O of ocean and leaf water. While most of the factors affecting δ17O and δ18O of air O 2 have been studied extensively in recent years, δ17O of leaf water—the substrate for all terrestrial photosynthesis—remained unknown. In order to understand the isotopic composition of atmospheric O 2 at present and in fossil air in ice cores, we studied leaf water in field experiments in Israel and in a European survey. We measured the difference in δ17O and δ18O between stem and leaf water, which is the result of isotope enrichment during transpiration. We calculated the slopes of the lines linking the isotopic compositions of stem and leaf water. The obtained slopes in ln( δ17O + 1) vs. ln( δ18O + 1) plots are characterized by very high precision (˜0.001) despite of relatively large differences between duplicates in both δ17O and δ18O (0.02-0.05‰). This is so because the errors in δ18O and δ17O are mass-dependent. The slope of the leaf transpiration process varied between 0.5111 ± 0.0013 and 0.5204 ± 0.0005, which is considerably smaller than the slope linking liquid water and vapor at equilibrium (0.529). We further found that the slope of the transpiration process decreases with atmospheric relative humidity ( h) as 0.522-0.008 × h, for h in the range 0.3-1. This slope is neither influenced by the plant species, nor by the environmental conditions where plants grow nor does it show strong variations along long leaves.

  16. The CBS spectra investigation as method of the PN chemical composition analysis

    Science.gov (United States)

    Shimanskaya, N. N.; Bikmaev, I. F.; Shimansky, V. V.; Sakhibullin, N. A.; Zhuchkov, R. Ya.; Shigapov, R. R.

    2007-10-01

    We report the results of the investigations of chemical composition of close binaries which had gone through the stage of common envelope and which are the remnants of planetary nebular cores. High resolution spectra for different phases of orbital period of V471 Tau were taken by RTT-150 telescope and were investigated by the modified SYNTH program. The spectra show noticeable variability with an appearance of emission components dependent of the orbital period phase. For chemical composition determination, the "solar" oscillator strengths of 700 lines were determined. It was found that the chemical content of V471 Tau is a composite one and is characterized by excess of α-process elements in the contrast to small underabundance of iron-peak elements. An estimation of different element abundances in the star allows to determine their contents in planetary nebular phase.

  17. Indirect Determination of Chemical Composition and Fuel Characteristics of Solid Waste

    DEFF Research Database (Denmark)

    Riber, Christian; Christensen, Thomas Højlund

    Determination of chemical composition of solid waste can be performed directly or indirectly by analysis of combustion products