WorldWideScience

Sample records for volcanic gas emission

  1. Monitoring gas emissions can help forecast volcanic eruptions

    Science.gov (United States)

    Kern, Christoph; Maarten de Moor,; Bo Galle,

    2015-01-01

    As magma ascends in active volcanoes, dissolved volatiles partition from melt into a gas phase, rise, and are released into the atmosphere from volcanic vents. The major components of high-temperature volcanic gas are typically water vapor, carbon dioxide, and sulfur dioxide. 

  2. Volcanic gas

    Science.gov (United States)

    McGee, Kenneth A.; Gerlach, Terrance M.

    1995-01-01

    In Roman mythology, Vulcan, the god of fire, was said to have made tools and weapons for the other gods in his workshop at Olympus. Throughout history, volcanoes have frequently been identified with Vulcan and other mythological figures. Scientists now know that the “smoke" from volcanoes, once attributed by poets to be from Vulcan’s forge, is actually volcanic gas naturally released from both active and many inactive volcanoes. The molten rock, or magma, that lies beneath volcanoes and fuels eruptions, contains abundant gases that are released to the surface before, during, and after eruptions. These gases range from relatively benign low-temperature steam to thick hot clouds of choking sulfurous fume jetting from the earth. Water vapor is typically the most abundant volcanic gas, followed by carbon dioxide and sulfur dioxide. Other volcanic gases are hydrogen sulfide, hydrochloric acid, hydrogen, carbon monoxide, hydrofluoric acid, and other trace gases and volatile metals. The concentrations of these gas species can vary considerably from one volcano to the next.

  3. Ground-based and airborne measurements of volcanic gas emissions at White Island in New Zealand

    Science.gov (United States)

    Tirpitz, Jan-Lukas; Poehler, Denis; Bobrowski, Nicole; Christenson, Bruce; Platt, Ulrich

    2017-04-01

    Quantitative understanding of volcanic gas emissions has twofold relevance for nature and society: 1) Variation in gas emission and/or in emitted gas ratios are tracers of the dynamic processes in the volcano interior indicating its activity. 2) Volcanic degassing plays an important role for the Earth's climate, for local sometimes even regional air quality and atmospheric chemistry. In autumn 2015, a campaign to White Island Volcano in New Zealand was organized to perform ground-based as well as airborne in-situ and remote sensing gas measurements of sulfur dioxide (SO2), carbon dioxide (CO2) and bromine monoxide (BrO). For all three gases the ratios and total emission rates were determined in different plume types and ages. An overview over the data will be presented with focus on the two most notable outcomes: 1) The first determination of the BrO/SO2 ratio in the White Island plume and a minimum estimate of the volcano's bromine emission rate; two of many parameters, which are important to assess the impact of volcanic degassing on the atmospheric halogen chemistry. 2) In-situ SO2 data was very successfully recorded with the PITSA, a prototype of a portable and cost-effective optical instrument. It is based on the principle of non-dispersive UV absorption spectroscopy and features different advantages over the customary electrochemical sensors, including a sub second response time, negligible cross sensitivities to other gases, and inherent calibration. The campaign data demonstrates the capabilities and limitations of the PITSA and shows, that it can be well applied as substitute for conventional electrochemical systems.

  4. Automatic semi-continuous accumulation chamber for diffuse gas emissions monitoring in volcanic and non-volcanic areas

    Science.gov (United States)

    Lelli, Matteo; Raco, Brunella; Norelli, Francesco; Virgili, Giorgio; Continanza, Davide

    2016-04-01

    Since various decades the accumulation chamber method is intensively used in monitoring activities of diffuse gas emissions in volcanic areas. Although some improvements have been performed in terms of sensitivity and reproducibility of the detectors, the equipment used for measurement of gas emissions temporal variation usually requires expensive and bulky equipment. The unit described in this work is a low cost, easy to install-and-manage instrument that will make possible the creation of low-cost monitoring networks. The Non-Dispersive Infrared detector used has a concentration range of 0-5% CO2, but the substitution with other detector (range 0-5000 ppm) is possible and very easy. Power supply unit has a 12V, 7Ah battery, which is recharged by a 35W solar panel (equipped with charge regulator). The control unit contains a custom programmed CPU and the remote transmission is assured by a GPRS modem. The chamber is activated by DataLogger unit, using a linear actuator between the closed position (sampling) and closed position (idle). A probe for the measure of soil temperature, soil electrical conductivity, soil volumetric water content, air pressure and air temperature is assembled on the device, which is already arranged for the connection of others external sensors, including an automatic weather station. The automatic station has been tested on the field at Lipari island (Sicily, Italy) during a period of three months, performing CO2 flux measurement (and also weather parameters), each 1 hour. The possibility to measure in semi-continuous mode, and at the same time, the gas fluxes from soil and many external parameters, helps the time series analysis aimed to the identification of gas flux anomalies due to variations in deep system (e.g. onset of volcanic crises) from those triggered by external conditions.

  5. Measurements of the gas emission from Holuhraun volcanic fissure eruption on Iceland, using Scanning DOAS instruments

    Science.gov (United States)

    Galle, Bo; Pfeffer, Melissa; Arellano, Santiago; Bergsson, Baldur; Conde, Vladimir; Barsotti, Sara; Stefansdottir, Gerdur; Ingvarsson, Thorgils; Bergsson, Bergur; Weber, Konradin

    2016-04-01

    On 31 August 2014 a volcanic fissure eruption started at Holuhraun on Iceland. The eruption lasted for 6 months and was by far the strongest source of sulfur dioxide in Europe over the last 230 years, with sustained emission rates exceeding 100 000 ton/day. This gas emission severely affected people within Iceland. Under the scope of the EU-project FUTUREVOLC, a project with 3.5 years duration, aiming at making Iceland a supersite for volcanological research as a European contribution to GEO, a version of the Scanning DOAS instrument that is adapted to high latitudes with low UV radiation and severe meteorological conditions was developed. Since the first day of the eruption several of these novel instruments were monitoring the SO2 emission from the eruption. A lot of work was needed to sustain this operation during the winter at a very remote site and under severe field conditions. At the same time the very high concentrations in the gas plume, in combination with bad meteorological conditions has required the development of novel methods to derive reliable flux estimates. A simple approach to make a first order correction for atmospheric scattering has been applied, as well as filtering of the dataset to remove the data most affected by scattering. Substantial work has also been made to obtain realistic information on plume height and wind speed. The data from these instruments are the only sustained ground-based measurements of this important gas emission event. In this presentation we will discuss the instrumental issues and evaluation procedures and present the latest version of the emission estimates made from our measurements.

  6. Effect of gas emissions from Tianchi volcano (NE China) on environment and its potential volcanic hazards

    Institute of Scientific and Technical Information of China (English)

    GUO; Zhengfu; LIU; Jiaqi; HAN; Jingtai; HE; Huaiyu; DAI; Guoliang; YOU; Haitao

    2006-01-01

    The Tianchi volcano in the Changbai Mountains is located on the boundary between China and North Korea. There are many times of eruptions of the Tianchi volcano during the Holocene. One of its large eruptions occurred around 1000 years ago dated by 14C method and historical records. Composition of products of the largest Tianchi volcanic eruption studied is characterized by comenditic Plinian fallout and unwelded ignimbrite, which are mainly distributed in China and North Korea. Caldera is about 4.4 km long and 3.4 km wide, which had filled with water (e.g. Tianchi Lake). The Tianchi volcanic cone is about 2700 m high above sea level. The Tianchi Lake is located on the summit of the volcanic cone, that is also highest peak of the Changbai Mountains in northeastern China. This study analyzed Cl, F, S and H2O concentrations of melt inclusions in the phenocryst minerals (anorthoclase and quartz) and co-existing matrix glasses using the electron microprobe and estimated environmental effect of Tianchi volcanic gases. The authors proposed a new method to evaluate future eruption of active volcano and estimate potential volcanic hazards based on contents of volatile emissions. Using this method, we made a perspective of future volcanic hazard in this region.

  7. Aborted eruptions at Mt. Etna (Italy) in spring 2007 unveiled by an integrated study of gas emission and volcanic tremor

    Science.gov (United States)

    Falsaperla, S.; Behncke, B.; Giammanco, S.; Neri, M.; Langer, H.; Pecora, E.; Salerno, G.

    2012-04-01

    In spring 2007, a sequence of paroxysmal episodes took place at the Southeast Crater of Mt. Etna, Italy. Eruptive activity, characterised by Strombolian explosions, lava fountains, emission of lava flows and tephra, were all associated with an outstanding increase in the amplitude of volcanic tremor. In periods of quiescence between the eruptive episodes, recurring phases of seismic unrest were observed in forms of small temporary enhancements of the volcanic tremor amplitude, even though none of them culminated in eruptive activity. Here, we present the results of an integrated geophysical and geochemical data analysis encompassing records of volcanic tremor, thermal data, plume SO2 flux and radon over two months. We conclude that between February and April 2007, magma triggered repeated episodes of gas pulses and rock fracturing, but failed to reach the surface. Our multidisciplinary study allowed us to unveil these 'aborted' eruptions by investigating the long-temporal evolution of gas measurements along with seismic radiation. Short-term changes were additionally highlighted using a method of pattern classification based on Kohonen Maps and Fuzzy Clustering applied to volcanic tremor and radon data.

  8. Ground based measurements of the gas emission from the Holuhraun volcanic fissure eruption on Iceland 2014/2015

    Science.gov (United States)

    Galle, Bo; Arellano, Santiago; Conde, Vladimir; Pfeffer, Melissa; Barsotti, Sara; Stefansdottir, Gerður; Bergsson, Baldur; Bergsson, Bergur; Ingvarsson, Thorgils; Weber, Konradin

    2015-04-01

    The since 31 August 2014 ongoing volcanic eruption at Holuhraun on Iceland is by far the strongest source of sulfur dioxide in Europe over the last 230 years with sustained emission rates exceeding 100 000 ton/day. This gas emission severely affects local population and has become a concern also for air traffic. The eruption has in December continued at constant pace for 3.5 months. Three scenarios are envisaged for the future; (1) the eruption stops, (2) the fissure extends under the Vattnajökul glacier and (3) Bardarbunga volcano erupts. The two later scenarios will cause increased gas emission, severe ash emissions and extended flooding. Under the scope of the EU-project FUTUREVOLC, a project with 3.5 years duration, aiming at making Iceland a supersite for volcanological research as a European contribution to GEO, we are developing a version of the Scanning DOAS instrument that is adapted to high latitudes with low UV radiation and severe meteorological conditions. Since the first day of the eruption several of these novel instruments has been monitoring the SO2 emission from the eruption. Data from our instruments are still after 3.5 months the only sustained ground-based monitoring of this gas emission. A lot of work is however needed to sustain this operation at a very remote site and under severe field conditions. At the same time the very high concentrations in the gas plume, in combination with bad meteorological conditions require the development of novel methods to derive reliable flux estimates. In this presentation we will discuss the instrumental issues and present the latest version of the emission estimates made from our measurements.

  9. 'Failed' eruptions revealed by integrated analysis of gas emission and volcanic tremor data at Mt. Etna, Italy

    Science.gov (United States)

    Salerno, G. G.; Falsaperla, S. M.; Behncke, B.; Langer, H. K.; Neri, M.; Giammanco, S.; Pecora, E.; Biale, E.

    2013-12-01

    Mt Etna in Sicily is among the most intensely monitored and studied volcanoes on Earth due to its very frequent activity, and its location in a densely populated area. Through a sophisticated monitoring system run by the Istituto Nazionale di Geofisica e Vulcanologia - Osservatorio Etneo (INGV-OE), scientists are gaining every day and in real time a picture of the state of volcanic activity of Etna. During the spring of 2007, various episodes of paroxysmal activity occurred at the South-East Crater, one of the four summit craters of Mt Etna. These episodes were always associated with a sharp increase in the amplitude of the volcanic tremor as well as changes in the spectral characteristics of this signal. Eruptive activity ranged from strong Strombolian explosions to lava fountains coupled with copious emission of lava flows and tephra. During inter-eruptive periods, recurrent seismic unrest episodes were observed in form of both temporary enhancements of the volcanic tremor amplitude as well as changes of spectral characteristics. These changes often triggered the automatic alert systems in the operation room of the INGV-OE, even though not being followed by manifest eruptive activity at the surface. The influence of man-made or meteorologically induced noise could be ruled out as a cause for the alarms. We therefore performed a multi-parametric analysis of these inter-eruptive periods by integrating seismic volcanic tremor, in-soil radon, plume SO2 flux and thermal data, discussing the potential volcano-dependent source of these episodes. Short-term changes were investigated applying pattern classification, in particular Kohonen Maps and fuzzy clustering, simultaneously on volcanic tremor, radon and ambient parameters (pressure and temperature). The well established SO2 flux and thermal radiation data were used as the 'smoking gun', for certifying that the observed changes in seismic and in radon data can be considered as volcanogenic. Our results unveil ';failed

  10. Volcanism and Oil & Gas In Northeast China

    Institute of Scientific and Technical Information of China (English)

    Shan Xuanlong

    2000-01-01

    Based on study on the relation with volcanic rock and oil & gas in Songliao Basin and Liaohe Basin in northeast China, author proposes that material from deep by volcanism enrichs the resources in basins, that heat by volcanism promotes organic matter transforming to oil and gas, that volcanic reservoir is fracture, vesicular, solution pore, intercrystal pore.Lava facies and pyroclastic facies are favourable reservoir. Mesozoic volcanic reservoir is majority of intermediate, acid rock,but Cenozoic volcanic reservoir is majority of basalt. Types of oil and gas pool relating to volcanic rock include volcanic fracture pool, volcanic unconformity pool, volcanic rock - screened pool, volcanic darpe structural pool.

  11. Gas emission from diffuse degassing structures (DDS) of the Cameroon volcanic line (CVL): Implications for the prevention of CO2-related hazards

    Science.gov (United States)

    Issa; Ohba, T.; Chako Tchamabé, B.; Padrón, E.; Hernández, P.; Eneke Takem, E. G.; Barrancos, J.; Sighomnoun, D.; Ooki, S.; Nkamdjou, Sigha; Kusakabe, M.; Yoshida, Y.; Dionis, S.

    2014-08-01

    In the mid-1980s, lakes Nyos and Monoun violently released massive gas, mainly magmatic CO2 killing about 1800 people. Subsequent geochemical surveys and social studies indicate that lakes Nyos and Monoun event is cyclic in nature and may occur anywhere in the about 37 other volcanic lakes located in the corridor of the Cameroon volcanic line (CVL). This potential threat motivated us to check if, alike Nyos and Monoun, the internal dynamic of the other lakes is also controlled by inputs of deep-seated-derived CO2 and attempt to measure and provide comprehensive insights on the passive gas emission along the CVL. This knowledge shall contribute to the prevention of volcanic lake-related hazards in Cameroon and the refinement of the Global Carbon Cycle. We used in situ fixation and dry gas phase sampling methods to determine CO2 origin and the concentration, and the accumulation chamber technique to measure diffuse CO2 emission from nine lakes and on soil at Nyos Valley and Mount Manenguba Caldera. The results suggest that, although in minor concentrations (compared to Nyos and Monoun), ranging from 0.56 mmol kg- 1 to 8.75 mmol kg- 1, the bottom waters of some lakes also contain measurable magmatic CO2 with δ13C varies from - 4.42‰ to - 9.16‰ vs. PDB. That finding implies that, under certain circumstances, e.g. increase to volcanic and/or tectonic activities along the CVL, the concerned lakes could develop a Nyos-type behavioural scheme. The diffuse gas emission results indicate that the nine surveyed lakes release approximately 3.69 ± 0.37 kt km- 2 yr- 1 of CO2 to the atmosphere; extrapolation to the approximately 39 volcanic lakes located on the CVL yields an approximate CO2 output of 27.37 ± 0.5 kt km- 2 yr- 1, representing 0.023% of the global CO2 output from volcanic lakes. In addition to the precedent value, the gas removal operation in lakes Nyos and Monoun released approximately 2.52 ± 0.46 × 108 mol km- 2 yr- 1 CO2 to the atmosphere from January

  12. Development and application of a sampling method for the determination of reactive halogen species in volcanic gas emissions

    Science.gov (United States)

    Rüdiger, Julian; Bobrowski, Nicole; Liotta, Marcello; Hoffmann, Thorsten

    2017-04-01

    Volcanoes are a potential large source of several reactive atmospheric trace gases including sulfur and halogen containing species. Besides the importance for atmospheric chemistry, the detailed knowledge of halogen chemistry in volcanic plumes can help to get insights into subsurface processes. In this study a gas diffusion denuder sampling method, using a 1,3,5-trimethoxybenzene (1,3,5-TMB) coating for the derivatization of reactive halogen species (RHS), was characterized by dilution chamber experiments. The coating proved to be suitable to collect selectively gaseous bromine species with oxidation states (OS) of +1 or 0 (such as Br2, BrCl, BrO(H) and BrONO2), while being ignorant to HBr (OS -1). The reaction of 1,3,5-TMB with reactive bromine species gives 1-bromo-2,4,6-trimethoxybenzene (1-bromo-2,4,6-TMB) - other halogens give corresponding products. Solvent elution of the derivatized analytes and subsequent analysis with gas chromatography mass spectrometry gives detection limits of 10 ng or less for Br2, Cl2, and I2. In 2015 the method was applied on volcanic gas plumes at Mt. Etna (Italy) giving reactive bromine mixing ratios from 0.8 ppbv to 7.0 ppbv. Total bromine mixing ratios of 4.7 ppbv to 27.5 ppbv were obtained by simultaneous alkaline trap sampling (by a Raschig-tube) followed by analysis with ion chromatography and inductively coupled plasma mass spectrometry. This leads to the first results of in-situ measured reactive bromine to total bromine ratios, spanning a range between 12±1 % and 36±2 %. Our finding is in an agreement with previous model studies, which imply values < 44 % for plume ages < 1 minute, which is consistent with the assumed plume age at the sampling sites.

  13. Global volcanic emissions: budgets, plume chemistry and impacts

    Science.gov (United States)

    Mather, T. A.

    2012-12-01

    Over the past few decades our understanding of global volcanic degassing budgets, plume chemistry and the impacts of volcanic emissions on our atmosphere and environment has been revolutionized. Global volcanic emissions budgets are needed if we are to make effective use of regional and global atmospheric models in order to understand the consequences of volcanic degassing on global environmental evolution. Traditionally volcanic SO2 budgets have been the best constrained but recent efforts have seen improvements in the quantification of the budgets of other environmentally important chemical species such as CO2, the halogens (including Br and I) and trace metals (including measurements relevant to trace metal atmospheric lifetimes and bioavailability). Recent measurements of reactive trace gas species in volcanic plumes have offered intriguing hints at the chemistry occurring in the hot environment at volcanic vents and during electrical discharges in ash-rich volcanic plumes. These reactive trace species have important consequences for gas plume chemistry and impacts, for example, in terms of the global fixed nitrogen budget, volcanically induced ozone destruction and particle fluxes to the atmosphere. Volcanically initiated atmospheric chemistry was likely to have been particularly important before biological (and latterly anthropogenic) processes started to dominate many geochemical cycles, with important consequences in terms of the evolution of the nitrogen cycle and the role of particles in modulating the Earth's climate. There are still many challenges and open questions to be addressed in this fascinating area of science.

  14. Diffuse volcanic gas emission and thermal energy release from the summit crater of Pico do Fogo, Cape Verde

    Science.gov (United States)

    Dionis, Samara M.; Melián, Gladys; Rodríguez, Fátima; Hernández, Pedro A.; Padrón, Eleazar; Pérez, Nemesio M.; Barrancos, Jose; Padilla, Germán; Sumino, Hirochika; Fernandes, Paulo; Bandomo, Zuleyka; Silva, Sónia; Pereira, José M.; Semedo, Hélio

    2015-02-01

    We report the first detailed study of diffuse emission of carbon dioxide (CO2), hydrogen sulfide (H2S), helium (He), and hydrogen (H2) from the summit crater of Pico do Fogo volcano, Cape Verde. Diffuse CO2, H2S, He, and H2 gas fluxes were measured at 57 sampling sites and ranged up to 12,800, 13, 1, and 6 g m-2 day-1, respectively. Soil temperature measurements at each sampling site were used to evaluate the heat flux. Most of the summit crater shows relatively high CO2 efflux, with highest values close to the fumarolic area, suggesting a structural control of the degassing process. In contrast, H2S effluxes were negligible or very low at the summit crater, except close to the fumarolic area where anomalously high CO2 efflux and soil temperatures were also measured. We estimate total CO2, H2S, He, and H2 diffuse gas fluxes of 219 t day-1, 25, 4, and 33 kg day-1, respectively. Based on a H2O/CO2 mass ratio of 1.52 measured at the fumaroles, we estimate a diffuse steam flux from the summit crater of approximately 330 t day-1. The enthalpy of this steam is equivalent to a heat flux of about 10.3 MW. The diffuse gas emission and thermal energy released from the summit crater of Pico do Fogo volcano are comparable to those observed at other volcanoes. Sustained surveillance of Pico do Fogo using these methods will be valuable for monitoring the activity of one of the most active volcanoes in the Atlantic Ocean.

  15. Quiescent Diffusive and Fumarolic Volcanic Bromocarbon Emissions

    Science.gov (United States)

    Schwandner, F. M.; Giźe, A. P.; Seward, T. M.; Hall, P. A.; Dietrich, V. J.

    2002-12-01

    Future scenarios of declining atmospheric burdens of Ozone Depleting Substances (ODS) such as halocarbons after phase-out following international regulation (Montreal Protocol) vary strongly depending on what contribution from natural sources is taken into account. In addition, current and pre-industrial global atmospheric budgets of ODS are poorly balanced by known natural and anthropogenic sources of halocarbons (Butler, 2000). Brominated halocarbons have a high Ozone Depletion Potential, Br is at least 40x as efficient as Cl in polar stratospheric ozone destruction (Solomon et al., 1992). CH3Br is the dominant Br carrier to the stratosphere with sources being ca.: 32% anthropogenic, 39% natural, but ca. 29% unaccounted for (WMO, 1998). Natural sources have been reviewed recently (Gribble, 2000, Butler, 2000), including magmatic inorganic (Bureau, 2000) and volcanic organic sources (Rassmussen et al., 1980; Schwandner et al., 2002). CH3Br and other bromocarbons have been reported in non-eruptive volcanic gases previously (Jordan et al., 2000; Schwandner et al., 2000). Due to its capability to extremely rapidly hydrolyse (Gan et al., 1995), CH3Br should not be sampled by the caustic soda bottle technique as used by Jordan et al. (2000) whose samples also show signs of air contamination, but by cryogenic separation of steam with subsequent sorbent trapping, as used by Isidorov (1990), Wahrenberger (1996) and Schwandner et al. (2000, 2001). To contribute significantly to the natural Br budget, volcanic gases would have to at least contain 2 ppmv (dry gas) CH3Br, scaled to a global CO2 emission of 66 Tgy-1 (Stoiber, 1995) based on CO2 flux to halocarbon concentration correlations (e.g. CFC-11: R2=0.91, Schwandner et al., 2002). However, CH3Br is not the only volcanogenic bromocarbon. Analysis of diffusive flank and crater degassing on Vulcano island (Italy) showed a strong diffusive component of CH3Br and C2H5Br emissions in 60-100°C hot pristine unvegetated

  16. Anomalous increase of diffuse CO_{2} emission from Brava (Cape Verde): evidence of volcanic unrest or increase gas release from a stationary magma body?

    Science.gov (United States)

    García-Merino, Marta; García-Hernández, Rubén; Montrond, Eurico; Dionis, Samara; Fernandes, Paulo; Silva, Sonia V.; Alfama, Vera; Cabral, Jeremías; Pereira, Jose M.; Padrón, Eleazar; Pérez, Nemesio M.

    2017-04-01

    Brava (67 km2) is the southwestern most and the smallest inhabited island of the Cape Verde archipelago. It is located 18 km west of Fogo Island and rises 976 m from the sea level. Brava has not any documented historical eruptions, but its Holocene volcanism and relatively high seismic activity clearly indicate that it is an active volcanic island. Since there have been no historic eruptions in Brava, volcanic hazard awareness among the population and the authorities is very low; therefore, its volcano monitoring program is scarce. With the aim of helping to provide a multidisciplinary monitoring program for the volcanic surveillance of the island, diffuse CO2 emission surveys have been carried out since 2010; approximately every 2 years. Soil CO2 efflux measurements are periodically performed at ˜ 275 observation sites all over the island and after taking into consideration their accessibility and the island volcano-structural characteristics. At each sampling site, soil CO2 efflux measurement was performed by means of a portable NDIR sensor according to the accumulation chamber method. To quantify the total diffuse CO2 emission from Brava volcanic system, soil CO2 efflux maps were constructed using sequential Gaussian simulations (sGs). An increase trend of diffuse CO2 emission rate from 42 to 681 t d-1at Brava was observed; just one year prior the 2014-2015 Fogo eruption and almost three years before the anomalous seismic activity recorded on August 2016 with more than 1000 seismic events registered by the INMG on August 1st, 2016 (Bruno Faria, personal communication). Due to this anomalous seismic activity, a diffuse CO2 emission survey at Brava was performed from August 2 to 10, 2016, and the estimated degassing rate yield a value about 72 t d-1; typical background values. An additional survey was carried out from October 22 to November 6, 2016. For this last survey, the estimated diffuse CO2 emission from Brava showed the highest observed value with a

  17. Volcanic gas impacts on vegetation at Turrialba Volcano, Costa Rica

    Science.gov (United States)

    Teasdale, R.; Jenkins, M.; Pushnik, J.; Houpis, J. L.; Brown, D. L.

    2010-12-01

    Turrialba volcano is an active composite stratovolcano that is located approximately 40 km east of San Jose, Costa Rica. Seismic activity and degassing have increased since 2005, and gas compositions reflect further increased activity since 2007 peaking in January 2010 with a phreatic eruption. Gas fumes dispersed by trade winds toward the west, northwest, and southwest flanks of Turrialba volcano have caused significant vegetation kill zones, in areas important to local agriculture, including dairy pastures and potato fields, wildlife and human populations. In addition to extensive vegetative degradation is the potential for soil and water contamination and soil erosion. Summit fumarole temperatures have been measured over 200 degrees C and gas emissions are dominated by SO2; gas and vapor plumes reach up to 2 km (fumaroles and gases are measured regularly by OVSICORI-UNA). A recent network of passive air sampling, monitoring of water temperatures of hydrothermal systems, and soil pH measurements coupled with measurement of the physiological status of surrounding plants using gas exchange and fluorescence measurements to: (1) identify physiological correlations between leaf-level gas exchange and chlorophyll fluorescence measurements of plants under long term stress induced by the volcanic gas emissions, and (2) use measurements in tandem with remotely sensed reflectance-derived fluorescence ratio indices to track natural photo inhibition caused by volcanic gas emissions, for use in monitoring plant stress and photosynthetic function. Results may prove helpful in developing potential land management strategies to maintain the biological health of the area.

  18. Integrating volcanic gas monitoring with other geophysical networks in Iceland

    Science.gov (United States)

    Pfeffer, Melissa A.

    2017-04-01

    The Icelandic Meteorological Office/Icelandic Volcano Observatory is rapidly developing and improving the use of gas measurements as a tool for pre- and syn-eruptive monitoring within Iceland. Observations of deformation, seismicity, hydrological properties, and gas emissions, united within an integrated approach, can provide improved understanding of subsurface magma movements. This is critical to evaluate signals prior to and during volcanic eruptions, issue timely eruption warnings, forecast eruption behavior, and assess volcanic hazards. Gas measurements in Iceland need to be processed to account for the high degree of gas composition alteration due to interaction with external water and rocks. Deeply-sourced magmatic gases undergo reactions and modifications as they move to the surface that exercise a strong control on the composition of surface emissions. These modifications are particularly strong at ice-capped volcanoes where most surface gases are dissolved in glacial meltwater. Models are used to project backwards from surface gas measurements to what the magmatic gas composition was prior to upward migration. After the pristine magma gas composition has been determined, it is used together with fluid compositions measured in mineral hosted melt inclusions to calculate magmatic properties to understand magma storage and migration and to discern if there have been changes in the volcanic system. The properties derived from surface gas measurements can be used as input to models interpreting deformation and seismic observations, and can be used as an additional, independent observation when interpreting hydrological and seismic changes. An integrated approach aids with determining whether observed hydro/geological changes can be due to the presence of shallow magma. Constraints on parameters such as magma gas content, viscosity and compressibility can be provided by the approach described above, which can be utilized syn-eruptively to help explain

  19. Visualising volcanic gas plumes with virtual globes

    Science.gov (United States)

    Wright, T. E.; Burton, M.; Pyle, D. M.; Caltabiano, T.

    2009-09-01

    The recent availability of small, cheap ultraviolet spectrometers has facilitated the rapid deployment of automated networks of scanning instruments at several volcanoes, measuring volcanic SO 2 gas flux at high frequency. These networks open up a range of other applications, including tomographic reconstruction of the gas distribution which is of potential use for both risk mitigation, particularly to air traffic, and environmental impact modelling. Here we present a methodology for visualising reconstructed plumes using virtual globes, such as Google Earth, which allows animations of the evolution of the gas plume to be displayed and easily shared on a common platform. We detail the process used to convert tomographically reconstructed cross-sections into animated gas plume models, describe how this process is automated and present results from the scanning network around Mt. Etna, Sicily. We achieved an average rate of one frame every 12 min, providing a good visual representation of the plume which can be examined from all angles. In creating these models, an approximation to turbulent diffusion in the atmosphere was required. To this end we derived the value of the turbulent diffusion coefficient for quiescent conditions near Etna to be around 200- 500m2s-1.

  20. Distinguishing contributions to diffuse CO2 emissions in volcanic areas from magmatic degassing and thermal decarbonation using soil gas 222Rn-δ13C systematics: Application to Santorini volcano, Greece

    Science.gov (United States)

    Parks, Michelle M.; Caliro, Stefano; Chiodini, Giovanni; Pyle, David M.; Mather, Tamsin A.; Berlo, Kim; Edmonds, Marie; Biggs, Juliet; Nomikou, Paraskevi; Raptakis, Costas

    2013-09-01

    Between January 2011 and April 2012, Santorini volcano (Greece) experienced a period of unrest characterised by the onset of detectable seismicity and caldera-wide uplift. This episode of inflation represented the first sizeable intrusion of magma beneath Santorini in the past 50 years. We employ a new approach using 222Rn-δ13C systematics to identify and quantify the source of diffuse degassing at Santorini during the period of renewed activity. Soil CO2 flux measurements were made across a network of sites on Nea Kameni between September 2010 and January 2012. Gas samples were collected in April and September 2011 for isotopic analysis of CO2 (δ13C), and radon detectors were deployed during September 2011 to measure (222Rn). Our results reveal a change in the pattern of degassing from the summit of the volcano (Nea Kameni) and suggest an increase in diffuse CO2 emissions between September 2010 and January 2012. High-CO2-flux soil gas samples have δ13C˜0‰. Using this value and other evidence from the literature we conclude that these CO2 emissions from Santorini were a mixture between CO2 sourced from magma, and CO2 released by the thermal or metamorphic breakdown of crustal limestone. We suggest that this mixing of magmatic and crustal carbonate sources may account more broadly for the typical range of δ13C values of CO2 (from ˜-4‰ to ˜+1‰) in diffuse volcanic and fumarole gas emissions around the Mediterranean, without the need to invoke unusual mantle source compositions. At Santorini a mixing model involving magmatic CO2 (with δ13C of -3±2‰ and elevated (222Rn)/CO2 ratios ˜105-106 Bqkg) and CO2 released from decarbonation of crustal limestone (with (222Rn)/CO2 ˜ 30-300 Bq kg-1, and δ13C of +5‰) can account for the δ13C and (222Rn)/CO2 characteristics of the 'high flux' gas source. This model suggests ˜60% of the carbon in the high flux deep CO2 end member is of magmatic origin. This combination of δ13C and (222Rn) measurements has

  1. Geochemical signatures of the diffuse CO2 emission from Brava volcanic system, Cape Verde

    Science.gov (United States)

    Rodriguez, F.; Bandomo, Z.; Barros, I.; Dias Fonseca, J.; Fernandes, P.; Rodrigues, J.; Melian Rodriguez, G.; Padron, E.; Dionis, S.; Sonia, S.; Gonçalves, A.; Fernandes, A.; Hernandez Perez, P. A.; Perez, N.

    2010-12-01

    Brava (67 km2) the smallest of the populated Cape Verde islands, lies at the southwestern end of the archipelagic crescent. Brava volcanic system has no documented historical eruptions, but its youthful volcanic morphology and the fact that earthquake swarms still occur indicate the potential for future eruptions. A geochemical survey of diffuse gas emissions was carried out in Brava island during February and March 2010. For this survey 228 sampling sites were selected all over the island to perform soil CO2 efflux measurements, using a portable accumulation chamber and an IR sensor, and soil temperature measurements at a depth of 30-50 cm. Soil gas samples were collected at 40 cm depth for chemical (He, H2, N2, CO2, CH4, Ar and O2) and isotopic (δ13C-CO2) analysis in 32 selected sampling sites. CO2 efflux values ranged from non-detectable up to 1.343 g m-2 d-1. To quantify the total diffuse CO2 emission from Brava volcanic system, a CO2 efflux map was constructed using sequential Gaussian simulations (sGs). Most of the studied area showed background levels of CO2 efflux (˜2 g m-2 d-1), while peak levels (>1300 g m-2 d-1) were mainly identified at Vinagre and Baleia areas. The total diffuse CO2 output from Brava volcanic system was estimated about 41.6 t d-1. The analysis of the carbon isotopic signature of the CO2 in the soil atmosphere provides an insight for evaluating the origin of the diffuse CO2 emission. Observed δ13C-CO2 values ranged from -20.86 to -1.26 ‰. A binary plot of CO2 concentrations versus δ13C-CO2 values allows us to represent three major geochemical reservoirs (atmospheric air, volcanic gas, and biogenic gas) and their related mixing lines. The chemical and isotopic analysis of Brava soil gas samples suggest a mixing with deep-seated CO2 and biogenic gas for the diffuse CO2 emission from Brava volcanic system. The lack of visible volcanic gas emission in Brava highlights the importance of monitoring diffuse CO2 emission to improve its

  2. National Greenhouse Gas Emission Inventory

    Data.gov (United States)

    U.S. Environmental Protection Agency — The National Greenhouse Gas Emission Inventory contains information on direct emissions of greenhouse gases as well as indirect or potential emissions of greenhouse...

  3. Atmospheric and environmental impacts of volcanic ash particle emissions

    Science.gov (United States)

    Durant, Adam

    2010-05-01

    Globally, at any one time, there may be 20 volcanoes erupting that collectively emit a constant flux of gases and aerosol, including silicate particles (tephra), to the atmosphere which influences processes including cloud microphysics, heterogeneous chemistry and radiative balance. The nature and impact of atmospheric volcanic particle fluxes depend on total mass erupted, emission rate, emission source location, physical and chemical properties of the particles, and the location and residence time of the particles in the atmosphere. Removal of ash particles from the atmosphere through sedimentation is strongly influenced by particle aggregation through hydrometeor formation, and convective instabilities such as mammatus. I will address the following questions: What are the atmospheric impacts of volcanic ash emissions? What controls the residence time of volcanic particles in the atmosphere? What affects particle accumulation at the surface? And what are the human and environmental impacts of ash fallout?

  4. OPIC Greenhouse Gas Emissions Inventory

    Data.gov (United States)

    Overseas Private Investment Corporation — Independent analysis details quantifying the greenhouse gas ("GHG") emissions directly attributable to projects to which the Overseas Private Investment Corporation...

  5. Multi-decadal satellite measurements of passive and eruptive volcanic SO2 emissions

    Science.gov (United States)

    Carn, Simon; Yang, Kai; Krotkov, Nickolay; Prata, Fred; Telling, Jennifer

    2015-04-01

    Periodic injections of sulfur gas species (SO2, H2S) into the stratosphere by volcanic eruptions are among the most important, and yet unpredictable, drivers of natural climate variability. However, passive (lower tropospheric) volcanic degassing is the major component of total volcanic emissions to the atmosphere on a time-averaged basis, but is poorly constrained, impacting estimates of global emissions of other volcanic gases (e.g., CO2). Stratospheric volcanic emissions are very well quantified by satellite remote sensing techniques, and we report ongoing efforts to catalog all significant volcanic SO2 emissions into the stratosphere and troposphere since 1978 using measurements from the ultraviolet (UV) Total Ozone Mapping Spectrometer (TOMS; 1978-2005), Ozone Monitoring Instrument (OMI; 2004 - present) and Ozone Mapping and Profiler Suite (OMPS; 2012 - present) instruments, supplemented by infrared (IR) data from HIRS, MODIS and AIRS. The database, intended for use as a volcanic forcing dataset in climate models, currently includes over 600 eruptions releasing a total of ~100 Tg SO2, with a mean eruption discharge of ~0.2 Tg SO2. Sensitivity to SO2 emissions from smaller eruptions greatly increased following the launch of OMI in 2004, but uncertainties remain on the volcanic flux of other sulfur species other than SO2 (H2S, OCS) due to difficulty of measurement. Although the post-Pinatubo 1991 era is often classified as volcanically quiescent, many smaller eruptions (Volcanic Explosivity Index [VEI] 3-4) since 2000 have injected significant amounts of SO2 into the upper troposphere - lower stratosphere (UTLS), peaking in 2008-2011. We also show how even smaller (VEI 2) tropical eruptions can impact the UTLS and sustain above-background stratospheric aerosol optical depth, thus playing a role in climate forcing on short timescales. To better quantify tropospheric volcanic degassing, we use ~10 years of operational SO2 measurements by OMI to identify the

  6. Volcanic gas composition, metal dispersion and deposition during explosive volcanic eruptions on the Moon

    Science.gov (United States)

    Renggli, C. J.; King, P. L.; Henley, R. W.; Norman, M. D.

    2017-06-01

    The transport of metals in volcanic gases on the Moon differs greatly from their transport on the Earth because metal speciation depends largely on gas composition, temperature, pressure and oxidation state. We present a new thermochemical model for the major and trace element composition of lunar volcanic gas during pyroclastic eruptions of picritic magmas calculated at 200-1500 °C and over 10-9-103 bar. Using published volatile component concentrations in picritic lunar glasses, we have calculated the speciation of major elements (H, O, C, Cl, S and F) in the coexisting volcanic gas as the eruption proceeds. The most abundant gases are CO, H2, H2S, COS and S2, with a transition from predominantly triatomic gases to diatomic gases with increasing temperatures and decreasing pressures. Hydrogen occurs as H2, H2S, H2S2, HCl, and HF, with H2 making up 0.5-0.8 mol fractions of the total H. Water (H2O) concentrations are at trace levels, which implies that H-species other than H2O need to be considered in lunar melts and estimates of the bulk lunar composition. The Cl and S contents of the gas control metal chloride gas species, and sulfide gas and precipitated solid species. We calculate the speciation of trace metals (Zn, Ga, Cu, Pb, Ni, Fe) in the gas phase, and also the pressure and temperature conditions at which solids form from the gas. During initial stages of the eruption, elemental gases are the dominant metal species. As the gas loses heat, chloride and sulfide species become more abundant. Our chemical speciation model is applied to a lunar pyroclastic eruption model with isentropic gas decompression. The relative abundances of the deposited metal-bearing solids with distance from the vent are predicted for slow cooling rates (<5 °C/s). Close to a volcanic vent we predict native metals are deposited, whereas metal sulfides dominate with increasing distance from the vent. Finally, the lunar gas speciation model is compared with the speciation of a H2O-, CO

  7. Monitoring Persistent Volcanic Emissions from Sulphur Springs, Saint Lucia: A Community Approach to Disaster Risk Reduction

    Science.gov (United States)

    Joseph, E. P.; Beckles, D. M.; Cox, L.; Jackson, V. B.; Alexander, D.

    2014-12-01

    Volcanic and geothermal emissions are known natural sources of volatiles to the atmosphere. Volcanogenic air pollutants known to cause the most serious impact are carbon dioxide (CO2), sulphur dioxide (SO2), hydrogen chloride (HCl) and hydrogen fluoride (HF). Some studies into the potential for volcanic emissions to produce chronic diseases in humans indicate that areas of major concern include respiratory problems, particularly silicosis (Allen et al. 2000; Baxter et al. 1999; Buist et al. 1986), psychological stress (Shore et al. 1986), and chemical impacts of gas or ash (Giammanco et al. 1998). Sulphur Springs Park in Saint Lucia has a very high recreational value with >200,000 visitors annually, while the nearby town of Soufrière has >8,400 residents. Residents and visitors have raised concerns about the volcanic emissions and its health effects. As part of the volcanic surveillance programme undertaken by the UWI, Seismic Research Centre (SRC) in Saint Lucia, a new monitoring network has been established for quantifying the ambient SO2 in air, to which staff and visitors at the volcanic park are exposed to. The implementation and continued operation of this network has involved the training of local personnel in the active field sampling and analytical techniques required for the assessment of ambient SO2 concentrations, using a low cost monitor as well as commercial passive samplers. This approach recognizes that environmental hazards are a usual part of life and productive livelihoods, and to minimize post-disaster response and recovery it is beneficial to promote preparedness and mitigation, which is best achieved at the local level with community involvement. It is also intended that the volcanic emissions monitoring network could be used as a method to establish and maintain community-based initiatives that would also be helpful when volcanic threat manifests.

  8. Continuous measurements of volcanic gases from Popocatepetl volcano by thermal emission spectroscopy

    Science.gov (United States)

    Taquet, Noemie; Stremme, Wolfgang; Meza, Israel; Grutter, Michel

    2016-04-01

    Passive volcanic gas emissions have been poorly studied despite their impact on the atmospheric chemistry with important consequences on its geochemical cycles and climate change on regional and global scale. Therefore, long-term monitoring of volcanic gas plumes and their composition are of prime importance for climatic models and the estimation of the volcanic contribution to climate change. We present a new measurement and analysis strategy based on remote thermal emission spectroscopy which can provide continuous (day and night) information of the composition of the volcanic plume. In this study we show results from the Popocatepetl volcano in Mexico with measurements performed during the year 2015 from the Altzomoni Atmospheric Observatory (19.12N, -98.65W, 3,985 masl). This site, which forms part of the RUOA (www.ruoa.unam.mx) and NDACC (https://www2.acom.ucar.edu/irwg) networks, is located north of the crater of this active volcano at 12 km distance. Emission spectra were recorded with an FTIR spectrometer (OPAG22, Bruker) at 0.5 cm-1 spectral resolution and processed using the SFIT4 radiative transfer and profile retrieval code, based on the Optimal Estimation method (Rodgers, 1976; 1990; 2000). This newly improved methodology is intercompared to a former retrieval strategy using measurements from 2008 and recent results of the variability of the SiF4/SO2 composition ratio during 2015 is presented. A discussion of how the new measurements improve the understating of the impact of volcanic gas emissions on the atmosphere on global and regional scale is included.

  9. Mercury emissions from soils and fumaroles of Nea Kameni volcanic centre, Santorini (Greece)

    National Research Council Canada - National Science Library

    BAGNATO, EMANUELA; TAMBURELLO, GIANCARLO; AIUPPA, ALESSANDRO; SPROVIERI, MARIO; VOUGIOUKALAKIS, GEORGE E; PARKS, MICHELLE

    2013-01-01

    There have been limited studies to date targeting mercury emissions from volcanic fumarolic systems, and no mercury flux data exist for soil or fumarolic emissions at Santorini volcanic complex, Greece...

  10. Global volcanic aerosol properties derived from emissions, 1990-2014, using CESM1(WACCM): VOLCANIC AEROSOLS DERIVED FROM EMISSIONS

    Energy Technology Data Exchange (ETDEWEB)

    Mills, Michael J. [Atmospheric Chemistry Observations and Modeling Laboratory, National Center for Atmospheric Research, Boulder Colorado USA; Schmidt, Anja [School of Earth and Environment, University of Leeds, Leeds UK; Easter, Richard [Atmospheric Sciences and Global Change Division, Pacific Northwest National Laboratory, Richland Washington USA; Solomon, Susan [Department of Earth, Atmospheric, and Planetary Sciences, Massachusetts Institute of Technology, Cambridge Massachusetts USA; Kinnison, Douglas E. [Atmospheric Chemistry Observations and Modeling Laboratory, National Center for Atmospheric Research, Boulder Colorado USA; Ghan, Steven J. [Atmospheric Sciences and Global Change Division, Pacific Northwest National Laboratory, Richland Washington USA; Neely, Ryan R. [School of Earth and Environment, University of Leeds, Leeds UK; National Centre for Atmospheric Science, University of Leeds, Leeds UK; Marsh, Daniel R. [Atmospheric Chemistry Observations and Modeling Laboratory, National Center for Atmospheric Research, Boulder Colorado USA; Conley, Andrew [Atmospheric Chemistry Observations and Modeling Laboratory, National Center for Atmospheric Research, Boulder Colorado USA; Bardeen, Charles G. [Atmospheric Chemistry Observations and Modeling Laboratory, National Center for Atmospheric Research, Boulder Colorado USA; Gettelman, Andrew [Atmospheric Chemistry Observations and Modeling Laboratory, National Center for Atmospheric Research, Boulder Colorado USA

    2016-03-06

    Accurate representation of global stratospheric aerosol properties from volcanic and non-volcanic sulfur emissions is key to understanding the cooling effects and ozone-loss enhancements of recent volcanic activity. Attribution of climate and ozone variability to volcanic activity is of particular interest in relation to the post-2000 slowing in the apparent rate of global average temperature increases, and variable recovery of the Antarctic ozone hole. We have developed a climatology of global aerosol properties from 1990 to 2014 calculated based on volcanic and non-volcanic emissions of sulfur sources. We have complied a database of volcanic SO2 emissions and plume altitudes for eruptions between 1990 and 2014, and a new prognostic capability for simulating stratospheric sulfate aerosols in version 5 of the Whole Atmosphere Community Climate Model, a component of the Community Earth System Model. Our climatology shows remarkable agreement with ground-based lidar observations of stratospheric aerosol optical depth (SAOD), and with in situ measurements of aerosol surface area density (SAD). These properties are key parameters in calculating the radiative and chemical effects of stratospheric aerosols. Our SAOD climatology represents a significant improvement over satellite-based analyses, which ignore aerosol extinction below 15 km, a region that can contain the vast majority of stratospheric aerosol extinction at mid- and high-latitudes. Our SAD climatology significantly improves on that provided for the Chemistry-Climate Model Initiative, which misses 60% of the SAD measured in situ. Our climatology of aerosol properties is publicly available on the Earth System Grid.

  11. Volcanic Gas Measurements During the 2004 Unrest at Mount St. Helens

    Science.gov (United States)

    McGee, K. A.; Gerlach, T. M.; Doukas, M. P.; Sutton, A. J.

    2004-12-01

    . Degassing of CO2 and H2S included emission via large bubbles ejected through pools of water. Field crews often reported intermittent strong H2S odor, especially after steam and ash events. However, persistent light and variable winds often prevented determination of emission rates. The few available emission rates for CO2 during this period are less than 150 t/d but may not be representative. Measurements during the period of dry volcanic degassing that began on October 5 or 6 were made as temperatures rose and steaming increased on the south side of the dome and as rock adjacent to the invading magma progressively dried out. These conditions enabled a buoyant plume to rise above the crater and enter higher elevation winds, which facilitated the transition to fixed-wing gas measurements. As of mid-October, fixed-wing measurements have yielded peak emission rates of 2400 t/d for CO2, 200 t/d for SO2, and 8 t/d for H2S. Emission rates of SO2 in 2004 are significantly smaller than those during the dome-building eruptions of the 1980's.

  12. Integration and Testing of Miniaturized Volcanic Gas-Sensing Instruments on UAS Platforms

    Science.gov (United States)

    Lopez, T. M.; Kern, C.; Diaz, J. A.; Vanderwaal, S. J.; Levy, A.

    2015-12-01

    Volcanologists measure the concentrations and emission rates of gases emitted from active volcanoes to understand magmatic processes, which aids in eruption forecasting, and to evaluate air quality for human and environmental health. Both of these applications become particularly important during periods of unusually high volcanic unrest when it is typically hazardous to approach a given volcano. Unmanned aerial systems (UASs) represent a promising platform for continued gas measurements during unrest, while reducing the risk to volcanologists. Two miniature gas-sensing instruments have been developed specifically for integration onto small UAS platforms. Both instruments weigh 1 kg or less, including integrated power. The microDOAS instrument is an upward-looking UV/vis spectrometer that measures the spectral absorption signature of SO2 and certain halogen oxides in scattered solar radiation. By flying beneath a volcanic plume, the instrument can measure the SO2 content in the plume cross-section which can be used to determine the SO2 emission rate. The miniGas instrument is flown within the volcanic plume and records in situ concentrations of CO2, SO2 and H2S, as well as atmospheric temperature, pressure, relative humidity and GPS location. All data are telemetered back to the base station to immediately alert the operator of potentially hazardous conditions. Both instruments have been successfully tested at active volcanoes in Alaska and Costa Rica and were integrated onto small ACUASI Ptarmigan hexacopters. A test mission was conducted at the Poker Flat Research Range in Alaska. During this experiment both instruments were successfully flown in flight patterns typical of manned volcanic gas measurements and new UAV-specific measurement strategies were developed. Here we describe the instruments and platforms employed, our experimental results and observations, and make recommendations for application to volcanic settings.

  13. Secondary emission gas chamber

    CERN Document Server

    In'shakov, V; Skvortsov, V

    2014-01-01

    For a hadron calorimeter active element there is considered a gaseous secondary emis-sion detector (150 micron gap, 50 kV/cm). Such one-stage parallel plate chamber must be a radiation hard, fast and simple. A model of such detector has been produced, tested and some characteristics are presented.

  14. Impact of volcanic fluoride and SO/sub 7/ emissions from moderated activity volcanoes on the surrounding vegetation

    Energy Technology Data Exchange (ETDEWEB)

    Garrec, J.P.; Plebin, R.; Faivre-Pierret, R.X.

    1984-01-01

    Studies in the regions of the volcanoes Etna (Italy) and Masaya (Nicaragua) show that the continuous emissions of gaseous pollutants (HF and SO/sub 2/) from moderated activity volcanoes causes a chronic pollution in the surrounding vegetation with certain economical and ecological consequences. Reciprocally the measure of the pollutants in the plants growing in volcanic regions may be a simple and fast method to investigate some characteristics of the volcanic plume: for example, intensity of the emissions of gas, direction and extent of the plume. 12 references.

  15. Natural emissions of methane from geothermal and volcanic sources in Europe

    Science.gov (United States)

    Etiope, G.; Fridriksson, T.; Italiano, F.; Winiwarter, W.; Theloke, J.

    2007-08-01

    It has recently been demonstrated that methane emission from lithosphere degassing is an important component of the natural greenhouse-gas atmospheric budget. Globally, the geological sources are mainly due to seepage from hydrocarbon-prone sedimentary basins, and subordinately from geothermal/volcanic fluxes. This work provides a first estimate of methane emission from the geothermal/volcanic component at European level. In Europe, 28 countries have geothermal systems and at least 10 countries host surface geothermal manifestations (hot springs, mofettes, gas vents). Even if direct methane flux measurements are available only for a few small areas in Italy, a fair number of data on CO 2, CH 4 and steam composition and flux from geothermal manifestations are today available for 6 countries (Czech Republic, Germany, Greece, Iceland, Italy, Spain). Following the emission factor and area-based approach, the available data have been analyzed and have led to an early and conservative estimate of methane emission into the atmosphere around 10,000 ton/yr (4000-16,000 ton/yr), basically from an area smaller than 4000 km 2, with a speculative upper limit in the order of 10 5 ton/yr. Only 4-18% of the conservative estimate (about 720 ton/yr) is due to 12 European volcanoes, where methane concentration in volcanic gases is generally in the order of a few tens of ppmv. Volcanoes are thus not a significant methane source. While the largest emission is due to geothermal areas, which may be situated next to volcanoes or independent. Here inorganic synthesis, thermometamorphism and thermal breakdown of organic matter are substantial. Methane flux can reach hundreds of ton/yr from small individual vents. Geothermal methane is mainly released in three countries located in the main high heat flow regions: Italy, Greece, and Iceland. Turkey is likely a fourth important contributor but the absolute lack of data prevents any emission estimate. Therefore, the actual European geothermal-volcanic

  16. Ground Based Ultraviolet Remote Sensing of Volcanic Gas Plumes

    Science.gov (United States)

    Kantzas, Euripides P.; McGonigle, Andrew J. S.

    2008-01-01

    Ultraviolet spectroscopy has been implemented for over thirty years to monitor volcanic SO2 emissions. These data have provided valuable information concerning underground magmatic conditions, which have been of utility in eruption forecasting efforts. During the last decade the traditionally used correlation spectrometers have been upgraded with miniature USB coupled UV spectrometers, opening a series of exciting new empirical possibilities for understanding volcanoes and their impacts upon the atmosphere. Here we review these technological developments, in addition to the scientific insights they have precipitated, covering the strengths and current limitations of this approach.

  17. Temporal variations of flux and altitude of sulfur dioxide emissions during volcanic eruptions: implications for long-range dispersal of volcanic clouds

    Directory of Open Access Journals (Sweden)

    M. Boichu

    2015-02-01

    of the modeled SO2 altitude is further confirmed by the detection of a layer of particles at the same altitude by the spaceborne CALIOP LiDAR. Analysis of CALIOP color and depolarization ratios suggests that these particles consist of sulfate aerosols formed from precursory volcanic SO2. The reconstruction of emission altitude, through inversion procedures which assimilate volcanic SO2 column amounts, requires specific meteorological conditions, especially sufficient wind shear so that gas parcels emitted at different altitudes follow distinct trajectories. We consequently explore the possibility and limits of assimilating in inverse schemes infrared (IR imagery of the volcanic SO2 cloud altitude which will render the inversion procedure independent of the wind shear prerequisite.

  18. Temporal variations of flux and altitude of sulfur dioxide emissions during volcanic eruptions: implications for long-range dispersal of volcanic clouds

    Directory of Open Access Journals (Sweden)

    M. Boichu

    2015-07-01

    exploiting the high spectral resolution of IASI. The validity of the modelled SO2 altitude is further confirmed by the detection of a layer of particles at the same altitude by the spaceborne Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP. Analysis of CALIOP colour and depolarization ratios suggests that these particles consist of sulfate aerosols formed from precursory volcanic SO2. The reconstruction of emission altitude, through inversion procedures which assimilate volcanic SO2 column amounts, requires specific meteorological conditions, especially sufficient wind shear so that gas parcels emitted at different altitudes follow distinct trajectories. We consequently explore the possibility and limits of assimilating in inverse schemes infrared (IR imagery of the volcanic SO2 cloud altitude which will render the inversion procedure independent of the wind shear prerequisite.

  19. Can satellite-based monitoring techniques be used to quantify volcanic CO2 emissions?

    Science.gov (United States)

    Schwandner, Florian M.; Carn, Simon A.; Kuze, Akihiko; Kataoka, Fumie; Shiomi, Kei; Goto, Naoki; Popp, Christoph; Ajiro, Masataka; Suto, Hiroshi; Takeda, Toru; Kanekon, Sayaka; Sealing, Christine; Flower, Verity

    2014-05-01

    Since 2010, we investigate and improve possible methods to regularly target volcanic centers from space in order to detect volcanic carbon dioxide (CO2) point source anomalies, using the Japanese Greenhouse gas Observing SATellite (GOSAT). Our long-term goals are: (a) better spatial and temporal coverage of volcano monitoring techniques; (b) improvement of the currently highly uncertain global CO2 emission inventory for volcanoes, and (c) use of volcanic CO2 emissions for high altitude, strong point source emission and dispersion studies in atmospheric science. The difficulties posed by strong relief, orogenic clouds, and aerosols are minimized by a small field of view, enhanced spectral resolving power, by employing repeat target mode observation strategies, and by comparison to continuous ground based sensor network validation data. GOSAT is a single-instrument Earth observing greenhouse gas mission aboard JAXA's IBUKI satellite in sun-synchronous polar orbit. GOSAT's Fourier-Transform Spectrometer (TANSO-FTS) has been producing total column XCO2 data since January 2009, at a repeat cycle of 3 days, offering great opportunities for temporal monitoring of point sources. GOSAT's 10 km field of view can spatially integrate entire volcanic edifices within one 'shot' in precise target mode. While it doesn't have any spatial scanning or mapping capability, it does have strong spectral resolving power and agile pointing capability to focus on several targets of interest per orbit. Sufficient uncertainty reduction is achieved through comprehensive in-flight vicarious calibration, in close collaboration between NASA and JAXA. Challenges with the on-board pointing mirror system have been compensated for employing custom observation planning strategies, including repeat sacrificial upstream reference points to control pointing mirror motion, empirical individualized target offset compensation, observation pattern simulations to minimize view angle azimuth. Since summer 2010

  20. Recent hotspot volcanism on Venus from VIRTIS emissivity data.

    Science.gov (United States)

    Smrekar, Suzanne E; Stofan, Ellen R; Mueller, Nils; Treiman, Allan; Elkins-Tanton, Linda; Helbert, Joern; Piccioni, Giuseppe; Drossart, Pierre

    2010-04-30

    The questions of whether Venus is geologically active and how the planet has resurfaced over the past billion years have major implications for interior dynamics and climate change. Nine "hotspots"--areas analogous to Hawaii, with volcanism, broad topographic rises, and large positive gravity anomalies suggesting mantle plumes at depth--have been identified as possibly active. This study used variations in the thermal emissivity of the surface observed by the Visible and Infrared Thermal Imaging Spectrometer on the European Space Agency's Venus Express spacecraft to identify compositional differences in lava flows at three hotspots. The anomalies are interpreted as a lack of surface weathering. We estimate the flows to be younger than 2.5 million years and probably much younger, about 250,000 years or less, indicating that Venus is actively resurfacing.

  1. Volcanic SO2 and SiF4 visualization and their ratio monitored using 2-D thermal emission spectroscopy

    Science.gov (United States)

    Stremme, W.; Krueger, A.; Harig, R.; Grutter, M.

    2011-09-01

    The composition and emission rates of volcanic gas plumes provide insight of the geologic internal activity, atmospheric chemistry, aerosol formation and radiative processes around it. Observations are necessary for public security and the aviation industry. Ground-based thermal emission infrared spectroscopy, which uses the radiation of the volcanic gas itself, allows for continuously monitoring during day and night from a save distance. We present measurements on Popocatépetl volcano based on thermal emission spectroscopy during different campaigns between 2006-2009 using a Scanning Infrared Gas Imaging System (SIGIS). The experimental set-up, measurement geometries and analytical algorithms are described. The equipment was operated from a safe distance of 12 km from the volcano at two different spectral resolutions: 0.5 and 4 cm-1. The 2-dimensional scanning capability of the instrument allows for an on-line visualization of the volcanic SO2 plume, animation and determination of its propagation speed. SiF4 was also identified in the infrared spectra recorded at both resolutions. The SiF4/SO2 molecular ratio can be calculated from each image and used as a highly useful parameter to follow changes in volcanic activity. A small Vulcanian eruption was monitored during the night of 16 to 17 November 2008 which was confirmed from the strong ash emission registered around 01:00 a.m. LST (Local Standard Time) and a pronounced SO2 cloud was registered. Enhanced SiF4/SO2 ratios were observed before and after the eruption. A validation of the results from thermal emission measurements with those from absorption spectra of the moon taken at the same time, as well as an error analysis, are presented. The inferred propagation speed from sequential imagees is used to calculate the emission rates at different distances from the crater.

  2. Volcanic CO2 Emissions and Glacial Cycles: Coupled Oscillations

    Science.gov (United States)

    Burley, J. M.; Huybers, P. J.; Katz, R. F.

    2016-12-01

    Following the mid-Pleistocene transition, the dominant period of glacial cycles changed from 40 ka to 100 ka. It is broadly accepted that the 40 ka glacial cycles were driven by cyclical changes in obliquity. However, this forcing does not explain the 100 ka glacial cycles. Mechanisms proposed for 100 ka cycles include isostatic bed depression and proglacial lakes destabilising the Laurentide ice sheet, non-linear responses to orbital eccentricity, and Antarctic ice sheets influencing deep-ocean stratification. None of these are universally accepted. Here we investigate the hypothesis that variations in volcanic CO2 emissions can cause 100 ka glacial cycles. Any proposed mechanism for 100 ka glacial cycles must give the Earth's climate system a memory of 10^4 - 10^5years. This timescale is difficult to achieve for surface processes, however it is possible for the solid Earth. Recent work suggests volcanic CO2 emissions change in response to glacial cycles [1] and that there could be a 50 ka delay in that response [2]. Such a lagged response could drive glacial cycles from 40 ka cycles to an integer multiple of the forcing period. Under what conditions could the climate system admit such a response? To address this, we use a simplified climate model modified from Huybers and Tziperman [3]. Our version comprises three component models for energy balance, ice sheet growth and atmospheric CO2 concentration. The model is driven by insolation alone with other components varying according to a system of coupled, differential equations. The model is run for 500 ka to produce several glacial cycles and the resulting changes in global ice volume and atmospheric CO2 concentration.We obtain a switch from 40 ka to 100 ka cycles as the volcanic CO2 response to glacial cycles is increased. These 100 ka cycles are phase-locked to obliquity, lasting 80 or 120 ka. Whilst the MOR response required (in this model) is larger than plausible estimates based on [2], it illustrates the

  3. Volcanic gas measurements at Mount Cleveland, 14-15 August 2015

    Science.gov (United States)

    Werner, Cynthia A.; Kern, Christoph; Kelly, Peter

    2017-01-01

    On 14-15 August 2015, helicopter-based measurements were made of the volcanic gases emitted from Mount Cleveland, AK. An upward-looking differential optical absorption spectroscopy (DOAS) system was used to measure incident scattered solar ultraviolet radiation while traversing beneath the plume on multiple occasions 14-15 August. This data was used to derive SO2 emission rates. Additionally, a Multi-Component Gas Analyzer System (Multi-GAS) was used to make measurements of trace gas concentrations while on a dedicated measurement flight passing through the gas plume on 15 August (19:15 - 19:56 UTC). Radiance spectra and gas compositions were both recorded at 1 second time resolution. Each spectrum and gas measurement was stamped with the GPS time and location. Each spectrum was saved in a separate ASCII file which includes 2048 radiances measured in the 285 - 430 nm spectral region and metadata associated with each acquisition. The Multi-GAS measurements are saved in a spreadsheet in the *.csv format.

  4. Potential Applications of JNPP to Infrared-Based Remote Sensing of Volcanic Emissions

    Science.gov (United States)

    Realmuto, V. J.

    2016-12-01

    The simultaneous collection of VIIRS, CrIS, and OMPS data will make JNPP an ideal platform for monitoring volcanic emissions. For daytime overpasses we will obtain three contemporaneous, but independent, estimates of SO2 column density, as well as information on the quantity and composition of aerosols and volcanic ash. We will use the independent measurements to validate individual retrieval techniques, and exploit the synergy between UV and TIR remote sensing. The finer spatial resolution of VIIRS (750 m at nadir), relative to OMPS (50 km) and CrIS (14 km), will allow us to characterize variations in surface conditions, plume composition, and the distribution of clouds within an IFOV of CrIS or OMPS, and assess the impact of these variations on the SO2retrievals. Atmospheric profiles are an essential input to the retrieval procedures, and the profiles derived from CrIS soundings will provide us with an accurate description of atmospheric conditions local to the plumes. In addition, the fine spectral resolution of CrIS will enable us to identify and quantify the components of heterogeneous (gas + particulate) plumes. We will demonstrate the potential use of JPSS to map volcanic planes through the analyses of TIR data acquired by EOS (ASTER, MODIS, and AIRS) and SNPP (VIIRS and CrIS) instruments over the plumes generated by recent eruptions of Eyjafallajökull, Bardarbunga (Iceland), Calbuco (Chile), and Ontake (Japan) Volcanoes. We will present comparisons of the TIR-based retrievals to OMI and SNPP-OMPS data products. Finally, we will outline a path to operations through collaboration with the Alaska Volcano Observatory (USGS), Anchorage Volcanic Ash Advisory Center (NWS + FAA), NASA-GSFC Direct Readout Lab, and University of Alaska-Fairbanks. This research was conducted at the Jet Propulsion Laboratory, California Institute of Technology, under contract to National Atmospheric and Space Administration.

  5. Volcanic gas composition changes during the gradual decrease of the gigantic degassing activity of Miyakejima volcano, Japan, 2000-2015

    Science.gov (United States)

    Shinohara, Hiroshi; Geshi, Nobuo; Matsushima, Nobuo; Saito, Genji; Kazahaya, Ryunosuke

    2017-02-01

    The composition of volcanic gases discharged from Miyakejima volcano has been monitored during the intensive degassing activity that began after the eruption in 2000. During the 15 years from 2000 to 2015, Miyakejima volcano discharged 25.5 Mt of SO2, which required degassing of 3 km3 of basaltic magma. The SO2 emission rate peaked at 50 kt/day at the end of 2000 and quickly decreased to 5 kt/day by 2003. During the early degassing period, the volcanic gas composition was constant with the CO2/SO2 = 0.8 (mol ratio), H2O/SO2 = 35, HCl/SO2 = 0.08, and SO2/H2S = 15. The SO2 emission rate decreased gradually to 0.5 kt/day by 2012, and the gas composition also changed gradually to CO2/SO2 = 1.5, H2O/SO2 = 150, HCl/SO2 = 0.15, and SO2/H2S = 6. The compositional changes are not likely caused by changes in degassing pressure or volatile heterogeneity of a magma chamber but are likely attributed to an increase of hydrothermal scrubbing caused by large decrease of the volcanic gas emission rate, suggesting a supply of gases with constant composition during the 15 years. The intensive degassing was modeled based on degassing of a convecting magma conduit. The gradual SO2 emission rate that decrease without changes in volcanic gas composition is attributed to a reduction of diameter of the convecting magma conduit.

  6. Accounting for Greenhouse Gas Emissions from Reservoirs

    Science.gov (United States)

    Nearly three decades of research has demonstrated that the impoundment of rivers and the flooding of terrestrial ecosystems behind dams can increase rates of greenhouse gas emission, particularly methane. The 2006 IPCC Guidelines for National Greenhouse Gas Inventories includes ...

  7. Accounting for Greenhouse Gas Emissions from Reservoirs

    Science.gov (United States)

    Nearly three decades of research has demonstrated that the impoundment of rivers and the flooding of terrestrial ecosystems behind dams can increase rates of greenhouse gas emission, particularly methane. The 2006 IPCC Guidelines for National Greenhouse Gas Inventories includes ...

  8. OPIC Greenhouse Gas Emissions Analysis Details

    Data.gov (United States)

    Overseas Private Investment Corporation — Summary project inventory with independent analysis to quantify the greenhouse gas ("GHG") emissions directly attributable to projects to which the Overseas Private...

  9. Ensemble Forecasting of Volcanic Emissions in Hawai’i

    Directory of Open Access Journals (Sweden)

    Andre Kristofer Pattantyus

    2015-03-01

    Full Text Available Deterministic model forecasts do not convey to the end users the forecast uncertainty the models possess as a result of physics parameterizations, simplifications in model representation of physical processes, and errors in initial conditions. This lack of understanding leads to a level of uncertainty in the forecasted value when only a single deterministic model forecast is available. Increasing computational power and parallel software architecture allows multiple simulations to be carried out simultaneously that yield useful measures of model uncertainty that can be derived from ensemble model results. The Hybrid Single Particle Lagrangian Integration Trajectory and Dispersion model has the ability to generate ensemble forecasts. A meteorological ensemble was formed to create probabilistic forecast products and an ensemble mean forecast for volcanic emissions from the Kilauea volcano that impacts the state of Hawai’i. The probabilistic forecast products show uncertainty in pollutant concentrations that are especially useful for decision-making regarding public health. Initial comparison of the ensemble mean forecasts with observations and a single model forecast show improvements in event timing for both sulfur dioxide and sulfate aerosol forecasts.  

  10. Modelling emissions from natural gas flaring

    OpenAIRE

    G. Ezaina Umukoro; O. Saheed Ismail

    2017-01-01

    The world today recognizes the significance of environmental sustainability to the development of nations. Hence, the role oil and gas industry plays in environmental degrading activities such as gas flaring is of global concern. This study presents material balance equations and predicts results for non-hydrocarbon emissions such as CO2, CO, NO, NO2, and SO2 etc. from flaring (combustion) of 12 natural gas samples representing composition of natural gas of global origin. Gaseous emission est...

  11. Intercomparison of SO2 camera systems for imaging volcanic gas plumes

    Science.gov (United States)

    Kern, Christoph; Lübcke, Peter; Bobrowski, Nicole; Campion, Robin; Mori, Toshiya; Smekens, Jean-François; Stebel, Kerstin; Tamburello, Giancarlo; Burton, Mike; Platt, Ulrich; Prata, Fred

    2015-07-01

    SO2 camera systems are increasingly being used to image volcanic gas plumes. The ability to derive SO2 emission rates directly from the acquired imagery at high time resolution allows volcanic process studies that incorporate other high time-resolution datasets. Though the general principles behind the SO2 camera have remained the same for a number of years, recent advances in CCD technology and an improved understanding of the physics behind the measurements have driven a continuous evolution of the camera systems. Here we present an intercomparison of seven different SO2 cameras. In the first part of the experiment, the various technical designs are compared and the advantages and drawbacks of individual design options are considered. Though the ideal design was found to be dependent on the specific application, a number of general recommendations are made. Next, a time series of images recorded by all instruments at Stromboli Volcano (Italy) is compared. All instruments were easily able to capture SO2 clouds emitted from the summit vents. Quantitative comparison of the SO2 load in an individual cloud yielded an intra-instrument precision of about 12%. From the imagery, emission rates were then derived according to each group's standard retrieval process. A daily average SO2 emission rate of 61 ± 10 t/d was calculated. Due to differences in spatial integration methods and plume velocity determination, the time-dependent progression of SO2 emissions varied significantly among the individual systems. However, integration over distinct degassing events yielded comparable SO2 masses. Based on the intercomparison data, we find an approximate 1-sigma precision of 20% for the emission rates derived from the various SO2 cameras. Though it may still be improved in the future, this is currently within the typical accuracy of the measurement and is considered sufficient for most applications.

  12. Intercomparison of SO2 camera systems for imaging volcanic gas plumes

    Science.gov (United States)

    Kern, Christoph; Lübcke, Peter; Bobrowski, Nicole; Campion, Robin; Mori, Toshiya; Smekens, Jean-Francois; Stebel, Kerstin; Tamburello, Giancarlo; Burton, Mike; Platt, Ulrich; Prata, Fred

    2015-01-01

    SO2 camera systems are increasingly being used to image volcanic gas plumes. The ability to derive SO2 emission rates directly from the acquired imagery at high time resolution allows volcanic process studies that incorporate other high time-resolution datasets. Though the general principles behind the SO2 camera have remained the same for a number of years, recent advances in CCD technology and an improved understanding of the physics behind the measurements have driven a continuous evolution of the camera systems. Here we present an intercomparison of seven different SO2 cameras. In the first part of the experiment, the various technical designs are compared and the advantages and drawbacks of individual design options are considered. Though the ideal design was found to be dependent on the specific application, a number of general recommendations are made. Next, a time series of images recorded by all instruments at Stromboli Volcano (Italy) is compared. All instruments were easily able to capture SO2 clouds emitted from the summit vents. Quantitative comparison of the SO2 load in an individual cloud yielded an intra-instrument precision of about 12%. From the imagery, emission rates were then derived according to each group's standard retrieval process. A daily average SO2 emission rate of 61 ± 10 t/d was calculated. Due to differences in spatial integration methods and plume velocity determination, the time-dependent progression of SO2 emissions varied significantly among the individual systems. However, integration over distinct degassing events yielded comparable SO2 masses. Based on the intercomparison data, we find an approximate 1-sigma precision of 20% for the emission rates derived from the various SO2 cameras. Though it may still be improved in the future, this is currently within the typical accuracy of the measurement and is considered sufficient for most applications.

  13. Combining four dimensional variational data assimilation and particle filtering for estimating volcanic ash emissions

    Science.gov (United States)

    Franke, Philipp; Elbern, Hendrik

    2016-04-01

    Estimating volcanic ash emissions is a very challenging task due to limited monitoring capacities of the ash plume and nonlinear processes in the atmosphere, which renders application of source strength and injection height estimations difficult. Most models, which estimate volcanic ash emissions, make strong simplifications of the dispersion of volcanic ash and corresponding atmospheric processes. The objective of this work is to estimate volcanic ash emissions and simulate the ensuing dispersion applying a full chemistry transport model in a hybrid approach by using its adjoint as well as an ensemble of model runs to quantify forecast uncertainties. Therefore, the four dimensional variational data assimilation version of the EURAD-IM chemistry transport model is extended to include a Sequential Importance Resampling Smoother (SIRS), introducing novel weighting and resampling strategies. In the main SIRS step the ensemble members exchange high rated emission patterns while rejecting emission patterns with low value for the forecast. The emission profiles of the ensemble members are perturbed afterwards to guarantee different emissions for all ensemble members. First identical twin experiments show the ability of the system to estimate the temporal and vertical distribution of volcanic ash emissions. The 4D-var data assimilation algorithm of the new system additionally provides quantitative emission estimation.

  14. CO Emissions from Gas Engines Operating on Biomass Producer Gas

    DEFF Research Database (Denmark)

    Ahrenfeldt, Jesper; Jensen, T. K.; Henriksen, Ulrik Birk

    2004-01-01

    High carbon monoxide (CO) emission from gas engines fueled by producer gas is a concerning problem in the struggle to make biomass gasification for heat and power production a success. CO emissions from engines operating on biomass producer gases are high, especially at very lean conditions where...

  15. Unmanned Airborne Platforms for Validation of Volcanic Emission Composition and Transport Models

    Science.gov (United States)

    Pieri, D. C.; Diaz, J. A.; Bland, G.; Fladeland, M. M.

    2012-12-01

    In recent years there has been an increasing realization that current remote sensing retrieval and transport models to detect, characterize, and track airborne volcanic emissions will be much improved fundamentally, and in their application, by the acquisition of in situ validation data. This issue was highlighted by the need for operational estimates of airborne ash concentrations during the 2010 eruption at Eyjafjallajökull-Fimmvörduháls in Iceland. In response, important campaigns were mounted in Europe to conduct airborne in situ observations with manned aircraft to validate ash concentration estimates based on remote sensing data. This effort had immediate application providing crucial accuracy and precision estimates for predicting locations, trajectories, and concentrations of the drifting ash to mitigate the severe economic impacts caused by the continent-wide grounding of aircraft. Manned flying laboratories, however, sustain serious risks if flown into the areas of volcanic plumes and drifting clouds that are of the highest interest, namely the zones of most concentrated ash and gas, which are often opaque to upwelling radiation at the longer infrared wavelengths (e.g., 8-12μm), where ash and gas can be most readily detected. Unmanned airborne vehicles (UAVs), of course, can provide volcanic aerosol and gas sampling and measurement platforms with no risk to flight crews, and can penetrate the most ash-concentrated zones of plumes and drifting clouds. Current interest has been high in developing and testing small UAVs (e.g., NASA, University of Costa Rica, University of Düsseldorf; INGV-Catania and Rome, and others) for proximal sulfur dioxide and solid aerosol observations and sampling in relatively quiescently erupting plumes as a first step toward more far ranging and higher altitude deployments into drifting volcanic ash clouds at regional scales. Nevertheless, in the aftermath of the Icelandic crisis, ash and gas concentrations from analysis of

  16. Dedicated natural gas vehicle with low emission

    NARCIS (Netherlands)

    Voogd, A. de; Weide, J. van der; Konig, A.; Wegener, R.

    1995-01-01

    In the introduction an overview is given of international activities in the field of natural gas vehicles. The main incentives for the use of natural gas in vehicles are: emission reduction in urban areas, fuel diversification, and long term availability. Heavy duty natural gas engines are mainly en

  17. Dedicated natural gas vehicle with low emission

    NARCIS (Netherlands)

    Voogd, A. de; Weide, J. van der; Konig, A.; Wegener, R.

    1995-01-01

    In the introduction an overview is given of international activities in the field of natural gas vehicles. The main incentives for the use of natural gas in vehicles are: emission reduction in urban areas, fuel diversification, and long term availability. Heavy duty natural gas engines are mainly en

  18. One hundred volatile years of volcanic gas studies at the Hawaiian Volcano Observatory: Chapter 7 in Characteristics of Hawaiian volcanoes

    Science.gov (United States)

    Sutton, A.J.; Elias, Tamar; Poland, Michael P.; Takahashi, T. Jane; Landowski, Claire M.

    2014-01-01

    The first volcanic gas studies in Hawai‘i, beginning in 1912, established that volatile emissions from Kīlauea Volcano contained mostly water vapor, in addition to carbon dioxide and sulfur dioxide. This straightforward discovery overturned a popular volatile theory of the day and, in the same action, helped affirm Thomas A. Jaggar, Jr.’s, vision of the Hawaiian Volcano Observatory (HVO) as a preeminent place to study volcanic processes. Decades later, the environmental movement produced a watershed of quantitative analytical tools that, after being tested at Kīlauea, became part of the regular monitoring effort at HVO. The resulting volatile emission and fumarole chemistry datasets are some of the most extensive on the planet. These data indicate that magma from the mantle enters the shallow magmatic system of Kīlauea sufficiently oversaturated in CO2 to produce turbulent flow. Passive degassing at Kīlauea’s summit that occurred from 1983 through 2007 yielded CO2-depleted, but SO2- and H2O-rich, rift eruptive gases. Beginning with the 2008 summit eruption, magma reaching the East Rift Zone eruption site became depleted of much of its volatile content at the summit eruptive vent before transport to Pu‘u ‘Ō‘ō. The volatile emissions of Hawaiian volcanoes are halogen-poor, relative to those of other basaltic systems. Information gained regarding intrinsic gas solubilities at Kīlauea and Mauna Loa, as well as the pressure-controlled nature of gas release, have provided useful tools for tracking eruptive activity. Regular CO2-emission-rate measurements at Kīlauea’s summit, together with surface-deformation and other data, detected an increase in deep magma supply more than a year before a corresponding surge in effusive activity. Correspondingly, HVO routinely uses SO2 emissions to study shallow eruptive processes and effusion rates. HVO gas studies and Kīlauea’s long-running East Rift Zone eruption also demonstrate that volatile emissions can

  19. GOSAT/TANSO-FTS Measurement of Volcanic and Geothermal CO2 Emissions

    Science.gov (United States)

    Schwandner, Florian M.; Carn, Simon A.; Newhall, Christopher G.

    2010-05-01

    Approximately one tenth of the Earth's human population lives in direct reach of volcanic hazards. Being able to provide sufficiently early and scientifically sound warning is a key to volcanic hazard mitigation. Quantitative time-series monitoring of volcanic CO2 emissions will likely play a key role in such early warning activities in the future. Impending volcanic eruptions or any potentially disastrous activity that involves movement of magma in the subsurface, is often preceded by an early increase of CO2 emissions. Conventionally, volcanic CO2 monitoring is done either in campaigns of soil emission measurements (grid of one-time measuring points) that are labor intensive and slow, or by ground-based remote FTIR measurements in emission plumes. These methods are not easily available at all sites of potential activity and prohibitively costly to employ on a large number of volcanoes. In addition, both of these ground-based approaches pose a significant risk to the workers conducting these measurements. Some aircraft-based measurements have been conducted as well in the past, however these are limited by the usually meager funding situation of individual observatories, the hazard such flights pose to equipment and crew, and by the inaccessibility of parts of the plume due to ash hazards. The core motivation for this study is therefore to develop a method for volcanic CO2 monitoring from space that will provide sufficient coverage, resolution, and data quality for an application to quantitative time series monitoring and correlation with other available datasets, from a safe distance and with potentially global reach. In summary, the purpose of the proposed research is to quantify volcanic CO2 emissions using satellite-borne observations. Quantitative estimates will be useful for warning of impending volcanic eruptions, and assessing the contribution of volcanic CO2 to global GHG. Our approach encompasses method development and testing for the detection of

  20. Economic growth and greenhouse gas emissions

    Energy Technology Data Exchange (ETDEWEB)

    Ansuategi, Alberto [Environment Department, University of York, York (United Kingdom); Escapa, Marta [Foundations of Economic Analysis Department, University of the Basque Country, Bilbao (Spain)

    2002-01-01

    Recent empirical research has examined the relationship between certain indicators of environmental degradation and income, concluding that in some cases an inverted U-shaped relationship, which has been called an environmental Kuznets curve (EKC), exists between these variables. Unfortunately, this inverted U-shaped relationship does not hold for greenhouse gas emissions. One explanation of the absence of EKC-like behavior in greenhouse gas emissions is that greenhouse gases are special pollutants that create global, not local, disutility. But the international nature of global warming is not the only reason that prevents de-linking greenhouse gas emissions from economic growth. The intergenerational nature of the negative impact of greenhouse gas emissions may have also been an important factor preventing the implementation of greenhouse gas abatement measures in the past. In this paper we explore the effect that the presence of intergenerational spillovers has on the emissions-income relationship. We use a numerically calibrated overlapping generations model of climate-economy interactions. We conclude that: (1) the intertemporal responsibility of the regulatory agency, (2) the institutional capacity to make intergenerational transfers and (3) the presence of intergenerationally lagged impact of emissions constitute important determinants of the relationship between economic growth and greenhouse gas emissions.

  1. Reservoir Greenhouse Gas Emissions at Russian HPP

    Energy Technology Data Exchange (ETDEWEB)

    Fedorov, M. P.; Elistratov, V. V.; Maslikov, V. I.; Sidorenko, G. I.; Chusov, A. N.; Atrashenok, V. P.; Molodtsov, D. V. [St. Petersburg State Polytechnic University (Russian Federation); Savvichev, A. S. [Russian Academy of Sciences, S. N. Vinogradskii Institute of Microbiology (Russian Federation); Zinchenko, A. V. [A. I. Voeikov Main Geophysical Observatory (Russian Federation)

    2015-05-15

    Studies of greenhouse-gas emissions from the surfaces of the world’s reservoirs, which has demonstrated ambiguity of assessments of the effect of reservoirs on greenhouse-gas emissions to the atmosphere, is analyzed. It is recommended that greenhouse- gas emissions from various reservoirs be assessed by the procedure “GHG Measurement Guidelines for Fresh Water Reservoirs” (2010) for the purpose of creating a data base with results of standardized measurements. Aprogram for research into greenhouse-gas emissions is being developed at the St. Petersburg Polytechnic University in conformity with the IHA procedure at the reservoirs impounded by the Sayano-Shushenskaya and Mainskaya HPP operated by the RusHydro Co.

  2. Geologic Features of Wangjiatun Deep Gas Reservoirs of Volcanic Rock in Songliao Basin

    Institute of Scientific and Technical Information of China (English)

    SHAN Xuanlong; CHEN Shumin; WU Dawei; Zang Yudong

    2001-01-01

    Wangjiatun gas pool is located at the north part of Xujiaweizi in Songliao basin. Commercial gas flow has been found in the intermediate and acid volcanic rock of upper Jurassic - lower Cretaceous, which makes a breakthrough in deep nature gas prospecting in Songliao basin. The deep natural gas entrapment regularity is discussed in the paper by the study of deep strata, structure and reservoir. Andesite, rhyolite and little pyroclastic rock are the main reservoirs. There are two types of volcanic reservoir space assemblage in this area: the pore and fissure and the pure fissure. Changes had taken place for volcanic reservoir space during long geologic time, which was controlled by tectonic movement and geologic environment.The developed degree of reservoir space was controlled by tectonic movement, weathering and filtering, corrosion and Filling. There are three types of source- reservoir-caprock assemblage in this area: lower source- upper reservoir model,upper source - lower reservoir model and lateral change model. Mudstone in Dengluoku formation and the compacted volcanic rock of upper Jurassic - lower Cretaceous are the caprock for deep gas reservoirs. Dark mudstone of deep lacustrine facies in Shahezi formation and lower part of Dengluoku formation are the source rock of deep gas. It can be concluded that deep gas pools are mainly volcanic lithologic reservoirs.

  3. The EU Greenhouse Gas Emissions Trading Scheme

    NARCIS (Netherlands)

    Woerdman, Edwin; Woerdman, Edwin; Roggenkamp, Martha; Holwerda, Marijn

    2015-01-01

    This chapter explains how greenhouse gas emissions trading works, provides the essentials of the Directive on the European Union Emissions Trading Scheme (EU ETS) and summarizes the main implementation problems of the EU ETS. In addition, a law and economics approach is used to discuss the dilemmas

  4. Modeling Greenhouse Gas Emissions from Enteric Fermentation

    NARCIS (Netherlands)

    Kebreab, E.; Tedeschi, L.; Dijkstra, J.; Ellis, J.L.; Bannink, A.; France, J.

    2016-01-01

    Livestock directly contribute to greenhouse gas (GHG) emissions mainly through methane (CH4) and nitrous oxide (N2O) emissions. For cost and practicality reasons, quantification of GHG has been through development of various types of mathematical models. This chapter addresses the utility and limita

  5. The EU Greenhouse Gas Emissions Trading Scheme

    NARCIS (Netherlands)

    Woerdman, Edwin; Woerdman, Edwin; Roggenkamp, Martha; Holwerda, Marijn

    2015-01-01

    This chapter explains how greenhouse gas emissions trading works, provides the essentials of the Directive on the European Union Emissions Trading Scheme (EU ETS) and summarizes the main implementation problems of the EU ETS. In addition, a law and economics approach is used to discuss the dilemmas

  6. Modelling emissions from natural gas flaring

    Directory of Open Access Journals (Sweden)

    G. Ezaina Umukoro

    2017-04-01

    Full Text Available The world today recognizes the significance of environmental sustainability to the development of nations. Hence, the role oil and gas industry plays in environmental degrading activities such as gas flaring is of global concern. This study presents material balance equations and predicts results for non-hydrocarbon emissions such as CO2, CO, NO, NO2, and SO2 etc. from flaring (combustion of 12 natural gas samples representing composition of natural gas of global origin. Gaseous emission estimates and pattern were modelled by coding material balance equations for six reaction types and combustion conditions with a computer program. On the average, anticipated gaseous emissions from flaring natural gas with an average annual global flaring rate 126 bcm per year (between 2000 and 2011 in million metric tonnes (mmt are 560 mmt, 48 mmt, 91 mmt, 93 mmt and 50 mmt for CO2, CO, NO, NO2 and SO2 respectively. This model predicted gaseous emissions based on the possible individual combustion types and conditions anticipated in gas flaring operation. It will assist in the effort by environmental agencies and all concerned to track and measure the extent of environmental pollution caused by gas flaring operations in the oil and gas industry.

  7. Livestock and greenhouse gas emissions

    DEFF Research Database (Denmark)

    Herrero, M; Gerber, P; Vellinga, T

    2011-01-01

    Estimates of global greenhouse gases (GHG) emissions attributable to livestock range from 8 to 51%. This variability creates confusion among policy makers and the public as it suggests that there is a lack of consensus among scientists with regard to the contribution of livestock to global GHG...... fixed fossil C through combustion. These deviances from internationally accepted protocols create confusion and direct attention from anthropomorphic practices which have the most important contribution to global GHG emissions. Global estimates of livestock GHG emissions are most reliable when...

  8. A Proposed Community Network For Monitoring Volcanic Emissions In Saint Lucia, Lesser Antilles

    Science.gov (United States)

    Joseph, E. P.; Beckles, D. M.; Robertson, R. E.; Latchman, J. L.; Edwards, S.

    2013-12-01

    Systematic geochemical monitoring of volcanic systems in the English-speaking islands of the Lesser Antilles was initiated by the UWI Seismic Research Centre (SRC) in 2000, as part of its volcanic surveillance programme for the English-speaking islands of the Lesser Antilles. This programme provided the first time-series observations used for the purpose of volcano monitoring in Dominica and Saint Lucia, permitted the characterization of the geothermal fluids associated with them, and established baseline studies for understanding of the hydrothermal systems during periods of quiescence (Joseph et al., 2011; Joseph et al., 2013). As part of efforts to improve and expand the capacity of SRC to provide volcanic surveillance through its geothermal monitoring programme, it is necessary to develop economically sustainable options for the monitoring of volcanic emissions/pollutants. Towards this effort we intend to work in collaboration with local authorities in Saint Lucia, to develop a monitoring network for quantifying the background exposure levels of ambient concentrations of volcanic pollutants, SO2 in air and As in waters (as health significant marker elements in the geothermal emissions) that would serve as a model for the emissions monitoring network for other volcanic islands. This programme would facilitate the building of local capacity and training to monitor the hazardous exposure, through the application and transfer of a regionally available low-cost and low-technology SO2 measurement/detection system in Saint Lucia. Existing monitoring technologies to inform evidence based health practices are too costly for small island Caribbean states, and no government policies or health services measures currently exist to address/mitigate these influences. Gases, aerosols and toxic elements from eruptive and non-eruptive volcanic activity are known to adversely affect human health and the environment (Baxter, 2000; Zhang et al., 2008). Investigations into the

  9. A decade of global volcanic SO2 emissions measured from space

    Science.gov (United States)

    Carn, S. A.; Fioletov, V. E.; McLinden, C. A.; Li, C.; Krotkov, N. A.

    2017-03-01

    The global flux of sulfur dioxide (SO2) emitted by passive volcanic degassing is a key parameter that constrains the fluxes of other volcanic gases (including carbon dioxide, CO2) and toxic trace metals (e.g., mercury). It is also a required input for atmospheric chemistry and climate models, since it impacts the tropospheric burden of sulfate aerosol, a major climate-forcing species. Despite its significance, an inventory of passive volcanic degassing is very difficult to produce, due largely to the patchy spatial and temporal coverage of ground-based SO2 measurements. We report here the first volcanic SO2 emissions inventory derived from global, coincident satellite measurements, made by the Ozone Monitoring Instrument (OMI) on NASA’s Aura satellite in 2005-2015. The OMI measurements permit estimation of SO2 emissions from over 90 volcanoes, including new constraints on fluxes from Indonesia, Papua New Guinea, the Aleutian Islands, the Kuril Islands and Kamchatka. On average over the past decade, the volcanic SO2 sources consistently detected from space have discharged a total of ~63 kt/day SO2 during passive degassing, or ~23 ± 2 Tg/yr. We find that ~30% of the sources show significant decadal trends in SO2 emissions, with positive trends observed at multiple volcanoes in some regions including Vanuatu, southern Japan, Peru and Chile.

  10. Life-cycle greenhouse gas emissions of shale gas, natural gas, coal, and petroleum.

    Science.gov (United States)

    Burnham, Andrew; Han, Jeongwoo; Clark, Corrie E; Wang, Michael; Dunn, Jennifer B; Palou-Rivera, Ignasi

    2012-01-17

    The technologies and practices that have enabled the recent boom in shale gas production have also brought attention to the environmental impacts of its use. It has been debated whether the fugitive methane emissions during natural gas production and transmission outweigh the lower carbon dioxide emissions during combustion when compared to coal and petroleum. Using the current state of knowledge of methane emissions from shale gas, conventional natural gas, coal, and petroleum, we estimated up-to-date life-cycle greenhouse gas emissions. In addition, we developed distribution functions for key parameters in each pathway to examine uncertainty and identify data gaps such as methane emissions from shale gas well completions and conventional natural gas liquid unloadings that need to be further addressed. Our base case results show that shale gas life-cycle emissions are 6% lower than conventional natural gas, 23% lower than gasoline, and 33% lower than coal. However, the range in values for shale and conventional gas overlap, so there is a statistical uncertainty whether shale gas emissions are indeed lower than conventional gas. Moreover, this life-cycle analysis, among other work in this area, provides insight on critical stages that the natural gas industry and government agencies can work together on to reduce the greenhouse gas footprint of natural gas.

  11. Greenhouse Gas Emission Accounting 2

    NARCIS (Netherlands)

    Amstel, van A.R.; Kroeze, C.; Janssen, L.H.J.M.; Olivier, J.G.J.

    1999-01-01

    Here, a more detailed analysis is made of differences between national emission estimates, including the second National Communications and global inventories such as EDGAR 2.0 and atmospheric concentration data. This follow-up report provides background information for IPCC expert meetings held on

  12. Particle Emissions from Domestic Gas Cookers

    DEFF Research Database (Denmark)

    Glarborg, Peter; Livbjerg, Hans; Wagner, Ayten Yilmaz

    2010-01-01

    The authors experimentally studied the formation of submicron particles from a domestic gas cooker in a compartment free from external particle sources. The effects of fuel (methane, natural gas, odorant-free natural gas), primary aeration, flow rate, and fuel sulphur content on particle emissions...... were investigated. The experiments confirmed reports from literature that blue burning flames of domestic gas cookers emit submicron particles. The particle number concentrations varied in the range 103-106 particles/cm3, depending on the fuel, flow rate, and primary air addition. The diameters...

  13. Compositional variation in aging volcanic plumes - Analysis of gaseous SO2, CO2 and halogen species in volcanic emissions using an Unmanned Aerial Vehicle (UAV).

    Science.gov (United States)

    Rüdiger, Julian; Lukas, Tirpitz; Bobrowski, Nicole; Gutmann, Alexandra; Liotta, Marcello; de Moor, Maarten; Hoffmann, Thorsten

    2017-04-01

    Volcanoes are a large source for several reactive atmospheric trace gases including sulfur and halogen containing species. The detailed understanding of volcanic plume chemistry is needed to draw information from gas measurements on subsurface processes. This knowledge is essential for using gas measurements as a monitoring tool for volcanic activity. The reactive bromine species bromine monoxide (BrO) is of particular interest, because BrO as well as SO2 are readily measurable from safe distance by spectroscopic remote sensing techniques. BrO is not directly emitted, but is formed in the plume by a multiphase reaction mechanism. The abundance of BrO changes as a function of the distance from the vent as well as the spatial position in the plume. The precursor substance for the formation of BrO is HBr with Br2as an intermediate product. In this study we present the application of a UAV as a carrier for a remote-controlled sampling system for halogen species (Br2, HBr, BrCl, etc), based on the gas diffusion denuder technique, which allows speciation and enrichment by selective organic reactions. For the analysis of gaseous SO2 and CO2 an in-situ gas monitoring system was additionally mounted. This setup was deployed into the gas plumes of Stromboli Volcano (Italy), Masaya Volcano (Nicaragua) and Turrialba Volcano (Costa Rica) in 2016, to investigate the halogen chemistry at distant locations in the plume further downwind to the emission source, which are in most cases not accessible by other approaches. Flights into the plume were conducted with ascents of up to 1000 m. From telemetrically transmitted SO2 mixing ratios, areas of dense plume where localized to keep the UAV stationary for up to 10 minutes of sampling time. Additionally, ground based samples were taken at the crater rim (at Masaya and Turrialba) using alkaline traps, denuder and gas sensors for comparison with airborne-collected data. Herein we will present time and spatial resolved gas mixing ratio

  14. Accounting For Greenhouse Gas Emissions From Flooded ...

    Science.gov (United States)

    Nearly three decades of research has demonstrated that the inundation of rivers and terrestrial ecosystems behind dams can lead to enhanced rates of greenhouse gas emissions, particularly methane. The 2006 IPCC Guidelines for National Greenhouse Gas Inventories includes a methodology for estimating methane emissions from flooded lands, but the methodology was published as an appendix to be used a ‘basis for future methodological development’ due to a lack of data. Since the 2006 Guidelines were published there has been a 6-fold increase in the number of peer reviewed papers published on the topic including reports from reservoirs in India, China, Africa, and Russia. Furthermore, several countries, including Iceland, Switzerland, and Finland, have developed country specific methodologies for including flooded lands methane emissions in their National Greenhouse Gas Inventories. This presentation will include a review of the literature on flooded land methane emissions and approaches that have been used to upscale emissions for national inventories. We will also present ongoing research in the United States to develop a country specific methodology. The research approaches include 1) an effort to develop predictive relationships between methane emissions and reservoir characteristics that are available in national databases, such as reservoir size and drainage area, and 2) a national-scale probabilistic survey of reservoir methane emissions. To inform th

  15. Accounting For Greenhouse Gas Emissions From Flooded ...

    Science.gov (United States)

    Nearly three decades of research has demonstrated that the inundation of rivers and terrestrial ecosystems behind dams can lead to enhanced rates of greenhouse gas emissions, particularly methane. The 2006 IPCC Guidelines for National Greenhouse Gas Inventories includes a methodology for estimating methane emissions from flooded lands, but the methodology was published as an appendix to be used a ‘basis for future methodological development’ due to a lack of data. Since the 2006 Guidelines were published there has been a 6-fold increase in the number of peer reviewed papers published on the topic including reports from reservoirs in India, China, Africa, and Russia. Furthermore, several countries, including Iceland, Switzerland, and Finland, have developed country specific methodologies for including flooded lands methane emissions in their National Greenhouse Gas Inventories. This presentation will include a review of the literature on flooded land methane emissions and approaches that have been used to upscale emissions for national inventories. We will also present ongoing research in the United States to develop a country specific methodology. The research approaches include 1) an effort to develop predictive relationships between methane emissions and reservoir characteristics that are available in national databases, such as reservoir size and drainage area, and 2) a national-scale probabilistic survey of reservoir methane emissions. To inform th

  16. Mitigating greenhouse gas emissions: Voluntary reporting

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-10-01

    The Voluntary Reporting Program, developed pursuant to Section 1605(b) of the Energy Policy Act of 1992, permits corporations, government agencies, households, and voluntary organizations to report on their emissions of greenhouse gases, and on actions taken that have reduced or avoided emissions or sequestered carbon, to the Energy Information Administration (EIA). This, the second annual report of the Voluntary Reporting Program, describes information provided by the participating organizations on their aggregate emissions and emissions reductions, as well as their emissions reduction or avoidance projects, through 1995. This information has been compiled into a database that includes reports from 142 organizations and descriptions of 967 projects that either reduced greenhouse gas emissions or sequestered carbon. Fifty-one reporters also provided estimates of emissions, and emissions reductions achieved, for their entire organizations. The projects described actions taken to reduce emissions of carbon dioxide from energy production and use; to reduce methane and nitrous oxide emissions from energy use, waste management, and agricultural processes; to reduce emissions of halocarbons, such as CFCs and their replacements; and to increase carbon sequestration.

  17. Estimation of volcanic ash emission profiles using ceilometer measurements and transport models

    Science.gov (United States)

    Chan, Ka Lok; Geiß, Alexander; Gasteiger, Josef; Wagner, Frank; Wiegner, Matthias

    2016-04-01

    In recent years, the number of active remote sensing systems grows rapidly, since several national weather services initiated ceilometer networks. These networks are excellent tools to monitor the dispersion of volcanic ash clouds and to validate chemical transport models. Moreover, it is expected that the can be used to refine model calculations to better predict situations that might be dangerous for aviation. As a ceilometer can be considered as a simple single-wavelength backscatter lidar, quantitative aerosol profile information, i.e., the aerosol backscatter coefficient (βp) profile, can be derived provided that the ceilometer is calibrated. Volcanic ash concentration profile can then be estimated by using prior optical properties of volcanic ash. These profiles are then used for the inverse calculation of the emission profile of the volcanic eruption, thus, improving one of the most critical parameters of the numerical simulation. In this study, the Lagrangian particle dispersion model FLEXPART (FLEXible PARTicle dispersion model) is used to simulate the dispersion of volcanic ash. We simulate the distribution of ash for a given time/height grid, in order to compute the sensitivity functions for each measurements. As an example we use ceilometer measurements of the German weather service to reconstruct the temporal and spatial emission profile of Eyjafjallajökull eruption in April 2010. We have also examined the sensitivity of the retrieved emission profiles to different measurement parameters, e.g., geolocation of the measurement sites, total number of measurement sites, temporal and vertical resolution of the measurements, etc. The first results show that ceilometer measurements in principle are feasible for the inversion of volcanic ash emission profiles.

  18. Volcanic SO2 and SiF4 visualization using 2-D thermal emission spectroscopy – Part 1: Slant-columns and their ratios

    Directory of Open Access Journals (Sweden)

    M. Grutter

    2012-02-01

    Full Text Available The composition and emission rates of volcanic gas plumes provide insight of the geologic internal activity, atmospheric chemistry, aerosol formation and radiative processes around it. Observations are necessary for public security and the aviation industry. Ground-based thermal emission infrared spectroscopy, which uses the radiation of the volcanic gas itself, allows for continuously monitoring during day and night from a safe distance. We present measurements on Popocatépetl volcano based on thermal emission spectroscopy during different campaigns between 2006–2009 using a Scanning Infrared Gas Imaging System (SIGIS. The experimental set-up, measurement geometries and analytical algorithms are described. The equipment was operated from a safe distance of 12 km from the volcano at two different spectral resolutions: 0.5 and 4 cm−1. The 2-dimensional scanning capability of the instrument allows for an on-line visualization of the volcanic SO2 plume and its animation. SiF4 was also identified in the infrared spectra recorded at both resolutions. The SiF4/SO2 molecular ratio can be calculated from each image and used as a highly useful parameter to follow changes in volcanic activity. A small Vulcanian eruption was monitored during the night of 16 to 17 November 2008 and strong ash emission together with a pronounced SO2 cloud was registered around 01:00 a.m. LST (Local Standard Time. Enhanced SiF4/SO2 ratios were observed before and after the eruption. A validation of the results from thermal emission measurements with those from absorption spectra of the moon taken at the same time, as well as an error analysis, are presented. The inferred propagation speed from sequential images is used in a subsequent paper (Part 2 to calculate the emission rates at different distances from the crater.

  19. Volcanic SO2 and SiF4 visualization using 2-D thermal emission spectroscopy - Part 1: Slant-columns and their ratios

    Science.gov (United States)

    Stremme, W.; Krueger, A.; Harig, R.; Grutter, M.

    2012-02-01

    The composition and emission rates of volcanic gas plumes provide insight of the geologic internal activity, atmospheric chemistry, aerosol formation and radiative processes around it. Observations are necessary for public security and the aviation industry. Ground-based thermal emission infrared spectroscopy, which uses the radiation of the volcanic gas itself, allows for continuously monitoring during day and night from a safe distance. We present measurements on Popocatépetl volcano based on thermal emission spectroscopy during different campaigns between 2006-2009 using a Scanning Infrared Gas Imaging System (SIGIS). The experimental set-up, measurement geometries and analytical algorithms are described. The equipment was operated from a safe distance of 12 km from the volcano at two different spectral resolutions: 0.5 and 4 cm-1. The 2-dimensional scanning capability of the instrument allows for an on-line visualization of the volcanic SO2 plume and its animation. SiF4 was also identified in the infrared spectra recorded at both resolutions. The SiF4/SO2 molecular ratio can be calculated from each image and used as a highly useful parameter to follow changes in volcanic activity. A small Vulcanian eruption was monitored during the night of 16 to 17 November 2008 and strong ash emission together with a pronounced SO2 cloud was registered around 01:00 a.m. LST (Local Standard Time). Enhanced SiF4/SO2 ratios were observed before and after the eruption. A validation of the results from thermal emission measurements with those from absorption spectra of the moon taken at the same time, as well as an error analysis, are presented. The inferred propagation speed from sequential images is used in a subsequent paper (Part 2) to calculate the emission rates at different distances from the crater.

  20. Short-period volcanic gas precursors to phreatic eruptions: Insights from Poás Volcano, Costa Rica

    Science.gov (United States)

    de Moor, Maarten; Aiuppa, Alessandro; Pacheco, Javier; Avard, Geoffroy; Kern, Christoph; Liuzzo, Marco; Martinez, Maria; Giudice, Gaetano; Fischer, Tobias P.

    2016-01-01

    Volcanic eruptions involving interaction with water are amongst the most violent and unpredictable geologic phenomena on Earth. Phreatic eruptions are exceptionally difficult to forecast by traditional geophysical techniques. Here we report on short-term precursory variations in gas emissions related to phreatic blasts at Poás volcano, Costa Rica, as measured with an in situ multiple gas analyzer that was deployed at the edge of the erupting lake. Gas emitted from this hyper-acid crater lake approaches magmatic values of SO2/CO2 1–6 days prior to eruption. The SO2 flux derived from magmatic degassing through the lake is measureable by differential optical absorption spectrometry (sporadic campaign measurements), which allows us to constrain lake gas output and input for the major gas species during eruptive and non-eruptive periods. We can further calculate power supply to the hydrothermal system using volatile mass balance and thermodynamics, which indicates that the magmatic heat flux into the shallow hydrothermal system increases from ∼27 MW during quiescence to ∼59 MW during periods of phreatic events. These transient pulses of gas and heat from the deeper magmatic system generate both phreatic eruptions and the observed short-term changes in gas composition, because at high gas flux scrubbing of sulfur by the hydrothermal system is both kinetically and thermodynamically inhibited whereas CO2gas is always essentially inert in hyperacid conditions. Thus, the SO2/CO2 of lake emissions approaches magmatic values as gas and power supply to the sub-limnic hydrothermal system increase, vaporizing fluids and priming the hydrothermal system for eruption. Our results suggest that high-frequency real-time gas monitoring could provide useful short-term eruptive precursors at volcanoes prone to phreatic explosions.

  1. Methane Gas Emissions - is Older Infrastructure Leakier?

    Science.gov (United States)

    Wendt, L. P.; Caulton, D.; Zondlo, M. A.; Lane, H.; Lu, J.; Golston, L.; Pan, D.

    2015-12-01

    Large gains in natural gas production from hydraulic fracturing is reinvigorating the US energy economy. It is a clean burning fuel with lower emissions than that of coal or oil. Studies show that methane (CH4) leaks from natural gas infrastructure vary widely. A broader question is whether leak rates of methane might offset the benefits of combustion of natural gas. Excess methane (CH4) is a major greenhouse gas with a radiative forcing constant of 25 times that of CO2 when projected over a 100-year period. An extensive field study of 250 wells in the Marcellus Shale conducted in July 2015 examined the emission rates of this region and identifed super-emitters. Spud production data will provide information as to whether older infrastructure is responsible for more of the emissions. Quantifying the emission rate was determined by extrapolating methane releases at a distance from private well pads using an inverse Gaussian plume model. Wells studied were selected by prevailing winds, distance from public roads, and topographical information using commercial (ARCGIS and Google Earth), non-profit (drillinginfo), and government (State of PA) databases. Data were collected from the mobile sensing lab (CH4, CO2 and H2O sensors), as well as from a stationary tower. Emission rates from well pads will be compared to their original production (spud dates) to evaluate whether infrastructure age and total production correlates with the observed leak rates. Very preliminary results show no statistical correlation between well pad production rates and observed leak rates.

  2. Greenhouse gas emissions intensity of global croplands

    Science.gov (United States)

    Carlson, Kimberly M.; Gerber, James S.; Mueller, Nathaniel D.; Herrero, Mario; MacDonald, Graham K.; Brauman, Kate A.; Havlik, Petr; O'Connell, Christine S.; Johnson, Justin A.; Saatchi, Sassan; West, Paul C.

    2017-01-01

    Stabilizing greenhouse gas (GHG) emissions from croplands as agricultural demand grows is a critical component of climate change mitigation. Emissions intensity metrics--including carbon dioxide equivalent emissions per kilocalorie produced (`production intensity’)--can highlight regions, management practices, and crops as potential foci for mitigation. Yet the spatial and crop-wise distribution of emissions intensity has been uncertain. Here, we develop global crop-specific circa 2000 estimates of GHG emissions and GHG intensity in high spatial detail, reporting the effects of rice paddy management, peatland draining, and nitrogen (N) fertilizer on CH4, CO2 and N2O emissions. Global mean production intensity is 0.16 Mg CO2e M kcal-1, yet certain cropping practices contribute disproportionately to emissions. Peatland drainage (3.7 Mg CO2e M kcal-1)--concentrated in Europe and Indonesia--accounts for 32% of these cropland emissions despite peatlands producing just 1.1% of total crop kilocalories. Methane emissions from rice (0.58 Mg CO2e M kcal-1), a crucial food staple supplying 15% of total crop kilocalories, contribute 48% of cropland emissions, with outsized production intensity in Vietnam. In contrast, N2O emissions from N fertilizer application (0.033 Mg CO2e M kcal-1) generate only 20% of cropland emissions. We find that current total GHG emissions are largely unrelated to production intensity across crops and countries. Climate mitigation policies should therefore be directed to locations where crops have both high emissions and high intensities.

  3. Coal fired flue gas mercury emission controls

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Jiang; Pan, Weiguo [Shanghai Univ. of Electric Power (China); Cao, Yan; Pan, Weiping [Western Kentucky Univ., Bowling Green, KY (United States)

    2015-05-01

    Mercury (Hg) is one of the most toxic heavy metals, harmful to both the environment and human health. Hg is released into the atmosphere from natural and anthropogenic sources and its emission control has caused much concern. This book introduces readers to Hg pollution from natural and anthropogenic sources and systematically describes coal-fired flue gas mercury emission control in industry, especially from coal-fired power stations. Mercury emission control theory and experimental research are demonstrated, including how elemental mercury is oxidized into oxidized mercury and the effect of flue gas contents on the mercury speciation transformation process. Mercury emission control methods, such as existing APCDs (air pollution control devices) at power stations, sorbent injection, additives in coal combustion and photo-catalytic methods are introduced in detail. Lab-scale, pilot-scale and full-scale experimental studies of sorbent injection conducted by the authors are presented systematically, helping researchers and engineers to understand how this approach reduces the mercury emissions in flue gas and to apply the methods in mercury emission control at coal-fired power stations.

  4. Accounting for Greenhouse Gas Emissions from Reservoirs ...

    Science.gov (United States)

    Nearly three decades of research has demonstrated that the impoundment of rivers and the flooding of terrestrial ecosystems behind dams can increase rates of greenhouse gas emission, particularly methane. The 2006 IPCC Guidelines for National Greenhouse Gas Inventories includes a methodology for estimating methane emissions from flooded lands, but the methodology was published as an appendix to be used as a ‘basis for future methodological development’ due to a lack of data. Since the 2006 Guidelines were published there has been a 6-fold increase in the number of peer reviewed papers published on the topic including reports from reservoirs in India, China, Africa, and Russia. Furthermore, several countries, including Iceland, Switzerland, and Finland, have developed country specific methodologies for including flooded lands methane emissions in their National Greenhouse Gas Inventories. This presentation will include a review of the literature on flooded land methane emissions and approaches that have been used to upscale emissions for national inventories. We will also present ongoing research in the United States to develop a country specific methodology. In the U.S., research approaches include: 1) an effort to develop predictive relationships between methane emissions and reservoir characteristics that are available in national databases, such as reservoir size and drainage area, and 2) a national-scale probabilistic survey of reservoir methane em

  5. Greenhouse Gas Emissions From Cattle

    Directory of Open Access Journals (Sweden)

    Podkówka Zbigniew

    2015-03-01

    Full Text Available Cattle produce greenhouse gases (GHG which lead to changes in the chemical composition of the atmosphere. These gases which cause greenhouse effect include: methane (CH4, nitrous oxide (N2O, nitrogen oxides (NOx, sulphur dioxide (SO2, ammonia (NH3, dust particles and non-methane volatile organic compounds, commonly described as other than methane hydrocarbons. Fermentation processes taking place in the digestive tract produce ‘digestive gases’, distinguished from gases which are emitted during the decomposition of manure. Among these digestive gases methane and non-methane volatile organic compounds are of particular relevance importance. The amount of gases produced by cows can be reduced by choosing to rear animals with an improved genetically based performance. A dairy cow with higher production efficiency, producing milk with higher protein content and at the same time reduced fat content emits less GHG into the environment. Increasing the ratio of feed mixtures in a feed ration also reduces GHG emissions, especially of methane. By selection of dairy cows with higher production efficiency and appropriate nutrition, the farm's expected milk production target can be achieved while at the same time, the size of the herd is reduced, leading to a reduction of GHG emissions.

  6. Coal fired flue gas mercury emission controls

    CERN Document Server

    Wu, Jiang; Pan, Weiguo; Pan, Weiping

    2015-01-01

    Mercury (Hg) is one of the most toxic heavy metals, harmful to both the environment and human health. Hg is released into the atmosphere from natural and anthropogenic sources and its emission control has caused much concern. This book introduces readers to Hg pollution from natural and anthropogenic sources and systematically describes coal-fired flue gas mercury emission control in industry, especially from coal-fired power stations. Mercury emission control theory and experimental research are demonstrated, including how elemental mercury is oxidized into oxidized mercury and the effect of

  7. MAGA, a new database of gas natural emissions: a collaborative web environment for collecting data.

    Science.gov (United States)

    Cardellini, Carlo; Chiodini, Giovanni; Frigeri, Alessandro; Bagnato, Emanuela; Frondini, Francesco; Aiuppa, Alessandro

    2014-05-01

    The data on volcanic and non-volcanic gas emissions available online are, as today, are incomplete and most importantly, fragmentary. Hence, there is need for common frameworks to aggregate available data, in order to characterize and quantify the phenomena at various scales. A new and detailed web database (MAGA: MApping GAs emissions) has been developed, and recently improved, to collect data on carbon degassing form volcanic and non-volcanic environments. MAGA database allows researchers to insert data interactively and dynamically into a spatially referred relational database management system, as well as to extract data. MAGA kicked-off with the database set up and with the ingestion in to the database of the data from: i) a literature survey on publications on volcanic gas fluxes including data on active craters degassing, diffuse soil degassing and fumaroles both from dormant closed-conduit volcanoes (e.g., Vulcano, Phlegrean Fields, Santorini, Nysiros, Teide, etc.) and open-vent volcanoes (e.g., Etna, Stromboli, etc.) in the Mediterranean area and Azores, and ii) the revision and update of Googas database on non-volcanic emission of the Italian territory (Chiodini et al., 2008), in the framework of the Deep Earth Carbon Degassing (DECADE) research initiative of the Deep Carbon Observatory (DCO). For each geo-located gas emission site, the database holds images and description of the site and of the emission type (e.g., diffuse emission, plume, fumarole, etc.), gas chemical-isotopic composition (when available), gas temperature and gases fluxes magnitude. Gas sampling, analysis and flux measurement methods are also reported together with references and contacts to researchers expert of each site. In this phase data can be accessed on the network from a web interface, and data-driven web service, where software clients can request data directly from the database, are planned to be implemented shortly. This way Geographical Information Systems (GIS) and

  8. Insights from fumarole gas geochemistry on the recent volcanic unrest of Pico do Fogo, Cape Verde

    Science.gov (United States)

    Melián, Gladys V.; Dionis, Samara; Asensio-Ramos, María; Padilla, Germán; Fernandes, Paulo; Pérez, Nemesio M.; Sumino, Hirochika; Padrón, Eleazar; Hernández, Pedro A.; Silva, Sónia; Pereira, José Manuel; Semedo, Helio; Cabral, Jeremias

    2015-04-01

    air or by ASW. Few samples show a significant increase of the relative nitrogen content toward sediment composition. Gas geothermometry, based on chemical reactions related to measured gas species, indicate equilibrium temperatures between 240 to 504°C using the H2/H2O-CO/CO2 geothermometer and between 240 to 638°C using the CH4/CO2-CO/CO2 geothermometer. The chemical evolution of Pico do Fogo fumarolic gases coupled with the observed increase of CO2 soil flux, suggests the occurrence of an important increase of convective heat flux and evidences an active magmatic degassing beneath the volcano before the eruption onset. H2O/CO2 and H2O/St molar ratios showed an increasing trend towards the eruption onset, with higher values coinciding with the anomalous soil CO2 emissions registered at the summit crater, November 2008 and March 2014, suggesting a heat pulse from the depth affected the hydrothermal reservoir before the eruption onset. This is corroborated by the sharp increase observed in the CO/CO2 and H2/CO2 molar ratios in November 2013 (one year before the eruption), the last one probably due by H2O thermal dissociation. Early degassing of new gas-rich magma batch at depth is also explained by the observed increase on the He/CO2 molar ratio, which showed two pulses in November 2008 to February 2011 and from November 2013 to March 2014, both also coinciding with two pulses on the soil CO2 emission. These two pulses on the He content occurred together with an increase on the 3He/4He isotopic ratio, indicating the prevalence of a magmatic dominated component during these two periods. The observed changes in the chemical and isotopic composition of Pico do Fogo fumarolic gases have proved to be clear geochemical precursory signals of the volcanic unrest occurred before the eruption onset of Pico do Fogo volcano in November 23, 2014.

  9. Greenhouse Gas Emission Curb Favors China's Economy

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    @@ Living affluently while breathing in polluted air is not a desirable lifestyle. The longwaited Kyoto Protocol went into force on February 16, winning big applause around the globe. China, as a developing country, doesn't have to follow Kyoto Protocol and reduce its greenhouse gas emissions, but China, as part of the global village, will not escape similar obligations in the future.

  10. Greenhouse gas emissions trading in the EU

    NARCIS (Netherlands)

    Peeters, Marjan; Farber, Daniel A.; Peeters, Marjan

    2016-01-01

    The major regulatory experiment with greenhouse gas emissions trading in the EU enables legal scholars to learn lessons regarding its design options and implementation problems. Some fundamental concerns are: (1) the issue of how to develop a fair allocation method, also in view of carbon leakage; (

  11. Detecting gas leaks by ultrasonic emission

    DEFF Research Database (Denmark)

    Rasmussen, Karsten Bo; Henriksen, Eigil

    1997-01-01

    The emission of noise in the frequency range 10 kHz to 25.6 kHz from an experimental gas leak in a flanged joint has been experimentally investigated. The overall conclusion is that the emitted noise is almost frequency independent in level within the considered frequency range.A small PC program...

  12. Greenhouse gas emissions from South Africa

    CSIR Research Space (South Africa)

    Scholes, RJ

    1996-05-01

    Full Text Available South African greenhouse gas emissions contributed about 1.2% to the global increase in the greenhouse effect in 1988. South Africa generated trace gases with a radiation absorption potential over a 20-year period equivalent to 534 million tons...

  13. Life cycle assessment of greenhouse gas emissions

    NARCIS (Netherlands)

    Reijnders, L.; Chen, W.Y.; Seiner, J.; Suzuki, T.; Lackner, M.

    2012-01-01

    Life cycle assessments of greenhouse gas emissions have been developed for analyzing products "from cradle to grave": from resource extraction to waste disposal. Life cycle assessment methodology has also been applied to economies, trade between countries, aspects of production and to waste

  14. Life Cycle Assessment of Greenhouse Gas Emissions

    NARCIS (Netherlands)

    Reijnders, L.; Chen, W.Y.; Suzuki, T.; Lackner, M.

    2016-01-01

    Life cycle assessments of greenhouse gas emissions have been developed for analyzing products "from cradle to grave": from resource extraction to waste disposal. Life cycle assessment methodology has also been applied to economies, trade between countries, aspects of production, and waste

  15. Evaluation of gas emissions from coal stockpile

    Energy Technology Data Exchange (ETDEWEB)

    Kozinc, J.; Zupancic-Kralj, L.; Zapusek, A. [University of Ljubljana, Ljubljana (Slovenia). Faculty of Chemistry & Chemical Technology

    2004-05-01

    Gas emissions of carbon dioxide, methane, dimethylsulfide, carbon monoxide and oxygen from a coal stockpile in Velenje were determined. Gases from the coal stockpile were collected in Alltech Standard sampling bags and then analysed using a capillary gas chromatograph and electrochemical sensors. A flame ionisation detector equipped with a Zr/Ni catalytic reactor was used for the determination of methane and carbon dioxide. Dimethylsulfide was detected with a flame photometric detector, and the concentrations of carbon monoxide and oxygen were determined by use of electrochemical sensors. The results showed that the main influence on gas emissions is related to the ambient temperature. Emissions of carbon dioxide during summer 2001 (average temperature during sampling period was 24{sup o}C) were approximately 30-times higher than during winter 2002 (average temperature during sampling period was -2{sup o}C) and were also influenced by the oxygen concentration. Carbon dioxide is mainly formed by oxidation of coal. Methane and dimethylsulfide are desorbed from coal, and are present in higher concentrations in stockpile emissions when stockpiles are renewed. The dimethylsulfide concentration, in contrast to laboratory experiments in stockpile emissions, falls immediately due to photo-degradation.

  16. Greenhouse gas emissions from Canadian prairie agriculture

    Energy Technology Data Exchange (ETDEWEB)

    Ellert, B.H.; Janzen, H.H. [Agriculture and Agri-food Canada Research Centre, Lethbridge, AB, (Canada)

    1999-07-01

    There is a close relationship between soil and air quality, on the one hand, and the exchange of greenhouse gases between the earth and atmosphere, on the other. International efforts by people such as soil conservationists and climatologists to control emissions of these gases and negotiations surrounding the Kyoto Protocol have increased the debate regarding the role of agricultural activities. From evaluation of both data available before global change became important and recent research efforts, much information on greenhouse gas emissions from Canadian agriculture has been gained. A summary is included of the contribution of Canadian prairie agriculture to emissions of carbon dioxide, nitrous oxide, and methane gas. A stress is placed on the subject of the carbon cycle and on how land management practices could influence soil carbon storage capacity. The potential for increasing this carbon storage capacity is described in relation to land use, historical changes in agricultural land, and recent observations on the influence of agricultural parctices, and obstacles to estimating changes in soil carbon dioxide emissions and carbon storage, and extending the estimates to large land areas are examined. Emissions of nitrous oxide and methane gas are considered in relation to the influence of agricultural management practices. (Abstract only)

  17. Inverse transport modeling of volcanic sulfur dioxide emissions using large-scale ensemble simulations

    Science.gov (United States)

    Heng, Y.; Hoffmann, L.; Griessbach, S.; Rößler, T.; Stein, O.

    2015-10-01

    An inverse transport modeling approach based on the concepts of sequential importance resampling and parallel computing is presented to reconstruct altitude-resolved time series of volcanic emissions, which often can not be obtained directly with current measurement techniques. A new inverse modeling and simulation system, which implements the inversion approach with the Lagrangian transport model Massive-Parallel Trajectory Calculations (MPTRAC) is developed to provide reliable transport simulations of volcanic sulfur dioxide (SO2). In the inverse modeling system MPTRAC is used to perform two types of simulations, i. e., large-scale ensemble simulations for the reconstruction of volcanic emissions and final transport simulations. The transport simulations are based on wind fields of the ERA-Interim meteorological reanalysis of the European Centre for Medium Range Weather Forecasts. The reconstruction of altitude-dependent SO2 emission time series is also based on Atmospheric Infrared Sounder (AIRS) satellite observations. A case study for the eruption of the Nabro volcano, Eritrea, in June 2011, with complex emission patterns, is considered for method validation. Meteosat Visible and InfraRed Imager (MVIRI) near-real-time imagery data are used to validate the temporal development of the reconstructed emissions. Furthermore, the altitude distributions of the emission time series are compared with top and bottom altitude measurements of aerosol layers obtained by the Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP) and the Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) satellite instruments. The final transport simulations provide detailed spatial and temporal information on the SO2 distributions of the Nabro eruption. The SO2 column densities from the simulations are in good qualitative agreement with the AIRS observations. Our new inverse modeling and simulation system is expected to become a useful tool to also study other volcanic

  18. Inverse transport modeling of volcanic sulfur dioxide emissions using large-scale ensemble simulations

    Directory of Open Access Journals (Sweden)

    Y. Heng

    2015-10-01

    Full Text Available An inverse transport modeling approach based on the concepts of sequential importance resampling and parallel computing is presented to reconstruct altitude-resolved time series of volcanic emissions, which often can not be obtained directly with current measurement techniques. A new inverse modeling and simulation system, which implements the inversion approach with the Lagrangian transport model Massive-Parallel Trajectory Calculations (MPTRAC is developed to provide reliable transport simulations of volcanic sulfur dioxide (SO2. In the inverse modeling system MPTRAC is used to perform two types of simulations, i. e., large-scale ensemble simulations for the reconstruction of volcanic emissions and final transport simulations. The transport simulations are based on wind fields of the ERA-Interim meteorological reanalysis of the European Centre for Medium Range Weather Forecasts. The reconstruction of altitude-dependent SO2 emission time series is also based on Atmospheric Infrared Sounder (AIRS satellite observations. A case study for the eruption of the Nabro volcano, Eritrea, in June 2011, with complex emission patterns, is considered for method validation. Meteosat Visible and InfraRed Imager (MVIRI near-real-time imagery data are used to validate the temporal development of the reconstructed emissions. Furthermore, the altitude distributions of the emission time series are compared with top and bottom altitude measurements of aerosol layers obtained by the Cloud–Aerosol Lidar with Orthogonal Polarization (CALIOP and the Michelson Interferometer for Passive Atmospheric Sounding (MIPAS satellite instruments. The final transport simulations provide detailed spatial and temporal information on the SO2 distributions of the Nabro eruption. The SO2 column densities from the simulations are in good qualitative agreement with the AIRS observations. Our new inverse modeling and simulation system is expected to become a useful tool to also study

  19. Gas venting rates from submarine hydrothermal areas around the island of Milos, Hellenic Volcanic Arc

    Science.gov (United States)

    Dando, P. R.; Hughes, J. A.; Leahy, Y.; Niven, S. J.; Taylor, L. J.; Smith, C.

    1995-07-01

    Gas seeps were located, by echo sounding, SCUBA divers and ROV observations, at hydrothermal sites around the island of Milos, in the Hellenic Volcanic Arc. Samples were collected by SCUBA divers and by a ROV from water depths between 3 and 110 m. Fifty-six flow rates from 39 individual seeps were measured and these ranged from 0.2 to 18.51 h -1 at the depth of collection. The major component, 54.9-91.9% of the gas, was carbon dioxide. Hydrogen (≤3%), methane (≤9.7%) and hydrogen sulphide (≤8.1%) were also measured. Hydrothermal free gas fluxes from the submarine hydrothermal areas around Milos were estimated to be greater than 10 10 moles y -1. It was concluded that submarine gas seeps along volcanic island arcs may be an important carbon dioxide source.

  20. Volcanic emissions of metals and halogens from White Island (New Zealand) and Erebus volcano (Antarctica) determined with chemical traps

    Science.gov (United States)

    Wardell, L. J.; Kyle, P. R.; Counce, D.

    2008-11-01

    Volcanic emission rates of As, Sb, Pb, Hg, Se, Cl, and F were determined at Erebus volcano, Antarctica and White Island, New Zealand, using chemical traps. The trace metal fluxes were determined by combining the species to S ratios in the solutions with SO 2 emission rates measured by correlation spectrometry at the two volcanoes. At Erebus volcano, fluxes for the metals Pb and Hg were 2.0 × 10 - 4 and 8.1 × 10 - 6 kg s - 11 , respectively. Fluxes for Cl, F, As, Sb and Se (0.35, 0.15, 2.5 × 10 - 4 , 1.2 × 10 - 5 , and 4.5 × 10 - 6 kg s - 1 , respectively) agreed within error limits for values determined previously by the LiOH impregnated filter method [Zreda-Gostynska, G., Kyle, P., Finnegan, D., Prestbo, K., 1997. Volcanic gas emissions from Mount Erebus and their impact on the Antarctic environment. Journal of Geophysical Research, 102(B7): 15039-15055.], demonstrating the utility of the chemical trap method. A fall in the As/S ratio from 7 × 10 - 4 in 1997/1999 to 3 × 10 - 4 in 2000 at Erebus coincided with a change in the frequency and style of eruptive activity that may have been due to injection of magma into the system. At White Island, chemical trap data indicated fluxes of Cl = 0.90, F = 0.0079, Pb = 2.7 × 10 - 4 , Hg = 1.1 × 10 - 5 , As = 1.3 × 10 - 4 , Sb = 1.9 × 10 - 5 and Se = 1.5 × 10 - 5 kg s - 1 . Samples collected 600 m downwind of the active crater were comparable to samples collected adjacent to the main gas vent, showing that this method can still be used at some distance from a degassing vent.

  1. Effects of Climate Change on Volcanic Emissions and Health Security in Hawaii by 2050

    Science.gov (United States)

    2017-08-01

    1 DANIEL K. INOUYE ASIA PACIFIC CENTER FOR SECURITY STUDIES OCCASIONAL PAPER, AUGUST 2017 Effects of Climate Change on Volcanic Emissions and...Health Security in Hawaii by 2050 Canyon DV, Campbell JR Abstract While it is commonly understood that climate change will modify the weather, it is...mites, cockroaches, cats and dogs. Climate change may actually play an indirect causal role by encouraging human behavior that exposes people to

  2. Reducing greenhouse gas emissions through energy action

    Energy Technology Data Exchange (ETDEWEB)

    Castillo, X. [Schneider Electric (France)

    2010-07-01

    Greenhouse gas emissions have increased dramatically in recent years for a number of reasons and this is a cause of serious concern. This paper discusses how to reduce greenhouse gas emissions through energy action. It is important to save the planet from irreversible climate change. Energy efficiency (EE) should be the priority; cleaner fuels are necessary but EE is quick and cheap. Passive EE is not enough, active EE is needed and it is the only way to sustain real change. With energy action there are energy savings with ROI value, a structured methodology to identify areas of savings, prioritization of energy efficiency management plans, and increased awareness of energy consumption. Energy action is explained using the example of a mine and the results are given. The paper concludes that it is important to use existing technology to maximize efficient use of available energy in the interests of saving the planet.

  3. CO2-emissions from Norwegian oil and gas extraction

    OpenAIRE

    2015-01-01

    Emissions from oil and gas extraction matter for the lifecycle emissions of fossil fuels, and account for significant shares of domestic emissions in many fossil fuel exporting countries. In this study we investigate empirically the driving forces behind CO2-emission intensities of Norwegian oil and gas extraction, using detailed field-specific data that cover all Norwegian oil and gas activity. We find that emissions per unit extraction increase significantly as a field’s extraction declines...

  4. CO2-emissions form Norwegian oil and gas extraction

    OpenAIRE

    2015-01-01

    Emissions from oil and gas extraction matter for the lifecycle emissions of fossil fuels, and account for significant shares of domestic emissions in many fossil fuel exporting countries. In this study we investigate empirically the driving forces behind CO2-emission intensities of Norwegian oil and gas extraction, using detailed field-specific data that cover all Norwegian oil and gas activity. We find that emissions per unit extraction increase significantly as a field's extraction declines...

  5. Validation of a novel Multi-Gas sensor for volcanic HCl alongside H2S and SO2 at Mt. Etna

    Science.gov (United States)

    Roberts, T. J.; Lurton, T.; Giudice, G.; Liuzzo, M.; Aiuppa, A.; Coltelli, M.; Vignelles, D.; Salerno, G.; Couté, B.; Chartier, M.; Baron, R.; Saffell, J. R.; Scaillet, B.

    2017-05-01

    Volcanic gas emission measurements inform predictions of hazard and atmospheric impacts. For these measurements, Multi-Gas sensors provide low-cost in situ monitoring of gas composition but to date have lacked the ability to detect halogens. Here, two Multi-Gas instruments characterized passive outgassing emissions from Mt. Etna's (Italy) three summit craters, Voragine (VOR), North-east Crater (NEC) and Bocca Nuova (BN) on 2 October 2013. Signal processing (Sensor Response Model, SRM) approaches are used to analyse H2S/SO2 and HCl/SO2 ratios. A new ability to monitor volcanic HCl using miniature electrochemical sensors is here demonstrated. A "direct-exposure" Multi-Gas instrument contained SO2, H2S and HCl sensors, whose sensitivities, cross-sensitivities and response times were characterized by laboratory calibration. SRM analysis of the field data yields H2S/SO2 and HCl/SO2 molar ratios, finding H2S/SO2 = 0.02 (0.01-0.03), with distinct HCl/SO2 for the VOR, NEC and BN crater emissions of 0.41 (0.38-0.43), 0.58 (0.54-0.60) and 0.20 (0.17-0.33). A second Multi-Gas instrument provided CO2/SO2 and H2O/SO2 and enabled cross-comparison of SO2. The Multi-Gas-measured SO2-HCl-H2S-CO2-H2O compositions provide insights into volcanic outgassing. H2S/SO2 ratios indicate gas equilibration at slightly below magmatic temperatures, assuming that the magmatic redox state is preserved. Low SO2/HCl alongside low CO2/SO2 indicates a partially outgassed magma source. We highlight the potential for low-cost HCl sensing of H2S-poor HCl-rich volcanic emissions elsewhere. Further tests are needed for H2S-rich plumes and for long-term monitoring. Our study brings two new advances to volcano hazard monitoring: real-time in situ measurement of HCl and improved Multi-Gas SRM measurements of gas ratios.

  6. Long-term autonomous volcanic gas monitoring with Multi-GAS at Mount St. Helens, Washington, and Augustine Volcano, Alaska

    Science.gov (United States)

    Kelly, P. J.; Ketner, D. M.; Kern, C.; Lahusen, R. G.; Lockett, C.; Parker, T.; Paskievitch, J.; Pauk, B.; Rinehart, A.; Werner, C. A.

    2015-12-01

    In recent years, the USGS Volcano Hazards Program has worked to implement continuous real-time in situ volcanic gas monitoring at volcanoes in the Cascade Range and Alaska. The main goal of this ongoing effort is to better link the compositions of volcanic gases to other real-time monitoring data, such as seismicity and deformation, in order to improve baseline monitoring and early detection of volcanic unrest. Due to the remote and difficult-to-access nature of volcanic-gas monitoring sites in the Cascades and Alaska, we developed Multi-GAS instruments that can operate unattended for long periods of time with minimal direct maintenance from field personnel. Our Multi-GAS stations measure H2O, CO2, SO2, and H2S gas concentrations, are comprised entirely of commercial off-the-shelf components, and are powered by small solar energy systems. One notable feature of our Multi-GAS stations is that they include a unique capability to perform automated CO2, SO2, and H2S sensor verifications using portable gas standards while deployed in the field, thereby allowing for rigorous tracking of sensor performances. In addition, we have developed novel onboard data-processing routines that allow diagnostic and monitoring data - including gas ratios (e.g. CO2/SO2) - to be streamed in real time to internal observatory and public web pages without user input. Here we present over one year of continuous data from a permanent Multi-GAS station installed in August 2014 in the crater of Mount St. Helens, Washington, and several months of data from a station installed near the summit of Augustine Volcano, Alaska in June 2015. Data from the Mount St. Helens Multi-GAS station has been streaming to a public USGS site since early 2015, a first for a permanent Multi-GAS site. Neither station has detected significant changes in gas concentrations or compositions since they were installed, consistent with low levels of seismicity and deformation.

  7. Air quality and greenhouse gas emissions (Chapter 3)

    CSIR Research Space (South Africa)

    Winkler, H

    2016-01-01

    Full Text Available Shale gas development (SGD) presents opportunities and risks with regards to air pollution and greenhouse gas (GHG) emissions. There is a potential opportunity to reduce emissions, if shale gas replaces ‘dirtier’ (more emissions-intensive) fuels...

  8. A New Model for Gas Transfer and Storage in a Permeable Volcanic Edifice

    Science.gov (United States)

    Collinson, A. D.; Neuberg, J.

    2011-12-01

    There is a marked contrast between the behaviour of a volcano in an open system compared to one which is closed. It is therefore essential to understand degassing, to appreciate how much gas is lost and where. Previous studies by a variety of scientists have led to the accumulation of data via field evidence from both active and fossil volcanoes (Stasiuk et al., 1996), laboratory experiments (Moore et al., 1994) and conceptual modelling, in which Darcy's law has become increasingly applicable (Eichelberger et al., 1986; Edmonds et al., 2003). Of particular interest for this study, is the effect different permeabilities have on the degree and pattern of the gas flux. A new method has been devised to investigate gas transport and storage in a permeable volcanic edifice. The continuity equation and Darcy's law are amalgamated to derive a partial differential equation which is solved using a finite element method to obtain the gas pressure. The associated pressure gradient is then used within Darcy's law to calculate the gas flux. The properties of the gas are described by the ideal gas law. The strength of this method is that it allows the modelling of two and three dimensional structures both in stationary equilibrium and as a time dependent progression. A geometry is created and the pressure and permeabilites incorporated into the model as boundary and domain conditions respectively. The aim of the model is to investigate how variable permeability and pressure gradients influence the gas flux, for example highly permeable cracks in the dome, or impermeable layers within the volcanic structure. We also use this gas model to complement the model of Neuberg et al. (2006) in which brittle failure of the conduit-wall boundary is used as a trigger mechanism of low-frequency earthquakes. The associated behaviour of the gas in response to the brittle failure is simulated in our model by increasing the permeability through a narrow zone at the boundary between the conduit

  9. Characterization of the Etna volcanic emissions through an active biomonitoring technique (moss-bags): part 2--morphological and mineralogical features.

    Science.gov (United States)

    Calabrese, S; D'Alessandro, W

    2015-01-01

    Volcanic emissions were studied at Mount Etna (Italy) by using moss-bags technique. Mosses were exposed around the volcano at different distances from the active vents to evaluate the impact of volcanic emissions in the atmosphere. Morphology and mineralogy of volcanic particulate intercepted by mosses were investigated using scanning electron microscopy (SEM) equipped with energy dispersive spectrometer (EDS). Particles emitted during passive degassing activity from the two active vents, Bocca Nuova and North East Crater (BNC and NEC), were identified as silicates, sulfates and halide compounds. In addition to volcanic particles, we found evidences also of geogenic, anthropogenic and marine spray input. The study has shown the robustness of this active biomonitoring technique to collect particles, very useful in active volcanic areas characterized by continuous degassing and often not easily accessible to apply conventional sampling techniques.

  10. Inverse transport modeling of volcanic sulfur dioxide emissions using large-scale simulations

    Science.gov (United States)

    Heng, Yi; Hoffmann, Lars; Griessbach, Sabine; Rößler, Thomas; Stein, Olaf

    2016-05-01

    An inverse transport modeling approach based on the concepts of sequential importance resampling and parallel computing is presented to reconstruct altitude-resolved time series of volcanic emissions, which often cannot be obtained directly with current measurement techniques. A new inverse modeling and simulation system, which implements the inversion approach with the Lagrangian transport model Massive-Parallel Trajectory Calculations (MPTRAC) is developed to provide reliable transport simulations of volcanic sulfur dioxide (SO2). In the inverse modeling system MPTRAC is used to perform two types of simulations, i.e., unit simulations for the reconstruction of volcanic emissions and final forward simulations. Both types of transport simulations are based on wind fields of the ERA-Interim meteorological reanalysis of the European Centre for Medium Range Weather Forecasts. The reconstruction of altitude-dependent SO2 emission time series is also based on Atmospheric InfraRed Sounder (AIRS) satellite observations. A case study for the eruption of the Nabro volcano, Eritrea, in June 2011, with complex emission patterns, is considered for method validation. Meteosat Visible and InfraRed Imager (MVIRI) near-real-time imagery data are used to validate the temporal development of the reconstructed emissions. Furthermore, the altitude distributions of the emission time series are compared with top and bottom altitude measurements of aerosol layers obtained by the Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP) and the Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) satellite instruments. The final forward simulations provide detailed spatial and temporal information on the SO2 distributions of the Nabro eruption. By using the critical success index (CSI), the simulation results are evaluated with the AIRS observations. Compared to the results with an assumption of a constant flux of SO2 emissions, our inversion approach leads to an improvement

  11. Greenhouse gas emission inventory for Senegal, 1991.

    Science.gov (United States)

    Sokona, Y

    1995-01-01

    The first greenhouse gas (GHG) emission estimates for Senegal, for the year 1991, were produced according to the draft IPCC/OECD guidelines for national inventories of GHGs. Despite certain discrepancies, nonavailability of data, the quality of some of the data collected, and the methodology, the estimates provide a provisional basis for Senegal to fulfill its obligations under the UN Framework Convention on Climate Change. This inventory reveals that GHG emissions in Senegal, like those in many developing countries, can mainly be attributed to the use of biomass for energy, land-use change and forestry, and savanna burning. Taking into account the direct global warming potential of the main GHGs (CO2, CH4, and N2O), Senegal's emissions are estimated at 17.6 Tg ECO2. The major gases emitted are CO2 (61% of GHG emissions), followed by CH4 (35%) and N2O (4%). Energy accounts for 45% of total emissions (12% from fossil energy and 33% from traditional biomass energy); land-use change and forests, 18%; agriculture, 24%; waste, 12%; and industry, 1%.

  12. Ground Based Ultraviolet Remote Sensing of Volcanic Gas Plumes

    Directory of Open Access Journals (Sweden)

    Andrew J. S. McGonigle

    2008-03-01

    Full Text Available Ultraviolet spectroscopy has been implemented for over thirty years to monitorvolcanic SO2 emissions. These data have provided valuable information concerningunderground magmatic conditions, which have been of utility in eruption forecastingefforts. During the last decade the traditionally used correlation spectrometers have beenupgraded with miniature USB coupled UV spectrometers, opening a series of exciting newempirical possibilities for understanding volcanoes and their impacts upon the atmosphere.Here we review these technological developments, in addition to the scientific insightsthey have precipitated, covering the strengths and current limitations of this approach.

  13. Ammonia emission from a permanent grassland on volcanic soil after the treatment with dairy slurry and urea

    Science.gov (United States)

    Salazar, F.; Martínez-Lagos, J.; Alfaro, M.; Misselbrook, T.

    2014-10-01

    Ammonia (NH3) is an air pollutant largely emitted from agricultural activities including the application of livestock manures and fertilizers to grassland. This gas has been linked with important negative impacts on natural ecosystems. In southern Chile, the use of inorganic and organic fertilizers (e.g. slurries) has increased in cattle production systems over recent years, heightening the risk of N losses to the wider environment. The objectives of this study were to evaluate on permanent grasslands on a volcanic ash soil in southern Chile: 1) the N loss due to NH3 volatilization following surface application of dairy slurry and urea fertilizer; and 2) the effect of a urease inhibitor on NH3 emissions from urea fertilizer application. Small plot field experiments were conducted over spring, fall, winter and summer seasons, using a system of wind tunnels to measure ammonia emissions. Ammonia losses ranged from 1.8 (winter) to 26.0% (fall) and 3.1 (winter) to 20.5% (summer) of total N applied for urea and slurry, respectively. Based on the readily available N applied (ammoniacal N for dairy slurry and urea N for urea fertilizer), losses from dairy slurry were much greater, at 16.1 and 82.0%, for winter and summer, respectively. The use of a urease inhibitor proved to be an effective option to minimize the N loss due NH3 volatilization from urea fertilizer, with an average reduction of 71% across all seasons. The results of this and other recent studies regarding N losses suggest that ammonia volatilization is the main pathway of N loss from grassland systems in southern Chile on volcanic ash soils when urea and slurry are used as an N source. The use of good management practices, such as the inclusion of a urease inhibitor with urea fertilizer could have a beneficial impact on reducing N losses due NH3 volatilization and the environmental and economic impact of these emissions.

  14. Application of microturbines to control emissions from associated gas

    Energy Technology Data Exchange (ETDEWEB)

    Schmidt, Darren D.

    2013-04-16

    A system for controlling the emission of associated gas produced from a reservoir. In an embodiment, the system comprises a gas compressor including a gas inlet in fluid communication with an associated gas source and a gas outlet. The gas compressor adjusts the pressure of the associated gas to produce a pressure-regulated associated gas. In addition, the system comprises a gas cleaner including a gas inlet in fluid communication with the outlet of the gas compressor, a fuel gas outlet, and a waste product outlet. The gas cleaner separates at least a portion of the sulfur and the water from the associated gas to produce a fuel gas. Further, the system comprises a gas turbine including a fuel gas inlet in fluid communication with the fuel gas outlet of the gas cleaner and an air inlet. Still further, the system comprises a choke in fluid communication with the air inlet.

  15. Application of microturbines to control emissions from associated gas

    Science.gov (United States)

    Schmidt, Darren D.

    2013-04-16

    A system for controlling the emission of associated gas produced from a reservoir. In an embodiment, the system comprises a gas compressor including a gas inlet in fluid communication with an associated gas source and a gas outlet. The gas compressor adjusts the pressure of the associated gas to produce a pressure-regulated associated gas. In addition, the system comprises a gas cleaner including a gas inlet in fluid communication with the outlet of the gas compressor, a fuel gas outlet, and a waste product outlet. The gas cleaner separates at least a portion of the sulfur and the water from the associated gas to produce a fuel gas. Further, the system comprises a gas turbine including a fuel gas inlet in fluid communication with the fuel gas outlet of the gas cleaner and an air inlet. Still further, the system comprises a choke in fluid communication with the air inlet.

  16. Diffuse H_{2} emission: a useful geochemical tool to monitor the volcanic activity at El Hierro volcano system

    Science.gov (United States)

    Pérez, Nemesio M.; Melián, Gladys; González-Santana, Judit; Barrancos, José; Padilla, Germán; Rodríguez, Fátima; Padrón, Eleazar; Hernández, Pedro A.

    2016-04-01

    The occurrence of interfering processes affecting reactive gases as CO2 during its ascent from magmatic bodies or hydrothermal systems toward the surface environment hinders the interpretation of their enrichments in the soil atmosphere and fluxes for volcano monitoring purposes (Marini and Gambardella, 2005). These processes include gas scrubbing by ground-waters and interaction with rocks, decarbonatation processes, biogenic production, etc. Within the rest of the soil gases, particularly interest has been addressed to light and highly mobile gases. They offer important advantages for the detection of vertical permeability structures, because their interaction with the surrounding rocks or fluids during the ascent toward the surface is minimum. H2 is one of the most abundant trace species in volcano-hydrothermal systems and is a key participant in many redox reactions occurring in the hydrothermal reservoir gas (Giggenbach, 1987). Although H2 can be produced in soils by N2-fixing and fertilizing bacteria, soils are considered nowadays as sinks of molecular hydrogen (Smith-Downey et al., 2006). Because of its chemical and physical characteristics, H2 generated within the crust moves rapidly and escapes to the atmosphere. These characteristics make H2 one of the best geochemical indicators of magmatic and geothermal activity at depth. El Hierro is the youngest and the SW-most of the Canary Islands and the scenario of the last volcanic eruption of the archipelago, a submarine eruption that took place 2 km off the southern coast of the island from October 2011 to March 2012. Since at El Hierro Island there are not any surface geothermal manifestations (fumaroles, etc), we have focused our studies on soil degassing surveys. Here we show the results of soil H2 emission surveys that have been carried out regularly since mid-2012. Soil gas samples were collected in ˜600 sites selected based on their accessibility and geological criteria. Soil gases were sampled at ˜40

  17. Development and application of gas diffusion denuder sampling techniques with in situ derivatization for the determination of hydrogen halides in volcanic plumes

    Science.gov (United States)

    Gutmann, Alexandra; Rüdiger, Julian; Bobrowski, Nicole; Hoffmann, Thorsten

    2017-04-01

    Volcanoes emit large amounts of gases into the atmosphere. The gas composition in volcanic plumes vary, driven by subsurface processes (such as magma rising) as well as by chemical reactions within the plume after mixing with ambient air. The knowledge of the gas composition can be a useful tool to monitor volcanic activity changes. However, to use the plume composition as a monitoring parameter, it is essential to understand the chemical reactions inside volcanic plumes, in particular when interpretation of volcanic activity changes is based on reactive gas species, such as bromine monoxide or molecular halogens. Changes in BrO/SO2-ratios, measured by UV spectrometers, have already been interpreted in connection with increasing volcanic activity prior to eruptions. But the abundance of BrO changes as a function of the reaction time, and therefore with distance from the vent, as well as the spatial position in the plume. Actually model and field studies assume a non-direct emission of BrO, but its formation due to photochemical and multiphase reactions involving gas and particle phase of volcanic emission mixed with the surrounding atmosphere. However, same models presume HBr as initially emitted species. Therefore, HBr is an important species linking BrO to geophysical processes in volcanic systems. Due to the lack of analytical methods for the accurate speciation of certain halogens (HBr, Br2, Br, BrCl, HOBr, etc.) there are still large uncertainties about the magnitude of volcanic halogen emissions, and in the understanding of the bromine chemistry in volcanic plumes. Since the concentrations of hydrogen halides are not directly accesable by remote sensing techniques, an in situ method with coated gas diffusion denuder was developed. The method uses selective derivatization reaction of gaseous hydrogen halides with an organic compound for the enrichment and immobilization. For this task 5,6-Epoxy-5,6-dihydro-1,10-phenanthrolin was identified as a suitable

  18. Reservoir characteristics and control factors of Carboniferous volcanic gas reservoirs in the Dixi area of Junggar Basin, China

    Directory of Open Access Journals (Sweden)

    Ji'an Shi

    2017-02-01

    Full Text Available Field outcrop observation, drilling core description, thin-section analysis, SEM analysis, and geochemistry, indicate that Dixi area of Carboniferous volcanic rock gas reservoir belongs to the volcanic rock oil reservoir of the authigenic gas reservoir. The source rocks make contact with volcanic rock reservoir directly or by fault, and having the characteristics of near source accumulation. The volcanic rock reservoir rocks mainly consist of acidic rhyolite and dacite, intermediate andesite, basic basalt and volcanic breccia: (1 Acidic rhyolite and dacite reservoirs are developed in the middle-lower part of the structure, have suffered strong denudation effect, and the secondary pores have formed in the weathering and tectonic burial stages, but primary pores are not developed within the early diagenesis stage. Average porosity is only at 8%, and the maximum porosity is at 13.5%, with oil and gas accumulation showing poor performance. (2 Intermediate andesite and basic basalt reservoirs are mainly distributed near the crater, which resembles the size of and suggests a volcanic eruption. Primary pores are formed in the early diagenetic stage, secondary pores developed in weathering and erosion transformation stage, and secondary fractures formed in the tectonic burial stage. The average porosity is at 9.2%, and the maximum porosity is at 21.9%: it is of the high-quality reservoir types in Dixi area. (3 The volcanic breccia reservoir has the same diagenetic features with sedimentary rocks, but also has the same mineral composition with volcanic rock; rigid components can keep the primary porosity without being affected by compaction during the burial process. At the same time, the brittleness of volcanic breccia reservoir makes it easily fracture under the stress; internal fracture was developmental. Volcanic breccia developed in the structural high part and suffered a long-term leaching effect. The original pore-fracture combination also made

  19. Greenhouse gas emissions related to Dutch food consumption

    NARCIS (Netherlands)

    Kramer, KJ; Moll, HC; Nonhebel, S; Wilting, HC

    1999-01-01

    The consumption of food products involves emissions of greenhouse gases. Emissions occur in the various stages of the life cycle of food products. In this paper we discuss the greenhouse gas emissions, CO2, CH4, and N2O, related to Dutch household food consumption. Combinations of greenhouse gas int

  20. Greenhouse gas emissions related to Dutch food consumption

    NARCIS (Netherlands)

    Kramer, KJ; Moll, HC; Nonhebel, S; Wilting, HC

    The consumption of food products involves emissions of greenhouse gases. Emissions occur in the various stages of the life cycle of food products. In this paper we discuss the greenhouse gas emissions, CO2, CH4, and N2O, related to Dutch household food consumption. Combinations of greenhouse gas

  1. Opportunities to reduce methane emissions in the natural gas industry

    Energy Technology Data Exchange (ETDEWEB)

    Cowgill, R.M. [Radian Corporation, Austin, TX (United States)

    1995-12-31

    The U.S. Environmental Protection Agency (EPA) and the Gas Research Institute (GRI) cofunded a project to quantify methane (CH{sub 4}) emissions from the U.S. natural gas industry. Methane, the major constituent of natural gas, is a potent greenhouse gas that is believed to increase the effect of global warming when released to the atmosphere. Reducing emissions from natural gas systems would lessen the greenhouse gas effect attributable to atmospheric CH{sub 4}. Further, mitigation methods to reduce emissions of natural gas, a marketable resource, could save money and increase energy efficiency. This presentation summarizes the major sources and quantity of methane being emitted to the atmosphere for all segments of the U.S. gas industry: production; processing; storage; transmission; and distribution. A description of how those emissions were determined is included here, as well as a discussion of which sources are potential candidates for reducing emissions. (author)

  2. Comparison of Low Cost Miniature Spectrometers for Volcanic SO2 Emission Measurements

    Directory of Open Access Journals (Sweden)

    Euripides P. Kantzas

    2009-04-01

    Full Text Available Miniature ultraviolet USB coupled spectrometers have become ubiquitously applied over the last decade for making volcanic SO2 emission rate measurements. The dominantly applied unit has recently been discontinued however, raising the question of which currently available devices should now be implemented. In this paper, we consider, and make recommendations on this matter, by studying a number of inexpensive compact spectrometers in respect of measurement performance and thermal behaviour. Of the studied units, the Avaspec demonstrated the best prospects for the highest time resolution applications, but in the majority of cases, we anticipate users likely preferring the less bulky USB2000+s.

  3. Comparison of Low Cost Miniature Spectrometers for Volcanic SO2 Emission Measurements

    Science.gov (United States)

    Kantzas, Euripides P.; McGonigle, Andrew J. S.; Bryant, Robert G.

    2009-01-01

    Miniature ultraviolet USB coupled spectrometers have become ubiquitously applied over the last decade for making volcanic SO2 emission rate measurements. The dominantly applied unit has recently been discontinued however, raising the question of which currently available devices should now be implemented. In this paper, we consider, and make recommendations on this matter, by studying a number of inexpensive compact spectrometers in respect of measurement performance and thermal behaviour. Of the studied units, the Avaspec demonstrated the best prospects for the highest time resolution applications, but in the majority of cases, we anticipate users likely preferring the less bulky USB2000+s. PMID:22412310

  4. Compositional Impact of Io Volcanic Emissions on Jupiter's Magnetosphere and the Icy Galilean Moons

    Science.gov (United States)

    Cooper, John; Fegley, Bruce; Lipatov, Alexander; Richardson, John; Sittler, Edward

    2011-01-01

    The magnetospheric ion population of Jupiter is dominated by the 1000 kg/s of iogenic material constantly ejected by IO volcanism as neutral gas (approx. 1 kg/s goes out as high speed dust grains), subsequent atmospheric losses to the IO torus, and radial transport of torus ions throughout the magnetosphere. As that magnetosphere is greatly distended in radial size by the iogenic plasma loading, so are surfaces of the other Galilean moons also significantly, and perhaps even dominantly, affected by iogenic plasma bombardment, e.g. at the level up to 0.2 kg/s heavy ions (mostly O and S) onto Europa as per local plasma ion measurements. In comparison, cometary impacts onto IO deliver about 0.02 kg/s of impact ejecta to Europa via ballistic transfer through the Jupiter system. The magnetosphere of this system operates as a powerful engine to produce and transport ions from the IO source to the surfaces of these other moons, and any future orbiter missions to these moons must account for surface distributions of the iogenic material and its chemical effects before real assessments can be made of sensible chemical materials otherwise arising from primordial formation and subsequent evolution of these moons. This is a fundamental problem of space weathering that must be addressed for all planetary bodies with thin atmospheres and direct surface exposure to their space plasma environments. Long-standing debates from Galileo Orbiter measurements about the origins of hydrate sulfates at Europa present examples of this problem, as to whether the sulfates arise from oceanic minerals or from iogenic sulfur chemistry. Any orbiter or landed mission to Europa for astrobiological investigations would further need to separate the potential chemical biosignatures of life or its precursors from the highly abundant background of iogenic material. Although no single ion carries a tag identifying it as of iogenic or other origin, the elemental abundance distributions of ions to be

  5. Measurement of greenhouse gas emissions from composting

    Energy Technology Data Exchange (ETDEWEB)

    Teshima, M.A.; Leonard, J. [Alberta Univ., Edmonton, AB (Canada)

    2003-07-01

    In response to concerns regarding greenhouse gas (GHG) emissions, several industries are looking into new technologies to mitigate GHG production. This paper described the ongoing research regarding composting and its application to the waste management sector. Baseline data has been collected on emissions of carbon dioxide, methane and nitrous oxides, the primary greenhouse gases. Four test trials were performed at a composting facility which involved windrows with: high carbon to nitrogen ratio, turned; high carbon to nitrogen ratio, unturned; low carbon to nitrogen ratio, turned; and, low carbon to nitrogen ratio, unturned. The objective was to verify the hypothesis that high carbon to nitrogen ratio could suppress nitrous oxide emissions due to less available nitrogen for mineralization and subsequent denitrification. Another objective was to confirm if turning the compost promotes an aerobic environment in which methane production is decreased. Concurrent bench-scale composting experiments were conducted to measure and analyze off-gases to evaluate the feasibility of field-scale composting operations.

  6. CO and PAH emissions from engines operating on producer gas

    DEFF Research Database (Denmark)

    Ahrenfeldt, Jesper

    2005-01-01

    from the start been that a high CO emission is a measure for incomplete combustion of hydrocarbons and thus an indicator for the presents of organic micro emissions such as polynuclear aromatic hydrocarbons (PAH). Measurements from two operating gasification plants show that there is no correlation...... between the high CO emissions and PAH emissions from engines operating on producer gas. The measured PAH emissions were more than 20 times lower than the recommended emission limit for gas engines. Since unburned CO and UHC are similar in origin the reasonable regulated limit for CO emissions from engines...

  7. Volcanic tremors and magma wagging: gas flux interactions and forcing mechanism

    Science.gov (United States)

    Bercovici, David; Jellinek, A. Mark; Michaut, Chloé; Roman, Diana C.; Morse, Robert

    2013-11-01

    Volcanic tremor is an important precursor to explosive eruptions and is ubiquitous across most silicic volcanic systems. Oscillations can persist for days and occur in a remarkably narrow frequency band (i.e. 0.5-7 Hz). The recently proposed magma-wagging model of Jellinek & Bercovici provides a basic explanation for the emergence and frequency evolution of tremor that is consistent with observations of many active silicic and andesitic volcanic systems. This model builds on work suggesting that the magma column rising in the volcanic conduit is surrounded by a permeable vesicular annulus of sheared bubbles. The magma-wagging model stipulates that the magma column rattles within the spring like foam of the annulus, and predicts oscillations at the range of observed tremor frequencies for a wide variety of volcanic environments. However, the viscous resistance of the magma column attenuates the oscillations and thus a forcing mechanism is required. Here we provide further development of the magma-wagging model and demonstrate that it implicitly has the requisite forcing to excite wagging behaviour. In particular, the extended model allows for gas flux through the annulus, which interacts with the wagging displacements and induces a Bernoulli effect that amplifies the oscillations. This effect leads to an instability involving growing oscillations at the lower end of the tremor frequency spectrum, and that drives the system against viscous damping of the wagging magma column. The fully non-linear model displays tremor oscillations associated with pulses in gas flux, analogous to observations of audible `chugging'. These oscillations also occur in clusters or envelopes that are consistent with observations of sporadic tremor envelopes. The wagging model further accurately predicts that seismic signals on opposite sides of a volcano are out of phase by approximately half a wagging or tremor period. Finally, peaks in gas flux occur at the end of the growing instability

  8. Experiments on gas-ash separation processes in volcanic umbrella plumes

    Science.gov (United States)

    Holasek, Rick E.; Woods, Andrew W.; Self, Stephen

    1996-03-01

    We present a series of analogue laboratory experiments which simulate the separation of ash and gas and the formation of secondary intrusions from finite volcanic umbrella plumes. We examined the lateral spreading of mixtures of freshwater and particles released into a laboratory tank containing a uniformly stratified aqueous solution. For times smaller than the sedimentation time of particles through the intrusion, the current remains coherent and intrudes laterally. As some of the particles settle into the underlying ambient fluid, a layer of particle-depleted fluid develops below the upper surface of the current and the density of the residual fluid is reduced. Over longer times, the intrusion ceases to be coherent, with small fingers of relatively buoyant, particle-depleted fluid rising from the upper part of the intrusion into the overlying fluid. Meanwhile, the lateral motion of the injected solution induces a return flow in the ambient fluid which sweeps some of the particles sedimenting from the lower surface of the intrusion inwards. As a result, relatively dense particle-laden fluid collects below the intrusion and then sinks into the underlying fluid. Eventually this fluid reaches a new neutral buoyancy height, where it intrudes to form a second laterally spreading current below the original intrusion. The process then repeats to form further weaker intrusions below. These results of the separation of the ash and volcanic gas in an umbrella plume are consistent with field observations at Sakurajima volcano where positively charged plumes, thought to consist of volcanic gas, have been observed above negatively charged plumes of ash. This work also suggests that volcanic aerosols may form up to a kilometer above the original injection height of the ash. In a strong wind shear, this could result in very different trajectories of the ash and gas and so be important for evaluating the impact of ash plumes on both aviation safety and volcanic aerosol formation

  9. CONTROL OF GAS EMISSION AT COAL FACE IN CHINA

    Institute of Scientific and Technical Information of China (English)

    俞启香; 付建华

    1991-01-01

    All the underground coal mines in China are gassy mines. The gas emission at coal face increasingly grows with the increase of working depth and coal output,for example,the gas emission at a full mechanized coal face of mine No.2 at Yongquan with a daily output of 2,000t/d is up to 66--72m3/min. Special gas emission phenomena such as gas blowout, gas and coal outburst etc. have occurred at some faces, which threatens the safe production of face, obstructs the growth of productivity and limits the full play of mechanized equipment. In this paper, gas at face is divided, according to its origin, into three constituents, namely, coming from the coal wall, mined coal and goaf; and a formula for calculation is given. Also, the characteristics of the variation of gas emission at coal face, and thesinfluence of mining sequence of a group of seams and supplied air quantity on the gas emission are discussed. Furthermore, based on the regularity of gas emission st coal face from the above three sources, and on the experiences of years, three principles on controlling gas emission at coal face are presented, that are managing the gas on classification basis, harnessing each source separately and comprehensive prevention and control. Finally, technical measures for prevention and treatment of the accumulation of gas in the upper corner of face, at the working place of coal-winning machine and in the bottom trough of conveyor are introduced.

  10. Carbonyl Emissions From Oil and Gas Production Facilities

    Science.gov (United States)

    Lyman, S. N.; O'Neil, T.; Tran, T.

    2015-12-01

    A number of recent studies have targeted emissions of methane and other hydrocarbons from oil and gas exploration and production activity. These measurements are greatly increasing understanding of the atmospheric impacts of oil and gas development. Very few measurements exist, however, of emissions of formaldehyde and other carbonyls from oil and gas equipment. Carbonyls are toxic and serve as important ozone precursors, especially during winter ozone episodes in places like Utah's Uintah Basin. Current air quality models are only able to reproduce observed high wintertime ozone if they incorporate emissions inventories with very high carbonyl emissions. We measured carbonyl emissions from oil and gas equipment and facilities—including glycol dehydrators, liquid storage tanks, raw gas leaks, raw gas-burning engines, and produced water surface impoundments—in Rocky Mountain oil and gas fields. Carbonyl emissions from raw gas were below detection, but emissions of formaldehyde, acetaldehyde, and other carbonyls were detected from liquid storage tanks, glycol dehydrators, and other oil and gas equipment. In some cases, carbonyls may be formed from the degradation of methanol and other chemicals used in oil and gas production, but the collected data provide evidence for other non-combustion formation pathways. Raw gas-burning engines also emitted carbonyls. Emissions from all measured sources were a small fraction of total volatile organic compound emissions. We incorporated our measurements into an emissions inventory, used that inventory in an air quality model (WRF-SMOKE-CAMx), and were unable to reproduce observed high wintertime ozone. This could be because (1) emission sources we have not yet measured, including compressors, gas processing plants, and others, are large; (2) non-carbonyl emissions, especially those that quickly degrade into carbonyls during photochemical processing, are underestimated in the inventory; or (3) the air quality model is unable

  11. Suggested guidelines for gas emission monitoring at danish landfills

    DEFF Research Database (Denmark)

    Kjeldsen, Peter; Scheutz, Charlotte

    2015-01-01

    Landfill gas is produced on waste disposal sites receiving organic waste resulting in emission of methane. Regulation requires that the landfill gas is managed in order to reduce emissions, but very few suggestions exist to how the landfill gas management activities are monitored, what requirements...... measures to determine the efficiency of the performed emission mitigation is defined. Finally, several principles are presented for how criteria can be developed for when a monitoring program can be terminated....

  12. Accounting For Greenhouse Gas Emissions From Flooded Lands

    Science.gov (United States)

    Nearly three decades of research has demonstrated that the inundation of rivers and terrestrial ecosystems behind dams can lead to enhanced rates of greenhouse gas emissions, particularly methane. The 2006 IPCC Guidelines for National Greenhouse Gas Inventories includes a method...

  13. Accounting For Greenhouse Gas Emissions From Flooded Lands

    Science.gov (United States)

    Nearly three decades of research has demonstrated that the inundation of rivers and terrestrial ecosystems behind dams can lead to enhanced rates of greenhouse gas emissions, particularly methane. The 2006 IPCC Guidelines for National Greenhouse Gas Inventories includes a method...

  14. Carbon and Noble Gas Isotopes in the Tengchong Volcanic Geothermal Area, Yunnan, Southwestern China

    Institute of Scientific and Technical Information of China (English)

    XU Sheng; Shun'ich NAKAI; Hiroshi WAKITA; WANG Xianbin

    2004-01-01

    Carbon and noble gas isotope analyses are reported for bubbling gas samples from the Tengchong volcanic geothermal area near the Indo-Eurasian suture zone. All samples contain a resolvable component of mantle-derived 3He.Occurrence of mantle-derived 3He coincides with surface volcanism. However, 3He occurs over a larger geographic area than do surface volcanics. δ13C values for CO2 and CH4 vary from -33.4 ‰ to 1.6 ‰ and from -52.8 ‰ to -2.8 ‰,respectively. He and C isotope systematics indicate that CO2 and CH4 in the CO2-rich gases originated predominantly from magmatic component mixed with crustal CO2 produced from carbonate. However, breakdown of organic matter and nearsurface processes accounts for the CH4 and CO2 in N2-rich gases. 3He/4He ratio distribution pattern suggests that mantlederived He and heat sources of high-temperature system in central Tengchong originate from a hidden magma reservoir at subsurface. CO2-rich gases with the highest 3He/4He ratio (5.2 Ra) may be representative of the Tengchong magmatic component. Compared with MORB, this relative low 3He/4He ratio could be fully attributed to either deep crustal contamination, or radioactive aging, or past contamination of the local mantle by U- and Th-rich subducted crustal material.However, a combination of low 3He/4He, high radiogenic 4He/40Ar ratio and identical CO2/3He and δ13Cco2 relative to MORB may suggest addition of prior subductedd crsustal material (ca 1%-2%) to the MORB reservoir around 1.3 Ga ago,which is essentially compatible with the LIL-elements, and Sr-Nd-Pb isotopes of volcanic rocks.

  15. A Low-Cost Smartphone Sensor-Based UV Camera for Volcanic SO2 Emission Measurements

    Directory of Open Access Journals (Sweden)

    Thomas Charles Wilkes

    2017-01-01

    Full Text Available Recently, we reported on the development of low-cost ultraviolet (UV cameras, based on the modification of sensors designed for the smartphone market. These units are built around modified Raspberry Pi cameras (PiCams; ≈USD 25, and usable system sensitivity was demonstrated in the UVA and UVB spectral regions, of relevance to a number of application areas. Here, we report on the first deployment of PiCam devices in one such field: UV remote sensing of sulphur dioxide emissions from volcanoes; such data provide important insights into magmatic processes and are applied in hazard assessments. In particular, we report on field trials on Mt. Etna, where the utility of these devices in quantifying volcanic sulphur dioxide (SO2 emissions was validated. We furthermore performed side-by-side trials of these units against scientific grade cameras, which are currently used in this application, finding that the two systems gave virtually identical flux time series outputs, and that signal-to-noise characteristics of the PiCam units appeared to be more than adequate for volcanological applications. Given the low cost of these sensors, allowing two-filter SO2 camera systems to be assembled for ≈USD 500, they could be suitable for widespread dissemination in volcanic SO2 monitoring internationally.

  16. Health hazards and disaster potential of ground gas emissions at Furnas volcano, São Miguel, Azores

    Science.gov (United States)

    Baxter, Peter J.; Baubron, Jean-Claude; Coutinho, Rui

    1999-09-01

    A health hazard assessment of exposure to soil gases (carbon dioxide and radon) was undertaken in the village of Furnas, located in the caldera of an active volcano. A soil survey to map the area of soil gas flow was undertaken, gas emissions were monitored at fumaroles and in eight houses, and a preliminary radon survey of 23 houses in the main anomaly area was performed. Potential volcanic sources of toxic contamination of air, food, and water were also investigated, and ambient air quality was evaluated. About one-third (41 ha) of the houses were located in areas of elevated carbon dioxide soil degassing. Unventilated, confined spaces in some houses contained levels of carbon dioxide which could cause asphyxiation. Mean indoor radon levels exceeded UK and US action levels in the winter months. A tenfold increase in radon levels in one house over 2 h indicated that large and potentially lethal surges of carbon dioxide could occur without warning. Toxic exposures from the gaseous emissions and from contamination of soil and water were minimal, but sulphur dioxide levels were mildly elevated close to fumaroles. In contrast, evidence of dental fluorosis was manifested in the population of the nearby fishing village of Ribeira Quente where drinking water in the past had contained elevated levels of fluoride. The disaster potential of volcanic carbon dioxide in the area could also be associated with the hydrothermal system storing dissolved carbon dioxide beneath the village. Felt, or unfelt, seismic activity, or magma unrest, especially with a reawakening of explosive volcanic activity (30% probability in the next 100 years) could result in an increase in gas flow or even a gas burst from the hydrothermal system. A survey of all houses in Furnas is advised as structural measures to prevent the ingress of soil gases, including radon, were needed in some of the study houses. Evaluations of the human hazards of volcanic gases should be undertaken in all settlements in

  17. Insights from gas and water chemistry on the geothermal system of the Domuyo volcanic complex (Patagonia, Argentina)

    Science.gov (United States)

    Tassi, F.; Liccioli, C.; Chiodini, G.; Agusto, M.; Caselli, A. T.; Caliro, S.; Vaselli, O.; Pecoraino, G.

    2015-12-01

    This study focuses on the geochemistry of geothermal fluids discharging from the western flank of the Domuyo volcanic complex (Argentina), which is hosted within an extensional basins that interrupts the Andes at latitudes comprises between 35° and 39°S. The analytical results of gas and water samples collected during three sampling campaigns (2013, 2014 and 2015) are presented and discussed in order to: i) evaluate the equilibrium temperature(s) of the main fluid reservoir, ii) provide information on the origin of the fluid discharges and the secondary processes controlling their chemistry. Geothermometry based on the chemical composition of thermal waters indicates a maximum equilibrium temperature of 220 °C. This temperature, coupled with the measured amount of discharged Cl, suggest that the total energy released from this system is 1.1±0.2 GW. Atmospheric gases from a thick shallow aquifer contaminate most gas emissions, masking the chemical features of the deep fluid component, with the only exception of a jet fumarole located at 3,000 m a.s.l. (Bramadora). The H2O-CO2-CH4-H2-CO-C3H6-C3H8 composition of this gas emission was used to construct a geochemical conceptual model showing that the hydrothermal reservoir is liquid-dominated and thermally stratified, with temperatures ranging from 180 to 270 °C. The helium isotopic ratios (up to 6.8 Ra) and the δ13C-CO2 values (from -7.05 to -7.75 ‰ V-PDB) indicate that mantle degassing represents the dominant primary source for this dormant volcano. These results highlight the huge potential of this system as energy resource for the region. Accordingly, the regional authorities have recently planned and approved an investigation project aimed to provide further insights into the fluid geochemistry and the geostructural assessment in this promising area.

  18. Greenhouse Gas Emissions Calculator for Grain and Biofuel Farming Systems

    Science.gov (United States)

    McSwiney, Claire P.; Bohm, Sven; Grace, Peter R.; Robertson, G. Philip

    2010-01-01

    Opportunities for farmers to participate in greenhouse gas (GHG) credit markets require that growers, students, extension educators, offset aggregators, and other stakeholders understand the impact of agricultural practices on GHG emissions. The Farming Systems Greenhouse Gas Emissions Calculator, a web-based tool linked to the SOCRATES soil…

  19. Greenhouse Gas Emissions Calculator for Grain and Biofuel Farming Systems

    Science.gov (United States)

    McSwiney, Claire P.; Bohm, Sven; Grace, Peter R.; Robertson, G. Philip

    2010-01-01

    Opportunities for farmers to participate in greenhouse gas (GHG) credit markets require that growers, students, extension educators, offset aggregators, and other stakeholders understand the impact of agricultural practices on GHG emissions. The Farming Systems Greenhouse Gas Emissions Calculator, a web-based tool linked to the SOCRATES soil…

  20. Vapour transport of rare earth elements (REE) in volcanic gas: Evidence from encrustations at Oldoinyo Lengai

    Science.gov (United States)

    Gilbert, C. D.; Williams-Jones, A. E.

    2008-10-01

    Fumarolic encrustations and natrocarbonatite lava from the active crater of Oldoinyo Lengai volcano, Tanzania, were sampled and analysed. Two types of encrustation were distinguished on the basis of their REE content, enriched (~ 2800-5600 × [REE chondrite]) and depleted (~ 100-200 × [REE chondrite]) relative to natrocarbonatite (1700-1900 × [REE chondrite]. REE-enriched encrustations line the walls of actively degassing fumaroles, whereas REE-depleted encrustations occur mainly along cracks in and as crusts on cooling natrocarbonatite lava flows; one of the low REE encrustation samples was a stalactite from the wall of a possible fumarole. The encrustations are interpreted to have different origins, the former precipitating from volcanic gas and the latter from meteoric/ground water converted to steam by the heat of the overlying lava flow(s). REE-profiles of encrustations and natrocarbonatite are parallel, suggesting that there was no preferential mobilization of specific REE by either volcanic vapour or meteoric water vapour. The elevated REE-content of the first group of encrustations suggests that direct REE-transport from natrocarbonatite to volcanic vapour is possible. The REE trends observed in samples precipitating directly from the volcanic vapour cannot be explained by dry volatility based on the available data as there is no evidence in the encrustation compositions of the greatly enhanced volatility predicted for Yb and Eu. The observed extreme REE-fractionation with steep La/Sm slopes parallel to those of the natrocarbonatite reflects solvation and complexation reactions in the vapour phase that did not discriminate amongst the different REE or similar transport of REE in both the natrocarbonatite magma and its exsolving vapour. The low concentrations of REE in the encrustations produced by meteoric vapour suggest that the temperature was too low or that this vapour did not contain the ligands necessary to permit significant mobilization of the REE.

  1. Experimental study of jet gas-particle interaction generated during explosive volcanic eruptions

    Science.gov (United States)

    Medici, E. F.; Waite, G. P.

    2014-12-01

    During violent volcanic eruptions, a shock wave may be generated that is immediately followed by the formation of a supersonic jet. The overpressurized vapor-solid-liquid mixture being ejected begins to expand and accelerate. Oblique shock waves and rarefaction waves are generated at the edge of the crater. The oblique shock waves, inclined relatively to the flow axis, intersect forming a structure called a "Mach disk" or "Mach diamond". This pattern repeats until the jet decelerates into subsonic flow. In an explosive volcanic eruption, unlike other applications involving jets, a mixture of hot gas and solid particles is present. The mixture typically contains a relatively high percentage of solid particles of different sizes. The relationship between jet and particle is one the major parameters affecting the formation of ash plume dynamics and the pyroclastic flows. Therefore, a more comprehensive study is needed in order to understand the mixing occurring within the volcanic eruption jet, specifically, the effect of particle size and concentration. In this work, a series of analog explosive volcanic experiments using an atmospheric shock tube are performed to generate supersonic jets. High-speed video imaging of the expanding jet as well as the pressure evolution at different points in space are recorded for different values of initial energy and particle sizes and concentrations. Particles of different sizes and in various concentrations are placed inside the jet stream in which all the environmental conditions are monitored. Understanding of the coupling between the particles and the jet dynamics interaction is the first step toward a more thorough understanding of ash plume dynamics and the pyroclastic flows formation.

  2. Lifecycle greenhouse gas emissions of coal, conventional and unconventional natural gas for electricity generation

    Science.gov (United States)

    An analysis of the lifecycle greenhouse gas (GHG) emissions associated with natural gas use recently published by Howarth et al. (2011) stated that use of natural gas produced from shale formations via hydraulic fracturing would generate greater lifecycle GHG emissions than petro...

  3. Toxic fluoride gas emissions from lithium-ion battery fires.

    Science.gov (United States)

    Larsson, Fredrik; Andersson, Petra; Blomqvist, Per; Mellander, Bengt-Erik

    2017-08-30

    Lithium-ion battery fires generate intense heat and considerable amounts of gas and smoke. Although the emission of toxic gases can be a larger threat than the heat, the knowledge of such emissions is limited. This paper presents quantitative measurements of heat release and fluoride gas emissions during battery fires for seven different types of commercial lithium-ion batteries. The results have been validated using two independent measurement techniques and show that large amounts of hydrogen fluoride (HF) may be generated, ranging between 20 and 200 mg/Wh of nominal battery energy capacity. In addition, 15-22 mg/Wh of another potentially toxic gas, phosphoryl fluoride (POF3), was measured in some of the fire tests. Gas emissions when using water mist as extinguishing agent were also investigated. Fluoride gas emission can pose a serious toxic threat and the results are crucial findings for risk assessment and management, especially for large Li-ion battery packs.

  4. Delayed CO2 emissions from mid-ocean ridge volcanism as a possible cause of late-Pleistocene glacial cycles

    Science.gov (United States)

    Huybers, Peter; Langmuir, Charles H.

    2017-01-01

    The coupled 100,000 year variations in ice volume, temperature, and atmospheric CO2 during the late Pleistocene are generally considered to arise from a combination of orbital forcing, ice dynamics, and ocean circulation. Also previously argued is that changes in glaciation influence atmospheric CO2 concentrations through modifying subaerial volcanic eruptions and CO2 emissions. Building on recent evidence that ocean ridge volcanism responds to changes in sea level, here it is suggested that ocean ridges may play an important role in generating late-Pleistocene 100 ky glacial cycles. If all volcanic CO2 emissions responded immediately to changes in pressure, subaerial and ocean-ridge volcanic emissions anomalies would oppose one another. At ocean ridges, however, the egress of CO2 from the mantle is likely to be delayed by tens-of-thousands of years, or longer, owing to ascent time. A simple model involving temperature, ice, and CO2 is presented that oscillates at ∼100 ky time scales when incorporating a delayed CO2 contribution from ocean ridge volcanism, even if the feedback accounts for only a small fraction of total changes in CO2. Oscillations readily become phase-locked with insolation forcing associated with changes in Earth's orbit. Under certain parameterizations, a transition from ∼40 ky to larger ∼100 ky oscillations occurs during the middle Pleistocene in response to modulations in orbital forcing. This novel description of Pleistocene glaciation should be testable through ongoing advances in understanding the circulation of carbon through the solid earth.

  5. Analysis of carbon dioxide emission of gas fuelled cogeneration plant

    Science.gov (United States)

    Nordin, Adzuieen; Amin, M.; Majid, A.

    2013-12-01

    Gas turbines are widely used for power generation. In cogeneration system, the gas turbine generates electricity and the exhaust heat from the gas turbine is used to generate steam or chilled water. Besides enhancing the efficiency of the system, the process assists in reducing the emission of CO2 to the environment. This study analyzes the amount of CO2 emission by Universiti Teknologi Petronas gas fuelled cogeneration system using energy balance equations. The results indicate that the cogeneration system reduces the CO2 emission to the environment by 60%. This finding could encourage the power plant owners to install heat recovery systems to their respective plants.

  6. CO and PAH emissions from engines operating on producer gas

    DEFF Research Database (Denmark)

    Ahrenfeldt, Jesper

    2005-01-01

    . When the environmental effect of the emissions is discussed, unburned hydrocarbons in the form of methane is a strong greenhouse gas (21 times higher than CO2) will CO only indirectly through photochemical reactions is involved in the production of the greenhouse gas ozone. The destruction of CO...... low that no plant could uphold regulations without expensive equipment for after treatment of the emissions. CO emissions from engines operating on biomass producer gases are high, especially at very lean conditions where the emissions exceed the regulated value significantly. The high CO emissions...

  7. Drivers of the Growth in Global Greenhouse Gas Emissions

    NARCIS (Netherlands)

    Arto, Inaki; Dietzenbacher, Erik

    2014-01-01

    Greenhouse gas emissions increased by 8.9 Gigatons CO2 equivalent (Gt) in the period 1995-2008. A phenomenon that has received due attention is the upsurge of emission transfers via international trade. A question that has remained unanswered is whether trade changes have affected global emissions.

  8. Australia’s Consumption-based Greenhouse Gas Emissions

    DEFF Research Database (Denmark)

    Levitt, Clinton J.; Saaby, Morten; Sørensen, Anders

    2017-01-01

    We use data from the World Input-Output Database in a multiregional input–output model to analyse Australian consumption-based greenhouse gas emissions for the years 1995 to 2009. We find that the emission content of Australian macroeconomic activity has changed over the 15-year period. Consumpti...... consumption emissions. Our results suggest that tracking consumption emissions together with production emissions provides a more complete picture of Australian emissions.......-based emissions have been growing faster than production-based emissions since 2001. We show that emissions embodied in Australian imports are increasingly becoming a significant source of emissions. We investigate emissions in Australian imports and find that increased trade with China contributed substantially...

  9. Carbon dioxide emissions from Deccan volcanism and a K/T boundary greenhouse effect

    Science.gov (United States)

    Caldeira, Ken; Rampino, Michael R.

    1990-01-01

    A greenhouse warming caused by increased emissions of carbon dioxide from the Deccan Traps volcanism has been suggested as the cause of the terminal Cretaceous extinctions on land and in the sea. Total eruptive and noneruptive CO2 output by the Deccan eruptions (from 6 to 20 x 10 to the 16th moles) over a period of several hundred thousand years is estimated based on best estimates of the CO2 weight fraction of the original basalts and basaltic melts, the fraction of CO2 degassed, and the volume of the Deccan Traps eruptions. Results of a model designed to estimate the effects of increased CO2 on climate and ocean chemistry suggest that increases in atmospheric pCO2 due to Deccan Traps CO2 emissions would have been less than 75 ppm, leading to a predicted global warming of less than 1 C over several hundred thousand years. It is concluded that the direct climate effects of CO2 emissions from the Deccan eruptions would have been too weak to be an important factor in the end-Cretaceous mass extinctions.

  10. Developing and testing a low cost method for high resolution measurements of volcanic water vapour emissions at Vulcano and Mt. Etna

    Science.gov (United States)

    Pering, Tom D.; McGonigle, Andrew J. S.; Tamburello, Giancarlo; Aiuppa, Alessandro; Bitetto, Marcello; Rubino, Cosimo

    2015-04-01

    The most voluminous of emissions from volcanoes are from water vapour (H2O) (Carroll and Holloway, 1994), however, measurements of this species receive little focus due to the difficulty of independent measurement, largely a result of high atmospheric background concentrations which often undergo rapid fluctuations. A feasible method of measuring H2O emissions at high temporal and spatial resolutions would therefore be highly valuable. We describe a new and low-cost method combining modified web cameras (i.e. with infrared filters removed) with measurements of temperature and relative humidity to produce high resolution measurements (≈ 0.25 Hz) of H2O emissions. The cameras are affixed with near-infrared filters at points where water vapour absorbs (940 nm) and doesn't absorb (850 nm) incident light. Absorption of H2O is then determined by using Lambert-Beer's law on a pixel by pixel basis, producing a high spatial resolution image. The system is then calibrated by placing a Multi-GAS unit within the gas source and camera field-of-view, which measures; SO2, CO2, H2S and relative humidity. By combining the point measurements of the Multi-GAS unit with pixel values for absorption, first correcting for the width of the gas source (generally a Gaussian distribution), a calibration curve is produced which allows the conversion of absorption values to mass of water within a pixel. In combination with relative humidity measurements made outside of the plume it is then possible to subtract the non-volcanic background H2O concentration to produce a high resolution calibrated volcanic H2O flux. This technique is demonstrated in detail at the active fumarolic system on Vulcano (Aeolian Islands, Italy). Data processing and image acquisition was completed in Matlab® using a purpose built code. The technique is also demonstrated for the plume of the North-East Crater of Mt. Etna (Sicily, Italy). Here, contemporaneously acquired measurements of SO2 using a UV camera, combined

  11. Quantifying greenhouse gas emissions from waste treatment facilities

    DEFF Research Database (Denmark)

    Mønster, Jacob

    times and the emissions ranged from 2.6 to 60.8 kg methane per hour, with the lowest emissions from the oldest and smallest landfills and the highest emissions from the bigger landfills. It was not possible to correlate the measured emission with a single factor such a landfill age, size or mitigation...... gas, and that this error becomes smaller with increasing measurement distance. A measurement protocol was developed and the methane emission was quantified from a series of landfills with different size, age and gas recovery and mitigation conditions. The landfills were measured between one and four...... actions. As an example the highest emission was measured at a landfill with active methane recovery and utilization. Compared with national and European greenhouse gas reporting schemes the measurement showed a large difference, with reporting ranging a factor of 100 above to a factor of 10 below...

  12. Greenhouse Gas Emissions: Quantifying Methane Emissions from Livestock

    Directory of Open Access Journals (Sweden)

    Rafiu O. Yusuf

    2012-01-01

    Full Text Available Problem statement: The rearing of animals for domestic consumption and export invariably lead to the production of methane as a product of digestion. This study investigated the emission of methane from Malaysian livestock between 1980 and 2008. Approach: Seven categories of animals identified were camel, buffalo, sheep, goats, horse, pigs and poultry. The estimation of methane was based on the IPCC Tier 1 and Tier 2 methods. Methane emission from cattle rose by 44% within the period from 45.61-65.57 Gg. Results: Buffalo recorded a drop in methane emission by 54% from 17.12-7.86 Gg while the methane emission from sheep initially rose by 350% in 1992 only to drop by another 56% by 2008. Goats emission only declined by 17% from 1.79 Gg in 1980-1.49 Gg by 2008. Methane emission from horse has been consistent at around 0.14 Gg. The decreasing stock of pigs has led to a drop in methane emission from these set of animals with most of the emission coming from manure management. Conclusion: The healthy export market for poultry has seen a rise in methane emission by 274% from 2.18 Gg in 1980-8.17 Gg by 2008. The overall increase in methane emission from all the livestock is 20% from 81.83 Gg in 1980-98.76 Gg in 2008. With the aggressive drive of government to boost cattle and goat production, there is the likelihood of an increase in methane emission in the future and mitigation options will have to be applied.

  13. Greenhouse Gas Emissions from Agricultural Production

    DEFF Research Database (Denmark)

    Bennetzen, Eskild Hohlmann

    unit. This dissertation presents results and comprehensions from my PhD study on the basis of three papers. The overall aim has been to develop a new identity-based framework, the KPI, to estimate and analyse GHG emissions from agriculture and LUC and apply this on national, regional and global level....... The KPI enables combined analyses of changes in total emissions, emissions per area and emissions per product. Also, the KPI can be used to assess how a change in each GHG emission category affects the change in total emissions; thus pointing to where things are going well and where things are going less...... well in relation to what is actually produced. The KPI framework is scale independent and can be applied at any level from field and farm to global agricultural production. Paper I presents the first attempt to develop the KPI identity framework and, as a case study, GHG emissions from Danish crop...

  14. Water and gas geochemistry of the Calatrava Volcanic Province (CVP) hydrothermal system (Ciudad Real, central Spain)

    Science.gov (United States)

    Vaselli, Orlando; Nisi, Barbara; Tassi, Franco; Giannini, Luciano; Grandia, Fidel; Darrah, Tom; Capecchiacci, Francesco; del Villar, Pèrez

    2013-04-01

    An extensive geochemical and isotopic investigation was carried out in the water and gas discharges of the Late Miocene-Quaternary Calatrava Volcanic Province (CVP) (Ciudad Real, Spain) with the aim reconstruct the fluid circulation in the area. CVP consists of a series of scattered (monogenetic) vents from where alkaline lava flows and pyroclastic deposits formed in two different periods. The first stage (8.7-6.4 Ma) mainly included ultra-potassic mafic extrusives, whilst the second stage (4.7-1.75 Ma) prevalently originated alkaline and ultra-alkaline volcanics. Both stages were followed by a volcanic activity that extended up to 1.3 and 0.7 Ma, respectively. This area can likely be regarded as one of the most important emitting zones of CO2 in the whole Peninsular Spain along with that of Selva-Emporda in northeastern Spain (Cataluña) and it can be assumed as one of the best examples of natural analogues of CO2 leakages in Spain. This latter aspect is further evidenced by the relatively common water-gas blast events that characterize the CCVF. In the last few years the presence of a CO2-pressurized reservoir at a relatively shallow level as indeed caused several small-sized explosion particularly during the drilling of domestic wells. The fluid discharging sites are apparently aligned along well-defined directions: NW-SE and NNW-SSE and subordinately, ENE-WSW, indicating a clear relationship between the thermal discharges and the volcanic centers that also distribute along these lineaments. The CVP waters are mostly hypothermal (up to 33 °C) and are generally Mg(Ca)-HCO3 in composition and occasionally show relatively high concentrations of Fe and Mn, with pH and electrical conductivity down to 5.5 and up to 6.5 mS/cm, respectively. The oxygen and hydrogen isotopes suggest a meteoric origin for these waters. The mantle source of these volcanic products is apparently preserved in the many CO2-rich (up to 990,000 mmol/mol) gas discharges that characterize CVP

  15. Decoupling of greenhouse gas emissions from global agricultural production

    DEFF Research Database (Denmark)

    Bennetzen, Eskild Hohlmann; Smith, Pete; Porter, John Roy

    2016-01-01

    Since 1970 global agricultural production has more than doubled; contributing ~1/4 of total anthropogenic greenhouse gas (GHG) burden in 2010. Food production must increase to feed our growing demands, but to address climate change, GHG emissions must decrease. Using an identity approach, we...... estimate and analyse past trends in GHG emission intensities from global agricultural production and land-use change and project potential future emissions. The novel Kaya-Porter identity framework deconstructs the entity of emissions from a mix of multiple sources of GHGs into attributable elements...... allowing not only a combined analysis of the total level of all emissions jointly with emissions per unit area and emissions per unit product. It also allows us to examine how a change in emissions from a given source contributes to the change in total emissions over time. We show that agricultural...

  16. MaGa, a web-based collaborative database for gas emissions: a tool to improve the knowledge on Earth degassing

    Science.gov (United States)

    Frigeri, A.; Cardellini, C.; Chiodini, G.; Frondini, F.; Bagnato, E.; Aiuppa, A.; Fischer, T. P.; Lehnert, K. A.

    2014-12-01

    The study of the main pathways of carbon flux from the deep Earth requires the analysis of a large quantity and variety of data on volcanic and non-volcanic gas emissions. Hence, there is need for common frameworks to aggregate available data and insert new observations. Since 2010 we have been developing the Mapping Gas emissions (MaGa) web-based database to collect data on carbon degassing form volcanic and non-volcanic environments. MaGa uses an Object-relational model, translating the experience of field surveyors into the database schema. The current web interface of MaGa allows users to browse the data in tabular format or by browsing an interactive web-map. Enabled users can insert information as measurement methods, instrument details as well as the actual values collected in the field. Measurements found in the literature can be inserted as well as direct field observations made by human-operated instruments. Currently the database includes fluxes and gas compositions from active craters degassing, diffuse soil degassing and fumaroles both from dormant volcanoes and open-vent volcanoes from literature survey and data about non-volcanic emission of the Italian territory. Currently, MaGa holds more than 1000 volcanic plume degassing fluxes, data from 30 sites of diffuse soil degassing from italian volcanoes, and about 60 measurements from fumarolic and non volcanic emission sites. For each gas emission site, the MaGa holds data, pictures, descriptions on gas sampling, analysis and measurement methods, together with bibliographic references and contacts to researchers having experience on each site. From 2012, MaGa developments started to be focused towards the framework of the Deep Earth Carbon Degassing research initiative of the Deep Carbon Observatory. Whithin the DECADE initiative, there are others data systems, as EarthChem and the Smithsonian Institution's Global Volcanism Program. An interoperable interaction between the DECADE data systems is being

  17. Greenhouse Gas Emissions from Agricultural Production

    DEFF Research Database (Denmark)

    Bennetzen, Eskild Hohlmann

    at critical issues towards reducing our climate footprints. A logical next step for developing the concept of identities regarding food production could be to integrate this production-based framework with identities on consumption and economic development. It must be a scientific goal to illustrate how we...... unit. This dissertation presents results and comprehensions from my PhD study on the basis of three papers. The overall aim has been to develop a new identity-based framework, the KPI, to estimate and analyse GHG emissions from agriculture and LUC and apply this on national, regional and global level....... The KPI enables combined analyses of changes in total emissions, emissions per area and emissions per product. Also, the KPI can be used to assess how a change in each GHG emission category affects the change in total emissions; thus pointing to where things are going well and where things are going less...

  18. Generation of porphyry copper deposits by gas-brine reaction in volcanic arcs

    Science.gov (United States)

    Blundy, J.; Mavrogenes, J.; Tattitch, B.; Sparks, S.; Gilmer, A.

    2015-03-01

    Porphyry copper deposits, that is, copper ore associated with hydrothermal fluids rising from a magma chamber, supply 75% of the world's copper. They are typically associated with intrusions of magma in the crust above subduction zones, indicating a primary role for magmatism in driving mineralization. However, it is not clear that a single, copper-rich magmatic fluid could trigger both copper enrichment and the subsequent precipitation of sulphide ore minerals within a zone of hydrothermally altered rock. Here we draw on observations of modern subduction zone volcanism to propose an alternative process for porphyry copper formation. We suggest that copper enrichment initially involves metalliferous, magmatic hyper-saline liquids, or brines, that exsolve from large, magmatic intrusions assembled in the shallow crust over tens to hundreds of thousands of years. In a subsequent step, sulphide ore precipitation is triggered by the interaction of the accumulated brines with sulphur-rich gases, liberated in short-lived bursts from the underlying mafic magmas. We use high-temperature and high-pressure laboratory experiments to simulate such gas-brine interactions. The experiments yield copper-iron sulphide minerals and hydrogen chloride gas at magmatic temperatures of 700-800 °C, with textural and chemical characteristics that resemble those in porphyry copper deposits. We therefore conclude that porphyry copper ore forms in a two-stage process of brine enrichment followed by gas-induced precipitation.

  19. Greenhouse Gas Emissions: Quantifying Methane Emissions from Livestock

    OpenAIRE

    2012-01-01

    Problem statement: The rearing of animals for domestic consumption and export invariably lead to the production of methane as a product of digestion. This study investigated the emission of methane from Malaysian livestock between 1980 and 2008. Approach: Seven categories of animals identified were camel, buffalo, sheep, goats, horse, pigs and poultry. The estimation of methane was based on the IPCC Tier 1 and Tier 2 methods. Methane emission from cattle rose by 44% within the period from 45....

  20. Harmonization of initial estimates of shale gas life cycle greenhouse gas emissions for electric power generation.

    Science.gov (United States)

    Heath, Garvin A; O'Donoughue, Patrick; Arent, Douglas J; Bazilian, Morgan

    2014-08-05

    Recent technological advances in the recovery of unconventional natural gas, particularly shale gas, have served to dramatically increase domestic production and reserve estimates for the United States and internationally. This trend has led to lowered prices and increased scrutiny on production practices. Questions have been raised as to how greenhouse gas (GHG) emissions from the life cycle of shale gas production and use compares with that of conventionally produced natural gas or other fuel sources such as coal. Recent literature has come to different conclusions on this point, largely due to differing assumptions, comparison baselines, and system boundaries. Through a meta-analytical procedure we call harmonization, we develop robust, analytically consistent, and updated comparisons of estimates of life cycle GHG emissions for electricity produced from shale gas, conventionally produced natural gas, and coal. On a per-unit electrical output basis, harmonization reveals that median estimates of GHG emissions from shale gas-generated electricity are similar to those for conventional natural gas, with both approximately half that of the central tendency of coal. Sensitivity analysis on the harmonized estimates indicates that assumptions regarding liquids unloading and estimated ultimate recovery (EUR) of wells have the greatest influence on life cycle GHG emissions, whereby shale gas life cycle GHG emissions could approach the range of best-performing coal-fired generation under certain scenarios. Despite clarification of published estimates through harmonization, these initial assessments should be confirmed through methane emissions measurements at components and in the atmosphere and through better characterization of EUR and practices.

  1. Generation of porphyry copper deposits by gas-brine reaction in volcanic arcs

    Science.gov (United States)

    Blundy, Jon; Mavrogenes, John; Tattitch, Brian; Sparks, Steve; Gilmer, Amy

    2014-05-01

    Porphyry copper deposits (PCDs) are characterised by a close spatial and temporal association with small, hypabyssal intrusions of silicic magmas in volcanic arcs. PCD formation requires elevated chlorine and water to concentrate copper in magmatic hypersaline liquids (or brines), and elevated sulphur to precipitate copper-rich sulphides. These twin requirements are hard to reconcile with experimental and petrological evidence that voluminous chlorine-rich, hydrous silicic magmas, of the variety favourable to copper enrichment, lack sufficient sulphur to precipitate directly the requisite quantities of sulphides. These features are, however, consistent with observations of active volcanic arcs whereby PCDs can be viewed as roots of dome volcanoes above shallow reservoirs where silicic magmas accumulate over long time spans. During protracted periods of dormancy metal-enriched dense brines accumulate in and above the silicic reservoir through slow, low-pressure degassing. Meanwhile cogenetic volatile-rich mafic magmas and their exsolved, sulphur and CO2-rich fluids accumulate in deeper reservoirs. Periodic destabilisation of these reservoirs leads to short-lived bursts of volcanism liberating sulphurous gases, which react with the shallow-stored brines to form copper-rich sulphides and acidic vapours. We test this hypothesis with a novel set of 'porphyry in a capsule' experiments designed to simulate low-pressure (1-2 kbar) interaction of basalt-derived, sulphur-rich gases with brine-saturated, copper-bearing, but sulphur-free, granite. Experiments were run at 720-850 ° C in cold-seal apparatus with basaltic andesite, loaded with H2O and S, situated below dacite, loaded with H2O, Cl and Cu. At run conditions both compositions are substantially degassed and crystallized. S-rich gas from the basaltic andesite ascends to react with Cu-rich brines exsolved from the dacite, Our experiments reveal the direct precipitation of copper-sulphide minerals, in vugs and veins

  2. Greenhouse gas emissions in Hong Kong

    Science.gov (United States)

    Leung, D. Y. C.; Lee, Y. T.

    This study provides a quantitative review of the emissions of carbon dioxide (CO 2) and methane (CH 4), the two most significant greenhouse gases (GHGs) in Hong Kong. Study indicated that CO 2 accounts for 90% of the local GHG emissions in Hong Kong. Among the different types of fuels coal is identified as the major source of CO 2, which constitutes about 50% by fuel type. On the other hand, CH 4, which mainly comes from waste decomposition, contributes to 5% of the total GHG emissions. Correlation study revealed that energy consumption and waste quantity were strongly correlated with population and gross domestic products (GDP), implying that not much has been done in Hong Kong to re-mediate GHG emissions. Regression analysis concluded that supply side management (fuel switch) was more effective than demand side management (energy conservation) in mitigating CO 2 emissions in Hong Kong.

  3. Modelling combustion reactions for gas flaring and its resulting emissions

    Directory of Open Access Journals (Sweden)

    O. Saheed Ismail

    2016-07-01

    Full Text Available Flaring of associated petroleum gas is an age long environmental concern which remains unabated. Flaring of gas maybe a very efficient combustion process especially steam/air assisted flare and more economical than utilization in some oil fields. However, it has serious implications for the environment. This study considered different reaction types and operating conditions for gas flaring. Six combustion equations were generated using the mass balance concept with varying air and combustion efficiency. These equations were coded with a computer program using 12 natural gas samples of different chemical composition and origin to predict the pattern of emission species from gas flaring. The effect of key parameters on the emission output is also shown. CO2, CO, NO, NO2 and SO2 are the anticipated non-hydrocarbon emissions of environmental concern. Results show that the quantity and pattern of these chemical species depended on percentage excess/deficiency of stoichiometric air, natural gas type, reaction type, carbon mass content, impurities, combustion efficiency of the flare system etc. These emissions degrade the environment and human life, so knowing the emission types, pattern and flaring conditions that this study predicts is of paramount importance to governments, environmental agencies and the oil and gas industry.

  4. Characteristics of volcanic gas correlated to the eruption activity; Case study in the Merapi Volcano, periods of 1990-1994

    Directory of Open Access Journals (Sweden)

    Priatna Priatna

    2014-06-01

    Full Text Available http://dx.doi.org/10.17014/ijog.vol2no4.20074Volcanic gases, collected from Gendol and Woro solfatara fields, the summit of Merapi Volcano during 1990-1994, show an increase in chemical composition of H , CO, CO , SO , and HCl prior to the volcanic events, on the contrary to the drastic decreasing water vapour. The carbon/sulfur ratio of the volcanic gases lies between 1.5 and 5.7 which means that they were derived from the fresh magma. The Apparent Equilibrium Temperature (AET which is calculated from chemical compositions of volcanic gases using reaction of SO +3H = H S+2H O showed an increasing value prior to the volcanic events. The Merapi activities lasted during August 1990 to November 1994 showed a significant increase in ratio SO /H S prior to the November 1994 pyroclastic flow. The isotopic composition of volcanic gas condensates indicates that water vapour in Gendol is directly derived from the fresh magma. On the other hand, the contamination and cooling by the subsurface water occurred around the Woro field at a shallow part. 

  5. Improving material management to reduce greenhouse gas emissions

    NARCIS (Netherlands)

    Hekkert, Marko Peter

    2001-01-01

    Climate change due to greenhouse gas emissions caused by human actions is probably one of the major global environmental problems that we face today. In order to reduce the risk of climate change and the potential effects thereof, the emission of greenhouse gases like carbon dioxide (CO2) and methan

  6. Mitigating Greenhouse Gas and Ammonia Emissions from Swine Manure Management

    NARCIS (Netherlands)

    Wang, Yue; Dong, Hongmin; Zhu, Zhiping; Gerber, Pierre J.; Xin, Hongwei; Smith, Pete; Opio, Carolyn; Steinfeld, Henning; Chadwick, Dave

    2017-01-01

    Gaseous emissions from animal manure are considerable contributor to global ammonia (NH3) and agriculture greenhouse gas (GHG) emissions. Given the demand to promote mitigation of GHGs while fostering sustainable development of the Paris Agreement, an improvement of management systems

  7. Gas emission problems in starting the workings and controlling measures

    Energy Technology Data Exchange (ETDEWEB)

    Kunz, E. [Deutsche Montan Technologie GmbH, Essen (Germany)

    2001-07-01

    When a working is being started and especially if the face advances very quickly from the beginning, there may occur sudden releases of large gas amounts from the roof as well as from the floor. Apparently, this risk arises quite frequently if there are extremely solid rock layers of only few-meter thickness (up to 10 m) between the working seam and a gaseous seam within the area of gas emission. In the Ruhr deposit these layers consist of sandy shale and sandstones. Consequently, it is necessary to know the rock sequence and its mechanical characteristics in roof and floor for the early detection of gas outbursts. If a longwall is planned in a rock formation of this kind one has to prepare a preventive drilling scheme for the starting front and gas drainage should start already before the winning work. Experience in one working has shown that even in the immediate starting phase large gas amounts can be released and drained respectively. Models were built that represented different rock sequences and it was possible to simulate the processes that occured when the area of gas emissions was opening during the start of a working for these rock sequences. According to that one has to expect even an obstruction of gas emission under certain conditions. Additionally, such an obstruction of gas emission can be detected early, too, with the continuous calculation of the accumulated gas make which should be carried out from the first day of winning work. Normally, there is a continuously even increase. If the accumulated gas make levels off or even decreases, this is a clear sign for problems in the steady opening of the gas emission zone. 1 ref., 8 figs.

  8. Modeling of municipal greenhouse gas emissions. Calculation of greenhouse gas emissions and the reduction possibilities of Dutch municipalities

    NARCIS (Netherlands)

    Vries de, Willem

    2011-01-01

    Summary Municipalities represent an active governmental layer in the Netherlands. They often have ambitions to reduce greenhouse gas emissions. In this way the municipalities take responsibility to reduce the threat of global warming. To implement effect

  9. Greenhouse Gas Emissions from Stored Dairy Slurry from Multiple Farms.

    Science.gov (United States)

    Le Riche, Etienne L; VanderZaag, Andrew C; Wood, Jeffrey D; Wagner-Riddle, Claudia; Dunfield, Kari; Ngwabie, N Martin; McCabe, John; Gordon, Robert J

    2016-11-01

    A significant need exists to improve our understanding of the extent of greenhouse gas emissions from the storage of livestock manure to both improve the reliability of inventory assessments and the impact of beneficial management practice adoption. Factors affecting the extent and variability of greenhouse gas emissions from stored dairy manure were investigated. Emissions from six slurries stored in clean concrete tanks under identical "warm-season" conditions were monitored consecutively over 173 d (18°C average air temperature). Methane (CH) emissions varied considerably among the manures from 6.3 to 25.9 g m d and accounted for ∼96% of the total CO equivalent greenhouse gas emissions. The duration of the lag period, when methane emissions were near baseline levels, varied from 30 to 90 d from the beginning of storage. As a result, CH emissions were poorly correlated with air temperature prior to the time of peak emissions (i.e., the initial 48 to 108 d of storage) but improved afterward. The air temperature following the time of the peak CH flux and the length of the active methanogenesis period (i.e., when the daily CH emissions ≥ 7.6 g m d) were highly correlated with CH emissions ( = 0.98, < 0.01). Methane conversion factors (MCFs) ranged from 0.08 to 0.52 for the different manures. The MCFs generated from existing CH emission models were correlated ( = 0.68, = 0.02) to MCFs calculated for the active methanogenesis period for manure containing wood bedding. A temperature component was added that improved the accuracy ( = 0.82, < 0.01). This demonstrated that an improved understanding of lag period dynamics will enhance stored dairy manure greenhouse gas emission inventory calculations.

  10. Supply Chain Greenhouse Gas Management under Emission Trading

    OpenAIRE

    Li, Fang

    2016-01-01

    To curb global warming man has to reduce greenhouse gas emissions (GHGs) created to the atmosphere by human activities, and it cannot neglect the efforts of corporate communities. Indeed, companiesa direct emissions are dwarfed by supply chain GHGs from an industry sector. No matter to prepare for future environmental regulations or to improve competitive advantages, companies are realizing that they have to reduce and mitigate GHGs from the supply chain perspective. Emission trading (also ca...

  11. Greenhouse gas emissions from shallow uncovered coal seams

    Institute of Scientific and Technical Information of China (English)

    Saghafi Abouna

    2014-01-01

    This study discusses a method of quantifying emissions from surface coal mining that has been trialled in Australia. The method is based on direct measurement of surface emissions from uncovered coal seams in mine pits, concurrent measurement of residual gas content of blasted coal in mine pits, and measurement of pre-mining gas content of the same seam from cores retrieved from exploration boreholes drilled away from active mining. The results from one of the mines studied are presented in this paper. In this mine, the pre-mining gas content of the target seam was measured using cores from an exploration borehole away from active mining. Gas content varied from 0.7 to 0.8 m3/t and gas composition varied from 16% to 21% CH4 (84-79% CO2). In-pit measurements included seam surface emissions and residual gas content of blasted and ripped coal. Residual gas content varied from 0.09 to 0.15 m3/t, less than twofold across the mine pit. Composition of the residual gas was in general 90%CO2 and 10%CH4, with slight var-iation between samples. Coal seam surface emissions varied from 1.03 to 7.50 mL of CO2-e per minute and per square meter of the coal seam surface, a sevenfold variation across the mine pit.

  12. Methane emission in the gas industry of Russia; Emissions de methane dans l'industrie gaziere de la Russie

    Energy Technology Data Exchange (ETDEWEB)

    Sedykh, A.D. [Join-Stock Company Gazprom (Russian Federation); Gritsenko, A.I.; Akopova, G.S. [VNIIGAZ (Russian Federation); Maksimov, V.M. [Oil and Gas Research Institute (Russian Federation)

    2000-07-01

    The paper presents the methodology of methane emission estimation and the strategy of the gas industry of Russia in the limitation of natural gas emission into the atmosphere. Special attention is paid to the problem of relationship between natural gas and climate change. The results of actual leakage and technological natural gas emission measurement, methods and control means are given. Design options on methane emission reduction under different processes, gas leakage and accidents. (authors)

  13. Aviation response to a widely dispersed volcanic ash and gas cloud from the August 2008 eruption of Kasatochi, Alaska, USA

    Science.gov (United States)

    Guffanti, Marianne; Schneider, David J.; Wallace, Kristi L.; Hall, Tony; Bensimon, Dov R.; Salinas, Leonard J.

    2010-01-01

    The extensive volcanic cloud from Kasatochi's 2008 eruption caused widespread disruptions to aviation operations along Pacific oceanic, Canadian, and U.S. air routes. Based on aviation hazard warnings issued by the National Oceanic and Atmospheric Administration, U.S. Geological Survey, the Federal Aviation Administration, and Meteorological Service of Canada, air carriers largely avoided the volcanic cloud over a 5 day period by route modifications and flight cancellations. Comparison of time coincident GOES thermal infrared (TIR) data for ash detection with Ozone Monitoring Instrument (OMI) ultraviolet data for SO2 detection shows congruent areas of ash and gas in the volcanic cloud in the 2 days following onset of ash production. After about 2.5 days, the area of SO2 detected by OMI was more extensive than the area of ash indicated by TIR data, indicating significant ash depletion by fall out had occurred. Pilot reports of visible haze at cruise altitudes over Canada and the northern United States suggested that SO2 gas had converted to sulfate aerosols. Uncertain about the hazard potential of the aging cloud, airlines coped by flying over, under, or around the observed haze layer. Samples from a nondamaging aircraft encounter with Kasatochi's nearly 3 day old cloud contained volcanic silicate particles, confirming that some fine ash is present in predominantly gas clouds. The aircraft's exposure to ash was insufficient to cause engine damage; however, slightly damaging encounters with volcanic clouds from eruptions of Reventador in 2002 and Hekla in 2000 indicate the possibility of lingering hazards associated with old and/or diffuse volcanic clouds.

  14. Geochemical variability of hydrothermal emissions between three Pacific volcanic arc systems: Alaskan-Aleutian and Cascadian, North America and Taupo Volcanic Zone, New Zealand

    Science.gov (United States)

    Blackstock, J. M.; Horton, T. W.; Gravley, D. M.; Deering, C. D.

    2013-12-01

    Knowledge of the source, transport, and fate of hydrothermal fluids in the upper crust informs our understanding and interpretation of ore-forming processes, volcanogenic hazards, geothermal resources, and volatile cycling. Co-variation between fluid inclusion CO2/CH4 and N2/Ar ratios is an established tracer of magmatic, meteoric, and crustal fluid end-members. Yet, this tracer has had limited application to macroscopic fluid reservoirs accessible via geothermal wells and hydrothermal features (e.g. pools). In this study, we compared the covariance CO2/CH4 and N2/Ar ratios of gases collected throughout the Taupo Volcanic Zone, New Zealand (TVZ), the Alaska-Aleutian Volcanic Arc, USA (AAVA), and the Cascadian Volcanic Arc, USA (CVA) with corresponding δ13C and 3He/4He values. Our findings show that there is good agreement between these proxies for different end-member contributions at coarse scales. However, some samples classified as meteoric water according to the CO2/CH4 and N2/Ar ratios also show more positive δ13C values (~ -7.0 per mil) and relatively higher 3He/4He ratios indicative of magmatic input from primarily mantle sources. This unexpected result may be related to magmatic fluids, CO2 in particular, mixing with predominantly meteoric derived waters. The potential to identify magmatic CO2 in groundwater samples overlying geothermal systems in differing volcanic arc settings using simple and cost-effective gas ratios is a promising step forward in the search for ';surface blind' but developable geothermal systems and volcanic monitoring. 3He/4He anomalies also support this inference and underscore the potential decoupling of thermal anomalies and magmatic-derived fluids in the Earth's crust. The general agreement between the co-variation of CO2/CH4 and N2/Ar ratios with other isotope and geochemical proxies for magmatic, meteoric, and crustal end-members is encouraging to employ expanded use of these ratios for both the exploration and monitoring of

  15. Surface heat flow and CO2 emissions within the Ohaaki hydrothermal field, Taupo Volcanic Zone, New Zealand

    Science.gov (United States)

    Rissmann, C.; Christenson, B.; Werner, C.; Leybourne, M.; Cole, J.; Gravley, D.

    2012-01-01

    Carbon dioxide emissions and heat flow have been determined from the Ohaaki hydrothermal field, Taupo Volcanic Zone (TVZ), New Zealand following 20a of production (116MW e). Soil CO2 degassing was quantified with 2663 CO2 flux measurements using the accumulation chamber method, and 2563 soil temperatures were measured and converted to equivalent heat flow (Wm -2) using published soil temperature heat flow functions. Both CO2 flux and heat flow were analysed statistically and then modelled using 500 sequential Gaussian simulations. Forty subsoil CO 2 gas samples were also analysed for stable C isotopes. Following 20a of production, current CO2 emissions equated to 111??6.7T/d. Observed heat flow was 70??6.4MW, compared with a pre-production value of 122MW. This 52MW reduction in surface heat flow is due to production-induced drying up of all alkali-Cl outflows (61.5MW) and steam-heated pools (8.6MW) within the Ohaaki West thermal area (OHW). The drying up of all alkali-Cl outflows at Ohaaki means that the soil zone is now the major natural pathway of heat release from the high-temperature reservoir. On the other hand, a net gain in thermal ground heat flow of 18MW (from 25MW to 43.3??5MW) at OHW is associated with permeability increases resulting from surface unit fracturing by production-induced ground subsidence. The Ohaaki East (OHE) thermal area showed no change in distribution of shallow and deep soil temperature contours despite 20a of production, with an observed heat flow of 26.7??3MW and a CO 2 emission rate of 39??3T/d. The negligible change in the thermal status of the OHE thermal area is attributed to the low permeability of the reservoir beneath this area, which has limited production (mass extraction) and sheltered the area from the pressure decline within the main reservoir. Chemistry suggests that although alkali-Cl outflows once contributed significantly to the natural surface heat flow (~50%) they contributed little (99% of the original CO 2

  16. Attachment B: URS Shale Gas Emissions Analysis

    Science.gov (United States)

    This data was provided in response to a request by ANGA for actual current data that could be compared to EPA's assumptions used in the newly proposed Oil and Natural Gas Air Pollution Standards, Subpart quad 0

  17. Numerical investigation of gas-particle interaction in polydisperse volcanic jets

    Science.gov (United States)

    Carcano, Susanna; Esposti Ongaro, Tomaso; Bonaventura, Luca; Neri, Augusto

    2014-05-01

    We investigate the problem of underexpanded jet decompression when the injected fluid is a mixture of a gaseous phase and different classes of solid particles. The underexpanded multiphase jet problem is representative of phenomena that can be observed in the first stages of explosive volcanic eruptions. Whereas the case of homogeneous jets has been studied deeply in the literature, both experimentally, theoretically and numerically, the case of multiphase gas--particle jets still presents some open issues. It has been proven theoretically and experimentally that vents with supersonic or sonic velocity and gas pressure greater than the atmospheric one result in a rapid expansion and acceleration of the fluid to high Mach number. A series of expansion waves form and are reflected as compression waves at the flow boundary. The compression waves coealesce to form a standing normal shock wave (Mach disk), across which the fluid is rapidly compressed and decelerated to subsonic speeds. When solid particles are added to the gas flow, new phenomena associated to kinetic and thermal non-equilibrium between gas and particulate phases arise. Such effects are controlled by drag and heat exchange terms in the momentum and energy equations. In the present work we carry out two- and three-dimensional numerical simulations with the multiphase flow model PDAC (Neri et al., J. Geophys. Res, 2003; Carcano et al., Geosci. Mod. Dev., 2013), to identify and quantify non-equilibrium effects related to the interaction between the jet decompression structure and solid particles. We quantify, on a theoretical basis, the expected non-equilibrium effects between the gas and the solid phase in terms of the particle Stokes numer (St), i.e. the ratio between the particle relaxation time and a characteristic time scale of the jet (taken as the formation time of the Mach disk shock), for two sample grain-size distributions of natural events (Mount St. Helens, 1980; Vesuvius, aD 79). The Stokes

  18. Are there biomedical criteria to assess an acute carbon dioxide intoxication by a volcanic emission?

    Science.gov (United States)

    Stupfel, Maurice; Le Guern, François

    1989-11-01

    On August 21, 1987, more than 1800 people, thousands of head of cattle and countless wild animals, including birds, were killed by a gas release which occurred during about 4 hours at the lake in the crater Iwi at Nyos in Cameroon; plant life was mostly unaffected. An international inquiry was performed by British, French, Italian, Japanese and U.S. volcanologists and physicians to determine what had been the cause of this disaster. An international conference organised by United Nations Educational Scientific, and Cultural Organisation (U.N.E.S.C.O.), the Cameroon Government and the U.N. Economic Commission for Africa held in Yaoundé March, 1987 concluded: 'that the cause of sudden death was suffocation (asphyxia) in a carbon dioxide atmosphere' The medical findings have been explained by asphyxia caused by carbon dioxide. The presence of other volcanic gases, e.g. hydrogen sulfide, cannot be ruled out' (Sigvaldason, 1989, this issue). This paper reviews what is mainly known about an acute carbon dioxide intoxication in order to disprove or confirm the diagnosis and helps to interpret the field observations and testimonies to provide a basis to discuss the prevention of such an intoxication.

  19. Bioindication of volatile elements emission by the Puyehue-Cordón Caulle (North Patagonia) volcanic event in 2011.

    Science.gov (United States)

    Bubach, Débora; Pérez Catán, Soledad; Arribére, María; Guevara, Sergio Ribeiro

    2012-07-01

    The emission of volatile pollutants from the volcanic eruption of the Puyehue-Cordón Caulle complex (North Patagonia Andean Range) that started in June 4th, 2011, was investigated by bioindication means with the epyphytic fruticose lichen Usnea sp. The elemental composition of pooled samples made up with 10 lichen thalli were analysed by Instrumental Neutron Activation Analysis. Eleven sampling sites were selected within the impacted region at different distance from the volcanic source. Five sites were selected as they were already sampled in a previous study prior to the eruption. Two other new sampling sites were selected from outside the impacted zone to provide non-impacted baseline sites. The elements associated with the lichen incorporation of particulate matter (PM) of geological origin were identified by linear correlation with a geochemical tracer (Sm concentrations). The elements associated with PM uptake were Ce, Eu, Fe, Hf, La, Lu, Na, Nd, Sb, Sc, Se, Ta, Tb, Th, U, and Yb. Arsenic and Cs concentrations showed contributions exceeding the PM fraction in sites near the volcanic centre, also higher than the baseline concentrations, which could be associated with permanent emissions from the geothermal system of the Puyehue-Cordón Caulle complex. The lichen concentrations of Ba, Ca, Co, Hg, K, Rb, Sr, and Zn were not associated with the PM, not showing higher concentrations in the sites nearby the volcanic source or respect to the baseline values either. Therefore, there is no indication of the emission of volatile forms of these elements in the lichen records. The lichen records only identified Br volatile emissions associated with the Puyehue-Cordón Caulle complex eruption in 2011.

  20. Greenhouse Gas and Noxious Emissions from Dual Fuel Diesel and Natural Gas Heavy Goods Vehicles.

    Science.gov (United States)

    Stettler, Marc E J; Midgley, William J B; Swanson, Jacob J; Cebon, David; Boies, Adam M

    2016-02-16

    Dual fuel diesel and natural gas heavy goods vehicles (HGVs) operate on a combination of the two fuels simultaneously. By substituting diesel for natural gas, vehicle operators can benefit from reduced fuel costs and as natural gas has a lower CO2 intensity compared to diesel, dual fuel HGVs have the potential to reduce greenhouse gas (GHG) emissions from the freight sector. In this study, energy consumption, greenhouse gas and noxious emissions for five after-market dual fuel configurations of two vehicle platforms are compared relative to their diesel-only baseline values over transient and steady state testing. Over a transient cycle, CO2 emissions are reduced by up to 9%; however, methane (CH4) emissions due to incomplete combustion lead to CO2e emissions that are 50-127% higher than the equivalent diesel vehicle. Oxidation catalysts evaluated on the vehicles at steady state reduced CH4 emissions by at most 15% at exhaust gas temperatures representative of transient conditions. This study highlights that control of CH4 emissions and improved control of in-cylinder CH4 combustion are required to reduce total GHG emissions of dual fuel HGVs relative to diesel vehicles.

  1. Technology Opportunities to Reduce U.S. Greenhouse Gas Emissions

    Energy Technology Data Exchange (ETDEWEB)

    National Lab Directors, . .

    2001-04-05

    The rise in greenhouse gas emissions from fossil fuel combustion and industrial and agricultural activities has aroused international concern about the possible impacts of these emissions on climate. Greenhouse gases--mostly carbon dioxide, some methane, nitrous oxide and other trace gases--are emitted to the atmosphere, enhancing an effect in which heat reflected from the earth's surface is kept from escaping into space, as in a greenhouse. Thus, there is concern that the earth's surface temperature may rise enough to cause global climate change. Approximately 90% of U.S. greenhouse gas emissions from anthropogenic sources come from energy production and use, most of which are a byproduct of the combustion of fossil fuels. On a per capita basis, the United States is one of the world's largest sources of greenhouse gas emissions, comprising 4% of the world's population, yet emitting 23% of the world's greenhouse gases. Emissions in the United States are increasing at around 1.2% annually, and the Energy Information Administration forecasts that emissions levels will continue to increase at this rate in the years ahead if we proceed down the business-as-usual path. President Clinton has presented a two-part challenge for the United States: reduce greenhouse gas emissions and grow the economy. Meeting the challenge will mean that in doing tomorrow's work, we must use energy more efficiently and emit less carbon for the energy expended than we do today. To accomplish these goals, President Clinton proposed on June 26, 1997, that the United States ''invest more in the technologies of the future''. In this report to Secretary of Energy Pena, 47 technology pathways are described that have significant potential to reduce carbon dioxide emissions. The present study was completed before the December 1997 United Nations Framework Convention on Climate Change and is intended to provide a basis to evaluate technology

  2. Consequences of agro-biofuel production for greenhouse gas emissions

    DEFF Research Database (Denmark)

    Carter, Mette Sustmann; Hauggaard-Nielsen, Henrik; Johansen, Anders

    2009-01-01

    that accelerated emissions of N2O associated with the production of biomass for bio-fuel purposes will outweigh the avoided emissions of fossil fuel-derived CO2 (Crutzen et al., 2008). In the present study we examined the effects on N2O and CH4 emissions when residues from bio-energy production were recycled...... associated with the use of nitrogen based fertilizers in agricultural production. Replacing fossil fuel-derived energy by biomass-derived energy is commonly and with increasing emphasis proposed as a mean to mitigate the CO2 emissions. However, a recent analysis of global emission data proposes...... as fertilizer for a maize energy crop within an organic cropping system. Furthermore, we assessed sustainability in terms of greenhouse gasses for co-production of bio-ethanol and bio-gas from maize. This was compared to estimated greenhouse gas balances for rye and grass-clover as alternative raw materials....

  3. Liability rules for international trading of greenhouse gas emissions quotas

    DEFF Research Database (Denmark)

    Haites, E.; Missfeldt, F.

    2001-01-01

    To reduce the costs of mitigating greenhouse gas emissions in accordance with the Kyoto protocol, international trades of emissions quotas are allowed. The revenue from the sale of quotas may exceed the sanctions for non-compliance if these penalties are weak or poorly enforced. Under these circu......To reduce the costs of mitigating greenhouse gas emissions in accordance with the Kyoto protocol, international trades of emissions quotas are allowed. The revenue from the sale of quotas may exceed the sanctions for non-compliance if these penalties are weak or poorly enforced. Under...... these circumstances emissions trading enables a country to benefit financially through non-compliance. To counter non-compliance due to trading a range of liability proposals have been suggested. Using a simple global model, we analyze the economic and environmental performance of these proposals for the first...

  4. Inversion Technique for Estimating Emissions of Volcanic Ash from Satellite Imagery

    Science.gov (United States)

    Pelley, Rachel; Cooke, Michael; Manning, Alistair; Thomson, David; Witham, Claire; Hort, Matthew

    2014-05-01

    When using dispersion models such as NAME (Numerical Atmospheric-dispersion Modelling Environment) to predict the dispersion of volcanic ash, a source term defining the mass release rate of ash is required. Inversion modelling using observations of the ash plume provides a method of estimating the source term for use in NAME. Our inversion technique makes use of satellite retrievals, calculated using data from the SEVIRI (Spinning Enhanced Visible and Infrared Imager) instrument on-board the MSG (Meteosat Second Generation) satellite, as the ash observations. InTEM (Inversion Technique for Emission Modelling) is the UK Met Office's inversion modelling system. Recently the capability to estimate time and height varying source terms has been implemented and applied to volcanic ash. InTEM uses a probabilistic approach to fit NAME model concentrations to satellite retrievals. This is achieved by applying Bayes Theorem to give a cost function for the source term. Source term profiles with lower costs generate model concentrations that better fit the satellite retrievals. InTEM uses the global optimisation technique, simulated annealing, to find the minimum of the cost function. The use of a probabilistic approach allows the uncertainty in the satellite retrievals to be incorporated into the inversion technique. InTEM makes use of satellite retrievals of both ash column loadings and of cloud free regions. We present a system that allows InTEM to be used during an eruption. The system is automated and can produce source term updates up to four times a day. To allow automation hourly satellite retrievals of ash are routinely produced using conservative detection limits. The conservative detection limits provide good detection of the ash plume while limiting the number of false alarms. Regions which are flagged as ash contaminated or free from cloud (both meteorological and ash) are used in the InTEM system. This approach is shown to improve the concentrations in the

  5. Geochemistry of volcanic gas at the 2012-13 New Tolbachik eruption, Kamchatka

    Science.gov (United States)

    Chaplygin, I. V.; Lavrushin, V. Y.; Dubinina, E. O.; Bychkova, Y. V.; Inguaggiato, S.; Yudovskaya, M. A.

    2016-09-01

    We report measurements of the chemical and isotopic composition of gas emitted from the lava flow at the 2012-13 New Tolbachik eruption. Gas and condensate samples were taken from two vents over a lava tube in May 2013. The 1030 °C gas sample was collected in evacuated Giggenbach bottle from a periodically pumping-to-venting outlet above active lava flow ~ 300 m from Naboko cone. Concentrations of major components in the 1030 °C gas sample are (mol%): 95.5 H2O, 0.47 CO2, 2.01 SO2, 1.18 HCl, 0.34 HF that are within a range of gas compositions for subduction zone volcanoes. Isotopic analysis of He gives a corrected to atmosphere R/Ra ratio = 7.24 (He/Ne ratio = 1.41) that is close to MORB values. The 1030 °C condensate contained 9.7 ppm Cu, 2.5 ppm Zn, 1.5 ppm Tl, 20 ppb Re and 3 ppb Au, and can be considered as a representative sample for the metal composition of exsolved magmatic gases at the 2012-13 Tolbachik eruption. Isotopic data on the 1030 °C condensate (δ18O = 6.4‰, δD = - 32‰) indicate a magmatic source. Another condensate sample taken at 690 °C was found to be drastically different from the magmatic 1030 °C condensate. We suggest that the disproportional enrichment in trace elements of this 690 °C condensate as compared to the 1030 °C condensate could result from evaporation at forced pumping during sampling and possible dissolution of earlier precipitated sublimates in the gas conduit. Unusual isotopic composition of the 690 °C condensate (δ18O = 18.9‰, δD = - 68.5‰) can be explained by the isotopic exchange between volcanic vapor and atmospheric O2 (δ18O = 23.5‰).

  6. Exhaust Gas Recirculation in Gas Turbines for Reduction of CO2 Emissions; Combustion Testing with Focus on Stability and Emissions

    Directory of Open Access Journals (Sweden)

    Johan E. Hustad

    2005-12-01

    Full Text Available Exhaust gas recirculation can be applied with the intention of reducing CO2 emissions. When a fraction of the exhaust gas is injected in the entry of a gas turbine, the amount of CO2 in the exhaust gas not being recirculated will be higher and less complicated to capture. However, with this change in combustion air composition, especially the reduced concentration of oxygen, the combustion process will be affected. The lower oxygen concentration decreases the stability and the increased amount of CO2, H2O and N2 will decrease the combustion temperature and thus, the NOx emissions. Testing has been performed on a 65 kW gas turbine combustor, to investigate the effect of adding N2, CO2 and O2 in the combustion process, with focus on stability and emissions of NOx. Results show that adding N2 and CO2 decreases the NOx emissions, whereas O2 addition increases the NOx emissions. The tests have been performed both in a diffusion flame (pilot burner and a premixed flame (main burner, and for additives being injected with the fuel or with the air stream. Addition into the fuel stream is proven to affect the NOx emissions the most. The stability limits of the flames are indicated with respect to mass-based additive-to-fuel ratios.

  7. Thermal effects of massive CO2 emissions associated with subduction volcanism

    NARCIS (Netherlands)

    Schuiling, R.D.

    2004-01-01

    Large volumes of CO₂ are emitted during volcanic activity at convergent plate boundaries, not only from volcanic centers. Their C isotopic signature indicates that this CO₂ is mainly derived from the decarbonation of subducted limestones or carbonated metabasalts, not as often admitted from magma

  8. LOW NOx EMISSIONS IN A FUEL FLEXIBLE GAS TURBINE

    Energy Technology Data Exchange (ETDEWEB)

    Raymond Drnevich; James Meagher; Vasilis Papavassiliou; Troy Raybold; Peter Stuttaford; Leonard Switzer; Lee Rosen

    2004-08-01

    In alignment with Vision 21 goals, a study is presented here on the technical and economic potential for developing a gas turbine combustor that is capable of generating less that 2 ppm NOx emissions, firing on either coal synthesis gas or natural gas, and being implemented on new and existing systems. The proposed solution involves controlling the quantity of H2 contained in the fuel. The presence of H2 leads to increased flame stability such that the combustor can be operated at lower temperatures and produce less thermal NOx. Coal gas composition would be modified using a water gas shift converter, and natural gas units would implement a catalytic partial oxidation (CPOX) reactor to convert part of the natural gas feed to a syngas before fed back into the combustor. While both systems demonstrated technical merit, the economics involved in implementing such a system are marginal at best. Therefore, Praxair has decided not to pursue the technology any further at this time.

  9. Panel discussion: Gas emissions with diesel efficiency

    Energy Technology Data Exchange (ETDEWEB)

    Cole, J. [Southwest Research Inst., San Antonio, TX (United States)

    1997-12-31

    The second of three papers in the panel discussion outlined the characteristics of spark-ignited natural gas (SING) engines. Currently, the SING engine is considered less efficient than a diesel engine because of the reduced compression ratio, the use of air-throttles, retarded ignition for low NOx, and increased heat transfer. To improve upon these characteristics and to make the SING engine equal to, or even surpass the diesel engine in efficiency, more research work needs to be done on advanced controls. These include (knock, misfire, humidity detection), various ignition enhancements (variable energy/gap plug, long-life plug, laser ignition), and possibly camless operation (cylinder deactivation, throttleless operation). The late-cycle High Pressure Gas Injection (LaCHIP) as an alternate means of improving the efficiency of natural gas engines was also described.

  10. 75 FR 57275 - Information Collection; Supplier Greenhouse Gas Emissions Inventory Pilot

    Science.gov (United States)

    2010-09-20

    ... ADMINISTRATION Information Collection; Supplier Greenhouse Gas Emissions Inventory Pilot AGENCY: Federal... Supplier Greenhouse Gas (GHG) Emissions Inventory pilot. Public comments are particularly invited on... Supplier GHG Emissions Inventory pilot, and whether it will have practical utility; whether our estimate...

  11. Drought Impact on Fumarole Gas Composition at Lassen Volcanic National Park, CA.

    Science.gov (United States)

    Bergfeld, D.; Lewicki, J. L.; Hunt, A. G.

    2015-12-01

    Surface expressions of the hydrothermal system at Lassen Volcanic National Park include numerous solfataras to the south and southeast of Lassen Peak. Extensive sampling of gas for chemical and isotope analyses took place from the mid-1970s through 2000. Based on those data the model for the Lassen hydrothermal system suggests the main gas upflow occurs at Sulphur Works, which is part of a circulating hydrothermal flow cell (HC1) that includes Bumpass Hell and Little Hot Springs Valley (Janik & McLaren, 2010). A second, slightly cooler cell (HC2) provides gas and steam to Boiling Springs Lake, Devils Kitchen and ultimately to features at Terminal Geyser. As part of the USGS volcano monitoring effort, sampling of Lassen gases resumed in 2014. Gas compositions of boiling point and superheated fumaroles at four of the Lassen solfataras contained lower concentrations of meteoric-derived components than most early samples. In 2014 the combined N2 and Ar concentrations from the individual areas decreased on average by 50 to 65% relative to CO2. N2/Ar ratios also shifted away from the ratio in air-saturated water toward values as high as 171, consistent with a decline in meteoric water content. Concentrations of hydrothermal gases CO2, H2S, and CH4, and d13C-CO2 values are similar to the early data. Helium concentrations are variable and show no trends. Helium isotope ratios (Rc/RA) since 2007 from HC1 are between 6.9 and 7.5 and for HC2 are between 6.0 and 6.5. A 2014 Terminal Geyser sample had a value of 6.0. A longer record of helium isotope data is required to examine temporal trends. Water in the Lassen hydrothermal system is ultimately derived from rain and snowfall at higher elevations in the park. The area has experienced drought conditions since at least 2012. The 2014 dataset suggests that the drought may influence gas compositions by reducing the input of shallow meteoric water. Lassen gases from the California drought of 1976-1977 exhibit similar behavior.

  12. Capturing fugitive methane emissions from natural gas compressor buildings.

    Science.gov (United States)

    Litto, R; Hayes, R E; Liu, B

    2007-08-01

    Fugitive methane emissions account for about 50% of the greenhouse gas (GHG) emissions from the Canadian conventional oil and gas sector. Sources include leaks in natural gas transmission facilities such as pipelines and compressor stations. There are three sources of methane emissions in a compressor station. The first is emissions resulting from incomplete combustion in the engine; the second is leaks in valves, flanges and other equipment in the building; and the third results from instrument venting. Fugitive methane emissions may be in low concentration relative to air, and thus cannot be destroyed by conventional combustion (below flammability limits of about 5-16%). The present study investigates the feasibility of capturing methane emissions from a compressor station. Computer modelling of the flow patterns of lean methane emissions inside the building is used to show the influence of doors, vents and leak location. Simulations show that for a typical building most fugitive methane exits through the ridge vent provided that the main doors remain closed. When the extraction rate through the ridge vent is controlled, the methane concentration is at acceptable levels for destruction in a catalytic flow reverse reactor, that is, in the range of 0.1-1% by volume.

  13. Greenhouse Gas Emissions from Excavation on Residential Construction Sites

    Directory of Open Access Journals (Sweden)

    Perry Forsythe

    2014-12-01

    Full Text Available Despite considerable research concerning the manifestation of greenhouse gases in the usage of buildings, little has been done concerning emissions arising from the construction process itself. This paper specifically examines emissions arising from cut and fill excavation on residential construction sites. Even though such excavation is often seen as being economical in terms of providing a flat base for concrete raft slab construction, the environmental consequences of this approach need to be considered more fully in terms of impact on the environment. This is particularly important when steeply sloping sites are involved and for different soil types. The paper undertakes a study that quantitatively assesses the cumulative greenhouse gas emissions caused by cut and fill excavation on 52 residential projects in Australia for a range of slope and soil types. The paper presents results from the study and concludes that greenhouse gas emissions increase as site slope increases; the building footprint area (as distinct from Gross Floor Area, exposes the need to reduce the area of the building to reduce greenhouse gas emissions; excavation of rock soils creates higher emissions than other soil types; and cut and fill excavation on steeply slope sites increase emissions. Potential alternative construction includes suspended floor construction systems which involve less excavation.

  14. Greenhouse Gas Emissions from Excavation on Residential Construction Sites

    Directory of Open Access Journals (Sweden)

    Perry Forsythe

    2014-12-01

    Full Text Available Despite considerable research concerning the manifestation of greenhouse gases in the usage of buildings, little has been done concerning emissions arising from the construction process itself. This paper specifically examines emissions arising from cut and fill excavation on residential construction sites. Even though such excavation is often seen as being economical in terms of providing a flat base for concrete raft slab construction, the environmental consequences of this approach need to be considered more fully in terms of impact on the environment. This is particularly important when steeply sloping sites are involved and for different soil types. The paper undertakes a study that quantitatively assesses the cumulative greenhouse gas emissions caused by cut and fill excavation on 52 residential projects in Australia for a range of slope and soil types. The paper presents results from the study and concludes that greenhouse gas emissions increase as site slope increases; the building footprint area (as distinct from Gross Floor Area, exposes the need to reduce the area of the building to reduce greenhouse gas emissions; excavation of rock soils creates higher emissions than other soil types; and cut and fill excavation on steeply slope sites increase emissions. Potential alternative construction includes suspended floor construction systems which involve less excavation. 

  15. FETC Programs for Reducing Greenhouse Gas Emissions

    Energy Technology Data Exchange (ETDEWEB)

    Ruether, J.A.

    1998-02-01

    Mark Twain once quipped that everyone talks about the weather but no one does anything about it. With interest in global climate change on the rise, researchers in the fossil-energy sector are feeling the heat to provide new technology to permit continued use of fossil fuels but with reduced emissions of so-called `greenhouse gases.` Three important greenhouse gases, carbon dioxide, methane, and nitrous oxide, are released to the atmosphere in the course of recovering and combusting fossil fuels. Their importance for trapping radiation, called forcing, is in the order given. In this report, we briefly review how greenhouse gases cause forcing and why this has a warming effect on the Earth`s atmosphere. Then we discuss programs underway at FETC that are aimed at reducing emissions of methane and carbon dioxide.

  16. Greenhouse gas emissions during composting of dairy manure: Delaying pile mixing does not reduce overall emissions

    Science.gov (United States)

    The effect of the timing of pile mixing on greenhouse gas (GHG) emissions during dairy manure composting was determined using large flux chambers designed to completely cover replicate pilot-scale compost piles. GHG emissions from compost piles that were mixed at 2, 3, 4, or 5 weeks after initial c...

  17. Wellbeing Impacts of City Policies for Reducing Greenhouse Gas Emissions

    Directory of Open Access Journals (Sweden)

    Rosemary Hiscock

    2014-11-01

    Full Text Available To mitigate climate change, city authorities are developing policies in areas such as transportation, housing and energy use, to reduce greenhouse gas emissions. In addition to their effects on greenhouse gas emissions, these policies are likely to have consequences for the wellbeing of their populations for example through changes in opportunities to take physical exercise. In order to explore the potential consequences for wellbeing, we first explore what ‘wellbeing’ is and how it can be operationalised for urban planners. In this paper, we illustrate how wellbeing can be divided into objective and subjective aspects which can be measured quantitatively; our review of measures informs the development of a theoretical model linking wellbeing to policies which cities use to reduce greenhouse gas emissions. Finally, we discuss the extent to which the links proposed in the conceptual model are supported by the literature and how cities can assess wellbeing implications of policies.

  18. [Progress in research of urban greenhouse gas emission inventory].

    Science.gov (United States)

    Chen, Cao-Cao; Liu, Chun-Lan; Tian, Gang; Wang, Hai-Hua; Li, Zheng

    2010-11-01

    Urban areas carry main responsibility for consuming massive energy sources and make great contribution to global anthropogenic greenhouse gas emissions. City and local governments are seen to have a key role in climate mitigation. Hence,one of the important work concerns accounting for city greenhouse gas (GHG) emissions, because it plays significant role in setting reduction targets and evaluating success of local measures. However, open system architectures like city face many challenges for greenhouse gas accounting. Based on the review in details the methodology and case study, our study focuses on the difference and interconnection between country and city GHG accounts,and uncertainty of accounts. Further, we propose the valuable experience in order to improve domestic research on city GHG emission inventory.

  19. Plume Tracker: Interactive mapping of volcanic sulfur dioxide emissions with high-performance radiative transfer modeling

    Science.gov (United States)

    Realmuto, Vincent J.; Berk, Alexander

    2016-11-01

    We describe the development of Plume Tracker, an interactive toolkit for the analysis of multispectral thermal infrared observations of volcanic plumes and clouds. Plume Tracker is the successor to MAP_SO2, and together these flexible and comprehensive tools have enabled investigators to map sulfur dioxide (SO2) emissions from a number of volcanoes with TIR data from a variety of airborne and satellite instruments. Our objective for the development of Plume Tracker was to improve the computational performance of the retrieval procedures while retaining the accuracy of the retrievals. We have achieved a 300 × improvement in the benchmark performance of the retrieval procedures through the introduction of innovative data binning and signal reconstruction strategies, and improved the accuracy of the retrievals with a new method for evaluating the misfit between model and observed radiance spectra. We evaluated the accuracy of Plume Tracker retrievals with case studies based on MODIS and AIRS data acquired over Sarychev Peak Volcano, and ASTER data acquired over Kilauea and Turrialba Volcanoes. In the Sarychev Peak study, the AIRS-based estimate of total SO2 mass was 40% lower than the MODIS-based estimate. This result was consistent with a 45% reduction in the AIRS-based estimate of plume area relative to the corresponding MODIS-based estimate. In addition, we found that our AIRS-based estimate agreed with an independent estimate, based on a competing retrieval technique, within a margin of ± 20%. In the Kilauea study, the ASTER-based concentration estimates from 21 May 2012 were within ± 50% of concurrent ground-level concentration measurements. In the Turrialba study, the ASTER-based concentration estimates on 21 January 2012 were in exact agreement with SO2 concentrations measured at plume altitude on 1 February 2012.

  20. Limiting net greenhouse gas emissions in the United States

    Energy Technology Data Exchange (ETDEWEB)

    Bradley, R A; Watts, E C; Williams, E R [eds.

    1991-09-01

    In 2988 the Congress requested DOE produce a study on carbon dioxide inventory and policy to provide an inventory of emissions sources and to analyze policies to achieve a 20% reduction in carbon dioxide emissions in 5 to 10 years and a 50% reduction in 15 to 20 years. This report presents the results of that study. Energy and environmental technology data were analyzed using computational analysis models. This information was then evaluated, drawing on current scientific understanding of global climate change, the possible consequences of anthropogenic climate change (change caused by human activity), and the relationship between energy production and use and the emission of radiactively important gases. Topics discussed include: energy and environmental technology to reduce greenhouse gas emissions, fossil energy production and electricity generation technologies, nuclear energy technology, renewable energy technologies, energy storage, transmission, and distribution technology, transportation, technology, industrial technology, residential and commercial building technology, greenhouse gas removal technology, approaches to restructuring the demand for energy.

  1. The bulk isotopic composition of hydrocarbons in subaerial volcanic-hydrothermal emissions from different tectonic settings

    Science.gov (United States)

    Fiebig, J.; Tassi, F.; Vaselli, O.; Viveiros, M. F.; Silva, C.; Lopez, T. M.; D'Alessandro, W.; Stefansson, A.

    2015-12-01

    Assuming that methane and its higher chain homologues derive from a common source, carbon isotope patterns have been applied as a criterion to identify occurrences of abiogenic hydrocarbons. Based on these, it has been postulated that abiogenic hydrocarbon production occurs within several (ultra)mafic environments. More evolved volcanic-hydrothermal systems may also provide all the prerequisites necessary for abiogenic hydrocarbon production, such as availability of inorganic CO2, hydrogen and heat. We have investigated the chemical and isotopic composition of n-alkanes contained within subaerial hydrothermal discharges emitted from a range of hot spot, subduction and rift-related volcanoes to determine the origin of hydrocarbons in these systems. Amongst these are Nisyros (Greece), Vesuvio, Campi Flegrei, Ischia, Pantelleria and Vulcano (all Italy), Mt. Mageik and Trident (USA), Copahue (Argentina), Teide (Spain), Furnas and Fogo (Portugal). The carbon isotopic composition of methane emitted from these sites varies from -65 to -8‰ , whereas δ13C of ethane and propane exhibit a much narrower variation from -17‰ to -31‰. Methane that occurs most enriched in 13C is also characterized by relatively positive δD values ranging up to -80‰. Carbon isotope reversals between methane and ethane are only observed for locations exhibiting δ13C-CH4 values > -20‰, such as Teide, Pantelleria, Trident and Furnas. At Furnas, δ13C-CH4 varies by 50‰ within a relatively short distance of <50m between two vents, whereas δ13C-C2H6 varies by less than 2‰ only. For some of the investigated locations apparent carbon isotopic temperatures between methane and CO2 are in agreement with those derived from gas concentration geothermometers. At these locations methane, however seems to be in disequilibrium with ethane and propane. These findings imply that methane on the one hand and the C2+ hydrocarbons on the other hand often might derive from distinct sources.

  2. Greenhouse Gas Emissions From Energy Systems: Comparison And Overview

    Energy Technology Data Exchange (ETDEWEB)

    Dones, R.; Heck, T.; Hirschberg, S

    2004-03-01

    The paper provides an overview and comparison of Greenhouse Gas Emissions associated with fossil, nuclear and renewable energy systems. In this context both the direct technology-specific emissions and the contributions from full energy chains within the Life Cycle Assessment framework are considered. Examples illustrating the differences between countries and regional electricity mixes are also provided. Core results presented here are based on the work performed at PSI, and by partners within the Swiss Centre for Life-Cycle Inventories. (author)

  3. Innovative technologies for greenhouse gas emission reduction in steel production

    Directory of Open Access Journals (Sweden)

    D. Burchart-Korol

    2016-01-01

    Full Text Available The main goal of the study was to present the most significant technological innovations aiming at reduction of greenhouse gas emission in steel production. Reduction of greenhouse gas and dust pollution is a very important aspect in the iron and steel industry. New solutions are constantly being searched for to reduce greenhouse gases (GHG. The article presents the most recent innovative technologies which may be applied in the steel industry in order to limit the emission of GHG. The significance of CCS (CO2 Capture and Storage and CCU (CO2 Capture and Utilization in the steel industry are also discussed.

  4. Assessing the greenhouse gas emissions from poultry fat biodiesel

    DEFF Research Database (Denmark)

    Jørgensen, Andreas; Bikker, Paul; Herrmann, Ivan Tengbjerg

    2012-01-01

    original use. This implies that even though the use of biodiesel is assumed to displace petrochemical diesel, the ‘original user’ of the poultry fat will have to find a substitute, whose production leads to a greenhouse gas emissions comparable to what is saved through driving on poultry fat biodiesel...... rather than petrochemical diesel. Given that it is the production of the substitute for the poultry fat which mainly eliminates the benefit from using poultry fat for biodiesel, it is argued that whenever assessing the greenhouse gas emissions from biodiesel made from by-products (such as rendered animal...

  5. A Survey of Methane Emissions from California's Natural Gas Infrastructure

    Science.gov (United States)

    Fischer, M. L.; Cui, X.; Jeong, S.; Conley, S. A.; Mehrotra, S.; Faloona, I. C.; Chen, T.; Blake, D. R.; Clements, C. B.; Lareau, N.; Lloyd, M.; Fairley, D.

    2015-12-01

    Methane emissions from natural gas infrastructure are estimated to contribute small but uncertain fractions of total natural gas consumed in California and of California's total GHG budget. Because natural gas (NG) methane is an energy resource, an economic commodity, a potential health hazard, and a potent greenhouse gas, it is important to identify and quantify and control both intentional venting, and un-intentional leakages. Here, we report results of an observational survey, measuring NG methane emissions across examples from subsectors of California's natural gas infrastructure, ranging from production and processing, to transmission and distribution, and notably including examples from the consumption subsector. At regional scales, a combination of tower and aircraft measurements are used to estimate emissions of NG methane for the San Francisco Bay Area. At facility scales, aircraft mass balance measurements are applied to estimate NG methane emissions from associated with individual petroleum production fields, NG storage facilities, and petroleum refineries. At local scales, ground-based roadway surveys are applied to place lower limits on NG emissions from aggregate leakage sources in selected urban and suburban areas, a sample of NG fueling stations, and a small number of capped gas wells. For a subset of the consumption subsector, mass balance and CH4:CO2 emission ratio measurements are used to estimate leakage from a sample of quiescent residential buildings and example operating gas appliances. In general, CH4 emissions are found to grow with the NG throughput in a given area or facility, though the observed ratio of leakage to throughput varies by more than an order of magnitude for some cases (e.g., urban areas), presumably in response to varied infrastructure type, vintage, and maintenance. Taken in sum, preliminary results of this initial survey are consistent with the commonly held assumption that total NG methane emissions from California NG

  6. Addressing biogenic greenhouse gas emissions from hydropower in LCA.

    Science.gov (United States)

    Hertwich, Edgar G

    2013-09-03

    The ability of hydropower to contribute to climate change mitigation is sometimes questioned, citing emissions of methane and carbon dioxide resulting from the degradation of biogenic carbon in hydropower reservoirs. These emissions are, however, not always addressed in life cycle assessment, leading to a bias in technology comparisons, and often misunderstood. The objective of this paper is to review and analyze the generation of greenhouse gas emissions from reservoirs for the purpose of technology assessment, relating established emission measurements to power generation. A literature review, data collection, and statistical analysis of methane and CO2 emissions are conducted. In a sample of 82 measurements, methane emissions per kWh hydropower generated are log-normally distributed, ranging from micrograms to 10s of kg. A multivariate regression analysis shows that the reservoir area per kWh electricity is the most important explanatory variable. Methane emissions flux per reservoir area are correlated with the natural net primary production of the area, the age of the power plant, and the inclusion of bubbling emissions in the measurement. Even together, these factors fail to explain most of the variation in the methane flux. The global average emissions from hydropower are estimated to be 85 gCO2/kWh and 3 gCH4/kWh, with a multiplicative uncertainty factor of 2. GHG emissions from hydropower can be largely avoided by ceasing to build hydropower plants with high land use per unit of electricity generated.

  7. Inclusion of Ash and SO2 emissions from volcanic eruptions in WRF-CHEM: development and some applications

    Directory of Open Access Journals (Sweden)

    S. Peckham

    2012-09-01

    Full Text Available We describe a new functionality within the Weather Research and Forecasting model with coupled Chemistry (WRF-Chem that allows simulating emission, transport, dispersion, transformation and sedimentation of pollutants released during volcanic activities. Emissions from both an explosive eruption case and relatively calm degassing situation are considered using the most recent volcanic emission databases. A preprocessor tool provides emission fields and additional information needed to establish the initial three-dimensional cloud umbrella/vertical distribution within the transport model grid, as well as the timing and duration of an eruption. From this source condition, the transport, dispersion and sedimentation of the ash-cloud can be realistically simulated by WRF-Chem using its own dynamics, physical parameterization as well as data assimilation. Examples of model validation include a comparison of tephra fall deposits from the 1989 eruption of Mount Redoubt (Alaska, and the dispersion of ash from the 2010 Eyjafjallajökull eruption in Iceland. Both model applications show good coincidence between WRF-Chem and observations.

  8. Inclusion of ash and SO2 emissions from volcanic eruptions in WRF-Chem: development and some applications

    Directory of Open Access Journals (Sweden)

    M. Stuefer

    2013-04-01

    Full Text Available We describe a new functionality within the Weather Research and Forecasting (WRF model with coupled Chemistry (WRF-Chem that allows simulating emission, transport, dispersion, transformation and sedimentation of pollutants released during volcanic activities. Emissions from both an explosive eruption case and a relatively calm degassing situation are considered using the most recent volcanic emission databases. A preprocessor tool provides emission fields and additional information needed to establish the initial three-dimensional cloud umbrella/vertical distribution within the transport model grid, as well as the timing and duration of an eruption. From this source condition, the transport, dispersion and sedimentation of the ash cloud can be realistically simulated by WRF-Chem using its own dynamics and physical parameterization as well as data assimilation. Examples of model applications include a comparison of tephra fall deposits from the 1989 eruption of Mount Redoubt (Alaska and the dispersion of ash from the 2010 Eyjafjallajökull eruption in Iceland. Both model applications show good coincidence between WRF-Chem and observations.

  9. Enhanced nighttime gas emissions from a lake

    Science.gov (United States)

    Podgrajsek, E.; Sahlée, E.; Rutgersson, A.

    2016-05-01

    Methane (CH4) and carbon dioxide (CO2) are two important greenhouse gases. Previous studies have shown that lakes can be important natural sources of atmospheric CH4 and CO2. It is therefore important to monitor the fluxes of these gases between lakes and the atmosphere in order to understand the processes that govern the exchange. Most previous lake flux studies are based on chamber measurements, by using the eddy covariance method, the resolution in time and in space of the fluxes is increased, which gives more information on the governing processes. Eddy covariance measurements at a Swedish lake show that both methane fluxes (FCH4 ) and carbon dioxide fluxes (FCO2 ) experience high nighttime fluxes for a large part of the data set (largest median FCH4night ≈ 13 nmol m2 s-1 and smallest median FCH4day ≈ 4.0 nmol m-2 s-1, largest median FCO2night ≈ 0.2 μmol m2 s-1 and smallest median FCO2day ≈ 0.02 μmol m-2 s-1, with larger variability during night). For the diel cycle of the CH4 fluxes it is suggested that water side convection could enhance the transfer velocity, transport CH4 rich water to the surface, as well as trigger ebullition. The high nighttime CO2 fluxes could to a large extent be explained with enhanced transfer velocities due to water side convection. If gas fluxes are not measured during nighttime, when water side convection normally is generated, periods of potential high gas flux might be missed and estimations of the total amount of gas released from lakes to the atmosphere will be biased.

  10. METHANE EMISSIONS FROM THE NATURAL GAS INDUSTRY VOLUME 15: GAS-ASSISTED GLYCOL PUMPS

    Science.gov (United States)

    The 15-volume report summarizes the results of a comprehensive program to quantify methane (CH4) emissions from the U.S. natural gas industry for the base year. The objective was to determine CH4 emissions from the wellhead and ending downstream at the customer's meter. The accur...

  11. Improving Empirical Approaches to Estimating Local Greenhouse Gas Emissions

    Science.gov (United States)

    Blackhurst, M.; Azevedo, I. L.; Lattanzi, A.

    2016-12-01

    Evidence increasingly indicates our changing climate will have significant global impacts on public health, economies, and ecosystems. As a result, local governments have become increasingly interested in climate change mitigation. In the U.S., cities and counties representing nearly 15% of the domestic population plan to reduce 300 million metric tons of greenhouse gases over the next 40 years (or approximately 1 ton per capita). Local governments estimate greenhouse gas emissions to establish greenhouse gas mitigation goals and select supporting mitigation measures. However, current practices produce greenhouse gas estimates - also known as a "greenhouse gas inventory " - of empirical quality often insufficient for robust mitigation decision making. Namely, current mitigation planning uses sporadic, annual, and deterministic estimates disaggregated by broad end use sector, obscuring sources of emissions uncertainty, variability, and exogeneity that influence mitigation opportunities. As part of AGU's Thriving Earth Exchange, Ari Lattanzi of City of Pittsburgh, PA recently partnered with Dr. Inez Lima Azevedo (Carnegie Mellon University) and Dr. Michael Blackhurst (University of Pittsburgh) to improve the empirical approach to characterizing Pittsburgh's greenhouse gas emissions. The project will produce first-order estimates of the underlying sources of uncertainty, variability, and exogeneity influencing Pittsburgh's greenhouse gases and discuss implications of mitigation decision making. The results of the project will enable local governments to collect more robust greenhouse gas inventories to better support their mitigation goals and improve measurement and verification efforts.

  12. Simulated effects of changes in direct and diffuse radiation on canopy scale isoprene emissions from vegetation following volcanic eruptions

    Directory of Open Access Journals (Sweden)

    D. J. Wilton

    2011-11-01

    Full Text Available Volcanic eruptions can alter the quality of incoming solar irradiance reaching the Earth's surface thereby influencing the interactions between vegetation and the Earth system. Isoprene (C5H8 is a biogenic volatile organic compound emitted from leaves at a rate that is strongly dependent on the received flux of photosynthetically active radiation (PAR. We used a theoretical approach to investigate the potential for volcanic eruptions to change the isoprene flux from terrestrial forests using canopy-scale isoprene emission simulations that vary either the relative or absolute amount of diffuse (Idiff and direct (Idir PAR. According to our simulations for a northern hardwood deciduous forest, if the total amount of PAR during summer remains constant while the proportion of Idiff increases, canopy-scale isoprene emissions increase. This effect increases as leaf area index (LAI increases. Simulating a decrease in the total amount of PAR, and a corresponding increase in Idiff fraction, as measured during the 1992 Pinatubo eruption, changes daily total canopy-scale isoprene emissions from terrestrial vegetation in summertime by +2.8% and −1.4% for LAI of 6 and 2, respectively. These effects have not previously been realized or quantified. Better capturing the effects of volcanic eruptions (and other major perturbations to the atmospheric aerosol content on isoprene emissions from the terrestrial biosphere, and hence on the chemistry of the atmosphere, therefore may require inclusion of the effects of aerosols they produce on climate and the quality of PAR.

  13. Compendium of Greenhouse Gas Emissions Estimation Methodologies for the Oil and Gas Industry

    Energy Technology Data Exchange (ETDEWEB)

    Shires, T.M.; Loughran, C.J. [URS Corporation, Austin, TX (United States)

    2004-02-01

    This document is a compendium of currently recognized methods and provides details for all oil and gas industry segments to enhance consistency in emissions estimation. This Compendium aims to accomplish the following goals: Assemble an expansive collection of relevant emission factors for estimating GHG emissions, based on currently available public documents; Outline detailed procedures for conversions between different measurement unit systems, with particular emphasis on implementation of oil and gas industry standards; Provide descriptions of the multitude of oil and gas industry operations, in its various segments, and the associated emissions sources that should be considered; and Develop emission inventory examples, based on selected facilities from the various segments, to demonstrate the broad applicability of the methodologies. The overall objective of developing this document is to promote the use of consistent, standardized methodologies for estimating GHG emissions from petroleum industry operations. The resulting Compendium documents recognized calculation techniques and emission factors for estimating GHG emissions for oil and gas industry operations. These techniques cover the calculation or estimation of emissions from the full range of industry operations - from exploration and production through refining, to the marketing and distribution of products. The Compendium presents and illustrates the use of preferred and alternative calculation approaches for carbon dioxide (CO2), methane (CH4), and nitrous oxide (N2O) emissions for all common emission sources, including combustion, vented, and fugitive. Decision trees are provided to guide the user in selecting an estimation technique based on considerations of materiality, data availability, and accuracy. API will provide (free of charge) a calculation tool based on the emission estimation methodologies described herein. The tool will be made available at http://ghg.api.org/.

  14. Monitoring of volcanic SO2 emissions using the GOME-2 instrument

    Science.gov (United States)

    Hedelt, Pascal; Valks, Pieter; Loyola, Diego

    2014-05-01

    This contribution focusses on the GOME-2 SO2 column products from the METOP-A and B satellites. The GOME-2 SO2 column product has been developed in the framework of EUMETSAT's Satellite Application Facility on Ozone and Atmospheric Chemistry Monitoring (O3M-SAF). Satellite-based remote sensing measurements of volcanic SO2 provide critical information for reducing volcanic hazards. Volcanic eruptions may bring ash and gases (e.g. SO2) high up into the atmosphere, where a long-range transport can occur. SO2 is an important indicator for volcanic activity and an excellent tracer for volcanic eruption clouds, especially if ash detection techniques fail. SO2 can affect aviation safety: In the cabin it can cause disease and respiratory symptoms, whereas in its hydrogenated form H2SO4 it is highly corrosive and can cause damage to jet engines as well as pitting of windscreens. We will present results for volcanic events retrieved from GOME-2 solar backscattered measurements in the UV wavelength region around 320nm using the Differential Optical Absorption Spectroscopy (DOAS) method. SO2 columns are generated operationally by DLR with the GOME Data Processor (GDP) version 4.7 and are available in near-real-time, i.e. within two hours after sensing. Using data from both MetOp satellites allows for a daily global coverage. We will furthermore present current improvements to the GOME-2 SO2 column product.

  15. Re-processing TOMS UV Measurements to Retrieve SO2 Emissions From Volcanic Eruptions

    Science.gov (United States)

    Fisher, B. L.; Krotkov, N. A.; Bhartia, P. K.; Li, C.; Haffner, D. P.; Leonard, P.; Carn, S. A.; Telling, J. W.

    2015-12-01

    The SO2 Monitoring Group at the NASA Goddard Space Flight Center is producing a new multi-satellite long term data set of volcanic SO2 column amounts and heights (MSVOLSO2L4) as part of the NASA MEaSUREs Program. Here we present re-analysis of the UV measurements (BUV) from the NASA Nimbus 7 Total Ozone Mapping Spectrometer (N7 TOMS: 1978-1993). Ozone is the dominant atmospheric absorber in the BUV spectrum, but volcanic eruptions can produce enough SO2 to be distinguished from ozone background. Quantitative retrieval of volcanic SO2 requires:1) Separation of the O3 and SO2 absorption in BUV radiances;2) Close to zero mean SO2 background;3) RT forward model that accounts for the presence of volcanic ash in the plume; 4) A priori knowledge of the ozone and SO2 vertical profiles.Our iterative retrieval algorithm returns O3 and SO2 column amounts, effective reflectivity and its spectral slope. The retrieval model also generates a 4 x 4 gain matrix for the SO2 free regions that is used to soft calibrate the measured 340 nm BUV radiance. The spectral slope implicitly accounts for the interference of volcanic ash, but more explicit ash treatment is required to better quantify SO2 errors in volcanic plumes heavily loaded with ash. This presentation will discuss the methods used to characterize the error sources and assess the quality of this unique long-term SO2 data set.

  16. Reducing the Green House Gas Emissions from the Transportation Sector

    Directory of Open Access Journals (Sweden)

    Oyewande Akinnikawe

    2010-02-01

    Full Text Available In the United States, two thirds of the carbon monoxide and about one third of carbon dioxide emissions come from the transportation sector. Ways to reduce these emissions in the future include replacing gasoline and diesel by biofuels, or by blend of biofuels with conventional gasoline and diesel, or by compressed natural gas (CNG, or by replacing internal combustion engines by electric motors powered by hydrogen fuel cells or battery-powered electric vehicles recharged from the electric grid. This presentation will review these technologies the fuel production pathways, when they are likely to be available, and by what fraction transportation sector green house gas emissions could be reduced by each. A well-to-wheels (WTW analysis is performed on each vehicle/ fuel technology using the GREET model and the total energy use, the CO 2 emissions, NO x emissions, SO x emissions for the life cycle of the vehicle technologies are calculated. Prospects for reducing foreign oil dependence as well as mitigating green house gases emission from the transportation sector will be considered in the analysis.

  17. Reducing greenhouse gas emissions in Czechoslovakia

    Energy Technology Data Exchange (ETDEWEB)

    Kostalova, M. (Office of International Economic Corp., Ministry of Foreign Affairs, Prague (Czechoslovakia)); Suk, J. (Inst. for Forecasting, Czechoslovak Academy of Sciences, Prague (Czechoslovakia)); Kolar, S. (Pacific Northwest Lab., Richland, WA (United States))

    1991-12-01

    In this paper are presented important findings on the potential for energy conservation and carbon emissions reduction over the coming decades in Czechoslovakia. The authors describe the state of the energy use in Czechoslovakia today and the measures required to transform its energy system to a market-based economy oriented towards the environmental goal of decreased energy intensity. This work furthers our understanding of the need for energy efficiency in the newly forming market economies of East and Central Europe. This paper is part of a series of country studies sponsored by the Global Climate Division of the Office of Policy, Planning, and Evaluation, United States Environmental Protection Agency (EPA). We have completed similar studies in Canada, the former Soviet Union, France, Hungary, Italy, Japan, Poland the United Kingdom, and the United States. Research is currently underway or planned in Bulgaria, Romania, and Ukraine.

  18. Evaluation of Reformer Produced Synthesis Gas for Emissions Reductions in Natural Gas Reciprocating Engines

    Energy Technology Data Exchange (ETDEWEB)

    Mark Scotto

    2010-05-30

    Rolls-Royce Fuel Cell Systems (US) Inc. (RRFCS) has developed a system that produces synthesis gas from air and natural gas. A near-term application being considered for this technology is synthesis gas injection into reciprocating engines for reducing NO{sub x} emissions. A proof of concept study using bottled synthesis gas and a two-stroke reciprocating engine showed that injecting small amounts of high-flammable content synthesis gas significantly improved combustion stability and enabled leaner engine operation resulting in over 44% reduction in NO{sub x} emissions. The actual NO{sub x} reduction that could be achieved in the field is expected to be engine specific, and in many cases may be even greater. RRFCS demonstrated that its synthesis gas generator could produce synthesis gas with the flammable content that was successfully used in the engine testing. An economic analysis of the synthesis gas approach estimates that its initial capital cost and yearly operating cost are less than half that of a competing NO{sub x} reduction technology, Selective Catalytic Reduction. The next step in developing the technology is an integrated test of the synthesis gas generator with an engine to obtain reliability data for system components and to confirm operating cost. RRFCS is actively pursuing opportunities to perform the integrated test. A successful integrated test would demonstrate the technology as a low-cost option to reduce NO{sub x} emissions from approximately 6,000 existing two-stroke, natural gas-fired reciprocating engines used on natural gas pipelines in North America. NO{sub x} emissions reduction made possible at a reasonable price by this synthesis gas technology, if implemented on 25% of these engines, would be on the order of 25,000 tons/year.

  19. Evaluation of Reformer Produced Synthesis Gas for Emissions Reductions in Natural Gas Reciprocating Engines

    Energy Technology Data Exchange (ETDEWEB)

    Mark V. Scotto; Mark A. Perna

    2010-05-30

    Rolls-Royce Fuel Cell Systems (US) Inc. (RRFCS) has developed a system that produces synthesis gas from air and natural gas. A near-term application being considered for this technology is synthesis gas injection into reciprocating engines for reducing NOx emissions. A proof of concept study using bottled synthesis gas and a two-stroke reciprocating engine showed that injecting small amounts of highflammables content synthesis gas significantly improved combustion stability and enabled leaner engine operation resulting in over 44% reduction in NOx emissions. The actual NOx reduction that could be achieved in the field is expected to be engine specific, and in many cases may be even greater. RRFCS demonstrated that its synthesis gas generator could produce synthesis gas with the flammables content that was successfully used in the engine testing. An economic analysis of the synthesis gas approach estimates that its initial capital cost and yearly operating cost are less than half that of a competing NOx reduction technology, Selective Catalytic Reduction. The next step in developing the technology is an integrated test of the synthesis gas generator with an engine to obtain reliability data for system components and to confirm operating cost. RRFCS is actively pursuing opportunities to perform the integrated test. A successful integrated test would demonstrate the technology as a low-cost option to reduce NOx emissions from approximately 6,000 existing two-stroke, natural gas-fired reciprocating engines used on natural gas pipelines in North America. NOx emissions reduction made possible at a reasonable price by this synthesis gas technology, if implemented on 25% of these engines, would be on the order of 25,000 tons/year.

  20. Income-Based Greenhouse Gas Emissions of Nations.

    Science.gov (United States)

    Liang, Sai; Qu, Shen; Zhu, Zeqi; Guan, Dabo; Xu, Ming

    2017-01-03

    Accounting for greenhouse gas (GHG) emissions of nations is essential to understanding their importance to global climate change and help inform the policymaking on global GHG mitigation. Previous studies have made efforts to evaluate direct GHG emissions of nations (a.k.a. production-based accounting method) and GHG emissions caused by the final consumption of nations (a.k.a. consumption-based accounting method), but overlooked downstream GHG emissions enabled by primary inputs of individual nations and sectors (a.k.a. income-based accounting method). Here we show that the income-based accounting method reveals new GHG emission profiles for nations and sectors. The rapid development of mining industries drives income-based GHG emissions of resource-exporting nations (e.g., Australia, Canada, and Russia) during 1995-2009. Moreover, the rapid development of sectors producing basic materials and providing financial intermediation services drives income-based GHG emissions of developing nations (e.g., China, Indonesia, India, and Brazil) during this period. The income-based accounting can support supply side policy decisions and provide additional information for determining GHG emission quotas based on cumulative emissions of nations and designing policies for shared responsibilities.

  1. Revised emission factors for gas engines including start/stop emissions

    Energy Technology Data Exchange (ETDEWEB)

    Nielsen, Malene; Boll Illerup, J.; Birr-Petersen, K.

    2008-06-15

    Liberalisation of the electricity market has led to Danish gas engine plants increasingly converting to the spot and regulating power markets. In order to offer regulating power, plants need to be able to start and stop the engines at the plants quickly. The liberalisation causes a considerable change of operation practice of the engines e.g. less full load operation hours /year. The project provides an inventory determining the scale of the emissions during the start and stop sequence as well as proposals for engine modifications aimed at reducing start/stop emissions. This report includes calculation of emission factors as well as an inventory of total emissions and reduction potentials. (au)

  2. Mitigating gas emissions at signalised intersections using wireless vehicle detectors

    Directory of Open Access Journals (Sweden)

    Moses Kwasi Torkudzor

    2015-09-01

    Full Text Available Traffic congestion on roads wastes travel times and increases fuel consumption as well as gas emissions which are dangerous to human health. This has led to growing concern about environmental protection and energy conservation and a number of studies to increase fuel economy and reduce gas emissions. To increase travel times so as to reduce fuel consumption and gas emissions, traffic signals at intersections must be well implemented. It is therefore necessary to employ the current technology of wireless sensor networks to enhance the optimisation of the signalised intersections so as to address such a concern. In this study, a vehicular traffic control model was developed to optimise a signalised intersection, using wireless vehicle detectors. Real-time traffic volume gathered were analysed to obtain the peak hour traffic volume causing congestion. The intersection was modelled and simulated in Synchro7 as an actuated signalised model using results from the analysed data. The model for morning peak and evening peak periods gave optimal cycle lengths which result in the reduction of gas emissions, fuel consumption and delay at the intersection.

  3. Can tourism deliver its "aspirational" greenhouse gas emission reduction targets?

    NARCIS (Netherlands)

    Scott, D.; Peeters, P.M.; Gössling, S.

    2010-01-01

    This review paper examines the greenhouse gas (GHG) emission reduction targets postulated by a range of organizations seeking to reduce the consequences of global climate change and how, or if, the global tourism sector can achieve its share of those targets. It takes both existing estimates of

  4. Aligning corporate greenhouse-gas emissions targets with climate goals

    NARCIS (Netherlands)

    Krabbe, Oskar; Linthorst, Giel; Blok, Kornelis; Crijns-Graus, Wina; Van Vuuren, Detlef P.; Höhne, Niklas; Faria, Pedro; Aden, Nate; Pineda, Alberto Carrillo

    2015-01-01

    Corporate climate action is increasingly considered important in driving the transition towards a low-carbon economy. For this, it is critical to ensure translation of global goals to greenhouse-gas (GHG) emissions reduction targets at company level. At the moment, however, there is a lack of clear

  5. Aligning corporate greenhouse-gas emissions targets with climate goals

    NARCIS (Netherlands)

    Krabbe, Oskar; Linthorst, Giel; Blok, Kornelis; Crijns-Graus, Wina; Vuuren, Van Detlef P.; Höhne, Niklas; Faria, Pedro; Aden, Nate; Pineda, Alberto Carrillo

    2015-01-01

    Corporate climate action is increasingly considered important in driving the transition towards a low-carbon economy. For this, it is critical to ensure translation of global goals to greenhouse-gas (GHG) emissions reduction targets at company level. At the moment, however, there is a lack of cle

  6. Greenhouse-gas emissions from soils increased by earthworms

    NARCIS (Netherlands)

    Lubbers, I.M.; Groenigen, van K.J.; Fonte, S.J.; Six, J.; Brussaard, L.; Groenigen, van J.W.

    2013-01-01

    Earthworms play an essential part in determining the greenhouse-gas balance of soils worldwide, and their influence is expected to grow over the next decades. They are thought to stimulate carbon sequestration in soil aggregates, but also to increase emissions of the main greenhouse gases carbon dio

  7. Greenhouse-gas emissions from soils increased by earthworms

    NARCIS (Netherlands)

    Lubbers, I.M.; Groenigen, van K.J.; Fonte, S.J.; Six, J.; Brussaard, L.; Groenigen, van J.W.

    2013-01-01

    Earthworms play an essential part in determining the greenhouse-gas balance of soils worldwide, and their influence is expected to grow over the next decades. They are thought to stimulate carbon sequestration in soil aggregates, but also to increase emissions of the main greenhouse gases carbon

  8. Can tourism deliver its "aspirational" greenhouse gas emission reduction targets?

    NARCIS (Netherlands)

    Scott, D.; Peeters, P.M.; Gössling, S.

    2010-01-01

    This review paper examines the greenhouse gas (GHG) emission reduction targets postulated by a range of organizations seeking to reduce the consequences of global climate change and how, or if, the global tourism sector can achieve its share of those targets. It takes both existing estimates of curr

  9. Unconventional Heavy Oil Growth and Global Greenhouse Gas Emissions.

    Science.gov (United States)

    Nduagu, Experience I; Gates, Ian D

    2015-07-21

    Enormous global reserves of unconventional heavy oil make it a significant resource for economic growth and energy security; however, its extraction faces many challenges especially on greenhouse gas (GHG) emissions, water consumption, and recently, social acceptability. Here, we question whether it makes sense to extract and use unconventional heavy oil in spite of these externalities. We place unconventional oils (oil sands and oil shale) alongside shale gas, coal, lignite, wood and conventional oil and gas, and compare their energy intensities and life cycle GHG emissions. Our results reveal that oil shale is the most energy intensive fuel among upgraded primary fossil fuel options followed by in situ-produced bitumen from oil sands. Lignite is the most GHG intensive primary fuel followed by oil shale. Based on future world energy demand projections, we estimate that if growth of unconventional heavy oil production continues unabated, the incremental GHG emissions that results from replacing conventional oil with heavy oil would amount to 4-21 Gt-CO2eq GtCO2eq over four decades (2010 by 2050). However, prevailing socio-economic, regional and global energy politics, environmental and technological challenges may limit growth of heavy oil production and thus its GHG emissions contributions to global fossil fuel emissions may be smaller.

  10. Impact of greenhouse gas emissions reduction in Indonesia: NO2

    Science.gov (United States)

    Susandi, A.

    2004-12-01

    In this study, we develop scenarios of total air pollution from fossil fuel consumption and its impacts for the 21st century, using an inter-temporal general equilibrium model MERGE. The Model for Evaluating the Regional and Global Effects of greenhouse gas reduction policies (MERGE) is used to project energy consumption and production. We use the base scenarios from IPCC (2000). These scenarios assume that no measures are undertaken to control greenhouse gas emissions. We extend the IPCC scenarios with mitigation scenarios, estimating the air pollution impacts of greenhouse gas emission reduction. The MERGE model was extended to analyze emissions of nitrogen dioxide (NO2), their concentrations, impacts on human health, and economic valuation. To estimate of nitrogen dioxide (NO2) impacts on respiratory symptoms, we calculated the NO2 concentration as derived from nitrogen oxide (NOx). In the baseline scenario, the concentrations of NO2 are rising to 2,263 μg/m3 in 2100. If the Organisation for Economic Co-operation and Development (OECD) countries reduce their emissions, respiratory symptoms among adult's associated with NO2 case would reach the highest to 65,741% of adult population cases by the end of century. If all countries reduce their emission in the future, the total health problem cost associated with NO2 will lower 35% of GDP than in the baseline scenario during the century.

  11. Estonian greenhouse gas emissions inventory report

    Energy Technology Data Exchange (ETDEWEB)

    Punning, J.M.; Ilomets, M.; Karindi, A.; Mandre, M.; Reisner, V. [Inst. of Ecology, Tallinn (Estonia); Martins, A.; Pesur, A. [Inst. of Energy Research, Tallinn (Estonia); Roostalu, H.; Tullus, H. [Estonian Agricultural Univ., Tartu (Estonia)

    1996-07-01

    It is widely accepted that the increase of greenhouse gas concentrations in the atmosphere due to human activities would result in warming of the Earth`s surface. To examine this effect and better understand how the GHG increase in the atmosphere might change the climate in the future, how ecosystems and societies in different regions of the World should adapt to these changes, what must policymakers do for the mitigation of that effect, the worldwide project within the Framework Convention on Climate Change was generated by the initiative of United Nations. Estonia is one of more than 150 countries, which signed the Framework Convention on Climate Change at the United Nations Conference on Environment and Development held in Rio de Janeiro in June 1992. In 1994 a new project, Estonian Country Study was initiated within the US Country Studies Program. The project will help to compile the GHG inventory for Estonia, find contemporary trends to investigate the impact of climate change on the Estonian ecosystems and economy and to formulate national strategies for Estonia addressing to global climate change.

  12. Exhaust gas emission from a two-stroke engine

    Energy Technology Data Exchange (ETDEWEB)

    Lippitsch, H.H.; Eichlseder, H.

    1986-01-01

    According to present day ideas, carbon monoxide CO, hydrocarbons HC and nitrogen oxide NO are regarded as harmful substances in the exhaust gas and are therefore limited by law in some countries. After a survey of the regulations in Europe and the USA, the origin of these substances in a two-stroke engine is briefly described. The effect of the type of engine is then shown by results from various engines. It was found that emission can be drastically reduced by new engine designs. The introduction of exhaust gas regulations in Austria has caused the firm of Bombadier-Rotax to intensify their development work in this field. The state of exhaust gas emission of present day mass-produced engines was compared with previous engines at this opportunity.

  13. Reducing Greenhouse Gas Emissions from Agricultural Wetlands in Borneo

    Science.gov (United States)

    Abdul, H.; Fatah, L.; Nursyamsi, D.; Kazuyuki, I.

    2011-12-01

    At the forum G20 meeting in 2009, Indonesian President delivered Indonesia's commitment to reduce national greenhouse gas (GHG) emissions by 26% in 2020 by unilateral action and by 41% with support of other countries. To achieve the target, Indonesian government has put forestry, agriculture (including peatlands), energy, industry and transportation as main responsible sectors. Development of crop with low GHG emissions, increasing C sequestration and the use of organic fertilizers are among the activities to be carried out in 2010-2020 period to minimize GHG emissions from agricultural sectors. Three experiments have been carried out to elucidate the reflectivity of crop selection, soil ameliorants and organic fertilizers on GHG emissions from agricultural wetlands in Borneo. Firstly, gas samples were collected in weekly basis from oil palm, paddy, and vegetables fields and analyzed for methane (CH4) and nitrous oxide (N2O) concentrations by a gas chromatography. Secondly, coal fly ash, dolomite and ZnSO4 were incorporated into a pot containing peat and/or alluvial soils taken from wetlands in South Kalimantan. The air samples were taken and analyzed for CH4 by a gas chromatography. Finally, microbial consortium are isolated from soil, sediment and cow dung. The microbes were then propagated and used in a rice straw composting processes. The CO2, CH4 and N2O emissions from composting vessel were measured at one, two and four weeks of composting processes. The results showed that shifting the use of peatlands for oil palm to vegetable field reduced the GHG emissions by about 74% and that to paddy field reduce the GHG emissions by about 82%. The CH4 emissions from paddy field can be further reduced by applying dolomite. However, the use of coal fly ash and ZnSO4 increased CH4 emissions from peat soil cultivated to rice. The use of microbe isolated from saline soil could reduce GHG emissions during the composting of rice straw. The social aspect of GHG reduction in

  14. Greenlandic Microbiomes and Greenhouse Gas Emissions

    Science.gov (United States)

    Jacobsen, C. S.; Nielsen, M. S.; Priemé, A.; Holben, W. E.; Stibal, M.; Morales, S.; Bælum, J.; Elberling, B.; Kuhry, P.; Hugelius, G.

    2014-12-01

    the potential (DNA) and activity (mRNA) found in the soils. However, distinct differences were found in the active microbiomes of the thawed soils, and this is discussed in relation to the emission of N2O, CH4 and CO2.

  15. Improvements on Near Real Time Detection of Volcanic Ash Emissions for Emergency Monitoring with Limited Satellite Bands

    Directory of Open Access Journals (Sweden)

    Torge Steensen

    2015-03-01

    Full Text Available Quantifying volcanic ash emissions syneruptively is an important task for the global aviation community. However, due to the near real time nature of volcano monitoring, many parameters important for accurate ash mass estimates cannot be obtained easily. Even when using the best possible estimates of those parameters, uncertainties associated with the ash masses remain high, especially if the satellite data is only available in the traditional 10.8 and 12.0 μm bands. To counteract this limitation, we developed a quantitative comparison between the ash extents in satellite and model data. The focus is the manual cloud edge definition based on the available satellite reverse absorption (RA data as well as other knowledge like pilot reports or ground-based observations followed by an application of the Volcanic Ash Retrieval on the defined subset with an RA threshold of 0 K. This manual aspect, although subjective to the experience of the observer, can show a significant improvement as it provides the ability to highlight ash that otherwise would be obscured by meteorological clouds or, by passing over different surfaces with unaccounted temperatures, might be lost entirely and thus remains undetectable for an automated satellite approach. We show comparisons to Volcanic Ash Transport and Dispersion models and outline a quantitative match as well as percentages of overestimates based on satellite or dispersion model data which can be converted into a level of reliability for near real time volcano monitoring. 

  16. The Effect of Taxation on Greenhouse Gas Emissions

    Directory of Open Access Journals (Sweden)

    Žiga KOTNIK

    2014-11-01

    Full Text Available This paper examines the effect of governmental environmental taxes on greenhouse gas (GHG emissions using a panel data set of 19 EU countries for the time period 1995-2010. We estimate both direct and indirect effects of governmental environmental taxes on GHG emissions in industrial processes. The indirect effect in particular operates through the effect of environmental expenditure for reduction of GHG emissions in industry. To take into account the dynamic nature and to properly address the potential endogeneity, adequate econometric methods are applied. We have shown that the direct effect of environmental taxes on GHG emissions is negative, while the indirect effect through environmental expenditures is also negative and even more statistically significant. Consequently, some policy implications may be derived from the results.

  17. The Effect of Taxation on Greenhouse Gas Emissions

    Directory of Open Access Journals (Sweden)

    Žiga KOTNIK

    2014-10-01

    Full Text Available This paper examines the effect of governmental environmental taxes on greenhouse gas (GHG emissions using a panel data set of 19 EU countries for the time period 1995-2010. We estimate both direct and indirect effects of governmental environmental taxes on GHG emissions in industrial processes. The indirect effect in particular operates through the effect of environmental expenditure for reduction of GHG emissions in industry. To take into account the dynamic nature and to properly address the potential endogeneity, adequate econometric methods are applied. We have shown that the direct effect of environmental taxes on GHG emissions is negative, while the indirect effect through environmental expenditures is also negative and even more statistically significant. Consequently, some policy implications may be derived from the results.

  18. A forward looking, actor based, indicator for climate gas emissions

    Energy Technology Data Exchange (ETDEWEB)

    Ericson, Torgeir; Randers, Joergen

    2011-04-15

    The most commonly used Norwegian indicator for climate change displays historical emissions and compare with Norway's Kyoto target. This indicator says little about future emissions, about the ongoing Norwegian effort to reduce climate gas emissions, or about its effect on sustainability. In this paper we propose an indicator that improves on these weaknesses. We present a forward looking climate indicator that in addition to historic data includes business as usual scenarios, different proposals for future domestic emissions, and national or international commitments and agreements. This indicator presents - in one graph - a broad diversity of views on how the climate challenge should be handled from now and into the future. This indicator-graph may contribute to a more transparent discussion of available policy options. (Author)

  19. The development of a new database of gas emissions: MAGA, a collaborative web environment for collecting data

    Science.gov (United States)

    Cardellini, C.; Chiodini, G.; Frigeri, A.; Bagnato, E.; Aiuppa, A.; McCormick, B.

    2013-12-01

    The data on volcanic and non-volcanic gas emissions available online are, as today, incomplete and most importantly, fragmentary. Hence, there is need for common frameworks to aggregate available data, in order to characterize and quantify the phenomena at various spatial and temporal scales. Building on the Googas experience we are now extending its capability, particularly on the user side, by developing a new web environment for collecting and publishing data. We have started to create a new and detailed web database (MAGA: MApping GAs emissions) for the deep carbon degassing in the Mediterranean area. This project is part of the Deep Earth Carbon Degassing (DECADE) research initiative, lunched in 2012 by the Deep Carbon Observatory (DCO) to improve the global budget of endogenous carbon from volcanoes. MAGA database is planned to complement and integrate the work in progress within DECADE in developing CARD (Carbon Degassing) database. MAGA database will allow researchers to insert data interactively and dynamically into a spatially referred relational database management system, as well as to extract data. MAGA kicked-off with the database set up and a complete literature survey on publications on volcanic gas fluxes, by including data on active craters degassing, diffuse soil degassing and fumaroles both from dormant closed-conduit volcanoes (e.g., Vulcano, Phlegrean Fields, Santorini, Nysiros, Teide, etc.) and open-vent volcanoes (e.g., Etna, Stromboli, etc.) in the Mediterranean area and Azores. For each geo-located gas emission site, the database holds images and description of the site and of the emission type (e.g., diffuse emission, plume, fumarole, etc.), gas chemical-isotopic composition (when available), gas temperature and gases fluxes magnitude. Gas sampling, analysis and flux measurement methods are also reported together with references and contacts to researchers expert of the site. Data can be accessed on the network from a web interface or as

  20. A GAS TEMPERATURE PROFILE BY INFRARED EMISSION-ABSORPTION SPECTROSCOPY

    Science.gov (United States)

    Buchele, D. R.

    1994-01-01

    This computer program calculates the temperature profile of a flame or hot gas. Emphasis is on profiles found in jet engine or rocket engine exhaust streams containing water vapor or carbon dioxide as radiating gases. The temperature profile is assumed to be axisymmetric with a functional form controlled by two variable parameters. The parameters are calculated using measurements of gas radiation at two wavelengths in the infrared spectrum. Infrared emission and absorption measurements at two or more wavelengths provide a method of determining a gas temperature profile along a path through the gas by using a radiation source and receiver located outside the gas stream being measured. This permits simplified spectral scanning of a jet or rocket engine exhaust stream with the instrumentation outside the exhaust gas stream. This program provides an iterative-cyclic computation in which an initial assumed temperature profile is altered in shape until the computed emission and absorption agree, within specified limits, with the actual instrument measurements of emission and absorption. Temperature determination by experimental measurements of emission and absorption at two or more wavelengths is also provided by this program. Additionally, the program provides a technique for selecting the wavelengths to be used for determining the temperature profiles prior to the beginning of the experiment. By using this program feature, the experimenter has a higher probability of selecting wavelengths which will result in accurate temperature profile measurements. This program provides the user with a technique for determining whether this program will be sufficiently accurate for his particular application, as well as providing a means of finding the solution. The input to the program consists of four types of data: (1) computer program control constants, (2) measurements of gas radiance and transmittance at selected wavelengths, (3) tabulations from the literature of gas

  1. Greenhouse gas emissions from septic systems in New York State

    Science.gov (United States)

    Truhlar, A. M.; Rahm, B. G.; Brooks, R. A.; Nadeau, S. A.; Walter, M. T.

    2015-12-01

    Onsite septic systems are a practical way to treat wastewater in rural or less-densely populated areas. Septic systems utilize microbial processes to eliminate organic wastes and nutrients such as nitrogen; these processes can contribute to air pollution through the release of greenhouse gases (GHGs). At each of nine septic systems, we measured fluxes of CH4, CO2, and N2O from the soil over the leach field and sand filter, and from the roof outlet vent. These are the most likely locations for gas emissions during normal operation of the septic system. The majority of all septic system gas emissions were released from the roof vent. However, our comparisons of the gas fluxes from these locations suggest that biological processes in the soil, especially the soil over the leach field, can influence the type and quantity of gas that is released from the system. The total vent, sand filter, and leach field GHG emissions were 0.12, 0.045, and 0.046 tonne CO2e capita-1 year-1, respectively. In total, this represents about 1.5% of the annual carbon footprint of an individual living in the US.

  2. Policy Considerations for Greenhouse Gas Emissions from Freshwater Reservoirs

    Directory of Open Access Journals (Sweden)

    Kirsi Mäkinen

    2010-06-01

    Full Text Available Emerging concern over greenhouse gas (GHG emissions from wetlands has prompted calls to address the climate impact of dams in climate policy frameworks. Existing studies indicate that reservoirs can be significant sources of emissions, particularly in tropical areas. However, knowledge on the role of dams in overall national emission levels and abatement targets is limited, which is often cited as a key reason for political inaction and delays in formulating appropriate policies. Against this backdrop, this paper discusses the current role of reservoir emissions in existing climate policy frameworks. The distance between a global impact on climate and a need for local mitigation measures creates a challenge for designing appropriate mechanisms to combat reservoir emissions. This paper presents a range of possible policy interventions at different scales that could help address the climate impact of reservoirs. Reservoir emissions need to be treated like other anthropogenic greenhouse gases. A rational treatment of the issue requires applying commonly accepted climate change policy principles as well as promoting participatory water management plans through integrated water resource management frameworks. An independent global body such as the UN system may be called upon to assess scientific information and develop GHG emissions policy at appropriate levels.

  3. Black Carbon Emissions from Associated Natural Gas Flaring.

    Science.gov (United States)

    Weyant, Cheryl L; Shepson, Paul B; Subramanian, R; Cambaliza, Maria O L; Heimburger, Alexie; McCabe, David; Baum, Ellen; Stirm, Brian H; Bond, Tami C

    2016-02-16

    Approximately 150 billion cubic meters (BCM) of natural gas is flared and vented in the world annually, emitting greenhouse gases and other pollutants with no energy benefit. About 7 BCM per year is flared in the United States, and half is from North Dakota alone. There are few emission measurements from associated gas flares and limited black carbon (BC) emission factors have been previously reported from the field. Emission plumes from 26 individual flares in the Bakken formation in North Dakota were sampled. Methane, carbon dioxide, and BC were measured simultaneously, allowing the calculation of BC mass emission factors using the carbon balance method. Particle optical absorption was measured using a three-wavelength particle soot absorption photometer (PSAP) and BC particle number and mass concentrations were measured with a single particle soot photometer. The BC emission factors varied over 2 orders of magnitude, with an average and uncertainty range of 0.14 ± 0.12 g/kg hydrocarbons in associated gas and a median of 0.07 g/kg which represents a lower bound on these measurements. An estimation of the BC emission factor derived from PSAP absorption provides an upper bound at 3.1 g/kg. These results are lower than previous estimations and laboratory measurements. The BC mass absorption cross section was 16 ± 12 m(2)/g BC at 530 nm. The average absorption Ångström exponent was 1.2 ± 0.8, suggesting that most of the light absorbing aerosol measured was black carbon and the contribution of light absorbing organic carbon was small.

  4. Greenhouse gas emissions in milk and dairy product chains

    DEFF Research Database (Denmark)

    Flysjö, Anna Maria

    Reducing greenhouse gas emissions from dairy products is one important step towards a more sustainable dairy sector. To ensure effective mitigation, reliable assessment methods are required. The present PhD thesis focuses on some of the most critical methodological aspects influencing the carbon...... footprint (CF) of milk and dairy products, namely; estimating CH4 and N2O emissions; accounting for land use change; co-product handling; and defining the functional unit. In addition, the CF is calculated for different types of dairy products, and suggestions on various mitigation measures are presented...

  5. Exergy analysis of waste emissions from gas flaring

    Directory of Open Access Journals (Sweden)

    Olawale Saheed ISMAIL

    2016-07-01

    Full Text Available Gas flaring produces a stream of waste gases at high temperature and pressure which contains carbon monoxide, Hydrogen Sulphide etc. The resultant effect of which is detrimental to our planet and, consequently, to the life of both the living and the non-living things. It’s well known that gas flaring contributes in no small measure to the global warming. Exergy analysis is applied in this work to analyze waste emissions from gas flaring so as to have a model through which impact of gas flaring can be measured. The study considers both the thermo-mechanical exergy and the chemical exergy of these gases. Relevant data on gas flaring activities in the Niger-Delta region of Nigeria between the periods of fifteen (15 years was obtained from the Nigerian National Petroleum Corporation (NNPC. A computer program (Exergy Calculator was developed based on the equations generated in the Model. Exergy associated with gas flaring activities in Nigeria between the periods of 1998 through 2012 was calculated. The results show that 1 mscf (in thousand cubic feet of flared gases generate 0.000041 MWh of energy leading to a value of 440158.607 MWh of energy for the period under review.The analysis provides important conclusions and recommendations for improving oil platforms operationsin in order to safeguard the environment, health of the populace, and maximize recovered exergy from gas flaring.

  6. Greenhouse gas emission factors associated with rewetting of organic soils

    Directory of Open Access Journals (Sweden)

    D. Wilson

    2016-04-01

    Full Text Available Drained organic soils are a significant source of greenhouse gas (GHG emissions to the atmosphere. Rewetting these soils may reduce GHG emissions and could also create suitable conditions for return of the carbon (C sink function characteristic of undrained organic soils. In this article we expand on the work relating to rewetted organic soils that was carried out for the 2014 Intergovernmental Panel on Climate Change (IPCC Wetlands Supplement. We describe the methods and scientific approach used to derive the Tier 1 emission factors (the rate of emission per unit of activity for the full suite of GHG and waterborne C fluxes associated with rewetting of organic soils. We recorded a total of 352 GHG and waterborne annual flux data points from an extensive literature search and these were disaggregated by flux type (i.e. CO2, CH4, N2O and DOC, climate zone and nutrient status. Our results showed fundamental differences between the GHG dynamics of drained and rewetted organic soils and, based on the 100 year global warming potential of each gas, indicated that rewetting of drained organic soils leads to: net annual removals of CO2 in the majority of organic soil classes; an increase in annual CH4 emissions; a decrease in N2O and DOC losses; and a lowering of net GHG emissions. Data published since the Wetlands Supplement (n = 58 generally support our derivations. Significant data gaps exist, particularly with regard to tropical organic soils, DOC and N2O. We propose that the uncertainty associated with our derivations could be significantly reduced by the development of country specific emission factors that could in turn be disaggregated by factors such as vegetation composition, water table level, time since rewetting and previous land use history.

  7. Uncertainties in the Norwegian greenhouse gas emission inventory

    Energy Technology Data Exchange (ETDEWEB)

    Flugsrud, Ketil; Hoem, Britta

    2011-11-15

    The national greenhouse gas (GHG) emission inventory is compiled from estimates based on emission factors and activity data and from direct measurements by plants. All these data and parameters will contribute to the overall inventory uncertainty. The uncertainties and probability distributions of the inventory input parameters have been assessed based on available data and expert judgements.Finally, the level and trend uncertainties of the national GHG emission inventory have been estimated using Monte Carlo simulation. The methods used in the analysis correspond to an IPCC tier 2 method, as described in the IPCC Good Practice Guidance (IPCC 2000) (IPCC 2000). Analyses have been made both excluding and including the sector LULUCF (land use, land-use change and forestry). The uncertainty analysis performed in 2011 is an update of the uncertainty analyses performed for the greenhouse gas inventory in 2006 and 2000. During the project we have been in contact with experts, and have collected information about uncertainty from them. Main focus has been on the source categories where changes have occured since the last uncertainty analysis was performed in 2006. This includes new methodology for several source categories (for example for solvents and road traffic) as well as revised uncertainty estimates. For the installations included in the emission trading system, new information from the annual ETS reports about uncertainty in activity data and CO2 emission factor (and N2O emission factor for nitric acid production) has been used. This has improved the quality of the uncertainty estimates for the energy and manufacturing sectors. The results show that the uncertainty level in the total calculated greenhouse gas emissions for 2009 is around 4 per cent. When including the LULUCF sector, the total uncertainty is around 17 per cent in 2009. The uncertainty estimate is lower now than previous analyses have shown. This is partly due to a considerable work made to improve

  8. Green house gas emissions from composting and mechanical biological treatment.

    Science.gov (United States)

    Amlinger, Florian; Peyr, Stefan; Cuhls, Carsten

    2008-02-01

    In order to carry out life-cycle assessments as a basis for far-reaching decisions about environmentally sustainable waste treatment, it is important that the input data be reliable and sound. A comparison of the potential greenhouse gas (GHG) emissions associated with each solid waste treatment option is essential. This paper addresses GHG emissions from controlled composting processes. Some important methodological prerequisites for proper measurement and data interpretation are described, and a common scale and dimension of emission data are proposed so that data from different studies can be compared. A range of emission factors associated with home composting, open windrow composting, encapsulated composting systems with waste air treatment and mechanical biological waste treatment (MBT) are presented from our own investigations as well as from the literature. The composition of source materials along with process management issues such as aeration, mechanical agitation, moisture control and temperature regime are the most important factors controlling methane (CH4), nitrous oxide (N2O) and ammoniac (NH3) emissions. If ammoniac is not stripped during the initial rotting phase or eliminated by acid scrubber systems, biofiltration of waste air provides only limited GHG mitigation, since additional N2O may be synthesized during the oxidation of NH3, and only a small amount of CH4 degradation occurs in the biofilter. It is estimated that composting contributes very little to national GHG inventories generating only 0.01-0.06% of global emissions. This analysis does not include emissions from preceding or post-treatment activities (such as collection, transport, energy consumption during processing and land spreading), so that for a full emissions account, emissions from these activities would need to be added to an analysis.

  9. Formation Conditions and Distribution Regularities of Oil—gas Pools in Tertiary Volcanic Rocks in Western Huimin Depression,Shandong Province

    Institute of Scientific and Technical Information of China (English)

    刘泽容; 王永杰; 等

    1989-01-01

    The formation conditions and distribution regularities of oil-gas pools in volcanic rocks in western Huimin Depression have been studied in terms of geolgic,sesmic and well logging information,This paper discusses the types and lithofacies,development and distribution of Tertiary volcanic rocks in the area.The results demonstrate that volcanic activity occurred mainly during the period from the Sha-4 stage to the Guantao episode,i.e.,before the oil-generating period(before the end of the Guantao episode and the Minghuazhen episode).The activity did not destroy oil and gas formation and accumulation,but was favourable for the concentration of organic matter and its conversion to hydrocarbons;besides,volcanic rocks can serve as reservoir rocks and cap rocks,playing a role very similar to that of a syndepositional anticline,The volcanic rocks are distributed near the margins of the oil-generating depression;there are many secondary interstices in the rocks,which are connected with each other.These are the leading conditions for the formation of oil-generating period and their self-sealing or good combination with other cap rocks are important factors for forming volcanic rock-hosted oil and gas pools.The oil-gas pools associated with volcanic rocks in western Huimin are mainly distributed around the deep oil-generating depression,in the central up lift or the high structural levels on the margins of the depression.In particular,the sites where several faults cross are usually locatons where hith-yielding oil-gas pools in volcanic rocks are concentrated.

  10. Trace Gas Emission from in-Situ Denitrifying Bioreactors

    Science.gov (United States)

    Pluer, W.; Walter, M. T.; Geohring, L.

    2014-12-01

    Despite decades of concerted effort to mitigate nonpoint source nitrate (NO3-) pollution from agricultural lands, these efforts have not been sufficient to arrest eutrophication. A primary process for removing excess NO3- from water is denitrification, where denitrifying bacteria use NO3- for respiration in the absence of oxygen. Denitrification results in reduced forms of nitrogen, often dinitrogen gas (N2) but also nitrous oxide (N2O), an aggressive greenhouse gas. A promising solution to NO3- pollution is to intercept agricultural discharges with denitrifying bioreactors (DNBRs). DNBRs provide conditions ideal for denitrifiers: an anaerobic environment, sufficient organic matter, and excess NO3-. These conditions are also ideal for methanogens, which produce methane (CH4), another harmful trace gas. While initial results from bioreactor studies show that they can cost-effectively remove NO3-, trace gas emissions are an unintended consequence. This study's goal was to determine how bioreactor design promotes denitrification while limiting trace gas production. Reactor inflow and outflow water samples were tested for nutrients, including NO3-, and dissolved inflow and outflow gas samples were tested for N2O and CH4. NO3- reduction and trace gas production were evaluated at various residence times, pHs, and inflow NO3- concentrations in field and lab-scale reactors. Low NO3- reduction indicated conditions that stressed denitrifying bacteria while high reductions indicated designs that optimized pollutant treatment for water quality. Several factors influenced high N2O, suggesting non-ideal conditions for the final step of complete denitrification. High CH4 emissions pointed to reactor media choice for discouraging methanogens, which may remove competition with denitrifiers. It is critical to understand all of potential impacts that DNBRs may have, which means identifying processes and design specifications that may affect them.

  11. Mapping Fugitive Gas Emission Sources and Severity Across Southeastern Saskatchewan

    Science.gov (United States)

    Baillie, J.; Risk, D. A.; Lavoie, M.; Williams, J. P.

    2015-12-01

    Southeastern Saskatchewan, Canada contains a 10,000 km2 region heavily developed by oil and gas activity that has been struggling with air quality issues, arising from hundreds or thousands of oil and gas leak points. The region is also very diverse in terms of oilfield operators, who use extraction techniques including conventional, enhanced oil recovery (EOR), and fracking. As regulators and operators need more knowledge about emission patterns locally, we undertook comprehensive mapping and characterization of leak sources at the regional scale using vehicle-based data collection, together with computational techniques. We measured the presence and source of fugitive emissions from infrastructure and oilfield activities in eight 100 km2 survey domains. These included two controls with no oil and gas activity, and otherwise the domains were selected to capture the diversity of development; targeting primarily conventional and EOR activities in the Weyburn-Midale beds, and unconventional activities in the Bakken play. A total of 25 unique operators fell within the survey domains. Each domain was surveyed multiple times for CO2, CH4, and H2S, allowing us to identify persistent leaks and to screen out one-time events. The multiple gas targets also provided opportunities for discriminating one type of fugitive emission from another (i.e. flares from storage tanks) using ratios of excess (above ambient) concentrations, after correcting for natural background variability with a signal-processing routine. Fugitive emissions were commonly observed in all study domains. Most emissions were associated with oil and gas infrastructure, as opposed to drilling and other short-term activities. There were obvious emissions at many well pads, storage tanks, and flares. We also observed high geochemical variability around flares, with some being very effective in combusting toxic gases, and others less so. Almost all observed concentrations fell below regulatory limits, but have a

  12. A Study of Gas Emissions from Dry Toilets

    OpenAIRE

    Tsang, Pui Ki

    2012-01-01

    Composting the human excreta in a dry-toilet is a widely applied procedure for stabilizing its organic matter content. A proper water balance in compost is an essential element in maintaining the microbial activity in the compost-mixture, and the moisture content of the compost can be significantly decreased by too intensive ventilation, which affects directly the composting performance. . The inevitable gas emission from the dry toilet, which indirectly reflects the composting process, is an...

  13. Greenhouse gas emissions from on-site wastewater treatment systems

    Science.gov (United States)

    Somlai-Haase, Celia; Knappe, Jan; Gill, Laurence

    2016-04-01

    Nearly one third of the Irish population relies on decentralized domestic wastewater treatment systems which involve the discharge of effluent into the soil via a percolation area (drain field). In such systems, wastewater from single households is initially treated on-site either by a septic tank and an additional packaged secondary treatment unit, in which the influent organic matter is converted into carbon dioxide (CO2) and methane (CH4) by microbial mediated processes. The effluent from the tanks is released into the soil for further treatment in the unsaturated zone where additional CO2 and CH4 are emitted to the atmosphere as well as nitrous oxide (N2O) from the partial denitrification of nitrate. Hence, considering the large number of on-site systems in Ireland and internationally, these are potential significant sources of greenhouse gas (GHG) emissions, and yet have received almost no direct field measurement. Here we present the first attempt to quantify and qualify the production and emissions of GHGs from a septic tank system serving a single house in the County Westmeath, Ireland. We have sampled the water for dissolved CO2, CH4 and N2O and measured the gas flux from the water surface in the septic tank. We have also carried out long-term flux measurements of CO2 from the drain field, using an automated soil gas flux system (LI-8100A, Li-Cor®) covering a whole year semi-continuously. This has enabled the CO2 emissions from the unsaturated zone to be correlated against different meteorological parameters over an annual cycle. In addition, we have integrated an ultraportable GHG analyser (UGGA, Los Gatos Research Inc.) into the automated soil gas flux system to measure CH4 flux. Further, manual sampling has also provided a better understanding of N2O emissions from the septic tank system.

  14. Opportunities for reducing greenhouse gas emissions in tropical peatlands.

    Science.gov (United States)

    Murdiyarso, D; Hergoualc'h, K; Verchot, L V

    2010-11-16

    The upcoming global mechanism for reducing emissions from deforestation and forest degradation in developing countries should include and prioritize tropical peatlands. Forested tropical peatlands in Southeast Asia are rapidly being converted into production systems by introducing perennial crops for lucrative agribusiness, such as oil-palm and pulpwood plantations, causing large greenhouse gas (GHG) emissions. The Intergovernmental Panel on Climate Change Guidelines for GHG Inventory on Agriculture, Forestry, and Other Land Uses provide an adequate framework for emissions inventories in these ecosystems; however, specific emission factors are needed for more accurate and cost-effective monitoring. The emissions are governed by complex biophysical processes, such as peat decomposition and compaction, nutrient availability, soil water content, and water table level, all of which are affected by management practices. We estimate that total carbon loss from converting peat swamp forests into oil palm is 59.4 ± 10.2 Mg of CO(2) per hectare per year during the first 25 y after land-use cover change, of which 61.6% arise from the peat. Of the total amount (1,486 ± 183 Mg of CO(2) per hectare over 25 y), 25% are released immediately from land-clearing fire. In order to maintain high palm-oil production, nitrogen inputs through fertilizer are needed and the magnitude of the resulting increased N(2)O emissions compared to CO(2) losses remains unclear.

  15. Gas Emissivity of a Modified Cellulose Mix at the Temperature of 900°C

    OpenAIRE

    Zawieja Z.; Sawicki J.

    2015-01-01

    This paper presents the findings of a study of gas emissivity and the volumetric gas flow rate from a patented modified cellulose mix used in production of disposable sand casting moulds. The modified cellulose mix with such additives as expanded perlite, expanded vermiculite and microspheres was used as the study material. The results for gas emissivity and the gas flow rate for the modified cellulose mix were compared with the gas emissivity of the commercial material used in gating systems...

  16. ICT and greenhouse gas emissions; IKT og klimagassutslipp

    Energy Technology Data Exchange (ETDEWEB)

    2009-08-15

    ICT can go from being a part of the climate challenge to be an important part of the solution by simplify, rationalize and replace a variety of features and services. ICT's contribute through production and operation for approx. 2.5 % of global greenhouse gas emissions. At the same time estimates show that ICT could help to reduce total greenhouse gas emissions by up to 15 % by 2020 through a series of measures. ICT can, for example. contribute to reduce travel activity through remote collaboration, the transition from material to virtual products and by greater energy efficiency in buildings and vehicles. Through remote collaboration, green tender rounds and change of focus from products to services, can authorities reduce their own emissions. In addition, the authorities go ahead as good examples by illustrating how environment benefits from governmental ICT investments. If we assume that video conferencing can replace 1 of 5 flights among the 140 000 state employees, this can lead to a reducted emission of 14 600 tonnes of CO{sub 2} per year. (AG)

  17. Gas/aerosol-ash interaction in volcanic plumes: New insights from surface analyses of fine ash particles

    Science.gov (United States)

    Delmelle, Pierre; Lambert, Mathieu; Dufrêne, Yves; Gerin, Patrick; Óskarsson, Niels

    2007-07-01

    The reactions occurring between gases/aerosols and silicate ash particles in volcanic eruption plumes remain poorly understood, despite the fact that they are at the origin of a range of volcanic, environmental, atmospheric and health effects. In this study, we apply X-ray photoelectron spectroscopy (XPS), a surface-sensitive technique, to determine the chemical composition of the near-surface region (2-10 nm) of nine ash samples collected from eight volcanoes. In addition, atomic force microscopy (AFM) is used to image the nanometer-scale surface structure of individual ash particles isolated from three samples. We demonstrate that rapid acid dissolution of ash occurs within eruption plumes. This process is favoured by the presence of fluoride and is believed to supply the cations involved in the deposition of sulphate and halide salts onto ash. AFM imaging also has permitted the detection of extremely thin (< 10 nm) coatings on the surface of ash. This material is probably composed of soluble sulphate and halide salts mixed with sparingly soluble fluoride compounds. The surface approach developed here offers promising aspects for better appraising the role of gas/aerosol-ash interaction in dictating the ability of ash to act as sinks for various volcanic and atmospheric chemical species as well as sources for others.

  18. Greenhouse Gas Emission Evaluation of the GTL Pathway.

    Science.gov (United States)

    Forman, Grant S; Hahn, Tristan E; Jensen, Scott D

    2011-10-15

    Gas to liquids (GTL) products have the potential to replace petroleum-derived products, but the efficacy with which any sustainability goals can be achieved is dependent on the lifecycle impacts of the GTL pathway. Life cycle assessment (LCA) is an internationally established tool (with GHG emissions as a subset) to estimate these impacts. Although the International Standard Organization's ISO 14040 standard advocates the system boundary expansion method (also known as the "displacement method" or the "substitution method") for life-cycle analyses, application of this method for the GTL pathway has been limited until now because of the difficulty in quantifying potential products to be displaced by GTL coproducts. In this paper, we use LCA methodology to establish the most comprehensive GHG emissions evaluation to date of the GTL pathway. The influence of coproduct credit methods on the GTL GHG emissions results using substitution methodology is estimated to afford the Well-to-Wheels (WTW) greenhouse gas (GHG) intensity of GTL Diesel. These results are compared to results using energy-based allocation methods of reference GTL diesel and petroleum-diesel pathways. When substitution methodology is used, the resulting WTW GHG emissions of the GTL pathway are lower than petroleum diesel references. In terms of net GHGs, an interesting way to further reduce GHG emissions is to blend GTL diesel in refineries with heavy crudes that require severe hydrotreating, such as Venezuelan heavy crude oil or bitumen derived from Canadian oil sands and in jurisdictions with tight aromatic specifications for diesel, such as California. These results highlight the limitation of using the energy allocation approach for situations where coproduct GHG emissions reductions are downstream from the production phase.

  19. Diffuse CO2 emission from the NE volcanic rift-zone of Tenerife (Canary Islands, Spain): a 15 years geochemical monitoring

    Science.gov (United States)

    Padilla, Germán; Alonso, Mar; Shoemaker, Trevor; Loisel, Ariane; Padrón, Eleazar; Hernández, Pedro A.; Pérez, Nemesio M.

    2016-04-01

    The North East Rift (NER) volcanic zone of Tenerife Island is one of the three volcanic rift-zones of the island (210 km2). The most recent eruptive activity along the NER volcanic zone took place in the 1704-1705 period with the volcanic eruptions of Siete Fuentes, Fasnia and Arafo volcanoes. The aim of this study was to report the results of a soil CO2 efflux survey undertaken in June 2015, with approximately 580 measuring sites. In-situ measurements of CO2 efflux from the surface environment of NER volcanic zone were performed by means of a portable non-dispersive infrared spectrophotometer (NDIR) model LICOR Li800 following the accumulation chamber method. To quantify the total CO2 emission from NER volcanic zone, soil CO2 efflux contour maps were constructed using sequential Gaussian simulation (sGs) as interpolation method. The total diffuse CO2 emission rate was estimated in 1209 t d-1, with CO2 efflux values ranging from non-detectable (˜0.5 g m-2 d-1) up to 123 g m-2 d-1, with an average value of 5.9 g m-2 d-1. If we compare these results with those obtained in previous surveys developed in a yearly basis, they reveal slightly variations from 2006 to 2015, with to pulses in the CO2 emission observed in 2007 and 2014. The main temporal variation in the total CO2 output does not seem to be masked by external variations. First peak precedes the anomalous seismicity registered in and around Tenerife Island between 2009 and 2011, suggesting stress-strain changes at depth as a possible cause for the observed changes in the total output of diffuse CO2 emission. Second peak could be related with futures changes in the seismicity. This study demonstrates the importance of performing soil CO2 efflux surveys as an effective surveillance volcanic tool.

  20. Greenhouse gas emission quantification from wastewater treatment plants, using a tracer gas dispersion method

    DEFF Research Database (Denmark)

    Delre, Antonio; Mønster, Jacob; Scheutz, Charlotte

    2017-01-01

    Plant-integrated methane (CH4) and nitrous oxide (N2O) emission quantifications were performed at five Scandinavian wastewater treatment plants, using a ground-based remote sensing approach that combines a controlled release of tracer gas from the plant with downwind concentration measurements. C...

  1. Limiting net greenhouse gas emissions in the United States

    Energy Technology Data Exchange (ETDEWEB)

    Bradley, R A; Watts, E C; Williams, E R [eds.

    1991-09-01

    In 1988, Congress requested that DOE produce a study on carbon dioxide inventory and policy to provide an inventory of emissions sources and to analyze policies to achieve a 20% reduction in carbon dioxide emissions in 5 to 10 years and a 50% reduction in 15 to 20 years. Energy and environmental technology data were analyzed using computational analysis models. This information was then evaluated, drawing on current scientific understanding of global climate change, the possible consequences of anthropogenic climate change (change caused by human activity) and the relationship between energy production and use and the emission of radiatively important gases. Topics discussed include: state of the science in estimating atmosphere/climate change relationships, the potential consequences of atmosphere/climate change, us greenhouse emissions past and present, an approach to analyzing the technical potential and cost of reducing US energy-related greenhouse gas emissions, current policy base and National Energy Strategy actions, fiscal instruments, regulatory instruments, combined strategies and instruments, macroeconomic impacts, carbon taxation and international trade, a comparison to other studies.

  2. Carbon soundings: greenhouse gas emissions of the UK music industry

    Science.gov (United States)

    Bottrill, C.; Liverman, D.; Boykoff, M.

    2010-01-01

    Over the past decade, questions regarding how to reduce human contributions to climate change have become more commonplace and non-nation state actors—such as businesses, non-government organizations, celebrities—have increasingly become involved in climate change mitigation and adaptation initiatives. For these dynamic and rapidly expanding spaces, this letter provides an accounting of the methods and findings from a 2007 assessment of greenhouse gas (GHG) emissions in the UK music industry. The study estimates that overall GHG emissions associated with the UK music market are approximately 540 000 t CO2e per annum. Music recording and publishing accounted for 26% of these emissions (138 000 t CO2e per annum), while three-quarters (74%) derived from activities associated with live music performances (400 000 t CO2e per annum). These results have prompted a group of music industry business leaders to design campaigns to reduce the GHG emissions of their supply chains. The study has also provided a basis for ongoing in-depth research on CD packaging, audience travel, and artist touring as well as the development of a voluntary accreditation scheme for reducing GHG emissions from activities of the UK music industry.

  3. Carbon soundings: greenhouse gas emissions of the UK music industry

    Energy Technology Data Exchange (ETDEWEB)

    Bottrill, C [Centre for Environmental Strategy, School of Engineering (D3), University of Surrey, Guildford, Surrey GU2 7XH (United Kingdom); Liverman, D [Institute of the Environment, University of Arizona, Tucson, AZ 85721 (United States); Boykoff, M, E-mail: c.bottrill@surrey.ac.u, E-mail: liverman@u.arizona.ed, E-mail: boykoff@colorado.ed [CIRES Center for Science and Technology Policy, Environmental Studies and Geography, University of Colorado - Boulder, 1333 Grandview Ave, Campus Box 488, Boulder, CO 80309 (United States)

    2010-01-15

    Over the past decade, questions regarding how to reduce human contributions to climate change have become more commonplace and non-nation state actors-such as businesses, non-government organizations, celebrities-have increasingly become involved in climate change mitigation and adaptation initiatives. For these dynamic and rapidly expanding spaces, this letter provides an accounting of the methods and findings from a 2007 assessment of greenhouse gas (GHG) emissions in the UK music industry. The study estimates that overall GHG emissions associated with the UK music market are approximately 540 000 t CO{sub 2}e per annum. Music recording and publishing accounted for 26% of these emissions (138 000 t CO{sub 2}e per annum), while three-quarters (74%) derived from activities associated with live music performances (400 000 t CO{sub 2}e per annum). These results have prompted a group of music industry business leaders to design campaigns to reduce the GHG emissions of their supply chains. The study has also provided a basis for ongoing in-depth research on CD packaging, audience travel, and artist touring as well as the development of a voluntary accreditation scheme for reducing GHG emissions from activities of the UK music industry.

  4. Assessing Embodied Energy and Greenhouse Gas Emissions in Infrastructure Projects

    Directory of Open Access Journals (Sweden)

    Jan Krantz

    2015-10-01

    Full Text Available Greenhouse gas (GHG emissions from construction processes are a serious concern globally. Of the several approaches taken to assess emissions, Life Cycle Assessment (LCA based methods do not just take into account the construction phase, but consider all phases of the life cycle of the construction. However, many current LCA approaches make general assumptions regarding location and effects, which do not do justice to the inherent dynamics of normal construction projects. This study presents a model to assess the embodied energy and associated GHG emissions, which is specifically adapted to address the dynamics of infrastructure construction projects. The use of the model is demonstrated on the superstructure of a prefabricated bridge. The findings indicate that Building Information Models/Modeling (BIM and Discrete Event Simulation (DES can be used to efficiently generate project-specific data, which is needed for estimating the embodied energy and associated GHG emissions in construction settings. This study has implications for the advancement of LCA-based methods (as well as project management as a way of assessing embodied energy and associated GHG emissions related to construction.

  5. Quantification and Controls of Wetland Greenhouse Gas Emissions

    Energy Technology Data Exchange (ETDEWEB)

    McNicol, Gavin [Univ. of California, Berkeley, CA (United States)

    2016-05-10

    Wetlands cover only a small fraction of the Earth’s land surface, but have a disproportionately large influence on global climate. Low oxygen conditions in wetland soils slows down decomposition, leading to net carbon dioxide sequestration over long timescales, while also favoring the production of redox sensitive gases such as nitrous oxide and methane. Freshwater marshes in particular sustain large exchanges of greenhouse gases under temperate or tropical climates and favorable nutrient regimes, yet have rarely been studied, leading to poor constraints on the magnitude of marsh gas sources, and the biogeochemical drivers of flux variability. The Sacramento-San Joaquin Delta in California was once a great expanse of tidal and freshwater marshes but underwent drainage for agriculture during the last two centuries. The resulting landscape is unsustainable with extreme rates of land subsidence and oxidation of peat soils lowering the surface elevation of much of the Delta below sea level. Wetland restoration has been proposed as a means to slow further subsidence and rebuild peat however the balance of greenhouse gas exchange in these novel ecosystems is still poorly described. In this dissertation I first explore oxygen availability as a control on the composition and magnitude of greenhouse gas emissions from drained wetland soils. In two separate experiments I quantify both the temporal dynamics of greenhouse gas emission and the kinetic sensitivity of gas production to a wide range of oxygen concentrations. This work demonstrated the very high sensitivity of carbon dioxide, methane, and nitrous oxide production to oxygen availability, in carbon rich wetland soils. I also found the temporal dynamics of gas production to follow a sequence predicted by thermodynamics and observed spatially in other soil or sediment systems. In the latter part of my dissertation I conduct two field studies to quantify greenhouse gas exchange and understand the carbon sources for

  6. Diffuse emissions of Volatile Organic Compounds (VOCs) from soil in volcanic and hydrothermal systems: evidences for the influence of microbial activity on the carbon budget

    Science.gov (United States)

    Venturi, Stefania; Tassi, Franco; Fazi, Stefano; Vaselli, Orlando; Crognale, Simona; Rossetti, Simona; Cabassi, Jacopo; Capecchiacci, Francesco

    2017-04-01

    Soils in volcanic and hydrothermal areas are affected by anomalously high concentrations of gases released from the deep reservoirs, which consists of both inorganic (mainly CO2 and H2S) and organic (volatile organic compounds; VOCs) species. VOCs in volcanic and hydrothermal fluids are mainly composed of saturated and unsaturated hydrocarbons (alkanes, aromatics, alkenes, and cyclics), with variable concentrations of O- and S-bearing compounds and halocarbons, depending on the physicochemical conditions at depth. VOCs in interstitial soil gases and fumarolic emissions from four volcanic and hydrothermal systems in the Mediterranean area (Solfatara Crater, Poggio dell'Olivo and Cava dei Selci, in Italy, and Nisyros Island, in Greece) evidenced clear compositional differences, suggesting that their behavior is strongly affected by secondary processes occurring at shallow depths and likely controlled by microbial activity. Long-chain saturated hydrocarbons were significantly depleted in interstitial soil gases with respect to those from fumarolic discharges, whereas enrichments in O-bearing compounds (e.g. aldehydes, ketones), DMSO2 and cyclics were commonly observed. Benzene was recalcitrant to degradation processes, whereas methylated aromatics were relatively instable. The chemical and isotopic (δ13C in CO2 and CH4) composition of soil gases collected along vertical profiles down to 50 cm depth at both Solfatara Crater and Poggio dell'Olivo (Italy) showed evidences of relevant oxidation processes in the soil, confirming that microbial activity likely plays a major role in modifying the composition of deep-derived VOCs. Despite their harsh conditions, being typically characterized by high temperatures, low pH, and high toxic gases and metal contents, the variety of habitats characterizing volcanic and hydrothermal environments offers ideal biomes to extremophilic microbes, whose metabolic activity can consume and/or produce VOCs. In the Solfatara Crater, microbial

  7. Volcanic hazards to airports

    Science.gov (United States)

    Guffanti, M.; Mayberry, G.C.; Casadevall, T.J.; Wunderman, R.

    2009-01-01

    Volcanic activity has caused significant hazards to numerous airports worldwide, with local to far-ranging effects on travelers and commerce. Analysis of a new compilation of incidents of airports impacted by volcanic activity from 1944 through 2006 reveals that, at a minimum, 101 airports in 28 countries were affected on 171 occasions by eruptions at 46 volcanoes. Since 1980, five airports per year on average have been affected by volcanic activity, which indicates that volcanic hazards to airports are not rare on a worldwide basis. The main hazard to airports is ashfall, with accumulations of only a few millimeters sufficient to force temporary closures of some airports. A substantial portion of incidents has been caused by ash in airspace in the vicinity of airports, without accumulation of ash on the ground. On a few occasions, airports have been impacted by hazards other than ash (pyroclastic flow, lava flow, gas emission, and phreatic explosion). Several airports have been affected repeatedly by volcanic hazards. Four airports have been affected the most often and likely will continue to be among the most vulnerable owing to continued nearby volcanic activity: Fontanarossa International Airport in Catania, Italy; Ted Stevens Anchorage International Airport in Alaska, USA; Mariscal Sucre International Airport in Quito, Ecuador; and Tokua Airport in Kokopo, Papua New Guinea. The USA has the most airports affected by volcanic activity (17) on the most occasions (33) and hosts the second highest number of volcanoes that have caused the disruptions (5, after Indonesia with 7). One-fifth of the affected airports are within 30 km of the source volcanoes, approximately half are located within 150 km of the source volcanoes, and about three-quarters are within 300 km; nearly one-fifth are located more than 500 km away from the source volcanoes. The volcanoes that have caused the most impacts are Soufriere Hills on the island of Montserrat in the British West Indies

  8. Upscaling of greenhouse gas emissions in upland forestry following clearfell

    Science.gov (United States)

    Toet, Sylvia; Keane, Ben; Yamulki, Sirwan; Blei, Emanuel; Gibson-Poole, Simon; Xenakis, Georgios; Perks, Mike; Morison, James; Ineson, Phil

    2016-04-01

    Data on greenhouse gas (GHG) emissions caused by forest management activities are limited. Management such as clearfelling may, however, have major impacts on the GHG balance of forests through effects of soil disturbance, increased water table, and brash and root inputs. Besides carbon dioxide (CO2), the biogenic GHGs nitrous oxide (N2O) and methane (CH4) may also contribute to GHG emissions from managed forests. Accurate flux estimates of all three GHGs are therefore necessary, but, since GHG emissions usually show large spatial and temporal variability, in particular CH4 and N2O fluxes, high-frequency GHG flux measurements and better understanding of their controls are central to improve process-based flux models and GHG budgets at multiple scales. In this study, we determined CO2, CH4 and N2O emissions following felling in a mature Sitka spruce (Picea sitchensis) stand in an upland forest in northern England. High-frequency measurements were made along a transect using a novel, automated GHG chamber flux system ('SkyLine') developed at the University of York. The replicated, linear experiment aimed (1) to quantify GHG emissions from three main topographical features at the clearfell site, i.e. the ridges on which trees had been planted, the hollows in between and the drainage ditches, and (2) to determine the effects of the green-needle component of the discarded brash. We also measured abiotic soil and climatic factors alongside the 'SkyLine' GHG flux measurements to identify drivers of the observed GHG emissions. All three topographic features were overall sources of GHG emissions (in CO2 equivalents), and, although drainage ditches are often not included in studies, GHG emissions per unit area were highest from ditches, followed by ridges and lowest in hollows. The CO2 emissions were most important in the GHG balance of ridges and hollows, but CH4 emissions were very high from the drainage ditches, contributing to over 50% of their overall net GHG emissions

  9. Characterization of the Etna volcanic emissions through an active biomonitoring technique (moss-bags): part 1--major and trace element composition.

    Science.gov (United States)

    Calabrese, S; D'Alessandro, W; Bellomo, S; Brusca, L; Martin, R S; Saiano, F; Parello, F

    2015-01-01

    Active biomonitoring using moss-bags was applied to an active volcanic environment for the first time. Bioaccumulation originating from atmospheric deposition was evaluated by exposing mixtures of washed and air-dried mosses (Sphagnum species) at 24 sites on Mt. Etna volcano (Italy). Concentrations of major and a large suite of trace elements were analysed by inductively coupled mass and optical spectrometry (ICP-MS and ICP-OES) after total acid digestion. Of the 49 elements analysed those which closely reflect summit volcanic emissions were S, Tl, Bi, Se, Cd, As, Cu, B, Na, Fe, Al. Enrichment factors and cluster analysis allowed clear distinction between volcanogenic, geogenic and anthropogenic inputs that affect the local atmospheric deposition. This study demonstrates that active biomonitoring with moss-bags is a suitable and robust technique for implementing inexpensive monitoring in scarcely accessible and harsh volcanic environments, giving time-averaged quantitative results of the local exposure to volcanic emissions. This task is especially important in the study area because the summit area of Mt. Etna is visited by nearly one hundred thousand tourists each year who are exposed to potentially harmful volcanic emissions. Copyright © 2014 Elsevier Ltd. All rights reserved.

  10. Indicators for Danish greenhouse gas emissions from 1990 to 2007

    Energy Technology Data Exchange (ETDEWEB)

    Lyck, E.; Nielsen, Malene; Nielsen, Ole-Kenneth; Winther, M.; Hoffmann, L.; Thomsen, M.

    2009-12-15

    The indicators defined according to the obligations under decisions of the EU Monitoring Mechanism have been worked out for 1990-2007. Discussions and comments on the definitions and the guidance of the indicators and their numerator and denominator were worked out. For many indicators the definitions and guidance were clear, for some indicators further text as definition and guidance would have been appropriate. Explanations on the data collection for the indicators for Denmark are given in this report. For the greenhouse gas emissions the source is the Danish inventories and the Danish inventory databases. For Economic data the source is Eurostat and for building data the source is Statistics Denmark. Only the energy, industry and transport sectors and only emissions of CO{sub 2} are covered by the indicators defined. A major result is that the main indicator (macro indicator 1) shows that the steady increase of gross domestic product is decoupled from the trend of the Danish national emissions of CO{sub 2}, since the indicator (the emissions divided by the GDP) in 2005-2007 decreased by 23-30 % compared to 1990. This decrease is mainly caused by higher efficiency in the heat and electricity production, a gradual shift to lesser CO{sub 2} emitting fuels, e.g. from coal to gas, and an increased use of biomass fuels. An important indicator for the industry sector is the CO{sub 2} emission over gross value added (priority indicator 4). The overall trend is a decrease from 1996 to 2007 after slightly fluctuating levels for the years 1990 to 1996. The rather steady increase of gross value added of industry, in 2007 27% above the 1990 level, simultaneously with an increase of CO{sub 2} emission of 5% only, is as for the macro indicator a decoupling. This causes the indicator in 2007 to be at 83 % of the 1990 level. The change to lower emitting fuels plays a role probably interplaying with the changes in industry structure towards less energy demanding industry. For

  11. Greenhouse gas emissions from municipal wastewater treatment plants

    Science.gov (United States)

    Parravicini, Vanessa; Svardal, Karl

    2016-04-01

    by a person in Germany or Austria (10.6 t CO2e/p/a, UBA, 2016). The results indicate that GHG emissions from WWTP have at global scale a small impact, as also highlighted by the Austrian national inventory report (NIR, 2015), where the estimated CO2e emissions from WWTPs account for only 0.23% of the total CO2e emission in Austria. References IPCC (2006). Intergovernmental Panel on Climate Change, Guidelines for National Greenhouse Gas Inventories, Prepared by the National Greenhouse Gas Inventories Program, Eggleston H.S., Buendia L., Miwa K., Ngara T. and Anabe K. (eds). Published: IGES, Japan. http://www.ipcc-nggip.iges.or.jp/public/2006gl/. NIR (2015). Austria's National Inventory Report 2015. Submission under the United Nations Framework Convention on Climate Change and under the Kyoto Protocol. Reports, Band 0552, ISBN: 978-3-99004-364-6, Umweltbundesamt, Wien. Parravicini V., Valkova T., Haslinger J., Saracevic E., Winkelbauer A., Tauber J., Svardal K., Hohenblum P., Clara M., Windhofer G., Pazdernik K., Lampert C. (2015). Reduktionspotential bei den Lachgasemissionen aus Kläranlagen durch Optimierung des Betriebes (ReLaKO). The research project was financially supported by the Ministry for agriculture, forestry, Environment and Water Management. Project leader: TU Wien, Institute for Water Quality, Ressources and Waste Management; Project partner: Umweltbundesamt GmbH. Final report: http://www.bmlfuw.gv.at/service/publikationen/wasser/Lachgasemissionen---Kl-ranlagen.html. UBA (2016). German average carbon footprint. Umweltbundesamt, Januar 2016, http://uba.klimaktiv-co2-rechner.de/de_DE/page/footprint/

  12. Reducing greenhouse gas emissions by recycling plastics and textiles into products

    OpenAIRE

    Korhonen, Marja-Riitta; Dahlbo, Helena

    2007-01-01

    Waste management generates greenhouse gas emissions. New waste management concepts for reducing these emissions are continuously being developed. In this study the potential of material recovery to reduce greenhouse gas emissions was assessed. The study was divided into two phases. In the first phase the material recovery concepts used in Finland were identified and approximate greenhouse gas emission savings calculations were conducted for some of the concepts. In the second phase two promis...

  13. Measurements of methane emissions at natural gas production sites in the United States

    OpenAIRE

    Allen, David T.; Torres, Vincent M.; Thomas, James; Sullivan, David W.; Harrison, Matthew; Hendler, Al; Herndon, Scott C.; Kolb, Charles E.; Fraser, Matthew P.; Hill, A. Daniel; Lamb, Brian K.; Miskimins, Jennifer; Sawyer, Robert F.; Seinfeld, John H.

    2013-01-01

    Engineering estimates of methane emissions from natural gas production have led to varied projections of national emissions. This work reports direct measurements of methane emissions at 190 onshore natural gas sites in the United States (150 production sites, 27 well completion flowbacks, 9 well unloadings, and 4 workovers). For well completion flowbacks, which clear fractured wells of liquid to allow gas production, methane emissions ranged from 0.01 Mg to 17 Mg (mean = 1.7 Mg; 95% confiden...

  14. Evaluation of sulfur dioxide emissions from explosive volcanism: the 1982-1983 eruptions of Galunggung, Java, Indonesia

    Science.gov (United States)

    Bluth, G.J.S.; Casadevall, T.J.; Schnetzler, C.C.; Doiron, S.D.; Walter, Louis S.; Krueger, A.J.; Badruddin, M.

    1994-01-01

    Galunggung volcano, Java, awoke from a 63-year quiescence in April 1982, and erupted sporadically through January 1983. During its most violent period from April to October, the Cikasasah Volcano Observatory reported 32 large and 56 moderate to small eruptions. From April 5 through September 19 the Total Ozone Mapping Spectrometer (TOMS), carried on NASA's Nimbus-7 satellite, detected and measured 24 different sulfur dioxide clouds; an estimated 1730 kilotons (kt) of SO2 were outgassed by these explosive eruptions. The trajectories, and rapid dispersion rates, of the SO2 clouds were consistent with injection altitudes below the tropopause. An additional 300 kt of SO2 were estimated to have come from 64 smaller explosive eruptions, based on the detection limit of the TOMS instrument. For the first time, an extended period of volcanic activity was monitored by remote sensing techniques which enabled observations of both the entire SO2 clouds produced by large explosive eruptions (using TOMS), and the relatively lower levels of SO2 emissions during non-explosive outgassing (using the Correlation Spectrometer, or COSPEC). Based on COSPEC measurements from August 1982 to January 1983, and on the relationship between explosive and non-explosive degassing, approximately 400 kt of SO2 were emitted during non-explosive activity. The total sulfur dioxide outgassed from Galunggung volcano from April 1982 to January 1983 is calculated to be 2500 kt (?? 30%) from both explosive and non-explosive activity. While Galunggung added large quantities of sulfur dioxide to the atmosphere, its sporadic emissions occurred in relatively small events distributed over several months, and reached relatively low altitudes, and are unlikely to have significantly affected aerosol loading of the stratosphere in 1982 by volcanic activity. ?? 1994.

  15. Estimating greenhouse gas emissions of European cities--modeling emissions with only one spatial and one socioeconomic variable.

    Science.gov (United States)

    Baur, Albert H; Lauf, Steffen; Förster, Michael; Kleinschmit, Birgit

    2015-07-01

    Substantive and concerted action is needed to mitigate climate change. However, international negotiations struggle to adopt ambitious legislation and to anticipate more climate-friendly developments. Thus, stronger actions are needed from other players. Cities, being greenhouse gas emission centers, play a key role in promoting the climate change mitigation movement by becoming hubs for smart and low-carbon lifestyles. In this context, a stronger linkage between greenhouse gas emissions and urban development and policy-making seems promising. Therefore, simple approaches are needed to objectively identify crucial emission drivers for deriving appropriate emission reduction strategies. In analyzing 44 European cities, the authors investigate possible socioeconomic and spatial determinants of urban greenhouse gas emissions. Multiple statistical analyses reveal that the average household size and the edge density of discontinuous dense urban fabric explain up to 86% of the total variance of greenhouse gas emissions of EU cities (when controlled for varying electricity carbon intensities). Finally, based on these findings, a multiple regression model is presented to determine greenhouse gas emissions. It is independently evaluated with ten further EU cities. The reliance on only two indicators shows that the model can be easily applied in addressing important greenhouse gas emission sources of European urbanites, when varying power generations are considered. This knowledge can help cities develop adequate climate change mitigation strategies and promote respective policies on the EU or the regional level. The results can further be used to derive first estimates of urban greenhouse gas emissions, if no other analyses are available.

  16. Understanding the Canadian oil sands industry's greenhouse gas emissions

    Science.gov (United States)

    Charpentier, Alex D.; Bergerson, Joule A.; MacLean, Heather L.

    2009-01-01

    The magnitude of Canada's oil sands reserves, their rapidly expanding and energy intensive production, combined with existing and upcoming greenhouse gas (GHG) emissions regulations motivate an evaluation of oil sands-derived fuel production from a life cycle perspective. Thirteen studies of GHG emissions associated with oil sands operations are reviewed. The production of synthetic crude oil (SCO) through surface mining and upgrading (SM&Up) or in situ and upgrading (IS&Up) processes is reported to result in emissions ranging from 62 to 164 and 99 to 176 kgCO2eq/bbl SCO, respectively (or 9.2-26.5 and 16.2-28.7 gCO2eq MJ-1 SCO, respectively), compared to 27-58 kgCO2eq/bbl (4.5-9.6 gCO2eq MJ-1) of crude for conventional oil production. The difference in emissions intensity between SCO and conventional crude production is primarily due to higher energy requirements for extracting bitumen and upgrading it into SCO. On a 'well-to-wheel' basis, GHG emissions associated with producing reformulated gasoline from oil sands with current SM&Up, IS&Up, and in situ (without upgrading) technologies are 260-320, 320-350, and 270-340 gCO2eq km-1, respectively, compared to 250-280 gCO2eq km-1 for production from conventional oil. Some variation between studies is expected due to differences in methods, technologies studied, and operating choices. However, the magnitude of the differences presented suggests that a consensus on the characterization of life cycle emissions of the oil sands industry has yet to be reached in the public literature. Recommendations are given for future studies for informing industry and government decision making.

  17. The Impact of a Potential Shale Gas Development in Germany and the United Kingdom on Pollutant and Greenhouse Gas Emissions

    Science.gov (United States)

    Weger, L.; Cremonese, L.; Bartels, M. P.; Butler, T. M.

    2016-12-01

    Several European countries with domestic shale gas reserves are considering extracting this natural gas resource to complement their energy transition agenda. Natural gas, which produces lower CO2 emissions upon combustion compared to coal or oil, has the potential to serve as a bridge in the transition from fossil fuels to renewables. However, the generation of shale gas leads to emissions of CH4 and pollutants such as PM, NOx and VOCs, which in turn impact climate as well as local and regional air quality. In this study, we explore the impact of a potential shale gas development in Europe, specifically in Germany and the United Kingdom, on emissions of greenhouse gases and pollutants. In order to investigate the effect on emissions, we first estimate a range of wells drilled per year and production volume for the two countries under examination based on available geological information and on regional infrastructural and economic limitations. Subsequently we assign activity data and emissions factors to the well development, gas production and processing stages of shale gas generation to enable emissions quantification. We then define emissions scenarios to explore different storylines of potential shale gas development, including low emissions (high level of regulation), high emissions (low level of regulation) and middle emissions scenarios, which influence fleet make-up, emission factor and activity data choices for emissions quantification. The aim of this work is to highlight important variables and their ranges, to promote discussion and communication of potential impacts, and to construct possible visions for a future shale gas development in the two study countries. In a follow-up study, the impact of pollutant emissions from these scenarios on air quality will be explored using the Weather Research and Forecasting model with chemistry (WRF-Chem) model.

  18. Production and emission of phosphine gas from wetland ecosystems.

    Science.gov (United States)

    Han, Chao; Gu, Xueyuan; Geng, Jinju; Hong, Yuning; Zhang, Rui; Wang, Xiaorong; Gao, Shixiang

    2010-01-01

    Phosphine is a part of an atmospheric link of phosphorus cycle on earth, which could be an important pathway for phosphorus transport in environment. Wetland ecosystems are important locations for global biogeochemical phosphorus cycle. In this study, production and emission fluxes of free phosphine from four wetlands types in southern China were observed in different seasons. The results showed that the concentration of phosphine liberated from wetlands was at pg/m3-ng/m3 level. The emission concentrations of different wetlands followed the sequence: paddy field (51.83 +/- 3.06) ng/m3 > or = marsh (46.54 +/- 20.55) ng/m3 > lake (37.05 +/- 22.74) ng/m3 > coastal wetland (1.71 +/- 0.73) ng/m3, the positive phosphine emission flux occurred in rice paddy field (6.67 +/- 5.18) ng/(m2 x hr) and marsh (6.23 +/- 26.9) ng/(m2 x hr), while a negative phosphine flux of (-13.11 +/- 35.04) ng/(m2 x hr) was observed on the water-air interface of Lake Taihu, suggesting that paddy field and marsh may be important sources for phosphine gas in atmosphere, while lake may be a sink of atmospheric phosphine gas during the sampling period. Atmospheric phosphine levels and emission flux from Yancheng marsh and rice paddy field varied in different seasons and vegetational zones. Both diffusion resistance in aqueous phase and temperature were dominating factors for the production and transportation of phosphine to atmosphere.

  19. Potential of greenhouse gas emission reductions in soybean farming

    DEFF Research Database (Denmark)

    Mohammadi, Ali; Dalgaard, Tommy; Knudsen, Marie Trydeman

    2013-01-01

    Joint implementation of Life Cycle Assessment (LCA) and Data Envelopment Analysis (DEA) has recently showed to be a suitable tool for measuring efficiency in agri-food systems. In the present study, LCA + DEA methodologies were applied for a total of 94 soybean farms in Iran to benchmark the level...... residue in the field generate significantly more greenhouse gas emissions than other farms. The raising of operational input efficiency and limiting of crop residue burning in the field are recommended options to ensure more environmental friendly soybean farming systems in the region....

  20. Scenarios for a Nordic Power System without Greenhouse Gas Emissions

    DEFF Research Database (Denmark)

    Graabak, Ingeborg; Nilsson, Måns; Wu, Qiuwei

    2014-01-01

    The paper presents scenarios for power production without greenhouse gas (GHG) emissions in Denmark, Finland, Norway and Sweden by 2050. The Nordic region already has a high share of renewables in its power production portfolio (about 60% in 2010), and possibilities for further deployment are very...... profitable investments in transmission grids with particular focus on the interconnections between the Nordic region and Continental Europe - Technical simulations of the power system with focus on balancing of large shares of non-dispatchable renewable resources in a future system. - Assess impacts...

  1. Technology Opportunities to Reduce U.S. Greenhouse Gas Emissions

    Energy Technology Data Exchange (ETDEWEB)

    1997-10-01

    This report serves as the technology basis of a needed national climate change technology strategy, with the confidence that a strong technology R&D program will deliver a portfolio of technologies with the potential to provide very substantial greenhouse gas emission reductions along with continued economic growth. Much more is needed to define such a strategy, including identification of complementary deployment policies and analysis to support the seeping and prioritization of R&D programs. A national strategy must be based upon governmental, industrial, and academic partnerships.

  2. Multi-component gas emission measurements of the active lava lake of Nyiragongo, DR Congo

    Science.gov (United States)

    Bobrowski, N.; Giuffrida, G. B.; Yalire, M.; Lübcke, P.; Arellano, S.; Balagizi, C.; Calabrese, S.; Galle, B.; Tedesco, D.

    2017-10-01

    diffuse and fumarolic degassing could have significant influence on measured gas composition. The measured gas composition might rather represent a gas mixture of plume, diffuse and fumarolic degassing than only representing the volcanic plume. 2. It is proposed that the interruption of the convection has taken place in the upper part of the conduit and deep degassing of CO2 and bromine initially continues while mixing already with gas emissions from an ageing source, which is characterized by an already diminishing sulfur content. These complex process but as well as the gas mixing of different sources, could explain general features of our dataset, but can unfortunately neither be confirmed nor disproven by the data available today.

  3. Impact of routine episodic emissions on the expected frequency distribution of emissions from oil and gas production sources.

    Science.gov (United States)

    Smith, N.; Blewitt, D.; Hebert, L. B.

    2015-12-01

    In coordination with oil and gas operators, we developed a high resolution (oil and gas emissions over a year. We include routine emissions from condensate tanks, dehydrators, pneumatic devices, fugitive leaks and liquids unloading. We explore the variability in natural gas emissions from these individual well-pad sources, and find that routine short-term episodic emissions such as tank flashing and liquids unloading result in the appearance of a skewed, or 'fat-tail' distribution of emissions, from an individual well-pad over time. Additionally, we explore the expected variability in emissions from multiple wells with different raw gas composition, gas/liquids production volumes and control equipment. Differences in well-level composition, production volume and control equipment translate into differences in well-level emissions leading to a fat-tail distribution of emissions in the absence of operational upsets. Our results have several implications for recent studies focusing on emissions from oil and gas sources. Time scale of emission estimates are important and have important policy implications. Fat tail distributions may not be entirely driven by avoidable mechanical failures, and are expected to occur under routine operational conditions from short-duration emissions (e.g., tank flashing, liquid unloading). An understanding of the expected distribution of emissions for a particular population of wells is necessary to evaluate whether the observed distribution is more skewed than expected. Temporal variability in well-pad emissions make comparisons to annual average emissions inventories difficult and may complicate the interpretation of long-term ambient fenceline monitoring data. Sophisticated change detection algorithms will be necessary to identify when true operational upsets occur versus routine short-term emissions.

  4. Communicating the Uncertainty in Greenhouse Gas Emissions from Agriculture

    Science.gov (United States)

    Milne, Alice; Glendining, Margaret; Perryman, Sarah; Whitmore, Andy

    2014-05-01

    Effective communication of the uncertainty in estimates of greenhouse gas emissions is important. It allows an individual, whether they are a scientist, policy maker or member of the public, to draw proper conclusions and so make sound decisions. Communicating uncertainty is challenging, however. There is no single best method for communicating uncertainty and the success of a particular method will depend on the subject matter and the target audience. Our interest is in communicating the uncertainty in estimates of greenhouse gas emissions from agriculture to those who might directly use the results from a national inventory. We tested six methods of communication. These were: calibrated phrases such as 'very uncertain' and 'likely'; probabilities, whereby the probability of being within a defined range of values is given; confidence intervals for the expected value; histograms; box plots and shaded arrays. We asked 64 individuals who use results from the greenhouse gas inventory for their opinions on how successfully these methods communicated uncertainty. We analysed the results to see which methods were preferred and to see whether this preference was affected either by the professional group to which individuals belonged or the level of mathematics to which they were educated. The professional groups represented in our study were categorised as (i) those who influence policy (ii) research scientists (iii) those representing the environment and (iv) those representing the agricultural industry. The responses to our questionnaire were varied but some clear messages came through. Our analysis showed that although calibrated phrases were thought to be a good method of communication they did not convey enough information and were open to misinterpretation. Shaded arrays were similarly criticized for being open to misinterpretation, but proved to give the best indication of uncertainty when individuals were asked to interpret results from the greenhouse gas

  5. Low emissions combustor development for an industrial gas turbine to utilize LCV fuel gas

    Energy Technology Data Exchange (ETDEWEB)

    Kelsall, G.J.; Smith, M.A. (British Coal Corp., Glos (United Kingdom). Coal Research Establishment); Cannon, M.F. (European Gas Turbines Ltd., Lincoln (United Kingdom). Aero and Technology Products)

    1994-07-01

    Advanced coal-based power generation systems such as the British Coal Topping Cycle offer the potential for high-efficiency electricity generation with minimum environmental impact. An important component of the Topping cycle program is the gas turbine, for which development of a combustion system to burn low calorific value coal derived fuel gas, at a turbine inlet temperature of 1,260 C (2,300 F), with minimum pollutant emissions, is a key R and D issue. A phased combustor development program is underway burning low calorific value fuel gas (3.6--4.1 MJ/m[sup 3]) with low emissions, particularly NO[sub x] derived from fuel-bound nitrogen. The first phase of the combustor development program has now been completed using a generic tubo-annular, prototype combustor design. Tests were carried out at combustor loading and Mach numbers considerably greater than the initial design values. Combustor performance at these conditions was encouraging. The second phase of the program is currently in progress. This will assess, initially, an improved variant of the prototype combustor operating at conditions selected to represent a particular medium sized industrial gas turbine. This combustor will also be capable of operating using natural gas as an auxiliary fuel, to suite the start-up procedure for the Topping Cycle. The paper presents the Phase 1 test program results for the prototype combustor. Design of the modified combustor for Phase 2 of the development program is discussed, together with preliminary combustor performance results.

  6. Greenhouse gas emissions and energy balance of palm oil biofuel

    Energy Technology Data Exchange (ETDEWEB)

    de Souza, Simone Pereira; Pacca, Sergio [Graduate Program on Environmental Engineering Science, School of Engineering of Sao Carlos, University of Sao Paulo, Rua Arlindo Bettio, 1000 Sao Paulo (Brazil); de Avila, Marcio Turra; Borges, Jose Luiz B. [Brazilian Agricultural Research Corporation (Embrapa - Soja) (Brazil)

    2010-11-15

    The search for alternatives to fossil fuels is boosting interest in biodiesel production. Among the crops used to produce biodiesel, palm trees stand out due to their high productivity and positive energy balance. This work assesses life cycle emissions and the energy balance of biodiesel production from palm oil in Brazil. The results are compared through a meta-analysis to previous published studies: Wood and Corley (1991) [Wood BJ, Corley RH. The energy balance of oil palm cultivation. In: PORIM intl. palm oil conference - agriculture; 1991.], Malaysia; Yusoff and Hansen (2005) [Yusoff S, Hansen SB. Feasibility study of performing an life cycle assessment on crude palm oil production in Malaysia. International Journal of Life Cycle Assessment 2007;12:50-8], Malaysia; Angarita et al. (2009) [Angarita EE, Lora EE, Costa RE, Torres EA. The energy balance in the palm oil-derived methyl ester (PME) life cycle for the cases in Brazil and Colombia. Renewable Energy 2009;34:2905-13], Colombia; Pleanjai and Gheewala (2009) [Pleanjai S, Gheewala SH. Full chain energy analysis of biodiesel production from palm oil in Thailand. Applied Energy 2009;86:S209-14], Thailand; and Yee et al. (2009) [Yee KF, Tan KT, Abdullah AZ, Lee KT. Life cycle assessment of palm biodiesel: revealing facts and benefits for sustainability. Applied Energy 2009;86:S189-96], Malaysia. In our study, data for the agricultural phase, transport, and energy content of the products and co-products were obtained from previous assessments done in Brazil. The energy intensities and greenhouse gas emission factors were obtained from the Simapro 7.1.8. software and other authors. These factors were applied to the inputs and outputs listed in the selected studies to render them comparable. The energy balance for our study was 1:5.37. In comparison the range for the other studies is between 1:3.40 and 1:7.78. Life cycle emissions determined in our assessment resulted in 1437 kg CO{sub 2}e/ha, while our analysis

  7. Magma-derived gas influx and water-rock interactions in the volcanic aquifer of Mt. Vesuvius, Italy

    Science.gov (United States)

    Federico, C.; Aiuppa, A.; Allard, P.; Bellomo, S.; Jean-Baptiste, P.; Parello, F.; Valenza, M.

    2002-03-01

    We report in this paper a systematic investigation of the chemical and isotopic composition of groundwaters flowing in the volcanic aquifer of Mt. Vesuvius during its current phase of dormancy, including the first data on dissolved helium isotope composition and tritium content. The relevant results on dissolved He and C presented in this paper reveal that an extensive interaction between rising magmatic volatiles and groundwaters currently takes place at Vesuvius. Vesuvius groundwaters are dilute (mean TDS ˜ 2800 mg/L) hypothermal fluids ( mean T = 17.7°C) with a prevalent alkaline-bicarbonate composition. Calcium-bicarbonate groundwaters normally occur on the surrounding Campanian Plain, likely recharged from the Apennines. δD and δ 18O data evidence an essentially meteoric origin of Vesuvius groundwaters, the contribution from either Tyrrhenian seawater or 18O-enriched thermal water appearing to be small or negligible. However, the dissolution of CO 2-rich gases at depth promotes acid alteration and isochemical leaching of the permeable volcanic rocks, which explains the generally low pH and high total carbon content of waters. Attainment of chemical equilibrium between the rock and the weathering solutions is prevented by commonly low temperature (10 to 28°C) and acid-reducing conditions. The chemical and isotope (C and He) composition of dissolved gases highlights the magmatic origin of the gas phase feeding the aquifer. We show that although the pristine magmatic composition may vary upon gas ascent because of either dilution by a soil-atmospheric component or fractionation processes during interaction with the aquifer, both 13C/ 12C and 3He/ 4He measurements indicate the contribution of a magmatic component with a δ 13C ˜ 0‰ and R/R a of ˜2.7, which is consistent with data from Vesuvius fumaroles and phenocryst melt inclusions in olivine phenocrysts. A main control of tectonics on gas ascent is revealed by data presented in this paper. For example

  8. 75 FR 41173 - Call for Information: Information on Greenhouse Gas Emissions Associated With Bioenergy and Other...

    Science.gov (United States)

    2010-07-15

    ... Intergovernmental Panel on Climate Change (IPCC). \\2\\ US EPA. 2010. Inventory of U.S. Greenhouse Gas Emissions and.... Greenhouse Gas Emissions and Sinks: 1990-2008. U.S. EPA 430-R-10-06. Intergovernmental Panel on Climate Change (IPCC). 1996. Revised 1996 IPCC Guidelines for National Greenhouse Gas Inventories, Prepared......

  9. CO and PAH Emissions from Engines Operating on Biomass Producer Gas

    DEFF Research Database (Denmark)

    Ahrenfeldt, Jesper; Jensen, Torben Kvist; Henriksen, Ulrik Birk

    2003-01-01

    High carbon monoxide (CO) emission from gas engines fueled by producer gas is a concerning problem in the struggle to make biomass gasification for heat and power production a success. The standing regulations concerning CO emissions from producer gas engine based power plants in most EU countries...

  10. Microbial mitigation of greenhouse gas emissions from landfill cover soils

    Science.gov (United States)

    Lee, Sung-Woo

    Landfills are one of the major sources of methane (CH4), a potent greenhouse gas with a global warming potential (GWP) ˜23 times higher than that of carbon dioxide (CO2). Although some effective strategies have been formulated to prevent methane emissions from large landfills, many landfills allow methane to be freely emitted to the atmosphere. In such situations, it is often proposed to stimulate methanotrophs, a group of bacteria that consume methane, in the cover soil to prevent fugitive methane emissions. Several factors, however, must be addressed to make such a biogenic removal mechanism effective. First, methanotrophic activity can be inhibited by nonmethane organic compounds (NMOCs) that are commonly found in landfill soil gas. Second, although methanotrophs can be easily stimulated with the addition of nitrogenous fertilizers, biogenic production of nitrous oxide with a GWP ˜296 times higher than that of carbon dioxide, is also stimulated. To consider these issues, two general areas of research were performed. First, a dimensionless number was developed based on Michaelis-Menten kinetics that describes the effects of the presence of multiple NMOCs on methanotrophic growth and survival. This model was validated via experimental measurements of methanotrophic growth in the presence of varying amounts of NMOCs. Second, the effects of nutrient amendments on methane oxidation and nitrous oxide production were examined by constructing soil microcosms using landfill cover soils. Here, it was shown that the addition of ammonium in the presence of phenylacetylene stimulated methane oxidation but inhibited nitrous oxide production. Furthermore, to understand the methanotrophic community structure and activity in response to these amendments, DNA microarray and transcript analyses were performed. The results indicated the predominance of Type II methanotrophs but that Type I methanotrophs responded more significantly to these amendments. Also, substantial activity

  11. Volcanic ash ingestion by a large gas turbine aeroengine: fan-particle interaction

    Science.gov (United States)

    Vogel, Andreas; Clarkson, Rory; Durant, Adam; Cassiani, Massimo; Stohl, Andreas

    2016-04-01

    Airborne particles from explosive volcanic eruptions are a major safety threat for aviation operations. The fine fraction of the emitted particles ( 20 microns) tend to be transported into the bypass duct of the engine (by the centrifugal effect of the fan), whereas the smaller particles follow the fluid flow streamlines and are distributed homogenously in the engine (bypass ducts and core region). This result is significant as it indicates that the absolute ash mass that causes issues for aeroengine operation is a fraction of the ambient (observed or forecast) ash quantity.

  12. Observations of Gas Emissions from Cascade Range Volcanoes (USA) using a Portable Real-Time Sensor Package and Evacuated Flasks

    Science.gov (United States)

    Kelly, P. J.; Werner, C. A.; Evans, W.; Ingebritsen, S.; Tucker, D.

    2012-12-01

    Degassing from most Cascade Range Volcanoes, USA, is characterized by low-temperature hydrothermal emissions. It is important to monitor these emissions as part of a comprehensive monitoring strategy yet access is often difficult and most features are sampled by the USGS only once per year at best. In an effort to increase the sampling frequency of major gas species and in preparation for building permanent, autonomous units, we built a portable sensor package capable of measuring H2O, CO2, SO2, and H2S in volcanic gas plumes. Here we compare results from the portable sensor package with gas analyses from direct samples obtained using a titanium tube and evacuated glass flasks collected at the same time. The sensor package is housed in a small, rugged case, weighs 5 kg, and includes sensors for measuring H2O (0-16 parts per thousand), CO2 (0-5000 ppmv), SO2 (0-100 ppm), and H2S (0-20 ppm) gases. Additional temperature and pressure sensors, a micro air pump, datalogger, and an internal battery are also incorporated. H2O and CO2 are measured using an infrared spectrometer (Licor 840) and sulfur-containing gases are measured using electrochemical sensors equipped with filters to mitigate cross-sensitivities. Data are collected at a 1 Hz sampling rate and can be recorded and displayed in real-time using a netbook computer or can be saved to the onboard datalogger. The data display includes timeseries of H2O, CO2, SO2, and H2S mixing ratios, the four-component bulk composition of the plume, and automated calculation of gas ratios commonly used in volcanic gas monitoring, such as H2O/CO2, CO2/SO2, and CO2/H2S . In the Cascade Range, the sensor package has been tested at Mt. Baker, Mt. St. Helens, Mt. Hood, and in Lassen Volcanic National Park. In each case, the instrument was placed 5 to 30 meters from the fumarole or fumarole field and emissions were sampled for 5 to 30 minutes. No SO2 was detected at any location. At Mt. Hood the sensor package yielded average CO2/H2S

  13. Gas emission from anaerobic decomposition of plant resources

    Directory of Open Access Journals (Sweden)

    Marcela Bianchessi da Cunha-Santino

    Full Text Available Abstract: Aim The aim of this study was to quantify the emission rates of gases resulting from the anaerobic decomposition of different plant resources under conditions usually found in sediments of tropical aquatic systems and drained organic soils. Methods Incubations were prepared with green leaves, bark, twigs, plant litter, sugarcane stalks and leaves, soybean leaves, grasses, forest leaves and an aquatic macrophyte (Typha domingensis. Over 10 months, the daily volume of gas evolved from decay was measured and a kinetic model was used to describe the anaerobic mineralization. Results Using the mathematical model, it can be observed that the composition of the plant resources is heterogeneous. The temporal variation of the gas rates indicated that the mineralization of the labile fractions of detritus varied, on a carbon basis, from 16.2 (bark to 100% (samples composed of leaves, grasses and sugar cane stalks. High gas emissions were observed during the mineralization of grasses, sugar cane stalks, leaves and plant litter, while low volumes of gases were measured during the mineralization of bark, twigs, forest leaves and T. domingensis, which are the most fibrous and recalcitrant resources (carbon content: 83.8, 78.2, 64.8 and 53.4%, respectively. The mineralization of labile carbon presented half-life values, which varied from 41 (twigs to 295 days (grasses. Conclusions Considering the high amount of remaining recalcitrant fraction, the anaerobic decomposition of these plant resources showed a strong trend towards accumulating organic matter in flooded soils. Despite the higher temperatures found in the tropical environment, these environments represent a sink of particulate detritus due to its slow decomposition.

  14. Evaluation of Greenhouse Gas Emission from Animal Manure Using the Closed Chamber Method for Gas Fluxes

    Directory of Open Access Journals (Sweden)

    Sebastian Călin VAC

    2013-12-01

    Full Text Available Animal manure is an important source of anthropogenic GHG (greenhouse gas: methane (CH4, nitrous oxide (N2O and carbon dioxide (CO2. The livestock contributes with 37% of global CH4 emission. The sources of GHG (CO2 and CH4 are the liquid manure or slurry storage and the compact solid manure. Measurement systems of GHG emission are important for the selection of the appropriate technology. By using the closed chamber method for soil, landfills, volcanoes etc., the present study evaluates the estimation of total emissions of methane and carbon dioxide from an experimental farm in Cluj County, Romania. The investigated area covered with sheep solid manure was about 579 m2 and ~5 cm thick, for cattle was about 12 m2 and 5 m thick and for swine was about 1.5 m5 and 0.5 m thick. The total methane emission measured for sheep manure was 0.83 t CH4/year and for cattle manure was 0.185 t CH4/year. The total carbon dioxide emission measured for sheep manure was 61.3 t CO2/year and for cattle manure was 4.7 t CO2/year. The measurement for pigs manure was high and this could be due to the freshness of the manure. The estimated emissions showed that a considerable amount of CH4 and CO2 is produced also by an experimental farm and an appropriate management of manure is important for reducing greenhouse gas. In this respect, we believe that the future solution for a green economy is to use manure in biogas plants.

  15. Numerical modelling of gas-water-rock interactions in volcanic-hydrothermal environment: the Ischia Island (Southern Italy) case study.

    Science.gov (United States)

    Di Napoli, R.; Federico, C.; Aiuppa, A.; D'Antonio, M.; Valenza, M.

    2012-04-01

    Hydrothermal systems hosted within active volcanic systems represent an excellent opportunity to investigate the interactions between aquifer rocks, infiltrating waters and deep-rising magmatic fluids, and thus allow deriving information on the activity state of dormant volcanoes. From a thermodynamic perspective, gas-water-rock interaction processes are normally far from equilibrium, but can be represented by an array of chemical reactions, in which irreversible mass transfer occurs from host rock minerals to leaching solutions, and then to secondary hydrothermal minerals. While initially developed to investigate interactions in near-surface groundwater environments, the reaction path modeling approach of Helgeson and co-workers can also be applied to quantitative investigation of reactions in high T-P environments. Ischia volcano, being the site of diffuse hydrothermal circulation, is an ideal place where to test the application of reaction-path modeling. Since its last eruption in 1302 AD, Ischia has shown a variety of hydrothermal features, including fumarolic emissions, diffuse soil degassing and hot waters discharges. These are the superficial manifestation of an intense hydrothermal circulation at depth. A recent work has shown the existence of several superposed aquifers; the shallowest (near to boiling) feeds the numerous surface thermal discharges, and is recharged by both superficial waters and deeper and hotter (150-260°C) hydrothermal reservoir fluids. Here, we use reaction path modelling (performed by using the code EQ3/6) to quantitatively constrain the compositional evolution of Ischia thermal fluids during their hydrothermal flow. Simulations suggest that compositions of Ischia groundwaters are buffered by interactions between reservoir rocks and recharge waters (meteoric fluids variably mixed - from 2 to 80% - with seawater) at shallow aquifer conditions. A CO2 rich gaseous phase is also involved in the interaction processes (fCO2 = 0.4-0.6 bar

  16. Magmatic gas flux emissions from Gorelyi volcano, Kamchatka, and implications for volatile recycling in the NW Pacific

    Science.gov (United States)

    Aiuppa, A.; Bagnato, E.; Calabrese, S.; Giudice, G.; Liuzzo, M.; Tamburello, G.; Allard, P.; Chaplygin, I.; Taran, Y.

    2012-04-01

    The Kamchatka peninsula, in the north-western part of the Pacific 'Ring of Fire', is one of the most active volcanic realms on Earth, with 29 historically erupting volcanoes along its ~700 km-long Eastern Volcanic Belt (EVB). This notwithstanding, volatile input and output fluxes along this arc sector have remained poorly characterised until very recently. We here report on the very first assessment of volatile flux emissions from Gorelyi, a large (25 km3, 1830 m high) and most active shield-like Holocene volcano located on the southern segment of the Kamchatka EVB. By combing results from a variety of in situ and remote sensing techniques (MultiGAS, filter packs, and UV camera), we determine the bulk plume molar concentrations of major (H2O 93.5%, CO2 2.6%, SO2 2.2%, HCl 1.1%, HF 0.3%, H2 0.2%) to trace-halogens (Br, I) and trace-element volatile species, and we estimate a total gas release of ~11,000 t/day from Gorelyi during ~900°C non-eruptive degassing. Using this observation, we derive new constraints on the abundances and origins of volatiles in the subduction-modified mantle source feeding magmatism in Kamchatka.

  17. Light-noble-gas isotopic ratios in gases from Mt. Etna (Southern Italy). Implications for mantle contamination and volcanic activity

    Energy Technology Data Exchange (ETDEWEB)

    Italiano, F. [Consiglio Nazionale delle Ricerche, Palermo (Italy). Ist. di Geochimica dei Fluidi; Nuccio, P.M. [Palermo Univ., Palermo (Italy). Ist. di Mineralogia, Petrografia e Geochimica; Nakai, S. [Tokyo Univ., Tokyo (Japan). Lab. for Earthquake Chemistry; Wakita, H. [Tokyo Univ., Tokyo (Japan). Earthquake Research Inst.

    1999-08-01

    Taking into account the light-noble-isotopic ratios signature of gas samples coming from the Etnean area (Southern Italy), it seems that in this area the crustal contamination played a minor role. Instead, processes that enriched the original MORB-type mantle in incompatible elements, have to be considered. The {sup 3}He/{sup 4}He ratios are, thus, lowered because of {sup 1}He produced by radioactive decay of U and Th. On the other hand, helium isotopic ratios have shown wide temporal variations sometimes reaching values as high as 7.6 Ra, out pf typical Etnean range. As these unusually high ratios have been measured during phases of unrest of the volcanic activity at Mt. Etna, this apparent discrepancy in the helium isotopic ratios is considered, as the effect of fractionation processes occurred during the magma uprising.

  18. Greenhouse Gas Emissions from Three Cage Layer Housing Systems

    Directory of Open Access Journals (Sweden)

    John Feddes

    2011-12-01

    Full Text Available Agriculture accounts for 10 to 12% of the World’s total greenhouse gas (GHG emissions. Manure management alone is responsible for 13% of GHG emissions from the agricultural sector. During the last decade, Québec’s egg production systems have shifted from deep-pit housing systems to manure belt housing systems. The objective of this study was to measure and compare carbon dioxide (CO2, methane (CH4 and nitrous oxide (N2O emissions from three different cage layer housing systems: a deep liquid manure pit and a manure belt with natural or forced air drying. Deep liquid manure pit housing systems consist of “A” frame layer cages located over a closed pit containing the hens’ droppings to which water is added to facilitate removal by pumping. Manure belt techniques imply that manure drops on a belt beneath each row of battery cages where it is either dried naturally or by forced air until it is removed. The experiment was replicated with 360 hens reared into twelve independent bench-scale rooms during eight weeks (19–27 weeks of age. The natural and forced air manure belt systems reduced CO2 (28.2 and 28.7 kg yr−1 hen−1, respectively, CH4 (25.3 and 27.7 g yr−1 hen−1, respectively and N2O (2.60 and 2.48 g yr−1 hen−1, respectively emissions by about 21, 16 and 9% in comparison with the deep-pit technique (36.0 kg CO2 yr−1 hen−1, 31.6 g CH4 yr−1 hen−1 and 2.78 g N2O yr−1 hen−1. The shift to manure belt systems needs to be encouraged since this housing system significantly decreases the production of GHG.

  19. a Review of Hydropower Reservoir and Greenhouse Gas Emissions

    Science.gov (United States)

    Rosa, L. P.; Dos Santos, M. A.

    2013-05-01

    Like most manmade projects, hydropower dams have multiple effects on the environment that have been studied in some depth over the past two decades. Among their most important effects are potential changes in water movement, flowing much slower than in the original river. This favors the appearance of phytoplankton as nutrients increase, with methanogenesis replacing oxidative water and generating anaerobic conditions. Although research during the late 1990s highlighted the problems caused by hydropower dams emitting greenhouse gases, crucial aspects of this issue still remain unresolved. Similar to natural water bodies, hydropower reservoirs have ample biota ranging from microorganisms to aquatic vertebrates. Microorganisms (bacteria) decompose organic matter producing biogenic gases under water. Some of these biogenic gases cause global warming, including methane, carbon dioxide and nitrous oxide. The levels of GHG emissions from hydropower dams are a strategic matter of the utmost importance, and comparisons with other power generation options such as thermo-power are required. In order to draw up an accurate assessment of the net emissions caused by hydropower dams, significant improvements are needed in carbon budgets and studies of representative hydropower dams. To determine accurately the net emissions caused by hydro reservoir formation is required significant improvement of carbon budgets studies on different representatives' hydro reservoirs at tropical, boreal, arid, semi arid and temperate climate. Comparisons must be drawn with emissions by equivalent thermo power plants, calculated and characterized as generating the same amount of energy each year as the hydropower dams, burning different fuels and with varying technology efficiency levels for steam turbines as well as coal, fuel oil and natural gas turbines and combined cycle plants. This paper brings to the scientific community important aspects of the development of methods and techniques applied

  20. Estimating greenhouse gas emissions of European cities — Modeling emissions with only one spatial and one socioeconomic variable

    Energy Technology Data Exchange (ETDEWEB)

    Baur, Albert H., E-mail: Albert.H.Baur@campus.tu-berlin.de; Lauf, Steffen; Förster, Michael; Kleinschmit, Birgit

    2015-07-01

    Substantive and concerted action is needed to mitigate climate change. However, international negotiations struggle to adopt ambitious legislation and to anticipate more climate-friendly developments. Thus, stronger actions are needed from other players. Cities, being greenhouse gas emission centers, play a key role in promoting the climate change mitigation movement by becoming hubs for smart and low-carbon lifestyles. In this context, a stronger linkage between greenhouse gas emissions and urban development and policy-making seems promising. Therefore, simple approaches are needed to objectively identify crucial emission drivers for deriving appropriate emission reduction strategies. In analyzing 44 European cities, the authors investigate possible socioeconomic and spatial determinants of urban greenhouse gas emissions. Multiple statistical analyses reveal that the average household size and the edge density of discontinuous dense urban fabric explain up to 86% of the total variance of greenhouse gas emissions of EU cities (when controlled for varying electricity carbon intensities). Finally, based on these findings, a multiple regression model is presented to determine greenhouse gas emissions. It is independently evaluated with ten further EU cities. The reliance on only two indicators shows that the model can be easily applied in addressing important greenhouse gas emission sources of European urbanites, when varying power generations are considered. This knowledge can help cities develop adequate climate change mitigation strategies and promote respective policies on the EU or the regional level. The results can further be used to derive first estimates of urban greenhouse gas emissions, if no other analyses are available. - Highlights: • Two variables determine urban GHG emissions in Europe, assuming equal power generation. • Household size, inner-urban compactness and power generation drive urban GHG emissions. • Climate policies should consider

  1. Estimation of volcanic ash emissions with satellite data: The inclusion of mass loading and plume height information in modified 4D-Var

    Science.gov (United States)

    Lu, Sha; Lin, Hai Xiang; Heemink, Arnold; Segers, Arjo; Fu, Guangliang

    2015-04-01

    Volcanic ash forecasting is a critical tool in hazard assessment and operational volcano monitoring. Emission parameters such as injection height, total emission mass and vertical distribution of the emission plume rate are essential and important in the implementation of volcanic ash models. Satellite instrument is a powerful tool to monitor volcanic aerosol evolution and satellite total-column data has been integrated in the modeling process to achieve a better initial condition for the forecasting. However, the use of total-column data,which has no vertical resolution, usually leads to an ill-conditioned problem and ineffective estimation of emission parameters. Fortunately, techniques to retrieve the information of total ash mass loading and injection height from satellite data has been developed recently. It provides a new possibility to increase the accuracy of estimation results by integrating them into data assimilation systems. In this work we propose a modified 4D-Var approach which seek the vertical emission distribution by observing ash cloud transport patterns from satellite total-ash-columns data, and two ways of including the information of mass loading and plume height in the assimilation process. The modified 4D-Var based on trajectory statistics forms a reformulated cost function which computes the total difference between observed ash columns and a linear combination of simulated ensemble columns coupled with a priori emission knowledge ('background' term). The ensembles are generated by a volcanic ash transport model with the tracer released form different layers. Experiment shows such straightforward method does not always guarantee the identification of injection height with a short assimilation time window, and additional information of injection height is needed to correct the solution. We propose two tricks to incorporate the information: 1. add extra terms containing the information to the cost function as restriction term; 2. generate a

  2. Dynamics and Evolution of SO2 Gas Condensation Around Prometheus-like Volcanic Plumes on Io as Seen by the Near Infrared Mapping Spectrometer

    Science.gov (United States)

    Doute, S.; Lopes-Gautier, R.; Smythe, W. D.; Kamp, L. W.; Carlson, R.

    2001-01-01

    Near Infrared Mapping Spectrometer data acquired during the I24, 25, and 27 Io's Fly-bys by Galileo are analyzed to map the SO2 frost abundance and granularity. This allows a better understanding of the dynamics and evolution of gas condensation around volcanic plumes. Additional information is contained in the original extended abstract.

  3. Remote and Onsite Direct Measurements of Emissions from Oil and Natural Gas Production

    Science.gov (United States)

    Environmentally responsible oil and gas production requires accurate knowledge of emissions from long-term production operations1, which can include methane, volatile organic compounds, and hazardous air pollutants. Well pad emissions vary based on the geologically-determined com...

  4. Total greenhouse gas emissions related to the Dutch crop production system

    NARCIS (Netherlands)

    Kramer, K.J.; Moll, H.C.; Nonhebel, S.

    1999-01-01

    This article discusses the greenhouse gas emissions (CO2, CH4, N2O) related to Dutch agricultural crop production. Emissions occur during agricultural processes (direct emissions) as well as in the life cycle of the required inputs (indirect emissions). An integrated approach assesses the total

  5. The Impact of Diffuse Ionized Gas on Emission-line Ratios and Gas Metallicity Measurements

    Science.gov (United States)

    Zhang, Kai; Yan, Renbin; MaNGA Team

    2016-01-01

    Diffuse Ionized Gas (DIG) is prevalent in star-forming galaxies. Using a sample of galaxies observed by MaNGA, we demonstrate how DIG in star-forming galaxies impact the measurements of emission line ratios, hence the gas-phase metallicity measurements and the interpretation of diagnostic diagrams. We demonstrate that emission line surface brightness (SB) is a reasonably good proxy to separate HII regions from regions dominated by diffuse ionized gas. For spatially-adjacent regions or regions at the same radius, many line ratios change systematically with emission line surface brightness, reflecting a gradual increase of dominance by DIG towards low SB. DIG could significantly bias the measurement of gas metallicity and metallicity gradient. Because DIG tend to have a higher temperature than HII regions, at fixed metallicity DIG displays lower [NII]/[OII] ratios. DIG also show lower [OIII]/[OII] ratios than HII regions, due to extended partially-ionized regions that enhance all low-ionization lines ([NII], [SII], [OII], [OI]). The contamination by DIG is responsible for a substantial portion of the scatter in metallicity measurements. At different surface brightness, line ratios and line ratio gradients can differ systematically. As DIG fraction could change with radius, it can affect the metallicity gradient measurements in systematic ways. The three commonly used strong-line metallicity indicators, R23, [NII]/[OII], O3N2, are all affected in different ways. To make robust metallicity gradient measurements, one has to properly isolate HII regions and correct for DIG contamination. In line ratio diagnostic diagrams, contamination by DIG moves HII regions towards composite or LINER-like regions.

  6. Gas Emissivity of a Modified Cellulose Mix at the Temperature of 900°C

    Directory of Open Access Journals (Sweden)

    Zawieja Z.

    2015-09-01

    Full Text Available This paper presents the findings of a study of gas emissivity and the volumetric gas flow rate from a patented modified cellulose mix used in production of disposable sand casting moulds. The modified cellulose mix with such additives as expanded perlite, expanded vermiculite and microspheres was used as the study material. The results for gas emissivity and the gas flow rate for the modified cellulose mix were compared with the gas emissivity of the commercial material used in gating systems in disposable sand casting moulds. The results have shown that the modified cellulose mix is characterized by a lower gas emissivity by as much as 50% and lower gas flow rate per unit mass during the process of thermal degradation at the temperature of 900°C, compared to the commercial mix. It was also noted that the amount of microspheres considerably affected the amount of gas produced.

  7. A spatially resolved fuel-based inventory of Utah and Colorado oil and natural gas emissions

    Science.gov (United States)

    Gorchov Negron, A.; McDonald, B. C.; De Gouw, J. A.; Frost, G. J.

    2015-12-01

    A fuel-based approach is presented for estimating emissions from US oil and natural gas production that utilizes state-level fuel surveys of oil and gas engine activity, well-level production data, and emission factors for oil and gas equipment. Emissions of carbon dioxide (CO2) and nitrogen oxides (NOx) are mapped on a 4 km x 4 km horizontal grid for 2013-14 in Utah and Colorado. Emission sources include combustion from exploration (e.g., drilling), production (e.g., heaters, dehydrators, and compressor engines), and natural gas processing plants, which comprise a large fraction of the local combustion activity in oil and gas basins. Fuel-based emission factors of NOx are from the U.S. Environmental Protection Agency, and applied to spatially-resolved maps of CO2 emissions. Preliminary NOx emissions from this study are estimated for the Uintah Basin, Utah, to be ~5300 metric tons of NO2-equivalent in 2013. Our result compares well with an observations-based top-down emissions estimate of NOx derived from a previous study, ~4200 metric tons of NO2-equivalent. By contrast, the 2011 National Emissions Inventory estimates oil and gas emissions of NOx to be ~3 times higher than our study in the Uintah Basin. We intend to expand our fuel-based approach to map combustion-related emissions in other U.S. oil and natural gas basins and compare with additional observational datasets.

  8. The tropospheric processing of acidic gases and hydrogen sulphide in volcanic gas plumes as inferred from field and model investigations

    Directory of Open Access Journals (Sweden)

    A. Aiuppa

    2007-01-01

    Full Text Available Improving the constraints on the atmospheric fate and depletion rates of acidic compounds persistently emitted by non-erupting (quiescent volcanoes is important for quantitatively predicting the environmental impact of volcanic gas plumes. Here, we present new experimental data coupled with modelling studies to investigate the chemical processing of acidic volcanogenic species during tropospheric dispersion. Diffusive tube samplers were deployed at Mount Etna, a very active open-conduit basaltic volcano in eastern Sicily, and Vulcano Island, a closed-conduit quiescent volcano in the Aeolian Islands (northern Sicily. Sulphur dioxide (SO2, hydrogen sulphide (H2S, hydrogen chloride (HCl and hydrogen fluoride (HF concentrations in the volcanic plumes (typically several minutes to a few hours old were repeatedly determined at distances from the summit vents ranging from 0.1 to ~10 km, and under different environmental conditions. At both volcanoes, acidic gas concentrations were found to decrease exponentially with distance from the summit vents (e.g., SO2 decreases from ~10 000 μg/m3at 0.1 km from Etna's vents down to ~7 μg/m3 at ~10 km distance, reflecting the atmospheric dilution of the plume within the acid gas-free background troposphere. Conversely, SO2/HCl, SO2/HF, and SO2/H2S ratios in the plume showed no systematic changes with plume aging, and fit source compositions within analytical error. Assuming that SO2 losses by reaction are small during short-range atmospheric transport within quiescent (ash-free volcanic plumes, our observations suggest that, for these short transport distances, atmospheric reactions for H2S and halogens are also negligible. The one-dimensional model MISTRA was used to simulate quantitatively the evolution of halogen and sulphur compounds in the plume of Mt. Etna. Model predictions support the hypothesis of minor HCl chemical processing during plume transport, at least in cloud-free conditions. Larger

  9. Pre-eruptive volatile and erupted gas phase characterization of the 2014 basalt of Bárðarbunga volcanic system, Iceland.

    Science.gov (United States)

    Haddadi, Baptiste; Moune, Séverine; Sigmarsson, Olgeir; Gauthier, Pierre-Jean; Gouhier, Mathieu

    2015-04-01

    The 2014 Holuhraun eruption on the Bárðarbunga Volcanic System is the largest fissure eruption in Iceland since the 1783 Laki eruption. The eruption started end of August 2014 and has been characterized by large emission of SO2 into the atmosphere. It provides a rare opportunity to study in details magmatic and degassing processes during a large-volume fissure eruption. In order to characterize the pre-eruptive magmatic composition and to assess the plume chemistry at the eruption site, lava and tephra were sampled together with the eruption plume. The basalt composition is olivine tholeiite with MgO close to 7 wt%. It is phenocryst-poor with plagioclase as the dominant mineral phase but olivine and clinopyroxene are also present together with sulphide globules composed principally of pyrite and chalcopyrite. The volatile (S, Cl and F) and major element concentrations were measured by the electron microprobe in melt inclusions (MIs) trapped in plagioclase and clinopyroxene and groundmass glass. The MIs composition ranges from fairly primitive basaltic compositions (MgO: 9.03 wt%) down to evolved qz-tholeiites (MgO: 5.57 wt%), with estimated pre-eruptive S concentrations of 1500 ppm. Tephra groundmass glass contains 400 ppm S, whereas Cl and F concentrations are respectively slightly lower and indistinguishable from those in the MIs. This implies limited exsolution of halogens but 75% of the initial sulphur content. Relatively to their total iron content, MIs are sulphur saturated, and their oxygen fugacity close to the FMQ buffer. The difference between the estimated initial volatile concentrations measured in the MIs and in the tephra groundmass (i.e. the so-called petrological method) yields 7.2 Mt SO2, limited HCl and no HF atmospheric mass loading from the Holuhraun 2014 eruption. The SO2/HCl molar ratio of the gas phase, calculated from the MIs, is 13 and 14, respectively, using average and estimated pre-eruptive S and Cl concentrations in the MIs. Filter

  10. Greenhouse gas emissions of realistic dietary choices in Denmark

    DEFF Research Database (Denmark)

    Werner, Louise Bruun; Flysjö, Anna; Tholstrup, Tine

    2014-01-01

    the nutritional value of alternative food choices. OBJECTIVE: The objective of this study was to elucidate the role of dairy products in overall nutrition and to clarify the effects of dietary choices on GHGE, and to combine nutritional value and GHGE data. METHODS: We created eight dietary scenarios......BACKGROUND: Dairy products are important in a healthy diet due to their high nutritional value; they are, however, associated with relatively large greenhouse gas emissions (GHGE) per kg product. When discussing the need to reduce the GHGE caused by the food system, it is crucial to consider...... with different quantity of dairy products using data from the Danish National Dietary Survey (1995-2006). Nutrient composition and GHGE data for 71 highly consumed foods were used to estimate GHGE and nutritional status for each dietary scenario. An index was used to estimate nutrient density in relation...

  11. Current perspectives on energy and mass fluxes in volcanic arcs

    Science.gov (United States)

    Leeman, William; Davidson, Jon; Fischer, Tobias; Grunder, Anita; Reagan, Mark; Streck, Martin

    Volcanoes of the Pacific Ring of Fire and other convergent margins worldwide are familiar manifestations of nature's energy, account for about 25% of global volcanic outputs, dominate volcanic gas emissions to the atmosphere, and pose significant physical threats to a large human population. Yet the processes behind this prolific activity remain poorly understood.An international “State of the Arc” (SOTA) conference was held in August on the slopes of Mt. Hood, Oregon, to address current views on the energy and mass fluxes in volcanic arcs. This meeting brought together some 90 leading experts and students of subduction zones and their related magmatism.

  12. The Role of Volcanic Sour Gas on the Alteration of Martian Basalt: Insights from Geochemical Modeling

    Science.gov (United States)

    Berger, G.; Treguier, E.; D'Uston, C.; Pinet, P.; Toplis, M. J.

    2008-03-01

    We assess the chemical constraints of the alteration of basaltic material by a cold aqueous phase under atmospheric sour gas containing SO3. Secondary chemistry and mineralogy are calculated by a geochemical simulator and compared to MER data.

  13. How phosphorus limitation can control climatic gas emission

    Science.gov (United States)

    Gypens, Nathalie; Borges, Alberto V.; Speeckaert, Gaelle; Ghyoot, Caroline

    2015-04-01

    Anthropogenic activities severely increased river nutrient [nitrogen (N) and phosphorus (P)] loads to European coastal areas. However, specific nutrient reduction policies implemented since the late 1990's have considerably reduced P loads, while N is maintained. In the Southern North Sea, the resulting N: P: Si imbalance (compared to phytoplankton requirements) stimulated the growth of Phaeocystis colonies modifying the functioning of the ecosystem and, therefore, the carbon cycle but also the biogenic sulphur cycle, Phaeocystis being a significant producer of DMSP (dimethylsulphide propionate), the precursor of dimethylsulfide (DMS). In this application, the mechanistic MIRO-BIOGAS model is used to investigate the effects of changing N and P loads on ecosystem structure and their impact on DMS and CO2 emissions. In particular, competition for P between phytoplankton groups (diatoms vs Phaeocystis colonies) but also between phytoplankton and bacteria is explored. The ability of autotroph and heterotroph organism to use dissolved organic phosphorus (DOP) as P nutrient source is also explored and its effect on climatic gas emission estimated. Simulations were done from 1950 to 2010 and different nutrient limiting conditions are analyzed.

  14. Estimating methane gas generation from Devil's swamp landfill using greenhouse gas emission models

    Science.gov (United States)

    Adeyemi, Ayodeji Thompson

    Greenhouse gas (GHG) has been a key issue in the study, design, and management of landfills. Landfill gas (LFG) is considered either as a significant source of renewable energy (if extracted and processed accordingly) or significant source of pollution and risk (if not mitigated or processed). A municipal solid waste (MSW) landfill emits a significant amount of methane, a potent GHG. Thus, quantification and mitigation of GHG emissions is an important area of study in engineering and other sciences related to landfill technology and management. The present study will focus on estimating methane generation from Devils swamp landfill (DSLF), a closed landfill in Baton Rouge, LA. The landfill operated for 53 years (1940-1993) and contains both industrial and municipal waste products. Since the Clean Air Act of 1963, landfills are now classified as New Source Performance Standard (NSPS) waste (i.e., waste that will decompose to generate LFG). Currently, the DSLF is being used as source of renewable energy through the "Waste to Energy" program. For this study, to estimate the methane potential in the DSLF, it is important to determine the characteristics and classification of the landfill's wastes. The study uses and compares different GHG modeling tools---LandGEM, a multiphase model, and a simple first-order model---to estimate methane gas emission and compare results with the actual emissions from the DSLF. The sensitivity of the methane generation rate was analyzed by the methane generation models to assess the effects of variables such as initial conditions, specific growth rate, and reaction rate constants. The study concludes that methane (L0) and initial organic concentration in waste (k) are the most important parameters when estimating methane generation using the models.

  15. Spectrum analysis of national greenhouse gas emission: a case study of Germany

    Energy Technology Data Exchange (ETDEWEB)

    Su, Meirong [Dongguan University of Technology, School of Chemistry and Environmental Engineering, Dongguan, Guangdong Province (China); Beijing Normal University, State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Beijing (China); Technical University of Munich, Strategic Landscape Planning and Management, Freising (Germany); Pauleit, Stephan; Xu, Chao [Technical University of Munich, Strategic Landscape Planning and Management, Freising (Germany)

    2016-10-15

    It is essential to abstract the key information from accounting results of greenhouse gas (GHG) emissions because it can provide a highly generalized and clear picture of GHG emissions, which is especially helpful for the public and policy makers. To clearly display the composition of GHG emissions, the concept of spectrum analysis is introduced and defined in this paper. Next, a multilayer analysis framework for national GHG emissions was proposed, which is represented by a pyramid of three layers: total emissions (first layer), emissions decomposed by gas type or sector (second layer), and emissions decomposed by both gas type and sector (third layer). Based on the analysis results from the first to third layers, the main compositional information of national GHG emissions was gradually summarized and analyzed until a spectrum of GHG emissions was acquired. The spectrum of GHG emissions displays the compositional structure of national GHG emissions in the different layers, which is helpful in identifying priorities for emissions reduction. A case study of Germany's GHG emissions during 1990-2012 was conducted, which indicated that CO{sub 2} and the energy sector were the biggest contributors to the total GHG emissions. Some suggestions for reducing GHG emissions are offered based on the obtained results. And the potential development of spectrum analysis for GHG emissions is also expected from aspects of both research and technology. (orig.)

  16. The disposal of flue gas desulphurisation waste: sulphur gas emissions and their control.

    Science.gov (United States)

    Raiswell, R; Bottrell, S H

    1991-06-01

    Flue gas desulphurisation (FGD) equipment to be fitted to UK coal-fired power stations will produce more than 0.8 Mtonnes of calcium sulphate, as gypsum. Most gypsum should be of commercial quality, but any low grade material disposed as waste has the potential to generate a range of sulphur gases, including H2S, COS, CS2, DMS and DMDS. Literature data from the USA indicates that well-oxidised waste with a high proportion of calcium sulphate (the main UK product of FGD) has relatively low emissions of sulphur gases, which are comparable to background levels from inland soils. However, sulphur gas fluxes are greatly enhanced where reducing conditions become established within the waste, hence disposal strategies should be formulated to prevent the sub-surface consumption of oxygen.

  17. Nitrogen enriched combustion of a natural gas internal combustion engine to reduce NO.sub.x emissions

    Science.gov (United States)

    Biruduganti, Munidhar S.; Gupta, Sreenath Borra; Sekar, R. Raj; McConnell, Steven S.

    2008-11-25

    A method and system for reducing nitrous oxide emissions from an internal combustion engine. An input gas stream of natural gas includes a nitrogen gas enrichment which reduces nitrous oxide emissions. In addition ignition timing for gas combustion is advanced to improve FCE while maintaining lower nitrous oxide emissions.

  18. Greenhouse Gas Emission from In-situ Denitrifying Bioreactors

    Science.gov (United States)

    Pluer, W.; Walter, M. T.; Geohring, L.

    2013-12-01

    Despite decades of concerted effort to mitigate nonpoint source nitrate (NO3-) pollution from agricultural lands, these efforts have not been sufficient to arrest eutrophication, which continues to be a serious and chronic problem. Two primary processes for removing excess NO3- from water are biological assimilation and denitrification. Denitrifying bacteria use NO3- as the electron acceptor for respiration in the absence of oxygen. Denitrification results in reduced forms of nitrogen, often dinitrogen gas (N2) but also nitrous oxide (N2O), an aggressive greenhouse gas (GHG). A promising solution to NO3- pollution is to intercept agricultural discharges with denitrifying bioreactors (DNBRs), though research has been limited to NO3- level reduction and omitted process mechanisms. DNBRs work by providing an anaerobic environment with plenty of organic matter (commonly woodchips) for denitrifying bacteria to flourish. While, initial results from bioreactor studies show that they can cost-effectively remove NO3-, GHG emission could be an unintended consequence. The study's goal is to determine how bioreactor design promotes microbial denitrification while limiting N2O production. It specifically focuses on expanding the body of knowledge concerning DNBRs in the areas of design implications and internal processes by measuring intermediate compounds and not solely NO3-. Nutrient samples are collected at inflow and outflow structures and tested for NO3- and nitrite (NO2-). Dissolved and headspace gas samples are collected and tested for N2O. Additional gas samples will be analyzed for naturally-occurring isotopic N2 to support proposed pathways. Designs will be analyzed both through the N2O/N2 production ratio and NO2- production caused by various residence times and inflow NO3- concentrations. High GHG ratios and NO2- production suggest non-ideal conditions or flow patterns for complete denitrification. NO3- reduction is used for comparison with previous studies. Few

  19. Greenhouse Gas Emissions in the Netherlands: summary Report 1990-1997 (IPCC Tables 7A)

    NARCIS (Netherlands)

    Olivier JGJ; Spakman J; Berg JC van den; LAE

    1999-01-01

    This report documents the Netherlands' annual greenhouse gas emission inventory submitted for 1998 according to the European Union's Greenhouse Gas Monitoring Mechanism and the United Nation's Framework Convention on Climate Change (FCCC). Emissions of CO2 and N2O increased from 1990 to 1997 (with a

  20. Implications of greenhouse gas emission mitigation scenarios for the main Asian regions

    NARCIS (Netherlands)

    van Ruijven, B.J.; van Vuuren, D.P.; van Vliet, J.; Mendoza Beltran, A.; Deetman, S.; den Elzen, M.G.J.

    2012-01-01

    In order to limit global mean temperature increase, long-term greenhouse gas emissions need to be reduced. This paper discusses the implications of greenhouse gas emission reductions for major Asian regions (China, India, Indonesia, South-East Asia, Japan and Korea) based on results from the IMAGE m

  1. Separate effects of flooding and anaerobiosis on soil greenhouse gas emissions and redox sensitive biogeochemistry

    Science.gov (United States)

    Gavin McNicol; Whendee L. Silver

    2014-01-01

    Soils are large sources of atmospheric greenhouse gases, and both the magnitude and composition of soil gas emissions are strongly controlled by redox conditions. Though the effect of redox dynamics on greenhouse gas emissions has been well studied in flooded soils, less research has focused on redox dynamics without total soil inundation. For the latter, all that is...

  2. Simulated Radiative Transfer DOAS - A new method for improving volcanic SO2 emissions retrievals from ground-based UV-spectroscopic measurements of scattered solar radiation

    Science.gov (United States)

    Kern, C.; Deutschmann, T.; Vogel, L.; Bobrowski, N.; Hoermann, C.; Werner, C. A.; Sutton, A. J.; Elias, T.

    2011-12-01

    Passive Differential Optical Absorption Spectroscopy (DOAS) has become a standard tool for measuring SO2 at volcanoes. More recently, ultra-violet (UV) cameras have also been applied to obtain 2D images of SO2-bearing plumes. Both techniques can be used to derive SO2 emission rates by measuring SO2 column densities, integrating these along the plume cross-section, and multiplying by the wind speed. Recent measurements and model studies have revealed that the dominating source of uncertainty in these techniques often originates from an inaccurate assessment of radiative transfer through the volcanic plume. The typical assumption that all detected radiation is scattered behind the volcanic plume and takes a straight path from there to the instrument is often incorrect. We recently showed that the straight path assumption can lead to column density errors of 50% or more in cases where plumes with high SO2 and aerosol concentrations are measured from several kilometers distance, or where the background atmosphere contains a large amount of scattering aerosols. Both under- and overestimation are possible depending on the atmospheric conditions and geometry during spectral acquisition. Simulated Radiative Transfer (SRT) DOAS is a new evaluation scheme that combines radiative transfer modeling with spectral analysis of passive DOAS measurements in the UV region to derive more accurate SO2 column densities than conventional DOAS retrievals, which in turn leads to considerably more accurate emission rates. A three-dimensional backward Monte Carlo radiative transfer model is used to simulate realistic light paths in and around the volcanic plume containing variable amounts of SO2 and aerosols. An inversion algorithm is then applied to derive the true SO2 column density. For fast processing of large datasets, a linearized algorithm based on lookup tables was developed and tested on a number of example datasets. In some cases, the information content of the spectral data is

  3. The Measurement of Landfill Gas Emissions with the Orbiting Carbon Observatory and CarbonSAT Satellites

    Science.gov (United States)

    Vigil, S. A.; Bovensmann, H.

    2010-12-01

    Landfill gas is a significant contributor to anthropogenic emissions of CH4 and CO2. The U.S. Environmental Protection Agency has estimated the total U.S. 2007 emissions of the CH4 component of landfill gas at 132.9 Tg CO2 Equivalent. This compares to total CH4 emission from all US sources in 2007 at 585.3 Tg CO2 Equivalent. Worldwide CH4 emissions from landfill gas have been estimated at 668 Tg CO2 Equivalent. Satellite remote sensing can also be used to characterize landfill gas emissions. The NASA Orbiting Carbon Observatory (OCO-2) and the proposed CarbonSAT (University of Bremen) satellites are particularly suited for this purpose. The Orbiting Carbon Observatory (OCO) was designed to provided high spatial resolution ( developed countries. In general, landfills in the developed countries have landfill gas control system ground based landfill gas monitoring systems. These ground-based measurements can be used to calibrate OCO-2 and CarbonSAT landfill gas measurements. OCO-2 and CarbonSAT can be used to measure landfill emissions from the large landfills and open dumps of the emerging megacities in the developing world where accurate ground measurements are not available. For example Mexico City generates 26,000 MT of municipal solid waste that is disposed of in two uncontrolled landfills. Similar conditions exist in Asia, Latin America, and Africa. Satellite based measurements of these landfill gas emissions could help prioritize greenhouse gas remediation projects for these countries.

  4. Crustal deformation and gas emission from the Krýsuvík high temperature geothermal system, Iceland

    Science.gov (United States)

    Rakel Gudjonsdottir, Sylvia; Ilyinskaya, Evgenia; Hreinsdottir, Sigrun; Michakczewska, Karolina; Bergsson, Baldur; Auippa, Alessandro; Agla Oladottir, Audur; Rut Hjartardottir, Asta

    2016-04-01

    The Krýsuvík volcanic system is located at the oblique spreading Reykjanes Peninsula, Iceland. Since early 2009 the region has been undergoing episodes of localized ground uplift and subsidence. From March 2011 to the end of 2012 the region inflated by over 7 cm, triggering upper crustal earthquakes at the plate boundary. From 2012 to present the region has been subsiding at a relatively steady rate, reaching the pre inflation state by the end of 2015. GPS measurements indicate that the deflation source is located at 3 km depth coinciding with a previously mapped low resistivity zone from MT measurements suggesting the presence of water, magma or conductive minerals. In April 2013, near-real time monitoring of gas emissions started in Krýsuvík using a MultiGAS sensor system to collect data gas composition. Gas emissions are correlated with crustal deformation and seismicity within the Krýsuvík geothermal system. The dataset comprises near-continuous gas composition time series (MultiGAS); quantification of diffuse CO2 gas flux; direct samples of dry gas; seismic records; and GPS dataset. The gas emissions from the Krýsuvík system are H2O dominated with CO2 as the most abundant dry gas species, followed by lesser amounts of H2S. The subsurface equilibrium temperature is calculated as 278°C. This is consistent with previous observations made through sporadical sampling campaigns (e.g. Arnórsson, 1987). In addition, the semi-continuous MultiGAS dataset reveals higher variations of gas composition than previously reported by spot sampling. The diffuse CO2 soil flux is found to be variable between the three degassing areas in Krýsuvík ranging from 10.9-70.9 T/day with the highest flux in Hveradalir where the MultiGAS station is located. The total flux was calculated as 101.4 T/day. Correlation of the MultiGAS data with the geophysical data shows that peaks of H2O-rich emissions follow events of crustal movements. Coinciding with the H2O-rich peaks, SO2 is

  5. A Chemical Detector for Gas Chromatography Using Pulsed Discharge Emission Spectroscopy on a Microchip

    Science.gov (United States)

    Luo, X.; Zhu, W.; Mitra, B.; Liu, J.; Liu, T.; Fan, X.; Gianchandani, Y.

    2011-12-01

    There is increasing interest in miniaturized systems for chemical analysis in harsh environments. Chemical detection by emission spectroscopy of on-chip microdischarges [1-3] can be performed at >200°C [4], suggesting utility inspace exploration, volcanic monitoring, and oil well monitoring. This abstract describes the first use of pulsed microdischarge spectroscopy for gas chromatography (GC).This effort supports NASA interests in monitoring closed-loop life support systems for spacecraft. The microdischarge occurs on a 1cm2 glass chip (Fig. 1a), with thin-film Ni electrodes separated by 160μm. A glass lid with a grooved gas-flow channel, and inlet/outlet capillary tubes are epoxy-sealed to the chip. Located downstream of the 1.7m-long, RTX-1-coated, GC separation column, the microdischarge chip is read by a spectrometer. In a typical experiment (Fig. 1b), a mixture of acetone 3.6μg, 1-hexanol 2.8μg and nitrobenzene 3.0μg, is injected, with He carrier gas at 1.56sccm, through the GC. Acetone elutes quickly while nitrobenzene is slower. Microdischarges are triggered at 0.5Hz for 6 min., and 0.04Hz thereafter. Each microdischarge consumes ≈8mJ; the average power is ≈1.14mW. The spectrum (Fig. 1b, inset) shows that the 388nm peak, representing CN/CH fragments [5], is enhanced by carbon compounds. Its strength relative to the 588nm peak of He provides a chromatogram. Fig. 1b also shows a benchmark result from a commercial flame ionization detector (FID). The differences in elution time are attributed to differences in the gas flow paths for the two detectors [1]. REFERENCES [1] Eijkel et al, Anal. Chem, 2000 [2] Mitra et al, IEEE Trans Plasma Sci, 2008 [3] Mitra et al, IEEE Sensors, 2008 [4] Wright et al, APL, 2009 [5] Pearse et al, The Identification of Molecular Spectra, 1963

  6. Experimental generation of volcanic lightning

    Science.gov (United States)

    Cimarelli, Corrado; Alatorre-Ibargüengoitia, Miguel; Kueppers, Ulrich; Scheu, Bettina; Dingwell, Donald B.

    2014-05-01

    Ash-rich volcanic plumes that are responsible for injecting large quantities of aerosols into the atmosphere are often associated with intense electrical activity. Direct measurement of the electric potential at the crater, where the electric activity in the volcanic plume is first observed, is severely impeded, limiting progress in its investigation. We have achieved volcanic lightning in the laboratory during rapid decompression experiments of gas-particle mixtures under controlled conditions. Upon decompression (from ~100 bar argon pressure to atmospheric pressure), loose particles are vertically accelerated and ejected through a nozzle of 2.8 cm diameter into a large tank filled with air at atmospheric conditions. Because of their impulsive character, our experiments most closely represent the conditions encountered in the gas-thrust region of the plume, when ash is first ejected from the crater. We used sieved natural ash with different grain sizes from Popocatépetl (Mexico), Eyjafjallajökull (Iceland), and Soufrière Hills (Montserrat) volcanoes, as well as micrometric glass beads to constrain the influence of material properties on lightning. We monitored the dynamics of the particle-laden jets with a high-speed camera and the pressure and electric potential at the nozzle using a pressure transducer and two copper ring antennas connected to a high-impedance data acquisition system, respectively. We find that lightning is controlled by the dynamics of the particle-laden jet and by the abundance of fine particles. Two main conditions are required to generate lightning: 1) self-electrification of the particles and 2) clustering of the particles driven by the jet fluid dynamics. The relative movement of clusters of charged particles within the plume generates the gradient in electrical potential, which is necessary for lightning. In this manner it is the gas-particle dynamics together with the evolving particle-density distribution within different regions of

  7. Characteristics of Gas Emission at Super-Length Fully-Mechanized Top Coal Caving Face

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    Characteristics of gas emission at the K8206 working face in the Third mine of the Yangquan Coal Group were investigated.The effects of strata movement, advancing velocity of working face, production capacity of working face and gas extraction capability of strike high-level entry on gas emission at K8206 working face were analyzed.A regression equation, reflecting the relationship between relative gas emission rate and the production capacity of working faces, was established.Another regression equation showing the relationship between the gas emission rate from adjacent layers when the working face was advancing for one metre and advancing velocity was derived.It can be concluded that, 1) the amount of gas emitted at the K8206 working face is far greater than that of ordinary top coal caving faces with a dip length of 180-190 m; 2) the dynamic process of gas emission from adjacent layers during the initial mining stage is controlled by the movement of key strata; 3) the amount of gas emitted that needs to be forced out by air is greatly affected by the capability of gas extraction; 4) when the advancing velocity is between 3.5-5.5 m/d or when the output is up to 8-12 kt/d, the gas emission from adjacent layers is almost constant.

  8. Prediction of Gas Emission Based on Information Fusion and Chaotic Time Series

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    In order to make more exact predictions of gas emissions, information fusion and chaos time series are combined to predict the amount of gas emission in pits. First, a multi-sensor information fusion frame is established. The frame includes a data level, a character level and a decision level. Functions at every level are interpreted in detail in this paper. Then, the process of information fusion for gas emission is introduced. On the basis of those data processed at the data and character levels, the chaos time series and neural network are combined to predict the amount of gas emission at the decision level. The weights of the neural network are gained by training not by manual setting, in order to avoid subjectivity introduced by human intervention. Finally, the experimental results were analyzed in Matlab 6.0 and prove that the method is more accurate in the prediction of the amount of gas emission than the traditional method.

  9. Biomass energy: Sustainable solution for greenhouse gas emission

    Science.gov (United States)

    Sadrul Islam, A. K. M.; Ahiduzzaman, M.

    2012-06-01

    sustainable carbon sink will be developed. Clean energy production from biomass (such as ethanol, biodiesel, producer gas, bio-methane) could be viable option to reduce fossil fuel consumption. Electricity generation from biomass is increasing throughout the world. Co-firing of biomass with coal and biomass combustion in power plant and CHP would be a viable option for clean energy development. Biomass can produce less emission in the range of 14% to 90% compared to emission from fossil for electricity generation. Therefore, biomass could play a vital role for generation of clean energy by reducing fossil energy to reduce greenhouse gas emissions. The main barriers to expansion of power generation from biomass are cost, low conversion efficiency and availability of feedstock. Internationalization of external cost in power generation and effective policies to improve energy security and carbon dioxide reduction is important to boost up the bio-power. In the long run, bio-power will depend on technological development and on competition for feedstock with food production and arable land use.

  10. Dynamic distribution of gas pressure and emission around a driving roadway

    Energy Technology Data Exchange (ETDEWEB)

    Gao Jian-liang; Hou San-zhong [Henan Polytechnic University, Jiaozuo (China). School of Safety Science and Engineering

    2007-11-15

    The finite difference method was applied to simulate the dynamic variation of gas pressure in coal seams around a developing roadway and the gas emission rate on the airway surface. The gas pressure distribution advances with the advancement of the working face. The rate of emission of gas from the roadway surface decreases with the elapse of exposure time of the roadway surface. When the new working face is first exposed the emission of methane is highest and it then decreases sharply. 11 refs., 7 figs., 1 tab.

  11. Assessing Emissions of Volatile Organic Componds from Landfills Gas

    Directory of Open Access Journals (Sweden)

    Fahime Khademi

    2016-01-01

    Full Text Available Background: Biogas is obtained by anaerobic decomposition of organic wastes buried materials used to produce electricity, heat and biofuels. Biogas is at the second place for power generation after hydropower and in 2000 about 6% of the world power generation was allocated to biogas. Biogas is composed of 40–45 vol% CO2, 55–65 vol% CH4, and about 1% non-methaneVOCs, and non-methane volatile organic compounds. Emission rates are used to evaluate the compliance with landfill gas emission regulations by the United States Environmental Protection Agency (USEPA. BTEX comounds affect the air quality and may be harmful to human health. Benzene, toluene, ethylbenzene and xylene isomers that are generally called BTEX compounds are the most abundant VOCs in biogas. Methods: Sampling of VOCs in biogas vents was operated passively or with Tedlar bags. 20 samples were collected from 40 wells of old and new biogas sites of Shiraz’ landfill. Immediately after sampling, the samples were transferred to the laboratory. Analysis of the samples was performed with GC-MS. Results: The results showed that in the collection of the old and new biogas sites, the highest concentration of VOCs was observed in toluene (0.85ppm followed by benzene (0.81ppm, ethylbenzene (0.13ppm and xylene (0.08ppm. Conclusion: The results of the study showed that in all samples, most available compounds in biogas vents were aromatic hydrocarbon compounds.These compounds’ constituents originate from household hazardous waste materials deposited in the landfill or from biological/chemical decomposition processes within the landfill.

  12. Compositions and greenhouse gas emission factors of flared and vented gas in the Western Canadian Sedimentary Basin.

    Science.gov (United States)

    Johnson, Matthew R; Coderre, Adam R

    2012-09-01

    A significant obstacle in evaluating mitigation strategies for flaring and venting in the upstream oil and gas industry is the lack of publicly available data on the chemical composition of the gas. This information is required to determine the economic value of the gas, infrastructure and processing requirements, and potential emissions or emissions credits, all of which have significant impact on the economics of such strategies. This paper describes a method for estimating the composition of solution gas being flared and vented at individual facilities, and presents results derived for Alberta, Canada, which sits at the heart of the Western Canadian Sedimentary Basin. Using large amounts of raw data obtained through the Alberta Energy Resources Conservation Board, a relational database was created and specialized queries were developed to link production stream data, raw gas samples, and geography to create production-linked gas composition profiles for approximately half of the currently active facilities. These were used to create composition maps for the entire region, to which the remaining facilities with unknown compositions were geographically linked. The derived data were used to compute a range of solution gas composition profiles and greenhouse gas emission factors, providing new insight into flaring and venting in the region and enabling informed analysis of future management and mitigation strategies. Accurate and transparent determination of environmental impacts of flaring and venting of gas associated with oil production, and potential benefits of mitigation, is severely hampered by the lack of publicly available gas composition data. In jurisdictions within the Western Canadian Sedimentary Basin, frameworks exist for regulating and trading carbon offset credits but current potential for mitigation is limited by a lack of standardized methods for calculating CO2 equivalent emissions. The composition and emission factor data derived in this paper

  13. Greenhouse Gas Emissions Reporting through Integrated Business Solutions

    Science.gov (United States)

    Smith, D.

    2010-12-01

    Given the risks posed by global climate change, it is important that society as a whole responds in order to reduce the emission of greenhouse gas (GHG) into the atmosphere. Whether you are an environmentalist, a small-to-medium business owner, or a corporate risk manager - the need to act is now in order to reduce future environmental damage. While this sounds overwhelming, it’s really quite simple. Carbon Management is the process of understanding where your commercial activities generate GHG emissions, so that you can reduce those emissions in a planned, financially responsible way. Specifically, governments have the capacity to lead in this area and reduce these costs throughout their cities. Village Green Global develops and manages demonstration projects for the government that act as exemplar models to assist in gathering verifiable GHG reporting within selected regions and cities. This model highlights opportunities for the capture of conservation and energy credit commodities for local financial markets to use in global trading. Information gathered will prepare government for the ongoing changing global requirements and mitigate risk of unnecessary market exposure and cost; allow government to take a measured, responsible approach to its environmental responsibilities; reduce operational costs, improving the government’s asset utilization and more effectively streamlining its operations; and establish the government as responsible and proactive due to its creative approach to environmental challenges. Village Green Global’s government partnership model aims to deliver new jobs and technologies in the emerging “green economy;” a linkage to education at both at College and University levels, then assisting industry and community needs; and the involvement of industry leaders ensures training is targeted to job creation and local capacity building opportunities, in turn creating new skills and career pathways for the displaced workforce from the

  14. Contingency planning for rapid reduction of greenhouse gas emissions

    Directory of Open Access Journals (Sweden)

    Larsson, Nils K.

    2010-03-01

    Full Text Available The current and predicted levels of greenhouse gas (GHG emissions are, according to the best international scientific estimates, leading the world towards climate change that will have serious consequences for all countries. The problem is aggravated by the tendency of people and institutions not to take action until catastrophic consequences emerge. The history of crises in other sectors show us that reactions are likely to focus on ad-hoc reactions or using plans that are readily available, with negative results. However, the alternative of developing public plans for drastic and rapid reductions is not likely to gain support because of their radical nature. The author therefore proposes that large organizations with direct or indirect control over substantial GHG emissions should prepare private contingency plans for very rapid reductions in emissions, so that more rational and less destructive plans will be available when the appropriate moment comes for last-minute action. Examples of the type of specific plans that may be appropriate are suggested.

    Según las estimaciones científicas internacionales más optimistas, los niveles actuales y previstos de emisiones de gases de efecto invernadero (GEI están llevando al mundo hacia un cambio climático que tendrá graves consecuencias para todos los países. El problema se ve agravado por la tendencia de personas e instituciones a no tomar medidas hasta que no se perciben las catastróficas consecuencias. El historial de crisis ocurridas en otros sectores nos demuestra que las reacciones probablemente se centren en medidas ad hoc o en emplear planes que ya existían, pero sin resultados. Sin embargo, es poco probable que la alternativa al desarrollo de planes públicos para las reducciones drásticas y rápidas consiga el apoyo necesario, debido precisamente a su radicalidad. El autor recomienda por tanto que las grandes organizaciones que tengan control directo o indirecto sobre un

  15. RE: Request for Correction, Technical Support Document, Greenhouse Gas Emissions Reporting from the Petroleum and Natural Gas Industry

    Science.gov (United States)

    The Industrial Energy Consumers of America (IECA) joins the U.S. Chamber of Commerce in its request for correction of information developed by the Environmental Protection Agency (EPA) in a background technical support document titled Greenhouse Gas Emissions Reporting from the Petroleum and Natural Gas Industry

  16. Greenhouse gas emissions from willow-based electricity: a scenario analysis for Portugal and The Netherlands

    NARCIS (Netherlands)

    Rebelo de Mira, R.; Kroeze, C.

    2006-01-01

    This study focuses on greenhouse gas emissions from power plants using willow as fuel compared to those using fossil fuels. More specifically, we quantify emissions of nitrous oxide (N2O) from soils on which willow is grown, and compare these to emissions of carbon dioxide (CO2) from fossil fuel-bas

  17. Development of a method for estimating emissions from oil and gas production sites utilizing remote observations

    Science.gov (United States)

    There is a lack of information on emissions of ozone precursors, hazardous air pollutants, and greenhouse gases from oil and gas production operations, and measurement of these emissions presents many challenges. Assessment is complicated by the fugitive nature ofthe emissions, v...

  18. Greenhouse gas emissions in Canada and Japan: sector-specific estimates and managerial and economic implications.

    Science.gov (United States)

    Hayami, Hitoshi; Nakamura, Masao

    2007-10-01

    Many firms generate large amounts of carbon dioxide and other greenhouse gases when they burn fossil fuels in their production processes. In addition, production of raw materials and other inputs the firms procure for their operations also generates greenhouse gases indirectly. These direct and indirect greenhouse gas emissions occur in many sectors of our economies. In this paper, we first present sector-specific estimates for such greenhouse gas emissions. We then show that estimates for such sector-specific greenhouse gas emissions are often required for various types of corporate as well as public policy analyses in both domestic and international contexts. Measuring greenhouse gas emissions resulting from firms' multi-stage production processes in a multi-sector context is relevant for policies related to the Kyoto protocol, an international agreement to limit global greenhouse gas emissions. For example, since the protocol allows firms to engage in trading and offsetting of their greenhouse gas emissions across national borders, provided that emissions are correctly measured, the firms can take advantage of such trading schemes by placing their energy-intensive production facilities globally and strategically. We present several case studies which illustrate the importance of this and other aspects of greenhouse gas emissions in firms' environmental management. We also argue that our modeling and estimation methods based on input-output analyses are suitable for the types of research goals we have in this paper. Our methods are applied to data for Canada and Japan in a variety of environmental management circumstances.

  19. A global gas flaring black carbon emission rate dataset from 1994 to 2012

    Science.gov (United States)

    Huang, Kan; Fu, Joshua S.

    2016-11-01

    Global flaring of associated petroleum gas is a potential emission source of particulate matters (PM) and could be notable in some specific regions that are in urgent need of mitigation. PM emitted from gas flaring is mainly in the form of black carbon (BC), which is a strong short-lived climate forcer. However, BC from gas flaring has been neglected in most global/regional emission inventories and is rarely considered in climate modeling. Here we present a global gas flaring BC emission rate dataset for the period 1994-2012 in a machine-readable format. We develop a region-dependent gas flaring BC emission factor database based on the chemical compositions of associated petroleum gas at various oil fields. Gas flaring BC emission rates are estimated using this emission factor database and flaring volumes retrieved from satellite imagery. Evaluation using a chemical transport model suggests that consideration of gas flaring emissions can improve model performance. This dataset will benefit and inform a broad range of research topics, e.g., carbon budget, air quality/climate modeling, and environmental/human exposure.

  20. Atmospheric emissions and air quality impacts from natural gas production and use.

    Science.gov (United States)

    Allen, David T

    2014-01-01

    The US Energy Information Administration projects that hydraulic fracturing of shale formations will become a dominant source of domestic natural gas supply over the next several decades, transforming the energy landscape in the United States. However, the environmental impacts associated with fracking for shale gas have made it controversial. This review examines emissions and impacts of air pollutants associated with shale gas production and use. Emissions and impacts of greenhouse gases, photochemically active air pollutants, and toxic air pollutants are described. In addition to the direct atmospheric impacts of expanded natural gas production, indirect effects are also described. Widespread availability of shale gas can drive down natural gas prices, which, in turn, can impact the use patterns for natural gas. Natural gas production and use in electricity generation are used as a case study for examining these indirect consequences of expanded natural gas availability.

  1. HI emission and absorption in nearby, gas-rich galaxies

    CERN Document Server

    Reeves, S N; Allison, J R; Koribalski, B S; Curran, S J; Pracy, M B

    2015-01-01

    We present the results of a targeted search for intervening HI absorption in six nearby, gas-rich galaxies using the Australia Telescope Compact Array (ATCA). The sightlines searched have impact parameters of 10-20 kpc. By targeting nearby galaxies we are also able to map their HI emission, allowing us to directly relate the absorption-line detection rate to the extended HI distribution. The continuum sightlines intersect the HI disk in four of the six galaxies, but no intervening absorption was detected. Of these four galaxies, we find that three of the non-detections are the result of the background source being too faint. In the fourth case we find that the ratio of the spin temperature to the covering factor ($T_{\\mathrm{S}}/f$) must be much higher than expected ($\\gtrsim$5700 K) in order to explain the non-detection. We discuss how the structure of the background continuum sources may have affected the detection rate of HI absorption in our sample, and the possible implications for future surveys. Future...

  2. Numerical analysis of gas emission rule from a goaf of tailing roadway

    Institute of Scientific and Technical Information of China (English)

    LI Zong-xiang; HUANG Zhi-an; ZHANG Ai-ran; SONG Jian-guo

    2008-01-01

    Targeting the problem of large amounts of gas emission from the goaf of the No.14201 working face in the Shaqu coal mine of Huajin Coking Coal Co. Ltd., we used a negative exponential function to describe the attenuation process of gas emission in goaf (the stable source) based on the principle of field flow. Equations of two-component flow (gas and air) and see- page-diffusion in a heterogeneous goaf flow field are solved by means of numerical simulation and fluid mechanics principles of air movement and gas distribution during gas emission from goaf. The results indicate that the air diversion volume has a negative, exponential relation with the volume of gas emitted from goaf to the working face and is clearly inversely related to gas concentration. We calculated the minimum amount of air diversion and distributed air volume in the tailing roadway required for safe production.

  3. Evaluation of Methods for the Determination of Black Carbon Emissions from an Aircraft Gas Turbine Engine

    Science.gov (United States)

    The emissions from aircraft gas turbine engines consist of nanometer size black carbon (BC) particles plus gas-phase sulfur and organic compounds which undergo gas-to-particle conversion downstream of the engine as the plume cools and dilutes. In this study, four BC measurement ...

  4. Determination of time- and height-resolved volcanic ash emissions and their use for quantitative ash dispersion modeling: the 2010 Eyjafjallajökull eruption

    Directory of Open Access Journals (Sweden)

    A. Stohl

    2011-05-01

    Full Text Available The April–May, 2010 volcanic eruptions of Eyjafjallajökull, Iceland caused significant economic and social disruption in Europe whilst state of the art measurements and ash dispersion forecasts were heavily criticized by the aviation industry. Here we demonstrate for the first time that large improvements can be made in quantitative predictions of the fate of volcanic ash emissions, by using an inversion scheme that couples a priori source information and the output of a Lagrangian dispersion model with satellite data to estimate the volcanic ash source strength as a function of altitude and time. From the inversion, we obtain a total fine ash emission of the eruption of 8.3 ± 4.2 Tg for particles in the size range of 2.8–28 μm diameter. We evaluate the results of our model results with a posteriori ash emissions using independent ground-based, airborne and space-borne measurements both in case studies and statistically. Subsequently, we estimate the area over Europe affected by volcanic ash above certain concentration thresholds relevant for the aviation industry. We find that during three episodes in April and May, volcanic ash concentrations at some altitude in the atmosphere exceeded the limits for the "Normal" flying zone in up to 14 % (6–16 %, 2 % (1–3 % and 7 % (4–11 %, respectively, of the European area. For a limit of 2 mg m−3 only two episodes with fractions of 1.5 % (0.2–2.8 % and 0.9 % (0.1–1.6 % occurred, while the current "No-Fly" zone criterion of 4 mg m−3 was rarely exceeded. Our results have important ramifications for determining air space closures and for real-time quantitative estimations of ash concentrations. Furthermore, the general nature of our method yields better constraints on the distribution and fate of volcanic ash in the Earth system.

  5. The importance of addressing methane emissions as part of a comprehensive greenhouse gas management strategy

    Energy Technology Data Exchange (ETDEWEB)

    Bylin, Carey [U.S. Environmental Protection Agency (EPA), Washington, DC (United States); Robinson, Donald; Cacho, Mariella; Russo, Ignacio; Stricklin, Eric [ICF International, Fairfax, VA (United States); Rortveit, Geir Johan [Statoil, Stavanger (Norway); Chakraborty, A.B. [Oil and Natural Gas Corporation Ltda. (ONGC), Dehradun (India); Pontiff, Mike [Newfield, The Woodlands, TX, (United States); Smith, Reid [British Petroleum (BP), London (United Kingdom)

    2012-07-01

    Given the climate forcing properties of greenhouse gases (GHGs) and the current state of the global economy, it is imperative to mitigate emissions of GHGs cost-effectively. Typically, CO{sub 2} is the main focus of most companies' and governments' GHG emissions reductions strategies. However, when considering near-term goals, it becomes clear that emissions reductions of other GHGs must be pursued. One such GHG is methane, the primary component of natural gas. Reducing GHG emissions and generating profits are not necessarily a mutually exclusive endeavor as illustrated by the United States Environmental Protection Agency's (EPA) Natural Gas STAR Program. The Program is a worldwide voluntary, flexible partnership of oil and gas companies which promotes cost-effective technologies and practices to reduce methane emissions from oil and natural gas operations. In an effort to meet environmental goals without sacrificing profitability, Natural Gas STAR partner companies have identified over 60 cost-effective best practices to reduce their methane emissions, which they report to the EPA. This paper discusses: 1) the importance of reducing methane emissions and its economic impact, 2) a comparison of methane emission reduction projects relative to other greenhouse gas reduction projects in the oil and gas industry, 3) the value of source-specific methane emissions inventories, and 4) methane emission reduction opportunities from hydraulically fractured gas well completions and centrifugal compressor wet seals. From the analyses and examples in this paper, it can be concluded that methane emission reduction projects can be readily identified, profitable, and effective in mitigating global climate change. (author)

  6. Unregulated greenhouse gas and ammonia emissions from current technology heavy-duty vehicles.

    Science.gov (United States)

    Thiruvengadam, Arvind; Besch, Marc; Carder, Daniel; Oshinuga, Adewale; Pasek, Randall; Hogo, Henry; Gautam, Mridul

    2016-11-01

    The study presents the measurement of carbonyl, BTEX (benzene, toluene, ethyl benzene, and xylene), ammonia, elemental/organic carbon (EC/OC), and greenhouse gas emissions from modern heavy-duty diesel and natural gas vehicles. Vehicles from different vocations that included goods movement, refuse trucks, and transit buses were tested on driving cycles representative of their duty cycle. The natural gas vehicle technologies included the stoichiometric engine platform equipped with a three-way catalyst and a diesel-like dual-fuel high-pressure direct-injection technology equipped with a diesel particulate filter (DPF) and a selective catalytic reduction (SCR). The diesel vehicles were equipped with a DPF and SCR. Results of the study show that the BTEX emissions were below detection limits for both diesel and natural gas vehicles, while carbonyl emissions were observed during cold start and low-temperature operations of the natural gas vehicles. Ammonia emissions of about 1 g/mile were observed from the stoichiometric natural gas vehicles equipped with TWC over all the driving cycles. The tailpipe GWP of the stoichiometric natural gas goods movement application was 7% lower than DPF and SCR equipped diesel. In the case of a refuse truck application the stoichiometric natural gas engine exhibited 22% lower GWP than a diesel vehicle. Tailpipe methane emissions contribute to less than 6% of the total GHG emissions. Modern heavy-duty diesel and natural gas engines are equipped with multiple after-treatment systems and complex control strategies aimed at meeting both the performance standards for the end user and meeting stringent U.S. Environmental Protection Agency (EPA) emissions regulation. Compared to older technology diesel and natural gas engines, modern engines and after-treatment technology have reduced unregulated emissions to levels close to detection limits. However, brief periods of inefficiencies related to low exhaust thermal energy have been shown to

  7. Methane emissions from process equipment at natural gas production sites in the United States: pneumatic controllers.

    Science.gov (United States)

    Allen, David T; Pacsi, Adam P; Sullivan, David W; Zavala-Araiza, Daniel; Harrison, Matthew; Keen, Kindal; Fraser, Matthew P; Daniel Hill, A; Sawyer, Robert F; Seinfeld, John H

    2015-01-06

    Emissions from 377 gas actuated (pneumatic) controllers were measured at natural gas production sites and a small number of oil production sites, throughout the United States. A small subset of the devices (19%), with whole gas emission rates in excess of 6 standard cubic feet per hour (scf/h), accounted for 95% of emissions. More than half of the controllers recorded emissions of 0.001 scf/h or less during 15 min of measurement. Pneumatic controllers in level control applications on separators and in compressor applications had higher emission rates than controllers in other types of applications. Regional differences in emissions were observed, with the lowest emissions measured in the Rocky Mountains and the highest emissions in the Gulf Coast. Average methane emissions per controller reported in this work are 17% higher than the average emissions per controller in the 2012 EPA greenhouse gas national emission inventory (2012 GHG NEI, released in 2014); the average of 2.7 controllers per well observed in this work is higher than the 1.0 controllers per well reported in the 2012 GHG NEI.

  8. Enhanced greenhouse gas emissions from the Arctic with experimental warming

    Science.gov (United States)

    Voigt, Carolina; Lamprecht, Richard E.; Marushchak, Maija E.; Lind, Saara E.; Novakovskiy, Alexander; Aurela, Mika; Martikainen, Pertti J.; Biasi, Christina

    2017-04-01

    Temperatures in the Arctic are projected to increase more rapidly than in lower latitudes. With temperature being a key factor for regulating biogeochemical processes in ecosystems, even a subtle temperature increase might promote the release of greenhouse gases (GHGs) to the atmosphere. Usually, carbon dioxide (CO2) and methane (CH4) are the GHGs dominating the climatic impact of tundra. However, bare, patterned ground features in the Arctic have recently been identified as hot spots for nitrous oxide (N2O). N2O is a potent greenhouse gas, which is almost 300 times more effective in its global warming potential than CO2; but studies on arctic N2O fluxes are rare. In this study we examined the impact of temperature increase on the seasonal GHG balance of all three important GHGs (CO2, CH4 and N2O) from three tundra surface types (vegetated peat soils, unvegetated peat soils, upland mineral soils) in the Russian Arctic (67˚ 03' N 62˚ 55' E), during the course of two growing seasons. We deployed open-top chambers (OTCs), inducing air and soil surface warming, thus mimicking predicted warming scenarios. We combined detailed CO2, CH4 and N2O flux studies with concentration measurements of these gases within the soil profile down to the active layer-permafrost interface, and complemented these GHG measurements with detailed soil nutrient (nitrate and ammonium) and dissolved organic carbon (DOC) measurements in the soil pore water profile. In our study, gentle air warming (˜1.0 ˚ C) increased the seasonal GHG release of all dominant surface types: the GHG budget of vegetated peat and mineral soils, which together cover more than 80 % of the land area in our study region, shifted from a sink to a source of -300 to 144 g CO2-eq m-2 and from -198 to 105 g CO2-eq m-2, respectively. While the positive warming response was governed by CO2, we provide here the first in situ evidence that warming increases arctic N2O emissions: Warming did not only enhance N2O emissions from

  9. Greenhouse gas emissions trading and project-based mechanisms. Proceedings - CATEP

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2004-01-01

    Greenhouse gas emissions trading and project-based mechanisms for greenhouse gas reduction are emerging market-based instruments for climate change policy. This book presents a selection of papers from an international workshop co-sponsored by the OECD and Concerted Action on Tradeable Emissions Permits (CATEP), to discuss key research and policy issues relating to the design and implementation of these instruments. The papers cover the experience of developing and transition countries with greenhouse gas emissions trading and project-based mechanisms. In addition, the papers examine the use of tradeable permits in policy mixes and harmonisation of emissions trading schemes, as well as transition issues relating to greenhouse gas emissions trading markets.

  10. Gas breakthrough and emission through unsaturated compacted clay in landfill final cover

    Energy Technology Data Exchange (ETDEWEB)

    Ng, C.W.W.; Chen, Z.K.; Coo, J.L. [Department of Civil and Environmental Engineering, Hong Kong University of Science and Technology, Clear Water Bay, Kowloon (Hong Kong); Chen, R., E-mail: chenrui1005@hotmail.com [Shenzhen Key Laboratory of Urban and Civil Engineering for Disaster Prevention and Mitigation, Harbin Institute of Technology Shenzhen Graduate School, Shenzhen 518055 (China); Zhou, C. [Department of Civil and Environmental Engineering, Hong Kong University of Science and Technology, Clear Water Bay, Kowloon (Hong Kong)

    2015-10-15

    Highlights: • Explore feasibility of unsaturated clay as a gas barrier in landfill cover. • Gas breakthrough pressure increases with clay thickness and degree of saturation. • Gas emission rate decreases with clay thickness and degree of saturation. • A 0.6 m-thick clay layer may be sufficient to meet gas emission rate limit. - Abstract: Determination of gas transport parameters in compacted clay plays a vital role for evaluating the effectiveness of soil barriers. The gas breakthrough pressure has been widely studied for saturated swelling clay buffer commonly used in high-level radioactive waste disposal facility where the generated gas pressure is very high (in the order of MPa). However, compacted clay in landfill cover is usually unsaturated and the generated landfill gas pressure is normally low (typically less than 10 kPa). Furthermore, effects of clay thickness and degree of saturation on gas breakthrough and emission rate in the context of unsaturated landfill cover has not been quantitatively investigated in previous studies. The feasibility of using unsaturated compacted clay as gas barrier in landfill covers is thus worthwhile to be explored over a wide range of landfill gas pressures under various degrees of saturation and clay thicknesses. In this study, to evaluate the effectiveness of unsaturated compacted clay to minimize gas emission, one-dimensional soil column tests were carried out on unsaturated compacted clay to determine gas breakthrough pressures at ultimate limit state (high pressure range) and gas emission rates at serviceability limit state (low pressure range). Various degrees of saturation and thicknesses of unsaturated clay sample were considered. Moreover, numerical simulations were carried out using a coupled gas–water flow finite element program (CODE-BRIGHT) to better understand the experimental results by extending the clay thickness and varying the degree of saturation to a broader range that is typical at different

  11. Volcanic Eruptions and Climate

    Science.gov (United States)

    LeGrande, Allegra N.; Anchukaitis, Kevin J.

    2015-01-01

    Volcanic eruptions represent some of the most climatically important and societally disruptive short-term events in human history. Large eruptions inject ash, dust, sulfurous gases (e.g. SO2, H2S), halogens (e.g. Hcl and Hbr), and water vapor into the Earth's atmosphere. Sulfurous emissions principally interact with the climate by converting into sulfate aerosols that reduce incoming solar radiation, warming the stratosphere and altering ozone creation, reducing global mean surface temperature, and suppressing the hydrological cycle. In this issue, we focus on the history, processes, and consequences of these large eruptions that inject enough material into the stratosphere to significantly affect the climate system. In terms of the changes wrought on the energy balance of the Earth System, these transient events can temporarily have a radiative forcing magnitude larger than the range of solar, greenhouse gas, and land use variability over the last millennium. In simulations as well as modern and paleoclimate observations, volcanic eruptions cause large inter-annual to decadal-scale changes in climate. Active debates persist concerning their role in longer-term (multi-decadal to centennial) modification of the Earth System, however.

  12. CFD Modeling of Syngas Combustion and Emissions for Marine Gas Turbine Applications

    Directory of Open Access Journals (Sweden)

    Ammar Nader R.

    2016-09-01

    Full Text Available Strong restrictions on emissions from marine power plants will probably be adopted in the near future. One of the measures which can be considered to reduce exhaust gases emissions is the use of alternative fuels. Synthesis gases are considered competitive renewable gaseous fuels which can be used in marine gas turbines for both propulsion and electric power generation on ships. The paper analyses combustion and emission characteristics of syngas fuel in marine gas turbines. Syngas fuel is burned in a gas turbine can combustor. The gas turbine can combustor with swirl is designed to burn the fuel efficiently and reduce the emissions. The analysis is performed numerically using the computational fluid dynamics code ANSYS FLUENT. Different operating conditions are considered within the numerical runs. The obtained numerical results are compared with experimental data and satisfactory agreement is obtained. The effect of syngas fuel composition and the swirl number values on temperature contours, and exhaust gas species concentrations are presented in this paper. The results show an increase of peak flame temperature for the syngas compared to natural gas fuel combustion at the same operating conditions while the NO emission becomes lower. In addition, lower CO2 emissions and increased CO emissions at the combustor exit are obtained for the syngas, compared to the natural gas fuel.

  13. Influence of the Gas Mixture Ratio on the Correlations Between the Excimer XeCl* Emission and the Sealed Gas Temperature in Dielectric Barrier Discharge Lamps

    Institute of Scientific and Technical Information of China (English)

    徐金洲; 梁荣庆; 任兆杏

    2002-01-01

    For dielectric barrier discharge lamps filled with various gas mixture ratios, the correlations between the excimer XeCl* emission and the sealed gas temperature have been founded, and a qualitative explication is presented. For gas mixture with chlorine larger than 3%, the emission intensity increases with the sealed gas temperature, while with chlorine about 2%, the emission intensity decreases with the increase in the gas temperature, and could be improved by cooling water. However, if chlorine is less than 1.5%, the discharge appears to be a mixture mode with filaments distributed in a diffused glow-like discharge, and the UV emission is independent on the gas temperature.

  14. Research on Forecast Technology of Mine Gas Emission Based on Fuzzy Data Mining(FDM)

    Institute of Scientific and Technical Information of China (English)

    XU Chang-kai; WANG Yao-cai; WANG Jun-wei

    2004-01-01

    The safe production of coalmine can be further improved by forecasting the quantity of gas emission based on the real-time data and historical data which the gas monitoring system has saved. By making use of the advantages of data warehouse and data mining technology for processing large quantity of redundancy data, the method and its application of forecasting mine gas emission quantity based on FDM were studied. The constructing fuzzy resembling relation and clustering analysis were proposed, which the potential relationship inside the gas emission data may be found. The mode finds model and forecast model were presented, and the detailed approach to realize this forecast was also proposed, which have been applied to forecast the gas emission quantity efficiently.

  15. Assessment of alternative disposal methods to reduce greenhouse gas emissions from municipal solid waste in India.

    Science.gov (United States)

    Yedla, Sudhakar; Sindhu, N T

    2016-06-01

    Open dumping, the most commonly practiced method of solid waste disposal in Indian cities, creates serious environment and economic challenges, and also contributes significantly to greenhouse gas emissions. The present article attempts to analyse and identify economically effective ways to reduce greenhouse gas emissions from municipal solid waste. The article looks at the selection of appropriate methods for the control of methane emissions. Multivariate functional models are presented, based on theoretical considerations as well as the field measurements to forecast the greenhouse gas mitigation potential for all the methodologies under consideration. Economic feasibility is tested by calculating the unit cost of waste disposal for the respective disposal process. The purpose-built landfill system proposed by Yedla and Parikh has shown promise in controlling greenhouse gas and saving land. However, these studies show that aerobic composting offers the optimal method, both in terms of controlling greenhouse gas emissions and reducing costs, mainly by requiring less land than other methods.

  16. Anthropogenic, biomass burning, and volcanic emissions of black carbon, organic carbon, and SO2 from 1980 to 2010 for hindcast model experiments

    Directory of Open Access Journals (Sweden)

    D. Streets

    2012-09-01

    Full Text Available Two historical emission inventories of black carbon (BC, primary organic carbon (OC, and SO2 emissions from land-based anthropogenic sources, ocean-going vessels, air traffic, biomass burning, and volcanoes are presented and discussed for the period 1980–2010. These gridded inventories are provided to the internationally coordinated AeroCom Phase II multi-model hindcast experiments. The horizontal resolution is 0.5°×0.5° and 1.0°×1.0°, while the temporal resolution varies from daily for volcanoes to monthly for biomass burning and aircraft emissions, and annual averages for land-based and ship emissions. One inventory is based on inter-annually varying activity rates of land-based anthropogenic emissions and shows strong variability within a decade, while the other one is derived from interpolation between decadal endpoints and thus exhibits linear trends within a decade. Both datasets capture the major trends of decreasing anthropogenic emissions over the USA and Western Europe since 1980, a sharp decrease around 1990 over Eastern Europe and the former USSR, and a steep increase after 2000 over East and South Asia. The inventory differences for the combined anthropogenic and biomass burning emissions in the year 2005 are 34% for BC, 46% for OC, and 13% for SO2. They vary strongly depending on species, year and region, from about 10% to 40% in most cases, but in some cases the inventories differ by 100% or more. Differences in emissions from wild-land fires are caused only by different choices of the emission factors for years after 1996 which vary by a factor of about 1 to 2 for OC depending on region, and by a combination of emission factors and the amount of dry mass burned for years up to 1996. Volcanic SO2 emissions, which are only provided in one inventory, include emissions from explosive, effusive, and quiescent degassing events for 1167 volcanoes.

  17. piscope - A Python based software package for the analysis of volcanic SO2 emissions using UV SO2 cameras

    Science.gov (United States)

    Gliss, Jonas; Stebel, Kerstin; Kylling, Arve; Solvejg Dinger, Anna; Sihler, Holger; Sudbø, Aasmund

    2017-04-01

    UV SO2 cameras have become a common method for monitoring SO2 emission rates from volcanoes. Scattered solar UV radiation is measured in two wavelength windows, typically around 310 nm and 330 nm (distinct / weak SO2 absorption) using interference filters. The data analysis comprises the retrieval of plume background intensities (to calculate plume optical densities), the camera calibration (to convert optical densities into SO2 column densities) and the retrieval of gas velocities within the plume as well as the retrieval of plume distances. SO2 emission rates are then typically retrieved along a projected plume cross section, for instance a straight line perpendicular to the plume propagation direction. Today, for most of the required analysis steps, several alternatives exist due to ongoing developments and improvements related to the measurement technique. We present piscope, a cross platform, open source software toolbox for the analysis of UV SO2 camera data. The code is written in the Python programming language and emerged from the idea of a common analysis platform incorporating a selection of the most prevalent methods found in literature. piscope includes several routines for plume background retrievals, routines for cell and DOAS based camera calibration including two individual methods to identify the DOAS field of view (shape and position) within the camera images. Gas velocities can be retrieved either based on an optical flow analysis or using signal cross correlation. A correction for signal dilution (due to atmospheric scattering) can be performed based on topographic features in the images. The latter requires distance retrievals to the topographic features used for the correction. These distances can be retrieved automatically on a pixel base using intersections of individual pixel viewing directions with the local topography. The main features of piscope are presented based on dataset recorded at Mt. Etna, Italy in September 2015.

  18. Role of natural gas in meeting an electric sector emissions reduction strategy and effects on greenhouse gas emissions

    Science.gov (United States)

    With advances in natural gas extraction technologies, there is an increase in availability of domestic natural gas, and natural gas is gaining a larger share of use as a fuel in electricity production. At the power plant, natural gas is a cleaner burning fuel than coal, but unce...

  19. Fuel prices, emission standards, and generation costs for coal vs natural gas power plants.

    Science.gov (United States)

    Pratson, Lincoln F; Haerer, Drew; Patiño-Echeverri, Dalia

    2013-05-07

    Low natural gas prices and stricter, federal emission regulations are promoting a shift away from coal power plants and toward natural gas plants as the lowest-cost means of generating electricity in the United States. By estimating the cost of electricity generation (COE) for 304 coal and 358 natural gas plants, we show that the economic viability of 9% of current coal capacity is challenged by low natural gas prices, while another 56% would be challenged by the stricter emission regulations. Under the current regulations, coal plants would again become the dominant least-cost generation option should the ratio of average natural gas to coal prices (NG2CP) rise to 1.8 (it was 1.42 in February 2012). If the more stringent emission standards are enforced, however, natural gas plants would remain cost competitive with a majority of coal plants for NG2CPs up to 4.3.

  20. VolcLab: A balloon-borne instrument package to measure ash, gas, electrical, and turbulence properties of volcanic plumes

    Science.gov (United States)

    Airey, Martin; Harrison, Giles; Nicoll, Keri; Williams, Paul; Marlton, Graeme

    2017-04-01

    Release of volcanic ash into the atmosphere poses a significant hazard to air traffic. Exposure to appreciable concentrations (≥4 mg m-3) of ash can result in engine shutdown, air data system loss, and airframe damage, with sustained lower concentrations potentially causing other long-term detrimental effects [1]. Disruption to flights also has a societal impact. For example, the closure of European airspace following the 2010 eruption of Eyjafjallajökull resulted in global airline industry losses of order £1100 million daily and disruption to 10 million passengers. Accurate and effective measurement of the mass of ash in a volcanic plume along with in situ characterisation of other plume properties such as charge, turbulence, and SO2 concentration can be used in combination with plume dispersion modelling, remote sensing, and more sophisticated flight ban thresholds to mitigate the impact of future events. VolcLab is a disposable instrument package that may be attached to a standard commercial radiosonde, for rapid emergency deployment on a weather balloon platform. The payload includes a newly developed gravimetric sensor using the oscillating microbalance principle to measure mass directly without assumptions about particles' optical properties. The package also includes an SO2 gas detector, an optical sensor to detect ash and cloud backscatter from an LED source [2], a charge sensor to characterise electrical properties of the plume [3], and an accelerometer to measure in-plume turbulence [4]. VolcLab uses the established PANDORA interface [5], to provide data exchange and power from the radiosonde. In addition to the VolcLab measurements, the radiosonde provides standard meteorological data of temperature, pressure, and relative humidity, and GPS location. There are several benefits of using this instrument suite in this design and of using this method of deployment. Firstly, this is an all-in-one device requiring minimal expertise on the part of the end

  1. Near-Zero Emissions Oxy-Combustion Flue Gas Purification

    Energy Technology Data Exchange (ETDEWEB)

    Minish Shah; Nich Degenstein; Monica Zanfir; Rahul Solunke; Ravi Kumar; Jennifer Bugayong; Ken Burgers

    2012-06-30

    The objectives of this project were to carry out an experimental program to enable development and design of near zero emissions (NZE) CO{sub 2} processing unit (CPU) for oxy-combustion plants burning high and low sulfur coals and to perform commercial viability assessment. The NZE CPU was proposed to produce high purity CO{sub 2} from the oxycombustion flue gas, to achieve > 95% CO{sub 2} capture rate and to achieve near zero atmospheric emissions of criteria pollutants. Two SOx/NOx removal technologies were proposed depending on the SOx levels in the flue gas. The activated carbon process was proposed for power plants burning low sulfur coal and the sulfuric acid process was proposed for power plants burning high sulfur coal. For plants burning high sulfur coal, the sulfuric acid process would convert SOx and NOx in to commercial grade sulfuric and nitric acid by-products, thus reducing operating costs associated with SOx/NOx removal. For plants burning low sulfur coal, investment in separate FGD and SCR equipment for producing high purity CO{sub 2} would not be needed. To achieve high CO{sub 2} capture rates, a hybrid process that combines cold box and VPSA (vacuum pressure swing adsorption) was proposed. In the proposed hybrid process, up to 90% of CO{sub 2} in the cold box vent stream would be recovered by CO{sub 2} VPSA and then it would be recycled and mixed with the flue gas stream upstream of the compressor. The overall recovery from the process will be > 95%. The activated carbon process was able to achieve simultaneous SOx and NOx removal in a single step. The removal efficiencies were >99.9% for SOx and >98% for NOx, thus exceeding the performance targets of >99% and >95%, respectively. The process was also found to be suitable for power plants burning both low and high sulfur coals. Sulfuric acid process did not meet the performance expectations. Although it could achieve high SOx (>99%) and NOx (>90%) removal efficiencies, it could not produce by

  2. Near-Zero Emissions Oxy-Combustion Flue Gas Purification

    Energy Technology Data Exchange (ETDEWEB)

    Minish Shah; Nich Degenstein; Monica Zanfir; Rahul Solunke; Ravi Kumar; Jennifer Bugayong; Ken Burgers

    2012-06-30

    The objectives of this project were to carry out an experimental program to enable development and design of near zero emissions (NZE) CO{sub 2} processing unit (CPU) for oxy-combustion plants burning high and low sulfur coals and to perform commercial viability assessment. The NZE CPU was proposed to produce high purity CO{sub 2} from the oxycombustion flue gas, to achieve > 95% CO{sub 2} capture rate and to achieve near zero atmospheric emissions of criteria pollutants. Two SOx/NOx removal technologies were proposed depending on the SOx levels in the flue gas. The activated carbon process was proposed for power plants burning low sulfur coal and the sulfuric acid process was proposed for power plants burning high sulfur coal. For plants burning high sulfur coal, the sulfuric acid process would convert SOx and NOx in to commercial grade sulfuric and nitric acid by-products, thus reducing operating costs associated with SOx/NOx removal. For plants burning low sulfur coal, investment in separate FGD and SCR equipment for producing high purity CO{sub 2} would not be needed. To achieve high CO{sub 2} capture rates, a hybrid process that combines cold box and VPSA (vacuum pressure swing adsorption) was proposed. In the proposed hybrid process, up to 90% of CO{sub 2} in the cold box vent stream would be recovered by CO{sub 2} VPSA and then it would be recycled and mixed with the flue gas stream upstream of the compressor. The overall recovery from the process will be > 95%. The activated carbon process was able to achieve simultaneous SOx and NOx removal in a single step. The removal efficiencies were >99.9% for SOx and >98% for NOx, thus exceeding the performance targets of >99% and >95%, respectively. The process was also found to be suitable for power plants burning both low and high sulfur coals. Sulfuric acid process did not meet the performance expectations. Although it could achieve high SOx (>99%) and NOx (>90%) removal efficiencies, it could not produce by

  3. Volatile organic compound emissions from unconventional natural gas production: Source signatures and air quality impacts

    Science.gov (United States)

    Swarthout, Robert F.

    Advances in horizontal drilling and hydraulic fracturing over the past two decades have allowed access to previously unrecoverable reservoirs of natural gas and led to an increase in natural gas production. Intensive unconventional natural gas extraction has led to concerns about impacts on air quality. Unconventional natural gas production has the potential to emit vast quantities of volatile organic compounds (VOCs) into the atmosphere. Many VOCs can be toxic, can produce ground-level ozone or secondary organic aerosols, and can impact climate. This dissertation presents the results of experiments designed to validate VOC measurement techniques, to quantify VOC emission rates from natural gas sources, to identify source signatures specific to natural gas emissions, and to quantify the impacts of these emissions on potential ozone formation and human health. Measurement campaigns were conducted in two natural gas production regions: the Denver-Julesburg Basin in northeast Colorado and the Marcellus Shale region surrounding Pittsburgh, Pennsylvania. An informal measurement intercomparison validated the canister sampling methodology used throughout this dissertation for the measurement of oxygenated VOCs. Mixing ratios of many VOCs measured during both campaigns were similar to or higher than those observed in polluted cities. Fluxes of natural gas-associated VOCs in Colorado ranged from 1.5-3 times industry estimates. Similar emission ratios relative to propane were observed for C2-C6 alkanes in both regions, and an isopentane:n-pentane ratio ≈1 was identified as a unique tracer for natural gas emissions. Source apportionment estimates indicated that natural gas emissions were responsible for the majority of C2-C8 alkanes observed in each region, but accounted for a small proportion of alkenes and aromatic compounds. Natural gas emissions in both regions accounted for approximately 20% of hydroxyl radical reactivity, which could hinder federal ozone standard

  4. Impact of alternative fuels on emissions characteristics of a gas turbine engine - part 1: gaseous and particulate matter emissions.

    Science.gov (United States)

    Lobo, Prem; Rye, Lucas; Williams, Paul I; Christie, Simon; Uryga-Bugajska, Ilona; Wilson, Christopher W; Hagen, Donald E; Whitefield, Philip D; Blakey, Simon; Coe, Hugh; Raper, David; Pourkashanian, Mohamed

    2012-10-01

    Growing concern over emissions from increased airport operations has resulted in a need to assess the impact of aviation related activities on local air quality in and around airports, and to develop strategies to mitigate these effects. One such strategy being investigated is the use of alternative fuels in aircraft engines and auxiliary power units (APUs) as a means to diversify fuel supplies and reduce emissions. This paper summarizes the results of a study to characterize the emissions of an APU, a small gas turbine engine, burning conventional Jet A-1, a fully synthetic jet fuel, and other alternative fuels with varying compositions. Gas phase emissions were measured at the engine exit plane while PM emissions were recorded at the exit plane as well as 10 m downstream of the engine. Five percent reduction in NO(x) emissions and 5-10% reduction in CO emissions were observed for the alternative fuels. Significant reductions in PM emissions at the engine exit plane were achieved with the alternative fuels. However, as the exhaust plume expanded and cooled, organic species were found to condense on the PM. This increase in organic PM elevated the PM mass but had little impact on PM number.

  5. Top-down Constraints on Emissions: Example for Oil and Gas Operations

    Science.gov (United States)

    Petron, G.; Sweeney, C.; Karion, A.; Brewer, A.; Hardesty, R.; Banta, R. M.; Frost, G. J.; Trainer, M.; Miller, B. R.; Conley, S. A.; Kofler, J.; Newberger, T.; Higgs, J. A.; Wolter, S.; Guenther, D.; Andrews, A. E.; Dlugokencky, E. J.; Lang, P. M.; Montzka, S. A.; Edwards, P. M.; Dube, W. P.; Brown, S. S.; Helmig, D.; Hueber, J.; Rella, C.; Jacobson, G. A.; Wolfe, D. E.; Bruhwiler, L.; Tans, P. P.; Schnell, R. C.

    2012-12-01

    In many countries, human-caused emissions of the two major long lived greenhouse gases, carbon dioxide and methane, are primarily linked to the use of fossil fuels (coal, oil and natural gas). Fugitive emissions of natural gas (mainly CH4) from the oil and gas exploration and production sector may also be an important contributor to natural gas life cycle/greenhouse gas footprint. Fuel use statistics have traditionally been used in combination with fuel and process specific emission factors to estimate CO2 emissions from fossil-fuel-based energy systems (power plants, motor vehicles…). Fugitive emissions of CH4, in contrast, are much harder to quantify. Fugitive emission levels may vary substantially from one oil and gas producing basin to another and may not scale with common activity data, such as production numbers. In the USA, recent efforts by the industry, States and the US Environmental Protection Agency have focused on developing new bottom-up inventory methodologies to assess methane and volatile organic compounds emissions from oil and gas producing basins. The underlying assumptions behind these inventories are multiple and result de facto in large uncertainties. Independent atmospheric-based estimates of emissions provide another valuable piece of information that can be used to evaluate inventories. Over the past year, the NOAA Earth System Research Laboratory has used its expertise in high quality GHG and wind measurements to evaluate regional emissions of methane from two oil and gas basins in the Rocky Mountain region. Results from these two campaigns will be discussed and compared with available inventories.

  6. Methane emissions from natural gas infrastructure and use in the urban region of Boston, Massachusetts.

    Science.gov (United States)

    McKain, Kathryn; Down, Adrian; Raciti, Steve M; Budney, John; Hutyra, Lucy R; Floerchinger, Cody; Herndon, Scott C; Nehrkorn, Thomas; Zahniser, Mark S; Jackson, Robert B; Phillips, Nathan; Wofsy, Steven C

    2015-02-17

    Methane emissions from natural gas delivery and end use must be quantified to evaluate the environmental impacts of natural gas and to develop and assess the efficacy of emission reduction strategies. We report natural gas emission rates for 1 y in the urban region of Boston, using a comprehensive atmospheric measurement and modeling framework. Continuous methane observations from four stations are combined with a high-resolution transport model to quantify the regional average emission flux, 18.5 ± 3.7 (95% confidence interval) g CH4 ⋅ m(-2) ⋅ y(-1). Simultaneous observations of atmospheric ethane, compared with the ethane-to-methane ratio in the pipeline gas delivered to the region, demonstrate that natural gas accounted for ∼ 60-100% of methane emissions, depending on season. Using government statistics and geospatial data on natural gas use, we find the average fractional loss rate to the atmosphere from all downstream components of the natural gas system, including transmission, distribution, and end use, was 2.7 ± 0.6% in the Boston urban region, with little seasonal variability. This fraction is notably higher than the 1.1% implied by the most closely comparable emission inventory.

  7. [Effects of superphosphate addition on NH3 and greenhouse gas emissions during vegetable waste composting].

    Science.gov (United States)

    Yang, Yan; Sun, Qin-ping; Li, Ni; Liu, Chun-sheng; Li, Ji-jin; Liu, Ben-sheng; Zou, Guo-yuan

    2015-01-01

    To study the effects of superphosphate (SP) on the NH, and greenhouse gas emissions, vegetable waste composting was performed for 27 days using 6 different treatments. In addition to the controls, five vegetable waste mixtures (0.77 m3 each) were treated with different amounts of the SP additive, namely, 5%, 10%, 15%, 20% and 25%. The ammonia volatilization loss and greenhouse gas emissions were measured during composting. Results indicated that the SP additive significantly decreased the ammonia volatilization and greenhouse gas emissions during vegetable waste composting. The additive reduced the total NH3 emission by 4.0% to 16.7%. The total greenhouse gas emissions (CO2-eq) of all treatments with SP additives were decreased by 10.2% to 20.8%, as compared with the controls. The NH3 emission during vegetable waste composting had the highest contribution to the greenhouse effect caused by the four different gases. The amount of NH3 (CO2-eq) from each treatment ranged from 59.90 kg . t-1 to 81.58 kg . t-1; NH3(CO2-eq) accounted for 69% to 77% of the total emissions from the four gases. Therefore, SP is a cost-effective phosphorus-based fertilizer that can be used as an additive during vegetable waste composting to reduce the NH3 and greenhouse gas emissions as well as to improve the value of compost as a fertilizer.

  8. Methane Emissions from Leak and Loss Audits of Natural Gas Compressor Stations and Storage Facilities.

    Science.gov (United States)

    Johnson, Derek R; Covington, April N; Clark, Nigel N

    2015-07-07

    As part of the Environmental Defense Fund's Barnett Coordinated Campaign, researchers completed leak and loss audits for methane emissions at three natural gas compressor stations and two natural gas storage facilities. Researchers employed microdilution high-volume sampling systems in conjunction with in situ methane analyzers, bag samples, and Fourier transform infrared analyzers for emissions rate quantification. All sites had a combined total methane emissions rate of 94.2 kg/h, yet only 12% of the emissions total resulted from leaks. Methane slip from exhausts represented 44% of the total emissions. Remaining methane emissions were attributed to losses from pneumatic actuators and controls, engine crankcases, compressor packing vents, wet seal vents, and slop tanks. Measured values were compared with those reported in literature. Exhaust methane emissions were lower than emissions factor estimates for engine exhausts, but when combined with crankcase emissions, measured values were 11.4% lower than predicted by AP-42 as applicable to emissions factors for four-stroke, lean-burn engines. Average measured wet seal emissions were 3.5 times higher than GRI values but 14 times lower than those reported by Allen et al. Reciprocating compressor packing vent emissions were 39 times higher than values reported by GRI, but about half of values reported by Allen et al. Though the data set was small, researchers have suggested a method to estimate site-wide emissions factors for those powered by four-stroke, lean-burn engines based on fuel consumption and site throughput.

  9. Life cycle greenhouse gas emissions from U.S. liquefied natural gas exports: implications for end uses.

    Science.gov (United States)

    Abrahams, Leslie S; Samaras, Constantine; Griffin, W Michael; Matthews, H Scott

    2015-03-03

    This study analyzes how incremental U.S. liquefied natural gas (LNG) exports affect global greenhouse gas (GHG) emissions. We find that exported U.S. LNG has mean precombustion emissions of 37 g CO2-equiv/MJ when regasified in Europe and Asia. Shipping emissions of LNG exported from U.S. ports to Asian and European markets account for only 3.5-5.5% of precombustion life cycle emissions, hence shipping distance is not a major driver of GHGs. A scenario-based analysis addressing how potential end uses (electricity and industrial heating) and displacement of existing fuels (coal and Russian natural gas) affect GHG emissions shows the mean emissions for electricity generation using U.S. exported LNG were 655 g CO2-equiv/kWh (with a 90% confidence interval of 562-770), an 11% increase over U.S. natural gas electricity generation. Mean emissions from industrial heating were 104 g CO2-equiv/MJ (90% CI: 87-123). By displacing coal, LNG saves 550 g CO2-equiv per kWh of electricity and 20 g per MJ of heat. LNG saves GHGs under upstream fugitive emissions rates up to 9% and 5% for electricity and heating, respectively. GHG reductions were found if Russian pipeline natural gas was displaced for electricity and heating use regardless of GWP, as long as U.S. fugitive emission rates remain below the estimated 5-7% rate of Russian gas. However, from a country specific carbon accounting perspective, there is an imbalance in accrued social costs and benefits. Assuming a mean social cost of carbon of $49/metric ton, mean global savings from U.S. LNG displacement of coal for electricity generation are $1.50 per thousand cubic feet (Mcf) of gaseous natural gas exported as LNG ($.028/kWh). Conversely, the U.S. carbon cost of exporting the LNG is $1.80/Mcf ($.013/kWh), or $0.50-$5.50/Mcf across the range of potential discount rates. This spatial shift in embodied carbon emissions is important to consider in national interest estimates for LNG exports.

  10. Fugitive Emissions from Conventional and Hydraulically Fractured Natural Gas Developments in Western Canada

    Science.gov (United States)

    Atherton, E. E.; Risk, D. A.; Lavoie, M.; Marshall, A. D.; Baillie, J.; Williams, J. P.

    2015-12-01

    Presently, fugitive emissions released into the atmosphere during the completion and production of oil and gas wells are poorly regulated within Canada. Some possible upstream sources of these emissions include flowback during well completions, liquid unloading, chemical injection pumps, and equipment leaks. The environmental benefits of combusting natural gas compared to oil or coal are negated if methane leakages surpass 3.2% of total production, so it is important to have a thorough understanding of these fugitive emissions. This study compares atmospheric leakage pathways of methane and other fugitive gases in both conventional and unconventional oil and gas developments in Western Canada to help fill this knowledge gap. Over 5000 kilometers of mobile survey campaigns were completed in carefully selected developments in the Montney shale play in British Columbia, and in conventional oil fields in Alberta. These sites are developed by more than 25 different operators. High precision laser and UV fluorescence gas analyzers were used to gather geolocated trace gas concentrations at a frequency of 1 Hz while driving. These data were processed with an adaptive technique to compensate for fluctuations in background concentrations for each gas. The residual excess concentrations were compositionally fingerprinted on the basis of the expected gas ratios for potential emission sites in order to definitively attribute anomalies to infrastructural leak sources. Preliminary results from the mobile surveys of both conventional and unconventional oil and gas sites are presented here. Pathways of methane and other fugitive gases are mapped to their respective sources, identifying common causes of emissions leaks across the oil and gas industry. This is the first bottom-up study of fugitive emissions from Canadian energy developments to produce publicly available data. These findings are significant to operators interested in lowering emissions for economic benefit, as well as

  11. Measurements of methane emissions from natural gas gathering facilities and processing plants: measurement methods

    Directory of Open Access Journals (Sweden)

    J. R. Roscioli

    2014-12-01

    Full Text Available Increased natural gas production in recent years has spurred intense interest in methane (CH4 emissions associated with its production, gathering, processing, transmission and distribution. Gathering and processing facilities (G&P facilities are unique in that the wide range of gas sources (shale, coal-bed, tight gas, conventional, etc. results in a wide range of gas compositions, which in turn requires an array of technologies to prepare the gas for pipeline transmission and distribution. We present an overview and detailed description of the measurement method and analysis approach used during a 20-week field campaign studying CH4 emissions from the natural gas G&P facilities between October 2013 and April 2014. Dual tracer flux measurements and onsite observations were used to address the magnitude and origins of CH4 emissions from these facilities. The use of a second tracer as an internal standard revealed plume-specific uncertainties in the measured emission rates of 20–47%, depending upon plume classification. Combining downwind methane, ethane (C2H6, carbon monoxide (CO, carbon dioxide (CO2, and tracer gas measurements with onsite tracer gas release allows for quantification of facility emissions, and in some cases a more detailed picture of source locations.

  12. Development of a new gas-flaring emission dataset for southern West Africa

    Science.gov (United States)

    Deetz, Konrad; Vogel, Bernhard

    2017-04-01

    A new gas-flaring emission parameterization has been developed, which combines remote sensing observations using Visible Infrared Imaging Radiometer Suite (VIIRS) nighttime data with combustion equations. The parameterization has been applied to southern West Africa, including the Niger Delta as a region that is highly exposed to gas flaring. Two 2-month datasets for June-July 2014 and 2015 were created. The parameterization delivers emissions of CO, CO2, NO, NO2 and SO2. A flaring climatology for both time periods has been derived. The uncertainties owing to cloud cover, parameter selection, natural gas composition and the interannual differences are assessed. The largest uncertainties in the emission estimation are linked to the parameter selection. It can be shown that the flaring emissions in Nigeria have significantly decreased by 25 % from 2014 to 2015. Existing emission inventories were used for validation. CO2 emissions with the estimated uncertainty in parentheses of 2.7 (3. 6/0. 5) Tg yr-1 for 2014 and 2.0 (2. 7/0. 4) Tg yr-1 for 2015 were derived. Regarding the uncertainty range, the emission estimate is in the same order of magnitude compared to existing emission inventories with a tendency for underestimation. The deviations might be attributed to a shortage in information about the combustion efficiency within southern West Africa, the decreasing trend in gas flaring or inconsistent emission sector definitions. The parameterization source code is available as a package of R scripts.

  13. Abstract on the Effective validation of both new and existing methods for the observation and forecasting of volcanic emissions

    Science.gov (United States)

    Sathnur, Ashwini

    2017-04-01

    Validation of the Existing products of the Remote Sensing instruments Review Comment Number 1 Ground - based instruments and space - based instruments are available for remote sensing of the Volcanic eruptions. Review Comment Number 2 The sunlight spectrum appears over the volcanic geographic area. This sunlight is reflected with the image of the volcano geographic area, to the satellite. The satellite captures this emitted spectrum of the image and further calculates the occurrences of the volcanic eruption. Review Comment Number 3 This computation system derives the presence and detection of sulphur dioxide and Volcanic Ash in the emitted spectrum. The temperature of the volcanic region is also measured. If these inputs derive the possibility of occurrence of an eruption, then the data is manually captured by the system for further usage and hazard mitigation. Review Comment Number 4 The instrument is particularly important in capturing the volcanogenic signal. This capturing operation should be carried out during the appropriate time of the day. This is carried out ideally at the time of the day when the reflected image spectra is best available. Capturing the data is not advisable to be performed at the night time, as the sunlight spectra is at its minimum. This would lead to erroneous data interpretation, as there is no sunlight for reflection of the volcanic region. Thus leading to the least capture of the emitted light spectra. Review Comment Number 5 An ideal area coverage of the spectrometer is mandatory. This is basically for the purpose of capturing the right area of data, in order to precisely derive the occurrence of a volcanic eruption. The larger the spatial resolution, there would be a higher capture of the geographic region, and this would lead to a lesser precise data capture. This would lead to missing details in the data capture. Review Comment Number 6 Ideal qualities for the remote sensing instrument are mentioned below:- Minimum "false

  14. Reduction in greenhouse gas emissions from vinasse through anaerobic digestion

    DEFF Research Database (Denmark)

    Moraes, Bruna S.; Petersen, Søren O.; Zaiat, Marcelo

    2017-01-01

    , and from fertirrigated soils. This study assessed GHG emissions in experiments simulating this vinasse management system, and the potential for reducing emissions of methane (CH4) and nitrous oxide (N2O) from vinasse via anaerobic digestion (AD) in biogas plants. During 21 days’ storage of untreated...... vinasse, 29% of dry matter (DM) and 40% of volatile solids (VS) were lost, which resulted in cumulative CH4 emissions of up to 43.8 kg CO2eq kg−1 C-vinasse. In contrast, there were no CH4 emissions from AD-treated vinasse (digestate) during storage. GHG emission was related to the biochemical...... characteristics of the untreated and digested vinasse. The accumulation of oxidised nitrogen (N) compounds was up to four-fold higher in soil amended with untreated vinasse than from digestate-amended soil. The N2O emissions from soil amended with untreated vinasse were also higher than from soil amended...

  15. Effect of greenhouse gas emissions on stratospheric ozone depletion

    OpenAIRE

    Velders GJM; LLO

    1997-01-01

    The depletion of the ozone layer is caused mainly by the increase in emissions of chlorine- and bromine-containing compounds like CFCs, halons, carbon tetrachloride, methyl chloroform and methyl bromide. Emissions of greenhouse gases can affect the depletion of the ozone layer through atmospheric interaction. We studied the interactions in the atmosphere between the greenhouse effect and stratospheric ozone depletion from the point of view of past and future emissions of the anthropogenic com...

  16. Effect of greenhouse gas emissions on stratospheric ozone depletion

    OpenAIRE

    Velders GJM; LLO

    1997-01-01

    The depletion of the ozone layer is caused mainly by the increase in emissions of chlorine- and bromine-containing compounds like CFCs, halons, carbon tetrachloride, methyl chloroform and methyl bromide. Emissions of greenhouse gases can affect the depletion of the ozone layer through atmospheric interaction. We studied the interactions in the atmosphere between the greenhouse effect and stratospheric ozone depletion from the point of view of past and future emissions of the anthropogenic com...

  17. An Adaptive Chemistry Approach to Modeling Emissions Performance of Gas Turbine Combustors Project

    Data.gov (United States)

    National Aeronautics and Space Administration — In this proposed SBIR project, we seek to implement the Adaptive Chemistry methodology in existing CFD codes used to investigate the emissions performance of gas...

  18. Greenhouse gas emissions in an agroforestry system in the southeastern U.S.

    Science.gov (United States)

    Agroforestry systems can provide diverse ecosystem services and economic benefits that conventional farming practices cannot. Importantly, these systems have the potential to mitigate greenhouse gas emissions by reducing the need for external inputs, enhancing nutrient cycling and promoting C seques...

  19. Executive Summary: EPA's Waiver Decision on California's Greenhouse Gas Emission Standards for New Motor Vehicles

    Science.gov (United States)

    This letter from EPA Administrator Stephen Johnson to Governor Schwarzenegger denies California's request for a waiver of Federal preemption for motor vehicle greenhouse gas emission standards submitted by the California Air Resources Board (CARB).

  20. The impact of demographic change on energy use and greenhouse gas emissions in Germany

    Energy Technology Data Exchange (ETDEWEB)

    Kronenberg, Tobias [Forschungszentrum Juelich, D-52425 Juelich (Germany)

    2009-08-15

    This paper estimates the impact of demographic change on energy use and greenhouse gas emissions in Germany. Since old people display different consumption patterns than young people, an increase in the proportion of old people affects overall consumption patterns. Micro data from a household survey are used to identify age-specific consumption patterns and to project the impact of demographic change on the structure of total consumption expenditure up to the year 2030. The resulting final demand vectors are entered into an environmental input-output model, which allows the calculation of sectoral production, energy use and greenhouse gas emissions. The model results suggest that until 2030, demographic change raises the share of methane in total greenhouse gas emissions and does not contribute to reducing energy use and greenhouse gas emissions in Germany. The model is also used to explore the effects of redistributing income between age groups and a policy-induced switch from motor vehicle use to public transport. (author)

  1. Soil C storage and greenhouse gas emission perennial grasses managed for bio energy feedstock

    Science.gov (United States)

    Perennial grasses like switchgrass or big bluestem when managed as bioenergy feedstock require nitrogenous inputs. Nitrogen fertilizer frequently cause nitrous oxide emission. Therefore, managing grasses as feedstock may reduce the greenhouse gas (GHG) mitigation potential expected from perennial. ...

  2. Gas Emission Prediction Model of Coal Mine Based on CSBP Algorithm

    Directory of Open Access Journals (Sweden)

    Xiong Yan

    2016-01-01

    Full Text Available In view of the nonlinear characteristics of gas emission in a coal working face, a prediction method is proposed based on cuckoo search algorithm optimized BP neural network (CSBP. In the CSBP algorithm, the cuckoo search is adopted to optimize weight and threshold parameters of BP network, and obtains the global optimal solutions. Furthermore, the twelve main affecting factors of the gas emission in the coal working face are taken as input vectors of CSBP algorithm, the gas emission is acted as output vector, and then the prediction model of BP neural network with optimal parameters is established. The results show that the CSBP algorithm has batter generalization ability and higher prediction accuracy, and can be utilized effectively in the prediction of coal mine gas emission.

  3. Effect of water injection on nitric oxide emissions of a gas turbine combustor burning natural gas fuel

    Science.gov (United States)

    Marchionna, N. R.; Diehl, L. A.; Trout, A. M.

    1973-01-01

    The effect of direct water injection on the exhaust gas emissions of a turbojet combustor burning natural gas fuel was investigated. The results are compared with the results from similar tests using ASTM Jet-A fuel. Increasing water injection decreased the emissions of oxides of nitrogen (NOX) and increased the emissions of carbon monoxide and unburned hydrocarbons. The greatest percentage decrease in NOX with increasing water injection was at the lowest inlet-air temperature tested. The effect of increasing inlet-air temperature was to decrease the effect of the water injection. The reduction in NOX due to water injection was almost identical to the results obtained with Jet-A fuel. However, the emission indices of unburned hydrocarbons, carbon monoxide, and percentage nitric oxide in NOX were not.

  4. XMM-Newton discovery of O VII emission from warm gas in clusters of galaxies

    CERN Document Server

    Kaastra, J S; Tamura, T; Paerels, F B S; Den Herder, J W A

    2003-01-01

    XMM-Newton recently discovered O VII line emission from ~2 million K gas near the outer parts of several clusters of galaxies. This emission is attributed to the Warm-Hot Intergalactic Medium. The original sample of clusters studied for this purpose has been extended and two more clusters with a soft X-ray excess have been found. We discuss the physical properties of the warm gas, in particular the density, spatial extent, abundances and temperature.

  5. Uncertainty in greenhouse-gas emission scenario projections: Experiences from Mexico and South Africa

    DEFF Research Database (Denmark)

    Puig, Daniel

    This report outlines approaches to quantify the uncertainty associated with national greenhouse-gas emission scenario projections. It does so by describing practical applications of those approaches in two countries – Mexico and South Africa. The goal of the report is to promote uncertainty...... quantification, because quantifying uncertainty has the potential to foster more robust climate-change mitigation plans. To this end the report also summarises the rationale for quantifying uncertainty in greenhouse-gas emission scenario projections....

  6. Combustion LES Software for Improved Emissions Predictions of High Performance Gas Turbine Combustors

    Science.gov (United States)

    2005-09-01

    94 vii 8503/8 ABSTRACT Low emissions of CO, NO,, and unburned hydrocarbons ( UHC ) are a difficult...NOR, UHC , and smoke, are becoming a requirement for today’s and future military gas turbine engines. Advanced, high performance gas turbines will...range, and operating pressure. 2 850318 1. INTRODUCTION Low emissions of pollutants, including CO, NO,,, UHC , and smoke, are becoming a requirement

  7. Characteristics of seismic waves composing Hawaiian volcanic tremor and gas-piston events observed by a near-source array

    Science.gov (United States)

    Ferrazzini, Valerie; Aki, Keiiti; Chouet, Bernard

    1991-04-01

    A correlation method, specifically designed for describing the characteristics of a complex wave field, is applied to volcanic tremor and gas-piston events recorded by a semicircular array of GEOS instruments set at the foot of the Puu Oo crater on the east rift of Kilauea volcano, Hawaii. The spatial patterns of correlation coefficients obtained as functions of frequency for the three components of motion over the entire array are similar for gas-piston events and tremor, and clearly depict dispersive waves propagating across the array from the direction of Puu Oo. The wave fields are composed of comparable amounts of Rayleigh and Love waves propagating with similar and extremely slow phase velocities ranging from 700 m/s at 2 Hz to 300 m/s at 8 Hz. The highly cracked solidified lava flow on which the array was deployed, and subjacent structure of alternating lava and ash layers formed during repeated eruptions of Puu Oo since 1983, appear to be responsible for the low velocities observed. The results from Puu Oo stand in sharp contrast to those obtained in an experiment conducted in 1976 on the partially solidified lava lake of Kilauea Iki. Rayleigh waves were not observed in Kilauea Iki, but well-developed trains of Love waves were seen to propagate there with velocities twice as high as those observed near Puu Oo. These differences in the propagation characteristics of surface waves at the two sites may be attributed to the presence of a soft horizontal layer of molten rock in Kilauea Iki, which may have lowered the phase velocity of Rayleigh waves more drastically than that of Love waves, resulting in severe scattering of the Rayleigh wave mode. On the other hand, the thin superficial pahoehoe flow under our array at Puu Oo may have favored the development of vertical columnar joints more extensively at this location than at Kilauea Iki, which may have reduced the shear moduli controlling the Love wave mode. The average phase velocities in the frequency band

  8. Natural Gas Methane Emissions in the United States Greenhouse Gas Inventory: Sources, Uncertainties and Opportunities for Improvement

    Energy Technology Data Exchange (ETDEWEB)

    Heath, Garvin; Warner, Ethan; Steinberg, Daniel; Brandt, Adam

    2015-11-19

    Presentation summarizing key findings of a Joint Institute for Strategic Energy Analysis Report at an Environmental Protection Agency workshop: 'Stakeholder Workshop on EPA GHG Data on Petroleum and Natural Gas Systems' on November 19, 2015. For additional information see the JISEA report, 'Estimating U.S. Methane Emissions from the Natural Gas Supply Chain: Approaches, Uncertainties, Current Estimates, and Future Studies' NREL/TP-6A50-62820.

  9. Estimation of Energy Consumption and Greenhouse Gas Emissions of Transportation in Beef Cattle Production

    Directory of Open Access Journals (Sweden)

    Narayanan Kannan

    2016-11-01

    Full Text Available Accounting for transportation is an important part of the life cycle analysis (LCA of beef cattle production because it is associated with energy consumption and greenhouse gas emissions. This paper describes the development and application of a model that estimates energy consumption and greenhouse gas emissions of transport in beef cattle production. The animal transport model is based on the weight and number of animals in each weight category, type of trailer, vehicle, and fuel used. The energy consumption and greenhouse gas emission estimates of animal feed transportation are based on the weight of a truckload and the number of truckloads of feed transported. Our results indicate that a truckload is travelling approximately 326 km in connection with beef cattle production in the study region. The fuel consumption amounts to 24 L of fossil fuel per 1000 kg of boneless beef. The corresponding greenhouse gas emission is 83 kg. It appears from our results that the majority of energy consumption and greenhouse gas emissions are associated with sending the finished cattle to slaughterhouses and bringing feeder cattle to feedlots. Our results point out appreciable reductions in energy consumption and greenhouse gas emissions by changing from conventional fuel to bio-fuel.

  10. Effect of greenhouse gas emissions on stratospheric ozone depletion

    NARCIS (Netherlands)

    Velders GJM; LLO

    1997-01-01

    The depletion of the ozone layer is caused mainly by the increase in emissions of chlorine- and bromine-containing compounds like CFCs, halons, carbon tetrachloride, methyl chloroform and methyl bromide. Emissions of greenhouse gases can affect the depletion of the ozone layer through atmospheric i

  11. Effect of greenhouse gas emissions on stratospheric ozone depletion

    NARCIS (Netherlands)

    Velders GJM; LLO

    1997-01-01

    The depletion of the ozone layer is caused mainly by the increase in emissions of chlorine- and bromine-containing compounds like CFCs, halons, carbon tetrachloride, methyl chloroform and methyl bromide. Emissions of greenhouse gases can affect the depletion of the ozone layer through atmospheric

  12. Consequences of agro-biofuel production for greenhouse gas emissions

    DEFF Research Database (Denmark)

    Carter, Mette Sustmann; Johansen, Anders; Hauggard-Nielsen, Henrik;

    2008-01-01

    The objective of the study was to examine the effect on N2O and CH4 emissions when residues from bio-energy production are recycling as organic fertilizer for a maize energy crop. The study showed that the N2O emission associated with the cultivation of the maize crop offset a considerable faction...

  13. Deep greenhouse gas emission reductions in Europe: Exploring different options

    NARCIS (Netherlands)

    Deetman, S.; Hof, A.F.; Pfluger, B.; Vuuren, D.P. van; Girod, B.; Ruijven, B.J. van

    2013-01-01

    Most modelling studies that explore emission mitigation scenarios only look into least-cost emission pathways, induced by a carbon tax. This means that European policies targeting specific - sometimes relatively costly - technologies, such as electric cars and advanced insulation measures, are usual

  14. Identification of tropospheric emissions sources from satellite observations: Synergistic use of HCHO, NO2, and SO2 trace gas measurements

    Science.gov (United States)

    Marbach, T.; Beirle, S.; Khokhar, F.; Platt, U.

    2005-12-01

    We present case studies for combined HCHO, NO2, and SO2 satellite observations, derived from GOME measurements. Launched on the ERS-2 satellite in April 1995, GOME has already performed continuous operations over 8 years providing global observations of the different trace gases. In this way, satellite observations provide unique opportunities for the identifications of trace gas sources. The satellite HCHO observations provide information concerning the localization of biomass burning (intense source of HCHO). The principal biomass burning areas can be observed in the Amazon basin region and in central Africa Weaker HCHO sources (south east of the United States, northern part of the Amazon basin, and over the African tropical forest), not correlated with biomass burning, could be due to biogenic isoprene emissions. The HCHO data can be compared with NO2 and SO2 results to identify more precisely the tropospheric sources (biomass burning events, human activities, additional sources like volcanic emissions). Biomass burning are important tropospheric sources for both HCHO and NO2. Nevertheless HCHO reflects more precisely the biomass burning as it appears in all biomass burning events. NO2 correlate with HCHO over Africa (grassland fires) but not over Indonesia (forest fires). In south America, an augmentation of the NO2 concentrations can be observed with the fire shift from the forest to grassland vegetation. So there seems to be a dependence between the NO2 emissions during biomass burning and the vegetation type. Other high HCHO, SO2, and NO2 emissions can be correlated with climatic events like the El Nino in 1997, which induced dry conditions in Indonesia causing many forest fires.

  15. Multi-objective optimisation of wastewater treatment plant control to reduce greenhouse gas emissions.

    Science.gov (United States)

    Sweetapple, Christine; Fu, Guangtao; Butler, David

    2014-05-15

    This study investigates the potential of control strategy optimisation for the reduction of operational greenhouse gas emissions from wastewater treatment in a cost-effective manner, and demonstrates that significant improvements can be realised. A multi-objective evolutionary algorithm, NSGA-II, is used to derive sets of Pareto optimal operational and control parameter values for an activated sludge wastewater treatment plant, with objectives including minimisation of greenhouse gas emissions, operational costs and effluent pollutant concentrations, subject to legislative compliance. Different problem formulations are explored, to identify the most effective approach to emissions reduction, and the sets of optimal solutions enable identification of trade-offs between conflicting objectives. It is found that multi-objective optimisation can facilitate a significant reduction in greenhouse gas emissions without the need for plant redesign or modification of the control strategy layout, but there are trade-offs to consider: most importantly, if operational costs are not to be increased, reduction of greenhouse gas emissions is likely to incur an increase in effluent ammonia and total nitrogen concentrations. Design of control strategies for a high effluent quality and low costs alone is likely to result in an inadvertent increase in greenhouse gas emissions, so it is of key importance that effects on emissions are considered in control strategy development and optimisation.

  16. Effects of headspace and oxygen level on off-gas emissions from wood pellets in storage.

    Science.gov (United States)

    Kuang, Xingya; Shankar, Tumuluru Jaya; Sokhansanj, Shahab; Lim, C Jim; Bi, Xiaotao T; Melin, Staffan

    2009-11-01

    Few papers have been published in the open literature on the emissions from biomass fuels, including wood pellets, during the storage and transportation and their potential health impacts. The purpose of this study is to provide data on the concentrations, emission factors, and emission rate factors of CO(2), CO, and CH(4) from wood pellets stored with different headspace to container volume ratios with different initial oxygen levels, in order to develop methods to reduce the toxic off-gas emissions and accumulation in storage spaces. Metal containers (45 l, 305 mm diameter by 610 mm long) were used to study the effect of headspace and oxygen levels on the off-gas emissions from wood pellets. Concentrations of CO(2), CO, and CH(4) in the headspace were measured using a gas chromatograph as a function of storage time. The results showed that the ratio of the headspace ratios and initial oxygen levels in the storage space significantly affected the off-gas emissions from wood pellets stored in a sealed container. Higher peak emission factors and higher emission rates are associated with higher headspace ratios. Lower emissions of CO(2) and CO were generated at room temperature under lower oxygen levels, whereas CH(4) emission is insensitive to the oxygen level. Replacing oxygen with inert gases in the storage space is thus a potentially effective method to reduce the biomass degradation and toxic off-gas emissions. The proper ventilation of the storage space can also be used to maintain a high oxygen level and low concentrations of toxic off-gassing compounds in the storage space, which is especially useful during the loading and unloading operations to control the hazards associated with the storage and transportation of wood pellets.

  17. Evaluation of greenhouse gas emissions from waste management approaches in the islands.

    Science.gov (United States)

    Chen, Ying-Chu

    2017-07-01

    Concerns about waste generation and climate change have attracted worldwide attention. Small islands, which account for more than one-sixth of the global land area, are facing problems caused by global climate change. This study evaluated the greenhouse gas emissions from five small islands surrounding Taiwan. These islands - Penghu County, Liuqui Island, Kinmen County, Matsu Island and Green Island - have their own waste management approaches that can serve as a guideline for waste management with greenhouse gas mitigation. The findings indicate that the total annual greenhouse gas emissions of the islands ranged from 292.1 to 29,096.2 [metric] tonne CO2-equivalent. The loading waste volumes and shipping distances were positively related to greenhouse gas emissions from transportation. The greenhouse gas emissions from waste-to-energy plants, mainly carbon dioxide and nitrous oxide, can be offset by energy recovery (approximately 38.6% of greenhouse gas emissions from incineration). In addition, about 34% and 11% of waste generated on the islands was successfully recycled and composted, respectively. This study provides valuable insights into the applicability of a policy framework for waste management approaches for greenhouse gas mitigation.

  18. Dense Molecular Gas and H2O Maser Emission in Galaxies

    Indian Academy of Sciences (India)

    F. Huang; J. S. Zhang; R. M. Li; H. K. Li

    2014-09-01

    Extragalactic H2O masers have been found in dense gas circumstance in off-nuclear star formation regions or within parsecs of Active Galactic Nuclei (AGNs). HCN molecular (one of the best dense gas tracers) Emission has been detected in more than 60 galaxies. For HCN-detected galaxy sample, the relation of maser and gas emission was investigated here to identify physical observable properties that differentiate maser and non-maser galaxies. Our analysis results show that there is no significant difference on the infrared and gas emission between maser galaxies and galaxies without maser detection. For maser host HCN-galaxies, maser luminosity is found to be correlated to CO luminosity (a proxy of the total molecular gas) and HCN luminosity, i.e., kilomasers (H2O < 10⊙) with low maser luminosity having low gas emission luminosity, with respect to megamasers (H2O > 10⊙). For normalized maser and HCN luminosity (for removing distance effect), the correlation is still apparent. However, for normalized maser and CO luminosity, the correlation disappeared completely. Thus one proposition that the amount of dense molecular gas should be a good tracer of H2O maser emission can be made.

  19. Particulate Matter Emission from Dual Fuel Diesel Engine Fuelled with Natural Gas

    Directory of Open Access Journals (Sweden)

    Stelmasiak Zdzisław

    2017-06-01

    Full Text Available The paper presents the results of examination of particulate matter emission from the Diesel engine FPT 1.3 MJT simultaneously fuelled with diesel oil and natural gas CNG. The basic premise for engine adaptation was the addition of a small amount of CNG to reduce exhaust gas opacity and particulate matter emission. At this assumption, diesel oil remained the basic fuel, with contribution amounting to 0,70-0,85 of total energy delivered to the engine. The dual fuel engine was examined using an original controller installed in the Diesel engine FPT 1.3 MJT which controlled the diesel fuel dose. The dose of the injected natural gas was controlled by changing the opening time of gas injectors at constant pressure in the gas collector. The examined issues included the exhaust gas opacity, and the total number and fractional distribution of the emitted particles. The measurements were performed at twenty selected measuring points corresponding to the New European Driving Cycle (NEDC test. The performed tests have demonstrated a positive effect of gas addition on exhaust gas opacity and particulate matter emission. Depending on test conditions, the exhaust gas opacity was reduced by 10÷92%, and the total number of particles by 30÷40%. The performed tests have revealed that a small addition of gas can reduce the load of the DPF filter, extend its lifetime, and increase engine reliability. Longer time intervals between successive DPF filter regenerations improve ecological properties of the engine.

  20. Characterization of Gas and Particle Emissions from Laboratory Burns of Peat

    Science.gov (United States)

    Peat cores collected from two locations in eastern North Carolina (NC, USA) were burned in a laboratory facility to characterize emissions during simulated field combustion. Particle and gas samples were analyzed to quantify emission factors for particulate matter (PM2.5), organi...

  1. METHANE EMISSIONS FROM THE NATURAL GAS INDUSTRY VOLUME 13: CHEMICAL INJECTION PUMPS

    Science.gov (United States)

    The 15-volume report summarizes the results of a comprehensive program to quantify methane (CH4) emissions from the U.S. natural gas industry for the base year. The objective was to determine CH4 emissions from the wellhead and ending downstream at the customer's meter. The accur...

  2. Life-cycle analysis of greenhouse gas emissions from renewable jet fuel production

    NARCIS (Netherlands)

    De Jong, Sierk; Antonissen, Kay; Hoefnagels, Ric; Lonza, Laura; Wang, Michael; Faaij, André; Junginger, Martin

    2017-01-01

    Background: The introduction of renewable jet fuel (RJF) is considered an important emission mitigation measure for the aviation industry. This study compares the well-to-wake (WtWa) greenhouse gas (GHG) emission performance of multiple RJF conversion pathways and explores the impact of different

  3. Pile mixing increases greenhouse gas emissions during composting of dairy manure

    Science.gov (United States)

    The effect of pile mixing on greenhouse gas (GHG) emissions from stored dairy manure was determined using large flux chambers designed to completely cover pilot-scale manure piles. GHG emissions from piles that were mixed four times during the 80 day trial were about 20% higher than unmixed piles. ...

  4. Greenhouse Gas Emissions in the Netherlands 1990-2011. National Inventory Report 2013

    Energy Technology Data Exchange (ETDEWEB)

    Coenen, P.W.H.G.; Droege, R. [Netherlands Organisation for Applied Scientific Research TNO, P.O. Box 80015, NL-3508 TA Utrecht (Netherlands); Zijlema, P.J. [NL Agency, P.O. Box 8242, NL-3503 RE Utrecht (Netherlands); Arets, E.J.M.M. [Alterra Wageningen UR, P.O. Box 47 NL-6700 AA Wageningen (Netherlands); Baas, K. [Statistics Netherlands CBS, P.O. Box 24500, NL-2490 HA Den Haag (Netherlands); Van den Berghe, A.C.W.M. [Rijkswaterstaat, P.O. Box 8242, NL-3503 RE Utrecht (Netherlands); Brandt, A.T. [Dutch Emissions Authority NEa, P.O. Box 91503, NL-2509 EC Den Haag (Netherlands); Geilenkirchen, G. [PBL Netherlands Environmental Assessment Agency, P.O. Box 303 NL-3720 AH Bilthoven (Netherlands); Van der Maas, C.W.M.; Te Biesebeek, J.D.; Van der Hoek, K.W.; Te Molder, R.; Montfoort, J.A.; Peek, C.J.; Vonk, J. [National Institute of Public Health and Environmental Protection RIVM, Bilthoven (Netherlands)

    2013-04-15

    Total greenhouse gas emissions from The Netherlands in 2011 decreased by approximately 7 per cent compared with 2010 emissions. This decrease is mainly the result of decreased fuel combustion in the Energy sector (less electricity production) and in the petrochemical industry. Fuel use for space heating decreased due to the mild winter compared with the very cold 2010 winter. In 2011, total direct greenhouse gas emissions (excluding emissions from LULUCF (land use, land use change and forestry) in The Netherlands amounted to 194.4 Tg CO2 eq. This is approximately 9 per cent below the emissions in the base year 2 (213.2 Tg CO2 eq). This report documents the Netherlands' 2012 annual submission of its greenhouse gas emissions inventory in accordance with the guidelines provided by the United Nations Framework Convention on Climate Change (UNFCCC), the Kyoto Protocol and the European Union's Greenhouse Gas Monitoring Mechanism. The report comprises explanations of observed trends in emissions; a description of an assessment of key sources and their uncertainty; documentation of methods, data sources and emission factors applied; and a description of the quality assurance system and the verification activities performed on the data.

  5. METHANE EMISSIONS FROM THE NATURAL GAS INDUSTRY VOLUME 12: PNEUMATIC DEVICES

    Science.gov (United States)

    The 15-volume report summarizes the results of a comprehensive program to quantify methane (CH4) emissions from the U.S. natural gas industry for the base year. The objective was to determine CH4 emissions from the wellhead and ending downstream at the customer's meter. The accur...

  6. Greenhouse gas emissions in The Netherlands 1990-2012; National inventory report 2014

    NARCIS (Netherlands)

    Coenen, P.W.H.G.; Maas, C.W.M.; Zijlema, P.J.; Arets, E.J.M.M.; Baas, K.; Berghe, van den A.C.W.M.; Biesebeek, te J.D.; Nijkamp, M.M.; Huis, E.P.

    2014-01-01

    Total greenhouse gas emissions from the Netherlands in 2012 decreased by approximately 1.7 per cent, compared with 2011 emissions. This decrease is mainly the result of decreased fuel combustion in the Energy sector (increased electricity import) and in road transport. In 2012, total direct greenhou

  7. Greenhouse gas emissions in The Netherlands 1990-2011. National Inventory Report 2013

    NARCIS (Netherlands)

    Coenen, P.W.H.G.; Maas, C.W.M.; Zijlema, P.J.; Arets, E.J.M.M.; Baas, K.; Berghe, van den A.C.W.M.; Biesebeek, te J.D.; Brandt, A.T.; Geilenkirchen, G.; Hoek, van der K.W.; Molder, te R.; Dröge, R.; Montfoort, J.A.; Peek, C.J.; Vonk, J.

    2013-01-01

    Total greenhouse gas emissions from The Netherlands in 2011 decreased by approximately 7 per cent compared with 2010 emissions. This decrease is mainly the result of decreased fuel combustion in the Energy sector (less electricity production) and in the petrochemical industry. Fuel use for space hea

  8. Subjective Well-Being Approach to Environmental Valuation: Evidence for Greenhouse Gas Emissions

    Science.gov (United States)

    Beja, Edsel L., Jr.

    2012-01-01

    The subjective well-being approach to environmental valuation is applied to analyze the valuation of greenhouse gas emissions with a fairness-adjustment in the valuation exercise. Results indicate that industrialized countries have high willingness-to-pay to reduce emissions. Developing countries differ in their valuations. Results indicate that…

  9. Lateral gas transport in soil adjacent to an old landfill: factors governing emissions and methane oxidation

    DEFF Research Database (Denmark)

    Christophersen, Mette; Kjeldsen, Peter; Holst, Helle

    2001-01-01

    Field investigations of lateral gas transport and subsequent emissions in soil adjacent to an old landfill in Denmark have been conducted during a one-year period. A significant seasonal variation in the emissions with high carbon dioxide and low methane fluxes in the summer (May to October...

  10. METHANE EMISSIONS FROM THE NATURAL GAS INDUSTRY VOLUME 11: COMPRESSOR DRIVER EXHAUST

    Science.gov (United States)

    The 15-volume report summarizes the results of a comprehensive program to quantify methane (CH4) emissions from the U.S. natural gas industry for the base year. The objective was to determine CH4 emissions from the wellhead and ending downstream at the customer's meter. The accur...

  11. METHANE EMISSIONS FROM THE NATURAL GAS INDUSTRY VOLUME 7: BLOW AND PURGE ACTIVITIES

    Science.gov (United States)

    The 15-volume report summarizes the results of a comprehensive program to quantify methane (CH4) emissions from the U.S. natural gas industry for the base year. The objective was to determine CH4 emissions from the wellhead and ending downstream at the customer's meter. The accur...

  12. 76 FR 50164 - Protocol Gas Verification Program and Minimum Competency Requirements for Air Emission Testing...

    Science.gov (United States)

    2011-08-12

    ... AGENCY 40 CFR Parts 72 and 75 RIN 2060-AQ06 Protocol Gas Verification Program and Minimum Competency... Program and Minimum Competency Requirements for Air Emission Testing rule. EPA published in the Federal... Program (PGVP) and the minimum competency requirements for Air Emission Testing Bodies (AETBs), and...

  13. Greenhouse Gas Emissions in the Netherlands 1990-2010. National Inventory Report 2012

    Energy Technology Data Exchange (ETDEWEB)

    Coenen, P.W.H.G.; Van der Hoek, K.W.; Te Molder, R.; Droege, R. [Netherlands Organisation for Applied Scientific Research TNO, P.O. Box 80015, NL-3508 TA Utrecht (Netherlands); Van der Maas, C.W.M.; Zijlema, P.J.; Van den Berghe, A.C.W.M. [NL Agency, P.O. Box 8242, NL-3503 RE Utrecht (Netherlands); Baas, K. [Statistics Netherlands CBS, P.O. Box 24500, NL-2490 HA Den Haag (Netherlands); Te Biesebeek, J.D.; Brandt, A.T. [Dutch Emission Authority, P.O. Box 91503, IPC 652, NL-2509 EC Den Haag (Netherlands); Geilenkirchen, G. [Netherlands Environmental Assessment Agency PBL, P.O. Box 303 NL-3720 AH Bilthoven (Netherlands); Montfoort, J.A.; Peek, C.J.; Vonk, J.; Van den Wyngaert, I. [Alterra Wageningen UR, P.O. Box 47 NL-6700 AA Wageningen (Netherlands)

    2012-03-15

    The total greenhouse gas emission from the Netherlands in 2010 increased by approximately 6% compared to the emission in 2009. This increase is mainly the result of increased fuel combustion in the energy sector and space heating. In 2010, total direct greenhouse gas emissions (excluding emissions from LULUCF - land use, land use change and forestry) in the Netherlands amounted to 210.1 Tg CO2 eq. This is approximately 1.5% below the emissions in the base year (213.3 Tg CO2 eq). This report documents the 2012 Netherlands' annual submission of its greenhouse gas emission inventory in accordance with the guidelines provided by the United Nations Framework Convention on Climate Change (UNFCCC), the Kyoto Protocol and the European Union's Greenhouse Gas Monitoring Mechanism. The report comprises explanations of observed trends in emissions; a description of an assessment of key sources and their uncertainty; documentation of methods, data sources and emission factors applied; and a description of the quality assurance system and the verification activities performed on the data.

  14. Greenhouse Gas Emissions in the Netherlands 1990-2009. National Inventory Report 2011

    Energy Technology Data Exchange (ETDEWEB)

    Coenen, P.W.H.G.; Van der Hoek, K.W.; Te Molder, R.; Droege, R. [Netherlands Organisation for Applied Scientific Research TNO, P.O. Box 80015, NL-3508 TA Utrecht (Netherlands); Van der Maas, C.W.M.; Zijlema, P.J.; Van den Berghe, A.C.W.M. [NL Agency, P.O. Box 8242, NL-3503 RE Utrecht (Netherlands); Baas, K. [Statistics Netherlands CBS, P.O. Box 24500, NL-2490 HA Den Haag (Netherlands); Te Biesebeek, J.D.; Brandt, A.T. [Dutch Emission Authority, P.O. Box 91503, IPC 652, NL-2509 EC Den Haag (Netherlands); Geilenkirchen, G. [Netherlands Environmental Assessment Agency PBL, P.O. Box 303 NL-3720 AH Bilthoven (Netherlands); Montfoort, J.A.; Peek, C.J.; Vonk, J.; Van den Wyngaert, I. [Alterra Wageningen UR, P.O. Box 47 NL-6700 AA Wageningen (Netherlands)

    2012-03-15

    The total greenhouse gas emission from the Netherlands in 2010 increased by approximately 6% compared to the emission in 2009. This increase is mainly the result of increased fuel combustion in the energy sector and space heating. In 2010, total direct greenhouse gas emissions (excluding emissions from LULUCF - land use, land use change and forestry) in the Netherlands amounted to 210.1 Tg CO2 eq. This is approximately 1.5% below the emissions in the base year (213.3 Tg CO2 eq). This report documents the 2012 Netherlands' annual submission of its greenhouse gas emission inventory in accordance with the guidelines provided by the United Nations Framework Convention on Climate Change (UNFCCC), the Kyoto Protocol and the European Union's Greenhouse Gas Monitoring Mechanism. The report comprises explanations of observed trends in emissions; a description of an assessment of key sources and their uncertainty; documentation of methods, data sources and emission factors applied; and a description of the quality assurance system and the verification activities performed on the data.

  15. Greenhouse gas emissions from an irrigated dairy forage rotation as influenced by fertilizer and manure applications

    Science.gov (United States)

    Little information is available regarding the long-term effects of nitrogen (N) fertilizer source on greenhouse gas (GHG) emissions from irrigated semiarid agricultural soils. In this study, conducted in south-central Idaho, we report nitrous oxide emissions along with carbon dioxide and methane fro...

  16. Life-cycle analysis of greenhouse gas emissions from renewable jet fuel production

    NARCIS (Netherlands)

    De Jong, Sierk; Antonissen, Kay; Hoefnagels, Ric; Lonza, Laura; Wang, Michael; Faaij, André; Junginger, Martin

    2017-01-01

    Background: The introduction of renewable jet fuel (RJF) is considered an important emission mitigation measure for the aviation industry. This study compares the well-to-wake (WtWa) greenhouse gas (GHG) emission performance of multiple RJF conversion pathways and explores the impact of different co

  17. Greenhouse gas emissions profiles of neighbourhoods in Durban, South Africa – an initial investigation

    CSIR Research Space (South Africa)

    Jagarnath, M

    2017-08-01

    Full Text Available Because current emissions accounting approaches focus on an entire city, cities are often considered to be large emitters of greenhouse gas (GHG) emissions, with no attention to the variation within them. This makes it more difficult to identify...

  18. Subjective Well-Being Approach to Environmental Valuation: Evidence for Greenhouse Gas Emissions

    OpenAIRE

    Beja Jr., Edsel L.

    2011-01-01

    The subjective well-being approach to environmental valuation is applied to analyze the valuation of greenhouse gas emissions. Dimensions like population and income are then incorporated into the valuation to get the fairness-adjusted marginal value of emissions. The results indicate that the industrialized countries have high willingness-to-pay to reduce emissions with the United States and Japan reporting the largest figures. Developing countries differ in their valuations, albeit they are ...

  19. Greenhouse Gas Emissions in the Netherlands 1990-2001. National Inventory Report 2003

    NARCIS (Netherlands)

    Olivier JGJ; Brandes LJ; Peters JAHW; Coenen PWHG; Vreuls HHJ; KMD; IMP

    2003-01-01

    This report documents the 2003 Netherlands' annual submission of its greenhouse gas emission inventory in accordance with the United Nation's Framework Convention on Climate Change (UNFCCC) and the European Union's Greenhouse Gas Monitoring Mechanism. The report comprises explanations of observed tr

  20. 77 FR 22391 - Standards of Performance for Greenhouse Gas Emissions for New Stationary Sources: Electric...

    Science.gov (United States)

    2012-04-13

    ... report, ``Each additional ton of greenhouse gases emitted commits us to further change and greater risks... Greenhouse Gas Concentrations; Board on Atmospheric Sciences and Climate, Division of Earth and Life Sciences... Greenhouse Gas Emissions for New Stationary Sources; Electric Utility Generating Units; Proposed Rule...

  1. Novel Oxygen Storage Components Promoted Palladium Catalysts for Emission Control in Natural Gas Powered Engines

    Institute of Scientific and Technical Information of China (English)

    Bin ZHAO; Mao Chu GONG; Xue Song FENG; Yong Yue LUO; Yao Qiang CHEN

    2005-01-01

    A three-way catalyst comprised novel oxygen storage components for emission control in natural gas powered engines was prepared. The addition of novel oxygen storage components to the Pd/γ-A12O3 catalysts resulted in improved activities of the fresh and aged catalyst by lowering the light-off temperature for methane in natural gas engines exhaust.

  2. Stoichiometric and lean burn heavy-duty gas engines: a dilemma between emissions and fuel consumption?

    NARCIS (Netherlands)

    Steen, M. van der; Rijke, J. de; Seppen, J.J.

    1996-01-01

    This paper compares stoichiometric with lean burn technology for heavy-duty gas engines (natural gas and LPG) and demonstrates that there is a future for both engine concepts on the multilateral global market. Emission limits in Europe as expected in the near future will facilitate both engine conce

  3. Fugitive methane emissions from leak-prone natural gas distribution infrastructure in urban environments.

    Science.gov (United States)

    Hendrick, Margaret F; Ackley, Robert; Sanaie-Movahed, Bahare; Tang, Xiaojing; Phillips, Nathan G

    2016-06-01

    Fugitive emissions from natural gas systems are the largest anthropogenic source of the greenhouse gas methane (CH4) in the U.S. and contribute to the risk of explosions in urban environments. Here, we report on a survey of CH4 emissions from 100 natural gas leaks in cast iron distribution mains in Metro Boston, MA. Direct measures of CH4 flux from individual leaks ranged from 4.0 - 2.3 × 10(4) g CH4•day(-1). The distribution of leak size is positively skewed, with 7% of leaks contributing 50% of total CH4 emissions measured. We identify parallels in the skewed distribution of leak size found in downstream systems with midstream and upstream stages of the gas process chain. Fixing 'superemitter' leaks will disproportionately stem greenhouse gas emissions. Fifteen percent of leaks surveyed qualified as potentially explosive (Grade 1), and we found no difference in CH4 flux between Grade 1 leaks and all remaining leaks surveyed (p = 0.24). All leaks must be addressed, as even small leaks cannot be disregarded as 'safely leaking.' Key methodological impediments to quantifying and addressing the impacts of leaking natural gas distribution infrastructure involve inconsistencies in the manner in which gas leaks are defined, detected, and classified. To address this need, we propose a two-part leak classification system that reflects both the safety and climatic impacts of natural gas leaks.

  4. Greenhouse Gas Emissions from Asphalt Pavement Construction: A Case Study in China.

    Science.gov (United States)

    Ma, Feng; Sha, Aimin; Lin, Ruiyu; Huang, Yue; Wang, Chao

    2016-03-22

    In China, the construction of asphalt pavement has a significant impact on the environment, and energy use and greenhouse gas (GHG) emissions from asphalt pavement construction have been receiving increasing attention in recent years. At present, there is no universal criterion for the evaluation of GHG emissions in asphalt pavement construction. This paper proposes to define the system boundaries for GHG emissions from asphalt pavement by using a process-based life cycle assessment method. A method for evaluating GHG emissions from asphalt pavement construction is suggested. The paper reports a case study of GHG emissions from a typical asphalt pavement construction project in China. The results show that the greenhouse gas emissions from the mixture mixing phase are the highest, and account for about 54% of the total amount. The second highest GHG emission phase is the production of raw materials. For GHG emissions of cement stabilized base/subbase, the production of raw materials emits the most, about 98%. The GHG emission for cement production alone is about 92%. The results indicate that any measures to reduce GHG emissions from asphalt pavement construction should be focused on the raw materials manufacturing stage. If the raw materials production phase is excluded, the measures to reduce GHG emissions should be aimed at the mixture mixing phase.

  5. Detecting deep crustal magma movement: Exploring linkages between increased gas emission, deep seismicity, and deformation (Invited)

    Science.gov (United States)

    Werner, C. A.; Poland, M. P.; Power, J. A.; Sutton, A. J.; Elias, T.; Grapenthin, R.; Thelen, W. A.

    2013-12-01

    Typically in the weeks to days before a volcanic eruption there are indisputable signals of unrest that can be identified in geophysical and geochemical data. Detection of signals of volcanic unrest months to years prior to an eruption, however, relies on our ability to recognize and link more subtle changes. Deep long-period earthquakes, typically 10-45 km beneath volcanoes, are thought to represent magma movement and may indicate near future unrest. Carbon dioxide (CO2 ) exsolves from most magmas at similar depths and increases in CO2 discharge may also provide a months-to-years precursor as it emits at the surface in advance of the magma from which it exsolved. Without the use of sensitive monitoring equipment and routine measurements, changes in CO2 can easily go undetected. Finally, inflation of the surface, through use of InSAR or GPS stations (especially at sites tens of km from the volcano) can also indicate accumulation of magma in the deep crust. Here we present three recent examples, from Redoubt, Kilauea, and Mammoth Mountain volcanoes, where increases in CO2 emission, deep long-period earthquakes, and surface deformation data indicate either the intrusion of magma into the deep crust in the months to years preceding volcanic eruptions or a change in ongoing volcanic unrest. At Redoubt volcano, Alaska, elevated CO2 emission (~ 1200 t/d, or roughly 20 times the background emission) was measured in October, 2008, over 5 months prior to the first magmatic eruption in March, 2009. In addition to CO2 release, deep long-period earthquakes were first recorded in December, 2008, and a deep deformation signal was detected starting in May 2008, albeit retrospectively. At Kilauea, Hawaii, increases in CO2 emissions from the summit (up to nearly 25 kt/d, over three times the background emission) were measured mid-2004, roughly coincident with a change in deformation behavior from deflation to inflation. Nearly 3 years later, a change in eruptive activity occurred

  6. Net greenhouse gas emissions at Eastmain-1 reservoir, Quebec, Canada

    Energy Technology Data Exchange (ETDEWEB)

    Tremblay, Alain; Bastien, Julie; Bonneville, Marie-Claude; del Giorgio, Paul; Demarty, Maud; Garneau, Michelle; Helie, Jean-Francois; Pelletier, Luc; Prairie, Yves; Roulet, Nigel; Strachan, Ian; Teodoru, Cristian

    2010-09-15

    The growing concern regarding the long-term contribution of freshwater reservoirs to atmospheric greenhouse gases (GHG), led Hydro-Quebec, to study net GHG emissions from Eastmain 1 reservoir, which are the emissions related to the creation of a reservoir minus those that would have been emitted or absorbed by the natural systems over a 100-year period. This large study was realized in collaboration with University du Quebec a Montreal, McGill University and Environnement IIlimite Inc. This is a world premiere and the net GHG emissions of EM-1 will be presented in details.

  7. National inventory report. Greenhouse gas emissions 1990-2010

    Energy Technology Data Exchange (ETDEWEB)

    Kolshus, Hans H.; Gjerald, Eilev; Hoem, Britta; Ramberg, Simen Helgesen; Haugland, Hege; Valved, Hilde; Nelson, George Nicholas; Asphjell, Torgrim; Christophersen, Oeyvind; Gaustad, Alice; Rubaek, Birgitte; Hvalryg, Marte Monsen

    2012-07-01

    Emissions of the following greenhouse gases are covered in this report: carbon dioxide (CO{sub 2}), methane (CH{sub 4}), nitrous oxide (N{sub 2}O), perfluoro carbons (PFCs), hydro fluorocarbons (HFCs) and sulphur hexafluoride (SF{sub 6}). In addition, the inventory includes calculations of emissions of the precursors NO{sub x}, NMVOC, and CO, as well as for SO{sub 2}. Indirect CO{sub 2} emissions originating from the fossil part of CH{sub 4} and NMVOC are calculated according to the reporting guidelines to the UNFCCC, and accounted for in the inventory.(eb)

  8. National inventory report. Greenhouse gas emissions 1990-2009

    Energy Technology Data Exchange (ETDEWEB)

    2011-05-15

    Emissions of the following greenhouse gases are covered in this report: carbon dioxide (CO{sub 2}), methane (CH{sub 4}), nitrous oxide (N{sub 2}O), perfluoro carbons (PFCs), hydro fluorocarbons (HFCs) and sulphur hexafluoride (SF{sub 6}). In addition, the inventory includes calculations of emissions of the precursors NO{sub x}, NMVOC, and CO, as well as for SO{sub 2}. Indirect CO{sub 2} emissions originating from the fossil part of CH{sub 4} and NMVOC are calculated according to the reporting guidelines to the UNFCCC, and accounted for in the inventory. (AG)

  9. Circumbinary Gas Accretion onto a Central Binary: Infrared Molecular Hydrogen Emission from GG Tau A

    CERN Document Server

    Beck, Tracy L; Dutrey, Anne; Piétu, Vincent; Guilloteau, Stephane; Lubow, S H; Simon, M

    2012-01-01

    We present high spatial resolution maps of ro-vibrational molecular hydrogen emission from the environment of the GG Tau A binary component in the GG Tau quadruple system. The H2 v= 1-0 S(1) emission is spatially resolved and encompasses the inner binary, with emission detected at locations that should be dynamically cleared on several hundred-year timescales. Extensions of H2 gas emission are seen to ~100 AU distances from the central stars. The v = 2-1 S(1) emission at 2.24 microns is also detected at ~30 AU from the central stars, with a line ratio of 0.05 +/- 0.01 with respect to the v = 1-0 S(1) emission. Assuming gas in LTE, this ratio corresponds to an emission environment at ~1700 K. We estimate that this temperature is too high for quiescent gas heated by X-ray or UV emission from the central stars. Surprisingly, we find that the brightest region of H2 emission arises from a spatial location that is exactly coincident with a recently revealed dust "streamer" which seems to be transferring material fr...

  10. Emission of gas and atmospheric dispersion of SO2 during the December 2013 eruption at San Miguel volcano (El Salvador)

    Science.gov (United States)

    Salerno, Giuseppe G.; Granieri, Domenico; Liuzzo, Marco; La Spina, Alessandro; Giuffrida, Giovanni B.; Caltabiano, Tommaso; Giudice, Gaetano; Gutierrez, Eduardo; Montalvo, Francisco; Burton, Michael; Papale, Paolo

    2016-04-01

    San Miguel volcano, also known as Chaparrastique, is a basaltic volcano along the Central American Volcanic Arc (CAVA). Volcanism is induced by the convergence of the Cocos Plate underneath the Caribbean Plate, along a 1200-km arc, extending from Guatemala to Costa Rica and parallel to the Central American Trench. The volcano is located in the eastern part of El Salvador, in proximity to the large communities of San Miguel, San Rafael Oriente, and San Jorge. Approximately 70,000 residents, mostly farmers, live around the crater and the city of San Miguel, the second largest city of El Salvador, ten km from the summit, has a population of ~180,000 inhabitants. The Pan-American and Coastal highways cross the north and south flanks of the volcano.San Miguel volcano has produced modest eruptions, with at least 28 VEI 1-2 events between 1699 and 1967 (datafrom Smithsonian Institution http://www.volcano.si.edu/volcano.cfm?vn=343100). It is characterized by visible milddegassing from a summit vent and fumarole field, and by intermittent lava flows and Strombolian activity. Since the last vigorous fire fountaining of 1976, San Miguel has only experienced small steam explosions and gas emissions, minor ash fall and rock avalanches. On 29 December 2013 the volcano erupted producing an eruption that has been classified as VEI 2. While eruptions tend to be low-VEI, the presence of major routes and the dense population in the surrounding of the volcano increases the risk that weak explosions with gas and/or ash emission may pose. In this study, we present the first inventory of SO2, CO2, HCl, and HF emission rates on San Miguel volcano, and an analysis of the hazard from volcanogenic SO2 discharged before, during, and after the December 2013 eruption. SO2 was chosen as it is amongst the most critical volcanogenic pollutants, which may cause acute and chronicle disease to humans. Data were gathered by the geochemical monitoring network managed by the Ministerio de Medio Ambiente

  11. Effect of Background Emissivity on Gas Detection in Thermal Hyperspectral Imagery

    Energy Technology Data Exchange (ETDEWEB)

    Walsh, Stephen J.; Tardiff, Mark F.; Chilton, Lawrence K.; Metoyer, Candace N.

    2008-10-02

    Detecting and identifying weak gaseous plumes using thermal imaging data is complicated by many factors. These include variability due to atmosphere, ground and plume temper- ature, and background clutter. This paper presents an analysis of one formulation of the physics-based radiance model, which describes at-sensor observed radiance. The background emissivity and plume/ground temperatures are isolated, and their effects on net chemical signal are described. This analysis shows that the plume’s physical state, emission or absorption, is directly dependent on the background emissivity. It then describes what conditions on the background emissivity have inhibiting effects on the net chemical signal. These claims are illustrated by analyzing synthetic hyperspectral imaging data with the Adaptive Matched Filter using four chemicals and three distinct background emissivities. Two chemicals (Carbontetrachloride and Tetraflourosilane) in the analysis had a very strong relationship with the background emissivities: they exhibited absorbance over a small range of wavenumbers and the background emissivities showed a consistent ordering at these wavenumbers. Analysis of simulated hyperspectral images containing these chemicals showed complete agreement with the analysis of the physics-based model that described when the background emissivities would have inhibiting effects on gas detection. The other chemicals considered (Ammonia and Tributylphosphate) exhibited very complex absorbance structure across the longwave infrared spectrum. Analysis of images containing these chemicals revealed that the the analysis of the physics-based model did not hold completely for these complex chemicals but did suggest that gas detection was dominated by their dominant absorbance features. These results provide some explanation of the effect of the background emissivity on gas detection and a more general exploration of gas absorbance/background emissivity variability and their effects on

  12. Projection of greenhouse gas emissions 2009 to 2030

    Energy Technology Data Exchange (ETDEWEB)

    Nielsen, Ole-Kenneth; Winther, M.; Hjorth Mikkelsen, M.; Gyldenkaerne, S.; Lyck, E.; Plejdrup, M.; Hoffmann, L.; Thomsen, M.; Hjelgaard, K.; Fauser, P.

    2010-09-15

    This report contains a description of models, background data and projections of CO{sub 2}, CH{sub 4}, N{sub 2}O, HFCs, PFCs and SF{sub 6} for Denmark. The emissions are projected to 2030 using basic scenarios together with the expected results of a few individual policy measures. Official Danish forecasts of activity rates are used in the models for those sectors for which the forecasts are available, i.e. the latest official forecast from the Danish Energy Agency. The emission factors refer to international guidelines and some are country-specific and refer to Danish legislation, Danish research reports or calculations based on emission data from a considerable number of plants. The projection models are based on the same structure and method as the Danish emission inventories in order to ensure consistency. (Author)

  13. Projection of greenhouse gas emissions 2007 to 2025

    Energy Technology Data Exchange (ETDEWEB)

    Nielsen, Ole-Kenneth; Winther, M.; Hjorth Mikkelsen, M.; Gyldenkaerne, S.; Lyck, E.; Plejdrup, M.; Hoffmann, L.; Thomsen, Marianne; Fauser, P.

    2009-02-15

    This report contains a description of models and background data for projection of CO{sub 2}, CH{sub 4}, N{sub 2}O, HFCs, PFCs and SF{sub 6} for Denmark. The emissions are projected to 2025 using basic scenarios together with the expected results of a few individual policy measures. Official Danish forecasts of activity rates are used in the models for those sectors for which the forecasts are available, i.e. the latest official forecast from the Danish Energy Agency. The emission factors refer to international guidelines and some are country-specific and refer to Danish legislation, Danish research reports or calculations based on emission data from a considerable number of plants. The projection models are based on the same structure and method as the Danish emission inventories in order to ensure consistency. (au)

  14. Greenhouse gas (N2O emission from Portuguese estuaries

    Directory of Open Access Journals (Sweden)

    Célia Gonçalves

    2014-07-01

    Tagus, Minho and Lima estuaries are source of N2O to the atmosphere. Particularly, in Lima estuary anthropogenic N input seems to play an important role on N2O emission. However, in a global perspective N2O attained emissions represent a reduced fraction (2O yr-1, Barnes and Upstill-Goddard, 2011. Values are comparable with those registered in some Portuguese estuaries and other European less eutrophic estuaries. However, it is known that higher N2O emissions in estuaries may occur during winter and spring (Sun et al., 2014. Thus, these systems may represent on an annual basis a larger source of N2O, which can only be clarified in future studies. Only a full comprehension of the global estuarine nitrogen cycle will provide an efficient basis of scientific knowledge for sustainably management of such ecosystems and ultimately reduce N2O emissions.

  15. Effect of Environmental Factors on Sulfur Gas Emissions from Drywall

    Energy Technology Data Exchange (ETDEWEB)

    Maddalena, Randy

    2011-08-20

    Problem drywall installed in U.S. homes is suspected of being a source of odorous and potentially corrosive indoor pollutants. The U.S. Consumer Product Safety Commission's (CPSC) investigation of problem drywall incorporates three parallel tracks: (1) evaluating the relationship between the drywall and reported health symptoms; (2) evaluating the relationship between the drywall and electrical and fire safety issues in affected homes; and (3) tracing the origin and the distribution of the drywall. To assess the potential impact on human health and to support testing for electrical and fire safety, the CPSC has initiated a series of laboratory tests that provide elemental characterization of drywall, characterization of chemical emissions, and in-home air sampling. The chemical emission testing was conducted at Lawrence Berkeley National Laboratory (LBNL). The LBNL study consisted of two phases. In Phase 1 of this study, LBNL tested thirty drywall samples provided by CPSC and reported standard emission factors for volatile organic compounds (VOCs), aldehydes, reactive sulfur gases (RSGs) and volatile sulfur compounds (VSCs). The standard emission factors were determined using small (10.75 liter) dynamic test chambers housed in a constant temperature environmental chamber. The tests were all run at 25 C, 50% relative humidity (RH) and with an area-specific ventilation rate of {approx}1.5 cubic meters per square meter of emitting surface per hour [m{sup 3}/m{sup 2}/h]. The thirty samples that were tested in Phase 1 included seventeen that were manufactured in China in 2005, 2006 and 2009, and thirteen that were manufactured in North America in 2009. The measured emission factors for VOCs and aldehydes were generally low and did not differ significantly between the Chinese and North American drywall. Eight of the samples tested had elevated emissions of volatile sulfur-containing compounds with total RSG emission factors between 32 and 258 micrograms per square

  16. Projection of greenhouse gas emissions 2010 to 2030

    Energy Technology Data Exchange (ETDEWEB)

    Nielsen, Ole-Kenneth; Winther, M.; Nielsen, Malene; Hjorth Mikkelsen, M.; Albrektsen, R.; Gyldenkaerne, S.; Plejdrup, M.; Hoffmann, L.; Thomsen, M.; Hjelgaard, K.; Fauser, P.

    2011-09-15

    This report contains a description of models, background data and projections of CO{sub 2}, CH{sub 4}, N{sub 2}O, HFCs, PFCs and SF{sub 6} for Denmark. The emissions are projected to 2030 using a scenario together with the expected results of a few individual policy measures. Official Danish forecasts of activity rates are used in the models for those sectors for which the forecasts are available, i.e. the latest official forecast from the Danish Energy Agency. The emission factors refer to international guidelines and some are country-specific and refer to Danish legislation, Danish research reports or calculations based on emission data from a considerable number of industrial plants. The projection models are based on the same structure and method as the Danish emission inventories in order to ensure consistency. (Author)

  17. Greenhouse gas emissions from Brazil’s Amazonian hydroelectric dams

    Science.gov (United States)

    Fearnside, Philip M.

    2016-01-01

    Tropical dams are often falsely portrayed as ‘clean’ emissions-free energy sources. The letter by de Faria et al (2015 Environ. Res. Lett. 10 124019) adds to evidence questioning this myth. Calculations are made for 18 dams that are planned or under construction in Brazilian Amazonia and show that emissions from storage hydroelectric dams would exceed those from electricity generation based on fossil fuels. Fossil fuels need not be the alternative, because Brazil has vast potential for wind and solar power as well as opportunities for energy conservation. Because dam-building is rapidly shifting to humid tropical areas, where emissions are higher than in other climatic zones, the impact of these emissions needs to be given proper weight in energy-policy decisions.

  18. National Greenhouse Gas Emission Inventory (EV-GHG)

    Data.gov (United States)

    U.S. Environmental Protection Agency — The EV-GHG Mobile Source Data asset contains measured mobile source GHG emissions summary compliance information on light-duty vehicles, by model, for certification...

  19. Projection of greenhouse gas emissions - 2005 to 2030

    Energy Technology Data Exchange (ETDEWEB)

    Illerup, J.B.; Nielsen, Ole-Kenneth; Winther, Morten; Hjort Mikekkelsen, M.; Lyck, E.; Nielsen, Malene; Hoffmann, L.; Gyldenkaerne, S.; Thomsen, Marianne [DMU-AU, Dept. of Policy Analysis (Denmark)

    2007-01-15

    This report contains a description of models and background data for projection of CO{sub 2}, CH{sub 4}, N{sub 2}O, HFCs, PFCs and SF{sub 6} for Denmark. The emissions are projected to 2030 using basic scenarios together with the expected results of a few individual policy measures. Official Danish forecasts of activity rates are used in the models for those sectors for which the forecasts are available, i.e. the latest official forecast from the Danish Energy Authority. The emission factors refer to international guidelines and some are country-specific and refer to Danish legislation, Danish research reports or calculations based on emission data from a considerable number of plants. The projection models are based on the same structure and method as the Danish emission inventories in order to ensure consistency. (au)

  20. FIRST CONNECTION BETWEEN COLD GAS IN EMISSION AND ABSORPTION: CO EMISSION FROM A GALAXY–QUASAR PAIR

    Energy Technology Data Exchange (ETDEWEB)

    Neeleman, Marcel; Prochaska, J. Xavier [Department of Astronomy and Astrophysics, UCO/Lick Observatory, University of California, 1156 High Street, Santa Cruz, CA 95064 (United States); Zwaan, Martin A.; Kampen, Eelco van; Møller, Palle [European Southern Observatory, Karl-Schwarzschild-strasse 2, D-85748 Garching bei München (Germany); Kanekar, Nissim [National Centre for Radio Astrophysics, Tata Institute of Fundamental Research, Pune 411007 (India); Christensen, Lise; Fynbo, Johan P. U. [Dark Cosmology Centre, Niels Bohr Institute, University of Copenhagen, Juliane Maries Vej 30, DK-2100 Copenhagen (Denmark); Dessauges-Zavadsky, Miroslava [Observatoire de Genève, Université de Genève, 51 Ch. des Maillettes, 1290 Sauverny (Switzerland); Zafar, Tayyaba, E-mail: marcel@ucsc.edu [Australian Astronomical Observatory, P.O. Box 915, North Ryde, NSW 1670 (Australia)

    2016-04-01

    We present the first detection of molecular emission from a galaxy selected to be near a projected background quasar using the Atacama Large Millimeter/submillimeter Array (ALMA). The ALMA detection of CO(1−0) emission from the z = 0.101 galaxy toward quasar PKS 0439–433 is coincident with its stellar disk and yields a molecular gas mass of M{sub mol} ≈ 4.2 × 10{sup 9} M{sub ⊙} (for a Galactic CO-to-H{sub 2} conversion factor), larger than the upper limit on its atomic gas mass. We resolve the CO velocity field, obtaining a rotational velocity of 134 ± 11 km s{sup −1} and a resultant dynamical mass of ≥4 × 10{sup 10} M{sub ⊙}. Despite its high metallicity and large molecular mass, the z = 0.101 galaxy has a low star formation rate, implying a large gas consumption timescale, larger than that typical of late-type galaxies. Most of the molecular gas is hence likely to be in a diffuse extended phase, rather than in dense molecular clouds. By combining the results of emission and absorption studies, we find that the strongest molecular absorption component toward the quasar cannot arise from the molecular disk, but is likely to arise from diffuse gas in the galaxy’s circumgalactic medium. Our results emphasize the potential of combining molecular and stellar emission line studies with optical absorption line studies to achieve a more complete picture of the gas within and surrounding high-redshift galaxies.

  1. Greenhouse Gas Emissions from Excavation on Residential Construction Sites

    OpenAIRE

    Perry Forsythe; Grace Ding

    2014-01-01

    Despite considerable research concerning the manifestation of greenhouse gases in the usage of buildings, little has been done concerning emissions arising from the construction process itself. This paper specifically examines emissions arising from cut and fill excavation on residential construction sites. Even though such excavation is often seen as being economical in terms of providing a flat base for concrete raft slab construction, the environmental consequences of this approach need to...

  2. Sensitivity of detection of fugitive methane emissions from coal seam gas fields

    Science.gov (United States)

    Feitz, A. J.; Berko, H.; Wilson, P.; Jenkins, C.; Loh, Z. M.; Etheridge, D.

    2013-12-01

    There is increasing recognition that minimising methane emissions from the oil and gas sector is a key step in reducing global greenhouse gas emissions in the near term. Atmospheric monitoring techniques are likely to play an important future role in measuring the extent of existing emissions and verifying emission reductions. They can be very suitable for monitoring gas fields as they are continuous and integrate emissions from a number of potential point and diffuse sources that may vary in time. Geoscience Australia and CSIRO Marine & Atmospheric Research have collected three years of continuous methane and carbon dioxide measurements at their atmospheric composition monitoring station ('Arcturus') in the Bowen Basin, Australia. Methane signals in the Bowen Basin are likely to be influenced by cattle production, landfill, coal production, and conventional and coal seam gas (CSG) production. Australian CSG is typically 'dry' and is characterised by a mixed thermogenic-biogenic methane source with an absence of C3-C6+ alkanes. The range of δ13C isotopic signatures of the CSG is similar to methane from landfill gas and cattle emissions. The absence of standard in-situ tracers for CSG fugitive emissions suggests that having a comprehensive baseline will be critical for successful measurement of fugitive emissions using atmospheric techniques. In this paper we report on the sensitivity of atmospheric techniques for the detection of fugitive emissions from a simulated new CSG field against a three year baseline signal. Simulation of emissions was performed for a 1-year period using the coupled prognostic meteorological and air pollution model TAPM at different fugitive emission rates (i.e. estimates of <1% to up to 10% of production lost) and distances (i.e. 10 - 50 km) from the station. Emissions from the simulated CSG field are based on well density, production volumes, and field size typical of CSG fields in Australia. The distributions of the perturbed and

  3. Optical sensors of gas on the basis of semiconductor sources of infrared emission

    Directory of Open Access Journals (Sweden)

    Kabatsiy V. N.

    2008-08-01

    Full Text Available Various constructions of optic sensors of gas and gas analyzers on their basis with the use of low-powered semiconductor sources of infrared emission for wave-length of 2,5–5,0 mm made on basis of InGaAs/InAs and InAsSbP/InAs heterostructures are worked out. The experimental results demonstrating the ability of application of semiconductor sources of infrared emission in optic sensors for measuring of metan concentration (CH4 and carbon dioxide (CO2 are given. The availability of use of such sensors in the gas analysis equipment of new generation is shown.

  4. Tropical deforestation as a source of greenhouse gas emissions

    Energy Technology Data Exchange (ETDEWEB)

    Houghton, R.A. [The Woods Hole Research Center, Woods Hole, MA (United States)

    2005-07-01

    Tropical deforestation, including both the permanent conversion of forests to croplands and pastures and the temporary or partial removal of forests for shifting cultivation and selective logging, is estimated to have released on the order of 1-2 PgC/yr (15-35% of annual fossil fuel emissions) during the 1990s. The magnitude of emissions depends on the rates of deforestation, the biomass of the forests deforested, and other reductions in biomass that result from forest use. If, in addition to carbon dioxide, one considers the emissions of methane, nitrous oxide, and other chemically reactive gases that result from deforestation and subsequent uses of the land, annual emissions during the 1990s accounted for about 25% of the total anthropogenic emissions of greenhouse gases. Trends in the rates of tropical deforestation are difficult to predict, but at today's rates, another 85 to 130 PgC will be released over the next 100 years, the emissions declining only as tropical forests are eliminated.

  5. Greenhouse Gas Emissions from Educational Facilities and the EPA Greenhouse Gas Reporting Rule: Actions You Need to Take Now

    Science.gov (United States)

    Wurmbrand, Mitchell M.; Klotz, Thomas C.

    2010-01-01

    On September 22, 2009, The United States Environmental Protection Agency (EPA) issued its final rule on greenhouse gas (GHG) emission reporting. The informational literature that EPA has published to support the rule clearly states that EPA believes the vast majority of smaller GHG-emitting facilities, such as educational facilities, will not be…

  6. Greenhouse gas emissions from alternative futures of deforestation and agricultural management in the southern Amazon.

    Science.gov (United States)

    Galford, Gillian L; Melillo, Jerry M; Kicklighter, David W; Cronin, Timothy W; Cerri, Carlos E P; Mustard, John F; Cerri, Carlos C

    2010-11-16

    The Brazilian Amazon is one of the most rapidly developing agricultural areas in the world and represents a potentially large future source of greenhouse gases from land clearing and subsequent agricultural management. In an integrated approach, we estimate the greenhouse gas dynamics of natural ecosystems and agricultural ecosystems after clearing in the context of a future climate. We examine scenarios of deforestation and postclearing land use to estimate the future (2006-2050) impacts on carbon dioxide (CO(2)), methane (CH(4)), and nitrous oxide (N(2)O) emissions from the agricultural frontier state of Mato Grosso, using a process-based biogeochemistry model, the Terrestrial Ecosystems Model (TEM). We estimate a net emission of greenhouse gases from Mato Grosso, ranging from 2.8 to 15.9 Pg CO(2)-equivalents (CO(2)-e) from 2006 to 2050. Deforestation is the largest source of greenhouse gas emissions over this period, but land uses following clearing account for a substantial portion (24-49%) of the net greenhouse gas budget. Due to land-cover and land-use change, there is a small foregone carbon sequestration of 0.2-0.4 Pg CO(2)-e by natural forests and cerrado between 2006 and 2050. Both deforestation and future land-use management play important roles in the net greenhouse gas emissions of this frontier, suggesting that both should be considered in emissions policies. We find that avoided deforestation remains the best strategy for minimizing future greenhouse gas emissions from Mato Grosso.

  7. Characterization factors for water consumption and greenhouse gas emissions based on freshwater fish species extinction.

    Science.gov (United States)

    Hanafiah, Marlia M; Xenopoulos, Marguerite A; Pfister, Stephan; Leuven, Rob S E W; Huijbregts, Mark A J

    2011-06-15

    Human-induced changes in water consumption and global warming are likely to reduce the species richness of freshwater ecosystems. So far, these impacts have not been addressed in the context of life cycle assessment (LCA). Here, we derived characterization factors for water consumption and global warming based on freshwater fish species loss. Calculation of characterization factors for potential freshwater fish losses from water consumption were estimated using a generic species-river discharge curve for 214 global river basins. We also derived characterization factors for potential freshwater fish species losses per unit of greenhouse gas emission. Based on five global climate scenarios, characterization factors for 63 greenhouse gas emissions were calculated. Depending on the river considered, characterization factors for water consumption can differ up to 3 orders of magnitude. Characterization factors for greenhouse gas emissions can vary up to 5 orders of magnitude, depending on the atmospheric residence time and radiative forcing efficiency of greenhouse gas emissions. An emission of 1 ton of CO₂ is expected to cause the same impact on potential fish species disappearance as the water consumption of 10-1000 m³, depending on the river basin considered. Our results make it possible to compare the impact of water consumption with greenhouse gas emissions.

  8. Greenhouse gas emissions in Sub-Saharan Africa

    Energy Technology Data Exchange (ETDEWEB)

    Graham, R.L.; Perlack, R.D.; Prasad, A.M.G.; Ranney, J.W.; Waddle, D.B.

    1990-11-01

    Current and future carbon emissions from land-use change and energy consumption were analyzed for Sub-Saharan Africa. The energy sector analysis was based on UN energy data tapes while the land-use analysis was based on a spatially-explicit land-use model developed specifically for this project. The impacts of different energy and land-use strategies on future carbon emissions were considered. (A review of anthropogenic emissions of methane, nitrous oxides, and chlorofluorocarbons in Sub-Saharan Africa indicated that they were probably minor in both a global and a regional context. The study therefore was focused on emissions of carbon dioxide.) The land-use model predicts carbon emissions from land use change and the amount of carbon stored in vegetation (carbon inventory) on a yearly basis between 1985 and 2001. Emissions and inventory are modeled at 9000 regularly-spaced point locations in Sub-Saharan Africa using location-specific information on vegetation type, soils, climate and deforestation. Vegetation, soils, and climate information were derived from continental-scale maps while relative deforestation rates(% of forest land lost each year) were developed from country-specific forest and deforestation statistics (FAO Tropical Forest Resources Assessment for Africa, 1980). The carbon emissions under different land use strategies in Sub-Saharan Africa were analyzed by modifying deforestation rates and altering the amount of carbon stored under different land uses. The considered strategies were: preservation of existing forests, implementation of agroforestry, and establishment of industrial tree plantations. 82 refs., 16 figs., 25 tabs.

  9. Emissions of Transport Refrigeration Units with CARB Diesel, Gas-to-Liquid Diesel, and Emissions Control Devices

    Energy Technology Data Exchange (ETDEWEB)

    Barnitt, R. A.; Chernich, D.; Burnitzki, M.; Oshinuga, A.; Miyasato, M.; Lucht, E.; van der Merwe, D.; Schaberg, P.

    2010-05-01

    A novel in situ method was used to measure emissions and fuel consumption of transport refrigeration units (TRUs). The test matrix included two fuels, two exhaust configurations, and two TRU engine operating speeds. Test fuels were California ultra low sulfur diesel and gas-to-liquid (GTL) diesel. Exhaust configurations were a stock muffler and a Thermo King pDPF diesel particulate filter. The TRU engine operating speeds were high and low, controlled by the TRU user interface. Results indicate that GTL diesel fuel reduces all regulated emissions at high and low engine speeds. Application of a Thermo King pDPF reduced regulated emissions, sometimes almost entirely. The application of both GTL diesel and a Thermo King pDPF reduced regulated emissions at high engine speed, but showed an increase in oxides of nitrogen at low engine speed.

  10. Reduction of CO2 emissions from road transport in cities impact of dynamic route guidance system on greenhouse gas emission

    CERN Document Server

    Markiewicz, Michal

    2017-01-01

    Michal Markiewicz presents the outcomes of his research regarding the influence of dynamic route guidance system on overall emission of carbon dioxide from road transport in rural areas. Sustainable transportation in smart cities is a big challenge of our time, but before electric vehicles replace vehicles that burn fossil fuels we have to think about traffic optimization methods that reduce the amount of greenhouse gas emissions. Contents Comparison of Travel Time Measurements Using Floating Car Data and Intelligent Infrastructure Integration of Cellular Automata Traffic Simulator with CO2 Emission Model Impact of Dynamic Route Guidance System on CO2 Emission Naxos Vehicular Traffic Simulator Target Groups Lecturers and students of computer science, transportation and logistics Traffic engineers The Author Dr. Michal Markiewicz defended his PhD thesis in computer science at the University of Bremen,TZI Technologie-Zentrum Informatik und Informationstechnik, Germany. Currently, he is working on commercializat...

  11. Characteristics of Greenhouse Gas Emissions from the Wheat Fields with Different Returning Methods of Maize Straws

    Directory of Open Access Journals (Sweden)

    LI Xin-hua

    2016-03-01

    Full Text Available In order to investigate the effect of different returning methods of maize straw on the greenhouse gas emissions from the wheat fields, we explored the greenhouse gas CO2, N2O and CH4 emissions from the wheat fields using static chamber-gas chromatograph technique from December 2013 to May 2014. The experiments set four treatments including no maize straw returning(CK, direct maize straw returning directly(CS, maize straw-rumen-cattle dung returning(CGS and maize straw-mushroom residue returning(CMS, and the four treatments were investigated under the same watering and fertilizing conditions. The results showed that the greenhouse gas emissions from the wheat fields all had distinct seasonal variations and the cumulative emissions of greenhouse gas emissions were different. During the maize growing season, the cumulative emissions of both CO2 and N2O were emitted and in the order of CK >CGS >CS >CMS while the cumulative absorptions of CH4 were in the order of CS >CGS >CK >CMS with the significant difference between different treatments(PCGS >CK >CMS under the different returning methods of maize straw, which indicated that direct straw returning could significantly increase the global warming potential of greenhouse gases from the wheat field, followed by CGS while the straw-mushroom residue returning(CMS could decrease the global warming potential of greenhouse gases from the wheat field. The method of straw-mushroom residue returning should be recommended from the viewpoint of reducing GWP of the greenhouse gas. In all, our study could provide the scientific foundation for the efficiency straw recycle and reducing greenhouse gas emission.

  12. Measurements and modeling to quantify emissions of methane and VOCs from shale gas operations: Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Presto, Albert A [Carnegie Mellon Univ., Pittsburgh, PA (United States)

    2017-06-30

    The objectives of the project were to determine the leakage rates of methane and ozone-forming Volatile Organic Compounds (VOCs) and the emission rates of air toxics from Marcellus shale gas activities. Methane emissions in the Marcellus Shale region were differentiated between “newer” sources associated with shale gas development and “older” sources associated with coal or conventional natural gas exploration. This project conducted measurements of methane and VOC emissions from both shale and non-shale natural gas resources. The initial scope of the project was the Marcellus Shale basin, and measurements were conducted in both the western wet gas regions (southwest PA and WV) and eastern dry gas region (northeast PA) of the basin. During this project, we obtained additional funding from other agencies to expand the scope of measurements to include additional basins. The data from both the Marcellus and other basins were combined to construct a national analysis of methane emissions from oil & gas production activities.

  13. [Study on greenhouse gas emissions from urban waste disposal system: a case study in Xiamen].

    Science.gov (United States)

    Yu, Yang; Cui, Sheng-Hui; Lin, Jian-Yi; Li, Fei

    2012-09-01

    Waste disposal is one of the sources of greenhouse gas (GHG) emissions from urban human activities. According to the method recommended by IPCC Guidelines for National Greenhouse Gas Inventories 2006, a calculation model was established to assess GHG emissions of waste disposal in Xiamen. Then GHG emissions from waste disposal in Xiamen during the year of 2005-2010 were estimated, including solid waste landfill, solid waste incineration and wastewater treatment. The results showed that total GHG emissions quantified in carbon dioxide equivalents (CO2e) from waste disposal was 406.3 kt in 2005, and increased to 704.6 kt in 2010. Because of the improvement of wastewater treatment process and rapid increasing municipal solid waste (MSW), the main source of emissions was from wastewater treatment turning to solid waste landfill. GHG emissions from solid waste landfill accounted for about 90% of total emissions from solid waste disposal process in 2005, and the proportion decreased to 75% in 2010. GHG emissions (quantified in CO2e) from waste water treatment reached the highest value 325.5 kt in 2007. Chemical raw materials and chemical industry have been the highest CH4 emission industry during 2005-2010, which accounted for more than 55% of total CH4 emission from industrial wastewater treatment.

  14. International markets for greenhouse gas emission reduction policies - possibilities for integrating developing countries

    DEFF Research Database (Denmark)

    Halsnæs, K.; Olhoff, A.

    2005-01-01

    Greenhouse gas (GHG) emissions are affecting a global common: the climate, and as a global environmental problem with a public good character it provides attractive opportunities for minimising control costs through the use of emission trading markets. This paper introduces cost and benefit princ...... principles that can be applied to the assessment of global markets for GHG emission reduction options and evaluates the scope for and the potential economic gains of such markets.......Greenhouse gas (GHG) emissions are affecting a global common: the climate, and as a global environmental problem with a public good character it provides attractive opportunities for minimising control costs through the use of emission trading markets. This paper introduces cost and benefit...

  15. Plant-integrated measurement of greenhouse gas emissions from a municipal wastewater treatment plant

    DEFF Research Database (Denmark)

    Yoshida, Hiroko; Mønster, Jacob; Scheutz, Charlotte

    2014-01-01

    Wastewater treatment plants (WWTPs) contribute to anthropogenic greenhouse gas (GHG) emissions. Due to its spatial and temporal variation in emissions, whole plant characterization of GHG emissions from WWTPs face a number of obstacles. In this study, a tracer dispersion method was applied...... to quantify plant-integrated, real-time emissions of methane and nitrous oxides. Two mobile cavity ring-down spectroscopy sampling devices were used to record downwind gas concentrations emitted from a municipal WWTP situated in Copenhagen, Denmark. This plant is equipped to remove biological nitrogen...... in the plant. As high as 4.27% of nitrogen entering the WWTP was emitted as nitrous oxide under the sub-optimal operation of biological treatment processes. The study shows that the unit process configuration, as well as the operation of the WWTP, determines the rate of GHG emission. The applied plant...

  16. First Connection between Cold Gas in Emission and Absorption: CO Emission from a Galaxy-Quasar Pair

    CERN Document Server

    Neeleman, M; Zwaan, M A; Kanekar, N; Christensen, L; Dessauges-Zavadsky, M; Fynbo, J P U; van Kampen, E; Møller, P; Zafar, T

    2016-01-01

    We present the first detection of molecular emission from a galaxy selected to be near a projected background quasar using the Atacama Large Millimeter/submillimeter Array (ALMA). The ALMA detection of CO(1$-$0) emission from the $z=0.101$ galaxy toward quasar PKS 0439-433 is coincident with its stellar disk and yields a molecular gas mass of $M_{\\rm mol} \\approx 4.2 \\times 10^9 M_\\odot$ (for a Galactic CO-to-H$_2$ conversion factor), larger than the upper limit on its atomic gas mass. We resolve the CO velocity field, obtaining a rotational velocity of $134 \\pm 11$ km s$^{-1}$, and a resultant dynamical mass of $\\geq 4 \\times 10^{10} M_\\odot$. Despite its high metallicity and large molecular mass, the $z=0.101$ galaxy has a low star formation rate, implying a large gas consumption timescale, larger than that typical of late-type galaxies. Most of the molecular gas is hence likely to be in a diffuse extended phase, rather than in dense molecular clouds. By combining the results of emission and absorption stud...

  17. Decoupling of greenhouse gas emissions from global agricultural production: 1970-2050.

    Science.gov (United States)

    Bennetzen, Eskild H; Smith, Pete; Porter, John R

    2016-02-01

    Since 1970 global agricultural production has more than doubled; contributing ~1/4 of total anthropogenic greenhouse gas (GHG) burden in 2010. Food production must increase to feed our growing demands, but to address climate change, GHG emissions must decrease. Using an identity approach, we estimate and analyse past trends in GHG emission intensities from global agricultural production and land-use change and project potential future emissions. The novel Kaya-Porter identity framework deconstructs the entity of emissions from a mix of multiple sources of GHGs into attributable elements allowing not only a combined analysis of the total level of all emissions jointly with emissions per unit area and emissions per unit product. It also allows us to examine how a change in emissions from a given source contributes to the change in total emissions over time. We show that agricultural production and GHGs have been steadily decoupled over recent decades. Emissions peaked in 1991 at ~12 Pg CO2 -eq. yr(-1) and have not exceeded this since. Since 1970 GHG emissions per unit product have declined by 39% and 44% for crop- and livestock-production, respectively. Except for the energy-use component of farming, emissions from all sources have increased less than agricultural production. Our projected business-as-usual range suggests that emissions may be further decoupled by 20-55% giving absolute agricultural emissions of 8.2-14.5 Pg CO2 -eq. yr(-1) by 2050, significantly lower than many previous estimates that do not allow for decoupling. Beyond this, several additional costcompetitive mitigation measures could reduce emissions further. However, agricultural GHG emissions can only be reduced to a certain level and a simultaneous focus on other parts of the food-system is necessary to increase food security whilst reducing emissions. The identity approach presented here could be used as a methodological framework for more holistic food systems analysis. © 2015 John Wiley

  18. 77 FR 11533 - Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2010; Notice of Availability and...

    Science.gov (United States)

    2012-02-27

    ... Framework Convention on Climate Change (UNFCCC) reporting guidelines. The Inventory of U.S. Greenhouse Gas... AGENCY Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2010; Notice of Availability and... availability and request for comments. SUMMARY: The Draft Inventory of U.S. Greenhouse Gas Emissions and...

  19. Transportation and Greenhouse Gas Emissions Trading. Final Technical Report

    Energy Technology Data Exchange (ETDEWEB)

    Steve Winkelman; Tim Hargrave; Christine Vanderlan

    1999-10-01

    The authors conclude in this report that an upstream system would ensure complete regulatory coverage of transportation sector emissions in an efficient and feasible manner, and as such represents a key component of a national least-cost GHG emissions abatement strategy. The broad coverage provided by an upstream system recommends this approach over vehicle-maker based approaches, which would not cover emissions from heavy-duty vehicles and the aviation, marine and off-road sub-sectors. The on-road fleet approach unfairly and inefficiently burdens vehicle manufacturers with responsibility for emissions that they cannot control. A new vehicles approach would exclude emissions from vehicles on the road prior to program inception. The hybrid approach faces significant technical and political complications, and it is not clear that the approach would actually change behavior among vehicle makers and users, which is its main purpose. They also note that a trading system would fail to encourage many land use and infrastructure measures that affect VMT growth and GHG emissions. They recommend that this market failure be addressed by complementing the trading system with a program specifically targeting land use- and infrastructure-related activities. A key issue that must be addressed in designing a national GHG control strategy is whether or not it is necessary to guarantee GHG reductions from the transport sector. Neither an upstream system nor a downstream approach would do so, since both would direct capital to the least-cost abatement opportunities wherever they were found. They review two reasons why it may be desirable to force transportation sector reductions: first, that the long-term response to climate change will require reductions in all sectors; and second, the many ancillary benefits associated with transportation-related, and especially VMT-related, emissions reduction activities. If policy makers find it desirable to establish transportation

  20. Transportation and Greenhouse Gas Emissions Trading. Final Technical Report

    Energy Technology Data Exchange (ETDEWEB)

    Steve Winkelman; Tim Hargrave; Christine Vanderlan

    1999-10-01

    The authors conclude in this report that an upstream system would ensure complete regulatory coverage of transportation sector emissions in an efficient and feasible manner, and as such represents a key component of a national least-cost GHG emissions abatement strategy. The broad coverage provided by an upstream system recommends this approach over vehicle-maker based approaches, which would not cover emissions from heavy-duty vehicles and the aviation, marine and off-road sub-sectors. The on-road fleet approach unfairly and inefficiently burdens vehicle manufacturers with responsibility for emissions that they cannot control. A new vehicles approach would exclude emissions from vehicles on the road prior to program inception. The hybrid approach faces significant technical and political complications, and it is not clear that the approach would actually change behavior among vehicle makers and users, which is its main purpose. They also note that a trading system would fail to encourage many land use and infrastructure measures that affect VMT growth and GHG emissions. They recommend that this market failure be addressed by complementing the trading system with a program specifically targeting land use- and infrastructure-related activities. A key issue that must be addressed in designing a national GHG control strategy is whether or not it is necessary to guarantee GHG reductions from the transport sector. Neither an upstream system nor a downstream approach would do so, since both would direct capital to the least-cost abatement opportunities wherever they were found. They review two reasons why it may be desirable to force transportation sector reductions: first, that the long-term response to climate change will require reductions in all sectors; and second, the many ancillary benefits associated with transportation-related, and especially VMT-related, emissions reduction activities. If policy makers find it desirable to establish transportation

  1. EAF Gas Waste Heat Utilization and Discussion of the Energy Conservation and CO2 Emissions Reduction

    Science.gov (United States)

    Yang, Ling-zhi; Zhu, Rong; Ma, Guo-hong

    2016-02-01

    As a large number of energy was taken away by the high temperature furnace gas during the EAF smelting process, a huge economic and environmental benefits would obtained to recycle and utilize. In this paper, the energy of the EAF was analyzed theoretically with the hot metal ratio of 50%. Combined with the utilization of the gas waste heat during the scrap preheating, electricity generation, production of steam and production of coal gas processes, the effect of the energy saving and emission was calculated with comprehensive utilization of the high temperature furnace gas. An optimal scheme for utilization of the waste heat was proposed based on the calculation. The results show that the best way for energy saving and carbon reduction is the production of coal gas, while the optimal scheme for waste heat utilization is combined the production of coal gas with the scrap preheating, which will save 170 kWh/t of energy and decrease 57.88 kg/t of carbon emission. As hot metal ratio in EAF steelmaking is often more than 50%, which will produce more EAF gas waste heat, optimizing EAF gas waste heat utilization will have more obvious effect on energy saving and emission reduction.

  2. Controlling of the gas emissions at high performance longwalls in the German hard coal mining industry

    Energy Technology Data Exchange (ETDEWEB)

    Brandt, J. [Deutsche Montan Technologie GmbH (Germany)

    2001-07-01

    In order to enhance productivity in German hard coal mining the total number of workings was reduced and at the same time the output per working point was increased considerably. The average output per working point rose to more than 10,000 t/d with top values of 18,000 t/d in single places. This was achieved by increasing the advance rate and lengthening the face to 450 m. At high performance faces, especially in seams with medium and high gas content rates, the gas inflow can easily become a safety risk and an obstacle to productivity. This paper gives an abstract about the tested techniques and introduces new approaches to the control of gas emission at high performance faces. Essential measures in the control of gas emission for high performance faces are: - pre-degasification of the working seam; optimization of conventional gas drainage; drilling of long deflected boreholes in the gas emission zone of workings (being currently tested); application of effective drilling techniques for rapid preparation of gas drainage boreholes (percussion drilling); selection of the optimal ventilation layout and; building a partially permeable roadside pack (gas windows). 8 refs., 13 figs.

  3. Comparison of green-house gas emission reductions and landfill gas utilization between a landfill system and an incineration system.

    Science.gov (United States)

    Haibin Han; Jisheng Long; Shude Li; Guangren Qian

    2010-04-01

    Electricity generation and greenhouse gas (GHG) reductions were researched by making comparisons between municipal solid waste (MSW) landfill and incineration systems with three different electricity generation efficiencies - 10%, 21%, and 24.7%. For MSW landfill systems, it is shown that the total electricity generation is 198,747 MWh, and the total GHG emission reduction is 1,386,081 tonne CO( 2) during a 21-year operation period. For incineration systems, the total electricity generation is 611,801 MWh, and the total GHG emission reduction is 1,339,158 tonne CO(2) during a 10-year operation period even if the electricity generation efficiency is only 10%. It is also shown that electricity generation increases quicker than the GHG emission reductions with the increase of electricity generation efficiency. However, incineration systems show great superiority in LFG utilisation and GHG emission reductions.

  4. Steam and gas emission rates from La Soufrière of Guadeloupe (Antilles arc): implications for the magmatic supply degassing during unrest

    Science.gov (United States)

    Allard, Patrick; Aiuppa, Alessandro; Beauducel, François; Calabrese, Sergio; Di Napoli, Rossella; Crispi, Olivier; Gaudin, Damien; Parello, Franceso; Hammouya, Gilbert; Tamburello, Giancarlo

    2015-04-01

    Since its last magmatic eruption in 1530 AD, La Soufrière andesitic volcano in Guadeloupe has displayed intense hydrothermal activity and six phreatic eruptive crises (the last of which, in 1976-1977, with 73000 evacuees). Here we report on the first direct quantification of gas plume emissions from La Soufrière summit vents, which gradually intensified during the past 20 years. Gas fluxes were determined in 2006 then 2012 [1] by measuring the horizontal and vertical distribution of volcanic gas concentrations in the air-diluted plume, the composition of the hot fumarolic fluid at exit (108°C), and scaling to the speed of plume transport (in situ measurements and FLIR imaging). We first demonstrate that all fumarolic vents of La Soufrière are fed by a common H2O-rich (97-98 mol %) fluid end-member, emitted almost unmodified at the most active South Crater while affected by secondary alterations (steam condensation, sulphur scrubbing) at other vents. Daily fluxes in 2012 (200 tons of H2O, 15 tons of CO2, ~4 tons of H2S and 1 ton of HCl) were augmented by a factor ~3 compared to 2006, in agreement with increasing activity. Summit fumarolic degassing contributes most of the bulk volatile and heat budget (8 MW) of the volcano. Isotopic evidences demonstrate that La Soufrière hydrothermal emissions are sustained by continuous heat and gas supply from an andesitic magma reservoir confined at 6-7 km depth. This magmatic supply mixes with abundant groundwater of tropical meteoric origin in the hydrothermal system. Based on petro-geochemical data for the erupted magma(s), we assess that the volcanic gas fluxes in 2012 can be accounted for by the release of free magmatic gas derived from about 1000 m3 per day of the basaltic melt replenishing the reservoir at depth. In terms of mass budget, the current degassing unrest is compatible with enhanced free gas release from that reservoir, without requiring any (actually undetected) magma intrusion. We recommend a regular

  5. Projection of Greenhouse Gas Emissions 2009 to 2030

    DEFF Research Database (Denmark)

    Nielsen, Ole-Kenneth; Winther, Morten; Mikkelsen, Mette Hjorth;

    This report contains a description of models, background data and projections of CO2, CH4, N2O, HFCs, PFCs and SF6 for Denmark. The emissions are projected to 2030 using basic scenarios together with the expected results of a few individual policy measures. Official Danish forecasts of activity...

  6. Projection of greenhouse gas emissions 2007 to 2025

    DEFF Research Database (Denmark)

    Nielsen, Ole-Kenneth; Winther, Morten; Mikkelsen, Mette Hjorth;

    This report contains a description of models and background data for projection of CO2, CH4, N2O, HFCs, PFCs and SF6 for Denmark. The emissions are projected to 2025 using basic scenarios together with the expected results of a few individual policy measures. Official Danish forecasts of activity...

  7. Projection of Greenhouse Gas Emissions 2010 to 2030

    DEFF Research Database (Denmark)

    Nielsen, Ole-Kenneth; Winther, Morten; Nielsen, Malene;

    This report contains a description of models, background data and projections of CO2, CH4, N2O, HFCs, PFCs and SF6 for Denmark. The emissions are projected to 2030 using a scenario combined with the expected results of a few individual policy measures. Official Danish forecasts of activity rates...

  8. Communicating uncertainty in the IPCC's greenhouse gas emissions scenarios

    NARCIS (Netherlands)

    Schenk, Niels J.; Lensink, Sander M.

    2007-01-01

    The issue of climate change required the development of the Special Report on Emission Scenarios (SRES) by the IPCC. The complexity of the subject and the unique science-policy relation resulted in confusion and discussions appeared in popular media like The Economist. This paper reviews scenario li

  9. Greenhouse Gas Emissions from Rubber Industry in Thailand

    NARCIS (Netherlands)

    Jawjit, W.; Kroeze, C.; Rattanapan, S.

    2010-01-01

    Rubber production has been taking place in Thailand for many decades. Thailand is currently the world's largest natural rubber producer. We present emissions of greenhouse gases associated with the production of fresh latex, and three primary rubber products, including concentrated latex, block rubb

  10. Greenhouse Gas Emissions from Rubber Industry in Thailand

    NARCIS (Netherlands)

    Jawjit, W.; Kroeze, C.; Rattanapan, S.

    2010-01-01

    Rubber production has been taking place in Thailand for many decades. Thailand is currently the world's largest natural rubber producer. We present emissions of greenhouse gases associated with the production of fresh latex, and three primary rubber products, including concentrated latex, block

  11. Supplanting ecosystem services provided by scavengers raises greenhouse gas emissions.

    Science.gov (United States)

    Morales-Reyes, Zebensui; Pérez-García, Juan M; Moleón, Marcos; Botella, Francisco; Carrete, Martina; Lazcano, Carolina; Moreno-Opo, Rubén; Margalida, Antoni; Donázar, José A; Sánchez-Zapata, José A

    2015-01-15

    Global warming due to human-induced increments in atmospheric concentrations of greenhouse gases (GHG) is one of the most debated topics among environmentalists and politicians worldwide. In this paper we assess a novel source of GHG emissions emerged following a controversial policy decision. After the outbreak of bovine spongiform encephalopathy in Europe, the sanitary regulation required that livestock carcasses were collected from farms and transformed or destroyed in authorised plants, contradicting not only the obligations of member states to conserve scavenger species but also generating unprecedented GHG emission. However, how much of this emission could be prevented in the return to traditional and natural scenario in which scavengers freely remove livestock carcasses is largely unknown. Here we show that, in Spain (home of 95% of European vultures), supplanting the natural removal of dead extensive livestock by scavengers with carcass collection and transport to intermediate and processing plants meant the emission of 77,344 metric tons of CO2 eq. to the atmosphere per year, in addition to annual payments of ca. $50 million to insurance companies. Thus, replacing the ecosystem services provided by scavengers has not only conservation costs, but also important and unnecessary environmental and economic costs.

  12. Improvement performance and emissions in a diesel engine dual-fueled with natural gas; Tennen gas dual fuel diesel kikan no seino haishutsu gas tokusei no kaizen

    Energy Technology Data Exchange (ETDEWEB)

    Nakayama, S.; Okamoto, T.; Kusaka, J.; Daisho, Y.; Kihara, R.; Saito, T. [Waseda University, Tokyo (Japan)

    1997-10-01

    This paper deals with a study on combustion and emission characteristics of a direct injection diesel engine dual-fueled with natural gas. Dual fueling systems tend to emit high unburned fuel especially at low load, resulting in a decreased thermal efficiency. This is because natural gas-air mixtures are too lean for flame to propagate under low load conditions. Intake charge heating and uncooled EGR are very useful to improve emissions and thermal efficiency at low load. Such favorable effects are supported by NO kinetic simulations. 2 refs., 13 figs.

  13. Black carbon particulate matter emission factors for buoyancy-driven associated gas flares.

    Science.gov (United States)

    McEwen, James D N; Johnson, Matthew R

    2012-03-01