Detection of small conformational changes of proteins by small-angle scattering

International Nuclear Information System (INIS)

Durchschlag, H.; Purr, G.; Zipper, P.; Wilfing, R.

1991-01-01

In the past the technique of small-angle scattering has been a powerful tool for studying conformational changes of protein which occur, for example, upon binding with ligands. Results obtained by different authors from X-ray and neutron experiments on a variety of proteins and under various conditions have been compiled. This offers the possibility of comparing the extent of changes in the molecular parameters investigated (e.g. change of the radius of gyration). Problems encountered with the detection of small changes are discussed. As an example, conformational changes of the enzyme citrate synthase upon substrate binding (oxaloacetate) are presented. X-ray crystallography had already found distinct changes between open and closed forms of the enzyme. Small-angle X-ray scattering studies registered slight changes of some parameters in solution. These changes could be paralleled with the results of other solution techniques (UV absorption, fluorescence and circular dichroism spectroscopy, analytical ultracentrifugation). The results found for citrate synthase are also compared with previous findings for malate synthase, an enzyme of similar enzymatic function. Above all, this study shows that care has to be taken when studying small conformational changes. It is absolutely necessary to use different methods and conditions and to study the problem from different points of view to avoid pitfalls. (orig.)

A small-angle large-acceptance detection system for hadrons

Science.gov (United States)

Kalantar-Nayestanaki, N.; Bacelar, J. C. S.; Brandenburg, S.; Huisman, H.; Messchendorp, J. G.; Mul, F. A.; Schadmand, S.; van der Schaaf, K.; Schippers, J. M.; Volkerts, M.

2000-04-01

The performance of a segmented large-acceptance detector, capable of measuring particles at small forward angles, is presented. The Small-Angle Large-Acceptance Detector (SALAD), was built to handle very high rates of particles impinging on the detector. Particles down to a few MeV can be detected with it. The position of charged particles is measured by two Multi-Wire Proportional Chambers while scintillator blocks are used to measure the energy of the detected particle. A stack of thin scintillators placed behind the energy detectors allows for a hardware rejection (veto) of high-energy particles going through the scintillator blocks.

A small-angle large-acceptance detection system for hadrons

CERN Document Server

Kalantar-Nayestanaki, N; Brandenburg, S; Huisman, H; Messchendorp, J G; Mul, F A; Schadmand, S; Schaaf, K V D; Schippers, J M; Volkerts, M

2000-01-01

The performance of a segmented large-acceptance detector, capable of measuring particles at small forward angles, is presented. The Small-Angle Large-Acceptance Detector (SALAD), was built to handle very high rates of particles impinging on the detector. Particles down to a few MeV can be detected with it. The position of charged particles is measured by two Multi-Wire Proportional Chambers while scintillator blocks are used to measure the energy of the detected particle. A stack of thin scintillators placed behind the energy detectors allows for a hardware rejection (veto) of high-energy particles going through the scintillator blocks.

A small-angle large-acceptance detection system for hadrons

International Nuclear Information System (INIS)

Kalantar-Nayestanaki, N.; Bacelar, J.C.S.; Brandenburg, S.; Huisman, H.; Messchendorp, J.G.; Mul, F.A.; Schadmand, S.; Schaaf, K. van der; Schippers, J.M.; Volkerts, M.

2000-01-01

The performance of a segmented large-acceptance detector, capable of measuring particles at small forward angles, is presented. The Small-Angle Large-Acceptance Detector (SALAD), was built to handle very high rates of particles impinging on the detector. Particles down to a few MeV can be detected with it. The position of charged particles is measured by two Multi-Wire Proportional Chambers while scintillator blocks are used to measure the energy of the detected particle. A stack of thin scintillators placed behind the energy detectors allows for a hardware rejection (veto) of high-energy particles going through the scintillator blocks

Modeling small angle scattering data using FISH

International Nuclear Information System (INIS)

Elliott, T.; Buckely, C.E.

2002-01-01

Full text: Small angle neutron scattering (SANS) and small angle x-ray scattering (SAXS) are important techniques for the characterisation of samples on the nanometer scale. From the scattered intensity pattern information about the sample such as particle size distribution, concentration and particle interaction can be determined. Since the experimental data is in reciprocal space and information is needed about real space, modeling of the scattering data to obtain parameters is extremely important and several paradigms are available. The use of computer programs to analyze the data is imperative for a robust description of the sample to be obtained. This presentation gives an overview of the SAS process and describes the data-modeling program FISH, written by R. Heenan 1983-2000. The results of using FISH to obtain the particle size distribution of bubbles in the aluminum hydrogen system and other systems of interest are described. Copyright (2002) Australian X-ray Analytical Association Inc

Spin-Echo Small-Angle Neutron Scattering Development

NARCIS (Netherlands)

Uca, O.

2003-01-01

Spin-Echo Small-Angle Neutron Scattering (SESANS) instrument is a novel SANS technique which enables one to characterize distances from a few nanometers up to the micron range. The most striking difference between normal SANS and SESANS is that in SESANS one gets information in real space, whereas

Small angle scattering and polymers

International Nuclear Information System (INIS)

Cotton, J.P.

1996-01-01

The determination of polymer structure is a problem of interest for both statistical physics and industrial applications. The average polymer structure is defined. Then, it is shown why small angle scattering, associated with isotopic substitution, is very well suited to the measurement of the chain conformation. The corresponding example is the old, but pedagogic, measurement of the chain form factor in the polymer melt. The powerful contrast variation method is illustrated by a recent determination of the concentration profile of a polymer interface. (author) 12 figs., 48 refs

A review on the study of polymer properties by Small Angle Neutron Scattering

International Nuclear Information System (INIS)

Seong, Baek Seok; Lee, Chang Hee; Sim, Hae Seop; Lee, Jung Sool; Kim, Hong Doo; Kim, Eu Gene; Cha, Kuk Heon

1998-05-01

This report contains concept of small angle neutron scattering , various design features and considerations of the small angle neutron spectrometer at HANARO, and recent trends of polymer studies by using this SANS technique with the installation of the spectrometer in near future. We, therefore, wish to review feasibility of small angle studies for polymer field at this spectrometer and to help possible beam time users for their experimental consideration. (author). 23 refs., 7 tabs., 23 figs

TOF-SEMSANS—Time-of-flight spin-echo modulated small-angle neutron scattering

NARCIS (Netherlands)

Strobl, M.; Tremsin, A.S.; Hilger, A.; Wieder, F.; Kardjilov, N.; Manke, I.; Bouwman, W.G.; Plomp, J.

2012-01-01

We report on measurements of spatial beam modulation of a polarized neutron beam induced by triangular precession regions in time-of-flight mode and the application of this novel technique spin-echo modulated small-angle neutron scattering (SEMSANS) to small-angle neutron scattering in the very

Small angle elastic scattering of electrons by noble gas atoms

International Nuclear Information System (INIS)

Wagenaar, R.W.

1984-01-01

In this thesis, measurements are carried out to obtain small angle elastic differential cross sections in order to check the validity of Kramers-Kronig dispersion relations for electrons scattered by noble gas atoms. First, total cross sections are obtained for argon, krypton and xenon. Next, a parallel plate electrostatic energy analyser for the simultaneous measurement of doubly differential cross section for small angle electron scattering is described. Also absolute differential cross sections are reported. Finally the forward dispersion relation for electron-helium collisions is dealt with. (Auth.)

Investigation of polydisperse, disordered, and fractal systems by small-angle x-ray and neutron scattering

International Nuclear Information System (INIS)

Schmidt, P.W.; Tang, Y.; Roell, A.; Steiner, M.; Hoehr, A.; Neumann, H.B.

1990-01-01

Small-angle x-ray and neutron scattering are useful methods for investigating the structure of materials on a scale from about 10 to 2000 A. Some experimental procedures and methods of data analysis for small-angle scattering are outlined, and the use of small-angle scattering for studies of polydisperse systems (i.e., systems of particles of different size) of independently scattering particles is reviewed. Some general properties of the small-angle scattering from mass and surface fractals are discussed, and some applications of these concepts in recent experimental studies are presented. Results obtained in calculations of the small-angle scattering from a model of a surface are summarized. (author) 3 figs., 18 refs

Small Angle Neutron Scattering From Iron. Vol. 2

Energy Technology Data Exchange (ETDEWEB)

Adib, M; Abdel-Kawy, A; Naguib, K; Habib, N; Kilany, M [Reactor and Neutron Physics Dept., Nuclear Research Centre, AEA, Cairo, (Egypt); Wahba, M [Faculty of Engineering, ain Shams University, Cairo, (Egypt); Ashry, A [Faculty of Education, Ain Shams University, Cairo, (Egypt)

1996-03-01

The total neutron cross-section measurements have been carried out for iron in both metallic and powder forms in the wavelengths band 0.35 nm to 0.52 nm. The measurements were performed using the TOF spectrometer installed in front of one of the horizontal channels of the ET-RR-1 reactor. The observed behavior for the small-angle neutron scattering cross-section of iron powder was analyzed in terms of its particle diameter, incident neutron wavelength and beam divergence. It was found that for iron particles of diameter 25 {mu}m the small-angle neutron scattering is only due to refraction of neutron wave traversing the particles. A method was established to determine the particle size of iron powders within an accuracy of 8% which is higher than that obtained by mesh analysis. 4 figs., 1 tab.

Small-angle neutron scattering technique in liquid crystal studies

International Nuclear Information System (INIS)

Shahidan Radiman

2005-01-01

The following topics discussed: general principles of SAS (Small-angle Neutron Scattering), liquid crystals, nanoparticle templating on liquid crystals, examples of SAS results, prospects of this studies

Experimental technique of small angle neutron scattering

International Nuclear Information System (INIS)

Xia Qingzhong; Chen Bo

2006-03-01

The main parts of Small Angle Neutron Scattering (SANS) spectrometer, and their function and different parameters are introduced from experimental aspect. Detailed information is also introduced for SANS spectrometer 'Membrana-2'. Based on practical experiments, the fundamental requirements and working condition for SANS experiments, including sample preparation, detector calibration, standard sample selection and data preliminary process are described. (authors)

Small-angle neutron scattering from colloidal dispersions

International Nuclear Information System (INIS)

Ottewill, R.H.

1991-01-01

A survey is given of recent work on the use of small-angle neutron scattering to examine colloidal dispersions. Particular attention is given to the determination of particle size and polydispersity, the determination of particle morphology and the behaviour of concentrated colloidal dispersions, both at rest and under the influence of an applied shear field. (orig.)

Time-resolved small-angle neutron scattering study on soap-free emulsion polymerization

Energy Technology Data Exchange (ETDEWEB)

Motokawa, Ryuhei [Research Group of Soft Matter and Neutron Scattering, Advanced Science Research Center, Japan Atomic Energy Research Institute, Tokai, Ibaraki 319-1195 (Japan); Koizumi, Satoshi [Research Group of Soft Matter and Neutron Scattering, Advanced Science Research Center, Japan Atomic Energy Research Institute, Tokai, Ibaraki 319-1195 (Japan)]. E-mail: koizumi@neutrons.tokai.jaeri.go.jp; Hashimoto, Takeji [Research Group of Soft Matter and Neutron Scattering, Advanced Science Research Center, Japan Atomic Energy Research Institute, Tokai, Ibaraki 319-1195 (Japan); Nakahira, Takayuki [Department of Applied Chemistry and Biotechnology, Chiba University, Chiba-shi, Chiba 263-8522 (Japan); Annaka, Masahiko [Department of Chemistry, Kyushu University, Fukuoka 812-8581 (Japan)

2006-11-15

We investigated an aqueous soap-free emulsion polymerization process of Poly(N-isopropylacrylamide)-block-poly(ethylene glycol) by ultra-small-angle and time-resolved small-angle neutron scattering methods. The results indicate that the compartmentalization of chain end radicals into solid-like micelle cores crucially leads to the quasi-living behavior of the radical polymerization by prohibiting recombination process.

Large or small angle MSW from single right-handed neutrino dominance

International Nuclear Information System (INIS)

King, S.F

2000-01-01

In this talk we discuss a natural explanation of both neutrino mass hierarchies and large neutrino mixing angles, as required by the atmospheric neutrino data, in terms of a single right-handed neutrino giving the dominant contribution to the 23 block of the light effective neutrino matrix, and illustrate this mechanism in the framework of models with U(1) family symmetries. Sub-dominant contributions from other right-handed neutrinos are required to give small mass splittings appropriate to the MSW solution to the solar neutrino problem. We present three explicit examples for achieving the small angle MSW solution in the framework of U(1) family symmetry models containing three right-handed neutrinos, which can naturally describe all quark and lepton masses and mixing angles. In this talk we also extend the analysis to the large angle MSW solution

A novel application of small-angle scattering techniques: Quality assurance testing of virus quantification technology

International Nuclear Information System (INIS)

Kuzmanovic, Deborah A.; Elashvili, Ilya; O'Connell, Catherine; Krueger, Susan

2008-01-01

Small-angle scattering (SAS) techniques, like small-angle X-ray scattering (SAXS) and small-angle neutron scattering (SANS), were used to measure and thus to validate the accuracy of a novel technology for virus sizing and concentration determination. These studies demonstrate the utility of SAS techniques for use in quality assurance measurements and as novel technology for the physical characterization of viruses

Proceedings of the workshop on small angle scattering data analysis. Micelle related topics

Energy Technology Data Exchange (ETDEWEB)

Yamaguchi, Toshio [Fukuoka Univ. (Japan). Faculty of Science; Furusaka, Michihiro; Ohtomo, Toshiya [eds.

1996-02-01

This workshop was held on December 13 and 14, 1995 at National Laboratory for High Energy Physics. At the workshop, the purpose of the workshop was explained, and lectures were given on the research on superhigh molecular structure by small angle neutron scattering, the verification of the reliability of WINK data (absolute intensity), the analysis of WINK data, the new data program of SAN, small angle X-ray scattering data analysis program (SAXS), the basis of the analysis of micelle system, analysis software manual and practice program Q-I(Q) ver 1.0, various analysis methods for small angle scattering and contrast modulation method and others, the ordering of and the countermeasures to the problems of WINK, and the hereafter of KENS small angle scattering facility. How to treat the analysis related to micelle, how to save WINK and how to install the SAN/reflectometer are the matters to be discussed at the workshop. In this book, the summaries of the lectures are collected. (K.I.)

SWIMS: a small-angle multiple scattering computer code

International Nuclear Information System (INIS)

Sayer, R.O.

1976-07-01

SWIMS (Sigmund and WInterbon Multiple Scattering) is a computer code for calculation of the angular dispersion of ion beams that undergo small-angle, incoherent multiple scattering by gaseous or solid media. The code uses the tabulated angular distributions of Sigmund and Winterbon for a Thomas-Fermi screened Coulomb potential. The fraction of the incident beam scattered into a cone defined by the polar angle α is computed as a function of α for reduced thicknesses over the range 0.01 less than or equal to tau less than or equal to 10.0. 1 figure, 2 tables

Characterization of porous materials by small-angle scattering

Indian Academy of Sciences (India)

With the availability of ultra small-angle scattering instruments, one can investigate porous materials in the sub-micron length scale. Because of the increased accessible length scale vis-a-vis the multiple scattering effect, conventional data analysis procedures based on single scattering approximation quite often fail.

Proceedings of the International school and symposium on small angle scattering

International Nuclear Information System (INIS)

Borbely, S.; Rosta, L.

1999-04-01

The meeting was devoted to small angle neutron and X-ray scattering with regard to the wide interest for this method in various fields of basic and applied research. Scientists from European laboratories gave introductory talks to various subject fields related to small angle scattering (SAS) techniques or data analysis methods as well as topical research area e.g. soft condensed matter, biology or materials science. An important number of contributed talks were presented on neutron or X-ray scattering and even on combining both of them, demonstrating the very useful complementarity of these methods. Some other papers give nice examples of SAS experiments completed by results of other techniques such as NMRE of light scattering. The variety of presented contributions is a nice demonstration for the interdisciplinary use of small angle scattering from physics through biology, chemistry, materials science to engineering. 18 items are indexed separately for the INIS database. (K.A.)

Small-angle neutron scattering studies of sodium butyl benzene

Indian Academy of Sciences (India)

Na-NBBS), in aqueous solutions is investigated by small-angle neutron scattering (SANS). Nearly ellipsoidal aggregates of Na-NBBS at concentrations well above its minimum hydrotrope concentration were detected by SANS. The hydrotrope ...

Small angle neutron scattering by polymer solutions

International Nuclear Information System (INIS)

Farnoux, B.; Jannink, G.

1980-08-01

Small angle neutron scattering is an experimental technique introduced since about 10 years for the observation of the polymer conformation in all the concentration range from dilute solution to the melt. After a brief recall of the elementary relations between scattering amplitude, index of refraction and scattered intensity, two concepts related to this last quantity (the contrast and the pair correlation function) are discussed in details

Small-angle scattering of swift electrons and positrons in a crystal

International Nuclear Information System (INIS)

Kudrin, V.V.; Vorobiev, S.A.

1975-01-01

Features of small-angle scattering of charged particles by the crystal structure and two-dimensional angular distribution are studied on the basis of Monte-Carlo calculations of 20 MeV electron and positron transmission through a MgO single crystal. An accurate method for calculation of the charged particle scattering in a heterogeneous electron gas in the crystal is proposed. The analytical conditions under which the string-effect influences the small-angle scattering are derived and comparison is carried out with well-known experimental data. (author)

Portable mini-chamber for temperature dependent studies using small angle and wide angle x-ray scattering

Science.gov (United States)

Dev, Arun Singh; Kumar, Dileep; Potdar, Satish; Pandit, Pallavi; Roth, Stephan V.; Gupta, Ajay

2018-04-01

The present work describes the design and performance of a vacuum compatible portable mini chamber for temperature dependent GISAXS and GIWAXS studies of thin films and multilayer structures. The water cooled body of the chamber allows sample annealing up to 900 K using ultra high vacuum compatible (UHV) pyrolytic boron nitride heater, thus making it possible to study the temperature dependent evolution of structure and morphology of two-dimensional nanostructured materials. Due to its light weight and small size, the chamber is portable and can be accommodated at synchrotron facilities worldwide. A systematic illustration of the versatility of the chamber has been demonstrated at beamline P03, PETRA-III, DESY, Hamburg, Germany. Temperature dependent grazing incidence small angle x-ray scattering (GISAXS) and grazing incidence wide angle x-ray scattering (GIWAXS) measurements were performed on oblique angle deposited Co/Ag multilayer structure, which jointly revealed that the surface diffusion in Co columns in Co/Ag multilayer enhances by increasing temperature from RT to ˜573 K. This results in a morphology change from columnar tilted structure to densely packed morphological isotropic multilayer.

A Microbeam Small-Angle X-ray Scattering Study on Enamel Crystallites in Subsurface Lesion

Energy Technology Data Exchange (ETDEWEB)

Yagi, N; Ohta, N; Matsuo, T [Japan Synchrotron Radiation Research Institute, 1-1-1 Kouto, Sayo, Hyogo 679-5198 (Japan); Tanaka, T; Terada, Y; Kamasaka, H; Kometani, T, E-mail: yagi@spring8.or.j [Ezaki Glico Co. Ltd., 4-6-5 Utajima, Nishiyodogawa-ku, Osaka 555-8502 (Japan)

2010-10-01

The early caries lesion in bovine tooth enamel was studied by two different X-ray diffraction systems at the SPring-8 third generation synchrotron radiation facility. Both allowed us simultaneous measurement of the small and large angle regions. The beam size was 6{mu}m at BL40XU and 50{mu}m at BL45XU. The small-angle scattering from voids in the hydroxyapatite crystallites and the wide-angle diffraction from the hydroxyapatite crystals were observed simultaneously. At BL40XU an X-ray image intensifier was used for the small-angle and a CMOS flatpanel detector for the large-angle region. At BL45XU, a large-area CCD detector was used to cover both regions. A linear microbeam scan at BL40XU showed a detailed distribution of voids and crystals and made it possible to examine the structural details in the lesion. The two-dimensional scan at BL45XU showed distribution of voids and crystals in a wider region in the enamel. The simultaneous small- and wide-angle measurement with a microbeam is a powerful tool to elucidate the mechanisms of demineralization and remineralization in the early caries lesion.

A Microbeam Small-Angle X-ray Scattering Study on Enamel Crystallites in Subsurface Lesion

International Nuclear Information System (INIS)

Yagi, N; Ohta, N; Matsuo, T; Tanaka, T; Terada, Y; Kamasaka, H; Kometani, T

2010-01-01

The early caries lesion in bovine tooth enamel was studied by two different X-ray diffraction systems at the SPring-8 third generation synchrotron radiation facility. Both allowed us simultaneous measurement of the small and large angle regions. The beam size was 6μm at BL40XU and 50μm at BL45XU. The small-angle scattering from voids in the hydroxyapatite crystallites and the wide-angle diffraction from the hydroxyapatite crystals were observed simultaneously. At BL40XU an X-ray image intensifier was used for the small-angle and a CMOS flatpanel detector for the large-angle region. At BL45XU, a large-area CCD detector was used to cover both regions. A linear microbeam scan at BL40XU showed a detailed distribution of voids and crystals and made it possible to examine the structural details in the lesion. The two-dimensional scan at BL45XU showed distribution of voids and crystals in a wider region in the enamel. The simultaneous small- and wide-angle measurement with a microbeam is a powerful tool to elucidate the mechanisms of demineralization and remineralization in the early caries lesion.

A national facility for small angle neutron scattering

International Nuclear Information System (INIS)

Buyers, W.J.L.; Katsaras, J.; Mellors, W.; Potter, M.M.; Powell, B.M.; Rogge, R.B.; Root, J.H.; Tennant, D.C.; Tun, Z.

1995-01-01

A world-class small angle neutron scattering (SANS) facility is proposed for Canada. It will provide users from the fields of biology, chemistry, physics, materials science and engineering with a uniquely powerful tool for investigating microstructural properties whose length scales lie in the optical to atomic range. (author). 7 refs

A national facility for small angle neutron scattering

Energy Technology Data Exchange (ETDEWEB)

Buyers, W J.L.; Katsaras, J; Mellors, W; Potter, M M; Powell, B M; Rogge, R B; Root, J H; Tennant, D C; Tun, Z [Atomic Energy of Canada Ltd., Chalk River, ON (Canada). Chalk River Nuclear Labs.; Epand, R; Gaulin, B D [McMaster Univ., Hamilton, ON (Canada)

1995-09-15

A world-class small angle neutron scattering (SANS) facility is proposed for Canada. It will provide users from the fields of biology, chemistry, physics, materials science and engineering with a uniquely powerful tool for investigating microstructural properties whose length scales lie in the optical to atomic range. (author). 7 refs.

Biological Small Angle Scattering: Techniques, Strategies and Tips

Energy Technology Data Exchange (ETDEWEB)

Chaudhuri, Barnali [University at Buffalo (SUNY); Muñoz, Inés G. [Centro Nacional de Investigaciones Oncológicas Madrid, Madrid, Spain; Urban, Volker S. [ORNL; Qian, Shuo [ORNL

2017-12-01

This book provides a clear, comprehensible and up-to-date description of how Small Angle Scattering (SAS) can help structural biology researchers. SAS is an efficient technique that offers structural information on how biological macromolecules behave in solution. SAS provides distinct and complementary data for integrative structural biology approaches in combination with other widely used probes, such as X-ray crystallography, Nuclear magnetic resonance, Mass spectrometry and Cryo-electron Microscopy. The development of brilliant synchrotron small-angle X-ray scattering (SAXS) beam lines has increased the number of researchers interested in solution scattering. SAS is especially useful for studying conformational changes in proteins, highly flexible proteins, and intrinsically disordered proteins. Small-angle neutron scattering (SANS) with neutron contrast variation is ideally suited for studying multi-component assemblies as well as membrane proteins that are stabilized in surfactant micelles or vesicles. SAS is also used for studying dynamic processes of protein fibrillation in amyloid diseases, and pharmaceutical drug delivery. The combination with size-exclusion chromatography further increases the range of SAS applications.The book is written by leading experts in solution SAS methodologies. The principles and theoretical background of various SAS techniques are included, along with practical aspects that range from sample preparation to data presentation for publication. Topics covered include techniques for improving data quality and analysis, as well as different scientific applications of SAS. With abundant illustrations and practical tips, we hope the clear explanations of the principles and the reviews on the latest progresses will serve as a guide through all aspects of biological solution SAS.The scope of this book is particularly relevant for structural biology researchers who are new to SAS. Advanced users of the technique will find it helpful for

Small angle slot divertor concept for long pulse advanced tokamaks

Science.gov (United States)

Guo, H. Y.; Sang, C. F.; Stangeby, P. C.; Lao, L. L.; Taylor, T. S.; Thomas, D. M.

2017-04-01

SOLPS-EIRENE edge code analysis shows that a gas-tight slot divertor geometry with a small-angle (glancing-incidence) target, named the small angle slot (SAS) divertor, can achieve cold, dissipative/detached divertor conditions at relatively low values of plasma density at the outside midplane separatrix. SAS exhibits the following key features: (1) strong enhancement of the buildup of neutral density in a localized region near the plasma strike point on the divertor target; (2) spreading of the cooling front across the divertor target with the slot gradually flaring out from the strike point, thus effectively reducing both heat flux and erosion on the entire divertor target surface. Such a divertor may potentially provide a power and particle handling solution for long pulse advanced tokamaks.

Small-angle X-ray scattering of solutions

International Nuclear Information System (INIS)

Koch, M.H.J.; Stuhrmann, H.B.; Vachette, P.; Tardieu, A.

1982-01-01

The use of synchrotron radiation in small-angle X-ray scattering (SAXS) techniques in biological structural studies is described. The main features of the monochromatic radiation systems and the white radiation systems are considered. The detectors, data acquisition and experimental procedures are briefly described. Experimental results are presented for 1) measurements on dilute solutions and weak scatterers, 2) measurement of conformational transitions, 3) contrast variation experiments, 4) time-resolved measurements and 5) complex contrast variation. (U.K.)

Small-angle scattering studies of the fully hydrated phospholipid DPPC

Energy Technology Data Exchange (ETDEWEB)

Mason, P.C.; Gaulin, B.D. [Department of Physics and Astronomy, McMaster University, Hamilton, Ontario, L8S 4M1 (CANADA); Epand, R.M. [Department of Biochemistry, McMaster University, Hamilton, Ontario, L8N 3Z5 (CANADA); Wignall, G.D.; Lin, J.S. [Center for Small-Angle Scattering Research, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States)

1999-01-01

Small-angle neutron and x-ray scattering studies have been carried out on fully hydrated dipalmitoylphosphatidylcholine (DPPC) multilamellar vesicles. This system is known to exhibit two distinct ripple (P{sub {beta}{sup {prime}}}) phases, which depend on sample history, at temperatures intermediate to its high-temperature liquid crystalline (L{sub {alpha}}), phase, and its low-temperature gel (L{sub {beta}{sup {prime}}}), phase. On cooling from the L{sub {alpha}} phase, the P{sub {beta}{sup {prime}}} phase displays a complex multipeak diffraction pattern that differs significantly from the diffraction pattern seen in the P{sub {beta}{sup {prime}}} phase obtained on warming from the L{sub {beta}{sup {prime}}} phase. Examining the P{sub {beta}{sup {prime}}} phase on cooling using small-angle neutron scattering and x-ray diffraction techniques leads to the conclusion that this phase is characterized by a long wavelength ripple ({lambda}{sub r}{approximately}330thinsp{Angstrom}) and a highly monoclinic unit cell ({gamma}{approximately}125{degree}). As the P{sub {beta}{sup {prime}}} phase is traversed in temperature, the ripple wavelength changes significantly while the monoclinicity remains unchanged. Ripples from the P{sub {beta}{sup {prime}}} phase are seen to persist into the L{sub {beta}{sup {prime}}} phase on cooling, leading to increased small-angle scattering characteristic of a disordered stacking of the lamellae. {copyright} {ital 1999} {ital The American Physical Society}

Small-angle x-ray scattering in amorphous silicon: A computational study

Science.gov (United States)

Paudel, Durga; Atta-Fynn, Raymond; Drabold, David A.; Elliott, Stephen R.; Biswas, Parthapratim

2018-05-01

We present a computational study of small-angle x-ray scattering (SAXS) in amorphous silicon (a -Si) with particular emphasis on the morphology and microstructure of voids. The relationship between the scattering intensity in SAXS and the three-dimensional structure of nanoscale inhomogeneities or voids is addressed by generating large high-quality a -Si networks with 0.1%-0.3% volume concentration of voids, as observed in experiments using SAXS and positron annihilation spectroscopy. A systematic study of the variation of the scattering intensity in the small-angle scattering region with the size, shape, number density, and the spatial distribution of the voids in the networks is presented. Our results suggest that the scattering intensity in the small-angle region is particularly sensitive to the size and the total volume fraction of the voids, but the effect of the geometry or shape of the voids is less pronounced in the intensity profiles. A comparison of the average size of the voids obtained from the simulated values of the intensity, using the Guinier approximation and Kratky plots, with that of the same from the spatial distribution of the atoms in the vicinity of void surfaces is presented.

Progress in small angle neutron scattering activities in Malaysia

International Nuclear Information System (INIS)

Abdul Aziz Bin Mohamed; Azali Bin Muhamad; Shukri Bin Mohd

1999-01-01

The current status of SANS (Small Angle Neutron Scattering facility) activities in Malaysia has been presented. Many works need to be done for system improvement before the system can be confidently used as one of effective quality control tools in materials production and engineering sectors. (author)

Multiple small-angle neutron scattering studies of anisotropic materials

CERN Document Server

Allen, A J; Long, G G; Ilavsky, J

2002-01-01

Building on previous work that considered spherical scatterers and randomly oriented spheroidal scatterers, we describe a multiple small-angle neutron scattering (MSANS) analysis for nonrandomly oriented spheroids. We illustrate this with studies of the multi-component void morphologies found in plasma-spray thermal barrier coatings. (orig.)

In situ microfluidic dialysis for biological small-angle X-ray scattering

DEFF Research Database (Denmark)

Skou, Magda; Skou, Soren; Jensen, Thomas Glasdam

2014-01-01

Owing to the demand for low sample consumption and automated sample changing capabilities at synchrotron small-angle X-ray (solution) scattering (SAXS) beamlines, X-ray microfluidics is receiving continuously increasing attention. Here, a remote-controlled microfluidic device is presented for sim...... in incidental sample purification. Hence, this versatile microfluidic device enables investigation of experimentally induced structural changes under dynamically controllable sample conditions. (C) 2014 International Union of Crystallography......Owing to the demand for low sample consumption and automated sample changing capabilities at synchrotron small-angle X-ray (solution) scattering (SAXS) beamlines, X-ray microfluidics is receiving continuously increasing attention. Here, a remote-controlled microfluidic device is presented...

Light scattering at small angles by atmospheric irregular particles: modelling and laboratory measurements

Science.gov (United States)

Lurton, T.; Renard, J.-B.; Vignelles, D.; Jeannot, M.; Akiki, R.; Mineau, J.-L.; Tonnelier, T.

2014-04-01

We have investigated the behaviour of light scattering by particulates of various sizes (0.1 μm to 100 μm) at a small scattering angle (below 20°). It has been previously shown that, for a small angle, the scattered intensities are weakly dependent upon the particulates' composition (Renard et al., 2010). Particles found in the atmosphere exhibit roughness that leads to large discrepancies with the classical Mie solution in terms of scattered intensities in the low angular set-up. This article focuses on building an effective theoretical tool to predict the behaviour of light scattering by real particulates at a small scattering angle. We present both the classical Mie theory and its adaptation to the case of rough particulates with a fairly simple roughness parameterisation. An experimental device was built, corresponding to the angular set-up of interest (low scattering angle and therefore low angular aperture). Measurements are presented that confirm the theoretical results with good agreement. It was found that differences between the classical Mie solution and actual measurements - especially for large particulates - can be attributed to the particulate roughness. It was also found that, in this low angular set-up, saturation of the scattered intensities occurs for relatively small values of the roughness parameter. This confirms the low variability in the scattered intensities observed for atmospheric particulates of different kinds. A direct interest of this study is a broadening of the dynamic range of optical counters: using a small angle of aperture for measurements allows greater dynamics in terms of particle size. Thus it allows a single device to observe a broad range of particle sizes whilst utilising the same electronics.

Progress in small angle neutron scattering activities in Malaysia

International Nuclear Information System (INIS)

Mohamed, Abudl Aziz Bin

2000-01-01

Research activities by use of small angle neutron scattering in Malaysia are briefly reported. Scattered neutron data are displayed in two or three-dimensional isometric view by the data acquisition system. Visual Basic is utilized for data acquisition and MathCad for data processing and analyses. (Y. Kazumata)

Progress in small angle neutron scattering activities in Malaysia

Energy Technology Data Exchange (ETDEWEB)

Mohamed, Abudl Aziz Bin [Industrial Technology Division, Malaysian Institute for Nuclear Technology Research (MINT) (Indonesia)

2000-10-01

Research activities by use of small angle neutron scattering in Malaysia are briefly reported. Scattered neutron data are displayed in two or three-dimensional isometric view by the data acquisition system. Visual Basic is utilized for data acquisition and MathCad for data processing and analyses. (Y. Kazumata)

Small Angle Neutron Scattering instrument at Malaysian TRIGA reactor

Energy Technology Data Exchange (ETDEWEB)

Mohd, Shukri; Kassim, Razali; Mahmood, Zal Uyun [Malaysian Inst. for Nuclear Technology Research (MINT), Bangi, Kajang (Malaysia); Radiman, Shahidan

1998-10-01

The TRIGA MARK II Research reactor at the Malaysian Institute for Nuclear Research (MINT) was commissioned in July 1982. Since then various works have been performed to utilise the neutrons produced from this steady state reactor. One of the project involved the Small Angle Neutron Scattering (SANS). (author)

The Small-Angle Neutron Scattering Data Analysis of the Phospholipid Transport Nanosystem Structure

Science.gov (United States)

Zemlyanaya, E. V.; Kiselev, M. A.; Zhabitskaya, E. I.; Aksenov, V. L.; Ipatova, O. M.; Ivankov, O. I.

2018-05-01

The small-angle neutron scattering technique (SANS) is employed for investigation of structure of the phospholipid transport nanosystem (PTNS) elaborated in the V.N.Orekhovich Institute of Biomedical Chemistry (Moscow, Russia). The SANS spectra have been measured at the YuMO small-angle spectrometer of IBR-2 reactor (Joint Institute of Nuclear Research, Dubna, Russia). Basic characteristics of polydispersed population of PTNS unilamellar vesicles (average radius of vesicles, polydispersity, thickness of membrane, etc.) have been determined in three cases of the PTNS concentrations in D2O: 5%, 10%, and 25%. Numerical analysis is based on the separated form factors method (SFF). The results are discussed in comparison with the results of analysis of the small-angle X-ray scattering spectra collected at the Kurchatov Synchrotron Radiation Source of the National Research Center “Kurchatov Institute” (Moscow, Russia).

The challenge of observation on livings things by employing an ultra small-angle neutron scattering method

International Nuclear Information System (INIS)

Koizumi, Satoshi; Motokawa, Ryuhei; Iwase, Hiroki; Miyamoto, Nobuyoshi; Tanaka, Kazuhiro; Masui, Tomomi; Iida, You; Yue, Zhao; Chiba, Kaori; Kumada, Takayuki; Yamaguchi, Daisuke; Hashimoto, Takeji

2007-01-01

To address the question as to how small-angle scattering is effectively applied to the cell, i.e., a hierarchically ordered system comprising multi-components of macro and small molecules, the size of which ranges from 100 μm to several μm, we reconstructed SANS-J (pinhole small-angle neutron scattering spectrometer at research reactor JRR3, Tokai) to focusing and polarized neutron small-angle spectrometer (SANS-J-II), by employing focusing neutron lenses and high resolution photomultiplier. Consequently, an accessible minimum wave number q min was improved from 3x10 -3 A -1 to medium ultra-small angle scattering of 3x10 -4 A -1 . The focusing USANS method, thus developed, is crucial to fill the gap in wave number q between those covered by a double crystal method and by a conventional pin-hole method. (author)

A LabVIEW based experiment system for the efficient collection and analysis of cyclic voltametry and electrode charge capacity measurements.

Science.gov (United States)

Detlefsen, D; Hu, Z; Troyk, P R

2006-01-01

Cyclic voltametry and recording of stimulation electrode voltage excursions are two critical methods of measurement for understanding the performance of implantable electrodes. Because implanted electrodes cannot easily be replaced, it is necessary to have an a-priori understanding of an electrode's implanted performance and capabilities. In-vitro exhaustive tests are often needed to quantify an electrodes performance. Using commonly available equipment, the human labor cost to conduct this work is immense. Presented is an automated experiment system that is highly configurable that can efficiently conduct a battery of repeatable CV and stimulation recording measurements. Results of preparing 96 electrodes prior to an animal implantation are also discussed.

Trace analysis of lead and cadmium in seafoods by differential pulse anodic stripping voltametry

International Nuclear Information System (INIS)

Sumera, F.C.; Verceluz, F.P.; Kapauan, P.A.

1979-01-01

A method for the simultaneous determination of cadmium and lead in seafoods is described. The sample is dry ashed in a muffle furnace elevating the temperature gradually up to 500 0 C. The ashed sample is treated with concentrated nitric acid, dried on a heating plate and returned to the muffle furnace for further heating. The treated ash is then dissolved in 1 N HCL acetate buffer and citric acid are added and the pH adjusted to 3.6-4. The resulting solution is analyzed for lead and cadmium by differential pulse anodic stripping voltametry (DPASV) using a wax-impregnated graphite thin film electrode. The average recoveries of 0.4 of cadmium and lead added to 5 fish samples were 97% and 99% respectively. The standard deviations, on a homogenized shark sample for lead and cadmium analysis were 6.7 ppb and 12.3 ppb, respectively, and the relative standard deviations were 21.0% and 15.5% respectively. Studies on instrumental parameters involved in the DPASV step of analysis and methods of measuring peak current signals were also made. (author)

Progresses in the measurement and evaluation of small-angle x-ray scattering data

International Nuclear Information System (INIS)

Bergmann, A.

2000-08-01

Scattering methods are a widely used technique for determining size and shape of particles in the mesoscopic size range. This work deals on the one hand with the development of instruments in the field of Small Angle x-ray Scattering (SAXS) and on the other hand with methodical contributions concerning the interpretation of small angle scattering data. After a short introduction about Small Angle Scattering (SAS) and its application in chapter one, follows in chapter two a derivation of the theory of Small Angle x-ray scattering. Thereafter indirect transformations (Generalized Indirect Fourier Transformation [GIFT], Indirect Fourier Transformation [IFT]) are discussed and in this connection the optimization of multidimensional hyper surfaces is described. There are different possibilities for optimizing such multidimensional surfaces. The pros and contras of the different optimization methods with respect to the evaluation of small angle scattering data from interacting systems are discussed in detail. Global optimization methods are mainly used, if the hypersurface, which has to be optimized, shows many local minima. The goal of the optimization is it to find the global minimum. It is essential, that the parameters of the hyper surface are independent of each other, as it is the case in the GIFT. If someone deals with problems in only few dimensions or with many boundary conditions, mostly local optimization routines are sufficient. Therefore a number of starting parameters for the optimization is chosen, which can be obtained systematically or randomly. The best solution obtained represents the result of the optimization procedure. Chapter 3 deals with the description of instruments used in the field of Small Angle x-ray Scattering. After a description of the components (x-ray sources, monochromators, detectors) of these instruments, the different beam geometries are discussed. In chapter 4 improvements of SAXS measurements on Kratky slit systems by Goebel

Small-angle neutron scattering studies on water soluble complexes ...

Indian Academy of Sciences (India)

... by small-angle neutron scattering. SANS data showed a positive indication of the formation of RCP-SDS complexes. Even though the complete structure of the polyion complexes could not be ascertained, the results obtained give us the information on the local structure in these polymer-surfactant systems. The data were ...

Modified sine bar device measures small angles with high accuracy

Science.gov (United States)

Thekaekara, M.

1968-01-01

Modified sine bar device measures small angles with enough accuracy to calibrate precision optical autocollimators. The sine bar is a massive bar of steel supported by two cylindrical rods at one end and one at the other.

Difference structures from time-resolved small-angle and wide-angle x-ray scattering

Science.gov (United States)

Nepal, Prakash; Saldin, D. K.

2018-05-01

Time-resolved small-angle x-ray scattering/wide-angle x-ray scattering (SAXS/WAXS) is capable of recovering difference structures directly from difference SAXS/WAXS curves. It does so by means of the theory described here because the structural changes in pump-probe detection in a typical time-resolved experiment are generally small enough to be confined to a single residue or group in close proximity which is identified by a method akin to the difference Fourier method of time-resolved crystallography. If it is assumed, as is usual with time-resolved structures, that the moved atoms lie within the residue, the 100-fold reduction in the search space (assuming a typical protein has about 100 residues) allows the exaction of the structure by a simulated annealing algorithm with a huge reduction in computing time and leads to a greater resolution by varying the positions of atoms only within that residue. This reduction in the number of potential moved atoms allows us to identify the actual motions of the individual atoms. In the case of a crystal, time-resolved calculations are normally performed using the difference Fourier method, which is, of course, not directly applicable to SAXS/WAXS. The method developed in this paper may be thought of as a substitute for that method which allows SAXS/WAXS (and hence disordered molecules) to also be used for time-resolved structural work.

Modelling small-angle scattering data from complex protein-lipid systems

DEFF Research Database (Denmark)

Kynde, Søren Andreas Røssell

This thesis consists of two parts. The rst part is divided into five chapters. Chapter 1 gives a general introduction to the bio-molecular systems that have been studied. These are membrane proteins and their lipid environments in the form of phospholipid nanodiscs. Membrane proteins...... the techniques very well suited for the study of the nanodisc system. Chapter 3 explains two different modelling approaches that can be used in the analysis of small-angle scattering data from lipid-protein complexes. These are the continuous approach where the system of interest is modelled as a few regular...... combine the bene ts of each of the methods and give unique structural information about relevant bio-molecular complexes in solution. Chapter 4 describes the work behind a proposal of a small-angle neutron scattering instrument for the European Spallation Source under construction in Lund. The instrument...

Particle and particle systems characterization small-angle scattering (SAS) applications

CERN Document Server

Gille, Wilfried

2016-01-01

Small-angle scattering (SAS) is the premier technique for the characterization of disordered nanoscale particle ensembles. SAS is produced by the particle as a whole and does not depend in any way on the internal crystal structure of the particle. Since the first applications of X-ray scattering in the 1930s, SAS has developed into a standard method in the field of materials science. SAS is a non-destructive method and can be directly applied for solid and liquid samples. Particle and Particle Systems Characterization: Small-Angle Scattering (SAS) Applications is geared to any scientist who might want to apply SAS to study tightly packed particle ensembles using elements of stochastic geometry. After completing the book, the reader should be able to demonstrate detailed knowledge of the application of SAS for the characterization of physical and chemical materials.

Small-angle light scattering studies of dense AOT-water-decane microemulsions

International Nuclear Information System (INIS)

Micali, N.; Trusso, S.; Mallamace, F.; Chen, S.H.

1996-01-01

It is performed extensive studies of a three-component microemulsion system composed of AOT-water-decane using small-angle light scattering (SALS). The small-angle scattering intensities are measured in the angular interval 0.001-0.1 radians, corresponding to a Bragg wave number range of 0.14 μm -1 -1 . The measurements were made by changing temperature and volume fraction φ of the dispersed phase in the range 0.65< φ < 0.75. All samples have a fixed water-to-AOT molar ratio, w [water[/[AOT[ = 40.8, in order to keep the same average droplet size in the stable one-phase region. With the SALS technique it is observed all the phase boundaries of a very complex phase diagram with a percolation line and many structural organizations within it. It is observed at the percolation transition threshold, a scaling behavior of the intensity data. In addition it is described in detail a structural transition from a droplet microemulsion to a bi continuous one a suggested by a recent small-angle neutron scattering experiment. From the data analysis it is show that both the percolation phenomenon and this novel structural transition are described from a large-scale aggregation between microemulsion droplets

Small-angle neutron scattering in materials science - an introduction

International Nuclear Information System (INIS)

Fratzl, P.

1996-01-01

The basic principles of the application of small-angle neutron scattering to materials research are summarized. The text focusses on the classical methods of data evaluation for isotropic and for anisotropic materials. Some examples of applications to the study of alloys, porous materials, composites and other complex materials are given. (author) 9 figs., 38 refs

Disordered porous solids : from chord distributions to small angle scattering

Science.gov (United States)

Levitz, P.; Tchoubar, D.

1992-06-01

Disordered biphasic porous solids are examples of complex interfacial media. Small angle scattering strongly depends on the geometrical properties of the internal surface partitioning a porous system. Properties of the second derivative of the bulk autocorrelation function quantitatively defines the level of connection between the small angle scattering and the statistical properties of this interface. A tractable expression of this second derivative, involving the pore and the mass chord distribution functions, was proposed by Mering and Tchoubar (MT). Based on the present possibility to make a quantitative connection between imaging techniques and the small angle scattering, this paper tries to complete and to extend the MT approach. We first discuss how chord distribution functions can be used as fingerprints of the structural disorder. An explicit relation between the small angle scattering and these chord distributions is then proposed. In a third part, the application to different types of disorder is critically discussed and predictions are compared to available experimental data. Using image processing, we will consider three types of disorder : the long-range Debye randomness, the “ correlated " disorder with a special emphasis on the structure of a porous glass (the vycor), and, finally, complex structures where length scale invariance properties can be observed. Les solides poreux biphasiques sont des exemples de milieux interfaciaux complexes. La diffusion aux petits angles (SAS) dépend fortement des propriétés géométriques de l'interface partitionant le milieu poreux. Les propriétés de la dérivée seconde de la fonction d'autocorrélation de densité définit quantitativement le niveau de connection entre la diffusion aux petits angles et les caractéristiques statistiques de cette interface. Une expression utilisable de cette seconde dérivée, impliquant les distributions de cordes associées à la phase massique et au réseau de pores, fut

Analysis of small-angle scattering data from micelles and microemulsions

DEFF Research Database (Denmark)

Pedersen, J.S.

1999-01-01

The free-form methods for analyzing small-angle scattering data have, during the last years, found more widespread use for micelles and microemulsions. Recent developments have made them applicable also to systems with size polydispersity and particle correlations, however, model fitting still...

Small-angle neutron scattering studies of nonionic surfactant: Effect

Indian Academy of Sciences (India)

Micellar solution of nonionic surfactant -dodecyloligo ethyleneoxide surfactant, decaoxyethylene monododecyl ether [CH3(CH2)11(OCH2CH2)10OH], C12E10 in D2O solution have been analysed by small-angle neutron scattering (SANS) at different temperatures (30, 45 and 60°C) both in the presence and absence of ...

Evaluation of solution stability for two-component polydisperse systems by small-angle scattering

Science.gov (United States)

Kryukova, A. E.; Konarev, P. V.; Volkov, V. V.

2017-12-01

The article is devoted to the modelling of small-angle scattering data using the program MIXTURE designed for the study of polydisperse multicomponent mixtures. In this work we present the results of solution stability studies for theoretical small-angle scattering data sets from two-component models. It was demonstrated that the addition of the noise to the data influences the stability range of the restored structural parameters. The recommendations for the optimal minimization schemes that permit to restore the volume size distributions for polydisperse systems are suggested.

The neutron small-angle camera D11 at the high-flux reactor, Grenoble

International Nuclear Information System (INIS)

Ibel, K.

1976-01-01

The neutron small-angle scattering system at the high-flux reactor in Grenoble consists of three major parts: the supply of cold neutrons via bent neutron guides; the small-angle camera D11; and the data handling facilities. The camera D11 has an overall length of 80 m. The effective length of the camera is variable. The full length of the collimator before the fixed sample position can be reduced by movable neutron guides; the second flight path of 40 m full length contains detector sites in various positions. Thus a large range of momentum transfers can be used with the same relative resolution. Scattering angles between 5 x 10 -4 and 0.5 rad and neutron wavelengths from 0.2 to 2.0 nm are available. A large-area position-sensitive detector is used which allows simultaneous recording of intensities scattered at different angles; it is a multiwire proportional chamber. 3808 elements of 1 cm 2 are arranged in a two-dimensional matrix. (Auth.)

Small angle neutron scattering from hydrated cement pastes

International Nuclear Information System (INIS)

Sabine, T.M.; Bertram, W.K.; Aldridge, L.P.

1996-01-01

Small angle neutron scattering (SANS) was used to study the microstructure of hydrating cement made with, and without silica fume. Some significant differences were found between the SANS spectra of pastes made from OPC (ordinary Portland cement) and DSP (made with silica fume and superplasticiser). The SANS spectra are interpreted in terms of scattering from simple particles. Particle growth was monitored during hydration and it was found that the growth correlated with the heat of hydration of the cement

Small angles X-ray diffraction and Mössbauer characterization of ...

Indian Academy of Sciences (India)

The effect of thermal annealing on the structure and magnetic properties of crystalline Tb/Fe multilayers has been studied using conversion electron Mössbauer spectrometry and small-angle X-ray diffraction. The growth of Tb–Fe amorphous alloy from the interface is observed with increasing annealing temperature.

Resolution effects and analysis of small-angle neutron scattering data

DEFF Research Database (Denmark)

Pedersen, J.S.

1993-01-01

A discussion of the instrumental smearing effects for small-angle neutron scattering (SANS) data sets is given. It is shown that these effects can be described by a resolution function, which describes the distribution of scattering vectors probed for the nominal values of the scattering vector...

Characterization of alumina using small angle neutron scattering (SANS)

International Nuclear Information System (INIS)

Megat Harun Al Rashidn Megat Ahmad; Abdul Aziz Mohamed; Azmi Ibrahim; Che Seman Mahmood; Edy Giri Rachman Putra; Muhammad Rawi Muhammad Zin; Razali Kassim; Rafhayudi Jamro

2007-01-01

Alumina powder was synthesized from an aluminium precursor and studied using small angle neutron scattering (SANS) technique and complemented with transmission electron microscope (TEM). XRD measurement confirmed that the alumina produced was high purity and highly crystalline αphase. SANS examination indicates the formation of mass fractals microstructures with fractal dimension of about 2.8 on the alumina powder. (Author)

Small angle X-ray scattering from hydrating tricalcium silicate

International Nuclear Information System (INIS)

Vollet, D.

1983-01-01

The small-angle X-ray scattering technique was used to study the structural evolution of hydrated tricalcium silicate at room temperature. The changes in specific area of the associated porosity and the evolution of density fluctuations in the solid hydrated phase were deduced from the scattering data. A correlation of these variations with the hydration mechanism is tried. (Author) [pt

Accounting for thermodynamic non-ideality in the Guinier region of small-angle scattering data of proteins.

Science.gov (United States)

Scott, David J

2016-12-01

Hydrodynamic studies of the solution properties of proteins and other biological macromolecules are often hard to interpret when the sample is present at a reasonably concentrated solution. The reason for this is that solutions exhibit deviations from ideal behaviour which is manifested as thermodynamic non-ideality. The range of concentrations at which this behaviour typically is exhibited is as low as 1-2 mg/ml, well within the range of concentrations used for their analysis by techniques such as small-angle scattering. Here we discuss thermodynamic non-ideality used previously used in the context of light scattering and sedimentation equilibrium analytical ultracentrifugation and apply it to the Guinier region of small-angle scattering data. The results show that there is a complementarity between the radially averaged structure factor derived from small-angle X-ray scattering/small-angle neutron scattering studies and the second virial coefficient derived from sedimentation equilibrium analytical ultracentrifugation experiments.

Small angles X-ray diffraction and Mössbauer characterization of ...

Indian Academy of Sciences (India)

Abstract. The effect of thermal annealing on the structure and magnetic properties of crystalline Tb/Fe multilayers has been studied using conversion electron Mössbauer spectrometry and small-angle X-ray diffraction. The growth of Tb–Fe amorphous alloy from the interface is observed with increasing annealing ...

Small-angle scattering from GP zones in Al–Cu alloy

Indian Academy of Sciences (India)

... and smallangle scattering experiments were carried on the powdered samples as a function of time during artificial aging. Small-angle scattering data were analysed, and evidence has been obtained for the occurrence of spinodal decomposition as the mechanism responsible in the early stages of formation of GP zones.

Small angle neutron scattering studies of mixed micelles of sodium

Indian Academy of Sciences (India)

The aqueous solutions of sodium cumene sulphonate (NaCS) and its mixtures with each of cetyl trimethylammonium bromide (CTAB) and sodium dodecyl sulphate (SDS) are characterized by small angle neutron scattering (SANS). NaCS when added to CTAB solution leads to the formation of long rod-shaped micelles with ...

Small-angle scattering in materials science

International Nuclear Information System (INIS)

Paris, O.; Fratzl, P.

1999-01-01

Small-angle scattering (SAS) of X-rays (SAXS) or neutrons (SANS) are a powerful tools to investigate inhomogeneities in the size range from ∼ 1 nm to ∼ 100 nm. Typical examples in materials science are pores, precipitates in metal alloys or nano-particles in composites. Frequently, these inhomogeneities are not spherical and their alignment is not random, quite in contrast to many other applications of SAS. This requires the use of pinhole geometry and area detectors for the experimental set-up. The present paper focuses on evaluation techniques of two-dimensional (2D) SAS-patterns from some materials investigated by the authors, i.e. metal alloys, carbon composites, wood and bone. Although the examples shown are derived exclusively from SAXS measurements, most of them could stem from SANS measurements as well. (author)

Small angle neutron scattering study of nano sized microstructure in Fe-Cr ODS steels for gen IV in-core applications.

Science.gov (United States)

Han, Young-Soo; Mao, Xiadong; Jang, Jinsung

2013-11-01

The nano-sized microstructures in Fe-Cr oxide dispersion strengthened steel for Gen IV in-core applications were studied using small angle neutron scattering. The oxide dispersion strengthened steel was manufactured through hot isostatic pressing with various chemical compositions and fabrication conditions. Small angle neutron scattering experiments were performed using a 40 m small angle neutron scattering instrument at HANARO. Nano sized microstructures, namely, yttrium oxides and Cr-oxides were quantitatively analyzed by small angle neutron scattering. The yttrium oxides and Cr-oxides were also observed by transmission electron microscopy. The microstructural analysis results from small angle neutron scattering were compared with those obtained by transmission electron microscopy. The effects of the chemical compositions and fabrication conditions on the microstructure were investigated in relation to the quantitative microstructural analysis results obtained by small angle neutron scattering. The volume fraction of Y-oxide increases after fabrication, and this result is considered to be due to the formation of non-stochiometric Y-Ti-oxides.

Small angle neutron scattering studies on the interaction of cationic

Indian Academy of Sciences (India)

The structure of the protein–surfactant complex of bovine serum albumin (BSA) and cationic surfactants has been studied by small angle neutron scattering. At low concentrations, the CTAB monomers are observed to bind to the protein leading to an increase in its size. On the other hand at high concentrations, surfactant ...

Pair production in small angle Bhabha scattering

International Nuclear Information System (INIS)

Arbuzov, A.B.; Kuraev, Eh.A.; Merenkov, N.P.; Trentadue, L.

1995-01-01

The radiative corrections due to a pair production in the small angle high energy e + e - Bhabha scattering are considered. The corrections due to the production of virtual pairs as well as real soft and hard ones are calculated analytically. The collinear and semi-collinear kinematical regions of the hard pair production are taken into account. The results in the leading and next-to-leading logarithmic approximations provide the accuracy of Ο (0.1%). The results of numerical calculations show that the effects of pairs production are to be taken into account in the precise luminosity determination at LEP. 9 refs., 3 figs., 2 tabs

Small-angle scattering at a pulsed neutron source: comparison with a steady-state reactor

Energy Technology Data Exchange (ETDEWEB)

Borso, C S; Carpenter, J M; Williamson, F S; Holmblad, G L; Mueller, M H; Faber, J Jr; Epperson, J E; Danyluk, S S [Argonne National Lab., IL (USA)

1982-08-01

A time-of-flight small-angle diffractometer employing seven tapered collimator elements and a two-dimensional gas proportional counter was successfully utilized to collect small-angle scattering data from a solution sample of the lipid salt cetylpyridinium chloride, C/sub 21/H/sub 38/N/sup +/.Cl/sup -/, at the Argonne National Laboratory prototype pulsed spallation neutron source, ZING-P'. Comparison of the small-angle scattering observed from the same compound at the University of Missouri Research Reactor corroborated the ZING-P' results. The results are used to compare the neutron flux available from the ZING-P' source relative to the well characterized University of Missouri source. Calculations based on experimentally determined parameters indicated the time-averaged rate of detected neutrons at the ZING-P' pulsed spallation source to have been at least 33% higher than the steady-state count rate from the same sample. Differences between time-of-flight techniques and conventional steady-state techniques are discussed.

Nucleation of small angle boundaries

CSIR Research Space (South Africa)

Nabarro, FRN

1996-12-01

Full Text Available The internal stresses induced by the strain gradients in an array of lattice cells delineated by low-angle dislocation boundaries are partially relieved by the creation of new low-angle boundaries. This is shown to be a first-order transition...

Investigation of metallic and ceramic materials by small-angle neutron scattering

NARCIS (Netherlands)

Smirnov, YI; Elyutin, NO

Small-angle neutron scattering measurements on a double-crystal spectrometer with perfect monochromator and analyzer crystals were used to follow microstructural changes in the aluminum alloy VD-17. refractory alloy ZhS-6, and dispersion-hardened zirconia-based ceramics with yttria additions. The

Time-of-flight small-angle scattering spectrometers on pulsed neutron sources

International Nuclear Information System (INIS)

Ostanevich, Yu.M.

1987-01-01

The operation principles, constructions, advantages and shortcomings of known time-of-flight small angle neutron scattering (TOF SANS) spectrometers built up with pulsed neutron sources are reviewed. The most important characteristics of TOF SANS apparatuses are rather a high luminosity and the possibility for the measurement in an extremely wide range of scattering vector at a single exposure. This is achieved by simultaneous employment of white beam, TOF technique for wave length-scan and the commonly known angle-scan. However, the electronic equipment, data-matching programs, and the measurement procedure, necessary for accurate normalization of experimental data and their transformation into absolute cross-section scale, they all become more complex, as compared with those for SANS apparatuses operating on steady-state neutron sources, where only angle-scan is used

Low-Resolution Structure of Detergent-Solubilized Membrane Proteins from Small-Angle Scattering Data.

Science.gov (United States)

Koutsioubas, Alexandros

2017-12-05

Despite the ever-increasing usage of small-angle scattering as a valuable complementary method in the field of structural biology, applications concerning membrane proteins remain elusive mainly due to experimental challenges and the relative lack of theoretical tools for the treatment of scattering data. This fact adds up to general difficulties encountered also by other established methods (crystallography, NMR) for the study of membrane proteins. Following the general paradigm of ab initio methods for low-resolution restoration of soluble protein structure from small-angle scattering data, we construct a general multiphase model with a set of physical constraints, which, together with an appropriate minimization procedure, gives direct structural information concerning the different components (protein, detergent molecules) of detergent-solubilized membrane protein complexes. Assessment of the method's precision and robustness is evaluated by performing shape restorations from simulated data of a tetrameric α-helical membrane channel (Aquaporin-0) solubilized by n-Dodecyl β-D-Maltoside and from previously published small-angle neutron scattering experimental data of the filamentous hemagglutinin adhesin β-barrel protein transporter solubilized by n-Octyl β-D-glucopyranoside. It is shown that the acquisition of small-angle neutron scattering data at two different solvent contrasts, together with an estimation of detergent aggregation number around the protein, permits the reliable reconstruction of the shape of membrane proteins without the need for any prior structural information. Copyright © 2017 Biophysical Society. Published by Elsevier Inc. All rights reserved.

Neutron elastic scattering at very small angles

CERN Multimedia

2002-01-01

This experiment will measure neutron-proton elastic scattering at very small angles and hence very small four-momentum transfer, |t|. The range of |t| depends on the incident neutron momentum of the events but the geometrical acceptance will cover the angular range 0.025 < $\\Theta_{lab}$ < 1.9 mrad. The higher figure could be extended to 8.4 mrad by changing the geometry of the experiment in a later phase. \\\\ \\\\ The neutron beam will be highly collimated and will be derived from a 400 GeV external proton beam of up to $4 \\times 10^{10}$ protons per pulse in the SPS North Area Hall 1. The hydrogen target will be gaseous, operating at 40 atm. pressure and acts as a multiwire proportional chamber to detect the recoil protons. The forward neutron will be detected and located by interaction in a neutron vertex detector and its energy measured by a conventional steel plate calorimeter. \\\\ \\\\ The experiment will cover the angular region of nucleon-nucleon scattering which is dominated by Coulomb scattering ...

Small angle X ray diffraction investigation of twinned opal_like structures

NARCIS (Netherlands)

Samusev, A.K.; Sinev, I.S.; Samusev, K.B.; Rybin, M.V.; Mistonov, A.A.; Grigoryeva, N.A.; Grigoriev, S.V.; Petukhov, A.V.; Byelov, D.; Trofimova, E.Y.; Kurdyukov, D.A.; Golubev, V.G.; Limonov, M.F.

2012-01-01

Small angle X ray diffraction from synthetic opal films has been investigated as a function of the orientation of the sample. All the observed (hkl) diffraction reflections have been interpreted. The reconstruct tion of the reciprocal lattice of the studied opal films has been carried out. The

Small angle X-ray scattering experiments with three-dimensional imaging gas detectors

International Nuclear Information System (INIS)

La Monaca, A.; Iannuzzi, M.; Messi, R.

1985-01-01

Measurements of small angle X-ray scattering of lupolen - R, dry collagen and dry cornea are presented. The experiments have been performed with synchrotron radiation and a new three-dimensional imaging drif-chamber gas detector

Ultra-small-angle neutron scattering. History, developments and applications

International Nuclear Information System (INIS)

Koizumi, Satoshi; Yamaguchi, Daisuke

2011-01-01

Ultra-small-angle neutron scattering (USANS), which is a scattering method observing in a q-region of q=10 -3 nm -1 , was initiated by double crystal (Bonse-Hart) method. Recently, a focusing USANS method was developed by combining a pin-hole type spectrometer and focusing lenses. These two methods, which are complementary to each other, were employed to achieve wide q-observations on microbial cellulose, actin cytoskeleton, tire, and membrane-electrolyte assembly of fuel cell. (author)

Stability Analysis of Hypersonic Boundary Layer over a Cone at Small Angle of Attack

Directory of Open Access Journals (Sweden)

Feng Ji

2014-04-01

Full Text Available An investigation on the stability of hypersonic boundary layer over a cone at small angle of attack has been performed. After obtaining the steady base flow, linear stability theory (LST analysis has been made with local parallel assumption. The growth rates of the first mode and second mode waves at different streamwise locations and different azimuthal angles are obtained. The results show that the boundary layer stability was greatly influenced by small angles of attack. The maximum growth rate of the most unstable wave on the leeward is larger than that on the windward. Moreover, dominating second mode wave starts earlier on the leeward than that on the windward. The LST result also shows that there is a “valley” region around 120°~150° meridian in the maximum growth rates curve.

Small angle neutron scattering using a triple axis spectrometer

International Nuclear Information System (INIS)

Ahmed, F.U.; Goyal, P.S.; Kamal, L.; Yunus, S.M.; Datta, T.K.; Rahman, M.O.; Azad, A.K.; Begum, S.; Zakaria, A.K.

1994-01-01

SANS techniques has been developed on a triple axis neutron spectrometer at TRIGA Mark II (3 MW) research reactor, AERE, Savar, Dhaka, Bangladesh. Double crystal (with very small mosaic spread ∼ 1 min.) diffraction known as Bonse and Hart's method has been employed. Such a device is a useful tool for small angle scattering in the Q range between 10 -5 and 10 -1 Angstroms -1 and for real time experiments at short time scales. Therefore, large objects and large distance interparticle correlations can be easily investigated. The results of SANS' measurements using alumina (A1 2 0 3 ) sample are presented. The radius of gyration has been determined and the data has been fitted to the scattering function of a sphere. 9 refs., 6 figs.,

Nucleon-nucleon scattering studies at small angles at COSY-ANKE

Energy Technology Data Exchange (ETDEWEB)

Bagdasarian, Zara [Forschungszentrum Juelich, Juelich (Germany); Tbilisi State University, Tbilisi (Georgia); Collaboration: ANKE-Collaboration

2015-07-01

The most accepted approach to describe nucleon-nucleon (NN) interaction is the partial wave analysis (PWA). The SAID database and analysis program comprise various experimental observables at different energies over the full angular range and express them in the partial waves. The goal of the experiments held at COSY-Juelich is to provide SAID with new valuable measurements. Scattering data was taken at small angles for six beam energies between 0.8 and 2.4 GeV with polarized proton beam incident on both proton and deuteron unpolarized targets using the ANKE spectrometer. First, the results of the proton-proton (pp) scattering analyzing power and cross section are presented. While pp data closes a very important gap at small angles in the database, proton-neutron (pn) data is a crucial contribution to the almost non-explored pn database above 800 MeV. Therefore, the talk will mainly concentrate on the proton-deuteron (pd) scattering studies, which includes the overview of the older COSY experiments with polarized deuteron beam, and the abovementioned new experiment with polarized proton beam and unpolarized deuteron target. The presentation will show the most recent results of the analyzing powers of pd elastic and pn scattering.

Data Analysis Of Small Angle X-Ray Solution Scattering And Its ...

African Journals Online (AJOL)

Small Angle X-ray Scattering analysis was used for the study of the protein, Human Tumour Necrosis Factor (TNF) homogeneously dispersed in solution. The experiment consisted in sending a well collimated beam of synchrotron radiation of wavelength, λ through the sample and measuring the variation of the intensity as a ...

Small angle scattering from protein/sugar conjugates

Science.gov (United States)

Jackson, Andrew; White, John

2006-11-01

The Maillard reaction between free amine groups on proteins and sugars is well known. We have examined the effect of the reaction of the casein group of milk proteins with sugars on their nanoscale structure and aggregation. The small angle neutron scattering from beta casein and sodium caseinate and their sugar conjugates have been studied as a function of solution concentration. At high conjugate concentration (greater than ca. 5 mg/ml) the addition of sugar reduces supra-micellar aggregation of the protein whilst at lower concentration, where the protein is expected to be deaggregated already, little effect is seen. Guinier analysis of the scattering data show a radius of gyration of around 75 A˚ for beta casein in solution and around 80 A˚ for the sucrose conjugate.

Two-dimensional position-sensitive detectors for small-angle neutron scattering

International Nuclear Information System (INIS)

McElhaney, S.A.; Vandermolen, R.I.

1990-05-01

In this paper, various detectors available for small angle neutron scattering (SANS) are discussed, along with some current developments being actively pursued. A section has been included to outline the various methodologies of position encoding/decoding with discussions on trends and limitations. Computer software/hardware vary greatly from institute and experiment and only a general discussion is given to this area. 85 refs., 33 figs

Insights into the interactions among Surfactin, betaines, and PAM: surface tension, small-angle neutron scattering, and small-angle X-ray scattering study.

Science.gov (United States)

Xiao, Jingwen; Liu, Fang; Garamus, Vasil M; Almásy, László; Handge, Ulrich A; Willumeit, Regine; Mu, Bozhong; Zou, Aihua

2014-04-01

The interactions among neutral polymer polyacrylamide (PAM) and the biosurfactant Surfactin and four betaines, N-dodecyl-N,N-dimethyl-3-ammonio-1-propanesulfonate (SDDAB), N-tetradecyl-N,N-dimethyl-3-ammonio-1-propanesulfonate (STDAB), N-hexadecyl-N,N-dimethyl-3-ammonio-1-propanesulfonate (SHDAB), and N-dodecyl-N,N-dimethyl-2-ammonio-acetate (C12BE), in phosphate buffer solution (PBS) have been studied by surface tension measurements, small-angle neutron scattering (SANS), small-angle X-ray scattering (SAXS), and rheological experiments. It has been confirmed that the length of alkyl chain is a key parameter of interaction between betaines and PAM. Differences in scattering contrast between X-ray and neutrons for surfactants and PAM molecules provide the opportunity to separately follow the changes of structure of PAM and surfactant aggregates. At concentrations of betaines higher than CMC (critical micelle concentration) and C2 (CMC of surfactant with the presence of polymer), spherical micelles are formed in betaines and betaines/PAM solutions. Transition from spherical to rod-like aggregates (micelles) has been observed in solutions of Surfactin and Surfactin/SDDAB (αSurfactin = 0.67 (molar fraction)) with addition of 0.8 wt % of PAM. The conformation change of PAM molecules only can be observed for Surfactin/SDDAB/PAM system. Viscosity values follow the structural changes suggested from scattering measurements i.e., gradually increases for mixtures PAM → Surfactin/PAM → Surfactin/SDDAB/PAM in PBS.

High-frequency impedance of small-angle tapers and collimators

Directory of Open Access Journals (Sweden)

G. Stupakov

2010-10-01

Full Text Available Collimators and transitions in accelerator vacuum chambers often include small-angle tapering to lower the wakefields generated by the beam. While the low-frequency impedance is well described by Yokoya’s formula (for axisymmetric geometry, much less is known about the behavior of the impedance in the high-frequency limit. In this paper we develop an analytical approach to the high-frequency regime for round collimators and tapers. Our analytical results are compared with computer simulations using the code ECHO.

Small angle scattering of X radiation and slow neutrons in structural analyses of amorphous solids

International Nuclear Information System (INIS)

Kostorz, G.

1980-01-01

Small angle scattering of x radiation and slow neutrons allows to detect inhomogeneities of the dimension of ten to some thousands of Angstroem by the difference in the scattering length density. The progress made during recent years in the development of apparatusses has created the possibility of solving very complicated problems. A first outline shows that in separation processes as well as in investigating extended defects the method of small angle scattering may provide valuable contributions to the analysis of the non-crystalline state

V4: The Small Angle Scattering Instrument (SANS at BER II

Directory of Open Access Journals (Sweden)

Uwe Keiderling

2016-11-01

Full Text Available V4 is a small-angle neutron scatting instrument with an accessible range of scattering vector 0.01 nm-1 < Q < 8.5 nm-1. Outstanding features of the instrument are the polarized neutron option and the list mode data acquisition, allowing for time-resolved measurements with µs time resolution.

Small-angle neutron scattering and cyclic voltammetry study on electrochemically oxidized and reduced pyrolytic carbon

International Nuclear Information System (INIS)

Braun, A.; Kohlbrecher, J.; Baertsch, M.; Schnyder, B.; Koetz, R.; Haas, O.; Wokaun, A.

2004-01-01

The electrochemical double layer capacitance and internal surface area of a pyrolytic carbon material after electrochemical oxidation and subsequent reduction was studied with cyclic voltammetry and small-angle neutron scattering. Oxidation yields an enhanced internal surface area (activation), and subsequent reduction causes a decrease of this internal surface area. The change of the Porod constant, as obtained from small-angle neutron scattering, reveals that the decrease in internal surface area is not caused merely by a closing or narrowing of the pores, but by a partial collapse of the pore network

Simulated small-angle scattering patterns for a plastically deformed model composite material

NARCIS (Netherlands)

Shenoy, V.B.; Cleveringa, H.H.M.; Phillips, R.; Giessen, E. van der; Needleman, A.

2000-01-01

The small-angle scattering patterns predicted by discrete dislocation plasticity versus local and non-local continuum plasticity theory are compared in a model problem. The problem considered is a two-dimensional model composite with elastic reinforcements in a crystalline matrix subject to

Design Principle of A Small Angle Neutron Scattering Spectrometer. Vol. 2

Energy Technology Data Exchange (ETDEWEB)

Ashry, A [Dept. of Physics, Faculty of Education, Ain Shams University, Cairo (Egypt)

1996-03-01

The design principle of a small angle neutron scattering (SANS) spectrometer is based on producing monochromatic neutron bursts using two phased rotors. The rotors have a number of slots to achieve the highly available intensity of monoenergetic neutrons at the required resolution. The design principle was applied to improve the performance of the pulsed monochromatic double rotor system at ET-RR-1 to operate as SANS spectrometer. It is shown that for rotors having 19 slots each with radius of curvature 96.8 cm, the intensity gain factor is 13. The proposed SANS spectrometer could cover the neutron wavelength range from 2 A{sup {omicron}} up to 6 A{sup {omicron}} through small angles of scattering from 5 x 10{sup -3} rad. to 0.1 rad. i.e, the scattering wavevector transfer between 0.6 A{sup {omicron}-1} and 0.01 A{sup {omicron}-1}. The maximum neutron flux density on the specimen is 5 x 10{sup 5} n cm{sup -2} s{sup -1}. 8 figs.

The Small angle TIle Calorimeter project in DELPHI

International Nuclear Information System (INIS)

Alvsvaag, S.J.; Maeland, O.A.; Klovning, A.

1995-01-01

The new Small Angle TIle Calorimeter (STIC) covers the forward regions in DELPHI. The main motivation for its construction was to achieve a systematic error of 0.1% on the luminosity determination. This detector consists of a ''shashlik'' type calorimeter, equipped with two planes of silicon pad detectors placed respectively after 4 and 7.4 radiation lengths. A veto counter, composed of two scintillator planes, covers the front of the calorimeter to allow e-γ separation and to provide a neutral energy trigger.The physics motivations for this project, results from extensive testbeam measurements and the performance during the 1994 LEP run are reported here. (orig.)

Small-angle tomography algorithm for transmission inspection of acoustic linear array

Directory of Open Access Journals (Sweden)

Soldatov Alexey

2016-01-01

Full Text Available The paper describes the algorithm of reconstruction of tomographic image used in the through-transition method in a small angle sounding of acoustic linear arrays and the results of practical application of the proposed algorithm. In alternate probing of each element of emitting array and simultaneous reception of all elements of the receiving array is a collection of shadow images of the testing zone. The testing zone is divided into small local areas and using the collection of shadow images computed matrix normalized transmission coefficients for each of the small local area. Tomographic image control zone is obtained by submitting the resulting matrix of normalized transmission coefficients in grayscale or colors.

Small angle scattering from protein/sugar conjugates

International Nuclear Information System (INIS)

Jackson, Andrew; White, John

2006-01-01

The Maillard reaction between free amine groups on proteins and sugars is well known. We have examined the effect of the reaction of the casein group of milk proteins with sugars on their nanoscale structure and aggregation. The small angle neutron scattering from beta casein and sodium caseinate and their sugar conjugates have been studied as a function of solution concentration. At high conjugate concentration (greater than ca. 5mg/ml) the addition of sugar reduces supra-micellar aggregation of the protein whilst at lower concentration, where the protein is expected to be deaggregated already, little effect is seen. Guinier analysis of the scattering data show a radius of gyration of around 75A-bar for beta casein in solution and around 80A-bar for the sucrose conjugate

Small angle scattering from protein/sugar conjugates

Energy Technology Data Exchange (ETDEWEB)

Jackson, Andrew [Research School of Chemistry, Australian National University, Canberra, ACT 0200 (Australia)]. E-mail: ajj@nist.gov; White, John [Research School of Chemistry, Australian National University, Canberra, ACT 0200 (Australia)

2006-11-15

The Maillard reaction between free amine groups on proteins and sugars is well known. We have examined the effect of the reaction of the casein group of milk proteins with sugars on their nanoscale structure and aggregation. The small angle neutron scattering from beta casein and sodium caseinate and their sugar conjugates have been studied as a function of solution concentration. At high conjugate concentration (greater than ca. 5mg/ml) the addition of sugar reduces supra-micellar aggregation of the protein whilst at lower concentration, where the protein is expected to be deaggregated already, little effect is seen. Guinier analysis of the scattering data show a radius of gyration of around 75A-bar for beta casein in solution and around 80A-bar for the sucrose conjugate.

Small-angle neutron scattering instrument at MINT

International Nuclear Information System (INIS)

Mohd Ali Sufi; Yusof Abdullah; Razali Kassim; Hamid; Shahidan Radiman; Mohammad Deraman; Abdul Ghaffar Ramli

1996-01-01

The Small Angle Neutron Scattering (SANS) Instrument has been developed at Malaysian Institute for Nuclear Technology Research (MINT) for studying structural properties of materials on the length scale 1 nm to 100 nm. This is the length scale which is relevant for many topics within soft condensed matter, like polymers, colloids, biological macromolecules, etc. The SANS is a complementary technique to X-ray and electron scattering. However, while these later techniques give information on structures near surface, SANS concerns the structure of the bulk. Samples studied by SANS technique are typically bulk materials of the sizes mm's to cm's, or materials dissolved in a liquid. This paper described the general characteristics of SANS instrument as well as the experimental formulation in neutron scattering. The preliminary results obtained by this instrument are shown

The analysis of nano structures based on small angle scattering of neutrons

International Nuclear Information System (INIS)

Len, Adel; Fuzi, Janos; Rosta, Laszlo; Harmat, Peter

2014-01-01

The paper describes the technology of small angle neutron scattering from neutron beam cooling to beam focusing and image processing. The applicability of the method is illustrated by sodium bubble analysis in tungsten, and investigation of the the effect of microbial transglutamase on casein micellas.

Small-angle neutron scattering at pulsed sources compared to reactor sources

International Nuclear Information System (INIS)

Hjelm, R.P. Jr.; Seeger, P.A.; Thiyagarajan, P.

1990-01-01

Detailed comparisons of measurements made on small-angle neutron scattering instruments at pulsed spallation and reactor sources show that the results from the two types of instruments are comparable. It is further demonstrated that spallation instruments are preferable for measurements in the mid-momentum transfer domain or when a large domain is needed. 8 refs., 2 figs

Small angle x-ray scattering from proteins in solution

International Nuclear Information System (INIS)

de Souza, C.F.; Torriani, I.L.; Bonafe, C.F.S.; Merrelles, N.C.; Vachette, P.

1989-01-01

In this work the authors report experiments performed with giant respiratory proteins from annelids (erythrocruorins), known to have a molecular weight in the order of four million Daltons. Preliminary x-ray scattering data was obtained using a conventional rotating anode source. High resolution small angle scattering curves were obtained with synchrotron radiation from the DCI storage ring at LURE. Data from solutions with several protein concentrations were analyzed in order to determine low resolution dimensional parameters, using Guinier plots from the smeared scattering curves and the inverse transformation method

A preliminary study of breast cancer diagnosis using laboratory based small angle x-ray scattering

Science.gov (United States)

Round, A. R.; Wilkinson, S. J.; Hall, C. J.; Rogers, K. D.; Glatter, O.; Wess, T.; Ellis, I. O.

2005-09-01

Breast tissue collected from tumour samples and normal tissue from bi-lateral mastectomy procedures were examined using small angle x-ray scattering. Previous work has indicated that breast tissue disease diagnosis could be performed using small angle x-ray scattering (SAXS) from a synchrotron radiation source. The technique would be more useful to health services if it could be made to work using a conventional x-ray source. Consistent and reliable differences in x-ray scatter distributions were observed between samples from normal and tumour tissue samples using the laboratory based 'SAXSess' system. Albeit from a small number of samples, a sensitivity of 100% was obtained. This result encourages us to pursue the implementation of SAXS as a laboratory based diagnosis technique.

A preliminary study of breast cancer diagnosis using laboratory based small angle x-ray scattering

Energy Technology Data Exchange (ETDEWEB)

Round, A R [Daresbury Laboratories, Warrington, WA4 4AD (United Kingdom); Wilkinson, S J [Daresbury Laboratories, Warrington, WA4 4AD (United Kingdom); Hall, C J [Daresbury Laboratories, Warrington, WA4 4AD (United Kingdom); Rogers, K D [Department of Materials and Medical Sciences, Cranfield University, Swindon, SN6 8LA (United Kingdom); Glatter, O [Department of Chemistry, University of Graz (Austria); Wess, T [School of Optometry and Vision Sciences, Cardiff University, Cardiff CF10 3NB, Wales (United Kingdom); Ellis, I O [Nottingham City Hospital, Nottingham (United Kingdom)

2005-09-07

Breast tissue collected from tumour samples and normal tissue from bi-lateral mastectomy procedures were examined using small angle x-ray scattering. Previous work has indicated that breast tissue disease diagnosis could be performed using small angle x-ray scattering (SAXS) from a synchrotron radiation source. The technique would be more useful to health services if it could be made to work using a conventional x-ray source. Consistent and reliable differences in x-ray scatter distributions were observed between samples from normal and tumour tissue samples using the laboratory based 'SAXSess' system. Albeit from a small number of samples, a sensitivity of 100% was obtained. This result encourages us to pursue the implementation of SAXS as a laboratory based diagnosis technique.

A preliminary study of breast cancer diagnosis using laboratory based small angle x-ray scattering

International Nuclear Information System (INIS)

Round, A R; Wilkinson, S J; Hall, C J; Rogers, K D; Glatter, O; Wess, T; Ellis, I O

2005-01-01

Breast tissue collected from tumour samples and normal tissue from bi-lateral mastectomy procedures were examined using small angle x-ray scattering. Previous work has indicated that breast tissue disease diagnosis could be performed using small angle x-ray scattering (SAXS) from a synchrotron radiation source. The technique would be more useful to health services if it could be made to work using a conventional x-ray source. Consistent and reliable differences in x-ray scatter distributions were observed between samples from normal and tumour tissue samples using the laboratory based 'SAXSess' system. Albeit from a small number of samples, a sensitivity of 100% was obtained. This result encourages us to pursue the implementation of SAXS as a laboratory based diagnosis technique

SIMSAS - a window based software package for simulation and analysis of multiple small-angle scattering data

International Nuclear Information System (INIS)

Jayaswal, B.; Mazumder, S.

1998-09-01

Small-angle scattering data from strong scattering systems, e.g. porous materials, cannot be analysed invoking single scattering approximation as specimen needed to replicate the bulk matrix in essential properties are too thick to validate the approximation. The presence of multiple scattering is indicated by invalidity of the functional invariance property of the observed scattering profile with variation of sample thickness and/or wave length of the probing radiation. This article delineates how non accounting of multiple scattering affects the results of analysis and then how to correct the data for its effect. It deals with an algorithm to extract single scattering profile from small-angle scattering data affected by multiple scattering. The algorithm can process the scattering data and deduce single scattering profile in absolute scale. A software package, SIMSAS, is introduced for executing this inversion step. This package is useful both to simulate and to analyse multiple small-angle scattering data. (author)

An upgrade beamline for combined wide, small and ultra small-angle x-ray scattering at the ESRF

Energy Technology Data Exchange (ETDEWEB)

Van Vaerenbergh, Pierre; Léonardon, Joachim; Sztucki, Michael; Boesecke, Peter; Gorini, Jacques; Claustre, Laurent; Sever, Franc; Morse, John; Narayanan, Theyencheri [ESRF - The European Synchrotron, F-38043 Grenoble (France)

2016-07-27

This contribution presents the main design features of the upgraded beamline ID02 (TRUSAXS). The beamline combines different small-angle X-ray scattering techniques in one unique instrument. The key component of this instrument is an evacuated (5×10{sup −3} mbar) stainless steel detector tube of length 34 m and diameter 2 m. Three different detectors (Rayonix MX170, Pilatus 300 K and FReLoN 4M) are housed inside a motorized wagon which travels along a rail system with very low parasitic lateral movements (± 0.3 mm). This system allows automatically changing the sample-to-detector distance from about 1 m to 31 m and selecting the desired detector. In addition, a wide angle detector (Rayonix LX170) is installed just above the entrance cone of the tube for optional wide-angle X-ray scattering measurements. The beamstop system enables monitoring of the X-ray beam intensity in addition to blocking the primary beam, and automated insertion of selected masks behind the primary beamstop. The focusing optics and collimation system permit to cover a scattering vector (q) range of 0.002 nm{sup −1} ≤ q ≤ 50 nm{sup −1} with one unique setting using 0.1 nm X-ray wavelength for moderate flux (5×10{sup 12} photons/sec). However, for higher flux (6x10{sup 13} photons/sec) or higher resolution (minimum q < 0.001 nm{sup −1}), focusing and collimation, respectively need to be varied. For a sample-to-detector distance of 31 m and 0.1 nm wavelength, two dimensional ultra small-angle X-ray scattering patterns can be recorded down to q≈0.001 nm{sup −1} with far superior quality as compared to one dimensional profiles obtained with a Bonse-Hart instrument.

Dispersion forces and small-angle neutron scattering from liquid noble metals

International Nuclear Information System (INIS)

March, N.H.

1988-01-01

Maggs and Ashcroft [Phys. Rev. letts., 59,113 (1987)] have re-opened the question of the analogy between the cohesion of a molecular crystal, in which dispersion forces play a major role, and that in a metal crystal with polarizable ion cores. It is pointed out that small-angle neutron scattering from liquid noble metals could be used to test their predictions. (author)

Hadron elastic scattering at small angles

CERN Multimedia

2002-01-01

This experiment is an extension of the measurements of the WA9 experiment up to the highest energies available in the North Area. It will measure the differential cross-section for hadron elastic scattering in the t-range 0.002-0.05 (GeV/c)$^{2}$ using an ionization chamber for the measurement of the energy and the angle of the recoil and a magnet-WC spectrometer to measure the momentum and direction of the forward particle. From these measurements will be obtained the ratio $\\rho$ of the real to imaginary parts of the forward elastic amplitude and the exponential slope parameter b of the hadronic amplitude at small t. The precision expected in these measurements is $\\Delta \\rho \\approx \\pm 0.01$ and $\\Delta$b $\\approx \\pm 0.2$ (GeV/c)$^{-2}$. \\\\ \\\\ The experimental programme includes: \\\\\\\\ i) measurements of $\\rho$ and b for $\\pi$p elastic scattering at incident momenta between 150 GeV/c and 300 GeV/c; \\\\ ii) measurements of $\\rho$ and b for $\\pi^{+}$p and pp elastic scattering at incident momenta between 5...

Informing the improvement of forest products durability using small angle neutron scattering

Science.gov (United States)

Nayomi Plaza Rodriguez; Sai Venkatesh Pingali; Shuo Qian; William T. Heller; Joseph E. Jakes

2016-01-01

A better understanding of how wood nanostructure swells with moisture is needed to accelerate the development of forest products with enhanced moisture durability. Despite its suitability to study nanostructures, small angle neutron scattering (SANS) remains an underutilized tool in forest products research. Nanoscale moisture-induced structural changes in intact and...

Small-angle X-ray scattering documents the growth of metal-organic frameworks

NARCIS (Netherlands)

Goesten, M.G.; Stavitski, I.; Juan-Alcañiz, J.; Martinez-Joaristi, A.; Petukhov, A.V.; Kapteijn, F.; Gascon, J.

2013-01-01

We present a combined in situ small- and wide-angle scattering (SAXS/WAXS) study on the crystallization of two topical metal-organic frameworks synthesized from similar metal and organic precursors: NH2-MIL-53(Al) and NH2-MIL-101(Al). A thorough analysis of SAXS data reveals the most important

A high resolution position sensitive X-ray MWPC for small angle X-ray diffraction

International Nuclear Information System (INIS)

Bateman, J.E.; Connolly, J.F.; Stephenson, R.; Tappern, G.J.

1981-02-01

A small sealed-off delay line readout MWPC X-ray detector has been designed and built for small angle X-ray diffraction applications. Featuring a sensitive area of 100 mm x 25 mm it yields a spatial resolution of 0.13 mm (standard deviation) with a high rate capability and good quantum efficiency for copper K radiation. (author)

Reversible membrane reorganizations during photosynthesis in vivo: revealed by small-angle neutron scattering

DEFF Research Database (Denmark)

Nagy, Gergely; Posselt, Dorthe; Kovacs, Laszlo

2011-01-01

In the present study, we determined characteristic repeat distances of the photosynthetic membranes in living cyanobacterial and eukaryotic algal cells, and in intact thylakoid membranes isolated from higher plants with time-resolved small-angle neutron scattering. This non-invasive technique...

Small-Angle Neutron Scattering Study of Structural Changes in Temperature-Sensitive Microgel Colloids

NARCIS (Netherlands)

Stieger, M.A.; Richtering, W.; Pedersen, J.S.; Lindner, P.

2004-01-01

The structure of temperature-sensitive poly(N-isopropylacrylamide) microgels in dilute suspension was investigated by means of small-angle neutron scattering. A direct modeling expression for the scattering intensity distribution was derived which describes very well the experimental data at all

Performance of the upgraded small angle tile calorimeter at LEP

CERN Document Server

Alvsvaag, S J; Barreira, G; Benvenuti, Alberto C; Bigi, M; Bonesini, M; Bozzo, M; Camporesi, T; Carling, H; Cassio, V; Castellani, L; Cereseto, R; Chignoli, F; Della Ricca, G; Dharmasiri, D R; Espirito-Santo, M C; Falk, E; Fenyuk, A; Ferrari, P; Gamba, D; Giordano, V; Guz, Yu; Guerzoni, M; Gumenyuk, S A; Hedberg, V; Jarlskog, G; Karyukhin, A N; Klovning, A; Konoplyannikov, A K; Kronkvist, I J; Lanceri, L; Leoni, R; Maeland, O A; Maio, A; Mazza, R; Migliore, E; Navarria, Francesco Luigi; Nossum, B; Obraztsov, V F; Onofre, A; Paganoni, M; Pegoraro, M; Peralta, L; Petrovykh, L P; Pimenta, M; Poropat, P; Prest, M; Read, A L; Romero, A; Shalanda, N A; Simonetti, L; Skaali, T B; Stugu, B; Terranova, F; Tomé, B; Torassa, E; Trapani, P P; Verardi, M G; Vallazza, E; Vlasov, E; Zaitsev, A

1998-01-01

The small angle tile calorimeter (STIC) provides calorimetric coverage in the very forward region of the DELPHI experiment at the CERN LEP collider. The structure of the calorimeters, built with so- called "shashlik" technique, $9 allows the insertion of tracking detectors within the sampling structure, in order to make it possible to determine the direction of the showering particle. Presented here are some results demonstrating the performance of the $9 calorimeter and of these tracking detectors at LEP. (5 refs).

Small-angle neutron-scattering studies of the magnetic phase diagram of MnSi

DEFF Research Database (Denmark)

Harris, P.; Lebech, B.; Hae Seop Shim

1995-01-01

The antiferromagnetic order of MnSi has been studied as function of temperature and applied magnetic field using small-angle neutron scattering. The results were analyzed using the three-dimensional resolution function and the scattering cross-section to model the diffraction data. Physical...

Wide-Area Assessment of Aperiodic Small Signal Rotor Angle Stability in Real-Time

DEFF Research Database (Denmark)

Jóhannsson, Hjörtur; Nielsen, Arne Hejde; Østergaard, Jacob

2014-01-01

in rotor angle and a loss of synchronism, referred to as aperiodic small signal instability. The paper provides the theoretical background of the method and an analytical assessment criterion. Furthermore, a mathematical mapping of the generators' operating points that enables informative visualization...

Structure of unilamellar vesicles: Numerical analysis based on small-angle neutron scattering data

International Nuclear Information System (INIS)

Zemlyanaya, E. V.; Kiselev, M. A.; Zbytovska, J.; Almasy, L.; Aswal, V. K.; Strunz, P.; Wartewig, S.; Neubert, R.

2006-01-01

The structure of polydispersed populations of unilamellar vesicles is studied by small-angle neutron scattering for three types of lipid systems, namely, single-, two-and four-component vesicular systems. Results of the numerical analysis based on the separated-form-factor model are reported

Calculation of atom ranges in solids for quasi-small-angle scattering

International Nuclear Information System (INIS)

Pustovit, A.N.

2004-01-01

A formula for quasi-small-angle scattering of atomic particle and power law interaction potential have been used for the calculation of the differential cross-section, elastic stopping cross-section and a mean projected range in a solid. It is found that the limit energy transfer in the collisions depends on the screening of the power law interaction potentials. The calculated mean ranges in matter are compared with experimental data [ru

TILT ANGLE AND FOOTPOINT SEPARATION OF SMALL AND LARGE BIPOLAR SUNSPOT REGIONS OBSERVED WITH HMI

International Nuclear Information System (INIS)

McClintock, B. H.; Norton, A. A.

2016-01-01

We investigate bipolar sunspot regions and how tilt angle and footpoint separation vary during emergence and decay. The Helioseismic and Magnetic Imager on board the Solar Dynamic Observatory collects data at a higher cadence than historical records and allows for a detailed analysis of regions over their lifetimes. We sample the umbral tilt angle, footpoint separation, and umbral area of 235 bipolar sunspot regions in Helioseismic and Magnetic Imager—Debrecen Data with an hourly cadence. We use the time when the umbral area peaks as time zero to distinguish between the emergence and decay periods of each region and we limit our analysis of tilt and separation behavior over time to within ±96 hr of time zero. Tilt angle evolution is distinctly different for regions with small (≈30 MSH), midsize (≈50 MSH), and large (≈110 MSH) maximum umbral areas, with 45 and 90 MSH being useful divisions for separating the groups. At the peak umbral area, we determine median tilt angles for small (7.°6), midsize (5.°9), and large (9.°3) regions. Within ±48 hr of the time of peak umbral area, large regions steadily increase in tilt angle, midsize regions are nearly constant, and small regions show evidence of negative tilt during emergence. A period of growth in footpoint separation occurs over a 72-hr period for all of the regions from roughly 40 to 70 Mm. The smallest bipoles (<9 MSH) are outliers in that they do not obey Joy's law and have a much smaller footpoint separation. We confirm the Muñoz-Jaramillo et al. results that the sunspots appear to be two distinct populations

On the study of the transfer ionization reactions at super small scattering angles

International Nuclear Information System (INIS)

Popov, Yu.V.; Chuluunbaatar, O.; Vinitskij, S.I.; Ancarani, L.U.; Dal Cappello, C.; Vinitskij, P.S.

2002-01-01

The hypothesis that the reaction p + He → H + He ++ + e at super small scattering angles of hydrogen can be used for purposes of the angular spectroscopy of electron-electron correlations in the target is considered. It is shown that this hypothesis is untenable

On the Study of the Transfer Ionization Reactions at Super Small Scattering Angles

CERN Document Server

Popov, Yu V; Vinitsky, S I; Ancarani, L U; Dal Cappello, C; Vinitsky, P S

2002-01-01

The hypothesis that the reaction p + He\\to H + He^{++} + e at super small scattering angles of hydrogen can be used for purposes of the angular spectroscopy of electron-electron correlations in the target is considered. It is shown that this hypothesis is insolvent.

Cylindrical aggregates of chlorophylls studied by small-angle neutron scatter

Energy Technology Data Exchange (ETDEWEB)

Worcester, D.L. [Univ. of Missouri, Columbus, MO (United States); Katz, J.J. [Argonne National Laboratory, IL (United States)

1994-12-31

Neutron small-angle scattering has demonstrated tubular chlorophyll aggregates formed by self-assembly of a variety of chlorophyll types in nonpolar solvents. The size and other properties of the tubular aggregates can be accounted for by stereochemical properties of the chlorophyll molecules. Features of some of the structures are remarkably similar to light harvesting chlorophyll complexes in vivo, particularly for photosynthetic bacteria. These nanotube chlorophyll structures may have applications as light harvesting biomaterials where efficient energy transfer occurs from an excited state which is highly delocalized.

A small-angle scattering study of bacteriophage T7 using synchrotron radiation

International Nuclear Information System (INIS)

Feigin, L.A.; Svergun, D.I.; Dembo, A.T.; Ronto, G.; Toth, K.

1989-01-01

Structure transitions in the bacterial virus T7, due to an environment of varying ionic strength, are investigated by means of synchrotron radiation small-angle scattering. Effects of radiation damages and kinetics of the structure transition are separated. Time dependencies of the structural parameters and distribution functions are obtained and characteristic features of the structure rearrangements are described. (orig.)

Small-angle neutron scattering at pulsed spallation sources

International Nuclear Information System (INIS)

Seeger, P.A.; Hjelm, R.P. Jr.

1991-01-01

The importance of small-angle neutron scattering (SANS) in biological, chemical, physical and engineering research mandates that all intense neutron sources be equipped with SANS instruments. Four existing instruments at pulsed sources are described and the general differences between pulsed-source and reactor-based instrument designs are discussed. The basic geometries are identical, but dynamic range is generally achieved by using a broad band of wavelengths (with time-of-flight analysis) rather than by moving the detector. This allows optimization for maximum beam intensity at a given beam size over the full dynamic range with fixed collimation. Data-acquisition requirements at a pulsed source are more severe, requiring large fast histrograming memories. Data reduction is also more complex, as all wavelength-dependent and angle-dependent backgrounds and nonlinearities must be accounted for before data can be transformed to intensity vs momentum transfer (Q). A comparison is shown between the Los Alamos pulsed instrument and D11 (Institut Laue-Langevin) and examples from the four major topics of the conference are shown. The general conclusion is that reactor-based instruments remain superior at very low Q or if only a narrow range of Q is required, but that the current generation of pulsed-source instruments is competitive of moderate Q and may be faster when a wide range of Q is required. (orig.)

ORNL 10-m small-angle X-ray scattering camera

International Nuclear Information System (INIS)

Hendricks, R.W.

1979-12-01

A new small-angle x-ray scattering camera utilizing a rotating anode x-ray source, crystal monochromatization of the incident beam, pinhole collimation, and a two-dimensional position-sensitive proportional counter was developed. The sample, and the resolution element of the detector are each approximately 1 x 1 mm 2 , the camera was designed so that the focal spot-to-sample and sample-to-detector distances may each be varied in 0.5-m increments up to 5 m to provide a system resolution in the range 0.5 to 4.0 mrad. A large, general-purpose specimen chamber has been provided into which a wide variety of special-purpose specimen holders can be mounted. The detector has an active area of 200 x 200 mm and has up to 200 x 200 resolution elements. The data are recorded in the memory of a minicomputer by a high-speed interface which uses a microprocessor to map the position of an incident photon into an absolute minicomputer memory address. The data recorded in the computer memory can be processed on-line by a variety of programs designed to enhance the user's interaction with the experiment. At the highest angular resolution (0.4 mrad), the flux incident on the specimen is 1.0 x 10 6 photons/s with the x-ray source operating at 45 kV and 100 mA. SAX and its associated programs OVF and MOT are high-priority, pre-queued, nonresident foreground tasks which run under the ModComp II MAX III operating system to provide complete user control of the ORNL 10-m small-angle x-ray scattering camera

The small angle tile calorimeter in the DELPHI experiment

International Nuclear Information System (INIS)

Alvsvaag, S.J.; Bari, M.; Barreira, G.; Benvenuti, A.C.; Bigi, M.; Bonesini, M.; Bozzo, M.; Camporesi, T.; Carling, H.; Cassio, V.; Castellani, L.; Cereseto, R.; Chignoli, F.; Della Ricca, G.; Dharmasiri, D.R.; Santo, M.C. Espirito; Falk, E.; Fenyuk, A.; Ferrari, P.; Gamba, D.; Giordano, V.; Gouz, Yu.; Guerzoni, M.; Gumenyuk, S.; Hedberg, V.; Jarlskog, G.; Karyukhin, A.; Klovning, A.; Konoplyannikov, A.; Kronkvist, I.; Lanceri, L.; Leoni, R.; Maeland, O.A.; Maio, A.; Mazza, R.; Migliore, E.; Navarria, F.L.; Negri, P.; Nossum, B.; Obraztsov, V.; Onofre, A.; Paganoni, M.; Pegoraro, M.; Peralta, L.; Petrovykh, L.; Pimenta, M.; Poropat, P.; Prest, M.; Read, A.L.; Romero, A.; Shalanda, N.; Simonetti, L.; Skaali, T.B.; Stugu, B.; Terranova, F.; Tome, B.; Torassa, E.; Trapani, P.P.; Verardi, M.G.; Vallazza, E.; Vlasov, E.; Zaitsev, A.

1999-01-01

The Small angle TIle Calorimeter (STIC) provides calorimetric coverage in the very forward region of the DELPHI experiment at the CERN LEP collider. The structure of the calorimeters, built with a so-called 'shashlik' technique, gives a perfectly hermetic calorimeter and still allows for the insertion of tracking detectors within the sampling structure to measure the direction of the showering particle. A charged-particle veto system, composed of two scintillator layers, makes it possible to trigger on single photon events and provides e-γ separation. Results are presented from the extensive studies of these detectors in the CERN testbeams prior of installation and of the detector performance at LEP

A small-angle camera for resonant scattering experiments at the storage ring DORIS

International Nuclear Information System (INIS)

Stuhrmann, H.B.; Gabriel, A.

1983-01-01

Resonant small-angle scattering is measured routinely in the wavelength range of 0.6 to 3.25 A with the instrument X15 at the storage ring DORIS. The monochromatic beam with a vertical offset of 1.22 m is achieved by a double monochromator system with a constant exit slit. The small-angle instrument allows for sample-detector distances between 0.37 and 7.33 m. A multiwire proportional counter with a sensitive area of 200 X 200 mm detects the scattered intensity with a spatial resolution of 2 X 2 mm. Its sensitivity can be adapted to the requirements of the experiment by activating a drift chamber of 8 cm depth at the back end of the detector. The performance of the instrument as a function of the wavelength is described. The energy resolution is about 1 eV at the L 3 absorption edge of caesium, as shown by the resonant scattering of ferritin in 30% CsCl solution. (Auth.)

Small-angle x-ray scattering from the early growth stages of zeolite A

International Nuclear Information System (INIS)

Singh, P.; White, J.

1999-01-01

Full text: The work presented here with the use of SAXS (Small-Angle X-ray Scattering) is in attempt to identify a different paradigm to the organic template induced crystallization of zeolites, in particular zeolite 'A'. The reactions have been followed by small angle X-ray scattering from the time of first mixing of the constituents until the final separation of zeolite A crystals. The processes happening during the growth are expected to follow successive transformation of intermediate metastable phases until the formation of thermodynamically most stable phase and scattering signatures from these developments may be useful for extracting interesting information about the processes in situ. The scattering functions from a synthesis system of zeolite 'A' at the initial and final stage of reaction are presented.The different growth processes of zeolite 'A' from different silicate and aluminium sources are found. The differences are attributed to different rate limiting steps in the syntheses

Small-Angle Neutron Scattering investigations of ferrofluids with different carrier liquids

International Nuclear Information System (INIS)

Balasoiu, M.; Avdeev, M. V.; Hasegan, D.; Ghenescu, V.; Ghenescu, M.; Bica, D.; Vekas, L.

2004-01-01

The aim of this paper is to present a method to investigate the properties of magnetic fluids by means of small angle neutron scattering (SANS). Ferrofluids are dispersions of small, single-domain magnetic particles suspended in a fluid carrier. The neutron scattering methods have been largely used the last two decades for the determination of structural properties of magnetic liquids at microscopic level. There can be investigated the structure of the particle, the aggregation phenomena, the magnetic liquid dynamics, particle-surfactant interaction, surfactant liquid-base interaction and structure and magnetic behavior of the samples. SANS is often used in structural studies of ferrofluids exploring two specific features of neutrons, the possibility of wide contrast variation using protonated/deuterated components and high magnetic scattering from ferromagnetics. This method can be effectively used for determination of the structural parameters of ferrofluids at the scale interval of 1-100 nm. In previous SANS experiments with ferrofluids of the same type it was shown that the nuclear scattering is described well by the spherical core-shell model (magnetite core plus surfactant shell) in a wide interval of momentum transfer (0.05 - 5 nm -1 ) and no significant effects of aggregation and interparticle interaction were observed in this interval for the magnetite concentration up to 5 vol. %. Experiments on small angle neutron scattering were carried out on SANS instrument YuMO in function at IBR-2 high pulsed reactor at the Frank Laboratory of Neutron Physics, Joint Institute of Nuclear Research, Dubna, Russia. (authors)

A compact solid-state detector for small angle particle tracking

International Nuclear Information System (INIS)

Altieri, S.; Barnaba, O.; Braghieri, A.; Cambiaghi, M.; Lanza, A.; Locatelli, T.; Panzeri, A.; Pedroni, P.; Pinelli, T.; Jennewein, P.; Lang, M.; Preobrazhensky, I.; Annand, J.R.M.; Sadiq, F.

2000-01-01

MIcrostrip Detector Array System (MIDAS) is a compact silicon-tracking telescope for charged particles emitted at small angles in intermediate energy photonuclear reactions. It was realized to increase the angular acceptance of the DAPHNE detector and used in an experimental program to check the Gerasimov-Drell-Hearn sum rule at the Mainz electron microtron (MAMI). MIDAS provides a trigger for charged hadrons, p/π ± identification and particle tracking in the region 7 deg. <θ<16 deg.. In this paper we present the main characteristics of MIDAS and its measured performances

A compact solid-state detector for small angle particle tracking

Energy Technology Data Exchange (ETDEWEB)

Altieri, S.; Barnaba, O.; Braghieri, A. E-mail: alessandro.braghieri@pv.infn.it; Cambiaghi, M.; Lanza, A.; Locatelli, T.; Panzeri, A.; Pedroni, P.; Pinelli, T.; Jennewein, P.; Lang, M.; Preobrazhensky, I.; Annand, J.R.M.; Sadiq, F

2000-09-21

MIcrostrip Detector Array System (MIDAS) is a compact silicon-tracking telescope for charged particles emitted at small angles in intermediate energy photonuclear reactions. It was realized to increase the angular acceptance of the DAPHNE detector and used in an experimental program to check the Gerasimov-Drell-Hearn sum rule at the Mainz electron microtron (MAMI). MIDAS provides a trigger for charged hadrons, p/{pi}{sup {+-}} identification and particle tracking in the region 7 deg. <{theta}<16 deg.. In this paper we present the main characteristics of MIDAS and its measured performances.

The polarized neutron small-angle scattering instrument at BENSC Berlin

International Nuclear Information System (INIS)

Keller, T.; Krist, T.; Danzig, A.; Keiderling, U.; Mezei, F.; Wiedenmann, A.

2000-01-01

A polarized neutron beam has been installed at the small-angle neutron-scattering instrument V4 at BENSC Berlin. The main component of this new option is a 1.8 m long cavity transmission polarizer. The advantages of this device compared to the conventional bender polarizers are: (i) high transmission (35% of unpolarized beam at λ=6 A); (ii) the polarization is better than 93% in the wavelength band 4 A 3 O 4 particles embedded in a glass matrix) are presented and compared to a measurement with unpolarized neutrons

Performance of silicon pixel detectors at small track incidence angles for the ATLAS Inner Tracker upgrade

Energy Technology Data Exchange (ETDEWEB)

Viel, Simon, E-mail: sviel@lbl.gov [Physics Division, Lawrence Berkeley National Laboratory and University of California, Berkeley, CA, United States of America (United States); Banerjee, Swagato [Department of Physics, University of Wisconsin, Madison, WI, United States of America (United States); Brandt, Gerhard; Carney, Rebecca; Garcia-Sciveres, Maurice [Physics Division, Lawrence Berkeley National Laboratory and University of California, Berkeley, CA, United States of America (United States); Hard, Andrew Straiton; Kaplan, Laser Seymour; Kashif, Lashkar [Department of Physics, University of Wisconsin, Madison, WI, United States of America (United States); Pranko, Aliaksandr [Physics Division, Lawrence Berkeley National Laboratory and University of California, Berkeley, CA, United States of America (United States); Rieger, Julia [Physics Division, Lawrence Berkeley National Laboratory and University of California, Berkeley, CA, United States of America (United States); II Physikalisches Institut, Georg-August-Universität, Göttingen (Germany); Wolf, Julian [Physics Division, Lawrence Berkeley National Laboratory and University of California, Berkeley, CA, United States of America (United States); Wu, Sau Lan; Yang, Hongtao [Department of Physics, University of Wisconsin, Madison, WI, United States of America (United States)

2016-09-21

In order to enable the ATLAS experiment to successfully track charged particles produced in high-energy collisions at the High-Luminosity Large Hadron Collider, the current ATLAS Inner Detector will be replaced by the Inner Tracker (ITk), entirely composed of silicon pixel and strip detectors. An extension of the tracking coverage of the ITk to very forward pseudorapidity values is proposed, using pixel modules placed in a long cylindrical layer around the beam pipe. The measurement of long pixel clusters, detected when charged particles cross the silicon sensor at small incidence angles, has potential to significantly improve the tracking efficiency, fake track rejection, and resolution of the ITk in the very forward region. The performance of state-of-the-art pixel modules at small track incidence angles is studied using test beam data collected at SLAC and CERN. - Highlights: • Extended inner pixel barrel layers are proposed for the ATLAS ITk upgrade. • Test beam results at small track incidence angles validate this ATLAS ITk design. • Long pixel clusters are reconstructed with high efficiency at low threshold values. • Excellent angular resolution is achieved using pixel cluster length information.

Performance of silicon pixel detectors at small track incidence angles for the ATLAS Inner Tracker upgrade

International Nuclear Information System (INIS)

Viel, Simon; Banerjee, Swagato; Brandt, Gerhard; Carney, Rebecca; Garcia-Sciveres, Maurice; Hard, Andrew Straiton; Kaplan, Laser Seymour; Kashif, Lashkar; Pranko, Aliaksandr; Rieger, Julia; Wolf, Julian; Wu, Sau Lan; Yang, Hongtao

2016-01-01

In order to enable the ATLAS experiment to successfully track charged particles produced in high-energy collisions at the High-Luminosity Large Hadron Collider, the current ATLAS Inner Detector will be replaced by the Inner Tracker (ITk), entirely composed of silicon pixel and strip detectors. An extension of the tracking coverage of the ITk to very forward pseudorapidity values is proposed, using pixel modules placed in a long cylindrical layer around the beam pipe. The measurement of long pixel clusters, detected when charged particles cross the silicon sensor at small incidence angles, has potential to significantly improve the tracking efficiency, fake track rejection, and resolution of the ITk in the very forward region. The performance of state-of-the-art pixel modules at small track incidence angles is studied using test beam data collected at SLAC and CERN. - Highlights: • Extended inner pixel barrel layers are proposed for the ATLAS ITk upgrade. • Test beam results at small track incidence angles validate this ATLAS ITk design. • Long pixel clusters are reconstructed with high efficiency at low threshold values. • Excellent angular resolution is achieved using pixel cluster length information.

Topological investigation of electronic silicon nanoparticulate aggregates using ultra-small-angle X-ray scattering

CSIR Research Space (South Africa)

Jonah, EO

2012-10-01

Full Text Available The network topology of two types of silicon nanoparticles, produced by high energy milling and pyrolysis of silane, in layers deposited from inks on permeable and impermeable substrates has been quantitatively characterized using ultra-small-angle...

Bacteriophage T7 structure according to the data of small-angle X-ray scattering

Energy Technology Data Exchange (ETDEWEB)

Rol' bin, Yu A; Svergun, D I; Feigin, L A; Gashpar, Sh; Ronto, D [AN SSSR, Moscow. Inst. Kristallografii

1980-01-01

An attempt is made to obtain complete data on the form, sizes, weight and hydration of the T7 bacteriophage cultivated on E.coli cells and the peculiarities of phage DNA structure using the method of small-angle scattering.

Structure of fullerene aggregates in pyridine/water solutions by small-angle neutron scattering

International Nuclear Information System (INIS)

Aksenov, V.L.; Belushkin, A.V.; Avdeev, M.V.; Rosta, L.; Mihailovic, D.; Mrzel, A.; Serdyuk, I.N.; Timchenko, A.A.

2001-01-01

Results of small-angle neutron scattering experiments on fullerenes (C 60 ) in pyridine/water solutions are reported. They confirm conclusions of the previous studies, in particular, dynamic light scattering experiments. Aggregates with characteristic radius of about 20 nm are formed in the solutions. The contrast variation using different combinations of protonated/deuterated components (water and pyridine) of the solutions points to the small pyridine content inside the aggregates. This fact testifies that the aggregates consist of a massive fullerene core covered by a thin pyridine shell

Small-angle neutron scattering at pulsed spallation sources

International Nuclear Information System (INIS)

Seeger, P.A.; Hjelm, R.P. Jr.

1990-01-01

The importance of small-angle neutron scattering (SANS) in biological, chemical, physical, and engineering research mandates that all intense neutron sources be equipped with SANS instruments. Four existing instruments are described, and the general differences between pulsed-source and reactor-based instrument designs are discussed. The basic geometries are identical, but dynamic range is achieved by using a broad band of wavelengths (with time-of-flight analysis) rather than by moving the detector. This allows a more optimized collimation system. Data acquisition requirements at a pulsed source are more severe, requiring large, fast histogramming memories. Data reduction is also more complex, as all wave length-dependent and angle-dependent backgrounds and non-linearities must be accounted for before data can be transformed to intensity vs Q. A comparison is shown between the Los Alamos pulsed instrument and D-11 (Institute Laue-Langevin), and examples from the four major topics of the conference are shown. The general conclusion is that reactor-based instruments remain superior at very low Q or if only a narrow range of Q is required, but that the current generation of pulsed-source instruments is competitive at moderate Q and may be faster when a wide range of Q is required. In principle, a user should choose which facility to use on the basis of optimizing the experiment; in practice the tradeoffs are not severe and the choice is usually made on the basis of availability

2017 publication guidelines for structural modelling of small-angle scattering data from biomolecules in solution: an update.

Science.gov (United States)

Trewhella, Jill; Duff, Anthony P; Durand, Dominique; Gabel, Frank; Guss, J Mitchell; Hendrickson, Wayne A; Hura, Greg L; Jacques, David A; Kirby, Nigel M; Kwan, Ann H; Pérez, Javier; Pollack, Lois; Ryan, Timothy M; Sali, Andrej; Schneidman-Duhovny, Dina; Schwede, Torsten; Svergun, Dmitri I; Sugiyama, Masaaki; Tainer, John A; Vachette, Patrice; Westbrook, John; Whitten, Andrew E

2017-09-01

In 2012, preliminary guidelines were published addressing sample quality, data acquisition and reduction, presentation of scattering data and validation, and modelling for biomolecular small-angle scattering (SAS) experiments. Biomolecular SAS has since continued to grow and authors have increasingly adopted the preliminary guidelines. In parallel, integrative/hybrid determination of biomolecular structures is a rapidly growing field that is expanding the scope of structural biology. For SAS to contribute maximally to this field, it is essential to ensure open access to the information required for evaluation of the quality of SAS samples and data, as well as the validity of SAS-based structural models. To this end, the preliminary guidelines for data presentation in a publication are reviewed and updated, and the deposition of data and associated models in a public archive is recommended. These guidelines and recommendations have been prepared in consultation with the members of the International Union of Crystallography (IUCr) Small-Angle Scattering and Journals Commissions, the Worldwide Protein Data Bank (wwPDB) Small-Angle Scattering Validation Task Force and additional experts in the field.

The small angle tile calorimeter in the DELPHI experiment

CERN Document Server

Alvsvaag, S J; Barreira, G; Benvenuti, Alberto C; Bigi, M; Bonesini, M; Bozzo, M; Camporesi, T; Carling, H; Cassio, V; Castellani, L; Cereseto, R; Chignoli, F; Della Ricca, G; Dharmasiri, D R; Espirito-Santo, M C; Falk, E; Fenyuk, A; Ferrari, P; Gamba, D; Giordano, V; Guz, Yu; Guerzoni, M; Gumenyuk, S A; Hedberg, V; Jarlskog, G; Karyukhin, A N; Klovning, A; Konoplyannikov, A K; Kronkvist, I J; Lanceri, L; Leoni, R; Maeland, O A; Maio, A; Mazza, R; Migliore, E; Navarria, Francesco Luigi; Negri, P; Nossum, B; Obraztsov, V F; Onofre, A; Paganoni, M; Pegoraro, M; Peralta, L; Petrovykh, L P; Pimenta, M; Poropat, P; Prest, M; Read, A L; Romero, A; Shalanda, N A; Simonetti, L; Skaali, T B; Stugu, B; Terranova, F; Tomé, B; Torassa, E; Trapani, P P; Verardi, M G; Vallazza, E; Vlasov, E; Zaitsev, A

1999-01-01

The {\\bf S}mall angle {\\bf TI}le {\\bf C}alorimeter ({\\bf STIC}) provides calorimetric coverage in the very forward region of the DELPHI experiment at the CERN LEP collider. The structure of the calorimeters, built with a so-called ``shashlik'' technique, gives a perfectly hermetic calorimeter and still allows for the insertion of tracking detectors within the sampling structure to measure the direction of the showering particle. A charged-particle veto system, composed of two scintillator layers, makes it possible to trigger on single photon events and provides e-$\\gamma$ separat ion. Results are presented from the extensive studies of these detectors in the CERN testbeams prior to installation and of the detector performance at LEP.

Small angle neutron scattering form polymer melts: structural investigation and phase behaviour

International Nuclear Information System (INIS)

Ertugrul, O.

2004-01-01

The Small-Angle Neutron Scattering (SANS) techniques have been used to study the structural properties and phase behavior of polymer melts. A model based on Random Phase Approximation (RPA) is proposed to predict the experimental data. By fitting the model to data we could be able to obtain radius of gyration (a measure of size of a polymer) and phase transition for the sample. (author)

Study of humic acids by small-angle X-ray and neutron scattering

International Nuclear Information System (INIS)

Timchenko, A.; Trubetskaya, O.; Kihara, H.

1999-01-01

Humic acids are an important component of natural ecological system and represent a polydisperse complex of natural biopolymers with molecular masses from several to hundreds kilodaltons. They are both a source of organic compounds and a protector against anthropogenic pollutions of biosphere. The aim of the report is to underline some possibilities of small-angle X-ray and neutron scattering to study HA and their fractions. (author)

Investigation of digestion Kinetics in commercial starches using in-situ small-angle neutron scattering

International Nuclear Information System (INIS)

Blazek, Jaroslav; Gilbert, Elliot Paul

2009-01-01

Full text: The digestion of starch has been the subject of many investigations, mostly involving in vitro measurement of the susceptibility of starches to attack by different enzymes, rather than measuring actual digestibility in vivo. The rate and extent of amylolytic hydrolysis of granular starches is known to vary according to botanical origin. Granule characteristics considered to influence susceptibility to attack by alpha-amylase include crystallinity, granule size and available specific surface, amylose content, porosity, structural inhomogeneities and degree of integrity. Most in-vitro studies of granular starch digestion have been limited to samples for which aliquots have been removed from the reaction mixture at various time intervals and freeze-dried to be subsequently characterized using a range of techniques. It remains unclear whether sample preparation creates artefacts in the samples. In this study, we have studied the kinetics of starch digestion of several commercial granular starches by time-resolved small-angle neutron scattering using an in-situ digestion chamber allowing, for the first time, to follow structural changes of starch in the course of digestion directly in the digestion mixture. Additionally, samples before and after digestion were studied by x-ray diffraction, small-angle x-ray scattering, differential scanning calorimetry and microscopy. Microscopy revealed that studied starches, which varied in their amylose content and digestion kinetics, followed different modes of attack The multidisciplinary approach allowed the nanostructural changes detected by small-angle scattering in the course of enzymic breakdown to be correlated with changes in crystallinity and functional properties.

Small angle neutron scattering measurements of magnetic cluster sizes in magnetic recorging disks

CERN Document Server

Toney, M

2003-01-01

We describe Small Angle Neutron Scattering measurements of the magnetic cluster size distributions for several longitudinal magnetic recording media. We find that the average magnetic cluster size is slightly larger than the average physical grain size, that there is a broad distribution of cluster sizes, and that the cluster size is inversely correlated to the media signal-to-noise ratio. These results show that intergranular magnetic coupling in these media is small and they provide empirical data for the cluster-size distribution that can be incorporated into models of magnetic recording.

Conformation of comb liquid crystal polymers by neutron small angle scattering

International Nuclear Information System (INIS)

Noirez, L.; Pepy, G.

1988-01-01

A review is made of the direct information obtained by small angle neutron scattering about the anisotropy of the components parallel and perpendicular to the orienting magnetic field of the radius of gyration of comb like liquid crystal polymers. The behaviour of the conformation versus temperature is reported for several samples. Until now all samples show an oblate conformation in the smectic phase and probably the whole range of the nematic phase. The results are compared with the available theoretical predictions

A particle-in-cell method for modeling small angle Coulomb collisions in plasmas

International Nuclear Information System (INIS)

Parker, S.E.

1989-01-01

We propose a computational method to self-consistently model small angle collisional effects. This method may be added to standard Particle-In-Cell (PIC) plasma simulations to include collisions, or as an alternative to solving the Fokker-Planck (FP) equation using finite difference methods. The distribution function is represented by a large number of particles. The particle velocities change due to the drag force, and the diffusion in velocity is represented by a random process. This is similar to previous Monte-Carlo methods except we calculate the drag force and diffusion tensor self- consistently. The particles are weighted to a grid in velocity space and associated ''Poisson equations'' are solved for the Rosenbluth potentials. The motivation is to avoid the very time consuming method of Coulomb scattering pair by pair. First the approximation for small angle Coulomb collisions is discussed. Next, the FP-PIC collision method is outlined. Then we show a test of the particle advance modeling an electron beam scattering off a fixed ion background. 4 refs

X-ray and neutron small-angle scattering studies of human serum lipoproteins

International Nuclear Information System (INIS)

Luzzati, V.; Tardieu, A.; Mateu, L.; Sardet, C.; Stuhrmann, H.B.; Aggerbeck, L.; Scanu, A.M.

1976-01-01

The paper describes an extended x-ray study of two types of human serum lipoproteins and a neutron study of one of them. The results are similar and to some extent complementary. Serum lipoproteins provide an excellent illustration of the wealth of information that can be obtained by a small-angle scattering approach to the structure of particles with non-uniform density distribution, by using solvents of variable density

Small-angle neutron scattering investigations of Co-doped iron oxide nanoparticles. Preliminary results

Science.gov (United States)

Creanga, Dorina; Balasoiu, Maria; Soloviov, Dmitro; Balasoiu-Gaina, Alexandra-Maria; Puscasu, Emil; Lupu, Nicoleta; Stan, Cristina

2018-03-01

Preliminary small-angle neutron scattering investigations on aqueous suspensions of several cobalt doped ferrites (CoxFe3-xO4, x=0; 0.5; 1) nanoparticles prepared by chemical co-precipitation method, are reported. The measurements were accomplished at the YuMO instrument in function at the IBR-2 reactor. Results of intermediary data treatment are presented and discussed.

Investigation of nanoscale structures by small-angle X-ray scattering in a radiochromic dosimeter

DEFF Research Database (Denmark)

Skyt, Peter Sandegaard; Jensen, Grethe Vestergaard; Wahlstedt, Isak Hannes

2014-01-01

This study examines the nanoscale structures in a radiochromic dosimeter that was based on leuco-malachite-green dye and the surfactant sodium dodecyl sulfate (SDS) suspended in a gelatin matrix. Small-angle X-ray scattering was used to investigate the structures of a range of compositions...

Small angle neutron scattering

Directory of Open Access Journals (Sweden)

Cousin Fabrice

2015-01-01

Full Text Available Small Angle Neutron Scattering (SANS is a technique that enables to probe the 3-D structure of materials on a typical size range lying from ∼ 1 nm up to ∼ a few 100 nm, the obtained information being statistically averaged on a sample whose volume is ∼ 1 cm3. This very rich technique enables to make a full structural characterization of a given object of nanometric dimensions (radius of gyration, shape, volume or mass, fractal dimension, specific area… through the determination of the form factor as well as the determination of the way objects are organized within in a continuous media, and therefore to describe interactions between them, through the determination of the structure factor. The specific properties of neutrons (possibility of tuning the scattering intensity by using the isotopic substitution, sensitivity to magnetism, negligible absorption, low energy of the incident neutrons make it particularly interesting in the fields of soft matter, biophysics, magnetic materials and metallurgy. In particular, the contrast variation methods allow to extract some informations that cannot be obtained by any other experimental techniques. This course is divided in two parts. The first one is devoted to the description of the principle of SANS: basics (formalism, coherent scattering/incoherent scattering, notion of elementary scatterer, form factor analysis (I(q→0, Guinier regime, intermediate regime, Porod regime, polydisperse system, structure factor analysis (2nd Virial coefficient, integral equations, characterization of aggregates, and contrast variation methods (how to create contrast in an homogeneous system, matching in ternary systems, extrapolation to zero concentration, Zero Averaged Contrast. It is illustrated by some representative examples. The second one describes the experimental aspects of SANS to guide user in its future experiments: description of SANS spectrometer, resolution of the spectrometer, optimization of

Comparison of X-ray and neutron small-angle scattering from an Al-Zn alloy

International Nuclear Information System (INIS)

Gerold, V.; Epperson, J.E.; Gerstenberg, K.W.

1978-01-01

The normalized integrated small-angle scattered intensity for Al-Zn alloys should be independent of whether the measurements are made with X-rays or neutrons. In order to check this, and thus the correction and standardization processes, the small-angle scattering from an Al-5.05 at.% Zn alloy containing GP zones was measured with these two types of radiation. The data were corrected and converted to absolute units with reference to the commonly accepted secondary standards: vanadium for the neutron data and polyethylene (Lupolen) for the X-ray data. The results are shown to differ by, at best, 6% if reasonable values for the change in atomic volume with alloy composition are taken into account. These findings are compared with those available from the literature, and the consistency is found to be somewhat lacking. Additional careful work is clearly needed to determine if the difficulty is traceable to the data correction or to the conversion to absolute units. (Auth.)

A small angle neutron scattering study of thermoplastic elastomer

Energy Technology Data Exchange (ETDEWEB)

Sutiarso,; Edy Giri, R Putra; Andon, Insani; Sudirman,; Sudaryanto, [Materials Science Research Centre, National Atomic Energy Agency, Jakarta (Indonesia)

1998-10-01

A bilateral scientific cooperation, in the small angle neutron scattering has been agreed upon between CIAE, China and BATAN, Indonesia as well as MINT Malaysia. As stated in the agreed proposal that the objective of this cooperation, in the initial stage (stage-1), was to have a regional intercomparison measurements of SANS instruments in order to determine their characteristic/performance. Therefore, this report is supposed to describe the progress in the SANS instrument development of each country involved during the period of 1996/97 and some activities related to the SANS instrument. Since, up to now, we have not yet received any progresses reported from either China or Malaysia, this report will describe the progress of SANS`s activities in BATAN only. (author)

User's guide for the small-angle neutron scattering facility

International Nuclear Information System (INIS)

Vlak, W.A.H.M.; Werkhoven, E.J.

1989-04-01

This report serves as a manual for the users of the small-angle neutron scattering instrument located at beamport HB3 of the High Flux Reactor in Petten. The main part of the text is devoted to the control of the facility and the data handling by means of a μVAX computer. Also, the various possibilities to access the facility across computer networks are discussed. A collection of menu-driven and command-driven programs, which utilize the flexibility of the VMS operating system without requiring detailed knowledge of the user about the computer environment, enables to control the instrument. For the convenience of the experienced user, who might wish to update or extend the software, a technical supplement is included. 15 figs.; 8 refs

Small-angle neutron scattering study of high-pressure sintered detonation nanodiamonds

Energy Technology Data Exchange (ETDEWEB)

Kidalov, S. V.; Shakhov, F. M., E-mail: fedor.shakhov@mail.ioffe.ru [Ioffe Physical-Technical Institute of the Russian Academy of Sciences (Russian Federation); Lebedev, V. T.; Orlova, D. N.; Grushko, Yu. S. [Russian Academy of Sciences, Konstantinov St. Petersburg Nuclear Physics Institute (Russian Federation)

2011-12-15

The structure of detonation diamonds sintered at a high pressure (7 GPa) and temperatures of 1200-1700 Degree-Sign C has been investigated by small-angle neutron scattering. It is shown that sintering leads to an increase in the particle size from 6 to 30 nm and established that this increase is due to the chainlike oriented attachment of particles. This study supplements the oriented-attachment model, which was suggested based on the X-ray diffraction spectra of detonation nanodiamonds (DNDs) sintered under the same conditions.

Small Angle Neutron Scattering experiments on ``side-on fixed"" liquid crystal polyacrylates

Science.gov (United States)

Leroux, N.; Keller, P.; Achard, M. F.; Noirez, L.; Hardouin, F.

1993-08-01

Small Angle Neutron Scattering experiments were carried out on liquid crystalline “side-on fixed” polyacrylates : we observe that the polymer backbone adopts a prolate conformation in the nematic phase. Such anisotropy of the global backbone is larger for smaller spacer length. In every case we measure at low temperatures a large chain extension as previously described in polysiloxanes. Par diffusion des neutrons aux petits angles nous observons que la chaîne de polyacrylates “en haltère” adopte une conformation type prolate en phase nématique. Son anisotropie est d'autant plus grande que l'espaceur est plus court. Dans tous les cas, nous retrouvons à basse température la forte extension de la chaîne polymère qui fut d'abord révélée dans les polysiloxanes.

Small-angle and wide-angle X-ray scattering study on the bilayer structure of synthetic and bovine heart cardiolipins

International Nuclear Information System (INIS)

Takahashi, Hiroshi; Hayakawa, Tomohiro; Ito, Kazuki; Takata, Masaki; Kobayashi, Toshihide

2010-01-01

Cardiolipin (CL) is a membrane phospholipid containing four fatty acid chains. CL plays an important role in energy transformation in mitochondria. The disorder of CL biosynthesis is involved in a genetic disease, Barth syndrome. Alteration of fatty acid composition of CLs has been found in Barth syndrome patients, i.e., the decrease of unsaturated fatty acid chains. In this study, we investigated how the degree of saturation alters the structure of CL bilayers by using X-ray scattering. Bovine heart CL and two synthetic CLs were compared. Fatty acid compositions of these three CLs have different saturation. Small-angle X-ray scattering data showed that the decrease of the number of double bonds in the unsaturated fatty acid chains causes to thicken the CL bilayers. In addition, wide-angle X-ray scattering data suggested that the decrease reduces the degree of disorder of the hydrophobic region in a liquid crystalline phase. These results may be related to the dysfunction of mitochondria in Barth syndrome.

Small-angle and wide-angle X-ray scattering study on the bilayer structure of synthetic and bovine heart cardiolipins

Energy Technology Data Exchange (ETDEWEB)

Takahashi, Hiroshi [Biophysics Laboratory, Department of Chemistry and Chemical Biology, Gunma University, Maebashi, Gunma, 371-8510 (Japan); Hayakawa, Tomohiro [Life Science Laboratory, Advanced Materials Laboratories, Sony Corporation, Yushima, Bunkyo-ku, Tokyo, 113-8510 (Japan); Ito, Kazuki; Takata, Masaki [Structural Materials Science Laboratory, RIKEN SPring-8 Center, Sayo, Hyogo 679-5148 (Japan); Kobayashi, Toshihide, E-mail: htakahas@chem-bio.gunma-u.ac.j [Lipid Biology Laboratory, RIKEN, Wako, Saitama 351-0198 (Japan)

2010-10-01

Cardiolipin (CL) is a membrane phospholipid containing four fatty acid chains. CL plays an important role in energy transformation in mitochondria. The disorder of CL biosynthesis is involved in a genetic disease, Barth syndrome. Alteration of fatty acid composition of CLs has been found in Barth syndrome patients, i.e., the decrease of unsaturated fatty acid chains. In this study, we investigated how the degree of saturation alters the structure of CL bilayers by using X-ray scattering. Bovine heart CL and two synthetic CLs were compared. Fatty acid compositions of these three CLs have different saturation. Small-angle X-ray scattering data showed that the decrease of the number of double bonds in the unsaturated fatty acid chains causes to thicken the CL bilayers. In addition, wide-angle X-ray scattering data suggested that the decrease reduces the degree of disorder of the hydrophobic region in a liquid crystalline phase. These results may be related to the dysfunction of mitochondria in Barth syndrome.

Small angle neutron scattering investigations of spin disorder in nanocomposite soft magnets

International Nuclear Information System (INIS)

Vecchini, C.; Moze, O.; Suzuki, K.; Cadogan, J.M.; Pranzas, K.; Michels, A.; Weissmueller, J.

2006-01-01

The technique of SANS (small angle neutron scattering) furnishes unique information on the characteristic magnetic length scales and local magnetic anisotropies at the nanoscale in nanocomposite ferromagnets. Such information is not presently available using any other microscopic technique. The basic principles and results of the technique will be presented with regard to a unique and unexpected observation of a dipole field controlled spin disorder in a prototypical soft nanocomposite ferromagnet of the Nanoperm type

Integrative structural modeling with small angle X-ray scattering profiles

Directory of Open Access Journals (Sweden)

Schneidman-Duhovny Dina

2012-07-01

Full Text Available Abstract Recent technological advances enabled high-throughput collection of Small Angle X-ray Scattering (SAXS profiles of biological macromolecules. Thus, computational methods for integrating SAXS profiles into structural modeling are needed more than ever. Here, we review specifically the use of SAXS profiles for the structural modeling of proteins, nucleic acids, and their complexes. First, the approaches for computing theoretical SAXS profiles from structures are presented. Second, computational methods for predicting protein structures, dynamics of proteins in solution, and assembly structures are covered. Third, we discuss the use of SAXS profiles in integrative structure modeling approaches that depend simultaneously on several data types.

Modified small angle magnetization rotation method in multilayer magnetic microwires

International Nuclear Information System (INIS)

Torrejon, J.; Badini, G.; Pirota, K.; Vazquez, M.

2007-01-01

The small angle magnetization rotation (SAMR) technique is a widely used method to quantify magnetostriction in elongated ultrasoft magnetic materials. In the present work, we introduce significant optimization of the method, particularly simplification of the required equipment, profiting of the very peculiar characteristics of a recently introduced family of multilayer magnetic microwires consisting of a soft magnetic core, insulating intermediate layer and a hard magnetic outer layer. The introduced modified SAMR method is used not only to determine the saturation magnetostriction constant of the soft magnetic nucleus but also the magnetoelastic and magnetostatic coupling. This new method has a great potential in multifunctional sensor applications

Small-angle and surface scattering from porous and fractal materials.

Energy Technology Data Exchange (ETDEWEB)

Sinha, S. K.

1998-09-18

We review the basic theoretical methods used to treat small-angle scattering from porous materials, treated as general two-phase systems, and also the basic experimental techniques for carrying out such experiments. We discuss the special forms of the scattering when the materials exhibit mass or surface fractal behavior, and review the results of recent experiments on several types of porous media and also SANS experiments probing the phase behavior of binary fluid mixtures or polymer solutions confined in porous materials. Finally, we discuss the analogous technique of off-specular scattering from surfaces and interfaces which is used to study surface roughness of various kinds.

Exotic behavior of elastic scattering differential cross-sections of weakly bound nucleus 17F at small angles

International Nuclear Information System (INIS)

Han Jianlong; Hu Zhengguo; Zhang Xueyin; Yuan Xiaohua; Xu Huagen; Qi Huirong; Wang Yue; Jia Fei; Wu Lijie; Ding Xianli; Gao Qi; Gao Hui; Bai Zhen

2006-01-01

The differential cross-sections for elastic scattering of 17 F and 17 O on 208 Pb have been measured at Radioactive Ion Beam Line at Lanzhou (RIBLL). The variation of the logarithms of differential cross-sections with the square of scattering angles shows clearly that there exists a turning point in the range of small scattering angles (6 degree-20 degree) for 17 F having exotic structure, while no turning point was observed in the 17 O elastic scattering. The experimental results have been compared with previous data. Systematical analysis on the available data seems to conclude that there is an exotic behavior of elastic scattering differential cross-sections of weakly bound nuclei with halo or skin structure as compared with that of the ordinary nuclei near stable line. Therefore the fact that the turning point of the logarithms of differential cross-sections appears at small angle for weakly bound nuclei could be used as a new probe to investigate the halo and skin phenomenon. (authors)

Elucidation of density profile of self-assembled sitosterol + oryzanol tubules with small-angle neutron scattering

NARCIS (Netherlands)

Bot, A.; Gilbert, E.P.; Bouwman, W.G.; Sawalha, H.I.M.; Adel, den R.; Garamus, V.M.; Venema, P.; Linden, van der E.; Flöter, E.

2012-01-01

Small-angle neutron scattering (SANS) experiments have been performed on self-assembled tubules of sitosterol and oryzanol in triglyceride oils to investigate details of their structure. Alternative organic phases (deuterated and non-deuterated decane, limonene, castor oil and eugenol) were used to

Small angle X-ray scattering on concentrated hemoglobin solutions

International Nuclear Information System (INIS)

Zinke, M.; Damaschun, G.; Mueller, J.J.; Ruckpaul, K.

1978-01-01

The small-angle X-ray scattering technique was used to determine the intermolecular structure and interaction potentials in oxi-and deoxi-hemoglobin solutions. The pair correlation function obtained by the ZERNICKE-PRINS equation characterizes the intermolecular structure of the hemoglobin molecules. The intermolecular structure is concentration dependent. The hemoglobin molecules have a 'short range order structure' with a range of about 4 molecule diameters at 324 g/l. The potential functions of the hemoglobin-hemoglobin interaction have been determined on the basis of fluid theories. Except for the deoxi-hemoglobin solution having the concentration 370 g/l, the pair interaction consists in a short repulsion and a weak short-range attraction against kT. The potential minimum is between 1.2 - 1.5 nm above the greatest hemoglobin diameter. (author)

Small angle neutron scattering analysis programs on the Rutherford Laboratory IBM 360/195 computers

International Nuclear Information System (INIS)

Knowles, K.J.; Johnson, M.W.

1980-06-01

The implementation and operation of the suite of programs used for the analysis of small angle neutron scattering data originally written at the ILL (Grenoble) is described. The programs make use of a circulating data file which is also described and may be used by a variety of data analysis programs. (author)

What DELPHI can get with an upgraded position for the very small angle tagger

International Nuclear Information System (INIS)

Almehed, S.; Jarlskog, G.; Mjornmark, U.; Kapusta, F.; Tyapkin, I.A.; Zimin, N.I.

1997-01-01

A rather large profit can be obtained for two-photon physics studies with an upgrade of the DELPHI very small angle tagger position. Results have been obtained by using FASTSIM simulation both for double tagged and single tagged modes of γγ interactions, and for Bhabha events used for the luminosity measurements

Invisible detergents for structure determination of membrane proteins by small-angle neutron scattering

DEFF Research Database (Denmark)

Midtgaard, Søren Roi; Darwish, Tamim A.; Pedersen, Martin Cramer

2018-01-01

A novel and generally applicable method for determining structures of membrane proteins in solution via small-angle neutron scattering (SANS) is presented. Common detergents for solubilizing membrane proteins were synthesized in isotope-substituted versions for utilizing the intrinsic neutron sca...... solution structure determination of membrane proteins by SANS and subsequent data analysis available to non-specialists. This article is protected by copyright. All rights reserved....

Ordered array of ω particles in β-Ti matrix studied by small-angle X-ray scattering

International Nuclear Information System (INIS)

Šmilauerová, J.; Harcuba, P.; Stráský, J.; Stráská, J.; Janeček, M.; Pospíšil, J.; Kužel, R.; Brunátová, T.; Holý, V.; Ilavský, J.

2014-01-01

Nanosized particles of ω phase in a β-Ti alloy were investigated by small-angle X-ray scattering using synchrotron radiation. We demonstrated that the particles are spontaneously weakly ordered in a three-dimensional cubic array along the 〈100〉-directions in the β-Ti matrix. The small-angle scattering data fit well to a three-dimensional short-range-order model; from the fit we determined the evolution of the mean particle size and mean distance between particles during ageing. The self-ordering of the particles is explained by elastic interaction between the particles, since the relative positions of the particles coincide with local minima of the interaction energy. We performed numerical Monte Carlo simulation of the particle ordering and we obtained a good agreement with the experimental data

Structure factor of dimyristoylphosphatidylcholine unilamellar vesicles: small-angle x-ray scattering study

International Nuclear Information System (INIS)

Kiselev, M.A.; Aksenov, V.L.; Lombardo, D.; Kisselev, A.M.; Lesieur, P.

2003-01-01

Small-angle X-ray scattering (SAXS) experiments have been performed on dimyristoylphosphatidylcholine (DMPC) unilamellar vesicles in 40% aqueous sucrose solution. Model of separated form factors was applied for the evaluation of SAXS curves from large unilamellar vesicles. For the first time vesicle structure factor, polydispersity, average radius and membrane thickness were calculated simultaneously from the SAXS curves at T=30 deg C for DMPC concentrations in the range from 15 to 75 mM (1-5% w/w). Structure factor correction to the scattering curve was shown to be negligibly small for the lipid concentration of 15 mM (1% w/w). It was proved to be necessary to introduce structure factor correction to the scattering curves for lipid concentrations ≥ 30 mM (2% w/w)

Structure Factor of Dimyristoylphosphatidylcholine Unilamellar Vesicles Small-Angle X-Ray Scattering Study

CERN Document Server

Kiselev, M A; Kisselev, A M; Lesieur, P; Aksenov, V L

2003-01-01

Small-angle X-ray scattering (SAXS) experiments have been performed on dimyristoylphosphatidylcholine (DMPC) unilamellar vesicles in 40 % aqueous sucrose solution. Model of separated form factors was applied for the evaluation of SAXS curves from large unilamellar vesicles. For the first time vesicle structure factor, polydispersity, average radius and membrane thickness were calculated simultaneously from the SAXS curves at T=306{\\circ}C for DMPC concentrations in the range from 15 to 75 mM (1-5 % w/w). Structure factor correction to the scattering curve was shown to be negligibly small for the lipid concentration of 15 mM (1 % w/w). It was proved to be necessary to introduce structure factor correction to the scattering curves for lipid concentrations {\\ge}30 mM (2 % w/w).

Small-angle scattering study of mesoscopic structures in charged gel and their evolution on dehydration

DEFF Research Database (Denmark)

Sugiyama, Masaaki; Annaka, Masahiko; Hara, Kazuhiro

2003-01-01

Mesoscopic structures, with length scales similar to10(2) Angstrom, were investigated by small-angle X-ray and neutron scattering (SAXS and SANS) in several N-isopropylacrylamide-sodium acrylate (NIPA-SA) copolymeric hydrogels with varying [NIPA]/[SA] ratios and water contents. The SAXS experimen...

Influence of multiple small-angle neutron scattering on diffraction peak broadening in ferritic steel

Czech Academy of Sciences Publication Activity Database

Woo, W.; Em, V.; Shin, E.; Mikula, Pavol; Ryukhtin, Vasyl

2015-01-01

Roč. 48, APR (2015), s. 350-356 ISSN 0021-8898 R&D Projects: GA ČR GB14-36566G; GA MŠk(CZ) LM2011019 Institutional support: RVO:61389005 Keywords : peak broadening * small-angle neutron scattering * neutron diffraction * magnetic domain Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 3.720, year: 2014

Traceable size determination of PMMA nanoparticles based on Small Angle X-ray Scattering (SAXS)

Energy Technology Data Exchange (ETDEWEB)

Gleber, G; Cibik, L; Mueller, P; Krumrey, M [Physikalisch-Technische Bundesanstalt (PTB), Abbestrasse 2-12, 10587 Berlin (Germany); Haas, S; Hoell, A, E-mail: gudrun.gleber@ptb.d [Helmholtz-Zentrum-Berlin fuer Materialien und Energie (HZB), Albert-Einstein-Strasse 15, 12489 Berlin (Germany)

2010-10-01

The size and size distribution of PMMA nanoparticles has been investigated with SAXS (small angle X-ray scattering) using monochromatized synchrotron radiation. The uncertainty has contributions from the wavelength or photon energy of the radiation, the scattering angle and the fit procedure for the obtained scattering curves. The wavelength can be traced back to the lattice constant of silicon, and the scattering angle is traceable via geometric measurements of the detector pixel size and the distance between the sample and the detector. SAXS measurements and data evaluations have been performed at different distances and photon energies for two PMMA nanoparticle suspensions with low polydispersity and nominal diameters of 108 nm and 192 nm, respectively, as well as for a mixture of both. The relative variation of the diameters obtained for different experimental conditions was below {+-} 0.3 %. The determined number-weighted mean diameters of (109.0 {+-} 0.7) nm and (188.0 {+-} 1.3) nm, respectively, are close to the nominal values.

Traceable size determination of PMMA nanoparticles based on Small Angle X-ray Scattering (SAXS)

Science.gov (United States)

Gleber, G.; Cibik, L.; Haas, S.; Hoell, A.; Müller, P.; Krumrey, M.

2010-10-01

The size and size distribution of PMMA nanoparticles has been investigated with SAXS (small angle X-ray scattering) using monochromatized synchrotron radiation. The uncertainty has contributions from the wavelength or photon energy of the radiation, the scattering angle and the fit procedure for the obtained scattering curves. The wavelength can be traced back to the lattice constant of silicon, and the scattering angle is traceable via geometric measurements of the detector pixel size and the distance between the sample and the detector. SAXS measurements and data evaluations have been performed at different distances and photon energies for two PMMA nanoparticle suspensions with low polydispersity and nominal diameters of 108 nm and 192 nm, respectively, as well as for a mixture of both. The relative variation of the diameters obtained for different experimental conditions was below ± 0.3 %. The determined number-weighted mean diameters of (109.0 ± 0.7) nm and (188.0 ± 1.3) nm, respectively, are close to the nominal values.

Traceable size determination of PMMA nanoparticles based on Small Angle X-ray Scattering (SAXS)

International Nuclear Information System (INIS)

Gleber, G; Cibik, L; Mueller, P; Krumrey, M; Haas, S; Hoell, A

2010-01-01

The size and size distribution of PMMA nanoparticles has been investigated with SAXS (small angle X-ray scattering) using monochromatized synchrotron radiation. The uncertainty has contributions from the wavelength or photon energy of the radiation, the scattering angle and the fit procedure for the obtained scattering curves. The wavelength can be traced back to the lattice constant of silicon, and the scattering angle is traceable via geometric measurements of the detector pixel size and the distance between the sample and the detector. SAXS measurements and data evaluations have been performed at different distances and photon energies for two PMMA nanoparticle suspensions with low polydispersity and nominal diameters of 108 nm and 192 nm, respectively, as well as for a mixture of both. The relative variation of the diameters obtained for different experimental conditions was below ± 0.3 %. The determined number-weighted mean diameters of (109.0 ± 0.7) nm and (188.0 ± 1.3) nm, respectively, are close to the nominal values.

The accurate assessment of small-angle X-ray scattering data.

Science.gov (United States)

Grant, Thomas D; Luft, Joseph R; Carter, Lester G; Matsui, Tsutomu; Weiss, Thomas M; Martel, Anne; Snell, Edward H

2015-01-01

Small-angle X-ray scattering (SAXS) has grown in popularity in recent times with the advent of bright synchrotron X-ray sources, powerful computational resources and algorithms enabling the calculation of increasingly complex models. However, the lack of standardized data-quality metrics presents difficulties for the growing user community in accurately assessing the quality of experimental SAXS data. Here, a series of metrics to quantitatively describe SAXS data in an objective manner using statistical evaluations are defined. These metrics are applied to identify the effects of radiation damage, concentration dependence and interparticle interactions on SAXS data from a set of 27 previously described targets for which high-resolution structures have been determined via X-ray crystallography or nuclear magnetic resonance (NMR) spectroscopy. The studies show that these metrics are sufficient to characterize SAXS data quality on a small sample set with statistical rigor and sensitivity similar to or better than manual analysis. The development of data-quality analysis strategies such as these initial efforts is needed to enable the accurate and unbiased assessment of SAXS data quality.

Interpretation of small-angle diffraction experiments on opal-like photonic crystals

Science.gov (United States)

Marlow, F.; Muldarisnur, M.; Sharifi, P.; Zabel, H.

2011-08-01

Comprehensive structural information on artificial opals involving the deviations from the strongly dominating face-centered cubic structure is still missing. Recent structure investigations with neutrons and synchrotron sources have shown a high degree of order but also a number of unexpected scattering features. Here, we point out that the exclusion of the allowed 002-type diffraction peaks by a small atomic form factor is not obvious and that surface scattering has to be included as a possible source for the diffraction peaks. Our neutron diffraction data indicate that surface scattering is the main reason for the smallest-angle peaks in the diffraction patterns.

Simulation of small-angle scattering patterns using a CPU-efficient algorithm

Science.gov (United States)

Anitas, E. M.

2017-12-01

Small-angle scattering (of neutrons, x-ray or light; SAS) is a well-established experimental technique for structural analysis of disordered systems at nano and micro scales. For complex systems, such as super-molecular assemblies or protein molecules, analytic solutions of SAS intensity are generally not available. Thus, a frequent approach to simulate the corresponding patterns is to use a CPU-efficient version of the Debye formula. For this purpose, in this paper we implement the well-known DALAI algorithm in Mathematica software. We present calculations for a series of 2D Sierpinski gaskets and respectively of pentaflakes, obtained from chaos game representation.

Small angle neutron scattering (SANS) under non-equilibrium conditions

International Nuclear Information System (INIS)

Oberthur, R.C.

1984-01-01

The use of small angle neutron scattering (SANS) for the study of systems under non-equilibrium conditions is illustrated by three types of experiments in the field of polymer research: - the relaxation of a system from an initial non-equilibrium state towards equilibrium, - the cyclic or repetitive installation of a series of non-equilibrium states in a system, - the steady non-equilibrium state maintained by a constant dissipation of energy within the system. Characteristic times obtained in these experiments with SANS are compared with the times obtained from quasi-elastic neutron and light scattering, which yield information about the equilibrium dynamics of the system. The limits of SANS applied to non-equilibrium systems for the measurement of relaxation times at different length scales are shown and compared to the limits of quasielastic neutron and light scattering

Reliable structural interpretation of small-angle scattering data from bio-molecules in solution--the importance of quality control and a standard reporting framework.

Science.gov (United States)

Jacques, David A; Guss, Jules Mitchell; Trewhella, Jill

2012-05-17

Small-angle scattering is becoming an increasingly popular tool for the study of bio-molecular structures in solution. The large number of publications with 3D-structural models generated from small-angle solution scattering data has led to a growing consensus for the need to establish a standard reporting framework for their publication. The International Union of Crystallography recently established a set of guidelines for the necessary information required for the publication of such structural models. Here we describe the rationale for these guidelines and the importance of standardising the way in which small-angle scattering data from bio-molecules and associated structural interpretations are reported.

Reliable structural interpretation of small-angle scattering data from bio-molecules in solution - the importance of quality control and a standard reporting framework

Directory of Open Access Journals (Sweden)

Jacques David A

2012-05-01

Full Text Available Abstract Small-angle scattering is becoming an increasingly popular tool for the study of bio-molecular structures in solution. The large number of publications with 3D-structural models generated from small-angle solution scattering data has led to a growing consensus for the need to establish a standard reporting framework for their publication. The International Union of Crystallography recently established a set of guidelines for the necessary information required for the publication of such structural models. Here we describe the rationale for these guidelines and the importance of standardising the way in which small-angle scattering data from bio-molecules and associated structural interpretations are reported.

A mechanical velocity selector for a small angle scattering instrument on a pulsed neutron source

International Nuclear Information System (INIS)

Meardon, B.H.; Stewart, R.J.; Williams, W.G.

1978-11-01

Design parameters and performance calculations are given for a straight-slot velocity selector which can be used for discriminating between elastic and inelastic scattering events in small angle scattering experiments on a pulsed neutron source. The selector has a high transmittance over the wavelength range 3 A 5%. (author)

Small-angle neutron scattering from multilamellar lipid bilayers: Theory, model, and experiment

DEFF Research Database (Denmark)

Lemmich, Jesper; Mortensen, Kell; Ipsen, John Hjorth

1996-01-01

Small-angle neutron scattering data obtained from fully hydrated, multilamellar phospholipid bilayers with deuterated acyl chains of different length are presented and analyzed within a paracrystalline theory and a geometric model that permit the bilayer structure to be determined under conditions...... of temperature for the lamellar repeat distance, the hydrophobic bilayer thickness, as well as the thickness of the aqueous and polar head group region. In addition to these geometric parameters the analysis permits determination of molecular cross-sectional area, number of interlamellar water molecules, as well...

Small-incision cataract extraction combined trabeculectomy for primary angle-closure glaucoma with cataract

Directory of Open Access Journals (Sweden)

Yu-Feng Wu

2014-09-01

Full Text Available AIM: To observe the curative effect of treating small-incision cataract extraction by intraocular lens implantation combined with trabeculectomy for primary angle-closure glaucoma with cataract. METHODS: Totally 44 cases(52 eyesof primary angle-closure glaucoma combined with cataract were selected to undergo the combined surgery, in order to observe the patients' pre- and postoperative eyesights, intraocular pressures and the postoperative complications.RESULTS: The postoperative eyesight was improved significantly as compared with the preoperative eyesight. The intraocular pressure was declined dramatically. The result was of statistical significance(P0.05. All the 52 cases' surgeries were performed by the same surgeon. The surgeries were processed smoothly, with 6 postoperative eyes of anterior chamber inflammation cell response, 3 eyes of anterior chamber fibrinoid exudate, 2 eyes of shallow anterior chamber through mydriasis and treatment with glucocorticoids and non-steroidal eyedrops before absorption, and no complications like malignant glaucoma, cyclodialysis, etc. were reported through mydriasis and pressure bandaging before recovery.CONCLUSION: Treating the primary angle-closure glaucoma combined with cataract through the combined surgery has high reliability and desirable curative effect. The surgical method is simple to learn and applicable for promotion on the basic level.

Survival probability in small angle scattering of low energy alkali ions from alkali covered metal surfaces

International Nuclear Information System (INIS)

Neskovic, N.; Ciric, D.; Perovic, B.

1982-01-01

The survival probability in small angle scattering of low energy alkali ions from alkali covered metal surfaces is considered. The model is based on the momentum approximation. The projectiles are K + ions and the target is the (001)Ni+K surface. The incident energy is 100 eV and the incident angle 5 0 . The interaction potential of the projectile and the target consists of the Born-Mayer, the dipole and the image charge potentials. The transition probability function corresponds to the resonant electron transition to the 4s projectile energy level. (orig.)

Soller collimators for small angle neutron scattering

International Nuclear Information System (INIS)

Crawford, R.K.; Epperson, J.E.; Thiyagarajan, P.

1989-01-01

The neutron beam transmitted through the soller collimators on the SAD (Small Angle Diffractometer) instrument at IPNS (Intense Pulsed Neutron Source) showed wings about the main beam. These wings were quite weak, but were sufficient to interfere with the low-Q scattering data. General considerations of the theory of reflection from homogeneous absorbing media, combined with the results from a Monte Carlo simulation, suggested that these wings were due to specular reflection of neutrons from the absorbing material on the surfaces of the collimator blades. The simulations showed that roughness of the surface was extremely important, with wing background variations of three orders of magnitude being observed with the range of roughness values used in the simulations. Based on the results of these simulations, new collimators for SAD were produced with a much rougher 10 B-binder surface coating on the blades. These new collimators were determined to be significantly better than the original SAD collimators. This work suggests that any soller collimators designed for use with long wavelengths should be fabricated with such a rough surface coating, in order to eliminate (or at least minimize) the undesirable reflection effects which otherwise seem certain to occur. 4 refs., 6 figs

The modular small-angle X-ray scattering data correction sequence.

Science.gov (United States)

Pauw, B R; Smith, A J; Snow, T; Terrill, N J; Thünemann, A F

2017-12-01

Data correction is probably the least favourite activity amongst users experimenting with small-angle X-ray scattering: if it is not done sufficiently well, this may become evident only during the data analysis stage, necessitating the repetition of the data corrections from scratch. A recommended comprehensive sequence of elementary data correction steps is presented here to alleviate the difficulties associated with data correction, both in the laboratory and at the synchrotron. When applied in the proposed order to the raw signals, the resulting absolute scattering cross section will provide a high degree of accuracy for a very wide range of samples, with its values accompanied by uncertainty estimates. The method can be applied without modification to any pinhole-collimated instruments with photon-counting direct-detection area detectors.

Small angle scattering methods to study porous materials under high uniaxial strain

Energy Technology Data Exchange (ETDEWEB)

Le Floch, Sylvie, E-mail: sylvie.le-floch@univ-lyon1.fr; Balima, Félix; Pischedda, Vittoria; Legrand, Franck; San-Miguel, Alfonso [Institut Lumière Matière, UMR5306 Université Lyon 1-CNRS, Université de Lyon, 69622 Villeurbanne Cedex (France)

2015-02-15

We developed a high pressure cell for the in situ study of the porosity of solids under high uniaxial strain using neutron small angle scattering. The cell comprises a hydraulically actioned piston and a main body equipped with two single-crystal sapphire windows allowing for the neutron scattering of the sample. The sample cavity is designed to allow for a large volume variation as expected when compressing highly porous materials. We also implemented a loading protocol to adapt an existing diamond anvil cell for the study of porous materials by X-ray small angle scattering under high pressure. The two techniques are complementary as the radiation beam and the applied pressure are in one case perpendicular to each other (neutron cell) and in the other case parallel (X-ray cell). We will illustrate the use of these two techniques in the study of lamellar porous systems up to a maximum pressure of 0.1 GPa and 0.3 GPa for the neutron and X-ray cells, respectively. These devices allow obtaining information on the evolution of porosity with pressure in the pore dimension subdomain defined by the wave-numbers explored in the scattering process. The evolution with the applied load of such parameters as the fractal dimension of the pore-matrix interface or the apparent specific surface in expanded graphite and in expanded vermiculite is used to illustrate the use of the high pressure cells.

Processing two-dimensional X-ray diffraction and small-angle scattering data in DAWN 2.

Science.gov (United States)

Filik, J; Ashton, A W; Chang, P C Y; Chater, P A; Day, S J; Drakopoulos, M; Gerring, M W; Hart, M L; Magdysyuk, O V; Michalik, S; Smith, A; Tang, C C; Terrill, N J; Wharmby, M T; Wilhelm, H

2017-06-01

A software package for the calibration and processing of powder X-ray diffraction and small-angle X-ray scattering data is presented. It provides a multitude of data processing and visualization tools as well as a command-line scripting interface for on-the-fly processing and the incorporation of complex data treatment tasks. Customizable processing chains permit the execution of many data processing steps to convert a single image or a batch of raw two-dimensional data into meaningful data and one-dimensional diffractograms. The processed data files contain the full data provenance of each process applied to the data. The calibration routines can run automatically even for high energies and also for large detector tilt angles. Some of the functionalities are highlighted by specific use cases.

Reflective small angle electron scattering to characterize nanostructures on opaque substrates

Science.gov (United States)

Friedman, Lawrence H.; Wu, Wen-Li; Fu, Wei-En; Chien, Yunsan

2017-09-01

Feature sizes in integrated circuits (ICs) are often at the scale of 10 nm and are ever shrinking. ICs appearing in today's computers and hand held devices are perhaps the most prominent examples. These smaller feature sizes demand equivalent advances in fast and accurate dimensional metrology for both development and manufacturing. Techniques in use and continuing to be developed include X-ray based techniques, optical scattering, and of course the electron and scanning probe microscopy techniques. Each of these techniques has their advantages and limitations. Here, the use of small angle electron beam scattering measurements in a reflection mode (RSAES) to characterize the dimensions and the shape of nanostructures on flat and opaque substrates is demonstrated using both experimental and theoretical evidence. In RSAES, focused electrons are scattered at angles smaller than 1 ° with the assistance of electron optics typically used in transmission electron microscopy. A proof-of-concept experiment is combined with rigorous electron reflection simulations to demonstrate the efficiency and accuracy of RSAES as a method of non-destructive measurement of shapes of features less than 10 nm in size on flat and opaque substrates.

Small-angle scattering study of Aspergillus awamori glycoprotein glucoamylase

Energy Technology Data Exchange (ETDEWEB)

Schmidt, A. E., E-mail: schmidt@omrb.pnpi.spb.ru; Shvetsov, A. V. [National Research Center “Kurchatov Institute”, Konstantinov Petersburg Nuclear Physics Institute (Russian Federation); Kuklin, A. I. [Joint Institute for Nuclear Research (Russian Federation); Lebedev, D. V.; Surzhik, M. A.; Sergeev, V. R.; Isaev-Ivanov, V. V. [National Research Center “Kurchatov Institute”, Konstantinov Petersburg Nuclear Physics Institute (Russian Federation)

2016-01-15

Glucoamylase from fungus Aspergillus awamori is glycoside hydrolase that catalyzes the hydrolysis of α-1,4- and α-1,6-glucosidic bonds in glucose polymers and oligomers. This glycoprotein consists of a catalytic domain and a starch-binding domain connected by an O-glycosylated polypeptide chain. The conformation of the linker, the relative arrangement of the domains, and the structure of the full-length enzyme are unknown. The structure of the recombinant glucoamylase GA1 was studied by molecular modelling and small-angle neutron scattering (SANS) methods. The experimental SANS data provide evidence that glucoamylase exists as a monomer in solution and contains a glycoside component, which makes a substantial contribution to the scattering. The model of full-length glucoamylase, which was calculated without taking into account the effect of glycosylation, is consistent with the experimental data and has a radius of gyration of 33.4 ± 0.6 Å.

Small-angle scattering study of Aspergillus awamori glycoprotein glucoamylase

International Nuclear Information System (INIS)

Schmidt, A. E.; Shvetsov, A. V.; Kuklin, A. I.; Lebedev, D. V.; Surzhik, M. A.; Sergeev, V. R.; Isaev-Ivanov, V. V.

2016-01-01

Glucoamylase from fungus Aspergillus awamori is glycoside hydrolase that catalyzes the hydrolysis of α-1,4- and α-1,6-glucosidic bonds in glucose polymers and oligomers. This glycoprotein consists of a catalytic domain and a starch-binding domain connected by an O-glycosylated polypeptide chain. The conformation of the linker, the relative arrangement of the domains, and the structure of the full-length enzyme are unknown. The structure of the recombinant glucoamylase GA1 was studied by molecular modelling and small-angle neutron scattering (SANS) methods. The experimental SANS data provide evidence that glucoamylase exists as a monomer in solution and contains a glycoside component, which makes a substantial contribution to the scattering. The model of full-length glucoamylase, which was calculated without taking into account the effect of glycosylation, is consistent with the experimental data and has a radius of gyration of 33.4 ± 0.6 Å

Small-angle scattering study of Aspergillus awamori glycoprotein glucoamylase

Science.gov (United States)

Schmidt, A. E.; Shvetsov, A. V.; Kuklin, A. I.; Lebedev, D. V.; Surzhik, M. A.; Sergeev, V. R.; Isaev-Ivanov, V. V.

2016-01-01

Glucoamylase from fungus Aspergillus awamori is glycoside hydrolase that catalyzes the hydrolysis of α-1,4- and α-1,6-glucosidic bonds in glucose polymers and oligomers. This glycoprotein consists of a catalytic domain and a starch-binding domain connected by an O-glycosylated polypeptide chain. The conformation of the linker, the relative arrangement of the domains, and the structure of the full-length enzyme are unknown. The structure of the recombinant glucoamylase GA1 was studied by molecular modelling and small-angle neutron scattering (SANS) methods. The experimental SANS data provide evidence that glucoamylase exists as a monomer in solution and contains a glycoside component, which makes a substantial contribution to the scattering. The model of full-length glucoamylase, which was calculated without taking into account the effect of glycosylation, is consistent with the experimental data and has a radius of gyration of 33.4 ± 0.6 Å.

Fractal morphology in lignite coal: a small angle x-ray scattering investigation

International Nuclear Information System (INIS)

Chitra, R.; Sen, D.; Mazumder, S.; Chandrasekaran, K.S.

1999-01-01

Small angle x-ray scattering technique has been used to study the pore morphology in lignite coal from Neyveli lignite mine (Tamilnadu, India). The sample were collected from three different locations of the same mine. SAXS profiles from all the three samples show almost identical functionality, irrespective of the locations from where the samples were collected. SAXS experiment using two different wavelengths also exhibit same functionality indicating the absence of multiple scattering. The analysis indicates the surface fractal nature of the pore morphology. The surface fractal dimension is calculated to be 2.58. (author)

Structure investigations on Portland cement paste by small angle neutron scattering

International Nuclear Information System (INIS)

Dragolici, C.A.; Lin, A.

2004-01-01

Hydrated Portland cement is a very complex material. Cement paste consists of many crystalline and non-crystalline phases in various ranges of sizes (μm and nm scale). The crystalline phases are embedded in amorphous phases of hydration products. We investigated the structural changes of hydrating phases in a time interval up to 18 days, at Budapest Neutron Center's SANS spectrometer. The small angle neutron scattering of Portland cements prepared with a various water-to-cement ratios, gave us information about the microstructure changes in the material. Fractals were a suitable way for structure modelling. Some comments regarding the opportunity of using the most common models are pointed out. (authors)

Mineral crystal alignment in mineralized fracture callus determined by 3D small-angle X-ray scattering

Energy Technology Data Exchange (ETDEWEB)

Liu Yifei; Manjubala, Inderchand; Fratzl, Peter [Department of Biomaterials, Max Planck Institute of Colloids and Interfaces, 14424 Potsdam (Germany); Roschger, Paul [4th Medical Department, Ludwig Boltzmann Institute of Osteology at Hanusch Hospital of WGKK and AUVA Trauma Centre Meidling, 1140 Vienna (Austria); Schell, Hanna; Duda, Georg N, E-mail: fratzl@mpikg.mpg.d [Julius Wolff Institut and Center for Musculoskeletal Surgery, Charite- University Medicine Berlin, Augustenburger Platz 1, 13353 Berlin (Germany)

2010-10-01

Callus tissue formed during bone fracture healing is a mixture of different tissue types as revealed by histological analysis. But the structural characteristics of mineral crystals within the healing callus are not well known. Since two-dimensional (2D) scanning small-angle X-ray scattering (sSAXS) patterns showed that the size and orientation of callus crystals vary both spatially and temporally [1] and 2D electron microscopic analysis implies an anisotropic property of the callus morphology, the mineral crystals within the callus are also expected to vary in size and orientation in 3D. Three-dimensional small-angle X-ray scattering (3D SAXS), which combines 2D SAXS patterns collected at different angles of sample tilting, has been previously applied to investigate bone minerals in horse radius [2] and oim/oim mouse femur/tibia [3]. We implement a similar 3D SAXS method but with a different way of data analysis to gather information on the mineral alignment in fracture callus. With the proposed accurate yet fast assessment of 3D SAXS information, it was shown that the plate shaped mineral particles in the healing callus were aligned in groups with their predominant orientations occurring as a fiber texture.

Mineral crystal alignment in mineralized fracture callus determined by 3D small-angle X-ray scattering

International Nuclear Information System (INIS)

Liu Yifei; Manjubala, Inderchand; Fratzl, Peter; Roschger, Paul; Schell, Hanna; Duda, Georg N

2010-01-01

Callus tissue formed during bone fracture healing is a mixture of different tissue types as revealed by histological analysis. But the structural characteristics of mineral crystals within the healing callus are not well known. Since two-dimensional (2D) scanning small-angle X-ray scattering (sSAXS) patterns showed that the size and orientation of callus crystals vary both spatially and temporally [1] and 2D electron microscopic analysis implies an anisotropic property of the callus morphology, the mineral crystals within the callus are also expected to vary in size and orientation in 3D. Three-dimensional small-angle X-ray scattering (3D SAXS), which combines 2D SAXS patterns collected at different angles of sample tilting, has been previously applied to investigate bone minerals in horse radius [2] and oim/oim mouse femur/tibia [3]. We implement a similar 3D SAXS method but with a different way of data analysis to gather information on the mineral alignment in fracture callus. With the proposed accurate yet fast assessment of 3D SAXS information, it was shown that the plate shaped mineral particles in the healing callus were aligned in groups with their predominant orientations occurring as a fiber texture.

Monomeric Amyloid Beta Peptide in Hexafluoroisopropanol Detected by Small Angle Neutron Scattering.

Directory of Open Access Journals (Sweden)

Bo Zhang-Haagen

Full Text Available Small proteins like amyloid beta (Aβ monomers are related to neurodegenerative disorders by aggregation to insoluble fibrils. Small angle neutron scattering (SANS is a nondestructive method to observe the aggregation process in solution. We show that SANS is able to resolve monomers of small molecular weight like Aβ for aggregation studies. We examine Aβ monomers after prolonged storing in d-hexafluoroisopropanol (dHFIP by using SANS and dynamic light scattering (DLS. We determined the radius of gyration from SANS as 1.0±0.1 nm for Aβ1-40 and 1.6±0.1 nm for Aβ1-42 in agreement with 3D NMR structures in similar solvents suggesting a solvent surface layer with 5% increased density. After initial dissolution in dHFIP Aβ aggregates sediment with a major component of pure monomers showing a hydrodynamic radius of 1.8±0.3 nm for Aβ1-40 and 3.2±0.4 nm for Aβ1-42 including a surface layer of dHFIP solvent molecules.

First results in rapid MR imaging of focal liver and spleen lesions using field echos and small angle excitation (gradient echo sequences)

International Nuclear Information System (INIS)

Griebel, J.; Hess, C.F.; Kurtz, B.; Klose, U.; Kueper, K.

1987-01-01

15 healthy subjects and 39 patients with focal liver and spleen lesions were examined via MR tomography at 1.5 tesla. Gradient field echos at small angle excitation ( 0 ) were employed. The imaging time per layer was 10 seconds so that rapid imaging could be carried out at respiratory standstill. This enabled visualisation of liver and spleen without interference by breathing artifacts and with accurate localisation. Focal lesions can be imaged best at low flip-angle pulses (liver) or low to medium-angle pulses (spleen). The primary liver cell carcinoma is visualised as an inhomogeneous structure with similar signal intensity as the surrounding tissue. All other examined liver lesions (metastases, haemangiomas, lymphatic infiltrates, echinococcus cysts, FNH, gummae) showed greater signal intensity than the remaining organ at small angle excitation. Furthermore, contrast reversals were seen at medium-angle pulses. Contrariwise, with the exception of the light-coloured spleen infarcts, spleen lesions (lymphatic infiltrate, Boeck's disease or sarcoidosis) appeared darker at all excitation angles than the surrounding tissue. (orig.) [de

First results in rapid MR imaging of focal liver and spleen lesions using field echos and small angle excitation (gradient echo sequences)

Energy Technology Data Exchange (ETDEWEB)

Griebel, J.; Hess, C.F.; Kurtz, B.; Klose, U.; Kueper, K.

1987-01-01

15 healthy subjects and 39 patients with focal liver and spleen lesions were examined via MR tomography at 1.5 tesla. Gradient field echos at small angle excitation (< 90/sup 0/) were employed. The imaging time per layer was 10 seconds so that rapid imaging could be carried out at respiratory standstill. This enabled visualisation of liver and spleen without interference by breathing artifacts and with accurate localisation. Focal lesions can be imaged best at low flip-angle pulses (liver) or low to medium-angle pulses (spleen). The primary liver cell carcinoma is visualised as an inhomogeneous structure with similar signal intensity as the surrounding tissue. All other examined liver lesions (metastases, haemangiomas, lymphatic infiltrates, echinococcus cysts, FNH, gummae) showed greater signal intensity than the remaining organ at small angle excitation. Furthermore, contrast reversals were seen at medium-angle pulses. Contrariwise, with the exception of the light-coloured spleen infarcts, spleen lesions (lymphatic infiltrate, Boeck's disease or sarcoidosis) appeared darker at all excitation angles than the surrounding tissue.

Direct comparison of Fe-Cr unmixing characterization by atom probe tomography and small angle scattering

Energy Technology Data Exchange (ETDEWEB)

Couturier, Laurent, E-mail: laurent.couturier55@hotmail.fr [Univ. Grenoble Alpes, SIMAP, F-38000 Grenoble (France); CNRS, SIMAP, F-38000 Grenoble (France); Department of Materials Engineering, The University of British Columbia, Vancouver, BC V6T 1Z4 (Canada); De Geuser, Frédéric; Deschamps, Alexis [Univ. Grenoble Alpes, SIMAP, F-38000 Grenoble (France); CNRS, SIMAP, F-38000 Grenoble (France)

2016-11-15

The fine microstructure obtained by unmixing of a solid solution either by classical precipitation or spinodal decomposition is often characterized either by small angle scattering or atom probe tomography. This article shows that a common data analysis framework can be used to analyze data obtained from these two techniques. An example of the application of this common analysis is given for characterization of the unmixing of the Fe-Cr matrix of a 15-5 PH stainless steel during long-term ageing at 350 °C and 400 °C. A direct comparison of the Cr composition fluctuations amplitudes and characteristic lengths obtained with both techniques is made showing a quantitative agreement for the fluctuation amplitudes. The origin of the discrepancy remaining for the characteristic lengths is discussed. - Highlights: •Common analysis framework for atom probe tomography and small angle scattering •Comparison of same microstructural characteristics obtained using both techniques •Good correlation of Cr composition fluctuations amplitudes from both techniques •Good correlation of Cr composition fluctuations amplitudes with classic V parameter.

Quantitative impact of small angle forward scatter on whole blood oximetry using a Beer-Lambert absorbance model.

Science.gov (United States)

LeBlanc, Serge Emile; Atanya, Monica; Burns, Kevin; Munger, Rejean

2011-04-21

It is well known that red blood cell scattering has an impact on whole blood oximetry as well as in vivo retinal oxygen saturation measurements. The goal of this study was to quantify the impact of small angle forward scatter on whole blood oximetry for scattering angles found in retinal oximetry light paths. Transmittance spectra of whole blood were measured in two different experimental setups: one that included small angle scatter in the transmitted signal and one that measured the transmitted signal only, at absorbance path lengths of 25, 50, 100, 250 and 500 µm. Oxygen saturation was determined by multiple linear regression in the 520-600 nm wavelength range and compared between path lengths and experimental setups. Mean calculated oxygen saturation differences between setups were greater than 10% at every absorbance path length. The deviations to the Beer-Lambert absorbance model had different spectral dependences between experimental setups, with the highest deviations found in the 520-540 nm range when scatter was added to the transmitted signal. These results are consistent with other models of forward scatter that predict different spectral dependences of the red blood cell scattering cross-section and haemoglobin extinction coefficients in this wavelength range.

Apparent Contact Angle and Contact Angle Hysteresis on Liquid Infused Surfaces

OpenAIRE

Semprebon, Ciro; McHale, Glen; Kusumaatmaja, Halim

2016-01-01

We theoretically investigate the apparent contact angle and contact angle hysteresis of a droplet placed on a liquid infused surface. We show that the apparent contact angle is not uniquely defined by material parameters, but also has a strong dependence on the relative size between the droplet and its surrounding wetting ridge formed by the infusing liquid. We derive a closed form expression for the contact angle in the limit of vanishing wetting ridge, and compute the correction for small b...

Small-angle X-ray scattering (SAXS) for metrological size determination of nanoparticles

Energy Technology Data Exchange (ETDEWEB)

Gleber, Gudrun; Krumrey, Michael; Cibik, Levent; Marggraf, Stefanie; Mueller, Peter [Physikalisch-Technische Bundesanstalt, Abbestr. 2-12, 10587 Berlin (Germany); Hoell, Armin [Helmholtz-Zentrum Berlin, Albert-Einstein-Str. 15, 12489 Berlin (Germany)

2011-07-01

To measure the size of nanoparticles, different measurement methods are available but their results are often not compatible. In the framework of an European metrology project we use Small-Angle X-ray Scattering (SAXS) to determine the size and size distribution of nanoparticles in aqueous solution, where the special challange is the traceability of the results. The experiments were performed at the Four-Crystal Monochromator (FCM) beamline in the laboratory of Physikalisch-Technische Bundesanstalt (PTB) at BESSY II using the SAXS setup of the Helmholtz-Zentrum Berlin (HZB). We measured different particles made of PMMA and gold in a diameter range of 200 nm down to about 10 nm. The aspects of traceability can be classified in two parts: the first is the experimental part with the uncertainties of distances, angles, and wavelength, the second is the part of analysis, with the uncertainty of the choice of the model used for fitting the data. In this talk we want to show the degree of uncertainty, which we reached in this work yet.

Small angle neutron scattering study on star di-block copolymers

International Nuclear Information System (INIS)

Ertugrul, O.

2006-01-01

Determining structural properties, phase transitions and stability of polymer mixtures is very important to produce new materials with desired and interesting properties. Small Angle Neutron Scattering Technique (SANS) has been one of the most powerful and intensely used methods for the characterization of polymers for last decades, m this study, we use a model based on Gaussian Random Phase Approximation (RPA) to describe Star Di-block Copolymers (SDC) mixtures with homo-polymers. We could able to predict the miscibility and phase transitions of the various mixtures along with their structure factors, producing a thermodynamic picture of the system. Also the results suggest that scattering intensity will be dictated by the structure factor of the core or shell parts of star polymer only, which depends on the homo-polymer type of the mixture

Quantitative anomalous small-angle X-ray scattering - The determination of chemical concentrations in nano-scale phases

International Nuclear Information System (INIS)

Goerigk, G.; Huber, K.; Mattern, N.; Williamson, D.L.

2012-01-01

In the last years Anomalous Small-Angle X-ray Scattering became a precise quantitative method resolving scattering contributions two or three orders of magnitude smaller compared to the overall small-angle scattering, which are related to the so-called pure-resonant scattering contribution. Additionally to the structural information precise quantitative information about the different constituents of multi-component systems like the fraction of a chemical component implemented into the materials nano-structures are obtained from these scattering contributions. The application of the Gauss elimination algorithm to the vector equation established by ASAXS measurements at three X-ray energies is demonstrated for three examples from chemistry and solid state physics. All examples deal with the quantitative analysis of the Resonant Invariant (RI-analysis). From the integrals of the pure-resonant scattering contribution the chemical concentrations in nano-scaled phases are determined. In one example the correlated analysis of the Resonant Invariant and the Non-resonant Invariant (NI-analysis) is employed. (authors)

Steel research using neutron beam techniques. In-situ neutron diffraction, small-angle neutron scattering and residual stress analysis

International Nuclear Information System (INIS)

Sueyoshi, Hitoshi; Ishikawa, Nobuyuki; Yamada, Katsumi; Sato, Kaoru; Nakagaito, Tatsuya; Matsuda, Hiroshi; Arakaki, Yu; Tomota, Yo

2014-01-01

Recently, the neutron beam techniques have been applied for steel researches and industrial applications. In particular, the neutron diffraction is a powerful non-destructive method that can analyze phase transformation and residual stress inside the steel. The small-angle neutron scattering is also an effective method for the quantitative evaluation of microstructures inside the steel. In this study, in-situ neutron diffraction measurements during tensile test and heat treatment were conducted in order to investigate the deformation and transformation behaviors of TRIP steels. The small-angle neutron scattering measurements of TRIP steels were also conducted. Then, the neutron diffraction analysis was conducted on the high strength steel weld joint in order to investigate the effect of the residual stress distribution on the weld cracking. (author)

Modeling the structure of RNA molecules with small-angle X-ray scattering data.

Directory of Open Access Journals (Sweden)

Michal Jan Gajda

Full Text Available We propose a novel fragment assembly method for low-resolution modeling of RNA and show how it may be used along with small-angle X-ray solution scattering (SAXS data to model low-resolution structures of particles having as many as 12 independent secondary structure elements. We assessed this model-building procedure by using both artificial data on a previously proposed benchmark and publicly available data. With the artificial data, SAXS-guided models show better similarity to native structures than ROSETTA decoys. The publicly available data showed that SAXS-guided models can be used to reinterpret RNA structures previously deposited in the Protein Data Bank. Our approach allows for fast and efficient building of de novo models of RNA using approximate secondary structures that can be readily obtained from existing bioinformatic approaches. We also offer a rigorous assessment of the resolving power of SAXS in the case of small RNA structures, along with a small multimetric benchmark of the proposed method.

Small-angle neutron scattering study of micropore collapse in amorphous solid water.

Science.gov (United States)

Mitterdorfer, Christian; Bauer, Marion; Youngs, Tristan G A; Bowron, Daniel T; Hill, Catherine R; Fraser, Helen J; Finney, John L; Loerting, Thomas

2014-08-14

Vapor-deposited amorphous solid water (ASW) is the most abundant solid molecular material in space, where it plays a direct role in both the formation of more complex chemical species and the aggregation of icy materials in the earliest stages of planet formation. Nevertheless, some of its low temperature physics such as the collapse of the micropore network upon heating are still far from being understood. Here we characterize the nature of the micropores and their collapse using neutron scattering of gram-quantities of D2O-ASW of internal surface areas up to 230 ± 10 m(2) g(-1) prepared at 77 K. The model-free interpretation of the small-angle scattering data suggests micropores, which remain stable up to 120-140 K and then experience a sudden collapse. The exact onset temperature to pore collapse depends on the type of flow conditions employed in the preparation of ASW and, thus, the specific surface area of the initial deposit, whereas the onset of crystallization to cubic ice is unaffected by the flow conditions. Analysis of the small-angle neutron scattering signal using the Guinier-Porod model suggests that a sudden transition from three-dimensional cylindrical pores with 15 Å radius of gyration to two-dimensional lamellae is the mechanism underlying the pore collapse. The rather high temperature of about 120-140 K of micropore collapse and the 3D-to-2D type of the transition unraveled in this study have implications for our understanding of the processing and evolution of ices in various astrophysical environments.

Detection of structural defects in lecithin membranes by the small-angle neutron scattering method

International Nuclear Information System (INIS)

Bezzabotnov, V.Yu.; Gordelij, V.I.; Ostanevich, Yu.M.; Yaguzhinskij, L.S.

1989-01-01

Irregularities interpreted as interdomain defects have been detected in model lipid membranes of dipalmitoil lecithin in liquid L α -phase by the method of small-angle scattering (lateral diffraction). The dimensions and concentrations of the defects were about those supposed within the dynamic cluster model of bilayer (Ivkov, 1984). No irregularities were detected in the solid Lβ ' -phase (the diffusion scattering intensity was at least ten times less)

Structure of polyacrylic acid and polymethacrylic acid solutions : a small angle neutron scattering study

OpenAIRE

Moussaid , A.; Schosseler , F.; Munch , J.; Candau , S.

1993-01-01

The intensity scattered from polyacrylic acid and polymethacrylic acid solutions has been measured by small angle neutron scattering experiemnts. The influence of polymer concentration, ionization degree, temperature and salt content has been investigated. Results are in qualitative agreement with a model which predicts the existence of microphases in the unstable region of the phase diagram. Quantitative comparison with the theory is performed by fitting the theoretical structure factor to t...

Effects of pressure and temperature on pore structure of ceramic synthesized from rice husk: A small angle neutron scattering investigation

Energy Technology Data Exchange (ETDEWEB)

Raut Dessai, R., E-mail: reshooin@yahoo.com [Department of Physics, Goa University, Taleigao Plateau, Goa 403 206 (India); Desa, J.A.E. [Department of Physics, Goa University, Taleigao Plateau, Goa 403 206 (India); Sen, D.; Mazumder, S. [Solid State Physics Division, Bhabha Atomic Research Centre, Trombay, Mumbai 400 085 (India)

2013-07-05

Highlights: ► A porous ceramic has been prepared from silica obtained from rice husk. ► The ceramic has a hierarchical pore structure from micrometric to nano-metric. ► Small Angle Neutron Scattering data indicate nano-pore connectivity to micro-pores. ► Pore morphology can be tuned by compaction pressure and sintering temperature. -- Abstract: Ceramic powder has been synthesized from rice husk as the source of silica. In order to probe the evolution of its hierarchical mesoscopic and microscopic porous structure, the ceramic powder was compacted at different pressures and was sintered at different temperatures. A glassy ceramic to crystalline transition under thermal treatment (up to 1000 °C) was revealed by X-ray diffraction. Existence of pores in two widely separated length scales was indicated by small angle neutron scattering with the smaller ones having mass fractal arrangement. Although no significant change in small pore structure under thermal effect was indicated, a significant modification of the same has been revealed by small angle neutron scattering at different compaction pressures. Connectivity between the pores was ascertained from scattering experiments on the ceramic compact impregnated with heavy water. Scanning electron microscopy shows the microstructure to undergo appreciable coalescence of micrometric ceramic particles for sintering temperature and pressure changes.

Studying nanostructure gradients in injection-molded polypropylene/montmorillonite composites by microbeam small-angle x-ray scattering

DEFF Research Database (Denmark)

Stribeck, Norbert; Schneider, Konrad; Zeinolebadi, Ahmad

2014-01-01

The core–shell structure in oriented cylindrical rods of polypropylene (PP) and nanoclay composites (NCs) from PP and montmorillonite (MMT) is studied by microbeam small-angle x-ray scattering (SAXS). The structure of neat PP is almost homogeneous across the rod showing regular semicrystalline......-shaped phyllosilicate filler particles....

Structure investigations on Portland cement paste by small angle neutron scattering

International Nuclear Information System (INIS)

Dragolici, C. A.; Len, A.

2003-01-01

Portland cement pastes consist of many crystalline and non-crystalline phases in various ranges of sizes (nm and mm scale). The crystalline phases are embedded in amorphous phases of the hydration products. We investigated the structural changes of hydrating phases in the time interval of 1-30 days at Budapest Neutron Center's SANS diffractometer. The small angle neutron scattering of Portland cements prepared with a water-to-cement ratio from 0,3 to 0,8 gave us information about the microstructure changes in the material. Fractals were a suitable way for structure modelling. The variation of fractals size depending on the preparation-to-measurement time interval and water-to-cement ratio could be observed. (authors)

A new package: MySAS for small angle scattering data analysis

International Nuclear Information System (INIS)

Huang Chaoqiang; Xia Qingzhong; Yan Guanyun; Sun Guang'ai; Chen Bo

2010-01-01

In this paper, A MySAS package, which is verified on Windows XP, can easily convert two-dimensional data in small angle neutron and X-ray scattering analysis, operate individually and execute one particular operation as numerical data reduction or analysis, and graphical visualization. This MySAS package can implement the input and output routines via scanning certain properties, thus recalling completely sets of repetition input and selecting the input files. On starting from the two-dimensional files, the MySAS package can correct the anisotropic or isotropic data for physical interpretation and select the relevant pixels. Over 50 model functions are fitted by the POWELL code using χ 2 as the figure of merit function. (authors)

Enhancement of graphic user interface data acquisition of small angle neutron scattering

International Nuclear Information System (INIS)

Abd Aziz Muhammad; Abd Jalil Abd Hamid

2004-01-01

This paper discusses the activities of the development of data acquisition software for PC, which capable of controlling instrument via IEEE-488 and graphic visualization for small angle neutron scattering (SANS) runs in DOS mode. With the help of outstanding free ware graphic library for DOS, this software has enhanced the efficiency of graphic visualization for SANSLab data acquisition. Featuring easy-to-use graphical user interface (GUI) and several other built-in tools for convenience, this software can be manipulated with the mouse or the keyboard. This software can be converted into an inexpensive data acquisition system for SANS. (Author)

Ion track annealing in quartz investigated by small angle X-ray scattering

Energy Technology Data Exchange (ETDEWEB)

Schauries, D.; Afra, B.; Rodriguez, M.D. [Department of Electronic Materials Engineering, Research School of Physics and Engineering, The Australian National University, Canberra, ACT 2601 (Australia); Trautmann, C. [GSI Helmholtz Centre for Heavy Ion Research, Planckstrasse 1, 64291 Darmstadt (Germany); Technische Universität Darmstadt, 64287 Darmstadt (Germany); Hawley, A. [Australian Synchrotron, 800 Blackburn Road, Clayton, VIC 3168 (Australia); Kluth, P. [Department of Electronic Materials Engineering, Research School of Physics and Engineering, The Australian National University, Canberra, ACT 2601 (Australia)

2015-12-15

We report on the reduction of cross-section and length of amorphous ion tracks embedded within crystalline quartz during thermal annealing. The ion tracks were created via Au ion irradiation with an energy of 2.2 GeV. The use of synchrotron-based small angle X-ray scattering (SAXS) allowed characterization of the latent tracks, without the need for chemical etching. Temperatures between 900 and 1000 °C were required to see a notable change in track size. The shrinkage in cross-section and length was found to be comparable for tracks aligned perpendicular and parallel to the c-axis.

Interphase effects in dental nanocomposites investigated by small-angle neutron scattering.

Science.gov (United States)

Wilson, Kristen S; Allen, Andrew J; Washburn, Newell R; Antonucci, Joseph M

2007-04-01

Small-angle and ultrasmall-angle neutron scattering (SANS and USANS) were used to characterize silica nanoparticle dispersion morphologies and the interphase in thermoset dimethacrylate polymer nanocomposites. Silica nanoparticle fillers were silanized with varying mass ratios of 3-methacryloxypropyltrimethoxysilane (MPTMS), a silane that interacts with the matrix through covalent and H-bonding, and n-octyltrimethoxysilane (OTMS), a silane that interacts through weak dispersion forces. Interphases with high OTMS mass fractions were found to be fractally rough with fractal dimensions, D(s), between 2.19 and 2.49. This roughness was associated with poor interfacial adhesion and inferior mechanical properties. Mean interparticle distances calculated for composites containing 10 mass % and 25 mass % silica suggest that the nanoparticles treated with more MPTMS than OTMS may be better dispersed than OTMS-rich nanoparticles. The results indicate that the covalent bonding and H-bonding of MPTMS-rich nanoparticles with the matrix are necessary for preparing well-dispersed nanocomposites. In addition, interphases containing equal masses of MPTMS and OTMS may yield composites with overall optimal properties. Finally, the combined SANS/USANS data could distinguish the differences, as a function of silane chemistry, in the nanoparticle/silane and silane/matrix interfaces that affect the overall mechanical properties of the composites. (c) 2006 Wiley Periodicals, Inc.

Crystallization behavior of polyethylene on silicon wafers in solution casting processes traced by time-resolved measurements of synchrotron grazing-incidence small-angle and wide-angle X-ray scattering

International Nuclear Information System (INIS)

Sasaki, S; Masunaga, H; Takata, M; Itou, K; Tashiro, K; Okuda, H; Takahara, A

2009-01-01

Crystallization behavior of polyethylene (PE) on silicon wafers in solution casting processes has been successfully traced by time-resolved grazing-incidence small-angle and wide-angle X-ray scattering (GISWAXS) measurements utilizing synchrotron radiation. A p-xylene solution of PE kept at ca. 343 K was dropped on a silicon wafer at ca. 298 K. While the p-xylene evaporated naturally from the dropped solution sample, PE chains crystallized to be a thin film. Raman spectral measurements were performed simultaneously with the GISWAXS measurements to evaluate quantitatively the p-xylene the dropped solution contained. Grazing-incidence wide-angle X-ray scattering (GIWAXS) patterns indicated nucleation and crystal growth in the dropped solution and the following as-cast film. GIWAXS and Raman spectral data revealed that crystallization of PE was enhanced after complete evaporation of the p-xylene from the dropped solution. The [110] and [200] directions of the orthorhombic PE crystal became relatively parallel to the wafer surface with time, which implied that the flat-on lamellae with respect to the wafer surface were mainly formed in the as-cast film. On the other hand, grazing-incidence small-angle X-ray scattering (GISAXS) patterns implied formation of isolated lamellae in the dropped solution. The lamellae and amorphous might alternatively be stacked in the preferred direction perpendicular to the wafer surface. The synchrotron GISWAXS experimental method could be applied for kinetic study on hierarchical structure of polymer thin films.

Neutron and synchrotorn x-ray small angle scattering instruments for applications in biology at the Brookhaven National Laboratory

International Nuclear Information System (INIS)

Schoenborn, B.P.; Wise, D.S.; Schneider, D.K.

1983-01-01

Facilities for small angle x-ray and neutron scattering are described, with emphasis on the characterization of the primary beam of the neutron instrument and the spectrometer control logic of the synchrotron instrument

Characterization of Nanocellulose Using Small-Angle Neutron, X-ray, and Dynamic Light Scattering Techniques.

Science.gov (United States)

Mao, Yimin; Liu, Kai; Zhan, Chengbo; Geng, Lihong; Chu, Benjamin; Hsiao, Benjamin S

2017-02-16

Nanocellulose extracted from wood pulps using TEMPO (2,2,6,6-tetramethylpiperidine-1-oxyl radical)-mediated oxidation and sulfuric acid hydrolysis methods was characterized by small-angle neutron scattering (SANS), small-angle X-ray scattering (SAXS), and dynamic light scattering (DLS) techniques. The dimensions of this nanocellulose (TEMPO-oxidized cellulose nanofiber (TOCN) and sulfuric acid hydrolyzed cellulose nanocrystal (SACN)) revealed by the different scattering methods were compared with those characterized by transmission electron microscopy (TEM). The SANS and SAXS data were analyzed using a parallelepiped-based form factor. The width and thickness of the nanocellulose cross section were ∼8 and ∼2 nm for TOCN and ∼20 and ∼3 nm for SACN, respectively, where the fitting results from SANS and SAXS profiles were consistent with each other. DLS was carried out under both the V V mode with the polarizer and analyzer parallel to each other and the H V mode having them perpendicular to each other. Using rotational and translational diffusion coefficients obtained under the H V mode yielded a nanocellulose length qualitatively consistent with that observed by TEM, whereas the length derived by the translational diffusion coefficient under the V V mode appeared to be overestimated.

Small-angle neutron scattering from poly(NIPA-co-AMPS) gels

DEFF Research Database (Denmark)

Travas-Sejdic, J.; Easteal, A.; Knott, R.

2000-01-01

was reversed; that is the lower cross-link density, the higher the scattered intensity. Therefore, the role of cross-links at high temperature was to suppress microphase separation. The fitting of the experimental data with the Rabin and Panyukov theory indicated qualitative agreement.......The microstructure of the poly( N-isopropylacrylamide-co-acrylamido- 2-methyl-1-propane sulphonic acid) gel, poly( NIPA-co-AMPS), was investigated as a function of temperature and cross-link density using the small angle neutron scattering technique. The sample temperature was varied in the range...... 30 to 55C. Two different behaviours of poly( NIPA-co-AMPS) gels were observed. At low temperature (30C), the magnitude of the scattered intensity increased with cross-link density suggesting that additional cross-links introduced more inhomogeneities in the gel network. At high temperatures the trend...

Study of the defect structures produced by heavy ions in dielectrics by means of small angle scattering

International Nuclear Information System (INIS)

Albrecht, D.J.

1983-11-01

The aim of the present thesis was to study the defects in dielectrics produced by fast ions. For this the small angle scattering was proved as suitable method. By the production by means of the ion beam of an accelerator the defects possess a pronounced preferential direction. In scattering experiments this system of scattering centers is distinguished by its unusually strong dependence of the sample orientation according to the primary beam. This property was studied, described, and illustrated by examples, and it could by shown that from this additional informations about the scattering defects can be derived. For the first time nuclear tracks were detected by means of small angle neutron scattering. It could be shown that here the same results are obtained as by small angle X-ray scattering. The measured intensity distributions could be assigned to a mathematical model description which gives form, width, and density of the tracks in the position space. On the base of this cylinder model computer codes were established which simulate the scattering experiment regarding the main influences and calculate the expected theoretical intensity distribution. The agreement between calculated and measured scattering distributions proves the validity of the model. The parameters determined by this model, maximal change of density in the track, defect length, radial dilatation, distance of the narrowings and there depth were determined. For the main quantities, radial dilatation and maximal change of densities a simple description of the energy dependence could be given via the energy loss. (orig./HSI) [de

Design of Single Stage Axial Turbine with Constant Nozzle Angle Blading for Small Turbojet

Science.gov (United States)

Putra Adnan, F.; Hartono, Firman

2018-04-01

In this paper, an aerodynamic design of a single stage gas generator axial turbine for small turbojet engine is explained. As per design requirement, the turbine should be able to deliver power output of 155 kW at 0.8139 kg/s gas mass flow, inlet total temperature of 1200 K and inlet total pressure of 335330 Pa. The design phase consist of several steps, i.e.: determination of velocity triangles in 2D plane, 2D blading design and 3D flow analysis at design point using Computational Fluid Dynamics method. In the determination of velocity triangles, two conditions are applied: zero inlet swirl (i.e. the gas flow enter the turbine at axial direction) and constant nozzle angle design (i.e. the inlet and outlet angle of the nozzle blade are constant from root to tip). The 2D approach in cascade plane is used to specify airfoil type at root, mean and tip of the blade based on inlet and outlet flow conditions. The 3D approach is done by simulating the turbine in full configuration to evaluate the overall performance of the turbine. The observed parameters including axial gap, stagger angle, and tip clearance affect its output power. Based on analysis results, axial gap and stagger angle are positively correlated with output power up to a certain point at which the power decreases. Tip clearance, however, gives inversely correlation with output power.

Microstructural characterization of a modified 706-type Ni-Fe superalloy by small-angle neutron scattering and electron microscopy

Czech Academy of Sciences Publication Activity Database

Del Genovese, D.; Strunz, Pavel; Mukherji, D.; Gilles, R.; Rösler, J.

36A, - (2005), s. 3439-3450 ISSN 1073-5623 Institutional research plan: CEZ:AV0Z10480505 Keywords : superalloys * small-angle neutron scattering Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 1.232, year: 2005

Measurement of small-angle antiproton-proton and proton-proton elastic scattering at the CERN intersecting storage rings

NARCIS (Netherlands)

Amos, N.; Block, M.M.; Bobbink, G.J.; Botje, M.A.J.; Favart, D.; Leroy, C.; Linde, F.; Lipnik, P.; Matheys, J-P.; Miller, D.

1985-01-01

Antiproton-proton and proton-proton small-angle elastic scattering was measured for centre-of-mass energies at the CERN Intersectung Storage Rings. In addition, proton-proton elastic scattering was measured at . Using the optical theorem, total cross sections are obtained with an accuracy of about

Small-angle X-ray scattering studies of metastable intermediates of beta-lactoglobulin isolated after heat-induced aggregation

DEFF Research Database (Denmark)

Carrotta, R.; Arleth, L.; Pedersen, J.S.

2003-01-01

Small-angle x-ray scattering was used for studying intermediate species, isolated after heat-induced aggregation of the A variant of bovine P-lactoglobulin. The intermediates were separated in two fractions, the heated metastable dimer and heated metastable oligomers larger than the dimer. The pa...

A small-angle neutron scattering investigation of coke deposits on catalysts

International Nuclear Information System (INIS)

Acharya, D.R.; Hughes, R.; Allen, A.J.

1990-01-01

Small-angle neutron scattering (SANS) has been used to characterize a silica-alumina catalyst before and after coke deposition. The reaction used to deactivate the catalyst was the isomerization of xylenes. The results showed that, while most of the surface area in this type of catalyst resides in the ultrafine pores of diameters less than 1 nm occupying about 7% of the sample volume, there appears to be no coke deposition in these pores. The coke seems to coat the solid structures of 3.3-nm diameter which are of capillary shape. Such structures occupy about 6% of the sample volume. The coke was found to correspond to amonolayer of composition CH 0.3 with a density of 1660 kg/m 3

Study of chemically unfolded β-casein by means of small-angle neutron scattering

International Nuclear Information System (INIS)

Aschi, Adel; Gharbi, Abdelhafidh; Daoud, Mohamed; Douillard, Roger; Calmettes, Patrick

2007-01-01

β-casein is a flexible amphiphilic milk protein which forms an unfolded conformation in presence of very high denaturant concentrations. The structure of β-casein formed at the bulk was studied by small-angle neutron scattering (SANS). The value of the second virial coefficient of the protein solutions indicates that the interactions between the polypeptide chain and solvent are repulsive. The protein conformation is similar to an excluded volume chain. The corresponding values of the contour length, L, the statistical length, b and the apparent radius of the chain cross-section, R c are given

Study of pore growth in glassy carbon using small angle x-ray scattering

International Nuclear Information System (INIS)

Hoyt, J.

1982-07-01

Small-angle x-ray scattering was used to study the average pore size in glass-like carbon as a function of both heat-treatment time and heat-treatment temperature. A pore-growth model based on graphitization processes is presented. The simple mechanism shows that the change in the average radius of gyration with time is related to the total number of pores as a function of time, which in turn depends on the irreversible thermal-expansion phenomenon. The results of this study are inconsistent with a vacancy-migration pore-growth mechanism proposed earlier

Anomalous small-angle scattering as a way to solve the Babinet principle problem

International Nuclear Information System (INIS)

Boiko, M. E.; Sharkov, M. D.; Boiko, A. M.; Bobyl, A. V.

2013-01-01

X-ray absorption spectra (XAS) have been used to determine the absorption edges of atoms present in a sample under study. A series of small-angle X-ray scattering (SAXS) measurements using different monochromatic X-ray beams at different wavelengths near the absorption edges is performed to solve the Babinet principle problem. The sizes of clusters containing atoms determined by the method of XAS were defined in SAXS experiments. In contrast to differential X-ray porosimetry, anomalous SAXS makes it possible to determine sizes of clusters of different atomic compositions

Anomalous small-angle scattering as a way to solve the Babinet principle problem

Energy Technology Data Exchange (ETDEWEB)

Boiko, M. E., E-mail: m.e.boiko@mail.ioffe.ru; Sharkov, M. D.; Boiko, A. M.; Bobyl, A. V. [Russian Academy of Sciences, Ioffe Physicotechnical Institute (Russian Federation)

2013-12-15

X-ray absorption spectra (XAS) have been used to determine the absorption edges of atoms present in a sample under study. A series of small-angle X-ray scattering (SAXS) measurements using different monochromatic X-ray beams at different wavelengths near the absorption edges is performed to solve the Babinet principle problem. The sizes of clusters containing atoms determined by the method of XAS were defined in SAXS experiments. In contrast to differential X-ray porosimetry, anomalous SAXS makes it possible to determine sizes of clusters of different atomic compositions.

Anomalous small-angle scattering as a way to solve the Babinet principle problem

Science.gov (United States)

Boiko, M. E.; Sharkov, M. D.; Boiko, A. M.; Bobyl, A. V.

2013-12-01

X-ray absorption spectra (XAS) have been used to determine the absorption edges of atoms present in a sample under study. A series of small-angle X-ray scattering (SAXS) measurements using different monochromatic X-ray beams at different wavelengths near the absorption edges is performed to solve the Babinet principle problem. The sizes of clusters containing atoms determined by the method of XAS were defined in SAXS experiments. In contrast to differential X-ray porosimetry, anomalous SAXS makes it possible to determine sizes of clusters of different atomic compositions.

Small-angle X-ray scattering at high brilliance european synchrotrons for biotechnology and nano-technology

International Nuclear Information System (INIS)

Svergun, D.; Malfois, M.; Svergun, D.; Douka, M.; Riekel, Ch.; Perez, J.; Roessle, M.; Amenitsch, H.; Gunter Grossman, J.; Vestergaard, B.; Receveur-Brechot, V.; Roth, St.V.; Ferrari, E.

2007-01-01

Different issues such as micro-fluidic devices for SAXS (small-angle X-ray diffraction), the use of electro-spray and ion trapping for SAXS in the gas phase, the study of flexible and disordered proteins through SAXS, the time-resolved SAXS studies in solution, or the study of nano-structured soft materials, were addressed in this workshop. This document gathers the transparencies of the presentations

Small-angle X-ray scattering at high brilliance european synchrotrons for biotechnology and nano-technology

Energy Technology Data Exchange (ETDEWEB)

Svergun, D.; Malfois, M. [EMBL c/o DESY, Hamburg (Germany); Svergun, D. [Institute of Crystallography, Russian Academy of Sciences, Moscow (Russian Federation); Douka, M. [Commission Europeenne, DG III, Bruxelles (Belgium); Riekel, Ch. [European Synchrotron Radiation Facility (ESRF), 38 - Grenoble (France); Perez, J. [Soleil, 91 - Saclay (France); Roessle, M. [European Molecular Biology Laboratory (EMBL), 38 - Grenoble (France); Amenitsch, H. [IBN/Elettra (Germany); Gunter Grossman, J. [Daresbury Synchrotron Radiation Source (SRS) (United Kingdom); Vestergaard, B. [University of Pharmaceutical Sciences, Copenhagen (Denmark); Receveur-Brechot, V. [Centre National de la Recherche Scientifique (CNRS/AFMB), 13 - Marseille (France); Roth, St.V. [Deutsches Elektronen Synchrotron (HASYLAB), Hamburg (Germany); Ferrari, E. [National Institute for the Physics of Matter (CNR-INFM), Trieste (Italy)

2007-07-01

Different issues such as micro-fluidic devices for SAXS (small-angle X-ray diffraction), the use of electro-spray and ion trapping for SAXS in the gas phase, the study of flexible and disordered proteins through SAXS, the time-resolved SAXS studies in solution, or the study of nano-structured soft materials, were addressed in this workshop. This document gathers the transparencies of the presentations.

Spin-wave dynamics in Invar Fe65Ni35 studied by small-angle polarized neutron scattering

NARCIS (Netherlands)

Brück, E.H.; Grigoriev, S.V.; Deriglazov, V.V.; Okorokov, A.I.; Dijk van, N.H.; Klaasse, J.C.P.

2002-01-01

Abstract. Spin dynamics in Fe65Ni35 Invar alloy has been studied by left-right asymmetry of small-angle polarized neutron scattering below TC=485 K in external magnetic fields of H=0.05-0.25 T inclined relative to the incident beam. The spin-wave stiffness D and the damping & were obtained by

The University of New Mexico/Sandia National Laboratories small-angle scattering laboratory

International Nuclear Information System (INIS)

Rieker, T.P.; Hubbard, P.F.

1998-01-01

The University of New Mexico/Sandia National Laboratories small-angle scattering laboratory provides a wide q-range, 3x10 -4 Angstrom -1 -1 , for the structural analysis of materials on length scales from a few angstrom to ∼0.1 μm. The wide q-range is accomplished by combining data from a Bonse-Hart spectrometer (3x10 -4 Angstrom -1 -2 Angstrom -1 ) and a 5 m pinhole (3x10 -3 Angstrom -1 -1 ) instrument. Automation of the data acquisition systems along with a variety of sample environments and sample changers yields flexible, high throughput instruments. copyright 1998 American Institute of Physics

Small angle scattering study of the structure and organization of RNA and protein in Brome Mosaic Virus (BMV)

Science.gov (United States)

Das, Narayan C.; Warren, Garfield T.; Cheng, Si; Kao, C. Cheng; Ni, Peng; Dragnea, Bogdan; Sokol, Paul E.

2012-02-01

Brome mosaic virus (BMV) is a small icosahedral of the alpha virus-like superfamily of RNA with a segmented positive-strand RNA genome and a mean diameter ˜ 268å that offers high levels of RNA synthesis and virus production in plants. BMV also tightly regulates the packaging of its four RNAs (RNA1 through RNA4) into three separate particles; RNA1 and RNA2 are encapsidated separately while one copy each of RNA3 and RNA4 are normally packaged together. Small angle neutron scattering (SANS) and small angle X-ray scattering (SAXS) were applied to study the size, shape and protein-RNA organization of BMV. D2O/H2O mixture was used to enhance contrast in SANS measurement. The radial distribution of BMV from the Fourier transform of scattering spectrum gives a clear indication of RNA packing, and distribution and their structure in the BMV. The result reveals that the virus is about 266 å in diameter and is composed of RNA inside the virion coated with a protein shell.

Spin-echo small-angle neutron scattering study of the structure organization of the chromatin in biological cell

NARCIS (Netherlands)

Iashina, E.G.; Bouwman, W.G.; Duif, C.P.; Filatov, M.V.; Grigoriev, S. V.

2017-01-01

Spin-echo small-angle scattering (SESANS) technique is a method to measure the structure of materials from nano- to micrmeter length scales. This method could be important for studying the packaging of DNA in the eukaryotic cell. We measured the SESANS function from chicken erythrocyte nuclei

ORNL-SAS: Versatile software for calculation of small-angle x-ray and neutron scattering intensity profiles from arbitrary structures

International Nuclear Information System (INIS)

Heller, William T; Tjioe, Elina

2007-01-01

ORNL-SAS is software for calculating solution small-angle scattering intensity profiles from any structure provided in the Protein Data Bank format and can also compare the results with experimental data

Experimental study of crossing angle collision

International Nuclear Information System (INIS)

Chen, T.; Rice, D.; Rubin, D.; Sagan, D.; Tigner, M.

1993-01-01

The non-linear coupling due to the beam-beam interaction with crossing angle has been studied. The major effect of a small (∼12mrad) crossing angle is to excite 5Q x ±Q s =integer coupling resonance family on large amplitude particles, which results in bad lifetime. On the CESR, a small crossing angle (∼2.4mr) was created at the IP and a reasonable beam-beam tune-shift was achieved. The decay rate of the beam is measured as a function of horizontal tune with and without crossing angle. The theoretical analysis, simulation and experimental measurements have a good agreement. The resonance strength as a function of crossing angle is also measured

Structure of clathrin-coated vesicles from small-angle scattering experiments

DEFF Research Database (Denmark)

Pedersen, J.S.

1993-01-01

Previously published small-angle neutron and X-ray scattering data from coated vesicles, reassembled coats, and stripped vesicles have been analyzed in terms of one common model. The neutron data sets include contrast variation measurements at three different D2O solvent concentrations. The model...... used for interpreting the data has spherical symmetry and explicitly takes into account polydispersity, which is described by a Gaussian distribution. A constant thickness of the clathrin coats is assumed. The fitting of the model shows that the coated vesicles consist of a low-density outer protein....... Thus, the membrane and the high-density protein shell overlap in space, which shows that the lipid membrane contains protein. The molecular mass of the average particle is 27 x 10(6) Da. The coated vesicles consist, on average, of approximately 85% protein and 15% lipids. About 40% of the protein mass...

Apparent contact angle and contact angle hysteresis on liquid infused surfaces.

Science.gov (United States)

Semprebon, Ciro; McHale, Glen; Kusumaatmaja, Halim

2016-12-21

We theoretically investigate the apparent contact angle and contact angle hysteresis of a droplet placed on a liquid infused surface. We show that the apparent contact angle is not uniquely defined by material parameters, but also has a dependence on the relative size between the droplet and its surrounding wetting ridge formed by the infusing liquid. We derive a closed form expression for the contact angle in the limit of vanishing wetting ridge, and compute the correction for small but finite ridge, which corresponds to an effective line tension term. We also predict contact angle hysteresis on liquid infused surfaces generated by the pinning of the contact lines by the surface corrugations. Our analytical expressions for both the apparent contact angle and contact angle hysteresis can be interpreted as 'weighted sums' between the contact angles of the infusing liquid relative to the droplet and surrounding gas phases, where the weighting coefficients are given by ratios of the fluid surface tensions.

Scanning small angle X-ray scattering investigations of bone

International Nuclear Information System (INIS)

Rinnerthaler, S.

1998-06-01

An important characteristic of bone is its strength, which is determined by bone mass, architecture and material quality. From a physical point of view bone is a composite material consisting of an organic matrix (collagen) and of inlets of mineral crystals (hydroxyapatite). These components build up a hierarchical, heterogeneous structure. The size of the mineral crystals lies in the nano-meter range and can be investigated by positionsensitive Small-Angle X-ray Scattering (Scanning-SAXS) in a non-destructive way. The average thickness, the degree and direction of the predominant orientation, as well as some information about shape and arrangement of the mineral crystals were determined in bones of humans, mice, and baboons by Scanning-SAXS with respect to age, bone diseases (osteogenesis imperfecta, pycnodysostosis) or medical treatments (fluoride or alendronate) of osteoporosis. The crystal thickness and the degree of orientation is much smaller in young individuals than in adults and the predominant orientation of the mineral crystals is different in a mixture of bone and mineralized cartilage compared to bone. Further, because position-resolved measurements are now possible, results from Scanning-SAXS measurements could be compared with the results of other position resolved methods. Due to this new feature it was possible, for the first time, to correlate directly 'mottled' bone visible in back-scattered electron imaging with small η-parameters evaluated from SAXS-patterns and the course of the collagen fibers with the predominant orientation of the mineral crystals. Scanning-SAXS proved to be a powerful tool to characterize bone nano-structure. (author)

Density model for medium range order in amorphous materials: application to small angle scattering

International Nuclear Information System (INIS)

Boucher, B.; Tournarie, M.; Chieux, P.; Convert, P.

1983-06-01

We consider a family of randomly spaced parallel planes, each plane dressed with a density function, h(x), where x is the distance from the plane. An expression for the volume scattering power from a system of N such families with random orientations in space is derived from Fourier transform of h(x), which can subsequently be determined from experimental observations. This density model is used to interpret the small angle neutron scattering (SANS) results for the amorphous alloy TbCusub(3.54)

Real-time remedial action against aperiodic small signal rotor angle instability

DEFF Research Database (Denmark)

Weckesser, Johannes Tilman Gabriel; Jóhannsson, Hjörtur; Østergaard, Jacob

2016-01-01

This paper presents a method that in real-time determines remedial actions, which restore stable operation with respect to aperiodic small signal rotor angle stability (ASSRAS) when insecure or unstable operation has been detected. An ASSRAS assessment method is used to monitor the stability...... impedance plane to determine an active power redispatch among selected generators to restore stable and secure operation. Since the method is purely based on analytically derived expression, the computation of the remedial actions is fast and well suited for real-time operation. The method was tested...... boundary for each generator in real-time. The ASSRAS boundary represents the condition when a generator reaches the maximum steady state active power injection. The proposed control method exploits analytically derived expressions for the ASSRAS boundary and other characteristic curves in the injection...

X-ray crystal structure and small-angle X-ray scattering of sheep liver sorbitol dehydrogenase

Energy Technology Data Exchange (ETDEWEB)

Yennawar, Hemant [Pennsylvania State University, 8 Althouse Laboratory, University Park, PA 16802 (United States); Møller, Magda [Cornell High Energy Synchrotron Source, Ithaca, NY 14853 (United States); University of Copenhagen, DK-2100 Copenhagen (Denmark); Gillilan, Richard [Cornell High Energy Synchrotron Source, Ithaca, NY 14853 (United States); Yennawar, Neela, E-mail: nhy1@psu.edu [Pennsylvania State University, 8 Althouse Laboratory, University Park, PA 16802 (United States)

2011-05-01

The X-ray crystal structure and a small-angle X-ray scattering solution structure of sheep liver sorbitol dehydrogenase have been determined. The details of the interactions that enable the tetramer scaffold to be the functional biological unit have been analyzed. The X-ray crystal structure of sheep liver sorbitol dehydrogenase (slSDH) has been determined using the crystal structure of human sorbitol dehydrogenase (hSDH) as a molecular-replacement model. slSDH crystallized in space group I222 with one monomer in the asymmetric unit. A conserved tetramer that superposes well with that seen in hSDH (despite belonging to a different space group) and obeying the 222 crystal symmetry is seen in slSDH. An acetate molecule is bound in the active site, coordinating to the active-site zinc through a water molecule. Glycerol, a substrate of slSDH, also occupies the substrate-binding pocket together with the acetate designed by nature to fit large polyol substrates. The substrate-binding pocket is seen to be in close proximity to the tetramer interface, which explains the need for the structural integrity of the tetramer for enzyme activity. Small-angle X-ray scattering was also used to identify the quaternary structure of the tetramer of slSDH in solution.

Characterization of the dimensions of colloidal calcium carbonate dispersions in toluene with neutron small-angle scattering

International Nuclear Information System (INIS)

Vlak, W.A.H.M.; Dorrepaal, J.

1987-02-01

Calcium carbonate particles, stabilized by a surface layer, and dispersed in toluene are investigated with neutron small-angle scattering. Estimates for the dimensions of the core particle and the layer have been obtained: the layer thickness is 8.6 A and the core particle radius is 16.5 A. The limits within which these results are valid are indicated. (Auth.)

Studies of protein structure in solution and protein folding using synchrotron small-angle x-ray scattering

Energy Technology Data Exchange (ETDEWEB)

Chen, Lingling [Stanford Univ., CA (United States)

1996-04-01

Synchrotron small angle x-ray scattering (SAXS) has been applied to the structural study of several biological systems, including the nitrogenase complex, the heat shock cognate protein (hsc70), and lysozyme folding. The structural information revealed from the SAXS experiments is complementary to information obtained by other physical and biochemical methods, and adds to our knowledge and understanding of these systems.

Study of chemically unfolded {beta}-casein by means of small-angle neutron scattering

Energy Technology Data Exchange (ETDEWEB)

Aschi, Adel [Laboratoire de Physique de la Matiere Molle, Faculte des Sciences de Tunis, Campus Universitaire, 1060, Tunis (Tunisia)]. E-mail: aschi13@yahoo.fr; Gharbi, Abdelhafidh [Laboratoire de Physique de la Matiere Molle, Faculte des Sciences de Tunis, Campus Universitaire, 1060, Tunis (Tunisia); Daoud, Mohamed [Service de Physique de l' Etat Condense. CEA Saclay. 91191 Gif-sur-Yvette cedex (France); Douillard, Roger [Equipe de Biochimie des Macromolecules Vegetales, Centre de Recherche Agronomique, 2Esplanade R. Garros, BP 224, 51686 Reims cedex 2 (France); Calmettes, Patrick [Laboratoire Leon Brillouin, CEA Saclay, 91191 Gif-sur-Yvette cedex (France)

2007-01-01

{beta}-casein is a flexible amphiphilic milk protein which forms an unfolded conformation in presence of very high denaturant concentrations. The structure of {beta}-casein formed at the bulk was studied by small-angle neutron scattering (SANS). The value of the second virial coefficient of the protein solutions indicates that the interactions between the polypeptide chain and solvent are repulsive. The protein conformation is similar to an excluded volume chain. The corresponding values of the contour length, L, the statistical length, b and the apparent radius of the chain cross-section, R{sub c} are given.

On the Casimir scaling violation in the cusp anomalous dimension at small angle

Science.gov (United States)

Grozin, Andrey; Henn, Johannes; Stahlhofen, Maximilian

2017-10-01

We compute the four-loop n f contribution proportional to the quartic Casimir of the QCD cusp anomalous dimension as an expansion for small cusp angle ϕ. This piece is gauge invariant, violates Casimir scaling, and first appears at four loops. It requires the evaluation of genuine non-planar four-loop Feynman integrals. We present results up to O({φ}^4) . One motivation for our calculation is to probe a recent conjecture on the all-order structure of the cusp anomalous dimension. As a byproduct we obtain the four-loop HQET wave function anomalous dimension for this color structure.

The small angle neutron scattering study on the segmented polyurethane

International Nuclear Information System (INIS)

Sudirman; Gunawan; Prasetyo, S.M.; Karo Karo, A.; Lahagu, I.M.; Darwinto, Tri

1999-01-01

The distance between hard segment (HS) and soft segment (SS) of segmented polyurethane have been determined using the Small Angle Neutron Scattering (SANS) technique. The segmented Polyurethanes (SPU) are linear multiblock copolymers, which include elastomer thermoplastic. SPU consist of hard segment and soft segment, each has tendency to make a group with similar type to form a domain. The soft segments used were polypropylene glycol (PPG) and 4,4 diphenylmethane diisocyanate (MDI), while l,4 butanediol (BD) was used as hard segment. The characteristic of SPU depends on its phase structure which is affected by several factors, such as type of chemical formula and the composition of the HS and SS, solvent as well as the synthesizing process. The samples used in this study were SPU56 and SPU68. Based on the appearance of SANS profile, it was obtained that domain distances are 12.32 nm for the SPU56 and 19 nm for the SPU68. (author)

Beyond the small-angle approximation for MBR anisotropy from seeds

International Nuclear Information System (INIS)

Stebbins, A.; Veeraraghavan, S.

1995-01-01

In this paper we give a general expression for the energy shift of massless particles traveling through the gravitational field of an arbitrary matter distribution as calculated in the weak field limit in an asymptotically flat space-time. It is not assumed that matter is nonrelativistic. We demonstrate the surprising result that if the matter is illuminated by a uniform brightness background that the brightness pattern observed at a given point in space-time (modulo a term dependent on the observer's velocity) depends only on the matter distribution on the observer's past light cone. These results apply directly to the cosmological MBR anisotropy pattern generated in the immediate vicinity of an object such as a cosmic string or global texture. We apply these results to cosmic strings, finding a correction to previously published results in the small-angle approximation. We also derive the full-sky anisotropy pattern of a collapsing texture knot

Numerical exploration of non-axisymmetric divertor closure in the small angle slot (SAS) divertor at DIII-D

Science.gov (United States)

Frerichs, H.; Schmitz, O.; Covele, B.; Feng, Y.; Guo, H. Y.; Hill, D.

2018-05-01

Numerical simulations of toroidal asymmetries in a tightly baffled small angle slot (SAS) divertor on the DIII-D tokamak show that toroidal asymmetries in divertor closure result in (non-axisymmetric) local onset of detachment within a density window of 10-15% on top of the nominal threshold separatrix density. The SAS divertor is explored at DIII-D for improving access to cold, dissipative/detached divertor conditions. The narrow width of the slot divertor coupled with a small magnetic field line-to-target angle facilitates the buildup of neutral density, thereby increasing radiative and neutrals-related (atoms and molecules) losses in the divertor. Small changes in the strike point location can be expected to have a large impact on divertor conditions. The combination of misaligned slot structure and non-axisymmetric perturbations to the magnetic field configuration causes the strike point to move along the divertor target plate, possibly leaving the divertor slot at some locations. The latter extreme case essentially introduces an opening in the divertor slot from where recycling neutrals can easily escape, and thereby degrade the performance of the slot divertor. Such a strike point dislocation is approximated by a finite gap in the divertor baffle for which 3D edge plasma and neutral gas simulations are performed with the EMC3-EIRENE code.

Quantitative analysis of inclusions in low carbon free cutting steel using small-angle X-ray and neutron scattering

International Nuclear Information System (INIS)

Oba, Yojiro; Koppoju, Suresh; Ohnuma, Masato; Kinjo, Yuki; Tomota, Yo; Morooka, Satoshi; Suzuki, Jun-ichi; Yamaguchi, Daisuke; Koizumi, Satoshi; Sato, Masugu; Shiraga, Tetsuo

2012-01-01

The microstructure of inclusions in low carbon free cutting steel without lead addition was investigated using small-angle X-ray scattering (SAXS) coupled with small-angle neutron scattering (SANS). The two-dimensional (2D) SAXS pattern shows clear scattering due to inclusions composed of large elongated particles aligned along the rolling direction, and small isotropic particles. From a comparison of the simulated and experimental 2D SAXS patterns, the shapes of the inclusions are regarded as ellipsoid for the larger inclusions and spherical for the smaller inclusions. The length of the minor axis in the large inclusion is 6.9 μm, while the diameter of the small inclusion is 0.50 μm. The aspect ratio of the large inclusion is estimated to be 3.8 in the lower q region, and is reduced slightly to 3.5 in the higher q region from the azimuthal plots. The results of an alloy contrast variation (ACV) analysis using both the SAXS and SANS data indicate that the chemical composition of the inclusions is almost NaCl-type manganese sulfide, and that the amount of iron sulfide is low. The volume fractions are 1.4% for the large inclusions and 0.2% for the small inclusions. This is consistent with the area fraction estimated using an optical microscope, and indicates that nearly all of the sulfur in the steel sample forms the manganese sulfide inclusions. (author)

The current status of small-angle x-ray scattering beamline at Diamond Light Source

International Nuclear Information System (INIS)

Inoue, Katsuaki; Doutch, James; Terrill, Nick

2013-01-01

The small-angle X-ray scattering (SAXS) covers the major disciplines of biology, chemistry and physics delivering structural and dynamic information in nanoscience, mesoscopic architectures, supramolecular structures, and nucleation/growth of crystals. SAXS is also proving to be important in archaeological, environmental, and conservation sciences, and has further indicated its ability to span wide-ranging scientific disciplines. Thus, strong needs for SAXS studies are increasing significantly in a broad range of scientific fields year by year. Based on such a background, the demand for high throughput SAXS experiments is increasing. At the synchrotron facility, Diamond Light Source, one SAXS beamline, Non-crystalline diffraction I22 is now operational and highly automated throughput small-angle X-ray scattering (HATSAXS) beamline B21 is now under construction. I22 is the Undulator beamline and wide varieties of experiments, including time-resolved experiments are attempted. Based on the concept of HATSAXS, the key feature of B21 will focuses on the automation of end-station equipment. A automated sample changer has been purchased for solution SAXS measurements on biomolecules. A robotic-arm-type automated sample changer that is capable of handling several kinds of samples in material science is also being constructed. B21 is expected to successfully provide all users highly automated throughput measurements with the highest possible reliability and accuracy. Construction of this beamline will end in the second half of 2012, and will be open for users in the early summer of 2013 after commissioning. (author)

Determination of low-field critical parameters of superconducting niobium by small-angle neutron diffraction

International Nuclear Information System (INIS)

Christen, D.K.; Spooner, S.; Thorel, P.; Kerchner, H.R.

1977-01-01

The perfect double-crystal small-angle diffraction technique enables measurement of scattering angles to within 0.3 arc sec. accuracy. At a wavelength of 2.55 A, this provides a resolution of 3 x 10 -6 A -1 in the scattering vector. This technique has been used to study the anisotropic behavior of the critical parameters B 0 and H/sub c1/, characteristic of the first-order magnetic phase transition which occurs in low-kappa type-II superconductors. Magnetic fields were applied parallel to several crystal axes of a large single-crystal sphere of pure niobium, resulting in well-defined flux-line lattices (FLL). Measurement of the FLL cell area in the intermediate mixed state field region gives the equilibrium flux density B 0 , which results from an attractive interaction between fluxoids. In addition, field variation of the scattered neutron intensity allows measurement of the transition field between the mixed state and intermediate mixed state. This transition field is related to the lower critical field H/sub c1/ and enables its determination to a precision 0.2%. Data at T = 4.3 K display a small anisotropic effect of about 2% in B 0 and 1% in H/sub c1/. Although orientation effects of this magnitude are difficult to resolve by bulk measurements, the neutron data are in accord with magnetization data. Observations regarding the temperature dependence of these parameters also will be presented, and comparisons made with current theoretical models

Ultra small angle neutron scattering : a tool to study packing of relatively monodisperse small polymer spheres and their binary mixtures

International Nuclear Information System (INIS)

Reynolds, Philip A.; McGillivray, Duncan J.; White, John W.; Jackson, Andrew J.; University of Maryland, College Paerk, Maryland, USA

2009-01-01

Full text: We measured ultra small angle neutron scattering (USANS) from polymethylmethacrylate spheres tamped down in air. Two slightly polydisperse pure sphere sizes (1.5/-lm and 7.5/-lm diameter) and five mixtures of these were used. All were loose packed (packing fractions 0.3 to 0.6) with nongravitational forces (e.g., friction) important, preventing close packing. The USANS data is rich in information on powder packing. A modified Percus-Yevick fluid model was used to parametrise the data - adequately but not well. The modifications required introduction of small voids, less than the sphere size, and a parameter reflecting substantial deviation from the Percus-Yevick prediction of the sphere-sphere correlation function. The mixed samples fitted less well, and two further modifying factors were necessary. These were local inhomogeneities, where the concentration of same-size spheres, both large and small, deviated from the mean packing, and a factor accounting for the presence within these 'clusters' of self avoidance of the large spheres (that is large spheres coated with more small spheres than Percus-Yevick would predict). The overall deviations from the hardsphere Percus-Yevick model that we find here suggests fluid models of loose packed powders are unlikely to be successful, but lay the groundwork for future theoretical and computational work.

Improved performances of 36 m small-angle neutron scattering spectrometer BATAN in Serpong Indonesia

International Nuclear Information System (INIS)

Putra, Edy Giri Rachman; Bharoto; Santoso, Eddy; Ikram, Abarrul

2009-01-01

SMARTer, a 36 m small-angle neutron scattering (SANS) spectrometer owned by the National Nuclear Energy Agency of Indonesia (BATAN) was installed at the Neutron Scattering Laboratory (NSL) in Serpong, Indonesia. Lots of works on replacing, upgrading and improving the control system, experimental methods, data collection and reduction in the last two years have been carried out to optimize the performance of SMARTer. Some standard samples such as silver behenate, monodisperse polystyrene nanoparticle, porous silica and block copolymer PS-PEP film were measured for the inter-laboratory comparison.

Structure of polyacrylic acid and polymethacrylic acid solutions: a small angle neutron scattering study

Energy Technology Data Exchange (ETDEWEB)

Moussaid, A. (Lab. d' Ultrasons et de Dynamique des Fluides Complexes, Univ. Louis Pasteur, 67 - Strasbourg (France)); Schosseler, F. (Lab. d' Ultrasons et de Dynamique des Fluides Complexes, Univ. Louis Pasteur, 67 - Strasbourg (France)); Munch, J.P. (Lab. d' Ultrasons et de Dynamique des Fluides Complexes, Univ. Louis Pasteur, 67 - Strasbourg (France)); Candau, S.J. (Lab. d' Ultrasons et de Dynamique des Fluides Complexes, Univ. Louis Pasteur, 67 - Strasbourg (France))

1993-04-01

The intensity scattered from polyacrylic acid and polymethacrylic acid solutions has been measured by small angle neutron scattering experiments. The influence of polymer concentration, ionization degree, temperature and salt content has been investigated. Results are in qualitative agreement with a model which predicts the existence of microphases in the unstable region of the phase diagram. Quantitative comparison with the theory is performed by fitting the theoretical structure factor to the experimental data. For a narrow range of ionization degrees nearly quantitative agreement with the theory is found for the polyacrylic acid system. (orig.).

Structure of polyacrylic acid and polymethacrylic acid solutions : a small angle neutron scattering study

Science.gov (United States)

Moussaid, A.; Schosseler, F.; Munch, J. P.; Candau, S. J.

1993-04-01

The intensity scattered from polyacrylic acid and polymethacrylic acid solutions has been measured by small angle neutron scattering experiemnts. The influence of polymer concentration, ionization degree, temperature and salt content has been investigated. Results are in qualitative agreement with a model which predicts the existence of microphases in the unstable region of the phase diagram. Quantitative comparison with the theory is performed by fitting the theoretical structure factor to the experimental data. For a narrow range of ionizaiton degrees nearly quantitative agreement with the theory is found for the polyacrylic acide system.

Q resolution calculation of small angle neutron scattering spectrometer and analysis of form factor

International Nuclear Information System (INIS)

Chen Liang; Peng Mei; Wang Yan; Sun Liangwei; Chen Bo

2011-01-01

The calculational methods of Small Angle Neutron Scattering (SANS) spectrometer Q resolution function and its correlative Q standard difference were introduced. The effects of Q standard difference were analysed with the geometry lay out of spectrometer and the spread of neutron wavelength. The one dimension Q resolution Gaussian function were analysed. The form factor curve of ideal solid sphere and two different instrument arrangement parameter was convoluted respectively and the different smearing curve of form factor was obtained. The combination of using the Q resolution function to more accurately analysis SANS data. (authors)

Small angle neutron scattering study of creep deformation and fracture of type 304 stainless steel

International Nuclear Information System (INIS)

Yoo, M.H.; Ogle, J.C.; Schneibel, J.H.; Swindeman, R.W.

1983-01-01

A small-angle neutron scattering (SANS) study has been performed to determine the size distribution of carbide precipitates that were formed during creep deformation in type 304 stainless steel. The hardening mechanism during primary creep by a fine dispersion of carbide particles in the matrix was confirmed by the SANS measurement and also by direct TEM observations. The size distribution of creep-induced cavities was also determined by SANS measurements after post-creep solution heat treatment. (author)

Small angle neutron scattering study of creep deformation and fracture of Type 304 stainless steel

International Nuclear Information System (INIS)

Yoo, M.H.; Ogle, J.C.; Schneibel, J.H.; Swindeman, R.W.

1982-01-01

A small-angle neutron scattering (SANS) study has been performed to determine the size distribution of carbide precipitates that were formed during creep deformation in Type 304 stainless steel. The hardening mechanism during primary creep by a fine dispersion of carbide particles in the matrix was confirmed by the SANS measurement and also by direct TEM observations. The size distribution of creep-induced cavities was also determined by SANS measurements after post-creep solution heat treatment

Luminosity measurement at LEP using the very small angle tagger of DELPHI

International Nuclear Information System (INIS)

Haakansson, A.

1993-01-01

In this thesis, the analysis of the luminosity measurement from Bhabha scattering within the polar angular region (5 to 7 mrad) covered by the Very Small Angle Tagger (VSAT) in the DELPHI experiment at LEP, is presented. Both by analytical integration and using Monte Carlo simulation, it is shown that the acceptance corrections to the detector can be reliably calculated, obtaining a relative luminosity measurement at the precision level of 0.1%. The absolute experimental error on the luminosity measurement is estimated to be 0.8%. Furthermore, measurement of the beam spot using the VSAT detector are described. The application of the relative luminosity measurement in the extraction of the hadronic lineshape parameters of the Z-particle is also presented

Small angle neutron scattering study of metallic alloys by a double crystal device

International Nuclear Information System (INIS)

Cser, L.; Kovacs, I.; Kroo, N.; Zsigmond, Gy.

1982-06-01

A double crystal small angle neutron scattering (SANS) device was built and a simple method for measuring the integrated SANS intensity was developed. The device and the method were tested and the possibility of future applications was demonstrated by measurements on different samples. The test measurements were performed on iron and teflon slabs of different thickness. On Fe-B metallic glasses a SANS intensity originating mainly from the multiple magnetic refraction at domain boundaries was observed. A very weak SANS intensity was found on turbine blades. The integrated SANS intensity was shown to correlate with the running time of the blades. Similar measurements were performed on artificially deformed steel samples. (author)

Electron-beam-induced current study of small-angle grain boundaries in multicrystalline silicon

International Nuclear Information System (INIS)

Chen, J.; Sekiguchi, T.; Xie, R.; Ahmet, P.; Chikyo, T.; Yang, D.; Ito, S.; Yin, F.

2005-01-01

Recombination activity of small-angle grain boundaries (SA GBs) in multicrystalline silicon (mc-Si) was studied by means of electron-beam-induced current (EBIC) technique. In the as-grown mc-Si, the EBIC contrasts of special Σ and random GBs were weak at both 300 and 100 K, whereas those of SA GBs were weak (<3%) at 300 K and strong (30-40%) at 100 K. In the contaminated mc-Si, SA GBs showed stronger EBIC contrast than Σ and R GBs at 300 K. It is indicated that SA GBs possess high density of shallow levels and are easily contaminated with Fe compared to other GBs

A small angle neutron study of irradiation induced microstructures in Cr-Mo-V WWER steels

International Nuclear Information System (INIS)

Levit, Vladimir I.; Santos, Ari S.; Louzada, Ana R.R.; Silveira, Cristina M.; Vaniel, Ana Paula H.; Odette, George R.; Mader, Eric

2000-01-01

Small angle neutron scattering (SANS) has proven to be a very effective technique for characterizing the ultrafine (∼1 nm) irradiation induced microstructures which are responsible for hardening and the concomitant embrittlement of reactor pressure vessel steels. SANS measurement were carried out on three irradiated and unirradiated weld materials of WWER- type on 8 m instrument at the National Institute of Standards and Technology, Washington, USA. Small (r m < 1 nm) irradiation induced features were found for all three materials. Were found volume fractions, number densities and ratios of magnetic to nuclear scattering. Some analyses of the irradiation induced precipitation nature and possible chemical composition were made by comparison of the results with other reactor materials SANS and Atom Probe Field Ion Microscopy data. (author)

Angled cool-tip electrode for radiofrequency ablation of small superficial subcapsular tumors in the liver: A feasibility study

Energy Technology Data Exchange (ETDEWEB)

Park, Sung Il; Shin, Min Woo; Shin, Won Seon [Severance Hospital, Yonsei University College of Medicine, Seoul (Korea, Republic of); and others

2016-09-15

To evaluate the feasibility of angled cool-tip electrode for radiofrequency ablation of small superficial subcapsular liver tumors abutting abdominal wall, in order to traverse normal liver parenchyma, and thereby, obtain favorable configuration of ablation margin. In this study, we retrospectively analyzed 15 small superficial subcapsular liver tumors abutting abdominal wall in 15 patients, treated with radiofrequency ablation from March 2013 to June 2015 using a cool-tip electrode manually modified to create 25–35° angle at the junction between exposed and insulated segments. The tumors were hepatocellular carcinoma (n = 13) and metastases (n = 2: cholangiocellular carcinoma and rectosigmoid cancer), with maximum diameter of 10–26 mm (mean, 15.68 ± 5.29 mm). Under ultrasonographic guidance, the electrode tip was advanced to the depth of the tumors' epicenter about 1 cm from the margin. The tip was re-directed to penetrate the tumor for radiofrequency ablation. Minimal ablation margin was measured at immediate post-treatment CT. Radiological images and medical records were evaluated for success rate, length of minimal ablation margin and complications. Technical success rate of obtaining complete necrosis of the tumors was 100%, with no procedure-related complication. Minimal ablation margin ranged from 3–12 mm (mean, 7.07 ± 2.23 mm). CT/MRI follow-up at 21–1022 days (mean, 519.47 ± 304.51 days) revealed no local recurrence, but distant recurrence in 9 patients. Using an angled cool-tip electrode for radiofrequency ablation of small superficial subcapsular tumors abutting abdominal wall may be a feasible technique for obtaining adequate ablation margin and lower complication rate.

Angled Cool-Tip Electrode for Radiofrequency Ablation of Small Superficial Subcapsular Tumors in the Liver: A Feasibility Study

Energy Technology Data Exchange (ETDEWEB)

Park, Sung Il [Department of Radiology, Research Institute of Radiological Science, Severance Hospital, Yonsei University College of Medicine, Seoul 03722 (Korea, Republic of); Kim, Il Jung [Department of Radiology, Bucheon St. Mary' s Hospital, College of Medicine, The Catholic University of Korea, Bucheon 14647 (Korea, Republic of); Lee, Shin Jae [Department of Radiology, CHA Bundang Medical Center, CHA University, Seongnam 13496 (Korea, Republic of); Shin, Min Woo; Shin, Won Sun; Chung, Yong Eun; Kim, Gyoung Min; Kim, Man Deuk; Won, Jong Yun; Lee, Do Yun [Department of Radiology, Research Institute of Radiological Science, Severance Hospital, Yonsei University College of Medicine, Seoul 03722 (Korea, Republic of); Choi, Jin Sub [Department of Surgery, Severance Hospital, Yonsei University College of Medicine, Seoul 03722 (Korea, Republic of); Han, Kwang-Hyub [Department of Internal Medicine, Severance Hospital, Yonsei University College of Medicine, Seoul 03722 (Korea, Republic of)

2016-11-01

To evaluate the feasibility of angled cool-tip electrode for radiofrequency ablation of small superficial subcapsular liver tumors abutting abdominal wall, in order to traverse normal liver parenchyma, and thereby, obtain favorable configuration of ablation margin. In this study, we retrospectively analyzed 15 small superficial subcapsular liver tumors abutting abdominal wall in 15 patients, treated with radiofrequency ablation from March 2013 to June 2015 using a cool-tip electrode manually modified to create 25–35° angle at the junction between exposed and insulated segments. The tumors were hepatocellular carcinoma (n = 13) and metastases (n = 2: cholangiocellular carcinoma and rectosigmoid cancer), with maximum diameter of 10–26 mm (mean, 15.68 ± 5.29 mm). Under ultrasonographic guidance, the electrode tip was advanced to the depth of the tumors' epicenter about 1 cm from the margin. The tip was re-directed to penetrate the tumor for radiofrequency ablation. Minimal ablation margin was measured at immediate post-treatment CT. Radiological images and medical records were evaluated for success rate, length of minimal ablation margin and complications. Technical success rate of obtaining complete necrosis of the tumors was 100%, with no procedure-related complication. Minimal ablation margin ranged from 3–12 mm (mean, 7.07 ± 2.23 mm). CT/MRI follow-up at 21–1022 days (mean, 519.47 ± 304.51 days) revealed no local recurrence, but distant recurrence in 9 patients. Using an angled cool-tip electrode for radiofrequency ablation of small superficial subcapsular tumors abutting abdominal wall may be a feasible technique for obtaining adequate ablation margin and lower complication rate.

Angled cool-tip electrode for radiofrequency ablation of small superficial subcapsular tumors in the liver: A feasibility study

International Nuclear Information System (INIS)

Park, Sung Il; Shin, Min Woo; Shin, Won Seon

2016-01-01

To evaluate the feasibility of angled cool-tip electrode for radiofrequency ablation of small superficial subcapsular liver tumors abutting abdominal wall, in order to traverse normal liver parenchyma, and thereby, obtain favorable configuration of ablation margin. In this study, we retrospectively analyzed 15 small superficial subcapsular liver tumors abutting abdominal wall in 15 patients, treated with radiofrequency ablation from March 2013 to June 2015 using a cool-tip electrode manually modified to create 25–35° angle at the junction between exposed and insulated segments. The tumors were hepatocellular carcinoma (n = 13) and metastases (n = 2: cholangiocellular carcinoma and rectosigmoid cancer), with maximum diameter of 10–26 mm (mean, 15.68 ± 5.29 mm). Under ultrasonographic guidance, the electrode tip was advanced to the depth of the tumors' epicenter about 1 cm from the margin. The tip was re-directed to penetrate the tumor for radiofrequency ablation. Minimal ablation margin was measured at immediate post-treatment CT. Radiological images and medical records were evaluated for success rate, length of minimal ablation margin and complications. Technical success rate of obtaining complete necrosis of the tumors was 100%, with no procedure-related complication. Minimal ablation margin ranged from 3–12 mm (mean, 7.07 ± 2.23 mm). CT/MRI follow-up at 21–1022 days (mean, 519.47 ± 304.51 days) revealed no local recurrence, but distant recurrence in 9 patients. Using an angled cool-tip electrode for radiofrequency ablation of small superficial subcapsular tumors abutting abdominal wall may be a feasible technique for obtaining adequate ablation margin and lower complication rate

Angled Cool-Tip Electrode for Radiofrequency Ablation of Small Superficial Subcapsular Tumors in the Liver: A Feasibility Study

International Nuclear Information System (INIS)

Park, Sung Il; Kim, Il Jung; Lee, Shin Jae; Shin, Min Woo; Shin, Won Sun; Chung, Yong Eun; Kim, Gyoung Min; Kim, Man Deuk; Won, Jong Yun; Lee, Do Yun; Choi, Jin Sub; Han, Kwang-Hyub

2016-01-01

To evaluate the feasibility of angled cool-tip electrode for radiofrequency ablation of small superficial subcapsular liver tumors abutting abdominal wall, in order to traverse normal liver parenchyma, and thereby, obtain favorable configuration of ablation margin. In this study, we retrospectively analyzed 15 small superficial subcapsular liver tumors abutting abdominal wall in 15 patients, treated with radiofrequency ablation from March 2013 to June 2015 using a cool-tip electrode manually modified to create 25–35° angle at the junction between exposed and insulated segments. The tumors were hepatocellular carcinoma (n = 13) and metastases (n = 2: cholangiocellular carcinoma and rectosigmoid cancer), with maximum diameter of 10–26 mm (mean, 15.68 ± 5.29 mm). Under ultrasonographic guidance, the electrode tip was advanced to the depth of the tumors' epicenter about 1 cm from the margin. The tip was re-directed to penetrate the tumor for radiofrequency ablation. Minimal ablation margin was measured at immediate post-treatment CT. Radiological images and medical records were evaluated for success rate, length of minimal ablation margin and complications. Technical success rate of obtaining complete necrosis of the tumors was 100%, with no procedure-related complication. Minimal ablation margin ranged from 3–12 mm (mean, 7.07 ± 2.23 mm). CT/MRI follow-up at 21–1022 days (mean, 519.47 ± 304.51 days) revealed no local recurrence, but distant recurrence in 9 patients. Using an angled cool-tip electrode for radiofrequency ablation of small superficial subcapsular tumors abutting abdominal wall may be a feasible technique for obtaining adequate ablation margin and lower complication rate

A small angle neutron scattering study of mica based glass-ceramics with applications in dentistry

International Nuclear Information System (INIS)

Kilcoyne, S.H.; Bentley, P.M.; Al-Jawad, M.; Bubb, N.L.; Al-Shammary, H.A.O.; Wood, D.J.

2004-01-01

We are currently developing machinable and load-bearing mica-based glass-ceramics for use in restorative dental surgery. In this paper we present the results of an ambient temperature small angle neutron scattering (SANS) study of several such ceramics with chemical compositions chosen to optimise machinability and strength. The SANS spectra are all dominated by scattering from the crystalline-amorphous phase interface and exhibit Q -4 dependence (Porod scattering) indicating that, on a 100 A scale, the surface of the crystals is smooth

Small-angle scattering of ions or atoms by atomic hydrogen

International Nuclear Information System (INIS)

Franco, V.

1982-01-01

A theory for small-angle scattering of arbitrary medium- or high-energy atoms or ions by atomic hydrogen is described. Results are obtained in terms of the known closed-form and easily calculable Glauber-approximation scattering amplitudes for electron-hydrogen collisions and for collisions between the nucleus (treated as one charged particle) of the ion or atom and the hydrogen atom, and in terms of the transition form factor of the arbitrary ion or atom. Applications are made to the angular differential cross sections for the excitation of atomic hydrogen to its n = 2 states by singly charged ground-state helium ions having velocities of roughly between 1/2 and 1 a.u. The differential cross sections are obtained in terms of electron-hydrogen amplitudes and the known He + ground-state form factor. Comparisons are made with other calculations and with recent measurements. The results are in good agreement with the data. It is seen that the effect of the He + electron is to produce significant constructive interference at most energies

Small angle neutron scattering. Report of a coordinated research project 2000-2003

International Nuclear Information System (INIS)

2006-03-01

Small angle neutron scattering (SANS) is a powerful technique for studying macro structures like polymers, precipitates in metallurgical specimens, biological molecules, micelles and magnetic systems like ferrofluids. Neutron scattering has an advantage over X ray scattering (XSAXS) due to selective absorption and scattering cross section of neutrons across the periodic table. It is possible to develop and use a SANS instrument even with a medium flux reactor. The present CRP was aimed at the development of components like collimators, monochromators, position sensitive detectors (PSD) etc. for improving the throughput of the instrument and foster the effective utilization of research reactors, as well as to provide a link between developing and developed facilities. The CRP was launched with the first research coordination meeting (RCM) in 2000 to refine the project proposals and define the action plans and partnerships. There were eight research contracts and four research agreements. Good partnerships were established between various participants with collaborations among participants from various countries including those from developing and developed countries. The progress of the individual projects and team work under the CRP was evaluated and discussed during the second RCM and the action plan for the final phase was formulated. The results of the work done under the CRP were then reviewed in the final RCM held in Vienna, December 2003. This publication presents the results of the work carried out by the participants under the CRP at their respective institutions. The information will be useful for the users and operators of research reactors in developing an instrument and building collaborations for capacity building. The development of collimators, detector assemblies, utilization of the SANS for microstructural characterization of advanced materials , development and design of a ultra small angle neutron scattering (USANS) and proposals for a new SANS

X-ray small angle scattering of polymer solutions

International Nuclear Information System (INIS)

Koyama, Ryuzo

1975-01-01

In recent papers, the calculated results were reported on the angular dependence of the intensity of scattered light or X-ray by chain polymers, on the basis of a stiff chain model. As the results, the curves of S 2 P (theta) corresponding to Kratky plot, for different molecular expansion, showed a plateau, and the height of the plateau was proportional to the inverse of molecular expansion coefficient α 2 . But as seen later, there is some possibility that the assumption made in the calculation overestimated the expansion of small segments which theoretically determines scattering curves at large scattering angles, such as the plateau. Accordingly, modified calculation was carried out by adopting the stiff chain polymer model as the previous case. When the contour length of a chain segment is very long, it can be treated approximately as a Gaussian coil, thus the equation for a chain segment expansion coefficient α (t) was obtained. Then the mean square distance of chain segments of polymer molecules was able to be determined, and the equation for a particle scattering factor P(theta) was obtained. The numerical calculation of P(theta) showed that this modified assumption considerably decreased the effect of molecular expansion on P(theta), and the curves of S 2 P(theta) increased monotonously without showing the plateau. The result of this calculation was compared with the experimental curves of polystyrene-toluene solution, and the agreement better than before was obtained. (Kako, I.)

Degradation of periodic multilayers as seen by small-angle x-ray scattering and x-ray diffraction

CERN Document Server

Rafaja, D; Simek, D; Zdeborova, L; Valvoda, V

2002-01-01

The capabilities of small-angle x-ray scattering (SAXS) and wide-angle x-ray diffraction (XRD) to recognize structural changes in periodic multilayers were compared on Fe/Au multilayers with different degrees of structural degradation. Experimental results have shown that both methods are equally sensitive to the multilayer degradation, i.e., to the occurrence of non-continuous interfaces, to short-circuits in the multilayer structure and to the multilayer precipitation. XRD yielded additional information on the multilayer crystallinity, whilst SAXS could better recognize fragments of a long-range periodicity (remnants of the original multilayer structure). Changes in the multilayer structure were initiated by successive annealing at 200 and 300 deg. C. Experimental data were complemented by numerical simulations performed using a combination of optical theory and the distorted wave Born approximation for SAXS or the kinematical Born approximation for XRD.

Segment-segment interactions of poly(N-isopropylacrylamide) in aqueous methanol solutions by using small-angle scattering

International Nuclear Information System (INIS)

Shimizu, S.; Kurita, K.; Furusaka, M.

2002-01-01

Small-angle neutron and X-ray scattering from semidilute solutions of poly(N-isopropylacrylamide) in D 2 O, methanol and methanol-water mixtures has been measured in the poor solvent regime. The binary and the ternary cluster integrals of polymer segments were determined from the concentration dependence of the correlation length at several temperatures just below the lower critical solution temperature. Then, contributions of segment-segment interactions to the entropy and the enthalpy have been calculated from the temperature dependence of interaction parameters and it has been found that both values are positive in the D 2 O and the methanol-water systems at a small content of methanol, while both values are negative in the other system. (orig.)

Time-resolved small-angle neutron scattering of a micelle-to-vesicle transition

Energy Technology Data Exchange (ETDEWEB)

Egelhaaf, S U [Institut Max von Laue - Paul Langevin (ILL), 38 -Grenoble (France); Schurtenberger, P [Eidgenoessische Technische Hochschule, Zurich (Switzerland)

1997-04-01

Amphiphilic molecules spontaneously self-assemble in solution to form a variety of aggregates. Only limited information is available on the kinetics of the structural transitions as well as on the existence of non-equilibrium or metastable states. Aqueous mixtures of lecithin and bile salt are very interesting biological model-systems which exhibit a spontaneous transition from polymer-like mixed micelles to vesicles upon dilution. The small-angle neutron scattering (SANS) instrument D22, with its very high neutron flux and the broad range of scattering vectors covered in a single instrumental setting, allowed us for the first time to perform time-resolved scattering experiments in order to study the micelle-to-vesicle transition. The temporal evolution of the aggregate structures were followed and detailed information was obtained even on molecular length-scales. (author). 5 refs.

Evidence of relationships between texture and structure in smectite systems by small angle synchrotron X ray scattering

International Nuclear Information System (INIS)

Pons, Charles-Henri

1980-01-01

Phyllosilicates are major constituents of soils, and their partially swelled or dispersed states play an important role in sedimentary geology, in soil science, in biochemistry, and also in various technological applications (drilling sludge, oil synthesis catalysts). Properties of these systems are also in direct relationship with problems such as fixation of pollutants by soil (pesticides, heavy metals, radioactive materials, so on). After having recalled works performed during the past forty years on water-smectite dispersions to define prevailing factors of processes of formation of colloidal states, the author presents the different phyllosilicates which have been studied, and recalls the determining factors of inflation and dispersion mechanisms. Then, he recalls methods of interpretation of X diffraction diagrams and of small angle scattering. He reports the detailed study of the inflation mechanism in the case of montmorillonite- Na, and discusses results obtained with other phyllosilicates or with other cations than sodium. In appendix, the author reports the study of bi-ionic (Na-Ca) montmorillonite suspensions prepared by two different methods. He also discusses the method of interpretation of neutron small angle scattering which had been used on similar systems, and shows why this method leads to questionable conclusions

Spin-Echo Small Angle Neutron Scattering analysis of liposomes and bacteria

Science.gov (United States)

van Heijkamp, Léon F.; Sevcenco, Ana-Maria; Abou, Diane; van Luik, Remko; Krijger, Gerard C.; Hagedoorn, Peter-Leon; de Schepper, Ignatz M.; Wolterbeek, Bert; Koning, Gerben A.; Bouwman, Wim G.

2010-10-01

Two types of liposomes, commonly used in drug delivery studies, and E. coli bacteria, all prepared in H2O, were resuspended in D2O and measured with Small Angle Spin-Echo Neutron Scattering (SESANS). Modeling was performed using correlation functions for solid spheres and hollow spheres. The signal strength and curve shape were more indicative of hollow particles, indicating that the H2O-D2O exchange occurred too fast to be observed with the available time resolution. Fitting the particle diameter and membrane thickness of the hollow sphere model to the data, gave results which were in good agreement with Dynamic Light Scattering (DLS) data and literature, showing as a proof-of-principle that SESANS is able to investigate such systems. SESANS may become a good alternative to conventional tritium studies or a tool with which to study intracellular vesicle transport phenomena, with possible in vivo applications. Calculations show that a substantial change in numbers of a mixed system of small and large biological particles should be observable. A possible application is the destruction by external means of great numbers of liposomes in the presence of tumor cells for triggered drug release in cancer treatment. Since SESANS is both non-invasive and non-destructive and can handle relatively thick samples, it could be a useful addition to more conventional techniques.

The application of small-angle neutron scattering to the study of mass transfer in clays

International Nuclear Information System (INIS)

Allen, A.J.; Baston, A.H.; Bourke, P.J.; Jefferies, N.L.

1990-01-01

An extensive study using small angle neutron scattering (SANS) has been made of the pore structures in London Clay and in Ca-montmorillonite. Using SANS contrast variation techniques, the accessibilities of the pores to D 2 O by diffusion and permeation have been studied. Characterisation of the accessibility to different parts of the pore structure is intended to provide input data for models of radionuclide transport through clay geological barriers, and to improve interpretation of laboratory experiments that measure sorption of radionuclides on clays. (author)

Transport cross section for small-angle scattering

International Nuclear Information System (INIS)

D'yakonov, M.I.; Khaetskii, A.V.

1991-01-01

Classical mechanics is valid for describing potential scattering under the conditions (1) λ much-lt α and (2) U much-gt ℎυ/α, where λ is the de Broglie wavelength, α is the characteristic size of the scatterer, U is the characteristic value of the potential energy, and υ is the velocity of the scattered particle. The second of these conditions means that the typical value of the classical scattering angle is far larger than the diffraction angle λ/α. In this paper the authors show that this second condition need not hold in a derivation of the transport cross section. In other words, provided that the condition λ much-lt α holds, it is always possible to calculate the transport cross section from the expressions of classical mechanics, even in the region U approx-lt ℎυ/α, where the scattering is diffractive,and the differential cross section is greatly different from the classical cross section. The transport cross section is found from the classical expression even in the anticlassical case U much-lt ℎυ/α, where the Born approximation can be used

Phase separation process in FeCr alloys studied by neutron small angle scattering

International Nuclear Information System (INIS)

Furusaka, Michihiro; Ishikawa, Yoshikazu; Yamaguchi, Sadae; Fujino, Yutaka.

1986-01-01

The very early stage as well as late stage of phase separation process in FeCr alloys (Fe-20, 30, 40, 60 at%Cr) have been studied by pulsed cold neutron small angle scattering instrument (SAN). At the early stage, scattering intensity I(q) obeys q -2 dependence at the high q side of the scattering function. The results are in accord with the theory of Langer et al. which takes into account nonlinear and thermal fluctuations effects. At the late stage where I(q) shows q -4 dependence, a dynamical scaling law holds, while it is not the case for the earlier stage. Phase diagram of FeCr system is also determined by critical scattering measurements. (author)

Limitation of the Mellin transform for small angle scattering by nearly spherical particles

International Nuclear Information System (INIS)

Melone, S.; Puliti, P.

1983-01-01

An analysis of the limit of validity of the Mellin transform when applied to small angle scattering curves produced by nearly spherical particles, i.e. by ellipsoids of semi-axes, a, a, va, was performed. The width of the assumed Gaussian distribution for the v values was used as a parameter. When this width tends to zero the inaccuracy of the Mellin transform vanishes as expected. However the inaccuracy becomes appreciable for large values of the width. In spite of this, the total volume fraction and the average radius of the scattering particles is also obtained by the Mellin transform with very high accuracy for large values of the width of the Gaussian distribution. (orig.)

A new small-angle X-ray scattering set-up on the crystallography beamline I711 at MAX-lab

DEFF Research Database (Denmark)

Knaapila, M.; Svensson, C.; Barauskas, J.

2009-01-01

A small-angle X-ray scattering (SAXS) set-up has recently been developed at beamline I711 at the MAX II storage ring in Lund (Sweden). An overview of the required modifications is presented here together with a number of application examples. The accessible q range in a SAXS experiment is 0.009-0...

Kinetics of the urea-induced dissociation of human plasma alpha-2-macroglobulin as measured by small-angle neutron scattering

DEFF Research Database (Denmark)

Sjöberg, B.; Pap, S.; Järnberg, S.-E.

1991-01-01

The kinetics of the urea-induced dissociation of human plasma alpha-2-macroglobulin into two half-molecular fragments was investigated at 21.0-degrees-C by using small-angle neutron scattering. The relative change in molecular mass that occurs upon dissociation was monitored by recording the forw...

Time-slicing subsystem of the biology small-angle x-ray scattering station at the National Synchrotron Light Source

International Nuclear Information System (INIS)

Stubblefield, F.W.

1985-11-01

The time-slicing subsystem of the Biology Small-Angle X-ray Scattering divides the time period during which the data for small-angle x-ray diffraction patterns from biological samples is collected into time slices (or frames). The subsystem, being part of a multiprocessor experiment control and data acquisition system, has its own dedicated processor; it also has special-purpose front-end electronics sufficient to generate the gating and other control signals required to produce a sequence of as many as 256 time slices, measured with a basic time unit of 1 μsec. The electronics also synchronizes with execution of the time slice sequence the application of stimuli to the biological sample, the measurement of voltages generated by the sample, and the application of auxiliary device trigger pulses and routes detector data and auxiliary scaler data into appropriate time-slice-indexed buffers in a large external data memory array. The structure of the entire experiment control and data acquisition system is briefly reviewed. Details of the structure and operation of the time slice subsystem are presented. 7 refs., 5 figs

Feasibility study of experiments to measure inclusive reactions at large x/sub F/ in ISABELLE's small-angle hall

International Nuclear Information System (INIS)

Aronson, S.; Danby, G.; Foley, K.; Paige, F.; Thorndike, A.; Engelmann, R.; McCarthy, R.; Pope, B.

1978-01-01

As a way of testing current ideas on the construction of experimental halls at ISABELLE, a particular class of experiments suggested for the small-angle (or 2 o' clock) hall, p + p → p + X and p + p → c + X, c not equal to p is examined. The result of this examination is that inclusive single-particle experiments are feasible over a suitable kinematic range without the use of previously proposed special insertion quadrupoles. The forward single-arm spectrometer is housed in a separate tunnel of modest transverse dimension. The extraction of scattered particles (theta greater than or equal to 1 mrad) into the spectrometer is accomplished with Lambertson septa and current sheet septa. Provision is made for overlap with the kinematic region covered by ISR and Fermilab experiments. The physics objectives of such experiments are reviewed first. Then the general layout of the apparatus is described, with special emphasis on the extraction system and the spectrometer. A guess at how this experiment would fit into the overall small-angle physics program is presented. 5 figures

Small angle X-ray scattering and transmission electron microscopy study of the Lactobacillus brevis S-layer protein

Energy Technology Data Exchange (ETDEWEB)

Jaeaeskelaeinen, Pentti [Department of Biomedical Engineering and Computational Science, PO Box 2200, FI-02015 Aalto University School of Science and Technology (Finland); Engelhardt, Peter [Haartman Institute, Department of Pathology, PO Box 21, FIN-00014 University of Helsinki (Finland); Hynoenen, Ulla; Palva, Airi [Department of Basic Veterinary Sciences, Division of Microbiology, FIN-00014 University of Helsinki (Finland); Torkkeli, Mika; Serimaa, Ritva, E-mail: ritva.serimaa@helsinki.f [Department of Physics, POB 64, 00014 University of Helsinki (Finland)

2010-10-01

The structure of self-assembly domain containing recombinant truncation mutants of Lactobacillus brevis surface layer protein SlpA in aqueous solution was studied using small-angle X-ray scattering and transmission electron microscopy. The proteins were found out to interact with each other forming stable globular oligomers of about 10 monomers. The maximum diameter of the oligomers varied between 75 A and 435 A.

Study of quadrupolar transitions by 108.5 MeV 3He inelastic scattering at small angles. Anomalous behaviour of giant quadrupole resonance

International Nuclear Information System (INIS)

Bouhelal, O.K.

1982-07-01

Giant resonances have been studied through the inelastic scattering of 108.5 MeV 3 He on several nuclei. At the very small angles (theta 0 ), the quadrupole giant resonance experimental cross-section is about twice the value predicted by DWBA calculations based on a collective model. The comparison of the experimental data and the theoretical data calculations confirms the validity of DWBA for the first excited state of low energy and same multipolarity L = 2 at the very small angles. The angular distribution for L = 0 transition of energy close to that of the quadrupole giant resonance reaches its maximum at 0 0 . The presence of an L = 0 component permits to describe the shape of the quadrupole giant resonance angular distribution, but difficulties are encountered when applying the sum rule for the heavy nuclei. Better agreement with the experimental angular distribution at small angles is obtained if a semimicroscopic convolution model of the quadrupole resonance is assumed. For excited states of low energy and multipolarity L not equal to 2, the results from the convolution model are as good as those from the standard collective model. The 2 + state in heavy nuclei is, however, much better described by the collective model [fr

Interactive graphical system for small-angle scattering analysis of polydisperse systems

International Nuclear Information System (INIS)

Konarev, P V; Volkov, V V; Svergun, D I

2016-01-01

A program suite for one-dimensional small-angle scattering analysis of polydisperse systems and multiple data sets is presented. The main program, POLYSAS , has a menu-driven graphical user interface calling computational modules from ATSAS package to perform data treatment and analysis. The graphical menu interface allows one to process multiple (time, concentration or temperature-dependent) data sets and interactively change the parameters for the data modelling using sliders. The graphical representation of the data is done via the Winteracter-based program SASPLOT . The package is designed for the analysis of polydisperse systems and mixtures, and permits one to obtain size distributions and evaluate the volume fractions of the components using linear and non-linear fitting algorithms as well as model-independent singular value decomposition. The use of the POLYSAS package is illustrated by the recent examples of its application to study concentration-dependent oligomeric states of proteins and time kinetics of polymer micelles for anticancer drug delivery. (paper)

Small-angle neutron scattering and rheological analyses of nanoemulsion for cosmetics

International Nuclear Information System (INIS)

Kume, Takuji

2014-01-01

A stable nanoemulsion consisting of nanometer-sized oil droplets in water having a self-standing capability was prepared by high-pressure emulsification. Rheological measurements show that the nanoemulsion has a high viscosity and a yield stress. Small-angle neutron scattering (SANS) revealed the presence of an ordered crystal-like lattice structure in addition to spherical domains with a diameter of ca. 30 nm. Nonfluidity of nanoemulsion is ascribed to crystal-like lattice structure of nanodroplets. A mixed solution of 2-hydroxyethyl cellulose and the nanoemulsion has shear-thickening behavior (shear-induced gelation). Real-time SANS measurements with a Couette geometry as a function of shear rate (Rheo-SANS) revealed that a possible mechanism of gelation was proposed from the viewpoint of shear-induced percolation transition. Furthermore, mixtures of the nanoemulsion and poly(acrylic acid) solutions were opaque and kept the same interdomain distance and high viscosity. We estimated that it had phase-separated structure between nanoemulsion phase and poly(acrylic acid) solution phase. (author)

Small angle neutron scattering study on a phase separation in a 3-component microemulsion system

International Nuclear Information System (INIS)

Seto, Hideki; Yokoi, Eiji; Komura, Shigehiro; Schwahn, Dietmar; Mortensen, Kell; Suzuki, Junichi; Funahashi, Satoru; Ito, Yuji.

1993-01-01

The mixture of three components, water, n-decane and 2-ethylhexylsulfosuccinate (AOT), is a well-known system that forms a 'water-in-oil' microemulsion at room temperature and decomposes with increasing temperature, thereby being associated with a critical phenomenon. Experimental results in previous literature, indicate that the phenomenon is interpreted to be that of the 3D-Ising, but we obtained the meanfield behavior of the susceptibility at 'near-critical region' by a small angle neutron scattering. The observed spinodal and binodal points were well explained assuming the van der Waals free energy expression. (author)

Investigation of the cluster structure in aqueous suspensions of nanodiamonds by small-angle neutron scattering

International Nuclear Information System (INIS)

Bulavin, L.A.; Tomchuk, O.V.; Avdeev, M.V.

2015-01-01

The paper presents the results of the structural study of various types of the water-detonation nanodiamond liquid systems, which are obtained by small-angle scattering of thermal neutrons. It was shown that in the mass fraction range (0.3/1.8) % the experimental spectra are well described by a two-level model of unified exponential/power-law approach. The resulting structural parameters allowed us to estimate the aggregation number in the studied systems. Sizes of the nanodiamond particles and their clusters are found as well as the fractal dimension of the latter

Segment-segment interactions of poly(N-isopropylacrylamide) in aqueous methanol solutions by using small-angle scattering

CERN Document Server

Shimizu, S; Furusaka, M

2002-01-01

Small-angle neutron and X-ray scattering from semidilute solutions of poly(N-isopropylacrylamide) in D sub 2 O, methanol and methanol-water mixtures has been measured in the poor solvent regime. The binary and the ternary cluster integrals of polymer segments were determined from the concentration dependence of the correlation length at several temperatures just below the lower critical solution temperature. Then, contributions of segment-segment interactions to the entropy and the enthalpy have been calculated from the temperature dependence of interaction parameters and it has been found that both values are positive in the D sub 2 O and the methanol-water systems at a small content of methanol, while both values are negative in the other system. (orig.)

Analysis of the aggregation structure from amphiphilic block copolymers in solutions by small-angle x-ray scattering

CERN Document Server

Rong Li Xia; Wang Jun; Wei Liu He; Li Fu Mian; Li Zi Chen

2002-01-01

The aggregation structure of polystyrene-p vinyl benzoic amphiphilic block copolymers which were prepared in different conditions was investigated by synchrotron radiation small-angle x-ray scattering (SAXS). The micelle was self-assembled in selective solvents of the block copolymers. Authors' results demonstrate that the structure of the micelle depends on the factors, such as the composition of the copolymers, the nature of the solvent and the concentration of the solution

Investigating the Nanoporous Structure of Aluminosilicate Geopolymers with Small Angle Scattering and Imaging Techniques

International Nuclear Information System (INIS)

Maitland, C.F.; Buckley, C.E.; O'Connor, B.H.; Rowles, M.R.; Hart, R.D.; Gilbert, E.P.; Connolly, J.

2005-01-01

Full text: Rowles and O'Connor optimised the compressive strength of a geopolymer produced by sodium silicate-activation of metakaolinite, and found that this material may have a greater compressive strength than ordinary Portland cement. It has been observed that similar metakaolin-based geopolymers have a multiscale structure that consists of partially dissolved metakaolinite embedded in a nanoporous matrix. The characteristics of the nanostructure within this matrix influence the physical properties of the geopolymer. An investigation, using small-angle neutron scattering and imaging techniques, into how the matrix nanostructure varies with chemical composition of the starting material has been undertaken. The results of this investigation will be reported. (authors)

Anomalous small-angle x-ray scattering of a femtosecond irradiated germano silicate fibre preform.

Energy Technology Data Exchange (ETDEWEB)

Hindle, F.; Fertein, E.; Seifert, S.; Przygodski, C.S.; Bocquet, R.; Douay, M.; Bychkov, E.; Experimental Facilities Division (APS); LPCA, CNRS; PhLAM; Univ. des Sciences et Tech. de Lille

2005-01-01

RADIATION is shown to induce significant mesoscopic structure. The scattering intensity for irradiated glasses is close to two orders of magnitude greater than that of unexposed material. Anomalous small-angle X-ray scattering (ASAXS) around the germanium K-edge for the silica and germanium doped silica regions of a fiber preform is used to demonstrate that identical structures are induced in both glass materials, with germanium displaying a capacity to isomorphically replace silicon in the case of the germanium doped silica. Analysis of measured scattering indicates that photo-inscribed features are produced at two distinct scales with typical radii of R {approx} 20 Angstroms and R{sub min} {approx} 200 Angstroms.

Robust, high-throughput solution structural analyses by small angle X-ray scattering (SAXS)

Energy Technology Data Exchange (ETDEWEB)

Hura, Greg L.; Menon, Angeli L.; Hammel, Michal; Rambo, Robert P.; Poole II, Farris L.; Tsutakawa, Susan E.; Jenney Jr, Francis E.; Classen, Scott; Frankel, Kenneth A.; Hopkins, Robert C.; Yang, Sungjae; Scott, Joseph W.; Dillard, Bret D.; Adams, Michael W. W.; Tainer, John A.

2009-07-20

We present an efficient pipeline enabling high-throughput analysis of protein structure in solution with small angle X-ray scattering (SAXS). Our SAXS pipeline combines automated sample handling of microliter volumes, temperature and anaerobic control, rapid data collection and data analysis, and couples structural analysis with automated archiving. We subjected 50 representative proteins, mostly from Pyrococcus furiosus, to this pipeline and found that 30 were multimeric structures in solution. SAXS analysis allowed us to distinguish aggregated and unfolded proteins, define global structural parameters and oligomeric states for most samples, identify shapes and similar structures for 25 unknown structures, and determine envelopes for 41 proteins. We believe that high-throughput SAXS is an enabling technology that may change the way that structural genomics research is done.

Polymer boosting effect in the droplet phase studied by small-angle neutron scattering

CERN Document Server

Frielinghaus, H; Allgaier, J; Richter, D; Jakobs, B; Sottmann, T; Strey, R

2002-01-01

Small-angle neutron-scattering experiments were performed in order to obtain the six partial scattering functions of a droplet microemulsion containing water, decane, C sub 1 sub 0 E sub 4 surfactant and PEP sub 5 -PEO sub 8 sub 0. We systematically varied the contrast around the polymer contrast, where only the polymer becomes visible, and we also measured bulk and film contrasts. With the singular value decomposition method we could extract the desired six partial scattering functions from the 15 measured spectra. We find a sphere-shell-shell structure of the droplets, where the innermost sphere consists of oil, the middle shell of surfactant and the outer shell is a depletion zone where the polymer is almost not present. (orig.)

Interpretation and Utility of the Moments of Small-Angle X-Ray Scattering Distributions.

Science.gov (United States)

Modregger, Peter; Kagias, Matias; Irvine, Sarah C; Brönnimann, Rolf; Jefimovs, Konstantins; Endrizzi, Marco; Olivo, Alessandro

2017-06-30

Small angle x-ray scattering has been proven to be a valuable method for accessing structural information below the spatial resolution limit implied by direct imaging. Here, we theoretically derive the relation that links the subpixel differential phase signal provided by the sample to the moments of scattering distributions accessible by refraction sensitive x-ray imaging techniques. As an important special case we explain the scatter or dark-field contrast in terms of the sample's phase signal. Further, we establish that, for binary phase objects, the nth moment scales with the difference of the refractive index decrement to the power of n. Finally, we experimentally demonstrate the utility of the moments by quantitatively determining the particle sizes of a range of powders with a laboratory-based setup.

Small-angle neutron scattering study of the ultrastructure of chloroplast thylakoid membranes - Periodicity and structural flexibility of the stroma lamellae

DEFF Research Database (Denmark)

Posselt, Dorthe; Nagy, Gergely; Kirkensgaard, Jacob J. K.

2012-01-01

The multilamellar organization of freshly isolated spinach and pea chloroplast thylakoid membranes was studied using small-angle neutron scattering. A broad peak at similar to 0.02 angstrom(-1) is ascribed to diffraction from domains of ordered, unappressed stroma lamellae, revealing a repeat dis...

Study of the M23C6 precipitation in AISI 304 stainless steel by small angle neutron scattering

International Nuclear Information System (INIS)

Boeuf, A.; Caciuffo, R.G.M.; Institut Max von Laue - Paul Langevin, 38 - Grenoble; Ancona Univ.; Melone, S.; Puliti, P.; Rustichelli, F.; Institut Max von Laue - Paul Langevin, 38 - Grenoble; Ancona Univ.; Coppola, R.

1985-01-01

The results of some small-angle neutron scattering (SANS) experiments on M 23 C 6 (M=Fe, Cr) carbide precipitation in AISI 304 stainless steel, aged at different temperatures during different times, are presented. The total volume fraction, the total surface of precipitates per unit sample volume and the size distribution functions of the M 23 C 6 carbides were determined. (orig.)

Measuring helium bubble diameter distributions in tungsten with grazing incidence small angle x-ray scattering (GISAXS)

Science.gov (United States)

Thompson, M.; Kluth, P.; Doerner, R. P.; Kirby, N.; Riley, D.; Corr, C. S.

2016-02-01

Grazing incidence small angle x-ray scattering was performed on tungsten samples exposed to helium plasma in the MAGPIE and Pisces-A linear plasma devices to measure the size distributions of resulting helium nano-bubbles. Nano-bubbles were fitted assuming spheroidal particles and an exponential diameter distribution. These particles had mean diameters between 0.36 and 0.62 nm. Pisces-A exposed samples showed more complex patterns, which may suggest the formation of faceted nano-bubbles or nano-scale surface structures.

Small-angle neutron scattering of short-segment block polymers

International Nuclear Information System (INIS)

Cooper, S.L.; Miller, J.A.; Homan, J.G.

1988-01-01

Small-angle neutron scattering has been used to investigate the chain conformation of the hard and soft segments in short-segment polyether-polyester and polyether-polyurethane materials. The method of phase-contrast matching was used to eliminate the coherent neutron scattering due to the two-phase microstructure in these materials. The partial deutero-labelling necessary for this technique also provides a neutron scattering contrast between labelled and unlabelled segments. The structure factor for each segment type is determined from the coherent scattering from such deuterolabelled materials. In all of the materials examined, the poly(tetramethylene oxide) (PTMO) soft segment was found to be in a slightly extended conformation relative to bulk PTMO at room temperature. Upon heating, the PTMO segments contracted to a more relaxed conformation. In one polyether-polyurethane sample, the radius of gyration of the PTMO segment increased again at high temperatures, indicating phase mixing. The hardsegment radii of gyration in the polyether-polyester materials were found to increase with temperature, indicating a transition from a chain-folded conformation at room temperature to a more extended conformation at higher temperatures. The radius of gyration of the whole polyether-polyester chain first decreased then increased with temperature, indicative of the combined effects of the component hard- and soft-segment chain conformation changes. The hard-segment radius of gyration in a polyether-polyurethane was observed to decrease with temperature. (orig.)

Looking for the best experimental conditions to detail the protein solvation shell in a binary aqueous solvent via small angle scattering

International Nuclear Information System (INIS)

Ortore, Maria Grazia; Sinibaldi, Raffaele; Spinozzi, Francesco; Carbini, Andrea; Carsughi, Flavio; Mariani, Paolo

2009-01-01

Protein hydration features attract particular interest in different fields, from biology up to physics, crossing chemistry and medicine. Particular attention is devoted to proteins dissolved in binary aqueous mixtures, since the presence of cosolvent can induce modifications in structural and functional properties. We have recently developed a methodology to obtain a quantitative description on protein solvation shell by a set of in-solution small angle scattering experiments, simultaneously analysed by a global-fit approach. In this paper, numerical simulations of small angle scattering curves are presented to figure out the sensitivity of the technique to different experimental conditions. Simulations concern two model proteins of different molecular weights and an unique cosolvent. A reliability test is introduced in order to find the best experimental conditions to be investigated, together with the most suitable scattering probe (neutrons or X-rays).

SANS [small-angle neutron scattering] evaluation of the RPA [random phase approximation] theory for binary homopolymer mixtures

International Nuclear Information System (INIS)

Bates, F.S.; Koehler, W.C.; Wignall, G.D.; Fetters, L.J.

1986-12-01

A well characterized binary mixture of normal (protonated) and perdeuterated monodisperse 1,2 polybutenes has been studied by small-angle neutron scattering (SANS). For scattering wavevectors q greater than the inverse radius-of-gyration R/sub g/ -1 , the SANS intensity is quantitatively predicted by the random phase approximation (RPA) theory of deGennes over all measured values of the segment-segment interaction parameter Chi. In the region (Chi s-Chi)Chi s -1 > 0.5 the interaction parameter determined using the RPA theory for q > R/sub g/ -1 is greater than that calculated from the zero-angle intensity based on an Ornstein-Zernike plot, where Chi s represents the limit of single phase stability. These findings indicate a correlation between the critical fluctuation length ξ and R/sub g/ which is not accounted for by the RPA theory

RMCSANS-modelling the inter-particle term of small angle scattering data via the reverse Monte Carlo method

International Nuclear Information System (INIS)

Gereben, O; Pusztai, L; McGreevy, R L

2010-01-01

A new reverse Monte Carlo (RMC) method has been developed for creating three-dimensional structures in agreement with small angle scattering data. Extensive tests, using computer generated quasi-experimental data for aggregation processes via constrained RMC and Langevin molecular dynamics, were performed. The software is capable of fitting several consecutive time frames of scattering data, and movie-like visualization of the structure (and its evolution) either during or after the simulation is also possible.

Determination of the thermodynamic state of concentrated hemoglobin solutions by means of small angle X-ray scattering

International Nuclear Information System (INIS)

Zinke, M.

1979-01-01

Exemplified by hemoglobin, the thermodynamic equilibrium properties of the dissolved macromolecular system could be determined solely from the small angle X-ray scattering of concentrated macromolecular solutions via the intermolecular structure of the dissolved macromolecules and their intermolecular potentials. From the scattering experiment on concentrated Hb solutions the concentration dependence of the following properties of the dissolved Hb system were determined: fluctuation, isothermic compressibility, internal energy, surface tension, and osmotic pressure. (author)

Small angle x-ray studies reveal that Aspergillus niger glucoamylase has a defined extended conformation and can form dimers in solution

DEFF Research Database (Denmark)

Jørgensen, Anders Dysted; Nøhr, Jane; Kastrup, Jette Sandholm

2008-01-01

is poorly understood and structurally undescribed, and data regarding domain organization and intramolecular functional cooperativity are conflicting or non-comprehensive. Here, we report a combined small angle x-ray scattering and calorimetry study of Aspergillus niger glucoamylase 1, glucoamylase 2, which...

PREFACE Proceedings of the XIV International Conference on Small-Angle Scattering, SAS-2009

Science.gov (United States)

King, Stephen; Terrill, Nicholas

2010-10-01

The XIV International Conference on Small-Angle Scattering, SAS-2009, was held in Oxford UK, 13-18 September 2009, and was jointly organised under the auspices of the International Union of Crystallography Commission on SAS by a team from the Diamond Light Source and the ISIS Pulsed Neutron Source - their first such joint venture - with help from the UK Science and Technology Facilities Council. It was the first time that this long running and successful series of conferences on the application, science and technology of small-angle scattering techniques had been staged in the UK. The UK has a proud heritage in small-angle scattering: as home to one of the world's first SANS instruments (at AERE Harwell), as the site of the world's first 2nd generation X-ray Synchrotron (the SRS at Daresbury with its suite of SAXS beamlines), and latterly as the location of the world's most successful pulsed source SANS instrument. Indeed, 2009 also marked the 25th Anniversary of neutron operations at ISIS and the opening of a Second Target Station. Whilst the SRS ceased operations in 2008, its mantle has been inherited by the Diamond synchrotron. Many delegates took the opportunity to visit both Diamond and ISIS during a conference excursion. Despite the prevailing global economic downturn, we were delighted that 434 delegates from 32 different countries were able to attend SAS-2009; two-thirds were drawn from the UK, Germany, Japan, the USA and France, but there were also sizeable contingents from Australia, Korea, Taiwan and South America. In many ways this geographical spread reflects the present and emerging distribution, respectively, of 3rd generation X-ray synchrotrons and high-flux neutron sources, although the scope of the conference was not solely limited to these probes. Financial support from the IUCr enabled us to grant bursaries to attend SAS-2009 to 12 delegates from emerging countries (Algeria, Argentina, Brazil, India, Nepal, Romania, Russia and the Ukraine). The

Application of small-angle X-ray scattering for differentiation among breast tumors

International Nuclear Information System (INIS)

Changizi, V.; Kheradmand, A. Arab; Oghabian, M.A.

2008-01-01

Small-angle X-ray scattering (SAXS) is an X-ray diffraction-based technique where a narrow collimated beam of X-rays is focused onto a sample and the scattered X-rays recorded by a detector. The pattern of the scattered X-rays carries information on the molecular structure of the material. As breast cancer is the most widespread cancer in women and differentiation among its tumors is important, this project compared the results of coherent X-ray scattering measurements obtained from benign and malignant breast tissues. The energy-dispersive method with a setup including X-ray tube, primary collimator, sample holder, secondary collimator and high-purity germanium (HpGe) detector was used. One hundred thirty-one breast-tissue samples, including normal, fibrocystic changes and carcinoma, were studied at the 6 deg scattering angle. Diffraction profiles (corrected scattered intensity versus momentum transfer) of normal, fibrocystic changes and carcinoma were obtained. These profiles showed a few peak positions for adipose (1.15 ± 0.06 nm -1 ), mixed normal (1.15 ± 0.06 nm -1 and 1.4 ± 0.04 nm -1 ), fibrocystic changes (1.46 ± 0.05 nm -1 and 1.74 ± 0.04 nm -1 ) and carcinoma (1.55 ± 0.04 nm -1 , 1.73 ± 0.06 nm -1 , 1.85 ± 0.05 nm -1 ). We were able to differentiate between normal, fibrocystic changes (benign) and carcinoma (malignant) breast tissues by SAXS. However, we were unable to differentiate between different types of carcinoma. (author)

Application of small-angle X-ray scattering for differentiation among breast tumors

Directory of Open Access Journals (Sweden)

Changizi V

2008-01-01

Full Text Available Small-angle X-ray scattering (SAXS is an X-ray diffraction-based technique where a narrow collimated beam of X-rays is focused onto a sample and the scattered X-rays recorded by a detector. The pattern of the scattered X-rays carries information on the molecular structure of the material. As breast cancer is the most widespread cancer in women and differentiation among its tumors is important, this project compared the results of coherent X-ray scattering measurements obtained from benign and malignant breast tissues. The energy-dispersive method with a setup including X-ray tube, primary collimator, sample holder, secondary collimator and high-purity germanium (HpGe detector was used. One hundred thirty-one breast-tissue samples, including normal, fibrocystic changes and carcinoma, were studied at the 6° scattering angle. Diffraction profiles (corrected scattered intensity versus momentum transfer of normal, fibrocystic changes and carcinoma were obtained. These profiles showed a few peak positions for adipose (1.15 ± 0.06 nm -1 , mixed normal (1.15 ± 0.06 nm -1 and 1.4 ± 0.04 nm -1 , fibrocystic changes (1.46 ± 0.05 nm -1 and 1.74 ± 0.04 nm -1 and carcinoma (1.55 ± 0.04 nm -1 , 1.73 ± 0.06 nm -1 , 1.85 ± 0.05 nm -1 . We were able to differentiate between normal, fibrocystic changes (benign and carcinoma (malignant breast tissues by SAXS. However, we were unable to differentiate between different types of carcinoma.

Metastatic Extrapulmonary Small Cell Carcinoma to the Cerebellopontine Angle: A Case Report and Review of the Literature

Directory of Open Access Journals (Sweden)

Debebe Theodros

2015-01-01

Full Text Available Extrapulmonary small cell carcinomas (EPSCC are rare malignancies with poor patient prognoses. We present the case of a 63-year-old male who underwent surgical resection of a poorly differentiated small cell carcinoma, likely from a small intestinal primary tumor that metastasized to the cerebellopontine angle (CPA. A 63-year-old male presented with mild left facial paralysis, hearing loss, and balance instability. MRI revealed a 15 mm mass in the left CPA involving the internal auditory canal consistent with a vestibular schwannoma. Preoperative MRI eight weeks later demonstrated marked enlargement to 35 mm. The patient underwent a suboccipital craniectomy and the mass was grossly different visually and in consistency from a standard vestibular schwannoma. The final pathology revealed a poorly differentiated small cell carcinoma. Postoperative PET scan identified avid uptake in the small intestine suggestive of either a small intestinal primary tumor or additional metastatic disease. The patient underwent whole brain radiation therapy and chemotherapy and at last follow-up demonstrated improvement in his symptoms. Surgical resection and radiotherapy are potential treatment options to improve survival in patients diagnosed with NET brain metastases. We present the first documented case of skull base metastasis of a poorly differentiated small cell carcinoma involving the CPA.

Investigation of the cluster structure in aqueous suspensions of nanodiamonds by small-angle neutron scattering

Directory of Open Access Journals (Sweden)

L. A. Bulavin

2015-07-01

Full Text Available The paper presents the results of the structural study of various types of the water-detonation nanodiamond liquid systems, which are obtained by small-angle scattering of thermal neutrons. It was shown that in the mass fraction range (0.3 - 1.8 % the experimental spectra are well described by a two-level model of unified exponential/power-law approach. The resulting structural parameters allowed us to estimate the aggregation number in the studied systems. Sizes of the nanodiamond particles and their clusters are found as well as the fractal dimension of the latter.

Structural dissection of human metapneumovirus phosphoprotein using small angle x-ray scattering.

Science.gov (United States)

Renner, Max; Paesen, Guido C; Grison, Claire M; Granier, Sébastien; Grimes, Jonathan M; Leyrat, Cédric

2017-11-01

The phosphoprotein (P) is the main and essential cofactor of the RNA polymerase (L) of non-segmented, negative-strand RNA viruses. P positions the viral polymerase onto its nucleoprotein-RNA template and acts as a chaperone of the nucleoprotein (N), thereby preventing nonspecific encapsidation of cellular RNAs. The phosphoprotein of human metapneumovirus (HMPV) forms homotetramers composed of a stable oligomerization domain (P core ) flanked by large intrinsically disordered regions (IDRs). Here we combined x-ray crystallography of P core with small angle x-ray scattering (SAXS)-based ensemble modeling of the full-length P protein and several of its fragments to provide a structural description of P that captures its dynamic character, and highlights the presence of varyingly stable structural elements within the IDRs. We discuss the implications of the structural properties of HMPV P for the assembly and functioning of the viral transcription/replication machinery.

Search for small-angle neutron scattering in MnO at 1700K

International Nuclear Information System (INIS)

Routbort, J.L.; Epperson, J.E.; Klippert, T.E.; Goretta, K.C.

1986-01-01

A preliminary small-angle scattering (SANS) experiment has been performed on MnO single crystal at the Intense Pulsed Neutron Source. The experiment was preformed at 1700 0 K at oxygen partial pressures of 2.2 x 10 -4 , 1 x 10 2 , and 2 x 10 2 Pa, which resulted in deviations from stoichiometry of about 0.0015, 0.082, and 0.127. No statistically significant change in SANS was observed at this temperature with the pressure changes. Neither was any significant change observed in the wavelength-dependent sample transmission, also measured in-situ as a function of pressure. Therefore, either clustering of cation vacancies is negligible in MnO for these conditions, or the clusters are smaller than about 5 A. Of proposed cluster configurations, only the existence of the smallest (4:1, 6:2, or possible 8:3) appears to be consistent with these results

Small angle x-ray scattering as a potential tool for cancer diagnosis

International Nuclear Information System (INIS)

Kitchen, M.; Siu, K.K.W.; Lewis, R.A.

2003-01-01

Full text: The diagnostic potential of Small Angle X-ray Scattering (SAXS) patterns has recently been investigated for malignant breast tissues. The demonstrated systematic differences in the scattering signatures of malignant, benign and normal breast tissue specimens are believed to arise from the changes in the fibrous proteins making up the extracellular matrix (ECM) with the disease progression. The technique may also have the potential to aid in the diagnosis of gliomas, a highly aggressive type of brain tumour. Although complex and difficult to interpret, SAXS data from malignant tissues may prove to be a more effective classification tool than conventional histology techniques. Here we present the methodology of the technique, as applied to breast cancer and brain tumour specimens to date, and some directions for future investigations. We also present a novel analysis method, which employs wavelet decomposition and a naive Bayesian classifier, as a potential semi-automated classification tool

Small-angle X-ray scattering studies of thermally-induced globular protein gels

International Nuclear Information System (INIS)

Clark, A.H.; Tuffnell, C.D.

1980-01-01

Small-angle X-ray scattering has been applied to gels formed by heating globular proteins, in aqueous solution, above their unfolding temperatures. A number of BSA gels, previously characterised by electron microscopy, have been studied, and by setting up theoretical models for the scattering process, the X-ray data have been shown to be consistent with the microscope conclusions regarding network structure. It is concluded that the networks form by a linearly-directed aggregation of unfolded, disc-like, protein molecules, three-dimensional geometry being achieved by occasional branching, and/or cross-linking. Long-range inhomogeneities in network structure, easily observed by electron microscopy, and correlated with variations in pH or ionic strength, have an effect on X-ray scattering, and hence the X-ray method is sensitive not only to different network strand thicknesses, but to different degrees of uniformity as well. (author)

Time-of-flight small-angle neutron scattering data reduction and analysis at LANSCE with program SMR

International Nuclear Information System (INIS)

Hjelm, R.P. Jr.; Seeger, P.A.

1988-01-01

A user-friendly integrated system, SMR, for the display, reduction and analysis of data from time-of-flight small-angle neutron diffractometers is described. Its purpose is to provide facilities for data display and assessment, and to provide these facilities in near real time. This allows the results of each scattering measurement to be available almost immediately, and enables the user to use the results of a measurement as a basis for other measurements in the same time allocation of the instrument. 8 refs., 10 figs

Energy dependent modulation of the ulf ion flux oscillations observed at small pitch angles

International Nuclear Information System (INIS)

Su, S.; Konradi, A.; Fritz, T.A.

1979-01-01

The characteristics of the ultralow frequency oscillations in the ion fluxes observed at small pitch angles by the National Oceanic and Atmospheric Adminstration detector telescopes on board ATS 6 are again examined. The present report concentrates on the dramatic variation of the flux modulations detected in various energy channels during a single event which occurred on February 18, 1975. The wave amplitude is observed to be larger in a higher energy channel with energies from 100 keV to 150 keV and to decrease toward the lower energy channels. The lowest-energy protons (25--33 keV) in general are seldom seen to be oscillating, but in this event they display a low-amplitude oscillation which is 180 0 out of p ase with the adjacent channel. Such energy dependent modulation of the flux oscillation is thought to be a consequence of the wave particle resonant interaction. However, the prediction of the bounce resonant interaction is not consistent with the observations of both the energy dependent variation of the flux amplitudes and a 180 0 change in the oscillation phase in the adjacent low-energy channels that occurred in the February 18, 1975, event. Since the shape of the undisturned particle distribution can also determine the variation of the particle perturbation at various energies, the first-order particle distribution derived in a homogeneous plasma with a uniform magnetic field is examined without any specification of the wave mode. When the average particle distribution during the wave observation is used together with a parallel wave electric field that presumably causes the flux modulation at small pitch angles, a reasonable agreement is found between the variation of flux modulation derived from the slope of the average particle distribution and that from the experimental observation

Small angle neutron and x-ray scattering studies of self-assembled nano structured materials

International Nuclear Information System (INIS)

Choi, Sung Min

2009-01-01

Full text: Small angle neutron and x-ray scattering are very powerful techniques to investigate nano structured materials. In this presentation, examples of nano structured materials investigated by neutron and x-ray scattering will be presented. Part I: The unique anisotropic physical properties of columnar discotic liquid crystals (DLCs) have attracted considerable interest for their potential applications as electronic devices. For many practical applications, however, it is crucial to obtain uniaxially oriented and highly ordered columnar superstructures of DLC molecules covering macroscopic area. Here, we present a simple and straight-forward approach to fabricate uniaxially oriented and highly ordered columnar superstructures of cobalt octa(n-decylthio) porphyrazine (CoS 1 0), a discotic supra-molecule, in bulk and on substrates [1] over a macroscopic length scale, utilizing an applied magnetic field and the interaction of CoS 1 0 with an OTS-functionalized substrate. The details of the oriented and ordered columnar nano-structures are investigated by SANS and GISAXS. Part II: Self-assembly of one-dimensional (1D) nanoparticles with metallic or semiconducting properties into highly ordered superstructures using various interactions has been of great interest as a route towards materials with new functionalities. Here, we report a new phase diagram of negatively charged 1D nanoparticle (cROD) and cationic liposome (CL) complexes in water which exhibit three different highly ordered phases [2]. Small angle neutron and x-ray scattering measurements show that the cROD-CL complexes exhibit three different highly ordered phases, intercalated lamellar, doubly intercalated lamellar and centered rectangular phases, depending on particle curvature and electrostatic interactions. The new phase diagram can be used to understand and design new highly ordered self-assemblies of 1D nanoparticles in soft matter which provide new functionalities. (author)

Small-angle neutron scattering study of D2O-alcohol solutions

International Nuclear Information System (INIS)

D'Arrigo, G.

1990-01-01

Small-angle neutron scattering (SANS) measurements have been carried out on heavy water solutions of ethanol, isopropyl alcohol, n-propyl alcohol, t-butyl alcohol and butoxyethanol between 5 and 37 0 C at the concentrations where ultrasonic attenuation exhibits peak values. The wavevector dependence and the absolute intensity of the scattered intensities were analysed according to a microscopic model of the solutions in terms of aggregated complexes. The results indicate that at 25 0 C there exist either alcohol 'micelle-like' structures or alcohol-heavy water complexes which increase on going from the lower to higher alcohol solutions. As temperature increases from 25 to 37 0 C a higher aggregation is observed in butyl alcohol and butoxyethanol solutions. This behaviour is attributed to the demixing tendency of these systems at high temperatures. On going from 25 to 5 0 C the aggregation increases again. This trend is associated with the anomalous behaviour of the specific heat and ultrasonic attenuation of these systems. The occurrence of a low-temperature phase transition suggested by these anomalies is supported by our results. (author)

Automated acquisition and analysis of small angle X-ray scattering data

International Nuclear Information System (INIS)

Franke, Daniel; Kikhney, Alexey G.; Svergun, Dmitri I.

2012-01-01

Small Angle X-ray Scattering (SAXS) is a powerful tool in the study of biological macromolecules providing information about the shape, conformation, assembly and folding states in solution. Recent advances in robotic fluid handling make it possible to perform automated high throughput experiments including fast screening of solution conditions, measurement of structural responses to ligand binding, changes in temperature or chemical modifications. Here, an approach to full automation of SAXS data acquisition and data analysis is presented, which advances automated experiments to the level of a routine tool suitable for large scale structural studies. The approach links automated sample loading, primary data reduction and further processing, facilitating queuing of multiple samples for subsequent measurement and analysis and providing means of remote experiment control. The system was implemented and comprehensively tested in user operation at the BioSAXS beamlines X33 and P12 of EMBL at the DORIS and PETRA storage rings of DESY, Hamburg, respectively, but is also easily applicable to other SAXS stations due to its modular design.

Magnetic particles studied with neutron depolarization and small-angle neutron scattering

International Nuclear Information System (INIS)

Rosman, R.

1991-01-01

Materials containing magnetic single-domain particles, referred to as 'particulate media', have been studied using neutron depolarization (ND) and small-angle neutron scattering (SANS). In a ND experiment the polarization vector of a polarized neutron beam is analyzed after transmission through a magnetic medium. Such an analysis in general yields the correlation length of variations in magnetic induction along the neutron path (denoted 'magnetic correlation length'), mean orientation of these variations and mean magnetic induction. In a SANS experiment, information about nuclear and magnetic inhomogeneities in the medium is derived from the broadening of a generally unpolarized neutron beam due to scattering by these inhomogeneities. Spatial and magnetic microstructure of a variety of particulate media have been studied using ND and/or SANS, by determination of the magnetic or nuclear correlation length in these media in various magnetic states. This thesis deals with the ND theory and its application to particulate media. ND and SANS experiments on a variety of particulate media are discussed. (author). 178 refs., 97 figs., 8 tabs

Small angle neutron scattering modeling of copper-rich precipitates in steel

International Nuclear Information System (INIS)

Spooner, S.

1997-11-01

The magnetic to nuclear scattering intensity ratio observed in the scattering from copper rich precipitates in irradiated pressure vessel steels is much smaller than the value of 11.4 expected for a pure copper precipitate in iron. A model for precipitates in pressure vessel steels which matches the observed scattering typically incorporates manganese, nickel, silicon and other elements and it is assumed that the precipitate is non-magnetic. In the present work consideration is given to the effect of composition gradients and ferromagnetic penetration into the precipitate on the small angle scattering cross section for copper rich clusters as distinguished from conventional precipitates. The calculation is an extension of a scattering model for micelles which consist of shells of varying scattering density. A discrepancy between recent SANS scattering experiments on pressure vessel steels was found to be related to applied magnetic field strength. The assumption of cluster structure and its relation to atom probe FIM findings as well as the effects of insufficient field for magnetic saturation is discussed

Kappa-casein micelles: structure, interaction and gelling studied by small-angle neutron scattering.

Science.gov (United States)

de Kruif, C G; May, R P

1991-09-01

Small-angle neutron scattering (SANS) measurements on dilute and concentrated dispersions of kappa-casein micelles in a buffer at pH = 6.7 were made using the D11 diffractometer in Grenoble. Results indicate that the micelles have a dense core with a fluffy outer layer. This outer layer appears to give rise to a steeply repulsive interaction on contact. In fact, the hard-sphere model best fits the measured scattering intensities. Adding chymosin to the dispersion initiated a fractal flocculation of the micelles and consecutively a coalescence of the micelles. This unexpected second process resembled that of spinodal demixing. The dispersion phase thus separates into a water and a protein phase on a time scale of hours. The observed phenomona contribute to the understanding of the cheese-making process.

Wide-Area Assessment of Aperiodic Small Signal Rotor Angle Stability in Real-Time

DEFF Research Database (Denmark)

Jóhannsson, Hjörtur; Nielsen, Arne Hejde; Østergaard, Jacob

2013-01-01

This paper presents the details of a new real-time stability assessment method. The method assesses a particular mechanism of stability: each generator’s capability to generate sufficient steady state electromechanical torque. The lack of sufficient steady state torque causes aperiodic increase...... of multiple operating points is derived in the paper. Finally, results from time-domain simulation of instability scenarios in the Nordic32 test system are presented and results used for testing the assessment method. The results illustrate the method’s capability to efficiently identify the location...... in rotor angle and a loss of synchronism, referred to as aperiodic small signal instability. The paper provides the theoretical background of the method and an analytical assessment criterion. Furthermore, a mathematical mapping of the generators’ operating points that enables informative visualization...

Particle size distribution models of small angle neutron scattering pattern on ferro fluids

International Nuclear Information System (INIS)

Sistin Asri Ani; Darminto; Edy Giri Rachman Putra

2009-01-01

The Fe 3 O 4 ferro fluids samples were synthesized by a co-precipitation method. The investigation of ferro fluids microstructure is known to be one of the most important problems because the presence of aggregates and their internal structure influence greatly the properties of ferro fluids. The size and the size dispersion of particle in ferro fluids were determined assuming a log normal distribution of particle radius. The scattering pattern of the measurement by small angle neutron scattering were fitted by the theoretical scattering function of two limitation models are log normal sphere distribution and fractal aggregate. Two types of particle are detected, which are presumably primary particle of 30 Armstrong in radius and secondary fractal aggregate of 200 Armstrong with polydispersity of 0.47 up to 0.53. (author)

A microstructural comparison of two nuclear-grade martensitic steels using small-angle neutron scattering

Science.gov (United States)

Coppola, R.; Fiori, F.; Little, E. A.; Magnani, M.

1997-06-01

Results are presented of a small-angle neutron scattering (SANS) study on two 10-13% Cr martensitic stainless steels of interest for nuclear applications, viz. DIN 1.4914 (MANET specification, for fusion reactors) and AISI 410. The investigation has focussed principally on microstructural effects associated with the differences in chromium content between the two alloys. The size distribution functions determined from nuclear and magnetic SANS components for the two steels given identical heat treatments are in accord with an interpretation based on the presence of ˜ 1 nm size CCr aggregates in the microstructure. Much larger (˜ 10 nm) scattering inhomogeneities with different magnetic contrast are also present and tentatively identified as carbides.

Novel tendencies in developing small-angle neutron scattering methods for studying the structure of biological macromolecules

International Nuclear Information System (INIS)

Serdyuk, I.

1995-01-01

In recent 20 years thermal neutron scattering has been acknowledged an important instrument for structural studies in molecular biology. The methods of neutron diffraction of high resolution, which are not discussed in this paper, have already permitted to obtain a detailed representation of the course of proteolytic reactions and have arisen a number of new problems connected with the localization of water molecules and the H-D exchange. The methods of low resolution widely used due to a relative simplicity of the experiment have been successfully applied for both solving structural problems per se and investigating the changes in the structure when macromolecules perform their biological functions. The most promising are novel experimental approaches: the triple isotopic substitution method and the method of spin dynamic polarization. These methods ensure solving structural problems at a higher resolution than the dimensions of the macromolecules studied. Installation of new experimental instruments makes neutron measurements more accessible, and development of direct methods for interpretation of experimental data using the apparatus of spherical harmonics opens new possibilities for small-angle neutron scattering making it a necessary element for interpretation of diffraction data of monocrystals of intricate biological macromolecules. The paper presents a brief account of the tendencies in theoretical development and practical use of small-angle scattering for studying biological macromolecules. Special attention is given to the studies carried out in the Laboratory of Neutron Physics on a unique pulse IBR-2 reactor. (author) 14 refs

Bioelectrical impedance phase angle in clinical practice: implications for prognosis in stage IIIB and IV non-small cell lung cancer

Directory of Open Access Journals (Sweden)

Grutsch James F

2009-01-01

Full Text Available Abstract Background A frequent manifestation of advanced lung cancer is malnutrition, timely identification and treatment of which can lead to improved patient outcomes. Bioelectrical impedance analysis (BIA is an easy-to-use and non-invasive technique to evaluate changes in body composition and nutritional status. We investigated the prognostic role of BIA-derived phase angle in advanced non-small cell lung cancer (NSCLC. Methods A case series of 165 stages IIIB and IV NSCLC patients treated at our center. The Kaplan Meier method was used to calculate survival. Cox proportional hazard models were constructed to evaluate the prognostic effect of phase angle, independent of stage at diagnosis and prior treatment history. Results 93 were males and 72 females. 61 had stage IIIB disease at diagnosis while 104 had stage IV. The median phase angle was 5.3 degrees (range = 2.9 – 8. Patients with phase angle 5.3 had 12.4 months (95% CI: 10.5 to 18.7; n = 84; (p = 0.02. After adjusting for age, stage at diagnosis and prior treatment history we found that every one degree increase in phase angle was associated with a relative risk of 0.79 (95% CI: 0.64 to 0.97, P = 0.02. Conclusion We found BIA-derived phase angle to be an independent prognostic indicator in patients with stage IIIB and IV NSCLC. Nutritional interventions targeted at improving phase angle could potentially lead to an improved survival in patients with advanced NSCLC.

Small-angle X-ray scattering on growth of AgCl crystallites in photochromic glasses

International Nuclear Information System (INIS)

Takatohi, U.E.; Bittencourt, D.R.S.; Watanabe, S.

1997-01-01

Reversible changes in the optical properties of photochromic glasses are observed owing to the presence of small silver halide crystals inside the glassy matrix. These crystals grow during the glass heat-treatment processing. Samples with molar composition of 40SiO 2 .10Al 2 O 3 .16.1K 2 O.33.9B 2 O 3 , doped with AgCl and CuO, were produced and submitted to different heat treatments: (i) for 0.5 h at temperatures from 753 to 893 K and (ii) at 873 K for periods of time from 0.25 to 1.25 h. Small-angle X-ray scattering (SAXS) was used to characterize the samples. The samples heat treated between 843 and 893 K presented an increasing growth rate of the Guinier radius (R g ). Samples heat treated at a fixed temperature of 873 K and different time t showed a law R g 3 = kt + c. Variations in the optical absorbance at 280 nm and the additional absorbance spectra of samples exposed to light showed correlation with the SAXS results. (orig.)

A high resolution, high counting rate bidimensional, MWPC imaging detector for small angle X-ray diffraction studies

International Nuclear Information System (INIS)

Bateman, J.E.; Connolly, J.F.; Sawyer, E.C.; Stephenson, R.

1981-07-01

The performance is reported of a 200 mm x 200 mm X-ray imaging MWPC aimed at applications in small angle X-ray diffraction and scattering. With quantum energies of approximately 8 keV high spatial resolution (+- 0.5 mm x +- 0.14 mm) with a capability for data taking at >approximately 350 kHz is reported. The detection efficiency is approximately 75% and the detector operates as a sealed unit with a long lifetime. (author)

Pepsi-SAXS : an adaptive method for rapid and accurate computation of small-angle X-ray scattering profiles

OpenAIRE

Grudinin , Sergei; Garkavenko , Maria; Kazennov , Andrei

2017-01-01

International audience; A new method called Pepsi-SAXS is presented that calculates small-angle X-ray scattering profiles from atomistic models. The method is based on the multipole expansion scheme and is significantly faster compared with other tested methods. In particular, using the Nyquist–Shannon–Kotelnikov sampling theorem, the multipole expansion order is adapted to the size of the model and the resolution of the experimental data. It is argued that by using the adaptive expansion ord...

The design and q resolution of the small and wide angle neutron scattering instrument (TAIKAN) in J-PARC

International Nuclear Information System (INIS)

Takata, Shin-ichi; Suzuki, Jun-ichi; Shinohara, Takenao; Oku, Takayuki; Tominaga, Taiki; Nakatani, Takeshi; Inamura, Yasuhiro; Suzuya, Kentaro; Aizawa, Kazuya; Arai, Masatoshi; Ohishi, Kazuki; Iwase, Hiroki; Ito, Takayoshi; Otomo, Toshiya; Sugiyama, Masaaki

2015-01-01

The small and wide angle neutron scattering instrument (TAIKAN) is designed to cover the wide q range of 0.005 0.3 Å"-"1 with the other banks. The q resolution was compared with the values experimentally obtained from the widths of Bragg peaks of a standard sample, silver behenate. The results of the experiment were consistent with the theory. It was confirmed that TAIKAN was completed as was expected. (author)

A posteriori determination of the useful data range for small-angle scattering experiments on dilute monodisperse systems.

Science.gov (United States)

Konarev, Petr V; Svergun, Dmitri I

2015-05-01

Small-angle X-ray and neutron scattering (SAXS and SANS) experiments on solutions provide rapidly decaying scattering curves, often with a poor signal-to-noise ratio, especially at higher angles. On modern instruments, the noise is partially compensated for by oversampling, thanks to the fact that the angular increment in the data is small compared with that needed to describe adequately the local behaviour and features of the scattering curve. Given a (noisy) experimental data set, an important question arises as to which part of the data still contains useful information and should be taken into account for the interpretation and model building. Here, it is demonstrated that, for monodisperse systems, the useful experimental data range is defined by the number of meaningful Shannon channels that can be determined from the data set. An algorithm to determine this number and thus the data range is developed, and it is tested on a number of simulated data sets with various noise levels and with different degrees of oversampling, corresponding to typical SAXS/SANS experiments. The method is implemented in a computer program and examples of its application to analyse the experimental data recorded under various conditions are presented. The program can be employed to discard experimental data containing no useful information in automated pipelines, in modelling procedures, and for data deposition or publication. The software is freely accessible to academic users.

Penetration route of functional molecules in stratum corneum studied by time-resolved small- and wide-angle x-ray diffraction

International Nuclear Information System (INIS)

Hatta, Ichiro; Ohta, Noboru; Yagi, Naoto; Nakazawa, Hiromitsu; Obata, Yasuko; Inoue, Katsuaki

2011-01-01

We studied effects of functional molecules on corneocytes in stratum corneum using time-resolved small- and wide-angle x-ray diffraction after applying a functional molecule. From these results it was revealed that in the stratum corneum a typical hydrophilic molecule, ethanol, penetrates via the transcellular route and on the other hand a typical hydrophobic molecule, d-limonene, penetrates via the intercellular route.

Perturbative estimates of lepton mixing angles in unified models

International Nuclear Information System (INIS)

Antusch, Stefan; King, Stephen F.; Malinsky, Michal

2009-01-01

Many unified models predict two large neutrino mixing angles, with the charged lepton mixing angles being small and quark-like, and the neutrino masses being hierarchical. Assuming this, we present simple approximate analytic formulae giving the lepton mixing angles in terms of the underlying high energy neutrino mixing angles together with small perturbations due to both charged lepton corrections and renormalisation group (RG) effects, including also the effects of third family canonical normalization (CN). We apply the perturbative formulae to the ubiquitous case of tri-bimaximal neutrino mixing at the unification scale, in order to predict the theoretical corrections to mixing angle predictions and sum rule relations, and give a general discussion of all limiting cases. We also discuss the implications for the sum rule relations of the measurement of a non-zero reactor angle, as hinted at by recent experimental measurements.

Extensive small-angle X-ray scattering studies of blood coagulation factor VIIa reveal interdomain flexibility

DEFF Research Database (Denmark)

Mosbæk, Charlotte Rode; Nolan, David; Persson, Egon

2010-01-01

Blood coagulation factor VIIa (FVIIa) is used in the treatment of replacement therapy resistant hemophilia patients, and FVIIa is normally activated upon complex formation with tissue factor (TF), potentially in context with structural rearrangements. The solution behavior of uncomplexed FVIIa...... is important for understanding the mechanism of activation and for the stability and activity of the pharmaceutical product. However, crystal structures of FVIIa in complex with TF and of truncated free FVIIa reveal different overall conformations while previous small-angle scattering studies suggest FVIIa...... causing resistance to activation, thereby emphasizing the connection between the distribution of different conformations of FVII and the mechanism of activation....

Small-angle neutron scattering studies of the template-mediated crystallization of ZSM-5 type zeolite

International Nuclear Information System (INIS)

Iton, L.E.; Brun, T.O.; Epperson, J.E.

1988-03-01

Small-angle neutron scattering is a useful new approach to the study of zeolite crystallization from aluminosilicate gels and the action of template molecules. It has been applied to gels for synthesis of zeolite ZSM-5 using tetrapropylammonium ions as templates where the scattering length densities of the gel particles and their texture were determined using contrast variation methods. Gels formulated from soluble silicate incorporate template molecules promptly into an amorphous ''embryonic'' structure and crystallization ensues via a solid hydrogel transformation mechanism. Gels formulated from colloidal silica show different scattering behavior, and a liquid phase transport mechanism is inferred. 8 refs., 4 figs., 2 tabs

Analysis of the nano-scale structure of a natural clayey soil using the small angle neutron scattering method

International Nuclear Information System (INIS)

Itakura, T.; Bertram, W.K.; Hathaway, P.V.; Knott, R.B.

2001-01-01

The small angle neutron scattering method (SANS) was used to analyze the nano-structure of a natural clayey soil used for containment of industrial liquid wastes. A Tertiary clay deposit called the Londonderry clay was used to contain the wastes in a state-run landfill facility in NSW. A number of site assessments have been carried out at the site and continual efforts have been made to characterize interactions between soil materials and contaminants at the site. Hence, it is of research and practical interest to investigate the effects of deformation on the nano-scale structure of the soil. Experiments have been conducted to analyze the structure of reconstituted clayey soil samples that were subjected to uniaxial compression ranging from 200 kPa to 800 kPa. The small angle neutron scattering instrument was used to measure the scattering intensity of these samples at a scattering vector (q) range between 0.01 and 0.1 Angstroms -1 . The sector integration technique was used to analyse elliptical scattering patterns along the major and minor axes. A relation between stress, void ratio and nano-scale structure properties was then briefly discussed for use in assessing the performance of clayey soils as in situ barriers

Small-angle X-ray-scattering investigation and structural-model study of the fatty-acid synthetase from pig liver

International Nuclear Information System (INIS)

Folkhard, W.; Felser, B.; Pilz, I.; Kratky, O.; Dutler, H.; Vogel, H.

1977-01-01

The structure of the fatty acid synthetase from pig liver was studied on models based upon structural and functional properties selected from pertinent results available from numerous investigations carried out with fatty acid synthetase from this and other sources. When comparing small-angle X-ray-scattering curves calculated with these models and curves obtained from small-angle X-ray-scattering experiments carried out with the pig-liver enzyme, we tried to select a model which would lead to an acceptable correlation between the calculated and the experimental curves and at the same time fulfil the known structural and the functional requirements. The comparison of the curves was started with a model of low complexity. The observed discrepancy, together with arguments from the structural and the functional properties, helped decide which is the next most reasonable model to be considered. This procedure was repeated for five models of increasing complexity. In the model which led to the best fit the multienzyme complex is composed of two halves in an asymmetric conformation including hollow spaces. This highly anisotropic model would imply that the two halves change their conformation each time a synthetic cycle is completed and that the growing fatty acid is handed over from one half to the other. (orig.) [de

Feasibility study of experiments to measure inclusive reactions at large x/sub F/ in ISABELLE's small-angle hall

International Nuclear Information System (INIS)

Aronson, S.; Danby, G.; Foley, K.; Paige, F.; Thorndike, A.; Engelmann, R.; McCarthy, R.; Pope, B.

1979-01-01

As a way of testing current ideas on the construction of experimental halls at ISABELLE, a particular class of experiments suggested for the small-angle (or 2 o'clock) hall are examined: p + p → p + X, and p + p → c + X, c is not = p. Somewhat more detail has been incorporated than in previous summer study and summer workshop treatments of these experiments. Briefly, the result of this examination is that inclusive single-particle experiments are feasible over a suitable kinematic range without the use of previously proposed special insertion quadrupoles. The forward single-arm spectrometer is housed in a separate tunnel of modest transverse dimension. The extraction of scattered particles (theta > approx. 1 mrad) into the spectrometer is accomplished with Lambertson septa and current sheet septa. Provision is made for overlap with the kinematic region covered by ISR and Fermilab experiments. Section II is a review of the physics objectives of such experiments. Section III describes the general layout of the apparatus, with the extraction system and the spectrometer discussed in more detail in Sections IV and V respectively. A guess at how this experiment would fit into the overall small-angle physics program is presented in Section VI

Small-angle neutron scattering and molecular dynamics structural study of gelling DNA nanostars

Energy Technology Data Exchange (ETDEWEB)

Fernandez-Castanon, J.; Bomboi, F. [Sapienza–Università di Roma, P.le A. Moro 5, 00185 Roma (Italy); Rovigatti, L. [Rudolf Peierls C.T.P., University of Oxford, 1 Keble Road, Oxford OX1 3NP (United Kingdom); Faculty of Physics, University of Vienna, Boltzmanngasse 5, A-1090 Vienna (Austria); Zanatta, M. [Dipartimento di Fisica, Università di Perugia, Via Pascoli, 06123 Perugia (Italy); CNR-ISC, UOS Sapienza–Università di Roma, I-00186 Roma (Italy); Paciaroni, A. [Dipartimento di Fisica, Università di Perugia, Via Pascoli, 06123 Perugia (Italy); Comez, L. [Dipartimento di Fisica, Università di Perugia, Via Pascoli, 06123 Perugia (Italy); IOM-CNR, UOS Perugia c/o Dipartimento di Fisica e Geologia, Università di Perugia, Via Pascoli, 06123 Perugia (Italy); Porcar, L. [Institut Laue-Langevin, 71 Avenue des Martyrs, CS 20156, 38042 Grenoble Cedex 9 (France); Jafta, C. J. [Helmholtz-Zentrum Berlin, Hahn-Meitner-Platz 1, 14109 Berlin (Germany); Fadda, G. C. [Laboratoire Léon Brillouin, LLB, CEA Saclay, 91191 Gif-sur-Yvette Cedex (France); Bellini, T. [Department of Medical Biotechnology and Translational Medicine, Università di Milano, I-20133 Milano (Italy); Sciortino, F., E-mail: francesco.sciortino@uniroma1.it [Sapienza–Università di Roma, P.le A. Moro 5, 00185 Roma (Italy); CNR-ISC, UOS Sapienza–Università di Roma, I-00186 Roma (Italy)

2016-08-28

DNA oligomers with properly designed sequences self-assemble into well defined constructs. Here, we exploit this methodology to produce bulk quantities of tetravalent DNA nanostars (each one composed of 196 nucleotides) and to explore the structural signatures of their aggregation process. We report small-angle neutron scattering experiments focused on the evaluation of both the form factor and the temperature evolution of the scattered intensity at a nanostar concentration where the system forms a tetravalent equilibrium gel. We also perform molecular dynamics simulations of one isolated tetramer to evaluate the form factor numerically, without resorting to any approximate shape. The numerical form factor is found to be in very good agreement with the experimental one. Simulations predict an essentially temperature-independent form factor, offering the possibility to extract the effective structure factor and its evolution during the equilibrium gelation.

Polyhydroxyalkanoate-based natural-synthetic hybrid copolymer films: A small-angle neutron scattering study

International Nuclear Information System (INIS)

Foster, L. John R.; Knott, Robert; Sanguanchaipaiwong, Vorapat; Holden, Peter J.

2006-01-01

Polyhydroxyalkanoates have attracted attention as biodegradable alternatives to conventional thermoplastics and as biomaterials. Through modification of their biosynthesis using Pseudomonas oleovorans, we have manipulated the material properties of these biopolyesters and produced a natural-synthetic hybrid copolymer of polyhydroxyoctanoate-block-diethylene glycol (PHO-b-DEG). A mixture of PHO and PHO-DEG were solvent cast from analytical grade chloroform and analysed using small-angle neutron scattering. A scattering pattern, easily distinguished above the background, was displayed by the films with a diffraction ring at q∼0.12 A -1 . This narrow ring of intensity is suggestive of a highly ordered system. Analysis of the diffraction pattern supported this concept and showed a d-spacing of approximately 50 A. In addition, conformation of the hybrid polymer chains can be manipulated to support their self-assembly into ordered microporous films

Proteins on surfaces investigated by microbeam grazing incidence small angle X-ray scattering

Energy Technology Data Exchange (ETDEWEB)

Gebhardt, Ronald; Riekel, Christian; Burghammer, Manfred [European Synchrotron Radiation Facility, B.P. 220, F-38043 Grenoble Cedex (France); Vendrely, Charlotte [Universite de Cergy-Pontoise, ERRMECE, F-95000, Cergy-Pontoise (France); Mueller-Buschbaum, Peter [TU Muenchen, Physik Department E13, Muenchen (Germany)

2009-07-01

Grazing incidence small angle scattering with a 1 micron x-ray beam ({mu}GISAXS) is applied to study structural ordering of casein micelles and fibroin in solution cast films. {mu}GISAXS scans provide the possibility to locate highly ordered areas and to investigate variation in the molecular packing. In the case of the casein micelles, ordered film structures have been generated by decreasing their natural size dispersion. While dynamic light scattering was used to characterize the different size fractions in solution, {mu}GISAXS and roughness are measured on the resulting casein films. GISAXS-Patterns are analyzed by simulations providing the dimension and nearest neighbor distances of casein micelles. In the case of fibroin, ordering of nano-fibers formed during the drying process is investigated. The experimental data are analyzed by simulations and compared to SEM, AFM and Raman scattering experiments.

Measuring module of spectrometer of neutron small angle scattering on the IBR pulse reactor

International Nuclear Information System (INIS)

Vagov, V.A.; Zhukov, G.P.; Kozlova, E.P.; Korobchenko, M.L.; Namsraj, Yu.; Ostanevich, Yu.M.; Savvateev, A.S.; Salamatin, I.M.; Sirotin, A.P.

1980-01-01

Equipment and software for experiments with neutron small angle scattering is described. It is intended for data acquisition, equipment control storage of collected data and their output to network of the Laboratory measuring centre. The set-up equipment includes: 9 neutron detectors with corresponding electronic apparatus, sample exchanging device, communication link, SM-3 type minicomputer of an extended configuration and some units of CAMAC electronic equipment. The software (MUR applied operatio system) is intended for the automatic performance of the given number of cycles of successive uniform runs of a given duration with the sample list at two possible filter positions. Besides, the MUR system contains test, debugging and service software. The software has been designed using the SANPO system means [ru

Identifying low and high density amorphous phases during zeolite amorphisation using small and wide angle X-ray scattering

International Nuclear Information System (INIS)

Meneau, F.; Greaves, G.N.

2005-01-01

In situ experiments following the thermal amorphisation of zeolites reveal massive increases in small angle X-ray scattering (SAXS), persisting well beyond the stage where wide angle X-ray scattering (WAXS) can detect that any crystalline phase is present. This heterogeneity in the amorphised phase is attributed to the transition from a low density amorphous phase (LDA) to a high density amorphous phase (HDA) at the glass transition. The fractions of zeolite, LDA and HDA phases obtained from SAXS analysis are discussed in the context of non-linear changes detected in 29 Si solid state NMR during zeolite amorphisation. Whilst the HDA phase is chemically disordered, the LDA phase exhibits much of the Al-Si ordering present in the starting zeolite. These findings are considered in the context of perfect glasses predicted to occur when super strong liquids are supercooled

The investigation of Fe-Mn-based alloys with shape memory effect by small-angle scattering of polarized neutrons

International Nuclear Information System (INIS)

Kopitsa, G.P.; Runov, V.V.; Grigoriev, S.V.; Bliznuk, V.V.; Gavriljuk, V.G.; Glavatska, N.I.

2003-01-01

The small-angle polarized neutron scattering (SAPNS) technique has been used to study a nuclear and magnetic homogeneity in the distribution of both substituent (Si, Cr, Ni) and interstitial (C, N) alloying elements on the mesoscopic range in Fe-Mn-based alloys with shape memory effect (SME). The four groups of alloys with various basic compositions: FeMn 18 (wt%), FeMn 20 Si 6 , FeMn 20 Cr 9 N 0.2 and FeMn 17 Cr 9 Ni 4 Si 6 were investigated. It was found that the small-angle scattering of neutrons and depolarization on these alloys are very small altogether. The scattering did not exceed 1.5% from the incident beam and depolarization ∼2% for all samples. It means that these alloys are well nuclear and magnetically homogeneous on the scale of 10-1000 A. However, the difference in the homogeneity depending on the compositions still takes place. Thus, the adding of Si in FeMn 18 and FeMn 20 Cr 9 N 0.2 alloys improves the homogeneity pronouncedly. At once, the effect of the doping by C or N atoms on the homogeneity in FeMn 20 Si 6 and FeMn 17 Cr 9 Ni 4 Si 6 alloys is multivalued and depend on the presence of substitutional atoms (Ni and Cr). The capability of SAPNS as a method for the study of mesoscopic homogeneity in materials with SME and testing of the quality of their preparation is discussed

Determination of the unilamellar dimyristoylphosphatidylcholine vesicle structure from the small-angle scattering data in the framework of a model of separated form-factors

International Nuclear Information System (INIS)

Zemlyanaya, E.V.; Kiselev, M.A.

2002-01-01

On the basis of the model of separated form-factors, a code for fitting of small-angle neutron scattering spectra of the polydispersed vesicle population has been developed with corrections to the resolution function of the YuMO spectrometer. Vesicle and membrane bilayer parameters have been analyzed for various hierarchical models of the neutron scattering length density across the membrane. It was shown that hydration of vesicle can be described by the linear distribution function of water molecules. For the first time from the small-angle experiment, without additional methods, the average radius and polydispersity of the vesicle population, thickness of the membrane bilayer, thickness of hydrophobic and hydrophilic parts of bilayer, water distribution function and number of water molecules in the hydrophilic part have been calculated. (author)

Impact parameter representation without high-energy, small-angle limitation

International Nuclear Information System (INIS)

Islam, M.M.

Using Watson-Sommerfeld transform the impact parameter representation of the scattering amplitude is shown to be valid for all physical energies and scattering angles. It is also shown how the direct channel Regge poles enter in the impact parameter amplitude [fr

Combined in situ small and wide angle X-ray scattering studies of TiO2 nano-particle annealing to 1023 K

DEFF Research Database (Denmark)

Kehres, Jan; Andreasen, Jens Wenzel; Krebs, Frederik C

2010-01-01

Combined in situ small- and wide-angle X-ray scattering (SAXS/WAXS) studies were performed in a recently developed laboratory setup to investigate the dynamical properties of dry oleic acid-capped titanium dioxide nanorods during annealing in an inert gas stream in a temperature interval of 298-1...

Quantification of RNA in bacteriophage MS2-like viruses in solution by small-angle X-ray scattering

International Nuclear Information System (INIS)

Kuzmanovic, Deborah A.; Elashvili, Ilya; Wick, Charles; O'Connell, Catherine; Krueger, Susan

2006-01-01

Recombinant forms of bacteriophage MS2 virus particles, wild-type MS2 and MS2 capsids have been examined in solution using small-angle X-ray scattering (SAXS). SAXS was used to determine the overall size of the virus particles and to quantify the amount of encapsulated viral RNA. These studies show that analysis of natural and recombinant forms of MS2 virus by SAXS can be used as both a quantitative measure of nucleic acid content in situ and diagnostic indicator of sample integrity

Angles in hyperbolic lattices

DEFF Research Database (Denmark)

Risager, Morten S.; Södergren, Carl Anders

2017-01-01

It is well known that the angles in a lattice acting on hyperbolic n -space become equidistributed. In this paper we determine a formula for the pair correlation density for angles in such hyperbolic lattices. Using this formula we determine, among other things, the asymptotic behavior of the den......It is well known that the angles in a lattice acting on hyperbolic n -space become equidistributed. In this paper we determine a formula for the pair correlation density for angles in such hyperbolic lattices. Using this formula we determine, among other things, the asymptotic behavior...... of the density function in both the small and large variable limits. This extends earlier results by Boca, Pasol, Popa and Zaharescu and Kelmer and Kontorovich in dimension 2 to general dimension n . Our proofs use the decay of matrix coefficients together with a number of careful estimates, and lead...

Small-angle physics at the intersecting storage rings forty years later

International Nuclear Information System (INIS)

Amaldi, Ugo

2012-01-01

It is often said that the ISR did not have the detectors needed to discover fundamental phenomena made accessible by its large and new energy range. This is certainly true for ‘high-momentum-transfer physics’, which, since the end of the 1960s, became a main focus of research, but the statement does not apply to the field that is the subject of this paper. In fact, looking back to the results obtained at the ISR by the experiments that were programmed to study ‘small-angle physics’, one can safely say that the detectors were very well suited to the tasks and performed much better than foreseen. As far as the results are concerned, in this particular corner of hadron–hadron physics, new phenomena were discovered, unexpected scaling laws were found and the first detailed studies of that elusive concept, which goes under the name ‘pomeron’, were performed, opening the way to phenomena that we hope will be observed at the LHC. Moreover, some techniques and methods have had a lasting influence: all colliders had and have their Roman pots, and the different methods developed at the ISR for measuring the luminosity are still in use.

Neutron small-angle scattering study of phase decomposition in Au-Pt

International Nuclear Information System (INIS)

Singhal, S.P.; Herman, H.

1978-01-01

Isothermal decomposition of a Au-60 at.% Pt alloy, quenched from the solid as well as the liquid state, has been studied with the D11 neutron small-angle scattering spectrometer at ILL, Grenoble. An incident neutron wavelength of 6.7 A was used and measurements were carried out in the range of scattering vector [β=4π sin theta/lambda] from 2.8x10 -2 to 21x10 -2 A -1 . The preliminary results indicate that decomposition of this alloy at 550 0 C takes place by a spinodal mode, although deviations were observed from linear spinodal theory, even at very early times. Slower aging kinetics were observed in liquid-quenched alloy as compared with solid-quenched. Liquid quenching is more efficient in suppressing quench clustering than is solid quenching. However, liquid quenching yields an extremely fine-grained material, which thereby enhances discontinuous precipitation at grain boundaries, competing with decomposition in the bulk. A Rundman-Hilliard analysis was used for the early stages of the spinodal reaction to obtain an interdiffusion coefficient of the order of 10 -16 cm 2 s -1 at 550 0 C for the solid-quenched alloy. (Auth.)

Small-angle X-ray scattering on growth of AgCl crystallites in photochromic glasses

Energy Technology Data Exchange (ETDEWEB)

Takatohi, U.E. [Inst. Adventista de Ensino, Sao Paulo (Brazil); Bittencourt, D.R.S.; Watanabe, S.

1997-10-01

Reversible changes in the optical properties of photochromic glasses are observed owing to the presence of small silver halide crystals inside the glassy matrix. These crystals grow during the glass heat-treatment processing. Samples with molar composition of 40SiO{sub 2}.10Al{sub 2}O{sub 3}.16.1K{sub 2}O.33.9B{sub 2}O{sub 3}, doped with AgCl and CuO, were produced and submitted to different heat treatments: (i) for 0.5 h at temperatures from 753 to 893 K and (ii) at 873 K for periods of time from 0.25 to 1.25 h. Small-angle X-ray scattering (SAXS) was used to characterize the samples. The samples heat treated between 843 and 893 K presented an increasing growth rate of the Guinier radius (R{sub g}). Samples heat treated at a fixed temperature of 873 K and different time t showed a law R{sub g}{sup 3} = kt + c. Variations in the optical absorbance at 280 nm and the additional absorbance spectra of samples exposed to light showed correlation with the SAXS results. (orig.). 16 refs.

Characterization of Nano Sized Microstructures in Fe and Ni Base ODS Alloys Using Small Angle Neutron Scattering

International Nuclear Information System (INIS)

Han, Young-Soo; Jang, Jin-Sung; Mao, Xiaodong

2015-01-01

Ferritic ODS(Oxide-dispersion-strengthened) alloy is known as a primary candidate material of the cladding tubes of a sodium fast reactor (SFR) in the Generation IV research program. In ODS alloy, the major contribution to the enhanced high-temperature mechanical property comes from the existence of nano-sized oxide precipitates, which act as obstacles to the movement of dislocations. In addition for the extremely high temperature application(>950 .deg. C) of future nuclear system, Ni base ODS alloys are considered as candidate materials. Therefore the characterization of nano-sized microstructures is important for determining the mechanical properties of the material. Small angle neutron scattering (SANS) technique non-destructively probes structures in materials at the nano-meter length of scale (1 - 1000 nm) and has been a very powerful tool in a variety of scientific/engineering research areas. In this study, nano-sized microstructures were quantitatively analyzed by small angle neutron scattering. Quantitative microstructural information on nanosized oxide in ODS alloys was obtained from SANS data. The effects of the thermo mechanical treatment on the size and volume fraction of nano-sized oxides were analyzed. For 12Cr ODS alloy, the experimental A-ratio is two-times larger than the theoretical A-ratio., and this result is considered to be due to the imperfections included in YTaO 4 . For Ni base ODS alloy, the volume fraction of the mid-sized particles (- 30 nm) increases rapidly as hot extrusion temperature decreases

Cosmic ray zenith angle distribution at low geomagnetic latitude

Energy Technology Data Exchange (ETDEWEB)

Aragon, G [Instituto de Astronomia y Fisica del Espacio, Buenos Aires, Argentina; Gagliardini, A; Ghielmetti, H S

1977-12-01

The intensity of secondary charged cosmic rays at different zenith angles was measured by narrow angle Geiger-Mueller telescopes up to an atmospheric depth of 2 g cm/sup -2/. The angular distribution observed at high altitudes is nearly flat at small angles around the vertical and suggests that the particle intensity peaks at large zenith angles, close to the horizon.

Influence of multiple well defined conformations on small-angle scattering of proteins in solution.

Science.gov (United States)

Heller, William T

2005-01-01

A common structural motif for many proteins comprises rigid domains connected by a flexible hinge or linker. The flexibility afforded by these domains is important for proper function and such proteins may be able to adopt more than one conformation in solution under equilibrium conditions. Small-angle scattering of proteins in solution samples all conformations that exist in the sampled volume during the time of the measurement, providing an ensemble-averaged intensity. In this paper, the influence of sampling an ensemble of well defined protein structures on the small-angle solution scattering intensity profile is examined through common analysis methods. Two tests were performed using simulated data: one with the extended and collapsed states of the bilobal calcium-binding protein calmodulin and the second with the catalytic subunit of protein kinase A, which has two globular domains connected by a glycine hinge. In addition to analyzing the simulated data for the radii of gyration Rg, distance distribution function P(r) and particle volume, shape restoration was applied to the simulated data. Rg and P(r) of the ensemble profiles could be easily mistaken for a single intermediate state. The particle volumes and models of the ensemble intensity profiles show that some indication of multiple conformations exists in the case of calmodulin, which manifests an enlarged volume and shapes that are clear superpositions of the conformations used. The effect on the structural parameters and models is much more subtle in the case of the catalytic subunit of protein kinase A. Examples of how noise influences the data and analyses are also presented. These examples demonstrate the loss of the indications of multiple conformations in cases where even broad distributions of structures exist. While the tests using calmodulin show that the ensemble states remain discernible from the other ensembles tested or a single partially collapsed state, the tests performed using the

Magnetic phase diagram of MnSi near critical temperature studied by neutron small angle scattering

International Nuclear Information System (INIS)

Ishikawa, Yoshikazu; Arai, Masatoshi

1984-01-01

The magnetic phase diagram of MnSi near the critical temperature T sub(N)=29.5K has been studied by neutron small angle scattering at KENS. It has been found that the anomalous new phase predicted by various methods to exist around at 28 K and 2 kOe is the paramagnetic phase where the magnetic correlations exhibit the same characteristics as those found at 29.5 K and zero magnetic field. This phenomenon, together with the sharp decrease of the magnetic phase boundary at T sub(N) and the substantial increase of the satellite Q vector at this temperature, has been found not to be interpreted by the current theories. (author)

Structure of magnetic particles studied by small angle neutron scattering. [Magnetic colloid particles in stable liquid dispersion

Energy Technology Data Exchange (ETDEWEB)

Cebula, D J; Charles, S W; Popplewell, J

1981-03-01

The purpose of this note is to show how the use of small angle neutron scattering (SANS) can provide fundamental information on the structure of magnetic colloid particles in stable liquid dispersion. A more detailed account elaborating the use of the technique to provide fundamental information on interactions will appear later. This contribution contains some principal results on particle structure. The technique of SANS provides a very sensitive means of measuring particle size by measuring the scattered neutron intensity, I(Q), as a function of scattered wave vector, Q.

Magnetization reversal of a Nd-Cu-infiltrated Nd-Fe-B nanocrystalline magnet observed with small-angle neutron scattering

Energy Technology Data Exchange (ETDEWEB)

Saito, Kotaro, E-mail: kotaro.saito@kek.jp; Ono, Kanta [Institute of Materials Structure Science, High Energy Accelerator Research Organization, 1-1 Oho, 305-0803 Tsukuba (Japan); Ueno, Tetsuro [Elements Strategy Initiative Center for Magnetic Materials, National Institute for Materials Science, 1-2-1 Sengen, 305-0047 Tsukuba (Japan); Yano, Masao; Shoji, Tetsuya; Sakuma, Noritsugu; Manabe, Akira; Kato, Akira [Toyota Motor Corporation, Toyota, Aichi 471-8571 (Japan); Harada, Masashi [Toyota Central R and D Labs, Inc., Aichi 480-1192 (Japan); Keiderling, Uwe [Helmholtz-Zentrum Berlin für Materialien and Energie, 14109 Berlin (Germany)

2015-05-07

The magnetization reversal process of Nd-Fe-B nanocrystalline magnets infiltrated with Nd-Cu alloy was examined using small-angle neutron scattering (SANS). The magnetic-field dependence of SANS intensity revealed a qualitative difference between Nd-Cu-infiltrated samples and as-deformed samples. Insufficient magnetic isolation along the direction perpendicular to the nominal c-axis is expected from comparable SANS intensities for different ranges of q values along this direction. For small q values near the coercivity field, Nd-Cu-infiltrated samples show a noticeable reduction in SANS intensity along the nominal c-axis, which is parallel to the external magnetic field. This indicates less spatial fluctuation of magnetic moments in Nd-Cu-infiltrated samples, owing to magnetically isolated Nd{sub 2}Fe{sub 14}B grains.

Magnetization reversal of a Nd-Cu-infiltrated Nd-Fe-B nanocrystalline magnet observed with small-angle neutron scattering

International Nuclear Information System (INIS)

Saito, Kotaro; Ono, Kanta; Ueno, Tetsuro; Yano, Masao; Shoji, Tetsuya; Sakuma, Noritsugu; Manabe, Akira; Kato, Akira; Harada, Masashi; Keiderling, Uwe

2015-01-01

The magnetization reversal process of Nd-Fe-B nanocrystalline magnets infiltrated with Nd-Cu alloy was examined using small-angle neutron scattering (SANS). The magnetic-field dependence of SANS intensity revealed a qualitative difference between Nd-Cu-infiltrated samples and as-deformed samples. Insufficient magnetic isolation along the direction perpendicular to the nominal c-axis is expected from comparable SANS intensities for different ranges of q values along this direction. For small q values near the coercivity field, Nd-Cu-infiltrated samples show a noticeable reduction in SANS intensity along the nominal c-axis, which is parallel to the external magnetic field. This indicates less spatial fluctuation of magnetic moments in Nd-Cu-infiltrated samples, owing to magnetically isolated Nd 2 Fe 14 B grains

Foucault imaging and small-angle electron diffraction in controlled external magnetic fields.

Science.gov (United States)

Nakajima, Hiroshi; Kotani, Atsuhiro; Harada, Ken; Ishii, Yui; Mori, Shigeo

2016-12-01

We report a method for acquiring Foucault images and small-angle electron diffraction patterns in external magnetic fields using a conventional transmission electron microscope without any modification. In the electron optical system that we have constructed, external magnetic fields parallel to the optical axis can be controlled using the objective lens pole piece under weak excitation conditions in the Foucault mode and the diffraction mode. We observe two ferromagnetic perovskite-type manganese oxides, La 0.7 Sr 0.3 MnO 3 (LSMO) and Nd 0.5 Sr 0.5 MnO 3 , in order to visualize magnetic domains and their magnetic responses to external magnetic fields. In rhombohedral-structured LSMO, pinning of magnetic domain walls at crystallographic twin boundaries was found to have a strong influence on the generation of new magnetic domains in external applied magnetic fields. © The Author 2016. Published by Oxford University Press on behalf of The Japanese Society of Microscopy. All rights reserved. For permissions, please e-mail: journals.permissions@oup.com.

A new small-angle neutron scattering spectrometer at China Mianyang research reactor

Energy Technology Data Exchange (ETDEWEB)

Peng, Mei, E-mail: pm740509@163.com; Sun, Liangwei; Chen, Liang; Sun, Guangai; Chen, Bo; Xie, Chaomei; Xia, Qingzhong; Yan, Guanyun; Tian, Qiang; Huang, Chaoqiang; Pang, Beibei; Zhang, Ying; Wang, Yun; Liu, Yaoguang; Kang, Wu; Gong, Jian

2016-02-21

A new pinhole small-angle neutron scattering (SANS) spectrometer, installed at the cold neutron source of the 20 MW China Mianyang Research Reactor (CMRR) in the Institute of Nuclear Physics and Chemistry, China Academy of Engineering Physics, has been put into use since 2014. The spectrometer is equipped with a multi-blade mechanical velocity selector, a multi-beam collimation system, and a two-dimensional He-3 position sensitive neutron detector. The q-range of the spectrometer covers from 0.01 nm{sup −1} to 5.0 nm{sup −1}. In this paper, the design and characteristics of the SANS spectrometer are described. The q-resolution calculations, together with calibration measurements of silver behenate and a dispersion of nearly monodisperse poly-methyl-methacrylate nanoparticles indicate that our SANS spectrometer has a good performance and is now in routine service. - Highlights: • A new SANS spectrometer has been put into use since 2014 in China. • One MBR selector possesses a higher resolution compared with traditional selector is used. • The spectrometer has a good performance and is now in routinely service.

Study on porosity of ceramic SiC using small angle neutron scattering

International Nuclear Information System (INIS)

Li Jizhou; Yang Jilian; Kang Jian; Ye Chuntang

1996-01-01

The mechanical properties of functional heat-resistant ceramics SiC are significantly influenced by the concentration and dimensions of pores. Small angle neutron scattering measurements for 3 SiC samples with different densities are performed on C1-2 SANS instrument of the University of Tokyo. Two groups of the neutron data are obtained using 8 and 16 m of secondary flight path, 1 and 0.7 nm of neutron wave lengths, respectively. After deduction of background measurement and transmission correction, both neutron data are linked up with each other. The patterns of neutron data of 3 samples with Q range from 0.028∼0.5 nm -1 are almost with axial symmetry, showing that the shape of pores is almost spherical. Using Mellin transform, size distributions of pores in 3 samples are obtained. The average size (∼19 nm) of pores for hot-pressed SiC sample with higher density is smaller than the others (∼ 21 nm). It seems to be the reason why the density of hot-pressed SiC sample is higher than not hot-pressed sample

Formation process of hierarchical structures in crystalline polymers as analyzed by simultaneous measurements of small-angle X-ray scattering and other techniques

International Nuclear Information System (INIS)

Yamamoto, Katsuhiro; Sakurai, Shinichi

2006-01-01

Crystalline polymers spontaneously form hierarchical structures, which provide us a potential use as a specialty material. Recently, not only a crystalline homopolymer but also semi-crystalline block copolymers and crystalline polymer blends have been attracting interests for the study of a hierarchical structure. In order to analyze such hierarchical structures in a variety of length scales, a simultaneous measurement of small-(SAXS) and wide-angle (WAXS) X-ray scattering with differential scanning calorimetry (DSC), or with small-angle light scattering (Hv-SALS) are most suitable. In this review, we show some examples of the simultaneous measurements. With DSC, exothermic heat flow can be simultaneously measured with X-ray scattering. On the other hand, with Hv-SALS it is possible to analyze evolution of a spherulitic structure, which is the structure at the highest rank in the hierarchy. For both cases, one can realize that it is impossible to obtain good statistics for SAXS and WAXS measurements without synchrotron radiations. (author)

Small angle X-ray scattering study on the conformation of polystyrene in the anti-solvent process of supercritical fluids

International Nuclear Information System (INIS)

Liu Yi; Wang Hongli; Zhao Xin; Chen Na; Li Dan; Liu Zhimin; Han Buxing; Rong Lixia; Zhao Hui; Wang Jun; Dong Baozhong

2003-01-01

The conformation of polystyrene in the anti-solvent process of supercritical fluids (compressed CO 2 + polystyrene + tetrahydrofuran) is studied by synchrotron radiation X-ray small angle scattering (SAXS). Coil-to-globule transform of polystyrene chain is observed with increasing the concentration of CO 2 . It is found that polystyrene coils at the pressure lower than cloud point pressure (p c ) and changes into globule with uniform density at the pressure higher than p c

Modelling the detachment dependence on strike point location in the small angle slot divertor (SAS) with SOLPS

Science.gov (United States)

Casali, Livia; Covele, Brent; Guo, Houyang

2017-10-01

The new Small Angle Slot (SAS) divertor in DIII-D is characterized by a shallow-angle target enclosed by a slot structure about the strike point (SP). SOLPS modelling results of SAS have demonstrated divertor closure's utility in widening the range of acceptable densities for adequate heat handling. An extensive database of runs has been built to study the detachment dependence on SP location in SAS. Density scans show that lower Te at lower upstream density occur when the SP is at the critical location in the slot. The cooling front spreads across the entire target at higher densities, in agreement with experimental Langmuir probe measurements. A localized increase of the atomic and molecular density takes place near the SP, which reduces the target incident power density and facilitates detachment at lower upstream density. Systematic scans of variables such as power, transport, and viscosity have been carried out to assess the detachment sensitivity. Therein, a positive role of the viscosity is found. This work supported by DOE Contract Number DE-FC02-04ER54698.

Compact structure of ribosomal protein S4 in solution as revealed by small-angle X-ray scattering

International Nuclear Information System (INIS)

Serdyuk, I.N.; Sarkisyan, M.A.; Gogia, Z.V.

1981-01-01

The authors report the results of a small-angle X-ray scattering study of ribosomal protein preparations obtained by neutron scattering method. The theoretical resolution of the diffractometer (Kratky camera, the entrance slit 80 μm, the receiving slit 190 μm, the sample-detector distance 20.4 cm) was the same as the resolution of X-ray diffractometers, on which high rsub(g) values for ribosomal proteins were obtained. They used protein S4 adjusted to 20 mg/ml without any essential loss of solubility. The scattering indicatrix obtained in a wide range of angles has demonstrated that the X-ray rsub(g) obtained here coincides with the earlier obtained neutron rsub(g) and the outer part of the scattering curve is similar to that of slightly elongated compact bodies. They conclude that all discrepancies between their data on the study of ribosomal protein structure in solution and other data are not connected with the characteristics of the instruments used but only with the quality of the protein preparations. (Auth.)

Morphological and structural characterization of PHBV/organoclay nanocomposites by small angle X-ray scattering

Energy Technology Data Exchange (ETDEWEB)

Carli, Larissa N., E-mail: lncarli@ucs.br [Instituto de Quimica, Universidade Federal do Rio Grande do Sul, Av. Bento Goncalves, 9500, Porto Alegre, 91501-970, RS (Brazil); Centro de Ciencias Exatas e Tecnologia, Universidade de Caxias do Sul, Rua Francisco Getulio Vargas, 1130, Caxias do Sul, 95070-560, RS (Brazil); Bianchi, Otavio, E-mail: obianchi@ucs.br [Centro de Ciencias Exatas e Tecnologia, Universidade de Caxias do Sul, Rua Francisco Getulio Vargas, 1130, Caxias do Sul, 95070-560, RS (Brazil); Machado, Giovanna, E-mail: giovannamachado@uol.com.br [Centro de Tecnologias Estrategicas do Nordeste, Av. Prof. Luiz Freire, 01, Cidade Universitaria, Recife, 50740-540, PE (Brazil); Programa de Pos-Graduacao de Materiais, Universidade Federal de Pernambuco, Av. Prof. Moraes Rego, 1235, Recife, 50670-901, PE (Brazil); Crespo, Janaina S., E-mail: jscrespo@ucs.br [Centro de Ciencias Exatas e Tecnologia, Universidade de Caxias do Sul, Rua Francisco Getulio Vargas, 1130, Caxias do Sul, 95070-560, RS (Brazil); Mauler, Raquel S., E-mail: raquel.mauler@ufrgs.br [Instituto de Quimica, Universidade Federal do Rio Grande do Sul, Av. Bento Goncalves, 9500, Porto Alegre, 91501-970, RS (Brazil)

2013-03-01

In this work, the morphological and structural behaviors of poly(hydroxybutyrate-co-hydroxyvalerate) (PHBV) nanocomposites were investigated using small angle X-ray scattering (SAXS), wide angle X-ray diffraction (WAXD) and transmission electron microscopy (TEM). The nanocomposites with 1, 3 and 5 wt.% of organically modified montmorillonite Cloisite Registered-Sign 30B (OMMT) were prepared by melt processing in a twin screw extruder using two different processing conditions (low and high shear intensity). The lamellar long period of the polymer was lower for the nanocomposites, with high polydispersity values. However, the crystalline thickness increased with the clay content and was independent of the processing conditions. This behavior resulted in a high linear crystallinity of the nanocomposites with 3 and 5 wt.% OMMT. The disruption factor ({beta}) was in agreement with the WAXD and TEM findings, indicating a good dispersion of the nanoparticles in the PHBV matrix with 3 wt.% of OMMT during the high shear intensity of melt processing. Highlights: Black-Right-Pointing-Pointer SAXS was used for morphological and crystalline studies of PHBV/OMMT nanocomposites. Black-Right-Pointing-Pointer The crystalline structure was influenced by the presence of clay. Black-Right-Pointing-Pointer The degree of clay dispersion in a polymer matrix was quantified. Black-Right-Pointing-Pointer The morphology comprised exfoliated particles, nanoscale and microscale clusters. Black-Right-Pointing-Pointer The results obtained by SAXS agreed well with TEM and WAXD results.

X-ray small-angle scattering of polytetrahydrofuran solution, 3

International Nuclear Information System (INIS)

Izumi, Yoshinobu; Fuji, Masayuki; Shinbo, Kazuyuki; Miyake, Yasuhiro

1975-01-01

In a previous report, the conformation of polytetrahydrofuran (PTHF) in isopropyl alcohol as a theta solvent and in n-butyl alcohol as an intermediate solvent was examined by the small angle scattering of X-ray. As the result, the experimental scattering curve at theta temperature was explained well with the calculated curve obtained by superposing, while it was impossible to apply the similar method to the analysis of the scattering curve in the intermediate solvent. Recently, as the results of the calculation by Koyama on the angular distribution of light intensity scattered by stiff chain polymers and of the studies by Edwards and de Gennes on the asymptotic behavior of scattering curves in good solvents, the direct comparison of experimental and calculated scattering curves became possible. In this report, the comparison of the scattering curves of PTHF-alcohol systems is described. The systems employed were PTHF-n-propyl alcohol, PTHF-isobutyl alcohol, PTHF-sec-butyl alcohol, and PTHF-tert-butyl alcohol in addition to the previous two systems. The Guinier plots of the cross section factors of the PTHF-alcohol systems showed that the Guinier approximation on cross sections was not satisfied in cases of PTHF-isobutyl alcohol and PTHF-sec-butyl alcohol. The light scattering data at 44.6 0 C, the theta temperature of PTHF-isopropyl alcohol, are given. From the figures comparing experimental and calculated scattering curves, it was shown that there was appreciable solvent effect on the scattering curves of PTHF-alcohol systems. The relation predicted by Edwards and de Gennes was satisfied well in case of the systems in good solvents. (Kako, I.)

On Small-Angle Neutron Scattering from Microemulsion Droplets the Role of Shape Fluctuations

CERN Document Server

Lisy, V

2001-01-01

The form factor and intensity of static neutron scattering from microemulsion droplets are calculated. The droplet is modeled by a double-layered sphere consisting of a fluid core and a thin surfactant layer, immersed in another fluid. All the three components are incompressible and characterized by different scattering length densities. As distinct from previous descriptions of small-angle neutron scattering (SANS), we consistently take into account thermal fluctuations of the droplet shape, to the second order of the fluctuations of the droplet radius. The properties of the layer are described within Helfrich's concept of the elasticity of curved interfaces. It is shown that in many cases the account for the fluctuations is essential for the interpretation of SANS. Information about two elastic constants \\kappa and \\bar\\kappa (so far extracted from the experiments in the combination 2\\kappa+\\bar\\kappa) can be now simultaneously obtained from SANS for system in conditions of two-phase coexistence. As an illu...

Frozen concentration fluctuations in a poly(N-isopropyl acrylamide) gel studied by neutron spin echo and small-angle neutron scattering

CERN Document Server

Koizumi, S; Richter, D; Schwahn, D; Faragó, B; Annaka, M

2002-01-01

By employing neutron spin echo and small-angle neutron scattering, we determined the structure factor of the frozen concentration fluctuations on nano-length scales in a swollen poly(N-isopropyl acrylamide) gel. The frozen contribution, showing a plateau at the low scattering wavenumber q (0.02 A sup - sup 1), is intimately related to the abnormal butterfly scattering pattern appearing at low q under deformation. (orig.)

Structural characterization of the phospholipid stabilizer layer at the solid-liquid interface of dispersed triglyceride nanocrystals with small-angle x-ray and neutron scattering

Science.gov (United States)

Schmiele, Martin; Schindler, Torben; Unruh, Tobias; Busch, Sebastian; Morhenn, Humphrey; Westermann, Martin; Steiniger, Frank; Radulescu, Aurel; Lindner, Peter; Schweins, Ralf; Boesecke, Peter

2013-06-01

Dispersions of crystalline nanoparticles with at least one sufficiently large unit cell dimension can give rise to Bragg reflections in the small-angle scattering range. If the nanocrystals possess only a small number of unit cells along these particular crystallographic directions, the corresponding Bragg reflections will be broadened. In a previous study of phospholipid stabilized dispersions of β-tripalmitin platelets [Unruh, J. Appl. Crystallogr.JACGAR0021-889810.1107/S0021889807044378 40, 1008 (2007)], the x-ray powder pattern simulation analysis (XPPSA) was developed. The XPPSA method facilitates the interpretation of the rather complicated small-angle x-ray scattering (SAXS) curves of such dispersions of nanocrystals. The XPPSA method yields the distribution function of the platelet thicknesses and facilitates a structural characterization of the phospholipid stabilizer layer at the solid-liquid interface between the nanocrystals and the dispersion medium from the shape of the broadened 001 Bragg reflection. In this contribution an improved and extended version of the XPPSA method is presented. The SAXS and small-angle neutron scattering patterns of dilute phospholipid stabilized tripalmitin dispersions can be reproduced on the basis of a consistent simulation model for the particles and their phospholipid stabilizer layer on an absolute scale. The results indicate a surprisingly flat arrangement of the phospholipid molecules in the stabilizer layer with a total thickness of only 12 Å. The stabilizer layer can be modeled by an inner shell for the fatty acid chains and an outer shell including the head groups and additional water. The experiments support a dense packing of the phospholipid molecules on the nanocrystal surfaces rather than isolated phospholipid domains.

Development and performance test of small angle neutron spectrometer at HANARO

International Nuclear Information System (INIS)

Han, Young Soo; Seong, Baek Seok; Lee, Chang Hee; Lee, Jeong Soo; Hong, Kwang Pyo; Choi, Byung Hoon; Choi, Young Hyun; Shin, Eun Joo; Park, Kook Nam

2004-12-01

The construction of Small Angle Neutron Spectrometer(SANS) at the CN beam port in HANARO was completed and has been opened to users in July 2001. the 2-D PSD (two dimensional position sensitive detector), the NVS (neutron velocity selector), the detector chamber rotation system, the detector horizontal moving system, the stepping motors, the beam shutter and the attenuator were fully tested and installed. The performance test of all the components was also completed. Wavelengths and resolutions of the neutron beam monochromatized by the NVS were calibrated using both the time-of-flight method and the diffraction measurement on standard material, the silver behenate. The relationship between the selector speed U[rpm] and the neutron wavelength λ[A] was obtained as λ[A]=0.11077+107171/U[rpm]. The controllers for the sample environments, the beam shutter and the stepping motors were constructed and its control programs for those controllers were also developed. The Beam test for the SANS has been finished and the characteristics of neutron beam was analyzed. The experimental methods of SANS and its data treatment method were established. The performance test of the HANARO SANS compared with that of foreign SANS's. shows that the HANARO SANS is quite well comparable with foreign SANS facilities

Gracing incidence small angle neutron scattering of incommensurate magnetic structures in MnSi thin films

Energy Technology Data Exchange (ETDEWEB)

Wiedemann, Birgit; Pfleiderer, Christian; Boeni, Peter [Physik Department, Technische Universitaet Muenchen (Germany); Zhang, Shilei; Hesjedal, Thorsten [Clarendon Laboratory, Department of Physics, University of Oxford (United Kingdom); Khaydukov, Yury; Soltwedel, Olaf; Keller, Thomas [Max-Planck-Institut fuer Festkoerperforschung (Germany); Max Planck Society, Outstation at FRM-II (Germany); Muehlbauer, Sebastian [Forschungsneutronenquelle Heinz Maier Leibnitz, Technische Universitaet Muenchen (Germany); Chacon, Alfonso [Physik Department, Technische Universitaet Muenchen (Germany); Forschungsneutronenquelle Heinz Maier Leibnitz, Technische Universitaet Muenchen (Germany)

2015-07-01

The topological stability of skyrmions in bulk samples of MnSi and the observation of spin transfer torque effects at ultra-low current densities have generated great interest in skyrmions in chiral magnets as a new route towards next generation spintronics devices. Yet, the formation of skyrmions in MBE grown thin films of MnSi reported in the literature is highly controversial. We report gracing incidence small angle neutron scattering (GISANS) of the magnetic order in selected thin films of MnSi grown by state of the art MBE techniques. In combination with polarised neutron reflectometry (PNR) and magnetisation measurements of the same samples our data provide direct reciprocal space information of the incommensurate magnetic order, clarifying the nature of magnetic phase diagram.

Grazing incidence small angle X-ray scattering study of silver nanoparticles in ion-exchanged glasses

Energy Technology Data Exchange (ETDEWEB)

Cheng, Weidong, E-mail: 57399942@qq.com [College of Materials Science and Engineering, Qiqihar University, Qiqihar 161006 (China); Wu, Zhaojun [Department of Practice Teaching and Equipment Management, Qiqihar University, Qiqihar 161006 (China); Gu, Xiaohua [College of Materials Science and Engineering, Qiqihar University, Qiqihar 161006 (China); Xing, Xueqing; Mo, Guang [Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China); Wu, Zhonghua, E-mail: wuzh@ihep.ac.cn [Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China)

2015-05-15

The size and distribution of silver nanoparticles in ion-exchanged silicate glass induced by thermal treatments in air at different temperatures were investigated by means of grazing incidence small angle X-ray scattering technique, X-ray diffraction and optical absorption spectra. Silver–sodium ion exchange of soda-lime silicate glasses was done at 350 °C for 240 min, then the samples were treated by thermal annealing in air at different temperatures 400, 500 and 550 °C, respectively, for 1 h. After the annealing treatment above 400 °C for 1 h, smaller Ag nanoparticles occurred, together with bigger ones. Both dissolution of smaller Ag nanoparticles and diffusion of larger ones are discussed in these stages of annealing in this contribution.

Small angle neutron scattering and calorimetric studies of large unilamellar vesicles of the phospholipid dipalmitoylphosphatidylcholine

Energy Technology Data Exchange (ETDEWEB)

Mason, P.C.; Gaulin, B.D. [Department of Physics and Astronomy, McMaster University, Hamilton, Ontario, L8S 4M1 (CANADA); Epand, R.M. [Department of Biochemistry, McMaster University, Hamilton, Ontario, L8N 3Z5 (CANADA); Wignall, G.D.; Lin, J.S. [Center for Small-Angle Scattering Research, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States)

1999-03-01

High-resolution differential scanning calorimetry (DSC) and small angle neutron scattering (SANS) experiments have been conducted on large unilamellar vesicles (LUV{close_quote}s) of the phospholipid dipalmitoylphosphatidylcholine (DPPC) in excess water. The DSC results indicate a phase transition at temperatures corresponding to the gel (L{sub {beta}{sup {prime}}}) to ripple (P{sub {beta}{sup {prime}}}) phase transition seen in multilamellar vesicles of DPPC while the SANS experiments provide direct evidence for the formation of the P{sub {beta}{sup {prime}}} phase in these systems. In addition, it is shown that SANS is an effective technique for extracting structural parameters such as vesicle radius and thickness in LUV model membrane systems. {copyright} {ital 1999} {ital The American Physical Society}

Carbon Condensation during High Explosive Detonation with Time Resolved Small Angle X-ray Scattering

Science.gov (United States)

Hammons, Joshua; Bagge-Hansen, Michael; Nielsen, Michael; Lauderbach, Lisa; Hodgin, Ralph; Bastea, Sorin; Fried, Larry; May, Chadd; Sinclair, Nicholas; Jensen, Brian; Gustavsen, Rick; Dattelbaum, Dana; Watkins, Erik; Firestone, Millicent; Ilavsky, Jan; van Buuren, Tony; Willey, Trevor; Lawrence Livermore National Lab Collaboration; Los Alamos National Laboratory Collaboration; Washington State University/Advanced Photon Source Team

Carbon condensation during high-energy detonations occurs under extreme conditions and on very short time scales. Understanding and manipulating soot formation, particularly detonation nanodiamond, has attracted the attention of military, academic and industrial research. An in-situ characterization of these nanoscale phases, during detonation, is highly sought after and presents a formidable challenge even with today's instruments. Using the high flux available with synchrotron X-rays, pink beam small angle X-ray scattering is able to observe the carbon phases during detonation. This experimental approach, though powerful, requires careful consideration and support from other techniques, such as post-mortem TEM, EELS and USAXS. We present a comparative survey of carbon condensation from different CHNO high explosives. This work was performed under the auspices of the US DOE by LLNL under Contract DE-AC52-07NA27344.

Watching Nanoparticles Form: An In Situ (Small-/Wide-Angle X-ray Scattering/Total Scattering) Study of the Growth of Yttria-Stabilised Zirconia in Supercritical Fluids

DEFF Research Database (Denmark)

Tyrsted, Christoffer; Pauw, Brian; Jensen, Kirsten Marie Ørnsbjerg

2012-01-01

Understanding nanoparticle formation reactions requires multitechnique in situ characterisation, since no single characterisation technique provides adequate information. Here, the first combined small-angle X-ray scattering (SAXS)/wide-angle X-ray scattering (WAXS)/total-scattering study of nano...... of nanoparticle formation is presented. We report on the formation and growth of yttria-stabilised zirconia (YSZ) under the extreme conditions of supercritical methanol for particles with Y2O3 equivalent molar fractions of 0, 4, 8, 12 and 25%....

Structure and dynamics of nonaqueous electrolyte solutions by small angle neutron scattering, brownian dynamics and primitive model theories

International Nuclear Information System (INIS)

Kunz, W.; Turq, P.

1990-01-01

The study of electrolyte solutions by small angle neutron scattering (static) of quasi-elastic neutron scattering (dynamics) gives new perspectives to the primitive model of electrolytes, for both static and dynamic properties of those systems. Whereas all properties can be interpreted by brownian dynamics, integral equations cannot be used at the present time to get transport coefficients in all cases. As regards the choice of the potentials at the McMillan Mayer level, specific Gurney terms for solvation are not needed for tetraalkylammonium salts. (orig.)

Topological investigation of electronic silicon nanoparticulate aggregates using ultra-small-angle X-ray scattering

International Nuclear Information System (INIS)

Jonah, E. O.; Britton, D. T.; Beaucage, P.; Rai, D. K.; Beaucage, G.; Magunje, B.; Ilavsky, J.; Scriba, M. R.; Härting, M.

2012-01-01

The network topology of two types of silicon nanoparticles, produced by high energy milling and pyrolysis of silane, in layers deposited from inks on permeable and impermeable substrates has been quantitatively characterized using ultra-small-angle X-ray scattering, supported by scanning electron microscopy observations. The milled particles with a highly polydisperse size distribution form agglomerates, which in turn cluster to form larger aggregates with a very high degree of aggregation. Smaller nanoparticles with less polydisperse size distribution synthesized by thermal catalytic pyrolysis of silane form small open clusters. The Sauter mean diameters of the primary particles of the two types of nanoparticles were obtained from USAXS particle volume to surface ratio, with values of ∼41 and ∼21 nm obtained for the high energy milled and pyrolysis samples, respectively. Assuming a log-normal distribution of the particles, the geometric standard deviation of the particles was calculated to be ∼1.48 for all the samples, using parameters derived from the unified fit to the USAXS data. The flow properties of the inks and substrate combination lead to quantitative changes in the mean particle separation, with slowly curing systems with good capillary flow resulting in denser networks with smaller aggregates and better contact between particles.

Structural evolution of regenerated silk fibroin under shear: Combined wide- and small-angle x-ray scattering experiments using synchrotron radiation

International Nuclear Information System (INIS)

Rossle, Manfred; Panine, Pierre; Urban, Volker S.; Riekel, Christine

2004-01-01

The structural evolution of regenerated Bombyx mori silk fibroin during shearing with a Couette cell has been studied in situ by synchrotron radiation small- and wide-angle x-ray scattering techniques. An elongation of fibroin molecules was observed with increasing shear rate, followed by an aggregation phase. The aggregates were found to be amorphous with β-conformation according to infrared spectroscopy. Scanning x-ray microdiffraction with a 5 (micro)m beam on aggregated material, which had solidified in air, showed silk II reflections and a material with equatorial reflections close to the silk I structure reflections, but with strong differences in reflection intensities. This silk I type material shows up to two low-angle peaks suggesting the presence of water molecules that might be intercalated between hydrogen-bonded sheets.

Structural evolution of regenerated silk fibroin under shear: Combined wide- and small-angle x-ray scattering experiments using synchrotron radiation

Energy Technology Data Exchange (ETDEWEB)

Rossle, Manfred [European Molecular Biology Laboratory (EMBL), France; Panine, Pierre [European Synchrotron Radiation Facility (ESRF); Urban, Volker S [ORNL; Riekel, Christine [European Synchrotron Radiation Facility (ESRF)

2004-04-01

The structural evolution of regenerated Bombyx mori silk fibroin during shearing with a Couette cell has been studied in situ by synchrotron radiation small- and wide-angle x-ray scattering techniques. An elongation of fibroin molecules was observed with increasing shear rate, followed by an aggregation phase. The aggregates were found to be amorphous with {beta}-conformation according to infrared spectroscopy. Scanning x-ray microdiffraction with a 5 {micro}m beam on aggregated material, which had solidified in air, showed silk II reflections and a material with equatorial reflections close to the silk I structure reflections, but with strong differences in reflection intensities. This silk I type material shows up to two low-angle peaks suggesting the presence of water molecules that might be intercalated between hydrogen-bonded sheets.

small signal analysis of load angle governing and excitation control

African Journals Online (AJOL)

Dr Obe

system stabilizers (PSS) or using terminal voltage for control of exciter and speed signal for governor. ... Vfd= generator field voltage. Xd, Xq ... each other in the frequency domain, and therefore ..... angle sensing equipment, relays and.

Power-law correlations and finite-size effects in silica particle aggregates studied by small-angle neutron scattering

DEFF Research Database (Denmark)

Freltoft, T.; Kjems, Jørgen; Sinha, S. K.

1986-01-01

Small-angle neutron scattering from normal, compressed, and water-suspended powders of aggregates of fine silica particles has been studied. The samples possessed average densities ranging from 0.008 to 0.45 g/cm3. Assuming power-law correlations between particles and a finite correlation length ξ......, the authors derive the scattering function S(q) from specific models for particle-particle correlation in these systems. S(q) was found to provide a satisfactory fit to the data for all samples studied. The fractal dimension df corresponding to the power-law correlation was 2.61±0.1 for all dry samples, and 2...

Investigation of coercivity mechanism in hot deformed Nd-Fe-B permanent magnets by small-angle neutron scattering

International Nuclear Information System (INIS)

Yano, M.; Manabe, A.; Shoji, T.; Kato, A.; Ono, K.; Harada, M.; Kohlbrecher, J.

2014-01-01

The magnetic reversal behaviors of single domain sized Nd-Fe-B permanent magnets, with and without isolation between the Nd 2 Fe 14 B grains, was clarified using small-angle neutron scattering (SANS). The SANS patterns obtained arose from changes in the magnetic domains and were analyzed using the Teubner–Stray model, a phenomenological correlation length model, to quantify the periodicity and morphology of the magnetic domains. The results indicated that the magnetic reversal evolved with the magnetic domains that had similar sized grains. The grain isolation enabled us to realize the reversals of single domains

Antibodies under pressure: A Small-Angle X-ray Scattering study of Immunoglobulin G under high hydrostatic pressure.

Science.gov (United States)

König, Nico; Paulus, Michael; Julius, Karin; Schulze, Julian; Voetz, Matthias; Tolan, Metin

2017-12-01

In the present work two subclasses of the human antibody Immunoglobulin G (IgG) have been investigated by Small-Angle X-ray Scattering under high hydrostatic pressures up to 5kbar. It is shown that IgG adopts a symmetric T-shape in solution which differs significantly from available crystal structures. Moreover, high-pressure experiments verify the high stability of the IgG molecule. It is not unfolded by hydrostatic pressures of up to 5kbar but a slight increase of the radius of gyration was observed at elevated pressures. Copyright © 2017 Elsevier B.V. All rights reserved.

Small-angle neutron scattering study of recombinant yeast-derived human hepatitis B virus surface antigen vaccine particle

Science.gov (United States)

Sato, M.; Ito, Y.; Kameyama, K.; Imai, M.; Ishikawa, N.; Takagi, T.

1995-02-01

The overall and internal structure of recombinant yeast-derived human hepatitis B virus surface antigen vaccine particles was investigated by small-angle neutron scattering using the contrast variation method. The vaccine is a nearly spherical particle, and its contrast-matching point was determined to be at about 24% D 2O content, indicating that a large part of the vaccine particle is occupied by lipids and carbohydrates from the yeast. The Stuhrmann plot suggests that the surface antigens exist predominantly in the peripheral region of the particle, which is favorable to the induction of anti-virus antibodies.

Microstructural characterization of dental zinc phosphate cements using combined small angle neutron scattering and microfocus X-ray computed tomography

Czech Academy of Sciences Publication Activity Database

Viani, Alberto; Sotiriadis, Konstantinos; Kumpová, Ivana; Mancini, L.; Appavou, M.-S.

2017-01-01

Roč. 33, č. 4 (2017), s. 402-417 ISSN 0109-5641 R&D Projects: GA MŠk(CZ) LO1219 Keywords : zinc phosphate cements * small angle neutron scattering * X-ray micro-computed tomography * X-ray powder diffraction * zinc oxide * acid-base cements Subject RIV: JJ - Other Materials OBOR OECD: Composites (including laminates, reinforced plastics, cermets, combined natural and synthetic fibre fabrics Impact factor: 4.070, year: 2016 https://www.sciencedirect.com/science/article/pii/S0109564116305127

Study of change in dispersion and orientation of clay platelets in a polymer nanocomposite during tensile test by variostage small-angle X-ray scattering

CSIR Research Space (South Africa)

Bandyopadhyay, J

2012-04-01

Full Text Available To understand the change in dispersion and orientation of clay platelets in three-dimensional space during tensile test, neat polymer and its nanocomposite samples were studied by small- and wide-angle X-ray scattering (SWAXS). The samples after...

The influence of C/Ta ratio on TaC precipitates in Co-Re base alloys investigated by small-angle neutron scattering

Czech Academy of Sciences Publication Activity Database

Karge, L.; Gilles, R.; Mukherji, D.; Strunz, Pavel; Beran, Přemysl; Hofmann, M.; Gavilano, J. L.; Keiderling, U.; Dolotko, O.; Kriele, A.; Neubert, A.; Rösler, J.; Petry, W.

2017-01-01

Roč. 132, JUN (2017), s. 354-366 ISSN 1359-6454 R&D Projects: GA ČR GB14-36566G Institutional support: RVO:61389005 Keywords : high temperature alloys * small-angle neutron scattering * precipitaiton * in-situ studies * phase transformation Subject RIV: BM - Solid Matter Physics ; Magnetism OBOR OECD: Condensed matter physics (including formerly solid state physics, supercond.) Impact factor: 5.301, year: 2016

Atomistic modelling of scattering data in the Collaborative Computational Project for Small Angle Scattering (CCP-SAS).

Science.gov (United States)

Perkins, Stephen J; Wright, David W; Zhang, Hailiang; Brookes, Emre H; Chen, Jianhan; Irving, Thomas C; Krueger, Susan; Barlow, David J; Edler, Karen J; Scott, David J; Terrill, Nicholas J; King, Stephen M; Butler, Paul D; Curtis, Joseph E

2016-12-01

The capabilities of current computer simulations provide a unique opportunity to model small-angle scattering (SAS) data at the atomistic level, and to include other structural constraints ranging from molecular and atomistic energetics to crystallography, electron microscopy and NMR. This extends the capabilities of solution scattering and provides deeper insights into the physics and chemistry of the systems studied. Realizing this potential, however, requires integrating the experimental data with a new generation of modelling software. To achieve this, the CCP-SAS collaboration (http://www.ccpsas.org/) is developing open-source, high-throughput and user-friendly software for the atomistic and coarse-grained molecular modelling of scattering data. Robust state-of-the-art molecular simulation engines and molecular dynamics and Monte Carlo force fields provide constraints to the solution structure inferred from the small-angle scattering data, which incorporates the known physical chemistry of the system. The implementation of this software suite involves a tiered approach in which GenApp provides the deployment infrastructure for running applications on both standard and high-performance computing hardware, and SASSIE provides a workflow framework into which modules can be plugged to prepare structures, carry out simulations, calculate theoretical scattering data and compare results with experimental data. GenApp produces the accessible web-based front end termed SASSIE-web , and GenApp and SASSIE also make community SAS codes available. Applications are illustrated by case studies: (i) inter-domain flexibility in two- to six-domain proteins as exemplified by HIV-1 Gag, MASP and ubiquitin; (ii) the hinge conformation in human IgG2 and IgA1 antibodies; (iii) the complex formed between a hexameric protein Hfq and mRNA; and (iv) synthetic 'bottlebrush' polymers.

Laser ablation and injection moulding as techniques for producing micro channels compatible with Small Angle X-Ray Scattering

DEFF Research Database (Denmark)

Haider, R.; Marmiroli, B.; Gavalas, I.

2018-01-01

Microfluidic mixing is an important means for in-situ sample preparation and handling while Small Angle X-Ray Scattering (SAXS) is a proven tool for characterising (macro-)molecular structures. In combination those two techniques enable investigations of fast reactions with high time resolution......, the requirement for low scattering especially limits the techniques suitable for producing the mixer, as the fabrication process can induce molecular orientations and stresses that can adversely influence the scattering signal. Not only is it important to find a production method that results in a device with low...

Automated microfluidic sample-preparation platform for high-throughput structural investigation of proteins by small-angle X-ray scattering

DEFF Research Database (Denmark)

Lafleur, Josiane P.; Snakenborg, Detlef; Nielsen, Søren Skou

2011-01-01

A new microfluidic sample-preparation system is presented for the structural investigation of proteins using small-angle X-ray scattering (SAXS) at synchrotrons. The system includes hardware and software features for precise fluidic control, sample mixing by diffusion, automated X-ray exposure...... control, UV absorbance measurements and automated data analysis. As little as 15 l of sample is required to perform a complete analysis cycle, including sample mixing, SAXS measurement, continuous UV absorbance measurements, and cleaning of the channels and X-ray cell with buffer. The complete analysis...

Application of a one-dimensional position-sensitive detector to a Kratky small-angle x-ray camera

International Nuclear Information System (INIS)

Russell, T.P.; Stein, R.S.; Kopp, M.K.; Zedler, R.E.; Hendricks, R.W.; Lin, J.S.

1979-01-01

A conventional Kratky small-angle collimation system has been modified to allow the use of a one-dimensional position-sensitive x-ray detector. The detector was designed specifically for use with a long-slit camera and has uniform sensitivity over the entire beam in the slit-length direction. Procedures for alignment of the collimation system are given, and a variety of tests of the performance of the system are presented. Among the latter are measurements of electronic noise and parasitic scattering as well as comparisons against samples which were also measured on other cameras. The good agreement of these comparisons demonstrates the success of the use of a position-sensitive detector with the Kratky collimation system

Characterization of oligomerization of a peptide from the ebola virus glycoprotein by small-angle neutron scattering

International Nuclear Information System (INIS)

Egorov, V. V.; Gorshkov, A. N.; Murugova, T. N.; Vasin, A. V.; Lebedev, D. V.; Isaev-Ivanov, V. V.; Kiselev, O. I.

2016-01-01

Transmission electron microscopy (TEM) and small-angle neutron scattering (SANS) studies showed that model peptides QNALVCGLRQ (G33) and QNALVCGLRG (G31) corresponding to region 551–560 of the GP protein of the Sudan Ebola virus are prone to oligomerization in solution. Both peptides can form amyloid-like fibrills. The G33 peptide forms fibrils within one day of incubation, whereas the fibrillogenesis of the G31 peptide is observed only after incubation for several months. The possible role of the observed processes in the pathogenesis and the possibility of applying a combination of the TEM and SANS techniques to search for new compounds that are able to influence the protein oligomerization are discussed

Characterization of oligomerization of a peptide from the ebola virus glycoprotein by small-angle neutron scattering

Energy Technology Data Exchange (ETDEWEB)

Egorov, V. V., E-mail: vlaegur@omrb.pnpi.spb.ru [National Research Center “Kurchatov Institute”, Konstantinov Petersburg Nuclear Physics Institute (Russian Federation); Gorshkov, A. N. [Ministry of Health of the Russian Federation, Research Institute of Influenza (Russian Federation); Murugova, T. N. [Joint Institute for Nuclear Research (Russian Federation); Vasin, A. V. [Ministry of Health of the Russian Federation, Research Institute of Influenza (Russian Federation); Lebedev, D. V.; Isaev-Ivanov, V. V. [National Research Center “Kurchatov Institute”, Konstantinov Petersburg Nuclear Physics Institute (Russian Federation); Kiselev, O. I. [Ministry of Health of the Russian Federation, Research Institute of Influenza (Russian Federation)

2016-01-15

Transmission electron microscopy (TEM) and small-angle neutron scattering (SANS) studies showed that model peptides QNALVCGLRQ (G33) and QNALVCGLRG (G31) corresponding to region 551–560 of the GP protein of the Sudan Ebola virus are prone to oligomerization in solution. Both peptides can form amyloid-like fibrills. The G33 peptide forms fibrils within one day of incubation, whereas the fibrillogenesis of the G31 peptide is observed only after incubation for several months. The possible role of the observed processes in the pathogenesis and the possibility of applying a combination of the TEM and SANS techniques to search for new compounds that are able to influence the protein oligomerization are discussed.

Application of a one-dimensional position-sensitive detector to a Kratky small-angle x-ray camera

Energy Technology Data Exchange (ETDEWEB)

Russell, T.P.; Stein, R.S.; Kopp, M.K.; Zedler, R.E.; Hendricks, R.W.; Lin, J.S.

1979-01-01

A conventional Kratky small-angle collimation system has been modified to allow the use of a one-dimensional position-sensitive x-ray detector. The detector was designed specifically for use with a long-slit camera and has uniform sensitivity over the entire beam in the slit-length direction. Procedures for alignment of the collimation system are given, and a variety of tests of the performance of the system are presented. Among the latter are measurements of electronic noise and parasitic scattering as well as comparisons against samples which were also measured on other cameras. The good agreement of these comparisons demonstrates the success of the use of a position-sensitive detector with the Kratky collimation system.

Characterization of oligomerization of a peptide from the ebola virus glycoprotein by small-angle neutron scattering

Science.gov (United States)

Egorov, V. V.; Gorshkov, A. N.; Murugova, T. N.; Vasin, A. V.; Lebedev, D. V.; Isaev-Ivanov, V. V.; Kiselev, O. I.

2016-01-01

Transmission electron microscopy (TEM) and small-angle neutron scattering (SANS) studies showed that model peptides QNALVCGLRQ (G33) and QNALVCGLRG (G31) corresponding to region 551-560 of the GP protein of the Sudan Ebola virus are prone to oligomerization in solution. Both peptides can form amyloid-like fibrills. The G33 peptide forms fibrils within one day of incubation, whereas the fibrillogenesis of the G31 peptide is observed only after incubation for several months. The possible role of the observed processes in the pathogenesis and the possibility of applying a combination of the TEM and SANS techniques to search for new compounds that are able to influence the protein oligomerization are discussed.

Domain interaction in rabbit muscle pyruvate kinase. II. Small angle neutron scattering and computer simulation.

Science.gov (United States)

Consler, T G; Uberbacher, E C; Bunick, G J; Liebman, M N; Lee, J C

1988-02-25

The effects of ligands on the structure of rabbit muscle pyruvate kinase were studied by small angle neutron scattering. The radius of gyration, RG, decreases by about 1 A in the presence of the substrate phosphoenolpyruvate, but increases by about the same magnitude in the presence of the allosteric inhibitor phenylalanine. With increasing pH or in the absence of Mg2+ and K+, the RG of pyruvate kinase increases. Hence, there is a 2-A difference in RG between two alternative conformations. Length distribution analysis indicates that, under all experimental conditions which increase the radius of gyration, there is a pronounced increase observed in the probability for interatomic distance between 80 and 110 A. These small angle neutron scattering results indicate a "contraction" and "expansion" of the enzyme when it transforms between its active and inactive forms. Using the alpha-carbon coordinates of crystalline cat muscle pyruvate kinase, a length distribution profile was calculated, and it matches the scattering profile of the inactive form. These observations are expected since the crystals were grown in the absence of divalent cations (Stuart, D. I., Levine, M., Muirhead, H., and Stammers, D. K. (1979) J. Mol. Biol. 134, 109-142). Hence, results from neutron scattering, x-ray crystallographic, and sedimentation studies (Oberfelder, R. W., Lee, L. L.-Y., and Lee, J.C. (1984) Biochemistry 23, 3813-3821) are totally consistent with each other. With the aid of computer modeling, the crystal structure has been manipulated in order to effect changes that are consistent with the conformational change described by the solution scattering data. The structural manipulation involves the rotation of the B domain relative to the A domain, leading to the closure of the cleft between these domains. These manipulations resulted in the generation of new sets of atomic (C-alpha) coordinates, which were utilized in calculations, the result of which compared favorably with the

Six-dimensional real and reciprocal space small-angle X-ray scattering tomography.

Science.gov (United States)

Schaff, Florian; Bech, Martin; Zaslansky, Paul; Jud, Christoph; Liebi, Marianne; Guizar-Sicairos, Manuel; Pfeiffer, Franz

2015-11-19

When used in combination with raster scanning, small-angle X-ray scattering (SAXS) has proven to be a valuable imaging technique of the nanoscale, for example of bone, teeth and brain matter. Although two-dimensional projection imaging has been used to characterize various materials successfully, its three-dimensional extension, SAXS computed tomography, poses substantial challenges, which have yet to be overcome. Previous work using SAXS computed tomography was unable to preserve oriented SAXS signals during reconstruction. Here we present a solution to this problem and obtain a complete SAXS computed tomography, which preserves oriented scattering information. By introducing virtual tomography axes, we take advantage of the two-dimensional SAXS information recorded on an area detector and use it to reconstruct the full three-dimensional scattering distribution in reciprocal space for each voxel of the three-dimensional object in real space. The presented method could be of interest for a combined six-dimensional real and reciprocal space characterization of mesoscopic materials with hierarchically structured features with length scales ranging from a few nanometres to a few millimetres--for example, biomaterials such as bone or teeth, or functional materials such as fuel-cell or battery components.

Spin-wave dynamics in the helimagnet FeGe studied by small-angle neutron scattering

Science.gov (United States)

Siegfried, S.-A.; Sukhanov, A. S.; Altynbaev, E. V.; Honecker, D.; Heinemann, A.; Tsvyashchenko, A. V.; Grigoriev, S. V.

2017-04-01

We have studied the spin-wave stiffness of the Dzyaloshinskii-Moriya helimagnet FeGe in a temperature range from 225 K up to TC≈278.7 K by small-angle neutron scattering. The method we have used is based on [Grigoriev et al., Phys. Rev. B 92, 220415(R) (2015), 10.1103/PhysRevB.92.220415] and was extended here for the application in polycrystalline samples. We confirm the validity of the anisotropic spin-wave dispersion for FeGe caused by the Dzyaloshinskii-Moriya interaction. We have shown that the spin-wave stiffness A for the FeGe helimagnet decreases with a temperature as A (T ) =194 [1 -0.7 (T/TC) 4.2] meVÅ 2 . The finite value of the spin-wave stiffness A =58 meVÅ 2 at TC classifies the order-disorder phase transition in FeGe as being the first-order one.

Small-angle scattering of polychromatic X-rays: effects of bandwidth, spectral shape and high harmonics

Energy Technology Data Exchange (ETDEWEB)

Chen, Sen; Luo, Sheng-Nian

2018-02-16

Polychromatic X-ray sources can be useful for photon-starved small-angle X-ray scattering given their high spectral fluxes. Their bandwidths, however, are 10–100 times larger than those using monochromators. To explore the feasibility, ideal scattering curves of homogeneous spherical particles for polychromatic X-rays are calculated and analyzed using the Guinier approach, maximum entropy and regularization methods. Monodisperse and polydisperse systems are explored. The influence of bandwidth and asymmetric spectra shape are exploredviaGaussian and half-Gaussian spectra. Synchrotron undulator spectra represented by two undulator sources of the Advanced Photon Source are examined as an example, as regards the influence of asymmetric harmonic shape, fundamental harmonic bandwidth and high harmonics. The effects of bandwidth, spectral shape and high harmonics on particle size determination are evaluated quantitatively.

Beyond simple small-angle X-ray scattering: developments in online complementary techniques and sample environments.

Science.gov (United States)

Bras, Wim; Koizumi, Satoshi; Terrill, Nicholas J

2014-11-01

Small- and wide-angle X-ray scattering (SAXS, WAXS) are standard tools in materials research. The simultaneous measurement of SAXS and WAXS data in time-resolved studies has gained popularity due to the complementary information obtained. Furthermore, the combination of these data with non X-ray based techniques, via either simultaneous or independent measurements, has advanced understanding of the driving forces that lead to the structures and morphologies of materials, which in turn give rise to their properties. The simultaneous measurement of different data regimes and types, using either X-rays or neutrons, and the desire to control parameters that initiate and control structural changes have led to greater demands on sample environments. Examples of developments in technique combinations and sample environment design are discussed, together with a brief speculation about promising future developments.

Small-angle scattering of polychromatic X-rays: effects of bandwidth, spectral shape and high harmonics.

Science.gov (United States)

Chen, Sen; Luo, Sheng Nian

2018-03-01

Polychromatic X-ray sources can be useful for photon-starved small-angle X-ray scattering given their high spectral fluxes. Their bandwidths, however, are 10-100 times larger than those using monochromators. To explore the feasibility, ideal scattering curves of homogeneous spherical particles for polychromatic X-rays are calculated and analyzed using the Guinier approach, maximum entropy and regularization methods. Monodisperse and polydisperse systems are explored. The influence of bandwidth and asymmetric spectra shape are explored via Gaussian and half-Gaussian spectra. Synchrotron undulator spectra represented by two undulator sources of the Advanced Photon Source are examined as an example, as regards the influence of asymmetric harmonic shape, fundamental harmonic bandwidth and high harmonics. The effects of bandwidth, spectral shape and high harmonics on particle size determination are evaluated quantitatively.

Elastic differential cross sections for small-angle scattering of 25-, 40-, and 60-keV protons by atomic hydrogen

International Nuclear Information System (INIS)

Rille, E.; Peacher, J.L.; Redd, E.; Kvale, T.J.; Seely, D.G.; Blankenship, D.M.; Olson, R.E.; Park, J.T.

1984-01-01

Elastic angular differential cross sections for small-angle scattering of protons by atomic hydrogen have been measured. The technique utilized unambigously distinguishes the elastically and inelastically scattered ions. The cross sections fall monotonically by 3 orders of magnitude in the angular range from 0.5 to 3.0 mrad, in the center-of-mass system. The experimental data obtained are in very good agreement with a multistate calculation and in fair agreement with both our Glauber-approximation and classical-trajectory Monte Carlo results

Structural changes in C–S–H gel during dissolution: Small-angle neutron scattering and Si-NMR characterization

Energy Technology Data Exchange (ETDEWEB)

Trapote-Barreira, Ana, E-mail: anatrapotebarreira@gmail.com [Institute of Environmental Assessment and Water Research (IDAEA), Barcelona 08034, Catalonia (Spain); Porcar, Lionel [National Institute of Standards and Technology (NIST), Gaithersburg, MD 20899 (United States); Large Scale Structure Group, Institut Laue Langevin, Grenoble (France); Cama, Jordi; Soler, Josep M. [Institute of Environmental Assessment and Water Research (IDAEA), Barcelona 08034, Catalonia (Spain); Allen, Andrew J. [National Institute of Standards and Technology (NIST), Gaithersburg, MD 20899 (United States)

2015-06-15

Flow-through experiments were conducted to study the calcium–silicate–hydrate (C–S–H) gel dissolution kinetics. During C–S–H gel dissolution the initial aqueous Ca/Si ratio decreases to reach the stoichiometric value of the Ca/Si ratio of a tobermorite-like phase (Ca/Si = 0.83). As the Ca/Si ratio decreases, the solid C–S–H dissolution rate increases from (4.5 × 10{sup −} {sup 14} to 6.7 × 10{sup −} {sup 12}) mol m{sup −} {sup 2} s{sup −} {sup 1}. The changes in the microstructure of the dissolving C–S–H gel were characterized by small-angle neutron scattering (SANS) and {sup 29}Si magic-angle-spinning nuclear magnetic resonance ({sup 29}Si-MAS NMR). The SANS data were fitted using a fractal model. The SANS specific surface area tends to increase with time and the obtained fit parameters reflect the changes in the nanostructure of the dissolving solid C–S–H within the gel. The {sup 29}Si MAS NMR analyses show that with dissolution the solid C–S–H structure tends to a more ordered tobermorite structure, in agreement with the Ca/Si ratio evolution.

Alzheimer's disease imaging biomarkers using small-angle x-ray scattering

Science.gov (United States)

Choi, Mina; Alam, Nadia; Dahal, Eshan; Ghammraoui, Bahaa; Badano, Aldo

2016-03-01

There is a need for novel imaging techniques for the earlier detection of Alzheimer's disease (AD). Two hallmarks of AD are amyloid beta (Aβ) plaques and tau tangles that are formed in the brain. Well-characterized x-ray cross sections of Aβ and tau proteins in a variety of structural states could potentially be used as AD biomarkers for small-angle x-ray scattering (SAXS) imaging without the need for injectable probes or contrast agents. First, however, the protein structures must be controlled and measured to determine accurate biomarkers for SAXS imaging. Here we report SAXS measurements of Aβ42 and tau352 in a 50% dimethyl sulfoxide (DMSO) solution in which these proteins are believed to remain monomeric because of the stabilizing interaction of DMSO solution. Our SAXS analysis showed the aggregation of both proteins. In particular, we found that the aggregation of Aβ42 slowly progresses with time in comparison to tau352 that aggregates at a faster rate and reaches a steady-state. Furthermore, the measured signals were compared to the theoretical SAXS profiles of Aβ42 monomer, Aβ42 fibril, and tau352 that were computed from their respective protein data bank structures. We have begun the work to systematically control the structural states of these proteins in vitro using various solvent conditions. Our future work is to utilize the distinct SAXS profiles of various structural states of Aβ and tau to build a library of signals of interest for SAXS imaging in brain tissue.

Small-angle neutron scattering investigation of the chain conformation of lamellar polystyrene/isoprene phase in solid state

International Nuclear Information System (INIS)

Constantinescu, L.M.

1994-01-01

Small-angle neutron scattering has been used in the study of chain conformation of lamellar styrene/isoprene block copolymers oriented in large single crystals. The radius of gyration of deuterated polystyrene chains around the normal to the interface has been measured. By comparing this direct evolution of the lateral dimension of the chains with the average chain separation given by the molecular area (the surface available at the interface for each covalent bond linking the blocks together) we characterized the transverse interpenetration degree of the chains. The polystyrene chains are displayed in simple strata own micro-domains, without an important interpenetration. (Author) 9 Figs., 2 Tabs., 25 Refs

Rapid small-angle X-ray diffraction of a tonically contracting molluscan smooth muscle recorded with imaging plates

International Nuclear Information System (INIS)

Tajima, Y.; Okada, K.; Yoshida, O.; Seto, T.; Amemiya, Y.

1989-01-01

Small-angle X-ray diffraction patterns from the anterior byssus retractor muscles of Mytilus edulis contracting tonically in response to stimulation with acetylcholine were recorded in a 30 s exposure with synchrotron radiation and a high-sensitivity X-ray area detector called an imaging plate. The 190 A layer line from the thin filaments increased in intensity with increase in tonic tension up to 6x10 4 kg m -2 . Above this value, the layer-line intensity remained almost constant and comparable to that for a contracting skeletal muscle, indicating that the same structural changes of the thin filaments occur in both muscles. (orig.)

General shape and hapten-induced conformational changes of pig anti-dinitrophenyl antibody. A small-angle scattering study

International Nuclear Information System (INIS)

Cher, L.; Gladkikh, I.A.; Franek, F.; Kunchenko, A.B.; Ostanevich, Yu.M.

1980-01-01

Pig anti-dinitrophenyl antibodies were studied by neutron and X-ray small-angle scattering. Observed scattering curves show that the shapes of two antibody types, precipitating and non-precipitating, are similar, however the latter being more compact. A hapten binding induced conformational change of antibody is observed. This conformational change might be described as a contraction of the whole molecule via similarity transformation. The spatial models of pig antibody molecule based on the existing experimental data were designed. Most probable models have a cavity in the Fsub(c) part and the Fsub(ab) parts are either fully extended or slightly bent down to the Fsub(c) part

In situ grazing incidence small-angle X-ray scattering investigation of polystyrene nanoparticle spray deposition onto silicon.

Science.gov (United States)

Herzog, Gerd; Benecke, Gunthard; Buffet, Adeline; Heidmann, Berit; Perlich, Jan; Risch, Johannes F H; Santoro, Gonzalo; Schwartzkopf, Matthias; Yu, Shun; Wurth, Wilfried; Roth, Stephan V

2013-09-10

We investigated the spray deposition and subsequent self-assembly during drying of a polystyrene nanoparticle dispersion with in situ grazing incidence small-angle X-ray scattering at high time resolution. During the fast deposition of the dispersion and the subsequent evaporation of the solvent, different transient stages of nanoparticle assembly can be identified. In the first stage, the solvent starts to evaporate without ordering of the nanoparticles. During the second stage, large-scale structures imposed by the breakup of the liquid film are observable. In this stage, the solvent evaporates further and nanoparticle ordering starts. In the late third drying stage, the nanoparticles self-assemble into the final layer structure.

Assess the Intra-molecular Cavity in PAMAM Dendrimers by Small Angle Neutron Scattering

International Nuclear Information System (INIS)

Chen, Wei-Ren

2008-01-01

In this report, we present a contrast variation small angle neutron scattering (SANS) study of a series of neutral PAMAM dendrimer in aqueous solutions using three different generations (G4-6) at a concentration of about 10 mg/ml. Varying the solvent hydrogen-deuterium ratio, the scattering contributions from the water molecules and the constituent components of PAMAM dendrimer can be determined. Using an analytical model of the scattering cross section I(Q) incorporating the effect of water penetration, we have quantified the intra-molecular space of PAMAM dendrimer by evaluating the number of guest water molecules and we draw a direct comparison to computational predictions. As expected, the overall available internal cavity was seen to increase as a function of increasing dendrimer generation. However, the fraction of water accessible volume in the internal cavity of a dendrimer was found to remain invariant for the three generation PAMAM dendrimers studied in this report. We have also estimated the average water density inside a dendrimer, which is found to be higher than that of bulk water

Fractal Structures on Silica Aerogels Containing Titanium: A Small Angle Neutron Scattering Study

International Nuclear Information System (INIS)

Widya Sari; Dian Fitriyani; Abdul Aziz Mohamed; Noordin Ibrahim

2009-01-01

Full text: The fractal structure of silica aerogels containing titanium has been investigated by means of small-angle neutron scattering (SANS) technique. The SANS experiments were conducted using a 36 meter SANS BATAN spectrometer (SMARTer) in Serpong, Indonesia in the range of momentum transfer Q, 0.006 -1 ) < 0.3. The power-law for a fractal object scattering Q-D observed from all measured samples. The Fourier transform of pattern I(Q) a pair correlation model function was implemented in analyzing the structure factor from the power-law scattering profiles. The results are showing that the silica aerogels containing titanium has a mass fractal where its dimension DM is larger than the pure silica aerogels. The mass fractal dimension of silica aerogels containing titanium is relatively constant between 2.23 to 2.40 with the decrease of acid concentrations during a sol-gel process and formed a nanometer size of aggregate. Those fractal structures were simulated using a Delphi language and the results are presented in this paper. (author)

On small-angle neutron scattering from microemulsion droplets: the role of shape fluctuations

International Nuclear Information System (INIS)

Lisy, V.; Brutovsky, B.

2001-01-01

The form factor and intensity of static neutron scattering from microemulsion droplets are calculated. The droplet is modeled by a double-layered sphere consisting of a fluid core and a thin surfactant layer, immersed in another fluid. All the three components are incompressible and characterized by different scattering length densities. As distinct from previous descriptions of small-angle neutron scattering (SANS), we consistently take into account thermal fluctuations of the droplet shape, to the second order of the fluctuations of the droplet radius. The properties of the layer are described within Helfrich's concept of the elasticity of curved interfaces. It is shown that in many cases the account for the fluctuations is essential for the interpretation of SANS. Information about two elastic constants k and k bar (so far extracted from the experiments in the combination 2k + k bar) can be now simultaneously obtained from SANS for the system in conditions of two-phase coexistence. As an illustration, the theory is applied for the quantitative description of SANS experiments from the literature

Limiting cases of the small-angle scattering approximation solutions for the propagation of laser beams in anisotropic scattering media

Science.gov (United States)

Box, M. A.; Deepak, A.

1981-01-01

The propagation of photons in a medium with strongly anisotropic scattering is a problem with a considerable history. Like the propagation of electrons in metal foils, it may be solved in the small-angle scattering approximation by the use of Fourier-transform techniques. In certain limiting cases, one may even obtain analytic expressions. This paper presents some of these results in a model-independent form and also illustrates them by the use of four different phase-function models. Sample calculations are provided for comparison purposes

III International Conference on Small Angle Neutron Scattering dedicated to the 80 anniversary of Yu.M. Ostanevich

International Nuclear Information System (INIS)

2017-01-01

Preface “Among the many well-known fundamental and applied consequences of neutron discovery, one of the first was the emergence of structural neutron diffraction - one of the methods for studying the spatial structure of condensed matter at the atomic level. Investigating the dynamics of biological macromolecules by neutron diffraction methods is an area that is almost untouched. We believe that also in this direction one should expect rapid progress.” Yu.M.Ostanevich and I.N.Serdyuk Uspekhi Fizicheskih Nauk (1982) More than 30 years after Ostanevich and Serdyuk reviewed the then 50 years from the neutron discovery, we are happy to support their statement and prediction by reporting on the further progress in the field of neutron scattering research. Frank Laboratory of Neutron Physics has organized the III International Conference on Small Angle Neutron Scattering (YuMO2016) that was – not coincidently – dedicated to the 80th anniversary of Ostanevich. Yuriy Mechislavovich Ostanevich (1936–1992) has had a determinative and crucial contribution to the construction of spectrometers at the pulsed reactor IBR in Dubna, Russia. He contributed in particular to the development of time-of-flight small-angle neutron scattering (SANS) technique, and the selection of advanced scientific areas for its application. The SANS instrument at the IBR-2 reactor is called YuMO in his honour. The Ostanevich’s leadership and outstanding scientific achievements in SANS studies of polyelectrolytes, small molecules, fractals, metallic glasses, macromolecules, polymers, etc., were recognized also by a number of awards including the State Prize of the Russian Federation in 2000. To this end of course, we should not forget mentioning the contribution of close collaborators of Ostanevich: Laszlo Cser, Josef Plestil as well as Alexander Kunchenko, Vadim Bezzabotnov and Nikolay Gorski. The YuMO2016 conference focused on providing opportunities to discuss various possibilities of

Imaging of small amounts of pleural fluid. Part one - small pleural effusions

International Nuclear Information System (INIS)

Kocijancic, I.

2005-01-01

Background. Small pleural effusions are not readily identified on conventional radiographic views of the chest, but may be an important finding, sometimes leading, via thoracocentesis, to a definitive diagnosis of pleural carcinomatosis, infection or transudate. A small meniscus sign and a medial displacement of the costophrenic angle are the only subtle signs of small accumulations of fluid on posteroanterior chest X-rays. On lateral views the finding of a small meniscus sign in the posterior costophrenic angle is the sign of small pleural effusion. Conclusions. Lateral decubitus chest radiographs were used for many years for the diagnosis of small pleural effusions. In last decades ultrasonography of pleural space becomes a leading real-time method for demonstrating small pleural effusions. (author)

A new approximate algorithm for image reconstruction in cone-beam spiral CT at small cone-angles

International Nuclear Information System (INIS)

Schaller, S.; Flohr, T.; Steffen, P.

1996-01-01

This paper presents a new approximate algorithm for image reconstruction with cone-beam spiral CT data at relatively small cone-angles. Based on the algorithm of Wang et al., our method combines a special complementary interpolation with filtered backprojection. The presented algorithm has three main advantages over Wang's algorithm: (1) It overcomes the pitch limitation of Wang's algorithm. (2) It significantly improves z-resolution when suitable sampling schemes are applied. (3) It avoids the waste of applied radiation dose inherent to Wang's algorithm. Usage of the total applied dose is an important requirement in medical imaging. Our method has been implemented on a standard workstation. Reconstructions of computer-simulated data of different phantoms, assuming sampling conditions and image quality requirements typical to medical CT, show encouraging results

Small angle neutron scattering study of the gemini nonionic surfactant in heavy water solutions

International Nuclear Information System (INIS)

Rajewska, A

2012-01-01

The nonionic gemini surfactant α α'-[2,4,7,9-tetramethyl-5-decyne-4,7diyl]bis[ω hydroxyl-polyoxyethylene] (S-10) was investigated in heavy water solutions only for concentrations: 2.3%, 2.5%,3%, 3.4%, 4% and 5% at temperature 25 C with small angle neutron scattering (SANS) method. All of surfactants solutions were prepared using D 2 O (99.9% deuterated, Prikladnaia Chimia, St. Petersburg, Russia) as a solvent. The nonionic gemini surfactant S-10 was obtained from Air Products and Chemicals, Inc., and used without further purification. All SANS measurements were performed on V-4 SANS spectrometer at BENSC, Berlin (Germany). Neutrons were used in wavelength range of 0.02 - 4 nm - 1. For the measurements quartz cells of were used during experiment. Up to 14 such cells were placed in a holder. Results from experiment was calculated and evaluated with PCG 2.0 program from Graz University (Austria). In the investigated solutions two axis ellipsoidal micelles was observed.

Inversion of the pahse diagram in polymer blends studied by small-angle neutron scattering

International Nuclear Information System (INIS)

Jinnai, Hiroshi; Hasegawa, Hirokazu; Hashimoto, Takeji; Han, C.C.

1993-01-01

The miscibility of an amorphous mixture of normal (protonated) polybutadiend (HPB) and perdeuterated polybutadiene (DPB) has been extensively studied and was characterized by an upper critical solution temperature (UCST). In this study the miscibility of HPB and DPB as a function of temperature was studied by small-angle neutron scattering (SANS). The vinyl component of the DPB was held constant at 16%, while the vinyl frantion of the HPB was varied from 17-80%. The binary interaction parameter, χ, was obtained. The mixtures of DPB and HPB with 17-39% vinyl show UCST behaviors; i.e., χ increases with decreasing temperature. The mixture of DPB and HPB with 52% vinyl was found to have almost no temperature dependence. However, the mixture of DPB and HPB with 65-80% show a lower critical solution temperature (LCST) behavior; i.e., χ increases with increasing temperature. This inversion of the phase diagram from UCST to LCST has never been observed. (author)

Recent developments in X-ray and neutron small-angle scattering instrumentation and data analysis

International Nuclear Information System (INIS)

Schelten, J.

1978-01-01

The developments in instrumentation and data analysis that have occurred in the field of small-angle X-ray and neutron scattering since 1973 are reviewed. For X-rays, the cone camera collimation was invented, synchrotrons and storage rings were demonstrated to be intense sources of X-radiation, and one- and two-dimensional position-sensitive detectors were interfaced to cameras with both point and line collimation. For neutrons, the collimators and detectors on the Juelich and Grenoble machines were improved, new D11-type instruments were built or are under construction at several sites, double-crystal instruments were set up, and various new machines have been proposed. Significant progress in data analysis and evaluation has been made through application of mathematical techniques such as the use of spline functions, error minimization with constraints, and linear programming. Several special experiments, unusual in respect to the anisotropy of the scattering pattern, gravitational effects, moving scatterers, and dynamic fast time slicing, are discussed. (Auth.)

Small angle neutron scattering on an absolute intensity scale and the internal surface of diatom frustules from three species of differing morphologies

Czech Academy of Sciences Publication Activity Database

Garvey, C. J.; Strobl, M.; Percot, A.; Šaroun, Jan; Haug, J.; Vyverman, W.; Chepurnov, V. A.; Ferris, J. M.

2013-01-01

Roč. 42, č. 5 (2013), s. 395-404 ISSN 0175-7571 Institutional support: RVO:61389005 Keywords : biosilica * diffusion limited aggregation * small angle neutron scattering * Raman spectroscopy * infrared spectroscopy * Porod law * BET isotherm * biomineralisation Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 2.474, year: 2013 http://link.springer.com/content/pdf/10.1007%2Fs00249-013-0889-x.pdf

From free to bound water - progress in hydratisation for concrete, measured by means of neutron small angle scatter

International Nuclear Information System (INIS)

Hempel, M.; Haeussler, F.; Eichhorn, E.

1993-01-01

Neutron small angle scatter (NSAS) is suitable for characterising matrix non-homogeneousness in many materials. The description of amorphous materials (distribution of clusters, defect structures, boundary surfaces, e.g.: Between pores and the solid matrix etc.) is possible, in principle, by NSAS. This method is non-destructive to the extent that no pretreatment of samples is necessary, which significantly affects the microstructure to be examined. The process of NSAS itself produces no changes in the sample regarding the target of the examination. Thus the progress of hydratisation in concrete can be observed by successive NSAS measurements in time. (orig./HP) [de

Solar cell angle of incidence corrections

Science.gov (United States)

Burger, Dale R.; Mueller, Robert L.

1995-01-01

Literature on solar array angle of incidence corrections was found to be sparse and contained no tabular data for support. This lack along with recent data on 27 GaAs/Ge 4 cm by 4 cm cells initiated the analysis presented in this paper. The literature cites seven possible contributors to angle of incidence effects: cosine, optical front surface, edge, shadowing, UV degradation, particulate soiling, and background color. Only the first three are covered in this paper due to lack of sufficient data. The cosine correction is commonly used but is not sufficient when the incident angle is large. Fresnel reflection calculations require knowledge of the index of refraction of the coverglass front surface. The absolute index of refraction for the coverglass front surface was not known nor was it measured due to lack of funds. However, a value for the index of refraction was obtained by examining how the prediction errors varied with different assumed indices and selecting the best fit to the set of measured values. Corrections using front surface Fresnel reflection along with the cosine correction give very good predictive results when compared to measured data, except there is a definite trend away from predicted values at the larger incident angles. This trend could be related to edge effects and is illustrated by a use of a box plot of the errors and by plotting the deviation of the mean against incidence angle. The trend is for larger deviations at larger incidence angles and there may be a fourth order effect involved in the trend. A chi-squared test was used to determine if the measurement errors were normally distributed. At 10 degrees the chi-squared test failed, probably due to the very small numbers involved or a bias from the measurement procedure. All other angles showed a good fit to the normal distribution with increasing goodness-of-fit as the angles increased which reinforces the very small numbers hypothesis. The contributed data only went to 65 degrees

Indirect transformation in reciprocal space: desmearing of small-angle scattering data from partially ordered systems

International Nuclear Information System (INIS)

Glatter, O.; Gruber, K.

1993-01-01

Indirect Fourier transformation is a widely used technique for the desmearing of instrumental broadening effects, for data smoothing and for Fourier transformation of small-angle scattering data. This technique, however, can only be applied to scattering curves with a band-limited Fourier transform, i.e. separated and noninteracting scattering centers. It can therefore not be used for scattering data from partially ordered systems. In this paper, a modified technique for partially ordered systems working in reciprocal space is presented. A peak-recognition technique allows its application to scattering functions with narrow peaks, such as the scattering functions of layered systems like lamellar stacks or strongly interacting particles. Arbitrary geometry effects and wavelength effects can be corrected. Examples of simulations show the merits and limits of this new method. One example shows its applicability to real data. (orig.)

Small angle neutron scattering study on short and long chain phosphatidylcholine mixture in trehalose solution

Energy Technology Data Exchange (ETDEWEB)

Takahashi, Hiroshi [Department of Physics, Gunma University, Maebashi, Gunma (Japan)

2001-03-01

Trehalose protects cells and proteins against various stresses due to low temperatures or dryness. In order to clarify the molecular mechanism of cryoprotective function of trehalose, we have studied the interaction between trehalose and phosphatidylcholine (PC) which is a main lipid component of cell membranes. In this study, the structural change of a binary PC mixture by the presence of trehalose was investigated by means of small angle neutron scattering. The PC binary mixture studied contains dihexanoyl-PC (diC{sub 6}PC) and dihexadecy-PC (DHPC). The former has short hydrocarbon chains and the latter has long hydrocarbon chains. The scattering profiles from the DHPC/diC{sub 6}PC mixture were changed, depending on trehalose concentrations. This change can be interpreted as suggesting that the presence of trehalose reduces the interfacial area between water and PCs. (author)

Beyond simple small-angle X-ray scattering: developments in online complementary techniques and sample environments

Directory of Open Access Journals (Sweden)

Wim Bras

2014-11-01

Full Text Available Small- and wide-angle X-ray scattering (SAXS, WAXS are standard tools in materials research. The simultaneous measurement of SAXS and WAXS data in time-resolved studies has gained popularity due to the complementary information obtained. Furthermore, the combination of these data with non X-ray based techniques, via either simultaneous or independent measurements, has advanced understanding of the driving forces that lead to the structures and morphologies of materials, which in turn give rise to their properties. The simultaneous measurement of different data regimes and types, using either X-rays or neutrons, and the desire to control parameters that initiate and control structural changes have led to greater demands on sample environments. Examples of developments in technique combinations and sample environment design are discussed, together with a brief speculation about promising future developments.

Analysis of a drum chopper for use on a new small angle diffractometer at IPNS

International Nuclear Information System (INIS)

Crawford, R.K.; Epperson, J.E.; Thiyagarajan, P.; Carpenter, J.M.

1990-01-01

Light-weight drum choppers rotating at 15 Hz have been in use on the IPNS powder diffractometers for several years, where they serve to eliminate the delayed-neutron background from much of the spectral region of interest. Monte Carlo simulations indicate that a similar chopper operated at 15 Hz should do an excellent job of delayed-neutron removal in the new small-angle diffractometer being designed at IPNS. The simulations also show that when the same chopper is operated at 7.5 Hz it performs quite successfully as a frame-elimination chopper, effectively eliminating neutrons from alternate pulses and allowing extension of the useful wavelength range of the instrument to ∼28 Angstrom. Thus the incorporation of such a chopper should add considerably to the range and flexibility of the new instrument. 7 refs., 9 figs

Conformation of cyclic and linear polydimethylsiloxane in the melt a small-angle neutron-scattering study

CERN Document Server

Gagliardi, S; Dagger, A; Semlyen, A J

2002-01-01

In this study we report small-angle neutron-scattering measurements of cyclic and linear polydimethylsiloxane (PDMS) in the melt. It has been suggested that due to the presence of topological constraints, rings in the melt may be more compact than Gaussian chains. We show that the cyclic chains are partially collapsed and do not follow Gaussian statistics: the weight-average radius of gyration R sub g sub , sub w is found to be proportional to M sub w sup 0 sup . sup 5 sup 3 and M sub w sup 0 sup . sup 4 sup 0 in the case of linear and cyclic PDMS, respectively. The results are in agreement with recent computer simulations, which predict R sub g to be proportional to N sup 2 sup / sup 5 , where N is the degree of polymerisation. (orig.)

Combining Single-Molecule Optical Trapping and Small-Angle X-Ray Scattering Measurements to Compute the Persistence Length of a Protein ER/K alpha-Helix

DEFF Research Database (Denmark)

Sivaramakrishnan, S.; Sung, J.; Ali, M.

2009-01-01

as a force transducer, rigid spacer, or flexible linker in proteins. In this study, we quantity this flexibility in terms of persistence length, namely the length scale over which it is rigid. We use single-molecule optical trapping and small-angle x-ray scattering, combined with Monte Carlo simulations...

Plasma-assisted atomic layer epitaxial growth of aluminum nitride studied with real time grazing angle small angle x-ray scattering

Energy Technology Data Exchange (ETDEWEB)

Anderson, Virginia R.; Nepal, Neeraj; Johnson, Scooter D.; Robinson, Zachary R.; Nath, Anindya; Kozen, Alexander C.; Qadri, Syed B.; DeMasi, Alexander; Hite, Jennifer K.; Ludwig, Karl F.; Eddy, Charles R.

2017-05-01

Wide bandgap semiconducting nitrides have found wide-spread application as light emitting and laser diodes and are under investigation for further application in optoelectronics, photovoltaics, and efficient power switching technologies. Alloys of the binary semiconductors allow adjustments of the band gap, an important semiconductor material characteristic, which is 6.2 eV for aluminum nitride (AlN), 3.4 eV for gallium nitride, and 0.7 eV for (InN). Currently, the highest quality III-nitride films are deposited by metalorganic chemical vapor deposition and molecular beam epitaxy. Temperatures of 900 °C and higher are required to deposit high quality AlN. Research into depositing III-nitrides with atomic layer epitaxy (ALEp) is ongoing because it is a fabrication friendly technique allowing lower growth temperatures. Because it is a relatively new technique, there is insufficient understanding of the ALEp growth mechanism which will be essential to development of the process. Here, grazing incidence small angle x-ray scattering is employed to observe the evolving behavior of the surface morphology during growth of AlN by ALEp at temperatures from 360 to 480 °C. Increased temperatures of AlN resulted in lower impurities and relatively fewer features with short range correlations.

Investigation of Monodisperse Dendrimeric Polysaccharide Nanoparticle Dispersions Using Small Angle Neutron Scattering

Science.gov (United States)

Atkinson, John; Nickels, Jonathan; Papp-Szabo, Erzsi; Katsaras, John; Dutcher, John

2015-03-01

Phytoglycogen is a highly branched polysaccharide that is very similar to the energy storage molecule glycogen. We have isolated monodisperse phytoglycogen nanoparticles from corn and these particles are attractive for applications in the cosmetic, food and beverage, and biomedical industries. Many of these promising applications are due to the special interaction between the nanoparticles and water, which results in: (1) high solubility; (2) low viscosity and high stability in aqueous dispersions; and (3) a remarkable capacity to sequester and retain water. Our rheology measurements indicate that the nanoparticles behave like hard spheres in water, with the viscosity diverging for concentrations >25% (w/w). Because of this, aqueous suspensions of phytoglycogen provide an ideal platform for detailed testing of theories of colloidal glasses and jamming. To further explore the interaction of the phytoglycogen particles and water, we have performed small angle neutron scattering (SANS) measurements on the Extended Q-Range SANS (EQ-SANS) diffractometer at the Spallation Neutron Source at Oak Ridge National Laboratory. Measurements performed on phytoglycogen dispersions in mixtures of hydrogenated and deuterated water have allowed us to determine the particle size and average particle spacing as a function of the phytoglycogen concentration in the limits of dilute and concentrated dispersions.

Small-angle scattering instruments on a 1 MW long pulse spallation source

Energy Technology Data Exchange (ETDEWEB)

Olah, G.A. [Los Alamos National Lab., Chemical Science and Tehcnology Div., Biosciences and Biotechnology Group, Los aalamos, NM (United States); Hjelm, R.P. [Los Alamos National Lab., Neutron Scattering Center, Los Alamos, NM (United States); Seeger, P.A.

1995-11-01

We have designed and optimized two small-angle neutron scattering instruments for installation at a 1 MW long pulse spallation source. The first of these instruments measures a Q-domain from 0.002 to 0.44 A{sup -1}, and the second instrument from 0.00069-0.17 A{sup -1}, Design characteristics were determined and optimization was done using a Monte Carlo instrument simulation package under development at Los alamos. A performance comparison was made between these instruments with D11 at the ILL by evaluating the scattered intensity and rms resolution for the instrument response function at different Q values for various instrument configurations needed to spn a Q-range of 0.0007-0.44 A{sup -1}. We concluded that the first of these instruments outperforms D11 in both intensity and resolution over most of the Q-domain and that the second is comparable to D11. Comparisons were also made of the performance of the optimized long pulse instruments with different reflectors and with a short pulse source, from which we concluded that there is an optimal moderator-reflector combination, and that a short pulse does not substantially improve the instrument performance. (author) 7 figs., 2 tabs., 9 refs.

Small-angle scattering instruments on a 1 MW long pulse spallation source

International Nuclear Information System (INIS)

Olah, G.A.; Hjelm, R.P.; Seeger, P.A.

1995-01-01

We have designed and optimized two small-angle neutron scattering instruments for installation at a 1 MW long pulse spallation source. The first of these instruments measures a Q-domain from 0.002 to 0.44 A -1 , and the second instrument from 0.00069-0.17 A -1 , Design characteristics were determined and optimization was done using a Monte Carlo instrument simulation package under development at Los alamos. A performance comparison was made between these instruments with D11 at the ILL by evaluating the scattered intensity and rms resolution for the instrument response function at different Q values for various instrument configurations needed to spn a Q-range of 0.0007-0.44 A -1 . We concluded that the first of these instruments outperforms D11 in both intensity and resolution over most of the Q-domain and that the second is comparable to D11. Comparisons were also made of the performance of the optimized long pulse instruments with different reflectors and with a short pulse source, from which we concluded that there is an optimal moderator-reflector combination, and that a short pulse does not substantially improve the instrument performance. (author) 7 figs., 2 tabs., 9 refs

Extraction of the missing low-Q data from small-angle scattering data

International Nuclear Information System (INIS)

Doherty, G.K.; Poland, G.A.

1996-01-01

A new method is presented that recovers the scatter intensity curve at low Q values from small-angle neutron scattering data. The method uses only the measured data, requiring no extrapolation of the scatter curve nor any a priori knowledge of the maximum chord length, radius of gyration or molecular weight of the particle under investigation. It is assumed that the incoherent level would have been extracted from the data in the normal course of events but any errors do not affect the method presented. The distance distribution function of any particle has a restricted extension in real space and any nonzero value beyond the maximum size of the particle is due to the effects of missing data segments and noise on the measured data. The effects due to the missing and noisy data are isolated from the distance distribution of the particle and a suitably scaled template particle is used to fill in the missing distribution data segment. The inverse transform of the new distribution function returns the missing low-Q scatter data and to some extent cancels out the noise. While the method is generally explored using noise-free analytically derived particles, its application to real experimental data is demonstrated. (orig.)

The association effect of human serum albumin under different zinc ion concentrations studied by small angle of neutron scattering

International Nuclear Information System (INIS)

He Jian; Xu Yanping; Yang Tonghua; He Jintian; Li Lianzhi; Zhou Yongqia

1997-01-01

The microscopic parameters of the HSA-Zn 2+ , R g and I(0), are obtained directedly by small angle of neutron scattering (SANS) under different concentrations of zinc ion. Comparing with other relevant experimental results, e.g. equilibrium dialysis, we can determine and distinguish the apparent interactive subsequences into more detailed sub-actions, such as self-association, inter-association, disintegration and deconformation et al., or even certain combination of them, other than some indirect and microscopic results. Results obtained by SANS can qualitatively and readily interpret the characteristics from the viewpoint of microscopic process

Comparison of the Behaviour of Polymers in Supercritical Fluids and Organic Solvents Via Small Angle Neutron Scattering

International Nuclear Information System (INIS)

Melnichenko, Y.B.; Kiran, E.; Heath, K.D.; Salaniwal, S.; Cochran, H.D.; Stamm, M.; Van Hook, W.A.; Wignall, G.D.

1999-01-01

Small-angle neutron scattering has been used to study the effect of temperature and pressure on the phase behavior of semidilute solutions of polymers dissolved in organic and supercritical solvents. Above the theta temperature (To), these systems exhibit a ''good solvent'' domain, where the molecules expand beyond the unperturbed dimensions in both organic solvents and in COZ. However, this transition can be made to occur at a critical ''theta pressure'' (PO) in CO2 and this represents a new concept in the physics of polymer-solvent systems. For T < To, and P < Po, the system enters the ''poor solvent'' domain where diverging concentration fluctuations prevent the chains from collapsing and allow them to maintain their unperturbed dimensions

Changes of creatine kinase structure upon ligand binding as seen by small-angle scattering

Science.gov (United States)

Forstner, Michael; Kriechbaum, Manfred; Laggner, Peter; Wallimann, Theo

1996-09-01

Small-angle X-ray and neutron scattering have been used to investigate structural changes upon binding of individual substrates or a transition state analogue complex (TSAC), consisting of Mg-ADP, creatine and KNO 3 to creatine kinase isoenzymes (dimeric M-CK and octameric Mi-CK) and monomeric arginine kinase (AK). Considerable changes in the shape and the size of the molecules occurred upon binding of Mg-ATP and TSAC, whereas creatine alone had only a small effect. In Mi-CK, the radius of gyration was reduced from 55.6 Å (free enzyme) to 48.9 Å (enzyme + Mg-ATP) and to 48.2 Å (enzyme + TSAC). The experiments performed with M-CK showed similar changes from 28.0 Å (free enzyme) to 25.6 Å (enzyme + Mg-ATP) and to 25.5 Å (enzyme + TSAC). Creatine alone did not lead to significant changes in the radii of gyration, nor did free ATP or ADP. AK showed the same behaviour: a change of the radius of gyration from 21.5 Å (free enzyme) to 19.7 Å (enzyme + MG-ATP), whereas with arginine alone only a minor change could be observed. The primary change in structure as seen with monomeric AK seems to be a magnesium-nucleotide induced domain movement relative to each other, whereas the effect of substrate may be of local order only. In creatine kinase, however, further movements must be involved in the large conformational change.

The tetragonal-monoclinic transformations of zirconia studied by small angle neutron scattering and differential thermal analysis

International Nuclear Information System (INIS)

Li, Z.; Epperson, J.E.; Fang, Y.; Chan, S.K.

1992-08-01

The tetragonal-monoclinic transformations of zirconia have been studied on pristine single crystals and on their cycled crystallites. Two complementary techniques have been used. Small angle neutron scattering experiments were carried out to monitor the degree of completion of a transformation under equilibrium conditions for collections of 20--30 large crystals using the total internal and external surface area as an indicator. Differential thermal analysis experiments were carried out on smaller single-domain crystals of different sizes individually during heating and cooling to measure the rates of latent heat absorption and emission. The investigation establishes the upper limit of stability of the monoclinic phase, the lower limit of stability of the tetragonal phase, and the coexistence temperature between the two phases. The characteristics of the transformations are also inferred from these experiments

Characterisation of creep cavitation damage in a stainless steel pressure vessel using small angle neutron scattering

CERN Document Server

Bouchard, P J; Treimer, W

2002-01-01

Grain-boundary cavitation is the dominant failure mode associated with initiation of reheat cracking, which has been widely observed in austenitic stainless steel pressure vessels operating at temperatures within the creep range (>450 C). Small angle neutron scattering (SANS) experiments at the LLB PAXE instrument (Saclay) and the V12 double-crystal diffractometer of the HMI-BENSC facility (Berlin) are used to characterise cavitation damage (in the size range R=10-2000 nm) in a variety of creep specimens extracted from ex-service plant. Factors that affect the evolution of cavities and the cavity-size distribution are discussed. The results demonstrate that SANS techniques have the potential to quantify the development of creep damage in type-316H stainless steel, and thereby link microstructural damage with ductility-exhaustion models of reheat cracking. (orig.)

X-ray magnetic circular dichroism and small angle neutron scattering studies of thiol capped gold nanoparticles

International Nuclear Information System (INIS)

de la Venta, J.; Bouzas, V.; Pucci, A.; Laguna-Marco, M.A.; Haskel, D.; te Velthuis, S.G.E; Hoffmann, A.; Lal, J.; Bleuel, M.; Ruggeri, G.; de Julian Fernandez, C.; Garcia, M.A.

2009-01-01

X-ray magnetic circular dichroism (XMCD) and Small Angle Neutron Scattering (SANS) measurements were performed on thiol capped Au nanoparticles (NPs) embedded into polyethylene. An XMCD signal of 0.8 · 10 -4 was found at the Au L 3 edge of thiol capped Au NPs embedded in a polyethylene matrix for which Superconducting Quantum Interference Device (SQUID) magnetometry yielded a saturation magnetization, M s , of 0.06 emu/g Au . SANS measurements showed that the 3.2 nm average-diameter nanoparticles are 28% polydispersed, but no detectable SANS magnetic signal was found with the resolution and sensitivity accessible with the neutron experiment. A comparison with previous experiments carried out on Au NPs and multilayers, yield to different values between XMCD signals and magnetization measured by SQUID magnetometer. We discuss the origin of those differences

Fat fraction bias correction using T1 estimates and flip angle mapping.

Science.gov (United States)

Yang, Issac Y; Cui, Yifan; Wiens, Curtis N; Wade, Trevor P; Friesen-Waldner, Lanette J; McKenzie, Charles A

2014-01-01

To develop a new method of reducing T1 bias in proton density fat fraction (PDFF) measured with iterative decomposition of water and fat with echo asymmetry and least-squares estimation (IDEAL). PDFF maps reconstructed from high flip angle IDEAL measurements were simulated and acquired from phantoms and volunteer L4 vertebrae. T1 bias was corrected using a priori T1 values for water and fat, both with and without flip angle correction. Signal-to-noise ratio (SNR) maps were used to measure precision of the reconstructed PDFF maps. PDFF measurements acquired using small flip angles were then compared to both sets of corrected large flip angle measurements for accuracy and precision. Simulations show similar results in PDFF error between small flip angle measurements and corrected large flip angle measurements as long as T1 estimates were within one standard deviation from the true value. Compared to low flip angle measurements, phantom and in vivo measurements demonstrate better precision and accuracy in PDFF measurements if images were acquired at a high flip angle, with T1 bias corrected using T1 estimates and flip angle mapping. T1 bias correction of large flip angle acquisitions using estimated T1 values with flip angle mapping yields fat fraction measurements of similar accuracy and superior precision compared to low flip angle acquisitions. Copyright © 2013 Wiley Periodicals, Inc.

An Assessment of Critical Dimension Small Angle X-ray Scattering Metrology for Advanced Semiconductor Manufacturing

Energy Technology Data Exchange (ETDEWEB)

Settens, Charles M. [State Univ. of New York (SUNY), Albany, NY (United States)

2015-01-01

Simultaneous migration of planar transistors to FinFET architectures, the introduction of a plurality of materials to ensure suitable electrical characteristics, and the establishment of reliable multiple patterning lithography schemes to pattern sub-10 nm feature sizes imposes formidable challenges to current in-line dimensional metrologies. Because the shape of a FinFET channel cross-section immediately influences the electrical characteristics, the evaluation of 3D device structures requires measurement of parameters beyond traditional critical dimension (CD), including their sidewall angles, top corner rounding and footing, roughness, recesses and undercuts at single nanometer dimensions; thus, metrologies require sub-nm and approaching atomic level measurement uncertainty. Synchrotron critical dimension small angle X-ray scattering (CD-SAXS) has unique capabilities to non-destructively monitor the cross-section shape of surface structures with single nanometer uncertainty and can perform overlay metrology to sub-nm uncertainty. In this dissertation, we perform a systematic experimental investigation using CD-SAXS metrology on a hierarchy of semiconductor 3D device architectures including, high-aspect-ratio contact holes, H2 annealed Si fins, and a series of grating type samples at multiple points along a FinFET fabrication process increasing in structural intricacy and ending with fully fabricated FinFET. Comparative studies between CD-SAXS metrology and other relevant semiconductor dimensional metrologies, particularly CDSEM, CD-AFM and TEM are used to determine physical limits of CD-SAXS approach for advanced semiconductor samples. CD-SAXS experimental tradeoffs, advice for model-dependent analysis and thoughts on the compatibility with a semiconductor manufacturing environment are discussed.

Spin waves in full-polarized state of Dzyaloshinskii-Moriya helimagnets: Small-angle neutron scattering study

Science.gov (United States)

Grigoriev, S. V.; Sukhanov, A. S.; Altynbaev, E. V.; Siegfried, S.-A.; Heinemann, A.; Kizhe, P.; Maleyev, S. V.

2015-12-01

We develop the technique to study the spin-wave dynamics of the full-polarized state of the Dzyaloshinskii-Moriya helimagnets by polarized small-angle neutron scattering. We have experimentally proven that the spin-waves dispersion in this state has the anisotropic form. We show that the neutron scattering image displays a circle with a certain radius which is centered at the momentum transfer corresponding to the helix wave vector in helimagnetic phase ks, which is oriented along the applied magnetic field H . The radius of this circle is directly related to the spin-wave stiffness of this system. This scattering depends on the neutron polarization showing the one-handed nature of the spin waves in Dzyaloshinskii-Moriya helimagnets in the full-polarized phase. We show that the spin-wave stiffness A for MnSi helimagnet decreased twice as the temperature increases from zero to the critical temperature Tc.

Ray-tracing studies for a whole-viewing-angle retroreflector

International Nuclear Information System (INIS)

Yang, B.; Friedsam, H.

2000-01-01

The APS Survey and Alignment team uses LEICA laser trackers for the majority of their alignment tasks. These instruments utilize several different retroreflectors for tracking the path of the laser interferometer. Currently in use are open-air corner cubes with an acceptance angle of ±20 degree, corner cube prisms with an acceptance angle of ±50degree, and a Cat's eye with an acceptance angle of ±60degree. Best measurement results can be achieved by using an open-air corner cube that eliminates the need for the laser beam to travel through a different medium before it returns to the instrument detector. However, the trade off is a small acceptance angle. In order to overcome the limitations of the small acceptance angles, Takatsuji et al. has proposed the creation of a full-viewing-angle retroreflector. Based on the notion that the radius R 1 of a common Cat's eye is proportional to R 2 , one can write: R 1 = (n minus 1)R 2 . In the case that n, the refractive index of glass, equals 2, the radii R 1 and R 2 are identical, and one can create a solid sphere Cat's eye. This design has the advantages that no adhesives are used to bond the two hemispheres together, misalignments between the hemispheres are not an issue, and most importantly, larger acceptance angles are possible. This paper shows the results of their ray tracing calculations characterizing the geometrical optics

Small-angle x-ray scattering investigation of the solution structure of troponin C

International Nuclear Information System (INIS)

Hubbard, S.R.; Hodgson, K.O.; Doniach, S.

1988-01-01

X-ray crystallographic studies of troponin C have revealed a novel protein structure consisting of two globular domains, each containing two Ca 2+ -binding sites, connected via a nine-turn alpha-helix, three turns of which are fully exposed to solvent. Since the crystals were grown at pH approximately 5, it is of interest to determine whether this structure is applicable to the protein in solution under physiological conditions. We have used small-angle x-ray scattering to examine the solution structure of troponin C at pH 6.8 and the effect of Ca 2+ on the structure. The scattering data are consistent with an elongated structure in solution with a radius of gyration of approximately 23.0 A, which is quite comparable to that computed for the crystal structure. The experimental scattering profile and the scattering profile computed from the crystal structure coordinates do, however, exhibit differences at the 40-A level. A weak Ca 2+ -facilitated dimerization of troponin C was observed. The data rule out large Ca 2+ -induced structural changes, indicating rather that the molecule with Ca 2+ bound is only slightly more compact than the Ca 2+ -free molecule

Small Angle Neutron Scattering (SANS) characterization of electrically conducting polyaniline nanofiber/polyimide nanocomposites

Energy Technology Data Exchange (ETDEWEB)

Hopkins, Alan R., E-mail: alan.r.hopkins@aero.org [Aerospace Corporation, Space Materials Lab, Micro/Nano Technology Dept, Polymers Section, M2/242, Los Angeles, CA 90009-2957 (United States); Tomczak, Sandra J. [AFRL/RZSM Materials Application Branch, Space and Missile Propulsion Division 10 East Saturn Blvd., Bldg. 8451, Edwards Air Force Base, CA 93524 (United States); Vij, Vandana [ERC. Inc., AFRL/PRSM, Edwards AFB, CA (United States); Jackson, Andrew J. [National Institute of Standards and Technology (NIST) Center for Neutron Research, 100 Bureau Drive, Stop 6102, Gaithersburg, MD 20899-6102 (United States)

2011-12-30

Nanocomposites of polyaniline nanofibers and polyimide were fabricated and studied using small angle neutron scattering (SANS). The immiscible nature of the conformationally dissimilar polyaniline nanofiber and polyimide host is established by a series of experiments involving neutron scattering. Based on these techniques, we conclude that the crystal structure of the polyimides is not disrupted, and that there is no mixing between the two components on a molecular level. The morphology of the conducting salt component was analyzed by SANS data and was treated by two common models: Debye-Bueche (D-B) and inverse power law (IPL). Due to deviations in the linear curve fitting over a large scattering range, neither the D-B nor the IPL model could be used to characterize the size and shape of all PANI-0.5-CSA (polyaniline camphor sulfonic acid doped polymer)/polyimide blend systems. At 1 and 2% concentration, the D-B model suggested salt domains between 20 and 70 A with fractal geometries implied by the IPL model. As salt concentrations increased to 5%, the structures were observed to change, but there is no simple structural model that provides a suitable basis for comparison.

Crystal Structures and Small-angle X-ray Scattering Analysis of UDP-galactopyranose Mutase from the Pathogenic Fungus Aspergillus fumigatus

Energy Technology Data Exchange (ETDEWEB)

Dhatwalia, Richa; Singh, Harkewal; Oppenheimer, Michelle; Karr, Dale B.; Nix, Jay C.; Sobrado, Pablo; Tanner, John J. (LBNL); (Missouri); (VPI)

2015-10-15

UDP-galactopyranose mutase (UGM) is a flavoenzyme that catalyzes the conversion of UDP-galactopyranose to UDP-galactofuranose, which is a central reaction in galactofuranose biosynthesis. Galactofuranose has never been found in humans but is an essential building block of the cell wall and extracellular matrix of many bacteria, fungi, and protozoa. The importance of UGM for the viability of many pathogens and its absence in humans make UGM a potential drug target. Here we report the first crystal structures and small-angle x-ray scattering data for UGM from the fungus Aspergillus fumigatus, the causative agent of aspergillosis. The structures reveal that Aspergillus UGM has several extra secondary and tertiary structural elements that are not found in bacterial UGMs yet are important for substrate recognition and oligomerization. Small-angle x-ray scattering data show that Aspergillus UGM forms a tetramer in solution, which is unprecedented for UGMs. The binding of UDP or the substrate induces profound conformational changes in the enzyme. Two loops on opposite sides of the active site move toward each other by over 10 {angstrom} to cover the substrate and create a closed active site. The degree of substrate-induced conformational change exceeds that of bacterial UGMs and is a direct consequence of the unique quaternary structure of Aspergillus UGM. Galactopyranose binds at the re face of the FAD isoalloxazine with the anomeric carbon atom poised for nucleophilic attack by the FAD N5 atom. The structural data provide new insight into substrate recognition and the catalytic mechanism and thus will aid inhibitor design.

Modified Angle's Classification for Primary Dentition.

Science.gov (United States)

Chandranee, Kaushik Narendra; Chandranee, Narendra Jayantilal; Nagpal, Devendra; Lamba, Gagandeep; Choudhari, Purva; Hotwani, Kavita

2017-01-01

This study aims to propose a modification of Angle's classification for primary dentition and to assess its applicability in children from Central India, Nagpur. Modification in Angle's classification has been proposed for application in primary dentition. Small roman numbers i/ii/iii are used for primary dentition notation to represent Angle's Class I/II/III molar relationships as in permanent dentition, respectively. To assess applicability of modified Angle's classification a cross-sectional preschool 2000 children population from central India; 3-6 years of age residing in Nagpur metropolitan city of Maharashtra state were selected randomly as per the inclusion and exclusion criteria. Majority 93.35% children were found to have bilateral Class i followed by 2.5% bilateral Class ii and 0.2% bilateral half cusp Class iii molar relationships as per the modified Angle's classification for primary dentition. About 3.75% children had various combinations of Class ii relationships and 0.2% children were having Class iii subdivision relationship. Modification of Angle's classification for application in primary dentition has been proposed. A cross-sectional investigation using new classification revealed various 6.25% Class ii and 0.4% Class iii molar relationships cases in preschool children population in a metropolitan city of Nagpur. Application of the modified Angle's classification to other population groups is warranted to validate its routine application in clinical pediatric dentistry.

Small angle, quasielastic and inelastic neutron scattering from 0.85AgPO3-0.15PbI2 glass

International Nuclear Information System (INIS)

Malugani, J.P.; Tachez, M.; Mercier, R.

1987-01-01

A small angle neutron scattering (SANS) experiment and a quasielastic neutron scattering (QENS) experiment were performed on the fast ionic conductor 0.85AgPO 3 -0.15PbI 2 , which is a vitreous electrolyte. The SANS data show that the scattering obeys Guinier's law for Q -2 A; dispersed heterogeneities are present in the glass with a mean radius of gyration of 20 A. The QENS spectra show a quasielastic broadening of the elastic peak and a long tail up to 40 meV which is due to an inelastic distribution. The results seem to confirm the hypothesis on the structure of this glass: small 'clusters' of AgI with tetrahedral coordination are dispersed in the AgPO 3 host glass. In order to build these clusters, an exchange between Ag + and Pb 2+ is proposed. 18 refs.; 6 figs.; 2 tabs

Long-term complications following tibial plateau levelling osteotomy in small dogs with tibial plateau angles > 30°.

Science.gov (United States)

Knight, Rebekah; Danielski, Alan

2018-04-21

Tibial plateau levelling osteotomy (TPLO) is commonly performed for surgical management of cranial cruciate ligament (CCL) disease. It has been suggested that small dogs may have steeper tibial plateau angles (TPAs) than large dogs, which has been associated with increased complication rates after TPLO. A retrospective study was performed to assess the rate and nature of long-term complications following TPLO in small dogs with TPAs>30°. Medical records were reviewed for dogs with TPAs>30° treated for CCL rupture by TPLO with a 2.0 mm plate over a five-year period. Radiographs were assessed to determine TPA, postoperative tibial tuberosity width and to identify any complication. Up-to-date medical records were obtained from the referring veterinary surgeon and any complications in the year after surgery were recorded. The effects of different variables on complication rate were assessed using logistic regression analysis. Minor complications were reported in 22.7 per cent of cases. This is similar to or lower than previously reported complication rates for osteotomy techniques in small dogs and dogs with steep TPAs. A smaller postoperative TPA was the only variable significantly associated with an increased complication rate. No major complications were identified. © British Veterinary Association (unless otherwise stated in the text of the article) 2018. All rights reserved. No commercial use is permitted unless otherwise expressly granted.

Joint small-angle X-ray and neutron scattering data analysis of asymmetric lipid vesicles

International Nuclear Information System (INIS)

Eicher, Barbara; Heberle, Frederick A.; Marquardt, Drew T.

2017-01-01

Low- and high-resolution models describing the internal transbilayer structure of asymmetric lipid vesicles have been developed. These models can be used for the joint analysis of small-angle neutron and X-ray scattering data. The models describe the underlying scattering length density/electron density profiles either in terms of slabs or through the so-called scattering density profile, previously applied to symmetric lipid vesicles. Both models yield structural details of asymmetric membranes, such as the individual area per lipid, and the hydrocarbon thickness of the inner and outer bilayer leaflets. The scattering density profile model, however, comes at a cost of increased computational effort but results in greater structural resolution, showing a slightly lower packing of lipids in the outer bilayer leaflet of ~120 nm diameter palmitoyloleoyl phosphatidylcholine (POPC) vesicles, compared to the inner leaflet. Here, analysis of asymmetric dipalmitoyl phosphatidylcholine/POPC vesicles did not reveal evidence of transbilayer coupling between the inner and outer leaflets at 323 K,i.e.above the melting transition temperature of the two lipids.

The small angle x-ray scattering of globular proteins in solution during heat denaturation

Science.gov (United States)

Banuelos, Jose; Urquidi, Jacob

2008-10-01

The ability of proteins to change their conformation in response to changes in their environment has consequences in biological processes like metabolism, chemical regulation in cells, and is believed to play a role in the onset of several neurodegenerative diseases. Factors such as a change in temperature, pressure, and the introduction of ions into the aqueous environment of a protein can give rise to the folding/unfolding of a protein. As a protein unfolds, the ratio of nonpolar to polar groups exposed to water changes, affecting a protein's thermodynamic properties. Using small angle x-ray scattering (SAXS), we are currently studying the intermediate protein conformations that arise during the folding/unfolding process as a function of temperature for five globular proteins. Trends in the observed intermediate structures of these globular proteins, along with correlations with data on protein thermodynamics may help elucidate shared characteristics between all proteins in the folding/unfolding process. Experimental design considerations will be discussed and preliminary results for some of these systems will be presented.

Scanning of Adsorption Hysteresis In Situ with Small Angle X-Ray Scattering.

Directory of Open Access Journals (Sweden)

Athanasios Ch Mitropoulos

Full Text Available Everett's theorem-6 of the domain theory was examined by conducting adsorption in situ with small angle x-ray scattering (SAXS supplemented by the contrast matching technique. The study focuses on the spectrum differences of a point to which the system arrives from different scanning paths. It is noted that according to this theorem at a common point the system has similar macroscopic properties. Furthermore it was examined the memory string of the system. We concluded that opposite to theorem-6: a at a common point the system can reach in a finite (not an infinite number of ways, b a correction for the thickness of the adsorbed film prior to capillary condensation is necessary, and c the scattering curves although at high-Q values coincide, at low-Q values are different indicating different microscopic states. That is, at a common point the system holds different metastable states sustained by hysteresis effects. These metastable states are the ones which highlight the way of a system back to a return point memory (RPM. Entering the hysteresis loop from different RPMs different histories are implanted to the paths toward the common point. Although in general the memory points refer to relaxation phenomena, they also constitute a characteristic feature of capillary condensation. Analogies of the no-passing rule and the adiabaticity assumption in the frame of adsorption hysteresis are discussed.

Scanning of Adsorption Hysteresis In Situ with Small Angle X-Ray Scattering

Science.gov (United States)

Mitropoulos, Athanasios Ch.; Favvas, Evangelos P.; Stefanopoulos, Konstantinos L.; Vansant, Etienne F.

2016-01-01

Everett’s theorem-6 of the domain theory was examined by conducting adsorption in situ with small angle x-ray scattering (SAXS) supplemented by the contrast matching technique. The study focuses on the spectrum differences of a point to which the system arrives from different scanning paths. It is noted that according to this theorem at a common point the system has similar macroscopic properties. Furthermore it was examined the memory string of the system. We concluded that opposite to theorem-6: a) at a common point the system can reach in a finite (not an infinite) number of ways, b) a correction for the thickness of the adsorbed film prior to capillary condensation is necessary, and c) the scattering curves although at high-Q values coincide, at low-Q values are different indicating different microscopic states. That is, at a common point the system holds different metastable states sustained by hysteresis effects. These metastable states are the ones which highlight the way of a system back to a return point memory (RPM). Entering the hysteresis loop from different RPMs different histories are implanted to the paths toward the common point. Although in general the memory points refer to relaxation phenomena, they also constitute a characteristic feature of capillary condensation. Analogies of the no-passing rule and the adiabaticity assumption in the frame of adsorption hysteresis are discussed. PMID:27741263

Optical fibre angle sensor used in MEMS

International Nuclear Information System (INIS)

Golebiowski, J; Milcarz, Sz; Rybak, M

2014-01-01

There is a need for displacement and angle measurements in many movable MEMS structures. The use of fibre optical sensors helps to measure micrometre displacements and small rotation angles. Advantages of this type of transducers are their simple design, high precision of processing, low costs and ability of a non-contact measurement. The study shows an analysis of a fibre-optic intensity sensor used for MEMS movable structure rotation angle measurement. An intensity of the light in the photodetector is basically dependent on a distance between a reflecting surface and a head surface of the fibre transmitting arm, and the deflection angle. Experimental tests were made for PMMA 980/1000 plastic fibres, Θ NA =33°. The study shows both analytical and practical results. It proves that calculated and experimental characteristics for the analysed transducers are similar.

Measurement of the running of the QED coupling in small-angle Bhabha scattering at LEP

CERN Document Server

Abbiendi, G.; Akesson, P.F.; Alexander, G.; Anagnostou, G.; Anderson, K.J.; Asai, S.; Axen, D.; Bailey, I.; Barberio, E.; Barillari, T.; Barlow, R.J.; Batley, R.J.; Bechtle, P.; Behnke, T.; Bell, Kenneth Watson; Bell, P.J.; Bella, G.; Bellerive, A.; Benelli, G.; Bethke, S.; Biebel, O.; Boeriu, O.; Bock, P.; Boutemeur, M.; Braibant, S.; Brown, Robert M.; Burckhart, H.J.; Campana, S.; Capiluppi, P.; Carnegie, R.K.; Carter, A.A.; Carter, J.R.; Chang, C.Y.; Charlton, D.G.; Ciocca, C.; Csilling, A.; Cuffiani, M.; Dado, S.; Dallavalle, G.M.; De Roeck, A.; De Wolf, E.A.; Desch, K.; Dienes, B.; Dubbert, J.; Duchovni, E.; Duckeck, G.; Duerdoth, I.P.; Etzion, E.; Fabbri, F.; Ferrari, P.; Fiedler, F.; Fleck, I.; Ford, M.; Frey, A.; Gagnon, P.; Gary, John William; Geich-Gimbel, C.; Giacomelli, G.; Giacomelli, P.; Giacomelli, R.; Giunta, Marina; Goldberg, J.; Gross, E.; Grunhaus, J.; Gruwe, M.; Gunther, P.O.; Gupta, A.; Hajdu, C.; Hamann, M.; Hanson, G.G.; Harel, A.; Hauschild, M.; Hawkes, C.M.; Hawkings, R.; Hemingway, R.J.; Herten, G.; Heuer, R.D.; Hill, J.C.; Horvath, D.; Igo-Kemenes, P.; Ishii, K.; Jeremie, H.; Jovanovic, P.; Junk, T.R.; Kanzaki, J.; Karlen, D.; Kawagoe, K.; Kawamoto, T.; Keeler, R.K.; Kellogg, R.G.; Kennedy, B.W.; Kluth, S.; Kobayashi, T.; Kobel, M.; Komamiya, S.; Kramer, T.; Krieger, P.; von Krogh, J.; Kuhl, T.; Kupper, M.; Lafferty, G.D.; Landsman, H.; Lanske, D.; Lellouch, D.; Lettso, J.; Levinson, L.; Lillich, J.; Lloyd, S.L.; Loebinger, F.K.; Lu, J.; Ludwig, A.; Ludwig, J.; Mader, W.; Marcellini, S.; Martin, A.J.; Mashimo, T.; Mattig, Peter; McKenna, J.; McPherson, R.A.; Meijers, F.; Menges, W.; Merritt, F.S.; Mes, H.; Meyer, Niels T.; Michelini, A.; Mihara, S.; Mikenberg, G.; Miller, D.J.; Mohr, W.; Mori, T.; Mutter, A.; Nagai, K.; Nakamura, I.; Nanjo, H.; Neal, H.A.; Nisius, R.; ONeale, S.W.; Oh, A.; Oreglia, M.J.; Orito, S.; Pahl, C.; Pasztor, G.; Pater, J.R.; Pilcher, J.E.; Pinfold, J.; Plane, David E.; Pooth, O.; Przybycien, M.; Quadt, A.; Rabbertz, K.; Rembser, C.; Renkel, P.; Roney, J.M.; Runge, K.; Sachs, K.; Saeki, T.; Sarkisyan, E.K.G.; Schaile, A.D.; Schaile, O.; Scharff-Hansen, P.; Schieck, J.; Schorner-Sadenius, T.; Schroder, Matthias; Schumacher, M.; Seuster, R.; Shears, T.G.; Shen, B.C.; Sherwood, P.; Skuja, A.; Smith, A.M.; Sobie, R.; Soldner-Rembold, S.; Spano, F.; Stahl, A.; Strom, David M.; Strohmer, R.; Tarem, S.; Tasevsky, M.; Teuscher, R.; Thomson, M.A.; Torrence, E.; Toya, D.; Tran, P.; Trigger, I.; Trocsanyi, Z.; Tsur, E.; Turner-Watson, M.F.; Ueda, I.; Ujvari, B.; Vollmer, C.F.; Vannerem, P.; Vertesi, R.; Verzocchi, M.; Voss, H.; Vossebeld, J.; Ward, C.P.; Ward, D.R.; Watkins, P.M.; Watson, A.T.; Watson, N.K.; Wells, P.S.; Wengler, T.; Wermes, N.; Wilson, G.W.; Wilson, J.A.; Wolf, G.; Wyatt, T.R.; Yamashita, S.; Zer-Zion, D.; Zivkovic, Lidija

2006-01-01

Using the OPAL detector at LEP, the running of the effective QED coupling alpha(t) is measured for space-like momentum transfer through its effect on the angular spectrum of small-angle Bhabha scattering. In an almost ideal QED framework, with very favourable experimental conditions, we obtain: Delta alpha(-6.07GeV^2) - Delta alpha(-1.81GeV^2) = (440 pm 58 pm 43 pm 30) X 10^-5, where the first error is statistical, the second is the experimental systematic and the third is the theoretical uncertainty. This is the strongest direct evidence ever presented that the running of alpha is consistent with Standard Model expectations. The null hypothesis that alpha remains constant within the above interval of -t is excluded with a significance above 5sigma. Similarly, our results are inconsistent at the level of 3sigma with the hypothesis that only leptonic loops contribute to the running, and therefore provide the first clear experimental evidence that hadronic loops also contribute.

X-ray magnetic circular dichroism and small angle neutron scattering studies of thiol capped gold nanoparticles.

Energy Technology Data Exchange (ETDEWEB)

de la Venta, J.; Bouzas, V.; Pucci, A.; Laguna-Marco, M. A.; Haskel, D.; te Velthuis, S. G. E; Hoffmann, A.; Lal, J.; Bleuel, M.; Ruggeri, G.; de Julian Fernandez, C.; Garcia, M. A.; Univ.Complutense de Madrid; Inst. de Magnetismo Aplicado; Univ. of Pisa; Lab. di Magnetismo Molecolare

2009-01-01

X-ray magnetic circular dichroism (XMCD) and Small Angle Neutron Scattering (SANS) measurements were performed on thiol capped Au nanoparticles (NPs) embedded into polyethylene. An XMCD signal of 0.8 {center_dot} 10{sup -4} was found at the Au L{sub 3} edge of thiol capped Au NPs embedded in a polyethylene matrix for which Superconducting Quantum Interference Device (SQUID) magnetometry yielded a saturation magnetization, M{sub s}, of 0.06 emu/g{sub Au}. SANS measurements showed that the 3.2 nm average-diameter nanoparticles are 28% polydispersed, but no detectable SANS magnetic signal was found with the resolution and sensitivity accessible with the neutron experiment. A comparison with previous experiments carried out on Au NPs and multilayers, yield to different values between XMCD signals and magnetization measured by SQUID magnetometer. We discuss the origin of those differences.

X-ray magnetic circular dichroism and small angle neutron scattering study of thiol capped gold nanoparticles.

Energy Technology Data Exchange (ETDEWEB)

de la Venta, J.; Bouzas, V.; Pucci, A.; Laguna-Marco, M. A.; Haskel, D.; Pinel, E. F.; te Velthuis, S. G. E.; Hoffmann, A.; Lal, J.; Bleuel, M.; Ruggeri, G.; de Julian, C.; Garcia, M. A.; Univ. Complutense de Madrid; Inst. de Magnetismo Aplicado UCM; Univ. Pisa; Univ. di Padova

2009-11-01

X-ray magnetic circular dichroism (XMCD) and Small Angle Neutron Scattering (SANS) measurements were performed on thiol capped Au nanoparticles (NPs) embedded into polyethylene. An XMCD signal of 0.8 {center_dot} 10{sup -4} was found at the Au L{sub 3} edge of thiol capped Au NPs embedded in a polyethylene matrix for which Superconducting Quantum Interference Device (SQUID) magnetometry yielded a saturation magnetization, M{sub s}, of 0.06 emu/g{sub Au}. SANS measurements showed that the 3.2 nm average-diameter nanoparticles are 28% polydispersed, but no detectable SANS magnetic signal was found with the resolution and sensitivity accessible with the neutron experiment. A comparison with previous experiments carried out on Au NPs and multilayers, yield to different values between XMCD signals and magnetization measured by SQUID magnetometer. We discuss the origin of those differences.

The measurement of antiproton-proton total cross sections and small-angle elastic scattering at low momentum

International Nuclear Information System (INIS)

Linssen, L.H.A.J.

1986-01-01

In this thesis two low-momentum antiproton-proton (anti pp) experiments are described. The first one is a set of 24 high statistics anti pp total cross section measurements as a function of the incoming antiproton momentum between p=388 MeV/c and p=599 MeV/c. These measurements simultaneously yield the charge exchange cross section (anti pp → anti nn). The second one comprises two high statistics anti pp small-angle elastic scattering measurements at p=233 MeV/c and p=272 MeV/c. The measurements were carried out using the high quality antiproton beam extracted from the Low Energy Antiproton Ring (LEAR) at CERN. The physics motivation for these experiments is a search for anti pp resonances or bound states on one hand, and a detailed study of the anti pp interaction on the other hand. (orig.)

The applications of small-angle X-ray scattering in studying nano-scaled polyoxometalate clusters in solutions

Science.gov (United States)

Li, Mu; Zhang, Mingxin; Wang, Weiyu; Cheng, Stephen Z. D.; Yin, Panchao

2018-05-01

Nano-scaled polyoxometalates (POMs) clusters with sizes ranging from 1 to 10 nm attract tremendous attention and have been extensively studied due to POMs' fascinating structural characteristics and prospects for wide-ranging applications. As a unique class of nanoparticles with well-defined structural topologies and monodispersed masses, the structures and properties of POMs in both bulk state and solutions have been explored with several well-developed protocols. Small-angle X-ray scattering (SAXS) technique, as a powerful tool for studying polymers and nanoparticles, has been recently extended to the investigating of solution behaviors of POMs. In this mini-review, the general principle and typical experimental procedures of SAXS are illustrated first. The applications of SAXS in characterizing POMs' morphology, counterion distribution around POMs, and short-range interactions among POMs in solutions are highlighted. [Figure not available: see fulltext.

Ultra-small-angle X-ray scattering characterization of diesel/gasoline soot: sizes and particle-packing conditions

Science.gov (United States)

Kameya, Yuki; Lee, Kyeong O.

2013-10-01

Regulations on particulate emissions from internal combustion engines tend to become more stringent, accordingly the importance of particulate filters in the after-treatment system has been increasing. In this work, the applicability of ultra-small-angle X-ray scattering (USAXS) to diesel soot cake and gasoline soot was investigated. Gasoline-direct-injection engine soot was collected at different fuel injection timings. The unified fits method was applied to analyze the resultant scattering curves. The validity of analysis was supported by comparing with carbon black and taking the sample images using a transmission electron microscope, which revealed that the primary particle size ranged from 20 to 55 nm. In addition, the effects of particle-packing conditions on the USAXS measurement were demonstrated by using samples suspended in acetone. Then, the investigation was extended to characterization of diesel soot cake deposited on a diesel particulate filter (DPF). Diesel soot was trapped on a small piece of DPF at different deposition conditions which were specified using the Peclet number. The dependence of scattering curve on soot-deposition conditions was demonstrated. To support the interpretation of the USAXS results, soot cake samples were observed using a scanning electron microscope and the influence of particle-packing conditions on scattering curve was discussed.

Ultra-small-angle X-ray scattering characterization of diesel/gasoline soot: sizes and particle-packing conditions

International Nuclear Information System (INIS)

Kameya, Yuki; Lee, Kyeong O.

2013-01-01

Regulations on particulate emissions from internal combustion engines tend to become more stringent, accordingly the importance of particulate filters in the after-treatment system has been increasing. In this work, the applicability of ultra-small-angle X-ray scattering (USAXS) to diesel soot cake and gasoline soot was investigated. Gasoline-direct-injection engine soot was collected at different fuel injection timings. The unified fits method was applied to analyze the resultant scattering curves. The validity of analysis was supported by comparing with carbon black and taking the sample images using a transmission electron microscope, which revealed that the primary particle size ranged from 20 to 55 nm. In addition, the effects of particle-packing conditions on the USAXS measurement were demonstrated by using samples suspended in acetone. Then, the investigation was extended to characterization of diesel soot cake deposited on a diesel particulate filter (DPF). Diesel soot was trapped on a small piece of DPF at different deposition conditions which were specified using the Peclet number. The dependence of scattering curve on soot-deposition conditions was demonstrated. To support the interpretation of the USAXS results, soot cake samples were observed using a scanning electron microscope and the influence of particle-packing conditions on scattering curve was discussed

Ultra-small-angle X-ray scattering characterization of diesel/gasoline soot: sizes and particle-packing conditions

Energy Technology Data Exchange (ETDEWEB)

Kameya, Yuki, E-mail: ykameya@anl.gov; Lee, Kyeong O. [Argonne National Laboratory, Center for Transportation Research (United States)

2013-10-15

Regulations on particulate emissions from internal combustion engines tend to become more stringent, accordingly the importance of particulate filters in the after-treatment system has been increasing. In this work, the applicability of ultra-small-angle X-ray scattering (USAXS) to diesel soot cake and gasoline soot was investigated. Gasoline-direct-injection engine soot was collected at different fuel injection timings. The unified fits method was applied to analyze the resultant scattering curves. The validity of analysis was supported by comparing with carbon black and taking the sample images using a transmission electron microscope, which revealed that the primary particle size ranged from 20 to 55 nm. In addition, the effects of particle-packing conditions on the USAXS measurement were demonstrated by using samples suspended in acetone. Then, the investigation was extended to characterization of diesel soot cake deposited on a diesel particulate filter (DPF). Diesel soot was trapped on a small piece of DPF at different deposition conditions which were specified using the Peclet number. The dependence of scattering curve on soot-deposition conditions was demonstrated. To support the interpretation of the USAXS results, soot cake samples were observed using a scanning electron microscope and the influence of particle-packing conditions on scattering curve was discussed.

SCT: a suite of programs for comparing atomistic models with small-angle scattering data.

Science.gov (United States)

Wright, David W; Perkins, Stephen J

2015-06-01

Small-angle X-ray and neutron scattering techniques characterize proteins in solution and complement high-resolution structural studies. They are of particular utility when large proteins cannot be crystallized or when the structure is altered by solution conditions. Atomistic models of the averaged structure can be generated through constrained modelling, a technique in which known domain or subunit structures are combined with linker models to produce candidate global conformations. By randomizing the configuration adopted by the different elements of the model, thousands of candidate structures are produced. Next, theoretical scattering curves are generated for each model for trial-and-error fits to the experimental data. From these, a small family of best-fit models is identified. In order to facilitate both the computation of theoretical scattering curves from atomistic models and their comparison with experiment, the SCT suite of tools was developed. SCT also includes programs that provide sequence-based estimates of protein volume (either incorporating hydration or not) and add a hydration layer to models for X-ray scattering modelling. The original SCT software, written in Fortran, resulted in the first atomistic scattering structures to be deposited in the Protein Data Bank, and 77 structures for antibodies, complement proteins and anionic oligosaccharides were determined between 1998 and 2014. For the first time, this software is publicly available, alongside an easier-to-use reimplementation of the same algorithms in Python. Both versions of SCT have been released as open-source software under the Apache 2 license and are available for download from https://github.com/dww100/sct.

Time-of-flight small-angle-neutron-scattering data reduction and analysis at LANSCE (Los Alamos Neutron Scattering Center) with program SMR

International Nuclear Information System (INIS)

Hjelm, R.P. Jr.; Seegar, P.A.

1989-01-01

A user-friendly, integrated system, SMR, for the display, reduction and analysis of data from time-of-flight small-angle neutron diffractometers is described. Its purpose is to provide facilities for data display and assessment and to provide these facilities in near real time. This allows the results of each scattering measurement to be available almost immediately, and enables the experimenter to use the results of a measurement as a basis for other measurements in the same instrument allocation. 8 refs., 11 figs

Emission-angle and polarization-rotation effects in the lensed CMB

Energy Technology Data Exchange (ETDEWEB)

Lewis, Antony [Department of Physics and Astronomy, University of Sussex, Brighton BN1 9QH (United Kingdom); Hall, Alex [Institute for Astronomy, University of Edinburgh, Royal Observatory, Blackford Hill, Edinburgh, EH9 3HJ (United Kingdom); Challinor, Anthony, E-mail: antony@cosmologist.info, E-mail: ahall@roe.ac.uk, E-mail: a.d.challinor@ast.cam.ac.uk [Institute of Astronomy and Kavli Institute for Cosmology, Madingley Road, Cambridge, CB3 0HA (United Kingdom)

2017-08-01

Lensing of the CMB is an important effect, and is usually modelled by remapping the unlensed CMB fields by a lensing deflection. However the lensing deflections also change the photon path so that the emission angle is no longer orthogonal to the background last-scattering surface. We give the first calculation of the emission-angle corrections to the standard lensing approximation from dipole (Doppler) sources for temperature and quadrupole sources for temperature and polarization. We show that while the corrections are negligible for the temperature and E-mode polarization, additional large-scale B-modes are produced with a white spectrum that dominates those from post-Born field rotation (curl lensing). On large scales about one percent of the total lensing-induced B-mode amplitude is expected to be due to this effect. However, the photon emission angle does remain orthogonal to the perturbed last-scattering surface due to time delay, and half of the large-scale emission-angle B modes cancel with B modes from time delay to give a total contribution of about half a percent. While not important for planned observations, the signal could ultimately limit the ability of delensing to reveal low amplitudes of primordial gravitational waves. We also derive the rotation of polarization due to multiple deflections between emission and observation. The rotation angle is of quadratic order in the deflection angle, and hence negligibly small: polarization typically rotates by less than an arcsecond, orders of magnitude less than a small-scale image rotates due to post-Born field rotation (which is quadratic in the shear). The field-rotation B modes dominate the other effects on small scales.

New developments in the simultaneous measurement system of wide-angle and small-angle x-ray scatterings and vibrational spectra for the static and dynamic analyses of the hierarchical structures of polymer solids

International Nuclear Information System (INIS)

Tashiro, Kohji; Yamamoto, Hiroko; Yoshioka, Taiyo; Ninh, Tran Hai; Shimada, Shigeru; Nakatani, Takeshi; Iwamoto, Hiroyuki; Ohta, Noboru; Masunaga, Hiroyasu

2012-01-01

A simultaneous measurement system of wide-angle X-ray diffraction (WAXD), small-angle X-ray scattering (SAXS) and Raman or transmission-type infrared spectroscopy was developed by us. Its purposes is to clarify the static and dynamic structural changes of polymer materials subjected to the various external condition changes. Some examples described here include the study of the stretch-induced reorientation phenomenon of a-axially-oriented polyethylene, the study of structural change in photo-induced solid-state polymerization reaction of muconic acid ester monomer crystal, the study of the two-stage high-temperature phase transitions of aliphatic nylons, the study of stress-induced crystalline phase transition of an oriented poly(tetramethylene terephthalate) sample and its relation to the higher-order structural change, and the study of structural regularization process of poly(L-lactic acid) in the isothermal crystallization of the meso phase. These case studies in the clarification of hierarchical structural changes of polymer materials have proven that the simultaneous measurement systems can be useful to examine the structural changes in polymer systems. (author)

Small angle neutron scattering studies of the vortex lattice in the UPt₃ mixed state: Direct structural evidence for the B->C transition

DEFF Research Database (Denmark)

Yaron, U.; Gammel, P.L.; Boebinger, G.S.

1997-01-01

Small angle neutron scattering studies of the flux line lattice (FLL) in UPt3 for fields H perpendicular to c provide direct microscopic evidence for the 5 kOe B --> C transition. We find a pronounced maximum in the longitudinal correlation length of the FLL at the transition and an abrupt change...

Direct monitoring of calcium-triggered phase transitions in cubosomes using small-angle X-ray scattering combined with microfluidics

DEFF Research Database (Denmark)

Ghazal, Aghiad; Gontsarik, Mark; Kutter, Jörg P.

2016-01-01

This article introduces a simple microfluidic device that can be combined with synchrotron small-angle X-ray scattering (SAXS) for monitoring dynamic structural transitions. The microfluidic device is a thiol-ene-based system equipped with 125 µm-thick polystyrene windows, which are suitable for ....... The combination of microfluidics with X-ray techniques can be used for investigating protein unfolding, for monitoring the formation of nanoparticles in real time, and for other biomedical and pharmaceutical investigations.......-ray experiments. The device was prepared by soft lithography using elastomeric molds followed by a simple UV-initiated curing step to polymerize the chip material and simultaneously seal the device with the polystyrene windows. The microfluidic device was successfully used to explore the dynamics...

Light Scattering at Various Angles

Science.gov (United States)

Latimer, Paul; Pyle, B. E.

1972-01-01

The Mie theory of scattering is used to provide new information on how changes in particle volume, with no change in dry weight, should influence light scattering for various scattering angles and particle sizes. Many biological cells (e.g., algal cells, erythrocytes) and large subcellular structures (e.g., chloroplasts, mitochondria) in suspension undergo this type of reversible volume change, a change which is related to changes in the rates of cellular processes. A previous study examined the effects of such volume changes on total scattering. In this paper scattering at 10° is found to follow total scattering closely, but scattering at 45°, 90°, 135°, and 170° behaves differently. Small volume changes can cause very large observable changes in large angle scattering if the sample particles are uniform in size; however, the natural particle size heterogeneity of most samples would mask this effect. For heterogeneous samples of most particle size ranges, particle shrink-age is found to increase large angle scattering. PMID:4556610

Numerical exploration of non-axisymmetric divertor closure in the small angle slot (SAS) divertor at DIII-D

Science.gov (United States)

Frerichs, Heinke; Schmitz, Oliver; Covele, Brent; Guo, Houyang; Hill, David; Feng, Yuhe

2017-10-01

In the Small Angle Slot (SAS) divertor in DIII-D, the combination of misaligned slot structure and non-axisymmetric perturbations to the magnetic field causes the strike point to vary radially along the divertor slot and even leave it at some toroidal locations. This effect essentially introduces an opening in the divertor slot from where recycling neutrals can easily escape, and thereby degrade performance of the slot divertor. This effect has been approximated by a finite gap in the divertor baffle. Simulations with EMC3-EIRENE show that a toroidally localized loss of divertor closure can result in non-axisymmetric divertor densities and temperatures. This introduces a density window of 10-15% on top of the nominal threshold separatrix density during which a non-axisymmetric onset of local detachment occurs, initially leaving the gap and up to 60 deg beyond that still attached. Conversely, the impact of such toroidally localized divertor perturbations on the toroidal symmetry of midplane separatrix conditions is small. This work has been funded by the U.S. Department of Energy under Early Career Award Grant DE-SC0013911, and Grant DE-FC02-04ER54698.

Neutron spin echo scattering angle measurement (SESAME)

International Nuclear Information System (INIS)

Pynn, R.; Fitzsimmons, M.R.; Fritzsche, H.; Gierlings, M.; Major, J.; Jason, A.

2005-01-01

We describe experiments in which the neutron spin echo technique is used to measure neutron scattering angles. We have implemented the technique, dubbed spin echo scattering angle measurement (SESAME), using thin films of Permalloy electrodeposited on silicon wafers as sources of the magnetic fields within which neutron spins precess. With 30-μm-thick films we resolve neutron scattering angles to about 0.02 deg. with neutrons of 4.66 A wavelength. This allows us to probe correlation lengths up to 200 nm in an application to small angle neutron scattering. We also demonstrate that SESAME can be used to separate specular and diffuse neutron reflection from surfaces at grazing incidence. In both of these cases, SESAME can make measurements at higher neutron intensity than is available with conventional methods because the angular resolution achieved is independent of the divergence of the neutron beam. Finally, we discuss the conditions under which SESAME might be used to probe in-plane structure in thin films and show that the method has advantages for incident neutron angles close to the critical angle because multiple scattering is automatically accounted for