Highly Polluted Wastewaters Treatment by Improved Dissolved Air Flotation Technology

Science.gov (United States)

Moga, I. C.; Covaliu, C. I.; Matache, M. G.; Doroftei, B. I.

2017-06-01

Numerous investigations are oriented towards the development of new wastewater treatment technologies, having high efficiencies for removing even low concentrations of pollutants found in water. These efforts were determined by the destroyer impact of the pollutants to the environment and human’s health. For this reason this paper presents our study concerning an improved dissolved air flotation technology for wastewater treatment. There is described a dissolved air flotation (DAF) installation composed by two equipments: pressurized capsule and lamellar settling. Also, there are presented some advantages of using nanoparticles as flotation collectors.

Experimental and numerical study of wastewater pollution in Yuhui channel, Jiashan city

Science.gov (United States)

Fu, Lei; Peng, Zhenhua; You, Aiju

2018-02-01

Due to the development of economics and society in China, the huge amount of wastewater becomes a serious problem in most of the Chinese cities. Therefore, the construction of wastewater treatment plant draws much more attentions than before. The discharge from the wastewater treatment plant is then considered as a point source in most of the important rivers and channels in China. In this study, a typical wastewater treatment plant extension project is introduced as a case study, a filed monitoring experiment is designed and executed to observe required data, then, a two-dimensional model is estabilished to simulate the water quality downsteam of the wastewater treatment plant, CODCr is considered as a typical pollutant during the simulation. The simulation results indicate that different discharge conditions will lead to different CODCr concentration downstream of the wastewater treatment plant, and an emergency plan should be prepared to minimize the risk of the pollution in the channel under unusual and accident conditions.

Wastewater treatment processes for the removal of emerging organic pollutants

Directory of Open Access Journals (Sweden)

Ainhoa Rubio Clemente

2013-12-01

Full Text Available Emerging organic pollutants form a very heterogeneous group of substances that have negative effects on aquatic organisms, so they should be removed from the environment. Unfortunately, conventional processes in wastewater treatment plants, especially biological ones, are inefficient in the degradation of these substances. It is therefore necessary to evaluate and optimize the effectiveness of the treatments, including advanced oxidation and membrane filtration processes. However, both techniques have drawbacks that may limit their stand-alone application, so it is proposed that the best solution may be to combine these technologies with biological processes to treat wastewater contaminated with emerging organic pollutants.

Micro-pollutant removal from wastewater treatment plant effluent by activated carbon

NARCIS (Netherlands)

Hu, J.

2016-01-01

In the recent years, the removal of micro-pollutants from treated wastewater has been highly advocated throughout Europe and the rest of the world. The relevant regulations and the suitable techniques have been proposed accordingly, which promoted the innovation of the conventional wastewater

Pollutant removal in subsurface wastewater infiltration systems with ...

African Journals Online (AJOL)

Ninety-five per cent of decentralized wastewater around the ... Organic pollutant and nitrogen removal performance of SWISs ... a rubber hose with flow rate control valves. .... the limitation of oxygen became more obvious, and resulted in. 4. 3.

Satellite Remote Sensing Detection of Coastal Pollution in Southern California: Stormwater Runoff and Wastewater Plumes

Science.gov (United States)

Trinh, R. C.; Holt, B.; Gierach, M.

2016-02-01

Coastal pollution poses a major health and environmental hazard, not only for beach goers and coastal communities but for marine organisms as well. Stormwater runoff is the largest source of environmental pollution in coastal waters of the Southern California Bight (SCB) and is of great concern in increasingly urbanized areas. Buoyant wastewater plumes also pose a marine environmental risk. In this study we provide a comprehensive overview of satellite remote sensing capabilities in detecting buoyant coastal pollutants in the form of stormwater runoff and wastewater effluent. The SCB is the final destination of four major urban rivers that act as channels for runoff and pollution during and after rainstorms. We analyzed and compared sea surface roughness data from various Synthetic Aperture Radar (SAR) instruments to ocean color data from the Moderate Imaging System (MODIS) sensor on board the Aqua satellite and correlated the results with existing environmental data in order to create a climatology of naturally occurring stormwater plumes in coastal waters after rain events, from 1992 to 2014 from four major rivers in the area. Heat maps of the primary extent of stormwater plumes were constructed to specify areas that may be subject to the greatest risk of coastal contamination. In conjunction with our efforts to monitor coastal pollution and validate the abilities of satellite remote sensing, a recent Fall 2015 wastewater diversion from the City of Los Angeles Hyperion Treatment Plant (HTP) provided the opportunity to apply these remote sensing methodologies of plume detection to wastewater. During maintenance of their 5-mile long outfall pipe, wastewater is diverted to a shorter outfall pipe that terminates 1-mile offshore and in shallower waters. Sea surface temperature (SST), chlorophyll-a (chl-a) fluorescence, remote sensing reflectance and particulate backscatter signatures were analyzed from MODIS. Terra-ASTER and Landsat-8 thermal infrared data were also

Effects of domestic wastewater treated by anaerobic stabilization on soil pollution, plant nutrition, and cotton crop yield.

Science.gov (United States)

Uzen, Nese; Cetin, Oner; Unlu, Mustafa

2016-12-01

This study has aimed to determine the effects of treated wastewater on cotton yield and soil pollution in Southeastern Anatolia Region of Turkey during 2011 and 2012. The treated wastewater was provided from the reservoir operated as anaerobic stabilization. After treatment, suspended solids (28-60 mg/l), biological oxygen demand (29-30 mg/l), and chemical oxygen demand (71-112 mg/l) decreased significantly compared to those in the wastewater. There was no heavy metal pollution in the water used. There were no significant amounts of coliform bacteria, fecal coliform, and Escherichia coli compared to untreated wastewater. The cottonseed yield (31.8 g/plant) in the tanks where no commercial fertilizers were applied was considerably higher compared to the yield (17.2 g/plant) in the fertilized tanks where a common nitrogenous fertilizer was utilized. There were no significant differences between the values of soil pH. Soil electrical conductivity (EC) after the experiment increased from 0.8-1.0 to 0.9-1.8 dS/m. Heavy metal pollution did not occur in the soil and plants, because there were no heavy metals in the treated wastewater. It can be concluded that treated domestic wastewater could be used to grow in a controlled manner crops, such as cotton, that would not be used directly as human nutrients.

Removal of Organic Pollutants from Municipal Wastewater by Applying High-Rate Algal Pond in Addis Ababa, Ethiopia

Science.gov (United States)

Alemu, Keneni; Assefa, Berhanu; Kifle, Demeke; Kloos, Helmut

2018-05-01

The discharge of inadequately treated municipal wastewater has aggravated the pollution load in developing countries including Ethiopia. Conventional wastewater treatment methods that require high capital and operational costs are not affordable for many developing nations, including Ethiopia. This study aimed to investigate the performance of two high-rate algal ponds (HRAPs) in organic pollutant removal from primary settled municipal wastewater under highland tropical climate conditions in Addis Ababa. The experiment was done for 2 months at hydraulic retention times (HRTs) ranging from 2 to 8 days using an organic loading rates ranging 333-65 kg {BOD}5 /ha/day using two HRAPs, 250 and 300 mm deep, respectively. In this experiment, Chlorella sp., Chlamydomonas sp., and Scenedesmus sp., the class of Chlorophyceae, were identified as the dominant species. Chlorophyll-a production was higher in the shallower ponds (250 mm) throughout the course of the study, whereas the deeper HRAP (300 mm) showed better dissolved oxygen production. The maximum COD and {BOD}5 removal of 78.03 and 81.8% was achieved at a 6-day HRT operation in the 250-mm-deep HRAP. Therefore, the 300-mm-deep HRAP is promising for scaling up organic pollutant removal from municipal wastewater at a daily average organic loading rate of 109.3 kg {BOD}5 /ha/day and a 6-day HRT. We conclude that the removal of organic pollutants in HRAP can be controlled by pond depth, organic loading rate, and HRT.

Estimating the global burden of thalassogenic diseases: human infectious diseases caused by wastewater pollution of the marine environment.

Science.gov (United States)

Shuval, Hillel

2003-06-01

This paper presents a preliminary attempt at obtaining an order-of-magnitude estimate of the global burden of disease (GBD) of human infectious diseases associated with swimming/bathing in coastal waters polluted by wastewater, and eating raw or lightly steamed filter-feeding shellfish harvested from such waters. Such diseases will be termed thalassogenic--caused by the sea. Until recently these human health effects have been viewed primarily as local phenomena, not generally included in the world agenda of marine scientists dealing with global marine pollution problems. The massive global scale of the problem can be visualized when one considers that the wastewater and human body wastes of a significant portion of the world's population who reside along the coastline or in the vicinity of the sea are discharged daily, directly or indirectly, into the marine coastal waters, much of it with little or no treatment. Every cubic metre of raw domestic wastewater discharged into the sea can carry millions of infectious doses of pathogenic microorganisms. It is estimated that globally, foreign and local tourists together spend some 2 billion man-days annually at coastal recreational resorts and many are often exposed there to coastal waters polluted by wastewater. Annually some 800 million meals of potentially contaminated filter-feeding shellfish/bivalves and other sea foods, harvested in polluted waters are consumed, much of it raw or lightly steamed. A number of scientific studies have shown that swimmers swallow significant amounts of polluted seawater and can become ill with gastrointestinal and respiratory diseases from the pathogens they ingest. Based on risk assessments from the World Health Organization (WHO) and academic research sources the present study has made an estimate that globally, each year, there are in excess of 120 million cases of gastrointestinal disease and in excess of 50 million cases of more severe respiratory diseases caused by swimming and

Study on Relationship between Seasonal Temperatures and Municipal Wastewater Pollutant Concentration and Removal Rate

Directory of Open Access Journals (Sweden)

Yuan Shaoxiong

2016-01-01

Full Text Available In this study, the temperatures, pollutant concentrations and other indicators of municipal wastewater influent and effluent were tested for 7 months in 6 constructed wetland microcosms; the hydraulic retention time is 2 days. The results indicated that for both influent and effluent, there was a highly significant negative correlation (P<0.01 between the temperature and the pollutant concentrations, there was a significant difference (P<0.05 between seasonal temperatures, and the pollutant concentrations in summer and autumn were significantly different from those in winter (P<0.05. Furthermore, a regression analysis of pollutant concentration (y based on changes in water temperature (x in different seasons was performed. The analysis revealed that the relationship has the form ‘y = a -bx + cx2’, that under certain circumstances, pollutant concentrations can be calculated based on the temperature, and that the concentrations of NH4-N, Total Phosphorus (TP and Soluble Reactive Phosphorus (SRP had a significantly negative correlation with their removal rate (P < 0.01. However, seasonal temperature clearly did not have a direct impact on the pollutant concentration, and some studies have indicated that the different manners in which urban residents use water as the temperature changes may be the real reason that the pollutant concentrations of municipal wastewater vary with seasonal temperature. Furthermore, when designing and operating constructed wetlands, the impact of the changes in pollutant concentrations generated by seasonal temperature should be fully considered, dilution and other means should be taken to ensure purification.

The supply and demand for pollution control: Evidence from wastewater treatment

Science.gov (United States)

McConnell, V.D.; Schwarz, G.E.

1992-01-01

This paper analyzes the determination of pollution control from wastewater treatment plants as an economic decision facing local or regional regulators. Pollution control is measured by plant design effluent concentration levels and is fully endogenous in a supply- and-demand model of treatment choice. On the supply side, plant costs are a function of the design treatment level of the plant, and on the demand side, treatment level is a function of both the costs of control and the regional or regulatory preferences for control. We find evidence that the economic model of effluent choice by local regulators has a good deal of explanatory power. We find evidence that wastewater treatment plant removal of biological oxygen demand (BOD) is sensitive to many local factors including the size of the treatment plant, the flow rate of the receiving water, the population density of the surrounding area, regional growth, state sensitivity to environmental issues, state income, and the extent to which the damages from pollution fall on other states. We find strong evidence that regulators are sensitive to capital costs in determining the design level of BOD effluent reduction at a plant. Thus, proposed reductions in federal subsidies for wastewater treatment plant construction are likely to have significant adverse effects on water quality. ?? 1992.

Temporal changes in the benthos along a pollution gradient: Discriminating the effects of natural phenomena from sewage-industrial wastewater effects

International Nuclear Information System (INIS)

Ferraro, S.P.; Swartz, R.C.; Cole, F.A.; Shults, D.W.

1991-01-01

As pollution from the Los Angeles County Sanitation Districts (LACSD) outfalls decreased between 1980 and 1983, the macrobenthic community partially recovered and surficial (0-2 cm deep) sediment contamination and toxicity decreased at 60 m water depth along a pollution gradient from the outfalls. Pollution from the LACSD outfalls continued to decrease but macrobenthic conditions and surficial sediment quality deteriorated 1 km, was unchanged 3 km, and improved 5-15 km from the LACSD outfalls between 1983 and 1986. The net effect of natural phenomena is indicated when ecosystem changes occur in the opposite direction from that expected under prevailing pollution conditions. The authors data suggest that the net effect of natural phenomena (e.g. winter storms, El Nino) on the benthos was greater than LACSD wastewater effects 1 km, about equal to LACSD wastewater effects 3 km, and less than the LACSD wastewater effects 5-15 km from the outfalls at the LACSD 1983-86 mass emission rate. Since natural phenomena may have an effect on the benthos = or > 3 years of LACSD wastewater effects, short-term benthic changes must be interpreted cautiously at the study site

Generation of synthetic influent data for performing (micro) pollutant wastewater treatment modelling studies

DEFF Research Database (Denmark)

Snip, L. J. P.; Aymerich, I.; Flores-Alsina, X.

2015-01-01

The use of Activated Sludge Models (ASM) (Henze et al., 2000) is constantly growing and both industry and academia are increasingly applying these tools when performing wastewater treatment plant (WWTP) engineering studies. Besides describing the behaviour of traditional pollutants such as organic...... carbon (C), nitrogen(N) and phosphorus(P), ASM models have been successfully upgraded to predict the fate of different types of micro-pollutants (Benedetti et al., 2013). Indeed, the potential adverse effects of micro-pollutants in aquatic environments have been an object of intensive research during...... (Gernaey et al., 2011). This is an important point since realistic data representing the influent wastewater dynamics are crucial to accomplish any WWTP modelling project (Rieger et al., 2012). For this reason, model-based influent generators/synthetic data are an alternative that has recently gained...

Environmental pollution and health hazards from distillery wastewater and treatment approaches to combat the environmental threats: A review.

Science.gov (United States)

Chowdhary, Pankaj; Raj, Abhay; Bharagava, Ram Naresh

2018-03-01

Distillery industries are the key contributor to the world's economy, but these are also one of the major sources of environmental pollution due to the discharge of a huge volume of dark colored wastewater. This dark colored wastewater contains very high biological oxygen demand, chemical oxygen demand, total solids, sulfate, phosphate, phenolics and various toxic metals. Distillery wastewater also contains a mixture of organic and inorganic pollutants such as melanoidins, di-n-octyl phthalate, di-butyl phthalate, benzenepropanoic acid and 2-hydroxysocaproic acid and toxic metals, which are well reported as genotoxic, carcinogenic, mutagenic and endocrine disrupting in nature. In aquatic resources, it causes serious environmental problems by reducing the penetration power of sunlight, photosynthetic activities and dissolved oxygen content. On other hand, in agricultural land, it causes inhibition of seed germination and depletion of vegetation by reducing the soil alkalinity and manganese availability, if discharged without adequate treatment. Thus, this review article provides a comprehensive knowledge on the distillery wastewater pollutants, various techniques used for their analysis as well as its toxicological effects on environments, human and animal health. In addition, various physico-chemicals, biological as well as emerging treatment methods have been also discussed for the protection of environment, human and animal health. Copyright © 2017 Elsevier Ltd. All rights reserved.

Pollution abatement with peat onsite wastewater treatment systems

Energy Technology Data Exchange (ETDEWEB)

Brooks, J L [University of Maine, Orano, ME (United States). Dept. of Civil Engineering

1994-02-01

The purpose of onsite wastewater treatment is to provide economical removal of dissolved nutrients, pathogens and other contaminates from septic tank effluent to avoid the pollution of groundwater or creation of other health hazards. The effective use of conventional soil adsorption systems is limited by a number of factors including site characteristics, soil type and condition, and the proximity of the system to surface waters or a source of potable water. On adverse sites, where the use of conventional subsurface soil adsorption systems does not provide acceptable levels of treatment, Sphagnum peat may be used as an economical method of onsite wastewater treatment. The peat system, when properly designed and constructed, is relatively simple to install, requires minimal energy and maintenance, and provides a high quality effluent without additional disinfection. 19 refs.

Removal of Oil and Grease as Emerging Pollutants of Concern (EPC in Wastewater Stream

Directory of Open Access Journals (Sweden)

Alade Abass O

2011-12-01

Full Text Available Wastewater characteristics, which depend on wastewater source, are increasingly becoming more toxic in recent times. The concentrations of oil and grease in wastewater streams have been observed to increase in wastewater stream with increasing adverse effects on the ecology. This results from the increasing use of oil and grease in high-demanded oil-processed foods, establishment and expansion of oil mills and refineries worldwide, as well as indiscriminate discharge of oil and grease into the water drains, domestically and industrially. This study reports the applications, efficiencies and challenges of the wastewater treatment techniques currently employed in the removal of oil and grease from the industrial wastewater and municipal water stream. The results shows that the concentrations of oil and grease injected into the ecosystem are of higher environmental impact and this needs to be given the desired attention. The desired development for effective removal of oil and grease as emerging pollutants of concern (EPC in wastewater stream are thus proposed. ABSTRAK: Ciri-ciri air sisa, bergantung kepada punca air sisa tersebut, menjadi semakin toksik akhir-akhir ini. Kepekatan minyak dan gris dalam air sisa anak sungai dilihat makin bertambah dalam air sisa anak sungai dengan bertambahnya kesan negatif ke atas ekologi. Ini disebabkan oleh peningkatan penggunaan minyak dan gris dalam makanan berproses yang tinggi permintaannya, penubuhan dan perkembangan kilang pertroleum dan loji penapisan di seluruh dunia. Minyak dan gris juga dibuang sewenang-wenangnya ke dalam parit air, dari kalangan domestik dan industry. Kajian ini membentangkan tentang aplikasi, keberkesanan dan teknik cabaran rawatan air buangan yang kini digunakan dalam pembuangan minyak dan gris dari air sisa industry dan air sungai perbandaran. Keputusan menunjukkan kepekatan minyak dan gris yang wujud dibuang ke dalam ekosistem mempunyai impak yang lebih tinggi terhadap persekitaran

Analysis of chemical reaction kinetics of depredating organic pollutants from secondary effluent of wastewater treatment plant in constructed wetlands.

Science.gov (United States)

Wang, Hao; Jiang, Dengling; Yang, Yong; Cao, Guoping

2013-01-01

Four subsurface constructed wetlands were built to treat the secondary effluent of a wastewater treatment plant in Tangshan, China. The chemical pollutant indexes of chemical oxygen demand (COD) were analyzed to evaluate the removal efficiency of organic pollutants from the secondary effluent of the wastewater treatment plant. In all cases, the subsurface constructed wetlands were efficient in treating organic pollutants. Under the same hydraulic loading condition, the horizontal flow wetlands exhibited better efficiency of COD removal than vertical flow wetlands: the removal rates in horizontal flow wetlands could be maintained at 68.4 ± 2.42% to 92.2 ± 1.61%, compared with 63.8 ± 1.19% to 85.0 ± 1.25% in the vertical flow wetlands. Meanwhile, the chemical reaction kinetics of organic pollutants was analyzed, and the results showed that the degradation courses of the four subsurface wetlands all corresponded with the first order reaction kinetics to a large extent.

Investigation of Wastewater Pollution at Clan Jetty, Penang

Directory of Open Access Journals (Sweden)

Razak Fazilah Md

2014-01-01

Full Text Available This study aims to determine the level of wastewater pollution at Clan Jetty, Penang. 20 locations were chosen for water sampling around the jetties. Experiments were conducted to investigate the parameters, namely, temperature at each point, Chemical Oxygen Demand (COD, Biochemical Oxygen Demand (BOD, pH, Dissolved Oxygen (DO, the presence of Coliform and E. coli, Nitrate Nitrogen, Ammonical Nitrogen, Suspended Solids, Oil and Grease as well as Total Phosphorus (TP. Laboratory results showed that Point 1A was the most polluted location compared to other sampling points. The highest COD recording was 5824 mg/L at Point 1A and the lowest amount of 103 mg/L was recorded at Point 4. This study demonstrates that the absence of a sewerage system contributes to marine pollution around the jetties. Thus, a sewerage system is the best solution to improve water quality around the jetties in the future.

Comparison of various advanced oxidation processes used in remediation of industrial wastewater laden with recalcitrant pollutants

Science.gov (United States)

Krishnan, S.; Rawindran, H.; Sinnathambi, C. M.; Lim, J. W.

2017-06-01

Due to the scarcity of water, it has become a necessity to improve the quality of wastewater that is discharged into the environment. Conventional wastewater treatment can be either a physical, chemical, and/or biological processes, or in some cases a combination of these operations. The main purpose of wastewater treatment is to eliminate nutrients, solids, and organic compounds from effluents. Current wastewater treatment technologies are deemed ineffective in the complete removal of pollutants, particularly organic matter. In many cases, these organic compounds are resistant to conventional treatment methods, thus creating the necessity for tertiary treatment. Advanced oxidation process (AOP), constitutes as a promising treatment technology for the management of wastewater. AOPs are characterised by a common chemical feature, where they utilize the highly reactive hydroxyl radicals for achieving complete mineralization of the organic pollutants into carbon dioxide and water. This paper delineates advanced oxidation processes currently used for the remediation of water and wastewater. It also provides the cost estimation of installing and running an AOP system. The costs are separated into three categories: capital, operational, and operating & maintenance.

Application of heterogeneous fenton oxidation for the removal of pollutants from wastewater

OpenAIRE

Rodríguez Rey, Daniel

2014-01-01

During the last century there has been a growing concern about water pollution throughout the developed countries. Water has a major impact on the environment as it is used by all living being. This leads to leave the wastewater used with an acceptable quality for its next destination. Fortunately, national and international water quality agreements and laws have pushed development of wastewater treatment technology that nowadays allows us to return the used water to the environment in goo...

Characterization and study of correlations among major pollution parameters in textile wastewater

International Nuclear Information System (INIS)

Hyder, S.; Bari, A.

2011-01-01

Wastewater characterization is an integral part of treatment and management strategies for industrial effluents. This paper outlines the results of detailed wastewater characterization studies conducted for a textile mill in Lahore, Punjab. The results of this study demonstrated that the composition of textile wastewater could change continuously due to inherent nature of textile operations. In general, textile wastewater was high in temperature and alkaline in nature. It was highly polluted in terms of solids and organic content. Most of the portion of solids and organic load was in the soluble form. On the basis of mean values, temperature, pH, TDS (Total Dissolved Solids), BOD (Biochemical Oxygen Demand) and COD (Chemical Oxygen Demand) were above the limits set by NEQS (National Environmental Quality Standards) while chlorides and sulfates were below the limits set by NEQS. Prior neutralization of wastewater with an acid and addition of phosphorus and nitrogen is imperative for its effective treatment. (author)

Removal of organic pollutants from industrial wastewater by applying photo-Fenton oxidation technology

OpenAIRE

Ebrahiem E. Ebrahiem; Mohammednoor N. Al-Maghrabi; Ahmed R. Mobarki

2017-01-01

The general strategy of this study was based on evaluation of the possibility of applying advanced photo-oxidation technique (Fenton oxidation process) for removal of the residuals organic pollutants present in cosmetic wastewater. The different parameters that affect the chemical oxidation process for dyes in their aqueous solutions were studied by using Fenton’s reaction. These parameters are pH, hydrogen peroxide (H2O2) dose, ferrous sulfate (FeSO4·7H2O) dose, Initial dye concentration, an...

Efficiency of WWTP to remove emerging pollutants in wastewater

Science.gov (United States)

Carmona, Eric; Llopis, Agustín; Andreu, Vicente; Picó, Yolanda

2016-04-01

of Economy and Competitiveness through the project CGL2011-29703-C02-02. References 1. Shraim, A., et al., Analysis of some pharmaceuticals in municipal wastewater of Almadinah Almunawarah. Arabian Journal of Chemistry, (0). 2. Andrés-Costa, M.J., et al., Occurrence and removal of drugs of abuse in Wastewater Treatment Plants of Valencia (Spain). Environmental Pollution, 2014. 194(0): p. 152-162.

Wastewater Treatment from Batik Industries Using TiO2 Nanoparticles

Science.gov (United States)

Arifan, Fahmi; Nugraheni, FS; Rama Devara, Hafiz; Lianandya, Niken Elsa

2018-02-01

Batik is cultural patterned fabric, and the this industries produce wastewater that can pollute the aquatic environment. Besides dyes, batik wastewater also contains synthetic compounds that are hard degraded, such as heavy metals, suspended solids, or organic compounds. In this study, photocatalitic membrane TiO2 coated plastic sheets have been used to degrade batik wastewater under solar exposure. A total of 8 pieces of catalyst sheets are added on 1000 ml of the waste, and managed to degrade 50.41% of the initial concentration during 5-days irradiation. In this study, several parameters of the water quality such as chemical oxygen demand (COD), biological oxygen demand (BOD), and total suspensed solids (TSS) of the wastewater were observed to be decreasing during photodegradation process. The catalyst sheet also is stable to be used repeatedly in wastewater treatment.

Removal of organic pollutants from industrial wastewater by applying photo-Fenton oxidation technology

Directory of Open Access Journals (Sweden)

Ebrahiem E. Ebrahiem

2017-05-01

Full Text Available The general strategy of this study was based on evaluation of the possibility of applying advanced photo-oxidation technique (Fenton oxidation process for removal of the residuals organic pollutants present in cosmetic wastewater. The different parameters that affect the chemical oxidation process for dyes in their aqueous solutions were studied by using Fenton’s reaction. These parameters are pH, hydrogen peroxide (H2O2 dose, ferrous sulfate (FeSO4·7H2O dose, Initial dye concentration, and time. The optimum conditions were found to be: pH 3, the dose of 1 ml/l H2O2 and 0.75 g/l for Fe(II and Fe(III and reaction time 40 min. Finally, chemical oxygen demands (COD, before and after oxidation process was measured to ensure the entire destruction of organic dyes during their removal from wastewater. The experimental results show that Fenton’s oxidation process successfully achieved very good removal efficiency over 95%.

Adsorption of organic pollutants from coking and papermaking wastewaters by bottom ash.

Science.gov (United States)

Sun, Wei-ling; Qu, Yan-zhi; Yu, Qing; Ni, Jin-ren

2008-06-15

Bottom ash, a power plant waste, was used to remove the organic pollutants in coking wastewater and papermaking wastewater. Particular attention was paid on the effect of bottom ash particle size and dosage on the removal of chemical oxygen demand (COD). UV-vis spectra, fluorescence excitation-emission matrix (FEEM) spectra, Fourier transform infrared (FTIR) spectra, and scanning electron microscopic (SEM) photographs were investigated to characterize the wastewaters and bottom ash. The results show that the COD removal efficiencies increase with decreasing particle sizes of bottom ash, and the COD removal efficiency for coking wastewater is much higher than that for papermaking wastewater due to its high percentage of particle organic carbon (POC). Different trends of COD removal efficiency with bottom ash dosage are also observed for coking and papermaking wastewaters because of their various POC concentrations. Significant variations are observed in the FEEM spectra of wastewaters after treatment by bottom ash. New excitation-emission peaks are found in FEEM spectra, and the fluorescence intensities of the peaks decrease. A new transmittance band in the region of 1400-1420 cm(-1) is observed in FTIR spectra of bottom ash after adsorption. The SEM photographs reveal that the surface of bottom ash particles varies evidently after adsorption.

Adsorption of organic pollutants from coking and papermaking wastewaters by bottom ash

International Nuclear Information System (INIS)

Sun Weiling; Qu Yanzhi; Yu Qing; Ni Jinren

2008-01-01

Bottom ash, a power plant waste, was used to remove the organic pollutants in coking wastewater and papermaking wastewater. Particular attention was paid on the effect of bottom ash particle size and dosage on the removal of chemical oxygen demand (COD). UV-vis spectra, fluorescence excitation-emission matrix (FEEM) spectra, Fourier transform infrared (FTIR) spectra, and scanning electron microscopic (SEM) photographs were investigated to characterize the wastewaters and bottom ash. The results show that the COD removal efficiencies increase with decreasing particle sizes of bottom ash, and the COD removal efficiency for coking wastewater is much higher than that for papermaking wastewater due to its high percentage of particle organic carbon (POC). Different trends of COD removal efficiency with bottom ash dosage are also observed for coking and papermaking wastewaters because of their various POC concentrations. Significant variations are observed in the FEEM spectra of wastewaters after treatment by bottom ash. New excitation-emission peaks are found in FEEM spectra, and the fluorescence intensities of the peaks decrease. A new transmittance band in the region of 1400-1420 cm -1 is observed in FTIR spectra of bottom ash after adsorption. The SEM photographs reveal that the surface of bottom ash particles varies evidently after adsorption

Enhancing mercury removal across air pollution control devices for coal-fired power plants by desulfurization wastewater evaporation.

Science.gov (United States)

Bin, Hu; Yang, Yi; Cai, Liang; Yang, Linjun; Roszak, Szczepan

2017-10-09

Desulfurization wastewater evaporation technology is used to enhance the removal of gaseous mercury (Hg) in conventional air pollution control devices (APCDs) for coal-fired power plants. Studies have affirmed that gaseous Hg is oxidized and removed by selective catalytic reduction (SCR), an electrostatic precipitator (ESP) and wet flue gas desulfurization (WFGD) in a coal-fired thermal experiment platform with WFGD wastewater evaporation. Effects of desulfurization wastewater evaporation position, evaporation temperature and chlorine ion concentration on Hg oxidation were studied as well. The Hg 0 oxidation efficiency was increased ranging from 30% to 60%, and the gaseous Hg removal efficiency was 62.16% in APCDs when wastewater evaporated before SCR. However, the Hg 0 oxidation efficiency was 18.99% and the gaseous Hg removal efficiency was 40.19% in APCDs when wastewater evaporated before ESP. The results show that WFGD wastewater evaporation before SCR is beneficial to improve the efficiency of Hg oxidized and removed in APCDs. Because Hg 2+ can be easily removed in ACPDs and WFGD wastewater in power plants is enriched with chlorine ions, this method realizes WFGD wastewater zero discharge and simultaneously enhances Hg removal in APCDs.

Pollutant removal-oriented yeast biomass production from high-organic-strength industrial wastewater: A review

International Nuclear Information System (INIS)

Yang, Min; Zheng, Shaokui

2014-01-01

Microbial single-cell-protein (SCP) production from high-organic-strength industrial wastewaters is considered an attractive method for both wastewater purification and resource utilization. In the last two decades, pollutant removal-oriented yeast SCP production processes, i.e., yeast treatment processes, have attracted a great deal of attention from a variety of research groups worldwide. Different from conventional SCP production processes, yeast treatment processes are characterized by higher pollutant removal rates, lower production costs, highly adaptive yeast isolates from nature, no excess nutrient supplements, and are performed under non-sterile conditions. Furthermore, yeast treatment processes are similar to bacteria-dominated conventional activated sludge processes, which offer more choices for yeast SCP production and industrial wastewater treatment. This review discusses why highly adaptive yeast species isolated from nature are used in the yeast treatment process rather than commercial SCP producers. It also describes the application of yeast treatment processes for treating high-carboxyhydrate, oil-rich and high-salinity industrial wastewater, focusing primarily on high-strength biodegradable organic substances, which usually account for the major fraction of biochemical oxygen demand. Also discussed is the biodegradation of xenobiotics, such as color (including dye and pigment) and toxic substances (including phenols, chlorophenols, polycyclic aromatic hydrocarbons, etc.), present in industrial wastewater. Based on molecular information of yeast community structures and their regulation in yeast treatment systems, we also discuss how to maintain efficient yeast species in yeast biomass and how to control bacterial and mold proliferation in yeast treatment systems. - Highlights: • Pollutant removal-oriented yeast SCP production processes offer more choices. • Highly adaptive yeast isolates replace commercial SCP producers. • Yeasts degrade

Urban wastewater treatment by using Ag/ZnO and Pt/TiO2 photocatalysts.

Science.gov (United States)

Murcia Mesa, Julie J; Arias Bolivar, Lizeth G; Sarmiento, Hugo Alfonso Rojas; Martínez, Elsa Giovanna Ávila; Páez, César Jaramillo; Lara, Mayra Anabel; Santos, José Antonio Navío; Del Carmen Hidalgo López, María

2018-03-02

In this study, the treatment of wastewater coming from a river highly polluted with domestic and industrial effluents was evaluated. For this purpose, series of photocatalysts obtained by ZnO and TiO 2 modification were evaluated. The effect of metal addition and Ti precursor (in the case of the titania series) over the physicochemical and photocatalytic properties of the materials obtained was also analyzed. The evaluation of the photocatalytic activity showed that semiconductor modification and precursor used in the materials synthesis are important factors influencing the physicochemical and therefore the photocatalytic properties of the materials obtained. The water samples analyzed in the present work were taken from a highly polluted river, and it was found that the effectiveness of the photocatalytic treatment increases when the reaction time increases and for both, wastewater samples and isolated Escherichia coli strain follow the next order Pt/TiO 2 < ZnO. It was also observed that biochemical and chemical demand oxygen and turbidity significantly decrease after treatment, thus indicating that photocatalysis is a non-selective technology, which can lead to recover wastewater containing different pollutants.

Body burden of pesticides and wastewater-derived pollutants on freshwater invertebrates: Method development and application in the Danube River

International Nuclear Information System (INIS)

Inostroza, Pedro A.; Wicht, Anna-Jorina; Huber, Thomas; Nagy, Claudia; Brack, Werner; Krauss, Martin

2016-01-01

While environmental risk assessment is typically based on toxicant concentrations in water and/or sediment, awareness is increasing that internal concentrations or body burdens are the key to understand adverse effects in organisms. In order to link environmental micropollutants as causes of observed effects, there is an increasing demand for methods to analyse these chemicals in organisms. Here, a multi-target screening method based on pulverised liquid extraction (PuLE) and a modified QuEChERS approach with an additional hexane phase was developed. It is capable to extract and quantify organic micropollutants of diverse chemical classes in freshwater invertebrates. The method was tested on gammarids from the Danube River (within the Joint Danube Survey 3) and target compounds were analysed by liquid chromatography-tandem mass spectrometry (LC-MS/MS). Furthermore, a non-target screening using high resolution-tandem mass spectrometry (LC-HRMS/MS) was conducted. A total of 17 pollutants were detected and/or quantified in gammarids at low concentrations. Pesticide concentrations ranged from 0.1 to 6.52 ng g −1 (wet weight), those of wastewater-derived pollutants from 0.1 to 2.83 ng g −1 (wet weight). The presence of wastewater-derived pollutants was prominent at all spots sampled. Using non-target screening, we could successfully identify several chlorinated compounds. These results demonstrate for the first time the presence of pesticides and wastewater-derived pollutants in invertebrates of the Danube River. - Highlights: • A method based on pulverised liquid extraction/QuEChERS for organic micropollutants in invertebrates was developed. • The method is applicable in assessing target environmental pollutants in invertebrates by LC-MS/MS. • The method allows for a nontarget screening of extracts by LC-HRMS. • First body burden analysis of pesticides and wastewater-derived pollutants in invertebrates in the Danube River is reported. - Capsule: A multi

A Review of Removal of Pollutants from Water/Wastewater Using Different Types of Nanomaterials

Directory of Open Access Journals (Sweden)

M. T. Amin

2014-01-01

Full Text Available The rapidly increasing population, depleting water resources, and climate change resulting in prolonged droughts and floods have rendered drinking water a competitive resource in many parts of the world. The development of cost-effective and stable materials and methods for providing the fresh water in adequate amounts is the need of the water industry. Traditional water/wastewater treatment technologies remain ineffective for providing adequate safe water due to increasing demand of water coupled with stringent health guidelines and emerging contaminants. Nanotechnology-based multifunctional and highly efficient processes are providing affordable solutions to water/wastewater treatments that do not rely on large infrastructures or centralized systems. The aim of the present study is to review the possible applications of the nanoparticles/fibers for the removal of pollutants from water/wastewater. The paper will briefly overview the availability and practice of different nanomaterials (particles or fibers for removal of viruses, inorganic solutes, heavy metals, metal ions, complex organic compounds, natural organic matter, nitrate, and other pollutants present in surface water, ground water, and/or industrial water. Finally, recommendations are made based on the current practices of nanotechnology applications in water industry for a stand-alone water purification unit for removing all types of contaminants from wastewater.

Shadow prices of emerging pollutants in wastewater treatment plants: Quantification of environmental externalities.

Science.gov (United States)

Bellver-Domingo, A; Fuentes, R; Hernández-Sancho, F

2017-12-01

Conventional wastewater treatment plants (WWTPs) are designed to remove mainly the organic matter, nitrogen and phosphorus compounds and suspended solids from wastewater but are not capable of removing chemicals of human origin, such as pharmaceutical and personal care products (PPCPs). The presence of PPCPs in wastewater has environmental effects on the water bodies receiving the WWTP effluents and renders the effluent as unsuitable as a nonconventional water source. Considering PPCPs as non-desirable outputs, the shadow prices methodology has been implemented using the output distance function to measure the environmental benefits of removing five PPCPs (acetaminophen, ibuprofen, naproxen, carbamazepine and trimethoprim) from WWTP effluents discharged to three different ecosystems (wetland, river and sea). Acetaminophen and ibuprofen show the highest shadow prices of the sample for wetland areas. Their values are 128.2 and 11.0 €/mg respectively. These results represent a proxy in monetary terms of the environmental benefit achieved from avoiding the discharge of these PPCPs in wetlands. These results suggest which PPCPs are urgent to remove from wastewater and which ecosystems are most vulnerable to their presence. The findings of this study will be useful for the plant managers in order to make decisions about prioritization in the removal of different pollutants. Copyright © 2017 Elsevier Ltd. All rights reserved.

Reduction of Wastewater Pollutants of Mandalay City Slaughterhouse

International Nuclear Information System (INIS)

May Thant Zin; Sint Soe

2010-12-01

Slaughterhouse (Meat Production Factor)under Mandaly City Development Committee (MCDC) in Myanmar has been discharging raw wastewater directly into Tat Thay Pont which is located at the back side of the slaughterhouse.It can cause some water pollutants in water source and need to prevent environmental impact. This paper was studied on the treatment of slaughterhouse wastewater using appropriate technique available in local area. Sample collection of slaughterhouse waste, analysing of waste quality on current situation,different ways of pre-treating and anaerobically digestion without recycling were done. Screening, coagulation, sedimentation and charcoal filtration were included as pre-treating steps before major anaerobic digestion. Ferric chloride and aluminum sulphate chemicals of both commercial and analytical grades were used as coagulants. Laboratory-scaled anaerobic reactor constructed with polyvinyl chloride (PVC) material was 15 cm diameter and 90 cm heigh. MCDC slaughterhouse wastewater containing 98.56% of total coarse particles was removed via minimum size of 1500 micron screen. Aluminium sulphate gave the best removal of fine solid particles. It was observed that pre-treating steps can reduce 56.72% of initial biological oxygen demand (BOD), 51.482% of initial chemical oxygen demand (COD) and 45.18% of inital total suspended solid (TSS) and anaerobic digester after 30 days can reduce 77.4% of influent BOD,81.5% of influent COD and 87.3% of influent TSS.

Application of radiation for wastewater treatment

International Nuclear Information System (INIS)

Han Bumsoo; Kim Jinkyu; Kim Yuri

2006-01-01

Electron beam processing of wastewater is non-chemical, and uses fast formation of short-lived reactive radicals that can interact with a wide range of pollutants. Such reactive radicals are strong oxidizing or reducing agents that can transform the pollutants in the liquids wastes. The first studies on the radiation treatment of wastes were carried out in the 1950s principally for disinfection. In the 1960s, these studies were extended to the purification of water and wastewater. After some laboratory research on industrial wastewaters and polluted groundwater in 1970s and 1980s, several pilot plants were built for extended research in the 1990s. The first full-scale application was reported for the purification of wastewater at the Voronezh synthetic rubber plant in Russia. Two accelerators (50 kW each) were used to convert the non-biodegradable emulsifier, 'nekal', present in the wastewater to a biodegradable form . The installation treats up to 2000 m3 of effluent per day. A pilot plant of 1000 m 3 /d for treating textile-dyeing wastewater has been constructed in Daegu, Korea with 1 MeV, 40 kW electron accelerator. High-energy irradiation produces instantaneous radiolytical transformations by energy transfer from accelerated electrons to orbital electrons of water molecules. Absorbed energy disturbs the electron system of the molecule and results in breakage of inter-atomic bonds. Hydrated electron eaq, H atom, . OH and HO 2 . radicals and hydrogen peroxide H 2 O 2 and H 2 are the most important products of the primary interactions (radiolysis products). Generally, radiation processing of wastewater has maximum efficiency at pollutant concentration less than 10 -3 mol/L (∼100 ppm). The treatment of such wastewater is simple, requires low dose (about 1 kGy or less) and gives almost complete elimination of odor, color, taste and turbidity. The radiation processing of polluted water containing specific contaminants may require creation of special conditions to

Effects of dissolved oxygen concentration on photosynthetic bacteria wastewater treatment: Pollutants removal, cell growth and pigments production.

Science.gov (United States)

Meng, Fan; Yang, Anqi; Zhang, Guangming; Wang, Hangyao

2017-10-01

Dissolved oxygen (DO) is an important parameter in photosynthetic bacteria (PSB) wastewater treatment. This study set different DO levels and detected the pollutants removal, PSB growth and pigments production. Results showed that DO significantly influenced the performances of PSB wastewater treatment process. The highest COD (93%) and NH 3 -N removal (83%) was achieved under DO of 4-8mg/L, but DO of 2-4mg/L was recommended considering the aeration cost. PSB biomass reached 1645mg/L under DO of 4-8mg/L with satisfying co-enzyme Q10 content. The biomass yield was relatively stable at all DO levels. For bacteriochlorophyll and carotenoids, DO>1mg/L could satisfy their production. On the other hand, DOpigments production occurred at 24h; biomass reached peak at 48h; and the optimal time for pollutants removal was 72h. Copyright © 2017 Elsevier Ltd. All rights reserved.

Body burden of pesticides and wastewater-derived pollutants on freshwater invertebrates: Method development and application in the Danube River.

Science.gov (United States)

Inostroza, Pedro A; Wicht, Anna-Jorina; Huber, Thomas; Nagy, Claudia; Brack, Werner; Krauss, Martin

2016-07-01

While environmental risk assessment is typically based on toxicant concentrations in water and/or sediment, awareness is increasing that internal concentrations or body burdens are the key to understand adverse effects in organisms. In order to link environmental micropollutants as causes of observed effects, there is an increasing demand for methods to analyse these chemicals in organisms. Here, a multi-target screening method based on pulverised liquid extraction (PuLE) and a modified QuEChERS approach with an additional hexane phase was developed. It is capable to extract and quantify organic micropollutants of diverse chemical classes in freshwater invertebrates. The method was tested on gammarids from the Danube River (within the Joint Danube Survey 3) and target compounds were analysed by liquid chromatography-tandem mass spectrometry (LC-MS/MS). Furthermore, a non-target screening using high resolution-tandem mass spectrometry (LC-HRMS/MS) was conducted. A total of 17 pollutants were detected and/or quantified in gammarids at low concentrations. Pesticide concentrations ranged from 0.1 to 6.52 ng g(-1) (wet weight), those of wastewater-derived pollutants from 0.1 to 2.83 ng g(-1) (wet weight). The presence of wastewater-derived pollutants was prominent at all spots sampled. Using non-target screening, we could successfully identify several chlorinated compounds. These results demonstrate for the first time the presence of pesticides and wastewater-derived pollutants in invertebrates of the Danube River. Copyright © 2016 Elsevier Ltd. All rights reserved.

Evaluating the Thermal Pollution Caused by Wastewaters Discharged from a Chain of Coal-Fired Power Plants along a River

Directory of Open Access Journals (Sweden)

Marc A. Rosen

2015-05-01

Full Text Available Reliable and safe operation of a coal-fired power plant is strongly linked to freshwater resources, and environmental problems related to water sources and wastewater discharge are challenges for power station operation. In this study, an evaluation on the basis of a wastewater thermal pollution vector is reported for the environmental impact of residual water generated and discharged in the Jiu River during the operation of thermoelectric units of the Rovinari, Turceni and Craiova coal-fired power plants in Romania. Wastewater thermal pollutant vector Plane Projection is applied for assessing the water temperature evolution in the water flow lane created downstream of each power plant wastewater outlet channel. Simulation on the basis of an Electricity of France model, and testing validation of the results for thermoelectric units of 330 MW of these power plants are presented.

Contribution of domestic wastewater to the total pollutant loading influent to a municipal wastewater treatment plant; Contribuciond e las aguas residuales domesticas a la carga total que accede a una EDAr municipal

Energy Technology Data Exchange (ETDEWEB)

Marin Galvin, R.; Perez de Siles, L. A.; Rojas Moreno, F. J.; Gonzalez Jimenez, M. M.

2004-07-01

A study on the purely domestic wastewater from Cordoba city (Abril to july 2003) has found a pollutant loading very high on these domestic wastewaters, by showing mean values of suspended solid, BOD{sub 5} and COD equal to respectively 452 mg/l, 505 mg/1 and 793 mg/l. This pollutants power probably emanates from the products for domestic cleaning used in our homes and must be associated to chemicals as citrates, oxalates, surfactants, polialcohols, organics complexing, ammonium compounds..., which show high value of pollutant loading up to 200 mg/l of BOD{sub 5} per ml of product have been measured on a commercial domestic dishwasher, and 9.000 mg/l of DQO for a domestic smoothing. Furthermore, the increasing use of pre-cooked foods can add to domestic wastewater fats, oils, and flours which can also increase the BOD:5 and COD values of these effluents. On the other hand, the measured pollutant loading or domestic wastewater from monofamily homes has been lower than those from multifamily buildings. Finally, due to the fact that the Golondrina's WWTP (Cordoba, 1991) was designed for treat values of suspended solids, BOD, and COD lower than those actually detected, its treatment processes should be probably modified in a near future. (Author) 24 refs.

Chemical Modifications of Hollow Silica Microspheres for the Removal of Organic Pollutants in Simulated Wastewater

KAUST Repository

Torano, Aniela Zarzar

2017-01-01

Aqueous industrial effluents containing organic pollutants, such as textile dyes and crude oil, represent environmental and human health concerns due to their toxicity and possible carcinogenic effects. Adsorption is the most promising wastewater

Application of the removal of pollutants from textile industry wastewater in constructed wetlands using fuzzy logic.

Science.gov (United States)

Dogdu, Gamze; Yalcuk, Arda; Postalcioglu, Seda

2017-02-01

There are more than a hundred textile industries in Turkey that discharge large quantities of dye-rich wastewater, resulting in water pollution. Such effluents must be treated to meet discharge limits imposed by the Water Framework Directive in Turkey. Industrial treatment facilities must be required to monitor operations, keep them cost-effective, prevent operational faults, discharge-limit infringements, and water pollution. This paper proposes the treatment of actual textile wastewater by vertical flow constructed wetland (VFCW) systems operation and monitoring effluent wastewater quality using fuzzy logic with a graphical user interface. The treatment performance of VFCW is investigated in terms of chemical oxygen demand and ammonium nitrogen (NH4-N) content, color, and pH parameters during a 75-day period of operation. A computer program was developed with a fuzzy logic system (a decision- making tool) to graphically present (via a status analysis chart) the quality of treated textile effluent in relation to the Turkish Water Pollution Control Regulation. Fuzzy logic is used in the evaluation of data obtained from the VFCW systems and for notification of critical states exceeding the discharge limits. This creates a warning chart that reports any errors encountered in a reactor during the collection of any sample to the concerned party.

Electrochemical oxidation of ammonia-containing wastewater using Ti/RuO2-Pt electrode

Directory of Open Access Journals (Sweden)

Wei-wu Hu

2009-12-01

Full Text Available The electrochemical oxidation degradation processes for artificial and actual wastewater containing ammonia were carried out with a Ti/RuO2-Pt anode and a Ti plate cathode. We studied the effects of different current densities, space sizes between the two electrodes, and amounts of added NaCl on ammonia-containing wastewater treatment. It was shown that, after a 30-min treatment under the optimal conditions, which were a current density of 20 mA/cm2, a space size between the two electrodes of 1 cm, and an added amount of 0.5 g/L of NaCl, the COD concentration in municipal wastewater was 40 mg/L, a removal rate of 90%; and the NH3-N concentration was 7 mg/L, a removal rate of 88.3%. The effluent of municipal wastewater qualified for Class A of the Discharge Standard of Pollutants for Municipal Wastewater Treatment Plant (GB18918-2002.

Removal of organic pollutants in tannery wastewater from wet-blue fur processing by integrated Anoxic/Oxic (A/O) and Fenton: Process optimization

DEFF Research Database (Denmark)

Wang, Yong; Li, Weiguang; Angelidaki, Irini

2014-01-01

Treatment of tannery wastewater has been a challenge in remediation of aquatic environment in developing countries. Removal of organic pollutants in tannery wastewater from wet-blue fur processing was studied using integrated processes of Anoxic/Oxic and Fenton. Analysis of COD composition based...... 80%. In the subsequent Fenton oxidation, effects of initial pH and H2O2 dose on COD removal were investigated, and response surface methodology was adopted to obtain the optimal conditions as initial pH of 4.0, H2O2 dose of 14.0mM, H2O2:Fe2+ molar ratio of 10.6, and reaction time of 3h to achieve...... the highest COD removal of 55.87%. GC-MS analysis was carried out to observe the change of organic composition during Fenton oxidation, and most of the residual organic pollutants resistant to Fenton treatment belonged to organosilanes and saturated alkanes. This study will provide useful information...

Destination of organic pollutants during electrochemical oxidation of biologically-pretreated dye wastewater using boron-doped diamond anode

Energy Technology Data Exchange (ETDEWEB)

Zhu, Xiuping [Department of Environmental Engineering, Peking University, the Key Laboratory of Water and Sediment Sciences, Ministry of Education, Beijing100871 (China); Ni, Jinren, E-mail: nijinren@iee.pku.edu.cn [Department of Environmental Engineering, Peking University, the Key Laboratory of Water and Sediment Sciences, Ministry of Education, Beijing100871 (China); Wei, Junjun; Xing, Xuan; Li, Hongna [Department of Environmental Engineering, Peking University, the Key Laboratory of Water and Sediment Sciences, Ministry of Education, Beijing100871 (China)

2011-05-15

Electrochemical oxidation of biologically-pretreated dye wastewater was performed in a boron-doped diamond (BDD) anode system. After electrolysis of 12 h, the COD was decreased from 532 to 99 mg L{sup -1} (<100 mg L{sup -1}, the National Discharge Standard of China). More importantly, the destination of organic pollutants during electrochemical oxidation process was carefully investigated by molecular weight distribution measurement, resin fractionation, ultraviolet-visible spectroscopy, HPLC and GC-MS analysis, and toxicity test. As results, most organic pollutants were completely removed by electrochemical oxidation and the rest was primarily degraded to simpler compounds (e.g., carboxylic acids and short-chain alkanes) with less toxicity, which demonstrated that electrochemical oxidation of biologically-pretreated dye wastewater with BDD anode was very effective and safe. Especially, the performance of BDD anode system in degradation of large molecular organics such as humic substances makes it very promising in practical applications as an advanced treatment of biologically-pretreated wastewaters.

Destination of organic pollutants during electrochemical oxidation of biologically-pretreated dye wastewater using boron-doped diamond anode.

Science.gov (United States)

Zhu, Xiuping; Ni, Jinren; Wei, Junjun; Xing, Xuan; Li, Hongna

2011-05-15

Electrochemical oxidation of biologically-pretreated dye wastewater was performed in a boron-doped diamond (BDD) anode system. After electrolysis of 12h, the COD was decreased from 532 to 99 mg L(-1) (destination of organic pollutants during electrochemical oxidation process was carefully investigated by molecular weight distribution measurement, resin fractionation, ultraviolet-visible spectroscopy, HPLC and GC-MS analysis, and toxicity test. As results, most organic pollutants were completely removed by electrochemical oxidation and the rest was primarily degraded to simpler compounds (e.g., carboxylic acids and short-chain alkanes) with less toxicity, which demonstrated that electrochemical oxidation of biologically-pretreated dye wastewater with BDD anode was very effective and safe. Especially, the performance of BDD anode system in degradation of large molecular organics such as humic substances makes it very promising in practical applications as an advanced treatment of biologically-pretreated wastewaters. Copyright © 2011 Elsevier B.V. All rights reserved.

Destination of organic pollutants during electrochemical oxidation of biologically-pretreated dye wastewater using boron-doped diamond anode

International Nuclear Information System (INIS)

Zhu, Xiuping; Ni, Jinren; Wei, Junjun; Xing, Xuan; Li, Hongna

2011-01-01

Electrochemical oxidation of biologically-pretreated dye wastewater was performed in a boron-doped diamond (BDD) anode system. After electrolysis of 12 h, the COD was decreased from 532 to 99 mg L -1 ( -1 , the National Discharge Standard of China). More importantly, the destination of organic pollutants during electrochemical oxidation process was carefully investigated by molecular weight distribution measurement, resin fractionation, ultraviolet-visible spectroscopy, HPLC and GC-MS analysis, and toxicity test. As results, most organic pollutants were completely removed by electrochemical oxidation and the rest was primarily degraded to simpler compounds (e.g., carboxylic acids and short-chain alkanes) with less toxicity, which demonstrated that electrochemical oxidation of biologically-pretreated dye wastewater with BDD anode was very effective and safe. Especially, the performance of BDD anode system in degradation of large molecular organics such as humic substances makes it very promising in practical applications as an advanced treatment of biologically-pretreated wastewaters.

Biotransformation of nitrogen- and sulfur-containing pollutants during coking wastewater treatment: Correspondence of performance to microbial community functional structure.

Science.gov (United States)

Joshi, Dev Raj; Zhang, Yu; Gao, Yinxin; Liu, Yuan; Yang, Min

2017-09-15

Although coking wastewater is generally considered to contain high concentration of nitrogen- and sulfur-containing pollutants, the biotransformation processes of these compounds have not been well understood. Herein, a high throughput functional gene array (GeoChip 5.0) in combination with Illumina MiSeq sequencing of the 16S rRNA gene were used to identify microbial functional traits and their role in biotransformation of nitrogen- and sulfur-containing compounds in a bench-scale aerobic coking wastewater treatment system operated for 488 days. Biotransformation of nitrogen and sulfur-containing pollutants deteriorated when pH of the bioreactor was increased to >8.0, and the microbial community functional structure was significantly associated with pH (Mantels test, P functional microbial community structure (P functional genes for biotransformation of nitrogen- and sulfur-containing pollutants. Functional characterization of taxa and network analysis suggested that Burkholderiales, Actinomycetales, Rhizobiales, Pseudomonadales, and Hydrogenophiliales (Thiobacillus) were key functional taxa. Variance partitioning analysis showed that pH and influent ammonia nitrogen jointly explained 25.9% and 35.5% of variation in organic pollutant degrading genes and microbial community structure, respectively. This study revealed a linkage between microbial community functional structure and the likely biotransformation of nitrogen- and sulfur-containing pollutants, along with a suitable range of pH (7.0-7.5) for stability of the biological system treating coking wastewater. Copyright © 2017 Elsevier Ltd. All rights reserved.

Wastewater Treatment

Science.gov (United States)

... day before releasing it back to the environment. Treatment plants reduce pollutants in wastewater to a level nature can handle. Wastewater is used water. It includes substances such as human waste, food ...

The protection of urban areas from surface wastewater pollutions

Directory of Open Access Journals (Sweden)

Vialkova Elena

2017-01-01

Full Text Available In this paper it considered the problem of collection, treatment and discharge into waters of rain and melted wastewater. To reduce the load on the combined sewer system, there are engineering solutions collect rain and melt water for use in the irrigation of lawns and green spaces. Research carried out at the department “Water supply and sanitation”, (Russia, confirm the high pollution concentrations of meltwater and rainfall in urban arias. Series of measurements of heavy metal in rainwater runoff carried out in Hungary demonstrates clearly the differences in concentrations in the function of distance from the edge of the road. Also differences are introduced between pollution concentrations in runoff water from within and outside urban traffic roads. The quality of snow cover, forming meltwater is observed to be changing in dependence on roadway location. Quality characteristics of surface runoff and its sediments can be effectively improved with super-high frequency radiation (SHF treatment which is presented in this paper.

Solar photo-catalysis to remove paper mill wastewater pollutants

Energy Technology Data Exchange (ETDEWEB)

Amat, A.M.; Arques, A. [Departamento de Ingenieria Textil y Papelera, Universidad Politecnica de Valencia, EPSA-UPV, Paseo del Viaducto 1, E-03801 Alcoy (Spain); Lopez, F. [Departamento de Ingenieria Quimica y Nuclear, Universidad Politecnica de Valencia, EPSA-UPV, Paseo del Viaducto 1, E-03801 Alcoy (Spain); Miranda, M.A. [Departamento de Quimica, Instituto de Tecnologia Quimica, Universidad Politecnica de Valencia, UPV-CSIC, 46071 Valencia (Spain)

2005-10-01

Solar degradation of effluents in board paper industries has been studied using different photo-catalysts: Fenton reagent and TiO{sub 2}. p-Toluenesulfonic acid was chosen as a model compound for sulfonated pollutants already present in the incoming waters. The abatement of a 0.005M solution of this pollutant after 6h was found to be 47% for photo-Fenton and 27% for TiO{sub 2} (pseudo-first-order rate constants 0.002 and 0.001min{sup -1}, respectively). Eugenol and guaiacol were chosen as models for lignin degradation products. They were efficiently degraded by both photo-catalysts, and reaction rates were higher for eugenol (0.0024min{sup -1}) than for guaiacol (0.0018min{sup -1}). A solution of sodium acetate, sodium butyrate and d-glucose was chosen to study the effect of photo-catalysis towards volatile fatty acids and saccharides arising from starch degradation. In this case a clearly worse performance was observed: only 20% degradation was observed after 7h of treatment. When the real wastewater was treated with photo-catalytic methods, the best performance was obtained in closed circuits, when the COD values were higher. This fact can be explained by taking into account that closure of the circuits results in an accumulation of reluctant phenolic pollutants, while starch derivatives are continuously degraded by microorganisms in the circuits; as phenolic compounds are more easily degraded by photo-catalytic means, these methods are suitable for closed circuits. Finally, changes in the BOD{sub st} were determined by means of active sludges respirometry. A noticeable BOD{sub st} increase (30-50%) was observed in all cases, attributable to chemical oxidation of biodegradable species. (author)

Wastewater reuse

OpenAIRE

Milan R. Radosavljević; Vanja M. Šušteršič

2013-01-01

Water scarcity and water pollution are some of the crucial issues that must be addressed within local and global perspectives. One of the ways to reduce the impact of water scarcity  and to minimizine water pollution is to expand water and wastewater reuse. The local conditions including regulations, institutions, financial mechanisms, availability of local technology and stakeholder participation have a great influence on the decisions for wastewater reuse. The increasing awareness of food s...

Analysis of pollution removal from wastewater by Ceratophyllum ...

African Journals Online (AJOL)

USER

2010-04-05

Apr 5, 2010 ... The treatments included raw municipal wastewater (RMW) and treated ... municipal wastewater (from 1.34 to 0.95 ds/m) and the EC of raw ... wastes are generated daily from highly populated cities ... plants is an integral part of the biogeochemical cycle of .... Waste Management and Treatment, 2nd ed.

Set organic pollution as an impact category to achieve more comprehensive evaluation of life cycle assessment in wastewater-related issues.

Science.gov (United States)

Zhao, Xinyue; Yang, Jixian; Ma, Fang

2018-02-01

For wastewater-related issues (WRI), life cycle assessment (LCA) is often used to evaluate environmental impacts and derive optimization strategies. To promote the application of LCA for WRI, it is critical to incorporate local impact of water pollutants. Organic pollution, a main type of water pollution, has not been given much consideration in current LCA systems. This paper investigates the necessity of setting a regionalized impact category to reflect the local impact of organic pollution. A case study is conducted concerning an upgraded wastewater treatment plant (WWTP) in China, which is assumed to meet different sewage control strategies. Chemical oxygen demand (COD) is selected to represent the organic pollution and treated as an individual impact category. CML 2002 is used to quantify the environmental impacts of different strategies. Results show that abnormal LCA results are generated with the traditional eutrophication impact category, and after the introduction of COD, more reasonable LCA results are obtained, making the entire comparison of different control strategies more meaningful and compelling. Moreover, BEES, Ecovalue 08, and Chinese factors are adopted here as different weighting methods. Different weighting results exhibited various trade-offs for the increasingly strict control strategies; the results of BEES and Ecovalue08 underlined the potential environmental burden, but the results of Chinese factors only emphasized the local environmental improvement. It is concluded that setting regionalized impact category for organic pollution can make LCA results more reasonable in wastewater treatment, especially in evaluating Chinese cases because of the serious water pollution caused by large quantities of COD emission.

Multifunctional gold coated rare-earth hydroxide fluoride nanotubes for simultaneous wastewater purification and quantitative pollutant determination

International Nuclear Information System (INIS)

Zhang, Da-Quan; Sun, Tian-Ying; Yu, Xue-Feng; Jia, Yue; Chen, Ming; Wang, Jia-Hong; Huang, Hao; Chu, Paul K.

2014-01-01

Highlights: • The morphology and properties of Ce-doped yttrium hydroxide fluoride nanotubes (YHF:Ce NTs) were investigated. • YHF:Ce NTs were conjugated with Au nanoparticles to produce Au-YHF:Ce nanocomposites. • Au-YHF:Ce NTs showed excellent capability and efficiency in removing Congo red from solutions. • Au-YHF:Ce NTs were utilized to determine the concentration of Congo red based on SERS. - Abstract: Ce-doped yttrium hydroxide fluoride nanotubes (YHF:Ce NTs) with large surface area are synthesized and conjugated with Au nanoparticles (NPs) to produce Au-YHF:Ce nanocomposites. The Au-YHF:Ce NTs have a hollow structure, rough surface, polymer coating, and good surface-enhanced Raman spectroscopy (SERS) properties. They are applied to wastewater treatment to remove Congo red as a typical pollutant. The materials not only remove pollutants rapidly from the wastewater, but also detect trace amounts of the pollutants quantitatively. The multifunctional Au-YHF:Ce NTs have commercial potential as nano-absorbents and nano-detectors in water treatment and environmental monitoring

Multifunctional gold coated rare-earth hydroxide fluoride nanotubes for simultaneous wastewater purification and quantitative pollutant determination

Energy Technology Data Exchange (ETDEWEB)

Zhang, Da-Quan; Sun, Tian-Ying [Key Laboratory of Artificial Micro- and Nano-Structures of Ministry of Education, School of Physics and Technology, Wuhan University, Wuhan 430072 (China); Yu, Xue-Feng, E-mail: yxf@whu.edu.cn [Key Laboratory of Artificial Micro- and Nano-Structures of Ministry of Education, School of Physics and Technology, Wuhan University, Wuhan 430072 (China); Department of Physics and Materials Science, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong (China); Jia, Yue; Chen, Ming; Wang, Jia-Hong [Key Laboratory of Artificial Micro- and Nano-Structures of Ministry of Education, School of Physics and Technology, Wuhan University, Wuhan 430072 (China); Huang, Hao [Key Laboratory of Artificial Micro- and Nano-Structures of Ministry of Education, School of Physics and Technology, Wuhan University, Wuhan 430072 (China); Department of Physics and Materials Science, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong (China); Chu, Paul K., E-mail: paul.chu@cityu.edu.hk [Department of Physics and Materials Science, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong (China)

2014-04-01

Highlights: • The morphology and properties of Ce-doped yttrium hydroxide fluoride nanotubes (YHF:Ce NTs) were investigated. • YHF:Ce NTs were conjugated with Au nanoparticles to produce Au-YHF:Ce nanocomposites. • Au-YHF:Ce NTs showed excellent capability and efficiency in removing Congo red from solutions. • Au-YHF:Ce NTs were utilized to determine the concentration of Congo red based on SERS. - Abstract: Ce-doped yttrium hydroxide fluoride nanotubes (YHF:Ce NTs) with large surface area are synthesized and conjugated with Au nanoparticles (NPs) to produce Au-YHF:Ce nanocomposites. The Au-YHF:Ce NTs have a hollow structure, rough surface, polymer coating, and good surface-enhanced Raman spectroscopy (SERS) properties. They are applied to wastewater treatment to remove Congo red as a typical pollutant. The materials not only remove pollutants rapidly from the wastewater, but also detect trace amounts of the pollutants quantitatively. The multifunctional Au-YHF:Ce NTs have commercial potential as nano-absorbents and nano-detectors in water treatment and environmental monitoring.

Pollutants Characterization of Car Wash Wastewater

Directory of Open Access Journals (Sweden)

Hashim Nor Haslina

2016-01-01

Full Text Available The huge quantity of water consumed per car during washing cars yields the untreated effluents discharged to the stormwater system. Wastewater samples from snow car wash and two full hand service car wash station were analyzed for pH and the presence of PO43-,TP, O&G, alkalinity, TSS, NO3-, NO2-, COD and surfactant in accordance Standard Method of Water and Wastewater 2012. Two full hand wash service stations and one station of snow foam service were investigated in this study. Amongst the stations, snow foam car wash station indicates the highest concentration of PO43-, TP, O&G, TSS, COD and surfactant with the average value of 10.18 ± 0.87 mg/L, 30.93 ± 0.31 mg/L , 85.00 ± 0.64 mg/L 325.0 ± 0.6 mg/L, 485.0 ± 0.3 mg/L and 54.00 ± 2.50 mg/L as MBAS, respectively. Whereas, in parameters characterization in different stages throughout the car wash process, O&G was found to be the highest in pre soak stage, PO43-, TP, TSS and COD in washing stage and NO3- and NO2- in rinse stage. All parameters were compared to Environmental Quality (Industrial Effluent Regulations, 2009. There is a strong need to study on the characterization of car wash water in order to suggest the suitable treatment need for this type of wastewater.

Automatic Regulation of Wastewater Discharge

Directory of Open Access Journals (Sweden)

Bolea Yolanda

2017-01-01

Full Text Available Wastewater plants, mainly with secondary treatments, discharge polluted water to environment that cannot be used in any human activity. When those dumps are in the sea it is expected that most of the biological pollutants die or almost disappear before water reaches human range. This natural withdrawal of bacteria, viruses and other pathogens is due to some conditions such as the salt water of the sea and the sun effect, and the dumps areas are calculated taking into account these conditions. However, under certain meteorological phenomena water arrives to the coast without the full disappearance of pollutant elements. In Mediterranean Sea there are some periods of adverse climatic conditions that pollute the coast near the wastewater dumping. In this paper, authors present an automatic control that prevents such pollution episodes using two mathematical models, one for the pollutant transportation and the other for the pollutant removal in wastewater spills.

Control and Prevention of Wastewater Pollution From Amerya Petroleum Refining Company

International Nuclear Information System (INIS)

Bakry, A.A.

2004-01-01

An oil refinery normally uses large quantities of water, for cooling and other process purpose. This water is treated from contaminants and finally returned to a lake or sea, outside the refinery. Amerya Petroleum Refining Company (APRC) uses conventional and special treatment methods for wastewater to remove all pollutants and to reduce the oil content in refinery final effluent water to a limit of 10 ppm , as the maximum permissible limit for environmental protection as designated by the Egyptian Act No.4 for the year 1994 . About 80% of oil in wastewater is separated by API (American Petroleum Institute) separator method and returned to refinery. Small oil droplets, emulsion and suspended matter escaped from API separator but were removed successfully in the dissolved air flotation (DAF) with chemical additives as the secondary treatment stage for wastewater. The flotation method with chemical additives and filtration were used to reduce the suspended solids and oil content to permissible levels (10 ppm) Furthermore, biological treatment unit was constructed to remove the dissolved oxygen consuming contaminates, e.g. phenolic compounds and traces of hydrocarbon derivatives. It was found that the BOD and COD of the effluent were reduced, and 100% removal of the trace amount of phenol was achieved in effluent

High levels of endocrine pollutants in US streams during low flow due to insufficient wastewater dilution

Science.gov (United States)

Rice, Jacelyn; Westerhoff, Paul

2017-08-01

Wastewater discharges from publicly owned treatment works are a significant source of endocrine disruptors and other contaminants to the aquatic environment in the US. Although remaining pollutants in wastewater pose environmental risks, treated wastewater is also a primary source of stream flow, which in turn is critical in maintaining many aquatic and riparian wildlife habitats. Here we calculate the dilution factor--the ratio of flow in the stream receiving discharge to the flow of wastewater discharge--for over 14,000 receiving streams in the continental US using streamflow observations and a spatially explicit watershed-scale hydraulic model. We found that wastewater discharges make up more than 50% of in-stream flow for over 900 streams. However, in 1,049 streams that experienced exceptional low-flow conditions, the dilution factors in 635 of those streams fell so low during those conditions that the safety threshold for concentrations of one endocrine disrupting compound was exceeded, and in roughly a third of those streams, the threshold was exceeded for two compounds. We suggest that streams are vulnerable to public wastewater discharge of contaminants under low-flow conditions, at a time when wastewater discharges are likely to be most important for maintaining stream flow for smaller sized river systems.

Interrelationships of metal transfer factor under wastewater reuse and soil pollution.

Science.gov (United States)

Papaioannou, D; Kalavrouziotis, I K; Koukoulakis, P H; Papadopoulos, F; Psoma, P

2018-06-15

The transfer of heavy metals under soil pollution wastewater reuse was studied in a Greenhouse experiment using a randomized block design, including 6 treatments of heavy metals mixtures composed of Zn, Mn, Cd, Co, Cu, Cr, Ni, and Pb, where each metal was taking part in the mixture with 0, 10, 20, 30, 40, 50 mg/kg respectively, in four replications. The Beta vulgaris L (beet) was used as a test plant. It was found that the metal transfer factors were statistically significantly related to the: (i) DTPA extractable soil metals, (ii) the soil pollution level as assessed by the pollution indices, (iii) the soil pH, (iv) the beet dry matter yield and (v) the interactions between the heavy metals in the soil. It was concluded that the Transfer Factor is subjected to multifactor effects and its real nature is complex, and there is a strong need for further study for the understanding of its role in metal-plant relationships. Copyright © 2017 Elsevier Ltd. All rights reserved.

Influence of microbial community diversity and function on pollutant removal in ecological wastewater treatment.

Science.gov (United States)

Bai, Yaohui; Huo, Yang; Liao, Kailingli; Qu, Jiuhui

2017-10-01

Traditional wastewater treatments based on activated sludge often encounter the problems of bulking and foaming, as well as malodor. To solve these problems, new treatment technologies have emerged in recent decades, including the ecological wastewater treatment process, which introduces selected local plants into the treatment system. With a focus on the underlying mechanisms of the ecological treatment process, we explored the microbial community biomass, composition, and function in the treatment system to understand the microbial growth in this system and its role in pollutant removal. Flow cytometry analysis revealed that ecological treatment significantly decreased influent bacterial quantity, with around 80% removal. 16S rRNA gene sequencing showed that the ecological treatment also altered the bacterial community structure of the wastewater, leading to a significant change in Comamonadaceae in the effluent. In the internal ecological system, because most of microbes aggregate in the plant rhizosphere and the sludge under plant roots, we selected two plant species (Nerium oleander and Arundo donax) to study the characteristics of rhizosphere and sludge microbes. Metagenomic results showed that the microbial community composition and function differed between the two species, and the microbial communities of A. donax were more sensitive to seasonal effects. Combined with their greater biomass and abundance of metabolic genes, microbes associated with N. oleander showed a greater contribution to pollutant removal. Further, the biodegradation pathways of some micropollutants, e.g., atrazine, were estimated.

Set organic pollution as an impact category to achieve more comprehensive evaluation of life cycle assessment in wastewater-related issues

NARCIS (Netherlands)

Zhao, X.; Yang, Jixian; Ma, Fang

2018-01-01

For wastewater-related issues (WRI), life cycle assessment (LCA) is often used to evaluate environmental impacts and derive optimization strategies. To promote the application of LCA for WRI, it is critical to incorporate local impact of water pollutants. Organic pollution, a main type of water

Pollutant exposure at wastewater treatment works affects the detoxification organs of an urban adapter, the Banana Bat

International Nuclear Information System (INIS)

Naidoo, Samantha; Vosloo, Dalene; Schoeman, M. Corrie

2016-01-01

The Banana Bat, Neoromicia nana, exploits pollution-tolerant chironomids at wastewater treatment works (WWTWs). We investigated how pollutant exposure impacts the detoxification organs, namely the liver and kidney of N. nana. (i) We performed SEM-EDS to quantify metal content and mineral nutrients, and found significant differences in essential metal (Fe and Zn) content in the liver, and significant differences in Cu and one mineral nutrient (K) in the kidneys. (ii) We performed histological analysis and found more histopathological lesions in detoxification organs of WWTW bats. (iii) We calculated hepatosomatic/renalsomatic indices (HSI/RSI) to investigate whole organ effects, and found significant increases in organ size at WWTWs. (iv) We quantified metallothionein 1E (MT1E), using Western Blot immunodetection. Contrary to predictions, we found no significant upregulation of MT1E in bats at WWTWs. Ultimately, N. nana exploiting WWTWs may suffer chronic health problems from sub-lethal damage to organs responsible for detoxifying pollutants. - Highlights: • We measured pollutant exposure effects on detoxification organs in bats. • Iron, zinc, copper and potassium levels were altered in pollutant-exposed bats. • There was no significant upregulation of metallothionein in liver or kidney. • Pollutant-exposed bats had increased organ indices and histopathological lesions. • These organ effects suggest health risks and increased mortality in the long-term. - Wastewater treatment plants provide a short-term benefit of abundant pollution-tolerant prey, but cause long-term physiological damage to the liver and kidneys in urban bats.

The role of wastewater treatment in reducing pollution of surface waters with zearalenone.

Science.gov (United States)

Gromadzka, Karolina; Waśkiewicz, Agnieszka; Świetlik, Joanna; Bocianowski, Jan; Goliński, Piotr

2015-06-01

Zearalenone (ZEA) is a mycotoxin produced by some Fusarium species in food and feed. The toxicity of ZEA and its metabolites is related to the chemical structure of the mycotoxin, which is similar to naturally occurring oestrogens. Currently, there is increasing awareness of the presence of fungi and their toxic metabolites in the aquatic environment. One of the sources of these compounds are the effluents from wastewater treatment plants. The average annual efficiency of zearalenone reduction in the Łęczyca plant in our three-year study was in the range from 51.35 to 69.70 %. The threeway analysis of variance (year, month, and kind of wastewater) shows that the main effects of all factors and all interactions between them were significant for zearalenone and dissolved organic carbon content. Our findings suggest that wastewater is not the main source of surface water pollution with zearalenone. Future research should investigate the means to reduce ZEA and its migration from the fields through prevention strategies such as breeding for crops, plant debris management (crop rotation, tillage), and/or chemical and biological control.

Effect of coupled UV-A and UV-C LEDs on both microbiological and chemical pollution of urban wastewaters

International Nuclear Information System (INIS)

Chevremont, A.-C.; Farnet, A.-M.; Coulomb, B.; Boudenne, J.-L.

2012-01-01

Wastewater reuse for irrigation is an interesting alternative for many Mediterranean countries suffering from water shortages. The development of new technologies for water recycling is a priority for these countries. In this study we test the efficiency of UV-LEDs (Ultraviolet-Light-Emitting Diodes) emitting UV-A or UV-C radiations, used alone or coupled, on bacterial and chemical indicators. We monitored the survival of fecal bioindicators found in urban wastewaters and the oxidation of creatinine and phenol which represent either conventional organic matter or the aromatic part of pollution respectively. It appears that coupling UV-A/UV-C i) achieves microbial reduction in wastewater more efficiently than when a UV-LED is used alone, and ii) oxidizes up to 37% of creatinine and phenol, a result comparable to that commonly obtained with photoreactants such as TiO 2 . - Highlights: ► We test UV-LEDs as an urban wastewater tertiary treatment. ► UV-A and UV-C are coupled, combining germicidal and oxidative properties of UV. ► Coupled wavelengths have the most efficient bactericidal effect. ► Coupling UV-A and UV-C leads to photooxidation of creatinine and phenol.

Priorities for toxic wastewater management in Pakistan

Energy Technology Data Exchange (ETDEWEB)

Rahman, A. [Sustainable Development Policy Institute, Islamabad (Pakistan)

1996-12-31

This study assesses the number of industries in Pakistan, the total discharge of wastewater, the biological oxygen demand (BOD) load, and the toxicity of the wastewater. The industrial sector is a major contributor to water pollution, with high levels of BOD, heavy metals, and toxic compounds. Only 30 industries have installed water pollution control equipment, and most are working at a very low operational level. Priority industrial sectors for pollution control are medium- to large-scale textile industries and small-scale tanneries and electroplating industries. Each day the textile industries discharge about 85,000 m{sup 3} of wastewater with a high BOD, while the electroplating industries discharge about 23,000 m{sup 3} of highly toxic and hazardous wastewater. Various in-plant modifications can reduce wastewater discharges. Economic incentives, like tax rebates, subsidies, and soft loans, could be an option for motivating medium- to large-scale industries to control water pollution. Central treatment plants may be constructed for treating wastewater generated by small-scale industries. The estimated costs for the treatment of textile and electroplating wastewater are given. The legislative structure in Pakistan is insufficient for control of industrial pollution; not only do existing laws need revision, but more laws and regulations are needed to improve the state of affairs, and enforcement agencies need to be strengthened. 15 refs., 1 fig., 9 tabs.

Odor control in evaporation ponds treating olive mill wastewater through the use of Ca(OH)2.

Science.gov (United States)

Lagoudianaki, E; Manios, T; Geniatakis, M; Frantzeskaki, N; Manios, V

2003-01-01

Different amounts of Ca(OH)2 were added in 2 L beakers containing 1 L of olive mill wastewater (OMW). The mixture was stirred for 45 min and left to settle. Wastewater analysis was used in order to determine the effect of the different amounts of calcium hydroxide in the treating process, three days after the application. The Odor Detection Threshold was used for determining the effect of the treatment in the odors produced in the beakers, three and 30 days after. Both sets of measurements indicated an important reduction in wastewater pollutants and odor emission when 10 g/L of Ca(OH)2 were added. In order to evaluate these results in more realistic conditions. 10 L plastic containers were filled with 6 L of OMW, relevant amounts of Ca(OH)2 were added, the mixture was stirred manually and left to settle in the open. Again, 10 g/L of calcium hydroxide produced the best results in odor reduction and wastewater treatment.

Analysis of some pharmaceuticals in municipal wastewater of Almadinah Almunawarah

KAUST Repository

Shraim, Amjad; Diab, Atef; Alsuhaimi, Awadh; Niazy, Esmail; Metwally, Mohammed; Amad, Maan H.; Sioud, Salim; Dawoud, Abdulilah

2012-01-01

The chemical pollution of water resources is a major challenge facing the humanity in this century. Pharmaceuticals and personal care products (PPCPs) are a group of emerging environmental chemical pollutants distinguished by their bioactivity and high solubility. They may also cause health complications to humans and living organisms. Pharmaceuticals enter the environment, mainly via wastewater and can eventually reach the surface and ground water. Despite this, PPCPs received less attention as environmental pollutants than other chemical pollutants (e.g. heavy metals and pesticides). The purpose of this work was to investigate the presence of some of the most frequently dispensed drugs for the residents of Almadinah Almunawarah, Saudi Arabia in the municipal wastewater before and after treatment. For this purpose, wastewater samples were collected biweekly from the city’s sewage treatment plant for a period of 4 months and analyzed the targeted drugs using tandem LC–MS. Out of the 19 investigated drugs, 5 pharmaceuticals have been found in concentrations greater than the limit of detection in both the influents and effluents of the sewage treatment plant. As expected, the concentrations of investigated pharmaceuticals in the wastewater were found to be low. These drugs and their average concentrations (in ng mL−1) in the influents were: acetaminophen (38.9), metformin (15.2), norfluoxetine (7.07), atenolol (2.04), and cephalexin (1.88). Meanwhile, the effluents contained slightly lower levels (in ng mL−1) than those of influents: acetaminophen (31.2), metformin (3.19), norfluoxetine (7.25), atenolol (0.545), and cephalexin (1.53). The results of this study supported by many other investigations indicate the inefficiency of current conventional wastewater treatment protocols in eliminating such a group of active and potentially hazardous pollutants from the wastewater.

Analysis of some pharmaceuticals in municipal wastewater of Almadinah Almunawarah

KAUST Repository

Shraim, Amjad

2012-11-29

The chemical pollution of water resources is a major challenge facing the humanity in this century. Pharmaceuticals and personal care products (PPCPs) are a group of emerging environmental chemical pollutants distinguished by their bioactivity and high solubility. They may also cause health complications to humans and living organisms. Pharmaceuticals enter the environment, mainly via wastewater and can eventually reach the surface and ground water. Despite this, PPCPs received less attention as environmental pollutants than other chemical pollutants (e.g. heavy metals and pesticides). The purpose of this work was to investigate the presence of some of the most frequently dispensed drugs for the residents of Almadinah Almunawarah, Saudi Arabia in the municipal wastewater before and after treatment. For this purpose, wastewater samples were collected biweekly from the city’s sewage treatment plant for a period of 4 months and analyzed the targeted drugs using tandem LC–MS. Out of the 19 investigated drugs, 5 pharmaceuticals have been found in concentrations greater than the limit of detection in both the influents and effluents of the sewage treatment plant. As expected, the concentrations of investigated pharmaceuticals in the wastewater were found to be low. These drugs and their average concentrations (in ng mL−1) in the influents were: acetaminophen (38.9), metformin (15.2), norfluoxetine (7.07), atenolol (2.04), and cephalexin (1.88). Meanwhile, the effluents contained slightly lower levels (in ng mL−1) than those of influents: acetaminophen (31.2), metformin (3.19), norfluoxetine (7.25), atenolol (0.545), and cephalexin (1.53). The results of this study supported by many other investigations indicate the inefficiency of current conventional wastewater treatment protocols in eliminating such a group of active and potentially hazardous pollutants from the wastewater.

Analysis of some pharmaceuticals in municipal wastewater of Almadinah Almunawarah

Directory of Open Access Journals (Sweden)

Amjad Shraim

2017-02-01

Full Text Available The chemical pollution of water resources is a major challenge facing the humanity in this century. Pharmaceuticals and personal care products (PPCPs are a group of emerging environmental chemical pollutants distinguished by their bioactivity and high solubility. They may also cause health complications to humans and living organisms. Pharmaceuticals enter the environment, mainly via wastewater and can eventually reach the surface and ground water. Despite this, PPCPs received less attention as environmental pollutants than other chemical pollutants (e.g. heavy metals and pesticides. The purpose of this work was to investigate the presence of some of the most frequently dispensed drugs for the residents of Almadinah Almunawarah, Saudi Arabia in the municipal wastewater before and after treatment. For this purpose, wastewater samples were collected biweekly from the city's sewage treatment plant for a period of 4 months and analyzed the targeted drugs using tandem LC–MS. Out of the 19 investigated drugs, 5 pharmaceuticals have been found in concentrations greater than the limit of detection in both the influents and effluents of the sewage treatment plant. As expected, the concentrations of investigated pharmaceuticals in the wastewater were found to be low. These drugs and their average concentrations (in ng mL−1 in the influents were: acetaminophen (38.9, metformin (15.2, norfluoxetine (7.07, atenolol (2.04, and cephalexin (1.88. Meanwhile, the effluents contained slightly lower levels (in ng mL−1 than those of influents: acetaminophen (31.2, metformin (3.19, norfluoxetine (7.25, atenolol (0.545, and cephalexin (1.53. The results of this study supported by many other investigations indicate the inefficiency of current conventional wastewater treatment protocols in eliminating such a group of active and potentially hazardous pollutants from the wastewater.

Development of non-thermal plasma jet and its potential application for color degradation of organic pollutant in wastewater treatment

Science.gov (United States)

Pirdo Kasih, Tota; Kharisma, Angel; Perdana, Muhammad Kevin; Murphiyanto, Richard Dimas Julian

2017-12-01

This paper presents the development of non-thermal plasma-based AOPs for color degradation in wastewater treatment. The plasma itself was generated by an in-house high voltage power supply (HVPS). Instead of gas-phase plasma system, we applied plasma jet system underwater during wastewater treatment without additional any chemicals (chemical-free processing). The method is thought to maximize the energy transfer and increase the efficient interaction between plasma and solution during the process. Our plasma jet system could proceed either by using helium (He), argon (Ar) and air as the medium in an open air atmosphere. Exploring the developed plasma to be applied in organic wastewater treatment, we demonstrated that the plasma jet could be generated underwater and yields in color degradation of methylene blue (MB) wastewater model. When using Ar gas as a medium, the color degradation of MB could be achieved within 90 minutes. Whereas, by using Ar with an admixing of oxygen (O2) gas, the similar result could be accomplished within 60 minutes. Additional O2 gas in the latter might produce more hydroxyl radicals and oxygen-based species which speed up the oxidative reaction with organic pollutants, and hence accelerate the process of color degradation.

Case study of the application of Fenton process to highly polluted wastewater from power plant.

Science.gov (United States)

Pliego, Gema; Zazo, Juan A; Casas, Jose A; Rodriguez, Juan J

2013-05-15

This work investigates the application of Fenton process to the treatment of a highly polluted industrial wastewater resulting from the pipeline cleaning in a power plant. This effluent is characterized by a high chemical oxygen demand (COD>40 g/L), low biodegradability and quite a high iron concentration (around 3g/L) this coming from pipeline corrosion. The effect of the initial reaction temperature (between 50 and 90 °C) and the way of feeding H2O2 on the mineralization percentage and the efficiency of H2O2 consumption has been analyzed. With the stoichiometric amount of H2O2 relative to initial COD, fed in continuous mode, more than 90% COD reduction was achieved at 90 °C. That was accompanied by a dramatic improvement of the biodegradability. Thus, a combined treatment based on semicontinuous high-temperature Fenton oxidation (SHTF) and conventional aerobic biological treatment would allow fulfilling the COD and ecotoxicity regional limits for industrial wastewaters into de municipal sewer system. For the sake of comparison, catalytic wet air oxidation was also tested with poor results (less than 30% COD removal at 140 °C and 8 atm oxygen pressure). Copyright © 2013 Elsevier B.V. All rights reserved.

Removal of organic pollutants from 2,2',5,5'-tetrachlorobenzidine (TCB) industrial wastewater by micro-electrochemical oxidation and air-stripping

International Nuclear Information System (INIS)

Xia Shibin; Xia Shuichun; Zhu Changqing

2007-01-01

A feasible method for treatment of the wastewater from the two-staged neutralization in 2,2',5,5'-tetrachlorobenzidine (TCB) manufacturing processes, a refractory dye intermediate effluents, based on combined micro-electrochemical oxidation or iron-chipping filtration (ICF) and air-stripping reactor (ASR), was developed. On conditions of HRT 1 h, pH 3.0 in ICF and HRT 38 h, gas-liquid ratio 15, pH 6.0-8.65, temperature 26 deg. C in ASR, the overall COD, color, TCB and NH 4 + -N removal were 96.8%, 91%, 87.61% and 62%, respectively, during the treatment of TCB wastewater from the two-staged neutralization dissolved by methanol. The averaged 18.3%, 81.7% of the total degraded COD, 35.2%, 64.8% of TCB were carried out in ICF and ASR, respectively. NH 4 + -N removal was finished mainly in ASR. The experimental results indicated that the combined micro-electrochemical oxidation and air-stripping process performed good treatment of COD, color, TCB and NH 4 + -N removal in TCB wastewater from the two-staged neutralization dissolved by ethanol or acetone, came up the discharge standard in China. But the TCB wastewater from the two-staged neutralization dissolved by methanol should be deeply treated before discharged

Zeolite A synthesized from alkaline assisted pre-activated halloysite for efficient heavy metal removal in polluted river water and industrial wastewater.

Science.gov (United States)

Meng, Qingpeng; Chen, Hong; Lin, Junzhong; Lin, Zhang; Sun, Junliang

2017-06-01

High quality zeolite A was synthesized through a hydrothermal process using alkaline-assisted pre-activated halloysite mineral as the alumina and silica source. The synthesis conditions employed in this study were finely tuned by varying the activating temperature, sodium hydroxide content, water content and Si/Al ratio. The obtained zeolite A showed excellent adsorption properties for both single metal cation solutions and mixed cation solutions when the concentrations of the mixed cations were comparable with those in polluted natural river water and industrial wastewater. High adsorptive capacities for Ag + (123.05mg/g) and Pb 2+ (227.70mg/g) were achieved using the synthesized zeolite A. This observation indicates that the zeolite A synthesized from alkaline-assisted pre-activated halloysite can be used as a low-cost and relatively effective adsorbent to purify heavy metal cation polluted natural river water and industrial wastewater. Copyright © 2016. Published by Elsevier B.V.

Treatment of persistent organic pollutants in wastewater using hydrodynamic cavitation in synergy with advanced oxidation process.

Science.gov (United States)

Badmus, Kassim Olasunkanmi; Tijani, Jimoh Oladejo; Massima, Emile; Petrik, Leslie

2018-03-01

Persistent organic pollutants (POPs) are very tenacious wastewater contaminants. The consequences of their existence have been acknowledged for negatively affecting the ecosystem with specific impact upon endocrine disruption and hormonal diseases in humans. Their recalcitrance and circumvention of nearly all the known wastewater treatment procedures are also well documented. The reported successes of POPs treatment using various advanced technologies are not without setbacks such as low degradation efficiency, generation of toxic intermediates, massive sludge production, and high energy expenditure and operational cost. However, advanced oxidation processes (AOPs) have recently recorded successes in the treatment of POPs in wastewater. AOPs are technologies which involve the generation of OH radicals for the purpose of oxidising recalcitrant organic contaminants to their inert end products. This review provides information on the existence of POPs and their effects on humans. Besides, the merits and demerits of various advanced treatment technologies as well as the synergistic efficiency of combined AOPs in the treatment of wastewater containing POPs was reported. A concise review of recently published studies on successful treatment of POPs in wastewater using hydrodynamic cavitation technology in combination with other advanced oxidation processes is presented with the highlight of direction for future research focus.

Weighing environmental advantages and disadvantages of advanced wastewater treatment of micro-pollutants using environmental life cycle assessment

DEFF Research Database (Denmark)

Wenzel, Henrik; Larsen, Henrik Fred; Clauson-Kaas, Jes

2008-01-01

Much research and development effort is directed towards advances in municipal wastewater treatment aiming at reducing the effluent content of micro-pollutants and pathogens. The objective is to further reduce the eco-toxicity, hormone effects and pathogenic effects of the effluent. Such further ...

Weighing environmental advantages and disadvantages of advanced wastewater treatment of micro-pollutants using environmental life cycle assessment

DEFF Research Database (Denmark)

Wenzel, Henrik; Larsen, Henrik Fred; Clauson-Kaas, Jes

2007-01-01

Much research and development effort is directed towards advances in municipal wastewater treatment aiming at reducing the effluent content of micro-pollutants and pathogens. The objective is to further reduce the eco-toxicity, hormone effects and pathogenic effects of the effluent. Such further ...

Characterization of livestock wastewater at various stages of wastewater treatment plant

International Nuclear Information System (INIS)

Ting Teo Ming; Kim, Tak Hyun; Lee, Myun Joo

2007-01-01

A characterization study has been conducted at Gongju Livestock Wastewater Treatment Plant, Gongju, South Korea. It is owned and operated by the government with treatment capacity of 250 tons per day. Livestock wastewater was collected from individual farmer and treated at the treatment plant. The centralized livestock wastewater treatment plant has various treatment processes namely pre-treatment, anaerobic digestion, nitrification, de-nitrification , chemical treatment, sand filtration and ozonization. The livestock wastewater was characterized by high COD, SS, T-N and T-P with concentration of 20600 mg/l, 6933 mg/l, 2820 mg/l and 700 mg/ l, respectively. After the wastewater has undergone various treatment processes it was discharged to waterways with concentration of COD, SS, T-N and T-P at 105 mg/l, 73 mg/l, 2.1 mg/l and 9 mg/l, respectively. This is part of the study to investigate the potential of irradiation to be applied at the centralized livestock wastewater treatment plant. Although livestock wastewater can be potentially applied to crop as source of nutrients it also affect the water quality due to runoff and leaching. When the wastewater applied at the rates in excess of crop uptake rates, the excess wastewater could potentially enter surface and groundwater and polluted them. (author)

Effect of coupled UV-A and UV-C LEDs on both microbiological and chemical pollution of urban wastewaters

Energy Technology Data Exchange (ETDEWEB)

Chevremont, A.-C., E-mail: anne-celine.chevremont@imbe.fr [Aix-Marseille Universite - CNRS, FR ECCOREV, Laboratoire Chimie de l' Environnement (FRE3416), Equipe ' Developpements Metrologiques et Chimie des Milieux' , 3 place Victor Hugo, case 29, 13331 Marseille Cedex 3 (France); Aix-Marseille Universite - CNRS, FR ECCOREV, Institut Mediterraneen de Biodiversite et d' Ecologie marine et continentale (UMR7263), Equipe ' Vulnerabilite des Systemes Microbiens' , Avenue Escadrille Normandie-Niemen, Boite 452, 13397 Marseille Cedex 20 (France); Farnet, A.-M. [Aix-Marseille Universite - CNRS, FR ECCOREV, Institut Mediterraneen de Biodiversite et d' Ecologie marine et continentale (UMR7263), Equipe ' Vulnerabilite des Systemes Microbiens' , Avenue Escadrille Normandie-Niemen, Boite 452, 13397 Marseille Cedex 20 (France); Coulomb, B.; Boudenne, J.-L. [Aix-Marseille Universite - CNRS, FR ECCOREV, Laboratoire Chimie de l' Environnement (FRE3416), Equipe ' Developpements Metrologiques et Chimie des Milieux' , 3 place Victor Hugo, case 29, 13331 Marseille Cedex 3 (France)

2012-06-01

Wastewater reuse for irrigation is an interesting alternative for many Mediterranean countries suffering from water shortages. The development of new technologies for water recycling is a priority for these countries. In this study we test the efficiency of UV-LEDs (Ultraviolet-Light-Emitting Diodes) emitting UV-A or UV-C radiations, used alone or coupled, on bacterial and chemical indicators. We monitored the survival of fecal bioindicators found in urban wastewaters and the oxidation of creatinine and phenol which represent either conventional organic matter or the aromatic part of pollution respectively. It appears that coupling UV-A/UV-C i) achieves microbial reduction in wastewater more efficiently than when a UV-LED is used alone, and ii) oxidizes up to 37% of creatinine and phenol, a result comparable to that commonly obtained with photoreactants such as TiO{sub 2}. - Highlights: Black-Right-Pointing-Pointer We test UV-LEDs as an urban wastewater tertiary treatment. Black-Right-Pointing-Pointer UV-A and UV-C are coupled, combining germicidal and oxidative properties of UV. Black-Right-Pointing-Pointer Coupled wavelengths have the most efficient bactericidal effect. Black-Right-Pointing-Pointer Coupling UV-A and UV-C leads to photooxidation of creatinine and phenol.

MBR technology: a promising approach for the (pre-)treatment of hospital wastewater.

Science.gov (United States)

Beier, S; Cramer, C; Mauer, C; Köster, S; Schröder, H Fr; Pinnekamp, J

2012-01-01

Membrane bioreactor (MBR) technology is a very reliable and extensively tested solution for biological wastewater treatment. Nowadays, separate treatment of highly polluted wastewater streams especially from hospitals and other health care facilities is currently under investigation worldwide. In this context, the MBR technology will play a decisive role because an effluent widely cleaned up from solids and nutrients is absolutely mandatory for a subsequent further elimination of organic trace pollutants. Taking hospital wastewater as an example, the aim of this study was to investigate to what extent MBR technology is an adequate 'pre-treatment' solution for further elimination of trace pollutants. Therefore, we investigated - within a 2-year period - the performance of a full-scale hospital wastewater treatment plant (WWTP) equipped with a MBR by referring to conventional chemical and microbiological standard parameters. Furthermore, we measured the energy consumption and tested different operating conditions. According to our findings the MBR treatment of the hospital wastewater was highly efficient in terms of the removal of solids and nutrients. Finally, we did not observe any major adverse effects on the operation and performance of the MBR system which potentially could derive from the composition of the hospital wastewater. In total, the present study proved that MBR technology is a very efficient and reliable treatment approach for the treatment of highly polluted wastewater from hospitals and can be recommended as a suitable pre-treatment solution for further trace pollutant removal.

Assessment of full-scale biological nutrient removal systems upgraded with physico-chemical processes for the removal of emerging pollutants present in wastewaters from Mexico.

Science.gov (United States)

Estrada-Arriaga, Edson Baltazar; Cortés-Muñoz, Juana Enriqueta; González-Herrera, Arturo; Calderón-Mólgora, César Guillermo; de Lourdes Rivera-Huerta, Ma; Ramírez-Camperos, Esperanza; Montellano-Palacios, Leticia; Gelover-Santiago, Silvia Lucila; Pérez-Castrejón, Sara; Cardoso-Vigueros, Lina; Martín-Domínguez, Alejandra; García-Sánchez, Liliana

2016-11-15

Two full-scale biological nutrient removal systems upgraded with three physico-chemical processes (coagulation, chemical precipitation, and neutral Fenton) were evaluated in order to determine the removal of emerging pollutants (EPs) present in municipal wastewater from Mexico. Between 41 and 55 EPs were detected in the influents of two wastewater treatment plants (WWTPs), including personal care products (PPCPs), antibiotics, analgesics, antiepileptics, antilipidemics, antihypertensives, antiseptics, stimulants, and hormones. Emerging pollutants were detected at concentrations ranging from 0.69ng/L to 94,600ng/L. High concentrations of emerging pollutants were found during dry season. WWTP 1, integrated by oxidation ditches and UV light lamps, showed removal efficiencies of EPs between 20% and 22%. On the other hand, WWTP 2 consisted of anaerobic/anoxic/aerobic tanks coupled with two disinfection processes; chlorine dioxide and UV light lamps, for which the removal of EPs was significant (up to 80%). The concentrations of emerging pollutants in WWTP 1 effluent was found within a rangeemerging pollutants in the effluent were below 210ng/L. WWTP 2 showed high emerging pollutant removals, compared to those of WWTP 1, due to a greater activity of the simultaneous nitrification-denitrification processes, hydraulic retention time, and solids retention time. The compounds that were more persistent with removals below 50% in both effluents were: carbamazepine, dehydronifedipine, meprobamate, sertraline, propranolol, propoxyphene, norverapamil, diazepam, alprazolam, sulfamethoxazole, metoprolol, ofloxacin, norfloxacin, fluoxetine, erythromycin-H2O, diphenhydramine, dehydronifedipine, clarithromycin, hydrochlorothiazide, and albuterol. The application of neutral Fenton reaction as post-treatment for the two effluents from the WWTPs is promising for the removal of emerging pollutants (up to 100%) and for assuring high quality of treated water. Copyright © 2016 Elsevier B

Natural light-micro aerobic condition for PSB wastewater treatment: a flexible, simple, and effective resource recovery wastewater treatment process.

Science.gov (United States)

Lu, Haifeng; Han, Ting; Zhang, Guangming; Ma, Shanshan; Zhang, Yuanhui; Li, Baoming; Cao, Wei

2018-01-01

Photosynthetic bacteria (PSB) have two sets of metabolic pathways. They can degrade pollutants through light metabolic under light-anaerobic or oxygen metabolic pathways under dark-aerobic conditions. Both metabolisms function under natural light-microaerobic condition, which demands less energy input. This work investigated the characteristics of PSB wastewater treatment process under that condition. Results showed that PSB had very strong adaptability to chemical oxygen demand (COD) concentration; with F/M of 5.2-248.5 mg-COD/mg-biomass, the biomass increased three times and COD removal reached above 91.5%. PSB had both advantages of oxygen metabolism in COD removal and light metabolism in resource recovery under natural light-microaerobic condition. For pollutants' degradation, COD, total organic carbon, nitrogen, and phosphorus removal reached 96.2%, 91.0%, 70.5%, and 92.7%, respectively. For resource recovery, 74.2% of C in wastewater was transformed into biomass. Especially, coexistence of light and oxygen promote N recovery ratio to 70.9%, higher than with the other two conditions. Further, 93.7% of N-removed was synthesized into biomass. Finally, CO 2 emission reduced by 62.6% compared with the traditional process. PSB wastewater treatment under this condition is energy-saving, highly effective, and environment friendly, and can achieve pollution control and resource recovery.

Modeling of Electrochemical Process for the Treatment of Wastewater Containing Organic Pollutants

Science.gov (United States)

Rodrigo, Manuel A.; Cañizares, Pablo; Lobato, Justo; Sáez, Cristina

Electrocoagulation and electrooxidation are promising electrochemical technologies that can be used to remove organic pollutants contained in wastewaters. To make these technologies competitive with the conventional technologies that are in use today, a better understanding of the processes involved must be achieved. In this context, the development of mathematical models that are consistent with the processes occurring in a physical system is a relevant advance, because such models can help to understand what is happening in the treatment process. In turn, a more detailed knowledge of the physical system can be obtained, and tools for a proper design of the processes, or for the analysis of operating problems, are attained. The modeling of these technologies can be carried out using single-variable or multivariable models. Likewise, the position dependence of the model species can be described with different approaches. In this work, a review of the basics of the modeling of these processes and a description of several representative models for electrochemical oxidation and coagulation are carried out. Regarding electrooxidation, two models are described: one which summarizes the pollution of a wastewater in only one model species and that considers a macroscopic approach to formulate the mass balances and other that considers more detailed profile of concentration to describe the time course of pollutants and intermediates through a mixed maximum gradient/macroscopic approach. On the topic of electrochemical coagulation, two different approaches are also described in this work: one that considers the hydrodynamic conditions as the main factor responsible for the electrochemical coagulation processes and the other that considers the chemical interaction of the reagents and the pollutants as the more significant processes in the description of the electrochemical coagulation of organic compounds. In addition, in this work it is also described a multivariable model

Performance of the constructed wetland systems in pollutants removal from hog wastewater

Directory of Open Access Journals (Sweden)

Wallison da Silva Freitas

2010-08-01

Full Text Available The main objective of this work was to evaluate the efficiency of a constructed wetland systems (CWS for pollutants removal, in mono crop and multi crop with three different species of plants, originated from hog wastewater treatment (HW. Therefore, 5 CWS of 24.0 m x 1.1 m x 0.7 m were constructed, sealed with a membrane of polyvinyl chloride (PVC and filled with 0.4 m of small gravel. In CWS1, CWS2 and CWS3 grown to cattail (Typha latifolia L., Alternanthera philoxeroides (Mart. Griseb. and Tifton 85 grass (Cynodon dactylon Pers., respectively. In the bed of CWS4 was planted at 1st third Alternanthera, cattail, in the 2nd third and tifton-85 grass and in the 3rd third of. The CWS5 was not planted and it was used as control. After passing through a filter filled with crushed bagasse of sugar cane, the HW was applied to the CWS in a flow of 0.8 m3 d-1, which corresponded to a hydraulic detention time of 4.8 days. According to the results it was shown that the five CWS(s had statistically nearly the same removal of pollutants, and the average removal efficiency of TSS, COD, BOD and Zn, were 91, 89, 86 and 94%, respectively. Also high removals were obtained concerning the ST, N-total, NH4+ and P-total, with average values of 62, 59, 52 and 50%, respectively. The plants in all planted CWS worked in a similar way maintaining the system efficiency and the non cultivated CWS presented analogous capacity of pollutants removal when compared to the cultivated CWS(s.

Treatment of Wastewater Containing Organic Pollutants by Ionizing Radiation

Energy Technology Data Exchange (ETDEWEB)

Kimura, A.; Taguchi, M. [Japan Atomic Energy Agency (Japan); Maruyama, A. [Gunma Prefectural Sewerage Manegement General Office (Japan)

2012-07-01

We have investigated the treatment of endocrine disrupting chemicals (EDCs) and halogented organic compounds (HOCs) in wastewater by ionizing radiation in the CRP. Three samples of the actual wastewater having estrogen activity were analyzed by the yeast two-hybrid assay, enzyme linked immunosorbent assay (ELISA) and total organic carbon (TOC) analysis. Treatment of the wastewater is required to decrease the estrogen activity to less than 1 ng / L; the lower limit concentration of appearance of endocrine disrupting property. Medaka estrogen activity (mEA) initially increased and then decreased by β-ray irradiation, indicating that decomposition products in the real wastewaters also have the estrogen activity. The doses required to decrease in mEA of samples 1 to 3 below 1 ng / L, D{sub 1ng}, were estimated to be 100, 200 and 150 Gy (J kg{sup -1}), respectively. Since the D{sub 1ng} of 17 β-stradiol (E2) at 500 ng/L (1.8 nmol/L) in pure water was estimated to be 5 Gy as mentioned in the previous CRP, the elimination of estrogen activity of real wastewater is considered to be interfered by organic impurities. The economic cost of the treatment process of EDCs using electron beam was estimated at 17 yen m{sup -3}. (author)

Treatment of Wastewater Containing Organic Pollutants by Ionizing Radiation

International Nuclear Information System (INIS)

Kimura, A.; Taguchi, M.; Maruyama, A.

2012-01-01

We have investigated the treatment of endocrine disrupting chemicals (EDCs) and halogented organic compounds (HOCs) in wastewater by ionizing radiation in the CRP. Three samples of the actual wastewater having estrogen activity were analyzed by the yeast two-hybrid assay, enzyme linked immunosorbent assay (ELISA) and total organic carbon (TOC) analysis. Treatment of the wastewater is required to decrease the estrogen activity to less than 1 ng / L; the lower limit concentration of appearance of endocrine disrupting property. Medaka estrogen activity (mEA) initially increased and then decreased by β-ray irradiation, indicating that decomposition products in the real wastewaters also have the estrogen activity. The doses required to decrease in mEA of samples 1 to 3 below 1 ng / L, D 1ng , were estimated to be 100, 200 and 150 Gy (J kg -1 ), respectively. Since the D 1ng of 17 β-stradiol (E2) at 500 ng/L (1.8 nmol/L) in pure water was estimated to be 5 Gy as mentioned in the previous CRP, the elimination of estrogen activity of real wastewater is considered to be interfered by organic impurities. The economic cost of the treatment process of EDCs using electron beam was estimated at 17 yen m -3 . (author)

Contributions of wastewater, runoff and sewer deposit erosion to wet weather pollutant loads in combined sewer systems.

Science.gov (United States)

Gasperi, J; Gromaire, M C; Kafi, M; Moilleron, R; Chebbo, G

2010-12-01

An observatory of urban pollutants was created in Paris for the purpose of assessing the dynamics of wastewater and wet weather flow (WW and WWF) pollutant loads within combined sewers. This observatory is composed of six urban catchments, covering land areas ranging in size from 42 ha to 2581 ha. For a wide array of parameters including total suspended solids (TSS), chemical and biochemical oxygen demand (COD and BOD(5)), total organic carbon (TOC), total Kjeldahl nitrogen (TKN), heavy metals (Cu and Zn) and polycyclic aromatic hydrocarbons (PAHs), this article is intended to evaluate the contributions of wastewater, runoff and in-sewer processes to WWF pollutant loads through the use of an entry-exit mass balance approach. To achieve this objective, a total of 16 rain events were sampled on these sites between May 2003 and February 2006. This study has confirmed that at the considered catchment scale (i.e. from 42 ha to 2581 ha) the production and transfer processes associated with WWF pollutant loads do not vary with basin scale. Entry-exit chemical mass balances over all catchments and for a large number of rain events indicate that wastewater constitutes the main source of organic and nitrogenous pollution, while runoff is the predominant source of Zn. For Cu, PAHs and TSS, the calculation underscores the major role played by in-sewer processes, specifically by sediment erosion, as a source of WWF pollution. A significant loss of dissolved metals was also observed during their transfer within the sewer network, likely as a consequence of the adsorption of dissolved metals on TSS and/or on sewer deposits. Moreover, the nature of eroded particles was examined and compared to the various sewer deposits. This comparison has highlighted that such particles exhibit similar organic and PAH contents to those measured in the organic layer, thus suggesting that the deposit eroded during a wet weather period is organic and of a nature comparable to the organic layer

A combined electrochemical-irradiation treatment of highly colored and polluted industrial wastewater

Energy Technology Data Exchange (ETDEWEB)

Barrera-Diaz, C. E-mail: cbarrera@uaemex.mx; Urena-Nunez, F. E-mail: fun@nuclear.inin.mx; Campos, E.; Palomar-Pardave, M. E-mail: mepp@correo.azc.uam.mx; Romero-Romo, M

2003-07-01

This study reports on the attainment of optimal conditions for two electrolytic methods to treat wastewater: namely, electrocoagulation and particle destabilization of a highly polluted industrial wastewater, and electrochemically induced oxidation induced by in situ generation of Fenton's reactive. Additionally, a combined method that consisted of electrochemical treatment plus {gamma}-irradiation was carried out. A typical composition of the industrial effluent treated was COD 3400 mg/l, color 3750 Pt/Co units, and fecal coliforms 21000 MPN/ml. The best removal efficiency was obtained with electrochemical oxidation induced in situ, that resulted in the reduction of 78% for the COD, 86% color and 99.9% fecal coliforms removal. A treatment sequence was designed and carried out, such that after both electrochemical processes, a {gamma}-irradiation technique was used to complete the procedure. The samples were irradiated with various doses in an ALC {gamma}-cell unit provided with a Co-60 source. The removal efficiency obtained was 95% for the COD values, 90% color and 99.9% for fecal coliforms.

A combined electrochemical-irradiation treatment of highly colored and polluted industrial wastewater

International Nuclear Information System (INIS)

Barrera-Diaz, C.; Urena-Nunez, F.; Campos, E.; Palomar-Pardave, M.; Romero-Romo, M.

2003-01-01

This study reports on the attainment of optimal conditions for two electrolytic methods to treat wastewater: namely, electrocoagulation and particle destabilization of a highly polluted industrial wastewater, and electrochemically induced oxidation induced by in situ generation of Fenton's reactive. Additionally, a combined method that consisted of electrochemical treatment plus γ-irradiation was carried out. A typical composition of the industrial effluent treated was COD 3400 mg/l, color 3750 Pt/Co units, and fecal coliforms 21000 MPN/ml. The best removal efficiency was obtained with electrochemical oxidation induced in situ, that resulted in the reduction of 78% for the COD, 86% color and 99.9% fecal coliforms removal. A treatment sequence was designed and carried out, such that after both electrochemical processes, a γ-irradiation technique was used to complete the procedure. The samples were irradiated with various doses in an ALC γ-cell unit provided with a Co-60 source. The removal efficiency obtained was 95% for the COD values, 90% color and 99.9% for fecal coliforms

A combined electrochemical-irradiation treatment of highly colored and polluted industrial wastewater

Science.gov (United States)

Barrera-Díaz, C.; Ureña-Nuñez, F.; Campos, E.; Palomar-Pardavé, M.; Romero-Romo, M.

2003-07-01

This study reports on the attainment of optimal conditions for two electrolytic methods to treat wastewater: namely, electrocoagulation and particle destabilization of a highly polluted industrial wastewater, and electrochemically induced oxidation induced by in situ generation of Fenton's reactive. Additionally, a combined method that consisted of electrochemical treatment plus γ-irradiation was carried out. A typical composition of the industrial effluent treated was COD 3400 mg/l, color 3750 Pt/Co units, and fecal coliforms 21000 MPN/ml. The best removal efficiency was obtained with electrochemical oxidation induced in situ , that resulted in the reduction of 78% for the COD, 86% color and 99.9% fecal coliforms removal. A treatment sequence was designed and carried out, such that after both electrochemical processes, a γ-irradiation technique was used to complete the procedure. The samples were irradiated with various doses in an ALC γ-cell unit provided with a Co-60 source. The removal efficiency obtained was 95% for the COD values, 90% color and 99.9% for fecal coliforms.

Decomposition Analysis of Wastewater Pollutant Discharges in Industrial Sectors of China (2001–2009 Using the LMDI I Method

Directory of Open Access Journals (Sweden)

Beidou Xi

2012-06-01

Full Text Available China’s industry accounts for 46.8% of the national Gross Domestic Product (GDP and plays an important strategic role in its economic growth. On the other hand, industrial wastewater is also the major source of water pollution. In order to examine the relationship between the underlying driving forces and various environmental indicators, values of two critical industrial wastewater pollutant discharge parameters (Chemical Oxygen Demand (COD and ammonia nitrogen (NH₄-N, between 2001 and 2009, were decomposed into three factors: i.e., production effects (caused by change in the scale of economic activity, structure effects (caused by change in economic structure and intensity effects (caused by change in technological level of each sector, using additive version of the Logarithmic Mean Divisia Index (LMDI I decomposition method. Results showed that: (1 the average annual effect of COD discharges in China was −2.99%, whereas the production effect, the structure effect, and the intensity effect were 14.64%, −1.39%, and −16.24%, respectively. Similarly, the average effect of NH₄-N discharges was −4.03%, while the production effect, the structure effect, and the intensity effect were 16.18%, −2.88%, and −17.33%, respectively; (2 the production effect was the major factor responsible for the increase in COD and NH₄-N discharges, accounting for 45% and 44% of the total contribution, respectively; (3 the intensity effect, which accounted for 50% and 48% of the total contribution, respectively, exerted a dominant decremental effect on COD and NH₄-N discharges; intensity effect was further decomposed into cleaner production effect and pollution abatement effect with the cleaner production effect accounting for 60% and 55% of the reduction of COD and NH₄-N, respectively; (4 the major contributors to incremental COD and NH₄-N discharges were divided among industrial sub

Post-treatment of biologically treated wastewater containing organic contaminants using a sequence of H2O2 based advanced oxidation processes: photolysis and catalytic wet oxidation.

Science.gov (United States)

Rueda-Márquez, J J; Sillanpää, M; Pocostales, P; Acevedo, A; Manzano, M A

2015-03-15

In this paper the feasibility of a multi-barrier treatment (MBT) for the regeneration of synthetic industrial wastewater (SIWW) was evaluated. Industrial pollutants (orange II, phenol, 4-chlorophenol and phenanthrene) were added to the effluent of municipal wastewater treatment plant. The proposed MBT begins with a microfiltration membrane pretreatment (MF), followed by hydrogen peroxide photolysis (H2O2/UVC) and finishing, as a polishing step, with catalytic wet peroxide oxidation (CWPO) using granular activated carbon (GAC) at ambient conditions. During the microfiltration step (0.7 μm) the decrease of suspended solids concentration, turbidity and Escherichia coli in treated water were 88, 94 and 99%, respectively. Also, the effluent's transmittance (254 nm) was increased by 14.7%. Removal of more than 99.9% of all added pollutants, mineralization of 63% of organic compounds and complete disinfection of total coliforms were reached during the H2O2/UVC treatment step (H2O2:TOC w/w ratio = 5 and an UVC average dose accumulated by wastewater 8.80 WUVC s cm(-2)). The power and efficiency of the lamp, the water transmittance and photoreactor geometry are taken into account and a new equation to estimate the accumulated dose in water is suggested. Remaining organic pollutants with a higher oxidation state of carbon atoms (+0.47) and toxic concentration of residual H2O2 were present in the effluent of the H2O2/UVC process. After 2.3 min of contact time with GAC at CWPO step, 90 and 100% of total organic carbon and residual H2O2 were removed, respectively. Also, the wastewater toxicity was studied using Vibrio fischeri and Sparus aurata larvae. The MBT operational and maintenance costs (O&M) was estimated to be 0.59 € m(-3). Copyright © 2015 Elsevier Ltd. All rights reserved.

Pharmaceutical grey water footprint: Accounting, influence of wastewater treatment plants and implications of the reuse.

Science.gov (United States)

Martínez-Alcalá, Isabel; Pellicer-Martínez, Francisco; Fernández-López, Carmen

2018-05-15

first approximation of the dilution that should be applied to the treated wastewater discharges when they are reused for another economic activity that imposes quality restrictions. For the case of agriculture in the Murcia Region, the dilution required is 2 (fresh water) to 1 (treated wastewater), taking into account the pollution thresholds established in this work. Copyright © 2018 Elsevier Ltd. All rights reserved.

Pilot-plant evaluation of TiO2 and TiO2-based hybrid photocatalysts for solar treatment of polluted water.

Science.gov (United States)

Andronic, Luminita; Isac, Luminita; Miralles-Cuevas, Sara; Visa, Maria; Oller, Isabel; Duta, Anca; Malato, Sixto

2016-12-15

Materials with photocatalytic and adsorption properties for advanced wastewater treatment targeting reuse were studied. Making use of TiO 2 as a well-known photocatalyst, Cu 2 S as a Vis-active semiconductor, and fly ash as a good adsorbent, dispersed mixtures/composites were prepared to remove pollutants from wastewater. X-ray diffraction, scanning electron microscopy, energy-dispersive X-Ray spectroscopy, atomic force microscopy, band gap energy, point of zero charge (pH pzc ) and BET porosity were used to characterize the substrates. Phenol, imidacloprid and dichloroacetic acid were used as pollutants for photocatalytic activity of the new photocatalysts. Experiments using the new dispersed powders were carried out at laboratory scale in two solar simulators and under natural solar irradiation at the Plataforma Solar de Almería, in a Compound Parabolic Collector (CPC) for a comparative analysis of pollutants removal and mineralization efficiencies, and to identify features that could facilitate photocatalyst separation and reuse. The results show that radiation intensity significantly affects the phenol degradation rate. The composite mixture of TiO 2 and fly ash is 2-3 times less active than sol-gel TiO 2 . Photodegradation kinetic data on the highly active TiO 2 are compared for pollutants elimination. Photodegradation of dichloroacetic acid was fast and complete after 90min in the CPC, while after 150min imidacloprid and phenol removal was 90% and 56% respectively. Copyright © 2016 Elsevier B.V. All rights reserved.

Pilot-plant evaluation of TiO_2 and TiO_2-based hybrid photocatalysts for solar treatment of polluted water

International Nuclear Information System (INIS)

Andronic, Luminita; Isac, Luminita; Miralles-Cuevas, Sara; Visa, Maria; Oller, Isabel; Duta, Anca; Malato, Sixto

2016-01-01

Materials with photocatalytic and adsorption properties for advanced wastewater treatment targeting reuse were studied. Making use of TiO_2 as a well-known photocatalyst, Cu_2S as a Vis-active semiconductor, and fly ash as a good adsorbent, dispersed mixtures/composites were prepared to remove pollutants from wastewater. X-ray diffraction, scanning electron microscopy, energy-dispersive X-Ray spectroscopy, atomic force microscopy, band gap energy, point of zero charge (pH_p_z_c) and BET porosity were used to characterize the substrates. Phenol, imidacloprid and dichloroacetic acid were used as pollutants for photocatalytic activity of the new photocatalysts. Experiments using the new dispersed powders were carried out at laboratory scale in two solar simulators and under natural solar irradiation at the Plataforma Solar de Almería, in a Compound Parabolic Collector (CPC) for a comparative analysis of pollutants removal and mineralization efficiencies, and to identify features that could facilitate photocatalyst separation and reuse. The results show that radiation intensity significantly affects the phenol degradation rate. The composite mixture of TiO_2 and fly ash is 2-3 times less active than sol-gel TiO_2. Photodegradation kinetic data on the highly active TiO_2 are compared for pollutants elimination. Photodegradation of dichloroacetic acid was fast and complete after 90 min in the CPC, while after 150 min imidacloprid and phenol removal was 90% and 56% respectively.

Treatment Of Wastewater For Reuse With Mobile Electron Beam Plant

Energy Technology Data Exchange (ETDEWEB)

Han, B.; Kim, J. K.; Kim, Y. R. [EB TECH Co., Ltd., Daejeon (Korea, Republic of); Zommer, N. [Pele Inc., Milpitas Californaa (United States)

2012-07-01

The use of alternative disinfectants to chlorine for the wastewater treatment has received increasing attention in recent years to treat either liquid or solids streams within wastewater treatment plants for pathogens and trace organics (TOrCs). Although several technologies have come to the forefront as an alternative to chlorine (e.g., ultraviolet [UV] and hydrogen peroxide), the majority of these technologies are chemically based, with the exception of UV. An attractive physical disinfection approach is by electron beam (EB) irradiation. EB treatment of wastewater leads to their purification from various pollutants. It is caused by the decomposition of pollutants as a result of their reactions with highly reactive species formed from water radiolysis: hydrated electron, OH free radical and H atom [Pikaev (1986)]. Sometimes methods such as EB with biological treatment, adsorption and others improve the effect of EB treatment of the wastewater purification. In the process of EB treatment of wastewater there are utilized chemical transformations of pollutants induced by ionizing radiation. At sufficiently high absorbed doses these transformations can result in complete decomposition (removal) of the substance. Under real conditions, i.e., at rather high content of pollutants in a wastewater and economically acceptable doses, partial decomposition of pollutant takes place as well as transformations of pollutant molecules that result in improving subsequent purification stages, efficiency of the process being notably influenced by irradiation conditions and wastewater composition [Woods and Pikaev (1994)]. (author)

Treatment Of Wastewater For Reuse With Mobile Electron Beam Plant

International Nuclear Information System (INIS)

Han, B.; Kim, J.K.; Kim, Y.R.; Zommer, N.

2012-01-01

The use of alternative disinfectants to chlorine for the wastewater treatment has received increasing attention in recent years to treat either liquid or solids streams within wastewater treatment plants for pathogens and trace organics (TOrCs). Although several technologies have come to the forefront as an alternative to chlorine (e.g., ultraviolet [UV] and hydrogen peroxide), the majority of these technologies are chemically based, with the exception of UV. An attractive physical disinfection approach is by electron beam (EB) irradiation. EB treatment of wastewater leads to their purification from various pollutants. It is caused by the decomposition of pollutants as a result of their reactions with highly reactive species formed from water radiolysis: hydrated electron, OH free radical and H atom [Pikaev (1986)]. Sometimes methods such as EB with biological treatment, adsorption and others improve the effect of EB treatment of the wastewater purification. In the process of EB treatment of wastewater there are utilized chemical transformations of pollutants induced by ionizing radiation. At sufficiently high absorbed doses these transformations can result in complete decomposition (removal) of the substance. Under real conditions, i.e., at rather high content of pollutants in a wastewater and economically acceptable doses, partial decomposition of pollutant takes place as well as transformations of pollutant molecules that result in improving subsequent purification stages, efficiency of the process being notably influenced by irradiation conditions and wastewater composition [Woods and Pikaev (1994)]. (author)

Characteristics of microbial community functional structure of a biological coking wastewater treatment system.

Science.gov (United States)

Joshi, Dev Raj; Zhang, Yu; Zhang, Hong; Gao, Yingxin; Yang, Min

2018-01-01

Nitrogenous heterocyclic compounds are key pollutants in coking wastewater; however, the functional potential of microbial communities for biodegradation of such contaminants during biological treatment is still elusive. Herein, a high throughput functional gene array (GeoChip 5.0) in combination with Illumina HiSeq2500 sequencing was used to compare and characterize the microbial community functional structure in a long run (500days) bench scale bioreactor treating coking wastewater, with a control system treating synthetic wastewater. Despite the inhibitory toxic pollutants, GeoChip 5.0 detected almost all key functional gene (average 61,940 genes) categories in the coking wastewater sludge. With higher abundance, aromatic ring cleavage dioxygenase genes including multi ring1,2diox; one ring2,3diox; catechol represented significant functional potential for degradation of aromatic pollutants which was further confirmed by Illumina HiSeq2500 analysis results. Response ratio analysis revealed that three nitrogenous compound degrading genes- nbzA (nitro-aromatics), tdnB (aniline), and scnABC (thiocyanate) were unique for coking wastewater treatment, which might be strong cause to increase ammonia level during the aerobic process. Additionally, HiSeq2500 elucidated carbozole and isoquinoline degradation genes in the system. These findings expanded our understanding on functional potential of microbial communities to remove organic nitrogenous pollutants; hence it will be useful in optimization strategies for biological treatment of coking wastewater. Copyright © 2017. Published by Elsevier B.V.

Life Cycle Assessment of urban wastewater reuse with ozonation as tertiary treatment

International Nuclear Information System (INIS)

Munoz, Ivan; Rodriguez, Antonio; Rosal, Roberto; Fernandez-Alba, Amadeo R.

2009-01-01

Life Cycle Assessment has been used to compare different scenarios involving wastewater reuse, with special focus on toxicity-related impact categories. The study is based on bench-scale experiments applying ozone and ozone in combination with hydrogen peroxide to a wastewater effluent from a Spanish sewage treatment plant. Two alternative characterisation models have been used to account for toxicity of chemical substances, namely USES-LCA and EDIP97. Four alternative scenarios have been assessed: wastewater discharge plus desalination supply, wastewater reuse without tertiary treatment, wastewater reuse after applying a tertiary treatment consisting on ozonation, and wastewater reuse after applying ozonation in combination with hydrogen peroxide. The results highlight the importance of including wastewater pollutants in LCA of wastewater systems assessing toxicity, since the contribution of wastewater pollutants to the overall toxicity scores in this case study can be above 90%. Key pollutants here are not only heavy metals and other priority pollutants, but also non-regulated pollutants such as pharmaceuticals and personal care products. Wastewater reuse after applying any of the tertiary treatments considered appears as the best choice from an ecotoxicity perspective. As for human toxicity, differences between scenarios are smaller, and taking into account the experimental and modelling uncertainty, the benefits of tertiary treatment are not so clear. From a global warming potential perspective, tertiary treatments involve a potential 85% reduction of greenhouse gas emissions when compared with desalination

Degradation Of Aggregate Pollutant In Textiles Wastewater By Electron Beam Irradiation

International Nuclear Information System (INIS)

Khomsaton Abu Bakar; Zulkafli Ghazali; Siti Aiasah Hashim; Selambakkannu, S.; Ming, T.T.; Natasha Isnin; Hasnul Nizam Osman; Khasmidatul Akma Mohd Khairul Azmi

2016-01-01

Aggregate pollutant were refer to the mixture of the excess material that is used in the manufacturing proses of textiles, present in wastewater. This paper studies the effect of the beam energy, beam current and absorbed dose on degradation of aggregate pollutant in textiles effluent which was indicate by COD, pH and UV-Vis spectrum. The impact of beam energy was conducted when sample were exposed to the irradiation at various beam energy (1 to 3 MeV) at 20 mA and 17 kGy. The COD reduced from 495 mg/l to the range 398.00 -358 mg/l at beam energy 1 MeV to 3 MeV. The irradiated sample also slightly become more acidic at higher beam energy. While 1 MeV beam energy was sufficient to eliminate the exposed peak at wavelength of 425 nm, 550 nm and 650 nm in the UV spectrum. In the case effect of current, the COD effluent tested at constant beam energy of 1 MeV and 3 MeV at various beam current (3 mA, 5 mA, 10 mA, 15 mA and 20 mA) decreased with higher beam current. While interested peak in UV spectrum of irradiated samples was varnish at 3 mA beam current and 1 MeV energy applied. Considering to the 19.66 % COD removal and electric power used, 1 MeV beam energy and 20 mA beam current was the optimum irradiation parameter selected for this study. At 1 MeV:20 mA textiles wastewater irradiated at various dose of 17, 20, 25, 30, 35, 100 and 200 kGy shows removal of COD, were in the range 4.42 % - 30.09 %. (author)

Affects of wastewater discharge from mining on soil heavy metal pollution and enzyme activities in northern Hunan province, Central South China

Science.gov (United States)

Jiang, Ying; Hu, Xue-Feng; Shu, Ying; Yan, Xiao-Juan; Luo, Fan

2013-04-01

Hunan province, Central South China, is rich in mineral resources and also a well-known nonferrous metal base in China. Mining and ore processing there, however, are mostly conducted in indigenous methods, and thus causing heavy metal pollution of abundant farmland. Situated in northern Hunan province, Y county has antimony, manganese, vanadium, and pyrite mines, but still belongs to a region of rice cultivation, of which, paddy fields make up 84.5% of the total farmland. Our investigations found that irrigation water is threatened by the release of mining wastewater in the county. For example, a stream used for irrigation turns dark-red after long-term receiving wastewater discharged from a pyrite company at HS Town of the county. Concentrations of Cu, Zn, Cd, Fe and Mn in the stream water reach 0.03 mg kg-1, 2.14 mg kg-1, 0.02 mg kg-1, 96.0 mg kg-1 and 11.5 mg kg-1, respectively; these in the paddy soils nearby are 67.3 mg kg-1, 297 mg kg-1, 4.0 mg kg-1, 33.1 mg g-1 and 463 mg kg-1 on average, respectively, with a maximum of Cd reaching 16.8 mg kg-1. Microbial biomass and activities are significantly reduced by metal toxicity in the soils. The counts of fungal, actinomycin and bacterial colonies in the polluted soils are 8.8×103 /g (Fresh soil), 4.9×105 /g (Fresh soil) and 6.4×105 /g (Fresh soil), respectively, which are only 4.68%, 10.3% and 20.9% of these in non-polluted soils in Y county, respectively. Likewise, the microbial biomass (MB) - C and MB - N of the polluted soils are only 36.8% and 50.3% of these in the non-polluted, respectively. The activities of dehydrogenase, urease, catalase, acid and neutral phosphatase and sucrase in the polluted soils are only 41.2%, 49.8%, 56.8%, 69.9%, 80.7% and 81.0% of these in the non-polluted, respectively. There are significant negative correlations between Cu, Zn and Cd contents and the activities of dehydrogenase and catalase, suggesting that the two enzymes are the most sensitive to heavy metal toxicity in the

Pollution prevention applications in batch manufacturing operations

Science.gov (United States)

Sykes, Derek W.; O'Shaughnessy, James

2004-02-01

Older, "low-tech" batch manufacturing operations are often fertile grounds for gains resulting from pollution prevention techniques. This paper presents a pollution prevention technique utilized for wastewater discharge permit compliance purposes at a batch manufacturer of detergents, deodorants, and floor-care products. This manufacturer generated industrial wastewater as a result of equipment rinses required after each product batch changeover. After investing a significant amount of capital on end of pip-line wastewater treatment technology designed to address existing discharge limits, this manufacturer chose to investigate alternate, low-cost approaches to address anticipated new permit limits. Mass balances using spreadsheets and readily available formulation and production data were conducted on over 300 products to determine how each individual product contributed to the total wastewater pollutant load. These mass balances indicated that 22 products accounted for over 55% of the wastewater pollutant. Laboratory tests were conducted to determine whether these same products could accept their individual changeover rinse water as make-up water in formulations without sacrificing product quality. This changeover reuse technique was then implement at the plant scale for selected products. Significant reductions in wastewater volume (25%) and wastewater pollutant loading (85+%) were realized as a direct result of this approach.

Comparing wastewater chemicals, indicator bacteria concentrations, and bacterial pathogen genes as fecal pollution indicators

Science.gov (United States)

Haack, S.K.; Duris, J.W.; Fogarty, L.R.; Kolpin, D.W.; Focazio, M.J.; Furlong, E.T.; Meyer, M.T.

2009-01-01

The objective of this study was to compare fecal indicator bacteria (FIB) (fecal coliforms, Escherichia coli [EC], and enterococci [ENT]) concentrations with a wide array of typical organic wastewater chemicals and selected bacterial genes as indicators of fecal pollution in water samples collected at or near 18 surface water drinking water intakes. Genes tested included esp (indicating human-pathogenic ENT) and nine genes associated with various animal sources of shiga-toxin-producing EC (STEC). Fecal pollution was indicated by genes and/or chemicals for 14 of the 18 tested samples, with little relation to FIB standards. Of 13 samples with animal sources of STEC) were detected in eight. Only the EC eaeA gene was positively correlated with FIB concentrations. Human-source fecal pollution was indicated by the esp gene and the human pharmaceutical carbamazepine in one of the nine samples that met all FIB recreational water quality standards. Escherichia coli rfbO157 and stx2c genes, which are typically associated with cattle sources and are of potential human health significance, were detected in one sample in the absence of tested chemicals. Chemical and gene-based indicators of fecal contamination may be present even when FIB standards are met, and some may, unlike FIB, indicate potential sources. Application of multiple water quality indicators with variable environmental persistence and fate may yield greater confidence in fecal pollution assessment and may inform remediation decisions. Copyright ?? 2009 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America. All rights reserved.

Construction and Operation Costs of Wastewater Treatment and Implications for the Paper Industry in China.

Science.gov (United States)

Niu, Kunyu; Wu, Jian; Yu, Fang; Guo, Jingli

2016-11-15

This paper aims to develop a construction and operation cost model of wastewater treatment for the paper industry in China and explores the main factors that determine these costs. Previous models mainly involved factors relating to the treatment scale and efficiency of treatment facilities for deriving the cost function. We considered the factors more comprehensively by adding a regional variable to represent the economic development level, a corporate ownership factor to represent the plant characteristics, a subsector variable to capture pollutant characteristics, and a detailed-classification technology variable. We applied a unique data set from a national pollution source census for the model simulation. The major findings include the following: (1) Wastewater treatment costs in the paper industry are determined by scale, technology, degree of treatment, ownership, and regional factors; (2) Wastewater treatment costs show a large decreasing scale effect; (3) The current level of pollutant discharge fees is far lower than the marginal treatment costs for meeting the wastewater discharge standard. Key implications are as follows: (1) Cost characteristics and impact factors should be fully recognized when planning or making policies relating to wastewater treatment projects or technology development; (2) There is potential to reduce treatment costs by centralizing wastewater treatment via industrial parks; (3) Wastewater discharge fee rates should be increased; (4) Energy efficient technology should become the future focus of wastewater treatment.

RECENT ADVANCES IN LEATHER TANNERY WASTEWATER TREATMENT

Directory of Open Access Journals (Sweden)

LOFRANO Giusy

2016-05-01

Full Text Available The tannery industry is one of the most important economic sectors in many countries, representing an important economic field also in developing countries. Leather tannery industry is water intensive and originates highly polluted wastewater that contain various micropollutants raising environmental and health concerns. Tannery wastewater is difficult to treat biologically because of complex characteristics like high salinity e high content of xenobiotics compounds. After conventional treatment (i.e., chromium precipitation–primary sedimentation–biological oxidation–secondary sedimentation, effluents still do not meet the required limits, at least for some parameters such as BOD, COD, salinity, ammonia and surfactants. The leather industry is being pressured to search cleaner, economically as well as environmentally friendly wastewater treatment technologies alternative or integrative to the conventional treatment in order to face the challenge of sustainability. The most spread approach to manage tannery wastewater is the steam segregation before conveying wastewaters to in treatment plants that typically include pre-treatment, mechanical and physico-chemical treatment, biological treatment, and treatment of the generated sludge. Thus proper treatment technologies are needed to handle tannery wastewater to remove effectively the environmental benign pollutants. However among various processes applied or proposed the sustainable technologies are emerging concern. This paper, as the-state-of-the-art, attempts to revise the over world trends of treatment technologies and advances for pollution prevention from tannery chemicals and wastewater.

High power accelerators and wastewater treatment

International Nuclear Information System (INIS)

Han, B.; Kim, J.K.; Kim, Y.R.; Kim, S.M.; Makaov, I.E.; Ponomarev, A.V.

2006-01-01

The problems of environmental damage and degradation of natural resources are receiving increasing attention throughout the world. The increased population, higher living standards, increased urbanization and enhanced industrial activities of humankind are all leading to degradation of the environment. Increasing urbanization has been accompanied by significant water pollution. Given the seriousness of the situation and future risk of crises, there is an urgent need to develop the water-efficient technologies including economical treatment methods of wastewater and polluted water. Therefore, cost-effective treatment of the municipal and industrial wastewater containing refractory pollutant with electron beam is actively studied in EB TECH Co.. Electron beam treatment of wastewater is caused by the decomposition of pollutants as a result of their reactions with highly reactive species formed from water radiolysis (hydrated electron, OH free radical and H atom). However, to have advantages over existing processes, the electron beam process should have cost-effective and reliable in operation. Therefore high power accelerators (400kW∼1MW) are developed for environmental application and they show the decrease in the cost of construction and operation of electron beam plant. In other way to reduce the cost for wastewater treatment, radical reactions accompanied by the other processes are introduced, and the synergistic effect upon the use of combined methods such as electron beam treatment with ozonation, biological treatment and physico-chemical adsorption and others also show the improvement of the effect of electron beam treatment for the wastewater purification. (author)

Review of wastewater problems and wastewater-management planning in the San Francisco Bay region, California

Science.gov (United States)

Hines, Walter G.

1973-01-01

The San Francisco Bay region has suffered adverse environmental effects related to the discharge of municipal-, industrial-, and agricultural- wastewater and storm-water runoff. Specific pollutional properties of theses discharges are not well understood in all cases although the toxic materials and aquatic-plant nutrients (biostimulants) found in municipal and industrial waterwater are considered to be a major cause of regional water-quality problems. Other water-quality problems in the region are commonly attributed to pesticides found in agricultural wastewater and potentially pathogenic bacteria in municipal-wastewater discharges and in storm-water runoff. The geographical distribution and magnitude of wastewater discharges in the bay region, particularly those from municipalities and industries, is largely a function of population, economic growth, and urban development. As might be expected, the total volume of wastewater has increased in a trend paralleling this growth and development. More significant, perhaps, is the fact that the total volume parameters such as BOD (biochemical oxygen demand), biostimulant concentrations, and toxicity, has increased despite large expenditures on new and improved municipal- and industrial-wastewater-treatment plants. Also, pollutant loadings from other major source, such as agriculture and storm-water runoff, have increased. At the time of writing (1972), many Federal, State, regional, and local agencies are engaged in a comprehensive wastewater-management-planning effort for the entire bay region. Initial objectives of this planning effort are: (1) the consolidation and coordination of loosely integrated wastewater-management facilities and (2) the elimination of wastewater discharges to ecologically sensitive areas, such as fresh-water streams and shallow extremities of San Francisco Bay. There has been some investigation of potential long-range wastewater-management alternatives based upon disposal in deep water in the

[The Influence of Runoff Pollution to DOM Features in an Urban Wastewater Treatment Plant].

Science.gov (United States)

He, Li; Ji, Fang-ying; Lai, Ming-sheng; Xu, Xuan; Zhou, Wei-wei; Mao, Bo-lin; Yang, Ming-jia

2015-03-01

Combined with wastewater treatment process, the sewage in sunny and rainy day was collected from a wastewater treatment plant in Chongqing. Three-dimensional fluorescence spectra was used to investigate the characteristic fluorescence of dissolved organic matter (DOM). DOM dissolved organic carbon (DOC), chemical oxygen demand (COD), fluorescence index (ƒ450/500) and fluorescence intensity ratio γ (A, C) of fulvic acid in ultraviolet and visible region were used to analyze the impact of rain runoff pollution on sewage DOM. According to the experimental data, the DOM fluorescence fingerprints of this wastewater treatment plant were quite different from typical municipal sewage, and the main component was tryptophan with low excitation wavelength (Peak S), then the tryptophan with long wavelength excitation (Peak T) followed. A2/O process had an approximative degradation of the protein-like both in sunny day and rainy day, but had a better degradation of fulvic-like, DOC and COD in rainy day than that in sunny day. Morever, the fluorescence peaks got red-shifted after the biological treatment. The differences of DOM fluorescence fingerprint between sunny and rainy day were significant, the fluorescence center of UV fulvic (Peak A) in rainy day getting blue-shifted obviously, shifting from 240 - 248/390 - 440 to 240 - 250/370 - 400 nm. Although the DOM types in sunny and rainy day were the same, the source of fulvic got more complex by runoff and the component ratio of DOM also changed. Compared with the sunny day, the proportion of Peak S in DOM dereased by 10%, and the proportion of Peak A increased by 7% in rainy day.

Biodegradation of Pollutants from Winery wastewater by Using Fungi Aspergillus fumigatus and Bacterium Bacillus subtilis

OpenAIRE

, C.S. Mahajan; , D.V. Patil; , D.B. Sarode; , R.N. Jadhav; , S.B. Attarde

2012-01-01

Aspergillus fumigatus was used as fungal strain and Bacillus subtilis was used as bacterial species for the biodegradation of winery wastewater pollutants. The fungal strain and bacterial species was allowed to grow on PDA and NA slant. Loop full of both fungal and bacterial culture was inoculated and incubated at room temperature for 7 days. After the incubation the sample was filtered and analyzed for the chemical characteristics to verify the degradation capacity of both species,after trea...

The improvement of removal effects on organic pollutants in Wastewater Treatment Plants (WWTP)

International Nuclear Information System (INIS)

Marincas, O; Avram, V; Moldovan, Z; Petrov, P; Ternes, T

2009-01-01

Purpose of this study is to improve the efficiency of removal in wastewater treatment plants of some organic pollutants like pharmaceuticals, antioxidants, pesticides (triazines, phenylurea herbicides), personal care products (PCPs) musk fragrances (galaxolide and tonalide) and estrogens using zeolites with excellent absorption capacity. The zeolite selected for all experiments was Szedimentin-MW. The experiment took place in three stages: no zeolite addition, zeolite added at the end of the bioreactor and zeolite added at the start of the bioreactor. The water samples were pre-concentrated with solid phase extraction (SPE) procedure and analyzed with analytical system Gas Chromatography/Mass Spectrometry (GC/MS).

The improvement of removal effects on organic pollutants in Wastewater Treatment Plants (WWTP)

Energy Technology Data Exchange (ETDEWEB)

Marincas, O; Avram, V; Moldovan, Z [National Institute for Research and Development of Isotopic and Molecular Technologies, 65-103 Donath, 400293 Cluj-Napoca (Romania); Petrov, P [Water Treatment Station Siluet B, 21 Pencho Slaveikov Street, Varna 9000 (Bulgaria); Ternes, T, E-mail: olivian.marincas@itim-cj.r [Federal Institute of Hydrology, Am Mainzer Tor 1, 56068 Koblenz (Germany)

2009-08-01

Purpose of this study is to improve the efficiency of removal in wastewater treatment plants of some organic pollutants like pharmaceuticals, antioxidants, pesticides (triazines, phenylurea herbicides), personal care products (PCPs) musk fragrances (galaxolide and tonalide) and estrogens using zeolites with excellent absorption capacity. The zeolite selected for all experiments was Szedimentin-MW. The experiment took place in three stages: no zeolite addition, zeolite added at the end of the bioreactor and zeolite added at the start of the bioreactor. The water samples were pre-concentrated with solid phase extraction (SPE) procedure and analyzed with analytical system Gas Chromatography/Mass Spectrometry (GC/MS).

Coagulation and Adsorption Treatment of Printing Ink Wastewater

Directory of Open Access Journals (Sweden)

Maja Klančnik

2015-03-01

Full Text Available The intention of the study was to improve the efficiency of total organic carbon (TOC and colour removal from the wastewater samples polluted with flexographic printing ink following coagulation treatments with further adsorption onto activated carbons and ground orange peel. The treatment efficiencies were compared to those of further flocculation treatments and of coagulation and adsorption processes individually. Coagulation was a relatively effective single-treatment method, removing 99.7% of the colour and 86.9% of the organic substances (TOC from the printing ink wastewater samples. Further flocculation did not further eliminate organic pollutants, whereas subsequent adsorption with 7 g/l of granular activated carbon further reduced organic substances by 35.1%, and adsorption with 7 g/l of powdered activated carbon further reduced organic substances by 59.3%. Orange peel was an inappropriate adsorbent for wastewater samples with low amounts of pollution, such as water that had been treated by coagulation. However, in highly polluted printing ink wastewater samples, the adsorption treatment with ground orange peel achieved efficiencies comparable to those of the granular activated carbon treatments.

Reuse of spent granular activated carbon for organic micro-pollutant removal from treated wastewater.

Science.gov (United States)

Hu, Jingyi; Shang, Ran; Heijman, Bas; Rietveld, Luuk

2015-09-01

Spent granular activated carbons (sGACs) for drinking water treatments were reused via pulverizing as low-cost adsorbents for micro-pollutant adsorption from a secondary treated wastewater effluent. The changes of physicochemical characteristics of the spent carbons in relation to the fresh carbons were determined and were correlated to the molecular properties of the respective GAC influents (i.e. a surface water and a groundwater). Pore size distribution analysis showed that the carbon pore volume decreased over a wider size range due to preloading by surface water, which contains a broader molecular weight distribution of organic matter in contrast to the groundwater. However, there was still considerable capacity available on the pulverized sGACs for atrazine adsorption in demineralized water and secondary effluent, and this was particularly the case for the groundwater spent GAC. However, as compared to the fresh counterparts, the decreased surface area and the induced surface acidic groups on the pulverized sGACs contributed both to the lower uptake and the more impeded adsorption kinetic of atrazine in the demineralized water. Nonetheless, the pulverized sGACs, especially the one preloaded by surface water, was less susceptible to adsorption competition in the secondary effluent, due to its negatively charged surface which can repulse the accessibility of the co-present organic matter. This suggests the reusability of the drinking water spent GACs for micro-pollutant adsorption in the treated wastewater. Copyright © 2015 Elsevier Ltd. All rights reserved.

Pilot-plant evaluation of TiO{sub 2} and TiO{sub 2}-based hybrid photocatalysts for solar treatment of polluted water

Energy Technology Data Exchange (ETDEWEB)

Andronic, Luminita, E-mail: andronic-luminita@unitbv.ro [Transilvania University of Brasov, Centre of Renewable Energy Systems and Recycling, Romania, Eroilor, 29, 500036, Brasov (Romania); Isac, Luminita [Transilvania University of Brasov, Centre of Renewable Energy Systems and Recycling, Romania, Eroilor, 29, 500036, Brasov (Romania); Miralles-Cuevas, Sara [Laboratory for Environmental Research in Arid Zones, LIMZA, School of Mechanical Engineering, University of Tarapaca, Arica (Chile); Visa, Maria [Transilvania University of Brasov, Centre of Renewable Energy Systems and Recycling, Romania, Eroilor, 29, 500036, Brasov (Romania); Oller, Isabel [Plataforma Solar de Almería, CIEMAT, P.O. Box 22, 04200 Tabernas, Almería (Spain); CIESOL, Joint Centre of the University of Almería-CIEMAT, 04120 Almería (Spain); Duta, Anca, E-mail: a.duta@unitbv.ro [Transilvania University of Brasov, Centre of Renewable Energy Systems and Recycling, Romania, Eroilor, 29, 500036, Brasov (Romania); Malato, Sixto [Plataforma Solar de Almería, CIEMAT, P.O. Box 22, 04200 Tabernas, Almería (Spain); CIESOL, Joint Centre of the University of Almería-CIEMAT, 04120 Almería (Spain)

2016-12-15

Materials with photocatalytic and adsorption properties for advanced wastewater treatment targeting reuse were studied. Making use of TiO{sub 2} as a well-known photocatalyst, Cu{sub 2}S as a Vis-active semiconductor, and fly ash as a good adsorbent, dispersed mixtures/composites were prepared to remove pollutants from wastewater. X-ray diffraction, scanning electron microscopy, energy-dispersive X-Ray spectroscopy, atomic force microscopy, band gap energy, point of zero charge (pH{sub pzc}) and BET porosity were used to characterize the substrates. Phenol, imidacloprid and dichloroacetic acid were used as pollutants for photocatalytic activity of the new photocatalysts. Experiments using the new dispersed powders were carried out at laboratory scale in two solar simulators and under natural solar irradiation at the Plataforma Solar de Almería, in a Compound Parabolic Collector (CPC) for a comparative analysis of pollutants removal and mineralization efficiencies, and to identify features that could facilitate photocatalyst separation and reuse. The results show that radiation intensity significantly affects the phenol degradation rate. The composite mixture of TiO{sub 2} and fly ash is 2-3 times less active than sol-gel TiO{sub 2}. Photodegradation kinetic data on the highly active TiO{sub 2} are compared for pollutants elimination. Photodegradation of dichloroacetic acid was fast and complete after 90 min in the CPC, while after 150 min imidacloprid and phenol removal was 90% and 56% respectively.

Physicochemical Characteristic of Municipal Wastewater in Tropical Area: Case Study of Surabaya City, Indonesia

Science.gov (United States)

Wijaya, I. M. W.; Soedjono, E. S.

2018-03-01

Municipal wastewater is the main contributor to diverse water pollution problems. In order to prevent the pollution risks, wastewater have to be treated before discharged to the main water. Selection of appropriated treatment process need the characteristic information of wastewater as design consideration. This study aims to analyse the physicochemical characteristic of municipal wastewater from inlet and outlet of ABR unit around Surabaya City. Medokan Semampir and Genteng Candi Rejo has been selected as wastewater sampling point. The samples were analysed in laboratory with parameters, such as pH, TSS, COD, BOD, NH4 +, NO3 -, NO2 -, P, and detergent. The results showed that all parameters in both locations are under the national standard of discharged water quality. In other words, the treated water is securely discharged to the river

Wastewater Industrial Contributors

Data.gov (United States)

Iowa State University GIS Support and Research Facility — Industrial contributors to municipal wastewater treatment facilities in Iowa for the National Pollutant Discharge Elimination System (NPDES) program.

Disinfection of septic tank and cesspool wastewater with peracetic acid.

Science.gov (United States)

Heinonen-Tanski, Helvi; Savolainen, Ritva

2003-08-01

Wastewaters of private household septic tanks and cesspools have been treated with peracetic acid (1-2 g L(-1)). Adding 1 g L(-1) peracetic acid to wastewaters was easy and has been found to be effective in destroying enteric indicator microorganisms. The careful mixing of peracetic acid and wastewater was found to be important. Winter periods with frozen soil, ice and snow did not constitute extra problems. The bad smell of these wastewaters almost totally disappeared during the treatment. When wastewaters treated with peracetic acid were emptied into animal slurry tanks, hygienization still continued in the mixture of animal slurry and the wastewaters. These wastewaters could thus be released into agricultural soil without risk of microbiological pollution to groundwaters.

Sequential micro and ultrafiltration of distillery wastewater

Directory of Open Access Journals (Sweden)

Vasić Vesna M.

2015-01-01

Full Text Available Water reuse and recycling, wastewater treatment, drinking water production and environmental protection are the key challenges for the future of our planet. Membrane separation technologies for the removal of all suspended solids and a fraction of dissolved solids from wastewaters, are becoming more and more promising. Also, these processes are playing a major role in wastewater purification systems because of their high potential for recovery of water from many industrial wastewaters. The aim of this work was to evaluate the application of micro and ultrafiltration for distillery wastewater purification in order to produce water suitable for reuse in the bioethanol industry. The results of the analyses of the permeate obtained after micro and ultrafiltration showed that the content of pollutants in distillery wastewater was significantly reduced. The removal efficiency for chemical oxygen demand, dry matter and total nitrogen was 90%, 99.2% and 99.9%, respectively. Suspended solids were completely removed from the stillage.

Wastewater Treatment Facilities

Data.gov (United States)

Iowa State University GIS Support and Research Facility — Individual permits for municipal, industrial, and semi-public wastewater treatment facilities in Iowa for the National Pollutant Discharge Elimination System (NPDES)...

Wastewater Treatment Plants

Data.gov (United States)

Iowa State University GIS Support and Research Facility — The actual treatment areas for municipal, industrial, and semi-public wastewater treatment facilities in Iowa for the National Pollutant Discharge Elimination System...

Utilization of portable effluent wastewater in brick manufacturing

International Nuclear Information System (INIS)

EI-Mahllawy, M.S.; El-Sokkary, T.M.

2005-01-01

Portable wastewater is produced from sedimentation and filtration tanks in portable water treatment plants. Usually, this useless wastewater is drained into River Nile Canal and not to the sewer system causing a potential pollution. Wastewater has been taken from Portable Treatment Plant located at Qalubia Province, Delta, Egypt. Evaluation of raw materials was carried out by using X-ray diffraction (XRD), X-ray fluorescence (XRF), thermal analyses (DTA and TGA) as well as plasticity and drying sensitivity coefficient (DSC) measurements. Technological properties of fired bricks were investigated according to Egyptian and American Specifications. The obtained experimental results encourage substitution of the drained portable wastewater for the tap water in bricks manufacturing. Thus, utilization of the studied portable effluent wastewater in such industry is possible and fulfills the double target of saving drinking water used in clay bricks manufacturing, rather than its environmental pollution prevention. Keywords: Portable wastewater, tap water, clay building bricks, physicomechanical properties

Polyvinyl alcohol-immobilized Phanerochaete chrysosporium and its application in the bioremediation of composite-polluted wastewater

Energy Technology Data Exchange (ETDEWEB)

Huang, Zhenzhen [College of Environmental Science and Engineering, Hunan University, Changsha 410082 (China); Key Laboratory of Environmental Biology and Pollution Control (Hunan University), Ministry of Education, Changsha 410082 (China); Chen, Guiqiu, E-mail: gqchen@hnu.edu.cn [College of Environmental Science and Engineering, Hunan University, Changsha 410082 (China); Key Laboratory of Environmental Biology and Pollution Control (Hunan University), Ministry of Education, Changsha 410082 (China); Zeng, Guangming, E-mail: zgming@hnu.edu.cn [College of Environmental Science and Engineering, Hunan University, Changsha 410082 (China); Key Laboratory of Environmental Biology and Pollution Control (Hunan University), Ministry of Education, Changsha 410082 (China); Chen, Anwei [College of Resources and Environment, Hunan Agricultural University, Changsha 410128 (China); Zuo, Yanan; Guo, Zhi; Tan, Qiong [College of Environmental Science and Engineering, Hunan University, Changsha 410082 (China); Key Laboratory of Environmental Biology and Pollution Control (Hunan University), Ministry of Education, Changsha 410082 (China); Song, Zhongxian [Faculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming 650500 (China); Niu, Qiuya [College of Environmental Science and Engineering, Hunan University, Changsha 410082 (China); Key Laboratory of Environmental Biology and Pollution Control (Hunan University), Ministry of Education, Changsha 410082 (China)

2015-05-30

Graphical abstract: Schematic diagram of polyvinyl alcohol-immobilized Phanerochaete chrysosporium beads (PPBs) for Cd(II) removal and 2,4-DCP degradation. - Highlights: • PVA-immobilized P. chrysosporium beads (PPBs) were fit for wastewater treatment. • Removal rates of Cd(II) and 2,4-DCP at optimum conditions were up to 78% and 95.4%. • 2,4-DCP removal rates were beyond 90% with varying initial 2,4-DCP concentrations. • PVA was vital to Cd(II) removal besides the function groups in P. chrysosporium. • Maximum recovery of the Cd(II)-laden PPBs after reuse three times was 98.9%. - Abstract: A novel biosorbent, polyvinyl alcohol (PVA)-immobilized Phanerochaete chrysosporium, was applied to the bioremediation of composite-polluted wastewater, containing both cadmium and 2,4-dichlorophenol (2,4-DCP). The optimum removal efficiency achieved was 78% for Cd(II) and 95.4% for 2,4-DCP at initial concentrations of 20 mg/L Cd(II) and 40 mg/L 2,4-DCP. PPBs had significantly enhanced the resistance of P. chrysosporium to 2,4-DCP, leading to the degradation rates of 2,4-DCP beyond 90% with varying initial 2,4-DCP concentrations. This research demonstrated that 2,4-DCP and secreted proteins might be used as carbon and nitrogen sources by PVA-immobilized P. chrysosporium beads (PPBs) for Cd(II) removal. Fourier transform infrared spectroscopy analysis showed that hydroxyl and carboxyl groups on the surface of PPBs were dominant in Cd(II) binding. The mechanism underlying the degradation of 2,4-DCP into fumaric acid and 1-hexanol was investigated. The adsorption–desorption studies indicated that PPBs kept up to 98.9% of desorption efficiency over three cycles.

Polyvinyl alcohol-immobilized Phanerochaete chrysosporium and its application in the bioremediation of composite-polluted wastewater

International Nuclear Information System (INIS)

Huang, Zhenzhen; Chen, Guiqiu; Zeng, Guangming; Chen, Anwei; Zuo, Yanan; Guo, Zhi; Tan, Qiong; Song, Zhongxian; Niu, Qiuya

2015-01-01

Graphical abstract: Schematic diagram of polyvinyl alcohol-immobilized Phanerochaete chrysosporium beads (PPBs) for Cd(II) removal and 2,4-DCP degradation. - Highlights: • PVA-immobilized P. chrysosporium beads (PPBs) were fit for wastewater treatment. • Removal rates of Cd(II) and 2,4-DCP at optimum conditions were up to 78% and 95.4%. • 2,4-DCP removal rates were beyond 90% with varying initial 2,4-DCP concentrations. • PVA was vital to Cd(II) removal besides the function groups in P. chrysosporium. • Maximum recovery of the Cd(II)-laden PPBs after reuse three times was 98.9%. - Abstract: A novel biosorbent, polyvinyl alcohol (PVA)-immobilized Phanerochaete chrysosporium, was applied to the bioremediation of composite-polluted wastewater, containing both cadmium and 2,4-dichlorophenol (2,4-DCP). The optimum removal efficiency achieved was 78% for Cd(II) and 95.4% for 2,4-DCP at initial concentrations of 20 mg/L Cd(II) and 40 mg/L 2,4-DCP. PPBs had significantly enhanced the resistance of P. chrysosporium to 2,4-DCP, leading to the degradation rates of 2,4-DCP beyond 90% with varying initial 2,4-DCP concentrations. This research demonstrated that 2,4-DCP and secreted proteins might be used as carbon and nitrogen sources by PVA-immobilized P. chrysosporium beads (PPBs) for Cd(II) removal. Fourier transform infrared spectroscopy analysis showed that hydroxyl and carboxyl groups on the surface of PPBs were dominant in Cd(II) binding. The mechanism underlying the degradation of 2,4-DCP into fumaric acid and 1-hexanol was investigated. The adsorption–desorption studies indicated that PPBs kept up to 98.9% of desorption efficiency over three cycles

Wastewater treatment

Directory of Open Access Journals (Sweden)

Ranđel N. Kitanović

2013-10-01

Full Text Available Quality of life on Earth in the future will largely depend on the amount of safe water. As the most fundamental source of life, water is relentlessly consumed and polluted. To halt this trend, many countries are taking extensive measures and investing substantial resources in order to stop the contamination of water and return at least tolerably good water quality to nature. The goal of water purification is to obtain clean water with the sewage sludge as a by-product. Clean water is returned to nature, and further treatment of sludge may be subject to other procedures. The conclusion of this paper is simple. The procedure with purified water is easily achievable, purified water is discharged into rivers, lakes and seas, but the problem of further treatment of sludge remains. This paper presents the basic methods of wastewater treatment and procedures for processing the products from contaminated water. The paper can serve as a basis for further elaboration. Water Pollution In order to ensure normal life of living creatures, the water in which they live or the water they use must have a natural chemical composition and natural features. When, as a result of human activities, the chemical composition of water and the ratio of its chemical elements significantly change, we say that water is polluted. When the pollutants come from industrial plants, we are talking about industrial wastewater, and when they come from households and urban areas, we are talking about municipal wastewater. Both contain a huge amount of pollutants that eventually end up in rivers. Then, thousands of defenseless birds, fish and other animals suffer, and environmental consequences become immeasurable. In addition, the waste fed to the water often ends up in the bodies of marine animals, so they can return to us as food. Thermal water pollution also has multiple effects on the changes in the wildlife composition of aquatic ecosystems. Polluted water can be purified by

Physiochemicals and Heavy Metal Removal from Domestic Wastewater via Phycoremediation

Directory of Open Access Journals (Sweden)

Ab Razak Abdul Rafiq

2016-01-01

Full Text Available The common sources of water pollution in Malaysia are domestic sewage and industrial waste. Therefore, domestic wastewater quality effluent should be improved before discharged through the outlets. The alternative method of treatment uses microalgae for water remediation which is known as phycoremediation was applied. This technique is to remove or reduce nutrients and harmful pollutants in domestic wastewater. Thus, objective of the present study is to bioremediate the physiochemical and heavy metal from domestic wastewater using freshwater green microalgae Botryococcus sp. A photobioreactor is used to treat the wastewater by employing the microalgae Botryococcus sp. as a vital part of the treatment system. The results show that several nutrients have been reduced successfully such as phosphate and total phosphorus of 100% removal, inorganic carbon of 99% removal, total carbon of 42% removal, and nitrate of 10%. The most prominent heavy metal content that has been removed is Aluminium of 41%. At the same time, the growth of microalgae Botryococcus sp. in this wastewater has achieved the maximum value at Day 4 with 2.58 × 105 cell/ml only. These results show the potential of Botryococcus sp. cultivation as an alternative method to treat domestic wastewater and any other biotechnology works in the future.

Organic pollution of rivers: Combined threats of urbanization, livestock farming and global climate change.

Science.gov (United States)

Wen, Yingrong; Schoups, Gerrit; van de Giesen, Nick

2017-02-23

Organic pollution of rivers by wastewater discharge from human activities negatively impacts people and ecosystems. Without treatment, pollution control relies on a combination of natural degradation and dilution by natural runoff to reduce downstream effects. We quantify here for the first time the global sanitation crisis through its impact on organic river pollution from the threats of (1) increasing wastewater discharge due to urbanization and intensification of livestock farming, and (2) reductions in river dilution capacity due to climate change and water extractions. Using in-stream Biochemical Oxygen Demand (BOD) as an overall indicator of organic river pollution, we calculate historical (2000) and future (2050) BOD concentrations in global river networks. Despite significant self-cleaning capacities of rivers, the number of people affected by organic pollution (BOD >5 mg/l) is projected to increase from 1.1 billion in 2000 to 2.5 billion in 2050. With developing countries disproportionately affected, our results point to a growing need for affordable wastewater solutions.

Organic pollution of rivers: Combined threats of urbanization, livestock farming and global climate change

Science.gov (United States)

Wen, Yingrong; Schoups, Gerrit; van de Giesen, Nick

2017-02-01

Organic pollution of rivers by wastewater discharge from human activities negatively impacts people and ecosystems. Without treatment, pollution control relies on a combination of natural degradation and dilution by natural runoff to reduce downstream effects. We quantify here for the first time the global sanitation crisis through its impact on organic river pollution from the threats of (1) increasing wastewater discharge due to urbanization and intensification of livestock farming, and (2) reductions in river dilution capacity due to climate change and water extractions. Using in-stream Biochemical Oxygen Demand (BOD) as an overall indicator of organic river pollution, we calculate historical (2000) and future (2050) BOD concentrations in global river networks. Despite significant self-cleaning capacities of rivers, the number of people affected by organic pollution (BOD >5 mg/l) is projected to increase from 1.1 billion in 2000 to 2.5 billion in 2050. With developing countries disproportionately affected, our results point to a growing need for affordable wastewater solutions.

Determination of the efficiency of sawdust and coco fiber used as Biofilter for pollutant removal for the treatment of wastewater

Directory of Open Access Journals (Sweden)

Jimmy Vicente Reyes

2016-09-01

Full Text Available Water is a resource used by mankind for industrial and domestic needs, which once used, is discharged into the public sewer system or septic tanks. This project proposes an ecological alternative for the treatment of wastewater from domestic use named Biofilter, which is built of living material (worms and inert material (chip and gravel, which filters the wastewater; the biological filter has shown high efficiency in the removal of organic matter and pathogens. The field work was carried out with experimental biological filters, to ascertain the best composition of inert material, different variants were used. Two experimental Biofilters, one using sawdust and the other coco fiber were used in the treatment of domestic wastewater; treated samples from each reactor were subjected to laboratory analysis. The analysis and interpretation of results showed that the Biofilter using sawdust removed 53.53 % of pollutants and is outside the required norm for wastewater treatment and the Biofilter using coco fiber removed 82.37 % of contaminants and is within the Environmental Quality Norm and Effluent Discharge: Water Resource.

Bioaugmentation: An Emerging Strategy of Industrial Wastewater Treatment for Reuse and Discharge

Directory of Open Access Journals (Sweden)

Alexis Nzila

2016-08-01

Full Text Available A promising long-term and sustainable solution to the growing scarcity of water worldwide is to recycle and reuse wastewater. In wastewater treatment plants, the biodegradation of contaminants or pollutants by harnessing microorganisms present in activated sludge is one of the most important strategies to remove organic contaminants from wastewater. However, this approach has limitations because many pollutants are not efficiently eliminated. To counterbalance the limitations, bioaugmentation has been developed and consists of adding specific and efficient pollutant-biodegrading microorganisms into a microbial community in an effort to enhance the ability of this microbial community to biodegrade contaminants. This approach has been tested for wastewater cleaning with encouraging results, but failure has also been reported, especially during scale-up. In this review, work on the bioaugmentation in the context of removal of important pollutants from industrial wastewater is summarized, with an emphasis on recalcitrant compounds, and strategies that can be used to improve the efficiency of bioaugmentation are also discussed. This review also initiates a discussion regarding new research areas, such as nanotechnology and quorum sensing, that should be investigated to improve the efficiency of wastewater bioaugmentation.

Analysis of Wastewater Treatment Efficiency in a Soft Drinks Industry

Science.gov (United States)

Boguniewicz-Zabłocka, Joanna; Capodaglio, Andrea G.; Vogel, Daniel

2017-10-01

During manufacturing processes, most industrial plants generate wastewater which could become harmful to the environment. Discharge of untreated or improperly treated industrial wastewaters into surface water could, in fact, lead to deterioration of the receiving water body's quality. This paper concerns wastewater treatment solutions used in the soft drink production industry: wastewater treatment plant effectiveness analysis was determined in terms of basic pollution indicators, such as BOD, COD, TSS and variable pH. Initially, the performance of mechanic-biological systems for the treatment of wastewater from a specific beverages production process was studied in different periods, due to wastewater flow fluctuation. The study then showed the positive effects on treatment of wastewater augmentation by methanol, nitrogen and phosphorus salts dosed into it during the treatment process. Results confirm that after implemented modification (methanol, nitrogen and phosphorus additions) pollution removal occurs mostly with higher efficiency.

Flow rate analysis of wastewater inside reactor tanks on tofu wastewater treatment plant

Science.gov (United States)

Mamat; Sintawardani, N.; Astuti, J. T.; Nilawati, D.; Wulan, D. R.; Muchlis; Sriwuryandari, L.; Sembiring, T.; Jern, N. W.

2017-03-01

The research aimed to analyse the flow rate of the wastewater inside reactor tanks which were placed a number of bamboo cutting. The resistance of wastewater flow inside reactor tanks might not be occurred and produce biogas fuel optimally. Wastewater from eleven tofu factories was treated by multi-stages anaerobic process to reduce its organic pollutant and produce biogas. Biogas plant has six reactor tanks of which its capacity for waste water and gas dome was 18 m3 and 4.5 m3, respectively. Wastewater was pumped from collecting ponds to reactors by either serial or parallel way. Maximum pump capacity, head, and electrical motor power was 5m3/h, 50m, and 0.75HP, consecutively. Maximum pressure of biogas inside the reactor tanks was 55 mbar higher than atmosphere pressure. A number of 1,400 pieces of cutting bamboo at 50-60 mm diameter and 100 mm length were used as bacteria growth media inside each reactor tank, covering around 14,287 m2 bamboo area, and cross section area of inner reactor was 4,9 m2. In each reactor, a 6 inches PVC pipe was installed vertically as channel. When channels inside reactor were opened, flow rate of wastewater was 6x10-1 L.sec-1. Contrary, when channels were closed on the upper part, wastewater flow inside the first reactor affected and increased gas dome. Initially, wastewater flowed into each reactor by a gravity mode with head difference between the second and third reactor was 15x10-2m. However, head loss at the second reactor was equal to the third reactor by 8,422 x 10-4m. As result, wastewater flow at the second and third reactors were stagnant. To overcome the problem pump in each reactor should be installed in serial mode. In order to reach the output from the first reactor and the others would be equal, and biogas space was not filled by wastewater, therefore biogas production will be optimum.

Environmental impacts of polluted effluents on human health

International Nuclear Information System (INIS)

Ahmad, M.S.

2005-01-01

One of the major environmental problems confronting Pakistan is water pollution. Human health is being affected by water pollution. The major sources of pollution for surface and groundwater resources are municipal sewage and industrial wastewater. The indiscriminate discharges of untreated sewage and industrial effluents into the water bodies have affected not only the water quality but also human health. Groundwater is also being contaminated by the discharge of untreated sewage into land. Water pollution is responsible for water borne diseases such as hepatitis, dysentery, typhoid, cholera, paratyphoid fever etc. This paper presents a general overview of the wastewater pollution in Pakistan, an evaluation and a specific reference to Lahore city and the effects on human health. Finally, sustainable treatment methods have been proposed to mitigate the water pollution problem. The analysis of water bodies at wastewater discharge points shows depletion of Dissolved Oxygen (DO) and high levels of E. Coli. There is an evidence of groundwater pollution in many areas due to the discharge of wastewater on open land. To protect the water sources from contamination, appropriate treatment methods/treatment technologies have also been discussed in this paper. In the end conclusion and recommendations are given. (author)

Environmental impacts of polluted effluents on human health

Energy Technology Data Exchange (ETDEWEB)

Ahmad, M S [NESPAK, Lahore (Pakistan). Geo-Environmental Engineering Div.

2005-07-15

One of the major environmental problems confronting Pakistan is water pollution. Human health is being affected by water pollution. The major sources of pollution for surface and groundwater resources are municipal sewage and industrial wastewater. The indiscriminate discharges of untreated sewage and industrial effluents into the water bodies have affected not only the water quality but also human health. Groundwater is also being contaminated by the discharge of untreated sewage into land. Water pollution is responsible for water borne diseases such as hepatitis, dysentery, typhoid, cholera, paratyphoid fever etc. This paper presents a general overview of the wastewater pollution in Pakistan, an evaluation and a specific reference to Lahore city and the effects on human health. Finally, sustainable treatment methods have been proposed to mitigate the water pollution problem. The analysis of water bodies at wastewater discharge points shows depletion of Dissolved Oxygen (DO) and high levels of E. Coli. There is an evidence of groundwater pollution in many areas due to the discharge of wastewater on open land. To protect the water sources from contamination, appropriate treatment methods/treatment technologies have also been discussed in this paper. In the end conclusion and recommendations are given. (author)

Can those organic micro-pollutants that are recalcitrant in activated sludge treatment be removed from wastewater by biofilm reactors (slow sand filters)?

International Nuclear Information System (INIS)

Escolà Casas, Mònica; Bester, Kai

2015-01-01

The degradation of seven compounds which are usually recalcitrant in classical activated sludge treatment (e.g., diclofenac, propranolol, iopromide, iohexol, iomeprol tebuconazole and propiconazole) was studied in a biofilm reactor (slow sand filtration). This reactor was used to treat real effluent-wastewater at different flow rates (hydraulic loadings) under aerobic conditions so removal and degradation kinetics of these recalcitrant compounds were calculated. With the hydraulic loading rate of 0.012 m 3 m 2 h −1 the reactor removed 41, 94, 58, 57 and 85% of diclofenac, propranolol, iopromide, iohexol and iomeprol respectively. For these compounds the removal efficiency was dependent on hydraulic residence-times. Only 59 and 21% of the incoming tebuconazole and propiconazole respectively were removed but their removal did not depend on hydraulic residence time. Biofilm reactors are thus efficient in removing micro-pollutants and could be considered as an option for advanced treatment in small wastewater treatment plants. - Highlights: • A biofilm reactor (biofilter) can remove micro-pollutants from WWTP effluent. • Sorption could be excluded as the dominant removal mechanism. • Biodegradation was responsible for removing seven compounds. • The removal efficiency was usually proportional to the hydraulic residence-time. • Single first-order removal rates apply for most compounds

Can those organic micro-pollutants that are recalcitrant in activated sludge treatment be removed from wastewater by biofilm reactors (slow sand filters)?

Energy Technology Data Exchange (ETDEWEB)

Escolà Casas, Mònica; Bester, Kai, E-mail: kb@dmu.dk

2015-02-15

The degradation of seven compounds which are usually recalcitrant in classical activated sludge treatment (e.g., diclofenac, propranolol, iopromide, iohexol, iomeprol tebuconazole and propiconazole) was studied in a biofilm reactor (slow sand filtration). This reactor was used to treat real effluent-wastewater at different flow rates (hydraulic loadings) under aerobic conditions so removal and degradation kinetics of these recalcitrant compounds were calculated. With the hydraulic loading rate of 0.012 m{sup 3} m{sup 2} h{sup −1} the reactor removed 41, 94, 58, 57 and 85% of diclofenac, propranolol, iopromide, iohexol and iomeprol respectively. For these compounds the removal efficiency was dependent on hydraulic residence-times. Only 59 and 21% of the incoming tebuconazole and propiconazole respectively were removed but their removal did not depend on hydraulic residence time. Biofilm reactors are thus efficient in removing micro-pollutants and could be considered as an option for advanced treatment in small wastewater treatment plants. - Highlights: • A biofilm reactor (biofilter) can remove micro-pollutants from WWTP effluent. • Sorption could be excluded as the dominant removal mechanism. • Biodegradation was responsible for removing seven compounds. • The removal efficiency was usually proportional to the hydraulic residence-time. • Single first-order removal rates apply for most compounds.

Options for wastewater management in Harare, Zimbabwe

NARCIS (Netherlands)

Nhapi, I.

2004-01-01

The sustainable management of wastewater should aim at pollution prevention and reduction first, followed by resource recovery and reuse. This thesis shows that substantial water quality improvements could be achieved through a so-called 3-Step Strategic Approach to wastewater management. This

Heavy metal pollution of vegetable crops irrigated with wastewater ...

African Journals Online (AJOL)

144) and edible parts of both exotic and traditional vegetables (samples = 240) irrigated with wastewater from some parts of Accra were studied. The concentrations of heavy metals in mg/l were quantified in wastewater from Accra and ...

Environmental pollution and control, second edition

International Nuclear Information System (INIS)

Vesilind, P.A.; Peirce, J.J.

1983-01-01

Most of the problems, principles, and solutions are presented here in a non-biased, easy-to-read format. The language used is non-technical for the most part, and the inclusion of a complete glossary aids when some technical terms must be used. The text itself is supported by photographs, drawings, tables, and examples. Major Sections: Environmental Pollution, Water Pollution; Measurement of Water Quality; Water Supply; Water Treatment; Collection of Wastewater; Wastewater Treatment; Sludge Treatment and Disposal; Nonpoint Source Water Pollution; Water Pollution Law; Solid Waste; Solid Waste Disposal; Resource Recovery; Hazardous Waste; Radioactive Waste; Solid and Hazardous Waste Law; Air Pollution; Meteorology and Air Quality; Measurement of Air Quality; Air Pollution Control; Air Pollution Law; Noise Pollution; Noise Measurement and Control; Environmental Impact; The Environmental Ethic; Appendix: Conversion Factors; Glossary and Abbreviations; Index

Measuring the CO2 shadow price for wastewater treatment: A directional distance function approach

International Nuclear Information System (INIS)

Molinos-Senante, María; Hanley, Nick; Sala-Garrido, Ramón

2015-01-01

Highlights: • The shadow price of CO 2 informs about the marginal abatement cost of this pollutant. • It is estimated the shadow price of CO 2 for wastewater treatment plants. • The shadow prices depend on the setting of the directional vectors of the distance function. • Sewage sludge treatment technology affects the CO 2 shadow price. - Abstract: The estimation of the value of carbon emissions has become a major research and policy topic since the establishment of the Kyoto Protocol. The shadow price of CO 2 provides information about the marginal abatement cost of this pollutant. It is an essential element in guiding environmental policy issues, since the CO 2 shadow price can be used when fixing carbon tax rates, in environmental cost-benefit analysis and in ascertaining an initial market price for a trading system. The water industry could play an important role in the reduction of greenhouse gas (GHG) emissions. This paper estimates the shadow price of CO 2 for a sample of wastewater treatment plants (WWTPs), using a parametric quadratic directional distance function. Following this, in a sensitivity analysis, the paper evaluates the impact of different settings of directional vectors on the shadow prices. Applying the Mann–Whitney and Kruskal–Wallis non-parametric tests, factors affecting CO 2 prices are investigated. The variation of CO 2 shadow prices across the WWTPs evaluated argues in favour of a market-based approach to CO 2 mitigation as opposed to command-and-control regulation. The paper argues that the estimation of the shadow price of CO 2 for non-power enterprises can provide incentives for reducing GHG emissions

Chemical phosphorus removal: A clean strategy for piggery wastewater management in Brazil

Science.gov (United States)

The intensive production of animal protein is known to be an environmental polluting activity, especially if the wastewater produced is not managed properly. Swine production in Brazil is growing and technologies to manage all pollutants present in the wastewater effluent are needed. This work prese...

A combined electrocoagulation-sorption process applied to mixed industrial wastewater

Energy Technology Data Exchange (ETDEWEB)

Linares-Hernandez, Ivonne [Universidad Autonoma del Estado de Mexico, Facultad de Quimica, Paseo Colon interseccion Paseo Tollocan S/N, C.P. 50120, Toluca (Mexico); Barrera-Diaz, Carlos [Universidad Autonoma del Estado de Mexico, Facultad de Quimica, Paseo Colon interseccion Paseo Tollocan S/N, C.P. 50120, Toluca (Mexico)]. E-mail: cbarrera@uaemex.mx; Roa-Morales, Gabriela [Universidad Autonoma del Estado de Mexico, Facultad de Quimica, Paseo Colon interseccion Paseo Tollocan S/N, C.P. 50120, Toluca (Mexico); Bilyeu, Bryan [University of North Texas, Department of Materials Science and Engineering, PO Box 305310, Denton, TX 76203-5310 (United States); Urena-Nunez, Fernando [Instituto Nacional de Investigaciones Nucleares, A.P. 18-1027, Col. Escandon, Delegacion Miguel Hidalgo, C.P. 11801, Mexico, D.F. (Mexico)

2007-06-01

The removal of organic pollutants from a highly complex industrial wastewater by a aluminium electrocoagulation process coupled with biosorption was evaluated. Under optimal conditions of pH 8 and 45.45 A m{sup -2} current density, the electrochemical method yields a very effective reduction of all organic pollutants, this reduction was enhanced when the biosorption treatment was applied as a polishing step. Treatment reduced chemical oxygen demand (COD) by 84%, biochemical oxygen demand (BOD{sub 5}) by 78%, color by 97%, turbidity by 98% and fecal coliforms by 99%. The chemical species formed in aqueous solution were determined. The initial and final pollutant levels in the wastewater were monitored using UV-vis spectrometry and cyclic voltammetry. Finally, the morphology and elemental composition of the biosorbent was characterized with scanning electron microscopy (SEM) and energy dispersion spectra (EDS)

A combined electrocoagulation-sorption process applied to mixed industrial wastewater

International Nuclear Information System (INIS)

Linares-Hernandez, Ivonne; Barrera-Diaz, Carlos; Roa-Morales, Gabriela; Bilyeu, Bryan; Urena-Nunez, Fernando

2007-01-01

The removal of organic pollutants from a highly complex industrial wastewater by a aluminium electrocoagulation process coupled with biosorption was evaluated. Under optimal conditions of pH 8 and 45.45 A m -2 current density, the electrochemical method yields a very effective reduction of all organic pollutants, this reduction was enhanced when the biosorption treatment was applied as a polishing step. Treatment reduced chemical oxygen demand (COD) by 84%, biochemical oxygen demand (BOD 5 ) by 78%, color by 97%, turbidity by 98% and fecal coliforms by 99%. The chemical species formed in aqueous solution were determined. The initial and final pollutant levels in the wastewater were monitored using UV-vis spectrometry and cyclic voltammetry. Finally, the morphology and elemental composition of the biosorbent was characterized with scanning electron microscopy (SEM) and energy dispersion spectra (EDS)

Occurrence of multi-class surfactants in urban wastewater: contribution of a healthcare facility to the pollution transported into the sewerage system.

Science.gov (United States)

Bergé, Alexandre; Wiest, Laure; Baudot, Robert; Giroud, Barbara; Vulliet, Emmanuelle

2018-04-01

Healthcare facility discharges, by their nature, are often considered as non-domestic effluent, which can provide significant pollution comparatively to other domestic sources. In this context, a total of 12 monthly sampling campaigns were collected from a healthcare facility as well as the output of a sewerage system of Site Pilote de Bellecombe (SIPIBEL) observatory. This study focuses more specifically on 12 surfactants and biocides: four anionics, four cationic, two non-ionic, one zwitterionic, and one dispersive agent, among the most commonly used commercial surfactants. Particular attention was also provided to routine wastewater quality parameters. Both effluents were heavily contaminated by most anionic surfactants; they displayed median concentrations up to 1 to 2 mg/L for linear alkylbenzene sulfonates and between 10 and 100 μg/L for other sodium sulfate congeners (lauryl and laureth). Overall, for the majority of surfactants, the healthcare facility contribution to the total flux reaching the wastewater treatment plant ranges between 5 and 9%.

Effect of solar radiation on multidrug resistant E. coli strains and antibiotic mixture photodegradation in wastewater polluted stream.

Science.gov (United States)

Rizzo, L; Fiorentino, A; Anselmo, A

2012-06-15

The effect of solar radiation on the inactivation of multidrug resistant Escherichia coli (MDR) strains selected from an urban wastewater treatment plant (UWWTP) effluent and the change of their resistance to a mixture of three antibiotics (evaluated in terms of minimum inhibit concentration (MIC)) in wastewater polluted stream were investigated. The solar photodegradation of the mixture of the three target antibiotics (amoxicillin (AMX), ciprofloxacin (CPX), and sulfamethoxazole (SMZ)) was also evaluated. Additionally, since UWWTP effluents are possible sources of antibiotics and antibiotic resistant bacteria, the disinfection by conventional chlorination process of the UWWTP effluent inoculated with MDR strains was investigated too. Solar radiation poorly affected the inactivation of the two selected antibiotic resistant E. coli strains (40 and 60% after 180 min irradiation). Moreover, solar radiation did not affect strain resistance to AMX (MIC>256 μg/mL) and SMZ (MIC>1024 μg/mL), but affected resistance of the lower resistance strain to CPX (MIC decreased by 33% but only after 180 min of irradiation). Chlorination of wastewater sample strongly decreased the number of the two selected antibiotic resistant E. coli strains (99.667 and 99.999%), after 60 min of contact time at 2.0 mg/L initial chlorine concentration, but the resistance of survived colonies to antibiotics was unchanged. Finally, the solar photodegradation rate of the antibiotic mixture (1mg/L initial concentration respectively) resulted in the following order (half-life time): CPX (t(1/2)=24 min)risk of the development of resistance to SMZ in surface water is significantly higher compared to CPX and AMX. Copyright © 2012 Elsevier B.V. All rights reserved.

Physicochemical Characterization of Wastewaters from a Cluster of ...

African Journals Online (AJOL)

Myina O M

chlorides – of the wastewaters from the various industries were investigated using standard protocols. The ranges of the ... water bodies of these wastewaters are at risk of being polluted. ... Most of it is in oceans, ice caps, underground aquifers ...

Supported Photocatalyst for Removal of Emerging Contaminants from Wastewater in a Continuous Packed-Bed Photoreactor Configuration

Directory of Open Access Journals (Sweden)

Mª Emma Borges

2015-02-01

Full Text Available Water pollution from emerging contaminants (ECs or emerging pollutants is an important environmental problem. Heterogeneous photocatalytic treatment, as advanced oxidation treatment of wastewater effluents, has been proposed to solve this problem. In this paper, a heterogeneous photocatalytic process was studied for emergent contaminants removal using paracetamol as a model contaminant molecule. TiO2 photocatalytic activity was evaluated using two photocatalytic reactor configurations: Photocatalyst solid suspension in wastewater in a stirred photoreactor and TiO2 supported on glass spheres (TGS configuring a packed bed photoreactor. The surface morphology and texture of the TGS were monitored by scanning electron microscope (SEM. The influence of photocatalyst amount and wastewater pH were evaluated in the stirred photoreactor and the influence of wastewater flowrate was tested in the packed bed photoreactor, in order to obtain the optimal operation conditions. Moreover, results obtained were compared with those obtained from photolysis and adsorption studies, using the optimal operation conditions. Good photocatalytic activities have been observed and leads to the conclusion that the heterogeneous photocatalytic system in a packed bed is an effective method for removal of emerging pollutants.

Treatment of wastewaters from manufactured gas plants

Energy Technology Data Exchange (ETDEWEB)

Cocheci, V.; Bogatu, C.; Radovan, C. [Technical University of Timisoara, Timisoara (Romania)

1995-12-31

The treatment of wastewaters with high concentrations of organic compounds often represents a difficult problem. In some cases, for the destruction and removal of toxic compounds using processes like biological and chemical oxidation were proposed. Wastewaters from manufactured gas plants contain high concentrations of organic pollutants and ammonia. In this paper a technology for the treatment of these wastewaters is proposed. The experiments were realized with wastewaters from two Romanian manufactured gas plants. The process consists of the following steps: polycondensation-settling-stripping-biological treatment-electrocoagulation-electrochemical oxidation, or chemical oxidation. 6 refs., 4 tabs.

Wastewater Treatment for Pollution Control | Nzabuheraheza ...

African Journals Online (AJOL)

Performance of a Dynamic Roughing Filter (DRF) coupled with a Horizontal Subsurface Flow Constructed Wetland (HSSFCW) in the treatment of a wastewater was studied in tropical conditions. The results show that in HSSFCW planted with Cyperus papyrus and Phragmites mauritianus in series, the removal rates of TDS, ...

Decontamination of industrial wastewater from sugarcane crops by combining solar photo-Fenton and biological treatments

International Nuclear Information System (INIS)

Mendoza-Marin, Claudia; Osorio, Paula; Benitez, Norberto

2010-01-01

The department of Valle del Cauca is the region with the largest sugarcane production in Colombia. This agricultural activity uses high quantities of herbicides, mainly Diuron and 2,4-Dichlorophenoxyacetic acid. Wastewater generated in the washing process of spray equipment and empty pesticide containers must be treated to keep natural water sources from being polluted with these pesticides when these effluents are disposed off. Conventional biological treatments are not able to remove recalcitrant substances like Diuron and 2,4-Dichlorophenoxyacetic acid; therefore, it is essential to have alternative treatment systems. In recent years, photocatalytic processes have been proven efficient methods in treating polluted water with recalcitrant organic substances. This study sought to evaluate the efficiency of a coupled treatment constituted for a solar photo-Fenton treatment and a biological system like an immobilized biological reactor to treat industrial wastewater containing pesticides (2,4-Dichlorophenoxyacetic acid and Diuron). The mineralization and degradation of pesticides were followed by measuring the dissolved organic carbon and pesticide concentrations. The results revealed that industrial wastewaters with high Diuron and 2,4-Dichlorophenoxyacetic acid concentrations can be successfully treated by a combined solar photo-Fenton-biological system, achieving mineralization of 79.8% in prepared wastewater and 82.5% in real industrial wastewater by using low Fe 2+ and H 2 O 2 concentrations.

Decontamination of industrial wastewater from sugarcane crops by combining solar photo-Fenton and biological treatments

Energy Technology Data Exchange (ETDEWEB)

Mendoza-Marin, Claudia; Osorio, Paula [Department of Chemistry, Faculty of Science, Universidad del Valle, A.A. 25360 Cali (Colombia); Benitez, Norberto, E-mail: lubenite@univalle.edu.co [Department of Chemistry, Faculty of Science, Universidad del Valle, A.A. 25360 Cali (Colombia)

2010-05-15

The department of Valle del Cauca is the region with the largest sugarcane production in Colombia. This agricultural activity uses high quantities of herbicides, mainly Diuron and 2,4-Dichlorophenoxyacetic acid. Wastewater generated in the washing process of spray equipment and empty pesticide containers must be treated to keep natural water sources from being polluted with these pesticides when these effluents are disposed off. Conventional biological treatments are not able to remove recalcitrant substances like Diuron and 2,4-Dichlorophenoxyacetic acid; therefore, it is essential to have alternative treatment systems. In recent years, photocatalytic processes have been proven efficient methods in treating polluted water with recalcitrant organic substances. This study sought to evaluate the efficiency of a coupled treatment constituted for a solar photo-Fenton treatment and a biological system like an immobilized biological reactor to treat industrial wastewater containing pesticides (2,4-Dichlorophenoxyacetic acid and Diuron). The mineralization and degradation of pesticides were followed by measuring the dissolved organic carbon and pesticide concentrations. The results revealed that industrial wastewaters with high Diuron and 2,4-Dichlorophenoxyacetic acid concentrations can be successfully treated by a combined solar photo-Fenton-biological system, achieving mineralization of 79.8% in prepared wastewater and 82.5% in real industrial wastewater by using low Fe{sup 2+} and H{sub 2}O{sub 2} concentrations.

City, (from Point of Organic Pollutants and Heavy Metals

Directory of Open Access Journals (Sweden)

Sajad Mazlomi

2014-03-01

Full Text Available Background: In this study quality and quantity characteristics wastewater of hospitals, clinics and health centers of Arak city and the potential impacts of them on Arak wastewater plant investigated. Methods: In this cross-sectional  study, which done during 2011-2012, the quantity and quality  of wastewater via point of COD,BOD5, pH, TKN, PO4and also heavy metals in the hospitals, clinics and health center of Arak were studied. Then, the effects of these pollutants as equal to person on wastewater convey system and wastewater treatment plant were assisted. Results: Monitoring of BOD5, TKN, and PO4 indicated that the daily disposal rate of these pollutants were equal 778.14, 102.7, and 53.6 kg/d, respectively, which equal to 15763, 51351, and 6700 person, respectively. The average water consumption of these centers was equal to 8.2l/s, and the estimated measure of produced wastewater was6.14 l/s. Also, after analysis the measure of heavy metals, Hg production (99.331 g/d was more than other heavy metals, and the next rank was related to Zn (41.96 g/d and Ag (41.96g/d, respectively. Conclusion: Although existence pretreatment process units can help to decrease the side effects of produced wastewater, this kind of wastewater needs complete treatment. Discharge of this kind wastewater to absorption trenches led to adverse health impacts in future. Therefore, a construction separate wastewater treatment plants and proper operation of these systems can reduce ecosystem impacts of wastewater discharges.

Wastewater treatment and pollution control in Indonesia

International Nuclear Information System (INIS)

Danu, Sugiarto

2006-01-01

Present status of radiation facilities for Co-60 gamma ray irradiation and electron beam irradiation in Indonesia is first presented. Wastewater treatment is explained: kinds of waste, industrial, agricultural, municipal and nuclear. Each liquid wastewater containing various kinds of contaminants, radioactive or non-radioactive is differently treated by waste treatment industries. On-going project is use of electron beams in which combination with ozone to reduce chlorinated solvent, disinfected sludge from sewage treatment containing organic and inorganic components for soil fertilizer, and high color river water for water supplying. The cost factor and the effect of combined treatment are being examined. Other on-going projects are applications of electron beams for vulcanization of natural rubber latex and flue gas treatment by BATAN. (S. Ohno)

Emerging energy-efficient technologies for the Californian wastewater industry

NARCIS (Netherlands)

Slaa, Jan Willem

2011-01-01

SUMMARY Wastewater treatment is of vital importance for protecting human health and minimizing the environmental impact of polluted water. Since the beginning of the 20th century public facilities have been installed globally which treat wastewater at a

Future wastewater solutions: removal of pharmaceuticals in conventional wastewater treatment plants

DEFF Research Database (Denmark)

Jensen, Thomas

Residues of pharmaceuticals, personal care products and industrial chemicals find their way into the environment mainly through incomplete removal in the conventional urban wastewater treatment plants (WWTPs) and appear as micro-pollutants at pg L-1 to μg L-1 concentrations. WWTPs were designed...

Enhancing anaerobic treatment of wastewaters containing oleic acid

NARCIS (Netherlands)

Hwu, C.S.

1997-01-01

INTRODUCTION

Lipids are one of the major organic pollutants in municipal and industrial wastewaters. Although domestic sewage typically contains about 40-100 mg/I lipids (Forster, 1992; Quéméneur and Marty, 1994), it is industrial wastewaters that are of greater

Removal of macro-pollutants in oily wastewater obtained from soil remediation plant using electro-oxidation process.

Science.gov (United States)

Zolfaghari, Mehdi; Drogui, Patrick; Blais, Jean François

2018-03-01

Electro-oxidation process by niobium boron-doped diamond (Nb/BDD) electrode was used to treat non-biodegradable oily wastewater provided from soil leachate contaminated by hydrocarbons. Firstly, the diffusion current limit and mass transfer coefficient was experimentally measured (7.1 mA cm -2 and 14.7 μm s -1 , respectively), in order to understand minimum applied current density. Later on, the oxidation kinetic model of each pollutant was investigated in different current densities ranged between 3.8 and 61.5 mA cm -2 . It was observed that direct oxidation was the main removal mechanism of organic and inorganic carbon, while the indirect oxidation in higher current density was responsible for nitrogen oxidation. Hydrocarbon in the form of colloidal particles could be removed by electro-flotation. On the other hand, electro-decomposition on the surface of cathode and precipitation by hydroxyl ions were the utmost removal pathway of metals. According to the initial experiments, operating condition was further optimized by central composite design model in different current density, treatment time, and electrolyte addition, based on the best responses on the specific energy consumption (SEC), chemical oxygen demand (COD), and total organic carbon (TOC) removal efficiency. Unde r optimum operating condition (current density = 23.1 mA cm -2 , time = 120 min, Ti/Pt as a cathode, and Nb/BDD as the anode), electro-oxidation showed the following removal efficiencies: COD (84.6%), TOC (68.2%), oil and grease (99%), color (87.9%), total alkalinity (92%), N tot (18%), NH 4 + (31%), Ca (66.4%), Fe (71.1%), Mg (41.4%), Mn (78.1%), P tot (75%), S (67.1%), and Si (19.1%). Graphical abstract Environmental significance statement Soil treatment facilities are rapidly grown throughout the world, especially in North America due to its intense industrialization. High water content soil in humid area like Canada produces significant amount of leachate which is

Progress in Treatment of Oily Wastewater by Inorganic Porous Ceramic Membrane

Directory of Open Access Journals (Sweden)

Dai Xiaoyuan

2017-01-01

Full Text Available The composition and complexity of oily wastewater contains many solid particles, free oil, emulsified oil and so on.It brought about a series of environmental pollution problems when oily wastewater was directly discharged into rivers, lakes and other water bodies. Therefore, researchers are committed to study how to deal with oily wastewater to deal with oily wastewater to apply it to meet the requirements of water injection.Inorganic porous ceramic membrane has excellent properties among many filtering methods. For example, high temperature and high pressure resistance, resistance to acid and alkali, low energy consumption, no pollution to the environment and has a good prospect in the field of oily wastewater treatment, which has attracted the attention of many scholars not only at home but also on abroad. This article describes the present situation of the research on the treatment of oily wastewater by ceramic membrane in recent years, and expounded the significance of the treatment of oily wastewater to people’s lives and makes an expectation for the development of inorganic porous ceramic membrane in the future.

[Ecological security of wastewater treatment processes: a review].

Science.gov (United States)

Yang, Sai; Hua, Tao

2013-05-01

Though the regular indicators of wastewater after treatment can meet the discharge requirements and reuse standards, it doesn't mean the effluent is harmless. From the sustainable point of view, to ensure the ecological and human security, comprehensive toxicity should be considered when discharge standards are set up. In order to improve the ecological security of wastewater treatment processes, toxicity reduction should be considered when selecting and optimizing the treatment processes. This paper reviewed the researches on the ecological security of wastewater treatment processes, with the focus on the purposes of various treatment processes, including the processes for special wastewater treatment, wastewater reuse, and for the safety of receiving waters. Conventional biological treatment combined with advanced oxidation technologies can enhance the toxicity reduction on the base of pollutants removal, which is worthy of further study. For the process aimed at wastewater reuse, the integration of different process units can complement the advantages of both conventional pollutants removal and toxicity reduction. For the process aimed at ecological security of receiving waters, the emphasis should be put on the toxicity reduction optimization of process parameters and process unit selection. Some suggestions for the problems in the current research and future research directions were put forward.

Microaerobic biodegradation of high organic load wastewater by ...

African Journals Online (AJOL)

USER

2010-06-21

Jun 21, 2010 ... concentration in the simulated wastewater as in the RCVBN medium. Optimization of wastewater composition and treatment conditions. SW with pollutants strength of 3600 mgl-1 COD was used to incubate the phototrophic bacteria microaerobically in the light (appro- ximately 2000 lx), the COD reduction ...

Sustainable technologies for olive mill wastewater management (abstract)

Science.gov (United States)

The California olive oil industry produces more than 600 million gallons of wastewater each year. Olive mill wastewater (OMWW) is considered a highly polluting effluent due to its high organic load and resistance to biological degradation. A current trend in OMWW management is to not only decrease e...

Application of Gamma Radiation for Removal of Organic Pollutants from Wastewater

Energy Technology Data Exchange (ETDEWEB)

Meguenni, H.; Mahlous, M.; Mansouri, B. [Centre de Recherche Nucléaire d' Alger, 2Bd Frantz Fanon BP-399 Alger (Algeria); Bouchfer, S. [ONA Office National de l’Assainissement, Alger (Algeria)

2012-07-01

The study of this research is focused on the possibility of using gamma radiation in order to decrease the concentration of polycyclic aromatic hydrocarbon (PAH) in effluents. The research was initiated with a concentration of 100ppm of synthetic naphthalene aqueous solution submitted to different absorbed doses. The HPLC analysis has shown that the dose of 30kGy degraded 99.96% of the naphthalene molecule. The identification program of NIST library has identified the by-products formed during the radiation process. Concerning the industrial effluent wastewater sample, we opted for analysis by GC-MS before and after gamma irradiation, to monitor the degradation of PAH and other pollutants from the refinery. The results show that in global view, gamma radiation decreases significantly the contaminated level, with the increase of the absorbed dose. In detailed view, the relative content of the naphthalene, 2,7 dimethyl in the effluent sample decreased with the increase of the absorbed dose. At the dose of 6 kGy the molecule was completely degraded. The COD of effluent sample presented a reduction of 58%, when 10 kGy dose was applied. After irradiation a secondary treatment, based on adsorption using a natural adsorbent, has to be applied in order to remove the by-products of radiation degradation, to get a better quality of effluent and consequently improve the environmental condition. (author)

Application of Gamma Radiation for Removal of Organic Pollutants from Wastewater

International Nuclear Information System (INIS)

Meguenni, H.; Mahlous, M.; Mansouri, B.; Bouchfer, S.

2012-01-01

The study of this research is focused on the possibility of using gamma radiation in order to decrease the concentration of polycyclic aromatic hydrocarbon (PAH) in effluents. The research was initiated with a concentration of 100ppm of synthetic naphthalene aqueous solution submitted to different absorbed doses. The HPLC analysis has shown that the dose of 30kGy degraded 99.96% of the naphthalene molecule. The identification program of NIST library has identified the by-products formed during the radiation process. Concerning the industrial effluent wastewater sample, we opted for analysis by GC-MS before and after gamma irradiation, to monitor the degradation of PAH and other pollutants from the refinery. The results show that in global view, gamma radiation decreases significantly the contaminated level, with the increase of the absorbed dose. In detailed view, the relative content of the naphthalene, 2,7 dimethyl in the effluent sample decreased with the increase of the absorbed dose. At the dose of 6 kGy the molecule was completely degraded. The COD of effluent sample presented a reduction of 58%, when 10 kGy dose was applied. After irradiation a secondary treatment, based on adsorption using a natural adsorbent, has to be applied in order to remove the by-products of radiation degradation, to get a better quality of effluent and consequently improve the environmental condition. (author)

Nanoscale TiO2 films and their application in remediation of organic pollutants

Science.gov (United States)

Photocatalysis is an advanced process for treatment of air, wastewater, and drinking water, the primary advantage being its ability to mineralize many pollutants. Among several nanoscale arrangements of photocatalysts, there has been a strong push to develop them as thin films be...

Fabrication of multi-functional porous microspheres in a modular fashion for the detection, adsorption, and removal of pollutants in wastewater.

Science.gov (United States)

Ding, Baojun; Wang, Jie; Tao, Shengyang; Ding, Yunzhe; Zhang, Lijing; Gao, Ning; Li, Guangtao; Shi, Haonan; Li, Weijun; Ge, Shuo

2018-07-15

Water pollution control has become significant challenges in recent years because of their extensive species diversity. It is critical to developing general-purpose materials for environmental rehabilitation. In this paper, a novel module-assembly method is developed to prepare multi-functional materials for treating pollutants in water. Building blocks are porous nanoparticles with a different function. Microspheres (MS) with a diameter of 90 μm are prepared and have a coefficient of variation of 6.8%. The modular fashion of self-assembly process in a microfluidic chip is the crucial factor in fabricating the multifunction material. The assembled microspheres with different building modules still have a specific surface area larger than 400 m 2 g -1 , and exhibit excellent performance in adsorbing various pollutants in water, such as heavy metal ions and organic dyes. The adsorption capacities of them to Hg 2+ and orange II reach 150 mg g -1 and 333 mg g -1 , respectively. The integrated fluorescence probes in microspheres can detect low concentration (9.8 ppb) of Hg 2+ . Microspheres integrated with Fe 3 O 4 nanoparticles have a magnetic susceptibility of 6.01 emu g -1 and can be easily removed from wastewater by applying an external magnetic. Due to the stability of inorganic building blocks, each function in the assembled system is well performed, and multi-functional "All-in-One" materials can be easily fabricated. Copyright © 2018 Elsevier Inc. All rights reserved.

Electron beam irradiation and adsorption as possibilities for wastewater reuse

International Nuclear Information System (INIS)

Borrely, Sueli I.; Higa, Marcela C.; Pinheiro, Alessandro; Morais, Aline V.; Fungaro, Denise A.

2013-01-01

The importance of water for life and for the industrial processes is forcing the development of combined technologies for wastewater improvement. The limitations of biological treatment for reducing micro-pollutants and the constant introduction of different chemical into environment make Ionizing Radiation a more interesting technique for pollutants abatement. Electron Accelerators are the main radiation source for cleaning waters purpose. Remazol Orange and Black B were decomposed by Electron Beam Irradiation. Another research consisted in reuse of burnt coal for cleaning wastewater and the Orange and Red dyes were adsorbed onto zeolitic material. Both color and toxicity were the main parameters to evaluate the efficacy of the process and also the recommended criteria which allow further industrial reuse. Real effluents were also treated by both technologies in batch scale. The radiation dose suggested for real effluents varied from 2.5kGy up to 5kGy. The characteristics of obtained zeolite will be presented. The removal of color and toxicity was enough to allow the industrial reuse of those products (wastewater). (author)

Segregation of metals-containing wastewater by pH

International Nuclear Information System (INIS)

Taylor, P.A.; McTaggart, D.R.

1990-10-01

A pH-based sampling system has shown that there is a high correlation between low pH and metals contamination for the wastewater from the 4500 area (manhole 190) and the 2000 area (pump station). Wastewater from the Radiochemical Engineering Development Center (REDC) and the High Flux Isotope Reactor (HFIR) has not shown any metals concentrations above the National Pollutant Discharge Elimination System (NPDES) permit limits for the Nonradiological Wastewater Treatment Plant (NRWTP). It is recommended that pH be used as the diversion criteria for wastewater from manhole 190 and the pump station to be sent to the metals tank of the NRWTP. Any wastewater with a pH less than 6.0 or greater than 10.0 should be sent to the metals tank. Based on the results of 29 weeks of sampling, it is expected that on the order of 36m 3 /wk (9500 gal/wk) of wastewater will be diverted to the metals tank of the NRWTP. Wastewater from REDC and HFIR can be sent to the nonmetals tank, but it should be sampled periodically and analyzed by Inductively Coupled Plasma (ICP) spectrophotometer to confirm that the metals concentration is not increasing. 1 ref., 2 figs., 9 tabs

Determination of total solutes in synfuel wastewaters

Energy Technology Data Exchange (ETDEWEB)

Wallace, J.R.; Bonomo, F.S.

1984-03-01

Efforts to investigate both lyophilization and the measurement of colligative properties as an indication of total solute content are described. The objective of the work described is to develop a method for measuring total dissolved material in retort wastewaters which is simple and rugged enough to be performed in a field laboratory in support of pollution control tests. The analysis should also be rapid enough to provide timely and pertinent data to the pollution control plant operator. To be of most value, the technique developed also should be applicable to other synfuel wastewaters, most of which contain similar major components as oil shale retort waters. 4 references, 1 table.

Importance of Electrode Material in the Electrochemical Treatment of Wastewater Containing Organic Pollutants

Science.gov (United States)

Panizza, Marco

Electrochemical oxidation is a promising method for the treatment of wastewaters containing organic compounds. As a general rule, the electrochemical incineration of organics at a given electrode can take place at satisfactory rates and without electrode deactivation only at high anodic potentials in the region of the water discharge due to the participation of the intermediates of oxygen evolution. The nature of the electrode material strongly influences both the selectivity and the efficiency of the process. In particular, anodes with low oxygen evolution overpotential (i.e., good catalysts for oxygen evolution reactions), such as graphite, IrO2, RuO2, and Pt only permit the partial oxidation of organics, while anodes with high oxygen evolution overpotential (i.e., anodes that are poor catalysts for oxygen evolution reactions), such as SnO2, PbO2, and boron-doped diamond (BDD) favor the complete oxidation of organics to CO2 and so are ideal electrodes for wastewater treatment.However, the application of SnO2 and PbO2 anodes may be limited by their short service life and the risk of lead contamination, while BDD electrodes exhibit good chemical and electrochemical stability, a long life, and a wide potential window for water discharge, and are thus promising anodes for industrial-scale wastewater treatment.

Effects of the Use of Ornamental Plants and Different Substrates in the Removal of Wastewater Pollutants through Microcosms of Constructed Wetlands

Directory of Open Access Journals (Sweden)

Luis Carlos Sandoval-Herazo

2018-05-01

Full Text Available The high costs involved in treating wastewater are problems that developing countries confront, mainly in rural areas. Therefore, Constructed Wetlands (CWs, which are composed of substrate, vegetation, and microorganisms, are an economically and ecologically viable option for wastewater treatment in these places. There is a wide variety of possibilities for substrates and ornamental plants that have not yet been evaluated to be implemented in future CW designs. The goal of this study was to evaluate the process of adaptation and removal of wastewater pollutants in CW microcosms using different terrestrial ornamental plants (Lavandula sp., Spathiphyllum wallisii, and Zantedeschia aethiopica. Those plants were sown in two types of substrate: red volcanic gravel (RVG and polyethylene terephthalate (PET. CWs with vegetation reduced 5-day biochemical oxygen demand (BOD5 by 68% with RVG substrate and 63% with PET substrate, nitrates 50% in RVG substrate and 35% in PET substrate, phosphates 38% in RVG substrate and 35% in PET substrate, and fecal coliforms 64% in RVG and 59% in PET substrate. In control microcosms without vegetation, reductions were significantly lower than those in the presence of plants, with reduction of BOD5 by 61% in RVG substrate and 55% in PET substrate, nitrates 26% in RVG substrate and 22% in PET substrate, phosphates 27% in RVG substrate and 25% in PET substrate. Concerning fecal coliforms 62% were removed in RVG substrate and 59% in PET substrate. Regarding the production of flowers, Lavandula sp. did not manage to adapt and died 45 days after sowing and did not produce flowers. Spathiphyllum wallisii produced 12 flowers in RVG and nine flowers in PET, while Zantedeschia aethiopica produced 10 in RVG and 7 in PET. These results showed that the use of substrates made of RVG and PET is a viable alternative to be implemented in CWs. In addition, the reuse of PET is an option that decreases pollution by garbage. The plants

Pollution at Lake Mariut

International Nuclear Information System (INIS)

Nour ElDin, H.; Halim, S. N.; Shalby, E.

2004-01-01

Lake Mariut, south Alexandria, Egypt suffered in the recent decades from intensive pollution as a result of a continuous discharge of huge amounts of agriculture wastewater that contains a large concentration of the washed pesticides and fertilizers in addition to domestic and industrial untreated wastewater. The over flow from the lake is discharged directly to the sea through El-Max pumping station via EI-Umum drain. Lake Mariout is surrounded by a huge number of different industrial activities and also the desert road is cutting the lake, this means that a huge number of various pollutants cycle through the air and settle down in the lake, by the time and during different seasons these pollutants after accumulation and different chemical interactions will release again from the lake to the surrounding area affecting the surrounding zone

Recent Progress in TiO2-Mediated Solar Photocatalysis for Industrial Wastewater Treatment

Directory of Open Access Journals (Sweden)

Tong Zhang

2014-01-01

Full Text Available The current paper reviews the application of TiO2-mediated solar photocatalysis for industrial wastewater treatment, starting with a brief introduction on the background of industrial wastewater and the development of wastewater treatment processes, especially advanced oxidation processes (AOPs. We, then, discuss the application of solar TiO2 photocatalysis in treating different kinds of industrial wastewater, such as paper mill wastewater, textile wastewater, and olive mill wastewater. In the end, we compare solar TiO2 photocatalysis with other AOPs in terms of effectiveness, energy, and chemical consumption. Personal perspectives are also given, which may provide new insights to the future development of TiO2 photocatalysis for industrial wastewater.

Winery wastewater treatment using the land filter technique.

Science.gov (United States)

Christen, E W; Quayle, W C; Marcoux, M A; Arienzo, M; Jayawardane, N S

2010-08-01

This study outlines a new approach to the treatment of winery wastewater by application to a land FILTER (Filtration and Irrigated cropping for Land Treatment and Effluent Reuse) system. The land FILTER system was tested at a medium size rural winery crushing approximately 20,000 tonnes of grapes. The approach consisted of a preliminary treatment through a coarse screening and settling in treatment ponds, followed by application to the land FILTER planted to pasture. The land FILTER system efficiently dealt with variable volumes and nutrient loads in the wastewater. It was operated to minimize pollutant loads in the treated water (subsurface drainage) and provide adequate leaching to manage salt in the soil profile. The land FILTER system was effective in neutralizing the pH of the wastewater and removing nutrient pollutants to meet EPA discharge limits. However, suspended solids (SS) and biological oxygen demand (BOD) levels in the subsurface drainage waters slightly exceeded EPA limits for discharge. The high organic content in the wastewater initially caused some soil blockage and impeded drainage in the land FILTER site. This was addressed by reducing the hydraulic loading rate to allow increased soil drying between wastewater irrigations. The analysis of soil characteristics after the application of wastewater found that there was some potassium accumulation in the profile but sodium and nutrients decreased after wastewater application. Thus, the wastewater application and provision of subsurface drainage ensured adequate leaching, and so was adequate to avoid the risk of soil salinisation. Crown Copyright 2010. Published by Elsevier Ltd. All rights reserved.

Evaluation on ecological stability and biodegradation of dyeing wastewater pre-treated by electron beam

International Nuclear Information System (INIS)

Lee, M.J.; Park, C.K.; Yoo, D.H.; Lee, J.K.; Lee, B.J.; Han, B.S.; Kim, J.K.; Kim, Y.R.

2005-01-01

Biological treatment of dye wastewater pre-treated by electron beam has been performed in order to evaluate the biodegradation and ecological stability of effluent. In the process of electron-beam treatment of wastewater there are utilized chemical transformations of pollutants induced by ionizing radiation. Partial decomposition of pollutant takes place as well as transformations of pollutant molecules that result in improving subsequent purification stages like as biological processing. Dyeing wastewater contains many kind of pollutants which are difficult to be decomposed completely by microorganisms. In this study, biodegradation with dyeing wastewater pre-treated by electron beams was observed. On the other hand, consideration on public acceptance in terms of ecological stability of biological effluent pre-treated by electron beams was given in this study. The results of laboratory investigations on biodegradation and ecological stability of effluent showed that biodegradation of dye wastewater pre-treated by electron beam was enhanced compared to unirradiated one. In the initial stage of biological oxidation regardless of different HRT, dye wastewater pre-treated by electron beam could be oxidized easily compare to without treated one. More number of survived daphnia magna could be observed in the biological effluent pre-treated by electron beam. This means that biological effluent pre-treated by electron beam can be said 'it is safe on the ecological system'

Agricultural use of treated municipal wastewaters preserving environmental sustainability

OpenAIRE

Pietro Rubino; Maurizia Catalano; Antonio Lonigro

2007-01-01

In this paper the utility of the treated municipal wastewaters in agriculture, analyzing the chemical, physical and microbiological characteristics and their pollution indicators evaluation are being illustrated. Some methods employed for treating wastewaters are examined, as well as instructions and rules actually in force in different countries of the world, for evaluating the legislative hygienic and sanitary and agronomic problems connected with the treated wastewaters use, are being coll...

Mixotrophic cultivation of a microalga Scenedesmus obliquus in municipal wastewater supplemented with food wastewater and flue gas CO2 for biomass production.

Science.gov (United States)

Ji, Min-Kyu; Yun, Hyun-Shik; Park, Young-Tae; Kabra, Akhil N; Oh, In-Hwan; Choi, Jaeyoung

2015-08-15

The biomass and lipid/carbohydrate production by a green microalga Scenedesmus obliquus under mixotrophic condition using food wastewater and flue gas CO2 with municipal wastewater was investigated. Different dilution ratios (0.5-2%) of municipal wastewater with food wastewater were evaluated in the presence of 5, 10 and 14.1% CO2. The food wastewater (0.5-1%) with 10-14.1% CO2 supported the highest growth (0.42-0.44 g L(-1)), nutrient removal (21-22 mg TN L(-1)), lipid productivity (10-11 mg L(-1)day(-1)) and carbohydrate productivity (13-16 mg L(-1)day(-1)) by S. obliquus after 6 days of cultivation. Food wastewater increased the palmitic and oleic acid contents up to 8 and 6%, respectively. Thus, application of food wastewater and flue gas CO2 can be employed for enhancement of growth, lipid/carbohydrate productivity and wastewater treatment efficiency of S. obliquus under mixotrophic condition, which can lead to development of a cost effective strategy for microalgal biomass production. Copyright © 2015 Elsevier Ltd. All rights reserved.

Whole effluent assessment of industrial wastewater for determination of BAT compliance. Part 2: metal surface treatment industry.

Science.gov (United States)

Gartiser, Stefan; Hafner, Christoph; Hercher, Christoph; Kronenberger-Schäfer, Kerstin; Paschke, Albrecht

2010-06-01

Toxicity testing has become a suitable tool for wastewater evaluation included in several reference documents on best available techniques of the Integrated Pollution Prevention and Control (IPPC) Directive. The IPPC Directive requires that for direct dischargers as well as for indirect dischargers, the same best available techniques should be applied. Within the study, the whole effluent assessment approach of OSPAR has been applied for determining persistent toxicity of indirectly discharged wastewater from the metal surface treatment industry. Twenty wastewater samples from the printed circuit board and electroplating industries which indirectly discharged their wastewater to municipal wastewater treatment plants (WWTP) have been considered in the study. In all factories, the wastewater partial flows were separated in collecting tanks and physicochemically treated in-house. For assessing the behaviour of the wastewater samples in WWTPs, all samples were biologically pretreated for 7 days in the Zahn-Wellens test before ecotoxicity testing. Thus, persistent toxicity could be discriminated from non-persistent toxicity caused, e.g. by ammonium or readily biodegradable compounds. The fish egg test with Danio rerio, the Daphnia magna acute toxicity test, the algae test with Desmodesmus subspicatus, the Vibrio fischeri assay and the plant growth test with Lemna minor have been applied. All tests have been carried out according to well-established DIN or ISO standards and the lowest ineffective dilution (LID) concept. Additionally, genotoxicity was tested in the umu assay. The potential bioaccumulating substances (PBS) were determined by solid-phase micro-extraction and referred to the reference compound 2,3-dimethylnaphthalene. The chemical oxygen demand (COD) and total organic carbon (TOC) values of the effluents were in the range of 30-2,850 mg L(-1) (COD) and 2-614 mg L(-1) (TOC). With respect to the metal concentrations, all samples were not heavily polluted. The

Selection of technologies for municipal wastewater treatment

Directory of Open Access Journals (Sweden)

Juan Pablo Rodríguez Miranda

2015-11-01

Full Text Available In water environmental planning in watersheds should contain aspects for the decontamination of receiving water body, therefore the selection of the treatment plants municipal wastewater in developing countries, you should consider aspects of the typical composition raw wastewater pollutant removal efficiency by technology, performance indicators for technology, environmental aspects of localization and spatial localization strategy. This methodology is built on the basis of technical, economic and environmental attributes, such as a tool for decision making future investments in treatment plants municipal wastewater with multidisciplinary elements.

Occurrence of emerging pollutants in urban wastewater and their removal through biological treatment followed by ozonation.

Science.gov (United States)

Rosal, Roberto; Rodríguez, Antonio; Perdigón-Melón, José Antonio; Petre, Alice; García-Calvo, Eloy; Gómez, María José; Agüera, Ana; Fernández-Alba, Amadeo R

2010-01-01

This work reports a systematic survey of over seventy individual pollutants in a Sewage Treatment Plant (STP) receiving urban wastewater. The compounds include mainly pharmaceuticals and personal care products, as well as some metabolites. The quantification in the ng/L range was performed by Liquid Chromatography-QTRAP-Mass Spectrometry and Gas Chromatography coupled to Mass Spectrometry. The results showed that paraxanthine, caffeine and acetaminophen were the main individual pollutants usually found in concentrations over 20 ppb. N-formyl-4-amino-antipiryne and galaxolide were also detected in the ppb level. A group of compounds including the beta-blockers atenolol, metoprolol and propanolol; the lipid regulators bezafibrate and fenofibric acid; the antibiotics erythromycin, sulfamethoxazole and trimethoprim, the antiinflammatories diclofenac, indomethacin, ketoprofen and mefenamic acid, the antiepileptic carbamazepine and the antiacid omeprazole exhibited removal efficiencies below 20% in the STP treatment. Ozonation with doses lower than 90 microM allowed the removal of many individual pollutants including some of those more refractory to biological treatment. A kinetic model allowed the determination of second order kinetic constants for the ozonation of bezafibrate, cotinine, diuron and metronidazole. The results show that the hydroxyl radical reaction was the major pathway for the oxidative transformation of these compounds. (c) 2009 Elsevier Ltd. All rights reserved.

Application of Electrocoagulation Process for Dairy Wastewater Treatment

Directory of Open Access Journals (Sweden)

Edris Bazrafshan

2013-01-01

Full Text Available Dairy industry wastewater is characterized by high biochemical oxygen demand (BOD5, chemical oxygen demand (COD, and other pollution load. The purpose of this study was to investigate the effects of the operating parameters such as applied voltage, number of electrodes, and reaction time on a real dairy wastewater in the electrocoagulation process. For this purpose, aluminum electrodes were used in the presence of potassium chloride as electrolytes. It has been shown that the removal efficiency of COD, BOD5, and TSS increased with increasing the applied voltage and the reaction time. The results indicate that electrocoagulation is efficient and able to achieve 98.84% COD removal, 97.95% BOD5 removal, 97.75% TSS removal, and >99.9% bacterial indicators at 60 V during 60 min. The experiments demonstrated the effectiveness of electrocoagulation techniques for the treatment of dairy wastewaters. Finally, the results demonstrated the technical feasibility of electrocoagulation process using aluminum electrodes as a reliable technique for removal of pollutants from dairy wastewaters.

Phycoremediation of Tannery Wastewater Using Microalgae Scenedesmus Species.

Science.gov (United States)

Ajayan, Kayil Veedu; Selvaraju, Muthusamy; Unnikannan, Pachikaran; Sruthi, Palliyath

2015-01-01

A number of microalgae species are efficient in removing toxicants from wastewater. Many of these potential species are a promising, eco-friendly, and sustainable option for tertiary wastewater treatment with a possible advantage of improving the economics of microalgae cultivation for biofuel production. The present study deals with the phycoremediation of tannery wastewater (TWW) using Scenedesmus sp. isolated from a local habitat. The test species was grown in TWW under laboratory conditions and harvested on the 12th day. The results revealed that the algal biomass during the growth period not only reduced the pollution load of heavy metals (Cr-81.2-96%, Cu-73.2-98%, Pb-75-98% and Zn-65-98%) but also the nutrients (NO3 >44.3% and PO4 >95%). Fourier Transform Infrared (FTIR) spectrums of Scenedesmus sp. biomass revealed the involvement of hydroxyl amino, carboxylic and carbonyl groups. The scanning electron micrograph (SEM) and Energy Dispersive X-ray Spectroscopic analysis (EDS) revealed the surface texture, morphology and element distribution of the biosorbent. Furthermore, the wastewater generated during wet-blue tanning process can support dense population of Scenedesmus sp., making it a potential growth medium for biomass production of the test alga for phycoremediation of toxicants in tannery wastewaters.

Removal of pollutants with determination of power consumption from landfill leachate wastewater using an electrocoagulation process: optimization using response surface methodology (RSM)

Science.gov (United States)

Asaithambi, Perumal; Beyene, Dejene; Aziz, Abdul Raman Abdul; Alemayehu, Esayas

2018-05-01

Treatment of landfill leachate wastewater by electrocoagulation process using an aluminium electrode was investigated in a batch electrochemical cell reactor. Response surface methodology based on central composite design was used to optimize the operating parameters for the removal of % color and % total organic carbon (TOC) together with power consumption from landfill leachate. Effects of three important independent parameters such as current density ( X 1), inter-electrode distance ( X 2) and solution pH ( X 3) of the landfill leachate sample on the % color and % TOC removal with power consumption were investigated. A quadratic model was used to predict the % color and % TOC removal with power consumption in different experimental conditions. The significance of each independent variable was calculated by analysis of variance. In order to achieve the maximum % color and % TOC removal with minimum of power consumption, the optimum conditions were about current density ( X 1)—5.25 A/dm2, inter-electrode distance ( X 2)—1 cm and initial solution of effluent pH ( X 3)—7.83, with the yield of color removal of 74.57%, and TOC removal of 51.75% with the power consumption of 14.80 kWh/m3. Electrocoagulation process could be applied to remove pollutants from industrial effluents and wastewater.

Identification of potential toxicity caused by O3 and ClO2 treatment of pharmaceuticals in wastewater

DEFF Research Database (Denmark)

Furuhagen, S. M.; Hörsing, Maritha; Ledin, Anna

2011-01-01

Chemical oxidation treatment is an effective innovative technology in wastewater treatment plants for removal of micro-pollutants in the effluent. In particular, ozonation (O3) and chlorine dioxide (ClO2) treatments are commonly used to degrade organic pollutants. By oxidation, the micro...... complemented by oxidative stress biomarkers to understand effect mechanisms in different test systems and species. All tests were complemented with chemical analysis to confirm to what degree the pharmaceuticals have been mineralized and degraded by oxidation. Early results with APIs in milli-Q water treated...... Carbamazepine by chemical oxidation were more harmful to aquatic organisms compared to the parent compound. The aim of our study is to evaluate the potential risk of oxidation treatment, using O3 and ClO2, due to formation of toxic transformation products. The ecotoxicological effects caused by the two...

Effect of solar radiation on multidrug resistant E. coli strains and antibiotic mixture photodegradation in wastewater polluted stream

International Nuclear Information System (INIS)

Rizzo, L.; Fiorentino, A.; Anselmo, A.

2012-01-01

The effect of solar radiation on the inactivation of multidrug resistant Escherichia coli (MDR) strains selected from an urban wastewater treatment plant (UWWTP) effluent and the change of their resistance to a mixture of three antibiotics (evaluated in terms of minimum inhibit concentration (MIC)) in wastewater polluted stream were investigated. The solar photodegradation of the mixture of the three target antibiotics (amoxicillin (AMX), ciprofloxacin (CPX), and sulfamethoxazole (SMZ)) was also evaluated. Additionally, since UWWTP effluents are possible sources of antibiotics and antibiotic resistant bacteria, the disinfection by conventional chlorination process of the UWWTP effluent inoculated with MDR strains was investigated too. Solar radiation poorly affected the inactivation of the two selected antibiotic resistant E. coli strains (40 and 60% after 180 min irradiation). Moreover, solar radiation did not affect strain resistance to AMX (MIC > 256 μg/mL) and SMZ (MIC > 1024 μg/mL), but affected resistance of the lower resistance strain to CPX (MIC decreased by 33% but only after 180 min of irradiation). Chlorination of wastewater sample strongly decreased the number of the two selected antibiotic resistant E. coli strains (99.667 and 99.999%), after 60 min of contact time at 2.0 mg/L initial chlorine concentration, but the resistance of survived colonies to antibiotics was unchanged. Finally, the solar photodegradation rate of the antibiotic mixture (1 mg/L initial concentration respectively) resulted in the following order (half-life time): CPX (t 1/2 = 24 min) 1/2 = 99 min) 1/2 = 577 min). Accordingly, the risk of the development of resistance to SMZ in surface water is significantly higher compared to CPX and AMX. - Highlights: ► Solar radiation did not affect E. coli strain resistance to AMX and SMZ. ► Solar radiation affected the resistance of one E. coli strain to CPX. ► MIC for CPX decreased by 33% after 180 min of solar irradiation. �

Effect of solar radiation on multidrug resistant E. coli strains and antibiotic mixture photodegradation in wastewater polluted stream

Energy Technology Data Exchange (ETDEWEB)

Rizzo, L., E-mail: l.rizzo@unisa.it [Department of Civil Engineering, University of Salerno, via Ponte don Melillo, 1-84084 Fisciano (Italy); Fiorentino, A. [Department of Civil Engineering, University of Salerno, via Ponte don Melillo, 1-84084 Fisciano (Italy); Anselmo, A. [Pluriacque, via Alento, 84060 Prignano Cilento (Italy)

2012-06-15

The effect of solar radiation on the inactivation of multidrug resistant Escherichia coli (MDR) strains selected from an urban wastewater treatment plant (UWWTP) effluent and the change of their resistance to a mixture of three antibiotics (evaluated in terms of minimum inhibit concentration (MIC)) in wastewater polluted stream were investigated. The solar photodegradation of the mixture of the three target antibiotics (amoxicillin (AMX), ciprofloxacin (CPX), and sulfamethoxazole (SMZ)) was also evaluated. Additionally, since UWWTP effluents are possible sources of antibiotics and antibiotic resistant bacteria, the disinfection by conventional chlorination process of the UWWTP effluent inoculated with MDR strains was investigated too. Solar radiation poorly affected the inactivation of the two selected antibiotic resistant E. coli strains (40 and 60% after 180 min irradiation). Moreover, solar radiation did not affect strain resistance to AMX (MIC > 256 {mu}g/mL) and SMZ (MIC > 1024 {mu}g/mL), but affected resistance of the lower resistance strain to CPX (MIC decreased by 33% but only after 180 min of irradiation). Chlorination of wastewater sample strongly decreased the number of the two selected antibiotic resistant E. coli strains (99.667 and 99.999%), after 60 min of contact time at 2.0 mg/L initial chlorine concentration, but the resistance of survived colonies to antibiotics was unchanged. Finally, the solar photodegradation rate of the antibiotic mixture (1 mg/L initial concentration respectively) resulted in the following order (half-life time): CPX (t{sub 1/2} = 24 min) < AMX (t{sub 1/2} = 99 min) < SMZ (t{sub 1/2} = 577 min). Accordingly, the risk of the development of resistance to SMZ in surface water is significantly higher compared to CPX and AMX. - Highlights: Black-Right-Pointing-Pointer Solar radiation did not affect E. coli strain resistance to AMX and SMZ. Black-Right-Pointing-Pointer Solar radiation affected the resistance of one E. coli strain

Characterization and correlations of various pollution parameters in the tannery effluent

International Nuclear Information System (INIS)

Haydar, S.

2008-01-01

Wastewater characterization is an integral part of treatment and management strategies for industrial effluents. This paper outlines the results of detailed wastewater characterization studies conducted for a tannery in Sheikhupura, Punjab. The results of this study demonstrated that the composition of tannery wastewater could change continuously due to inherent nature of tannery operations. In general, tannery effluent was alkaline in nature and highly polluted in terms of organic, solids, sulfates, sulfides and chromium content. Basic ingredients of tannery effluent i.e. high alkalinity and substantial portions of BOD (Biochemical Oxygen Demand), COD (Chemical Oxygen Demand) and other pollutants in particulate form rendered it suitable for enhanced pollutant removals at primary stage of treatment using suitable coagulants. Results of primary treatment of wastewater from this tannery suggested that primary treatment alone was not capable of reducing pollutant loads significantly. Hence post-primary biological treatment was required to meet local effluent quality standards. (author)

Present status on the use of electron accelerator for wastewater treatment in Korea

International Nuclear Information System (INIS)

Lee, Myun Joo; Han, Bum Soo; Choi, Jang Seung; Kang, Ho

2006-01-01

In the part 1, four major irradiation R and D works studied in field of wastewater treatment in Korea were introduced. Disinfection of total coli-forms in unchlorinated secondary effluent, removal of color in dyeing wastewater and feasibility test to control algal bloom used the electron beam as a radiation source. Treatment of groundwater polluted by TCE and PCE used gamma rays as a radiation source. Backgrounds and experimental results on each research topic were introduced. In the part 2, national on-going projects related to wastewater treatment using irradiation technology in Korea were introduced. With regarding these projects, EB treatment plant for textile dyeing wastewater was described based on the construction and evaluation of ecological stability. (author)

Wastewater Management Efficiency and Determinant Factors in the Chinese Industrial Sector from 2004 to 2014

Directory of Open Access Journals (Sweden)

Hidemichi Fujii

2017-08-01

Full Text Available This study analyzes industrial wastewater management efficiency using a Chinese provincial dataset from 2004 to 2014. The weighted Russell directional distance model is used to evaluate the efficiency of management practices. Determinants analysis was conducted based on governmental policy, pollution abatement, and market factors to identify the main drivers of industrial wastewater management efficiency in China. The results indicate that the wastewater management efficiency improved in the eastern and central regions. However, there is a significant efficiency gap between provinces in the western region. Moreover, the main determinants of wastewater management efficiency differ among regions and pollutants.

Evolution of industrial wastewater pollution in the Barcelona Metropolitan Area; Evolucion de la contaminacion industrial en las aguas residuales del area metropolitana de Barcelona

Energy Technology Data Exchange (ETDEWEB)

Mantecon Pascual, R.

2005-07-01

The Environmental Agency of the Barcelona Metropolitan Area has full powers regarding sewerage. Industrial wastewater emptied into the public sewer system has been monitored and analysed since 1988. the data showing the evolution of the pollution in industrial wastewater are presented, broken down by activities and parameters. These data are based on the analysis of 14,528 samples taken during 19,555 inspections of 5,655 factories. It was found that there has been a gradual improvement in the quality of the effluents. Failure to meet the requirements concerning one or more of the physico-chemical parameters fell from 71% to 39% of the samples analysed. (Author)

Sterols indicate water quality and wastewater treatment efficiency.

Science.gov (United States)

Reichwaldt, Elke S; Ho, Wei Y; Zhou, Wenxu; Ghadouani, Anas

2017-01-01

As the world's population continues to grow, water pollution is presenting one of the biggest challenges worldwide. More wastewater is being generated and the demand for clean water is increasing. To ensure the safety and health of humans and the environment, highly efficient wastewater treatment systems, and a reliable assessment of water quality and pollutants are required. The advance of holistic approaches to water quality management and the increasing use of ecological water treatment technologies, such as constructed wetlands and waste stabilisation ponds (WSPs), challenge the appropriateness of commonly used water quality indicators. Instead, additional indicators, which are direct measures of the processes involved in the stabilisation of human waste, have to be established to provide an in-depth understanding of system performance. In this study we identified the sterol composition of wastewater treated in WSPs and assessed the suitability of human sterol levels as a bioindicator of treatment efficiency of wastewater in WSPs. As treatment progressed in WSPs, the relative abundance of human faecal sterols, such as coprostanol, epicoprostanol, 24-ethylcoprostanol, and sitostanol decreased significantly and the sterol composition in wastewater changed significantly. Furthermore, sterol levels were found to be correlated with commonly used wastewater quality indicators, such as BOD, TSS and E. coli. Three of the seven sterol ratios that have previously been used to track sewage pollution in the environment, detected a faecal signal in the effluent of WSPs, however, the others were influenced by high prevalence of sterols originating from algal and fungal activities. This finding poses a concern for environmental assessment studies, because environmental pollution from waste stabilisation ponds can go unnoticed. In conclusion, faecal sterols and their ratios can be used as reliable indicators of treatment efficiency and water quality during wastewater

Treatment of landfill leachate biochemical effluent using the nano-Fe3O4/Na2S2O8 system: Oxidation performance, wastewater spectral analysis, and activator characterization.

Science.gov (United States)

Liu, Zhanmeng; Li, Xian; Rao, Zhiwei; Hu, Fengping

2018-02-15

Nano-Fe 3 O 4 was used as heterogeneous catalyst to activate Na 2 S 2 O 8 for the generation of the sulfate radicals (SO 4 - ) to oxidize the residual pollutants in landfill leachate biochemical effluent. The oxidation performance, wastewater spectral analysis and activator characterization were discussed. Oxidation experimental result shows that nano-Fe 3 O 4 has obvious catalytic effect on Na 2 S 2 O 8 and can significantly enhance the oxidation efficiencies of Na 2 S 2 O 8 on landfill leachate biochemical effluent, with COD and color removals above 63% and 95%, respectively. Based on the analyses of three-dimensional excitation emission matrix fluorescence spectrum (3DEEM), ultraviolet-visible spectra (UV-vis), and Fourier Transform infrared spectroscopy (FTIR) of wastewater samples before and after treatment, it can be concluded that the pollution level of dissolved organic matter (DOM) declined and that the humic acid (HA) fractions were efficiently degraded into small molecules of fulvic acid (FA) fractions with less weight and stable structure. Compared to the raw wastewater sample, the aromaticity and substituent groups of the DOM were lessened in the treated wastewater sample. Moreover, the main structure of the organics and functional groups were changed by the Fe 3 O 4 /Na 2 S 2 O 8 system, with substantial decrease of conjugated double bonds. The micro morphology of nano-Fe 3 O 4 was characterized before and after reaction by the methods of scanning electron microscope spectra (SEM), X-ray diffraction pattern (XRD), and X-ray photoelectron spectroscopy (XPS). The XRD pattern analysis showed that nano-Fe 3 O 4 was oxidized into r-Fe 2 O 3 and that the particle size of it also became smaller after reaction. XPS was employed to analyze the content and iron valence on the nano-Fe 3 O 4 surface, and it can be found that the ratio of Fe 3+ /Fe 2+ decreased from 1.8 before reaction to 0.8 after reaction. From the SEM analysis after the treatment, it was

Using oysters as anthropogenic indicators to evaluate the occurrence of the wastewater contamination of the estuaries

Science.gov (United States)

Ding, Wang-Hsien

2015-04-01

The oyster (Crossostrea gigas) is an important aquacultural species in Taiwan. With an area of over 85% of the total inshore aquacultural field, its production, measured by quantity or economic value, ranks above all other aquacultural products in Taiwan. Since oyster's habitat is on shelves near the coast, the samples from a particular "oyster cultural site" can be applied to evaluate the pollution of a segment of the coastal water. Deficient wastewater treatment has caused untreated wastewaters to have flown in rivers into oyster cultural areas in estuaries as well as shallow coastal water. Therefore, the concentration of pollutants in the oysters can be used as anthropogenic indicators to evaluate the occurrence of the for wastewater contamination of the coastal water. In this study, two groups of anthropogenic organic compounds, chlorinated flame retardant (i.e., Dechlorane Plus) and benzophenone-type UV absorbing substances (i.e., 2-hydroxy-4-methoxybenzophenone), were determined in oyster samples as wastewater contamination pollutants. The method involves the use of matrix solid-phase dispersion prior to their determination by gas chromatography mass spectrometry. The results show that these two groups of compounds are ubiquitous in oysters with the concentrations of chlorinated flame retardant and benzophenone-type UV absorbing substances ranging from 0.3 to 3.6 ng/g and from 120 to 910 ng/g (lipid weight), respectively. Oysters are useful anthropogenic indicators of organic pollutants in Taiwan's marine environment. The ubiquity of these pollutants in Taiwan's coastal environment supports the need for greater awareness of bioaccumulation processes.

The use of moving bed bio-reactor to laundry wastewater treatment

Science.gov (United States)

Bering, Sławomira; Mazur, Jacek; Tarnowski, Krzysztof; Janus, Magdalena; Mozia, Sylwia; Waldemar Morawski, Antoni

2017-11-01

Large laboratory scale biological treatment test of industrial real wastewater, generated in industrial big laundry, has been conducted in the period of May 2016-August 2016. The research aimed at selection of laundry wastewater treatment technology included tests of two-stage Moving Bed Bio Reactor (MBBR), with two reactors filled with carriers Kaldnes K5 (specific area - 800 m2/m3), have been realized in aerobic condition. Operating on site, in the laundry, reactors have been fed real wastewater from laundry retention tank. To the laundry wastewater, contained mainly surfactants and impurities originating from washed fabrics, a solution of urea to supplement nitrogen content and a solution of acid to correct pH have been added. Daily flow of raw wastewater Qd was equal to 0.6-0.8 m3/d. The values of determined wastewater quality indicators showed that substantial decrease of pollutants content have been reached: BOD5 by 94.7-98.1%, COD by 86.9-93.5%, the sum of anionic and nonionic surfactants by 98.7-99.8%. The quality of the purified wastewater, after star-up period, meets the legal requirements regarding the standards for wastewater discharged to the environment.

Application of agricultural fibers in pollution removal from aqueous solution

International Nuclear Information System (INIS)

Mahvi, A. H.

2008-01-01

Discharging different kinds of wastewater and polluted waters such as domestic, industrial and agricultural wastewaters into environment, especially to surface water, can cause heavy pollution of this body sources. With regard to increasing effluent discharge standards to the environment, high considerations should be made when selecting proper treatment processes. Any of chemical, biological and physical treatment processes have its own advantages and disadvantages. It should be kept in mind that economical aspects are important, too. In addition, employing environment friendly methods for treatment is emphasized much more these days. Application of some waste products that could help in this regard, in addition to reuse of these waste materials, can be an advantage, Agricultural fibers are agricultural wastes and are generated in high amounts. The majority of such materials is generated in developing countries and, since they are very cheap, they can be employed as bio sorbents in water and wastewater applications. Polluted surface waters, different wastewaters and partially treated wastewater may be contaminated by heavy metals or some organic matters and these waters should be treated to reduce pollution. The results of investigations show high efficiency of agricultural fibers in heavy metal and phenol removal. In this paper, some studies conducted by the author of this article and other investigators are reviewed

Light-Assisted Advanced Oxidation Processes for the Elimination of Chemical and Microbiological Pollution of Wastewaters in Developed and Developing Countries

Directory of Open Access Journals (Sweden)

Stefanos Giannakis

2017-06-01

Full Text Available In this work, the issue of hospital and urban wastewater treatment is studied in two different contexts, in Switzerland and in developing countries (Ivory Coast and Colombia. For this purpose, the treatment of municipal wastewater effluents is studied, simulating the developed countries’ context, while cheap and sustainable solutions are proposed for the developing countries, to form a barrier between effluents and receiving water bodies. In order to propose proper methods for each case, the characteristics of the matrices and the targets are described here in detail. In both contexts, the use of Advanced Oxidation Processes (AOPs is implemented, focusing on UV-based and solar-supported ones, in the respective target areas. A list of emerging contaminants and bacteria are firstly studied to provide operational and engineering details on their removal by AOPs. Fundamental mechanistic insights are also provided on the degradation of the effluent wastewater organic matter. The use of viruses and yeasts as potential model pathogens is also accounted for, treated by the photo-Fenton process. In addition, two pharmaceutically active compound (PhAC models of hospital and/or industrial origin are studied in wastewater and urine, treated by all accounted AOPs, as a proposed method to effectively control concentrated point-source pollution from hospital wastewaters. Their elimination was modeled and the degradation pathway was elucidated by the use of state-of-the-art analytical techniques. In conclusion, the use of light-supported AOPs was proven to be effective in degrading the respective target and further insights were provided by each application, which could facilitate their divulgation and potential application in the field.

Light-Assisted Advanced Oxidation Processes for the Elimination of Chemical and Microbiological Pollution of Wastewaters in Developed and Developing Countries.

Science.gov (United States)

Giannakis, Stefanos; Rtimi, Sami; Pulgarin, Cesar

2017-06-26

In this work, the issue of hospital and urban wastewater treatment is studied in two different contexts, in Switzerland and in developing countries (Ivory Coast and Colombia). For this purpose, the treatment of municipal wastewater effluents is studied, simulating the developed countries' context, while cheap and sustainable solutions are proposed for the developing countries, to form a barrier between effluents and receiving water bodies. In order to propose proper methods for each case, the characteristics of the matrices and the targets are described here in detail. In both contexts, the use of Advanced Oxidation Processes (AOPs) is implemented, focusing on UV-based and solar-supported ones, in the respective target areas. A list of emerging contaminants and bacteria are firstly studied to provide operational and engineering details on their removal by AOPs. Fundamental mechanistic insights are also provided on the degradation of the effluent wastewater organic matter. The use of viruses and yeasts as potential model pathogens is also accounted for, treated by the photo-Fenton process. In addition, two pharmaceutically active compound (PhAC) models of hospital and/or industrial origin are studied in wastewater and urine, treated by all accounted AOPs, as a proposed method to effectively control concentrated point-source pollution from hospital wastewaters. Their elimination was modeled and the degradation pathway was elucidated by the use of state-of-the-art analytical techniques. In conclusion, the use of light-supported AOPs was proven to be effective in degrading the respective target and further insights were provided by each application, which could facilitate their divulgation and potential application in the field.

Use of Both Anode and Cathode Reactions in Wastewater Treatment

Science.gov (United States)

Brillas, Enric; Sirés, Ignasi; Cabot, Pere LluíS.

Here, we describe the fundamentals, laboratory experiments, and environmental applications of indirect electrooxidation methods based on H2O2 electrogeneration such as electro-Fenton, photoelectro-Fenton and peroxicoagulation for the treatment of acidic wastewaters containing toxic and recalcitrant organics. These methods are electrochemical advanced oxidation processes that can be used in divided and undivided electrolytic cells in which pollutants are oxidized by hydroxyl radical (•OH) produced from anode and/or cathode reactions. H2O2 is generated from the two-electron reduction of O2 at reticulated vitreous carbon, graphite, carbon-felt, and O2-diffusion cathodes. The most usual method is electro-Fenton where Fe2 + added to the wastewater reacts with electrogenerated H2O2 to yield •OH and Fe3 + from Fenton's reaction. An advantage of this technique is that Fe2 + is continuously regenerated from cathodic reduction of Fe3 +. The characteristics of different electro-Fenton systems where pollutants are simultaneously destroyed by •OH formed in the medium from Fenton's reaction and at the anode surface from water oxidation are explained. The effect of the anode [Pt or boron-doped diamond (BDD)] and cathode (carbon-felt or O2-diffusion) on the degradation rate of persistent industrial by-products, herbicides, pharmaceuticals, dyes, etc. is examined. Initial pollutants react much more rapidly with •OH formed in the medium and their degradation sequences are discussed from aromatic intermediates and finally short aliphatic acids are detected. The synergetic positive catalytic effect of Cu2 + on the electro-Fenton process is evidenced. The photoelectro-Fenton method involves the irradiation of the wastewater with UVA light that rapidly photodecomposes complexes of Fe3 + with final carboxylic acids enhancing total decontamination. The peroxicoagulation method uses a sacrificial Fe anode that is continuously oxidized to Fe2 + and organics are either mineralized

Water pollution control for underground coal gasification

International Nuclear Information System (INIS)

Humenick, M.J.

1984-01-01

Water pollution arising from underground gasification of coal is one of the important considerations in the eventual commercialization of the process. Because many coal seams which are amenable to in situ gasification are also ground-water aquifers, contaminants may be released to these ground waters during and after gasification. Also, when product gas is processed above ground for use, wastewater streams are generated which are too polluted to be discharged. The purpose of this paper is to characterize the nature of the groundwater and above-ground pollutants, discuss the potential long and short-term effects on ground water, propose control and restoration strategies, and to identify potential wastewater treatment schemes

Synthesis, characterization and catalytic performance of ZnO-CeO2 nanoparticles in wet oxidation of wastewater containing chlorinated compounds

Science.gov (United States)

Anushree; Kumar, S.; Sharma, C.

2017-11-01

Here we report the catalytic property of ZnO-CeO2 nanoparticles towards oxidative degradation of organic pollutants present in industrial wastewater. The catalysts were prepared by co-precipitation method without using any surfactant. The physicochemical properties of catalysts were studied by XRD, Raman, XPS, N2-sorption, FE-SEM, TEM and EDX techniques. The characterization results confirmed the formation of porous ZnO-CeO2 nanocatalysts with high surface area, pore volume and oxygen vacancies. ZnO-CeO2 nanocatalysts exhibited appreciable efficiency in CWAO of industrial wastewater under mild conditions. The Ce40Zn60 catalyst was found to be most efficient with 72% color, 64% chemical oxygen demand (COD) and 63% total organic carbon (TOC) removal. Efficient removal of chlorophenolics (CHPs, 59%) and adsorbable organic halides (AOX, 54%) indicated the feasibility of using ZnO-CeO2 nanocatalysts in degradation of non-biodegradable and toxic chlorinated compounds.

Qualitative and Quantitative Assessment of Wastewater of Pistachio Processing Terminals (Case Study: Kerman city

Directory of Open Access Journals (Sweden)

F Khademi

2016-03-01

Full Text Available Introduction: Wastewaters resulting from seasonal processing such as pistachio processing industry are one of the most important factors of environmental pollution. High concentration of pollutants are the qualitative characteristics of wastewaters that due high consumption of water and energy resources as well as high levels production of waste have a good potential to realization of projects to reduce the environmental impacts and optimizing the consumption of energy resources.The aim of this study was to determine the wastewater̛ s quality and quantity of pistachio processing terminals. Methods: this study is cross-sectional study that has been implemented from mid –September until late October (pistachio harvest season in each of the years 2012-2013-2014 in Kerman.Firstely according to field study, the characteristics and location of 20 pistachio processing terminals were determined by a GPS device. Then 8 pistachio processing terminals were selected in around of wastewater collection system. Composite sampling method with total of 72 samples was done in each year during pistachio operation. Samples were conducted from pistachio processing wastewater screen filter outlet. In each of samples BOD5, COD, TSS, pH and Total phenolic were determined. Sampling and tests were done according to water and wastewater standard methods book (20th edition. Concentration of Phenolic compounds was measured by folin ciocaltive method. The Data was analyzed by SPSS software. Results: the average of total produced wastewater in pistachio processing terminals in this study was 85.9m3/d. The average BOD5, COD, TSS, Total phenolic and PH were 6106, 21570, 682, 4154 (mg/L and 5.5 respectively. Conclusion: The obtained results from raw wastewater of pistachio processing terminals showed they have high BOD and COD. This is caused by presentation of priority pollutants (phenolic compounds which have high potential in pollution and toxicity for discharging any

Wastewater reuse

Directory of Open Access Journals (Sweden)

Milan R. Radosavljević

2013-12-01

Full Text Available Water scarcity and water pollution are some of the crucial issues that must be addressed within local and global perspectives. One of the ways to reduce the impact of water scarcity  and to minimizine water pollution is to expand water and wastewater reuse. The local conditions including regulations, institutions, financial mechanisms, availability of local technology and stakeholder participation have a great influence on the decisions for wastewater reuse. The increasing awareness of food safety and the influence of the countries which import food are influencing policy makers and agriculturists to improve the standards of wastewater reuse in agriculture. The environmental awareness of consumers has been putting pressure on the producers (industries to opt for environmentally sound technologies including those which conserve water and reduce the level of pollution. It may be observed that we have to move forwards to implement strategies and plans for wastewater reuse. However, their success and sustainability will depend on political will, public awareness and active support from national and international agencies to create favorable    environment for the promotion of environmentally sustainable technologies. Wastewater treatment has a long history, especially in agriculture, but also in industry and households. Poor quality of wastewater can pose a significant risk to the health of farmers and users of agricultural products. The World Health Organization (WHO is working on a project for the reuse of wastewater in agriculture. To reduce effects of human activities to the minimum, it is necessary to provide such technical and technological solutions that would on the one hand ensure complying with  the existing regulations and legislation, and on the other hand provide economically viable systems as seen through investments and operating costs. The use of wastewater The practice of using wastewater varies from country to country. Its

Polyacrylamide+Al2(SO4)3 and polyacrylamide+CaO remove coliform bacteria and nutrients from swine wastewater

International Nuclear Information System (INIS)

Entry, J.A.; Phillips, Ian; Stratton, Helen; Sojka, R.E.

2003-01-01

Polyacrylamide mixture may be able to reduce run-off of enteric bacteria from animal wastes. - Animal wastes are a major contributor of nutrients and enteric microorganisms to surface water and ground water. Polyacrylamide (PAM) mixtures are an effective flocculent, and we hypothesized that they would reduce transport of microorganisms in flowing water. After waste water running at 60.0 l min -1 flowed over PAM+Al 2 (SO 4 ) 3 , or PAM+CaO in furrows, total coliform bacteria (TC) and fecal coliform bacteria (FC) were reduced by 30-50% at 1 and 50 m downstream of the treatments compared to the control. In a column study, PAM+Al 2 (SO 4 ) 3 , and PAM+CaO applied to sandy, sandy loam, loam, and clay soils reduced NH 4 + and ortho-P concentrations in leachate compared to the source waste water and the control. PAM+Al 2 (SO 4 ) 3 and PAM+CaO applied to sandy, sandy loam and loam soils reduced both total and ortho-P, concentrations in leachate compared to the source wastewater and control treatment. In a field study, PAM+Al 2 (SO 4 ) 3 , or PAM+CaO treatments did not consistently reduce NH 4 + , NO 3 - , ortho-P, and total P concentrations in wastewater flowing over any soil compared to inflow wastewater or the control treatment. With proper application PAM+ Al 2 (SO 4 ) 3 and PAM+CaO may be able to reduce the numbers of enteric bacteria in slowly flowing wastewater running off animal confinement areas, reducing the amount of pollutants entering surface water and groundwater

Removal of oil and grease from automobile garage wastewater using electrocoagulation

Science.gov (United States)

Manilal, A. M.; Harinarayanan Nampoothiri, M. G.; Soloman, P. A.

2017-06-01

Wastewater from automobile garages and workshops is an important contributor to the water pollution. Oil and grease is one of the major content of wastewater from vehicle garages. Wastewater from a public transport depot at Thrissur district in Kerala, India was collected for the study. A batch reactor has been devised to assess the efficacy of electrocoagulation in removing oil and grease from the wastewater. Aluminium and iron were tested as the anode material with stainless steel as cathode. Experiments were conducted to investigate the effect of various operating parameters such as current density, pH, time and salt concentration on oil and grease removal. The results shown that aluminium is superior to iron in removing the oil and grease from the wastewater. The reactor with aluminium as anode was able to remove 90.8 % of the oil and grease at a current density of 0.6 A/dm2 in 15 minutes. The calculated specific energy consumption is also less for aluminium in comparison with iron.

Synthesis of adsorbent from Tamarix hispida and modified by lanthanum metal for fluoride ions removal from wastewater: Adsorbent characteristics and real wastewater treatment data

Directory of Open Access Journals (Sweden)

Nasim Habibi

2017-08-01

Full Text Available This data article describes a facile method for production of an adsorbent from Tamarix hispida wasted wood and modified by lanthanum metal for fluoride ions removal from wastewater. The main characteristics of the adsorbent consist of BET surface area, functional groups, and elemental analysis is presented. The data for attenuating the pollutants from a real wastewater treatment which was provided from a glass factory is also represented. More than 90% of fluoride content of the real wastewater was treated by the adsorbent. Generally, these data would be informative for extend research aim to industrial wastewater treatment and those who work in the wastewater treatment plants.

Use of ClO2 for removal of estrogenic substances in wastewater

DEFF Research Database (Denmark)

2010-01-01

The present invention pertains to wastewater treatment. More particularly, the invention concerns inactivation of biologically active compounds, such as estrogenic compounds, present in wastewater comprising sewage by the use of an oxidant, such as CIO2. A method is disclosed for inactivating one...... or more estrogenic substance(s) in wastewater, such as in a wastewater treatment plant, said method comprising a step of adding a dose of CIO2 to the water to be discharged, and said CIO2-dose being less than the CIO2- demand of the water to be discharged....

Anaerobic baffled reactor coupled with chemical precipitation for treatment and toxicity reduction of industrial wastewater.

Science.gov (United States)

Laohaprapanona, Sawanya; Marquesa, Marcia; Hogland, William

2014-01-01

This study describes the reduction of soluble chemical oxygen demand (CODs) and the removal of dissolved organic carbon (DOC), formaldehyde (FA) and nitrogen from highly polluted wastewater generated during cleaning procedures in wood floor manufacturing using a laboratory-scale biological anaerobic baffled reactor followed by chemical precipitation using MgCI2 .6H20 + Na2HPO4. By increasing the hydraulic retention time from 2.5 to 3.7 and 5 days, the reduction rates of FA, DOC and CODs of nearly 100%, 90% and 83%, respectively, were achieved. When the Mg:N:P molar ratio in the chemical treatment was changed from 1:1:1 to 1.3:1:1.3 at pH 8, the NH4+ removal rate increased from 80% to 98%. Biologically and chemically treated wastewater had no toxic effects on Vibrio fischeri and Artemia salina whereas chemically treated wastewater inhibited germination of Lactuca sativa owing to a high salt content. Regardless of the high conductivity of the treated wastewater, combined biological and chemical treatment was found to be effective for the removal of the organic load and nitrogen, and to be simple to operate and to maintain. A combined process such as that investigated could be useful for on-site treatment of low volumes of highly polluted wastewater generated by the wood floor and wood furniture industries, for which there is no suitable on-site treatment option available today.

Upgrading the Benchmark Simulation Model Framework with emerging challenges - A study of N₂O emissions and the fate of pharmaceuticals in urban wastewater systems

DEFF Research Database (Denmark)

Snip, Laura

Nowadays a wastewater treatment plant (WWTP) is not only expected to remove traditional pollutants from the wastewater; other emerging challenges have arisen as well. A WWTP is now, among other things, expected to also minimise its carbon footprint and deal with micropollutants. Optimising...

Industrial wastewater treatment with electron beam

Energy Technology Data Exchange (ETDEWEB)

Han, Bumsoo; Ko, Jaein; Kim, Jinkyu; Kim, Yuri; Chung, Wooho [Central Research Institute of Samsung Heavy Industries Co., Taejon (Korea)

2001-03-01

Global withdrawals of water to satisfy human demands have grown dramatically in this century. Between 1900 and 1945, water consumption increased by over six times, more than double the rate of population growth. This rapid growth in water demand is due to the increasing reliance on irrigation to achieve food security, the growth of industrial uses, and the increasing use per capita for domestic purposes. Given the seriousness of the situation and future risk of crises, there is an urgent need to develop the water-efficient technologies including economical treatment methods of wastewater and polluted water. In the Central Research Institute of Samsung Heavy Industries (SHI), many industrial wastewater including leachate from landfill area, wastewater from papermill, dyeing complex, petrochemical processes, etc. are under investigation with electron beam irradiation. For the study of treating dyeing wastewater combined with conventional facilities, an electron beam pilot plant for treating 1,000m{sup 3}/day of wastewater from 80,000m{sup 3}/day of total dyeing wastewater has constructed and operated in Taegu Dyeing Industrial Complex. A commercial plant for re-circulation of wastewater from Papermill Company is also designed for S-paper Co. in Cheongwon City, and after the successful installation, up to 80% of wastewater could be re-used in paper producing process. (author)

Industrial wastewater treatment with electron beam

International Nuclear Information System (INIS)

Han, Bumsoo; Ko, Jaein; Kim, Jinkyu; Kim, Yuri; Chung, Wooho

2001-01-01

Global withdrawals of water to satisfy human demands have grown dramatically in this century. Between 1900 and 1945, water consumption increased by over six times, more than double the rate of population growth. This rapid growth in water demand is due to the increasing reliance on irrigation to achieve food security, the growth of industrial uses, and the increasing use per capita for domestic purposes. Given the seriousness of the situation and future risk of crises, there is an urgent need to develop the water-efficient technologies including economical treatment methods of wastewater and polluted water. In the Central Research Institute of Samsung Heavy Industries (SHI), many industrial wastewater including leachate from landfill area, wastewater from papermill, dyeing complex, petrochemical processes, etc. are under investigation with electron beam irradiation. For the study of treating dyeing wastewater combined with conventional facilities, an electron beam pilot plant for treating 1,000m 3 /day of wastewater from 80,000m 3 /day of total dyeing wastewater has constructed and operated in Taegu Dyeing Industrial Complex. A commercial plant for re-circulation of wastewater from Papermill Company is also designed for S-paper Co. in Cheongwon City, and after the successful installation, up to 80% of wastewater could be re-used in paper producing process. (author)

[Characteristics and loads of key sources of pollutions discharged into Beishi River, Changzhou City].

Science.gov (United States)

Li, Chun-Ping; Jiang, Jian-Guo; Chen, Ai-Mei; Wu, Jia-Ling; Fan, Xiu-Juan; Ye, Bin

2010-11-01

Choosing the Beishi river, Changzhou City as the study area, the sewage generation, pollutants characteristics and sewage discharge in catchment area of Beishi river were conducted, detailed investigated and monitored. After using pollution coefficients, the yearly loads of all sources of pollutions were calculated to determine the highest sewage. The results showed that: except pH, the high concentration of SS, COD, BOD5, ammonia nitrogen, TN and TP discharged from MSW collecting houses, MSW transfer stations, public toilets and dining in Changzhou city far exceeded the "Integrated Wastewater Discharge Standard" (GB 8978-1996) and "Effluent Discharged into the City Sewer Water Quality Standards" (CJ 3082-1999). Among which: the highest concentration of COD discharged from MSW transfer stations was up to 51 700 mg/L, while the ammonia nitrogen and TN were as high as 1 616 mg/L and 2 044 mg/L in the toilet wastewater. In addition to this, the ratio of wastewater discharged directly into the river through storm water pipe network was higher from MSW houses, MSW transfer stations, public toilets, dining and other waste in Changzhou city. The 125.2 t/a of COD and 40.53 t/a of BOD5 were the two highest concentrations of various sources of pollution. The highest annual polluting loads discharged into Beishi river is dining, followed by the sanitation facilities. Therefore, cutting pollution control of food and sanitation facilities along the river is particularly urgent.

Transcriptomic effects-based monitoring for endocrine active chemicals: Assessing relative contribution of treated wastewater to downstream pollution

Science.gov (United States)

Martinovic-Weigelt, Dalma; Mehinto, Alvine C.; Ankley, Gerald T.; Denslow, Nancy D.; Barber, Larry B.; Lee, Kathy E.; King, Ryan J.; Schoenfuss, Heiko L.; Schroeder, Anthony L.; Villeneuve, Daniel L.

2014-01-01

The present study investigated whether a combination of targeted analytical chemistry information with unsupervised, data-rich biological methodology (i.e., transcriptomics) could be utilized to evaluate relative contributions of wastewater treatment plant (WWTP) effluents to biological effects. The effects of WWTP effluents on fish exposed to ambient, receiving waters were studied at three locations with distinct WWTP and watershed characteristics. At each location, 4 d exposures of male fathead minnows to the WWTP effluent and upstream and downstream ambient waters were conducted. Transcriptomic analyses were performed on livers using 15 000 feature microarrays, followed by a canonical pathway and gene set enrichment analyses. Enrichment of gene sets indicative of teleost brain–pituitary–gonadal–hepatic (BPGH) axis function indicated that WWTPs serve as an important source of endocrine active chemicals (EACs) that affect the BPGH axis (e.g., cholesterol and steroid metabolism were altered). The results indicated that transcriptomics may even pinpoint pertinent adverse outcomes (i.e., liver vacuolization) and groups of chemicals that preselected chemical analytes may miss. Transcriptomic Effects-Based monitoring was capable of distinguishing sites, and it reflected chemical pollution gradients, thus holding promise for assessment of relative contributions of point sources to pollution and the efficacy of pollution remediation.

Behavior of the new composites obtained from fly ash and titanium dioxide in removing of the pollutants from wastewater

Energy Technology Data Exchange (ETDEWEB)

Visa, Maria; Andronic, Luminita; Enesca, Alexandru

2016-12-01

Graphical abstract: - Highlights: • A novel substrates FLY1, 2, 3 and FLY2NPt is obtained by hydrothermal synthesis. • The composite type structure has specific surface ten times higher than fly ash. • Simultaneous removal of three pollutants reaches efficiencies above 80%. • Kinetic investigations show fast adsorption of the dye on the new composite. - Abstract: The goal of this paper was to develop a low-temperature TiO{sub 2}-fly ash (TiO{sub 2}-FA) composite based on interaction in alkaline solution using hydrothermal methods, to obtain crystalline nanocomposite at low temperature. These composites are interesting to be applied in visible photocatalysis/adsorption simultaneous advanced wastewater processes. Combining fly ash with titanium dioxide has the following advantages: (1) the titanium oxide crystallites grow on the support (active fly ash); (2) pollutant molecules migrate to the surface of TiO{sub 2} can be degraded by photocatalysis; and (3) activated fly ash substrates are regenerated in situ. The composites were characterized by the scanning electron microscopy (SEM) and atomic force microscopy (AFM) for morphological characterization of the surface, X-ray diffraction (XRD) for phase and crystallinity analysis, UV–vis spectroscopy to calculate the energy band gap, surface analysis by determining the contact angle, porosity analysis (BET). The photocatalytic property of the composites was evaluated by dye (methylene blue), surfactant (dodecylbenzenesulfonate–SDBS) degradation under UV and Visible irradiation. The adsorption tests were made on heavy metal (Cu{sup 2+}) cation. Properties of composites were correlated with the adsorption/photocatalytic activity of the samples.

Wastewater treatment technologies to satisfy 1990's energy conservation/pollution prevention goals

International Nuclear Information System (INIS)

Keith, L.W.; Beers, A.R.

1993-01-01

Anheuser-Busch, like most other companies, relied through the mid-1970's on end-of-pipe, energy-intensive aerobic treatment systems for its wastewater. Little if any attention was placed on source reduction. There are several factors that help explain why industry had adopted this approach. Energy was relatively cheap, sludge disposal was not a major problem and many municipalities provided wastewater treatment capacity to industry as an inducement for industry to locate there. The saying for A-B was open-quotes We know how to make beer - municipalities know how to treat our wastewater - let's not mix the two.close quotes The 1973 oil embargo and the resulting mid-1970's energy crisis changed Anheuser-Busch's wastewater treatment philosophy. The days of cheap energy and wastewater treatment were gone. This was only exaggerated by the more stringent treatment requirements resulting from the passage of PL92-500 (Clean Water Act). Increasing sludge disposal problems with associated increased disposal costs also occurred. From the mid-1970's to the mid-1980's Anheuser-Busch performed significant developmental work on land application of wastewater. This technology, which requires only about 10% of the energy of aerobic activated sludge treatment systems and produces no sludge for disposal, was installed at six Anheuser-Busch locations. During this time period considerable improvement was made in the area of waste load reduction. However, the main driving force was economics; that is, it was done if cheaper than wastewater treatment. Anheuser-Busch still had a basic end-of-pipe treatment philosophy

Characterization of sludges of La Golondrina WWTP: sludges as final containers of the domestic wastewater pollution; Caracterizacion de fangos de la EDAR La Golondrina (EMACSA-Cordoba): su funcion como receptores finales de la contaminacion del agua residual urbana

Energy Technology Data Exchange (ETDEWEB)

Marin Galvin, R.; Alonso Perez de siles, L.; Rojas Moreno, F. J.

2005-07-01

Treatment of wastewater is to concentrate the original pollution in a by-product: the wastewater sludge or bio-solid. As example, La Golondrina WWTP (Cordoba-spain) promotes the production of 1,3 kg of sludge per m''3 of wastewater, yielding logically a treated water according to laws. Furthermore, the treatment process there applied reduces the levels of nine majority metals (Cu, Fe, Mn, Pb, Cd, Ni, Cr, Zn, Hg) from 2,72 mg/l to 1.42 mg/l in the treated water, generating almost, a sludge agrees with the spanish normative to sludge intended to agricultural use (its main fate). Summarizing, the treatment of wastewater supposes the concentration of the original biodegradable load into the sludge around 340 times, while metals exhibited a different concentration degree for each one (from 10.000 times for Fe, u pto 1-2 times for Cd and Hg). Finally, the concentration degree of a metal in the sludge is mainly led by the removed concentration of metal in the treatment process, and after, by the original concentration of metal in the influent wastewater. (Author) 24 refs.

Degradation and biodegradability improvement of the olive mill wastewater by peroxi-electrocoagulation/electrooxidation-electroflotation process with bipolar aluminum electrodes.

Science.gov (United States)

Esfandyari, Yahya; Mahdavi, Yousef; Seyedsalehi, Mahdi; Hoseini, Mohammad; Safari, Gholam Hossein; Ghozikali, Mohammad Ghanbari; Kamani, Hossein; Jaafari, Jalil

2015-04-01

Olive mill wastewater is considered as one of the most polluting effluents of the food industry and constitutes a source of important environmental problems. In this study, the removal of pollutants (chemical oxygen demand (COD), biochemical oxygen demand (BOD5), polyphenols, turbidity, color, total suspended solids (TSS), and oil and grease) from olive oil mill processing wastewater by peroxi-electrocoagulation/electrooxidation-electroflotation process with bipolar aluminum electrodes was evaluated using a pilot continuous reactor. In the electrochemical unit, aluminum (Al), stainless steel, and RuO2/Ti plates were used. The effects of pH, hydrogen peroxide doses, current density, NaCl concentrations, and reaction times were studied. Under optimal conditions of pH 4, current density of 40 mA/m(2), 1000 mg/L H2O2, 1 g/L NaCl, and 30-min reaction time, the peroxi-electrochemical method yielded very effective removal of organic pollution from the olive mill wastewater diluted four times. The treatment process reduced COD by 96%, BOD5 by 93.6%, total, polyphenols by 94.4%, color by 91.4%, turbidity by 88.7, suspended solids by 97% and oil and grease by 97.1%. The biodegradability index (BOD5/COD) increased from 0.29 to 0.46. Therefore, the peroxi-electrocoagulation/electrooxidation-electroflotation process is considered as an effective and feasible process for pre-treating olive mill wastewater, making possible a post-treatment of the effluent in a biological system.

Reducing Marine and Coastal Pollution

OpenAIRE

World Bank Group

2016-01-01

The West African coastline is home to major industries, mining activities, peri-urban and agro-industry, and tourism, as well as urban and seaside residences, all of which generate waste and cause pollution. Many areas along the coast also lack adequate wastewater and solid waste management systems. As a result, large volumes of untreated wastewater and solid waste are dumped into the open...

Comparison of Some Rural Wastewater Refining Systems Considering Chemical Properties and Heavy Metals

Directory of Open Access Journals (Sweden)

Najme Yazdanpanah

2016-02-01

Full Text Available Introduction: Water scarcity is an important challenge worldwide, especially in arid and semi-arid regions. In these areas, the excessive exploitation of groundwater for irrigation, inefficient irrigation methods, irrigation with low-quality water and uncontrolled utilization of fertilizers in agricultural lands in addition to contamination of water resources by domestic and industrial wastewater in urban as well as rural regions, have led to water pollution problems. Furthermore, pollution and transportation of pollutants through wastewater have been considered as an environmental issue. Wastewater is a term that is used to describe waste materials that includes liquid waste and sewage waste. Wastewaters from single houses in the countryside that are not connected to sewers are generally treated on-site by septic tank systems or individual domestic wastewater treatment systems. Study on wastewater quality derived from refining systems in rural areas has been rarely taken into account. This study investigates the efficiency of some refining systems in the reduction of wastewater pollution indices and heavy metal concentrations. Materials and Methods: This study was done in four rural areas including Dehmilan, Hotkan, Sarbagh and Sekukan which are located around the city of Zarand in the Kerman province. Recently, some refining systems have been established in these areas in order to mitigate the environmental issues. An experiment was done to assess the efficiency of these refining systems and to determine the pollution indices for such small communities. Wastewater sampling was done in 10 replicates each at one week interval from four refineries. Different variables including BOD, COD, TOC, EC, TSS, TDS, DO, TKN, TP, pH, temperature, turbidity (Turb, alkanity (Alk and also the concentrations of Cd, Zn, Pb, Ni and Mo were measured using standard methods. To quantify the performance of each system, the amount of each variable at the outlet was

Agricultural use of treated municipal wastewaters preserving environmental sustainability

Directory of Open Access Journals (Sweden)

Antonio Lonigro

2007-07-01

Full Text Available In this paper the utility of the treated municipal wastewaters in agriculture, analyzing the chemical, physical and microbiological characteristics and their pollution indicators evaluation are being illustrated. Some methods employed for treating wastewaters are examined, as well as instructions and rules actually in force in different countries of the world, for evaluating the legislative hygienic and sanitary and agronomic problems connected with the treated wastewaters use, are being collected and compared. Successively, in order to provide useful indications for the use of treated municipal wastewaters, results of long-term field researches, carried out in Puglia, regarding two types of waters (treated municipal wastewater and conventional water and two irrigation methods (drip and capillary sub-irrigation on vegetable crops grown in succession, are being reported. For each crop cycle, chemical physical and microbiological analyses have been performed on irrigation water, soil and crop samples. The results evidenced that although irrigating with waters having high colimetric values, higher than those indicated by law and with two different irrigation methods, never soil and marketable yield pollutions have been observed. Moreover, the probability to take infection and/or disease for ingestion of fruits coming from crops irrigated with treated wastewaters, calculated by Beta-Poisson method, resulted negligible and equal to 1 person for 100 millions of exposed people. Concentrations of heavy metals in soil and crops were lesser than those admissible by law. The free chlorine, coming from disinfection, found in the wastewaters used for watering, in some cases caused toxicity effects, which determined significant yield decreases. Therefore, municipal wastewaters, if well treated, can be used for irrigation representing a valid alternative to the conventional ones.

Foraging at wastewater treatment works increases the potential for ...

African Journals Online (AJOL)

Wastewater treatment works (WWTWs) are known to provide profitable foraging areas for insectivorous bats in Europe and the New World because of their association with high abundance of pollution-tolerant midges (Diptera). However, bats that feed on these insects may also accumulate metal pollutants such as cadmium ...

Wastewater sludge treatment at selected wastewater treatment plants of the region Banska Bystrica

International Nuclear Information System (INIS)

Samesova, D.; Mitterpach, J.; Martinkova, A.

2014-01-01

The management of sewage sludges in water treatment plants of Banska Bystrica region. The paper deals with the problems of sewage sludge in wastewater treatment plants, its origin and possibilities how to use it in accordance with the current legislation of the Slovak Republic. We described radioactive pollution of sewage sludges. The paper consists of review of sludge production and its usage in the Slovak Republic and in selected states of the European Union. The paper deals with the sludge treatment in selected wastewater treatment plants in Banska Bystrica region in the context of biogas production and its usage by the help of the electricity and heat production. (authors)

Decentralized wastewater treatment using passively aerated biological filter.

Science.gov (United States)

Abou-Elela, Sohair I; Hellal, Mohamed S; Aly, Olfat H; Abo-Elenin, Salah A

2017-10-13

This study aimed to evaluate the efficiency of a novel pilot-scale passively aerated biological filter (PABF) as a low energy consumption system for the treatment of municipal wastewater. It consists of four similar compartments, each containing 40% of a non-woven polyester fabric as a bio-bed. The PABF was fed with primary treated wastewater under a hydraulic retention time (HRT) of 3.5 hr and a hydraulic loading rate of 5.5 m 2 /m 3 /d. The effect of media depth, HRT, dissolved oxygen (DO) and surface area of the media on the removal efficiency of pollutants was investigated. Results indicated that increasing media depth along the axis of the reactor and consequently increasing the HRT and DO resulted in great removal of different pollutants. A significant increase in the DO levels in the final effluent up to 6.7 mg/l resulted in good nitrification processes. Statistical analysis using SPSS showed that the reactor performance has significant removal efficiency (p filter systems.

Public health aspects of waste-water treatment

International Nuclear Information System (INIS)

Lund, E.

1975-01-01

Among the bacteria, viruses and parasites which may be found in waste-water and polluted waters, those that are pathogenic to man are briefly described. The efficiency of different conventional waste-water treatments in removing the pathogens is reviewed, as well as additional factors of importance for the presence of micro-organisms in recipient waters. It is concluded that at present for treated waters no conventional treatment results in an effluent free from pathogens if they are present in the original waste-water. This is also true for sludges apart from pasteurization. The importance to public health of the presence of pathogens in recipient waters is briefly discussed. (author)

Modification of Wastewater Treatment Technology at Cottonseed Oil Plant

Directory of Open Access Journals (Sweden)

Alshabab Mary Shick

2016-01-01

Full Text Available Wastewaters from cottonseed oil producing plant in Syria were studied in laboratory experiments. Aim of the study was to suggest modification of wastewater treatment technology in order to increase its efficiency. Concentration of pollutants in wastewaters was controlled by measurement of COD. According to the results of experiments it was suggested to decrease significantly (8-20 times dosages of reagents (acidifier, coagulant, flocculant in several actual stages of treatment (acidification, separation, coagulation and sedimentation and add stage of dispersed air flotation before coagulation treatment. The modified wastewater treatment technology would reduce COD to the values allowed for irrigation waters by Syrian National Standard.

Polar pollutants in municipal wastewater and the water cycle: occurrence and removal of benzotriazoles.

Science.gov (United States)

Reemtsma, Thorsten; Miehe, Ulf; Duennbier, Uwe; Jekel, Martin

2010-01-01

1H-benzo-1,2,3-triazole (BTri) and its methylated analogues (tolyltriazole, TTri) are corrosion inhibitors used in many industrial applications, but also in households in dishwashing agents and in deicing fluids at airports and elsewhere. BTri and one of the TTri-isomers (4-TTri) are typical examples of polar and poorly degradable trace pollutants. Benzotriazole elimination in four wastewater treatment plants (WWTP) in Berlin ranged from 20 to 70% for 5-TTRi over 30 to 55% for BTri to insignificant for 4-TTri. WWTP effluent concentrations were in the range of 7-18 microg/L of BTri, 1-5 microg/L of 4-TTri and 0.8-1.2 microg/L of 5-TTri. BTri and 4-TTri proved to be omnipresent in surface waters of the rivers Rhine and Elbe with concentrations increasing from water for drinking water production from surface waters. Even after residence times of several months BTri and 4-TTri were determined in concentrations of a few hundred ng/L in bank filtration water. Isotherm data from batch experiments indicate that activated carbon filtration should be suitable to avoid intrusion of TTri into drinking water in partially closed water cycles. For BTri, however, sorption to activated carbon appears to be too weak and ozonation may be mandatory to remove it from raw waters. (c) 2009 Elsevier Ltd. All rights reserved.

Characterization of wastewaters from vehicle washing companies and environmental impacts

Directory of Open Access Journals (Sweden)

Valderi Duarte Leite

2011-12-01

Full Text Available The car wash business has developed rapidly in recent years due to the increased number of cars, thus, it can cause serious environmental problems considering its potential source of pollution. The aim of this study was to characterize the wastewater from car washing companies in the city of Campina Grande, in Paraiba state, and to analyze the environmental impacts generated. A survey was conducted from November 2009 to July 2010. The first step we present a survey of car wash businesses in the city, and identified 20 licensed companies in which we evaluated the number of vehicles washed per week, the existence of a system of pre-treatment of wastewater generated and infrastructure that would allow the realization of the collection of samples of the effluent, the second step was carried out chemical and physical characterization of wastewater from five 20 companies surveyed in the previous step, and third stage were measured pollution loads of wastewater from washing of vehicles in the city, from the results obtained in previous steps. The characterization parameters were analyzed: oil and grease, COD, heavy metals, TS, TSS, turbidity, TKN, total P, pH and color. The results demonstrated that the wastewater from the car wash establishments shows high concentrations of organic matter, oils and grease, heavy metals and solids, and as such did not conform with the specific environmental legislation. Evaluation of pollutant loads demonstrated that if releases without proper treatment, it can cause serious environmental problems. It is therefore essential that these establishments are properly monitored.

Application of a Novel Semiconductor Catalyst, CT, in Degradation of Aromatic Pollutants in Wastewater: Phenol and Catechol

Directory of Open Access Journals (Sweden)

Xiao Chen

2014-01-01

Full Text Available Water-soluble phenol and phenolic compounds were generally removed via advanced oxidation processes. A novel semiconductor catalyst, CT, was the first-time employed in the present study to degrade phenol and catechol. The phenolic compounds (initial concentration of 88 mg L−1 were completely mineralized by the CT catalytic nanoparticles (1% within 15 days, under acidic condition and with the presence of mild UV radiation (15 w, the emitted wavelength is 254 nm and the light intensity <26 μw/cm2. Under the same reaction condition, 1% TiO2 (mixture of rutile and anatase, nanopowder, <100 nm and H2O2 had lower removal efficiency (phenol: <42%; catechol: <60%, whereas the control (without addition of catalysts/H2O2 only showed <12% removal. The processes of phenol/catechol removal by CT followed pseudo-zero-order kinetics. The aromatic structures absorbed the UV energy and passed to an excited state, which the CT worked on. The pollutants were adsorbed on the CT’s surface and oxidized via charge-transfer and hydroxyl radical generation by CT. Given low initial concentrations, a circumstance encountered in wastewater polishing, the current set-up should be an efficient and less energy- and chemical-consumptive treatment method.

Brewer, Maine Wastewater Treatment Plant Recognized for Excellence

Science.gov (United States)

The Brewer Water Pollution Control Facility was recently honored with a 2015 Regional Wastewater Treatment Plant Excellence Award by the US Environmental Protection Agency's New England regional office.

Reuse the pulp and paper industry wastewater by using fashionable technology

Science.gov (United States)

Sudarshan, K.; Maruthaiya, K.; Kotteeswaran, P.; Murugan, A.

2017-10-01

This proposed method is a promising way, which can be implemented in pulp and paper industries by effective removal of the color and chemical oxygen demand (COD) and the resulting treated water may surely reuse to the other streams. Fourier Transformer Infra Red spectra confirmed the presence of the respective functional groups in the removed pollutants from the wastewater. The efficiency of Non-ferric Alum (NF Alum) and cationic polyacrylamide (C-PAM) with and without power boiler fly ash was also studied. The reduction efficiency of color and chemical oxygen demand (COD) is evaluated at the optimum dosage of NF Alum, fly ash, and C-PAM. At the optimized pH attained from these coagulants using to treat the wastewater, the flocs formation/settling and the pollutant removal efficiency are encouraging and the resulting color of the wastewater is to 40 PtCo units from 330 PtCo units and COD to 66 mg/L from 218 mg/L. While using NF Alum alone with C-PAM for the treatment of wastewater, the highest reduction efficiency of COD is 97 mg/L from 218 mg/L and the color is 60 from 330 PtCo units at pH 4.8 was noted. From these observations, NF Alum and power boiler fly ash with C-PAM can effectively remove the pollutants from the pulp and paper mill wastewater and the water can be reused for other streams.

Microbial Fuel Cells using Mixed Cultures of Wastewater for Electricity Generation

International Nuclear Information System (INIS)

Zain, S.M; Roslani, N.S.; Hashim, R.; Anuar, N.; Suja, F.; Basi, N.E.A.; Anuar, N.; Daud, W.R.W.

2011-01-01

Fossil fuels (petroleum, natural gas and coal) are the main resources for generating electricity. However, they have been major contributors to environmental problems. One potential alternative to explore is the use of microbial fuel cells (MFCs), which generate electricity using microorganisms. MFCs uses catalytic reactions activated by microorganisms to convert energy preserved in the chemical bonds between organic molecules into electrical energy. MFC has the ability to generate electricity during the wastewater treatment process while simultaneously treating the pollutants. This study investigated the potential of using different types of mixed cultures (raw sewage, mixed liquor from the aeration tank and return waste activated sludge) from an activated sludge treatment plant in MFCs for electricity generation and pollutant removals (COD and total kjeldahl nitrogen, TKN). The MFC in this study was designed as a dual-chambered system, in which the chambers were separated by a Nafion TM membrane using a mixed culture of wastewater as a bio catalyst. The maximum power density generated using activated sludge was 9.053 mW/ cm 2 , with 26.8 % COD removal and 40 % TKN removal. It is demonstrated that MFC offers great potential to optimize power generation using mixed cultures of wastewater. (author)

Assessment of the interactions between economic growth and industrial wastewater discharges using co-integration analysis: a case study for China's Hunan Province.

Science.gov (United States)

Xiao, Qiang; Gao, Yang; Hu, Dan; Tan, Hong; Wang, Tianxiang

2011-07-01

We have investigated the interactions between economic growth and industrial wastewater discharge from 1978 to 2007 in China's Hunan Province using co-integration theory and an error-correction model. Two main economic growth indicators and four representative industrial wastewater pollutants were selected to demonstrate the interaction mechanism. We found a long-term equilibrium relationship between economic growth and the discharge of industrial pollutants in wastewater between 1978 and 2007 in Hunan Province. The error-correction mechanism prevented the variable expansion for long-term relationship at quantity and scale, and the size of the error-correction parameters reflected short-term adjustments that deviate from the long-term equilibrium. When economic growth changes within a short term, the discharge of pollutants will constrain growth because the values of the parameters in the short-term equation are smaller than those in the long-term co-integrated regression equation, indicating that a remarkable long-term influence of economic growth on the discharge of industrial wastewater pollutants and that increasing pollutant discharge constrained economic growth. Economic growth is the main driving factor that affects the discharge of industrial wastewater pollutants in Hunan Province. On the other hand, the discharge constrains economic growth by producing external pressure on growth, although this feedback mechanism has a lag effect. Economic growth plays an important role in explaining the predicted decomposition of the variance in the discharge of industrial wastewater pollutants, but this discharge contributes less to predictions of the variations in economic growth.

Sources of pollution

Indian Academy of Sciences (India)

First page Back Continue Last page Overview Graphics. Sources of pollution. Domestic wastewater (Sewage). Organic matter; Nitrogen & phosphorus; Pathogens, viruses, …. Agricultural runoff. Nitrogen & phosphorus; Pesticides; Industrial effluents; Organics (oil &grease, pigments, phenols, organic matter ….) Heavy ...

REUSE IN EXHAUST DYEING PROCESSES OF TEXTILE WASTEWATERS

OpenAIRE

P. Monllor; J.F. Sanz; R. Vicente; M. Bonet

2013-01-01

Textile dyeing and wet finishing wastewaters are considered a major concern because of the necessity of removing colour and pollutants before their discharge into the environment. Their chemical composition is diverse depending mainly on fashion, material and process. After the homogenization of all the wastewaters coming from the different textile processes, the generally used multi-stage technology for their treatment and purification combines physico-chemical and biological processes. Howe...

Plastic pollutants in water environment

Directory of Open Access Journals (Sweden)

Mrowiec Bożena

2017-12-01

Full Text Available Nowadays, wide applications of plastics result in plastic waste being present in the water environment in a wide variety of sizes. Plastic wastes are in water mainly as microplastics (the size range of 1 nm to < 5 mm. Microplastics have been recognized as an emerging threat, as well as ecotoxicological and ecological risk for water ecosystems. In this review are presented some of the physicochemical properties of plastic materials that determine their toxic effect on the aquatic environment. Wastewater treatment plants (WWTPs are mentioned as one of main sources of microplastics introduced into fresh water, and rivers are the pathways for the transportation of the pollutants to seas and oceans. But, effluents from tertiary wastewater treatment facilities can contain only minimally microplastic loads. The issue of discharge reduction of plastic pollutants into water environment needs activities in the scope of efficient wastewater treatment, waste disposal, recycling of plastic materials, education and public involvement.

Anthropogenic impacts on global organic river pollution

NARCIS (Netherlands)

Wen, Y.

2017-01-01

Organic pollution of rivers by wastewater discharge from human activities negatively impacts people and ecosystems. Without treatment, pollution control relies on a combination of natural degradation and dilution by natural runoff to reduce downstream effects. To implement integrated water

Slaughterhouse wastewater treatment by combined chemical coagulation and electrocoagulation process.

Science.gov (United States)

Bazrafshan, Edris; Kord Mostafapour, Ferdos; Farzadkia, Mehdi; Ownagh, Kamal Aldin; Mahvi, Amir Hossein

2012-01-01

Slaughterhouse wastewater contains various and high amounts of organic matter (e.g., proteins, blood, fat and lard). In order to produce an effluent suitable for stream discharge, chemical coagulation and electrocoagulation techniques have been particularly explored at the laboratory pilot scale for organic compounds removal from slaughterhouse effluent. The purpose of this work was to investigate the feasibility of treating cattle-slaughterhouse wastewater by combined chemical coagulation and electrocoagulation process to achieve the required standards. The influence of the operating variables such as coagulant dose, electrical potential and reaction time on the removal efficiencies of major pollutants was determined. The rate of removal of pollutants linearly increased with increasing doses of PACl and applied voltage. COD and BOD(5) removal of more than 99% was obtained by adding 100 mg/L PACl and applied voltage 40 V. The experiments demonstrated the effectiveness of chemical and electrochemical techniques for the treatment of slaughterhouse wastewaters. Consequently, combined processes are inferred to be superior to electrocoagulation alone for the removal of both organic and inorganic compounds from cattle-slaughterhouse wastewater.

Slaughterhouse Wastewater Treatment by Combined Chemical Coagulation and Electrocoagulation Process

Science.gov (United States)

Bazrafshan, Edris; Kord Mostafapour, Ferdos; Farzadkia, Mehdi; Ownagh, Kamal Aldin; Mahvi, Amir Hossein

2012-01-01

Slaughterhouse wastewater contains various and high amounts of organic matter (e.g., proteins, blood, fat and lard). In order to produce an effluent suitable for stream discharge, chemical coagulation and electrocoagulation techniques have been particularly explored at the laboratory pilot scale for organic compounds removal from slaughterhouse effluent. The purpose of this work was to investigate the feasibility of treating cattle-slaughterhouse wastewater by combined chemical coagulation and electrocoagulation process to achieve the required standards. The influence of the operating variables such as coagulant dose, electrical potential and reaction time on the removal efficiencies of major pollutants was determined. The rate of removal of pollutants linearly increased with increasing doses of PACl and applied voltage. COD and BOD5 removal of more than 99% was obtained by adding 100 mg/L PACl and applied voltage 40 V. The experiments demonstrated the effectiveness of chemical and electrochemical techniques for the treatment of slaughterhouse wastewaters. Consequently, combined processes are inferred to be superior to electrocoagulation alone for the removal of both organic and inorganic compounds from cattle-slaughterhouse wastewater. PMID:22768233

Treatment of Wastewater by Ozone Produced in Dielectric Barrier Discharge

Directory of Open Access Journals (Sweden)

Rita Bhatta

2015-01-01

Full Text Available There is rapid diminishing of water resources in many countries due to, for example, population growth and constant reduction in fresh water supply. The sewage wastewater, industrial effluents, and municipal wastewater are directly and indiscriminately discharged into rivers and lakes and thus primarily cause water pollution in Nepal. This has increased the water crisis and also causes environmental deterioration. Therefore, the need for the development of an effective, cheap, and environmentally friendly process for the treatment of wastewater before discharging into aquatic environment has emerged. Treatment by ozone produced from dielectric barrier discharge is one of the emerging technologies for such application. The ozonation process is more effective for disinfection and degradation of organic pollutants from water. The current study describes the treatment of wastewater of selected site within Kathmandu. Results on various physicochemical and microbial parameters of the inlet and outlet samples are discussed. Our results showed slight increase in pH, decrease in chemical oxygen demand, and significant increase in dissolved oxygen after ozonation. Importantly, ozonation caused total reduction of fecal coliform.

Electrochemical peroxidation as a tool to remove arsenic and copper from smelter wastewater

DEFF Research Database (Denmark)

Gutiérrez, Claudia; Hansen, Henrik K.; Nuñez, Patricio

2010-01-01

Electrochemical peroxidation (ECP) is a method that recently has been applied in the treatment of heavy metal polluted wastewater. This method is based on the anodic dissolution of iron to ferrous ions that reacts with H2O2 to produce tiny particles of ferric oxides. These oxides adsorb metals ef...

Reducing the pollutant load of olive mill wastewater by photocatalytic membranes and monitoring the process using both tyrosinase biosensor and COD test

Science.gov (United States)

Martini, Elisabetta; Tomassetti, Mauro; Campanella, Luigi; Fortuna, Antonio

2013-12-01

Photocatalytic technique had already been employed in the treatment of olive mill wastewater (OMW) using the photocatalysis in suspension. The coupling of photocatalytic and membrane techniques should result in a very powerful process bringing great innovation to OMW depollution. Despite the potential advantages using these hybrid photoreactors, research on the combined use of photocatalysis and membranes has so far not been sufficiently developed. The present paper describes a study to assess the photocatalytic efficacy of a new ceramic membrane containing titanium dioxide, irradiated by UV light, used to abate the pollutant load of olive mill wastewater. Good results were obtained (more than 90% of the phenol content was removed and the COD decrease was of the order of 46-51 % in 24 h) particularly using the ceramic membrane compared with those offered by analogous catalytic membranes made of metallic or polymeric materials.

Phytoremediation potential of water caltrop (Trapa natans L.) using municipal wastewater of the activated sludge process-based municipal wastewater treatment plant.

Science.gov (United States)

Kumar, Vinod; Chopra, A K

2018-01-01

Phytoremediation experiments were carried out to assess the phytoremediation potential of water caltrop (Trapa natans L.) using municipal wastewater collected from the activated sludge process- (ASP) based municipal wastewater treatment plant. The results revealed that T. natans significantly (P ≤ .05/P ≤ .01/P ≤ .001) reduced the contents of total dissolved solids (TDS), electrical conductivity (EC), biochemical oxygen demand (BOD 5 ), chemical oxygen demand, total Kjeldahl nitrogen, phosphate ([Formula: see text]), sodium (Na + ), potassium (K + ), calcium (Ca 2+ ), magnesium (Mg 2+ ), cadmium (Cd), chromium (Cr), copper (Cu), iron (Fe), manganese (Mn), lead (Pb), zinc (Zn), standard plate count, and most probable number of the municipal wastewater after phytoremediation experiments. The maximum removal of these parameters was obtained at 60 days of the phytoremediation experiments, but the removal rate of these parameters was gradually increased from 15 to 45 days and it was slightly decreased at 60 days. Most contents of Cd, Cu, Fe, Mn and Zn were translocated in the leaves of T. natans, whereas most contents of Cr and Pb were accumulated in the root of T. natans after phytoremediation experiments. The contents of different biochemical components were recorded in the order of total sugar > crude protein > total ash > crude fiber > total fat in T. natans after phytoremediation of municipal wastewater. Therefore, T. natans was found to be effective for the removal of different parameters of municipal wastewater and can be used effectively to reduce the pollution load of municipal wastewater drained from the ASP-based treatment plants.

The use of constructed wetlands for the treatment of industrial wastewater

Directory of Open Access Journals (Sweden)

Skrzypiecbcef Katarzyna

2017-09-01

Full Text Available Constructed wetlands are characterized by specific conditions enabling simultaneous various physical and biochemical processes. This is the result of specific environment for the growth of microorganisms and hydrophytes (aquatic and semiaquatic plants which are capable of living in aerobic, anaerobic and facultative anaerobic conditions. Their interaction contributes to the intensification of oxidation and reduction responsible for the removal and retention of pollutants. These processes are supported by sorption, sedimentation and assimilation. Thanks to these advantages, treatment wetland systems have been used in communal management for over 50 years. In recent years, thanks to its advantages, low operational costs and high removal efficiency, there is growing interest in the use of constructed wetlands for the treatment or pre-treatment of various types of industrial wastewater. The study analyzes current use of these facilities for the treatment of industrial wastewater in the world. The conditions of use and efficiency of pollutants removal from readily and slowly biodegradable wastewater, with special emphasis on specific and characteristic pollutants of particular industries were presented. The use of subsurface horizontal flow beds for the treatment of industrial wastewater, among others from crude oil processing, paper production, food industry including wineries and distillery, olive oil production and coffee processing was described. In Poland constructed wetlands are used for the treatment of sewage and sludge from milk processing in pilot scale or for dewatering of sewage sludge produced in municipal wastewater treatment plant treating domestic sewage with approximately 40% share of wastewater from dairy and fish industry. In all cases, constructed wetlands provided an appropriate level of treatment and in addition the so-called ecosystem service.

On the possibility of using biological toxicity tests to monitor the work of wastewater treatment plants

Directory of Open Access Journals (Sweden)

Zorić Jelena

2008-01-01

Full Text Available The aim of this study was to ascertain the possibility of using biological toxicity tests to monitor influent and effluent wastewaters of wastewater treatment plants. The information obtained through these tests is used to prevent toxic pollutants from entering wastewater treatment plants and discharge of toxic pollutants into the recipient. Samples of wastewaters from the wastewater treatment plants of Kragujevac and Gornji Milanovac, as well as from the Lepenica and Despotovica Rivers immediately before and after the influx of wastewaters from the plants, were collected between October 2004 and June 2005. Used as the test organism in these tests was the zebrafish Brachydanio rerio Hamilton - Buchanon (Cyprinidae. The acute toxicity test of 96/h duration showed that the tested samples had a slight acutely toxic effect on B. rerio, except for the sample of influent wastewater into the Cvetojevac wastewater treatment plant, which had moderately acute toxicity, indicating that such water should be prevented from entering the system in order to eliminate its detrimental effect on the purification process.

Green Systems for Wastewater Treatment

Science.gov (United States)

Environmental Science and Technology, 1975

1975-01-01

Plants found in marshlands and wetlands in many parts of the world may play an increasing part in a very new, yet very old approach to treatment of water and wastewater--the application of biological methods. Biological water pollution control methods being utilized around the world are examined. (BT)

Tracing wastewater effluents in surface and groundwaters: a couple approach with organic/inorganic tracers and isotopes

Science.gov (United States)

Petelet-Giraud, Emmanuelle; Baran, Nicole; Soulier, Coralie

2017-04-01

In the context of land use change, the origins of contamination of water resources are often multiple, including for a single chemical element or molecule. For instance, excess of nitrates in both surface and groundwater can originate from agricultural practices and wastewater effluents. The discrimination of the origins and vectors of contamination in the environment is both an environmental and societal issue in order to define an integrated water resources management at the catchment or water body scale by implementing appropriate measures to effectively struggle against pollution. The objective of this study is to define a methodology for the identification of a "domestic wastewater" contamination within surface waters and groundwater. An ideal tracer should be conservative, persistent in the different water compartments, present in quantity above the detection limit and originate from a single type of pollution source. There is, however, no ideal tracer in the strict sense. Indeed, even chloride which is present in quantity in wastewater, and which behaves conservatively in the environment, is not an univocal tracer of wastewater, as it may come from atmospheric inputs, from the dissolution of evaporitic rocks, from the salting of roads or from fertilizers. To overcome this limitation, in this study, we propose a multi-tracer approach (chemical and isotopic) to identify and validate the relevance of foreseen tracers. Among the relevant tracers of wastewater, the following may be used for their intrinsic or combined discriminant power: 1) organic effluent tracers: nitrogen contents and isotopic ratios of nitrogen and oxygen of nitrates; 2) tracer of detergents: boron contents and boron isotopes; 3) pharmaceuticals tracers: e.g. carbamazepine, ibuprofen, paracetamol, gadolinium anomaly; 4) life-style tracers: e.g. caffeine. The originality of the study relies on small capacities wastewater treatment plants without tertiary treatment process. Results on a

River pollution caused by natural stone industry

Science.gov (United States)

Oktriani, Ani; Darmajanti, Linda; Soesilo, Tri Edhi Budhi

2017-03-01

The natural stone industry is classified as small industry. Current wastewater treatment still causes pollution in the river. This thesis aims to analyze the performance of wastewater treatment in natural stones industry. The data was collected from water quality test (parameters: temperature, pH, DO, and TSS). The wastewater treatment performance was in a slightly higher position compared to the 2nd class quality standards of Government Regulation No. 82/2001. The parameter that exceeded quality standards was the concentration of TSS, which was up to 240.8 mg/l. The high concentration of TSS was affected by the absence of sludge management schedule, which resulted in non-optimal precipitation. Besides that, the design of sedimentation basin was still not adapted with wastewater debit. Referring to the results, this study suggests the government of Cirebon District to provide wastewater treatment development through the village staff. Furthermore, the government also needs to give strict punishment to business owner who does not treat waste correctly and does not have a business license. Moreover, the sale value of sludge as byproduct of wastewater treatment needs to be increased.

Integrated Watershed Pollution Control at Wujingang Canal, China

Science.gov (United States)

Zheng, Z.; Yang, X.; Luo, X.

2012-04-01

With a drainage area of 400 square kilometers, Wujingang Canal is located at the economically developed Yangtz Delta of eastern China. As a major tributary, the canal contributes a significant amount of pollutant load to the Lake Tai. Over the past many years, water quality of the canal and its tributaries could not meet the lowest Category V of Chinese surface water quality standard, indicating that its water is not suitable for the purposes of irrigation or scenic views. Major pollution sources in the watershed include industries, residential households, agriculture, fishery, and animal feedlot operations. A comprehensive plan with a budget of 2 billion RMB for the Wujingang watershed pollution control was developed in 2008 and has been implemented progressively ever since. Major components of the plan include: (1) advanced treatment of wastewater from industries and municipal sewage plants for further removal of nitrogen and phosphorous; (2) industrial wastewater reuse; (3) contiguous treatment of sewage from rural residential households with cost-effective technologies such as tower ecofilter system; (4) recycling of rural wastes to generate high-value added products using technologies such as multi-phase anaerobic co-digestion; and (5) making full use of the local landscape and configuring physical, chemical, and biological pollutant treatment structures to build the "clean river network" for treatment of mildly polluted agricultural discharge and surface runoff. Through the implementation of the above measures, water quality of the Wujingang Canal and its tributaries is expected to improve to meet Category IV of Chinese surface water quality standard by 2012, and Category III standard by 2020. Keywords watershed pollution control, non-point source pollution, rural sewage, rural waste, Lake Tai

Treatment of hospital laundry wastewater by UV/H2O2 process.

Science.gov (United States)

Zotesso, Jaqueline Pirão; Cossich, Eneida Sala; Janeiro, Vanderly; Tavares, Célia Regina Granhen

2017-03-01

Hospitals consume a large volume of water to carry out their activities and, hence, generate a large volume of effluent that is commonly discharged into the local sewage system without any treatment. Among the various sectors of healthcare facilities, the laundry is responsible for the majority of water consumption and generates a highly complex effluent. Although several advanced oxidation processes (AOPs) are currently under investigation on the degradation of a variety of contaminants, few of them are based on real wastewater samples. In this paper, the UV/H 2 O 2 AOP was evaluated on the treatment of a hospital laundry wastewater, after the application of a physicochemical pretreatment composed of coagulation-flocculation and anthracite filtration. For the UV/H 2 O 2 process, a photoreactor equipped with a low-pressure UV-C lamp was used and the effects of initial pH and [H 2 O 2 ]/chemical oxygen demand (COD) ratio on COD removal were investigated through a randomized factorial block design that considered the batches of effluent as blocks. The results indicated that the initial pH had no significant effect on the COD removal, and the process was favored by the increase in [H 2 O 2 ]/COD ratio. Color and turbidity were satisfactorily reduced after the application of the physicochemical pretreatment, and COD was completely removed by the UV/H 2 O 2 process under suitable conditions. The results of this study show that the UV/H 2 O 2 AOP is a promising candidate for hospital laundry wastewater treatment and should be explored to enable wastewater reuse in the washing process.

Synergistic effects of irradiation of waste-water

International Nuclear Information System (INIS)

Woodbridge, D.D.

1975-01-01

Water is an absolute necessity for all forms of animal and plant life. As man's requirements for water increase, the need for better methods of purification also increase. Technology has been slow to develop new methods of water treatment for the direct utilization of waste-water. Many new construction projects are at a standstill because waste-water treatment methods have not been developed to handle adequately the ever-increasing flow of sewage. Theoretical considerations of the use of high-level radiation in the treatment of waste-water have failed to consider the effects of the hydrated electron, and the potential of the possible synergistic effects of combining chlorine, oxygen and irradiation. An extensive testing programme at the University Center for Pollution Research of the Florida Institute of Technology over the past four years has shown that irradiation of waste-water samples immersed in an aqueous environment provide bacterial kill and reduction in organic pollution far greater than that obtained from theoretical considerations of G values and earlier experiments where the waste samples were not immersed in an aqueous environment. These testing programmes have investigated the synergistic effects of combining oxygen and irradiation. Each of these combined treatments resulted in an increased bacterial kill factor. Tests on Staphylococcus aureus bacteria and faecal streptococcus bacteria indicate that the synergistic effects observed for faecal coliform bacteria also apply to the pathogenic bacteria. A statistical analysis of the data obtained shows the relationships between the various effects on the bacteria. A definite shielding factor from the turbidity of the waste-water has been shown to exist. Synergistic effects have been shown to offset significantly the shielding effects. Optimization of these synergistic effects can greatly increase the effectiveness of irradiation in the treatment of waste-water. (author)

Advanced oxidation process-biological system for wastewater containing a recalcitrant pollutant.

Science.gov (United States)

Oller, I; Malato, S; Sánchez-Pérez, J A; Maldonado, M I; Gernjak, W; Pérez-Estrada, L A

2007-01-01

Two advanced oxidation processes (AOPs), ozonation and photo-Fenton, combined with a pilot aerobic biological reactor at field scale were employed for the treatment of industrial non-biodegradable saline wastewater (TOC around 200 mgL(-1)) containing a biorecalcitrant compound, alpha-methylphenylglycine (MPG), at a concentration of 500 mgL(-1). Ozonation experiments were performed in a 50-L reactor with constant inlet ozone of 21.9 g m(-3). Solar photo-Fenton tests were carried out in a 75-L pilot plant made up of four compound parabolic collector (CPC) units. The catalyst concentration employed in this system was 20 mgL(-1) of Fe2+ and the H2O2 concentration was kept in the range of 200-500mgL(-1). Complete degradation of MPG was attained after 1,020 min of ozone treatment, while only 195 min were required for photo-Fenton. Samples from different stages of both AOPs were taken for Zahn-Wellens biocompatibility tests. Biodegradability enhancement of the industrial saline wastewater was confirmed (>70% biodegradability). Biodegradable compounds generated during the preliminary oxidative processes were biologically mineralised in a 170-L aerobic immobilised biomass reactor (IBR). The global efficiency of both AOP/biological combined systems was 90% removal of an initial TOC of over 500 mgL(-1).

Stripping of organic compounds from wastewater as an auxiliary fuel of regenerative thermal oxidizer

International Nuclear Information System (INIS)

Chang, Meng-Wen; Chern, Jia-Ming

2009-01-01

Organic solvents with different volatilities are widely used in various processes and generate air and water pollution problems. In the cleaning processes of electronics industries, most volatile organic compounds (VOCs) are vented to air pollution control devices while most non-volatile organic solvents dissolve in the cleaning water and become the major sources of COD in wastewater. Discharging a high-COD wastewater stream to wastewater treatment facility often disturbs the treatment performance. A pretreatment of the high-COD wastewater is therefore highly desirable. This study used a packed-bed stripping tower in combination with a regenerative thermal oxidizer to remove the COD in the wastewater from a printed circuit board manufacturing process and to utilize the stripped organic compounds as the auxiliary fuel of the RTO. The experimental results showed that up to 45% of the COD could be removed and 66% of the RTO fuel could be saved by the combined treatment system.

Contamination of nonylphenolic compounds in creek water, wastewater treatment plant effluents, and sediments from Lake Shihwa and vicinity, Korea: Comparison with fecal pollution

Science.gov (United States)

Choi, Minkyu; Furlong, Edward T.; Moon, Hyo-Bang; Yu, Jun; Choi, Hee-Gu

2011-01-01

Nonylphenolic compounds (NPs), coprostanol (COP), and cholestanol, major contaminants in industrial and domestic wastewaters, were analyzed in creek water, wastewater treatment plant (WWTP) effluent, and sediment samples from artificial Lake Shihwa and its vicinity, one of the most industrialized regions in Korea. We also determined mass discharge of NPs and COP, a fecal sterol, into the lake, to understand the linkage between discharge and sediment contamination. Total NP (the sum of nonylphenol, and nonylphenol mono- and di-ethoxylates) were 0.32–875 μg L-1 in creeks, 0.61–87.0 μg L-1 in WWTP effluents, and 29.3–230 μg g-1 TOC in sediments. Concentrations of COP were 0.09–19.0 μg L-1 in creeks, 0.11–44.0 μg L-1 in WWTP effluents, and 2.51–438 μg g-1 TOC in sediments. The spatial distributions of NPs in creeks and sediments from the inshore region were different from those of COP, suggesting that Lake Shihwa contamination patterns from industrial effluents differ from those from domestic effluents. The mass discharge from the combined outfall of the WWTPs, located in the offshore region, was 2.27 kg d-1 for NPs and 1.00 kg d-1 for COP, accounting for 91% and 95% of the total discharge into Lake Shihwa, respectively. The highest concentrations of NPs and COP in sediments were found in samples at sites near the submarine outfall of the WWTPs, indicating that the submarine outfall is an important point source of wastewater pollution in Lake Shihwa.

TREATMENT OF BIODIESEL WASTEWATER USING YELLOW MUSTARD SEEDS

OpenAIRE

SAVCI, Serpil

2017-01-01

In thisstudy, removal of original biodiesel wastewater (BOD, COD, oil&greas) by yellow mustard seeds was examined bya batch system. The effect of the adsorption time 300 minutes, adsorbent dose(1.0 g/L) and mixing rate (120 rpm) on the adsorption capacity of pollutants.The applicability of the Langmuir and Freundlich isotherms were examined.According to the data obtained from experiments, biodiesel wastewater can betreated by adsorption using yellow mustard seeds.

Red cabbage yield, heavy metal content, water use and soil chemical characteristics under wastewater irrigation.

Science.gov (United States)

Tunc, Talip; Sahin, Ustun

2016-04-01

The objective of this 2-year field study was to evaluate the effects of drip irrigation with urban wastewaters reclaimed using primary (filtration) and secondary (filtration and aeration) processes on red cabbage growth and fresh yield, heavy metal content, water use and efficiency and soil chemical properties. Filtered wastewater (WW1), filtered and aerated wastewater (WW2), freshwater and filtered wastewater mix (1:1 by volume) (WW3) and freshwater (FW) were investigated as irrigation water treatments. Crop evapotranspiration decreased significantly, while water use efficiency increased under wastewater treatments compared to FW. WW1 treatment had the lowest value (474.2 mm), while FW treatments had the highest value (556.7 mm). The highest water use efficiency was found in the WW1 treatment as 8.41 kg m(-3), and there was a twofold increase with regard to the FW. Wastewater irrigation increased soil fertility and therefore red cabbage yield. WW2 treatment produced the highest total fresh yield (40.02 Mg ha(-1)). However, wastewater irrigation increased the heavy metal content in crops and soil. Cd content in red cabbage heads was above the safe limit, and WW1 treatment had the highest value (0.168 mg kg(-1)). WW3 treatment among wastewater treatments is less risky in terms of soil and crop heavy metal pollution and faecal coliform contamination. Therefore, WW3 wastewater irrigation for red cabbage could be recommended for higher yield and water efficiency with regard to freshwater irrigation.

Treatment of coffee wastewater by gamma radiation

International Nuclear Information System (INIS)

Aguilera, Y.; Consuegra, R.; Rapado, M.

1998-01-01

Radiation energy can be an important resource in the treatment of wastewaters from different industries both directly and in combination with other processes to improve economics. The aim of this study was to evaluate the effect of an ionizing radiation on coffee wastewater in order to decompose chemical organic refractory substances which cannot be degradated by biological treatment. One of the approaches employed in the survey was the chemical treatment followed by the irradiation of the samples since no nuclear changes of the coagulant solution or wastewater samples were expected. Irradiation is a high cost treatment although it has increased its applications nowadays. The method is safe, fast and effective and it does not generate any pollution

Field observations and management strategy for hot spring wastewater in Wulai area, Taiwan.

Science.gov (United States)

Lin, J Y; Chen, C F; Lei, F R; Hsieh, C D

2010-01-01

Hot springs are important centers for recreation and tourism. However, the pollution that may potentially be caused by hot spring wastewater has rarely been discussed. More than half of Taiwan's hot springs are located in areas where the water quality of water bodies is to be protected, and untreated wastewater could pollute the receiving water bodies. In this study, we investigate hot spring wastewater in the Wulai area, one of Taiwan's famous hot spring resorts. Used water from five hot spring hotels was sampled and ten sampling events were carried out to evaluate the changes in the quality of used water in different seasons, at different periods of the week, and from different types of hotels. The concentrations of different pollutants in hot spring wastewater were found to exhibit wide variations, as follows: COD, 10-250 mg/L; SS, N.D.-93 mg/L; NH(3)-N, 0.01-1.93 mg/L; TP, 0.01-0.45 mg/L; and E. coli, 10-27,500 CFU/100 mL. The quality of hot spring wastewater depends on the operation of public pools, because this affects the frequency of supplementary fresh water and the outflow volume. Two management strategies, namely, onsite treatment systems and individually packaged treatment equipment, are considered, and a multi-objective optimization model is used to determine the optimal strategy.

Chemical and biological treatment technologies for leather tannery chemicals and wastewaters: a review.

Science.gov (United States)

Lofrano, Giusy; Meriç, Sureyya; Zengin, Gülsüm Emel; Orhon, Derin

2013-09-01

Although the leather tanning industry is known to be one of the leading economic sectors in many countries, there has been an increasing environmental concern regarding the release of various recalcitrant pollutants in tannery wastewater. It has been shown that biological processes are presently known as the most environmental friendly but inefficient for removal of recalcitrant organics and micro-pollutants in tannery wastewater. Hence emerging technologies such as advanced oxidation processes and membrane processes have been attempted as integrative to biological treatment for this sense. This paper, as the-state-of-the-art, attempts to revise the over world trends of treatment technologies and advances for pollution prevention from tannery chemicals and wastewater. It can be elucidated that according to less extent advances in wastewater minimization as well as in leather production technology and chemicals substitution, biological and chemical treatment processes have been progressively studied. However, there has not been a full scale application yet of those emerging technologies using advanced oxidation although some of them proved good achievements to remove xenobiotics present in tannery wastewater. It can be noted that advanced oxidation technologies integrated with biological processes will remain in the agenda of the decision makers and water sector to apply the best prevention solution for the future tanneries. Copyright © 2013 Elsevier B.V. All rights reserved.

Disposal of olive mill wastewater with DC arc plasma method.

Science.gov (United States)

Ibrahimoglu, Beycan; Yilmazoglu, M Zeki

2018-07-01

Olive mill wastewater is an industrial waste, generated as a byproduct of olive oil production process and generally contains components such as organic matter, suspended solids, oil, and grease. Although various methods have been developed to achieve the disposal of this industrial wastewater, due to the low cost, the most common disposal application is the passive storage in the lagoons. The main objective of this study is to reduce pollution parameters in olive mill wastewater and draw water to discharge limits by using plasma technology. Plasma-assisted disposal of olive mill wastewater method could be an alternative disposal technique when considering potential utilization of treated water in agricultural areas and economic value of flammable plasma gas which is the byproduct of disposal process. According to the experimental results, the rates of COD (chemical oxygen demand) and BOD (biological oxygen demand) of olive mill wastewater are decreased by 94.42% and 95.37%, respectively. The dissolved oxygen amount is increased from 0.36 to 6.97 mg/l. In addition, plasma gas with high H 2 content and treated water that can be used in agricultural areas for irrigation are obtained from non-dischargeable wastewater. Copyright © 2018 Elsevier Ltd. All rights reserved.

Hydroponic root mats for wastewater treatment-a review.

Science.gov (United States)

Chen, Zhongbing; Cuervo, Diego Paredes; Müller, Jochen A; Wiessner, Arndt; Köser, Heinz; Vymazal, Jan; Kästner, Matthias; Kuschk, Peter

2016-08-01

Hydroponic root mats (HRMs) are ecotechnological wastewater treatment systems where aquatic vegetation forms buoyant filters by their dense interwoven roots and rhizomes, sometimes supported by rafts or other floating materials. A preferential hydraulic flow is created in the water zone between the plant root mat and the bottom of the treatment system. When the mat touches the bottom of the water body, such systems can also function as HRM filter; i.e. the hydraulic flow passes directly through the root zone. HRMs have been used for the treatment of various types of polluted water, including domestic wastewater; agricultural effluents; and polluted river, lake, stormwater and groundwater and even acid mine drainage. This article provides an overview on the concept of applying floating HRM and non-floating HRM filters for wastewater treatment. Exemplary performance data are presented, and the advantages and disadvantages of this technology are discussed in comparison to those of ponds, free-floating plant and soil-based constructed wetlands. Finally, suggestions are provided on the preferred scope of application of HRMs.

Artificial wetland for wastewater treatment

International Nuclear Information System (INIS)

Arias I, Carlos A; Brix, Hans

2003-01-01

The development of constructed wetland technology for wastewater treatment has gone a long way and from an experimental and unknown empirical method, which was capable of handling wastewater a sound technology was developed. Thanks to research, and the work of many public and private companies that have gather valuable operation information, constructed wetland technology has evolved to be a relievable, versatile and effective way to treat wastewater, run off, handle sludge and even improve environmental quality and provide recreation sites, while maintaining low operation and maintenance costs, and at the same time, producing water of quality that can meet stringent regulations, while being and environmental friendly solution to treat waste-waters. Constructed wetlands can be established in many different ways and its characteristics can differ greatly, according to the user needs, the geographic site and even the climatic conditions of the area. The following article deals with the general characteristics of the technology and the physical and chemical phenomena that govern the pollution reduction with in the different available systems

Linking the environmental loads to the fate of PPCPs in Beijing: Considering both the treated and untreated wastewater sources

International Nuclear Information System (INIS)

Wang, Bin; Dai, Guohua; Deng, Shubo; Huang, Jun; Wang, Yujue; Yu, Gang

2015-01-01

The environmental loads of pharmaceutical and personal care products (PPCPs) in Beijing were estimated from direct discharge of untreated wastewater and WWTP treated effluent. The annual environmental loads of 15 PPCP components ranged from 16.3 kg (propranolol) to 9.85 tons (caffeine). A fugacity model was developed to successfully estimate the PPCP pollution based on the estimated environmental load. The modeled results approximated the observed PPCP concentrations in Beijing. The untreated wastewater contributed significantly to PPCP pollution in Beijing, ranging from 46% (propranolol) to 99% (caffeine). The total environmental burden of target PPCPs ranged from 0.90 kg (propranolol) to 536 kg (caffeine). Water is the most important media for the fate of PPCPs. Monte Carlo-based concentration distributions of PPCPs are consistent with the observed results. The most important way to reduce the PPCP pollution is to both improve wastewater collection rate and adopt deep treatment technologies. - Highlights: • Annual environmental loads of PPCPs ranged from 16.3 kg to 9.85 tons in Beijing. • The environmental loads can be linked to PPCP pollution by fugacity model. • Untreated wastewater significantly contributed to PPCP pollution in Beijing. • The environmental burden of 15 PPCPs in Beijing ranged from 0.90 kg to 536 kg. • Uncertainty simulation successfully generated PPCP concentration distribution. - The environmental loads from both the treated and untreated wastewater sources contribute to PPCPs pollution in the surface water in Beijing, China

Treatment of wastewater from rubber industry in Malaysia ...

African Journals Online (AJOL)

Treatment of wastewater from rubber industry in Malaysia. ... Discharge of untreated rubber effluent to waterways resulted in water pollution that affected the human health. ... Key words: Rubber industry, effluent, waste management, Malaysia.

CONSTRUCTED WETLAND TECHNOLOGY TO PREVENT WATER RESOURCES POLLUTION

Directory of Open Access Journals (Sweden)

Zeki Gökalp

2016-07-01

Full Text Available Discharge of untreated waste waters into surface waters creates significant pollution in these resources. Wastewaters are most of the time discharged into seas, rivers and other water bodies without any treatments due to high treatment costs both in Turkey and throughout the world. Constructed wetlands, also called as natural treatment systems, are used as an alternative treatment system to conventional high-cost treatment systems because of their low construction, operation and maintenance costs, energy demands, easy operation and low sludge generation. Today, constructed wetland systems are largely used to treat domestic wastewaters, agricultural wastewaters, industrial wastewater and runoff waters and ultimately to prevent water pollution and to improve water quality of receiving water bodies. In present study, currently implemented practices in design, construction, operation and maintenance of constructed wetlands were assessed and potential mistakes made in different phases these systems were pointed out and possible solutions were proposed to overcome these problems.

Wastewater treatments and the impact on environment and agriculture: A case city of Annaba (north eastern of Algeria)

Science.gov (United States)

Abour, Fella; Hannouche, Mani; Belksier, Mohamed Salah

2018-05-01

The present study deals with wastewater treatment which represents a real challenge in the world especially for developing countries. Our investigation takes place in the Annaba (North Eastern of Algeria) which represents one of big cities in the country. The wastewater is treated collectively in the Allalik station which provides a global wastewater treatment to guarantee the sustainability of the ecosystem. The obtained results on treated wastewater show a contamination with Selenium (IS index for Selenium = 5.9). Whereas the other analysed parameters highlight values without exceeding standards excepting the nitrites. The microbiological analyses and Bourgeois index indicate the human origin for pollution (IB >1). In spite of the actual treatment, the pollution selenium and nitrites suggest the improvement of the process of wastewater treatment.

Organic micropollutants discharged by combined sewer overflows - Characterisation of pollutant sources and stormwater-related processes.

Science.gov (United States)

Launay, Marie A; Dittmer, Ulrich; Steinmetz, Heidrun

2016-11-01

To characterise emissions from combined sewer overflows (CSOs) regarding organic micropollutants, a monitoring study was undertaken in an urban catchment in southwest Stuttgart, Germany. The occurrence of 69 organic micropollutants was assessed at one CSO outfall during seven rain events as well as in the sewage network at the influent of the wastewater treatment plant (WWTP) and in the receiving water. Several pollutant groups like pharmaceuticals and personal care products (PPCPs), urban biocides and pesticides, industrial chemicals, organophosphorus flame retardants, plasticisers and polycyclic aromatic hydrocarbons (PAHs) were chosen for analysis. Out of the 69 monitored substances, 60 were detected in CSO discharges. The results of this study show that CSOs represent an important pathway for a wide range of organic micropollutants from wastewater systems to urban receiving waters. For most compounds detected in CSO samples, event mean concentrations varied between the different events in about one order of magnitude range. When comparing CSO concentrations with median wastewater concentrations during dry weather, two main patterns could be observed depending on the source of the pollutant: (i) wastewater is diluted by stormwater; (ii) stormwater is the most important source of a pollutant. Both wastewater and stormwater only play an important role in pollutant concentration for a few compounds. The proportion of stormwater calculated with the conductivity is a suitable indicator for the evaluation of emitted loads of dissolved wastewater pollutants, but not for all compounds. In fact, this study demonstrates that remobilisation of in-sewer deposits contributed from 10% to 65% to emissions of carbamazepine in CSO events. The contribution of stormwater to CSO emitted loads was higher than 90% for all herbicides as well as for PAHs. Regarding the priority substance di(2-ethylhexyl)phthalate (DEHP), this contribution varied between 39% and 85%. The PAH

The '333' integrated strategy for effective pollution control and its application to the heavily polluted Jialu River in north China.

Science.gov (United States)

Huang, Yu; Sun, Jie; Li, Aimin; Xie, Xianchuan

2018-05-01

In this study, an integrated approach named the '333' strategy was applied to pollution control in the Jialu River, in northern China, which is heavily burdened with anthropogenic pollution. Due to a deficiency of the natural ecological inflow, the Jialu River receives predominantly industrial and municipal effluent. The '333' strategy is composed of three steps of pollution control including industrial point-source pollution control, advanced treatment of municipal wastewater, and ecological restoration; three increased stringency emission standards; and three stages of reclamation. Phase 1 of the '333' strategy focuses on industrial point-source pollution control; phase 2 aims to harness municipal wastewater and minimize sewage effluents using novel techniques for advanced water purification; phase 3 of the '333' strategy focuses on the further purification of effluents flowing into Jialu River with the employment of an engineering-based ecological restoration project. The application of the '333' strategy resulted in the development of novel techniques for water purification including modified magnetic resins (NDMP resin), a two-stage internal circulation anaerobic reactor (IC reactor) and an ecological restoration system. The results indicate that water quality in the river was significantly improved, with increased concentrations of dissolved oxygen (DO), as well as reduction of COD by 42.8% and NH 3 -N by 61.4%. In addition, it was observed that the total population of phytoplankton in treated river water notably increased from only one prior to restoration to 8 following restoration. This system also provides a tool for pollution control of other similar industrial and anthropogenic source polluted rivers.

Municipal wastewater treatment for effective removal of organic matter and nitrogen

International Nuclear Information System (INIS)

Grebenevich, E.V.; Zaletova, N.A.; Terentieva, N.A.

1987-01-01

The organic matter, as well as nitrogen and phosphorus, are nutrient substances. Their excess concentrations in water receiving bodies lead to eutrophication, moreover, the nitrogen content in water bodies is standardized according the sanitary-toxicological criterion of harmfulness: NH 4 + -N ≤0,39-2,0 mgl - , NO 3 -N ≤9,1-10 mgl - . The municipal wastewater contain, usually, organic matter estimated by BOD 150-200 mgl - , and COD 300-400 mgl - , the nitrogen compounds 50-60 mgl - , and NH 4 + -N 20-25 mgl - . NO x -N are practically absent. Their presence indicated on discharge of industrial wastewater. The total phosphorus is present in the concentration of 15 mgl - , PO 4 - - P 5-8 mgl - . Activated sludge process has been most widely used in the USSR for municipal wastewater treatment. The activated sludge is biocenoses of heterotrophic and auto trophic microorganisms. They consume nutrient matters, transferring pollution of wastewater by means of enzyme systems in acceptable forms. C, N and P-containing matters are removed from wastewater by biological intake for cell synthesis. Moreover C- containing matters are removed by oxidation to CO 2 and H 2 O. P-containing compounds under definite conditions associate with solid fraction of activated sludge and thus simultaneously removed from wastewater. The removal of nitrogen in addition to biosynthesis is carried out only in the denitrification process, when oxygen of NO x -N is used for oxidation of organic matter and produced gaseous nitrogen escapes into the atmosphere

Remediation of the effect of adding cyanides on an algal/bacterial treatment of a mixture of organic pollutants in a continuous photobioreactor.

Science.gov (United States)

Essam, Tamer; ElRakaiby, Marwa; Agha, Azza

2014-09-01

The effect of inorganic pollutants on the treatment of organic pollutants using algal/bacterial microcosm was investigated in a continuous photobioreactor. The microcosm was composed of Chlorella vulgaris MM1 and Pseudomonas MT1 and was able to efficiently treat artificial waste-water contaminated with 6.4 salicylate and 2.2 mM phenol at a hydraulic retention time of 4 days. No negative effect was recorded when the waste-water was supplemented with 1.6 mM thiocyanate; however, the treatment efficiency severely deteriorated when the system was challenged with 0.74 mM cyanide. Addition of 2 g NaHCO3 l(-1) did not improve the efficiency of the treatment. Toxicity of the pollutants to the alga was cyanide > thiocyanate > phenol > salicylate. The high toxicity of the waste-water was eliminated either by a 25-fold dilution or by photocatalytic pre-treatment which allowed the subsequent efficient biological treatment.

Natural treatment system models for wastewater management: a study from Hyderabad, India.

Science.gov (United States)

Sonkamble, Sahebrao; Wajihuddin, Md; Jampani, Mahesh; Sarah, S; Somvanshi, V K; Ahmed, Shakeel; Amerasinghe, Priyanie; Boisson, Alexandre

2018-01-01

Wastewater generated on a global scale has become a significant source of water resources which necessitates appropriate management strategies. However, the complexities associated with wastewater are lack of economically viable treatment systems, especially in low- and middle-income countries. While many types of treatment systems are needed to serve the various local issues, we propose natural treatment systems (NTS) such as natural wetlands that are eco-friendly, cost-effective, and can be jointly driven by public bodies and communities. In order for it to be part of wastewater management, this study explores the NTS potential for removal of pollutants, cost-effectiveness, and reuse options for the 1.20 million m 3 /day of wastewater generated in Hyderabad, India. The pilot study includes hydro-geophysical characterization of natural wetland to determine pollutant removal efficiency and its effective utilization for treated wastewater in the peri-urban habitat. The results show the removal of organic content (76-78%), nutrients (77-97%), and microbes (99.5-99.9%) from the wetland-treated wastewater and its suitability for agriculture applications. Furthermore, the wetland efficiency integrated with engineered interventions led to the development of NTS models with different application scenarios: (i) constructed wetlands, (ii) minimized community wetlands, and (iii) single outlet system, suitable for urban, peri-urban and rural areas, respectively.

Reducing the pollutant load of olive mill wastewater by photocatalytic membranes and monitoring the process using both tyrosinase biosensor and COD test

Directory of Open Access Journals (Sweden)

Elisabetta eMartini

2013-12-01

Full Text Available Photocatalytic technique had already been employed in the treatment of olive mill wastewater (OMW using the photocatalysis in suspension. The coupling of photocatalytic and membrane techniques should result in a very powerful process bringing great innovation to OMW depollution. Despite the potential advantages using these hybrid photoreactors, research on the combined use of photocatalysis and membranes has so far not been sufficiently developed. The present paper describes a study to assess the photocatalytic efficacy of a new ceramic membrane containing titanium dioxide, irradiated by UV light, used to abate the pollutant load of olive mill wastewater. Good results were obtained (more than 90% of the phenol content was removed and the COD decrease was of the order of 46-51 % in 24 h particularly using the ceramic membrane compared with those offered by analogous catalytic membranes made of metallic or polymeric materials.

Analysis on the relationship between economic development and water environment pollution in Shandong province

Science.gov (United States)

Liu, Yi; Zhang, Zhengxian

2018-02-01

With the continuous development of the economy of the Shandong Province watershed, a large number of pollutant emission, resulting in water quality of the basin has undergone significant changes. To study the Shandong Province watershed economic development and the relationship between the discharge of pollutants, in this paper, the relationship between economic growth and pollutant emissions in the Shandong Province watershed was established by Shandong Province watershed in 2002-2015 per capita GDP and wastewater, COD, ammonia nitrogen(AN) pollutant emissions. The data were analyzed by software such as SPSS, and the cubic equation model between various pollutants and economic indexes was fitted. To further make the relationship between pollutants and economic development map to study the conventional pollutant emissions and economic development trends. It is found that only the relationship between industrial wastewater discharge and per capita GDP is most coordinated, that is, industrial wastewater emissions with the continuous development of the basin economy, showing a tendency to rise first and then fall. Finally, ultimately based on the results of the study of the water environment and economic development proposals were proposed.

Removal of COD, phenols and ammonium from Lurgi coal gasification wastewater using A2O-MBR system

International Nuclear Information System (INIS)

Wang, Zixing; Xu, Xiaochen; Gong, Zheng; Yang, Fenglin

2012-01-01

Highlights: ► Anaerobic–anoxic–aerobic MBR system treated the coal gasification wastewater. ► COD removal rate was 97.4% with effluent concentration less than 100 mg/L. ► NH 4 + -N removal rate was 92.8% with effluent concentration less than 12 mg/L. ► HRT and recycle ratio strongly affected the performance of the system. ► GC/MS analysis found refractory organic removal in anaerobic and anoxic stage. - Abstract: As a typical industrial wastewater, coal gasification wastewater has poor biodegradability and high toxicity. In this paper, a laboratory-scale anaerobic–anoxic–oxic membrane reactor (A 2 O-MBR) system was developed to investigate the treatment ability of coal gasification wastewater. The removal capacity of each pollutants used in this system were determined at different hydraulic residence times (HRT) and mixed liquor recycle ratios (R). The experimental results showed that this system could effectively deal with COD and phenol removal and remain in a stable level when the operational parameters altered, while the nitrification was sensitive to operational conditions. The best performance was obtained at HRT of 48 h and R of 3. The maximum removal efficiencies of COD, NH 4 + -N and phenols were 97.4%, 92.8% and 99.7%, with final concentrations in the effluent of 71 mg/L, 9.6 mg/L and 3 mg/L, respectively. Organics degradation and transformation were analyzed by GC/MS and it was found that anaerobic process played an important role in degradation of refractory compounds.

Wastewater and sludge reuse in agriculture

Science.gov (United States)

Kalavrouziotis, Ioannis

2016-04-01

The reuse of Municipal wastewaters (TMWW) for irrigation of crops, and of sludge for the amendment of soils, is a multidimensional disposal practice aiming at: (i) minimizing the environmental problems by releasing the pressure exerted by these two inputs on the environment, (ii) providing the growing plants with water and nutrients and (ii) improving soil fertility and productivity, The research work conducted in our University in relation to accomplishing a safe reuse has been focused on the study of the following aspects of reuse: (i) heavy metal accumulation in soils and plants with emphasis on their edible part. This aspect has been studied by conducting a series of experiments aiming at the study of the accumulation of heavy metals in soils, and in plant roots, stalks, leaves and fruits. The conclusions drawn so far with regard to the order of accumulation of heavy metals are: Roots>leaves>stalks>fruits ( edible parts) (ii) interactions between heavy metals, plant nutrients and soil chemical and physical properties. After the examinations of hundreds of interactions, and the development of a quantification of the interactions contribution, it was found that considerable quantities of heavy metals and nutrients are contributed to the soil and to various plant parts , emphasizing the important role of the elemental interactions in plants.(iii) assessment of soil pollution with heavy metals based on pollution indices, Three pollution Indices have been established by our research team and were proposed internationally for application in actual practice for the prediction of soil pollution due to long term reuse of wastewater and sludge. These indices are as follows: (a) Elemental pollution Index (EPI), (b) Heavy Metal Load (HML), and (c) Total Concentration Factor (TCF) and (iv) construction of a computer program for the control of the reuse of TMWW and sludge, and forecasting soil pollution due to accumulation of heavy metal by means of pollution indices.

AN INVESTIGATION ON PATHOGENIC VIBRIOS DISTRIBUTION IN DOMESTIC WASTEWATER

OpenAIRE

A. Almasi

2005-01-01

Municipal wastewater is one of the most important pollution sources for water supply resources. Identification and enumeration of pathogenic agents particularly pathogenic Vibrios are beneficial for controlling and prevention planning of the infectious diseases. This research was carried out to identify the distribution of the recognized pathogenic Vibrios with emphasizing on identification of Vibrio cholera in the wastewater of Kermanshah city western Iran in 2002. The method of study was cr...

Removal of Organic Dyes from Industrial Wastewaters Using UV/H2O2, UV/H2O2/Fe (II, UV/H2O2/Fe (III Processes

Directory of Open Access Journals (Sweden)

Nezamaddin Daneshvar

2007-03-01

Full Text Available UV/H2O2, UV/H2O2/Fe (II and UV/H2O2/Fe (III processes are very effective in removing pollutants from wastewater and can be used for treatment of dyestuff units wastewaters. In this study, Rhodamine B was used as a typical organic dye. Rhodamine B has found wide applications in wax, leather, and paper industries. The results from this study showed that this dye was degradable in the presence of hydrogen peroxide under UV-C irradiation (30W mercury light and Photo-Fenton process. The dye was resistant to UV irradiation. In the absence of UV irradiation, the decolorization efficiency was very negligible in the presence of hydrogen. The effects of different system variables such as initial dye concentration, duration of UV irradiation, and initial hydrogen peroxide concentration were investigated in the UV/H2O2 process. Investigation of the kinetics of the UV/H2O2 process showed that the semi-log plot of the dye concentration versus time was linear, suggesting a first order reaction. It was found that Rhodamine B decolorization efficiencies in the UV/H2O2/Fe (II and UV/H2O2/Fe (III processes were higher than that in the UV/H2O2 process. Furthermore, a solution containing 20 ppm of Rhodamine B was decolorized in the presence 18 mM of H2O2 under UV irradiation for 15 minutes. It was also found that addition of 0.1 mM Fe(II or Fe(III to the solution containing  20  ppm of the dye and 5 mM H2O2 under UV light  illumination decreased removal time to 10 min.

Supported Photocatalyst for Removal of Emerging Contaminants from Wastewater in a Continuous Packed-Bed Photoreactor Configuration

OpenAIRE

Borges, Mª; García, Dulce; Hernández, Tania; Ruiz-Morales, Juan; Esparza, Pedro

2015-01-01

Water pollution from emerging contaminants (ECs) or emerging pollutants is an important environmental problem. Heterogeneous photocatalytic treatment, as advanced oxidation treatment of wastewater effluents, has been proposed to solve this problem. In this paper, a heterogeneous photocatalytic process was studied for emergent contaminants removal using paracetamol as a model contaminant molecule. TiO2 photocatalytic activity was evaluated using two photocatalytic reactor configurations: Photo...

Coupling of anodic oxidation and adsorption by granular activated carbon for chemical oxygen demand removal from 4,4'-diaminostilbene-2,2'-disulfonic acid wastewater.

Science.gov (United States)

Wang, Lizhang; Zhao, Yuemin

2010-01-01

Experiments were performed to reduce chemical oxygen demand (COD) from 4,4'-diaminostilbene-2,2'-disulfonic (DSD) acid manufacturing wastewater using electrochemical oxidation coupled with adsorption by granular activated carbon. The COD removal is affected by the residence time and applied voltage. When the residence time is increased, lower value of COD effluent could be obtained, however, the average current efficiency (ACE) decreased rapidly, and so does the applied voltage. In addition, aeration could effectively enhance COD removal efficiency and protect anodes from corrosion. Furthermore, the acidic condition is beneficial to the rapid decrease of COD and the values of pH effluent are independent of the initial solution pH. The optimization conditions obtained from these experiments are applied voltage of 4.8 V, residence time of 180 min and air-liquid ratio of 4.2 with the COD effluent of about 690 mg L⁻¹. In these cases, the ACE and energy consumption are 388% and 4.144 kW h kg⁻¹ COD, respectively. These perfect results from the experiments illustrate that the combined process is a considerable alternative for the treatment of industrial wastewater containing high concentration of organic pollutants and salinity.

Researching the technology of tar removal from coke-chemical plants’ wastewater by reagent flotation method

Directory of Open Access Journals (Sweden)

Anna V. Ivanchenko

2015-03-01

Full Text Available The study aims to identify process patterns of tars and oils removal from phenolic wastewater by reagent flotation with bringing those components’ content to acceptable concentrations. For the first time established is the effect of Al2(SO43, AlCl3, FeSO4, Fe2(SO43, Al2(OH5Cl and FeCl3 doses onto residual tar content in phenolic wastewater. Results obtained give the possibility to prevent air pollution resulting from the toxic substances emission at the wet quenching with water containing excessive oils and to increase the quality of wastewater biological treatment. It is shown experimentally that the most efficient are Fe2(SO43, FeCl3 and Al2(OH5Cl at optimum concentrations of 50, 30 and 30 mg/dm3 respectively. The Al2(OH5Cl can be recommended for implementation at industry on existing coking plants and municipal wastewater treatment plants to improve the environmental air and water resources condition in Ukraine.

Greenhouse cultivation mitigates metal-ingestion-associated health risks from vegetables in wastewater-irrigated agroecosystems

Energy Technology Data Exchange (ETDEWEB)

Cao, Chun [College of Earth and Environmental Sciences, Lanzhou University, Lanzhou 730000, Gansu (China); College of Geography and Environmental Science, Northwest Normal University, Lanzhou 730070, Gansu (China); Chen, Xing-Peng; Ma, Zhen-Bang [College of Earth and Environmental Sciences, Lanzhou University, Lanzhou 730000, Gansu (China); Jia, Hui-Hui [State High-Tech Industrial Innovation Center, Shenzhen 518057, Guangdong (China); Wang, Jun-Jian, E-mail: junjian.wang@utoronto.ca [Department of Physical and Environmental Sciences, University of Toronto, Toronto M1C 1A4 (Canada)

2016-08-01

Wastewater irrigation can elevate metal concentrations in soils and crops and increase the metal-associated health risks via vegetable ingestion in arid and semiarid northwestern China. Here, we investigated the As, Cd, Cr, Cu, Ni, Pb, and Zn concentrations in four vegetable species from Dongdagou and Xidagou farmlands in Baiyin, Gansu, China. We evaluated the effects of irrigation type (Dongdagou: industrial wastewater; Xidagou: domestic wastewater) and cultivation mode (open field and greenhouse) on the vegetable metal concentration, metal partitioning, soil-to-plant bioconcentration factor (BCF), and the health risk index. All stream waters, soils, and vegetables were found most severely polluted by As and Cd, with higher severity in the industrial-wastewater-irrigated Dongdagou than the domestic-wastewater-irrigated Xidagou. All vegetables had higher or, at least, comparable metal mass allocated in the shoot than in the root. Greenhouse cultivation could reduce metal-ingestion-associated health risks from edible vegetable biomass by decreasing the soil to plant bioaccumulation (BCF) and the metal concentration. This effect was always significant for all vegetables within Xidagou, and for carrot within Dongdagou. This mitigation effect of greenhouse cultivation could be attributed to the metal sorption by a higher level of soil organic matter and faster growth rate over metal uptake rate in greenhouses compared to open fields. Such mitigation effect was, however, insignificant for leafy vegetables within Dongdagou, when much more severely polluted water for irrigation was applied in greenhouses compared to open fields within Dongdagou. The present study highlights greenhouse cultivation as a potential mitigating approach to providing less-polluted vegetables for residents in the severely polluted area in addition to the source pollution control. - Highlights: • Vegetable farmlands in Baiyin, Gansu, China were severely polluted by As and Cd. • Greenhouses had

Greenhouse cultivation mitigates metal-ingestion-associated health risks from vegetables in wastewater-irrigated agroecosystems

International Nuclear Information System (INIS)

Cao, Chun; Chen, Xing-Peng; Ma, Zhen-Bang; Jia, Hui-Hui; Wang, Jun-Jian

2016-01-01

Wastewater irrigation can elevate metal concentrations in soils and crops and increase the metal-associated health risks via vegetable ingestion in arid and semiarid northwestern China. Here, we investigated the As, Cd, Cr, Cu, Ni, Pb, and Zn concentrations in four vegetable species from Dongdagou and Xidagou farmlands in Baiyin, Gansu, China. We evaluated the effects of irrigation type (Dongdagou: industrial wastewater; Xidagou: domestic wastewater) and cultivation mode (open field and greenhouse) on the vegetable metal concentration, metal partitioning, soil-to-plant bioconcentration factor (BCF), and the health risk index. All stream waters, soils, and vegetables were found most severely polluted by As and Cd, with higher severity in the industrial-wastewater-irrigated Dongdagou than the domestic-wastewater-irrigated Xidagou. All vegetables had higher or, at least, comparable metal mass allocated in the shoot than in the root. Greenhouse cultivation could reduce metal-ingestion-associated health risks from edible vegetable biomass by decreasing the soil to plant bioaccumulation (BCF) and the metal concentration. This effect was always significant for all vegetables within Xidagou, and for carrot within Dongdagou. This mitigation effect of greenhouse cultivation could be attributed to the metal sorption by a higher level of soil organic matter and faster growth rate over metal uptake rate in greenhouses compared to open fields. Such mitigation effect was, however, insignificant for leafy vegetables within Dongdagou, when much more severely polluted water for irrigation was applied in greenhouses compared to open fields within Dongdagou. The present study highlights greenhouse cultivation as a potential mitigating approach to providing less-polluted vegetables for residents in the severely polluted area in addition to the source pollution control. - Highlights: • Vegetable farmlands in Baiyin, Gansu, China were severely polluted by As and Cd. • Greenhouses had

Desorption of organophosphorous pesticides from soil with wastewater and surfactant solutions

International Nuclear Information System (INIS)

Hernandez-Soriano, M. C.; Mingorance, M. D.; Pena, A.

2009-01-01

Surfactants can be introduced in the environment by wastewater discharge, point-charge pollution or deliberate action, e. g. to remediate contaminated soil or groundwater. The irrigation of soil with wastewater containing surfactants may modify pesticide desorption from soil, thus affecting their affecting their environmental fate. Desorption from soil of the plain of Granada (South-eastern Spain) of two organophosphorous pesticides, diazinon and dimethoate, differing in solubility and hydrophobicity, has been evaluated in the presence of different surfactant aqueous solutions and municipal wastewater. (Author)

Economics of social trade-off: Balancing wastewater treatment cost and ecosystem damage.

Science.gov (United States)

Jiang, Yu; Dinar, Ariel; Hellegers, Petra

2018-04-01

We have developed a social optimization model that integrates the financial and ecological costs associated with wastewater treatment and ecosystem damage. The social optimal abatement level of water pollution is determined by finding the trade-off between the cost of pollution control and its resulting ecosystem damage. The model is applied to data from the Lake Taihu region in China to demonstrate this trade-off. A wastewater treatment cost function is estimated with a sizable sample from China, and an ecological damage cost function is estimated following an ecosystem service valuation framework. Results show that the wastewater treatment cost function has economies of scale in facility capacity, and diseconomies in pollutant removal efficiency. Results also show that a low value of the ecosystem service will lead to serious ecological damage. One important policy implication is that the assimilative capacity of the lake should be enhanced by forbidding over extraction of water from the lake. It is also suggested that more work should be done to improve the accuracy of the economic valuation. Copyright © 2018 Elsevier Ltd. All rights reserved.

Treatability study of pesticide-based industrial wastewater.

Science.gov (United States)

Shah, Kinnari; Chauhan, L I; Galgale, A D

2012-10-01

This paper finds out appropriate treatment methods for wastewater of an Organophosphorus viz, chloropyrifos pesticide manufacturing industry. The characterization of wastewater generated during trial production of chloropyrifos was carried out. Based on the characterization of wastewater, various treatability studies were conducted. The most desirable results were obtained with treatment scheme employing acidification, chlorination with NaOCl, suspended growth biological treatment, chemical precipitation for phosphorous removal and activated carbon treatment. Acidification of wastewater helps in by-product recovery as well as reduction in COD upto 36.26%. Chlorination followed by biological treatment was found to be effective to reduce the COD level by 62.06%. To comply with permissible limits prescribed by Effluent Channel Project Ltd.(ECPL)* and Gujarat Pollution Control Board (GPCB) for discharge of industrial effluent into channel, further treatment in the form of chemical precipitation (for phosphorous removal) and granular activated carbon is suggested.

Influence of temperature on hydrogen production from bread mill wastewater by sewage sludge

Energy Technology Data Exchange (ETDEWEB)

Tang, G.L.; Huang, J.; Li, Y.Y.; Sun, Z.J. [China Agricultural Univ., Beijing (China). College of Resources and Environmental Sciences; Tang, Q.Q. [Nanjing Univ., Nanjing (China). Medical School

2008-07-01

Hydrogen (H{sub 2}) energy has been touted as a sustainable and clean energy source that can solve environmental problems such as acid rain, greenhouse gases and transboundary pollution. While most hydrogen is currently produced from nonrenewable sources such as oil, natural gas, and coal, these processes are energy-intensive and costly. The biological production of hydrogen using fermentative bacteria is an environmentally friendly and energy-saving process which has recently attracted much attention as an effective way of converting biomass into H{sub 2}. Waste-based H{sub 2} production processes mainly include wastewater from paper mills, municipal solid waste, rice winery wastewater, and food wastewater from cafeterias. This study investigated the use of bread mill wastewater for biological production of hydrogen due to its high production potential. Annual bread production in China is estimated to be over 1.5 million tons, producing 10 m{sup 3} of wastewater per ton of bread. The wastewater has high chemical oxygen demand and carbohydrate concentrations and is therefore suitable for anaerobic treatment processes. This study evaluated the effect of temperature on H{sub 2} production from bread mill wastewater by sewage sludge in lab-scale experiments. H{sub 2} production, the distribution of volatile fatty acids and the lag-phase time were influenced by temperature. H{sub 2} production and H{sub 2} yield increased with increasing temperature. The optimal temperature for H{sub 2} production was 50 degrees C. Butyrate, acetate and alcohol were the main by-products of H{sub 2} fermentation. According to 16S rDNA analysis, the dominant microflora was Clostridium, but the microbial species varied with temperature. The activation energy for H{sub 2} production was estimated to be 92 kJ per mol for bread mill wastewater. It was concluded that bread mill wastewater could potentially serve as a substrate for H{sub 2} production. This research provides a means of

Application of three tailing-based composites in treating comprehensive electroplating wastewater.

Science.gov (United States)

Liu, Hongbo; Zhu, Mengling; Gao, Saisai

2014-01-01

Heavy metals and chemical oxygen demand (COD) are major challenging pollutants for most electroplating wastewater treatment plants. A novel composite material, prepared with a mixture of calcium and sodium compounds and tailings, was simply mixed by ratios and used to treat a comprehensive electroplating wastewater with influent COD, total copper (T-Cu), and total nickel (T-Ni) respectively as 690, 4.01, and 20.60 mg/L on average. Operational parameters, i.e. the contact time, pH, mass ratio of calcium and sodium compounds and tailings, were optimized as 30 min, 10.0, and 4:2:1. Removal rates for COD, T-Cu, and T-Ni could reach 71.8, 90.5, and 98.1%, respectively. No significant effect of initial concentrations on removal of T-Cu and T-Ni was observed for the composite material. The adsorption of Cu(II) and Ni(II) on the material fitted Langmuir and Freundlich isotherms respectively. Weight of waste sludge from the calcium/sodium-tailing system after reaction was 10% less than that from the calcium-tailing system. The tailing-based composite is cost-effective in combating comprehensive electroplating pollution, which shows a possibility of applying the tailings in treating electroplating wastewater.

Catalytic Wastewater Treatment Using Pillared Clays

Science.gov (United States)

Perathoner, Siglinda; Centi, Gabriele

After introduction on the use of solid catalysts in wastewater treatment technologies, particularly advanced oxidation processes (AOPs), this review discussed the use of pillared clay (PILC) materials in three applications: (i) wet air catalytic oxidation (WACO), (ii) wet hydrogen peroxide catalytic oxidation (WHPCO) on Cu-PILC and Fe-PILC, and (iii) behavior of Ti-PILC and Fe-PILC in the photocatalytic or photo-Fenton conversion of pollutants. Literature data are critically analyzed to evidence the main direction to further investigate, in particularly with reference to the possible practical application of these technologies to treat industrial, municipal, or agro-food production wastewater.

Design and operation of UASB—A/O process for treatment starch and VB12 wastewater

Directory of Open Access Journals (Sweden)

Yuanyuan CHEN

2016-12-01

Full Text Available Starch and VB12 wastewater with higher COD and ammonia nitrogen concentration, contains a large number of difficult biodegradable material, complex composition, is difficult to deal with. In recent years, with the increasingly stringent wastewater discharge standards, require the use of a stable and efficient wastewater treatment process for purification treatment of high concentration of ammonia nitrogen in wastewater and the refractory organic pollutants, to achieve discharge standards. Upflow Anaerobic Sludge Blanket (UASB—Anoxic/Oxic(A/O process was employed in a wastewater treatment of starch and Vitamin B12 wastewater, which was 5 000 m3/d with highly concentrated organic pollutants and ammonia. The efficiency and reliability of the process has been proven. The results of the system operation show that the concentration of the effluent COD, ammonia and total nitrogen (TN were at 78.4 mg/L, 18.7 mg/L and 41.1 mg/L, and the treatment efficiencies of COD, ammonia and TN reached over 99%, 92.1%, 82.7%, respectively, when the influent COD and TN concentration were in the ranges of 8 544~9 720 mg/L and 240~250 mg/L. The quality of the treated wastewater met the first-class discharge standards in Integrated Wastewater Discharge Standard(GB 8978—1996.

Dynamic Membrane Technology for Printing Wastewater Reuse

Science.gov (United States)

Liu, Lin; Lu, Xujie; Chen, Jihua

As environmental regulations become rigid and the cost of freshwater increases, wastewater is considered as a major resource in China. The paper presented a study on the implementation of the advanced treatment process using dynamic membrane (DM) in reusing of printing wastewater. The DM was well formed by circulating 1.5g/L of PAC in 20 minutes, the trans-membrane pressure of 200 kPa and the cross-flow velocity of 0.75m/s. The printing effluents were treated in effluent treatment plants comprising a physicochemical option followed by biological process. The treated effluent contained chemical oxygen demand (COD), color and turbidity in the range of 45-60 mg/L, 0.030-0.045 (absorbance at 420 nm) and 3-5 NTU. The results showed that the COD, color and turbidity removal efficiencies of the DM permeate were 84%, 85% and 80%, respectively. The wastewater treated by DM was reused as process water and the final concentrated retentate could be discharged directly into sewage treatment works with no additional treatments. Cleaning and regeneration of DM were very convenient if necessary. The proper process was that the polluted DM was cleaned with tap water at high cross-flow velocity. When irreversible pollutants accumulate, it would be rinsed with chemicals tested and the membrane flux would be restored up to 95%. The result showed that DM was considered as a promising method for purification aimed at reuse of printing wastewater, resulting in direct environmental and economic benefits.

A novel PSB-EDI system for high ammonia wastewater treatment, biomass production and nitrogen resource recovery: PSB system.

Science.gov (United States)

Wang, Hangyao; Zhou, Qin; Zhang, Guangming; Yan, Guokai; Lu, Haifeng; Sun, Liyan

A novel process coupling photosynthetic bacteria (PSB) with electrodeionization (EDI) treatment was proposed to treat high ammonia wastewater and recover bio-resources and nitrogen. The first stage (PSB treatment) was used to degrade organic pollutants and accumulate biomass, while the second stage (EDI) was for nitrogen removal and recovery. The first stage was the focus in this study. The results showed that using PSB to transform organic pollutants in wastewater into biomass was practical. PSB could acclimatize to wastewater with a chemical oxygen demand (COD) of 2,300 mg/L and an ammonia nitrogen (NH4(+)-N) concentration of 288-4,600 mg/L. The suitable pH was 6.0-9.0, the average COD removal reached 80%, and the biomass increased by an average of 9.16 times. The wastewater COD removal was independent of the NH4(+)-N concentration. Moreover, the PSB functioned effectively when the inoculum size was only 10 mg/L. The PSB-treated wastewater was then further handled in an EDI system. More than 90% of the NH4(+)-N was removed from the wastewater and condensed in the concentrate, which could be used to produce nitrogen fertilizer. In the whole system, the average NH4(+)-N removal was 94%, and the average NH4(+)-N condensing ratio was 10.0.

Application of electron beam to industrial wastewater treatment

International Nuclear Information System (INIS)

Han, B.; Kim, D.K.; Boo, J.Y.; Kim, J.K.; Kim, Y.; Chung, W.; Choi, J.S.; Kang, H.J.; Pikaev, A.K.

2001-01-01

Global withdrawals of water to satisfy human demands have grown dramatically in this century. Between 1900 and 1995, water consumption increased by over six times, more than double the rate of population growth. This rapid growth in water demand is due to the increasing reliance on irrigation to achieve food security, the growth of industrial uses, and the increasing use per capita for domestic purposes. Given the seriousness of the situation and future risk of crises, there is an urgent need to develop the water efficient technologies including economical treatment methods of wastewater and polluted water. In the Central Research Institute of Samsung Heavy Industries (SHI), many industrial wastewater including leachate from landfill area, wastewater from papermill, dyeing complex, petrochemical processes, etc. are under investigation with EB irradiation. For the study of treating dyeing wastewater combined with conventional facilities, an EB pilot plant for treating 1,000m 3 /day of wastewater from 60,000m 3 /day of total dyeing wastewater has been constructed and operated in Taegu Dyeing Industrial Complex. A commercial plant for re-circulation of wastewater from Papermill Company is also designed for S-paper Co. in Cheongwon City, and after the successful installation, up to 80% of wastewater could be re-used in paper producing process. (author)

Mining Upgrades to Reduce Pollution

Science.gov (United States)

Settlement with Southern Coal Corporation and 26 affiliates requires the companies to comprehensively upgrade their coal mining and processing operations to prevent polluted wastewater from threatening rivers and streams and communities across Appalachia.

Characterization of Missouri surface waters near point sources of pollution reveals potential novel atmospheric route of exposure for bisphenol A and wastewater hormonal activity pattern

Science.gov (United States)

Kassotis, Christopher D.; Alvarez, David A.; Taylor, Julia A.; vom Saal, Frederick S.; Nagel, Susan C.; Tillitt, Donald E.

2015-01-01

Surface water contamination by chemical pollutants increasingly threatens water quality around the world. Among the many contaminants found in surface water, there is growing concern regarding endocrine disrupting chemicals, based on their ability to interfere with some aspect of hormone action in exposed organisms, including humans. This study assessed water quality at several sites across Missouri (near wastewater treatment plants and airborne release sites of bisphenol A) based on hormone receptor activation potencies and chemical concentrationspresent in the surface water. We hypothesized that bisphenol A and ethinylestradiol would be greater in water near permitted airborne release sites and wastewater treatment plant inputs, respectively, and that these two compounds would be responsible for the majority of activities in receptor-based assays conducted with water collected near these sites. Concentrations of bisphenol A and ethinylestradiol were compared to observed receptor activities using authentic standards to assess contribution to total activities, and quantitation of a comprehensive set of wastewater compounds was performed to better characterize each site. Bisphenol A concentrations were found to be elevated in surface water near permitted airborne release sites, raising questions that airborne releases of BPA may influence nearby surface water contamination and may represent a previously underestimated source to the environment and potential for human exposure. Estrogen and androgen receptor activities of surface water samples were predictive of wastewater input, although the lower sensitivity of the ethinylestradiol ELISA relative to the very high sensitivity of the bioassay approaches did not allow a direct comparison. Wastewater-influenced sites also had elevated anti-estrogenic and anti-androgenic equivalence, while sites without wastewater discharges exhibited no antagonist activities.

Characterization of Missouri surface waters near point sources of pollution reveals potential novel atmospheric route of exposure for bisphenol A and wastewater hormonal activity pattern.

Science.gov (United States)

Kassotis, Christopher D; Alvarez, David A; Taylor, Julia A; vom Saal, Frederick S; Nagel, Susan C; Tillitt, Donald E

2015-08-15

Surface water contamination by chemical pollutants increasingly threatens water quality around the world. Among the many contaminants found in surface water, there is growing concern regarding endocrine disrupting chemicals, based on their ability to interfere with some aspect of hormone action in exposed organisms, including humans. This study assessed water quality at several sites across Missouri (near wastewater treatment plants and airborne release sites of bisphenol A) based on hormone receptor activation potencies and chemical concentrations present in the surface water. We hypothesized that bisphenol A and ethinylestradiol would be greater in water near permitted airborne release sites and wastewater treatment plant inputs, respectively, and that these two compounds would be responsible for the majority of activities in receptor-based assays conducted with water collected near these sites. Concentrations of bisphenol A and ethinylestradiol were compared to observed receptor activities using authentic standards to assess contribution to total activities, and quantitation of a comprehensive set of wastewater compounds was performed to better characterize each site. Bisphenol A concentrations were found to be elevated in surface water near permitted airborne release sites, raising questions that airborne releases of BPA may influence nearby surface water contamination and may represent a previously underestimated source to the environment and potential for human exposure. Estrogen and androgen receptor activities of surface water samples were predictive of wastewater input, although the lower sensitivity of the ethinylestradiol ELISA relative to the very high sensitivity of the bioassay approaches did not allow a direct comparison. Wastewater-influenced sites also had elevated anti-estrogenic and anti-androgenic equivalence, while sites without wastewater discharges exhibited no antagonist activities. Published by Elsevier B.V.

Anaerobic degradation of the various fractions of slaughterhouse wastewater

Energy Technology Data Exchange (ETDEWEB)

Sayed, S.; Zanden, J. van der; Wijffels, R.; Lettinga, G.

1988-01-01

The main objectives of the present investigations were to determine the maximum extent of anaerobic biological degradation of the soluble, colloidal and Coarse Suspended Solids fractions of slaughterhouse wastewater, in order to elucidate the mechanisms involved in the removal of these organic pollutant fractions and to determine the rate-limiting steps in the degradation of each fraction of the wastewater, and to assess the effects of the fractions on the methanogenic activity of the sludge.

Environmental and public health implications of wastewater quality

African Journals Online (AJOL)

user

2011-03-28

Mar 28, 2011 ... metals are one of the most persistent pollutants in waste- water. Unlike organic ... nitrate levels that affect infants do not pose a direct threat to older children ...... Rybicki S (1997). Advanced Wastewater Treatment: Phosphorus.

Optimization of Dye Removal from Textile Wastewater using ...

African Journals Online (AJOL)

OLUWASOGO

however, this often gets polluted through the activities of man ... study examines the treatment of effluent from a textile industry in Kano ... II. MATERIALS AND METHODS. A. Materials. The textile wastewater used in this research was collected.

The Value of Decentralisation in Wastewater Management: Gauteng Province Case Study, South Africa

Directory of Open Access Journals (Sweden)

Cornelius Chris Reynders

2012-07-01

Full Text Available In a semi-arid water scarce country like South Africa, the efficient use of limited water resources and measures to extend the service value of these resources is a prerequisite for achieving sustainable development. The conventional supply-sided management approach to water supply causes increased wastewater generation with accompanied increased pollution loads requiring higher levels of mitigation environmental pollution. Where disposal of wastewater treatment effluent takes place in rivers and natural water bodies, the lack of adequate natural compensating capacity of such water bodies typically result in severe ecological damage of the aquatic environment. With a shift of emphasis to a sustainable demand side management approach (as opposed to a supply side one, the avoidance of water wastage and high wastewater generation represents both resource conservation and environmental protection friendly approaches and contribute to overall sustainability. The integrated nature of water supply and wastewater management systems require an approach that considers these systems holistically. A new paradigm for water management is therefore needed to ensure that the issues of waste disposal and pollution are dealt with in a sustainable manner taking into account the emerging objectives of modern society for resource conservation and environmental protection. A balance therefore has to be found between the uses of additional fresh water resources as a means of satisfying en ever increasing water demand on the one hand and alternative unconventional resource exploration and employment, without the risk of depletion of natural available fresh water resource flow, irreversible harm to the environment and social and economic constraints. This paper explores wastewater and grey water reuse as unconventional resources in a qualitative manner within this balancing equation. It further proposes a methodology for deriving monetary indicator values for wastewater

Does wastewater discharge have relations with increase of Turner syndrome and Down syndrome?

Science.gov (United States)

Choi, Intae

2017-01-01

The purpose of this study is to examine whether water and air pollutants have a relationship with an increase in the genetic disorders Turner syndrome and Down syndrome, which are caused by congenital chromosomal abnormalities, and to generate a hypothesis about the genetic health effects of environmental pollutants. A panel regression based on random effect was conducted on Korea's metropolitan councils from 2012 to 2014. The dependent variable was the number of Turner syndrome and Down syndrome cases, and the main independent variables were those regarding the water and air pollution. Air pollutants did not have a significant impact on the number of Turner syndrome and Down syndrome cases; however, the increase in number of wastewater discharge companies did have a significant relationship with the number of cases. The more the number of wastewater discharge companies, the more the number Turner syndrome and Down syndrome cases were observed. Therefore, scientific investigation on water and air pollutants in relation with genetic health effects needs to be performed.

Frontiers International Conference on Wastewater Treatment

CERN Document Server

2017-01-01

This book describes the latest research advances, innovations, and applications in the field of water management and environmental engineering as presented by leading researchers, engineers, life scientists and practitioners from around the world at the Frontiers International Conference on Wastewater Treatment (FICWTM), held in Palermo, Italy in May 2017. The topics covered are highly diverse and include the physical processes of mixing and dispersion, biological developments and mathematical modeling, such as computational fluid dynamics in wastewater, MBBR and hybrid systems, membrane bioreactors, anaerobic digestion, reduction of greenhouse gases from wastewater treatment plants, and energy optimization. The contributions amply demonstrate that the application of cost-effective technologies for waste treatment and control is urgently needed so as to implement appropriate regulatory measures that ensure pollution prevention and remediation, safeguard public health, and preserve the environment. The contrib...

Amoco-US Environmental Protection Agency, pollution prevention project, Yorktown, Virginia: Surface water data

International Nuclear Information System (INIS)

Baloo, S.

1991-08-01

The report summarizes the surface water sampling program at the Amoco Refinery at Yorktown, Virginia. This was undertaken as a part of the joint project between Amoco Corporation and the United States Environmental Protection Agency to review pollution prevention alternatives at a petroleum refinery. The surface water data provides a snapshot of surface water pollutant generation and discharge from the refinery. Different process units contribute to the total wastewater flow of 460 GPM in the refinery. Water in the ditch system, which is non-process water, is free of organic contamination. Oil and grease, phenols, ammonia and sulfides are the significant components measured in the process wastewater. The concentrations of organics in most water streams leaving the individual process units are relatively low, in the 1-5 parts per million (ppm) range. A few individual streams such as the crude desalter brine and tank water draws have high pollutant loadings. Concentrations of metals in the refinery wastewater are very low. The wastewater treatment plant is very effective in reducing the pollutant loading in the water with overall removal efficiencies greater than 99% for most organics and inorganics

40 CFR 63.1433 - Wastewater provisions.

Science.gov (United States)

2010-07-01

... for Hazardous Air Pollutant Emissions for Polyether Polyols Production § 63.1433 Wastewater provisions... operation of the treatment process or control technique, the owner or operator shall instead comply with the... calibration gas for Method 25A, 40 CFR part 60, appendix A shall be the single organic HAP representing the...

PHOTO-CATALYST DEGRADATION OF TARTRAZINE COMPOUND IN WASTEWATER USING TiO2 AND UV LIGHT

Directory of Open Access Journals (Sweden)

SALAM K. AL-DAWERY

2013-12-01

Full Text Available Organic contaminants present in industrial wastewater are of major concern with respect to the health of the general public. Photo-catalytic process, one of the Advanced Oxidation Processes, is a promising technology for remediation of organic pollutants at ambient conditions. Photo-catalytic processes in the presence of TiO2 provide an interesting method to destroy hazardous organic contaminants. The experimental results showed that considerable degradation of Tartrazine organic compound has been achieved by combination of TiO2 and UV light, the process followed first order kinetics. The results showed that the increased level of TiO2 concentration does not necessarily increase the rate of degradation of organic compounds. Also, it was found that the higher the TiO2 concentrations the higher the pH values and more oscillatory behaviors were observed. Not much effect has been noted on the process due to temperature variation.

Efficient treatment of aniline containing wastewater in bipolar membrane microbial electrolysis cell-Fenton system.

Science.gov (United States)

Li, Xiaohu; Jin, Xiangdan; Zhao, Nannan; Angelidaki, Irini; Zhang, Yifeng

2017-08-01

Aniline-containing wastewater can cause significant environmental problems and threaten the humans's life. However, rapid degradation of aniline with cost-efficient methods remains a challenge. In this work, a novel microbial electrolysis cell with bipolar membrane was integrated with Fenton reaction (MEC-Fenton) for efficient treatment of real wastewater containing a high concentration (4460 ± 52 mg L -1 ) of aniline. In this system, H 2 O 2 was in situ electro-synthesized from O 2 reduction on the graphite cathode and was simultaneously used as source of OH for the oxidation of aniline wastewater under an acidic condition maintained by the bipolar membrane. The aniline was effectively degraded following first-order kinetics at a rate constant of 0.0166 h -1 under an applied voltage of 0.5 V. Meanwhile, a total organic carbon (TOC) removal efficiency of 93.1 ± 1.2% was obtained, revealing efficient mineralization of aniline. The applicability of bipolar membrane MEC-Fenton system was successfully demonstrated with actual aniline wastewater. Moreover, energy balance showed that the system could be a promising technology for removal of biorefractory organic pollutants from wastewaters. Copyright © 2017 Elsevier Ltd. All rights reserved.

Rhizofiltration of a Heavy metal (lead) containing wastewater using the wetland plant carex pendula

Energy Technology Data Exchange (ETDEWEB)

Yadav, Brijesh K. [Environmental Hydrogeology Group, Department of Earth Sciences, Faculty of Geosciences, University of Utrecht, Utrecht (Netherlands); Indian Institute of Technology Delhi, Department of Civil Engineering, New Delhi (India); Siebel, Maarten A.; Bruggen, Johan J.A. van [Department of Environmental Resources, UNESCO-IHE Institute for Water Education, Delft (Netherlands)

2011-05-15

Rhizofiltration is a subset technique of phytoremediation which refers to the approach of using plant biomass for removing contaminants, primarily toxic metals, from polluted water. The effective implementation of this in situ remediation technology requires experimental as well as conceptual insight of plant-water interactions that control the extraction of targeted metal from polluted water resources. Therefore, pot and simulation experiments are used in this study to investigate the rhizofiltration of a lead containing wastewater using plants of Carex pendula, a common wetland plant found in Europe. The metal contaminant extraction along with plant growth and water uptake rates from a wastewater having varying Pb concentration is studied experimentally for 2 wk. The temporal distribution of the metal concentration in the wastewater and the accumulated metal in different compartments of C. pendula at the end are analyzed using atomic absorption spectrometry. Parameters of the metal uptake kinetics are deduced experimentally for predicting the metal removal by root biomass. Further, mass balance equations coupled with the characterized metal uptake kinetics are used for simulating the metal partitioning from the wastewater to its accumulation in the plant biomass. The simulated metal content in wastewater and plant biomass is compared with the observed data showing a good agreement with the later. Results show that C. pendula accumulates considerable amounts of lead, particularly in root biomass, and can be considered for the cleanup of lead contaminated wastewaters in combination with proper biomass disposal alternatives. Also, the findings can be used for performing further non-hydroponics experiment to mimic the real wetland conditions more closely. (Copyright copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

Biodegradability enhancement of textile wastewater by electron beam irradiation

International Nuclear Information System (INIS)

Kim, Tak-Hyun; Lee, Jae-Kwang; Lee, Myun-Joo

2007-01-01

Textile wastewater generally contains various pollutants, which can cause problems during biological treatment. Electron beam radiation technology was applied to enhance the biodegradability of textile wastewater for an activated sludge process. The biodegradability (BOD 5 /COD) increased at a 1.0 kGy dose. The biorefractory organic compounds were converted into more easily biodegradable compounds such as organic acids having lower molecular weights. In spite of the short hydraulic retention time (HRT) of the activated sludge process, not only high organic removal efficiencies, but also high microbial activities were achieved. In conclusion, textile wastewater was effectively treated by the combined process of electron beam radiation and an activated sludge process

Purification and treatment of industrial wastewater by electron beam process: it's potential and effectiveness evaluation

International Nuclear Information System (INIS)

Zulkafli Ghazali; Khomsaton Abu Bakar; Ting Teo Ming; Siti Aiasah Hashim; Khairul Zaman Mohd Dahlan

2002-01-01

Demand for water has grown dramatically globally. We have seen how acute is the demand for treated water in Malaysia during dry spell of late. Between 1900 and 1995, water consumption increased by over six times, globally, more than double the rate of population growth. This rapid growth in water demand is due to the increasing reliance on irrigation to achieve food security, the growth of industries, and the increasing use for domestic purposes. Given the seriousness of the situation and future risk of crises, there is an urgent need to develop the water-efficient technologies including economical treatment methods of wastewater and polluted water. Electron beam treatment (E-Beam treatment) is a comparatively new method of wastewater purification. E-beam treatment is also an environment-friendly approach for the cleanup of contaminated groundwater and industrial wastewater. E-beam treatment treats multi-components waste streams and does not require any hazardous chemical additives nor does it create any secondary wastes. It uses fast formation of short-lived reactive particles, which are capable of efficient decomposition of pollutants inside wastewater. This paper highlights the practical treatment of wastewater using E-Beam method that gives essential conveniences and advantages of the followings: - strongest reducing and oxidizing agents; - universality and interchangeability of redox agents; - variety of paths for pollutant conversion; - process controllability; - wide choice of equipment and technological regimes; - compatibility with conventional methods. (Author)

Wastewater Treatment in Greenland

DEFF Research Database (Denmark)

Gunnarsdottir, Ragnhildur

treatment in these regions. However, designing, constructing and operating wastewater collection systems in the Arctic is challenging because of e.g. permafrost conditions, hard rock surfaces, freezing, limited quantity of water and high costs of electricity, fuel and transportation, as well as a settlement...... or water saving toilets. This opens up for co-treatment of organic waste fractions. Freezing and thawing has also been recognised as being a cost-effective wastewater treatment method in cold regions. Thus it was chosen to concentrate on the effect of the mentioned processes, namely freezing, anaerobic...... spreading of nutrients, diseases and potential pollution issues. Due to the above mentioned challenges alternative treatment methods are needed, especially in small and remotely located communities. Decentralized solutions are well suited for Greenland. Ideal solutions should reduce the need for expensive...

Characterization of Wastewaters obtained from Hatay Tanneries

Directory of Open Access Journals (Sweden)

Şana Sungur

2017-06-01

Full Text Available The leather tanning industry is one of the most significant pollutants in terms of both conventional and toxic parameters. On the other hand, leather industry has an important economic role both in Turkey and in the World. In this study, wastewater samples were taken from 15 different tanneries in the Hatay Region. Wastewaters obtained from liming process and chromium tanning process was analyzed. Sulfide, chromium (III, chromium (VI, oil and grease, total suspended solids (TSS, organic matters, biochemical oxygen demand (BOD, chemical oxygen demand (COD, pH and alkalinity were determined according to Turkish Standard Methods. The determined averages values belong to wastewaters obtained from liming process were as following: pH 11.71; COD 16821 mg L-1; BOD 4357 mg L-1; TSS 39023 mg L-1; oil and grease 364 mg L-1; S-2 concentration 802 mg L-1; alkalinity 2115 mg L-1. The determined averages values belong to wastewaters obtained from chromium tanning process were also as following: pH 4.23; COD 6740 mg L-1; BOD 377 mg L-1; Cr+3 concentrations 372 mg L-1; Cr+6 concentrations 127 mg L-1; TSS 14553 mg L-1; oil and grease 343 mg L-1. The results of all analyzes were higher than wastewater discharge standards. As a result, it’s necessary to use more effective treatments in order to reduce the negative impacts of leather tanning industry that affect environment, natural water resources and at last human health and welfare.

Radiation-induced degradation of organic pollutants in wastewater

International Nuclear Information System (INIS)

Bagyo, A.N.M.; Lindu, W.A.; Sadjirun, S.; Winarno, E.K.; Widayat, E.; Aryanti; Winarno, H.

2001-01-01

The degradation and decolouration of organic pollutants, i.e. dye stuffs and phenolic compounds, by gamma irradiation have been studied. First, samples from effluent of textile industry were taken to be irradiated at a certain condition. Irradiation was done after dissolving the samples five times with distilled water in laboratory scale, followed by upscaling those samples into 5 litre in volume. Irradiation was done at a dose of 0- 25 kGy, aerated and a dose rate of 5 kGy/h. The parameters examined were the change of absorption spectra. COD (Chemical Oxygen Demand), the percentage of the degradation, the change of pH and degradation product using HPLC. It was demonstrated that the dilution of sample enhanced the degradation and decreased the COD values. The degradation product of textile wastewater is mainly oxalic acid. Second, the effects of radiation on aerated phenolic compounds mixture, i.e. resorcinol, o-cresol and m- cresol were done. Individual phenol was studied followed by mixture of the phenolic compounds. Irradiation was done in aerated condition with doses of 0-10 kGy, dose rate of 5 kGy/h and pH range from 3 to 12. The initial concentration of resorcinol, o-cresol and w-cresol were 50 ppm and 60 ppm for phenolic compounds mixture, respectively. Parameters examined were absorption spectrum, pH, and degradation products. The uv-vis absorption of the solution were observed before and after irradiation. HPLC was used to determine the products of degradation. Degradation of resorcinol, w-cresol and o-cresol could be achieved at dose of 6 kGy at pH 9, while o-cresol in acid condition (pH 3). The degree of degradation for resorcinol, w-cresol and o-cresol at above conditions were 90%, 88% and 45%, respectively. Degradation of phenolic compound mixture occurred at a dose of 7.5 kGy and pH 9', at this condition almost 99% of phenolic compounds degraded. Oxalic acid was the main degradation product. (author)

Hauled liquid waste as a pollutant of soils and waters in Poland

Directory of Open Access Journals (Sweden)

Karczmarczyk Agnieszka

2016-06-01

Full Text Available Hauled liquid waste as a pollutant of soils and waters in Poland. Improperly maintained holding tanks are often underestimated source of contamination of soil, groundwater and surface water. As a rule, wastewater stored in holding tanks, should be transported and treated in municipal wastewater treatment plants (WWTPs. There are 2,257,000 holding tanks in Poland, located mainly in rural areas. The article presents the results of analysis of wastewater management in 20 rural and urban-rural communes, which were chosen at random from the total number of 2,174 communes in Poland. The only criterion of commune selection was total or partial lack of sewerage system. Analysis of the collected data showed that on average only 27% of liquid waste from holding tanks ended at the WWTPs. The median is even lower and amounts to 17.5%. More than 4,000 Mg of P and 26,000 Mg of N is dispersed in the environment in uncontrolled manner. Those diffuse point sources of pollution may be one of the reasons in the difficulty of achieving of good ecological status of rivers and affect the quality of the Baltic Sea.

Oxidation of Mixed Active Pharmaceutical Ingredients in Biologically Treated Wastewater by ClO2

DEFF Research Database (Denmark)

Moradas, Gerly; Fick, Jerker; Ledin, Anna

2011-01-01

Biologically treated wastewater containing a mixture of 53 active pharmaceutical ingredients (APIs)was treated with 0-20 mg/l chlorine dioxide (ClO2) solution. Wastewater effluents were taken from two wastewater treatment plants in Sweden, one with (low COD) and one without (high COD) extended...... removed at 5 mg/l ClO2 dose. Removal of the same APIs from the high COD effluent was observed when the ClO2 dose was increased to 1.25 mg/l and an increase in API removal only after treatment with 8 mg/l ClO2. This illustrates that treatment of wastewater effluents with chlorine dioxide has potential...

The color removal and fate of organic pollutants in a pilot-scale MBR-NF combined process treating textile wastewater with high water recovery.

Science.gov (United States)

Li, Kun; Jiang, Chao; Wang, Jianxing; Wei, Yuansong

2016-01-01

A combination of membrane bioreactor (MBR) and nanofiltration (NF) was tested at pilot-scale treating textile wastewater from the wastewater treatment station of a textile mill in Wuqing District of Tianjin (China). The MBR-NF process showed a much better treatment efficiency on the removal of the chemical oxygen demand, total organic carbon, color and turbidity in comparison with the conventional processes. The water recovery rate was enhanced to over 90% through the recycling of NF concentrate to the MBR, while the MBR-NF showed a stable permeate water quality that met with standards and could be directly discharged or further reused. The recycled NF concentrate caused an accumulation of refractory compounds in the MBR, which significantly influenced the treatment efficiency of the MBR. However, the sludge characteristics showed that the activated sludge activity was not obviously inhibited. The results of fluorescence spectra and molecular weight distribution indicated that those recalcitrant pollutants were mostly protein-like substances and a small amount of humic acid-like substances (650-6,000 Da), which contributed to membrane fouling of NF. Although the penetrated protein-like substances caused the residual color in NF permeate, the MBR-NF process was suitable for the advanced treatment and reclamation of textile wastewater under high water yield.

The application of ionising radiation in industrial wastewater treatment technology

Energy Technology Data Exchange (ETDEWEB)

Kos, L. [Inst. of Knitting Technology and Techniques, Lodz (Poland); Perkowski, J. [Inst. of Applied Radiation Chemistry, Technical Univ. of Lodz, Lodz (Poland); Ledakowicz, S. [Dept. of Bioprocess Engineering, Technical Univ. of Lodz, Lodz (Poland)

2003-07-01

An attempt was made to apply radiation techniques in the treatment of industrial wastewater from a dairy, brewery and sugar factory. For degradation of pollutants present in the wastewater, the following methods were used: irradiation, irradiation combined with aeration, ozonation, and combined irradiation and ozonation. For all three types of wastewater, the best method among these listed above appeared to be the method of irradiation combined with ozonation. Most degradable was the wastewater produced in sugar factories, and the least biodegradable appeared to be dairy wastewater. Depending on the dose of ozone and radiation, a maximum 60% reduction of COD was obtained. No effect of the wastewater aeration on its degradation by radiation was found. Changes in the content of mineral compounds were observed in none of the cases. The process of biological treatment of wastewater was carried out in a low-loaded, wetted bed. Pretreatment of the wastewater had no significant effect on the improvement of the biological step operation. Some effect was observed only in the case of the wastewater coming from a sugar factory. For medium concentrated wastewater from food industry, it is not economically justified to apply the pretreatment with the use of ionising radiation. (orig.)

Polyacrylamide+Al{sub 2}(SO{sub 4}){sub 3} and polyacrylamide+CaO remove coliform bacteria and nutrients from swine wastewater

Energy Technology Data Exchange (ETDEWEB)

Entry, J.A.; Phillips, Ian; Stratton, Helen; Sojka, R.E

2003-03-01

Polyacrylamide mixture may be able to reduce run-off of enteric bacteria from animal wastes. - Animal wastes are a major contributor of nutrients and enteric microorganisms to surface water and ground water. Polyacrylamide (PAM) mixtures are an effective flocculent, and we hypothesized that they would reduce transport of microorganisms in flowing water. After waste water running at 60.0 l min{sup -1} flowed over PAM+Al{sub 2}(SO{sub 4}){sub 3}, or PAM+CaO in furrows, total coliform bacteria (TC) and fecal coliform bacteria (FC) were reduced by 30-50% at 1 and 50 m downstream of the treatments compared to the control. In a column study, PAM+Al{sub 2}(SO{sub 4}){sub 3}, and PAM+CaO applied to sandy, sandy loam, loam, and clay soils reduced NH{sub 4}{sup +} and ortho-P concentrations in leachate compared to the source waste water and the control. PAM+Al{sub 2}(SO{sub 4}){sub 3} and PAM+CaO applied to sandy, sandy loam and loam soils reduced both total and ortho-P, concentrations in leachate compared to the source wastewater and control treatment. In a field study, PAM+Al{sub 2}(SO{sub 4}){sub 3}, or PAM+CaO treatments did not consistently reduce NH{sub 4}{sup +}, NO{sub 3}{sup -}, ortho-P, and total P concentrations in wastewater flowing over any soil compared to inflow wastewater or the control treatment. With proper application PAM+ Al{sub 2}(SO{sub 4}){sub 3} and PAM+CaO may be able to reduce the numbers of enteric bacteria in slowly flowing wastewater running off animal confinement areas, reducing the amount of pollutants entering surface water and groundwater.

Water Pollution Prediction in the Three Gorges Reservoir Area and Countermeasures for Sustainable Development of the Water Environment.

Science.gov (United States)

Li, Yinghui; Huang, Shuaijin; Qu, Xuexin

2017-10-27

The Three Gorges Project was implemented in 1994 to promote sustainable water resource use and development of the water environment in the Three Gorges Reservoir Area (hereafter "Reservoir Area"). However, massive discharge of wastewater along the river threatens these goals; therefore, this study employs a grey prediction model (GM) to predict the annual emissions of primary pollution sources, including industrial wastewater, domestic wastewater, and oily and domestic wastewater from ships, that influence the Three Gorges Reservoir Area water environment. First, we optimize the initial values of a traditional GM (1,1) model, and build a new GM (1,1) model that minimizes the sum of squares of the relative simulation errors. Second, we use the new GM (1,1) model to simulate historical annual emissions data for the four pollution sources and thereby test the effectiveness of the model. Third, we predict the annual emissions of the four pollution sources in the Three Gorges Reservoir Area for a future period. The prediction results reveal the annual emission trends for the major wastewater types, and indicate the primary sources of water pollution in the Three Gorges Reservoir Area. Based on our predictions, we suggest several countermeasures against water pollution and towards the sustainable development of the water environment in the Three Gorges Reservoir Area.

Presence and distribution of organic wastewater compounds in wastewater, surface, ground, and drinking waters, Minnesota, 2000-02

Science.gov (United States)

Lee, Kathy E.; Barber, Larry B.; Furlong, Edward T.; Cahill, Jeffery D.; Kolpin, Dana W.; Meyer, Michael T.; Zaugg, Steven D.

2004-01-01

Selected organic wastewater compounds (OWCs) such as household, industrial, and agricultural-use compounds, pharmaceuticals, antibiotics, and sterols and hormones were measured at 65 sites in Minnesota as part of a cooperative study among the Minnesota Department of Health, Minnesota Pollution Control Agency, and the U.S. Geological Survey. Samples were collected in Minnesota during October 2000 through November 2002 and analyzed for the presence and distribution of 91 OWCs at sites including wastewater treatment plant influent and effluent; landfill and feedlot lagoon leachate; surface water; ground water (underlying sewered and unsewered mixed urban land use, a waste dump, and feedlots); and the intake and finished drinking water from drinking water facilities.

Assessing the ecological long-term impact of wastewater irrigation on soil and water based on bioassays and chemical analyses.

Science.gov (United States)

Richter, Elisabeth; Hecht, Fabian; Schnellbacher, Nadine; Ternes, Thomas A; Wick, Arne; Wode, Florian; Coors, Anja

2015-11-01

The reuse of treated wastewater for irrigation and groundwater recharge can counteract water scarcity and reduce pollution of surface waters, but assessing its environmental risk should likewise consider effects associated to the soil. The present study therefore aimed at determining the impact of wastewater irrigation on the habitat quality of water after soil passage and of soil after percolation by applying bioassays and chemical analysis. Lab-scale columns of four different soils encompassing standard European soil and three field soils of varying characteristics and pre-contamination were continuously percolated with treated wastewater to simulate long-term irrigation. Wastewater and its percolates were tested for immobilization of Daphnia magna and growth inhibition of green algae (Pseudokirchneriella subcapitata) and water lentils (Lemna minor). The observed phytotoxicity of the treated wastewater was mostly reduced by soil passage, but in some percolates also increased for green algae. Chemical analysis covering an extensive set of wastewater-born organic pollutants demonstrated that many of them were considerably reduced by soil passage, particularly through peaty soils. Taken together, these results indicated that wastewater-born phytotoxic substances may be removed by soil passage, while existing soil pollutants (e.g. metals) may leach and impair percolate quality. Soils with and without wastewater irrigation were tested for growth of plants (Avena sativa, Brassica napus) and soil bacteria (Arthrobacter globiformis) and reproduction of collembolans (Folsomia candida) and oligochaetes (Enchytraeus crypticus, Eisenia fetida). The habitat quality of the standard and two field soils appeared to be deteriorated by wastewater percolation for at least one organism (enchytraeids, plants or bacteria), while for two pre-contaminated field soils it also was improved (for plants and/or enchytraeids). Wastewater percolation did not seem to raise soil concentrations

Determination of total Cr in wastewaters of Cr electroplating factories in the I.organize industry region (Kayseri, Turkey) by ICP-AES.

Science.gov (United States)

Yilmaz, Selehattin; Türe, Melike; Sadikoglu, Murat; Duran, Ali

2010-08-01

The wastewater pollution in industrial areas is one of the most important environmental problems. Heavy metal pollution, especially chromium pollution in the wastewater sources from electroplating, dyeing, and tannery, has affected the life on earth. This pollution can affect on all ecosystems and human health directly or by food chain. Therefore, the determination of total chromium in this study is of great importance. In this study, accurate, rapid, sensitive, selective, simple, and low-cost technique for the direct determination of total Cr in wastewater samples collected from the some Cr electroplating factories in March 2008 by inductively coupled plasma-atomic emission spectrometry has been developed. The analysis of a given sample is completed in about 15 min by this technique applied. As the result of the chromium analysis, the limit of quantification for the total Cr were founded to be over the limit value (0.05 mg L(-1); WHO, EPA, TSE 266, and inland water quality classification) as 1,898.78+/-0.34 mg/L at station 1 and 3,189.02+/-0.56 mg/L at station 2. The found concentration of total Cr has been determined to be IV class quality water according to the inland water classification. In order to validate the applied method, recovery studies were performed.

Application of aragonite shells for the removal of aqueous metals in polluted soils and wastewaters.

Science.gov (United States)

Bucca, M.; Köhler, S. J.; Dietzel, M.

2009-04-01

In the present study the use of coupled precipitation/dissolution processes for metal (Me) removal from polluted soils and waters by biogenic carbonate (CaCO3) shell surfaces is proposed, according to the following overall reaction: CaCO3 + Me2+ = MeCO3 + Ca2+ This reaction has been investigated at fixed experimental conditions using synthetic model systems consisting in columns, batch, and reactors (e.g. lead, zinc, and cadmium artificial solutions mixed with aragonite shells) that allowed quantifying the kinetics of the process of metal carbonate formation. The above mentioned process has the potential of being used in three different areas of water treatment: a) use of shells as a cheap and effective geologic barrier for contaminated ground or surface waters, b) use as a material in filter beds or fluidized bed for selective cleaning of waste water with the potential of partial metal recovery and c) use as seed crystals during the elimination of metals through precipitation with soda (Na2CO3). Acidic wastewaters containing several pollutants, including heavy and trace metals, are created during production of pesticides, paper, lubricating oil, batteries, acid/alkali, or in ship repair manufacturing, mines drainage systems, metalworking and metal plating industries. Biogenic shells are a waste product in many coastal countries and may thus be more favorable than other solid phases such as clays or zeolithes from an economic viewpoint. Our metal elimination study aims at setting up a low-cost effective elimination system for various types of metal rich waste waters. A number of experimental techniques such as batch, column and flow through reactors were used to optimize the metal removal efficiency in both synthetic and waste waters from the metal finishing industry. Solid liquid ratio, initial and final pH, metal concentration and combination of metals have been varied. Measurements of pH, metal concentration, conductivity and alkalinity were recorded over the

Treatment of municipal wastewater treatment plant effluents with modified photo-Fenton as a tertiary treatment for the degradation of micro pollutants and disinfection.

Science.gov (United States)

Klamerth, Nikolaus; Malato, Sixto; Agüera, Ana; Fernández-Alba, Amadeo; Mailhot, Gilles

2012-03-06

The goal of this paper was to develop a modified photo-Fenton treatment able to degrade micro pollutants in municipal wastewater treatment plant (MWTP) effluents at a neutral pH with minimal iron and H(2)O(2) concentrations. Complexation of Fe by ethylenediamine-N,N'-disuccinic acid (EDDS) leads to stabilization and solubilization of Fe at natural pH. Photo-Fenton experiments were performed in a pilot compound parabolic collector (CPC) solar plant. Samples were treated with solid phase extraction (SPE) and analyzed by HPLC-Qtrap-MS. The rapid degradation of contaminants within the first minutes of illumination and the low detrimental impact on degradation of bicarbonates present in the water suggested that radical species other than HO(•) are responsible for the efficiency of such photo-Fenton process. Disinfection of MWTP effluents by the same process showed promising results, although disinfection was not complete.

Soil Chemistry after Irrigation with Treated Wastewater in Semiarid Climate

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Pedro Carlos Pacheco de Oliveira

2016-01-01

Full Text Available ABSTRACT Soil irrigation using treated wastewater in the Brazilian semiarid region is a promising practice as this area currently faces water scarcity and pollution of water resources by domestic sewage. The aim of this study was to evaluate the use of treated wastewater in drip irrigation and its effect on the chemistry of soil cultivated with squash (Cucurbita maxima Duch. Coroa IAC and to verify whether there was an increase in soil salinity under a semiarid climate. The experiment was conducted for 123 days on a farm close to the sewage treatment plant, in a randomized block design with five treatments and four replications. The treatments consisted of two irrigation water depths (100 and 150 % of the evapotranspiration, two applications of gypsum to attenuate wastewater sodicity (0 and 5.51 g per plant, and a control treatment with no application of wastewater or gypsum. During the experiment, treated wastewater and soil gravitational water, at a depth of 0.40 m, were collected for measurement of Na+, K+, Ca2+, Mg2+, NO−3, NH4+, Cl− , alkalinity, electrical conductivity, pH and sodium adsorption ratio. At the end of the experiment, soil samples were collected at depths of 0.00-0.10, 0.10-0.20, and 0.20-0.40 m; and pH, total N, organic C, exchangeable cations and electrical conductivity of the saturation extract (CEs were analyzed. Besides an increase in pH and a reduction in total N, the irrigation with wastewater reduces soil salinity of the naturally salt-rich soils of the semiarid climate. It also led to soil sodification, in spite of the added gypsum, which indicates that irrigation with wastewater might require the addition of greater quantities of gypsum to prevent physical degradation of the soil.

Review of Hosein Aabad Sugar Factory (HASF) Wastewater and ...

African Journals Online (AJOL)

MICHAEL HORSFALL

evaluate the quality and quantity of wastewater of the said factory and to estimate the pollution ... appropriate for artificial recharge use, discharge in rivers and lakes or utilization in agriculture ..... These problems have a negative impact on.

Identification of significant pressures and assessment of wastewater discharge on Krivaja River water quality

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Pešić Vesna Z.

2017-01-01

Full Text Available One of the key stages of the process of preparing management plans for the river basin is the analysis of pressures and impacts, as well as the risk assessment of failing to achieve the environmental objectives. DPSIR framework (Driving Forces-Pressure-State-Impact-Response was developed by the European Agency for the environmental protection, and makes the conceptual basis for the pressures and impacts analysis, taking into account the complexity of the interactions in the environment and represents the tool for their analysis. Impact assessment of the water body requires some quantitative information to describe the condition of the water body and/or the pressures that act on it. The aim of the study was to determine the effect of wastewater discharge on Krivaja watercourse. Impact assessment is carried out based on data of polluters’ wastewater and monitoring information for water in Krivaja. For each site at which sampling was performed, the specific risk quotients for surface water were calculated, as the ratio of the each pollutant concentration in surface water at the sampling point and environmental quality standards for pollutants, as well as their sum that represents the risk index. In order to have the integrated perceive of processes in the Krivaja River, taking into account cumulative effects from point sources, the concept of total maximum daily load was applied, using which the pollution amount, that can be discharged daily in a water body without degrading his prescribed/required quality, was calculated. Comparison of emitted loads from pollution point sources with maximum allowable ones was performed. Wastewaters of different polluters located on Krivaja are, due to insufficient treatment, very loaded with organic matter and nutrients. Krivaja receives daily 1332 m3 of wastewater, 999 kg COD, 722 kg BOD, 144 kg of nitrogen, 4.3 kg of phosphorus and 627 kg of suspended solids. Of the total wastewater volume, the majority (69

Assessment of ground water quality in a fractured aquifer under continue wastewater injection

International Nuclear Information System (INIS)

Carrieri, C.; Masciopinto, C.

2000-01-01

Experimental studies have been carried out in a fractured coastal aquifer of the Salento Region (Nardo' (Le) Italy), subject since 1991 to injection of 12000 m 3 /d of treated municipal wastewater in a natural sink. The analytical parameters of ground water sampled in monitoring wells, have been compared before and after the injection started. The mound of water table (1.5 m), the reduction of seawater extent of 2 km and the spreading of pollutants injected were evaluated by means of mathematical model results. After ten years operation, the volume of the available resource for agricultural and drinking use has been increased, without notable decrease of the pre existent ground water quality. Moreover for preserving such resource from pollution, the mathematical model allowed the standards of wastewater quality for recharge to be identified. Around the sink, a restricted area was also defined with prohibition of withdrawals, to avoid infection and other risks on human health [it

Application of Opuntia ficus-indica in bioremediation of wastewaters. A critical review.

Science.gov (United States)

Nharingo, Tichaona; Moyo, Mambo

2016-01-15

Heavy metal ion, pesticide and dye wastewaters cause severe ecological contamination with conventional treatment methods proving inadequate, unsuccessful or expensive to apply. Several biomaterials have recently been explored for the biosorption and biocoagulation-flocculation of pollutants from wastewaters. In the past 10 years, there has been an extensive research output on the use of biological materials such as agricultural wastes, chitosan, Moringa Oleifera, Eichhornia crassipes, bacteria, algae, Cactus plants etc. in environmental remediation. The present paper reviews the scattered information about the green technology involving Opuntia ficus-indica derived biomaterials in wastewater decontamination. Its characterization, physicochemical compositions, its application in biosorption and flocculation of dyes, pesticides and metallic species focussing on equilibrium, kinetics and thermodynamic properties are reviewed. The main results obtained in the depollution of a variety of contaminated wastewaters using cladodes, fruit pulp and peels mucilage and electrolytes show very high and promising pollutant maximum sorption capacities and removal percentages in the range -125.4-1000 mg/g and 0.31-2251.56 mg/g for the biosorption of dyes and metallic species respectively and removal % ranges of 50-98.7%, 11-93.62% and 17-100% for turbidity, chemical oxygen demand and heavy metals respectively by coagulation-flocculation process. The biomaterials proved to be efficient in pollutant removal that there is need to explore the scaling up of the study from the laboratory scale to community pilot plants and eventually to industrial levels. Copyright © 2015 Elsevier Ltd. All rights reserved.

Removal of Cr, Mn, and Co from textile wastewater by horizontal rotating tubular bioreactor.

Science.gov (United States)

Zeiner, Michaela; Rezić, Tonci; Santek, Bozidar; Rezić, Iva; Hann, Stephan; Stingeder, Gerhard

2012-10-02

Environmental pollution by industrial wastewaters polluted with toxic heavy metals is of great concern. Various guidelines regulate the quality of water released from industrial plants and of surface waters. In wastewater treatment, bioreactors with microbial biofilms are widely used. A horizontal rotating tubular bioreactor (HRTB) is a combination of a thin layer and a biodisc reactor with an interior divided by O-ring shaped partition walls as carriers for microbial biomass. Using a biofilm of heavy metal resistant bacteria in combination with this special design provides various advantages for wastewater treatment proven in a pilot study. In the presented study, the applicability of HRTB for removing metals commonly present in textile wastewaters (chromium, manganese, cobalt) was investigated. Artificial wastewaters with a load of 125 mg/L of each metal underwent the bioreactor treatment. Different process parameters (inflow rate, rotation speed) were applied for optimizing the removal efficiency. Samples were drawn along the bioreactor length for monitoring the metal contents on site by UV-vis spectrometry. The metal uptake of the biomass was determined by ICP-MS after acidic microwave assisted digestion. The maximum removal rates obtained for chromium, manganese, and cobalt were: 100%, 94%, and 69%, respectively.

Development of Polyvinylidene fluoride (PVDF)-ZIF-8 Membrane for Wastewater Treatment

Science.gov (United States)

Ibrahim, N. A.; Wirzal, M. D. H.; Nordin, N. A. H.; Halim, N. S. Abd

2018-04-01

Nowadays, the water shortage problem following the urbanization and increasing pollution of natural water source have increased the awareness to treat wastewater. Membrane filtration is often used in wastewater treatment plants to filter out more residual activated sludge from aeration process in the secondary stage. However, fouling is the main concern due to the fact it can happen to any membrane application. Antifouling properties in membrane can be improved by blending membranes with fillers or additives to make them more hydrophilic. This study aims to improve the antifouling properties in polyvinylidene fluoride (PVDF) membranes while optimizing the loading of Zeolitic imidazolate framework-8 (ZIF-8) fillers; at different loading (2.0 wt. %, 4.0 wt. %, 6.0 wt. %, 8.0 wt. % and 10.0 wt. %). Manual hand-casting of flat sheet membrane was done and the fabricated membranes were tested for their filterability against pure water and domestic wastewater. Both permeability tests showed that PVDF with 8% ZIF-8 membrane was the most permeable with a pure water and wastewater permeability of 150 L/m2.h.bar and 94 L/m2.h.bar, respectively. The pure water permeability of PVDF with 8% ZIF-8 membrane increases for about 130% compared to the pure PVDF membrane. The turbidity test of the initial feed and final permeate of wastewater, PVDF with 8% ZIF-8 membrane also gave out the highest reduction rate at 87%, which is 36% higher than that of pure PVDF membrane. It can be deduced that 8% of ZIF-8 is the ideal loading to PVDF in improving its antifouling properties to be used in domestic wastewater treatment.

Wastewater treatment of chemical laboratory using electro assisted-phytoremediation (EAPR)

Science.gov (United States)

Putra, Rudy Syah; Trahadinata, Gilang Ahmad; Latif, Arif; Solehudin, Mochamad

2017-03-01

The EAPR process using water hyacinth (Eichornia crassipes) on the wastewater treatment of chemical laboratory had been evaluated. The purpose of the EAPR process was to decrease the BOD, COD and heavy metal concentration in the wastewater. The effectiveness of the process on the wastewater treatment was evaluated using COD, BOD, and heavy metal (Pb, Cu) concentration, respectively. The result showed that the EAPR process decrease the COD, BOD, Pb and Cu in the 4 h of EAPR process. Those concentrations were met the water quality standard of class IV according to government regulation No. 82/2001 regarding the water quality management and water pollution control of the Republic of Indonesia.

THE USE OF HALLOYSITE TO REDUCE POLLUTIONS CONCENTRATION IN MUNICIPAL WASTEWATER

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Alicja Machnicka

2016-12-01

Full Text Available One of the methods of municipal wastewater treatment allows the use of biofilters. The study used a bed filled halloysite. In operation of the bed, depending on the hydraulic load, the concentration of phosphate, ammonium and organic matter was reduced. Highest reduction of the concentration PO43- (89% and N – NH4+ (81% in the waste water of the hydraulic load – 0,04 m3/m2h was obtained. The concentration of the organic substrate was reduced by approximately 86%.

Treatment of laundry wastewater by biological and electrocoagulation methods.

Science.gov (United States)

Ramcharan, Terelle; Bissessur, Ajay

2017-01-01

The present study describes an improvement in the current electrocoagulation treatment process and focuses on a comparative study for the clean-up of laundry wastewater (LWW) after each wash and rinse cycle by biological and electrocoagulation treatment methods. For biological treatment, the wastewater was treated with a Bacillus strain of aerobic bacteria especially suited for the degradation of fats, lipids, protein, detergents and hydrocarbons. Treatment of the LWW by electrocoagulation involved the oxidation of aluminium metal upon the application of a controlled voltage which produces various aluminium hydroxy species capable of adsorbing pollutants from the wastewater. The efficiency of the clean-up of LWW using each method was assessed by determination of surfactant concentration, chemical oxygen demand and total dissolved solids. A rapid decrease in surfactant concentration was noted within 0.5 hour of electrocoagulation, whereas a notable decrease in the surfactant concentration was observed only after 12 hour of biological treatment. The rapid generation of aluminium hydroxy species in the electrocoagulation cell allowed adsorption of pollutants at a faster rate when compared to the aerobic degradation of the surfactant; hence a reduced period of time is required for treatment of LWW by electrocoagulation.

Does wastewater discharge have relations with increase of Turner syndrome and Down syndrome?

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Intae Choi

2017-08-01

Full Text Available The purpose of this study is to examine whether water and air pollutants have a relationship with an increase in the genetic disorders Turner syndrome and Down syndrome, which are caused by congenital chromosomal abnormalities, and to generate a hypothesis about the genetic health effects of environmental pollutants. A panel regression based on random effect was conducted on Korea’s metropolitan councils from 2012 to 2014. The dependent variable was the number of Turner syndrome and Down syndrome cases, and the main independent variables were those regarding the water and air pollution. Air pollutants did not have a significant impact on the number of Turner syndrome and Down syndrome cases; however, the increase in number of wastewater discharge companies did have a significant relationship with the number of cases. The more the number of wastewater discharge companies, the more the number Turner syndrome and Down syndrome cases were observed. Therefore, scientific investigation on water and air pollutants in relation with genetic health effects needs to be performed.

Occurrence of bisphenol A in wastewater and wastewater sludge of CUQ treatment plant

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Dipti Prakash Mohapatra

2011-09-01

Full Text Available The identification and quantification of bisphenol A (BPA in wastewater (WW and wastewater sludge (WWS is of major interest to assess the endocrine activity of treated effluent discharged into the environment. BPA is manufactured in high quantities fro its use in adhesives, powder paints, thermal paper and paper coatings among others. Due to the daily use of these products, high concentration of BPA was observed in WW and WWS. BPA was measured in samples from Urban Community of Quebec wastewater treatment plant located in Quebec (Canada using LC-MS/MS method. The results showed that BPA was present in significant quantities (0.07 μg L–1 to 1.68 μg L–1 in wastewater and 0.104 μg g–1 to 0.312 μg g–1 in wastewater sludge in the wastewater treatment plant (WWTP. The treatment plant is efficient (76 % in removal of pollutant from process stream, however, environmentally significant concentrations of 0.41 μg L–1 were still present in the treated effluent. Rheological study established the partitioning of BPA within the treatment plant. This serves as the base to judge the portion of the process stream requiring more treatment for degradation of BPA and also in selection of different treatment methods. Higher BPA concentration was observed in primary and secondary sludge solids (0.36 and 0.24 μg g–1, respectively as compared to their liquid counterpart (0.27 and 0.15 μg L–1, respectively separated by centrifugation. Thus, BPA was present in significant concentrations in the WWTP and mostly partitioned in the solid fraction of sludge (Partition coefficient (Kd for primary, secondary and mixed sludge was 0.013, 0.015 and 0.012, respectively.

Electrolysis of polluting wastes: I - Wastewater from a seasoning freeze-drying industry

OpenAIRE

Angelis, Dejanira F. de; Corso, Carlos R.; Bidoia, Ederio D.; Moraes, Peterson B.; Domingos, Roberto N.; Rocha-Filho, Romeu C.

1998-01-01

Wastewater from a seasoning freeze-drying industry was electrolysed to increase its biodegradability. Stainless-steel electrodes were used at 9.09 A/m², for up to 80 min. Conductivity, pH, biochemical (BOD) and chemical (COD) oxygen demands, Daphnia similis acute toxicity bioassays, and bacteria counting through the plate count agar method were determined after different times of electrolysis. The results (e.g. higher BOD and lower COD) showed that the biodegradability of the wastewater was s...

Phytoremediation of industrial mines wastewater using water hyacinth.

Science.gov (United States)

Saha, Priyanka; Shinde, Omkar; Sarkar, Supriya

2017-01-02

The wastewater at Sukinda chromite mines (SCM) area of Orissa (India) showed high levels of toxic hexavalent chromium (Cr VI). Wastewater from chromium-contaminated mines exhibit potential threats for biotic community in the vicinity. The aim of the present investigation is to develop a suitable phytoremediation technology for the effective removal of toxic hexavalent chromium from mines wastewater. A water hyacinth species Eichhornia crassipes was chosen to remediate the problem of Cr (VI) pollution from wastewater. It has been observed that this plant was able to remove 99.5% Cr (VI) of the processed water of SCM in 15 days. This aquatic plant not only removed hexavalent Cr, but is also capable of reducing total dissolved solids (TDS), biological oxygen demand (BOD), chemical oxygen demand (COD), and other elements of water also. Large-scale experiment was also performed using 100 L of water from SCM and the same removal efficiency was achieved.

Phytoremediation of industrial mines wastewater using water hyacinth

Science.gov (United States)

Saha, Priyanka; Shinde, Omkar; Sarkar, Supriya

2017-01-01

ABSTRACT The wastewater at Sukinda chromite mines (SCM) area of Orissa (India) showed high levels of toxic hexavalent chromium (Cr VI). Wastewater from chromium-contaminated mines exhibit potential threats for biotic community in the vicinity. The aim of the present investigation is to develop a suitable phytoremediation technology for the effective removal of toxic hexavalent chromium from mines wastewater. A water hyacinth species Eichhornia crassipes was chosen to remediate the problem of Cr (VI) pollution from wastewater. It has been observed that this plant was able to remove 99.5% Cr (VI) of the processed water of SCM in 15 days. This aquatic plant not only removed hexavalent Cr, but is also capable of reducing total dissolved solids (TDS), biological oxygen demand (BOD), chemical oxygen demand (COD), and other elements of water also. Large-scale experiment was also performed using 100 L of water from SCM and the same removal efficiency was achieved. PMID:27551860

Effects of pharmaceutical micropollutants on the membrane fouling of a submerged MBR treating municipal wastewater: case of continuous pollution by carbamazepine.

Science.gov (United States)

Li, Chengcheng; Cabassud, Corinne; Reboul, Bernard; Guigui, Christelle

2015-02-01

Membrane bioreactor (MBR) is increasingly used for municipal wastewater treatment and reuse and great concerns have been raised to some emerging trace pollutants found in aquatic environment in the last decade, notably the pharmaceuticals. As a consequence the removal of pharmaceutical micropollutants by MBRs has been extensively investigated. But there is still a lack of knowledge on the effects of the current presence of pharmaceutical micropollutants in domestic wastewaters on MBR fouling. Among the different pharmaceuticals, it was decided to focus on carbamazepine (CBZ), an anti-epileptic drug, because of its occurrence in domestic wastewaters and persistency in biological processes including MBRs. This paper focuses on the effects of continuous carbamazepine pollution on MBR fouling. A continuous introduction of CBZ into the MBR via the feed (about 90 μg L(-1) CBZ in the feed) provoked a TMP jump. It occurred just 1 day after the addition of CBZ in MBR and a significantly higher increase rate of TMP was also observed after 1 day after addition of CBZ in MBR, as compared to that before addition of CBZ. This indicates that the pharmaceutical stress induced by CBZ causes more severe membrane fouling. Addition of CBZ was shown to induce a significant increase of the concentration of proteins in the supernatant at the beginning several days then stabilized to original level whereas no significant change was found for polysaccharides. HPLC-SEC analysis showed that addition of CBZ induced a decrease of 100-1000 kDa protein-like SMPs and a more significant increase of 10-100 kDa protein-like SMPs in the supernatant. Moreover it was found that addition of CBZ in the MBR affected the sludge microbial activities, as a slight inhibition (about 20%) of the exogenous respiration rate was observed. The increased membrane fouling could be related to the change in biomass characteristics and supernatant quality after addition of CBZ in MBR. This study allows also

Microbial Biotreatment of Actual Textile Wastewater in a Continuous Sequential Rice Husk Biofilter and the Microbial Community Involved

Science.gov (United States)

Lindh, Markus V.; Pinhassi, Jarone; Welander, Ulrika

2017-01-01

Textile dying processes often pollute wastewater with recalcitrant azo and anthraquinone dyes. Yet, there is little development of effective and affordable degradation systems for textile wastewater applicable in countries where water technologies remain poor. We determined biodegradation of actual textile wastewater in biofilters containing rice husks by spectrophotometry and liquid chromatography mass spectrometry. The indigenous microflora from the rice husks consistently performed >90% decolorization at a hydraulic retention time of 67 h. Analysis of microbial community composition of bacterial 16S rRNA genes and fungal internal transcribed spacer (ITS) gene fragments in the biofilters revealed a bacterial consortium known to carry azoreductase genes, such as Dysgonomonas, and Pseudomonas and the presence of fungal phylotypes such as Gibberella and Fusarium. Our findings emphasize that rice husk biofilters support a microbial community of both bacteria and fungi with key features for biodegradation of actual textile wastewater. These results suggest that microbial processes can substantially contribute to efficient and reliable degradation of actual textile wastewater. Thus, development of biodegradation systems holds promise for application of affordable wastewater treatment in polluted environments. PMID:28114377

Microbial Biotreatment of Actual Textile Wastewater in a Continuous Sequential Rice Husk Biofilter and the Microbial Community Involved.

Directory of Open Access Journals (Sweden)

Jörgen Forss

Full Text Available Textile dying processes often pollute wastewater with recalcitrant azo and anthraquinone dyes. Yet, there is little development of effective and affordable degradation systems for textile wastewater applicable in countries where water technologies remain poor. We determined biodegradation of actual textile wastewater in biofilters containing rice husks by spectrophotometry and liquid chromatography mass spectrometry. The indigenous microflora from the rice husks consistently performed >90% decolorization at a hydraulic retention time of 67 h. Analysis of microbial community composition of bacterial 16S rRNA genes and fungal internal transcribed spacer (ITS gene fragments in the biofilters revealed a bacterial consortium known to carry azoreductase genes, such as Dysgonomonas, and Pseudomonas and the presence of fungal phylotypes such as Gibberella and Fusarium. Our findings emphasize that rice husk biofilters support a microbial community of both bacteria and fungi with key features for biodegradation of actual textile wastewater. These results suggest that microbial processes can substantially contribute to efficient and reliable degradation of actual textile wastewater. Thus, development of biodegradation systems holds promise for application of affordable wastewater treatment in polluted environments.

Optimizing TOC and COD removal for the biodiesel wastewater by electrocoagulation

Science.gov (United States)

Tanattı, N. Pınar; Şengil, İ. Ayhan; Özdemir, Abdil

2018-05-01

In this study, the chemical oxygen demand (COD) and the total organic carbon content (TOC) in biodiesel wastewater iron and aluminum electrodes arranged in a bipolar position. In the EC of the biodiesel wastewater, the effects of the supporting electrolyte, initial pH, electrolysis time and current density were examined. The results showed that the majority of the pollutants in the biodiesel wastewater were effectively removed when the iron or aluminum electrodes were used as a sacrificial anode. The highest COD and TOC removal efficiencies were successfully obtained with the iron electrode. COD removal efficiencies are 91.74 and 90.94% for iron and aluminum electrode, respectively. In the same way, TOC removal efficiencies were obtained as 91.79 and 91.98% for the iron and aluminum electrodes, respectively, at initial pH of 6, the current density of 0.3226 mA/cm2, NaCl concentration 1 g/L and 1 min of operating time.

Indirect Electrochemical Oxidation with Multi Carbon Electrodes for Restaurant Wastewater Treatment

Directory of Open Access Journals (Sweden)

I Dewa Ketut Sastrawidana

2018-01-01

Full Text Available The removal of organic matter from the restaurant wastewater was investigated using the electrochemical oxida-tion method with multi carbon electrodes in a parallel construction. The degradation process was monitored by the measurement of COD concentration as a function of electrolysis time. The effectof operating parameter conditions on COD removal were investigated including initial pH, distance between electrodes, and the applied voltage difference.The results showed that the treatment of restaurant wastewater containing 2 g/L chloride ion using the electrochemical oxidation technique at the operation conditions characterized by: pH 5, distance between electrode of 10 cm and applied voltage of 12 V, enabled to obtained COD removal of 92.84% within 90 min electrolysis time. It is can be concluded that the indirect electrochemical oxidation method with multi carbon electrodes can be used effectivelyas an alternative technology for reducing COD and may be potentially applied for removal organic pollutants from wastewater at the industrial scale.

Analysis of pollution removal from wastewater by Ceratophyllum ...

African Journals Online (AJOL)

Water is one of the most stable and abundant complexes on nature that can be polluted with natural and human factors. Polluted water is harmful to human health and need to purify. One of the economic and rapid methods for elements removal is displacement of metals by biosorption. Two treatments in four replications for ...

Using single-chamber microbial fuel cells as renewable power sources of electro-Fenton reactors for organic pollutant treatment

International Nuclear Information System (INIS)

Zhu, Xiuping; Logan, Bruce E.

2013-01-01

Highlights: ► A new type of electro-Fenton system was developed for wastewater treatment. ► Degradation efficiency of organic pollutants was substantially improved. ► Operation cost was greatly reduced compared to other microbial fuel cell designs. -- Abstract: Electro-Fenton reactions can be very effective for organic pollutant degradation, but they typically require non-sustainable electrical power to produce hydrogen peroxide. Two-chamber microbial fuel cells (MFCs) have been proposed for pollutant treatment using Fenton-based reactions, but these types of MFCs have low power densities and require expensive membranes. Here, more efficient dual reactor systems were developed using a single-chamber MFC as a low-voltage power source to simultaneously accomplish H 2 O 2 generation and Fe 2+ release for the Fenton reaction. In tests using phenol, 75 ± 2% of the total organic carbon (TOC) was removed in the electro-Fenton reactor in one cycle (22 h), and phenol was completely degraded to simple and readily biodegradable organic acids. Compared to previously developed systems based on two-chamber MFCs, the degradation efficiency of organic pollutants was substantially improved. These results demonstrate that this system is an energy-efficient and cost-effective approach for industrial wastewater treatment of certain pollutants

Water Pollution Prediction in the Three Gorges Reservoir Area and Countermeasures for Sustainable Development of the Water Environment

Directory of Open Access Journals (Sweden)

Yinghui Li

2017-10-01

Full Text Available The Three Gorges Project was implemented in 1994 to promote sustainable water resource use and development of the water environment in the Three Gorges Reservoir Area (hereafter “Reservoir Area”. However, massive discharge of wastewater along the river threatens these goals; therefore, this study employs a grey prediction model (GM to predict the annual emissions of primary pollution sources, including industrial wastewater, domestic wastewater, and oily and domestic wastewater from ships, that influence the Three Gorges Reservoir Area water environment. First, we optimize the initial values of a traditional GM (1,1 model, and build a new GM (1,1 model that minimizes the sum of squares of the relative simulation errors. Second, we use the new GM (1,1 model to simulate historical annual emissions data for the four pollution sources and thereby test the effectiveness of the model. Third, we predict the annual emissions of the four pollution sources in the Three Gorges Reservoir Area for a future period. The prediction results reveal the annual emission trends for the major wastewater types, and indicate the primary sources of water pollution in the Three Gorges Reservoir Area. Based on our predictions, we suggest several countermeasures against water pollution and towards the sustainable development of the water environment in the Three Gorges Reservoir Area.

Water Pollution Prediction in the Three Gorges Reservoir Area and Countermeasures for Sustainable Development of the Water Environment

Science.gov (United States)

Huang, Shuaijin; Qu, Xuexin

2017-01-01

The Three Gorges Project was implemented in 1994 to promote sustainable water resource use and development of the water environment in the Three Gorges Reservoir Area (hereafter “Reservoir Area”). However, massive discharge of wastewater along the river threatens these goals; therefore, this study employs a grey prediction model (GM) to predict the annual emissions of primary pollution sources, including industrial wastewater, domestic wastewater, and oily and domestic wastewater from ships, that influence the Three Gorges Reservoir Area water environment. First, we optimize the initial values of a traditional GM (1,1) model, and build a new GM (1,1) model that minimizes the sum of squares of the relative simulation errors. Second, we use the new GM (1,1) model to simulate historical annual emissions data for the four pollution sources and thereby test the effectiveness of the model. Third, we predict the annual emissions of the four pollution sources in the Three Gorges Reservoir Area for a future period. The prediction results reveal the annual emission trends for the major wastewater types, and indicate the primary sources of water pollution in the Three Gorges Reservoir Area. Based on our predictions, we suggest several countermeasures against water pollution and towards the sustainable development of the water environment in the Three Gorges Reservoir Area. PMID:29077006

Response surface modeling for optimization heterocatalytic Fenton oxidation of persistence organic pollution in high total dissolved solid containing wastewater.

Science.gov (United States)

Sekaran, G; Karthikeyan, S; Boopathy, R; Maharaja, P; Gupta, V K; Anandan, C

2014-01-01

The rice-husk-based mesoporous activated carbon (MAC) used in this study was precarbonized and activated using phosphoric acid. N2 adsorption/desorption isotherm, X-ray powder diffraction, electron spin resonance, X-ray photoelectron spectroscopy and scanning electron microscopy, transmission electron microscopy, (29)Si-NMR spectroscopy, and diffuse reflectance spectroscopy were used to characterize the MAC. The tannery wastewater carrying high total dissolved solids (TDS) discharged from leather industry lacks biodegradability despite the presence of dissolved protein. This paper demonstrates the application of free electron-rich MAC as heterogeneous catalyst along with Fenton reagent for the oxidation of persistence organic compounds in high TDS wastewater. The heterogeneous Fenton oxidation of the pretreated wastewater at optimum pH (3.5), H2O2 (4 mmol/L), FeSO4[Symbol: see text]7H2O (0.2 mmol/L), and time (4 h) removed chemical oxygen demand, biochemical oxygen demand, total organic carbon and dissolved protein by 86, 91, 83, and 90%, respectively.

Woody biomass production in a spray irrigation wastewater treatment facility in North Carolina

International Nuclear Information System (INIS)

Frederick, D.; Lea, R.; Milosh, R.

1993-01-01

Application of municipal wastewater to deciduous tree plantations offers a viable opportunity to dispose of nutrients and pollutants, while protecting water quality. Production of woody biomass for energy or pulp mill furnish, using wastewater if feasible and markets exist in may parts of the world for this biomass. Plantations of sycamore (Platanus occidentalis L.), and sweetgum (Liquidambar styraciflua L.), have been established in Edenton, North Carolina for application of municipal wastewater. Research describing the dry weight biomass following the fifth year of seedling growth is presented along with future estimates for seedling and coppice yields. Ongoing and future work for estimating nutrient assimilation and wastewater renovation are described and discussed

Wastewater purification. Combined electron-beam and ozone action in the aerosol flow

International Nuclear Information System (INIS)

Podzorova, E.A.; Pikaev, A.K.

1998-01-01

Complete text of publication follows. Ozone is forming with high enough radiation chemical yield during work of electron accelerator. It is useful to use oxidizing properties of ozone with combination of ionizing radiation. The combined action of ionized radiation and ozone on aqueous solutions increases efficiency of water purification. But at the same time, this kind process of water purification is characterized by some limited stages: 1. Ozone mass transfer rate from gaseous phase (where it is formed) into liquid phase (where pollutants present); 2. Small solubility ozone in water; 3. High rate constant of radiation induced decomposition of ozone. We have proposed some optimizations for this kind of process. The most effective action of ionized radiation and radiolytic ozone on polluted water is running this process in aerosol flow. The highly developed surface of phase division is provided the maximum rate of reaction of ozone with pollutants. The volatile pollutants react with radiolytic ozone in gaseous phase in ozone creation moment. Ozonoradiolysis of real municipal wastewater in an aerosol flow was investigated on a facility with electron accelerator with electron energy E=0,3 MeV, power up to 15 kWatt, productivity 500 m 3 /day. Density of the irradiated aerosol was 0,02-0,05 g/cm 3 . It is increase low-energy electron range on 1-2 orders of magnitude as compared with liquid water and increases effective depth of uniformed irradiated layer. Because aerosol density is much higher compare with air density, it is clear, that water drops in aerosol flow absorbed main energy. The treated municipal wastewater in this facility was cleaned from organic and inorganic pollutants. COD and BOD values were reduced. Water disinfecting is achieved to sanitary standards

Environmental systems analysis of wastewater management

International Nuclear Information System (INIS)

Kaerrman, Erik

2000-01-01

relation to those from the society a whole. Further analysis of the four system structures described above gave the basis for formulation of four strategies for less environmental impact and less resource usage of wastewater management: 1) Handle nutrient-rich flows separately from other waste flows, 2) Recycle nutrients and use energy efficiently, 3) Avoid contamination of wastewater flows and 4) Put unavoidable pollution on landfill

Ultraviolet and solar photocatalytic ozonation of municipal wastewater: Catalyst reuse, energy requirements and toxicity assessment.

Science.gov (United States)

Mecha, Achisa C; Onyango, Maurice S; Ochieng, Aoyi; Momba, Maggy N B

2017-11-01

The present study evaluated the treatment of municipal wastewater containing phenol using solar and ultraviolet (UV) light photocatalytic ozonation processes to explore comparative performance. Important aspects such as catalyst reuse, mineralization of pollutants, energy requirements, and toxicity of treated wastewater which are crucial for practical implementation of the processes were explored. The activity of the photocatalysts did not change significantly even after three consecutive uses despite approximately 2% of the initial quantity of catalyst being lost in each run. Analysis of the change in average oxidation state (AOS) demonstrated the formation of more oxidized degradation products (ΔAOS values of 1.0-1.7) due to mineralization. The energy requirements were determined in terms of electrical energy per order (E EO ) and the collector area per order (A CO ). The E EO (kWh m -3  Order -1 ) values were 26.2 for ozonation, 38-47 for UV photocatalysis and 7-22 for UV photocatalytic ozonation processes. On the other hand, A CO (m 2  m -3  order -1 ) values were 31-69 for solar photocatalysis and 8-13 for solar photocatalytic ozonation. Thus photocatalytic ozonation processes required less energy input compared to the individual processes. The cytotoxicity of the wastewater was analysed using the 3-(4, 5-dimethylthiazol-2-yl)-2, 5-diphenyltetrazolium bromide (MTT) assay with Vero cells. The cell viability increased from 28.7% in untreated wastewater to 80% in treated wastewater; thus showing that the treated wastewater was less toxic. The effectiveness of photocatalytic ozonation, recovery and reusability of the photocatalysts, as well as detoxification of the wastewater make this low energy consumption process attractive for wastewater remediation. Copyright © 2017 Elsevier Ltd. All rights reserved.

Conventional pollution, emerging pollutants and priority substances in Spanish's public sewage network

International Nuclear Information System (INIS)

Marin Galvin, R.; Ripolles Pascual, F.; Santateresa Forcada, E.; Lahora Cano, A.; Mantecon Pascual, R.; Rodriguez Amaro, R.

2009-01-01

Spanish's waste water shoes a conventional pollution, and increased DQO values. Contains several organic and inorganic compounds. For domestic wastewater this situation imply to apply measures of control from the origin and another of environmental education. While WWTP investigated obtain high yielding in treatment of metals, HPA, VOC and alquilphenols, the behaviour versus plaguicides, thin-organic compounds and other organic is more un-favourable. Several substances overpasses the values established in the E-PRTR normative, so in the next future could be experience problems to fulfil the normative about this subject, as well as those related to reuse of treated wastewater and bio-solids generated in the WWP. (Author) 9 refs.

ADVANCED OXIDATION PROCESSES FOR FOOD INDUSTRIAL WASTEWATER DECONTAMINATION

Directory of Open Access Journals (Sweden)

Dorota Krzemińska

2015-02-01

Full Text Available High organic matter content is a basic problem in food industry wastewaters. Typically, the amount and composition of the effluent varies considerably. In the article four groups of advanced processes and their combination of food industry wastewater treatment have been reviewed: electrochemical oxidation (EC, Fenton’s process, ozonation of water and photocatalytic processes. All advanced oxidation processes (AOP`s are characterized by a common chemical feature: the capability of exploiting high reactivity of HO• radicals in driving oxidation processes which are suitable for achieving decolonization and odour reduction, and the complete mineralization or increase of bioavailability of recalcitrant organic pollutants.

NPDES Permit for Soap Creek Associates Wastewater Treatment Facility in Montana

Science.gov (United States)

Under National Pollutant Discharge Elimination System permit number MT-0023183, Soap Creek Associates, Inc. is authorized to discharge from its wastewater treatment facility located in West, Bighorn County, Montana, to Soap Creek.

Semi-industrial production of methane from textile wastewaters

Energy Technology Data Exchange (ETDEWEB)

Opwis, Klaus; Mayer-Gall, Thomas; Gutmann, Jochen S. [Deutsches Textilforschungszentrum Nord-West e.V., Krefeld (DE)] (and others)

2012-12-15

The enzymatic desizing of starch-sized cotton fabrics leads to wastewaters with an extremely high chemical oxygen demand due to its high sugar content. Nowadays, these liquors are still disposed without use, resulting in a questionable ecological pollution and high emission charges for cotton finishing manufacturers. In this paper, an innovative technology for the production of energy from textile wastewaters from cotton desizing was developed. Such desizing liquors were fermented by methane-producing microbes to biogas. For this purpose, a semi-industrial plant with a total volume of more than 500 L was developed and employed over a period of several weeks. The robust and trouble-free system produces high amounts of biogas accompanied by a significant reduction of the COD of more than 85%. With regard to growing standards and costs for wastewater treatment and disposal, the new process can be an attractive alternative for textile finishing enterprises in wastewater management, combining economic and ecological benefits. Moreover, the production of biogas from textile wastewaters can help to overcome the global energy gap within the next decades, especially with respect to the huge dimension of cotton pretreatment and, therefore, huge desizing activities worldwide.

General assessment of estuarine pollution

Indian Academy of Sciences (India)

First page Back Continue Last page Overview Graphics. General assessment of estuarine pollution. Contamination of estuaries by untreated domestic wastewater is widespread, however, in absence of time-series studies the responses of native flora and fauna to modified environment are unclear. Agricultural runoff ...

Inventing Wastewater: The Social and Scientific Construction of Effluent in the Northeastern United States

Science.gov (United States)

Brideau, J. M.; Ng, M.; Hoover, J. H.; Hale, R. L.; Thomas, B.; Vogel, R. M.; Northeast ConsortiumHydrologic Synthesis Summer Institute, 2010--Biogeochemistry

2010-12-01

Title: Inventing Wastewater: The Social and Scientific Construction of Effluent in the Northeastern United States Authors: Jeffrey Brideau, Melissa Ng, Joseph Hoover, Rebecca Hale, Brian Thomas, and Richard Vogel Presented by: Jeffrey Brideau B.A., M.A., PhD Candidate, Department of History, University of Maryland Regulation of pollution is a prevalent part of contemporary American society. Scientists and policy makers have established acceptable effluent thresholds, with the ostensible goal of protecting human and stream health. However, this ubiquity of regulation is a recent phenomenon, and institutional mechanisms for effluent control were virtually non-existent in the early 20th century. Nonetheless, these same decades witnessed the emergence of nascent efforts at water pollution abatement. This project aims to explore social and scientific perceptions of wastewater, and begins with the simple premise that socio-cultural values underlay human decision-making in water management, and that wastewater is imbued with a matrix of human values that are continuously renegotiated. So what were the primary motivations for abatement efforts? Were they aesthetic and olfactory, or scientific concern for public and stream health? This paper proposes that there are social as well as scientific thresholds for pollutant loads. Collaborating with a team of interdisciplinary researchers we have created and aggregated discrete data sets to model, using export coefficient and linear regression modeling techniques, historic pollutant loading in the Northeastern United States. Concurrently, we have drawn on historical narratives of agitation by abatement advocates, nuisance laws, regulatory regimes, and changing scientific understanding; and contrasting the modeling results with these narratives allows this project to quantitatively determine where social thresholds lay in relation to their scientific counterparts. This project’s novelty lies in its use of existing narratives of

Cross-Comparison of Human Wastewater-Associated Molecular Markers in Relation to Fecal Indicator Bacteria and Enteric Viruses in Recreational Beach Waters.

Science.gov (United States)

Hughes, B; Beale, D J; Dennis, P G; Cook, S; Ahmed, W

2017-04-15

Detection of human wastewater contamination in recreational waters is of critical importance to regulators due to the risks posed to public health. To identify such risks, human wastewater-associated microbial source tracking (MST) markers have been developed. At present, however, a greater understanding of the suitability of these markers for the detection of diluted human wastewater in environmental waters is necessary to predict risk. Here, we compared the process limit of detection (PLOD) and process limit of quantification (PLOQ) of six human wastewater-associated MST markers ( Bacteroides HF183 [HF183], Escherichia coli H8 [EC H8], Methanobrevibacter smithii nifH , human adenovirus [HAdV], human polyomavirus [HPyV], and pepper mild mottle virus [PMMoV]) in relation to a fecal indicator bacterium (FIB), Enterococcus sp. 23S rRNA (ENT 23S), and three enteric viruses (human adenovirus serotypes 40/41 [HAdV 40/41], human norovirus [HNoV], and human enterovirus [EV]) in beach water samples seeded with raw and secondary-treated wastewater. Among the six MST markers tested, HF183 was the most sensitive measure of human fecal pollution and was quantifiable up to dilutions of 10 -6 and 10 -4 for beach water samples seeded with raw and secondary-treated wastewater, respectively. Other markers and enteric viruses were detected at various dilutions (10 -1 to 10 -5 ). These MST markers, FIB, and enteric viruses were then quantified in beach water ( n = 12) and sand samples ( n = 12) from South East Queensland (SEQ), Australia, to estimate the levels of human fecal pollution. Of the 12 sites examined, beach water and sand samples from several sites had quantifiable concentrations of HF183 and PMMoV markers. Overall, our results indicate that while HF183 is the most sensitive measure of human fecal pollution, it should be used in conjunction with a conferring viral marker to avoid overestimating the risk of gastrointestinal illness. IMPORTANCE MST is an effective tool to

Heterogeneity of the environmental regulation of industrial wastewater: European wineries.

Science.gov (United States)

Román-Sánchez, Isabel M; Aznar-Sánchez, José A; Belmonte-Ureña, Luis J

2015-01-01

The European legislation of the pollution of industrial wastewater shows a high degree of heterogeneity. This fact implies that there is a market failure with relevant consequences. Within the European Union, each Member State performs a specific transposition of the Water Framework Directive 2000/60. The member states introduce different sanitation fees to correct water pollution. In this paper, the case of the European wine industry is analyzed. It studies the sanitation fees of the five major wine producing countries: France, Italy, Spain, Germany and Portugal. Results show significant differences among the wastewater fees and the study reveals how such heterogeneity leads to relevant market distortions. The research concludes that more homogeneous environmental regulation would promote more sustainable wine production processes with more efficient water management and purification systems, as well as the introduction of cutting edge technologies.

Radiation degradation of aromatic pollutants exit in wastewater and ph dependence

International Nuclear Information System (INIS)

Takriti, S.

2002-12-01

The effect of gamma radiation on the degradation of phenol (hydroxybenzene), resorcinol (1,3 dihydroxybenzen) and hydroquinone (1,4 dihydroxybenzen) exit in waste water was investigated. The concentrations of these pollutants as well as the irradiated solution ph were studied. The results showed that the phenol is very resistance against the radiation doses comparing the other phenol compounds. Phenol was also a product of radiolysis of resorcinol and hydroquinone. On the other hand, the acid phase of the irradiation sample increased the degradation rate of pollutants. Spectrophotometer (UV-VIS) and chromatography (HPLC) were used to monitor the analysis of the radiation product solution. The results illustrated the existing of many substances such as organic alcohol, aldehyde, ketone and acidic functional groups as a final radiation products. The degradation of benzene, monochlorobenzene (CB) and 1,2 dichlorobenzene (1,2 DCB) exit in waste water by gamma irradiation was investigated. The effect of the irradiated solution composition was studied. The results showed that the benzene is very resistance against the radiation doses comparing to other chlorobenzene. However, the existence of oxidizing substances in the irradiation phase leads to increase the degradation rate of pollutants. The dechlorination of CB and 1,2 DCB that is a result of the hydrated electron reaction with studied compounds was observed. Chromatography (HPLC) and spectrophotometer (UV-VIS) were used to monitor the analysis of the radiation product solution. The results illustrated the existing of many species as a final radiation product. On the other, the irradiation phase containing scavengers such as methanol and ethanol requires large doses to decompose the pollutants, while the oxidizing phase accelerates the degradation. (author)

Bioremediation potential of the Sava river water polluted by oil refinery wastewater

International Nuclear Information System (INIS)

Jaksic, B.; Matavulj, M.; Vukic, Lj.; Radnovic, D.

2002-01-01

Microbial enumeration is a screening-level tool which can be used to evaluate in-situ response of water microorganisms to petroleum hydrocarbon contamination as well as for evaluating enhanced bioremediation potential of petroleum hydrocarbon contamination. In this investigations the increase between 17- and 44-fold of number of heterotrophs in hydrocarbon contaminated the Sava River water when compared with the no contaminated river water have been recorded. The significant increase of number of facultative oligotrophs in the river Sava water downstream of wastewater discharge (between 70- and almost 100-fold higher number) direct to the conclusion that oligotrophic bacteria (adapted to the environments with low amount of easy-to-degrade nutrients, oligocarbophilic microorganisms) could be better indicator of water bioremediation potential than number of heterotrophic (THR) bacteria. Quantitative composition of heterotrophic, facultative oligotrophic, crude oil degrading, and other physiological groups of bacteria, being, as a rule, higher in samples taken downstream of the waste-water discharge, testify about high biodegradative potential of the River Sava microbial community, if the oil refinery wastewater is taken into consideration. (author)

Qualitative monitoring of a treated wastewater reuse extensive ...

African Journals Online (AJOL)

2006-01-01

Jan 1, 2006 ... limited and threatened by pollution from various human activi- ties. ... The problem with treated wastewater sampling, which will ... since any alternative solution (such as discharge into the sea) is not permitted, due to the extensive tour- ism. Hersonissos is famous for its crystal-clean sea and beaches.

Use of AOP's to remove paper mill wastewater pollutants

Energy Technology Data Exchange (ETDEWEB)

Amat, A.M.; Arques, A. [Dpto. de Ingenieria Textil y Papelera, EPSA-UPV, Univ. Politecnica de Valencia, Alcoy (Spain); Garcia, C.; Lopez, F. [Dpto. de Ingenieria Quimica y Nuclear, Univ. Politecnica de Valencia, Alcoy (Spain)

2003-07-01

Ozone and UV radiation are aggressive advanced oxidation processes that have been tested to degrade paper mill effluents. Eugenol and guaiacol, models of the lignin fraction of these wastewaters are easily oxidisable by ozone even at low dosages (0.8 g/h). On the other hand, glucose and fatty acids are more difficult to degrade, although the combination O{sub 3}/UV improves the process and important decrease in COD and BOD values were observed. Solar photocatalysis is a milder alternative to O{sub 3}/UV; photo-Fenton reaction and titanium dioxide have been tested. Both methods have been able to degrade the phenolic components of paper wastewaters, but they were not able to oxidise glucose or volatile fatty acids. (orig.)

Tetracycline removal during wastewater treatment in high-rate algal ponds

International Nuclear Information System (INIS)

Godos, Ignacio de; Muñoz, Raúl; Guieysse, Benoit

2012-01-01

Highlights: ► Tetracycline removal was most likely caused by photodegradation and biosorption. ► Tetracycline presence was linked to biomass deflocculation and poor settleability. ► Deflocculation did not impact treatment efficiency. ► Deflocculation may hamper biomass recover during full-scale treatment. - Abstract: With the hypothesis that light supply can impact the removal of veterinary antibiotics during livestock wastewater treatment in high rate algal ponds (HRAPs), this study was undertaken to determine the mechanisms of tetracycline removal in these systems. For this purpose, two HRAPs were fed with synthetic wastewater for 46 days before tetracycline was added at 2 mg L −1 to the influent of one of the reactors (Te-HRAP). From day 62, dissolved tetracycline removal stabilized around 69 ± 1% in the Te-HRAP and evidence from batch assays suggests that this removal was mainly caused by photodegradation and biosorption. Tetracycline addition was followed by the deflocculation of the Te-HRAP biomass but had otherwise no apparent impact on the removal of the chemical oxygen demand (COD) and biomass productivity. The results from the batch assays also suggested that the light-shading and/or pollutant-sequestrating effects of the biomass limited tetracycline removal in the pond. For the first time, these results demonstrate that the shallow geometry of HRAPs is advantageous to support the photodegradation of antibiotics during wastewater biological treatment but that the presence of these pollutants could hamper biomass recovery. These findings have significant implications for algal-based environmental biotechnologies and must be confirmed under field conditions.

A new technology for harnessing the dye polluted water and dye collection in the chemical factory

Institute of Scientific and Technical Information of China (English)

无

2001-01-01

A new technology for harnessing the dye polluted water and dyecollection was developed. It is based on the enhanced evaporation by using solar, wind, and air temperature energy and additional heat-electric energy. It consists of four parts: (1) evaporation carrier system (evaporation carrier and frame for evaporation carrier) for polluted water; (2) polluted water circulating system (pumping-spraying-collecting); (3) heating system; (4) workshop with polluted water reservoir-tanks and rainfall prevention roof. The polluted water was (heated in case necessary) sprayed to the evaporation carrier system and the water was evaporated when it moved in the space and downward along the carrier mainly by using natural (solar, wind, and air temperature energy). In case, when there is no roof for the carrier system, thepolluted water can be stored in the reservoirs (storage volume for about 20 days). The first 10-25 mm rainfall also need to be stored in the reservoirs to meet the state standard for discharging wastewater. The dye may be collected at the surface in the reservoir-tanks and the crystallized salt may be collected at the bottom plate. The black-color wastewater released by the factory is no more discharged to the surface water system of Taihu Lake Basin. About 2 kg dye and 200 kg industrial salt may be collected from each tone of the polluted water. The non-pollution production of dye may be realized by using this technology with environmental, economical and social benefits.

Radiation degradation adsorption treatment of some toxic dyes present in wastewater

International Nuclear Information System (INIS)

Dessouki, A.M.; Hegazy, E.A.; El-Kelesh, N.A.

2000-01-01

The degradation kinetics due to gamma irradiation of aqueous solutions of some organic pollutants (reactive yellow dye, acidic yellow Dye and fast yellow Dye) were investigated. A combined treatment of gamma irradiation and conventional methods was applied and is much more effective than either alone. Factors affecting the radiolysis of the pollutants such as concentration, irradiation dose, dose rate and ph of the solutions was studied. Radiochemical degradation yields were calculated to elucidate the mechanism of the degradation process. Also, the feasibility of using granular activated carbon (GAC), ion exchange resins (Merck I, III, Iv) for the removal of these pollutants from aqueous solution were studied. Synergistic treatment of the dye solutions by irradiation methods showed that the saturation of the dye solutions with nitrogen did not enhance the radiation degradation of the dyes, while addition of O 2 , H 2 O 2 or Na Ocl resulted in remarkable enhancement. Adsorption of the dyes into GAC and some ion-exchangers, showed that GAC has the highest adsorption capacity compared with ion-exchangers. Irradiation followed by adsorption resulted in the removal of these toxic pollutants from wastewater

Radiation degradation adsorption treatment of some toxic dyes present in wastewater

International Nuclear Information System (INIS)

Al-Dousougi, A. M.; Hijarzi, A. A.; Al-Qalash, N. A. A.

2002-01-01

The degradation kinetics due to gamma irradiation of aqueous solutions of some organic pollutants (Reactive Yellow Dye, acidic yellow dye and fast yellow dye) were investigated. A combined treatment of gamma irradiation and conventional methods was applied and is much more effective than either alone. Factors affecting the radiolysis of the pollutants such as concentration, irradiation dose, dose rate, and pH of the solutions was studied. Radiochemical degradation yields were calculated to elucidate the mechanism of the degradation process. Also, the feasibility of using granular Activated carbon (GAC), ion exchange resins (Metck I, II, III, IV) for the removal of these pollutants from aqueous solutions were studied. Synergistic treatment of the dye solutions by irradiation methods showed that the saturation of the dye solutions with nitrogen did not enhance the radiation degradation of the dyes, while addition of O 2 , H 2 O 2 or NaOCI resulted in remarkable enhancement. Adsorption of the dyes onto GAC and some ion-exchangers, showed that GAC has the highest adsorption capacity compared with ion-exchangers. Irradiation followed by adsorption resulted in the removal of these toxic pollutants from wastewater. (author)

Potential chemical and microbiological risks on human health from urban wastewater reuse in agriculture. Case study of wastewater effluents in Spain.

Science.gov (United States)

Muñoz, Ivan; Tomàs, Núria; Mas, Jordi; García-Reyes, Juan Fracisco; Molina-Díaz, Antonio; Fernández-Alba, Amadeo R

2010-05-01

Potential health risks derived from wastewater reuse in agriculture have been evaluated with Risk Assessment modelling techniques, in a case study involving the effluents of two Spanish wastewater treatment plants. One of the plants applies primary and secondary treatment, and the other one applies an additional tertiary treatment. Health risks were assessed on the basis of ingesting contaminated food, due to exposure to: (i) 22 chemical pollutants, namely pharmaceuticals and personal care products (PPCPs), and priority pollutants included in the European Framework Directive, and (ii) microorganisms, namely enterovirus. Chemical Risk Assessment has been carried out following the European Commission's technical guidelines, while risks from exposure to viruses have been evaluated by means of Quantitative Microbial Risk Assessment, assuming a virus to coliform ratio of 1:10(5). The results of the chemical assessment show that there is a margin of safety above 100 for all substances, with the exception of gemfibrozil, for which the mean margin of safety (MOS) is above 100, but the lower bound of MOS with a 95 % confidence interval lies in the 3-4 range. A MOS under 100 was also found for 2,3,7,8-TCDD in one of the effluents. The assessment of risks from viruses shows a very low probability of infection. The overall results show that risks are lower for the plant applying tertiary treatment, especially concerning microbiological parameters.

Ecotoxicity of Wastewater from Medical Facilities: A Review

Directory of Open Access Journals (Sweden)

Cidlinová A.

2018-03-01

Full Text Available Wastewater from medical facilities contains a wide range of chemicals (in particular pharmaceuticals, disinfectants, heavy metals, contrast media, and radionuclides and pathogens, therefore it constitutes a risk to the environment and human health. Many micropollutants are not efficiently eliminated during wastewater treatment and contaminate both surface water and groundwater. As we lack information about the long-term effects of low concentrations of micropollutants in the aquatic environment, it is not possible to rule out their adverse effects on aquatic organisms and human health. It is, therefore, necessary to focus on the evaluation of chronic toxicity in particular when assessing the environmental and health risks and to develop standards for the regulation of hazardous substances in wastewater from medical facilities on the basis of collected data. Wastewater from medical facilities is a complex mixture of many compounds that may have synergetic, antagonistic or additive effects on organisms. To evaluate the influence of a wide range of pollutants contained in the effluents from medical facilities on aquatic ecosystems, it is necessary to determine their ecotoxicity.

Microbial Biotreatment of Actual Textile Wastewater in a Continuous Sequential Rice Husk Biofilter and the Microbial Community Involved

OpenAIRE

Forss, J?rgen; Lindh, Markus V.; Pinhassi, Jarone; Welander, Ulrika

2017-01-01

Textile dying processes often pollute wastewater with recalcitrant azo and anthraquinone dyes. Yet, there is little development of effective and affordable degradation systems for textile wastewater applicable in countries where water technologies remain poor. We determined biodegradation of actual textile wastewater in biofilters containing rice husks by spectrophotometry and liquid chromatography mass spectrometry. The indigenous microflora from the rice husks consistently performed >90% de...

Molasses wastewater treatment and lipid production at low temperature conditions by a microalgal mutant Scenedesmus sp. Z-4

OpenAIRE

Ma, Chao; Wen, Hanquan; Xing, Defeng; Pei, Xuanyuan; Zhu, Jiani; Ren, Nanqi; Liu, Bingfeng

2017-01-01

Background Simultaneous wastewater treatment and lipid production by oleaginous microalgae show great potential to alleviate energy shortage and environmental pollution, because they exhibit tremendous advantages over traditional activated sludge. Currently, most research on wastewater treatment by microalgal are carried out at optimized temperature conditions (25?35??C), but no information about simultaneous wastewater treatment and lipid production by microalgae at low temperatures has been...

Sandia National Laboratories, California Pollution Prevention Program annual report

International Nuclear Information System (INIS)

Harris, Janet S.

2011-01-01

The annual program report provides detailed information about all aspects of the SNL/CA Pollution Prevention Program for a given calendar year. It functions as supporting documentation to the SNL/CA Environmental Management System Program Manual. The program report describes the activities undertaken during the past year, and activities planned in future years to implement the Pollution Prevention Program, one of six programs that supports environmental management at SNL/CA. Pollution Prevention supports the goals and objectives to increase the procurement and use of environmentally friendly products and materials and minimize the generation of waste (nonhazardous, hazardous, radiological, wastewater). Through participation on the Interdisciplinary Team P2 provides guidance for integration of environmentally friendly purchasing and waste minimization requirements into projects during the planning phase. Table 7 presents SNL's corporate objectives and targets that support the elements of the Pollution Prevention program.

Removal Efficiency of Nitrite and Sulfide Pollutants by Electrochemical Process by Using Ti/RuIrO2 Anode

Directory of Open Access Journals (Sweden)

Aris Mukimin

2018-05-01

Full Text Available In general, wastewater treatment by physical, chemical and biological methods are only focused on TSS, BOD and COD removals that the effluent still contains anion pollutant as NO2- and S2-. Electrochemical technology is a proper method for those pollutants treatment due to its fast process, easy operation and minimum amount of sludge. Electrocatalytic reactor with 8 L capacity using Ti/RuIrO2 cylinder as anode and Fe plate as cathode was arranged and applied to treat anion pollutants. Hydraulic retention time (30, 60, 90 and 120 min, salt concentration (250, 500 and 750 mg/L and voltage (4, 5, and 6 V were chosen as operation variables and NO2- and S2- concentrations as parameter indicators. Nitrite removal efficiency reached 75 and 99.7% after 60 and 120 min of electrolysis, respectively, while sulfide could obtain higher efficiency, i.e., 97 and 99.9% after 60 and 90 min, respectively, at operation variables of potential of 5 V and salt of 500 mg/L. Removal process is dominated by indirect oxidation mechanism by HClO/ClO- oxidators generated at anode surface as intermediate products. The lifespan of electrode and electric consumption are two main factors of operation cost. Electric consumed was 0.452 kWh per 1 g nitrite removed.

Enrichment of bio-oil after hydrothermal liquefaction (HTL) of microalgae C. vulgaris grown in wastewater: Bio-char and post HTL wastewater utilization studies.

Science.gov (United States)

Arun, Jayaseelan; Varshini, Padmanabhan; Prithvinath, P Kamath; Priyadarshini, Venkataramani; Gopinath, Kannappan Panchamoorthy

2018-08-01

In this study, bio-oil was produced through hydrothermal liquefaction (HTL) of C. vulgaris biomass cultivated in wastewater and was enriched into transportation fuels. Bio-oil yield was 29.37% wt at 300 °C, 60 min, at 15 g/200 mL biomass loading rate with 3% wt nano ZnO catalyst loading. Applying catalyst reduced oxygen and nitrogen content in bio-oil and increased its calorific value (19.6 ± 0.8 MJ/Kg). Bio-oil was enriched through liquid-liquid extraction (LLE) and higher yield was obtained at 30 °C for dichloromethane solvent (18.2% wt). Compounds of enriched oil were within the petro-diesel range (C 8 -C 21 ). Bio-char after HTL process was activated and used as adsorbent in wastewater treatment process to remove organic pollutants (COD, NO 3 , NH 3 and PO 4 ). Treated wastewater can be supplied as growth medium for microalgae cultivation in further experiments. Nearly 3-4 times the nanocatalyst can be reused in the HTL process. Copyright © 2018 Elsevier Ltd. All rights reserved.

Assessment of dairy wastewater treatment and its potential for ...

African Journals Online (AJOL)

The extent of pollution of dairy wastewater treated in a septic tank and its potential for biogas production was investigated. Performance of the existing treatment system was assessed through characterization of both raw and treated effluents. From the analysis parameters likeChemical Oxygen Demand (COD), Biochemical ...

Design of a neutral electro-Fenton system with Fe-Fe2O3/ACF composite cathode for wastewater treatment

International Nuclear Information System (INIS)

Li Jinpo; Ai Zhihui; Zhang Lizhi

2009-01-01

The narrow pH range limits the wide application of Fenton reaction in the wastewater treatment. It is of great importance to widen working pH range of Fenton reaction from strong acidic condition to neutral, even basic ones. In this study, for the first time nanostructured Fe-Fe 2 O 3 was loaded on active carbon fiber (ACF) as an oxygen diffusion cathode to be used in a heterogeneous electro-Fenton (E-Fenton) oxidation system. This novel Fe-Fe 2 O 3 /ACF composite cathode was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray (EDX) analysis, transmission electron microscopy (TEM), and element mapping. On the degradation of dye pollutant rhodamine B in water, this heterogeneous E-Fenton system with the Fe-Fe 2 O 3 /ACF cathode showed much higher activity than other E-Fenton systems with commercial zero valent iron powders (Fe 0 ) and ferrous ions (Fe 2+ ) under neutral pH. On the basis of experimental results, we proposed a possible pathway of rhodamine B degradation in this heterogeneous Fe-Fe 2 O 3 /ACF E-Fenton process. This heterogeneous E-Fenton system is very promising to remove organic pollutants in water at neutral pH

Research on treatment of wastewater containing heavy metal by microbial fuel cell

Science.gov (United States)

Chen, Zixuan; Lu, Xun; Yin, Ruixia; Luo, Yunyi; Mai, Hanjian; Zhang, Nan; Xiong, Jingfang; Zhang, Hongguo; Tang, Jinfeng; Luo, Dinggui

2018-02-01

With rapid development of social economy, serious problem has been caused by wastewater containing heavy metals, which was difficult to be treated by many kinds of traditional treatment methods, such as complex processes, high cost or easy to cause secondary pollution. As a novel biological treatment technology, microbial fuel cells (MFC) can generate electric energy while dealing with wastewater, which was proposed and extensively studied. This paper introduced the working principle of MFC, the classification of cathode, and the research progress on the treatment of wastewater containing Cr(VI), Cu(II), Ag(I), Mn(II) and Cd(II) by MFC. The study found that different cathode, different heavy metals anddifferent hybrid systems would affect the performance of the system and removal effect for heavy metal in MFC. MFC was a highly potential pollution control technology. Until now, the research was still in the laboratory stage. Its industrial application for recovery of heavy metal ion, improving the energy recovery rate and improvement or innovation of system were worthy of further research.

APPLICATION OF PAN/PANI COMPOSITE MEMBRANES IN PURIFICATION OF INDUSTRIAL WASTEWATER GENERATED DURING PROCESSING OF METALS

Directory of Open Access Journals (Sweden)

Beata Fryczkowska

2017-04-01

Full Text Available The paper presents results of research on the use of composite membranes of polyacrylonitrile (PAN doped polyaniline (PANI to remove contaminations of industrial wastewater generated during the processing of metals. Wastewater obtained from industry was pre-treated with the flocculant Magnafloc®336, and then the supernatant solution was introduced into the ultrafiltration cell, AMICON (Millipore equipped in the previously prepared polymer membrane. Using spectrophotometer UV-Vis (HACH and atomic absorption spectrometry (AAS pollution indicators was marked before and after the integrated purification proces, to determine the degree of removal of selected ions from wastewater. As a result of flocculation from wastewater there have been removed phosphates (79%, chlorides (11-14%, sulfates (2-10% and iron (36-92%, cobalt (~ 80%, cadmium (~ 31% and nickel (~ 25%. However, the pressure membrane process almost completely removed zinc, copper and cadmium (~ 100%, iron (by a further 43-69% and phosphate anions, which was a little.

Tolerance of Myriophyllum aquaticum to exposure of industrial wastewater pretreatment with electrocoagulation and their efficiency in the removal of pollutants.

Science.gov (United States)

Cano-Rodríguez, Claudia Teodora; Roa-Morales, Gabriela; Amaya-Chávez, Araceli; Valdés-Arias, Ricardo Antonio; Barrera-Díaz, Carlos Eduardo; Balderas-Hernández, Patricia

2014-01-01

The wastewater used in this study was obtained from a treatment plant where it mixed with wastewater of 142 industries and was treated using electrocoagulation with iron electrode and phytoremediation with Myriophyllum aquaticum, likewise certain biomarkers of oxidative stress of the plant were evaluated to find out its resistance to contaminant exposure. Electrocoagulation was performed under optimum operating conditions at pH 8 and with a current density of 45.45 A m(-2) to reduce the COD by 42%, color 89% and turbidity 95%; the electrochemical method produces partial elimination of contaminants, though this was improved using phytoremediation. Thus the coupled treatment reduced the COD by 94%, color 97% and turbidity 98%. The exposure of M. aquaticum to electrocoagulated wastewater did not have an effect on the ratio of chlorophyll a/b (2.84 + 0.24); on the activity of SOD, CAT and lipoperoxidation. The results show the potential of M. aquaticum to remove contaminants from pretreated wastewater since the enzymatic system of the plants was not significantly affected.

Degradation of cytotoxic agent in soap and detergent wastewater by advanced oxidation processes

International Nuclear Information System (INIS)

Iqbal, M.; Bhatti, I.A.; Nisar, J.

2017-01-01

Wastewater from soap and detergent industries is a source of high pollution and contamination for water sheds. In present investigation, cytotoxic profiling was documented from Faisalabad, Sargodha and Gujranwala cities, Pakistan, followed by advanced oxidation processes (AOPs) treatments (UV and gamma radiation). The cytotoxicity was evaluated by Allium cepa, haemolytic and brine shrimp bioassays. Independent variables such as gamma radiation absorbed dose, H2O2, TiO2 concentrations, reaction time, pH and shaking speed were optimized using statistical techniques. The raw soap and detergent wastewater showed cytotoxicity up to high extent. At optimized conditions, > 94% degradation was achieved both in case of UV (exposure time 100 min, TiO2 concentration 5.93 g/L, H2O2 4.39%, pH 6.50 and shaking speed 110 rpm) and gamma radiation (12.69 kGy absorbed dose in the presence of 4.65% H2O2) treated samples and water quality parameters (WQP) also improved significantly. The cytotoxicity reduced sharply as a result of AOPs treatment at optimized conditions. From the results, it is evident that AOPs under investigation could be used for the degradation and cytotoxicity reduction of soap and detergent wastewater. (author)

Regulating industrial wastewater discharged to public wastewater treatment plants - A conceptual approach

DEFF Research Database (Denmark)

Grüttner, Henrik

1997-01-01

The paper describes some of the basic principles behind the DEPA Guidelines for discharge of industrial wastewater to public sewers set in operation in 1995 and evaluates some of the experiences with the implementation. It is described how such guidelines support the approach of pollution...... prevention and the implementation of cleaner technology by putting a stress on the industry. Further an approach for the balance between environmental and technological considerations is introduced. The need for easily understandable environmental priorities is stressed and a concept for this is presented...

Technology of surface wastewater purification, including high-rise construction areas

Science.gov (United States)

Tsyba, Anna; Skolubovich, Yury

2018-03-01

Despite on the improvements in the quality of high-rise construction areas and industrial wastewater treatment, the pollution of water bodies continues to increase. This is due to the organized and unorganized surface untreated sewage entry into the reservoirs. The qualitative analysis of some cities' surface sewage composition is carried out in the work. Based on the published literature review, the characteristic contamination present in surface wastewater was identified. The paper proposes a new technology for the treatment of surface sewage and presents the results of preliminary studies.

Phthalate esters in the environment: A critical review of their occurrence, biodegradation, and removal during wastewater treatment processes.

Science.gov (United States)

Gao, Da-Wen; Wen, Zhi-Dan

2016-01-15

Phthalate esters are one of the most frequently detected persistent organic pollutants in the environment. A better understanding of their occurrence and degradation in the environment and during wastewater treatment processes will facilitate the development of strategies to reduce these pollutants and to bioremediate contaminated freshwater and soil. Phthalate esters occur at measurable levels in different environments worldwide. For example, the concentrations of dimethyl phthalate (DMP) in atmospheric particulate matter, fresh water and sediments, soil, and landfills are N.D.-10.4 ng/m(3), N.D.-31.7 μg/L, N.D.-316 μg/kg dry weight, and N.D.-200 μg/kg dry weight, N.D.-43.27 μg/L, respectively. Bis(2-ethylhexyl) phthalate (DEHP) and di-n-butyl phthalate (DBP) are primary phthalate ester pollutants. Urbanization has increased the discharge of phthalate esters to atmospheric and aquatic environments, and the use of agricultural plastics has exacerbated soil contamination by phthalate esters in rural areas. Aerobic biodegradation is the primary manner of phthalate ester mineralization in the environment, and this process has been widely studied. Phthalate esters can be removed during wastewater treatment processes. The combination of different wastewater treatment technologies showed greater efficiency in the removal of phthalate esters than individual treatment steps, such as the combination of anaerobic wastewater treatment with a membrane bioreactor would increase the efficiency of phthalate ester removal from 65%-71% to 95%-97%. This review provides a useful framework to identify future research objectives to achieve the mineralization and elimination of phthalate esters in the environment. Copyright © 2015 Elsevier B.V. All rights reserved.

EMISSION OF POLLUTANTS FROM COMBINED SEWER OVERFLOWS IN THE ASPECT OF THEIR IMPACT ON A RECEIVER

Directory of Open Access Journals (Sweden)

Agnieszka Brzezińska

2016-06-01

Full Text Available Increased efficiency of wastewater treatment highlights the role of combined sewer overflows in deterioration the quality of water receiver because pollutant loads discharged by them have a growing share in entire load discharged into a receiver. The article contains the results of the wastewater quality analyzes emitted into the receiver from the three studied combined sewer overflows of the city of Lodz. The results demonstrated a large variations in the pollutant concentration directed to the receiver during rain events. The possible impact of untreated wastewater emitted to the receiver is also presented. Apart from the pollution of the receiver, mainly by organic and nutrient substances, the microbiological contamination which is dangerous for people using the river as a recreation area and for animals that use a water receiver as a source of drinking water, should be taken into particular attention.

Removal of toxic Cr(VI) ions from tannery industrial wastewater using a newly designed three-phase three-dimensional electrode reactor

Science.gov (United States)

Grace Pavithra, K.; Senthil Kumar, P.; Carolin Christopher, Femina; Saravanan, A.

2017-11-01

In this research, the wastewater samples were collected from leather tanning industry at different time intervals. The parameters like pH, electrical conductivity, temperature, turbidity, chromium and chemical oxygen demand (COD) of the samples were analyzed. A three-phase three-dimensional fluidized type electrode reactor (FTER) was newly designed for the effective removal of toxic pollutants from wastewater. The influencing parameters were optimized for the maximum removal of toxic pollutants from wastewater. The optimum condition for the present system was calculated as: contact time of 30 min, applied voltage of 3 V and the particle electrodes of 15 g. The particle electrode was characterized by using FT-IR analysis. Langmuir-Hinshelwood and pseudo-second order kinetic models were fits well with the experimental data. The results showed that the FTER can be successfully employed for the treatment of industrial wastewater.

A Verhulst model for microalgae Botryococcus sp. growth and nutrient removal in wastewater

Science.gov (United States)

Jamaian, Siti Suhana; Bakeri, Noorhadila Mohd; Sunar, Norshuhaila Mohamed; Gani, Paran

2017-08-01

Microalgae Botryococcus sp. is a colonial green alga found in lakes and reservoirs in Malaysia. Previous studies reported that the potential of Botryococcus sp. photosynthesis as a source of fuel. The Botryococcus sp. contains hydrocarbon up to 75% of dry weight, which can be converted into petrol, diesel or turbine fuel or other liquid or gaseous hydrocarbons. Recently, an experimental study was conducted on phycoremediation technology for wastewater using Botryococcus sp. The phycoremediation technology is useful to remove the excess of nutrients such as nitrogen, phosphorus and also have the ability to remove various pollutants from wastewater. This research implements the Verhulst model to estimate the nutrient removal by microalgae Botryococcus sp. from the wastewater. This model has been validated with the experiments of microalgae Botryococcus sp. grown in domestic and palm oil wastewater. The results suggested that microalgae Botryococcus sp. could be cultured in domestic and palm oil wastewater while nutrients are reduced from these wastewaters.

Mixed Wastewater Coupled with CO2 for Microalgae Culturing and Nutrient Removal.

Directory of Open Access Journals (Sweden)

Lili Yao

Full Text Available Biomass, nutrient removal capacity, lipid productivity and morphological changes of Chlorella sorokiniana and Desmodesmus communis were investigated in mixed wastewaters with different CO2 concentrations. Under optimal condition, which was 1:3 ratio of swine wastewater to second treated municipal wastewater with 5% CO2, the maximum biomass concentrations were 1.22 g L-1 and 0.84 g L-1 for C. sorokiniana and D. communis, respectively. Almost all of the ammonia and phosphorus were removed, the removal rates of total nitrogen were 88.05% for C. sorokiniana and 83.18% for D. communis. Lipid content reached 17.04% for C. sorokiniana and 20.37% for D. communis after 10 days culture. CO2 aeration increased intracellular particle numbers of both microalgae and made D. communis tend to be solitary. The research suggested the aeration of CO2 improve the tolerance of microalgae to high concentration of NH4-N, and nutrient excess stress could induce lipid accumulation of microalgae.

Soil aquifer treatment to remove priority organic pollutants in the Llobregat river area

OpenAIRE

Huerta, Maria; Solé, Josep; Aceves, Mercè; Valhondo González, Cristina; Hernández, Marta; Gullón Santos, Martín

2013-01-01

The Llobregat River is the main source of water supply in this area. This river together with its aquifer has suffered from several damages which had contributed to endanger a suitable ecological and hydrological status; among them, pollution is a serious problem to deal with. In the last decades, the presence of organic pollutants in this river has been demonstrated [1,2]. Some of them are persistent to biological degradation and have shown to survive wastewater treatments almost unaltered a...

Textile wastewater treatment: colour and COD removal of reactive black-5 by ozonation

Science.gov (United States)

Suryawan, I. W. K.; Helmy, Q.; Notodarmojo, S.

2018-01-01

Textile industries produced a large amount of highly coloured wastewater containing variety of dyes in different concentrations. Due to the high concentration of organics in the effluents and the higher stability of modern synthetic dyes, the conventional biological treatment methods are ineffective for the complete colour removal and degradation of organics and dyes. On the other hand, physical-chemical treatment are not destructive, mainly just concentrate and separate the pollutants phases. This research paper investigates the removal of colour and chemical oxygen demand/COD from textile wastewater using ozone treatment. Varied ozone dosages of 1.16; 3.81; 18.79; and 40.88 mg/minute were used in the experiment. Varied wastewater containing Reactive Black 5 (RB-5) concentrations of 40 mg/L, 100 mg/L were also applied. Research result showed the highest colour removal efficiency of 96.9 % was achieved after 5 hours incubation time, while the highest COD removal efficiency of 77.5% was achieved after 2 hours incubation time.

Diagnosis Report Gouda Wastewater Monitoring Network The Netherlands

NARCIS (Netherlands)

Vélez, C.; Popescu, I.; Lobbrecht, A.; Galvis, A.; Cardona, D.A.; Mosquera, P.A.

2008-01-01

Urban pollution managers are being forced to optimize the control of Urban Wastewater Systems (UWwS) in order to deal with more pressure and new criteria for performance. Furthermore, one of the main causes of the deficient control of the UWwSs is the lack of data in each subsystem and the lack of

Winery wastewater treatment by a combined process: long term aerated storage and Fenton's reagent.

Science.gov (United States)

Lucas, Marco S; Mouta, Maria; Pirra, António; Peres, José A

2009-01-01

The degradation of the organic pollutants present in winery wastewater was carried out by the combination of two successive steps: an aerobic biological process followed by a chemical oxidation process using Fenton's reagent. The main goal of this study was to evaluate the temporal characteristics of solids and chemical oxygen demand (COD) present in winery wastewater in a long term aerated storage bioreactor. The performance of different air dosage daily supplied to the biologic reactor, in laboratory and pilot scale, were examined. The long term hydraulic retention time, 11 weeks, contributed remarkably to the reduction of COD (about 90%) and the combination with the Fenton's reagent led to a high overall COD reduction that reached 99.5% when the mass ratio (R = H(2)O(2)/COD) used was equal to 2.5, maintaining constant the molar ratio H(2)O(2)/Fe(2+)=15.