WorldWideScience

Sample records for waste incinerator ash

  1. Possibilities of municipal solid waste incinerator fly ash utilisation.

    Science.gov (United States)

    Hartmann, Silvie; Koval, Lukáš; Škrobánková, Hana; Matýsek, Dalibor; Winter, Franz; Purgar, Amon

    2015-08-01

    Properties of the waste treatment residual fly ash generated from municipal solid waste incinerator fly ash were investigated in this study. Six different mortar blends with the addition of the municipal solid waste incinerator fly ash were evaluated. The Portland cement replacement levels of the municipal solid waste incinerator fly ash used were 25%, 30% and 50%. Both, raw and washed municipal solid waste incinerator fly ash samples were examined. According to the mineralogical composition measurements, a 22.6% increase in the pozzolanic/hydraulic properties was observed for the washed municipal solid waste incinerator fly ash sample. The maximum replacement level of 25% for the washed municipal solid waste incinerator fly ash in mortar blends was established in order to preserve the compressive strength properties. Moreover, the leaching characteristics of the crushed mortar blend was analysed in order to examine the immobilisation of its hazardous contents. © The Author(s) 2015.

  2. Study on solidification for municipal solid waste incineration fly ash

    Energy Technology Data Exchange (ETDEWEB)

    Lu, C.; Liu, Q.; Yang, J.; Xi, W. [Chongqing Univ., Chongqing (China); Huang, B. [Southwest Petroleum Univ., Chengdu (China)

    2008-07-01

    The appropriate management of municipal solid waste (MSW) is a major environmental issues, despite the significant efforts to prevent, reduce, reuse and recycle waste. Two primary options can be used for managing MSW incineration fly ash. These are landfill disposal or incineration. Incineration is effective in toxic substance destruction, waste volume reduction and energy recovery, as compared with landfill. MSW fly ash generally contains higher content of easily leachable heavy metals such as lead, cadmium, and zinc. In China, source separation of municipal solid wastes is not well practiced and has resulted in high concentrations of heavy metals being detected in the MSW fly ash. This paper presented a preliminary study to examine the properties of MSW fly ash and the fixing abilities of ordinary Portland cement and hydrated time on heavy metals. The paper discussed the effects of experimental parameters on the properties of solidified fly ash and the optimal technology conditions. The fly ash used in the study was collected from solid waste incineration plants in Shenzhen, Shanghai, and Chongqing, China. It was concluded that the effect on solidification got better and the leaching quantities of heavy metals such as zinc, lead, cadmium, or chromium decreased with the addition of cement used as adhesive. The optimal proportion of cement was 8 per cent. 14 refs., 5 tabs., 2 figs.

  3. Speciation of Chromium in Bottom Ash Obtained by the Incineration of the Leather Waste Shavings

    OpenAIRE

    k. louhab; H. Assas

    2006-01-01

    The evolution of bottom ash morphology and chromium metals behavior during incineration of a leather waste shavings at different incineration temperature have been studied. The Cr, Ca, Mg, Cl rates in bottom ashes, flay ashes and emitted gases in different incineration temperature of the tannery wastes are also determined. The morphology of the bottom ashes obtained by incineration at different temperature from the leather waste shavings was examined by MEB. The result sho...

  4. Smelting disposal of municipal solid waste incineration fly ash

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Q.; Lu, C.; Yang, J. [Chongqing Univ., Chongqing (China); Huang, B. [Southwest Petroleum Univ., Chengdu Sichuan (China)

    2008-07-01

    Municipal solid waste (MSW) fly ash contains a significant amount of heavy metals which must be treated safely as it has a negative impact on the environment and the sustainable development of cities. The primary disposal methods used around the world are landfilling and incineration. In China, the most widely used treatment methods of MSW are open-air stacking and landfill disposal due to protected research on incineration. This paper explored the technology of the smelting operation process. It discussed the proportion of hydrated lime in the process of solidification and the effect of temperature on the separation rate of heavy metals in fly ash. The paper described the experiment and presented the physical and chemical properties of fly ash. The leaching toxicities of heavy metals in fly ash were also displayed in table format. The melting separation process of MSW incineration fly ash was discussed with particular reference to the solidification of fly ash and melting separation technology for heavy metals. It was concluded that it was feasible to use the smelting separation technology for disposal of MSW incineration fly ash as it could eliminate pollution due to heavy metals and dioxins, reduce secondary pollution, and recycle many of the heavy metals present. 9 refs., 3 tabs., 3 figs.

  5. Thermal behaviour of ESP ash from municipal solid waste incinerators.

    Science.gov (United States)

    Yang, Y; Xiao, Y; Wilson, N; Voncken, J H L

    2009-07-15

    Stricter environmental regulations demand safer treatment and disposal of incinerator fly ashes. So far no sound technology or a process is available for a sustainable and ecological treatment of the waste incineration ashes, and only partial treatment is practised for temporary and short-term solutions. New processes and technology need to be developed for comprehensive utilization and detoxification of the municipal solid waste (MSW) incinerator residues. To explore the efficiency of thermal stabilisation and controlled vitrification, the thermal behaviour of electrostatic precipitator (ESP) ash was investigated under controlled conditions. The reaction stages are identified with the initial moisture removal, volatilization, melting and slag formation. At the temperature higher than 1100 degrees C, the ESP ashes have a quicker weight loss, and the total weight loss reaches up to 52%, higher than the boiler ash. At 1400 degrees C a salt layer and a homogeneous glassy slag were formed. The effect of thermal treatment on the leaching characteristics of various elements in the ESP ash was evaluated with the availability-leaching test. The leaching values of the vitrified slag are significantly lowered than that of the original ash.

  6. Electrodialytic upgrading of municipal waste incineration fly ash for reuse

    DEFF Research Database (Denmark)

    Jensen, Pernille Erland; Kirkelund, Gunvor Marie; Ottosen, Lisbeth M.

    2012-01-01

    content of water soluble, mobile salts and heavy metals. It was shown that the mobility of salts and toxic elements can be significantly reduced by extraction with electrodialysis in stack [1, 2]; and that treated MSWI fly ash may potentially be utilized as a substitute for cement in concrete [3......As incineration becomes a more widespread means of waste treatment, volumes of incineration residues increase and new means of handling become a demand. Municipal Solid Waste Incineration (MSWI) fly ash is hazardous material, which is presently disposed off as such; primarily due to its high...... to investigate the leachability of salts and toxic elements as a function of treatment time and current density. Results show that a delicate balance between pH and treatment-time exist and that continuous monitoring of pH and conductivity may be used for controlling of the process at an industrial scale...

  7. Pretreatment and utilization of waste incineration bottom ashes

    DEFF Research Database (Denmark)

    Astrup, Thomas

    2007-01-01

    , however, have had a strong emphasis on lab experiments with little focus on full scale bottom ash upgrading methods. The introduction of regulatory limit values restricting leaching from utilized bottom ashes, has created a need for a better understanding of how lab scale experiences can be utilized....../aging, washing with and without additives, organic matter, sampling techniques, utilization options, and assessment tools. This paper provides an overview of these projects. The main results and experiences are discussed and evaluated with respect to bottom ash upgrading and utilization. Based on this discussion......Within recent years, researchers and authorities have had increasing focus on leaching properties from waste incineration bottom ashes. Researchers have investigated processes such as those related to carbonation, weathering, metal complexation, and leaching control. Most of these investigations...

  8. Current Methods to Detoxify Fly Ash from Waste Incineration

    Energy Technology Data Exchange (ETDEWEB)

    Hallgren, Christine; Stroemberg, Birgitta [TPS Termiska Processer AB, Nykoeping (Sweden)

    2004-07-01

    Fly ash from waste incineration contains large amounts of heavy metals and dioxins, which will cause a significant disposal problem within the coming years. The amount of fly ash produced in Sweden is currently approximately 60,000 tons/y. New technological options for the decontamination and/or inertization of incinerator fly ash are being developed with the objective of rendering a product that can be reused or, at least, be deposited at standard landfill sites with no risk. Many of these technologies have been tested at industrial scale or in pilot projects. The proposed alternatives include: Thermal treatments; Immobilization/stabilization by cement based techniques; Wet chemical treatments (extractions, immobilizations); Microbiological treatments. Of these, thermal treatments are the most promising solution. Depending on the temperature thermal treatments are classified in two main types: 1) low temperature (below 600 deg C) thermal treatments and 2) high temperature (above 1200 deg C) thermal treatments (vitrification). Most dioxins can be successfully destroyed at temperatures up to 400 deg C under oxygen deficient conditions and at temperatures up to 600 deg C under oxidising conditions. However most heavy metals remain in the fly ash after low temperature treatment. At a temperature of 900 deg C most heavy metals can also be removed in a 10% HCl atmosphere by forming volatile metal chlorides (CT-Fluapur process). During vitrification processes the fly ash melts and forms an inert glassy slag. The product does not leach any significant amount of heavy metals and is free from dioxin. The volume of the fly ash is significantly reduced. The product can be land filled at low costs or used as construction material. The properties of the product depend on the cooling process and on additives such as sand, limestone or waste glass. A series of vitrification methods at industrial size or in pilot scale using different furnaces are studied. Among these, plasma

  9. UTYLIZATION METHODS OF SLAGS AND ASH FROM WASTE INCINERATION PLANTS

    Directory of Open Access Journals (Sweden)

    Janusz Mikuła

    2017-06-01

    Full Text Available The paper presents modern management methods, solidification and immobilization of ash and slag from waste incineration plants. The innovative technologies for solving this kind of problem were described. Results focused on the most promising technologies of solidification, among others geopolymerization processes. The paper presents examples of the results of solidified ash and slag in the geopolymer matrix. The studies showed that the leachable of heavy metals from the geopolymer matrix containing ashes from the incineration of municipal waste qualifies them for storage in landfills for non-hazardous and inert. Moreover, these studies demonstrated practically 100% effectiveness for immobilization of the elements: bar (Ba, cadmium (Cd, zinc (Zn, mercury (Hg, nickel (Ni, lead (Pb. In the case of chromium III (Cr+3 97% level of effectiveness of the immobilization was achieved. In order to immobilize chromium VI (Cr+6 introduced additions of sulfur compounds. The study confirmed the low efficiency of the immobilization of: arsenic (As, selenium (Se and molybdenum (Mo.

  10. High temperature co-treatment of bottom ash and stabilized fly ashes from waste incineration

    DEFF Research Database (Denmark)

    Sørensen, Mette Abildgaard; Mogensen, E.P.B.; Lundtorp, Kasper

    2001-01-01

    Bottom ashes from two Danish municipal solid waste incineration plants were heated at 900 degreesC with iron oxide stabilized air pollution control residues at actual mass flow ratios (9:1), simulating a treating method for the residues. The two residues were cotreated, producing one combined...

  11. Heavy Metal Contamination of Soils around a Hospital Waste Incinerator Bottom Ash Dumps Site

    Directory of Open Access Journals (Sweden)

    M. Adama

    2016-01-01

    Full Text Available Waste incineration is the main waste management strategy used in treating hospital waste in many developing countries. However, the release of dioxins, POPs, and heavy metals in fly and bottom ash poses environmental and public health concerns. To determine heavy metal (Hg, Pb, Cd, Cr, and Ag in levels in incinerator bottom ash and soils 100 m around the incinerator bottom ash dump site, ash samples and surrounding soil samples were collected at 20 m, 40 m, 60 m, 80 m, 100 m, and 1,200 m from incinerator. These were analyzed using the absorption spectrophotometer method. The geoaccumulation (Igeo and pollution load indices (PLI were used to assess the level of heavy metal contamination of surrounding soils. The study revealed high concentrations in mg/kg for, Zn (16417.69, Pb (143.80, Cr (99.30, and Cd (7.54 in bottom ash and these were above allowable limits for disposal in landfill. The study also found soils within 60 m radius of the incinerator to be polluted with the metals. It is recommended that health care waste managers be educated on the implication of improper management of incinerator bottom ash and regulators monitor hospital waste incinerator sites.

  12. To fractionate municipal solid waste incineration bottom ash: Key for utilisation?

    Science.gov (United States)

    Sormunen, Laura Annika; Rantsi, Riina

    2015-11-01

    For the past decade, the Finnish waste sector has increasingly moved from the landfilling of municipal solid waste towards waste incineration. New challenges are faced with the growing amounts of municipal solid waste incineration bottom ash, which are mainly landfilled at the moment. Since this is not a sustainable or a profitable solution, finding different utilisation applications for the municipal solid waste incineration bottom ash is crucial. This study reports a comprehensive analysis of bottom ash properties from one waste incineration plant in Finland, which was first treated with a Dutch bottom ash recovery technique called advanced dry recovery. This novel process separates non-ferrous and ferrous metals from bottom ash, generating mineral fractions of different grain sizes (0-2 mm, 2-5 mm, 5-12 mm and 12-50 mm). The main aim of the study was to assess, whether the advanced bottom ash treatment technique, producing mineral fractions of different grain sizes and therefore properties, facilitates the utilisation of municipal solid waste incineration bottom ash in Finland. The results were encouraging; the bottom ash mineral fractions have favourable behaviour against the frost action, which is especially useful in the Finnish conditions. In addition, the leaching of most hazardous substances did not restrict the utilisation of bottom ash, especially for the larger fractions (>5 mm). Overall, this study has shown that the advanced bottom ash recovering technique can be one solution to increase the utilisation of bottom ash and furthermore decrease its landfilling in Finland. © The Author(s) 2015.

  13. An overview on characterization, utilization and leachate analysis of biomedical waste incinerator ash.

    Science.gov (United States)

    Rajor, Anita; Xaxa, Monika; Mehta, Ratika; Kunal

    2012-10-15

    Solid waste management is one of the major global environmental issues, as there is continuous increase in industrial globalization and generation of waste. Solid wastes encompass the heterogeneous mass of throwaways from the urban community as well as the homogeneous accumulations of agricultural, industrial and mineral wastes. Biomedical waste pose a significant impact on health and environment. A proper waste management system should be required to dispose hazardous biomedical waste and incineration should be the best available technology to reduce the volume of this hazardous waste. The incineration process destroys pathogens and reduces the waste volume and weight but leaves a solid material called biomedical waste ash as residue which increases the levels of heavy metals, inorganic salts and organic compounds in the environment. Disposal of biomedical waste ash in landfill may cause contamination of groundwater as metals are not destroyed during incineration. The limited space and the high cost for land disposal led to the development of recycling technologies and the reuse of ash in different systems. In order to minimize leaching of its hazardous components into the environment several studies confirmed the successful utilization of biomedical waste ash in agriculture and construction sector. This paper presents the overview on the beneficial use of ash in agriculture and construction materials and its leachate characteristics. This review also stressed on the need to further evaluate the leachate studies of the ashes and slag for their proper disposal and utilization. Copyright © 2012 Elsevier Ltd. All rights reserved.

  14. Properties of municipal solid waste incineration ashes with respect to their separation temperature

    Czech Academy of Sciences Publication Activity Database

    Keppert, M.; Pavlík, Z.; Tydlitát, V.; Volfová, P.; Švarcová, Silvie; Šyc, Michal; Černý, R.

    2012-01-01

    Roč. 30, č. 10 (2012), s. 1041-1048 ISSN 0734-242X Institutional support: RVO:61388980 ; RVO:67985858 Keywords : bottom ash * fly ash * municipal solid waste incinerator * pozzolanic activity * hydration heat * separation temperature * building industry Subject RIV: CA - Inorganic Chemistry Impact factor: 1.047, year: 2012

  15. Thermal treatment of ashes[Fly Ash from Municipal Waste Incineration]; Termisk rening av askor

    Energy Technology Data Exchange (ETDEWEB)

    Wikman, Karin; Berg, Magnus; Bjurstroem, Henrik [AaF-Energi och Miljoe AB, Stockholm (Sweden); Nordin, Anders [Umeaa Univ. (Sweden). Dept. of Applied Physics and Electronics

    2003-04-01

    In this project descriptions of different processes for thermal treatment of ashes have been compiled. A technical and economic evaluation of the processes has been done to identify possibilities and problems. The focus in the project lays on treatment of fly ash from municipal waste incineration but the processes can also be used to treat other ashes. When the ash is heated in the thermal treatment reactor, with or without additives, the material is sintered or vitrified and at the same time volatile substances (Zn, Pb, Cd, Hg etc.) are separated. In general the separation is more effective in processes with reducing conditions compared to oxidizing conditions. Oxidizing processes have both worse separation capacity and require more energy. The oxidizing processes are mainly used to stabilize the ash through vitrification and they are in some cases developed for management of municipal sewage sludge and bottom ash. However, these processes are often not as complex as for example an electric arc melting furnace with reducing conditions. The research today aim to develop more effective electrical melting systems with reducing conditions such as plasma melting furnaces, electric resistance melting furnaces and low frequency induction furnaces. A central question in the evaluation of different thermal treatment processes for ash is how the residues from the treatment can be used. It is not certain that the vitrified material is stable enough to get a high economic value, but it can probably be used as construction material. How the remaining metals in the ash are bound is very important in a long-time perspective. Further studies with leaching tests are necessary to clarify this issue. The heavy metal concentrate from the processes contains impurities, such as chlorine, which makes it unprofitable to obtain the metals. Instead the heavy metal concentrate has to be land filled. However, the amount of material for land filling will be much smaller if only the heavy

  16. [Correlation of Persistent Free Radicals, PCDD/Fs and Metals in Waste Incineration Fly Ash].

    Science.gov (United States)

    Wang, Tian-jiao; Chen, Tong; Zhan, Ming-xiu; Guo, Ying; Li, Xiao-dong

    2016-03-15

    Environmentally persistent free radicals (EPFRs) are relatively highly stable and found in the formation of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs). Recent studies have concentrated on model dioxin formation reactions and there are few studies on actual waste incineration fly ash. In order to study EPFRs and the correlation with dioxins and heavy metals in waste incineration fly ash, the spins of EPFRs, concentration of PCDD/Fs and metals in samples from 6 different waste incinerators were detected. The medical waste incineration fly ash from Tianjin, municipal solid waste incineration fly ash from Jiangxi Province, black carbon and slag from municipal solid waste incinerator in Lanxi, Zhejiang Province, all contained EPFRs. Above all the signal in Tianjin sample was the strongest. Hydroxyl radicals, carbon-center radicals and semiquinone radicals were detected. Compared with other samples, Jiangxi fly ash had the highest toxic equivalent quantity (TEQ) of dioxins, up to 7.229 4 ng · g⁻¹. However, the dioxin concentration in the Tianjin sample containing the strongest EPFR signals was only 0.092 8 ng · g⁻¹. There was perhaps little direct numeric link between EPFRs and PCDD/Fs. But the spins of EPFRs in samples presented an increasing trend as the metal contents increased, especially with Al, Fe, Zn. The signal strength of radicals was purposed to be related to the metal contents. The concentration of Zn (0.813 7% ) in the Tianjin sample was the highest and this sample contained much more spins of oxygen-center radicals. We could presume the metal Zn had a greater effect on the formation of EPFRs, and was easier to induce the formation of radicals with a longer half-life period.

  17. The rare earth elements in municipal solid waste incinerators ash and promising tools for their prospecting

    Energy Technology Data Exchange (ETDEWEB)

    Funari, Valerio, E-mail: valerio.funari@unibo.it [Dipartimento di Scienze Biologiche, Geologiche e Ambientali (BiGeA)—University of Bologna, Piazza di Porta San Donato 1, Bologna (Italy); Bokhari, Syed Nadeem Hussain [General and Analytical Chemistry—Montanuniversität Leoben, Franz-Josef-Str. 18, Leoben (Austria); Vigliotti, Luigi [Istituto di Scienze Marine (ISMAR-CNR)—National Research Council, Via Piero Gobetti 101, Bologna (Italy); Meisel, Thomas [General and Analytical Chemistry—Montanuniversität Leoben, Franz-Josef-Str. 18, Leoben (Austria); Braga, Roberto [Dipartimento di Scienze Biologiche, Geologiche e Ambientali (BiGeA)—University of Bologna, Piazza di Porta San Donato 1, Bologna (Italy)

    2016-01-15

    Highlights: • The REE concentrations of bottom and fly ashes from municipal incinerators are investigated. • First attempt toward discriminating the magnetic signature (susceptibility) of ashes from incinerators. • New methods and parameters for REE prospecting, which can be determined quickly and with limited costs, are provided. - Abstract: Bottom and fly ashes from Municipal Solid Waste Incinerators (MSWI) are hazardous products that present concern for their safe management. An attractive option to reduce their impact both on the environment and the financial commitment is turning MSWI ashes into secondary raw materials. In this study we present the REE content and distribution of bottom and fly ashes from MSWI after a highly effective digestion method and samples analysis by ICP–MS. The chondrite-normalised REE patterns of MSWI bottom and fly ash are comparable with that of crustal averages, suggesting a main geogenic source. Deviations from typical crustal pattern (e.g., Eu, Tb) disclose a contribution of likely anthropogenic provenance. The correlation with major elements indicates possible sources for REE and facilitates a preliminary resource assessment. Moreover, magnetic susceptibility measurements can be a useful prospecting method in urban ores made of MSWI ashes. The relationship between REE and some influencing parameters (e.g., Pricing Influence Factor) emphasises the importance of MSWI ash as alternative source of REE and the need of further efforts for REE recovery and purification from low concentrations but high flows waste.

  18. Formation of cement mortar with incineration municipal solid waste bottom ash

    Science.gov (United States)

    Jun, Ng Hooi; Abdullah, Mohd Mustafa Al Bakri; Hussin, Kamarudin; Jin, Tan Soo

    2017-04-01

    Product of incineration municipal solid waste bottom ash was substitute to Portland cement in construction industry. This study investigated the changes of bottom ash in Portland cement by chemical and mineralogical testing. Various substitution of bottom ash (10%, 20%, 30%, and 40%) to Portland cement was investigated. The main purpose was to clarify the mechanisms behind the formation of the cement mortar with bottom ash particles. The result indicated that the chemical and mineralogical of the cement mortar incorporating bottom ash was not significantly changed with the substitution of 10-40% bottom ash. However, the use of bottom ash minimizes the main composition of cement mortar. Overall, it was found that there is significant potential to increase the utilization of bottom ash.

  19. Characterization of municipal solid waste incineration fly ash before and after electrodialytic treatment

    DEFF Research Database (Denmark)

    Pedersen, Anne Juul; Gardner, Kevin H.

    2003-01-01

    Municipal solid waste incineration (MSWI) fly ash, which has been treated electrodialytically for the removal of heavy metals, may have changed characteristics compared to untreated fly ash. In this study, MSWI fly ash was characterized with respect to leaching properties (pH static leaching...... metals had been removed from the ash during the electrodialytic treatment, the leachability of several of the residual metals had actually increased. The increased leachability was most probably caused by mineral dissolution and chelating of metals by residual citrate in the ash. Ammonium citrate had...... been added to the ash before and during electrodialytic treatment to increase the heavy metal desorption. The morphology and mineralogy of the ash was also altered as a result of the treatment. XRPD ex-aminations revealed that a severe depletion of Cl, Na and K in the treated ashes was due to wash out...

  20. Carbon speciation in municipal solid waste incinerator (MSWI) bottom ash in relation to facilitated metal leaching

    NARCIS (Netherlands)

    Zomeren, van A.; Comans, R.N.J.

    2009-01-01

    The release of inorganic and organic contaminants from municipal solid waste incinerator (MSWI) bottom ash is controlled to a large extent by the release of dissolved organic carbon (DOC), and in particular by the reactive humic (HA) and fulvic acids (FA) subfractions of DOC. The properties of

  1. Leaching from waste incineration bottom ashes treated in a rotary kiln

    DEFF Research Database (Denmark)

    Hyks, Jiri; Nesterov, Igor; Mogensen, Erhardt

    2011-01-01

    Leaching from municipal solid waste incineration bottom ash treated in a rotary kiln was quantified using a combination of lab-scale leaching experiments and geochemical modelling. Thermal treatment in the rotary kiln had no significant effect on the leaching of Al, Ba, Ca, Mg, Si, Sr, Zn, sulfate...... the thermal treatment. Overall, rotary kiln thermal treatment of bottom ashes can be recommended to reduce the leaching of Cu, Pb, Cl and DOC; however, increased leaching of Cr and Mo should be expected....

  2. Effects of different surface modification and contents on municipal solid waste incineration fly ash/epoxy composites.

    Science.gov (United States)

    Goh, C K; Valavan, S E; Low, T K; Tang, L H

    2016-12-01

    Incineration fly ash, a waste from municipal solid waste incineration plant can be used to replace conventional filler as reinforcing filler to enhance the mechanical strength of a composite. Surface modification was performed on the incineration fly ash before mixing into the soft polymer matrix so as to improve interfacial bond of the filler and epoxy resin. In this study, detailed characterisation of mechanical, morphological and leaching behaviours of municipal solid waste incineration (MSWI) fly ash infused composite has been carried out. Flexural and tensile test was conducted to determine the effect on mechanical properties of the composite by varying the concentration of incineration fly ash filler added into polymer matrix and surface modification of incineration fly ash filler using silane coupling agent and colloidal mesoporous silica (CMS). The results indicated that composite infused with incineration fly ash filler surface treated with CMS shown improvement on the tensile and flexural strengths. In addition, SEM images showed that surface modification of incineration fly ash with colloidal mesoporous silica enhanced the interfacial bonding with polymer resin which explained the improvement of mechanical strength. Leaching test showed result of toxic metals such as Pb, Zn, Fe, Cu, Cr, Cd and Rb immobilised in the polymer matrix of the composite. Hence, the use of MSWI fly ash as reinforcing filler in the composite appears green and sustainable because this approach is a promising opportunity to substitute valuable raw material with MSWI fly ash. Copyright © 2016 Elsevier Ltd. All rights reserved.

  3. Properties of municipal solid waste incineration ashes with respect to their separation temperature.

    Science.gov (United States)

    Keppert, Martin; Pavlík, Zbysek; Tydlitát, Vratislav; Volfová, Petra; Svarcová, Silvie; Syc, Michal; Cerny, Robert

    2012-10-01

    Fly ashes generated by power and heating plants are commonly used in the production of building materials in some countries, mainly as partial replacement of cement or aggregates in concrete. The ashes from municipal solid waste incinerators can be applied in a similar way. However, their chemical and mineralogical composition, granulometry and toxic constituents have to be taken into account. In this paper, four types of municipal solid waste incinerator (MSWI) ashes produced by the modern MSWI facility in Liberec, Czech Republic, were investigated. The relationship between the particular ash properties (morphology, chemical composition) and its separation temperature in the incinerator line is discussed. A coal fly ash (class F) is characterized as well, for a comparison because its utilization in building industry is more developed. The studied MSWI ashes exhibit high concentration of chlorides and sulfates which is an unfavourable feature for a potential concrete admixture. On the other hand, three of four ashes are found to be pozzolanic active and certain hydration reactions are indicated.

  4. EU landfill waste acceptance criteria and EU Hazardous Waste Directive compliance testing of incinerated sewage sludge ash.

    Science.gov (United States)

    Donatello, S; Tyrer, M; Cheeseman, C R

    2010-01-01

    A hazardous waste assessment has been completed on ash samples obtained from seven sewage sludge incinerators operating in the UK, using the methods recommended in the EU Hazardous Waste Directive. Using these methods, the assumed speciation of zinc (Zn) ultimately determines if the samples are hazardous due to ecotoxicity hazard. Leaching test results showed that two of the seven sewage sludge ash samples would require disposal in a hazardous waste landfill because they exceed EU landfill waste acceptance criteria for stabilised non-reactive hazardous waste cells for soluble selenium (Se). Because Zn cannot be proven to exist predominantly as a phosphate or oxide in the ashes, it is recommended they be considered as non-hazardous waste. However leaching test results demonstrate that these ashes cannot be considered as inert waste, and this has significant implications for the management, disposal and re-use of sewage sludge ash.

  5. Re-use of stabilised flue gas ashes from solid waste incineration in cement-treated base layers for pavements

    DEFF Research Database (Denmark)

    Cai, Zuansi; Jensen, Dorthe Lærke; Christensen, Thomas Højlund

    2003-01-01

    Fly ash from coal-burning power plants has been used extensively as a pozzolan and fine filter in concrete for many years. Laboratory experiments were performed investigating the effect of substituting the coal-based fly ash with chemically stabilised flue gas ashes (FGA) from waste incineration....

  6. Sieving of municipal solid waste incineration (MSWI) bottom ash; Siktning av askor fraan avfallsfoerbraenning

    Energy Technology Data Exchange (ETDEWEB)

    Todorovic, Jelena

    2010-07-01

    Waste-to-Energy is steadily increasing in Sweden and more than 46 % of municipal solid waste (MSW) is being incinerated. Solid residues from MSW incineration (MSWI) mainly constitute of bottom ash and air pollution control (APC) residues. Bottom ashes from MSWI amounted to 0.7 millions of tons and APC residues to 0.2 millions of tons in 2008. Bottom ashes from MSWI contain pollutants like metals (e.g. Pb, Zn, Cu), metalloids (e.g. As, Se), elements forming oxyanions (e.g. Sb, Cr, Mo) and easily soluble salts like chlorides and sulphates. These constituents can leach out polluting the environment if ash comes in contact with water. Treatment methods for decreasing the amount of pollutants in ashes or their mobility are therefore needed. Sieving was investigated as a separate or a complementary treatment method for MSWI ashes. Hypothesis was that the large share of pollutant concentrations could be removed from the ashes through separation of the finest fractions. The rest is less harmful to the environment, more acceptable as secondary construction material or less costly to landfill. Investigation included three MSWI ashes, namely bottom ash from Boraas Energy och Miljoe's plant with fluid bad, boiler ash from the same plant and bottom ash from Renova's stocker grate type plant. Ashes were sieved in 2-4 size fractions. Total content of pollutants and their leachability (batch leaching test, L/S=10 l/kg) was assessed for each of the fractions. Leaching results were compared to limit values stipulated by Swedish Environmental Protection Agency for acceptance of waste at landfills as wells as to recommendations for reuse of waste as a construction material. Results from bottom ash from the stocker grate type incinerator and from the boiler ash confirm the hypothesis that pollutants leach out in higher concentrations from the finer fractions. A large amount of pollutant could be removed from the ashes through sieving, but the goal to produce a fraction that

  7. The potential impact of municipal solid waste incinerators ashes on the anthropogenic osmium budget

    Energy Technology Data Exchange (ETDEWEB)

    Funari, Valerio, E-mail: valerio.funari@unibo.it [Dipartimento di Scienze Biologiche, Geologiche e Ambientali (BiGeA), University of Bologna, Piazza di Porta San Donato 1, Bologna (Italy); Meisel, Thomas [General and Analytical Chemistry, Montanuniversität Leoben, Franz-Josef-Str. 18, Leoben (Austria); Braga, Roberto [Dipartimento di Scienze Biologiche, Geologiche e Ambientali (BiGeA), University of Bologna, Piazza di Porta San Donato 1, Bologna (Italy)

    2016-01-15

    Osmium release from Municipal Solid Waste Incinerators (MSWI), even if acknowledged to occur at least over the last fifteen years, remains overlooked in the majority of recent studies. We present the osmium concentration and {sup 187}Os/{sup 188}Os isotopic measurements of different kinds of bottom and fly ash samples from MSWI plants and reference materials of incinerator fly ash (BCR176 and BCR176R). The analysis of the unknown ash samples shows a relatively wide range of {sup 187}Os/{sup 188}Os ratios (0.24–0.70) and Os concentrations (from 0.026 ng/g to 1.65 ng/g). Osmium concentrations and isotopic signatures differ from those of other known Os sources, either natural or manmade, suggesting a mixture of both contributions in the MSWI feedstock material. Furthermore, the comparison between the BCR176 and the renewed BCR176R indicates a decrease in Os concentration of one order of magnitude over the years (from 1 to 0.1 ng/g) due to improved recycling efficiency of Os-bearing waste. The estimated annual amount of Os from a typical incinerator (using average Os values and MSWI mass balance) is 13.4 g/a. The osmium potentially released from MSWI smokestacks is predicted to be from 16 to 38 ng Os/m{sup 2}/a, considering a medium size country having 50 MSWI facilities; therefore much higher than the naturally transported osmium from continental dust in the atmosphere (about 1 pg Os/m{sup 2}/a). MSWI systems are considered one of the best options for municipal solid waste management in industrialised countries, but their contribution to the Os budget can be significant. - Highlights: • Bottom and fly ashes from municipal solid waste incinerators are investigated. • Their Os levels and Os isotopic signatures are discussed. • An estimate of Os release from incinerators and incinerated ashes is given. • Os contamination from incineration plants impacts the geochemical Os cycle.

  8. Thermal treatment and vitrification of boiler ash from a municipal solid waste incinerator.

    Science.gov (United States)

    Yang, Y; Xiao, Y; Voncken, J H L; Wilson, N

    2008-06-15

    Boiler ash generated from municipal solid waste (MSW) incinerators is usually classified as hazardous materials and requires special disposal. In the present study, the boiler ash was characterized for the chemical compositions, morphology and microstructure. The thermal chemical behavior during ash heating was investigated with thermal balance. Vitrification of the ash was conducted at a temperature of 1400 degrees C in order to generate a stable silicate slag, and the formed slag was examined with chemical and mineralogical analyses. The effect of vitrification on the leaching characteristics of various elements in the ash was evaluated with acid leaching. The study shows that the boiler ash as a heterogeneous fine powder contains mainly silicate, carbonate, sulfates, chlorides, and residues of organic materials and heavy metal compounds. At elevated temperatures, the boiler ash goes through the initial moisture removal, volatilization, decomposition, sintering, melting, and slag formation. At 1400 degrees C a thin layer of salt melt and a homogeneous glassy slag was formed. The experimental results indicate that leaching values of the vitrified slag are significantly reduced compared to the original boiler ash, and the vitrification could be an interesting alternative for a safer disposal of the boiler ash. Ash compacting, e.g., pelletizing can reduce volatilization and weight loss by about 50%, and would be a good option for the feed preparation before vitrification.

  9. Solidification/stabilization of ash from medical waste incineration into geopolymers.

    Science.gov (United States)

    Tzanakos, Konstantinos; Mimilidou, Aliki; Anastasiadou, Kalliopi; Stratakis, Antonis; Gidarakos, Evangelos

    2014-10-01

    In the present work, bottom and fly ash, generated from incinerated medical waste, was used as a raw material for the production of geopolymers. The stabilization (S/S) process studied in this paper has been evaluated by means of the leaching and mechanical properties of the S/S solids obtained. Hospital waste ash, sodium hydroxide, sodium silicate solution and metakaolin were mixed. Geopolymers were cured at 50°C for 24h. After a certain aging time of 7 and 28 days, the strength of the geopolymer specimens, the leachability of heavy metals and the mineralogical phase of the produced geopolymers were studied. The effects of the additions of fly ash and calcium compounds were also investigated. The results showed that hospital waste ash can be utilized as source material for the production of geopolymers. The addition of fly ash and calcium compounds considerably improves the strength of the geopolymer specimens (2-8 MPa). Finally, the solidified matrices indicated that geopolymerization process is able to reduce the amount of the heavy metals found in the leachate of the hospital waste ash. Copyright © 2014 Elsevier Ltd. All rights reserved.

  10. Characteristics of residual organics in municipal solid waste incinerator bottom ash.

    Science.gov (United States)

    Lin, Yen-Ching; Yen, Jui-Hung; Lateef, Shaik Khaja; Hong, Pui-Kwan Andy; Lin, Cheng-Fang

    2010-10-15

    Although heavy metals in bottom ash have been a primary issue in resource recovery of municipal solid waste incinerator residues in past decades, less studied are potentially toxic and odorous organic fractions that exist as they have not been completely oxidized during the mass burn process. Using supercritical fluid extraction (SFE) and soxtec extraction (SE) techniques, this study investigated the characteristics of un-oxidized organic residues contained in bottom ash from three municipal solid waste incinerators in Taiwan during 2008-2009. All together 99 organics were identified in bottom ash samples using gas chromatography-mass spectrometry (GC-MS). Among the identified organics, aromatic compounds were most frequently detected. No polycyclic aromatic hydrocarbons were extracted by SFE or SE. Several phthalates (e.g., phthalic acid isobutyl tridec-2-yn-1-yl ester, dibutyl phthalate and 2-butoxyethyl butyl benzene-1,2-dicarboxylate), organic phosphates (e.g., octicizer and phosphoric acid isodecyl diphenyl ester), and aromatics and amines including pyridine, quinoline derivatives, chloro- and cyano-organics were successfully extracted. Aromatic amines (e.g., 1-nitro-9,10-dioxo-9,10-dihydro-anthracene-2-carboxylic acid diethylamide and 3-bromo-N-(4-bromo-2-chlorophenyl)-propanamide) and aromatic compounds (other than amines) (e.g., 7-chloro-4-methoxy-3-methylquinoline and 2,3-dihydro-N-hydroxy-4-methoxy-3,3-dimethyl indole-2-one) are probably the major odorous compounds in bottom ash. This work identifies organic pollutants in incinerated bottom ash that have received far less attention than their heavy metals counterpart. 2010 Elsevier B.V. All rights reserved.

  11. Electrodialytic removal of heavy metals from municipal solid waste incineration fly ash using ammonium citrate as assisting agent

    DEFF Research Database (Denmark)

    Pedersen, Anne Juul; Ottosen, Lisbeth M.; Villumsen, Arne

    2005-01-01

    Electrodialytic remediation, an electrochemically assisted separation method, has previ-ously shown potential for removal of heavy metals from municipal solid waste incineration (MSWI) fly ashes. In this work electrodialytic remediation of MSWI fly ash using ammonium citrate as assisting agent...

  12. Geo-environmental application of municipal solid waste incinerator ash stabilized with cement

    Directory of Open Access Journals (Sweden)

    Davinder Singh

    2017-04-01

    Full Text Available The behavior of soluble salts contained in the municipal solid waste incinerator (MSWI ash significantly affects the strength development and hardening reaction when stabilized with cement. The present study focuses on the compaction and strength behavior of mixed specimens of cement and MSWI ash. A series of indices such as unconfined compressive strength, split tensile strength, California bearing ratio (CBR and pH value was examined. Prior to this, the specimens were cured for 7 d, 14 d, and 28 d. The test results depict that the maximum dry density (MDD decreases and the optimum moisture content (OMC increases with the addition of cement. The test results also reveal that the cement increases the strength of the mixed specimens. Thus, the combination of MSWI ash and cement can be used as a lightweight filling material in different structures like embankment and road construction.

  13. Chemical stability of geopolymers containing municipal solid waste incinerator fly ash.

    Science.gov (United States)

    Lancellotti, Isabella; Kamseu, Elie; Michelazzi, Marco; Barbieri, Luisa; Corradi, Anna; Leonelli, Cristina

    2010-04-01

    Municipal solid waste incinerators every year produce tons of fly ashes which, differently from coal fly ashes, contain large amounts of toxic substances (heavy metals, dioxins, furans). The stabilization/solidification (S/S) technology known as geopolymerization is proposed with the purpose to bond physically and chemically incinerator fly ashes (IFA) in a solid matrix, in order to reduce pollutant mobility. The chemical stability of geopolymers with Si/Al ratio of 1.8-1.9 and Na/Al ratio of 1.0, synthesized by alkali activation of metakaolin and the addition of 20wt% of two different kinds of IFA, is presented. The concentration of the alkaline solution, water to solid ratio and curing process have been optimized. The room temperature consolidation of IFA containing geopolymers has been tested for leachability in water for 1day, accordingly to EN 12457 regulation and extended to 7days to increase the water attack on solid granules. Leachable metals in the test solution, determined by ICP_AES, fall within limit values set by regulation for non-dangerous waste landfill disposal. Geopolymeric matrix evolution with leaching time has been also evaluated in terms of pH and electrical conductivity increase in solution. Copyright 2009 Elsevier Ltd. All rights reserved.

  14. Particle size distribution of fly ash from co-incineration of bituminous coal with municipal solid waste

    Directory of Open Access Journals (Sweden)

    Cieślik Ewelina

    2018-01-01

    Full Text Available One of the source of air pollutants is emission from local coal-fired boiler-houses and domestic heating boilers. The consequence of incineration of municipal waste is the introduction of additional pollutants into the atmosphere, including fly ash. The aim of this work was to evaluate the particle size distribution of fly ash emitted by coal combustion and co-incineration of coal with municipal waste in a domestic 18 kW central heating boiler equipped with an automatic fuel feeder. Mixtures of bituminous coal with different types of solid waste (5, 10 and 15% of mass fraction were used. Solid waste types consisted of: printed, colored PE caps, fragmented cable trunking, fragmented car gaskets and shredded tires from trucks. During the incineration of a given mixture of municipal waste with bituminous coal, the velocity of exhaust gas was specified, the concentration and mass flow of fly ash were determined together with the physico-chemical parameters of the exhaust gas, the samples of emitted fly ash were taken as the test material. Particle size analysis of fly ash was performed using laser particle sizer Fritch Analysette 22. The PM10 share from all fly ashes from incineration of mixtures was about 100%. Differences were noted between PM2.5 and PM1.

  15. Comparison between rice husk ash grown in different regions for stabilizing fly ash from a solid waste incinerator.

    Science.gov (United States)

    Benassi, L; Bosio, A; Dalipi, R; Borgese, L; Rodella, N; Pasquali, M; Depero, L E; Bergese, P; Bontempi, E

    2015-08-15

    The Stabilization of heavy metals from municipal solid waste incineration (MSWI) fly ash by rice husk ash (RHA) is under intense study as an effective strategy to recover and reuse industrial and agricultural waste together. We compare the metal entrapment performances of RHA from different Asian rice sources – namely from Japonica rice grown in Italy and Indica rice grown in India – Physicochemical and morphological characterization of the final stabilized material show that the same thermal treatment may result in marked structural differences in the silica contained in the two RHA. Remarkably, one of them displays a crystalline silica content, although obtained by a thermal treatment below 800 °C. We also find that the presence of an alkali metal ion (potassium) in the rice husk plays a crucial role in the attainment of the final silica phase. These physicochemical differences are mirrored by different stabilization yields by the two RHA. Copyright © 2015 Elsevier Ltd. All rights reserved.

  16. Electrodialytic extraction of Cu, Pb and Cl from municipal solid waste incineration fly ash suspended in water

    DEFF Research Database (Denmark)

    Ottosen, Lisbeth M.; Lima, Ana Teresa; Pedersen, Anne Juul

    2006-01-01

    The possibility of using fly ash from municipal solid waste incineration (MSWI) in, for example, concrete is considered. MSWI fly ash, however, has too high a concentration of heavy metals, which may cause leaching problems during use or problems with waste handling at the end of the lifetime...... of the concrete. The Cl content in MSWI fly ash is also too high and will cause corrosion problems in reinforced concrete. The possibility of removing some of the unwanted heavy metals (Cu and Pb) together with Cl from an MSWI fly ash suspended in water using an electrodialytic separation method was investigated...

  17. Copper speciation in municipal solid waste incinerator bottom ash leachates; Kopparformer i lakvatten fraan energiaskor

    Energy Technology Data Exchange (ETDEWEB)

    Olsson, Susanna; Gustafsson, Jon Petter [Royal Inst. of Tech., Stockholm (Sweden); Schaik, Joris van; Berggren Kleja, Dan [Swedish Univ. of Agricultural Sciences, Uppsala (Sweden); Hees, Patrick van [Oerebro Univ. (Sweden)

    2006-03-15

    The formation of copper (Cu) complexes with dissolved organic carbon (DOC) in bottom ash from municipal solid waste incineration (MSWI) may increase the total amount of Cu released but at the same time reduce its toxicity. In this study, DOC in a MSWI bottom ash leachate was characterized and the Cu-binding properties of different DOC fractions in the ash leachate and in a soil solution were studied. This knowledge may be used for improved environmental assessment of MSWI bottom ash in engineering applications. The Cu{sup 2+} activity at different pH values was measured potentiometrically using a Cu-ion selective electrode (Cu-ISE). Experimental copper complexation results were compared to speciation calculations made in Visual MINTEQ with the NICA-Donnan model and the Stockholm Humic Model (SHM). The MSWI bottom ash leachate contained a larger proportion of hydrophilic organic carbon than the investigated soil solution and other natural waters. The hydrophilic fraction of both samples showed Cu{sup 2+} binding properties similar to that of the bulk, cation-exchanged, leachate. For the ash leachate, the pH dependence of the Cu activity was not correctly captured by neither the SHM nor the NICA-Donnan model, but for the soil solution the model predictions of Cu speciation were in good agreement with the obtained results. The complex formation properties of the ash DOC appears to be less pH-dependent than what is assumed for DOC in natural waters. Hence, models calibrated for natural DOC may give inconsistent simulations of Cu-DOC complexation in MSWI bottom ash leachate. A Biotic Ligand Model for Daphnia Magna was used to provide an estimate of the copper concentrations at LC50 for a simulated bottom ash leachate. It was concluded that the Cu concentrations in certain bottom ash leachates are high enough to pose an ecotoxicological risk; however, after dilution and soil sorption, the risks for neighboring water bodies are most likely negligible. Three processes were

  18. Effect of COSMOS technologies in detoxifying municipal solid waste incineration fly ash, preliminary results

    Science.gov (United States)

    Piccinelli, Elsa; Lasagni, Marina; Collina, Elena; Bonaiti, Stefania; Bontempi, Elza

    2017-05-01

    This study investigates the effect of technologies for heavy metal stabilization on the concentration of PolyChlorinatedDibenzo-p-Dioxins (PCDD) and PolyChlorinatedDibenzoFurans (PCDF), abbreviated PCDD/F, in Municipal Solid Waste Incineration (MSWI) fly ash. We determined the variation of the Total Organic Carbon (TOC) and PCDD/F concentration between raw and stabilized material. The technologies, that already proved to be very promising for heavy metal entrapment, showed encouraging results also for PCDD/F detoxification. This result could be very impacting on the management of MSWI fly ash: at the best of our knowledge, there are no methods, in literature, that can provide good results in stabilization of heavy metals, and abatement of chlorinated organic pollutants contained in the same matrix.

  19. Multielement-analysis of city waste incineration ash with total reflection X-ray fluorescence (TXRF)

    Energy Technology Data Exchange (ETDEWEB)

    Gerwinski, W.; Goetz, D.; Koelling, S.; Kunze, J.

    1987-06-01

    The toal reflection X-ray fluorescence technique (TXRF) was used for the routine analysis of city waste incineration ash. Subjects of these analyses were digested ashes (a) and aqueous leaching solutions (b). The accuracy of TXRF was estimated in comparison with atomic absorption spectroscopy (AAS) and atomic emission spectroscopy (ICP-AES) measurements. Satisfactory agreement was found between the results of the different methods for both types of samples. In addition to the direct measurements without prior sample preparation sample type (b) was used to compare three different extraction methods. In each case a dithiocarbamate derivative was used as complexing agent. The separation of the precipitate was performed with a silicagel column, by liquid/liquid extraction and by leaching the sample on a quartz target. Satisfying agreement was found between direct measurements and the different extraction methods.

  20. New fired bricks based on municipal solid waste incinerator bottom ash.

    Science.gov (United States)

    Taurino, R; Karamanova, E; Barbieri, L; Atanasova-Vladimirova, S; Andreola, F; Karamanov, A

    2017-10-01

    The main objective of this work was to study the sintering process and technological properties of new fired bricks based on high amount of post-treated municipal solid waste incinerator bottom ash and refractory clay. In addition, the effect of the minor addition of flux (Na2CO3) or reinforce (corundum) was also highlighted. Several methods were used to study the effect of compositions variations on the sintering process, structure and the mechanical characteristics of the test briquettes. Differential thermal analysis (TG/DTA) and dilatometry techniques were applied to study the thermal behaviour while scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy and high-temperature X-ray diffraction were used to elucidate the structure and the phase composition. The mechanical characteristics were estimated by micro-indentation, strength and various physical tests (porosity, linear shrinkage and water absorption, etc). The results highlight the possibility to use very high amount of municipal solid waste incinerator bottom ashes in the production of new fired bricks with good performances at all levels. It is also shown that the addition of additives managed the final properties, affecting the crystal phase formation, porosity and greatly the strength of the samples.

  1. Retention and leaching of nitrite by municipal solid waste incinerator bottom ash under the landfill circumstance.

    Science.gov (United States)

    Yao, Jun; Kong, Qingna; Zhu, Huayue; Long, Yuyang; Shen, Dongsheng

    2015-01-01

    The retention and leaching of nitrite by municipal solid waste incinerator (MSWI) bottom ash could affect its migration in the landfill. In this study, the effect of the dosage of MSWI bottom ash as well as the variation of the landfill environmental parameters including pH, anions and organic matter on the nitrite retention and leaching behavior was investigated by batch experiments. The highest removal percentage (73.0%) of nitrite was observed when the dosage of MSWI bottom ash was 10 g L(-1) in 2 mg L(-1) nitrite solution. Further increase of the dosage would retard the retention, as the nitrite leaching from MSWI bottom ash was enhanced. The optimum retention of nitrite was observed when the pH was 5.0, while the leaching of nitrite showed a consistent reduction with the increase of pH. Besides, the presence of Cl(-), SO4(2)(-) and acetic acid could enhance the leaching of nitrite and mitigate the retention process. However, the retention of nitrite was enhanced by PO4(3)(-), which was probably due to the formation of the apatite, an active material for the adsorption of the nitrite. These results suggested that MSWI bottom ash could affect the migration of nitrite in the landfill, which was related to the variation of the landfill circumstance. Copyright © 2014 Elsevier Ltd. All rights reserved.

  2. Stabilization/solidification of a municipal solid waste incineration residue using fly ash-based geopolymers.

    Science.gov (United States)

    Luna Galiano, Y; Fernández Pereira, C; Vale, J

    2011-01-15

    The stabilization/solidification (S/S) of a municipal solid waste incineration (MSWI) fly ash containing hazardous metals such as Pb, Cd, Cr, Zn or Ba by means of geopolymerization technology is described in this paper. Different reagents such as sodium hydroxide, potassium hydroxide, sodium silicate, potassium silicate, kaolin, metakaolin and ground blast furnace slag have been used. Mixtures of MSWI waste with these kinds of geopolymeric materials and class F coal fly ash used as silica and alumina source have been processed to study the potential of geopolymers as waste immobilizing agents. To this end, the effects of curing conditions and composition have been tested. S/S solids are submitted to compressive strength and leaching tests to assess the results obtained and to evaluate the efficiency of the treatment. Compressive strength values in the range 1-9 MPa were easily obtained at 7 and 28 days. Concentrations of the metals leached from S/S products were strongly pH dependent, showing that the leachate pH was the most important variable for the immobilization of metals. Comparison of fly ash-based geopolymer systems with classical Portland cement stabilization methods has also been accomplished. Copyright © 2010 Elsevier B.V. All rights reserved.

  3. A feasibility study of municipal solid waste incineration fly ash utilisation in Estonia.

    Science.gov (United States)

    Berber, Hakan; Frey, Ruedi; Voronova, Viktoria; Koroljova, Arina

    2017-09-01

    The purpose of this paper is to discuss the alternative environmental management options for the utilisation of municipal solid waste (MSW) incineration fly ash (FA), which is generated at Iru Power Plant where MSW is incinerated in Estonia. To determine sustainable and economically feasible environmental management options for MSW incineration FA in Estonia, CO2 sequestration with a further carbonation process was examined. A partial Cost & Benefit Analysis has been conducted to compare the carbonation process to the current situation. Two carbonation options were developed. Option 1 is to use carbonated FA in any other processes based on the waste-to-product principle. Option 2 is to send carbonated FA to the non-hazardous landfill in Tallinn, Estonia. Important parameters, such as Net Present Value (NPV), Internal Rate of Return (IRR), Benefit-Cost Ratio (BCR) and Break Even Point (BEP), have been calculated for carbonation options and the current case. In addition, a sensitivity analysis has been conducted to examine its robustness. The results showed that the best option is carbonation Option 1 with NPV of 9,209,662 EUR, IRR of 43%, BCR of 2.63 and BEP between 2018 and 2019. Both Options 1 and 2 constitute more sustainable and environmentally friendly management options compared to the current situation. It can be concluded that this preliminary feasibility study showed that running a carbonation plant may be profitable and sustainable for Estonia. Currently, there is no treatment technology for MSW incineration FA in Estonia and FA is sent to a neighbouring country for further utilisation. This is the first study to demonstrate FA management options with economic and environmental benefits.

  4. Phosphate stabilization of flue gas ashes from waste incineration; Fosfatstabilisering av roekgasaska fraan avfallsfoerbraenning

    Energy Technology Data Exchange (ETDEWEB)

    Kullberg, S. [Geodesign AB, Linkoeping (Sweden)

    1995-05-01

    This study deals with the immobilization of heavy metals and other elements in flue gas ashes from household waste incineration by the addition of phosphates to the ash. It also describes the FUDD-technique (FUnction-adapted Design and Deposition) for deposition of the stabilized ash. In this work, phosphates obtained from phosphoric acid have been added to ash in proportions of 2.8% and 3.7% by weight of ash. Phosphates have also been injected into the flue gases, in this case with proportions of 4.7% and 16.3%. The samples have been studied both in the field and in the laboratory in regard to compaction properties, permeability, chemical solid phase content, HCl in the flue gases, leaching of metals via batch tests, availability tests and column tests. In batch tests, the stabilized samples show an immobilization of most metals except cadmium. Lead has been reduced by 97.0-99.9%. Cadmium has been mobilized by a factor of 2-30 in this experiment. The best results are obtained with addition of phosphates to the flue gases. In the availability tests, with addition of phosphates to flue gases, all environmentally destructive metals except arsenic and nickel have been immobilized to varying degree. The reduction is greatest for lead, aluminium, copper, mercury and zinc. With the addition of phosphates to ash, aluminium, copper and lead have been immobilized. In opposite, arsenic, cobalt and nickel were mobilized. The addition of 4-5% phosphates in the flue gas reactor produced only a marginal effect on the HCl concentration in the flue gases. The use of phosphates increases the HF concentration by about 3 mg/Nm{sup 3}. The cost for phosphate stabilization have been estimated at SEK 110-220 per ton of ash including costs for stabilization equipment. 18 refs, 15 figs, 13 tabs

  5. Chemical associations and mobilization of heavy metals in fly ash from municipal solid waste incineration.

    Science.gov (United States)

    Weibel, Gisela; Eggenberger, Urs; Schlumberger, Stefan; Mäder, Urs K

    2017-04-01

    This study focusses on chemical and mineralogical characterization of fly ash and leached filter cake and on the determination of parameters influencing metal mobilization by leaching. Three different leaching processes of fly ash from municipal solid waste incineration (MSWI) plants in Switzerland comprise neutral, acidic and optimized acidic (+ oxidizing agent) fly ash leaching have been investigated. Fly ash is characterized by refractory particles (Al-foil, unburnt carbon, quartz, feldspar) and newly formed high-temperature phases (glass, gehlenite, wollastonite) surrounded by characteristic dust rims. Metals are carried along with the flue gas (Fe-oxides, brass) and are enriched in mineral aggregates (quartz, feldspar, wollastonite, glass) or vaporized and condensed as chlorides or sulphates. Parameters controlling the mobilization of neutral and acidic fly ash leaching are pH and redox conditions, liquid to solid ratio, extraction time and temperature. Almost no depletion for Zn, Pb, Cu and Cd is achieved by performing neutral leaching. Acidic fly ash leaching results in depletion factors of 40% for Zn, 53% for Cd, 8% for Pb and 6% for Cu. The extraction of Pb and Cu are mainly limited due to a cementation process and the formation of a PbCu 0 -alloy-phase and to a minor degree due to secondary precipitation (PbCl 2 ). The addition of hydrogen peroxide during acidic fly ash leaching (optimized acidic leaching) prevents this reduction through oxidation of metallic components and thus significantly higher depletion factors for Pb (57%), Cu (30%) and Cd (92%) are achieved. The elevated metal depletion using acidic leaching in combination with hydrogen peroxide justifies the extra effort not only by reduced metal loads to the environment but also by reduced deposition costs. Copyright © 2016 Elsevier Ltd. All rights reserved.

  6. Geotechnical characterization of a Municipal Solid Waste Incineration Ash from a Michigan monofill.

    Science.gov (United States)

    Zekkos, Dimitrios; Kabalan, Mohammad; Syal, Sita Marie; Hambright, Matt; Sahadewa, Andhika

    2013-06-01

    A field and laboratory geotechnical characterization study of a Municipal Solid Waste Incineration Ash disposed of at the Carleton Farms monofill in Michigan was performed. Field characterization consisted of field observations, collection of four bulk samples and performance of shear wave velocity measurements at two locations. Laboratory characterization consisted of basic geotechnical characterization, i.e., grain size distribution, Atterberg limits, specific gravity tests, compaction tests as well as moisture and organic content assessment followed by direct shear and triaxial shear testing. The test results of this investigation are compared to results in the literature. The grain size distribution of the samples was found to be very similar and consistent with the grain size distribution data available in the literature, but the compaction characteristics were found to vary significantly. Specific gravities were also lower than specific gravities of silicic soils. Shear strengths were higher than typically reported for sandy soils, even for MSWI ash specimens at a loose state. Strain rate was not found to impact the shear resistance. Significant differences in triaxial shear were observed between a dry and a saturated specimen not only in terms of peak shear resistance, but also in terms of stress-strain response. In situ shear wave velocities ranged from 500 to 800 m/s at a depth of about 8m, to 1100-1200 m/s at a depth of 50 m. These high shear wave velocities are consistent with field observations indicating the formation of cemented blocks of ash with time, but this "ageing" process in MSWI ash is still not well understood and additional research is needed. An improved understanding of the long-term behavior of MSWI ash, including the effects of moisture and ash chemical composition on the ageing process, as well as the leaching characteristics of the material, may promote unbound utilization of the ash in civil infrastructure. Copyright © 2013 Elsevier

  7. Characterisation and management of ash produced in the hospital waste incinerator of Athens, Greece

    Energy Technology Data Exchange (ETDEWEB)

    Kougemitrou, Irene [Harokopio University of Athens, 70 El. Venizelou Str., 17671 Athens (Greece); Godelitsas, Athanasios, E-mail: agodel@geol.uoa.gr [University of Athens, Panepistimioupoli Zographou, 15784 Athens (Greece); Tsabaris, Christos [Hellenic Center of Marine Research, 19013 Anavyssos (Greece); Stathopoulos, Vassilis [Technological Educational Institute of Chalkida, 34400 Psahna (Greece); Papandreou, Andreas [CERECO S.A. Ceramics and Refractories Technological Development Company, 34100 Chalkida (Greece); Gamaletsos, Platon [University of Athens, Panepistimioupoli Zographou, 15784 Athens (Greece); Economou, George [Institute of Geology and Mineral Exploration, Olympic Village, 13677 Acharnai (Greece); Papadopoulos, Dimitris [APOTEFROTIRAS S.A., Ano Liossia, 19200 Elefsina (Greece)

    2011-03-15

    Bottom and fly ash samples (BASH and FASH) from the APOTEFROTIRAS S.A. medical waste incinerator (Athens, Greece) were investigated. Powder-XRD data and geochemical diagrams showed BASH to be an amorphous material, analogous to basaltic glass, and FASH consisting of crystalline compounds (mainly CaClOH). Bulk analyses by ICP-MS and point analyses by SEM-EDS indicated a high content of heavy metals, such as Fe, Cu and Cr, in both samples. However, BASH was highly enriched in Ni while FASH was additionally enriched in Zn and Pb. Gamma-ray measurements showed that the radioactivity of both ash samples, due to natural and artificial radionuclides ({sup 137}Cs, {sup 57}Co), was within the permissible levels recommended by IAEA. According to EN-type leaching tests, BASH was practically inert with regard to the mobility of the hazardous elements in aqueous media. FASH, however, showed a relatively high EN (and TCLP) leachability with regard to Pb and Zn. Finally, the stabilisation method, suggested for the treatment of FASH, included compression of the powder into briquettes using an appropriate machine and embedding the briquettes into pozzolanic cement blocks. After this treatment, TCLP and EN-type tests showed minimal release of Pb and Zn, thereby demonstrating a reliable management of ash waste.

  8. The leaching of trace elements from municipal solid waste incinerator bottom ash at different stages of weathering

    NARCIS (Netherlands)

    Meima, J.A.; Comans, R.N.J.

    1999-01-01

    For a proper assessment of the environmental impact of the utilisation and disposal of Municipal Solid Waste Incinerator (MSWI) bottom ash it is necessary to understand weathering processes and their effects on (trace) element leaching. The authors have investigated the processes that control the

  9. Greenlandic Waste Incineration Fly And Bottom Ash As Secondary Resource In Mortar

    DEFF Research Database (Denmark)

    Kirkelund, Gunvor Marie; Ottosen, Lisbeth M.; Jensen, Pernille Erland

    2016-01-01

    , the effects on compressive strengths of mortars by substituting cement or sand by raw, washed and electrodialytically treated fly ash or bottom ash were investigated. Parts of the experimental fly ash had been pre-treated by either washing with distilled water or electro-dialytically treated to remove salts...... and by the latter method, also heavy metals. Mortar samples were cast where cement (5%–20%) or sand (5%–10%) was replaced with fly ash or bottom ash, together with references without replacements. The compressive strengths were measured after 7, 14, 28 and 42 days. Replacing cement by fly ash resulted in lower...... and cement with fly ash. Based on the compressive strength tests, it is found that using Greenlandic incineration ashes in mortar as 5% cement replacement could consume all ash instead of disposals, and could thus turn the ashes into a local resource and simultaneously reduce the import of cement....

  10. Relation between leaching characteristics of heavy metals and physical properties of fly ashes from typical municipal solid waste incinerators.

    Science.gov (United States)

    Ni, Peng; Li, Hailong; Zhao, Yongchun; Zhang, Junying; Zheng, Chuguang

    2017-09-01

    Due to the alkalinity and high concentration of potentially hazardous heavy metals, fly ash from a municipal solid waste (MSW) incinerator is classified as hazardous waste, which should be of particular concern. Physical and chemical characterizations of the contrasted fly ashes were investigated to explore the relation between leaching characteristics of heavy metals and physical properties of fly ashes. The results showed that CaClOH, NaCl, Ca(OH)2, KCl and SiO2 were primary mineral compositions in the MSWI fly ashes, and the particle size distribution of fly ash ranged between 10 μm and 300 μm. The smaller the particle size distribution of fly ash, the larger the BET-specific surface area, which was beneficial to the leaching of heavy metals. As a result of various pores, it easily accumulated heavy metals as well. The leaching tests exhibited a high leachability of heavy metals and the leaching concentration of Pb in almost all of the fly ash samples went far beyond the Standard for Pollution Control on the Landfill Site of Municipal Solid Waste. Thereupon, it is necessary to establish proper disposal systems and management strategies for environmental protection based on the characteristics of MSW incineration (MSWI) fly ash in China.

  11. Landfilling of waste incineration residues

    DEFF Research Database (Denmark)

    Christensen, Thomas Højlund; Astrup, Thomas; Cai, Zuansi

    2002-01-01

    Residues from waste incineration are bottom ashes and air-pollution-control (APC) residues including fly ashes. The leaching of heavy metals and salts from the ashes is substantial and a wide spectrum of leaching tests and corresponding criteria have been introduced to regulate the landfilling...

  12. Achieving zero waste of municipal incinerator fly ash by melting in electric arc furnaces while steelmaking.

    Science.gov (United States)

    Yang, Gordon C C; Chuang, Tsun-Nan; Huang, Chien-Wen

    2017-04-01

    The main objective of this work was to promote zero waste of municipal incinerator fly ash (MIFA) by full-scale melting in electric arc furnaces (EAFs) of steel mini mills around the world. MIFA, generally, is considered as a hazardous waste. Like in many countries, MIFA in Taiwan is first solidified/stabilized and then landfilled. Due to the scarcity of landfill space, the cost of landfilling increases markedly year by year in Taiwan. This paper presents satisfactory results of treating several hundred tons of MIFA in a full-scale steel mini mill using the approach of "melting MIFA while EAF steelmaking", which is somewhat similar to "molten salt oxidation" process. It was found that this practice yielded many advantages such as (1) about 18wt% of quicklime requirement in EAF steelmaking can be substituted by the lime materials contained in MIFA; (2) MIFA would totally end up as a material in fractions of recyclable EAF dust, oxidized slag and reduced slag; (3) no waste is needed for landfilling; and (4) a capital cost saving through the employment of existing EAFs in steel mini mills instead of building new melting plants for the treatment of MIFA. Thus, it is technically feasible to achieve zero waste of MIFA by the practice of this innovative melting technology. Copyright © 2017 Elsevier Ltd. All rights reserved.

  13. Innovative treatment trains of bottom ash (BA) from municipal solid waste incineration (MSWI) in Germany.

    Science.gov (United States)

    Holm, Olaf; Simon, Franz-Georg

    2017-01-01

    The industrial sector of bottom ash (BA) treatment from municipal solid waste incineration (MSWI) in Germany is currently changing. In order to increase the recovery rates of metals or to achieve a higher quality of mineral aggregates derived from BA, new procedures have been either implemented to existing plants or completely new treatment plants have been built recently. Three treatment trains, which are designated as entire sequences of selected processing techniques of BA, are introduced and compared. One treatment train is mainly characterized by usage of a high speed rotation accelerator whereas another is operating completely without crushing. In the third treatment train the BA is processed wet directly after incineration. The consequences for recovered metal fractions and the constitution of remaining mineral aggregates are discussed in the context of legislative and economical frameworks. Today the recycling or disposal options of mineral residues still have a high influence on the configuration and the operation mode of the treatment trains of BA despite of the high value of recovered metals. Copyright © 2016 Elsevier Ltd. All rights reserved.

  14. Metallic elements occurrences within metallic fragments in the municipal waste incineration bottom ash

    Science.gov (United States)

    Kowalski, Piotr; Kasina, Monika; Michalik, Marek

    2017-04-01

    Bottom ash (BA) from municipal solid waste incineration (MSWI) is composed of grainy ash material, residual components and metallic fragments (from few µm up to 3-5 cm). Its mineral and chemical composition is related to the composition of the waste stream in the incinerator operational area. Wide use of thermal techniques in management of solid waste makes important the studies on valuable components and their distribution within the material in terms of their further processing. By using various valorization or extraction techniques it is possible to extend the range of its possible further application. To investigate metallic elements distribution within metallic fragments of the MSWI BA material produced in municipal waste incineration plant in Poland were collected in 2015 and 2016. BA and its components were investigated using spectroscopic methods of chemical analysis: ICP-OES, ICP-MS, LECO and EDS (used for microanalysis during SEM observations). BA is a material rich in Si (22.5 wt%), Ca (13.4 wt%), Fe (4 wt%), Al (5.2 wt%) and Na (3.5 wt%), composed of equal part of amorphous (silicate glass dominated) and crystalline phase (rich in silicates, aluminosilicates, oxides of non- and metallic elements and sulphates). The content of metallic elements (Al, Fe, Mg, Ti, Mn, Cr, Ni, Sc, Mo, Cu, Pb, Zn, Sn) is 11.5 wt% with domination of Al (5.2 wt%) and Fe (4 wt%) and elevated values of Mg (1 wt%), Ti (0.54 wt%), Cu (0.26 wt%) and Zn (0.27 wt%) (Kowalski et al., 2016). They were mostly concentrated in the form of metallic fragments, mainly as metallic inclusions in the size of 1-20 µm and separated metallic grains in the size of 50-300 µm. Metallic fragments present in the BA are characterized by their composition heterogeneity and various oxygen content. Fragments are rarely composed of single metallic element and usually in their composition up to few main elements dominated over others. The most common were Fe-, Al- and Zn-rich fragments forming respectively

  15. Enrichment and distribution of 24 elements within the sub-sieve particle size distribution ranges of fly ash from wastes incinerator plants.

    Science.gov (United States)

    Raclavská, Helena; Corsaro, Agnieszka; Hartmann-Koval, Silvie; Juchelková, Dagmar

    2017-12-01

    The management of an increasing amount of municipal waste via incineration has been gaining traction. Fly ash as a by-product of incineration of municipal solid waste is considered a hazardous waste due to the elevated content of various elements. The enrichment and distribution of 24 elements in fly ash from three wastes incinerators were evaluated. Two coarse (>100 μm and particle size fractions separated on a cyclosizer system were analyzed. An enhancement in the enrichment factor was observed in all samples for the majority of elements in >100 μm range compared with particle size ranges. These variations were attributed primarily to: (i) the vaporization and condensation mechanisms, (ii) the different design of incineration plants, (iii) incineration properties, (iv) the type of material being incinerated, and (v) the affinity of elements. Copyright © 2017 Elsevier Ltd. All rights reserved.

  16. Re-use of stabilised flue gas ashes from solid waste incineration in cement-treated base layers for pavements.

    Science.gov (United States)

    Cai, Zuansi; Jensen, Dorthe L; Christensen, Thomas H; Bager, Dirch H

    2003-02-01

    Fly ash from coal-burning power plants has been used extensively as a pozzolan and fine filler in concrete for many years. Laboratory experiments were performed investigating the effect of substituting the coal-based fly ash with chemically stabilised flue gas ashes (FGA) from waste incineration. Two types of FGA were treated by the Ferrox-process, which removes the majority of the easily soluble salts in the FGA and provides binding sites for heavy metals in terms of ferrihydrite. Cubes of cement treated base layer materials containing 5% stabilised FGA were cast, sealed and cured for two weeks. Cylinders (diameter 100 mm, length 150 mm) were drilled from these cubes for tank leaching experiments. Duplicate specimens were subject to compression strength testing and to tank leaching experiments. The compressive strength of the CTB fulfilled the Danish requirements for CTB, i.e. strength more than 5 MPa after 7 days. The tank leaching tests revealed that leaching of heavy metals was not significantly affected by the use of chemically stabilised flue gas ashes from waste incineration. Assuming that diffusion controls the leaching process it was calculated that less than 1% of the metals would leach during a 100-year period from a 0.5 m thick concrete slab exposed to water on one side. Leaching of the common ions Ca, Cl, Na and SO4 was increased 3-20 times from the specimens with chemically stabilised flue gas ashes from waste incineration. However, the quantities leached were still modest. These experiments suggest that FGA from waste incineration after Ferrox-treatment could be re-used in CTB without compromising the strength and leaching from the base layer.

  17. Geotechnical engineering properties of incinerator ash mixes.

    Science.gov (United States)

    Muhunthan, B; Taha, R; Said, J

    2004-08-01

    The incineration of solid waste produces large quantities of bottom and fly ash. Landfilling has been the primary mode of disposal of these waste materials. Shortage in landfill space and the high cost of treatment have, however, prompted the search for alternative uses of these waste materials. This study presents an experimental program that was conducted to determine the engineering properties of incinerator ash mixes for use as construction materials. Incinerator ash mixes were tested as received and around optimum compacted conditions. Compaction curves, shear strength, and permeability values of fly ash, bottom ash, and their various blends were investigated. Bottom ash tends to achieve maximum dry density at much lower water content than does fly ash. The mixes displayed a change in their cohesion and friction angle values when one of the two mix components was altered or as a result of the addition of water. The permeability of bottom ash is quite comparable to that of sand. The permeability of fly ash lies in the range of those values obtained for silts and clays. A 100% bottom ash compacted at the optimum water content has a lower density value and yields a higher friction angle and cohesion values than most construction fills. This would encourage the use of bottom ash as a fill or embankment material because free drainage of water will prevent the buildup of pore water pressures.

  18. Experimental investigation of ash deposits on convection heating surfaces of a circulating fluidized bed municipal solid waste incinerator.

    Science.gov (United States)

    Tang, Zhi; Chen, Xiaoping; Liu, Daoyin; Zhuang, Yaming; Ye, Minghua; Sheng, Hongchan; Xu, Shaojuan

    2016-10-01

    Incineration of municipal solid waste (MSW) is a waste treatment method which can be sustainable in terms of waste volume reduction, as well as a source of renewable energy. During MSW combustion, increased formation of deposits on convection heating exchanger surfaces can pose severe operational problems, such as fouling, slagging and corrosion. These problems can cause lower heat transfer efficiency from the hot flue gas to the working fluid inside the tubes. A study was performed where experiments were carried out to examine the ash deposition characteristics in a full-scale MSW circulating fluidized bed (CFB) incinerator, using a newly designed deposit probe that was fitted with six thermocouples and four removable half rings. The influence of probe exposure time and probe surface temperature (500, 560, and 700°C) on ash deposit formation rate was investigated. The results indicate that the deposition mass and collection efficiency achieve a minimum at the probe surface temperature of 560°C. Ash particles are deposited on both the windward and leeward sides of the probe by impacting and thermophoretic/condensation behavior. The major inorganic elements present in the ash deposits are Ca, Al and Si. Compared to ash deposits formed on the leeward side of the probe, windward-side ash deposits contain relatively higher Ca and S concentrations, but lower levels of Al and Si. Among all cases at different surface temperatures, the differences in elemental composition of the ash deposits from the leeward side are insignificant. However, as the surface temperature increases, the concentrations of Al, Si, K and Na in the windward-side ash deposits increase, but the Ca concentration is reduced. Finally, governing mechanisms are proposed on the basis of the experimental data, such as deposit morphology, elemental composition and thermodynamic calculations. Copyright © 2016. Published by Elsevier B.V.

  19. Modified fly ash from municipal solid waste incineration as catalyst support for Mn-Ce composite oxides

    Science.gov (United States)

    Chen, Xiongbo; Liu, Ying; Yang, Ying; Ren, Tingyan; Pan, Lang; Fang, Ping; Chen, Dingsheng; Cen, Chaoping

    2017-08-01

    Fly ash from municipal solid waste incineration was modified by hydrothermal treatment and used as catalyst support for Mn-Ce composite oxides. The prepared catalyst showed good activity for the selective catalytic reduction (SCR) of NO by NH3. A NO conversion of 93% could be achieved at 300 °C under a GHSV of 32857 h-1. With the help of characterizations including XRD, BET, SEM, TEM, XPS and TPR, it was found that hydrothermal treatment brought a large surface area and abundant mesoporous to the modified fly ash, and Mn-Ce composite oxides were highly dispersed on the surface of the support. These physical and chemical properties were the intrinsic reasons for the good SCR activity. This work transformed fly ash into high value-added products, providing a new approach to the resource utilization and pollution control of fly ash.

  20. The Use of Municipal Solid Waste Incineration Ash in Various Building Materials: A Belgian Point of View

    Directory of Open Access Journals (Sweden)

    Aneeta Mary Joseph

    2018-01-01

    Full Text Available Huge amounts of waste are being generated, and even though the incineration process reduces the mass and volume of waste to a large extent, massive amounts of residues still remain. On average, out of 1.3 billion tons of municipal solid wastes generated per year, around 130 and 2.1 million tons are incinerated in the world and in Belgium, respectively. Around 400 kT of bottom ash residues are generated in Flanders, out of which only 102 kT are utilized here, and the rest is exported or landfilled due to non-conformity to environmental regulations. Landfilling makes the valuable resources in the residues unavailable and results in more primary raw materials being used, increasing mining and related hazards. Identifying and employing the right pre-treatment technique for the highest value application is the key to attaining a circular economy. We reviewed the present pre-treatment and utilization scenarios in Belgium, and the advancements in research around the world for realization of maximum utilization are reported in this paper. Uses of the material in the cement industry as a binder and cement raw meal replacement are identified as possible effective utilization options for large quantities of bottom ash. Pre-treatment techniques that could facilitate this use are also discussed. With all the research evidence available, there is now a need for combined efforts from incineration and the cement industry for technical and economic optimization of the process flow.

  1. Phosphate bonded solidification of radioactive incinerator wastes

    Energy Technology Data Exchange (ETDEWEB)

    Walker, B. W.; Langton, C. A.; Singh, D.

    1999-12-03

    The incinerator at the Department of Energy Savannah River Site burns low level radioactive and hazardous waste. Ash and scrubber system waste streams are generated during the incineration process. Phosphate Ceramic technology is being tested to verify the ash and scrubber waste streams can be stabilized using this solidification method. Acceptance criteria for the solid waste forms include leachability, bleed water, compression testing, and permeability. Other testing on the waste forms include x-ray diffraction and scanning electron microscopy.

  2. Improved cement mortars by addition of carbonated fly ash from solid waste incinerators

    Directory of Open Access Journals (Sweden)

    López-Zaldívar, O.

    2015-09-01

    Full Text Available This article presents the results of a research developing high performance cement mortars with the addition of municipal solid waste incineration fly ash (MSWIFA stabilized as insoluble carbonates. The encapsulation of hazardous wastes in mortar matrixes has also been achieved. The ashes present high concentrations of chlorides, Zn and Pb. A stabilization process with NaHCO3 has been developed reducing 99% the content of chlorides. Developed mortars replace 10% per weight of the aggregates by treated MSWIFA. Physical/mechanical properties of these mortars have been studied. Presence of Zn, Pb, Cu and Cd has been also analyzed confirming that leaching of these heavy metal ions is mitigated. Conclusions prove better behavior of CAC and CSA mortars than those of CEM-I and CEM-II cement. Results are remarkable for the CAC mortars, improving reference strengths in more than 25%, which make them a fast-curing product suitable for the repair of structures or industrial pavements.Este artículo presenta los resultados del desarrollo de morteros mejorados con la incorporación de cenizas volantes de residuos sólidos urbanos inertizadas en forma de carbonatos. Además se consigue la encapsulación de un residuo peligroso. Las cenizas presentan una alta concentración de cloruros, Zn y Pb. Se ha desarrollado un proceso de estabilización con NaHCO3 reduciendo en un 99% el contenido de cloruros. Los morteros reemplazan un 10% en peso del árido por cenizas tratadas. Se han analizado sus propiedades físico/mecánicas y la presencia de Zn, Pb, Cu y Cd. Se demuestra un mejor comportamiento de los morteros de CAC y CSA que los de CEM-I y CEM-II y se mitiga el lixiviado de metales pesados. Los resultados son significativos en los morteros CAC al mejorar las resistencias de los de referencia en un 25%. Los morteros desarrollados son de curado rápido adecuados para la reparación de estructuras o soleras industriales.

  3. Municipal solid waste incineration bottom ash: environmental and recycling-related properties; Muellverbrennungsschlacken: umwelt- und verwertungsrelevante Eigenschaften

    Energy Technology Data Exchange (ETDEWEB)

    Riedel, H. [Bayerisches Landesamt fuer Umweltschutz, Augsburg (Germany). Josef-Vogt-Technikum

    2004-07-01

    Re-utilisation of municipal solid waste incinerator (MSWI) bottom ash in civil engineering requires compliance with quality standards defined in term of bulk and leachate concentrations. In addition, solid phase properties comparable to natural construction materials are necessary. Addressing the perspectives and possible constraints of bottom ash recycling, this study includes the results of laboratory analyses, a field leaching experiment, and a survey of several construction projects in which MSWI bottom ash was used as a grounding material. (orig.) [German] Im Rahmen zweier Forschungsvorhaben wurden die umwelt- und verwertungsrelevanten Eigenschaften von Muellverbrennungsschlacke (MV-Schlacke) eingehend untersucht. Aufbau, Schadstoffgehalt und Auslaugverhalten von Schlacke sowie die Eignung von Schlacke fuer den Einsatz bei Bauvorhaben standen als zwei Schwerpunkte im Vordergrund. Der Einsatz von MV-Schlacke als Sekundaerrohstoff z.B. in Bauvorhaben stellt entsprechend der Untersuchungsergebnisse eine sinnvolle Verwertungsmoeglichkeit dar. (orig.)

  4. Recycling of Pre-Washed Municipal Solid Waste Incinerator Fly Ash in the Manufacturing of Low Temperature Setting Geopolymer Materials

    Directory of Open Access Journals (Sweden)

    Raffaele Cioffi

    2013-08-01

    Full Text Available In this work, three samples of municipal solid waste incinerators fly ash (MSWI-FA have been stabilized in systems containing coal fly ash to create geopolymers through a polycondensation reaction. Monolithic products have been obtained with both MSWI fly ash as received and after the partial removal of chloride and sulfate by water washing. The polycondensation products have been characterized qualitatively by means of Fourier transform infrared spectroscopy, X-ray diffraction and scanning electron microscopy and quantitatively, through the determination of the volume of reacted water and silicate. Furthermore, the heavy metals and chloride releases together with the physico-mechanical properties have been evaluated on the hardened products. In conclusion, considering the technological and environmental performances of the obtained geopolymers, they could be suitable for many non-structural applications, such as backfilling of abandoned quarries, decorative materials or brick fireplaces, hearths, patios, etc.

  5. Recycling of Pre-Washed Municipal Solid Waste Incinerator Fly Ash in the Manufacturing of Low Temperature Setting Geopolymer Materials.

    Science.gov (United States)

    Ferone, Claudio; Colangelo, Francesco; Messina, Francesco; Santoro, Luciano; Cioffi, Raffaele

    2013-08-12

    In this work, three samples of municipal solid waste incinerators fly ash (MSWI-FA) have been stabilized in systems containing coal fly ash to create geopolymers through a polycondensation reaction. Monolithic products have been obtained with both MSWI fly ash as received and after the partial removal of chloride and sulfate by water washing. The polycondensation products have been characterized qualitatively by means of Fourier transform infrared spectroscopy, X-ray diffraction and scanning electron microscopy and quantitatively, through the determination of the volume of reacted water and silicate. Furthermore, the heavy metals and chloride releases together with the physico-mechanical properties have been evaluated on the hardened products. In conclusion, considering the technological and environmental performances of the obtained geopolymers, they could be suitable for many non-structural applications, such as backfilling of abandoned quarries, decorative materials or brick fireplaces, hearths, patios, etc.

  6. Migration of nitrate, nitrite, and ammonia through the municipal solid waste incinerator bottom ash layer in the simulated landfill.

    Science.gov (United States)

    Yao, Jun; Chen, Luxi; Zhu, Huayue; Shen, Dongsheng; Qiu, Zhanhong

    2017-04-01

    Simulated landfill was operated for 508 days to investigate the effect of municipal solid waste incinerator (MSWI) bottom ash layer on the migration of nitrate, nitrite, and ammonia when it was used as the intermediate layer in the landfill. The result suggested that the MSWI bottom ash layer could capture the nitrate, nitrite, and ammonia from the leachate. The adsorption of the nitrate, nitrite, and ammonia on the MSWI bottom ash layer was saturated at the days 396, 34, and 97, respectively. Afterwards, the nitrogen species were desorbed from the MSWI bottom ash layer. Finally, the adsorption and desorption could reach the equilibrium. The amounts of adsorbed nitrate and nitrite on the MSWI bottom ash layer were 1685.09 and 7.48 mg, respectively, and the amount of the adsorbed and transformed ammonia was 13,773.19 mg, which was much higher than the desorbed. The water leaching test and synthetic precipitation leaching procedure (SPLP) results showed that the leachable nitrate, nitrite, and ammonia in the MSWI bottom ash were greatly increased after the landfill operation, suggesting that the adsorbed nitrogen could be finally leached out. Besides, the results also showed that MSWI bottom ash layer could affect the release of nitrate and ammonia at the initial stage of the landfill. However, it had little effect on the release of nitrite.

  7. Use of municipal solid waste incineration bottom ashes in alkali-activated materials, ceramics and granular applications: A review.

    Science.gov (United States)

    Silva, R V; de Brito, J; Lynn, C J; Dhir, R K

    2017-10-01

    This paper presents a literature review on the incorporation of municipal solid waste incinerated bottom ash as raw material in several markets, other than those where it is conventionally used, such as geotechnical applications and road pavement construction. The main findings of an ample selection of experimental investigations on the use of the bottom ash as precursor of alkali-activated materials, as an adsorbent material for the removal of hazardous elements from wastewater and landfill gases, as soil replacement in agricultural activities, as partial or complete substitute of raw materials for the manufacture of ceramic-based products, as landfill cover and as biogas production enhancer, were gathered, collated and analysed. Copyright © 2017 Elsevier Ltd. All rights reserved.

  8. Leachability of Heavy Metals from Lightweight Aggregates Made with Sewage Sludge and Municipal Solid Waste Incineration Fly Ash

    Science.gov (United States)

    Wei, Na

    2015-01-01

    Lightweight aggregate (LWA) production with sewage sludge and municipal solid waste incineration (MSWI) fly ash is an effective approach for waste disposal. This study investigated the stability of heavy metals in LWA made from sewage sludge and MSWI fly ash. Leaching tests were conducted to find out the effects of MSWI fly ash/sewage sludge (MSWI FA/SS) ratio, sintering temperature and sintering time. It was found that with the increase of MSWI FA/SS ratio, leaching rates of all heavy metals firstly decreased and then increased, indicating the optimal ratio of MSWI fly ash/sewage sludge was 2:8. With the increase of sintering temperature and sintering time, the heavy metal solidifying efficiencies were strongly enhanced by crystallization and chemical incorporations within the aluminosilicate or silicate frameworks during the sintering process. However, taking cost-savings and lower energy consumption into account, 1100 °C and 8 min were selected as the optimal parameters for LWA sample- containing sludge production. Furthermore, heavy metal leaching concentrations under these optimal LWA production parameters were found to be in the range of China’s regulatory requirements. It is concluded that heavy metals can be properly stabilized in LWA samples containing sludge and cannot be easily released into the environment again to cause secondary pollution. PMID:25961800

  9. Agglomeration potential of TiO2 in synthetic leachates made from the fly ash of different incinerated wastes.

    Science.gov (United States)

    He, Xu; Mitrano, Denise M; Nowack, Bernd; Bahk, Yeon Kyoung; Figi, Renato; Schreiner, Claudia; Bürki, Melanie; Wang, Jing

    2017-04-01

    Material flow studies have shown that a large fraction of the engineered nanoparticles used in products end up in municipal waste. In many countries, this municipal waste is incinerated before landfilling. However, the behavior of engineered nanoparticles (ENPs) in the leachates of incinerated wastes has not been investigated so far. In this study, TiO2 ENPs were spiked into synthetic landfill leachates made from different types of fly ash from three waste incineration plants. The synthetic leachates were prepared by standard protocols and two types of modified procedures with much higher dilution ratios that resulted in reduced ionic strength. The pH of the synthetic leachates was adjusted in a wide range (i.e. pH 3 to 11) to understand the effects of pH on agglomeration. The experimental results indicated that agglomeration of TiO2 in the synthetic landfill leachate simultaneously depend on ionic strength, ionic composition and pH. However, when the ionic strength was high, the effects of the other two factors were masked. The zeta potential of the particles was directly related to the size of the TiO2 agglomerates formed. The samples with an absolute zeta potential value < 10 mV were less stable, with the size of TiO2 agglomerates in excess of 1500 nm. It can be deduced from this study that TiO2 ENPs deposited in the landfill may be favored to form agglomerates and ultimately settle from the water percolating through the landfill and thus remain in the landfill. Copyright © 2017 Elsevier Ltd. All rights reserved.

  10. Stabilization treatment of the heavy metals in fly ash from municipal solid waste incineration using diisopropyl dithiophosphate potassium.

    Science.gov (United States)

    Xu, Ying; Chen, Yu; Feng, Yueyang

    2013-01-01

    A stabilization treatment was developed for heavy metals in fly ash from municipal solid waste incineration using the heavy metal chelator diisopropyl dithiophosphate potassium (DDP). The mechanism and effect of the DDP chelator treatment on heavy metals in the fly ash was also studied, along with the form transformation rules of the heavy metals after DDP chelator treatment. The results show that 1% DDP achieves a stabilization rate of over 95% for Pb, Zn, and Cd. The effect of DDP was better than that of inorganic stabilizers such as sodium sulphide and lime. The heavy metal concentrations in the leachate after the treatment were lower than those required by the Pollution Control Standards for Hazardous Waste Landfill (GB18598-2001). At pH 1-13, the heavy metal concentrations in the fly ash leachate were far lower than those using the inorganic stabilizers sodium sulphide and lime. DDP retains its stabilizing effect under a broader pH range. After stabilization treatment, the heavy metals in the exchangeable fraction and those bound to carbonates were mainly transformed into those bound to organic matter. This process decreases the unstable content and reduces the risk of secondary pollution of the stabilized products in the environment.

  11. Thermal Properties of Cement Based Composites with Municipal Solid Waste Incinerator Fly Ash Accessed by Two Different Transient Methods

    Directory of Open Access Journals (Sweden)

    Jan FOŘT

    2016-05-01

    Full Text Available Thermal properties of cement composite with Mixed Fly Ash (MFA from different parts of Municipal Solid Waste Incineration (MSWI process as a partial replacement of Portland cement are researched in the paper. MFA is applied in the amount of 10 %, 20 % and 30 % of the mass of cement, while sand and water quantities are kept constant. For the sake of comparison, a reference mixture with Portland cement as the only binder is studied as well. For the characterization of studied materials, their basic physical properties as bulk density, matrix density and total open porosity are measured using gravimetric method combined with helium pycnometry. Among the thermal properties, thermal conductivity, thermal diffusivity and specific heat capacity are accessed by two transient methods having different experimental arrangement and time of measurement. The measured data obtained by the particular methods are compared and the applicability of the methods for the measurement of thermal properties of solid building materials is discussed.

  12. [Bioleaching of fly ash from municipal solid waste incinerator using sewage sludge and pig manure as culture media].

    Science.gov (United States)

    Zhou, Shun-gui; Chang, Ming; Hu, Pei; Ni, Jin-ren

    2005-11-01

    A mixed culture of Acidihiobacillus ferrooaidans and Acidihiobacillus thiooxidans was used to leach heavy metals from municipal solid waste incineration fly ash (MSWI fly ash). This study explored the possibility of using sewage sludge or pig manure as nutrients for supporting the growth of the leaching bacteria and allowing metal solubilization like a synthetic mineral medium. In contrast to pig manure, there is a high ability for acidification of the fly ash and solubilization of toxic metals using sewage sludge at the same content. After 15 d of bioleaching, the following removal efficiencies were obtained for the treatment with the addition of 1% sewage sludge: Cd 88.1%; Zn 78.7%; Cu 69.6%, whereas their removal efficiencies for the treatment with the addition of 1% pig manure were 82.4%, 73.5% and 60.0%, respectively. Results demonstrate that the inhibition by sewage sludge DOM is much more significant than by pig manure DOM at the same concentration level. The dissolved organic carbon in excess of 400 and 150 mg/L was inhibitory to the bacterial growth using sludge DOM and manure DOM, respectively. Compared with sewage sludge, pig manure contained a higher fraction of DOM with molecular size <1000, which led to its higher toxicity.

  13. Rice Husk Ash to Stabilize Heavy Metals Contained in Municipal Solid Waste Incineration Fly Ash: First Results by Applying New Pre-treatment Technology.

    Science.gov (United States)

    Benassi, Laura; Franchi, Federica; Catina, Daniele; Cioffi, Flavio; Rodella, Nicola; Borgese, Laura; Pasquali, Michela; Depero, Laura E; Bontempi, Elza

    2015-10-09

    A new technology was recently developed for municipal solid waste incineration (MSWI) fly ash stabilization, based on the employment of all waste and byproduct materials. In particular, the proposed method is based on the use of amorphous silica contained in rice husk ash (RHA), an agricultural byproduct material (COSMOS-RICE project). The obtained final inert can be applied in several applications to produce "green composites". In this work, for the first time, a process for pre-treatment of rice husk, before its use in the stabilization of heavy metals, based on the employment of Instant Pressure Drop technology (DIC) was tested. The aim of this work is to verify the influence of the pre-treatment on the efficiency on heavy metals stabilization in the COSMOS-RICE technology. DIC technique is based on a thermomechanical effect induced by an abrupt transition from high steam pressure to a vacuum, to produce changes in the material. Two different DIC pre-treatments were selected and thermal annealing at different temperatures were performed on rice husk. The resulting RHAs were employed to obtain COSMOS-RICE samples, and the stabilization procedure was tested on the MSWI fly ash. In the frame of this work, some thermal treatments were also realized in O2-limiting conditions, to test the effect of charcoal obtained from RHA on the stabilization procedure. The results of this work show that the application of DIC technology into existing treatment cycles of some waste materials should be investigated in more details to offer the possibility to stabilize and reuse waste.

  14. Rice Husk Ash to Stabilize Heavy Metals Contained in Municipal Solid Waste Incineration Fly Ash: First Results by Applying New Pre-treatment Technology

    Directory of Open Access Journals (Sweden)

    Laura Benassi

    2015-10-01

    Full Text Available A new technology was recently developed for municipal solid waste incineration (MSWI fly ash stabilization, based on the employment of all waste and byproduct materials. In particular, the proposed method is based on the use of amorphous silica contained in rice husk ash (RHA, an agricultural byproduct material (COSMOS-RICE project. The obtained final inert can be applied in several applications to produce “green composites”. In this work, for the first time, a process for pre-treatment of rice husk, before its use in the stabilization of heavy metals, based on the employment of Instant Pressure Drop technology (DIC was tested. The aim of this work is to verify the influence of the pre-treatment on the efficiency on heavy metals stabilization in the COSMOS-RICE technology. DIC technique is based on a thermomechanical effect induced by an abrupt transition from high steam pressure to a vacuum, to produce changes in the material. Two different DIC pre-treatments were selected and thermal annealing at different temperatures were performed on rice husk. The resulting RHAs were employed to obtain COSMOS-RICE samples, and the stabilization procedure was tested on the MSWI fly ash. In the frame of this work, some thermal treatments were also realized in O2-limiting conditions, to test the effect of charcoal obtained from RHA on the stabilization procedure. The results of this work show that the application of DIC technology into existing treatment cycles of some waste materials should be investigated in more details to offer the possibility to stabilize and reuse waste.

  15. Integral recycling of municipal solid waste incineration (MSWI) bottom ash fines (0-2mm) and industrial powder wastes by cold-bonding pelletization.

    Science.gov (United States)

    Tang, P; Brouwers, H J H

    2017-04-01

    The cold-bonding pelletizing technique is applied in this study as an integrated method to recycle municipal solid waste incineration (MSWI) bottom ash fines (BAF, 0-2mm) and several other industrial powder wastes. Artificial lightweight aggregates are produced successfully based on the combination of these solid wastes, and the properties of these artificial aggregates are investigated and then compared with others' results reported in literature. Additionally, methods for improving the aggregate properties are suggested, and the corresponding experimental results show that increasing the BAF amount, higher binder content and addition of polypropylene fibres can improve the pellet properties (bulk density, crushing resistance, etc.). The mechanisms regarding to the improvement of the pellet properties are discussed. Furthermore, the leaching behaviours of contaminants from the produced aggregates are investigated and compared with Dutch environmental legislation. The application of these produced artificial lightweight aggregates are proposed according to their properties. Copyright © 2017 Elsevier Ltd. All rights reserved.

  16. Stabilization of lead in an alkali-activated municipal solid waste incineration fly ash-Pyrophyllite-based system.

    Science.gov (United States)

    Shiota, Kenji; Nakamura, Takafumi; Takaoka, Masaki; Aminuddin, Siti Fatimah; Oshita, Kazuyuki; Fujimori, Takashi

    2017-10-01

    This work focuses on the stabilization and speciation of lead (Pb) in a composite solid produced from an alkali-activated municipal solid waste incineration fly ash (MSWIFA)-pyophyllite-based system. The solid product was synthesized after mixtures of raw materials (dehydrated pyrophyllite, MSWIFA, 14 mol/L aqueous sodium hydroxide, and sodium silicate solution) were cured at 105 °C for 24 h. The product could reduce the leaching of Pb and the Pb concentration in the leachate was 7.0 × 10-3 using the Japanese leaching test and 9.7 × 10-4 mg/L using toxicity characteristics leaching procedure method, which satisfied the respective test criteria and successfully stabilized Pb in this system. The solid product had a compressive strength of 2 MPa and consisted mainly of crystalline phases. Scanning electron microscopy with X-ray analysis and X-ray absorption fine structure suggested that Pb was present along with Al, Si, and O, and that the atomic environment around the Pb was similar to that of PbSiO3. These results suggest that the alkali-activated MSWIFA-pyrophyllite-based system could be used to stabilize Pb in MSWIFA. Copyright © 2017 Elsevier Ltd. All rights reserved.

  17. Evaluation of the genotoxic, mutagenic and oxidant stress potentials of municipal solid waste incinerator bottom ash leachates

    Energy Technology Data Exchange (ETDEWEB)

    Radetski, C.M.; Ferrari, B.; Cotelle, S.; Masfaraud, J.-F.; Ferard, J.F

    2004-10-15

    Triplicate aqueous leachates of a municipal solid waste incineration bottom ash (MSWIBA) were produced according to a European standardised method. Leachates analysis showed relatively low concentrations (less than 1 mg{center_dot}l{sup -1}) for four metals (iron, cadmium, lead and copper). No mutagenic activity was revealed after performing the Salmonella/microsome assay with and without microsomal activation. With the Vicia root tip micronucleus assay, a significant increase in micronucleated cells was observed between 3.4% and 100% leachate concentration. Significant and elevated antioxidant stress enzyme activities, e.g., superoxide dismutase (SOD), catalase (CAT), peroxidase (PER) and glutathione reductase (GR), were detected in Vicia root tissues even at the lowest tested leachate concentration (i.e., 0.3%), whereas this was not always the case in leaf tissues, which showed tissue specificity for the tested enzymes. At the lowest concentration (i.e., 0.3%), a higher increase was observed (respectively 197% and 45% compared to the control) for root glutathione reductase and peroxidase activities over those of other enzymes (superoxide dismutase and catalase). Our results suggest that MSWIBA aqueous leachates need to be formally tested with genotoxic sensitive tests before recycling and support the hypothesis that plant genotoxicity is related to the cellular production of reactive oxygen species (ROS)

  18. Co-detoxification of transformer oil-contained PCBs and heavy metals in medical waste incinerator fly ash under sub- and supercritical water.

    Science.gov (United States)

    Wang, Chunfeng; Zhu, Nengmin; Wang, Yanmin; Zhang, Fushen

    2012-01-17

    The simultaneous detoxification processes of transformer oil-contained PCBs and heavy metals in medical waste incinerator (MWI) fly ash were developed under sub- and supercritical water. The addition of MWI fly ash to transformer oil-contained PCBs was found to increase the destruction efficiency of PCBs, at the same time, it facilitated reducing the leaching concentration of toxic metals from residues (obtained after reaction) for harmless disposal. In this study, we elucidated primarily the catalysis possibility of heavy metals in raw MWI fly ash for PCBs degradation by adopting the sequential extraction procedure. For both MWI fly ashes, more than 90% destruction efficiency of PCBs was achieved at ≥375 °C for 30 min, and trichlorobenzene (TCB) existing in the transformer oil was also completely decomposed. The correlation of catalytic performance to PCBs degradation was discussed based on structural characteristics and dechlorinated products. Likewise, such process rendered residues innocuous through supercritical water treatment for reuse or disposal in landfill.

  19. Use of municipal solid waste incineration bottom ash and crop by-product for producing lightweight aggregate

    Science.gov (United States)

    Giro-Paloma, J.; Ribas-Manero, V.; Maldonado-Alameda, A.; Formosa, J.; Chimenos, J. M.

    2017-10-01

    Due to the growing amount of residues in Europe, it is mandatory to provide a viable alternative for managing wastes contributing to the efficient use of resources. Besides, it is also essential to move towards a low carbon economy, priority EU by 2050. Among these, it is important to highlight the development of sustainable alternatives capable of incorporating different kind of wastes in their formulations.Municipal Solid Waste Incineration (MSWI) is estimated to increase in Europe, where the accessibility of landfill is restricted. Bottom ash (BA) is the most significant by-product from MSWI as it accounts for 85 - 95 % of the solid product resulting from combustion. BA is a mixture of calcium-rich compounds and others silicates enriched in iron and sodium. In addition, it is categorized as non-hazardous waste which can be revalorized as secondary material in construction or civil engineering fields, previous weathering stabilization during 2 - 3 months. Taking into account the relative proportion of each size fraction and the corresponding material characterization, the content of glass (primary and secondary) is estimated to be around 60 wt%. Furthermore, as a renewable resource and according to waste management European policies, residual agricultural biomass has attracted attention in preparation of advanced materials for various applications, due to their low cost, abundance, and environment friendliness. Among this residual biomass, rice husk is a by-product of rice milling industry which has high content of silica and has been widely used in buildings as natural thermal insulation material.Weathered BA (WBA) with a particle size less than 30 mm was milled under 100 μm, mixed with 2.0 - 5.0 mm rice husk, formed into ball-shaped pellets and sintered by different thermal treatments, which remove the organic matter content generating a large porosity. Physico-chemical analysis and mechanical behavior of the manufactured lightweight aggregates were tested

  20. Influence of composition variations on the initial alteration rate of vitrified domestic waste incineration fly-ash.

    Science.gov (United States)

    Frugier, P; Godon, N; Vernaz, E; Larché, F

    2002-01-01

    Vitrification as a waste stabilization technology has often been considered applicable only to high-level radioactive waste for which, with the use of suitable additives, it yields a vitreous material with excellent chemical durability. It has become apparent in recent years that some waste forms-notably domestic waste incineration fly-ash purification residues--contain most of the ingredients of a vitrified material, although their composition variations are difficult to control. It is thus important to ensure not only that the materials are suitable for vitrification, but also that the resulting product exhibits acceptable long-term behavior under all circumstances. An initial study showed that, allowing for the compensation changes inherent in the melting process builtby EDF**, the residue collected by a single fly-ash dust separation defines a composition range within which the suitability of the vitrified material can be verified. "Vitrified material" refers to a melted material that contains no unmelted inclusions after cooling, but that may contain a variable fraction of crystallized phases. Five composition parameters were identified for the long-term behavior assessment: the concentrations of the three major elements (silicon, aluminum and calcium), the total alkali metal (sodium and potassium) concentration, and the sum of the concentrations of two toxic elements (zinc and lead). The other elements were assumed constant at molar ratios representative of industrial wastes. The experimentation plan methodology applied to the composition range identified fourteen materials suilable for developing and validating first-order models of the material components. The fly-ash composition had a very significant effect on the degree and kinetics and crystallization in the vitrified material within the experimental composition range; the cooling rate was the determining factor for some of the fourteen materials studied. Two crystailine phases predominated: spinels

  1. Gas generation in incinerator ash; Gasbildning i aska

    Energy Technology Data Exchange (ETDEWEB)

    Arm, Maria; Lindeberg, Johanna; Rodin, Aasa; Oehrstroem, Anna; Backman, Rainer; Oehman, Marcus; Bostroem, Dan

    2006-02-15

    In recent years, explosions have occurred in certain phases of ash handling in Sweden. Investigations have revealed that hydrogen may have been present in all cases. The hydrogen is believed to be generated by chemical reactions of aluminium and other metals within the ash in the presence of water. The purpose with this study is to increase the knowledge of gas generation of incinerator ash. Thereby, guides for appropriate ash management can be introduced and the risk for further explosions prevented. The study has comprised analyses of the ash properties, such as chemical and physical composition and the pH, of ash from 14 incineration plants (mostly waste incineration plants). Different fractions of ash materials representing different parts of the process in each plant have been analysed. Furthermore, the fuel and the technical differences between the plants have been analysed. A tool for measuring the gas generation in the laboratory has been developed and the gas generation of the different ash materials at natural and increased pH was measured. Gas analyses and thermodynamic calculations have also been performed. The results showed that: bottom ash from fluidised bed boilers generated small amounts of gas at increased pH, much smaller amounts than the idle pass, cyclone and filter ash did, bottom ash from grate fired boilers generated more gas at increased pH than their cyclone ash and filter ash, with exception of the Linkoeping plant, all bio waste incineration plants generated ash with low gas generation potential, all fly ash materials with a gas generation potential of more than 10 l/kg originated from municipal waste incineration plants, filter ash that had been stored in oxygen rich environment generated significant less gas than fresh filter ash of the same origin, hardly any other gases were generated apart from hydrogen (very small amounts of acetone, furane, benzene and most likely methane were detected in some of the ash materials), there were no

  2. Heavy metals extraction from municipal solid waste incineration fly ash using adapted metal tolerant Aspergillus niger.

    Science.gov (United States)

    Yang, Jie; Wang, Qunhui; Wang, Qi; Wu, Tingji

    2009-01-01

    This study focused on the adaptation of Aspergillus niger tolerating high concentration of heavy metals for bioleaching of fly ash. The Plackett-Burman design indicated that Al and Fe inhibited the growth of A. niger (AS 3.879 and AS 3.40) significantly. The single metal (Al and Fe) and multi-metals adapted AS 3.879 strain tolerated up to 3500 mg/L Al, 700 mg/L Fe, and 3208.1mg/L multi-metals, respectively. The order of metal extraction yield in two-step bioleaching of 60 and 70 g/L fly ash using Al adapted, multi-metals adapted and un-adapted AS 3.879 strains was as follows: multi-metals adapted>Al adapted>un-adapted. The multi-metals adapted strain grew with up to 70 g/L fly ash and secreted 256 mmol/L organic acids after 288 h, where 87.4% Cd, 64.8% Mn, 49.4% Zn and 45.9% Pb were dissolved. The extracted metals in TCLP test of the bioleached fly ash by multi-metals adapted strain were under the regulated levels in China.

  3. Life cycle assessment of resource recovery from municipal solid waste incineration bottom ash

    DEFF Research Database (Denmark)

    Allegrini, Elisa; Vadenbo, Carl; Boldrin, Alessio

    2015-01-01

    routes were compared: landfilling, road sub-base and aggregate in concrete, while specific leaching data were used as the basis for evaluating toxic impacts. The recovery and recycling of aluminium, ferrous, stainless steel and copper scrap were considered, and the importance of aluminium scrap quality...... scrap metals may limit recycling potential, and the utilisation of aggregates may cause the release of toxic substances into the natural environment through leaching. A life cycle assessment (LCA) was applied to a full-scale MSWI bottom ash management and recovery system to identify environmental......, choice of marginal energy technologies and substitution rates between primary and secondary aluminium, stainless steel and ferrous products, were assessed and discussed. The modelling resulted in burdens to toxic impacts associated with metal recycling and leaching from aggregates during utilisation...

  4. Hospital waste incinerator bottom ash leachate induced cyto-genotoxicity in Allium cepa and reproductive toxicity in mice.

    Science.gov (United States)

    Akinbola, Temitayo I; Adeyemi, Adetutu; Morenikeji, Olajumoke A; Bakare, Adekunle A; Alimba, Chibuisi G

    2011-07-01

    The potentials of hospital incinerator bottom ash leachate (HIBAL) to induce cyto-genotoxicity in Allium cepa and reproductive anomalies in the mouse were investigated. The leachate obtained from simulation of the bottom ash was analyzed for some physico-chemical parameters. The A. cepa, mouse sperm morphology and histopathological tests were carried out at concentrations ranging from 1% to 50% of the leachate sample. In A. cepa, HIBAL caused significant (p animal assays, there was 100% mortality at the 50% concentrations. The leachate caused insignificant (p > 0.05) concentration-dependent induction of various types of sperm morphology. There was accumulation of fluid in the seminiferous tubule lumen and necrosis of stem cells in the testes. These effects were believed to be provoked by the somatic and germ cell genotoxins, particularly the heavy metals in the leachate. Our finding is of environmental and public health significance.

  5. Waste incineration. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Egede Rasmussen, Anja

    2004-06-15

    This prepatory thesis is a literature study on the incineration of waste. It deals with the concepts of municipal solid waste, the composition and combustion of it. A main focus is on the European emission regulations and the formation of dioxins, as well as a big effort is put into the treatment of solid residues from municipal solid waste incineration. In the latter area, concepts of treatment, such as physical and chemical separations, solidification and stabilization techniques, thermal methods, and extraction methods have been discussed. Evaluation of possible methods of treatment has been done, but no conclusions made of which is the best. Though, indications exist that especially two methods have shown positive qualities and must be further investigated. These methods are the acid extraction and sulfide stabilization (AES) process and the phosphate stabilization method of WES-PHix. Economic potentials of the two methods have been evaluated, and with the information obtained, it seems that the price for treatment and later landfilling of a material with improved leaching characteristics, will be approximately the same as the presently most used solution of export to Norway. However, more tests, investigations and economic evaluations are necessary in order for support of the findings in this work. (au)

  6. Influence of ignition process on mineral phase transformation in municipal solid waste incineration (MSWI) fly ash: Implications for estimating loss-on-ignition (LOI).

    Science.gov (United States)

    Mu, Yue; Saffarzadeh, Amirhomayoun; Shimaoka, Takayuki

    2017-01-01

    This research focused on the mineral phase transformation under varied ignition conditions with the objective of estimating loss-on-ignition (LOI) parameter in municipal solid waste incineration (MSWI) fly ash residues. LOI is commonly used to measure the volatile species, unburned carbon and moisture in the solid materials. There are criteria for LOI measurement in some research fields, while there is no standard protocol for LOI measurement in MSWI fly ash. Using thermogravimetry technique, the ignition condition candidates were proposed at 440/700/900°C for 1 and 2h. Based on X-ray diffractometry results, obvious mineral phase transformation occurred as a function of ignition temperature variation rather than ignition time. Until 440°C, only some minor phases disappeared comparing with the original state. Significant mineral phase transformations of major phases (Ca- and Cl-based minerals) occurred between 440 and 700°C. The mineral phase transformation and the occurrence of newly-formed phases were determined not only by the ignition condition but also by the content of the co-existing components. Mineral phase components rarely changed when ignition temperature rose from 700 to 900°C. Consequently, in order to prevent critical damages to the original mineralogical composition of fly ash, the lowest ignition temperature (440°C) for 2h was suggested as an ideal measurement condition of LOI in MSWI fly ash. Copyright © 2016 Elsevier Ltd. All rights reserved.

  7. Characterization of a former dump site in the Lagoon of Venice contaminated by municipal solid waste incinerator bottom ash, and estimation of possible environmental risk.

    Science.gov (United States)

    Rigo, Chiarafrancesca; Zamengo, Luca; Rampazzo, Giancarlo; Argese, Emanuele

    2009-10-01

    Bottom ash from a municipal solid waste incinerator on a former contaminated site, the island of Sacca San Biagio (Lagoon of Venice), was examined in order to evaluate levels of pollutants and their potential mobility and availability. Heavy metal concentrations were determined and the actual contamination of the site was compared with national legislation on polluted sites. The site was mainly contaminated by zinc, copper and lead. Physico-chemical characterization of bottom ash was carried out by SEM (Scanning Electron Microscopy) with micro-analysis by EDS (Energy Dispersive X-ray Spectroscopy) and XRD (X-ray Diffractometry), for information on newly formed minerals. SEM-EDS analysis revealed the presence of particles, compounds and clusters containing heavy metals and, in particular, the presence of barium sulfate, which was assumed to be a site-specific compound. Similarities between bottom ash and atmospheric PM10 collected on the adjacent island of Sacca Fisola were studied and a risk of aerodispersion of the fine fraction of ash was assumed. Lastly, in order to evaluate the potentially available fraction of metals (non-residual fraction) and the directly exchangeable fraction, two single extraction procedures with HCl and citric acid were carried out, respectively. Results showed a relatively low concentration of readily phyto-available metals, as well as the high concentrations found for some heavy metals (Cu, Pb, Zn) in the potentially mobilizable fraction.

  8. Effect of additional materials on the properties of glass-ceramic produced from incinerator fly ashes.

    Science.gov (United States)

    Cheng, T W

    2004-07-01

    There are 21 Metro-waste incinerators in Taiwan under construction and are expected to be finished at year 2003. It is estimated that these incinerators will produce about two million tons of incinerator ash. In order to reduce the volume and eliminate contamination problems, high temperature molten technology studies have been conducted. The purpose of this research was that of trying to control the chemical composition of the glass-ceramic produced from incinerator fly ash, in order to improve the characteristics of the glass-ceramic. The experimental results showed that the additional materials, Mg(OH)2 and waste glass cullet, can change glass-ceramic phases from gehlenite to augite, pigeonite, and diopside. The physical, mechanical and chemical resistance properties of the glass-ceramic also showed much better characteristics than prepared glass-ceramic using incinerator fly ash alone.

  9. Characterization of fly ashes from a municipal solid waste incinerator to explore its using in construction; Caracterizacion de cenizas procedentes de plantas de incineracion de residuos solidos urbanos para su posible utilizacion en construccion

    Energy Technology Data Exchange (ETDEWEB)

    Alaejos Gutierrez, M. P.

    2002-07-01

    The paper describes the physical and chemical characterization of fly ashes from municipal solid waste incinerator. The objective is to explore potential applications of this residue in construction products. The results show the no pozzolanic nature of the fly ashes, so its utilization as mineral admixture is discarded. however, the study reveals the expansive character of the fly ashes when are mixed with water. The results of X-ray diffraction confirm the presence of metallic aluminium in the fly ash as the origin of this expansion. This chemical reaction generates a considerable amount of hydrogen, inflammable gas. Three ways to avoid this reaction are proposed. On the other way, the expansive behaviour of the fly ashes allow to explore its possible application to produce cellular mortars, as the traditional production of these mortars have several similarities with the reaction of fly ash and water. (Author) 9 refs.

  10. The effects of alkaline dosage and Si/Al ratio on the immobilization of heavy metals in municipal solid waste incineration fly ash-based geopolymer.

    Science.gov (United States)

    Zheng, Lei; Wang, Wei; Shi, Yunchun

    2010-04-01

    The present research explored the application of geopolymerization for the immobilization and solidification of municipal solid waste incineration (MSWI) fly ash. The influence of alkaline activator dosage and Si/Al molar ratio on the compressive strength and microstructure of MSWI fly ash-based geopolymer was investigated. A geopolymer with the highest strength was identified to occur at an intermediate alkaline activator dosage and Si/Al ratio, and the optimal Na/MSWI fly ash and Si/Al molar ratio was close to 2.8 mol kg(-1) and 2.0, respectively. IR spectra showed that higher alkaline activator dosage enhanced the structural disruption of the original aluminosilicate phases and a higher degree of polymerization of the geopolymer networks. At low Si/Al ratio, there was an increasing number of tetrahedral Al incorporating into the silicate backbone. As the Na/MSWI fly ash ratio increased, the microstructure changed from containing large macropores to more mesopores and micropores, indicating that more geopolymers are formed. Furthermore, the pore volume distribution of geopolymers was observed to shift to larger pores as the Si/Al ratio increased, which suggests that the soluble silicon content serves to reduce the amount of geopolymers. Heavy metal leaching was successfully elucidated using the first-order reaction/reaction-diffusion model. Combining the results from the microstructure of samples with the kinetic analysis, the immobilization mechanism of Cr, Cu, and Zn was inferred in this study. The methodologies described could provide a powerful set of tools for the systematic evaluation of element release from geopolymers. 2010 Elsevier Ltd. All rights reserved.

  11. Behavior of radioactive cesium during incineration of radioactively contaminated wastes from decontamination activities in Fukushima.

    Science.gov (United States)

    Fujiwara, Hiroshi; Kuramochi, Hidetoshi; Nomura, Kazutaka; Maeseto, Tomoharu; Osako, Masahiro

    2017-11-01

    Large volumes of decontamination wastes (DW) generated by off-site decontamination activities in Fukushima Prefecture have been incinerated since 2015. The behavior of radioactive cesium during incineration of DW was investigated at a working incineration plant. The incineration discharged bottom ash (BA) and fly ash (FA) with similar levels of radiocesium, and the leachability of the radiocesium from both types of ash was very low (<1%). These results are significantly different from those obtained for the incineration of contaminated municipal solid waste (CMSW) reported in earlier studies. The source of radiocesium in DW-FA is chiefly small particles derived from DW and DW-BA blown into the flue gas, not the deposition of gaseous synthesized radiocesium compounds on the surfaces of ash particles in the flue gas as observed in CMSW incineration. This source difference causes the behavior of radiocesium during waste incineration to differ between DW and CMSW. Copyright © 2017 Elsevier Ltd. All rights reserved.

  12. A full-scale study on thermal degradation of polychlorinated dibenzo- p-dioxins and dibenzofurans in municipal solid waste incinerator fly ash and its secondary air pollution control in China.

    Science.gov (United States)

    Gao, Xingbao; Ji, Bingjing; Yan, Dahai; Huang, Qifei; Zhu, Xuemei

    2017-04-01

    Degradation of polychlorinated dibenzo- p-dioxins and dibenzofurans in municipal solid waste incinerator fly ash is beneficial to its risk control. Fly ash was treated in a full-scale thermal degradation system (capacity 1 t d-1) to remove polychlorinated dibenzo- p-dioxins and dibenzofurans. Apart from the confirmation of the polychlorinated dibenzo- p-dioxin and dibenzofuran decomposition efficiency, we focused on two major issues that are the major obstacles for commercialising this decomposition technology in China, desorption and regeneration of dioxins and control of secondary air pollution. The toxic equivalent quantity values of polychlorinated dibenzo- p-dioxins and dibenzofurans decreased to solid waste incinerator economiser, and then co-processed in the air pollution control system. The degradation furnace released relatively large amounts of cadmium, lead and polychlorinated dibenzo- p-dioxins and dibenzofurans compared with the municipal solid waste incinerator, but the amounts emitted to the atmosphere did not exceed the Chinese national emission limits. Thermal degradation can therefore be used as a polychlorinated dibenzo- p-dioxin and dibenzofuran abatement method for municipal solid waste incinerator source in China.

  13. COMPARATIVE STUDY OF HEAVY METALS IN BOTTOM ASH FROM INCINERATORS AND OPEN PIT FROM HEALTHCARE FACILITIES IN GHANA

    OpenAIRE

    Richard Amfo-Otua; Sarah Graham Kyerewaa; Emmanuel Adu Ofori; Adams Sadick

    2015-01-01

    Treatment of healthcare waste either by incinerating or open burning in a pit produces bottom ashes which contains heavy metals and other chemicals which are toxic, persistent and accumulate in the food chain resulting in adverse health effects in human and the environment. The study investigated the level of heavy metals in the ashes of thermally treated medical waste from four health care facilities in Ghana. Two batch of the ash samples were collected from two hospital incinerators and the...

  14. Studies of Cd, Pb and Cr distribution characteristics in bottom ash following agglomeration/defluidization in a fluidized bed boiler incinerating artificial waste

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Zhen-Shu [Department of Safety, Health and Environmental Engineering, Ming Chi University of Technology, 84 Gungjuan Rd., Taishan, Taipei, 243 (China); Lin, Chiou-Liang [Department of Civil and Environmental Engineering, National University of Kaohsiung, Kaohsiung, 811 (China); Chou, Jing-Dong [Department of Environmental Engineering, National Chung-Hsing University, Taichung, 402 (China)

    2010-06-15

    This study focused on the effects of agglomeration/defluidization on the Cd, Pb and Cr distribution in bottom ash particles of different sizes. In this study we have incinerated artificial waste, which was a mixture of sawdust, polypropylene, selected metal solutions, and polyethylene. The experimental parameters included Na concentration, addition of Ca and Mg and operating temperature. The results indicated that particle size decreased by attrition and thermal impact in the absence of added Na. When Na was added to the system, this metal reacted with silica sand to form eutectics, which increased particle size. Further addition of Ca and Mg was found to prolong the operating time, with greater amounts of liquid eutectic accumulating, leading to increase particle size. The heavy metal concentrations in coarse and fine particles were greater than those present in particles of intermediate sizes over a range of experimental conditions. As the particle size decreased below 0.59 mm or increased above 0.84 mm, the heavy metal concentrations increased. As Ca and Mg were added, the heavy metal concentrations in particles of all sizes increased relative to those present in identical particles when no metals or only Na were added. Additionally, the ratio of Cd sorption to silica sand decreased with increasing Na concentration, but Cr sorption had the opposite tendency. Therefore, while the addition of Na tended to increase agglomeration, it also increased the tendency for heavy metals to remain in the sand bed of fluidized bed incinerators. Addition of Ca and Mg not only inhibited the agglomeration/defluidization process, resulting in increased operating time, but also enhanced the removal of heavy metals by silica sand, decreasing the concentration of heavy metals in reactor exhaust. (author)

  15. Recover heat from waste incineration

    Energy Technology Data Exchange (ETDEWEB)

    Ganapathy, V. [ABCO Industries, Abilene, TX (United States)

    1995-09-01

    Using these guidelines, engineers can address critical design problems associated with burning process-waste streams and select cost-effective waste-heat boilers. Incinerating contaminant streams is a win-win situation: (1) complete destruction of pollutant(s) is attained and (2) valuable thermal energy is recovered as steam and returned to process, thus conserving energy. However, recovering thermal energy from incinerated flue-gas streams contains some caveats. This treatment method creates a large high-temperature flue gas from which valuable thermal energy is recovered as saturated or superheated steam. Unfortunately, because a process-waste stream is used as feed, this stream will have variations in contaminant and component concentrations which influence the load on the boiler. Also, burning contaminants may create acid gases which will accelerate corrosion problems for the boiler at elevated temperatures. The following guidelines and checklist clarify the do`s and don`ts when designing waste-heat boilers.

  16. Utilization of municipal solid waste incineration (MSWI) fly ash in blended cement Part 1: Processing and characterization of MSWI fly ash.

    Science.gov (United States)

    Aubert, J E; Husson, B; Sarramone, N

    2006-08-25

    This paper is the first of a series of two articles dealing with the processes applied to MSWI fly ash with a view to reusing it safely in cement-based materials. Part 1 presents two stabilization processes and Part 2 deals with the use of the two treated fly ashes (TFA) in mortars. Two types of binder were used: an Ordinary Portland Cement (OPC) containing more than 95% clinker (CEM I 52.5R) and a binary blend cement composed of 70% ground granulated blast furnace slag and 30% clinker (CEM III-B 42.5N). In this first part, two stabilization processes are presented: the conventional process, called "A", based on the washing, phosphation and calcination of the ash, and a modified process, called "B", intended to eliminate metallic aluminum and sulfate contained in the ash. The physical, chemical and mineralogical characteristics of the two TFA were comparable. The main differences observed were those expected, i.e. TFA-B was free of metallic aluminum and sulfate. The mineralogical characterization of the two TFAs highlighted the presence of large amounts of a calcium aluminosilicate phase taking two forms, a crystalline form (gehlenite) and an amorphous form. Hydration studies on pastes containing mixed TFA and calcium hydroxide showed that this phase reacted with calcium hydroxide to form calcium aluminate hydrates. This formation of hydrates was accompanied by a hardening of the pastes. These results are very encouraging for the reuse of such TFA in cement-based materials because they can be considered as pozzolanic additions and could advantageously replace a part of the cement in cement-based materials. Finally, leaching tests were carried out to evaluate the environmental impact of the two TFAs. The elements which were less efficiently stabilized by process A were zinc, cadmium and antimony but, when the results of the leaching tests were compared with the thresholds of the European landfill directive, TFA-A could nevertheless be accepted at landfills for non

  17. Characterization of fly ash from bio and municipal waste

    DEFF Research Database (Denmark)

    Lima, Ana T.; Ottosen, Lisbeth M.; Pedersen, Anne Juul

    2008-01-01

    Four different fly ashes are characterized in the present paper. The ashes differ in the original fuel type and were sampled at distinct plants. The investigation includes two different ashes from municipal solid waste incineration (with and without sorbents addition), a straw ash and an ash from...... potentiality to be valorized. The main conclusion of this paper regards fly ash’s profound dissimilarity, where each ash should be studied separately....

  18. [Effect of desilication treatment using silicate bacteria on the bioleaching efficiency of municipal solid waste incineration fly ash].

    Science.gov (United States)

    Yang, Jie; Wang, Qun-Hui; Luo, Qi-Shi; Wang, Qi; Wu, Ting-Ji

    2010-01-01

    One silicate bacteria strain SDB6 with good performance in silicon removal was isolated and screened from soil. Based on the morphological, physiological, biochemical characteristics and 16S rDNA sequence analysis, SDB6 was identified as Bacillus mucilaginosus strain. The effects of nitrogen source, pH, temperature, rotate speed and medium volume on the growth of SDB6 were investigated. The above factors were optimized using the orthogonal design. The optimized condition was described as follows: 10 g/L yeast, 250 mL flask with 50 mL culture medium, pH 7.5, 30 degrees C, 180 r/min. The bioleaching of un-desilicated and desilicated fly ash using the adapted Aspergillus niger AS 3.879M strain was carried out for 20d. The results indicated that the metal extraction yield in bioleaching increased obviously with desilication treatment comparing to that without desilication treatment. The extraction yield of Cu, Mn, Cr, Zn and Fe from desilicated fly ash was 31%, 75%, 60%, 60% and 48%, respectively. The total metals extraction yield of desilicated fly ash increased to 50%. The TCLP results of the fly ash after bioleaching indicated that the leaching toxicities of the treated fly ash were far lower than the regulated levels of China and permitted to the further landfill or reuse.

  19. Production of coloured glass-ceramics from incinerator ash using thermal plasma technology.

    Science.gov (United States)

    Cheng, T W; Huang, M Z; Tzeng, C C; Cheng, K B; Ueng, T H

    2007-08-01

    Incineration is a major treatment process for municipal solid waste in Taiwan. It is estimated that over 1.5 Mt of incinerator ash are produced annually. This study proposes using thermal plasma technology to treat incinerator ash. Sintered glass-ceramics were produced using quenched vitrified slag with colouring agents added. The experimental results showed that the major crystalline phases developed in the sintered glass-ceramics were gehlenite and wollastonite, but many other secondary phases also appeared depending on the colouring agents added. The physical/mechanical properties, chemical resistance and toxicity characteristic leaching procedure of the coloured glass-ceramics were satisfactory. The glass-ceramic products obtained from incinerator ash treated with thermal plasma technology have great potential for building applications.

  20. ALKALINE TREATMENT AND IMMOBILIZATION OF SECONDARY WASTE FROM WASTE INCINERATION

    Directory of Open Access Journals (Sweden)

    Dariusz Mierzwiński

    2017-04-01

    Full Text Available This paper regards the possibility of using geopolymer matrix to immobilize heavy metals present in ash and slag from combustion of waste. In the related research one used the fly ash from coal combustion in one Polish CHP plant and the waste from Polish incineration plants. It was studied if the above-named waste materials are useful in the process of alkali-activation. Therefore, three sets of geopolymer mixtures were prepared containing 60, 50 and 30% of ash and slag from the combustion of waste and fly ash combustion of sewage skudge. The remaining content was fly ash from coal combustion. The alkali-activation was conducted by means of 14M solution of NaOH and sodium water glass. The samples, whose dimensions were in accordance with the PN-EN 206-1 norm, were subjected to 75°C for 24h. According to the results, the geopolymer matrix is able to immobilize heavy metals and retain compressive strength resembling that of concrete.

  1. Influence of ammonia on leaching behaviors of incineration fly ash and its geochemical modeling

    DEFF Research Database (Denmark)

    Astrup, Thomas Fruergaard; Guan, Zhen Zhen; Chen, De Zhen

    2013-01-01

    Incineration fly ash could be contaminated with NH3 that was slipped from the ammonia-based selective non-catalytic reduction(SNCR) process and from evaporation of municipal solid wastes' leachate involved in the wastes. This research was conducted to investigate the impacts of ammonia on leaching...... of dissolved organic carbon (DOC) and metals from incineration fly ash in the pH range of 3.66-12.44 with an active ammonia spike. A geochemical modeling software Visual MINTEQ was adopted to calculate the chemical speciation of metals under the leaching conditions to reveal the mechanism behind the impacts...... by precipitation/dissolution and surface complexation/precipitation processes; Visual MINTEQ modeling could well describe the leaching behaviors of Al, Cu, Pb and Zn from incineration fly ash....

  2. Organic waste incineration processes

    Energy Technology Data Exchange (ETDEWEB)

    Lemort, F.; Charvillat, J.P.; Nabot, J.P. [CEA Valrho, Bagnols sur Ceze Cedex (France); Chateauvieux, H.; Thiebaut, C. [CEA Valduc, 21 - Is-sur-Tille (France)

    2001-07-01

    Nuclear activities produce organic waste compatible with thermal processes designed to obtain a significant weight and volume reduction as well as to stabilize the inorganic residue in a form suitable for various interim storage or disposal routes. Several processes may be implemented (e.g. excess air, plasma, fluidized bed or rotating furnace) depending on the nature of the waste and the desired objectives. The authors focus on the IRIS rotating-kiln process, which was used for the first time with radioactive materials during the first half of 1999. IRIS is capable of processing highly chlorinated and {alpha}-contaminated waste at a rate of several kilograms per hour, while limiting corrosion due to chlorine as well as mechanical entrainment of radioactive particles in the off-gas stream. Although operated industrially, the process is under continual development to improve its performance and adapt it to a wider range of industrial applications. The main focus of attention today is on adapting the pyrolytic processes to waste with highly variable compositions and to enhance the efficiency of the off-gas purification systems. These subjects are of considerable interest for a large number of heat treatment processes (including all off-gas treatment systems) for which extremely durable, high-performance and low-flow electrostatic precipitators are now being developed. (author)

  3. Studying the melting behaviour of fly ash from the incineration of MSW using viscosity and heated stage XRD data

    DEFF Research Database (Denmark)

    Arvelakis, Stelios; Folkedahl, B.; Frandsen, F. J.

    2008-01-01

    The purpose of the present study has been to investigate the melting behaviour of fly ashes from the incineration of MSW (municipal solid waste). Four fly ash samples from the Svendborg WtE (waste-to-energy) plant (2nd-3rd pass, super-heater, economizer, ESP), in Denmark, have been investigated...

  4. Electrochemical incineration of wastes

    Science.gov (United States)

    Bhardwaj, R. C.; Sharma, D. K.; Bockris, J. Om.

    1990-08-01

    The novel technology of waste removal in space vehicles by electrochemical methods is presented to convert wastes into chemicals that can be eventually recycled. The important consideration for waste oxidation is to select a right kind of electrode (anode) material that should be stable under anodic conditions and also a poor electrocatalyst for oxygen and chlorine evolution. On the basis of long term electrolysis experiments on seven different electrodes and on the basis of total organic carbon reduced, two best electrodes were identified. The effect of redox ions on the electrolyte was studied. Though most of the experiments were done in mixtures of urine and waste, the experiments with redox couples involved 2.5 M sulfuric acid in order to avoid the precipitation of redox ions by urea. Two methods for long term electrolysis of waste were investigated: (1) the oxidation on Pt and lead dioxide electrodes using the galvanostatic methods; and (2) potentiostatic method on other electrodes. The advantage of the first method is the faster rate of oxidation. The chlorine evolution in the second method is ten times less then in the first. The accomplished research has shown that urine/feces mixtures can be oxidized to carbon dioxide and water, but current densities are low and must be improved. The perovskite and Ti4O7 coated with RuO2 are the best electrode materials found. Recent experiment with the redox agent improves the current density, however, sulphuric acid is required to keep the redox agent in solution to enhance oxidation effectively. It is desirable to reduce the use of acid and/or find substitutes.

  5. A study on the safety of radioactive waste incineration facilities

    Energy Technology Data Exchange (ETDEWEB)

    Seo, Y. C. [Yonsei Univ., Seoul (Korea, Republic of); Park, W. J.; Lee, B. S.; Lee, S. H. [Korea Institute of Nuclear Safety, Taejon (Korea, Republic of)

    1994-12-15

    The main scope of the project is the selection of some considerable items in design criteria of radioactive waste incineration facilities not only for the protection of workers and residents during operation but also for the safe disposal of ashes after incineration. The technological and regulational status on incineration technologies in domestic and foreign is surveyed and analyzed for providing such basic items which must be contained in the guideline for safe and appropriate design, construction and operation of the facilities. The contents of the project are summarized as follows; surveying the status on incineration technologies for both radioactive and non-radioactive wastes in domestic and foreign, surveying and analysing same related technical standards and regulations in domestic and foreign, picking out main considerable items and proposing a direction of further research.

  6. Electrodialytic removal of heavy metals and chloride from municipal solid waste incineration fly ash and air pollution control residue in suspension - test of a new two compartment experimental cell

    DEFF Research Database (Denmark)

    Kirkelund, Gunvor Marie; Magro, Cátia; Guedes, Paula

    2015-01-01

    heavy metal leaching except when the pH was reduced to a level below 8 for the fly ash. On the other hand, Cr leaching increased by the electrodialytic treatment. Cl leaching from the MSWI residues was less dependent on experimental conditions and was reduced in all experiments compared to the initial......Municipal solid waste incineration (MSWI) residues such as fly ash and air pollution control (APC) residues are classified as hazardous waste and disposed of, although they contain potential resources. The most problematic elements in MSWI residues are leachable heavy metals and salts. For reuse...... of MSWI residues in for instance concrete, the aim of remediation should be reduction of the heavy metal leaching, while at the same time keeping the alkaline pH, so the residue can replace cement. In this study a MSWI residues were subjected to electrodialytic remediation under various experimental...

  7. A comparative assessment of waste incinerators in the UK.

    Science.gov (United States)

    Nixon, J D; Wright, D G; Dey, P K; Ghosh, S K; Davies, P A

    2013-11-01

    The uptake in Europe of Energy from Waste (EfW) incinerator plants has increased rapidly in recent years. In the UK, 25 municipal waste incinerators with energy recovery are now in operation; however, their waste supply chains and business practices vary significantly. With over a hundred more plant developments being considered it is important to establish best business practices for ensuring efficient environmental and operational performance. By reviewing the 25 plants we identify four suitable case study plants to compare technologies (moving grate, fluidised bed and rotary kiln), plant economics and operations. Using data collected from annual reports and through interviews and site visits we provide recommendations for improving the supply chain for waste incinerators and highlight the current issues and challenges faced by the industry. We find that plants using moving grate have a high availability of 87-92%. However, compared to the fluidised bed and rotary kiln, quantities of bottom ash and emissions of hydrogen chloride and carbon monoxide are high. The uptake of integrated recycling practices, combined heat and power, and post incineration non-ferrous metal collections needs to be increased among EfW incinerators in the UK. We conclude that one of the major difficulties encountered by waste facilities is the appropriate selection of technology, capacity, site, waste suppliers and heat consumers. This study will be of particular value to EfW plant developers, government authorities and researchers working within the sector of waste management. Copyright © 2013 Elsevier Ltd. All rights reserved.

  8. Materials for Waste Incinerators and Biomass Plants

    DEFF Research Database (Denmark)

    Rademakers, P.; Grossmann, G.; Karlsson, A.

    1998-01-01

    This paper reviews the projects of the sub-package on waste incineration and biomass firing carried out within COST 501 Round III, Work Package 13.......This paper reviews the projects of the sub-package on waste incineration and biomass firing carried out within COST 501 Round III, Work Package 13....

  9. Highly Efficient Fecal Waste Incinerator Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Volume reduction is a critical element of Solid Waste Management for manned spacecraft and planetary habitations. To this end, the proposed fecal waste incinerator...

  10. Influence of bacteria on lanthanide and actinide transfer from specific soil components (humus, soil minerals and vitrified municipal solid waste incinerator bottom ash) to corn plants: Sr-Nd isotope evidence

    Energy Technology Data Exchange (ETDEWEB)

    Aouad, Georges [Ecole et Observatoire des Sciences de la Terre, Centre de Geochimie de la Surface/CNRS UMR 7517, 1 rue Blessig, 67084 Strasbourg Cedex (France); Stille, Peter [Ecole et Observatoire des Sciences de la Terre, Centre de Geochimie de la Surface/CNRS UMR 7517, 1 rue Blessig, 67084 Strasbourg Cedex (France)]. E-mail: pstille@illite.u-strasbg.fr; Crovisier, Jean-Louis [Ecole et Observatoire des Sciences de la Terre, Centre de Geochimie de la Surface/CNRS UMR 7517, 1 rue Blessig, 67084 Strasbourg Cedex (France); Geoffroy, Valerie A. [UMR 7156 Universite Louis-Pasteur/CNRS, Genetique Moleculaire, Genomique Microbiologie, Departement Micro-organisme, Genomes, Environnement, 28 rue Goethe, 67083 Strasbourg Cedex (France); Meyer, Jean-Marie [UMR 7156 Universite Louis-Pasteur/CNRS, Genetique Moleculaire, Genomique Microbiologie, Departement Micro-organisme, Genomes, Environnement, 28 rue Goethe, 67083 Strasbourg Cedex (France); Lahd-Geagea, Majdi [Ecole et Observatoire des Sciences de la Terre, Centre de Geochimie de la Surface/CNRS UMR 7517, 1 rue Blessig, 67084 Strasbourg Cedex (France)

    2006-11-01

    Experiments have been performed to test the stability of vitrified municipal solid waste (MSW) incinerator bottom ash under the presence of bacteria (Pseudomonas aeruginosa) and plants (corn). The substratum used for the plant growth was a humus-rich soil mixed with vitrified waste. For the first time, information on the stability of waste glasses in the presence of bacteria and plants is given. Results show that inoculated plant samples contained always about two times higher lanthanide and actinide element concentrations. Bacteria support the element transfer since plants growing in inoculated environment developed a smaller root system but have higher trace element concentrations. Compared with the substratum, plants are light rare earth element (LREE) enriched. The vitrified bottom ash has to some extent been corroded by bacteria and plant activities as indicated by the presence of Nd (REE) and Sr from the vitrified waste in the plants. {sup 87}Sr/{sup 86}Sr and {sup 143}Nd/{sup 144}Nd isotope ratios of plants and soil components allow the identification of the corroded soil components and confirm that bacteria accelerate the assimilation of elements from the vitrified bottom ash. These findings are of importance for landfill disposal scenarios, and similar experiments should be performed in order to better constrain the processes of microbially mediated alteration of the MSW glasses in the biosphere.

  11. Evaluating the use of waste-to-energy bottom ash as road construction materials : [summary].

    Science.gov (United States)

    2014-02-01

    Municipal solid waste incineration (MSWI) generates millions of tons of ash each year. In European and Asian countries, this ash has been recycled into road beds, asphalt paving, and concrete products encouraged and enforced by standards, managem...

  12. The Use of Microwave Incineration to Process Biological Wastes

    Science.gov (United States)

    Sun, Sidney C.; Srinivasan, Venkatesh; Covington, Alan (Technical Monitor)

    1994-01-01

    The handling and disposal of solid waste matter that has biological or biohazardous components is a difficult issue for hospitals, research laboratories, and industry. NASA faces the same challenge as it is developing regenerative systems that will process waste materials into materials that can be used to sustain humans living in space for extended durations. Plants provide critical functions in such a regenerative life support scheme in that they photosynthesize carbon dioxide and water into glucose and oxygen. The edible portions of the plant provide a food source for the crew. Inedible portions can be processed into materials that are more recyclable. The Advanced Life Support Division at NASA Ames Research Center has been evaluating a microwave incinerator that will oxidize inedible plant matter into carbon dioxide and water. The commercially available microwave incinerator is produced by Matsushita Electronic Instruments Corporation of Japan. Microwave incineration is a technology that is simple, safe, and compact enough for home use. It also has potential applications for institutions that produce biological or biohazardous waste. The incinerator produces a sterile ash that has only 13% of the mass of the original waste. The authors have run several sets of tests with the incinerator to establish its viability in processing biological material. One goal of the tests is to show that the incinerator does not generate toxic compounds as a byproduct of the combustion process. This paper will describe the results of the tests, including analyses of the resulting ash and exhaust gases. The significance of the results and their implications on commercial applications of the technology will also be discussed.

  13. Recycling of boiler and incinerator ash into value added glass products

    Energy Technology Data Exchange (ETDEWEB)

    Hnat, J.G.; Bartone, L.M. [Vortec Corp., Collegeville, PA (United States)

    1996-09-01

    This paper discusses the recycling of coal-fired boiler and incinerator ashes into value added glass products via the use of a newly developed, fossil-fuel fired, high temperature melting process. The Vortec patented Cyclone Melting System (CMS{trademark}) has a number of significant advantages for recycling solid wastes including: the oxidation of organic and metal contaminants, formation of non-leachable glasses which can be sold as value added products, high melting efficiencies, multi-fuel capability, low operating and maintenance costs and low NO{sub x} emissions. This paper summarizes some of the challenges facing process industries and utilities in the recycling and reuse of industrial solid wastes. The results of laboratory and pilot scale testing with several pulverized coal-fired boiler ashes, several municipal solid waste incinerator ashes, and a sewage sludge incinerator ash are summarized. Information on ash properties, melting characteristics, system performance, toxicity characteristics leaching procedure (TCLP) testing results, flue gas emissions, recycled products, and economics are presented. The application of the CMS to the production of several value added glass and ceramic products is also discussed.

  14. Porous materials produced from incineration ash using thermal plasma technology.

    Science.gov (United States)

    Yang, Sheng-Fu; Chiu, Wen-Tung; Wang, To-Mai; Chen, Ching-Ting; Tzeng, Chin-Ching

    2014-06-01

    This study presents a novel thermal plasma melting technique for neutralizing and recycling municipal solid waste incinerator (MSWI) ash residues. MSWI ash residues were converted into water-quenched vitrified slag using plasma vitrification, which is environmentally benign. Slag is adopted as a raw material in producing porous materials for architectural and decorative applications, eliminating the problem of its disposal. Porous materials are produced using water-quenched vitrified slag with Portland cement and foaming agent. The true density, bulk density, porosity and water absorption ratio of the foamed specimens are studied here by varying the size of the slag particles, the water-to-solid ratio, and the ratio of the weights of the core materials, including the water-quenched vitrified slag and cement. The thermal conductivity and flexural strength of porous panels are also determined. The experimental results show the bulk density and the porosity of the porous materials are 0.9-1.2 g cm(-3) and 50-60%, respectively, and the pore structure has a closed form. The thermal conductivity of the porous material is 0.1946 W m(-1) K(-1). Therefore, the slag composite materials are lightweight and thermal insulators having considerable potential for building applications. Copyright © 2013 Elsevier Ltd. All rights reserved.

  15. Production of materials with alumina and ashes from incineration of chromium tanned leather shavings: environmental and technical aspects.

    Science.gov (United States)

    Basegio, T; Haas, C; Pokorny, A; Bernardes, A M; Bergmann, C P

    2006-09-21

    The leather tannery industry produces a significant amount of solid and hazardous wastes. Chromium-containing wastes like tanned shavings used to be incinerated in order to recover energy. The incineration process generates ashes that must be disposed of. This paper is a report on the results of the evaluation of technological properties and environmental compatibility of products made of alumina and ashes from incinerated chrome tanned shavings. The raw materials, tannery ashes and alumina were mixed together in different proportions. The ceramic bodies were molded using a hydraulic press and fired with a heating rate of 100 K/h until 1400 degrees C for 4 h in a muffle furnace. The ceramic specimens were characterized regarding physical, mechanical and thermal properties. Leaching tests, according to Brazilian, German and Dutch regulations, were performed on ceramic bodies containing different additions of ash. Results show that the ceramic materials produced are acceptable for refractory applications.

  16. Environmental impact assessment of the incineration of municipal solid waste with auxiliary coal in China

    DEFF Research Database (Denmark)

    Zhao, Yan; Xing, Wei; Lu, Wenjing

    2012-01-01

    The environmental impacts of waste incineration with auxiliary coal were investigated using the life-cycle-based software, EASEWASTE, based on the municipal solid waste (MSW) management system in Shuozhou City. In the current system, MSW is collected, transported, and incinerated with 250kg of coal...... per ton of waste. Based on observed environmental impacts of incineration, fossil CO2 and heavy metals were primary contributors to global warming and ecotoxicity in soil, respectively. Compared with incinerators using excess coal, incineration with adequate coal presents significant benefits...... (GB13223-2011)” implemented in 2012 introduced stricter policies on controlling SO2 and NOx emissions from coal power plants. Thus, increased use of auxiliary coal during incineration yields fewer avoided impacts on acidification and nutrient enrichment. When two-thirds of ash is source-separated...

  17. Recovery and distribution of incinerated aluminum packaging waste.

    Science.gov (United States)

    Hu, Y; Bakker, M C M; de Heij, P G

    2011-12-01

    A study was performed into relations between physical properties of aluminum packaging waste and the corresponding aluminum scraps in bottom ash from three typical incineration processes. First, Dutch municipal solid waste incineration (MSWI) bottom ash was analyzed for the identifiable beverage can alloy scraps in the +2mm size ranges using chemical detection and X-ray fluorescence. Second, laboratory-scale pot furnace tests were conducted to investigate the relations between aluminum packaging in base household waste and the corresponding metal recovery rates. The representative packaging wastes include beverage cans, foil containers and thin foils. Third, small samples of aluminum packaging waste were incinerated in a high-temperature oven to determine leading factors influencing metal recovery rates. Packaging properties, combustion conditions, presence of magnesium and some specific contaminants commonly found in household waste were investigated independently in the high-temperature oven. In 2007, the bottom ash (+2mm fraction) from the AEB MSWI plant was estimated to be enriched by 0.1 wt.% of aluminum beverage cans scrap. Extrapolating from this number, the recovery potential of all eleven MSWI plants in the Netherlands is estimated at 720 ton of aluminum cans scrap. More than 85 wt.% of this estimate would end up in +6mm size fractions and were amenable for efficient recycling. The pot furnace tests showed that the average recovery rate of metallic aluminum typically decreases from beverage cans (93 wt.%) to foil containers (85 wt.%) to thin foils (77 wt.%). The oven tests showed that in order of decreasing impact the main factors promoting metallic aluminum losses are the packaging type, combustion temperature, residence time and salt contamination. To a lesser degree magnesium as alloying element, smaller packaging size and basic contaminations may also promote losses. Crown Copyright © 2011. Published by Elsevier Ltd. All rights reserved.

  18. Phosphorus dissolution from ash of incinerated sewage sludge and animal carcasses using sulphuric acid.

    Science.gov (United States)

    Cohen, Yariv

    2009-10-01

    Large amounts of phosphorus are present in organic waste, mainly in sewage sludge and animal by-products. Increasingly, the waste is incinerated and phosphorus ends up in the ash. Sustainable waste management requires the beneficial reuse of phosphorus present in such ash. The first necessary step when recovering phosphorus from ash is dissolution by acid. The objective of this study was to quantify the acid requirement for phosphorus dissolution from sewage sludge ash and animal carcass ash. Both the amount of acid applied and its concentration were varied. Furthermore, phosphorus dissolution was optimized by controlling the pH during acid addition. Elemental analysis of sewage sludge ash showed that it comprised 6-10% P, 7-18% Ca, 2-11% Fe and 3-9% Al. The elemental content of animal carcass ash was even higher: 18% P and 30% Ca. The amount of acid required to obtain >85% phosphorus dissolution from sludge ash was 0.39-0.78 kg H2SO4 kg(-1) ash, depending on the total cation/phosphorus equivalent ratio. The amount required to obtain the highest possible P dissolution within two hours (73%) from animal carcass ash was 0.69 kg H2SO4 kg(-1) ash. Lower amounts of sulphuric acid were required for P dissolution in ashes of sludge from a bio-P treatment process and animal carcass, compared with the theoretical acid requirement for apatite dissolution. Applying pH control during dissolution resulted in reduced acid consumption (20%) and enabled more than 85% phosphorus dissolution from sludge ash at pH 2.0 in the two-hour dissolution time.

  19. Quantifying capital goods for waste incineration

    DEFF Research Database (Denmark)

    Brogaard, Line Kai-Sørensen; Riber, C.; Christensen, Thomas Højlund

    2013-01-01

    Materials and energy used for the construction of modern waste incineration plants were quantified. The data was collected from five incineration plants (72,000–240,000tonnes per year) built in Scandinavia (Norway, Finland and Denmark) between 2006 and 2012. Concrete for the buildings was the main...... of producing the materials used in the construction, steel for the building and the machinery contributed the most. The material and energy used for the construction corresponded to the emission of 7–14kg CO2 per tonne of waste combusted throughout the lifetime of the incineration plant. The assessment showed...... material used amounting to 19,000–26,000tonnes per plant. The quantification further included six main materials, electronic systems, cables and all transportation. The energy used for the actual on-site construction of the incinerators was in the range 4000–5000MWh. In terms of the environmental burden...

  20. Thermal Stability and Material Balance of Nanomaterials in Waste Incineration

    Science.gov (United States)

    Paur, H.-R.; Baumann, W.; Hauser, M.; Lang, I.; Teuscher, N.; Seifert, H.; Stapf, D.

    2017-06-01

    Nanostructured materials are widely used to improve the properties of consumer products such as tires, cosmetics, light weight equipment etc. Due to their complex composition these products are hardly recycled and thermal treatment is preferred. In this study we investigated the thermal stability and material balance of nanostructured metal oxides in flames and in an industrial waste incinerator. We studied the size distribution of nanostructured metal oxides (CeO2, TiO2, SiO2) in a flame reactor and in a heated reaction tube. In the premixed ethylene/air flame, nano-structured CeO2 partly evaporates forming a new particle mode. This is probably due to chemical reactions in the flame. In addition sintering of agglomerates takes place in the flame. In the electrically heated reaction tube however only sintering of the agglomerated nanomaterials is observed. Ceria has a low background in waste incinerators and is therefore a suitable tracer for investigating the fate of nanostructured materials. Low concentrations of Ceria were introduced by a two-phase nozzle into the post-combustion zone of a waste incinerator. By the incineration of coal dust in a burning chamber the Ceria nanoparticles are mainly found in the size range of the fly ash (1 - 10 µm) because of agglomeration. With gas as a fuel less agglomeration was observed and the Ceria nanoparticles were in the particle size range below 1 µm.

  1. Heavy metals in MSW incineration fly ashes

    DEFF Research Database (Denmark)

    Ferreira, Celia; Ribeiro, Alexandra B.; Ottosen, Lisbeth M.

    2003-01-01

    is characterized regarding its physical-chemical properties: pH, solubility, chemical composition, and leaching, amongst others. Results indicate a high alkalinity and the presence of large amounts of calcium, chlorides, sulfates, carbonates, sodium and potassium. Metal concentrations in fly ash are: 6,2 g....../kg for zinc, 2,4 g/kg for lead, 1,7 g/kg for iron, and 7,9 g/kg for magnesium. Copper, manganese, chromium and cadmium are also present with 546, 338, 104 and 91 mg/kg of fly ash, respectively. These results are extremely important in subsequent studies on the treatment of fly ash....

  2. Treatment and recycling of incinerated ash using thermal plasma technology.

    Science.gov (United States)

    Cheng, T W; Chu, J P; Tzeng, C C; Chen, Y S

    2002-01-01

    To treat incinerated ash is an important issue in Taiwan. Incinerated ashes contain a considerable amount of hazardous materials such as dioxins and heavy metals. If these hazardous materials are improperly treated or disposed of, they shall cause detrimental secondary contamination. Thermal plasma vitrification is a robust technology to treat and recycle the ash residues. Under the high temperature plasma environment, incinerated ashes are vitrified into benign slag with large volume reduction and extreme detoxification. Several one-step heat treatment processes are carried out at four temperatures (i.e. 850, 950, 1,050 and 1,150 degrees C) to obtain various "microstructure materials". The major phase to form these materials is a solid solution of gehlenite (Ca2Al2SiO7) and åkermanite (Ca2MgSi2O7) belonging to the melilite group. The physical and mechanical properties of the microstructure materials are improved by using one-step post-heat treatment process after plasma vitrification. These microstructure materials with good quality have great potential to serve as a viable alternative for construction applications.

  3. Quantifying capital goods for waste incineration

    Energy Technology Data Exchange (ETDEWEB)

    Brogaard, L.K., E-mail: lksb@env.dtu.dk [Department of Environmental Engineering, Building 115, Technical University of Denmark, DK-2800 Kongens Lyngby (Denmark); Riber, C. [Ramboll, Consulting Engineers, Hannemanns Allé 53, DK-2300 Copenhagen S (Denmark); Christensen, T.H. [Department of Environmental Engineering, Building 115, Technical University of Denmark, DK-2800 Kongens Lyngby (Denmark)

    2013-06-15

    Highlights: • Materials and energy used for the construction of waste incinerators were quantified. • The data was collected from five incineration plants in Scandinavia. • Included were six main materials, electronic systems, cables and all transportation. • The capital goods contributed 2–3% compared to the direct emissions impact on GW. - Abstract: Materials and energy used for the construction of modern waste incineration plants were quantified. The data was collected from five incineration plants (72,000–240,000 tonnes per year) built in Scandinavia (Norway, Finland and Denmark) between 2006 and 2012. Concrete for the buildings was the main material used amounting to 19,000–26,000 tonnes per plant. The quantification further included six main materials, electronic systems, cables and all transportation. The energy used for the actual on-site construction of the incinerators was in the range 4000–5000 MW h. In terms of the environmental burden of producing the materials used in the construction, steel for the building and the machinery contributed the most. The material and energy used for the construction corresponded to the emission of 7–14 kg CO{sub 2} per tonne of waste combusted throughout the lifetime of the incineration plant. The assessment showed that, compared to data reported in the literature on direct emissions from the operation of incinerators, the environmental impacts caused by the construction of buildings and machinery (capital goods) could amount to 2–3% with respect to kg CO{sub 2} per tonne of waste combusted.

  4. Solid waste utilization: incineration with heat recovery

    Energy Technology Data Exchange (ETDEWEB)

    Boegly, W.J. Jr.

    1978-04-01

    As a part of the Integrated Community Energy Systems (ICES) Program, Technology Evaluations, this evaluation considers the potential utilization of municipal solid wastes as an energy source by use of incineration with heat recovery. Subjects covered include costs, design data, inputs and outputs, and operational problems. Two generic types of heat recovery incinerators are evaluated. The first type, called a waterwall incinerator, is one in which heat is recovered directly from the furnace using water circulated through tubes imbedded in the furnace walls. This design normally is used for larger installations (>200 tons/day). The second type, a starved-air incinerator is used mainly in smaller sizes (<100 tons/day). Burning is performed in the incinerator, and heat recovery is obtained by the use of heat exchangers on the flue gases from the incinerator. Currently there are not many installations of either type in the United States; however, interest in this form of solid-waste handling appears to be increasing.

  5. Incineration facilities for treatment of radioactive wastes: a review

    Energy Technology Data Exchange (ETDEWEB)

    Perkins, B.L.

    1976-02-01

    A description is given of incinerator installations in the US and in foreign countries. Included are descriptions of inactive incinerators, incinerator facilities currently in operation, and incinerator installations under construction. Special features of each installation and operational problems of each facility are emphasized. Problems in the incineration of radioactive waste are discussed in relation to the composition of the waste and the amount and type of radioactive contaminant.

  6. Recycling of ash from biomass incinerator in clay matrix to produce ceramic bricks.

    Science.gov (United States)

    Pérez-Villarejo, L; Eliche-Quesada, D; Iglesias-Godino, Fco J; Martínez-García, C; Corpas-Iglesias, Fco A

    2012-03-01

    The objective of this study is to investigate the effect of incorporation of ash from biomass incinerator as raw material on the production of ceramic bricks for their application in construction. So, for the fabrication of bricks, compositions were prepared with addition of increasing amounts of waste ash (0%, 10%, 20%, 30%, 40% and 50% in wt.) in the clay body. The mixed samples were sintered using conventional powder processing based on powder compaction at 54.5 MPa and firing them at 950 °C without the addition of additives. Effect on apparent density, water absorption and mechanical properties were investigated. The results showed that water absorption increased and apparent density and compressive strength decreased with higher amounts of ash. Bricks with an ash content up to 20% meet the UNE standards compressive strength. As a result, since interesting performances were observed, the potential use of ashes from biomass incinerator up to 20 wt.% in ceramic formulations of industrial interest was confirmed. In this sense, incorporating ashes into clay body reduces environmental problems and total cost of raw material disposition. Copyright © 2010. Published by Elsevier Ltd.

  7. Usage of Ash from Coal incineration in Wuhai, China

    OpenAIRE

    Sun, Shiyu

    2007-01-01

    This master thesis has been carried out at Industrial Ecology at Royal Institute ofTechnology, KTH, in cooperation with Swedish Environmental Research Institute, IVL.This thesis discussed the usage of the ash from coal incineration in Wuhai, Inner Mongolia,China by studying and analyzing the fly ash from the case plant, the North Power Company.In the first part, there are some background information about the study area, like Wuhaicity and the case plant, the North Power Company. The study fo...

  8. Energy utilization: municipal waste incineration. Final report

    Energy Technology Data Exchange (ETDEWEB)

    LaBeck, M.F.

    1981-03-27

    An assessment is made of the technical and economical feasibility of converting municipal waste into useful and useable energy. The concept presented involves retrofitting an existing municipal incinerator with the systems and equipment necessary to produce process steam and electric power. The concept is economically attractive since the cost of necessary waste heat recovery equipment is usually a comparatively small percentage of the cost of the original incinerator installation. Technical data obtained from presently operating incinerators designed specifically for generating energy, documents the technical feasibility and stipulates certain design constraints. The investigation includes a cost summary; description of process and facilities; conceptual design; economic analysis; derivation of costs; itemized estimated costs; design and construction schedule; and some drawings.

  9. Treatment of radioactive wastes by incineration; Tratamiento de desechos radiactivos por incineracion

    Energy Technology Data Exchange (ETDEWEB)

    Priego C, E., E-mail: emmanuel.priego@inin.gob.mx [ININ, Carretera Mexico-Toluca s/n, 52750 Ocoyoacac, Estado de Mexico (Mexico)

    2013-10-15

    Great part of the radioactive wastes of low and intermediate level generated during the nuclear fuel cycle, in laboratories and other sites where the radionuclides are used for the research in the industry, in medicine and other activities, are combustible wastes. The incineration of these radioactive wastes provides a very high reduction factor and at the same time converts the wastes in radioactive ashes and no-flammable residuals, chemically inert and much more homogeneous that the initial wastes. With the increment of the costs in the repositories and those every time but strict regulations, the incineration of radioactive wastes has been able to occupy an important place in the strategy of the wastes management. However, in a particular way, the incineration is a complex process of high temperature that demands the execution of safety and operation requirements very specific. (author)

  10. Sludge as dioxins suppressant in hospital waste incineration.

    Science.gov (United States)

    Yan, Mi; Li, Xiaodong; Yang, Jie; Chen, Tong; Lu, Shengyong; Buekens, Alfons G; Olie, Kees; Yan, Jianhua

    2012-07-01

    Nitrogen containing compounds such as ammonia, urea and amines can effectively inhibit the formation of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs). Sewage sludge accumulates both sulfur and nitrogen during wastewater treatment so it could be used to reduce PCDD/Fs formation. Indeed, it is observed in this study that the gas evolving from the sludge drying process can significantly suppress chlorobenzene (CBz) and PCDD/Fs formation from fly ash collected from a hospital waste incinerator. For instance, the reduction of hexachlorobenzene (HxCBz) and PCDD/Fs amount was 92.1% and 78.7%, respectively, when the drying gas evolving from 2g sludge flew through 2g fly ash. These tests were conducted in the frame of projects devoted to hospital waste incineration. The disposal technology for hospital waste (HW), developed in this institute, features rotary kiln pyrolysis combined with post-combustion followed by flue gas cleaning. Hence, some preliminary tests were devoted to investigate dioxins suppression by co-pyrolysis and co-combustion of polyvinyl chloride (PVC) and sludge in lab scale. More experimental research will be conducted to appropriately assess these effects of sludge on PCDD/Fs emissions during co-pyrolysis/combustion of HW and sludge. Copyright © 2012 Elsevier Ltd. All rights reserved.

  11. Incineration, pyrolysis and gasification of electronic waste

    Directory of Open Access Journals (Sweden)

    Gurgul Agnieszka

    2017-01-01

    Full Text Available Three high temperature processes of the electronic waste processing: smelting/incineration, pyrolysis and gasification were shortly discussed. The most distinctive feature of electronic waste is complexity of components and their integration. This type of waste consists of polymeric materials and has high content of valuable metals that could be recovered. The purpose of thermal treatment of electronic waste is elimination of plastic components (especially epoxy resins while leaving non-volatile mineral and metallic phases in more or less original forms. Additionally, the gaseous product of the process after cleaning may be used for energy recovery or as syngas.

  12. Incineration, pyrolysis and gasification of electronic waste

    Science.gov (United States)

    Gurgul, Agnieszka; Szczepaniak, Włodzimierz; Zabłocka-Malicka, Monika

    2017-11-01

    Three high temperature processes of the electronic waste processing: smelting/incineration, pyrolysis and gasification were shortly discussed. The most distinctive feature of electronic waste is complexity of components and their integration. This type of waste consists of polymeric materials and has high content of valuable metals that could be recovered. The purpose of thermal treatment of electronic waste is elimination of plastic components (especially epoxy resins) while leaving non-volatile mineral and metallic phases in more or less original forms. Additionally, the gaseous product of the process after cleaning may be used for energy recovery or as syngas.

  13. Evaluating the use of waste-to-energy bottom ash as road construction materials.

    Science.gov (United States)

    2014-02-01

    Current management practice, existing regulations, and environmental consequences of municipal solid : waste incineration (MSWI) ash utilization were comprehensively reviewed worldwide and nationwide : in the U.S. Efforts were made to physically and ...

  14. Effect of composition variations on the long-term wasteform behavior of vitrified domestic waste incineration fly-ash purification residues; Influence des variations de composition des vitrifiats de refiom - residus d'epuration des fumees d'incineration d'ordures menageres - sur leur comportement a long terme

    Energy Technology Data Exchange (ETDEWEB)

    Frugier, P.

    2000-07-01

    The effect of variations in the composition of fly-ash purification residue from incinerated domestic waste on the quality of the containment achieved by vitrification was investigated. Three main factors determine the long-term containment quality: the production of a vitrified wasteform, the occurrence of possible crystallization, and the key parameters of long-term alteration in aqueous media. Each of these aspects is described within a composition range defined by variations in the three major elements. (silicon, calcium and aluminum) and two groups of constituents (alkali metals and toxic elements). The silicon fraction in the fly-ash residue was found to be decisive: it is impossible to obtain a satisfactory vitrified wasteform below a given silicon concentration. Compounds with the lowest silica content also exhibited the greatest tendency to crystallize under the cooling conditions prevailing in industrial processes (the dominant crystallized phase is a melilite that occupies a significant fraction of the material and considerably modifies the alteration mechanisms). The initial alteration rate in pure water and the altered glass thickness measured in a closed system at an advanced stage of the dissolution reaction are both inversely related to the silicon concentration in the glass. Several types of long-term behavior were identified according to the composition range, the process conditions and the vitrified waste disposal scenario. Four distinct 'classes' of vitrified wasteform were defined for direct application in industrial processes. (author)

  15. Waste processing building with incineration technology

    Science.gov (United States)

    Wasilah, Wasilah; Zaldi Suradin, Muh.

    2017-12-01

    In Indonesia, waste problem is one of major problem of the society in the city as part of their life dynamics. Based on Regional Medium Term Development Plan of South Sulawesi Province in 2013-2018, total volume and waste production from Makassar City, Maros, Gowa, and Takalar Regency estimates the garbage dump level 9,076.949 m3/person/day. Additionally, aim of this design is to present a recommendation on waste processing facility design that would accommodate waste processing process activity by incineration technology and supported by supporting activity such as place of education and research on waste, and the administration activity on waste processing facility. Implementation of incineration technology would reduce waste volume up to 90% followed by relative negative impact possibility. The result planning is in form of landscape layout that inspired from the observation analysis of satellite image line pattern of planning site and then created as a building site pattern. Consideration of building orientation conducted by wind analysis process and sun path by auto desk project Vasari software. The footprint designed by separate circulation system between waste management facility interest and the social visiting activity in order to minimize the croos and thus bring convenient to the building user. Building mass designed by inseparable connection series system, from the main building that located in the Northward, then connected to a centre visitor area lengthways, and walked to the waste processing area into the residue area in the Southward area.

  16. Tracing source and migration of Pb during waste incineration using stable Pb isotopes

    Energy Technology Data Exchange (ETDEWEB)

    Li, Yang [State Key Laboratory of Pollution Control and Resources Reuse, Tongji University, 1239 Siping Road, Shanghai 200092 (China); Institute of Waste Treatment and Reclamation, Tongji University, 1239 Siping Road, Shanghai 200092 (China); Zhang, Hua, E-mail: zhanghua_tj@tongji.edu.cn [State Key Laboratory of Pollution Control and Resources Reuse, Tongji University, 1239 Siping Road, Shanghai 200092 (China); Institute of Waste Treatment and Reclamation, Tongji University, 1239 Siping Road, Shanghai 200092 (China); Shao, Li-Ming; He, Pin-Jing [Institute of Waste Treatment and Reclamation, Tongji University, 1239 Siping Road, Shanghai 200092 (China); Research and Training Center on Rural Waste Management, Ministry of Housing and Urban-Rural Development of P.R. China, 1239 Siping Road, Shanghai 200092 (China)

    2017-04-05

    Highlights: • The migration of Pb during waste incineration was investigated using Pb isotopes. • Source tracing of Pb during incineration by isotopic technology was feasible. • Contributions of MSW components were measured to trace Pb sources quantitatively. • Isotopic technology helps understand the migration of Pb during thermal treatment. - Abstract: Emission of Pb is a significant environmental concern during solid waste incineration. To target Pb emission control strategies effectively, the major sources of Pb in the waste incineration byproducts must be traced and quantified. However, identifying the migration of Pb in each waste component is difficult because of the heterogeneity of the waste. This study used a laboratory-scale incinerator to simulate the incineration of municipal solid waste (MSW). The Pb isotope ratios of the major waste components ({sup 207}Pb/{sup 206}Pb = 0.8550–0.8627 and {sup 208}Pb/{sup 206}Pb = 2.0957–2.1131) and their incineration byproducts were measured to trace sources and quantify the Pb contribution of each component to incineration byproducts. As the proportions of food waste (FW), newspaper (NP), and polyethylene bag (PE) in the artificial MSW changed, the contribution ratios of FW and PE to Pb in fly ash changed accordingly, ranging from 31.2% to 50.6% and from 35.0% to 41.8%, respectively. The replacement of PE by PVC significantly increased the partitioning and migration ratio of Pb. The use of Pb isotope ratios as a quantitative tool for tracing Pb from raw waste to incineration byproducts is a feasible means for improving Pb pollution control.

  17. An emerging pollutant contributing to the cytotoxicity of MSWI ash wastes: Strontium

    Energy Technology Data Exchange (ETDEWEB)

    Huang, Wu-Jang, E-mail: wjhuang@mail.npust.edu.tw [Department of Environmental Engineering and Science, National Ping-Tung University of Science and Technology, 912 Ping-Tung, Taiwan (China); Tang, Hsing-Chuan [Department of Environmental Engineering and Science, National Ping-Tung University of Science and Technology, 912 Ping-Tung, Taiwan (China); Lin, Kae-Long [Department of Environmental Engineering, National I-Lan University, 260 I-Lan, Taiwan (China); Liao, Ming-Huei [Department of Veterinary Medicine, National Ping-Tung University of Science and Technology, 912 Ping-Tung, Taiwan (China)

    2010-01-15

    In this study, we used the multiple toxicity characteristic leaching procedure to test the long-term leaching behavior of bottom ash, scrubber residue, and baghouse ash from a municipal solid waste incinerator (MSWI). We used the short-term viability percentage of African green monkey kidney cells (Vero cells) as a bioindicator to investigate the cytotoxicity of the leachates from the MSWI ash wastes. We found that strontium was a significant contributor to the cytotoxicity of the bottom ash.

  18. Exergy analysis of aluminum recovery from municipal solid waste incineration

    DEFF Research Database (Denmark)

    Vyzinkarova, Dana; Allegrini, Elisa; Laner, D.

    in a two-step system consisting of a waste-to-energy process and a consequent bottom ash treatment. B) An aluminum-pre-sorting step takes place prior to the thermal treatment. In case of B, an additional exergy is spent on pre-sorting, but, in return, a metal of higher quality is obtained. The discussion......Two main challenges, associated with the recovery of aluminum from state-of-the-art municipal solid waste (MSW) incineration plants, are yield as well as quality losses of metallic aluminum due to particle surface oxidation and presence of impurities. Yet, in the framework of life cycle assessment...... in parallel to each other, with a goal to evaluate the added value of exergy for LCA studies in the resource recovery context. The functional unit is the treatment of 1 ton MSW. Two alternative approaches for recovering aluminum from MSW directed to a waste-to-energy plant are considered. A) MSW is treated...

  19. Clinical waste incinerators in Cameroon--a case study

    DEFF Research Database (Denmark)

    Mochungong, Peter Ikome Kuwoh; Gulis, Gabriel; Sodemann, Morten

    2012-01-01

    Incinerators are widely used to treat clinical waste in Cameroon's Northwest Region. These incinerators cause public apprehension owing to purported risks to operators, communities and the environment. This article aims to summarize findings from an April 2008 case study.......Incinerators are widely used to treat clinical waste in Cameroon's Northwest Region. These incinerators cause public apprehension owing to purported risks to operators, communities and the environment. This article aims to summarize findings from an April 2008 case study....

  20. Danish Emission Inventory for Waste Incineration and Other Waste

    DEFF Research Database (Denmark)

    Hjelgaard, Katja

    2013-01-01

    This report contains detailed methodological issues, activity data, emission factors, uncertainties and references for waste incineration without energy recovery and other waste source categories of the Danish emission inventories 2013. The emissions are calculated for the years 1980-2011 according...

  1. Vitrified bottom ash slag from municipal solid waste incinerators - Phase relations of CaO-SiO2-Na20 oxide system

    NARCIS (Netherlands)

    Zhang, Z.; Xiao, Y.; Yang, Y.; Boom, R.; Voncken, J.H.L.

    2009-01-01

    Vitrification is considered to be an attractive technology for bottom ash treatment because it destroys the hazardous organics, contributes to immobilization of the heavy metals, and additionally it reduces drastically the volume. The main components of the vitrified bottom ash slag are SiO2 , CaO,

  2. Experimental investigation in separating the heavy metal elements of refuse incineration fly ashes by using molten iron

    Energy Technology Data Exchange (ETDEWEB)

    Yang, J. [Chongqing Univ., Chongqing (China)]|[CPI-Yuanda Environmental-protection Engineering Co. Ltd., Chongqing (China); Liu, Q.; Dong, L. [Chongqing Univ., Chongqing (China); Du, Y. [CPI-Yuanda Environmental-protection Engineering Co. Ltd., Chongqing (China)

    2008-07-01

    One of the main waste treatment methods in the world for municipal solid waste (MSW) is incineration. It is effective in toxic substance destruction, waste volume reduction, and energy recovery. Some chemical substances are accumulated during incineration, most notably lead, zinc, chromium and cadmium, as well as other heavy metals. Untreated fly ash disposed in landfills can pollute the soil, surface water and groundwater because of the high levels of hazardous heavy metals and high salt concentration that can be leached out. This paper presented an experiment that melt-separated the heavy metal elements from fly ash generated during refuse incineration. Molted iron, was used as resolvent to dissolve the heavy metal elements in it. The paper described the materials and methods as well as the results of the study. It was concluded that using molted iron to separate the heavy metal elements from MSW incineration fly ash was feasible. The removal ratio of the main heavy metal elements was above 80 per cent, and some of it was above 99 per cent. 5 refs., 7 tabs., 1 fig.

  3. Flow analysis of heavy metals in a pilot-scale incinerator for residues from waste electrical and electronic equipment dismantling

    Energy Technology Data Exchange (ETDEWEB)

    Long, Yu-Yang; Feng, Yi-Jian; Cai, Si-Shi; Ding, Wei-Xu; Shen, Dong-Sheng, E-mail: shends@zju.edu.cn

    2013-10-15

    Highlights: • Cu, Zn, Pb, and Ni are enriched in bottom ash from WEEE dismantling residues. • The heavy metal residual fraction restricts transfer in the incinerator. • Pre-treatment to remove heavy metals from WEEE residues would reduce emissions. -- Abstract: The large amount of residues generated from dismantling waste electrical and electronic equipment (WEEE) results in a considerable environmental burden. We used material flow analysis to investigate heavy metal behavior in an incineration plant in China used exclusively to incinerate residues from WEEE dismantling. The heavy metals tested were enriched in the bottom and fly ashes after incineration. However, the contents of heavy metals in the bottom ash, fly ash and exhaust gas do not have a significant correlation with that of the input waste. The evaporation and recondensation behavior of heavy metals caused their contents to differ with air pollution control equipment because of the temperature difference during gas venting. Among the heavy metals tested, Cd had the strongest tendency to transfer during incineration (T{sub Cd} = 69.5%) because it had the lowest melting point, followed by Cu, Ni, Pb and Zn. The exchangeable and residual fractions of heavy metals increased substantially in the incineration products compared with that of the input residues. Although the mass of residues from WEEE dismantling can be reduced by 70% by incineration, the safe disposal of the metal-enriched bottom and fly ashes is still required.

  4. Significance of waste incineration in Germany; Stellenwert der Abfallverbrennung in Deutschland

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2008-10-15

    The report on the relevance of waste incineration in Germany is covering the following issues: change of the issue waste incineration in the last century, the controversy on waste incineration in the 80ies; environmental relevance of waste incineration; utilization of incineration residues; contribution to environmental protection; possible hazards for human health due are waste incinerator plants; the central challenges of waste incineration today; potential restraints to energy utilization in thermal waste processing; optimization of the energetic utilization of municipal wastes; future of the waste management and the relevance of waste incineration.

  5. Experience of superheater tubes in municipal waste incineration plant

    Energy Technology Data Exchange (ETDEWEB)

    Noguchi, M.; Yakuwa, H.; Miyasaka, M. [Ebara Research Co., Ltd., Fujisawa-shi (Japan); Yokono, M.; Matsumoto, A. [Tokachi Association for Municipal Disposal and Treatment Services, Obihiro-shi (Japan); Miyoshi, K.; Kosaka, K. [Ebara Co., Ltd. Minatominami Minato-ku (Japan); Fukuda, Y. [Babcock-Hitachi K.K. Kure Research Lab., Hiroshima-ken (Japan)

    2000-11-01

    Two years after the start of operations at the Tokachi Association for Municipal Waste Disposal and Treatment Services municipal waste incineration plant (name: Kuririn Center), which generates 400 C steam, an investigation of the plant's superheater tubes was conducted. The investigation consisted primarily of analyzing ash deposits, measuring tube wall thickness loss and observing tube sections after removal. The concentration of Cl in the deposited ash was found to increase as the temperature of the gas rose, and the amount of deposited ash tended to increase as the temperature of the gas rose. Tube damage consisted primarily of a uniform loss in thickness. Intergranular corrosion and other local corrosion was not observed. The results of thickness-loss measurements showed that, after approximately two years in operation, tubes (SUS310) lost a maximum of 0.45 mm in thickness due to high-temperature corrosion in locations where the steam temperature reached 400 C. Superheater tubes were also apparently damaged from the effects of a soot blower, resulting in an observed maximum loss of 0.9 mm thickness after approximately two years. Furthermore, the rate of thickness loss tended to increase after one year had passed. (orig.)

  6. Curbing dioxin emissions from municipal solid waste incineration in China: re-thinking about management policies and practices.

    Science.gov (United States)

    Cheng, Hefa; Hu, Yuanan

    2010-09-01

    As one of the countries with large amounts of dioxin releases, the control of dioxins is a major challenge for China. Municipal solid waste (MSW) incineration should be considered a high priority source of dioxin emissions because it is playing an increasingly more important role in waste management. MSW incineration in China has much higher emission rates of dioxins than in the developed countries, partially resulting from the gaps in the technologies of incineration and flue gas cleaning. Moreover, the current management policies and practices also contribute significantly to the problem. We recommend lowering dioxin emission standard, strengthening fly ash management, and improving regulation enforcement to reduce dioxin releases into the environment from MSW incineration. We also propose that alternative strategies should be considered on dioxin control and call for an expansion of economic instruments in waste management to reduce waste generation and thus the need for incineration. Copyright (c) 2010 Elsevier Ltd. All rights reserved.

  7. Electrodialytic remediation of municipal solid waste incineration residues using different membranes

    DEFF Research Database (Denmark)

    Parés Viader, Raimon; Jensen, Pernille Erland; Ottosen, Lisbeth M.

    2017-01-01

    In the present work, three different commercial membrane brands were used in an identical electrodialytic cell setup and operating conditions, in order to reduce the leaching of metals and salt anions of two types of municipal solid waste incineration residues: air pollution control residues...... below than those of certified coal fly ash (e.g. Al or Cr), a material which is commonly used in construction materials; at the same time, some of these values were reduced to below the Danish law thresholds on the use of contaminated soil in constructions. These results show the potential of ED...... as a technology to upgrade municipal solid waste incineration residues....

  8. Nutrient recovery from ash after incineration of organic residues

    Energy Technology Data Exchange (ETDEWEB)

    Hermann, L. [ASH DEC Umwelt AG, Vienna (Austria)

    2006-08-15

    Organic residues (sewage sludge, biomass, manure) contain significant amounts of nutrients and organic matter that have justified their cheap disposal on cropland. In recent years, however, many plant and soil scientists, public authorities and food industry companies have called for restrictions on uncontrolled spreading of organic residues on cropland because of constant (PAHs, phthalates) or increasing (PBDEs, Bisphenol A, hormones, antibiotics etc.) concentrations of organic pollutants and heavy metals that are partly accumulated in soils and may be transferred to the food chain. Moreover, intensive cattle and pig farming produces increasing quantities of manure that may lead to over-fertilization of croplands and eutrophication of aquatic bodies. An alternative and safe disposal route for organic residues in incineration that makes use of the calorific value of organics, yields energy, destroys the organic pollutants and concentrates inorganic pollutants and most nutrients - except nitrogen that is lost to the atmosphere - in the ash. Most sludge-, manure- and biomass ashes contain P and K (15-25%), Ca (20-30%); Si (15-25%), Fe (10-20%) and trace nutrients. Because of their commonly high concentrations of copper, zinc, lead and cadmium and their limited usability as a fertilizer (dust, insufficient nutrient plant availability) untreated ashes are frequently banned from application on crop- or woodland and are disposed of in landfills, where nutrient are lost or may even adversely affect water bodies. To minimize adverse effects of biomass-to-energy concepts, ash must be converted to a P-rich fertilizer raw material. The selected technological approach is a thermo-chemical ash treatment at around 1.000 deg. C that removes harmful heavy metals and makes P fully plant available. (BA)

  9. the development of new generation of solid waste refuse incinerators

    African Journals Online (AJOL)

    produce large volumes of organic wastes which rapidly become offensive in hot climates (Pickford, 1977) ... However, Rudden, (2004) explained that efficient combustion of any fuel including municipal solid waste ..... These incinerators can be fitted with filters to cope with the incineration of all forms of plastics as it is in.

  10. Oxidation and waste-to-energy output of aluminium waste packaging during incineration: A laboratory study.

    Science.gov (United States)

    López, Félix A; Román, Carlos Pérez; García-Díaz, Irene; Alguacil, Francisco J

    2015-09-01

    This work reports the oxidation behaviour and waste-to-energy output of different semi-rigid and flexible aluminium packagings when incinerated at 850°C in an air atmosphere enriched with 6% oxygen, in the laboratory setting. The physical properties of the different packagings were determined, including their metallic aluminium contents. The ash contents of their combustion products were determined according to standard BS ISO 1171:2010. The net calorific value, the required energy, and the calorific gain associated with each packaging type were determined following standard BS EN 13431:2004. Packagings with an aluminium lamina thickness of >50μm did not fully oxidise. During incineration, the weight-for-weight waste-to-energy output of the packagings with thick aluminium lamina was lower than that of packagings with thin lamina. The calorific gain depended on the degree of oxidation of the metallic aluminium, but was greater than zero for all the packagings studied. Waste aluminium may therefore be said to act as an energy source in municipal solid waste incineration systems. Copyright © 2015 Elsevier Ltd. All rights reserved.

  11. Development process for the stabilization of incinerator bottom ash and sizing baghouse dust material

    Energy Technology Data Exchange (ETDEWEB)

    Hunt, L.F.; Boehmer, A.M.

    1987-04-01

    EG G Idaho Inc. has initiated a program to develop safe, efficient, cost-effective treatment methods for the stabilization and subsequent disposal of some of the hazardous and mixed wastes generated at the Idaho National Engineering Laboratory (INEL). Lab-scale testing has shown that Extraction Procedure (EP) toxic wastes can be successfully stabilized by solidification, using various binders to produce nontoxic, stable waste forms for safe, long-term disposal. The purpose of this report is to present the results of drum-scale testing of WERF incinerator bottom ash and WERF sizing baghouse dust. The drum-scale test program was conducted to determine if a production procedure that would produce a waste form which was suitable for disposal as a low-level radioactive waste could be developed. The use of 71-gallon square drums for solidification processing were also evaluated. During the test program, eleven drums of ash material were solidified. All of the samples from all of the drums passed the EPA leach test criteria. Although there is a distinct weight addition associated with the solidification process, there is no relative volume increase. 4 refs., 6 figs., 8 tabs.

  12. Flow analysis of heavy metals in a pilot-scale incinerator for residues from waste electrical and electronic equipment dismantling.

    Science.gov (United States)

    Long, Yu-Yang; Feng, Yi-Jian; Cai, Si-Shi; Ding, Wei-Xu; Shen, Dong-Sheng

    2013-10-15

    The large amount of residues generated from dismantling waste electrical and electronic equipment (WEEE) results in a considerable environmental burden. We used material flow analysis to investigate heavy metal behavior in an incineration plant in China used exclusively to incinerate residues from WEEE dismantling. The heavy metals tested were enriched in the bottom and fly ashes after incineration. However, the contents of heavy metals in the bottom ash, fly ash and exhaust gas do not have a significant correlation with that of the input waste. The evaporation and recondensation behavior of heavy metals caused their contents to differ with air pollution control equipment because of the temperature difference during gas venting. Among the heavy metals tested, Cd had the strongest tendency to transfer during incineration (TCd=69.5%) because it had the lowest melting point, followed by Cu, Ni, Pb and Zn. The exchangeable and residual fractions of heavy metals increased substantially in the incineration products compared with that of the input residues. Although the mass of residues from WEEE dismantling can be reduced by 70% by incineration, the safe disposal of the metal-enriched bottom and fly ashes is still required. Copyright © 2013 Elsevier B.V. All rights reserved.

  13. Environmental assessment of the reuse of municipal solid waste incineration bottom ash in quarry backfilling; Evaluation environnementale de la valorisation de machefers d'incineration d'ordures menageres en remplissage de carriere

    Energy Technology Data Exchange (ETDEWEB)

    Brons-Laot, G.

    2002-10-15

    The leaching behaviour of three different MSWI bottom ashes-based materials containing hydraulic binders is assessed in the conditions specified by the quarry backfilling application. An adapted approach methodology is applied: - physical, mineralogical and chemical characterizations of materials, - use of parametric tests to determine the effect of main scenarios factors on the release, - chemical modelling based on mineralogical and experimental leaching data with geochemical calculation codes, - chemical reaction / transport coupled modelling. The main results demonstrate that: - the batch and dynamic tests allow to obtain enough data to model and to predict the long term behaviour, - the chemical modelling of the solid / liquid equilibrium permits the determination of the chemical reactions involved and the prediction of pollutants solubilization in different chemical contexts, - the new materials (source term) present a low environmental impact in the conditions specified by the considered scenarios. (author)

  14. Ash chemistry in MSW incineration plants: Advanced characterization and thermodynamic considerations

    Energy Technology Data Exchange (ETDEWEB)

    Frandsen, Flemming J.; Laursen, Karin; Arvelakis, S. (and others)

    2004-07-15

    A number of ash samples where collected at four Danish municipal solid waste incineration (MSWI) plants. Samples of bottom ash/slag, 2nd-3rd pass ashes and ESP/E-filter ash were collected at the plants. The ashes were analyzed by a number of standard chemical analyses, and a number of advanced analytical techniques. The wet chemical analyses of the different ash fractions revealed that residual ash is formed on the grate by interaction of the main ash forming elements, Al, Ca, Fe and Si. Some of this ash is entrained from the grate and carried with the flue gas along the flue gas duct, where volatile species of K, Na, Pb, Zn, Cl and S starts to condense heterogeneously on the fly ash, thereby causing a dilution of the main ash forming elements. When compared plant-by-plant, the ash chemical analyses showed that the plant with the highest S-content in the fly ash is the one with the most often operational problems in relation to deposition, while a high Cl-content is indicative of a high corrosive potential. An existing Computer Controlled Scanning Electron Microscopy (CCSEM) algorithm was extended with chemical classes covering Pb- and Zn-rich phases. This has made it possible also to analyze MSW-derived ashes by use of CCSEM. Representative samples of 2nd-3rd pass and ESP/E-filter ashes from the four plants have been analyzed by Quantitative X-Ray Diffraction (QXRD) analysis. Only a few crystalline phases were identified: KCl, NaCl, CaSO{sub 4}, SiO{sub 2} and CaCO{sub 3} being the main ones. No crystalline phases containing Pb or Zn were identified by QXRD. A comparison between CCSEM and QXRD revealed the expected surface nature of the CCSEM analysis. Samples of 2nd-3rd pass and ESP/E-filter ash from the four plants where investigated for melting behavior in the Simultaneous Thermal Analyzer (STA). It was shown that it is possible to quantify the melting behavior of these ashes, and that the melting goes on in two steps (salts followed by silicates/oxides). The

  15. LCA Comparison of waste incineration in Denmark and Italy

    DEFF Research Database (Denmark)

    Turconi, Roberto; Butera, Stefania; Boldrin, Alessio

    2011-01-01

    Every year around 50 millions Mg solid waste are incinerated in Europe. Large differences exist in different regions, mainly regarding energy recovery, flue gas treatment and management of solid residues. This paper aims to identify and quantify those differences, providing a Life Cycle Assessment...... of two incinerator systems that are representative of conditions in Northern and Southern Europe. The two case studies are Aarhus (Denmark) and Milan (Italy). The results show that waste incineration appears more environmentally friendly in the Danish case than in the Italian one, due to the higher...... energy recovery and to local conditions, e.g. substitution of electricity and heat in the area. Focusing on the incineration process, Milan incinerator performs better than Aarhus, since its upstream impacts (related to the production of chemicals used in flue gas cleaning) are more than compensated...

  16. Viscosity of ashes from energy production and municipal solid waste handling: A comparative study between two different experimental setups

    DEFF Research Database (Denmark)

    Arvelakis, Stelios; Frandsen, Flemming; Folkedahl, B.

    2008-01-01

    This paper discusses the viscosity characteristics of ash fractions produced from the co-combustion of coal and biomass in a pilot-scale pulverized fuel (PF) boiler and from the incineration of municipal solid waste (MSW) in a Danish incinerator that were determined using the high-temperature rot...

  17. Solid residues from Italian municipal solid waste incinerators: A source for "critical" raw materials.

    Science.gov (United States)

    Funari, Valerio; Braga, Roberto; Bokhari, Syed Nadeem Hussain; Dinelli, Enrico; Meisel, Thomas

    2015-11-01

    The incineration of municipal solid wastes is an important part of the waste management system along with recycling and waste disposal, and the solid residues produced after the thermal process have received attention for environmental concerns and the recovery of valuable metals. This study focuses on the Critical Raw Materials (CRM) content in solid residues from two Italian municipal waste incinerator (MSWI) plants. We sampled untreated bottom ash and fly ash residues, i.e. the two main outputs of common grate-furnace incinerators, and determined their total elemental composition with sensitive analytical techniques such as XRF and ICP-MS. After the removal of a few coarse metallic objects from bottom ashes, the corresponding ICP solutions were obtained using strong digestion methods, to ensure the dissolution of the most refractory components that could host significant amounts of precious metals and CRM. The integration of accurate chemical data with a substance flow analysis, which takes into account the mass balance and uncertainties assessment, indicates that bottom and fly ashes can be considered as a low concentration stream of precious and high-tech metals. The magnesium, copper, antimony and zinc contents are close to the corresponding values of a low-grade ore. The distribution of the elements flow between bottom and fly ash, and within different grain size fractions of bottom ash, is appraised. Most elements are enriched in the bottom ash flow, especially in the fine grained fractions. However, the calculated transfer coefficients indicate that Sb and Zn strongly partition into the fly ashes. The comparison with available studies indicates that the CRM concentrations in the untreated solid residues are comparable with those residues that undergo post-treatment beneficiations, e.g. separation between ferrous and non-ferrous fractions. The suggested separate collection of "fresh" bottom ash, which could be processed for further mineral upgrading, can

  18. Stabilize ash using Clemson`s sintering process (Part 1 -- Phase 1 results): Mixed waste fly ash stabilization. Innovative technology summary report

    Energy Technology Data Exchange (ETDEWEB)

    1998-12-01

    Incineration of applicable Department of Energy (DOE) mixed wastes has produced a secondary waste stream of radioactive and Resource Conservation and Recovery Act (RCRA) hazardous fly ash that also requires treatment before land disposal. Unlike bottom ash, fly ash usually contains constituents making efficient stabilization difficult. For example, fly ash from the DOE Waste Experimental Reduction Facility (WERF) incinerator at the Idaho National Engineering and Environmental Laboratory (INEEL) contains volatile metals, metal salts, high concentrations of zinc, and unburned organic residues. All of these constituents can effect the stabilization process. The Department of Energy, and in particular the Mixed Waste Focus Area (MWFA) of EM-50, has stated the need for improved stabilization methods would accept a higher ash waste loading while meeting waste form disposal criteria. These alternative stabilization technologies should include delivery systems to minimize worker exposure and minimize secondary waste generation, while maximizing operational flexibility and radionuclide containment. Currently, the standard practice for stabilizing ash is mixing with Portland cement at room temperature. This standard practice produces a significant increase of waste material volume or has difficulty in adequately stabilizing the components in the fly ash to ensure regulatory requirements are consistently satisfied. To address these fly ash stabilization shortcomings, the MWFA, a DOE/EM-50 program, invested in the development of several fly ash stabilization alternatives, including the Clemson University sintering method.

  19. Study of the leaching of heavy metals from waste water sludge and incinerator's ash, using coupled thermostated columns and DTPA as complex agent; Estudio de la extraccion de metales pesados de lodos y cenizas de aguas residuales usando columnas termostatizadas acopladas y DTPA como agente complejante

    Energy Technology Data Exchange (ETDEWEB)

    Vite T, J.; Vite T, M.; Guerrero D, J.; Carreno de Leon, M.C. [Departamento de Estudios del Ambiente, Instituto Nacional de Investigaciones Nucleares, A.P. 18-1027, 11801 Mexico D.F. (Mexico)

    2000-07-01

    We studied the metallic composition from waste water sludge and incinerators ashes of an incinerator located in Toluca, Mexico, the qualitative studies were made using the Activation Analysis technique, and fluorescence X-ray techniques. The quantitative analysis of heavy metals in the wastes were made using Inductively coupled plasma atomic emission spectrometry (Icp-Aes). For leaching the samples, we used four coupled thermostated columns, each one had a p H of 2,5, 7 and 10. The flux of the air was of 1600 cc/min. The temperature was maintain constant in 60 Centigrade using a thermostated system. For this study we used 100 g of wastes mixed with mineral acid or sodium hydroxide to reach p H 2,5,7 and 10. We added a reducing and tensoactive agents and finally DTPA as complex agent. With this method, we obtain a better leaching efficiency using a complex agent. However the high DTPA cost, make this process expansive that is why we recommend to work with another classes of complex agents, that be cheaper to leach metals of different chemistry matrix. (Author)

  20. Comparison of phosphorus recovery from incineration and gasification sewage sludge ash.

    Science.gov (United States)

    Parés Viader, Raimon; Jensen, Pernille Erland; Ottosen, Lisbeth M; Thomsen, Tobias P; Ahrenfeldt, Jesper; Hauggaard-Nielsen, Henrik

    2017-03-01

    Incineration of sewage sludge is a common practice in many western countries. Gasification is an attractive option because of its high energy efficiency and flexibility in the usage of the produced gas. However, they both unavoidably produce sewage sludge ashes, a material that is rich in phosphorus, but which is commonly landfilled or used in construction materials. With current uncertainty in phosphate rock supply, phosphorus recovery from sewage sludge ashes has become interesting. In the present work, ashes from incineration and gasification of the same sewage sludge were compared in terms of phosphorus extractability using electrodialytic (ED) methods. The results show that comparable recovery rates of phosphorus were achieved with a single ED step for incineration ashes and a sequential combination of two ED steps for gasification ashes, which was due to a higher influence of iron and/or aluminium in phosphorus solubility for the latter. A product with lower level of metallic impurities and comparable to wet process phosphoric acid was eventually obtained from gasification ashes. Thus, gasification becomes an interesting alternative to incineration also in terms of phosphorus separation.

  1. Characteristics and heavy metal leaching of ash generated from incineration of automobile shredder residue.

    Science.gov (United States)

    Lee, Hwa Young

    2007-08-17

    Bottom and fly ash collected from automobile shredder residue (ASR) incinerator have been characterized in terms of particle size, compositions, and heavy metal leaching by the standard TCLP method. Two alternative methods were also examined for the treatment of heavy metals in ASR incinerator ash from the aspect of recycling into construction or lightweight aggregate material. It was remarkable that the concentration of Cu was very high compared to common MSWI bottom and fly ash, which was probably originated from copper wires contained in ASR. As a whole, the results of characterization of ASR fly ash were in good agreement with common MSWI fly ash in terms of particle size, pH, and water-soluble compounds. It was clearly found that heavy metals could be removed thoroughly or partly from ASR fly ash through acid washing with dilute HCl solution so that the remaining fly ash could be landfilled or used as construction material. It was also found that the amount of heavy metal leachability of lightweight aggregate pellet prepared with ASR incineration ash could be significantly decreased so that the application of it to lightweight aggregate would be possible without pre-treatment for the removal of heavy metals.

  2. LCA of management strategies for RDF incineration and gasification bottom ash based on experimental leaching data.

    Science.gov (United States)

    Di Gianfilippo, Martina; Costa, Giulia; Pantini, Sara; Allegrini, Elisa; Lombardi, Francesco; Astrup, Thomas Fruergaard

    2016-01-01

    The main characteristics and environmental properties of the bottom ash (BA) generated from thermal treatment of waste may vary significantly depending on the type of waste and thermal technology employed. Thus, to ensure that the strategies selected for the management of these residues do not cause adverse environmental impacts, the specific properties of BA, in particular its leaching behavior, should be taken into account. This study focuses on the evaluation of potential environmental impacts associated with two different management options for BA from thermal treatment of Refuse Derived Fuel (RDF): landfilling and recycling as a filler for road sub bases. Two types of thermal treatment were considered: incineration and gasification. Potential environmental impacts were evaluated by life-cycle assessment (LCA) using the EASETECH model. Both non-toxicity related impact categories (i.e. global warming and mineral abiotic resource depletion) and toxic impact categories (i.e. human toxicity and ecotoxicity) were assessed. The system boundaries included BA transport from the incineration/gasification plants to the landfills and road construction sites, leaching of potentially toxic metals from the BA, the avoided extraction, crushing, transport and leaching of virgin raw materials for the road scenarios, and material and energy consumption for the construction of the landfills. To provide a quantitative assessment of the leaching properties of the two types of BA, experimental leaching data were used to estimate the potential release from each of the two types of residues. Specific attention was placed on the sensitivity of leaching properties and the determination of emissions by leaching, including: leaching data selection, material properties and assumptions related to emission modeling. The LCA results showed that for both types of BA, landfilling was associated with the highest environmental impacts in the non-toxicity related categories. For the toxicity

  3. Curbing dioxin emissions from municipal solid waste incineration in China: Re-thinking about management policies and practices

    Energy Technology Data Exchange (ETDEWEB)

    Cheng Hefa, E-mail: hefac@umich.ed [State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640 (China); Hu Yuanan [Education Program for Gifted Youth, Stanford University, Stanford, CA 94025 (United States)

    2010-09-15

    As one of the countries with large amounts of dioxin releases, the control of dioxins is a major challenge for China. Municipal solid waste (MSW) incineration should be considered a high priority source of dioxin emissions because it is playing an increasingly more important role in waste management. MSW incineration in China has much higher emission rates of dioxins than in the developed countries, partially resulting from the gaps in the technologies of incineration and flue gas cleaning. Moreover, the current management policies and practices also contribute significantly to the problem. We recommend lowering dioxin emission standard, strengthening fly ash management, and improving regulation enforcement to reduce dioxin releases into the environment from MSW incineration. We also propose that alternative strategies should be considered on dioxin control and call for an expansion of economic instruments in waste management to reduce waste generation and thus the need for incineration. - The management policies and practices need to be improved to curb the increasing dioxin releases from municipal solid waste incineration in China.

  4. Mercury and toxic metals in ash from combustion and incineration processes; Mercurio y metales toxicos en cenizas provenientes de procesos de combustion e incineracion

    Energy Technology Data Exchange (ETDEWEB)

    Mugica, V.; Amador, M.A.; Torres, M.; Figueroa, J. de J. [Universidad Autonomo-Metropolitana-Azcapotzalco, Reynosa (Mexico)

    2003-07-01

    In Mexico, most of the ashes from combustion and incineration process were not appropriately disposed, they are either left on industrial yards and cliffs or thrown away in open spaces and then carried by the wind to places where they can harm population, affect aquatic environment or soils. For prevention and control, the knowledge on the concentration of trace elements in waste ashes is necessary. In this study, several oxidation methods for digestion of ashes followed by inductively coupled plasma emission spectrometry were evaluated. Hg, Cd, Cr, Cu, Ni, Pb and V were determined in ashes from coal and fuel oil combustion, as well as in ashes from the incineration of municipal, water treatment sludge, and medical wastes. Results showed important concentrations of different trace elements in the ashes. This suggests that adequate disposal of these wastes should be mandatory. On the other hand, concentration of trace elements in the leachates indicated that these wastes are not toxic and they could be disposed in sanitary landfill. 23 refs.

  5. Leaching of Antimony (Sb)from Municipal Solid Waste Incineration (MSWI) Residues

    Energy Technology Data Exchange (ETDEWEB)

    Herrmann, Inga

    2004-07-01

    The mobility of antimony (Sb) in municipal solid waste incineration (MSWI) residues often exceeds the limit values stipulated by the European Union. As an ash treatment by washing is conceivable, this work investigated the Sb release from Swedish bottom ash and fly ash when mixed with water. The leaching experiments revealed the factors significantly (a = 0.05) affecting Sb release from the ashes. The following factors were investigated: Liquid to solid ratio (L/S), time, pH, carbonation (treatment with CO{sub 2}), ultrasonics and temperature. The data were evaluated using multiple linear regression (MLR). The impact of the factors could be quantified. The maximum Sb release calculated was 13 mg/kg DM for bottom ash and 51 mg/kg DM for fly ash. The derived models explained the observed data well. Nevertheless, the calculated values were subject to a high uncertainty. For bottom ash, a lowering of the Sb total content of approximately 22% could be achieved. If this also involves a sufficient lowering of the Sb mobility to meet EU limit values could not yet be assessed. Chemical equilibrium calculations were performed to explain the empirical results. However, no solid phases controlling Sb release from the ashes could be identified.

  6. Sustainable waste management via incineration system: an Islamic ...

    African Journals Online (AJOL)

    This paper would firstly examine solid waste management currently experienced in Malaysia with special concentration given to waste incineration. Its function and benefits entailed from this system shall then be identified. This paper attempts to emphasize this notion within the Islamic perspective, stressing on the needs to ...

  7. Inhalation pathway risk assessment of hazardous waste incineration facilities

    Energy Technology Data Exchange (ETDEWEB)

    Travis, C.C.; Etnier, E.L.; Holton, G.A.; O' Donnell, F.R.; Hetrick, D.M.; Dixon, E.; Harrington, E.S.

    1984-10-01

    The purpose of this assessment was to determine the relative importance of plant design and waste physicochemical variables on human inhalation exposure and health risk resulting from hazardous waste incineration. A hypothetical waste incineration site in the northern Midwest was chosen as the primary site for analysis. This site has a population of 0.45 x 10/sup 6/ persons, with the closest individuals residing 1500 m from the incineration site. Two facility designs (liquid injection and rotary kiln) of three sizes (1, 10, and 150 x 10/sup 6/ Btu/h), each burning three generic wastes, were selected. Three levels of destruction and removal efficiency (DRE) were considered (99.0, 99.9 and 99.99% DRE). The three waste groups selected for study, in order of increasing incinerability were: (1) pesticide-related chemicals (chloroform, ethylene dichloride, hexachlorobutadiene, and 1,1,2,2-tetrachloroethane); (2) API separator sludge chemicals (arsenic, chromium, lead, and phenol) and (3) phenol/acetone distillation chemicals (toluene, pyridine, phthalic anhydride, and methyl styrene). Annual-average ground level air concentrations of representative chemical pollutants were estimated using IEM, an automated inhalation exposure methodology. Air concentrations were estimated for both stack and fugitive emissions using region-specific meteorological and climatological data. Estimates of individual and total population exposure resulting from incineration of hazardous materials were calculated and estimates of risk obtained. 31 references, 36 tables. (ACR)

  8. Behavior of TiO₂ nanoparticles during incineration of solid paint waste: a lab-scale test.

    Science.gov (United States)

    Massari, Andrea; Beggio, Marta; Hreglich, Sandro; Marin, Riccardo; Zuin, Stefano

    2014-10-01

    In order to assess the potential impacts posed by products containing engineered nanoparticles, it is essential to generate more data about the release of these particles from products' life cycle. Although first studies were performed to investigate the release of nanoparticles from use phase, very few data are available on the potential release from recycling or disposal of nano-enhanced products. In this work, we investigated the behavior of TiO2 nanoparticles from incineration of solid paint waste containing these particles. Solid paint debris with and without TiO2 nanoparticles were treated in a lab scale incineration plant at 950°C (combustion temperature) and in oxidizing atmosphere. The obtained ashes were also vitrified with additives and the release of Ti was finally evaluated by leaching test. From our incineration lab-scale experiment, we did not observe a release of TiO2 nanoparticles into the atmosphere, and Ti was attached to the surface of obtained solid residues (i.e. ashes). The characterization of ashes showed that TiO2 nanoparticles reacted during the incineration to give calcium titanate. Finally, a very low release of Ti was measured, less 1 mg/kg, during the leaching test of ashes vitrified with glass cullet and feldspathic inert. Our work suggests that TiO2 nanoparticles added in paints may undergo to physicochemical transformation during the incineration, and that Ti found in ashes may be strongly immobilized in glass matrix. Since this conclusion is based on lab-scale experiment, further research is required to identify which nanoparticles will be emitted to the environment from a real-word-incineration system of household hazardous waste. Copyright © 2014 Elsevier Ltd. All rights reserved.

  9. Pilot-scale incineration of wastes with high content of chlorinated and non-halogenated organophosphorus flame retardants used as alternatives for PBDEs

    Energy Technology Data Exchange (ETDEWEB)

    Matsukami, Hidenori, E-mail: matsukami.hidenori@nies.go.jp [Center for Material Cycles and Waste Management Research, National Institute for Environmental Studies (NIES), 16-2 Onogawa, Tsukuba 305-8506 (Japan); Graduate School of Frontier Sciences, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa 277-8563 (Japan); Kose, Tomohiro [Faculty of Applied Life Sciences, Niigata University of Pharmacy and Applied Life Sciences, 265-1, Higashijima, Akiha-ku, Niigata 956-8603 (Japan); Watanabe, Mafumi [Center for Material Cycles and Waste Management Research, National Institute for Environmental Studies (NIES), 16-2 Onogawa, Tsukuba 305-8506 (Japan); Takigami, Hidetaka [Center for Material Cycles and Waste Management Research, National Institute for Environmental Studies (NIES), 16-2 Onogawa, Tsukuba 305-8506 (Japan); Graduate School of Frontier Sciences, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa 277-8563 (Japan)

    2014-09-15

    Chlorinated and non-halogenated organophosphorus flame retardants (OPFRs) including tris(2-chloroisopropyl) phosphate (TCIPP), diethylene glycol bis(di(2-chloroisopropyl) phosphate) (DEG-BDCIPP), triphenyl phosphate (TPHP), and bisphenol A bis(diphenyl phosphate) (BPA-BDPP) have been used increasingly as alternatives to polybrominated diphenyl ethers and other brominated flame retardants. For this study, five batches of incineration experiments of wastes containing approximately 1% of TCIPP, DEG-BDCIPP, TPHP, and BPA-BDPP were conducted using a pilot-scale incinerator. Destruction and emission behaviors of OPFRs were investigated along with the effects on behaviors of unintentional persistent organic pollutants (POPs) such as polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs), dioxin-like polychlorinated biphenyls (dl-PCBs), hexachlorobenzene (HCB), pentachlorobenzene (PeCB), and pentachlorophenol (PCP). Incineration conditions were chosen according to current regulations for waste incinerators in Japan and UNEP. The OPFRs in the input materials were mainly destroyed in the primary combustion with destruction efficiencies greater than 99.999%. Concentrations of the OPFRs in the exhaust gases and ash were, respectively, < 0.01–0.048 μg m{sup −3} and < 0.5–68 μg kg{sup −1}. Almost all of the total phosphorus in the input materials was partitioned into the ash, but less into final exit gases, indicating negligible emissions of volatile phosphorus compounds during incineration. Inputs of chlorinated OPFRs did not affect the formation markedly. Destruction and emission behaviors of unintentional POPs were investigated. Emissions of such POPs in exhaust gases and the ash were lower than the Japanese and international standards. Results show that even in wastes with high contents of chlorinated and non-halogenated OPFRs, waste incineration by the current regulations for the waste incinerators can control environmental emissions of

  10. Experiences with waste incineration for energy production in Denmark

    DEFF Research Database (Denmark)

    Kirkeby, Janus; Grohnheit, Poul Erik; Møller Andersen, Frits

    The Bioenergy Department in SENER have requested assistance with planning for the deployment of bioenergy (Biomass, biogas and waste incineration) in Mexico and information on Danish experiences with developing policy initiatives promoting bioenergy. This introduction to the Danish experiences wi...... with waste incineration for energy production use is compiled as preparation for SENER’s potential visit to Denmark in 2014. This report was prepared 19 June, 2014 by COWI DTU System Analysis to Danish Energy Agency (DEA) as part of a frame contract agreement.......The Bioenergy Department in SENER have requested assistance with planning for the deployment of bioenergy (Biomass, biogas and waste incineration) in Mexico and information on Danish experiences with developing policy initiatives promoting bioenergy. This introduction to the Danish experiences...

  11. Bacterial Treatment and Metal Characterization of Biomedical Waste Ash

    Directory of Open Access Journals (Sweden)

    Shelly Heera

    2014-01-01

    Full Text Available Biomedical waste ash generated due to the incineration of biomedical waste contains large amounts of heavy metals and polycyclic aromatic hydrocarbons (PAHs, which is disposed of in regular landfills, and results in unfavorable amounts of hazardous materials seeping into the ground and may pollute surface water and groundwater. Therefore, it is essential to remove the toxicity of ash before disposal into landfills or reutilization. Environmental characteristic analysis of BMW ash showed increased hardness (1320 mg/L and chloride (8500 mg/L content in leachate compared to World Health Organization (WHO and Environment Protection Agency (EPA guidelines for drinking water (hardness, 300 mg/L; chloride, 250 mg/L. The alkalinity and pH of the ash leachate were 400 mg/L and 8.35, respectively. In this paper, study was carried out to investigate the metal tolerance level of bacterial isolates isolated from soil. The isolate Bacillus sp. KGMDI can tolerate up to 75 mg/L of metal concentration (Mn, Mo, Cr, Fe, Cu, and Zn in enriched growth medium. This shows that the isolated culture is capable of growing in presence of high concentration of heavy metals and acts as potential biological tool to reduce the negative impact of BMW ash on the environment during landfilling.

  12. Use of jet grouting to create a low permeability horizontal barrier below an incinerator ash landfill

    Energy Technology Data Exchange (ETDEWEB)

    Furth, A.J.; Burke, G.K. [Hayward Baker Inc., Odenton, MD (United States); Deutsch, W.L. Jr. [Roy F. Weston, Inc., West Chester, PA (United States)

    1997-12-31

    The City of Philadelphia`s Division of Aviation (DOA) has begun construction of a new commuter runway, designated as Runway 8-26, at the Philadelphia International Airport. A portion of this runway will be constructed over a former Superfund site known as the Enterprise Avenue Landfill, which for many years was used to dispose of solid waste incinerator ash and other hazardous materials. The site was clay capped in the 1980`s, but in order for the DOA to use the site, additional remediation was needed to meet US EPA final closure requirements. One component of the closure plan included installation of a low permeability horizontal barrier above a very thin (approximately 0.61 to 0.91 meters) natural clay stratum which underlies an approximately 1020 m{sup 2} area of the landfill footprint so as to insure that a minimum 1.52 meter thick low permeability barrier exists beneath the entire 150,000 m{sup 2} landfill. The new barrier was constructed using jet grouting techniques to achieve remote excavation and replacement of the bottom 0.91 meters of the waste mass with a low permeability grout. The grout was formulated to meet the low permeability, low elastic modulus and compressive strength requirements of the project design. This paper will discuss the advantages of using jet grouting for the work and details the development of the grout mixture, modeling of the grout zone under load, field construction techniques, performance monitoring and verification testing.

  13. Leaching from municipal solid waste incineration residues

    Energy Technology Data Exchange (ETDEWEB)

    Hyks, J.

    2008-02-15

    Leaching of pollutants from Municipal Solid Waste Incineration (MSWI) residues has been investigated combining a range of laboratory leaching experiments with geochemical modeling. Special attention was paid to assessing the applicability of laboratory data for subsequent modeling with respect to presumed full-scale conditions; both sample pretreatment and actual influence of leaching conditions on the results of laboratory experiments were considered. It was shown that sample pretreatment may have large impact on leaching test data. In particular, a significant fraction of Pb was shown mobile during the washing of residues with water. In addition, drying of residues (i.e. slow oxidation) prior to leaching experiments increased the leaching of Cr significantly. Significant differences regarding the leaching behavior of individual elements with respect to (non)equilibrium conditions in column percolation experiments were observed in the study. As a result, three groups of elements were identified based on the predominant leaching control and the influence of (non)equilibrium on the results of the laboratory column experiments: I. Predominantly availability-controlled elements (e.g. Na, K, Cl) II. Solubility-controlled elements (e.g. Ca, S, Si, Al, Ba, and Zn) III. Complexation-controlled elements (e.g. Cu and Ni) With respect to the above groups it was suggested that results of laboratory column experiments can, with consideration, be used to estimate full-scale leaching of elements from Group I and II. However, in order to avoid large underestimations in the assessment of leaching from Group III, it is imperative to describe the time-dependent transport of dissolved organic carbon (DOC) in the tested system or to minimize the physical non-equilibrium during laboratory experiments (e.g. bigger column, slower flow velocity). Forward geochemical modeling was applied to simulate long-term release of elements from a MSWI air-pollution-control residue. Leaching of a

  14. Comparison of phosphorus recovery from incineration and gasification sewage sludge ash

    DEFF Research Database (Denmark)

    Parés Viader, Raimon; Jensen, Pernille Erland; Ottosen, Lisbeth M.

    Incineration of sewage sludge is a common practice in many western countries. Gasification is an attractive option because of its high energy efficiency and flexibility in the usage of the produced gas. However, they both unavoidably produce sewage sludge ash (SSA), a material which is rich...... in phosphorus (P), but that it is commonly landfilled or used in construction materials. With current uncertainty in phosphate rock (PR) supply, P recovery from SSA has become interesting. In the present work, ashes from incineration and gasification of the same sewage sludge were compared in terms of P...... extractability using electrodialytic (ED) methods. The results show that comparable recovery rates of P were achieved with a single ED step for incineration SSA and a sequential combination of two ED steps for gasification SSA, which was due to a higher influence of Fe and/or Al in P solubility for the latter...

  15. Comparison of phosphorus recovery from incineration and gasification sewage sludge ash

    DEFF Research Database (Denmark)

    Parés Viader, Raimon; Jensen, Pernille Erland; Ottosen, Lisbeth M.

    2017-01-01

    Incineration of sewage sludge is a common practice in many western countries. Gasification is an attractive option because of its high energy efficiency and flexibility in the usage of the produced gas. However, they both unavoidably produce sewage sludge ash (SSA), a material which is rich...... in phosphorus (P), but that it is commonly landfilled or used in construction materials. With current uncertainty in phosphate rock (PR) supply, P recovery from SSA has become interesting. In the present work, ashes from incineration and gasification of the same sewage sludge were compared in terms of P...... extractability using electrodialytic (ED) methods. The results show that comparable recovery rates of P were achieved with a single ED step for incineration SSA and a sequential combination of two ED steps for gasification SSA, which was due to a higher influence of Fe and/or Al in P solubility for the latter...

  16. Comparison of phosphorus recovery from incineration and gasification sewage sludge ash

    DEFF Research Database (Denmark)

    Parés Viader, Raimon; Jensen, Pernille Erland; Ottosen, Lisbeth M.

    2017-01-01

    Incineration of sewage sludge is a common practice in many western countries. Gasification is an attractive option because of its high energy efficiency and flexibility in the usage of the produced gas. However, they both unavoidably produce sewage sludge ash (SSA), a material which is rich in ph...

  17. Extracting phosphorous from incinerated sewage sludge ash rich in iron or aluminum

    DEFF Research Database (Denmark)

    Ottosen, Lisbeth M.; Kirkelund, Gunvor M.; Jensen, Pernille E.

    2013-01-01

    Ashes from mono-incineration of sewage sludge (ISSA) generally contain high concentrations of phosphorous (P) and can be regarded as secondary P resources. ISSA has no direct value as fertilizer as P is not plant available. The present paper experimentally compares P extraction in acid from two...

  18. Solidification/stabilization of fly ash from city refuse incinerator facility and heavy metal sludge with cement additives.

    Science.gov (United States)

    Cerbo, Atlas Adonis V; Ballesteros, Florencio; Chen, Teng Chien; Lu, Ming-Chun

    2017-01-01

    Solidification and stabilization are well-known technologies used for treating hazardous waste. These technologies that use cementitious binder have been applied for decades as a final treatment procedure prior to the hazardous waste disposal. In the present work, hazardous waste like fly ash containing high concentrations of heavy metals such Zn (4715.56 mg/kg), Pb (1300.56 mg/kg), and Cu (534.72 mg/kg) and amounts of Ag, Cd, Co, Cr, Mn, and Ni was sampled from a city refuse incinerator facility. This fly ash was utilized in the solidification/stabilization of heavy metal sludge since fly ash has cement-like characteristics. Cement additives such as sodium sulfate, sodium carbonate, and ethylenediaminetetraacetic acid (EDTA) was incorporated to the solidified matrix in order to determine its effect on the solidification/stabilization performance. The solidified matrix was cured for 7, 14, 21, and 28 days prior for its physical and chemical characterizations. The results show that the solidified matrix containing 40% fly ash and 60% cement with heavy metal sludge was the formulation that has the highest fly ash content with a satisfactory strength. The solidified matrix was also able to immobilize the heavy metals both found in the fly ash and sludge based on the toxicity characteristic leaching procedure (TCLP) test. It also shows that the incorporation of sodium carbonate into the solidified matrix not only further improved the compressive strength from 0.36 MPa (without Na2CO3) to 0.54 MPa (with Na2CO3) but also increased its leaching resistance.

  19. Clay Improvement with Burned Olive Waste Ash

    Directory of Open Access Journals (Sweden)

    Utkan Mutman

    2013-01-01

    Full Text Available Olive oil is concentrated in the Mediterranean basin countries. Since the olive oil industries are incriminated for a high quantity of pollution, it has become imperative to solve this problem by developing optimized systems for the treatment of olive oil wastes. This study proposes a solution to the problem. Burned olive waste ash is evaluated for using it as clay stabilizer. In a laboratory, bentonite clay is used to improve olive waste ash. Before the laboratory, the olive waste is burned at 550°C in the high temperature oven. The burned olive waste ash was added to bentonite clay with increasing 1% by weight from 1% to 10%. The study consisted of the following tests on samples treated with burned olive waste ash: Atterberg Limits, Standard Proctor Density, and Unconfined Compressive Strength Tests. The test results show promise for this material to be used as stabilizer and to solve many of the problems associated with its accumulation.

  20. Emission of greenhouse gases from waste incineration in Korea.

    Science.gov (United States)

    Hwang, Kum-Lok; Choi, Sang-Min; Kim, Moon-Kyung; Heo, Jong-Bae; Zoh, Kyung-Duk

    2017-07-01

    Greenhouse gas (GHG) emission factors previously reported from various waste incineration plants have shown significant variations according to country-specific, plant-specific, and operational conditions. The purpose of this study is to estimate GHG emissions and emission factors at nine incineration facilities in Korea by measuring the GHG concentrations in the flue gas samples. The selected incineration plants had different operation systems (i.e., stoker, fluidized bed, moving grate, rotary kiln, and kiln & stoker), and different nitrogen oxide (NO x ) removal systems (i.e., selective catalytic reduction (SCR) and selective non-catalytic reduction (SNCR)) to treat municipal solid waste (MSW), commercial solid waste (CSW), and specified waste (SW). The total mean emission factors for A and B facilities for MSW incineration were found to be 134 ± 17 kg CO 2 ton -1 , 88 ± 36 g CH 4 ton -1 , and 69 ± 16 g N 2 O ton -1 , while those for CSW incineration were 22.56 g CH 4 ton -1 and 259.76 g N 2 O ton -1 , and for SW incineration emission factors were 2959 kg CO 2 ton -1 , 43.44 g CH 4 ton -1 and 401.21 g N 2 O ton -1 , respectively. Total emissions calculated using annual incineration for MSW were 3587 ton CO 2 -eq yr -1 for A facility and 11,082 ton CO 2 -eq yr -1 for B facility, while those of IPCC default values were 13,167 ton CO 2- eq yr -1 for A facility and 32,916 ton CO 2- eq yr -1 , indicating that the emissions of IPCC default values were estimated higher than those of the plant-specific emission factors. The emission of CSW for C facility was 1403 ton CO 2 -eq yr -1 , while those of SW for D to I facilities was 28,830 ton CO 2 -eq yr -1 . The sensitivity analysis using a Monte Carlo simulation for GHG emission factors in MSW showed that the GHG concentrations have a greater impact than the incineration amount and flow rate of flue gas. For MSW incineration plants using the same stoker type in operation, the estimated emissions and

  1. Fluorination of incinerator ash by hydrofluorination or ammonium bifluoride fusion for plutonium recovery

    Energy Technology Data Exchange (ETDEWEB)

    Fink, S.D.; Gray, J.H.; Kent, S.J.; Apgar, S.A.

    1989-01-01

    Incinerator ash containing small quantities of plutonium has been accumulating across the defense complex for many years. Although the total Pu inventory is small, the ash is a nondiscardable residue which presents storage and accountability difficulties. The work discussed here is the result of a joint exploratory effort between members of Savannah River Laboratory and Los Alamos National Laboratory to compare two proposed pyrochemical pretreatments of incinerator ash prior to aqueous processing. These experiments attempted to determine the relative effectiveness of hydrofluorination and ammonium bifluoride fusion as head-end operations for a two step aqueous recovery method. The two pretreatments are being considered as possible second generation enhancements for the New Special Recovery Facility nearing operation at Savannah River Plant. Experimental results and potential engineering concerns are discussed. 3 figs.

  2. Stabilization of APC residues from waste incineration with ferrous sulfate on a semi-industrial scale

    DEFF Research Database (Denmark)

    Lundtorp, Kasper; Jensen, Dorthe Lærke; Christensen, Thomas Højlund

    2002-01-01

    A stabilization method for air pollution control (APC) residues from municipal solid waste incineration (MSWI) involving mixing of the residue with water and FeSO4 has been demonstrated on a semi-industrial scale on three types of APC residues: a semidy (SD) APC residue, a fly ash (FA), and an FA...... mixed with sludge (FAS) from a wet flue gas cleaning system. The process was performed in batches of 165-175 kg residue. It generates a wastewater that is highly saline but has a low content of heavy metals such as Cd, Cr, and Pb. The stabilized and raw residues have been subject to a range of leaching...

  3. Possibilities for gas turbine and waste incinerator integration

    NARCIS (Netherlands)

    Korobitsyn, M.A.; Jellema, P.; Hirs, Gerard

    1999-01-01

    The aggressive nature of the flue gases in municipal waste incinerators does not allow the temperature of steam in the boiler to rise above 400°C. An increase in steam temperature can be achieved by external superheating in a heat recovery steam generator positioned behind a gas turbine, so that

  4. Effectiveness of incinerators in the management of medical wastes ...

    African Journals Online (AJOL)

    This study aimed at determining the effectiveness of incinerators in Eldoret municipality in the management of medical wastes in relation to its maintenance and operation with an aim of giving recommendations towards reducing environmental pollution caused by emission of toxic pollutants and safeguarding the health of ...

  5. Mineralogy and pore water chemistry of a boiler ash from a MSW fluidized-bed incinerator.

    Science.gov (United States)

    Bodénan, F; Guyonnet, D; Piantone, P; Blanc, P

    2010-07-01

    This paper presents an investigation of the mineralogy and pore water chemistry of a boiler ash sampled from a municipal solid waste fluidized-bed incinerator, subject to 18 months of dynamic leaching in a large percolation column experiment. A particular focus is on the redox behaviour of Cr(VI) in relation to metal aluminium Al(0), as chromium may represent an environmental or health hazard. The leaching behaviour and interaction between Cr(VI) and Al(0) are interpreted on the basis of mineralogical evolutions observed over the 18-month period and of saturation indices calculated with the geochemical code PhreeqC and reviewed thermodynamic data. Results of mineralogical analyses show in particular the alteration of mineral phases during leaching (e.g. quartz and metal aluminium grains), while geochemical calculations suggest equilibria of percolating fluids with respect to specific mineral phases (e.g. monohydrocalcite and aluminium hydroxide). The combination of leaching data on a large scale and mineralogical analyses document the coupled leaching behaviour of aluminium and chromium, with chromium appearing in the pore fluids in its hexavalent and mobile state once metal aluminium is no longer available for chromium reduction. Copyright (c) 2010 Elsevier Ltd. All rights reserved.

  6. Plant monitoring of air quality around waste incinerators

    Energy Technology Data Exchange (ETDEWEB)

    Tonneijck, A.E.G.; Dijk, C.J. van; Dueck, T.A. [Plant Research International, Wageningen (Niger). Dept. of Crop and Production Ecology

    2002-07-01

    Since the early 1990's, three new waste incineration plants have come into operation in agricultural regions in The Netherlands. Multi-year standardised biomonitoring programmes around these incinerators were set up to determine the absence of adverse effects on quality of crop produce due to the incineration of waste. Depending on time of year, plants of kale (Brassica oleracea) and spinach (Spinacia oleracea) were cultivated for use as accumulators of cadmium (Cd), mercury (Hg) and polycyclic aromatic hydrocarbons (PAHs). Trends in fluoride contents were followed by sampling field-grown pasture grass. Cow milk was sampled to determine the concentrations of dioxins. Plants of gladiola (Gladiolus gandavensis) were used for the assessment of visible injury by ambient fluoride in one programme only. The results of many years of biomonitoring showed that the emissions of the waste incinerators did not affect the quality of crop produce and cow milk. Concentrations of the various components in these products were generally similar to background levels and did not exceed standards for maximum allowable concentrations. On one occasion, concentrations of PAHs in spinach were clearly enhanced due to the use of wood-preserving compounds at a barn close to the monitoring site. This incident reveals that our biomonitoring projects are an appropriate tool to detect changes in air quality. (orig.)

  7. Controlled air incinerator conceptual design study

    Energy Technology Data Exchange (ETDEWEB)

    1982-01-01

    This report presents a conceptual design study for a controlled air incinerator facility for incineration of low level combustible waste at Three Mile Island Unit 2 (TMI-2). The facility design is based on the use of a Helix Process Systems controlled air incinerator. Cost estimates and associated engineering, procurement, and construction schedules are also provided. The cost estimates and schedules are presented for two incinerator facility designs, one with provisions for waste ash solidification, the other with provisions for packaging the waste ash for transport to an undefined location.

  8. Partitioning characteristics and particle size distributions of heavy metals in the O{sub 2}/RFG waste incineration system

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Jyh-Cherng, E-mail: jcchen@sunrise.hk.edu.tw [Department of Safety, Health and Environmental Engineering, HungKuang University, No. 34, Chung-Chie Rd., Shalu, Taichung County 43302, Taiwan (China); Huang, Jian-Sheng [Department of Safety, Health and Environmental Engineering, HungKuang University, No. 34, Chung-Chie Rd., Shalu, Taichung County 43302, Taiwan (China)

    2009-12-30

    This study applies the oxygen/recycled flue gas (O{sub 2}/RFG) combustion technology for waste incineration and investigates the effects of different RFG rates on the concentrations of gas pollutants as well as the partitioning characteristics and particle size distributions of five heavy metals (Cr, Cu, Pb, Zn, and Cd). Experimental results show that the combustion efficiency can be improved and the concentration of CO{sub 2} is increased by appropriately controlling the RFG rate in the O{sub 2}/RFG incineration system. The partitioning characteristics and size distributions of heavy metals in O{sub 2}/RFG combustion system are different from those in general air combustion system. Under O{sub 2}/RFG combustion system, the partitioning percentages of heavy metals in sand bed, bottom ash, and collected ash are increased. The particle size distributions of heavy metals display the triple-peak curves. As the RFG rate rises, the concentrations of volatile heavy metals are increased in small-size (<1 {mu}m) fly ash, decreased in medium-size (1-10 {mu}m) fly ash and increased in large-size (>10 {mu}m) fly ash. These phenomena will benefit to increase the overall control efficiency of heavy metals in the incineration system.

  9. The domestic wastes incinerators; Les incinerateurs d'ordures menegares: quels risques? quelles politiques?

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2004-10-01

    This document presents the opinion of the Committee of Prevention and Precaution (CPP), on the domestic wastes incinerators, in the framework of the global wastes policy. The seven chapters detail and bring advices on the following topics: the elements which are going in and out of the incinerators, the technical processes, the occupational activities and the risks bound to the incinerators use, the transfer modes towards the different environmental areas, the exposure estimation, the risks of people living near the domestic wastes incinerators compared to the other concerning a cancer development, the legislation concerning the domestic wastes and the social acceptability of the incinerators. (A.L.B.)

  10. Development of thermal conditioning technology for Alpha-containment wastes: Alpha-contaminated waste incineration technology

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Joon Hyung; Kim, Jeong Guk; Yang, Hee Chul; Choi, Byung Seon; Jeong, Myeong Soo

    1999-03-01

    As the first step of a 3-year project named 'development of alpha-contaminated waste incineration technology', the basic information and data were reviewed, while focusing on establishment of R and D direction to develop the final goal, self-supporting treatment of {alpha}- wastes that would be generated from domestic nuclear industries. The status on {alpha} waste incineration technology of advanced states was reviewed. A conceptual design for {alpha} waste incineration process was suggested. Besides, removal characteristics of volatile metals and radionuclides in a low-temperature dry off-gas system were investigated. Radiation dose assessments and some modification for the Demonstration-scale Incineration Plant (DSIP) at Korea Atomic Energy Research Institute (KAERI) were also done.

  11. Investigation of heavy metal partitioning influenced by flue gas moisture and chlorine content during waste incineration.

    Science.gov (United States)

    Li, Qinghai; Meng, Aihong; Jia, Jinyan; Zhang, Yanguo

    2010-01-01

    The impact of moisture on the partitioning of the heavy metals including Pb, Zn, Cu and Cd in municipal solid waste (MSW) was studied in a laboratory tubular furnace. A thermodynamic investigation using CHEMKIN software was performed to compare the experimental results. Simulated waste, representative of typical MSW with and without chlorine compounds, was burned at the background temperature of 700 and 950 degrees C, respectively. In the absence of chlorine, the moisture content has no evident effect on the volatility of Pb, Zn and Cu at either 700 or 950 degrees C, however, as flue gas moisture increasing the Cd distribution in the bottom ash increased at 700 degrees C and reduced at 950 degrees C, respectively. In the presence of chlorine, the flue gas moisture reduced the volatility of Pb, Zn and Cu due to the transformation of the more volatile metal chlorides into less volatile metal oxides, and the reduction became significant as chlorine content increase. For Cd, the chlorine promotes its volatility through the formation of more volatile CdCl2. As a result, the increased moisture content increases the Pb, Zn, Cu and Cd concentrations in the bottom ash, which limits the utilization of the bottom ash as a construction material. Therefore, in order to accumulate heavy metals into the fly ash, MSW should be dried before incineration.

  12. Residues from waste incineration. Final report. Rev. ed.

    Energy Technology Data Exchange (ETDEWEB)

    Astrup, T.; Juul Pedersen, A.; Hyks, J.; Frandsen, F.J.

    2010-04-15

    The overall objective of the project was to improve the understanding of the formation and characteristics of residues from waste incineration. This was done focusing on the importance of the waste input and the operational conditions of the furnace. Data and results obtained from the project have been discussed in this report according to the following three overall parts: i) mass flows and element distribution, ii) flue gas/particle partitioning and corrosion/deposition aspects, and iii) residue leaching. This has been done with the intent of structuring the discussion while tacitly acknowledging that these aspects are interrelated and cannot be separated. Overall, it was found that the waste input composition had significant impact of the characteristics of the generated residues. A similar correlation between operational conditions and residue characteristics could not be observed. Consequently, the project recommend that optimization of residue quality should focus on controlling the waste input composition. The project results showed that including specific waste materials (and thereby also excluding the same materials) may have significant effects on the residue composition, residue leaching, aerosol and deposit formation.It is specifically recommended to minimize Cl in the input waste. Based on the project results, it was found that a significant potential for optimization of waste incineration exist. (Author)

  13. Paper waste - Recycling, incineration or landfilling?

    DEFF Research Database (Denmark)

    Villanueva, Alejandro; Wenzel, Henrik

    2007-01-01

    A review of existing life cycle assessments (LCAs) on paper and cardboard waste has been undertaken. The objectives of the review were threefold. Firstly, to see whether a consistent message comes out of published LCA literature on optimum disposal or recycling solutions for this waste type. Such...

  14. Activated carbon treatment of municipal solid waste incineration flue gas.

    Science.gov (United States)

    Lu, Shengyong; Ji, Ya; Buekens, Alfons; Ma, Zengyi; Jin, Yuqi; Li, Xiaodong; Yan, Jianhua

    2013-02-01

    Activated carbon injection is widely used to control dioxins and mercury emissions. Surprisingly little attention has been paid to its modelling. This paper proposes an expansion of the classical Everaerts-Baeyens model, introducing the expression of fraction of free adsorption sites, f (s), and asserting the significant contribution of fly ash to dioxins removal. Moreover, the model monitors dioxins partitioning between vapour and particulate phase, as well as removal efficiency for each congener separately. The effects of the principal parameters affecting adsorption are analysed according to a semi-analytical, semi-empirical model. These parameters include temperature, contact time during entrained-flow, characteristics (grain-size, pore structure, specific surface area) and dosage of activated carbon, lignite cokes or mineral adsorbent, fly ash characteristics and concentration, and type of incinerator plant.

  15. Chemical and physical properties of cyclone fly ash from the grate-fired boiler incinerating forest residues at a small municipal district heating plant (6MW).

    Science.gov (United States)

    Pöykiö, R; Rönkkömäki, H; Nurmesniemi, H; Perämäki, P; Popov, K; Välimäki, I; Tuomi, T

    2009-03-15

    In Finland, the new limit values for maximal allowable heavy metal concentrations for materials used as an earth construction agent came into force in July 2006. These limit values are applied if ash is utilized, e.g. in roads, cycling paths, pavements, car parks, sport fields, etc. In this study we have determined the most important chemical and physical properties of the cyclone fly ash originating from the grate-fired boiler incinerating forest residues (i.e. wood chips, sawdust and bark) at a small municipal district heating plant (6 MW), Northern Finland. This study clearly shows that elements are enriched in cyclone fly ash, since the total element concentrations in the cyclone fly ash were within 0.2-10 times higher than those in the bottom ash. The total concentrations of Cd (25 mg kg(-1); d.w.), Zn (3630 mg kg(-1); d.w.), Ba (4260 mg kg(-1); d.w.) and Hg (1.7 mg kg(-1); d.w.) exceeded the limit values, and therefore the cyclone fly ash cannot be used as an earth construction agent. According to the leached amounts of Cr (38 mg kg(-1); d.w.), Zn (51 mg kg(-1); d.w.) and sulphate (50,000 mg kg(-1); d.w.), the cyclone fly ash is classified as a hazardous waste, and it has to be deposited in a hazardous waste landfill.

  16. The Louisiana State University waste-to-energy incinerator

    Science.gov (United States)

    1994-10-01

    This proposed action is for cost-shared construction of an incinerator/steam-generation facility at Louisiana State University under the State Energy Conservation Program (SECP). The SECP, created by the Energy Policy and Conservation Act, calls upon DOE to encourage energy conservation, renewable energy, and energy efficiency by providing Federal technical and financial assistance in developing and implementing comprehensive state energy conservation plans and projects. Currently, LSU runs a campus-wide recycling program in order to reduce the quantity of solid waste requiring disposal. This program has removed recyclable paper from the waste stream; however, a considerable quantity of other non-recyclable combustible wastes are produced on campus. Until recently, these wastes were disposed of in the Devil's Swamp landfill (also known as the East Baton Rouge Parish landfill). When this facility reached its capacity, a new landfill was opened a short distance away, and this new site is now used for disposal of the University's non-recyclable wastes. While this new landfill has enough capacity to last for at least 20 years (from 1994), the University has identified the need for a more efficient and effective manner of waste disposal than landfilling. The University also has non-renderable biological and potentially infectious waste materials from the School of Veterinary Medicine and the Student Health Center, primarily the former, whose wastes include animal carcasses and bedding materials. Renderable animal wastes from the School of Veterinary Medicine are sent to a rendering plant. Non-renderable, non-infectious animal wastes currently are disposed of in an existing on-campus incinerator near the School of Veterinary Medicine building.

  17. GIS analysis in the siting of incinerators as a panacea for solid waste ...

    African Journals Online (AJOL)

    Solid waste represents a key issue that threatens environmental quality in Kaduna metropolis. One of the most viable options to treat such an issue is to incinerate the collected solid waste, which can reduce the cost of solid waste disposal as well as pollution and generate electricity. Despite the significance of incineration, ...

  18. Accelerated carbonation of different size fractions of bottom ash from RDF incineration.

    Science.gov (United States)

    Baciocchi, R; Costa, G; Lategano, E; Marini, C; Polettini, A; Pomi, R; Postorino, P; Rocca, S

    2010-07-01

    This paper investigates the effects of accelerated carbonation on the characteristics of bottom ash from refuse derived fuel (RDF) incineration, in terms of CO(2) uptake, heavy metal leaching and mineralogy of different particle size fractions. Accelerated aqueous carbonation batch experiments were performed to assess the influence of operating parameters (temperature, CO(2) pressure and L/S ratio) on reaction kinetics. Pressure was found to be the most relevant parameter affecting the carbonation yield. This was also found to be largely dependent on the specific BA fraction treated, with CO(2) uptakes ranging from approximately 4% for the coarse fractions to approximately 14% for the finest one. Carbonation affected both the mineralogical characteristics of bottom ash, with the appearance of neo-formation minerals, and the leaching behaviour of the material, which was found to be mainly related to the change upon carbonation in the natural pH of the ash. Copyright (c) 2009 Elsevier Ltd. All rights reserved.

  19. Caracterização inorgânica de cinza volante de uma estação de incineração de resíduos sólidos urbanos com vista à sua eventual reciclagem Inorganic characterization of fly ash from municipal solid waste incinerator aiming their recycling

    Directory of Open Access Journals (Sweden)

    A. Varela

    2009-01-01

    Full Text Available As cinzas volantes de estações de incineração de resíduos sólidos urbanos (EIRSU são consideradas resíduos perigosos. De forma a reduzir o seu impacto ambiental, estas cinzas são normalmente submetidas a estabilização (inertização por adição de cimento antes de um destino final adequado (deposição em aterro sanitário. Tal traduz-se por um aumento do volume das cinzas, gasto de matériasprimas e área de aterro, não sendo garantida a sua inocuidade a longo prazo. As cinzas constituem um problema de gestão de resíduos, tanto mais que a sua produção tem tendência a crescer, tornando-se premente estudar vias alternativas de tratamento que visem a posterior reciclagem/reutilização, baseadas num desenvolvimento sustentado e sem esquecer o princípio da precaução. O processo electrodialítico (PE parece ser, no caso destes resíduos, uma técnica de remediação promissora. Este processo baseia-se na aplicação de uma corrente contínua, de baixa intensidade, à matriz contaminada. O campo eléctrico gerado funciona como “agente de limpeza”, efectuando-se a remoção dos contaminantes da matriz, pela acção combinada do movimento electrocinético, com o princípio da electrodiálise. Os contaminantes s��o mobilizados para um dos compartimentos dos eléctrodos/electrólitos, dos quais poderão posteriormente ser removidos. Está em curso o Projecto POCTI/AGG/45073/2002, que tem como objectivo estudar a aplicação do PE na remoção de contaminantes de cinzas volantes de EIRSU, para uma possível reciclagem da cinza tratada (correctivo de solos ácidos, incorporação em materiais de construção ou outras, e ainda, a recuperação dos metais pesados, para posterior reutilização. No presente trabalho apresenta-se a caracterização inorgânica de uma cinza volante de EIRSU.Fly ashes from municipal solid waste incinerators (MSWI are considered hazardous waste. In Portugal, they are expected to increase over time

  20. Environmental impacts and resource losses of incinerating misplaced household special wastes (WEEE, batteries, ink cartridges and cables)

    DEFF Research Database (Denmark)

    Bigum, Marianne Kristine Kjærgaard; Damgaard, Anders; Scheutz, Charlotte

    2017-01-01

    to quantify the impact of abiotic resources not recovered from incineration residues. This appeared to be a significant impact category, and the special waste contributed about 96% of this category although it by weight makes up only 0.5% of the waste. Furthermore, enhancing the recovery of iron (Fe......) and aluminum (Al) from the ashes would not affect the loss of abiotic resources significantly. Only by recovering elements as platinum (Pt), copper (Cu), gold (Au), and silver (Ag) would it be possible to reduce the loss of abiotic resources from the system. These elements are primarily found in misplaced...

  1. Controlled combustion tests and bottom ash analysis using household waste with varying composition.

    Science.gov (United States)

    Hu, Yanjun; Bakker, Maarten; Brem, Gerrit; Chen, Guanyi

    2011-02-01

    The influence of the co-combustion of household waste with either sewage sludge, shredder fluff, electronic and electrical waste (WEEE) or PVC on the bottom ash quality and content was investigated under controlled laboratory conditions using a pot furnace. This laboratory approach avoids the interpretation problems related to large variations in input waste composition and combustion conditions that are observed in large scale MSW incinerators. The data for metals content, transfer coefficients and leaching values are presented relative to data for a base household waste composition that did not contain any of the added special wastes. The small WEEE invited direct measurement of precious metals content in the ashes, where measurement accuracy is facilitated by using only mobile phone scrap for small WEEE. The analyses were carried out for different particle size ranges that are of relevance to the recyclability of metals and minerals in the ashes. Positive correlations were found between elements content of the input waste and the bottom ashes, and also between increased levels of Cl, Mo and Cu in the input waste and their leaching in the bottom ashes. These correlations indicate that addition of PVC, small WEEE and shredder fluff in input waste can have a negative influence on the quality of the bottom ashes. Enrichment of Au and Ag occurred in the fractions between 0.15 and 6 mm. The precious metals content represents an economically interesting intrinsic value, even when the observed peak values are properly averaged over a larger volume of ashes. Overall, it has been shown that changes in quality and content of bottom ashes may be traced back to the varied input waste composition. Copyright © 2010 Elsevier Ltd. All rights reserved.

  2. Assessing the leaching of hazardous metals from pharmaceutical wastes and their ashes.

    Science.gov (United States)

    Gerassimidou, Spyridoula; Komilis, Dimitrios

    2015-02-01

    The purpose of this research was the determination of the leaching potential of eight hazardous metals from expired pharmaceutical wastes and their ashes obtained after simulated incineration. A standardized leaching test (EN 14429) was used to assess leaching over a range of pH and comparison with the limits included in Decision 2003/33/EC was done at liquid/solid ratio 10. The goal was to assess the environmental impacts of pharmaceutical wastes after different disposal techniques (direct landfilling, incineration). A 3-year old composite sample of expired pharmaceutical wastes (drugs) was obtained and was separated into solid and liquid drugs. The packaging from each type of drug was also removed and tested separately, whilst the solid drugs and their packaging were incinerated at 900°C. Leaching tests on all solid substrates (solid drugs, packaging, ashed drugs, ashed packaging) were performed over a wide range of pH. The experiments showed that ashed drugs leached the highest amounts of all metals, except iron, and should be disposed of to a hazardous waste landfill, since Cd, Ni, and Pb exceeded the corresponding limits. Raw expired drugs, raw and ashed packaging did not exceed the pertinent limit values and could be, thus, disposed of directly to a non-hazardous waste landfill. In all experiments, the highest leaching potential (>90% of the total metal content) was measured at acidic pHs (<4). The leachable concentration of all metals increased as pH decreased, whilst Zn observed a small re-dissolution in the alkaline range. © The Author(s) 2015.

  3. Selective mobilization of critical elements in incineration ashes; Selektiv mobilisering av kritiska element hos energiaskor

    Energy Technology Data Exchange (ETDEWEB)

    Svensson, Malin; Herrmann, Inga; Ecke, Holger [Luleaa Univ. of Technology (Sweden); Sjoeblom, Rolf [TEKEDO AB, Nykoeping (Sweden)

    2005-05-01

    In the project SMAK, the selective mobilization of critical elements in ashes was studied. Non-hazardous bottom ash from Daava kraftvaermeverk, Umeaa, and hazardous fly ash from Hoegdalenverket, Stockholm, line P6 were investigated. Sb, Mo, Cu, Cr and Cl{sup -} were identified as critical elements in the bottom ash since these elements exceeded the limit values for acceptance on landfills as inert waste according to the Council decision on acceptance criteria at landfills. Critical elements in the fly ash were Cr, Se, Pb and Cl{sup -}, these elements exceeded the limit values for acceptance on landfills as non-hazardous waste. The mobilization of the critical elements was studied in experiments performed according to a reduced 2{sup 6-1} factorial design with three centerpoints. Factors in the experiments were ultrasonic pre-treatment, pre-treatment with carbonation, L/S-ratio, pH, time and temperature. Empirical models of the mobilization were used to identify the optimal factor setting ensuring sufficient mobilization of critical elements, i.e. to achieve a solid residue meeting non-hazardous and inert landfill criteria for fly ash and bottom ash, respectively. No ultrasonic treatment, pre-treatment with carbonation, L/Sratio 5, pH 12, time 2h and temperature at 20 deg C were identified as optimal factor setting for the bottom ash. For the fly ash, no ultrasonic treatment, no pre-treatment with carbonation, L/S-ratio 5, pH 7, time 2h and temperature at 20 deg C were identified as optimal factor setting. The treatment with optimal factor settings did not change the classification according to the Council decision on acceptance criteria at landfills of neither ash. For the bottom ash, Sb, Mo and Cr exceeded the limit values for landfilling as inert waste according to the Council decision on acceptance criteria at landfills. Only Cr exceeded the limit value for landfilling the fly ash as non-hazardous waste. According to the Waste Decree (Avfallsfoerordningen) both

  4. Polycyclic aromatic hydrocarbons in municipal waste ashes from ...

    African Journals Online (AJOL)

    The levels of isolated polycyclic aromatic hydrocarbons (PAH) in ash residues of wastes from some major waste dumps in Lagos, Nigeria, were determined. The total amounts of the PAH in the ashes were in the range of 0.06 – 0.4 mg/g. The ash from the waste dump that contains the highest level also displayed greatest ...

  5. Environmental impacts of residual Municipal Solid Waste incineration: A comparison of 110 French incinerators using a life cycle approach

    Energy Technology Data Exchange (ETDEWEB)

    Beylot, Antoine, E-mail: a.beylot@brgm.fr; Villeneuve, Jacques

    2013-12-15

    Highlights: • 110 French incinerators are compared with LCA based on plant-specific data. • Environmental impacts vary as a function of plants energy recovery and NO{sub x} emissions. • E.g. climate change impact ranges from −58 to 408 kg CO{sub 2}-eq/tonne of residual MSW. • Implications for LCA of waste management in a decision-making process are detailed. - Abstract: Incineration is the main option for residual Municipal Solid Waste treatment in France. This study compares the environmental performances of 110 French incinerators (i.e. 85% of the total number of plants currently in activity in France) in a Life Cycle Assessment perspective, considering 5 non-toxic impact categories: climate change, photochemical oxidant formation, particulate matter formation, terrestrial acidification and marine eutrophication. Mean, median and lower/upper impact potentials are determined considering the incineration of 1 tonne of French residual Municipal Solid Waste. The results highlight the relatively large variability of the impact potentials as a function of the plant technical performances. In particular, the climate change impact potential of the incineration of 1 tonne of waste ranges from a benefit of −58 kg CO{sub 2}-eq to a relatively large burden of 408 kg CO{sub 2}-eq, with 294 kg CO{sub 2}-eq as the average impact. Two main plant-specific parameters drive the impact potentials regarding the 5 non-toxic impact categories under study: the energy recovery and delivery rate and the NO{sub x} process-specific emissions. The variability of the impact potentials as a function of incinerator characteristics therefore calls for the use of site-specific data when required by the LCA goal and scope definition phase, in particular when the study focuses on a specific incinerator or on a local waste management plan, and when these data are available.

  6. An LCA model for waste incineration enhanced with new technologies for metal recovery and application to the case of Switzerland.

    Science.gov (United States)

    Boesch, Michael E; Vadenbo, Carl; Saner, Dominik; Huter, Christoph; Hellweg, Stefanie

    2014-02-01

    A process model of municipal solid waste incinerators (MSWIs) and new technologies for metal recovery from combustion residues was developed. The environmental impact is modeled as a function of waste composition as well as waste treatment and material recovery technologies. The model includes combustion with a grate incinerator, several flue gas treatment technologies, electricity and steam production from waste heat recovery, metal recovery from slag and fly ash, and landfilling of residues and can be tailored to specific plants and sites (software tools can be downloaded free of charge). Application of the model to Switzerland shows that the treatment of one tonne of municipal solid waste results on average in 425 kg CO2-eq. generated in the incineration process, and 54 kg CO2-eq. accrue in upstream processes such as waste transport and the production of operating materials. Downstream processes, i.e. residue disposal, generates 5 kg CO2-eq. Savings from energy recovery are in the range of 67 to 752 kg CO2-eq. depending on the assumptions regarding the substituted energy production, while the recovery of metals from slag and fly ash currently results in a net saving of approximately 35 kg CO2-eq. A similar impact pattern is observed when assessing the MSWI model for aggregated environmental impacts (ReCiPe) and for non-renewable resource consumption (cumulative exergy demand), except that direct emissions have less and no relevance, respectively, on the total score. The study illustrates that MSWI plants can be an important element of industrial ecology as they provide waste disposal services and can help to close material and energetic cycles. Copyright © 2013 Elsevier Ltd. All rights reserved.

  7. Dioxin-like PCBs released from waste incineration and their deposition flux.

    Science.gov (United States)

    Akai, S; Hayakawa, K; Takatsuki, H; Kawakami, I

    2001-09-15

    To investigate the formation and decomposition behaviors of dioxin-like PCBs during incineration of municipal solid wastes in a recently constructed facility, the concentrations of dioxin-like PCBs were measured in municipal solid waste before incineration and in the incinerator emission gas and residues. Using these values, release/inflow ratios of dioxin-like PCB congeners (ratio of the amount released from the incinerator to the amount flowing into the incinerator through waste) were calculated. For PCB congeners 126, 169, and 189, these ratios were greater than 1. In contrast, ratios of the other dioxin-like congeners were much less than 1. To take into account atmospheric sources, the amounts of dioxin-like PCBs released via emissions from municipal solid waste incineration were compared with atmospheric depositions in the Kyoto City area. Most of the PCDD/F congeners and homologue groups were deposited in amounts similar to those found in emissions from the waste incinerator. Deposition of dioxin-like PCB congeners 81, 126, 169, and 189 were also found in amounts similar to those released via the waste incinerator emissions. However, depositions of congeners 105, 114, and 118 greatly exceeded the amounts released via waste incinerator emissions. In reviewing the congener profiles of industrial PCB products and emission gas, the following general trends were observed: (i) For congeners whose contents are high in industrial PCB products (e.g., 105 and 118), the amounts deposited were much higher than the amounts released with waste incineration emission gas. (ii) For congeners whose percentages were high in the waste incineration emission gas (e.g., 126 and 189), the amounts deposited were similar to the amounts released in the waste emission gas.

  8. Characterization of deposits and their influence on corrosion in waste incineration plants in Denmark

    DEFF Research Database (Denmark)

    Montgomery, Melanie; Larsen, OH

    2001-01-01

    A program has been initiated in Denmark to investigate the aggressive environment in various waste incineration plants. The results described are the preliminary results from one waste incineration plant. Deposits and corrosion products have been removed from various locations in the boiler...

  9. Long term plant biomonitoring in the vicinity of waste incinerators in The Netherlands

    NARCIS (Netherlands)

    Dijk, van C.J.; Doorn, van W.; Alfen, van A.J.

    2015-01-01

    Since the mid-nineties new waste incineration plants have come into operation in the Netherlands. Burning of waste can result in the emission of potentially toxic compounds. Although the incineration plants must comply with strict conditions concerning emission control, public concern on the

  10. Monetising the impacts of waste incinerators sited on brownfield land using the hedonic pricing method.

    Science.gov (United States)

    Rivas Casado, Monica; Serafini, Jan; Glen, John; Angus, Andrew

    2017-03-01

    In England and Wales planning regulations require local governments to treat waste near its source. This policy principle alongside regional self-sufficiency and the logistical advantages of minimising distances for waste treatment mean that energy from waste incinerators have been built close to, or even within urban conurbations. There is a clear policy and research need to balance the benefits of energy production from waste incinerators against the negative externalities experienced by local residents. However, the monetary costs of nuisance emissions from incinerators are not immediately apparent. This study uses the Hedonic Pricing Method to estimate the monetary value of impacts associated with three incinerators in England. Once operational, the impact of the incinerators on local house prices ranged from approximately 0.4% to 1.3% of the mean house price for the respective areas. Each of the incinerators studied had been sited on previously industrialised land to minimise overall impact. To an extent this was achieved and results support the effectiveness of spatial planning strategies to reduce the impact on residents. However, negative impacts occurred in areas further afield from the incinerator, suggesting that more can be done to minimise the impacts of incinerators. The results also suggest that in some case the incinerator increased the value of houses within a specified distance of incinerators under specific circumstances, which requires further investigation. Copyright © 2016 Elsevier Ltd. All rights reserved.

  11. Energy potential of municipal solid waste incineration in urban areas of China.

    NARCIS (Netherlands)

    Zheng, Ling

    2006-01-01

    This study aims to evaluate the energy potential of municipal solid waste (MSW) incineration in Chinese cities from 1996 to 2020. In China, with improving the standard of living recently, the extreme increase of the municipal solid waste generation (MSWG)

  12. Beyond waste: new sustainable fillers from fly ashes stabilization, obtained by low cost raw materials

    Directory of Open Access Journals (Sweden)

    N. Rodella

    2016-09-01

    Full Text Available A sustainable economy can be achieved only by assessing processes finalized to optimize the use of resources. Waste can be a relevant source of energy thanks to energy-from-waste processes. Concerns regarding the toxic fly ashes can be solved by transforming them into resource as recycled materials. The commitment to recycle is driven by the need to conserve natural resources, reduce imports of raw materials, save landfill space and reduce pollution. A new method to stabilize fly ash from Municipal Solid Waste Incinerator (MSWI at room temperature has been developed thanks to COSMOS-RICE LIFE+ project (www.cosmos-rice.csmt.eu. This process is based on a chemical reaction that occurs properly mixing three waste fly ashes with rice husk ash, an agricultural by-product. COSMOS inert can replace critical raw materials (i.e. silica, fluorspar, clays, bentonite, antimony and alumina as filler. Moreover the materials employed in the stabilization procedure may be not available in all areas. This paper investigates the possibility of substituting silica fume with corresponding condensed silica fume and to substitute flue-gas desulfurization (FGD residues with low-cost calcium hydroxide powder. The removal of coal fly ash was also considered. The results will be presented and a possible substitution of the materials to stabilize fly ash will be discussed.

  13. Reuse of cement-solidified municipal incinerator fly ash in cement mortars: physico-mechanical and leaching characteristics.

    Science.gov (United States)

    Cinquepalmi, Maria Anna; Mangialardi, Teresa; Panei, Liliana; Paolini, Antonio Evangelista; Piga, Luigi

    2008-03-01

    The reuse of cement-solidified Municipal Solid Waste Incinerator (MSWI) fly ash (solidified/stabilised (S/S) product) as an artificial aggregate in Portland cement mortars was investigated. The S/S product consisted of a mixture of 48 wt.% washed MSWI fly ash, 20 wt.% Portland cement and 32 wt.% water, aged for 365 days at 20 degrees C and 100% RH. Cement mortars (water/cement weight ratio=0.62) were made with Portland cement, S/S product and natural sand at three replacement levels of sand with S/S product (0%, 10% and 50% by mass). After 28 days of curing at 20 degrees C and 100% RH, the mortar specimens were characterised for their physico-mechanical (porosity, compressive strength) and leaching behaviour. No retardation in strength development, relatively high compressive strengths (up to 36 N/mm2) and low leaching rates of heavy metals (Cr, Cu, Pb and Zn) were always recorded. The leaching data from sequential leach tests on monolithic specimens were successfully elaborated with a pseudo-diffusional model including a chemical retardation factor related to the partial dissolution of contaminant.

  14. Municipal Waste Incinerator Public Works Center, Yokosuka Japan Evaluation and Recommendations

    Science.gov (United States)

    1993-04-01

    Combustible Material Not Requiring Processing 18 C. Wood Shredder 18 £ D. Refuse Mixing and Charging 19 Ill. The Municipal Waste Incinerator 19 A...Description of the Municipal Waste Incinerator 19 * B. Combustion Gases Treatment and Monitoring 22 1. Exhaust Gas Cooling Chamber 22 U I I Page 3 2...Emission Charts 3 Appendix C Refuse Residence Time Calculations Appendix D Sorted Analysis of the Municipal Waste Appendix E Model of Municipal Waste

  15. Assessment of incineration and melting treatment technologies for RWMC buried waste

    Energy Technology Data Exchange (ETDEWEB)

    Geimer, R.; Hertzler, T.; Gillins, R. (Science Applications International Corp., Idaho Falls, ID (United States)); Anderson, G.L. (EG and G Idaho, Inc., Idaho Falls, ID (United States))

    1992-02-01

    This report provides an identification, description, and ranking evaluation of the available thermal treatment technologies potentially capable of treating the Idaho National Engineering Laboratory Radioactive Waste Management Complex (RWMC) buried mixed waste. The ranking evaluation focused separately upon incinerators for treatment of combustible wastes and melters for noncombustible wastes. The highest rank incinerators are rotary kilns and controlled air furnaces, while the highest rank melters are the hearth configuration plasma torch, graphite electrode arc, and joule-heated melters. 4 refs.

  16. Design of municipal solid waste incinerator for use in semi-arid regions

    Directory of Open Access Journals (Sweden)

    M. B. Oumarou

    2012-08-01

    Full Text Available The paper treats the design of a municipal solid waste incinerator suited to the semiarid regions with northern Nigeria and Niger Republic in West Africa as the study area. Proximate and ultimate analyses results from the solid waste were used as basis for calculations, using standard formulas and correlations. The calorific value of the solid waste samples in the study area is not high enough to sustain an incineration process and it ranges from 5.024 MJ/kg to 5.867 MJ/kg. For these types of low calorific value fuels, the parallel flow concept was found to be the appropriate type of incinerator. The solid waste to be fed in the incinerator needs to be mixed with 50% of supplementary fuel in the form of readily available bagasse to make it up to the required lower calorific value. Major characteristics of the designed municipal solid waste incinerator were: total volume of incinerator chamber: 82.5 m3, length of the incinerator bed: 11m; width of the incinerator bed: 3m and height of the incinerator chamber: 2.5 m, while the suitable adiabatic flame temperature was found to be 1,587 K.

  17. Sewage sludge ash (SSA) from large and small incineration plants as a potential source of phosphorus - Polish case study.

    Science.gov (United States)

    Smol, Marzena; Kulczycka, Joanna; Kowalski, Zygmunt

    2016-12-15

    The aim of this research is to present the possibility of using the sewage sludge ash (SSA) generated in incineration plants as a secondary source of phosphorus (P). The importance of issues related to P recovery from waste materials results from European Union (UE) legislation, which indicated phosphorus as a critical raw material (CRM). Due to the risks of a shortage of supply and its impact on the economy, which is greater than other raw materials, the proper management of phosphorus resources is required in order to achieve global P security. Based on available databases and literature, an analysis of the potential use of SSA for P-recovery in Poland was conducted. Currently, approx. 43,000 Mg/year of SSA is produced in large and small incineration plants and according to in the Polish National Waste Management Plan 2014 (NWMP) further steady growth is predicted. This indicates a great potential to recycle phosphorus from SSA and to reintroduce it again into the value chain as a component of fertilisers which can be applied directly on fields. The amount of SSA generated in installations, both large and small, varies and this contributes to the fact that new and different P recovery technology solutions must be developed and put into use in the years to come (e.g. mobile/stationary P recovery installations). The creation of a database focused on the collection and sharing of data about the amount of P recovered in EU and Polish installations is identified as a helpful tool in the development of an efficient P management model for Poland. Copyright © 2016 Elsevier Ltd. All rights reserved.

  18. Improved electrical efficiency and bottom ash quality on waste combustion plants. Appendix A7 to A10

    Energy Technology Data Exchange (ETDEWEB)

    Hyks, J.; Astrup, T.; Jensen, Peter A.; Nesterov, I.; Boejer, M.; Frandsen, F.; Dam-Johansen, K.; Hedegaard Madsen, O.; Lundtorp, K. (Technical Univ. of Denmark, Kgs. Lyngby (Denmark)); Mogensen, Erhardt (Babcock and Wilcox Voelund A/S, Glostrup (Denmark))

    2010-07-01

    Investigations making it possible to evaluate and further develop concepts to improve electrical efficiency in a waste combustion plant were performed. Furthermore, one objective of the study was to investigate the possibilities of improving waste bottom ash leaching properties by use of a rotary kiln treatment. The project work included construction of a bench-scale rotary kiln, performing ash rotary kiln treatment experiments, conducting gas suction probe measurements on a waste incineration plant and making some concept evaluations. The influence of the rotary kiln thermal treatment on the leaching of Ca, Al, Si, Mg, Ba, Sr, Cl, Cu, Pb, Zn, Cr, Mo, sulfate, DOC and carbonate was determined. As a result of these tests, the rotary kiln thermal treatment of bottom ashes can be recommended for reducing the leaching of Cu, Pb, Cl, Zn and DOC; however, an increased leaching of Cr and Mo should be expected. The combustion conditions above the grate of a waste incineration plant were investigated and the release and concentration of volatile ash species in the flue gas such as Cl, Na, K, Ca, Pb, Zn and S were measured. The conducted measurements show that flue gas from grate sections 3 and 4 can produce a sufficiently hot flue gas that contains only low concentrations of corrosive species, and therefore can be used to increase superheater temperatures. Implementation of the so-called flue gas split concept together with other steam circle modifications on a waste combustion plant, and using a reasonable increase in final steam temperature from 400 to 500 deg. C, have the potential to increase electrical efficiency from 24 to 30% (with respect to lower fuel heating value) in a waste combustion plant. The appendices deal with the influence of kiln treatment on incineration bottom ash leaching; the influence of kiln treatment on corrosive species in deposits; operational strategy for rotary kiln; alkali/chloride release during refuse incineration on a grate. (Author)

  19. Next generation of high-efficient waste incinerators. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Jappe Frandsen, F.

    2010-11-15

    Modern society produces increasing amounts of combustible waste which may be utilized for heat and power production, at a lower emission of CO{sub 2}, e.g. by substituting a certain fraction of energy from fossil fuel-fired power stations. In 2007, 20.4 % of the district heating and 4.5 % of the power produced in Denmark came from thermal conversion of waste, and waste is a very important part of a future sustainable, and independent, Danish energy supply [Frandsen et al., 2009; Groen Energi, 2010]. In Denmark, approx 3.3 Mtons of waste was produced in 2005, an amount predicted to increase to 4.4 Mtons by the year 2030. According to Affald Danmark, 25 % of the current WtE plant capacity in Denmark is older than 20 years, which is usually considered as the technical and economical lifetime of WtE plants. Thus, there is a need for installation of a significant fraction of new waste incineration capacity, preferentially with an increased electrical efficiency, within the next few years. Compared to fossil fuels, waste is difficult to handle in terms of pre-treatment, combustion, and generation of reusable solid residues. In particular, the content of inorganic species (S, Cl, K, Na, etc.) is problematic, due to enhanced deposition and corrosion - especially at higher temperatures. This puts severe constraints on the electrical efficiency of grate-fired units utilizing waste, which seldom exceeds 26-27%, campared to 46-48 % for coal combustion in suspension. The key parameters when targeting higher electrical efficiency are the pressure and temperature in the steam cycle, which are limited by high-temperature corrosion, boiler- and combustion-technology. This report reviews some of the means that can be applied in order to increase the electrical efficiency in plants firing waste on a grate. (Author)

  20. Heavy metal migration during electroremediation of fly ash from different wastes--modelling.

    Science.gov (United States)

    Lima, A T; Rodrigues, P C; Mexia, J T

    2010-03-15

    Fly ash is an airborne material which is considered hazardous waste due to its enrichment on heavy metals. Depending on the waste from which they are originated, fly ash may be further valorised, e.g. as soil amendment or concrete and ceramics adjuvant, or landfilled, when defined as hazardous material. In any case, heavy metal content has to be decreased either for fly ash valorisation or for complying with landfill criteria. The electrodialytic (EDR) process is a remediation technique based on the principle of electrokinetics and dialysis, having the aim to remove heavy metals from contaminated solid media. EDR was here applied to fly ashes from the combustion of straw (ST), from the incineration of municipal solid waste (DK and PT) and from the co-combustion of wood (CW). A statistical study, using F tests, Bonferroni multiple comparison method and a categorical regression, was carried out to determine which variables ("Ash type", "Duration", "Initial pH", "Final pH", "Acidification" and "Dissolution") were the most significant for EDR efficiency. After establishing these, the selected variables were then used to characterize some kinetic parameters, from metals migration during EDR, using a biregressional design. Cd, Cr, Cu, Ca and Zn migration velocity and acceleration to the electrodes (anode and cathode) were then considered. Cd and Cu migration to the cathode were found to be significantly influenced by "Ash type", "Duration", "Final pH" and "Dissolution". (c) 2009 Elsevier B.V. All rights reserved.

  1. An LCA model for waste incineration enhanced with new technologies for metal recovery and application to the case of Switzerland

    Energy Technology Data Exchange (ETDEWEB)

    Boesch, Michael E. [Aveny GmbH, Schwandenholzstr. 212, CH-8046 Zürich (Switzerland); Vadenbo, Carl, E-mail: vadenbo@ifu.baug.ethz.ch [ETH Zurich, Institute of Environmental Engineering, Schafmattstrasse 6, CH-8093 Zurich (Switzerland); Saner, Dominik [Swiss Post, Communications, Politics and Social Responsibility, Viktoriastrasse 21, P.O. Box, CH-3030 Berne (Switzerland); Huter, Christoph [City of Zürich, ERZ Entsorgung - Recycling Zürich, Hagenholzstrasse 110, P.O. Box, CH-8050 Zürich (Switzerland); Hellweg, Stefanie [ETH Zurich, Institute of Environmental Engineering, Schafmattstrasse 6, CH-8093 Zurich (Switzerland)

    2014-02-15

    Highlights: • An enhanced process-based LCA model for MSWI is featured and applied in case study. • LCA modeling of recent technological developments for metal recovery from fly ash. • Net release from Swiss MSWI 133 kg CO{sub 2}-eq/tonne waste from attributional LCA perspective. • Net savings from a consequential LCA perspective reach up to 303 kg CO{sub 2}-eq/tonne waste. • Impacts according to ReCiPe and CExD show similar pattern to climate change. - Abstract: A process model of municipal solid waste incinerators (MSWIs) and new technologies for metal recovery from combustion residues was developed. The environmental impact is modeled as a function of waste composition as well as waste treatment and material recovery technologies. The model includes combustion with a grate incinerator, several flue gas treatment technologies, electricity and steam production from waste heat recovery, metal recovery from slag and fly ash, and landfilling of residues and can be tailored to specific plants and sites (software tools can be downloaded free of charge). Application of the model to Switzerland shows that the treatment of one tonne of municipal solid waste results on average in 425 kg CO{sub 2}-eq. generated in the incineration process, and 54 kg CO{sub 2}-eq. accrue in upstream processes such as waste transport and the production of operating materials. Downstream processes, i.e. residue disposal, generates 5 kg CO{sub 2}-eq. Savings from energy recovery are in the range of 67 to 752 kg CO{sub 2}-eq. depending on the assumptions regarding the substituted energy production, while the recovery of metals from slag and fly ash currently results in a net saving of approximately 35 kg CO{sub 2}-eq. A similar impact pattern is observed when assessing the MSWI model for aggregated environmental impacts (ReCiPe) and for non-renewable resource consumption (cumulative exergy demand), except that direct emissions have less and no relevance, respectively, on the total

  2. Possible Removal of Mercury in Dry Flue Gas Cleaning Lines of Solid Waste Incineration Units

    OpenAIRE

    Svoboda, Karel

    2014-01-01

    Here we will focus on dry flue gas cleaning methods applied for MSW incineration. Majority of dust from the incineration is usually removed in electrostatic filters or fabric (bag) filters. Dry method of flue gas cleaning are advantageous particularly in smaller solid waste incineration units, they have usually lower capital costs and simpler operation. The dry gas cleaning methods are based on an alkali sorbent injection and fabric filters for removal of dust and solid products from cleaning...

  3. Waste heat usage in sludge incineration; Abwaermenutzung Schlammverbrennung. ARA Basel

    Energy Technology Data Exchange (ETDEWEB)

    Fath, H.

    2001-07-01

    This preliminary report for the Swiss Federal Office of Energy (SFOE) discusses the results of measurements made on a sewage-sludge incineration plant in Basle, Switzerland, that was fitted with heat recovery apparatus in 1999. A comparison is made between the energy balance of the incineration installation before and after its modification. The values for waste-heat recovery that were measured - normalised to enable the comparison - are presented. The use of the heat recovered for local heating purposes and for feeding into Basle's district heating system is described. The reasons for the discrepancy between the energy quantities that were initially expected and those actually attained are discussed: Increased in-house heating requirements and losses caused for unexpected reasons (partial drying of the flue gasses of one of the ovens to prevent corrosion) are quoted as causes for the discrepancy. The authors also note that the emergency cooler previously used before the heat-recovery system was added is no longer needed.

  4. Environmental assessment of waste incineration in a life-cycle-perspective (EASEWASTE).

    Science.gov (United States)

    Riber, Christian; Bhander, Gurbakhash S; Christensen, Thomas H

    2008-02-01

    A model for life-cycle assessment of waste incinerators is described and applied to a case study for illustrative purposes. As life-cycle thinking becomes more integrated into waste management, quantitative tools for assessing waste management technologies are needed. The presented model is a module in the life-cycle assessment model EASEWASTE. The module accounts for all uses of materials and energy and credits the incinerator for electricity and heat recovered. The energy recovered is defined by the user as a percentage of the energy produced, calculated on the lower heating value of the wet waste incinerated. Emissions are either process-specific (related to the amount of waste incinerated) or input-specific (related to the composition of the waste incinerated), while mass transfer to solid outputs are governed by transfer coefficients specified by the user. The waste input is defined by 48 material fractions and their chemical composition. The model was used to quantify the environmental performance of the incineration plant in Aarhus, Denmark before and after its upgrading in terms of improved flue gas cleaning and energy recovery. It demonstrated its usefulness in identifying the various processes and substances that contributed to environmental loadings as well as to environmental savings. The model was instrumental in demonstrating the importance of the energy recovery system not only for electricity but also heat from the incinerator.

  5. Wet physical separation of MSWI bottom ash

    NARCIS (Netherlands)

    Muchova, L.

    2010-01-01

    Bottom ash (BA) from municipal solid waste incineration (MSWI) has high potential for the recovery of valuable secondary materials. For example, the MSWI bottom ash produced by the incinerator at Amsterdam contains materials such as non-ferrous metals (2.3%), ferrous metals (8-13%), gold (0.4 ppm),

  6. Wet physical separation of MSWI bottom ash

    NARCIS (Netherlands)

    Van Breugel, K.; Muchova, L.

    Bottom ash (BA) from municipal solid waste incineration (MSWI) has high potential for the recovery of valuable secondary materials. For example, the MSWI bottom ash produced by the incinerator at Amsterdam contains materials such as non-ferrous metals (2.3%), ferrous metals (8-13%), gold (0.4 ppm),

  7. STORAGE AND RECOVERY OF SECONDARY WASTE COMING FROM MUNICIPAL WASTE INCINERATION PLANTS IN UNDERGROUND MINE

    Directory of Open Access Journals (Sweden)

    Waldemar Korzeniowski

    2016-09-01

    Full Text Available Regarding current and planned development of municipal waste incineration plants in Poland there is an important problem of the generated secondary waste management. The experience of West European countries in mining shows that waste can be stored successfully in the underground mines, but especially in salt mines. In Poland there is a possibility to set up the underground storage facility in the Salt Mine “Kłodawa”. The mine today is capable to locate over 3 million cubic meters and in the future it can increase significantly. Two techniques are proposed: 1 – storage of packaged waste, 2 – waste recovery as selfsolidifying paste with mining technology for rooms backfilling. Assuming the processing capacity of the storage facility as 100 000 Mg of waste per year, “Kłodawa” mine will be able to accept around 25 % of currently generated waste coming from the municipal waste incineration plants and the current volume of the storage space is sufficient for more than 20 years. Underground storage and waste recovery in mining techniques are beneficial for the economy and environment.

  8. Characterization of flue gas, fly ash, aerosol and deposit compositions as a function of waste composition and grate operation

    DEFF Research Database (Denmark)

    Pedersen, Anne Juul; Zeuthen, Frederik Jacob; Frandsen, Flemming

    2007-01-01

    The Danish strategy for waste management is still to increase recycling and on the same time to reduce the volume of land-filled waste, in order to avoid loss of resources, and waste incineration is an important part of this strategy. In 2004, 26 % of the total reported Danish waste production...... metals, was then mixed with the reference fuel in the individual test runs. The dedicated waste fractions comprised NaCl (road salt), batteries, automotive shredder waste, CCA (Copper-Chromate-Arsenate)-impregnated wood, PVC plastics, and (leather) shoes. Test runs with varying operational parameters, e...... elements Pb, Zn, Cd and Cu was found in the fly ash fractions sampled at app. 175oC, but not in the deposits sampled at 400oC. This indicated condensation of metal chlorides at lower temperatures. It was concluded that the composition of the input waste affected the composition of the fly ash and deposits...

  9. Electrodialytic treatment of fly ash

    DEFF Research Database (Denmark)

    Jensen, Pernille Erland; Pedersen, Anne Juul; Kirkelund, Gunvor Marie

    Heavy metals are removed from the fly ashes by an electrodialytic treatment with the aim of up-grading the ashes for reuse in stead of disposal in landfill.A great potential for upgrading of bio- and waste incineration ashes by electrodialytic treatment exists. In the future, the applicability...

  10. Stabilization and separation of heavy metals in incineration fly ash during the hydrothermal treatment process.

    Science.gov (United States)

    Hu, Yuyan; Zhang, Pengfei; Li, Jianping; Chen, Dezhen

    2015-12-15

    In the paper, hydrothermal treatment (HT) of MSWI fly ashes was performed to stabilize and separate heavy metals. Influences of pre-treatment, types of ferric and/or ferrous additives, and subsequent heavy metal stabilization procedure by adding phosphate were investigated. The chemical stability of hydrothermal products was examined by solid waste extraction procedure with acetic acid buffer solution. Mineralogical investigation of selected hydrothermal product was carried out by XRD. FEGE SEM- -EDX was used to study the morphology and surface compositions of the ash particles. Experimental results revealed that HT process facilitated heavy metal exposure to leaching solution. FEGE SEM-EDX images revealed that fly ash particles were re-organized during hydrothermal process and that the minerals with special shapes and containing high levels of heavy metals were formed. A mild acid washing treatment with final pH around 6.20 could remove soluble heavy metals. Therefore, it may be a proper pre- or post-treatment method for fly ash particles for the purpose of reducing heavy metal contents. For the purpose of stabilizing heavy metals, the addition of ferric/ferrous salts in the HT process or phosphate stabilization after HT is recommended. The HT process may be applied to realize the environmentally sound management of MSWI fly ash or to recover and utilize MSWI fly ash. Copyright © 2015 Elsevier B.V. All rights reserved.

  11. Improved electrical efficiency and bottom ash quality on waste combustion plants. Appendix A4 to A6

    Energy Technology Data Exchange (ETDEWEB)

    Kloeft, H.; Jensen, Peter A.; Nesterov, I.; Hyks, J.; Astrup, T. (Technical Univ. of Denmark, Kgs. Lyngby (Denmark)); Mogensen, Erhardt (Babcock and Wilcox Voelund A/S, Glostrup (Denmark))

    2010-07-01

    Investigations making it possible to evaluate and further develop concepts to improve electrical efficiency in a waste combustion plant were performed. Furthermore, one objective of the study was to investigate the possibilities of improving waste bottom ash leaching properties by use of a rotary kiln treatment. The project work included construction of a bench-scale rotary kiln, performing ash rotary kiln treatment experiments, conducting gas suction probe measurements on a waste incineration plant and making some concept evaluations. The influence of the rotary kiln thermal treatment on the leaching of Ca, Al, Si, Mg, Ba, Sr, Cl, Cu, Pb, Zn, Cr, Mo, sulfate, DOC and carbonate was determined. As a result of these tests, the rotary kiln thermal treatment of bottom ashes can be recommended for reducing the leaching of Cu, Pb, Cl, Zn and DOC; however, an increased leaching of Cr and Mo should be expected. The combustion conditions above the grate of a waste incineration plant were investigated and the release and concentration of volatile ash species in the flue gas such as Cl, Na, K, Ca, Pb, Zn and S were measured. The conducted measurements show that flue gas from grate sections 3 and 4 can produce a sufficiently hot flue gas that contains only low concentrations of corrosive species, and therefore can be used to increase superheater temperatures. Implementation of the so-called flue gas split concept together with other steam circle modifications on a waste combustion plant, and using a reasonable increase in final steam temperature from 400 to 500 deg. C, have the potential to increase electrical efficiency from 24 to 30% (with respect to lower fuel heating value) in a waste combustion plant. The appendices deal with collection of slags for the rotary kiln experiments; overview of the thermal treatment experiments - phase 1; a journal paper with the title ''Quantification of leaching from waste incineration bottom ash treated in a rotary kiln

  12. Production of technical grade phosphoric acid from incinerator sewage sludge ash (ISSA).

    Science.gov (United States)

    Donatello, S; Tong, D; Cheeseman, C R

    2010-01-01

    The recovery of phosphorus from sewage sludge ash samples obtained from 7 operating sludge incinerators in the UK using a sulfuric acid washing procedure to produce a technical grade phosphoric acid product has been investigated. The influences of reaction time, sulfuric acid concentration, liquid to solid ratio and source of ISSA on P recovery have been examined. The optimised conditions were the minimum stoichiometric acid requirement, a reaction time of 120 min and a liquid to solid ratio of 20. Under these conditions, average recoveries of between 72% and 91% of total phosphorus were obtained. Product filtrate was purified by passing through a cation exchange column, concentrated to 80% H(3)PO(4) and compared with technical grade H(3)PO(4) specifications. The economics of phosphate recovery by this method are briefly discussed. 2010 Elsevier Ltd. All rights reserved.

  13. Recycling municipal incinerator fly- and scrubber-ash into fused slag for the substantial replacement of cement in cement-mortars.

    Science.gov (United States)

    Lee, Tzen-Chin; Rao, Ming-Kang

    2009-06-01

    Fly- and scrubber-ash (weight ratio of approximately 1:3) from municipal solid waste incinerators (MSWI) are a major land-fill disposal problem due to their leaching of heavy metals. We uniformly mixed both types of ash with optimal amounts of waste glass frit, which was then melted into a glassy slag. The glassy slag was then pulverized to a particle size smaller than 38microm for use as a cement substitute (20-40% of total cement) and blended with sand and cement to produce slag-blended cement-mortar (SCM) specimens. The toxicity characteristics of the leaching procedure tests on the pulverized slag samples revealed that the amount of leached heavy metals was far below regulatory thresholds. The compressive strength of the 28-day cured SCM specimens was comparable to that of ordinary Portland cement mortars, while the compressive strength of specimens cured for 60 or 90 days were 3-11% greater. The observed enhanced strength is achieved by Pozzolanic reaction. Preliminary evaluation shows that the combination of MSWI fly- and scrubber-ash with waste glass yields a cost effective and environmentally friendly cement replacement in cement-mortars.

  14. Risk of Congenital Anomalies in the Vicinity of Municipal Solid Waste Incinerators

    National Research Council Canada - National Science Library

    S. Cordier; C. Chevrier; E. Robert-Gnansia; C. Lorente; P. Brula; M. Hours

    2004-01-01

    Background: Although municipal solid waste incineration (MSWI) has contributed to increase the overall environmental load of particulate matter containing dioxins and metals, evidence of health consequences to populations is sparse. Aims...

  15. Dangerous waste incineration and its impact on air quality. Case study: the incinerator SC Mondeco SRL Suceava

    Directory of Open Access Journals (Sweden)

    Dumitru MIHĂILĂ

    2015-03-01

    Full Text Available Dangerous waste, such as oil residues, pesticides, lacquers, stains, glues, organic solvents, hospital and food industry residues represent a major risk for all components of the environment (water, air, earth, soil, flora, fauna, people as well. Consequently, their incineration with high-performance burning installations lessens the impact on the environment, especially on the air quality, and it gives the possibility to recuperate the warmth of the incineration. This research presents a representative technique of incineration of dangerous waste at S.C. Mondeco S.R.L. Suceava, which runs according to the European standards, located in the industrial zone of Suceava, on the Suceava river valley Suceava. Also it is analysed the impact of this unit on the quality of nearby air. Moreover, not only the concentrations of gases and powders during the action of the incineration process (paramaters that are continuously monitored by highly methods are analysed, but also here are described the dispersions of those pollutants in the air, taking into account the characteristics of the source and the meteorological parametres that are in the riverbed. 

  16. Incineration technologies

    CERN Document Server

    Buekens, Alfons

    2013-01-01

    Waste incineration is the art of completely combusting waste, while maintaining or reducing emission levels below current emission standards. Where possible, objectives include the recovering of energy as well as the  combustion residues.  Successful waste incineration makes it possible to achieve a deep reduction in waste volume, obtain a compact and sterile residue, and eliminate a wide array of pollutants. This book places waste incineration within the wider context of waste management, and demonstrates that, in contrast to landfills and composting, waste incineration can eliminate objectionable and hazardous properties such as flammability and toxicity, result in a significant reduction in volume, and destroy gaseous and liquid waste streams leaving little or no residues beyond those linked to flue gas neutralization and treatment. Moreover, waste incineration sterilizes and destroys putrescible matter, and produces usable heat.  Incineration Technologies first appeared as a peer-reviewed contribution ...

  17. Efficiency of energy recovery from waste incineration, in the light of the new Waste Framework Directive.

    Science.gov (United States)

    Grosso, Mario; Motta, Astrid; Rigamonti, Lucia

    2010-07-01

    This paper deals with a key issue related to municipal waste incineration, which is the efficiency of energy recovery. A strong driver for improving the energy performances of waste-to-energy plants is the recent Waste Framework Directive (Directive 2008/98/EC of the European Parliament and of the Council of 19 November 2008 on waste and repealing certain Directives), which allows high efficiency installations to benefit from a status of "recovery" rather than "disposal". The change in designation means a step up in the waste hierarchy, where the lowest level of priority is now restricted to landfilling and low efficiency wastes incineration. The so-called "R1 formula" reported in the Directive, which counts for both production of power and heat, is critically analyzed and correlated to the more scientific-based approach of exergy efficiency. The results obtained for waste-to-energy plants currently operating in Europe reveal some significant differences in their performance, mainly related to the average size and to the availability of a heat market (district heating). Copyright (c) 2010 Elsevier Ltd. All rights reserved.

  18. Improved electrical efficiency and bottom ash quality on waste combustion plants. Appendix A1 to A3

    Energy Technology Data Exchange (ETDEWEB)

    Nesterov, I.; Jensen, Peter A.; Dam-Johansen, K.; Kloeft, H.; Boejer, M. (Technical Univ. of Denmark, Kgs. Lyngby (Denmark)); Mogensen, Erhardt (Babcock and Wilcox Voelund A/S, Esbjerg (Denmark))

    2010-07-01

    Investigations making it possible to evaluate and further develop concepts to improve electrical efficiency in a waste combustion plant were performed. Furthermore, one objective of the study was to investigate the possibilities of improving waste bottom ash leaching properties by use of a rotary kiln treatment. The project work included construction of a bench-scale rotary kiln, performing ash rotary kiln treatment experiments, conducting gas suction probe measurements on a waste incineration plant and making some concept evaluations. The influence of the rotary kiln thermal treatment on the leaching of Ca, Al, Si, Mg, Ba, Sr, Cl, Cu, Pb, Zn, Cr, Mo, sulfate, DOC and carbonate was determined. As a result of these tests, the rotary kiln thermal treatment of bottom ashes can be recommended for reducing the leaching of Cu, Pb, Cl, Zn and DOC; however, an increased leaching of Cr and Mo should be expected. The combustion conditions above the grate of a waste incineration plant were investigated and the release and concentration of volatile ash species in the flue gas such as Cl, Na, K, Ca, Pb, Zn and S were measured. The conducted measurements show that flue gas from grate sections 3 and 4 can produce a sufficiently hot flue gas that contains only low concentrations of corrosive species, and therefore can be used to increase superheater temperatures. Implementation of the so-called flue gas split concept together with other steam circle modifications on a waste combustion plant, and using a reasonable increase in final steam temperature from 400 to 500 deg. C, have the potential to increase electrical efficiency from 24 to 30% (with respect to lower fuel heating value) in a waste combustion plant. The appendices deal with incineration bottom ash leaching properties; design and construction of rotary kiln facility; manual to rotary kiln experiments. (Author)

  19. Recovering metals from sewage sludge, waste incineration residues and similar substances with hyperaccumulative plants

    Science.gov (United States)

    Kisser, Johannes; Gattringer, Heinz; Iordanopoulos-Kisser, Monika

    2015-04-01

    Sewage sludges as well as ashes from waste incineration plants are known accumulation sinks of many elements that are either important nutrients for biological organisms (phosphorus, potassium, magnesium, etc.) or valuable metals when considered on their own in pure form (nickel, chrome, zinc, etc.); they are also serious pollutants when they occur in wild mixtures at localized anthropogenic end- of-stream points. Austria and many other countries have to import up to 90% of the material inputs of metals from abroad. These primary resources are becoming more expensive as they become more scarce and remaining deposits more difficult to mine, which is a serious concern for industrialized nations. Basic economic and strategic reasoning demands an increase in recycling activities and waste minimization. Technologies to recover metals in a reasonable and economically relevant manner from very diffuse sources are practically non-existent or require large amounts of energy and chemicals, which pose environmental risks. On the other hand agriculture uses large volumes of mineral fertilizers, which are often sourced from mines as well, and thus are also subject to the same principle of finiteness and potential shortage in supply. These converted biological nutrients are taken up by crops and through the food chain and human consumption end up in sewage systems and in wastewater treatment plants in great quantities. The metabolized nutrients mostly do not return to agriculture, but due to contamination with heavy metals are diverted to be used as construction aggregates or are thermally treated and end up rather uselessly in landfills. The project BIO-ORE aimed to explore new pathways to concentrate metals from diluted sources such as sewage sludge and wastewater by using highly efficient biological absorption and transport mechanisms. These enzymatic systems from plants work with very little energy input. The process is called bioaccumulation and can be most effectively

  20. Effect of municipal solid waste ash on comprehensive strength ...

    African Journals Online (AJOL)

    The blocks were moulded in a CINVA-Ram machine by replacing 0%, 2%, 5% and 10% of municipal solid waste ash (MSW ash) as a stabilizing agent. The compressive strengths of individual blocks were obtained after curing for 7, 14 and 28 days. The 2%MSW ash replacement gave the highest compressive strength and ...

  1. Legal problems in the licensing of installations for recycling of solid wastes from municipal waste incineration. Rechtsprobleme bei der Genehmigung von Anlagen zur Verwertung fester Verbrennungsrueckstaende aus der Hausmuellverbrennung

    Energy Technology Data Exchange (ETDEWEB)

    Herkommer, E.; Kressel, E.; Wollenschlaeger, M.

    1989-07-01

    The article mentions the solid wastes from municipal waste incineration and discusses in particular the treatment and use of raw ashes. The existing legal provisions governing the treatment and use of such solid waste are reviewed, including an examination of the applicability of the federal waste management law (AbfG) and the federal law on prevention of immissions (BImSchG). The conclusion is that solid residues from waste incineration may for the most part be recycled, but pollutant concentration limits provided by the law must be observed and thus may prevent recycling. The recycling facilities are subject to licensing in compliance with section 4, sub-sec. (1) of the BImSchG, but the categories given in column 2 (item 8.4) of the annex to the 4th Ordinance on Prevention of Immissions require only a simplified licensing procedure according to section 19. (orig./RST).

  2. CO2 emission factors for waste incineration: Influence from source separation of recyclable materials

    DEFF Research Database (Denmark)

    Larsen, Anna Warberg; Astrup, Thomas

    2011-01-01

    variations between emission factors for different incinerators, but the background for these variations has not been thoroughly examined. One important reason may be variations in collection of recyclable materials as source separation alters the composition of the residual waste incinerated. The objective...... of this study was to quantify the importance of source separation for determination of emission factors for incineration of residual household waste. This was done by mimicking various source separation scenarios and based on waste composition data calculating resulting emission factors for residual waste...... waste; however the fossil carbon ratio of the waste after source separation was found to be appropriately correlated with the emission factor. Based on the results, it is recommended to carefully evaluate the source separation and collection systems behind reported literature values when comparing...

  3. Waste policy and learning. Policy dynamics of waste management and waste incineration in the Netherlands and Bavaria

    Energy Technology Data Exchange (ETDEWEB)

    Eberg, J.W.

    1997-12-31

    This study is structured by applying the Advocacy Coalition Framework (ACF, a general model of policy evolution)., In Chapter 2 actors are grouped into four institutional clusters: government, business, science, and public, and the waste problems are ordered along four basic questions. Next, the relatively stable parameters and dynamic system events, and the development of waste policy are elaborated for the Netherlands and Bavaria in Germany. While chapter 2 works out the `left-hand side` of the ACF (institutional aspects), chapter 3 concentrates on the `right-hand side` of the ACF (constructivist aspects), deals with waste incineration technology for both municipal and hazardous waste, and discusses technological generations as well as arguments regarding waste incineration. Also four waste incineration policy issues (`main topics`) in relation to the ACF are discussed, structuring the contents of the following case study chapters: organizational preferences, capacity need, risk assessments, and technological fixes. The case studies elaborate certain characteristic features, e.g. political stability and the role of citizens` initiatives in Bavaria, and the prominent position of AVR as a waste incinerator in the Netherlands. In chapter 8, the case study results and learning aspects are summarized, and the two main research questions answered. Research question two is answered with the help of institutional-political insights and Cultural Theory. For each country, policy styles and political cultures are outlined, indicating the relation between waste policy and national policy. Chapter 9 assesses the usefulness of the ACF, and the combination of the ACF and the cultural approach. It is to be shown that the ACF and Cultural Theory are complementary frameworks. Finally, this chapter formulates recommendations to waste policy. figs., tabs., refs.

  4. Environmental assessment of waste incineration and alternatives; Miljoevurdering af affaldsforbraending og alternativer

    Energy Technology Data Exchange (ETDEWEB)

    Moeller, J.; Fruergaard, T.; Riber, C.; Astrup, T.; Hoejlund Christensen, T.

    2008-06-15

    Life cycle environmental assessment of waste combustion and alternatives were made using the LCA model EASEWASTE. Possible environmental effects for nine effect categories and the resource consumption of fossil fuels through treating 1 ton combustible waste were defined for several waste systems, including waste-only incineration, co-combustion in a fossil-fueled cogeneration plant, and combined biogas and compost production from household waste. The main conclusions of the analyses are: 1) with an optimum location, i.e. in the vicinity to a coal-fueled cogeneration plant, waste-only incineration, co-combustion , and combined biogas and compost production are all equal environmentally viable alternatives . 2) Regarding potential toxic impacts in the area of a coal-fueled cogeneration plant, waste-only incineration and combined biogas and compost production will result in slightly less net emissions compared to co-combustion because of better flue gas cleaning of heavy metals in incinerators than in power plants. 3) Siting the incinerator in a decentralized natural gas cogeneration area, co-combustion in a cogeneration plant is a better solution. 4) Combined biogas and compost production and waste-only combustion are environmentally equal treatments in all power plant areas. (ln)

  5. Municipal solid waste incineration in China and the issue of acidification: A review.

    Science.gov (United States)

    Ji, Longjie; Lu, Shengyong; Yang, Jie; Du, Cuicui; Chen, Zhiliang; Buekens, Alfons; Yan, Jianhua

    2016-04-01

    In China, incineration is essential for reducing the volume of municipal solid waste arising in its numerous megacities. The evolution of incinerator capacity has been huge, yet it creates strong opposition from a small, but vocal part of the population. The characteristics of Chinese municipal solid waste are analysed and data presented on its calorific value and composition. These are not so favourable for incineration, since the sustained use of auxiliary fuel is necessary for ensuring adequate combustion temperatures. Also, the emission standard for acid gases is more lenient in China than in the European Union, so special attention should be paid to the issue of acidification arising from flue gas. Next, the techniques used in flue gas cleaning in China are reviewed and the acidification potential by cleaned flue gas is estimated. Still, acidification induced by municipal solid waste incinerators remains marginal compared with the effects of coal-fired power plants. © The Author(s) 2016.

  6. Distribution of polybrominated diphenyl ethers (PBDEs) and polybrominated dibenzo-p-dioxins and dibenzofurans (PBDD/Fs) in municipal solid waste incinerators

    Energy Technology Data Exchange (ETDEWEB)

    Wang, L.-C., E-mail: lcwang@csu.edu.t [Department of Chemical and Materials Engineering, Cheng Shiu University, 840, Chengching Road, Kaohsiung 833, Taiwan (China); Super Micro Mass Research and Technology Center, Cheng Shiu University, 840, Chengching Road, Kaohsiung 833, Taiwan (China); Hsi, H.-C. [Institute of Environmental Engineering and Management, National Taipei University of Technology, 1, Sec. 3, Chung-hsiao E. Road, Taipei 10608, Taiwan (China); Wang, Y.-F. [Department of Bioenvironmental Engineering, Chung Yuan Christian University, 200, Chung-Pei Road, Chung-Li 320, Taiwan (China); R and D Center of Membrane Technology, Chung Yuan Christian University, 200, Chung-Pei Road, Chung-Li 320, Taiwan (China); Lin, S.-L. [Department of Environmental Engineering, National Cheng Kung University, 1, University Road, Tainan 70101, Taiwan (China); Sustainable Environment Research Center, National Cheng Kung University, 1, University Road, Tainan 70101, Taiwan (China); Guo-Ping Chang-Chien [Department of Chemical and Materials Engineering, Cheng Shiu University, 840, Chengching Road, Kaohsiung 833, Taiwan (China); Super Micro Mass Research and Technology Center, Cheng Shiu University, 840, Chengching Road, Kaohsiung 833, TaiwanC (China)

    2010-05-15

    The stack flue gases and the ashes in different units of two municipal solid waste incinerators (MSWIs) are sampled to investigate the characteristics of polybrominated diphenyl ethers (PBDEs), polybrominated dibenzo-p-dioxins and dibenzofurans (PBDD/Fs), and polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs). Bottom ashes (BA) exhibited much higher PBDD/F (8.11-52.2 pg TEQ/g) and PBDE contents (20.4-186 ng/g) than those of fly ashes (0.0932-2.02 pg TEQ/g and 0.332-25.5 ng/g), revealing that the PBDD/Fs and PBDEs in the feeding waste may not be completely destroyed. The PBDE concentrations/contents in the stack flue gases (26.1-109 ng/Nm{sup 3}) and in the BA (20.4-186 ng/g) of the MSWIs could reach three orders higher than those in the atmosphere and reference soils. PBDE contributions to the environment from the stack flue gases or the reutilization of BA of MSWIs should not be ignored from the developing PBDE inventory. - Municipal solid waste incinerators contributed PBDEs and PBDD/Fs to the environment through stack flue gases and reutilization of bottom ashes.

  7. Life cycle assessment of a national policy proposal - the case of a Swedish waste incineration tax.

    Science.gov (United States)

    Björklund, Anna E; Finnveden, Göran

    2007-01-01

    At the core of EU and Swedish waste policy is the so-called waste hierarchy, according to which waste should first be prevented, but should otherwise be treated in the following order of prioritisation: reuse, recycling when environmentally motivated, energy recovery, and last landfilling. Some recent policy decisions in Sweden aim to influence waste management in the direction of the waste hierarchy. In 2001 a governmental commission assessed the economic and environmental impacts of introducing a weight-based tax on waste incineration, the purpose of which would be to encourage waste reduction and increase materials recycling and biological treatment. This paper presents the results of a life cycle assessment (LCA) of the waste incineration tax proposal. It was done in the context of a larger research project concerning the development and testing of a framework for Strategic Environmental Assessment (SEA). The aim of this paper is to assess the life cycle environmental impacts of the waste incineration tax proposal, and to investigate whether there are any possibilities of more optimal design of such a tax. The proposed design of the waste incineration tax results in increased recycling, but only in small environmental improvements. A more elaborate tax design is suggested, in which the tax level would partly be related to the fossil carbon content of the waste.

  8. Utilization of ash from municipal solid waste combustion

    Energy Technology Data Exchange (ETDEWEB)

    Jones, C.; Hahn, J.; Magee, B.; Yuen, N.; Sandefur, K.; Tom, J.; Yap, C.

    1999-09-01

    This ash study investigated the beneficial use of municipal waste combustion combined ash from the H-POWER facility in Oahu. These uses were grouped into intermediate cover for final closure of the Waipahu landfill, daily cover at the Waimanalo Gulch Landfill, and partial replacement for aggregate in asphalt for road paving. All proposed uses examine combined fly and bottom ash from a modern waste-to-energy facility that meets requirements of the Clean Air Act Amendments for Maximum Achievable Control Technology.

  9. Protective Coatings in the Power Boilers Used to Incinerate Waste – Fuel Characteristics of Waste as the Source of Energy

    Directory of Open Access Journals (Sweden)

    Słania J.

    2016-03-01

    Full Text Available A general characteristics of waste management was presented. Municipal waste was characterised and its fuel properties were provided. Numerous thermal processes of waste utilisation were described such as an incinerating process, free-oxygen technology - pyrolysis, technology with oxygen deficiency - gasification and the plasma technology.

  10. Energy recovery from waste incineration: assessing the importance of district heating networks.

    Science.gov (United States)

    Fruergaard, T; Christensen, T H; Astrup, T

    2010-07-01

    Municipal solid waste incineration contributes with 20% of the heat supplied to the more than 400 district heating networks in Denmark. In evaluation of the environmental consequences of this heat production, the typical approach has been to assume that other (fossil) fuels could be saved on a 1:1 basis (e.g. 1GJ of waste heat delivered substitutes for 1GJ of coal-based heat). This paper investigates consequences of waste-based heat substitution in two specific Danish district heating networks and the energy-associated interactions between the plants connected to these networks. Despite almost equal electricity and heat efficiencies at the waste incinerators connected to the two district heating networks, the energy and CO(2) accounts showed significantly different results: waste incineration in one network caused a CO(2) saving of 48 kg CO(2)/GJ energy input while in the other network a load of 43 kg CO(2)/GJ. This was caused mainly by differences in operation mode and fuel types of the other heat producing plants attached to the networks. The paper clearly indicates that simple evaluations of waste-to-energy efficiencies at the incinerator are insufficient for assessing the consequences of heat substitution in district heating network systems. The paper also shows that using national averages for heat substitution will not provide a correct answer: local conditions need to be addressed thoroughly otherwise we may fail to assess correctly the heat recovery from waste incineration. Copyright (c) 2010 Elsevier Ltd. All rights reserved.

  11. Polychlorinated biphenyls emission from a medical waste incinerator in China.

    Science.gov (United States)

    Chen, Tong; Li, Xiaodong; Yan, Jianhua; Jin, Yuqi

    2009-12-30

    Detailed polychlorinated biphenyls (PCBs) congener patterns were determined in the flue gas from a medical waste incinerator (MWI) using high-resolution gas chromatograph coupled to high-resolution mass spectrometer (HRGC/HRMS). The total PCBs concentration of all homologues (mono- to deca-chlorinated homologues) in the flue gas ranged from 138.01 to 855.35 ng/Nm(3) and the WHO-TEQ value varied from 0.046 to 0.549 ng/Nm(3) under the different operating conditions. PCB-77 concentration was the highest among dioxin-like PCBs and PCB-126 contributed mostly to the WHO-TEQ. The ratios of dioxin-like PCBs in the total PCB concentrations in the flue gas varied between 11.7% and 26.0% (the average value is 18.7%). Three inhibitors, sulfur, urea, and ammonium sulfate were tested to investigate the capacity for preventing PCBs formation. The decomposition efficiency for total PCBs and PCBs TEQ ranged from 38% to 84% and 69% to 92% respectively. It was shown that urea mixed with ammonium sulfate and more activated carbon was proved to be the most effective inhibitor for PCBs formation. The removal efficiencies (REs) of the total PCBs concentration and PCBs TEQ by the bag filter under two conditions were 69% and 85%, and 86% and 94% respectively.

  12. Energy and exergy optimization of food waste pretreatment and incineration.

    Science.gov (United States)

    Tang, Yuanjun; Dong, Jun; Chi, Yong; Zhou, Zhaozhi; Ni, Mingjiang

    2017-08-01

    With the aim of upgrading current food waste (FW) management strategy, a novel FW hydrothermal pretreatment and air-drying incineration system is proposed and optimized from an energy and exergy perspective. Parameters considered include the extracted steam quality, the final moisture content of dehydrated FW, and the reactor thermal efficiency. Results show that optimal working condition can be obtained when the temperature and pressure of extracted steam are 159 °C and 0.17 MPa, the final moisture content of dehydrated FW is 10%, and the reactor thermal efficiency is 90%. Under such circumstance, the optimal steam energy and exergy increments reach 194.92 and 324.50 kJ/kg-FW, respectively. The novel system is then applied under the local conditions of Hangzhou, China. Results show that approximately 2.7 or 11.6% (from energy or exergy analysis perspective) of electricity can be additionally generated from 1 ton of MSW if the proposed novel FW system is implemented. Besides, comparisons between energy and exergy analysis are also discussed.

  13. The development of new generation of solid waste refuse incinerators

    African Journals Online (AJOL)

    The heat retention is so high that it allows incineration of subsequent rubbish. Results indicate total destruction capability of wet to dry rubbish into their mineral constituents. The design of these incinerators does not allow combustion products directly into the atmosphere as was in the case of the older ones and with ...

  14. Incinerator performance: effects of changes in waste input and furnace operation on air emissions and residues

    DEFF Research Database (Denmark)

    Astrup, Thomas; Riber, Christian; Pedersen, Anne Juul

    2011-01-01

    Waste incineration can be considered a robust technology for energy recovery from mixed waste. Modern incinerators are generally able to maintain relatively stable performance, but changes in waste input and furnace operation may affect emissions. This study investigated how inorganic air emissio...... ranges of element transfer coefficients were provided as the basis for sensitivity analysis of life-cycle assessment (LCA) results involving waste incinerator technologies...... and residue composition at a full-scale incinerator were affected by known additions of specific waste materials to the normal municipal solid waste (MSW) input. Six individual experiments were carried out (% ww of total waste input): NaCl (0.5%), shoes (1.6%), automobile shredder waste (14%), batteries (0.......5%), poly(vinyl chloride) (5.5%) and chromate-cupper-arsenate impregnated wood (11%). Materials were selected based on chemical composition and potential for being included or excluded from the waste mix. Critical elements in the waste materials were identified based on comparison with six experiments...

  15. Metals control efficiency test at a dry-scrubber and baghouse-equipped hazardous-waste incinerator

    Energy Technology Data Exchange (ETDEWEB)

    Garg, S.; Holloway, J.R.

    1990-09-01

    The Environmental Protection Agency, Office of Solid Waste is developing regulations to control emissions of toxic metals from hazardous waste incinerators. As part of an effort to gather data on control efficiencies that can be achieved by hazardous waste incineration facilities, equipped with various types of air pollution control devices, a test was performed at Unit No. 4 in Sauget, Illinois.

  16. Technical and economic assessment of power generation from municipal solid waste incineration on steam cycle

    Energy Technology Data Exchange (ETDEWEB)

    Romero Luna, Carlos Manuel; Carrocci, Luiz Roberto; Ferrufino, Gretta Larisa Aurora Arce; Balestieri, Jose Antonio Perrella [Dept. of Energy. UNESP, Sao Paulo State University, Guaratingueta, SP (Brazil)], e-mails: carrocci@feg.unesp.br, perrella@feg.unesp.br

    2010-07-01

    Nowadays, there is a concern in development of environmentally friendly methods for a municipal solid waste (MSW) management and demand for renewable energy sources. The source of waste is increasing, and the capacity and availability Landfill treatment and disposal are coming to be insufficient. In Sao Paulo City, the 10 million inhabitants produce 10,000 t of residential solid waste daily, being that 76% this quantity goes to landfill sites. In order to adopt a new treatment technology for MSW that will promote a solution minimizing this problem, within the order of priorities regarding waste management, the MSW incineration with energy recovery shown as the leading choice on the point of view of efficiency in converting energy. MSW incineration with energy recovery received wide acceptance from various countries including European Union members and the rest of the world in the past 15 years. Incineration has the ability decrease 90 % the volume of waste to be used in landfills, increasing the useful life of existing as well as a reduction in the emission of greenhouse gases. MSW incineration systems have a low global warming potential (GWP). now has become a less important source of dioxins and furans due to the current available technology. MSW incineration with energy recovery could contribute considerably in the energy matrix, thus promote the conservation of non-renewable resources. This paper proposes the assessment the technical and economic feasibility of a steam cycle with conventional steam generator for MSW incineration with energy recovery for power generation in Sao Paulo City. Will be developed a thermoeconomic analysis aiming at the total power generation product of MSW incineration, and the assessment investment cost regarding the total sale of power generated. The study shows that Sao Paulo City has potential for power generation from the MSW incineration, although it has a high cost investment this technology shown as a suitable alternative for

  17. Washing of fly ash from combustion of municipal solid waste using water as leachant; Vattentvaett av flygaska fraan avfallsfoerbraenning

    Energy Technology Data Exchange (ETDEWEB)

    Steenari, Britt-Marie; Zhao, Dongmei

    2010-03-15

    Ashes from combustion of municipal solid waste contain a large amount of minerals, salts and other metal compounds that are more or less soluble in water. The metal salts are often enriched in the fly ash which leads to a classification of the ash as hazardous waste. This makes ash management complicated and costly. Many stabilisation methods for Municipal Solid Waste Incineration (MSWI) fly ash have been developed and most of them are based on a removal of chloride and sulfate in addition to a binding of metals in less soluble forms. The aim is to avoid the common situation that the ash does not comply to leaching limit values due to release of harmless salts. The aim of this project was to investigate if a simple washing with water can remove enough of the fly ash content of chloride and sulphate so that the ash can be landfilled in a simpler and less costly way than today. The project was focused on fly ashes from the MSWI units owned by Boraas Energi och Miljoe AB and Renova AB Goeteborg, i.e. a electro filter ash from grate fired boilers at Renova and a cyclone ash from a fluid bed boiler at Boraas. The results show that the main part of the chloride content of the ashes can be removed easily, but the washing with water is less effective in the removal of sulphate. A water-to-ash ratio of 1-2 l/kg removes about 100% of chloride but only 8-16% of the sulphate content. In many cases, the leachability of sulphate increases after the washing step. This is due to the rather complex sulphate chemistry with several possible reactions taking place in the ash-water system. For both the tested ashes the high level of chloride leaching is an important factor that prevents admittance on a landfill for hazardous waste without treatment.. The leaching of certain metals, such as Pb, is also high from both ashes but in the case of the Renova fly ash this is dealt with by treatment of the ash according to the Bamberg method. After a water washing with L/S 1-2 (L/kg dry ash

  18. Incineration or autoclave? A comparative study in isfahan hospitals waste management system (2010).

    Science.gov (United States)

    Ferdowsi, Ali; Ferdosi, Masoud; Mehrani, Mohammd Javad

    2013-03-01

    Medical wastes are among hazardous wastes and their disposal requires special methods prior to landfilling. Medical wastes are divided into infected and non-infected wastes and the infected wastes require treatment. Incineration is one of the oldest methods for treatment of medical wastes, but their usage have faced wide objections due to emission of hazardous gases such as CO2 and CO as well as Carcinogenic gases such as Dioxins and Furans which are generated as a result of incomplete combustion of compositions like PVCs. Autoclave is one the newest methods of medical wastes treatment which works based on wet disinfection. The statistical population in this descriptive, comparative study includes hospitals located in Isfahan city and the sample hospitals were selected randomly. To environmentally evaluate the Autoclave method, TST (time, steam, temperature) and Spore tests were used. Also, samples were made from incinerator's stack gases and their analyses results were compared with WHO standards. TST and spore tests results were negative in all cases indicating the success of treatment process. The comparison of incinerator's stack gases with WHO standards showed the high concentration of CO in some samples indicating the incomplete combustion. Also, the incineration efficiency in some cases was less than 99.5 percent, which is the efficiency criterion according to the administrative regulations of wastes management law of Iran. No needle stick was observed in Autoclave method during the compaction of bags containing wastes, and the handlers were facing no danger in this respect. The comparison of costs indicated that despite higher capital investment for purchasing autoclave, its current costs (e.g. maintenance, etc) are much less than the incineration method. Totally, due to inappropriate operation of incinerators and lack of air pollution control devices, the use of incinerators doesn't seem rational anymore. Yet, despite the inefficiency of autoclaves in

  19. Electrodialytic removal of heavy metals from fly ashes

    DEFF Research Database (Denmark)

    Pedersen, Anne Juul

    2002-01-01

    The aim of the Ph.D. work was to develop the electrodialytic remediation method for removal of heavy metals from fly ashes. The work was focused on two types of fly ashes: fly ashes from wood combustion and fly ashes from municipal solid waste incineration....

  20. Radioactive wastes dispersed in stabilized ash cements

    Energy Technology Data Exchange (ETDEWEB)

    Rubin, J.B.; Taylor, C.M.V.; Sivils, L.D.; Carey, J.W.

    1997-12-31

    One of the most widely-used methods for the solidification/stabilization of low-level radwaste is by incorporation into Type-I/II ordinary portland cement (OPC). Treating of OPC with supercritical fluid carbon dioxide (SCCO{sub 2}) has been shown to significantly increase the density, while simultaneously decreasing porosity. In addition, the process significantly reduces the hydrogenous content, reducing the likelihood of radiolytic decomposition reactions. This, in turn, permits increased actinide loadings with a concomitant reduction in disposable waste volume. In this article, the authors discuss the combined use of fly-ash-modified OPC and its treatment with SCCO{sub 2} to further enhance immobilization properties. They begin with a brief summary of current cement immobilization technology in order to delineate the areas of concern. Next, supercritical fluids are described, as they relate to these areas of concern. In the subsequent section, they present an outline of results on the application of SCCO{sub 2} to OPC, and its effectiveness in addressing these problem areas. Lastly, in the final section, they proffer their thoughts on why they believe, based on the OPC results, that the incorporation of fly ash into OPC, followed by supercritical fluid treatment, can produce highly efficient wasteforms.

  1. Geopolymers based on the valorization of Municipal Solid Waste Incineration residues

    Science.gov (United States)

    Giro-Paloma, J.; Maldonado-Alameda, A.; Formosa, J.; Barbieri, L.; Chimenos, J. M.; Lancellotti, I.

    2017-10-01

    The proper management of Municipal Solid Waste (MSW) has become one of the main environmental commitments for developed countries due to the uncontrolled growth of waste caused by the consumption patterns of modern societies. Nowadays, municipal solid waste incineration (MSWI) is one of the most feasible solutions and it is estimated to increase in Europe where the accessibility of landfill is restricted. Bottom ash (BA) is the most significant by-product from MSWI as it accounts for 85 - 95 % of the solid product resulting from combustion, which is classified as a non-hazardous residue that can be revalorized as a secondary aggregate in road sub-base, bulk lightweight filler in construction. In this way, revalorization of weathered BA (WBA) for the production of geopolymers may be a good alternative to common reuse as secondary aggregate material; however, the chemical process to obtain these materials involves several challenges that could disturb the stability of the material, mainly from the environmental point of view. Accordingly, it is necessary that geopolymers are able to stabilize heavy metals contained in the WBA in order to be classified as non-hazardous materials. In this regard, the SiO2/Al2O3 ratio plays an important role for the encapsulation of heavy metals and other toxic elements. The aim of this research is to formulate geopolymers starting from the 0 - 2 mm particle size fraction of WBA, as a unique raw material used as aluminumsilicate precursor. Likewise, leaching tests of the geopolymers formulated were performed to assess their environmental impact. The findings show that it is possible to formulate geopolymers using 100 % WBA as precursor, although more investigations are needed to sustain that geopolymer obtained can be considered as non-hazardous materials.

  2. Incineration and co-combustion of waste: accounting of greenhouse gases and global warming contributions

    DEFF Research Database (Denmark)

    Astrup, Thomas; Møller, Jacob; Fruergaard, Thilde

    2009-01-01

    Important greenhouse gas (GHG) emissions related to waste incineration and co-combustion of waste were identified and considered relative to critical aspects such as: the contents of biogenic and fossil carbon, N2O emissions, fuel and material consumptions at the plants, energy recovery, and soli...

  3. Heat supply from municipal solid waste incineration plants in Japan: Current situation and future challenges.

    Science.gov (United States)

    Tabata, Tomohiro; Tsai, Peii

    2016-02-01

    The use of waste-to-energy technology as part of a municipal solid waste management strategy could reduce the use of fossil fuels and contribute to prevention of global warming. In this study, we examined current heat and electricity production by incineration plants in Japan for external use. Herein, we discuss specific challenges to the promotion of heat utilisation and future municipal solid waste management strategies. We conducted a questionnaire survey to determine the actual conditions of heat production by incineration plants. From the survey results, information of about 498 incineration plants was extracted. When we investigated the relationship between heat production for external use and population density where incineration plants were located, we found that regions with a population density energy for factories, markets, and related use, was noted in cities with a population density of 2000 to 4000 persons (km(2))(-1). Several incineration plants have poor performance for heat production because there are few facilities near them to provide demand for the energy. This is the result of redundant capacity, and is reflected in the heat production performance. Given these results, we discussed future challenges to creating energy demand around incineration plants where there is presently none. We also examined the challenges involved in increasing heat supply beyond the present situation. © The Author(s) 2015.

  4. Thermal and hydrometallurgical recovery methods of heavy metals from municipal solid waste fly ash

    Energy Technology Data Exchange (ETDEWEB)

    Kuboňová, L., E-mail: lenka.kubonova@vsb.cz [VSB – Technical University of Ostrava, 17. listopadu 15/2172, 708 33 Ostrava (Czech Republic); Langová, Š. [VSB – Technical University of Ostrava, 17. listopadu 15/2172, 708 33 Ostrava (Czech Republic); Nowak, B.; Winter, F. [Institute of Chemical Engineering, Vienna University of Technology, Getreidemarkt 9/166, A-1060 Vienna (Austria)

    2013-11-15

    Highlights: • MSW fly ash was thermally and hydrometallurgically treated to remove heavy metals. • More than 90% of easy volatile heavy metals (Cd and Pb) were removed thermally. • More than 90% of Cd, Cr, Cu an Zn were removed by alkaline – acid leaching. • The best results were obtained for the solution of 3 M NaOH and 2 M H{sub 2}SO{sub 4}. - Abstract: Heavy metals in fly ash from municipal solid waste incinerators are present in high concentrations. Therefore fly ash must be treated as a hazardous material. On the other hand, it may be a potential source of heavy metals. Zinc, lead, cadmium, and copper can be relatively easily removed during the thermal treatment of fly ash, e.g. in the form of chlorides. In return, wet extraction methods could provide promising results for these elements including chromium and nickel. The aim of this study was to investigate and compare thermal and hydrometallurgical treatment of municipal solid waste fly ash. Thermal treatment of fly ash was performed in a rotary reactor at temperatures between 950 and 1050 °C and in a muffle oven at temperatures from 500 to 1200 °C. The removal more than 90% was reached by easy volatile heavy metals such as cadmium and lead and also by copper, however at higher temperature in the muffle oven. The alkaline (sodium hydroxide) and acid (sulphuric acid) leaching of the fly ash was carried out while the influence of temperature, time, concentration, and liquid/solid ratio were investigated. The combination of alkaline-acidic leaching enhanced the removal of, namely, zinc, chromium and nickel.

  5. Life cycle assessment modelling of waste-to-energy incineration in Spain and Portugal.

    Science.gov (United States)

    Margallo, M; Aldaco, R; Irabien, A; Carrillo, V; Fischer, M; Bala, A; Fullana, P

    2014-06-01

    In recent years, waste management systems have been evaluated using a life cycle assessment (LCA) approach. A main shortcoming of prior studies was the focus on a mixture of waste with different characteristics. The estimation of emissions and consumptions associated with each waste fraction in these studies presented allocation problems. Waste-to-energy (WTE) incineration is a clear example in which municipal solid waste (MSW), comprising many types of materials, is processed to produce several outputs. This paper investigates an approach to better understand incineration processes in Spain and Portugal by applying a multi-input/output allocation model. The application of this model enabled predictions of WTE inputs and outputs, including the consumption of ancillary materials and combustibles, air emissions, solid wastes, and the energy produced during the combustion of each waste fraction. © The Author(s) 2014.

  6. A comparative study of PCDD/F emissions from medical and industrial waste incinerators in Medellin-Colombia (South America)

    Energy Technology Data Exchange (ETDEWEB)

    Aristizabal, B.; Montes, C.; Cobo, M. [Antioquia Univ., Medellin (Colombia); Abad, E.; Rivera, J. [CID-CSIC, Barcelona (Spain). Dept. of Ecotechnologies

    2004-09-15

    Municipal waste management often combines different strategies such as recycling, composting, thermal treatment or landfill disposal. In Colombia, urban solid waste is landfill disposed but, industrial and medical wastes are incinerated. The total medical and pathological wastes generated in this zone are about 1643 ton/year from which 1022 ton/year are incinerated in six plants operating in Medellin metropolitan area. As a result, new regulations governing stack gas emissions have been enforced with the aim of reducing air pollutant emissions. Few incinerators are equipped with a gas-cleaning system and thus, most do not have any cleaning system. Medical waste incineration has been recognized as one of the major known sources of polychlorinated dibenzo-pdioxins and polychlorinated dibenzofurans (PCDD/PCDF). To the best of our knowledge, there are not reports about emissions of dioxins and furans from the incineration sector in Colombia. The first aim of this work was to evaluate PCDD/PCDF emissions from the largest incinerators operating in Medellin (Colombia). In this contribution we report results obtained from three incinerators (A, B and C). The incinerated waste in plant A consisted of polymerization sludge, whereas in plants B and C medical and pathological residues were incinerated. Common medical wastes include dirty bandages, culture dishes, plastic, surgical gloves and instruments (including needles) as well as human tissue.

  7. Environmental assessment of waste incineration in a life-cycle-perspective (EASEWASTE)

    DEFF Research Database (Denmark)

    Riber, Christian; Bhander, Gurbakhash Singh; Christensen, Thomas Højlund

    2008-01-01

    is a module in the life-cycle assessment model EASEWASTE. The module accounts for all uses of materials and energy and credits the incinerator for electricity and heat recovered. The energy recovered is defined by the user as a percentage of the energy produced, calculated on the lower heating value......A model for life-cycle assessment of waste incinerators is described and applied to a case study for illustrative purposes. As life-cycle thinking becomes more integrated into waste management, quantitative tools for assessing waste management technologies are needed. The presented model...... is defined by 48 material fractions and their chemical composition. The model was used to quantify the environmental performance of the incineration plant in Aarhus, Denmark before and after its upgrading in terms of improved flue gas cleaning and energy recovery. It demonstrated its usefulness...

  8. Is One Village able to Produce as Many Dioxins as a Big Waste Incineration Plant?

    Directory of Open Access Journals (Sweden)

    Jiří HORÁK

    2011-06-01

    Full Text Available Three large waste incineration plants incinerated c. 360 thousand tons of waste in 2009, during which time they emitted c. 40 mg of PCDD/F expressed as TEQ in flue gasses into the air. If heated by solid fuels only (c. 4 thousand tons of fuel, one average (hypothetical village with two thousand inhabitants would emit c. 2 to 60 mg of PCDD/F expressed as TEQ in flue gasses into the air during the heating season. We can state that in term of PCDD/F emissions into the air, one village being heated with solid fuels has a potential to produce similar (in some cases even higher amount of diox-ins as a large waste incineration plant.

  9. Envirotoxins from waste incineration - how does the supervision work?; Miljoegifter fraan avfallsfoerbraenningen - hur fungerar tillsynen?

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2005-02-01

    Incineration of household wastes has increased rapidly in Sweden during the last few years, and new plants are being built. The volume of residues from waste incineration is expected to grow from 450,000 tons in 1999 to 1,100,000 tons in 2008. The National Audit Office (SNAO) has made an inquiry into the supervision by responsible authorities of incineration plants and landfills in order to how the environmental legislation is applied in practise. The investigation includes case studies of six incineration plants and seven landfills where the residues from the plants are disposed. The supervision is part of a complex system made up of state, local and private actors who all have a responsibility for applying the environmental legislation. SNAO has found serious shortcomings in the operational supervision of all incineration plants studied and several landfills concerning the risk of toxins leaching into the environment. SNAO also points at the lack of knowledge at the Swedish EPA regarding the potential environmental problems of incineration residues and the need for evaluation of the supervisory function. SNAO recommends that the government take an initiative for making more detailed demands in the environmental legislation, and that the Swedish EPA should improve its knowledge about the quality of the operational supervision in accordance with the legislation.

  10. Mixed-waste treatment -- What about the residuals? A comparative analysis of MSO and incineration

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1993-06-01

    This report examines the issues concerning final waste forms, or residuals, that result from the treatment of mixed waste in molten salt oxidation (MSO) and incinerator systems. MSO is a technology with the potential to treat a certain segment of the waste streams at US Department of Energy (DOE) sites. MSO was compared with incineration because incineration is the best demonstrated available technology (BDAT) for the same waste streams. The Grand Junction Projects Office (GJPO) and Oak Ridge National Laboratory (ORNL) prepared this report for the DOE Office of Environmental Restoration (OER). The goals of this study are to objectively evaluate the anticipated residuals from MSO and incineration, examine regulatory issues for these final waste forms, and determine secondary treatment options. This report, developed to address concerns that MSO residuals present unique disposal difficulties, is part of a larger effort to successfully implement MSO as a treatment technology for mixed and hazardous waste. A Peer Review Panel reviewed the MSO technology in November 1991, and the implementation effort is ongoing under the guidance of the MSO Task Force.

  11. Waste incineration on its way to the power plants; Muellverbrennung auf dem Weg zum Kraftwerk

    Energy Technology Data Exchange (ETDEWEB)

    Reich, J. [STEAG encotec GmbH, Essen (Germany); Neukirchen, B. [STEAG AG, Essen (Germany)

    2004-07-01

    Looking at the year 2005 and the end of disposal of untreated domestic waste the politic hopes that the prognosticated lack of waste treatment capacity is remedied by coal-fired power plants. The classical municipal waste incinerators by contrast want to get recognition as energetic recycler in comparison with power stations. The decision of the European Court of Justice concerning recycling and disposal of domestic waste by incineration has started the discussion and competition on fuel-rich commercial waste. Are municipal waste incineration plants power stations or must power plants be regarded as incinerators? These questions are still open. (orig.) [German] Mit Blick auf das Jahr 2005 und das Ende der Ablagerung von unbehandeltem Siedlungsabfall hofft die Politik, dass der prognostizierte Mangel an Vorbehandlungskapazitaeten von den Kohlekraftwerken behoben wird. Die klassischen Muellverbrennungsanlagen wollen dagegen mit dem Kraftwerksvergleich die Anerkennung als energetische Verwerter erreichen. Das EuGH-Urteil zur Verwertung oder Beseitigung von Siedlungsabfall durch Verbrennen hat in diesem Jahr die Diskussion und den Kampf um den heizwertreichen Gewerbeabfall angeheizt. Die Frage, wie weit in Zukunft die Muellverbrennungsanlagen als Kraftwerke, aber auch die Kraftwerke als Muellverbrennungsanlagen angesehen werden muessen, ist noch offen. (orig.)

  12. Field Investigation of Various Weld Overlays in a Waste Incineration Plant

    DEFF Research Database (Denmark)

    Montgomery, Melanie; Larsen, O. H.

    2005-01-01

    . In addition to the test waterwall exposure, the chemical environment from the waste incineration was also monitored by analyzing deposits and corrosion products from various locations in the boiler. These were analyzed with respect to morphology and composition using electron microscopy with EDS analysis......A test waterwall was fabricated so that alternatives to alloy 625 could be exposed in the first pass of the waste incineration plant Haderslev. The difference between application method was also a parameter, such that manual welding, machine welding and arc spraycoating of alloy 625 were compared...

  13. Incineration and inertization of industrial wastes. Incineracion e inertizacion de residuos industriales

    Energy Technology Data Exchange (ETDEWEB)

    Fernandez Rubio, R.

    1994-01-01

    The author provides information on the incineration plant from Merex (France). The plant investment cost was 200 million Francs. It has a capacity of treatment of 60.000 T/year. It deals with liquid and solid wastes produced by refineries, oil industry, fine chemistry and other. The incineration process takes places in a rotary kiln at 1000 degree centigree. Off-gases are subjected to a post-combustion treatment at 1200 degree centigree. Inertization of the final solid waste is treated with the ECOFIX process.

  14. Organic household waste - incineration or recycling; Skal husholdningernes madaffald braendes eller genanvendes? Samfundsoekonomisk analyse af oeget genanvendelse af organisk dagrenovation

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2003-07-01

    The Danish Environmental Protection Agency has carried out a cost benefit analysis of the consequences of increasing recycling of organic household waste. In the cost benefit analysis both the economic consequences for the affected parties and the welfare-economic consequences for the society as a whole have been investigated. In the welfare-economic analysis the value of the environmental effects has been included. The analysis shows that it is more expensive for the society to recycle organic household waste by anaerobic digestion or central composting than by incineration. Incineration is the cheapest solution for the society, while central composting is the most expensive. Furthermore, technical studies have shown that there are only small environmental benefits connected with anaerobic digestion of organic waste compared with incineration of the waste. The primary reason for recycling being more expensive than incineration is the necessary, but cost-intensive, dual collection of the household waste. Treatment itself is cheaper for recycling compared to incinerating. (BA)

  15. Phosphorus recovery and leaching of trace elements from incinerated sewage sludge ash (ISSA).

    Science.gov (United States)

    Fang, Le; Li, Jiang-Shan; Guo, Ming Zhi; Cheeseman, C R; Tsang, Daniel C W; Donatello, Shane; Poon, Chi Sun

    2017-11-08

    Chemical extraction of phosphorus (P) from incinerated sewage sludge ash (ISSA) is adversely influenced by co-dissolution of metals and metalloids. This study investigated P recovery and leaching of Zn, Cu, Pb, As and Ni from ISSA using inorganic acids (sulphuric acid and nitric acid), organic acids (oxalic acid and citric acid), and chelating agents (ethylenediaminetetraacetic acid (EDTA) and ethylene diamine tetramethylene phosphonate (EDTMP)). The aim of this study was to optimize a leaching process to recover P-leachate with high purity for P fertilizer production. The results show that both organic and inorganic acids extract P-containing phases but organic acids leach more trace elements, particularly Cu, Zn, Pb and As. Sulphuric acid was the most efficient for P recovery and achieved 94% of total extraction under the optimal conditions, which were 2-h reaction with 0.2 mol/L H2SO4 at a liquid-to-solid ratio of 20:1. EDTA extracted only 20% of the available P, but the leachates were contaminated with high levels of trace elements under optimum conditions (3-h reaction with EDTA at 0.02 mol/L, pH 2, and liquid-to-solid ratio of 20:1). Therefore, EDTA was considered an appropriate pre-treatment agent for reducing the total metal/metalloid content in ISSA, which produced negligible changes in the structure of ISSA and reduced contamination during subsequent P extraction using sulphuric acid. Copyright © 2017 Elsevier Ltd. All rights reserved.

  16. Domestic wastes incineration in France situation in 2000 evolution and perspectives the 31.12.2002; Incineration des dechets menagers en France situation en 2000 evolution et perspectives au 31.12.2002

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2003-07-01

    This document presents the analysis and the conclusions of a working group, concerning the domestic wastes incineration. It presents successively the place of the domestic wastes in the wastes management approach, the regulations, the methodology and the corresponding results of an inquiry realized in 2000 and the research programs on the incineration as the Best Available Techniques, the sanitary impacts of the UIOM (domestic wastes incineration plants), the vitrification, the greenhouse effect. (A.L.B.)

  17. Waste incineration within the Swedish district heating systems - Sub-Project 4; Avfallsfoerbraenning inom Sveriges fjaerrvaermesystem - Delprojekt 4 inom projektet Perspektiv paa framtida avfallsbehandling

    Energy Technology Data Exchange (ETDEWEB)

    Haraldsson, Maarten; Holmstroem; David

    2012-07-01

    Waste incineration within the Swedish district heating systems is one of the five sub-projects within the project Perspectives on sustainable waste treatment. The goal of this project is to evaluate the economic potential for waste incineration in the Swedish district heating systems. With the current expansion of incineration, we may relatively soon reach an upper limit for what is demanded by the Swedish district heating systems. How much more waste incineration that is economically attractive to build is of great importance for the development of the Swedish waste system, not least for the alternatives to incineration as for example biogas production. With continued rising quantities of waste and stagnant demand for waste incineration from the district heating systems, today's surplus of treatment capacity may change the market picture for other waste treatment options. How much more waste incineration requested and how quickly the market reaches this level is studied in this project.

  18. Life-cycle assessment (EASEWASTE) of two municipal solid waste incineration technologies in China.

    Science.gov (United States)

    Chen, Dezhen; Christensen, Thomas H

    2010-06-01

    The environmental profile of two municipal solid waste incineration (MSWI) technologies with semi-dry flue gas cleaning, namely grated firing incinerators (GFI) and fluidised bed incinerators (FBI) that are commonly used in China were evaluated and compared by life-cycle assessment (LCA) using the EASEWASTE model. All emissions of key pollutants as well as energy, resource and material inputs and outputs associated with the two MSWI technologies were determined and the corresponding environmental impact potentials were modelled. Incineration of MSW with a lower heating value (LHV) around 4.5 MJ kg(-1) demands that auxiliary fuel is used, and both GFI and FBI caused environmental loads by contributing with environmental impact potentials in most categories except for some saving in global warming (GW100) and hazardous waste (HW). Coal combustion in FBI is a main contributor to the environmental impact potentials and thus should always be limited to a minimum. Auxiliary fuels can be avoided when the LHV of MSW is higher than 5-6 MJ kg(- 1). For all scenarios, GFI saves more global warming potentials than FBI due to its higher net power generation from combustion of MSW itself. Leachate from the bunker could be sprayed into the furnace for evaporation under high temperature, as an alternative to waste-water treatment, without major changes in the environmental profile of the incinerator. The presented evaluations may contribute to a more balanced environmental assessment of the two incineration technologies with respect to incineration of MSW with low heating values as often found in Asia and China.

  19. Waste management concept for charged activated coke from the after-cleaning of flue gas with reference to the sintering of fly ash. Entsorgungskonzepte fuer beladenen Aktivkoks aus der Rauchgasnachreinigung unter Einbeziehung der Verschlackung von Flugasche

    Energy Technology Data Exchange (ETDEWEB)

    Goerner, K. (Babcock Feuerungssysteme GmbH (BFS), Oberhausen (Germany))

    1993-11-01

    The new limits prescribed by the 17th BImSchV (regulation) are causing particular difficulties, especially for waste incineration plant. Furnace bottom ash and fly ash from waste incineration plants will be capable of being improved on account of their high heavy metal content in the future only by a thermal after-treatment in the elution process on account of this constituent material. It has been possible in waste incineration plants to utilise the resulting charged activate coke as an auxiliary fuel necessary for this and a sensible waste management route can be constructed for both problem materials, both from the point of view of utilization of material and from the point of view of energy production. (orig.)

  20. Construction demolition wastes, Waelz slag and MSWI bottom ash: a comparative technical analysis as material for road construction.

    Science.gov (United States)

    Vegas, I; Ibañez, J A; San José, J T; Urzelai, A

    2008-01-01

    The objective of the study is to analyze the technical suitability of using secondary materials from three waste flows (construction and demolition waste (CDW), Waelz slag and municipal solid waste incineration (MSWI) bottom ash), under the regulations and standards governing the use of materials for road construction. A detailed technical characterization of the materials was carried out according to Spanish General Technical Specifications for Road Construction (PG3). The results show that Waelz slag can be adequate for using in granular structural layers, while CDW fits better as granular material in roadbeds. Likewise, fresh MSWI bottom ash can be used as roadbed material as long as it does not contain a high concentration of soluble salts. This paper also discusses the adequacy of using certain traditional test methods for natural soils when characterizing secondary materials for use as aggregates in road construction.

  1. Design of multifunctional floating waste incineration plant. Umi ni ukabu takinogata yojo seisokojo wo koan

    Energy Technology Data Exchange (ETDEWEB)

    Kodama, T. (Shimizu Corp., Tokyo (Japan))

    1991-11-01

    A multifunctional floating waste incineration plant (aqua- amusement land: AAL) with combined health and leisure facilities is designed which can be built in much less time than the conventional plant and can be freely enlarged. The concepts for the AAL are the docking of water park and marine facilities to the floating waste incineration plant high degree reutilization of space materials and energy solving problems of high cost of land and traffic jam at the incineration plant due to environmental problem high price of land and overpopulation of cities. At the facility several waste disposal plant units are integrated various leisure facilities ocean culture facilities etc. are provided in two stages of upper and lower floors and exhaust heat generated by waste incineration is utilized effectively as the power source heat source etc. The feature of the AAL are solving land shortage problem shortening the term of works no necessity for submarine ground improvement flexibility of locational conditions high efficient use of exhaust heat flexibility of throughput performance possibility of marine transportation of wastes etc. 8 refs.

  2. Estimation of CO2 emissions from waste incinerators: Comparison of three methods.

    Science.gov (United States)

    Lee, Hyeyoung; Yi, Seung-Muk; Holsen, Thomas M; Seo, Yong-Seok; Choi, Eunhwa

    2017-12-05

    Climate-relevant CO2 emissions from waste incineration were compared using three methods: making use of CO2 concentration data, converting O2 concentration and waste characteristic data, and using a mass balance method following Intergovernmental Panel on Climate Change (IPCC) guidelines. For the first two methods, CO2 and O2 concentrations were measured continuously from 24 to 86 days. The O2 conversion method in comparison to the direct CO2 measurement method had a 4.8% mean difference in daily CO2 emissions for four incinerators where analyzed waste composition data were available. However, the IPCC method had a higher difference of 13% relative to the direct CO2 measurement method. For three incinerators using designed values for waste composition, the O2 conversion and IPCC methods in comparison to the direct CO2 measurement method had mean differences of 7.5% and 89%, respectively. Therefore, the use of O2 concentration data measured for monitoring air pollutant emissions is an effective method for estimating CO2 emissions resulting from waste incineration. Copyright © 2017 Elsevier Ltd. All rights reserved.

  3. Improved electrical efficiency and bottom ash quality on waste combustion plants. Appendix A11 to A14

    Energy Technology Data Exchange (ETDEWEB)

    Hedegaard Madsen, O.; Boejer, M.; Jensen, Peter A.; Dam-Johansen, K.; Lundtorp, K. (Technical Univ. of Denmark, Kgs. Lyngby (Denmark)); Mogensen, Erhardt (Babcock and Wilcox Voelund A/S, Glostrup (Denmark))

    2010-07-01

    Investigations making it possible to evaluate and further develop concepts to improve electrical efficiency in a waste combustion plant were performed. Furthermore, one objective of the study was to investigate the possibilities of improving waste bottom ash leaching properties by use of a rotary kiln treatment. The project work included construction of a bench-scale rotary kiln, performing ash rotary kiln treatment experiments, conducting gas suction probe measurements on a waste incineration plant and making some concept evaluations. The influence of the rotary kiln thermal treatment on the leaching of Ca, Al, Si, Mg, Ba, Sr, Cl, Cu, Pb, Zn, Cr, Mo, sulfate, DOC and carbonate was determined. As a result of these tests, the rotary kiln thermal treatment of bottom ashes can be recommended for reducing the leaching of Cu, Pb, Cl, Zn and DOC; however, an increased leaching of Cr and Mo should be expected. The combustion conditions above the grate of a waste incineration plant were investigated and the release and concentration of volatile ash species in the flue gas such as Cl, Na, K, Ca, Pb, Zn and S were measured. The conducted measurements show that flue gas from grate sections 3 and 4 can produce a sufficiently hot flue gas that contains only low concentrations of corrosive species, and therefore can be used to increase superheater temperatures. Implementation of the so-called flue gas split concept together with other steam circle modifications on a waste combustion plant, and using a reasonable increase in final steam temperature from 400 to 500 deg. C, have the potential to increase electrical efficiency from 24 to 30% (with respect to lower fuel heating value) in a waste combustion plant. The appendices deal with electrical efficiency by dividing the combustion products; release of potentially corrosive constituents from the grate; CFD modeling of grate with and without vertical divider. (Author)

  4. ON THE RELATIONSHIP BETWEEN CO, POHC, AND PIC EMISSIONS FROM A SIMULATED HAZARDOUS WASTE INCINERATOR

    Science.gov (United States)

    Measurements conducted on full-scale hazardous waste incinerators have occasionally shown a relationship between carbon monoxide (CO) emissions and emissions of toxic organic compounds. In this study, four mixtures of chlorinated C1 and C2 hydrocarbons were diluted in commercial...

  5. Design, operation and management of waste incinerators; Design, Betrieb und Management von Muellverbrennungsanlagen

    Energy Technology Data Exchange (ETDEWEB)

    Schmidt, U.; Swithenbank, J.; Nasserzadeh, V.; Ewan, B.; Lee, P.H. [Sheffield Univ. (United Kingdom). Waste Incineration Centre; Lawrence, D.; Garrod, N.P. [Sheffield Heat and Power Ltd. (United Kingdom); Jones, B.; Sykes, G. [Sheffield Incinerator Plant (United Kingdom); Bernet, U. [Electrowatt Engineering Ltd. (Switzerland)

    1998-09-01

    Design of combustion chambers for solid residues combution is hampered by the non-existence of accurate mathematical models of the combustion process, so that semi-empirical correlations must be used. Modern flow simulation programs (computational fluid dynamics), on the other hand, offer the pssibility of predicting flow in the gaseous phase although further tests are still required for validation. Since experiments on a laboratory scale hardly ever provide reliable data material, research in the field of waste incineration must make tests on industrial-scale systems. For this reason, the Sheffield University Waste Incineration Centre (SUWIC) cooperated with Sheffield Heat and Power Ltd and was therefore able to carry out extensive research at the Bernard Road waste incinerator in Sheffield. (orig./SR) [Deutsch] Die Konstruktion von Feueraeumen zur Feststoffverbrennung wird dadurch behindert, dass kein genaues mathematisches Modell fuer den Verbrennungsprozess existiert. Statt dessen muss noch immer auf halb-empirische Korrelationen zurueckgegriffen werden. Aufgrund moderner Stroemungssimulationsprogramme (Computational Fluid Dynamics) ist hingegen die Vorhersage des Stroemungsverhaltens der Gasphase in Verbrennungsanlagen weiter entwickelt, obwohl zusaetzliche Tests zur Validierung noch erforderlich sind. Da Versuche im Testmassstab selten verlaessliches Datenmaterial liefern, ist die Forschung im Bereich der Muellverbrennung auf Tests an Grossanlagen angewiesen. Dank der guten Beziehungen zu Sheffield Heat and Power Ltd hat Sheffield University Waste Incineration Centre (SUWIC) an der Bernard Road Muellverbrennungsanlage in Sheffield ein umfangreiches Forchungsprogramm durchfuehren koennen. (orig./SR)

  6. Ultrafine particle emission of waste incinerators and comparison to the exposure of urban citizens.

    Science.gov (United States)

    Buonanno, Giorgio; Morawska, Lidia

    2015-03-01

    On the basis of the growing interest on the impact of airborne particles on human exposure as well as the strong debate in Western countries on the emissions of waste incinerators, this work reviewed existing literature to: (i) show the emission factors of ultrafine particles (particles with a diameter less than 100 nm) of waste incinerators; and (ii) assess the contribution of waste incinerators in terms of ultrafine particles to exposure and dose of people living in the surrounding areas of the plants in order to estimate eventual risks. The review identified only a limited number of studies measuring ultrafine particle emissions, and in general they report low particle number concentrations at the stack (the median value was equal to 5.5×10(3) part cm(-3)), in most cases higher than the outdoor background value. The lowest emissions were achieved by utilization of the bag-house filter which has an overall number-based filtration efficiency higher than 99%. Referring to reference case, the corresponding emission factor is equal to 9.1×10(12) part min(-1), that is lower than one single high-duty vehicle. Since the higher particle number concentrations found in the most contributing microenvironments to the exposure (indoor home, transportation, urban outdoor), the contribution of the waste incinerators to the daily dose can be considered as negligible. Copyright © 2014 Elsevier Ltd. All rights reserved.

  7. Life cycle assessment of waste incineration in Denmark and Italy using two LCA models

    DEFF Research Database (Denmark)

    Turconi, Roberto; Butera, Stefania; Boldrin, Alessio

    2011-01-01

    . Differences in waste composition between the two countries mainly affected global warming and human toxicity via water. Overall, SimaPro and EASEWASTE provided consistent ranking of the individual scenarios. However, important differences in results from the two models were related to differences...... in the databases and modelling approaches, in particular the possibility for modelling of waste-specific emissions affected the toxicity-related impact categories. The results clearly showed that the use of site-specific data was essential for the results.......In Europe, about 20% of municipal solid waste is incinerated. Large differences can be found between northern and southern Europe regarding energy recovery efficiencies, flue gas cleaning technologies and residue management. Life-cycle assessment (LCA) of waste incineration often provides...

  8. In situ corrosion testing of various nickel alloys at Måbjerg waste incineration plant

    DEFF Research Database (Denmark)

    Montgomery, Melanie; Hansson, A. N.; Jensen, S. A.

    2013-01-01

    The majority of waste in Denmark is disposed via waste to energy (WTE) incineration plants which are fabricated from carbon steel. However, due to the increasing corrosiveness of waste over the years, more corrosion resistant alloys are required. In Denmark, Inconel 625 (UNSN06625) is the weld...... overlay material currently being used to give improved corrosion resistance. In order to assess the use of alternative nickel alloys, test panels have been manufactured and inserted into Måbjerg waste incineration plant. Inconel 625 as a 50% weld overlay, two layered weld overlay and as a spiral weld....... The composition of the deposits from the exposed waterwall panels was also analysed each time sections were removed. This paper will compare the various nickel alloys in the two areas and assess the results of the long‐term testing project....

  9. RICE-HUSK ASH-CARBIDE-WASTE STABILIZATION OF ...

    African Journals Online (AJOL)

    This paper present results of the laboratory evaluation of the characteristics of carbide waste and rice husk ash stabilized reclaimed asphalt pavement waste with a view to determine its suitability for use as flexible pavement material. The mixtures were subjected to British Standard heavy compactive effort to determine the ...

  10. Municipal waste incineration and emissions trading; Die Einbeziehung von Siedlungsabfallverbrennungsanlagen in den Emissionsrechtehandel

    Energy Technology Data Exchange (ETDEWEB)

    Treder, Martin [ITAD und VKU (Germany). AG Klimaschutz und Abfallwirtschaft

    2011-11-15

    The task of energetic waste recovery is the disposal of nonrecyclable waste in an environmentally sound way, while recovering as much of the energetic content as possible. The objective therefore is to reach a complete combustion of the biogenic and fossil carbon, thus transforming it into carbon dioxide. Hence the amount of greenhouse gas emitted solely depends on the amount and type of waste incinerated. Taking into account the climate neutrality of the biogenic fraction and the fossil fuels substituted, the German WtE-plants are contributing to climate protection by relieving it of a burden of around 4 billion each year. For these reasons municipal waste incineration plants are not included in the emissions trading scheme. Since the term 'municipal waste' is not defined within the acts, it is vital to settle for an interpretation including all wastes stemming from municipal wastes. Otherwise plants accepting presorted or conditioned municipal waste are prone to an inclusion in the emissions trading scheme. This would not only cause costs for the emission allowances without any sensible steering effects, but also face the operator with numerous reporting-, measuring and sampling obligations. This would lead to shifts in waste mass flows but also cause waste fees to increase. (orig.)

  11. Possibilities of mercury removal in the dry flue gas cleaning lines of solid waste incineration units.

    Science.gov (United States)

    Svoboda, Karel; Hartman, Miloslav; Šyc, Michal; Pohořelý, Michael; Kameníková, Petra; Jeremiáš, Michal; Durda, Tomáš

    2016-01-15

    Dry methods of the flue gas cleaning (for HCl and SO2 removal) are useful particularly in smaller solid waste incineration units. The amount and forms of mercury emissions depend on waste (fuel) composition, content of mercury and chlorine and on the entire process of the flue gas cleaning. In the case of high HCl/total Hg molar ratio in the flue gas, the majority (usually 70-90%) of mercury is present in the form of HgCl2 and a smaller amount in the form of mercury vapors at higher temperatures. Removal of both main forms of mercury from the flue gas is dependent on chemical reactions and sorption processes at the temperatures below approx. 340 °C. Significant part of HgCl2 and a small part of elemental Hg vapors can be adsorbed on fly ash and solid particle in the air pollution control (APC) processes, which are removed in dust filters. Injection of non-impregnated active carbon (AC) or activated lignite coke particles is able to remove mainly the oxidized Hg(2+) compounds. Vapors of metallic Hg(o) are adsorbed relatively weakly. Much better chemisorption of Hg(o) together with higher sorbent capacity is achieved by AC-based sorbents impregnated with sulfur, alkali poly-sulfides, ferric chloride, etc. Inorganic sorbents with the same or similar chemical impregnation are also applicable for deeper Hg(o) removal (over 85%). SCR catalysts convert part of Hg(o) into oxidized compounds (HgO, HgCl2, etc.) contributing to more efficient Hg removal, but excess of NH3 has a negative effect. Both forms, elemental Hg(o) and HgCl2, can be converted into HgS particles by reacting with droplets/aerosol of poly-sulfides solutions/solids in flue gas. Mercury captured in the form of water insoluble HgS is more advantageous in the disposal of solid waste from APC processes. Four selected options of the dry flue gas cleaning with mercury removal are analyzed, assessed and compared (in terms of efficiency of Hg-emission reduction and costs) with wet methods and retrofits for more

  12. Investigation of Dioxin formation- and destruction mechanisms in waste incineration plants in order to improve the quality of the residues. Phase 2 and 3

    Energy Technology Data Exchange (ETDEWEB)

    Joergensen, Jan; Dahl, J.; Akoh Hove, E. (FORCE Technology, Kgs. Lyngby (Denmark)); Baun, D.L.; Hulgaard, T. (Ramboell, Copenhagen (Denmark)); Marklund, S. (Umeaa Univ., Umeaa (Sweden)); Astrup, T. (Technical Univ. of Denmark. Dept. of Environmental Engineering, Kgs. Lyngby (Denmark)); Lundtorp, K. (Babcock and Wilcox Voelund, Esbjerg (Denmark))

    2009-11-15

    The aim of this project was to produce a theory and a model for the formation of dioxin suitable for prediction of dioxin formation in flue gas, based on experiments conducted at Umeaa University. Furthermore the model should be tested using data from another project, where measurements on the FASAN waste incineration plant has been carried out. A theory has been proposed and a model has been programmed and implemented into the FLUENT CFD software package. The predictions show qualitative and quantitative correlation between the model and the Umeaa test reactor. When the developed model was implemented on the full scale plant, it was however not possible to obtain a quantitative correlation between the model results and the measurements of dioxins in ash samples. There was however a reasonable qualitative correlation. The model needs further work to produce better quantitative results for full scale plants. This work must focus more on full scale measurements, in order to obtain good data for tuning and comparison. It is also recommended to do some work on a more basic level at the Umeaa test reactor to tune the more basic echanisms in the model. The model shows a very small region in the full scale boiler where the vast majority of the dioxin formation takes place. This knowledge is useful as it can point to uncontaminated ash fractions in waste incineration plants. The discovery of a small region where dioxin formation takes place is also an inspiration for potential future evelopments in boiler design for minimizing dioxin formation. Dioxin measurements in ash samples from the full scale test runs show dioxin levels in the same order of magnitude for all experiments with minor differences between the various experiments. This indicates that changes in waste input within the range of products tested is likely to have limited effect on dioxin formation in the boiler, and hence the dioxin content of fly ash and flue gas upstream the flue gas treatment system. (LN)

  13. Environmental impacts and costs of solid waste: a comparison of landfill and incineration.

    Science.gov (United States)

    Rabl, Ari; Spadaro, Joseph V; Zoughaib, Assaad

    2008-04-01

    The methodology for evaluating the impacts and damage costs ('external costs') due to pollution from waste treatment is described and the results are presented, based on the ExternE project series of the European Commission. The damage costs of landfill and incineration of municipal solid waste are compared, with due account for energy and materials recovery, as well as possible differences in transport distance. We have not been able to quantify the total damage costs of leachates because of the complexity of the environmental pathways and of the long time horizon of some persistent pollutants, but we consider an extreme scenario to show that they are not worth worrying about in the sense that reducing the pollutants in leachates beyond current regulations would bring negligible benefit in comparison with the abatement of other sources of the same pollutants. The damage costs due to the construction of the waste treatment facility are negligible. The damage costs of waste transport, which are illustrated by an arbitrary choice of a 100 km round trip by a 16 tonne truck, are also negligible. The benefits of materials recovery make a small contribution to the total damage cost. The only significant contributions come from direct emissions (of the landfill or incinerator) and from avoided emissions due to energy recovery (from an incinerator). Damage costs for incineration range from about 4 to 21 EUR tonne waste(-1), and they are extremely dependent on the assumed scenario for energy recovery. For landfill the cost ranges from about 10 to 13 EUR tonne waste(-1); it is dominated by greenhouse gas emissions because only a fraction of the CH4 can be captured (here assumed to be 70%). Amenity costs (odour, visual impact, noise) are highly site-specific and we only cite results from a literature survey which indicates that such costs could make a significant contribution, very roughly on the order of 1 EUR tonne waste(-1).

  14. Assessing recycling versus incineration of key materials in municipal waste: The importance of efficient energy recovery and transport distances

    DEFF Research Database (Denmark)

    Merrild, Hanna; Larsen, Anna W.; Christensen, Thomas H.

    2012-01-01

    that there are environmental benefits when recycling paper, glass, steel and aluminium instead of incinerating it. For cardboard and plastic the results were more unclear, depending on the level of energy recovery at the incineration plant, the system boundaries chosen and which impact category was in focus. Further......Recycling of materials from municipal solid waste is commonly considered to be superior to any other waste treatment alternative. For the material fractions with a significant energy content this might not be the case if the treatment alternative is a waste-to-energy plant with high energy recovery...... rates. The environmental impacts from recycling and from incineration of six material fractions in household waste have been compared through life cycle assessment assuming high-performance technologies for material recycling as well as for waste incineration. The results showed...

  15. Regular Recycling of Wood Ash to Prevent Waste Production (RecAsh). Technical Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Andersson, Lars E-mail: lars.t.andersson@skogsstyreslen.se

    2007-03-15

    At present, the extraction of harvest residues is predicted to increase in Sweden and Finland. As an effect of the intensified harvesting, the export of nutrients and acid buffering substances from the growth site is also increased. Wood ash could be used to compensate forest soils for such losses. Most wood fuel ash is today often deposited in landfills. If the wood ash is recycled, wood energy is produced without any significant waste production. Ash recycling would therefore contribute to decreasing the production of waste, and to maintaining the chemical quality of forest waters and biological productivity of forest soils in the long term. The project has developed, analysed and demonstrated two regular ash-recycling systems. It has also distributed knowledge gathered about motives for ash recycling as well as technical and administrative solutions through a range of media (handbooks, workshops, field demonstrations, reports, web page and information videos). Hopefully, the project will contribute to decreasing waste problems related to bio-energy production in the EU at large. The project has been organised as a separate structure at the beneficiary and divided in four geographically defined subprojects, one in Finland and three in Sweden (Central Sweden, Northern Sweden, and South-western Sweden). The work in each subproject has been lead by a subproject leader. Each subproject has organised a regional reference group. A project steering committee has been established consisting of senior officials from all concerned partners. The project had nine main tasks with the following main expected deliverables and output: 1. Development of two complete full-scale ash-recycling systems; 2. Production of handbooks of the ash recycling system; 3. Ash classification study to support national actions for recommendations; 4. Organise regional demonstrations of various technical options for ash treatment and spreading; 5. Organise national seminars and demonstrations of

  16. Research paper 2000-B-8: the implementation of the municipal waste incineration directives

    Energy Technology Data Exchange (ETDEWEB)

    Lulofs, K. [Twente Univ., Center for Clean Technology and Environmental Policy, Enschede (Netherlands)

    2000-07-01

    End-of-pipe options are needed whenever recycling and source reduction can not cope with waste streams at acceptable costs. One of the disposal options is waste incineration. The incineration of waste was considered 'clean' for a long time. In the 1970's and 1980's it proved that the incineration of municipal waste was a significant source of air pollution. Notorious pollutants were hydrogen chloride, hydrogen florid, sulphur dioxide, oxides of nitrogen, fine particulate matter, 'heavy metals' and dioxines and furans. Most notorious and issue of public anxiety in some countries were emissions of dioxines and that might cause cancer and birth defects. Municipal waste is domestic waste from households and comparable waste from markets and companies. Consent is present that in the long history of waste incinerators, incineration in plants started in Europe around 1900, important steps to secure health and the environment have been taken and will be taken in the future. Debates are still going on the level of emissions that is negligible and acceptable. Also in the European arena waste management is about knowledge, perceptions, uncertainties and negotiations. Arguments are on the right level of ambition and the right level of fine-tuning where precautionary measures are discussed. The European Union decided to issue two European Directives on the atmospheric emissions from municipal waste incineration in 1989. This chapter focuses on the implementation and effects of the 1989 Directives. In section 2 of this chapter we summarize the bargaining on the 1989 European Directives. Section 2 indicates that characteristics of municipal waste incineration and the level of pre-existing national regulation sectors in individual member states played decisive roles. When the 1989 Directives came into force, the requirements had to be integrated in the national legislation in European Member States. In section 3 Germany and the Netherlands will prove

  17. Modeling the dioxin emission of a municipal solid waste incinerator using neural networks.

    Science.gov (United States)

    Bunsan, Sond; Chen, Wei-Yea; Chen, Ho-Wen; Chuang, Yen Hsun; Grisdanurak, Nurak

    2013-07-01

    Incineration is considered as an efficient approach in dealing with the increasing demand for municipal and industrial solid waste treatment, especially in areas without sufficient land resources. Facing the concern of health risk, the toxic pollutants emitted from incinerators have attracted much attention from environmentalists, even though this technology is capable of reducing solid waste volume and demand for landfill areas, together with plenty of energy generation. To reduce the negative impacts of toxic chemicals emitted from incinerators, various monitoring and control plans are made not only for use in facilities performance evaluation but also better control of operation for stable effluent quality. How to screen out the key variables from massive observed and control variables for modeling the dioxin emission has become an important issue in incinerator operation and pollution prevention. For these reasons, this study used 4-year monitoring data of an incinerator in Taiwan as a case study, and developed a prediction model based on an artificial neural network (ANN) to forecast the dioxin emission. By doing this, a simplified monitoring strategy for incinerators with regarding to dioxin emission control can be achieved. The result indicated that the prediction model based on a back-propagation neural network is a promising method to deal with complex and non-linear data with the help of statistics in screening out the useful variables for modeling. The suitable architecture of an ANN for using in the dioxin prediction consists of 5 input factors, 3 basic layers with 8 hidden nodes. The R(2) was found to equal 0.99 in both the training and testing steps. In addition, sensitivity analysis can identify the most significant variables for the dioxin emission. From the obtained results, the frequency of activated carbon injection showed as the factor of highest relative importance for the dioxin emission. Copyright © 2013 Elsevier Ltd. All rights reserved.

  18. Characterisation of major component leaching and buffering capacity of RDF incineration and gasification bottom ash in relation to reuse or disposal scenarios

    NARCIS (Netherlands)

    Rocca, S.; Zomeren, van A.; Costa, G.; Dijkstra, J.J.; Comans, R.N.J.; Lombardi, F.

    2012-01-01

    Thermal treatment of refuse derived fuel (RDF) in waste-to-energy (WtE) plants is considered a promising solution to reduce waste volumes for disposal, while improving material and energy recovery from waste. Incineration is commonly applied for the energetic valorisation of RDF, although RDF

  19. Characterisation of major component leaching and buffering capacity of RDF incineration and gasification bottom ash in relation to reuse or disposal scenarios.

    Science.gov (United States)

    Rocca, Stefania; van Zomeren, André; Costa, Giulia; Dijkstra, Joris J; Comans, Rob N J; Lombardi, Francesco

    2012-04-01

    Thermal treatment of refuse derived fuel (RDF) in waste-to-energy (WtE) plants is considered a promising solution to reduce waste volumes for disposal, while improving material and energy recovery from waste. Incineration is commonly applied for the energetic valorisation of RDF, although RDF gasification has also gained acceptance in recent years. In this study we focused on the environmental properties of bottom ash (BA) from an RDF incineration (RDF-I, operating temperature 850-1000°C) and a RDF gasification plant (RDF-G, operating temperature 1200-1400°C), by evaluating the total composition, mineralogy, buffering capacity, leaching behaviour (both at the material's own pH and as a function of pH) of both types of slag. In addition, buffering capacity results and pH-dependence leaching concentrations of major components obtained for both types of BA were analysed by geochemical modelling. Experimental results showed that the total content of major components for the two types of BA was fairly similar and possibly related to the characteristics of the RDF feedstock. However, significant differences in the contents of trace metals and salts were observed for the two BA samples as a result of the different operating conditions (i.e. temperature) adopted by the two RDF thermal treatment plants. Mineralogy analysis showed in fact that the RDF-I slag consisted of an assemblage of several crystalline phases while the RDF-G slag was mainly made up by amorphous glassy phases. The leached concentrations of major components (e.g. Ca, Si) at the natural pH of each type of slag did not reflect their total contents as a result of the partial solubility of the minerals in which these components were chemically bound. In addition, comparison of total contents with leached concentrations of minor elements (e.g. Pb, Cu) showed no obvious relationship for the two types of BA. According to the compliance leaching test results, the RDF-G BA would meet the limits of the Italian

  20. Utilization of ash products from combustion of shredded solid waste

    Energy Technology Data Exchange (ETDEWEB)

    Mahoney, P.F.; Mullen, J.F. (Energy Answers Corp, Albany, NY (US))

    1988-01-01

    One of the major problems with the siting, permitting, construction, and operation of a municipal solid waste-to- energy facility is the disposal of residues. As resource recovery increasingly becomes the disposal option of choice and necessity for municipalities across the country, the foci of environmental concerns has switched from groundwater contamination and inappropriate land use issues associated with landfilling, to air pollution control and residue disposal issues associated with waste combustion. It is suggested that the two separate ash streams can no longer reasonably be considered one and should be analyzed and treated separately, thereby increasing and enhancing the opportunity to recycle from the bottom ash (75 percent) and to focus on a reduced quantity of fly ash material (25 percent) for fixation and reuse or disposal. Such action would conform to the principles of, and the present regulatory trend towards waste minimization. However, there are many regulatory, institutional, and logistical barriers to such promising and seemingly simple waste reduction strategies. While the spirit of solid and hazardous waste legislation may emphasize waste minimization, ambiguities in the regulations have undermined the actual intent, creating an environment of confusion and indecisiveness with respect to treatment and disposal of ash from resource recovery facilities. This book reports on a research and development program to assess the feasibility and possible environmental impacts of utilizing a selected fraction of the bottom ash stream from processed refuse fuel-fired boilers as an aggregate substitute. The purpose of the research program is to develop data on the characteristics of bottom ash during exposure to rain and weathering in proposed applications.

  1. Life cycle assessment of selective non-catalytic reduction (SNCR) of nitrous oxides in a full-scale municipal solid waste incinerator

    DEFF Research Database (Denmark)

    Møller, Jacob; Munk, Bjarne; Crillesen, Kim

    2011-01-01

    Selective non-catalytic reduction (SNCR) of nitrous oxides in a full-scale municipal solid waste incinerator was investigated using LCA. The relationship between NOx-cleaning and ammonia dosage was measured at the plant. Un-reacted ammonia – the ammonia slip – leaving the flue-gas cleaning system...... adsorbed to fly-ash or in the effluent of the acidic scrubber was quantified from the stoichiometric reaction of NOx and ammonia assuming no other reaction products was formed. Of the ammonia slip, 37% was associated with the fly-ash and 63% was in the effluent of the acidic scrubber. Based on NOx......-cleaning efficiency, the fate of the ammonia slip as well as the environmental impact from ammonia production, the potential acidification and nutrient enrichment from NOx-cleaning was calculated as a function of ammonia dosage. Since the exact fate of the ammonia slip could not be measured directly, a number...

  2. A review of municipal solid waste environmental standards with a focus on incinerator residues

    Directory of Open Access Journals (Sweden)

    Alec Liu

    2015-12-01

    Full Text Available Environmental issues are often neglected until a lapse in the care for environment, which leads to serious human health problem, would then put regulation gaps in the spotlight. Environmental regulations and standards are important as they maintain balance among competing resources and help protect human health and the environment. One important environmental standard is related to municipal solid waste (MSW. Proper MSW management is crucial for urban public health. Meanwhile, the sustainability of landfills is also of concern as increasing volumes of MSW consume finite landfill space. The incineration of MSW and the reuse of incinerated residues help alleviate the burden on landfill space. However, the reuse of MSW incinerator residues must be regulated because they may expose the environment to toxic heavy metal elements. The study of environmental standards from different countries applicable to MSW is not widely published, much less those for incinerated MSW residue reuse. This paper compares extant waste classification and reuse standards pertinent to MSW, and explores the unique recent history and policy evolution in some countries exhibiting high environmental regard and rapid changes, so that policy makers can propose new or revise current MSW standards in other countries.

  3. Choice of noxious facilities: case of a solid waste incinerator versus a sanitary landfill in Malaysia.

    Science.gov (United States)

    Othman, Jamal; Khee, Pek Chuen

    2014-05-01

    A choice experiment analysis was conducted to estimate the preference for specific waste disposal technologies in Malaysia. The study found that there were no significant differences between the choice of a sanitary landfill or an incinerator. What matters is whether any disposal technology would lead to obvious social benefits. A waste disposal plan which is well linked or integrated with the community will ensure its acceptance. Local authorities will be challenged to identify solid waste disposal sites that are technically appropriate and also socially desirable.

  4. Establishing the propensity for dioxin formation using a plume temperature model for medical waste incinerator emissions in developing countries

    CSIR Research Space (South Africa)

    Brent, AC

    2002-07-01

    Full Text Available Air pollution control devices (APCDs) are not compulsory for medical waste incinerators (MWIs) in developing countries. In South Africa, combustion gases are usually vented directly to the atmosphere at temperatures greater than the formation...

  5. Commercial and Industrial Solid Waste Incineration Units (CISWI): New Source Performance Standards (NSPS) and Emission Guidelines (EG) for Existing Sources

    Science.gov (United States)

    Learn about the New Source Performance Standards (NSPS) for commercial and industrial solid waste incineration (CISWI) units including emission guidelines and compliance times for the rule. Read the rule history and summary, and find supporting documents

  6. Fluidized beds and their application to hazardous wastes incineration. Lecho fluidizado y su aplicacion a la incineracion de residuos peligrosos

    Energy Technology Data Exchange (ETDEWEB)

    Mullen, J.F.; Franco, M.

    1993-01-01

    The fluidized bed combustion technology and its application to sludge and hazardous wastes incineration are analyzed. A review on specific advantages of this technology including those related to investment costs, operation and maintenance, as well as operation flexibility are given.

  7. LCA of management strategies for RDF incineration and gasification bottom ash based on experimental leaching data

    DEFF Research Database (Denmark)

    Gianfilippo, Martina Di; Costa, Giulia; Pantini, Sara

    2016-01-01

    Fuel (RDF): landfilling and recycling as a filler for road sub bases. Two types of thermal treatment were considered: incineration and gasification. Potential environmental impacts were evaluated by life-cycle assessment (LCA) using the EASETECH model. Both non-toxicity related impact categories (i.......e. global warming and mineral abiotic resource depletion) and toxic impact categories (i.e. human toxicity and ecotoxicity) were assessed. The system boundaries included BA transport from the incineration/gasification plants to the landfills and road construction sites, leaching of potentially toxic metals...... to the total impacts had a dominant role, with the highest environmental loads resulting for the road scenario. For the gasification BA, the opposite result was obtained, due to the lower release of contaminants observed for this material compared to incineration BA. Based on the results of this study, it may...

  8. The Design of a Portable Municipal Waste Incinerator With Fuzzy Logic Based Support for Emission Estimation

    Directory of Open Access Journals (Sweden)

    Jude C. Akpe

    2016-12-01

    Full Text Available A fuzzy logic interface system to estimate oxygen requirement for complete combustion as well as the level of pollution from incinerator gas flue in order to manage solid waste from domestic, institutional, medical and industrial sources was designed. The designed incinerator is double chambered operating with a maximum temperature of 760 °C in the lower chamber and 1000°C in the upper chamber.  The insulating wall is made up of a refractory brick of 55mm in thickness having a 2mm thickness low carbon steel as the outer wall.  Hydrogen Chloride (HCl and Nitrous oxides (NOx are the gases was used to demonstrate the Fuzzy Inference System (FIS model. The FIS was built with five input variables (Food, PVC, Polythene, Paper and Textile and three input variables with two membership functions. The FIS was developed to estimation the degree of possibility distribution of pollution that should be expected when a certain composition of waste is incinerated. The plots of composition of waste high in food against oxygen require for combustion gives a possibility distribution of about 0.9 which is high according to the fuzzy set definition while the plot of waste composition high in PVC against HCL shows linearity.

  9. Refuse-fueled power stations and waste incinerators. Different plant technology?; Ersatzbrennstoffkraftwerke und Abfallverbrennungsanlagen. Unterschiedliche Anlagentechnik?

    Energy Technology Data Exchange (ETDEWEB)

    Seeger, H. [umwelttechnik und ingenieure GmbH, Hannover (Germany)

    2007-07-01

    The conceptual delimitation of a refuse-fueled power station in relation to a waste incinerator results from the primary setting of tasks for the plant. In the case of waste incinerators, the combustion of solid wastes is the centre of attention. In contrast to this, the production of utilization energy is the centre of interest at refuse-fueled power stations. Accordingly, the refuse-fueled power station is planned under the aspect of power requirement as a function of the production time of the customers. In particular, if there are industrial customers with strong variations in power requirement, then the refuse-derived fuel power station either has to go in part load or has to be able to deal with large quantities of surplus steam. A refuse-fueled power station conceptually differs from a waste incinerator by the priority of the power supply in relation to the aspect of disposal. The power requirement is the crucial fundamental condition for the plant concept. The special characteristics of secondary fuels require adjustments in the equipment technology in order to meet the requirement regarding to energy efficiency and supply security.

  10. The safety of non-incineration waste disposal devices in four hospitals of Tehran.

    Science.gov (United States)

    Farshad, Aliasghar; Gholami, Hamid; Farzadkia, Mahdi; Mirkazemi, Roksana; Kermani, Majid

    2014-01-01

    The safe management of hospital waste is a challenge in many developing countries. The aim of this study was to compare volatile organic compounds (VOCs) emissions and the microbial disinfectant safety in non-incineration waste disposal devices. VOC emissions and microbial infections were measured in four non-incineration waste disposal devices including: autoclave with and without a shredder, dry heat system, and hydroclave. Using NIOSH and US EPA-TO14 guidelines, the concentration and potential risk of VOCs in emitted gases from four devices were assessed. ProSpore2 biological indicators were used to assess the microbial analysis of waste residue. There was a significant difference in the type and concentration of VOCs and microbial infection of residues in the four devices. Emissions from the autoclave with a shredder had the highest concentration of benzene, ethyl benzene, xylene, and BTEX, and emissions from the hydroclave had the highest concentration of toluene. The highest level of microbial infection was observed in the residues of the autoclave without a shredder. There is an increased need for proper regulation and control of non-incinerator devices and for monitoring and proper handling of these devices in developing countries.

  11. Incineration and co-combustion of waste: accounting of greenhouse gases and global warming contributions.

    Science.gov (United States)

    Astrup, Thomas; Møller, Jacob; Fruergaard, Thilde

    2009-11-01

    Important greenhouse gas (GHG) emissions related to waste incineration and co-combustion of waste were identified and considered relative to critical aspects such as: the contents of biogenic and fossil carbon, N(2)O emissions, fuel and material consumptions at the plants, energy recovery, and solid residues generated. GHG contributions were categorized with respect to direct emissions from the combustion plant as well as indirect upstream contributions (e.g. provision of fuels and materials) and indirect downstream contributions (e.g. substitution of electricity and heat produced elsewhere). GHG accounting was done per tonne of waste received at the plant. The content of fossil carbon in the input waste, for example as plastic, was found to be critical for the overall level of the GHG emissions, but also the energy conversion efficiencies were essential. The emission factors for electricity provision (also substituted electricity) affected the indirect downstream emissions with a factor of 3-9 depending on the type of electricity generation assumed. Provision of auxiliary fuels, materials and resources corresponded to up to 40% of the direct emission from the plants (which were 347-371 kg CO(2)-eq. tonne( -1) of waste for incineration and 735-803 kg CO(2)-eq. tonne(-1) of waste for co-combustion). Indirect downstream savings were within the range of -480 to -1373 kg CO(2)eq. tonne(-1) of waste for incineration and within -181 to -2607 kg CO(2)-eq. tonne(- 1) of waste for co-combustion. N(2)O emissions and residue management did not appear to play significant roles.

  12. Incinerated sewage sludge ash as alternative binder in cement-based materials

    DEFF Research Database (Denmark)

    Krejcirikova, Barbora; Goltermann, Per; Hodicky, Kamil

    2013-01-01

    Sewage sludge ash is characterized by its pozzolanic properties, as cement is. This predetermines its use in a substitution of cement and cementitious materials. Utilization of sewage sludge ash does not only decrease the consumption of cement, one of the largest cause of CO2 emissions, but also ...

  13. Evaluation of Cement, Lime, and Asphalt Amended Municipal Solid Waste Incinerator Residues

    Science.gov (United States)

    1989-09-01

    typical lime contents seen in the residues produced from in- cinerators using flue gas cleaning materials (Forrester, 1988). For comparative purposes, the...1987) By-product disposal from MSW incinerator flue gas cleaning systems. Proceedings 80th APCA Meeting, NY Drever, J. (1988) The Geochemistry of...to Congress. EPA/530-SW-87-021a EPA (1987b) Municipal waste combustion study - Flue gas cleaning technology. EPA/530-SW-87-021d EPRI (1984) Chemical

  14. Integrated management of ash from industrial and domestic combustion : a new sustainable approach for reducing greenhouse gas emissions from energy conversion

    OpenAIRE

    Benassi, L.; R. Dalipi; Consigli, V; Pasquali, M.; Borgese, L.; Depero, L.E.; Clegg, Francis; Bingham, Paul; Bontempi, E.

    2017-01-01

    This work supports, for the first time, the integrated management of waste materials arising from industrial processes (fly ash from municipal solid waste incineration and coal fly ash), agriculture (rice husk ash), and domestic activities (ash from wood biomass burning in domestic stoves). The main novelty of the paper is the reuse of wood pellet ash, an underestimated environmental problem, by the application of a new technology (COSMOS-RICE) that already involves the reuse of fly ashes fro...

  15. A quantitative assessment of the BSE risk associated with fly ash and slag from the incineration of meat-and-bone meal in a gas-fired power plant in Denmark

    DEFF Research Database (Denmark)

    Paisley, Larry; Hostrup-Pedersen, J.

    2005-01-01

    It has been recommended that meat-and-bone meal (MBM) be incinerated at 850 degrees C for at least 2 s and the ashes and slag disposed of in controlled landfills, to dispose of animal-derived proteins. Most commonly, the MBM is incinerated in cement works or coal-fired power plants and the ashes...... in controlied landfills and the feasibility of use of the ash by the phosphate and fertilizer industries. We assumed that all specified risk material (SRM) and MBM produced in Denmark would be incinerated in this gas-fired power plant. Based on observations in 2001, we assumed that, on average, six (range: 0...

  16. Silica from Ash-A Valuable Product from Waste Material

    Indian Academy of Sciences (India)

    ... Resonance – Journal of Science Education; Volume 2; Issue 7. Silica from Ash - A Valuable Product from Waste Material. Davinder Mittal. General Article Volume 2 ... Author Affiliations. Davinder Mittal1. Chemical Technology Dept. Sont Longowal Institute of Engg. & Tech. Longowal 148 106, Distt.Sangrur, Punjab, India ...

  17. Pozzolanic characteristics of municipal solid waste ash | Sanewu ...

    African Journals Online (AJOL)

    It is with this backdrop that this paper describes the pozzolanic characteristics of municipal solid waste ash (MSWA) and its use as a stabilizing agent. The total elemental concentration in the MSWA was determined by use of Total X‐ray Florescence method, while the laser particle analysis method was used to determine the ...

  18. Effects of agricultural wastes ash on nutrients concentration and ...

    African Journals Online (AJOL)

    Field trials and a pot experiment were conducted during the 2005 and 2006 cropping seasons at Michael Okpara University of Agriculture, Umudike, Nigeria, to assess the effect of various agricultural wastes ash on nutrient concentration, growth and yield of maize in a Haplic Acrisol. The treatments comprised palm bunch ...

  19. DEMOLITION OF HANFORDS 232-Z WASTE INCINERATION FACILITY

    Energy Technology Data Exchange (ETDEWEB)

    LLOYD, E.R.

    2006-11-21

    The 232-Z Plutonium Incinerator Facility was a small, highly alpha-contaminated, building situated between three active buildings located in an operating nuclear complex. Approximately 500 personnel worked within 250 meters (800 ft) of the structure and expectations were that the project would neither impact plant operations nor result in any restrictions when demolition was complete. Precision demolition and tight controls best describe the project. The team used standard open-air demolition techniques to take the facility to slab-on-grade. Several techniques were key to controlling contamination and confining it to the demolition area: spraying fixatives before demolition began; using misting systems, frequently applying fixatives, and using a methodical demolition sequence and debris load-out process. Detailed air modeling was done before demolition to determine necessary facility source-term levels, establish radiological boundaries, and confirm the adequacy of the proposed demolition approach. By only removing the major source term in equipment, HEPA filters, gloveboxes, and the like, and leaving fixed contamination on the walls, ceilings and floors, the project showed considerable savings and reduced worker hazards and exposure. The ability to perform this demolition safely and without the spread of contamination provides confidence that similar operations can be performed successfully. By removing the major source terms, fixing the remaining contamination in the building, and using controlled demolition and contamination control techniques, similar structures can be demolished cost effectively and safely.

  20. Green, Eco, Innovative Design, and Manufacturing Technology of a 1-Ton per Batch Municipal Solid Waste Incinerator

    Directory of Open Access Journals (Sweden)

    Kerdsuwan Somrat

    2016-01-01

    Full Text Available The thermal treatment of waste by incineration is considered an ultimate solution in order to get rid of waste properly by using the combustible properties of waste and transforming them into inert form and gaseous emission, with the main advantage of a huge reduction in mass and volume of treated waste, destruction of the dangerous components in waste, and obtaining green and clean energy from the exothermal reaction from the completed combustion process. In order to achieve the main goal of incineration, a good design, construction, supervision, and intensive operation and maintenance must be taken into account, especially for the small-scale incinerator. This research will deal with the green, innovative, and eco design and manufacturing technology of a 1-ton per batch municipal solid waste (MSW incinerator. The concept design of the incinerator will focus on the design of the feeding process where only one batch of waste will be discharged into the combustion chamber at one time instead of the semi-feed process, as found in the conventional incinerator. This will ease the operation of the operator and reduce the operating cost. Moreover, the innovative design includes the redesign of combustion air injection into either the primary or secondary combustion chamber in order to achieve the 3Ts of combustion (time, temperature. and turbulence. This design can eliminate the use of an auxiliary burner in the primary combustion chamber. Rethinking the innovative design of using recirculation hot flue gas for preheating of wet garbage in order to pre-dry the waste before combustion is also taken into account. The manufacturing process of the wall composition as well as other parts of the incinerator are also examined.

  1. ECOLOGICAL AND TECHNOLOGYCAL ASPECTS OF ASH AND SLAG WASTES UTILIZATION

    Directory of Open Access Journals (Sweden)

    Tatyana Aleksandrova

    2017-07-01

    Full Text Available The article presents the results of investigation focused on the utilization of ash and slag wastes (ASW in Russia including investigation of chemical and physical properties of ASW and processing products. Many factors influence the technological properties of ash and slag materials: naturals, processes and environments. The integrated treatment of ash and slag wastes of both stored and re-formed types will allow obtaining the following commercial products: coal concentrate, iron concentrate, aluminosilicate cenospheres, aluminosilicate product. In this study we have analyzed the methods for separation of ASW iron-containing part using the different types of the magnetic separation from the ash and slag material from one of the combined heat and power plant (CHPP in the Russian Far East Federal District. The greatest interest is the dry magnetic separation with travelling electromagnetic field. The subject of research was a sample taken from one of ash dump of CHPP in the Far East. In the study iron concentrate containing Fetotal = 64% was obtained recovery 68% in the low intensity (up to 5 kOe travelling magnetic field.

  2. ASSESSMENT OF THE USE FOR FERTILISATION PURPOSES INCINERATION ASH PELLETS USING GASIFICATION BURNER LESTER

    Directory of Open Access Journals (Sweden)

    Marzena Gibczyńska

    2016-12-01

    Full Text Available The use of biomass in system energetics for the purpose of increasing the share of renewable energy sources in the overall energy mix by biomass and coal co-combustion is not an optimal solution in the light of previous experience in Poland. It is appropriate to develop local biomass market for energy purposes as a basis for future distributed energy generation based on biomass. This solution facilitates the use of ash from biomass combustion for plant fertilisation. The present paper concerns the assessment of the use of ash from combustion of pellets in an innovative gasifying pellet burner – LESTER type, for soil fertilisation. The paper presents the analysis of the content of macro- and microelements in ash against the chemical composition of pellets in relation to permissible contents in fertilisers. The content of phosphorus, potassium, calcium and magnesium in bottom and fly ash from combustion of wood pellet and rye straw in LESTER gasifying burner validates the use of this material for soil fertilisation purposes. However, due to low nitrogen content – comparable to that found in soil, the material is not to be considered as fertiliser supplying this macroelement to soil. The analysed bottom ash used for fertilisation meets the conditions set out in the Regulation of the Minister of Environment of 9 September 2002. However, fly ash should be used with considerable caution due to high content of iron, zinc and nickel. The yield of bottom ash is several times higher than that of fly ash, therefore the possibility of its use in the form of mixtures in adequate proportions should be considered.

  3. Life cycle assessment of waste incineration in Denmark and Italy using two LCA models.

    Science.gov (United States)

    Turconi, Roberto; Butera, Stefania; Boldrin, Alessio; Grosso, Mario; Rigamonti, Lucia; Astrup, Thomas

    2011-10-01

    In Europe, about 20% of municipal solid waste is incinerated. Large differences can be found between northern and southern Europe regarding energy recovery efficiencies, flue gas cleaning technologies and residue management. Life-cycle assessment (LCA) of waste incineration often provides contradictory results if these local conditions are not properly accounted for. The importance of regional differences and site-specific data, and choice of LCA model itself, was evaluated by assessment of two waste incinerators representing northern and southern Europe (Denmark and Italy) based on two different LCA models (SimaPro and EASEWASTE). The results showed that assumptions and modelling approaches regarding energy recovery/substitution and direct air emissions were most critical. Differences in model design and model databases mainly had consequences for the toxicity-related impact categories. The overall environmental performance of the Danish system was better than the Italian, mainly because of higher heat recovery at the Danish plant. Flue gas cleaning at the Italian plant was, however, preferable to the Danish, indicating that efficient flue gas cleaning may provide significant benefits. Differences in waste composition between the two countries mainly affected global warming and human toxicity via water. Overall, SimaPro and EASEWASTE provided consistent ranking of the individual scenarios. However, important differences in results from the two models were related to differences in the databases and modelling approaches, in particular the possibility for modelling of waste-specific emissions affected the toxicity-related impact categories. The results clearly showed that the use of site-specific data was essential for the results.

  4. Avaliação do uso de poli(tereftalato de etileno (PET como matriz de imobilização de cinzas de incineradores Assessment of the use of polyethylene terephthalate (PET as matrix for immobilization of incinerator ash

    Directory of Open Access Journals (Sweden)

    Flávia Gonçalves Pacheco

    2009-01-01

    Full Text Available Industrial hazardous wastes must receive appropriate treatment to ensure a safe disposal to humans and environment. One of the techniques adopted for this purpose is the stabilization/solidification in polymer matrices. This paper evaluated the use of recycled polyethylene terephthalate as an incorporation matrix of incinerator ash. The polymer and the ash were submitted to an extrusion process in different percentages. The final product was evaluated through thermal and leaching tests and the leachate extracts constituents were determinated by atomic absorption spectrophotometry. The results showed a reduction in the release of substances up to 99% by mass for the conditions used.

  5. Waste incineration: estimation of the workers' internal exposure to PCB, PAH chlorophenols and other relevant agents

    Science.gov (United States)

    Angerer, Juergen; Heinzow, B.; Reimann, D. O.; Knorz, W.; Lehnert, G.

    1993-03-01

    Fifty-four persons occupied in a municipal waste incinerator were examined with respect to their internal exposure to organic substances which are possibly produced during pyrolysis of organic matter. For this purpose the levels of benzene of blood, polychlorinated biphenyls (PCB) and hexachlorobenzene (HCB) in plasma as well as mono- (MCP), di- (DCP), tri- (TCP), tetra- (TECP) and pentachlorophenols (PCP) and hydroxypyrene in urine have been determined. Four hundred thirty-one men and women were examined for control purposes. Statistical significantly higher values for the workers were found for the excretion of hydroxypyrene 2,5/2,4-DCP, 2,4,5 TCP, and for the HCB level in plasma. For the concentrations of 4-MCP and 2,3,4,6-2,3,5,6-TECP the controls had significantly higher concentrations in urine than the workers in the incineration plant. No significant differences between workers and controls were detected with respect to benzene in blood, 2,4,6-TCP and PCP in urine, and to the levels of PCP congeners in plasma. The elevated levels of hydroxypyrene, 2,4-/2,5 DCP, 2,4,5-TCP, and HCB in biological material may be related to the incineration of the waste. These elevations, however, are very small and attract attention more from the environmental than from the occupational point of view.

  6. A Critical Evaluation of Waste Incineration Plants in Wuhan (China) Based on Site Selection, Environmental Influence, Public Health and Public Participation

    Science.gov (United States)

    Hu, Hui; Li, Xiang; Nguyen, Anh Dung; Kavan, Philip

    2015-01-01

    With the rapid development of the waste incineration industry in China, top priority has been given to the problem of pollution caused by waste incineration. This study is the first attempt to assess all the waste incineration plants in Wuhan, the only national key city in central China, in terms of environmental impact, site selection, public health and public participation. By using a multi-criterion assessment model for economic, social, public health and environmental effects, this study indicates these incineration plants are established without much consideration of the local residents’ health and environment. A location analysis is also applied and some influences of waste incineration plants are illustrated. This study further introduces a signaling game model to prove that public participation is a necessary condition for improving the environmental impact assessment and increasing total welfare of different interest groups in China. This study finally offers some corresponding recommendations for improving the environmental impact assessments of waste incineration projects. PMID:26184242

  7. A Critical Evaluation of Waste Incineration Plants in Wuhan (China Based on Site Selection, Environmental Influence, Public Health and Public Participation

    Directory of Open Access Journals (Sweden)

    Hui Hu

    2015-07-01

    Full Text Available With the rapid development of the waste incineration industry in China, top priority has been given to the problem of pollution caused by waste incineration. This study is the first attempt to assess all the waste incineration plants in Wuhan, the only national key city in central China, in terms of environmental impact, site selection, public health and public participation. By using a multi-criterion assessment model for economic, social, public health and environmental effects, this study indicates these incineration plants are established without much consideration of the local residents’ health and environment. A location analysis is also applied and some influences of waste incineration plants are illustrated. This study further introduces a signaling game model to prove that public participation is a necessary condition for improving the environmental impact assessment and increasing total welfare of different interest groups in China. This study finally offers some corresponding recommendations for improving the environmental impact assessments of waste incineration projects.

  8. Strategy for nuclear wastes incineration in hybrid reactors; Strategies pour l'incineration de dechets nucleaires dans des reacteurs hybrides

    Energy Technology Data Exchange (ETDEWEB)

    Lelievre, F

    1998-12-11

    The transmutation of nuclear wastes in accelerator-driven nuclear reactorsoffers undeniable advantages. But before going into the detailed study of a particular project, we should (i) examine the possible applications of such systems and (ii) compare the different configurations, in order to guide technological decisions. We propose an approach, answering both concerns, based on the complete description of hybrid reactors. It is possible, with only the transmutation objective and a few technological constraints chosen a posteriori, to determine precisely the essential parameters of such reactors: number of reactors, beam current, size of the core, sub-criticality... The approach also clearly pinpoints the strategic decisions, for which the scientist or engineer is not competent. This global scheme is applied to three distinct nuclear cycles: incineration of solid fuel without recycling, incineration of liquid fuel without recycling and incineration of liquid fuel with on-line recycling; and for two spectra, either thermal or fast. We show that the radiotoxicity reduction with a solid fuel is significant only with a fast spectrum, but the incineration times range from 20 to 30 years. The liquid fuel is appropriate only with on-line recycling, at equilibrium. The gain on the radiotoxicity can be considerable and we describe a number of such systems. The potential of ADS for the transmutation of nuclear wastes is confirmed, but we should continue the description of specific systems obtained through this approach. (author)

  9. Assessment of long-term pH developments in leachate from waste incineration residues

    DEFF Research Database (Denmark)

    Astrup, Thomas; Jakobsen, Rasmus; Christensen, Thomas Højlund

    2006-01-01

    influenced by changes in pH over time. The paper presents an approach for assessing pH changes in leachate from municipal solid waste incineration (MSWI) air-pollution-control (APC) residues. Residue samples were subjected to a stepwise batch extraction method in order to obtain residue samples at a range......Environmental assessment of residue disposal needs to account for long-term changes in leaching conditions. Leaching of heavy metals from incineration residues are highly affected by the leachate pH; the overall environmental consequences of disposing of these residues are therefore greatly...... of pH Values (similar to common pH-dependence tests), and then on these samples to determine leaching of alkalinity as well as remaining solid phase alkalinity. On a range of APC residues covering various pretreatment and disposal options, this procedure was used to determine leachable and residual...

  10. Local CFD kinetic model of cadmium vaporization during fluid bed incineration of municipal solid waste

    Energy Technology Data Exchange (ETDEWEB)

    Soria, J. [Instituto Multidisciplinario de Investigación y Desarrollo de la Patagonia Norte (IDEPA, CONICET-UNCo) y Facultad de Ingeniería, Universidad Nacional del Comahue, Buenos Aires 1400, 8300 Neuquén (Argentina); Laboratoire Procédés, Matériaux et Energie Solaire (CNRS-PROMES), 7 Rue du Four Solaire, Odeillo, 66120 Font-Romeu (France); Gauthier, D., E-mail: Daniel.Gauthier@promes.cnrs.fr [Laboratoire Procédés, Matériaux et Energie Solaire (CNRS-PROMES), 7 Rue du Four Solaire, Odeillo, 66120 Font-Romeu (France); Falcoz, Q.; Flamant, G. [Laboratoire Procédés, Matériaux et Energie Solaire (CNRS-PROMES), 7 Rue du Four Solaire, Odeillo, 66120 Font-Romeu (France); Mazza, G. [Instituto Multidisciplinario de Investigación y Desarrollo de la Patagonia Norte (IDEPA, CONICET-UNCo) y Facultad de Ingeniería, Universidad Nacional del Comahue, Buenos Aires 1400, 8300 Neuquén (Argentina)

    2013-03-15

    Highlights: ► A 2-D local CFD model for simulating the Cd vaporization process is presented. ► It includes a kinetic expression of Cd vaporization into the incineration process. ► Pyrolysis, volatiles’ combustion and residual carbon combustion are also taken into account. ► It fits very well the experimental results obtained on a lab-scale fluidized bed reported in literature. ► It also compares favorably with a model developed previously by the group. -- Abstract: The emissions of heavy metals during incineration of Municipal Solid Waste (MSW) are a major issue to health and the environment. It is then necessary to well quantify these emissions in order to accomplish an adequate control and prevent the heavy metals from leaving the stacks. In this study the kinetic behavior of Cadmium during Fluidized Bed Incineration (FBI) of artificial MSW pellets, for bed temperatures ranging from 923 to 1073 K, was modeled. FLUENT 12.1.4 was used as the modeling framework for the simulations and implemented together with a complete set of user-defined functions (UDFs). The CFD model combines the combustion of a single solid waste particle with heavy metal (HM) vaporization from the burning particle, and it takes also into account both pyrolysis and volatiles’ combustion. A kinetic rate law for the Cd release, derived from the CFD thermal analysis of the combusting particle, is proposed. The simulation results are compared with experimental data obtained in a lab-scale fluidized bed incinerator reported in literature, and with the predicted values from a particulate non-isothermal model, formerly developed by the authors. The comparison shows that the proposed CFD model represents very well the evolution of the HM release for the considered range of bed temperature.

  11. Treatment of clinical solid waste using a steam autoclave as a possible alternative technology to incineration.

    Science.gov (United States)

    Hossain, Md Sohrab; Balakrishnan, Venugopal; Rahman, Nik Norulaini Nik Ab; Sarker, Md Zaidul Islam; Kadir, Mohd Omar Ab

    2012-03-01

    A steam autoclave was used to sterilize bacteria in clinical solid waste in order to determine an alternative to incineration technology in clinical solid waste management. The influence of contact time (0, 5, 15, 30 and 60 min) and temperature (111 °C, 121 °C and 131 °C) at automated saturated steam pressure was investigated. Results showed that with increasing contact time and temperature, the number of surviving bacteria decreased. The optimum experimental conditions as measured by degree of inactivation of bacteria were 121 °C for 15 minutes (min) for Gram negative bacteria, 121 °C and 131 °C for 60 and 30 min for Gram positive bacteria, respectively. The re-growth of bacteria in sterilized waste was also evaluated in the present study. It was found that bacterial re-growth started two days after the inactivation. The present study recommends that the steam autoclave cannot be considered as an alternative technology to incineration in clinical solid waste management.

  12. Municipal solid wastes incineration with combined cycle: a case study from Sao Paulo

    Energy Technology Data Exchange (ETDEWEB)

    Cerda Balcazar, Juan Galvarino; Dias, Rubens Alves; Balestieri, Jose Antonio Perrella [Universidade Estadual Paulista (UNESP), Guaratingueta, SP (Brazil)], E-mails: pos09007@feg.unesp.br, rubdias@feg.unesp.br

    2010-07-01

    Large urban centers have a huge demand for electricity, for the needs of its residents, and a growing problem of management of solid waste generated by it, that becomes an public administrative and great social problem. The correct disposal of solid waste generated by large urban centers is now one of the most complex engineering problems involving logistics, safety, environment, energy spent among other tools for sound management of municipal solid waste (MSW). This study was carried out a study of the use of incinerators and residue derived fuel and MSW with combined cycles, with the aim of producing thermal and mechanical energy (this later becomes electrical energy) and solid waste treatment in Sao Paulo. We used existing models and real plants in the European Union in this case, with the aim of making it the most viable and compatible with the current context of energy planning and resource today. A technical and economic feasibility study for a plant of this nature, using the scheme, is presented. It is expected a good attractiveness of using incinerators combined-cycle, due to its high efficiency and its ability to thermoelectric generation. (author)

  13. Environmental Assessment of a Waste Incineration Tax. Case Study and Evaluation of a Framework for Strategic Environmental Assessment

    Energy Technology Data Exchange (ETDEWEB)

    Bjoerklund, Anna; Johansson, Jessica [Swedish Defence Research Agency, Stockholm (Sweden); Nilsson, Maans [Stockholm Environment Inst., Stockholm (Sweden); Eldh, Peter; Finnveden, Goeran [Royal Inst. of Technology, Stockholm (Sweden). Dept. of Industrial Ecology

    2003-12-01

    A framework for Strategic Environmental Assessment (SEA) is tested in a case study on a proposed waste incineration tax. Also included is testing of developed methods for valuation and site-dependent life cycle impact assessment. The results indicate that although a suggested waste incineration tax of 400 SEK/ton is likely to lead to environmental improvements, these are small compared to the potential improvements as shown in more visionary scenarios. In order to go in this direction a waste incineration tax based on the content of fossil carbon in the waste would be useful. The framework for SEA includes several different pathways. These have different advantages and disadvantages and provide different types of information. It is therefore suggested that they largely complement each other and that the choice of methods should be done in relation to the function of the SEA and the questions asked.

  14. Role of accelerator-driven systems in waste incineration scenarios

    Energy Technology Data Exchange (ETDEWEB)

    Salvatores, M.; Slessarev, I.; Tchistiakov, A. [CEA Centre d`Etudes de Cadarache, 13 - Saint-Paul-lez-Durance (France). Direction des Reacteurs Nucleaires; Spiro, M.; Terrien, Y.; Mouney, H.; Vergnes, J.

    1997-12-31

    At CEA accelerator-driven systems (ADS) are studied in the frame of the R and D required to answer the request of a law voted in 1991 by the French Parliament, `to search for solutions allowing to partition and transmute long lived radioactive wastes, in order to reduce their volume and toxicity`. These systems (called `INCAs`) are still at a conceptual level. However, the role of ADS has been clarified as a first step, and this will be the subject of the present paper. (author)

  15. Life cycle assessment of pyrolysis, gasification and incineration waste-to-energy technologies: Theoretical analysis and case study of commercial plants.

    Science.gov (United States)

    Dong, Jun; Tang, Yuanjun; Nzihou, Ange; Chi, Yong; Weiss-Hortala, Elsa; Ni, Mingjiang

    2018-01-19

    Municipal solid waste (MSW) pyrolysis and gasification are in development, stimulated by a more sustainable waste-to-energy (WtE) option. Since comprehensive comparisons of the existing WtE technologies are fairly rare, this study aims to conduct a life cycle assessment (LCA) using two sets of data: theoretical analysis, and case studies of large-scale commercial plants. Seven systems involving thermal conversion (pyrolysis, gasification, incineration) and energy utilization (steam cycle, gas turbine/combined cycle, internal combustion engine) are modeled. Theoretical analysis results show that pyrolysis and gasification, in particular coupled with a gas turbine/combined cycle, have the potential to lessen the environmental loadings. The benefits derive from an improved energy efficiency leading to less fossil-based energy consumption, and the reduced process emissions by syngas combustion. Comparison among the four operating plants (incineration, pyrolysis, gasification, gasification-melting) confirms a preferable performance of the gasification plant attributed to syngas cleaning. The modern incineration is superior over pyrolysis and gasification-melting at present, due to the effectiveness of modern flue gas cleaning, use of combined heat and power (CHP) cycle, and ash recycling. The sensitivity analysis highlights a crucial role of the plant efficiency and pyrolysis char land utilization. The study indicates that the heterogeneity of MSW and syngas purification technologies are the most relevant impediments for the current pyrolysis/gasification-based WtE. Potential development should incorporate into all process aspects to boost the energy efficiency, improve incoming waste quality, and achieve efficient residues management. Copyright © 2018 Elsevier B.V. All rights reserved.

  16. 40 CFR 60.2971 - What are the emission limitations for air curtain incinerators that burn only wood waste, clean...

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 6 2010-07-01 2010-07-01 false What are the emission limitations for air curtain incinerators that burn only wood waste, clean lumber, and yard waste? 60.2971 Section 60.2971 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) STANDARDS OF PERFORMANCE FOR NEW STATIONARY...

  17. 40 CFR 62.14815 - What are the emission limitations for air curtain incinerators that burn 100 percent wood wastes...

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 8 2010-07-01 2010-07-01 false What are the emission limitations for air curtain incinerators that burn 100 percent wood wastes, clean lumber and/or yard waste? 62.14815 Section 62.14815 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) APPROVAL AND PROMULGATION OF STATE...

  18. 40 CFR 60.3066 - What are the emission limitations for air curtain incinerators that burn only wood waste, clean...

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 6 2010-07-01 2010-07-01 false What are the emission limitations for air curtain incinerators that burn only wood waste, clean lumber, and yard waste? 60.3066 Section 60.3066 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) STANDARDS OF PERFORMANCE FOR NEW STATIONARY...

  19. Nitrous oxide and methane emissions and nitrous oxide isotopic composition from waste incineration in Switzerland

    Energy Technology Data Exchange (ETDEWEB)

    Harris, Eliza, E-mail: eliza.harris@empa.ch [Empa, Laboratory for Air Pollution and Environmental Technology, Überlandstrasse 129, CH-8600 Dübendorf (Switzerland); Zeyer, Kerstin [Empa, Laboratory for Air Pollution and Environmental Technology, Überlandstrasse 129, CH-8600 Dübendorf (Switzerland); Kegel, Rainer; Müller, Beat [FOEN, Federal Office for the Environment, Air Pollution Control and Chemicals, CH-3003 Berne (Switzerland); Emmenegger, Lukas; Mohn, Joachim [Empa, Laboratory for Air Pollution and Environmental Technology, Überlandstrasse 129, CH-8600 Dübendorf (Switzerland)

    2015-01-15

    Highlights: • N{sub 2}O emissions from waste incineration with SNCR NO{sub x} removal are 51.5 ± 10.6 g t{sup −1}. • This is significantly lower than the reported Swiss emission factor of 120 g t{sup −1} (FOEN, 2013). • N{sub 2}O contributes <0.3% and ≈2.5% of GHG emissions from SCR and SNCR plants. • Measured isotopic SP of 17.7‰ is likely characteristic for N{sub 2}O emissions from SNCR. • CH{sub 4} emitted by waste incineration is negligible, contributing <0.01% to total GHGs. - Abstract: Solid waste incineration accounts for a growing proportion of waste disposal in both developed and developing countries, therefore it is important to constrain emissions of greenhouse gases from these facilities. At five Swiss waste incineration facilities with grate firing, emission factors for N{sub 2}O and CH{sub 4} were determined based on measurements of representative flue gas samples, which were collected in Tedlar bags over a one year period (September 2010–August 2011) and analysed with FTIR spectroscopy. All five plants burn a mixture of household and industrial waste, and two of the plants employ NO{sub x} removal through selective non-catalytic reduction (SNCR) while three plants use selective catalytic reduction (SCR) for NO{sub x} removal. N{sub 2}O emissions from incineration plants with NO{sub x} removal through selective catalytic reduction were 4.3 ± 4.0 g N{sub 2}O tonne{sup −1} waste (wet) (hereafter abbreviated as t{sup −1}) (0.4 ± 0.4 g N{sub 2}O GJ{sup −1}), ten times lower than from plants with selective non-catalytic reduction (51.5 ± 10.6 g N{sub 2}O t{sup −1}; 4.5 ± 0.9 g N{sub 2}O GJ{sup −1}). These emission factors, which are much lower than the value of 120 g N{sub 2}O t{sup −1} (10.4 g N{sub 2}O GJ{sup −1}) used in the 2013 Swiss national greenhouse gas emission inventory, have been implemented in the most recent Swiss emission inventory. In addition, the isotopic composition of N{sub 2}O emitted from the two

  20. Treatment of waste incinerator air-pollution-control residues with FeSO4: concept and product characterisation.

    Science.gov (United States)

    Lundtorp, K; Jensen, D L; Sørensen, M A; Christensen, T H; Mogensen, E P B

    2002-02-01

    This paper describes a new concept for treatment of air pollution-control (APC) residues from waste incineration and characterises the wastewater and stabilised residues generated by the process. The process involves mixing of APC-residues with a ferrous sulphate solution and subsequent oxidation of the suspension (Ferrox-process 1996). The process results in a significant reduction in the leaching of salts and heavy metals from the residue, by washing out most of the salts and by binding the heavy metals in the iron oxides formed. In the laboratory, a semidry gas-cleaning residue and a fly ash were treated by the process. The generated wastewater contained low concentrations of heavy metals (e.g. Pb: 27-39 microg l(-1) and Cd: 2.6-4.6 microg l(-1)), but high concentrations of salts (e.g. Cl, Na, K, and Ca). The treatment process redUced the leaching of Pb from the residues by more than two orders of magnitude at fixed pH as determined by pH-static leaching tests. Likewise, the leaching of Cd, Zn and Cu was significantly reduced. The effect on elements that form oxyanions (e.g. Cr) is marginal and in the current process there is no reduction in the release of Hg.

  1. Nitrous oxide and methane emissions and nitrous oxide isotopic composition from waste incineration in Switzerland.

    Science.gov (United States)

    Harris, Eliza; Zeyer, Kerstin; Kegel, Rainer; Müller, Beat; Emmenegger, Lukas; Mohn, Joachim

    2015-01-01

    Solid waste incineration accounts for a growing proportion of waste disposal in both developed and developing countries, therefore it is important to constrain emissions of greenhouse gases from these facilities. At five Swiss waste incineration facilities with grate firing, emission factors for N2O and CH4 were determined based on measurements of representative flue gas samples, which were collected in Tedlar bags over a one year period (September 2010-August 2011) and analysed with FTIR spectroscopy. All five plants burn a mixture of household and industrial waste, and two of the plants employ NOx removal through selective non-catalytic reduction (SNCR) while three plants use selective catalytic reduction (SCR) for NOx removal. N2O emissions from incineration plants with NOx removal through selective catalytic reduction were 4.3 ± 4.0g N2O tonne(-1) waste (wet) (hereafter abbreviated as t(-1)) (0.4 ± 0.4 g N2O GJ(-1)), ten times lower than from plants with selective non-catalytic reduction (51.5 ± 10.6g N2O t(-1); 4.5 ± 0.9g N2O GJ(-1)). These emission factors, which are much lower than the value of 120g N2O t(-1) (10.4g N2O GJ(-1)) used in the 2013 Swiss national greenhouse gas emission inventory, have been implemented in the most recent Swiss emission inventory. In addition, the isotopic composition of N2O emitted from the two plants with SNCR, which had considerable N2O emissions, was measured using quantum cascade laser spectroscopy. The isotopic site preference of N2O - the enrichment of (14)N(15)NO relative to (15)N(14)NO - was found to be 17.6 ± 0.8‰, with no significant difference between the two plants. Comparison to previous studies suggests SP of 17-19‰ may be characteristic for N2O produced from SNCR. Methane emissions were found to be insignificant, with a maximum emission factor of 2.5 ± 5.6g CH4 t(-1) (0.2 ± 0.5g CH4 GJ(-1)), which is expected due to high incinerator temperatures and efficient combustion. Copyright © 2014 Elsevier Ltd

  2. Solidification of coal mining wastes using pozzolanic fly ash

    Energy Technology Data Exchange (ETDEWEB)

    Laczny, J.M.; Dabrowska, L. [Inst. for Ecology of Industrial Areas, Katowice (Poland)

    2001-07-01

    A detailed analysis of chemical composition of porous waters in coal mining wastes and fly ashes has shown that there is a possibility of such alternate disposal which would facilitate forming a protective barrier, which due to reactions undergoing between chemical compounds of both phases would result in forming the so called 'reactive barrier'. This new solution is under patent procedure. 6 refs.

  3. Examination of the possibilities of the application of waste materials (gypsum, fly ash and bottom ash in construction

    Directory of Open Access Journals (Sweden)

    Trifunović Prvoslav

    2014-01-01

    Full Text Available The possibilities of the application of waste gypsum (citrogypsum, nitrogyosum and sulphogypsum, fly ash and bottom ash in construction: for production of gypsum binders (a-calcium sulphate hemihydrate, b-calcium sulphata hemihydrate and b-anhydrite, for obtaining construction products (bricks and blocks and as component materials for road layers were presented in this work. Also, the possibilities of the application of sulphogypsum (or FGD gypsum for solidification and stabilization of fly ash were presented. The obtained results could have great importance in both ecological and economic views (elimination of important pollutants of water, air and soil, replacement of natural by waste materials, reduction of waste disposal cost.

  4. Thermodynamic data for biomass conversion and waste incineration

    Energy Technology Data Exchange (ETDEWEB)

    Domalski, E.S.; Jobe, T.L. Jr; Milne, T.A.

    1986-09-01

    The general purpose of this collection of thermodynamic data of selected materials is to make property information available to the engineering community on chemical mixtures, polymers, composite materials, solid wastes, biomass, and materials not easily identifiable by a single stoichiometric formula. More than 700 materials have been compiled covering properties such as specific heat, gross heat of combustion, heat of fusion, heat of vaporization, and vapor pressure. The information was obtained from the master files of the NBS Chemical Thermodynamics Data Center, the annual issues of the Bulletin of Chemical Thermodynamics, intermittent examinations of the Chemical Abstracts subject indexes, individual articles by various authors, and other general reference sources. The compilation is organized into several broad categories; materials are listed alphabetically within each category. For each material, the physical state, information as to the composition or character of the material, the kind of thermodynamic property reported, the specific property values for the material, and citations to the reference list are given. In addition, appendix A gives an empirical formula that allows heats of combustion of carbonaceous materials to be predicted with surprising accuracy when the elemental composition is known. A spread sheet illustrates this predictability with examples from this report and elsewhere. Appendix B lists some reports containing heats of combustion not included in this publication. Appendix C contains symbols, units, conversion factors, and atomic weights used in evaluating and compiling the thermodynamic data.

  5. Combustion aerosols from municipal waste incineration - Effect of fuel feedstock and plant operation

    DEFF Research Database (Denmark)

    Zeuthen, J.H.; Pedersen, Anne Juul; Hansen, Jørn

    2007-01-01

    ( NaCl), batteries, and automotive shredder waste. Also, runs with different changes in the operational conditions of the incinerator were made. Mass- based particle size distributions were measured using a cascade impactor and the number- based size distributions were measured using a Scanning...... Mobility Particle Sizer. The plant is equipped with flue gas cleaning and the penetration through this was determined. The particle morphology was investigated by Transmission Electron Microscopy ( TEM) and chemical analysis of the aerosol particles was made by Energy Dispersive X- ray Spectroscopy ( EDS...

  6. Thermally induced transformations of iron oxide stabilised APC residues from waste incineration

    DEFF Research Database (Denmark)

    Sørensen, Mette Abildgaard; Koch, C.B.

    2001-01-01

    Air pollution control (APC) facilities at waste incinerator plants produce large quantities of solid residues rich in salts and heavy metals. Heavy metals are readily released to water from the residues and it has, therefore, been found suitable to apply a rapid co-precipitation/adsorption process...... as a means to immobilize the toxic elements. In the 'Ferrox process', this immobilization is based on co-precipitation with an Fe(III) oxide formed by oxidation of Fe(II) by air in an aqueous slurry with the APC residue at alkaline pH. In this work we have undertaken a Mossbauer spectroscopy study of the Fe...

  7. Testing of toxicology and emissions-sampling methodology for ocean incineration of hazardous wastes. Final report, January 1985-January 1986

    Energy Technology Data Exchange (ETDEWEB)

    Boehm, P.; Cooke, M.; Carr, S.; Piispanen, W.; Werme, C.

    1988-05-01

    This report addresses the development and testing of a system to expose marine organisms to hazardous-waste emissions in order to assess the potential toxicity of incinerator plumes at sea as they contact the marine environment through air-sea exchange and initial mixing. A sampling train was designed and tested at EPA's land-based hazardous-waste incinerator, using transformer oil as a waste feed. The incinerator was operated under conditions which would be appropriate for at-sea incinerators. The sampling train (Marine Incineration Biological Assessment Sampler--MIBAS) provides a sea-water sample containing a plume emission for the marine organisms testing. Five toxicity-test protocols were refined and/or developed for use in the program: (1) a sea-urchin fertilization test; (2) a chronic test using macroalgae Champia parvula; (3) a 7-day chronic test using growth and reproduction of the crustacean Mysidopsis bahia; (4) a 7-day growth and survival test with the fish Menidia beryllina; and (5) a 7-day life-cycle test using the archiannelid worm Dinophilus gyrocilatus. The results of applying these tests during a hazardous-waste burn are given.

  8. Decomposition of BFRs and emission of dioxins from co-incineration of MSW and electrical and electronic plastics waste

    Energy Technology Data Exchange (ETDEWEB)

    Borgnes, D.; Rikheim, B. [Kjelforeningen Norsk Energi, Oslo (Norway)

    2004-09-15

    The most common use for BFRs is in building materials, textiles and electronic supplies, e.g. TVs, PCs and photocopiers. In incineration plants with good combustion BFRs will decompose and form other brominated compounds, mainly hydrogen bromide (HBr). In addition, other brominated compounds will also be formed, such as dioxins where chlorine is fully or partly substituted by bromine (brominated and brominated/chlorinated dioxins). The Norwegian Ministry of the Environment presented in the autumn of 2002 a working plan for reducing the emissions and discharges of BFRs. One action is to investigate the emissions from incineration of waste containing BFRs. The objective of the project reported in this short paper was to investigate the emissions of dioxincompounds that may occur from incineration of plastic waste containing brominated flame retardants (BFRs) together with waste from households and the commercial sector. The decomposition of BFRs should also be investigated.

  9. Life-cycle-assessment of the historical development of air pollution control and energy recovery in waste incineration

    DEFF Research Database (Denmark)

    Damgaard, Anders; Riber, C.; Fruergaard, Thilde

    2010-01-01

    of the waste, but also the energy recovery efficiency has a large importance. The historical development of air pollution control in waste incineration was studied through life-cycle-assessment modelling of eight different air pollution control technologies. The results showed a drastic reduction...... in the release of air emissions and consequently a significant reduction in the potential environmental impacts of waste incineration. Improvements of a factor 0.85–174 were obtained in the different impact potentials as technology developed from no emission control at all, to the best available emission control...... technologies of today (2010). The importance of efficient energy recovery was studied through seven different combinations of heat and electricity recovery, which were modelled to substitute energy produced from either coal or natural gas. The best air pollution control technology was used at the incinerator...

  10. Air pollution abatement plan for dioxins from waste incineration in North-Rhine Westphalia ('EMDA'). Emissionsminderungsplan fuer Dioxine an Abfallverbrennungsanlagen in NRW (EMDA)

    Energy Technology Data Exchange (ETDEWEB)

    Stulgies, H. (Ministerium fuer Umwelt, Raumordnung und Landwirtschaft des Landes Nordrhein-Westfalen, Duesseldorf (Germany). Landesausschuss fuer Landwirtschaftliche Forschung, Erziehung und Wirtschaftsberatung)

    The Air Pollution Abatement Plan for Dioxins from Waste Incinerations (EMDA) is presented as a set of tools for redeveloping existing waste incinerators in North-Rhine-Westphalia as to their dioxin and furan emissions. In the article, the objective of the EMDA and its essential contents are described. (BBR).

  11. The incorporation of wood waste ash as a partial cement replacement material for making structural grade concrete: An overview

    Directory of Open Access Journals (Sweden)

    Swaptik Chowdhury

    2015-06-01

    Full Text Available With increasing industrialization, the industrial byproducts (wastes are being accumulated to a large extent, leading to environmental and economic concerns related to their disposal (land filling. Wood ash is the residue produced from the incineration of wood and its products (chips, saw dust, bark for power generation or other uses. Cement is an energy extensive industrial commodity and leads to the emission of a vast amount of greenhouse gases, forcing researchers to look for an alternative, such as a sustainable building practice. This paper presents an overview of the work and studies done on the incorporation of wood ash as partial replacement of cement in concrete from the year 1991 to 2012. The aspects of wood ash such as its physical, chemical, mineralogical and elemental characteristics as well as the influence of wood ash on properties such as workability, water absorption, compressive strength, flexural rigidity test, split tensile test, bulk density, chloride permeability, freeze thaw and acid resistance of concrete have been discussed in detail.

  12. Corrosion in waste incineration facilities; Korrosion i avfallsfoerbraenningsanlaeggningar

    Energy Technology Data Exchange (ETDEWEB)

    Staalenheim, Annika; Henderson, Pamela

    2004-11-01

    Waste is a heterogeneous fuel, often with high levels of chlorine, alkali and heavy metals. This leads to much more severe corrosion problems than combustion of fossil fuels. The corrosion rates of the materials used can be extremely high. Materials used for heat transferring parts are usually carbon steel or low alloyed steel. These are significantly cheaper than other steels. Austenitic stainless steel is also used, but is often avoided due to its sensitivity to stress corrosion cracking. More advanced materials, such as nickel base alloys, can be used in extremely aggressive environments. Since these materials are expensive and do not always have sufficient mechanical properties, they are often used as coatings on carbon steel tubes or as composite tubes. A new method, which shows good results at the first tests in plants, is electroplating with nickel. Plastic materials can be used in low temperature parts if the temperature does not exceed 150 deg C. A glass fibre inforced material is probably the best choice. The parts of the furnace that are most prone to corrosion are waterwalls where the refractory coating is lost, has not been applied to a sufficient height in the boiler or is not used at all. Failures of superheaters often occur in areas near soot blowers or on the tubes exposed to the highest flue gas temperatures. Few cases of low temperature corrosion are reported in the literature, possibly because these problems are unusual or because low temperature corrosion rarely causes costly and dramatic failures. Waterwall tubes should be made of carbon steel, because of the price and to minimise the risk for stress corrosion cracking. Usually the tubes must be covered with a more corrosion resistant material to withstand the environment in the boiler. Metal coatings can be used in less demanding environments. Refractory is probably the best protection for waterwalls from severe erosion. Surfaces in extremely corrosive areas, e.g. the fuel feed area, should

  13. Dioxine and PAH-emissions from private incineration of wastes; Dioxin- und PAK-Emissionen der privaten Abfallverbrennung: Umwelt-Materialien Nr. 172 Luft

    Energy Technology Data Exchange (ETDEWEB)

    Nussbaumer, T.

    2004-07-01

    This report published by the Swiss Agency for the Environment, Forests and Landscape (SAEFL) presents the results of a literature study and situation analysis on the burning of wastes at the domestic level. The private burning of municipal solid waste, urban waste wood and other wastes as a potential source of toxic emissions and residues is discussed. Beside the heavy metals found in ash and flue gas, the paper looks at organic substances such as polycyclic aromatic hydrocarbons (PAH) and polychlorinated dibenzo-p-dioxines and polychlorinated dibenzofuranes (PCDD/F) that can be emitted in relevant concentrations. The aim of the study - to evaluate emission factors of PCDD/F and PAH from private waste incineration in wood stoves and boilers, in barrels, and in open fires - is discussed. A survey of recent investigations in Europe and the United States and the correlation between the most relevant emission factors is looked at. Critical situations leading to extremely high PCDD/F emissions are described.

  14. Testing cleanable/reuseable HEPA prefilters for mixed waste incinerator air pollution control systems

    Energy Technology Data Exchange (ETDEWEB)

    Burns, D.B.; Wong, A.; Walker, B.W.; Paul, J.D. [Westinghouse Savannah River Co., Aiken, SC (United States)

    1997-08-01

    The Consolidated Incineration Facility (CIF) at the US DOE Savannah River Site is undergoing preoperational testing. The CIF is designed to treat solid and liquid RCRA hazardous and mixed wastes from site operations and clean-up activities. The technologies selected for use in the air pollution control system (APCS) were based on reviews of existing incinerators, air pollution control experience, and recommendations from consultants. This approach resulted in a facility design using experience from other operating hazardous/radioactive incinerators. In order to study the CIF APCS prior to operation, a 1/10 scale pilot facility, the Offgas Components Test Facility (OCTF), was constructed and has been in operation since late 1994. Its mission is to demonstrate the design integrity of the CIF APCS and optimize equipment/instrument performance of the full scale production facility. Operation of the pilot facility has provided long-term performance data of integrated systems and critical facility components. This has reduced facility startup problems and helped ensure compliance with facility performance requirements. Technical support programs assist in assuring all stakeholders the CIF can properly treat combustible hazardous, mixed, and low-level radioactive wastes. High Efficiency Particulate Air (HEPA) filters are used to remove hazardous and radioactive particulates from the exhaust gas strewn before being released into the atmosphere. The HEPA filter change-out frequency has been a potential issue and was the first technical issue to be studied at the OCTF. Tests were conducted to evaluate the performance of HEPA filters under different operating conditions. These tests included evaluating the impact on HEPA life of scrubber operating parameters and the type of HEPA prefilter used. This pilot-scale testing demonstrated satisfactory HEPA filter life when using cleanable metal prefilters and high flows of steam and water in the offgas scrubber. 8 figs., 2 tabs.

  15. Estimating Particulate Exposure from Modern Municipal Waste Incinerators in Great Britain.

    Science.gov (United States)

    Douglas, Philippa; Freni-Sterrantino, Anna; Leal Sanchez, Maria; Ashworth, Danielle C; Ghosh, Rebecca E; Fecht, Daniela; Font, Anna; Blangiardo, Marta; Gulliver, John; Toledano, Mireille B; Elliott, Paul; de Hoogh, Kees; Fuller, Gary W; Hansell, Anna L

    2017-07-05

    Municipal Waste Incineration (MWI) is regulated through the European Union Directive on Industrial Emissions (IED), but there is ongoing public concern regarding potential hazards to health. Using dispersion modeling, we estimated spatial variability in PM10 concentrations arising from MWIs at postcodes (average 12 households) within 10 km of MWIs in Great Britain (GB) in 2003-2010. We also investigated change points in PM10 emissions in relation to introduction of EU Waste Incineration Directive (EU-WID) (subsequently transposed into IED) and correlations of PM10 with SO2, NOx, heavy metals, polychlorinated dibenzo-p-dioxins/furan (PCDD/F), polycyclic aromatic hydrocarbon (PAH) and polychlorinated biphenyl (PCB) emissions. Yearly average modeled PM10 concentrations were 1.00 × 10(-5) to 5.53 × 10(-2) μg m(-3), a small contribution to ambient background levels which were typically 6.59-2.68 × 10(1) μg m(-3), 3-5 orders of magnitude higher. While low, concentration surfaces are likely to represent a spatial proxy of other relevant pollutants. There were statistically significant correlations between PM10 and heavy metal compounds (other heavy metals (r = 0.43, p = <0.001)), PAHs (r = 0.20, p = 0.050), and PCBs (r = 0.19, p = 0.022). No clear change points were detected following EU-WID implementation, possibly as incinerators were operating to EU-WID standards before the implementation date. Results will be used in an epidemiological analysis examining potential associations between MWIs and health outcomes.

  16. Research paper 2000-B-1: the implementation of the municipal waste incineration directive (89/429) in France

    Energy Technology Data Exchange (ETDEWEB)

    Schucht, S.

    2000-07-01

    This paper constitutes a contribution to the project 'IMPOL - The Implementation of EU Environmental Policies: Efficiency Issues'. The paper deals with the implementation of the EU Directives directed at atmospheric emissions from new (89/369/EEC) and existing (89/429/EEC) municipal waste incineration plants in France. The goal of this paper is twofold: a historic review of the implementation processes and their evaluation following economic criteria of environmental effectiveness and economic efficiency. The focus is on the implementation of the Directives' requirements towards existing municipal waste incineration plants, i.e. those plants having received their operation licence after December 1, 1990. For France we find a general picture of poor compliance. This result has to be differentiated, though: the current compliance rate of plants of a capacity above 6 t/h is almost 100% (although compliance often came late) while the majority of smaller plants does not comply with the Directive's requirements. With a waste incineration park of about 250 plants currently, many of which are very small plants and only treat weak amounts of waste, France constitutes an exception compared to other European countries. A further specific characteristic of France is the high share of waste incineration in total waste treatment (especially in the big cities) which amounts to almost 40%. The outline of the paper is the following: chapter two gives some context information on the French municipal waste incineration plant park and its structure, on the development of waste quantities, on the legal framework and on available subsidy schemes. Chapter three assesses environmental effectiveness, i.e. goal attainment and factors explaining the results. Chapter four comprises the assessment of cost efficiency. Chapter five contains the historic review, i.e. a characterisation of the implementation process, and chapter six concludes, linking the characterisation of

  17. Geopolymerisation of fly ashes with waste aluminium anodising etching solutions.

    Science.gov (United States)

    Ogundiran, M B; Nugteren, H W; Witkamp, G J

    2016-10-01

    Combined management of coal combustion fly ash and waste aluminium anodising etching solutions using geopolymerisation presents economic and environmental benefits. The possibility of using waste aluminium anodising etching solution (AES) as activator to produce fly ash geopolymers in place of the commonly used silicate solutions was explored in this study. Geopolymerisation capacities of five European fly ashes with AES and the leaching of elements from their corresponding geopolymers were studied. Conventional commercial potassium silicate activator-based geopolymers were used as a reference. The geopolymers produced were subjected to physical, mechanical and leaching tests. The leaching of elements was tested on 28 days cured and crushed geopolymers using NEN 12457-4, NEN 7375, SPLP and TCLP leaching tests. After 28 days ambient curing, the geopolymers based on the etching solution activator showed compressive strength values between 51 and 84 MPa, whereas the commercial potassium silicate based geopolymers gave compressive strength values between 89 and 115 MPa. Based on the regulatory limits currently associated with the used leaching tests, all except one of the produced geopolymers (with above threshold leaching of As and Se) passed the recommended limits. The AES-geopolymer geopolymers demonstrated excellent compressive strength, although less than geopolymers made from commercial activator. Additionally, they demonstrated low element leaching potentials and therefore can be suitable for use in construction works. Copyright © 2016. Published by Elsevier Ltd.

  18. PCDD/F emissions during startup and shutdown of a hazardous waste incinerator.

    Science.gov (United States)

    Li, Min; Wang, Chao; Cen, Kefa; Ni, Mingjiang; Li, Xiaodong

    2017-08-01

    Compared with municipal solid waste incineration, studies on the PCDD/F emissions of hazardous waste incineration (HWI) under transient conditions are rather few. This study investigates the PCDD/F emission level, congener profile and removal efficiency recorded during startup and shutdown by collecting flue gas samples at the bag filter inlet and outlet and at the stack. The PCDD/F concentration measured in the stack gas during startup and shutdown were 0.56-4.16 ng I-TEQ Nm(-3) and 1.09-3.36 ng I-TEQ Nm(-3), respectively, far exceeding the present codes in China. The total amount of PCDD/F emissions, resulting from three shutdown-startup cycles of this HWI-unit is almost equal to that generated during one year under normal operating conditions. Upstream the filter, the PCDD/F in the flue gas is mainly in the particle phase; however, after being filtered PCDD/F prevails in the gas phase. The PCDD/F fraction in the gas phase even exceeds 98% after passing through the alkaline scrubber. Especially higher chlorinated PCDD/F accumulate on inner walls of filters and ducts during these startup periods and could be released again during normal operation, significantly increasing PCDD/F emissions. Copyright © 2017. Published by Elsevier Ltd.

  19. Synthetic aggregates from combustion ashes using an innovative rotary kiln.

    Science.gov (United States)

    Wainwright, P J; Cresswell, D J

    2001-01-01

    This paper describes the use of a number of different combustion ashes to manufacture synthetic aggregates using an innovative rotary 'Trefoil' kiln. Three types of combustion ash were used, namely: incinerated sewage sludge ash (ISSA); municipal solid waste incinerator bottom ash (MSWIBA-- referred to here as BA); and pulverised fuel ash (Pfa). The fine waste ash fractions listed above were combined with a binder to create a plastic mix that was capable of being formed into 'green pellets'. These pellets were then fired in a Trefoil kiln to sinter the ashes into hard fused aggregates that were then tested for use as a replacement for the natural coarse aggregate in concrete. Results up to 28 days showed that these synthetic aggregates were capable of producing concretes with compressive strengths ranging from 33 to 51 MPa, equivalent to between 73 and 112% of that of the control concrete made with natural aggregates.

  20. Inventory Analysis and Social Life Cycle Assessment of Greenhouse Gas Emissions from Waste-to-Energy Incineration in Taiwan

    Directory of Open Access Journals (Sweden)

    Yu-Tsang Lu

    2017-10-01

    Full Text Available Waste-to-energy (WtE incineration technology is widely used to solve the energy supply, greenhouse gas emissions, and waste generation problems in urban areas. In Taiwan, there are new laws and regulations that would affect greenhouse gas management of WtE incineration plants. This research aims to identify or raise key issues to be promoted for WtE incineration plants due to existing management systems and complex issues mixed with GHG, energy, and solid waste treatment. This study utilizes inventory analysis and social LCA (SLCA approach on GHG management of WtE incineration plants in Taiwan to systematically identify materiality issues to be promoted. According to the results of materiality analysis for SLCA, this study generalizes four stakeholders, nine subcategories, and their 15 inventory indicators; and concludes that, among assessment results of 15 inventory indicators, three indicators are at a high level, four at a medium level, and eight at a low level. In total, 12 materiality issues are recognized. This study suggests WtE incineration plants should consider the following materiality issues with respect to priority: a systematic database and calculation methods, the goal and criteria of the laws and regulations, technology development toward circular economy and promotion activity or opportunity for local community and organization level.

  1. Electrical efficiency in waste incineration plants - Turgi case study; Elektrizitaetseffizienz in Kehrichtverwertungsanlagen - Fallbeispiel KVA Turgi

    Energy Technology Data Exchange (ETDEWEB)

    Haenny, D.; Schnyder, G.

    2004-07-01

    This final report for the Swiss Federal Office of Energy (SFOE) presents the results of a study made on the more efficient use of electricity in the waste incineration plant in Turgi, Switzerland. Using this plant as a model, an evaluation of the potential for increasing efficiencies in the area of electricity consumption was carried out. All energy-relevant processes and technologies were analysed on site in order to draw up a catalogue of optimisation measures. The measures described were evaluated and classified, whereby their feasibility and economic viability were taken into account. The electricity savings potential for the Turgi plant was extrapolated: the potential increase in efficiency in all thermal waste treatment plants in Switzerland indicates annual savings of around 38 GWh, which is equivalent to the electricity consumption of around 10,000 private households.

  2. A chemical basis for the partitioning of radionuclides in incinerator operation

    Energy Technology Data Exchange (ETDEWEB)

    Burger, L.L.

    1994-09-01

    For waste containing small amounts of radioactivity, rad waste (RW), or mixed waste (MW) containing both radioactive and chemically hazardous components, incineration is a logical management candidate because of inherent safety, waste volume reduction, and low costs. Successful operation requires that the facility is properly designed and operated to protect workers and to limit releases of hazardous materials. The large decrease in waste volume achieved by incineration also results in a higher concentration of most of the radionuclides and non radioactive heavy metals in the ash products. These concentrations impact subsequent treatment and disposal. The various constituents (chemical elements) are not equal in concentration in the various incinerator feed materials, nor are they equal in their contribution to health risks on subsequent handling, or accidental release. Thus, for management of the wastes it is important to be able to predict how the nuclides partition between the primary combustion residue which may be an ash or a fused slag, the fine particulates or fly ash that is trapped in the burner off-gas by several different techniques, and the airborne fraction that escapes to the atmosphere. The objective of this report is to provide an estimate of how different elements of concern may behave in the chemical environment of the incinerator. The study briefly examines published incinerator operation data, then considers the properties of the elements of concern, and employs thermodynamic calculations, to help predict the fate of these RW and MW constituents. Many types and configurations of incinerators have been designed and tested.

  3. Global warming potential of material fractions occurring in source-separated organic household waste treated by anaerobic digestion or incineration under different framework conditions.

    Science.gov (United States)

    Naroznova, Irina; Møller, Jacob; Scheutz, Charlotte

    2016-12-01

    This study compared the environmental profiles of anaerobic digestion (AD) and incineration, in relation to global warming potential (GWP), for treating individual material fractions that may occur in source-separated organic household waste (SSOHW). Different framework conditions representative for the European Union member countries were considered. For AD, biogas utilisation with a biogas engine was considered and two potential situations investigated - biogas combustion with (1) combined heat and power production (CHP) and (2) electricity production only. For incineration, four technology options currently available in Europe were covered: (1) an average incinerator with CHP production, (2) an average incinerator with mainly electricity production, (3) an average incinerator with mainly heat production and (4) a state-of-the art incinerator with CHP working at high energy recovery efficiencies. The study was performed using a life cycle assessment in its consequential approach. Furthermore, the role of waste-sorting guidelines (defined by the material fractions allowed for SSOHW) in relation to GWP of treating overall SSOHW with AD was investigated. A case-study of treating 1tonne of SSOHW under framework conditions in Denmark was conducted. Under the given assumptions, vegetable food waste was the only material fraction which was always better for AD compared to incineration. For animal food waste, kitchen tissue, vegetation waste and dirty paper, AD utilisation was better unless it was compared to a highly efficient incinerator. Material fractions such as moulded fibres and dirty cardboard were attractive for AD, albeit only when AD with CHP and incineration with mainly heat production were compared. Animal straw, in contrast, was always better to incinerate. Considering the total amounts of individual material fractions in waste generated within households in Denmark, food waste (both animal and vegetable derived) and kitchen tissue are the main material

  4. UK: Technical data for waste incineration background for modelling of product-specific emissions in a life cycle assessment context

    DEFF Research Database (Denmark)

    Hauschild, Michael Zwicky

    UK: In life cycle assessment (LCA) the environmental impacts from a product are assessed throughout the entire life-cycle of the product, i.e. from the extraction of the raw materials from which the product is made through manufacture and use of the product to the final disposal of the product...... and possible recycling hereof. The assessment is based on an inventory of inputs and outputs (resource/material consumption and generation of energy and emissions) for all the processes that occur as part of the product life-cycle. A model is developed to estimate the inputs and outputs associated...... with the disposal of a product through waste incineration. Based on knowledge of the material composition of the product and the technology applied in the waste incineration plant, the model estimates input of energy and auxiliary materials required for the incineration of the product and generation of energy...

  5. Technical data for waste incineration - background for modelling of product-specific emissions in a life cycle assessment context

    DEFF Research Database (Denmark)

    Erichsen, Hanne; Hauschild, Michael Zwicky

    In life cycle assessment (LCA) the environmental impacts from a product are assessed throughout the entire life-cycle of the product, i.e. from the extraction of the raw materials from which the product is made through manufacture and use of the product to the final disposal of the product...... and possible recycling hereof. The assessment is based on an inventory of inputs and outputs (resource/material consumption and generation of energy and emissions) for all the processes that occur as part of the product life-cycle. A model is developed to estimate the inputs and outputs associated...... with the disposal of a product through waste incineration. Based on knowledge of the material composition of the product and the technology applied in the waste incineration plant, the model estimates input of energy and auxiliary materials required for the incineration of the product and generation of energy...

  6. Effect of grinding process on the level of leachability of the contaminants from the fly ashes from combustion of biomass

    OpenAIRE

    Pawluk Aleksandra

    2016-01-01

    The most commonly used renewable energy source in Polish energy production companies is solid biomass which is used both as a separate fuel or as a component co-incinerated together with (mostly) hard coal. During its incineration the biomass generates by-products with diverse and variable physicochemical properties. The most of the waste from production of electricity and/or heat are fly ashes. The fly ashes from combustion of biomass are a particular kind of waste distinguished by high leve...

  7. Effects of heat recovery for district heating on waste incineration health impact: a simulation study in Northern Italy.

    Science.gov (United States)

    Cordioli, Michele; Vincenzi, Simone; De Leo, Giulio A

    2013-02-01

    The construction of waste incinerators in populated areas always causes substantial public concern. Since the heat from waste combustion can be recovered to power district heating networks and allows for the switch-off of domestic boilers in urbanized areas, predictive models for health assessment should also take into account the potential benefits of abating an important source of diffuse emission. In this work, we simulated the dispersion of atmospheric pollutants from a waste incinerator under construction in Parma (Italy) into different environmental compartments and estimated the potential health effect of both criteria- (PM(10)) and micro-pollutants (PCDD/F, PAH, Cd, Hg). We analyzed two emission scenarios, one considering only the new incinerator, and the other accounting for the potential decrease in pollutant concentrations due to the activation of a district heating network. We estimated the effect of uncertainty in parameter estimation on health risk through Monte Carlo simulations. In addition, we analyzed the robustness of health risk to alternative assumptions on: a) the geographical origins of the potentially contaminated food, and b) the dietary habits of the exposed population. Our analysis showed that under the specific set of assumptions and emission scenarios explored in the present work: (i) the proposed waste incinerator plant appears to cause negligible harm to the resident population; (ii) despite the net increase in PM(10) mass balance, ground-level concentration of fine particulate matter may be curbed by the activation of an extensive district heating system powered through waste combustion heat recovery and the concurrent switch-off of domestic/industrial heating boilers. In addition, our study showed that the health risk caused by waste incineration emissions is sensitive to assumptions about the typical diet of the resident population, and the geographical origins of food production. Copyright © 2012 Elsevier B.V. All rights reserved.

  8. PCDD/Fs atmospheric deposition fluxes and soil contamination close to a municipal solid waste incinerator.

    Science.gov (United States)

    Vassura, Ivano; Passarini, Fabrizio; Ferroni, Laura; Bernardi, Elena; Morselli, Luciano

    2011-05-01

    Bulk depositions and surface soil were collected in a suburban area, near the Adriatic Sea, in order to assess the contribution of a municipal solid waste incinerator to the area's total contamination with polychlorinated dibenzodioxins and polychlorinated dibenzofurans (PCDDs and PCDFs). Samples were collected at two sites, situated in the area most affected by plant emissions (according to the results of the Calpuff air dispersion model), and at an external site, considered as a reference. Results show that the studied area is subject to low contamination, as far as these compounds are concerned. Deposition fluxes range from 14.3 pg m(-2)d(-1) to 89.9 pg m(-2)d(-1) (0.75 pg-TEQ m(-2)d(-1) to 3.73 pg-TEQ m(-2)d(-1)) and no significant flow differences are observed among the three monitored sites. Total soil concentration amounts to 93.8 ng kg(-1) d.w. and 1.35 ng-TEQ kg(-1)d.w, on average, and confirms a strong homogeneity in the studied area. Furthermore, from 2006 to 2009, no PCDD/Fs enrichment in the soil was noticed. Comparing the relative congener distributions in environmental samples with those found in stack emissions from the incineration plant, significant differences are observed in the PCDD:PCDF ratio and in the contribution of the most chlorinated congeners. From this study we can conclude that the incineration plant is not the main source of PCDD/Fs in the studied area, which is apparently characterized by a homogeneous and widespread contamination situation, typical of an urban area. Copyright © 2011 Elsevier Ltd. All rights reserved.

  9. Application of CFD in Investigation of Ventilation Strategies for Improvement of Working Environment in a Waste Incineration Plant

    DEFF Research Database (Denmark)

    Heiselberg, Per; Svidt, Kjeld; Kragh, Hans

    In this study CFD was applied to investigate the ability of different ventilation systems and strategies to improve working conditions in a waste incineration plant. The plant, VS Amagerforbn:ending, had expanded to supply both district heating and power. Because of that too high temperatures were...... generated in the working zones and measures to reduce these levels had to be taken ....

  10. Bulk deposition close to a Municipal Solid Waste incinerator: one source among many.

    Science.gov (United States)

    Venturini, Elisa; Vassura, Ivano; Ferroni, Laura; Raffo, Simona; Passarini, Fabrizio; Beddows, David C S; Harrison, Roy M

    2013-07-01

    In order to assess the contribution of a Municipal Solid Waste incinerator to the area's total contamination, metals and soluble ions have been determined in bulk deposition collected at sites affected by different levels of plant emissions, according to the results of the Calpuff air dispersion model. Results show that in general fluxes monitored at the different sites during the same period are quite similar for each analyte. Deposition fluxes of nitrite and ammonium are significantly lower at the more distant site, while copper is significantly higher at this site, possibly because of copper fungicide used on the nearby agriculture land. The presence of sea spray and resuspended soil dust can be inferred from Pearson correlation coefficients, while enrichment factors indicate that Cu, Pb and Zn have a probable anthropogenic origin. A more complete evaluation of the sources affecting the area was obtained with PMF analysis. The sources associated with each factor were identified from the source profile and temporal trends. Six factors were identified, three sources associate with natural matrices, while three factors represent anthropogenic sources. The greatest contribution of heavy metals, the most toxic and persistent components determined, is associated with resuspended soil dust, especially when weighted according to their toxicity. The anthropogenic source contribution is similar at all sites, and therefore the incinerator's relative contribution to the total pollutant load appears to be negligible compared to other sources affecting the area. Copyright © 2013 Elsevier B.V. All rights reserved.

  11. Health risk assessment of PCDD/F emissions from municipal solid waste incinerators (MSWIs) in China.

    Science.gov (United States)

    Jin, Yu-Qi; Liu, Hong-Mei; Li, Xiao-Dong; Ma, Xiao-Jun; Lu, Sheng-Yong; Chen, Tong; Yan, Jian-Hua

    2012-12-01

    The objectives of this study were to determine the environmental impacts of polychlorinated dibenzo-p-dioxin and polychlorinated dibenzofuran (PCDD/Fs) emitted from two typical municipal solid-waste incinerators (MSWIs), named M and L, in China. The main differences between the two MSWIs relate to incineration technologies, treatment capacities, emission standards and meteorological conditions. The distribution of PCDD/Fs in the surrounding ambient air and soils of the MWSIs were monitored and compared. In addition, air dispersion models and health risk assessments were combined to determine the behaviour and transport of PCDD/Fs. The results indicated that higher PCDD/F emission levels resulted in higher concentrations in the surrounding environment. The average PCDD/F levels emitted from the M MSWI was about seven times higher than those emitted from the L MSWI and about 10 times and 2 times higher in air and soils, respectively. The simulation results were similar to the trend of the monitored results. Both the observed and the simulation results suggested that the atmospheric pollution by PCDD/F surrounding the M MSWI was relatively serious; the environmental impact of the L MSWI was not significant.

  12. Study of air pollution in the proximity of a waste incinerator

    Energy Technology Data Exchange (ETDEWEB)

    Barrera, V. [Department of Physics and Astronomy – University of Florence, Via G. Sansone 1, 50019 Sesto Fiorentino (Italy); Calzolai, G. [Department of Physics and Astronomy – University of Florence, Via G. Sansone 1, 50019 Sesto Fiorentino (Italy); National Institute of Nuclear Physics (INFN) – Florence, Via G. Sansone 1, 50019 Sesto Fiorentino (Italy); Chiari, M. [National Institute of Nuclear Physics (INFN) – Florence, Via G. Sansone 1, 50019 Sesto Fiorentino (Italy); Lucarelli, F., E-mail: lucarelli@fi.infn.it [Department of Physics and Astronomy – University of Florence, Via G. Sansone 1, 50019 Sesto Fiorentino (Italy); National Institute of Nuclear Physics (INFN) – Florence, Via G. Sansone 1, 50019 Sesto Fiorentino (Italy); Nava, S.; Giannoni, M. [National Institute of Nuclear Physics (INFN) – Florence, Via G. Sansone 1, 50019 Sesto Fiorentino (Italy); Becagli, S.; Frosini, D. [Department of Chemistry – University of Florence, Via della Lastruccia 3, 50019 Sesto Fiorentino (Italy)

    2015-11-15

    Montale is a small town in Tuscany characterised by high PM10 levels. Close to the town there is a waste incinerator plant. There are many concerns in the population and in the press about the causes of the high levels of pollution in this area. Daily PM10 samples were collected for 1 year by the FAI Hydra Dual sampler and analysed by different techniques in order to obtain a complete chemical speciation (elements by PIXE and ICP-MS, ions by Ion Chromatography, elemental and organic carbon by a thermo-optical instrument); hourly fine (<2.5 μm) and coarse (2.5–10 μm) PM samples were collected for shorter periods by the Streaker sampler and hourly elemental concentrations were obtained by PIXE analysis. Positive Matrix Factorization identified and quantified the major aerosol sources. Biomass burning turned out to be the most important source with an average percentage contribution to PM10 of 27% of and even higher percentages during the winter period when there are the highest PM10 concentrations. The contribution of the incinerator source has been estimated as about 6% of PM10.

  13. Utilization of coal fly ash in solidification of liquid radioactive waste from research reactor.

    Science.gov (United States)

    Osmanlioglu, Ahmet Erdal

    2014-05-01

    In this study, the potential utilization of fly ash was investigated as an additive in solidification process of radioactive waste sludge from research reactor. Coal formations include various percentages of natural radioactive elements; therefore, coal fly ash includes various levels of radioactivity. For this reason, fly ashes have to be evaluated for potential environmental implications in case of further usage in any construction material. But for use in solidification of radioactive sludge, the radiological effects of fly ash are in the range of radioactive waste management limits. The results show that fly ash has a strong fixing capacity for radioactive isotopes. Specimens with addition of 5-15% fly ash to concrete was observed to be sufficient to achieve the target compressive strength of 20 MPa required for near-surface disposal. An optimum mixture comprising 15% fly ash, 35% cement, and 50% radioactive waste sludge could provide the solidification required for long-term storage and disposal. The codisposal of radioactive fly ash with radioactive sludge by solidification decreases the usage of cement in solidification process. By this method, radioactive fly ash can become a valuable additive instead of industrial waste. This study supports the utilization of fly ash in industry and the solidification of radioactive waste in the nuclear industry.

  14. Municipal waste management in Italy. Incinerators; Impianti di smaltimento. Indagine sui termoutilizzatori RU (rifiuti urbani)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-09-01

    In this work are reported the data related to the incineration plants of municipal wastes in Italy. Technologies, energy production, air pollution monitoring and emission analysis are here considered. [Italian] L'obiettivo di questo lavoro e' proseguire e sviluppare l'analisi presentata per la prima volta da Federambiente nel 1998 che riguarda il parco impianti incenerimento dei rifiuti urbani e assimilabili presenti o presenti su tutto il territorio nazionale. I dati sono riferiti a 63 impianti ed aggiornati al 1999. Sono state trattate le tecnologie utilizzate dai forni, le capacita', le quantita' trattate nel 1998 e 1999, la produzione energetica e, particolare enfasi e' stata data all'analisi delle emissioni, con riferimento alla normativa vigente.

  15. Impact of Capital and Current Costs Changes of the Incineration Process of the Medical Waste on System Management Cost

    Science.gov (United States)

    Jolanta Walery, Maria

    2017-12-01

    The article describes optimization studies aimed at analysing the impact of capital and current costs changes of medical waste incineration on the cost of the system management and its structure. The study was conducted on the example of an analysis of the system of medical waste management in the Podlaskie Province, in north-eastern Poland. The scope of operational research carried out under the optimization study was divided into two stages of optimization calculations with assumed technical and economic parameters of the system. In the first stage, the lowest cost of functioning of the analysed system was generated, whereas in the second one the influence of the input parameter of the system, i.e. capital and current costs of medical waste incineration on economic efficiency index (E) and the spatial structure of the system was determined. Optimization studies were conducted for the following cases: with a 25% increase in capital and current costs of incineration process, followed by 50%, 75% and 100% increase. As a result of the calculations, the highest cost of system operation was achieved at the level of 3143.70 PLN/t with the assumption of 100% increase in capital and current costs of incineration process. There was an increase in the economic efficiency index (E) by about 97% in relation to run 1.

  16. The High Teperature Influence on Geopolymer Fly Ash Mixture’s Compressisive Strength with Insudtrial Waste Material Substitution

    Science.gov (United States)

    Bayuaji, R.; Wibowo, B.; Subekti, S.; Santoso, S. E.; Hardiyanto, E.; Kaelani, Y.; Mallu, L. L.

    2017-11-01

    This research aimed to figure out the influence of fly ash mixture from the industrial waste at the temperatures of 150°C, 450°C, 750°C viewed from the strength and resistance of geopolymer paste. As a result, cement will be substituted by industrial waste like fly ash. This experimental research was conducted on the mix design of geopolymer concrete which was made by dimension with 2.5 cm in diameter and 5 cm in height from four mixture composition of fly ash and industrial waste i.e. 100% fly ash, 50% fly ash+50% bottom ash, 50% fly ash+50% sandblast, and 50% fly ash+50% carbide waste. Each mixture was tested in terms of porosity and compressive strength. In conclusion, in the mixture of 50% fly ash+50% Sandblast and 50% fly ash+50% bottom ash in 12 molars, 1.5 activator comparison can be used to substitute fly ash at high temperature. Meanwhile, the mixture of 50% fly ash+50% carbide waste in 8 molars, 0.5 activator comparison has very small strength remaining if it is compared to the mixture of fly ash and other industrial waste (Bottom ash and Sandblast). The performance of mixture paste of 50% fly ash+50% carbide waste was very vulnerable after being burnt. Consequently, it cannot be used as the main structure at high temperature.

  17. Remedial Measures for Erroneous Environmental Policies: Assessing Infrastructure Projects of Waste-to-Energy Incineration in Taiwan with a Case Study of the Taitung Incinerator

    Directory of Open Access Journals (Sweden)

    Lih-Ren Liu

    2016-12-01

    Full Text Available Taiwan, like many other countries, often incentivizes private investors to participate in the construction of infrastructures for environmental protection. The build-operate-transfer (BOT or build-operate-own (BOO model of financing public infrastructure was introduced to Taiwan in the 1990s. Among them, the construction of incinerators to treat the municipal solid waste using the BOT/BOO model was quite a success in the beginning. With the socio-technical change of lifestyle and waste generation, the amount of amount of trash dropped dramatically. The policy failed eventually, however, because the government over-estimated the trash quantity and refrained from inter-municipality cooperation to treat trash efficiently. This failure triggered a rash of intense debates and legal disputes. In the case of the Taitung incinerator, the 26th incinerator located in southeastern Taiwan, the arbitration resulted in the government making significant compensation payments to the private sector. The finished construction was consequently converted into a “mothballed and pensioned off” facility. This study applies in-depth interviews and literature review to discuss aspects contributing to the policy failure and proposes some possible remedial measures. Five aspects are summarized, namely, the administrative organization’s rigid attitude, the irrationality of the BOT/BOO contracts, the loss of the spirit of BOO partnerships, the heavy financial burden on local government, and the abandonment of inter-municipality cooperation. The remedial measures for the policy failure are presented in the form of thorough policy evaluation, room for contract adjustments under the BOT/BOO model, encouragement of cross-boundary cooperation, and revision of the legal framework for implementing decentralization.

  18. Regular recycling of wood ash to prevent waste production. RecAsh - A Life-environment demonstration project

    Energy Technology Data Exchange (ETDEWEB)

    Andersson, Lars; Emilsson, Stig [Regional Forestry Board of Vaermland-Oerebro, Karlstad (Sweden)

    2005-07-01

    At present, the extraction of harvest residues is predicted to increase in Sweden and Finland. As an effect of the intensified harvest, the export of nutrients and acid buffering substances from the growth site is also increased. Wood ash could be used to compensate forest soils for such losses. Most wood fuel ash is today deposited in landfills. If the wood ash is recycled, wood energy is produced without any significant waste production. Ash recycling would therefore contribute to decreasing the production of waste, and to maintaining the chemical quality of forest waters and biological productivity of forest soils in the long term. In order to create better conditions for a regular recycling of wood, the Regional Forestry Board of Vaermland - Oerebro and the National Board of Forestry took the initiative for creating a LIFE-Environment demonstration project. The project will develop, analyse and demonstrate at least two regular ash-recycling systems. It will also distribute knowledge gathered about motives for ash recycling as well as technical and administrative solutions through a range of media (handbooks, workshops, field demonstrations, reports, web page and information videos). Hopefully, the project will contribute to decreasing waste problems related to bio-energy production in the EU at large.

  19. Risk of cancer in the vicinity of municipal solid waste incinerators: importance of using a flexible modelling strategy

    Directory of Open Access Journals (Sweden)

    Goria Sarah

    2009-05-01

    Full Text Available Abstract Background We conducted an ecological study in four French administrative departments and highlighted an excess risk in cancer morbidity for residents around municipal solid waste incinerators. The aim of this paper is to show how important are advanced tools and statistical techniques to better assess weak associations between the risk of cancer and past environmental exposures. Methods The steps to evaluate the association between the risk of cancer and the exposure to incinerators, from the assessment of exposure to the definition of the confounding variables and the statistical analysis carried out are detailed and discussed. Dispersion modelling was used to assess exposure to sixteen incinerators. A geographical information system was developed to define an index of exposure at the IRIS level that is the geographical unit we considered. Population density, rural/urban status, socio-economic deprivation, exposure to air pollution from traffic and from other industries were considered as potential confounding factors and defined at the IRIS level. Generalized additive models and Bayesian hierarchical models were used to estimate the association between the risk of cancer and the index of exposure to incinerators accounting for the confounding factors. Results Modelling to assess the exposure to municipal solid waste incinerators allowed accounting for factors known to influence the exposure (meteorological data, point source characteristics, topography. The statistical models defined allowed modelling extra-Poisson variability and also non-linear relationships between the risk of cancer and the exposure to incinerators and the confounders. Conclusion In most epidemiological studies distance is still used as a proxy for exposure. This can lead to significant exposure misclassification. Additionally, in geographical correlation studies the non-linear relationships are usually not accounted for in the statistical analysis. In studies of

  20. Incineration of household wastes in France, situation in the year 2000, evolution and perspectives in December 31, 2002; Incineration des dechets menagers en France, situation en 2000, evolution et perspectives au 31.12.2002

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2003-07-01

    This document is the result of the working group 'thermal treatment' of the French general association of municipal hygienists and technicians (AGHTM). It makes a status of the incineration of municipal wastes in France: 1 - general considerations: waste resources, place of incineration in a global approach of waste management, regulation; 2 - methodology of information gathering: information sources, methodology and field of the inquiry - status in the year 2000, representativeness of results; 3 - inquiry analysis and results: facilities, distribution with respect to the type of waste, type of furnaces, smokes treatment, management of residues, energy valorization; 4 - works in progress: best available techniques, sanitary impact of incineration facilities, residues of thermal processes, vitrification (Vivaldi program), technical specifications of facilities, greenhouse effect; conclusion; appendixes. (J.S.)

  1. Immobilization and volume reduction of heavy metals in municipal solid waste fly ash using nano-size calcium and iron-dispersed reagent.

    Science.gov (United States)

    Mallampati, Srinivasa Reddy; Mitoma, Yoshiharu; Simion, Cristian; Lee, Byoung Ho

    2015-10-01

    This study was conducted to examine the synthesis and application of novel nano-size calcium/iron-based composite material as an immobilizing and separation treatment of the heavy metals in fly ash from municipal solid waste incineration. After grinding with nano-Fe/Ca/CaO and with nano-Fe/Ca/CaO/[PO₄], approximately 30 wt% and 25 wt% of magnetic fraction fly ash were separated. The highest amount of entrapped heavy metals was found in the lowest weight of the magnetically separated fly ash fraction (i.e., 91% in 25% of treated fly ash). Heavy metals in the magnetic or nonmagnetic fly ash fractions were about 98% and 100% immobilized, respectively. Additionally, scanning electron microscopy combined with energy-dispersive X-ray spectrometry (SEM-EDS) observations indicate that the main fraction of enclosed/bound materials on treated fly ash includes Ca/PO₄-associated crystalline complexes. After nano-Fe/Ca/CaO/[PO₄] treatment, the heavy metal concentrations in the fly ash leachate were much lower than the Japan standard regulatory limit for hazardous waste landfills. These results appear to be extremely promising. The addition of a nano-Fe/Ca/CaO/PO₄mixture with simple grinding technique is potentially applicable for the remediation and volume reduction of fly ash contaminated by heavy metals. After grinding with nano-Fe/Ca/CaO and nano-Fe/Ca/CaO/[PO₄], approximately 30 wt% and 25 wt% of magnetic fraction fly ash were separated. The highest amount of entrapped heavy metals was found in the lowest weight of the magnetically separated fly ash fraction (i.e., 91% in 25% of treated fly ash), whereas heavy metals either in the magnetic or nonmagnetic fly ash fractions were about 98% and 100% immobilized. These results appear to be very promising, and the addition of nano-Fe/Ca/CaO/PO₄mixture with simple grinding technique may be considered potentially applicable for the remediation and volume reduction of contaminated fly ash by heavy metals.

  2. Concentrating precious metals from ash and slag waste of Far Eastern energy enterprises

    Science.gov (United States)

    Taskin, A. V.; Ivannikov, I. S.; Danilov, O. S.

    2017-10-01

    This work represents the data on the content of gold, noble metals and rare earth metals in ash and slag waste taken from the ash disposal areas of the Far Eastern energy enterprises. Ash and slag objects with increased concentration of Au and Ag were found. The chemical content of samples from researched ash and slag disposal areas is represented in this work. A scheme of dividing ash and slag waste into different mineral fractions is offered in this work. The mechanisms of collecting and distribution of Au, Pt and Ag concentrations in ash and slag wastes were determined during the research. Also, the possibility of gold concentration in heavy non-magnetic fraction is shown.

  3. Wastes incineration and public health: status of recent knowledge and risk evaluation; L'incineration des dechets et la sante publique: bilan des connaissances recentes et evaluation du risque

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-07-01

    The incineration of municipal and industrial wastes produces combustion products with various pollutants like: dusts, acid gases, heavy metals, nitrogen oxides, dioxines etc.. This report analyzes the toxicity of different pollutants (particulates, polycyclic halogenated compounds, cadmium, mercury, lead), the exposure of the population with respect to incineration pollutants (occupational and general exposure), and the risks linked with this exposure (hazard identification, exposure evaluation, risk characterization, results). (J.S.)

  4. Decolorization of a textile vat dye by adsorption on waste ash

    OpenAIRE

    MIODRAG ŠMELCEROVIĆ; DRAGAN ĐORĐEVIĆ; MILE NOVAKOVIĆ; MIRJANA MIZDRAKOVIĆ

    2010-01-01

    An adsorption process using cheap adsorbents could be described as a simple, selective and low cost alternative for the treatment of colored waste water compared to conventional physical and chemical processes. In this study the use of a natural waste adsorbent–ash was investigated for the removal of a textile vat dye Ostanthren blue GCD remaining after the dyeing of cotton textile. The ash obtained as a waste material during the burning of brown coal in the heating station of Leskovac (Serbi...

  5. Waste management system alternatives for treatment of wastes from spent fuel reprocessing

    Energy Technology Data Exchange (ETDEWEB)

    McKee, R.W.; Swanson, J.L.; Daling, P.M.; Clark, L.L.; Craig, R.A.; Nesbitt, J.F.; McCarthy, D.; Franklin, A.L.; Hazelton, R.F.; Lundgren, R.A.

    1986-09-01

    This study was performed to help identify a preferred TRU waste treatment alternative for reprocessing wastes with respect to waste form performance in a geologic repository, near-term waste management system risks, and minimum waste management system costs. The results were intended for use in developing TRU waste acceptance requirements that may be needed to meet regulatory requirements for disposal of TRU wastes in a geologic repository. The waste management system components included in this analysis are waste treatment and packaging, transportation, and disposal. The major features of the TRU waste treatment alternatives examined here include: (1) packaging (as-produced) without treatment (PWOT); (2) compaction of hulls and other compactable wastes; (3) incineration of combustibles with cementation of the ash plus compaction of hulls and filters; (4) melting of hulls and failed equipment plus incineration of combustibles with vitrification of the ash along with the HLW; (5a) decontamination of hulls and failed equipment to produce LLW plus incineration and incorporation of ash and other inert wastes into HLW glass; and (5b) variation of this fifth treatment alternative in which the incineration ash is incorporated into a separate TRU waste glass. The six alternative processing system concepts provide progressively increasing levels of TRU waste consolidation and TRU waste form integrity. Vitrification of HLW and intermediate-level liquid wastes (ILLW) was assumed in all cases.

  6. Assessing the potential of coal ash and bagasse ash as inorganic amendments during composting of municipal solid wastes.

    Science.gov (United States)

    Mohee, Romeela; Boojhawon, Anuksha; Sewhoo, Babita; Rungasamy, Selven; Somaroo, Geeta D; Mudhoo, Ackmez

    2015-08-15

    This study investigates the potential of incorporating inorganic amendments such as coal and bagasse ashes in different composting mixes. 10 different composting mixes were assessed as follows: A-20% bagasse ash (BA) with unsorted municipal solid wastes (UMSW); B-40% BA with UMSW; C-UMSW; D-20% BA with sorted municipal solid wastes (SMSW); E-40% BA with SMSW; F-SMSW; G-20% coal ash (CA) with UMSW; H-40% CA with UMSW; I-20% CA with SMSW and J-40% CA with SMSW. The composting processes were carried out in rotary drum composters. Composting mixes D, F, G and I achieved a temperature above 55 °C for at least 3 days, with the following peak temperatures: D-62 °C, F-57 °C, G-62 °C and I-58 °C. D resulted in the highest average net Volatile solids (VS) degradation of 68.6% and yielded the highest average volume reduction of 66.0%. The final compost from D, G, I, C and F were within range for electrical conductivities (EC) (794-1770 μS/cm) and pH (6.69-7.12). The ashes also helped in maintaining high average water holding capacities within the range of 183-217%. The C/N ratio of sorted wastes was improved by the addition of 20% coal ash and bagasse ash. Higher germination indices, above 0.8 were obtained for the ash-amended compost (D, G, I), indicating the feasibility and enhancement of using bagasse and coal ash as inorganic amendment in the composting process. Regarding heavy metals content, the chromium concentration for the composting mix G was found to be the highest whereas mixes D and I showed compliance with the MS (Mauritian Standards) 164 standards. Copyright © 2015. Published by Elsevier Ltd.

  7. Incineration as treatment system of urban solid wastes. La incineracion como parte del sistem integral de tratamiento de residuos solidos urbanos

    Energy Technology Data Exchange (ETDEWEB)

    Serrano Martinez, F. (IDAE. Madrid (Spain))

    1993-01-01

    Spain produces 12 million tons of municipal solid wastes. The incineration is the cleanest process and, at the moment, its use is complementary with the recycling. This article analyzes the Spanish situation and the process in USA and European Community.

  8. International experience of Foster Wheeler in the incineration of urban solid wastes; Experiencia internacional de Foster Wheeler en el campo de la incineracion de residuos solidos urbanos

    Energy Technology Data Exchange (ETDEWEB)

    Eisen, C.; Florez, J. M.

    1996-12-01

    The enterprise Foster Wheeler presents its experience on incineration or urban solid wastes. The main examples of construction in the international area are the Camden and the Valorsul plants. (Author)

  9. Wet physical separation of MSWI bottom ash

    OpenAIRE

    Muchova, L.

    2010-01-01

    Bottom ash (BA) from municipal solid waste incineration (MSWI) has high potential for the recovery of valuable secondary materials. For example, the MSWI bottom ash produced by the incinerator at Amsterdam contains materials such as non-ferrous metals (2.3%), ferrous metals (8-13%), gold (0.4 ppm), silver (10 ppm), stainless steel (0.1%) and minerals that can be converted into building products such as aggregates utilized for concrete, asphalt, etc. Since the composition of BA varies from cou...

  10. Effect of drying on leaching testing of treated municipal solid waste incineration APC-residues.

    Science.gov (United States)

    Hu, Yuyan; Hyks, Jiri; Astrup, Thomas; Christensen, Thomas H

    2008-08-01

    Air-pollution-control (APC) residues from waste incinerators are hazardous waste according to European legislation and must be treated prior to landfilling. Batch and column leaching data determine which type of landfill can receive the treated APC-residues. CEN standards are prescribed for the batch and column leaching test; however, these standards do not specify whether or not the residue samples should be dried prior to the leaching testing. Laboratory tests were performed in parallel (dried/non-dried) on treated APC-residue samples and evaluated with respect to Cr, Cd, Cu, Pb and Zn leaching. The effect of drying of the wet APC-residue samples was particularly dramatic regarding the leaching of Cr. Drying resulted in 10-100 times more Cr leaching in both batch and columns test. Drying also affected the leaching of Cd, Cu and Pb. Initial Cd leaching was up to 100 times higher in column tests with dried APC-residue than in tests with wet residues. The effect of drying appeared to be a combination of decreasing the reduction capacity of the sample (Cr), decreasing pH (Cd, Cu) and in column tests also a wash-out of salts (probably affecting Cd and Pb). If the leaching tests are intended to mimic landfill conditions, the results of this paper suggest that the tests should be done on wet, non-dried residue samples, although this may be less practical than testing dried samples.

  11. Nanometer-sized emissions from municipal waste incinerators: A qualitative risk assessment

    Energy Technology Data Exchange (ETDEWEB)

    Johnson, David R., E-mail: david.r.johnson@ghd.com

    2016-12-15

    Municipal waste incinerators (MWI) are beneficial alternatives to landfills for waste management. A recent constituent of concern in emissions from these facilities is incidental nanometer-sized particles (INP{sub MWI}), i.e., particles smaller than 1 micrometer in size that may deposit in the deepest parts of the lungs, cross into the bloodstream, and affect different regions of the body. With limited data, the public may fear INP{sub MWI} due to uncertainty, which may affect public acceptance, regulatory permitting, and the increased lowering of air quality standards. Despite limited data, a qualitative risk assessment paradigm can be applied to determine the relative risk due to INP{sub MWI} emissions. This review compiles existing data on nanometer-sized particle generation by MWIs, emissions control technologies used at MWIs, emission releases into the atmosphere, human population exposure, and adverse health effects of nanometer-sized particles to generate a qualitative risk assessment and identify data gaps. The qualitative risk assessment conservatively concludes that INP{sub MWI} pose a low to moderate risk to individuals, primarily due to the lack of relevant toxicological data on INP{sub MWI} mixtures in ambient particulate matter.

  12. Innovative HSR process to transform waste incinerator slag into useful mineral additives

    Energy Technology Data Exchange (ETDEWEB)

    Mayer, A. [Montanuniversitaet Leoben (Austria). Inst. fuer Gesteinshuettenkunde; Rey, T. [Holderbank Management and Consulting Ltd. (Switzerland)

    1996-12-31

    The Holderbank Smelting Redox-Process (HSR), which is patented world-wide, was born as a consequence of the general need for the reuse of waste and reduction of tipping fees for landfilling. Holderbank Management and Consulting Ltd (HMC) together with the Montan University of Leoben have developed a process to transform slags from municipal waste incineration into mineral additives. Laboratory and semi-industrial tests show its suitability as a mineral additive and the heavy metal compounds in the slag are transferred into usable heavy metal alloys separated from the molten slag. Preliminary estimates of the production costs are comparable with the costs of landfilling in Switzerland. Involved in the industrialization of the HSR process is Von Roll Environmental Engineering Division, Zurich. Moreover, the project is financially supported by the public authorities of Switzerland, comprising the Swiss Federal Ministry of Environment and several cantons. The HSR pilot plant will remain in operation for 2 years collecting all the relevant data required for planning the first industrial plant which should be in operation in 1998 with a capacity of about 20,000 t.p.a.

  13. Waste to Energy : The Waste Incineration Directive and its Implementation in the Netherlands

    NARCIS (Netherlands)

    Duman, Murat; Boels, Luciaan

    2007-01-01

    Essent operates a coal-fired power plant, called AC-9, in Geertruidenberg. A gasifier connected to AC-9 thermally treats waste wood through gasification. The waste wood Essent used is demolition and construction wood, the so-called B-wood. The gas produced through gasification is fed into the

  14. Determination of hexavalent chromium concentration in industrial waste incinerator stack gas by using a modified ion chromatography with post-column derivatization method.

    Science.gov (United States)

    Miyake, Yuichi; Tokumura, Masahiro; Iwazaki, Yuta; Wang, Qi; Amagai, Takashi; Horii, Yuichi; Otsuka, Hideyuki; Tanikawa, Noboru; Kobayashi, Takeshi; Oguchi, Masahiro

    2017-06-16

    An ion chromatography with post-column derivatization with 1,5-diphenylcarbazide (IC-DPC) analytical method was modified to enable measurement of trace-level hexavalent chromium (Cr(VI)) in air. One of the difficulties in determining trace levels of Cr(VI) in air with conventional IC-DPC methods is co-elution of the solvent and ion peaks due to high concentrations of ionic compounds in the extract. However, by using gradient elution rather than isocratic elution we were able to fully resolve the Cr(VI) ion peak from the solvent peak without the need for diluting the extract, which would have reduced the minimum quantifiable level of the method. With this method, we were able to detect Cr(VI) in air at concentrations of 5.3ng/m3 (assuming a sampling volume of 1m3 and a final solution volume of 10mL). Recovery tests at three different concentrations of Cr(VI) (50, 250, 1000ng) were performed with or without fly ash; recovery rates at all the concentrations of Cr(VI), with or without fly ash, ranged from 68% to 110% (mean±relative standard deviation, 96%±11%), and there were no differences in recovery rates with respect to the presence or absence of fly ash. Finally, we used the developed method to determine the concentration of Cr(VI) in stack gases collected from eight industrial waste incinerators located in Japan. The concentration of Cr(VI) in the stack gases ranged from below the method quantification limit to 3100ng/m3. The highest concentrations of Cr(VI) detected in the stack gases were two to three orders of magnitude higher than that in ambient air in Japan. Copyright © 2017 Elsevier B.V. All rights reserved.

  15. Mitigation of gaseous mercury emissions from waste-to-energy facilities: Homogeneous and heterogeneous Hg-oxidation pathways in presence of fly ashes.

    Science.gov (United States)

    Rumayor, M; Svoboda, K; Švehla, J; Pohořelý, M; Šyc, M

    2017-10-27

    This study describes the main mechanisms that take part in the mercury homogeneous oxidation pathway in presence of some of the main reactive compounds formed during waste incineration processes (O2, HCl, SO2 and NO). Series of model, synthetic dry flue gases were used to elucidate the effects of HCl, SO2, NO and their proportions in the gas on mercury behaviour. Three samples of fly ash collected from a MSWI facility were characterized and evaluated both for Hg heterogeneous oxidation and Hg removal in a laboratory scale device. The results obtained in this study showed that homogeneous mercury oxidation in the models MSWI and coal combustion flue gas atmospheres was 52 ± 5% and 25%, respectively. SO2, NO and HCl have a synergetic effect in Hg oxidation in presence of oxygen, but the main differences found are mainly caused by the strong influence of HCl and the likely inhibitory oxidation effects of SO2. Surface area together with carbon and chloride content of the fly ashes were correlated with their capacity for Hg-heterogeneous oxidation and adsorption. The sample of fly ash with relatively high content of unburnt carbon and chlorine, and with BET surface (2.42 m(2)/g) was able to remove up to 100% of Hg(0) (g) during 300 min. The results obtained in this study provide a complete overview of the behaviour of mercury during MSWI processes and may help to clarify the fate/behaviour of mercury in a filter (e.g. electrostatic precipitator) providing a deeper knowledge about the impacts of fly ash properties on mercury fate in waste incineration. Copyright © 2017 Elsevier Ltd. All rights reserved.

  16. Re-use of incinerated agro-industrial waste as pozzolanic addition. Comparison with spanish silica fume

    Directory of Open Access Journals (Sweden)

    Delgado, A.

    2009-12-01

    Full Text Available This study attempted to determine the viability of using incinerated agro-industrial waste, ashes C1 and C2, as possible artificial pozzolanic additions in traditional and highperformance concretes and mortars, mainly, and for this reason, a comparative study was likewise conducted with Spanish silica fume (HS. The conclusion drawn from the findings was that the two ashes used could be regarded to be centainly, silicic artificial pozzolanic additions but only C2, which had a higher SiO2 content, could be regarded to be a “microsilica”, however, because its loss on ignition, L.O.I., fell within the acceptable range of variability. In contrast, C1 could not be so regarded because its L.O.I. was too high, despite its higher reactive silica SiO2r- content. For this reason, ash C1 had to be ruled out for any of the proposed uses, even though in terms of chemical and sulfatic characterization it was closer to HS than C2. By contrast, the mechanical strength values of C2 and HS were comparable, making the former initially acceptable for any of such uses. Finally, it has also been justified that, adoption of any method of trial to determine potential resistance to the sulfates of the Portland cements with calcareous filler lacks of sense.Este trabajo ha tenido por objetivo determinar la viabilidad de uso de dos residuos agroindustriales incinerados, cenizas C1 y C2, como posibles adiciones puzolánicas artificiales, para fabricar cementos y/o de sus productos derivados, hormigones y morteros tradicionales y especiales, principalmente; de aquí su estudio comparativo con el humo de sílice español, HS. Y la conclusión que se obtuvo fue que las dos cenizas pueden ser consideradas como adiciones puzolánicas artificiales con carácter químico silícico cierto, pero sólo una, la C2, podría llegar a ser considerada como “microsílice”, porque su pérdida por calcinación se encuentra dentro de su límite permitido. En cambio la C1, no, porque

  17. Lightweight Brick by Carbon Ash from The Mixed Plastic Waste Treatment Plant

    Directory of Open Access Journals (Sweden)

    Chen Kuo-Wei

    2016-01-01

    Full Text Available This study was designed to investigate the mixed plastic waste from the production of light carbon ash bricks performance. The mixed waste plastic pyrolysis process generated waste - Carbon ash. After extrusion, a Lightweight brick was made by carbon ash, additive and Cement mortar. In general, the set compressive strength and insulation effect of lightweight bricks with carbon ash proportion for significant impact. The set water absorption and thermal conductivity of lightweight bricks with carbon ash proportion for significant impact. The set density of lightweight brick ameliorates with M3824 additive and CM3 cement mortar for significant impact. Under conditions of technology and economic, the results of this study as reference for market-oriented marketing and commercialization of production.

  18. Comparison of the co-gasification of sewage sludge and food wastes and cost-benefit analysis of gasification- and incineration-based waste treatment schemes.

    Science.gov (United States)

    You, Siming; Wang, Wei; Dai, Yanjun; Tong, Yen Wah; Wang, Chi-Hwa

    2016-10-01

    The compositions of food wastes and their co-gasification producer gas were compared with the existing data of sewage sludge. Results showed that food wastes are more favorable than sewage sludge for co-gasification based on residue generation and energy output. Two decentralized gasification-based schemes were proposed to dispose of the sewage sludge and food wastes in Singapore. Monte Carlo simulation-based cost-benefit analysis was conducted to compare the proposed schemes with the existing incineration-based scheme. It was found that the gasification-based schemes are financially superior to the incineration-based scheme based on the data of net present value (NPV), benefit-cost ratio (BCR), and internal rate of return (IRR). Sensitivity analysis was conducted to suggest effective measures to improve the economics of the schemes. Copyright © 2016 Elsevier Ltd. All rights reserved.

  19. Environmental evaluation of the electric and cogenerative configurations for the energy recovery of the Turin municipal solid waste incineration plant.

    Science.gov (United States)

    Panepinto, Deborah; Genon, Giuseppe

    2014-07-01

    Given the desirability of reducing fossil fuel consumption, together with the increasing production of combustible solid wastes, there is clearly a need for waste treatment systems that achieve both volume reduction and energy recovery. Direct incineration method is one such system. The aim of this work was to analyze the municipal solid waste incineration plant currently under construction in the province of Turin (Piedmont, North Italy), especially the potential for energy recovery, and the consequent environmental effects. We analyzed two kinds of energy recovery: electric energy (electrical configuration) only, and both electric and thermal energy (cogenerative configuration), in this case with a different connection hypothesis to the district heating network. After we had evaluated the potential of the incinerator and considered local demographic, energy and urban planning effects, we assumed different possible connections to the district heating network. We computed the local and global environmental balances based on the characteristics of the flue gas emitted from the stack, taking into consideration the emissions avoided by the substituted sources. The global-scale results provided relevant information on the carbon dioxide emissions parameter. The results on the local scale were used as reference values for the implementation of a Gaussian model (Aermod) that allows evaluation of the actual concentration of the pollutants released into the atmosphere. The main results obtained highlight the high energy efficiency of the combined production of heat and electricity, and the opportunity to minimize the environmental impact by including cogeneration in a district heating scheme. © The Author(s) 2014.

  20. Phosphorus leaching from soils amended with thermally gasified piggery waste ash

    DEFF Research Database (Denmark)

    Kuligowski, Ksawery; Poulsen, Tjalfe

    2009-01-01

    from anaerobically digested, thermally gasified (GA) and incinerated (IA) piggery waste has been tested using water loads ranging from 0.1 to 200 ml g−1. Leaching of P from soil columns amended with GA was investigated for one P application rate (205 kg P ha−1 corresponding to 91 mg P kg−1 soil dry...

  1. Simulation of a waste incineration process with flue-gas cleaning and heat recovery sections using Aspen Plus.

    Science.gov (United States)

    Cimini, Silvano; Prisciandaro, Marina; Barba, Diego

    2005-01-01

    In the present paper, the modeling of a dual-purpose plant for the production of electrical and thermal energy from the heat treatment of solid wastes is presented. Particularly, the process has been modeled by using the Aspen Plus Shell, with the aim of performing a study about the applicability of this software in the simulation of a solid waste incineration process, which involves complex gas-solid reactions where the solids are referred to as "non-conventional". The model is developed to analyze and quantify the expected benefits associated with refuse derived fuel (RDF) thermal utilization; thus attention is focused on the performance of the energy recovery section.

  2. Coupling scales for modelling heavy metal vaporization from municipal solid waste incineration in a fluid bed by CFD

    Energy Technology Data Exchange (ETDEWEB)

    Soria, José, E-mail: jose.soria@probien.gob.ar [Institute for Research and Development in Process Engineering, Biotechnology and Alternative Energies (PROBIEN, CONICET – UNCo), 1400 Buenos Aires St., 8300 Neuquén (Argentina); Gauthier, Daniel; Flamant, Gilles [Processes, Materials and Solar Energy Laboratory (PROMES-CNRS, UPR 8521), 7 Four Solaire Street, Odeillo, 66120 Font-Romeu (France); Rodriguez, Rosa [Chemical Engineering Institute, National University of San Juan, 1109 Libertador (O) Avenue, 5400 San Juan (Argentina); Mazza, Germán [Institute for Research and Development in Process Engineering, Biotechnology and Alternative Energies (PROBIEN, CONICET – UNCo), 1400 Buenos Aires St., 8300 Neuquén (Argentina)

    2015-09-15

    Highlights: • A CFD two-scale model is formulated to simulate heavy metal vaporization from waste incineration in fluidized beds. • MSW particle is modelled with the macroscopic particle model. • Influence of bed dynamics on HM vaporization is included. • CFD predicted results agree well with experimental data reported in literature. • This approach may be helpful for fluidized bed reactor modelling purposes. - Abstract: Municipal Solid Waste Incineration (MSWI) in fluidized bed is a very interesting technology mainly due to high combustion efficiency, great flexibility for treating several types of waste fuels and reduction in pollutants emitted with the flue gas. However, there is a great concern with respect to the fate of heavy metals (HM) contained in MSW and their environmental impact. In this study, a coupled two-scale CFD model was developed for MSWI in a bubbling fluidized bed. It presents an original scheme that combines a single particle model and a global fluidized bed model in order to represent the HM vaporization during MSW combustion. Two of the most representative HM (Cd and Pb) with bed temperatures ranging between 923 and 1073 K have been considered. This new approach uses ANSYS FLUENT 14.0 as the modelling platform for the simulations along with a complete set of self-developed user-defined functions (UDFs). The simulation results are compared to the experimental data obtained previously by the research group in a lab-scale fluid bed incinerator. The comparison indicates that the proposed CFD model predicts well the evolution of the HM release for the bed temperatures analyzed. It shows that both bed temperature and bed dynamics have influence on the HM vaporization rate. It can be concluded that CFD is a rigorous tool that provides valuable information about HM vaporization and that the original two-scale simulation scheme adopted allows to better represent the actual particle behavior in a fluid bed incinerator.

  3. Examination of Babcock and Wilcox tubes after exposure in an industrial waste incinerator

    Energy Technology Data Exchange (ETDEWEB)

    Keiser, J.R.; Ferber, M.K.; Longmire, H.F.; Walker, L.R.; Hindman, D.L.

    1996-06-01

    Seven ceramic tubes provided by, and in most cases manufactured by, Babcock and Wilcox were exposed in E. I. DuPont`s Wilmington, Delaware, hazardous waste incinerator. These tubes were subsequently examined at Oak Ridge National Laboratory to determine the effect of exposure on the strength and microstructural integrity of the tube materials. An unexposed tube section of one of the materials was also examined. Evaluation methods included c-ring compression tests, light microscopy, and electron microprobe spectroscopy. The c-ring compression tests revealed a very wide range in the strengths of the materials tested; the strongest was DuPont Lanxide Composites (DLC) silicon carbide particulate-strengthened alumina, and the weakest was the DLC Type B mixed-oxide material. The only material for which data on unexposed samples were available showed lower strength than the exposed material. Microstructural examination of the samples yielded minimal evidence of interaction of most of the tube materials with the components of the environment. Microprobe examination showed some segregation of yttrium in the matrix and along the surface of one of the PRD166/zirconia tubes and limited interaction of the fibers in the same tube with the components of the environment.

  4. [Mercury pollution investigation in predominant plants surrounding Shenzhen Qingshuihe municipal solid waste incineration plant].

    Science.gov (United States)

    Zhao, Hong-Wei; Zhong, Xiu-Ping; Liu, Yang-Sheng; Wang, Jun-Jian; Hong, Yuan; Zhao, Kang-Sai; Zeng, Hui

    2009-09-15

    In order to investigate the effects of mercury emission from municipal solid waste incineration (MSWI) on the surrounding plants and soils, the mercury concentrations were examined in the plant samples including leaves and stems and the soil samples around Shenzhen Qingshuihe MSWI Plant. Results show that, these plants are significantly polluted by mercury, the mercury concentrations of the plant leaves are 0.030 9-0.246 7 mg x kg(-1), with the mean value 0.094 8 mg x kg(-1), among the local prominent plants, the mercury concentrations in the leaves are in the order of: Acacia confuse > Litsea rotundifolia > Acacia mangium > Acacia auriculaeformis > Schima superb > Ilex asprella. The mercury concentrations of the plant stems are 0.007 4-0.119 6 mg x kg(-1), with the mean value 0.041 7 mg x kg(-1). For the same plant, the mercury concentration in its leaf correlates positively with that in its stem, but presents little correlation with that in the soil where it grows. Under the direction of the dominant wind, the concentration of smoke diffusion is often influenced by the distance from the stack and the difference of terrain. The mercury concentrations of the plant leaves and stems vary almost in accordance with spatial heterogeneity patterns of smoke diffusion. These results demonstrate that the interaction of the smoke and plant leaves play the leading role in the mercury exchange between plants and environment.

  5. Simulation of the plume emitted by a municipal waste incinerator located in the Madeira island

    Energy Technology Data Exchange (ETDEWEB)

    Coutinho, M.; Ribeiro, C.; Pereira, M.; Borrego, C. [Campus Univ., AVEIRO (Portugal). IDAD - Inst. of Environment and Development

    2004-07-01

    The study of meteorological circulations in small islands has been quite limited with the majority of the research published concerning the analysis of the eolic potential for energy production. Other researchers focused on the description of the dispersion of gases emitted by volcanic activity. In this paper, a mesoscale meteorological and dispersion model was applied to simulate the behaviour of the plume of a municipal waste incinerator (MSW) that was constructed in the southern slope of the Madeira island at an altitude of 1380 m. Madeira is a Portuguese island located in the Atlantic Ocean at approximately 32 40'N and 16 52'W with a clear east-west development. The island is relatively small (60 x 20 km{sup 2}) but is characterized by very complex orography with maximum peaks reaching 1800 m. The fact that the orography has the same east-west development creates a very strong distinction between the northern and the southern slopes. The northern slope is strongly exposed to the prevalent synoptic flows and the southern slope is much warmer, quiet and where the majority of the population lives. The climate is very mild with small thermal amplitudes and maximum temperatures between 18 to 28 C. Sea temperature during summer rises to 22-23 C. (orig.)

  6. Comparison between landfill gas and waste incineration for power generation in Astana, Kazakhstan.

    Science.gov (United States)

    Inglezakis, Vassilis J; Rojas-Solórzano, Luis; Kim, Jong; Aitbekova, Aisulu; Ismailova, Aizada

    2015-05-01

    The city of Astana, the capital of Kazakhstan, which has a population of 804,474, and has been experiencing rapid growth over the last 15 years, generates approximately 1.39 kg capita(-1) day(-1) of municipal solid waste (MSW). Nearly 700 tonnes of MSW are collected daily, of which 97% is disposed of at landfills. The newest landfill was built using modern technologies, including a landfill gas (LFG) collection system.The rapid growth of Astana demands more energy on its path to development, and the viability analysis of MSW to generate electricity is imperative. This paper presents a technical-economic pre-feasibility study comparing landfill including LFG utilization and waste incineration (WI) to produce electricity. The performance of LFG with a reciprocating engine and WI with steam turbine power technologies were compared through corresponding greenhouse gases (GHG) reduction, cost of energy production (CEP), benefit-cost ratio (BCR), net present value (NPV) and internal rate of return (IRR) from the analyses. Results demonstrate that in the city of Astana, WI has the potential to reduce more than 200,000 tonnes of GHG per year, while LFG could reduce slightly less than 40,000 tonnes. LFG offers a CEP 5.7% larger than WI, while the latter presents a BCR two times higher than LFG. WI technology analysis depicts a NPV exceeding 280% of the equity, while for LFG, the NPV is less than the equity, which indicates an expected remarkable financial return for the WI technology and a marginal and risky scenario for the LFG technology. Only existing landfill facilities with a LFG collection system in place may turn LFG into a viable project. © The Author(s) 2015.

  7. THE IMPACT OF REDUCING THE CAPACITY INCINERATORS OF MEDICAL WASTE ON THE VALUE OF THE COST-EFFECTIVENESS INDEX

    Directory of Open Access Journals (Sweden)

    Maria Walery

    2016-05-01

    Full Text Available The main subject of this paper is the optimization of a model of disposal and treatment of municipal waste as well as computer software MRGO+ (Model for Regional Waste Management, through which the model was implemented. It has been verified by the author and adapted to the needs of the proposed model to optimize the disposal and treatment of medical waste in the example of the Podlaskie Province. This paper describes the optimization study aimed to analysis of the impact of reducing the capacity incinerators of medical waste on the value of the cost-effectiveness index (E. The study was conducted on the example of the analysis of medical waste management system in north-eastern Poland, in the Podlaskie Province. Introduction of bandwidth limitations 3 intermediate objects and lack of bandwidth limitations in an incineration plant in Hajnówka, resulted in a significant decrease in system costs by approx. 17%, and consequently also a significant decrease in the cost-effectiveness index E.

  8. The durability of fired brick incorporating textile factory waste ash and basaltic pumice

    Energy Technology Data Exchange (ETDEWEB)

    Binici, Hanifi [Kahramanmaras Sutcu Imam Univ., Kahramanmaras (Turkey). Dept. of Civil Engineering; Yardim, Yavuz [Epoka Univ., Tirana (Albania). Dept. of Civil Engineering

    2012-07-15

    This study investigates the durability of fired brick produced with additives of textile factories' waste ash and basaltic pumice. The effects of incorporating waste ash and basaltic pumice on durability and mechanical properties of the clay bricks were studied. Samples were produced with different ratios of the textile factories' waste ash and basaltic pumice added and at different fire temperatures of 700, 900, and 1 050 C for 8 h. The bricks with additives were produced by adding equal amounts of textile factories' waste ash and basaltic pumice, separately and together, with rates of 5, 10 and 20 wt.%. The produced samples were kept one year in sodium sulphate and sodium nitrate and tested under freezing - unfreezing and drying - wetting conditions. Then compression strength and mass loss of the samples with and without additives were investigated. The test results were compared with standards and results obtained from control specimens. The results showed that incorporations up to 10 wt.% of textile factories' waste ash and basaltic pumice is beneficial to the fired brick. Both textile factories' waste ash and basaltic pumice were suitable additives and could be used for more durable clay brick production at 900 C fire temperature. (orig.)

  9. Reduction of heavy metals in residues from the dismantling of waste electrical and electronic equipment before incineration.

    Science.gov (United States)

    Long, Yu-Yang; Feng, Yi-Jian; Cai, Si-Shi; Hu, Li-Fang; Shen, Dong-Sheng

    2014-05-15

    Residues disposal from the dismantling of waste electrical and electronic equipment are challenging because of the large waste volumes, degradation-resistance, low density and high heavy metal content. Incineration is advantageous for treating these residues but high heavy metal contents may exist in incinerator input and output streams. We have developed and studied a specialized heavy metal reduction process, which includes sieving and washing for treating residues before incineration. The preferable screen aperture for sieving was found to be 2.36mm (8 meshes) in this study; using this screen aperture resulted in the removal of approximately 47.2% Cu, 65.9% Zn, 26.5% Pb, 55.4% Ni and 58.8% Cd from the residues. Subsequent washing further reduces the heavy metal content in the residues larger than 2.36mm, with preferable conditions being 400rpm rotation speed, 5min washing duration and liquid-to-solid ratio of 25:1. The highest cumulative removal efficiencies of Cu, Zn, Pb, Ni and Cd after sieving and washing reached 81.1%, 61.4%, 75.8%, 97.2% and 72.7%, respectively. The combined sieving and washing process is environmentally friendly, can be used for the removal of heavy metals from the residues and has benefits in terms of heavy metal recycling. Copyright © 2014 Elsevier B.V. All rights reserved.

  10. Effects of waste glass and waste foundry sand additions on reclaimed tiles containing sewage sludge ash.

    Science.gov (United States)

    Lin, Deng-Fong; Luo, Huan-Lin; Lin, Kuo-Liang; Liu, Zhe-Kun

    2017-07-01

    Applying sewage sludge ash (SSA) to produce reclaimed tiles is a promising recycling technology in resolving the increasing sludge wastes from wastewater treatment. However, performance of such reclaimed tiles is inferior to that of original ceramic tiles. Many researchers have therefore tried adding various industrial by-products to improve reclaimed tile properties. In this study, multiple materials including waste glass and waste foundry sand (WFS) were added in an attempt to improve physical and mechanical properties of reclaimed tiles with SSA. Samples with various combinations of clay, WFS, waste glass and SSA were made with three kiln temperatures of 1000°C, 1050°C, and 1100°C. A series of tests on the samples were next conducted. Test results showed that waste glass had positive effects on bending strength, water absorption and weight loss on ignition, while WFS contributed the most in reducing shrinkage, but could decrease the tile bending strength when large amount was added at a high kiln temperature. This study suggested that a combination of WFS from 10% to 15%, waste glass from 15% to 20%, SSA at 10% at a kiln temperature between 1000°C and 1050°C could result in quality reclaimed tiles with a balanced performance.

  11. ZeroWaste

    DEFF Research Database (Denmark)

    Goltermann, Per; Ottosen, Lisbeth M.; Jensen, Pernille Erland

    2014-01-01

    The ZeroWaste research group at the Department of Civil Engineering at the Technical University of Denmark (DTU Byg) was established two years ago and covers the broad range of expertise, required for turning waste materials into attractive, new materials. Members of the group have, prior to that......, developed methods for removal of heavy metals and phosphorous from waste incineration, sewage sludge and other bio ashes, providing the basis of to make these ash types an attractive, new material for the building sector. Initial results for upgrading and using different types of ashes are presented...

  12. The prospects for incineration of municipal solid waste in Russia in order to produce heat and electric power

    Science.gov (United States)

    Baskakov, A. P.

    2014-04-01

    The article presents the results of the low-temperature pyrolysis of the main components of municipal solid waste (MSW): wood, products of wood processing (paper, cardboard, fabrics, etc.), various plastics, rubber, as well as of a representative sample of MSW. A waste-to-energy plant is described, at which municipal solid waste is subjected to the pyrolysis, and then pyrolysis products are incinerated in a slagging-bottom furnace. The paper presents an analysis of the operation of a modern waste-to-energy plant equipped with a wet scrubber, with a high-degree recovery of the heat of exhaust gases by means of a heat pump, and with evaporation cooling of glowing slag in a tank filled with water. Chemical treatment of water circulating in the system makes it possible to convert heavy metals and other hazardous substances into the insoluble form and then to remove them.

  13. A particulate model of solid waste incineration in a fluidized bed combining combustion and heavy metal vaporization

    Energy Technology Data Exchange (ETDEWEB)

    Mazza, G. [Facultad de Ingenieria, Departamento de Quimica, Universidad Nacional del Comahue, UE Neuquen (CONICET - UNCo), Buenos Aires 1400, 8300 Neuquen (Argentina); Falcoz, Q.; Gauthier, D.; Flamant, G. [Laboratoire Procedes Materiaux et Energie Solaire (CNRS-PROMES), 7 Rue du Four Solaire, Odeillo, 66120 Font-Romeu (France)

    2009-11-15

    This study aims to develop a particulate model combining solid waste particle combustion and heavy metal vaporization from burning particles during MSW incineration in a fluidized bed. The original approach for this model combines an asymptotic combustion model for the carbonaceous solid combustion and a shrinking core model to describe the heavy metal vaporization. A parametric study is presented. The global metal vaporization process is strongly influenced by temperature. Internal mass transfer controls the metal vaporization rate at low temperatures. At high temperatures, the chemical reactions associated with particle combustion control the metal vaporization rate. A comparison between the simulation results and experimental data obtained with a laboratory-scale fluid bed incinerator and Cd-spiked particles shows that the heavy metal vaporization is correctly predicted by the model. The predictions are better at higher temperatures because of the temperature gradient inside the particle. Future development of the model will take this into account. (author)

  14. Study of composition change and agglomeration of flue gas cleaning residue from a fluidized bed waste incinerator.

    Science.gov (United States)

    Lievens, P; Verbinnen, B; Bollaert, P; Alderweireldt, N; Mertens, G; Elsen, J; Vandecasteele, C

    2011-10-01

    Blocking of the collection hoppers of the baghouse filters in a fluidized bed incinerator for co-incineration of high calorific industrial solid waste and sludge was observed. The composition of the flue gas cleaning residue (FGCR), both from a blocked hopper and from a normal hopper, was investigated by (differential) thermogravimetric analysis, quantitative X-ray powder diffraction and wet chemical analysis. The lower elemental carbon concentration and the higher calcium carbonate concentration of the agglomerated sample was the result of oxidation of carbon and subsequent reaction of CO2 with CaO. The evolved heat causes a temperature increase, with the decomposition of CaOHCl as a consequence. The formation of calcite and calcium chloride and the evolution of heat caused agglomeration of the FGCR. Activated lignite coke was replaced by another adsorption agent with less carbon, so the auto-ignition temperature increased; since then no further block formation has occurred.

  15. Economic screening of renewable energy technologies: Incineration, anaerobic digestion, and biodiesel as applied to waste water scum.

    Science.gov (United States)

    Anderson, Erik; Addy, Min; Ma, Huan; Chen, Paul; Ruan, Roger

    2016-12-01

    In the U.S., the total amount of municipal solid waste is continuously rising each year. Millions of tons of solid waste and scum are produced annually that require safe and environmentally sound disposal. The availability of a zero-cost energy source like municipal waste scum is ideal for several types of renewable energy technologies. However, the way the energy is produced, distributed and valued also contributes to the overall process sustainability. An economic screening method was developed to compare the potential energy and economic value of three waste-to-energy technologies; incineration, anaerobic digestion, and biodiesel. A St. Paul, MN wastewater treatment facility producing 3175 "wet" kilograms of scum per day was used as a basis of the comparison. After applying all theoretically available subsidies, scum to biodiesel was shown to have the greatest economic potential, valued between $491,949 and $610,624/year. The incineration of scum yielded the greatest reclaimed energy potential at 29billion kilojoules/year. Copyright © 2016 Elsevier Ltd. All rights reserved.

  16. 40 CFR 62.14820 - How must I monitor opacity for air curtain incinerators that burn 100 percent wood wastes, clean...

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 8 2010-07-01 2010-07-01 false How must I monitor opacity for air curtain incinerators that burn 100 percent wood wastes, clean lumber, and/or yard waste? 62.14820 Section 62.14820 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) APPROVAL AND PROMULGATION OF STATE PLANS FO...

  17. Recycle of Inorganic Nutrients for Hydroponic Crop Production Following Incineration of Inedible Biomass

    Science.gov (United States)

    Bubenheim, David L.; Wignarajah, Kanapathipillai; Kliss, Mark H. (Technical Monitor)

    1996-01-01

    Recovery of resources from waste streams is essential for future implementation and reliance on a regenerative life support system. The major waste streams of concern are from human activities and plant wastes. Carbon, water and inorganics are the primary desired raw materials of interest. The goal of resource recovery is maintenance of product quality to insure support of reliable and predictable levels of life support function performance by the crop plant component. Further, these systems must be maintained over extended periods of time, requiring maintenance of nutrient solutions to avoid toxicity and deficiencies. Today, reagent grade nutrients are used to make nutrient solutions for hydroponic culture and these solutions are frequently changed during the life cycle or sometimes managed for only one crop life cycle. The focus of this study was to determine the suitability of the ash product following incineration of inedible biomass as a source of inorganic nutrients for hydroponic crop production. Inedible wheat biomass was incinerated and ash quality characterized. The incinerator ash was dissolved in adequate nitric acid to establish a consistent nitrogen concentration in all nutrient solution treatments. Four experimental nutrient treatments were included: control, ash only, ash supplemented to match control, and ash only quality formulated with reagent grade chemicals. When nutrient solutions are formulated using only ash following-incineration of inedible biomass, a balance in solution is established representing elemental retention following incineration and nutrient proportions present in the original biomass. The resulting solution is not identical to the control. This imbalance resulted in suppression of crop growth. When the ash is supplemented with nutrients to establish the same balance as in the control, growth is identical to the control. The ash appears to carry no phytotoxic materials. Growth in solution formulated with reagent grade chemicals

  18. Multi-criteria GIS-based siting of an incineration plant for municipal solid waste.

    Science.gov (United States)

    Tavares, Gilberto; Zsigraiová, Zdena; Semiao, Viriato

    2011-01-01

    Siting a municipal solid waste (MSW) incineration plant requires a comprehensive evaluation to identify the best available location(s) that can simultaneously meet the requirements of regulations and minimise economic, environmental, health, and social costs. A spatial multi-criteria evaluation methodology is presented to assess land suitability for a plant siting and applied to Santiago Island of Cape Verde. It combines the analytical hierarchy process (AHP) to estimate the selected evaluation criteria weights with Geographic Information Systems (GIS) for spatial data analysis that avoids the subjectivity of the judgements of decision makers in establishing the influences between some criteria or clusters of criteria. An innovative feature of the method lies in incorporating the environmental impact assessment of the plant operation as a criterion in the decision-making process itself rather than as an a posteriori assessment. Moreover, a two-scale approach is considered. At a global scale an initial screening identifies inter-municipal zones satisfying the decisive requirements (socio-economic, technical and environmental issues, with weights respectively, of 48%, 41% and 11%). A detailed suitability ranking inside the previously identified zones is then performed at a local scale in two phases and includes environmental assessment of the plant operation. Those zones are ranked by combining the non-environmental feasibility of Phase 1 (with a weight of 75%) with the environmental assessment of the plant operation impact of Phase 2 (with a weight of 25%). The reliability and robustness of the presented methodology as a decision supporting tool is assessed through a sensitivity analysis. The results proved the system effectiveness in the ranking process. Copyright © 2011 Elsevier Ltd. All rights reserved.

  19. rice-husk ash-carbide-waste stabilization of reclaimed asphalt

    African Journals Online (AJOL)

    user

    2016-07-03

    Jul 3, 2016 ... This paper present results of the laboratory evaluation of the characteristics of carbide waste and rice husk ash stabilized reclaimed asphalt pavement waste with a view to determine its suitability for use as flexible pavement material. The mixtures were subjected to British Standard heavy compactive effort ...

  20. The influences on leachate from landfill of incineration residuals by acid precipitation.

    Science.gov (United States)

    Chow, Jing-Dong; Chai, Wan-Lan

    2007-04-02

    Incineration of municipal solid wastes (MSW) is the main method of waste management in Taiwan. Although the incineration of MSW processes the solid wastes at 850-950 degrees C and destroys most of the organics, the content of incineration ashes is still a problem for landfill. Moreover, acid precipitation is much worse than before in Taiwan, especially in the northern areas. For instance, the occurrence probabilities of acid precipitation measured from 1991 to 1998 in Taipei increase from 73% to 85%. Therefore, it is more important to get a series of data that will help explore the influence of acid precipitation during disposal on characterization of pollutants than to analyze the ash properties after the incinerators have been constructed and regularly used. In this investigation, the disposal site of incineration ashes is simulated in laboratory by test columns. An irrigation experiment is taken to simulate the acid precipitation at room temperature. In order to explore the exact influence on leachate quality of the main chemical composition of acid precipitation, columns are migrated with different concentrations of sulfate in acid precipitation. This investigation showed that the sulfate concentration of acid precipitation has an increasing effect on the accumulative release of heavy metals, such as Zn, Pb and Cu, from leachate. The sulfate concentration of acid precipitation, however, will not influence the trend of chemical oxygen demand (COD), biochemical oxygen demand (BOD(5)) and total organic carbon (TOC) in the leachate release.

  1. Size fractionation of waste-to-energy boiler ash enables separation of a coarse fraction with low dioxin concentrations

    DEFF Research Database (Denmark)

    Weidemann, E.; Allegrini, Elisa; Astrup, Thomas Fruergaard

    2016-01-01

    Polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/F) formed in modern Waste-to-Energy plants are primarily found in the generated ashes and air pollution control residues, which are usually disposed of as hazardous waste. The objective of this study was to explore the occurrence of PCDD....../F in different grain size fractions in the boiler ash, i.e. ash originating from the convection pass of the boiler. If a correlation between particle size and dioxin concentrations could be found, size fractionation of the ashes could reduce the total amount of hazardous waste. Boiler ash samples from ten...... content. While the total mass of the coarse fraction in this boiler was relatively small, sieving could reduce the amount of ash containing toxic PCDD/F by around 0.5. kg per tonne input waste or around 15% of the collected boiler ash from the convection pass. The mid-size fraction in this study covered...

  2. Recycling of sugarcane bagasse ash waste in the production of clay bricks.

    Science.gov (United States)

    Faria, K C P; Gurgel, R F; Holanda, J N F

    2012-06-30

    This work investigates the recycling of sugarcane bagasse ash waste as a method to provide raw material for clay brick bodies, through replacement of natural clay by up 20 wt.%. Initially, the waste sample was characterized by its chemical composition, X-ray diffraction, differential thermal analysis, particle size, morphology and pollution potential. Clay bricks pieces were prepared, and then tested, so as to determine their technological properties (e.g., linear shrinkage, water absorption, apparent density, and tensile strength). The sintered microstructure was evaluated by scanning electron microscopy (SEM). It was found that the sugarcane bagasse ash waste is mainly composed by crystalline silica particles. The test results indicate that the sugarcane bagasse ash waste could be used as a filler in clay bricks, thus enhancing the possibility of its reuse in a safe and sustainable way. Copyright © 2012 Elsevier Ltd. All rights reserved.

  3. LCA Of The “Renescience” Concept: An Alternative To Incineration For The Treatment Of Residual Municipal Solid Waste

    DEFF Research Database (Denmark)

    Tonini, Davide; Astrup, Thomas

    2010-01-01

    incineration (INC) with respect to Global Warming (GW), Acidification (AC) and Ecotoxicity in water, chronic (ETwc). The major savings are due to electricity recovery at the power plant. The waste refinery (pretreatment) contributes with a net load on GW equal to 20-30 mPE/tonne of ww. Savings from recycling......The “REnescience” system consists on a pretreatment of the waste based on heat and enzymes which liquefy the biogenic fraction of the waste (paper and organics). The outputs of the process are then liquid slurry and a remaining solid fraction from which metals, plastic and glass can eventually...... are mainly connected to metals recovery (around -12 mPE/tonne of ww). The results for the toxicity categories show that the “REnescience” options are more environmentally friendly with respect to ETwc because of the higher recycling but contribute with environmental loads on HTs and HTw because of potential...

  4. Reduction of heavy metals in residues from the dismantling of waste electrical and electronic equipment before incineration

    Energy Technology Data Exchange (ETDEWEB)

    Long, Yu-Yang; Feng, Yi-Jian; Cai, Si-Shi [Zhejiang Provincial Key Laboratory of Solid Waste Treatment and Recycling, School of Environmental Science and Engineering, Zhejiang Gongshang University, Hangzhou 310012 (China); Hu, Li-Fang [College of Quality and Safety Engineering, China Jiliang University, Hangzhou 310018 (China); Shen, Dong-Sheng, E-mail: shends@zju.edu.cn [Zhejiang Provincial Key Laboratory of Solid Waste Treatment and Recycling, School of Environmental Science and Engineering, Zhejiang Gongshang University, Hangzhou 310012 (China)

    2014-05-01

    Highlights: • The highest metal reduction occurs at a 2.36 mm sieving size. • Washing promotes heavy metal recycling without secondary pollution. • Sieving and washing are environmentally friendly pretreatments for WEEE wastes. - Abstract: Residues disposal from the dismantling of waste electrical and electronic equipment are challenging because of the large waste volumes, degradation-resistance, low density and high heavy metal content. Incineration is advantageous for treating these residues but high heavy metal contents may exist in incinerator input and output streams. We have developed and studied a specialized heavy metal reduction process, which includes sieving and washing for treating residues before incineration. The preferable screen aperture for sieving was found to be 2.36 mm (8 meshes) in this study; using this screen aperture resulted in the removal of approximately 47.2% Cu, 65.9% Zn, 26.5% Pb, 55.4% Ni and 58.8% Cd from the residues. Subsequent washing further reduces the heavy metal content in the residues larger than 2.36 mm, with preferable conditions being 400 rpm rotation speed, 5 min washing duration and liquid-to-solid ratio of 25:1. The highest cumulative removal efficiencies of Cu, Zn, Pb, Ni and Cd after sieving and washing reached 81.1%, 61.4%, 75.8%, 97.2% and 72.7%, respectively. The combined sieving and washing process is environmentally friendly, can be used for the removal of heavy metals from the residues and has benefits in terms of heavy metal recycling.

  5. Separation of CO2 in a Solid Waste Management Incineration Facility Using Activated Carbon Derived from Pine Sawdust

    Directory of Open Access Journals (Sweden)

    Inés Durán

    2017-06-01

    Full Text Available The selective separation of CO2 from gas mixtures representative of flue gas generated in waste incineration systems is studied on two activated carbons obtained from pine sawdust and compared to a commercial activated carbon. Dynamic adsorption experiments were conducted in a fixed-bed adsorption column using a binary mixture (N2/CO2 with a composition representative of incineration streams at temperatures from 30 to 70 °C. The adsorption behavior of humid mixtures (N2/CO2/H2O was also evaluated in order to assess the influence of water vapor in CO2 adsorption at different relative humidity in the feed gas: 22% and 60%. Moreover, CO2 adsorption was studied in less favorable conditions, i.e., departing from a bed initially saturated with H2O. In addition, the effect of CO2 on H2O adsorption was examined. Experimental results showed that the CO2 adsorption capacity can be reduced significantly by the adsorption of H2O (up to 60% at high relative humidity conditions. On the other hand, the breakthrough tests over the adsorbent initially saturated with water vapor indicated that H2O is little affected by CO2 adsorption. The experimental results pointed out the biomass based carbons as best candidates for CO2 separation under incineration flue gas conditions.

  6. Comparison of dioxins and related compounds in the emission during the start-up procedures at a municipal waste incinerator

    Energy Technology Data Exchange (ETDEWEB)

    Gass, H.C.; Suenderhauf, W. [GfA - Gesellschaft fuer Arbeitsplatz und Umweltanalytik mbH, Berlin (Germany); Lueder, K. [MVB Muellverwertung Borsigstrasse GmbH, Hamburg (Germany); Wilken, M. [MWC - Michael Wilken Consulting, Berlin (Germany)

    2004-09-15

    In 2002/2003 we reported about PCDD/F-emissions during the start-up of a municipal waste incinerator. With primary and secondary measures during the optimization of the cold start-up phase we could show a sustainable reduction of the stack gas emissions of PCDD/F down to the range of normal operation even in the start-up phase. The measurement results of chlorophenols (ClP) and chlorobenzenes (ClB) in the flue gas (sampling point ''after boiler'') during cold-start up procedure of selected campaigns will be discussed in this paper.

  7. Burning mill sludge in a fluidized-bed incinerator and waste-heat-recovery system; Ten years of successful operation

    Energy Technology Data Exchange (ETDEWEB)

    Nickull, O. (Metsa Serla, Oy (FI)); Lehtonen, O. (Tampella Ltd., Tampere (FI)); Mullen, J. (Tampella Keeler, Williamsport, PA (US))

    1991-03-01

    This paper reports on burning mill sludge in a fluidized-bed incinerator and waste-heat-recovery system. In the late 1970s, the Lielahti sulfite mill of G.A. Serlachius Corp. (now Metsa Serla Oy) began investigating alternative methods of sludge disposal. The mill had an annual capacity of 100,000 tons of bleached pulp, generated 80,000 tons of by-product lignin sulfonates, and specialized in dissolving pulps. Because of the end product's high quality requirements, the mill had a low pulp yield and high losses in the form of both dissolved and suspended solids.

  8. Optimised utilisation of existing incinerators by installation of upstream reactors for treatment of waste with high calorifica value - HYBRID waste treatment plants; Optimierte Nutzung bestehender Abfallverbrennungsanlagen durch Errichtung vorgeschalteter Reaktoren zur Behandlung heizwertreicher Abfaelle - HYBRID-Abfallbehandlungsanlagen

    Energy Technology Data Exchange (ETDEWEB)

    El Labani, M.

    2000-07-01

    Waste incineration plants are based on the process of thermal waste treatment, i.e. the generation of power from the controlled conversion of organic reactive residue waste. Statutory requirements forced operators to install powerful flue gas cleaning systems into their existing waste incineration plants. This led to a tremendous increase in cost and treatment prices generating pressure to optimize the process. Currently, markets demand additional capacities for the treatment of waste of elevated heating value ({proportional_to}5,0 MWh/Mg). It is possible to treat this type of waste in a conventional waste incineration plant. However, the elevated heating value dictates a reduction in throughput with ever increasing pressure on costs. This is why current concepts consider the treatment of waste of elevated heating value in specific, so called de-centralized plants. These plants are usually of low throughput with accordingly high specific cost of developing the infrastructure. The capacity of existing waste incineration plants has been investigated in order to assess the potential for optimization. Extensive test runs at the Municipal Solid Waste Incineration Plant (MSW) Darmstadt revealed a capacity gap in the flue gas cleaning system even with the incineration unit running at full capacity. This gap could be filled with an additional incineration plant for waste of elevated heating value, whose capacity is matched accordingly. Such additional incineration plant defines in conjunction with the existing waste incineration plant a so called HYBRID Waste Treatment Plant. It is the aim of this treatise to develop an instrument to support the decision making process related to the planning of such plants. (orig.) [German] Abfallverbrennungsanlagen basieren auf dem Verfahren der thermischen Abfallbehandlung; das ist die Energieerzeugung aus der kontrollierten Umwandlung organischer, reaktionsfaehiger Restabfaelle. Aufgrund gesetzlicher Vorgaben mussten bestehende

  9. Leaching studies of inorganic and organic compounds from fly ash

    NARCIS (Netherlands)

    Ariese, F.; Swart, K.; Morabito, R.; Brunori, C.; Balzamo, S.; Slobodnik, J.; Korenkova, E.; Janos, P.; Wildnerova, M.; Hlavay, J.; Polyak, K.; Fodor, P.; Muntau, H.

    2002-01-01

    Fly ash is produced in massive quantities by fossil fuel based power plants and waste incinerators, and contains high levels of potentially toxic chemicals. Various leaching tests exist to determine the available fractions, but the outcome is strongly dependent on the experimental conditions, and

  10. Synthesis of hydroxy sodalite from coal fly ash using waste industrial brine solution.

    Science.gov (United States)

    Musyoka, Nicholas M; Petrik, Leslie F; Balfour, Gillian; Gitari, Wilson M; Hums, Eric

    2011-01-01

    The effect of using industrial waste brine solution instead of ultra pure water was investigated during the synthesis of zeolites using three South African coal fly ashes as Si feedstock. The high halide brine was obtained from the retentate effluent of a reverse osmosis mine water treatment plant. Synthesis conditions applied were; ageing of fly ash was at 47 ° C for 48 hours, and while the hydrothermal treatment temperature was set at 140 ° C for 48 hours. The use of brine as a solvent resulted in the formation of hydroxy sodalite zeolite although unconverted mullite and hematite from the fly ash feedstock was also found in the synthesis product.

  11. Regular recycling of Wood Ash to Prevent Waste Production. Recash a Life-Environment Demonstration Project

    Energy Technology Data Exchange (ETDEWEB)

    Andersson, Lars; Emilsson, Stig [Swedish Forest Agency, Karlstad (Sweden)

    2006-07-01

    At present, the extraction of harvest residues is predicted to increase in Sweden and Finland. As an effect of the intensified harvest, the export of nutrients and acid buffering substances from the growth site is also increased. Wood ash could be used to compensate forest soils for such losses. Most wood fuel ash is today deposited in landfills. If the wood ash is recycled, wood energy is produced without any significant waste production. Ash recycling would therefore contribute to decreasing the production of waste, and to maintaining the chemical quality of forest waters and biological productivity of forest soils in the long term. In order to create better conditions for a regular recycling of wood, the Swedish Forest Agency took the initiative for creating a LIFE-Environment demonstration project. The project has developed, analysed and demonstrated two regular ash-recycling systems. It has also distribute knowledge gathered about motives for ash recycling as well as technical and administrative solutions through a range of media (handbooks, workshops, field demonstrations, reports, web page and information videos). Hopefully, the project will contribute to decreasing waste problems related to bio-energy production in the EU at large.

  12. Coupling scales for modelling heavy metal vaporization from municipal solid waste incineration in a fluid bed by CFD.

    Science.gov (United States)

    Soria, José; Gauthier, Daniel; Flamant, Gilles; Rodriguez, Rosa; Mazza, Germán

    2015-09-01

    Municipal Solid Waste Incineration (MSWI) in fluidized bed is a very interesting technology mainly due to high combustion efficiency, great flexibility for treating several types of waste fuels and reduction in pollutants emitted with the flue gas. However, there is a great concern with respect to the fate of heavy metals (HM) contained in MSW and their environmental impact. In this study, a coupled two-scale CFD model was developed for MSWI in a bubbling fluidized bed. It presents an original scheme that combines a single particle model and a global fluidized bed model in order to represent the HM vaporization during MSW combustion. Two of the most representative HM (Cd and Pb) with bed temperatures ranging between 923 and 1073K have been considered. This new approach uses ANSYS FLUENT 14.0 as the modelling platform for the simulations along with a complete set of self-developed user-defined functions (UDFs). The simulation results are compared to the experimental data obtained previously by the research group in a lab-scale fluid bed incinerator. The comparison indicates that the proposed CFD model predicts well the evolution of the HM release for the bed temperatures analyzed. It shows that both bed temperature and bed dynamics have influence on the HM vaporization rate. It can be concluded that CFD is a rigorous tool that provides valuable information about HM vaporization and that the original two-scale simulation scheme adopted allows to better represent the actual particle behavior in a fluid bed incinerator. Copyright © 2015 Elsevier Ltd. All rights reserved.

  13. Recycling by the brick making industry of ashes from sewage sludge incineration; Verwertung von Aschen der Klaerschlammverbrennung in der Ziegelindustrie

    Energy Technology Data Exchange (ETDEWEB)

    Wiebusch, B.; Seyfried, C.F. [Hannover Univ. (Germany). ISAH Inst. fuer Siedlungswasserwirtschaft und Abfalltechnik

    1998-09-01

    The present project focuses on the recycling of sewage sludge ashes by the brick making industry. The following aspects are dealt with in detail: Overview of the state of the art of sewage sludge combustion in Germany; influence of wastewater and sludge treatment on ash quality (determination of the seasonal course of chemical sewage sludge composition); use of sewage sludge ashes in as loading material in fluidised-bed furnaces or as clay substitute in brick manufacture; semi-technical trials in ceramic laboratories; assessment of the environmental impact of bricks containing sewage sludge ash; performance of leaching experiments; and examination of the mineralogical binding of heavy metals into the ceramic matrix. [Deutsch] Das Projekt konzentriert sich dabei auf eine Verwertung von Klaerschlammaschen in der Ziegelindustrie, wobei die im folgenden genannten Aspekte im Einzelnen bearbeitet werden: - Ueberblick ueber den Stand der Technik bei der Klaerschlammverbrennung in Deutschland - Einfluss der Abwasser- und Schlammbehandlung auf die Aschequalitaet (Ermittlung von Jahresganglinien der chemischen Zusammensetzung von Klaerschlammaschen) - Einsatz von Klaerschlammaschen aus Wirbelschichtoefen als Zuschlagstoff bzw. Tonersatz bei der Ziegelproduktion - halbtechnische Versuche im keramischen Labor - Abschaetzung der Umweltvertraeglichkeit von Ziegeln mit Klaerschlammaschezusatz: Durchfuehrung von Auslangversuchen, Untersuchung einer mineralogischen Einbindung von Schwermetallen in die keramische Matrix. (orig./SR)

  14. Calcium and organic matter removal by carbonation process with waste incineration flue gas towards improvement of leachate biotreatment performance.

    Science.gov (United States)

    Zhang, Cheng; Zhu, Xuedong; Wu, Liang; Li, Qingtao; Liu, Jianyong; Qian, Guangren

    2017-09-01

    Municipal solid wastes incineration (MSWI) flue gas was employed as the carbon source for in-situ calcium removal from MSWI leachate. Calcium removal efficiency was 95-97% with pH of 10.0-11.0 over 100min of flue gas aeration, with both bound Ca and free Ca being removed effectively. The fluorescence intensity of tryptophan, protein-like and humic acid-like compounds increased after carbonation process. The decrease of bound Ca with the increase of precipitate indicated that calcium was mainly converted to calcium carbonate precipitate. It suggested that the interaction between dissolved organic matter and Ca(2+) was weakened. Moreover, 10-16% of chemical oxygen demand removal and the decrease of ultraviolet absorption at 254nm indicated that some organics, especially aromatic compound decreased via adsorption onto the surface of calcium carbonate. The results indicate that introduce of waste incineration flue gas could be a feasible way for calcium removal from leachate. Copyright © 2017 Elsevier Ltd. All rights reserved.

  15. Life Cycle Assessment of Thermal Treatment Technologies. An environmental and financial systems analysis of gasification, incineration and landfilling of waste

    Energy Technology Data Exchange (ETDEWEB)

    Assefa, Getachew; Eriksson, Ola [Royal Inst. of Tech., Stockholm (Sweden). Industrial Ecology; Jaeraas, Sven; Kusar, Henrik [Royal Inst. of Tech., Stockholm (Sweden). Chemical Technology

    2003-05-01

    A technology which is currently developed by researchers at KTH is catalytic combustion. which is one component of a gasification system. Instead of performing the combustion in the gas turbine by a flame, a catalyst is used. When the development of a new technology (as catalytic combustion) reaches a certain step where it is possible to quantify material-, energy- and capital flows, the prerequisites for performing a systems analysis is at hand. The systems analysis can be used to expand the know-how about the potential advantages of the catalytic combustion technology by highlighting its function as a component of a larger system. In this way it may be possible to point out weak points which have to be investigated more, but also strong points to emphasise the importance of further development. The aim of this project was to assess the energy turnover as well as the potential environmental impacts and economic costs of thermal treatment technologies in general and catalytic combustion in particular. By using a holistic assessment of the advantages and disadvantages of catalytic combustion of waste it was possible to identify the strengths and weaknesses of the technology under different conditions. Following different treatment scenarios have been studied: (1) Gasification with catalytic combustion, (2) Gasification with flame combustion, (3) Incineration with energy recovery and (4) Landfilling with gas collection. In the study compensatory district heating is produced by combustion. of biofuel. The power used for running the processes in the scenarios is supplied by the waste-to-energy technologies themselves while compensatory power is assumed to be produced. from natural gas. The emissions from the system studied were classified and characterised using methodology from Life Cycle Assessment into the following environmental impact categories: Global Warming Potential, Acidification Potential, Eutrophication Potential and finally Formation of Photochemical

  16. Global warming potential of material fractions occurring in source-separated organic household waste treated by anaerobic digestion or incineration under different framework conditions

    DEFF Research Database (Denmark)

    Naroznova, Irina; Møller, Jacob; Scheutz, Charlotte

    2016-01-01

    This study compared the environmental profiles of anaerobic digestion (AD) and incineration, in relation to global warming potential (GWP), for treating individual material fractions that may occur in source-separated organic household waste (SSOHW). Different framework conditions representative....... The study was performed using a life cycle assessment in its consequential approach. Furthermore, the role of waste-sorting guidelines (defined by the material fractions allowed for SSOHW) in relation to GWP of treating overall SSOHW with AD was investigated. A case-study of treating 1tonne of SSOHW under...... framework conditions in Denmark was conducted. Under the given assumptions, vegetable food waste was the only material fraction which was always better for AD compared to incineration. For animal food waste, kitchen tissue, vegetation waste and dirty paper, AD utilisation was better unless it was compared...

  17. Waste Minimization Protocols for the Process of Synthesizing Zeolites from South African Coal Fly Ash

    OpenAIRE

    Petrik, Leslie F.; Tunde V. Ojumu; Du Plessis, Pieter W.

    2013-01-01

    Production of a high value zeolite from fly ash has been shown to be an avenue for the utilization of South African fly ash which presently constitutes a huge disposal problem. The synthesis of zeolites Na-P1 and analcime on a micro-scale has been successful and preliminary investigation shows that scale-up synthesis is promising. However, the post-synthesis supernatant waste generated contains high levels of NaOH that may constitute a secondary disposal problem. A waste minimization protocol...

  18. Vitrification of Rocky Flats ash followed by encapsulation in the Defense Waste Processing Facility

    Energy Technology Data Exchange (ETDEWEB)

    McKibben, J.M. [Westinghouse Savannah River Co., Aiken, SC (United States); Land, B. [Safe Sites of Colorado, Golden, CO (United States); Strachan, D.M. [Argonne National Lab., IL (United States); Perez, J.M. [Pacific Northwest Lab., Richland, WA (United States)

    1995-12-31

    Approximately 10 to 20 metric tons of plutonium in the US is in the form of scrap, residues, oxides, ash, metal, sludge, compounds, etc. This paper describes a relatively simple concept of stabilizing most of this type of plutonium by converting it into encapsulated glass. A full-scale hot demonstration of the concept is proposed, in which Rocky Flats ash would be vitrified and sealed in small cans, followed by encapsulation of the cans in Defense Waste Processing Facility (DWPF) canisters with high-level waste glass. The proposal described in this paper offers an integrated national approach for early stabilization and disposition of the nation`s plutonium-bearing residues.

  19. Using cement, lignite fly ash and baghouse filter waste for solidification of chromium electroplating treatment sludge

    OpenAIRE

    Wantawin, C.; Chobthiangtham, P.

    2004-01-01

    The objective of the study is to use baghouse filter waste as a binder mixed with cement and lignite fly ash to solidify sludge from chromium electroplating wastewater treatment. To save cost of solidification, reducing cement in binder and increasing sludge in the cube were focused on. Minimum percent cement in binder of 20 for solidification of chromium sludge was found when controlling lignite fly ash to baghouse filter waste at the ratio of 30:70, sludge to binder ratio of 0.5, water to m...

  20. Quantification of the resource recovery potential of municipal solid waste incineration bottom ashes

    DEFF Research Database (Denmark)

    Allegrini, Elisa; Maresca, Alberto; Olsson, Mikael Emil

    2014-01-01

    data, all individual flows (representing different grain size fractions) within the recovery facility were quantified, (ii) the resource potential of ferrous (Fe) and non-ferrous (NFe) metals as well as rare earth elements (REE) was determined, (iii) recovery efficiencies were quantified for scrap...... initiatives for these elements....

  1. Solidification of fly ash from municipal solid waste incinerator by the use of sorel cement

    Directory of Open Access Journals (Sweden)

    Hepworth Malcolm T.

    1996-03-01

    Full Text Available Spaľovanie tuhého komunálneho odpadu významne redukuje objem a hmotnosť tuhého komunálneho odpadu, avšak zvyšky po spaľovaní sú klasifikované ako nebezpečné odpady. Použitím stabilizačnej technológie solidifikácie popolčeka z elektrostatických odlučovačov spaľovne na komunálny odpad využitím Sorelovho cementu vznikne popolčekový cement, ktorého environmentálne a inžinierske vlastnosti ponúkajú možnosť jeho užitočného využitia pre účely stavebníctva.

  2. Waste incineration models for operation optimization. Phase 1: Advanced measurement equipment for improved operation of waste fired plants; Affaldsforbraendingsmodeller til driftsoptimering. Fase 1: Avanceret maeleudstyr til forbedret drift af affaldsfyrede anlaeg

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2005-06-01

    This report describes results from the PSO projects ELTRA-5294 and ELTRA-5348: Waste incineration models for operation optimization. Phase 1, and Advanced measurement equipment for improved operation of waste fired plants. Phase 1. The two projects form the first step in a project course build on a long-term vision of a fully automatic system using a wide range of advanced measurement data, advanced dynamic models for prediction of operation and advanced regulation methods for optimization of the operation of waste incinerator plants. (BA)

  3. Waste to energy – key element for sustainable waste management

    Energy Technology Data Exchange (ETDEWEB)

    Brunner, Paul H., E-mail: paul.h.brunner@tuwien.ac.at; Rechberger, Helmut

    2015-03-15

    Highlights: • First paper on the importance of incineration from a urban metabolism point of view. • Proves that incineration is necessary for sustainable waste management. • Historical and technical overview of 100 years development of MSW incineration. - Abstract: Human activities inevitably result in wastes. The higher the material turnover, and the more complex and divers the materials produced, the more challenging it is for waste management to reach the goals of “protection of men and environment” and “resource conservation”. Waste incineration, introduced originally for volume reduction and hygienic reasons, went through a long and intense development. Together with prevention and recycling measures, waste to energy (WTE) facilities contribute significantly to reaching the goals of waste management. Sophisticated air pollution control (APC) devices ensure that emissions are environmentally safe. Incinerators are crucial and unique for the complete destruction of hazardous organic materials, to reduce risks due to pathogenic microorganisms and viruses, and for concentrating valuable as well as toxic metals in certain fractions. Bottom ash and APC residues have become new sources of secondary metals, hence incineration has become a materials recycling facility, too. WTE plants are supporting decisions about waste and environmental management: They can routinely and cost effectively supply information about chemical waste composition as well as about the ratio of biogenic to fossil carbon in MSW and off-gas.

  4. Very low emissions of airborne particulate pollutants measured from two municipal solid waste incineration plants in Switzerland

    Science.gov (United States)

    Setyan, Ari; Patrick, Michael; Wang, Jing

    2017-10-01

    A field campaign has been performed in two municipal solid waste incineration (MSWI) plants in Switzerland, at Hinwil (ZH) and Giubiasco (TI). The aim was to measure airborne pollutants at different locations of the abatement systems (including those released from the stacks into the atmosphere) and at a near-field (∼1 km) downwind site, in order to assess the efficiency of the abatement systems and the environmental impact of these plants. During this study, we measured the particle number concentration with a condensation particle counter (CPC), and the size distribution with a scanning mobility particle sizer (SMPS) and an aerodynamic particle sizer (APS). We also sampled particles on filters for subsequent analyses of the morphology, size and elemental composition with a scanning electron microscope coupled to an energy dispersive X-ray spectroscope (SEM/EDX), and of water soluble ions by ion chromatography (IC). Finally, volatile organic compounds (VOCs) were sampled on adsorbing cartridges and analyzed by thermal desorption-gas chromatography/mass spectrometry (TD-GC/MS), and a portable gas analyzer was used to monitor NO, SO2, CO, CO2, and O2. The particle concentration decreased significantly at two locations of the plants: at the electrostatic precipitator and the bag-house filter. The particle concentrations measured at the stacks were very low (<100 #/cm3), stressing the efficiency of the abatement system of the two plants. At Hinwil, particles sampled at the stack were mainly constituted of NaCl and KCl, two salts known to be involved in the corrosion process in incinerators. At Giubiasco, no significant differences were observed for the morphology and chemical composition of the particles collected in the ambient background and at the downwind site, suggesting that the incineration plant released very limited amounts of particles to the surrounding areas.

  5. MSWI bottom ash for thermal energy storage: An innovative and sustainable approach for its reutilization

    OpenAIRE

    Valle-Zermeño, Ricardo del; Barreneche Güerisoli, Camila; Cabeza, Luisa F.; Formosa, Joan; Fernández, Ana Inés; Chimenos, J. M.

    2016-01-01

    The management of Municipal Solid Waste (MSW) is a very important issue that must be dealt by the perspective of the 3 Rs (Reuse, reduce, recycle. MSW incineration bottom ash (BA) accounts for 85–95% of the total solids that remained after incineration. Finding suitable alternatives for its revalorization is very attractive, especially in terms of environmental sustainability. Thermal energy storage (TES) is a complementary technology of renewable energy. The aim of this study is to evaluate ...

  6. Molecular hydrogen (H2) combustion emissions and their isotope (D/H) signatures from domestic heaters, diesel vehicle engines, waste incinerator plants, and biomass burning

    NARCIS (Netherlands)

    Vollmer, M.K.; Walter, S.; Mohn, J.; Steinbacher, M.; Bond, S.W.; Röckmann, T.|info:eu-repo/dai/nl/304838233; Reimann, S.

    2012-01-01

    Molecular hydrogen (H2), its stable isotope signature ( D), and the key combustion parameters carbon monoxide (CO), carbon dioxide (CO2), and methane (CH4) were measured from various combustion processes. H2 in the exhaust of gas and oil-fired heaters and of waste incinerator plants was generally

  7. Establishment of line A and partial renovation of the infrastructure of the waste incinerator Berlin Ruhleben during operation; Errichtung der Linie A und teilweise Erneuerung der Infrastruktur im laufenden Betrieb der Abfallverbrennungsanlage Berlin Ruhleben

    Energy Technology Data Exchange (ETDEWEB)

    Gosten, Alexander [Berliner Stadtreinigungsbetriebe (BSR), Berlin (Germany). Abfallverwertung und -beseitigung; Hauser, Ralf; Rintel, Bernd; Hensel, Jochen [Berliner Stadtreinigungsbetriebe (BSR), Berlin (Germany). Projekt ERIN/Bunkerertuechtigung

    2013-03-01

    In the light of the implementation of the Technical Guidelines for the treatment and disposal of municipal waste, the incineration of waste materials in the thermal power plant Berlin-Ruhleben (Federal Republic of Germany) awarded a crucial importance in the waste management concept of the Land of Berlin. The contribution describes the construction of the line A and partial renovation of the infrastructure of the waste incinerator Berlin Ruhleben. First of all, the history of the former waste incinerator and the partial renovation as well as the starting situation and the basis for decision-making for replacement investments are described. Subsequently, the project ERIN is presented, in which components of the existing waste incinerator are substituted. Further aspects of this contribution are the general conditions for the development of the project organisation, requirements relative to the project organisation, accessibility of the project organization to the business unit.

  8. Reuse and recycling options for solid prescribed industrial wastes and brown coal fly ash

    OpenAIRE

    Seyoum Hailu, Tesfaye

    2017-01-01

    This dissertation presents the results of detailed investigation of the possible use of stabilised sludge and brown coal fly ash as raw material ingredients for road construction and manufacture of building bricks. The thesis is organised into seven chapters including a general introduction chapter. A literature review of solid waste management practices employed in Australia and some selected countries are discussed (chapter 1) together with waste generation from power station...

  9. Characterization of flue gas, fly ash, aerosol and deposit compositions as a function of waste composition and grate operation

    DEFF Research Database (Denmark)

    Pedersen, Anne Juul; Zeuthen, Frederik Jacob; Frandsen, Flemming

    2007-01-01

    The Danish strategy for waste management is still to increase recycling and on the same time to reduce the volume of land-filled waste, in order to avoid loss of resources, and waste incineration is an important part of this strategy. In 2004, 26 % of the total reported Danish waste production...... metals, was then mixed with the reference fuel in the individual test runs. The dedicated waste fractions comprised NaCl (road salt), batteries, automotive shredder waste, CCA (Copper-Chromate-Arsenate)-impregnated wood, PVC plastics, and (leather) shoes. Test runs with varying operational parameters, e...

  10. Electrodialytic removal of heavy metals from different fly ashes. Influence of heavy metal speciation in the ashes

    DEFF Research Database (Denmark)

    Pedersen, Anne Juul; Ottosen, Lisbeth M.; Villumsen, Arne

    2003-01-01

    in lab scale, and the results were discussed in relation to the expected heavy metal speciation in the ashes. In initial leaching experiments the pH-dependent desorption characteristics of the heavy metals Cd, Pb, Zn and Cu were analogous in the two MSWI ashes, and thus it was expected...... that the speciation of these metals was similar in the two ashes. On the other hand, the leaching behaviour (and concentration) of Cr was diverse. The apparent similar speciation of Cd, Pb, Zn and Cu was only partly confirmed in the following electrodialytic remediation experiments. Significant differences in re......Electrodialytic Remediation has recently been suggested as a potential method for removal of heavy metals from fly ashes. In this work electrodialytic remediation of three different fly ashes, i.e. two municipal solid waste incinerator (MSWI) fly ashes and one wood combustion fly ash was studied...

  11. Effect of carbide waste on the properties of rice husk ash concrete ...

    African Journals Online (AJOL)

    The impact of carbide waste,CW on the strength of concrete made with cement partially replaced with Rice Husk Ash,RHA for use in rigid pavement was investigated. Oxide composition analysis of CW and RHA confirm their status as non pozzolanic material rich in CaO component and pozzolanic materials, respectively.

  12. Sustainable asphalt pavement: Application of slaughterhouse waste oil and fly ash in asphalt binder

    Science.gov (United States)

    Sanchez Ramos, Jorge Luis

    Increasing energy costs, lack of sufficient natural resources and the overwhelming demand for petroleum has stimulated the development of alternative binders to modify or replace petroleum-based asphalt binders. In the United States, the petroleum-based asphalt binder is mainly used to produce the Hot Mix Asphalt (HMA). There are approximately 4000 asphalt plants that make 500 million tons of asphalt binder valued at roughly 3 billion/year. The instability of the world's oil market has pushed oil prices to more than 80 per barrel in 2012, which increased the cost of asphalt binder up to $570 per ton. Therefore, there is a timely need to find alternative sustainable resources to the asphalt binder. This paper investigates the possibility of the partial replacement of the asphalt binder with slaughterhouse waste and/or fly ash. In order to achieve this objective, the asphalt binder is mixed with different percentages of waste oil and/or fly ash. In order to investigate the effect of these additives to the performance of the asphalt binder, a complete performance grade test performed on multiple samples. The results of the performance grade tests are compared with a control sample to observe how the addition of the waste oil and/or fly ash affects the sample. Considering the increasing cost and demand of asphalt, the use of slaughterhouse waste oil and/or fly ash as a partial replacement may result in environmental and monetary improvements in the transportation sector.

  13. Effect of Cement–Locust Bean Waste Ash Blend on the Gradation ...

    African Journals Online (AJOL)

    OPC) and up to 8% locust bean waste ash (LBWA) by dry weight of soil to investigate its effect on the gradation and plasticity characteristics of the modified soil. Test results generally show that the gradation and plasticity characteristics of the ...

  14. Properties of concrete modified with waste Low Density Polyethylene and saw dust ash

    Science.gov (United States)

    Srimanikandan, P.; Sreenath, S.

    2017-07-01

    The increase in industrialization creates need for disposal of large quantity of by-products. To overcome the difficulty of disposal, these by-products can be used as a replacement for raw material. In this concern, non-conventional industrial wastes such as plastic bags, PET bottles, pulverized waste Low Density Polyethylene (LDPE) and biological waste such as saw-dust ash, coconut coir were used as a replacement in concrete. In this project, saw-dust ash and pulverized waste LDPE were introduced as the partial replacement for cement and fine aggregates respectively. 0%, 5%, 10%, 15% and 20% of sand by volume was replaced with LDPE and 0%, 1%, 3%, 5% and 10% of cement by volume was replaced with saw dust ash. Standard cube, cylinder and prism specimens were cast to assess the compressive strength, split tensile strength and flexural strength of modified concrete after 28 days of curing. Optimum percentage of replacement was found by comparing the test results. The mix with 5% of LDPE and 3% of saw dust ash showed a better result among the other mixes.

  15. A study of transformation water - soluble forms of hevy metals at waste incenerator for detoxicationof ash.

    Directory of Open Access Journals (Sweden)

    Bilets'ka V. А.

    2011-11-01

    Full Text Available The complex research processes of transformation of soluble forms of heavy metals in sediment interaction with ash. Proved that the adsorption processes of immobilization lead to a significant decrease of soluble forms of heavy metals in the waste.

  16. Effect of municipal solid waste ash on the strength of earthen bricks ...

    African Journals Online (AJOL)

    The aim of this study was to evaluate the effect of different amounts of Municipal Solid Waste Ash (MSWA) on the strength characteristics of the walls subjected to compressive loads. The soil used for making the bricks was stabilized using MSWA applied at the rate of 0%, 2%, 5% and 10% of the weight of soil.

  17. The evaluation of chosen properties of ashes created by thermal utilization of hazardous and communal wastes

    Directory of Open Access Journals (Sweden)

    Damian Krawczykowski

    2005-11-01

    Full Text Available One of methods of the waste neutralization is their thermal transformation in suitable installations or devices in order to achieve the state, which is no longer dangerous for the human health and life or for the environment. In effect of the thermal transformation the “new” wastes are created, which, by law are suppose a to be utilized first. These wastes may be utilized if their properties are suitable. In the paper, the process of thermal utilization of hazardous and municipal wastes is presented, together with the investigation results of the grain composition, surface area, density and of the initial chemical analysis of the created ashes. The research of the grain composition was conducted by using the “Fritsch” apparatus. On the base of the grain composition, the surface area of ashes under investigation was determined, whereas the density was determined by using the helium pycnometer. The purpose of the research was to determine how the properties of ashes are changed and if the differences allow to use these ashes in future.

  18. Industrial-scale heat pump in a waste incinerator; Grosswaermepumpe in einer Muellverbrennungsanlage

    Energy Technology Data Exchange (ETDEWEB)

    Bailer, P. [Sulzer Friotherm, Winterthur (Switzerland)

    2000-12-01

    Umea Energi AG at Umea in northern Sweden constructed an incinerator of 20 t/h. The plant was designed for maximum ecological acceptability and is probably the world's most economical incinerator. Incineration is combined with heat and power generation in two Sulzer Friotherm UNITOP28 heat pumps with a total capacity of about 14 MW{sub th} at a water temperature of 75 C and with R134a as refrigerant. The wet flue gas leaving the scrubber is condensed and serves as heat source. Heat recovery enhances the total efficiency of the plant from 94% to 107% - quite a perpetuum mobile?. [German] Umea Energi AG in Umea Nordschweden hat eine neue Muellverbrennungsanlage fuer eine Muellmenge von 20 t/h gebaut. Die Muellverbrennung erfuellt strengste Umweltanforderungen und ist vermutlich die wirtschaftlichste Muellverbrennungsanlage der Welt. Die Verbrennung wird kombiniert mit der Erzeugung von Strom- und Heiz-Energie. Als wichtiger Teil in dieser Anlage ist der Einsatz von zwei Sulzer Friotherm Grosswaermepumpen UNITOP28 mit einer gesamten Heizleistung von ca. 14 MW bei einer Heizwassertemperatur von 75 C mit R134a als Kaeltemittel. Das durch die Rauchgaswaesche feuchte Rauchgas wird kondensiert und dient als Waermequelle. Die Waermerueckgewinnung durch die Waermepumpen erhoeht den Gesamtwirkungsgrad der Anlage von 94% auf 107% - somit ein Perpetuum mobile?. (orig.)

  19. Characterization of PM2.5 particles originating from a modern waste incineration plant by factor analysis of chemical data, mass and black carbon in ambient aerosol

    DEFF Research Database (Denmark)

    Aboh, Innocent Joy Kwame; Henrikson, Dag; Laursen, Jens

    are subject to restrictions are well below the allowed limits as stated by Swedish and European standards. The aim of the present work is to study the particle pollutants with emphasis on PM2.5 in the ambient air and to identify the specific contribution from the new incineration plant. Many different sources...... contribute to PM2.5 in urban air. Thus, the general problem is to characterise and identify the particle pollution, which can be attributed to gases and/or particles emitted by the waste incineration plant. For this reason aerosol samples, PM2.5, were collected and analyzed for concentrations of twenty...

  20. Elemental analysis of ash residue from combustion of CCA treated wood waste before and after electrodialytic extraction

    DEFF Research Database (Denmark)

    Pedersen, Anne Juul; Ottosen, Lisbeth M.

    2006-01-01

    Element distribution in a combined fly ash and bottom ash from combustion of copper chromate arsenate (CCA) treated wood waste was investigated by scanning electron microscopy (SEM/EDX) before and after electrodialytic extraction. The untreated ash contained various particles, including pieces....... Chemical analyses of untreated and treated ash confirmed that most As, but only smaller amounts of Cu and Cr was removed due to the electrodialytic extraction. Overall metal contents in the original ash residue were: 1.4 g As, 2.76 g Cu and 2.48 g Cr, after electrodialytic extraction these amounts were...

  1. Review: Potential Strength of Fly Ash-Based Geopolymer Paste with Substitution of Local Waste Materials with High-Temperature Effect

    Science.gov (United States)

    Subekti, S.; Bayuaji, R.; Darmawan, M. S.; Husin, N. A.; Wibowo, B.; Anugraha, B.; Irawan, S.; Dibiantara, D.

    2017-11-01

    This research provided an overview of the potential fly ash based geopolymer paste for application in building construction. Geopolymer paste with various variations of fly ash substitution with local waste material and high-temperature influence exploited with the fresh and hardened condition. The local waste material which utilized for this study were sandblasting waste, carbide waste, shell powder, bagasse ash, rice husk and bottom ash. The findings of this study indicated that fly-based geopolymer paste with local waste material substitution which had high-temperature influence ash showed a similar nature of OPC binders potentially used in civil engineering applications.

  2. Economic assessment and energy model scenarios of municipal solid waste incineration and gas turbine hybrid dual-fueled cycles in Thailand.

    Science.gov (United States)

    Udomsri, Seksan; Martin, Andrew R; Fransson, Torsten H

    2010-07-01

    Finding environmentally benign methods related to sound municipal solid waste (MSW) management is of highest priority in Southeast Asia. It is very important to study new approaches which can reduce waste generation and simultaneously enhance energy recovery. One concrete example of particular significance is the concept of hybrid dual-fuel power plants featuring MSW and another high-quality fuel like natural gas. The hybrid dual-fuel cycles provide significantly higher electrical efficiencies than a composite of separate single-fuel power plant (standalone gas turbine combined cycle and MSW incineration). Although hybrid versions are of great importance for energy conversion from MSW, an economic assessment of these systems must be addressed for a realistic appraisal of these technologies. This paper aims to further examine an economic assessment and energy model analysis of different conversion technologies. Energy models are developed to further refine the expected potential of MSW incineration with regards to energy recovery and environmental issues. Results show that MSW incineration can play role for greenhouse gas reduction, energy recovery and waste management. In Bangkok, the electric power production via conventional incineration and hybrid power plants can cover 2.5% and 8% of total electricity consumption, respectively. The hybrid power plants have a relative short payback period (5 years) and can further reduce the CO(2) levels by 3% in comparison with current thermal power plants. Copyright (c) 2010 Elsevier Ltd. All rights reserved.

  3. Mercury risk assessment combining internal and external exposure methods for a population living near a municipal solid waste incinerator.

    Science.gov (United States)

    Deng, Chunyan; Xie, Han; Ye, Xuejie; Zhang, Haoran; Liu, Maodian; Tong, Yindong; Ou, Langbo; Yuan, Wen; Zhang, Wei; Wang, Xuejun

    2016-12-01

    Risk assessments for human health have been conducted for municipal solid waste incinerators (MSWIs) in many western countries, whereas only a few risk assessments have been performed for MSWIs in developing countries such as China where the use of waste incineration is increasing rapidly. To assess the mercury exposure risks of a population living near the largest MSWI in South China, we combined internal exposure and external exposure assessment with an individual-specific questionnaire. The mercury concentrations in air, soil, and locally collected food around the MSWI were assessed. The total mercury (T-Hg) and methylmercury (MeHg) of 447 blood samples from a control group, residential exposure group, and MSWI workers were measured. The internal and external exposures of the subject population were analyzed. Significant difference in MeHg concentrations was observed between the control group and the exposed group, between the control group and the MSWI workers, and between the exposed group and the MSWI workers (median levels: 0.70 μg/L, 0.81 μg/L, and 1.02 μg/L for the control group, exposed group, and MSWI workers, respectively). The MeHg/T-Hg ratio was 0.51 ± 0.19, 0.59 ± 0.17 and 0.58 ± 0.25, respectively. Multiple linear regression analysis indicated that MeHg concentrations were positively correlated with the gaseous mercury in the air. Combining internal and external exposure assessment showed that the direct contribution of MSWI emissions was minor compared with the dietary contribution. The external and internal exposures were well matched with each other. This study also suggested that an integrated method combining internal and external exposure assessment with an individual-specific questionnaire is feasible to assess the risks for a population living near a MSWI. Copyright © 2016 Elsevier Ltd. All rights reserved.

  4. Decolorization of a textile vat dye by adsorption on waste ash

    Directory of Open Access Journals (Sweden)

    MIODRAG ŠMELCEROVIĆ

    2010-06-01

    Full Text Available An adsorption process using cheap adsorbents could be described as a simple, selective and low cost alternative for the treatment of colored waste water compared to conventional physical and chemical processes. In this study the use of a natural waste adsorbent–ash was investigated for the removal of a textile vat dye Ostanthren blue GCD remaining after the dyeing of cotton textile. The ash obtained as a waste material during the burning of brown coal in the heating station of Leskovac (Serbia was used for the treatment of waste waters from the textile industry, i.e., waste water after the dyeing process. The effect of ash quantity, initial dye concentration, pH and agitation time on adsorption was studied. The Langmuir model was used to describe the adsorption isotherm. Based on the analytical expression of the Langmuir model, the adsorption constants, such as adsorption capacity and adsorption energy, were found. Pseudo first and second order kinetic models were studied to evaluate the kinetic data.

  5. Review of palm oil fuel ash and ceramic waste in the production of concrete

    Science.gov (United States)

    Natasya Mazenan, Puteri; Sheikh Khalid, Faisal; Shahidan, Shahiron; Shamsuddin, Shamrul-mar

    2017-11-01

    High demand for cement in the concrete production has been increased which become the problems in the industry. Thus, this problem will increase the production cost of construction material and the demand for affordable houses. Moreover, the production of Portland cement leads to the release of a significant amount of CO2 and other gases leading to the effect on global warming. The need for a sustainable and green construction building material is required in the construction industry. Hence, this paper presents utilization of palm oil fuel ash and ceramic waste as partial cement replacement in the production of concrete. Using both of this waste in the concrete production would benefit in many ways. It is able to save cost and energy other than protecting the environment. In short, 20% usage of palm oil fuel ash and 30% replacement of ceramic waste as cement replacement show the acceptable and satisfactory strength of concrete.

  6. Waste Water Treatment-Bed of Coal Fly Ash for Dyes and Pigments Industry

    Directory of Open Access Journals (Sweden)

    Syed Farman Ali Shah

    2015-12-01

    Full Text Available The highly porous power plant waste ashes have been utilized to treat toxic effluent of a dyes manufacturing plant. An attempt has been made for the first time in Pakistan, to generate an effective and economically sound treatment facility for the toxic effluent of a dyes manufacturing plant. This is an indigenous bed which could replace expensive treatment facilities, such as reverse osmosis (RO, granulated activated carbon (GAC bed, etc. The treatment efficiency was improved by coupling coagulants with fly ash adsorbent bed. The ash was collected from coal fired boilers of power plant at Lakhra Power Generation Company, Jamshoro, Pakistan. The use of this ash resolved the disposal and environmental issues by treating wastewater of chemical, dyes and pigment industry. The treatment bed comprised of briquettes of coal fly ash coupled with commercial coagulant ferrous sulfate-lime reduced COD, color, turbidity and TSS of effluent remarkably. An adsorption capacity and chemical behavior of fly ash bed was also studied. In coagulation treatment, coagulant FeSO4-lime influenced reduction of COD, color, turbidity and TSS by 32%, 48%, 50% and 51%, respectively. The CFAB coupled with coagulant, resulted an excessive removal of color, TSS, COD, and turbidity by 88%, 92%, 67% and89%, respectively.

  7. Phosphorus and zinc dissolution from thermally gasified piggery waste ash using sulphuric acid.

    Science.gov (United States)

    Kuligowski, Ksawery; Poulsen, Tjalfe G

    2010-07-01

    Ash from thermally gasified piggery waste (GA) was treated with sulphuric acid (H(2)SO(4)) using two extraction methods. First different loads (0.39-0.98 kg H(2)SO(4)/kg ash) and concentrations (0.2-2M) were used in 3h extraction. Second, titration of 1:25 (w/w) ash:water suspension was conducted with 4M H(2)SO(4) to determine ash buffer capacity at nine pH steps from 12 to 0.1. Total P and zinc (Zn) dissolution was monitored. Optimal acid load and concentration to dissolve 94% P and 55% Zn from GA was 0.98 kg H(2)SO(4)/kg ash and 0.6M, respectively, which corresponds to acid demand of 19.2 kg H(2)SO(4)/kg P recovered. High concentrations (2M) did not improve P dissolution, but Zn was easier released. Ash buffer capacity was the highest at pH 4 and 0.1, first one due to dissolution of Ca, the second one due to autoprotolysis of water. Acid load had stronger effect on dissolution than concentration in the first method, however in the second; both factors had comparable effect. Copyright (c) 2010 Elsevier Ltd. All rights reserved.

  8. ZeroWaste BYG: Redesigning construction materials towards zero waste society

    DEFF Research Database (Denmark)

    Kirkelund, Gunvor Marie; Schmidt, Jacob Wittrup; Ottosen, Lisbeth M.

    2014-01-01

    and phosphorous from waste incineration, sewage sludge and other bio ashes [1], providing the basis to make these ash types an attractive, new material for the building sector.The amount of waste increases and it is both difficult and expensive to handle many waste types as e.g.different ashes. At the same time......The ZeroWaste research group (www.zerowaste.byg.dtu.dk) at the Department of Civil Engineering was established in 2012 and covers the broad range of expertise required for turning waste materials into attractive, new materials. Members of the group have developed methods for removal of heavy metals...... there are fewer natural resources and the general consumption increases. We wish to utilize alternative and new ash types as raw material in concrete, similarly to what was previously seen with fly ash from coal combustion and microsilica, which were both transformed from problematic waste to valuable raw...

  9. Arsenic and copper stabilisation in a contaminated soil by coal fly ash and green waste compost.

    Science.gov (United States)

    Tsang, Daniel C W; Yip, Alex C K; Olds, William E; Weber, Paul A

    2014-09-01

    In situ metal stabilisation by amendments has been demonstrated as an appealing low-cost remediation strategy for contaminated soil. This study investigated the short-term leaching behaviour and long-term stability of As and Cu in soil amended with coal fly ash and/or green waste compost. Locally abundant inorganic (limestone and bentonite) and carbonaceous (lignite) resources were also studied for comparison. Column leaching experiments revealed that coal fly ash outperformed limestone and bentonite amendments for As stabilisation. It also maintained the As stability under continuous leaching of acidic solution, which was potentially attributed to high-affinity adsorption, co-precipitation, and pozzolanic reaction of coal fly ash. However, Cu leaching in the column experiments could not be mitigated by any of these inorganic amendments, suggesting the need for co-addition of carbonaceous materials that provides strong chelation with oxygen-containing functional groups for Cu stabilisation. Green waste compost suppressed the Cu leaching more effectively than lignite due to the difference in chemical composition and dissolved organic matter. After 9-month soil incubation, coal fly ash was able to minimise the concentrations of As and Cu in the soil solution without the addition of carbonaceous materials. Nevertheless, leachability tests suggested that the provision of green waste compost and lignite augmented the simultaneous reduction of As and Cu leachability in a fairly aggressive leaching environment. These results highlight the importance of assessing stability and remobilisation of sequestered metals under varying environmental conditions for ensuring a plausible and enduring soil stabilisation.

  10. Waste Minimization Protocols for the Process of Synthesizing Zeolites from South African Coal Fly Ash

    Directory of Open Access Journals (Sweden)

    Leslie F. Petrik

    2013-04-01

    Full Text Available Production of a high value zeolite from fly ash has been shown to be an avenue for the utilization of South African fly ash which presently constitutes a huge disposal problem. The synthesis of zeolites Na-P1 and analcime on a micro-scale has been successful and preliminary investigation shows that scale-up synthesis is promising. However, the post-synthesis supernatant waste generated contains high levels of NaOH that may constitute a secondary disposal problem. A waste minimization protocol was developed to reduce the volume of waste generated with a view to enhancing the feasibility of the scale synthesis. Series of experiments were conducted in 100 mL jacketed batch reactors. Fly ash was reacted with 5 Mol NaOH on a 1:1 mass basis during the aging step, followed by hydrothermal treatment in which ultrapure water was added to the slurry. This study shows that by re-introducing the supernatant waste into the experiments in such a way that it supplies the required reagent (NaOH for the zeolite synthesis, zeolite Na-P1 and analcime can be synthesized. It also shows that the synthesis process can be altered to allow up to 100% re-use of the supernatant waste to yield high value zeolitic products. This study effectively constructed two protocols for the minimization of waste generated during the synthesis of zeolites from South African coal fly ash. This result could be used to establish a basis for legal and environmental aspects involved in the commission of a full-scale plant synthesizing zeolites NaP1 and analcime.

  11. Waste Minimization Protocols for the Process of Synthesizing Zeolites from South African Coal Fly Ash.

    Science.gov (United States)

    Plessis, Pieter W Du; Ojumu, Tunde V; Petrik, Leslie F

    2013-04-29

    Production of a high value zeolite from fly ash has been shown to be an avenue for the utilization of South African fly ash which presently constitutes a huge disposal problem. The synthesis of zeolites Na-P1 and analcime on a micro-scale has been successful and preliminary investigation shows that scale-up synthesis is promising. However, the post-synthesis supernatant waste generated contains high levels of NaOH that may constitute a secondary disposal problem. A waste minimization protocol was developed to reduce the volume of waste generated with a view to enhancing the feasibility of the scale synthesis. Series of experiments were conducted in 100 mL jacketed batch reactors. Fly ash was reacted with 5 Mol NaOH on a 1:1 mass basis during the aging step, followed by hydrothermal treatment in which ultrapure water was added to the slurry. This study shows that by re-introducing the supernatant waste into the experiments in such a way that it supplies the required reagent (NaOH) for the zeolite synthesis, zeolite Na-P1 and analcime can be synthesized. It also shows that the synthesis process can be altered to allow up to 100% re-use of the supernatant waste to yield high value zeolitic products. This study effectively constructed two protocols for the minimization of waste generated during the synthesis of zeolites from South African coal fly ash. This result could be used to establish a basis for legal and environmental aspects involved in the commission of a full-scale plant synthesizing zeolites NaP1 and analcime.

  12. Los Alamos Controlled Air Incinerator for radioactive waste. Volume II. Engineering design reference manual

    Energy Technology Data Exchange (ETDEWEB)

    Koenig, R.A.; Draper, W.E.; Newmyer, J.M.; Warner, C.L.

    1982-10-01

    This two-volume report is a detailed design and operating documentation of the Los Alamos National Laboratory Controlled Air Incinerator (CAI) and is an aid to technology transfer to other Department of Energy contractor sites and the commercial sector. Volume I describes the CAI process, equipment, and performance, and it recommends modifications based on Los Alamos experience. It provides the necessary information for conceptual design and feasibility studies. Volume II provides descriptive engineering information such as drawings, specifications, calculations, and costs. It aids duplication of the process at other facilities.

  13. The incineration of hazardous industrial wastes; La incineracion de residuos industriales peligrosos

    Energy Technology Data Exchange (ETDEWEB)

    Tinas Galvez, J. [Terraire (Spain)

    1995-08-01

    The environmental laws demand a major control of industrial waste management. The combustion is an important solution for these wastes in the European Union. This article presents the state of the art of this technology. (Author)

  14. Thermal processing technology of shredder residue. Incineration; Shredder dust no netsushori gijutsu. Shokyakuho

    Energy Technology Data Exchange (ETDEWEB)

    Hino, J. [Nikko Mikkaichi Recycle Co. Ltd., Toyama (Japan)

    1997-12-25

    A national project of technology development called the Recycle Mine Park plan for three years from FY 1996 has been proposed by MITI. Metal Group of Nippon Mining has participated in this project, and an incinerator modified from the zinc smelting equipment which has already shut down was renewed by Nikko Mikkaichi Recycle. Incineration tests on shredder dust (SD) have been conducted since November, 1996. This paper describes a progress of the investigation. For the incineration tests, SD mainly from abandoned automobiles was used. The SD is mainly composed of organic materials, and contains heavy metals, such as iron, aluminum, copper, zinc, and lead. Incinerating capacity of the test plant is 1.5 t/hr for SD, and 1.0 t/hr for liquid waste. Among non-ferrous metals in SD, copper is distributed mainly in the bottom ash, and lead and zinc are distributed mainly in the fly ash in the incineration process. It was found that the existing non-ferrous metal smelting process can be practically applied to the incineration of SD with some problems to be solved. 4 refs., 4 figs., 6 tabs.

  15. Thermal and Ash Characterization of Indonesian Bamboo and Its Potential for Solid Fuel and Waste Valorization

    Directory of Open Access Journals (Sweden)

    Aprilina Purbasari

    2016-08-01

    Full Text Available Bamboo has been widely used in Indonesia for construction, handicrafts, furniture and other uses. However, the use of bamboo as a biomass for renewable energy source has not been extensively explored. This paper describes the thermal and ash characterization of three bamboo species found in Indonesia, i.e. Gigantochloa apus, Gigantochloa levis and Gigantochloa atroviolacea. Characterization of bamboo properties as a solid fuel includes proximate and ultimate analyses, calorific value measurement and thermogravimetric analysis. Ash characterization includes oxide composition analysis and phase analysis by X-Ray diffraction. The selected bamboo species have calorific value comparable with wood with low nitrogen and sulphur contents, indicating that they can be used as renewable energy sources. Bamboo ash contains high silicon so that bamboo ash has potential to be used further as building materials or engineering purposes. Ash composition analysis also indicates high alkali that can cause ash sintering and slag formation in combustion process. This implies that the combustion of bamboo requires the use of additives to reduce the risk of ash sintering and slag formation. Article History: Received May 15, 2016; Received in revised form July 2nd, 2016; Accepted July 14th, 2016; Available online How to Cite This Article: Purbasari, A., Samadhi, T.W. & Bindar, Y. (2016 Thermal and Ash Characterization of Indonesian Bamboo and its Potential for Solid Fuel and Waste Valorization. Int. Journal of Renewable Energy Development, 5(2, 95-100. http://dx.doi.org/10.14710/ijred.5.2.96-100 

  16. Obtaining zeolites from slags and ashes from a waste combustion plant in an autoclave process

    Directory of Open Access Journals (Sweden)

    Grela Agnieszka

    2017-01-01

    Full Text Available Waste combustion is associated with the generation of post-processing solid products – waste such as slag and ash. One of the promising technologies in waste management and processing is the synthesis of zeolites and other materials exhibiting sorption properties. The aim of this study was to characterise and assess the physicochemical properties of the waste and the products synthesised from it. This paper presents the possibility of synthesis zeolites from the slag and ash from two waste combustion plants. The investigated waste is classified as hazardous waste and denoted by the EWC code 190111*. The paper presents the results of physicochemical studies of these materials. As a result of synthesis in an autoclave at 140°C with the use of 2 M NaOH, and other compounds, such zeolite forms as chabazite and sodalite were obtained. Textural studies and ion-exchange capacity investigations carried out allowed characterisation of the sorption properties of the materials. It was found that the materials obtained are characterised by the BET specific surface areas of 25.45 m2/g and 16.79 m2/g.

  17. 78 FR 28051 - Federal Plan Requirements for Hospital/Medical/Infectious Waste Incinerators Constructed On or...

    Science.gov (United States)

    2013-05-13

    ... emissions limits? C. What are the final amendments to the waste management plan requirements? D. What are... biphenyls (PCBs). The 2009 final rule's revised waste management plan provisions encourage segregation of types of waste that lead to reductions in emissions, such as chlorinated plastics and PCB- containing...

  18. MECHANISMS GOVERNING TRANSIENTS FROM THE BATCH INCINERATION OF LIQUID WASTES IN ROTARY KILNS

    Science.gov (United States)

    When "containerized" liquid wastes, bound on sorbents. are introduced into a rotary kiln in a batch mode, transient phenomena in-volving heat transfer into, and waste mass transfer out of, the sorbent can oromote the raoid release of waste vaoor into the kiln environment. This ra...

  19. Development of fission micro-chambers for nuclear waste incineration studies

    CERN Document Server

    Fadil, M; Christophe, S; Deruelle, O; Fioni, G; Marie, F; Mounier, C; Ridikas, D; Trapp, J P

    2002-01-01

    The Incineration by Accelerator (INCA) project of the Directorate for Science of Matter of the French Atomic Energy Authority (CEA/DSM) aims to outline the ideal physical conditions to transmute minor actinides in a high intensity neutron flux obtained either by hybrid systems or innovative critical reactors. To measure on-line the incineration rates of minor actinides, we are developing an innovative Double Deposit Fission Chamber (DDFC) working in current mode. Our method is based on a comparison between the isotope under study and a reference material whose nuclear parameters are well known, as sup 2 sup 3 sup 5 U and sup 2 sup 3 sup 9 Pu. This new fission chamber will be used in the High Flux Reactor in Grenoble/France in a neutron flux of 1.2x10 sup 1 sup 5 n cm sup - sup 2 s sup - sup 1 for 50 days, the operating cycle of the reactor. These specific experimental conditions require substantial modifications of the existing chambers. The first experiment will be carried out in fall 2000.

  20. Using cement, lignite fly ash and baghouse filter waste for solidification of chromium electroplating treatment sludge

    Directory of Open Access Journals (Sweden)

    Wantawin, C.

    2004-02-01

    Full Text Available The objective of the study is to use baghouse filter waste as a binder mixed with cement and lignite fly ash to solidify sludge from chromium electroplating wastewater treatment. To save cost of solidification, reducing cement in binder and increasing sludge in the cube were focused on. Minimum percent cement in binder of 20 for solidification of chromium sludge was found when controlling lignite fly ash to baghouse filter waste at the ratio of 30:70, sludge to binder ratio of 0.5, water to mixer ratio of 0.3 and curing time of 7 days. Increase of sludge to binder ratio from 0.5 to 0.75 and 1 resulted in increase in the minimum percent cement in binder up to 30 percent in both ratios. With the minimum percent cement in binder, the calculated cement to sludge ratios for samples with sludge to binder ratios of 0.5, 0.75 and 1 were 0.4, 0.4 and 0.3 respectively. Leaching chromium and compressive strength of the samples with these ratios could achieve the solidified waste standard by the Ministry of Industry. For solidification of chromium sludge at sludge to binder ratio of 1, the lowest cost binder ratio of cement to lignite fly ash and baghouse filter waste in this study was 30:21:49. The cost of binder in this ratio was 718 baht per ton dry sludge.

  1. Leaching and toxicity behavior of coal-biomass waste cocombustion ashes

    Energy Technology Data Exchange (ETDEWEB)

    Skodras, G.; Prokopidou, M.; Sakellaropoulos, G.P. [Aristotle University in Thessaloniki, Thessaloniki (Greece). Dept. for Chemical Engineering

    2006-08-15

    Land disposal of ash residues, obtained from the cocombustion of Greek lignite with biomass wastes, is known to create problems due to the harmful constituents present. In this regard, the leachability of trace elements from lignite, biomass, and blends cocombustion ashes was investigated by using the Toxicity Characteristic Leaching Procedure (TCLP) of the US Environmental Protection Agency (US EPA). In this work, the toxicity of the aqueous leachates and the concentrations of the metals obtained from the leaching procedure were measured using the Microtox test (Vibrio fischen) and inductive coupled plasma-atomic emission spectrometer (