Reaction of pyridine-N-oxides with halogens; Vzaimodejstvie piridin-N-oksidov s galogenami

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Kanibolotskij, A L; Mikhzajlov, V A; Savelova, V A [AN Ukrainskoj SSR, Donetsk (Ukraine). Inst. Fiziko-Organicheskoj Khimii i Uglekhimii

1994-12-31

By the methods of conductometry, NMR and IR spectroscopy it has been ascertained that interaction of pyridine-N-oxides with bromine, iodine and interhalides (ICl and IBr) gives rise to the formation of crystal complexes of 1:1 composition. The complexes mentioned are of presumably ionic structure: [RC{sub 5}H{sub 4}N-O...X...O-NC{sub 5}H{sub 4}R]{sup +}[Y-X-Y]{sup -},where X,Y = Cl,Br,I.

Proceedings of the Fourth international conference 'Interaction of radiation with solids'; Materialy chetvertoj mezhdunarodnoj konferentsii 'Vzaimodejstvie izluchenij s tverdym telom'

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Anishchik, V M [ed.; Zhukova, S I; Azarko, I I; Prikhod' ko, Zh L

2001-10-01

The 132 collected papers form the Proceedings of the International Conference 'Interaction of Radiation with Solids'. This Conference is the fourth forum biennially gathering in Minsk the specialists from different countries. The scope of the problems considered at the Conference is widening steadily from year to year including the recent results and most advanced leads in the field of radiation physics of condensed matter. In the proceedings consideration is being given to 'Processes of ion interaction with solids', 'Plasma interaction with surface' and 'Radiation effects in solids'.

Reactions of vanadium(5) with aluminium(3) in weakly acid aqueous solutions; Vzaimodejstvie mezhdu vanadiem(5) i alyhminiem(3) v slabokislykh vodnykh rastvorakh

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Ditrikh, I V; Makhno, A Ya [Donetskij Gosudarstvennyj Univ., Donetsk (Ukraine)

1997-12-31

Conditions of vanadium(5) heteropolycompounds formation in aqueous solutions containing aluminium(3) have been studied. By the methods of potentiometry and conductometry in solutions of Al(NO{sub 3}){sub 3}-NaVO{sub 3} salt mixture the formation of complexes with the ratios [Al{sup 3+}]:[V{sup 5+}]=1:3, 1:6 and 1:12 has been ascertained. A salt of gross formula 3NaO {center_dot} (Al{sub 2}){sub 3} {center_dot} 12V{sub 2}O{sub 5} {center_dot} 67H{sub 2}O has been isolated. 3 refs.; 2 figs.

Sila kojom vazduh pritiska pokretnu ploču/Force of the air pressure on a moving plate

Directory of Open Access Journals (Sweden)

Leonid Ivanovich Gretchihin

2014-10-01

Full Text Available U radu je razrađena matematički model gasodinamičkog opstrujavanja ravne ploče pri njenom kretanju sa pozitivnim i negativnim napadnim uglom. Pokazano je da pri malim brzinama kretanja, silu uzgona i čeoni otpor određuje gasodinamički tok vazduha u izlaznoj oblasti opstrujavanja, a pri brzinama kretanja koje su bliske brzini zvuka odlučujuću ulogu vrši uzajamno udarno dejstvo ploče sa molekulima okružujuće sredine u ulaznoj oblasti opstrujavanja. Otcepljena struja iza ploče se ne pojavljuje pri malim brzinama kretanja. Određeni su uslovi kada čeoni otpor i sila uzgona ploče menjaju znak. / (ruski Razrabotana matematičeskaja model' gazodinamičeskogo obtekanija ploskoj plastiny pri ee dviženii s položitel'nym i otricatel'nym uglom ataki. Pokazano, čto pri malyh skorostjah dviženija plastiny pod''emnaja sila i lobovoe soprotivlenie opredeljajutsja gazodinamikoj tečenija vozduha v tyl'noj oblasti, a pri skorostjah dviženija blizkih k skorosti zvuka rešajuščuju rol' vypolnjaet udarnoe vzaimodejstvie plastiny s molekulami okružajuščej sredy v perednej oblasti. Sryvnoe tečenie za plastinoj pri malyh skorostjah dviženija ne voznikaet. Opredeleny uslovija, kogda lobovoe soprotivlenie i pod''emnaja sila plastiny izmenjaet znak. / This paper developed a mathematical model of gas dynamic fluid flow for a flat plate during its movement with positive and negative angles of attack. It is shown that at low velocities, the lifting force and the frontal resistance are determined by gasdynamic air flow in the fluid flow exit areawhile at velocities close to the speed of sound the decisive role is played by a mutualeffect of the pplate coliding with molecules of the surrounding environment in the fluid flow incidence field. The airflow behind the plate does not appear at low velocities. The conditions when the frontal resistance and the lifting force change the sign are determined.

Interaction Between Hf Waves and Plasma in Delta-2; Interaction dans 'Delta-2' d'une Onde Progressive Electromagnetique de Haute Frequence et d'un Plasma; Vzaimodejstvie vysokochastotnoj ehlektromagnitnoj begushchej volny s plazmoj na ustanovke ''Del'ta-2'; Interaccion de una Onda Progresiva Electromagnetica de Alta Frecuencia con el Plasma en la Instalacion 'Delta-2'

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Breus, S. N.; Kurdjumov, V. N.; Levin, M. L.; Osovec, S. M.; Popova, N. Ja.; Popov, I. A.; Hodataev, K. V.; Shimchuk, V. P. [Radiotehnicheskij Institut AN SSSR, Moskva, SSSR (Russian Federation)

1966-04-15

las corrientes transversales en el plasma. Este campo tiene una estructura compleja y, posiblemente, esta determinado, como indica una teorfa aproximada, por el efecto toroidal. La existencia de los campos magneticos cuasi-estacionarios guarda al parecer una relacion con las oscilaciones del plasma que se han observado, de 200 a 500 kHz, correspondientes, aproximadamente, a las oscilaciones de Alfven en dichos campos. La presencia de campos y de corrientes cuasi-estacionarios hace que sea mas diffcil separar el plasma de las paredes de la camara de descarga y lograr la constriccion ulterior. Sin embargo, las corrientes constantes axiales, por si mismas, no pueden dar lugar a la aparicion de inestabilidades del tipo cinetico, ya que las velocidades electronicas que les corresponden son menores que la velocidad de fase de la onda progresiva, la cual es, aproximadamente, igual a 5 * 10{sup 7} cm/s, es decir, apreciablemente menor que la velocidad termica de los electrones. (author) [Russian] Izlagajutsja rezul'taty issledovanija vzaimodejstvija plotnoj plazmy s vysokochastotnym polem magnitnoj volny, begushhej vdol' toroidal'noj razrjadnoj kamery (bol'shoj diametr - 700 mm, malyj - 85 mm). Begushhaja volna vozbuzhdaetsja na chastote f = 2,4 Mgc trehfaznym avtogeneratorom moshhnost'ju okolo 50 Mvt s dlitel'nost'ju impul'sa okolo 250 i 350 mksek. Pri jeksperimentah diapazon nachal'nyh davlenij sostavljal 0,1 - 0,001 tor, a amplituda vysokochastotnogo magnitnogo polja na poverhnosti plazmy dostigala 500-600 je. V jetih uslovijah osnovnye javlenija, opredeljajushhie vzaimodejstvie plazmy s polem begushhej volny, svjazany s nalichiem nelinejnyh jeffektov i, prezhde vsego, s pojavleniem postojannoj sostavljajushhej prodol'nogo toka, kotoraja dostigala znachenij neskol'kih tysjach amper. V centre kamery v oblasti malyh polej provodimost' plazmy byla porjadka (3 - 4)*10{sup 14} CGSE, chto pri stepeni ionizacii, blizkoj k 100%, sootvetstvuet jelektronnoj temperature 8 - 12 jev. V

Interaction of phosphorus pentachloride with trichlorides of metals of the second half of lanthanide series and scandium subgroup; Vzaimodejstvie pentakhlorida fosfora s trikhloridami metallov vtoroj poloviny semejstva lantanidov i podgruppy skandiya

Energy Technology Data Exchange (ETDEWEB)

Salyulev, A B; Vovkotrub, Eh G; Strekalovskij, V N [Inst. Vysokotemperaturnoj Ehlektrokhimii UrO RAN, Ekaterinburg (Russian Federation)

1999-02-01

With the use of Raman laser spectroscopy a study is made into interactions of molten TbCl{sub 3}, ErCl{sub 3}, YbCl{sub 3}, YCl{sub 3} and ScCl{sub 3} with phosphorus pentachloride vapors at elevated pressure (up to 30-35 atm) as well as solid REM trichlorides with molten PCl{sub 5}. It is revealed for first time that the interaction can be accompanied by reactions resulting in formation of complex chloride cations [PCl{sub 4}]{sup +} and anions [MCl{sub 6}]{sup 3-} of trivalent metals. The prediction is made about the possibility of chemical interaction of phosphorus pentachloride with trichlorides of all yttrium subgroup lanthanides under similar conditions.

Beam-plasma interaction with an electron beam injecting into a symmetrically open plasma system; Electron beam relaxation. Puchkovo-plazmennoe vzaimodejstvie pri inzhektsii ehlektronnogo puchka v simmetrichno otkrytuyu plazmennuyu sistemu; Relaksatsiya ehlektronnogo puchka

Energy Technology Data Exchange (ETDEWEB)

Opanasenko, A V; Romanyuk, L I [AN Ukrainskoj SSR, Kiev (Ukrainian SSR). Inst. Yadernykh Issledovanij

1989-10-01

The relaxation of the electron beam with the electron density of 1-2 keV injected through the symmetrically open plasma system with the independent hot cathode Penning discharge is experimentally investigated. It is shown that the velocity distribution function of the electron beam changes after passing each wave generation zone induced by the beam. The contribution of different wave zones to the beam relaxation depends on the prehistory of the beam-plasma interaction and may be regulated by the selection of the plasma system parameters. By this way the complete relaxation of the electron beam can be achieved after the beam crossing the whole system.

Study of leading neutral pions: (interactions of cosmic rays with matter at energies above 3 TeV). Izuchenie lidiruyushchikh nejtral'nykh pionov (vzaimodejstvie kosmicheskikh chastits s veshchestvom pri ehnergiyakh vyshe 3 TeV)

Energy Technology Data Exchange (ETDEWEB)

Eremenko, Yu A

1988-01-01

An experimental plant consisting of a full-automatic ionized colorimeter of 44m{sup 2}, electronics of which is based on modern integral schemes and performed in CAMAC standard; of an x-ray emulsion chamber and of changeable dense target is described. The plant permits to measure the energy of a primary particle, as well as to study in detail a neutral component of products of strong indifferent target atoms. Experimental data on leading neutral mesons with energy from 10 GeV to the cosmic particle energies are analysed using the plant. A new experiment, which aim is the detection of interactions with anomalously great multiplicity and study of microstructure of extensive air showers, is suggested. 277 refs.

Interaction of zirconium and hafnium tetrachlorides with cesium, rubidium and potassium chlorides and Raman spectra of reaction products; Vzaimodejstvie tetrakhloridov tsirkoniya i gafniya s khloridami tseziya, rubidiya i kaliya i spektry KRS produktov reaktsij

Energy Technology Data Exchange (ETDEWEB)

Salyulev, A B; Vovkotrub, Eh G; Strekalovskij, V N [UrO RAN, Inst. Vysokotemperaturnoj Ehlektrokhimii, Ekaterinburg (Russian Federation)

2008-05-15

Raman spectroscopy was used to reveal the formation of novel complexes involving [Zr{sub 2}Cl{sub 9}]{sup -} and [Hf{sub 2}Cl{sub 9}]{sup -} anions in molten mixtures of ZrCl{sub 4} and HfCl{sub 4} with CsCl, RbCl, and KCl. A prediction is made about the presence of the above-mentioned complex anions in poorly investigated melts of the corresponding binary systems at high concentrations of ZrCl{sub 4} or HfCl{sub 4}.

The Possibility of Making a Quantitative Study of the Precipitin Reaction by Gamma-Radioactive Tracers; Possibilite d'une Etude Quantitative de la Reaction de Precipitation par Marquage a l'Aide d'Emetteurs Gamma; Vozmozhnost' kolichestvennogo opredeleniya reaktsii osazhdeniya s pomoshch'yu gamma-radioaktivnykh indikatorov; Estudio Cuantitativo de la Reaccion de Precipitacion con Ayuda de Indicadores Gamma

Energy Technology Data Exchange (ETDEWEB)

Bonev, L.; Todorov, S.; Robev, S. [Nauchno-Issledovatel' skij Institut Radiologii i Radiacionnoj Bezopasnosti, Sofija (Bulgaria)

1965-10-15

indicadores gamma que no reaccionan quimicamente con las moleculas de albumina. Como indicadores pueden utilizarse ciertos compuestos de cromo, manganeso y hierro que, por su teridencia a hidrolizarse, permiten fijar el indicador radiactivo en el antigeno y en el anticuerpo, respectivamente. La radiactividad de los componentes se determino con ayuda de un analizador multicanal de amplitud de impulsos. Los resultados obtenidos demuestran que la curva de precipitacion, trazada sobre la base de los datos radiometricos, concuerda con la que se obtiene por los metodos cuantitativos corrientemente empleados en la valoracion de la albumiRa. Los autores examinan las posibilidades de aplicacion del metodo descrito. (author) [Russian] Soobshhajutsja pervye rezul'taty kolichestvennogo opredelenija reakcii osazhdenija (obrazovanija kompleksa antigen-antitelo) posredstvom mechenija precipitacionnyh komponentov gamma-radioaktivnymi indikatorami, ne vstupajushhimi v himicheskoe vzaimodejstvie s belkovymi molekulami. V kachestve indikatorov mogut byt' ispol'zovany hromomargancevye soedinenija i soedinenija zheleza, sklonnost' kotoryh k gidrolizu obespechivaet fiksaciju radioaktivnogo indikatora na antigene sootvetstvenno i na antitelo. Opredelenie radioaktivnosti komponentov proizvoditsja posredstvom mnogokanal'nogo amplitudnogo analizatora. Poluchennye rezul'taty pokazyvajut, chto precipitacionnaja krivaja, postroennaja na osnovanii radiometrichnyh dannyh, nahoditsja v blizkom sootvetstvii s krivoj, postroennoj izvestnymi kolichestvennymi metodami, sluzhashhimi dlja opredelenija belka. Rassmatrivajutsja vozmozhnosti primenenija jetogo metoda na praktike. (author)

The Self-Correlation Function of Real Gases; Fonction d'Autocorrelation des Gaz Reels; 0424 0423 041d 041a 0426 0418 042f 0421 0410 041c 041e 041a 041e 0420 0420 0415 041b 042f 0426 0418 0418 0420 0415 0410 041b 042c 041d 042b 0425 0413 0410 0417 041e 0412 ; La Funcion de Autocorrelacion de los Gases Reales

Energy Technology Data Exchange (ETDEWEB)

Sigmar, D. J. [Institute for Theoretical Physics, Technical University of Vienna Vienna (Austria)

1965-06-15

autocorrelacion {gamma}{sub s}(K, t) para tiempos breves, incluido el primer termino no gaussiano. El desarrollo en racimo cesa despues del primer termino de interaccion, de forma que los resultados solo son validos para densidades bajas. Pero aun asi aparecen en cada coeficiente muchos tipos diferentes de racimos que contienen hasta siete puntos. En cuanto al potencial, se admite la hipotesis de un nucleo rigido formado por dos particulas. Como han demostrado Singwi y sus col., el comportamiento a largo plazo de {gamma}{sub s} viene determinado por la integral, respecto del tiempo, de la autocorrelacion de la velocidad; {integral}{sup {infinity}}{sub 0} {sub T}dt. Con el fin de determinar el integrando correspondiente a cualquier tiempo, se puede recurrir al desarrollo en racimo cuando t es pequefio, y aceptar la teoria de la difusion de Langevin en los casos en que t es grande. Se estan realizando calculos numericos. (author) [Russian] V formal'noj teorii neuprugogo rassejanija nejtronov funkcija samokorreljacii vyvedena v sredne-statisticheskih proizvodnyh vzaimodejstvie-potencial N-tela rasseivatelja. V dannom doklade jeti srednie znachenija opredeljajutsja dlja real'nyh gazov razlozheniem na gruppy, svjazannym s metodom Majera-Ursellja. Jeto privodit k polucheniju nekotoryh nelinejnyh tipov grupp, kotorye izuchajutsja v otnoshenii topologii graf, ih mnogokratnosti (metodami kombinatornogo analiza) i ih kvadratury. Kak predpolagaetsja v svjazi s problemoj mnogih tel, nekotorye iz grupp nerazdelimy, i ih neobhodimo integrirovat' s pomosh'ju schetno-reshajushhih mashin. Takim putem rasschityvaetsja funkcija samokorreljacii {gamma}{sub s}(K, t) dlja korotkih promezhutkov vremeni, v tom chisle i pervyj negaussovskij chlen. Razlozhenie na gruppy preryvaetsja posle pervogo chlena, vyrazhajushhego vzaimodejstvie, tak chto rezul'taty spravedlivy tol'ko dlja nizkoj plotnosti. Jeto tem ne menee privodit k samym razlichnym tipam grupp, v kotoryh soderzhitsja do

The Interaction of C{sup 14} Recoil Atoms in Binary Mixtures; Interaction entre Atomes {sup 14}C de Recul et Composants de Melanges Binaires; Vzaimodejstvie atomov otdachi ugleroda-14 v binarnykh smesyakh; Interaccion de los Atomos de Retroceso del {sup 14}C en Mezclas Binarias

Energy Technology Data Exchange (ETDEWEB)

Firsova, L. P.; Barakat, M. F.; Forys, M.; Nesmejanov, An. N. [Moskovskij Gosudarstvennyj Universitet, Moskva, SSSR (Russian Federation)

1965-04-15

A study was made of the intermolecular distribution of activity in C{sup 14} -labelled products, formed as a result of the interaction of C{sup 14} atoms with components of binary liquid mixtures containing heterocyclic compounds. Particular attention was paid to the systems indole-aniline, indole-pyridine, {alpha}-picoline-toluene, {alpha}-picolene-aniline, etc. Data were obtained on the relation between the radiochemical yields of labelled products and the concentration of components in dilute solutions and in comparable concentrations of substances in mixtures. Analysis of the experimental results for an additive system enabled us to determine the deviations from the additivity principle. The deviations observed were interpreted as the result of the participation of the second component of the system in the primary and secondary reactions accompanying nuclear transformations. In considering the role of the second component, we took into account the variations in its predominant reaction mechanisms in various concentration ranges. Special attention was paid to the possibility of an intermolecular transfer of the energy of a radiation shield, and also of the mechanism of the corresponding processes. (author) [French] Les auteurs etudient la distribution intermoleculaire de la radioactivite dans les produits marques avec {sup 14}C qui se forment a la suite de l'interaction entre le carbone-14 et les composants de melanges liquides binaires contenant des substances heterocycliqiies. Ils examinent notamment les systemes indole-aniline, indole- pyxidine, {alpha}-picoline-toluol, {alpha}-picoline-aniline, etc. Ils ont obtenu des donnees sur la relation entre le rendement radiochimique en produits marques et la concentration des composants pour des solutions diluees et pour des melanges ou les deux substances ont des concentrations comparables. En traitant les donnees experimentales selon un schema additif, ils ont constate des ecarts par rapport a la regle d'additivite. Ces ecarts sont consideres comme resultant du fait que le deuxieme composant du systeme participe aux reactions primaires et secondaires qui accompagnent les transformations nucleaires. En examinant le role du deuxieme composant, les auteurs tiennent compte des particularites que presentent les mecanismes dominants des reactions subies par ce composant dans les divers intervalles de concentration. Ils etudient notamment la possibilite.d'un transfert d'energie intermoleculaire, ainsi que les mecanismes des processus correspondants. (author) [Spanish] Los autores han investigado la distribucion intermolecular de la actividad en los productos marcados con {sup 14}C, formados como resultado de la interaccion de atomos de {sup 14}C con los componentes de mezclas binarias en estado liquido que contienen compuestos heterociclicos. Prestaron particular atencion a los sistemas indol-anilina, indol-piridina, {alpha}-picolina-tolueno, {alpha}-picolina-anilina, etc. Obtuvieron datos sobre los rendimientos radioquimicos de los productos marcados en funcion de la concentracion de los componentes en soluciones diluidas y en mezclas con concentraciones comparables de sustancias. El analisis de los resultados experimentales correspondientes a un sistema de adicion, permitio a los autores determinar las desviaciones con respecto a la normal. Estas desviaciones se consideraron como resultado de la participacion de un segundo componente del sistema en las reacciones primarias y secundarias que acompanan a las transformaciones nucleares. Al examinar el papel desempenado por el segundo componente, tuvieron en cuenta la variacion de los mecanismos de reaccion predominantes en distintos intervalos de concentracion. Examinaron en particular la posibilidad de una transferencia intermolecular de la energfa de resistencia a la radiolisis, asi como los mecanismos de los procesos correspondientes. (author) [Russian] Issledovano mezhmolekuljarnoe raspredelenie aktivnosti v mechennyhpo C{sup 14} produktah, obrazujushhihsja v rezul'tate vzaimodejstvija atomov ugleroda-14 s komponentami binarnyh zhidkih smesej, soderzhashhih geterociklicheskie soedinenija. V chastnosti, izucheny sistemy indol- anilin, indol- piridin, {alpha}-pikolin -toluol, {alpha}-pikolin-anilin i t.d. Polucheny dannye po zavisimosti radiohimicheskih vyhodov mechenyh produktov ot koncentracii komponentov v oblasti razbavlennyh rastvorov i v oblasti sravnimyh koncentracij veshhestv v smesjah. Pri obrabotke jeksperimental'nyh rezul'tatov po additivnoj sheme bshsh zafiksirovany otklonenija ot pravila additivnosti. Nabljudavshiesja otklonenija traktujutsja kak rezul'tat uchastija vtorogo komponenta sistemy v pervichnyh i vtorichnyh reakcijah soprovozhdajushhih jadernye prevrashhenija. Pri obsuzhdenii roli vtorogo komponenta uchityvajutsja otlichija preobladajushhih mehanizmov ego reakcij v razlichnyh koncentracionnyh intervalah. Rassmatrivajutsja v chastnosti vozmozhnost' mezhmolekuljarnoj peredachi jenergii radiacionnoj zashhity, a takzhe mehanizmy sootvetstvujushhih processov. (author)

Book of abstracts of the 3rd International conference and the 3rd International School for young scientists Interaction of hydrogen isotopes with structural materials. IHISM-07; Tezisy dokladov Tret'ej mezhdunarodnoj konferentsii i Tret'ej mezhdunarodnoj Shkoly molodykh uchenykh i spetsialistov Vzaimodejstvie izotopov vodoroda s konstruktsionnymi materialami. IHISM-07

Energy Technology Data Exchange (ETDEWEB)

NONE

2007-07-01

The book involves abstracts of presentations at the 3rd International Conference and the 3rd International School for Young Scientists Interaction of Hydrogen Isotopes with Structural Materials (IHISM-07). The activities of Russian and foreign scientific centers associated with the use of hydrogen isotopes in power engineering, national economy and basic research are considered. The presentations cover the following areas: kinetics and interaction between hydrogen isotopes and solids including effects of radiogenic helium accumulation, hydrides and hydride transformations; structural transformations and mechanical properties; equipment and research techniques.

Chemical Changes Induced by Irradiation in Meats and Meat Components; Transformations Chimiques Provoquees par les Rayonnements dans les Viandes et Leurs Constituants; Khimicheskie prevrashcheniya v myasnykh produktakh i ikh sostavnykh chastyakh pod vozdejstviem oblucheniya; Alteraciones Quimicas Producidas por Irradiacion de las Carnes y de sus Componentes

Energy Technology Data Exchange (ETDEWEB)

Merritt, C. Jr. [Pioneering Research Division, United States Army Natick Laboratories, Natick, MA (United States)

1966-11-15

'ju konservacii otrazhaetsja na vkusovyh kachestvah, vyzyvaja pojavlenie specificheskogo privkusa i zapaha. Polagajut, chto jeto ob{sup j}asnjaetsja obrazovaniem letuchih himicheskih soedinenij pri dejstvii radiacii na belki i lipidnye molekuly. Analiz letuchih soedinenij osushhestvljaetsja na gazovom hromatografe s kriogennym ohlazhdeniem do zadannoj temperatury, gde proishodit razdelenie slozhnyh smesej. Identifikacija vydelennyh komponentov provoditsja s pomoshh'ju mass-spektrometrii s bystrym skennirovaniem. Proveden ischerpyvajushhij analjz letuchih soedinenij, vydeljajushhihsja iz govjadiny, svininy, baraniny i teljatiny, kotorye byli oblucheny, a takzhe analiz letuchih soedinenij, obrazujushhihsja pri razlozhenii pod dejstviem obluchenija nekotoryh aminokislot, belkov, zhivotnogo zhira, metilovyh jefirov zhirnyh kislot i trigliceridov. Rezul'taty analizov obluchennyh komponentov mjasnyh produktov sravnivajutsja s rezul'tatami, poluchennymi pri obluchenii samogo mjasa i ego otdel'nyh frakcij, chto daet vozmozh - nost' ustanovit' rol' kazhdoj frakcii v celom. Postulirujutsja mehanizmy obrazovanija letuchih komponentov ot kazhdoj frakcii, a takzhe vzaimodejstvie promezhutochnyh produktov ot razlichnyh frakcij. (author)

Study of reactions of metals with sulphur and phosphorus compounds by pulsed temperatures; Etude des reactions entre metaux et composes du soufre et du phosphore au moyen de brusques hausses de temperature; Issledovanie reaktsii metallov s soedineniyami sery i fosfora pri regulyarnykh izmeneniyakh temperatury; Estudio de reacciones entre metales y compuestos de azufre y de fosforo empleando impulsos de temperatura

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Campbell, R B; Grunberg, L [National Engineering Laboratory, East Kilbride, Glasgow (United Kingdom)

1962-01-15

, los autores han tenido en cuenta la estructura de los materiales empleados y los procesos de difusion a los que se debe el progreso de la reaccion una vez iniciada esta. (author) [Russian] Protivoiznosnoe dejstvie sernykh i fosfornykh soedinenij, kotorye obychno dobavlyayutsya k mashinnym maslam, zavisit ot khimicheskikh reaktsij s metallicheskimi poverkhnostyami shesterenok. EHti reaktsii imeyut mesto kak pri osnovnoj temperature masel (primerno 100 Degree-Sign C), tak i pri vysokikh temperaturakh (priblizitel'no 600 Degree-Sign C) v techenie nebol'shogo promezhutka vremeni, kogda zubtsy shesterenok vstupayut vo vzai-modejstvie pod nagruzkoj. Temperaturnye izmeneniya sozdavalis' v apparate, v kotorom korotkie impul'sy ehlektrotoka ispol'zovalis' dlya nagrevaniya metallicheskikh provodov, pogruzhennykh v mineral'noe maslo, soderzhashchee v rastvore mechenye soedineniya sery-35 i fosfora-32. Zameryalas' voznikavshaya v provodakh radioaktivnost'. Stepen' reaktsii opredelyalas' kak funktsiya temperatury i vremeni. Rezul'taty reaktsii vyrazhalis' posredstvom osnovnykh zakonov kinetiki. Izucheniyu podverglis' voprosy izmeneniya skorosti reaktsii v zavisimosti ot nalichiya drugikh sostavov v rastvore. Bylo takzhe opredeleno vliyanie predvaritel'no obrazovannykh pokrytij poverkhnosti, soderzhashchikh seru, fosfor, khlor i/ili kislorod. Dlya ob{sup y}asneniya rezul'tatov raboty ispol'zuyutsya dannye o strukture materialov, a takzhe rassmatrivayutsya protsessy diffuzij tam, gde reaktsii vykhodili za svoi nachal'nye stadii. (author)

Disposal of Radioactive Wastes in Natural Salt; Elimination des Dechets Radioactifs dans le Sel Naturel; 0423 0414 ; Evacuacion de Desechos Radiactivos en Formaciones Salinas Naturales

Energy Technology Data Exchange (ETDEWEB)

Parker, F. L.; Boegly, W. J.; Bradshaw, R. L.; Empson, F. M.; Hemphill, L.; Struxness, E. G.; Tamura, T. [Health Physics Division, Oak Ridge National Laboratory, Oak Ridge, TN (United States)

1960-07-01

pueden solo estudiarse en las formaciones salinas inalteradas. En un yacimiento estratificado de sal situado en Hutchinson, Kansas, se han hecho experimentos con modelos a escala 1:5 y se estan realizando pruebas sobre el terreno a escala 1:1. (author) [Russian] Predlagaemoe ispol'zovanie polostej soljanyh zalezhej v kachestve mest dlja udalenija radioaktivnyh othodov osnovyvaetsja na: 1. Sushhestvovanii soli v techenie geologicheskih vekov, 2. Vodonepronicaemosti soli, 3. Shirokom geologicheskom rasprostranenii soli, 4. Chrezvychajno bol'shih kolichestvah imejushhejsja soli, 5. Strukturnoj prochnosti soli, 6. Sravnitel'no vysokoj teploprovodnosti soli po sravneniju s drugimi geologicheskimi obrazovanijami obshhek haraktera, 7. Vozmozhnom ispol'zovanii cennyh rasshhepljajushhihsja produktov v othodah, vvedennyh v sol', J 8. Sravnitel'no legkom sozdanii polostej v soli putem vyemki porody i eshhe bol'shej legkosti i nizkih zatratah na razrabotku v soli rastvornyh polostej, 9. Nizkoj sejsmichnosti v rajonah glavnyh soljanyh zalezhej. Zhidkie radioaktivnye othody mogut hranit'sja v polostjah, nahodjashhihsja . v zalezhah prirodnoj soli, esli strukturnye svojstva soli ne narusheny himicheskim vzaimodejstviem, davleniem, temperaturoj ili radiaciej. Analiticheskie issledovanija pokazyvajut, chto mozhno hranit' 800 gal/tonn dvuhgodichnyh othodov na 10000 MWD/T v sfere diametrom 10 futov, esli temperatura ne. prevyshaet 200 Degree-Sign po Farengejtu. Laboratornye ispytanija pokazyvajut, chto strukturnye svojstva i teploprovodnost' gornoj soli ne izmenjajutsja v znachitel'noj stepeni pod vozdejstviem vysokih doz radiacii, hotja vysokie temperatury uvelichivajut stepen' polzuchesti kak dlja obluchennyh, tak i dlja neobluchennyh obrazcov. Himicheskoe vzaimodejstvie zhidkih othodov s sol'ju daet hlor i drugie hloristye gazoobraznye soedinenija, no ih kolichestvo ne veliko. Migracija nuklidov v soli i deformacija polosti i kamery mogut byt' izucheny tol'ko v netronutoj zalezhi soli

Thermal Annealing of Paramagnetic Defects Induced by Gamma Irradiation in (NH{sub 4}){sub 2}SO{sub 4} and (ND{sub 4}){sub 2}SO{sub 4} Single Crystals: Experimental Verification of the Theory of Fletcher and Brown; Recuit Thermique des Defauts Paramagnetiques Induits par Irradiation Gamma dans des Monocristaux de (NH{sub 4}){sub 2}SO{sub 4} et (ND{sub 4}){sub 2}SO{sub 4}: Verification Experimentale de la Theorie de Fletcher et Brown; 0422 0415 0420 041c 0414 ; Regeneracion Termica de los Defectos Paramagneticos Inducidos por Irradiacion Gamma en Monocristales de (NH{sub 4}){sub 2}SO{sub 4} y (ND{sub 4}){sub 2}SO{sub 4}: Verificacion Experimental de la Teoria de Fletcher y Brown

Energy Technology Data Exchange (ETDEWEB)

Calusaru, A.; Barbur, I.; Ursu, I. [Institut de Physique Atomique, Bucarest (Romania); Universite ' Babes' , Cluj (Romania)

1965-04-15

kinetika s edinym plato, sootvetstvujushhim obshhej rekombinacii radikalov. Dlja kazhdoj izotermy predstavljaetsja vozmozhnym sostavit' sootvetstvujushhee uravnenie, ispol'zuja pri jetom funkciju oshibok, vyvedennuju Fletcherom i Braunom pri rassmotrenii modeli i rekombinacii par, vnachale korrelirovannyh, a zatem vydelennyh v sootvetstvii s processom besporjadochnogo dvizhenija. Posle ispravlenija jetoj funkcii s uchetom kojefficienta q dannaja funkcija byla privedena v sootvetstvie s opytom. Sostavnaja krivaja otzhiga ochen' horosho otrazhaet funkciju ispravlennyh oshibok. Pri primenenii fenomenologicheskogo metoda Fletchera i Brauna dlja rascheta jenergii aktivacii bylo najdeno znachenie 1,594 jev, sootvetstvujushhee pervomu radikalu v (NH{sub 4}){sub 2}SO{sub 4}. Ispol'zuja izmenenie kojefficienta diffuzii'v zavisimosti ot temperatury, dlja toj zhe jenergii aktivacii bylo ustanovleno znachenie v 1,592 jev. S pomoshh'ju metoda Vand-Primak bylo najdeno znachenie v 1,45 jev, kotoroe javljaetsja men'shim po sravneniju s dvumja predydushhimi. V zakljuchenie otmechaetsja, chto model' rekombinacii par, korrelirovannyh v sootvetstvii s processom besporjadochnogo dvizhenija, primenima v forme, privedennoj v teorii, kogda imeetsja dovol'no slaboe vzaimodejstvie mezhdu obrazovavshimisja vidami i reshetkoj; takim putem pervonachal'no korrelirovannye pary mogut byt' vydeleny. (author)

Inelastic Neutron Scattering from Doped Germanium and Silicon; Diffusion Inelastique des Neutrons dans du Germanium et du Silicium Contenant une 'Impurete'; Neuprugoe rasseyanie nejtronov na germanii i kremnii s prisadkoj; Dispersion Inelastica de Neutrones en Germanio y Silicio Deliberadamente Impurificados

Energy Technology Data Exchange (ETDEWEB)

Dolling, G. [Chalk River Nuclear Laboratories, Chalk River, ON (Canada)

1965-04-15

experimental. En los casos mas favorables, esta exactitud (relativa) alcanza al 0,5% del valor de la frecuencia, y llega hasta 2,0 Degree-Sign Inverted-Exclamation-Mark o tratandose de algunos modos opticos longitudinales en el silicio. (author) [Russian] Normal'nye formy kolebanija chistyh poluprovodnikov germanija i kremnija shiroko izuchalis' s pomoshh'ju kogerentnogo odnofononnogo rassejanija medlenny nejtronov na mono-kristallicheskih obrazcah. V dannom doklade opisyvajutsja analogichnye jeksperimenty, vypolnennye 1) s germaniem s bol'shoj prisadkoj ( Tilde-Operator 0,1%) a) mysh'jaka i '') galija, a takzhe 2) s kremniem s fosfornoj prisadkoj. V kazhdom sluchae kontrol'nye jeksperimenty provodilis' na kristallah vysokoj chistoty. Vse izmerenija vypolnjalis' na trehosnom kristallicheskom spektrometre v laboratorijah v Chok- River. Kak izvestno, postojannaja uprugosti C{sub 44} dlja germanija v znachitel'noj stepeni zavisit ot koncentracii prisadki, i pojetomu nekotorye poperechnye akusticheskie koljobanija (TA) s bol'shoj dlinoj volny izuchalis' s cel'ju vyjasnenija nalichija takih jeffektov v dispergirujushhej oblasti. Drugie TA kolebanija, chastoty kotoryh mozhno izmerjat' s vysokoj stepen'ju tochnosti, takzhe izuchalis' v oboih materialah s cel'ju vozmozhno bolee tochnoj proverki nebol'shih jeffektov, kotorye mozhno bylo by pripisat' nalichiju izbytka jelektronov ili dyrok. Osobenno tshhatel'no izuchalis' kolebanija so sledujushhimi volnovymi vektorami (aq/2{pi}, gde a -storona kubicheskoj jelementarnoj jachejki): 1) v germanii (1; 0; 0); 2) v kremnii (0.85; 0.85; 0) i (0.3; 0;0). Mozhno bylo by predpolozhit', chto takie normal'nye kolebanija projavjat neobychnye cherty v kristallah n-nogo tipa, poskol'ku dlja rassejanija jelektronov mezhdu sosednimi minimumami zon provodimosti potrebovalos' by vzaimodejstvie dlja sohranenija {sup i}mpul'sa kristalla{sup .} Rezul'taty vo vseh sluchajah byli otricatel'nymi, t.e. v predelah tochnosti jeksperimentov ne nabljudalos' nikakih

Instability and Related Macroscopic Effects in Toroidal Discharges; Instabilites et Effets Macroscopiques qui les Accompagnent dans les Decharges Toroidales; Neustojchivost' i svyazannye s nej makroskopicheskie ehffekty v toroidal'nykh razryadakh; Inestabilidad y Efectos Macroscopicos Conexos, en las Descargas Toroidales

Energy Technology Data Exchange (ETDEWEB)

Kadomcev, B. B.; Pogutse, O. P. [Institut Atomnoj Ehnergii Im. I.V. Kurchatova, Moskva, SSSR (Russian Federation)

1966-04-15

perenositsja konvekciej. Pri ochen' sil'nom magnitnom pole konvekcionnye jachejki perekryvajutsja mezhdu soboj, i makroskopicheskie potoki tepla i chastic mogut znachitel'no prevoshodit' klassicheskie potoki, opredeljaemye parnymi stolknovenijami Priuvelichenii davlenija plazmy konvekcionnye jachejki perestajut perekryvat'sja, i makroskopicheskij jeffekt ot tokovokonvektivnoj neustojchivosti stanovitsja malym. Pri eshhe bol'shem davlenii plazmy neustojchivye kolebanija stanovjatsja nepotencial'nymi i soprovozhdajutsja iskrivleniem silovyh linij, vsledstvie kotorogo proishodit perestrojka magnitnyh poverhnostej. Narjadu s tokovokonvektivnoj neustojchivost'ju v plazme nizkogo davlenija razvivaetsja drejfovaja neustojchivost', dlja kotoroj takzhe provedeno nelinejnoe rassmotrenie. Rassmotreno vzaimodejstvie drejfovyh kolebanij s konvekcionnymi jachejkami. (author)

Strain Dependence of the Frequencies and the Thermal Expansion of the Hexagonal Close-Packed Lattice; Variations, en Fonction de la Deformation, des Frequences et de la Dilatation Thermique du Reseau a Structure Hexagonale Compacte; Zavisimost' chastot i teplovogo rasshireniya geksagonal'noj reshetki s plotnoj upakovkoj ot napryazheniya; Variacion de las Frecuencias y de la Dilatacion Termica de la Red Hexagonal Compacta en Funcion de la Deformacion

Energy Technology Data Exchange (ETDEWEB)

Srinivasan, R.; Ramji Rao, R. [Physics Department, Indian Institute of Technology, Madras (India)

1965-04-15

}{sub 6} ot vysheukazannyh naprjazhenij. Byli ustanovleny verhnie i nizhnie temperaturnye predely jekvivalentnyh parametrov Grjunajzena ''{gamma}G i {gamma}'' dlja treh par znachenij tip. Ustanovleno, chto {gamma}' = {gamma}'' i chto verhnij temperaturnyj predel 7 Inverted-Question-Mark bol'she nizhnego temperaturnogo predela {gamma}' primerno v 0,3 raza. Velichina jetoj raznicy, okazyvaetsja, ne zavisit ot znachenij tip. Uchityvaja vzaimodejstvie so sledujushhim sosednim chlenom, mozhno ozhidat' umen'shenija jetoj raznicy. Jeti teoreticheskie rezul'taty sopostavljajutsja s rezul'tatami jeksperimentov s magniem. (author)