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Sample records for waste hlw prior

  1. Development Of Glass Matrices For HLW Radioactive Wastes

    International Nuclear Information System (INIS)

    Jantzen, C.

    2010-01-01

    Vitrification is currently the most widely used technology for the treatment of high level radioactive wastes (HLW) throughout the world. Most of the nations that have generated HLW are immobilizing in either borosilicate glass or phosphate glass. One of the primary reasons that glass has become the most widely used immobilization media is the relative simplicity of the vitrification process, e.g. melt waste plus glass forming frit additives and cast. A second reason that glass has become widely used for HLW is that the short range order (SRO) and medium range order (MRO) found in glass atomistically bonds the radionuclides and governs the melt properties such as viscosity, resistivity, sulphate solubility. The molecular structure of glass controls contaminant/radionuclide release by establishing the distribution of ion exchange sites, hydrolysis sites, and the access of water to those sites. The molecular structure is flexible and hence accounts for the flexibility of glass formulations to waste variability. Nuclear waste glasses melt between 1050-1150 C which minimizes the volatility of radioactive components such as Tc 99 , Cs 137 , and I 129 . Nuclear waste glasses have good long term stability including irradiation resistance. Process control models based on the molecular structure of glass have been mechanistically derived and have been demonstrated to be accurate enough to control the world's largest HLW Joule heated ceramic melter in the US since 1996 at 95% confidence.

  2. DEVELOPMENT OF GLASS MATRICES FOR HLW RADIOACTIVE WASTES

    Energy Technology Data Exchange (ETDEWEB)

    Jantzen, C.

    2010-03-18

    Vitrification is currently the most widely used technology for the treatment of high level radioactive wastes (HLW) throughout the world. Most of the nations that have generated HLW are immobilizing in either borosilicate glass or phosphate glass. One of the primary reasons that glass has become the most widely used immobilization media is the relative simplicity of the vitrification process, e.g. melt waste plus glass forming frit additives and cast. A second reason that glass has become widely used for HLW is that the short range order (SRO) and medium range order (MRO) found in glass atomistically bonds the radionuclides and governs the melt properties such as viscosity, resistivity, sulphate solubility. The molecular structure of glass controls contaminant/radionuclide release by establishing the distribution of ion exchange sites, hydrolysis sites, and the access of water to those sites. The molecular structure is flexible and hence accounts for the flexibility of glass formulations to waste variability. Nuclear waste glasses melt between 1050-1150 C which minimizes the volatility of radioactive components such as Tc{sup 99}, Cs{sup 137}, and I{sup 129}. Nuclear waste glasses have good long term stability including irradiation resistance. Process control models based on the molecular structure of glass have been mechanistically derived and have been demonstrated to be accurate enough to control the world's largest HLW Joule heated ceramic melter in the US since 1996 at 95% confidence.

  3. Waste Isolation Pilot Plant in situ experimental program for HLW

    International Nuclear Information System (INIS)

    Molecke, M.A.

    1977-01-01

    The Waste Isolation Pilot Plant (WIPP) will be a facility to demonstrate the environmental and operational safety of storing radioactive wastes in a deep geologic bedded salt facility. The WIPP will be located in southeastern New Mexico, approximately 30 miles east of the city of Carlsbad. The major focus of the pilot plant operation involves ERDA defense related low and intermediate-level transuranic wastes. The scope of the project also specifically includes experimentation utilizing commercially generated high-level wastes, or alternatively, spent unreprocessed fuel elements. WIPP HLW experiments are being conducted in an inter-related laboratory, bench-scale, and in situ mode. This presentation focuses on the planned in situ experiments which, depending on the availability of commercially reprocessed waste plus delays in the construction schedule of the WIPP, will begin in approximately 1985. Such experiments are necessary to validate preceding laboratory results and to provide actual, total conditions of geologic storage which cannot be adequately simulated. One set of planned experiments involves emplacing bare HLW fragments into direct contact with the bedded salt environment. A second set utilizes full-size canisters of waste emplaced in the salt in the same manner as planned for a future HLW repository. The bare waste experiments will study in an accelerated manner waste-salt bed-brine interactions including matrix integrity/degradation, brine leaching, system chemistry, and potential radionuclide migration through the salt bed. Utilization of full-size canisters of HLW in situ permits us to demonstrate operational effectiveness and safety. Experiments will evaluate corrosion and compatibility interactions between the waste matrix, canister and overpack materials, getter materials, stored energy, waste buoyancy, etc. Using full size canisters also allows us to demonstrate engineered retrievability of wastes, if necessary, at the end of experimentation

  4. Conclusions on the two technical panels on HLW-disposal and waste treatment processes respectively

    International Nuclear Information System (INIS)

    Dinkespiller, J.A.; Dejonghe, P.; Feates, F.

    1986-01-01

    The paper reports the concluding panel session at the European Community Conference on radioactive waste management and disposal, Luxembourg 1985. The panel considered the conclusions of two preceeding technical panels on high level waste (HLW) disposal and waste treatment processes. Geological disposal of HLW, waste management, safety assessment of waste disposal, public opinion, public acceptance of the manageability of radioactive wastes, international cooperation, and waste management in the United States, are all discussed. (U.K.)

  5. NOx AND HETEROGENEITY EFFECTS IN HIGH LEVEL WASTE (HLW)

    International Nuclear Information System (INIS)

    Meisel, Dan; Camaioni, Donald M.; Orlando, Thom

    2000-01-01

    We summarize contributions from our EMSP supported research to several field operations of the Office of Environmental Management (EM). In particular we emphasize its impact on safety programs at the Hanford and other EM sites where storage, maintenance and handling of HLW is a major mission. In recent years we were engaged in coordinated efforts to understand the chemistry initiated by radiation in HLW. Three projects of the EMSP (''The NOx System in Nuclear Waste,'' ''Mechanisms and Kinetics of Organic Aging in High Level Nuclear Wastes, D. Camaioni--PI'' and ''Interfacial Radiolysis Effects in Tanks Waste, T. Orlando--PI'') were involved in that effort, which included a team at Argonne, later moved to the University of Notre Dame, and two teams at the Pacific Northwest National Laboratory. Much effort was invested in integrating the results of the scientific studies into the engineering operations via coordination meetings and participation in various stages of the resolution of some of the outstanding safety issues at the sites. However, in this Abstract we summarize the effort at Notre Dame

  6. Technical and economic optimization study for HLW waste management

    International Nuclear Information System (INIS)

    Deffes, A.

    1989-01-01

    This study was conducted to assess the technical and economic aspects of high level waste (HLW) management with the objective of optimizing the interim storage duration and the dimensions of the underground repository site. The procedure consisted in optimizing the economic criterion under specified constraints. The results are intended to identify trends and guide the choice from among available options; simple and highly flexible models were therefore used in this study, and only nearfield thermal constraints were taken into consideration. Because of the present uncertainty on the physicochemical properties of the repository environment and on the unit cost figures, this study focused on developing a suitable method rather than on obtaining definitive results. With the physical and economic data bases used for the two media investigated (granite and salt) the optimum values found show that it is advisable to minimize the interim storage time, and that the geological repository should feature a high degree of spatial dilution. These results depend to a considerable extent on the assumption of high interim storage costs

  7. High Level Waste (HLW) Processing Experience with Increased Waste Loading

    International Nuclear Information System (INIS)

    JANTZEN, CAROL

    2004-01-01

    The Defense Waste Processing Facility (DWPF) Engineering requested characterization of glass samples that were taken after the second melter had been operational for about 5 months. After the new melter had been installed, the waste loading had been increased to about 38 weight percentage after a new quasicrystalline liquidus model had been implemented. The DWPF had also switched from processing with refractory Frit 200 to a more fluid Frit 320. The samples were taken after DWPF observed very rapid buildup of deposits in the upper pour spout bore and on the pour spout insert while processing the high waste loading feedstock. These samples were evaluated using various analytical techniques to determine the cause of the crystallization. The pour stream sample was homogeneous, amorphous, and representative of the feed batch from which it was derived. Chemical analysis of the pour stream sample indicated that a waste loading of 38.5 weight per cent had been achieved. The data analysis indicated that surface crystallization, induced by temperature and oxygen fugacity gradients in the pour spout, caused surface crystallization to occur in the spout and on the insert at the higher waste loadings even though there was no crystallization in the pour stream

  8. HIGH ALUMINUM HLW (HIGH LEVEL WASTE) GLASSES FOR HANFORD'S WTP (WASTE TREATMENT PROJECT)

    International Nuclear Information System (INIS)

    Kruger, A.A.; Bowan, B.W.; Joseph, I.; Gan, H.; Kot, W.K.; Matlack, K.S.; Pegg, I.L.

    2010-01-01

    This paper presents the results of glass formulation development and melter testing to identify high waste loading glasses to treat high-Al high level waste (HLW) at Hanford. Previous glass formulations developed for this HLW had high waste loadings but their processing rates were lower that desired. The present work was aimed at improving the glass processing rate while maintaining high waste loadings. Glass formulations were designed, prepared at crucible-scale and characterized to determine their properties relevant to processing and product quality. Glass formulations that met these requirements were screened for melt rates using small-scale tests. The small-scale melt rate screening included vertical gradient furnace (VGF) and direct feed consumption (DFC) melter tests. Based on the results of these tests, modified glass formulations were developed and selected for larger scale melter tests to determine their processing rate. Melter tests were conducted on the DuraMelter 100 (DMIOO) with a melt surface area of 0.11 m 2 and the DuraMelter 1200 (DMI200) HLW Pilot Melter with a melt surface area of 1.2 m 2 . The newly developed glass formulations had waste loadings as high as 50 wt%, with corresponding Al 2 O 3 concentration in the glass of 26.63 wt%. The new glass formulations showed glass production rates as high as 1900 kg/(m 2 .day) under nominal melter operating conditions. The demonstrated glass production rates are much higher than the current requirement of 800 kg/(m 2 .day) and anticipated future enhanced Hanford Tank Waste Treatment and Immobilization Plant (WTP) requirement of 1000 kg/(m 2 .day).

  9. 12 Flasktransport of vitrified High Level Waste (HLW)

    Energy Technology Data Exchange (ETDEWEB)

    Verdier, A.; Lancelot, J. [COGEMA Logistics (AREVA Group) (France); Gisbertz, A.; Graf, W. [GNS (Germany); Bartagnon, O. [COGEMA (AREVA Group) (France)

    2004-07-01

    The return of HLW to Germany has started in 1996 with the first attribution of 28 glass canisters to German utilities by COGEMA. After several transports comprising 1, 2 and 6 flasks per shipment German and French Authorities requested to transport 12 flasks in a single shipment. The first of these 12-flask-transports was performed with the type CASTOR {sup registered} HAW 20/28 CG flask in 2002 and the second followed in 2003. COGEMA LOGISTICS is responsible for the overall transport assigned by GNS (Gesellschaft fuer Nuklear-Service mbH) being itself entrusted by the German utilities with the return of reprocessing residues.

  10. 12 Flasktransport of vitrified High Level Waste (HLW)

    International Nuclear Information System (INIS)

    Verdier, A.; Lancelot, J.; Gisbertz, A.; Graf, W.; Bartagnon, O.

    2004-01-01

    The return of HLW to Germany has started in 1996 with the first attribution of 28 glass canisters to German utilities by COGEMA. After several transports comprising 1, 2 and 6 flasks per shipment German and French Authorities requested to transport 12 flasks in a single shipment. The first of these 12-flask-transports was performed with the type CASTOR registered HAW 20/28 CG flask in 2002 and the second followed in 2003. COGEMA LOGISTICS is responsible for the overall transport assigned by GNS (Gesellschaft fuer Nuklear-Service mbH) being itself entrusted by the German utilities with the return of reprocessing residues

  11. Technetium Chemistry in HLW

    International Nuclear Information System (INIS)

    Hess, Nancy J.; Felmy, Andrew R.; Rosso, Kevin M.; Xia Yuanxian

    2005-01-01

    Tc contamination is found within the DOE complex at those sites whose mission involved extraction of plutonium from irradiated uranium fuel or isotopic enrichment of uranium. At the Hanford Site, chemical separations and extraction processes generated large amounts of high level and transuranic wastes that are currently stored in underground tanks. The waste from these extraction processes is currently stored in underground High Level Waste (HLW) tanks. However, the chemistry of the HLW in any given tank is greatly complicated by repeated efforts to reduce volume and recover isotopes. These processes ultimately resulted in mixing of waste streams from different processes. As a result, the chemistry and the fate of Tc in HLW tanks are not well understood. This lack of understanding has been made evident in the failed efforts to leach Tc from sludge and to remove Tc from supernatants prior to immobilization. Although recent interest in Tc chemistry has shifted from pretreatment chemistry to waste residuals, both needs are served by a fundamental understanding of Tc chemistry

  12. Enhanced HLW glass formulations for the waste treatment and immobilization plant

    Energy Technology Data Exchange (ETDEWEB)

    Kruger, Albert A. [DOE-WTP Project Office, US Department of Energy, Richland, Washington (United States)

    2013-07-01

    Current estimates and glass formulation efforts are conservative vis-a-vis achievable waste loadings. These formulations have been specified to ensure that glasses are homogenous, contain essentially no crystalline phases, are processable in joule-heated, ceramic-lined melters and meet WTP Contract terms. The WTP's overall mission will require the immobilization of tank waste compositions that are dominated by mixtures of aluminum, chromium, bismuth, iron, phosphorous, zirconium, and sulfur compounds as waste-limiting components. Glass compositions for these waste mixtures have been developed based upon previous experience and current glass property models. DOE has a testing program to develop and characterize HLW glasses with higher waste loadings. This work has demonstrated the feasibility of increases in waste loading from 25 wt% to 33-50 wt% (based on oxide loading) in the glass depending on the waste stream. It is expected these higher waste loading glasses will reduce the HLW canister production requirement by 25% or more. (authors)

  13. High-Level Waste (HLW) Feed Process Control Strategy

    International Nuclear Information System (INIS)

    STAEHR, T.W.

    2000-01-01

    The primary purpose of this document is to describe the overall process control strategy for monitoring and controlling the functions associated with the Phase 1B high-level waste feed delivery. This document provides the basis for process monitoring and control functions and requirements needed throughput the double-shell tank system during Phase 1 high-level waste feed delivery. This document is intended to be used by (1) the developers of the future Process Control Plan and (2) the developers of the monitoring and control system

  14. Novel waste forms for HLW and ILW immobilisation

    International Nuclear Information System (INIS)

    Lee, William E.; Milestone, Neil B.; Ojovan, Michael I.; Hyatt, Neil C.; Stennett, Martin C.; Setiadi, Anthony; Zhou, Qizhi

    2006-01-01

    The complex nature and heterogeneity of legacy wastes means that a toolbox of different host systems must be developed in which to immobilize them. New zirconolite ceramic, glass composite materials and novel cement systems including calcium sulpho aluminate cements and alkali activated slags being examined in the Immobilisation Science Laboratory at the University of Sheffield are described. (authors)

  15. MELT RATE ENHANCEMENT FOR HIGH ALUMINUM HLW (HIGH LEVEL WASTE) GLASS FORMULATION FINAL REPORT 08R1360-1

    Energy Technology Data Exchange (ETDEWEB)

    KRUGER AA; MATLACK KS; KOT W; PEGG IL; JOSEPH I; BARDAKCI T; GAN H; GONG W; CHAUDHURI M

    2010-01-04

    This report describes the development and testing of new glass formulations for high aluminum waste streams that achieve high waste loadings while maintaining high processing rates. The testing was based on the compositions of Hanford High Level Waste (HLW) with limiting concentrations of aluminum specified by the Office of River Protection (ORP). The testing identified glass formulations that optimize waste loading and waste processing rate while meeting all processing and product quality requirements. The work included preparation and characterization of crucible melts and small scale melt rate screening tests. The results were used to select compositions for subsequent testing in a DuraMelter 100 (DM100) system. These tests were used to determine processing rates for the selected formulations as well as to examine the effects of increased glass processing temperature, and the form of aluminum in the waste simulant. Finally, one of the formulations was selected for large-scale confirmatory testing on the HLW Pilot Melter (DM1200), which is a one third scale prototype of the Hanford Tank Waste Treatment and Immobilization Plant (WTP) HLW melter and off-gas treatment system. This work builds on previous work performed at the Vitreous State Laboratory (VSL) for Department of Energy (DOE) to increase waste loading and processing rates for high-iron HLW waste streams as well as previous tests conducted for ORP on the same high-aluminum waste composition used in the present work and other Hanford HLW compositions. The scope of this study was outlined in a Test Plan that was prepared in response to an ORP-supplied statement of work. It is currently estimated that the number of HLW canisters to be produced in the WTP is about 13,500 (equivalent to 40,500 MT glass). This estimate is based upon the inventory of the tank wastes, the anticipated performance of the sludge treatment processes, and current understanding of the capability of the borosilicate glass waste form

  16. MELT RATE ENHANCEMENT FOR HIGH ALUMINUM HLW (HIGH LEVEL WASTE) GLASS FORMULATION. FINAL REPORT 08R1360-1

    International Nuclear Information System (INIS)

    Kruger, A.A.; Matlack, K.S.; Kot, W.; Pegg, I.L.; Joseph, I.; Bardakci, T.; Gan, H.; Gong, W.; Chaudhuri, M.

    2010-01-01

    This report describes the development and testing of new glass formulations for high aluminum waste streams that achieve high waste loadings while maintaining high processing rates. The testing was based on the compositions of Hanford High Level Waste (HLW) with limiting concentrations of aluminum specified by the Office of River Protection (ORP). The testing identified glass formulations that optimize waste loading and waste processing rate while meeting all processing and product quality requirements. The work included preparation and characterization of crucible melts and small scale melt rate screening tests. The results were used to select compositions for subsequent testing in a DuraMelter 100 (DM100) system. These tests were used to determine processing rates for the selected formulations as well as to examine the effects of increased glass processing temperature, and the form of aluminum in the waste simulant. Finally, one of the formulations was selected for large-scale confirmatory testing on the HLW Pilot Melter (DM1200), which is a one third scale prototype of the Hanford Tank Waste Treatment and Immobilization Plant (WTP) HLW melter and off-gas treatment system. This work builds on previous work performed at the Vitreous State Laboratory (VSL) for Department of Energy (DOE) to increase waste loading and processing rates for high-iron HLW waste streams as well as previous tests conducted for ORP on the same high-aluminum waste composition used in the present work and other Hanford HLW compositions. The scope of this study was outlined in a Test Plan that was prepared in response to an ORP-supplied statement of work. It is currently estimated that the number of HLW canisters to be produced in the WTP is about 13,500 (equivalent to 40,500 MT glass). This estimate is based upon the inventory of the tank wastes, the anticipated performance of the sludge treatment processes, and current understanding of the capability of the borosilicate glass waste form

  17. High level waste (HLW) steam reducing station evaluation

    International Nuclear Information System (INIS)

    Gannon, R.E.

    1993-01-01

    Existing pressure equipment in High Level Waste does not have a documented technical baseline. Based on preliminary reviews, the existing equipment seems to be based on system required capacity instead of system capability. A planned approach to establish a technical baseline began September 1992 and used the Works Management System preventive maintenance schedule. Several issues with relief valves being undersized on steam reducing stations created a need to determine the risk of maintaining the steam in service. An Action Plan was developed to evaluate relief valves that did not have technical baselines and provided a path forward for continued operation. Based on Action Plan WER-HLE-931042, the steam systems will remain in service while the designs are being developed and implemented

  18. Comparison of the corrosion behaviors of the glass-bonded sodalite ceramic waste form and reference HLW glasses

    International Nuclear Information System (INIS)

    Ebert, W. L.; Lewis, M. A.

    1999-01-01

    A glass-bonded sodalite ceramic waste form is being developed for the long-term immobilization of salt wastes that are generated during spent nuclear fuel conditioning activities. A durable waste form is prepared by hot isostatic pressing (HIP) a mixture of salt-loaded zeolite powders and glass frit. A mechanistic description of the corrosion processes is being developed to support qualification of the CWF for disposal. The initial set of characterization tests included two standard tests that have been used extensively to study the corrosion behavior of high level waste (HLW) glasses: the Material Characterization Center-1 (MCC-1) Test and the Product Consistency Test (PCT). Direct comparison of the results of tests with the reference CWF and HLW glasses indicate that the corrosion behaviors of the CWF and HLW glasses are very similar

  19. Optimization method for dimensioning a geological HLW waste repository

    International Nuclear Information System (INIS)

    Ouvrier, N.; Chaudon, L.; Malherbe, L.

    1990-01-01

    This method was developed by the CEA to optimize the dimensions of a geological repository by taking account of technical and economic parameters. It involves optimizing radioactive waste storage conditions on the basis of economic criteria with allowance for specified thermal constraints. The results are intended to identify trends and guide the choice from among available options: simple and highly flexible models were therefore used in this study, and only nearfield thermal constraints were taken into consideration. Because of the present uncertainty on the physicochemical properties of the repository environment and on the unit cost figures, this study focused on developing a suitable method rather than on obtaining definitive results. The optimum values found for the two media investigated (granite and salt) show that it is advisable to minimize the interim storage time, implying the containers must be separated by buffer material, whereas vertical spacing may not be required after a 30-year interim storage period. Moreover, the boreholes should be as deep as possible, on a close pitch in widely spaced handling drifts. These results depend to a considerable extent on the assumption of high interim storage costs

  20. DM100 AND DM1200 MELTER TESTING WITH HIGH WASTE LOADING GLASS FORMULATIONS FOR HANFORD HIGH-ALUMINUM HLW STREAMS

    Energy Technology Data Exchange (ETDEWEB)

    KRUGER AA; MATLACK KS; KOT WK; PEGG IL; JOSEPH I

    2009-12-30

    This Test Plan describes work to support the development and testing of high waste loading glass formulations that achieve high glass melting rates for Hanford high aluminum high level waste (HLW). In particular, the present testing is designed to evaluate the effect of using low activity waste (LAW) waste streams as a source of sodium in place ofchemical additives, sugar or cellulose as a reductant, boehmite as an aluminum source, and further enhancements to waste processing rate while meeting all processing and product quality requirements. The work will include preparation and characterization of crucible melts in support of subsequent DuraMelter 100 (DM 100) tests designed to examine the effects of enhanced glass formulations, glass processing temperature, incorporation of the LAW waste stream as a sodium source, type of organic reductant, and feed solids content on waste processing rate and product quality. Also included is a confirmatory test on the HLW Pilot Melter (DM1200) with a composition selected from those tested on the DM100. This work builds on previous work performed at the Vitreous State Laboratory (VSL) for Department of Energy's (DOE's) Office of River Protection (ORP) to increase waste loading and processing rates for high-iron HLW waste streams as well as previous tests conducted for ORP on the same waste composition. This Test Plan is prepared in response to an ORP-supplied statement of work. It is currently estimated that the number of HLW canisters to be produced in the Hanford Tank Waste Treatment and Immobilization Plant (WTP) is about 12,500. This estimate is based upon the inventory ofthe tank wastes, the anticipated performance of the sludge treatment processes, and current understanding of the capability of the borosilicate glass waste form. The WTP HLW melter design, unlike earlier DOE melter designs, incorporates an active glass bubbler system. The bubblers create active glass pool convection and thereby improve heat

  1. Collaboration, Automation, and Information Management at Hanford High Level Radioactive Waste (HLW) Tank Farms

    International Nuclear Information System (INIS)

    Aurah, Mirwaise Y.; Roberts, Mark A.

    2013-01-01

    Washington River Protection Solutions (WRPS), operator of High Level Radioactive Waste (HLW) Tank Farms at the Hanford Site, is taking an over 20-year leap in technology, replacing systems that were monitored with clipboards and obsolete computer systems, as well as solving major operations and maintenance hurdles in the area of process automation and information management. While WRPS is fully compliant with procedures and regulations, the current systems are not integrated and do not share data efficiently, hampering how information is obtained and managed

  2. Crystallization in high level waste (HLW) glass melters: Savannah River Site operational experience

    Energy Technology Data Exchange (ETDEWEB)

    Fox, Kevin M. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Peeler, David K. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Kruger, Albert A. [USDOE Office of River Protection, Richland, WA (United States)

    2015-06-12

    This paper provides a review of the scaled melter testing that was completed for design input to the Defense Waste Processing Facility (DWPF) melter. Testing with prototype melters provided the data to define the DWPF operating limits to avoid bulk (volume) crystallization in the un-agitated DWPF melter and provided the data to distinguish between spinels generated by refractory corrosion versus spinels that precipitated from the HLW glass melt pool. A review of the crystallization observed with the prototype melters and the full-scale DWPF melters (DWPF Melter 1 and DWPF Melter 2) is included. Examples of actual DWPF melter attainment with Melter 2 are given. The intent is to provide an overview of lessons learned, including some example data, that can be used to advance the development and implementation of an empirical model and operating limit for crystal accumulation for a waste treatment and immobilization plant.

  3. Development Of High Waste-Loading HLW Glasses For High Bismuth Phosphate Wastes, VSL-12R2550-1, Rev 0

    International Nuclear Information System (INIS)

    Kruger, A. A.; Pegg, Ian L.; Gan, Hao; Kot, Wing K.

    2012-01-01

    This report presents results from tests with new glass formulations that have been developed for several high Bi-P HLW compositions that are expected to be processed at the WTP that have not been tested previously. WTP HLW feed compositions were reviewed to select waste batches that are high in Bi-P and that are reasonably distinct from the Bi-limited waste that has been tested previously. Three such high Bi-P HLW compositions were selected for this work. The focus of the present work was to determine whether the same type of issues as seen in previous work with high-Bi HLW will be seen in HLW with different concentrations of Bi, P and Cr and also whether similar glass formulation development approaches would be successful in mitigating these issues. New glass compositions were developed for each of the three representative Bi-P HLW wastes and characterized with respect to key processing and product quality properties and, in particular, those relating to crystallization and foaming tendency

  4. Development Of High Waste-Loading HLW Glasses For High Bismuth Phosphate Wastes, VSL-12R2550-1, Rev 0

    Energy Technology Data Exchange (ETDEWEB)

    Kruger, A. A. [Department of Energy, Office of River Protection, Richland, Washington (United States); Pegg, Ian L. [The Catholic University of America, Washington, DC (United States); Gan, Hao [The Catholic University of America, Washington, DC (United States); Kot, Wing K. [The Catholic University of America, Washington, DC (United States)

    2012-12-13

    This report presents results from tests with new glass formulations that have been developed for several high Bi-P HLW compositions that are expected to be processed at the WTP that have not been tested previously. WTP HLW feed compositions were reviewed to select waste batches that are high in Bi-P and that are reasonably distinct from the Bi-limited waste that has been tested previously. Three such high Bi-P HLW compositions were selected for this work. The focus of the present work was to determine whether the same type of issues as seen in previous work with high-Bi HLW will be seen in HLW with different concentrations of Bi, P and Cr and also whether similar glass formulation development approaches would be successful in mitigating these issues. New glass compositions were developed for each of the three representative Bi-P HLW wastes and characterized with respect to key processing and product quality properties and, in particular, those relating to crystallization and foaming tendency.

  5. Preliminary formulation studies for a ''hydroceramic'' alternative waste form for INEEL HLW

    International Nuclear Information System (INIS)

    Siemer, D.D.; Gougar, M.L.D.; Grutzeck, M.W.; Scheetz, B.E.

    1999-01-01

    Herein the authors discuss scoping studies performed to develop an efficient way to prepare the Idaho National Engineering and Environmental Laboratory (INEEL) nominally high-level (∼40 W/m 3 ) calcined radioactive waste (HLW) and liquid metal (sodium) reactor coolants for disposal. The investigated approach implements the chemistry of Hanford's cancrinite-making clay reaction process via Oak Ridge National Laboratory's (ORNL's) formed-under-elevated-temperatures-and-pressures concrete monolith-making technology to make hydroceramics (HCs). The HCs differ from conventional Portland cement/blast furnace slag (PC/BFS) grouts in that the binder minerals formed during the curing process are hydrated alkali-aluminosilicates (feldspathoids-sodalites, cancrinites, and zeolites) rather than hydrated calcium silicates (CSH). This is desirable because (a) US defense-type radioactive wastes generally contain much more sodium and aluminum than calcium; (b) sodalites/cancrinites do a much better job of retaining the anionic components of real radioactive waste (e.g., nitrate) than do calcium silicates; (c) natural feldspathoids form from glasses (and therefore are more stable) in that region of the United States where a repository for this sort of waste could be sited; and (d) if eventually deemed necessary, feldspathoid-type concrete wasteforms could be hot-isostatically-pressed into even more durable materials without removing them from their original canisters

  6. Washing of waste prior to landfilling.

    Science.gov (United States)

    Cossu, Raffaello; Lai, Tiziana

    2012-05-01

    The main impact produced by landfills is represented by the release of leachate emissions. Waste washing treatment has been investigated to evaluate its efficiency in reducing the waste leaching fraction prior to landfilling. The results of laboratory-scale washing tests applied to several significant residues from integrated management of solid waste are presented in this study, specifically: non-recyclable plastics from source separation, mechanical-biological treated municipal solid waste and a special waste, automotive shredded residues. Results obtained demonstrate that washing treatment contributes towards combating the environmental impacts of raw wastes. Accordingly, a leachate production model was applied, leading to the consideration that the concentrations of chemical oxygen demand (COD) and total Kjeldahl nitrogen (TKN), parameters of fundamental importance in the characterization of landfill leachate, from a landfill containing washed wastes, are comparable to those that would only be reached between 90 and 220years later in the presence of raw wastes. The findings obtained demonstrated that washing of waste may represent an effective means of reducing the leachable fraction resulting in a consequent decrease in landfill emissions. Further studies on pilot scale are needed to assess the potential for full-scale application of this treatment. Copyright © 2012 Elsevier Ltd. All rights reserved.

  7. Crystallization In High Level Waste (HLW) Glass Melters: Operational Experience From The Savannah River Site

    Energy Technology Data Exchange (ETDEWEB)

    Fox, K. M. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2014-02-27

    processing strategy for the Hanford Tank Waste Treatment and Immobilization Plant (WTP). The basis of this alternative approach is an empirical model predicting the crystal accumulation in the WTP glass discharge riser and melter bottom as a function of glass composition, time, and temperature. When coupled with an associated operating limit (e.g., the maximum tolerable thickness of an accumulated layer of crystals), this model could then be integrated into the process control algorithms to formulate crystal tolerant high level waste (HLW) glasses targeting higher waste loadings while still meeting process related limits and melter lifetime expectancies. This report provides a review of the scaled melter testing that was completed in support of the Defense Waste Processing Facility (DWPF) melter. Testing with scaled melters provided the data to define the DWPF operating limits to avoid bulk (volume) crystallization in the un-agitated DWPF melter and provided the data to distinguish between spinels generated by K-3 refractory corrosion versus spinels that precipitated from the HLW glass melt pool. This report includes a review of the crystallization observed with the scaled melters and the full scale DWPF melters (DWPF Melter 1 and DWPF Melter 2). Examples of actual DWPF melter attainment with Melter 2 are given. The intent is to provide an overview of lessons learned, including some example data, that can be used to advance the development and implementation of an empirical model and operating limit for crystal accumulation for WTP. Operation of the first and second (current) DWPF melters has demonstrated that the strategy of using a liquidus temperature predictive model combined with a 100 °C offset from the normal melter operating temperature of 1150 °C (i.e., the predicted liquidus temperature (TL) of the glass must be 1050 °C or less) has been successful in preventing any detrimental accumulation of spinel in the DWPF melt pool, and spinel has not been

  8. DM100 AND DM1200 MELTER TESTING WITH HIGH WASTE LOADING FORMULATIONS FOR HANFORD HIGH-ALUMINUM HLW STREAMS, TEST PLAN 09T1690-1

    International Nuclear Information System (INIS)

    Kruger, A.A.; Matlack, K.S.; Kot, W.K.; Pegg, I.L.; Joseph, I.

    2009-01-01

    This Test Plan describes work to support the development and testing of high waste loading glass formulations that achieve high glass melting rates for Hanford high aluminum high level waste (HLW). In particular, the present testing is designed to evaluate the effect of using low activity waste (LAW) waste streams as a source of sodium in place ofchemical additives, sugar or cellulose as a reductant, boehmite as an aluminum source, and further enhancements to waste processing rate while meeting all processing and product quality requirements. The work will include preparation and characterization of crucible melts in support of subsequent DuraMelter 100 (DM 100) tests designed to examine the effects of enhanced glass formulations, glass processing temperature, incorporation of the LAW waste stream as a sodium source, type of organic reductant, and feed solids content on waste processing rate and product quality. Also included is a confirmatory test on the HLW Pilot Melter (DM1200) with a composition selected from those tested on the DM100. This work builds on previous work performed at the Vitreous State Laboratory (VSL) for Department of Energy's (DOE's) Office of River Protection (ORP) to increase waste loading and processing rates for high-iron HLW waste streams as well as previous tests conducted for ORP on the same waste composition. This Test Plan is prepared in response to an ORP-supplied statement of work. It is currently estimated that the number of HLW canisters to be produced in the Hanford Tank Waste Treatment and Immobilization Plant (WTP) is about 12,500. This estimate is based upon the inventory ofthe tank wastes, the anticipated performance of the sludge treatment processes, and current understanding of the capability of the borosilicate glass waste form. The WTP HLW melter design, unlike earlier DOE melter designs, incorporates an active glass bubbler system. The bubblers create active glass pool convection and thereby improve heat transfer and

  9. An alternative waste form for the final disposal of high-level radioactive waste (HLW) on the basis of a survey of solidification and final disposal of HLW

    International Nuclear Information System (INIS)

    Bauer, C.

    1982-01-01

    The dissertation comprises two separate parts. The first part presents the basic conditions and concepts of the process leading to the development of a waste form, such as:origin, composition and characteristics of the high-level radioactive waste; evaluation of the methods available for the final disposal of radioactive waste, especially the disposal in a geological formation, including the resulting consequences for the conditions of state in the surroundings of the waste package; essential option for the conception of a waste form and presentation of the waste forms developed and examined on an international level up to now. The second part describes the production of a waste form on TiO 2 basis, in which calcined radioactive waste particles in the submillimeter range are embedded in a rutile matrix. That waste form is produced by uniaxial pressure sintering in the temperature range of 1223 K to 1423 K and pressures between 5 MPa and 20 MPa. Microstructure, mechanical properties and leaching rates of the waste form are presented. Moreover, a method is explained allowing compacting of the rutile matrix and also integration of a wasteless overpack of titanium or TiO 2 into the waste form. (orig.) [de

  10. Modelling of radionuclide migration and heat transport from an High-Level-Radioactive-Waste-repository (HLW) in Boom clay

    International Nuclear Information System (INIS)

    Put, M.; Henrion, P.

    1992-01-01

    For the modelling of the migration of radionuclides in the Boom clay formation, the analytical code MICOF has been updated with a 3-dimensional analytical solution for discrete sources. the MICOF program is used for the calculation of the release of α and β emitters from the HIGH LEVEL RADIOACTIVE WASTES (HLW). A coherent conceptual model is developed which describes all the major physico-chemical phenomena influencing the migration of radionuclides in the Boom clay. The concept of the diffusion accessible porosity is introduced and included in the MICOF code. Different types of migration experiments are described with their advantages and disadvantages. The thermal impact of the HLW disposal in the stratified Boom clay formation has been evaluated by a finite element simulation of the coupled heat and mass transport equation. The results of the simulations show that under certain conditions thermal convection cells may form, but the convective heat transfer in the clay formation is negligible. 6 refs., 19 figs., 2 tabs., 5 appendices

  11. Execution techniques and approach for high level radioactive waste disposal in Japan: Demonstration of geological disposal techniques and implementation approach of HLW project

    International Nuclear Information System (INIS)

    Kawanishi, M.; Komada, H.; Kitayama, K.; Akasaka, H.; Tsuchi, H.

    2001-01-01

    In Japan, the high-level radioactive waste (HLW) disposal project is expected to start fully after establishment of the implementing organization, which is planned around the year 2000 and to dispose the wastes in the 2030s to at latest in the middle of 2040s. Considering each step in the implementation of the HLW disposal project in Japan, this paper discusses the execution procedure for HLW disposal project, such as the selection of candidate/planned disposal sites, the construction and operation of the disposal facility, the closure and decommissioning of facilities, and the institutional control and monitoring after the closure of disposal facility, from a technical viewpoint for the rational execution of the project. Furthermore, we investigate and propose some ideas for the concept of the design of geological disposal facility, the validation and demonstration of the reliability on the disposal techniques and performance assessment methods at a candidate/planned site. Based on these investigation results, we made clear a milestone for the execution of the HLW disposal project in Japan. (author)

  12. Economic comparison of crystalline ceramic and glass waste forms for HLW disposal

    International Nuclear Information System (INIS)

    McKee, R.W.; Daling, P.M.; Wiles, L.E.

    1983-05-01

    A titanate-based, crystalline ceramic produced by hot isostatic pressing has been proposed as a potentially more stable and improved waste form for high-level nuclear waste disposal compared to the currently favored borosilicate glass waste form. This paper describes the results of a study to evaluate the relative costs for disposal of high-level waste from a 70,000 metric ton equivalent (MTE) system. The entire waste management system, including waste processing and encapsulation, transportation, and final repository disposal, was included in this analysis. The repository concept is based on the current basalt waste isolation project (BWIP) reference design. A range of design basis alternatives is considered to determine if this would influence the relative economics of the two waste forms. A thermal analysis procedure was utilized to define optimum canister sizes to assure that each waste form was compared under favorable conditions. Repository costs are found to favor the borosilicate glass waste form while transportation costs greatly favor the crystalline ceramic waste form. The determining component in the cost comparison is the waste processing cost, which strongly favors the borosilicate glass process because of its relative simplicity. A net cost advantage on the order of 12% to 15% on a waste management system basis is indicated for the glass waste form

  13. Results of Sludge Mobilization Testing at Hanford High Level Waste (HLW) Tank

    International Nuclear Information System (INIS)

    STAEHR, T.W.

    2001-01-01

    Waste stored in the Tank 241-AZ-101 at the US DOE Hanford is scheduled as the initial feed for high-level waste vitrification. Tank 241-AZ-101 currently holds over 3,000,000 liters of waste made up of a settled sludge layer covered by a layer of liquid supernant. To retrieve the waste from the tank, it is necessary to mobilize and suspend the settled sludge so that the resulting slurry can be pumped from the tank for treatment and vitrification. Two 223.8-kilowatt mixer pumps have been installed in Tank 241-AZ-101 to mobilize the settled sludge layer of waste for retrieval. In May of 2000, the mixer pumps were subjected to a series of tests to determine (1) the extent to which the mixer pumps could mobilize the settle sludge layer of waste, (2) if the mixer pumps could function within operating parameters, and (3) if state-of-the-art monitoring equipment could effectively monitor and quantify the degree of sludge mobilization and suspension. This paper presents the major findings and results of the Tank 241-AZ-101 mixer pump tests, based on analysis of data and waste samples that were collected during the testing. Discussion of the results focuses on the effective cleaning radius achieved and the volume and concentration of sludge mobilized, with both one and two pumps operating in various configurations and speeds. The Tank 241-AZ-101 mixer pump tests were unique in that sludge mobilization parameters were measured using actual waste in an underground storage tank at the hanford Site. The methods and instruments that were used to measure waste mobilization parameters in Tank 241-AZ-101 can be used in other tanks. It can be concluded from the testing that the use of mixer pumps is an effective retrieval method for the mobilization of settled solids in Tank 241-AZ-101

  14. Derived Requirements for Double Shell Tank (DST) High Level Waste (HLW) Auxiliary Solids Mobilization

    Energy Technology Data Exchange (ETDEWEB)

    TEDESCHI, A.R.

    2000-02-28

    The potential need for auxiliary double-shell tank waste mixing and solids mobilization requires an evaluation of optional technologies. This document formalizes those operating and design requirements needed for further engineering evaluations.

  15. Derived Requirements for Double-Shell Tank (DST) High Level Waste (HLW) Auxiliary Solids Mobilization

    International Nuclear Information System (INIS)

    TEDESCHI, A.R.

    2000-01-01

    The potential need for auxiliary double-shell tank waste mixing and solids mobilization requires an evaluation of optional technologies. This document formalizes those operating and design requirements needed for further engineering evaluations

  16. High level waste containing granules coated and embedded in metal as an alternative to HLW glasses

    International Nuclear Information System (INIS)

    Neumann, W.

    1980-01-01

    Simulated high level waste containing granules were overcoated with pyrocarbon or nickel respectively. The coatings were performed by the use of chemical vapour deposition in a fluidized bed. The coated granules were embedded in an aluminium-silicon-alloy to improve the dissipation of radiation induced heat. The metal-granules-composites obtained were of improved product stability related to the high level waste containing glasses. (orig.) [de

  17. Hanford high level waste (HLW) tank mixer pump safe operating envelope reliability assessment

    International Nuclear Information System (INIS)

    Fischer, S.R.; Clark, J.

    1993-01-01

    The US Department of Energy and its contractor, Westinghouse Corp., are responsible for the management and safe storage of waste accumulated from processing defense reactor irradiated fuels for plutonium recovery at the Hanford Site. These wastes, which consist of liquids and precipitated solids, are stored in underground storage tanks pending final disposition. Currently, 23 waste tanks have been placed on a safety watch list because of their potential for generating, storing, and periodically releasing various quantities of hydrogen and other gases. Tank 101-SY in the Hanford SY Tank Farm has been found to release hydrogen concentrations greater than the lower flammable limit (LFL) during periodic gas release events. In the unlikely event that an ignition source is present during a hydrogen release, a hydrogen burn could occur with a potential to release nuclear waste materials. To mitigate the periodic gas releases occurring from Tank 101-SY, a large mixer pump currently is being installed in the tank to promote a sustained release of hydrogen gas to the tank dome space. An extensive safety analysis (SA) effort was undertaken and documented to ensure the safe operation of the mixer pump after it is installed in Tank 101-SY.1 The SA identified a need for detailed operating, alarm, and abort limits to ensure that analyzed safety limits were not exceeded during pump operations

  18. Performance of a buried radioactive high level waste (HLW) glass after 24 years

    International Nuclear Information System (INIS)

    Jantzen, Carol M.; Kaplan, Daniel I.; Bibler, Ned E.; Peeler, David K.; John Plodinec, M.

    2008-01-01

    A radioactive high level waste glass was made in 1980 with Savannah River Site (SRS) Tank 15 waste. This glass was buried in a lysimeter in the SRS burial ground for 24 years. Lysimeter leachate data was available for the first 8 years. The glass was exhumed in 2004. The glass was predicted to be very durable and laboratory tests confirmed this. Scanning electron microscopy of the glass burial surface showed no significant glass alteration consistent with results of other laboratory and field tests. Radionuclide profiling for alpha, beta, and 137 Cs indicated that Pu was not enriched in the soil while 137 Cs and 9 deg. C Sr were enriched in the first few centimeters surrounding the glass. Lysimeter leachate data indicated that 9 deg. C Sr and 137 Cs leaching from the glass was diffusion controlled

  19. Physical, Chemical and Structural Evolution of Zeolite - Containing Waste Forms Produced from Metakaolinite and Calcined HLW

    International Nuclear Information System (INIS)

    Grutzeck, Michael

    2005-01-01

    During the seventh year of the current grant (DE-FG02-05ER63966) we completed an exhaustive study of cold calcination and began work on the development of tank fill materials to fill empty tanks and control residuals. Cold calcination of low and high NOx low activity waste (LAW) SRS Tank 44 and Hanford AN-107 simulants, respectively with metallic Al + Si powders was evaluated. It was found that a combination of Al and Si powders could be used as reducing agents to reduce the nitrate and nitrite content of both low and high NOx LAW to low enough levels to allow the LAW to be solidified directly by mixing it with metakaolin and allowing it to cure at 90 C. During room temperature reactions, NOx was reduced and nitrogen was emitted as N2 or NH3. This was an important finding because now one can pretreat LAW at ambient temperatures which provides a low-temperature alternative to thermal calcination. The significant advantage of using Al and Si metals for denitration/denitrition of the LAW is the fact that the supernate could potentially be treated in situ in the waste tanks themselves. Tank fill materials based upon a hydroceramic binder have been formulated from mixtures of metakaolinite, Class F fly ash and Class C flue gas desulphurization (FGD) ash mixed with various concentrations of NaOH solution. These harden over a period of hours or days depending on composition. A systematic study of properties of the tank fill materials (leachability) and ability to adsorb and hold residuals is under way

  20. MIIT: International in-situ testing of simulated HLW forms--preliminary analyses of SRL 165/TDS waste glass and metal systems

    International Nuclear Information System (INIS)

    Wicks, G.G.; Lodding, A.R.; Macedo, P.B.; Molecke, M.A.

    1989-01-01

    The first in-situ tests involving burial of simulated high-level waste (HLW) forms conducted in the United States were started on July 22, 1986. This effort, called the Materials Interface Interactions Tests (MIIT), comprises the largest, most cooperative field testing venture in the international waste management community. Included in the study are over 900 waste form samples comprising 15 different systems supplied by seven countries. Also included are almost 300 potential canister or overpack metal samples of 11 different metals along with more than 500 geologic and backfill specimens. There are a total of 1926 relevant interactions that characterize this effort which is being conducted in the bedded salt site at the Waste Isolation Pilot Plant (WIPP), near Carlsbad, New Mexico

  1. Evaluation of engineering aspects of backfill placement for high level nuclear waste (HLW) deep geologic repositories

    International Nuclear Information System (INIS)

    Roberds, W.; Kleppe, J.; Gonano, L.

    1984-04-01

    This report includes the identification and subjective evaluation of alternative schemes for backfilling around waste packages and within emplacement rooms. The aspects of backfilling specifically considered in this study include construction and testing; costs have not been considered. However, because construction and testing are simply implementation and verification of design, a design basis for backfill is required. A generic basis has been developed for this study by first identifying qualitative performance objectives for backfill and then weighting each with respect to its potential influence on achieving the repository system performance objectives. Alternative backfill materials and additives have been identified and evaluated with respect to the perceived extent to which each combination can be expected to achieve the backfill design basis. Several distinctly different combinations of materials and additives which are perceived to have the highest potential for achieving the backfill design basis have been selected for further study. These combinations include zeolite/clinoptilolite, bentonite, muck, and muck mixed with bentonite. Feasible alternative construction and testing procedures for each selected combination have been discussed. Recommendations have been made regarding appropriate backfill schemes for hard rock (i.e., basalt at Hanford, Washington, tuff at Nevada Test Site, and generic granite) and salt (i.e., domal salt on the Gulf Coast and generic bedded salt). 27 references, 8 figures, 31 tables

  2. HLW immobilization in glass

    International Nuclear Information System (INIS)

    Leroy, P.; Jacquet-Francillon, N.; Runge, S.

    1992-01-01

    The immobilization of High Level Waste in glass in France is a long history which started as early as in the 1950's. More than 30 years of Research and Development have been invested in that field. Two industrial facilities are operating (AVM and R7) and a third one (T7), under cold testing, is planned to start active operation in the mid-92. While vitrification has been demonstrated to be an industrially mastered process, the question of the quality of the final waste product, i.e. the HLW glass, must be addressed. The scope of the present paper is to focus on the latter point from both standpoints of the R and D and of the industrial reality

  3. Post-test evaluations of Waste Isolation Pilot Plant - Savannah River simulated defense HLW canisters and waste form

    International Nuclear Information System (INIS)

    Molecke, M.A.; Sorensen, N.R.; Harbour, J.R.; Ferrara, D.M.

    1993-01-01

    Eighteen nonradioactive defense high-level waste (DHLW) canisters were emplaced in and subjected to accelerated overtest thermal conditions for about three years at the bedded salt Waste Isolation Pilot Plant (WIPP) facility. Post-test laboratory corrosion results of several stainless steel 304L waste canisters, cast steel overpacks, and associated instruments ranged from negligible to moderate. We found appreciable surface corrosion and corrosion products on the cast steel overpacks. Pieces of both 304L and 316 stainless steel test apparatus underwent extensive stress-corrosion cracking failure and nonuniform attack. One of the retrieved test packages contained nonradioactive glass waste form from the Savannah River Site. We conducted post-test analyses of this glass to determine the degree of resultant glass fracturing, and whether any respirable fines were present. Linear glass fracture density ranged from about 1 to 8 fractures intersecting every 5 cm (2 inch) segment along a diameter line of the canister cross-section. Glass fines between 1 and 10 microns in diameter were detected, but were not quantified

  4. Summary of International Waste Management Programs (LLNL Input to SNL L3 MS: System-Wide Integration and Site Selection Concepts for Future Disposition Options for HLW)

    Energy Technology Data Exchange (ETDEWEB)

    Greenberg, Harris R. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Blink, James A. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Halsey, William G. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Sutton, Mark [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

    2011-08-11

    The Used Fuel Disposition Campaign (UFDC) within the Department of Energy’s Office of Nuclear Energy (DOE-NE) Fuel Cycle Technology (FCT) program has been tasked with investigating the disposal of the nation’s spent nuclear fuel (SNF) and high-level nuclear waste (HLW) for a range of potential waste forms and geologic environments. This Lessons Learned task is part of a multi-laboratory effort, with this LLNL report providing input to a Level 3 SNL milestone (System-Wide Integration and Site Selection Concepts for Future Disposition Options for HLW). The work package number is: FTLL11UF0328; the work package title is: Technical Bases / Lessons Learned; the milestone number is: M41UF032802; and the milestone title is: “LLNL Input to SNL L3 MS: System-Wide Integration and Site Selection Concepts for Future Disposition Options for HLW”. The system-wide integration effort will integrate all aspects of waste management and disposal, integrating the waste generators, interim storage, transportation, and ultimate disposal at a repository site. The review of international experience in these areas is required to support future studies that address all of these components in an integrated manner. Note that this report is a snapshot of nuclear power infrastructure and international waste management programs that is current as of August 2011, with one notable exception. No attempt has been made to discuss the currently evolving world-wide response to the tragic consequences of the earthquake and tsunami that devastated Japan on March 11, 2011, leaving more than 15,000 people dead and more than 8,000 people missing, and severely damaging the Fukushima Daiichi nuclear power complex. Continuing efforts in FY 2012 will update the data, and summarize it in an Excel spreadsheet for easy comparison and assist in the knowledge management of the study cases.

  5. Safety of HLW shipments

    International Nuclear Information System (INIS)

    1998-01-01

    The third shipment back to Japan of vitrified high-level radioactive waste (HLW) produced through reprocessing in France is scheduled to take place in early 1998. A consignment last March drew protest from interest groups and countries along the shipping route. Requirements governing the shipment of cargoes of this type and concerns raised by Greenpeace that were assessed by an international expert group, were examined in a previous article. A further report prepared on behalf of Greenpeace Pacific has been released. The paper: Transportation accident of a ship carrying vitrified high-level radioactive waste, Part 1 Impact on the Federated States of Micronesia by Resnikoff and Champion, is dated 31 July 1997. A considerable section of the report is given over to discussion of the economic situation of the Federated Statess of Micronesia, and lifestyle and dietary factors which would influence radiation doses arising from a release. It postulates a worst case accident scenario of a collision between the HLW transport ship and an oil tanker 1 km off Pohnpei with the wind in precisely the direction to result in maximum population exposure, and attempts to assess the consequences. In summary, the report postulates accident and exposure scenarios which are conceivable but not credible. It combines a series of worst case scenarios and attempts to evaluate the consequences. Both the combined scenario and consequences have probabilities of occurrence which are negligible. The shipment carried by the 'Pacific Swan' left Cherbourgon 21 January 1998 and comprised 30 tonnes of reprocessed vitrified waste in 60 stainless steel canisters loaded into three shipping casks. (author)

  6. Physical, Chemical and Structural Evolution of Zeolite-Containing Waste Forms Produced from Metakaolinite and Calcined HLW

    International Nuclear Information System (INIS)

    Grutzeck, Michael; Jantzen, Carol M.

    1999-01-01

    Natural and synthetic zeolites are extremely versatile materials. They can adsorb a variety of liquids and gases, and also take part in cation exchange reactions. Zeolites are easy to synthesize from a wide variety of natural and man made materials. One combination of starting materials that exhibits a great deal of promise is a mixture of metakaolinite and/or Class F fly ash and concentrated sodium hydroxide solution. Once these ingredients are mixed and cured at elevated temperatures, they react to form a hard, dense, ceramic-like material that contains significant amounts of crystalline tectosilicates (zeolites and feldspathoids). Zeolites have the ability to sequester ions in lattice positions or within their networks of channels and voids. As such they are nearly perfect waste forms, the zeolites can host alkali, alkaline earth and a variety of higher valance cations. In addition to zeolites, it has been found that the zeolites are accompanied by an alkali aluminosilicate hydrate matrix that is a host, not only to the zeolites, but to residual amounts of insoluble hydroxide phases as well. A previous publication has established the fact that a mixture of a calcined equivalent ICPP waste (sodium aluminate/hydroxide solution containing ∼3:1 Na:Al) and fly ash and/or metakaolinite could be cured at various temperatures to produce a monolith containing Zeolite A (80 C) or Na-P1 plus hydroxy sodalite (130 C) crystals dispersed in an alkali aluminosilicate hydrate matrix. Dissolution tests have shown these materials (so-called hydroceramics) to have superior retention for alkali, alkaline earth and heavy metal ions. The zeolitization process is a simple one. Metakaolinite and/or Class F fly ash is mixed with a caustic sodium-bearing calcine and enough water to make a thick paste. The paste is transferred to a metal canister and ''soaked'' for a few hours at 70-80 C prior to steam autoclaving the sample at ∼200 C for 6-8 hours. The waste form produced in this

  7. Implementation of a geological disposal facility (GDF) in the UK by the NDA Radioactive Waste Management Directorate (RWMD): the potential for interaction between the co-located ILW/LLW and HLW/SF components of a GDF - 16306

    International Nuclear Information System (INIS)

    Towler, George; Hicks, Tim; Watson, Sarah; Norris, Simon

    2009-01-01

    In June 2008 the UK government published a 'White Paper' as part of the 'Managing Radioactive Waste Safety' (MRWS) programme to provide a framework for managing higher activity radioactive wastes in the long-term through geological disposal. The White Paper identifies that there are benefits to disposing all of the UK's higher activity wastes (Low and Intermediate Level Waste (LLW and ILW), High Level Waste (HLW), Spent Fuel (SF), Uranium (U) and Plutonium (Pu)) at the same site, and this is currently the preferred option. It also notes that research will be required to support the detailed design and safety assessment in relation to any potentially detrimental interactions between the different modules. Different disposal system designs and associated Engineered Barrier Systems (EBS) will be required for these different waste types, i.e. ILW/LLW and HLW/SF. If declared as waste U would be disposed as ILW and Pu as HLW/SF. The Geological Disposal Facility (GDF) would therefore comprise two co-located modules (respectively for ILW/LLW and HLW/SF). This paper presents an overview of a study undertaken to assess the implications of co-location by identifying the key Thermo-Hydro-Mechanical-Chemical (THMC) interactions that might occur during both the operational and post-closure phases, and their consequences for GDF design, performance and safety. The MRWS programme is currently seeking expressions of interest from communities to host a GDF. Therefore, the study was required to consider a wide range of potential GDF host rocks and consistent, conceptual disposal system designs. Two example disposal concepts (i.e. combinations of host rock, GDF design including wasteform and layout, etc.) were carried forward for detailed assessment and a third for qualitative analysis. Dimensional and 1D analyses were used to identify the key interactions, and 3D models were used to investigate selected interactions in more detail. The results of this study show that it is possible

  8. SOURCE TERMS FOR HLW GLASS CANISTERS

    International Nuclear Information System (INIS)

    J.S. Tang

    2000-01-01

    This calculation is prepared by the Monitored Geologic Repository (MGR) Waste Package Design Section. The objective of this calculation is to determine the source terms that include radionuclide inventory, decay heat, and radiation sources due to gamma rays and neutrons for the high-level radioactive waste (HLW) from the, West Valley Demonstration Project (WVDP), Savannah River Site (SRS), Hanford Site (HS), and Idaho National Engineering and Environmental Laboratory (INEEL). This calculation also determines the source terms of the canister containing the SRS HLW glass and immobilized plutonium. The scope of this calculation is limited to source terms for a time period out to one million years. The results of this calculation may be used to carry out performance assessment of the potential repository and to evaluate radiation environments surrounding the waste packages (WPs). This calculation was performed in accordance with the Development Plan ''Source Terms for HLW Glass Canisters'' (Ref. 7.24)

  9. Progress and future direction for the interim safe storage and disposal of Hanford high level waste (HLW)

    International Nuclear Information System (INIS)

    Wodrich, D.D.

    1996-01-01

    This paper describes the progress made at the largest environmental cleanup program in the United States. Substantial advances in methods to start interim safe storage of Hanford Site high-level wastes, waste characterization to support both safety- and disposal-related information needs, and proceeding with cost-effective disposal by the US DOE and its Hanford Site contractors, have been realized. Challenges facing the Tank Waste Remediation System Program, which is charged with the dual and parallel missions of interim safe storage and disposal of the high-level tank waste stored at the Hanford Site, are described

  10. HLW disposal in Germany - R and D achievements and outlook

    International Nuclear Information System (INIS)

    Steininger, W.

    2006-01-01

    The paper gives a brief overview of the status of R and D on HLW disposal. Shortly addressed is the current nuclear policy. After describing the responsibilities regarding R and D for disposing of heat-generating high-level (HLW) waste (vitrified waste and spent fuel), selected projects are mentioned to illustrate the state of knowledge in disposing of waste in rock salt. Participation in international projects and programs is described to illustrate the value for the German concepts and ideas for HLW disposal in different rock types. Finally, a condensed outlook on future activities is given. (author)

  11. PHYSICAL, CHEMICAL, AND STRUCTURAL EVOLUTION OF ZEOLITE-CONTAINING WASTE FORMS PRODUCED FROM METAKAOLINITE AND CALCINED HLW

    International Nuclear Information System (INIS)

    Pareizs, J. M.; Jantzenm, C.M.

    2000-01-01

    Natural and synthetic zeolites are extremely versatile materials. They can adsorb a variety of liquids and gases, and also take part in cation exchange reactions. Zeolites have the ability to sequester ions in lattice positions or within their networks of channels and voids. The zeolites can host alkali, alkaline earth and a variety of higher valance cations. As such they may be a viable alternative for immobilization of low activity waste (LAW) salts and calcines. The process for synthesizing zeolites is well documented for pure starting materials. A reactive aluminosilicate is reacted with an alkaline hydroxide at low temperature (<300 C) to form a zeolite. Processing time and temperature and specific reactants determine the type of zeolite formed. Zeolites are easy to make, and can be synthesized from a wide variety of natural and man made materials. However, relatively little is known about the process if one of the starting materials is a poorly characterized complex mixture of oxides (waste) containing nearly every element in the periodic table. The purpose of this work is to develop a clearer understanding of the advantages and limitations of producing a zeolite waste form from radioactive waste. Dr. M. W. Grutzeck at the Pennsylvania State University is investigating the production of a zeolite waste form using nonradioactive simulants. Dr. C. M. Jantzen and J. M. Pareizs at the Savannah River Technology Center will use the results from simulant work as a starting point for producing a zeolite waste form from an actual Savannah River Site radioactive waste stream

  12. Physical, chemical, and structural evolution of zeolite-containing waste forms produced from metakaolinite and calcined HLW

    International Nuclear Information System (INIS)

    Pareizs, J.M.

    2000-01-01

    Natural and synthetic zeolites are extremely versatile materials. They can adsorb a variety of liquids and gases, and also take part in cation exchange reactions. Zeolites have the ability to sequester ions in lattice positions or within their networks of channels and voids. The zeolites can host alkali, alkaline earth and a variety of higher valence cations. As such they may be a viable alternative for immobilization of low activity waste (LAW) salts and calcines. The process for synthesizing zeolites is well documented for pure starting materials. A reactive aluminosilicate is reacted with an alkaline hydroxide at low temperature to form a zeolite. Processing time and temperature and specific reactants determine the type of zeolite formed. Zeolites are easy to make, and can be synthesized from a wide variety of natural and man made materials. However, relatively little is known about the process if one of the starting materials is a poorly characterized complex mixture of oxides (waste) containing nearly every element in the periodic table. The purpose of this work is to develop a clearer understanding of the advantages and limitations of producing a zeolite waste form from radioactive waste. Dr. M. W. Grutzeck at the Pennsylvania State University is investigating the production of a zeolite waste form using non-radioactive simulants. Dr. C. M. Jantzen and J. M. Pareizs at the Savannah River Technology Center will use the results from simulant work as a starting point for producing a zeolite waste form from an actual Savannah River Site radioactive waste stream

  13. Tc Chemistry in HLW: Role of Organic Complexants

    International Nuclear Information System (INIS)

    Hess, Nancy S.; Conradsen, Steven D.

    2003-01-01

    Tc complexation with organic compounds in tank waste plays a significant role in the redox chemistry of Tc and the partitioning of Tc between the supernatant and sludge components in waste tanks. These processes need to be understood so that strategies to effectively remove Tc from high-level nuclear waste prior to waste immobilization can be developed and so that long-term consequences of Tc remaining in residual waste after sludge removal can be evaluated. Only limited data on the stability of Tc-organic complexes exists and even less thermodynamic data on which to develop predictive models of Tc chemical behavior is available. To meet these challenges we are conducting a research program to study to develop thermodynamic data on Tc-organic complexation over a wide range of chemical conditions. We will attempt to characterize Tc-speciation in actual tank waste using state-of-the-art analytical organic chemistry, separations, and speciation techniques to validate our model. On the basis of such studies we will develop credible model of Tc chemistry in HLW that will allow prediction of Tc speciation in tank waste and Tc behavior during waste pretreatment processing and in waste tank residuals

  14. Citizen Contributions to the Closure of High-Level Waste (HLW) Tanks 18 and 19 at the Department of Energy's (DOE) Savannah River Site (SRS) - 13448

    Energy Technology Data Exchange (ETDEWEB)

    Lawless, W.F. [Paine College, Departments of Math and Psychology, 1235 15th Street, Augusta, GA 30901 (United States)

    2013-07-01

    Citizen involvement in DOE's decision-making for the environmental cleanup from DOE's management of its nuclear wastes across the DOE complex has had a positive effect on the cleanup of its SRS site, characterized by an acceleration of cleanup not only for the Transuranic wastes at SRS, but also for DOE's first two closures of HLW tanks, both of which occurred at SRS. The Citizens around SRS had pushed successfully for the closures of Tanks 17 and 20 in 1997, becoming the first closures of HLW tanks under regulatory guidance in the USA. However, since then, HLW tank closures ceased due to a lawsuit, the application of new tank clean-up technology, interagency squabbling between DOE and NRC over tank closure criteria, and finally and almost fatally, from budget pressures. Despite an agreement with its regulators for the closure of Tanks 18 and 19 by the end of calendar year 2012, the outlook in Fall 2011 to close these two tanks had dimmed. It was at this point that the citizens around SRS became reengaged with tank closures, helping DOE to reach its agreed upon milestone. (authors)

  15. Immobilized High-Level Waste (HLW) Interim Storage Alternative Generation and analysis and Decision Report - second Generation Implementing Architecture

    International Nuclear Information System (INIS)

    CALMUS, R.B.

    2000-01-01

    Two alternative approaches were previously identified to provide second-generation interim storage of Immobilized High-Level Waste (IHLW). One approach was retrofit modification of the Fuel and Materials Examination Facility (FMEF) to accommodate IHLW. The results of the evaluation of the FMEF as the second-generation IHLW interim storage facility and subsequent decision process are provided in this document

  16. Comparison of risks due to HLW and SURF repositories in bedded salt

    International Nuclear Information System (INIS)

    Chu, M.S.Y.; Ortiz, N.R.; Wahi, K.K.

    1983-01-01

    A methodology was developed for use in the analysis of risks from geologic disposal of nuclear wastes. This methodology is applied to two conceptual nuclear waste repositories in bedded salt containing High-Level Waste (HLW) and Spent Un-Reprocessed Fuel (SURF), respectively. A comparison of the risk estimated from the HLW and SURF repositories is presented

  17. Prediction of geological and mechanical processes while disposing of high-level waste (HLW) into the earth crust

    International Nuclear Information System (INIS)

    Kedrovsky, O.L.; Morozov, V.N.

    1992-01-01

    Prediction of geological and mechanical processes while disposing of high-level waste of atomic industry into the earth crust is the fundamental base for ecological risk assessment (possible consequences) while developing repository designs. The subject of this paper is the analytical estimate of possibilities of rock fracturing mechanisms to predict isolation properties loss by massif beginning from crystal lattice of minerals up to large fracture disturbances under conditions of long-term influence of pressure, temperature, and radiation. To solve the problem possibilities of kinetic

  18. HIGH ALUMINUM HLW GLASSES FOR HANFORD'S WTP

    International Nuclear Information System (INIS)

    Kruger, A.A.; Joseph, I.; Bowman, B.W.; Gan, H.; Kot, W.; Matlack, K.S.; Pegg, I.L

    2009-01-01

    The world's largest radioactive waste vitrification facility is now under construction at the United State Department of Energy's (DOE's) Hanford site. The Hanford Tank Waste Treatment and Immobilization Plant (WTP) is designed to treat nearly 53 million gallons of mixed hazardous and radioactive waste now residing in 177 underground storage tanks. This multi-decade processing campaign will be one of the most complex ever undertaken because of the wide chemical and physical variability of the waste compositions generated during the cold war era that are stored at Hanford. The DOE Office of River Protection (ORP) has initiated a program to improve the long-term operating efficiency of the WTP vitrification plants with the objective of reducing the overall cost of tank waste treatment and disposal and shortening the duration of plant operations. Due to the size, complexity and duration of the WTP mission, the lifecycle operating and waste disposal costs are substantial. As a result, gains in High Level Waste (HLW) and Low Activity Waste (LAW) waste loadings, as well as increases in glass production rate, which can reduce mission duration and glass volumes for disposal, can yield substantial overall cost savings. EnergySolutions and its long-term research partner, the Vitreous State Laboratory (VSL) of the Catholic University of America, have been involved in a multi-year ORP program directed at optimizing various aspects of the HLW and LAW vitrification flow sheets. A number of Hanford HLW streams contain high concentrations of aluminum, which is challenging with respect to both waste loading and processing rate. Therefore, a key focus area of the ORP vitrification process optimization program at EnergySolutions and VSL has been development of HLW glass compositions that can accommodate high Al 2 O 3 concentrations while maintaining high processing rates in the Joule Heated Ceramic Melters (JHCMs) used for waste vitrification at the WTP. This paper, reviews the

  19. Thermal analysis in the near field for geological disposal of high-level radioactive waste. Establishment of the disposal tunnel spacing and waste package pitch on the 2nd progress report for the geological disposal of HLW in Japan

    International Nuclear Information System (INIS)

    Taniguchi, Wataru; Iwasa, Kengo

    1999-11-01

    For the underground facility of the geological disposal of high-level radioactive waste (HLW), the space is needed to set the engineered barrier, and the set engineered barrier and rock-mass of near field are needed to satisfy some conditions or constraints for their performance. One of the conditions above mentioned is thermal condition arising from heat outputs of vitrified waste and initial temperature at the disposal depth. Hence, it is needed that the temperature of the engineered barrier and rock mass is less degree than the constraint temperature of each other. Therefore, the design of engineered barrier and underground facility is conducted so that the temperature of the engineered barrier and rock mass is less degree than the constraint temperature of each other. One of these design is establishment of the disposal tunnel spacing and waste package pitch. In this report, thermal analysis is conducted to establish the disposal tunnel spacing and waste package pitch to satisfy the constraint temperature in the near field. Also, other conditions or constraints for establishment of the disposal tunnel spacing and waste package pitch are investigated. Then, design of the disposal tunnel spacing and waste package pitch, considering these conditions or constraints, is conducted. For the near field configuration using the results of the design above mentioned, the temperature with time dependency is studied by analysis, and then the temperature variation due to the gaps, that will occur within the engineered barrier and between the engineered barrier and rock mass in setting engineered barrier in the disposal tunnel or pit, is studied. At last, the disposal depth variation is studied to satisfy the temperature constraint in the near field. (author)

  20. Conditioning of Radioactive Wastes Prior to disposal; Segregation and Repackaging

    Energy Technology Data Exchange (ETDEWEB)

    Kang, Il Sik; Kim, Ki Hong; Hong, Dae Seok; Lee, Bum Chul [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2014-05-15

    We stored several types of radioactive wastes at interim storage facility of KAERI ; the combustible wastes (cloths, decontamination paper and vinyls) from Hanaro multipurpose research reactor, nuclear fuel cycle facility, RI production facility and laboratories, and the non-combustible wastes (metals and glass) dismantled and discarded from the apparatus of laboratories which deteriorated, and also the miscellaneous wastes (spent air-filters). After a segregation of these wastes as the same type, they were treated by using a proper method in order to meet both the national regulation and the waste acceptance criteria of Kyung-ju disposal site. For a safe disposal of waste drums, the waste characterization system including a scaling factor which is hard to measure special radionuclides is established completely. All data of those repackaged drums were input into an ANSIM system so that we could manage them clearly and effectively such like an easy transparent traceability. Through a decontamination of empty drums generated in a repackaging process of the stored drums, these drums can be reused or compressed to reduce their volume reduction for disposal. As a result, the space to store radioactive waste drums are secured more than before, and also the interim storage facility are maintained in a good state. The combustible wastes, which stored at the interim storage facility of KAERI, are managed safely in compliance with the specifications of the national regulations and disposal site. Through the classification and repackage of them, the storage space of drums at RWTF was secured more than before, and the storage facility was kept in a good state, and also the disposal cost of all stored waste drums of KAERI will be reduced due to the reduction of waste volume. Base on the experiences, the non-combustible wastes will be treated soon.

  1. Pre-disposal storage, transport and handling of vitrified high level waste

    International Nuclear Information System (INIS)

    Kempe, T.F.; Martin, A.

    1981-05-01

    The objectives of the study were to review non site-specific engineering features of the storage, transport and handling of vitrified high level radioactive waste prior to its transfer into an underground repository, and to identify those features which require validation or development. Section headings are: introduction (historical and technical background); characteristics and arisings of vitrified high level waste; overpacks (additional containment barrier, corrosion resistant); interim storage of HLW; transport of HLW; handling; conclusions and recommendations. (U.K.)

  2. Industrial scale-plant for HLW partitioning in Russia

    International Nuclear Information System (INIS)

    Dzekun, E.G.; Glagolenko, Y.V.; Drojko, E.G.; Kurochkin, A.I.

    1996-01-01

    Radiochemical plant of PA > at Ozersk, which was come on line in December 1948 originally for weapon plutonium production and reoriented on the reprocessing of spent fuel, till now keeps on storage HLW of the military program. Application of the vitrification method since 1986 has not essentially reduced HLW volumes. So, as of September 1, 1995 vitrification installations had been processed 9590 m 3 HLW and 235 MCi of radionuclides was included in glass. However only 1100 m 3 and 20.5 MCi is part of waste of the military program. The reason is the fact, that the technology and equipment of vitrification were developed for current waste of Purex-process, for which low contents of corrosion-dangerous impurity to materials of vitrification installation is characteristic of. With reference to HLW, which are growing at PA > in the course of weapon plutonium production, the program of Science-Research Works includes the following main directions of work. Development of technology and equipment of installations for immobilising HLW with high contents of impurity into a solid form at induction melter. Application of High-temperature Adsorption Method for sorption of radionuclides from HLW on silica gel. Application of Partitioning Method of radionuclides from HLW, based on extraction cesium and strontium into cobalt dicarbollyde or crown-ethers, but also on recovery of cesium radionuclides by sorption on inorganic sorbents. In this paper the results of work on creation of first industrial scale-plant for partitioning HLW by the extraction and sorption methods are reported

  3. PHYSICAL, CHEMICAL AND STRUCTURAL EVOLUTIION OF ZEOLITE-CONTAINING WASTE FORMS PRODUCED FROM METAKAOLINITE AND CALCINED SODUIM BEARING WASTE (HLW AND/OR LLW)

    International Nuclear Information System (INIS)

    Grutzeck, Michael W.

    2003-01-01

    Zeolites can adsorb liquids and gases, take part in catalytic reactions and serve as cation exchange media. They are commercially available as finely divided powders. Using zeolites to manage radioactive waste is not new, but a process by which zeolites can be made to act both as a host phase and a cementing agent is. It is notable that zeolites occur in nature as well consolidated/cemented deposits. The Romans used blocks of Neapolitan zeolitized tuff as a building material and some of these buildings are still standing. Zeolites are easy to synthesize from a wide range of both natural and man-made precursor materials. The method of making a ''hydroceramic'' is derived from a process in which metakaolinite (thermally dehydroxylated kaolinite) is slurried with a dilute sodium hydroxide (NaOH) solution and then reacted for hours to days at mildly elevated temperatures (60-200 C). The zeolites that form in solution are finely divided powders containing micrometer sized crystals. However, if the process is changed and only enough concentrated sodium hydroxide solution (e.g. 12 M) is added to the metakaolinite to give the mixture a putty-like consistency and the mixture is then cured under similar conditions, the mixture becomes a very hard ceramic-like material containing distinct tectosilicate crystallites (zeolites and feldspathoids) imbedded in an X-ray amorphous sodium aluminosilicate hydrate matrix. Due to the material's vitreous character, the composite has been called a hydroceramic. Similar to zeolite/feldspathoid powders, a hydroceramic is able to sequester cations and a wide range of salt molecules (e.g., nitrate, nitrite and sulfate) in lattice positions and within structural channels and voids thus rendering them ''insoluble'' and making them an ideal contingency waste form for solidifying radioactive waste. The obvious similarities between a hydroceramic waste form and a waste form based on solidified Portland-cement grout are superficial because their

  4. A dose of HLW reality

    International Nuclear Information System (INIS)

    Payne, J.

    1993-01-01

    What many people were sure they knew, and some others were fairly confident they knew, was acknowledged by the US Department of Energy in December: A monitored retrievable storage (MRS) facility will not be ready to accept spent fuel by January 31, 1998. A dose of reality has thus been added to the US high-level radioactive waste scene. Perhaps as important as the new reality is the practical, businesslike nature of the DOE's plan. The Department's proposal has the quality of a plan aimed at genuinely solving a problem rather just going through the motions. (In contrast, some readers are familiar with New York State's procedures for siting and licensing a low-level waste facility - procedures so labyrinthine that they are much more likely to protect political careers in that state than they are to achieve an LLW site). The DOE has received a lot of criticism - some justified, some not - about its handling of the HLW program. In this instance, it is proposing what many in the industry might have recommended: Make available storage capacity for spent nuclear fuel at existing federal government sites

  5. Counter current decantation washing of HLW sludge

    International Nuclear Information System (INIS)

    Brooke, J.N.; Peterson, R.A.

    1997-01-01

    The Savannah River Site (SRS) has 51 High Level Waste (HLW) tanks with typical dimensions 25.9 meters (85 feet) diameter and 10 meters (33 feet) high. Nearly 114 million liters (30 M gallons) of HLW waste is stored in these tanks in the form of insoluble solids called sludge, crystallized salt called salt cake, and salt solutions. This waste is being converted to waste forms stable for long term storage. In one of the processes, soluble salts are washed from HLW sludge in preparation for vitrification. At present, sludge is batch washed in a waste tank with one or no reuse of the wash water. Sodium hydroxide and sodium nitrite are added to the wash water for tank corrosion protection; the large volumes of spent wash water are recycled to the evaporator system; additional salt cake is produced; and sodium carbonate is formed in the washed sludge during storage by reaction with CO 2 from the air. High costs and operational concerns with the current washing process prompts DOE and WSRC to seek an improved washing method. A new method should take full advantage of the physical/chemical properties of sludge, experience from other technical disciplines, processing rate requirements, inherent process safety, and use of proven processes and equipment. Counter current solids washing is a common process in the minerals processing and chemical industries. Washing circuits can be designed using thickeners, filters or centrifuges. Realizing the special needs of nuclear work and the low processing rates required, a Counter Current Decantation (CCD) circuit is proposed using small thickeners and fluidic pumps

  6. PHYSICAL, CHEMICAL AND STRUCTURAL EVOLUTIION OF ZEOLITE-CONTAINING WASTE FORMS PRODUCED FROM METAKAOLINITE AND CALCINED SODUIM BEARING WASTE (HLW AND/OR LLW)

    International Nuclear Information System (INIS)

    Grutzeck, Michael W.

    2004-01-01

    Zeolites are extremely versatile. They can adsorb liquids and gases and serve as cation exchange media. They occur in nature as well cemented deposits. The Romans used blocks of zeolitized tuff as a building material. Using zeolites for the management of radioactive waste is not new, but a process by which the zeolites can be made to act as a cementing agent is. Zeolitic materials are relatively easy to synthesize from a wide range of both natural and man-made precursors. The process under study is derived from a well known method in which metakaolin (thermally dehydroxylated kaolin a mixture of kaolinite and smaller amounts of quartz and mica that has been heated to ∼700 C) is mixed with sodium hydroxide (NaOH) and water and reacted in slurry form (for a day or two) at mildly elevated temperatures. The zeolites form as finely divided powders containing micrometer ((micro)m) sized crystals. However, if the process is changed slightly and just enough concentrated sodium hydroxide solution is added to the metakaolinite to make a thick paste and then the paste is cured under mild hydrothermal conditions (60-200 C), the mixture forms a concrete-like ceramic material made up of distinct crystalline tectosilicate minerals (zeolites and feldspathoids) imbedded in an X-ray amorphous hydrated sodium aluminosilicate matrix. Due to its vitreous character we have chosen to call this composite a ''hydroceramic''. Similar to zeolite powders, a hydroceramic is able to sequester cations in both lattice positions and within the channels and voids present in its tectosilicate framework structure. It can also accommodate a wide range of salt molecules (e.g., sodium nitrate) within these same openings thus rendering them insoluble. Due to its fine crystallite size and cementing character, the matrix develops significant physical strength. The obvious similarities between a hydroceramic waste form and a waste form based on solidified Portland cement grout are only superficial because

  7. MIIT: International in-situ testing of simulated HLW forms - performance of SRS simulated waste glass after 6 mos., 1 yr., 2 yrs. and 5 yrs. of burial at WIPP

    International Nuclear Information System (INIS)

    Wicks, G.G.; Lodding, A.R.; Macedo, P.B.; Clark, D.E.

    1991-01-01

    The first field test, involving burial of simulated high-level waste (HLW) forms and package components, to be conducted in the United States, was begun in July of 1986. This program, called the Materials Interface Interactions Test or MIIT, comprises the largest cooperative field-testing venture in the international waste management community. Included in the study are over 900 waste form samples comprising 15 different systems supplied by 7 countries. Also included are about 300 potential canister or overpack metal samples along with more than 500 geologic and backfill specimens. There are almost 2000 relevant interactions that characterize this effort which is being conducted in the bedded salt site at the Waste Isolation Pilot Plant (WIPP), near Carlsbad, New Mexico. The MIIT program represents a joint effort managed by Sandia National Laboratories in Albuquerque, N.M., and Savannah River Laboratory in Aiken, S.C. and sponsored by the US Department of Energy. Also involved in MIIT are participants from various laboratories and universities in France, Germany, Belgium, Canada, Japan, Sweden, the United Kingdom, and the United States. In July of 1991, the experimental portion of the 5-yr. MIIT program was completed. Although only about 5% of all MIIT samples have been assessed thus far, there are already interesting findings that have emerged. The present paper will discuss results obtained for SRS 165/TDS waste glass after burial of 6 mo., 1 yr. and 2 yrs., along with initial analyses of 5 yr. samples

  8. Predisposal management of high level radioactive waste. Safety guide

    International Nuclear Information System (INIS)

    2005-01-01

    Radioactive waste is generated in the generation of electricity in nuclear power plants and in the use of radioactive material in industry, research and medicine. The importance of the safe management of radioactive waste for the protection of human health and the environment has long been recognized. The principles and requirements that govern the safety of the management of radioactive waste are presented in 'The Principles of Radioactive Waste Management', 'Legal and Governmental Infrastructure for Nuclear, Radiation, Radioactive Waste and Transport Safety' and 'Predisposal Management of Radioactive Waste, Including Decommissioning'. The objective of this Safety Guide is to provide regulatory bodies and the operators that generate and manage radioactive waste with recommendations on how to meet the principles and requirements established in Refs for the predisposal management of HLW. This Safety Guide applies to the predisposal management of HLW. For liquid HLW arising from the reprocessing of spent fuel the recommendations of this Safety Guide apply from when liquid waste from the first extraction process is collected for storage and subsequent processing. Recommendations and guidance on the storage of spent fuel, whether or not declared as waste, subsequent to its removal from the storage facility of a reactor are provided in Refs. For spent fuel declared as waste this Safety Guide applies to all activities subsequent to its removal from the storage facility of a reactor and prior to its disposal. Requirements pertaining to the transport of spent fuel, whether or not declared as waste, and of all forms of HLW are established. This Safety Guide provides recommendations on the safety aspects of managing HLW, including the planning, design, construction, commissioning, operation and decommissioning of equipment or facilities for the predisposal management of HLW. It addresses the following elements: (a) The characterization and processing (i.e. pretreatment

  9. HLW Disposal System Development

    Energy Technology Data Exchange (ETDEWEB)

    Choi, J. W.; Choi, H. J.; Lee, J. Y. (and others)

    2007-06-15

    A KRS is suggested through design requirement analysis of the buffer and the canister which are the constituent of disposal system engineered barrier and HLW management plans are proposed. In the aspect of radionuclide retention capacity, the thickness of the buffer is determined 0.5m, the shape to be disc and ring and the dry density to be 1.6 g/cm{sup 3}. The maximum temperature of the buffer is below 100 .deg. which meets the design requirement. And bentonite blocks with 5 wt% of graphite showed more than 1.0 W/mK of thermal conductivity without the addition of sand. The result of the thermal analysis for proposed double-layered buffer shows that decrease of 7 .deg. C in maximum temperature of the buffer. For the disposal canister, the copper for the outer shell material and cast iron for the inner structure material is recommended considering the results analyzed in terms of performance of the canisters and manufacturability and the geochemical properties of deep groundwater sampled from the research area with granite, salt water intrusion, and the heavy weight of the canister. The results of safety analysis for the canister shows that the criticality for the normal case including uncertainty is the value of 0.816 which meets subcritical condition. Considering nation's 'Basic Plan for Electric Power Demand and Supply' and based on the scenario of disposing CANDU spent fuels in the first phase, the disposal system that the repository will be excavated in eight phases with the construction of the Underground Research Laboratory (URL) beginning in 2020 and commissioning in 2040 until the closure of the repository is proposed. Since there is close correlation between domestic HLW management plans and front-end/back-end fuel cycle plans causing such a great sensitivity of international environment factor, items related to assuring the non-proliferation and observing the international standard are showed to be the influential factor and acceptability

  10. Physical, Chemical and Structural Evolution of Zeolite-Containing Waste Forms Produced from Metakaolinite and Calcined Sodium Bearing Waste (HLW and/or LLW)

    International Nuclear Information System (INIS)

    Grutzeck, Michael W.

    2005-01-01

    Zeolites are extremely versatile. They can adsorb liquids and gases and serve as cation exchange media. They occur in nature as well cemented deposits. The ancient Romans used blocks of zeolitized tuff as a building material. Using zeolites for the management of radioactive waste is not a new idea, but a process by which the zeolites can be made to act as a cementing agent is. Zeolitic materials are relatively easy to synthesize from a wide range of both natural and man-made substances. The process under study is derived from a well known method in which metakaolin (an impure thermally dehydroxylated kaolinite heated to ∼700 C containing traces of quartz and mica) is mixed with sodium hydroxide (NaOH) and reacted in slurry form (for a day or two) at mildly elevated temperatures. The zeolites form as finely divided powders containing micrometer ((micro)m) sized crystals. However, if the process is changed slightly and only just enough concentrated sodium hydroxide solution is added to the metakaolinite to make a thick crumbly paste and then the paste is compacted and cured under mild hydrothermal conditions (60-200 C), the mixture will form a hard ceramic-like material containing distinct crystalline tectosilicate minerals (zeolites and feldspathoids) imbedded in an X-ray amorphous hydrated sodium aluminosilicate matrix. Due to its lack of porosity and vitreous appearance we have chosen to call this composite a ''hydroceramic''

  11. Korean Reference HLW Disposal System

    Energy Technology Data Exchange (ETDEWEB)

    Choi, Heui Joo; Lee, J. Y.; Kim, S. S. (and others)

    2008-03-15

    This report outlines the results related to the development of Korean Reference Disposal System for High-level radioactive wastes. The research has been supported around for 10 years through a long-term research plan by MOST. The reference disposal method was selected via the first stage of the research during which the technical guidelines for the geological disposal of HLW were determined too. At the second stage of the research, the conceptual design of the reference disposal system was made. For this purpose the characteristics of the reference spent fuels from PWR and CANDU reactors were specified, and the material and specifications of the canisters were determined in term of structural analysis and manufacturing capability in Korea. Also, the mechanical and chemical characteristics of the domestic Ca-bentonite were analyzed in order to supply the basic design parameters of the buffer. Based on these parameters the thermal and mechanical analysis of the near-field was carried out. Thermal-Hydraulic-Mechanical behavior of the disposal system was analyzed. The reference disposal system was proposed through the second year research. At the final third stage of the research, the Korean Reference disposal System including the engineered barrier, surface facilities, and underground facilities was proposed through the performance analysis of the disposal system.

  12. HLW Canister and Can-In-Canister Drop Calculation

    International Nuclear Information System (INIS)

    H. Marr

    1999-01-01

    The purpose of this calculation is to evaluate the structural response of the standard high-level waste (HLW) canister and the HLW canister containing the cans of immobilized plutonium (''can-in-canister'' throughout this document) to the drop event during the handling operation. The objective of the calculation is to provide the structure parameter information to support the canister design and the waste handling facility design. Finite element solution is performed using the commercially available ANSYS Version (V) 5.4 finite element code. Two-dimensional (2-D) axisymmetric and three-dimensional (3-D) finite element representations for the standard HLW canister and the can-in-canister are developed and analyzed using the dynamic solver

  13. Influence of Glass Property Restrictions on Hanford HLW Glass Volume

    International Nuclear Information System (INIS)

    Kim, Dong-Sang; Vienna, John D.

    2001-01-01

    A systematic evaluation of Hanford High-Level Waste (HLW) loading in alkali-alumino-borosilicate glasses was performed. The waste feed compositions used were obtained from current tank waste composition estimates, Hanford's baseline retrieval sequence, and pretreatment processes. The waste feeds were sorted into groups of like composition by cluster analysis. Glass composition optimization was performed on each cluster to meet property and composition constraints while maximizing waste loading. Glass properties were estimated using property models developed for Hanford HLW glasses. The impacts of many constraints on the volume of HLW glass to be produced at Hanford were evaluated. The liquidus temperature, melting temperature, chromium concentration, formation of multiple phases on cooling, and product consistency test response requirements for the glass were varied one- or many-at-a-time and the resultant glass volume was calculated. This study shows clearly that the allowance of crystalline phases in the glass melter can significantly decrease the volume of HLW glass to be produced at Hanford.

  14. PAIRWISE BLENDING OF HIGH LEVEL WASTE

    International Nuclear Information System (INIS)

    CERTA, P.J.

    2006-01-01

    The primary objective of this study is to demonstrate a mission scenario that uses pairwise and incidental blending of high level waste (HLW) to reduce the total mass of HLW glass. Secondary objectives include understanding how recent refinements to the tank waste inventory and solubility assumptions affect the mass of HLW glass and how logistical constraints may affect the efficacy of HLW blending

  15. Safety assessment of HLW geological disposal system

    International Nuclear Information System (INIS)

    Naito, Morimasa

    2006-01-01

    In accordance with the Japanese nuclear program, the liquid waste with a high level of radioactivity arising from reprocessing is solidified in a stable glass matrix (vitrification) in stainless steel fabrication containers. The vitrified waste is referred to as high-level radioactive waste (HLW), and is characterized by very high initial radioactivity which, even though it decreases with time, presents a potential long-term risk. It is therefore necessary to thoroughly manage HLW from human and his environment. After vitrification, HLW is stored for a period of 30 to 50 years to allow cooling, and finally disposed of in a stable geological environment at depths greater than 300 m below surface. The deep underground environment, in general, is considered to be stable over geological timescales compared with surface environment. By selecting an appropriate disposal site, therefore, it is considered to be feasible to isolate the waste in the repository from man and his environment until such time as radioactivity levels have decayed to insignificance. The concept of geological disposal in Japan is similar to that in other countries, being based on a multibarrier system which combines the natural geological environment with engineered barriers. It should be noted that geological disposal concept is based on a passive safety system that does not require any institutional control for assuring long term environmental safety. To demonstrate feasibility of safe HLW repository concept in Japan, following technical steps are essential. Selection of a geological environment which is sufficiently stable for disposal (site selection). Design and installation of the engineered barrier system in a stable geological environment (engineering measures). Confirmation of the safety of the constructed geological disposal system (safety assessment). For site selection, particular consideration is given to the long-term stability of the geological environment taking into account the fact

  16. HLW immobilization in glass: industrial operation and product quality

    International Nuclear Information System (INIS)

    Jacquet-Francillon, N.; Leroy, P.; Runge, S.

    1992-01-01

    This extended summary discusses the immobilization of high level wastes from the viewpoint of the quality of the final product, i.e. the HLW glass. The R and D studies comprise 3 steps: glass formulation, glass characterization and long term behaviour studies

  17. Long-term storage or disposal of HLW-dilemma

    International Nuclear Information System (INIS)

    Ninkovic, M. M.; Raicevic, J.

    1995-01-01

    In this paper, a new concept approach to HLW management founded on deterministic safety philosophy - i.e. long-term storage with final objective of destroying was justified and proposed instead of multi barrier concept with final disposal in extra stable environmental conditions, which are founded on probabilistic safety approach model. As a support to this new concept some methods for destruction of waste which are now accessible, on scientific stage only, as transmutation in fast reactors and accelerators of heavy ions were briefly discussed . It is justified to believe that industrial technology for destruction of HLW would be developed in not so far future. (author).

  18. Active geothermal systems as natural analogs of HLW repositories

    International Nuclear Information System (INIS)

    Elders, W.A.; Williams, A.E.; Cohen, L.H.

    1988-01-01

    Geologic analogs of long-lived processes in high-level waste (HLW) repositories have been much studied in recent years. However, most of these occurrences either involve natural processes going on today at 25 degree C, or, if they are concerned with behavior at temperatures similar to the peak temperatures anticipated near HLW canisters, have long since ended. This paper points out the usefulness of studying modern geothermal systems as natural analogs, and to illustrate the concept with a dramatic example, the Salton Sea geothermal system (SSGS)

  19. R and D on HLW Partitioning in Russia

    International Nuclear Information System (INIS)

    Khaperskaya, A.; Babain, V.; Alyapyshev, M.

    2015-01-01

    Results of more than thirty years investigations on high level radioactive waste (HLW) partitioning in Russia are described. The objectives of research and development is to assess HLW partitioning technical feasibility and its advantages compared to direct vitrification of long-lived radionuclides. Many technological flowsheets for long-lived nuclides (cesium, strontium and minor actinides) separation were developed and tested with simulated and actual HLW. Different classes of extractants, including carbamoyl-phosphine oxides, dialkyl-phosphoric acids, crown ethers and diamides of heterocyclic acids were studied. Some of these processes were tested at PA 'Mayak' and MCC. Many extraction systems based on chlorinated cobalt dicarbollide (CCD), including UNEX-extractant and its modifications, were also observed. Diamides of diglycolic acid and diamides of heterocyclic acids in polar diluents have shown promising properties for minor actinide-lanthanide extraction and separation. Comparison of different solvents and possible ways of implementing new flowsheets in radiochemical technology are also discussed. (authors)

  20. Database and Interim Glass Property Models for Hanford HLW Glasses

    International Nuclear Information System (INIS)

    Hrma, Pavel R; Piepel, Gregory F; Vienna, John D; Cooley, Scott K; Kim, Dong-Sang; Russell, Renee L

    2001-01-01

    The purpose of this report is to provide a methodology for an increase in the efficiency and a decrease in the cost of vitrifying high-level waste (HLW) by optimizing HLW glass formulation. This methodology consists in collecting and generating a database of glass properties that determine HLW glass processability and acceptability and relating these properties to glass composition. The report explains how the property-composition models are developed, fitted to data, used for glass formulation optimization, and continuously updated in response to changes in HLW composition estimates and changes in glass processing technology. Further, the report reviews the glass property-composition literature data and presents their preliminary critical evaluation and screening. Finally the report provides interim property-composition models for melt viscosity, for liquidus temperature (with spinel and zircon primary crystalline phases), and for the product consistency test normalized releases of B, Na, and Li. Models were fitted to a subset of the screened database deemed most relevant for the current HLW composition region

  1. Final Report Start-Up And Commissioning Tests On The Duramelter 1200 HLW Pilot Melter System Using AZ-101 HLW Simulants VSL-01R0100-2, Rev. 0, 1/20/03

    International Nuclear Information System (INIS)

    Kruger, A.A.; Matlack, K.S.; Kot, W.K.; Brandys, M.; Wilson, C.N.; Schatz, T.R.; Gong, W.; Pegg, I.L.

    2011-01-01

    This document provides the final report on data and results obtained from commissioning tests performed on the one-third scale DuraMelter(trademark) 1200 (DM 1200) HLW Pilot Melter system that has been installed at VSL with an integrated prototypical off-gas treatment system. That system has replaced the DM1000 system that was used for HLW throughput testing during Part BI (1). Both melters have similar melt surface areas (1.2 m 2 ) but the DM1200 is prototypical of the present RPP-WTP HLW melter design whereas the DM1000 was not. These tests were performed under a corresponding RPP-WTP Test Specification and associated Test Plan. This report is a followup to the previously issued Preliminary Data Summary Report. The DM1200 system will be used for testing and confirmation of basic design, operability, flow sheet, and process control assumptions as well as for support of waste form qualification and permitting. This will include data on processing rates, off-gas treatment system performance, recycle stream compositions, as well as process operability and reliability. Consequently, this system is a key component of the overall HLW vitrification development strategy. The results presented in this report are from the initial series of short-duration tests that were conducted to support the start-up and commissioning of this system prior to conducting the main body of development tests that have been planned for this system. These tests were directed primarily at system 'debugging,' operator training, and procedure refinement. The AZ-101 waste simulant and glass composition that was used for previous testing was selected for these tests.

  2. FINAL REPORT START-UP AND COMMISSIONING TESTS ON THE DURAMELTER 1200 HLW PILOT MELTER SYSTEM USING AZ-101 HLW SIMULANTS VSL-01R0100-2 REV 0 1/20/03

    Energy Technology Data Exchange (ETDEWEB)

    KRUGER AA; MATLACK KS; KOT WK; BRANDYS M; WILSON CN; SCHATZ TR; GONG W; PEGG IL

    2011-12-29

    This document provides the final report on data and results obtained from commissioning tests performed on the one-third scale DuraMelter{trademark} 1200 (DM 1200) HLW Pilot Melter system that has been installed at VSL with an integrated prototypical off-gas treatment system. That system has replaced the DM1000 system that was used for HLW throughput testing during Part BI [1]. Both melters have similar melt surface areas (1.2 m{sup 2}) but the DM1200 is prototypical of the present RPP-WTP HLW melter design whereas the DM1000 was not. These tests were performed under a corresponding RPP-WTP Test Specification and associated Test Plan. This report is a followup to the previously issued Preliminary Data Summary Report. The DM1200 system will be used for testing and confirmation of basic design, operability, flow sheet, and process control assumptions as well as for support of waste form qualification and permitting. This will include data on processing rates, off-gas treatment system performance, recycle stream compositions, as well as process operability and reliability. Consequently, this system is a key component of the overall HLW vitrification development strategy. The results presented in this report are from the initial series of short-duration tests that were conducted to support the start-up and commissioning of this system prior to conducting the main body of development tests that have been planned for this system. These tests were directed primarily at system 'debugging,' operator training, and procedure refinement. The AZ-101 waste simulant and glass composition that was used for previous testing was selected for these tests.

  3. COMSOL Multiphysics Model for HLW Canister Filling

    Energy Technology Data Exchange (ETDEWEB)

    Kesterson, M. R. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2016-04-11

    The U.S. Department of Energy (DOE) is building a Tank Waste Treatment and Immobilization Plant (WTP) at the Hanford Site in Washington to remediate 55 million gallons of radioactive waste that is being temporarily stored in 177 underground tanks. Efforts are being made to increase the loading of Hanford tank wastes in glass while meeting melter lifetime expectancies and process, regulatory, and product quality requirements. Wastes containing high concentrations of Al2O3 and Na2O can contribute to nepheline (generally NaAlSiO4) crystallization, which can sharply reduce the chemical durability of high level waste (HLW) glass. Nepheline crystallization can occur during slow cooling of the glass within the stainless steel canister. The purpose of this work was to develop a model that can be used to predict temperatures of the glass in a WTP HLW canister during filling and cooling. The intent of the model is to support scoping work in the laboratory. It is not intended to provide precise predictions of temperature profiles, but rather to provide a simplified representation of glass cooling profiles within a full scale, WTP HLW canister under various glass pouring rates. These data will be used to support laboratory studies for an improved understanding of the mechanisms of nepheline crystallization. The model was created using COMSOL Multiphysics, a commercially available software. The model results were compared to available experimental data, TRR-PLT-080, and were found to yield sufficient results for the scoping nature of the study. The simulated temperatures were within 60 ºC for the centerline, 0.0762m (3 inch) from centerline, and 0.2286m (9 inch) from centerline thermocouples once the thermocouples were covered with glass. The temperature difference between the experimental and simulated values reduced to 40 ºC, 4 hours after the thermocouple was covered, and down to 20 ºC, 6 hours after the thermocouple was covered

  4. Application of QA to R ampersand D support of HLW programs

    International Nuclear Information System (INIS)

    Ryder, D.E.

    1988-01-01

    Quality has always been of primary importance in the research and development (R ampersand D) environment. An organization's ability to attract funds for new or continued research is largely dependent on the quality of past performance. However, with the possible exceptions of peer reviews for fund allocation and the referee process prior to publication, past quality assurance (QA) activities were primarily informal good practices. This resulted in standards of acceptable practice that varied from organization to organization. The increasing complexity of R ampersand D projects and the increasing need for project results to be upheld outside the scientific community (i.e., lawsuits and licensing hearings) are encouraging R ampersand D organizations and their clients to adopt more formalized methods for the scientific process and to increase control over support organizations (i.e., suppliers and subcontractors). This has become especially true for R ampersand D organizations involved in the high-level (HLW) projects for a number of years. The PNL began to implement QA program requirements within a few HLW repository preliminary studies in 1978. In 1985, PNL developed a comprehensive QA program for R ampersand D activities in support of two of the proposed repository projects. This QA program was developed by the PNL QA department with a significant amount of support assistance and guidance from PNL upper management, the Basalt Waste Isolation Project (BWIP), and the Salt Repository Program Office (SPRO). The QA program has been revised to add a three-level feature and is currently being implemented on projects sponsored by the Office of Geologic Repositories (DOE/OGR), Repository Technology Program (DOE-CH), Nevada Nuclear Waste Storage Investigation (NNWSI) Project, and other HLW projects

  5. TWRS HLW interim storage facility search and evaluation

    Energy Technology Data Exchange (ETDEWEB)

    Calmus, R.B., Westinghouse Hanford

    1996-05-16

    The purpose of this study was to identify and provide an evaluation of interim storage facilities and potential facility locations for the vitrified high-level waste (HLW) from the Phase I demonstration plant and Phase II production plant. In addition, interim storage facilities for solidified separated radionuclides (Cesium and Technetium) generated during pretreatment of Phase I Low-Level Waste Vitrification Plant feed was evaluated.

  6. HLW disposal dilemma

    International Nuclear Information System (INIS)

    Andrei, V.; Glodeanu, F.

    2003-01-01

    The radioactive waste is an inevitable residue from the use of radioactive materials in industry, research and medicine, and from the operation of generating electricity nuclear power stations. The management and disposal of such waste is therefore an issue relevant to almost all countries. Undoubtedly the biggest issue concerning radioactive waste management is that of high level waste. The long-lived nature of some types of radioactive wastes and the associated safety implications of disposal plans have raised concern amongst those who may be affected by such facilities. For these reasons the subject of radioactive waste management has taken on a high profile in many countries. Not one Member State in the European Union can say that their high level waste will be disposed of at a specific site. Nobody can say 'that is where it is going to go'. Now, there is a very broad consensus on the concept of geological disposal. The experts have little, if any doubt that we could safely dispose of the high level wastes. Large sectors of the public continue to oppose to most proposals concerning the siting of repositories. Given this, it is increasingly difficult to get political support, or even political decisions, on such sites. The failure to advance to the next step in the waste management process reinforces the public's initial suspicion and resistance. In turn, this makes the political decisions even harder. In turn, this makes the political decisions even harder. The management of spent fuel from nuclear power plant became a crucial issue, as the cooling pond of the Romanian NPP is reaching saturation. During the autumn of 2000, the plant owner proceeded with an international tendering process for the supply of a dry storage system to be implemented at the Cernavoda station to store the spent fuel from Unit 1 and eventually from Unit 2 for a minimum period of 50 years. The facility is now in operation. As concern the disposal of the spent fuel, the 'wait and see

  7. HLW Tank Space Management, Final Report

    International Nuclear Information System (INIS)

    Sessions, J.

    1999-01-01

    The HLW Tank Space Management Team (SM Team) was chartered to select and recommend an HLW Tank Space Management Strategy (Strategy) for the HLW Management Division of Westinghouse Savannah River Co. (WSRC) until an alternative salt disposition process is operational. Because the alternative salt disposition process will not be available to remove soluble radionuclides in HLW until 2009, the selected Strategy must assure that it safely receives and stores HLW at least until 2009 while continuing to supply sludge slurry to the DWPF vitrification process

  8. HLW Long-term Management Technology Development

    International Nuclear Information System (INIS)

    Choi, Jong Won; Kang, C. H.; Ko, Y. K.

    2010-02-01

    Permanent disposal of spent nuclear fuels from the power generation is considered to be the unique method for the conservation of human being and nature in the present and future. In spite of spent nuclear fuels produced from power generation, based on the recent trends on the gap between supply and demand of energy, the advance on energy price and reduction of carbon dioxide, nuclear energy is expected to play a role continuously in Korea. It means that a new concept of nuclear fuel cycle is needed to solve problems on spent nuclear fuels. The concept of the advanced nuclear fuel cycle including PYRO processing and SFR was presented at the 255th meeting of the Atomic Energy Commission. According to the concept of the advanced nuclear fuel cycle, actinides and long-term fissile nuclides may go out of existence in SFR. And then it is possible to dispose of short term decay wastes without a great risk bearing. Many efforts had been made to develop the KRS for the direct disposal of spent nuclear fuels in the representative geology of Korea. But in the case of the adoption of Advanced nuclear fuel cycle, the disposal of PYRO wastes should be considered. For this, we carried out the Safety Analysis on HLW Disposal Project with 5 sub-projects such as Development of HLW Disposal System, Radwaste Disposal Safety Analysis, Feasibility study on the deep repository condition, A study on the Nuclide Migration and Retardation Using Natural Barrier, and In-situ Study on the Performance of Engineered Barriers

  9. Legal precedents regarding use and defensibility of risk assessment in Federal transportation of SNF and HLW

    International Nuclear Information System (INIS)

    Bentz, E.J. Jr.; Bentz, C.B.; O'Hora, T.D.; Chen, S.Y.

    1997-01-01

    Risk assessment has become an increasingly important and essential tool in support of Federal decision-making regarding the handling, storage, disposal, and transportation of spent nuclear fuel (SNF) and high-level radioactive waste (HLW). This paper analyzes the current statutory and regulatory framework and related legal precedents with regard to SNF and HLW transportation. The authors identify key scientific and technical issues regarding the use and defensibility of risk assessment in Federal decision-making regarding anticipated shipments

  10. Development of Simulants to Support Mixing Tests for High Level Waste and Low Activity Waste

    International Nuclear Information System (INIS)

    EIBLING, RUSSELLE.

    2004-01-01

    The objectives of this study were to develop two different types of simulants to support vendor agitator design studies and mixing studies. The initial simulant development task was to develop rheologically-bounding physical simulants and the final portion was to develop a nominal chemical simulant which is designed to match, as closely as possible, the actual sludge from a tank. The physical simulants to be developed included a lower and upper rheologically bounded: pretreated low activity waste (LAW) physical simulant; LAW melter feed physical simulant; pretreated high level waste (HLW) physical simulant; HLW melter feed physical simulant. The nominal chemical simulant, hereafter referred to as the HLW Precipitated Hydroxide simulant, is designed to represent the chemical/physical composition of the actual washed and leached sludge sample. The objective was to produce a simulant which matches not only the chemical composition but also the physical properties of the actual waste sample. The HLW Precipitated Hydroxide simulant could then be used for mixing tests to validate mixing, homogeneity and representative sampling and transferring issues. The HLW Precipitated Hydroxide simulant may also be used for integrated nonradioactive testing of the WTP prior to radioactive operation

  11. Long-term integrity of waste package final closure for HLW geological disposal, (2). Applicability of TIG welding method to overpack final closure

    International Nuclear Information System (INIS)

    Asano, Hidekazu; Sawa, Shuusuke; Aritomi, Masanori

    2005-01-01

    Overpack, a high-level radioactive waste package for geological disposal, seals vitrified waste and in line with Japan's waste management program is required to isolate it from contact with groundwater for 1,000 years. In this study, TIG (Tungsten Inert Gas) welding method, a typical arc welding method and widely used in various industries, was examined for its applicability to seal a carbon steel overpack lid with a thickness of 190 mm. Welding conditions and welding parameters were examined for multi-layer welding in a narrow gap for four different groove depths. Weld joint tests were conducted and weld flaws, macro- and microstructure, and mechanical properties were assessed within tentatively applied criteria for weld joints. Measurement and numerical calculation for residual stress were also conducted and the tendency of residual stress distribution was discussed. These test results were compared with the basic requirements of the welding method for overpack which were pointed out in our first report. It is assessed that the TIG welding method has the potential to provide the necessary requirements to complete the final closure of overpack with a maximum thickness of 190 mm. (author)

  12. A Safety Case Approach for Deep Geologic Disposal of DOE HLW and DOE SNF in Bedded Salt - 13350

    Energy Technology Data Exchange (ETDEWEB)

    Sevougian, S. David [Advanced Nuclear Energy Programs Group, Sandia National Laboratories, P.O. Box 5800, Albuquerque, NM 87185 (United States); MacKinnon, Robert J. [Advanced Nuclear Energy Programs Group, Sandia National Laboratories, P.O. Box 5800, Albuquerque, NM 87185 (United States); Leigh, Christi D. [Defense Waste Management Programs Group, Sandia National Laboratories, P.O. Box 5800, Albuquerque, NM 87185 (United States); Hansen, Frank D. [Geoscience Research and Applications Group, Sandia National Laboratories, P.O. Box 5800, Albuquerque, NM 87185 (United States)

    2013-07-01

    The primary objective of this study is to investigate the feasibility and utility of developing a defensible safety case for disposal of United States Department of Energy (U.S. DOE) high-level waste (HLW) and DOE spent nuclear fuel (SNF) in a conceptual deep geologic repository that is assumed to be located in a bedded salt formation of the Delaware Basin [1]. A safety case is a formal compilation of evidence, analyses, and arguments that substantiate and demonstrate the safety of a proposed or conceptual repository. We conclude that a strong initial safety case for potential licensing can be readily compiled by capitalizing on the extensive technical basis that exists from prior work on the Waste Isolation Pilot Plant (WIPP), other U.S. repository development programs, and the work published through international efforts in salt repository programs such as in Germany. The potential benefits of developing a safety case include leveraging previous investments in WIPP to reduce future new repository costs, enhancing the ability to effectively plan for a repository and its licensing, and possibly expediting a schedule for a repository. A safety case will provide the necessary structure for organizing and synthesizing existing salt repository science and identifying any issues and gaps pertaining to safe disposal of DOE HLW and DOE SNF in bedded salt. The safety case synthesis will help DOE to plan its future R and D activities for investigating salt disposal using a risk-informed approach that prioritizes test activities that include laboratory, field, and underground investigations. It should be emphasized that the DOE has not made any decisions regarding the disposition of DOE HLW and DOE SNF. Furthermore, the safety case discussed herein is not intended to either site a repository in the Delaware Basin or preclude siting in other media at other locations. Rather, this study simply presents an approach for accelerated development of a safety case for a potential

  13. A Safety Case Approach for Deep Geologic Disposal of DOE HLW and DOE SNF in Bedded Salt - 13350

    International Nuclear Information System (INIS)

    Sevougian, S. David; MacKinnon, Robert J.; Leigh, Christi D.; Hansen, Frank D.

    2013-01-01

    The primary objective of this study is to investigate the feasibility and utility of developing a defensible safety case for disposal of United States Department of Energy (U.S. DOE) high-level waste (HLW) and DOE spent nuclear fuel (SNF) in a conceptual deep geologic repository that is assumed to be located in a bedded salt formation of the Delaware Basin [1]. A safety case is a formal compilation of evidence, analyses, and arguments that substantiate and demonstrate the safety of a proposed or conceptual repository. We conclude that a strong initial safety case for potential licensing can be readily compiled by capitalizing on the extensive technical basis that exists from prior work on the Waste Isolation Pilot Plant (WIPP), other U.S. repository development programs, and the work published through international efforts in salt repository programs such as in Germany. The potential benefits of developing a safety case include leveraging previous investments in WIPP to reduce future new repository costs, enhancing the ability to effectively plan for a repository and its licensing, and possibly expediting a schedule for a repository. A safety case will provide the necessary structure for organizing and synthesizing existing salt repository science and identifying any issues and gaps pertaining to safe disposal of DOE HLW and DOE SNF in bedded salt. The safety case synthesis will help DOE to plan its future R and D activities for investigating salt disposal using a risk-informed approach that prioritizes test activities that include laboratory, field, and underground investigations. It should be emphasized that the DOE has not made any decisions regarding the disposition of DOE HLW and DOE SNF. Furthermore, the safety case discussed herein is not intended to either site a repository in the Delaware Basin or preclude siting in other media at other locations. Rather, this study simply presents an approach for accelerated development of a safety case for a potential

  14. Cesium and strontium fractionation from HLW for thermal-stress reduction in a geologic repository

    International Nuclear Information System (INIS)

    McKee, R.W.

    1983-02-01

    Results are described for a study to assess the benefits and costs of fractionating the cesium and strontium components in commercial high-level waste (HLW) to a separate waste stream for the purpose of reducing geologic repository thermal stresses. System costs are developed for a broad range of conditions comparing the Cs/Sr fractionation concept with disposal of 10-year old vitrified HLW and vitrified HLW aged to achieve (through decay) the same heat output as the fractionated high-level waste (FHLW). All comparisons are based on a 50,000 metric ton equivalent (MTE) system. The FHLW and the Cs/Sr waste are both disposed of a vitrified waste but emplaced in separate areas of a basalt repository. The FHLW is emplaced in high-integrity packages at relatively high waste loading but low heat loading, while the Cs/Sr waste is emplaced in minimum integrity packages at relatively high heat loading. System cost comparisons are based on minimum cost combinations of canister diameter, waste concentration, and canister spacing in a basalt repository for each waste type. The effects on both long- and near-term safety considerations are also addressed. The major conclusion is that the Cs/Sr fractionation concept offers, potentially, a substantial total system cost advantage for HLW disposal if reduced HLW package temperatures in a basalt repository are desired. However, there is no cost advantage if currently designated maximum design temperatures are acceptable. Aging the HLW for 50 to 100 years can accomplish similar results at equivalent or loser costs

  15. HLW Glass Studies: Development of Crystal-Tolerant HLW Glasses

    Energy Technology Data Exchange (ETDEWEB)

    Matyas, Josef; Huckleberry, Adam R.; Rodriguez, Carmen P.; Lang, Jesse B.; Owen, Antionette T.; Kruger, Albert A.

    2012-04-02

    In our study, a series of lab-scale crucible tests were performed on designed glasses of different compositions to further investigate and simulate the effect of Cr, Ni, Fe, Al, Li, and RuO2 on the accumulation rate of spinel crystals in the glass discharge riser of the HLW melter. The experimental data were used to expand the compositional region covered by an empirical model developed previously (Matyáš et al. 2010b), improving its predictive performance. We also investigated the mechanism for agglomeration of particles and impact of agglomerates on accumulation rate. In addition, the TL was measured as a function of temperature and composition.

  16. RECENT PROCESS IMPROVEMENTS TO INCREASE HLW THROUGHPUT AT THE DWPF

    International Nuclear Information System (INIS)

    Herman, C

    2007-01-01

    The Savannah River Site's (SRS) Defense Waste Processing Facility (DWPF), the world's largest operating high level waste (HLW) vitrification plant, began stabilizing about 35 million gallons of SRS liquid radioactive waste by-product in 1996. The DWPF has since filled over 2000 canisters with about 4000 pounds of radioactive glass in each canister. In the past few years there have been several process and equipment improvements at the DWPF to increase the rate at which the waste can be stabilized. These improvements have either directly increased waste processing rates or have desensitized the process and therefore minimized process upsets and thus downtime. These improvements, which include glass former optimization, increased waste loading of the glass, the melter heated bellows liner, and glass surge protection software, will be discussed in this paper

  17. Redox Control For Hanford HLW Feeds VSL-12R2530-1, REV 0

    International Nuclear Information System (INIS)

    Kruger, A. A.; Matlack, Keith S.; Pegg, Ian L.; Kot, Wing K.; Joseph, Innocent

    2012-01-01

    The principal objectives of this work were to investigate the effects of processing simulated Hanford HLW at the estimated maximum concentrations of nitrates and oxalates and to identify strategies to mitigate any processing issues resulting from high concentrations of nitrates and oxalates. This report provides results for a series of tests that were performed on the DM10 melter system with simulated C-106/AY-102 HLW. The tests employed simulated HLW feeds containing variable amounts of nitrates and waste organic compounds corresponding to maximum concentrations proj ected for Hanford HLW streams in order to determine their effects on glass production rate, processing characteristics, glass redox conditions, melt pool foaming, and the tendency to form secondary phases. Such melter tests provide information on key process factors such as feed processing behavior, dynamic effects during processing, processing rates, off-gas amounts and compositions, foaming control, etc., that cannot be reliably obtained from crucible melts

  18. Redox Control For Hanford HLW Feeds VSL-12R2530-1, REV 0

    Energy Technology Data Exchange (ETDEWEB)

    Kruger, A. A. [Department of Energy, Office of River Protection, Richland, Washington (United States); Matlack, Keith S. [The Catholic University of America, Washington, DC (United States); Pegg, Ian L. [The Catholic University of America, Washington, DC (United States); Kot, Wing K. [The Catholic University of America, Washington, DC (United States); Joseph, Innocent [The Catholic University of America, Washington, DC (United States)

    2012-12-13

    The principal objectives of this work were to investigate the effects of processing simulated Hanford HLW at the estimated maximum concentrations of nitrates and oxalates and to identify strategies to mitigate any processing issues resulting from high concentrations of nitrates and oxalates. This report provides results for a series of tests that were performed on the DM10 melter system with simulated C-106/AY-102 HLW. The tests employed simulated HLW feeds containing variable amounts of nitrates and waste organic compounds corresponding to maximum concentrations proj ected for Hanford HLW streams in order to determine their effects on glass production rate, processing characteristics, glass redox conditions, melt pool foaming, and the tendency to form secondary phases. Such melter tests provide information on key process factors such as feed processing behavior, dynamic effects during processing, processing rates, off-gas amounts and compositions, foaming control, etc., that cannot be reliably obtained from crucible melts.

  19. Melter Throughput Enhancements for High-Iron HLW

    Energy Technology Data Exchange (ETDEWEB)

    Kruger, A. A. [Department of Energy, Office of River Protection, Richland, Washington (United States); Gan, Hoa [The Catholic University of America, Washington, DC (United States); Joseph, Innocent [The Catholic University of America, Washington, DC (United States); Pegg, Ian L. [The Catholic University of America, Washington, DC (United States); Matlack, Keith S. [The Catholic University of America, Washington, DC (United States); Chaudhuri, Malabika [The Catholic University of America, Washington, DC (United States); Kot, Wing [The Catholic University of America, Washington, DC (United States)

    2012-12-26

    This report describes work performed to develop and test new glass and feed formulations in order to increase glass melting rates in high waste loading glass formulations for HLW with high concentrations of iron. Testing was designed to identify glass and melter feed formulations that optimize waste loading and waste processing rate while meeting all processing and product quality requirements. The work included preparation and characterization of crucible melts to assess melt rate using a vertical gradient furnace system and to develop new formulations with enhanced melt rate. Testing evaluated the effects of waste loading on glass properties and the maximum waste loading that can be achieved. The results from crucible-scale testing supported subsequent DuraMelter 100 (DM100) tests designed to examine the effects of enhanced glass and feed formulations on waste processing rate and product quality. The DM100 was selected as the platform for these tests due to its extensive previous use in processing rate determination for various HLW streams and glass compositions.

  20. The production of advanced glass ceramic HLW forms using cold crucible induction melter

    International Nuclear Information System (INIS)

    Rutledge, V.J.; Maio, V.

    2013-01-01

    Cold Crucible Induction Melters (CCIM) will favorably change how High-Level radioactive Waste (from nuclear fuel recovery) is treated in a near future. Unlike the existing Joule-Heated Melters (JHM) currently in operation for the glass-based immobilization of High-Level Waste (HLW), CCIM offers unique material features that will increase melt temperatures, increase throughput, increase mixing, increase loading in the waste form, lower melter foot prints, eliminate melter corrosion and lower costs. These features not only enhance the technology for producing HLW forms, but also provide advantageous attributes to the waste form by allowing more durable alternatives to glass. It is concluded that glass ceramic waste forms that are tailored to immobilize fission products of HLW can be can be made from the HLW processed with the CCIM. The advantageous higher temperatures reached with the CCIM and unachievable with JHM allows the lanthanides, alkali, alkaline earths, and molybdenum to dissolve into a molten glass. Upon controlled cooling they go into targeted crystalline phases to form a glass ceramic waste form with higher waste loadings than achievable with borosilicate glass waste forms. Natural cooling proves to be too fast for the formation of all targeted crystalline phases

  1. Chemical compatibility of HLW borosilicate glasses with actinides

    International Nuclear Information System (INIS)

    Walker, C.T.; Scheffler, K.; Riege, U.

    1978-11-01

    During liquid storage of HLLW the formation of actinide enriched sludges is being expected. Also during melting of HLW glasses an increase of top-to-bottom actinide concentrations can take place. Both effects have been studied. Besides, the vitrification of plutonium enriched wastes from Pu fuel element fabrication plants has been investigated with respect to an isolated vitrification process or a combined one with the HLLW. It is shown that the solidification of actinides from HLLW and actinide waste concentrates will set no principal problems. The leaching of actinides has been measured in salt brine at 23 0 C and 115 0 C. (orig.) [de

  2. Rheology of Savannah River site tank 42 HLW radioactive sludge

    International Nuclear Information System (INIS)

    Ha, B.C.

    1997-01-01

    Knowledge of the rheology of the radioactive sludge slurries at the Savannah River Site is necessary in order to ensure that they can be retrieved from waste tanks and processed for final disposal. At Savannah River Site, Tank 42 sludge represents on of the first HLW radioactive sludges to be vitrified in the Defense Waste Processing Facility. The rheological properties of unwashed Tank 42 sludge slurries at various solids concentrations were measured remotely in the Shielded Cells at the Savannah River Technology Center using a modified Haake Rotovisco viscometer

  3. Using process instrumentation to obviate destructive examination of canisters of HLW glass

    International Nuclear Information System (INIS)

    Kuhn, W.L.; Slate, S.C.

    1983-01-01

    An important concern of a manufacturer of packages of solidified high-level waste (HLW) is quality assurance of the waste form. The vitrification of HLW as a borosilicate glass is considered, and, based on a reference vitrification process, it is proposed that information from process instrumentation may be used to assure quality without the need for additional information obtained by destructive examining (core drilling) canisters of glass. This follows mainly because models of product performance and process behavior must be previously established in order to confidently select the desired glass formulation, and to have confidence that the process is well enough developed to be installed and operated in a nuclear facility

  4. Molecular glasses for nuclear waste encapsulation

    International Nuclear Information System (INIS)

    Ropp, R.C.

    1982-01-01

    The use of a molecular glass based upon a polymerized phosphate of aluminum (PAP), indium or gallium overcomes all of the prior objections to use of glass as a high-level nuclear waste (HLW) encapsulation agent. This HLW glass product could not be made to devitrify, dissolved all of the oxides found in calcine, including the difficultly soluble ones, did not form microcrystallites in the melt or subsequent glass-casting, and possessed a hydrolytic etching rate to boiling water even lower than that of HLW-ZBS glass. A precursor compound, M(H 2 PO 4 ) 3 , is prepared, where M is a trivalent metal selected from the group consisting of aluminum, indium and gallium. The impurity level is carefully controlled so as not to exceed 300 ppm total. The precursor crystals may be washed to remove excess phosphoric acid as desired. HLW is added to the crystals and the mixture is then heated at a controlled heating rate to induce solid state polymerization and to form a melt at 1350 degrees C in which the HLW oxides dissolve rapidly

  5. R and D programme for HLW disposal in Japan

    International Nuclear Information System (INIS)

    Tsuboya, Takao

    1997-01-01

    The Power Reactor and Nuclear Fuel Development Corporation (PNC) has been active in developing an R and D programme for high-level radioactive waste (HLW) disposal in accordance with the overall HLW management programme defined by the Atomic Energy Commission (AEC) of Japan. The aim of the R and D activities at the current stage is to provide a scientific and technical basis for the geological disposal of HLW in Japan, which is turn promotes understanding of the safety concept not only in the scientific and technical community but also by the general public. As a major milestone in the R and D programme, PNC submitted a first progress report, referred to as H3, in September 1992. H3 summarised the results of R and D activities up to March 1992 and identified priority issues for further study. The second progress report, scheduled to be submitted around 2000, and should demonstrated more rigorously and transparently the feasibility of the specified disposal concept. It should also provide input for the siting and regulatory processes, which will be set in motion after the year 2000. (author). 10 refs., 4 figs

  6. Cement encapsulation of low-level waste liquids. Final report

    International Nuclear Information System (INIS)

    Baker, M.N.; Houston, H.M.

    1999-01-01

    Pretreatment of liquid high-level radioactive waste at the West Valley Demonstration Project (WVDP) was essential to ensuring the success of high-level waste (HLW) vitrification. By chemically separating the HLW from liquid waste, it was possible to achieve a significant reduction in the volume of HLW to be vitrified. In addition, pretreatment made it possible to remove sulfates, which posed several processing problems, from the HLW before vitrification took place

  7. SNF/HLW Transfer System Description Document

    International Nuclear Information System (INIS)

    W. Holt

    2005-01-01

    The purpose of this system description document (SDD) is to establish requirements that drive the design of the spent nuclear fuel (SNF)/high-level radioactive waste (HLW) transfer system and associated bases, which will allow the design effort to proceed to license application. This SDD will be revised at strategic points as the design matures. This SDD identifies the requirements and describes the system design, as it currently exists, with emphasis on attributes of the design provided to meet the requirements. This SDD is an engineering tool for design control. Accordingly, the primary audience and users are design engineers. This SDD is part of an iterative design process. It leads the design process with regard to the flowdown of upper tier requirements onto the system. Knowledge of these requirements is essential in performing the design process. The SDD follows the design with regard to the description of the system. The description provided in this SDD reflects the current results of the design process

  8. Disposal of defense spent fuel and HLW from the Idaho Chemical Processing Plant

    International Nuclear Information System (INIS)

    Ermold, L.F.; Loo, H.H.; Klingler, R.D.; Herzog, J.D.; Knecht, D.A.

    1992-12-01

    Acid high-level radioactive waste (HLW) resulting from fuel reprocessing at the Idaho Chemical Processing Plant (ICPP) for the US Department of Energy (DOE) has been solidified to a calcine since 1963 and stored in stainless steel bins enclosed by concrete vaults. Several different types of unprocessed irradiated DOE-owned fuels are also in storage ate the ICPP. In April, 1992, DOE announced that spent fuel would no longer be reprocessed to recover enriched uranium and called for a shutdown of the reprocessing facilities at the ICPP. A new Spent Fuel and HLW Technology Development program was subsequently initiated to develop technologies for immobilizing ICPP spent fuels and HLW for disposal, in accordance with the Nuclear Waste Policy Act. The Program elements include Systems Analysis, Graphite Fuel Disposal, Other Spent Fuel Disposal, Sodium-Bearing Liquid Waste Processing, Calcine Immobilization, and Metal Recycle/Waste Minimization. This paper presents an overview of the ICPP radioactive wastes and current spent fuels, with an emphasis on the description of HLW and spent fuels requiring repository disposal

  9. Support for HLW Direct Feed - Phase 2, VSL-15R3440-1

    Energy Technology Data Exchange (ETDEWEB)

    Matlack, K. S. [The Catholic Univ. of America, Washington, DC (United States); Pegg, I. [The Catholic Univ. of America, Washington, DC (United States); Joseph, I. [EnergySolutions, Columbia, MD (United States); Kot, W. K. [The Catholic Univ. of America, Washington, DC (United States)

    2017-03-20

    This report describes work performed to develop and test new glass and feed formulations originating from a potential flow-sheet for the direct vitrification of High Level Waste (HLW) with minimal or no pretreatment. In the HLW direct feed option that is under consideration for early operations at the Hanford Tank Waste Treatment and Immobilization Plant (WTP), the pretreatment facility would be bypassed in order to support an earlier start-up of the vitrification facility. For HLW, this would mean that the ultrafiltration and caustic leaching operations that would otherwise have been performed in the pretreatment facility would either not be performed or would be replaced by an interim pretreatment function (in-tank leaching and settling, for example). These changes would likely affect glass formulations and waste loadings and have impacts on the downstream vitrification operations. Modification of the pretreatment process may result in: (i) Higher aluminum contents if caustic leaching is not performed; (ii) Higher chromium contents if oxidative leaching is not performed; (iii) A higher fraction of supernate in the HLW feed resulting from the lower efficiency of in-tank washing; and (iv) A higher water content due to the likely lower effectiveness of in-tank settling compared to ultrafiltration. The HLW direct feed option has also been proposed as a potential route for treating HLW streams that contain the highest concentrations of fast-settling plutoniumcontaining particles, thereby avoiding some of the potential issues associated with such particles in the WTP Pretreatment facility [1]. In response, the work presented herein focuses on the impacts of increased supernate and water content on wastes from one of the candidate source tanks for the direct feed option that is high in plutonium.

  10. Intermediate Level Waste Research Programme: Progress report for 1986/87 from the Waste Treatment and Disposal Working Party covering Joint Funded Work

    International Nuclear Information System (INIS)

    Claxton, D.G.S.A.

    1988-06-01

    The Waste Treatment and Disposal Working Party (WTDWP) covered the areas of: ILW Product Evaluation; ILW and HLW Disposal Studies, and ILW and HLW Quality Checking. The objectives of the programme were to evaluate potential waste products arising from the treatment of ILW/HLW, and to develop appropriate techniques which could be used to check the quality of the finished waste product. (author)

  11. Evaluation of a new pulping technology for pre-treating source-separated organic household waste prior to anaerobic digestion

    DEFF Research Database (Denmark)

    Naroznova, Irina; Møller, Jacob; Larsen, Bjarne

    2016-01-01

    A new technology for pre-treating source-separated organic household waste prior to anaerobic digestion was assessed, and its performance was compared to existing alternative pre-treatment technologies. This pre-treatment technology is based on waste pulping with water, using a specially developed...... screw mechanism. The pre-treatment technology rejects more than 95% (wet weight) of non-biodegradable impurities in waste collected from households and generates biopulp ready for anaerobic digestion. Overall, 84-99% of biodegradable material (on a dry weight basis) in the waste was recovered...... in the biopulp. The biochemical methane potential for the biopulp was 469±7mL CH4/g ash-free mass. Moreover, all Danish and European Union requirements regarding the content of hazardous substances in biomass intended for land application were fulfilled. Compared to other pre-treatment alternatives, the screw...

  12. Technetium Chemistry in High-Level Waste

    International Nuclear Information System (INIS)

    Hess, Nancy J.

    2006-01-01

    Tc contamination is found within the DOE complex at those sites whose mission involved extraction of plutonium from irradiated uranium fuel or isotopic enrichment of uranium. At the Hanford Site, chemical separations and extraction processes generated large amounts of high level and transuranic wastes that are currently stored in underground tanks. The waste from these extraction processes is currently stored in underground High Level Waste (HLW) tanks. However, the chemistry of the HLW in any given tank is greatly complicated by repeated efforts to reduce volume and recover isotopes. These processes ultimately resulted in mixing of waste streams from different processes. As a result, the chemistry and the fate of Tc in HLW tanks are not well understood. This lack of understanding has been made evident in the failed efforts to leach Tc from sludge and to remove Tc from supernatants prior to immobilization. Although recent interest in Tc chemistry has shifted from pretreatment chemistry to waste residuals, both needs are served by a fundamental understanding of Tc chemistry

  13. Studies on the immobilization of simulated HLW in NaTi2(PO4)3 (NTP) matrix

    International Nuclear Information System (INIS)

    Raja Madhavan, R.; Govindan Kutty, K.V.; Gandhi, A.S.

    2015-01-01

    Immobilization of high level nuclear waste (HLW) is a big challenge faced by the nuclear industry today. The HLW has to be contained and isolated from the biosphere for geological timescales. NZP family of compounds is very versatile monophasic hosts for HLW immobilization. Their crystal structure can accommodate nearly all the cations known to be present in HLW due to its open structure with voids of different size. In the present study a systematic investigation on NaTi 2 (PO 4 ) 3 belonging to the NZP family; as a potential host for HLW immobilization was carried out. A simulated HLW expected from Fast Breeder Test Reactor, India (FBTR) (150Gwd/T burnup, 1 year cooling) was used. Simulated NTP waste forms with 5, 10, 15 wt. % waste loading were prepared by employing a wet chemical method and characterized. Single phase simulated NTP waste forms with up to 5 wt.% waste loading could be prepared for samples sintered in air and above 5 wt.% waste loading, monazite phase is observed as a minor secondary phase. It was found that when sintering is done in Ar/10%H 2 , NTP matrix accepts up to 10 wt.% waste loading without formation of any second phase. From the SEM studies, it was observed that samples sintered in air as well as Ar/10%H 2 palladium segregated as a metal phase and uniformly distributed throughout the waste matrix. The elemental mapping revealed retention of some of the fission products like Ru, Mo, Cs that are volatile during sintering above 1173 K and are homogenously distributed in the matrix. (author)

  14. Development of thermal analysis method for the near field of HLW repository using ABAQUS

    Energy Technology Data Exchange (ETDEWEB)

    Kuh, Jung Eui; Kang, Chul Hyung; Park, Jeong Hwa [Korea Atomic Energy Research Institute, Taejon (Korea)

    1998-10-01

    An appropriate tool is needed to evaluate the thermo-mechanical stability of high level radioactive waste (HLW) repository. In this report a thermal analysis methodology for the near field of HLW repository is developed to use ABAQUS which is one of the multi purpose FEM code and has been used for many engineering area. The main contents of this methodology development are the structural and material modelling to simulate a repository, setup of side conditions, e.g., boundary and load conditions, and initial conditions, and the procedure to selection proper material parameters. In addition to these, the interface programs for effective production of input data and effective change of model size for sensitivity analysis for disposal concept development are developed. The results of this work will be apply to evaluate the thermal stability and to use as main input data for mechanical analysis of HLW repository. (author). 20 refs., 15 figs., 5 tabs.

  15. Applicability of thermodynamic database of radioactive elements developed for the Japanese performance assessment of HLW repository

    International Nuclear Information System (INIS)

    Yui, Mikazu; Shibata, Masahiro; Rai, Dhanpat; Ochs, Michael

    2003-01-01

    In 1999 Japan Nuclear Cycle Development Institute (JNC) published a second progress report (also known as H12 report) on high-level radioactive waste (HLW) disposal in Japan (JNC 1999). This report helped to develop confidence in the selected HLW disposal system and to establish the implementation body in 2000 for the disposal of HLW. JNC developed an in-house thermodynamic database for radioactive elements for performance analysis of the engineered barrier system (EBS) and the geosphere for H12 report. This paper briefly presents the status of the JNC's thermodynamic database and its applicability to perform realistic analyses of the solubilities of radioactive elements, evolution of solubility-limiting solid phases, predictions of the redox state of Pu in the neutral pH range under reducing conditions, and to estimate solubilities of radioactive elements in cementitious conditions. (author)

  16. The Results of HLW Processing Using Zirconium Salt of Dibutyl phosphoric Acid in Hot Cell

    Energy Technology Data Exchange (ETDEWEB)

    Fedorov, Yu.S.; Zilberman, B.Ya.; Shmidt, O.V. [Khlopin Radium Institute, 2nd Murinsky Ave., 28, Saint-Petersburg, 194021 (Russian Federation)

    2008-07-01

    Zirconium salt of dibutyl phosphoric acid (ZS HDBP), is an effective solvent for liquid HLW and ILW (high and intermediate level wastes) processing with radionuclide partitioning into different groups for further immobilization according to radiotoxicity. The rig trials in mixer-settles in hot cells were carried out using 30 L of real HLW containing transplutonium (TPE), rare earths (RE), Sr and Cs in 2 mol/L HNO{sub 3}, characterized by total specific activity 520 MBk/L. The recovery factor for TPE and RE was as high as 10{sup 4}, but only 10 for Sr. Purification factor of TPE and RE from Cs and Sr was 10{sup 4}, and that of Sr from TPE and Cs was 10{sup 3}. Almost all Cs was localized in the second cycle raffinate. So Zr salt of HDBP can be used in HLW processing with radionuclide partitioning with respect to the categories of radiotoxicity. (authors)

  17. HLW Melter Control Strategy Without Visual Feedback VSL-12R2500-1 Rev 0

    Energy Technology Data Exchange (ETDEWEB)

    Kruger, A A. [Department of Energy, Office of River Protection, Richland, Washington (United States); Joseph, Innocent [The Catholic University of America, Washington, DC (United States); Matlack, Keith S. [The Catholic University of America, Washington, DC (United States); Callow, Richard A. [The Catholic University of America, Washington, DC (United States); Abramowitz, Howard [The Catholic University of America, Washington, DC (United States); Pegg, Ian L. [The Catholic University of America, Washington, DC (United States); Brandys, Marek [The Catholic University of America, Washington, DC (United States); Kot, Wing K. [The Catholic University of America, Washington, DC (United States)

    2012-11-13

    Plans for the treatment of high level waste (HL W) at the Hanford Tank Waste Treatment and Immobilization Plant (WTP) are based upon the inventory of the tank wastes, the anticipated performance of the pretreatment processes, and current understanding of the capability of the borosilicate glass waste form [I]. The WTP HLW melter design, unlike earlier DOE melter designs, incorporates an active glass bubbler system. The bubblers create active glass pool convection and thereby improve heat and mass transfer and increase glass melting rates. The WTP HLW melter has a glass surface area of 3.75 m{sup 2} and depth of ~ 1.1 m. The two melters in the HLW facility together are designed to produce up to 7.5 MT of glass per day at 100% availability. Further increases in HL W waste processing rates can potentially be achieved by increasing the melter operating temperature above 1150°C and by increasing the waste loading in the glass product. Increasing the waste loading also has the added benefit of decreasing the number of canisters for storage.

  18. HLW Melter Control Strategy Without Visual Feedback VSL-12R2500-1 Rev 0

    International Nuclear Information System (INIS)

    Kruger, A A.; Joseph, Innocent; Matlack, Keith S.; Callow, Richard A.; Abramowitz, Howard; Pegg, Ian L.; Brandys, Marek; Kot, Wing K.

    2012-01-01

    Plans for the treatment of high level waste (HL W) at the Hanford Tank Waste Treatment and Immobilization Plant (WTP) are based upon the inventory of the tank wastes, the anticipated performance of the pretreatment processes, and current understanding of the capability of the borosilicate glass waste form [I]. The WTP HLW melter design, unlike earlier DOE melter designs, incorporates an active glass bubbler system. The bubblers create active glass pool convection and thereby improve heat and mass transfer and increase glass melting rates. The WTP HLW melter has a glass surface area of 3.75 m 2 and depth of ∼ 1.1 m. The two melters in the HLW facility together are designed to produce up to 7.5 MT of glass per day at 100% availability. Further increases in HL W waste processing rates can potentially be achieved by increasing the melter operating temperature above 1150°C and by increasing the waste loading in the glass product. Increasing the waste loading also has the added benefit of decreasing the number of canisters for storage

  19. Solidification as low cost technology prior to land filling of industrial hazardous waste sludge.

    Science.gov (United States)

    El-Sebaie, O; Ahmed, M; Ramadan, M

    2000-01-01

    The aim of this study is to stabilize and solidify two different treated industrial hazardous waste sludges, which were selected from factories situated close to Alexandria. They were selected to ensure their safe transportation and landfill disposal by reducing their potential leaching of hazardous elements, which represent significant threat to the environment, especially the quality of underground water. The selected waste sludges have been characterized. Ordinary Portland Cement (OPC), Cement Kiln Dust (CKD) from Alexandria Portland Cement Company, and Calcium Sulphate as a by-product from the dye industry were used as potential solidification additives to treat the selected treated waste sludges from tanning and dyes industry. Waste sludges as well as the solidified wastes have been leach-tested, using the General Acid Neutralization Capacity (GANC) procedure. Concentration of concerning metals in the leachates was determined to assess changes in the mobility of major contaminants. The treated tannery waste sludge has an acid neutralization capacity much higher than that of the treated dyes waste sludge. Experiment results demonstrated the industrial waste sludge solidification mix designs, and presented the reduction of contaminant leaching from two types of waste sludges. The main advantages of solidification are that it is simple and low cost processing which includes readily available low cost solidification additives that will convert industrial hazardous waste sludges into inert materials.

  20. Partitioning of actinide from simulated high level wastes arising from reprocessing of PHWR fuels: counter current extraction studies using CMPO

    International Nuclear Information System (INIS)

    Deshingkar, D.S.; Chitnis, R.R.; Wattal, P.K.; Theyyunni, T.K.; Nair, M.K.T.; Ramanujam, A.; Dhami, P.S.; Gopalakrishnan, V.; Rao, M.K.; Mathur, J.N.; Murali, M.S.; Iyer, R.H.; Badheka, L.P.; Banerji, A.

    1994-01-01

    High level wastes (HLW) arising from reprocessing of pressurised heavy water reactor (PHWR) fuels contain actinides like neptunium, americium and cerium which are not extracted in the Purex process. They also contain small quantities of uranium and plutonium in addition to fission products. Removal of these actinides prior to vitrification of HLW can effectively reduce the active surveillance period of final waste form. Counter current studies using indigenously synthesised octyl (phenyl)-N, N-diisobutylcarbamoylmethylphosphine oxide (CMPO) were taken up as a follow-up of successful runs with simulated sulphate bearing low acid HLW solutions. The simulated HLW arising from reprocessing of PHWR fuel was prepared based on presumed burnup of 6500 MWd/Te of uranium, 3 years cooling period and 800 litres of waste generation per tonne of fuel reprocessed. The alpha activity of the HLW raffinate after extraction with the CMPO-TBP mixture could be brought down to near background level. (author). 13 refs., 2 tabs., 12 figs

  1. Partitioning of actinide from simulated high level wastes arising from reprocessing of PHWR fuels: counter current extraction studies using CMPO

    Energy Technology Data Exchange (ETDEWEB)

    Deshingkar, D S; Chitnis, R R; Wattal, P K; Theyyunni, T K; Nair, M K.T. [Bhabha Atomic Research Centre, Bombay (India). Process Engineering and Systems Development Div.; Ramanujam, A; Dhami, P S; Gopalakrishnan, V; Rao, M K [Bhabha Atomic Research Centre, Bombay (India). Fuel Reprocessing Group; Mathur, J N; Murali, M S; Iyer, R H [Bhabha Atomic Research Centre, Bombay (India). Radiochemistry Div.; Badheka, L P; Banerji, A [Bhabha Atomic Research Centre, Bombay (India). Bio-organic Div.

    1994-12-31

    High level wastes (HLW) arising from reprocessing of pressurised heavy water reactor (PHWR) fuels contain actinides like neptunium, americium and cerium which are not extracted in the Purex process. They also contain small quantities of uranium and plutonium in addition to fission products. Removal of these actinides prior to vitrification of HLW can effectively reduce the active surveillance period of final waste form. Counter current studies using indigenously synthesised octyl (phenyl)-N, N-diisobutylcarbamoylmethylphosphine oxide (CMPO) were taken up as a follow-up of successful runs with simulated sulphate bearing low acid HLW solutions. The simulated HLW arising from reprocessing of PHWR fuel was prepared based on presumed burnup of 6500 MWd/Te of uranium, 3 years cooling period and 800 litres of waste generation per tonne of fuel reprocessed. The alpha activity of the HLW raffinate after extraction with the CMPO-TBP mixture could be brought down to near background level. (author). 13 refs., 2 tabs., 12 figs.

  2. Historical fuel reprocessing and HLW management in Idaho

    International Nuclear Information System (INIS)

    Knecht, D.A.; Staiger, M.D.; Christian, J.D.

    1997-01-01

    This article review some of the key decision points in the historical development of spent fuel reprocessing and waste management practices at the Idaho Chemical Processing Plant that have helped ICPP to successfully accomplish its mission safely and with minimal impact on the environment. Topics include ICPP reprocessing development; batch aluminum-uranium dissolution; continuous aluminum uranium dissolution; batch zirconium dissolution; batch stainless steel dissolution; semicontinuous zirconium dissolution with soluble poison; electrolytic dissolution of stainless steel-clad fuel; graphite-based rover fuel processing; fluorinel fuel processing; ICPP waste management consideration and design decisions; calcination technology development; ICPP calcination demonstration and hot operations; NWCF design, construction, and operation; HLW immobilization technology development. 80 refs., 4 figs

  3. Final Report - Crystal Settling, Redox, and High Temperature Properties of ORP HLW and LAW Glasses, VSL-09R1510-1, Rev. 0, dated 6/18/09

    Energy Technology Data Exchange (ETDEWEB)

    Kruger, Albert A.; Wang, C.; Gan, H.; Pegg, I. L.; Chaudhuri, M.; Kot, W.; Feng, Z.; Viragh, C.; McKeown, D. A.; Joseph, I.; Muller, I. S.; Cecil, R.; Zhao, W.

    2013-11-13

    The radioactive tank waste treatment programs at the U. S. Department of Energy (DOE) have featured joule heated ceramic melter technology for the vitrification of high level waste (HLW). The Hanford Tank Waste Treatment and Immobilization Plant (WTP) employs this same basic technology not only for the vitrification of HLW streams but also for the vitrification of Low Activity Waste (LAW) streams. Because of the much greater throughput rates required of the WTP as compared to the vitrification facilities at the West Valley Demonstration Project (WVDP) or the Defense Waste Processing Facility (DWPF), the WTP employs advanced joule heated melters with forced mixing of the glass pool (bubblers) to improve heat and mass transport and increase melting rates. However, for both HLW and LAW treatment, the ability to increase waste loadings offers the potential to significantly reduce the amount of glass that must be produced and disposed and, therefore, the overall project costs. This report presents the results from a study to investigate several glass property issues related to WTP HLW and LAW vitrification: crystal formation and settling in selected HLW glasses; redox behavior of vanadium and chromium in selected LAW glasses; and key high temperature thermal properties of representative HLW and LAW glasses. The work was conducted according to Test Plans that were prepared for the HLW and LAW scope, respectively. One part of this work thus addresses some of the possible detrimental effects due to considerably higher crystal content in waste glass melts and, in particular, the impact of high crystal contents on the flow property of the glass melt and the settling rate of representative crystalline phases in an environment similar to that of an idling glass melter. Characterization of vanadium redox shifts in representative WTP LAW glasses is the second focal point of this work. The third part of this work focused on key high temperature thermal properties of

  4. Comparing technical concepts for disposal of Belgian vitrified HLW

    International Nuclear Information System (INIS)

    Bel, J.; Bock, C. de; Boyazis, J.P.

    2004-01-01

    The choice of a suitable repository design for different categories of radioactive waste is an important element in the decisional process that will eventually lead to the waste disposal in geological ground layers during the next decades. Most countries are in the process of elaborating different technical solutions for their EBS '. Considering possible design alternatives offers more flexibility to cope with remaining uncertainties and allows optimizing some elements of the EBS in the future. However, it is not feasible to continue carrying out detailed studies for a large number of alternative design options. At different stages in the decisional process, choices, even preliminary ones, have to be made. Although the impact of different stakeholders (regulator, waste agencies, waste producers, research centers,...) in making these design choices can differ from one country to another, the choices should be based on sound, objective, clear and unambiguous justification grounds. Moreover, the arguments should be carefully reported and easy to understand by the decision makers. ONDRAF/NIRAS recently elaborated three alternative designs for the disposal of vitrified HLW. These three designs are briefly described in the next section. A first series of technological studies pointed out that the three options are feasible. It would however be unreasonable to continue R and D work on all three alternatives in parallel. It is therefore planned to make a preliminary choice of a reference design for the vitrified HLW in 2003. This selection will depend on the way the alternative design options can be evaluated against a number of criteria, mainly derived from general repository design requirements. The technique of multi-criteria analysis (MCA) will be applied as a tool for making the optimum selection, considering all selection criteria and considering different strategic approaches. This paper describes the used methodology. The decision on the actual selection will be

  5. Waste treatment

    International Nuclear Information System (INIS)

    Hutson, G.V.

    1996-01-01

    Numerous types of waste are produced by the nuclear industry ranging from high-level radioactive and heat-generating, HLW, to very low-level, LLW and usually very bulky wastes. These may be in solid, liquid or gaseous phases and require different treatments. Waste management practices have evolved within commercial and environmental constraints resulting in considerable reduction in discharges. (UK)

  6. Biased and inadequate citation of prior research in reports of cardiovascular trials is a continuing source of waste in research.

    Science.gov (United States)

    Sawin, Veronica I; Robinson, Karen A

    2016-01-01

    We assessed citation of prior research over time and the association of citation with the agreement of results between the trial being reported and the prior trial. Groups of pharmacologic trials in cardiovascular disease were created using meta-analyses, and we assessed citation within these groups. We calculated the proportion of prior trials cited, the proportion of study participants captured in citations, and agreement of results between citing and cited trials. Analysis included 86 meta-analyses with 580 trials published between 1982 and 2011. Reports of trials cited 25% (median; 95% confidence interval [CI], 23-27%) of prior trials, capturing 31% (95% CI, 25-36%) of trial participants. Neither measure differed by publication of the citing trial before vs. after 2005. Prior trials with results that agreed with the reports of trials (supportive trials) were significantly more likely to be cited than nonsupportive trials (relative risk 1.45; 95% CI, 1.30-1.61, P < 0.001). Selective undercitation of prior research continues; three quarters of existing evidence is ignored. This source of waste may result in unnecessary, unethical, and unscientific studies. Copyright © 2016 Elsevier Inc. All rights reserved.

  7. THOREX processing and zeolite transfer for high-level waste stream processing blending

    International Nuclear Information System (INIS)

    Kelly, S. Jr.; Meess, D.C.

    1997-07-01

    The West Valley Demonstration Project (WVDP) completed the pretreatment of the high-level radioactive waste (HLW) prior to the start of waste vitrification. The HLW originated form the two million liters of plutonium/uranium extraction (PUREX) and thorium extraction (THOREX) wastes remaining from Nuclear Fuel Services' (NFS) commercial nuclear fuel reprocessing operations at the Western New York Nuclear Service Center (WNYNSC) from 1966 to 1972. The pretreatment process removed cesium as well as other radionuclides from the liquid wastes and captured these radioactive materials onto silica-based molecular sieves (zeolites). The decontaminated salt solutions were volume-reduced and then mixed with portland cement and other admixtures. Nineteen thousand eight hundred and seventy-seven 270-liter square drums were filled with the cement-wastes produced from the pretreatment process. These drums are being stored in a shielded facility on the site until their final disposition is determined. Over 6.4 million liters of liquid HLW were processed through the pretreatment system. PUREX supernatant was processed first, followed by two PUREX sludge wash solutions. A third wash of PUREX/THOREX sludge was then processed after the neutralized THOREX waste was mixed with the PUREX waste. Approximately 6.6 million curies of radioactive cesium-137 (Cs-137) in the HLW liquid were removed and retained on 65,300 kg of zeolites. With pretreatment complete, the zeolite material has been mobilized, size-reduced (ground), and blended with the PUREX and THOREX sludges in a single feed tank that will supply the HLW slurry to the Vitrification Facility

  8. Key Factors to Determine the Borehole Spacing in a Deep Borehole Disposal for HLW

    International Nuclear Information System (INIS)

    Lee, Jongyoul; Choi, Heuijoo; Lee, Minsoo; Kim, Geonyoung; Kim, Kyeongsoo

    2015-01-01

    Deep fluids also resist vertical movement because they are density stratified and reducing conditions will sharply limit solubility of most dose critical radionuclides at the depth. Finally, high ionic strengths of deep fluids will prevent colloidal transport. Therefore, as an alternative disposal concept, i.e., deep borehole disposal technology is under consideration in number of countries in terms of its outstanding safety and cost effectiveness. In this paper, the general concept for deep borehole disposal of spent fuels or high level radioactive wastes which has been developed by some countries according to the rapid advance in the development of drilling technology, as an alternative method to the deep geological disposal method, was reviewed. After then an analysis on key factors for the distance between boreholes for the disposal of HLW was carried out. In this paper, the general concept for deep borehole disposal of spent fuels or HLW wastes, as an alternative method to the deep geological disposal method, were reviewed. After then an analysis on key factors for the determining the distance between boreholes for the disposal of HLW was carried out. These results can be used for the development of the HLW deep borehole disposal system

  9. Key Factors to Determine the Borehole Spacing in a Deep Borehole Disposal for HLW

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Jongyoul; Choi, Heuijoo; Lee, Minsoo; Kim, Geonyoung; Kim, Kyeongsoo [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2015-05-15

    Deep fluids also resist vertical movement because they are density stratified and reducing conditions will sharply limit solubility of most dose critical radionuclides at the depth. Finally, high ionic strengths of deep fluids will prevent colloidal transport. Therefore, as an alternative disposal concept, i.e., deep borehole disposal technology is under consideration in number of countries in terms of its outstanding safety and cost effectiveness. In this paper, the general concept for deep borehole disposal of spent fuels or high level radioactive wastes which has been developed by some countries according to the rapid advance in the development of drilling technology, as an alternative method to the deep geological disposal method, was reviewed. After then an analysis on key factors for the distance between boreholes for the disposal of HLW was carried out. In this paper, the general concept for deep borehole disposal of spent fuels or HLW wastes, as an alternative method to the deep geological disposal method, were reviewed. After then an analysis on key factors for the determining the distance between boreholes for the disposal of HLW was carried out. These results can be used for the development of the HLW deep borehole disposal system.

  10. Development of a Korean Reference disposal System(A-KRS) for the HLW from Advanced Fuel Cycles

    International Nuclear Information System (INIS)

    Choi, Heui Joo; Choi, J. W.; Lee, J. Y.

    2010-04-01

    A database program for analyzing the characteristics of spent fuels was developed, and A-SOURCE program for characterizing the source term of HLW from advanced fuel cycles. A new technique for developing a copper canister by introducing a cold spray technique was developed, which could reduce the amount of copper. Also, to enhance the performance of A-KRS, two kinds of properties, thermal performance and iodine adsorption, were studied successfully. A complex geological disposal system which can accommodate all the HLW (CANDU and HANARO spent fuels, HLW from pyro-processing of PWR spent fuels, decommissioning wastes) was developed, and a conceptual design was carried out. Operational safety assessment system was constructed for the long-term management of A-KRS. Three representative accidental cases were analyzed, and the probabilistic safety assessment was adopted as a methodology for the safety evaluation of A-KRS operation. A national program was proposed to support the HLW national policy on the HLW management. A roadmap for HLW management was proposed based on the optimum timing of disposal

  11. Defense High Level Waste Disposal Container System Description Document

    International Nuclear Information System (INIS)

    Pettit, N. E.

    2001-01-01

    The Defense High Level Waste Disposal Container System supports the confinement and isolation of waste within the Engineered Barrier System of the Monitored Geologic Repository (MGR). Disposal containers are loaded and sealed in the surface waste handling facilities, transferred to the underground through the accesses using a rail mounted transporter, and emplaced in emplacement drifts. The defense high level waste (HLW) disposal container provides long-term confinement of the commercial HLW and defense HLW (including immobilized plutonium waste forms [IPWF]) placed within disposable canisters, and withstands the loading, transfer, emplacement, and retrieval loads and environments. US Department of Energy (DOE)-owned spent nuclear fuel (SNF) in disposable canisters may also be placed in a defense HLW disposal container along with commercial HLW waste forms, which is known as co-disposal. The Defense High Level Waste Disposal Container System provides containment of waste for a designated period of time, and limits radionuclide release. The disposal container/waste package maintains the waste in a designated configuration, withstands maximum handling and rockfall loads, limits the individual canister temperatures after emplacement, resists corrosion in the expected handling and repository environments, and provides containment of waste in the event of an accident. Defense HLW disposal containers for HLW disposal will hold up to five HLW canisters. Defense HLW disposal containers for co-disposal will hold up to five HLW canisters arranged in a ring and one DOE SNF canister inserted in the center and/or one or more DOE SNF canisters displacing a HLW canister in the ring. Defense HLW disposal containers also will hold two Multi-Canister Overpacks (MCOs) and two HLW canisters in one disposal container. The disposal container will include outer and inner cylinders, outer and inner cylinder lids, and may include a canister guide. An exterior label will provide a means by

  12. Separation of palladium from high-level waste using metal ferro cyanide loaded resins

    International Nuclear Information System (INIS)

    Valsala, T.P.; Joseph, Annie; Yeotikar, R.G.

    2005-01-01

    High-level waste (HLW) is generated during reprocessing of spent fuel. HLW contains corrosion products, unextracted actinides, process chemicals and fission products. A recent trend is there to consider waste as a source of wealth. Among the fission products separation and recovery of platinum group metals have gained great attention. HLW is a good source of palladium of the platinum group metal. The present study shows the feasibility of ion exchange separation of Pd from HLW. (author)

  13. Final Report - Melt Rate Enhancement for High Aluminum HLW Glass Formulation, VSL-08R1360-1, Rev. 0, dated 12/19/08

    Energy Technology Data Exchange (ETDEWEB)

    Kruger, Albert A.; Pegg, I. L.; Chaudhuri, M.; Gong, W.; Gan, H.; Matlack, K. S.; Bardakci, T.; Kot, W.

    2013-11-13

    The principal objective of the work reported here was to develop and identify HLW glass compositions that maximize waste processing rates for the aluminum limted waste composition specified by ORP while maintaining high waste loadings and acceptable glass properties. This was accomplished through a combination of crucible-scale tests, confirmation tests on the DM100 melter system, and demonstration at pilot scale (DM1200). The DM100-BL unit was selected for these tests since it was used previously with the HLW waste streams evaluated in this study, was used for tests on HLW glass compositions to support subsequent tests on the HLW Pilot Melter, conduct tests to determine the effect of various glass properties (viscosity and conductivity) and oxide concentrations on glass production rates with HLW feed streams, and to assess the volatility of cesium and technetium during the vitrification of an HLW AZ-102 composition. The same melter was selected for the present tests in order to maintain comparisons between the previously collected data. These tests provide information on melter processing characteristics and off-gas data, including formation of secondary phases and partitioning. Once DM100 tests were completed, one of the compositions was selected for further testing on the DM1200; the DM1200 system has been used for processing a variety of simulated Hanford waste streams. Tests on the larger melter provide processing data at one third of the scale of the actual WTP HLW melter and, therefore, provide a more accurate and reliable assessment of production rates and potential processing issues. The work focused on maximizing waste processing rates for high aluminum HLW compositions. In view of the diversity of forms of aluminum in the Hanford tanks, tests were also conducted on the DM100 to determine the effect of changes in the form of aluminum on feed properties and production rate. In addition, the work evaluated the effect on production rate of modest increases

  14. HLW Feed Delivery AZ101 Batch Transfer to the Private Contractor Transfer and Mixing Process Improvements [Initial Release at Rev 2

    Energy Technology Data Exchange (ETDEWEB)

    DUNCAN, G.P.

    2000-02-28

    The primary purpose of this business case is to provide Operations and Maintenance with a detailed transfer process review for the first High Level Waste (HLW) feed delivery to the Privatization Contractor (PC), AZ-101 batch transfer to PC. The Team was chartered to identify improvements that could be implemented in the field. A significant penalty can be invoked for not providing the quality, quantity, or timely delivery of HLW feed to the PC.

  15. Design options for HLW repository operation technology. (4) Shotclay technique for seamless construction of EBS

    International Nuclear Information System (INIS)

    Kobayashi, Ichizo; Fujisawa, Soh; Nakajima, Makoto; Toida, Masaru; Nakashima, Hitoshi; Asano, Hidekazu

    2011-01-01

    The shotclay method is construction method of the high density bentonite engineered barrier by spraying method. Using this method, the dry density of 1.6 Mg/m 3 , which was considered impossible with the spray method, is achieved. In this study, the applicability of the shotclay method to HLW bentonite-engineered barriers was confirmed experimentally. In the tests, an actual scale vertical-type HLW bentonite-engineered barrier was constructed. This was a bentonite-engineered barrier with a diameter of 2.22 m and a height of 3.13 m. The material used was bentonite with 30% silica sand, and water content was adjusted by mixing chilled bentonite with powdered ice before thawing. Work progress was 11.2 m 3 and the weight was 21.7 Mg. The dry density of the entire buffer was 1.62 Mg/m 3 , and construction time was approximately 8 hours per unit. After the formworks were removed, the core and block of the actual scale HLW bentonite-engineered barrier were sampled to confirm homogeneity. As a result, homogeneity was confirmed, and no gaps were observed between the formwork and the buffer material and between the simulated waste and the buffer material. The applicability to HLW of the shotclay method has been confirmed through this examination. (author)

  16. Viability for controlling long-term leaching of radionuclides from HLW glass by amorphous silica additives

    International Nuclear Information System (INIS)

    Inagaki, Y.; Uehara, S.

    2004-01-01

    Dissolution and deterioration experiments in coexistence system of amorphous silica and vitrified wastes have been executed in order to evaluating the effects of amorphous silica addition to high level radioactive vitrified waste (HLW glass) on suppression of nuclide leaching. Geo-chemical reaction mechanism among the vitrified waste, the amorphous silica and water was also evaluated. Dissolution of the silica network was suppressed by addition of the amorphous silica. However, the leaching of soluble nuclides like B proceeded depending on the hydration deterioration reaction. (A. Hishinuma)

  17. The senate working party on HLW management in Spain - historical perspective

    International Nuclear Information System (INIS)

    Lang-Lenton, J.

    2007-01-01

    As the first case history Jorge Lang Lenton, Corporate Director of ENRESA, recounted the failed attempt to establish an underground disposal facility for HLW. The site selection process, which was planned by ENRESA in the 1980's, was aimed at finding the 'technically best' site. The process was conducted by technical experts without public involvement. When 40 candidate siting areas were identified in the mid-1990's, information leaked out, creating vigorous public opposition in all of these locations. In 1998 the siting process was halted. The Senate proposed to continue R and D on geological disposal and on P and T, to reduce waste production, and to develop an energy policy that relies more on renewable energy sources. They also suggested that public participation be promoted. The 5. General Radioactive Waste Management Plan, which was developed in 1999, took these proposals into consideration. Regarding underground disposal, the government postponed any decision until 2010. At the end of 2004 a decision was made by Parliament to establish a centralized storage facility for HLW. Mr. Lang-Lenton highlighted the main lessons of the failed siting attempt. First, it has to be acknowledged that HLW management is a societal rather than a technical problem. Second, for any radioactive waste management facility a socially feasible rather than a technically optimal site should be selected, i.e., 'the best site is the possible site'. Finally, transparency and openness are needed for building confidence in the decision-making process. (author)

  18. Immobilization of defense high-level waste: an assessment of technological strategies and potential regulatory goals. Volume II

    International Nuclear Information System (INIS)

    1979-06-01

    This volume contains the following appendices: selected immobilization processes, directory of selected European organizations involved in HLW management, U.S. high-level waste inventories, and selected European HLW program

  19. Policy and practice of radioactive waste management in India

    International Nuclear Information System (INIS)

    Sunder Radzhan, N.S.

    1986-01-01

    The Indian program on radioactive waste management comprising two main variants: engineering subsurface repositories for low- and intermediate-level wastes and deep geological formations for alpha-bearing and high-level wastes (HLW) is presented. One of the problems deals with the matrices with improved properties for HLW inclusion. The other aspect concerns development of management with alpha-emitting radionuclides in HLW. Special attention is paid to the problems of safety

  20. Corrosion of copper containers prior to saturation of a nuclear fuel waste disposal vault

    International Nuclear Information System (INIS)

    King, F.; Kolar, M.

    1997-12-01

    The buffer material surrounding the containers in a Canadian nuclear fuel waste disposal vault will partially desiccate as a result of the elevated temperature at the container surface. This will lead to a period of corrosion in a moist air atmosphere. Corrosion will either take the form of slow oxidation if the container surface remains dry or aqueous electrochemical corrosion if the surface is wetted by a thin liquid film. The relevant literature is reviewed, from which it is concluded that corrosion should be uniform in nature, except if the surface is wetted, in which case localized corrosion is a possibility. A quantitative analysis of the extent and rate of uniform corrosion during the unsaturated period is presented. Two bounding cases are considered: first, the case of slow oxidation in moist air following either logarithmic or parabolic oxide-growth kinetics and, second, the case of electrochemically based corrosion occurring in a thin liquid film uninhibited by the growth of corrosion products. (author)

  1. Final Report - Testing of Optimized Bubbler Configuration for HLW Melter VSL-13R2950-1, Rev. 0, dated 6/12/2013

    Energy Technology Data Exchange (ETDEWEB)

    Kruger, Albert A.; Pegg, I. L.; Callow, R. A.; Joseph, I.; Matlack, K. S.; Kot, W. K.

    2013-11-13

    The principal objective of this work was to determine the glass production rate increase and ancillary effects of adding more bubbler outlets to the current WTP HLW melter baseline. This was accomplished through testing on the HLW Pilot Melter (DM1200) at VSL. The DM1200 unit was selected for these tests since it was used previously with several HLW waste streams including the four tank wastes proposed for initial processing at Hanford. This melter system was also used for the development and optimization of the present baseline WTP HLW bubbler configuration for the WTP HLW melter, as well as for MACT testing for both HLW and LAW. Specific objectives of these tests were to: Conduct DM1200 melter testing with the baseline WTP bubbling configuration and as augmented with additional bubblers. Conduct DM1200 melter testing to differentiate the effects of total bubbler air flow and bubbler distribution on glass production rate and cold cap formation. Collect melter operating data including processing rate, temperatures at a variety of locations within the melter plenum space, melt pool temperature, glass melt density, and melter pressure with the baseline WTP bubbling configuration and as augmented with additional bubblers. Collect melter exhaust samples to compare particulate carryover for different bubbler configurations. Analyze all collected data to determine the effects of adding more bubblers to the WTP HLW melter to inform decisions regarding future lid re-designs. The work used a high aluminum HLW stream composition defined by ORP, for which an appropriate simulant and high waste loading glass formulation were developed and have been previously processed on the DM1200.

  2. Public Perspectives in the Japanese HLW Disposal Program

    Energy Technology Data Exchange (ETDEWEB)

    Inatsugu, Shigefumi; Takeuchi, Mitsuo; Kato, Toshiaki [Nuclear Waste Management Organization of Japan (NUNIO), Tokyo (Japan)

    2006-09-15

    Following legislation entitled the 'Specified Radioactive Waste Final Disposal Act', the Nuclear Waste Management Organization of Japan (NUMO) was established in October 2000 as the implementing organization for geological disposal of vitrified high-level waste (HLW). Implementation of NUMO's disposal project will be based on three principles: 1) respecting public initiative and opinion, 2) adopting a stepwise approach and 3) ensuring transparency in information disclosure. NUMO has decided to adopt an open solicitation approach to finding volunteer municipalities for Preliminary Investigation Areas (PIAs). The official announcement of the start of the open solicitation program was made in 2002. Although no official applications had been received from volunteer municipalities by the end of 2005, NUMO has been continuing to carry out various activities aimed specifically at public communication and encouraging dialogue about the deep geological disposal project This paper summarizes the results obtained and lessons learned so far and identifies the issues that NUMO must tackle immediately in the areas of communication and dialogue.

  3. Public Perspectives in the Japanese HLW Disposal Program

    International Nuclear Information System (INIS)

    Inatsugu, Shigefumi; Takeuchi, Mitsuo; Kato, Toshiaki

    2006-01-01

    Following legislation entitled the 'Specified Radioactive Waste Final Disposal Act', the Nuclear Waste Management Organization of Japan (NUMO) was established in October 2000 as the implementing organization for geological disposal of vitrified high-level waste (HLW). Implementation of NUMO's disposal project will be based on three principles: 1) respecting public initiative and opinion, 2) adopting a stepwise approach and 3) ensuring transparency in information disclosure. NUMO has decided to adopt an open solicitation approach to finding volunteer municipalities for Preliminary Investigation Areas (PIAs). The official announcement of the start of the open solicitation program was made in 2002. Although no official applications had been received from volunteer municipalities by the end of 2005, NUMO has been continuing to carry out various activities aimed specifically at public communication and encouraging dialogue about the deep geological disposal project This paper summarizes the results obtained and lessons learned so far and identifies the issues that NUMO must tackle immediately in the areas of communication and dialogue

  4. Rheology of Savannah River Site Tank 51 HLW radioactive sludge

    International Nuclear Information System (INIS)

    Ha, B.C.

    1993-01-01

    Savannah River Site (SRS) Tank 51 HLW radioactive sludge represents a major portion of the first batch of sludge to be vitrified in the Defense Waste Processing Facility (DWPF) at SRS. The rheological properties of Tank 51 sludge will determine if the waste sludge can be pumped by the current DWPF process cell pump design and the homogeneity of melter feed slurries. The rheological properties of Tank 51 sludge and sludge/frit slurries at various solids concentrations were measured remotely in the Shielded Cells Operations (SCO) at the Savannah River Technology Center (SRTC) using a modified Haake Rotovisco viscometer system. Rheological properties of Tank 51 radioactive sludge/Frit 202 slurries increased drastically when the solids content was above 41 wt %. The yield stresses of Tank 51 sludge and sludge/frit slurries fall within the limits of the DWPF equipment design basis. The apparent viscosities also fall within the DWPF design basis for sludge consistency. All the results indicate that Tank 51 waste sludge and sludge/frit slurries are pumpable throughout the DWPF processes based on the current process cell pump design, and should produce homogeneous melter feed slurries

  5. Enhanced sludge processing of HLW: Hydrothermal oxidation of chromium, technetium, and complexants by nitrate. 1998 annual progress report

    International Nuclear Information System (INIS)

    Buelow, S.J.; Robinson, J.M.

    1998-01-01

    'The objective of this project is to develop the scientific basis for hydrothermal separation of chromium from High Level Waste (HLW) sludges. The worked is aimed at attaining a fundamental understanding of chromium speciation, oxidation/reduction and dissolution kinetics, reaction mechanisms, and transport properties under hydrothermal conditions in both simple and complex salt solutions that will ultimately lead to an efficient chromium leaching process. This report summarizes the research over the first 1.5 years of a 3 year project. The authors have examined the dissolution of chromium hydroxide using different oxidants as a function of temperature and alkalinity. The results and possible applications to HLW sludges are discussed'

  6. The Production of Advanced Glass Ceramic HLW Forms using Cold Crucible Induction Melter

    Energy Technology Data Exchange (ETDEWEB)

    Veronica J Rutledge; Vince Maio

    2013-10-01

    Cold Crucible Induction Melters (CCIMs) will favorably change how High-Level radioactive Waste (from nuclear fuel recovery) is treated in the 21st century. Unlike the existing Joule-Heated Melters (JHMs) currently in operation for the glass-based immobilization of High-Level Waste (HLW), CCIMs offer unique material features that will increase melt temperatures, increase throughput, increase mixing, increase loading in the waste form, lower melter foot prints, eliminate melter corrosion and lower costs. These features not only enhance the technology for producing HLW forms, but also provide advantageous attributes to the waste form by allowing more durable alternatives to glass. This paper discusses advantageous features of the CCIM, with emphasis on features that overcome the historical issues with the JHMs presently utilized, as well as the benefits of glass ceramic waste forms over borosilicate glass waste forms. These advantages are then validated based on recent INL testing to demonstrate a first-of-a-kind formulation of a non-radioactive ceramic-based waste form utilizing a CCIM.

  7. Technology for the long-term management of defense HLW at the Idaho Chemical Processing Plant

    International Nuclear Information System (INIS)

    Staples, B.A.; Berreth, J.R.; Knecht, D.A.

    1986-01-01

    The Defense Waste Management Plan of June 1983 includes a reference plan for the long-term management of Idaho Chemical Processing Plant (ICPP) high-level waste (HLW), with a goal of disposing of the annual output in 500 canisters a year by FY-2008. Based on the current vitrification technology, the ICPP base-glass case would produce 1700 canisters per year after FY-2007. Thus, to meet the DWMP goal processing steps including fuel dissolution, waste treatment, and waste immobilization are being studied as areas where potential modifications could result in HLW volume reductions for repository disposal. It has been demonstrated that ICPP calcined wastes can be densified by hot isostatic pressing to multiphase ceramic forms of high loading and density. Conversion of waste by hot isostatic pressing to these forms has the potential of reducing the annual ICPP waste production to volumes near those of the goal of the DWMP. This report summarizes the laboratory-scale information currently available on the development of these forms

  8. Interference of different ionic species on the analysis of phosphate in HLW using spectrophotometer

    International Nuclear Information System (INIS)

    Mishra, P.K.; Ghongane, D.E.; Valsala, T.P.; Sonavane, M.S.; Kulkarni, Y.; Changrani, R.D.

    2010-01-01

    During reprocessing of spent nuclear fuel by PUREX process different categories of radioactive liquid wastes like High Level (HL), Intermediate Level (IL) and Low Level (LL) are generated. Different methodologies are adopted for management of these wastes. Since PUREX solvent (30% Tri butyl phosphate-70% Normal Paraffin Hydrocarbon) undergoes chemical degradation in the highly acidic medium of dissolver solution, presence of phosphate in the waste streams is inevitable. Since higher concentrations of phosphate in the HLW streams will affect its management by vitrification, knowledge about the concentration of phosphate in the waste is essential before finalising the glass composition. Since a large number of anionic and cationic species are present in the waste, these species may interfere phosphate analysis using spectrophotometer. In the present work, the interference of different anionic and cationic species on the analysis of phosphate in waste solutions using spectrophotometer was studied

  9. Safety case development in the Japanese programme for geological disposal of HLW: Evolution in the generic stage

    International Nuclear Information System (INIS)

    Ueda, Hiroyoshi; Ishiguro, Katsuhiko; Takeuchi, Mitsuo; Fujihara, Hiroshi; Takeda, Seietsu

    2014-01-01

    In the Japanese programme for nuclear power generation, the safe management of the resulting radioactive waste, particularly vitrified high-level waste (HLW) from fuel reprocessing, has been a major concern and a focus of R and D since the late 70's. According to the specifications in a report issued by an advisory committee of the Japan Atomic Energy Commission (JAEC, 1997), the Second Progress Report on R and D for the Geological Disposal of HLW (H12 report) (JNC, 2000) was published after two decades of R and D activities and showed that disposal of HLW in Japan is feasible and can be practically implemented at sites which meet certain geological stability requirements. The H12 report supported government decisions that formed the basis of the 'Act on Final Disposal of Specified Radioactive Waste' (Final Disposal Act), which came into force in 2000. The Act specifies deep geological disposal of HLW at depths greater than 300 metres, together with a stepwise site selection process in three stages. Following the Final Disposal Act, the supporting 'Basic Policy for Final Disposal' and the 'Final Disposal Plan' were authorised in the same year. (authors)

  10. Institute for Nuclear Waste Disposal. Annual Report 2011

    International Nuclear Information System (INIS)

    Geckeis, H.; Stumpf, T.

    2012-01-01

    The R and D at the Institute for Nuclear Waste Disposal, INE, (Institut fuer Nukleare Entsorgung) of the Karlsruhe Institute of Technology (KIT) focuses on (i) long term safety research for nuclear waste disposal, (ii) immobilization of high level radioactive waste (HLW), (iii) separation of minor actinides from HLW and (iv) radiation protection.

  11. Integrated HLW Conceptual Process Flowsheet(s) for the Crystalline Silicotitanate Process SRDF-98-04

    International Nuclear Information System (INIS)

    Jacobs, R.A.

    1998-01-01

    The Strategic Research and Development Fund (SRDF) provided funds to develop integrated conceptual flowsheets and material balances for a CST process as a potential replacement for, or second generation to, the ITP process. This task directly supports another SRDF task: Glass Form for HLW Sludge with CST, SRDF-98-01, by M. K. Andrews which seeks to further develop sludge/CST glasses that could be used if the ITP process were replaced by CST ion exchange. The objective of the proposal was to provide flowsheet support for development and evaluation of a High Level Waste Division process to replace ITP. The flowsheets would provide a conceptual integrated material balance showing the impact on the HLW division. The evaluation would incorporate information to be developed by Andrews and Harbour on CST/DWPF glass formulations and provide the bases for evaluating the economic impact of the proposed replacement process. Coincident with this study, the Salt Disposition Team began its evaluation of alternatives for disposition of the HLW salts in the SRS waste tanks. During that time, the CST IX process was selected as one of four alternatives (of eighteen Phase II alternatives) for further evaluation during Phase III

  12. Results of screening activities in salt states prior to the enactment of the Nationall Waste Policy Act

    International Nuclear Information System (INIS)

    Carbiener, W.A.

    1983-01-01

    The identification of potential sites for a nuclear waste repository through screening procedures in the salt states is a well-established, deliberate process. This screening process has made it possible to carry out detailed studies of many of the most promising potential sites, and general studies of all the sites, in anticipation of the siting guidelines specified in the Nuclear Waste Policy Act. The screening work completed prior to the passage of the Act allowed the Secretary of Energy to identify seven salt sites as potentially acceptable under the provisions of Section 116(a) of the Act. These sites were formally identified by letters from Secretary Hodel to the states of Texas, Utah, Mississippi, and Louisiana on February 2, 1983. The potentially acceptable salt sites were in Deaf Smith and Swisher Counties in Texas; Davis and Lavender Canyons in the Gibson Dome location in Utah; Richton and Cypress Creek Domes in Mississippi; and Vacherie Dome in Louisiana. Further screening will include comparison of each potentially acceptable site against disqualification factors and selection of a preferred site in each of the three geohydrologic settings from those remaining, in accordance with the siting guidelines. These steps will be documented in statutory Environmental Assessments prepared for each site to be nominated for detailed characterization. 9 references

  13. Source term measurements on vitrified HLW

    International Nuclear Information System (INIS)

    Hough, A.; Marples, J.A.C.

    1988-01-01

    The equilibrium concentrations of Tc-99, Np-237, Pu-239/240 and Am-241 have been measured in the presence of materials likely to be present in a vitrified HLW repository: glass, iron, backfill and rock. Results were measured under both oxidising and reducing conditions and at pH values set by the backfill bentonite and cement. Under reducing conditions and with cementitious backfills, the equilibrium concentrations ranged from three to 30 times allowed drinking water levels for the four isotopes. (author)

  14. Strategic management of HLW repository projects

    International Nuclear Information System (INIS)

    Bartlett, J.W.

    1984-01-01

    This paper suggests an approach to strategic management of HLW repository projects based on the premise that a primary objective of project activities is resolution of issues. The approach would be implemented by establishing an issues management function with responsibility to define the issues agenda, develop and apply the tools for assessing progress toward issue resolution, and develop the issue resolution criteria. A principal merit of the approach is that it provides a defensible rationale for project plans and activities. It also helps avoid unnecessary costs and schedule delays, and it helps assure coordination between project functions that share responsibilities for issue resolution

  15. Compas project stress analysis of HLW containers: behaviour under realistic disposal conditions

    International Nuclear Information System (INIS)

    Ove Arup and Partners, London

    1990-01-01

    The Compas project is concerned with the structural performance of metal overpacks which may be used to encapsulate vitrified high-level waste (HLW) forms before disposal in deep geological repositories. In this final stage of the project, analysis of an HLW overpack of realistic design is performed to predict its behaviour when subjected to likely repository loads. This analysis work is undertaken with the benefit of experience gained in previous phases of the project in which the ability to accurately predict overpack behaviour, when subjected to a uniform external pressure, was demonstrated. Burial in clay, granite and salt environments has been considered and two distinct loading arrangements identified, in an attempt to represent the worst conditions that could be imposed by such media. The analysis successfully demonstrates the ability of the containers to withstand extreme, yet credible, repository loads

  16. Application of Epoxy Based Coating Instacote on Waste Tank Tops

    International Nuclear Information System (INIS)

    Pike, J.A.

    1998-01-01

    This evaluation examines the compatibility of coating Instacote with existing High-Level Waste facilities and safety practices. No significant incompatibilities are identified. The following actions need to be completed as indicated when applying Instacote on waste tank tops:(1) Prior to application in ITP facilities, the final product should be tested for chemical resistance to sodium tetraphenylborate solutions or sodium titanate slurries.(2) Any waste contaminated with Part A or B that can not be removed by the vendor such as for radiological contamination, HLW must hold the waste until HLW completes a formal assessment of the waste, disposal criteria, and impact.(3) Prior to the start of any application of the coating, each riser needs to be evaluated for masking and masking applied if needed.(4) At the conclusion of an application actual total weight of material applied to a waste tank needs to documented and sent to the tank top loading files for reference purposes.(5) Verify that the final product contains less than 250 ppm chloride

  17. Grouping in partitioning of HLW for burning and/or transmutation with nuclear reactors

    International Nuclear Information System (INIS)

    Kitamoto, Asashi; Mulyanto.

    1995-01-01

    A basic concept on partitioning and transmutation treatment by neutron reaction was developed in order to improve the waste management and the disposal scenario of high level waste (HLW). The grouping in partitioning was important factor and closely linked with the characteristics of B/T (burning and/or transmutation) treatment. The selecting and grouping concept in partitioning of HLW was proposed herein, such as Group MA1 (Np, Am, and unrecovered U and Pu), Group MA2 (Cm, Cf etc.), Group A (Tc and I), Group B (Cs and Sr) and Group R (the partitioned remain of HLW), judging from the three criteria for B/T treatment proposed in this study, which is related to (1) the value of hazard index for long-term tendency based on ALI, (2) the relative dose factor related to the mobility or retardation in ground water penetrated through geologic layer, and (3) burning and/or transmutation characteristics for recycle B/T treatment and the decay acceleration ratio by neutron reaction. Group MA1 and Group A could be burned effectively by thermal B/T reactor. Group MA2 could be burned effectively by fast B/T reactor. Transmutation of Group B by neutron reaction is difficult, therefore the development of radiation application of Group B (Cs and Sr) in industrial scale may be an interesting option in the future. Group R, i.e. the partitioned remains of HLW, and also a part of Group B should be immobilized and solidified by the glass matrix. HI ALI , the hazard index based on ALI, due to radiotoxicity of Group R can be lower than HI ALI due to standard mill tailing (smt) or uranium ore after about 300 years. (author)

  18. Enhanced sludge processing of HLW: Hydrothermal oxidation of chromium, technetium, and complexants by nitrate. 1997 mid-year progress report

    International Nuclear Information System (INIS)

    Buelow, S.

    1997-01-01

    'Treatment of High Level Waste (HLW) is the second most costly problem identified by OEM. In order to minimize costs of disposal, the volume of HLW requiring vitrification and long term storage must be reduced. Methods for efficient separation of chromium from waste sludges, such as the Hanford Tank Wastes (HTW), are key to achieving this goal since the allowed level of chromium in high level glass controls waste loading. At concentrations above 0.5 to 1.0 wt.% chromium prevents proper vitrification of the waste. Chromium in sludges most likely exists as extremely insoluble oxides and minerals, with chromium in the plus III oxidation state [1]. In order to solubilize and separate it from other sludge components, Cr(III) must be oxidized to the more soluble Cr(VI) state. Efficient separation of chromium from HLW could produce an estimated savings of $3.4B[2]. Additionally, the efficient separation of technetium [3], TRU, and other metals may require the reformulation of solids to free trapped species as well as the destruction of organic complexants. New chemical processes are needed to separate chromium and other metals from tank wastes. Ideally they should not utilize additional reagents which would increase waste volume or require subsequent removal. The goal of this project is to apply hydrothermal processing for enhanced chromium separation from HLW sludges. Initially, the authors seek to develop a fundamental understanding of chromium speciation, oxidation/reduction and dissolution kinetics, reaction mechanisms, and transport properties under hydrothermal conditions in both simple and complex salt solutions. The authors also wish to evaluate the potential of hydrothermal processing for enhanced separations of technetium and TRU by examining technetium and TRU speciation at hydrothermal conditions optimal for chromium dissolution.'

  19. Commercial waste treatment program annual progress report for FY 1983

    Energy Technology Data Exchange (ETDEWEB)

    McElroy, J.L.; Burkholder, H.C. (comps.)

    1984-02-01

    This annual report describes progress during FY 1983 relating to technologies under development by the Commercial Waste Treatment Program, including: development of glass waste form and vitrification equipment for high-level wastes (HLW); waste form development and process selection for transuranic (TRU) wastes; pilot-scale operation of a radioactive liquid-fed ceramic melter (LFCM) system for verifying the reliability of the reference HLW treatment proces technology; evaluation of treatment requirements for spent fuel as a waste form; second-generation waste form development for HLW; and vitrification process control and product quality assurance technologies.

  20. Final Report Tests On The Duramelter 1200 HLW Pilot Melter System Using AZ-101 HLW Simulants VSL-02R0100-2, Rev. 1, 2/17/03

    International Nuclear Information System (INIS)

    Kruger, A.A.; Matlack, K.S.; Kot, W.K.; Bardakci, T.; Gong, W.; D'Angelo, N.A.; Schatz, T.R.; Pegg, I.L.

    2011-01-01

    This document provides the final report on data and results obtained from a series of nine tests performed on the one-third scale DuraMelter(trademark) 1200 (DM1200) HLW Pilot Melter system that has been installed at VSL with an integrated prototypical off-gas treatment system. That system has replaced the DM1000 system that was used for HLW throughput testing during Part B1 (1). Both melters have similar melt surface areas (1.2 m 2 ) but the DM1200 is prototypical of the present RPP-WTP HLW melter design whereas the DM1000 was not. These tests were performed under a corresponding RPP-WTP Test Specification and associated Test Plans. The nine tests reported here were preceded by an initial series of short-duration tests conducted to support the start-up and commissioning of this system. This report is a followup to the previously issued Preliminary Data Summary Reports. The DM1200 system was deployed for testing and confirmation of basic design, operability, flow sheet, and process control assumptions as well as for support of waste form qualification and permitting. These tests include data on processing rates, off-gas treatment system performance, recycle stream compositions, as well as process operability and reliability. Consequently, this system is a key component of the overall HLW vitrification development strategy. The primary objective of the present series of tests was to determine the effects of a variety of parameters on the glass production rate in comparison to the RPP-WTP HL W design basis of 400 kg/m 2 /d. Previous testing on the DMIOOO system (1) concluded that achievement of that rate with simulants of projected WTP melter feeds (AZ-101 and C-106/AY-102) was unlikely without the use of bubblers. As part of those tests, the same feed that was used during the cold-commissioning of the West Valley Demonstration Project (WVDP) HLW vitrification system was run on the DM1000 system. The DM1000 tests reproduced the rates that were obtained at the larger

  1. FINAL REPORT TESTS ON THE DURAMELTER 1200 HLW PILOT MELTER SYSTEM USING AZ-101 HLW SIMULANTS VSL-02R0100-2 REV 1 2/17/03

    Energy Technology Data Exchange (ETDEWEB)

    KRUGER AA; MATLACK KS; KOT WK; BARDAKCI T; GONG W; D' ANGELO NA; SCHATZ TR; PEGG IL

    2011-12-29

    This document provides the final report on data and results obtained from a series of nine tests performed on the one-third scale DuraMelter{trademark} 1200 (DM1200) HLW Pilot Melter system that has been installed at VSL with an integrated prototypical off-gas treatment system. That system has replaced the DM1000 system that was used for HLW throughput testing during Part B1 [1]. Both melters have similar melt surface areas (1.2 m{sup 2}) but the DM1200 is prototypical of the present RPP-WTP HLW melter design whereas the DM1000 was not. These tests were performed under a corresponding RPP-WTP Test Specification and associated Test Plans. The nine tests reported here were preceded by an initial series of short-duration tests conducted to support the start-up and commissioning of this system. This report is a followup to the previously issued Preliminary Data Summary Reports. The DM1200 system was deployed for testing and confirmation of basic design, operability, flow sheet, and process control assumptions as well as for support of waste form qualification and permitting. These tests include data on processing rates, off-gas treatment system performance, recycle stream compositions, as well as process operability and reliability. Consequently, this system is a key component of the overall HLW vitrification development strategy. The primary objective of the present series of tests was to determine the effects of a variety of parameters on the glass production rate in comparison to the RPP-WTP HL W design basis of 400 kg/m{sup 2}/d. Previous testing on the DMIOOO system [1] concluded that achievement of that rate with simulants of projected WTP melter feeds (AZ-101 and C-106/AY-102) was unlikely without the use of bubblers. As part of those tests, the same feed that was used during the cold-commissioning of the West Valley Demonstration Project (WVDP) HLW vitrification system was run on the DM1000 system. The DM1000 tests reproduced the rates that were obtained at the

  2. The use of mineral-like matrices for hlw solidification and spent fuel immobilization

    International Nuclear Information System (INIS)

    Pokhitonov, J.A.; Starchenko, V.A.; Strelnikov, A.V.; Sorokin, V.T.; Shvedov, A.A.

    2000-01-01

    The conception of radioactive waste management is based upon the multi-barrier protection principle stating that the long-lived radionuclides safety isolation is ensured by a system of engineering and natural geological barriers. One of the effective ways of the long-lived radionuclides immobilization is the integration of these materials within a mineral-like matrice. This technique may be used both for isolation of separated groups of nuclides (Cs, Sr, TUE, TRE) and for immobilization of spent fuel which for some reason can't be processed at the radiochemical plant. In this paper two variants of flowsheets HLW management are discussed. The following ways of HLW reprocessing are considered: - The first cycle raffinate solidification (without partitioning); - The individual solidification of two separated radionuclide groups (Sr+Cs+FP fraction and TPE+TRE fraction). The calcination of some characteristics (annual and total amounts, specific activity, radiochemical composition and radiogenic heat) of HLW integrated within a mineral-like matrix are performed for both options. The matrix compositions may be also used for spent fuel immobilization by means of the hot isostatic pressing technique. (authors)

  3. Time evolution of the Clay Barrier Chemistry in a HLW deep geological disposal in granite

    International Nuclear Information System (INIS)

    Font, I.; Miguel, M. J.; Juncosa, R.

    2000-01-01

    The main goal of a high level waste geological disposal is to guarantee the waste isolation from the biosphere, locking them away into very deep geological formations. The best way to assure the isolation is by means of a multiple barrier system. These barriers, in a serial disposition, should assure the confinement function of the disposal system. Two kinds of barriers are considered: natural barriers (geological formations) and engineered barriers (waste form, container and backfilling and sealing materials). Bentonite is selected as backfilling and sealing materials for HLW disposal into granite formations, due to its very low permeability and its ability to fill the remaining spaces. bentonite has also other interesting properties, such as, the radionuclide retention capacity by sorption processes. Once the clay barrier has been placed, the saturation process starts. The granite groundwater fills up the voids of the bentonite and because of the chemical interactions, the groundwater chemical composition varies. Near field processes, such as canister corrosion, waste leaching and radionuclide release, strongly depends on the water chemical composition. Bentonite pore water composition is such a very important feature of the disposal system and its determination and its evolution have great relevance in the HLW deep geological disposal performance assessment. The process used for the determination of the clay barrier pore water chemistry temporal evolution, and its influence on the performance assessment, are presented in this paper. (Author)

  4. 26 CFR 1.381(c)(18)-1 - Depletion on extraction of ores or minerals from the waste or residue of prior mining.

    Science.gov (United States)

    2010-04-01

    ... 26 Internal Revenue 4 2010-04-01 2010-04-01 false Depletion on extraction of ores or minerals from... Reorganizations § 1.381(c)(18)-1 Depletion on extraction of ores or minerals from the waste or residue of prior... transfer, to an allowance for depletion under section 611 in respect of ores or minerals extracted from...

  5. Current status and future plans of R and D on geological disposal of HLW in Japan

    International Nuclear Information System (INIS)

    Sasaki, Noriaki

    1994-01-01

    As to the final disposal of HLW, it is considered highly important to provide a clear distinction between implementation of disposal and the research and development as independent processes, and to increase the transparency of the overall disposal program by defining concrete schedules and the roles and responsibilities of the organizations involved. The Power Reactor and Nuclear Fuel Development Corporation (PNC) has being conducted research and development on the geological disposal of HLW, as the leading organization. The responsibility of PNC is to ensure smooth progress of research and development project and to carry out studies of geological environment. The role of the Japanese government is to take overall responsibilities for appropriate and steady implementations of the program, as well as enacting any laws or policies required. On the other hand, electricity supply utilities are responsible to secure necessary funds for disposal, and in accordance with their role as waste producers, they are expected to cooperate even at the stage of research and development. Fundamental features of research and development of PNC carried out at this stage are as follows; (1) Generic research and development, (2) To establish scientific and technical bases of geological isolation of HLW in Japan, (3) About 15 years program from 1989 with documentation of progress reports, (4) Approach from near-field to far-field. PNC summarized the findings obtained by 1991, and submitted a document (H3 Report) in September 1992 as the first progress report. H3 Report is the first and comprehensive technical report on geological disposal of HLW in Japan, and provides information for the public to find out the current status of the research and development. This paper reviews the conclusions of H3 Report, overall procedures and schedule for implementing geological disposal, and future plans of R and D in PNC. (J.P.N.)

  6. Setting up a safe deep repository for long-lived HLW and ILW in Russia: Current state of the works

    International Nuclear Information System (INIS)

    Polyakov, Yu.D.; Porsov, A.Yu.; Beigul, V.P.; Palenov, M.V.

    2014-01-01

    The concept of RW disposal in Russia in accordance with the Federal Law 'On Radioactive Waste Management and Amendments to Specific Legal Acts of the Russian Federation' No. 190-FL dated 11 July 2011, is oriented at the ultimate disposal of waste, without an intent for their subsequent retrieval. The law 190-FL has it as follows: - A radioactive waste repository is a radioactive waste storage facility intended for disposal of the radioactive wastes without an intent for their subsequent retrieval. - Disposal of solid long-lived high-level waste and solid long-lived intermediate-level waste is carried out in deep repositories for radioactive waste. - Import into the Russian Federation of radioactive waste for the purpose of its storage, processing and disposal, except for spent sealed sources of ionising radiation originating from the Russian Federation, is prohibited. For safe final disposal of long-lived HLW and ILW, it is planned to construct a deep repository for radioactive waste (DRRW) in a low-pervious monolith rock massif in the Krasnoyarsk region in the production territory of the Mining and Chemical Combine (FSUE 'Gorno-khimicheskiy kombinat'). According to the IAEA recommendations and in line with the international experience in feasibility studies for setting up of HLW and SNF underground disposal facilities, the first mandatory step is the construction of an underground research laboratory. An underground laboratory serves the following purposes: - itemised research into the characteristics of enclosing rock mass, with verification of massive material suitability for safe disposal of long-lived HLW and ILW; - research into and verification of the isolating properties of an engineering barrier system; - development of engineering solutions and transportation and process flow schemes for construction and running of a future RW ultimate isolation facility. (authors)

  7. River Protection Project Mission Analysis Waste Blending Study

    International Nuclear Information System (INIS)

    Shuford, D.H.; Stegen, G.

    2010-01-01

    Preliminary evaluation for blending Hanford site waste with the objective of minimizing the amount of high-level waste (HLW) glass volumes without major changes to the overall waste retrieval and processing sequences currently planned. The evaluation utilizes simplified spreadsheet models developed to allow screening type comparisons of blending options without the need to use the Hanford Tank Waste Operations Simulator (HTWOS) model. The blending scenarios evaluated are expected to increase tank farm operation costs due to increased waste transfers. Benefit would be derived from shorter operating time period for tank waste processing facilities, reduced onsite storage of immobilized HLW, and reduced offsite transportation and disposal costs for the immobilized HLW.

  8. Stress analysis of HLW containers advanced test work Compas project

    International Nuclear Information System (INIS)

    Ove Arup and Partners

    1990-01-01

    The Compas project is concerned with the structural performance of metal overpacks which may be used to encapsulate vitrified high-level waste forms before disposal in deep geological repositories. This document describes the activities performed between June and August 1989 forming the advanced test work phase of this project. This is the culmination of two years' analysis and test work to demonstrate whether the analytical ability exists to model containers subjected to realistic loads. Three mild steel containers were designed and manufactured to be one-third scale models of a realistic HLW container, modified to represent the effect of anisotropic loading and to facilitate testing. The containers were tested under a uniform external pressure and all failed by buckling in the mid-body region. The outer surface of each container was comprehensively strain-gauged to provide strain history data at all positions of interest. In parallel with the test work, Compas project partners, from five different European countries, independently modelled the behaviour of each of the containers using their computer codes to predict the failure pressure and produce strain history data at a number of specified locations. The first axisymmetric container was well modelled but predictions for the remaining two non-axisymmetric containers were much more varied, with differences of up to 50% occurring between failure predictions and test data

  9. Thermal analysis of the vertical disposal for HLW

    International Nuclear Information System (INIS)

    Zhao Honggang; Wang Ju; Liu Yuemiao; Su Rui

    2013-01-01

    The temperature on the canister surface is set to be no more than 100℃ in the high level radioactive waste (HLW) repository, it is a criterion to dictate the thermal dimension of the repository. The factors that affect the temperature on the canister surface include the initial power of the canister, the thermal properties of material as the engineered barrier system (EBS), the gaps around the canister in the EBS, the initial ground temperature and thermal properties of the host rock, the repository layout, etc. This article examines the thermal properties of the material in host rock and the EBS, the thermal conductivity properties of the different gaps in the EBS, the temperature evolution around the single canister by using the analysis method and the numerical method. The findings are as follows: 1) The most important and the sensitive parameter is the initial disposal power of the canister; 2) The two key factors that affect the highest temperature on the canister surface are the parameter of uncertainty and nature variability of material as the host rock and the EBS, and the gaps around the canister in the EBS; 3) The temperature difference between the canister and bentonite is no more than 10℃ , and the bigger the inner gaps are, the bigger the temperature difference will be; when the gap between the bentonite and the host rock is filled with water, the temperature difference becomes small, but it will be 1∼3℃ higher than the gaps filled will air. (authors)

  10. Biosphere modelling for a HLW repository - scenario and parameter variations

    International Nuclear Information System (INIS)

    Grogan, H.

    1985-03-01

    In Switzerland high-level radioactive wastes have been considered for disposal in deep-lying crystalline formations. The individual doses to man resulting from radionuclides entering the biosphere via groundwater transport are calculated. The main recipient area modelled, which constitutes the base case, is a broad gravel terrace sited along the south bank of the river Rhine. An alternative recipient region, a small valley with a well, is also modelled. A number of parameter variations are performed in order to ascertain their impact on the doses. Finally two scenario changes are modelled somewhat simplistically, these consider different prevailing climates, namely tundra and a warmer climate than present. In the base case negligibly low doses to man in the long term, resulting from the existence of a HLW repository have been calculated. Cs-135 results in the largest dose (8.4E-7 mrem/y at 6.1E+6 y) while Np-237 gives the largest dose from the actinides (3.6E-8 mrem/y). The response of the model to parameter variations cannot be easily predicted due to non-linear coupling of many of the parameters. However, the calculated doses were negligibly low in all cases as were those resulting from the two scenario variations. (author)

  11. Compas project stress analysis of HLW containers intermediate testwork

    International Nuclear Information System (INIS)

    Ove Arup and Partners London

    1990-01-01

    The Compas project is concerned with the structural performance of metal overpacks which may be used to encapsulate vitrified high-level waste forms before disposal in deep geological repositories. This document describes the series of experiments and associated calculations performed in the Intermediate testwork phase of this project. Seven mild steel, one-third scale simplified models of HLW containers were manufactured in a variety of configurations of geometry and weld type. The effects of reducing the wall thickness, corroding the external surface of the container, and using different welding methods were all investigated. The containers were tested under the action of a uniform external pressure up to their respective failure points. All containers failed by buckling at pressures of between 42 and 87 MPa dependent upon the particular geometric and weld configuration. The outer surface of each container was comprehensively strain-gauged in order to provide strain histories at positions of interest. The Compas project partners, from five different European countries, independently modelled the behaviour of three of the five different containers. Test results and computer predictions were compared and an assessment of the overall performance of the codes demonstrated good agreement in the initial loading of each container. However once stresses exceeded the material yield point there was a considerable spread in the predicted container behaviour

  12. Final Report - Management of High Sulfur HLW, VSL-13R2920-1, Rev. 0, dated 10/31/2013

    Energy Technology Data Exchange (ETDEWEB)

    Kruger, Albert A.; Gan, H.; Pegg, I. L.; Feng, Z.; Gan, H; Joseph, I.; Matlack, K. S.

    2013-11-13

    The present report describes results from a series of small-scale crucible tests to determine the extent of corrosion associated with sulfur containing HLW glasses and to develop a glass composition for a sulfur-rich HLW waste stream, which was then subjected to small-scale melter testing to determine the maximum acceptable sulfate loadings. In the present work, a new glass formulation was developed and tested for a projected Hanford HLW composition with sulfate concentrations high enough to limit waste loading. Testing was then performed on the DM10 melter system at successively higher waste loadings to determine the maximum waste loading without the formation of a separate sulfate salt phase. Small scale corrosion testing was also conducted using the glass developed in the present work, the glass developed in the initial phase of this work [26], and a high iron composition, all at maximum sulfur concentrations determined from melter testing, in order to assess the extent of Inconel 690 and MA758 corrosion at elevated sulfate contents.

  13. Immobilization and Waste Form Product Acceptance for Low Level and TRU Waste Forms

    International Nuclear Information System (INIS)

    Holtzscheiter, E.W.; Harbour, J.R.

    1998-05-01

    The Tanks Focus Area is supporting technology development in immobilization of both High Level (HLW) and Low Level (LLW) radioactive wastes. The HLW process development at Hanford and Idaho is patterned closely after that of the Savannah River (Defense Waste Processing Facility) and West Valley Sites (West Valley Demonstration Project). However, the development and options open to addressing Low Level Waste are diverse and often site specific. To start, it is important to understand the breadth of Low Level Wastes categories

  14. Geological aspects of the nuclear waste disposal problem

    International Nuclear Information System (INIS)

    Laverov, N.P.; Omelianenko, B.L.; Velichkin, V.I.

    1994-06-01

    For the successful solution of the high-level waste (HLW) problem in Russia one must take into account such factors as the existence of the great volume of accumulated HLW, the large size and variety of geological conditions in the country, and the difficult economic conditions. The most efficient method of HLW disposal consists in the maximum use of protective capacities of the geological environment and in using inexpensive natural minerals for engineered barrier construction. In this paper, the principal trends of geological investigation directed toward the solution of HLW disposal are considered. One urgent practical aim is the selection of sites in deep wells in regions where the HLW is now held in temporary storage. The aim of long-term investigations into HLW disposal is to evaluate geological prerequisites for regional HLW repositories

  15. Expected behavior of HLW glass in storage

    International Nuclear Information System (INIS)

    McElroy, J.L.

    1975-01-01

    Glass produced by solidification of high-level radioactive liquid waste is studied. Conditions to which the waste form will be exposed in a typical handling sequence representative of current U. S. planning are tabulated. The reference matrix for waste form characterization is discussed, and some of the properties of high-level waste glass are described: physical properties, leachability, fracturing, vaporization, and containment in canister. 12 fig, 5 tables

  16. Advances in Glass Formulations for Hanford High-Alumimum, High-Iron and Enhanced Sulphate Management in HLW Streams-13000

    International Nuclear Information System (INIS)

    Kruger, Albert A.

    2013-01-01

    The current estimates and glass formulation efforts have been conservative in terms of achievable waste loadings. These formulations have been specified to ensure that the glasses are homogenous, contain essentially no crystalline phases, are processable in joule-heated, ceramic-lined melters and meet Hanford Tank Waste Treatment and Immobilization Plant (WTP) Contract terms. The WTP's overall mission will require the immobilization of tank waste compositions that are dominated by mixtures of aluminum (Al), chromium (Cr), bismuth (Bi), iron (Fe), phosphorous (P), zirconium (Zr), and sulphur (S) compounds as waste-limiting components. Glass compositions for these waste mixtures have been developed based upon previous experience and current glass property models. Recently, DOE has initiated a testing program to develop and characterize HLW glasses with higher waste loadings and higher throughput efficiencies. Results of this work have demonstrated the feasibility of increases in waste loading from about 25 wt% to 33-50 wt% (based on oxide loading) in the glass depending on the waste stream. In view of the importance of aluminum limited waste streams at Hanford (and also Savannah River), the ability to achieve high waste loadings without adversely impacting melt rates has the potential for enormous cost savings from reductions in canister count and the potential for schedule acceleration. Consequently, the potential return on the investment made in the development of these enhancements is extremely favorable. Glass composition development for one of the latest Hanford HLW projected compositions with sulphate concentrations high enough to limit waste loading have been successfully tested and show tolerance for previously unreported tolerance for sulphate. Though a significant increase in waste loading for high-iron wastes has been achieved, the magnitude of the increase is not as substantial as those achieved for high-aluminum, high-chromium, high-bismuth or sulphur

  17. Proceedings: EPRI Workshop 2 -- Technical basis for EPA HLW disposal criteria

    International Nuclear Information System (INIS)

    Rogers, V.

    1993-03-01

    The Electric Power Research Institute (EPRI) sponsored this workshop to address the scientific and technical issues underlying the regulatory criteria, or standard, for the disposal of spent nuclear fuel, high-level radioactive waste, and transuranic waste, commonly referred to collectively as high-level waste (HLW). These regulatory criteria were originally promulgated by the US Environmental Protection Agency (EPA) in 40 CFR Part 191 in 1985. However, significant portions of the regulation were remanded by the Ninth Circuit Court of Appeals in 1987. This is the second of two workshops. Topics discussed include: gas pathway; individual and groundwater protection; human intrusion; population protection; performance; TRU conversion factors and discussions. Individual projects re processed separately for the databases

  18. Liquid waste treatment system. Final report

    International Nuclear Information System (INIS)

    Baker, M.N.; Houston, H.M.

    1999-01-01

    Pretreatment of high-level liquid radioactive waste (HLW) at the West Valley Demonstration Project (WVDP) involved three distinct processing operations: decontamination of liquid HLW in the Supernatant Treatment System (STS); volume reduction of decontaminated liquid in the Liquid Waste Treatment System (LWTS); and encapsulation of resulting concentrates into an approved cement waste form in the Cement Solidification System (CSS). Together, these systems and operations made up the Integrated Radwaste Treatment System (IRTS)

  19. Technetium Chemistry in HLW: Role of Organic Complexants

    International Nuclear Information System (INIS)

    Hess, Nancy J.; Blanchard, David L. Jr.; Campbell, James A.; Cho, Herman M.; Rai, Dhanpat Rai; Xia, Yuanxian; Conradson, Steven D.

    2002-01-01

    Technetium complexation with organic compounds in tank waste plays a significant role in the redox chemistry of Tc and the partitioning of Tc between the supernatant and sludge components in waste tanks. These processes need to be understood so that strategies to effectively remove Tc from high-level nuclear waste prior to waste immobilization can be developed and so that longterm consequences of Tc remaining in residual waste after sludge removal can be evaluated. Only limited data on the stability of Tc-organic complexes exists, and even less thermodynamic data on which to develop predictive models of Tc chemical behavior is available. To meet these challenges, we present a research program to study Tc-speciation in actual tank waste using state-of-the-art analytical organic chemistry, separations, and speciation techniques. On the basis of such studies, we will acquire thermodynamic data for the identified Tc-organic complexes over a wide range of chemical conditions in order to develop credible models to predict Tc speciation in tank waste and Tc behavior during waste pretreatment processing and in waste tank residuals

  20. Long-term product consistency test of simulated 90-19/Nd HLW glass

    International Nuclear Information System (INIS)

    Gan, X.Y.; Zhang, Z.T.; Yuan, W.Y.; Wang, L.; Bai, Y.; Ma, H.

    2011-01-01

    Chemical durability of 90-19/Nd glass, a simulated high-level waste (HLW) glass in contact with the groundwater was investigated with a long-term product consistency test (PCT). Generally, it is difficult to observe the long term property of HLW glass due to the slow corrosion rate in a mild condition. In order to overcome this problem, increased contacting surface (S/V = 6000 m -1 ) and elevated temperature (150 o C) were employed to accelerate the glass corrosion evolution. The micro-morphological characteristics of the glass surface and the secondary minerals formed after the glass alteration were analyzed by SEM-EDS and XRD, and concentrations of elements in the leaching solution were determined by ICP-AES. In our experiments, two types of minerals, which have great impact on glass dissolution, were found to form on 90-19/Nd HLW glass surface when it was subjected to a long-term leaching in the groundwater. One is Mg-Fe-rich phyllosilicates with honeycomb structure; the other is aluminosilicates (zeolites). Mg and Fe in the leaching solution participated in the formation of phyllosilicates. The main components of phyllosilicates in alteration products of 90-19/Nd HLW glass are nontronite (Na 0.3 Fe 2 Si 4 O 10 (OH) 2 .4H 2 O) and montmorillonite (Ca 0.2 (Al,Mg) 2 Si 4 O 10 (OH) 2 .4H 2 O), and those of aluminosilicates are mordenite ((Na 2 ,K 2 ,Ca)Al 2 Si 10 O 24 .7H 2 O)) and clinoptilolite ((Na,K,Ca) 5 Al 6 Si 30 O 72 .18H 2 O). Minerals like Ca(Mg)SO 4 and CaCO 3 with low solubility limits are prone to form precipitant on the glass surface. Appearance of the phyllosilicates and aluminosilicates result in the dissolution rate of 90-19/Nd HLW glass resumed, which is increased by several times over the stable rate. As further dissolution of the glass, both B and Na in the glass were found to leach out in borax form.

  1. Idaho National Engineering Laboratory High-Level Waste Roadmap

    International Nuclear Information System (INIS)

    1993-08-01

    The Idaho National Engineering Laboratory (INEL) High-Level Waste (HLW) Roadmap takes a strategic look at the entire HLW life-cycle starting with generation, through interim storage, treatment and processing, transportation, and on to final disposal. The roadmap is an issue-based planning approach that compares ''where we are now'' to ''where we want and need to be.'' The INEL has been effectively managing HLW for the last 30 years. Calcining operations are continuing to turn liquid HLW into a more manageable form. Although this document recognizes problems concerning HLW at the INEL, there is no imminent risk to the public or environment. By analyzing the INEL current business operations, pertinent laws and regulations, and committed milestones, the INEL HLW Roadmap has identified eight key issues existing at the INEL that must be resolved in order to reach long-term objectives. These issues are as follows: A. The US Department of Energy (DOE) needs a consistent policy for HLW generation, handling, treatment, storage, and disposal. B. The capability for final disposal of HLW does not exist. C. Adequate processes have not been developed or implemented for immobilization and disposal of INEL HLW. D. HLW storage at the INEL is not adequate in terms of capacity and regulatory requirements. E. Waste streams are generated with limited consideration for waste minimization. F. HLW is not adequately characterized for disposal nor, in some cases, for storage. G. Research and development of all process options for INEL HLW treatment and disposal are not being adequately pursued due to resource limitations. H. HLW transportation methods are not selected or implemented. A root-cause analysis uncovered the underlying causes of each of these issues

  2. Stress analysis of HLW containers. Compas project

    International Nuclear Information System (INIS)

    1989-01-01

    This document reports the work carried out for the Compas project which looked at the performance of various computer codes in a selected benchmark exercise. This exercise consisted of several analyses on simplified models which have features typical of HLW containers. These analyses comprise two groups; one related to thick walled, stressed shell overpacks, the other related to thin walled, supported shell overpacks with a lead filler. The first set of analyses looked at an elastic-plastic behaviour and large deformation of a cylinder representative of the main body of thick walled containers). The second set looked at creep behaviour of the lead filler, and the shape the base of thin walled containers will take up, after hundreds of years in the repository. On the thick walled analyses with the cylinder subject to an external pressure all the codes gave consistent results in the elastic region and there is good agreement in the yield pressures. Once in the plastic region there is more divergence in the results although a consistent trend is predicted. One of the analyses predicted a non-axisymmetric mode of deformation as would be expected in reality. Fewer results were received for the creep analysis, however the transient creep results showed consistency, and were bounded by the final-state results

  3. Economic analysis of waste management alternatives for reprocessing wastes

    International Nuclear Information System (INIS)

    McKee, R.W.; Clark, L.L.; Daling, P.M.; Nesbitt, J.F.; Swanson, J.L.

    1984-02-01

    This study describes the results of a cost analysis of a broad range of alternatives for management of reprocessing wastes that would require geologic repository disposal. The intent was to identify cost-effective alternatives and the costs of potential repository performance requirements. Four integrated treatment facility alternatives for transuranic (TRU) wastes are described and compared. These include no treatment, compaction, incineration, and hulls melting. The advantages of reducing high-level wastes (HLW) volume are also evaluated as are waste transportation alternatives and several performance-related alternatives for emplacing waste in a basalt repository. Results show (1) that system costs for disposal of reprocessing waste are likely to be higher than those for disposal of spent fuel; (2) that volume reduction is cost-effective for both remote-handled (RH) TRU wastes and HLW, and that rail transport for HLW is more cost-effective than truck transport; (3) that coemplacement of RH-TRU wastes with HLW does not have a large cost advantage in a basalt repository; and (4) that, relative to performance requirements, the cost impact for elimination of combustibles is about 5%, long-lived containers for RH-TRU wastes can increase repository costs 10% to 20%, and immediate backfill compared to delayed backfill (bentonite/basalt) around the HLW canisters would increase repository costs up to 10% or overall system costs up to about 5%. 13 references, 4 figures, 12 tables

  4. An analytical overview of the consequences of microbial activity in a Swiss HLW repository

    International Nuclear Information System (INIS)

    McKinley, I.G.; West, J.M.; Grogan, H.A.

    1985-04-01

    Microorganisms are known to be important factors in many geochemical processes and their presence can be assured throughout the envisaged Swiss type C repository for HLW. It is likely that both introduced and resident microbes will colonise the near-field even at times when ambient temperature and radiation fields are relatively high. A simple quantitative model has been developed which indicates that microbial growth in the near-field is limited by the rate of supply of chemical energy from corrosion of the canister. Microbial processes examined include biodegradation of structural and packaging materials, alteration of groundwater chemistry (Eh, pH, organic complexant concentration) and direct nuclide uptake by microorganisms. The most important effects of such organisms are likely to be enhancement of release and mobility of key nuclides due to their complexation by microbial by-product. Resident micro-organisms in the far-field could potentially act as 9 living colloids' thus enhancing nuclide transport. In the case of flow paths through shear zones (kakirites), however, any microbes capable of penetrating the surrounding weathered rock matrix would be extensively retarded. It is concluded that microbial processes are unlikely to be of significance for HLW but will be more important for low/intermediate waste types. As data requirements are similar for all waste types, results from such studies would also resolve the main uncertainties remaining for the HLW case. Key research areas are identified as characterisation of a) nutrient availability in the near-field, b) the bioenergetics of iron corrosion, c) production of organic by-products, d) nuclide sorption by organisms and e) microbial mobility in the near-and far-field

  5. Benefits Of Vibration Analysis For Development Of Equipment In HLW Tanks - 12341

    International Nuclear Information System (INIS)

    Stefanko, D.; Herbert, J.

    2012-01-01

    Vibration analyses of equipment intended for use in the Savannah River Site (SRS) radioactive liquid waste storage tanks are performed during pre-deployment testing and has been demonstrated to be effective in reducing the life-cycle costs of the equipment. Benefits of using vibration analysis to identify rotating machinery problems prior to deployment in radioactive service will be presented in this paper. Problems encountered at SRS and actions to correct or lessen the severity of the problem are discussed. In short, multi-million dollar cost saving have been realized at SRS as a direct result of vibration analysis on existing equipment. Vibration analysis of equipment prior to installation can potentially reduce inservice failures, and increases reliability. High-level radioactive waste is currently stored in underground carbon steel waste tanks at the United States Department of Energy (DOE) Savannah River Site and at the Hanford Site, WA. Various types of rotating machinery (pumps and separations equipment) are used to manage and retrieve the tank contents. Installation, maintenance, and repair of these pumps and other equipment are expensive. In fact, costs to remove and replace a single pump can be as high as a half million dollars due to requirements for radioactive containment. Problems that lead to in-service maintenance and/or equipment replacement can quickly exceed the initial investment, increase radiological exposure, generate additional waste, and risk contamination of personnel and the work environment. Several different types of equipment are considered in this paper, but pumps provide an initial example for the use of vibration analysis. Long-shaft (45 foot long) and short-shaft (5-10 feet long) equipment arrangements are used for 25-350 horsepower slurry mixing and transfer pumps in the SRS HLW tanks. Each pump has a unique design, operating characteristics and associated costs, sometimes exceeding a million dollars. Vibration data are routinely

  6. BENEFITS OF VIBRATION ANALYSIS FOR DEVELOPMENT OF EQUIPMENT IN HLW TANKS - 12341

    Energy Technology Data Exchange (ETDEWEB)

    Stefanko, D.; Herbert, J.

    2012-01-10

    Vibration analyses of equipment intended for use in the Savannah River Site (SRS) radioactive liquid waste storage tanks are performed during pre-deployment testing and has been demonstrated to be effective in reducing the life-cycle costs of the equipment. Benefits of using vibration analysis to identify rotating machinery problems prior to deployment in radioactive service will be presented in this paper. Problems encountered at SRS and actions to correct or lessen the severity of the problem are discussed. In short, multi-million dollar cost saving have been realized at SRS as a direct result of vibration analysis on existing equipment. Vibration analysis of equipment prior to installation can potentially reduce inservice failures, and increases reliability. High-level radioactive waste is currently stored in underground carbon steel waste tanks at the United States Department of Energy (DOE) Savannah River Site and at the Hanford Site, WA. Various types of rotating machinery (pumps and separations equipment) are used to manage and retrieve the tank contents. Installation, maintenance, and repair of these pumps and other equipment are expensive. In fact, costs to remove and replace a single pump can be as high as a half million dollars due to requirements for radioactive containment. Problems that lead to in-service maintenance and/or equipment replacement can quickly exceed the initial investment, increase radiological exposure, generate additional waste, and risk contamination of personnel and the work environment. Several different types of equipment are considered in this paper, but pumps provide an initial example for the use of vibration analysis. Long-shaft (45 foot long) and short-shaft (5-10 feet long) equipment arrangements are used for 25-350 horsepower slurry mixing and transfer pumps in the SRS HLW tanks. Each pump has a unique design, operating characteristics and associated costs, sometimes exceeding a million dollars. Vibration data are routinely

  7. Cognition of high-level radioactive waste disposal in the Tokyo metropolitan area

    International Nuclear Information System (INIS)

    Kimura, Hiroshi

    2010-01-01

    In Japan, the disposal of high-level radioactive waste (HLW) produced by nuclear power generation is an urgent issue. Recently, some questionnaire surveys were conducted. Especially the surveys in the Tokyo metropolitan area which were conducted by AESJ include the fulfilling questions concerning HLW relatively. In this paper, the author shows the results of surveys by AESJ. These results show that the issue concerning HLW is not so much concern for the respondents by comparison with many kinds of issues in the society. They also show that female respondents have less understanding about HLW disposal and have more degree of anxiety against HLW and disposal than male respondents. (author)

  8. Status of the safety concept and safety demonstration for an HLW repository in salt. Summary report

    Energy Technology Data Exchange (ETDEWEB)

    Bollingerfehr, W.; Buhmann, D.; Filbert, W.; and others

    2013-12-15

    Salt formations have been the preferred option as host rocks for the disposal of high level radioactive waste in Germany for more than 40 years. During this period comprehensive geological investigations have been carried out together with a broad spectrum of concept and safety related R and D work. The behaviour of an HLW repository in salt formations, particularly in salt domes, has been analysed in terms of assessment of the total system performance. This was first carried out for concepts of generic waste repositories in salt and, since 1998, for a repository concept with specific boundary conditions, taking the geology of the Gorleben salt dome as an example. Suitable repository concepts and designs were developed, the technical feasibility has been proven and operational and long-term safety evaluated. Numerical modelling is an important input into the development of a comprehensive safety case for a waste repository. Significant progress in the development of numerical tools and their application for long-term safety assessment has been made in the last two decades. An integrated approach has been used in which the repository concept and relevant scientific and engineering data are combined with the results from iterative safety assessments to increase the clarity and the traceability of the evaluation. A safety concept that takes full credit of the favourable properties of salt formations was developed in the course of the R and D project ISIBEL, which started in 2005. This concept is based on the safe containment of radioactive waste in a specific part of the host rock formation, termed the containment providing rock zone, which comprises the geological barrier, the geotechnical barriers and the compacted backfill. The future evolution of the repository system will be analysed using a catalogue of Features, Events and Processes (FEP), scenario development and numerical analysis, all of which are adapted to suit the safety concept. Key elements of the

  9. Situation concerning the HLW repository in Germany

    International Nuclear Information System (INIS)

    Lempert, J.P.

    1992-01-01

    Final disposal of radioactive waste has been defined in Germany as: maintenance-free, safe emplacement of radioactive waste, time unlimited and no intention of retrievability. The responsibility for final disposal lies in the hands of the German Federal Government, which has assigned a federal authority to plan, erect and operate the federal facilities for long-term storage of nuclear waste. The federal authority has in lack of industrial experience contracted my company DBE which is responsible for the engineering, erection and operation of all German nuclear waste repositories. (author)

  10. Progress report for 1985/86 from the Waste Treatment and Disposal Working Party covering joint funded work

    International Nuclear Information System (INIS)

    Claxton, D.G.S.A.

    1986-01-01

    The Waste Treatment and Disposal Working Party (WTDWP) covered the areas of: ILW Product Evaluation, ILW and HLW Disposal Studies and ILW and HLW Quality Checking. The objectives of the programme were to evaluate potential waste products arising from the treatment of ILW, and to develop appropriate techniques which could be used to check the quality of the finished waste product. (author)

  11. HLW Flexible jumper materials compatibility evaluation

    Energy Technology Data Exchange (ETDEWEB)

    Skidmore, T. E. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2017-11-13

    H-Tank Farm Engineering tasked SRNL/Materials Science & Technology (MS&T) to evaluate the compatibility of Goodyear Viper® chemical transfer hose with HLW solutions. The hose is proposed as a flexible Safety Class jumper for up to six months service. SRNL/MS&T performed various tests to evaluate the effects of radiation, high pH chemistry and elevated temperature on the hose, particularly the inner liner. Test results suggest an upper dose limit of 50 Mrad for the hose. Room temperature burst pressure values at 50 Mrad are estimated at 600- 800 psi, providing a safety factor of 4.0-5.3X over the anticipated operating pressure of 150 psi and a safety factor of 3.0-4.0X over the working pressure of the hose (200 psi), independent of temperature effects. Radiation effects are minimal at doses less than 10 Mrad. Doses greater than 50 Mrad may be allowed, depending on operating conditions and required safety factors, but cannot be recommended at this time. At 250 Mrad, burst pressure values are reduced to the hose working pressure. At 300 Mrad, burst pressures are below 150 psi. At a bounding continuous dose rate of 57,870 rad/hr, the 50 Mrad dose limit is reached within 1.2 months. Actual dose rates may be lower, particularly during non-transfer periods. Refined dose calculations are therefore recommended to justify longer service. This report details the tests performed and interpretation of the results. Recommendations for shelf-life/storage, component quality verification, and post-service examination are provided.

  12. Final Report - Effects of High Spinel and Chromium Oxide Crystal Contents on Simulated HLW Vitrification in DM100 Melter Tests, VSL-09R1520-1, Rev. 0, dated 6/22/09

    Energy Technology Data Exchange (ETDEWEB)

    Kruger, Albert A.; Matlack, K. S.; Kot, W.; Pegg, I. L.; Chaudhuri, M.; Lutze, W.

    2013-11-13

    The principal objective of the work was to evaluate the effects of spinel and chromium oxide particles on WTP HLW melter operations and potential impacts on melter life. This was accomplished through a combination of crucible-scale tests, settling and rheological tests, and tests on the DM100 melter system. Crucible testing was designed to develop and identify HLW glass compositions with high waste loadings that exhibit formation of crystalline spinel and/or chromium oxide phases up to relatively high crystal contents (i.e., > 1 vol%). Characterization of crystal settling and the effects on melt rheology was performed on the HLW glass formulations. Appropriate candidate HLW glass formulations were selected, based on characterization results, to support subsequent melter tests. In the present work, crucible melts were formulated that exhibit up to about 4.4 vol% crystallization.

  13. Design and validation of the THMC China-Mock-Up test on buffer material for HLW disposal

    Directory of Open Access Journals (Sweden)

    Yuemiao Liu

    2014-04-01

    Full Text Available According to the preliminary concept of the high-level radioactive waste (HLW repository in China, a large-scale mock-up facility, named China-Mock-Up was constructed in the laboratory of Beijing Research Institute of Uranium Geology (BRIUG. A heater, which simulates a container of radioactive waste, is placed inside the compacted Gaomiaozi (GMZ-Na-bentonite blocks and pellets. Water inflow through the barrier from its outer surface is used to simulate the intake of groundwater. The numbers of water injection pipes, injection pressure and the insulation layer were determined based on the numerical modeling simulations. The current experimental data of the facility are herein analyzed. The experiment is intended to evaluate the thermo-hydro-mechano-chemical (THMC processes occurring in the compacted bentonite-buffer during the early stage of HLW disposal and to provide a reliable database for numerical modeling and further investigation of engineered barrier system (EBS, and the design of HLW repository.

  14. Glass formulation development and testing for the vitrification of DWPF HLW sludge coupled with crystalline silicotitanate (CST)

    International Nuclear Information System (INIS)

    Andrews, M.K.; Workman, P.J.

    1997-01-01

    An alternative to the In Tank Precipitation and sodium titanate processes at the Savannah River Site is the removal of cesium, strontium, and plutonium from the tank supernate by ion exchange using crystalline silicotitanate (CST). This inorganic material has been shown to effectively and selectively sorb these elements from supernate. The loaded CST could then be immobilized with High-Level Waste (HLW) sludge during vitrification. Initial efforts on the development of a glass formulation for a coupled waste stream indicate that reasonable loadings of both sludge and CST can be achieved in glass

  15. Status of Progress Made Toward Safety Analysis and Technical Site Evaluations for DOE Managed HLW and SNF.

    Energy Technology Data Exchange (ETDEWEB)

    Sevougian, S. David [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Stein, Emily [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Gross, Michael B [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Hammond, Glenn Edward [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Frederick, Jennifer M [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Mariner, Paul [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2016-11-01

    The Spent Fuel and Waste Science and Technology (SFWST) Campaign of the U.S. Department of Energy (DOE) Office of Nuclear Energy (NE) is conducting research and development (R&D) on generic deep geologic disposal systems (i.e., repositories). This report describes specific activities in FY 2016 associated with the development of a Defense Waste Repository (DWR)a for the permanent disposal of a portion of the HLW and SNF derived from national defense and research and development (R&D) activities of the DOE.

  16. Safety studies of HLW-disposal in the Mors salt dome - Support to the salt option of the Pagis project

    International Nuclear Information System (INIS)

    Lindstroem Jensen, K.E.

    1987-01-01

    The study, which is a support to the Pagis project, covers three tasks concerning the evaluation of the Danish salt dome Mors (variant disposal site): evaluation of the human intrusion scenario where a cavern is excavated near the HLW-repository by solution mining technique. The waste is supposed to be leached during the operation period until the abandoned cavern is closed by convergence and the contaminated brine is pressed up into the overburden. Evaluation of the brine intrusion scenario, where the HLW-repository is inadvertently located close to a major brine pocket which subsequently releases its brine content through defects in the repository to the discharge stream for the catchment area. Collection and description of hydrological data of surface and deep layers (down to circa 700 metres) in the repository region. The data will be used by GSF to calculate the radionuclide migration in the geosphere

  17. Regional Geologic Evaluations for Disposal of HLW and SNF: The Pierre Shale of the Northern Great Plains

    Energy Technology Data Exchange (ETDEWEB)

    Perry, Frank Vinton [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Kelley, Richard E. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2017-09-14

    The DOE Spent Fuel and Waste Technology (SWFT) R&D Campaign is supporting research on crystalline rock, shale (argillite) and salt as potential host rocks for disposal of HLW and SNF in a mined geologic repository. The distribution of these three potential repository host rocks is limited to specific regions of the US and to different geologic and hydrologic environments (Perry et al., 2014), many of which may be technically suitable as a site for mined geologic disposal. This report documents a regional geologic evaluation of the Pierre Shale, as an example of evaluating a potentially suitable shale for siting a geologic HLW repository. This report follows a similar report competed in 2016 on a regional evaluation of crystalline rock that focused on the Superior Province of the north-central US (Perry et al., 2016).

  18. Effect of composition on peraluminous glass properties: An application to HLW containment

    Science.gov (United States)

    Piovesan, V.; Bardez-Giboire, I.; Perret, D.; Montouillout, V.; Pellerin, N.

    2017-01-01

    Part of the Research and Development program concerning high level nuclear waste (HLW) glasses aims to assess new glass formulations able to incorporate a high waste content with enhanced properties in terms of thermal stability, chemical durability, and process ability. This study focuses on peraluminous glasses of the SiO2 - Al2O3 - B2O3 - Na2O - Li2O - CaO - La2O3 system, defined by an excess of aluminum ions Al3+ in comparison with modifier elements such as Na+, Li+ or Ca2+. To understand the effect of composition on physical properties of glasses (viscosity, density, Tg), a Design Of Experiments (DOE) approach was applied to investigate the peraluminous glass domain. The influence of each oxide was quantified to build predictive models for each property. Lanthanum and lithium oxides appear to be the most influential factors on peraluminous glass properties.

  19. Current status of preparing buffer/backfill block in HLW disposal abroad

    International Nuclear Information System (INIS)

    Yan Ming; Wang Xuewen; Zhang Huyuan

    2014-01-01

    There is an urgent need for China to commence the full-scale compaction test, resolving the preparation problem for buffer/backfill blocks when underground research laboratory project is planned for High Level Radioactive Waste (HLW) disposal. The foreign countries have some research about the preparation of buffer/backfill blocks in engineered barrier systems. The foreign research shows that installation of clay blocks with sector shape at waste pollution area is a feasible engineering method. Compacted clay blocks need to be cured in a cabinet with controlled temperature and humidity to avoid desiccation and surface powdering. A freeze mixing method, mixing powdered-ice and cooled bentonite, can be operated more easily and obtain more uniform hydration than the traditional mixing of water and bentonite. It is helpful to review and adsorb the foreign research results for the design of full-scale test of bentonite compaction. (authors)

  20. Vitrification of HLW in cold crucible melter

    International Nuclear Information System (INIS)

    Bordier, G.

    2005-01-01

    The performance of the vitrification process currently used in the La Hague commercial reprocessing plants has been continuously improved during more than ten years of operation. In parallel the CEA (French Atomic Energy Commission), COGEMA (Industrial Operator), and SGN (COGEMA's Engineering) have developed the cold crucible melter vitrification technology to obtain greater operating flexibility, increased plant availability and further reduction of secondary waste generated during operations. The cold crucible is a compact water-cooled melter in which the radioactive waste and the glass additives are melted by direct high frequency induction. The cooling of the melter produces a solidified glass layer that protects the melter's inner wall from corrosion. Because the heat is transferred directly to the melt, high operating temperatures can be achieved with no impact on the melter itself. COGEMA plans to implement the cold crucible technology to vitrify high level liquid waste from reprocessed spent U-Mo-Sn-Al fuel (used in gas cooled reactor). The cold crucible was selected for the vitrification of this particularly hard-to-process waste stream because it could not be reasonably processed in the standard hot induction melters currently used at the La Hague vitrification facilities: the waste has a high molybdenum content which makes it very corrosive and also requires a special high temperature glass formulation to obtain sufficiently high waste loading factors (12 % in molybdenum). A special glass formulation has been developed by the CEA and has been qualified through lab and pilot testing to meet standard waste acceptance criteria for final disposal of the U-Mo waste. The process and the associated technologies have been also qualified on a full-scale prototype at the CEA pilot facility in Marcoule. Engineering study has been integrated in parallel in order to take into account that the Cold Crucible should be installed remotely in one of the R7 vitrification

  1. Actinide partitioning from HLW in a continuous DIDPA extraction process by means of centrifugal extractors

    International Nuclear Information System (INIS)

    Morita, Y.; Kubota, M.; Glatz, J.P.; Koch, L.; Pagliosa, G.; Roemer, K.; Nicholl, A.

    1996-01-01

    An experiment on actinide partitioning from real high level waste (HLW) was performed in a continuous process by extraction with diisodecylphosphoric acid (DIDPA) using a battery of 12 centrifugal extractors installed in a hot cell. The HNO 3 concentration of the HLW was adjusted to 0.5 M by dilution. The extraction section had 8 stages, and H 2 O 2 was added to extract Np effectively. After extraction, Am and Cm were back-extracted with 4 M HNO 3 in 4 stages and Np and Pu were stripped with 0.8 M H 2 C 2 O 4 in 8 stages. The actinides, expect Np, were extracted from HLW with a very high yield. Although only 84% of the Np were recovered in the present experiment, the recovery would be improved to 99.7 % by increasing the temperature to 45 degree C, the number of stages from 8 to 16 and the H 2 O 2 concentration from 1 M to 2 M. Long-lived Tc and the main heat and radiation emitters Cs and Sr were not extracted and were thus separated from the actinides with high decontamination factors. About 98% of Am and Cm were recovered from the loaded solvent in the first stripping step with 4M HNO 3 . About 86% of Np and about 92% of Pu were back-extracted with 0.8 M H 2 C 2 O 4 . These incomplete recoveries would be improved by increasing the number of stages and by optimizing the other process parameters. 18 refs., 5 figs., 3 tabs

  2. Sensitivity of Nuclide Release Behavior to Groundwater Flow in an HLW Repository

    International Nuclear Information System (INIS)

    Lee, Youn-Myoung; Hwang, Yong-Soo

    2008-01-01

    Evaluation of the dose exposure rate to human being due to long-term nuclide releases from a high-level waste repository (HLW) is of importance to meet the dose limit presented by the regulatory bodies in order to ensure the performance of a repository. During the last few years, tools by which such a dose rate to an individual can be evaluated have been developed and implemented for a practical calculation to demonstrate the suitability of an HLW repository, with the aid of commercial tools such as AMBER and GoldSim, both of which are capable of probabilistic and deterministic calculations with their convenient user interface. Recently a migration from AMBER based models to GoldSim based ones has been made in accordance with a better feature of GoldSim, which is designed to facilitate the object-oriented modules to address any specialized programs, similar to solving jig saw puzzles and shows more advantage in a detailed complex modeling over AMBER. Recently a compartment modeling approach both for a geosphere and biosphere has been mainly carried out with AMBER in KAERI, which causes a necessity for a newly devised system performance evaluation model in which geosphere and biosphere models could be coupled organically together with less conservatism in the frame of the development of a total system performance assessment modeling tool, which could be successfully done with the aid of GoldSim. Therefore, through the current study, some probabilistic results of the GoldSim approach for a normal situation that could take place in a typical HLW repository are introduced

  3. Examining the role of canister cooling conditions on the formation of nepheline from nuclear waste glasses

    Energy Technology Data Exchange (ETDEWEB)

    Christian, J. H. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2015-09-01

    Nepheline (NaAlSiO₄) crystals can form during slow cooling of high-level waste (HLW) glass after it has been poured into a waste canister. Formation of these crystals can adversely affect the chemical durability of the glass. The tendency for nepheline crystallization to form in a HLW glass increases with increasing concentrations of Al₂O₃ and Na₂O.

  4. Cooling and cracking of technical HLW glass products

    International Nuclear Information System (INIS)

    Kienzler, B.

    1989-01-01

    The author discusses various cooling procedures applied to canisters filled with inactive simulated HLW glass and the measured temperature distributions compared with numerically computed data. Stress computations of the cooling process were carried out with a finite element method. Only those volume elements having temperatures below the transformation temperature Tg were assumed to contribute thermoelastically to the developing stresses. Model calculations were extended to include real HLW glass canisters with inherent thermal power. The development of stress as a function of variations of heat flow conditions and of the radioactive decay was studied

  5. The development of basic glass formulations for solidifying HLW from nuclear fuel reprocessing plant

    International Nuclear Information System (INIS)

    Jiang Yaozhong; Tang Baolong; Zhang Baoshan; Zhou Hui

    1995-01-01

    Basic glass formulations 90U/19, 90U/20, 90Nd/7 and 90Nd/10 applied in electric melting process are developed by using the mathematical model of the viscosity and electric resistance of waste glass. The yellow phase does not occur for basic glass formulations 90U/19 and 90U/20 solidifying HLW from nuclear fuel reprocessing plant when the waste loading is 20%. Under the waste loading is 16%, the process and product properties of glass 90U/19 and 90U/20 come up to or surpass the properties of the same kind of foreign waste glasses, and other properties are about the same to them of foreign waste glasses. The process and product properties of basic glass formulations 90Nd/7 and 90Nd/10 used for the solidification of 'U replaced by Nd' liquid waste are almost similar to them of 90U/19 and 90U/20. These properties fairly meet the requirements of 'joint test' (performed at KfK-INE, Germany). Among these formulations, 90Nd/7 is applied in cold engineering scale electric melting test performed at KfK-INE in Germany. The main process properties of cold test is similar to laboratory results

  6. Chemical analysis of simulated high level waste glasses to support stage III sulfate solubility modeling

    Energy Technology Data Exchange (ETDEWEB)

    Fox, K. M. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2016-03-17

    The U.S. Department of Energy (DOE), Office of Environmental Management (EM) is sponsoring an international, collaborative project to develop a fundamental model for sulfate solubility in nuclear waste glass. The solubility of sulfate has a significant impact on the achievable waste loading for nuclear waste forms within the DOE complex. These wastes can contain relatively high concentrations of sulfate, which has low solubility in borosilicate glass. This is a significant issue for low-activity waste (LAW) glass and is projected to have a major impact on the Hanford Tank Waste Treatment and Immobilization Plant (WTP). Sulfate solubility has also been a limiting factor for recent high level waste (HLW) sludge processed at the Savannah River Site (SRS) Defense Waste Processing Facility (DWPF). The low solubility of sulfate in glass, along with melter and off-gas corrosion constraints, dictate that the waste be blended with lower sulfate concentration waste sources or washed to remove sulfate prior to vitrification. The development of enhanced borosilicate glass compositions with improved sulfate solubility will allow for higher waste loadings and accelerate mission completion.The objective of the current scope being pursued by SHU is to mature the sulfate solubility model to the point where it can be used to guide glass composition development for DWPF and WTP, allowing for enhanced waste loadings and waste throughput at these facilities. A series of targeted glass compositions was selected to resolve data gaps in the model and is identified as Stage III. SHU fabricated these glasses and sent samples to SRNL for chemical composition analysis. SHU will use the resulting data to enhance the sulfate solubility model and resolve any deficiencies. In this report, SRNL provides chemical analyses for the Stage III, simulated HLW glasses fabricated by SHU in support of the sulfate solubility model development.

  7. Final Report Integrated DM1200 Melter Testing Using AZ-102 And C-106/AY-102 HLW Simulants: HLW Simulant Verification VSL-05R5800-1, Rev. 0, 6/27/05

    International Nuclear Information System (INIS)

    Kruger, A.A.; Matlack, K.S.; Gong, W.; Bardakci, T.; D'Angelo, N.A.; Brandys, M.; Kot, W.K.; Pegg, I.L.

    2011-01-01

    The principal objectives of the DM1200 melter tests were to determine the effects of feed rheology, feed solid content, and bubbler configuration on glass production rate and off-gas system performance while processing the HLW AZ-101 and C-106/AY-102 feed compositions; characterize melter off-gas emissions; characterize the performance of the prototypical off-gas system components, as well as their integrated performance; characterize the feed, glass product, and off-gas effluents; and perform pre- and post test inspections of system components. The specific objectives (including test success criteria) of this testing, along with how each objective was met, are outlined in a table. The data provided in this Final Report address the impacts of HLW melter feed rheology on melter throughput and validation of the simulated HLW melter feeds. The primary purpose of this testing is to further validate/verify the HLW melter simulants that have been used for previous melter testing and to support their continued use in developing melter and off-gas related processing information for the Project. The primary simulant property in question is rheology. Simulants and melter feeds used in all previous melter tests were produced by direct addition of chemicals; these feed tend to be less viscous than rheological the upper-bound feeds made from actual wastes. Data provided here compare melter processing for the melter feed used in all previous DM100 and DM1200 tests (nominal melter feed) with feed adjusted by the feed vendor (NOAH Technologies) to be more viscous, thereby simulating more closely the upperbounding feed produced from actual waste. This report provides results of tests that are described in the Test Plan for this work. The Test Plan is responsive to one of several test objectives covered in the WTP Test Specification for this work; consequently, only part of the scope described in the Test Specification was addressed in this particular Test Plan. For the purpose of

  8. FINAL REPORT INTEGRATED DM1200 MELTER TESTING USING AZ 102 AND C 106/AY-102 HLW SIMULANTS: HLW SIMULANT VERIFICATION VSL-05R5800-1 REV 0 6/27/05

    Energy Technology Data Exchange (ETDEWEB)

    KRUGER AA; MATLACK KS; GONG W; BARDAKCI T; D' ANGELO NA; BRANDYS M; KOT WK; PEGG IL

    2011-12-29

    The principal objectives of the DM1200 melter tests were to determine the effects of feed rheology, feed solid content, and bubbler configuration on glass production rate and off-gas system performance while processing the HLW AZ-101 and C-106/AY-102 feed compositions; characterize melter off-gas emissions; characterize the performance of the prototypical off-gas system components, as well as their integrated performance; characterize the feed, glass product, and off-gas effluents; and perform pre- and post test inspections of system components. The specific objectives (including test success criteria) of this testing, along with how each objective was met, are outlined in a table. The data provided in this Final Report address the impacts of HLW melter feed rheology on melter throughput and validation of the simulated HLW melter feeds. The primary purpose of this testing is to further validate/verify the HLW melter simulants that have been used for previous melter testing and to support their continued use in developing melter and off-gas related processing information for the Project. The primary simulant property in question is rheology. Simulants and melter feeds used in all previous melter tests were produced by direct addition of chemicals; these feed tend to be less viscous than rheological the upper-bound feeds made from actual wastes. Data provided here compare melter processing for the melter feed used in all previous DM100 and DM1200 tests (nominal melter feed) with feed adjusted by the feed vendor (NOAH Technologies) to be more viscous, thereby simulating more closely the upperbounding feed produced from actual waste. This report provides results of tests that are described in the Test Plan for this work. The Test Plan is responsive to one of several test objectives covered in the WTP Test Specification for this work; consequently, only part of the scope described in the Test Specification was addressed in this particular Test Plan. For the purpose of

  9. Sampling plan to support HLW tank 16

    International Nuclear Information System (INIS)

    Rodwell, P.O.; Martin, B.

    1997-01-01

    Plans are to remove the residual waste from the annulus of High-Level Waste Tank 16, located in the H-Area Tank Farm, in 1998. The interior of the tank is virtually clean. In the late 1970's, the waste was removed from the interior of the tank by several campaigns of waste removal with slurry pumps, spray washing, and oxalic acid cleaning. The annulus of the tank at one time had several thousand gallons of waste salt, which had leaked from the tank interior. Some of this salt was removed by adding water to the annulus and circulating, but much of the salt remains in the annulus. In order to confirm the source term used for fate and transport modeling, samples of the tank interior and annulus will be obtained and analyzed. If the results of the analyses indicate that the data used for the initial modeling is bounding then no changes will be made to the model. However, if the results indicate that the source term is higher than that assumed in the initial modeling, thus not bounding, additional modeling will be performed. The purpose of this Plan is to outline the approach to sampling the annulus and interior of Tank 16 as a prerequisite to salt removal in the annulus and closure of the entire tank system. The sampling and analysis of this tank system must be robust to reasonably ensure the actual tank residual is within the bounds of analysis error

  10. Preliminary waste form characteristics report Version 1.0. Revision 1

    International Nuclear Information System (INIS)

    Stout, R.B.; Leider, H.R.

    1991-01-01

    This report focuses on radioactive waste form characteristics that will be used to design a waste package and an engineered barrier system (EBS) for a suitable repository as part of the Yucca Mountain Project. The term waste form refers to irradiated reactor fuel, other high-level waste (HLW) in various physical forms, and other radioactive materials (other than HLW) which are received for emplacement in a geologic repository. Any encapsulating of stabilizing matrix is also referred to as a waste form

  11. Sodalite as a vehicle to increase Re retention in waste glass simulant during vitrification

    Energy Technology Data Exchange (ETDEWEB)

    Luksic, Steven A., E-mail: steven.luksic@pnnl.gov; Riley, Brian J.; Parker, Kent E.; Hrma, Pavel

    2016-10-15

    Technetium (Tc) retention during Hanford waste vitrification can be increased if the volatility can be controlled. Incorporating Tc into a thermally stable mineral phase, such as sodalite, is one way to achieve increased retention. Here, rhenium (Re)-bearing sodalite was tested as a vehicle to transport perrhenate (ReO{sub 4}{sup −}), a nonradioactive surrogate for pertechnetate (TcO{sub 4}{sup −}), into high-level (HLW) and low-activity waste (LAW) glass simulants. After melting HLW and LAW simulant feeds, the retention of Re in the glass was measured and compared with the Re retention in glass prepared from a feed containing Re{sub 2}O{sub 7}. Phase analysis of sodalite in both these glasses across a profile of temperatures describes the durability of Re-sodalite during the feed-to-glass transition. The use of Re sodalite improved the Re retention by 21% for HLW glass and 85% for LAW glass, demonstrating the potential improvement in Tc-retention if TcO{sub 4}{sup −} were to be encapsulated in a Tc-sodalite prior to vitrification. - Highlights: • Re retention is improved by incorporation into sodalite structure. • LAW-type glass shows lower retention but larger improvement with Re-sodalite. • Sodalite is stable to higher temperatures in high-alumina glass melts.

  12. Co-ensiling as a new technique for long-term storage of agro-industrial waste with low sugar content prior to anaerobic digestion.

    Science.gov (United States)

    Hillion, Marie-Lou; Moscoviz, Roman; Trably, Eric; Leblanc, Yoann; Bernet, Nicolas; Torrijos, Michel; Escudié, Renaud

    2018-01-01

    Biodegradable wastes produced seasonally need an upstream storage, because of the requirement for a constant feeding of anaerobic digesters. In the present article, the potential of co-ensiling biodegradable agro-industrial waste (sugar beet leaves) and lignocellulosic agricultural residue (wheat straw) to obtain a mixture with low soluble sugar content was evaluated for long-term storage prior to anaerobic digestion. The aim is to store agro-industrial waste while pretreating lignocellulosic biomass. The dynamics of co-ensiling was evaluated in vacuum-packed bags at lab-scale during 180 days. Characterization of the reaction by-products and microbial communities showed a succession of metabolic pathways. Even though the low initial sugars content was not sufficient to lower the pH under 4.5 and avoid undesirable fermentations, the methane potential was not substantially impacted all along the experiment. No lignocellulosic damages were observed during the silage process. Overall, it was shown that co-ensiling was effective to store highly fermentable fresh waste evenly with low sugar content and offers new promising possibilities for constant long-term supply of industrial anaerobic digesters. Copyright © 2017 Elsevier Ltd. All rights reserved.

  13. Managing nuclear waste: Social and economic impacts

    International Nuclear Information System (INIS)

    Hemphill, R.C.; Bassett, G.W. Jr.

    1993-01-01

    Recent research has focused on perceptions of risk dominant source of economic impacts due to siting a high level radioactive waste facility. This article addresses the social and economic considerations involved with the issue of risk perception and other types of negative imagery. Emphasis is placed on ways of measuring the potential for economic effects resulting from perceptions prior to construction and operation of a HLW facility. We describe the problems in arriving at defensible estimates of economic impacts. Our review has found that although legal and regulatory bases may soon allow inclusion of these impacts in EIS and for compensation purposes, credible scientific methods do not currently exist for predicting the existence or magnitude of changes in economic decision-making. Policy-makers should recognize the potential for perception-based economic impacts in determining the location and means of managing radioactive waste; but, they also need be cognizant of the current limitations of quantitative estimates of impacts in this area

  14. Engineering-scale vitrification of commercial high-level waste

    International Nuclear Information System (INIS)

    Bonner, W.F.; Bjorklund, W.J.; Hanson, M.S.; Knowlton, D.E.

    1980-04-01

    To date, technology for immobilizing commercial high-level waste (HLW) has been extensively developed, and two major demonstration projects have been completed, the Waste Solidification Engineering Prototypes (WSEP) Program and the Nuclear Waste Vitrification Project (NWVP). The feasibility of radioactive waste solidification was demonstrated in the WSEP program between 1966 and 1970 (McElroy et al. 1972) using simulated power-reactor waste composed of nonradioactive chemicals and HLW from spent, Hanford reactor fuel. Thirty-three engineering-scale canisters of solidified HLW were produced during the operations. In early 79, the NWVP demonstrated the vitrification of HLW from the processing of actual commercial nuclear fuel. This program consisted of two parts, (1) waste preparation and (2) vitrification by spray calcination and in-can melting. This report presents results from the NWVP

  15. Threshold Assessment: Definition of Acceptable Sites as Part of Site Selection for the Japanese HLW Program

    International Nuclear Information System (INIS)

    McKenna, S.A.; Wakasugi, Keiichiro; Webb, E.K.; Makino, Hitoshi; Ishihara, Yoshinao; Ijiri, Yuji; Sawada, Atsushi; Baba, Tomoko; Ishiguro, Katsuhiko; Umeki, Hiroyuki

    2000-01-01

    For the last ten years, the Japanese High-Level Nuclear Waste (HLW) repository program has focused on assessing the feasibility of a basic repository concept, which resulted in the recently published H12 Report. As Japan enters the implementation phase, a new organization must identify, screen and choose potential repository sites. Thus, a rapid mechanism for determining the likelihood of site suitability is critical. The threshold approach, described here, is a simple mechanism for defining the likelihood that a site is suitable given estimates of several critical parameters. We rely on the results of a companion paper, which described a probabilistic performance assessment simulation of the HLW reference case in the H12 report. The most critical two or three input parameters are plotted against each other and treated as spatial variables. Geostatistics is used to interpret the spatial correlation, which in turn is used to simulate multiple realizations of the parameter value maps. By combining an array of realizations, we can look at the probability that a given site, as represented by estimates of this combination of parameters, would be good host for a repository site

  16. Mineral surface processes responsible for the decreased retardation (or enhanced mobilization) of 137Cs from HLW tank discharges. 1998 annual progress report

    International Nuclear Information System (INIS)

    Bertsch, P.M.; Zachara, J.M.

    1998-01-01

    'Cesium (137) is a major component of high level weapons waste. At Hanford, single shell tanks (SST''s) with high level wastes (HLW) have leaked supernate containing over 10 6 Ci of 137 Cs and other co-contaminants into the vadose zone. In select locations, 137 Cs has migrated further than expected from retardation experiments and performance assessment calculations. Deep 137 Cs migration has been observed beneath the SX tank farm at Hanford with REDOX wastes as the carrier causing regulatory and stakeholder concern. The causes for expedited migration are unclear. This research is investigating how the sorption chemistry of Cs on Hanford vadose zone sediments changes after contact with solutions characteristic of HLW. The central scientific hypothesis is that the high Na concentration of HLW will suppress surface-exchange reactions of Cs, except those to highly-selective frayed edge sites (FES) of the micaceous fraction. The authors further speculate that the concentrations, ion selectivity, and structural aspects of the FES will change after contact with HLW and that these changes will be manifest in the macroscopic sorption behavior of Cs. The authors believe that migration predictions of Cs can be improved substantially if such changes are understood and quantified. The research has three objectives: (1.) identify how the multi-component surface exchange behavior of Cs on Hanford sediments changes after contact with HLW simulants that span a range of relevant chemical (Na, OH, Al, K) and temperature conditions (23-80 C); (2) reconcile changes in sorption chemistry with microscopic and molecular changes in site distribution, chemistry, mineralogy, and surface structure of the micaceous fraction; (3) integrate mass-action-solution exchange measurements with changes in the structure/site distribution of the micaceous fraction to yield a multicomponent exchange model relevant to high ionic strength and hydroxide for prediction of environmental Cs sorption.'

  17. Brief historical perspective on the definition of high-level nuclear wastes

    International Nuclear Information System (INIS)

    Jacobs, D.G.; Szluha, A.T.; Gablin, K.A.; Croff, A.G.

    1985-03-01

    This report constitutes a historical perspective on the definition of HLW with emphasis on the US situation. The major HLW definitions are summarized chronologically, including a categorization of the considerations (e.g., waste source, heat generation rate, radiological effects) forming the bases of the definitions. High-level waste (HLW) definitions are then discussed in terms of these considerations. A brief discussion of the institutional aspects of HLW regulation and management are presented. An appendix to the report constitutes an annotated, chronological bibliography that formed the basis of the perspective

  18. Drop Calculations of HLW Canister and Pu Can-in-Canister

    International Nuclear Information System (INIS)

    Sreten Mastilovic

    2001-01-01

    The objective of this calculation is to determine the structural response of the standard high-level waste (HLW) canister and the canister containing the cans of immobilized plutonium (Pu) (''can-in-canister'' [CIC] throughout this document) subjected to drop DBEs (design basis events) during the handling operation. The evaluated DBE in the former case is 7-m (23-ft) vertical (flat-bottom) drop. In the latter case, two 2-ft (0.61-m) corner (oblique) drops are evaluated in addition to the 7-m vertical drop. These Pu CIC calculations are performed at three different temperatures: room temperature (RT) (20 C), T = 200 F = 93.3 C , and T = 400 F = 204 C ; in addition to these the calculation characterized by the highest maximum stress intensity is performed at T = 750 F = 399 C as well. The scope of the HLW canister calculation is limited to reporting the calculation results in terms of: stress intensity and effective plastic strain in the canister, directional residual strains at the canister outer surface, and change of canister dimensions. The scope of Pu CIC calculation is limited to reporting the calculation results in terms of stress intensity, and effective plastic strain in the canister. The information provided by the sketches from Reference 26 (Attachments 5.3,5.5,5.8, and 5.9) is that of the potential CIC design considered in this calculation, and all obtained results are valid for this design only. This calculation is associated with the Plutonium Immobilization Project and is performed by the Waste Package Design Section in accordance with Reference 24. It should be noted that the 9-m vertical drop DBE, included in Reference 24, is not included in the objective of this calculation since it did not become a waste acceptance requirement. AP-3.124, ''Calculations'', is used to perform the calculation and develop the document

  19. Small Scale Mixing Demonstration Batch Transfer and Sampling Performance of Simulated HLW - 12307

    Energy Technology Data Exchange (ETDEWEB)

    Jensen, Jesse; Townson, Paul; Vanatta, Matt [EnergySolutions, Engineering and Technology Group, Richland, WA, 99354 (United States)

    2012-07-01

    The ability to effectively mix, sample, certify, and deliver consistent batches of High Level Waste (HLW) feed from the Hanford Double Shell Tanks (DST) to the Waste treatment Plant (WTP) has been recognized as a significant mission risk with potential to impact mission length and the quantity of HLW glass produced. At the end of 2009 DOE's Tank Operations Contractor, Washington River Protection Solutions (WRPS), awarded a contract to EnergySolutions to design, fabricate and operate a demonstration platform called the Small Scale Mixing Demonstration (SSMD) to establish pre-transfer sampling capacity, and batch transfer performance data at two different scales. This data will be used to examine the baseline capacity for a tank mixed via rotational jet mixers to transfer consistent or bounding batches, and provide scale up information to predict full scale operational performance. This information will then in turn be used to define the baseline capacity of such a system to transfer and sample batches sent to WTP. The Small Scale Mixing Demonstration (SSMD) platform consists of 43'' and 120'' diameter clear acrylic test vessels, each equipped with two scaled jet mixer pump assemblies, and all supporting vessels, controls, services, and simulant make up facilities. All tank internals have been modeled including the air lift circulators (ALCs), the steam heating coil, and the radius between the wall and floor. The test vessels are set up to simulate the transfer of HLW out of a mixed tank, and collect a pre-transfer sample in a manner similar to the proposed baseline configuration. The collected material is submitted to an NQA-1 laboratory for chemical analysis. Previous work has been done to assess tank mixing performance at both scales. This work involved a combination of unique instruments to understand the three dimensional distribution of solids using a combination of Coriolis meter measurements, in situ chord length distribution

  20. Formulation of special glass frit and its use for decontamination of Joule melter employed for vitrification of high level and radioactive liquid waste

    International Nuclear Information System (INIS)

    Valsala, T.P.; Mishra, P.K.; Thakur, D.A.; Ghongane, D.E.; Jayan, R.V.; Dani, U.; Sonavane, M.S.; Kulkarni, Y.

    2012-01-01

    Advanced vitrification system at TWMP Tarapur was used for successful vitrification of large volume of HLW stored in waste tank farm. After completion of the operational life of the joule melter, dismantling was planned. Prior to the dismantling, the hold up inventory of active glass product from the melter was flushed out using specially formulated inactive glass frit to reduce the air activity buildup in the cell during dismantling operations. The properties of the special glass frit prepared are comparable with that of the regular product glass. More than 94% of holdup activity was flushed out from the joule melter prior to the dismantling of the melter. (author)

  1. Environmental risk assessment: its contribution to criteria development for HLW disposal

    International Nuclear Information System (INIS)

    Smith, G.M.; Little, R.H.; Watkins, B.M.

    1999-01-01

    Principles for radioactive waste management have been provided by the International Atomic Energy Agency in Safety Series No.111-F, which was published in 1995. This has been a major step forward in the process of achieving acceptance for proposals for disposal of radioactive waste, for example, for High Level Waste disposal in deep repositories. However, these principles have still to be interpreted and developed into practical radiation protection criteria. Without prejudicing final judgements on the acceptability of waste proposals, an important aspect is that practical demonstration of compliance (or the opposite) with these criteria must be possible. One of the IAEA principles requires that radioactive waste shall be managed in such a way as to provide an acceptable level of protection of the environment. There has been and continues to be considerable debate as to how to demonstrate compliance with such a principle. This paper briefly reviews the current status and considers how experience in other areas of environmental protection could contribute to criteria development for HLW disposal

  2. Idaho National Engineering Laboratory High-Level Waste Roadmap. Revision 2

    Energy Technology Data Exchange (ETDEWEB)

    1993-08-01

    The Idaho National Engineering Laboratory (INEL) High-Level Waste (HLW) Roadmap takes a strategic look at the entire HLW life-cycle starting with generation, through interim storage, treatment and processing, transportation, and on to final disposal. The roadmap is an issue-based planning approach that compares ``where we are now`` to ``where we want and need to be.`` The INEL has been effectively managing HLW for the last 30 years. Calcining operations are continuing to turn liquid HLW into a more manageable form. Although this document recognizes problems concerning HLW at the INEL, there is no imminent risk to the public or environment. By analyzing the INEL current business operations, pertinent laws and regulations, and committed milestones, the INEL HLW Roadmap has identified eight key issues existing at the INEL that must be resolved in order to reach long-term objectives. These issues are as follows: A. The US Department of Energy (DOE) needs a consistent policy for HLW generation, handling, treatment, storage, and disposal. B. The capability for final disposal of HLW does not exist. C. Adequate processes have not been developed or implemented for immobilization and disposal of INEL HLW. D. HLW storage at the INEL is not adequate in terms of capacity and regulatory requirements. E. Waste streams are generated with limited consideration for waste minimization. F. HLW is not adequately characterized for disposal nor, in some cases, for storage. G. Research and development of all process options for INEL HLW treatment and disposal are not being adequately pursued due to resource limitations. H. HLW transportation methods are not selected or implemented. A root-cause analysis uncovered the underlying causes of each of these issues.

  3. Modelling spent fuel and HLW behaviour in repository conditions

    Energy Technology Data Exchange (ETDEWEB)

    Esparza, A M; Esteban, J A

    2003-07-01

    The aim of this report is to give the reader an overall insight of the different models, which are used to predict the long-term behaviour of the spent fuels and HLW disposed in a repository. The models must be established on basic data and robust kinetics describing the mechanisms controlling spent fuel alteration/dissolution in a repository. The UO2 matrix, or source term, contains embedded in it the , majority of radionuclides of the spent fuel (some are in the gap cladding). For this reason the SF radionuclides release models play a significant role in the performance assessment of radioactive waste disposal. The differences existing between models published in the literature are due to the conceptual understanding of the processes and the degree of the conservatism used with the parameter values, and the boundary conditions. They mainly differ in their level of simplification and their final objective. Sometimes are focused the show compliance with regulatory requirements, other to support decision making, to increase the level of confidence of public and scientific community, could be empirical, semi-empirical or analytical. The models take into account the experimental results from radionuclides releases and their extrapolation to the very long term. Its necessary a great statistics for have a representative dissolution rate, due at the number of experimental results is not very high and many of them show a great scatter, independently of theirs different compositions by axial and radial variations, due to linear power or local burnup. On the other hand, it is difficult to predict the spent fuel behaviour over the long term, based in short term experiments. In this report is given a little description of the radionuclides distribution in the spent fuel and also in the cladding/pellet gap, grain boundary, cracks and rim zones (the matrix rim zone can be considered with an especial characteristics very different to the rest of the spent fuel), and structural

  4. Modelling spent fuel and HLW behaviour in repository conditions

    International Nuclear Information System (INIS)

    Esparza, A. M.; Esteban, J. A.

    2003-01-01

    The aim of this report is to give the reader an overall insight of the different models, which are used to predict the long-term behaviour of the spent fuels and HLW disposed in a repository. The models must be established on basic data and robust kinetics describing the mechanisms controlling spent fuel alteration/dissolution in a repository. The UO2 matrix, or source term, contains embedded in it the , majority of radionuclides of the spent fuel (some are in the gap cladding). For this reason the SF radionuclides release models play a significant role in the performance assessment of radioactive waste disposal. The differences existing between models published in the literature are due to the conceptual understanding of the processes and the degree of the conservatism used with the parameter values, and the boundary conditions. They mainly differ in their level of simplification and their final objective. Sometimes are focused the show compliance with regulatory requirements, other to support decision making, to increase the level of confidence of public and scientific community, could be empirical, semi-empirical or analytical. The models take into account the experimental results from radionuclides releases and their extrapolation to the very long term. Its necessary a great statistics for have a representative dissolution rate, due at the number of experimental results is not very high and many of them show a great scatter, independently of theirs different compositions by axial and radial variations, due to linear power or local burnup. On the other hand, it is difficult to predict the spent fuel behaviour over the long term, based in short term experiments. In this report is given a little description of the radionuclides distribution in the spent fuel and also in the cladding/pellet gap, grain boundary, cracks and rim zones (the matrix rim zone can be considered with an especial characteristics very different to the rest of the spent fuel), and structural

  5. Proposals of geological sites for L/ILW and HLW repositories. Geological background. Text volume

    International Nuclear Information System (INIS)

    2008-01-01

    On April 2008, the Swiss Federal Council approved the conceptual part of the Sectoral Plan for Deep Geological Repositories. The Plan sets out the details of the site selection procedure for geological repositories for low- and intermediate-level waste (L/ILW) and high-level waste (HLW). It specifies that selection of geological siting regions and sites for repositories in Switzerland will be conducted in three stages, the first one (the subject of this report) being the definition of geological siting regions within which the repository projects will be elaborated in more detail in the later stages of the Sectoral Plan. The geoscientific background is based on the one hand on an evaluation of the geological investigations previously carried out by Nagra on deep geological disposal of HLW and L/ILW in Switzerland (investigation programmes in the crystalline basement and Opalinus Clay in Northern Switzerland, investigations of L/ILW sites in the Alps, research in rock laboratories in crystalline rock and clay); on the other hand, new geoscientific studies have also been carried out in connection with the site selection process. Formulation of the siting proposals is conducted in five steps: A) In a first step, the waste inventory is allocated to the L/ILW and HLW repositories; B) The second step involves defining the barrier and safety concepts for the two repositories. With a view to evaluating the geological siting possibilities, quantitative and qualitative guidelines and requirements on the geology are derived on the basis of these concepts. These relate to the time period to be considered, the space requirements for the repository, the properties of the host rock (depth, thickness, lateral extent, hydraulic conductivity), long-term stability, reliability of geological findings and engineering suitability; C) In the third step, the large-scale geological-tectonic situation is assessed and large-scale areas that remain under consideration are defined. For the L

  6. Status Of The Development Of In-Tank/At-Tank Separations Technologies For High-Level Waste Processing For The U.S. Department Of Energy

    International Nuclear Information System (INIS)

    Aaron, G.; Wilmarth, B.

    2011-01-01

    Within the U.S. Department of Energy's (DOE) Office of Technology Innovation and Development, the Office of Waste Processing manages a research and development program related to the treatment and disposition of radioactive waste. At the Savannah River (South Carolina) and Hanford (Washington) Sites, approximately 90 million gallons of waste are distributed among 226 storage tanks (grouped or collocated in 'tank farms'). This waste may be considered to contain mixed and stratified high activity and low activity constituent waste liquids, salts and sludges that are collectively managed as high level waste (HLW). A large majority of these wastes and associated facilities are unique to the DOE, meaning many of the programs to treat these materials are 'first-of-a-kind' and unprecedented in scope and complexity. As a result, the technologies required to disposition these wastes must be developed from basic principles, or require significant re-engineering to adapt to DOE's specific applications. Of particular interest recently, the development of In-tank or At-Tank separation processes have the potential to treat waste with high returns on financial investment. The primary objective associated with In-Tank or At-Tank separation processes is to accelerate waste processing. Insertion of the technologies will (1) maximize available tank space to efficiently support permanent waste disposition including vitrification; (2) treat problematic waste prior to transfer to the primary processing facilities at either site (i.e., Hanford's Waste Treatment and Immobilization Plant (WTP) or Savannah River's Salt Waste Processing Facility (SWPF)); and (3) create a parallel treatment process to shorten the overall treatment duration. This paper will review the status of several of the R and D projects being developed by the U.S. DOE including insertion of the ion exchange (IX) technologies, such as Small Column Ion Exchange (SCIX) at Savannah River. This has the potential to align the

  7. Siting Process for HLW Repository in Japan

    International Nuclear Information System (INIS)

    Masuda, S.; Kitayama, K.; Umeki, H.; Naito, M.

    2002-01-01

    In the year 2000, the geological disposal program for high-level radioactive waste in Japan moved from the phase of generic research and development (R and D) into the phase of implementation. Following legislation entitled the ''Specified Radioactive Waste Final Disposal Act'', the Nuclear Waste Management Organization of Japan (NUMO) was established as the implementing organization. The assigned activities of NUMO include selection of the repository site, demonstration of disposal technology at the site, developing relevant licensing applications and construction, operation and closure of the repository. As the first milestone of siting process, NUMO announced to the public an overall procedure for selection of preliminary investigation areas for potential candidate sites on October 29, 2001. The procedure specifies that NUMO will solicit volunteer municipalities for preliminary investigation areas with publishing four documents as an information package. These documents are tentatively entitled ''Instructions for Application'', ''Siting Factors for the Preliminary Investigation Areas'', a ''Repository Concepts'' as well as an ''Site Investigation Community Outreach Scheme''

  8. Tank Waste Remediation System optimized processing strategy

    International Nuclear Information System (INIS)

    Slaathaug, E.J.; Boldt, A.L.; Boomer, K.D.; Galbraith, J.D.; Leach, C.E.; Waldo, T.L.

    1996-03-01

    This report provides an alternative strategy evolved from the current Hanford Site Tank Waste Remediation System (TWRS) programmatic baseline for accomplishing the treatment and disposal of the Hanford Site tank wastes. This optimized processing strategy performs the major elements of the TWRS Program, but modifies the deployment of selected treatment technologies to reduce the program cost. The present program for development of waste retrieval, pretreatment, and vitrification technologies continues, but the optimized processing strategy reuses a single facility to accomplish the separations/low-activity waste (LAW) vitrification and the high-level waste (HLW) vitrification processes sequentially, thereby eliminating the need for a separate HLW vitrification facility

  9. Radioactive waste management

    International Nuclear Information System (INIS)

    Tsoulfanidis, N.

    1991-01-01

    The management of radioactive waste is a very important part of the nuclear industry. The future of the nuclear power industry depends to a large extent on the successful solution of the perceived or real problems associated with the disposal of both low-level waste (LLW) and high-level waste (HLW). All the activities surrounding the management of radioactive waste are reviewed. The federal government and the individual states are working toward the implementation of the Nuclear Waste Policy Act and the Low-Level Waste Policy Act. The two congressional acts are reviewed and progress made as of early 1990 is presented. Spent-fuel storage and transportation are discussed in detail as are the concepts of repositories for HLW. The status of state compacts for LLW is also discussed. Finally, activities related to the decommissioning of nuclear facilities are also described

  10. The systems approach to spent fuel and high level nuclear waste management

    International Nuclear Information System (INIS)

    Norman, N.A.

    1987-01-01

    Based on the prior successful experience in the application of systems engineering techniques to large, complex, multi-participant programs the U.S. DOE has elected to apply the systems engineering process to the U.S. High Level Nuclear Waste Management Program (HLNWMP). Features of the systems engineering process as it applies to the U.S. HLNWMP and the importance of the component interdependencies are descirbed. Four principle components of the U.S. HLW Managment System are also given. They are the reactors or defense sources, transportation system, interium storoge modes, and the final repository. (Huang)

  11. KAERI Underground Research Facility (KURF) for the Demonstration of HLW Disposal Technology

    International Nuclear Information System (INIS)

    Hahn, P. S.; Cho, W. J.; Kwon, S.

    2006-01-01

    In order to dispose of high-level radioactive waste(HLW) safely in geological formations, it is necessary to assess the feasibility, safety, appropriateness, and stability of the disposal concept at an underground research site, which is constructed in the same geological formation as the host rock. In this paper, the current status of the conceptual design and the construction of a small scale URL, which is named as KURF, were described. To confirm the validity of the conceptual design of the underground facility, a geological survey including a seismic refraction survey, an electronic resistivity survey, a borehole drilling, and in situ and laboratory tests had been carried out. Based on the site characterization results, it was possible to effectively design the KURF. The construction of the KURF was started in May 2005 and the access tunnel was successfully completed in March 2006. Now the construction of the research modules is under way

  12. An Ilustrative Nuclide Release Behavior from an HLW Repository due to an Earthquake Event

    International Nuclear Information System (INIS)

    Lee, Youn-Myoung; Hwang, Yong-Soo; Choi, Jong-Won

    2008-01-01

    Program for the evaluation of a high-level waste repository which is conceptually modeled. During the last few years, programs developed with the aid of AMBER and GoldSim by which nuclide transports in the near- and far-field of a repository as well as transport through the biosphere under various normal and disruptive release scenarios could be modeled and evaluated, have been continuously demonstrated. To show its usability, as similarly done for the natural groundwater flow scheme, influence of a possible disruptive event on a nuclide release behavior from an HLW repository system caused naturally due to an earthquake has been investigated and illustrated with the newly developed GoldSim program

  13. Assessment of dose conversion factors in a generic biosphere of a Korea HLW repository

    International Nuclear Information System (INIS)

    Hwang, Y. S.; Park, J. B.; Kang, C. H.

    2002-01-01

    Radioactive species released from a waste repository migrate through engineered and natural barriers and eventually reach the biosphere. Once entered the biosphere, contaminants transport various exposure pathways and finally reach a human. In this study the full RES matrix explaining the key compartments in the biosphere and their interactions is introduced considering the characteristics of the Korean biosphere. Then the three exposure groups are identified based on the compartments of interest. The full exposure pathways and corresponding mathematical expression for mass transfer coefficients and etc are developed and applied to assess the dose conversion factors of nuclides for a specific exposure group. Dose conversion factors assessed in this study will be used for total system performance assessment of a potential Korean HLW repository

  14. Initiating the Validation of CCIM Processability for Multi-phase all Ceramic (SYNROC) HLW Form: Plan for Test BFY14CCIM-C

    Energy Technology Data Exchange (ETDEWEB)

    Maio, Vince [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2014-08-01

    This plan covers test BFY14CCIM-C which will be a first–of–its-kind demonstration for the complete non-radioactive surrogate production of multi-phase ceramic (SYNROC) High Level Waste Forms (HLW) using Cold Crucible Induction Melting (CCIM) Technology. The test will occur in the Idaho National Laboratory’s (INL) CCIM Pilot Plant and is tentatively scheduled for the week of September 15, 2014. The purpose of the test is to begin collecting qualitative data for validating the ceramic HLW form processability advantages using CCIM technology- as opposed to existing ceramic–lined Joule Heated Melters (JHM) currently producing BSG HLW forms. The major objectives of BFY14CCIM-C are to complete crystalline melt initiation with a new joule-heated resistive starter ring, sustain inductive melting at temperatures between 1600 to 1700°C for two different relatively high conductive materials representative of the SYNROC ceramic formation inclusive of a HLW surrogate, complete melter tapping and pouring of molten ceramic material in to a preheated 4 inch graphite canister and a similar canister at room temperature. Other goals include assessing the performance of a new crucible specially designed to accommodate the tapping and pouring of pure crystalline forms in contrast to less recalcitrant amorphous glass, assessing the overall operational effectiveness of melt initiation using a resistive starter ring with a dedicated power source, and observing the tapped molten flow and subsequent relatively quick crystallization behavior in pans with areas identical to standard HLW disposal canisters. Surrogate waste compositions with ceramic SYNROC forming additives and their measured properties for inductive melting, testing parameters, pre-test conditions and modifications, data collection requirements, and sampling/post-demonstration analysis requirements for the produced forms are provided and defined.

  15. WTP Waste Feed Qualification: Glass Fabrication Unit Operation Testing Report

    Energy Technology Data Exchange (ETDEWEB)

    Stone, M. E. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL). Hanford Missions Programs; Newell, J. D. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL). Process Technology Programs; Johnson, F. C. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL). Engineering Process Development; Edwards, T. B. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL). Engineering Process Development

    2016-07-14

    The waste feed qualification program is being developed to protect the Hanford Tank Waste Treatment and Immobilization Plant (WTP) design, safety basis, and technical basis by assuring waste acceptance requirements are met for each staged waste feed campaign prior to transfer from the Tank Operations Contractor to the feed receipt vessels inside the Pretreatment Facility. The Waste Feed Qualification Program Plan describes the three components of waste feed qualification: 1. Demonstrate compliance with the waste acceptance criteria 2. Determine waste processability 3. Test unit operations at laboratory scale. The glass fabrication unit operation is the final step in the process demonstration portion of the waste feed qualification process. This unit operation generally consists of combining each of the waste feed streams (high-level waste (HLW) and low-activity waste (LAW)) with Glass Forming Chemicals (GFCs), fabricating glass coupons, performing chemical composition analysis before and after glass fabrication, measuring hydrogen generation rate either before or after glass former addition, measuring rheological properties before and after glass former addition, and visual observation of the resulting glass coupons. Critical aspects of this unit operation are mixing and sampling of the waste and melter feeds to ensure representative samples are obtained as well as ensuring the fabrication process for the glass coupon is adequate. Testing was performed using a range of simulants (LAW and HLW simulants), and these simulants were mixed with high and low bounding amounts of GFCs to evaluate the mixing, sampling, and glass preparation steps in shielded cells using laboratory techniques. The tests were performed with off-the-shelf equipment at the Savannah River National Laboratory (SRNL) that is similar to equipment used in the SRNL work during qualification of waste feed for the Defense Waste Processing Facility (DWPF) and other waste treatment facilities at the

  16. The basic corrosion mechanisms of HLW glasses

    International Nuclear Information System (INIS)

    Conradt, R.; Roggendorf, H.; Ostertag, R.

    1986-01-01

    During the years 1975 to 1984, the Commission of the European Communities organized and promoted an R and D programme on the testing and evaluation of solidified high-level waste forms with the purpose of providing a scientific basis for the management and storage of radioactive waste. A fair number of materials were tested under a broad variation of experimental data. The Fraunhofer-Institut fuer Silicatforschung, Wuerzburg, has undertaken to perform a synoptic evaluation of the above data. The purpose of this evaluation is: - to compile the data from the individual national contributors (as presented in the joint annual reports of the EC) with respect to: the materials, or the experimental parameters, or further aspects, and to harmonize them with respect to their presentation, choice of units, etc., - to compare the results to the international state of information, - to elaborate and demonstrate common features of the diverse materials, e.g. common patterns of the corrosion behaviour, - to check the validity of present models, - to define shortcomings and questions that are still open

  17. Natural analogue of redox front formation in near-field environment at post-closure phase of HLW geological disposal

    International Nuclear Information System (INIS)

    Yoshida, Hidekazu; Yamamoto, Koushi; Amano, Yuki

    2005-01-01

    Redox fronts are created in the near field of rocks, in a range of oxidation environments, by microbial activity in rock groundwater. Such fronts, and the associated oxide formation, are usually unavoidable around high level radioactive waste (HLW) repositories, whatever their design. The long term behaviour of these oxides after repositories have been closed is however little known. Here we introduce an analogue of redox front formation, such as 'iron oxide' deposits, known as takashikozo forming cylindrical nodules, and the long term behaviour of secondarily formed iron oxyhydroxide in subsequent geological environments. (author)

  18. Advances in Glass Formulations for Hanford High-Aluminum, High-Iron and Enhanced Sulphate Management in HLW Streams - 13000

    Energy Technology Data Exchange (ETDEWEB)

    Kruger, Albert A. [WTP Engineering Division, United States Department of Energy, Office of River Protection, Post Office Box 450, Richland, Washington 99352 (United States)

    2013-07-01

    The current estimates and glass formulation efforts have been conservative in terms of achievable waste loadings. These formulations have been specified to ensure that the glasses are homogenous, contain essentially no crystalline phases, are processable in joule-heated, ceramic-lined melters and meet Hanford Tank Waste Treatment and Immobilization Plant (WTP) Contract terms. The WTP's overall mission will require the immobilization of tank waste compositions that are dominated by mixtures of aluminum (Al), chromium (Cr), bismuth (Bi), iron (Fe), phosphorous (P), zirconium (Zr), and sulphur (S) compounds as waste-limiting components. Glass compositions for these waste mixtures have been developed based upon previous experience and current glass property models. Recently, DOE has initiated a testing program to develop and characterize HLW glasses with higher waste loadings and higher throughput efficiencies. Results of this work have demonstrated the feasibility of increases in waste loading from about 25 wt% to 33-50 wt% (based on oxide loading) in the glass depending on the waste stream. In view of the importance of aluminum limited waste streams at Hanford (and also Savannah River), the ability to achieve high waste loadings without adversely impacting melt rates has the potential for enormous cost savings from reductions in canister count and the potential for schedule acceleration. Consequently, the potential return on the investment made in the development of these enhancements is extremely favorable. Glass composition development for one of the latest Hanford HLW projected compositions with sulphate concentrations high enough to limit waste loading have been successfully tested and show tolerance for previously unreported tolerance for sulphate. Though a significant increase in waste loading for high-iron wastes has been achieved, the magnitude of the increase is not as substantial as those achieved for high-aluminum, high-chromium, high-bismuth or

  19. Concept development for HLW disposal research tunnel

    International Nuclear Information System (INIS)

    Queon, S. K.; Kim, K. S.; Park, J. H.; Jeo, W. J.; Han, P. S.

    2003-01-01

    In order to dispose high-level radioactive waste in a geological formation, it is necessary to assess the safety of a disposal concept by excavating a research tunnel in the same geological formation as the host rock mass. The design concept of a research tunnel depends on the actual disposal concept, repository geometry, experiments to be carried at the tunnel, and geological conditions. In this study, analysis of the characteristics of the disposal research tunnel, which is planned to be constructed at KAERI site, calculation of the influence of basting impact on neighbor facilities, and computer simuation for mechanical stability analysis using a three-dimensional code, FLAC3D, had been carried out to develop the design concept of the research tunnel

  20. A methodology of uncertainty/sensitivity analysis for PA of HLW repository learned from 1996 WIPP performance assessment

    International Nuclear Information System (INIS)

    Lee, Y. M.; Kim, S. K.; Hwang, Y. S.; Kang, C. H.

    2002-01-01

    The WIPP (Waste Isolation Pilot Plant) is a mined repository constructed by the US DOE for the permanent disposal of transuranic (TRU) wastes generated by activities related to defence of the US since 1970. Its historical disposal operation began in March 1999 following receipt of a final permit from the State of NM after a positive certification decision for the WIPP was issued by the EPA in 1998, as the first licensed facility in the US for the deep geologic disposal of radioactive wastes. The CCA (Compliance Certification Application) for the WIPP that the DOE submitted to the EPA in 1966 was supported by an extensive Performance Assessment (PA) carried out by Sandia National Laboratories (SNL), with so-called 1996 PA. Even though such PA methodologies could be greatly different from the way we consider for HLW disposal in Korea largely due to quite different geologic formations in which repository are likely to be located, a review on lots of works done through the WIPP PA studies could be the most important lessons that we can learn from in view of current situation in Korea where an initial phase of conceptual studies on HLW disposal has been just started. The objective of this work is an overview of the methodology used in the recent WIPP PA to support the US DOE WIPP CCA ans a proposal for Korean case

  1. Groundwater impacts of foreseeable human activities on a HLW repository

    International Nuclear Information System (INIS)

    Coleman, N.M.

    1993-01-01

    The Nuclear Regulatory Commission (NRC) staff has begun a program of Systematic Regulatory Analysis (SRA) to help ensure that all important technical issues related to the disposal of civilian, high-level nuclear wastes will be identified prior to the receipt of a license application. Large-scale groundwater withdrawals near a repository could have significant impacts on the groundwater flow system. Future large-scale withdrawals of groundwater could occur to support irrigation to growing population centers, such as Las Vegas. Various scenarios of groundwater withdrawals, along with other scenarios of future human activity, will need to be tested before evaluation of the Yucca Mountain site is complete

  2. Rheology of Savannah River site tank 42 and tank 51 HLW radioactive sludges

    International Nuclear Information System (INIS)

    Ha, B.C.; Bibler, N.E.

    1996-01-01

    Knowledge of the rheology of the radioactive sludge slurries at the Savannah River Site (SRS) is necessary in order to ensure that they can be retrieved from waste tanks and processed for final disposal. The high activity radioactive wastes stored as caustic slurries at SRS result from the neutralization of acid waste generated from production of nuclear defense materials. During storage, the wastes separate into a supernate layer and a sludge layer. In the Defense Waste Processing Facility (DWPF) at SRS, the radionuclides from the sludge and supernate will be immobilized into borosilicate glass for long term storage and eventual disposal. Before transferring the waste from a storage tank to the DWPF, a portion of the aluminum in the waste sludge will be dissolved and the sludge will be extensively washed to remove sodium. Tank 51 and Tank 42 radioactive sludges represent the first batch of HLW sludge to be processed in the DWPF. This paper presents results of rheology measurements of Tank 51 and Tank 42 at various solids concentrations. The rheologies of Tank 51 and Tank 42 radioactive slurries were measured remotely in the Shielded Cells Operations (SCO) at the Savannah River Technology Center (SRTC) using a modified Haake Rotovisco RV-12 with an M150 measuring drive unit and TI sensor system. Rheological properties of the Tank 51 and Tank 42 radioactive sludges were measured as a function of weight percent solids. The weight percent solids of Tank 42 sludge was 27, as received. Tank 51 sludge had already been washed. The weight percent solids were adjusted by dilution with water or by concentration through drying. At 12, 15, and 18 weight percent solids, the yield stresses of Tank 51 sludge were 5, 11, and 14 dynes/cm2, respectively. The apparent viscosities were 6, 10, and 12 centipoises at 300 sec-1 shear rate, respectively

  3. Supplemental Immobilization Cast Stone Technology Development and Waste Form Qualification Testing Plan

    Energy Technology Data Exchange (ETDEWEB)

    Westsik, Joseph H. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Serne, R. Jeffrey [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Pierce, Eric M. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Cozzi, Alex [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Chung, Chul-Woo [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Swanberg, David J. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2013-05-31

    The Hanford Tank Waste Treatment and Immobilization Plant (WTP) is being constructed to treat the 56 million gallons of radioactive waste stored in 177 underground tanks at the Hanford Site. The WTP includes a pretreatment facility to separate the wastes into high-level waste (HLW) and low-activity waste (LAW) fractions for vitrification and disposal. The LAW will be converted to glass for final disposal at the Integrated Disposal Facility (IDF). The pretreatment facility will have the capacity to separate all of the tank wastes into the HLW and LAW fractions, and the HLW Vitrification Facility will have the capacity to vitrify all of the HLW. However, a second immobilization facility will be needed for the expected volume of LAW requiring immobilization. A number of alternatives, including Cast Stone—a cementitious waste form—are being considered to provide the additional LAW immobilization capacity.

  4. Management strategy for site characterization at candidate HLW repository sites

    International Nuclear Information System (INIS)

    Bartlett, J.W.

    1988-01-01

    This paper describes a management strategy for HLW repository site characterization which is aimed at producing an optimal characterization trajectory for site suitability and licensing evaluations. The core feature of the strategy is a matrix of alternative performance targets and alternative information-level targets which can be used to allocate and justify program effort. Strategies for work concerning evaluation of expected and disrupted repository performance are distinguished, and the need for issue closure criteria is discussed

  5. Separation, Concentration, and Immobilization of Technetium and Iodine from Alkaline Supernate Waste

    Energy Technology Data Exchange (ETDEWEB)

    James Harvey; Michael Gula

    1998-12-07

    Development of remediation technologies for the characterization, retrieval, treatment, concentration, and final disposal of radioactive and chemical tank waste stored within the Department of Energy (DOE) complex represents an enormous scientific and technological challenge. A combined total of over 90 million gallons of high-level waste (HLW) and low-level waste (LLW) are stored in 335 underground storage tanks at four different DOE sites. Roughly 98% of this waste is highly alkaline in nature and contains high concentrations of nitrate and nitrite salts along with lesser concentrations of other salts. The primary waste forms are sludge, saltcake, and liquid supernatant with the bulk of the radioactivity contained in the sludge, making it the largest source of HLW. The saltcake (liquid waste with most of the water removed) and liquid supernatant consist mainly of sodium nitrate and sodium hydroxide salts. The main radioactive constituent in the alkaline supernatant is cesium-137, but strontium-90, technetium-99, and transuranic nuclides are also present in varying concentrations. Reduction of the radioactivity below Nuclear Regulatory Commission (NRC) limits would allow the bulk of the waste to be disposed of as LLW. Because of the long half-life of technetium-99 (2.1 x 10 5 y) and the mobility of the pertechnetate ion (TcO 4 - ) in the environment, it is expected that technetium will have to be removed from the Hanford wastes prior to disposal as LLW. Also, for some of the wastes, some level of technetium removal will be required to meet LLW criteria for radioactive content. Therefore, DOE has identified a need to develop technologies for the separation and concentration of technetium-99 from LLW streams. Eichrom has responded to this DOE-identified need by demonstrating a complete flowsheet for the separation, concentration, and immobilization of technetium (and iodine) from alkaline supernatant waste.

  6. 75 FR 81037 - Waste Confidence Decision Update

    Science.gov (United States)

    2010-12-23

    ... radioactive wastes produced by NPPs ``can be safely disposed of, to determine when such disposal or offsite... safe permanent disposal of high-level radioactive waste (HLW) would be available when they were needed... proceedings designed to assess the degree of assurance that radioactive wastes generated by nuclear power...

  7. DETERMINATION OF HLW GLASS MELT RATE USING X-RAY COMPUTED TOMOGRAPHY

    Energy Technology Data Exchange (ETDEWEB)

    Choi, A.; Miller, D.; Immel, D.

    2011-10-06

    The purpose of the high-level waste (HLW) glass melt rate study is two-fold: (1) to gain a better understanding of the impact of feed chemistry on melt rate through bench-scale testing, and (2) to develop a predictive tool for melt rate in support of the on-going frit development efforts for the Defense Waste Processing Facility (DWPF). In particular, the focus is on predicting relative melt rates, not the absolute melt rates, of various HLW glass formulations solely based on feed chemistry, i.e., the chemistry of both waste and glass-forming frit for DWPF. Critical to the successful melt rate modeling is the accurate determination of the melting rates of various HLW glass formulations. The baseline procedure being used at the Savannah River National Laboratory (SRNL) is to; (1) heat a 4 inch-diameter stainless steel beaker containing a mixture of dried sludge and frit in a furnace for a preset period of time, (2) section the cooled beaker along its diameter, and (3) measure the average glass height across the sectioned face using a ruler. As illustrated in Figure 1-1, the glass height is measured for each of the 16 horizontal segments up to the red lines where relatively large-sized bubbles begin to appear. The linear melt rate (LMR) is determined as the average of all 16 glass height readings divided by the time during which the sample was kept in the furnace. This 'visual' method has proved useful in identifying melting accelerants such as alkalis and sulfate and further ranking the relative melt rates of candidate frits for a given sludge batch. However, one of the inherent technical difficulties of this method is to determine the glass height in the presence of numerous gas bubbles of varying sizes, which is prevalent especially for the higher-waste-loading glasses. That is, how the red lines are drawn in Figure 1-1 can be subjective and, therefore, may influence the resulting melt rates significantly. For example, if the red lines are drawn too low

  8. Lithological suitability for HLW repository in Korea

    International Nuclear Information System (INIS)

    Kim, C.S.; Bae, D.S.; Kim, K.S.; Koh, Y.K.

    2001-01-01

    Regional geologic conditions of Korea were summarized with emphasis on rock mass and fracture system as a part of the research program for high level radioactive wastes disposal. The eastern margin of the Korea-China platform has been regarded as stable crotonic nature. The Mesozoic tectonic activities followed by igneous intrusion were the most vigorous crustal movement in the entire Korean peninsula. During the Jurassic-Cretaceous orogeny (180-130 Ma Bp), igneous activity resulted in forming a large batholith of Dab granitic rock (Jurassic granite). Rejuvenized igneous activities during the Cretaceous period formed the Bulguksa granite which are associated with felsic volcanic rocks and NE-SW/NNE-SSW geologic structures. The primary host rock is considered to be Daebo granite batholiths intruded in the geologic age of late Triassic to early Jurassic (205±15 Ma). The emplacement depths are in the range of 10-20 km and the crystallization occurs under the geopressure of 3∼7 kb. (author)

  9. Final waste management programmatic environmental impact statement for managing treatment, storage, and disposal of radioactive and hazardous waste. Summary

    International Nuclear Information System (INIS)

    1997-05-01

    This Waste Management Programmatic Environmental Impact Statement (WM PEIS) is a nationwide study examining the environmental impacts of managing five types of radioactive and hazardous wastes generated by past and future nuclear defense and research activities at a variety of sites located around the United States. The five waste types are low-level mixed waste (LLMW), low-level waste (LLW), transuranic waste (TRUW), high-level waste (HLW), and hazardous waste (HW)

  10. FINAL REPORT REGULATORY OFF GAS EMISSIONS TESTING ON THE DM1200 MELTER SYSTEM USING HLW AND LAW SIMULANTS VSL-05R5830-1 REV 0 10/31/05

    Energy Technology Data Exchange (ETDEWEB)

    KRUGER AA; MATLACK KS; GONG W; BARDAKCI T; D' ANGELO NA; BRANDYS M; KOT WK; PEGG IL

    2011-12-29

    The operational requirements for the River Protection Project - Waste Treatment Plant (RPP-WTP) Low Activity Waste (LAW) and High Level Waste (HLW) melter systems, together with the feed constituents, impose a number of challenges to the off-gas treatment system. The system must be robust from the standpoints of operational reliability and minimization of maintenance. The system must effectively control and remove a wide range of solid particulate matter, acid mists and gases, and organic constituents (including those arising from products of incomplete combustion of sugar and organics in the feed) to concentration levels below those imposed by regulatory requirements. The baseline design for the RPP-WTP LAW primary off-gas system includes a submerged bed scrubber (SBS), a wet electrostatic precipitator (WESP), and a high efficiency particulate air (HEPA) filter. The secondary off-gas system includes a sulfur-impregnated activated carbon bed (AC-S), a thermal catalytic oxidizer (TCO), a single-stage selective catalytic reduction NOx treatment system (SCR), and a packed-bed caustic scrubber (PBS). The baseline design for the RPP-WTP HLW primary off-gas system includes an SBS, a WESP, a high efficiency mist eliminator (HEME), and a HEPA filter. The HLW secondary off-gas system includes a sulfur-impregnated activated carbon bed, a silver mordenite bed, a TCO, and a single-stage SCR. The one-third scale HLW DM1200 Pilot Melter installed at the Vitreous State Laboratory (VSL) was equipped with a prototypical off-gas train to meet the needs for testing and confirmation of the performance of the baseline off-gas system design. Various modifications have been made to the DM1200 system as the details of the WTP design have evolved, including the installation of a silver mordenite column and an AC-S column for testing on a slipstream of the off-gas flow; the installation of a full-flow AC-S bed for the present tests was completed prior to initiation of testing. The DM1200

  11. Optimizing High Level Waste Disposal

    International Nuclear Information System (INIS)

    Dirk Gombert

    2005-01-01

    If society is ever to reap the potential benefits of nuclear energy, technologists must close the fuel-cycle completely. A closed cycle equates to a continued supply of fuel and safe reactors, but also reliable and comprehensive closure of waste issues. High level waste (HLW) disposal in borosilicate glass (BSG) is based on 1970s era evaluations. This host matrix is very adaptable to sequestering a wide variety of radionuclides found in raffinates from spent fuel reprocessing. However, it is now known that the current system is far from optimal for disposal of the diverse HLW streams, and proven alternatives are available to reduce costs by billions of dollars. The basis for HLW disposal should be reassessed to consider extensive waste form and process technology research and development efforts, which have been conducted by the United States Department of Energy (USDOE), international agencies and the private sector. Matching the waste form to the waste chemistry and using currently available technology could increase the waste content in waste forms to 50% or more and double processing rates. Optimization of the HLW disposal system would accelerate HLW disposition and increase repository capacity. This does not necessarily require developing new waste forms, the emphasis should be on qualifying existing matrices to demonstrate protection equal to or better than the baseline glass performance. Also, this proposed effort does not necessarily require developing new technology concepts. The emphasis is on demonstrating existing technology that is clearly better (reliability, productivity, cost) than current technology, and justifying its use in future facilities or retrofitted facilities. Higher waste processing and disposal efficiency can be realized by performing the engineering analyses and trade-studies necessary to select the most efficient methods for processing the full spectrum of wastes across the nuclear complex. This paper will describe technologies being

  12. Waste-Mixes Study for space disposal

    International Nuclear Information System (INIS)

    McCallum, R.F.; Blair, H.T.; McKee, R.W.; Silviera, D.J.; Swanson, J.L.

    1983-01-01

    The Wastes Mixes Study is a component of Cy-1981 and 1982 research activities to determine if space disposal could be a feasible complement to geologic disposal for certain high-level (HLW) and transuranic wastes (TRU). The objectives of the study are: to determine if removal of radionuclides from HLW and TRU significantly reduces the long-term radiological risks of geologic disposal; to determine if chemical partitioning of the waste for space disposal is technically feasible; to identify acceptable waste forms for space disposal; and to compare improvements in geologic disposal system performance to impacts of additional treatment, storage, and transportation necessary for space disposal. To compare radiological effects, five system alternatives are defined: Reference case - All HLW and TRU to a repository. Alternative A - Iodine to space, the balance to a repository. Alternative B - Technetium to space, the balance to a repository. Alternative C - 95% of cesium and strontium to a repository; the balance of HLW aged first, then to space; plutonium separated from TRU for recycle; the balance of the TRU to a repository. Alternative D - HLW aged first, then to space, plutonium separated from TRU for recycle; the balance of the TRU to a repository. The conclusions of this study are: the incentive for space disposal is that it offers a perception of reduced risks rather than significant reduction. Suitable waste forms for space disposal are cermet for HLW, metallic technetium, and lead iodide. Space disposal of HLW appears to offer insignificant safety enhancements when compared to geologic disposal; the disposal of iodine and technetium wastes in space does not offer risk advantages. Increases in short-term doses for the alternatives are minimal; however, incremental costs of treating, storing and transporting wastes for space disposal are substantial

  13. High-level waste melter alternatives assessment report

    Energy Technology Data Exchange (ETDEWEB)

    Calmus, R.B.

    1995-02-01

    This document describes the Tank Waste Remediation System (TWRS) High-Level Waste (HLW) Program`s (hereafter referred to as HLW Program) Melter Candidate Assessment Activity performed in fiscal year (FY) 1994. The mission of the TWRS Program is to store, treat, and immobilize highly radioactive Hanford Site waste (current and future tank waste and encapsulated strontium and cesium isotopic sources) in an environmentally sound, safe, and cost-effective manner. The goal of the HLW Program is to immobilize the HLW fraction of pretreated tank waste into a vitrified product suitable for interim onsite storage and eventual offsite disposal at a geologic repository. Preparation of the encapsulated strontium and cesium isotopic sources for final disposal is also included in the HLW Program. As a result of trade studies performed in 1992 and 1993, processes planned for pretreatment of tank wastes were modified substantially because of increasing estimates of the quantity of high-level and transuranic tank waste remaining after pretreatment. This resulted in substantial increases in needed vitrification plant capacity compared to the capacity of original Hanford Waste Vitrification Plant (HWVP). The required capacity has not been finalized, but is expected to be four to eight times that of the HWVP design. The increased capacity requirements for the HLW vitrification plant`s melter prompted the assessment of candidate high-capacity HLW melter technologies to determine the most viable candidates and the required development and testing (D and T) focus required to select the Hanford Site HLW vitrification plant melter system. An assessment process was developed in early 1994. This document describes the assessment team, roles of team members, the phased assessment process and results, resulting recommendations, and the implementation strategy.

  14. High-level waste melter alternatives assessment report

    International Nuclear Information System (INIS)

    Calmus, R.B.

    1995-02-01

    This document describes the Tank Waste Remediation System (TWRS) High-Level Waste (HLW) Program's (hereafter referred to as HLW Program) Melter Candidate Assessment Activity performed in fiscal year (FY) 1994. The mission of the TWRS Program is to store, treat, and immobilize highly radioactive Hanford Site waste (current and future tank waste and encapsulated strontium and cesium isotopic sources) in an environmentally sound, safe, and cost-effective manner. The goal of the HLW Program is to immobilize the HLW fraction of pretreated tank waste into a vitrified product suitable for interim onsite storage and eventual offsite disposal at a geologic repository. Preparation of the encapsulated strontium and cesium isotopic sources for final disposal is also included in the HLW Program. As a result of trade studies performed in 1992 and 1993, processes planned for pretreatment of tank wastes were modified substantially because of increasing estimates of the quantity of high-level and transuranic tank waste remaining after pretreatment. This resulted in substantial increases in needed vitrification plant capacity compared to the capacity of original Hanford Waste Vitrification Plant (HWVP). The required capacity has not been finalized, but is expected to be four to eight times that of the HWVP design. The increased capacity requirements for the HLW vitrification plant's melter prompted the assessment of candidate high-capacity HLW melter technologies to determine the most viable candidates and the required development and testing (D and T) focus required to select the Hanford Site HLW vitrification plant melter system. An assessment process was developed in early 1994. This document describes the assessment team, roles of team members, the phased assessment process and results, resulting recommendations, and the implementation strategy

  15. Licensing information needs for a high-level waste repository

    International Nuclear Information System (INIS)

    Wright, R.J.; Greeves, J.T.; Logsdon, M.J.

    1985-01-01

    The information needs for licensing findings during the development of a repository for high-level waste (HLW) are described. In particular, attention is given to the information and needs to demonstrate, for construction authorization purposes: repository constructibility, waste retrievability, waste containment, and waste isolation

  16. Development of knowledge building program concerning about high-level radioactive waste disposal

    International Nuclear Information System (INIS)

    Kimura, Hiroshi; Yamada, Kazuhiro; Takase, Hiroyasu

    2005-01-01

    Acquirement of knowledge about the high-level radioactive waste (HLW) disposal is one of the important factors for public to determine the social acceptance of HLW disposal. However in Japan, public do not have knowledge about HLW and its disposal sufficiently. In this work, we developed the knowledge building program concerning about HLW disposal based on Nonaka, and Takeuchi's SECI spiral model in knowledge management, and carried to the experiment on this program. In the results, we found that the participants' knowledge about the HLW disposal increased and changed from misunderstanding' or 'assuming' to 'facts' or 'consideration' through this experimental program. These results said that the experimental program leads participants to have higher quality of knowledge about the HLW disposal. In consequence, this knowledge building program may be effective in the acquirement of high quality knowledge. (author)

  17. Numerical investigation of high level nuclear waste disposal in deep anisotropic geologic repositories

    KAUST Repository

    Salama, Amgad; El Amin, Mohamed F.; Sun, Shuyu

    2015-01-01

    One of the techniques that have been proposed to dispose high level nuclear waste (HLW) has been to bury them in deep geologic formations, which offer relatively enough space to accommodate the large volume of HLW accumulated over the years since

  18. Conceptual design report for immobilized high-level waste interim storage facility (Phase 1)

    International Nuclear Information System (INIS)

    Burgard, K.C.

    1998-01-01

    The Hanford Site Canister Storage Building (CSB Bldg. 212H) will be utilized to interim store Phase 1 HLW products. Project W-464, Immobilized High-Level Waste Interim Storage, will procure an onsite transportation system and retrofit the CSB to accommodate the Phase 1 HLW products. The Conceptual Design Report establishes the Project W-464 technical and cost basis

  19. Conceptual design report for immobilized high-level waste interim storage facility (Phase 1)

    Energy Technology Data Exchange (ETDEWEB)

    Burgard, K.C.

    1998-04-09

    The Hanford Site Canister Storage Building (CSB Bldg. 212H) will be utilized to interim store Phase 1 HLW products. Project W-464, Immobilized High-Level Waste Interim Storage, will procure an onsite transportation system and retrofit the CSB to accommodate the Phase 1 HLW products. The Conceptual Design Report establishes the Project W-464 technical and cost basis.

  20. Focusing on clay formation as host media of HLW geological disposal in China

    International Nuclear Information System (INIS)

    Zheng Hualing; Chen Shi; Sun Donghui

    2007-01-01

    Host medium is vitally important for safety for HLW geological disposal. Chinese HLW disposal effort in the past decades were mainly focused on granite formation. However, the granite formation has fatal disadvantage for HLW geological disposal. This paper reviews experiences gained and lessons learned in the international community and analyzes key factors affecting the site selection. It is recommended that clay formation should be taken into consideration and additional effort should be made before decision making of host media of HLW disposal in China. (authors)

  1. TESTS WITH HIGH-BISMUTH HLW GLASSES FINAL REPORT VSL-10R1780-1, Rev. 0; 12/13/10

    International Nuclear Information System (INIS)

    Matlack, K.S.; Kruger, A.A.; Joseph, I.; Gan, H.; Kot, W.K.; Chaudhuri, M.; Mohr, R.K.; Mckeown, D.A.; Bardakei, T.; Gong, W.; Buecchele, A.C.; Pegg, I.L.

    2011-01-01

    This Final Report describes the testing of glass formulations developed for Hanford High Level Waste (HLW) containing high concentrations of bismuth. In previous work on high-bismuth HLW streams specified by the Office of River Protection (ORP), fully compliant, high waste loading compositions were developed and subjected to melter testing on the DM100 vitrification system. However, during heat treatment according to the Hanford Tank Waste Treatment and Immobilization Plant (WTP) HLW canister centerline cooling (CCC) curves, crucible melts of the high-bismuth glasses were observed to foam. Clearly, such an occurrence during cooling of actual HLW canisters would be highly undesirable. Accordingly, the present work involves larger-scale testing to determine whether this effect occurs under more prototypical conditions, as well as crucible-scale tests to determine the causes and potentially remediate the observed foaming behavior. The work included preparation and characterization of crucible melts designed to determine the underlying causes of the foaming behavior as well as to assess potential mitigation strategies. Testing was also conducted on the DM1200 HLW Pilot melter with a composition previously tested on the DM100 and shown to foam during crucible-scale CCC heat treatment. The DM1200 tests evaluated foaming of glasses over a range of bismuth concentrations poured into temperature-controlled, 55-gallon drums which have a diameter that is close to that of the full-scale WTP HLW canisters. In addition, the DM1200 tests provided the first large-scale melter test data on high-bismuth WTP HLW compositions, including information on processing rates, cold cap behavior and off-gas characteristics, and data from this waste composition on the prototypical DM1200 off-gas treatment system. This work builds on previous work performed at the Vitreous State Laboratory (VSL) for ORP on the same waste composition. The scope of this study was outlined in a Test Plan that was

  2. TESTS WITH HIGH-BISMUTH HLW GLASSES FINAL REPORT VSL-10R1780-1 REV 0 12/13/10

    Energy Technology Data Exchange (ETDEWEB)

    MATLACK KS; KRUGER AA; JOSEPH I; GAN H; KOT WK; CHAUDHURI M; MOHR RK; MCKEOWN DA; BARDAKEI T; GONG W; BUECCHELE AC; PEGG IL

    2011-01-05

    This Final Report describes the testing of glass formulations developed for Hanford High Level Waste (HLW) containing high concentrations of bismuth. In previous work on high-bismuth HLW streams specified by the Office of River Protection (ORP), fully compliant, high waste loading compositions were developed and subjected to melter testing on the DM100 vitrification system. However, during heat treatment according to the Hanford Tank Waste Treatment and Immobilization Plant (WTP) HLW canister centerline cooling (CCC) curves, crucible melts of the high-bismuth glasses were observed to foam. Clearly, such an occurrence during cooling of actual HLW canisters would be highly undesirable. Accordingly, the present work involves larger-scale testing to determine whether this effect occurs under more prototypical conditions, as well as crucible-scale tests to determine the causes and potentially remediate the observed foaming behavior. The work included preparation and characterization of crucible melts designed to determine the underlying causes of the foaming behavior as well as to assess potential mitigation strategies. Testing was also conducted on the DM1200 HLW Pilot melter with a composition previously tested on the DM100 and shown to foam during crucible-scale CCC heat treatment. The DM1200 tests evaluated foaming of glasses over a range of bismuth concentrations poured into temperature-controlled, 55-gallon drums which have a diameter that is close to that of the full-scale WTP HLW canisters. In addition, the DM1200 tests provided the first large-scale melter test data on high-bismuth WTP HLW compositions, including information on processing rates, cold cap behavior and off-gas characteristics, and data from this waste composition on the prototypical DM1200 off-gas treatment system. This work builds on previous work performed at the Vitreous State Laboratory (VSL) for ORP on the same waste composition. The scope of this study was outlined in a Test Plan that was

  3. Operational safety and radiation protection considerations in designing an HLW repository in Germany

    International Nuclear Information System (INIS)

    Filbert, W.; Kreienmeyer, M.; Poehler, M.; Niehues, N.

    2008-01-01

    In Germany the reference concept for disposal of heat generating radioactive waste considers emplacing canisters with vitrified waste in deep vertical boreholes drilled from the drifts of a repository mine in salt at a depth of 870 m. Spent fuel is to be disposed of in self-shielding POLLUX casks in horizontal drifts. An optimized disposal concept anticipates emplacing unshielded canisters with vitrified HLW and canisters containing the fuel rods of 3 PWR or 9 BWR fuel assemblies in boreholes with a diameter of 60 cm and a depth of up to 300 m.. In all cases the void space between POLLUX cask and drifts and canisters and borehole wall will be backfilled with crushed salt. (1) Operational Safety: Based on a detailed description of all underground disposal operation steps, the possible impacts on the disposal operations were analysed and the need for further studies determined. The disposal operation steps comprise e.g. rail bound transport from the shaft to the emplacement drift and emplacement process itself. As possible impacts the following occurrences were considered: ventilation failure, power supply failure, rock mechanics impact including cross-section convergence, irregular floor uplift and rock fall, brine and natural gas intrusion, derailing of transport carts and finally internal fire. (2) Radiation Protection: According to the German Atomic Energy Act (AtG), the design, construction and operation of a nuclear site like a final repository has to be licensed by the responsible authority. The Radiological Protection Ordinance and further guidelines i.e. concerning the emission and immission of released radioactive nuclides or the risk analysis of possible failure, build the basis for the licensing procedures. To ensure adequate protection against undue radiation exposure the repository is divided into different radiological protection areas. Generally, the handling of shielded waste packages above und under ground (including all the pathway of transport and

  4. Waste acceptance product specifications for vitrified high-level waste forms

    International Nuclear Information System (INIS)

    Applewhite-Ramsey, A.; Sproull, J.F.

    1993-01-01

    The Nuclear Waste Policy Act of 1982 mandated that all high-level waste (HLW) be sent to a federal geologic repository for permanent disposal. DOE published the Environmental Assessment in 1982 which identified borosilicate glass as the chosen HLW form. 1 In 1985 the Department of Energy instituted a Waste Acceptance Process to assure that DWPF glass waste forms would be acceptable to such a repository. This assurance was important since production of waste forms will precede repository construction and licensing. As part of this Waste Acceptance Process, the DOE Office of Civilian Radioactive Waste Management (RW) formed the Waste Acceptance Committee (WAC). The WAC included representatives from the candidate repository sites, the waste producing sites and DOE. The WAC was responsible for developing the Waste Acceptance Preliminary Specifications (WAPS) which defined the requirements the waste forms must meet to be compatible with the candidate repository geologies

  5. Production of a High-Level Waste Glass from Hanford Waste Samples

    International Nuclear Information System (INIS)

    Crawford, C.L.; Farrara, D.M.; Ha, B.C.; Bibler, N.E.

    1998-09-01

    The HLW glass was produced from a HLW sludge slurry (Envelope D Waste), eluate waste streams containing high levels of Cs-137 and Tc-99, solids containing both Sr-90 and transuranics (TRU), and glass-forming chemicals. The eluates and Sr-90/TRU solids were obtained from ion-exchange and precipitation pretreatments, respectively, of other Hanford supernate samples (Envelopes A, B and C Waste). The glass was vitrified by mixing the different waste streams with glass-forming chemicals in platinum/gold crucibles and heating the mixture to 1150 degree C. Resulting glass analyses indicated that the HLW glass waste form composition was close to the target composition. The targeted waste loading of Envelope D sludge solids in the HLW glass was 30.7 wt percent, exclusive of Na and Si oxides. Condensate samples from the off-gas condenser and off-gas dry-ice trap indicated that very little of the radionuclides were volatilized during vitrification. Microstructure analysis of the HLW glass using Scanning Electron Microscopy (SEM) and Energy Dispersive X-Ray Analysis (EDAX) showed what appeared to be iron spinel in the HLW glass. Further X-Ray Diffraction (XRD) analysis confirmed the presence of nickel spinel trevorite (NiFe2O4). These crystals did not degrade the leaching characteristics of the glass. The HLW glass waste form passed leach tests that included a standard 90 degree C Product Consistency Test (PCT) and a modified version of the United States Environmental Protection Agency Toxicity Characteristic Leaching Procedure (TCLP)

  6. Advanced waste form and melter development for treatment of troublesome high-level wastes

    Energy Technology Data Exchange (ETDEWEB)

    Marra, James [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Kim, Dong -Sang [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Maio, Vincent [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2015-09-02

    A number of waste components in US defense high level radioactive wastes (HLW) have proven challenging for current Joule heated ceramic melter (JHCM) operations and have limited the ability to increase waste loadings beyond already realized levels. Many of these "troublesome" waste species cause crystallization in the glass melt that can negatively impact product quality or have a deleterious effect on melter processing. Recent efforts at US Department of Energy laboratories have focused on understanding crystallization behavior within HLW glass melts and investigating approached to mitigate the impacts of crystallization so that increases in waste loading can be realized. Advanced glass formulations have been developed to highlight the unique benefits of next-generation melter technologies such as the Cold Crucible Induction Melter (CCIM). Crystal-tolerant HLW glasses have been investigated to allow sparingly soluble components such as chromium to crystallize in the melter but pass out of the melter before accumulating.

  7. Separation processes for high-level radioactive waste treatment

    International Nuclear Information System (INIS)

    Sutherland, D.G.

    1992-11-01

    During World War II, production of nuclear materials in the United States for national defense, high-level waste (HLW) was generated as a byproduct. Since that time, further quantities of HLW radionuclides have been generated by continued nuclear materials production, research, and the commercial nuclear power program. In this paper HLW is defined as the highly radioactive material resulting from the processing of spent nuclear fuel. The HLW is the liquid waste generated during the recovery of uranium and plutonium in a fuel processing plant that generally contains more than 99% of the nonvolatile fission products produced during reactor operation. Since this paper deals with waste separation processes, spent reactor fuel elements that have not been dissolved and further processed are excluded

  8. Grouping of HLW in partitioning for B/T (burning and/or transmutation) treatment with neutron reactors based on three criteria

    International Nuclear Information System (INIS)

    Kitamoto, Mulyanto; Kitamoto, Asashi

    1995-01-01

    A grouping concept of HLW in partitioning for B/T (burning and/or transmutation) treatment by fission reactor was developed in order to improve the disposal in waste management from the safety aspect. The selecting and grouping concept was proposed herein, such as Group MA1 (Np, Am, and unrecovered U and Pu), Group MA2 (Cm, and trace quantity of Cf, etc.), Group A (Tc and I), Group B (Cs and Sr) and Group R (the partitioned remains of HLW), judging from the three criteria for B/T treatment, based on (1) the concept of the potential risk estimated by the hazard index for long-term tendency based on ALI (2) the concept of the relative dose factor related to the adsorbed migration rate transferred through ground water, and (3) the concept of the decay acceleration factor, the burning and/or transmutation characteristics for recycle B/T treatment. (author)

  9. 77 FR 38789 - Notice of Availability of Draft Waste Incidental to Reprocessing Evaluation for the Concentrator...

    Science.gov (United States)

    2012-06-29

    ... disposal facility, either the Area 5 Radioactive Waste Management Site at DOE's Nevada National Security... offsite LLW disposal facility, either the NNSS Area 5 Radioactive Waste Management Site or the Waste... radioactive waste (HLW) and may be managed and disposed of offsite as low-level waste (LLW). DOE prepared the...

  10. Thermo-hydro-mechanical processes in the nearfield around a HLW repository in argillaceous formations. Vol. I. Laboratory investigations

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Chun-Liang; Czaikowski, Oliver; Rothfuchs, Tilmann; Wieczorek, Klaus

    2013-06-15

    All over the world, clay formations are being investigated as host medium for geologic disposal of radioactive waste because of their favourable properties, such as very low hydraulic conductivity against fluid transport, good sorption capacity for retardation of radionuclides, and high potential of self-sealing of fractures. The construction of a repository, the disposal of heat-emitting high-level radioactive waste (HLW), the backfilling and sealing of the remaining voids, however, will inevitably induce mechanical (M), hydraulic (H), thermal (T) and chemical (C) disturbances to the host formation and the engineered barrier system (EBS) over very long periods of time during the operation and post-closure phases of the repository. The responses and resulting property changes of the clay host rock and engineered barriers are to be well understood, characterized, and predicted for assessing the long-term performance and safety of the repository.

  11. Challenges in development of matrices for vitrification of old legacy waste and high-level radioactive waste generated from reprocessing of AHWR and FBR spent fuel

    International Nuclear Information System (INIS)

    Kaushik, C.P.

    2012-01-01

    Majority of radioactivity in entire nuclear fuel cycle is concentrated in HLW. A three step strategy for management of HLW has been adopted in India. This involves immobilization of waste oxides in stable and inert solid matrices, interim retrievable storage of the conditioned waste product under continuous cooling and disposal in deep geological formations. Glass has been accepted as most suitable matrix world-wide for immobilization of HLW, because of its attractive features like ability to accommodate wide range of waste constituents, modest processing temperatures, adequate chemical, thermal and radiation stability. Borosilicate glass matrix developed by BARC in collaboration with CGCRI has been adopted in India for immobilization of HLW. In view of compositional variation of HLW from site to site, tailor make changes in the glass formulations are often necessary to incorporate all the waste constituents and having the product of desirable characteristics. The vitrified waste products made with different glass formulations and simulated waste need to be characterized for chemical durability, thermal stability, homogeneity etc. before finalizing a suitable glass formulation. The present extended abstract summarises the studies carried out for development of glass formulations for vitrification of legacy waste and futuristic waste likely to be generated from AHWR and FBR having wide variations in their compositions. The presently stored HLW at Trombay is characterized by significant concentrations of uranium, sodium and sulphate in addition to fission products, corrosion products and small amount of other actinides

  12. Use of Gap-fills in the Buffer and Backfill of an HLW Repository

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Jae Owan; Lee, Min Soo; Choi, Heui Joo [KAERI, Daejeon (Korea, Republic of)

    2016-05-15

    The buffer and backfill are significant barrier components of the repository. They play the roles of preventing the inflow of groundwater from the surrounding rock, retarding the release of radionuclides from the waste, supporting disposal container against external impacts, and discharging decay heat from the waste. When the buffer and backfill are installed for the HLW repository, there may be gaps between the container and buffer and between the backfill and the wall of disposal tunnels, respectively. These gaps occur because spaces are allowed for ease of the installation of the buffer and backfill in excavated deposition boreholes and disposal tunnels. If the gaps are left without any sealing as they are, however, the buffer and backfill can't accomplish their functions as the barrier components. This paper reviews the gap-fill concepts of the developed foreign countries, and then suggests a gap-fill concept which is applicable for the KRS. The gap-fill is suggested to employ bentonite- based materials with a type of pellet, granule, and pellet-granule mixture. The roller compression method and extrusion-cutting method are applicable for the fabrication of the bentonite pellets which can have the high density and the required amount for use to the buffer and backfill. For the installation of the gap-fill, the pouring and then pressing method and the shotcrete- blowing method are preferable for the gap of the deposition borehole and the gap of the disposal tunnel, respectively.

  13. Nuclide release calculation in the near-field of a reference HLW repository

    International Nuclear Information System (INIS)

    Lee, Youn Myoung; Hwang, Yong Soo; Kang, Chul Hyung

    2004-01-01

    The HLW-relevant R and D program for disposal of high-level radioactive waste has been carried out at Korea Atomic Energy Research Institute (KAERI) since early 1997 in order to develop a conceptual Korea Reference Repository System for direct disposal of nuclear spent fuel by the end of 2007. A preliminary reference geologic repository concept considering such established criteria and requirements as waste and generic site characteristics in Korea was roughly envisaged in 2003 focusing on the near-field components of the repository system. According to above basic repository concept, which is similar to that of Swedish KBS-3 repository, the spent fuel is first encapsulated in corrosion resistant canisters, even though the material has not yet been determined, and then emplaced into the deposition holes surrounded by high density bentonite clay in tunnels constructed at a depth of about 500 m in a stable plutonic rock body. Not only to demonstrate how much a reference repository is safe in the generic point of view with several possible scenarios and cases associated with a preliminary repository concept by conducting calculations for nuclide release and transport in the near-field components of the repository, even though enough information has not been available that much yet, but also to show a methodology by which a generic safety assessment could be performed for further development of Korea reference repository concept, nuclide release calculation study strongly seems to be necessary

  14. Impact Of Particle Agglomeration On Accumulation Rates In The Glass Discharge Riser Of HLW Melter

    International Nuclear Information System (INIS)

    Kruger, A. A.; Rodriguez, C. A.; Matyas, J.; Owen, A. T.; Jansik, D. P.; Lang, J. B.

    2012-01-01

    The major factor limiting waste loading in continuous high-level radioactive waste (HLW) melters is an accumulation of particles in the glass discharge riser during a frequent and periodic idling of more than 20 days. An excessive accumulation can produce robust layers a few centimeters thick, which may clog the riser, preventing molten glass from being poured into canisters. Since the accumulation rate is driven by the size of particles we investigated with x-ray microtomography, scanning electron microscopy, and image analysis the impact of spinel forming components, noble metals, and alumina on the size, concentration, and spatial distribution of particles, and on the accumulation rate. Increased concentrations of Fe and Ni in the baseline glass resulted in the formation of large agglomerates that grew over the time to an average size of ∼185+-155 μm, and produced >3 mm thick layer after 120 h at 850 deg C. The noble metals decreased the particle size, and therefore significantly slowed down the accumulation rate. Addition of alumina resulted in the formation of a network of spinel dendrites which prevented accumulation of particles into compact layers

  15. Effect of composition on peraluminous glass properties: An application to HLW containment

    Energy Technology Data Exchange (ETDEWEB)

    Piovesan, V. [CEA, DEN, DTCD, SECM, LDMC – Marcoule, F-30207 Bagnols sur Cèze (France); CNRS, CEMHTI UPR3079, Univ. Orléans, F-45071 Orléans (France); Bardez-Giboire, I., E-mail: isabelle.giboire@cea.fr [CEA, DEN, DTCD, SECM, LDMC – Marcoule, F-30207 Bagnols sur Cèze (France); Perret, D. [CEA, DEN, DTCD, SECM, LDMC – Marcoule, F-30207 Bagnols sur Cèze (France); Montouillout, V.; Pellerin, N. [CNRS, CEMHTI UPR3079, Univ. Orléans, F-45071 Orléans (France)

    2017-01-15

    Part of the Research and Development program concerning high level nuclear waste (HLW) glasses aims to assess new glass formulations able to incorporate a high waste content with enhanced properties in terms of thermal stability, chemical durability, and process ability. This study focuses on peraluminous glasses of the SiO{sub 2} – Al{sub 2}O{sub 3} – B{sub 2}O{sub 3} – Na{sub 2}O – Li{sub 2}O – CaO – La{sub 2}O{sub 3} system, defined by an excess of aluminum ions Al{sup 3+} in comparison with modifier elements such as Na{sup +}, Li{sup +} or Ca{sup 2+}. To understand the effect of composition on physical properties of glasses (viscosity, density, T{sub g}), a Design Of Experiments (DOE) approach was applied to investigate the peraluminous glass domain. The influence of each oxide was quantified to build predictive models for each property. Lanthanum and lithium oxides appear to be the most influential factors on peraluminous glass properties. - Highlights: • A Design of Experiment approach to link composition and glass properties. • Adding alkali decreases glass transition temperature. • Adding La{sub 2}O{sub 3} strongly decreases glass melt viscosity. • Adding La{sub 2}O{sub 3} increases density.

  16. A Green Preconcentration Method for Determination of Cobalt and Lead in Fresh Surface and Waste Water Samples Prior to Flame Atomic Absorption Spectrometry

    Directory of Open Access Journals (Sweden)

    Naeemullah

    2012-01-01

    Full Text Available Cloud point extraction (CPE has been used for the preconcentration and simultaneous determination of cobalt (Co and lead (Pb in fresh and wastewater samples. The extraction of analytes from aqueous samples was performed in the presence of 8-hydroxyquinoline (oxine as a chelating agent and Triton X-114 as a nonionic surfactant. Experiments were conducted to assess the effect of different chemical variables such as pH, amounts of reagents (oxine and Triton X-114, temperature, incubation time, and sample volume. After phase separation, based on the cloud point, the surfactant-rich phase was diluted with acidic ethanol prior to its analysis by the flame atomic absorption spectrometry (FAAS. The enhancement factors 70 and 50 with detection limits of 0.26 μg L−1 and 0.44 μg L−1 were obtained for Co and Pb, respectively. In order to validate the developed method, a certified reference material (SRM 1643e was analyzed and the determined values obtained were in a good agreement with the certified values. The proposed method was applied successfully to the determination of Co and Pb in a fresh surface and waste water sample.

  17. Fundamental problem of high-level radioactive waste disposal policy in Japan. Critical analysis responding to the publication of 'Nationwide Map of Scientific Features for Geological Disposal' by the Japanese government

    International Nuclear Information System (INIS)

    Juraku, Kohta

    2017-01-01

    The government explains that 'Scientific Characteristic Map' (hereinafter 'Map') shows the scientific characteristics of sites that are thought necessary to be taken into account when choosing the place to implement geological disposal and their geographical distribution on the Japanese map for the convenience to 'roughly overlook.' Nuclear Waste Management Organization of Japan (NUMO) as the implementing agency for geological disposal and the government (Agency for Natural Resources and Energy of Ministry of Economy, Trade and Industry) stress that this Map does not indicate so-called 'optimum land,' but it is the 'first step of a long way to realize disposal' for high-level radioactive waste (HLW). However, there clearly lurks a debate about the acceptance of the location of geological disposal in the future. The author has pointed out that the essence of the HLW disposal problem is a problem of 'value selection' that should be decided prior to the location of disposal site. The author believes that it is the competence of society how to identify the path of countermeasures by reconciling in a high degree the justice of the policies supported by scientific and professional knowledge and the justice of social decision making through a democratic duty process. However, the government is trying to forward HLW disposal only from the viewpoint of location problems, while neglecting the problem of 'value selection.' (A.O.)

  18. The chemical stockpile intergovernmental consultation program: Lessons for HLW public involvement

    International Nuclear Information System (INIS)

    Feldman, D.L.

    1991-01-01

    This paper assesses the appropriateness of the US Army's Chemical Stockpile Disposal Program's (CSDP) Intergovernmental Consultation and Coordination Boards (ICCBs) as models for incorporating public concerns in the future siting of HLW repositories by DOE. ICCB structure, function, and implementation are examined, along with other issues relevant to the HLW context. 27 refs

  19. Spent fuel and HLW transportation the French experience

    International Nuclear Information System (INIS)

    Giraud, J.P.; Charles, J.L.

    1995-01-01

    With 53 nuclear power plants in operation at EDF and a fuel cycle with recycling policy of the valuable materials, COGEMA is faced with the transport of a wide range of radioactive materials. In this framework, the transport activity is a key link in closing the fuel cycle. COGEMA has developed a comprehensive Transport Organization System dealing with all the sectors of the fuel cycle. The paper will describe the status of transportation of spent fuel and HLW in France and the experience gathered. The Transport Organization System clearly defines the role of all actors where COGEMA, acting as the general coordinator, specifies the tasks to be performed and brings technical and commercial support to its various subcontractors: TRANSNUCLEAIRE, specialized in casks engineering and transport operations, supplies packaging and performs transport operations, LEMARECHAL and CELESTIN operate transport by truck in the Vicinity of the nuclear sites while French Railways are in charge of spent fuel transport by train. HLW issued from the French nuclear program is stored for 30 years in an intermediate storage installation located at the La Hague reprocessing plant. Ultimately, these canisters will be transported to the disposal site. COGEMA has set up a comprehensive transport organization covering all operational aspects including adapted procedures, maintenance programs and personnel qualification

  20. Defense High Level Waste Disposal Container System Description Document

    International Nuclear Information System (INIS)

    2000-01-01

    The Defense High Level Waste Disposal Container System supports the confinement and isolation of waste within the Engineered Barrier System of the Monitored Geologic Repository (MGR). Disposal containers are loaded and sealed in the surface waste handling facilities, transferred to the underground through the accesses using a rail mounted transporter, and emplaced in emplacement drifts. The defense high level waste (HLW) disposal container provides long-term confinement of the commercial HLW and defense HLW (including immobilized plutonium waste forms (IPWF)) placed within disposable canisters, and withstands the loading, transfer, emplacement, and retrieval loads and environments. U.S. Department of Energy (DOE)-owned spent nuclear fuel (SNF) in disposable canisters may also be placed in a defense HLW disposal container along with commercial HLW waste forms, which is known as 'co-disposal'. The Defense High Level Waste Disposal Container System provides containment of waste for a designated period of time, and limits radionuclide release. The disposal container/waste package maintains the waste in a designated configuration, withstands maximum handling and rockfall loads, limits the individual canister temperatures after emplacement, resists corrosion in the expected handling and repository environments, and provides containment of waste in the event of an accident. Defense HLW disposal containers for HLW disposal will hold up to five HLW canisters. Defense HLW disposal containers for co-disposal will hold up to five HLW canisters arranged in a ring and one DOE SNF canister in the ring. Defense HLW disposal containers also will hold two Multi-Canister Overpacks (MCOs) and two HLW canisters in one disposal container. The disposal container will include outer and inner cylinders, outer and inner cylinder lids, and may include a canister guide. An exterior label will provide a means by which to identify the disposal container and its contents. Different materials

  1. Waste management system alternatives for treatment of wastes from spent fuel reprocessing

    International Nuclear Information System (INIS)

    McKee, R.W.; Swanson, J.L.; Daling, P.M.

    1986-09-01

    This study was performed to help identify a preferred TRU waste treatment alternative for reprocessing wastes with respect to waste form performance in a geologic repository, near-term waste management system risks, and minimum waste management system costs. The results were intended for use in developing TRU waste acceptance requirements that may be needed to meet regulatory requirements for disposal of TRU wastes in a geologic repository. The waste management system components included in this analysis are waste treatment and packaging, transportation, and disposal. The major features of the TRU waste treatment alternatives examined here include: (1) packaging (as-produced) without treatment (PWOT); (2) compaction of hulls and other compactable wastes; (3) incineration of combustibles with cementation of the ash plus compaction of hulls and filters; (4) melting of hulls and failed equipment plus incineration of combustibles with vitrification of the ash along with the HLW; (5a) decontamination of hulls and failed equipment to produce LLW plus incineration and incorporation of ash and other inert wastes into HLW glass; and (5b) variation of this fifth treatment alternative in which the incineration ash is incorporated into a separate TRU waste glass. The six alternative processing system concepts provide progressively increasing levels of TRU waste consolidation and TRU waste form integrity. Vitrification of HLW and intermediate-level liquid wastes (ILLW) was assumed in all cases

  2. Cavern disposal concepts for HLW/SF: assuring operational practicality and safety with maximum programme flexibility

    International Nuclear Information System (INIS)

    McKinley, Ian G.; Apted, Mick; Umeki, Hiroyuki; Kawamura, Hideki

    2008-01-01

    Most conventional engineered barrier system (EBS) designs for HLW/SF repositories are based on concepts developed in the 1970s and 1980s that assured feasibility with high margins of safety, in order to convince national decision makers to proceed with geological disposal despite technological uncertainties. In the interval since the advent of such 'feasibility designs', significant progress has been made in reducing technological uncertainties, which has lead to a growing awareness of other, equally important uncertainties in operational implementation and challenges regarding social acceptance in many new, emerging national repository programs. As indicated by the NUMO repository concept catalogue study (NUMO, 2004), there are advantages in reassessing how previous designs can be modified and optimised in the light of improved system understanding, allowing a robust EBS to be flexibly implemented to meet nation-specific and site-specific conditions. Full-scale emplacement demonstrations, particularly those carried out underground, have highlighted many of the practical issues to be addressed; e.g., handling of compacted bentonite in humid conditions, use of concrete for support infrastructure, remote handling of heavy radioactive packages in confined conditions, quality inspection, monitoring / ease of retrieval of emplaced packages and institutional control. The CAvern REtrievable (CARE) concept reduces or avoids such issues by emplacement of HLW or SF within multi-purpose transportation / storage / disposal casks in large ventilated caverns at a depth of several hundred metres. The facility allows the caverns to serve as inspectable stores for an extended period of time (up to a few hundred years) until a decision is made to close them. At this point the caverns are backfilled and sealed as a final repository, effectively with the same safety case components as conventional 'feasibility designs'. In terms of operational practicality an d safety, the CARE

  3. Simulation of HTM processes in buffer-rock barriers based on the French HLW disposal concept

    International Nuclear Information System (INIS)

    Li, Xiaoshuo; Roehlig, Klaus-Juergen; Zhang, Chunliang

    2012-01-01

    Document available in extended abstract form only. The main objectives of this paper are to gain experience with modelling and analysis of HTM processes in clay rock and bentonite buffer surrounding heat-generating radioactive waste. The French concept for HLW disposal in drifts with backfilled bentonite buffer considered in numerical calculations which are carried out by using the computer code CODE-BRIGHT developed by the Technical University of Catalonia in Barcelona. The French repository designed by ANDRA is located in the middle of the Callovo-Oxfordian argillaceous formation (COX) of 250 m thickness at a depth of 500 to 630 m below the surface. The French concept has been simplified at this simulation work. A drift is considered to be excavated at a depth of 500 m below the surface. It has a diameter of 2.2 m and a length of 20 m. A large volume of the rock mass around the drift is taken into account by an axisymmetric model of 100 m radius and 100 m length. In fact, this model represents a cylindrical rock-buffer-system with the central axis of the containers, as shown in Figure 1. Some points are selected in the buffer and the rock along the radial line (dash yellow line) in the middle of the drift for recording HTM parameters with time. The display and analysis of the results at this paper are chiefly along this line. The simulation work has been divided to two time steps. At the first step, the drift excavation and ventilation is simulated by reducing the stress normal to the drift wall down to zero and circulating gas along the drift wall with relative humidity of 85 %. Following the drift excavation and ventilation, the HLW containers and the bentonite are emplaced in the drift as the second step of the simulation. This is simulated by simultaneously applying the initial conditions of the buffer and the decayed heat emitting from the waste containers as thermal boundary conditions. Two materials (Clay rock and bentonite buffer) are taken into account

  4. The Spanish general radioactive waste plan

    International Nuclear Information System (INIS)

    Redondo, J.M.

    2007-01-01

    The author summarized the current status of Spain's general radioactive waste management plan. This plan forms the basis for a national radioactive waste management policy and decommissioning strategy. It is updated periodically, the current 5. plan was approved in 1999. The most important element of the current strategy is the development of a centralized interim HLW storage facility by 2010. (A.L.B.)

  5. Determination of a radioactive waste classification system

    Energy Technology Data Exchange (ETDEWEB)

    Cohen, J.J.; King, W.C.

    1978-03-01

    Several classification systems for radioactive wastes are reviewed and a system is developed that provides guidance on disposition of the waste. The system has three classes: high-level waste (HLW), which requires complete isolation from the biosphere for extended time periods; low-level waste (LLW), which requires containment for shorter periods; and innocuous waste (essentially nonradioactive), which may be disposed of by conventional means. The LLW/innocuous waste interface was not defined in this study. Reasonably conservative analytical scenarios were used to calculate that HLW/LLW interface level which would ensure compliance with the radiological exposure guidelines of 0.5 rem/y maximum exposure for a few isolated individuals and 0.005 rem/y for large population groups. The recommended HLW/LLW interface level for /sup 239/Pu or mixed transuranic waste is 1.0 ..mu..Ci/cm/sup 3/ of waste. Levels for other radionuclides are based upon a risk equivalent to this level. A cost-benefit analysis in accordance with as low as reasonably achievable (ALARA) and National Environmental Protection Act (NEPA) guidance indicates that further reduction of this HLW/LLL interface level would entail marginal costs greater than $10/sup 8/ per man-rem of dose avoided. The environmental effects considered were limited to those involving human exposure to radioactivity.

  6. Determination of a radioactive waste classification system

    International Nuclear Information System (INIS)

    Cohen, J.J.; King, W.C.

    1978-03-01

    Several classification systems for radioactive wastes are reviewed and a system is developed that provides guidance on disposition of the waste. The system has three classes: high-level waste (HLW), which requires complete isolation from the biosphere for extended time periods; low-level waste (LLW), which requires containment for shorter periods; and innocuous waste (essentially nonradioactive), which may be disposed of by conventional means. The LLW/innocuous waste interface was not defined in this study. Reasonably conservative analytical scenarios were used to calculate that HLW/LLW interface level which would ensure compliance with the radiological exposure guidelines of 0.5 rem/y maximum exposure for a few isolated individuals and 0.005 rem/y for large population groups. The recommended HLW/LLW interface level for 239 Pu or mixed transuranic waste is 1.0 μCi/cm 3 of waste. Levels for other radionuclides are based upon a risk equivalent to this level. A cost-benefit analysis in accordance with as low as reasonably achievable (ALARA) and National Environmental Protection Act (NEPA) guidance indicates that further reduction of this HLW/LLL interface level would entail marginal costs greater than $10 8 per man-rem of dose avoided. The environmental effects considered were limited to those involving human exposure to radioactivity

  7. Waste Acceptance System Requirements document (WASRD)

    International Nuclear Information System (INIS)

    1993-01-01

    This Waste Acceptance System Requirements document (WA-SRD) describes the functions to be performed and the technical requirements for a Waste Acceptance System for accepting spent nuclear fuel (SNF) and high-level radioactive waste (HLW) into the Civilian Radioactive Waste Management System (CRWMS). This revision of the WA-SRD addresses the requirements for the acceptance of HLW. This revision has been developed as a top priority document to permit DOE's Office of Environmental Restoration and Waste Management (EM) to commence waste qualification runs at the Savannah River Site's (SRS) Defense Waste Processing Facility (DWPF) in a timely manner. Additionally, this revision of the WA-SRD includes the requirements from the Physical System Requirements -- Accept Waste document for the acceptance of SNF. A subsequent revision will fully address requirements relative to the acceptance of SNF

  8. Test plan: Effects of phase separation on waste loading for high level waste glasses

    International Nuclear Information System (INIS)

    Jantzen, C.M.

    2000-01-01

    As part of the Tanks Focus Area's (TFA) effort to increase waste loading for high-level waste (HLW) vitrification at various facilities in the Department of Energy (DOE) complex, the occurrence of phase separation in waste glasses spanning the Savannah River Site (SRS) and Idaho National Engineering and Environmental Laboratory (INEEL) composition ranges were studied during FY99. The type, extent, and impact of phase separation on glass durability for a series of HLW glasses, e.g., SRS-type and INEEL-type, were examined

  9. Time-frames and the demonstration of safety for HLW disposal

    International Nuclear Information System (INIS)

    Watkins, B.; Kessler, J.

    1999-01-01

    An important principle which is often embodied in the criteria for the safe disposal of long-lived radioactive wastes is that a similar level of radiation protection should be provided to future generations as that provided for those alive today. This has resulted in the development of performance assessment methodologies to evaluate the potential long term impacts of HLW disposal on humans, usually in terms of individual dose or risk. However, the actual periods of time over which it is expected that there will be full control over high level waste disposals are extremely short in comparison with the times over which radionuclides in the wastes could potentially move from the deep repository and emerge into the surface environment. This leads to problems in setting quantitative dose or risk based standard appropriate for the short and long term, and in setting the time-frames for which calculations should be carried out. This is especially difficult in view of the uncertainty in predicting changes in human behaviour and changes in the biosphere and geosphere over the time-scales involved. Different assessment time-frames and approaches proposed by IAEA, Nordic countries, Britain and US guidance documents are briefly reviewed. Whilst accepting the basic radiation protection objective of protecting future generations, no international consensus bas been agreed on what time-frames should be used in performance assessments. It is recommended that different time-frames should be associated with different quantitative or qualitative performance measures. As a result, a range of indicators of safety may be appropriate in demonstrating compliance with regulatory performance criteria and the consequent overall assessment context. It is argued that what is required is a simple, robust yet defensible approach to time-frames and performance indicators which can be accepted by the public, regulators and the nuclear industry

  10. Vitrified waste option study report

    International Nuclear Information System (INIS)

    Lopez, D.A.; Kimmitt, R.R.

    1998-02-01

    A open-quotes Settlement Agreementclose quotes between the Department of Energy and the State of Idaho mandates that all radioactive high-level waste (HLW) now stored at the Idaho Chemical Processing Plant (ICPP) will be treated so that it is ready to be moved out of Idaho for disposal by a target date of 2035. This report investigates vitrification treatment of all ICPP calcine, including the existing and future HLW calcine resulting from calcining liquid Sodium-Bearing Waste (SBW). Currently, the SBW is stored in the tank farm at the ICPP. Vitrification of these wastes is an acceptable treatment method for complying with the Settlement Agreement. This method involves vitrifying the calcined waste and casting the vitrified mass into stainless steel canisters that will be ready to be moved out of the Idaho for disposal by 2035. These canisters will be stored at the Idaho National Engineering and Environmental Laboratory (INEEL) until they are sent to a HLW national repository. The operating period for vitrification treatment will be from 2013 through 2032; all HLW will be treated and in storage by the end of 2032

  11. Vitrified waste option study report

    Energy Technology Data Exchange (ETDEWEB)

    Lopez, D.A.; Kimmitt, R.R.

    1998-02-01

    A {open_quotes}Settlement Agreement{close_quotes} between the Department of Energy and the State of Idaho mandates that all radioactive high-level waste (HLW) now stored at the Idaho Chemical Processing Plant (ICPP) will be treated so that it is ready to be moved out of Idaho for disposal by a target date of 2035. This report investigates vitrification treatment of all ICPP calcine, including the existing and future HLW calcine resulting from calcining liquid Sodium-Bearing Waste (SBW). Currently, the SBW is stored in the tank farm at the ICPP. Vitrification of these wastes is an acceptable treatment method for complying with the Settlement Agreement. This method involves vitrifying the calcined waste and casting the vitrified mass into stainless steel canisters that will be ready to be moved out of the Idaho for disposal by 2035. These canisters will be stored at the Idaho National Engineering and Environmental Laboratory (INEEL) until they are sent to a HLW national repository. The operating period for vitrification treatment will be from 2013 through 2032; all HLW will be treated and in storage by the end of 2032.

  12. Timing of High-level Waste Disposal

    International Nuclear Information System (INIS)

    2008-01-01

    This study identifies key factors influencing the timing of high-level waste (HLW) disposal and examines how social acceptability, technical soundness, environmental responsibility and economic feasibility impact on national strategies for HLW management and disposal. Based on case study analyses, it also presents the strategic approaches adopted in a number of national policies to address public concerns and civil society requirements regarding long-term stewardship of high-level radioactive waste. The findings and conclusions of the study confirm the importance of informing all stakeholders and involving them in the decision-making process in order to implement HLW disposal strategies successfully. This study will be of considerable interest to nuclear energy policy makers and analysts as well as to experts in the area of radioactive waste management and disposal. (author)

  13. Progress of the research and development on the geological disposal technology of HLW with aid of the industry/university collaboration system and fixed term researcher system

    International Nuclear Information System (INIS)

    Yamada, Fumitaka; Sonobe, Hitoshi; Igarashi, Hiroshi

    2008-02-01

    In Japan Atomic Energy Agency (JAEA), various systems associated with the collaboration with industries and universities on the Nuclear Fuel Cycle and the Postdoctoral Fellow system, etc. are enacted. These systems have been operated considering the needs of JAEA's program, industry and academia, resultantly contributed, for example, to basic research and the project development. The activities under these collaboration systems contain personal exchanges, the publication of the accomplishments and utilization of those, in research and development concerning geological disposal technology of high-level radioactive waste (HLW). These activities have progressed in Power Reactor and Nuclear Fuel Development Corporation (PNC) and Japan Nuclear Cycle Development Institute (JNC), which are the successive predecessors of JAEA, through JAEA. The accomplishments from these systems have been not only published as papers in journals and individual technical reports but also integrated into the project reports, accordingly contributed to the advancement of the national program on the geological disposal of HLW. In this report, the progress of the research and development under these systems was investigated from the beginning of the operation of the systems. The contribution to the research and development on geological disposal technology of HLW was also studied. On the basis of these studies, the future utilization of the systems of the collaboration was also discussed from the view point of the management of research and development program. A CD-ROM is attached as an appendix. (J.P.N.)

  14. Preparation and characterization of an improved borosilicate glass for the solidification of high level radioactive fission product solutions (HLW). Pt. 2

    International Nuclear Information System (INIS)

    Kahl, L.; Ruiz-Lopez, M.C.; Saidl, J.; Dippel, T.

    1982-04-01

    In the 'Institut fuer Nuklare Entsorgungstechnik' the borosilicate glass VG 98/12 has been developed for the solidification of the high level radioactive waste (HLW). This borosilicate glass can be used in a direct heated ceramic melter and forms together with the HLW the borosilicate glass product GP 98/12. This borosilicate glass product has been examined in detail both in liquid and solid state. The elements contained in the HLW can be incorporated without problems. Only in a few exceptions the concentration must be kept below certain limits to exclude the formation of a second phase ('yellow phase') by separation. No spontaneous crystallization and no crystallization over a long time could be observed as long as the temperature of the borosilicate glass product is kept below its transformation area. Simulating accidental conditions in the final storage, samples had been leached at temperatures up to 200 0 C and pressures up to 130 bar with saturated rock salt brine and saturated quinary salt brine. The leaching process seems to be stopped by the formed 'leached layer' on the surface of the borosilicate glass product after a limited leaching time. Detailed investigations have been started to explain this phenomenon. (orig.) [de

  15. Technical Exchange on Improved Design and Performance of High Level Waste Melters - Final Report

    Energy Technology Data Exchange (ETDEWEB)

    SK Sundaram; ML Elliott; D Bickford

    1999-11-19

    SIA Radon is responsible for management of low- and intermediate-level radioactive waste (LILW) produced in Central Russia. In cooperation with Minatom organizations Radon carries out R and D programs on treatment of simulated high level waste (HLW) as well. Radon scientists deal with a study of materials for LILW, HLW, and Nuclear Power Plants (NPP) wastes immobilization, and development and testing of processes and technologies for waste treatment and disposal. Radon is mostly experienced in LILW vitrification. This experience can be carried over to HLW vitrification especially in field of melting systems. The melter chosen as a basic unit for the vitrification plant is a cold crucible. Later on Radon experience in LILW vitrification as well as our results on simulated HLW vitrification are briefly described.

  16. Technical Exchange on Improved Design and Performance of High Level Waste Melters - Final Report

    International Nuclear Information System (INIS)

    Sundaram, S.K.; Elliott, M.L.; Bickford, D.

    1999-01-01

    SIA Radon is responsible for management of low- and intermediate-level radioactive waste (LILW) produced in Central Russia. In cooperation with Minatom organizations Radon carries out R and D programs on treatment of simulated high level waste (HLW) as well. Radon scientists deal with a study of materials for LILW, HLW, and Nuclear Power Plants (NPP) wastes immobilization, and development and testing of processes and technologies for waste treatment and disposal. Radon is mostly experienced in LILW vitrification. This experience can be carried over to HLW vitrification especially in field of melting systems. The melter chosen as a basic unit for the vitrification plant is a cold crucible. Later on Radon experience in LILW vitrification as well as our results on simulated HLW vitrification are briefly described

  17. Mechanisms and Kinetics of Organic Aging and Characterization of Intermediates in High Level Waste

    Energy Technology Data Exchange (ETDEWEB)

    Camaioni, Donald M.; Autrey, S. Tom; Dupuis, Michel

    2005-06-01

    This project aims to develop quantitative understanding of the significant chemical changes that highlevel waste (HLW) undergoes during storage, retrieval and treatment operations and computational capabilities to model that chemistry.

  18. Hanford Immobilized Low-Activity Waste Product Acceptance Test Plan

    International Nuclear Information System (INIS)

    Peeler, D.

    1999-01-01

    'The Hanford Site has been used to produce nuclear materials for the U.S. Department of Energy (DOE) and its predecessors. A large inventory of radioactive and mixed waste, largely generated during Pu production, exists in 177 underground single- and double-shell tanks. These wastes are to be retrieved and separated into low-activity waste (LAW) and high-level waste (HLW) fractions. The DOE is proceeding with an approach to privatize the treatment and immobilization of Handord''s LAW and HLW.'

  19. Hanford Immobilized Low-Activity Waste Product Acceptance Test Plan

    Energy Technology Data Exchange (ETDEWEB)

    Peeler, D.

    1999-06-22

    'The Hanford Site has been used to produce nuclear materials for the U.S. Department of Energy (DOE) and its predecessors. A large inventory of radioactive and mixed waste, largely generated during Pu production, exists in 177 underground single- and double-shell tanks. These wastes are to be retrieved and separated into low-activity waste (LAW) and high-level waste (HLW) fractions. The DOE is proceeding with an approach to privatize the treatment and immobilization of Handord''s LAW and HLW.'

  20. Evaluation and compilation of DOE waste package test data

    International Nuclear Information System (INIS)

    Interrante, C.G.; Escalante, E.; Fraker, A.C.

    1990-11-01

    This report summarizes evaluations by the National Institute of Standards and Technology (NIST) of Department of Energy (DOE) activities on waste packages designed for containment of radioactive high-level nuclear waste (HLW) for the six-month period August 1988 through January 1989. Included are reviews of related materials research and plans, activities for the DOE Materials Characterization Center, information on the Yucca Mountain Project, and other information regarding supporting research and special assistance. NIST comments are given on the Yucca Mountain Consultation Draft Site Characterization Plan (CDSCP) and on the Waste Compliance Plan for the West Valley Demonstration Project (WVDP) High-Level Waste (HLW) Form. 3 figs

  1. The Prior Internet Resources 2017

    DEFF Research Database (Denmark)

    Engerer, Volkmar Paul; Albretsen, Jørgen

    2017-01-01

    The Prior Internet Resources (PIR) are presented. Prior’s unpublished scientific manuscripts and his wast letter correspondence with fellow researchers at the time, his Nachlass, is now subject to transcription by Prior-researchers worldwide, and form an integral part of PIR. It is demonstrated...

  2. Demonstration of pyrometallurgical processing for metal fuel and HLW

    International Nuclear Information System (INIS)

    Tadafumi, Koyama; Kensuke, Kinoshita; Takatoshi, Hizikata; Tadashi, Inoue; Ougier, M.; Rikard, Malmbeck; Glatz, J.P.; Lothar, Koch

    2001-01-01

    CRIEPI and JRC-ITU have started a joint study on pyrometallurgical processing to demonstrate the capability of this type of process for separating actinide elements from spent fuel and HLW. The equipment dedicated for this experiments has been developed and installed in JRC-ITU. The stainless steel box equipped with tele-manipulators is operated under pure Ar atmosphere, and prepared for later installation in a hot cell. Experiments on pyro-processing of un-irradiated U-Pu-Zr metal alloy fuel by molten salt electrorefining has been carried out. Recovery of U and Pu from this type alloy fuel was first demonstrated with using solid iron cathode and liquid Cd cathode, respectively. (author)

  3. Development of gap filling technique in HLW repository

    International Nuclear Information System (INIS)

    Nakashima, Hitoshi; Saito, Akira; Ishii, Takashi; Toguri, Satohito; Okihara, Mitsunobu; Iwasa, Kengo

    2016-01-01

    HLW is supposed to be disposed underground at depths more than 300 m in Japan. Buffer is an artificial barrier that controls radionuclides migrating into the groundwater. The buffer would be made of a natural swelling clay, bentonite. Construction technology for the buffer has been studied for many years, but studies for the gaps surrounding the buffer are little. The proper handling of the gaps is important for guaranteeing the functions of the buffer. In this paper, gap filling techniques using bentonite pellets have been developed in order to the gap having the same performance as the buffer. A new method for manufacturing high-density spherical pellets has been developed to fill the gap higher density ever reported. For the bentonite pellets, the filling performance and how to use were determined. And full-scale filling tests provided availability of the bentonite pellets and filling techniques. (author)

  4. Performance Enhancements to the Hanford Waste Treatment and Immobilization Plant Low-Activity Waste Vitrification System

    International Nuclear Information System (INIS)

    Hamel, W. F.; Gerdes, K.; Holton, L. K.; Pegg, I.L.; Bowan, B.W.

    2006-01-01

    The U.S Department of Energy Office of River Protection (DOE-ORP) is constructing a Waste Treatment and Immobilization Plant (WTP) for the treatment and vitrification of underground tank wastes stored at the Hanford Site in Washington State. The WTP comprises four major facilities: a pretreatment facility to separate the tank waste into high level waste (HLW) and low-activity waste (LAW) process streams, a HLW vitrification facility to immobilize the HLW fraction; a LAW vitrification facility to immobilize the LAW fraction, and an analytical laboratory to support the operations of all four treatment facilities. DOE has established strategic objectives to optimize the performance of the WTP facilities and the LAW and HLW waste forms to reduce the overall schedule and cost for treatment and vitrification of the Hanford tank wastes. This strategy has been implemented by establishing performance expectations in the WTP contract for the facilities and waste forms. In addition, DOE, as owner-operator of the WTP facilities, continues to evaluate 1) the design, to determine the potential for performance above the requirements specified in the WTP contract; and 2) improvements in production of the LAW and HLW waste forms. This paper reports recent progress directed at improving production of the LAW waste form. DOE's initial assessment, which is based on the work reported in this paper, is that the treatment rate of the WTP LAW vitrification facility can be increased by a factor of 2 to 4 with a combination of revised glass formulations, modest increases in melter glass operating temperatures, and a second-generation LAW melter with a larger surface area. Implementing these improvements in the LAW waste immobilization capability can benefit the LAW treatment mission by reducing the cost of waste treatment. (authors)

  5. Managing fusion high-level waste-A strategy for burning the long-lived products in fusion devices

    International Nuclear Information System (INIS)

    El-Guebaly, L.A.

    2006-01-01

    Fusion devices appear to be a viable option for burning their own high-level waste (HLW). We propose a novel strategy to eliminate (or minimize) the HLW generated by fusion systems. The main source of the fusion HLW includes the structural and recycled materials, refractory metals, and liquid breeders. The basic idea involves recycling and reprocessing the waste, separating the long-lived radionuclides from the bulk low-level waste, and irradiating the limited amount of HLW in a specially designed module to transmute the long-lived products into short-lived radioisotopes or preferably, stable elements. The potential performance of the new concept seems promising. Our analysis indicated moderate to excellent transmutation rates could be achieved in advanced fusion designs. Successive irradiation should burn the majority of the HLW. The figures of merit for the concept relate to the HLW burn-up fraction, neutron economy, and impact on tritium breeding. Hopefully, the added design requirements could be accommodated easily in fusion power plants and the cost of the proposed system would be much less than disposal in a deep geological HLW repository. Overall, this innovative approach offers benefits to fusion systems and helps earn public acceptance for fusion as a HLW-free source of clean nuclear energy

  6. An analytical hierarchy process for decision making of high-level-waste management

    International Nuclear Information System (INIS)

    Wang, J.H.C.; Jang, W.

    1995-01-01

    To prove the existence value of nuclear technology for the world of post cold war, demonstration of safe rad-waste disposal is essential. High-level-waste (HLW) certainly is the key issue to be resolved. To assist a rational and persuasive process on various disposal options, an Analytical Hierarchy Process (AHP) for the decision making of HLW management is presented. The basic theory and rationale are discussed, and applications are shown to illustrate the usefulness of the AHP. The authors wish that the AHP can provide a better direction for the current doomed situations of Taiwan nuclear industry, and to exchange with other countries for sharing experiences on the HLW management

  7. High Level Waste plant operation and maintenance concepts. Final report, March 27, 1995

    International Nuclear Information System (INIS)

    Janicek, G.P.

    1995-01-01

    The study reviews and evaluates worldwide High Level Waste (HLW) vitrification operating and maintenance (O ampersand M) philosophies, plant design concepts, and lessons learned with an aim towards developing O ampersand M recommendations for either, similar implementation or further consideration in a HLW vitrification facility at Hanford. The study includes a qualitative assessment of alternative concepts for a variety of plant and process systems and subsystems germane to HLW vitrification, such as, feed materials handling, melter configuration, glass form, canister handling, failed equipment handling, waste handling, and process control. Concept evaluations and recommendations consider impacts to Capital Cost, O ampersand M Cost, ALARA, Availability, and Reliability

  8. Cleanup of a HLW nuclear fuel-reprocessing center using 3-D database modeling technology

    International Nuclear Information System (INIS)

    Sauer, R.C.

    1992-01-01

    A significant challenge in decommissioning any large nuclear facility is how to solidify the large volume of residual high-level radioactive waste (HLW) without structurally interfering with the existing equipment and piping used at the original facility or would require rework due to interferences which were not identified during the design process. This problem is further compounded when the nuclear facility to be decommissioned is a 35 year old nuclear fuel reprocessing center designed to recover usable uranium and plutonium. Facilities of this vintage usually tend to lack full documentation of design changes made over the years and as a result, crude traps or pockets of high-level contamination may not be fully realized. Any miscalculation in the construction or modification sequences could compound the overall dismantling and decontamination of the facility. This paper reports that development of a 3-dimensional (3-D) computer database tool was considered critical in defining the most complex portions of this one-of-a-kind vitrification facility

  9. Storage of HLW in engineered structures: air-cooled and water-cooled concepts

    International Nuclear Information System (INIS)

    Ahner, S.; Dekais, J.J.; Puttke, B.; Staner, P.

    1981-01-01

    A comparative study on an air-cooled and a water-cooled intermediate storage of vitrified, highly radioactive waste (HLW) in overground installations has been performed by Nukem and Belgonucleaire respectively. In the air-cooled storage concept the decay heat from the storage area will be removed using natural convection. In the water-cooled storage concept the decay heat is carried off by a primary and secondary forced-cooling system with redundant and diverse devices. The safety study carried out by Nukem used a fault tree method. It shows that the reliability of the designed water-cooled system is very high and comparable to the inherent, safe, air-cooled system. The impact for both concepts on the environment is determined by the release route, but even during accident conditions the release is far below permissible limits. The economic analysis carried out by Belgonucleaire shows that the construction costs for both systems do not differ very much, but the operation and maintenance costs for the water-cooled facility are higher than for the air cooled facility. The result of the safety and economic analysis and the discussions with the members of the working group have shown some possible significant modifications for both systems, which are included in this report. The whole study has been carried out using certain national criteria which, in certain Member States at least, would lead to a higher standard of safety than can be justified on any social, political or economic grounds

  10. Seismic design evaluation guidelines for buried piping for the DOE HLW Facilities

    International Nuclear Information System (INIS)

    Lin, Chi-Wen; Antaki, G.; Bandyopadhyay, K.; Bush, S.H.; Costantino, C.; Kennedy, R.

    1995-01-01

    This paper presents the seismic design and evaluation guidelines for underground piping for the Department of Energy (DOE) High-Level-Waste (HLW) Facilities. The underground piping includes both single and double containment steel pipes and concrete pipes with steel lining, with particular emphasis on the double containment piping. The design and evaluation guidelines presented in this paper follow the generally accepted beam-on-elastic-foundation analysis principle and the inertial response calculation method, respectively, for piping directly in contact with the soil or contained in a jacket. A standard analysis procedure is described along with the discussion of factors deemed to be significant for the design of the underground piping. The following key considerations are addressed: the design feature and safety requirements for the inner (core) pipe and the outer pipe; the effect of soil strain and wave passage; assimilation of the necessary seismic and soil data; inertial response calculation for the inner pipe; determination of support anchor movement loads; combination of design loads; and code comparison. Specifications and justifications of the key parameters used, stress components to be calculated and the allowable stress and strain limits for code evaluation are presented

  11. Preliminary waste acceptance criteria for the ICPP spent fuel and waste management technology development program

    International Nuclear Information System (INIS)

    Taylor, L.L.; Shikashio, R.

    1993-09-01

    The purpose of this document is to identify requirements to be met by the Producer/Shipper of Spent Nuclear Fuel/High-LeveL Waste SNF/HLW in order for DOE to be able to accept the packaged materials. This includes defining both standard and nonstandard waste forms

  12. Characteristics of borosilicate waste glass form for high-level radioactive waste

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Seung Soo; Chun, Kwan Sik; Choi, Jong Won; Kang, Chul Hyung

    2001-03-01

    Basic data, required for the design and the performance assessment of a repository of HLW, suchas the chemical composition and the characteristics of the borosilicate waste glass have been identified according to the burn-ups of spent PWR fuels. The diemnsion of waste canister is 430mm in diameter and 1135mm in length, and the canister should hold less than 2kwatts of heat from their decay of radionuclides contained in the HLW. Based on the reprocessing of 5 years-cooled spent fuel, one canister could hold about 11.5wt.% and 10.8wt.% of oxidized HLW corresponding to their burn-ups of 45,000MWD/MTU and 55,000MWD/MTU, respectively. These waste forms have been recommanded as the reference waste forms of HLW. The characteristics of these wastes as a function of decay time been evaluated. However, after a specific waste form and a specific site for the disposal would be selected, the characteristics of the waste should be reevaluated under the consideration of solidification period, loaded waste, storage condition and duration, site circumstances for the repository system and its performance assessment.

  13. Waste-rock interactions in the immediate repository

    International Nuclear Information System (INIS)

    McCarthy, G.J.

    1977-01-01

    The high level wastes (HLW's) to be placed underground in rock formations will contain significant amounts of radioactive decay heat for the first hundred-or-so years of isolation. Several physical-chemical changes analogous to natural geochemical processes can occur during this ''thermal period.'' The waste canister can act as a heat source and cause changes in the mineralogy and properties of the surrounding rocks. Geochemically, this is ''contact metamorphism.'' In the event that the canister is corroded and breached, chemical reactions can occur between the HLW, the surrounding rock and possibly the remains of the canister. In a dry repository which has not been backfilled (and thus pressurized) these interactions could be slow at best and with rates decreasing rapidly as the HLW cools. However, significant interactions can occur in years, months or even days under hydrothermal conditions. These conditions could be created by the combination of HLW heat, overburden pressure and water mobilized from the rocks or derived from groundwater intrusion. At the end of the thermal period these interaction products would constitute the actual HLW form (or ''source term'') subject to the low temperature leaching and migration processes under investigation in other laboratories. It is quite possible that these interaction product waste forms will have superior properties compared to the original HLW. Experimental programs initiated at Penn State during the last year aim at determining the nature of any chemical or mineralogical changes in, or interactions between, HLW solids and host rocks under various repository ambients. The accompanying figures describe the simulated HLW forms and the experimental approach and techniques. Studies with basalts as the repository rock are supported by Rockwell Hanford Operations and with shales by the Office of Waste Isolation

  14. High-level waste issues and resolutions document

    International Nuclear Information System (INIS)

    1994-05-01

    The High-Level Waste (HLW) Issues and Resolutions Document recognizes US Department of Energy (DOE) complex-wide HLW issues and offers potential corrective actions for resolving these issues. Westinghouse Management and Operations (M ampersand O) Contractors are effectively managing HLW for the Department of Energy at four sites: Idaho National Engineering Laboratory (INEL), Savannah River Site (SRS), West Valley Demonstration Project (WVDP), and Hanford Reservation. Each site is at varying stages of processing HLW into a more manageable form. This HLW Issues and Resolutions Document identifies five primary issues that must be resolved in order to reach the long-term objective of HLW repository disposal. As the current M ampersand O contractor at DOE's most difficult waste problem sites, Westinghouse recognizes that they have the responsibility to help solve some of the complexes' HLW problems in a cost effective manner by encouraging the M ampersand Os to work together by sharing expertise, eliminating duplicate efforts, and sharing best practices. Pending an action plan, Westinghouse M ampersand Os will take the initiative on those corrective actions identified as the responsibility of an M ampersand O. This document captures issues important to the management of HLW. The proposed resolutions contained within this document set the framework for the M ampersand Os and DOE work cooperatively to develop an action plan to solve some of the major complex-wide problems. Dialogue will continue between the M ampersand Os, DOE, and other regulatory agencies to work jointly toward the goal of storing, treating, and immobilizing HLW for disposal in an environmentally sound, safe, and cost effective manner

  15. An Assessment of Using Vibrational Compaction of Calcined HLW and LLW in DWPF Canisters

    International Nuclear Information System (INIS)

    Yi, Yun-Bo; Amme, Robert C.; Shayer, Zeev

    2008-01-01

    both of them) of applying the vibrational forces? 2) What is best mode of operation: first fill the canister with calcined waste and then vibrate it and refill it again, or apply vibrational forces during the filling process. By optimum or best we mean less creation of stress/strain forces during the volume reduction vibration process. Lessons learnt: This preliminary study shows that; 1) The maximum stress concentration always occurs in the canister wall, however its location varies and depends on the loading condition, and vibration process. 2) The proposed vibrational process would not cause any damages to the granulated calcined waste. 3) The first natural frequency of the longitudinal vibration of the canister is around 400 Hz, which is far away from the applied vibrational frequencies and from possibility of resonance phenomena that may cause damage to the canister 4) The relationship between the maximum internal stress and the frequency of the applied load is not parabolic. 5) The mechanical properties of the granulated calcined nuclear waste have small impact on the internal stress of the canister. Finally, the calculated data suggested that applying vibrational forces will keep the entire canister whole without any indication of development defects, and will have significant economical benefits of handling HLW and LLW in calcined forms, from waste manipulation, storage and transportation

  16. Determination of alpha dose rate profile at the HLW nuclear glass/water interface

    Energy Technology Data Exchange (ETDEWEB)

    Mougnaud, S., E-mail: sarah.mougnaud@cea.fr [CEA Marcoule, DEN/DTCD/SECM, BP 17171, 30207 Bagnols-sur-Cèze cedex (France); Tribet, M.; Rolland, S. [CEA Marcoule, DEN/DTCD/SECM, BP 17171, 30207 Bagnols-sur-Cèze cedex (France); Renault, J.-P. [CEA Saclay, NIMBE UMR 3685 CEA/CNRS, 91191 Gif-sur-Yvette cedex (France); Jégou, C. [CEA Marcoule, DEN/DTCD/SECM, BP 17171, 30207 Bagnols-sur-Cèze cedex (France)

    2015-07-15

    Highlights: • The nuclear glass/water interface is studied. • The way the energy of alpha particles is deposited is modeled using MCNPX code. • A model giving dose rate profiles at the interface using intrinsic data is proposed. • Bulk dose rate is a majoring estimation in alteration layer and in surrounding water. • Dose rate is high in small cracks; in larger ones irradiated volume is negligible. - Abstract: Alpha irradiation and radiolysis can affect the alteration behavior of High Level Waste (HLW) nuclear glasses. In this study, the way the energy of alpha particles, emitted by a typical HLW glass, is deposited in water at the glass/water interface is investigated, with the aim of better characterizing the dose deposition at the glass/water interface during water-induced leaching mechanisms. A simplified chemical composition was considered for the nuclear glass under study, wherein the dose rate is about 140 Gy/h. The MCNPX calculation code was used to calculate alpha dose rate and alpha particle flux profiles at the glass/water interface in different systems: a single glass grain in water, a glass powder in water and a water-filled ideal crack in a glass package. Dose rate decreases within glass and in water as distance to the center of the grain increases. A general model has been proposed to fit a dose rate profile in water and in glass from values for dose rate in glass bulk, alpha range in water and linear energy transfer considerations. The glass powder simulation showed that there was systematic overlapping of radiation fields for neighboring glass grains, but the water dose rate always remained lower than the bulk value. Finally, for typical ideal cracks in a glass matrix, an overlapping of irradiation fields was observed while the crack aperture was lower than twice the alpha range in water. This led to significant values for the alpha dose rate within the crack volume, as long as the aperture remained lower than 60 μm.

  17. Study on a transportation and emplacement system of pre-assembled EBS module for HLW geological disposal

    International Nuclear Information System (INIS)

    Awano, Toshihiko; Kanno, Takeshi; Katsumata, Syunsuke; Kosuge, Kazuhiro

    2009-01-01

    HLW disposal is one of the largest issue to utilize Nuclear power safely. In the past study, the concept, which buffer materials and Overpacked waste were transported into underground respectively, have shown. The concept of pre-assembled engineered barrier has advantage to simplify the logistics and emplacement procedure, however there are difficulties to support heavy weight of pre-assembled package by equipment under the condition of little clearance between tunnel and package. In this study, Combination of air bearing and two degree-of-freedom wheels were suggested for transportation, and air jack was suggested for unloading and emplacement system. Also, whole system for transportation and emplacement procedure was designed, and Scale model test was examined to evaluate the feasibility of these concept and functions. (author)

  18. Alternative biosphere modeling for safety assessment of HLW disposal taking account of geosphere-biosphere interface of marine environment

    International Nuclear Information System (INIS)

    Kato, Tomoko; Ishiguro, Katsuhiko; Naito, Morimasa; Ikeda, Takao; Little, Richard

    2001-03-01

    In the safety assessment of a high-level radioactive waste (HLW) disposal system, it is required to estimate radiological impacts on future human beings arising from potential radionuclide releases from a deep repository into the surface environment. In order to estimated the impacts, a biosphere model is developed by reasonably assuming radionuclide migration processes in the surface environment and relevant human lifestyles. It is important to modify the present biosphere models or to develop alternative biosphere models applying the biosphere models according to quality and quantify of the information acquired through the siting process for constructing the repository. In this study, alternative biosphere models were developed taking geosphere-biosphere interface of marine environment into account. Moreover, the flux to dose conversion factors calculated by these alternative biosphere models was compared with those by the present basic biosphere models. (author)

  19. A comparison of three methods for determining the amount of nitric acid needed to treat HLW sludge at SRS

    International Nuclear Information System (INIS)

    Siegwald, S.F.; Ferrara, D.M.

    1994-01-01

    A comparison was made of three methods for determining the amount of nitric acid which will be needed to treat a sample of high-level waste (HLW) sludge from the Savannah River Site (SRS) Tank Farm. The treatment must ensure the resulting melter feed will have the necessary rheological and oxidation-reduction properties, reduce mercury and manganese in the sludge, and be performed in a fashion which does not produce a flammable gas mixture. The three methods examined where an empirical method based on pH measurements, a computational method based on known reactions of the species in the sludge and a titration based on neutralization of carbonate in the solution

  20. Microcrack growing and long-term mechanical stability in a HLW deep-borehole repository in granite

    International Nuclear Information System (INIS)

    Biurrun, E.; Hahne, K.

    1989-01-01

    The long-term host rock integrity assessment of a deep borehole emplacement for HLW in granite has been addressed with a detailed new constitutive model considering temperature and pressure effects on microscale phenomena (as microcracking) under repository conditions. The results of these finite element calculations have been compared with results obtained using conventional, state-of-the-art constitutive modelling. While the results of conventional modelling did suggest the existence of an important safety margin before failure, the improved calculations with the new model predict a thin but very long region of degradated host rock along the waste canister column. The results obtained up to now may well be considered as safety relevant, because they suggest that the actual long-term granite strength lies well below the conventionally determined failure limits, thus challenging the barrier properties of this host rock if the actual strength is not properly considered in the repository design

  1. Studies of mechanisms and processes of relevance to the safety of nuclear waste repositories, as carried out prior to, during and after flovelling of the Hope potash salt mine

    International Nuclear Information System (INIS)

    1985-01-01

    Studies on the effects of a hypothetical accident involving water or brine intrusion into a waste repository in a salt mine are of special importance within the framework of safety assessments of salt formations as candidate sites for nuclear waste repositories. The measuring activities under review include the following: Physicochemical measurements for determining dissolution and recipitation of salts, transport mechanisms, temperature curves, natural build-up and efficiency of geochemical barriers in the brine. Geochemical measurements for obtaining information on the rock deformation prior to, during, and after flovelling. Geophysical measurements of microseismic behaviour of rock masses prior to, during, and after flovelling. Examination of an artificial barrier structure for the testing and assessment of technical barriers and their efficiency. (orig./HP) [de

  2. Characteristics of potential repository wastes

    International Nuclear Information System (INIS)

    1992-07-01

    This document, and its associated appendices and microcomputer (PC) data bases, constitutes the reference OCRWM data base of physical and radiological characteristics data of radioactive wastes. This Characteristics Data Base (CDB) system includes data on spent nuclear fuel and high-level waste (HLW), which clearly require geologic disposal, and other wastes which may require long-term isolation, such as sealed radioisotope sources. The data base system was developed for OCRWM by the CDB Project at Oak Ridge National Laboratory. Various principal or official sources of these data provided primary information to the CDB Project which then used the ORIGEN2 computer code to calculate radiological properties. The data have been qualified by an OCRWM-sponsored peer review as suitable for quality-affecting work meeting the requirements of OCRWM's Quality Assurance Program. The wastes characterized in this report include: light-water reactor (LWR) spent fuel and immobilized HLW

  3. The solubilities of significant organic compounds in HLW tank supernate solutions -- FY 1995 progress report

    International Nuclear Information System (INIS)

    Barney, G.S.

    1996-01-01

    At the Hanford Site organic compounds were measured in tank supernate simulant solutions during FY 1995. This solubility information will be used to determine if these organic salts could exist in solid phases (saltcake or sludges) in the waste where they might react violently with the nitrate or nitrite salts present in the tanks. Solubilities of sodium glycolate, succinate, and caproate salts; iron and aluminum and butylphosphate salts; and aluminum oxalate were measured in simulated waste supernate solutions at 25 degree C, 30 degree C, 40 degree C, and 50 degree C. The organic compounds were selected because they are expected to exist in relatively high concentrations in the tanks. The solubilities of sodium glycolate, succinate, caproate, and butylphosphate in HLW tank supernate solutions were high over the temperature and sodium hydroxide concentration ranges expected in the tanks. High solubilities will prevent solid sodium salts of these organic acids from precipitating from tank supernate solutions. The total organic carbon concentrations (YOC) of actual tank supernates are generally much lower than the TOC ranges for simulated supernate solutions saturated (at the solubility limit) with the organic salts. This is so even if all the dissolved carbon in a given tank and supernate is due to only one of these eight soluble compounds (an unlikely situation). Metal ion complexes of and butylphosphate and oxalate in supernate solutions were not stable in the presence of the hydroxide concentrations expected in most tanks. Iron and aluminum dibutylphosphate compounds reacted with hydroxide to form soluble sodium dibutylphosphate and precipitated iron and aluminum hydroxides. Aluminum oxalate complexes were also not stable in the basic simulated supernate solutions. Solubilities of all the organic salts decrease with increasing sodium hydroxide concentration because of the common ion effect of Na+. Increasing temperatures raised the solubilities of the organic

  4. The experiment of affective web risk communication on HLW geological disposal

    International Nuclear Information System (INIS)

    Kugo, Akihide; Yoshikawa, Eiwa; Wakabayashi, Yasunaga; Shimoda, Hiroshi; Uda, Akinobu; Ito, Kyoko

    2006-01-01

    Dialog mode web contents regarding the HLW risk is effective to altruism. To make it more effectively, we introduced affective elements such as facial expression of character agents and sympathetic response on the BBS by experts, which brought us smooth risk communication. This paper describes the result of preliminary experiments surrounding the affective ways to communicate on the risk of HLW geological disposal, leading to enhance the social cooperation, and the public open experiment for one month on the Web. (author)

  5. Nuclide transport models for HLW repository safety assessment in Finland, Japan, Sweden, and Canada

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Young Myoung; Kang, Chul Hyung; Hwang, Yong Soo; Choi, Jong Won; Kim, Sung Gi; Koh, Won Il

    1997-10-01

    Disposal and design concepts in such countries as Sweden, Finland, Canada and Japan which have already published safety assessment reports for the HLW repositories have been reviewed mainly in view of nuclide transport models used in their assessment. This kind of review would be very helpful in doing similar research in Korea where research program regarding HLW has been just started. (author). 44 refs., 2 tabs., 30 figs

  6. Final Report Melter Tests With AZ-101 HLW Simulant Using A Duramelter 100 Vitrification System VSL-01R10N0-1, Rev. 1, 2/25/02

    International Nuclear Information System (INIS)

    Kruger, A.A.; Matlack, K.S.; Kot, W.K.; Pegg, I.L.

    2011-01-01

    This report provides data, analyses, and conclusions from a series of tests that were conducted at the Vitreous State Laboratory of The Catholic of America (VSL) to determine the processing rates that are achievable with AZ-101 HLW simulants and corresponding melter feeds on a DuraMelter 100 (DM100) vitrification system. One of the most critical pieces of information in determining the required size of the RPP-WTP HLW melter is the specific glass production rate in terms of the mass of glass that can be produced per unit area of melt surface per unit time. The specific glass production rate together with the waste loading (essentially, the ratio of waste-in to glass-out, which is determined from glass formulation activities) determines the melt area that is needed to achieve a given waste processing rate with due allowance for system availability. Tests conducted during Part B1 (VSL-00R2590-2) on the DM1000 vitrification system installed at the Vitreous State Laboratory of The Catholic University of America showed that, without the use of bubblers, glass production rates with AZ-101 and C-106/AY-102 simulants were significantly lower than the Project design basis rate of 0.4 MT/m 2 /d. Conversely, three-fold increases over the design basis rate were demonstrated with the use of bubblers. Furthermore, an un-bubbled control test using a replica of the melter feed used in cold commissioning tests at West Valley reproduced the rates that were observed with that feed on the WVDP production melter. More recent tests conducted on the DM1200 system, which more closely represents the present RPP-WTP design, are in general agreement with these earlier results. Screening tests conducted on the DM10 system have provided good indications of the larger-scale processing rates with bubblers (for both HL W and LAW feeds) but significantly overestimated the DM1000 un-bubbled rate observed for C-106/AY-102 melter feeds. This behavior is believed to be a consequence of the role of

  7. FINAL REPORT MELTER TESTS WITH AZ-101 HLW SIMULANT USING A DURAMELTER 100 VITRIFICATION SYSTEM VSL-01R10N0-1 REV 1 2/25/02

    Energy Technology Data Exchange (ETDEWEB)

    KRUGER AA; MATLACK KS; KOT WK; PEGG IL

    2011-12-29

    This report provides data, analyses, and conclusions from a series of tests that were conducted at the Vitreous State Laboratory of The Catholic of America (VSL) to determine the processing rates that are achievable with AZ-101 HLW simulants and corresponding melter feeds on a DuraMelter 100 (DM100) vitrification system. One of the most critical pieces of information in determining the required size of the RPP-WTP HLW melter is the specific glass production rate in terms of the mass of glass that can be produced per unit area of melt surface per unit time. The specific glass production rate together with the waste loading (essentially, the ratio of waste-in to glass-out, which is determined from glass formulation activities) determines the melt area that is needed to achieve a given waste processing rate with due allowance for system availability. Tests conducted during Part B1 (VSL-00R2590-2) on the DM1000 vitrification system installed at the Vitreous State Laboratory of The Catholic University of America showed that, without the use of bubblers, glass production rates with AZ-101 and C-106/AY-102 simulants were significantly lower than the Project design basis rate of 0.4 MT/m{sup 2}/d. Conversely, three-fold increases over the design basis rate were demonstrated with the use of bubblers. Furthermore, an un-bubbled control test using a replica of the melter feed used in cold commissioning tests at West Valley reproduced the rates that were observed with that feed on the WVDP production melter. More recent tests conducted on the DM1200 system, which more closely represents the present RPP-WTP design, are in general agreement with these earlier results. Screening tests conducted on the DM10 system have provided good indications of the larger-scale processing rates with bubblers (for both HL W and LAW feeds) but significantly overestimated the DM1000 un-bubbled rate observed for C-106/AY-102 melter feeds. This behavior is believed to be a consequence of the role of

  8. Development and application of a conceptual approach for defining high-level waste

    International Nuclear Information System (INIS)

    Croff, A.G.; Forsberg, C.W.; Kocher, D.C.; Cohen, J.J.; Smith, C.F.; Miller, D.E.

    1986-01-01

    This paper presents a conceptual approach to defining high-level radioactive waste (HLW) and a preliminary quantitative definition obtained from an example implementation of the conceptual approach. On the basis of the description of HLW in the Nuclear Waste Policy Act of 1982, we have developed a conceptual model in which HLW has two attributes: HLW is (1) highly radioactive and (2) requires permanent isolation via deep geologic disposal. This conceptual model results in a two-dimensional waste categorization system in which one axis, related to ''requires permanent isolation,'' is associated with long-term risks from waste disposal and the other axis, related to ''highly radioactive,'' is associated with short-term risks from waste management and operations; this system also leads to the specification of categories of wastes that are not HLW. Implementation of the conceptual model for defining HLW was based primarily on health and safety considerations. Wastes requiring permanent isolation via deep geologic disposal were defined by estimating the maximum concentrations of radionuclides that would be acceptable for disposal using the next-best technology, i.e., greater confinement disposal (GCD) via intermediate-depth burial or engineered surface structures. Wastes that are highly radioactive were defined by adopting heat generation rate as the appropriate measure and examining levels of decay heat that necessitate special methods to control risks from operations in a variety of nuclear fuel-cycle situations. We determined that wastes having a power density >200 W/m 3 should be considered highly radioactive. Thus, in the example implementation, the combination of maximum concentrations of long-lived radionuclides that are acceptable for GCD and a power density of 200 W/m 3 provides boundaries for defining wastes that are HLW

  9. Characterization of high level waste for minor actinides by chemical separation and alpha spectrometry

    International Nuclear Information System (INIS)

    Murali, M.S.; Bhattacharayya, A.; Kar, A.S.; Tomar, B.S.; Manchanda, V.K.

    2010-01-01

    Quantification of minor actinides present in of High Level Waste (HLW) solutions originating from the power reactors is important in view of management of radioactive wastes and actinide partitioning. Several methods such as ICP-MS, X-ray fluorescence methods, ICP-AES, alpha spectrometry are used in characterizing such types of wastes. As alpha spectrometry is simple and reliable, this technique has been used for the estimation of minor actinides after devising steps of separation for estimating Np and Pu present in HLW solutions of PHWR origin. Using a wealth of knowledge appropriate to the solution chemistry of actinides, the task of separation, though appears easy, it is challenging job for a radiochemist handling high-dose HLW samples, for obtaining clean alpha peaks for Np and Pu. This paper reports on the successful attempt made to quantify 241 Am, 244 Cm, Pu (239 mainly) and 237 Np present in HLW-PHWR obtained from PREFRE, Tarapur

  10. Final Report Determination Of The Processing Rate Of RPP-WTP HLW Simulants Using A Duramelter J 1000 Vitrification System VSL-00R2590-2, Rev. 0, 8/21/00

    International Nuclear Information System (INIS)

    Kruger, A.A.; Matlack, K.S.; Kot, W.K.; Perez-Cardenas, F.; Pegg, I.L.

    2011-01-01

    This report provides data, analysis, and conclusions from a series of tests that were conducted at the Vitreous State Laboratory of The Catholic University of America (VSL) to determine the melter processing rates that are achievable with RPP-WTP HLW simulants. The principal findings were presented earlier in a summary report (VSL-00R2S90-l) but the present report provides additional details. One of the most critical pieces of information in determining the required size of the RPP-WTP HLW melter is the specific glass production rate in terms of the mass of glass that can be produced per unit area of melt surface per unit time. The specific glass production rate together with the waste loading (essentially, the ratio of waste-in to glass-out, which is determined from glass formulation activities) determines the melt area that is needed to achieve a given waste processing rate with due allowance for system availability. As a consequence of the limited amount of relevant information, there exists, for good reasons, a significant disparity between design-base specific glass production rates for the RPP-WTP LAW and HLW conceptual designs (1.0 MT/m 2 /d and 0.4 MT/m 2 /d, respectively); furthermore, small-scale melter tests with HLW simulants that were conducted during Part A indicated typical processing rates with bubbling of around 2.0 MT/m 2 /d. This range translates into more than a factor of five variation in the resultant surface area of the HLW melter, which is clearly not without significant consequence. It is clear that an undersized melter is undesirable in that it will not be able to support the required waste processing rates. It is less obvious that there are potential disadvantages associated with an oversized melter, over and above the increased capital costs. A melt surface that is consistently underutilized will have poor cold cap coverage, which will result in increased volatilization from the melt (which is generally undesirable) and increased plenum

  11. FINAL REPORT DETERMINATION OF THE PROCESSING RATE OF RPP WTP HLW SIMULANTS USING A DURAMELTER J 1000 VITRIFICATION SYSTEM VSL-00R2590-2 REV 0 8/21/00

    Energy Technology Data Exchange (ETDEWEB)

    KRUGER AA; MATLACK KS; KOT WK; PEREZ-CARDENAS F; PEGG IL

    2011-12-29

    This report provides data, analysis, and conclusions from a series of tests that were conducted at the Vitreous State Laboratory of The Catholic University of America (VSL) to determine the melter processing rates that are achievable with RPP-WTP HLW simulants. The principal findings were presented earlier in a summary report (VSL-00R2S90-l) but the present report provides additional details. One of the most critical pieces of information in determining the required size of the RPP-WTP HLW melter is the specific glass production rate in terms of the mass of glass that can be produced per unit area of melt surface per unit time. The specific glass production rate together with the waste loading (essentially, the ratio of waste-in to glass-out, which is determined from glass formulation activities) determines the melt area that is needed to achieve a given waste processing rate with due allowance for system availability. As a consequence of the limited amount of relevant information, there exists, for good reasons, a significant disparity between design-base specific glass production rates for the RPP-WTP LAW and HLW conceptual designs (1.0 MT/m{sup 2}/d and 0.4 MT/m{sup 2}/d, respectively); furthermore, small-scale melter tests with HLW simulants that were conducted during Part A indicated typical processing rates with bubbling of around 2.0 MT/m{sup 2}/d. This range translates into more than a factor of five variation in the resultant surface area of the HLW melter, which is clearly not without significant consequence. It is clear that an undersized melter is undesirable in that it will not be able to support the required waste processing rates. It is less obvious that there are potential disadvantages associated with an oversized melter, over and above the increased capital costs. A melt surface that is consistently underutilized will have poor cold cap coverage, which will result in increased volatilization from the melt (which is generally undesirable) and

  12. Ramifications of defining high-level waste

    International Nuclear Information System (INIS)

    Wood, D.E.; Campbell, M.H.; Shupe, M.W.

    1987-01-01

    The Nuclear Regulatory Commission (NRC) is considering rule making to provide a concentration-based definition of high-level waste (HLW) under authority derived from the Nuclear Waste Policy Act (NWPA) of 1982 and the Low Level Waste Policy Amendments Act of 1985. The Department of Energy (DOE), which has the responsibility to dispose of certain kinds of commercial waste, is supporting development of a risk-based classification system by the Oak Ridge National Laboratory to assist in developing and implementing the NRC rule. The system is two dimensional, with the axes based on the phrases highly radioactive and requires permanent isolation in the definition of HLW in the NWPA. Defining HLW will reduce the ambiguity in the present source-based definition by providing concentration limits to establish which materials are to be called HLW. The system allows the possibility of greater-confinement disposal for some wastes which do not require the degree of isolation provided by a repository. The definition of HLW will provide a firm basis for waste processing options which involve partitioning of waste into a high-activity stream for repository disposal, and a low-activity stream for disposal elsewhere. Several possible classification systems have been derived and the characteristics of each are discussed. The Defense High Level Waste Technology Lead Office at DOE - Richland Operations Office, supported by Rockwell Hanford Operations, has coordinated reviews of the ORNL work by a technical peer review group and other DOE offices. The reviews produced several recommendations and identified several issues to be addressed in the NRC rule making. 10 references, 3 figures

  13. High-level waste description, inventory and hazard

    International Nuclear Information System (INIS)

    Crandall, J.; Hennelly, E.J.; McElroy, J.L.

    1983-01-01

    High-level nuclear waste (HLW), including its origin, is described and the current differences in definitions discussed. Quantities of defense and commercial radioactive HLW, both volume and curie content, are given. Current waste handling, which is interimin nature, is described for the several sites. The HLW hazard is defined by the times during which various radionuclides are the dominant contributors. The hazard is also compared to that of the ore. Using ICRP-2, which is the legal reference in the US, the hazard of the waste reduces to a level equal to the ore in about 300 years. The disposal plans are summarized and it is shown that regulatory requirements will probably govern disposal operations in such a conservative manner that the risk (product of hazard times probability of release) may well be lower than for any other wastes in existence or perhaps lower than those for any other human endeavor

  14. Glass formulation for phase 1 high-level waste vitrification

    International Nuclear Information System (INIS)

    Vienna, J.D.; Hrma, P.R.

    1996-04-01

    The purpose of this study is to provide potential glass formulations for prospective Phase 1 High-Level Waste (HLW) vitrification at Hanford. The results reported here will be used to aid in developing a Phase 1 HLW vitrification request for proposal (RFP) and facilitate the evaluation of ensuing proposals. The following factors were considered in the glass formulation effort: impact on total glass volume of requiring the vendor to process each of the tank compositions independently versus as a blend; effects of imposing typical values of B 2 O 3 content and waste loading in HLW borosilicate glasses as restrictions on the vendors (according to WAPS 1995, the typical values are 5--10 wt% B 2 O 3 and 20--40 wt% waste oxide loading); impacts of restricting the processing temperature to 1,150 C on eventual glass volume; and effects of caustic washing on any of the selected tank wastes relative to glass volume

  15. Development of high-level waste solidification technology 1

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Joon Hyung; Kim, Hwan Young; Kim, In Tae [and others

    1999-02-01

    Spent nuclear fuel contains useful nuclides as valuable resource materials for energy, heat and catalyst. High-level wastes (HLW) are expected to be generated from the R and D activities and reuse processes. It is necessary to develop vitrification or advanced solidification technologies for the safe long-term management of high level wastes. As a first step to establish HLW vitrification technology, characterization of HLWs that would arise at KAERI site, glass melting experiments with a lab-scale high frequency induction melter, and fabrication and property evaluation of base-glass made of used HEPA filter media and additives were performed. Basic study on the fabrication and characterization of candidate ceramic waste form (Synroc) was also carried out. These HLW solidification technologies would be directly useful for carrying out the R and Ds on the nuclear fuel cycle and waste management. (author). 70 refs., 29 tabs., 35 figs.

  16. Proposed classification scheme for high-level and other radioactive wastes

    International Nuclear Information System (INIS)

    Kocher, D.C.; Croff, A.G.

    1986-01-01

    The Nuclear Waste Policy Act (NWPA) of 1982 defines high-level radioactive waste (HLW) as: (A) the highly radioactive material resulting from the reprocessing of spent nuclear fuel....that contains fission products in sufficient concentrations; and (B) other highly radioactive material that the Commission....determines....requires permanent isolation. This paper presents a generally applicable quantitative definition of HLW that addresses the description in paragraph (B). The approach also results in definitions of other waste classes, i.e., transuranic (TRU) and low-level waste (LLW). A basic waste classification scheme results from the quantitative definitions

  17. Evaluation of forms for the immobilization of high-level and transuranic wastes

    International Nuclear Information System (INIS)

    Schuman, R.P.; Cox, N.D.; Gibson, G.W.; Kelsey, P.V. Jr.

    1982-08-01

    A figure-of-merit (FOM) analysis has been made of a number of waste forms for solidifying both defense and commercial high-level reprocessing waste (HLW) and transuranic (TRU) wastes. The evaluation includes iron-enriched basalt (IEB), a fusion-produced glass-ceramic, which has not been included in other assessments. For HLW, concrete receives the highest FOM, but may not meet regulatory requirements; IEB and glass are the best choices of the materials that should easily meet regulatory requirements. Concrete waste forms are the best choice for TRU wastes, with IEB a close contender. 116 references, 3 figures, 112 tables

  18. Tank waste remediation system optimized processing strategy with an altered treatment scheme

    International Nuclear Information System (INIS)

    Slaathaug, E.J.

    1996-03-01

    This report provides an alternative strategy evolved from the current Hanford Site Tank Waste Remediation System (TWRS) programmatic baseline for accomplishing the treatment and disposal of the Hanford Site tank wastes. This optimized processing strategy with an altered treatment scheme performs the major elements of the TWRS Program, but modifies the deployment of selected treatment technologies to reduce the program cost. The present program for development of waste retrieval, pretreatment, and vitrification technologies continues, but the optimized processing strategy reuses a single facility to accomplish the separations/low-activity waste (LAW) vitrification and the high-level waste (HLW) vitrification processes sequentially, thereby eliminating the need for a separate HLW vitrification facility

  19. Alternatives Generation and Analysis for Phase 1 High-Level Waste Feed Tanks Selection

    International Nuclear Information System (INIS)

    CRAWFORD, T.W.

    1999-01-01

    A recent revision of the US Department of Energy privatization contract for the immobilization of high-level waste (HLW) at Hanford necessitates the investigation of alternative waste feed sources to meet contractual feed requirements. This analysis identifies wastes to be considered as HLW feeds and develops and conducts alternative analyses to comply with established criteria. A total of 12,426 cases involving 72 waste streams are evaluated and ranked in three cost-based alternative models. Additional programmatic criteria are assessed against leading alternative options to yield an optimum blended waste feed stream

  20. Aluminum Removal And Sodium Hydroxide Regeneration From Hanford Tank Waste By Lithium Hydrotalcite Precipitation Summary Of Prior Lab-Scale Testing

    International Nuclear Information System (INIS)

    Sams, T.L.; Guillot, S.

    2011-01-01

    Scoping laboratory scale tests were performed at the Chemical Engineering Department of the Georgia Institute of Technology (Georgia Tech), and the Hanford 222-S Laboratory, involving double-shell tank (DST) and single-shell tank (SST) Hanford waste simulants. These tests established the viability of the Lithium Hydrotalcite precipitation process as a solution to remove aluminum and recycle sodium hydroxide from the Hanford tank waste, and set the basis of a validation test campaign to demonstrate a Technology Readiness Level of 3.

  1. Permitting plan for the high-level waste interim storage

    International Nuclear Information System (INIS)

    Deffenbaugh, M.L.

    1997-01-01

    This document addresses the environmental permitting requirements for the transportation and interim storage of solidified high-level waste (HLW) produced during Phase 1 of the Hanford Site privatization effort. Solidified HLW consists of canisters containing vitrified HLW (glass) and containers that hold cesium separated during low-level waste pretreatment. The glass canisters and cesium containers will be transported to the Canister Storage Building (CSB) in a U.S. Department of Energy (DOE)-provided transportation cask via diesel-powered tractor trailer. Tri-Party Agreement (TPA) Milestone M-90 establishes a new major milestone, and associated interim milestones and target dates, governing acquisition and/or modification of facilities necessary for: (1) interim storage of Tank Waste Remediation Systems (TWRS) immobilized HLW (IHLW) and other canistered high-level waste forms; and (2) interim storage and disposal of TWRS immobilized low-activity tank waste (ILAW). An environmental requirements checklist and narrative was developed to identify the permitting path forward for the HLW interim storage (HLWIS) project (See Appendix B). This permitting plan will follow the permitting logic developed in that checklist

  2. Development and evaluation of candidate high-level waste forms

    International Nuclear Information System (INIS)

    Bernadzikowski, T.A.

    1981-01-01

    Some seventeen candidate waste forms have been investigated under US Department of Energy programs as potential media for the immobilization and geologic disposal of the high-level radioactive wastes (HLW) resulting from chemical processing of nuclear reactor fuels and targets. Two of these HLW forms were selected at the end of fiscal year (FY) 1981 for intensive development if FY 1982 to 1983. Borosilicate glass was continued as the reference form. A crystalline ceramic waste form, SYNROC, was selected for further product formulation and process development as the alternative to borosilicate glass. This paper describes the bases on which this decision was made

  3. Deep repositories for waste central to uranium debate

    International Nuclear Information System (INIS)

    Kannegieter, T.

    1991-01-01

    While no deep repositories for high level wastes (HLW) have yet been constructed it is shown that technology to safely entomb the wastes for tens of thousands of years already exists. The borosilicate glass (vitrification) developed in France has been accepted by all countries who are reprocessing. Meanwhile, the Australian Synroc has not yet been put into service. Synroc developers at the Australian Nuclear Science and Technology Organization believe it will be the second generation waste form. The advantages and disadvantages of both technologies are briefly discussed as well as some of the regulatory, political, legal and technical conflicts surrounding the issue of HLW repositories. 1 tab., ills

  4. 'Practicality' as a key constraint to HLW repository design

    International Nuclear Information System (INIS)

    Kitayama, Kazumi; Sakabe, Yasushi; Ishiguro, Katsuhiko

    2007-01-01

    Designs of repositories in Japan for HLW have focused very much on demonstration of post-closure safety. Safety can be assured using very simple assessment techniques, which make many conservative simplifications. Such a situation is reasonable for the early stages of generic concept demonstration, but becomes less appropriate as NUMO moves towards siting, where a number of issues involved with construction and operation of a repository - generally grouped together as 'practicality'. The engineering logistics and conventional safety of repository construction and operation have been relatively little studied and present major challenges. Current designs emphasise a minimum of infrastructure in the emplacement tunnels and remote-handled operation. This would be difficult enough, but such operations need to be carried out to strict quality limits and need to be robust in the event of equipment failure or disruptive events. The paper will first examine how designs can be modified from the viewpoint of logistics. The implications of such modifications on operational robustness and associated safety in case of perturbation scenarios are then considered. (author)

  5. Feasibility Study for Preparation and Use of Glass Grains as an Alternative to Glass Nodules for Vitrification of Nuclear Waste

    Energy Technology Data Exchange (ETDEWEB)

    Sonavane, M S; Mishra, P.K., E-mail: maheshss@barc.gov.in [Nuclear Recycle Board, Bhabha Atomic Research Centre, Mumbai (India); Mandal, S; Barik, S; Roy Chowdhury, A; Sen, R [Central Glass and Ceramic Institute, Kolkata (India)

    2012-10-15

    High level nuclear liquid waste (HLW) is immobilized using borosilicate glass matrix. Presently joule heated ceramic melter is being employed for vitrification of HLW in India. Preformed nodules of base glass are fed to melter along with liquid waste in predetermined ratio. In order to reduce the cost incurred for production of glass nodules of base glass, an alternative option of using glass grains was evaluated for its preparation and its suitability for the melter operation. (author)

  6. Feasibility Study for Preparation and Use of Glass Grains as an Alternative to Glass Nodules for Vitrification of Nuclear Waste

    International Nuclear Information System (INIS)

    Sonavane, M.S.; Mishra, P.K.; Mandal, S.; Barik, S.; Roy Chowdhury, A.; Sen, R.

    2012-01-01

    High level nuclear liquid waste (HLW) is immobilized using borosilicate glass matrix. Presently joule heated ceramic melter is being employed for vitrification of HLW in India. Preformed nodules of base glass are fed to melter along with liquid waste in predetermined ratio. In order to reduce the cost incurred for production of glass nodules of base glass, an alternative option of using glass grains was evaluated for its preparation and its suitability for the melter operation. (author)

  7. 76 FR 17970 - Board Meeting: April 27, 2011-Amherst, New York; the U.S. Nuclear Waste Technical Review Board...

    Science.gov (United States)

    2011-03-31

    ... the 2008-9 study on Quantitative Risk Assessment of the State Licensed Radioactive Waste Disposal Area... of vitrified high-level radioactive waste (HLW); determination of waste classification of the melter... NUCLEAR WASTE TECHNICAL REVIEW BOARD Board Meeting: April 27, 2011--Amherst, New York; the U.S...

  8. Systems study of the feasibility of high-level nuclear waste fractionation for thermal stress control in a geologic repository: appendices

    International Nuclear Information System (INIS)

    McKee, R.W.; Elder, H.K.; McCallum, R.F.; Silviera, D.J.; Swanson, J.L.; Wiles, L.E.

    1983-06-01

    This study assesses the benefits and costs of fractionating the cesium and strontium (Cs/Sr) components in commercial high-level waste (HLW) to a separate waste stream for the purpose of reducing geologic-repository thermal stresses in the region of the HLW. The major conclusion is that the Cs/Sr fractionation concept offers the prospect of a substantial total system cost advantage for HLW disposal if reduced HLW package temperatures in a basalt repository are desired. However there is no cost advantage if currently designated maximum design temperatures are acceptable. Aging the HLW for 50 to 100 years can accomplish similar results at equivalent or lower costs. Volume II contains appendices for: (1) thermal analysis supplement; (2) fractionation process experimental results supplement; (3) cost analysis supplement; and (4) radiological risk analysis supplement

  9. Transportation packagings for high-level wastes and unprocessed transuranic wastes

    International Nuclear Information System (INIS)

    Wilmot, E.L.; Romesberg, L.E.

    1982-01-01

    Packagings used for nuclear waste transport are varied in size, shape, and weight because they must accommodate a wide variety of waste forms and types. However, this paper will discuss the common characteristics among the packagings in order to provide a broad understanding of packaging designs. The paper then discusses, in some detail, a design that has been under development recently at Sandia National Laboratories (SNL) for handling unprocessed, contact-handled transuranic (CHTRU) wastes as well as a cask design for defense high-level wastes (HLW). As presently conceived, the design of the transuranic package transporter (TRUPACT) calls for inner and outer boxes that are separated by a rigid polyurethane foam. The inner box has a steel frame with stainless steel surfaces; the outer box is similarly constructed except that carbon steel is used for the outside surfaces. The access to each box is through hinged doors that are sealed after loading. To meet another waste management need, a cask is being developed to transport defense HLW. The cask, which is at the preliminary design stage, is being developed by General Atomic under the direction of the TTC. The cask design relies heavily on state-of-the-art spent-fuel cask designs though it can be much simpler due to the characteristics of the HLW. A primary purpose of this paper is to show that CHTRU waste and defense HLW currently are and will be transported in packagings designed to meet the hazards of transportation that are present in general commerce

  10. Geologic environments for nuclear waste repositories

    Directory of Open Access Journals (Sweden)

    Paleologos Evan K.

    2017-01-01

    Full Text Available High-level radioactive waste (HLW results from spent reactor fuel and reprocessed nuclear material. Since 1957 the scientific consensus is that deep geologic disposal constitutes the safest means for isolating HLW for long timescales. Nuclear power is becoming significant for the Arab Gulf countries as a way to diversify energy sources and drive economic developments. Hence, it is of interest to the UAE to examine the geologic environments currently considered internationally to guide site selection. Sweden and Finland are proceeding with deep underground repositories mined in bedrock at depths of 500m, and 400m, respectively. Equally, Canada’s proposals are deep burial in the plutonic rock masses of the Canadian Shield. Denmark and Switzerland are considering disposal of their relative small quantities of HLW into crystalline basement rocks through boreholes at depths of 5,000m. In USA, the potential repository at Yucca Mountain, Nevada lies at a depth of 300m in unsaturated layers of welded volcanic tuffs. Disposal of low and intermediate-level radioactive wastes, as well as the German HLW repository favour structurally-sound layered salt stata and domes. Our article provides a comprehensive review of the current concepts regarding HLW disposal together with some preliminary analysis of potentially appropriate geologic environments in the UAE.

  11. Panel session: Disposal of HLW - ready for implementation

    International Nuclear Information System (INIS)

    Heremans, R.; Come, B.; Barbreau, A.; Girardi, F.

    1986-01-01

    The paper is a report of a panel session at the European Community conference on radioactive waste management and disposal, Luxembourg 1985, concerning the safe and long-term disposal of high-activity and long-lived waste. The subjects discussed include: geological barriers including deep sea-bed sediments, engineered barriers, technological problems (repository construction, waste emplacement, backfilling and sealing), safety analysis, performance assessment of disposal system components, and finally institutional, legal and financial aspects of geological disposal. (U.K.)

  12. Deliberated opinion of the Environment Authority concerning the prior definition of the Cigeo project, industrial centre of deep reversible storage of radioactive wastes in Meuse/Haute-Marne

    International Nuclear Information System (INIS)

    2013-01-01

    This document first describes the project and its context: history and legal framework, types of wastes dedicated to Cigeo, definition of the warehousing, storage, notions of reversibility and retrievability, project location, program for the installation, transport of wastes to Cigeo. It describes the associated administrative procedures: creation authorization request, and other procedures including an impact study. It recalls the questions asked by the ANDRA and gives the corresponding answers. These questions concern the perimeter of the impact study to be performed, dates and modalities of submission to the Environment Authority, scenarios to be presented in the impact study, definition of impact study areas, and impacts after installation closure

  13. DEFENSE HIGH LEVEL WASTE GLASS DEGRADATION

    International Nuclear Information System (INIS)

    Ebert, W.

    2001-01-01

    The purpose of this Analysis/Model Report (AMR) is to document the analyses that were done to develop models for radionuclide release from high-level waste (HLW) glass dissolution that can be integrated into performance assessment (PA) calculations conducted to support site recommendation and license application for the Yucca Mountain site. This report was developed in accordance with the ''Technical Work Plan for Waste Form Degradation Process Model Report for SR'' (CRWMS M andO 2000a). It specifically addresses the item, ''Defense High Level Waste Glass Degradation'', of the product technical work plan. The AP-3.15Q Attachment 1 screening criteria determines the importance for its intended use of the HLW glass model derived herein to be in the category ''Other Factors for the Postclosure Safety Case-Waste Form Performance'', and thus indicates that this factor does not contribute significantly to the postclosure safety strategy. Because the release of radionuclides from the glass will depend on the prior dissolution of the glass, the dissolution rate of the glass imposes an upper bound on the radionuclide release rate. The approach taken to provide a bound for the radionuclide release is to develop models that can be used to calculate the dissolution rate of waste glass when contacted by water in the disposal site. The release rate of a particular radionuclide can then be calculated by multiplying the glass dissolution rate by the mass fraction of that radionuclide in the glass and by the surface area of glass contacted by water. The scope includes consideration of the three modes by which water may contact waste glass in the disposal system: contact by humid air, dripping water, and immersion. The models for glass dissolution under these contact modes are all based on the rate expression for aqueous dissolution of borosilicate glasses. The mechanism and rate expression for aqueous dissolution are adequately understood; the analyses in this AMR were conducted to

  14. Methodology of fuel cycles long-term safety assessment of SNF/HLW geological disposal

    International Nuclear Information System (INIS)

    Pritrsky, J.

    2008-02-01

    Methodology for the long-term safety assessment of nuclear fuel cycles is given in the presented doctoral thesis. The aim of work was to develop a geological repository model for disposal of spent nuclear fuel (SNF) and high level waste (HLW) using an appropriate software code able to calculate the influence of partitioning and transmutation in advanced fuel cycles. The first step in this process was specifying of indicators which can be used to quantify the radiological impact of each fuel cycle. Indicators such as annual effective dose and radiotoxicity of inventory have been quantitatively analysed to determine the potential risk and radiological consequences associated with production of SNF/HLW. Advanced fuel types bring a number of advantages in comparison to uranium oxide fuel UO 2 used worldwide nowadays in terms of safety improvement due to minor actinides transmutation and non-proliferation aspects as well. Within the scope of work, three different fuel cycles are compared from the point of view of long-term safety of deep geological repository. The first considered fuel cycle is the currently used open fuel cycle (UOX) which uses only U-FA (Uranium Fuel Assembly). The second assessed cycle is a closed fuel cycle (MOX) with MOX-FA (Mixed OXides Fuel Assembly) and the third considered one is a partially closed fuel cycle (IMF) with IMC-FA (Inert Matrix Combined Fuel Assembly). Description and input data of advanced fuel cycles have been gained by participation in the EC project RED-IMPACT. Results were calculated using code AMBER, which is a flexible software tool that allows building dynamic compartmental models to represent the migration and fate of contaminants in a system, for example in the surface and sub-surface environment. Contaminants in solid, liquid and gaseous phases can be considered. AMBER gives the user the flexibility to define any number of compartments; any number of contaminants and associated decays; deterministic, probabilistic and

  15. Methodology of fuel cycles long-term safety assessment of SNF/HLW geological disposal

    International Nuclear Information System (INIS)

    Pritrsky, J.

    2008-01-01

    Methodology for the long-term safety assessment of nuclear fuel cycles is given in the presented doctoral thesis. The aim of work was to develop a geological repository model for disposal of spent nuclear fuel (SNF) and high level waste (HLW) using an appropriate software code able to calculate the influence of partitioning and transmutation in advanced fuel cycles. The first step in this process was specifying of indicators which can be used to quantify the radiological impact of each fuel cycle. Indicators such as annual effective dose and radiotoxicity of inventory have been quantitatively analysed to determine the potential risk and radiological consequences associated with production of SNF/HLW. Advanced fuel types bring a number of advantages in comparison to uranium oxide fuel UO 2 used worldwide nowadays in terms of safety improvement due to minor actinides transmutation and non-proliferation aspects as well. Within the scope of work, three different fuel cycles are compared from the point of view of long-term safety of deep geological repository. The first considered fuel cycle is the currently used open fuel cycle (UOX) which uses only U-FA (Uranium Fuel Assembly). The second assessed cycle is a closed fuel cycle (MOX) with MOX-FA (Mixed OXides Fuel Assembly) and the third considered one is a partially closed fuel cycle (IMF) with IMC-FA (Inert Matrix Combined Fuel Assembly). Description and input data of advanced fuel cycles have been gained by participation in the EC project RED-IMPACT. Results were calculated using code AMBER, which is a flexible software tool that allows building dynamic compartmental models to represent the migration and fate of contaminants in a system, for example in the surface and sub-surface environment. Contaminants in solid, liquid and gaseous phases can be considered. AMBER gives the user the flexibility to define any number of compartments; any number of contaminants and associated decays; deterministic, probabilistic and

  16. Hydro-mechanical behaviour of crushed COx argillite used as backfilling material in HLW repository

    International Nuclear Information System (INIS)

    Tang Chaosheng; Shi Bin; Cui Yujun; Anh-Minh Tang

    2010-01-01

    At present, the crushed Callovo-Oxfordian (COx) argillite powder is proposed as an alternative backfilling material in France, which will be constructed in the engineering barrier of high-level radioactive waste (HLW) repository. In this investigation, the compression behavior of two crushed COx argillite powders (coarser one and finer one) was studied by running l-D compression tests with several loading-unloading cycles. After the final dry density 2.0 g/cm 3 was reached, the specimen was flooding with distilled water and the evolution of axial stress was studied during saturation process. The effects of initial axial stress level and grain size distribution (GSD) on hydro-mechanical behaviour of compacted specimen were analyzed. The results show that the compression curves are significantly influenced by the GSD of the soils. To obtain the same degree of compaction, the axial stress applied to finer soil is much higher than that of coarser soil. In addition, the compression index of the finer soil is bigger than that of coarser soil. The swelling index at initial water content increases with the dry density and seems to be independent of the GSD. During saturation, the initial lower axial stress causes obvious swelling behavior for both the coarser and finer powder samples and the corresponding axial stress increase gradually. At initial higher axial stress condition, monotone collapse behavior is observed for the coarser powder samples. Whereas the axial stress decrease firstly, then increase and finally decrease again for the finer powder samples. After saturation, the equilibrium axial stresses of finer powder samples are higher than that of coarser powder samples. (authors)

  17. Dissolution of ORNL HLW sludge and partitioning of the actinides using the TRUEX process

    International Nuclear Information System (INIS)

    Spencer, B.B.; Egan, B.Z.; Beahm, E.C.; Chase, C.W.; Dillow, T.A.

    1997-01-01

    Experiments were conducted to evaluate the transuranium extraction (TRUEX) process for partitioning actinides from actual dissolved high-level radioactive waste (HLW) sludge. Samples of sludge from melton Valley Storage Tank W-25 were rinsed with mild caustic (0.2 M NaOH) to reduce the concentrations of nitrates and fission products associated with the interstitial liquid. In one campaign the rinsed sludge was leached in nitric acid, and about 50% of the dry mass of the sludge was dissolved. The resulting solution contained total metal concentrations of ∼ 1.8 M with a nitric acid concentration of 2.9 M. In the other campaign the sludge was neutralized with nitric acid to destroy the carbonates, then leached with 2.6 M NaOH for ∼ 6 h before rinsing with the mild caustic. The sludge was then leached in nitric acid, and about 80% of the sludge dissolved. The resulting solution contained total metal concentrations of ∼ 0.6 M with a nitric acid concentration of 1.7 M. Chemical analyses of both phases were used to evaluate the process. Evaluation was based on two metrics: the fraction of TRU elements removed from the dissolved sludge and comparison of the results with predictions made with the Generic TRUEX Model (GTM). The fractions of Eu, Pu, Cm, Th and U species removed from aqueous solution in only one extraction stage were > 95% and were close to the values predicted by the GTM. Mercury was also found to be strongly extracted, with a one-stage removal of > 92%. In one test, vanadium appeared to be moderately extracted

  18. DESIGN OF A CONCRETE SLAB FOR STORAGE OF SNF AND HLW CASKS

    International Nuclear Information System (INIS)

    J. Bisset

    2005-01-01

    This calculation documents the design of the Spent Nuclear Fuel (SNF) and High-Level Waste (HLW) Cask storage slab for the Aging Area. The design is based on the weights of casks that may be stored on the slab, the weights of vehicles that may be used to move the casks, and the layout shown on the sketch for a 1000 Metric Ton of Heavy Metal (MTHM) storage pad on Attachment 2, Sht.1 of the calculation 170-C0C-C000-00100-000-00A (BSC 2004a). The analytical model used herein is based on the storage area for 8 vertical casks. To simplify the model, the storage area of the horizontal concrete modules and their related shield walls is not included. The heavy weights of the vertical storage casks and the tensile forces due to pullout at the anchorages will produce design moments and shear forces that will envelope those that would occur in the storage area of the horizontal modules. The design loadings will also include snow and live loads. In addition, the design will also reflect pertinent geotechnical data. This calculation will document the preliminary thickness and general reinforcing steel requirements for the slab. This calculation also documents the initial design of the cask anchorage. Other slab details are not developed in this calculation. They will be developed during the final design process. The calculation also does not include the evaluation of the effects of cask drop loads. These will be evaluated in this or another calculation when the exact cask geometry is known

  19. Evaluation and selection of candidate high-level waste forms

    International Nuclear Information System (INIS)

    1982-03-01

    Seven candidate waste forms being developed under the direction of the Department of Energy's National High-Level Waste (HLW) Technology Program, were evaluated as potential media for the immobilization and geologic disposal of high-level nuclear wastes. The evaluation combined preliminary waste form evaluations conducted at DOE defense waste-sites and independent laboratories, peer review assessments, a product performance evaluation, and a processability analysis. Based on the combined results of these four inputs, two of the seven forms, borosilicate glass and a titanate based ceramic, SYNROC, were selected as the reference and alternative forms for continued development and evaluation in the National HLW Program. Both the glass and ceramic forms are viable candidates for use at each of the DOE defense waste-sites; they are also potential candidates for immobilization of commercial reprocessing wastes. This report describes the waste form screening process, and discusses each of the four major inputs considered in the selection of the two forms

  20. Processing of nuclear waste

    International Nuclear Information System (INIS)

    Hennelly, E.J.

    1981-01-01

    The processing of nuclear waste to transform the liquid waste from fuel reprocessing activities is well defined. Most solid waste forms, if they are cooled and contain diluted waste, are compatible with many permanent storage environments. The public acceptance of methods for disposal is being delayed in the US because of the alternatives studies of waste forms and repositories now under way that give the impression of indecision and difficulty for the disposal of HLW. Conservative programs that dilute and cool solid waste are under way in France and Sweden and demonstrate that a solution to the problem is available now. Research and development should be directed toward improving selected methods rather than seeking a best method, which at best, may always be illusory

  1. Processes for production of alternative waste forms

    International Nuclear Information System (INIS)

    Ross, W.A.; Rusin, J.M.; McElroy, J.L.

    1979-01-01

    During the past 20 years, numerous waste forms and processes have been proposed for solidification of high-level radioactive wastes (HLW). The number has increased significantly during the past 3 to 4 years. At least five factors must be considered in selecting the waste form and process method: 1) processing flexibility, 2) waste loading, 3) canister size and stability, 4) waste form inertness and stability, and 5) processing complexity. This paper describes various waste form processes and operations, and a simple system is proposed for making comparisons. This system suggests that one goal for processes would be to reduce the number of process steps, thereby providing less complex processing systems

  2. Alternative solidified forms for nuclear wastes

    International Nuclear Information System (INIS)

    McElroy, J.L.; Ross, W.A.

    1976-01-01

    Radioactive wastes will occur in various parts of the nuclear fuel cycle. These wastes have been classified in this paper as high-level waste, intermediate and low-level waste, cladding hulls, and residues. Solidification methods for each type of waste are discussed in a multiple barrier context of primary waste form, applicable coatings or films, matrix encapsulation, canister, engineered structures, and geological storage. The four major primary forms which have been most highly developed are glass for HLW, cement for ILW, organics for LLW, and metals for hulls

  3. Numerical analysis of thermal process in the near field around vertical disposal of high-level radioactive waste

    Directory of Open Access Journals (Sweden)

    H.G. Zhao

    2014-02-01

    Full Text Available For deep geological disposal of high-level radioactive waste (HLW in granite, the temperature on the HLW canisters is commonly designed to be lower than 100 °C. This criterion dictates the dimension of the repository. Based on the concept of HLW disposal in vertical boreholes, thermal process in the near field (host rock and buffer surrounding HLW canisters has been simulated by using different methods. The results are drawn as follows: (a the initial heat power of HLW canisters is the most important and sensitive parameter for evolution of temperature field; (b the thermal properties and variations of the host rock, the engineered buffer, and possible gaps between canister and buffer and host rock are the additional key factors governing the heat transformation; (c the gaps width and the filling by water or air determine the temperature offsets between them.

  4. High-Level Waste Glass Formulation Model Sensitivity Study 2009 Glass Formulation Model Versus 1996 Glass Formulation Model

    International Nuclear Information System (INIS)

    Belsher, J.D.; Meinert, F.L.

    2009-01-01

    This document presents the differences between two HLW glass formulation models (GFM): The 1996 GFM and 2009 GFM. A glass formulation model is a collection of glass property correlations and associated limits, as well as model validity and solubility constraints; it uses the pretreated HLW feed composition to predict the amount and composition of glass forming additives necessary to produce acceptable HLW glass. The 2009 GFM presented in this report was constructed as a nonlinear optimization calculation based on updated glass property data and solubility limits described in PNNL-18501 (2009). Key mission drivers such as the total mass of HLW glass and waste oxide loading are compared between the two glass formulation models. In addition, a sensitivity study was performed within the 2009 GFM to determine the effect of relaxing various constraints on the predicted mass of the HLW glass.

  5. 10 CFR 60.135 - Criteria for the waste package and its components.

    Science.gov (United States)

    2010-01-01

    ... Section 60.135 Energy NUCLEAR REGULATORY COMMISSION (CONTINUED) DISPOSAL OF HIGH-LEVEL RADIOACTIVE WASTES... for HLW shall be designed so that the in situ chemical, physical, and nuclear properties of the waste package and its interactions with the emplacement environment do not compromise the function of the waste...

  6. Summary of research and development activities in support of waste acceptance criteria for WIPP

    International Nuclear Information System (INIS)

    Hunter, T.O.

    1979-11-01

    The development of waste acceptance criteria for the Waste Isolation Pilot Plant (WIPP) is summarized. Specifications for acceptable waste forms are included. Nine program areas are discussed. They are: TRU characterization, HLW interactions, thermal/structural interactions, nuclide migration, permeability, brine migration, borehole plugging, operation/design support, and instrumentation development. Recommendations are included

  7. High-level waste tank modifications, installation of mobilization equipment/check out

    International Nuclear Information System (INIS)

    Schiffhauer, M.A.; Thompson, S.C.

    1992-01-01

    PUREX high-level waste (HLW) is contained at the West Valley Demonstration Project (WVDP) in an underground carbon-steel storage tank. The HLW consists of a precipitated sludge and an alkaline supernate. This report describes the system that the WVDP has developed and implemented to resuspend and wash the HLW sludge from the tank. The report discusses Sludge Mobilization and Wash System (SMWS) equipment design, installation, and testing. The storage tank required modifications to accommodate the SMWS. These modifications are discussed as well

  8. The general situation of clay site for high-level waste geological disposal repository

    International Nuclear Information System (INIS)

    Wang Changxuan; Liu Xiaodong; Liu Pinghui

    2008-01-01

    Host medium is vitally important for safety of high-level radiaoactive waste (HLW) geological disposal. Clay, as host media of geological repository of HLW, has received greater attention for its inherent advantages. This paper summarizes IAEA and OECD/NEA's some safety guides on site selection and briefly introduces the process of the site selection, their studies and the characteristics of the clay formations in Switz-erland, France and Belgian. Based on these analyses, some suggestions are made to China's HLW repository clay site selection. (authors)

  9. Isothermal crystallization kinetics in simulated high-level nuclear waste glass

    International Nuclear Information System (INIS)

    Vienna, J.D.; Hrma, P.; Smith, D.E.

    1997-01-01

    Crystallization kinetics of a simulated high-level waste (HLW) glass were measured and modelled. Kinetics of acmite growth in the standard HW39-4 glass were measured using the isothermal method. A time-temperature-transformation (TTT) diagram was generated from these data. Classical glass-crystal transformation kinetic models were empirically applied to the crystallization data. These models adequately describe the kinetics of crystallization in complex HLW glasses (i.e., RSquared = 0.908). An approach to measurement, fitting, and use of TTT diagrams for prediction of crystallinity in a HLW glass canister is proposed

  10. A comparison of high-level waste form characteristics

    International Nuclear Information System (INIS)

    Salmon, R.; Notz, K.J.

    1991-01-01

    The US DOE is responsible for the eventual disposal in a repository of spent fuels, high-level waste (HLW) and other radioactive wastes that may require long-term isolation. This includes light-water reactor (LWR) spent fuel and immobilized HLW as the two major sources, plus other forms including non-LWR spent fuels and miscellaneous sources (such as activated metals in the Greater-Than-Class-C category). The Characteristics Data Base, sponsored by DOE's Office of Civilian Radioactive Waste Management (OCRWM), was created to systematically tabulate the technical characteristics of these materials. Data are presented here on the immobilized HLW forms that are expected to be produced between now and 2020

  11. Crystallization in high-level waste glass: A review of glass theory and noteworthy literature

    Energy Technology Data Exchange (ETDEWEB)

    Christian, J. H. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2015-08-18

    There is a fundamental need to continue research aimed at understanding nepheline and spinel crystal formation in high-level waste (HLW) glass. Specifically, the formation of nepheline solids (K/NaAlSiO4) during slow cooling of HLW glass can reduce the chemical durability of the glass, which can cause a decrease in the overall durability of the glass waste form. The accumulation of spinel solids ((Fe, Ni, Mn, Zn)(Fe, Cr)2O4), while not detrimental to glass durability, can cause an array of processing problems inside HLW glass melters. In this review, the fundamental differences between glass and solid-crystals are explained using kinetic, thermodynamic, and viscosity arguments, and several highlights of glass-crystallization research, as it pertains to high-level waste vitrification, are described. In terms of mitigating spinel in the melter and both spinel and nepheline formation in the canister, the complexity of HLW glass and the intricate interplay between thermal, chemical, and kinetic factors further complicates this understanding. However, new experiments seeking to elucidate the contributing factors of crystal nucleation and growth in waste glass, and the compilation of data from older experiments, may go a long way towards helping to achieve higher waste loadings while developing more efficient processing strategies. Higher waste loadings and more efficient processing strategies will reduce the overall HLW Hanford Tank Waste Treatment and Immobilization Plant (WTP) vitrification facilities mission life.

  12. A QUARTER CENTURY OF NUCLEAR WASTE MANAGEMENT IN JAPAN

    International Nuclear Information System (INIS)

    Masuda, S.

    2002-01-01

    This paper is entitled ''A QUARTER CENTURY OF NUCLEAR WASTE MANAGEMENT IN JAPAN''. Since the first statement on the strategy for radioactive waste management in Japan was made by the Atomic Energy Commission (AEC) in 1976, a quarter century has passed, in which much experience has been accumulated both in technical and social domains. This paper looks back in this 25-year history of radioactive waste management in Japan by highlighting activities related to high-level radioactive waste (HLW) disposal

  13. A regulatory perspective on design and performance requirements for engineered systems in high-level waste

    International Nuclear Information System (INIS)

    Bernero, R.M.

    1992-01-01

    For engineered systems, this paper gives an overview of some of the current activities at the U.S. Nuclear Regulatory Commission (NRC), with the intent of elucidating how the regulatory process works in the management of high-level waste (HLW). Throughout the waste management cycle, starting with packaging and transportation, and continuing to final closure of a repository, these activities are directed at taking advantage of the prelicensing consultation period, a period in which the NRC, DOE and others can interact in ways that will reduce regulatory, technical and institutional uncertainties, and open the path to development and construction of a deep geologic repository for permanent disposal of HLW. Needed interactions in the HLW program are highlighted. Examples of HLW regulatory activities are given in discussions of a multipurpose-cask concept and of current NRC work on the meaning of the term substantially complete containment

  14. DOE requests waiver on double containment for HLW canisters

    International Nuclear Information System (INIS)

    Lobsenz, G.

    1994-01-01

    The Energy Department has asked the Nuclear Regulatory Commission to waive double containment requirements for vitrified high-level radioactive waste canisters, saying the additional protection is not necessary and too costly. NRC said it had received a petition from DOE contending that the vitrified waste canisters were durable enough without double containment to prevent any potential plutonium release during handling and shipping. DOE said testing had shown that the vitrified waste canisters were similar - even superior - in durability to spent reactor fuel shipments, which NRC specifically exempted from the double containment requirement

  15. Spacing Sensitivity Analysis of HLW Intermediate Storage Facility

    International Nuclear Information System (INIS)

    Youn, Bum Soo; Lee, Kwang Ho

    2010-01-01

    Currently, South Korea's spent fuels are stored in its temporary storage within the plant. But the temporary storage is expected to be reaching saturation soon. For the effective management of spent fuel wastes, the need for intermediate storage facility is a desperate position. However, the research for the intermediate storage facility for waste has not made active so far. In addition, in case of foreign countries it is mostly treated confidentially and the information isn't easy to collect. Therefore, the purpose of this study is creating the basic thermal analysis data for the waste storage facility that will be valuable in the future

  16. Combined Waste Form Cost Trade Study

    International Nuclear Information System (INIS)

    Gombert, Dirk; Piet, Steve; Trickel, Timothy; Carter, Joe; Vienna, John; Ebert, Bill; Matthern, Gretchen

    2008-01-01

    A new generation of aqueous nuclear fuel reprocessing, now in development under the auspices of the DOE Office of Nuclear Energy (NE), separates fuel into several fractions, thereby partitioning the wastes into groups of common chemistry. This technology advance enables development of waste management strategies that were not conceivable with simple PUREX reprocessing. Conventional wisdom suggests minimizing high level waste (HLW) volume is desirable, but logical extrapolation of this concept suggests that at some point the cost of reducing volume further will reach a point of diminishing return and may cease to be cost-effective. This report summarizes an evaluation considering three groupings of wastes in terms of cost-benefit for the reprocessing system. Internationally, the typical waste form for HLW from the PUREX process is borosilicate glass containing waste elements as oxides. Unfortunately several fission products (primarily Mo and the noble metals Ru, Rh, Pd) have limited solubility in glass, yielding relatively low waste loading, producing more glass, and greater disposal costs. Advanced separations allow matching the waste form to waste stream chemistry, allowing the disposal system to achieve more optimum waste loading with improved performance. Metals can be segregated from oxides and each can be stabilized in forms to minimize the HLW volume for repository disposal. Thus, a more efficient waste management system making the most effective use of advanced waste forms and disposal design for each waste is enabled by advanced separations and how the waste streams are combined. This trade-study was designed to juxtapose a combined waste form baseline waste treatment scheme with two options and to evaluate the cost-benefit using available data from the conceptual design studies supported by DOE-NE

  17. Distributions of 14 elements on 60 selected absorbers from two simulant solutions (acid-dissolved sludge and alkaline supernate) for Hanford HLW Tank 102-SY

    International Nuclear Information System (INIS)

    Marsh, S.F.; Svitra, Z.V.; Bowen, S.M.

    1993-10-01

    Sixty commercially available or experimental absorber materials were evaluated for partitioning high-level radioactive waste. These absorbers included cation and anion exchange resins, inorganic exchangers, composite absorbers, and a series of liquid extractants sorbed on porous support-beads. The distributions of 14 elements onto each absorber were measured from simulated solutions that represent acid-dissolved sludge and alkaline supernate solutions from Hanford high-level waste (HLW) Tank 102-SY. The selected elements, which represent fission products (Ce, Cs, Sr, Tc, and Y); actinides (U, Pu, and Am); and matrix elements (Cr, Co, Fe, Mn, Zn, and Zr), were traced by radionuclides and assayed by gamma spectrometry. Distribution coefficients for each of the 1680 element/absorber/solution combinations were measured for dynamic contact periods of 30 min, 2 h, and 6 h to provide sorption kinetics information for the specified elements from these complex media. More than 5000 measured distribution coefficients are tabulated

  18. Wastes

    International Nuclear Information System (INIS)

    Bovard, Pierre

    The origin of the wastes (power stations, reprocessing, fission products) is determined and the control ensuring the innocuity with respect to man, public acceptance, availability, economics and cost are examined [fr

  19. Managing nuclear waste: Social and economic impacts

    International Nuclear Information System (INIS)

    Hemphill, R.C.; Bassett, G.W. Jr.

    1993-01-01

    Recent research has focused on perceptions of risk as a dominant source of economic impacts due to siting a high level radioactive waste facility. This article addresses the social and economic considerations involved with the issue of risk perception and other types of negative imagery. Emphasis is placed on ways of measuring the potential for economic effects resulting from perceptions prior to construction and operation of HLW facility. We describe the problems in arriving at defensible estimates of economic impacts. Our review has found that although legal and regulatory bases may soon allow inclusion of these impacts in EIS and for compensation purposes, credible scientific methods do not currently exist for predicting the existence or magnitude of changes in economic decision-making. Policy-makers should recognize the potential for perception-based economic impacts in determining the location and means of managing radioactive waste; but, they also need be cognizant of the current limitations of quantitative estimates of impacts in this area

  20. Regulatory status on the safety assessment of a HLW repository in other countries

    International Nuclear Information System (INIS)

    Lee, Sung Ho; Hwang, Yong Soo

    2008-12-01

    To construct a HLW repository, it is essential to meet the requirements on the regulation for a deep geological disposal. Even if the construction of a HLW repository is determined positively, technical standards which assert the performance of a repository will be needed. Among various technical standards, safety assessment based on the repository evolution in the future will play an important role in the licensing process. The foreign countries' technical standards on the safety assessment of a HLW repository may be an indicator to carry out the R and D activities on geological disposal effectively. In this report, assessment period, limit of radiation dose and uncertainty related to the safety assessment are investigated and analyzed in detail. Especially, the technical reviews of USA regulation bodies seems to be reasonable in the point of the intrinsic attribute of safety assessment

  1. Study on evaluation method for potential effect of natural phenomena on a HLW disposal system

    International Nuclear Information System (INIS)

    Kawamura, Makoto; Makino, Hitoshi; Umeda, Koji; Osawa, Hideaki; Seo, Toshihiro; Ishimaru, Tsuneaki

    2005-01-01

    Evaluation for the potential effect of natural phenomena on a HLW disposal system is an important issue in safety assessment. A scenario construction method for the effects on a HLW disposal system condition and performance has been developed for two purposes: the first being effective elicitation and organization of information from investigators of natural phenomena and performance assessor and the second being, maintenance of traceability of scenario construction processes with suitable records. In this method, a series of works to construct scenarios is divided into pieces to facilitate and to elicit the features of potential effect of natural phenomena on a HLW disposal system and is organized to create reasonable scenarios with consistency, traceability and adequate conservativeness within realistic view. (author)

  2. Current R and D Status on High-Level Radioactive Waste Disposal in Selected Countries

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Youn Myoung; Hwang, Yong Soo

    2008-11-15

    Current R and D status of such countries moving forward as the United States, Sweden, France, Japan and a few other countries for high-level radioactive waste (HLW) disposal in deep geological formation has been reviewed. Even though no HLW repositories have not practically constructed nor operated yet, lots of related R and D are being proceeded in many countries as well as in Korea. Through this brief review further progress is anticipated in this related R and D area in Korea.

  3. Decontamination of stainless steel canisters that contain high-level waste

    International Nuclear Information System (INIS)

    Bray, L.A.

    1987-01-01

    At the West Valley Nuclear Services Company (WVNSC) in West Valley, New York, high-level radioactive waste (HLW) will be vitrified into a borosilicate glass form and poured into large, stainless steel canisters. During the filling process, volatile fission products, principally 137 Cs, condense on the exterior of the canisters. The smearable contamination that remains on the canisters after they are filled and partially cooled must be removed from the canisters' exterior surfaces prior to their storage and ultimate shipment to a US Department of Energy (DOE) repository for disposal. A simple and effective method was developed for decontamination of HLW canisters. This method of chemical decontamination is applicable to a wide variety of contaminated equipment found in the nuclear industry. The process employs a reduction-oxidation system [Ce(III)/Ce(IV)] in nitric acid solution to chemically mill the surface of stainless steel, similar to the electropolishing process, but without the need for an applied electrical current. Contaminated canisters are simply immersed in the solution at controlled temperature and Ce(IV) concentration levels

  4. Processes for consensus building and role sharing. Lessons learned from HLW policies in European countries

    International Nuclear Information System (INIS)

    Nagano, Koji

    2003-01-01

    This report attempts to obtain lessons in implementation of HLW management policies for Japan by reviewing past experiences and present status of policy formulation and implementation as well as reflection of public opinions and consensus building of selected European countries, such as Finland, Sweden and others. After examining the situations of those countries, the author derives four key aspects that need to be addressed; separation of nuclear energy policies and HLW policies, fundamental support shared among national public, sense of controllability, and proper scheme of responsibility sharing. (author)

  5. LIQUIDUS TEMPERATURE AND ONE PERCENT CRYSTAL CONTENT MODELS FOR INITIAL HANFORD HLW GLASSES

    International Nuclear Information System (INIS)

    Vienna, John D.; Edwards, Tommy B.; Crum, Jarrod V.; Kim, Dong-Sang; Peeler, David K.

    2005-01-01

    Preliminary models for liquidus temperature (TL) and temperature at 1 vol% crystal (T01) applicable to WTP HLW glasses in the spinel primary phase field were developed. A series of literature model forms were evaluated using consistent sets of data form model fitting and validation. For TL, the ion potential and linear mixture models performed best, while for T01 the linear mixture model out performed all other model forms. TL models were able to predict with smaller uncertainty. However, the lower T01 values (even with higher prediction uncertainties) were found to allow for a much broader processing envelope for WTP HLW glasses

  6. Waste Handling and Emplacement Options for Disposal of Radioactive Waste in Deep Boreholes.

    Energy Technology Data Exchange (ETDEWEB)

    Cochran, John R.; Hardin, Ernest

    2015-11-01

    Traditional methods cannot be used to handle and emplace radioactive wastes in boreholes up to 16,400 feet (5 km) deep for disposal. This paper describes three systems that can be used for handling and emplacing waste packages in deep borehole: (1) a 2011 reference design that is based on a previous study by Woodward–Clyde in 1983 in which waste packages are assembled into “strings” and lowered using drill pipe; (2) an updated version of the 2011 reference design; and (3) a new concept in which individual waste packages would be lowered to depth using a wireline. Emplacement on coiled tubing was also considered, but not developed in detail. The systems described here are currently designed for U.S. Department of Energy-owned high-level waste (HLW) including the Cesium- 137/Strontium-90 capsules from the Hanford Facility and bulk granular HLW from fuel processing in Idaho.

  7. Waste Handling and Emplacement Options for Disposal of Radioactive Waste in Deep Boreholes

    International Nuclear Information System (INIS)

    Cochran, John R.; Hardin, Ernest

    2015-01-01

    Traditional methods cannot be used to handle and emplace radioactive wastes in boreholes up to 16,400 feet (5 km) deep for disposal. This paper describes three systems that can be used for handling and emplacing waste packages in deep borehole: (1) a 2011 reference design that is based on a previous study by Woodward-Clyde in 1983 in which waste packages are assembled into ''strings'' and lowered using drill pipe; (2) an updated version of the 2011 reference design; and (3) a new concept in which individual waste packages would be lowered to depth using a wireline. Emplacement on coiled tubing was also considered, but not developed in detail. The systems described here are currently designed for U.S. Department of Energy-owned high-level waste (HLW) including the Cesium- 137/Strontium-90 capsules from the Hanford Facility and bulk granular HLW from fuel processing in Idaho.

  8. Engineering materials for high level radioactive waste repository

    International Nuclear Information System (INIS)

    Wen Zhijian

    2009-01-01

    Radioactive wastes can arise from a wide range of human activities and have different physical and chemical forms with various radioactivity. The high level radioactive wastes (HLW)are characterized by nuclides of very high initial radioactivity, large thermal emissivity and the long life-term. The HLW disposal is highly concerned by the scientists and the public in the world. At present, the deep geological disposal is regarded as the most reasonable and effective way to safely dispose high-level radioactive wastes in the world. The conceptual model of HLW geological disposal in China is based on a multi-barrier system that combines an isolating geological environment with an engineering barrier system(EBS). The engineering materials in EBS include the vitrified HLW, canister, overpack, buffer materials and backfill materials. Referring to progress in the world, this paper presents the function, the requirement for material selection and design, and main scientific projects of R and D of engineering materials in HLW repository. (authors)

  9. Decontamination of high-level waste canisters

    International Nuclear Information System (INIS)

    Nesbitt, J.F.; Slate, S.C.; Fetrow, L.K.

    1980-12-01

    This report presents evaluations of several methods for the in-process decontamination of metallic canisters containing any one of a number of solidified high-level waste (HLW) forms. The use of steam-water, steam, abrasive blasting, electropolishing, liquid honing, vibratory finishing and soaking have been tested or evaluated as potential techniques to decontaminate the outer surfaces of HLW canisters. Either these techniques have been tested or available literature has been examined to assess their applicability to the decontamination of HLW canisters. Electropolishing has been found to be the most thorough method to remove radionuclides and other foreign material that may be deposited on or in the outer surface of a canister during any of the HLW processes. Steam or steam-water spraying techniques may be adequate for some applications but fail to remove all contaminated forms that could be present in some of the HLW processes. Liquid honing and abrasive blasting remove contamination and foreign material very quickly and effectively from small areas and components although these blasting techniques tend to disperse the material removed from the cleaned surfaces. Vibratory finishing is very capable of removing the bulk of contamination and foreign matter from a variety of materials. However, special vibratory finishing equipment would have to be designed and adapted for a remote process. Soaking techniques take long periods of time and may not remove all of the smearable contamination. If soaking involves pickling baths that use corrosive agents, these agents may cause erosion of grain boundaries that results in rough surfaces

  10. Preliminary Waste Form Compliance Plan for the Idaho National Engineering and Environmental Laboratory High-Level Waste

    International Nuclear Information System (INIS)

    Staples, B. A.; O'Holleran, T. P.

    1999-01-01

    The Department of Energy (DOE) has specific technical and documentation requirements for high-level waste (HLW) that is to be placed in a federal repository. This document describes in general terms the strategy to be used at the Idaho National Engineering and Environmental Laboratory (INEEL) to demonstrate that vitrified HLW, if produced at the INEEL, meets these requirements. Waste form, canister, quality assurance, and documentation specifications are discussed. Compliance strategy is given, followed by an overview of how this strategy would be implemented for each specification

  11. Preliminary Waste Form Compliance Plan for the Idaho National Engineering and Environmental Laboratory High-Level Waste

    Energy Technology Data Exchange (ETDEWEB)

    B. A. Staples; T. P. O' Holleran

    1999-05-01

    The Department of Energy (DOE) has specific technical and documentation requirements for high-level waste (HLW) that is to be placed in a federal repository. This document describes in general terms the strategy to be used at the Idaho National Engineering and Environmental Laboratory (INEEL) to demonstrate that vitrified HLW, if produced at the INEEL, meets these requirements. Waste form, canister, quality assurance, and documentation specifications are discussed. Compliance strategy is given, followed by an overview of how this strategy would be implemented for each specification.

  12. Public and political issues in HLW management: The Spanish approach

    International Nuclear Information System (INIS)

    Gonzalez, V.; Molina, M.

    1993-01-01

    ENRESA (Empresa Nacional de Residuos Radiactivos, S.A.), is a State-owned company, founded in 1985 and is responsible for radioactive waste management in Spain. ENRESA's activities are carried out in accordance with a General Radioactive Waste Plant approved by the Spanish Government. In Spain, as in most countries, the public is concerned about many of the activities involving radioactive or rad-waste management; this concern arises for different reasons, but mainly due to lack of information on the matter. This situation leads to the information available being misused by certain politicians, green groups and media, which serves to increase the distrust with which the public sometimes views responsible companies and institutions. At the root of both these problems is a lack of political consensus regarding development of the activity. To gain public acceptance, it would be necessary to develop a long-term information policy, since in the field of communications results are only ever achieved in the long term. ENRESA is carrying out an on-going Communication Plan (CP), implemented successfully in the areas surrounding a low- and intermediate-level waste disposal site and a disused uranium mill in which remedial actions are currently being performed. Implementation of this plan at national level is being accomplished stepwise. This document deals with the most relevant issues relating to the radioactive waste situation in Spain and with the efforts made in communications

  13. Development of a Rotary Microfilter for SRS HLW Applications

    International Nuclear Information System (INIS)

    MICHAEL, POIRIER

    2004-01-01

    The processing rate of Savannah River Site high level waste decontamination processes are limited by the flow rate of the solid-liquid separation. The baseline process, using a 0.1 micron cross flow filter, produces 0.02 gpm/ft2 of filtrate under expected operating conditions. Savannah River National Laboratory personnel identified the rotary microfilter as a technology that could significantly increase filter flux, with throughput improvements of as much as 10X for that specific operation. With funding from the Department of Energy Office of Cleanup Technologies, SRNL personnel are evaluating and developing the rotary microfilter for radioactive service at SRS. This work includes pilot-scale and actual waste testing to evaluate system reliability, the impact of radiation on system components, the filter flux for a variety of waste streams, and relative performance for alternative filter media

  14. SIERRA Mechanics, an emerging massively parallel HPC capability, for use in coupled THMC analyses of HLW repositories in clay/shale

    International Nuclear Information System (INIS)

    Bean, J.E.; Sanchez, M.; Arguello, J.G.

    2012-01-01

    Document available in extended abstract form only. Because, until recently, U.S. efforts had been focused on the volcanic tuff site at Yucca Mountain, radioactive waste disposal in U.S. clay/shale formations has not been considered for many years. However, advances in multi-physics computational modeling and research into clay mineralogy continue to improve the scientific basis for assessing nuclear waste repository performance in such formations. Disposal of high-level radioactive waste (HLW) in suitable clay/shale formations is attractive because the material is essentially impermeable and self-sealing, conditions are chemically reducing, and sorption tends to prevent radionuclide transport. Vertically and laterally extensive shale and clay formations exist in multiple locations in the contiguous 48 states. This paper describes an emerging massively parallel (MP) high performance computing (HPC) capability - SIERRA Mechanics - that is applicable to the simulation of coupled-physics processes occurring within a potential clay/shale repository for disposal of HLW within the U.S. The SIERRA Mechanics code development project has been underway at Sandia National Laboratories for approximately the past decade under the auspices of the U.S. Department of Energy's Advanced Scientific Computing (ASC) program. SIERRA Mechanics was designed and developed from its inception to run on the latest and most sophisticated massively parallel computing hardware, with the capability to span the hardware range from single workstations to systems with thousands of processors. The foundation of SIERRA Mechanics is the SIERRA tool-kit, which provides finite element application-code services such as: (1) mesh and field data management, both parallel and distributed; (2) transfer operators for mapping field variables from one mechanics application to another; (3) a solution controller for code coupling; and (4) included third party libraries (e.g., solver libraries, communications

  15. A proposed classification system for high-level and other radioactive wastes

    International Nuclear Information System (INIS)

    Kocher, D.C.; Croff, A.G.

    1987-06-01

    This report presents a proposal for quantitative and generally applicable risk-based definitions of high-level and other radioactive wastes. On the basis of historical descriptions and definitions of high-level waste (HLW), in which HLW has been defined in terms of its source as waste from reprocessing of spent nuclear fuel, we propose a more general definition based on the concept that HLW has two distinct attributes: HLW is (1) highly radioactive and (2) requires permanent isolation. This concept leads to a two-dimensional waste classification system in which one axis, related to ''requires permanent isolation,'' is associated with long-term risks from waste disposal and the other axis, related to ''highly radioactive,'' is associated with shorter-term risks due to high levels of decay heat and external radiation. We define wastes that require permanent isolation as wastes with concentrations of radionuclides exceeding the Class-C limits that are generally acceptable for near-surface land disposal, as specified in the US Nuclear Regulatory Commission's rulemaking 10 CFR Part 61 and its supporting documentation. HLW then is waste requiring permanent isolation that also is highly radioactive, and we define ''highly radioactive'' as a decay heat (power density) in the waste greater than 50 W/m 3 or an external radiation dose rate at a distance of 1 m from the waste greater than 100 rem/h (1 Sv/h), whichever is the more restrictive. This proposal also results in a definition of Transuranic (TRU) Waste and Equivalent as waste that requires permanent isolation but is not highly radioactive and a definition of low-level waste (LLW) as waste that does not require permanent isolation without regard to whether or not it is highly radioactive

  16. Assessing the performance of the Nagra HLW disposal concept

    International Nuclear Information System (INIS)

    Smith, P.; Zuidema, P.; McKinley, I.G.

    1995-01-01

    This article outlines the procedures used in safety assessment and illustrates their application in evaluating the performance of a high-level waste repository. Nagra's general safety assessment methodology has five main components: formulating the aims of the analysis, defining the safety concept, scenario development, consequence analysis and interpretation of results. A safety analysis based on conservative assumptions shows that the engineered barriers of the high-level waste repository are very effective in preventing release of radionuclides; this alone is sufficient to ensure that regulatory requirements can be met. The function of the host rock is to provide a favourable environment for the engineered barrier system. (author) 8 figs

  17. Baseline levels of bioaerosols and volatile organic compounds around a municipal waste incinerator prior to the construction of a mechanical-biological treatment plant

    International Nuclear Information System (INIS)

    Vilavert, Lolita; Nadal, Marti; Inza, Isabel; Figueras, Maria J.; Domingo, Jose L.

    2009-01-01

    New waste management programs are currently aimed at developing alternative treatment technologies such as mechanical-biological treatment (MBT) and composting plants. However, there is still a high uncertainty concerning the chemical and microbiological risks for human health, not only for workers of these facilities, but also for the population living in the neighborhood. A new MBT plant is planned to be constructed adjacently to a municipal solid waste incinerator (MSWI) in Tarragona (Catalonia, Spain). In order to evaluate its potential impact and to differentiate the impacts of MSWI from those of the MBT when the latter is operative, a pre-operational survey was initiated by determining the concentrations of 20 volatile organic compounds (VOCs) and bioaerosols (total bacteria, Gram-negative bacteria, fungi and Aspergillus fumigatus) in airborne samples around the MSWI. The results indicated that the current concentrations of bioaerosols (ranges: 382-3882, 18-790, 44-926, and 3 for fungi at 25 deg. C, fungi at 37 deg. C, total bacteria, and Gram-negative bacteria, respectively) and VOCs (ranging from 0.9 to 121.2 μg/m 3 ) are very low in comparison to reported levels in indoor and outdoor air in composting and MBT plants, as well in urban and industrial zones. With the exception of total bacteria, no correlations were observed between the environmental concentrations of biological agents and the direction/distance from the facility. However, total bacteria presented significantly higher levels downwind. Moreover, a non-significant increase of VOCs was detected in sites closer to the incinerator, which means that the MSWI could have a very minor impact on the surrounding environment.

  18. Long-term stability of the near-field about high-level radioactive waste repository in thermo-hydro-mechanical coupling action condition

    International Nuclear Information System (INIS)

    Liu Yuemiao; Wang Ju; Ke Dan; Cai Meifeng

    2008-01-01

    It is a long-term process for the high-level radioactive waste repository, from opening, construction to end of its service. The long-term stability of the near-field is the key issue for the design of HLW repository because the opening and heat generated from the HLW. Through a nationwide investigation, Beishan area, a Gobi desert in Gansu province, is considered as a suitable candidate and GMZ bentonite deposit which located in Xinghe County, Inner Mongolia has been proposed for the supplier of buffer/backfill material for HLW geological repository in China. According to the R and D guide of high-level radioactive waste disposal in China, the 3D model of HLW repository with high-level radioactive waste, canister and buffer/backfill material is established using FLAC3D. To take into account in situ stress, geothermal gradient, groundwater, thermal relief of HLW and swelling pressure of buffer/backfill material, the evolution of temperature, stress and displacement of HLW repository under thermo-mechanical coupling, hydro-mechanical coupling and thermo-hydro-mechanical coupling conditions was analyzed respectively. The long-term stability of HLW repository in Beishan area was studied. (authors)

  19. Waste streams from reprocessing operations

    International Nuclear Information System (INIS)

    Andersson, B.; Ericsson, A.-M.

    1978-03-01

    The three main products from reprocessing operations are uranium, plutonium and vitrified high-level-waste. The purpose of this report is to identify and quantify additional waste streams containing radioactive isotops. Special emphasis is laid on Sr, Cs and the actinides. The main part, more than 99 % of both the fission-products and the transuranic elements are contained in the HLW-stream. Small quantities sometimes contaminate the U- and Pu-streams and the rest is found in the medium-level-waste

  20. Treatment of low level radioactive liquid waste containing appreciable concentration of TBP degraded products.

    Science.gov (United States)

    Valsala, T P; Sonavane, M S; Kore, S G; Sonar, N L; De, Vaishali; Raghavendra, Y; Chattopadyaya, S; Dani, U; Kulkarni, Y; Changrani, R D

    2011-11-30

    The acidic and alkaline low level radioactive liquid waste (LLW) generated during the concentration of high level radioactive liquid waste (HLW) prior to vitrification and ion exchange treatment of intermediate level radioactive liquid waste (ILW), respectively are decontaminated by chemical co-precipitation before discharge to the environment. LLW stream generated from the ion exchange treatment of ILW contained high concentrations of carbonates, tributyl phosphate (TBP) degraded products and problematic radio nuclides like (106)Ru and (99)Tc. Presence of TBP degraded products was interfering with the co-precipitation process. In view of this a modified chemical treatment scheme was formulated for the treatment of this waste stream. By mixing the acidic LLW and alkaline LLW, the carbonates in the alkaline LLW were destroyed and the TBP degraded products got separated as a layer at the top of the vessel. By making use of the modified co-precipitation process the effluent stream (1-2 μCi/L) became dischargeable to the environment after appropriate dilution. Based on the lab scale studies about 250 m(3) of LLW was treated in the plant. The higher activity of the TBP degraded products separated was due to short lived (90)Y isotope. The cement waste product prepared using the TBP degraded product was having good chemical durability and compressive strength. Copyright © 2011 Elsevier B.V. All rights reserved.

  1. Progress report on safety research of high-level waste management for the period April, 1981 to March, 1982

    International Nuclear Information System (INIS)

    Tashiro, Shingo

    1982-10-01

    Main results obtained on Safety Research of High-Level Waste Management in 1981 were edited. The research tjeme are following. (1) Characterization of vitrified waste. (2) Alternative waste form development. (3) Durability tests for HLW storage facility. (4) Safety evaluation of geologic disposal. (5) Preparation for hot test. (author)

  2. HANFORD MEDIUM & LOW CURIE WASTE PRETREATMENT PROJECT PHASE 1 LAB REPORT

    Energy Technology Data Exchange (ETDEWEB)

    HAMILTON, D.W.

    2006-01-30

    A fractional crystallization (FC) process is being developed to supplement tank waste pretreatment capabilities provided by the Waste Treatment and Immobilization Plant (WTP). FC can process many tank wastes, separating wastes into a low-activity fraction (LAW) and high-activity fraction (HLW). The low-activity fraction can be immobilized in a glass waste form by processing in the bulk vitrification (BV) system.

  3. Risk analysis of transporting vitrified high-level radioactive waste by train

    International Nuclear Information System (INIS)

    Schneider, K.A.; Merz, E.

    1983-01-01

    Reprocessing plants (RPPs) and final disposal sites for vitrified high level radioactive waste (HLW) will be at distant locations in the Federal Republic of Germany (FRG). HLW will also have to be shipped from RPPs located in foreign countries to a final disposal site in the FRG. Thus transportation of HLW on public routes will become necessary. A model of an HLW shipping system is presented which meets the needs of an established nuclear industry. Reference ages of the HLW were assumed to range between about 5 years and about 50 years. Thus HLW shipping systems covering this period are analyzed. The safety of nuclear installations is ensured by means of a design according to the design based accident. The same applies to shipping casks for radioactive materials (RAM) according to the IAEA Regulations. The aim of this work was to make as complete as reasonably possible an estimate of the risk of shipping HLW. The safety of the system was therefore analyzed by means of probabilistic risk assessment. Release of radioactive material due to transportation accidents is considered. 5 references, 5 figures, 6 tables

  4. DATA SUMMARY REPORT SMALL SCALE MELTER TESTING OF HLW ALGORITHM GLASSES MATRIX1 TESTS VSL-07S1220-1 REV 0 7/25/07

    Energy Technology Data Exchange (ETDEWEB)

    KRUGER AA; MATLACK KS; PEGG IL

    2011-12-29

    Eight tests using different HLW feeds were conducted on the DM100-BL to determine the effect of variations in glass properties and feed composition on processing rates and melter conditions (off-gas characteristics, glass processing, foaming, cold cap, etc.) at constant bubbling rate. In over seven hundred hours of testing, the property extremes of glass viscosity, electrical conductivity, and T{sub 1%}, as well as minimum and maximum concentrations of several major and minor glass components were evaluated using glass compositions that have been tested previously at the crucible scale. Other parameters evaluated with respect to glass processing properties were +/-15% batching errors in the addition of glass forming chemicals (GFCs) to the feed, and variation in the sources of boron and sodium used in the GFCs. Tests evaluating batching errors and GFC source employed variations on the HLW98-86 formulation (a glass composition formulated for HLW C-106/AY-102 waste and processed in several previous melter tests) in order to best isolate the effect of each test variable. These tests are outlined in a Test Plan that was prepared in response to the Test Specification for this work. The present report provides summary level data for all of the tests in the first test matrix (Matrix 1) in the Test Plan. Summary results from the remaining tests, investigating minimum and maximum concentrations of major and minor glass components employing variations on the HLW98-86 formulation and glasses generated by the HLW glass formulation algorithm, will be reported separately after those tests are completed. The test data summarized herein include glass production rates, the type and amount of feed used, a variety of measured melter parameters including temperatures and electrode power, feed sample analysis, measured glass properties, and gaseous emissions rates. More detailed information and analysis from the melter tests with complete emission chemistry, glass durability, and

  5. Development of methodology to construct a generic conceptual model of river-valley evolution for performance assessment of HLW geological disposal

    International Nuclear Information System (INIS)

    Kawamura, Makoto; Tanikawa, Shin-ichi; Yasue, Ken-ichi; Niizato, Tadafumi

    2011-01-01

    In order to assess the long-term safety of a geological disposal system for high-level radioactive waste (HLW), it is important to consider the impact of uplift and erosion, which cannot be precluded on a timescale in the order of several hundred thousand years for many locations in Japan. Geomorphic evolution, caused by uplift and erosion and coupled to climatic and sea-level changes, will impact the geological disposal system due to resulting spatial and temporal changes in the disposal environment. Degradation of HLW barrier performance will be particularly significant when the remnant repository structures near, and are eventually exposed at, the ground surface. In previous studies, fluvial erosion was densified as the key concern in most settings in Japan. Interpretation of the impact of the phenomena at relevant locations in Japan has led to development of a generic conceptual model which contains the features typical at middle reach of rivers. Here, therefore, we present a methodology for development of a generic conceptual model based on best current understanding of fluvial erosion in Japan, which identifies the simplifications and uncertainties involved and assesses their consequences in the context of repository performance. (author)

  6. High Pressure Soxhlet Type Leachability testing device and leaching test of simulated high-level waste glass at high temperature

    International Nuclear Information System (INIS)

    Senoo, Muneaki; Banba, Tsunetaka; Tashiro, Shingo; Shimooka, Kenji; Araki, Kunio

    1979-11-01

    A High Pressure Soxhlet Type Leachability Testing Device (HIPSOL) was developed to evaluate long-period stability of high-level waste (HLW) solids. For simulated HLW solids, temperature dependency of the leachability was investigated at higher temperatures from 100 0 C to 300 0 C at 80 atm. Leachabilities of cesium and sodium at 295 0 C were 20 and 7 times higher than at 100 0 C, respectively. In the repository, the temperatures around solidified products may be hundred 0 C. It is essential to test them at such elevated temperatures. HIPSOL is also usable for accelerated test to evaluate long-period leaching behavior of HLW products. (author)

  7. On immobilization of high-level waste in an Y–Al garnet-based cermet matrix in SHS conditions

    OpenAIRE

    Konovalov, E.E.; Lastov, A.I.; Nerozin, N.A.

    2015-01-01

    A method of high-level waste (HLW) radionuclide immobilization in a long-life matrix based on Y–Al garnet, a material highly chemically resistant to natural environments, has been developed for the ultimate HLW isolation from the environment. Model systems containing Ce, Nd, Sm, Zr, Mo, 238U, and 241Am were used in the study as simulators of HLW radionuclides. An energy-saving technology of self-propagating high-temperature synthesis (SHS) was employed to synthesize the matrix material with f...

  8. Interfaces between transport and geologic disposal systems for high-level radioactive wastes and spent nuclear fuel: A new international guidance document

    International Nuclear Information System (INIS)

    Pope, R.B.; Baekelandt, L.; Hoorelbeke, J.M.; Han, K.W.; Pollog, T.; Blackman, D.; Villagran, J.E.

    1994-01-01

    An International Atomic Energy Agency (IAEA) Technical Document (TECDOC) has been developed and will be published by the IAEA. The TECDOC addresses the interfaces between the transport and geologic disposal systems for, high-level waste (HLW) and spent nuclear fuel (SNF). The document is intended to define and assist in discussing, at both the domestic and the international level, regulatory, technical, administrative, and institutional interfaces associated with HLW and SNF transport and disposal systems; it identifies and discusses the interfaces and interface requirements between the HLW and SNF, the waste transport system used for carriage of the waste to the disposal facility, and the HLW/SNF disposal facility. It provides definitions and explanations of terms; discusses systems, interfaces and interface requirements; addresses alternative strategies (single-purpose packages and multipurpose packages) and how interfaces are affected by the strategies; and provides a tabular summary of the requirements

  9. Selection of Technical Solutions for the Management of Radioactive Waste

    International Nuclear Information System (INIS)

    2017-07-01

    The objectives of this publication are to identify and critically review the criteria to be considered while selecting waste management technologies; summarize, evaluate, rank and compare the different technical solutions; and offer a systematic approach for selecting the best matching solution. This publication covers the management of radioactive waste from all nuclear operations, including waste generated from research reactors, power reactors, and nuclear fuel cycle activities including high level waste (HLW) arising from reprocessing and spent nuclear fuel declared as waste (SFW), as well as low level waste (LLW) and intermediate level waste (ILW) arising from the production and use of radionuclides in industry, agriculture, medicine, education and research.

  10. Optimization of Deep Borehole Systems for HLW Disposal

    International Nuclear Information System (INIS)

    Driscoll, Michael; Baglietto, Emilio; Buongiorno, Jacopo; Lester, Richard; Brady, Patrick; Arnold, B. W.

    2015-01-01

    This is the final report on a project to update and improve the conceptual design of deep boreholes for high level nuclear waste disposal. The effort was concentrated on application to intact US legacy LWR fuel assemblies, but conducted in a way in which straightforward extension to other waste forms, host rock types and countries was preserved. The reference fuel design version consists of a vertical borehole drilled into granitic bedrock, with the uppermost kilometer serving as a caprock zone containing a diverse and redundant series of plugs. There follows a one to two kilometer waste canister emplacement zone having a hole diameter of approximately 40-50 cm. Individual holes are spaced 200-300 m apart to form a repository field. The choice of verticality and the use of a graphite based mud as filler between the waste canisters and the borehole wall liner was strongly influenced by the expectation that retrievability would continue to be emphasized in US and worldwide repository regulatory criteria. An advanced version was scoped out using zinc alloy cast in place to fill void space inside a disposal canister and its encapsulated fuel assembly. This excludes water and greatly improves both crush resistance and thermal conductivity. However the simpler option of using a sand fill was found adequate and is recommended for near-term use. Thermal-hydraulic modeling of the low permeability and porosity host rock and its small (@@@ 1%) saline water content showed that vertical convection induced by the waste's decay heat should not transport nuclides from the emplacement zone up to the biosphere atop the caprock. First order economic analysis indicated that borehole repositories should be cost-competitive with shallower mined repositories. It is concluded that proceeding with plans to drill a demonstration borehole to confirm expectations, and to carry out priority experiments, such as retention and replenishment of in-hole water is in order.

  11. Operating experience during high-level waste vitrification at the West Valley Demonstration Project

    International Nuclear Information System (INIS)

    Valenti, P.J.; Elliott, D.I.

    1999-01-01

    This report provides a summary of operational experiences, component and system performance, and lessons learned associated with the operation of the Vitrification Facility (VF) at the West Valley Demonstration Project (WVDP). The VF was designed to convert stored high-level radioactive waste (HLW) into a stable waste form (borosilicate glass) suitable for disposal in a federal repository. Following successful completion on nonradioactive test, HLW processing began in July 1995. Completion of Phase 1 of HLW processing was reached on 10 June 1998 and represented the processing of 9.32 million curies of cesium-137 (Cs-137) and strontium-90 (Sr-90) to fill 211 canisters with over 436,000 kilograms of glass. With approximately 85% of the total estimated curie content removed from underground waste storage tanks during Phase 1, subsequent operations will focus on removal of tank heel wastes

  12. A GoldSim Based Biosphere Assessment Model for a HLW Repository

    International Nuclear Information System (INIS)

    Lee, Youn-Myoung; Hwang, Yong-Soo; Kang, Chul-Hyung

    2007-01-01

    To demonstrate the performance of a repository, the dose exposure to a human being due to nuclide releases from a repository should be evaluated and the results compared to the dose limit presented by the regulatory bodies. To evaluate a dose rate to an individual due to a long-term release of nuclides from a HLW repository, biosphere assessment models and their implemented codes such as ACBIO1 and ACBIO2 have been developed with the aid of AMBER during the last few years. BIOMASS methodology has been adopted for a HLW repository currently being considered in Korea, which has a similar concept to the Swedish KBS-3 HLW repository. Recently, not just only for verifying the purpose for biosphere assessment models but also for varying the possible alternatives to assess the consequences in a biosphere due to a HLW repository, another version of the assessment modesl has been newly developed in the frame of development programs for a total system performance assessment modeling tool by utilizing GoldSim. Through a current study, GoldSim approach for a biosphere modeling is introduced. Unlike AMBER by which a compartment scheme can be rather simply constructed with an appropriate transition rate between compartments, GoldSim was designed to facilitate the object-oriented modules by which specific models can be addressed in an additional manner, like solving jig saw puzzles

  13. HLW Salt Disposition Alternatives Identification Preconceptual Phase I Summary Report (Including Attachments)

    International Nuclear Information System (INIS)

    Piccolo, S.F.

    1999-01-01

    The purpose of this report is to summarize the process used by the Team to systematically develop alternative methods or technologies for final disposition of HLW salt. Additionally, this report summarizes the process utilized to reduce the total list of identified alternatives to an ''initial list'' for further evaluation. This report constitutes completion of the team charter major milestone Phase I Deliverable

  14. Identification of potential transuranic waste tanks at the Hanford Site

    Energy Technology Data Exchange (ETDEWEB)

    Colburn, R.P.

    1995-05-05

    The purpose of this document is to identify potential transuranic (TRU) material among the Hanford Site tank wastes for possible disposal at the Waste Isolation Pilot Plant (WIPP) as an alternative to disposal in the high-level waste (HLW) repository. Identification of such material is the initial task in a trade study suggested in WHC-EP-0786, Tank Waste Remediation System Decisions and Risk Assessment (Johnson 1994). The scope of this document is limited to the identification of those tanks that might be segregated from the HLW for disposal as TRU, and the bases for that selection. It is assumed that the tank waste will be washed to remove soluble inert material for disposal as low-level waste (LLW), and the washed residual solids will be vitrified for disposal. The actual recommendation of a disposal strategy for these materials will require a detailed cost/benefit analysis and is beyond the scope of this document.

  15. Identification of potential transuranic waste tanks at the Hanford Site

    International Nuclear Information System (INIS)

    Colburn, R.P.

    1995-01-01

    The purpose of this document is to identify potential transuranic (TRU) material among the Hanford Site tank wastes for possible disposal at the Waste Isolation Pilot Plant (WIPP) as an alternative to disposal in the high-level waste (HLW) repository. Identification of such material is the initial task in a trade study suggested in WHC-EP-0786, Tank Waste Remediation System Decisions and Risk Assessment (Johnson 1994). The scope of this document is limited to the identification of those tanks that might be segregated from the HLW for disposal as TRU, and the bases for that selection. It is assumed that the tank waste will be washed to remove soluble inert material for disposal as low-level waste (LLW), and the washed residual solids will be vitrified for disposal. The actual recommendation of a disposal strategy for these materials will require a detailed cost/benefit analysis and is beyond the scope of this document

  16. National high-level waste systems analysis plan

    International Nuclear Information System (INIS)

    Kristofferson, K.; Oholleran, T.P.; Powell, R.H.; Thiel, E.C.

    1995-05-01

    This document details the development of modeling capabilities that can provide a system-wide view of all US Department of Energy (DOE) high-level waste (HLW) treatment and storage systems. This model can assess the impact of budget constraints on storage and treatment system schedules and throughput. These impacts can then be assessed against existing and pending milestones to determine the impact to the overall HLW system. A nation-wide view of waste treatment availability will help project the time required to prepare HLW for disposal. The impacts of the availability of various treatment systems and throughput can be compared to repository readiness to determine the prudent application of resources or the need to renegotiate milestones

  17. Final disposal of radioactive waste

    Directory of Open Access Journals (Sweden)

    Freiesleben H.

    2013-06-01

    Full Text Available In this paper the origin and properties of radioactive waste as well as its classification scheme (low-level waste – LLW, intermediate-level waste – ILW, high-level wasteHLW are presented. The various options for conditioning of waste of different levels of radioactivity are reviewed. The composition, radiotoxicity and reprocessing of spent fuel and their effect on storage and options for final disposal are discussed. The current situation of final waste disposal in a selected number of countries is mentioned. Also, the role of the International Atomic Energy Agency with regard to the development and monitoring of international safety standards for both spent nuclear fuel and radioactive waste management is described.

  18. Cementitious waste option scoping study report

    International Nuclear Information System (INIS)

    Lee, A.E.; Taylor, D.D.

    1998-02-01

    A Settlement Agreement between the Department of Energy (DOE) and the State of Idaho mandates that all high-level radioactive waste (HLW) now stored at the Idaho Chemical Processing Plant (ICPP) on the Idaho National Engineering and Environmental Laboratory (INEEL) will be treated so that it is ready to be moved out of Idaho for disposal by a target date of 2035. This study investigates the nonseparations Cementitious Waste Option (CWO) as a means to achieve this goal. Under this option all liquid sodium-bearing waste (SBW) and existing HLW calcine would be recalcined with sucrose, grouted, canisterized, and interim stored as a mixed-HLW for eventual preparation and shipment off-Site for disposal. The CWO waste would be transported to a Greater Confinement Disposal Facility (GCDF) located in the southwestern desert of the US on the Nevada Test Site (NTS). All transport preparation, shipment, and disposal facility activities are beyond the scope of this study. CWO waste processing, packaging, and interim storage would occur over a 5-year period between 2013 and 2017. Waste transport and disposal would occur during the same time period

  19. Cementitious waste option scoping study report

    Energy Technology Data Exchange (ETDEWEB)

    Lee, A.E.; Taylor, D.D.

    1998-02-01

    A Settlement Agreement between the Department of Energy (DOE) and the State of Idaho mandates that all high-level radioactive waste (HLW) now stored at the Idaho Chemical Processing Plant (ICPP) on the Idaho National Engineering and Environmental Laboratory (INEEL) will be treated so that it is ready to be moved out of Idaho for disposal by a target date of 2035. This study investigates the nonseparations Cementitious Waste Option (CWO) as a means to achieve this goal. Under this option all liquid sodium-bearing waste (SBW) and existing HLW calcine would be recalcined with sucrose, grouted, canisterized, and interim stored as a mixed-HLW for eventual preparation and shipment off-Site for disposal. The CWO waste would be transported to a Greater Confinement Disposal Facility (GCDF) located in the southwestern desert of the US on the Nevada Test Site (NTS). All transport preparation, shipment, and disposal facility activities are beyond the scope of this study. CWO waste processing, packaging, and interim storage would occur over a 5-year period between 2013 and 2017. Waste transport and disposal would occur during the same time period.

  20. Development of a glass matrix for vitrification of sulphate bearing high level radioactive liquid waste

    International Nuclear Information System (INIS)

    Kaushik, C.P.; Mishra, R.K.; Thorat, Vidya; Ramchandran, M.; Amar Kumar; Ozarde, P.D.; Raj, Kanwar; Das, D.

    2004-07-01

    High level radioactive liquid waste (HLW) is generated during reprocessing of spent nuclear fuel. In the earlier reprocessing flow sheet ferrous sulphamate has been used for valancy adjustment of Pu from IV to III for effective separation. This has resulted in generation of HLW containing significance amount of sulphate. Internationally borosilicate glass matrix has been adopted for vitrification of HLW. The first Indian vitrification facility at Waste Immobilislition Plant (WIP), Tarapur a five component borosilicate matrix (SiO 2 :B 2 O 3 :Na 2 O : MnO : TiO 2 ) has been used for vitrification of waste. However at Trombay HLW contain significant amount of sulphate which is not compatible with standard borosilicate formulation. Extensive R and D efforts were made to develop a glass formulation which can accommodate sulphate and other constituents of HLW e.g., U, Al, Ca, etc. This report deals with development work of a glass formulations for immobilization of sulphate bearing waste. Different glass formulations were studied to evaluate the compatibility with respect to sulphate and other constituents as mentioned above. This includes sodium, lead and barium borosilicate glass matrices. Problems encountered in different glass matrices for containment of sulphate have also been addressed. A glass formulation based on barium borosilicate was found to be effective and compatible for sulphate bearing high level waste. (author)

  1. Waste vitrification: a historical perspective

    International Nuclear Information System (INIS)

    McElroy, J.L.; Bjorklund, W.J.; Bonner, W.F.

    1982-02-01

    The possibility of converting high-level wastes (HLW) to glass was first pursued in Canada and England at a time when other countries were evaluating many other alternatives. By 1966, the British had completed radioactive demonstrations of the FINGAL pot process, converting HLW to borosilicate glass. By this time other countries, including France and the United States, had begun using the glass waste form. Beginning in 1966, several processes, including phosphate and borosilicate glass, were demonstrated by the US in the Waste Solidification Engineering Prototypes (WSEP) program at the Pacific Northwest Laboratory (PNL). Most of the current vitrification processes are adaptations of the FINGAL pot process or the continuous metallic melter used in the WSEP program. One notable exception is the joule-heated ceramic melter, which was adapted from commercial glass technology for HLW by PNL in the mid-1970's. Both batch and continuous processes have been developed to an advanced stage of readiness. These processes are described and compared in this paper

  2. Workshop on the role of natural analogs in geologic disposal of high-level nuclear waste

    International Nuclear Information System (INIS)

    Murphy, W.M.; Kovach, L.A.

    1995-01-01

    A workshop on the Role of Natural Analogs in Geologic Disposal of High-Level Nuclear Waste (HLW) was held in San Antonio, Texas, on July 22-25, 1991. It was sponsored by the US Nuclear Regulatory Commission (NRC) and the Center for Nuclear Waste Regulatory Analyses (CNWRA). Invitations to the workshop were extended to a large number of individuals with a variety of technical and professional interests related to geologic disposal of nuclear waste and natural analog studies. The objective of the workshop was to examine the role of natural analog studies in performance assessment, site characterization, and prioritization of research related to geologic disposal of HLW

  3. Low-risk alternative waste forms for problematic high-level and long-lived nuclear wastes

    International Nuclear Information System (INIS)

    Stewart, M.W.A.; Begg, B.D.; Moricca, S.; Day, R.A.

    2006-01-01

    Full text: The highest cost component the nuclear waste clean up challenge centres on high-level waste (HLW) and consequently the greatest opportunity for cost and schedule savings lies with optimising the approach to HLW cleanup. The waste form is the key component of the immobilisation process. To achieve maximum cost savings and optimum performance the selection of the waste form should be driven by the characteristics of the specific nuclear waste to be immobilised, rather than adopting a single baseline approach. This is particularly true for problematic nuclear wastes that are often not amenable to a single baseline approach. The use of tailored, high-performance, alternative waste forms that include ceramics and glass-ceramics, coupled with mature process technologies offer significant performance improvements and efficiency savings for a nuclear waste cleanup program. It is the waste form that determines how well the waste is locked up (chemical durability), and the number of repository disposal canisters required (waste loading efficiency). The use of alternative waste forms for problematic wastes also lowers the overall risk by providing high performance HLW treatment alternatives. The benefits tailored alternative waste forms bring to the HLW cleanup program will be briefly reviewed with reference to work carried out on the following: The HLW calcines at the Idaho National Laboratory; SYNROC ANSTO has developed a process utilising a glass-ceramic combined with mature hot-isostatic pressing (HIP) technology and has demonstrated this at a waste loading of 80 % and at a 30 kg HIP scale. The use of this technology has recently been estimated to result in a 70 % reduction in waste canisters, compared to the baseline borosilicate glass technology; Actinide-rich waste streams, particularly the work being done by SYNROC ANSTO with Nexia Solutions on the Plutonium-residues wastes at Sellafield in the UK, which if implemented is forecast to result in substantial

  4. Proposal for geological site selection for L/ILW and HLW repositories. Statement of requirements, procedure and results. Technical report 08-03

    International Nuclear Information System (INIS)

    2008-10-01

    Important steps in the process of managing radioactive wastes have already been implemented in Switzerland. These include the handing and packaging of the waste, waste characterisation and documentation of waste inventories and interim storage along with associated transport. In terms of preparing for deep geological disposal, the necessary scientific and technical work is well advanced and the feasibility of constructing geological repositories that provide the required long-term safety has been successfully demonstrated for all waste types arising in Switzerland. Sufficient knowledge is available to allow the next steps in the selection of repository sites to be defined. The legal framework is also in place and organisational measures have been provided that will allow the tasks to be performed in the coming years to be implemented efficiently. The selection of geological siting regions and sites for repositories in Switzerland will be conducted in three stages. Stage 1 ends with the definition of geological siting regions within which the repository projects will be elaborated in more detail in stages 2 and 3. This report documents and justifies the siting proposals prepared by Nagra for the repositories for low- and intermediate-level waste (L/ILW) and high-level waste (HLW). Formulation of these proposals is conducted in five steps: 1) The waste inventory, which includes reserves for future developments, is allocated to the L/ILW and HLW repositories; 2) Based on this waste allocation, the second step involves defining the barrier and safety concepts for the two repositories. With a view to evaluating the geological siting possibilities, quantitative and qualitative guidelines and requirements on the geology are derived on the basis of these concepts. These relate to the time period to be considered, the space requirements for the repository, the properties of the host rock (depth, thickness, lateral extent, hydraulic conductivity), long-term stability

  5. Thermo-mechanical analysis for multi-level HLW repository concept

    International Nuclear Information System (INIS)

    Kwon, Sang Ki; Choi, Jong Won

    2004-01-01

    This work aims to investigate the influence of design parameters for the underground high-level nuclear waste repository with multi-level concept. B. Necessity o In order to construct an HLW repository in deep underground, it is required to select a site, which is far from major discontinuities. To dispose the whole spent fuels generated from the Korean nuclear power plants in a repository, the underground area of about 4km 2 is required. This would be a constraints for selecting an adequate repository site. It is recommended to dispose the two different spent fuels, PWR and CANDU, in different areas at the operation efficiency point of view. It is necessary to investigate the influence of parameters, which can affect the stability of multi-level repository. It is also needed to consider the influence of heat generated from the HLW and the high in situ stress in deep location. Therefore, thermo-mechanical coupling analysis should be carried out and the results should be compared with the results from single-level repository concept. Three-dimensional analysis is required to model the disposal tunnel and deposition hole. It is recommended to use the Korean geological condition and actually measured rock properties in Korea in order to achieve reliable modeling results. A FISH routine developed for effective modeling of Thermal-Mechanical coupling was implemented in the modeling using FLAC3D, which is a commercial three-dimensional FDM code. The thermal and mechanical properties of rock and rock mass achieved from Yusung drilling site, were used for the computer modeling. Different parameters such as level distance, waste type disposed on different levels, and time interval between the operation on different levels, were considered in the three-dimensional analysis. From the analysis, it was possible to derive adequate multi-level repository concept. Results and recommendations for application From the thermal-mechanical analysis for the multi-level repository

  6. Taking account of the biosphere in HLW assessment

    International Nuclear Information System (INIS)

    Smith, G.M.; Grogan, H.A.

    1992-01-01

    Evaluation of the biosphere in High level Waste assessment is beset with difficulties concerned with the disparity in timescales for geosphere and biosphere processes and prediction of the long term conditions in the biosphere. These issues are discussed against the background of developments on criteria, calculational end points, timescales, environmental change and human activities, relationship to other parts of the assessment, and uncertainty and variability. In this paper an outline for a surface environment assessment program is proposed

  7. Optimization of Deep Borehole Systems for HLW Disposal

    Energy Technology Data Exchange (ETDEWEB)

    Driscoll, Michael [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Baglietto, Emilio [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Buongiorno, Jacopo [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Lester, Richard [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Brady, Patrick [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Arnold, B. W. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2015-09-09

    This is the final report on a project to update and improve the conceptual design of deep boreholes for high level nuclear waste disposal. The effort was concentrated on application to intact US legacy LWR fuel assemblies, but conducted in a way in which straightforward extension to other waste forms, host rock types and countries was preserved. The reference fuel design version consists of a vertical borehole drilled into granitic bedrock, with the uppermost kilometer serving as a caprock zone containing a diverse and redundant series of plugs. There follows a one to two kilometer waste canister emplacement zone having a hole diameter of approximately 40-50 cm. Individual holes are spaced 200-300 m apart to form a repository field. The choice of verticality and the use of a graphite based mud as filler between the waste canisters and the borehole wall liner was strongly influenced by the expectation that retrievability would continue to be emphasized in US and worldwide repository regulatory criteria. An advanced version was scoped out using zinc alloy cast in place to fill void space inside a disposal canister and its encapsulated fuel assembly. This excludes water and greatly improves both crush resistance and thermal conductivity. However the simpler option of using a sand fill was found adequate and is recommended for near-term use. Thermal-hydraulic modeling of the low permeability and porosity host rock and its small (≤ 1%) saline water content showed that vertical convection induced by the waste’s decay heat should not transport nuclides from the emplacement zone up to the biosphere atop the caprock. First order economic analysis indicated that borehole repositories should be cost-competitive with shallower mined repositories. It is concluded that proceeding with plans to drill a demonstration borehole to confirm expectations, and to carry out priority experiments, such as retention and replenishment of in-hole water is in order.

  8. High Level Waste Feed Delivery AZ-101 Batch Transfer to the Private Contractor Transfer and Mixing Process Improvements

    International Nuclear Information System (INIS)

    DUNCAN, G.P.

    2000-01-01

    The primary purpose of this business case is to provide Operations and Maintenance with a detailed transfer process review for the first High Level Waste (HLW) feed delivery to the Privatization Contractor (PC), AZ-101 batch transfer to PC. The Team was chartered to identify improvements that could be implemented in the field. A significant penalty can be invoked for not providing the quality, quantity, or timely delivery of HLW feed to the PC

  9. US DOE Initiated Performance Enhancements to the Hanford Waste Treatment and Immobilization Plant (WTP) Low-activity Waste Vitrification (LAW) System

    International Nuclear Information System (INIS)

    Hamel, William F.; Gerdes, Kurt D.; Holton, Langdon K.; Pegg, Ian L.; Bowen, Brad W.

    2006-01-01

    The U.S Department of Energy Office of River Protection (DOE-ORP) is constructing a Waste Treatment and Immobilization Plant (WTP) for the treatment and vitrification of underground tank wastes stored at the Hanford Site in Washington State. The WTP comprises four major facilities: a pretreatment facility to separate the tank waste into high level waste (HLW) and low-activity waste (LAW) process streams, a HLW vitrification facility to immobilize the HLW fraction; a LAW vitrification facility to immobilize the LAW fraction, and an analytical laboratory to support the operations of all four treatment facilities. DOE has established strategic objectives to optimize the performance of the WTP facilities and the LAW and HLW waste forms to reduce the overall schedule and cost for treatment and vitrification of the Hanford tank wastes. This strategy has been implemented by establishing performance expectations in the WTP contract for the facilities and waste forms. In addition, DOE, as owner-operator of the WTP facilities, continues to evaluate (1) the design, to determine the potential for performance above the requirements specified in the WTP contract; and (2) improvements in production of the LAW and HLW waste forms. This paper reports recent progress directed at improving production of the LAW waste form. DOE's initial assessment, which is based on the work reported in this paper, is that the capacity of the WTP LAW vitrification facility can be increased by a factor of 2 to 4 with a combination of revised glass formulations, modest increases in melter glass operating temperatures, and a second-generation LAW melter with a larger surface area. Implementing these improvements in the LAW waste immobilization capability can benefit the LAW treatment mission by reducing both processing time and cost

  10. Encapsulating of high-level radioactive waste with use of pyrocarbon and silicon carbide coatings

    International Nuclear Information System (INIS)

    Chernikov, A.

    2007-01-01

    It is known that high-level radioactive waste (HLW) constitute a real danger to biosphere, especially that their part, which contains transuranium and long-lived radionuclides resulting during reprocessing of nuclear fuel industrial and power reactors. Such waste contains approximately 99 % of long-lived fission products and transplutonium elements. At present, the concept of multi barrier protection of biosphere from radioactive waste is generally acknowledged. The main barriers are the physicochemical form of waste and enclosing strata of geological formation at places of waste-disposal. Applied methods of solidification of HLW with preparation of phosphatic and borosilicate glasses do not guarantee in full measure safety of places of waste-disposal of solidified waste in geological formations during thousand years. One promising way to improve HLW handling safety is placing of radionuclides in mineral-like matrixes similar to natural materials. The other possible way to increase safety of HLW disposal places is suggested for research by experts of Russian research institutes, for example, in the proposal for the Project of ISTC and considered in the present report, is to introduce an additional barrier on a radionuclides migration path by coating of HLW particles. Unique protective properties of pyrocarbon and silicon carbide such as low coefficients of diffusion of gaseous and solid fission products and high chemical and radiation stability [1] attract attention to these materials for coating of solidified HLW. The objective of the Project is the development of method of HLW encapsulating with use of pyrocarbon and silicon carbide coatings. To gain this end main direction of researches, including analysis of various encapsulation processes of fractionated HLW, and expected results are presented. Realization of the Project will allow to prove experimentally the efficiency of the proposed approach in the solution of the problem of HLW conditioning and ecological

  11. Material chemistry challenges in vitrification of high level radioactive waste

    International Nuclear Information System (INIS)

    Kaushik, C.P.

    2008-01-01

    Full text: Nuclear technology with an affective environmental management plan and focused attention on safety measures is a much cleaner source of electricity generation as compared to other sources. With this perspective, India has undertaken nuclear energy program to share substantial part of future need of power. Safe containment and isolation of nuclear waste from human environment is an indispensable part of this programme. Majority of radioactivity in the entire nuclear fuel cycle is high level radioactive liquid waste (HLW), which is getting generated during reprocessing of spent nuclear fuels. A three stage strategy for management of HLW has been adopted in India. This involves (i) immobilization of waste oxides in stable and inert solid matrices, (ii) interim retrievable storage of the conditioned waste product under continuous cooling and (iii) disposal in deep geological formation. Borosilicate glass matrix has been adopted in India for immobilization of HLW. Material issue are very important during the entire process of waste immobilization. Performance of the materials used in nuclear waste management determines its safety/hazards. Material chemistry therefore has a significant bearing on immobilization science and its technological development for management of HLW. The choice of suitable waste form to deploy for nuclear waste immobilization is difficult decision and the durability of the conditioned product is not the sole criterion. In any immobilization process, where radioactive materials are involved, the process and operational conditions play an important role in final selection of a suitable glass formulation. In remotely operated vitrification process, study of chemistry of materials like glass, melter, materials of construction of other equipment under high temperature and hostile corrosive condition assume significance for safe and un-interrupted vitrification of radioactive to ensure its isolation waste from human environment. The present

  12. Development of a Rotary Microfilter for SRS HLW Applications

    International Nuclear Information System (INIS)

    MICHAEL, POIRIER

    2005-01-01

    The processing rate of Savannah River Site (SRS) high-level waste decontamination processes are limited by the flow rate of the solid-liquid separation. The baseline process, using a 0.1 micron cross-flow filter, produces approximately 0.02 gpm/sq. ft. of filtrate under expected operating conditions. Savannah River National Laboratory (SRNL) personnel identified the rotary microfilter as a technology that could significantly increase filter flux, with throughput improvements of as much as 10X for that specific operation. With funding from the U. S. Department of Energy Office of Cleanup Technology, SRNL personnel are evaluating and developing the rotary microfilter for radioactive service at SRS. This work includes pilot-scale and actual waste testing to evaluate system reliability, the impact of radiation on system components, the filter flux for a variety of waste streams, and relative performance for alternative filter media. Personnel revised the design for the disks and filter unit to make them suitable for high-level radioactive service

  13. Nuclear Waste Fund management

    International Nuclear Information System (INIS)

    Rosselli, R.

    1984-01-01

    The Nuclear Waste Policy Act of 1982 (NWPA) established two separate special bank accounts: the Nuclear Waste Fund (NWF) was established to finance all of the Federal Government activities associated with the disposal of High-Level Waste (HLW) or Spent Nuclear Fuel (SNF). The Interim Storage Fund (ISF) is the financial mechanism for the provision of Federal Interim Storage capacity, not to exceed 1900 metric tons of SNF at civilian power reactors. The management of these funds is discussed. Since the two funds are identical in features and the ISF has not yet been activated, the author's remarks are confined to the Nuclear Waste Fund. Three points discussed include legislative features, current status, and planned activities

  14. Technical baseline description of high-level waste and low-activity waste feed mobilization and delivery

    International Nuclear Information System (INIS)

    Papp, I.G.

    1997-01-01

    This document is a compilation of information related to the high-level waste (HLW) and low-activity waste (LAW) feed staging, mobilization, and transfer/delivery issues. Information relevant to current Tank Waste Remediation System (TWRS) inventories and activities designed to feed the Phase I Privatization effort at the Hanford Site is included. Discussions on the higher level Phase II activities are offered for a perspective on the interfaces

  15. A compartment model for nuclide release calculation in the near-and far-field of a HLW repository

    International Nuclear Information System (INIS)

    Lee, Youn Myoung; Hwang, Yong Soo; Kang, Chul Hyung; Hahn, Pil Soo

    2004-01-01

    The HLW-relevant R and D program for disposal of high-level radioactive waste has been carried out at Korea Atomic Energy Research Institute (KAERI) since early 1997, from which a conceptual Korea Reference Repository System for direct disposal of nuclear spent fuel is to be introduced by the end of 2007. A preliminary reference geologic repository concept considering such established criteria and requirements as spent fuel and generic site characteristics in Korea was roughly envisaged in 2003. Not only to demonstrate how much a reference repository is safe in the generic point of view with several possible scenarios and cases associated with a preliminary repository concept by conducting calculations for nuclide release and transport in the near - and far - field components of the repository, even though sufficient information has not been available that much yet, but also to show a appropriate methodology by which both a generic and site - specific safety assessment could be performed for further in - depth development of Korea reference repository concept, nuclide release calculation study for various nuclide release cases is mandatory. To this end a similar study done and yet limited for the near - field release case has been extended to the case including far - field system by introducing some more geosphere compartments. Advective and longitudinal dispersive nuclide transports along the fracture with matrix diffusion as well as several retention mechanisms and nuclide ingrowth has been added

  16. Mechanical behavior of host rock close to H.L.W. disposal cavities in a deep granitic formation

    International Nuclear Information System (INIS)

    Hoorelbeke, J.M.; Dourthe, M.

    1986-01-01

    The construction of a H.L.W. repository in a deep granitic formation creates mechanical disturbances in the rock on the scale of the massif and in the nearfield. Amongst all the disturbances noted in the nearfield, this study is concerned with examining the evolution of stresses linked with the excavation of the rock and the rise in temperature in the proximity of the waste packages. Several linear elasticity calculations were made using on the one hand finite element models and on the other simple analytical models. These calculations concern two different storage concepts - in room concept and in floor concept- whose differences in mechanical behavior are analyzed. A study of sensitivity with regard to the characteristics of the rock and to the initial geostatic stresses is presented. The comparison of the calculated stresses with three-dimensional failure criteria gives a clear indication of the satisfactory behavior of granite for final storage. However, the need for experimental study and complementary calculation must be emphasized

  17. Feasibility studies for alpha waste disposal on geological formations in France

    International Nuclear Information System (INIS)

    Jaouen, C.; Boulanger, A.

    1985-01-01

    Since 1977, SGN has been involved in many feasibility studies and consultant works in the fields of HLW storages. Starting as nuclear consultant company in the KBS review of the long term storage of HLW, SGN and Geostock were entrusted in 1978 by the EEC for the basic design and evaluation of the deep storage into granite rock of HLW, followed by a participation in the thermal sensitivity study of such a storage. The cooperation with Geostock was first extended in 1981 to a preliminary study of HLW storage conditions in granite for a Japanese company, and then in France for several feasibility studies of HLW and TRU waste geological disposal. Three kinds of scenarios have been forecasted and evaluated in the case of vitrified HLW storage, allowing the thermal power to be decreased and the whole management scheme to be optimized. More recently, SGN participation to French engineering studies has been extended by ANDRA to the TRU waste repository evaluation. All these works for French authorities have been performed in a close connection with several specialized departments in the CEA group, and with the help of geological specialists, under the leadership of ANDRA [fr

  18. High-gradient magnetic separation for the treatment of high-level radioactive wastes

    International Nuclear Information System (INIS)

    Ebner, A.D.; Ritter, J.A.; Nunez, L.

    1999-01-01

    Argonne National Laboratory is developing an open-gradient magnetic separation (OGMS) system to fractionate and remove nonglass-forming species from high-level radioactive wastes (HLW); however, to avoid clogging, OGMS may require high-gradient magnetic separation (HGMS) as a pretreatment to remove the most magnetic species from the HLW. In this study, the feasibility of using HGMS in the pretreatment of HLW was demonstrated. A HLW simulant of hanford's C-103 tank waste, which contained precipitate hydroxides and oxides of Fe, Al, Si, and Ca, was used. Preliminary fractionation results from a 0.3-T bench-scale HGMS unit showed that a significant amount of Fe could be removed from the HLW simulant. Between 1 and 2% of the total Fe in the sludge was removed during each stage, with over 18.5% removed in the 13 stages that were carried out. Also, in each stage, the magnetically retained fraction contained about 20% more Fe than the untreated HLW; however, it also contained a significant amount of SiO 2 in relatively large particles. This indicated that SiO 2 was acting possibly as a nucleation agent for Fe (i.e., an Fe adsorbent) and that the fractionation was based more on size than on magnetic susceptibility

  19. Necessary contents of public outreach for high level radioactive waste disposal

    International Nuclear Information System (INIS)

    Kanzaki, Noriko; Okamoto, Koji

    2011-01-01

    Nuclear power generation is one of the solutions for global warming. However, the nuclear power generation technology can not be completed unless the disposal method of the radioactive waste is decided. Various actions are performed about the High Level Radioactive Waste (HLW) disposal in particular in each country. However, planning of HLW disposal site was not successful, except Finland and Sweden. In Japan, geological disposal of HLW was selected. The operating body and the capital management body are also decided. Up to the present, no municipality apply the disposal site candidate. An important social element for HLW disposal is careful explanation and communication for municipality. For this purpose, a symposium to explain necessity of HLW is held in each district in Japan. The symposium is not successful, because of lack of carefulness to local situation considered. In this study, we evaluates the questionnaire by the symposium attendee to extract the idea and requests by the local people. With these questionnaire, the responsibility of the government should be more enhanced. Also, the detail answer to the people's questions are needed. Using these knowledge, the HLW disposal social acceptance has been discussed. (author)

  20. Feasibility studies for alpha waste disposal on geological formations in France

    International Nuclear Information System (INIS)

    Jaouen, C.; Boulanger, A.

    1986-01-01

    Since 1977, SGN has been involved in many feasibility studies and consultant works in the fields of HLW storages. Starting as nuclear consultant company in the KBS review of the long term storage of HLW, SGN and GEOSTOCK were entrusted in 1978 by the EEC for the basic design and evaluation of the deep storage into granite rock of HLW, followed by a participation in the thermal sensitivity study of such a storage. The cooperation with GEOSTOCK was first extended in 1981 to a preliminary study of HLW storage conditions in granite for a Japanese company, and then in France for several feasibility studies of HLW and TRU waste geological disposal. Three kinds of scenarios have been forecasted and evaluated in the case of vitrified HLW storage, allowing the thermal power to be decreased and the whole management scheme to be optimized. More recently, SGN participation to French engineering studies has been extended by ANDRA to the TRU waste repository evaluation. All these works for French authorities have been performed in a close connection with several specialized departments in the CEA group, and with the help of geological specialists, under the leadership of ANDRA [fr

  1. Investigations on pretreatment of waste prior to fermentation by percolation using the ISKA {sup registered} process; Untersuchungen zur Vorbehandlung von Abfaellen vor der Vergaerung mittels Perkolation nach dem ISKA {sup registered} -Verfahren

    Energy Technology Data Exchange (ETDEWEB)

    Santen, H. [Technische Univ. Braunschweig (Germany). FG Abfallwirtschaft; Fricke, K. [Technische Univ. Braunschweig (Germany). Lehrstuhl Abfallwirtschaft; Engelhard, T.; Widmer, C. [ISKA GmbH, Ettlingen (Germany)

    2004-07-01

    Waste treatment prior to fermentation is a key aspect in achieving economic efficiency. One process is presented here in particular: percolation, in which waste is hydrolyzed aerobically, treated mechanically, and washed out with the aid of process water. The process involves a percolation stage followed by a fermentation stage. The process water burdened with organic matter is passed into a fermentation reactor in which the organic components are reacted anaerobically into biogas and bacterial mass, and the process water is recirculated into the percolation reactor. (orig.) [German] Vergaerungstechnologien zaehlen zu den etablierten Verfahren zur Gewinnung regenerativer Energien aus Biomasse. Fuer die Energieeffizienz dieser Verfahren sind die Leistung der Vergaerungsstufe, die Hoehe der Verfuegbarkeit der anaerob abzubauenden organischen Substanzen und der spezifische Energiebedarf des Behandlungsverfahrens massgeblich. Eine Schluesselstellung fuer die Optimierung beider Faktoren nimmt die Abfallaufbereitung vor der Vergaerung ein. Eine Technoloie zur Aufbereitung vor der Vergaerung basiert auf dem Verfahren der Perkolation, in der der Abfall aerob hydrolysiert,mechanisch aufgeschlossen und durch Zugabe von Prozesswasser ausgewaschen wird. Das Verfahren besteht aus einer Aufbereitung - der Perkolation - sowie einer nachgeschalteten Vergaerung. Das mit vergaerbarer Organik beladene Prozesswasser wird einem Vergaerungsreaktor zugefuehrt, in dem die organischen Komponenten anaerob zu Biogas und Bakterienmasse umgesetzt werden. Das aufbereitete Prozesswasser wird anschliessend wieder dem Perkolationsreaktor zugefuehrt. (orig.)

  2. FINAL REPORT INTEGRATED DM1200 MELTER TESTING OF REDOX EFFECTS USING HLW AZ-101 AND C-106/AY-102 SIMULANTS VSL-04R4800-1 REV 0 5/6/

    Energy Technology Data Exchange (ETDEWEB)

    KRUGER AA; MATLACK KS; GONG W; BARDAKCI T; D' ANGELO NA; LUTZE W; BIZOT PM; CALLOW RA; BRANDYS M; KOT WK; PEGG IL

    2011-12-29

    This report documents melter and off-gas performance results obtained on the DM1200 HLW Pilot Melter during processing of AZ-101 and C-106/AY-102 HLW simulants. The tests reported herein are a subset of three tests from a larger series of tests described in the Test Plan for the work; results from the remaining tests will be reported separately. Three nine day tests, one with AZ-101 and two with C-106/AY-102 feeds were conducted with variable amounts of added sugar to address the effects of redox. The test with AZ-101 included ruthenium spikes to also address the effects of redox on ruthenium volatility. One of tests addressed the effects of increased flow-sheet nitrate levels using C-106/AY-102 feeds. With high nitrate/nitrite feeds (such as WTP LAW feeds), reductants are required to prevent melt foaming and deleterious effects on glass production rates. Sugar is the baseline WTP reductant for this purpose. WTP HLW feeds typically have relatively low nitrate/nitrite content in comparison to the organic carbon content and, therefore, have typically not required sugar additions. However, HLW feed variability, particularly with respect to nitrate levels, may necessitate the use of sugar in some instances. The tests reported here investigate the effects of variable sugar additions to the melter feed as well as elevated nitrate levels in the waste. Variables held constant to the extent possible included melt temperature, bubbling rate, plenum temperature, cold cap coverage, the waste simulant composition, and the target glass composition. The principal objectives of the DM1200 melter testing were to determine the achievable glass production rates for simulated HLW feeds with variable amounts of added sugar and increased nitrate levels; characterize melter off-gas emissions; characterize the performance of the prototypical off-gas system components as well as their integrated performance; characterize the feed, glass product, and off-gas effluents; and perform pre- and

  3. Final Report Integrated DM1200 Melter Testing Of Redox Effects Using HLW AZ-101 And C-106/AY-102 Simulants VSL-04R4800-1, Rev. 0, 5/6/04

    International Nuclear Information System (INIS)

    Kruger, A.A.; Matlack, K.S.; Gong, W.; Bardakci, T.; D'Angelo, N.A.; Lutze, W.; Bizot, P.M.; Callow, R.A.; Brandys, M.; Kot, W.K.; Pegg, I.L.

    2011-01-01

    This report documents melter and off-gas performance results obtained on the DM1200 HLW Pilot Melter during processing of AZ-101 and C-106/AY-102 HLW simulants. The tests reported herein are a subset of three tests from a larger series of tests described in the Test Plan for the work; results from the remaining tests will be reported separately. Three nine day tests, one with AZ-101 and two with C-106/AY-102 feeds were conducted with variable amounts of added sugar to address the effects of redox. The test with AZ-101 included ruthenium spikes to also address the effects of redox on ruthenium volatility. One of tests addressed the effects of increased flow-sheet nitrate levels using C-106/AY-102 feeds. With high nitrate/nitrite feeds (such as WTP LAW feeds), reductants are required to prevent melt foaming and deleterious effects on glass production rates. Sugar is the baseline WTP reductant for this purpose. WTP HLW feeds typically have relatively low nitrate/nitrite content in comparison to the organic carbon content and, therefore, have typically not required sugar additions. However, HLW feed variability, particularly with respect to nitrate levels, may necessitate the use of sugar in some instances. The tests reported here investigate the effects of variable sugar additions to the melter feed as well as elevated nitrate levels in the waste. Variables held constant to the extent possible included melt temperature, bubbling rate, plenum temperature, cold cap coverage, the waste simulant composition, and the target glass composition. The principal objectives of the DM1200 melter testing were to determine the achievable glass production rates for simulated HLW feeds with variable amounts of added sugar and increased nitrate levels; characterize melter off-gas emissions; characterize the performance of the prototypical off-gas system components as well as their integrated performance; characterize the feed, glass product, and off-gas effluents; and perform pre- and

  4. Contribution of the European Commission to a European Strategy for HLW Management through Partitioning and Transmutation: Presentation of MYRRHA and its Role in the European P and T Strategy

    International Nuclear Information System (INIS)

    Abderrahim, H.A.; Van den Eynde, G.; Baeten, P.; Schyns, M.; Vandeplassche, D.; Kochetkov, A.

    2015-01-01

    To be able to answer the world's increasing demand for energy, nuclear energy must be part of the energy mix. As a consequence of the nuclear electricity generation, high-level nuclear waste (HLW) is produced. The HLW is presently considered to be managed through its burying in geological storage. Partitioning and transmutation (P and T) has been pointed out as the strategy to reduce the radiological impact of HLW. Transmutation can be achieved in an efficient way in fast neutron spectrum facilities, both in critical fast reactors as well as in accelerator driven systems (ADSs). For more than two decades, the European Commission has been co-funding various research and development projects conducted in many European research organisations and industries related to P and T as a complementary strategy for high-level waste management to the geological disposal. In 2005, a European strategy for the implementation of P and T for a large part of the HLW in Europe indicated the need for the demonstration of its feasibility at an 'engineering' level. The R and D activities of this strategy were arranged in four 'building blocks': 1. Demonstration of the capability to process a sizable amount of spent fuel from commercial light water reactors (LWRs) in order to separate plutonium, uranium and minor actinides. 2. Demonstration of the capability to fabricate at a semi-industrial level the dedicated fuel needed as load in a dedicated transmuter. 3. Design and construction of one or more dedicated transmuters. 4. Provision of a specific installation for processing of the dedicated fuel unloaded from the transmuter, which can be of a different type than the one used to process the original spent fuel unloaded from the commercial power plants, together with the fabrication of new dedicated fuel. MYRRHA contributes to the third building block. MYRRHA is an ADS under development at SCK.CEN in collaboration with a large number of European partners. One of

  5. Secondary Waste Cast Stone Waste Form Qualification Testing Plan

    Energy Technology Data Exchange (ETDEWEB)

    Westsik, Joseph H.; Serne, R. Jeffrey

    2012-09-26

    The Hanford Tank Waste Treatment and Immobilization Plant (WTP) is being constructed to treat the 56 million gallons of radioactive waste stored in 177 underground tanks at the Hanford Site. The WTP includes a pretreatment facility to separate the wastes into high-level waste (HLW) and low-activity waste (LAW) fractions for vitrification and disposal. The LAW will be converted to glass for final disposal at the Integrated Disposal Facility (IDF). Cast Stone – a cementitious waste form, has been selected for solidification of this secondary waste stream after treatment in the ETF. The secondary-waste Cast Stone waste form must be acceptable for disposal in the IDF. This secondary waste Cast Stone waste form qualification testing plan outlines the testing of the waste form and immobilization process to demonstrate that the Cast Stone waste form can comply with the disposal requirements. Specifications for the secondary-waste Cast Stone waste form have not been established. For this testing plan, Cast Stone specifications are derived from specifications for the immobilized LAW glass in the WTP contract, the waste acceptance criteria for the IDF, and the waste acceptance criteria in the IDF Permit issued by the State of Washington. This testing plan outlines the testing needed to demonstrate that the waste form can comply with these waste form specifications and acceptance criteria. The testing program must also demonstrate that the immobilization process can be controlled to consistently provide an acceptable waste form product. This testing plan also outlines the testing needed to provide the technical basis for understanding the long-term performance of the waste form in the disposal environment. These waste form performance data are needed to support performance assessment analyses of the long-term environmental impact of the secondary-waste Cast Stone waste form in the IDF

  6. Cold-Crucible Design Parameters for Next Generation HLW Melters

    International Nuclear Information System (INIS)

    Gombert, D.; Richardson, J.; Aloy, A.; Day, D.

    2002-01-01

    The cold-crucible induction melter (CCIM) design eliminates many materials and operating constraints inherent in joule-heated melter (JHM) technology, which is the standard for vitrification of high-activity wastes worldwide. The cold-crucible design is smaller, less expensive, and generates much less waste for ultimate disposal. It should also allow a much more flexible operating envelope, which will be crucial if the heterogeneous wastes at the DOE reprocessing sites are to be vitrified. A joule-heated melter operates by passing current between water-cooled electrodes through a molten pool in a refractory-lined chamber. This design is inherently limited by susceptibility of materials to corrosion and melting. In addition, redox conditions and free metal content have exacerbated materials problems or lead to electrical short-circuiting causing failures in DOE melters. In contrast, the CCIM design is based on inductive coupling of a water-cooled high-frequency electrical coil with the glass, causing eddycurrents that produce heat and mixing. A critical difference is that inductance coupling transfers energy through a nonconductive solid layer of slag coating the metal container inside the coil, whereas the jouleheated design relies on passing current through conductive molten glass in direct contact with the metal electrodes and ceramic refractories. The frozen slag in the CCIM design protects the containment and eliminates the need for refractory, while the corrosive molten glass can be the limiting factor in the JH melter design. The CCIM design also eliminates the need for electrodes that typically limit operating temperature to below 1200 degrees C. While significant marketing claims have been made by French and Russian technology suppliers and developers, little data is available for engineering and economic evaluation of the technology, and no facilities are available in the US to support testing. A currently funded project at the Idaho National Engineering

  7. HLW vitrification in France industrial experience and glass quality

    International Nuclear Information System (INIS)

    Desvaux, J.L.; Delahaye, P.

    1994-01-01

    This paper describes the vitrification process, the technology and process improvements at the La Hague plant in R 7 and T 7 facilities. The main achievements relate to the process flexibility, the reliability of the equipment and solid waste management. The quality of the vitrified glass produced and canisters compliance with agreed specifications are demonstrated through characterization studies. Since the active start-up of R 7/T 7 facilities, canisters compliance with specifications relies upon a complete quality assurance/quality control program including process control. 1 tab., 1 fig

  8. Corrosion resistance of metal materials for HLW canister

    International Nuclear Information System (INIS)

    Furuya, Takashi; Muraoka, Susumu; Tashiro, Shingo

    1982-02-01

    In order to verify the materials as an important artificial barrier for canister of vitrified high-level waste from spent fuel reprocessing, data and reports were researched on corrosion resistance of the materials under conditions from glass form production to final disposal. Then, in this report, investigated subjects, improvement methods and future subjects are reviewed. It has become clear that there would be no problem on the inside and outside corrosion of the canister during glass production, but long term corrosion and radiation effect tests and the vitrification methods would be subjects in future on interim storage and final disposal conditions. (author)

  9. Radioactive waste management solutions

    International Nuclear Information System (INIS)

    Siemann, Michael

    2015-01-01

    One of the more frequent questions that arise when discussing nuclear energy's potential contribution to mitigating climate change concerns that of how to manage radioactive waste. Radioactive waste is produced through nuclear power generation, but also - although to a significantly lesser extent - in a variety of other sectors including medicine, agriculture, research, industry and education. The amount, type and physical form of radioactive waste varies considerably. Some forms of radioactive waste, for example, need only be stored for a relatively short period while their radioactivity naturally decays to safe levels. Others remain radioactive for hundreds or even hundreds of thousands of years. Public concerns surrounding radioactive waste are largely related to long-lived high-level radioactive waste. Countries around the world with existing nuclear programmes are developing longer-term plans for final disposal of such waste, with an international consensus developing that the geological disposal of high-level waste (HLW) is the most technically feasible and safe solution. This article provides a brief overview of the different forms of radioactive waste, examines storage and disposal solutions, and briefly explores fuel recycling and stakeholder involvement in radioactive waste management decision making

  10. Japanese Nuclear Waste Avatars

    International Nuclear Information System (INIS)

    Wynn Kirby, Peter; Stier, Daniel

    2016-01-01

    Japan's cataclysmic 2011 tsunami has become a vast, unwanted experiment in waste management. The seismic event and resulting Fukushima Daiichi radiation crisis created an awkwardly fortuitous rupture in Japanese nuclear practice that exposed the lax and problematic management of nuclear waste in this country to broader scrutiny, as well as distortions in its very conception. This article looks at the full spectrum of nuclear waste in post-tsunami Japan, from spent fuel rods to contorted reactor containment, and the ways that nuclear waste mirrors or diverges from more quotidian waste practices in Japanese culture. Significantly, the Fukushima Daiichi plant itself and its erstwhile banal surroundings have themselves transmuted into an unwieldy form of nuclear waste. The immense challenges of the Fukushima Daiichi site have stimulated a series of on-the-fly innovations that furnish perspective on more everyday nuclear waste practices in the industry. While some HLW can be reprocessed for limited use in today's reactors, it cannot be ignored that much of Japan's nuclear waste is simply converted into other forms of waste. In a society that has long been fixated on segregating filth, maintaining (imagined) purity, and managing proximity to pollution, the specter of nuclear waste looms over contemporary Japan and its ongoing debates over resources, risk, and Japanese nuclear identity itself

  11. Prediction of temperature increases in a salt repository expected from the storage of spent fuel or high-level waste

    International Nuclear Information System (INIS)

    Llewellyn, G.H.

    1978-04-01

    Comparisons in temperature increases incurred from hypothetical storage of 133 MW of 10-year-old spent fuel (SF) or high-level waste (HLW) in underground salt formations have been made using the HEATING5 computer code. The comparisons are based on far-field homogenized models that cover areas of 65 and 25 sq miles for SF and HLW, respectively, and near-field unit-cell models covering respective areas of 610 ft 2 and 400 ft 2 . Preliminary comparisons based on heat loads of 150 kW/acre and 3.5 kW/canister indicated near-field temperature increases about 20% higher for the storage of the spent fuel than for the high-level waste. In these comparisons, it was also found that the thermal energy deposited in the salt after 500 years is about twice the energy deposited by the high-level waste. The thermal load in a repository containing 10-year-old spent fuel was thus limited to 60 kW/acre to obtain comparable far-field thermal effects as obtained in a repository containing 10-year-old high-level waste loaded at 150 kW/acre. Detailed far-field and unit-cell comparisons of transient temperature increases have been made based on these loadings. Unit-cell comparisons were made between a canister containing high-level waste with an initial heat production rate of 2.1 kW and a canister containing a PWR spent fuel assembly producing 0.55 kW. Using a three-dimensional unit-cell model, a maximum salt temperature increase of 260 0 F was calculated for the high-level waste prior to back-filling (5 years after burial), whereas a maximum temperature increase of 110 0 F was calculated for the spent fuel prior to backfilling (25 years after burial). Comparisons were also made between various configurational models for the high-level waste showing the applicability of each model

  12. Distributions of 14 elements on 63 absorbers from three simulant solutions (acid-dissolved sludge, acidified supernate, and alkaline supernate) for Hanford HLW Tank 102-SY

    International Nuclear Information System (INIS)

    Marsh, S.F.; Svitra, Z.V.; Bowen, S.M.

    1994-08-01

    As part of the Hanford Tank Waste Remediation System program at Los Alamos, we evaluated 63 commercially available or experimental absorber materials for their ability to remove hazardous components from high-level waste (HLW). These absorbers included cation and anion exchange resins, inorganic exchangers, composite absorbers, and a series of liquid extractants sorbed on porous support-beads. We tested these absorbers with three solutions prepared to simulate acid-dissolved sludge (pH 0.6), acidified supernate (pH 3.5), and alkaline supernate (pH 13.9) from underground storage tank 102-SY at the Hanford Reservation near Richland, Washington. To these simulants we added the appropriate radionuclides and used gamma spectrometry to measure fission products (Ce, Cs, Sr, Tc, and Y), actinides (U, Pu, and Am), and matrix elements (Cr, Co, Fe, Mn, Zn, and Zr). For each of more than 2500 element/absorber/solution combinations, we measured distribution coefficients for dynamic contact periods of 30 min, 2 h, and 6 h to obtain information about sorption kinetics. Because we measured the sorption of many different elements, the tabulated results indicate those elements most likely to interfere with the sorption of elements of greater interest. On the basis of nearly 7500 measured distribution coefficients, we determined that many of these absorbers appear suitable for processing HLW. This study supersedes the previous version of LA-12654, in which results attributed to a solution identified as an alkaline supernate simulant were misleading because that solution contained insufficient hydroxide

  13. Effects of beta/gamma radiation on nuclear waste glasses

    Energy Technology Data Exchange (ETDEWEB)

    Weber, W.J. [Pacific Northwest National Lab., Richland, WA (United States)

    1997-07-01

    A key challenge in the disposal of high-level nuclear waste (HLW) in glass waste forms is the development of models of long-term performance based on sound scientific understanding of relevant phenomena. Beta decay of fission products is one source of radiation that can impact the performance of HLW glasses through the interactions of the emitted {beta}-particles and g-rays with the atoms in the glass by ionization processes. Fused silica, alkali silicate glasses, alkali borosilicate glasses, and nuclear waste glasses are all susceptible to radiation effects from ionization. In simple glasses, defects (e.g., non-bridging oxygen and interstitial molecular oxygen) are observed experimentally. In more complex glasses, including nuclear waste glasses, similar defects are expected, and changes in microstructure, such as the formation of bubbles, have been reported. The current state of knowledge regarding the effects of {beta}/{gamma} radiation on the properties and microstructure of nuclear waste glasses are reviewed. (author)

  14. Does the choice of reactor affect public acceptance of wastes?

    International Nuclear Information System (INIS)

    Inhaber, H.

    1993-01-01

    A prime goal of this conference is to suggest future reactor types that would produce greater public acceptability. Presumably the wastes generated by these cycles would, because of lesser amounts or activities, engender fewer disputes over policy than in the past. However, the world-wide arguments over low-level wastes (LLW) suggest this intent is not likely to be achieved. While the activity of these wastes is a tiny fraction of high-level wastes (HLW), the controversies over the former, in Korea, the US and elsewhere, have been as great as for the latter. There is no linear relationship between activity and political desirability. What is needed is a new approach to disposing of and siting all nuclear wastes: LLW, mixed and HLW

  15. Effects of beta/gamma radiation on nuclear waste glasses

    International Nuclear Information System (INIS)

    Weber, W.J.

    1997-01-01

    A key challenge in the disposal of high-level nuclear waste (HLW) in glass waste forms is the development of models of long-term performance based on sound scientific understanding of relevant phenomena. Beta decay of fission products is one source of radiation that can impact the performance of HLW glasses through the interactions of the emitted β-particles and g-rays with the atoms in the glass by ionization processes. Fused silica, alkali silicate glasses, alkali borosilicate glasses, and nuclear waste glasses are all susceptible to radiation effects from ionization. In simple glasses, defects (e.g., non-bridging oxygen and interstitial molecular oxygen) are observed experimentally. In more complex glasses, including nuclear waste glasses, similar defects are expected, and changes in microstructure, such as the formation of bubbles, have been reported. The current state of knowledge regarding the effects of β/γ radiation on the properties and microstructure of nuclear waste glasses are reviewed. (author)

  16. Experimental programme to demonstrate the viability of the supercontainer concept for HLW

    International Nuclear Information System (INIS)

    Van Humbeeck, Hughes; De Bock, Chris; Bastiaens, Wim; Van Cotthem, Alain

    2008-01-01

    The EIG EURIDICE (a joint venture between the Belgian Organisation for Radioactive Waste Management - ONDRAF/NIRAS - and the Belgian Nuclear Research Centre - SCKoCEN) is responsible for performing large-scale tests, technical demonstrations and experiments to assess the feasibility of a final disposal of vitrified radioactive waste in deep clay layers. This is part of the Belgian Research and Development programme managed by ONDRAF/NIRAS. The current Belgian reference design for vitrified HLW and spent fuel assemblies is the so-called Supercontainer design. The vitrified waste canisters or spent fuel assemblies are enclosed in a carbon steel overpack which has to prevent contact between water from the host formation and the waste during the thermal phase. In order to maintain favourable chemical conditions to avoid corrosion during this period (several hundred or even thousand of years), the overpack is surrounded by a high alkaline concrete buffer of about 70 cm thick. The buffer also provides permanent radiological shielding for the workers, simplifying handling and other operations. All the components of the Supercontainer are constructed in above ground installations, thus creating favourable QA/QC conditions. After the emplacement of the Supercontainers in the disposal galleries, the remaining space will be backfilled. Tests to demonstrate the viability and the construction feasibility of the supercontainer design have been initiated. The viability programme includes Tests to verify the feasibility to construct and emplace the components of the supercontainers, and tests to verify the feasibility to backfill the disposal galleries once the supercontainers are placed. Supercontainer construction: Tests in column to verify the construction feasibility (risk of cracking) of the buffer with two different types of concrete (a self-compacting concrete - SCC - and a rheoplastic concrete RPC) were performed in collaboration with the Belgian concrete factory Socea. A

  17. High-level waste program integration within the DOE complex

    International Nuclear Information System (INIS)

    Valentine, J.H.; Malone, K.; Schaus, P.S.

    1998-03-01

    Eleven major Department of Energy (DOE) site contractors were chartered by the Assistant Secretary to use a systems engineering approach to develop and evaluate technically defensible cost savings opportunities across the complex. Known as the complex-wide Environmental Management Integration (EMI), this process evaluated all the major DOE waste streams including high level waste (HLW). Across the DOE complex, this waste stream has the highest life cycle cost and is scheduled to take until at least 2035 before all HLW is processed for disposal. Technical contract experts from the four DOE sites that manage high level waste participated in the integration analysis: Hanford, Savannah River Site (SRS), Idaho National Engineering and Environmental Laboratory (INEEL), and West Valley Demonstration Project (WVDP). In addition, subject matter experts from the Yucca Mountain Project and the Tanks Focus Area participated in the analysis. Also, departmental representatives from the US Department of Energy Headquarters (DOE-HQ) monitored the analysis and results. Workouts were held throughout the year to develop recommendations to achieve a complex-wide integrated program. From this effort, the HLW Environmental Management (EM) Team identified a set of programmatic and technical opportunities that could result in potential cost savings and avoidance in excess of $18 billion and an accelerated completion of the HLW mission by seven years. The cost savings, schedule improvements, and volume reduction are attributed to a multifaceted HLW treatment disposal strategy which involves waste pretreatment, standardized waste matrices, risk-based retrieval, early development and deployment of a shipping system for glass canisters, and reasonable, low cost tank closure

  18. Evaluation of methods and tools to develop safety concepts and to demonstrate safety for an HLW repository in salt. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Bollingerfehr, W.; Buhmann, D.; Doerr, S.; and others

    2017-03-15

    Salt formations have been the preferred option as host rocks for the disposal of high level radioactive waste in Germany for more than 40 years. During this period comprehensive geological investigations have been carried out together with a broad spectrum of concept and safety related R and D work. The behaviour of an HLW repository in salt formations, particularly in salt domes, has been analysed in terms of assessment of the total system performance. This was first carried out for concepts of generic waste repositories in salt and, since 1998, for a repository concept with specific boundary conditions, taking the geology of the Gorleben salt dome as an example. Suitable repository concepts and designs were developed, the technical feasibility has been proven and operational and long-term safety evaluated. Numerical modelling is an important input into the development of a comprehensive safety case for a waste repository. Significant progress in the development of numerical tools and their application for long-term safe ty assessment has been made in the last two decades. An integrated approach has been used in which the repository concept and relevant scientific and engineering data are combined with the results from iterative safety assessments to increase the clarity and the traceability of the evaluation. A safety concept that takes full credit of the favourable properties of salt formations was developed in the course of the R and D project ISIBEL, which started in 2005. This concept is based on the safe containment of radioactive waste in a specific part of the host rock formation, termed the containment providing rock zone, which comprises the geological barrier, the geotechnical barriers and the compacted backfill. The future evolution of the repository system will be analysed using a catalogue of Features, Events and Processes (FEP), scenario development and numerical analysis, all of which are adapted to suit the safety concept. Key elements of the

  19. Evaluation of methods and tools to develop safety concepts and to demonstrate safety for an HLW repository in salt. Final report

    International Nuclear Information System (INIS)

    Bollingerfehr, W.; Buhmann, D.; Doerr, S.

    2017-03-01

    Salt formations have been the preferred option as host rocks for the disposal of high level radioactive waste in Germany for more than 40 years. During this period comprehensive geological investigations have been carried out together with a broad spectrum of concept and safety related R and D work. The behaviour of an HLW repository in salt formations, particularly in salt domes, has been analysed in terms of assessment of the total system performance. This was first carried out for concepts of generic waste repositories in salt and, since 1998, for a repository concept with specific boundary conditions, taking the geology of the Gorleben salt dome as an example. Suitable repository concepts and designs were developed, the technical feasibility has been proven and operational and long-term safety evaluated. Numerical modelling is an important input into the development of a comprehensive safety case for a waste repository. Significant progress in the development of numerical tools and their application for long-term safe ty assessment has been made in the last two decades. An integrated approach has been used in which the repository concept and relevant scientific and engineering data are combined with the results from iterative safety assessments to increase the clarity and the traceability of the evaluation. A safety concept that takes full credit of the favourable properties of salt formations was developed in the course of the R and D project ISIBEL, which started in 2005. This concept is based on the safe containment of radioactive waste in a specific part of the host rock formation, termed the containment providing rock zone, which comprises the geological barrier, the geotechnical barriers and the compacted backfill. The future evolution of the repository system will be analysed using a catalogue of Features, Events and Processes (FEP), scenario development and numerical analysis, all of which are adapted to suit the safety concept. Key elements of the

  20. Superconducting Open-Gradient Magnetic Separation for the Pretreatment of Radioactive or Mixed Waste Vitrification Feeds

    International Nuclear Information System (INIS)

    Nunez', L.; Kaminsky', M.D.; Crawford, C.; Ritter, J.A.

    1999-01-01

    An open-gradient magnetic separation (OGMS) process is being considered to separate deleterious elements from radioactive and mixed waste streams prior to vitrification or stabilization. By physically segregating solid wastes and slurries based on the magnetic properties of the solid constituents, this potentially low-cost process may serve the U.S. Department of Energy (DOE) by reducing the large quantities of glass produced from defense-related high-level waste (HLW). Furthermore, the separation of deleterious elements from low-level waste (LLW) also can reduce the total quantity of waste produced in LLW immobilization activities. Many HLW 'and LLW waste' streams at both Hanford and the Savannah River Site (SRS) include constituents deleterious to the durability of borosilicate glass and the melter many of the constituents also possess paramagnetism. For example, Fe, Cr, Ni, and other transition metals may limit the waste loading and affect the durability of the glass by forming spine1 phases at the high operating temperature used in vitrification. Some magnetic spine1 phases observed in glass formation are magnetite (Fe,O,), chromite (FeCrO,), and others [(Fe, Ni, Mg, Zn, Mn)(Al, Fe, Ti, Cr)O,] as described elsewhere [Bates-1994, Wronkiewicz-1994] Stable spine1 phases can cause segregation between the glass and the crystalline phases. As a consequence of the difference in density, the spine1 phases tend to accumulate at the bottom of the glass melter, which decreases the conductivity and melter lifetime [Sproull-1993]. Crystallization also can affect glass durability [Jantzen-1985, Turcotte- 1979, Buechele-1990] by changing the chemical composition of the matrix glass surrounding the crystals or causing stress at the glass/crystal interface. These are some of the effects that can increase leaching [Jantzen-1985]. A SRS glass that was partially crystallized to contain 10% vol. crystals composed of spinels, nepheline, and acmite phases showed minimal changes in

  1. Application of intelligence based uncertainty analysis for HLW disposal

    International Nuclear Information System (INIS)

    Kato, Kazuyuki

    2003-01-01

    Safety assessment for geological disposal of high level radioactive waste inevitably involves factors that cannot be specified in a deterministic manner. These are namely: (1) 'variability' that arises from stochastic nature of the processes and features considered, e.g., distribution of canister corrosion times and spatial heterogeneity of a host geological formation; (2) 'ignorance' due to incomplete or imprecise knowledge of the processes and conditions expected in the future, e.g., uncertainty in the estimation of solubilities and sorption coefficients for important nuclides. In many cases, a decision in assessment, e.g., selection among model options or determination of a parameter value, is subjected to both variability and ignorance in a combined form. It is clearly important to evaluate both influences of variability and ignorance on the result of a safety assessment in a consistent manner. We developed a unified methodology to handle variability and ignorance by using probabilistic and possibilistic techniques respectively. The methodology has been applied to safety assessment of geological disposal of high level radioactive waste. Uncertainties associated with scenarios, models and parameters were defined in terms of fuzzy membership functions derived through a series of interviews to the experts while variability was formulated by means of probability density functions (pdfs) based on available data set. The exercise demonstrated applicability of the new methodology and, in particular, its advantage in quantifying uncertainties based on expert's opinion and in providing information on dependence of assessment result on the level of conservatism. In addition, it was also shown that sensitivity analysis could identify key parameters in reducing uncertainties associated with the overall assessment. The above information can be used to support the judgment process and guide the process of disposal system development in optimization of protection against

  2. Application of PCT to the EBR II ceramic waste form

    International Nuclear Information System (INIS)

    Ebert, W. L.; Lewis, M. A.; Johnson, S. G.

    2002-01-01

    We are evaluating the use of the Product Consistency Test (PCT) developed to monitor the consistency of borosilicate glass waste forms for application to the multiphase ceramic waste form (CWF) that will be used to immobilize waste salts generated during the electrometallurgical conditioning of spent sodium-bonded nuclear fuel from the Experimental Breeder Reactor No. 2 (EBR II). The CWF is a multiphase waste form comprised of about 70% sodalite, 25% borosilicate glass binder, and small amounts of halite and oxide inclusions. It must be qualified for disposal as a non-standard high-level waste (HLW) form. One of the requirements in the DOE Waste Acceptance System Requirements Document (WASRD) for HLW waste forms is that the consistency of the waste forms be monitored.[1] Use of the PCT is being considered for the CWF because of the similarities of the dissolution behaviors of both the sodalite and glass binder phases in the CWF to borosilicate HLW glasses. This paper provides (1) a summary of the approach taken in selecting a consistency test for CWF production and (2) results of tests conducted to measure the precision and sensitivity of the PCT conducted with simulated CWF

  3. Concept of grouping in partitioning of HLW for self-consistent fuel cycle

    International Nuclear Information System (INIS)

    Kitamoto, A.; Mulyanto

    1993-01-01

    A concept of grouping for partitioning of HLW has been developed in order to examine the possibility of a self-consistent fuel recycle. The concept of grouping of radionuclides is proposed herein, such as Group MA1 (MA below Cm), Group MA2 (Cm and higher MA), Group A ( 99 Tc and I), Group B (Cs and Sr) and Group R (the partitioned remain of HLW). Group B is difficult to be transmuted by neutron reaction, so a radiation application in an industrial scale should be developed in the future. Group A and Group MA1 can be burned by a thermal reactor, on the other hand Group MA2 should be burned by a fast reactor. P-T treatment can be optimized for the in-core and out-core system, respectively

  4. Study on the properties of Gaomiaozi bentonite as the buffer/backfilling materials for HLW disposal

    International Nuclear Information System (INIS)

    Liu Xiaodong; Luo Taian; Zhu Guoping; Chen Qingchun

    2007-12-01

    Systematic studies including mineral composition and structure, physico- chemical properties and thermal properties have been conducted on Gaomiaozi bentonite, Xinghe County, Inner Mongolia Autonomous Region. The compaction characteristics of bentonite and the influence of additive to bentonite have been discussed. The analysis of mineral composition and structure show that the bentonite ores are dominated by montmorillonite. Preliminary studies of the characteristics of ores indicated that No-type bentonite from the deposit has good absorption, excellent swelling and high cation exchangeability. The compressibility of bentonite will be improved by adding the additives such as quartz sand. The studies indicated that the characteristics of Gaomiaozi bentonite can satisfy the requirement of buffer/backfilling materials for HLW repository and the ores can be selected as the preferential candidate to provide buffer/backfill- ing materials for HLW repository in China. (authors)

  5. The interpretation of remote sensing image on the stability of fault zone at HLW repository site

    International Nuclear Information System (INIS)

    Liu Linqing; Yu Yunxiang

    1994-01-01

    It is attempted to interpret the buried fault at the preselected HLW repository site in western Gansu province with a remote sensing image. The authors discuss the features of neotectonism of Shule River buried fault zone and its two sides in light of the remote sensing image, geomorphology, stream pattern, type and thickness difference of Quaternary sediments, and structural basin, etc.. The stability of Shule River fault zone is mainly dominated by the neotectonic movement pattern and strength of its two sides. Although there exist normal and differential vertical movements along it, their strengths are small. Therefore, this is a weakly-active passive fault zone. The east Beishan area north to Shule River fault zone is weakliest active and is considered as the target for further pre-selection for HLW repository site

  6. Study on the properties of Gaomiaozi bentonite as the buffer/backfilling materials for HLW disposal

    Energy Technology Data Exchange (ETDEWEB)

    Xiaodong, Liu [East China Inst. of Technology, Fuzhou (China); [Key Laboratory of Nuclear Resources and Environment of Ministry of Education, Fuzhou (China); Taian, Luo; Guoping, Zhu; Qingchun, Chen [East China Inst. of Technology, Fuzhou (China)

    2007-12-15

    Systematic studies including mineral composition and structure, physico- chemical properties and thermal properties have been conducted on Gaomiaozi bentonite, Xinghe County, Inner Mongolia Autonomous Region. The compaction characteristics of bentonite and the influence of additive to bentonite have been discussed. The analysis of mineral composition and structure show that the bentonite ores are dominated by montmorillonite. Preliminary studies of the characteristics of ores indicated that No-type bentonite from the deposit has good absorption, excellent swelling and high cation exchangeability. The compressibility of bentonite will be improved by adding the additives such as quartz sand. The studies indicated that the characteristics of Gaomiaozi bentonite can satisfy the requirement of buffer/backfilling materials for HLW repository and the ores can be selected as the preferential candidate to provide buffer/backfill- ing materials for HLW repository in China. (authors)

  7. 10 years of transport of vitrified High Level Waste (HLW) from COGEMA La Hague

    International Nuclear Information System (INIS)

    Lancelot, J.; Martinotti, B.; Tourneux, F.

    2004-01-01

    COGEMA has been using, for decades, its large experience of Reprocessing in both Gas Cooled reactors (GCR) and LWR fuels with the following facilities: Marcoule UP1 plant started up in late 50's: La Hague UP2 plant started up in 1966 first with GCR fuels and from 1976 with LWR Fuel (including foreign fuels): La Hague UP3 plant started up in 1990 Foreign Utilities signed Reprocessing Contracts with COGEMA from 1970's, providing returns of residues to the country of origin where they will be managed in a safe storage facility. Therefore, for nearly 30 years Spent Fuel coming from Japan, Germany, Belgium, Switzerland and the Netherlands are processed on La Hague site

  8. River Protection Project (RPP) Immobilized High-Level Waste (HLW) Interim Storage Plan

    International Nuclear Information System (INIS)

    BRIGGS, M.G.

    2000-01-01

    This document replaces HNF-1751, Revision 1. It incorporates updates to reflect changes in programmatic direction associated with the vitrification plant contract and associated DOE-ORP guidance. In addition it includes planning associated with failed/used melter and sample handling and disposition work scope. The document also includes format modifications and section numbering update consistent with CH2M HILL Hanford Group, Inc. procedures

  9. Pyrochemical processing of Idaho Chemical Processing Plant (ICPP) High Level Waste (HLW) calcine

    International Nuclear Information System (INIS)

    Bronson, M.C.; Ebbinghaus, B.B.; Riley, D.C.; Nelson, L.; Del Debbio, J.

    1994-01-01

    Inertial force damping control by micromanipulator modulation is proposed to suppress the vibrations of a micro/macro-manipulator system. The proposed controller, developed using classical control theory, is added to the existing control system. The proposed controller uses real-time measurements of macro-manipulator flexibility to adjust the motion of the micro manipulator to counteract structural vibrations. Experimental studies using an existing micro/macro flexible link manipulator testbed demonstrate the effectiveness of the proposed approach to suppression of vibrations in the macro/micro-manipulator system using micromanipulator-based inertial active damping control

  10. Summary of investigations carried out prior to 19 October 1984 regarding the location of the Vaalputs radioactive waste disposal site for the burial of intermediate and low-level waste

    International Nuclear Information System (INIS)

    Hambleton-Jones, B.B.

    1984-10-01

    A recommendation by a specialist study group that the State set in motion a program to locate a suitable site or sites for the storage/disposal of radioactive waste in South Africa was accepted in 1978. A site-selection program was therefore duly initiated and in February 1983 culminated in the purchase of three farms, Garing, Geelpan and Stofkloof, some 100 km south-southeast of the town of Springbok in the northwestern Cape. The site, known as Vaalputs, is about 10 000 ha in extent. Detailed geological, geophysical, geohydrological, geobotanical, geomorphological and environmental investigations have been completed, with emphasis on the Geelpan Block, previously recommended as being the most suitable area for a disposal site. The final site of 0,5 X 0,7 km has now been selected

  11. Multipurpose optimization models for high level waste vitrification

    International Nuclear Information System (INIS)

    Hoza, M.

    1994-08-01

    Optimal Waste Loading (OWL) models have been developed as multipurpose tools for high-level waste studies for the Tank Waste Remediation Program at Hanford. Using nonlinear programming techniques, these models maximize the waste loading of the vitrified waste and optimize the glass formers composition such that the glass produced has the appropriate properties within the melter, and the resultant vitrified waste form meets the requirements for disposal. The OWL model can be used for a single waste stream or for blended streams. The models can determine optimal continuous blends or optimal discrete blends of a number of different wastes. The OWL models have been used to identify the most restrictive constraints, to evaluate prospective waste pretreatment methods, to formulate and evaluate blending strategies, and to determine the impacts of variability in the wastes. The OWL models will be used to aid in the design of frits and the maximize the waste in the glass for High-Level Waste (HLW) vitrification

  12. Researches on tectonic uplift and denudation with relation to geological disposal of HLW in Japan

    International Nuclear Information System (INIS)

    Fujiwara, Osamu; Sanga, Tomoji; Moriya, Toshifumi

    2005-01-01

    This paper reviews the present state of researches on tectonic uplift and denudation, and shows perspective goals and direction of future researches from the viewpoint of geological disposal of HLW in Japan. Detailed history of tectonics and denudation in geologic time scale, including the rates, temporal and spatial distributions and processes, reconstructed from geologic and geomorphologic evidences will enable us to make the geological predictions. Improvements of the analytic methods for the geological histories, e.g. identification of the tectonic and denudational imprints and age determinations, are indispensable for the accurate prediction. Developments of the tools and methodologies for assessments of the degree and extension of influences by the tectonic uplift, subsidence and denudation on the geological environments such as ground water flows are also fundamental problem in the study field of the geological disposal of HLW. Collaboration of scientific researches using the geological and geomorphological methods and applied technology, such as numerical simulations of ground water flows, is important in improving the safety and accuracy of the geological disposal of HLW. (author)

  13. Sealing of rock fractures around HLW repositories, 2

    International Nuclear Information System (INIS)

    Chigira, Masahiro

    1993-01-01

    During the flow of a silica-saturated hydrothermal solution in rock with negative temperature gradients, the behavior of silica in such solution is controlled by temperature, temperature gradient, pH, flow velocity, and solid surface area/fluid mass ratio (A/M). Such behavior could not be analysed precisely and totally at present state, but 'threshold conditions' have been found experimentally, under which solution keeps in equilibrium with solid silica in a flow field with temperature gradients. Solution keeps in equilibrium with solid silica under the conditions of A/M ratios more than 700 m 2 /kg, temperatures 80 - 120degC, temperature gradients less than 50degC/m, and pH 6 - 9, if mean pore velocities are less than 100 m/y. Under the same A/M ratios, temperature gradients, and pH, mean pore velocities must be less than 5 m/y in order to keep solution in equilibrium with solid silica in a flow field with temperatures 80 - 25degC. These 'threshold conditions' are expected to be satisfied in a near field of a repository of high-level radioactive waste, which suggests that if a groundwater is once saturated with silica under a higher temperature in a near field it would flow with decreasing temperatures in equilibrium with solid silica. In this case, the precipitation rate of amorphous silica along the flow path can be estimated without kinetic consideration. (author) 54 refs

  14. Defense Waste Processing Facility (DWPF) Viscosity Model: Revisions for Processing High TiO2 Containing Glasses

    Energy Technology Data Exchange (ETDEWEB)

    Jantzen, C. M. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Edwards, T. B. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2016-08-30

    Radioactive high-level waste (HLW) at the Savannah River Site (SRS) has successfully been vitrified into borosilicate glass in the Defense Waste Processing Facility (DWPF) since 1996. Vitrification requires stringent product/process (P/P) constraints since the glass cannot be reworked once it is poured into ten foot tall by two foot diameter canisters. A unique “feed forward” statistical process control (SPC) was developed for this control rather than statistical quality control (SQC). In SPC, the feed composition to the DWPF melter is controlled prior to vitrification. In SQC, the glass product would be sampled after it is vitrified. Individual glass property-composition models form the basis for the “feed forward” SPC. The models transform constraints on the melt and glass properties into constraints on the feed composition going to the melter in order to guarantee, at the 95% confidence level, that the feed will be processable and that the durability of the resulting waste form will be acceptable to a geologic repository. The DWPF SPC system is known as the Product Composition Control System (PCCS). The DWPF will soon be receiving wastes from the Salt Waste Processing Facility (SWPF) containing increased concentrations of TiO2, Na2O, and Cs2O . The SWPF is being built to pretreat the high-curie fraction of the salt waste to be removed from the HLW tanks in the F- and H-Area Tank Farms at the SRS. In order to process TiO2 concentrations >2.0 wt% in the DWPF, new viscosity data were developed over the range of 1.90 to 6.09 wt% TiO2 and evaluated against the 2005 viscosity model. An alternate viscosity model is also derived for potential future use, should the DWPF ever need to process other titanate-containing ion exchange materials. The ultimate limit on the amount of TiO2 that can be accommodated from SWPF will be determined by the three PCCS models, the waste composition of a given sludge

  15. Development of the high-level waste high-temperature melter feed preparation flowsheet for vitrification process testing

    International Nuclear Information System (INIS)

    Seymour, R.G.

    1995-01-01

    High-level waste (HLW) feed preparation flowsheet development was initiated in fiscal year (FY) 1994 to evaluate alternative flowsheets for preparing melter feed for high-temperature melter (HTM) vitrification testing. Three flowsheets were proposed that might lead to increased processing capacity relative to the Hanford Waste Vitrification Plant (HWVP) and that were flexible enough to use with other HLW melter technologies. This document describes the decision path that led to the selection of flowsheets to be tested in the FY 1994 small-scale HTM tests. Feed preparation flowsheet development for the HLW HTM was based on the feed preparation flowsheet that was developed for the HWVP. This approach allowed the HLW program to build upon the extensive feed preparation flowsheet database developed under the HWVP Project. Primary adjustments to the HWVP flowsheet were to the acid adjustment and glass component additions. Developmental background regarding the individual features of the HLW feed preparation flowsheets is provided. Applicability of the HWVP flowsheet features to the new HLW vitrification mission is discussed. The proposed flowsheets were tested at the laboratory-scale at Pacific Northwest Laboratory. Based on the results of this testing and previously established criteria, a reductant-based flowsheet using glycolic acid and a nitric acid-based flowsheet were selected for the FY 1994 small-scale HTM testing

  16. Application of self-propagation high-temperature synthesis for immobilization of hard radioactive wastes in ceramet materials

    International Nuclear Information System (INIS)

    Ilyin, E.; Pashkeev, I.; Senin, A.; Gerasimova, N.

    2001-01-01

    The possibility of self-propagating high-temperature synthesis (SPHTS) application for an immobilization of solid high level wastes (HLW) in cermet materials is considered. The schemes of multilayer cermet blocks formation are offered. Such blocks consist of a ceramet core with immobilized HLW and a protective cover - ceramet without HLW. The influence of the base components form (pure Ti and Si, ferrotitanium and ferrosilicon), metallic components (Ni, Cu, Cr, Fe, ferrochromium) and nonmetallic components (SiO 2 , Al 2 O 3 , TiO 2 ) on burning rate and cover ceramet structure is investigated in compositions on a basis of Ti+B, Ti+Si, Ti+C systems. Model samples of multilayer cermet blocks are manufactured using of HLW simulators. (authors)

  17. Self-sealing of rock fractures. A possibility around the repositories of high-level radioactive wastes

    International Nuclear Information System (INIS)

    Chigira, Masahiro; Nakata, Eiji

    1995-01-01

    To the goal of the safe geological disposal of high-level radioactive wastes (HLW), we must provide long-term confidence for the isolation of HLW in various ways. In particular, groundwater flow, the most likely transport media of radioactive nuclides from HLW, must be restricted around a repository for long time. For that purpose, grouting techniques using cement, bentonite, or other materials have been studied in many countries. In this paper we report the results of a series of experiments on silica precipitation behavior in a flow path with negative temperature gradients in granite and also describe a natural example of hydrothermal alteration of diatomite intruded by andesite. Based on these, we will discuss the possibility of self-sealing around HLW repository. (J.P.N.)

  18. Waste package materials selection process

    International Nuclear Information System (INIS)

    Roy, A.K.; Fish, R.L.; McCright, R.D.

    1994-01-01

    The office of Civilian Radioactive Waste Management (OCRWM) of the United States Department of Energy (USDOE) is evaluating a site at Yucca Mountain in Southern Nevada to determine its suitability as a mined geologic disposal system (MGDS) for the disposal of high-level nuclear waste (HLW). The B ampersand W Fuel Company (BWFC), as a part of the Management and Operating (M ampersand O) team in support of the Yucca Mountain Site Characterization Project (YMP), is responsible for designing and developing the waste package for this potential repository. As part of this effort, Lawrence Livermore National Laboratory (LLNL) is responsible for testing materials and developing models for the materials to be used in the waste package. This paper is aimed at presenting the selection process for materials needed in fabricating the different components of the waste package

  19. Final Report - Glass Formulation Development and Testing for DWPF High AI2O3 HLW Sludges, VSL-10R1670-1, Rev. 0, dated 12/20/10

    Energy Technology Data Exchange (ETDEWEB)

    Kruger, Albert A.; Pegg, I. L.; Kot, W. K.; Gan, H.; Matlack, K. S.

    2013-11-13

    The principal objective of the work described in this Final Report is to develop and identify glass frit compositions for a specified DWPF high-aluminum based sludge waste stream that maximizes waste loading while maintaining high production rate for the waste composition provided by ORP/SRS. This was accomplished through a combination of crucible-scale, vertical gradient furnace, and confirmation tests on the DM100 melter system. The DM100-BL unit was selected for these tests. The DM100-BL was used for previous tests on HLW glass compositions that were used to support subsequent tests on the HLW Pilot Melter. It was also used to process compositions with waste loadings limited by aluminum, bismuth, and chromium, to investigate the volatility of cesium and technetium during the vitrification of an HLW AZ-102 composition, to process glass formulations at compositional and property extremes, and to investigate crystal settling on a composition that exhibited one percent crystals at 963{degrees}C (i.e., close to the WTP limit). The same melter was selected for the present tests in order to maintain comparisons between the previously collected data. The tests provide information on melter processing characteristics and off-gas data, including formation of secondary phases and partitioning. Specific objectives for the melter tests are as follows: Determine maximum glass production rates without bubbling for a simulated SRS Sludge Batch 19 (SB19). Demonstrate a feed rate equivalent to 1125 kg/m{sup 2}/day glass production using melt pool bubbling. Process a high waste loading glass composition with the simulated SRS SB19 waste and measure the quality of the glass product. Determine the effect of argon as a bubbling gas on waste processing and the glass product including feed processing rate, glass redox, melter emissions, etc.. Determine differences in feed processing and glass characteristics for SRS SB19 waste simulated by the co-precipitated and direct

  20. Evaluation and compilation of DOE waste package test data: Biannual report, August 1986-January 1987

    International Nuclear Information System (INIS)

    Interrante, C.; Escalante, E.; Fraker, A.; Harrison, S.; Shull, R.; Linzer, M.; Ricker, R.; Ruspi, J.

    1987-10-01

    This report summarizes results of the National Bureau of Standards (NBS) evaluations of Department of Energy (DOE) activities on waste packages designed for containment of radioactive high-level nuclear waste (HLW). The waste package is a proposed engineered barrier that is part of a permanent repository for HLW. Metal alloys are the principal barriers within the engineered system. Technical discussions are given for the corrosion of metals proposed for the canister, particularly carbon and stainless steels, and copper. In the section on tuff, the current level of understanding of several canister materials is questioned. Within the Basalt Waste Isolation Project (BWIP) section, discussions are given on problems concerning groundwater, materials for use in the metallic overpack, and diffusion through the packing. For the proposed salt site, questions are raised on the work on both ASTM A216 Steel and Ti-Code 12. NBS work related to the vitrification of HLW borosilicate glass at the West Valley Demonstration Project (WVDP) and the Defense Waste Processing Facility (DWPF) is covered. NBS reviews of selected DOE technical reports and a summary of current waste-package activities of the Materials Characterization Center (MCC) is presented. Using a database management system, a computerized database for storage and retrieval of reviews and evaluations of HLW data has been developed and is described. 17 refs., 2 figs., 2 tabs

  1. National high-level waste systems analysis

    International Nuclear Information System (INIS)

    Kristofferson, K.; O'Holleran, T.P.

    1996-01-01

    Previously, no mechanism existed that provided a systematic, interrelated view or national perspective of all high-level waste treatment and storage systems that the US Department of Energy manages. The impacts of budgetary constraints and repository availability on storage and treatment must be assessed against existing and pending negotiated milestones for their impact on the overall HLW system. This assessment can give DOE a complex-wide view of the availability of waste treatment and help project the time required to prepare HLW for disposal. Facilities, throughputs, schedules, and milestones were modeled to ascertain the treatment and storage systems resource requirements at the Hanford Site, Savannah River Site, Idaho National Engineering Laboratory, and West Valley Demonstration Project. The impacts of various treatment system availabilities on schedule and throughput were compared to repository readiness to determine the prudent application of resources. To assess the various impacts, the model was exercised against a number of plausible scenarios as discussed in this paper

  2. Experimental study of web communication about high-level radioactive waste. Analysis of the changes in attitudes of the participants in the ORCAT system

    International Nuclear Information System (INIS)

    Kimura, Hiroshi; Katsumura, Soichiro; Furuta, Kazuo; Tanaka, Hiroshi

    2009-01-01

    Risk communication about high-level radioactive waste (HLW) disposal is necessary for public acceptance of the HLW disposal program in Japan. To support risk communication, we developed the Online Risk Communication Assistant Tool (ORCAT) system on the World Wide Web (WWW). In this research, we analyzed the changes in participants' attitudes to HLW disposal through the test operation of the ORCAT system. We carried out the test operation of the ORCAT system from Oct. 29 to Dec. 12, 2005. One hundred fifty nonexpert participants, five experts, and two facilitators participated in this operation. To measure the changes in participants' attitudes to a HLW disposal program, we carried out web questionnaires before and after the test operation. Consequently, we found that most of the participants exhibited on increased level of concern about HLW as well as increased understanding regarding the necessity of HLW disposal. Nonetheless, they did not necessarily reduced their perceived risk of HLW disposal. In addition, we also found that the active participants drew conclusions based on thorough review of the information that experts posted on the ORCAT system, while the inactive participants made decisions primarily based on the context of the information presented on the ORCAT system. (author)

  3. Investigation of two-phase flow phenomena associated with corrosion in an SF/HLW repository in Opalinus Clay, Switzerland

    International Nuclear Information System (INIS)

    Senger, R.; Marschall, P.; Finsterle, S.

    2008-01-01

    Gas generation from corrosion of the waste canisters and gas accumulation in the backfilled emplacement tunnels is a key issue in the assessment of long-term radiological safety of the proposed repository for spent fuel and high-level waste (SF/HLW) sited in the Opalinus Clay formation of Northern Switzerland. Previous modeling studies indicated a significant pressure buildup in the backfilled emplacement tunnels for those sensitivity runs, where corrosion rates were high and the permeability of the Opalinus Clay was very low. As an extension to those studies, a refined process model of the canister corrosion phenomena has been developed, which accounts not only for the gas generation but also for the water consumption associated with the chemical reaction of corrosion of steel under anaerobic conditions. The simulations with the new process model indicate, that with increasing corrosion rates and decreasing host-rock permeability, pressure buildup increased, as expected. However, the simulations taking into account water consumption show that the pressure buildup is reduced compared to the simulation considering only gas generation. The pressure reduction is enhanced for lower permeability of the Opalinus Clay and for higher corrosion rates, which correspond to higher gas generations rates and higher water consumption rates. Moreover, the simulated two-phase flow patterns in the engineered barrier system (EBS) and surrounding Opalinus Clay show important differences at late time of the gas production phase as the generated gas continues to migrate outward into the surrounding host rock. For the case without water consumption, the water flow indicates overall downward flow due to a change in the overall density of the gas-fluid mixture from that based on the initially prescribed hydrostatic pressure gradient. For the case with water consumption, water flow converges toward the waste canister at a rate corresponding to the water consumption rate associated with the

  4. Review of the effective approaches for providing the R and D information on the geological disposal of HLW

    International Nuclear Information System (INIS)

    Mitsuhashi, Hiroshi; Okuhara, Hidehiko; Nanjo, Yuki

    2001-03-01

    Japan Nuclear Cycle Development Institute (JNC) had already carried out Research and development (R and D) activities for the Geological Disposal of High-level Radioactive Waste (HLW) in Japan, the information activities in order to gain a public understanding in Japan. At present, however, the information on the geological disposal project including R and D is still unpopular among the public and does not draw so much attention compared to the other current topics. To make a national consensus on the project, the effective public relational activities with the suitable approaches for the various groups/classes among the public should be done. From the viewpoint of gaining the social recognition, having the valuable interviews with the authorities, opinion leaders and other specialists, we reviewed the approaches of the effective information activities to gain the public attention and let them have proper understanding. We also had some group interviews subject to the university students and housewives, who are expected to have no concern with the geological disposal. During these interviews, we had monitored the degree of understanding on the geological disposal and JNC's R and D activities utilizing the conventional materials that JNC had already prepared, such as brochures and video tape recording, and found if the materials were helpful or not, for proper understanding. A questionnaire survey on the internet was done, as one of yardsticks for the effect of the JNC's activities. We studied the degree of understanding of the respondents, and analyzed the effect of the JNC's public relational activities. Based on the another questionnaire survey results at 'Forum on geological disposal', which was held by JNC, we also analyzed the effect of the forum as one of two-way communications tools. Following the above analysis, the effective approaches of the future public relational activities of the Geological disposal was reviewed. (author)

  5. A comparative Study between GoldSim and AMBER Based Biosphere Assessment Models for an HLW Repository

    International Nuclear Information System (INIS)

    Lee, Youn-Myoung; Hwang, Yong-Soo