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Sample records for volcanic arc deposits

  1. The Chahnaly low sulfidation epithermal gold deposit, western Makran volcanic arc, southeastern Iran

    Science.gov (United States)

    Sholeh, Ali; Rastad, Ebrahim; Huston, David L.; Gemmell, J. Bruce; Taylor, Ryan D.

    2016-01-01

    The Chahnaly low-sulfidation epithermal Au deposit and nearby Au prospects are located northwest of the intermittently active Bazman stratovolcano on the western end of the Makran volcanic arc, which formed as the result of subduction of the remnant Neo-Tethyan oceanic crust beneath the Lut block. The arc hosts the Siah Jangal epithermal and Kharestan porphyry prospects, near Taftan volcano, as well as the Saindak Cu-Au porphyry deposit and world-class Reko Diq Cu-Au porphyry deposit, near Koh-i-Sultan volcano to the east-northeast in Pakistan. The host rocks for the Chahnaly deposit include early Miocene andesite and andesitic volcaniclastic rocks that are intruded by younger dacitic domes. Unaltered late Miocene dacitic ignimbrites overlie these rocks. Laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) U-Pb zircon geochronology data yield ages between 21.8 and 9.9 Ma for the acidic-intermediate regional volcanism. The most recent volcanic activity of the Bazman stratovolcano involved extrusion of an olivine basalt during Pliocene to Quaternary times. Interpretation of geochemical data indicate that the volcanic rocks are synsubduction and calc-alkaline to subalkaline. The lack of a significant negative Eu anomaly, a listric-shaped rare earth element pattern, and moderate La/Yb ratios of host suites indicate a high water content of the source magma.

  2. Generation of porphyry copper deposits by gas-brine reaction in volcanic arcs

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    Blundy, Jon; Mavrogenes, John; Tattitch, Brian; Sparks, Steve; Gilmer, Amy

    2014-05-01

    Porphyry copper deposits (PCDs) are characterised by a close spatial and temporal association with small, hypabyssal intrusions of silicic magmas in volcanic arcs. PCD formation requires elevated chlorine and water to concentrate copper in magmatic hypersaline liquids (or brines), and elevated sulphur to precipitate copper-rich sulphides. These twin requirements are hard to reconcile with experimental and petrological evidence that voluminous chlorine-rich, hydrous silicic magmas, of the variety favourable to copper enrichment, lack sufficient sulphur to precipitate directly the requisite quantities of sulphides. These features are, however, consistent with observations of active volcanic arcs whereby PCDs can be viewed as roots of dome volcanoes above shallow reservoirs where silicic magmas accumulate over long time spans. During protracted periods of dormancy metal-enriched dense brines accumulate in and above the silicic reservoir through slow, low-pressure degassing. Meanwhile cogenetic volatile-rich mafic magmas and their exsolved, sulphur and CO2-rich fluids accumulate in deeper reservoirs. Periodic destabilisation of these reservoirs leads to short-lived bursts of volcanism liberating sulphurous gases, which react with the shallow-stored brines to form copper-rich sulphides and acidic vapours. We test this hypothesis with a novel set of 'porphyry in a capsule' experiments designed to simulate low-pressure (1-2 kbar) interaction of basalt-derived, sulphur-rich gases with brine-saturated, copper-bearing, but sulphur-free, granite. Experiments were run at 720-850 ° C in cold-seal apparatus with basaltic andesite, loaded with H2O and S, situated below dacite, loaded with H2O, Cl and Cu. At run conditions both compositions are substantially degassed and crystallized. S-rich gas from the basaltic andesite ascends to react with Cu-rich brines exsolved from the dacite, Our experiments reveal the direct precipitation of copper-sulphide minerals, in vugs and veins

  3. Generation of porphyry copper deposits by gas-brine reaction in volcanic arcs

    Science.gov (United States)

    Blundy, J.; Mavrogenes, J.; Tattitch, B.; Sparks, S.; Gilmer, A.

    2015-03-01

    Porphyry copper deposits, that is, copper ore associated with hydrothermal fluids rising from a magma chamber, supply 75% of the world's copper. They are typically associated with intrusions of magma in the crust above subduction zones, indicating a primary role for magmatism in driving mineralization. However, it is not clear that a single, copper-rich magmatic fluid could trigger both copper enrichment and the subsequent precipitation of sulphide ore minerals within a zone of hydrothermally altered rock. Here we draw on observations of modern subduction zone volcanism to propose an alternative process for porphyry copper formation. We suggest that copper enrichment initially involves metalliferous, magmatic hyper-saline liquids, or brines, that exsolve from large, magmatic intrusions assembled in the shallow crust over tens to hundreds of thousands of years. In a subsequent step, sulphide ore precipitation is triggered by the interaction of the accumulated brines with sulphur-rich gases, liberated in short-lived bursts from the underlying mafic magmas. We use high-temperature and high-pressure laboratory experiments to simulate such gas-brine interactions. The experiments yield copper-iron sulphide minerals and hydrogen chloride gas at magmatic temperatures of 700-800 °C, with textural and chemical characteristics that resemble those in porphyry copper deposits. We therefore conclude that porphyry copper ore forms in a two-stage process of brine enrichment followed by gas-induced precipitation.

  4. Remelting of Neoproterozoic relict volcanic arcs in the Middle Jurassic: Implication for the formation of the Dexing porphyry copper deposit, Southeastern China

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    Liu, Xuan; Fan, Hong-Rui; Santosh, M.; Hu, Fang-Fang; Yang, Kui-Feng; Li, Qiu-Li; Yang, Yue-Heng; Liu, Yongsheng

    2012-10-01

    The Dexing copper deposit in southeastern China is a typical non-arc porphyry deposit, the origin of which has been a topic of debate for several decades. Here we present new results from U-Pb geochronology, whole-rock chemistry and Sr-Nd-Hf-O isotopic investigations on the ore-forming granodioritic porphyry. LA-ICPMS zircon U-Pb data suggest that the granodioritic porphyry was formed in the Middle Jurassic (ca. 172.5 Ma) probably associated with lithospheric thinning driven by either sub-continental lithospheric mantle delamination or asthenospheric upwelling. The porphyry displays both arc-like and adakitic trace element signatures. The adakitic features suggest that HREE (heavy rare earth elements)-rich minerals such as garnet and hornblende, in the absence of plagioclase resided in the source region. The arc-like signatures are broadly comparable with those of the proximal Neoproterozoic island arc rocks including the keratophyre from Shuangxiwu Group and associated granitoids indicating a potential genetic relationship. The porphyry has chondritic ɛNd(t) of - 0.28 to 0.25 and radiogenic ɛHf(t) of 2 to 7, and correspondingly, uniform two stage depleted mantle Nd model ages of 940-980 Ma and Hf model ages of 800-1100 Ma (mean ~ 920 Ma). On Nd and Hf isotopic evolution diagrams, these values are markedly similar to those of the adjacent Neoproterozoic arc rocks when calculated forward to the Mid-Jurassic. Zircons of the porphyry show mantle-like oxygen isotope characters with δ18O values clustering in the range of 4.7-5.9‰, similar to the values for the Neoproterozoic arc rocks mentioned above. The geochemical and isotopic features recorded in our study suggest mantle-derived magmas with no significant supracrustal input for the source of the porphyry. With regard to the source of the Cu ore, we consider a model involving the remelting of sulfide-bearing arc-related lower crustal source. Furthermore, the occurrence of a Neoproterozoic VMS (volcanic massive

  5. Submarine volcanoes along the Aegean volcanic arc

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    Nomikou, Paraskevi; Papanikolaou, Dimitrios; Alexandri, Matina; Sakellariou, Dimitris; Rousakis, Grigoris

    2013-06-01

    The Aegean volcanic arc has been investigated along its offshore areas and several submarine volcanic outcrops have been discovered in the last 25 years of research. The basic data including swath bathymetric maps, air-gun profiles, underwater photos and samples analysis have been presented along the four main volcanic groups of the arc. The description concerns: (i) Paphsanias submarine volcano in the Methana group, (ii) three volcanic domes to the east of Antimilos Volcano and hydrothermal activity in southeast Milos in the Milos group, (iii) three volcanic domes east of Christiana and a chain of about twenty volcanic domes and craters in the Kolumbo zone northeast of Santorini in the Santorini group and (iv) several volcanic domes and a volcanic caldera together with very deep slopes of several volcanic islands in the Nisyros group. The tectonic structure of the volcanic centers is described and related to the geometry of the arc and the neotectonic graben structures that usually host them. The NE-SW direction is dominant in the Santorini and Nisyros volcanic groups, located at the eastern part of the arc, where strike-slip is also present, whereas NW-SE direction dominates in Milos and Methana at the western part, where co-existence of E-W disrupting normal faults is observed. The volcanic relief reaches 1100-1200 m in most cases. This is produced from the outcrops of the volcanic centers emerging usually at 400-600 m depth and ending either below sea level or at high altitudes of 600-700 m on the islands. Hydrothermal activity at relatively high temperatures observed in Kolumbo is remarkable whereas low temperature phenomena have been detected in the Santorini caldera around Kameni islands and in the area southeast of Milos. In Methana and Nisyros, hydrothermal activity seems to be limited in the coastal areas without other offshore manifestations.

  6. Magnesium isotope geochemistry in arc volcanism

    Science.gov (United States)

    Teng, Fang-Zhen; Hu, Yan; Chauvel, Catherine

    2016-06-01

    Incorporation of subducted slab in arc volcanism plays an important role in producing the geochemical and isotopic variations in arc lavas. The mechanism and process by which the slab materials are incorporated, however, are still uncertain. Here, we report, to our knowledge, the first set of Mg isotopic data for a suite of arc lava samples from Martinique Island in the Lesser Antilles arc, which displays one of the most extreme geochemical and isotopic ranges, although the origin of this variability is still highly debated. We find the δ26Mg of the Martinique Island lavas varies from -0.25 to -0.10, in contrast to the narrow range that characterizes the mantle (-0.25 ± 0.04, 2 SD). These high δ26Mg values suggest the incorporation of isotopically heavy Mg from the subducted slab. The large contrast in MgO content between peridotite, basalt, and sediment makes direct mixing between sediment and peridotite, or assimilation by arc crust sediment, unlikely to be the main mechanism to modify Mg isotopes. Instead, the heavy Mg isotopic signature of the Martinique arc lavas requires that the overall composition of the mantle wedge is buffered and modified by the preferential addition of heavy Mg isotopes from fluids released from the altered subducted slab during fluid-mantle interaction. This, in turn, suggests transfer of a large amount of fluid-mobile elements from the subducting slab to the mantle wedge and makes Mg isotopes an excellent tracer of deep fluid migration.

  7. Magnesium isotope geochemistry in arc volcanism.

    Science.gov (United States)

    Teng, Fang-Zhen; Hu, Yan; Chauvel, Catherine

    2016-06-28

    Incorporation of subducted slab in arc volcanism plays an important role in producing the geochemical and isotopic variations in arc lavas. The mechanism and process by which the slab materials are incorporated, however, are still uncertain. Here, we report, to our knowledge, the first set of Mg isotopic data for a suite of arc lava samples from Martinique Island in the Lesser Antilles arc, which displays one of the most extreme geochemical and isotopic ranges, although the origin of this variability is still highly debated. We find the δ(26)Mg of the Martinique Island lavas varies from -0.25 to -0.10, in contrast to the narrow range that characterizes the mantle (-0.25 ± 0.04, 2 SD). These high δ(26)Mg values suggest the incorporation of isotopically heavy Mg from the subducted slab. The large contrast in MgO content between peridotite, basalt, and sediment makes direct mixing between sediment and peridotite, or assimilation by arc crust sediment, unlikely to be the main mechanism to modify Mg isotopes. Instead, the heavy Mg isotopic signature of the Martinique arc lavas requires that the overall composition of the mantle wedge is buffered and modified by the preferential addition of heavy Mg isotopes from fluids released from the altered subducted slab during fluid-mantle interaction. This, in turn, suggests transfer of a large amount of fluid-mobile elements from the subducting slab to the mantle wedge and makes Mg isotopes an excellent tracer of deep fluid migration.

  8. Magnesium isotope geochemistry in arc volcanism

    Science.gov (United States)

    Teng, Fang-Zhen; Hu, Yan

    2016-01-01

    Incorporation of subducted slab in arc volcanism plays an important role in producing the geochemical and isotopic variations in arc lavas. The mechanism and process by which the slab materials are incorporated, however, are still uncertain. Here, we report, to our knowledge, the first set of Mg isotopic data for a suite of arc lava samples from Martinique Island in the Lesser Antilles arc, which displays one of the most extreme geochemical and isotopic ranges, although the origin of this variability is still highly debated. We find the δ26Mg of the Martinique Island lavas varies from −0.25 to −0.10, in contrast to the narrow range that characterizes the mantle (−0.25 ± 0.04, 2 SD). These high δ26Mg values suggest the incorporation of isotopically heavy Mg from the subducted slab. The large contrast in MgO content between peridotite, basalt, and sediment makes direct mixing between sediment and peridotite, or assimilation by arc crust sediment, unlikely to be the main mechanism to modify Mg isotopes. Instead, the heavy Mg isotopic signature of the Martinique arc lavas requires that the overall composition of the mantle wedge is buffered and modified by the preferential addition of heavy Mg isotopes from fluids released from the altered subducted slab during fluid−mantle interaction. This, in turn, suggests transfer of a large amount of fluid-mobile elements from the subducting slab to the mantle wedge and makes Mg isotopes an excellent tracer of deep fluid migration. PMID:27303032

  9. Numerical modeling of volcanic arc development

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    Gerya, T.; Gorczyk, W.; Nikolaeva, K.

    2007-05-01

    We have created a new coupled geochemical-petrological-thermomechanical numerical model of subduction associated with volcanic arc development. The model includes spontaneous slab bending, subducted crust dehydration, aqueous fluid transport, mantle wedge melting and melt extraction resulting in crustal growth. Two major volcanic arc settings are modeled so far: active continental margins, and intraoceanic subduction. In case of Pacific-type continental margin two fundamentally different regimes of melt productivity are observed in numerical experiments which are in line with natural observations: (1) During continuous convergence with coupled plates highest amounts of melts are formed immediately after the initiation of subduction and then decrease rapidly with time due to the steepening of the slab inclination angle precluding formation of partially molten mantle wedge plumes; (2) During subduction associated with slab delamination and trench retreat resulting in the formation of a pronounced back arc basin with a spreading center in the middle melt production increases with time due to shallowing/stabilization of slab inclination associated with upward asthenospheric mantle flow toward the extension region facilitating propagation of hydrous partially molten plumes from the slab. In case of spontaneous nucleation of retreating oceanic subduction two scenarios of tecono-magmatic evolution are distinguished: (1) decay and, ultimately, the cessation of subduction and related magmatic activity, (2) increase in subduction rate (to up to ~12 cm/yr) and stabilization of subduction and magmatic arc growth. In the first case the duration of subduction correlates positively with the intensity of melt extraction: the period of continued subduction increases from 15,4 Myrs to 47,6 Myrs with the increase of melt extraction threshold from 1% to 9%. In scenario (1) the magmatic arc crust includes large amounts of rocks formed by melting of subducted crust atop the thermally

  10. Characteristics of Mineralized Volcanic Centers in Javanese Sunda Island Arc, Indonesia

    Science.gov (United States)

    Setijadji, L. D.; Imai, A.; Watanabe, K.

    2007-05-01

    The subduction-related arc magmatism in Java island, Sunda Arc, Indonesia might have started in earliest Tertiary period, but the distinctively recognizable volcanic belts related with Java trench subduction occurred since the Oligocene. We compiled geoinformation on volcanic centers of different epochs, distribution of metallic mineral deposits, petrochemistry of volcanic rocks, geologic structures, and regional gravity image in order to elucidate characteristics of the known mineralized volcanic centers. Metallic deposits are present in various styles from porphyry-related, high-sulfidation, and low-sulfidation epithermal systems; all related with subaerial volcanism and subvolcanic plutonism. Only few and small occurrences of volcanigenic massive sulfides deposits suggest that some mineralization also occurred in a submarine environment. Most locations of mineral deposits can be related with location of Tertiary volcanic centers along the volcanic arcs (i.e. volcanoes whose genetic link with subduction is clear). On the other side there is no mineralization has been identified to occur associated with backarc magmatism whose genetic link with subduction is under debate. There is strong evidence that major metallic deposit districts are located within compressive tectonic regime and bound by coupling major, deep, and old crustal structures (strike-slip faults) that are recognizable from regional gravity anomaly map. So far the most economical deposits and the only existing mines at major industry scale are high-grade epithermal gold deposits which are young (Upper Miocene to Upper Pliocene), concentrated in Bayah dome complex in west Java, and are associated with alkalic magmatism-volcanism. On the other hand, known porphyry Cu-Au deposits are associated with old (Oligocene to Upper Miocene) stocks, and except for one case, all deposits are located in east Java. Petrochemical data suggest a genetic relationship between porphyry mineralization with low- to

  11. Continental arc volcanism as the principal driver of icehouse-greenhouse variability

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    McKenzie, N. Ryan; Horton, Brian K.; Loomis, Shannon E.; Stockli, Daniel F.; Planavsky, Noah J.; Lee, Cin-Ty A.

    2016-04-01

    Variations in continental volcanic arc emissions have the potential to control atmospheric carbon dioxide (CO2) levels and climate change on multimillion-year time scales. Here we present a compilation of ~120,000 detrital zircon uranium-lead (U-Pb) ages from global sedimentary deposits as a proxy to track the spatial distribution of continental magmatic arc systems from the Cryogenian period to the present. These data demonstrate a direct relationship between global arc activity and major climate shifts: Widespread continental arcs correspond with prominent early Paleozoic and Mesozoic greenhouse climates, whereas reduced continental arc activity corresponds with icehouse climates of the Cryogenian, Late Ordovician, late Paleozoic, and Cenozoic. This persistent coupled behavior provides evidence that continental volcanic outgassing drove long-term shifts in atmospheric CO2 levels over the past ~720 million years.

  12. Geology and geochemistry characteristics of the Chiapanecan Volcanic Arc (Central Area), Chiapas Mexico

    Science.gov (United States)

    Mora, J. C.; Jaimes-Viera, M. C.; Garduño-Monroy, V. H.; Layer, P. W.; Pompa-Mera, V.; Godinez, M. L.

    2007-04-01

    The Chiapanecan Volcanic Arc (CVA), located in the central portion of the State of Chiapas, is a 150 km stretch of volcanoes irregularly aligned in the northwest direction between two great volcanic features: the Trans-Mexican Volcanic Belt to the northwest and the Central American Volcanic Arc to the southeast. The CVA is located in a complex zone marking the interaction of the North American, Caribbean and Cocos plates, near the Motagua-Polochic fault system, the boundary between North American and Caribbean plates. The central part of the CVA is composed of an irregular northwest alignment of at least 10 volcanic structures generally lying along NNW-SSE-trending faults splayed from the Motagua-Polochic system. Among the structures there are seven volcanic domes (Huitepec, Amahuitz, La Iglesia, Mispía, La Lanza, Venustiano Carranza and Santotón), one explosion crater (Navenchauc), one collapse structure (Apas), and one dome complex (Tzontehuitz). In the majority of the structures there is a clear resurgence with the formation of several domes in the same structure, with the destruction of previous domes (Navenchauc) or with the formation of new explosion craters or collapse structures (Apas). The volcanic activity in the CVA was mainly effusive accompanied by explosive and phreatomagmatic events and is characterized by volcanic domes accompanied by block-and-ash-flows, ash flows with accretionary lapilli, falls, and pumice flows. The volcanic structures and deposits are calcalkaline in composition with a medium to high content of potassium. CVA volcanic rocks vary from andesite to dacite with SiO 2 between 57 and 66 wt.%, show low concentrations of Ti, P, Nb and Ta, are enriched in Light Rare Earths, depleted in Heavy Rare Earths, and show a small Eu anomaly; all indicative of arc-related volcanism associated with subduction of the Cocos plate under the North American plate, but complicated by the geometry of the plate boundary fault system.

  13. Magma genesis of the acidic volcanism in the intra-arc rift zone of the Izu volcanic arc, Japan

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    Haraguchi, S.; Tokuyama, H.; Ishii, T.

    2010-12-01

    The Izu volcanic arc extends over 550 km from the Izu Peninsula, Japan, to the Nishinoshima Trough or Sofugan tectonic line. It is the northernmost segment of the Izu-Bonin-Mariana arc system, which is located at the eastern side of the Philippine Sea Plate. The recent magmatism of the Izu arc is bimodal and characterized by basalt and rhyolite (e.g. Tamura and Tatsumi 2002). In the southern Izu arc, volcanic front from the Aogashima to the Torishima islands is characterized by submarine calderas and acidic volcanisms. The intra-arc rifting, characterized by back-arc depressions, small volcanic knolls and ridges, is active in this region. Volcanic rocks were obtained in 1995 during a research cruise of the R/V MOANA WAVE (Hawaii University, cruise MW9507). Geochemical variation of volcanic rocks and magma genesis was studied by Hochstaedter et al. (2000, 2001), Machida et al (2008), etc. These studies focused magma and mantle dynamics of basaltic volcanism in the wedge mantle. Acidic volcanic rocks were also dredged during the curies MW9507. However, studies of these acidic volcanics were rare. Herein, we present petrographical and chemical analyses of these acidic rocks, and compare these results with those of other acidic rocks in the Izu arc and lab experiments, and propose a model of magma genesis in a context of acidic volcanism. Dredge sites by the cruise MW9507 are 120, and about 50 sites are in the rift zone. Recovered rocks are dominated by the bimodal assemblage of basalt-basaltic andesite and dacite-rhyolite. The most abundant phase is olivine basalt, less than 50 wt% SiO2. Andesites are minor in volume and compositional gap from 56 to 65 wt% SiO2 exists. The across-arc variation of the HFSE contents and ratios, such as Zr/Y and Nb/Zr of rhyolites exhibit depleted in the volcanic front side and enriched in reararc side. This characteristic is similar to basaltic volcanism pointed out by Hochstaedter et al (2000). The petrographical features of rhyolites

  14. Submarine Arc Volcanism in the Southern Mariana Arc: Results of Recent ROV studies

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    Nichols, A. R.; Tamura, Y.; Stern, R. J.; Embley, R. W.; Hein, J. R.; Jordan, E.; Ribeiro, J. M.; Sica, N.; Kohut, E. J.; Whattam, S. A.; Hirahara, Y.; Senda, R.; Nunokawa, A.

    2009-12-01

    The submarine Diamante cross-arc volcanoes (~16°N) and the Sarigan-Zealandia Bank Multi-Volcano Complex (SZBMVC; ~16°45’N), north and south, respectively, of Anatahan Island in the southern Mariana Arc, were studied during several dives in June 2009 using the ROV Hyper-Dolphin, cruise NT09-08 (R/V Natsushima); neither has been studied in detail before. The data collected provide a new perspective on how the subduction factory operates to complement previous studies on other cross-arc volcanic chains in the Izu-Bonin-Mariana Arc. The Diamante complex consists of three major edifices, two cones (West and Central Diamante) and a more complex caldera-like edifice at the volcanic front (East Diamante). West and Central Diamante are basaltic volcanoes but East Diamante has a more complex history. Our studies indicate initial construction of a basaltic volcano. Magmatic evolution led to a violent caldera-forming and quieter dome-building events. Post-caldera quiescence allowed a carbonate platform to grow, now preserved on the eastern caldera wall. Felsic magma or hot rock provides a heat source for an active hydrothermal field associated with felsic domes in the caldera, which NOAA investigators discovered in 2004. A new type of hydrothermal deposit was discovered in the hydrothermal field, consisting of large sulfide-sulfate mounds topped by bulbous constructions of low-temperature Fe and Mn oxides. Vents on the mounds were observed to emit shimmering water. The SZBMVC consists of six closely spaced edifices whose loci are aligned along two parallel trends, one along the volcanic front (Zealandia Bank, Sarigan and South Sarigan), and one about 15 km west towards the rear-arc (Northwest Zealandia, West Zealandia and West Sarigan). Zealandia Bank dives revealed that, as with East Diamante, initial activity was basaltic and became more evolved with time. The western half of Zealandia Bank is dominated by felsic lavas centered on a small (~2 km diameter) caldera and

  15. Current perspectives on energy and mass fluxes in volcanic arcs

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    Leeman, William; Davidson, Jon; Fischer, Tobias; Grunder, Anita; Reagan, Mark; Streck, Martin

    Volcanoes of the Pacific Ring of Fire and other convergent margins worldwide are familiar manifestations of nature's energy, account for about 25% of global volcanic outputs, dominate volcanic gas emissions to the atmosphere, and pose significant physical threats to a large human population. Yet the processes behind this prolific activity remain poorly understood.An international “State of the Arc” (SOTA) conference was held in August on the slopes of Mt. Hood, Oregon, to address current views on the energy and mass fluxes in volcanic arcs. This meeting brought together some 90 leading experts and students of subduction zones and their related magmatism.

  16. Geology and Geochronology of the Central Part of Chiapanecan Volcanic Arc, Mexico.

    Science.gov (United States)

    Layer, P. W.

    2006-12-01

    The Chiapanecan Volcanic Arc (CVA) is a 150 km stretch of volcanoes irregularly aligned in a northwest direction, including El Chichón volcano located in the central portion of the State of Chiapas, southern Mexico. It lies between two great volcanic features: the Trans-Mexican Volcanic Arc to the northwest, and the Central American Volcanic Arc to the southeast, in a complex zone of the interaction of the North American, Caribbean and Cocos Plates. The central part of the CVA is composed of an irregular northwest alignment of at least 12 volcanic structures located 80 km to the southeast of El Chichón (the only currently active volcano in the CVA). These structures include one explosion crater (Navenchauc), one collapse structure (Apas), one dome complex (Tzontehuitz) and nine volcanic domes (Navenchauc, Huitepec, Amahuitz, La Iglesia, Mispía, La Lanza, Venustiano Carranza, Miguel Hidalgo and Santotón) with associated pyroclastic flow deposits. The juvenile lithics from these deposits have a porphyritic texture with phenocrysts of plagioclase (±), amphibole (±), clinopyroxene (±), orthopyroxene (±) and Fe-Ti oxides surrounded by a matrix composed by microlites of plagioclase and glass. The chemical results obtained from representative samples from the deposits and structures indicate that these belong to the series of subalkaline rocks, and fall into the calcalkaline field with medium to high contents of potassium. They vary in their composition from andesite to dacite with an interval of silica between a 56 to a 66% (wt.). The ages reported in the literature and obtained in this study by means of the K-Ar and the 40Ar/39Ar methods, respectively, indicated that volcanism was episodic and spanned a time from 2100 ky ago (Tzontehuitz) to 225 ky ago (Venustiano Carranza).

  17. Along-arc geochemical and isotopic variations in Javanese volcanic rocks: 'crustal' versus 'source' contamination at the Sunda arc, Indonesia

    Science.gov (United States)

    Handley, H.; Blichert-Toft, J.; Turner, S.; Macpherson, C. G.

    2012-12-01

    Understanding the genesis of volcanic rocks in subduction zone settings is complicated by the multitude of differentiation processes and source components that exert control on lava geochemistry. Magma genesis and evolution at the Sunda arc is controlled and influenced by 1) along arc changes in the composition and thickness of the overriding Eurasian plate, 2) the variable age of the subducting oceanic crust and, 3) changes in the type and amount of sediment deposited on the subducting plate. Along-arc changes in geochemistry have long been recognised in the Sunda arc (Whitford, 1975), but debate still prevails over the cause of such variations and the relative importance of shallow (crustal) versus deep (subduction) contamination at the Sunda arc, Indonesia. Detailed study of individual Sunda arc volcanic centres is, therefore, a prerequisite in order to establish the relative importance and contributions of various potential source components and composition modifying differentiation processes at individual volcanoes, prior to an along arc comparative petrogenetic investigation. We present new radiogenic isotope data for Javanese volcanoes, which is combined with our recently published (Handley et al., 2007; Handley et al., 2008, Handley et al., 2010; Handley et al., 2011) geochemical and isotopic data of Javanese volcanic rocks along with data from other detailed geochemical studies to establish whether variable contributions from the subducting slab, or a change in crustal architecture of the overriding plate, best explain along-arc variations in isotope ratios and trace element characteristics. In West and Central Java Sr isotope ratios of the volcanic rocks broadly correlate with inferred lithospheric thickness implicating a shallow level control on isotopic composition. However, key trace element ratios combined with Hf isotope data indicate that the subducted slab and slab thermal regime also exert major control on the composition of the erupted Javanese

  18. The Fina Nagu volcanic complex: Unusual submarine arc volcanism in the rapidly deforming southern Mariana margin

    Science.gov (United States)

    Brounce, Maryjo; Kelley, Katherine A.; Stern, Robert; Martinez, Fernando; Cottrell, Elizabeth

    2016-10-01

    In the Mariana convergent margin, large arc volcanoes disappear south of Guam even though the Pacific plate continues to subduct and instead, small cones scatter on the seafloor. These small cones could form either due to decompression melting accompanying back-arc extension or flux melting, as expected for arc volcanoes, or as a result of both processes. Here, we report the major, trace, and volatile element compositions, as well as the oxidation state of Fe, in recently dredged, fresh pillow lavas from the Fina Nagu volcanic chain, an unusual alignment of small, closely spaced submarine calderas and cones southwest of Guam. We show that Fina Nagu magmas are the consequence of mantle melting due to infiltrating aqueous fluids and sediment melts sourced from the subducting Pacific plate into a depleted mantle wedge, similar in extent of melting to accepted models for arc melts. Fina Nagu magmas are not as oxidized as magmas elsewhere along the Mariana arc, suggesting that the subduction component responsible for producing arc magmas is either different or not present in the zone of melt generation for Fina Nagu, and that amphibole or serpentine mineral destabilization reactions are key in producing oxidized arc magmas. Individual Fina Nagu volcanic structures are smaller in volume than Mariana arc volcanoes, although the estimated cumulative volume of the volcanic chain is similar to nearby submarine arc volcanoes. We conclude that melt generation under the Fina Nagu chain occurs by similar mechanisms as under Mariana arc volcanoes, but that complex lithospheric deformation in the region distributes the melts among several small edifices that get younger to the northeast.

  19. Preliminary geochemical characterization of volcanic and geothermal fluids discharged from the Ecuadorian volcanic arc.

    OpenAIRE

    Inguaggiato, S.; Hidalgo, S.; Beate, B.; Bourquin, J.

    2009-01-01

    In Ecuador, magmatism results from the subduction of the Nazca Plate beneath the North Western part of South America (Pennington, 1981; Kellogg and Vega, 1995; Witt et al., 2006). North of 2.5°S, the Ecuadorian Quaternary volcanic arc is characterized by about 60 volcanoes distributed in three different parallel chains. Many of these volcanoes are potentially active or currently in activity and display associated geothermal fields. South of this latitude, no active arc is present in Ecuador. ...

  20. Linear volcanic segments in the Sunda Arc, Indonesia: Implications for arc lithosphere control upon volcano distribution

    Science.gov (United States)

    Macpherson, C. G.; Pacey, A.; McCaffrey, K. J.

    2012-12-01

    The overall curvature of many subduction zones is immediately apparent and the term island arc betrays the common assumption that subduction zone magmatism occurs in curved zones. This assumption can be expressed by approximating island arcs as segments of small circles on the surface of a sphere. Such treatments predict that the location of arc volcanoes is related to their vertical separation from the slab (in fact, the depth to seismicity in the slab) and require that the primary control on the locus of magmatism lies either within the subducted slab or the mantle wedge that separates the subducted and overriding lithospheric plates. The concept of curved arcs ignores longstanding observations that magmatism in many subduction systems occurs as segments of linearly arranged volcanic centres. Further evidence for this distribution comes from the close relationship between magmatism and large scale, arc-parallel fabrics in some arcs. Similarly, exposures of deep arc crust or mantle often reveal elongation of magmatic intrusions sub-parallel to the inferred trend of the arc. The Sunda Arc forms the Indonesian islands from Sumatra to Alor and provides an important test for models of volcano distribution for several reasons. First, Sunda has hosted abundant historic volcanic activity. Second, with the notable exception of Krakatau, every volcano in the arc is subaerial from base to cone and, therefore, can be readily identified where there is a suitable extent of local mapping that can be used to ground-truth satellite imagery. Third, there are significant changes in the stress regime along the length of the arc, allowing the influence of the upper plate to be evaluated by comparison of different arc segments. Finally, much of the Sunda Arc has proved difficult to accommodate in models that try to relate volcano distribution to the depth to the subducted slab. We apply an objective line-fitting protocol; the Hough Transform, to explore the distribution of volcanoes

  1. Detailed Seismic Reflection Images of the Central American Volcanic Arc

    Science.gov (United States)

    McIntosh, K. D.; Fulthorpe, C. S.

    2005-12-01

    New high-resolution seismic reflection profiles across the Central American volcanic arc (CAVA) reveal an asymmetric deformation pattern with large-scale folding and uplift of basinal strata in the forearc contrasted by intrusive bodies, normal faults, and possible strikes-slip faults in the backarc. Since Miocene times the CAVA has migrated seaward, apparently impinging on the Sandino forearc basin and creating or modifying the low-lying Nicaragua depression, which contains the backarc and much of the arc. However the structural nature of the depression and its possible relationship to forearc sliver movement is poorly known. In November-December 2004 we recorded a large, high-resolution, seismic reflection dataset largely on the Pacific shelf (forearc) area of Central America, extending from NW Costa Rica to the SE edge of El Salvador's territorial waters. We seized an opportunity to study the nature of the CAVA by recording data into the Gulf of Fonseca, a large embayment at the intersection of Nicaragua, Honduras, and El Salvador. With 3 GI airguns and a 2100 m streamer we recorded data with typical penetration of 2-3 seconds in the Sandino basin and frequency content of ~10-250 Hz (at shallow levels). Penetration was limited over the arc summit with high velocity volcanic rocks encountered at depths as shallow as a few hundred meters. To the NE the edge of the Nicaragua depression occurs abruptly; our data show a well-developed sedimentary basin 1.5-3 km thick separated by numerous steeply-dipping faults. The broadband signal and good penetration of this dataset will help us determine the chronology of arc development in this position and the styles of deformation in the forearc, arc, and backarc areas. In turn, this will help us understand the regional tectonic and stratigraphic development of this margin due to the profound affects of the arc.

  2. Stress fields of the overriding plate at convergent margins and beneath active volcanic arcs.

    Science.gov (United States)

    Apperson, K D

    1991-11-01

    Tectonic stress fields in the overriding plate at convergent plate margins are complex and vary on local to regional scales. Volcanic arcs are a common element of overriding plates. Stress fields in the volcanic arc region are related to deformation generated by subduction and to magma generation and ascent processes. Analysis of moment tensors of shallow and intermediate depth earthquakes in volcanic arcs indicates that the seismic strain field in the arc region of many convergent margins is subhorizontal extension oriented nearly perpendicular to the arc. A process capable of generating such a globally consistent strain field is induced asthenospheric corner flow below the arc region.

  3. Gravitational removal of volcanic arc roots in Cordilleran orogens

    Science.gov (United States)

    Currie, C. A.; Ducea, M. N.; DeCelles, P. G.; Beaumont, C.

    2013-12-01

    Cordilleran orogens, such as the central Andes, form above subduction zones and their evolution depends on processes associated with oceanic plate subduction and continental plate shortening. Such orogens are characterized by abundant arc volcanism and the formation of thick (>30 km) granitoid batholiths. The magma composition is consistent with a multi-stage model, in which parental mantle-derived basaltic magmas stagnate within the continental lithosphere and then undergo differentiation. Felsic partial melts rise through the crust, leaving a high-density garnet pyroxenite root in the deep lithosphere. Here, we study the dynamics of gravitational removal of this root using regional two-dimensional thermal-mechanical models of subduction below a continent. In the models, the volcanic arc location is determined dynamically based on subduction zone thermal structure, and formation of the batholith-root complex is simulated by changing the density of the volcanic arc lithosphere over time. For the lithosphere structure used in our models, arc roots that undergo even a small density increase are readily removed through gravitational foundering for a wide range of root strengths and subduction rates. The dynamics of removal depend on the relative rates of downward gravitational growth and horizontal shearing by subduction-induced mantle flow. Gravitational growth dominates for high root densification rates, high root viscosities and low subduction rates, leading to drip-like removal of the root as a single downwelling over 1-3 Myr. At lower growth rates, the root is removed over ~6 Myr through shear entrainment, as it is carried sideways by mantle flow and then subducted on top of the oceanic plate. In all models, >80% of the root is removed, making this an effective way to thin mantle lithosphere in the volcanic arc region. This can help resolve the mass problem in the central Andes, where observations indicate a thin mantle lithosphere, despite significant crustal

  4. Plasma distribution of cathodic ARC deposition system

    Energy Technology Data Exchange (ETDEWEB)

    Anders, S.; Raoux, S.; Krishnan, K.; MacGill, R.A.; Brown, I.G. [Lawrence Berkeley National Lab., CA (United States)

    1996-08-01

    The plasma distribution using a cathodic arc plasma source with and without magnetic macroparticle filter has been determined by depositing on a transparent plastic substrate and measuring the film absorption. It was found that the width of the distribution depends on the arc current, and it also depends on the cathode material which leads to a spatial separation of the elements when an alloy cathode is used. By applying a magnetic multicusp field near the exit of the magnetic filter, it was possible to modify the plasma distribution and obtain a flat plasma profile with a constant and homogeneous elemental distribution.

  5. Forearc Deformation, Arc Volcanism, and Landscape Evolution near the Cocos-Nazca-Caribbean Triple Junction

    Science.gov (United States)

    Morell, K. D.; Fisher, D.; Gardner, T.; Protti, M.

    2005-12-01

    New geologic mapping in SE Costa Rica and SW Panama reveals a system of structures and landscape features that are actively propagating with the Cocos-Nazca-Caribbean Triple Junction. The triple junction migrates to the SE at ~50 km/my, so the upper plate inboard of the Nazca plate experiences a rapid change from steep, slow subduction of the Nazca plate to shallow, rapid subduction of the Cocos plate. High plate boundary coupling for ~100 km NW of the triple junction has led to the development of the Fila Costena Thrust Belt. Balanced cross-sections indicate that shortening rates are highest near the center of the thrust belt, and decrease to the SE nearest the triple junction, where the thrust belt abruptly terminates. Right lateral tear faults cut the thrusts of the Fila Costena and allow for a sharp gradient in upper plate shortening above the subducted projection of the Panama Fracture Zone (PFZ), or the Cocos-Nazca boundary. East of the triple junction, a ridge exposes a fault-related anticline that may represent the incipient propagation of the Fila Costena into Panama. The volcanic arc is active just to the east of the onland projection of the subducting PFZ (e.g., Volcan Baru), with the extinct Talamanca arc lying to the west of this projection. Lahar fans on the slopes of the active Volcan Baru are analogous to the backtilted lahars now restricted to the rear of the Fila Costena. The spatial and temporal distribution of arc volcanism is consistent with a mantle wedge restricted to the east of the PFZ that migrates eastward with the triple junction. The Rio Chiriqui drainage system is currently the only river that carries arc volcanics to the eastern thrust front. The river skirts the southeast edge of the thrust belt and is inset into lahar fans on the slopes of Volcan Baru. Uplifted Quaternary fluvial terraces, located several kilometers west from the current drainage system, are offset at the thrust front by about 100-150 m. Andesite clasts in these

  6. Filtered cathodic arc deposition apparatus and method

    Science.gov (United States)

    Krauss, Alan R.

    1999-01-01

    A filtered cathodic arc deposition method and apparatus for the production of highly dense, wear resistant coatings which are free from macro particles. The filtered cathodic arc deposition apparatus includes a cross shaped vacuum chamber which houses a cathode target having an evaporable surface comprised of the coating material, means for generating a stream of plasma, means for generating a transverse magnetic field, and a macro particle deflector. The transverse magnetic field bends the generated stream of plasma in the direction of a substrate. Macro particles are effectively filtered from the stream of plasma by traveling, unaffected by the transverse magnetic field, along the initial path of the plasma stream to a macro particle deflector. The macro particle deflector has a preformed surface which deflects macro particles away from the substrate.

  7. Plasma transferred arc deposition of beryllium

    Science.gov (United States)

    Hollis, K.; Bartram, B.; Withers, J.; Storm, R.; Massarello, J.

    2006-12-01

    The exceptional properties of beryllium (Be), including low density and high elastic modulus, make it the material of choice in many defense and aerospace applications. However, health hazards associated with Be material handling limit the applications that are suited for its use. Innovative solutions that enable continued use of Be in critical applications while addressing worker health concerns are highly desirable. Plasma transferred arc solid free-form fabrication is being evaluated as a Be fabrication technique for civilian and military space-based components. Initial experiments producing Be deposits are reported here. Deposit shape, microstructure, and mechanical properties are reported.

  8. Magmatic control along a strike-slip volcanic arc: The central Aeolian arc (Italy)

    KAUST Repository

    Ruch, Joel

    2016-01-23

    The regional stress field in volcanic areas may be overprinted by that produced by magmatic activity, promoting volcanism and faulting. In particular, in strike-slip settings, the definition of the relationships between the regional stress field and magmatic activity remains elusive. To better understand these relationships, we collected stratigraphic, volcanic and structural field data along the strike-slip Central Aeolian arc (Italy): here the islands of Lipari and Vulcano separate the extensional portion of the arc (to the east) from the contractional one (to the west). We collected >500 measurements of faults, extension fractures and dikes at 40 sites. Most structures are NNE-SSW to NNW-SSE oriented, eastward dipping, and show almost pure dip-slip motion; consistent with an E-W extension direction, with minor dextral and sinistral shear. Our data highlight six eruptive periods during the last 55 ka, which allow considering both islands as a single magmatic system, in which tectonic and magmatic activity steadily migrated eastward and currently focus on a 10 km long x 2 km wide active segment. Faulting appears to mostly occur in temporal and spatial relation with magmatic events, supporting that most of the observable deformation derives from transient magmatic activity (shorter-term, days to months), rather than from steady longer-term regional tectonics (102-104 years). More in general, the Central Aeolian case shows how magmatic activity may affect the structure and evolution of volcanic arcs, overprinting any strike-slip motion with magma-induced extension at the surface.

  9. Magmatic control along a strike-slip volcanic arc: The central Aeolian arc (Italy)

    Science.gov (United States)

    Ruch, J.; Vezzoli, L.; De Rosa, R.; Di Lorenzo, R.; Acocella, V.

    2016-02-01

    The regional stress field in volcanic areas may be overprinted by that produced by magmatic activity, promoting volcanism and faulting. In particular, in strike-slip settings, the definition of the relationships between the regional stress field and magmatic activity remains elusive. To better understand these relationships, we collected stratigraphic, volcanic, and structural field data along the strike-slip central Aeolian arc (Italy): here the islands of Lipari and Vulcano separate the extensional portion of the arc (to the east) from the contractional one (to the west). We collected >500 measurements of faults, extension fractures, and dikes at 40 sites. Most structures are NNE-SSW to NNW-SSE oriented, eastward dipping, and show almost pure dip-slip motion, consistent with an E-W extension direction, with minor dextral and sinistral shear. Our data highlight six eruptive periods during the last 55 ka, which allow considering both islands as a single magmatic system, in which tectonic and magmatic activities steadily migrated eastward and currently focus on a 10 km long × 2 km wide active segment. Faulting appears to mostly occur in temporal and spatial relation with magmatic events, supporting that most of the observable deformation derives from transient magmatic activity (shorter term, days to months), rather than from steady longer-term regional tectonics (102-104 years). More in general, the central Aeolian case shows how magmatic activity may affect the structure and evolution of volcanic arcs, overprinting any strike-slip motion with magma-induced extension at the surface.

  10. The arc arises: The links between volcanic output, arc evolution and melt composition

    Science.gov (United States)

    Brandl, Philipp A.; Hamada, Morihisa; Arculus, Richard J.; Johnson, Kyle; Marsaglia, Kathleen M.; Savov, Ivan P.; Ishizuka, Osamu; Li, He

    2017-03-01

    Subduction initiation is a key process for global plate tectonics. Individual lithologies developed during subduction initiation and arc inception have been identified in the trench wall of the Izu-Bonin-Mariana (IBM) island arc but a continuous record of this process has not previously been described. Here, we present results from International Ocean Discovery Program Expedition 351 that drilled a single site west of the Kyushu-Palau Ridge (KPR), a chain of extinct stratovolcanoes that represents the proto-IBM island arc, active for ∼25 Ma following subduction initiation. Site U1438 recovered 150 m of oceanic igneous basement and ∼1450 m of overlying sediments. The lower 1300 m of these sediments comprise volcaniclastic gravity-flow deposits shed from the evolving KPR arc front. We separated fresh magmatic minerals from Site U1438 sediments, and analyzed 304 glass (formerly melt) inclusions, hosted by clinopyroxene and plagioclase. Compositions of glass inclusions preserve a temporal magmatic record of the juvenile island arc, complementary to the predominant mid-Miocene to recent activity determined from tephra layers recovered by drilling in the IBM forearc. The glass inclusions record the progressive transition of melt compositions dominated by an early 'calc-alkalic', high-Mg andesitic stage to a younger tholeiitic stage over a time period of 11 Ma. High-precision trace element analytical data record a simultaneously increasing influence of a deep subduction component (e.g., increase in Th vs. Nb, light rare earth element enrichment) and a more fertile mantle source (reflected in increased high field strength element abundances). This compositional change is accompanied by increased deposition rates of volcaniclastic sediments reflecting magmatic output and maturity of the arc. We conclude the 'calc-alkalic' stage of arc evolution may endure as long as mantle wedge sources are not mostly advected away from the zones of arc magma generation, or the rate of

  11. Drilling of Submarine Shallow-water Hydrothermal Systems in Volcanic Arcs of the Tyrrhenian Sea, Italy

    Science.gov (United States)

    Petersen, S.; Augustin, N.; de Benedetti, A.; Esposito, A.; Gaertner, A.; Gemmell, B.; Gibson, H.; He, G.; Huegler, M.; Kleeberg, R.; Kuever, J.; Kummer, N. A.; Lackschewitz, K.; Lappe, F.; Monecke, T.; Perrin, K.; Peters, M.; Sharpe, R.; Simpson, K.; Smith, D.; Wan, B.

    2007-12-01

    Seafloor hydrothermal systems related to volcanic arcs are known from several localities in the Tyrrhenian Sea in water depths ranging from 650 m (Palinuro Seamount) to less than 50 m (Panarea). At Palinuro Seamount 13 holes (Metal enrichment at the top of the deposit is evident in some cores with polymetallic (Zn, Pb, Ag) sulfides overlying more massive and dense pyritic ore. The massive sulfide mineralization at Palinuro Seamount contains a number of unusual minerals, including enargite, tennantite, luzonite, and Ag-sulfosalts, that are not commonly encountered in mid-ocean ridge massive sulfides. In analogy to epithermal deposits forming on land, the occurrence of these minerals suggests a high sulfidation state of the hydrothermal fluids during deposition implying that the mineralizing fluids were acidic and oxidizing rather than near-neutral and reducing as those forming typical base metal rich massive sulfides along mid-ocean ridges. Oxidizing conditions during sulfide deposition can probably be related to the presence of magmatic volatiles in the mineralizing fluids that may be derived from a degassing magma chamber. Elevated temperatures within sediment cores and TV-grab stations (up to 60°C) indicate present day hydrothermal fluid flow. This is also indicated by the presence of small tube-worm bushes present on top the sediment. A number of drill holes were placed around the known phreatic gas-rich vents of Panarea and recovered intense clay-alteration in some holes as well as abundant massive anhydrite/gypsum with only trace sulfides along a structural depression suggesting the presence of an anhydrite seal to a larger hydrothermal system at depth. The aim of this study is to understand the role that magmatic volatiles and phase separation play in the formation of these precious and trace element-rich shallow water (hydrothermal systems in the volcanic arcs of the Tyrrhenian Sea.

  12. Submarine record of volcanic island construction and collapse in the Lesser Antilles arc: First scientific drilling of submarine volcanic island landslides by IODP Expedition 340

    Science.gov (United States)

    Le Friant, A.; Ishizuka, O.; Boudon, G.; Palmer, M. R.; Talling, P. J.; Villemant, B.; Adachi, T.; Aljahdali, M.; Breitkreuz, C.; Brunet, M.; Caron, B.; Coussens, M.; Deplus, C.; Endo, D.; Feuillet, N.; Fraas, A. J.; Fujinawa, A.; Hart, M. B.; Hatfield, R. G.; Hornbach, M.; Jutzeler, M.; Kataoka, K. S.; Komorowski, J.-C.; Lebas, E.; Lafuerza, S.; Maeno, F.; Manga, M.; Martínez-Colón, M.; McCanta, M.; Morgan, S.; Saito, T.; Slagle, A.; Sparks, S.; Stinton, A.; Stroncik, N.; Subramanyam, K. S. V.; Tamura, Y.; Trofimovs, J.; Voight, B.; Wall-Palmer, D.; Wang, F.; Watt, S. F. L.

    2015-02-01

    IODP Expedition 340 successfully drilled a series of sites offshore Montserrat, Martinique and Dominica in the Lesser Antilles from March to April 2012. These are among the few drill sites gathered around volcanic islands, and the first scientific drilling of large and likely tsunamigenic volcanic island-arc landslide deposits. These cores provide evidence and tests of previous hypotheses for the composition and origin of those deposits. Sites U1394, U1399, and U1400 that penetrated landslide deposits recovered exclusively seafloor sediment, comprising mainly turbidites and hemipelagic deposits, and lacked debris avalanche deposits. This supports the concepts that i/ volcanic debris avalanches tend to stop at the slope break, and ii/ widespread and voluminous failures of preexisting low-gradient seafloor sediment can be triggered by initial emplacement of material from the volcano. Offshore Martinique (U1399 and 1400), the landslide deposits comprised blocks of parallel strata that were tilted or microfaulted, sometimes separated by intervals of homogenized sediment (intense shearing), while Site U1394 offshore Montserrat penetrated a flat-lying block of intact strata. The most likely mechanism for generating these large-scale seafloor sediment failures appears to be propagation of a decollement from proximal areas loaded and incised by a volcanic debris avalanche. These results have implications for the magnitude of tsunami generation. Under some conditions, volcanic island landslide deposits composed of mainly seafloor sediment will tend to form smaller magnitude tsunamis than equivalent volumes of subaerial block-rich mass flows rapidly entering water. Expedition 340 also successfully drilled sites to access the undisturbed record of eruption fallout layers intercalated with marine sediment which provide an outstanding high-resolution data set to analyze eruption and landslides cycles, improve understanding of magmatic evolution as well as offshore sedimentation

  13. Oligocene and Miocene arc volcanism in northeastern California: evidence for post-Eocene segmentation of the subducting Farallon plate

    Science.gov (United States)

    Colgan, J.P.; Egger, A.E.; John, D.A.; Cousens, B.; Fleck, R.J.; Henry, C.D.

    2011-01-01

    The Warner Range in northeastern California exposes a section of Tertiary rocks over 3 km thick, offering a unique opportunity to study the long-term history of Cascade arc volcanism in an area otherwise covered by younger volcanic rocks. The oldest locally sourced volcanic rocks in the Warner Range are Oligocene (28–24 Ma) and include a sequence of basalt and basaltic andesite lava flows overlain by hornblende and pyroxene andesite pyroclastic flows and minor lava flows. Both sequences vary in thickness (0–2 km) along strike and are inferred to be the erosional remnants of one or more large, partly overlapping composite volcanoes. No volcanic rocks were erupted in the Warner Range between ca. 24 and 16 Ma, although minor distally sourced silicic tuffs were deposited during this time. Arc volcanism resumed ca. 16 Ma with eruption of basalt and basaltic andesite lavas sourced from eruptive centers 5–10 km south of the relict Oligocene centers. Post–16 Ma arc volcanism continued until ca. 8 Ma, forming numerous eroded but well-preserved shield volcanoes to the south of the Warner Range. Oligocene to Late Miocene volcanic rocks in and around the Warner Range are calc-alkaline basalts to andesites (48%–61% SiO2) that display negative Ti, Nb, and Ta anomalies in trace element spider diagrams, consistent with an arc setting. Middle Miocene lavas in the Warner Range are distinctly different in age, composition, and eruptive style from the nearby Steens Basalt, with which they were previously correlated. Middle to Late Miocene shield volcanoes south of the Warner Range consist of homogeneous basaltic andesites (53%–57% SiO2) that are compositionally similar to Oligocene rocks in the Warner Range. They are distinctly different from younger (Late Miocene to Pliocene) high-Al, low-K olivine tholeiites, which are more mafic (46%–49% SiO2), did not build large edifices, and are thought to be related to backarc extension. The Warner Range is ∼100 km east of the

  14. Age and duration of intra-oceanic arc volcanism built on a suprasubduction zone type oceanic crust in southern Neotethys, SE Anatolia

    Directory of Open Access Journals (Sweden)

    Fatih Karaoğlan

    2013-07-01

    Full Text Available The southeastern Anatolia comprises numbers of tectono-magmatic/stratigraphic units such as the metamorphic massifs, the ophiolites, the volcanic arc units and the granitoid rocks. All of them play important role for the late Cretaceous evolution of the southern Neotethys. The spatial and temporal relations of these units suggest the progressive development of coeval magmatism and thrusting during the late Cretaceous northward subduction/accretion. Our new U-Pb zircon data from the rhyolitic rocks of the wide-spread volcanic arc unit show ages of (83.1 ± 2.2–(74.6 ± 4.4 Ma. Comparison of the ophiolites, the volcanic arc units and the granitoids suggest following late Cretaceous geological evolution. The ophiolites formed in a suprasubduction zone (SSZ setting as a result of northward intra-oceanic subduction. A wide-spread island-arc tholeiitic volcanic unit developed on the top of the SSZ-type crust during 83–75 Ma. Related to regional plate convergence, northward under-thrusting of SSZ-type ophiolites and volcanic arc units was initiated beneath the Tauride platform (Malatya-Keban and followed by the intrusion of I-type calc-alkaline volcanic arc granitoids during 84–82 Ma. New U-Pb ages from the arc-related volcanic-sedimentary unit and granitoids indicate that under-thrusting of ophiolites together with the arc-related units beneath the Malatya-Keban platform took place soon after the initiation of the volcanic arc on the top of the SSZ-type crust. Then the arc-related volcanic-sedimentary unit continued its development and lasted at ∼75 Ma until the deposition of the late Campanian–Maastrichtian shallow marine limestone. The subduction trench eventually collided with the Bitlis-Pütürge massif giving rise to HP-LT metamorphism of the Bitlis massif. Although the development of the volcanic arc units and the granitoids were coeval at the initial stage of the subduction/accretion both tectono-magmatic units were

  15. Geophysical imaging of buried volcanic structures within a continental back-arc basin

    DEFF Research Database (Denmark)

    Stratford, Wanda Rose; Stern, T.A.

    2008-01-01

    Hidden beneath the ~2 km thick low-velocity volcaniclastics on the western margin of the Central Volcanic Region, North Island, New Zealand, are two structures that represent the early history of volcanic activity in a continental back-arc. These ~20×20 km structures, at Tokoroa and Mangakino, fo...

  16. An Early Cretaceous volcanic arc/marginal basin transition zone, Peninsula hardy, southernmost Chile

    Science.gov (United States)

    Miller, Christopher A.; Barton, Michael; Hanson, Richard E.; Fleming, Thomas H.

    1994-10-01

    The Hardy Formation represents a latest Jurassic-Early Cretaceous volcanic arc that was located along the Pacific margin of southern South America. It was separated from the continent by a marginal basin floored by portions of an ophiolite sequence (the Rocas Verdes ophiolites). The transition between the arc and marginal basin occurs on Peninsula Hardy, southernmost Chile, where there is a lateral facies transition from arc deposits of the Hardy Formation into proximal marginal basin fill of the Yahgan Formation. Interfingering of arc and marginal basin sequences demonstrates that subduction-related arc magmatism was concurrent with marginal basin formation. The lateral facies transition is reflected in the geochemistry of volcanic rocks from the Hardy and Yahgan formations. Basalts, andesites and dacites of the arc sequence follow a calc-alkaline differentiation trend whereas basalts from the marginal basin follow a tholeiitic differentiation trend. Estimates of temperature and oxygen fugacity for crystallization of the arc andesites are similar to values reported for other calc-alkaline andesites. It is suggested that water activity influenced the early or late crystallization of Ti-magnetite and this controlled the style of differentiation of the magmas erupted on Peninsula Hardy. Magmas with high water contents evolved along the calc-alkaline differentiation trend whereas those with low water contents evolved along the tholeiitic differentiation trend. Some rhyolites are differentiated from the calc-alkaline andesites and dacites, but most appear to be the products of crustal anatexis on the basis of trace-element evidence. The arc basalts and some marginal basin basalts show relative enrichment in LILE, relative depletion in HFSE, and enrichment in LREE. Other marginal basin basalts are LREE depleted and show small relative depletions in HFSE. Basalts with both calc-alkaline and tholeiitic affinities can also be recognized in the Rocas Verdes ophiolites

  17. Backarc tectonism, volcanism, and mass wasting shape seafloor morphology in the Santorini-Christiana-Amorgos region of the Hellenic Volcanic Arc

    Science.gov (United States)

    Hooft, Emilie E. E.; Nomikou, Paraskevi; Toomey, Douglas R.; Lampridou, Danai; Getz, Claire; Christopoulou, Maria-Eleni; O'Hara, Daniel; Arnoux, Gillean M.; Bodmer, Miles; Gray, Melissa; Heath, Benjamin A.; VanderBeek, Brandon P.

    2017-08-01

    In subduction zone backarcs, extensional deformation and arc volcanism interact and these processes, together with mass wasting, shape the seafloor morphology. We present a new bathymetric map of the Santorini-Christiana-Amorgos backarc region of the Hellenic subduction zone by merging high-resolution multibeam swath data from the R/V Langseth PROTEUS seismic experiment with existing maps. The map together with Knudsen subbottom echosounding profiles reveal that recent tectonism, volcanism, and mass wasting are more prevalent in the Santorini-Amorgos region on the east side of Santorini than in the Christiana Basin on the west side. In the Santorini-Amorgos region, large normal faults form the Anydros and Anafi Basins. Where normal fault segments overlap, two nearby accommodation zones generate a relay ramp and the adjoining Anydros synclinal horst with associated complex faulting and elevated seismicity. The ongoing normal faulting in the Santorini-Amorgos region is accompanied by potentially tsunamigenic submarine landsliding; we identified a large submarine landslide along the Santorini-Amorgos Fault and a smaller landslide with an overlying debris chute along the Amorgos Fault. Volcanic activity is also focused in this eastern region along the Kolumbo lineament within the Anydros Basin. Within the Christiana Basin we discovered the Proteus Knoll and adjacent buried edifice. We suggest that this is an older volcanic edifice formed along the Hellenic Volcanic Arc between Santorini and Milos. Around Santorini itself, features formed during, and immediately after, the Late Bronze Age eruption dominate the seafloor morphology such as the northern strait and wrinkled seafloor pyroclastic flow deposits. This topography is continually reshaped at a smaller scale by ongoing mass wasting. We infer that the earthquake, volcanic, and tsunami activity of the Santorini-Amorgos region is a consequence of focused northwest-southeast extension as the southeastern Aegean moves

  18. Geothermal systems in volcanic arcs: Volcanic characteristics and surface manifestations as indicators of geothermal potential and favorability worldwide

    Science.gov (United States)

    Stelling, P.; Shevenell, L.; Hinz, N.; Coolbaugh, M.; Melosh, G.; Cumming, W.

    2016-09-01

    This paper brings a global perspective to volcanic arc geothermal assessments by evaluating trends and correlations of volcanic characteristic and surface manifestation data from world power production sites in subduction zone volcanic settings. The focus of the work was to evaluate volcanic centers individually and as a group in these arcs by correlating various geologic characteristics with known potential to host electricity grade geothermal systems at the volcanic centers. A database was developed that describes key geologic factors expected to be indicative of productive geothermal systems in a global training set, which includes all 74 subduction zone volcanic centers world-wide with current or proven power production capability. Importantly, this data set only contains data from subduction zone volcanoes and contains no negative cases, limiting the populations of any statistical groups. Regardless, this is the most robust geothermal benchmark training set for magmatic-heated systems to date that has been made public. The work reported here is part of a larger project that included data collection, evaluation, correlations and weightings, fairway and favorability modeling and mapping, prediction of blind systems, and uncertainty analysis to estimate errors associated with model predictions. This first paper describes volcano characteristics, compositions and eruption ages and trends along with surface manifestation observations and temperatures as they relate to known power producing systems. Our findings show a strong correlation between the presence and size of active flank fumarole areas and installed power production. Additionally, the majority of volcanic characteristics, including long-held anecdotal correlations related to magmatic composition or size, have limited to no correlation with power production potential. Notable exceptions are correlations between greater power yield from geothermal systems associated with older (Pleistocene) caldera systems

  19. Landscape evolution within a retreating volcanic arc, Costa Rica, Central America

    Science.gov (United States)

    Marshall, Jeffrey S.; Idleman, Bruce D.; Gardner, Thomas W.; Fisher, Donald M.

    2003-05-01

    Subduction of hotspot-thickened seafloor profoundly affects convergent margin tectonics, strongly affecting upper plate structure, volcanism, and landscape evolution. In southern Central America, low-angle subduction of the Cocos Ridge and seamount domain largely controls landscape evolution in the volcanic arc. Field mapping, stratigraphic correlation, and 40Ar/39Ar geochronology for late Cenozoic volcanic rocks of central Costa Rica provide new insights into the geomorphic response of volcanic arc landscapes to changes in subduction parameters (slab thickness, roughness, dip). Late Neogene volcanism was focused primarily along the now-extinct Cordillera de Aguacate. Quaternary migration of the magmatic front shifted volcanism northeastward to the Caribbean slope, creating a new topographic divide and forming the Valle Central basin. Stream capture across the paleo Aguacate divide led to drainage reversal toward the Pacific slope and deep incision of reorganized fluvial networks. Pleistocene caldera activity generated silicic ash flows that buried the Valle Central and descended the Tárcoles gorge to the Orotina debris fan at the coast. Growth of the modern Cordillera Central accentuated relief along the new divide, establishing the Valle Central as a Pacific slope drainage basin. Arc migration, relocation of the Pacific-Caribbean drainage divide, and formation of the Valle Central basin resulted from slab shallowing as irregular, hotspot-thickened crust entered the subduction zone. The geomorphic evolution of volcanic arc landscapes is thus highly sensitive to changes in subducting plate character.

  20. The trace-element characteristics of Aegean and Aeolian volcanic arc marine tephra

    Science.gov (United States)

    Clift, Peter; Blusztajn, Jerzy

    1999-10-01

    High-silica volcanic ashes are found within deep-sea sediments throughout the Eastern Mediterranean. Although coring by Ocean Drilling Program has penetrated Lower Pliocene (˜4 Ma) sediments, few ashes older than 400 k.y. have been recovered, suggesting a young initiation to subaerial Aegean Arc volcanism. Ashes derived from the Aegean volcanic front were cored south and east of the arc, and are typified by medium-K, calc-alkaline major-element compositions, contrasting with high-K ashes from the Aeolian Arc found in the Ionian Sea and as far east as Crete. Ion microprobe analysis of individual glass shards shows that all the ashes have a light rare earth element (LREE)-enriched pattern after normalizing against a chondrite standard. Aeolian Arc-derived ashes show greater enrichment than those from the Aegean area. Within the latter set, two groups are discernible, a mildly enriched set similar to the volcanoes of the arc volcanic front, and a more enriched group corresponding to lavas from the backarc region or possible from western Anatolia. Multi-element `spider diagrams' also show a bimodal division of enriched and depleted Aegean ashes, possibly caused by source depletion due to melt extraction in the Aegean backarc followed by remelting under the volcanic front. Relative Nb depletion, a characteristic of arc volcanism, is seen to be modest in Aegean and non-existent in Aeolian ashes. Using B/Be as a proxy for the flux of material from the subducting slab, this influence is seen to be low in the Aeolian Arc but higher than at Vesuvius. B/Be is higher again in the Aegean Arc. These differences may reflect the rate of subduction in each system. Data suggest caution is required when correlating ashes solely on the basis of major elements, as alkaline ashes from the central part of the study may be derived from Italy or from the Aegean backarc.

  1. The Relationship Between the Signature of Subducted Sediments in Volcanic Gases and Volatile Flux along the Central American Volcanic Arc

    Science.gov (United States)

    Fischer, T. P.; Zimmer, M. M.; Hilton, D. R.; Shaw, A. M.; Cameron, B. I.; Walker, J. A.; Molina C., E.

    2002-05-01

    Volcanic arcs are locations where elements are recycled from the Earth's surface into the mantle. Fluxes of volcanic volatile emissions can vary significantly along a single arc and a fundamental aim of arc-related studies is to quantify these variations and compare them to subduction zone parameters. As part of the Central American arc study, we report N2, He and Ar abundance relationships and N-isotope ratios for 7 volcanic centers in Guatemala to complement on-going studies in Costa Rica. In Guatemala, the arc crust is thicker and older than in Costa Rica and the entire sediment sequence on the down-going plate is likely to contribute to the slab flux. Sulfur dioxide fluxes vary significantly along the arc (2001 measurements): in the Guatemala segment, Fuego and Pacaya emit a total of ~1500 t/day whereas in Costa Rica, Arenal and Poas are emitting only ~190 t/day. The Guatemalan volcanic centers of Amatitlan-Pacaya, Fuego, Moyuta, Tecuamburro, Amatitlan, Zunil and San Marcos have N2/He ratios ranging from 2200 - 8100, typical for arc-related fluids. N2/Ar ratios (40-500) and the high N2/He indicate addition of N2 from subducted sediments or arc crust to a mantle derived component (N2/He Guatemala are in contrast to typical mantle-derived N2/He ratios (160 - 600) measured at Poas and Turialba, Costa Rica. Nitrogen isotope ratios for the Guatemalan volcanic centers range from δ 15N = + 1.0‰ for San Marcos to + 5.8‰ for Fuego (δ 15N air = 0.0‰ ), indicating a sedimentary nitrogen component. The mantle-derived N2/He ratios for Poas (- 3.0‰ ) are consistent with a more mantle-like δ 15N. In Guatemala, the highest 3He/4He ratios (7.6 for Pacaya and 7.3 Ra for Fuego) correlate with the lowest N2/He ratios (1500 and 2100) and high δ 15N values (+3.8‰ and +5.8‰ ). Mixing relationships (3He/4He and δ 15N) suggest that at Fuego and Pacaya up to 20% of the nitrogen is of subducted sedimentary origin, contrary to Poas and Turialba where the slab derived

  2. Stratigraphic and geochemical evolution of an oceanic arc upper crustal section: The Jurassic Talkeetna Volcanic Formation, south-central Alaska

    Science.gov (United States)

    Clift, P.D.; Draut, A.E.; Kelemen, P.B.; Blusztajn, J.; Greene, A.

    2005-01-01

    The Early Jurassic Talkeetna Volcanic Formation forms the upper stratigraphic level of an oceanic volcanic arc complex within the Peninsular Terrane of south-central Alaska. The section comprises a series of lavas, tuffs, and volcaniclastic debris-How and flow turbidite deposits, showing significant lateral facies variability. There is a general trend toward more volcaniclastic sediment at the top of the section and more lavas and tuff breccias toward the base. Evidence for dominant submarine, mostly mid-bathyal or deeper (>500 m) emplacement is seen throughout the section, which totals ???7 km in thickness, similar to modern western Pacific arcs, and far more than any other known exposed section. Subaerial sedimentation was rare but occurred over short intervals in the middle of the section. The Talkeetna Volcanic Formation is dominantly calc-alkatine and shows no clear trend to increasing SiO2 up-section. An oceanic subduction petrogenesis is shown by trace element and Nd isotope data. Rocks at the base of the section show no relative enrichment of light rare earth elements (LREEs) versus heavy rare earth elements (REES) or in melt-incompatible versus compatible high field strength elements (HFSEs). Relative enrichment of LREEs and HFSEs increases slightly up-section. The Talkeetna Volcanic Formation is typically more REE depleted than average continental crust, although small volumes of light REE-enriched and heavy REE-depleted mafic lavas are recognized low in the stratigraphy. The Talkeetna Volcanic Formation was formed in an intraoceanic arc above a north-dipping subduction zone and contains no preserved record of its subsequent collisions with Wrangellia or North America. ?? 2005 Geological Society of America.

  3. The Dras arc: two successive volcanic events on eroded oceanic crust

    Science.gov (United States)

    Reuber, Ingrid

    1989-04-01

    The Dras arc is recognized as a volcanic arc system in the western part of the Indus suture zone and it constitutes the link between the Ladakh batholith and the Kohistan arc. This study is based on detailed mapping of the area between Dras, Kargil and Sanku which revealed the following: (1) The ultramafics of Dras and Thasgam can be followed across the Suru Dras ridge and are not intrusive into the arc volcanics, but instead constitute the most probably oceanic substratum of these volcanics. (2) Successive volcanic events are distinguished: (a) Dras I is a variable volcaniclastic series rich in slates and carbonates, which can probably be assigned to the Albo-Cenomanian, as dated by orbitolines. This series is intruded by gabbro, diorite and granite and is deformed, essentially in the northern part. It is unconformably overlain by (b) the Dras II pyroclastics which grade southward into volcanic breccia and thus enable the location of the centres of volcanic activity during this younger period.

  4. The volcanic response to deglaciation: Evidence from glaciated arcs and a reassessment of global eruption records

    Science.gov (United States)

    Watt, Sebastian F. L.; Pyle, David M.; Mather, Tamsin A.

    Several lines of evidence have previously been used to suggest that ice retreat after the last glacial maximum (LGM) resulted in regionally-increased levels of volcanic activity. It has been proposed that this increase in volcanism was globally significant, forming a substantial component of the post-glacial rise in atmospheric CO2, and thereby contributing to climatic warming. However, as yet there has been no detailed investigation of activity in glaciated volcanic arcs following the LGM. Arc volcanism accounts for 90% of present-day subaerial volcanic eruptions. It is therefore important to constrain the impact of deglaciation on arc volcanoes, to understand fully the nature and magnitude of global-scale relationships between volcanism and glaciation. The first part of this paper examines the post-glacial explosive eruption history of the Andean southern volcanic zone (SVZ), a typical arc system, with additional data from the Kamchatka and Cascade arcs. In all cases, eruption rates in the early post-glacial period do not exceed those at later times at a statistically significant level. In part, the recognition and quantification of what may be small (i.e. less than a factor of two) increases in eruption rate is hindered by the size of our datasets. These datasets are limited to eruptions larger than 0.1 km3, because deviations from power-law magnitude-frequency relationships indicate strong relative under-sampling at smaller eruption volumes. In the southern SVZ, where ice unloading was greatest, eruption frequency in the early post-glacial period is approximately twice that of the mid post-glacial period (although frequency increases again in the late post-glacial). A comparable pattern occurs in Kamchatka, but is not observed in the Cascade arc. The early post-glacial period also coincides with a small number of very large explosive eruptions from the most active volcanoes in the southern and central SVZ, consistent with enhanced ponding of magma during

  5. Ages and geochemical comparison of coeval plutons and volcanics from the central and eastern Aleutian arc

    Science.gov (United States)

    Cai, Y.; Kelemen, P. B.; Goldstein, S. L.; Yogodzinski, G. M.; Hemming, S. R.; Rioux, M. E.; Cooperdock, E. H. G.

    2016-12-01

    On average, arc volcanics are compositionally different from the bulk continental crust. The relatively little known plutonic part of intra-oceanic arcs is more similar to continental crust, and may play a significant role for understanding continental crust formation. Our pilot study [1] demonstrated that in the central and eastern Aleutian islands, predominantly tholeiitic Quaternary volcanic rocks have statistically different Pb-Nd-Sr-Hf isotopic signatures than predominantly calc-alkaline Miocene and older plutonic rocks, showing that these plutonics and volcanics were derived from compositionally different sources. However, studies of older volcanics are needed to determine whether (1) there was a change in magma chemistry in the central and eastern Aleutian arc between the Miocene and the present-day, or (2) coeval plutonics and volcanics are compositionally different, and formed by different processes. For example, silica- and water-rich calc-alkaline magmas may preferentially stall and form plutons after extensive degassing and rapid viscosity increase in the mid-crust, while silica- and water-poor tholeiitic magmas tend to erupt at the surface. Here we report new geochronological and geochemical results on samples collected during the 2015 GeoPRISMS shared logistics field campaign. We collected more than 500 volcanic and plutonic samples from Unalaska, Umnak and Atka islands, including pillow lavas, sills, and larger plutons. A subset of 50 samples has been analyzed for major and trace element chemistry, Pb-Nd-Sr-Hf isotopes, and Ar-Ar geochronology. So far,40Ar/39Ar cooling dates measured for the volcanics span a wide range, from zero to 35 Ma, which is comparable to the age distribution of the plutons ( 9 Ma to 39 Ma) from these islands. The forthcoming, combined geochronology and geochemistry of coeval plutonics and volcanics will contribute to our understanding of the connections between arc magmatism and continental crust formation. [1] Cai et al

  6. Geochemical variations in the Quaternary Andean back-arc volcanism, southern Mendoza, Argentina

    Science.gov (United States)

    Espanon, Venera R.; Chivas, Allan R.; Kinsley, Leslie P. J.; Dosseto, Anthony

    2014-11-01

    The Payenia Basaltic Province (PBP) is located 450 km east of the Chile-Peru trench in central west Argentina, behind the Andean arc front, constituting the back-arc. In order to evaluate the influence of the subducting slab as well as the magmatic source of this region, two volcanic fields located at comparable distance to the trench, having abundant basaltic products and similar eruptive timeframes were chosen. The Llancanelo (LLVF) and the Payún Matrú (PMVF) volcanic fields are part of the PBP and exhibit abundant basaltic activity during the Pleistocene. The geochemical data suggest that the LLVF has some arc signatures which have been described as weak as they are not as pronounced as in the Andean arc. The weak arc signature is not derived from slab dehydration as high Th enrichment relative to U cannot be explained by this process. We relate the Th enrichment as well as the lack of large residual garnet signatures, to slab sediments in the source. In the case of the PMVF, no arc signature has been inferred despite being only 30 km south of the LLVF. However the PMVF has a composition similar to that of the local intraplate end member, represented by the Rio Colorado volcanic field. The two volcanic fields, LLVF and PMVF, show indications of lower crustal assimilation as they trend towards the lower continental crust end member in Nb/U vs Ce/Pb and Nb/Yb vs Th/Yb diagrams. The geochemical differences between the LLVF and the PMVF as well as between several volcanic fields are illustrated using spatial distribution maps of geochemical ratios. Using this new approach, the decrease in arc signature can be traced in the back-arc and the higher enrichment in high field strength elements (HFSE) relative to large ion lithophile elements (LILE) in the PMVF compared to the LLVF is explicitly shown. These geospatial maps provide a graphical manner to illustrate the presence of two distinct types of volcanism (OIB-like and arc-like) occurring in the same Quaternary

  7. Spatial distribution of helium isotopes in volcanic gases and thermal waters along the Vanuatu (New Hebrides) volcanic arc

    Science.gov (United States)

    Jean-Baptiste, P.; Allard, P.; Fourré, E.; Bani, P.; Calabrese, S.; Aiuppa, A.; Gauthier, P. J.; Parello, F.; Pelletier, B.; Garaebiti, E.

    2016-08-01

    We report the first helium isotope survey of volcanic gases, hot springs and some olivine phenocrysts along the Vanuatu island arc, from Tanna in the south to Vanua Lava in the north. Low CO2 content and low 3He/4He ratios in thermal fluids of Epi (4.0 ± 0.1 Ra), Efate (4.5 ± 0.1 Ra) and Pentecost (5.3 ± 0.5 Ra) islands coherently indicate reduced mantle gas leakage and crustal contamination by radiogenic helium on these extinct volcanic systems of the former (Pliocene) arc. Instead, presently active Vanuatu volcanoes display 3He/4He and C/3He ratios typical of subduction-related volcanic arcs: 3He/4He ratios range from 6.4 ± 0.5 Ra in southernmost Tanna and 7.23 ± 0.09 Ra in northernmost Vanua Lava to typical MORB values in the central islands of Gaua (7.68 ± 0.06 Ra), Ambrym (7.6 ± 0.8 Ra) and Ambae (7 ± 2 Ra in groundwaters, 7.9 ± 1.4 Ra in olivine phenocrysts, and 8.0 ± 0.1 Ra in summit fumaroles of Aoba volcano). On Ambrym, however, we discover that hydrothermal manifestations separated by only 10-15 km on both sides of a major E-W transverse fault zone crossing the island are fed by two distinct helium sources, with different 3He/4He signatures: while fluids in southwest Ambrym (Baiap and Sesivi areas) have typical arc ratios (7.6 ± 0.8 Ra), fluids on the northwest coast (Buama Bay area) display both higher 3He/4He ratios (9.8 ± 0.2 Ra in waters to 10.21 ± 0.08 Ra in bubbling gases) and lower C/3He ratios that evidence a hotspot influence. We thus infer that the influx of Indian MORB mantle beneath the central Vanuatu arc, from which Ambrym magmas originate, also involves a 3He-rich hotspot component, possibly linked to a westward influx of Samoan hotspot material or another yet unknown local source. This duality in magmatic He source at Ambrym fits with the bimodal composition and geochemistry of the erupted basalts, implying two distinct magma sources and feeding systems. More broadly, the wide He isotopic variations detected along the Vanuatu

  8. Evidence for voluminous bimodal pyroclastic volcanism during rifting of a Paleoproterozoic arc at Snow Lake, Manitoba

    National Research Council Canada - National Science Library

    Lafrance, Bruno; Rubingh, Kate E; Gibson, Harold L

    2017-01-01

    ...) assemblage of the Flin Flon belt. Stratigraphic correlation of volcanic strata of the MB sequence with strata of the thrust-bounded Chisel sequence indicates that distinctive, submarine, eruption-fed, pyroclastic flow deposits...

  9. Postcaldera volcanism and hydrothermal activity revealed by autonomous underwater vehicle surveys in Myojin Knoll caldera, Izu-Ogasawara arc

    Science.gov (United States)

    Honsho, Chie; Ura, Tamaki; Kim, Kangsoo; Asada, Akira

    2016-06-01

    Myojin Knoll caldera, one of the submarine silicic calderas lying on the volcanic front of the northern Izu-Ogasawara arc, has attracted increasing attention since the discovery of a large hydrothermal field called the Sunrise deposit. Although numerous submersible surveys have been conducted in Myojin Knoll caldera, they have not sufficiently explored areas to produce a complete picture of the caldera and understand the origin of the Sunrise deposit. We conducted comprehensive deep-sea surveys using an autonomous underwater vehicle and obtained high-resolution bathymetric and magnetic data and sonar images from ~70% of the caldera. The detailed bathymetric map revealed that faulting and magma eruptions, possibly associated with an inflation-deflation cycle of the magma reservoir during postcaldera volcanism, had generally occurred in the caldera wall. The main dome of the central cone was covered with lava flows and exhibits exogenous growth, which is unusual for rhyolitic domes. The magnetization distribution in the central cone indicates preferential magma intrusion along a NW-SE direction. It is presumed that magma migrated along this direction and formed a rhyolite dome at the foot of the southeastern caldera wall, where the Sunrise deposit occurs. The Sunrise deposit is composed mainly of three ridges extending in slope directions and covers ~400 × ~400 m. Magnetization reduction in the deposit area is small, indicating that the alteration zone beneath the Sunrise deposit is slanting rather than vertical. It is presumed that several slanting and near-vertical volcanic vents serve as pathways of hydrothermal fluid in Myojin Knoll caldera.

  10. Magmatism and Epithermal Gold-Silver Deposits of the Southern Ancestral Cascade Arc, Western Nevada and Eastern California

    Science.gov (United States)

    John, David A.; du Bray, Edward A.; Henry, Christopher D.; Vikre, Peter

    2015-01-01

    Many epithermal gold-silver deposits are temporally and spatially associated with late Oligocene to Pliocene magmatism of the southern ancestral Cascade arc in western Nevada and eastern California. These deposits, which include both quartz-adularia (low- and intermediate-sulfidation; Comstock Lode, Tonopah, Bodie) and quartz-alunite (high-sulfidation; Goldfield, Paradise Peak) types, were major producers of gold and silver. Ancestral Cascade arc magmatism preceded that of the modern High Cascades arc and reflects subduction of the Farallon plate beneath North America. Ancestral arc magmatism began about 45 Ma, continued until about 3 Ma, and extended from near the Canada-United States border in Washington southward to about 250 km southeast of Reno, Nevada. The ancestral arc was split into northern and southern segments across an inferred tear in the subducting slab between Mount Shasta and Lassen Peak in northern California. The southern segment extends between 42°N in northern California and 37°N in western Nevada and was active from about 30 to 3 Ma. It is bounded on the east by the northeast edge of the Walker Lane. Ancestral arc volcanism represents an abrupt change in composition and style of magmatism relative to that in central Nevada. Large volume, caldera-forming, silicic ignimbrites associated with the 37 to 19 Ma ignimbrite flareup are dominant in central Nevada, whereas volcanic centers of the ancestral arc in western Nevada consist of andesitic stratovolcanoes and dacitic to rhyolitic lava domes that mostly formed between 25 and 4 Ma. Both ancestral arc and ignimbrite flareup magmatism resulted from rollback of the shallowly dipping slab that began about 45 Ma in northeast Nevada and migrated south-southwest with time. Most southern segment ancestral arc rocks have oxidized, high potassium, calc-alkaline compositions with silica contents ranging continuously from about 55 to 77 wt%. Most lavas are porphyritic and contain coarse plagioclase

  11. Transient magmatic control in a tectonic domain: the central Aeolian volcanic arc (South Italy)

    KAUST Repository

    Ruch, Joel

    2015-04-01

    The background stress field in volcanic areas may be overprinted by that produced by transient magmatic intrusions, generating local faulting. These events are rarely monitored and thus not fully understood, generating debate about the role of magma and tectonics in any geodynamic setting. Here we carried out a field structural analysis on the NNW-SSE strike-slip system of the central Aeolian Arc, Italy (Lipari and Vulcano islands) with ages constrained by stratigraphy to better capture the tectonic and magmatic evolution at the local and regional scales. We consider both islands as a single magmatic system and define 5 principal stratigraphic units based on magmatic and tectonic activity. We collected >500 measurements of faults, extension fractures and dikes at 40 sites, mostly NNE-SSW to NNW-SSE oriented with a dominant NS orientation. These structures are governed quasi exclusively by pure dip-slip motion, consistent with an E-W extension direction, with minor dextral and sinistral slip, the latter being mostly related to old deposits (>50 ka). We further reconstructed the evolution of the Vulcano-Lipari system during the last ~20 ka and find that it consists of an overall half-graben-like structure, with faults with predominant eastward dips. Field evidence suggests that faulting occurs often in temporal and spatial relation with magmatic events, suggesting that most of the observable deformation derived from transient magmatic activity, rather than from steady regional tectonics. To explain the dominant magmatic and episodic extension in a tectonic dominant domain, we propose a model where the regional N-S trending maximum horizontal stress, responsible for strike-slip activity, locally rotates to vertical in response to transient pressurization of the magmatic system and magma rise below Lipari and Vulcano. This has possibly generated the propagation of N-S trending dikes in the past 1 ka along a 10 km long by 1 km wide crustal corridor, with important

  12. Arc-related porphyry molybdenum deposit model: Chapter D in Mineral deposit models for resource assessment

    Science.gov (United States)

    Taylor, Ryan D.; Hammarstrom, Jane M.; Piatak, Nadine M.; Seal, Robert R., II

    2012-01-01

    This report provides a descriptive model for arc-related porphyry molybdenum deposits. Presented within are geological, geochemical, and mineralogical characteristics that differentiate this deposit type from porphyry copper and alkali-feldspar rhyolite-granite porphyry molybdenum deposits. The U.S. Geological Survey's effort to update existing mineral deposit models spurred this research, which is intended to supplement previously published models for this deposit type that help guide mineral-resource and mineral-environmental assessments.

  13. Significance of an Active Volcanic Front in the Far Western Aleutian Arc

    Science.gov (United States)

    Yogodzinski, G. M.; Kelemen, P. B.; Hoernle, K.

    2015-12-01

    Discovery of a volcanic front west of Buldir Volcano, the western-most emergent Aleutian volcano, demonstrates that the surface expression of Aleutian volcanism falls below sea level just west of 175.9° E longitude, but is otherwise continuous from mainland Alaska to Kamchatka. The newly discovered sites of western Aleutian seafloor volcanism are the Ingenstrem Depression, a 60 km-long structural depression just west of Buldir, and an unnamed area 300 km further west, referred to as the Western Cones. These locations fall along a volcanic front that stretches from Buldir to Piip Seamount near the Komandorsky Islands. Western Aleutian seafloor volcanic rocks include large quantities of high-silica andesite and dacite, which define a highly calc-alkaline igneous series and carry trace element signatures that are unmistakably subduction-related. This indicates that subducting oceanic lithosphere is present beneath the westernmost Aleutian arc. The rarity of earthquakes below depths of 200 km indicates that the subducting plate is unusually hot. Some seafloor volcanoes are 6-8 km wide at the base, and so are as large as many emergent Aleutian volcanoes. The seafloor volcanoes are submerged in water depths >3000 m because they sit on oceanic lithosphere of the Bering Sea. The volcanic front is thus displaced to the north of the ridge of arc crust that underlies the western Aleutian Islands. This displacement, which developed since approximately 6 Ma when volcanism was last active on the islands, must be a consequence of oblique convergence in a system where the subducting plate and large blocks of arc crust are both moving primarily in an arc-parallel sense. The result is a hot-slab system where low subduction rates probably limit advection of hot mantle to the subarc, and produce a relatively cool and perhaps stagnant mantle wedge. The oceanic setting and highly oblique subduction geometry also severely limit rates of sediment subduction, so the volcanic rocks, which

  14. Volcanic-hosted massive sulfide deposits in the Murchison greenstone belt, South Africa

    Science.gov (United States)

    Schwarz-Schampera, Ulrich; Terblanche, Hennie; Oberthür, Thomas

    2010-02-01

    The Archean Murchison greenstone belt, Limpopo Province, South Africa, represents a rifted epicontinental arc sequence containing the largest volcanic-hosted massive sulfide (VMS) district in Southern Africa. The so-called Cu-Zn line is host to 12 deposits of massive sulfide mineralization including: Maranda J, LCZ, Romotshidi, Mon Desir, Solomons, and Mashawa with a total tonnage of three million metric tons of very high grade Zn, subordinate Cu, and variable Pb and Au ore. The deposits developed during initial phases of highly evolved felsic volcanism between 2,974.8 ± 3.6 and 2,963.2 ± 6.4 Ma and are closely associated with quartz porphyritic rhyolite domes. Elevated heat supply ensured regional hydrothermal convection along the entire rift. Recurrent volcanism resulted in frequent disruption of hydrothermal discharge and relative short-lived episodes of hydrothermal activity, probably responsible for the small size of the deposits. Stable thermal conditions led to the development of mature hydrothermal vent fields from focused fluid discharge and sulfide precipitation within thin layers of felsic volcaniclastic rocks. Two main ore suites occur in the massive sulfide deposits of the “Cu-Zn line”: (1) a low-temperature venting, polymetallic assemblage of Zn, Pb, Sb, As, Cd, Te, Bi, Sn, ±In, ±Au, ±Mo occurring in the pyrite- and sphalerite-dominated ore types and (2) a higher temperature suite of Cu, Ag, Au, Se, In, Co, Ni is associated with chalcopyrite-bearing ores. Sphalerite ore, mineralogy, and geochemical composition attest to hydrothermal activity at relatively low temperatures of ≤250 °C for the entire rift, with short-lived pulses of higher temperature upflow, reflected by proportions of Zn-rich versus Cu-rich deposits. Major- and trace-metal composition of the deposits and Pb isotope signatures reflect the highly evolved felsic source rock composition. Geological setting, host rock composition, and metallogenesis share many similarities not

  15. Systematic Osmium Isotope Binary Mixing Arrays in Arc Volcanism

    Science.gov (United States)

    Alves, S.; Alves, S.; Schiano, P.; Capmas, F.; Allegre, C. J.

    2001-12-01

    Isotopic and geochemical studies on subduction-related lavas aim at constraining the nature of their mantle sources and the respective roles of source heterogeneity and petrogenetic processes in their compositions. Many components are potentially involved in producing the geochemical signatures of arc lavas: depleted mantle, subducted oceanic crust and sediments, and the overlying continental or oceanic crust. A further complication in characterizing mantle sources of arc lavas is complex mixing of some component parts via derivative fluids or melts released from the slab. Os isotope ratios are potential tracers of slab contribution in arc lavas because 1) subducted sediments are very radiogenic in Os compared to the upper mantle, and 2) Re behaves as a moderately incompatible element during mantle partial melting, whereas Os is highly compatible. Therefore, MORB have much higher Re/Os ratios than peridotites. Consequently, old oceanic crust is likely to be extremely more radiogenic than the depleted upper mantle so that recycled basaltic components should be identified by their elevated 187Os/188Os ratios. Os isotope ratios and Os and Re concentrations have been measured in 55 lavas coming from 10 different subduction zones. Samples span a large range of major element concentrations (from basalts to dacites) and Mg# (from 0.32 to 0.81). The 10 subduction zones, namely the Lesser Antilles, Java, Papua-New Guinea, the Philippines, Izu-Bonin, Kamchatka, the Aleutians, Mexico, Colombia and Peru-Chile, have a range of basement nature and thickness, as well as a range of age and sediment cover of the subducting plate. Measured 187Os/188Os ratios range from 0.130 to 1.524 and Os concentrations range from 0.048 to 46 ppt. Re concentrations range from 37 to 915 ppt. Os initial isotope ratios are systematically positively and linearly correlated with the inverse of Os concentrations in arc lavas from a given volcano, indicating that the Os isotopic compositions always

  16. From northern Gondwana passive margin to arc dismantling: a geochemical discrimination of Ordovician volcanisms (Sardinia, Italy)

    Science.gov (United States)

    Gaggero, L.; Oggiano, G.; Buzzi, L.; Funedda, A.

    2009-04-01

    In Sardinia, one of the southernmost remain of the European Variscan belt, a crustal section through northern Gondwanan paleodomains is largely preserved. It bears significant evidence of igneous activity, recently detailed in field relationships and radiometric dating (Oggiano et al., submitted). A Cambro - Ordovician (491.7 ± 3.5 Ma ÷ 479.9 ± 2.1 Ma, LA-ICP-MS U-Pb zircon age) bimodal volcanic suite occurs with continuity in external and inner Variscan nappes of Sardinia below the so-called Sardic unconformity. The igneous suite represents an intraplate volcanic activity developed through subsequent episodes: i) an intermediate explosive and effusive volcanism, i.e. pyroclastic fall deposits and lava flows, embedded into epicontinental clastic sediments, culminating in silicic ignimbrite eruptions, and ii) mafic effusives. Geochemical data document a transitional, within-plate signature, e.g. the average Th/Ta (4.5) and La/Nb (2.7) overlap the upper continental crust values. The volcanites are characterized by slight fractionation of LREEs, nearly flat HREE abundance. The negative Eu anomaly increases towards evolved compositions. Some prominent HREE depletion (GdCN/YbCN = 13.8), and the high Nb/Y suggest a garnet-bearing source. The high 87Sr radiogenic content (87Sr/86Sr 490 Ma = 0.71169) and the epsilon Nd 490 Ma value of -6.54 for one dacite sample, imply a time integrated LREE-enriched source with a high Rb/Sr, such as a metasedimentary source. The stratigraphy of the succession and the geochemical composition of igneous members suggest a volcanic passive margin along the northern Gondwana at the early Ordovician. The bimodal Mid-Ordovician arc volcanism (465.4 ± 1.4 Ma, U-Pb zircon age; Oggiano et al., submitted) is developed in the external nappes (e.g. in Sarrabus and Sarcidano) and in the foreland occurs as clasts at the base of the Hirnantian succession (Leone et al. 1991). The Mid Ordovician sub-alkalic volcanic suite has reliable stratigraphic and

  17. Physical Properties of Volcanic Deposits on Venus from Radar Polarimetry

    Science.gov (United States)

    Carter, Lynn M.; Campbell, Donald B.; Campbell, Bruce A.

    2005-01-01

    Studies of the morphology and radar properties of volcanic deposits can aid in understanding their differences and formation. On Venus, volcanoes range in size from large highland edifices, such as Theia Mons, to small shields and domes which are often found in groups of tens to hundreds. In plains regions, windstreaks are sometimes found near shield fields, suggesting that there may be fine grained deposits associated with the volcanoes. Previous studies of Bell Regio suggest the presence of fine-grained material in a low dielectric constant triangular shaped region on the flank of Tepev Mons, which may be crater ejecta or a pyroclastic deposit spread westward by wind. The eastern caldera on Tepev Mons shows a steep trend in backscattered power with incidence angle and has high RMS-slopes, implying a finegrained covering such as ash. Radar waves can easily penetrate smooth mantling layers such as ash and aeolian deposits. If a radar system can measure two orthogonal polarizations, it is possible to detect subsurface scattering and infer the presence of surficial deposits. The Magellan spacecraft could only measure one polarization and was therefore not able to fully characterize the polarization state of the radar echoes. We compare Arecibo dual-polarization data for Venus to Magellan images and emissivity data to investigate the physical properties of volcanic deposits.

  18. Gas venting rates from submarine hydrothermal areas around the island of Milos, Hellenic Volcanic Arc

    Science.gov (United States)

    Dando, P. R.; Hughes, J. A.; Leahy, Y.; Niven, S. J.; Taylor, L. J.; Smith, C.

    1995-07-01

    Gas seeps were located, by echo sounding, SCUBA divers and ROV observations, at hydrothermal sites around the island of Milos, in the Hellenic Volcanic Arc. Samples were collected by SCUBA divers and by a ROV from water depths between 3 and 110 m. Fifty-six flow rates from 39 individual seeps were measured and these ranged from 0.2 to 18.51 h -1 at the depth of collection. The major component, 54.9-91.9% of the gas, was carbon dioxide. Hydrogen (≤3%), methane (≤9.7%) and hydrogen sulphide (≤8.1%) were also measured. Hydrothermal free gas fluxes from the submarine hydrothermal areas around Milos were estimated to be greater than 10 10 moles y -1. It was concluded that submarine gas seeps along volcanic island arcs may be an important carbon dioxide source.

  19. Three Filtered Vacuum Arc Plasma Sources Deposition & Implantation System

    Institute of Scientific and Technical Information of China (English)

    WU Xian-ying; ZHANG Hui-xing; LI Qiang

    2004-01-01

    A deposition & implantation system, which includes three filtered vacuum arc plasma sources, has been built. Vacuum arc discharge is used to produce high-density metal plasma; Curved magnetic filtering technique is used to transfer the plasma into out-of-sight vacuum chamber and reduce macro-particles from the vacuum arc plasma in order to drastically reduce the macro-particles contamination of the films. The up to 30 kV negative bias applied to the target can be used for ion implantation in order to improve the film adhesion; or for ion sputtering to clear the substrate surface. The 0 to 300 V negative bias can be used to adjust the ion energy which forming films. The system is designed for various thin films synthesizing, such as single-layer, compound layer, multi-layer films. It's principle, components and applications are described in the literature.

  20. FUNDAMENTAL PROBLEMS IN PULSED-BIAS ARC DEPOSITION

    Institute of Scientific and Technical Information of China (English)

    G.Q.Lin; Z.F.Ding; D.Qi; N.H.Wang; M.D.Huang; D.Z.Wang; Y.N.Wang; C.Dong; L.S.Wen

    2002-01-01

    Arc deposition, a widely used surface coating technique, has disadvantages such aslarge droplet size and high deposition temperature. Recent trend in its renovation isthe introduction of pulsed bias at the substrate. The present paper attempts to describethe deposition process of TiN films using this technique with emphasis laid on theunderstanding of the basic problems such as discharge plasma properties, temperaturecalculation, and droplet size reduction. We show that this technique improves thefilm microstructure and quality, lowers deposition temperature, and allows coatingson insulating substrates. After analyzing load current oscillation behaviors, we havedetermined that the plasma load is of capacitance nature due to plasma sheath and thatit is equivalent to a circuit element consisting of parallel capacitance and resistance.At last, we point out the remaining problems and future development of the pulsed-biasarc deposition technique.

  1. Early Permian arc-related volcanism and sedimentation at the western margin of Gondwana:Insight from the Choiyoi Group lower section

    Institute of Scientific and Technical Information of China (English)

    Leonardo Strazzere; Daniel A. Gregori; Leonardo Benedini

    2016-01-01

    Permian sedimentary and basic to intermediate volcanic rocks assigned to the Conglomerado del Río Blanco and Portezuelo del Cenizo Formation, lower part of the Choiyoi Group, crop out between the Cordon del Plata, Cordillera Frontal and Precordillera of Mendoza Province, Argentina. The sedimentary rocks are represented by six lithofacies grouped in three facies associations. They were deposited by mantled and gravitational flows modified by high-energy fluvial currents that evolved to low-energy fluvial and lacustrine environments. They constitute the Conglomerado del Río Blanco, which cover unconformably marine Carboniferous sequences. Five volcanic and volcaniclastic facies make up the beginning of volcanic activity. The first volcanic event in the Portezuelo del Cenizo is basaltic to andesitic lava-flows emplaced in the flanks of volcanoes. Lava collapse produced thick block and ash flows. Interbedding in the intermediate volcanic rocks, there are dacites of different geochemical signature, which indicate that the development of acidic volcanism was coetaneous with the first volcanic activity. The geochemistry of these rocks induces to consider that the Choiyoi Group Lower section belongs to a magmatic arc on continental crust. The age of this section is assigned to the lower Permian (277 ? 3.0 Ma, Kungurian age).

  2. Formation of metal oxides by cathodic arc deposition

    Energy Technology Data Exchange (ETDEWEB)

    Anders, S.; Anders, A.; Rubin, M.; Wang, Z.; Raoux, S.; Kong, F.; Brown, I.G.

    1995-03-01

    Metal oxide thin films are of interest for a number of applications. Cathodic arc deposition, an established, industrially applied technique for formation of nitrides (e.g. TiN), can also be used for metal oxide thin film formation. A cathodic arc plasma source with desired cathode material is operated in an oxygen atmosphere, and metal oxides of various stoichiometric composition can be formed on different substrates. We report here on a series of experiments on metal oxide formation by cathodic arc deposition for different applications. Black copper oxide has been deposited on ALS components to increase the radiative heat transfer between the parts. Various metal oxides such as tungsten oxide, niobium oxide, nickel oxide and vanadium oxide have been deposited on ITO glass to form electrochromic films for window applications. Tantalum oxide films are of interest for replacing polymer electrolytes. Optical waveguide structures can be formed by refractive index variation using oxide multilayers. We have synthesized multilayers of Al{sub 2}O{sub 3}/Y{sub 2}O{sub 3}/AI{sub 2}O{sub 3}/Si as possible basic structures for passive optoelectronic integrated circuits, and Al{sub 2-x}Er{sub x}O{sub 3} thin films with a variable Er concentration which is a potential component layer for the production of active optoelectronic integrated devices such as amplifiers or lasers at a wavelength of 1.53 {mu}m. Aluminum and chromium oxide films have been deposited on a number of substrates to impart improved corrosion resistance at high temperature. Titanium sub-oxides which are electrically conductive and corrosion resistant and stable in a number of aggressive environments have been deposited on various substrates. These sub-oxides are of great interest for use in electrochemical cells.

  3. Constraints on the origin and evolution of magmas in the Payún Matrú Volcanic Field, Quaternary Andean Back-arc of Western Argentina

    NARCIS (Netherlands)

    Hernando, I.R.; Aragón, E.; Frei, R.; González, P.D.; Spakman, W.

    2014-01-01

    The Payún Matrú Volcanic Field (Pleistocene–Holocene) is located in the Andean back-arc of the Southern Volcanic Zone, western Argentina, and is contemporaneous with the Andean volcanic arc at the same latitude. It includes two polygenetic, mostly trachytic volcanoes: Payún Matrú (with a summit cald

  4. Colonisation of freshly deposited volcanic tephra by soil fungi

    Science.gov (United States)

    Tarasenko, Inga; Opfergelt, Sophie; Stenuit, Benoît; Daily, Hélène; Bonneville, Steeve; Müller, Dirk; Delmelle, Pierre

    2016-04-01

    In active volcanic regions, soils are repeatedly exposed to eruption products, notably tephra emissions. Deposition of volcanic tephra on soil may modify water and gas exchanges between the soil surface and the atmosphere. Through chemical weathering, the silicate glass and mineral components of freshly deposited tephra act as a source of bioavailable potassium and phosphorus. In addition, opportunist fungi may be able to enhance access to these elements via physical and biochemical processes. Altogether, tephra deposition has the potential to affect biological activity and hence, nutrient cycling in the buried soil. Here we present the preliminary results of an ongoing investigation aimed at shedding light on the interaction of soil fungi with freshly deposited tephra. The study site (elevation - 1755 m a.s.l.) is a coniferous forest on the northeastern slope of Etna volcano, Sicily, which received about 20 cm of tephra in November 2013. Soil and tephra samples were collected in September 2014 and October 2015. A variety of biological, chemical and mineralogical analyses were carried out to determine fungal biomass, fungi species and tephra weathering stage. Colonisation of the fresh tephra by fungi is evidenced by the high fungal biomass measured in this material. DNA analyses further indicate that these fungi originate from the soil beneath the tephra layer. While chemical weathering of the tephra material has started, there is no clear indication that fungi colonisation is enhancing this process. We will continue to monitor fungi-tephra interaction on Etna during the next few years.

  5. Bioindication of volcanic mercury (Hg) deposition around Mt Etna (Sicily)

    Science.gov (United States)

    Martin, R.; Witt, M. L.; Sawyer, G. M.; Watt, S.; Bagnato, E.; Calabrese, S.; Aiuppa, A.; Delmelle, P.; Pyle, D. M.; Mather, T. A.

    2012-12-01

    Mt. Etna is a major natural source of Hg to the Mediterranean region. Total mercury concentrations, [Hg]tot, in Castanea sativa (sweet chestnut) leaves sampled 7-13 km from Etna's vents (during six campaigns in 2005-2011) were determined using atomic absorption spectroscopy. [Hg]tot in C. sativa was greatest on Etna's SE flank reflecting Hg deposition from the typically overhead volcanic plume. When adjusted for leaf age, [Hg]tot in C. sativa also increased with recent eruptive activity. [Hg]tot in C. sativa was not controlled by [Hg]tot in soils, which instead was greatest on the (upwind) NW flank and correlated strongly with soil organic matter (% Org). Our results suggest that at least ~1% of Hg emitted from Etna is deposited proximally, supporting recent measurement and model results which indicate that GEM (Hg0; the dominant form of Hg in high temperature magmatic gases) is oxidised rapidly to RGM and Hgp in ambient temperature volcanic plumes. Samples of C. sativa and soils were also collected in July and September 2012 alongside SO2 and acid gas diffusion tube samples. These new samples will enable us to investigate Hg accumulation over a single growth season with reference to the exposure of vegetation to volcanic gases and particles.

  6. Temporal and geochemical evolution of Miocene volcanism in the Andean back-arc between 36°S and 38°S and U-series analyses of young volcanic centers in the arc and back-arc, Argentina

    DEFF Research Database (Denmark)

    Dyhr, Charlotte Thorup

    New 40Ar/39Ar, major and trace element, and Sr, Nd and Pb isotopic data for the c. 24-7 Ma volcanic rocks from the Andean back-arc (35°S – 38°S) in the Mendoza and Neuquén (Argentina) regions shed light on the Miocene evolution of the back-arc of the Southern Volcanic Zone. Incipient shallowing...... lasting from ~17 to ~9 Ma. The reoccurrence of extensive magmatism in the Sierra de Palaoco provides evidence for a retreat of the shallow subduction zone towards the west during the Late Miocene. Evidence for the ending of the time of flat subduction comes from major- and trace element chemistry and Nd...

  7. The Dras arc Complex: lithofacies and reconstruction of a Late Cretaceous oceanic volcanic arc in the Indus Suture Zone, Ladakh Himalaya

    Science.gov (United States)

    Robertson, Alastair; Degnan, Paul

    1994-08-01

    The purpose of this paper is to give an integrated description and interpretation of mainly volcaniclastic sediments related to excellently exposed oceanic volcanic arc successions in the Ladakh Himalayas. The mainly Late Cretaceous (Aptian—Paleocene?) Dras arc Complex in the Indus Suture Zone (N. India) is reconstructed as an oceanic arc, passing southwards into a proximal to distal forearc apron. The arc complex comprises three structural units. From west to east these are the Suru unit, the Naktul unit and the Nindam Formation. The Suru unit and the Naktul unit are unconformably underlain by dissected Late Jurassic? oceanic crust and mantle. The Suru unit preserves the interior of the arc and is divided into Dras 1 and Dras 2 sub-units. The Dras 1 Sub-unit, of mid-Late Cretaceous age, was intruded by arc plutonics, deformed, then unconformably overlain by the poorly dated Dras 2 Sub-unit (Lower Tertiary). The Dras 1 Sub-unit comprises arc extrusives, volcaniclastic and tuffaceous sedimentary rocks, and mainly redeposited shallow-water limestones. The Dras 2 Sub-unit is dominated by coarse volcaniclastics and lava flows, passing up into rhythmically layered acidic extrusives, with interbedded turbiditic siltstones and siliceous pelagic limestones. Further east, the Naktul unit is mainly clastic, with large volumes of massive volcaniclastic talus, thick-bedded debris flows, volcaniclastic turbidites and reworked shallow-water carbonates. Pillowed extrusives and ribbon radiolarites are present, mainly low in the succession in some areas, while pelagic carbonates are abundant near the top. The Naktul unit is interpreted as a proximal forearc apron. The Nindam Formation in the east is dominated by deep-water volcaniclastic turbidites, tuffaceous sediments and pelagic carbonates, with subordinate debris flows and is interpreted as a distal deep-water forearc succession. Cyclical alternations of mainly volcaniclastics and pelagic carbonates in the Nindam Formation

  8. Western Eisila Regio, Venus - Radar properties of volcanic deposits

    Science.gov (United States)

    Campbell, Bruce A.; Campbell, Donald B.

    1990-08-01

    The 1988 Arecibo Observatory dual-polarization radar images are presented for Western Eisila Regio, Venus. The polarization information and Pioneer-Venus Orbiter reflectivity and altimetry data are analyzed for volcanic deposits on two 400-500 km radius constructs, Sif and Gula Montes. Many of the large effusive deposits studied appear to require superposed flows or multiple vents to explain the observed progression of roughness along their length. High Fresnel reflectivity material may be present along the summit region of Gula Mons and in an embayed tessera-like region to the N. Radar-dark units on the flanks of Sif Mons are inferred to be pyroclastic deposits, but radar-dark features near the summits of both edifices are more consistent with very smooth lava flows. Higher spatial resolution Magellan data will be useful in testing these predictions.

  9. Tectonic shortening and coeval volcanism during the Quaternary, Northeast Japan arc

    Indian Academy of Sciences (India)

    Koji Umeda; Masao Ban; Shintaro Hayashi; Tomohiro Kusano

    2013-02-01

    The Northeast Japan arc, a mature volcanic arc with a back-arc marginal basin (Japan Sea), is located on a convergent plate boundary along the subducting Pacific plate and the overriding North American plate. From a compilation and analysis of stratigraphy, radiometric age and data on erupted magma volumes, 176 eruptive episodes identified from 69 volcanoes so far, indicate that notable changes in eruption style, magma discharge rates and distribution of eruptive centres occurred around 1.0 Ma. Before ca.1.0 Ma, large-volume felsic eruptions were dominant, forming large calderas in the frontal arc, a region of low crustal strain rate. After ca. 1.0 Ma to the present, the calc-alkaline andesite magma eruptions in the frontal and rear arcs, synchronous with crustal shortening characterized by reverse faulting, resulted in stratovolcano development along narrow uplifted zones. Although, it is widely assumed that magma cannot rise easily in a compressional setting, some of the magma stored within basal sills could be extruded where N–S-trending uplifted mountains bounded by reverse faults formed since about ca.1.0 Ma.

  10. Arc-rift transition volcanism in the Volcanic Hills, Jacumba and Coyote Mountains, San Diego and Imperial Counties, california

    Science.gov (United States)

    Fisch, Gregory Zane

    Neogene volcanism associated with the subduction of the Farallon-Pacific spreading center and the transition from a subduction zone to a rift zone has been studied extensively in Baja, California, Mexico. One of the main goals of these studies was to find a geochemical correlation with slab windows that may have formed during that complicated transition. While workers have been able to find distinct geochemical signatures in samples from Baja California, none have shown statistically significant correlation with samples from southern California that are thought to be related to the same arc-rift transition events. All of the basaltic samples from this study of southern California rocks have prominent Nb depletions typical of island-arc subduction-related volcanism, in contrast to the chemistry of Baja California volcanics that have trace element patterns typical of synrift related volcanism. The work done by previous investigators has been additionally complicated due to each investigator's choice of important ratios or patterns, which bears little, if any, correlation with work done by others working in the same area. For example, Martin-Barajas et al. (1995) use K/Rb ratios in their study of the Puertocitos Volcanic Province, while Castillo (2008) argues that Sr/Y vs. Y is a better indicator of petrogenetic processes. Little petrologic work has been done on Neogene volcanic rocks in the Imperial Valley and eastern San Diego County region of Southern California. This thesis combines new research with that of previous workers and attempts to establish a better understanding of the processes involved with the transition volcanism. Prior work documents significant differences in the geochemistry between some of these areas, especially those in close proximity to each other (e.g. the Volcanic Hills and Coyote Mountains). These differences were thought to be largely the result different magmatic sources. The potential of finding two differing magma types in close

  11. Geochemical characteristics of island-arc volcanic rocks in the Nan-Nam Pat-Phetchabun zone, northern Thailand

    Institute of Scientific and Technical Information of China (English)

    SHEN Shangyue; FENG Qinglai; YANG Wenqiang; ZHANG Zhibin; Chongpom Chonglakmani

    2010-01-01

    Late Permian-Early Triassic (P2-T1) volcanic rocks distributed on the eastern side of ocean-ridge and oceanic-island basalts in the Nan-Uttaradit zone were analyzed from aspects of petrographic characteristics, rock assemblage, REE, trace elements, geotectonic setting, etc., indicating that those volcanic rocks possess the characteristic features of island-arc volcanic rocks. The volcanic rock assemblage is basalt-basaltic andesite-andesite. The volcanic rocks are sub-alkaline, dominated by calc-alkaline series, with tholeiite series coming next. The chemical composition of the volcanic rocks is characterized by low TiO2 and K2O and high Al2O3 and Na2O. Their REE patterns are of the flat, weak LREE-enrichment right-inclined type. The trace elements are characterized by the enrichment of large cation elements such as K, Rb and Ba, common enrichment of U and Th, and depletion of Nb, Ta, Zr and Hf. The petrochemical plot falls within the field of volcanic rocks, in consistency with the plot of island-arc volcanic rocks in the Jinsha River zone of China. This island-arc volcanic zone, together with the ocean-ridge/oceanic island type volcanic rocks in the Nan-Uttaradit zone, constitutes the ocean-ridge volcanic rock-island-arc magmatic rock zones which are distributed in pairs, indicating that the oceanic crust of the Nan-Uttaradit zone once was of eastward subduction. This work is of great significance in exploring the evolution of paleo-Tethys in the Nan-Uttaradit zone.

  12. Volcanic gas composition, metal dispersion and deposition during explosive volcanic eruptions on the Moon

    Science.gov (United States)

    Renggli, C. J.; King, P. L.; Henley, R. W.; Norman, M. D.

    2017-06-01

    The transport of metals in volcanic gases on the Moon differs greatly from their transport on the Earth because metal speciation depends largely on gas composition, temperature, pressure and oxidation state. We present a new thermochemical model for the major and trace element composition of lunar volcanic gas during pyroclastic eruptions of picritic magmas calculated at 200-1500 °C and over 10-9-103 bar. Using published volatile component concentrations in picritic lunar glasses, we have calculated the speciation of major elements (H, O, C, Cl, S and F) in the coexisting volcanic gas as the eruption proceeds. The most abundant gases are CO, H2, H2S, COS and S2, with a transition from predominantly triatomic gases to diatomic gases with increasing temperatures and decreasing pressures. Hydrogen occurs as H2, H2S, H2S2, HCl, and HF, with H2 making up 0.5-0.8 mol fractions of the total H. Water (H2O) concentrations are at trace levels, which implies that H-species other than H2O need to be considered in lunar melts and estimates of the bulk lunar composition. The Cl and S contents of the gas control metal chloride gas species, and sulfide gas and precipitated solid species. We calculate the speciation of trace metals (Zn, Ga, Cu, Pb, Ni, Fe) in the gas phase, and also the pressure and temperature conditions at which solids form from the gas. During initial stages of the eruption, elemental gases are the dominant metal species. As the gas loses heat, chloride and sulfide species become more abundant. Our chemical speciation model is applied to a lunar pyroclastic eruption model with isentropic gas decompression. The relative abundances of the deposited metal-bearing solids with distance from the vent are predicted for slow cooling rates (<5 °C/s). Close to a volcanic vent we predict native metals are deposited, whereas metal sulfides dominate with increasing distance from the vent. Finally, the lunar gas speciation model is compared with the speciation of a H2O-, CO

  13. Transition of magma genesis estimated by change of chemical composition of Izu-bonin arc volcanism associated with spreading of Shikoku Basin

    Science.gov (United States)

    Haraguchi, S.; Ishii, T.

    2006-12-01

    Arc volcanism in the Izu-Ogasawara arc is separated into first and latter term at the separate of Shikoku Basin. Middle to late Eocene early arc volcanism formed a vast terrane of boninites and island arc tholeiites that is unlike active arc systems. A following modern-style arc volcanism was active during the Oligocene, along which intense tholeiitic and calc-alkaline volcanism continued until 29Ma, before spreading of the back- arc basin. The recent arc volcanism in the Izu-Ogasawara arc have started in the middle Miocene, and it is assumed that arc volcanism were decline during spreading of back-arc basin. In the northern Kyushu-Palau Ridge, submarine bottom materials were dredged during the KT95-9 and KT97-8 cruise by the R/V Tansei-maru, Ocean Research Institute, university of Tokyo, and basaltic to andesitic volcanic rocks were recovered during both cruise except for Komahashi-Daini Seamount where recovered acidic plutonic rocks. Komahashi-Daini Seamount tonalite show 37.5Ma of K-Ar dating, and this age indicates early stage of normal arc volcanism. These volcanic rocks are mainly cpx basalt to andesite. Two pyroxene basalt and andesite are only found from Miyazaki Seamount, northern end of the Kyushu-Palau Ridge. Volcanic rocks show different characteristics from first term volcanism in the Izu-Ogasawara forearc rise and recent arc volcanism. The most characteristic is high content of incompatible elements, that is, these volcanics show two to three times content of incompatible elements to Komahashi-Daini Seamount tonalite and former normal arc volcanism in the Izu outer arc (ODP Leg126), and higher content than recent Izu arc volcanism. This characteristic is similar to some volcanics at the ODP Leg59 Site448 in the central Kyushu- Palau Ridge. Site448 volcanic rocks show 32-33Ma of Ar-Ar ages, which considered beginning of activity of Parece Vela Basin. It is considered that the dredged volcanic rocks are uppermost part of volcanism before spreading of

  14. Sandstone provenance and U-Pb ages of detrital zircons from Permian-Triassic forearc sediments within the Sukhothai Arc, northern Thailand: Record of volcanic-arc evolution in response to Paleo-Tethys subduction

    Science.gov (United States)

    Hara, Hidetoshi; Kunii, Miyuki; Miyake, Yoshihiro; Hisada, Ken-ichiro; Kamata, Yoshihito; Ueno, Katsumi; Kon, Yoshiaki; Kurihara, Toshiyuki; Ueda, Hayato; Assavapatchara, San; Treerotchananon, Anuwat; Charoentitirat, Thasinee; Charusiri, Punya

    2017-09-01

    Provenance analysis and U-Pb dating of detrital zircons in Permian-Triassic forearc sediments from the Sukhothai Arc in northern Thailand clarify the evolution of a missing arc system associated with Paleo-Tethys subduction. The turbidite-dominant formations within the forearc sediments include the Permian Ngao Group (Kiu Lom, Pha Huat, and Huai Thak formations), the Early to earliest Late Triassic Lampang Group (Phra That and Hong Hoi formations), and the Late Triassic Song Group (Pha Daeng and Wang Chin formations). The sandstones are quartzose in the Pha Huat, Huai Thak, and Wang Chin formations, and lithic wacke in the Kiu Lom, Phra That, Hong Hoi and Pha Daeng formations. The quartzose sandstones contain abundant quartz, felsic volcanic and plutonic fragments, whereas the lithic sandstones contain mainly basaltic to felsic volcanic fragments. The youngest single-grain (YSG) zircon U-Pb age generally approximates the depositional age in the study area, but in the case of the limestone-dominant Pha Huat Formation the YSG age is clearly older. On the other hand, the youngest cluster U-Pb age (YC1σ) represents the peak of igneous activity in the source area. Geological evidence, geochemical signatures, and the YC1σ ages of the sandstones have allowed us to reconstruct the Sukhothai arc evolution. The initial Sukhothai Arc (Late Carboniferous-Early Permian) developed as a continental island arc. Subsequently, there was general magmatic quiescence with minor I-type granitic activity during the Middle to early Late Permian. In the latest Permian to early Late Triassic, the Sukhothai Arc developed in tandem with Early to Middle Triassic I-type granitic activity, Middle to Late Triassic volcanism, evolution of an accretionary complex, and an abundant supply of sediments from the volcanic rocks to the trench through a forearc basin. Subsequently, the Sukhothai Arc became quiescent as the Paleo-Tethys closed after the Late Triassic. In addition, parts of sediments of

  15. The Galapagos-OIB signature of the central Costa Rican volcanic front: arc-hotspot interaction

    Science.gov (United States)

    Gazel, E.; Carr, M. J.; Hoernle, K.; Feigenson, M. D.; Hauff, F.; Szymanski, D.; van den Bogaard, P.

    2008-12-01

    Although most Central American magmas have a typical arc geochemical signature, magmas in southern Central America have isotopic and trace element compositions with an OIB affinity, similar to the Galapagos hotspot lavas. Our new data for Costa Rica suggest that this signature, unusual for a convergent margin, has a relatively recent origin (Late Miocene-Pliocene ca. 6 Ma). We also show that there was a transition from typical arc magmas (analogous to the modern Nicaraguan volcanic front) to OIB-like magmas. The geographic distribution of the Galapagos signature in recent lavas from southern Central America is present landward from the subduction of the Galapagos hotspot tracks (the Seamount Province and the Cocos/Coiba Ridges) at the Middle American Trench. The higher Pb isotopic ratios, relatively low Nd isotopic ratios and enriched geochemical signature of central Costa Rican magmas can be explained by arc-hotspot interaction. The isotopic ratios of central Costa Rican lavas require the subducting Seamount Province (Northern Galapagos Domain) component, whereas the isotopic ratios of the adakites and alkaline basalts from southern Costa Rica and Panama are in the geochemical range of the subducting Cocos/Coiba Ridges (Central Galapagos Domain). Geological, geochemical, and isotopic evidence collectively indicate that the relatively recent Galapagos-OIB signature in southern Central America represents a geochemical signal from subducting Galapagos hotspot tracks, which started to collide with the margin ~8 Ma ago. The Galapagos hotspot contribution decreases systematically along the volcanic front from central Costa Rica to NW Nicaragua.

  16. Geodetic Constraints From The Volcanic Arc Of The Andaman - Nicobar Subduction Zone

    Science.gov (United States)

    Earnest, A.; Krishnan, R.; Mayandi, S.; Sringeri, S. T.; Jade, S.

    2012-12-01

    We report first ever GPS derived surface deformation rates in the Barren and Narcondum volcanic islands east of Andaman-Nicobar archipelago which lies in the Bay of Bengal, a zone that generates frequent earthquakes, and coincides with the eastern plate boundary of India. The tectonics of this region is predominantly driven by the subduction of the Indian plate under the Burma plate. Andaman sea region hosts few volcanoes which lies on the inner arc extending between Sumatra and Myanmar with the sub-aerial expressions at Barren and Narcondum Islands. Barren Island, about 135 km ENE of Port Blair, is presently active with frequent eruptive histories whereas Narcondum is believed to be dormant. We initiated precise geodetic campaign mode measurements at Barren Island between 2007 to 2012 and one year (2011-2012) continuous measurements at Narcondum island. Preliminary results from this study forms a unique data set, being the first geodetic estimate from the volcanic arc of this subducting margin. Our analysis indicates horizontal convergence of the Barren benchmark to south-westward (SW) direction towards the Andaman accretionary fore-arc wedge where as the Narcondum benchmark recorded northeast (NE) motion. West of the Andaman fore-arc there is NE oriented subduction of the Indian plate which is moving at the rate of ~5 cm/yr. Convergence rates for the Indian plate from the Nuvel 1A model also show oblique convergence towards N23°E at 5.4 cm/yr. GPS derived inter seismic motion of Andaman islands prior to 2004 Sumatra earthquake is ~4.5 cm/yr NE. The marginal sea basin east of Barren Island at the Andaman spreading ridge has a NNW orienting opening of the sea-floor at 3.6 cm/yr. However the recent post seismic measurements of Andaman islands indicate rotation of displacement vectors from SW to NNE during 2005 to 2012. In this tectonic backdrop, the estimated rate of displacement of the volcanic islands probably represents a composite signal of tectonic as well as

  17. Formation of carbon deposits from coal in an arc plasma

    Energy Technology Data Exchange (ETDEWEB)

    Wang, B.; Tian, Y.; Zhang, Y.; Zhu, S.; Lu, Y.; Zhang, Y.; Xie, K. [Taiyuan University of Technology, Taiyuan (China)

    2007-07-01

    The issue of deposited carbon (DC) on a reactor wall during the production of acetylene by the coal/arc plasma process is a potential obstacle for the industrialization process. The formation mechanism of DC is very difficult to reveal because the high complexity of coal and the volatile matter. Combining with quenching technique, the methane, liquid petroleum gas and benzene were employed as the model materials to roughly act as the light gas, chain and aromatic subcomponents of volatile matter, and then the reasonable formation mechanism of DC was subtly speculated accordingly.

  18. A distinct source and differentiation history for Kolumbo submarine volcano, Santorini volcanic field, Aegean arc.

    Science.gov (United States)

    Klaver, Martijn; Carey, Steven; Nomikou, Paraskevi; Smet, Ingrid; Godelitsas, Athanasios; Vroon, Pieter

    2016-08-01

    This study reports the first detailed geochemical characterization of Kolumbo submarine volcano in order to investigate the role of source heterogeneity in controlling geochemical variability within the Santorini volcanic field in the central Aegean arc. Kolumbo, situated 15 km to the northeast of Santorini, last erupted in 1650 AD and is thus closely associated with the Santorini volcanic system in space and time. Samples taken by remotely-operated vehicle that were analyzed for major element, trace element and Sr-Nd-Hf-Pb isotope composition include the 1650 AD and underlying K2 rhyolitic, enclave-bearing pumices that are nearly identical in composition (73 wt.% SiO2, 4.2 wt.% K2O). Lava bodies exposed in the crater and enclaves are basalts to andesites (52-60 wt.% SiO2). Biotite and amphibole are common phenocryst phases, in contrast with the typically anhydrous mineral assemblages of Santorini. The strong geochemical signature of amphibole fractionation and the assimilation of lower crustal basement in the petrogenesis of the Kolumbo magmas indicates that Kolumbo and Santorini underwent different crustal differentiation histories and that their crustal magmatic systems are unrelated. Moreover, the Kolumbo samples are derived from a distinct, more enriched mantle source that is characterized by high Nb/Yb (>3) and low (206)Pb/(204)Pb (<18.82) that has not been recognized in the Santorini volcanic products. The strong dissimilarity in both petrogenesis and inferred mantle sources between Kolumbo and Santorini suggests that pronounced source variations can be manifested in arc magmas that are closely associated in space and time within a single volcanic field.

  19. Geomorphic and exhumational response of the Central American Volcanic Arc to Cocos Ridge subduction

    Science.gov (United States)

    Morell, Kristin D.; Kirby, Eric; Fisher, Donald M.; van Soest, Matthijs

    2012-04-01

    The timing of collision of the Cocos Ridge at the Middle America Trench remains one of the outstanding questions in the tectonic evolution of the Central American convergent margin. New analyses of the tectonic geomorphology of the Cordillera de Talamanca, the extinct volcanic arc inboard of the Cocos Ridge, coupled with low temperature thermochronometry data, provide insight into the cooling and erosional history of the arc from late Miocene to present. We identify a low-relief surface at high elevation along the northeastern flanks of the range, which represents a relict erosional landscape cut across shallow plutonic rocks of the arc edifice. Longitudinal profiles of rivers on this surface are isolated from steep downstream sections by prominent knickzones that are interpreted to reflect a migrating wave of transient incision generated during differential rock uplift of the range. Reconstruction of pre-incision profiles suggests that rock uplift during the growth of the Cordillera de Talamanca is no greater than ˜2 km. This inference is corroborated by results from our apatite (U-Th)/He and apatite fission track analyses along an elevation transect on Mt. Chirripó, the highest mountain in the Cordillera de Talamanca. Low-temperature cooling ages overlap significantly with published high-temperature40Ar/39Ar ages; the combined results imply that rapid cooling in the late Miocene was related to secular cooling of a shallow pluton, rather than exhumation. Our results imply that rapid incision along downstream channel segments, differential rock uplift, and growth of the Talamanca as a bivergent orogenic wedge associated with the onset of Cocos Ridge subduction are relatively young characteristics of the range. A review of previously published radiometric ages and revised plate reconstructions for the late Miocene further suggest that the cessation of arc volcanism in both the Cordillera de Talamanca and the Cordillera Central of western Panama was coeval with the

  20. NOAA Deepwater Exploration of the Marianas 2016: Volcanic arc and Backarc Basin

    Science.gov (United States)

    Stern, R. J.; Brounce, M. N.; Chadwick, B.; Fryer, P. B.; Glickson, D.; Merle, S. G.

    2016-12-01

    Legs 1 and 3 of NOAA Okeanos Explorer EX1605 devoted a total of 17 ROV dives to exploring the Mariana magmatic arc and backarc basin (BAB). Dives were carried out on 11 submarine arc volcanoes, the submerged slopes of two volcanic islands, and at 3 BAB sites along 1000 km of the Mariana arc system. Four of the studied arc volcanoes are extinct, three are dormant, and six are active. All BAB dives were on the spreading ridge between 15-17°N, which is volcanically active. Geologic highpoints of these dives include: 1) discovery of an extinct hydrothermal chimney ( 15m tall) in Fina Nagu A (Leg 1, Dive 7; L1D7); 2) observations of very fresh (<3 years old) BAB pillow basalts (L1D9); 3) discovery of a very active BAB hydrothermal field (T 340°C, active chimneys up to 30m tall; L1D11); 4) examination of Esmeralda Bank crater floor (active venting but too murky to find vents; L1D19); 5) discovery of hydrothermal vents with vent fauna on Chamorro volcano (L3D7; T 30°C, active chimneys 2m tall); and 6) examination of active venting and S degassing at 500-350 m depth on Daikoku volcano (L3D9). Video clips of some of the most exciting discoveries and examinations will be presented. We plan to compare previous bathymetry over the active volcanoes with what was collected during EX1605 to quantify how these edifices have changed since when these were previously mapped, over the past 13 years or less. These dives also provided visual evidence in support of the hypothesis that individual edifices of the Fina Nagu Volcanic Complex increase in age from NE to SW, interpreted as due to the motion of actively-extending lithosphere of the southern Mariana BAB to the SW over a relatively fixed source of arc magma above the subducting Pacific plate (Brounce et al. G3 2016). Continuous interaction between biologists and geologists on EX1605 allowed us to identify regions of high faunal density on hard substrates around some active volcanoes, for example Esmeralda Bank, presumably

  1. Optimal likelihood-based matching of volcanic sources and deposits in the Auckland Volcanic Field

    Science.gov (United States)

    Kawabata, Emily; Bebbington, Mark S.; Cronin, Shane J.; Wang, Ting

    2016-09-01

    In monogenetic volcanic fields, where each eruption forms a new volcano, focusing and migration of activity over time is a very real possibility. In order for hazard estimates to reflect future, rather than past, behavior, it is vital to assemble as much reliable age data as possible on past eruptions. Multiple swamp/lake records have been extracted from the Auckland Volcanic Field, underlying the 1.4 million-population city of Auckland. We examine here the problem of matching these dated deposits to the volcanoes that produced them. The simplest issue is separation in time, which is handled by simulating prior volcano age sequences from direct dates where known, thinned via ordering constraints between the volcanoes. The subproblem of varying deposition thicknesses (which may be zero) at five locations of known distance and azimuth is quantified using a statistical attenuation model for the volcanic ash thickness. These elements are combined with other constraints, from widespread fingerprinted ash layers that separate eruptions and time-censoring of the records, into a likelihood that was optimized via linear programming. A second linear program was used to optimize over the Monte-Carlo simulated set of prior age profiles to determine the best overall match and consequent volcano age assignments. Considering all 20 matches, and the multiple factors of age, direction, and size/distance simultaneously, results in some non-intuitive assignments which would not be produced by single factor analyses. Compared with earlier work, the results provide better age control on a number of smaller centers such as Little Rangitoto, Otuataua, Taylors Hill, Wiri Mountain, Green Hill, Otara Hill, Hampton Park and Mt Cambria. Spatio-temporal hazard estimates are updated on the basis of the new ordering, which suggest that the scale of the 'flare-up' around 30 ka, while still highly significant, was less than previously thought.

  2. Late Miocene volcanism and intra-arc tectonics during the early development of the Trans-Mexican Volcanic Belt

    Science.gov (United States)

    Ferrari, Luca; Conticelli, Sandro; Vaggelli, Gloria; Petrone, Chiara M.; Manetti, Piero

    2000-03-01

    The early stage of the Trans-Mexican Volcanic Belt (hereafter TMVB) is marked by widespread, mafic to intermediate, volcanism emplaced between 11 and 7 Ma from the Pacific coast to the longitude of Mexico City, to the north of the modern volcanic arc. Petrological and geochronological data support the hypothesis that this volcanism made up a unique late Miocenic central Mexican comagmatic province. Mafic lavas at the mouth of the Gulf of California and along the northwestern sector of the TMVB made up the Nayarit district, which includes calc-alkaline to transitional varieties. The central sector of the TMVB is characterized by two basaltic districts: the Jalisco-Guanajuato and the Queretaro-Hidalgo, which are distinguished from the westernmost ones by their lower Nb/La and generally lower HFSE/LILE values, as well as by spider diagrams characterized by larger negative spikes at Th, Ta, Nb, and Ti. The surface occurrence of the late Miocene basalts appears to be controlled by pre-existing zones of crustal weakness that channeled the mafic magmas. Field observations suggest that these structures have been reactivated in a transtensional fashion induced by differential tectonic motion of crustal blocks to the south and to the north of the TMVB. Starting from ˜12 Ma the TMVB separates a northern tectonic domain, subject to the developing divergent Pacific-North America plate boundary, from a southern tectonic domain, characterized by oblique subduction of the Rivera and Cocos plates. Apparently, far field stresses related to these complex plate boundaries reactivated older suture zones, allowing rapid uprise of mantle-derived magmas. The subduction-related signature shown by Miocene mafic lavas of the Jalisco-Guanajuato district argues against the existence of mantle plumes beneath this sector of the North America plate. On the other hand, the occurrence in the western TMVB and in the Guadalajara region of a large volume of mafic magmas, which sometimes show

  3. Primitive magmas at five Cascade volcanic fields: Melts from hot, heterogeneous sub-arc mantle

    Science.gov (United States)

    Bacon, C.R.; Bruggman, P.E.; Christiansen, R.L.; Clynne, M.A.; Donnelly-Nolan, J. M.; Hildreth, W.

    1997-01-01

    Major and trace element concentrations, including REE by isotope dilution, and Sr, Nd, Pb, and O isotope ratios have been determined for 38 mafic lavas from the Mount Adams, Crater Lake, Mount Shasta, Medicine Lake, and Lassen volcanic fields, in the Cascade arc, northwestern part of the United States. Many of the samples have a high Mg# [100Mg/(Mg + FeT) > 60] and Ni content (>140 ppm) such that we consider them to be primitive. We recognize three end-member primitive magma groups in the Cascades, characterized mainly by their trace-element and alkali-metal abundances: (1) High-alumina olivine tholeiite (HAOT) has trace element abundances similar to N-MORB, except for slightly elevated LILE, and has Eu/Eu* > 1. (2) Arc basalt and basaltic andesite have notably higher LILE contents, generally have higher SiO2 contents, are more oxidized, and have higher Cr for a given Ni abundance than HAOT. These lavas show relative depletion in HFSE, have lower HREE and higher LREE than HAOT, and have smaller Eu/Eu* (0.94-1.06). (3) Alkali basalt from the Simcoe volcanic field east of Mount Adams represents the third end-member, which contributes an intraplate geochemical signature to magma compositions. Notable geochemical features among the volcanic fields are: (1) Mount Adams rocks are richest in Fe and most incompatible elements including HFSE; (2) the most incompatible-element depleted lavas occur at Medicine Lake; (3) all centers have relatively primitive lavas with high LILE/HFSE ratios but only the Mount Adams, Lassen, and Medicine Lake volcanic fields also have relatively primitive rocks with an intraplate geochemical signature; (4) there is a tendency for increasing 87Sr/86Sr, 207Pb/204Pb, and ??18O and decreasing 206Pb/204Pb and 143Nd/144Nd from north to south. The three end-member Cascade magma types reflect contributions from three mantle components: depleted sub-arc mantle modestly enriched in LILE during ancient subduction; a modern, hydrous subduction component

  4. Bromine release during Plinian eruptions along the Central American Volcanic Arc

    Science.gov (United States)

    Hansteen, T. H.; Kutterolf, S.; Appel, K.; Freundt, A.; Perez-Fernandez, W.; Wehrmann, H.

    2010-12-01

    Volcanoes of the Central American Volcanic Arc (CAVA) have produced at least 72 highly explosive eruptions within the last 200 ka. The eruption columns of all these “Plinian” eruptions reached well into the stratosphere such that their released volatiles may have influenced atmospheric chemistry and climate. While previous research has focussed on the sulfur and chlorine emissions during such large eruptions, we here present measurements of the heavy halogen bromine by means of synchrotron radiation induced micro-XRF microanalysis (SR-XRF) with typical detection limits at 0.3 ppm (in Fe rich standard basalt ML3B glass). Spot analyses of pre-eruptive glass inclusions trapped in minerals formed in magma reservoirs were compared with those in matrix glasses of the tephras, which represent the post-eruptive, degassed concentrations. The concentration difference between inclusions and matrix glasses, multiplied by erupted magma mass determined by extensive field mapping, yields estimates of the degassed mass of bromine. Br is probably hundreds of times more effective in destroying ozone than Cl, and can accumulate in the stratosphere over significant time scales. Melt inclusions representing deposits of 22 large eruptions along the CAVA have Br contents between 0.5 and 13 ppm. Br concentrations in matrix glasses are nearly constant at 0.4 to 1.5 ppm. However, Br concentrations and Cl/Br ratios vary along the CAVA. The highest values of Br contents (>8 ppm) and lowest Cl/Br ratios (170 to 600) in melt inclusions occur across central Nicaragua and southern El Salvador, and correlate with bulk-rock compositions of high Ba/La > 85 as well as low La/Yb discharged 700 kilotons of Br. On average, each of the remaining 21 CAVA eruptions studied have discharged c.100 kilotons of bromine. During the past 200 ka, CAVA volcanoes have emitted a cumulative mass of 3.2 Mt of Br through highly explosive eruptions. There are six periods in the past (c. 2ka, 6ka, 25ka, 40ka, 60ka, 75

  5. Multicomponent Thin Films Deposited by PVD ARC and LARC Technology

    Directory of Open Access Journals (Sweden)

    Dagmar JAKUBÉCZYOVÁ

    2014-04-01

    Full Text Available The paper is focused on a comparison of advanced layers deposited by two coating technologies – cathodic arc deposition (ARC and lateral rotating cathodes (LARC. For characterization standard analyses were selected: the determination of the layer wear resistance by Calotest method, specification of the depth concentration profiles of constituting elements from the coating surface down to the substrate, and measurement of the nanohardness at dynamic loading. The thickness of the CrTiN layer reached 1380 nm – 1740 nm and that of the multi/nanolayers AlXN3 was 2630 nm – 3160 nm. The coating nanohardness on the surface attained 39 GPa for AlXN3 (X = Cr, 33 GPa for CrTiN and 12.5 GPa for the substrate. Only at coating prepared by LARC-Technology it is possible to create the multilayers of nanometric dimensions. AlXN3 coating was formed by 48 layers with dimensions of 58 nm – 70 nm. These nanolayers lead to the increase of system toughness as they prevent the crack propagation. Their application on the tools and components promises to increase their durability under service conditions.DOI: http://dx.doi.org/10.5755/j01.ms.20.1.3716

  6. Geochemistry and Petrogenesis of Volcanic Rocks in the Yeba Formation on the Gangdise Magmatic Arc, Tibet

    Institute of Scientific and Technical Information of China (English)

    Geng Quanru; Pan Guitang; Jin Zhenmin; Wang Liquan; Liao Zhongli

    2005-01-01

    The Early Jurassic bimodal volcanic rocks in the Yeba Formation, situated between Lhasa, Dagzê and Maizhokunggar, composed of metabasalt, basaltic ignimbrite, dacite, silicic tuff and volcanic breccia, are an important volcanic suite for the study of the tectonic evolution of the Gangdise magmatic arc and the Mesozoic Tethys. Based on systematic field investigations, we carried out geochemical studies on representative rock samples. Major and trace element compositions were analyzed for these rock samples by XRF and ICP-MS respectively, and an isotope analysis of Rb-Sr and Sm-Nd was carried out by a MAT 262 mass spectrograph. The results show that the SiO2 contents in lava rocks are 41 %-50.4 % and 64 %-69 %, belonging to calc-alkaline basalt and dacite. One notable feature of the basalt is its low TiO2 content, 0.66 %-1.01 %, much lower than those of continental tholeiite. The ΣREE contents of basalt and dacite are 60.3-135 μg/g and 126.4-167.9 μg/g respectively. Both rocks have similar REE and other trace element characteristics, with enriched LREE and LILE relative to HREE and HFS, similar REE patterns without Eu anomaly. The basalts have depleted Ti, Ta and Nb and slightly negative Nb and Ta anomalies, with Nb*=0.54-1.17 averaging 0.84. The dacites have depleted P and Ti and also slightly negative Nb and Ta anomalies, with Nb*=0.74-1.06 averaging 0.86. Major and trace elemental and isotopic studies suggest that both basalt and dacite originated from the partial melting of the mantle wedge at different degrees above the subduction zone. The spinal lherzolite in the upper mantle is likely to be their source rocks, which might have been affected by the selective metasomatism of fluids with crustal geochemistry. The LILE contents of both rocks were affected by metamorphism at later stages. The Yeba bimodal volcanic rocks formed in a temporal extensional situation in a mature island arc resulting from the Indosinian Gangdise magmatic arc.

  7. Palaeoproterozoic Volcanic Massive Sulphides (VMS) in the Lithuanian crystalline basement: evidences for a back-arc tectonic setting

    Science.gov (United States)

    Skridlaite, Grazina; Siliauskas, Laurynas

    2014-05-01

    which there are amphibolites with layers or lenses of skarns formed in marbles. Some amphibolites resemble porphyritic basalts. These might be dikes of basalts, which are common for back arc VMS surroundings. The volcano-clastic rock from the Lz13 yielded c. 1.83 Ga and c. 1.80 Ga ages. The whole rock Sm-Nd isotopic composition points towards juvenile origin of the rock (TDM=2.08 Ga, ɛNd (1.9) +1.8). After the comparison of the obtained data set with VMS deposits formed in different environments, it is most likely that the volcano-sedimentary sequence of Lz13 was formed in a back arc tectonic setting. The volcano-sedimentary sequence can be correlated with the 1.83 Ga Oskarshamn-Jönköping Belt (Mansfeld et al., 2005) and the volcano-sedimentary Vetlanda formation (Makowsky and Mansfeld, 2013) in southeastern Sweden. The c. 1.83-1.80 Ga volcanic arc and back-arc system continues from southeastern Sweden through the Baltic Sea to Lithuania. This is a contribution to the Open Access Centre activities Mansfeld, J., Beunk, F.F. and Barling, J., 2005. GFF, 127: 149-157 Makowsky, F., Mansfeld, J., 2013. 31st Nordic Geological Winter Meeting, Lund, Sweden, 89-90.

  8. The record of magma chamber processes in plagioclase phenocrysts at Thera Volcano, Aegean Volcanic Arc, Greece

    Science.gov (United States)

    Stamatelopoulou-Seymour, Karen; Vlassopoulos, Dimitrios; Pearce, Thomas H.; Rice, Craig

    1990-01-01

    Lavas and pyroclastic rocks throughout the volcanic stratigraphy of the Tertiary-Quaternary volcanic complex of Thera in the Aegean island arc display inhomogenous plagioclase populations and phenocryst resorption textures, interpreted as indicative of magma mixing. Plagioclase zoning characteristics studied by Nomarski and laser interferometry techniques establish three main categories of plagioclase: (i) inherited plagioclase (nucleated in endmember prior to initial mixing event) (ii) in situ plagioclase (nucleated in mixed or hybrid magma) and (iii) xenocrystic plagioclase. Nomarski contrast images and linearized compositional zoning profiles reveal striking differences between calcic and sodic plagioclases, depending on the composition of the lava in which they are hosted. These differences reflect the contrasting effects of changes in physical-chemical parameters in basic vis-a-vis more acidic melts during magma mixing and/or influx of new magma into the subvolcanic magma chamber, as well as the influence of magma chamber dynamics on plagioclase equilibration. Variations in bulk major and trace element abundances of Thera volcanic products reflect the dominant overprint of crystal fractionation, but decoupling between major and trace element fractionation models and variations in incompatible trace element distributions are all indicative of magma mixing processes, consistent with compositional and textural zoning in plagioclases.

  9. Metagenomic investigation of the geologically unique Hellenic Volcanic Arc reveals a distinctive ecosystem with unexpected physiology.

    Science.gov (United States)

    Oulas, Anastasis; Polymenakou, Paraskevi N; Seshadri, Rekha; Tripp, H James; Mandalakis, Manolis; Paez-Espino, A David; Pati, Amrita; Chain, Patrick; Nomikou, Paraskevi; Carey, Steven; Kilias, Stephanos; Christakis, Christos; Kotoulas, Georgios; Magoulas, Antonios; Ivanova, Natalia N; Kyrpides, Nikos C

    2016-04-01

    Hydrothermal vents represent a deep, hot, aphotic biosphere where chemosynthetic primary producers, fuelled by chemicals from Earth's subsurface, form the basis of life. In this study, we examined microbial mats from two distinct volcanic sites within the Hellenic Volcanic Arc (HVA). The HVA is geologically and ecologically unique, with reported emissions of CO2 -saturated fluids at temperatures up to 220°C and a notable absence of macrofauna. Metagenomic data reveals highly complex prokaryotic communities composed of chemolithoautotrophs, some methanotrophs, and to our surprise, heterotrophs capable of anaerobic degradation of aromatic hydrocarbons. Our data suggest that aromatic hydrocarbons may indeed be a significant source of carbon in these sites, and instigate additional research into the nature and origin of these compounds in the HVA. Novel physiology was assigned to several uncultured prokaryotic lineages; most notably, a SAR406 representative is attributed with a role in anaerobic hydrocarbon degradation. This dataset, the largest to date from submarine volcanic ecosystems, constitutes a significant resource of novel genes and pathways with potential biotechnological applications.

  10. Andesite petrogenesis in a hybrid arc-rift setting: the Western Trans-Mexican Volcanic Belt

    Science.gov (United States)

    Gómez-Tuena, A.; Vázquez-Duarte, A.; Díaz-Bravo, B.; Mori, L.

    2011-12-01

    The western sector of the Mexican subduction zone is characterized by the steep subduction of one of the youngest slabs on the planet (Rivera plate), and by the existence of a continental rift at ~230 km to the north from the trench (the so-called Tepic-Zacoalco rift, TZR), under which the subducted slab is either extremely deep or even absent (>250 km). The volcanic front is located at ~170 km from the trench and contains abundant potassic-alkaline lamprophyres with strong subduction (Ba/Ta= 1600-6000) and garnet signatures (Gd/Yb= 2-8), that have been recently interpreted as influenced by deep K2O-rich slab melts or supercritical fluids (Gómez-Tuena et al., 2011, GCA). In contrast, the most mafic rocks within the TZR are high-Nb, intraplate-like basalts that appear to derive from low extents of melting of a dryer (Ba/Ta= 800-60) and shallower (Gd/Yb= 2-2.5) mantle source. Even though a simple transition from an arc environment to an extensional tectonic regime is apparent when only the most primitive volcanic rocks are taken into account, the scenario becomes more complicated since at least five stratovolcanoes have been erupting typical arc andesites within the TZR over the last million years (San Juan, Sanganguey, Tepetiltic, Ceboruco and Tequila). Surprisingly, true calc-alkaline basalts that could be parental to andesites have not been found, indicating that andesites may have a direct mantle origin. Indeed, mayor and trace element compositions of volcanic rocks from western Mexico arrange in discrete suites with linear trends that are indicative of mixing, but they form sub-parallel arrays that do not converge to a common primitive basaltic melt, and often follow diverging trends in trace element-ratio plots. Melt-crust interactions likely occurred during magma ascent, since the volcanic rocks frequently include xenoliths and disequilibrium textures, but correlations among isotopic compositions and indexes of fractionation are not clearly observed in the

  11. Volcanic glass signatures in spectroscopic survey of newly proposed lunar pyroclastic deposits

    Science.gov (United States)

    Besse, S.; Sunshine, J.M.; Gaddis, L.R.

    2014-01-01

    Moon Mineralogy Mapper spectroscopic observations are used to assess the mineralogy of five sites that have recently been proposed to include lunar dark mantle deposits (DMDs). Volcanic glasses have, for the first time, clearly been identified at the location of three of the proposed pyroclastic deposits. This is the first time that volcanic glasses have been identified at such a small scale on the lunar surface from remote sensing observations. Deposits at Birt E, Schluter, and Walther A appear to be glassy DMDs. Deposits at Birt E and Schluter show (1) morphological evidence suggesting a likely vent and (2) mineralogical evidence indicative of the presence of volcanic glasses. The Walther A deposits, although they show no morphological evidence of vents, have the spectroscopic characteristics diagnostic of volcanic glasses. The deposits of the Freundlich-Sharonov basin are separated in two areas: (1) the Buys-Ballot deposits lack mineralogical and morphological evidence and thus are found to be associated with mare volcanism not with DMDs and (2) the Anderson crater deposits, which do not exhibit glassy DMD signatures, but they appear to be associated with possible vent structures and so may be classifiable as DMDs. Finally, dark deposits near the crater Kopff are found to be associated with likely mare volcanism and not associated with DMDs. The spectral identification of volcanic glass seen in many of the potential DMDs is a strong indicator of their pyroclastic origin.

  12. Amorphous boron coatings produced with vacuum arc deposition technology

    CERN Document Server

    Klepper, C C; Yadlowsky, E J; Carlson, E P; Keitz, M D; Williams, J M; Zuhr, R A; Poker, D B

    2002-01-01

    In principle, boron (B) as a material has many excellent surface properties, including corrosion resistance, very high hardness, refractory properties, and a strong tendency to bond with most substrates. The potential technological benefits of the material have not been realized, because it is difficult to deposit it as coatings. B is difficult to evaporate, does not sputter well, and cannot be thermally sprayed. In this article, first successful deposition results from a robust system, based on the vacuum (cathodic) arc technology, are reported. Adherent coatings have been produced on 1100 Al, CP-Ti, Ti-6Al-4V, 316 SS, hard chrome plate, and 52 100 steel. Composition and thickness analyses have been performed by Rutherford backscattering spectroscopy. Hardness (H) and modules (E) have been evaluated by nanoindentation. The coatings are very pure and have properties characteristic of B suboxides. A microhardness of up to 27 GPa has been measured on a 400-nm-thick film deposited on 52 100 steel, with a corresp...

  13. Modeling Central American Volcanic Front Primitive Lavas with the Arc Basalt Simulator (abs 4.0)

    Science.gov (United States)

    Feigenson, M.; Carr, M. J.; Gazel, E.

    2012-12-01

    We have used the Arc Basalt Simulator (ABS), developed by J-I Kimura, to explore the conditions and components of melting beneath the Central American volcanic front. ABS is a comprehensive forward model that incorporates slab dehydration and melting and mantle wedge fluxing and melting using realistic P-T conditions and experimentally determined phase relations and partition coefficients. We have applied ABS version 4.00, which includes melting/dehydration relations in eight distinct subducting layers, to model representative magma types along the Central American volcanic front. These magmas are first projected to primary melt compositions by the addition of olivine until they reach Fo90. Then, using a wide range of input parameters including variations in slab components, extent of peridotite depletion, depth of slab dehydration and wedge fluxing and degree of peridotite melting, successful model fits are generated (based on trace element and isotope matching). The solution space is probed using a Monte Carlo technique to cover the enormous range of parameter values. Nicaragua and Costa Rica represent geochemical and geophysical end members of the volcanic front, differing greatly in volcano volume, slab dip beneath the volcano, isotopic composition and incompatible element enrichment. Using appropriate input compositions for ABS 4.0, we find through millions of simulations that the Cerro Negro primary magma (Nicaragua) requires high degrees of source melting (22-27%) and large amounts of slab-derived water (3-5%). In contrast, the Irazu primary magma (central Costa Rica) is generated from more enriched sources with only a small amount of water (less than 0.5%) and at low degrees of partial melting (less than 5%). Other Central American lavas with intermediate geochemical characteristics are produced from conditions within the Nicaragua-Costa Rica range. By reproducing the lava geochemistry with ABS 4.0, it becomes possible to extract constraints on source input

  14. Structure and petrology of newly discovered volcanic centers in the northern Kermadec-southern Tofua arc, South Pacific Ocean

    Science.gov (United States)

    Graham, Ian J.; Reyes, Agnes G.; Wright, Ian C.; Peckett, Kimberley M.; Smith, Ian E. M.; Arculus, Richard J.

    2008-08-01

    The NZAPLUME III expedition of September-October 2004 to the northern Kermadec-southern Tofua (NKST) arc, between 28°52'S and 25°07'S, resulted in the discovery of at least seven new submarine volcanic centers and a substantial caldera complex adjacent to the previously known Monowai Seamount. The volcanic centers form a sublinear chain that coincides with the Kermadec Ridge crest in the south (Hinetapeka) and diverges ˜45 km westward of the ridge crest in the north ("V") just to the south of where the Louisville Ridge intersects with the arc. All of the centers contain calderas or caldera-like structures, as well as multiple cones, domes, fissure ridges, and vent fields. All show signs of recent eruptive and current hydrothermal activity. There are strong structural controls on edifice location, with cones and fissure ridges typically associated with faulting parallel to the regional ˜12° strike of the arc front. Several of the calderas are ellipsoidal, orientated northwest-southeast in the general direction of least compressive stress. Sampled volcanic rocks, representing the most recently erupted lavas, are all low-K tholeiites. Two of the centers, Gamble and Rakahore, yielded only high-silica dacite to rhyolite (69-74 wt% silica), whereas two others, Monowai and "V," yielded only basalt to andesite (48-63 wt% silica). Mineral assemblages are plagioclase-pyroxene dominated, with accessory Fe-Ti oxides, apatite, olivine, and quartz/tridymite/cristobalite, typical of dry volcanic arc systems. Hornblende occurs only in a felsitic rhyolite from Hinepuia volcanic center, and zircon is absent. Glass contents range to 57% in basalts-andesites (mean 20%), and 97% in andesites-rhyolites (mean 59%) and other quench textures, including swallow-tailed, plumose, or dendritic crystal forms and crystallites, are common. Most lavas are highly vesicular (≤63%; mean 28%) and have low volatile contents (mostly cristobalite, indicates explosive eruption and rapid cooling

  15. Late cenozoic vertical movements of non-volcanic islands in the Banda Arc area

    Science.gov (United States)

    De Smet, M. E. M.; Fortuin, A. R.; Tjokrosapoetro, S.; Van Hinte, J. E.

    During onshore campaigns of the Snellius-II Expedition late Cenozoic sections were recorded and systematically sampled on the non-volcanic outer Banda Arc Islands of Timor, Buton, Buru, Seram and Kai. Microfaunal studies provided age and palaeobathymetric data to construct geohistory diagrams. Geohistory analysis of field and laboratory data allows to calculate rates of vertical movements of the island basements. The vertical movements were intermittent and differed widely from place to place in the arc; short periods of uplift alternated with longer periods of tectonic rest or subsidence and lateral variations in timing and magnitude seem to be more the rule than the exception. Movements affected larger segments of the arc at about the same time, especially since the late Pliocene, when widespread vertical movements started, which led to the present configuration of the arc. Rates of uplift or subsidence differed within each segment. On an intermediate scale, deformation has the character of tilting or doming of whole islands or parts of islands. On a local scale, various types of deformation occur. Calculated duration of uplift pulses is in the order of a million years where less than 50 cm·ka -1 of vertical movements are involved. Sections, however, with a high time stratigraphic resolutions show pulses of uplift with a duration of only some hundreds of thousands of years and rates of more than 500 cm·ka -1. The duration of such pulses therefore is comparable to that of eustatic third order sea level changes. But because their amplitude is an order of magnitude larger, this implies that in tectonically active areas eustatic signals, preserved in the sedimentary record, will be overprinted by tectonics, i.e. will be difficult to disentangle from the tectonic signal.

  16. Geochronology of middle Neoproterozoic volcanic deposits in Yangtze Craton interior of South China and its implications to tectonic settings

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    Here we report new SHRIMP dating results of the crystal tuff in Ejiaao Formation of middle Banxi Group in northern Guizhou. The results indicate that the volcanic deposition occurred at ~780 Ma. We also suggests that the igneous activities across Yangtze Craton with diabase dyke swarms and basal volcanic rocks during middle Banxi time are indicative of the episodic, extensive and vigorous great bimodal igneous events during middle Neoproterozoic (825-720 Ma) in South China. The characteristics of the igneous series are contrary to the model claiming they are of island-arc origin, but suggest that they are the records of rifting process and may be related to the episodic plume activities leading to the break-up of Rodinia.

  17. Assessment of Prospecting Potentiality for Superlarge Continental Volcanic Rock—Type Uranium Deposits in China

    Institute of Scientific and Technical Information of China (English)

    陈贵华; 陈名佐; 等

    1999-01-01

    The superlarge continental volcanic rock-type uranium deposits,which were discovered abroad long ago,have not ye been reported up to now in China.This is an important problem that needs to be urgently solved by uranium geologists at present.In this paper,on the basis of analyzing the metallogenic settings and geological conditions of the superlarge continental volcanic rock-type uranium deposits discovered in the world along with the metallogenic characteristics of those of the same type in China,the space-time distribution patterns of continental volcanics and the metallogenic potential of main tectono-volcanic belts in China are discussed,and a synthetic conclusion has been drawn that there is a possibility to discover the superlarge continental volcanic rock-type uranium deposits in China.Moreover,it is evidenced that the Ganhang,Nanling,Yanliao,Da Hinggan Ling and other tectono-volcanic belts possess favorable geological conditions for the formation of ssuperlarge ore deposits of the continental volcanic rock type.The intersecting and overlapping locations of the aforementioned main belts with other tectono-volcanic(-intrusive)belts are the most potential areas where the superlarge continental volcanic rock-type uranium deposits would be found.

  18. Late Cretaceous volcanic arc system in Southwest Korea: Occurrence, lithological characteristics, SHRIMP zircon U-Pb age, and tectonic implications

    Science.gov (United States)

    Koh, Hee Jae; Kwon, Chang Woo

    2017-04-01

    In the southwest region of the Korean Peninsula, four large volcanoes, the Buan, Seonunsan, Wido, and Beopseongpo, with a maximum diameter of ca 20 km, form a distinct topographic undulation along the NE-SW-trending Hamyeol Fault. These volcanics comprise various types of pyroclastic, sedimentary, and lava/intrusive rocks, and are interpreted as remnants of calderas resulting from various volcanic eruptions, indicating that Hamyeol Fault, together with crustal extension, played an important role in volcano formation in this region. SHRIMP U-Pb ages of zircon isolated from each volcanics are as follows. For Buan Volcanics, Cheonmasan Tuff 87.23 ±0.92 Ma, Udongje Tuff 86.79 ±0.71 Ma, Seokpo Tuff 87.30 ±0.99 Ma and Yujeongje Tuff 86.66 ±0.93 Ma. For Seonunsan Volcanics, Gyeongsusan Tuff 84.9 ±1.1 Ma and Yeongije Tuff 86.61 ±0.67 Ma. These ages indicate that the four volcanics were formed in the Late Cretaceous. The ages are comparable to those of the volcanic rocks of the Aioi and Arima groups in Southwestern Japan, suggesting that the Late Cretaceous volcanic arc systems developed in a NE-SW direction from the Japanese Islands to the southwestern part of the Korean Peninsula caused by regional magmatism together with crustal deformation as reflected by occurrence of the volcanic rocks along the Hamyeol Fault.

  19. Implications of volcanic erratics in Quaternary deposits of North Greenland

    DEFF Research Database (Denmark)

    Funder, Svend Visby; Larsen, Ole

    1982-01-01

    Erratic boulders, petrographically similar to the volcanics exposed around Kap Washington, are found on islands and along the coast much further to the east. Isotopic measurements on two such boulders show that these volcanic rocks are of the same age as the Kap Washington volcanics. The regional...

  20. Halogen content in Lesser Antilles arc volcanic rocks : exploring subduction recycling

    Science.gov (United States)

    Thierry, Pauline; Villemant, Benoit; Caron, Benoit

    2016-04-01

    Halogens (F, Cl, Br and I) are strongly reactive volatile elements which can be used as tracers of igneous processes, through mantle melting, magma differentiation and degassing or crustal material recycling into mantle at subduction zones. Cl, Br and I are higly incompatible during partial melting or fractional cristallization and strongly depleted in melts by H2O degassing, which means that no Cl-Br-I fractionation is expected through magmatic differenciation [current thesis]. Thus, Cl/Br/I ratios in lavas reflect the halogen content of their mantle sources. Whereas these ratios seemed quite constant (e.g. Cl/Br =300 as seawater), recent works suggest significant variations in arc volcanism [1,2]. In this work we provide high-precision halogen measurements in volcanic rocks from the recent activity of the Lesser Antilles arc (Montserrat, Martinique, Guadeloupe, Dominique). Halogen contents of powdered samples were determined through extraction in solution by pyrohydrolysis and analysed by Ion Chromatography for F and Cl and high performance ICP-MS (Agilent 8800 Tripe Quad) for Cl, Br and I [3,4]. We show that lavas - and mantle sources - display significant vraiations in Cl/Br/I ratios along the Lesser Antilles arc. These variations are compared with Pb, Nd and Sr isotopes and fluid-mobile elements (Ba, U, Sr, Pb etc.) compositions which vary along the arc from a nothern ordinary arc compositions to a southern 'crustal-like' composition [5,6]. These characteristics are attributed to subducted sediments recycling into the mantle wedge, whose contribution vary along the arc from north to south [7,8]. The proportion of added sediments is also related to the distance to the trench as sediment melting and slab dehydration may occur depending on the slab depth [9]. Further Cl-Br-I in situ measurements by LA-ICP-MS in Lesser Antilles arc lavas melt inclusions will be performed, in order to provide better constraints on the deep halogen recycling cycle from crust to

  1. Multidisciplinary exploratory study of a geothermal resource in the active volcanic arc of Basse-Terre (Guadeloupe, Lesser Antilles)

    Science.gov (United States)

    Navelot, Vivien; Favier, Alexiane; Géraud, Yves; Diraison, Marc; Corsini, Michel; Verati, Chrystèle; Lardeaux, Jean-Marc; Mercier de Lépinay, Jeanne; Munschy, Marc

    2017-04-01

    The GEOTREF project (high enthalpy geothermal energy in fractured reservoirs), supported by the French government program, "Investissements d'avenir" develops a sustainable geothermal resource in the Vieux Habitants area, 8-km south of the currently exploited Bouillante geothermal field. The Basse Terre Island is a recent volcanic arc (geothermal gradient of 70 ˚ C/km.

  2. Deep long-period earthquakes west of the volcanic arc in Oregon: evidence of serpentine dehydration in the fore-arc mantle wedge

    Science.gov (United States)

    Vidale, John E.; Schmidt, David A.; Malone, Stephen D.; Hotovec-Ellis, Alicia J.; Moran, Seth C.; Creager, Kenneth C.; Houston, Heidi

    2014-01-01

    Here we report on deep long-period earthquakes (DLPs) newly observed in four places in western Oregon. The DLPs are noteworthy for their location within the subduction fore arc: 40–80 km west of the volcanic arc, well above the slab, and near the Moho. These “offset DLPs” occur near the top of the inferred stagnant mantle wedge, which is likely to be serpentinized and cold. The lack of fore-arc DLPs elsewhere along the arc suggests that localized heating may be dehydrating the serpentinized mantle wedge at these latitudes and causing DLPs by dehydration embrittlement. Higher heat flow in this region could be introduced by anomalously hot mantle, associated with the western migration of volcanism across the High Lava Plains of eastern Oregon, entrained in the corner flow proximal to the mantle wedge. Alternatively, fluids rising from the subducting slab through the mantle wedge may be the source of offset DLPs. As far as we know, these are among the first DLPs to be observed in the fore arc of a subduction-zone system.

  3. The tectonic emplacement of Sumba in the Sunda-Banda Arc: paleomagnetic and geochemical evidence from the early Miocene Jawila volcanics

    NARCIS (Netherlands)

    Wensink, H.; Bergen, M.J. van

    1995-01-01

    The island of Sumba is a continental fragment in the fore-arc region near the transition between the Sunda Arc and Banda Arc in southeastern Indonesia. Paleomagnetic and geochemical evidence from the early Miocene volcanics of the Jawila Formation in western Sumba constrain the final drift stage

  4. Deep-crustal magma reservoirs beneath the Nicaraguan volcanic arc, revealed by 2-D and semi 3-D inversion of magnetotelluric data

    Science.gov (United States)

    Brasse, Heinrich; Schäfer, Anja; Díaz, Daniel; Alvarado, Guillermo E.; Muñoz, Angélica; Mütschard, Lutz

    2015-11-01

    A long-period magnetotelluric (MT) experiment was conducted in early 2009 in western Nicaragua to study the electrical resistivity and thus fluid/melt distribution at the Central American continental margin where the Cocos plate subducts beneath the Caribbean plate. Strike analysis yields a preference direction perpendicular to the profile, with moderate deviation from two-dimensionality, however. Two-dimensional modeling maps the sediments of the Nicaraguan Depression and a high-conductivity zone in the mid-crust, slightly offset from the arc. Further conductors are modeled in the backarc. However, these features are probably artifacts when a 2-D program is applied to data which show moderate 3-D characteristics. 3-D inversion clarifies the situation, and the major remaining conductive structure is now quasi directly beneath the volcanic chain and interpreted as a deep-seated magma deposit. Conductivity in the backarc is also relatively high and may either be caused by still existing partial melts beneath the Paleocene to Miocene volcanic arcs or by related metallic deposits in the aureoles of hydrothermal alteration.

  5. ZrN coatings deposited by high power impulse magnetron sputtering and cathodic arc techniques

    Energy Technology Data Exchange (ETDEWEB)

    Purandare, Yashodhan, E-mail: Y.Purandare@shu.ac.uk; Ehiasarian, Arutiun; Hovsepian, Papken [Nanotechnology Centre for PVD Research, Materials and Engineering Research Institute, Sheffield Hallam University, Sheffield S1 1WB (United Kingdom); Santana, Antonio [Ionbond AG Olten, Industriestrasse 211, CH-4600 Olten (Switzerland)

    2014-05-15

    Zirconium nitride (ZrN) coatings were deposited on 1 μm finish high speed steel and 316L stainless steel test coupons. Cathodic Arc (CA) and High Power Impulse Magnetron Sputtering (HIPIMS) + Unbalanced Magnetron Sputtering (UBM) techniques were utilized to deposit coatings. CA plasmas are known to be rich in metal and gas ions of the depositing species as well as macroparticles (droplets) emitted from the arc sports. Combining HIPIMS technique with UBM in the same deposition process facilitated increased ion bombardment on the depositing species during coating growth maintaining high deposition rate. Prior to coating deposition, substrates were pretreated with Zr{sup +} rich plasma, for both arc deposited and HIPIMS deposited coatings, which led to a very high scratch adhesion value (L{sub C2}) of 100 N. Characterization results revealed the overall thickness of the coatings in the range of 2.5 μm with hardness in the range of 30–40 GPa depending on the deposition technique. Cross-sectional transmission electron microscopy and tribological experiments such as dry sliding wear tests and corrosion studies have been utilized to study the effects of ion bombardment on the structure and properties of these coatings. In all the cases, HIPIMS assisted UBM deposited coating fared equal or better than the arc deposited coatings, the reasons being discussed in this paper. Thus H+U coatings provide a good alternative to arc deposited where smooth, dense coatings are required and macrodroplets cannot be tolerated.

  6. Stratigraphy and Characterization of Volcanic Deposits on the Northwestern Flanks of Mt. Makiling, Laguna, Philippines

    Science.gov (United States)

    Ybanez, R. L.; Bonus, A. A. B.; Judan, J. M.; Racoma, B. A.; Morante, K. A. M.; Balangue, M. I. R. D.

    2014-12-01

    Mt. Makiling is an inactive stratovolcano located in the province of Laguna. Semi-detailed geologic field mapping on the northwestern low-level flanks and apron of the volcano was conducted. Exposures reveal a volcanic terrain hosting a wide variety of volcanic rocks: lava flows, pyroclastic surges, pyroclastic flows, and tuff deposits. Stratigraphic logging of the volcanic deposits showed differences in occurrence of the deposit types as well as their characteristics. The pyroclastic flow deposits are found at the base of the column overlain by pyroclastic surges which were more common in the area. Capping the pyroclastic surges is a thin layer of tuffaceous units. Isolated deposits of lava flows of andesitic composition were mapped in the western flank of Mt. Makiling. These varying volcanic deposits are derived from different eruptive activities of Mt. Makiling, with at least three separate eruptive episodes indicated by the exposed deposits. Two separate explosive eruptions are marked by two different pyroclastic deposits, while an effusive episode, marked by andesitic lava flows, can also be identified. The pyroclastic surge deposit is uncharacteristically thick, around a hundred meters or more exposed, providing further questions as to the magnitude of past eruptions or the mechanism of pyroclastic material deposition around the volcano. Mt. Makiling, thus, has historically undergone different eruption types, but still releases generally the same material composition across varying deposits: intermediate or andesitic composition. This is consistent with the trend of Philippine volcanoes, and with the Macolod corridor which hosts this volcanic system.

  7. 3-D numerical simulations of volcanic ash transport and deposition

    Science.gov (United States)

    Suzuki, Y. J.; Koyaguchi, T.

    2012-12-01

    During an explosive volcanic eruption, volcanic gas and pyroclasts are ejected from the volcanic vent. The pyroclasts are carried up within a convective plume, advected by the surrounding wind field, and sediment on the ground depending on their terminal velocity. The fine ash are expected to have atmospheric residence, whereas the coarser particles form fall deposits. Accurate modeling of particle transport and deposition is of critical importance from the viewpoint of disaster prevention. Previously, some particle-tracking models (e.g., PUFF) and advection-diffusion models (e.g., TEPHRA2 and FALL3D) tried to forecast particle concentration in the atmosphere and particle loading at ground level. However, these models assumed source conditions (the grain-size distribution, plume height, and mass release location) based on the simple 1-D model of convective plume. In this study, we aim to develop a new 3-D model which reproduces both of the dynamics of convective plume and the ash transport. The model is designed to describe the injection of eruption cloud and marker particles from a circular vent above a flat surface into the stratified atmosphere. Because the advection is the predominant mechanism of particle transport near the volcano, the diffusive process is not taken into account in this model. The distribution of wind velocity is given as an initial condition. The model of the eruption cloud dynamics is based on the 3-D time-dependent model of Suzuki et al. (2005). We apply a pseudo-gas model to calculate the eruption cloud dynamics: the effect of particle separation on the cloud dynamics is not considered. In order to reproduce the drastic change of eruption cloud density, we change the effective gas constant and heat capacity of the mixture in the equation of state for ideal gases with the mixing ratio between the ejected material and entrained air. In order to calculate the location and movement of ash particles, the present model employs Lagrangian marker

  8. Volcanic rock-hosted gold and base-metal mineralization associated with neoproterozoic-early Paleozoic back-arc extension in the Carolina terrane, southern Appalachian Piedmont

    Energy Technology Data Exchange (ETDEWEB)

    Feiss, P.G. (Univ. of North Carolina, Chapel Hill (United States)); Vance, R.K. (Georgia Southern Univ., Statesboro (United States)); Wesolowski, D.J. (Oak Ridge National Lab., TN (United States))

    1993-05-01

    Volcanogenic mineral deposits in the Carolina terrane, southern Appalachian Piedmont, include Kuroko-type polymetallic massive sulfide deposits and disseminated gold-pyrite deposits associated with propylitic, silicic, argillic, and advanced argillic alteration. Host rocks are metavolcaniclastic and metaepiclastic rocks of a Neoproterozoic-Early Cambrian magmatic arc. The favorable gold horizon is the transition from a lower succession of andesitic and rhyolitic pyroelastic rocks with basal mafic lavas to an upper sequence of epiclastic sedimentary units and minor lava and ash flows. Kuroko-type deposits are associated with mafic to bimodal volcanic rocks in the upper sequence. Whole-rock oxygen isotope analyses indicate that gold mineralization is associated with a transition from hydrothermal systems dominated by isotopically relatively light ([delta][sup 18]O = -6% to -10%) waters, typical of high-latitude subaerial systems, to seawater ([delta][sup 18]O = 0%). Plots of [delta][sup 18]O vs. SiO[sub 2] of the host rocks show a compositional gap associated with mineralization at the subaerial to submarine transition. Values of [delta][sup 18]O for the hydrothermal waters, lithostratigraphic analyses, and tectonic models of the Carolina terrane demonstrate that mineralization coincided with extension in a rifted arc. 34 refs., 3 figs.

  9. Age and chemical constraints of Volcán Tunupa: Implications for behind arc volcanism in the Bolivian central Andes

    Science.gov (United States)

    salisbury, M. J.; Kent, A. J.; Jiménez, N.; Jicha, B. R.

    2011-12-01

    New 40Ar/39Ar age determinations of groundmass separates and whole-rock geochemical data constrain the Pleistocene eruptive history of Volcán Tunupa, a glacially-dissected composite volcano (~50 km3) situated between the Salar de Uyuni and Salar de Coipasa. Tunupa erupted ~110 km east of the arc front of the Western Cordillera of the central Andes near the eastern edge of the Intersalar Volcanic Field, an arc-perpendicular expression of volcanism that extends to the central Altiplano basin of Bolivia. 40Ar/39Ar age determinations indicate that the edifice was constructed between ~1.40 and 1.55 Ma, whereas nearby Cerro Huayrana lavas erupted ~ 11 Ma. Published ages from the Western Cordillera that are concordant with both Tunupa and Huayrana lavas demonstrate that the central Altiplano lavas are a long-lived expression of behind arc volcanism. The Tunupa lavas define a calc-alkaline trend from trachyandesite to trachydacite (wt.% SiO2 = 60.6 - 63.6; wt.% K2O + Na2O = 7.5 - 8.3) and are overlain by younger, more silicic (wt.% SiO2 = 66) trachydacitic domes. Major element compositions of Tunupa and Huayrana are enriched in FeO and TiO2 compared to the arc front. These lavas are also enriched in high field strength elements, notably Nb and Ta, and are characterized by considerably lower Ba/Nb and La/Ta ratios than arc front lavas in northern Chile. The geochemical and spatiotemporal patterns of the behind arc Tunupa and Huayrana lavas suggest different petrogenetic histories from typical central Andean arc lavas.

  10. Textural and chemical variation in phenocrysts from the early eruptions of Lutao volcanic island, the northern Luzon arc

    Science.gov (United States)

    Liu, Y.; Iizuka, Y.; Huang, K.

    2012-12-01

    The Lutao volcanic island at the northern end of Luzon arc was formed by the subduction of South China Sea Plate beneath the Philippine Sea plate. Three edifices on the island were built up by pyroclastic deposits from different eruption stages. In this study, the textural and chemical zonings in phenocrysts are used to characterize the subvolcanic magma chamber for the earliest eruption stage (1.4-2.0 Ma). The high 143Nd/144Nd and 176Hf/177Hf ratios of six volcanic breccias collected from the lowermost layer indicate that they were derived from a common depleted mantle source. However, their compositional variations cannot be explained by simple fractional crystallization. The textures and compositions of the phenocrysts reveal the complication in the magma chamber processes. Compared to the average primitive arc basalts, two basaltic andesites have similar major element compositions with higher incompatible trace element abundances. The un-zoned or normally zoned olivine, plagioclase, and pyroxenes indicate the relatively undisturbed processes (961-1011°C and 2.8-5.5 kb) at the earlier crystallization stage. The peritectic olivine and abundance melt inclusions accompanied by abrupt XAn increase at the rims of plagioclase inferred recharge of H2O-rich mafic melt at later stage, which also triggered rapid eruption. The cryptic magma mixing had limited effect on isotopic signatures and major element variations, but had great chance to modify the bulk trace element abundances. In contrast, plagioclase phenocrysts in four low-mg# basaltic samples contain An-rich dissolved or resorbed cores with abundant melt inclusions, which were formed from rapid decompression of volatile-rich magma at H2O-undersaturated conditions. The calcic plagioclase and minor Mg-rich olivine formed at greater depth were rapidly brought to magma chamber to crystallized sodic plagioclase rim, clinopyroxene, and minor orthopyroxene (954-994°C and 2.1-4.1 kb). The normally zoned clinopyroxene

  11. Seismotectonic pattern and the source region of volcanism in the central part of Sunda Arc

    Science.gov (United States)

    Špičák, Aleš; Hanuš, Václav; Vaněk, Jiří

    2005-07-01

    The seismotectonic pattern in the central part of the Sunda Arc (Java, Nusa Tenggara) was studied in relation to the distribution of active calc-alkaline volcanoes, using global seismological data. Hypocentral determinations of the International Seismological Centre from the period 1964-1999, as relocated by Engdahl, and Harvard Centroid Moment Tensor Solutions from the period 1976-2003 were used. The following phenomena, which could assist the location of the source region of primary magma for island arc calc-alkaline volcanism, were observed: (1) An aseismic gap without any strong teleseismically recorded earthquakes was found in the Wadati-Benioff zone of the subducting slab along the whole investigated region of the Sunda Arc, forming a continuous strip of laterally variable depth and shape, at depths between 100 and 200 km. The absence of strong earthquakes (with mb>4.0) indicates a significant change in the mechanical properties of the subducting slab at intermediate depths. All active calc-alkaline volcanoes in the Sunda Arc are located above this gap. (2) The majority of earthquakes occurring in the lithospheric wedge of the Eurasian Plate above the subducted slab could be attributed to several deep-rooted seismically active fracture zones of regional extent. All delineated active fracture zones display a thrust tectonic regime as shown by the available fault plane solutions. (3) Clusters of earthquakes were found beneath active volcanoes of western Java, Bali and Nusa Tenggara in the lithospheric wedge above the slab and identified as seismically active columns. These clusters occur only beneath the volcanoes that are located at the outcrops of seismically active fracture zones. We interpret the earthquakes in these clusters beneath volcanoes as events induced by magma transport through the medium of the lithospheric wedge that has been subcritically pre-stressed by the process of plate convergence. (4) Beneath the volcanoes of central Java no seismically

  12. Submarine Hydrothermal Sites in Arc Volcanic-Back Arc Environment: Insight from Recent Marine Geophysical Investigations in the Southern Tyrrhenian Sea.

    Science.gov (United States)

    Cocchi, L.; Ligi, M.; Bortoluzzi, G.; Petersen, S.; Plunkett, S.; Muccini, F.; Canese, S.; Caratori Tontini, F.; Carmisciano, C.

    2014-12-01

    Hydrothermal alteration processes involve mineralogical and chemical changes, which are reflected in a major modification of potential field patterns observed over hydrothermal areas. Basalt-hosted hydrothermal sites exhibit characteristic responses with magnetic lows and minima of the gravity field. Near bottom AUV (Autonomous Underwater Vehicle) based potential field surveys have become a very effective technique in deep sea exploration. Here we present results of recent ship-borne and near seafloor magnetic and gravity investigations at deep (Marsili and Palinuro seamounts) and shallow (Panarea, Basiluzzo and Secca del Capo) hydrothermal sites in the Southern Tyrrhenian Sea including multibeam bathymetry, seafloor reflectivity and seismic profiles. At Marsili seamount, a large Fe-Mn-oxyhydroxides-rich chimney field is located at the summit (500 m depth). This site is correlated with pronounced magnetic and gravity lows (0 A/m and 2.0 g/cm3). Deep tow magnetic survey (Cruise MAVA11) revealed strong association between the complicated magnetization pattern and the main volcano-tectonic features of the ridge. Hydrothermal manifestations at Palinuro seamount occur mainly on the western sector within the rim of a caldera structure at depth of 600m. Recent AUV based magnetic surveys (Cruise POS442, 2012 using AUV "Abyss") detailed a magnetization low interpreted to represent the local distribution of subseafloor hydrothermal alteration (potentially massive sulfide deposits), and also mapped previously undiscovered inactive chimney fields. Hydrothermal sites observed at the arc-related volcanic islands (Panarea, Basiluzzo, Eolo and Secca del Capo) are confined to shallow depths (less then 300m) and associated with large ochreaceous mounds, vents and chimney fields such as those observed E of Basiluzzo Island. At this site a recent magnetic survey (Cruise PANA13_ASTREA) combined with Remote Operated Vehicle (ROV) investigations revealed that the submarine geothermal

  13. Macroparticles Reduction Using Filter Free Cathodic Vacuum Arc Deposition Method in ZnO Thin Films.

    Science.gov (United States)

    Yuvakkumar, R; Peranantham, P; Nathanael, A Joseph; Nataraj, D; Mangalaraj, D; Hong, Sun Ig

    2015-03-01

    We report a new method to reduce macroparticles in ZnO thin films using filter free cathodic vacuum arc deposition without using any cooling arrangements operated at low arc current. The detailed mechanism has been proposed to reduce macroparticles during thin film deposition. The successful reduction of macroparticles was confirmed employing FESEM-EDX studies. FESEM images of ZnO thin films deposited with cathode spot to substrate distance from 10 to 20 cm revealed that the population of the macroparticles were reduced with the increase of cathode spot to substrate distances at low arc current. The prepared ZnO films were characterised and showed good structural and optical properties.

  14. Off-axis magmatism along a subaerial back-arc rift: Observations from the Taupo Volcanic Zone, New Zealand.

    Science.gov (United States)

    Hamling, Ian J; Hreinsdóttir, Sigrun; Bannister, Stephen; Palmer, Neville

    2016-06-01

    Continental rifting and seafloor spreading play a fundamental role in the generation of new crust. However, the distribution of magma and its relationship with tectonics and volcanism remain poorly understood, particularly in back-arc settings. We show evidence for a large, long-lived, off-axis magmatic intrusion located on the margin of the Taupo Volcanic Zone, New Zealand. Geodetic data acquired since the 1950s show evidence for uplift outside of the region of active extension, consistent with the inflation of a magmatic body at a depth of ~9.5 km. Satellite radar interferometry and Global Positioning System data suggest that there was an increase in the inflation rate from 2003 to 2011, which correlates with intense earthquake activity in the region. Our results suggest that the continued growth of a large magmatic body may represent the birth of a new magma chamber on the margins of a back-arc rift system.

  15. Insights from Pb and O isotopes into along-arc variations in subduction inputs and crustal assimilation for volcanic rocks in Java, Sunda arc, Indonesia

    Science.gov (United States)

    Handley, Heather K.; Blichert-Toft, Janne; Gertisser, Ralf; Macpherson, Colin G.; Turner, Simon P.; Zaennudin, Akhmad; Abdurrachman, Mirzam

    2014-08-01

    New Pb isotope data are presented for Gede Volcanic Complex, Salak and Galunggung volcanoes in West Java, Merbabu and Merapi volcanoes in Central Java and Ijen Volcanic Complex in East Java of the Sunda arc, Indonesia. New O isotope data for Merbabu and new geochemical and radiogenic isotope data (Sr-Nd-Hf-Pb) for three West Javanese, upper crustal, Tertiary sedimentary rocks are also presented. The data are combined with published geochemical and isotopic data to constrain the relative importance of crustal assimilation and subducted input of crustal material in petrogenesis in Java. Also discussed are the significance of limestone assimilation in controlling the geochemical and isotopic characteristics of erupted Javanese rocks and the geochemical impact upon central and eastern Javanese arc rocks due to the subduction of Roo Rise between 105 and 109°E. The negative correlation between Pb isotopes and SiO2, combined with mantle-like δ18O values in Gede Volcanic Complex rocks, West Java, are most likely explained by assimilation of more isotopically-primitive arc rocks and/or ophiolitic crust known to outcrop in West Java. The negative Pb isotope-SiO2 trend cannot be explained by assimilation of the known compositions of the upper crustal rocks. A peak in δ18O whole-rock and mineral values in Central Javanese volcanic rocks (Merbabu and Merapi) combined with along-arc trends in Sr isotope ratios suggest that a different or additional crustal assimilant exerts control on the isotopic composition of Central Javanese volcanic rocks. This assimilant (likely carbonate material) is characterised by high δ18O and high Sr isotope ratio but is not particularly elevated in its Pb isotopic ratio. Once the effects of crustal assimilation are accounted for, strong East to West Java regional variations in Ba concentration, Ba/Hf ratio and Pb isotopic composition are evident. These differences are attributed to heterogeneity in the subducted source input component along the

  16. Investigations of the geochemical controls on anomalous arsenic enrichment in the Santiago Peak Volcanics of Southern California: implications for arsenic distribution in volcanic arc systems

    Science.gov (United States)

    Johnston, E. C.; Pollock, M.; Cathcart, E. M.; AlBashaireh, A.; O'shea, B. M.

    2016-12-01

    The Santiago Peak Volcanics (SPV) of Southern CA and Northern Baja CA, Mexico are remnants of a Cretaceous subaerial volcanic arc system that underwent greenschist facies metamorphism contemporaneous with volcanism. Observed SPV exposed at the surface of Black Mountain Open Space Park (San Diego, CA) exhibit anomalous arsenic (As) enrichment (100 - 480,000 ppm) up to five orders of magnitude greater than average for igneous rocks (1.5 ppm). We hypothesize that these rocks underwent localized syn-volcanic hydrothermal alteration along a highly fractured zone that today trends between N10°W and N20°W, leading to anomalous As enrichment on the spatial scale of tens of meters. We suspect that such As has been further mobilized by modern water-rock interactions. Using standard geochemical techniques (e.g. XRD, XRF, EDX) and mass balance analyses, we aim to (1) summarize the extent of As enrichment in altered SPV, and (2) present an integrated view of the interactions between ancient hydrothermal volcanic arc processes, surficial weathering, and observed As anomalies. Alteration textures of samples range from partially altered phenocrysts (i.e. minimally altered) to massive hydrothermal replacement, in which virtually all primary phases are altered to new hydrothermal minerals such as epidote, Fe-rich chlorite, and sericite (i.e. highly altered). Highly altered rocks contain average As concentrations (mean = 37,680 +/- 15,396 ppm, n = 23) >10,000 times that of minimally altered SPV (mean = 26 +/- 6 ppm As, n = 19). In some rocks, As-rich iron oxide and gypsum containing up to 900 ppm As are present as surficial rinds, suggesting modern day remobilization of As from hydrothermal host minerals, like arsenopyrite. These findings indicate that such As is highly soluble and, therefore, may be further mobilized by physical and chemical weathering. No other trace metals (e.g. Pb, Cu, Ag, Au) are consistently enriched above upper-crustal averages, and As does not always occur

  17. On-and offshore tephrostratigraphy and -chronology of the southern Central American Volcanic Arc (CAVA)

    Science.gov (United States)

    Schindlbeck, J. C.; Kutterolf, S.; Hemming, S. R.; Wang, K. L.

    2015-12-01

    Including the recently drilled CRISP sites (IODP Exp. 334&344) the deep sea drilling programs have produced 69 drill holes at 29 Sites during 9 Legs at the Central American convergent margin, where the Cocos plate subducts beneath the Caribbean plate. The CAVA produced numerous plinian eruptions in the past. Although abundant in the marine sediments, information and data regarding large late Cenozoic explosive eruptions from Costa Rica, Nicaragua, Honduras, El Salvador, and Guatemala remain very sparse and discontinuous on land. We have established a tephrostratigraphy from recent through Miocene times from the unique archive of ODP/IODP sites offshore Central America in which we identify tephra source regions by geochemical fingerprinting using major and trace element glass shard compositions. Here we present first order correlations of ­~500 tephra layers between multiple holes at a single site as well as between multiple sites. We identified ashes supporting Costa Rican (~130), Nicaraguan (17) and Guatemalan (27) sources as well as ~150 tephra layers from the Galápagos hotspot. Within our marine record we also identified well-known marker beds such as the Los Chocoyos tephra from Atitlán Caldera in Guatemala and the Tiribi Tuff from Costa Rica but also correlations to 15 distinct deposits from known Costa Rican and Nicaraguan eruptions within the last 4.1 Ma. These correlations, together with new radiometric age dates, provide the base for an improved tephrochronostratigraphy in this region. Finally, the new marine record of explosive volcanism offshore southern CAVA provides insights into the eruptive history of long-living volcanic complexes (e.g., Barva, Costa Rica) and into the distribution and frequency of large explosive eruptions from the Galápagos hotspot. The integrated approach of Ar/Ar age dating, correlations with on land deposits from CAVA, biostratigraphic ages and sediment accumulation rates improved the age models for the drilling sites.

  18. The characteristics of arc beam shaping in hybrid plasma and laser deposition manufacturing

    Institute of Scientific and Technical Information of China (English)

    ZHANG; Hai'ou; QIAN; Yingping; WANG; Guilan; ZHENG; Qiguang

    2006-01-01

    As a new direct metal prototyping technology,the hybrid plasma and laser deposition manufacturing (PLDM) is proposed in this paper. In order to figure out the characteristics of plasma arc beam and mould in the PLDM process of high temperature alloy, the high speed CCD camera is used to obtain the picture around the plasma arc. Afterwards the sketch of picture is clearly obtained. And the effect of laser parameter, such as average power, pulse width, pulse repetition frequency and the angle between laser beam and plasma arc beam on the plasma arc appearance, is studied experimentally. The results show that the modality of plasma arc beam is markedly influenced by laser beam. And the improvements of shape precision and surface state of the layer deposited by PLDM are confirmed.

  19. Age and geochemistry of host rocks of the Cobre Panama porphyry Cu-Au deposit, central Panama: Implications for the Paleogene evolution of the Panamanian magmatic arc

    Science.gov (United States)

    Baker, Michael J.; Hollings, Peter; Thompson, Jennifer A.; Thompson, Jay M.; Burge, Colin

    2016-04-01

    The Cobre Panama porphyry Cu-Au deposit, located in the Petaquilla district of central Panama, is hosted by a sequence of medium- to high-K calc-alkaline volcanic and sub-volcanic rocks. New crystallisation ages obtained from a granodiorite Petaquilla batholith and associated mineralised diorite to granodiorite porphyry stocks and dikes at Cobre Panama indicate that the batholith was emplaced as a multi-phase intrusion, over a period of ~ 4 million years from 32.20 ± 0.76 Ma to 28.26 ± 0.61 Ma, while the porphyritic rocks were emplaced over a ~ 2 million year period from 28.96 ± 0.62 Ma to 27.48 ± 0.68 Ma. Both the volcanic to sub-volcanic host rocks and intrusive rocks of the Cobre Panama deposit evolved via fractional crystallisation processes, as demonstrated by the major elements (e.g. Al2O3, Fe2O3, TiO2 and MgO) displaying negative trends with increasing SiO2. The Petaquilla intrusive rocks, including the diorite-granodiorite porphyries and granodiorite batholith, are geochemically evolved and appear to have formed from more hydrous magmas than the preceding host volcanic rocks, as evidenced by the presence of hornblende phenocrysts, higher degrees of large-ion lithophile element (LILE) and light rare earth element (LREE) enrichment and heavy rare earth element (HREE) depletion, and higher Sr/Y and La/Yb values. However, the degree of LREE enrichment, HREE depletion and La/Yb values are insufficient for the intrusive rocks to be considered as adakites. Collectively, the volcanic and intrusive rocks have LILE, REE and mobile trace element concentrations similar to enriched Miocene-age Cordilleran arc magmatism found throughout central and western Panama. Both the Petaquilla and Cordilleran arc magmatic suites are geochemically more evolved than the late Cretaceous to Eocene Chagres-Bayano arc magmas from northeastern Panama, as they display higher degrees of LILE and LREE enrichment. The geochemical similarities between the Petaquilla and Cordilleran arc

  20. Deposition and immersion-mode nucleation of ice by three distinct samples of volcanic ash

    Science.gov (United States)

    Schill, G. P.; Genareau, K.; Tolbert, M. A.

    2015-07-01

    Ice nucleation of volcanic ash controls both ash aggregation and cloud glaciation, which affect atmospheric transport and global climate. Previously, it has been suggested that there is one characteristic ice nucleation efficiency for all volcanic ash, regardless of its composition, when accounting for surface area; however, this claim is derived from data from only two volcanic eruptions. In this work, we have studied the depositional and immersion freezing efficiency of three distinct samples of volcanic ash using Raman microscopy coupled to an environmental cell. Ash from the Fuego (basaltic ash, Guatemala), Soufrière Hills (andesitic ash, Montserrat), and Taupo (Oruanui eruption, rhyolitic ash, New Zealand) volcanoes were chosen to represent different geographical locations and silica content. All ash samples were quantitatively analyzed for both percent crystallinity and mineralogy using X-ray diffraction. In the present study, we find that all three samples of volcanic ash are excellent depositional ice nuclei, nucleating ice from 225 to 235 K at ice saturation ratios of 1.05 ± 0.01, comparable to the mineral dust proxy kaolinite. Since depositional ice nucleation will be more important at colder temperatures, fine volcanic ash may represent a global source of cold-cloud ice nuclei. For immersion freezing relevant to mixed-phase clouds, however, only the Oruanui ash exhibited appreciable heterogeneous ice nucleation activity. Similar to recent studies on mineral dust, we suggest that the mineralogy of volcanic ash may dictate its ice nucleation activity in the immersion mode.

  1. Zircon U-Pb Age Determination of Volcanic Eruptions in Lutao and Lanyu in the Northern Luzon Magmatic Arc

    Directory of Open Access Journals (Sweden)

    Wen-Yu Shao

    2014-01-01

    Full Text Available This paper reports for the first time zircon U-Pb ages of volcanic rocks and sands from Lutao and Lanyu, two islets off SE Taiwan in the north Luzon arc. The samples include (1 seven andesites from four volcanic units and three river/beach sands from Lutao and (2 five basaltic andesites from four volcanic units and two river/beach sands from Lanyu. The Lutao andesites contain abundant magmatic zircons, aging from ~1.54 to ~1.24 Ma for individual sample, which yielded an overall mean 206Pb/238U age of 1.31 ±± 0.03 Ma (n = 190, MSWD = 2.6. This is slightly older than, or broadly coincident with, a mean 206Pb/238U age of 1.23 ±± 0.03 Ma (n = 103, MSWD = 1.9 given by detrital zircons from the three sands. The Lanyu volcanics appear to have less abundant magmatic zircons, aging from ~2.72 to ~2.35 Ma for individual sample, which yielded an overall mean 206Pb/238U age of 2.61 ±± 0.13 Ma (n = 11, MSWD = 1.8. This accords with a mean 206Pb/238U age of 2.69 ±± 0.11 Ma (n = 34, MSWD = 4.7 obtained by detrital zircons from the two sands. The age data suggest that in Lutao and Lanyu the major volcanic eruptions occurred at ~1.3 and ~2.6 Ma, respectively. Moreover, volcanic samples from both islets contain various amounts of older inherited zircons, ~11% in Lutao and up to ~82% in Lanyu, which together with detrital zircons from the sands show main age peaks at ~150 Ma and ~1.9 and ~2.5 Ga, consistent with the notion for a _ continental crust involved in the genesis of the northern Luzon magmatic arc.

  2. Geochemical variability of hydrothermal emissions between three Pacific volcanic arc systems: Alaskan-Aleutian and Cascadian, North America and Taupo Volcanic Zone, New Zealand

    Science.gov (United States)

    Blackstock, J. M.; Horton, T. W.; Gravley, D. M.; Deering, C. D.

    2013-12-01

    Knowledge of the source, transport, and fate of hydrothermal fluids in the upper crust informs our understanding and interpretation of ore-forming processes, volcanogenic hazards, geothermal resources, and volatile cycling. Co-variation between fluid inclusion CO2/CH4 and N2/Ar ratios is an established tracer of magmatic, meteoric, and crustal fluid end-members. Yet, this tracer has had limited application to macroscopic fluid reservoirs accessible via geothermal wells and hydrothermal features (e.g. pools). In this study, we compared the covariance CO2/CH4 and N2/Ar ratios of gases collected throughout the Taupo Volcanic Zone, New Zealand (TVZ), the Alaska-Aleutian Volcanic Arc, USA (AAVA), and the Cascadian Volcanic Arc, USA (CVA) with corresponding δ13C and 3He/4He values. Our findings show that there is good agreement between these proxies for different end-member contributions at coarse scales. However, some samples classified as meteoric water according to the CO2/CH4 and N2/Ar ratios also show more positive δ13C values (~ -7.0 per mil) and relatively higher 3He/4He ratios indicative of magmatic input from primarily mantle sources. This unexpected result may be related to magmatic fluids, CO2 in particular, mixing with predominantly meteoric derived waters. The potential to identify magmatic CO2 in groundwater samples overlying geothermal systems in differing volcanic arc settings using simple and cost-effective gas ratios is a promising step forward in the search for ';surface blind' but developable geothermal systems and volcanic monitoring. 3He/4He anomalies also support this inference and underscore the potential decoupling of thermal anomalies and magmatic-derived fluids in the Earth's crust. The general agreement between the co-variation of CO2/CH4 and N2/Ar ratios with other isotope and geochemical proxies for magmatic, meteoric, and crustal end-members is encouraging to employ expanded use of these ratios for both the exploration and monitoring of

  3. The Alboran volcanic arc archipelago isolated the Mediterranean during the Messinian salinity crisis forming the land bridge for biota dispersal across the western Mediterranean

    Science.gov (United States)

    Booth-Rea, Guillermo; Ranero, Cesar R.; Grevemeyer, Ingo

    2017-04-01

    The Mediterranean Sea desiccation during isolation from the world oceans created the well-known Messinian salinity crisis but also landbridges that permitted the exchange of terrestrial biota between Africa and Iberia contributing to the present biodiversity of the Mediterranean region. The hypotheses for the cause chocking the Mediterranean have typically sought to explain geological features, particularly the giant salt deposits, but the implications of the faunal changes occurring around that time remain inadequately integrated by current geological models. We present wide-angle seismic data that constrain for the first time the 16-18 km thick crust structure of a volcanic arc formed mostly between 10 to 6 Ma across the eastern region of the Alboran basin. The crustal structure supports that the arc created an archipelago forming a land bridge across the basin that largely isolated the Mediterranean. After the cessation of volcanic activity, the archipelago progressively submerged by thermal subsidence and accompanying sediment loading, having emerged islands that persisted into the Pleistocene time and shallow straits forming sills during the early Pliocene. The presence of an archipelago in the eastern region of the basin may explain a number of puzzling observations previously inexplicable by the proposed barriers closing the Gibraltar arc west of Alboran. The progressive volcanic build up of the archipelago together with the closure of the Betic and Rifean marine corridors would explain the initial isolation of the Mediterranean since 7.1 Ma and the exchange of terrestrial biota since 6.2 Ma, i.e. before desiccation, which diversified radiating from SE Iberia and the opposite segment of the eastern Rif. In addition, an eastern barrier agrees with the continuous Messinian-age open marine sediments drilled at ODP site 976 in the western Alboran basin, which may have been the refuge of typical Mediterranean taxa that rapidly repopulated the Mediterranean in the

  4. The role of crystallization-driven exsolution on the sulfur mass balance in volcanic arc magmas

    Science.gov (United States)

    Su, Y.; Huber, Christian; Bachmann, Olivier; Zajacz, Zoltán.; Wright, Heather; Vazquez, Jorge

    2016-08-01

    The release of large amounts of sulfur to the stratosphere during explosive eruptions affects the radiative balance in the atmosphere and consequentially impacts climate for up to several years after the event. Quantitative estimations of the processes that control the mass balance of sulfur between melt, crystals, and vapor bubbles is needed to better understand the potential sulfur yield of individual eruption events and the conditions that favor large sulfur outputs to the atmosphere. The processes that control sulfur partitioning in magmas are (1) exsolution of volatiles (dominantly H2O) during decompression (first boiling) and during isobaric crystallization (second boiling), (2) the crystallization and breakdown of sulfide or sulfate phases in the magma, and (3) the transport of sulfur-rich vapor (gas influx) from deeper unerupted regions of the magma reservoir. Vapor exsolution and the formation/breakdown of sulfur-rich phases can all be considered as closed-system processes where mass balance arguments are generally easier to constrain, whereas the contribution of sulfur by vapor transport (open system process) is more difficult to quantify. The ubiquitous "excess sulfur" problem, which refers to the much higher sulfur mass released during eruptions than what can be accounted for by amount of sulfur originally dissolved in erupted melt, as estimated from melt inclusion sulfur concentrations (the "petrologic estimate"), reflects the challenges in closing the sulfur mass balance between crystals, melt, and vapor before and during a volcanic eruption. In this work, we try to quantify the relative importance of closed- and open-system processes for silicic arc volcanoes using kinetic models of sulfur partitioning during exsolution. Our calculations show that crystallization-induced exsolution (second boiling) can generate a significant fraction of the excess sulfur observed in crystal-rich arc magmas. This result does not negate the important role of vapor

  5. The role of crystallization-driven exsolution on the sulfur mass balance in volcanic arc magmas

    Science.gov (United States)

    Su, Yanqing; Huber, Christian; Bachmann, Olivier; Zajacz, Zoltán; Wright, Heather M.; Vazquez, Jorge A.

    2016-01-01

    The release of large amounts of sulfur to the stratosphere during explosive eruptions affects the radiative balance in the atmosphere and consequentially impacts climate for up to several years after the event. Quantitative estimations of the processes that control the mass balance of sulfur between melt, crystals, and vapor bubbles is needed to better understand the potential sulfur yield of individual eruption events and the conditions that favor large sulfur outputs to the atmosphere. The processes that control sulfur partitioning in magmas are (1) exsolution of volatiles (dominantly H2O) during decompression (first boiling) and during isobaric crystallization (second boiling), (2) the crystallization and breakdown of sulfide or sulfate phases in the magma, and (3) the transport of sulfur-rich vapor (gas influx) from deeper unerupted regions of the magma reservoir. Vapor exsolution and the formation/breakdown of sulfur-rich phases can all be considered as closed-system processes where mass balance arguments are generally easier to constrain, whereas the contribution of sulfur by vapor transport (open system process) is more difficult to quantify. The ubiquitous “excess sulfur” problem, which refers to the much higher sulfur mass released during eruptions than what can be accounted for by amount of sulfur originally dissolved in erupted melt, as estimated from melt inclusion sulfur concentrations (the “petrologic estimate”), reflects the challenges in closing the sulfur mass balance between crystals, melt, and vapor before and during a volcanic eruption. In this work, we try to quantify the relative importance of closed- and open-system processes for silicic arc volcanoes using kinetic models of sulfur partitioning during exsolution. Our calculations show that crystallization-induced exsolution (second boiling) can generate a significant fraction of the excess sulfur observed in crystal-rich arc magmas. This result does not negate the important role of

  6. Late Cenozoic tephrostratigraphy offshore the southern Central American Volcanic Arc: 2. Implications for magma production rates and subduction erosion

    Science.gov (United States)

    Schindlbeck, J. C.; Kutterolf, S.; Freundt, A.; Straub, S. M.; Vannucchi, P.; Alvarado, G. E.

    2016-11-01

    Pacific drill sites offshore Central America provide the unique opportunity to study the evolution of large explosive volcanism and the geotectonic evolution of the continental margin back into the Neogene. The temporal distribution of tephra layers established by tephrochonostratigraphy in Part 1 indicates a nearly continuous highly explosive eruption record for the Costa Rican and the Nicaraguan volcanic arc within the last 8 Myr. The widely distributed marine tephra layers comprise the major fraction of the respective erupted tephra volumes and masses thus providing insights into regional and temporal variations of large-magnitude explosive eruptions along the southern Central American Volcanic Arc (CAVA). We observe three pulses of enhanced explosive volcanism between 0 and 1 Ma at the Cordillera Central, between 1 and 2 Ma at the Guanacaste and at >3 Ma at the Western Nicaragua segments. Averaged over the long-term the minimum erupted magma flux (per unit arc length) is ˜0.017 g/ms. Tephra ages, constrained by Ar-Ar dating and by correlation with dated terrestrial tephras, yield time-variable accumulation rates of the intercalated pelagic sediments with four prominent phases of peak sedimentation rates that relate to tectonic processes of subduction erosion. The peak rate at >2.3 Ma near Osa particularly relates to initial Cocos Ridge subduction which began at 2.91 ± 0.23 Ma as inferred by the 1.5 Myr delayed appearance of the OIB geochemical signal in tephras from Barva volcano at 1.42 Ma. Subsequent tectonic re-arrangements probably involved crustal extension on the Guanacaste segment that favored the 2-1 Ma period of unusually massive rhyolite production.

  7. Geochemical discrimination of the geotectonic environment of basaltic-andesitic volcanic rocks associated with the Laochang polymetallic ore deposit at Lancang, Yunnan

    Institute of Scientific and Technical Information of China (English)

    GAO Jianguo

    2006-01-01

    The Laochang polymetallic ore deposit at Lancang is one of the well known ancient ore deposits associated with volcanic rocks in the Sanjiang (Tri-river) region of Southwest China. Volcanic rocks are dominated by alkali basalt and trachyte basalt. There has long been a controversy on the environment of formation of basalts. Some scholars hold that the basalts were formed in a continental environment, some thought they were formed in an oceanic environment and others considered that the basalts were emplaced in a back-arc basin. This study focuses on the geochemical characteristics of the basalts on the basis of their major elements, REEs and trace elements. At the same time, strongly incompatible elements such as Ta, Th and Hf and their ratios were used to differentiate the geotectonic settings of basalts. The results showed that the basalts in the region studied were formed in a continental rift environment.

  8. Segmentation of the Cascade Arc Based on Compositional and Sr and Nd Isotopic Variations in Primitive Volcanic Rocks

    Science.gov (United States)

    Schmidt, M. E.; Grunder, A. L.

    2006-12-01

    We define four segments in the Cascade Volcanic Arc based on 87Sr/86Sr and 143Nd/144Nd of primitive volcanic rocks: 1) The North segment extends 450 km from Mt. Meager to Glacier Peak; 2) the 350-km Columbia segment includes volcanoes from Mt. Rainier to Mt. Jefferson; 3) the 250 km Central segment comprises the portion of the arc between the Three Sisters and Crater Lake; and 4) the 350-km South segment includes Mt. Shasta to Mt. Lassen. Isotopic data were compiled for primitive bulk composition (MgO concentrations >8 wt.% MgO) as a fingerprint mantle sources. The North segment has a range in 87Sr/86Sr of 0.7030-0.7037 and is distinguished by the predominance of calcalkaline basalts (CAB) and few low K tholeiites (LKT). The North segment lies on the North Cascade craton where convergence is near orthogonal. Oblique subduction occurs beneath the Columbia, Central, and South segments. The Columbia segment (87Sr/86Sr of 0.7028-0.7037) has both LKT and CABs as well as enriched ocean island-like basalts (OIB) that are found both on the arc axis and, especially at the Simcoe Volcanic Field, behind the arc. This segment lies primarily on the accreted Tertiary oceanic plateau terrane of the Columbia Embayment. The Central segment is dominated by LKT with lesser CAB and has the most restricted Sr isotopic range (0.7034- 0.7038). Like the South segment, the Central segment mainly overlies accreted terranes stitched by Mesozoic plutons and has Basin and Range (B&R) extension behind as well as locally within the arc. Medicine Lake Volcano, on the margin of the B&R behind Mt. Shasta is also dominated by LKT and has a narrow isotopic range like the Central segment. This suggests that the LKT's are related to extension in the arc. The South segment is distinguished by the widest Sr isotopic range (0.7028-0.7042) and the presence of high Mg basaltic andesite and andesite compositions in addition to LKT and CABs. These arc segments broadly correspond to physical segments that were

  9. A new view into the Cascadia subduction zone and volcanic arc: Implications for earthquake hazards along the Washington margin

    Science.gov (United States)

    Parsons, T.; Trehu, A.M.; Luetgert, J.H.; Miller, K.; Kilbride, F.; Wells, R.E.; Fisher, M.A.; Flueh, E.; ten Brink, U.S.; Christensen, N.I.

    1998-01-01

    In light of suggestions that the Cascadia subduction margin may pose a significant seismic hazard for the highly populated Pacific Northwest region of the United States, the U.S. Geological Survey (USGS), the Research Center for Marine Geosciences (GEOMAR), and university collaborators collected and interpreted a 530-km-long wide-angle onshore-offshore seismic transect across the subduction zone and volcanic arc to study the major structures that contribute to seismogenic deformation. We observed (1) an increase in the dip of the Juan de Fuca slab from 2??-7?? to 12?? where it encounters a 20-km-thick block of the Siletz terrane or other accreted oceanic crust, (2) a distinct transition from Siletz crust into Cascade arc crust that coincides with the Mount St. Helens seismic zone, supporting the idea that the mafic Siletz block focuses seismic deformation at its edges, and (3) a crustal root (35-45 km deep) beneath the Cascade Range, with thinner crust (30-35 km) east of the volcanic arc beneath the Columbia Plateau flood basalt province. From the measured crustal structure and subduction geometry, we identify two zones that may concentrate future seismic activity: (1) a broad (because of the shallow dip), possibly locked part of the interplate contact that extends from ???25 km depth beneath the coastline to perhaps as far west as the deformation front ???120 km offshore and (2) a crustal zone at the eastern boundary between the Siletz terrane and the Cascade Range.

  10. ELECTRIC ARC WELDING DEPOSITION OF METALLIC SURFACES BY VIBRATING ELECTRODE IN PROTECTIVE GAS MEDIUM

    OpenAIRE

    N. Spiridonov; A. Кudina; V. Кurash

    2013-01-01

    The paper presents methods for obtaining qualitative metallic surfaces by electric arc welding deposition while using consumable electrode in a protective gas medium and executing regularized drop transfer of electrode metal. The drop transfer efficiency of electrode metal and productivity of welding deposition are significantly increased due to excitation of lateral vibrations in the consumable electrode with preset amplitude. The paper describes a method and a device for welding deposition ...

  11. Surface energy evaluation of unhydrogenated DLC thin film deposited by thermionic vacuum arc (TVA) method

    Science.gov (United States)

    Vladoiu, R.; Dinca, V.; Musa, G.

    2009-08-01

    The aim of this paper is concerned with the surface energy evaluation by contact angle measurements of DLC films deposited by thermionic vacuum arc (TVA) on different substrates: glass plate, zinc foil, stainless steel and alumina foil. TVA is an original method based on a combination of the evaporation by electron bombardment and anodic arc. The evaluation of the surface free energy has been carried out by surface energy evaluation system (SEE System). The influence of the experimental conditions is also investigated.

  12. Evolving volcanism at the tip of a propagating arc: The earliest high-Mg andesites in northern New Zealand

    Science.gov (United States)

    Booden, Mathijs A.; Smith, Ian E. M.; Mauk, Jeffrey L.; Black, Philippa M.

    2010-08-01

    A NNW-striking string of isolated volcanic centers, the Kiwitahi chain, erupted between 15 and 5.5 Ma in northern New Zealand. Prior to 6.2 Ma, the erupted rocks were plagioclase- and hornblende-dominated andesites, which are geochemically comparable to coeval andesites erupted in the nearby, much larger Coromandel Volcanic Zone (CVZ). Compared to CVZ andesites, however, the Kiwitahi andesites show more subdued incompatible element enrichments, and they generally have relatively unradiogenic Sr isotope compositions. These features, and the small eruption volumes involved, suggest that the Kiwitahi centers formed over the edge of a magmatic system that was centered on the CVZ. The Kiwitahi centers progressively become younger towards the SSE representing the migration over the time of the edge of this magmatic system. Between 6.2 and 5.5 Ma, four centers at the southern end of the chain erupted pyroxene-dominated, high-magnesium andesites that are geochemically unlike coeval andesites in the CVZ, but similar to Quaternary high-Mg andesites erupted along the western edge of the Taupo Volcanic Zone. These are the earliest known high-Mg andesites in northern New Zealand; their appearance may mark the inception of the current configuration where high-Mg andesite eruptions precede regular andesitic volcanism at the leading edge of the arc.

  13. Intraplate volcanism controlled by back-arc and continental structures in NE Asia inferred from transdimensional Bayesian ambient noise tomography

    Science.gov (United States)

    Kim, Seongryong; Tkalčić, Hrvoje; Rhie, Junkee; Chen, Youlin

    2016-08-01

    Intraplate volcanism adjacent to active continental margins is not simply explained by plate tectonics or plume interaction. Recent volcanoes in northeast (NE) Asia, including NE China and the Korean Peninsula, are characterized by heterogeneous tectonic structures and geochemical compositions. Here we apply a transdimensional Bayesian tomography to estimate high-resolution images of group and phase velocity variations (with periods between 8 and 70 s). The method provides robust estimations of velocity maps, and the reliability of results is tested through carefully designed synthetic recovery experiments. Our maps reveal two sublithospheric low-velocity anomalies that connect back-arc regions (in Japan and Ryukyu Trench) with current margins of continental lithosphere where the volcanoes are distributed. Combined with evidences from previous geochemical and geophysical studies, we argue that the volcanoes are related to the low-velocity structures associated with back-arc processes and preexisting continental lithosphere.

  14. GPS-derived coupling estimates for the Central America subduction zone and volcanic arc faults: El Salvador, Honduras and Nicaragua

    Science.gov (United States)

    Correa-Mora, F.; DeMets, C.; Alvarado, D.; Turner, H. L.; Mattioli, G.; Hernandez, D.; Pullinger, C.; Rodriguez, M.; Tenorio, C.

    2009-12-01

    We invert GPS velocities from 32 sites in El Salvador, Honduras and Nicaragua to estimate the rate of long-term forearc motion and distributions of interseismic coupling across the Middle America subduction zone offshore from these countries and faults in the Salvadoran and Nicaraguan volcanic arcs. A 3-D finite element model is used to approximate the geometries of the subduction interface and strike-slip faults in the volcanic arc and determine the elastic response to coupling across these faults. The GPS velocities are best fit by a model in which the forearc moves 14-16 mmyr-1 and has coupling of 85-100 per cent across faults in the volcanic arc, in agreement with the high level of historic and recent earthquake activity in the volcanic arc. Our velocity inversion indicates that coupling across the potentially seismogenic areas of the subduction interface is remarkably weak, averaging no more than 3 per cent of the plate convergence rate and with only two poorly resolved patches where coupling might be higher along the 550-km-long segment we modelled. Our geodetic evidence for weak subduction coupling disagrees with a seismically derived coupling estimate of 60 +/- 10 per cent from a published analysis of earthquake damage back to 1690, but agrees with three other seismologic studies that infer weak subduction coupling from 20th century earthquakes. Most large historical earthquakes offshore from El Salvador and western Nicaragua may therefore have been intraslab normal faulting events similar to the Mw 7.3 1982 and Mw 7.7 2001 earthquakes offshore from El Salvador. Alternatively, the degree of coupling might vary with time. The evidence for weak coupling indirectly supports a recently published hypothesis that much of the Middle American forearc is escaping to the west or northwest away from the Cocos Ridge collision zone in Costa Rica. Such a hypothesis is particularly attractive for El Salvador, where there is little or no convergence obliquity to drive the

  15. A study on the geochemical characteristics of Upper Permian continental marginal arc volcanic rocks in the northern segment of South Lancangjiang Belt

    Institute of Scientific and Technical Information of China (English)

    SHEN Shangyue; FENG Qinglai; WEI Qirong; ZHANG Zhibin; ZHANG Hu

    2006-01-01

    Geochemical characteristics of the Upper Permian ( P2 ) continental marginal arc volcanic rocks are described, which have been found recently around the areas of Xiaodingxi and Zangli on the eastern side of the Yunxian-Lincang granite, in terms of rock assemblage, petrochemistry, REE, trace elements, Pb isotopes, geotectonic environment and so on. The volcanic rock assemblage is dominated by basalt-andesite-dacite, with minor trachyte andecite-trachyte; the volcanic rock series is predominated by the calc-alkaline series, with minor tholleiite series and alkaline series rocks; the volcanic rocks are characterized by high Al2O3 and low TiO2 , with K2O contents showing extremely strong polarity; the REE distribution patterns are characterized by LREE enrichment and right-inclined type; trace elements and large cation elements are highly enriched, Ti and Cr are depleted, and P and Nb are partially depleted; the Pb composition is of the Gondwana type; the petrochemical points mostly fall within the field of island-arc volcanic rocks, in consistency with the projection of data points of continental marginal volcanic rocks in the southern segment of the South Lancangjiang Belt and the North Lancangjiang Belt. This continental marginal arc volcanic rock belt, together with the ocean-ridge and ocean-island volcanic rocks and ophiolites in the Changning-Menglian Belt, constitute the ocean-ridge volcanic rock, ophiolite-arc rock-magmatic rock belts which are distributed in pairs, indicating that the Lancangjiang oceanic crust subducted eastwards. This result is of great importance in constraining the evolution of the paleo-Tethys in the Lancangjiang Belt.

  16. Late Pleistocene ages for the most recent volcanism and glacial-pluvial deposits at Big Pine volcanic field, California, USA, from cosmogenic 36Cl dating

    Science.gov (United States)

    Vazquez, Jorge A.; Woolford, Jeff M

    2015-01-01

    The Big Pine volcanic field is one of several Quaternary volcanic fields that poses a potential volcanic hazard along the tectonically active Owens Valley of east-central California, and whose lavas are interbedded with deposits from Pleistocene glaciations in the Sierra Nevada Range. Previous geochronology indicates an ∼1.2 Ma history of volcanism, but the eruption ages and distribution of volcanic products associated with the most-recent eruptions have been poorly resolved. To delimit the timing and products of the youngest volcanism, we combine field mapping and cosmogenic 36Cl dating of basaltic lava flows in the area where lavas with youthful morphology and well-preserved flow structures are concentrated. Field mapping and petrology reveal approximately 15 vents and 6 principal flow units with variable geochemical composition and mineralogy. Cosmogenic 36Cl exposure ages for lava flow units from the top, middle, and bottom of the volcanic stratigraphy indicate eruptions at ∼17, 27, and 40 ka, revealing several different and previously unrecognized episodes of late Pleistocene volcanism. Olivine to plagioclase-pyroxene phyric basalt erupted from several vents during the most recent episode of volcanism at ∼17 ka, and produced a lava flow field covering ∼35 km2. The late Pleistocene 36Cl exposure ages indicate that moraine and pluvial shoreline deposits that overlie or modify the youngest Big Pine lavas reflect Tioga stage glaciation in the Sierra Nevada and the shore of paleo-Owens Lake during the last glacial cycle.

  17. Permian-Triassic Magmatism Along the Southern Gondwana Margin: Correlating Proximal and Distal Volcanic Deposits

    Science.gov (United States)

    McKay, M. P.; Weislogel, A. L.; Fildani, A.

    2014-12-01

    Active margins are dominated by erosion, structural deformation, tectonic dissection, and igneous intrusions. These destructive processes lead to an incomplete record of past magmatism in active margins. Volcanic airfall tuffs that are transported and deposited in distal sedimentary basins may be more likely to be preserved in the rock record. Tuffs, however, may be affected by atmospheric fractionation during transport, postdepositional weathering, and diagenesis during burial, potentially altering ash texture, mineralogy, and geochemistry. We use outcrop observations, stratigraphic relationships, whole rock geochemistry, U-Pb zircon geochronology, and zircon rare-earth element geochemistry from Permian-Triassic strata of South Africa and South America to correlate distal volcanic ashes to proximal volcanic deposits and plutonic suites within southern Gondwana. U-Pb zircon signals of the tuffs are treated as "detrital"; the distinct zircon signals were then used to correlate distal airfall ashes to potential magmatic sources. This suggests that airfall fractionation of zircon populations is not a significant concern in tuff geochronology. Additionally, zircon inheritance may be a useful tool in matching far-traveled ashes with parental magmatic suites. Although previous studies have shown that the geochemistry of volcanic tuff deposits varies with distance from the volcanic vent, we employ whole rock and zircon REE compositions to differentiate distinct magmatic periods using distal ashes that were deposited >750 km from the volcanic source. The results of this study support a geochronologic interpretation that the Karoo strata of S. Africa are >10 Ma younger than previously thought based on biostratigraphy. Since the Karoo basin is heavily studied as a record of the end-Permian extinction and paleoclimate change, our results have major implication for this key time in Earth History.

  18. Geothermal Potential of the Cascade and Aleutian Arcs, with Ranking of Individual Volcanic Centers for their Potential to Host Electricity-Grade Reservoirs

    Energy Technology Data Exchange (ETDEWEB)

    Shevenell, Lisa [ATLAS Geosciences, Inc., Reno, NV (United States); Coolbaugh, Mark [ATLAS Geosciences, Inc., Reno, NV (United States); Hinz, Nick [Univ. of Nevada, Reno, NV (United States); Stelling, Pete [Western Washington Univ., Bellingham, WA (United States); Melosh, Glenn [GEODE, Santa Rosa, CA (United States); Cumming, William [Cumming Geoscience, Santa Rosa, CA (United States)

    2015-10-16

    This project brings a global perspective to volcanic arc geothermal play fairway analysis by developing statistics for the occurrence of geothermal reservoirs and their geoscience context worldwide in order to rank U.S. prospects. The focus of the work was to develop play fairways for the Cascade and Aleutian arcs to rank the individual volcanic centers in these arcs by their potential to host electricity grade geothermal systems. The Fairway models were developed by describing key geologic factors expected to be indicative of productive geothermal systems in a global training set, which includes 74 volcanic centers world-wide with current power production. To our knowledge, this is the most robust geothermal benchmark training set for magmatic systems to date that will be made public.

  19. The temporal evolution of back-arc magmas from the Auca Mahuida shield volcano (Payenia Volcanic Province, Argentina)

    Science.gov (United States)

    Pallares, Carlos; Quidelleur, Xavier; Gillot, Pierre-Yves; Kluska, Jean-Michel; Tchilinguirian, Paul; Sarda, Philippe

    2016-09-01

    In order to better constrain the temporal volcanic activity of the back-arc context in Payenia Volcanic Province (PVP, Argentina), we present new K-Ar dating, petrographic data, major and trace elements from 23 samples collected on the Auca Mahuida shield volcano. Our new data, coupled with published data, show that this volcano was built from about 1.8 to 1.0 Ma during five volcanic phases, and that Auca Mahuida magmas were extracted from, at least, two slightly different OIB-type mantle sources with a low partial melting rate. The first one, containing more garnet, was located deeper in the mantle, while the second contains more spinel and was thus shallower. The high-MgO basalts (or primitive basalts) and the low-MgO basalts (or evolved basalts), produced from the deeper and shallower lherzolite mantle sources, respectively, are found within each volcanic phase, suggesting that both magmatic reservoirs were sampled during the 1 Myr lifetime of the Auca Mahuida volcano. However, a slight increase of the proportion of low-MgO basalts, as well as of magmas sampled from the shallowest source, can be observed through time. Similar overall petrological characteristics found in the Pleistocene-Holocene basaltic rocks from Los Volcanes and Auca Mahuida volcano suggest that they originated from the same magmatic source. Consequently, it can be proposed that the thermal asthenospheric anomaly is probably still present beneath the PVP. Finally, our data further support the hypothesis that the injection of hot asthenosphere with an OIB mantle source signature, which was triggered by the steepening of the Nazca subducting plate, induced the production of a large volume of lavas within the PVP since 2 Ma.

  20. Subaqueous environment and volcanic evolution of the Late Cretaceous Chelopech Au-Cu epithermal deposit, Bulgaria

    Science.gov (United States)

    Chambefort, Isabelle; Moritz, Robert

    2014-12-01

    A detailed field and petrographic study constrains the volcanic evolution and environment setting of the volcano-sedimentary-hosted Chelopech Cu-Au epithermal deposit, Bulgaria. Magmatic activity and associated high-sulfidation epithermal mineralization occurred at about 91 Ma in the Panagyurishte ore district of the Eastern European Banat-Timok-Srednogorie metallogenic belt. Volcanic and hydrothermal activity took place in a complex subaqueous setting, resulting in the intercalation of quartz sandstone with andesitic volcanic and volcaniclastic breccia. There are also hypabyssal andesite intrusion, phreatomagmatic breccia and interbeds of pyroclastic, oolithic and bioclastic rocks. The presence of altered cerebroid ooid-bearing sedimentary units characteristic of salty environment is in accordance with a lagoon environment predating the mineralization at Chelopech. Four principal stages of evolution for the Chelopech district are proposed based on field and petrographic observations. Initial volcanism occurred in a lake or in a coastal, shallow lagoon environment above crystalline basement. The Chelopech "phreatomagmatic" breccia and subsurface andesites were emplaced at this time. Subsequent hydrothermal activity produced the different hydrothermal breccia types, advanced argillic and quartz-phyllic alteration, and Au-Cu vein and replacement mineralization. The end of volcanism and hydrothermal activity was associated with opening of a pull-apart basin that covered the Chelopech environment with a sedimentary flysch. Tertiary compression faulting juxtaposed various rocks and tilted the ore deposit during the Alpine orogeny.

  1. Filtered cathodic arc deposition with ion-species-selectivebias

    Energy Technology Data Exchange (ETDEWEB)

    Anders, Andre; Pasaja, Nitisak; Sansongsiri, Sakon; Lim, SunnieH.N.

    2006-10-05

    A dual-cathode arc plasma source was combined with acomputer-controlled bias amplifier such as to synchronize substrate biaswith the pulsed production of plasma. In this way, bias can be applied ina material-selective way. The principle has been applied to the synthesismetal-doped diamond-like carbon films, where the bias was applied andadjusted when the carbon plasma was condensing, and the substrate was atground when the metal was incorporated. In doing so, excessive sputteringby too-energetic metal ions can be avoided while the sp3/sp2 ratio can beadjusted. It is shown that the resistivity of the film can be tuned bythis species-selective bias. The principle can be extended tomultiple-material plasma sources and complex materials

  2. Analysis of Volcanic Deposits on Venus Using Radar Polarimetry

    Science.gov (United States)

    Douglas, M.; Carter, L. M.

    2015-12-01

    The atmosphere of Venus is relatively transparent at radio wavelengths, providing an opportunity to examine its volcanic planetary surface using radar. The highest resolution radar images come from the Magellan mission, which mapped 98% of Venus's surface by transmitting and receiving unidirectionally polarized radio waves. Upgrades to the ground-based Arecibo telescope in 1999 allowed further imaging of the surface of Venus at conjunction in 1999, 2001, and 2004 by the transmission of a circularly polarized beam at 12.6cm wavelength and then the reception of two orthogonal circular polarization components [Carter et al., 2006]. We apply the Stokes vector method to the Arecibo measurements to calculate the circular polarization ratio (CPR), an indication of surface roughness, and the degree of linear polarization (DLP), a measure of whether there is subsurface scattering of the radar wave. We combine both the CPR and DLP datasets to enable a more holistic geologic interpretation of Magellan images. This allows us to examine geographic variations in high-altitude, high-emissivity regions such Beta Regio, and to investigate regions that may contain young lava flows such as Themis Regio. Our approach permits a more precise geologic mapping of the textures of coronas and lava flow fields, including the identification of abnormally rugged lava flows. The data were also used to search for pyroclastics emanating from large and intermediate sized volcanoes within the region visible to Arecibo.

  3. Role of volcanic dust in the atmospheric transport and deposition of polycyclic aromatic hydrocarbons and mercury.

    Science.gov (United States)

    Stracquadanio, Milena; Dinelli, Enrico; Trombini, Claudio

    2003-12-01

    The role of volcanic ash as scavenger of atmospheric pollutants, in their transport and final deposition to the ground is examined. Attention is focused on polycyclic aromatic hydrocarbons (PAHs) and on particulate mercury (Hgp). The ash-fall deposits studied belong to the 2001 and 2002 eruptive activity of Mount Etna, Southern Italy, and were investigated at three (2001) and four (2002) sites downwind of the major tephra dispersal pattern. The dry deposition of mercury and PAHs was determined, and, in particular, a downward flux to the ground of PAHs (approximately 7.29 microg m(-2) per day) and mercury (750 ng m(-2) per day) was estimated in Catania from October 26 to October 28, 2002. Finally, evidence on the anthropogenic origin of PAHs scavenged from the troposphere by volcanic ash is supported by the analysis of PAH compositions in granulometrically homogeneous fractions.

  4. Modelling wet deposition in simulations of volcanic ash dispersion from hypothetical eruptions of Merapi, Indonesia

    Science.gov (United States)

    Dare, Richard A.; Potts, Rodney J.; Wain, Alan G.

    2016-10-01

    The statistical impact of including the process of wet deposition in dispersion model predictions of the movement of volcanic ash is assessed. Based on hypothetical eruptions of Merapi, Indonesia, sets of dispersion model simulations were generated, each containing four simulations per day over a period of three years, to provide results based on a wide range of atmospheric conditions. While on average dry sedimentation removes approximately 10% of the volcanic ash from the atmosphere during the first 24 h, wet deposition removes an additional 30% during seasons with highest rainfall (December and January) but only an additional 1% during August and September. The majority of the wet removal is due to in-cloud rather than below-cloud collection of volcanic ash particles. The largest uncertainties in the amount of volcanic ash removed by the process of wet deposition result from the choice of user-defined parameters used to compute the scavenging coefficient, and from the definition of the cloud top height. Errors in the precipitation field provided by the numerical weather prediction model utilised here have relatively less impact.

  5. Ultra-small platinum and gold nanoparticles by arc plasma deposition

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Sang Hoon, E-mail: kim_sh@kist.re.kr [Center for Materials Architecturing, Korea Institute of Science and Technology (KIST), Seoul 136-791 (Korea, Republic of); Jeong, Young Eun; Ha, Heonphil; Byun, Ji Young [Center for Materials Architecturing, Korea Institute of Science and Technology (KIST), Seoul 136-791 (Korea, Republic of); Kim, Young Dok [Department of Chemistry, Sungkyunkwan University, Suwon 440-746 (Korea, Republic of)

    2014-04-01

    Highlights: • Ultra-small (<2 nm) and bigger platinum and gold nanoparticles were produced by arc plasma deposition (APD). • Size and coverage of deposited nanoparticles were easily controlled with APD parameters. • Crystalline structures of deposited nanoparticles emerged only when the particle size was bigger than ∼2 nm. - Abstract: Ultra-small (<2 nm) nanoparticles of platinum and gold were produced by arc plasma deposition (APD) in a systematic way and the deposition behavior was studied. Nanoparticles were deposited on two dimensional amorphous carbon and amorphous titania thin films and characterized by transmission electron microscopy (TEM). Deposition behavior of nanoparticles by APD was studied with discharge voltage (V), discharge condenser capacitance (C), and the number of plasma pulse shots (n) as controllable parameters. The average size of intrinsic nanoparticles generated by APD process was as small as 0.9 nm and deposited nanoparticles began to have crystal structures from the particle size of about 2 nm. V was the most sensitive parameter to control the size and coverage of generated nanoparticles compared to C and n. Size of APD deposited nanoparticles was also influenced by the nature of evaporating materials and substrates.

  6. Stratigraphy, petrology, and geochemistry of the Spurr Volcanic Complex, eastern Aleutian Arc, Alaska. [(Appendix for geothermal fluid chemistry)

    Energy Technology Data Exchange (ETDEWEB)

    Nye, C.J.

    1987-12-01

    The Spurr Volcanic Complex (SVC) is a calcalkaline, medium-K, sequence of andesites erupted over the last quarter of a million years by the easternmost currently active volcanic center in the Aleutian Arc. The ancestral Mt. Spurr was built mostly of andesites of uniform composition (58 to 60% SiO/sub 2/), although andesite production was episodically interrupted by the introduction of new batches of more mafic magma. Near the end of the Pleistocene the ancestral Mt. Spurr underwent Bezyianny-type avalanche caldera formation, resulting in the production of a volcanic debris avalanche with overlying ashflows. Immediately afterward, a large dome (the present Mt. Spurr) was emplaced in the caldera. Both the ashflows and dome are made of acid andesite more silicic than any analyzed lavas from the ancestral Mt. Spurr (60 to 63% SiO/sub 2/), yet contain olivine and amphibole xenocrysts derived from more mafic magma. The mafic magma (53 to 57% SiO/sub 2/) erupted during and after dome emplacement, forming proto-Crater Peak and Crater Peak. Hybrid pyroclastic flows and lavas were also produced. Proto-Crater Peak underwent glacial dissection prior to the formation of Crater Peak in approximately the same location. Appendices II through VIII contain a summary of mineral compositions; Appendix I contains geochemical data. Appendix IX by R.J. Motyka and C.J. Nye describes the chemistry of geothermal fluids. 78 refs., 16 figs., 3 tabs.

  7. The 10 April 2014 Nicaraguan Crustal Earthquake: Evidence of Complex Deformation of the Central American Volcanic Arc

    Science.gov (United States)

    Suárez, Gerardo; Muñoz, Angélica; Farraz, Isaac A.; Talavera, Emilio; Tenorio, Virginia; Novelo-Casanova, David A.; Sánchez, Antonio

    2016-10-01

    On 10 April 2014, an M w 6.1 earthquake struck central Nicaragua. The main event and the aftershocks were clearly recorded by the Nicaraguan national seismic network and other regional seismic stations. These crustal earthquakes were strongly felt in central Nicaragua but caused relatively little damage. This is in sharp contrast to the destructive effects of the 1972 earthquake in the capital city of Managua. The differences in damage stem from the fact that the 1972 earthquake occurred on a fault beneath the city; in contrast, the 2014 event lies offshore, under Lake Managua. The distribution of aftershocks of the 2014 event shows two clusters of seismic activity. In the northwestern part of Lake Managua, an alignment of aftershocks suggests a northwest to southeast striking fault, parallel to the volcanic arc. The source mechanism agrees with this right-lateral, strike-slip motion on a plane with the same orientation as the aftershock sequence. For an earthquake of this magnitude, seismic scaling relations between fault length and magnitude predict a sub-surface fault length of approximately 16 km. This length is in good agreement with the extent of the fault defined by the aftershock sequence. A second cluster of aftershocks beneath Apoyeque volcano occurred simultaneously, but spatially separated from the first. There is no clear alignment of the epicenters in this cluster. Nevertheless, the decay of the number of earthquakes beneath Apoyeque as a function of time shows the typical behavior of an aftershock sequence and not of a volcanic swarm. The northeast-southwest striking Tiscapa/Ciudad Jardín and Estadio faults that broke during the 1972 and 1931 Managua earthquakes are orthogonal to the fault where the 10 April earthquake occurred. These orthogonal faults in close geographic proximity show that Central Nicaragua is being deformed in a complex tectonic setting. The Nicaraguan forearc sliver, between the trench and the volcanic arc, moves to the

  8. The 10 April 2014 Nicaraguan Crustal Earthquake: Evidence of Complex Deformation of the Central American Volcanic Arc

    Science.gov (United States)

    Suárez, Gerardo; Muñoz, Angélica; Farraz, Isaac A.; Talavera, Emilio; Tenorio, Virginia; Novelo-Casanova, David A.; Sánchez, Antonio

    2015-11-01

    On 10 April 2014, an M w 6.1 earthquake struck central Nicaragua. The main event and the aftershocks were clearly recorded by the Nicaraguan national seismic network and other regional seismic stations. These crustal earthquakes were strongly felt in central Nicaragua but caused relatively little damage. This is in sharp contrast to the destructive effects of the 1972 earthquake in the capital city of Managua. The differences in damage stem from the fact that the 1972 earthquake occurred on a fault beneath the city; in contrast, the 2014 event lies offshore, under Lake Managua. The distribution of aftershocks of the 2014 event shows two clusters of seismic activity. In the northwestern part of Lake Managua, an alignment of aftershocks suggests a northwest to southeast striking fault, parallel to the volcanic arc. The source mechanism agrees with this right-lateral, strike-slip motion on a plane with the same orientation as the aftershock sequence. For an earthquake of this magnitude, seismic scaling relations between fault length and magnitude predict a sub-surface fault length of approximately 16 km. This length is in good agreement with the extent of the fault defined by the aftershock sequence. A second cluster of aftershocks beneath Apoyeque volcano occurred simultaneously, but spatially separated from the first. There is no clear alignment of the epicenters in this cluster. Nevertheless, the decay of the number of earthquakes beneath Apoyeque as a function of time shows the typical behavior of an aftershock sequence and not of a volcanic swarm. The northeast-southwest striking Tiscapa/Ciudad Jardín and Estadio faults that broke during the 1972 and 1931 Managua earthquakes are orthogonal to the fault where the 10 April earthquake occurred. These orthogonal faults in close geographic proximity show that Central Nicaragua is being deformed in a complex tectonic setting. The Nicaraguan forearc sliver, between the trench and the volcanic arc, moves to the

  9. Arc discharge deposition of stainless steel coatings at different nitrogen pressures

    Energy Technology Data Exchange (ETDEWEB)

    Koskinen, J. [VTT Manufacturing Technology (Finland); Torri, P. [Helsinki Univ. (Finland). Dept. of Physics; Hirvonen, J.P. [VTT Manufacturing Technology (Finland); Mahiout, A. [VTT Manufacturing Technology (Finland); Stanishevsky, A. [Plasmoteg Engineering Centre, Minsk (Belarus)

    1996-03-01

    A filtered arc discharge process was employed to deposit stainless steel films using an AISI316 cathode. In this procedure, macroparticles and droplets, which are the most serious drawback of arc deposition processes especially in corrosion applications, are mostly filtered out. Films were deposited in vacuum or in the presence of a nitrogen plasma at different partial pressures. Low carbon steel and silicon single crystals were employed as substrates. Rutherford backscattering spectrometry (RBS), nuclear reaction analysis (NRA) and X-ray diffraction (XRD) were used to characterize the films. The corrosion properties were examined using electrochemical polarization measurements. The corrosion current density was clearly lower than that of bulk steel, but higher than that of bulk AISI316. Increasing the film thickness and nitrogen content lowered the corrosion current density. (orig.)

  10. ELECTRIC ARC WELDING DEPOSITION OF METALLIC SURFACES BY VIBRATING ELECTRODE IN PROTECTIVE GAS MEDIUM

    Directory of Open Access Journals (Sweden)

    N. Spiridonov

    2013-01-01

    Full Text Available The paper presents methods for obtaining qualitative metallic surfaces by electric arc welding deposition while using consumable electrode in a protective gas medium and executing regularized drop transfer of electrode metal. The drop transfer efficiency of electrode metal and productivity of welding deposition are significantly increased due to excitation of lateral vibrations in the consumable electrode with preset amplitude. The paper describes a method and a device for welding deposition of metallic surfaces by vibrating  electrode where vibrations are excited by ultrasound.

  11. Newly developed evidence for the original Tethysan island-arc volcanic rocks in the southern segment of the South Lancangjiang Belt

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    This paper re-describes the characteristics of pre-Ordovician (Pt3) metamorphic volcanic rocks in the Huimin-Manlai region of Yunnan Province from the aspects of petrographic characteristics, rock assemblage, petrochemistry, REE, trace elements, lead isotopes and geotectonic setting. The metamorphic volcanic rocks maintain blasto-intergranular and blasto-andesitic textures; the volcanic rocks are characterized by a basalt-andesite-dacite assemblage; the volcanic rocks are basic-intermediate-intermediate-acid in chemical composition, belonging to semi-alkaline rocks, with calc-alkaline series and tholeiite series coexisting, and they are characterized by low TiO2 contents; their REE distribution patterns are of the LREE-enrichment right-inclined type; the volcanic rocks are enriched in large cation elements and commonly enriched in Th and partly depleted in Ti, Cr and P, belonging to the Gondwana type as viewed from their Pb isotopic composition; petrochemically the data points fall mostly within the field of island-arc volcanic rocks. All these characteristics provided new evidence for the existence of original Tethysan island-arc volcanic rocks in the region studied.

  12. Depositional and Immersion-Mode Ice Nucleation of Fine-Grained Volcanic Ash Samples

    Science.gov (United States)

    Cloer, S.; Woods, T.; Genareau, K. D.

    2016-12-01

    Volcanic lightning is a common phenomenon during explosive eruptions; occurring as vent discharges, near-vent discharges, and plume lightning. Plume lightning is most similar to thunderstorm lightning, where volcanic ash may act as ice nuclei. Volcanic ash samples derived from eight volcanoes: Augustine, Crater Peak, Katmai, Okmok, Redoubt (Alaska, U.S.A.), Lathrop Well (Nevada, U.S.A.), Taupo (New Zealand), and Valles Caldera (New Mexico, U.S.A.); were used to determine what roles ash mineralogy, particularly Fe-oxide-bearing minerals and silica-enriched minerals, grain shape, and grain size have in the nucleation of ice, which can generate plume lightning. Depositional and immersion-mode ice nucleation experiments were performed using a Nicolet Almega XR Dispersive Raman spectrometer, following the methods of Schill et al. (2015), where samples were shaken for 24 h prior to experiments in ultra-pure water, then nebulized to super micron droplets. Depositional nucleation experiments were conducted from 225-235 K, and immersion-mode nucleation experiments were conducted from 233-278 K. A JEOL JSM 6010 Plus/LA scanning electron microscope (SEM), along with Image-J freeware, was used to quantify the number density of Fe-oxide mineral phases in backscattered electron images, with an x-ray diffractometer (XRD) used to determine bulk mineral abundance and an x-ray fluorescence (XRF) spectrometer to determine bulk ash composition. Based on previous studies, we hypothesize that all ash samples will efficiently form depositional ice nuclei; however, certain mineral phases will dictate the efficiency of immersion-mode ice nucleation including K or Na / Ca feldspars, which have been shown to be efficient nuclei, and Fe-oxide-bearing minerals. These results will shed new light on volcanic cloud dynamics and add new parameters for atmospheric models, which currently only address effects of mineral dust as ice nuclei and overlook the potential role of volcanic ash.

  13. Late-Pleistocene to precolumbian behind-the-arc mafic volcanism in the eastern Mexican Volcanic Belt; implications for future hazards

    Science.gov (United States)

    Siebert, Lee; Carrasco-Núñez, Gerardo

    2002-06-01

    An area of widespread alkaline-to-subalkaline volcanism lies at the northern end of the Cofre de Perote-Citlaltépetl (Pico de Orizaba) volcanic chain in the eastern Mexican Volcanic Belt (MVB). Two principal areas were active. About a dozen latest-Pleistocene to precolumbian vents form the 11-km-wide, E-W-trending Cofre de Perote vent cluster (CPVC) at 2300-2800 m elevation on the flank of the largely Pleistocene Cofre de Perote shield volcano and produced an extensive lava field that covers >100 km 2. More widely dispersed vents form the Naolinco volcanic field (NVF) in the Sierra de Chiconquiaco north of the city of Jalapa (Xalapa). Three generations of flows are delineated by cone and lava-flow morphology, degree of vegetation and cultivation, and radiocarbon dating. The flows lie in the behind-the-arc portion of the northeastern part of the MVB and show major- and trace-element chemical patterns transitional between intraplate and subduction zone environments. Flows of the oldest group originated from La Joya cinder cone (radiocarbon ages ˜42 000 yr BP) at the eastern end of the CPVC. This cone fed an olivine-basaltic flow field of ˜20 km 2 that extends about 14 km southeast to underlie the heavily populated northern outskirts of Jalapa, the capital city of the state of Veracruz. The Central Cone Group (CCG), of intermediate age, consists of four morphologically youthful cinder cones and associated vents that were the source of a lava field>27 km 2 of late-Pleistocene or Holocene age. The youngest group includes the westernmost flow, from Cerro Colorado, and a lava flow ˜2980 BP from the Rincón de Chapultepec scoria cone of the NVF. The latest eruption, from the compound El Volcancillo scoria cone, occurred about 870 radiocarbon years ago and produced two chemically and rheologically diverse lava flows that are among the youngest precolumbian flows in México and resemble paired aa-pahoehoe flows from Mauna Loa volcano. The El Volcancillo eruption

  14. Sintering of Glass in Hydrous Atmospheres and its Implications for Welding of Volcanic Deposits

    Science.gov (United States)

    von Aulock, F. W.; Wadsworth, F. B.; Lavallée, Y.; Vasseur, J.

    2014-12-01

    Volcanic ash sintering can occur during hot deposition or upon reheating, and recently published models have improved our understanding of viscous sintering timescales at magmatic temperatures. However, in most volcanic environments, water is present either from meteoric or magmatic sources. Water significantly lowers the viscosity of liquids and therefore should alter the onset temperature and timescales of sintering. The diffusion of water in melts and glasses at low (sub-liquidus) temperatures and pressures, and the partitioning between water vapor and dissolved water species are poorly understood. We investigate the impact of a water rich Ar -atmosphere on viscous sintering at temperatures close to the glass transition. Synthetic near-spherical soda-lime silica glass beads with a well-constrained size of about 10-350μm (produced by Spheriglass) were heated in simultaneous thermal analyses of both differential scanning calorimetry and thermogravimetry. Glass transition temperature onset and mass stayed consistent under argon atmosphere during successive heating cycles at a rate of 10 °C.min-1. Contrastingly, preliminary results show that, when heated, closely packed in a water-argon atmosphere (1) there is a measurable water uptake during timescales as short as 2 hours, and (2) sintering is more efficient and densification takes place at lower temperatures and/or within shorter timescales. Sintering of volcanic materials reduces both porosity and permeability of volcanic products. The process of sintering is, however, limited by quenching of the material shortly after eruption. External water present during deposition could allow welding of pyroclastic deposits at conditions and timescales otherwise not achievable from the deposited pyroclasts alone.. Viscous sintering in a water-rich atmosphere may enhance resorption and encourage the formation of vesicle-free obsidian.

  15. Geochemistry and petrology of the most recent deposits from Cotopaxi volcano, Northern Volcanic Zone, Ecuador.

    OpenAIRE

    2011-01-01

    Cotopaxi volcano is located in the Northern Volcanic Zone of the South American Andes. Pyroclastic deposits and lava flows from Cotopaxi comprise basaltic andesites, andesites and rhyolites that have erupted since 13 200 years BP. Nine rhyolite eruptions were produced in at least five separate events, punctuated by intermittent andesite eruptions. High La/Yb (>5) and 230Th excesses in the andesites are consistent with equilibration of magma with garnet-bearing lower crust or mantle, and numer...

  16. Filtered pulsed cathodic arc deposition of fullerene-like carbon and carbon nitride films

    Energy Technology Data Exchange (ETDEWEB)

    Tucker, Mark D., E-mail: martu@ifm.liu.se; Broitman, Esteban; Näslund, Lars-Åke; Hultman, Lars; Rosen, Johanna [Thin Film Physics Division, Department of Physics, Chemistry and Biology (IFM), Linköping University, SE-58183 Linköping (Sweden); Czigány, Zsolt [Institute for Technical Physics and Materials Science, RCNS, Hungarian Academy of Sciences, P.O. Box 49, H-1525 Budapest (Hungary)

    2014-04-14

    Carbon and carbon nitride films (CN{sub x}, 0 ≤ x ≤ 0.26) were deposited by filtered pulsed cathodic arc and were investigated using transmission electron microscopy and X-ray photoelectron spectroscopy. A “fullerene-like” (FL) structure of ordered graphitic planes, similar to that of magnetron sputtered FL-CN{sub x} films, was observed in films deposited at 175 °C and above, with N{sub 2} pressures of 0 and 0.5 mTorr. Higher substrate temperatures and significant nitrogen incorporation are required to produce similar FL structure by sputtering, which may, at least in part, be explained by the high ion charge states and ion energies characteristic of arc deposition. A gradual transition from majority sp{sup 3}-hybridized films to sp{sup 2} films was observed with increasing substrate temperature. High elastic recovery, an attractive characteristic mechanical property of FL-CN{sub x} films, is evident in arc-deposited films both with and without nitrogen content, and both with and without FL structure.

  17. Filtered pulsed cathodic arc deposition of fullerene-like carbon and carbon nitride films

    Science.gov (United States)

    Tucker, Mark D.; Czigány, Zsolt; Broitman, Esteban; Näslund, Lars-Åke; Hultman, Lars; Rosen, Johanna

    2014-04-01

    Carbon and carbon nitride films (CNx, 0 ≤ x ≤ 0.26) were deposited by filtered pulsed cathodic arc and were investigated using transmission electron microscopy and X-ray photoelectron spectroscopy. A "fullerene-like" (FL) structure of ordered graphitic planes, similar to that of magnetron sputtered FL-CNx films, was observed in films deposited at 175 °C and above, with N2 pressures of 0 and 0.5 mTorr. Higher substrate temperatures and significant nitrogen incorporation are required to produce similar FL structure by sputtering, which may, at least in part, be explained by the high ion charge states and ion energies characteristic of arc deposition. A gradual transition from majority sp3-hybridized films to sp2 films was observed with increasing substrate temperature. High elastic recovery, an attractive characteristic mechanical property of FL-CNx films, is evident in arc-deposited films both with and without nitrogen content, and both with and without FL structure.

  18. Behavior of volatiles in arc volcanism : geochemical and petrologic evidence from active volcanoes in Indonesia

    NARCIS (Netherlands)

    Hoog, J.C.M. de

    2001-01-01

    Large amounts of material are recycled along subduction zones by uprising magmas, of which volcanoes are the surface expression. This thesis focuses on the behavior of volatiles elements (S, Cl, H) during these recycling processes. The study area is the Indonesian arc system, which hosts

  19. Behavior of volatiles in arc volcanism : geochemical and petrologic evidence from active volcanoes in Indonesia

    NARCIS (Netherlands)

    Hoog, J.C.M. de

    2001-01-01

    Large amounts of material are recycled along subduction zones by uprising magmas, of which volcanoes are the surface expression. This thesis focuses on the behavior of volatiles elements (S, Cl, H) during these recycling processes. The study area is the Indonesian arc system, which hosts

  20. Fracture development within a stratovolcano: The Karaha-Telaga Bodas geothermal field, Java volcanic arc

    Science.gov (United States)

    Nemcok, M.; Moore, J.N.; Allis, R.; McCulloch, J.

    2004-01-01

    Karaha-Telaga Bodas, a vapour-dominated geothermal system located in an active volcano in western Java, is penetrated by more than two dozen deep geothermal wells reaching depths of 3 km. Detailed paragenetic and fluid-inclusion studies from over 1000 natural fractures define the liquid-dominated, transitional and vapour-dominated stages in the evolution of this system. The liquid-dominated stage was initiated by ashallow magma intrusion into the base of the volcanic cone. Lava and pyroclastic flows capped a geothermal system. The uppermost andesite flows were only weakly fractured due to the insulating effect of the intervening altered pyroclastics, which absorbed the deformation. Shear and tensile fractures that developed were filled with carbonates at shallow depths, and by quartz, epidote and actinolite at depths and temperatures over 1 km and 300??C. The system underwent numerous cycles of overpressuring, documented by subhorizontal tensile fractures, anastomosing tensile fracture patterns and implosion breccias. The development of the liquidsystem was interrupted by a catastrophic drop in fluid pressures. As the fluids boiled in response to this pressure drop, chalcedony and quartz were selectively deposited in fractures that had the largest apertures and steep dips. The orientations of these fractures indicate that the escaping overpressured fluids used the shortest possible paths to the surface. Vapour-dominated conditions were initiated at this time within a vertical chimney overlying the still hot intrusion. As pressures declined, these conditions spread outward to form the marginal vapour-dominated region encountered in the drill holes. Downward migration of the chimney, accompanied by growth of the marginal vapour-dominated regime, occurred as the intrusion cooled and the brittle-ductile transition migrated to greater depths. As the liquids boiled off, condensate that formed at the top of the vapour-dominated zone percolated downward and low

  1. The Montesbelos mass-flow (southern Amazonian craton, Brazil): a Paleoproterozoic volcanic debris avalanche deposit?

    Science.gov (United States)

    Roverato, M.

    2016-07-01

    The present contribution documents the extremely well-preserved Paleoproterozoic architecture of the Montesbelos breccia (named here for the first time), which is interpreted as a rare example of a subaerial paleoproterozoic (>1.85 Ga) granular-dominated mass-flow deposit, few of which are recorded in the literature. Montesbelos deposit is part of the andesitic Sobreiro Formation located in the São Felix do Xingu region, southern Amazonian craton, northern Brazil. The large volume, high variability of textural features, presence of broken clasts, angular low sphericity fragments, mono- to heterolithic character, and the size of the outcrops point to a volcanic debris avalanche flow. Fluviatile sandy material and debris flows are associated with the deposit as a result of post-depositional reworking processes.

  2. Localised magmatic constraints on continental back-arc volcanism in southern Mendoza, Argentina: the Santa Maria Volcano

    Science.gov (United States)

    Espanon, Venera R.; Chivas, Allan R.; Turner, Simon P.; Kinsley, Leslie P. J.; Dosseto, Anthony

    2016-11-01

    The Payún Matrú Volcanic Field constitutes part of the continental back-arc in Argentina. This volcanic field has been the focus of several regional investigations; however, geochemical analysis of recent volcanoes (<8 ka) at the scale of an individual volcano has not been conducted. We present a morphological description for the Santa Maria Volcano in addition to results from major and trace element analysis and 238U-230Th-226Ra disequilibria. The trace element evidence suggests that the Santa Maria magmatic source has a composition similar to that of the local intraplate end member (resembling an ocean island basalt-like source), with a slight contribution from subduction-related material. The U-series analyses suggest a high 226Ra excess over 230Th for this volcano, which is not derived from a shallow process such as hydrothermal alteration or upper crustal contamination. Furthermore, intermediate-depth processes such as fractional crystallisation have been inferred for the Santa Maria Volcano, but they are not capable of producing the 226Ra excess measured. The 226Ra excess is explained by deep processes like partial melting of mantle lithologies with some influence from subducted Chilean trench sediments. Due to the short half-life of 226Ra (1600 years), we infer that fast magma ascent rates are required to preserve the high 226Ra excess.

  3. Growth and characteristics of tantalum oxide thin films deposited using thermionic vacuum arc technology

    Science.gov (United States)

    Vladoiu, Rodica; Ciupina, Victor; Mandes, Aurelia; Dinca, Virginia; Prodan, Madalina; Musa, Geavit

    2010-11-01

    Tantalum pentoxide (Ta2O5) thin films were synthesized using thermionic vacuum arc (TVA) technology. TVA is an original deposition method using a combination of anodic arc and electron gun system for the growth of thin films from solid precursors under vacuum of 10-6 Torr. The properties of the deposited Ta2O5 thin films were investigated in terms of wettability, refractive index, morphology, and structure. The surface free energy was determined by means of surface energy evaluation system indicating a hydrophilic character and the refractive index was measured by Filmetrics F20 device. The morphology was determined from bright field transmission electron microscopy (TEM) image performed by Philips CM 120 ST TEM system. It exhibits nanoparticles of 3-6 nm diameter smoothly distributed. Selected area electron diffraction pattern revealed the contrast fringes given by complex polycrystalline particles included in the amorphous film. The measured fringes could be indexed using monoclinic structure of Ta2O5.

  4. The influence of volcanic activity in the Campi Flegrei coastal depositional system

    Science.gov (United States)

    Violante, Crescenzo; Esposito, Eliana; Molisso, Flavia; Porfido, Sabina; Sacchi, Marco

    2010-05-01

    The Campi Flegrei coastal area includes the bay of Pozzuoli, Procida and Ischia islands, characterized by active tectonics and volcanism since the Pleistocene. Numerous monogenic volcanoes occur close to the shoreline and volcanic debris interpreted as submarine counterpart of subaerial flows and surges, have been detected offshore. In the Pozzuoli area the most recent eruptive volcanic activity occurred from 10.0 to 8.0 ky B.P and 4.5 to 3.7 ky B.P. followed by the September 1538 Monte Nuovo eruption. Here magma-related activity is testified by extensive hydrothermalism, and recent episodes (1970-71 and 1982-84 on Pozzuoli coast) of shallow seismicity and ground deformation, exceeding rates of 100 cm/year in the years 1983-1984. The most recent volcanic activity on Ischia island starts around 10.0 ky B.P. to which associates several eruptive centres mostly located in the western sector. The last eruption dates back to Arso flow in 1302. Nevertheless the landscape of Ischia is dominated by Mount Epomeo in the central part of the island, which is the highest peak (788 m). It is a volcano-tectonic structure that raised above sea level between 33 and 28 ka BP, due to the intrusion of magma at shallow depth. Procida island is composed of five monogenic Volcanoes (Vivara, Terra Murata, Pozzo Vecchio, Fiumicello and Solchiaro) that have been active over the last 80 ky producing pyroclastic deposits and a lava dome. A sixth volcanic structure has been reported recently off P.ta Serra by marine investigations and confirmed by airborne magnetic surveys. The emplacement of large amount of volcanoclastic material from volcanic and volcano-tectonic activity in the Campi Flegrei coastal area produced extensive avalanche deposits off Ischia island, seafloor instabilities in the form of creep/slump, channelled sediment flow and deep sedimentary fans, and is largely responsible for aggradation/progradation of the coastal area during the Quaternary. Moreover, numerous volcanic bank

  5. The tectonic emplacement of Sumba in the Sunda-Banda Arc: paleomagnetic and geochemical evidence from the early Miocene Jawila volcanics

    Science.gov (United States)

    Wensink, Hans; van Bergen, Manfred J.

    1995-11-01

    The island of Sumba is a continental fragment in the fore-arc region near the transition between the Sunda Arc and Banda Arc in southeastern Indonesia. Paleomagnetic and geochemical evidence from the early Miocene volcanics of the Jawila Formation in western Sumba constrain the final drift stage and tectonic emplacement of the island. The lavas range from predominantly andesites to dacites, and display textural evidence for a weak metamorphism. Rock magnetic and mineral chemical data point to pseudo-single- to multi-domain (titano)magnetite (Fe 2.5-3Ti 0.5-0O 3), with grain sizes up to 10 μm, as the main carrier of remanence. The Jawila Formation reveals a ChRM direction with declination = 4.6°, inclination = - 19.2°, α95 = 9.9° and a paleolatitude of 9.9°S, which corroborates earlier results (Chamalaun and Sunata, 1982). Taking paleomagnetic evidence from other formations on the island into account, we conclude that the Sumba fragment has occupied approximately its present position since the Miocene. The calc-alkaline affinity and trace-element signatures of the lavas point to an origin in an arc environment. This occurrence of subduction-related volcanic activity in the early Miocene on Sumba implies that a volcanic arc existed south of the present-day East Sunda Arc, or that the island was located within the latter arc between Sumbawa and eastern Flores, and still had a minor southward drift to cover.

  6. Structure and properties of protective coatings produced by vacuum arc deposition

    Energy Technology Data Exchange (ETDEWEB)

    Leontiev, S.A. [Leningradsky Metallitchesky Zavod, St. Petersburg (Russian Federation); Kuznetsov, V.G. [Machine Research Problems Institute, Russian Academy of Sciences V.O., Bolshoy pr. 61, 199178 St. Petersburg (Russian Federation); Rybnikov, A.I. [Polzunov Central Boiler and Turbine Institute (NPO TsKTI), Polytechnicheskaya 24, 194021 St. Petersburg (Russian Federation); Burov, I.V. [Machine Research Problems Institute, Russian Academy of Sciences V.O., Bolshoy pr. 61, 199178 St. Petersburg (Russian Federation)

    1995-11-01

    CoCrAlY, NiCrWTi and CoCrAlY/ZrO{sub 2}+8wt.%Y{sub 2}O{sub 3} coatings were deposited by vacuum arc evaporation. Coatings were deposited onto specimens for metallographic analysis, corrosion resistance testing, thermal fatigue testing, high-frequency fatigue and onto gas turbine blades. It has been shown by testing that the developed procedures ensure gas turbine blade coatings of high quality comparable with those manufactured by electron beam procedures. (orig.)

  7. Geochemistry of the Bonin Fore-arc Volcanic Sequence: Results from IODP Expedition 352

    Science.gov (United States)

    Godard, M.; Ryan, J. G.; Shervais, J. W.; Whattam, S. A.; Sakuyama, T.; Kirchenbaur, M.; Li, H.; Nelson, W. R.; Prytulak, J.; Pearce, J. A.; Reagan, M. K.

    2015-12-01

    The Izu-Bonin-Mariana intraoceanic arc system, in the western Pacific, results from ~52 My of subduction of the Pacific plate beneath the eastern margin of the Philippine Sea plate. Four sites were drilled south of the Bonin Islands during IODP Expedition 352 and 1.22 km of igneous basement was cored upslope to the west of the trough. These stratigraphically controlled igneous suites allow study of the earliest stages of arc development from seafloor spreading to convergence. We present the preliminary results of a detailed major and trace element (ICPMS) study on 128 igneous rocks drilled during Expedition 352. Mainly basalts and basaltic andesites were recovered at the two deeper water sites (U1440 and U1441) and boninites at the two westernmost sites (U1439 and U1442). Sites U1440 and U1441 basaltic suites are trace element depleted (e.g. Yb 4-6 x PM); they have fractionated REE patterns (LREE/HREE = 0.2-0.4 x C1-chondrites) compared to mid-ocean ridge basalts. They have compositions overlapping that of previously sampled Fore-Arc Basalts (FAB) series. They are characterized also by an increase in LILE contents relative to neighboring elements up-section (e.g. Rb/La ranging from FAB generation into their mantle source.

  8. Tsunami deposits at high altitudes on the flanks of volcanic islands

    Science.gov (United States)

    Paris, Raphael

    2016-04-01

    It is actually difficult to infer the mechanisms and dynamics of giant mass failures of oceanic shield volcanoes and to evaluate related tsunami hazards. Marine conglomerates and gravels found at unusually high elevations in Hawaii, Cape Verde, Mauritius and Canary Islands are often interpreted as being the result of tsunami waves generated by such massive flank failures. In the first part of this contribution, we document tsunami deposits (marine gravels with pumices) attached to the northwestern slopes of Tenerife, Canary Islands, at altitudes up to 132 m asl. Stratigraphy of the deposits and composition of the pumices allows identifying sources of the successive tsunamis and proposing a new scenario for the Icod flank failure and El Abrigo caldera-forming eruption ca. 170 ka. Then we propose a litterature review of tsunami deposits at high altitudes on the flanks of volcanic islands, and especially oceanic shield volcanoes. These deposits are discussed in terms of texture, structure, composition and particularly the juvenile volcanic material, and implications for better understanding the mechanisms controlling massive flank failures.

  9. Contamination due to memory effects in filtered vacuum arc plasma deposition systems

    CERN Document Server

    Martins, D R; Verdonck, P; Brown, I G

    2002-01-01

    Thin film synthesis by filtered vacuum arc plasma deposition is a widely used technique with a number of important emerging technological applications. A characteristic feature of the method is that during the deposition process not only is the substrate coated by the plasma, but the plasma gun itself and the magnetic field coil and/or vacuum vessel section constituting the macroparticle filter are also coated to some extent. If then the plasma gun cathode is changed to a new element, there can be a contamination of the subsequent film deposition by sputtering from various parts of the system of the previous coating species. We have experimentally explored this effect and compared our results with theoretical estimates of sputtering from the SRIM (Stopping and Range of Ions in Matter) code. We find film contamination of order 10-4 - 10-3, and the memory of the prior history of the deposition hardware can be relatively long-lasting.

  10. Wear Resistance of Deposited Layer Using Nickel-Based Composite Powders by Plasma-Arc Surfacing

    Institute of Scientific and Technical Information of China (English)

    DONG Li-hong; ZHU Sheng; XU Bin-shi; DU Ze-yu

    2004-01-01

    Nickel-based composite alloy powders were deposited on the surface of Q235 steel by plasma-arc surfacing in this work. Optimal proportions of elements intensifying the composite powders were ascertained by orthogonal design of three factors and three levels and orthogonal polynomial regression analysis , which Cr , Mn , W were 10% ,4% and 7 % respectively.Phase and structure of deposited materials were characterized by optical microscope and X- ray diffraction. Hardness tests and wear resistance tests were carried out to determine the performance of the deposited layers. The results show that the microstructure of deposited layers of composite powders mainly consist of γ-( Ni, Fe ) , γ- Ni, WC, W2 C, Mn31Si12, Cr23 C6,Cr7 C3, Cr, NiB, Ni2B etc. Wear resistance and hardness of the surface increased evidently.

  11. Temporal and geochemical evolution of Miocene volcanism in the Andean back-arc between 36°S and 38°S and U-series analyses of young volcanic centers in the arc and back-arc, Argentina

    DEFF Research Database (Denmark)

    Dyhr, Charlotte Thorup

    of the subducting slab at ca. 20 Ma is inferred. The eruption of 24-20 Ma alkali olivine basalt up to 500 km east of the trench marks the beginning of a long-lasting magmatic episode with widespread volcanism north of the Cortaderas lineament following a regional magmatic hiatus lasting from 39 Ma to 26 Ma...

  12. Basalt-Limestone and Andesite-Limestone Interaction in the Arc Crust - Implications for Volcanic Degassing of CO2

    Science.gov (United States)

    Carter, L. B.; Dasgupta, R.

    2014-12-01

    Volcanically emitted CO2 is generally mantle-derived, but high degassing rates at some arcs (e.g. Merapi [1] and Colli Albani Volcanic District [2]) are thought to be affected by magma-carbonate interaction in the upper plate. However, the effects of depth, temperature, and composition on this process are poorly known. We experimentally simulated magma (50%)-limestone (50%) wallrock interactions at 0.5-1.0 GPa, 1100-1200 °C using pure calcite and a hydrous (~3-5 wt.% H2O) melt (basalt, andesite, or dacite). At 1.0 GPa, 1200 °C starting melts are superliquidus, whereas in the presence of calcite, Ca-rich cpx ± Ca-scapolite are produced. With increasing T, basalt-calcite interaction causes the melt, on a volatile-free basis, to become silica-poor and Ca-rich with alumina decreasing as cpx becomes more CaTs-rich. The same trend is seen with all starting melt compositions as P decreases at a constant T (1200 °C), producing melts similar to ultracalcic (CaO/Al2O3>>1) melt inclusions found in arc settings. Shifting from basalt to andesite has little effect on SiO2 and CaO of the reacted melt (e.g. 37 wt.% SiO2, 42 wt.% CaO at 0.5 GPa, 1200 °C), whereas Al2O3 of andesite-derived reacted melt is lower, likely a result of lower alumina in the starting andesite. Wall-rock calcite consumption is observed to increase with increasing T, decreasing P, and increasing melt XSiO2. At 0.5 GPa between 1100 and 1200 °C, our basalt experiments yield carbonate assimilation from 22 to 48 wt.%. This decreases to 20 wt.% at 1.0 GPa, 1200 °C, whereas an andesitic composition assimilates 59 to 52 wt.% from 0.5 to 1.0 GPa at 1200 °C. The higher assimilation in andesite-added runs at high-T is because of lower silicate liquidus as evidenced by lower modal proportion or absence of cpx ± scapolite. Using a magma flux rate estimated for Mt. Vesuvius [3], we obtain a CO2 outflux for a single such volcano experiencing arc magma-calcite reaction [4] of at least 2-4% of the present

  13. Characterization of volcanic deposits and geoarchaeological studies from the 1815 eruption of Tambora volcano

    Directory of Open Access Journals (Sweden)

    Igan Supriatman Sutawidjaja

    2014-06-01

    Full Text Available http://dx.doi.org/10.17014/ijog.vol1no1.20066aThe eruption of Tambora volcano on the island of Sumbawa in 1815 is generally considered as the largest and the most violent volcanic event in recorded history. The cataclysmic eruption occurred on 11 April 1815 was initiated by Plinian eruption type on 5 April and killed more than 90,000 people on Sumbawa and nearby Lombok. The type plinian eruptions occurred twice and ejected gray pumice and ash, to form stratified deposits as thick as 40-150 cm on the slopes and mostly distributed over the district west of the volcano. Following this, at about 7 pm, on 11 April the first pyroclastic surge was generated and progressively became greater extending to almost whole direction, mainly to the north, west, and south districts from the eruption center. The deadliest volcanic eruption buried ancient villages by pyroclastic surge and flow deposits in almost intact state, thus preserving important archaeological evidence for the period. High preservation in relatively stable conditions and known date of the eruptions provide approximate dating for the archaeological remains. Archaeological excavations on the site uncovered a variety of remains were relieved by ground penetrating radar (GPR to map structural remains of the ancient villages under the pyroclastic surge and flow deposits. These traverses showed that GPR could define structures as deep as 10 m (velocity 0.090 m/ns and could accurately map the thickness of the stratified volcanic deposits in the Tambora village area.    

  14. Characterization of volcanic deposits and geoarchaeological studies from the 1815 eruption of Tambora volcano

    Directory of Open Access Journals (Sweden)

    Igan Supriatman Sutawidjaja

    2014-06-01

    Full Text Available http://dx.doi.org/10.17014/ijog.vol1no1.20066aThe eruption of Tambora volcano on the island of Sumbawa in 1815 is generally considered as the largest and the most violent volcanic event in recorded history. The cataclysmic eruption occurred on 11 April 1815 was initiated by Plinian eruption type on 5 April and killed more than 90,000 people on Sumbawa and nearby Lombok. The type plinian eruptions occurred twice and ejected gray pumice and ash, to form stratified deposits as thick as 40-150 cm on the slopes and mostly distributed over the district west of the volcano. Following this, at about 7 pm, on 11 April the first pyroclastic surge was generated and progressively became greater extending to almost whole direction, mainly to the north, west, and south districts from the eruption center. The deadliest volcanic eruption buried ancient villages by pyroclastic surge and flow deposits in almost intact state, thus preserving important archaeological evidence for the period. High preservation in relatively stable conditions and known date of the eruptions provide approximate dating for the archaeological remains. Archaeological excavations on the site uncovered a variety of remains were relieved by ground penetrating radar (GPR to map structural remains of the ancient villages under the pyroclastic surge and flow deposits. These traverses showed that GPR could define structures as deep as 10 m (velocity 0.090 m/ns and could accurately map the thickness of the stratified volcanic deposits in the Tambora village area.    

  15. Neotectonic development of the El Salvador Fault Zone and implications for deformation in the Central America Volcanic Arc: Insights from 4-D analog modeling experiments

    Science.gov (United States)

    Alonso-Henar, Jorge; Schreurs, Guido; Martinez-Díaz, José Jesús; Álvarez-Gómez, José Antonio; Villamor, Pilar

    2015-01-01

    The El Salvador Fault Zone (ESFZ) is an active, approximately 150 km long and 20 km wide, segmented, dextral strike-slip fault zone within the Central American Volcanic Arc striking N100°E. Although several studies have investigated the surface expression of the ESFZ, little is known about its structure at depth and its kinematic evolution. Structural field data and mapping suggest a phase of extension, at some stage during the evolution of the ESFZ. This phase would explain dip-slip movements on structures that are currently associated with the active, dominantly strike slip and that do not fit with the current tectonic regime. Field observations suggest trenchward migration of the arc. Such an extension and trenchward migration of the volcanic arc could be related to slab rollback of the Cocos plate beneath the Chortis Block during the Miocene/Pliocene. We carried out 4-D analog model experiments to test whether an early phase of extension is required to form the present-day fault pattern in the ESFZ. Our experiments suggest that a two-phase tectonic evolution best explains the ESFZ: an early pure extensional phase linked to a segmented volcanic arc is necessary to form the main structures. This extensional phase is followed by a strike-slip dominated regime, which results in intersegment areas with local transtension and segments with almost pure strike-slip motion. The results of our experiments combined with field data along the Central American Volcanic Arc indicate that the slab rollback intensity beneath the Chortis Block is greater in Nicaragua and decreases westward to Guatemala.

  16. Biomimetic thermal barrier coating in jet engine to resist volcanic ash deposition

    Science.gov (United States)

    Song, Wenjia; Major, Zsuzsanna; Schulz, Uwe; Muth, Tobias; Lavallée, Yan; Hess, Kai-Uwe; Dingwell, Donald B.

    2017-04-01

    The threat of volcanic ash to aviation safety is attracting extensive attention when several commercial jet aircraft were damaged after flying through volcanic ash clouds from the May 1980 eruptions of Mount St. Helen in Washington, U.S. and especially after the air traffic disruption in 2010 Eyjafjallajökull eruption. A major hazard presented by volcanic ash to aircraft is linked to the wetting and spreading of molten ash droplets on engine component surfaces. Due to the fact ash has a lower melting point, around 1100 °C, than the gas temperature in the hot section (between 1400 to 2000 °C), this cause the ash to melt and potentially stick to the internal components (e.g., combustor and turbine blades), this cause the ash to melt and potentially stick to the internal components of the engine creating, substantial damage or even engine failure after ingestion. Here, inspiring form the natural surface of lotus leaf (exhibiting extreme water repellency, known as 'lotus effect'), we firstly create the multifunctional surface thermal barrier coatings (TBCs) by producing a hierarchical structure with femtosecond laser pulses. In detail, we investigate the effect of one of primary femtosecond laser irradiation process parameter (scanning speed) on the hydrophobicity of water droplets onto the two kinds of TBCs fabricated by electron-beam physical vapor deposition (EB-PVD) and air plasma spray (APS), respectively as well as their corresponding to morphology. It is found that, comparison with the original surface (without femtosecond laser ablation), all of the irradiated samples demonstrate more significant hydrophobic properties due to nanostructuring. On the basis of these preliminary room-temperature results, the wettability of volcanic ash droplets will be analysed at the high temperature to constrain the potential impact of volcanic ash on the jet engines.

  17. Comparing Volcanic Terrains on Venus and Earth: How Prevalent are Pyroclastic Deposits on Venus?

    Science.gov (United States)

    Carter, Lynn M.; Campbell, B. A.; Glaze, L. S.

    2012-01-01

    In the last several years, astronomers have discovered several exoplanets with masses less than 10 times that of the Earth [1]. Despite the likely abundance of Earth-sized planets, little is known about the pathways through which these planets evolve to become habitable or uninhabitable. Venus and Earth have similar planetary radii and solar orbital distance, and therefore offer a chance to study in detail the divergent evolution of two objects that now have radically different climates. Understanding the extent, duration, and types of volcanism present on Venus is an important step towards understanding how volatiles released from the interior of Venus have influenced the development of the atmosphere. Placing constraints on the extent of explosive volcanism on Venus can provide boundary conditions for timing, volumes, and altitudes for atmospheric injection of volatiles. In addition, atmospheric properties such as near-surface temperature and density affect how interior heat and volatiles are released. Radar image data for Venus can be used to determine the physical properties of volcanic deposits, and in particular, they can be used to search for evidence of pyroclastic deposits that may result from explosive outgassing of volatiles. For explosive volcanism to occur with the current high atmospheric pressure, magma volatile contents must be higher than is typical on Earth (at least 2-4% by weight) [2,3]. In, addition, pyroclastic flows should be more prevalent on Venus than convective plumes and material may not travel as far from the vent source as it would on Earth [3]. Areas of high radar backscatter with wispy margins that occur near concentric fractures on Sapho Patera [4] and several coronae in Eastern Eistla Regio [5] have been attributed to collapse of eruption columns and runout of rough materials.

  18. Oxygen isotope geochemistry of the lassen volcanic center, California: Resolving crustal and mantle contributions to continental Arc magmatism

    Science.gov (United States)

    Feeley, T.C.; Clynne, M.A.; Winer, G.S.; Grice, W.C.

    2008-01-01

    This study reports oxygen isotope ratios determined by laser fluorination of mineral separates (mainly plagioclase) from basaltic andesitic to rhyolitic composition volcanic rocks erupted from the Lassen Volcanic Center (LVC), northern California. Plagioclase separates from nearly all rocks have ??18O values (6.1-8.4%) higher than expected for production of the magmas by partial melting of little evolved basaltic lavas erupted in the arc front and back-arc regions of the southernmost Cascades during the late Cenozoic. Most LVC magmas must therefore contain high 18O crustal material. In this regard, the ??18O values of the volcanic rocks show strong spatial patterns, particularly for young rhyodacitic rocks that best represent unmodified partial melts of the continental crust. Rhyodacitic magmas erupted from vents located within 3.5 km of the inferred center of the LVC have consistently lower ??18 O values (average 6.3% ?? 0.1%) at given SiO2 contents relative to rocks erupted from distal vents (>7.0 km; average 7.1% ?? 0.1%). Further, magmas erupted from vents situated at transitional distances have intermediate values and span a larger range (average 6.8% ?? 0.2%). Basaltic andesitic to andesitic composition rocks show similar spatial variations, although as a group the ??18O values of these rocks are more variable and extend to higher values than the rhyodacitic rocks. These features are interpreted to reflect assimilation of heterogeneous lower continental crust by mafic magmas, followed by mixing or mingling with silicic magmas formed by partial melting of initially high 18O continental crust (??? 9.0%) increasingly hybridized by lower ??18O (???6.0%) mantle-derived basaltic magmas toward the center of the system. Mixing calculations using estimated endmember source ??18O values imply that LVC magmas contain on a molar oxygen basis approximately 42 to 4% isotopically heavy continental crust, with proportions declining in a broadly regular fashion toward the

  19. The volcanic-sedimentary sequence of the Lousal deposit, Iberian Pyrite Belt (Portugal)

    Science.gov (United States)

    Rosa, Carlos; Rosa, Diogo; Matos, Joao; Relvas, Jorge

    2010-05-01

    The Iberian Pyrite Belt (IPB) is a massive sulfide province that is located in the south of Portugal and Spain, and hosts more than 90 massive sulfide deposits that amount to more than 1850 million metric tonnes of sulfide ore (Tornos, 2006). The ore deposits size, vary from ~1Mt to >100Mt (e.g. Neves Corvo and Aljustrel in Portugal, and Rio Tinto and Tharsis in Spain). The ore deposits are hosted by a submarine sedimentary and volcanic, felsic dominated, succession that constitutes the Upper Devonian to Lower Carboniferous Volcanic and Sedimentary Complex (VSC). The VSC ranges in thickness from approximately 600 to 1300 m (Tornos 2006). The VSC overlies the Phyllite-Quartzite Group (PQ) (Upper Devonian, base unknown) and is overlain by the Baixo Alentejo Flysch Group (Lower to Upper Carboniferous). The Lousal massive sulfide deposit is located in the western part of the IPB and occurs mostly interbedded with black mudstone. The VSC sequence at Lousal mine consists of a mudstone and quartzite sequence (PQ Group) in the lower part of the succession, over which a thick sequence of rhyolitic lavas (>300 m) occurs. Above the rhyolitic lavas there is a thick sequence of black and grey mudstone that hosts the massive sulfide ore bodies, and a rhyolitic sill. The upper part of the VSC sequence consists of a thick mudstone interval that hosts two thick basaltic units, locally with pillows. The rhyolites have small coherent cores, locally with flow bands, that grade to surrounding massive clastic intervals, with large lateral extent. The clasts show jigsaw-fit arrangement in many places and have planar or curviplanar margins and locally are perlitic at the margin. The top contact of these units is in most locations not exposed, which makes difficult to interpret the mode of emplacement. However, the thick clastic intervals, above described, are in accordance with quenching of volcanic glass with abundant water and therefore indicate that quenching of the rhyolites was the

  20. Deposition and immersion mode nucleation of ice by three distinct samples of volcanic ash using Raman spectroscopy

    Science.gov (United States)

    Schill, G. P.; Genareau, K.; Tolbert, M. A.

    2015-01-01

    Ice nucleation on volcanic ash controls both ash aggregation and cloud glaciation, which affect atmospheric transport and global climate. Previously, it has been suggested that there is one characteristic ice nucleation efficiency for all volcanic ash, regardless of its composition, when accounting for surface area; however, this claim is derived from data from only two volcanic eruptions. In this work, we have studied the depositional and immersion freezing efficiency of three distinct samples of volcanic ash using Raman Microscopy coupled to an environmental cell. Ash from the Fuego (basaltic ash, Guatemala), Soufrière Hills (andesitic ash, Montserrat), and Taupo (Oruanui euption, rhyolitic ash, New Zealand) volcanoes were chosen to represent different geographical locations and silica content. All ash samples were quantitatively analyzed for both percent crystallinity and mineralogy using X-ray diffraction. In the present study, we find that all three samples of volcanic ash are excellent depositional ice nuclei, nucleating ice from 225-235 K at ice saturation ratios of 1.05 ± 0.01, comparable to the mineral dust proxy kaolinite. Since depositional ice nucleation will be more important at colder temperatures, fine volcanic ash may represent a global source of cold-cloud ice nuclei. For immersion freezing relevant to mixed-phase clouds, however, only the Oruanui ash exhibited heterogeneous ice nucleation activity. Similar to recent studies on mineral dust, we suggest that the mineralogy of volcanic ash may dictate its ice nucleation activity in the immersion mode.

  1. Deposition of TiN Films by Novel Filter Cathodic Arc Technique

    Institute of Scientific and Technical Information of China (English)

    NIU Er-Wu; FAN Song-Hua; LI Li; L(U) Guo-Hua; FENG Wen-Ran; ZHANG Gu-Ling; YANG Si-Ze

    2006-01-01

    A straight magnetic filtering arc source is used to deposit thin films of titanium nitride.The properties of thefilms depend strongly on the deposition process.TiN films can be deposited directly onto heated substrates in anitrogen atmosphere or onto unbiased substrates by condensing the Ti+ ion beam in about 300 eV N2+ nitrogen ionbombardment.In the latter case.the film stoichiometry is varied from an N:Ti ratio of 0.6-1.1 by controlling thearrival rates of Ti and nitrogen ions.Meanwhile,simple models are used to describe the evolution of compressivestress as function of the arrival ratio and the composition of the ion-assisted TiN films.

  2. Investigation of the thermal regime and geologic history of the Cascade volcanic arc: First phase of a program for scientific drilling in the Cascade Range

    Energy Technology Data Exchange (ETDEWEB)

    Priest, G.R.

    1987-01-01

    A phased, multihole drilling program with associated science is proposed as a means of furthering our understanding of the thermal regime and geologic history of the Cascade Range of Washington, Oregon, and northern California. The information obtained from drilling and ancillary geological and geophysical investigations will contribute to our knowledge in the following general areas: (1) the magnitude of the regional background heat flow of parts of the Quaternary volcanic belt dominated by the most abundant volcanic rock types, basalt and basaltic andesite; (2) the nature of the heat source responsible for the regional heat-flow anomaly; (3) the characteristics of the regional hydrothermal and cold-water circulation; the rates of volcanism for comparison with models for the rate and direction of plate convergence of the Cascades; (5) the history of deformation and volcanism in the volcanic arc that can be related to subduction; (6) the present-day stress regime of the volcanic arc and the relation of these stresses to plate interactions and possible large earthquakes; and the current geometry of the subducted oceanic plate below the Cascade Range and the relationship of the plate to the distribution of heat flow, Quaternary volcanism, and Quaternary deformation. Phase I research will be directed toward a detailed investigation of the Santiam Pass segment. In concert with the Santiam Pass research, a detailed study of the nearby Breitenbush Hot Springs area is also recommended as a component of Phase I. The object of the Breitenbush research is to study one of the hottest known Cascade hydrothermal systems, which coincidentally also has a good geological and geophysical data base. A coordinated program of drilling, sampling, subsurface measurements, and surface surveys will be associated with the drilling of several holes.

  3. A structural outline of the Yenkahe volcanic resurgent dome (Tanna Island, Vanuatu Arc, South Pacific)

    Science.gov (United States)

    Merle, O.; Brothelande, E.; Lénat, J.-F.; Bachèlery, P.; Garaébiti, E.

    2013-12-01

    A structural study has been conducted on the resurgent Yenkahe dome (5 km long by 3 km wide) located in the heart of the Siwi caldera of Tanna Island (Vanuatu arc, south Pacific). This spectacular resurgent dome hosts a small caldera and a very active strombolian cinder cone - the Yasur volcano - in the west and exhibits an intriguing graben in its central part. Detailed mapping and structural observations make it possible to unravel the volcano-tectonic history of the dome. It is shown that, following the early formation of a resurgent dome in the west, a complex collapse (caldera plus graben) occurred and this was associated with the recent uplift of the eastern part of the present dome. Eastward migration of the underlying magma related to regional tectonics is proposed to explain this evolution.

  4. Deposition of titanium nitride layers by electric arc - Reactive plasma spraying method

    Energy Technology Data Exchange (ETDEWEB)

    Serban, Viorel-Aurel [University ' Politehnica' of Timisoara, Faculty of Mechanical Engineering, No. 1 Mihai Viteazu Boulevard, 300222 Timisoara (Romania); Rosu, Radu Alexandru, E-mail: raduniz@gmail.com [University ' Politehnica' of Timisoara, Faculty of Mechanical Engineering, No. 1 Mihai Viteazu Boulevard, 300222 Timisoara (Romania); Bucur, Alexandra Ioana [National Institute for Research and Development in Electrochemistry and Condensed Matter Timisoara, Analysis and Characterization Department, No. 1 P Andronescu Street, Timisoara 300224 (Romania); Pascu, Doru Romulus [Romania National Research and Development Institute for Welding and Material Testing Timisoara, No. 30 Mihai Viteazu Boulevard, 300222 Timisoara (Romania)

    2013-01-15

    Highlights: Black-Right-Pointing-Pointer Titanium nitride layers deposited by electric arc - reactive plasma spraying method. Black-Right-Pointing-Pointer Deposition of titanium nitride layers on C45 steel at different spraying distances. Black-Right-Pointing-Pointer Characterization of the coatings hardness as function of the spraying distances. Black-Right-Pointing-Pointer Determination of the corrosion behavior of titanium nitride layers obtained. - Abstract: Titanium nitride (TiN) is a ceramic material which possesses high mechanical properties, being often used in order to cover cutting tools, thus increasing their lifetime, and also for covering components which are working in corrosive environments. The paper presents the experimental results on deposition of titanium nitride coatings by a new combined method (reactive plasma spraying and electric arc thermal spraying). In this way the advantages of each method in part are combined, obtaining improved quality coatings in the same time achieving high productivity. Commercially pure titanium wire and C45 steel as substrate were used for experiments. X-ray diffraction analysis shows that the deposited coatings are composed of titanium nitride (TiN, Ti{sub 2}N) and small amounts of Ti{sub 3}O. The microstructure of the deposited layers, investigated both by optical and scanning electron microscopy, shows that the coatings are dense, compact, without cracks and with low porosity. Vickers microhardness of the coatings presents maximum values of 912 HV0.1. The corrosion tests in 3%NaCl solution show that the deposited layers have a high corrosion resistance compared to unalloyed steel substrate.

  5. Dating of the late Quaternary volcanic events using Uranium-series technique on travertine deposit: A case study in Ihlara, Central Anatolia Volcanic Province

    Science.gov (United States)

    Karabacak, Volkan; Tonguç Uysal, İ.; Ünal-İmer, Ezgi

    2016-04-01

    Dating of late Quaternary volcanism is crucial to understanding of the recent mechanism of crustal deformation and future volcanic explosivity risk of the region. However, radiometric dating of volcanic products has been a major challenge because of high methodological error rate. In most cases, there are difficulties on discrimination of the volcanic lava flow relations in the field. Furthermore, there would be unrecorded and unpreserved volcanoclastic layers by depositional and erosional processes. We present a new method that allows precise dating of late Quaternary volcanic events (in the time range of 0-500,000 years before present) using the Uranium-series technique on travertine mass, which is thought to be controlled by the young volcanism. Since the high pressure CO2 in the spring waters are mobilized during crustal strain cycles and the carbonates are precipitated in the fissures act as conduit for hot springs, thus, travertine deposits provide important information about crustal deformation. In this study we studied Ihlara fissure ridge travertines in the Central Anatolia Volcanic Province. This region is surrounded by many eruption centers (i.e. Hasandaǧı, Acıgöl and Göllüdaǧı) known as the late Quaternary and their widespread volcanoclastic products. Recent studies have suggested at least 11 events at around Acıgöl Caldera for the last 180 ka and 2 events at Hasandaǧı Stratovolcano for the last 30 ka. Active travertine masses around Ihlara deposited from hotwaters, which rise up through deep-penetrated fissures in volcanoclastic products of surrounding volcanoes. Analyses of the joint systems indicate that these vein structures are controlled by the crustal deformation due to young volcanism in the vicinity. Thus, the geological history of Ihlara travertine mass is regarded as a record of surrounding young volcanism. We dated 9 samples from 5 ridge-type travertine masses around Ihlara region. The age distribution indicates that the crustal

  6. Middle Jurassic Topawa group, Baboquivari Mountains, south-central Arizona: Volcanic and sedimentary record of deep basins within the Jurassic magmatic arc

    Science.gov (United States)

    Haxel, G.B.; Wright, J.E.; Riggs, N.R.; Tosdal, R.M.; May, D.J.

    2005-01-01

    Among supracrustal sequences of the Jurassic magmatic arc of the southwestern Cordillera, the Middle Jurassic Topawa Group, Baboquivari Mountains, south-central Arizona, is remarkable for its lithologic diversity and substantial stratigraphic thickness, ???8 km. The Topawa Group comprises four units (in order of decreasing age): (1) Ali Molina Formation-largely pyroclastic rhyolite with interlayered eolian and fluvial arenite, and overlying conglomerate and sandstone; (2) Pitoikam Formation-conglomerate, sedimentary breccia, and sandstone overlain by interbedded silt- stone and sandstone; (3) Mulberry Wash Formation-rhyolite lava flows, flow breccias, and mass-flow breccias, with intercalated intraformational conglomerate, sedimentary breccia, and sandstone, plus sparse within-plate alkali basalt and comendite in the upper part; and (4) Tinaja Spring Porphyry-intrusive rhyolite. The Mulberry Wash alkali basalt and comendite are genetically unrelated to the dominant calcalkaline rhyolite. U-Pb isotopic analyses of zircon from volcanic and intrusive rocks indicate the Topawa Group, despite its considerable thickness, represents only several million years of Middle Jurassic time, between approximately 170 and 165 Ma. Sedimentary rocks of the Topawa Group record mixing of detritus from a minimum of three sources: a dominant local source of porphyritic silicic volcanic and subvolcanic rocks, identical or similar to those of the Topawa Group itself; Meso- proterozoic or Cambrian conglomerates in central or southeast Arizona, which contributed well-rounded, highly durable, polycyclic quartzite pebbles; and eolian sand fields, related to Middle Jurassic ergs that lay to the north of the magmatic arc and are now preserved on the Colorado Plateau. As the Topawa Group evidently represents only a relatively short interval of time, it does not record long-term evolution of the Jurassic magmatic arc, but rather represents a Middle Jurassic "stratigraphic snapshot" of the arc

  7. Thick CrN/NbN multilayer coating deposited by cathodic arc technique

    Energy Technology Data Exchange (ETDEWEB)

    Araujo, Juliano Avelar; Tschiptschin, Andre Paulo; Souza, Roberto Martins, E-mail: antschip@usp.br [Universidade de Sao Paulo (USP), SP (Brazil); Lima, Nelson Batista de [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)

    2017-01-15

    The production of tribological nanoscale multilayer CrN/NbN coatings up to 6 μm thick by Sputtering/HIPIMS has been reported in literature. However, high demanding applications, such as internal combustion engine parts, need thicker coatings (>30 μm). The production of such parts by sputtering would be economically restrictive due to low deposition rates. In this work, nanoscale multilayer CrN/NbN coatings were produced in a high-deposition rate, industrial-size, Cathodic Arc Physical Vapor Deposition (ARC-PVD) chamber, containing three cathodes in alternate positions (Cr/ Nb/Cr). Four 30 μm thick NbN/CrN multilayer coatings with different periodicities (20, 10, 7.5 and 4 nm) were produced. The coatings were characterized by X-Ray Diffraction (XRD) and Transmission Electron Microscopy (TEM). The multilayer coating system was composed of alternate cubic rock salt CrN and NbN layers, coherently strained due to lattice mismatch. The film grew with columnar morphology through the entire stratified structure. The periodicities adopted were maintained throughout the entire coating. The 20 nm periodicity coating showed separate NbN and CrN peaks in the XRD patterns, while for the lower periodicity (≤10nm) coatings, just one intermediate lattice (d-spacing) was detected. An almost linear increase of hardness with decreasing bilayer period indicates that interfacial effects can dominate the hardening mechanisms. (author)

  8. Mechanical properties and scratch resistance of filtered-arc-deposited titanium oxide thin films on glass

    Energy Technology Data Exchange (ETDEWEB)

    Borrero-Lopez, Oscar, E-mail: oborlop@unex.es [Departamento de Ingenieria Mecanica, Energetica y de los Materiales, Universidad de Extremadura, 06071, Badajoz (Spain); School of Materials Science and Engineering, University of New South Wales NSW 2052, Sydney (Australia); Hoffman, Mark [School of Materials Science and Engineering, University of New South Wales NSW 2052, Sydney (Australia); Bendavid, Avi; Martin, Phil J. [CSIRO Materials Science and Engineering, P.O. Box 218, Lindfield NSW 2070 (Australia)

    2011-09-01

    The mechanical properties and the scratch resistance of titanium oxide (TiO{sub 2}) thin films on a glass substrate have been investigated. Three films, with crystalline (rutile and anatase) and amorphous structures, were deposited by the filtered cathodic vacuum arc deposition technique on glass, and characterized by means of nanoindentation and scratch tests. The different damage modes (arc-like, longitudinal and channel cracks in the crystalline films; Hertzian cracks in the amorphous film) were assessed by means of optical and focused ion beam microscopy. In all cases, the deposition of the TiO{sub 2} film improved the contact-mechanical properties of uncoated glass. Crystalline films were found to possess a better combination of mechanical properties (i.e. elastic modulus up to 221 GPa, hardness up to 21 GPa, and fracture strength up to 3.6 GPa) than the amorphous film. However, under cyclic sliding contact above the critical fracture load, the amorphous film was found to withstand a higher number of cycles. The results are expected to provide useful insight for the design of optical coatings with improved contact-damage resistance.

  9. Flank collapse at Mount Wrangell, Alaska, recorded by volcanic mass-flow deposits in the Copper River lowland

    Science.gov (United States)

    Waythomas, C.F.; Wallace, K.L.

    2002-01-01

    An areally extensive volcanic mass-flow deposit of Pleistocene age, known as the Chetaslina volcanic mass-flow deposit, is a prominent and visually striking deposit in the southeastern Copper River lowland of south-central Alaska. The mass-flow deposit consists of a diverse mixture of colorful, variably altered volcanic rocks, lahar deposits, glaciolacustrine diamicton, and till that record a major flank collapse on the southwest flank of Mount Wrangell. The deposit is well exposed near its presumed source, and thick, continuous, stratigraphic exposures have permitted us to study its sedimentary characteristics as a means of better understanding the origin, significance, and evolution of the deposit. Deposits of the Chetaslina volcanic mass flow in the Chetaslina River drainage are primary debris-avalanche deposits and consist of two principal facies types, a near-source block facies and a distal mixed facies. The block facies is composed entirely of block-supported, shattered and fractured blocks with individual blocks up to 40 m in diameter. The mixed facies consists of block-sized particles in a matrix of poorly sorted rock rubble, sand, and silt generated by the comminution of larger blocks. Deposits of the Chetaslina volcanic mass flow exposed along the Copper, Tonsina, and Chitina rivers are debris-flow deposits that evolved from the debris-avalanche component of the flow and from erosion and entrainment of local glacial and glaciolacustrine diamicton in the Copper River lowland. The debris-flow deposits were probably generated through mixing of the distal debris avalanche with the ancestral Copper River, or through breaching of a debris-avalanche dam across the ancestral river. The distribution of facies types and major-element chemistry of clasts in the deposit indicate that its source was an ancestral volcanic edifice, informally known as the Chetaslina vent, on the southwest side of Mount Wrangell. A major sector collapse of the Chetaslina vent initiated

  10. Cell adhesion property of cathodic arc plasma deposited CrN thin film

    Science.gov (United States)

    Kim, Sun Kyu; Pham, Vuong Hung

    2009-09-01

    The interaction between human osteoblast cells and CrN thin film was studied in vitro. CrN thin films were produced by cathodic arc plasma deposition. The surface was characterized by atomic force microscopy. Cell adhesion on the coatings was assessed by MTT assay and visualization. Cell cytoskeleton organization was studied by analyzing microtubule and actin cytoskeleton organization. Focal contact adhesion was monitored by analyzing vinculin density. The study found that the CrN thin film is a potential candidate as a protective coating on implantable devices that require minimal cellular adhesion.

  11. Depositional and welding processes in low aspect ratio ignimbrites: examples from the Sulcis Volcanic District(Sardinia, Italy)

    OpenAIRE

    Mulas, Maurizio

    2013-01-01

    The rheomorphic, high-grade, welded ignimbrites are a special type of pyroclastic density current (PDC) deposits usually associated with high intensity volcanic explosive activity (VEI >4). They are characterized by a high variability of physical features and sedimentological structures that may testify different emplacement mechanisms from a PDC and a different response to topography during and after the end of the depositional processes. When the temperatures of the deposits are higher than...

  12. A 36,000-Year-Old Volcanic Eruption Depicted in the Chauvet-Pont d'Arc Cave (Ardèche, France)?

    Science.gov (United States)

    Nomade, Sébastien; Genty, Dominique; Sasco, Romain; Scao, Vincent; Féruglio, Valérie; Baffier, Dominique; Guillou, Hervé; Bourdier, Camille; Valladas, Hélène; Reigner, Edouard; Debard, Evelyne; Pastre, Jean-François; Geneste, Jean-Michel

    2016-01-01

    Among the paintings and engravings found in the Chauvet-Pont d'Arc cave (Ardèche, France), several peculiar spray-shape signs have been previously described in the Megaloceros Gallery. Here we document the occurrence of strombolian volcanic activity located 35 km northwest of the cave, and visible from the hills above the cave entrance. The volcanic eruptions were dated, using 40Ar/39Ar, between 29 ± 10 ka and 35 ± 8 ka (2σ), which overlaps with the 14C AMS and thermoluminescence ages of the first Aurignacian occupations of the cave in the Megaloceros Gallery. Our work provides the first evidence of an intense volcanic activity between 40 and 30 ka in the Bas-Vivarais region, and it is very likely that Humans living in the Ardèche river area witnessed one or several eruptions. We propose that the spray-shape signs found in the Chauvet-Pont d'Arc cave could be the oldest known depiction of a volcanic eruption, predating by more than 34 ka the description by Pliny the Younger of the Vesuvius eruption (AD 79) and by 28 ka the Çatalhöyük mural discovered in central Turkey.

  13. Age, geochemical and isotopic variations in volcanic rocks from the Coastal Range of Taiwan: Implications for magma generation in the Northern Luzon Arc

    Science.gov (United States)

    Lai, Yu-Ming; Song, Sheng-Rong; Lo, Ching-Hua; Lin, Te-Hsien; Chu, Mei-Fei; Chung, Sun-Lin

    2017-02-01

    This paper reports the first systematic analysis of age and geochemical variations in volcanic rocks from the Coastal Range of Taiwan, the Northern Luzon Arc. The rocks, recovered from four main volcanoes, vary from low-K tholeiitic to medium-K calc-alkaline basalts to dacites. The rocks are typical of arc magmatic products, exhibiting enrichment in the large ion lithophile elements and depletion in the high field strength elements. Our new 40Ar/39Ar age data constrain the youngest eruption time in each of the four volcanoes, i.e., from north to south, at 7.2 Ma (Yuemei), 4.2 Ma (Chimei), 6.2 Ma (Chengkuang'ao) and 8.5 Ma (Tuluanshan), respectively. These data indicate that volcanism in the Northern Luzon Arc did not cease progressively from north to south, as previously alleged. The high and broadly uniform Nd isotope ratios [εNd = + 10.1 to + 8.8] and trace element characteristics of the rocks suggest a principal magma source from the depleted mantle wedge. Their overall geochemical variations are ascribed to magma chamber processes. The effects of magmatic differentiation and crustal contamination differ among each volcano, most likely owing to the discrepancy of residence time in individual magma chambers. Consequently, we propose a binary mixing model for the magma generation that involves arc magmas sourced from the depleted mantle wedge and up to 5% crustal contamination with a continental fragment split off from the Eurasian margin.

  14. Back arc extension, tectonic inheritance, and volcanism in the Ligurian Sea, Western Mediterranean

    Science.gov (United States)

    Rollet, Nadège; Déverchère, Jacques; Beslier, Marie-Odile; Guennoc, Pol; Réhault, Jean-Pierre; Sosson, Marc; Truffert, Catherine

    2002-06-01

    The Ligurian basin, western Mediterranean Sea, has opened from late Oligocene to early Miocene times, behind the Apulian subduction zone and partly within the western Alpine belt. We analyze the deep structures of the basin and its conjugate margins in order to describe the tectonic styles of opening and to investigate the possible contributions of forces responsible for the basin formation, especially the pulling force induced by the retreating subduction hinge and the gravitational body force from the Alpine wedge. To undertake this analysis, we combine new multichannel seismic reflection data (Malis cruise, 1995) with other geophysical data (previous multichannel and monochannel seismic sections, magnetic anomalies) and constrain them by geological sampling from two recent cruises (dredges from Marco cruise, 1995, and submersible dives from Cylice cruise, 1997). From an analysis of basement morphology and seismic facies, we refine the extent of the different domains in the Ligurian Sea: (1) the continental thinned margins, with strong changes in width and structure along strike and on both sides of the ocean; (2) the transitional domain to the basin; and (3) a narrow, atypical oceanic domain. Margin structures are characterized by few tilted blocks along the narrow margins, where inherited structures seem to control synrift sedimentation and margin segmentation. On the NW Corsican margin, extension is distributed over more than 120 km, including offshore Alpine Corsica, and several oceanward faults sole on a relatively flat reflector. We interpret them as previous Alpine thrusts reactivated during rifting as normal faults soling on a normal ductile shear zone. Using correlations between magnetic data, seismic facies, and sampling, we propose a new map of the distribution of magmatism. The oceanic domain depicts narrow, isolated magnetic anomalies and is interpreted as tholeitic volcanics settled within an unroofed upper mantle, whereas calcalkaline volcanism

  15. Microstructural Evolution and Mechanical Properties of Inconel 625 Alloy during Pulsed Plasma Arc Deposition Process

    Institute of Scientific and Technical Information of China (English)

    Fujia Xu; Yaohui Lv; Yuxin Liu; Fengyuan Shu; Peng He; Binshi Xu

    2013-01-01

    Pulsed plasma arc deposition (PPAD),which combines pulsed plasma cladding with rapid prototyping,is a promising technology for manufacturing near net shape components due to its superiority in cost and convenience of processing.In the present research,PPAD was successfully used to fabricate the Ni-based superalloy Inconel 625 components.The microstructures and mechanical properties of deposits were investigated by scanning electron microscopy (SEM),optical microscopy (OM),transmission electron microscopy (TEM) with energy dispersive spectrometer (EDS),microhardness and tensile testers.It was found that the as-deposited structure exhibited homogenous columnar dendrite structure,which grew epitaxially along the deposition direction.Moreover,some intermetallic phases such as Laves phase,minor MC (NbC,TiC) carbides and needle-like δ-Ni3Nb were observed in γ-Ni matrix.Precipitation mechanism and distribution characteristics of these intermetallic phases in the as-deposited 625 alloy sample were analyzed.In order to evaluate the mechanical properties of the deposits,microhardness was measured at various location (including transverse plane and longitudinal plane).The results revealed hardness was in the range of 260-285 HVo.2.In particular,microhardness at the interface region between two adjacent deposited layers was slightly higher than that at other regions due to highly refined structure and the disperse distribution of Laves particles.Finally,the influence of precipitation phases and fabrication strategies on the tensile properties of the as-deposited samples was investigated.The failure modes of the tensile specimens were analyzed with fractography.

  16. NiCrSiB Coatings Deposited by Plasma Transferred Arc on Different Steel Substrates

    Science.gov (United States)

    Reinaldo, P. R.; D'Oliveira, A. S. C. M.

    2013-02-01

    Colmonoy 6 (NiCrSiB) is a Ni-based alloy recognized for its superior mechanical properties, attributed to the presence of a dispersion of hard carbides and borides, which is strongly dependent on processing technique. This work gathered microstructure data from the literature and analyzed Colmonoy 6 coatings deposited by plasma transferred arc hardfacing. The aim of the study was to determine the influence of PTA deposition parameters and substrate chemical composition on NiCrSiB coating characteristics. Coatings were characterized in terms of their hardness, dilution, and microstructure, as well as mass loss during abrasive sliding wear tests. The results showed that coating performance is strongly dependent on the chemical composition of the substrate. Carbon steel substrate yielded coatings with greater wear resistance. Processing parameters also alter the performance of coatings, and the lower current and lower travel speed result in reduced mass loss.

  17. CrAlN coatings deposited by cathodic arc evaporation at different substrate bias

    Energy Technology Data Exchange (ETDEWEB)

    Romero, J. [Departament de Fisica Aplicada i Optica, Universitat de Barcelona, Avda. Diagonal 647, E-08028 Barcelona, Catalunya (Spain); Gomez, M.A. [Departament de Fisica Aplicada i Optica, Universitat de Barcelona, Avda. Diagonal 647, E-08028 Barcelona, Catalunya (Spain); Grupo de Corrosion y Proteccion, Universidad de Antioquia, A.A. 1226 Medellin (Colombia); Esteve, J. [Departament de Fisica Aplicada i Optica, Universitat de Barcelona, Avda. Diagonal 647, E-08028 Barcelona, Catalunya (Spain); Montala, F. [Tratamientos Termicos Carreras, TTC S.A., C/Doctor Almera 85, E-08205 Sabadell, Catalunya (Spain); Carreras, L. [Tratamientos Termicos Carreras, TTC S.A., C/Doctor Almera 85, E-08205 Sabadell, Catalunya (Spain); Grifol, M. [Tratamientos Termicos Carreras, TTC S.A., C/Doctor Almera 85, E-08205 Sabadell, Catalunya (Spain); Lousa, A. [Departament de Fisica Aplicada i Optica, Universitat de Barcelona, Avda. Diagonal 647, E-08028 Barcelona, Catalunya (Spain)]. E-mail: alousa@ub.edu

    2006-09-25

    CrAlN is a good candidate as an alternative to conventional CrN coatings especially for high temperature oxidation-resistance applications. Different CrAlN coatings were deposited on hardened steel substrates by cathodic arc evaporation (CAE) from chromium-aluminum targets in a reactive nitrogen atmosphere at negative substrate bias between - 50 and - 400 V. The negative substrate bias has important effects on the deposition growth rate and crystalline structure. All our coatings presented hardness higher than conventional CrN coatings. The friction coefficient against alumina and tungsten carbide balls was around 0.6. The sliding wear coefficient of the CrAlN coatings was very low while an important wear was observed in the balls before a measurable wear were produced in the coatings. This effect was more pronounced as the negative substrate bias was increased.

  18. Late Quaternary incision and deposition in an active volcanic setting: The Volturno valley fill, southern Italy

    Science.gov (United States)

    Amorosi, Alessandro; Pacifico, Annamaria; Rossi, Veronica; Ruberti, Daniela

    2012-12-01

    Extensive illustration of depositional facies, ostracod and foraminiferal assemblages, and Late Quaternary stratigraphic architecture is offered for the first time from beneath the modern coastal plain of Volturno River, the longest river in southern Italy. Proximity to an active volcanic district, including quiescent Vesuvius Volcano, provides an easily identifiable stratigraphic marker (Campania Grey Tuff or CGT), up to 55 m thick, emplaced 39 ky cal BP by a large-volume explosive pyroclastic eruption. Identification of top CGT to a maximum depth of 30 m allows tracing out the shape of a 15-20 km wide Late Quaternary palaeovalley incised by Volturno River into the thick ignimbritic unit immediately after its deposition. A terraced palaeotopography of the valley flanks is reconstructed on the basis of core data. Above the basal fluvial deposits, the early Holocene transgressive facies consist of a suite of estuarine (freshwater to brackish) deposits. These are separated from overlying transgressive barrier sands by a distinctive wave ravinement surface. Upwards, a distinctive shallowing-upward succession of middle-late Holocene age is interpreted to reflect initiation and subsequent progradation of a wave-dominated delta system, with flanking strandplains, in response to reduced rate of sea-level rise. The turnaround from transgressive to highstand conditions is identified on the basis of subtle changes in the meiofauna. These enable tracking of the maximum flooding surface into its updip (lagoonal/estuarine) counterpart, thus highlighting the role of refined palaeontological criteria as a powerful tool for high-resolution sequence-stratigraphic studies.

  19. Effects of deposition parameters on microstructure and thermal conductivity of diamond films deposited by DC arc plasma jet chemical vapor deposition

    Institute of Scientific and Technical Information of China (English)

    QU Quan-yan; QIU Wan-qi; ZENG De-chang; LIU Zhong-wu; DAI Ming-jiang; ZHOU Ke-song

    2009-01-01

    The uniform diamond films with 60 mm in diameter were deposited by improved DC arc plasma jet chemical vapor deposition technique. The structure of the film was characterized by scanning electronic microcopy(SEM) and laser Raman spectrometry. The thermal conductivity was measured by a photo thermal deflection technique. The effects of main deposition parameters on microstructure and thermal conductivity of the films were investigated. The results show that high thermal conductivity, 10.0 W/(K-cm), can be obtained at a CH4 concentration of 1.5% (volume fraction) and the substrate temperatures of 880-920 ℃ due to the high density and high purity of the film. A low pressure difference between nozzle and vacuum chamber is also beneficial to the high thermal conductivity.

  20. Transparent and conductive indium doped cadmium oxide thin films prepared by pulsed filtered cathodic arc deposition

    Energy Technology Data Exchange (ETDEWEB)

    Zhu Yuankun, E-mail: yuan.kun.zhu@gmail.com [Center for Composite Materials and Structures, Harbin Institute of Technology, Harbin 150080 (China); Plasma Applications Group, Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States); Mendelsberg, Rueben J. [Plasma Applications Group, Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States); Molecular Foundry, Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States); Zhu Jiaqi, E-mail: zhujq@hit.edu.cn [Center for Composite Materials and Structures, Harbin Institute of Technology, Harbin 150080 (China); Han Jiecai [Center for Composite Materials and Structures, Harbin Institute of Technology, Harbin 150080 (China); Anders, Andre [Plasma Applications Group, Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States)

    2013-01-15

    Highlights: Black-Right-Pointing-Pointer High quality CdO:In films were prepared on glass by pulsed filtered cathodic arc. Black-Right-Pointing-Pointer 230 nm thick films show low resistivity of 7.23 Multiplication-Sign 10{sup -5} {Omega} cm and mobility of 142 cm{sup 2}/Vs. Black-Right-Pointing-Pointer In-doping significantly improves the conductivity and extends the transparent range. Black-Right-Pointing-Pointer Film crystalline quality is maintained with increasing In concentration. Black-Right-Pointing-Pointer The pulsed arc-grown CdO:In show excellent reproducibility of film properties. - Abstract: Indium doped cadmium oxide (CdO:In) films with different In concentrations were prepared on low-cost glass substrates by pulsed filtered cathodic arc deposition (PFCAD). It is shown that polycrystalline CdO:In films with smooth surface and dense structure are obtained. In-doping introduces extra electrons leading to remarkable improvements of electron mobility and conductivity, as well as improvement in the optical transmittance due to the Burstein-Moss effect. CdO:In films on glass substrates with thickness near 230 nm show low resistivity of 7.23 Multiplication-Sign 10{sup -5} {Omega} cm, high electron mobility of 142 cm{sup 2}/Vs, and mean transmittance over 80% from 500 to 1250 nm (including the glass substrate). These high quality pulsed arc-grown CdO:In films are potentially suitable for high efficiency multi-junction solar cells that harvest a broad range of the solar spectrum.

  1. Chlorine Stable Isotopes to reveal contribution of magmatic chlorine in subduction zones: the case of the Kamchatka-Kuril and the Lesser Antilles Volcanic Arcs

    Science.gov (United States)

    Agrinier, Pierre; Shilobreeva, Svetlana; Bardoux, Gerard; Michel, Agnes; Maximov, Alexandr; Kalatcheva, Elena; Ryabinin, Gennady; Bonifacie, Magali

    2015-04-01

    By using the stable isotopes of chlorine (δ 37Cl), we have shown that magmatic chlorine (δ 37Cl ≤ -0.6 ‰ [1]) is different from surface chlorine (δ 37Cl ≈ 0 ‰ [1]) in hydrothermal system of Soufrière and Montagne Pelé from the young arc volcanic system of Lesser Antilles. First measurements on condensed chlorides from volcanic gases (e.g. [2], [3]) did not permitted to get sensible δ 37Cl values on degassed chlorine likely because chlorine isotopes are fractionated during the HClgas - chloride equilibrium in the fumaroles or during sampling artifacts. Therefore we have developed an alternative strategy based on the analysis of chloride in thermal springs, streams, sout{f}lowing on the flanks of the volcanoes. Due to the highly hydrophilic behavior of Cl, we hypothesize that thermal springs incorporate chlorine without fractionation of chlorine isotopes and might reflect the chlorine isotopic composition degassed by magmas [1]. Indeed Thermal spring with low δ 37Cl chlorides (≤ -0.6 perthousand{}) are linked with magmatic volatiles characters (3He ratio at 5 Ra at and δ 13C CO2 quad ≈ -3 perthousand{}). To go further in the potentiality of using the Chlorine isotopes to reveal contribution of magmatic chlorine in volcanic systems, we have started the survey of thermal springs and wells waters in the Kamchatka-Kuril volcanic mature Arc (on sites Mutnovsky, Paratunka, Nalychevsky, Khodutkinsky, Paramushir Island, identified by Taran, 2009 [4] for concentrations of chloride). Preliminary results show δ 37Cl values ranging from 0.5 to -0.2 ‰ and generally higher chloride concentrations. The δ 37Cl values are higher than the value recorded for the young arc volcanic system of lesser Antilles. At present moment very few negative δ 37Cl have been measured in the Kamchatka-Kuril volcanic mature Arc. [1] Li et al., 2015 EPSL in press. [2] Sharp et al. 2010 GCA. [3] Rizzo et al., 2013, EPSL, 371, 134. [4] Taran, 2009, GCA, 73, 1067

  2. Structure of MoCN films deposited by cathodic arc evaporation

    Energy Technology Data Exchange (ETDEWEB)

    Gilewicz, A., E-mail: adam.gilewicz@tu.koszalin.pl [Koszalin University of Technology, Faculty of Technology and Education, Sniadeckich 2, 75-453 Koszalin (Poland); Jedrzejewski, R.; Kochmanska, A.E. [West Pomeranian University of Technology Szczecin, Faculty of Mechanical Engineering and Mechatronics, 19 Piastów Ave., 70-313 Szczecin (Poland); Warcholinski, B. [Koszalin University of Technology, Faculty of Technology and Education, Sniadeckich 2, 75-453 Koszalin (Poland)

    2015-02-27

    Molybdenum carbonitride (MoCN) coatings were deposited onto HS6-5-2 steel substrate using pure Mo targets in mixed acetylene and nitrogen atmosphere by cathodic arc evaporation. The structural properties of MoCN coatings with different carbon contents (as an effect of the C{sub 2}H{sub 2} flow rate) were investigated systematically. Phase and chemical composition evolution of the coatings were characterized both by the glancing angle of X-ray diffraction (XRD) and wavelength dispersive spectrometry, respectively. These analyses have been supplemented by estimates of grain sizes and stress in the coatings. The XRD results show that the increase in acetylene flow rate causes the formation of molybdenum carbide (MoC) hexagonal phase in the coatings, a reduction of grain size and an increase in internal stress. - Highlights: • MoN and MoCN coatings were deposited by cathodic arc evaporation in nitrogen atmosphere. • MoCN coatings were formed using different acetylene flow rates. • Phase composition evolution was observed. • Crystallite size and stress were calculated.

  3. Fluid-melt partitioning of sulfur in differentiated arc magmas and the sulfur yield of explosive volcanic eruptions

    Science.gov (United States)

    Masotta, M.; Keppler, H.; Chaudhari, A.

    2016-03-01

    The fluid-melt partitioning of sulfur (DSfluid/melt) in differentiated arc magmas has been experimentally investigated under oxidizing conditions (Re-ReO2 buffer) from 800 to 950 °C at 200 MPa. The starting glasses ranged in composition from trachyte to rhyolite and were synthesized targeting the composition of the residual melt formed after 10-60% crystallization of originally trachy-andesitic, dacitic and rhyodacitic magmas (Masotta and Keppler, 2015). Fluid compositions were determined both by mass balance and by Raman spectroscopy of fluid inclusions. DSfluid/melt increases exponentially with increasing melt differentiation, ranging from 2 to 15 in the trachytic melt, from 20 to 100 in the dacitic and rhyodacitic melts and from 100 to 120 in the rhyolitic melt. The variation of the DSfluid/melt is entirely controlled by the compositional variation of the silicate melt, with temperature having at most a minor effect within the range investigated. Experiments from this study were used together with data from the literature to calibrate the following model that allows predicting DSfluid/melt for oxidized arc magmas: where nbo/t is the non-bridging oxygen atoms per tetrahedron, ASI is the alumina saturation index, Al# and Ca# are two empirical compositional parameters calculated in molar units (Al # = XAl2O3/XSiO2 +XTiO2 +XAl2O3 and Ca # = XCaO/XNa2O +XK2O). The interplay between fluid-melt partitioning and anhydrite solubility determines the sulfur distribution among anhydrite, melt and fluid. At increasing melt polymerization, the exponential increase of the partition coefficient and the decrease of anhydrite solubility favor the accumulation of sulfur either in the fluid phase or as anhydrite. On the other hand, the higher anhydrite solubility and lower partition coefficient for less polymerized melts favor the retention of sulfur in the melt. At equilibrium conditions, these effects yield a maximum of the sulfur fraction in the fluid phase for slightly

  4. Geochronology and geochemistry of the Early Jurassic Yeba Formation volcanic rocks in southern Tibet: Initiation of back-arc rifting and crustal accretion in the southern Lhasa Terrane

    Science.gov (United States)

    Wei, Youqing; Zhao, Zhidan; Niu, Yaoling; Zhu, Di-Cheng; Liu, Dong; Wang, Qing; Hou, Zengqian; Mo, Xuanxue; Wei, Jiuchuan

    2017-05-01

    Understanding the geological history of the Lhasa Terrane prior to the India-Asia collision ( 55 ± 10 Ma) is essential for improved models of syn-collisional and post-collisional processes in the southern Lhasa Terrane. The Miocene ( 18-10 Ma) adakitic magmatism with economically significant porphyry-type mineralization has been interpreted as resulting from partial melting of the Jurassic juvenile crust, but how this juvenile crust was accreted remains poorly known. For this reason, we carried out a detailed study on the volcanic rocks of the Yeba Formation (YF) with the results offering insights into the ways in which the juvenile crust may be accreted in the southern Lhasa Terrane in the Jurassic. The YF volcanic rocks are compositionally bimodal, comprising basalt/basaltic andesite and dacite/rhyolite dated at 183-174 Ma. All these rocks have an arc-like signature with enriched large ion lithophile elements (LILEs; e.g., Rb, Ba and U) and light rare earth elements (LREEs) and depleted high field strength elements (HFSEs; e.g., Nb, Ta, Ti). They also have depleted whole-rock Sr-Nd and zircon Hf isotopic compositions, pointing to significant mantle isotopic contributions. Modeling results of trace elements and isotopes are most consistent with the basalts being derived from a mantle source metasomatized by varying enrichment of subduction components. The silicic volcanic rocks show the characteristics of transitional I-S type granites, and are best interpreted as resulting from re-melting of a mixed source of juvenile amphibole-rich lower crust with reworked crustal materials resembling metagraywackes. Importantly, our results indicate northward Neo-Tethyan seafloor subduction beneath the Lhasa Terrane with the YF volcanism being caused by the initiation of back-arc rifting. The back-arc setting is a likely site for juvenile crustal accretion in the southern Lhasa Terrane.

  5. Deposition of titanium nitride layers by electric arc - Reactive plasma spraying method

    Science.gov (United States)

    Şerban, Viorel-Aurel; Roşu, Radu Alexandru; Bucur, Alexandra Ioana; Pascu, Doru Romulus

    2013-01-01

    Titanium nitride (TiN) is a ceramic material which possesses high mechanical properties, being often used in order to cover cutting tools, thus increasing their lifetime, and also for covering components which are working in corrosive environments. The paper presents the experimental results on deposition of titanium nitride coatings by a new combined method (reactive plasma spraying and electric arc thermal spraying). In this way the advantages of each method in part are combined, obtaining improved quality coatings in the same time achieving high productivity. Commercially pure titanium wire and C45 steel as substrate were used for experiments. X-ray diffraction analysis shows that the deposited coatings are composed of titanium nitride (TiN, Ti2N) and small amounts of Ti3O. The microstructure of the deposited layers, investigated both by optical and scanning electron microscopy, shows that the coatings are dense, compact, without cracks and with low porosity. Vickers microhardness of the coatings presents maximum values of 912 HV0.1. The corrosion tests in 3%NaCl solution show that the deposited layers have a high corrosion resistance compared to unalloyed steel substrate.

  6. Energetic deposition of carbon in a cathodic vacuum arc with a biased mesh

    Science.gov (United States)

    Moafi, A.; Lau, D. W. M.; Sadek, A. Z.; Partridge, J. G.; McKenzie, D. R.; McCulloch, D. G.

    2011-04-01

    Carbon films were deposited in a filtered cathodic vacuum arc with a bias potential applied to a conducting mesh mounted in the plasma stream between the source and the substrate. We determined the stress and microstructural properties of the resulting carbon films and compared the results with those obtained using direct substrate bias with no mesh. Since the relationship between deposition energy and the stress, sp2 fraction and density of carbon are well known, measuring these film properties enabled us to investigate the effect of the mesh on the energy and composition of the depositing flux. When a mesh was used, the film stress showed a monotonic decrease for negative mesh bias voltages greater than 400V, even though the floating potential of the substrate did not vary. We explain this result by the neutralization of some ions when they are near to or passing through the negatively biased mesh. The microstructure of the films showed a change from amorphous to glassy carbonlike with increasing bias. Potential applications for this method include the deposition of carbon films with controlled stress on low conductivity substrates to form rectifying or ohmic contacts.

  7. Microstructure Changes of Ti-Al-C Films Deposited by Filtered Cathodic Vacuum Arc

    Directory of Open Access Journals (Sweden)

    Xianjuan Pang

    2014-01-01

    Full Text Available Nanocomposite Ti-Al-C films were deposited by filtered cathodic vacuum arc (FCVA at different CH4 flows. The deposited films were characterized in terms of elemental and phase compositions, chemical bonds, and texture as a function of CH4 flow rate by XRD, XPS, HRTEM, Raman spectroscopy, and IR spectroscopy. The results show that the TiC grain size decreases from 4.2 to 2.9 nm as the CH4 flow rate increases from 30 to 80 sccm. The analysis of XPS, HRTEM, and Raman spectroscopy shows that the microstructure of deposited films turns from a TiC dominant TiC-C film to a carbon network dominant TiAl-doped a-C film structure as the CH4 flow increases from 30 sccm to 80 sccm. IR spectroscopy shows that most of the hydrogen atoms in the deposited films are bonded to the sp3-hybridized C atoms. All the composition and microstructure change can be explained by considering the plasma conditions and the effect of CH4 flow.

  8. Petroleum exploration of shallow marine deposit Carboniferous volcanic tuff reservoir in the western margin of Junggar Basin

    Institute of Scientific and Technical Information of China (English)

    Wang Jianyong; Wang Xuezhong; Ma Liqun

    2013-01-01

    In 2011,petroleum exploration of shallow marine deposits Carboniferous and volcanic tuff reservoir re-alized breakthroughs at Chepaizi slope in the western margin of Junggar Basin. Pai 61 well ,with 855.7 ~949.6 m section,in the conventional test oil obtained 6 t/d industrial oil flow. The surface viscosity is 390 mPa· s (50℃). The marine deposit of Carboniferous are deep oil source rocks and high-quality reservoir. Magma volcanic activity provides the basis for volcanic reservoir development and distribution. The weathering crust and secondary cracks developed volcanic tuff by strong rock weathering and dissolution of organic acids which has become top quality reservoir. Deep Permian oil-gas migrated and accumulated to high parts along Hong-Che fault belt and stratigraphic unconformity stripping. Permian and Triassic volcanic rocks or dense mudstone sedimentary cover as a regional seal for the late Carboniferous oil-gas to save critically. The seismic pre-stack time migration processing technologies for the problem of poor inner structures of Carboniferous were developed. Response of volcanic rock seismic and logging are obvious. The application imaging logging and nuclear magnetic technology achieved the qualitative identification and quantification of fracture description.

  9. Palaeoclimatic considerations of talus flatirons and aeolian deposits in Northern Fuerteventura volcanic island (Canary Islands, Spain)

    Science.gov (United States)

    Gutiérrez-Elorza, Mateo; Lucha, Pedro; Gracia, F.-Javier; Desir, Gloria; Marín, Cinta; Petit-Maire, Nicole

    2013-09-01

    Fuerteventura volcanic island has been subject to considerable aeolian activity since the Late Pleistocene. The aeolian record includes inactive aeolian deposits with interbedded entisols, whose age by OSL dating ranges between 46 and 26 ky BP. The Corralejo active dune field, where sand sheets, nebkhas, coppice dunes, blowouts, barchans and transverse dunes have been described, constitutes a more recent Aeolian deposit. Here the age is about 14 ky BP. On Fuerteventura Island aeolian dust has been deposited on valleys and slopes. This last type of accumulation has been affected by gully incision, producing talus flatirons. Samples taken on the apex of these palaeo-slopes indicate an OSL age of 30 and 50 ky BP. A palaeoclimatic succession has been interpreted during which a prevailing arid period took place in OIS 4, with the accumulation of aeolian dust. A humid period occurred in OIS 2, during which slopes were dissected and formed talus flatirons. An arid period about 14 ky BP gave rise to the Corralejo dune field, which has continued until present with slight climatic oscillations.

  10. Silver sulfotellurides from volcanic-hosted massive sulfide deposits in the Southern Urals

    Science.gov (United States)

    Novoselov, K. A.; Belogub, E. V.; Zaykov, V. V.; Yakovleva, V. A.

    2006-07-01

    This paper addresses Ag-sulfotellurides occurring in volcanic-hosted massive sulfide deposits of the Southern Urals. Cervelleite-like minerals were identified in ores from the Gayskoe, Yaman-Kasy, Severo-Uvaryazhskoe, Tash-Tau, and Babaryk deposits, where they occur in ores containing chalcopyrite, galena, sphalerite, tennantite ± bornite. Other Ag- and Te-bearing minerals (electrum, hessite, stromeyerite and Ag-bearing chalcocite) are present in the association. A benleonardite-like mineral associated with sylvanite and native tellurium was found as a metastable phase in paleohydrothermal tubes relics from the Yaman-Kasy deposit. Formation of the sulfotellurides indicates relative low fTe2 in the hydrothermal systems, insufficient for formation of most S-free tellurides. The significant Cu enrichment in cervelleite relates to the association with bornite. Broad variations in composition and physical properties of cervelleite-like sulfotellurides allow the supposition of the presence of several, as yet unnamed mineral species, which can be distinguished by Cu contents, Te/S ratios, and presumably by crystal structure.

  11. Thermal conductivity of titanium aluminum silicon nitride coatings deposited by lateral rotating cathode arc

    Energy Technology Data Exchange (ETDEWEB)

    Samani, M.K., E-mail: majid1@e.ntu.edu.sg [School of Electrical and Electronic Engineering, Nanyang Technological University, Nanyang Avenue, Singapore 639798 (Singapore); Surface Technology Group, Singapore Institute of Manufacturing Technology, 71 Nanyang Drive, Singapore 638075 (Singapore); CINTRA-CNRS/NTU/THALES, UMI 3288, Research Techno Plaza, 50 Nanyang Drive, Border X Block, Level 6, Singapore 637553 (Singapore); Ding, X.Z. [Surface Technology Group, Singapore Institute of Manufacturing Technology, 71 Nanyang Drive, Singapore 638075 (Singapore); Amini, S. [School of Materials Science and Engineering. Nanyang Technological University, 50 Nanyang Avenue, Singapore (Singapore); Khosravian, N.; Cheong, J.Y. [School of Electrical and Electronic Engineering, Nanyang Technological University, Nanyang Avenue, Singapore 639798 (Singapore); Chen, G. [BC Photonics Technological Company, 5255 Woodwards Rd., Richmond, BC V7E 1G9 (Canada); Tay, B.K. [School of Electrical and Electronic Engineering, Nanyang Technological University, Nanyang Avenue, Singapore 639798 (Singapore); CINTRA-CNRS/NTU/THALES, UMI 3288, Research Techno Plaza, 50 Nanyang Drive, Border X Block, Level 6, Singapore 637553 (Singapore)

    2013-06-30

    A series of physical vapour deposition titanium aluminum silicon nitride nanocomposite coating with a different (Al + Si)/Ti atomic ratio, with a thickness of around 2.5 μm were deposited on stainless steel substrate by a lateral rotating cathode arc process in a flowing nitrogen atmosphere. The composition and microstructure of the as-deposited coatings were analyzed by energy dispersive X-ray spectroscopy, and X-ray diffraction, and cross-sectional scanning electron microscopy observation. The titanium nitride (TiN) coating shows a clear columnar structure with a predominant (111) preferential orientation. With the incorporation of Al and Si, the crystallite size in the coatings decreased gradually, and the columnar structure and (111) preferred orientation disappeared. Thermal conductivity of the as-deposited coating samples at room temperature was measured by using pulsed photothermal reflectance technique. Thermal conductivity of the pure TiN coating is about 11.9 W/mK. With increasing the (Al + Si)/Ti atomic ratio, the coatings' thermal conductivity decreased monotonously. This reduction of thermal conductivity could be ascribed to the variation of coatings' microstructure, including the decrease of grain size and the resultant increase of grain boundaries, the disruption of columnar structure, and the reduced preferential orientation. - Highlights: • A series of titanium aluminum silicon nitride with different (Al + Si)/Ti atomic ratio were deposited on Fe304. • The composition and microstructure of the as-deposited coatings were analyzed. • Thermal conductivity of the samples was measured by pulsed photothermal reflectance. • With increasing the (Al + Si)/Ti atomic ratio, thermal conductivity decreased. • Reduction of thermal conductivity is ascribed to the variation of its microstructure.

  12. Paleoproterozoic arc basalt-boninite-high magnesian andesite-Nb enriched basalt association from the Malangtoli volcanic suite, Singhbhum Craton, eastern India: Geochemical record for subduction initiation to arc maturation continuum

    Science.gov (United States)

    Rajanikanta Singh, M.; Manikyamba, C.; Ganguly, Sohini; Ray, Jyotisankar; Santosh, M.; Dhanakumar Singh, Th.; Chandan Kumar, B.

    2017-02-01

    The Singhbhum Craton of eastern India preserves distinct signatures of ultramafic-mafic-intermediate-felsic magmatism of diverse geodynamic affiliations spanning from Paleo-Mesoarchean to Proterozoic. Here we investigate the 2.25 Ga Malangtoli volcanic rocks that are predominantly clinopyroxene- and plagioclase-phyric, calc-alkaline in nature, display basalt-basaltic andesite compositions, and preserve geochemical signatures of subduction zone magmatism. Major, trace and rare earth element characteristics classify the Malangtoli volcanic rocks as arc basalts, boninites, high magnesian andesites (HMA) and Nb enriched basalts (NEB). The typical LILE enriched-HFSE depleted geochemical attributes of the arc basalts corroborate a subduction-related origin. The boninitic rocks have high Mg# (0.8), MgO (>25 wt.%), Ni and Cr contents, high Al2O3/TiO2 (>20), Zr/Hf and (La/Sm)N (>1) ratios with low (Gd/Yb)N (54 wt.%), MgO (>6 wt.%), Mg# (0.47) with elevated Cr, Co, Ni and Th contents, depleted (Nb/Th)N, (Nb/La)N, high (Th/La)N and La/Yb (<9) ratio, moderate depletion in HREE and Y with low Sr/Y. The NEBs have higher Nb contents (6.3-24 ppm), lower magnitude of negative Nb anomalies with high (Nb/Th)pm = 0.28-0.59 and (Nb/La)pm = 0.40-0.69 and Nb/U = 2.8-34.4 compared to normal arc basalts [Nb = <2 ppm; (Nb/Th)pm = 0.10-1.19; (Nb/La)pm 0.17-0.99 and Nb/U = 2.2-44 respectively] and HMA. Arc basalts and boninites are interpreted to be the products of juvenile subduction processes involving shallow level partial melting of mantle wedge under hydrous conditions triggered by slab-dehydrated fluid flux. The HMA resulted through partial melting of mantle wedge metasomatized by slab-dehydrated fluids and sediments during the intermediate stage of subduction. Slab-melting and mantle wedge hybridization processes at matured stages of subduction account for the generation of NEB. Thus, the arc basalt-boninite-HMA-NEB association from Malangtoli volcanic suite in Singhbhum Craton

  13. ATMOSPHERIC DISPERSAL AND DEPOSITION OF TEPHRA FROM A POTENTIAL VOLCANIC ERUPTION AT YUCCA MOUNTAIN, NEVADA

    Energy Technology Data Exchange (ETDEWEB)

    C. Harrington

    2004-10-25

    The purpose of this model report is to provide documentation of the conceptual and mathematical model (Ashplume) for atmospheric dispersal and subsequent deposition of ash on the land surface from a potential volcanic eruption at Yucca Mountain, Nevada. This report also documents the ash (tephra) redistribution conceptual model. These aspects of volcanism-related dose calculation are described in the context of the entire igneous disruptive events conceptual model in ''Characterize Framework for Igneous Activity'' (BSC 2004 [DIRS 169989], Section 6.1.1). The Ashplume conceptual model accounts for incorporation and entrainment of waste fuel particles associated with a hypothetical volcanic eruption through the Yucca Mountain repository and downwind transport of contaminated tephra. The Ashplume mathematical model describes the conceptual model in mathematical terms to allow for prediction of radioactive waste/ash deposition on the ground surface given that the hypothetical eruptive event occurs. This model report also describes the conceptual model for tephra redistribution from a basaltic cinder cone. Sensitivity analyses and model validation activities for the ash dispersal and redistribution models are also presented. Analyses documented in this model report update the previous documentation of the Ashplume mathematical model and its application to the Total System Performance Assessment (TSPA) for the License Application (TSPA-LA) igneous scenarios. This model report also documents the redistribution model product outputs based on analyses to support the conceptual model. In this report, ''Ashplume'' is used when referring to the atmospheric dispersal model and ''ASHPLUME'' is used when referencing the code of that model. Two analysis and model reports provide direct inputs to this model report, namely ''Characterize Eruptive Processes at Yucca Mountain, Nevada and Number of Waste Packages Hit

  14. The geochemistry of lithium-bearing geothermal water, Taupo Volcanic Zone, and shallow fluid processes in a very active silicic volcanic arc

    Science.gov (United States)

    Dean, A. S.; Hoskin, P. W.; Rudnick, R. L.; Liu, X.; Boseley, C.

    2011-12-01

    The Li abundances and isotopic systematics of Taupo Volcanic Zone (TVZ) geothermal fluids preserves a record of processes occurring within shallow portions of geothermal reservoirs as well as deeper portions of the arc crust. Understanding Li cycling and isotopic fractionation in TVZ geothermal systems contributes to a more refined understanding of physicochemical processes affecting New Zealand's geothermal resources. A comprehensive dataset of 73 samples was compiled, with samples collected from geothermal surface features (springs, spouters, geysers, etc.) and electric-power industry production wells, collectively representing18 geothermal fields across the breadth and width the TVZ. No comparable dataset of fluid analyses exists. Ion chromatography, AAS, and quadrupole ICP-MS analyses were done for Li, Cl-, SiO2, SO42- K, Na, Ca, Mg, B, Sr and Pb concentrations. Lithium abundance in geothermal fluids from the TVZ have a dataset-wide average of 5.9 mg/L and range 4 μg/L to 29 mg/L. The Li abundance and Li/Cl ratios for geothermal water and steam condensates vary systematically as a result of boiling, mixing, and water/rock reaction. Lithium abundance and Li/Cl ratios are, therefore, indicators of shallow (above 2.5 km) and locally variable reservoir processes. δ7Li analysis of 63 samples was performed at the University of Maryland, College Park. Data quality was controlled by measurement of L-SVEC as a calibration standard and by multiple analysis of selected samples. The average δ7Li value for TVZ geothermal fluids is -0.8%. Most δ7Li values for geothermal water fall within a small range of about -3% to+2% indicating similar processes are causing similar isotopic fractionation throughout the region. Considered together, Li aundances and δ7Li values, in combination with numerical models, indicate possible evolution pathways and water/rock reactions in TVZ geothermal systems. Models based on rocks and surface water analysis indicate that Li cycles and

  15. Inorganic-solid-state electrolyte layer deposited by cathodic arc plasma for rapidly switching electrochromic device

    Science.gov (United States)

    Chen, Po-Wen; Chang, Chen-Te; Wu, Jin-Yu; Jan, Der-Jun; Li, Yu-Chen; Hsieh, Cheng-Chang; Tsai, Wen-Fa

    2017-08-01

    This work focuses on fabricating a solid electrolyte Ta2O5 thin film deposited by cathodic arc plasm (CAP) deposition through three different ratio of oxygen and argon. In our experiments, refractive index of Ta2O5 films are taken as 2.25, 1.96, 1.9 with various O2/Ar= 1.5, O2/Ar= 2, O2/Ar= 2.4, respectively. Our results show that the refractive index mostly decreased as we increase the oxygen flow rate, in which the minimum is found at 240 sccm. It provides good conduction pathways for ions through smaller thin-film's refractive index that exhibits more porosity voids. This property enhances ion's mobility for electrochromic device causing rapid coloring/bleaching phenomenon. Ta2O5 thin film is suitable as a solid electrolyte layer in center of electrochromic device (ECD) using CAP deposition. As a result, rapid response times were observed in fabricated device with an area of 5 cm×5 cm, exhibiting transmittance optical modulation ΔT = 61.5% (@550 nm) with the bleaching time τ = 8 s and transmittance optical modulation ΔT = 50% (@550 nm) with the coloring time τ = 10 s.

  16. X-ray reflectivity analysis of titanium dioxide thin films grown by cathodic arc deposition.

    Science.gov (United States)

    Kleiman, A; Lamas, D G; Craievich, A F; Márquez, A

    2014-05-01

    TiO2 thin films deposited by a vacuum arc on a glass substrate were characterized by X-ray reflectivity (XRR), X-ray diffraction (XRD), scanning electron microscopy (SEM) and atomic force microscopy (AFM). Several thin films with different amounts of deposited TiO2 mass and different deposition and annealing temperatures were studied. A qualitative analysis of the XRD patterns indicated the presence of the anatase and/or rutile crystalline phases in most of the studied samples. From the analysis of the experimental XRR curves--which exhibited a wide angular range of oscillatory behavior--the thickness, mass density and interface roughness were determined. All XRR patterns were well fitted by modeled curves that assume the presence of a single and homogeneous TiO2 layer over which a very thin H2O layer is adsorbed. The thickest H2O adsorption layers were developed in films with the highest anatase content. Our overall results of the XRR analyses are consistent with those derived from the imaging techniques (SEM and AFM).

  17. Bioactivity and cytocompatibility of zirconia (ZrO(2)) films fabricated by cathodic arc deposition.

    Science.gov (United States)

    Liu, Xuanyong; Huang, Anping; Ding, Chuanxian; Chu, Paul K

    2006-07-01

    Zirconium oxide thin films were fabricated on silicon wafers using a filtered cathodic arc system in concert with oxygen plasma. The structure and phase composition of the zirconium oxide thin films were characterized by atomic force microscopy (AFM), X-ray diffraction (XRD), Rutherford backscattering spectrometry (RBS), and transmission electron microscopy (TEM). The bioactivity was assessed by investigating the formation of apatite on the film surface after soaking in simulated body fluids. Bone marrow mesenchymal stem cells (BMMSC) were used to further evaluate the cytocompatibility of the materials. The results indicate that the films are composed of stoichiometric ZrO(2) and the composition is quite uniform throughout the thickness. Bone-like apatite can be formed on the surface of the ZrO(2) thin film in our SBF immersion experiments, suggesting that the surface is bioactive. The outermost layer of the ZrO(2) thin film comprises nano-sized particles that can be identified by AFM images taken on the thin film surface and TEM micrographs obtained from the interface between the ZrO(2) thin film and apatite layer. The nanostructured surface is believed to be the key factor that apatite is induced to precipitate on the surface. Bone marrow mesenchymal stem cells are observed to grow and proliferate in good states on the film surface. Our results show that ZrO(2) thin films fabricated by cathodic arc deposition exhibit favorable bioactivity and cytocompatibility.

  18. Ultrathin diamond-like carbon films deposited by filtered carbon vacuum arcs

    Energy Technology Data Exchange (ETDEWEB)

    Anders, Andre; Fong, Walton; Kulkarni, Ashok; Ryan, Francis W.; Bhatia, C. Singh

    2001-07-13

    Ultrathin (< 5 nm) hard carbon films are of great interest to the magnetic storage industry as the areal density approaches 100 Gbit/in{sup 2}. These films are used as overcoats to protect the magnetic layers on disk media and the active elements of the read-write slider. Tetrahedral amorphous carbon films can be produced by filtered cathodic arc deposition, but the films will only be accepted by the storage industry only if the ''macroparticle'' issue has been solved. Better plasma filters have been developed over recent years. Emphasis is put on the promising twist filter system - a compact, open structure that operates with pulsed arcs and high magnetic field. Based on corrosion tests it is shown that the macroparticle reduction by the twist filter is satisfactory for this demanding application, while plasma throughput is very high. Ultrathin hard carbon films have been synthesized using S-filter and twist filter systems. Film properties such as hardness, elastic modulus, wear, and corrosion resistance have been tested.

  19. Ultrathin diamond-like carbon films deposited by filtered carbon vacuum arcs

    Energy Technology Data Exchange (ETDEWEB)

    Anders, Andre; Fong, Walton; Kulkarni, Ashok; Ryan, Francis W.; Bhatia, C. Singh

    2001-07-13

    Ultrathin (< 5 nm) hard carbon films are of great interest to the magnetic storage industry as the areal density approaches 100 Gbit/in{sup 2}. These films are used as overcoats to protect the magnetic layers on disk media and the active elements of the read-write slider. Tetrahedral amorphous carbon films can be produced by filtered cathodic arc deposition, but the films will only be accepted by the storage industry only if the ''macroparticle'' issue has been solved. Better plasma filters have been developed over recent years. Emphasis is put on the promising twist filter system - a compact, open structure that operates with pulsed arcs and high magnetic field. Based on corrosion tests it is shown that the macroparticle reduction by the twist filter is satisfactory for this demanding application, while plasma throughput is very high. Ultrathin hard carbon films have been synthesized using S-filter and twist filter systems. Film properties such as hardness, elastic modulus, wear, and corrosion resistance have been tested.

  20. Efusiones subácueas del arco volcánico ordovícico en el norte del sistema de Famatina Subaqueous eruptions in the Ordovician volcanic arc in the northern Famatina System

    Directory of Open Access Journals (Sweden)

    Clara Eugenia Cisterna

    2010-03-01

    hyaloclastites are valuable indicators of the effusive volcanism under subaqueous conditions. The sequence, including debris-flows and turbidity-current levels, especially at the upper levels of the column, may have developed as a result of repeated syn-volcanic sedimentation events. The fossil content in the volcanogenic facies and levels with pyroclastic clasts and accretionary lapilli reflect a shallow water depositional environment. An exclusive volcanic provenance was recognized even in the epiclastic deposits, pointing to a continuous magmatic activity of the arc and an intermittent intrabasinal contribution related to the instability events. The very high proportion of volcaniclastic deposits in the sequence, especially at the upper levels, indicates an efficient fragmentation processes as well as repeated erosion events during the evolution of the Ordovician basin.

  1. Preparation and tribological properties of DLC/Ti film by pulsed laser arc deposition

    Institute of Scientific and Technical Information of China (English)

    Zhang Zhen-Yu; Lu Xin-Chun; Luo Jian-Bin; Shao Tian-Min; Qing Tao; Zhang Chen-Hui

    2006-01-01

    This paper reports that DLC (diamond like carbon)/Ti and DLC films were prepared by using pulsed laser arc deposition. R-ray diffraction, Auger electron spectroscopy, Raman spectroscopy, atomic force microscopy, nanoindenter, spectroscopic ellipsometer, surface profiler and micro-tribometer were employed to study the structure and tribological properties of DLC/Ti and DLC films. The results show that DLC/Ti film, with I(D)/I(G) 0.28 and corresponding to 76% sp3 content calculated by Raman spectroscopy, uniform chemical composition along depth direction, 98 at% content of carbon, hardness 8.2 GPa and Young's modulus 110.5 GPa, compressive stress 6.579 GPa, thickness 46 nm,coefficient of friction 0.08, and critical load 95mN, exhibits excellent mechanical and tribological properties.

  2. Review of cathodic arc deposition technology at the start of the new millennium

    Energy Technology Data Exchange (ETDEWEB)

    Sanders, D M; Anders, A

    2000-02-24

    The vacuum cathodic arc has been known to provide a means of producing coatings since the second half of the 19th century. This makes it one of the oldest known means for making coatings in a vacuum. In the last century it has been recognized that the copious quantities of ions produced by the process offers certain advantages in terms of coating properties. Specifically, ions can be steered and/or accelerated toward the parts to be coated. This, in turn, can provide enhanced adhesion, film density, and composition stoichiometry in the case of compound coatings. The ions generated by the cathodic arc have high ''natural'' kinetic energy values in the range 20-200 eV, leading to enhanced surface mobility during the deposition process and even ion subplantation. In many cases, dense coatings are achieved even when non-normal arrival angles are involved. The ion energy can further manipulated by the plasma immersion biasing technique. The issue of macroparticle contamination has been addressed by a variety of novel plasma filters. In spite of all of these advantages, this deposition technique has not been widely adopted in the western nations for commercial coating except in the case of enhancing the performance of cutting tools. The purpose of the this review is to explore reasons for this lack of general use of the technology and to point out some encouraging recent developments which may lead to its accelerated adoption for a much wider variety of applications in the near future.

  3. Geochemistry of Volcanic Rocks from International Ocean Discovery Program (IODP) Site 1438, Amami Sankaku Basin: Implications for Izu-Bonin-Mariana (IBM) Arc Initiation

    Science.gov (United States)

    Hickey-Vargas, R.; Ishizuka, O.; Yogodzinski, G. M.; Bizimis, M.; Savov, I. P.; McCarthy, A. J.; Arculus, R. J.; Bogus, K.

    2015-12-01

    IODP Expedition 351 drilled 150 m of volcanic basement overlain by 1461 m of sedimentary material at Site 1438 in the Amami Sankaku basin, just west of the Kyushu Palau Ridge, the locus of IBM arc initiation. Age interpretations based on biostratigraphy (Arculus et al., Nat. Geosci., in-press) determined that the age of the basement section is between 64 and 51 Ma, encompassing the age of the earliest volcanic products of the IBM arc. The Site 1438 volcanic basement consists of multiple flows of aphyric microcrystalline to finely crystalline basalts containing plagioclase and clinopyroxene with rare olivine pseudomorphs. New XRF major and ICPMS trace element data confirm findings of shipboard analysis that the basalts are moderately differentiated (6-14 % MgO; Mg# = 51-83; 73-490 ppm Cr and 58-350 ppm Ni) with downcore variations related to flow units. Ti/V and Ti/Sc ratios are 16-27 and 75-152, respectively, with lowest values at the base of the core. One prominent characteristic of the basalts is their depletion of immobile highly incompatible elements compared with MORB. Basalts have MORB-normalized La/Nd of 0.5 to 0.9, and most have Th/La andesites from three sills in the lowermost sedimentary unit have arc-like trace element patterns with La/Nb > 3 and primitive mantle normalized La/Yb > 1. Our results suggest that mantle melting at the onset of subduction involved exceptionally depleted sources. Enrichment over time may be related to increasing subduction inputs and/or other processes, such as entrainment of fertile asthenosphere during extension of the overriding plate.

  4. Witwatersrand gold deposits formed by volcanic rain, anoxic rivers and Archaean life

    Science.gov (United States)

    Heinrich, Christoph A.

    2015-03-01

    The Witwatersrand Basin in South Africa is one of the best-preserved records of fluvial sedimentation on an Archaean continent. The basin hosts the worlds biggest gold resource in thin pebble beds, but the process for gold enrichment is debated. Mechanical accumulation of gold particles from flowing river water is the prevailing hypothesis, yet there is evidence for hydrothermal mobilization of gold by fluids invading the metasedimentary rocks after their burial. Earth's atmosphere three billion years ago was oxygen free, but already sustained some of the oldest microbial life on land. Here I use thermodynamic modelling and mass-balance calculations to show that these conditions could have led to the chemical transport and precipitation of gold in anoxic surface waters, reconciling the evidence for fluvial deposition with evidence for hydrothermal-like chemical reactions. I suggest that the release of sulphurous gases from large volcanic eruptions created acid rain that enabled the dissolution and transport of gold in surface waters as sulphur complexes. Precipitation of the richest gold deposits could have been triggered by chemical reduction of the dissolved gold onto organic material in shallow lakes and pools. I conclude that the Witwatersrand gold could have formed only during the Archaean, after the emergence of continental life but before the rise of oxygen in the Earth's atmosphere.

  5. Probabilities of future VEI ≥ 2 eruptions at the Central American Volcanic Arc: a statistical perspective based on the past centuries' eruption record

    Science.gov (United States)

    Dzierma, Yvonne; Wehrmann, Heidi

    2014-10-01

    A probabilistic eruption forecast is provided for seven historically active volcanoes along the Central American Volcanic Arc (CAVA), as a pivotal empirical contribution to multi-disciplinary volcanic hazards assessment. The eruption probabilities are determined with a Kaplan-Meier estimator of survival functions, and parametric time series models are applied to describe the historical eruption records. Aside from the volcanoes that are currently in a state of eruptive activity (Santa María, Fuego, and Arenal), the highest probabilities for eruptions of VEI ≥ 2 occur at Concepción and Cerro Negro in Nicaragua, which are likely to erupt to 70-85 % within the next 10 years. Poás and Irazú in Costa Rica show a medium to high eruption probability, followed by San Miguel (El Salvador), Rincón de la Vieja (Costa Rica), and Izalco (El Salvador; 24 % within the next 10 years).

  6. Petrogenesis of meta-volcanic rocks from the Maimón Formation (Dominican Republic): Geochemical record of the nascent Greater Antilles paleo-arc

    Science.gov (United States)

    Torró, Lisard; Proenza, Joaquín A.; Marchesi, Claudio; Garcia-Casco, Antonio; Lewis, John F.

    2017-05-01

    Metamorphosed basalts, basaltic andesites, andesites and plagiorhyolites of the Early Cretaceous, probably pre-Albian, Maimón Formation, located in the Cordillera Central of the Dominican Republic, are some of the earliest products of the Greater Antilles arc magmatism. In this article, new whole-rock element and Nd-Pb radiogenic isotope data are used to give new insights into the petrogenesis of the Maimón meta-volcanic rocks and constrain the early evolution of the Greater Antilles paleo-arc system. Three different groups of mafic volcanic rocks are recognized on the basis of their immobile element contents. Group 1 comprises basalts with compositions similar to low-Ti island arc tholeiites (IAT), which are depleted in light rare earth elements (LREE) and resemble the forearc basalts (FAB) and transitional FAB-boninitic basalts of the Izu-Bonin-Mariana forearc. Group 2 rocks have boninite-like compositions relatively rich in Cr and poor in TiO2. Group 3 comprises low-Ti island arc tholeiitic basalts with near-flat chondrite-normalized REE patterns. Plagiorhyolites and rare andesites present near-flat to subtly LREE-depleted chondrite normalized patterns typical of tholeiitic affinity. Nd and Pb isotopic ratios of plagiorhyolites, which are similar to those of Groups 1 and 3 basalts, support that these felsic lavas formed by anatexis of the arc lower crust. Geochemical modelling points that the parental basic magmas of the Maimón meta-volcanic rocks formed by hydrous melting of a heterogeneous spinel-facies mantle source, similar to depleted MORB mantle (DMM) or depleted DMM (D-DMM), fluxed by fluids from subducted oceanic crust and Atlantic Cretaceous pelagic sediments. Variations of subduction-sensitive element concentrations and ratios from Group 1 to the younger rocks of Groups 2 and 3 generally match the geochemical progression from FAB-like to boninite and IAT lavas described in subduction-initiation ophiolites. Group 1 basalts likely formed at magmatic

  7. Bimodal volcanism in northeast Puerto Rico and the Virgin Islands (Greater Antilles Island Arc): Genetic links with Cretaceous subduction of the mid-Atlantic ridge Caribbean spur

    Science.gov (United States)

    Jolly, Wayne T.; Lidiak, Edward G.; Dickin, Alan P.

    2008-07-01

    Bimodal extrusive volcanic rocks in the northeast Greater Antilles Arc consist of two interlayered suites, including (1) a predominantly basaltic suite, dominated by island arc basalts with small proportions of andesite, and (2) a silicic suite, similar in composition to small volume intrusive veins of oceanic plagiogranite commonly recognized in oceanic crustal sequences. The basaltic suite is geochemically characterized by variable enrichment in the more incompatible elements and negative chondrite-normalized HFSE anomalies. Trace element melting and mixing models indicate the magnitude of the subducted sediment component in Antilles arc basalts is highly variable and decreases dramatically from east to west along the arc. In the Virgin Islands, the sediment component ranges betweenCampanian strata. In comparison, sediment proportions in central Puerto Rico range between 0.5 to 1.5% in the Albian to 2 to > 4% during the Cenomanian-Campanian interval. The silicic suite, consisting predominantly of rhyolites, is characterized by depleted Al 2O 3 (average arc-like Sr, Nd, and Pb isotope signatures, and by the presence of plagioclase. All of these features are consistent with an anatexic origin in gabbroic sources, of both oceanic and arc-related origin, within the sub-arc basement. The abundance of silicic lavas varies widely along the length of the arc platform. In the Virgin Islands on the east, rhyolites comprise up to 80% of Lower Albian strata (112 to 105 Ma), and about 20% in post-Albian strata (105 to 100 Ma). Farther west, in Puerto Rico, more limited proportions (Campanian times. Within this hypothetical setting the centrally positioned Virgin Islands terrain remained approximately fixed above the subducting ridge as the Antilles arc platform swept northeastward into the slot between the Americas. Accordingly, heat flow in the Virgin Islands was elevated throughout the Cretaceous, giving rise to widespread crustal melting, whereas the subducted sediment

  8. Comprehensive study of the seismotectonics of the easter Aleutian arc and associated volcanic systems. Annual progress report, March 1, 1978--February 28, 1979

    Energy Technology Data Exchange (ETDEWEB)

    Jacob, K.H.; Davies, J.N.; Beavan, J.; Johnson, D.; House, L.; Krause, J.; Hickman, S.; Winslow, M.; Hauptman, J.; Mori, J.; Sykes, L.R.

    1979-01-01

    Based on the historic seismic record and accurate hypocenter data obtained from the eastern Aleutian seismic network, a relationship between the subduction-zone seismicity, volcano-trench separation, and the occurrence of great thrust earthquakes has been established for the Aleutian arc. On the basis of strong-motion accelerometer data it was found that high stress drops (540 t 650 bars) were associated with two moderate-size earthquakes (m/sub b/ = 6.0 and 5.8) within the Shumagin Islands seismic gap. This indicates that near the down-dip end of the major thrust zone, at depths of about 40 km, high tectonic stresses have accumulated within the gap segment of the arc. That such accumulation of stress is presently an ongoing process is corroborated by results from geodetic precision leveling on Unga Island. The leveling data indicate tilt rates of about 1 microradian/year. The tilting is directed down towards the trench and up towards the volcanic arc. Whether the recent activity of Pavlof, Shishaldin and Westdahl volcanoes indicates transmission of high tectonic stresses from the major thrust zone to the volcanic arc is unresolved. The search for a shallow magma chamber beneath the seismically monitored Pavlof volcano is still inconclusive although large amounts of recently acquired data remain to be analyzed. A geologic reconnaissance of the Shumagin Islands and the Adjacent Alaska Peninsula revealed Quaternary uplifted marine terraces and evidence for Holocene faulting. Both findings have severe implications for long-term tectonic activity and seismic hazards in the region of this seismic gap, portions of which are presently considered for off-shore hydrocarbon exploration and development. A critical analysis of th presently operating seimic data acquisition system reveals that a major change in remote sensing and central recording equipment is urgently needed for the Pavlof, Cold Bay, and Shumagin sections of the seismic array.

  9. New ion-assisted filtered cathodic arc deposition (IFCAD) technology for producing advanced thin films on temperature-sensitive substrates

    Science.gov (United States)

    Fulton, Michael L.

    1999-10-01

    An innovative Ion-Assisted Filtered Cathodic Arc Deposition (IFCAD) system has been developed for low temperature production of thin-film coatings. The IFCAD system employs electro-magnetic and mechanical filtering techniques to remove unwanted macroparticles and neutral atoms from the plasma stream. Therefore, only ions within a defined energy range arrive at the substrate surface, depositing thin-films with excellent mechanical and optical properties. Ion- Assisted-Deposition is coupled with Filtered Cathodic Arc technology to enhance and modify the arc deposited thin- films. Using an advanced computer controlled plasma beam scanning system, high quality, large area, uniform IFCAD multi-layer film structures are attained. Amorphous Diamond- Like-Carbon films (up to 85% sp3 bonded carbon; and micro- hardness greater than 50 GPa) have been deposited in multi- layer thin-film combinations with other IFCAD source materials (such as: Al2O3) for optical and tribological applications. Rutile TiO2 (refractive index of 2.8 at 500 nm) has been deposited with this technology for advanced optical filter applications. The new IFCAD technology has been included in development programs, such as: plastic and glass lens coatings for optical systems; wear resistant coatings on various metal substrates, ultra smooth, durable, surface hydrophobic coatings for aircraft windows; EUV coatings for space instrumentation; transparent conductive coatings; and UV protective coatings for solar cell concentrator plastic Fresnel lens elements for space power.

  10. Interface control of atomic layer deposited oxide coatings by filtered cathodic arc deposited sublayers for improved corrosion protection

    Energy Technology Data Exchange (ETDEWEB)

    Härkönen, Emma, E-mail: emma.harkonen@helsinki.fi [Laboratory of Inorganic Chemistry, University of Helsinki, P.O. Box 55, FIN-00014 Helsinki (Finland); Tervakangas, Sanna; Kolehmainen, Jukka [DIARC-Technology Inc., Espoo (Finland); Díaz, Belén; Światowska, Jolanta; Maurice, Vincent; Seyeux, Antoine; Marcus, Philippe [Laboratoire de Physico-Chimie des Surfaces, CNRS (UMR 7075) – Chimie ParisTech (ENSCP), F-75005 Paris (France); Fenker, Martin [FEM Research Institute, Precious Metals and Metals Chemistry, D-73525 Schwäbisch Gmünd (Germany); Tóth, Lajos; Radnóczi, György [Research Centre for Natural Sciences HAS, (MTA TKK), Budapest (Hungary); Ritala, Mikko [Laboratory of Inorganic Chemistry, University of Helsinki, P.O. Box 55, FIN-00014 Helsinki (Finland)

    2014-10-15

    Sublayers grown with filtered cathodic arc deposition (FCAD) were added under atomic layer deposited (ALD) oxide coatings for interface control and improved corrosion protection of low alloy steel. The FCAD sublayer was either Ta:O or Cr:O–Ta:O nanolaminate, and the ALD layer was Al{sub 2}O{sub 3}–Ta{sub 2}O{sub 5} nanolaminate, Al{sub x}Ta{sub y}O{sub z} mixture or graded mixture. The total thicknesses of the FCAD/ALD duplex coatings were between 65 and 120 nm. Thorough analysis of the coatings was conducted to gain insight into the influence of the FCAD sublayer on the overall coating performance. Similar characteristics as with single FCAD and ALD coatings on steel were found in the morphology and composition of the duplex coatings. However, the FCAD process allowed better control of the interface with the steel by reducing the native oxide and preventing its regrowth during the initial stages of the ALD process. Residual hydrocarbon impurities were buried in the interface between the FCAD layer and steel. This enabled growth of ALD layers with improved electrochemical sealing properties, inhibiting the development of localized corrosion by pitting during immersion in acidic NaCl and enhancing durability in neutral salt spray testing. - Highlights: • Corrosion protection properties of ALD coatings were improved by FCAD sublayers. • The FCAD sublayer enabled control of the coating-substrate interface. • The duplex coatings offered improved sealing properties and durability in NSS. • The protective properties were maintained during immersion in a corrosive solution. • The improvements were due to a more ideal ALD growth on the homogeneous FCAD oxide.

  11. The multilayered structure of ultrathin amorphous carbon films synthesized by filtered cathodic vacuum arc deposition

    KAUST Repository

    Wang, Na

    2013-08-01

    The structure of ultrathin amorphous carbon (a-C) films synthesized by filtered cathodic vacuum arc (FCVA) deposition was investigated by high-resolution transmission electron microscopy, electron energy loss spectroscopy, and x-ray photoelectron spectroscopy. Results of the plasmon excitation energy shift and through-thickness elemental concentration show a multilayered a-C film structure comprising an interface layer consisting of C, Si, and, possibly, SiC, a buffer layer with continuously increasing sp 3 fraction, a relatively thicker layer (bulk film) of constant sp 3 content, and an ultrathin surface layer rich in sp 2 hybridization. A detailed study of the C K-edge spectrum indicates that the buffer layer between the interface layer and the bulk film is due to the partial backscattering of C+ ions interacting with the heavy atoms of the silicon substrate. The results of this study provide insight into the minimum thickness of a-C films deposited by FCVA under optimum substrate bias conditions. Copyright © 2013 Materials Research Society.

  12. Characteristics of Single-Track and Multi-track Depositions of Stellite by Micro-plasma Transferred Arc Powder Deposition Process

    Science.gov (United States)

    Sawant, Mayur S.; Jain, N. K.

    2017-08-01

    This paper describes the characteristics study of single-track and multi-track deposition of Stellite 6 on AISI 4130 steel substrate by indigenously developed micro-plasma transferred arc powder deposition (μ-PTAPD) process. Deposition height and width, dilution and microstructure have been used to characterize the single-track depositions by studying effects of micro-plasma power, travel speed of worktable and powder mass flow rate on energy consumption per unit traverse length and power consumption per unit powder mass flow rate. Micro-plasma power was found to be the most influential parameter that affects energy and deposition material consumption. Consequently, its influence on micro-hardness and abrasion resistance of multi-track deposition was studied. Results showed that increase in micro-plasma power decreases micro-hardness and scratch hardness number and increases mean value of friction coefficient. Comparison of microstructure and chemical composition of single-track and multi-track depositions revealed that single-track has finer dendritic microstructure than the multi-track deposition. The black colored matrix and white colored dendrites present in the multi-track deposition have higher wt.% of cobalt and less wt.% of chromium than the single-track deposition. Comparison of µ-PTAPD process capabilities with the existing processes for Stellite deposition establishes that it is an energy-efficient, cost-effective and good quality deposition yielding process.

  13. Antibacterial efficacy of advanced silver-amorphous carbon coatings deposited using the pulsed dual cathodic arc technique

    Energy Technology Data Exchange (ETDEWEB)

    Endrino, J L; Anders, A; Albella, J M; Horton, J A; Horton, T H; Ayyalasomayajula, P R; Allen, M, E-mail: jlendrino@icmm.csic.es

    2010-11-01

    Amorphous carbon (a-C) also referred as diamond-like carbon (DLC) films are well known to be a biocompatible material with good chemical in ertness; this makes it a strong candidate to be used as a matrix that embeds metallic elements with an antimicrobial effect. We have deposited as et of a-C:Ag films using a dual-cathode pulsed filtered cathodic arc source, the arc pulse frequency of the silver and graphite cathodes was controlled in order to obtain samples with various silver contents. In this study, we show the deposition of silver and carbon ions using this technique and analyze the advantages of incorporating silver into a-C by studying the antimicrobial properties against staphylococcus of samples deposited on Ti{sub 6}Al{sub 4}V coupons and evaluated using 24-well tissue culture plates.

  14. Radiocarbon Dates from Volcanic Deposits of the Chaos Crags and Cinder Cone Eruptive Sequences and Other Deposits, Lassen Volcanic National Park and Vicinity, California

    Science.gov (United States)

    Clynne, Michael A.; Christiansen, Robert L.; Trimble, Deborah A.; McGeehin, John P.

    2008-01-01

    This contribution reports radiocarbon ages obtained from charcoal, wood and other samples collected between 1979 and 2001 in Lassen Volcanic National Park and vicinity and a few samples from other nearby localities. Most of the samples are from the Chaos Crags and Cinder Cone eruptive sequences. Brief summaries are given of the Chaos Crags and Cinder Cone eruptive sequences.

  15. Effects of incidence angle on the structure and properties of cathodic vacuum arc deposition MgO thin films

    Energy Technology Data Exchange (ETDEWEB)

    Zhu, D.Y., E-mail: zhudy@gdut.edu.cn [State Key Laboratory of Optoelectronic Materials and Technologies, School of Physics and Engineering, Sun Yat-sen University, Guangzhou 510275 (China); Experiment Teaching Department, Guangdong University of Technology, Guangzhou 510006 (China); Liu, Y. [College of Physics Science and Technology, Shenzhen University, Shenzhen 518060 (China); Zheng, C.X.; Wang, M.D.; Chen, D.H. [State Key Laboratory of Optoelectronic Materials and Technologies, School of Physics and Engineering, Sun Yat-sen University, Guangzhou 510275 (China); He, Z.H., E-mail: stshzh@mail.sysu.edu.cn [State Key Laboratory of Optoelectronic Materials and Technologies, School of Physics and Engineering, Sun Yat-sen University, Guangzhou 510275 (China)

    2012-06-15

    MgO thin films, as the protective layers for plasma display panels (PDP), were prepared by using cathodic vacuum arc deposition technique. The influences of deposition angle between -60 Degree-Sign and 60 Degree-Sign on film structure and properties were investigated. X-ray diffraction (XRD), ellipsometer, thermal field emission environment scanning electron microscopy (SEM) and UV-Visible spectrophotometry were used to study the properties of MgO thin films like crystallization, surface structures, thicknesses and refraction indices. Our results show that the thickness of MgO thin film decreases with the increase of incidence angle. This is confirmed by the transmittance spectra as well. The film deposited at 0 Degree-Sign shows sharper diffraction peaks and smaller FWHMs (full width at half maximum) of both MgO (200) and (220), which means better crystallization quality of the film. The higher packing density is achieved on the 0 Degree-Sign deposited film as well. - Highlights: Black-Right-Pointing-Pointer The thickness of MgO thin film decreases with the increase of incidence angle. Black-Right-Pointing-Pointer Low-angle deposition can increase film deposition rate and improve its crystallinity. Black-Right-Pointing-Pointer Multi-arc setting or rotating substrate is necessary for uniform deposition.

  16. Early Devonian back-arc extension in the eastern Central Asian Orogenic Belt: Evidence from a bimodal volcanic sequence from Xilinhot, central Inner Mongolia (North China)

    Science.gov (United States)

    Liao, Wen; Xu, Bei; Wang, Yanyang; Zhao, Pan; Li, Qunsheng

    2017-08-01

    The Early Devonian bimodal volcanic sequence is firstly recognized in the Xilinhot area, central Inner Mongolia (North China). Zircon U-Pb dating of rhyolitic sample gives crystallization age of 407 ± 2 Ma, which is interpreted as the extrusive age of this bimodal volcanic sequence. Basaltic samples belong to tholeiite series whereas rhyolitic samples are peraluminous. Basaltic rocks show typical N-MORB-like REE and trace elemental patterns, with depletion of LREEs and negligible anomalies of Eu (δEu = 0.83-1.00). They have initial 87Sr/86Sr ratios ranging from 0.7077 to 0.7086, and positive εNd(t) values from +7.5to +9.0. By contrast, rhyolitic rocks show enrichment in LREEs and LILEs but depletion in HFSEs, with negative Eu anomalies (δEu = 0.58-0.68). They have negative εNd(t) values from -6.7 to -7.7 and TDM2 (Nd) values from 1695 to 1771 Ma. These elemental and isotopic data indicate that basaltic rocks were derived from a depleted mantle source with input of slab-derived fluids, whereas rhyolitic rocks might have been derived from remelting of Paleoproterozoic crustal materials. From our data and previous geological studies in this region, a back-arc setting was proposed for the Early Devonian bimodal volcanic rocks in the Xilinhot region. Subduction of the Paleo-Asian oceanic lithosphere caused opening of this back-arc basin and upwelling of mantle caused the formation of basalts and provided heat for remelting of crustal materials and formation of rhyolite.the

  17. Role of the Alboran Sea volcanic arc choking the Mediterranean to the Messinian salinity crisis and foundering biota diversification in North Africa and Southeast Iberia

    Science.gov (United States)

    Booth-Rea, Guillermo; Ranero, Cesar R.; Grevemer, Ingo

    2016-04-01

    The Mediterranean Sea desiccated ~5.96 million years ago when it became isolated from the world oceans during the Messinian salinity crisis. This event permitted the exchange of terrestrial biota between Africa and Iberia contributing to the present rich biodiversity of the Mediterranean region. The cause chocking the Mediterranean has been proposed to be tectonic uplift and dynamic topography but the driving mechanism still remains debated. We present a new wide-angle seismic profile that provides a detailed image of the thickness and seismic velocity distribution of the crust in the eastern Alboran basin. The velocity model shows a characteristic structure of a subduction-related volcanic arc with a high-velocity lower crust and a 16-18 km total-thickness igneous crust that magmatic accreted mostly between ~10-6 Ma across the eastern Alboran basin. Estimation of the isostatically corrected depth of the arc crust taking into account the original thermal structure and sediment-loading subsidence since 6 Ma places a large area of the eastern Alboran basin above sea level at the time. This estimation is supported by geophysical data showing subaereal erosional unconformities for that time. This model may explain several up-to-now-disputed features of the Messinian salinity crisis, including: the progressive isolation of the Mediterranean since 7.1 Ma with the disappearance of open marine taxa, the existence of evaporites mostly to the east of the volcanic arc, the evidence that the Gibraltar straits were not a land bridge offered by continuous Messinian open marine sediments at ODP site 976 in the western Alboran basin, the importance of southeastern Iberia and North Africa as centres of biota diversification since before the salinity crisis, and patterns of speciation irradiating from SE Iberia and the eastern Rif in some taxons.

  18. Geochemistry of the Ophiolite and Island-Arc Volcanic Rocks in the Mianxian-Lueyang Suture Zone,Southern Qinling and Their Tectonic Significance

    Institute of Scientific and Technical Information of China (English)

    1999-01-01

    Ultrabasic rocks in the Mianxian-Lueyang ophiolitic melange zone include harzburgite and dunite which exhibit LREE depletion with remarkable positive Eu anomaly.The diabase dike swarm shows LREE enrichment but slightly negative Eu anomaly.Metamorphosed volcanic rocks can be divided into two groups in terms of their REE geochemistry and trace element ratios of Ti/V,Th/Ta,Th/Yb and Ta/Yb.One is ths MORB-type basalt with LREE depletion,representing the fragments of oceanic crust and implying an association of the MORB-type ophiolite and an ancient ocean basin between the Qinling and Yangtze plates during the Middle Paleozoic-Early Mesozoic era.The oter comprises the island-arc volcanic rocks including tholeiitic basalt and a large amount of calc-alkaline intermediate-acic volcanic rock,which could not be the component of the ancient oceanic crust but the result of magmatism at the continental margin.This indicates that the Mianxian-Lueyang limited ocean basin had undergone a whole process of development,evolution and vanishing from Devonian-Cretaceous to Permian.And the Qinling area had becone an independent lithospheric microplate,on the southern side of which there were exhibited the tectonic characteristics of active continental margins during the Late Paleozoic-Early Mesozoic.That is to say.the Qinling cannot be simply considered as a result of collision between the Yangtze and North China plates.

  19. Depositional model of Permian Luodianian volcanic island and its impact on the distribution of fusulinid assemblage in southern Qinghai, Northwest China

    Institute of Scientific and Technical Information of China (English)

    NIU ZhiJun; XU AnWu; WANG JianXiong; DUAN QiFa; ZHAO XiaoMing; YAO HuaZhou

    2008-01-01

    Pan-riftizational tectonic activity reached climax at Luodianian (Permian) in the East Tethyan Domain,Qinghai-Tibet Plateau. Because of eruptive volcanics and influence of terrigenous materials, a complex volcanic-sedimentary landform formed on the sea floor in southern Qinghai. Four sedimentary facies types were recognized based on detailed field mapping. Spatially, platform facies volcanic-limestone type was located at the center belt approximately trending NWW, surrounded by shallow water slope facies tuff/tuffite type at the two flanks and deep water slope facies breccia/calcirudite at the most outside. The depression facies sandstone-mudstone type, which comprised mainly mudstone, deposited between volcanic islands (platform facies volcanic-limestone type). Based on the field mapping and stratigraphic section data, seven rift-related sedimentary facies were recognized and a depositional model for volcanic island was proposed. It is revealed that some volcanic island chain formed quickly and intermittently in the Qamdo Block during violent eruption, and small carbonate reef, shoal,platform occurred above or on edge of volcanic island, and some slope sedimentary facies surrounded volcano island chain during dormant period of volcanic activities. Three types of fusulinid assemblages were distinguished in the carbonate rocks, which deposited in varied positions of a palaeo-volcanic island: (1) Misellina- Schwagerina assemblage occurred above or on edge of volcanic island, (2) Parafusulina assemblage was located at restricted depression facies among volcanic islands or carbonate platform, and (3) the reworked Pseudofusulina-Schwagerina assemblage occurred at slope facies near margin of volcanic island, which originally deposited in the shallow-water carbonate platform, then collapsed along the volcanic island margin with fusulinid-bearing grain-supported carbonate conglomerate or calcirudite, and finally re-deposited on the deeper slope. The sedimentary sequence

  20. Depositional model of Permian Luodianian volcanic island and its impact on the distribution of fusulinid assemblage in southern Qinghai,Northwest China

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    Pan-riftizational tectonic activity reached climax at Luodianian (Permian) in the East Tethyan Domain, Qinghai-Tibet Plateau. Because of eruptive volcanics and influence of terrigenous materials, a complex volcanic-sedimentary landform formed on the sea floor in southern Qinghai. Four sedimentary facies types were recognized based on detailed field mapping. Spatially, platform facies volcanic-limestone type was located at the center belt approximately trending NWW, surrounded by shallow water slope facies tuff/tuffite type at the two flanks and deep water slope facies breccia/calcirudite at the most outside. The depression facies sandstone-mudstone type, which comprised mainly mudstone, de-posited between volcanic islands (platform facies volcanic-limestone type). Based on the field map-ping and stratigraphic section data, seven rift-related sedimentary facies were recognized and a depo-sitional model for volcanic island was proposed. It is revealed that some volcanic island chain formed quickly and intermittently in the Qamdo Block during violent eruption, and small carbonate reef, shoal, platform occurred above or on edge of volcanic island, and some slope sedimentary facies surrounded volcano island chain during dormant period of volcanic activities. Three types of fusulinid assemblages were distinguished in the carbonate rocks, which deposited in varied positions of a palaeo-volcanic island: (1) Misellina-Schwagerina assemblage occurred above or on edge of volcanic island, (2) Para-fusulina assemblage was located at restricted depression facies among volcanic islands or carbonate platform, and (3) the reworked Pseudofusulina-Schwagerina assemblage occurred at slope facies near margin of volcanic island, which originally deposited in the shallow-water carbonate platform, then collapsed along the volcanic island margin with fusulinid-bearing grain-supported carbonate con-glomerate or calcirudite, and finally re-deposited on the deeper slope. The sedimentary

  1. Complex Indigenous Organic Matter Embedded in Apollo 17 Volcanic Black Glass Surface Deposits

    Science.gov (United States)

    Thomas-Keprta, Kathie L.; Clemett, S. J.; Ross, D. K.; Le, L.; Rahman, Z.; Gonzalez, C.; McKay, D. S.; Gibson, E. K.

    2013-01-01

    Papers presented at the first Lunar Science Conference [1] and those published in the subsequent Science Moon Issue [2] reported the C content of Apollo II soils, breccias, and igneous rocks as rang-ing from approx.50 to 250 parts per million (ppm). Later Fegley & Swindle [3] summarized the C content of bulk soils from all the Apollo missions as ranging from 2.5 (Apollo 15) to 280 ppm (Apollo 16) with an overall average of 124+/- 45 ppm. These values are unexpectedly low given that multiple processes should have contributed (and in some cases continue to contribute) to the lunar C inventory. These include exogenous accretion of cometary and asteroidal dust, solar wind implantation, and synthesis of C-bearing species during early lunar volcanism. We estimate the contribution of C from exogenous sources alone is approx.500 ppm, which is approx.4x greater than the reported average. While the assessm ent of indigenous organic matter (OM) in returned lunar samples was one of the primary scientific goals of the Apollo program, extensive analysis of Apollo samples yielded no evidence of any significant indigenous organic species. Furthermore, with such low concentrations of OM reported, the importance of discriminating indigenous OM from terrestrial contamination (e.g., lunar module exhaust, sample processing and handling) became a formidable task. After more than 40 years, with the exception of CH4 [5-7], the presence of indigenous lunar organics still remains a subject of considerable debate. We report for the first time the identification of arguably indigenous OM present within surface deposits of black glass grains collected on the rim of Shorty crater during the Apollo 17 mission by astronauts Eugene Cernan and Harrison Schmitt.

  2. Recording the transition from flare-up to steady-state arc magmatism at the Purico-Chascon volcanic complex, northern Chile

    Science.gov (United States)

    Burns, Dale H.; de Silva, Shanaka L.; Tepley, Frank; Schmitt, Axel K.; Loewen, Matthew W.

    2015-07-01

    The long-term evolution of continental magmatic arcs is episodic, where a few transient events of high magmatic flux or flare-ups punctuate the low-flux magmatism or "steady state" that makes up most of the arc history. How this duality manifests in terms of differences in crustal architecture, magma dynamics and chemistry, and the time scale over which transitions occur is poorly known. Herein we use multiscale geochemical and isotopic characteristics coupled with geothermobarometry at the Purico-Chascon Volcanic Complex (PCVC) in the Central Andes to identify a transition from flare-up to steady state arc magmatism over ∼800 kyr during which significant changes in upper crustal magmatic dynamics are recorded. The PCVC is one of the youngest volcanic centers related to a 10-1 Ma ignimbrite flare-up in the Altiplano-Puna Volcanic Complex of the Central Andes. Activity at the PCVC initiated 0.98 ± 0.03 Ma with the eruption of a large 80-100 km3 crystal-rich dacite ignimbrite. High, restricted 87Sr/86Sr isotope ratios between 0.7085 and 0.7090 in the bulk rock and plagioclase crystals from the Purico ignimbrite, combined with mineral chemistry and phase relationships indicate the dacite magma accumulated and evolved at relatively low temperatures around 800-850 °C in the upper crust at 4-8 km depth. Minor andesite pumice erupted late in the ignimbrite sequence records a second higher temperature (965 °C), higher pressure environment (17-20 km), but with similar restricted radiogenic bulk rock 87Sr/86Sr = 0.7089-0.7091 to the dacites. The compositional and isotopic characteristics of the Purico ignimbrite implicate an extensive zone of upper crustal mixing, assimilation, storage and homogenization (MASH) between ∼30 and 4 km beneath the PCVC ∼1 Ma. The final eruptions at the PCVC environments; an upper crustal environment identical to that recorded in the Purico ignimbrite, and a second deeper, ∼15-20 km depth, higher temperature (∼922-1001

  3. Characterization of geothermal paleosystem in the Lesser Antilles volcanic arc: structural, petrographic, thermodynamic and petrophysics analysis of Terre-de-Haut (Les Saintes archipelago, Lesser Antilles)

    Science.gov (United States)

    Favier, Alexiane; Navelot, Vivien; Verati, Chrystèle; Lardeaux, Jean-Marc; Corsini, Michel; Diraison, Marc; Géraud, Yves; Mercier de Lépinay, Jeanne; Munschy, Marc

    2017-04-01

    This survey takes part in the GEOTREF project (high enthalpy geothermal energy in fractured reservoirs), supported by the French government program "Investments for the future". The program focuses on the exploration of geothermal resource in the Lesser Antilles volcanic arc. An exclusive license has been issued in the Vieux-Habitants area (Basse-Terre, Guadeloupe) to carry on the development of high-temperature geothermal energy in this active volcanic region. The deep geothermal reservoir on the Basse-Terre island could be characterized in exhumed paleosystems. The reference paleosystem in the Guadeloupe archipelago is located in Terre-de-Haut. Four major fault directions have been highlighted N000-N020, N050-N070, N090-N110 and N130-N140. Field observations emphasize three major cleavage directions overlaying the fault systems: N035-N060, N080-N110, N145-N165. Volcanic rocks affected by cleavage display several metamorphic transformation grades. The more transformed calc-alkaline rocks are located at the intersection of several cleavage directions. Mineralogical transformations due to metamorphism and surimposed fractures are also responsible for strong changes of petrophysical properties. In comparison with the reference protolith of andesitic lava flows outcropping in Vieux-Habitants, which have porosity and permeability lower than 5 % and 10-15 m2, andesites of Terre-de-Haut have better reservoir properties with connected porosity and permeability higher than 15 % and 10-14-10-15 m2 respectively. Thermodynamic modelling based on petrography and chemical composition of the most transformed rocks highlights a steady state mineral assemblage between 0.25 - 1.5 kbar and 350 - 450 ˚ C. It corresponds to a geothermal gradient higher than 120 to 150˚ C/km. This is consistent with temperatures measured in Bouillante wells. However, this geothermal gradient is notably higher to a usual volcanic arc conductive gradient estimated to 70-100˚ C/km. It can be explained

  4. Optical and Surface Characteristics of Mg-Doped GaAs Nanocrystalline Thin Film Deposited by Thermionic Vacuum Arc Technique

    Science.gov (United States)

    Pat, Suat; Özen, Soner; Şenay, Volkan; Korkmaz, Şadan

    2017-01-01

    Magnesium (Mg) is the most promising p-type dopant for gallium arsenide (GaAs) semiconductor technology. Mg-doped GaAs nanocrystalline thin film has been deposited at room temperature by the thermionic vacuum arc technique, a rapid deposition method for production of doped GaAs material. The microstructure and surface and optical properties of the deposited sample were investigated by x-ray diffraction analysis, scanning electron microscopy, energy-dispersive x-ray spectroscopy, atomic force microscopy, ultraviolet-visible spectrophotometry, and interferometry. The crystalline direction of the deposited sample was determined to be (220) plane and (331) plane at 44.53° and 72.30°, respectively. The Mg-doped GaAs nanocrystalline sample showed high transmittance.

  5. Microstructure and mechanical properties of nanocomposite coatings deposited by cathodic arc evaporation

    Directory of Open Access Journals (Sweden)

    K. Lukaszkowicz

    2010-09-01

    Full Text Available Purpose: The main aim of the this research was the investigation of the structure and the mechanical properties of the nanocomposite TiAlSiN, CrAlSiN, AlTiCrN coatings deposited by cathodic arc evaporation method onto hot work tool steel substrate.Design/methodology/approach: The surfaces’ topography and the structure of the PVD coatings were observed on the scanning electron microscopy. Diffraction and thin film structure were tested with the use of the transmission electron microscopy. The microhardness tests were made on the dynamic ultra-microhardness tester. Tests of the coatings’ adhesion to the substrate material were made using the scratch test.Findings: It was found that the structure of the PVD coatings consisted of fine crystallites, while their average size fitted within the range of 11-25 nm, depending on the coating type. The coatings demonstrated columnar structure and dense cross-section morphology as well as good adhesion to the substrate. The critical load LC2 lies within the range of 46-54 N, depending on the coating and substrate type. The coatings demonstrate a high hardness (~40 GPa.Practical implications: In order to evaluate with more detail the possibility of applying these surface layers in tools, further investigations should be concentrated on the determination of the thermal fatigue resistance of the coatings. The very good mechanical properties of the nanocomposite coatings make them suitable in industrial applications.Originality/value: The investigation results will provide useful information to applying the nanocomposite coatings for the improvement of mechanical properties of the hot work tool steels.

  6. The conjunction of factors that lead to formation of giant gold provinces and deposits in non-arc settings

    Science.gov (United States)

    Groves, David I.; Goldfarb, Richard J.; Santosh, M.

    2016-01-01

    It is quite evident that it is not anomalous metal transport, nor unique depositional conditions, nor any single factor at the deposit scale, that dictates whether a mineral deposit becomes a giant or not. A hierarchical approach thus is required to progressively examine controlling parameters at successively decreasing scales in the total mineral system to understand the location of giant gold deposits in non-arc environments. For giant orogenic, intrusion-related gold systems (IRGS) and Carlin-type gold deposits and iron oxide-copper-gold (IOCG) deposits, there are common factors among all of these at the lithospheric to crustal scale. All are sited in giant gold provinces controlled by complex fundamental fault or shear zones that follow craton margins or, in the case of most Phanerozoic orogenic giants, define the primary suture zones between tectonic terranes. Giant provinces of IRGS, IOCG, and Carlin-type deposits require melting of metasomatized lithosphere beneath craton margins with ascent of hybrid lamprophyric to granitic magmas and associated heat flux to generate the giant province. The IRGS and IOCG deposits require direct exsolution of volatile-rich magmatic-hydrothermal fluids, whereas the association of such melts with Carlin-type ores is more indirect and enigmatic. Giant orogenic gold provinces show no direct relationship to such magmatism, forming from metamorphic fluids, but show an indirect relationship to lamprophyres that reflect the mantle connectivity of controlling first-order structures.

  7. Chemical signature of two Permian volcanic ash deposits within a bentonite bed from Melo, Uruguay

    Directory of Open Access Journals (Sweden)

    Liane M. Calarge

    2006-09-01

    Full Text Available A Permian bentonite deposit at Melo, Uruguay is composed of a calcite-cemented sandstone containing clay pseudomorphs of glass shards (0-0.50 m overlying a pink massive clay deposit (0.50-2.10m. The massive bed is composed of two layers containing quartz and smectite or pure smectite respectively. The smectite is remarkably homogeneous throughout the profile: it is a complex mixed layer composed of three layer types whose expandability with ethylene glycol (2EG 1EG or 0EG sheets in the interlayer zone which correspond to low-, medium- and high-charge layers respectively varies with the cation saturating the interlayer zone. The smectite homogeneity through the profile is the signature of an early alteration process in a lagoonal water which was over saturated with respect to calcite. Compaction during burial has made the bentonite bed a K-depleted closed system in which diagenetic illitization was inhibited. Variations in major, REE and minor element abundances throughout the massive clay deposit suggest that it originated from two successive ash falls. The incompatible element abundances are consistent with that of a volcanic glass fractionated from a rhyolite magma formed in a subduction/collision geological context.Um depósito Permiano de bentonita em Melo, Uruguai,é composto por um arenito com cimento calcítico contendo pseudomorfos de argila sobre detritos vítreos(0-0.50 m superpostos a um deposito maciço de argila rosado (0.50-2.10 m. A camada maciça é composta por dois níveis contendo quartzo e esmectita ou esmectita pura, respectivamente. A homogeneidade de esmectita ao longo do perfil é notável: trata-se de um interestratificado composto de três tipos de camadas, cuja expansibilidade com etileno-glicol (folhas 2EG, 1EG ou 0EG na zona interfoliar correspondentes a camadas com baixa, média e alta carga, respectivamente variam com o tipo de cátion que satura a zona interfoliar. A homogeneidade da esmectita ao longo do perfil

  8. Cathodic arcs

    OpenAIRE

    Anders, Andre

    2003-01-01

    Cathodic arc plasma deposition has become the technology of choice for hard, wear and corrosion resistant coatings for a variety of applications. The history, basic physics of cathodic arc operation, the infamous macroparticle problem and common filter solutions, and emerging high-tech applications are briefly reviewed. Cathodic arc plasmas stand out due to their high degree of ionization, with important consequences for film nucleation, growth, and efficient utilization of substrate bia...

  9. Geochemistry and zircon U-Pb-Hf isotopes of Early Paleozoic arc-related volcanic rocks in Sonid Zuoqi, Inner Mongolia: Implications for the tectonic evolution of the southeastern Central Asian Orogenic Belt

    Science.gov (United States)

    Chen, Yan; Zhang, Zhicheng; Li, Ke; Yu, Haifei; Wu, Tairan

    2016-11-01

    An Early Paleozoic acid volcanic sequence has been recently detected southeast of Sonid Zuoqi in central Inner Mongolia to constrain the tectonic evolution of the Central Asian Orogenic Belt in this area. First, the volcanic rocks have zircon U-Pb ages of 439-445 Ma. They are characterized by (a) a high silica content, moderate alkali content and low iron content; (b) enrichment in light rare earth elements, depletion of heavy rare earth elements, and negative Eu anomalies; and (c) negative Nb, Ta, and Ti anomalies. Finally, the volcanic samples yield εHf(t) values of - 4.7 to + 9.2 with TDM2 ages of 835-1724 Ma. For petrogenesis, they were possibly arc derived, from predominant juvenile materials with subordinate ancient continental crust. Combined with previous studies, the Early Paleozoic Sonid Zuoqi arc magmatism can be divided into three stages: a primitive arc stage represented by 464-490 Ma low-K, calcic granitoids; a normal continental arc stage represented by 439-445 Ma medium-K, calcic to calcic-alkalic plutons and volcanic rocks and a syn-collisional stage represented by 423-424 Ma high-K granites. Furthermore, the timing and tectonic settings of the above magmatic rocks show similarities to those in Xilinhot and other areas of the northern Early to Mid-Paleozoic orogenic belt (NOB), although the rock assemblies and their proportions vary more or less in different areas. Accordingly, the NOB that formed on this arc was probably attributed to the northward subduction of the Paleo-Asian Ocean beginning at 500 Ma, which experienced this type of arc development and was terminated by a soft collision before the Late Devonian.

  10. Recognizing subtle evidence for silicic magma derivation from petrochemically-similar arc crust: Isotopic and chemical evidence for the bimodal volcanic series of Gorely Volcanic Center, Kamchatka, Russia

    Science.gov (United States)

    Seligman, A. N.; Bindeman, I. N.; Ellis, B. S.; Ponomareva, V.; Leonov, V.

    2012-12-01

    The Kamchatka Peninsula is home to some of the most prolific subduction related volcanic activity in the world. Gorely caldera and its central volcano are located in the rear of its currently active Eastern Volcanic Front. Recent work determined the presence of explosive ignimbrite eruptions sourced from Gorely volcano during the Pleistocene. We studied 32 eruptive units, including tephrochronologically-dated Holocene tephra, stratigraphically-arranged ignimbrites, as well as pre- and post-caldera lavas. We analyzed oxygen isotope ratios of pyroxene and plagioclase grains by laser fluorination, and major and trace element compositions of whole rocks. In addition, we determined 87Sr/86Sr and 143Nd/144Nd ratios of caldera-forming ignimbrite eruptions. Chemical compositions show that Gorely eruptive units range from basalt to basaltic andesite in the "Pra-Gorely" stages prior to caldera formation and the modern Gorely stages forming its current edifice. In contrast, eruptive material from earlier ignimbrites exposed at Opasny Ravine consists primarily of dacite. Whole rock analyses for Gorely indicate that silicic rocks and ignimbrites volumetrically dominate all other products, forming separate bimodal peaks in our SiO2-frequency diagram. In addition, trace element concentrations and ratios define two trends, one for more silicic and another for more mafic material. δ18Omelt values range from a low of 4.85 up to 6.22‰, where the lowest value was found in the last caldera forming eruption, suggesting incorporation of hydrothermally-altered material from earlier eruptions. 87Sr/86Sr and 143Nd/144Nd ratios range from 0.70328 to 0.70351 and from 0.51303 to 0.51309 respectively, with higher and more diverse values being characteristic of earlier ignimbrite units; again suggesting incorporation of surrounding crustal material. In contrast to these results, MELTS modeling using a variety of likely primitive basalts from Gorely shows it is possible to obtain silicic

  11. Depositional conditions of the coal-bearing Hirka Formation beneath late Miocene explosive volcanic products in NW central Anatolia, Turkey

    Energy Technology Data Exchange (ETDEWEB)

    Sener, M. [Nigde University, Nigde (Turkey). Dept. of Geology

    2007-04-15

    This work focuses on the relationship between the coal deposition and explosive volcanism of the Miocene basin, NW central Anatolia, Turkey. The coal-bearing Hirka Formation was deposited over the Galatian Andesitic Complex and/or massive lagoonal environments during the Miocene. The investigated lignite is a high ash (from 32 to 58%) and sulphur (from 1.43 to 3.03%) lignite which is petrographically characterised by a high humunite content. The mineral matter of the studied lignite samples is made up of mainly clay minerals (illite-smectite and kaolinite), plagioclase and quartz in Bolu coal field, clay minerals (illite-smectite, smectite and illite), quartz, calcite, plagioclase and gypsum in Seben coal field, quartz, K-feldspar, plagioclase and clay minerals (kaolinite and illite) in Kibriscik, and dolomite, quartz, clinoptilolite, opal CT and gypsum in Camhdere coal field. The differences in these four types of lignite with specific mineralogical patterns may be due to the explosive volcanic events and depositional conditions which changed from one coal field to the others. There is a zonation from SW to SE in the studied area for zeolites. Carbonate minerals are commonly calcite in Seben and Kibriscik coal fields. In Bolu, coal samples are devoid of calcite and dolomite. These analyses show that there is an increase in the amount of Mg and a decrease in the amount of Na from the northwestern part to the southern part in the study area.

  12. Effects of filtered cathodic vacuum arc deposition (FCVAD) conditions on photovoltaic TiO{sub 2} films

    Energy Technology Data Exchange (ETDEWEB)

    Aramwit, C. [Plasma and Beam Physics Research Facility, Department of Physics and Materials Science, Faculty of Science, Chiang Mai University, Chiang Mai 50200 (Thailand); Intarasiri, S. [Science and Technology Research Institute, Chiang Mai University, Chiang Mai 50200 (Thailand); Thailand Center of Excellence in Physics, Commission on Higher Education, 328 Si Ayutthaya Road, Bangkok 10400 (Thailand); Bootkul, D. [Thailand Center of Excellence in Physics, Commission on Higher Education, 328 Si Ayutthaya Road, Bangkok 10400 (Thailand); Department of General Science, Faculty of Science, Srinakharinwirot University, Bangkok 10110 (Thailand); Tippawan, U. [Plasma and Beam Physics Research Facility, Department of Physics and Materials Science, Faculty of Science, Chiang Mai University, Chiang Mai 50200 (Thailand); Thailand Center of Excellence in Physics, Commission on Higher Education, 328 Si Ayutthaya Road, Bangkok 10400 (Thailand); Supsermpol, B.; Seanphinit, N. [Department of General Science, Faculty of Science, Srinakharinwirot University, Bangkok 10110 (Thailand); Western Digital Thailand Co. Ltd., Ayutthaya 13160 (Thailand); Ruangkul, W. [Thailand Center of Excellence in Physics, Commission on Higher Education, 328 Si Ayutthaya Road, Bangkok 10400 (Thailand); Yu, L.D., E-mail: yuld@thep-center.org [Plasma and Beam Physics Research Facility, Department of Physics and Materials Science, Faculty of Science, Chiang Mai University, Chiang Mai 50200 (Thailand); Thailand Center of Excellence in Physics, Commission on Higher Education, 328 Si Ayutthaya Road, Bangkok 10400 (Thailand)

    2014-08-15

    Highlights: • Titanium dioxide films were synthesized using the FCVAD technique. • Various FCVAD conditions were tested. • The TiO{sub 2} films were characterized. • The FCVAD condition effects on the film characteristics were studied. • The O{sub 2} pressure had the most important effect on the film quality. - Abstract: Titanium dioxide (TiO{sub 2}) films for photovoltaic applications were synthesized using filtered cathodic vacuum arc deposition (FCVAD) technique. Various deposition conditions were tested for an optimal film formation. The conditions included the oxygen (O{sub 2}) pressure which was varied from a base pressure 10{sup −5} to 10{sup −4}, 10{sup −3}, 10{sup −2} and 10{sup −1} Torr, sample holder bias varied using 0 or −250 V, deposition time varied from 10, 20 to 30 min, and deposition distance varied from 1 to 3 cm. The deposited films were also annealed and compared with unannealed ones. The films under various conditions were characterized using optical microscopy, scanning electron microscopy (SEM), atomic force microscopy (AFM), energy-dispersive X-ray spectroscopy (EDS) and Raman spectroscopy techniques. The film transparency increased and thickness decreased to a nanoscale with increasing of the O{sub 2} pressure. The transparent deposited films contained stoichiometric titanium and oxygen under the medium O{sub 2} pressure. The as-deposited films were TiO{sub 2} containing some rutile but no anatase which needed annealing to form.

  13. The pre-Kos Plateau Tuff Volcanic Rocks on Kefalos Peninsula (Kos Island, Dodecanese, Greece): Crescendo to the Largest Eruption of the Modern Aegean Arc

    Science.gov (United States)

    Bachmann, O.; Schnyder, C.

    2006-12-01

    Young volcanic rocks (K-Ar ages of 3 to 0.5 Ma) from the Kefalos Peninsula (Kos Island, Dodecanese, Greece) erupted prior to the voluminous (>60 km\\ 3) Kos Plateau Tuff (KPT; Ar-Ar age of 0.16 Ma) were studied in order to better define the conditions that led to the paroxysmal eruption of the modern Aegean Arc. Two different whole-rock compositions were sampled on Kefalos peninsula; dacites (63-65 wt% SiO2) and rhyolites (75-77 wt% SiO2). Kefalos dacites are crystal-rich (>40% crystals), show high Sr-Ba contents compared to other continental arcs, and have "adakitic" Sr/Y ratios (>40). Kefalos rhyolites are typical high- SiO2 arc magmas, similar in composition and mineralogy to the KPT, but displaying lower crystallinities (30% in most of the KPT). The high Sr/Y ratios of the dacites is surprising in an area where the subducting slab is not particularly hot and the continental crust relatively thin (~30 km). If the low Y and high Sr-Ba contents result from the fact that magma formed deep enough to supress plagioclase and have garnet present, dacite magma generation must have occurred in the mantle. There is geochemical and mineralogical evidence for the Kefalos and KPT rhyolites being generated by fractional crystallization from magmas similar to the Kefalos dacites. However, the few distinctions between KPT and Kefalos rhyolites (KPT is more voluminous, contains more crystals, has lower whole-rock U and Th contents, and lower MgO-SiO2, but higher Al2O3-FeOtot in biotite) suggest slightly different conditions in the magma chambers. These observations, together with increasing explosivity of the volcanic products from ~3 Ma to 0.16 Ma, may indicate that the build-up to the large KPT eruption could be the result of an increase in magmatic water input in the system through time.

  14. Cathodic micro-arc electro-deposition of ZrO2 coatings in an aqueous solution containing colloidal particles

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    By a novel technique-cathodic micro-arc electro-deposition (CMED), ZrO2 coatings were deposited on an FeCrAl alloy. Experimental results show that the necessary conditions for obtaining ZrO2 coatings are to apply a pulse peak voltage over a critical value and add moderate amounts of ZrO2 colloidal particles and Zr(NO3)4 in the aqueous solution. The as-deposited coatings are porous because hydrogen, water, and other vapors are generated and released from the coatings to the solution during the spark reaction. The coatings contain monoclinic and tetragonal crystalline ZrO2with certain degree of amorphous structure. The processing parameters and mechanism of CMED were discussed.

  15. The Quetzalapa Pumice: a voluminous late Pleistocene rhyolite deposit in the eastern Trans-Mexican Volcanic Belt

    Science.gov (United States)

    Rodríguez, Sergio-Raúl; Siebe, Claus; Komorowski, Jean-Christophe; Abrams, Michael

    2002-03-01

    The study area is located in the east part of the Trans-Mexican Volcanic Belt, in the Las Cumbres Volcanic Complex (LCVC) which lies between two large stratovolcanoes: Pico de Orizaba (5700 m a.s.l.) to the south, and Cofre de Perote (4200 m a.s.l.) to the NNE. The most conspicuous structure of the LCVC is a 4-km-diameter circular crater with a dacitic dome in the center, which constitutes the remains of a destroyed stratovolcano. The Quetzalapa Pumice (QP) was produced by a plinian eruption that was dated by the 14C method at 20 000 yr. BP. The eruptive sequence consists predominantly of pumice fall deposits and scarce intra-plinian pyroclastic flow deposits, which crop out on the west flank of the LCVC. The absence of post-plinian ignimbrite deposits is striking. The deposits are well sorted, clast-supported with reverse grading at the base, with a medium to high accessory lithics content. The maximum average thickness of the deposit in the proximal areas is about 15 m and has been divided into three members: the Basal Member (BM), 2 m thick with four submembers (BMf 1, BMf 2, BMf 3, and BMafl), the Intermediate Member (IM), 10 m thick with two submembers (IMpf and IMaf), and the Upper Member (UM), 3 m thick with four submembers (UMpl, UMsdf, UMwaf, and UMpls). The predominant component of the fall deposits is a white, highly vesiculated pumice with 71% SiO 2 content. Plagioclase is the most abundant mineral followed by 1-3-mm-long biotite phenocrysts. The accessory lithics are lavas mostly of andesitic composition. Their abundance increases toward the uppermost levels of the sequence. We calculate a minimum volume of 8.4 km 3 (2.22 km 3 dense rock equivalent), for the entire QP deposit. Isopach and isopleth maps show that the IM deposit has an elongated distribution with a NNE-SSW direction, whereas the UM deposit has a circular distribution. We estimate a maximum eruptive column height for the IM of 20 km. Field studies and isopach and isopleth maps indicate

  16. Geophysical imaging of the lacustrine sediments deposited in the La Calderilla Volcanic Caldera (Gran Canaria Island, Spain) for paleoclimate research

    Science.gov (United States)

    Himi, Mahjoub; Rodríguez-González, Alejandro; Criado, Constantino; Tapias, Josefina C.; Ravazzi, Cesare; Pérez-Torrado, Francisco; Casas, Albert

    2016-04-01

    The discovery of well-preserved maar structures is important not only for studying the eruptive activity and formation of volcanoes, but also for paleoclimate research, since laminated maar lake sediments may contain very detailed archives of climate and environmental history. Maars are a singular type of volcanic structure generated by explosive phreatomagmatic eruptions as a result of interaction between rising magma and groundwater. This kind of structures are characterised by circular craters, often filled with water and/or lacustrine sediments and surrounded by a ring of pyroclastic deposits.Recently a borehole was drilled at the bottom of La Calderilla volcanic complex which penetrated about 8.7 m in its sedimentary sequence and paleobotanical study has supplied the first evidence of paleoenvironmental evolution during the Holocene on the Gran Canaria Island. This survey, however, did not penetrate into the substrate because the total thickness of the sedimentary fill was unknown. Since the age of formation of La Calderilla volcanic complex based on K/Ar dating is about 85,000 years (Upper Pleistocene), the possibility of its sedimentary fill extends beyond of the Holocene is extremely attractive, since, for example, there are few paleoenvironmental data regarding how much the last glaciation that affected the Canary Islands. In these circumstances, the knowledge of the total thickness of the lacustrine sediments is crucial to design a deeper borehole in the next future. Therefore, the subsurface characterisation provided by geophysics is essential for determining thickness and geometry of the sedimentary filling. Multielectrode ERT method was used to obtain five 2-D resistivity cross-sections into La Calderilla volcanic caldera. An Iris Syscal Pro resistivity system with 48 electrodes connected to a 94 m long cable (2m electrode spacing) in Wenner-Schlumberger configuration for an investigation depth of about 20 m. Data quality (q 8000 Ω.m) that can be

  17. Cascadia subducting plate fluids channelled to fore-arc mantle corner: ETS and silica deposition

    Science.gov (United States)

    Hyndman, R. D.; McCrory, P. A.; Wech, A.; Kao, H.; Ague, J.

    2015-06-01

    In this study we first summarize the constraints that on the Cascadia subduction thrust, there is a 70 km gap downdip between the megathrust seismogenic zone and the Episodic Tremor and Slip (ETS) that lies further landward; there is not a continuous transition from unstable to conditionally stable sliding. Seismic rupture occurs mainly offshore for this hot subduction zone. ETS lies onshore. We then suggest what does control the downdip position of ETS. We conclude that fluids from dehydration of the downgoing plate, focused to rise above the fore-arc mantle corner, are responsible for ETS. There is a remarkable correspondence between the position of ETS and this corner along the whole margin. Hydrated mineral assemblages in the subducting oceanic crust and uppermost mantle are dehydrated with downdip increasing temperature, and seismic tomography data indicate that these fluids have strongly serpentinized the overlying fore-arc mantle. Laboratory data show that such fore-arc mantle serpentinite has low permeability and likely blocks vertical expulsion and restricts flow updip within the underlying permeable oceanic crust and subduction shear zone. At the fore-arc mantle corner these fluids are released upward into the more permeable overlying fore-arc crust. An indication of this fluid flux comes from low Poisson's Ratios (and Vp/Vs) found above the corner that may be explained by a concentration of quartz which has exceptionally low Poisson's Ratio. The rising fluids should be silica saturated and precipitate quartz with decreasing temperature and pressure as they rise above the corner.

  18. Massive Volcanic SO2 Oxidation and Sulphate Aerosol Deposition in Cenozoic North America

    Science.gov (United States)

    Volcanic eruptions release a large amount of sulphur dioxide (SO2) into the atmosphere. SO2 is oxidized to sulphate and can subsequently form sulphate aerosol, which can affect the Earth's radiation balance, biologic productivity and high-altitude ozone co...

  19. Cathodic arcs

    Energy Technology Data Exchange (ETDEWEB)

    Anders, Andre

    2003-10-29

    Cathodic arc plasma deposition has become the technology of choice for hard, wear and corrosion resistant coatings for a variety of applications. The history, basic physics of cathodic arc operation, the infamous macroparticle problem and common filter solutions, and emerging high-tech applications are briefly reviewed. Cathodic arc plasmas standout due to their high degree of ionization, with important consequences for film nucleation, growth, and efficient utilization of substrate bias. Industrial processes often use cathodic arc plasma in reactive mode. In contrast, the science of arcs has focused on the case of vacuum arcs. Future research directions include closing the knowledge gap for reactive mode, large area coating, linear sources and filters, metal plasma immersion process, with application in high-tech and biomedical fields.

  20. Volcanic and impact deposits of the Moon's Aristarchus Plateau: A new view from Earth-based radar images

    Science.gov (United States)

    Campbell, Bruce A.; Carter, Lynn M.; Hawke, B. Ray; Campbell, Donald B.; Ghent, Rebecca R.

    2008-02-01

    Lunar pyroclastic deposits reflect an explosive stage of thebasaltic volcanism that filled impact basins across the nearside.These fine-grained mantling layers are of interest for theirassociation with early mare volcanic processes, and as possiblesources of volatiles and other species for lunar outposts. Wepresent Earth-based radar images, at 12.6 and 70 cm wavelengths,of the pyroclastic deposit that blankets the Aristarchus Plateau.The 70 cm data reveal the outlines of a lava-flow complex thatcovers a significant portion of the plateau and appears to haveformed by spillover of magma from the large sinuous rille VallisSchröteri. The pyroclastics mantling these flows are heavilycontaminated with rocks 10 cm and larger in diameter. The 12.6cm data confirm that other areas are mantled by 20 m or lessof material, and that there are numerous patches of 2 cm andlarger rocks associated with ejecta from Aristarchus crater.Some of the radar-detected rocky debris is within the mantlingmaterial and is not evident in visible-wavelength images. Theradar data identify thick, rock-poor areas of the pyroclasticdeposit best suited for resource exploitation.

  1. Petrography and geochemistry of achnelithic tephra from Las Herrerías Volcano (Calatrava volcanic field, Spain): Formation of nephelinitic achneliths and post-depositional glass alteration

    Science.gov (United States)

    Carracedo-Sánchez, M.; Sarrionandia, F.; Arostegui, J.; Errandonea-Martin, J.; Gil-Ibarguchi, J. I.

    2016-11-01

    We present the results of a petrographic and geochemical study carried out on a layer of achnelithic tephra outcropping at the base of the volcanic cone of Las Herrerías (Miocene-Quaternary volcanic region of Campo de Calatrava, Spain). The tephra, with a composition of nephelinite and ash (volcanic maar lake. Afterwards, there was no more water circulation through the achnelithic tephra, which was sealed from water by overlying hydrovolcanic tuff deposits. It was this isolation that made possible the preservation of glass to the present day.

  2. Influence of deposition temperature and bias voltage on the crystalline phase of Er{sub 2}O{sub 3} thin films deposited by filtered cathodic arc

    Energy Technology Data Exchange (ETDEWEB)

    Adelhelm, Christoph, E-mail: christoph.adelhelm@ipp.mpg.de [Max-Planck-Institut fuer Plasmaphysik, Materials Research, EURATOM Association, Boltzmannstrasse 2, 85748 Garching (Germany); Pickert, Thomas [Max-Planck-Institut fuer Plasmaphysik, Materials Research, EURATOM Association, Boltzmannstrasse 2, 85748 Garching (Germany); Koch, Freimut, E-mail: freimut.koch@ipp.mpg.de [Max-Planck-Institut fuer Plasmaphysik, Materials Research, EURATOM Association, Boltzmannstrasse 2, 85748 Garching (Germany); Balden, Martin; Jahn, Stephan [Max-Planck-Institut fuer Plasmaphysik, Materials Research, EURATOM Association, Boltzmannstrasse 2, 85748 Garching (Germany); Rinke, Monika [Forschungszentrum Karlsruhe, Institute for Materials Research I, Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen (Germany); Maier, Hans [Max-Planck-Institut fuer Plasmaphysik, Materials Research, EURATOM Association, Boltzmannstrasse 2, 85748 Garching (Germany)

    2011-10-01

    Er{sub 2}O{sub 3} thin films on Eurofer steel substrates were produced by a filtered cathodic arc device, varying the substrate temperature (RT - 700 deg. C) and sample bias (0 to -450 V). The crystallographic phase was analyzed by X-ray diffraction and Raman spectroscopy. Deposition at {>=}600 deg. C without bias lead to solely formation of the cubic Er{sub 2}O{sub 3} phase. Thin films of the uncommon, monoclinic B-phase were prepared with a negative bias voltage of {>=}100 V at RT, and at temperatures {<=}500 deg. C for -250 V bias. The B-phase films exhibit a strongly textured film structure. Residual stress measurements show high compressive stress for B-phase films deposited at RT.

  3. The conjunction of factors that lead to formation of giant gold provinces and deposits in non-arc settings

    Institute of Scientific and Technical Information of China (English)

    David I. Groves; Richard J. Goldfarb; M. Santosh

    2016-01-01

    It is quite evident that it is not anomalous metal transport, nor unique depositional conditions, nor any single factor at the deposit scale, that dictates whether a mineral deposit becomes a giant or not. A hierarchical approach thus is required to progressively examine controlling parameters at successively decreasing scales in the total mineral system to understand the location of giant gold deposits in non-arc environments. For giant orogenic, intrusion-related gold systems (IRGS) and Carlin-type gold deposits and iron oxide-copper-gold (IOCG) deposits, there are common factors among all of these at the litho-spheric to crustal scale. All are sited in giant gold provinces controlled by complex fundamental fault or shear zones that follow craton margins or, in the case of most Phanerozoic orogenic giants, define the primary suture zones between tectonic terranes. Giant provinces of IRGS, IOCG, and Carlin-type deposits require melting of metasomatized lithosphere beneath craton margins with ascent of hybrid lamp-rophyric to granitic magmas and associated heat flux to generate the giant province. The IRGS and IOCG deposits require direct exsolution of volatile-rich magmatic-hydrothermal fluids, whereas the associa-tion of such melts with Carlin-type ores is more indirect and enigmatic. Giant orogenic gold provinces show no direct relationship to such magmatism, forming from metamorphic fluids, but show an indirect relationship to lamprophyres that reflect the mantle connectivity of controlling first-order structures. In contrast to their province scale similarities, the different giant gold deposit styles show contrasting critical controls at the district to deposit scale. For orogenic gold deposits, the giants appear to have formed by conjunction of a greater number of parameters to those that control smaller deposits, with resultant geometrical and lithostratigraphic complexity as a guide to their location. There are few giant IRGS due to their inferior fluid

  4. Nanostructured (Ti-Zr-NbN Coatings Obtained by Vacuum-arc Deposition Method: Structure and Properties

    Directory of Open Access Journals (Sweden)

    О.V. Maksakova

    2015-12-01

    Full Text Available In the article discusses the results of the deposition of nanostructured coatings obtained by vacuum arc deposition of cathode (Ti-Zr-Nb, and analyzes their structure, morphology, elemental composition, and tribological properties (friction, wear and adhesion. The structural analysis showed the formation of an FCC phase and BCC phase in a small amount (at a chamber pressure Р = 4×10 – 3 Тоrr. The results of tribological tests showed that the friction coefficient varies from 0.61 to 0.491, and Vickers hardness from 37 to 44.57 GPa when changing (increasing the pressure in the chamber. The analysis of the elements in the tracks of friction was studied.

  5. The effect of substrate bias on titanium carbide/amorphous carbon nanocomposite films deposited by filtered cathodic vacuum arc

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Xu, E-mail: zhangxu@bnu.edu.cn [Key Laboratory of Beam Technology and Material Modification of Ministry of Education, College of Nuclear Science and Technology, Beijing Normal University (China); Liang, Hong [Key Laboratory of Beam Technology and Material Modification of Ministry of Education, College of Nuclear Science and Technology, Beijing Normal University (China); Wu, Zhenglong [Analytical and Testing Center, Beijing Normal University (China); Wu, Xiangying; Zhang, Huixing [Key Laboratory of Beam Technology and Material Modification of Ministry of Education, College of Nuclear Science and Technology, Beijing Normal University (China)

    2013-07-15

    The titanium carbide/amorphous carbon nanocomposite films have been deposited on silicon substrate by filtered cathodic vacuum arc (FCVA) technology, the effects of substrate bias on composition, structures and mechanical properties of the films are studied by scanning electron spectroscopy, X-ray diffraction and X-ray photoelectron spectroscopy and nano-indentation. The results show that the Ti content, deposition rate and hardness at first increase and then decrease with increasing the substrate bias. Maximum hardness of the titanium carbide/amorphous carbon nanocomposite film is 51 Gpa prepared at −400 V. The hardness enhancement may be attributed to the compressive stress and the fraction of crystalline TiC phase due to ion bombardment.

  6. Cascadia subducting plate fluids channelled to fore-arc mantle corner: ETS and silica deposition

    Science.gov (United States)

    Hyndman, Roy D; McCrory, Patricia A.; Wech, Aaron; Kao, Han; Ague, Jay j

    2015-01-01

    In this study we first summarize the constraints that on the Cascadia subduction thrust, there is a 70 km gap downdip between the megathrust seismogenic zone and the Episodic Tremor and Slip (ETS) that lies further landward; there is not a continuous transition from unstable to conditionally stable sliding. Seismic rupture occurs mainly offshore for this hot subduction zone. ETS lies onshore. We then suggest what does control the downdip position of ETS. We conclude that fluids from dehydration of the downgoing plate, focused to rise above the fore-arc mantle corner, are responsible for ETS. There is a remarkable correspondence between the position of ETS and this corner along the whole margin. Hydrated mineral assemblages in the subducting oceanic crust and uppermost mantle are dehydrated with downdip increasing temperature, and seismic tomography data indicate that these fluids have strongly serpentinized the overlying fore-arc mantle. Laboratory data show that such fore-arc mantle serpentinite has low permeability and likely blocks vertical expulsion and restricts flow updip within the underlying permeable oceanic crust and subduction shear zone. At the fore-arc mantle corner these fluids are released upward into the more permeable overlying fore-arc crust. An indication of this fluid flux comes from low Poisson's Ratios (and Vp/Vs) found above the corner that may be explained by a concentration of quartz which has exceptionally low Poisson's Ratio. The rising fluids should be silica saturated and precipitate quartz with decreasing temperature and pressure as they rise above the corner.

  7. Morphology and microstructure evolution of Ti-50 at.% Al cathodes during cathodic arc deposition of Ti-Al-N coatings

    Science.gov (United States)

    Syed, Bilal; Zhu, Jianqiang; Polcik, Peter; Kolozsvari, Szilard; Hâkansson, Greger; Johnson, Lars; Ahlgren, Mats; Jöesaar, Mats; Odén, Magnus

    2017-06-01

    Today's research on the cathodic arc deposition technique and coatings therefrom primarily focuses on the effects of, e.g., nitrogen partial pressure, growth temperature, and substrate bias. Detailed studies on the morphology and structure of the starting material—the cathode—during film growth and its influence on coating properties at different process conditions are rare. This work aims to study the evolution of the converted layer, its morphology, and microstructure, as a function of the cathode material grain size during deposition of Ti-Al-N coatings. The coatings were reactively grown in pure N2 discharges from powder metallurgically manufactured Ti-50 at.% Al cathodes with grain size distribution averages close to 1800, 100, 50, and 10 μm, respectively, and characterized with respect to microstructure, composition, and mechanical properties. The results indicate that for the cathode of 1800 μm grain size the disparity in the work function among parent phases plays a dominant role in the pronounced erosion of Al, which yields the coatings rich in macro-particles and of high Al content. We further observed that a reduction in the grain size of Ti-50 at.% Al cathodes to 10 μm provides favorable conditions for self-sustaining reactions between Ti and Al phases upon arcing to form γ phase. The combination of self-sustaining reaction and the arc process not only result in the formation of hole-like and sub-hole features on the converted layer but also generate coatings of high Al content and laden with macro-particles.

  8. Depositional conditions of the coal-bearing Hirka Formation beneath Late Miocene explosive volcanic products in NW central Anatolia, Turkey

    Indian Academy of Sciences (India)

    Mehmet Şener

    2007-04-01

    This work focuses on the relationship between the coal deposition and explosive volcanism of the Miocene basin, NW central Anatolia, Turkey. The coal-bearing Hirka Formation was deposited over the Galatian Andesitic Complex and/or massive lagoonal environments during the Miocene. The investigated lignite is a high ash (from 32 to 58%) and sulphur (from 1.43 to 3.03%) lignite which is petrographically characterised by a high humunite content. The mineral matter of the studied lignite samples is made up of mainly clay minerals (illite–smectite and kaolinite), plagioclase and quartz in Bolu coal field, clay minerals (illite–smectite, smectite and illite), quartz, calcite, plagioclase and gypsum in Seben coal field, quartz, K-feldspar, plagioclase and clay minerals (kaolinite and illite) in Kıbrıscık, and dolomite, quartz, clinoptilolite, opal CT and gypsum in C¸ amlıdere coal field. The differences in these four types of lignite with specific mineralogical patterns may be due to the explosive volcanic events and depositional conditions which changed from one coal field to the others. There is a zonation from SW to SE in the studied area for zeolites such as Opal CT+smectite-clinoptilolite-analcime-K-feldspar. Carbonate minerals are commonly calcite in Seben and Kıbrıscık coal fields. In Bolu, coal samples are devoid of calcite and dolomite. These analyses show that there is an increase in the amount of Mg and a decrease in the amount of Na from the northwestern part to the southern part in the study area.

  9. Orographic effects on the transport and deposition of volcanic ash: A case study of Mount Sakurajima, Japan

    Science.gov (United States)

    Poulidis, Alexandros P.; Takemi, Tetsuya; Iguchi, Masato; Renfrew, Ian A.

    2017-09-01

    Volcanic ash is a major atmospheric hazard that has a significant impact on local populations and international aviation. The topography surrounding a volcano affects the transport and deposition of volcanic ash, but these effects have not been studied in depth. Here we investigate orographic impacts on ash transport and deposition in the context of the Sakurajima volcano in Japan, using the chemistry-resolving version of the Weather Research and Forecasting model. Sakurajima is an ideal location for such a study because of the surrounding mountainous topography, frequent eruptions, and comprehensive observing network. At Sakurajima, numerical experiments reveal that across the 2-8ϕ grain size range, the deposition of "medium-sized" ash (3-5ϕ) is most readily affected by orographic flows. The direct effects of resolving fine-scale orographic phenomena are counteracting: mountain-induced atmospheric gravity waves can keep ash afloat, while enhanced downslope winds in the lee of mountains (up to 50% stronger) can force the ash downward. Gravity waves and downslope winds were seen to have an effect along the dispersal path, in the vicinity of both the volcano and other mountains. Depending on the atmospheric conditions, resolving these orographic effects means that ash can be transported higher than the initial injection height (especially for ash finer than 2ϕ), shortly after the eruption (within 20 min) and close to the vent (within the first 10 km), effectively modifying the input plume height used in an ash dispersal model—an effect that should be taken into account when initializing simulations.

  10. Deposition or not? The fate of volcanic ash after aggregation processes

    Science.gov (United States)

    Mueller, Sebastian B.; Kueppers, Ulrich; Wadsworth, Fabian B.; Ayris, Paul M.; Casas, Ana S.; Cimarelli, Corrado; Ametsbichler, Jonathan; Delmelle, Pierre; Taddeucci, Jacopo; Jacob, Michael; Dingwell, Donald B.

    2017-04-01

    In the course of explosive volcanic eruptions, large amounts of ash are released into the atmosphere and may subsequently pose a threat to infrastructure, such as aviation industry. Ash plume forecasting is therefore a crucial tool for volcanic hazard mitigation but may be significantly affected by aggregation, altering the aerodynamic properties of particles. Models struggle with the implementation of aggregation since external conditions promoting aggregation have not been completely understood; in a previous study we have shown the rapid generation of ash aggregates through liquid bonding via the use of fluidization bed technology and further defined humidity and temperature ranges necessary to trigger aggregation. Salt (NaCl) was required for the recovery of stable aggregates, acting as a cementation agent and granting aggregate cohesion. A numerical model was used to explain the physics behind particle aggregation mechanisms and further predicted a dependency of aggregation efficiency on liquid binder viscosity. In this study we proof the effect of viscosity on particle aggregation. HCl and H2SO4 solutions were diluted to various concentrations resulting in viscosities between 1 and 2 mPas. Phonolitic and rhyolitic ash samples as well as soda-lime glass beads (serving as analogue material) were fluidized in the ProCell Lab® of Glatt Ingenieurtechnik GmbH and treated with the acids via a bottom-spray technique. Chemically driven interaction between acid liquids and surfaces of the three used materials led to crystal precipitation. Salt crystals (e.g. NaCl) have been confirmed through scanning electron microscopy (SEM) and leachate analysis. Both volcanic ash samples as well as the glass beads showed a clear dependency of aggregation efficiency on viscosity of the sprayed HCl solution. Spraying H2SO4 provoked a collapse of the fluidized bed and no aggregation has been observed. This is accounted by the high hygroscopicity of H2SO4. Dissolving CaCl2 (known to be

  11. Compositional and Textural Analysis of Maar-Diatreme Volcanic Deposits at Hopi Buttes Volcanic Field (AZ) Using GigaPan Panoramic and Thermal Infrared Imagery

    Science.gov (United States)

    Lee, R.; Graettinger, A. H.; Weinell, M.; Hughes, C. G.

    2016-12-01

    Basaltic maar-diatreme volcanoes are produced when rising magma interacts with groundwater and produces a maar crater at the ground surface. This crater is underlain by a diatreme, a downward-tapering conical structure filled with a mixture of fragments of intruded magma, fractured host rock, and clasts recycled through repeated discrete subsurface explosions. The debris of the diatreme records the mixing processes caused by subsurface explosions and is the source for ejected material that forms maar tephra rings. Determining the variable depths and lateral locations of these explosions and how energy is dissipated in the subsurface is critical to understanding how maar-diatreme eruptions progress. The Hopi Buttes Volcanic Field (HBVF) in the Navajo Nation, Arizona, USA, contains several diatremes and incised tephra rings with heterolithic clasts 10 mm - 10 m in size, and are well-exposed near-vertical to vertical outcrops. Our ability to measure the length scales and distribution of textures produced by subsurface explosions in these diatremes is limited by the physical accessibility of the exposures, due to both the verticality of the outcrops and the cultural sensitivity of the site. Quantifying the number and locations of explosions is dependent on our ability to investigate the full diatreme outcrop, and not just what can be accessed through traditional field observations. We present a novel field and computer-based technique for both quantitatively and qualitatively characterizing the composition and texture of maar-diatreme deposits in vertical outcrops. This technique uses a combination of field-collected multispectral thermal infrared (TIR) image data and visible wavelength GigaPan imagery to characterize the compositional and textural variations over a whole outcrop. To increase the spatial and spectral resolution of the TIR data, a super-resolution technique will be applied. The technique provides a simple and efficient method to augment the study of the

  12. 天山石炭纪火山岩系中含有富Nb岛弧玄武岩吗?%Do the Tianshan Carboniferous volcanic successions contain Nb-enriched arc basalts?

    Institute of Scientific and Technical Information of China (English)

    夏林圻; 夏祖春; 徐学义; 李向民; 马中平

    2009-01-01

    中国西北部天山石炭纪-早二叠世裂谷火山作用代表了一个新近被认可的大火成岩省.有人认为,在天山石炭纪火山岩系中发育有富Nb岛弧玄武岩、埃达克岩和高镁安山岩组合.然而,该岩石组合具有与典型富Nb岛弧玄武岩、埃达克岩和高镁安山岩不同的化学和同位素特点,表明其并非是岛弧岩石组合.这一推断的岛弧岩石组合实际上是大陆板内火山岩组合,由未遭受地壳混染、受到地壳轻微混染和遭受地壳强烈混染的大陆火山岩组成.%The Tianshan Carboniferous-Early Permian rift-related volcanism in northwestern China represents a newly recognized large igneous province. It has been deemed that an assemblage of Nb-enriched arc basalt, adakite and high-Mg andesite occurred in the Tianshan Carboniferous volcanic successions. Divergent chemical and isotopic characteristics between this rock assemblage and the typical Nb-enriched arc basalts, adakites and high-Mg andesites reveal that the former is not arc related. This postulated arc-related assemblage is indeed an intracontinental volcanic assemblage that consists of crustally uncontaminated, less-contaminated and strongly contaminated continental volcanic rocks.

  13. Periodicities in sediment temperature time-series at a marine shallow water hydrothermal vent in Milos Island (Aegean Volcanic arc, Eastern Mediterranean)

    Science.gov (United States)

    Aliani, Stefano; Meloni, Roberto; Dando, Paul R.

    2004-05-01

    Time-series data sets of total bottom pressure (tidal plus atmospheric), seawater temperature and sediment temperature from a marine shallow hydrothermal vent (Milos, Hellenic Volcanic Arc, Aegean Sea) were studied to determine factors influencing periodicity at the vents. Bottom pressure and vent temperature were mainly opposite in phase, with the main fluctuations of vent temperature occurring at tidal frequencies. Although the fluctuations in atmospheric pressure were of the same order as those due to tidal pressure, the contribution of atmospheric pressure was considerably weaker at diurnal frequencies. Some sudden discontinuities in sediment temperature were recorded, at least one of these may have been caused by seismic events. Seawater temperature changes were not reflected in the sediment temperature record. Transient loadings, such as tidal loadings, barometric pressure and earth tides, may affect the pore pressure in sediments, influencing fluid expulsion and sediment temperature as a consequence. Most of the contribution to the fluctuations in sediment temperature depends on tidal loadings. Gravitational forces, in the form of earth tides, can also be involved and barometric pressure is probably responsible for long period temperature oscillations.

  14. Constraints on the origin and evolution of magmas in the Payún Matrú Volcanic Field, Quaternary Andean back-arc of western Argentina

    DEFF Research Database (Denmark)

    Hernadno, I R; Aragón, E; Frei, Robert

    2014-01-01

    and Sr–Nd isotopic compositions of the basaltic lavas and Payún Matrú rocks indicate that the trachytes of Payún Matrú are the result of fractional crystallization of basaltic parent magmas without significant upper crustal contamination, and that the basalts have a geochemical similarity to ocean island...... basalt (La/Nb = 0·8–1·5, La/Ba = 0·05–0·08). The Sr–Nd isotopic compositions of the basaltic to trachytic rocks range between 0·703813 and 0·703841 (87Sr/86Sr) and 0·512743 and 0·512834 (143Nd/144Nd). Mass-balance and Rayleigh fractionation models support the proposed origin of the trachytes...... that the basaltic lavas originated in the asthenospheric mantle, probably within the spinel stability field and beneath an attenuated continental lithosphere in the back-arc area. The lack of a slab-fluid signature in the Payún Matrú Volcanic Field rocks, along with unpublished and published geophysical results...

  15. Friction properties of amorphous carbon ultrathin films deposited by filtered cathodic vacuum arc and radio-frequency sputtering

    Energy Technology Data Exchange (ETDEWEB)

    Matlak, J.; Komvopoulos, K., E-mail: kyriakos@me.berkeley.edu

    2015-03-31

    The friction properties of ultrathin films of amorphous carbon (a-C) deposited on Si(100) substrates by filtered cathodic vacuum arc and radio-frequency sputtering were investigated by surface force microscopy. Deposition parameters yielding a-C films with high sp{sup 3} content were used to deposit films of thickness between 5 and 35 nm. The coefficient of friction of both types of a-C films was measured with a 1-μm-radius conical diamond tip and normal loads in the range of 20–640 μN. The results show a strong dependence of the friction properties on the surface roughness, thickness, and structure of the a-C films, which are influenced by the intricacies of the deposition method. The dependence of the coefficient of friction on normal load and the dominance of adhesion and plowing friction mechanisms are interpreted in terms of the through-thickness variation of carbon atom hybridization of the a-C films. - Highlights: • Comparison of nanoscale friction properties of ultrathin amorphous carbon films. • Friction dependence on film roughness, thickness, and structure (hybridization). • Effect of through-thickness changes in carbon atom hybridization on film friction. • Explanation of film friction trends in terms of competing friction mechanisms.

  16. Influence of substrate bias on the structure and properties of ZrN films deposited by cathodic vacuum arc

    Energy Technology Data Exchange (ETDEWEB)

    Niu, E.W. [Beijing National Laboratory for Condensed Matter, Institute of Physics, Chinese Academy of Science, 100080 Beijing (China)], E-mail: new05@aphy.iphy.ac.cn; Li, L. [Beijing National Laboratory for Condensed Matter, Institute of Physics, Chinese Academy of Science, 100080 Beijing (China); Lv, G.H. [Beijing National Laboratory for Condensed Matter, Institute of Physics, Chinese Academy of Science, 100080 Beijing (China); Chen, H. [Beijing National Laboratory for Condensed Matter, Institute of Physics, Chinese Academy of Science, 100080 Beijing (China); Feng, W.R. [Beijing National Laboratory for Condensed Matter, Institute of Physics, Chinese Academy of Science, 100080 Beijing (China); Fan, S.H. [Beijing National Laboratory for Condensed Matter, Institute of Physics, Chinese Academy of Science, 100080 Beijing (China); Yang, S.Z. [Beijing National Laboratory for Condensed Matter, Institute of Physics, Chinese Academy of Science, 100080 Beijing (China); Yang, X.Z. [Beijing National Laboratory for Condensed Matter, Institute of Physics, Chinese Academy of Science, 100080 Beijing (China)

    2007-07-15

    ZrN films were deposited by cathodic vacuum arc (CVA) technique in N{sub 2} atmosphere at low temperature with different substrate bias. The ZrN films deposited are atomically smooth. The influence of substrate bias at the wide range (0 to -500 V) on the deposition rate, surface morphology, crystal structure, internal stress, and mechanical properties of the ZrN films were systematically investigated. Increasing substrate bias results in the decrease of deposition rate and the increase of surface roughness. It was found that there is a strong correlation between the substrate bias, film structure and properties. At the bias of 0 V, ZrN films characterize with random orientation, low surface roughness, small grain size. With the increase of bias, the structure changes from random orientation to (1 1 1) preferred orientation and then to (2 2 0) orientation. As substrate bias increases to about -150 V, the internal stress, hardness and Young's modulus increase to maximum. A further increase of bias results in the gradual decrease to lower level.

  17. Tectonostratigraphy and depositional history of the Neoproterozoic volcano-sedimentary sequences in Kid area, southeastern Sinai, Egypt: Implications for intra-arc to foreland basin in the northern Arabian-Nubian Shield

    Science.gov (United States)

    Khalaf, E. A.; Obeid, M. A.

    2013-09-01

    This paper presents a stratigraphic and sedimentary study of Neoproterozoic successions of the South Sinai, at the northernmost segment of the Arabian-Nubian Shield (ANS), including the Kid complex. This complex is composed predominantly of thick volcano-sedimentary successions representing different depositional and tectonic environments, followed by four deformational phases including folding and brittle faults (D1-D4). The whole Kid area is divisible from north to south into the lower, middle, and upper rock sequences. The higher metamorphic grade and extensive deformational styles of the lower sequence distinguishes them from the middle and upper sequences. Principal lithofacies in the lower sequence include thrust-imbricated tectonic slice of metasediments and metavolcanics, whereas the middle and upper sequences are made up of clastic sediments, intermediate-felsic lavas, volcaniclastics, and dike swarms. Two distinct Paleo- depositional environments are observed: deep-marine and alluvial fan regime. The former occurred mainly during the lower sequence, whereas the latter developed during the other two sequences. These alternations of depositional conditions in the volcano-sedimentary deposits suggest that the Kid area may have formed under a transitional climate regime fluctuating gradually from warm and dry to warm and humid conditions. Geochemical and petrographical data, in conjunction with field relationships, suggest that the investigated volcano-sedimentary rocks were built from detritus derived from a wide range of sources, ranging from Paleoproterozoic to Neoproterozoic continental crust. Deposition within the ancient Kid basin reflects a complete basin cycle from rifting and passive margin development, to intra-arc and foreland basin development and, finally, basin closure. The early phase of basin evolution is similar to various basins in the Taupo volcanics, whereas the later phases are similar to the Cordilleran-type foreland basin. The

  18. Indigenous Carbonaceous Phases Embedded Within Surface Deposits on Apollo 17 Volcanic Glass Beads

    Science.gov (United States)

    Thomas-Keprta, K. L.; Clemett, S. J.; Ross, D. K.; Le, L.; McKay, D. S.; Gibson, E. K.; Gonzalez, C.

    2012-01-01

    The assessment of indigenous organic matter in returned lunar samples was one of the primary scientific goals of the Apollo program. Prior studies of Apollo samples have shown the total amount of organic matter to be in the range of approx 50 to 250 ppm. Low concentrations of lunar organics may be a consequence not only of its paucity but also its heterogeneous distribution. Several processes should have contributed to the lunar organic inventory including exogenous carbonaceous accretion from meteoroids and interplanetary dust particles, and endogenous synthesis driven by early planetary volcanism and cosmic and solar radiation.

  19. Occurrence of volcanic ash in the Quaternary alluvial deposits, lower Narmada basin, western India

    Indian Academy of Sciences (India)

    Rachna Raj

    2008-02-01

    This communication reports the occurrence of an ash layer intercalated within the late Quaternary alluvial succession of the Madhumati River, a tributary of the lower Narmada River. Petrographic, morphological and chemical details of glass shards and pumice fragments have formed the basis of this study. The ash has been correlated with the Youngest Toba Tuff. The finding of ash layer interbedded in Quaternary alluvial sequences of western Indian continental margin is significant, as ash being datable material, a near precise time-controlled stratigraphy can be interpreted for the Quaternary sediments of western India. The distant volcanic source of this ash requires a fresh re-assessment of ash volume and palaeoclimatic interpretations.

  20. Assessment of correlation between geophysical and hydrogeological parameters of volcanic deposits at Bandama Caldera (Gran Canaria, Canary Islands, Spain)

    Science.gov (United States)

    Casas, Albert; Himi, Mahjoub; Estévez, Esmeralda; Lovera, Raúl; Sendrós, Alexandre; Palacios-Díaz, M. Pino; Tapias, Josefina C.; Cabrera, M. Carmen

    2015-04-01

    The characterization of the preferential areas of water infiltration through the vadose zone is of paramount importance to assess the pollution vulnerability of the underlying aquifers. Nevertheless, geometry and the hydraulic conductivity of each geological unit which constitute the unsaturated zone are difficult to study from traditional techniques (samples from trenches) and normally do not go beyond a meter depth from of the surface. On the other hand, boreholes are expensive and provide only local information not always representative of the whole unsaturated zone. For this reason, geophysical techniques and among them the electrical resistivity tomography method can be applicable in volcanic areas, where basaltic rocks, pyroclastic and volcanic ash-fall deposits have a wide range of values. In order to characterize the subsurface geology below the golf course of Bandama (Gran Canaria Island), irrigated with reclaimed wastewater, a detailed electrical resistivity tomography survey has been carried out. This technique has allowed to define the geometry of the existing geological formations by their high electrical resistivity contrast. Subsequently, in representative outcrops the value of resistivity of each of these lithologies has been measured and simultaneously undisturbed samples have been taken measuring the hydraulic conductivity in the laboratory. Finally a statistical correlation between both variables has been established for evaluating the vulnerability to groundwater pollution at different zones of the golf course.

  1. Prospecting for clay minerals within volcanic successions: Application of electrical resistivity tomography to characterise bentonite deposits in northern Sardinia (Italy)

    Science.gov (United States)

    Longo, V.; Testone, V.; Oggiano, G.; Testa, A.

    2014-12-01

    Electrical resistivity tomography (ERT) is applied to prospect for and characterise a bentonitic clay deposit in northern Sardinia. Sardinian bentonites derived from the hydrothermal alteration of thick successions of pyroclastic flows and epiclastites are associated with the Oligo-Miocene calc-alkaline volcanic cycle. The alteration of these rocks is generally controlled by faults that control the local circulation of hydrothermal fluids. Two-dimensional ERT investigations were performed close to a faulted area to define the location, thickness and lateral continuity of the clayey body, and determine how it relates to faulting and stratigraphy. A line-based three-dimensional ERT data acquisition was carried out in a selected area to estimate the available clay reserves. The reliability of these resistivity models was assessed by comparison with local borehole data. Finally, the interpretation of the ERT results was optimised through synthetic modelling of the electrical resistivity imaging technique. The results define the extent and geometry of the bentonitic deposit with good accuracy and outline the scenarios where the ERT method may provide optimal results when prospecting for clay deposits.

  2. High resolution seismic data coupled to Multibeam bathymetry of Stromboli island collected in the frame of the Stromboli geophysical experiment: implications with the marine geophysics and volcanology of the Aeolian Arc volcanic complex (Sicily, Southern Tyrrhenian sea, Italy).

    Science.gov (United States)

    Aiello, Gemma; Di Fiore, Vincenzo; Marsella, Ennio; Passaro, Salvatore

    2014-01-01

    New high resolution seismic data (Subbottom Chirp) coupled to high resolution Multibeam bathymetry collected in the frame of the Stromboli geophysical experiment aimed at recording active seismic data and tomography of the Stromboli Island are here presented. The Stromboli geophysical experiment has been already carried out based on onshore and offshore data acquisition in order to investigate the deep structure and the location of the magma chambers of the Stromboli volcano. A new detailed swath bathymetry of Stromboli Island is here shown and discussed to reconstruct an up-to-date morpho-bathymetry and marine geology of the area compared to the volcanologic setting of the Aeolian Arc volcanic complex. Due to its high resolution the new Digital Terrain Model of the Stromboli Island gives interesting information about the submerged structure of the volcano, particularly about the volcano-tectonic and gravitational processes involving the submarine flanks of the edifice. Several seismic units have been identified based on the geologic interpretation of Subbottom Chirp profiles recorded around the volcanic edifice and interpreted as volcanic acoustic basement pertaining to the volcano and overlying slide chaotic bodies emplaced during its complex volcano-tectonic evolution. They are related to the eruptive activity of Stromboli, mainly poliphasic and to regional geological processes involving the intriguing geology of the Aeolian Arc, a volcanic area still in activity and needing improved research interest.

  3. SEM study on the deposition of coal pyrolysis in arc plasma jet

    Energy Technology Data Exchange (ETDEWEB)

    Tian, Y.J.; Chen, H.G.; Yan, Y.L.; Lu, Y.K.; Li, F.; Xie, K.C. [Taiyuan University of Technology, Taiyuan (China). Shanxi Key Lab of Coal Science and Technology

    1999-07-01

    During coal pyrolysis in hydrogen plasma, residue was deposited on the reactor wall. Scanning electron microscopy indicated that metaplast were formed during the process. The mechanism of formation of deposits, their morphology, porosity and mechanical properties are discussed. It was shown that particles do not blend with plasma under these operation conditions. 4 refs., 5 figs., 2 tabs.

  4. Hydrous basalt-limestone interaction at crustal conditions: Implications for generation of ultracalcic melts and outflux of CO2 at volcanic arcs

    Science.gov (United States)

    Carter, Laura B.; Dasgupta, Rajdeep

    2015-10-01

    High degassing rates for some volcanoes, typically in continental arcs, (e.g., Colli Albani Volcanic District, Etna, Vesuvius, Italy; Merapi, Indonesia; Popocatepetl, Mexico) are thought to be influenced by magma-carbonate interaction in the crust. In order to constrain the nature of reaction and extent of carbonate breakdown, we simulated basalt-limestone wall-rock interactions at 0.5-1.0 GPa, 1100-1200 °C using a piston cylinder and equal mass fractions of calcite (CaCO3) and a hydrous (∼4 wt.% H2O) basalt in a layered geometry contained in AuPd capsules. All experiments produce melt + fluid + calcite ± clinopyroxene ± plagioclase ± calcic-scapolite ± spinel. With increasing T, plagioclase is progressively replaced by scapolite, clinopyroxene becomes CaTs-rich, and fluid proportion, as inferred from vesicle population, increases. At 1.0 GPa, 1200 °C our hydrous basalt is superliquidus, whereas in the presence of calcite, the experiment produces calcite + clinopyroxene + scapolite + melt. With the consumption of calcite with increasing T and decreasing P, melt, on a volatile-free basis, becomes silica-poor (58.1 wt.% at 1.0 GPa, 1100 °C to 34.9 wt.% at 0.5 GPa, 1200 °C) and CaO-rich (6.7 wt.% at 1.0 GPa, 1100 °C to 43.7 wt.% at 0.5 GPa, 1200 °C), whereas Al2O3 drops (e.g., 19.7 at 1100 °C to 12.8 wt.% at 1200 °C at 1.0 GPa) as clinopyroxene becomes more CaTs-rich. High T or low P melt compositions are 'ultracalcic,' potentially presenting a new hypothesis for the origin of ultracalcic melt inclusions in arc lava olivines. Wall-rock calcite consumption is observed to increase with increasing T and decreasing P. At 0.5 GPa, our experiments yield carbonate assimilation from 21.6 to 47.6% between 1100 and 1200 °C. Using measured CO2 outflux rates for Mts. Vesuvius, Merapi, Etna and Popocatepetl over a T variation of 1100 to 1200 °C at 0.5 GPa, we calculate 6-92% of magmatic input estimates undergo this extent of assimilation, suggesting that up to ∼3

  5. Nanodiamond embedded ta-C composite film by pulsed filtered vacuum arc deposition from a single target

    Science.gov (United States)

    Iyer, Ajai; Etula, Jarkko; Ge, Yanling; Liu, Xuwen; Koskinen, Jari

    2016-11-01

    Detonation Nanodiamonds (DNDs) are known to have sp3 core, sp2 shell, small size (few nm) and are gaining importance as multi-functional nanoparticles. Diverse methods have been used to form composites, containing detonation nanodiamonds (DNDs) embedded in conductive and dielectric matrices for various applications. Here we show a method, wherein DND-ta-C composite film, consisting of DNDs embedded in ta-C matrix have been co-deposited from the same cathode by pulsed filtered cathodic vacuum arc method. Transmission Electron Microscope analysis of these films revel the presence of DNDs embedded in the matrix of amorphous carbon. Raman spectroscopy indicates that the presence of DNDs does not adversely affect the sp3 content of DND-ta-C composite film compared to ta-C film of same thickness. Nanoindentation and nanowear tests indicate that DND-ta-C composite films possess improved mechanical properties in comparison to ta-C films of similar thickness.

  6. Effect of Sample Configuration on Droplet-Particles of TiN Films Deposited by Pulse Biased Arc Ion Plating

    Institute of Scientific and Technical Information of China (English)

    Yanhui Zhao; Guoqiang Lin; Jinquan Xiao; Chuang Dong; Lishi Wen

    2009-01-01

    Orthogonal experiments are used to design the pulsed bias related parameters, including bias magnitude, duty cycle and pulse frequency, during arc ion deposition of TiN films on stainless steel substrates in the case of samples placing normal to the plasma flux. The effect of these parameters on the amount and the size distribution of droplet-particles are investigated, and the results have provided sufficient evidence for the physical model, in which particles reduction is due to the case that the particles are negatively charged and repulsed from negative pulse electric field. The effect of sample configuration on amount and size distribution of the particles are analyzed. The results of the amount and size distribution of the particles are compared to those in the case of samples placing parallel to the plasma flux.

  7. Felsic Magmatism through Intracrustal Melting of Previously Formed Volcanic-Arc Crust: Implications for Differentiation and Secular Evolution of the Continental Crust

    Science.gov (United States)

    G R, R. K.; C, S.

    2015-12-01

    The fundamental challenge in understanding the origin and evolution of the continental crust is to recognize how primary mantle source, and oceanic crust, which are essentially mafic to ultramafic in composition, could differentiate into a more or less felsic compositions. It is possible to understand growth and differentiation of the continental crust by constraining the interplay of magmatism, deformation, and high-grade metamorphism in the lower crust. Here, we apply this knowledge on the lower crustal granitoids of southern India and speculate on the variations in geochemistry as a consequence of differentiation and secular evolution of the continental crust.The major groups of granitoids of southern India are classified as metatonalites, comparable to typical Archaean TTGs with pronounced calc-alkaline affinity, and metagranites which are magmatic fractionation produced by reworking of early crust. Metatonalites are sodic-trondhjemites with slightly magnesian, moderate LREE (average LaN = 103) and low HREE (average YbN = 2) characerestics, where as metagranites are calc-alkaline ferroan types with enriched LREE (average LaN = 427) and HREE (average YbN = 23). Petrogenetic characteristics of granitoids illustrate continuous evolution of a primary crust into diverse magmatic units by multiple stages of intracrustal differentiation processes attributed to following tectonic scenarios: (1) formation of tonalitic magma by low- to moderate-degree partial melting of hydrated basaltic crust at pressures high enough to stabilize garnet-amphibole residue and (2) genesis of granite in a continental arc-accretion setting by an episode of crustal remelting of the tonalitic crust, within plagioclase stability field. The first-stage formed in a flat-subduction setting of an volcanic-arc, leading to the formation of tonalites. The heat budget required is ascribed to the upwelling of the mantle and/or basaltic underplating. Progressive decline in mantle potential temperature

  8. The application of imperialist competitive algorithm for optimization of deposition rate in submerged arc welding process using TiO{sub 2} nano particle

    Energy Technology Data Exchange (ETDEWEB)

    Ghaderi, Mohammad Reza; Eslampanah, Amirhossein; Ghaderi, Kianoosh [Islamic Azad University, Sanandaj (Iran, Islamic Republic of); Aghakhani, Masood [Razi University, Kermanshah (Iran, Islamic Republic of)

    2015-01-15

    We used a novel optimization algorithm based on the imperialist competitive algorithm (ICA) to optimize the deposition rate in the submerged arc welding (SAW) process. This algorithm offers some advantages such as simplicity, accuracy and time saving. Experiments were conducted based on a five factor, five level rotatable central composite design (RCCD) to collect welding data for deposition rate as a function of welding current, arc voltage, contact tip to plate distance, welding speed and thickness of TiO{sub 2} nanoparticles coated on the plates of mild steel. Furthermore, regression equation for deposition rate was obtained using least squares method. The regression equation as the cost function was optimized using ICA. Ultimately, the levels of input variables to achieve maximum deposition rate were obtained using ICA. Computational results indicate that the proposed algorithm is quite effective and powerful in optimizing the cost function.

  9. True polar wander driven by late-stage volcanism and the distribution of paleopolar deposits on Mars

    CERN Document Server

    Kite, Edwin S; Manga, Michael; Perron, J Taylor; Mitrovica, Jerry X

    2009-01-01

    The areal centroids of the youngest polar deposits on Mars are offset from those of adjacent paleopolar deposits by 5-10 degrees. We test the hypothesis that the offset is the result of true polar wander (TPW), the motion of the solid surface with respect to the spin axis, caused by a mass redistribution within or on the surface of Mars. In particular, we consider TPW driven by late-stage volcanism during the late Hesperian to Amazonian. There is observational and qualitative support for this hypothesis: in both North and South, observed offsets lie close to a great circle 90 degrees from Tharsis, as expected for polar wander after Tharsis formed. We calculate the magnitude and direction of TPW produced by mapped late-stage lavas for a range of lithospheric thicknesses, lava thicknesses, eruption histories, and prior polar wander events. If Tharsis formed close to the equator, the stabilizing effect of a fossil rotational bulge located close to the equator leads to predicted TPW of <2 degrees, too small to...

  10. Recent crustal foundering in the Northern Volcanic Zone of the Andean arc: Petrological insights from the roots of a modern subduction zone

    Science.gov (United States)

    Bloch, Elias; Ibañez-Mejia, Mauricio; Murray, Kendra; Vervoort, Jeffrey; Müntener, Othmar

    2017-10-01

    Periodic loss of the lower lithosphere into the convecting mantle due to gravitational instability is postulated to be a major mechanism for lithosphere recycling in orogenic zones, but unequivocal petrologic evidence of this process is elusive. The Granatifera Tuff, located in the Mercaderes-Rio Mayo area of the southern Colombian Andes, contains a wide variety of crustal and mantle xenoliths. Here we focus on the thermobarometry and Lu-Hf isotope systematics of crustal garnet clinopyroxenite xenoliths, the results of which offer the first evidence of recent, and likely active, crustal foundering in the Northern Volcanic Zone of the Andean arc. We find that most of these xenoliths equilibrated between 60-80 km depths, ∼7-27 km below the seismically determined Moho in this region, and that at least one crustal garnet clinopyroxenite re-equilibrated at depths exceeding 95 km. A second garnet clinopyroxenite equilibrated at ∼150 km depths, and is either foundered lithospheric material or the product of reaction between peridotite and a mobile component (either silicic melt or fluids) at >4 GPa. All of the investigated garnet clinopyroxenites are negatively buoyant relative to the upper mantle asthenosphere. The presence of minor amounts of secondary amphibole and orthopyroxene, coupled with the lack of major-element retrograde zonation in primary phases within these xenoliths, indicates that these rocks were rapidly transported to, and briefly resided at, shallow depths before eruption. Lu-Hf ages from two garnet clinopyroxenites and one garnet-clinopyroxene hornblendite are material, which the Mercaderes xenoliths document, without catastrophic removal of the crustal root.

  11. Fabrication for multilayered composite thin films by dual-channel vacuum arc deposition.

    Science.gov (United States)

    Dai, Hua; Shen, Yao; Wang, Jing; Xu, Ming; Li, Liuhe; Li, Xiaoling; Cai, Xun; Chu, Paul K

    2008-06-01

    A flexible dual-channel curvilinear electromagnetic filter has been designed and constructed to fabricate multilayered composite films in vacuum arc ion plating. The filter possesses two guiding channels and one mixing unit. Multilayered TiN/AlN and TiAlN composite films can be produced by controlling the frequency or interval of the two cathodes. The x-ray photoelectron spectroscopy and low-angle x-ray diffraction results reveal the periodic Ti and Al structures in the TiN/AlN films. The TiAlN films exhibit a smooth surface morphology confirming effective filtering of macroparticles by the filter. High temperature oxidation conducted at 700 degrees C for an hour indicates that the weight increment in the TiAlN films produced by the dual filter is only half of that of the TiAlN films produced without a filter, thereby showing better resistance against surface oxidation.

  12. Fabrication for multilayered composite thin films by dual-channel vacuum arc deposition

    Science.gov (United States)

    Dai, Hua; Shen, Yao; Wang, Jing; Xu, Ming; Li, Liuhe; Li, Xiaoling; Cai, Xun; Chu, Paul K.

    2008-06-01

    A flexible dual-channel curvilinear electromagnetic filter has been designed and constructed to fabricate multilayered composite films in vacuum arc ion plating. The filter possesses two guiding channels and one mixing unit. Multilayered TiN /AlN and TiAlN composite films can be produced by controlling the frequency or interval of the two cathodes. The x-ray photoelectron spectroscopy and low-angle x-ray diffraction results reveal the periodic Ti and Al structures in the TiN /AlN films. The TiAlN films exhibit a smooth surface morphology confirming effective filtering of macroparticles by the filter. High temperature oxidation conducted at 700°C for an hour indicates that the weight increment in the TiAlN films produced by the dual filter is only half of that of the TiAlN films produced without a filter, thereby showing better resistance against surface oxidation.

  13. Sulfur mass loading of the atmosphere from volcanic eruptions: Calibration of the ice core record on basis of sulfate aerosol deposition in polar regions from the 1982 El Chichon eruption

    Science.gov (United States)

    Sigurdsson, Haraldur; Laj, Paolo

    1990-01-01

    Major volcanic eruptions disperse large quantities of sulfur compound throughout the Earth's atmosphere. The sulfuric acid aerosols resulting from such eruptions are scavenged by snow within the polar regions and appear in polar ice cores as elevated acidity layers. Glacio-chemical studies of ice cores can, thus, provide a record of past volcanism, as well as the means for understanding the fate of volcanic sulfur in the atmosphere. The primary objectives of this project are to study the chemistry and physical properties of volcanic fallout in a Greenland Ice Core in order to evaluate the impact of the volcanic gases on the atmospheric chemistry and the total atmospheric mass of volcanic aerosols emitted by major volcanic eruptions. We propose to compare the ice core record to other atmospheric records performed during the last 10 years to investigate transport and deposition of volcanic materials.

  14. Postglacial volcanic deposits at Glacier Peak, Washington, and potential hazards from future eruptions; a preliminary report

    Science.gov (United States)

    Beget, J.E.

    1982-01-01

    Eruptions and other geologic events at Glacier Peak volcano in northern Washington have repeatedly affected areas near the volcano as well as areas far downwind and downstream. This report describes the evidence of this activity preserved in deposits on the west and east flanks of the volcano. On the west side of Glacier Peak the oldest postglacial deposit is a large, clayey mudflow which traveled at least 35 km down the White Chuck River valley sometime after 14,000 years ago. Subsequent large explosive eruptions produced lahars and at least 10 pyroclastic-flow deposits, including a semiwelded vitric tuff in the White Chuck River valley. These deposits, known collectively as the White Chuck assemblage, form a valley fill which is locally preserved as far as 100 km downstream from the volcano in the Stillaguamish River valley. At least some of the assemblage is about 11,670-11,500 radiocarbon years old. A small clayey lahar, containing reworked blocks of the vitric tuff, subsequently traveled at least 15 km down the White Chuck River. This lahar is overlain by lake sediments containing charred wood which is about 5,500 years old. A 150-m-thick assemblage of pyroclastic-flow deposits and lahars, called the Kennedy Creek assemblage, is in part about 5,500-5,100 radiocarbon years old. Lithic lahars from this assemblage extend at least 100 km downstream in the Skagit River drainage. The younger lahar assemblages, each containing at least three lahars and reaching at least 18 km downstream from Glacier Peak in the White Chuck River valley, are about 2,800 and 1,800 years old, respectively. These are postdated by a lahar containing abundant oxyhornblende dacite, which extends at least 30 km to the Sauk River. A still younger lahar assemblage that contains at least five lahars, and that also extends at least 30 km to the Sauk River, is older than a mature forest growing on its surface. At least one lahar and a flood deposit form a low terrace at the confluence of the

  15. Hummock alignment in Japanese volcanic debris avalanches controlled by pre-avalanche slope of depositional area

    Science.gov (United States)

    Yoshida, Hidetsugu

    2014-10-01

    This paper investigates the relationship of hummock orientation to the flow dynamics of volcanic debris avalanches. There are opposing views on whether hummocks are systematically aligned along debris avalanche paths, or not. To investigate this geomorphologically fundamental question, I investigated hummock orientation for six Japanese debris avalanches of two simple styles: four "freely spreading" debris avalanches, and two "valley-filling" debris avalanches. Quantitative GIS-based data analysis revealed that hummock orientation along the avalanche flow path alternated between dominantly parallel to and dominantly perpendicular to the flow direction. These changes of alignment reflect dynamic changes of the local stress field within the avalanche, alternating between extensional and compressional in response to changes of the slope of the pre-avalanche ground surface. Changes of hummock alignment from perpendicular to parallel indicate that the local stress regime has changed from compressional to extensional. Conversely, changes of hummock alignment from parallel to perpendicular indicate that the local stress regime has changed from extensional to compressional. Thus, this research demonstrated a clear relationship between hummock orientation and dynamic changes of stress regime within avalanches that are related to changes of the slope of the pre-avalanche ground surface.

  16. Spatial distribution of damage around faults in the Joe Lott Tuff Member of the Mount Belknap Volcanics, Utah: A mechanical analog for faulting in pyroclastic deposits on Mars

    Science.gov (United States)

    Okubo, Chris H.

    2012-01-01

    Volcanic ash is thought to comprise a large fraction of the Martian equatorial layered deposits and much new insight into the process of faulting and related fluid flow in these deposits can be gained through the study of analogous terrestrial tuffs. This study identifies a set of fault-related processes that are pertinent to understanding the evolution of fault systems in fine-grained, poorly indurated volcanic ash by investigating exposures of faults in the Miocene-aged Joe Lott Tuff Member of the Mount Belknap Volcanics, Utah. The porosity and granularity of the host rock are found to control the style of localized strain that occurs prior to and contemporaneous with faulting. Deformation bands occur in tuff that was porous and granular at the time of deformation, while fractures formed where the tuff lost its porous and granular nature due to silicic alteration. Non-localized deformation of the host rock is also prominent and occurs through compaction of void space, including crushing of pumice clasts. Significant off-fault damage of the host rock, resembling fault pulverization, is recognized adjacent to one analog fault and may reflect the strain rate dependence of the resulting fault zone architecture. These findings provide important new guidelines for future structural analyses and numerical modeling of faulting and subsurface fluid flow through volcanic ash deposits on Mars.

  17. Geochemistry of meta-volcanic rocks from the Longbohe Cu deposit, Yunnan Province, China: Implications for the genesis and tectonic setting

    Institute of Scientific and Technical Information of China (English)

    CUI Yinliang; QING Dexian; CHEN Yaoguang

    2007-01-01

    The Longbohe Cu deposit, which is located in the southern part of the Honghe ore-forming zone, Yunnan Province, China, belongs to a typical ore field where volcanic rocks are of wide distribution and are associated with Cu mineralization in time and space. The volcanic rocks in the ore field, which have experienced varying degree of alteration or regional metamorphism, can be divided into three types, i.e., meta-andesite, meta-subvolcanic rock and meta-basic volcanic rock in accordance with their mineral assemblages. These three types of volcanic rocks in the ore field are relatively rich in Na and the main samples plot in the area of alkali basalts in the geochemical classification diagram. With the exception of very few elements, these three types of volcanic rocks are similar in the content of trace elements. In comparison to the basalts of different tectonic settings, the meta-volcanic rocks in the ore field are rich in high field strength elements (HFSE) such as Th, Nb, etc. and depleted in large ion lithophile elements (LILE) such as Sr, Ba, etc. and their primary mantle-normalized trace element patterns show remarkable negative Th and Nb anomalies and negative Sr and Ba anomalies. These three types of volcanic rocks are similar in REE content range and chondrite-normalized REE patterns with the exception of Eu anomaly. Various lines of evidence show that these three types of volcanic rocks in the ore field have the same source but are the products of different stages of magmatic evolution, their original magma is a product of partial melting of the metasomatically enriched mantle in the tensional tectonic setting within the continent plate, and the crystallization differentiation plays an important role in the process of magmatic evolution.

  18. Evidence for Slab Melt Contributions to the Mexican Volcanic Belt and Other Young Hot Slab Arcs from Lu-Hf Isotopes

    Science.gov (United States)

    Goldstein, S. L.; Cai, Y. M.; Langmuir, C. H.; Lagatta, A.; Straub, S. M.; Gomez-Tuena, A.; Martin Del Pozzo, A.

    2007-12-01

    Despite major advances in delineating the processes that govern magma generation at convergent margins, the problem persists of distinguishing slab, mantle wedge, and crustal contributions. A corrollary question is whether there is significant melting of subducted ocean crust. Especially in thick crust regions, the importance of crustal versus mantle contributions to lavas represents a long-standing fundamental issue in arc magma geochemistry. We show that frontal arc magmas from the Central Mexican Volcanic Belt (CMVB), including the large andesitic stratovolcanoes Popocatepetl and Nevado de Toluca, display negligible crustal contamination, and contain substantial contributions from melting of subducted Pacific ocean crust. Despite ca. 50 km thick continental crust, the CMVB erupts near primitive lavas including "high-Nb" alkaline basalts that show negligible "subduction signatures" in their trace element patterns. These "high-Nb" basalts define the regional mantle wedge composition in isotope-trace element space. The "normal" calcalkaline lavas form a negative correlation between Hf isotopes and Lu/Hf. One endmember is like the high Nb basalts representing the regional mantle wedge. The other endmember has higher Hf isotopes (approaching values of Pacific MORB) and very low Lu/Hf of less than 0.04 (e.g. compared to typical values of ca. 0.2 in Pacific MORB). The low Lu/Hf values require low degree partial melting of a source rich in garnet. The high Hf isotopes require a depleted mantle source with isotopes like Pacific MORB. Together the Lu-Hf data indicate a substantial component derived from melting of eclogitic Pacific ocean crust. A key feature of the data is that the stratovolcano lavas showing the largest slab melt signature also show the highest Hf isotope ratios and thus are more "depleted mantle-like" than the regional mantle wedge. Thus, the integrated data allow us to clearly distinguish between mantle and crustal sources in the CMVB and point to

  19. Effect of deposition parameters on the photocatalytic activity and bioactivity of TiO2 thin films deposited by vacuum arc on Ti-6Al-4V substrates.

    Science.gov (United States)

    Lilja, Mirjam; Welch, Ken; Astrand, Maria; Engqvist, Håkan; Strømme, Maria

    2012-05-01

    This article evaluates the influence of the main parameters in a cathodic arc deposition process on the microstructure of titanium dioxide thin coatings and correlates these to the photocatalytic activity (PCA) and in vitro bioactivity of the coatings. Bioactivity of all as deposited coatings was confirmed by the growth of uniform layers of hydroxyapatite (HA) after 7 days in phosphate buffered saline at 37°C. Comparison of the HA growth after 24 h indicated enhanced HA formation on coatings with small titanium dioxide grains of rutile and anatase phase. The results from the PCA studies showed that coatings containing a mixed microstructure of both anatase and rutile phases, with small grain sizes in the range of 26-30 nm and with a coating thickness of about 250 nm, exhibited enhanced activity as compared with other microstructures and higher coating thickness. The results of this study should be valuable for the development of new bioactive implant coatings with photocatalytically induced on-demand antibacterial properties.

  20. Evolution of Eocene to Oligocene arc-related volcanism in the North Patagonian Andes (39-41°S), prior to the break-up of the Farallon plate

    Science.gov (United States)

    Iannelli, Sofía B.; Litvak, Vanesa D.; Fernández Paz, Lucía; Folguera, Andrés; Ramos, Miguel E.; Ramos, Víctor A.

    2017-01-01

    Voluminous Paleogene magmatic rocks (44 to 29 Ma) are found in a retroarc position in the Northern Patagonian to Southern Central Andes ( 39-42°S), whose origin remains controversial. Geochemical data in these Eocene to Oligocene volcanic associations are herein used to unravel their origin and understand changes in subduction parameters. Geochemical signatures indicate arc-related associations and reflect changing geodynamic boundary conditions of the Andean margin through time. In particular, Eocene magmatism ( 44 Ma; Pilcaniyeu Belt) shows an alkaline-like signature and limited slab influence. Reported contemporaneous within-plate magmatism ( 47-43 Ma) in an easternmost position reflects a more typical enriched source. Oligocene arc-like volcanism ( 29 Ma; El Maitén Belt), which developed in an extensional retroarc setting, shows a higher contribution from slab-derived fluids and a calc-alkaline source. A comparison with younger arc-related magmas from the region ( 26-20 Ma), emplaced in an intra- to retroarc position (Cura Mallín and Abanico basins), indicates a progressive increase in slab-signature, associated with a tholeiitic magma source. We propose that these compositional variations could be directly related to changes in plate configuration before and after the Farallon plate break-up and the initiation of a more orthogonal convergence typical of the present Andean-type subduction zone.

  1. Structure and sliding wear behavior of 321 stainless steel/Al composite coating deposited by high velocity arc spraying technique

    Institute of Scientific and Technical Information of China (English)

    CHEN Yong-xiong; XU Bin-shi; LIU Yan; LIANG Xiu-bing; XU Yi

    2008-01-01

    A typical 321 stainless steel/aluminum composite coating (321/Al coating) was prepared by high velocity arc spraying technique (HVAS) with 321 stainless steel wire as the anode and aluminum wire as the cathode.The traditional 321 stainless steel coating was also prepared for comparison.Tribological properties of the coatings were evaluated with the ring-block wear tester under different conditions.The structure and worn surface of the coatings were analyzed by scanning electron microscopy (SEM),X-ray diffractometry (XRD) and energy dispersion spectroscopy (EDS).The results show that,except for aluminum phase addition in tne 321/Al coating,no other phases are created compared with the 321 coating.However,due to the addition of aluminum,the 321/Al coating forms a type of "ductile/hard phases inter-deposited" structure and performs quite different tribological behavior.Under the dry sliding condition,the anti-wear property of 321/Al coating is about 42% lower than that of 321 coating.Butunder the oil lubricated conditions with or without 32h oil-dipping pretreatment,the anti-wear property of 321/Al coating is about 9% and 5% higher than that of 321 coating,respectively.The anti-wear mechanism of the composite coating is mainly relevant to the decrease of oxide impurities and the strengthening action resulted from the "ductile/hard phases inter-deposited" coating structure.

  2. Carbon fluxes from hydrothermal vents off Milos, Aegean Volcanic Arc, and the influence of venting on the surrounding ecosystem.

    Science.gov (United States)

    Dando, Paul; Aliani, Stefano; Bianchi, Nike; Kennedy, Hilary; Linke, Peter; Morri, Carla

    2014-05-01

    The island of Milos, in the Aegean Sea, has extensive hydrothermal fields to the east and southeast of the island with additional venting areas near the entrance to and within the central caldera. A calculation of the total area of the vent fields, based on ship and aerial surveys, suggested that the hydrothermal fields occupy 70 km2, twice the area previously estimated. The vents ranged in water depth from the intertidal to 300 m. As a result of the low depths there was abundant free gas release: in places water boiled on the seabed. The stream of gas bubbles rising through the sandy seabed drove a shallow re-circulation of bottom seawater. The majority of the water released with the gas, with a mean pH of 5.5, was re-circulated bottom water that had become acidified in contact with CO2 gas and was often diluted by admixture with the vapour phase from the deeper fluids. The major component of the free gas, 80%, was CO2, with an estimated total flux of 1.5-7.5 x 1012 g a-1. The methane flux, by comparison, was of the order of 1010 g a.-1 Using methane as a tracer it was shown that the major gas export from the vents was below the thermocline towards the southwest, in agreement with the prevailing currents. Areas of hydrothermal brine seepage occurred between the gas vents and occasional brine pools were observed in seabed depressions. Under relatively calm conditions, many of the brine seeps were covered by thick minero-bacterial mats consisting of silica and sulphur and surrounded by mats of diatoms and cyanobacteria. The minerals were not deposited in the absence of bacteria. Storms disrupted the mats, leading to an export of material to the surrounding area. Stable isotope data from sediments and sediment trap material suggested that exported POM was processed by zooplankton. The combined effects of the geothermal heating of the seabed, the large gas flux, variation in the venting and the effect of the brine seeps had a dramatic effect on the surrounding

  3. The December 2002 volcanic activity at Stromboli: fall and tsunami deposits characterization

    Science.gov (United States)

    Andronico, D.; Coltelli, M.; Corsaro, R. A.; Miraglia, L.; Pompilio, M.

    2003-04-01

    The volcano of Stromboli in the Aeolian Islands (Italy) was known since the Roman age as the "lighthouse" of the Mediterranean Sea, due to its persistent "Strombolian" activity resulting in a summit firelight. During its eruptive history, Stromboli displayed effusive activity and paroxysmal eruptions, too. Lava flows usually flood down the Sciara del Fuoco, a steep depression cutting the NW flank of the cone. Paroxysmals often eject large bombs which can injure the inhabited areas and more rarely form small pyroclastic or debris flows. On the evening of 28 December 2002, effusive activity began after 17 years from the Crater 1; a lava flow reached in about 30 minutes the sea, going down the Sciara del Fuoco. On 30 December, two landslides interested a wide sector of the Sciara del Fuoco, flowing down into the sea. The first one, at about 1.15 p.m., was smaller than the second event which occurred a few minutes later and caused the detachment towards the sea of a more consistent rock volume. This events generated strong tsunami waves which affected the coastline of most of the Aeolian Islands reaching the Milazzo port, about 50 km far. Up to 10 m high waves caused severe damages to the seaside of Stromboli and to the small buildings located at Ficogrande village. We sampled the tsunami sand deposits on the beach and within the houses and the ashes emitted before, and after the tsunami event. The deposits have been studied carrying out grain-size, component analysis, morphometric and compositional characterization. The resulting data allowed to investigate magma fragmentation mechanisms and, for the first time in Stromboli, to characterize the deposit correlated to a tsunami event.

  4. LARGE AREA FILTERED ARC DEPOSITION OF CARBON AND BORON BASED HARD COATINGS

    Energy Technology Data Exchange (ETDEWEB)

    Bhattacharya, Rabi S.

    2003-12-05

    This document is a final report covering work performed under Contract No. DE-FG02-99ER82911 from the Department of Energy under a SBIR Phase II Program. Wear resistant, hard coatings can play a vital role in many engineering applications. The primary goal of this project was to develop coatings containing boron and carbon with hardness greater than 30 GPa and evaluate these coatings for machining applications. UES has developed a number of carbon and boron containing coatings with hardness in the range of 34 to 65 GPa using a combination of filtered cathodic arc and magnetron sputtering. The boron containing coatings were based on TiB2, TiBN, and TiBCN, while the carbon containing coatings ere TiC+C and hydrogen free diamond-like-carbon. Machining tests were performed with single and multilayer coated tools. The turning and milling tests were run at TechSolve Inc., under a subcontract at Ohio State University. Significant increases in tool lives were realized in end milling of H-13 die steel (8X) and titanium alloy (80%) using the TiBN coating. A multilayer TiBN/TiN performed the best in end-milling of highly abrasive Al-Si alloys. A 40% increase in life over the TiAlN benchmark coating was found. Further evaluations of these coatings with commercialization partners are currently in progress.

  5. Thermal conductivity of titanium nitride/titanium aluminum nitride multilayer coatings deposited by lateral rotating cathode arc

    Energy Technology Data Exchange (ETDEWEB)

    Samani, M.K., E-mail: majid1@e.ntu.edu.sg [Novitas, Nanoelectronics Centre of Excellence, School of Electrical & Electronic Engineering, Nanyang Technological University, Singapore 639798 (Singapore); Surface Technology Group, Singapore Institute of Manufacturing Technology, 71 Nanyang Drive, Singapore 638075 (Singapore); Research Group PLASMANT, Department of Chemistry, University of Antwerp, Universiteitsplein 1, B-2610 Antwerp (Belgium); Ding, X.Z. [Surface Technology Group, Singapore Institute of Manufacturing Technology, 71 Nanyang Drive, Singapore 638075 (Singapore); Khosravian, N. [Research Group PLASMANT, Department of Chemistry, University of Antwerp, Universiteitsplein 1, B-2610 Antwerp (Belgium); Amin-Ahmadi, B. [Electron Microscopy for materials Science (EMAT), Department of Physics, University of Antwerpen, Groenenborgerlan 171, B-2020 Antwerpen (Belgium); Yi, Yang [Data Storage Institute, A*STAR (Agency for Science, Technology and Research), 117608 (Singapore); Chen, G. [BC Photonics Technological Company, 5255 Woodwards Rd., Richmond, BC V7E 1G9 (Canada); Neyts, E.C.; Bogaerts, A. [Research Group PLASMANT, Department of Chemistry, University of Antwerp, Universiteitsplein 1, B-2610 Antwerp (Belgium); Tay, B.K. [Novitas, Nanoelectronics Centre of Excellence, School of Electrical & Electronic Engineering, Nanyang Technological University, Singapore 639798 (Singapore)

    2015-03-02

    A series of [TiN/TiAlN]{sub n} multilayer coatings with different bilayer numbers n = 5, 10, 25, 50, and 100 were deposited on stainless steel substrate AISI 304 by a lateral rotating cathode arc technique in a flowing nitrogen atmosphere. The composition and microstructure of the coatings have been analyzed by using energy dispersive X-ray spectroscopy, X-ray diffraction (XRD), and conventional and high-resolution transmission electron microscopy (HRTEM). XRD analysis shows that the preferential orientation growth along the (111) direction is reduced in the multilayer coatings. TEM analysis reveals that the grain size of the coatings decreases with increasing bilayer number. HRTEM imaging of the multilayer coatings shows a high density misfit dislocation between the TiN and TiAlN layers. The cross-plane thermal conductivity of the coatings was measured by a pulsed photothermal reflectance technique. With increasing bilayer number, the multilayer coatings' thermal conductivity decreases gradually. This reduction of thermal conductivity can be ascribed to increased phonon scattering due to the disruption of columnar structure, reduced preferential orientation, decreased grain size of the coatings and present misfit dislocations at the interfaces. - Highlights: • TiN/TiAlN multilayer coatings with different bilayer number were deposited on SS. • The composition and microstructure of the as-deposited coatings were analyzed. • Thermal conductivity of the coatings was measured by pulsed photothermal reflectance. • Thermal conductivity depends on the coatings' microstructure and number of layers. • With increasing the bilayer number, thermal conductivity decreased.

  6. Effect of high substrate bias and hydrogen and nitrogen incorporation on filtered cathodic vacuum arc deposited tetrahedral amorphous carbon films

    Energy Technology Data Exchange (ETDEWEB)

    Panwar, O.S. [Plasma Processed Materials Group, National Physical Laboratory, Dr. K.S. Krishnan Road, New Delhi-110 012 (India)], E-mail: ospanwar@mail.nplindia.ernet.in; Khan, Mohd. Alim [Plasma Processed Materials Group, National Physical Laboratory, Dr. K.S. Krishnan Road, New Delhi-110 012 (India); Kumar, Mahesh; Shivaprasad, S.M. [Surface Physics and Nanostructures Group, National Physical Laboratory, Dr. K.S. Krishnan Road, New Delhi-110 012 (India); Satyanarayana, B.S. [MIT Innovation Centre and Electronics and Communication Department, Manipal Institute of Technology, Manipal-579104 (India); Dixit, P.N. [Plasma Processed Materials Group, National Physical Laboratory, Dr. K.S. Krishnan Road, New Delhi-110 012 (India); Bhattacharyya, R. [Emeritus Scientist, National Physical Laboratory, New Delhi-110012 (India); Khan, M.Y. [Department of Physics, Jamia Millia Islamia, Central University, New Delhi-110025 (India)

    2008-02-29

    The application of a sufficiently high negative substrate bias, during the growth of tetrahedral amorphous carbon (ta-C), is usually associated with low sp{sup 3} bonding configuration and stressed films. However, in an effort to understand and utilize the higher pseudo thermo dynamical conditions during the film growth, at high negative substrate bias (- 300 V), reported here is a study on ta-C films grown under different hydrogen and nitrogen concentration. As grown ta-C films were studied under different negative substrate bias conditions. The variation of the sp{sup 3} content and sp{sup 3}/sp{sup 2} ratio in the ta-C films exhibits a trend similar to those reported in literature, with a subtle variation in this report being the substrate bias voltage, which was observed to be around - 200 V, for obtaining the highest sp{sup 3} (80%) bonding and sp{sup 3}/sp{sup 2} (3.95) ratio. The hydrogen and nitrogen incorporated ta-C films studied, at a bias of - 300 V, show an increase in sp{sup 3} (87-91%) bonding and sp{sup 3}/sp{sup 2} (7-10) ratio in the range of studies reported. The inference is drawn on the basis of the set of data obtained from measurements carried out using X-ray photoelectron spectroscopy, X-ray induced Auger electron spectroscopy and Raman spectroscopy of as grown and hydrogen and nitrogen incorporated ta-C films deposited using an S bend filtered cathodic vacuum arc system. The study indicates the possibility of further tailoring ta-C film properties and also extending capabilities of the cathodic arc system for developing carbon based films for electronics and tribological applications.

  7. Early Eocene volcanic ashes on Greifswalder Oie and their depositional environment, with an overview of coeval ash-bearing deposits in northern Germany and Denmark

    Science.gov (United States)

    Obst, Karsten; Ansorge, Jörg; Matting, Sabine; Hüneke, Heiko

    2015-11-01

    Unconsolidated bentonites and carbonate-cemented volcanic ashes occur in northern Germany within the clay sequence of the Lamstedt and Schlieven Formations documented by several wells. Ash-bearing carbonate concretions (so-called cementstones) are also known from glacially transported rafts and erratic boulders on the Baltic Sea island Greifswalder Oie, representing the easternmost exposures of early Eocene sediments in the North Sea Basin. The ashes can be correlated with water-lain ashes of the Danish Fur and Ølst Formations (mo-clay) generated during the opening of the North Atlantic Ocean about 55 Ma ago. Two types of cementstones can be distinguished on the basis of the mineralogical composition, sedimentary features and fossil content. Greifswalder Oie type I contains a black, up to 12-cm-thick ash deposit that follows above two distinct thin grey ash layers. The major ash unit has a rather homogeneous lower part; only a very weak normal grading and faint lamination are discernible. In the upper part, however, intercalations with light mudstone, in part intensively bioturbated, together with parallel and cross-lamination suggest reworking of the ash in a shallow marine environment. Major and trace element compositions are used to correlate type I ashes with those of the Danish-positive series which represent rather uniform ferrobasalts of the Danish stage 4, probably related to the emergence of proto-Iceland. In contrast, type II ash comprises a single, normally graded, about 5-cm-thick layer of water-lain air-fall tuff, which is embedded in fine-grained sandstone to muddy siltstone. Type II ash is characterised by very high TiO2 but low MgO contents. Exceptional REE patterns with a pronounced positive Eu anomaly suggest intense leaching of the glass that hampers exact correlation with pyroclastic deposits within the North Atlantic Igneous Province.

  8. A Measure of Intense in West and Central Java Through Manifestation of River Basin Morphometry Development on Quaternary Volcanic Deposits

    Directory of Open Access Journals (Sweden)

    Febri Hirnawan

    2014-06-01

    Full Text Available DOI: 10.17014/ijog.v4i4.88Indications exhibiting active tectonic movements in Java occur in many places, characterized by unstable regions, such as active faults, earthquakes, volcanic eruptions, etc. The results of researches conducted at several areas in West and Central Java on tectonic morphometry developments of river basins both in Quaternary deposits and Tertiary sediments exhibit a degree of active tectonic intensity. Such the researches are very important regarding to the spatial development design that is related to a region of active tectonism that should be well understood by planners for decision making mainly through comprehensive approach, in which the phenomena involved explaining the characteristics of the region as part of an active plate margin. Statistic approach as the chosen methodology had been utilized to gain meaningful conclusions through the verification of hypotheses, which are based on valid and reliable tested data obtained from the fields and satellite imagery. Results of regression-correlation tests between azimuths of river segment and lineaments in both chronostratigraphic systems mentioned earlier are significant with several large values of correlation coefficients r of no less than 0.9. On the other hand, results of t-tests are not a significant difference of means of bifurcation ratio (Rb and drainage density (Dd from many to river basins. The results of all tests have verified the effect of active tectonic control on the morphometry development process regarding to river segments and density of drainage patterns development in Tertiary and Quaternary deposits.

  9. Persistence of seed bank under thick volcanic deposits twenty years after eruptions of Mount Usu, Hokkaido Island, Japan.

    Science.gov (United States)

    Tsuyuzaki, S; Goto, M

    2001-10-01

    The topsoil that contained the seed bank became buried under thick tephra after the eruptions of Mount Usu during 1977 and 1978. To determine the seed bank potential of the topsoil 20 yr after the eruptions, i.e., in 1998, 408 100-cm(3) samples were excavated under 115-185 cm of volcanic deposits. The topsoil was collected at 10-cm intervals along the horizontal scale and was divided into a 0-5 cm deep upper layer and a 5-10 cm deep lower layer. The seed bank was estimated by both the germination (GM) and flotation (FM) methods. In total, 23 species with an average seed density of 1317 seeds/m(2) were identified by GM, and 30 species with a density of 2986 seeds/m(2) were extracted by FM. The dominant species was Rumex obtusifolius, and perennial herbs, such as Carex oxyandra, Viola grypoceras, and Poa pratensis, were common. For nine species this study provided the first records for field seed longevity >20 yr. The seed density in the upper layer was double that in the lower layer, and the horizontal distribution was heterogeneous even at 10-cm intervals. We concluded that the seed bank has retained the original structure of the seed bank under the tephra and will persist longer with soil water content between 20 and 40%, no light, and low temperature fluctuations (±0.17°C of standard deviation in a day).

  10. Properties of low-temperature deposited ZnO thin films prepared by cathodic vacuum arc technology on different flexible substrates

    Energy Technology Data Exchange (ETDEWEB)

    Pan, Cheng-Tang [Department of Mechanical and Electron-Mechanical Engineering, National Sun Yat-Sen University, Kaohsiung City 804, Taiwan (China); Yang, Ru-Yuan, E-mail: ryyang@mail.npust.edu.tw [Graduate Institute of Materials Engineering, National Pingtung University of Science and Technology, Pingtung County 912, Taiwan (China); Weng, Min-Hang [Medical Devices and Opto-Electronics Equipment Department, Metal Industries Research and Development Center, Kaohsiung City 821, Taiwan (China); Huang, Chien-Wei [Department of Mechanical and Electron-Mechanical Engineering, National Sun Yat-Sen University, Kaohsiung City 804, Taiwan (China)

    2013-07-31

    Un-doped zinc oxide (ZnO) films were deposited on three different substrates (polyethylene terephthalate (PET), polyvinyl butyral (PVB) and polyimide (PI)) at a low temperature (< 75 °C) by cathode vacuum arc deposition. The microstructure, optical and electrical properties of the deposited films were investigated and discussed. All the deposited films reveal a preferred orientation with the c-axis perpendicular to the substrate, and an average transmittance of over 85% in the visible region. The calculated optical band gaps are around 2.6, 3.14 and 3.18 eV, respectively, for the ZnO films deposited on the PI, PVB and PET substrates. The lowest resistivity and the highest Hall mobility are 5.31 × 10{sup −3} Ω-cm and 15.16 cm{sup 2}/V-s for the ZnO film deposited on the PET substrate. - Highlights: • Polyethylene terephthalate, polyvinyl butyral and polyimide were used as substrates. • ZnO films were prepared by cathodic arc plasma deposition. • ZnO films have different properties due to different substrates. • The microstructure control of ZnO film on polymer substrate is important.

  11. New Insights Into Volcanic Hazards in Western Mexico: Multiple Cone-Building Episodes at Arc Stratovolcanoes Revealed by 40Ar/39Ar Geochronology

    Science.gov (United States)

    Frey, H. M.; Lewis-Kenedi, K.; Lange, R. A.; Hall, C. M.; Delgado-Granados, H.

    2003-12-01

    The detailed eruptive histories of two andesitic stratocones, Volcáns Ceboruco and Tequila, in the western Mexican arc have been documented using 40Ar/39Ar geochronology. The volumes of these volcanoes were obtained with mapping, airphotos, and digital elevation models. The age and volume data constrain the rate and duration of major cone-building events, which bears on the longevity of the underlying upper-crustal magma chambers that fed the eruptions. The results indicate that at each stratovolcano there were two discrete cone-building events, separated by a hiatus. At V. Tequila, six samples from the edifice yielded dates (196 +/- 8, 196 +/- 19, 178 +/- 8, 191 +/- 13, 216 +/- 11, and 198 +/- 11 ka; errors are 1 sigma) with a mean eruption age of 196 +/- 12 ka. Thus the bulk of the main edifice ( ˜31 km3) erupted within 24 kyrs (at the 2 sigma level), leading to a cone-building rate of > 1.3 km3/kyr. After a hiatus of ˜110 kyrs, ˜14 km3 of andesite erupted along the NW and SE flanks of V. Tequila at 90 +/- 19 ka. The last activity at V. Tequila produced a ˜2 km3 parasitic cone at ˜60 ka. Since an eruption has not occurred in the last 60 kyrs, V. Tequila is often considered an extinct volcano. This may be the view held by the > 75,000 inhabitants of the town of Tequila located on the northern flanks. A similar history of two discrete cone-building events is found at V. Ceboruco, ˜75 km to the NW. Seven samples taken from various parts of the edifice, including the inner caldera wall, indicate an initial cone-building event at ˜45 ka in which ˜37 km3 of andesite erupted. After a hiatus of nearly 44 kyrs, a second eruptive period began ˜1000 years ago. The first eruption to occur after the hiatus was Plinian and released 3-4 km3 of dacite. In the last 1 kyr, 9.5 km3 of andesite and dacite erupted effusively, culminating in the historic 1870 flow. The sobering conclusion, in terms of volcanic hazards assessment, is that the only Plinian eruption to occur

  12. Discovery of an active shallow submarine silicic volcano in the northern Izu-Bonin Arc: volcanic structure and potential hazards of Oomurodashi Volcano (Invited)

    Science.gov (United States)

    Tani, K.; Ishizuka, O.; Nichols, A. R.; Hirahara, Y.; Carey, R.; McIntosh, I. M.; Masaki, Y.; Kondo, R.; Miyairi, Y.

    2013-12-01

    Oomurodashi is a bathymetric high located ~20 km south of Izu-Oshima, an active volcanic island of the northern Izu-Bonin Arc. Using the 200 m bathymetric contour to define its summit dimensions, the diameter of Oomurodashi is ~20 km. Oomurodashi has been regarded as inactive, largely because it has a vast flat-topped summit at 100 - 150 meters below sea level (mbsl). During cruise NT07-15 of R/V Natsushima in 2007, we conducted a dive survey in a small crater, Oomuro Hole, located in the center of the flat-topped summit, using the remotely-operated vehicle (ROV) Hyper-Dolphin. The only heat flow measurement conducted on the floor of Oomuro Hole during the dive recorded an extremely high value of 4,200 mW/m2. Furthermore, ROV observations revealed that the southwestern wall of Oomuro Hole consists of fresh rhyolitic lavas. These findings suggest that Oomurodashi is in fact an active silicic submarine volcano. To confirm this hypothesis, we conducted detailed geological and geophysical ROV Hyper-Dolphin (cruise NT12-19). In addition to further ROV surveys, we carried out single-channel seismic (SCS) surveys across Oomurodashi in order to examine the shallow structures beneath the current edifice. The ROV surveys revealed numerous active hydrothermal vents on the floor of Oomuro Hole, at ~200 mbsl, with maximum water temperature measured at the hydrothermal vents reaching 194°C. We also conducted a much more detailed set of heat flow measurements across the floor of Oomuro Hole, detecting very high heat flows of up to 29,000 mW/m2. ROV observations revealed that the area surrounding Oomuro Hole on the flat-topped summit of Oomurodashi is covered by extensive fresh rhyolitic lava and pumice clasts with minimum biogenetic or manganese cover, suggesting recent eruption(s). These findings strongly indicate that Oomurodashi is an active silicic submarine volcano, with recent eruption(s) occurring from Oomuro Hole. Since the summit of Oomurodashi is in shallow water, it

  13. Geochronology of the Hongniu-Hongshan porphyry and skarn Cu deposit, northwestern Yunnan province, China: Implications for mineralization of the Zhongdian arc

    Science.gov (United States)

    Peng, Hui-juan; Mao, Jing-wen; Pei, Rong-fu; Zhang, Chang-qing; Tian, Guang; Zhou, Yunman; Li, Jianxin; Hou, Lin

    2014-01-01

    The Hongniu-Hongshan porphyry and skarn copper deposit is located in the Triassic Zhongdian island arc, northwestern Yunnan province, China. Single-zircon laser ablation inductively coupled plasma mass spectrometry U-Pb dating suggests that the diorite porphyry and the quartz monzonite porphyry in the deposit area formed at 200 Ma and 77 Ma, respectively. A Re-Os isotopic date of molybdenite from the ore is 78.9 Ma, which indicates that in addition to the known Triassic Cu-(Au) porphyry systems, a Late Cretaceous porphyry Cu-Mo mineralization event also exists in the Zhongdian arc. The quartz monzonite porphyry shows characteristics of a magnetite series intrusion, with a high concentration of Al, K, Rb, Ba, and Pb, low amount of Ta, Ti, Y, and Yb, and a high ratio of Sr/Y (average 26.42). The Cretaceous porphyry also shows a strong fractionation between light and heavy rare earth elements (average (La/Yb)N 37.9), which is similar to those of the Triassic subduction-related diorite porphyry in the Hongniu-Hongshan deposit and the porphyry hosting the Pulang copper deposit. However, in contrast to the older intrusions, the quartz monzonite porphyry contains higher concentrations of large ion lithophile elements and Co, and lesser Sr and Zr. Therefore, whereas the Triassic porphyry Cu-(Au) mineralization is related to slab subduction slab in an arc setting, the quartz monzonite porphyry in the Hongniu-Hongshan deposit formed by the remelting of the residual oceanic slab combined with contributions from subduction-modified arc lithosphere and continental crust, which provided the metals for the Late Cretaceous mineralization.

  14. Incidence Angle Effect of Energetic Carbon Ions on Deposition Rate, Topography, and Structure of Ultrathin Amorphous Carbon Films Deposited by Filtered Cathodic Vacuum Arc

    KAUST Repository

    Wang, N.

    2012-07-01

    The effect of the incidence angle of energetic carbon ions on the thickness, topography, and structure of ultrathin amorphous carbon (a-C) films synthesized by filtered cathodic vacuum arc (FCVA) was examined in the context of numerical and experimental results. The thickness of a-C films deposited at different incidence angles was investigated in the light of Monte Carlo simulations, and the calculated depth profiles were compared with those obtained from high-resolution transmission electron microscopy (TEM). The topography and structure of the a-C films were studied by atomic force microscopy (AFM) and X-ray photoelectron spectroscopy (XPS), respectively. The film thickness decreased with the increase of the incidence angle, while the surface roughness increased and the content of tetrahedral carbon hybridization (sp 3) decreased significantly with the increase of the incidence angle above 45° , measured from the surface normal. TEM, AFM, and XPS results indicate that the smoothest and thinnest a-C films with the highest content of sp 3 carbon bonding were produced for an incidence angle of 45°. The findings of this study have direct implications in ultrahigh-density magnetic recording, where ultrathin and smooth a-C films with high sp 3 contents are of critical importance. © 2012 IEEE.

  15. Deglaciated areas of Kilimanjaro as a source of volcanic trace elements deposited on the ice cap during the late Holocene

    Science.gov (United States)

    Gabrielli, P.; Hardy, D. R.; Kehrwald, N.; Davis, M.; Cozzi, G.; Turetta, C.; Barbante, C.; Thompson, L. G.

    2014-06-01

    Ice fields on Kilimanjaro (5895 m a.s.l., Tanzania) are retreating and 85% of the ice cover has been lost since 1912. The degree to which this recession is exceptional during the Holocene is uncertain, as age control of the entire ice stratigraphy exists only for the very shallow and very bottom ice of the Northern Ice Field. This empirical evidence suggests that the Kilimanjaro ice cover may be a persistent Holocene feature, while a model based on maximum possible extent and a constant shrinkage rate of the summit glaciers suggests a cyclic decay time on the order of one to two centuries. Today the mass balance of these ice fields is negative and no persistent ice accumulation zones are observed over multiannual scales. The expanding deglaciated area within the Kilimanjaro caldera should act as an increasingly larger and productive source of volcanic-origin aeolian dust that is quickly deposited onto the surface of the adjacent ice fields, particularly in the seasonal absence of caldera snow cover. Variations in the local dust influx may directly influence albedo and the energy balance of these ice fields. Investigating the characteristics of insoluble material entrapped in the ice remnants of Kilimanjaro can thus provide insights into the extent of ice and/or continuity of the summit snow cover through time. Here we report the trace element composition linked to the insoluble particles entrapped in Holocene Kilimanjaro ice in the context of the current understanding of the past ice accumulation processes (including solid precipitations and ablation) contributing to build the horizontal caldera ice fields. For this purpose we analysed an ice core drilled to bedrock from the Northern Ice Field thought to span the late Holocene (2200 BC-1950 AD). The ultra low trace element concentrations recorded in this Kilimanjaro core are consistent with a generally low volcanic dust source availability (i.e. limited exposure of the deglaciated area in the caldera) and fairly

  16. Annealing effect of thermal spike in MgO thin film prepared by cathodic vacuum arc deposition

    Energy Technology Data Exchange (ETDEWEB)

    Zhu, Daoyun, E-mail: zhudy@gdut.edu.cn [Experiment Teaching Department, Guangdong University of Technology, Guangzhou 510006 (China); State Key Laboratory of Optoelectronic Materials and Technologies, School of Physics and Engineering, Sun Yat-sen University, Guangzhou 510275 (China); Zhao, Shoubai [School of Physics and Electronic Engineering, Guangzhou University, Guangzhou 510400 (China); Zheng, Changxi; Chen, Dihu [State Key Laboratory of Optoelectronic Materials and Technologies, School of Physics and Engineering, Sun Yat-sen University, Guangzhou 510275 (China); He, Zhenhui, E-mail: stshzh@mail.sysu.edu.cn [State Key Laboratory of Optoelectronic Materials and Technologies, School of Physics and Engineering, Sun Yat-sen University, Guangzhou 510275 (China)

    2013-12-16

    MgO films were prepared by using pulsed cathodic vacuum arc deposition technique. The substrate bias voltage was in the range of −150 to −750 V. Film structure was investigated by X-ray diffraction (XRD). The annealing effect of thermal spike produced by the impacting of energetic ions was analyzed. The calculated results showed that the lifetime of a thermal spike generated by an energetic ion with the energy of 150 eV was less than one picosecond and it was sufficient to allow Mg{sup 2+} or O{sup 2-} to move one bond length to satisfy the intrinsic stress relief in the affected volume. The MgO(200) lattice spacings of the films deposited at different bias voltages were all larger than the ideal value of 2.1056 Å. As the bias amplitude increased the lattice spacing decreased, which indicated that the compressive stress in the film was partially relieved with increasing impacting ion energy. The stress relief also could be reflected from the film orientation with bias voltage. The biaxial elastic modulus for MgO(100), MgO(110) and MgO(111) planes were calculated and they were M{sub (100)} = 199 GPa, M{sub (110)} = 335 GPa and M{sub (111)} = 340 GPa, respectively. The M values indicated that the preferred orientation will be MgO(200) due to the minimum energy configuration when the lattice strain was large. It was confirmed by the XRD results in our experiments. - Highlights: • MgO thin films with preferred orientation were obtained by CVAD technique. • Annealing effect of a thermal spike in MgO film was discussed. • Lattice spacing of MgO film decreased with the increase of bias voltage. • Film preferred orientation changed from (200) to (220) as the bias voltage increased.

  17. Characteristics of CrAlSiN + DLC coating deposited by lateral rotating cathode arc PVD and PACVD process

    Science.gov (United States)

    Lukaszkowicz, Krzysztof; Sondor, Jozef; Balin, Katarzyna; Kubacki, Jerzy

    2014-09-01

    Coating system composed of CrAlSiN film covered by diamond-like carbon (DLC)-based lubricant, deposited on hot work tool steel substrate was the subject of the research. The CrAlSiN and DLC layers were deposited by PVD lateral rotating ARC-cathodes (LARC) and PACVD technology on the X40CrMoV5-1 respectively. HRTEM investigation shows an amorphous character of DLC layer. It was found that the tested CrAlSiN layer has a nanostructural character with fine crystallites while their average size is less than 10 nm. Based on the XRD pattern of the CrAlSiN, the occurrence of fcc phase was only observed in the coating, the texture direction is perpendicular to the sample surface. Combined SEM, AES and ToF-SIMS studies confirmed assumed chemical composition and layered structure of the coating. The chemical distribution of the elements inside the layers and at the interfaces was analyzed by SEM and AES methods. It was shown that additional CrN layer is present between substrate and CrAlSiN coating. The atomic concentration of the particular elements of DLC and CrAlSiN layer was calculated from the XPS measurements. In sliding dry friction conditions the friction coefficient for the investigated elements is set in the range between 0.05 and 0.07. The investigated coating reveals high wear resistance. The coating demonstrated a dense cross-sectional morphology as well as good adhesion to the substrate.

  18. Density changes with substrate negative bias for ta-C films deposited by filter cathode vacuum arc

    Institute of Scientific and Technical Information of China (English)

    TAN Man-lin; ZHU Jia-qi; HAN Jie-cai; MENG Song-he

    2004-01-01

    Specular X-ray reflectivity (XRR) measurements were used to study the density and cross-section information of tetrahedral amorphous carbon (ta-C) films deposited by filter cathode vacuum arc(FCVA) system at different substrate bias. According to the correlation between density and substrate negative bias, it is found that the value of density reaches a maximum at -80 V bias. As the substrate bias increases or decreases, the density tends to lower gradually. Based on the density of diamond and graphite, sp3 bonding ratio of ta-C films was obtained from their corresponding density according to a simple equation between the two. And a similar parabolic variation was observed for ta-C films with the sp3 content changes with substrate negative bias. The mechanical properties such as hardness and elastic modulus were also measured and compared with the corresponding density for ta-C films. From the distribution of data points, a linear proportional correlation between them was found, which shows that the density is a critical parameter to characterize the structure variation for ta-C films.

  19. Wire + Arc Additive Manufacturing

    OpenAIRE

    Williams, Stewart W.; Martina, Filomeno; Addison, Adrian C.; Ding, Jialuo; Pardal, Goncalo; Colegrove, Paul A.

    2016-01-01

    Depositing large components (>10 kg) in titanium, aluminium, steel and other metals is possible using Wire + Arc Additive Manufacturing. This technology adopts arc welding tools and wire as feedstock for additive manufacturing purposes. High deposition rates, low material and equipment costs, and good structural integrity make Wire+Arc Additive Manufacturing a suitable candidate for replacing the current method of manufacturing from solid billets or large forgings, especially with regards to ...

  20. Subduction of continental material in the Banda Arc, Eastern Indonesia : Sr-Nd-Pb isotope and trace-element evidence from volcanics and sediments

    NARCIS (Netherlands)

    Vroon, Pieter Z.

    1992-01-01

    This thesis presents the results of a geochemical study of the Banda Arc (East Indonesia) where magma genesis is influenced by subducted source components that are controlled by an active arc-continent collision. The main objective of this study is to investigate the role of subducted continental

  1. Superhard carbon deposited by pulsed high-current arc as protective nanocoating for magnetic hard disks; Superharter Kohlenstoff abgeschieden mit gepulstem Hochstrombogen als Nanoschutzschicht fuer Magnetspeicherplatten

    Energy Technology Data Exchange (ETDEWEB)

    Neuhaeuser, M.; Hilgers, H. [IBM Mainz (Germany). Abt. 4627; Witke, T. [Infenion Dresden (Germany). Bereich PVD; Siemroth, P. [Fraunhofer-Institut fuer Werkstoffphysik und Schichttechnologie (IWS), Dresden (Germany)

    2001-08-01

    Superhard amorphous carbon films (ta-C) deposited by pulsed high-current arc (HCA) possess a good perspective to be used as future ultrathin protective coatings for magnetic hard disks. The ta-C coatings meet all demands concerning the mechanical, chemical and tribological properties required for corrosion and wear protective coatings with thicknesses of 2-3 nm. From the current point of view the deposition technique also qualifies for an industrial mass production. Consequently there is a very good prospect that in near future the high-current arc technique will be the method of choice for carbon deposition in industrial hard disk drive production. (orig.) [German] Superharte amorphe Kohlenstoffschichten (ta-C), die mit gepulstem Hochstrombogen (high-current arc, HCA) abgeschieden werden, besitzen ein hohes Potential als zukuenftige ultraduenne Schutzschichten fuer Magnetspeicherplatten. Die ta-C-Schichten erfuellen alle wesentlichen Anforderungen, die in mechanischer, chemischer und tribologischer Hinsicht an 2-3 nm dicke Verschleiss- und Korrosionsschutzschichten gestellt werden. Auch die Beschichtungstechnik ist aus jetziger Sicht fuer die Massenproduktion geeignet. Damit bestehen sehr gute Aussichten, dass in naher Zukunft die Hochstrombogenverdampfung die Methode der Wahl fuer die Kohlenstoffabscheidung in der industriellen Festplattenproduktion darstellt. (orig.)

  2. Influence of substrate structure on adhesion behavior of TiN and TiAl3/TiAlN coatings deposited by vacuum arc plasma

    Science.gov (United States)

    Vardanyan, E.; Ramazanov, K.; Yagafarov, I.; Budilov, V.; Agzamov, R.

    2017-05-01

    This paper presents the study of the influence of a substrate structure on the adhesion behavior of monolayer coatings TiN and multilayer coatings TiAl3 / TiAlN deposited by vacuum arc plasma. Martensitic steel with a coarse-grained (CG) and ultrafine-grained (UFG) structure was used for samples. The samples were subjected to ion nitriding in a glow discharge before coating deposition. Adhesion of the coatings was examined with CSM ScratchTEST. For samples with different structures, critical load was defined at which microcracks are formed in the coatings.

  3. The geochemistry and petrogenesis of volcanics and sheeted dikes from the Hatay (Kizildag) Ophiolite, southern Turkey: Possible formation with the Troodos Ophiolite, Cyprus, along fore-arc spreading centers

    Science.gov (United States)

    Lytwyn, J. N.; Casey, J. F.

    1993-08-01

    Geochemical and petrological investigations of the Hatay (Kizildag) Ophiolite, southern Turkey, indicate that the volcanics and sheeted dikes compositionally range from island-arc tholeiites and basaltic andesites to transitional boninitictype lavas formed within a supra-subduction zone environment. Geochemical modeling indicates that the compositional trends within both the sheeted dike and pillow basalt sections of Hatay cannot be related through fractional crystallization alone but require multiple parental magmas of differing compositions within each unit. The more refractory liquids (higher MgO, Ni and Cr coupled with lower concentrations of Ti, Zr, Y and REE) formed at lower pressures (shallower depths) through greater degrees of partial melting of a more depleted mantle source relative to less-refractory magmas which formed at higher pressures and possibly lower degrees of melting. The Hatay volcanics and dikes span the compositional range of Lower Pillow Lavas (LPLs) and Upper Pillow Lavas (UPLs) from the Troodos Complex, Cyprus, suggesting, along with other evidence, that the two ophiolites may be petrogenetically and tectonically related. Formation of the Hatay and Troodos ophiolites was possibly associated with extension within a fore-arc environment following compression and detachment along an intra-oceanic ridge system and development of a subduction zone. The range of parental liquid compositions for volcanics and dikes may reflect variable mixing of geochemically diverse melt increments generated within a polybaric melting column in the mantle wedge. The melting column may have additionally received contributions of LREE-enriched melts from deeper, more juvenile (fertile) sources. Formation of parental liquids through variable mixing of melt increments appears to be common to both the Hatay and Troodos ophiolites.

  4. Synthesis of carbon nanotubes by arc-discharge and chemical vapor deposition method with analysis of its morphology, dispersion and functionalization characteristics

    Directory of Open Access Journals (Sweden)

    Ritu Sharma

    2015-12-01

    Full Text Available In this paper, multi-walled carbon nanotubes are synthesized by arc-discharge and chemical vapor decomposition methods. Multi-walled carbon nanotubes are synthesized on thin film of nickel sputtered on silicon substrate by thermal chemical vapor deposition of acetylene at a temperature of 750°C. The flow of current in arc-discharge method varies in the range 50–200 A. Further arc-synthesized carbon nanotubes are characterized by X-ray diffraction (XRD, scanning electron microscopy (SEM, transmission electron microscopy (TEM, and the results are compared with nanotubes grown by chemical vapor deposition method. XRD result shows a characteristic peak (0 0 2 at 26.54° corresponding to the presence of carbon nanotubes. SEM and TEM results give morphology of as-synthesized multi-walled nanotubes. TEM results indicate synthesis of well-graphitized carbon nanotubes by arc-discharge method. Dispersion of arc-synthesized nanotubes in SDS solution under the effect of different sonication times is studied. Dispersion of nanotubes in SDS solution is analyzed using UV–vis–NIR spectroscopy and it shows an absorption peak at 260 nm. It was found that with the increase in sonication time, the absorption peak in UV–vis–NIR spectra will increase and optimum sonication time was 2 hours. Functionalization of synthesized carbon nanotubes by H2SO4 and HNO3 acids has been studied and analysis of functionalized groups has been done using FT-IR spectroscopy and compared and the results are reported in this paper. FT-IR spectroscopy verifies the presence of carboxylic groups attached to carbon nanotubes. These functional groups may change properties of carbon nanotubes and may be used in vast applications of carbon nanotubes.

  5. Effect of O2/Ar Gas Flow Ratios on Properties of Cathodic Vacuum Arc Deposited ZnO Thin Films on Polyethylene Terephthalate Substrate

    Directory of Open Access Journals (Sweden)

    Chien-Wei Huang

    2016-01-01

    Full Text Available Cathodic vacuum arc deposition (CVAD can obtain a good quality thin film with a low growth temperature and a high deposition rate, thus matching the requirement of film deposition on flexible electronics. This paper reported the room-temperature deposition of zinc oxide (ZnO thin films deposited by CVAD on polyethylene terephthalate (PET substrate. Microstructure, optical, and electrical measurements of the deposited ZnO thin films were investigated with various O2/Ar gas flow ratios from 6 : 1 to 10 : 1. The films showed hexagonal wurtzite crystal structure. With increasing the O2/Ar gas flow ratios, the c-axis (002 oriented intensity decreased. The crystal sizes were around 16.03 nm to 23.42 nm. The average transmittance values in the visible range of all deposited ZnO films were higher than 83% and the calculated band gaps from the absorption data were found to be around 3.1 to 3.2 eV. The resistivity had a minimum value in the 3.65 × 10−3 Ω·cm under the O2/Ar gas flow ratio of 8 : 1. The luminescence mechanisms of the deposited film were also investigated to understand the defect types of room-temperature grown ZnO films.

  6. The Late Cambrian Takaka Terrane, NW Nelson, New Zealand: Accretionary-prism development and arc collision followed by extension and fan-delta deposition at the SE margin of Gondwana

    Science.gov (United States)

    Pound, K. S.

    2013-12-01

    Re-evaluation of field and lab data indicates that the Cambrian portion of the Takaka Terrane in the Cobb Valley area of NW Nelson, New Zealand preserves the remnants of an accretionary prism complex, across which the Lockett Conglomerate fan-delta was deposited as a consequence of extension. Previous work has recognized that the structurally disrupted lower Takaka Terrane rocks present an amalgam of sedimentary and igneous rocks generated prior to convergence (Junction Formation) or during convergence (Devil River Volcanics Group, Haupiri Group), including arc-related and MORB components. Portions of the sequence have in the past been loosely described as an accretionary prism. Reevaluation of the detailed mapping, sedimentological and provenance studies shows that remnants of a stratigraphic sequence (Junction Formation, Devil River Volcanics Group, Haupiri Group) can be traced through 10 fault-bounded slices, which include a mélange-dominated slice (Balloon Mélange). These slices are the remnants of the accretionary prism; the stratigraphy within each slice generally youngs to the east, and the overall pattern of aging (based on relative age from provenance studies, sparse fossils, stratigraphic relations, and limited isotopic data) indicates that the older rocks generally dominate fault slices to the east, and younger rocks dominate fault slices to the west, delineating imbricate slices within an eastward-dipping subduction zone, in which the faults record a complex history of multi-phase reactivation. The Lockett Conglomerate is a ~500-m thick fan-delta conglomerate that is the preserved within one of the fault slices, where it is stratigraphically and structurally highest unit in the lower Takaka Terrane; it is also present as blocks within the Balloon Melange. The Lockett Conglomerate is marine at its base and transitions upwards to fluvial facies. The Lockett Conglomerate has previously been interpreted to result from erosion consequent on continued

  7. Comprehensive study of the seismotectonics of the eastern Aleutian arc and associated volcanic systems. Annual progress report, March 1, 1980-February 28, 1981

    Energy Technology Data Exchange (ETDEWEB)

    Jacob, K.H.; Davies, J.N.; House, L.

    1981-01-01

    Refined hypocenter locations beneath the Shumagin Islands seismic network of the eastern Aleutian arc, Alaska, provide for the first time conclusive evidence for a double-sheeted dipping seismic (Benioff) zone in this arc. This refined seismicity structure was obtained in the arc section centered on the Shumagin seismic gap. A thorough review of three seismic gaps in the eastern Aleutian arc shows a high potential for great earthquakes within the next one to two decades in the Shumagin and Yakataga seismic gaps, and a less certain potential for a large or great earthquake in the possible Unalaska gap. A tilt reversal was geodetically observed to have occurred in 1978/79 in the forearc region of the Shumagin gap and could indicate the onset of a precursory strain relief episode prior to a great quake. A comparative study of the Pavlof volcano seismicity with that of other recently active volcanoes (i.e., Mt. St. Helens) indicates that island-arc (explosive-type) volcanoes respond to small ambient, periodic stress changes (i.e., tides). Stress drop measurements from earthquakes on the main thrust zone indicate high stress drops within the seismic gap regions of the Aleutian arc and low stress drops outside the gap region.

  8. Discovery of double-peaking potassic volcanic rocks in Langshan Group of the Tanyaokou hydrothermal-sedimentary deposit, Inner Mongolia, and its indicating significance

    Institute of Scientific and Technical Information of China (English)

    PENG; Runmin; ZHAI; Yusheng; WANG; Zhigang; HAN; Xuefeng

    2005-01-01

    It is revealed that the protolith of gray-light brown potash-feldspar-leucogranulites and granulites in the 2nd formation of the LG in Tanyaokou deposit are quartz kerotophyre of synsedimentary eruption based on the following facts and features: (1) The rocks look compact and homogeneous without obvious crystals with naked eyes; (2) they contain blastoporphyritic or glomeroporphyritic and blasto-crystalloclastic crystals consisting of quartz with wavy extinction and albite with obvious alteration and deformation; (3) they also contain radiated and fibrous blasto-microspherulitic texture and swallow-tailed bifurcate and blasto-hollow-skeleton crystal texture, representing the rapid cooling characteristic of the magma during submarine volcanic eruption; (4) the major chemical compositions of the rocks are: SiO2 = 70.80%―76.00%, K2O (4.83%―6.22%)>Na2O(2.78%―3.80%), and K2O+Na2O = 8.63%―9.00%; and (5) their petrochemical diagrams indicate that they are volcanic rocks. Together with the characteristic that they occur in the same sequence with potassic spilite (SiO2 = 46.12%―50.68%, K2O = 4.23%―5.93%>Na2O = 2.15%―3.14%, K2O+Na2O = 6.51%―8.08%), it can be confirmed that the volcanics occurring in the 2nd Formation of the LG in Tanyaokou district are double-peaking potassic volcanic rocks. The discovery, together with the tuffs with ore minerals and the distribution of lead isotopic as well as the value of Co/Ni of pyrites >1 showing the obvious endogenic metalization, can prove that the Tanyaokou deposit is an untypical SEDEX-type deposit formed in the extension fault basin in the Mesoproterozonic aulacogen of the northern margin of the North China Platform, and its metallogenesis is related to the synsedimentary volcanic activities and the hydrothermal exhalation, and both the ore-forming material source and volcanics came from mantle or lower crust. These facts mentioned above, together with the meta-volcanic rocks (double-peaking) found in the

  9. Structural evolution of Ti destroyable interlayer in large-size diamond film deposition by DC arc plasma jet

    Science.gov (United States)

    Guo, Jianchao; Li, Chengming; Liu, Jinlong; Wei, Junjun; Chen, Liangxian; Hua, Chenyi; Yan, Xiongbo

    2016-05-01

    The addition of titanium (Ti) interlayer was verified to reduce the residual stress of diamond films by self-fracturing and facilitate the harvest of a crack-free free-standing diamond film prepared by direct current (DC) arc plasma jet. In this study, the evolution of the Ti interlayer between large-area diamond film and substrate was studied and modeled in detail. The evolution of the interlayer was found to be relevant to the distribution of the DC arc plasma, which can be divided into three areas (arc center, arc main, and arc edge). The formation rate of titanium carbide (TiC) in the arc main was faster than in the other two areas and resulted in the preferred generation of crack in the diamond film in the arc main during cooling. Sandwich structures were formed along with the growth of TiC until the complete transformation of the Ti interlayer. The interlayer released stress via self-fracture. Avoiding uneven fragile regions that formed locally in the interlayer and achieving cooperatively released stress are crucial for the preparation of large crack-free diamond films.

  10. Deposition of thin layers of boron nitrides and hydrogenated microcrystalline silicon assisted by high current direct current arc plasma; Deposition assistee par un plasma a arc a haut courant continu de couches minces de Nitrure de Bore et de Silicium microcristallin hydrogene

    Energy Technology Data Exchange (ETDEWEB)

    Franz, D. [Ecole Polytechnique Federale de Lausanne, Centre de Recherches en Physique des Plasmas (CRPP), CH-1015 Lausanne (Switzerland)

    1999-09-01

    In the frame of this thesis, a high current direct current arc (HCDCA) used for the industrial deposition of diamond, has been adapted to study the deposition of two types of coatings: a) boron nitride, whose cubic phase is similar to diamond, for tribological applications, b) hydrogenated microcrystalline silicon, for applications in the semiconductor fields (flat panel displays, solar cells,...). For the deposition of these coatings, the substrates were placed in the diffusion region of the arc. The substrate heating is mainly due to atomic species recombining on its surface. The deposition temperature, varying from 300 to 900 {sup o}C according to the films deposited, is determined by the substrate position, the arc power and the injected gas fluxes, without the use of any external heating or cooling system. Measurements performed on the arc plasma show that the electronic temperature is around 2 eV (23'000 K) while the gas temperature is lower than 5500 K. Typical electronic densities are in the range of 10{sup 12}-10{sup 1'}3 cm{sup -3}. For the deposition of boron nitride films, different boron precursors were used and a wide parameter range was investigated. The extreme difficulty of synthesising cubic boron nitride films by chemical vapour deposition (CVD) did not allow to stabilize the cubic phase of boron nitride in HCDCA. Coatings resulted in hexagonal or amorphous boron nitride with a chemical composition close to stoichiometric. The presence of hydrogen leads to the deposition of rough and porous films. Negative biasing of the samples, for positive ion bombardment, is commonly used to stabilize the cubic phase. In HCDCA and in our biasing range, only a densification of the films could be observed. A boron nitride deposition plasma study by infrared absorption spectroscopy in a capacitive radio frequency reactor has demonstrated the usefulness of this diagnostic for the understanding of the various chemical reactions which occur in this kind

  11. Effect of substrate bias in nitrogen incorporated amorphous carbon films with embedded nanoparticles deposited by filtered cathodic jet carbon arc technique

    Energy Technology Data Exchange (ETDEWEB)

    Panwar, O.S., E-mail: ospanwar@mail.nplindia.ernet.in [Amorphous and Microcrystalline Silicon Solar Cell Group, Physics of Energy Harvesting Division, National Physical Laboratory (C.S.I.R.), Dr. K.S. Krishnan Road, New Delhi-110012 (India); Kumar, Sushil; Ishpal,; Srivastava, A.K.; Chouksey, Abhilasha; Tripathi, R.K.; Basu, A. [Amorphous and Microcrystalline Silicon Solar Cell Group, Physics of Energy Harvesting Division, National Physical Laboratory (C.S.I.R.), Dr. K.S. Krishnan Road, New Delhi-110012 (India)

    2012-02-15

    Highlights: Black-Right-Pointing-Pointer a-C: N films having nanoparticles were deposited by filtered cathodic jet carbon arc (FCJCA) technique. Black-Right-Pointing-Pointer The effect of negative substrate bias on the properties of a-C: N films embedded with nanoparticles have been studied. Black-Right-Pointing-Pointer The properties of a-C: N films deposited by FCJCA technique have been compared with ta-C: N films deposited by FCVA process. - Abstract: The properties of nitrogen incorporated amorphous carbon (a-C: N) films with embedded nanoparticles, deposited using a filtered cathodic jet carbon arc technique, are reported. X-ray diffraction, high resolution transmission electron microscope and Raman spectroscopy measurements reveal an amorphous structure, but on closer examination the presence of clusters of nanocarbon single crystals with d-spacing close to diamond cubic-phase have also been identified. The effect of substrate bias on the microstructure, conductivity, activation energy, optical band gap, optical constants, residual stress, hardness, elastic modulus, plastic index parameter, percentage elastic recovery and density of states of a-C: N films have been studied and the properties obtained are found to depend on the substrate bias.

  12. Effect of deposition parameters on mechanical properties of TiN films coated on 2A12 aluminum alloys by arc ion plating (AIP)

    Institute of Scientific and Technical Information of China (English)

    AWAD Samir Hamid; QIAN Han-cheng

    2005-01-01

    TiN films were deposited on 2A12 aluminum alloy by arc ion plating (AIP). The Vickers hardness of the films deposited at different bias voltages and different nitrogen gas pressures, and that of the substrate were measured. The surface roughness of the TiN films diposited at -30 V and -80 V respectively and at different nitrogen gas pressure was measured also. The mass loss of TiN films deposited at 0 V, -30 V and -80 V respectively were analyzed in dry sand rubber wheel abrasive wear tests and wet ones in comparison with uncoated Al alloy and austenitic stainless steel (AISI 316L). It is revealed that the highest hardness of the TiN film is obtained at a bias voltage of -30 V and a N2 gas pressure of 0.5 Pa. The surface roughness of the film is larger at -80 V than that at -30 V and reduces as the increase of the N2 gas pressure. The mass loss of TiN-film coated 2A12 aluminum alloy is remarkably less than that of uncoated Al alloy and also that of AISI 316L, which indicates that the abrasive wear rate is greatly reduced by the application of TiN coating. TiN coating deposited by arc ion plating (AIP) technique on aluminum alloy can be a potential coating for machine parts requiring preciseness and lightness.

  13. Geology, Genetic Types and Metallogeny of Gold Deposits in the Eastern Tianshan, Xinjiang

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    As a typical Palaeozoic island arc system, the eastern Tianshan area, Xinjiang, is different from eastern China but similar to the Meso-Cenozoic island arc metallogenic provinces along the coast of the Pacific Ocean in metallogenic environment, geology and geochemistry. Three types of gold deposits, ductile shear zone-hosted gold deposits (Kanggur `), magmatic hydrothermal gold deposits (Jinwozi) and volcanic- or subvolcanic-hosted gold deposits (Xitan and Mazhuangshan), have been identified in this area. Regionally, gold deposits are structurally controlled by the Kanggur Tag ductile shear zone, Shaquanzi fault, Hongliuhe fault and Yamansu fault. Generally, gold mineralization occurs in the transition zones from volcanic rocks to sedimentary rocks. The horizon bearing well-developed jasper is an important indicator for gold mineralization. Each of the three types of gold deposits has its distinctive metallogenic background and geological-geochemical characteristics.

  14. Diagnosis of gas phase near the substrate surface in diamond film deposition by high-power DC arc plasma jet CVD

    Institute of Scientific and Technical Information of China (English)

    Zuyuan Zhou; Guangchao Chen; Bin Li; Weizhong Tang; Fanxiu Lv

    2007-01-01

    Optical emission spectroscopy (OES) was used to study the gas phase composition near the substrate surface during diamond deposition by high-power DC arc plasma jet chemical vapor deposition (CVD). C2 radical was determined as the main carbon radical in this plasma atmosphere. The deposition parameters, such as substrate temperature, anode-substrate distance, methane concentration, and gas flow rate, were inspected to find out the influence on the gas phase. A strong dependence of the concentrations and distribution of radicals on substrate temperature was confirmed by the design of experiments (DOE). An explanation for this dependence could be that radicals near the substrate surface may have additional ionization or dissociation and also have recombination,or are consumed on the substrate surface where chemical reactions occur.

  15. Provenance of the Walash-Naopurdan back-arc-arc clastic sequences in the Iraqi Zagros Suture Zone

    Science.gov (United States)

    Ali, Sarmad A.; Sleabi, Rajaa S.; Talabani, Mohammad J. A.; Jones, Brian G.

    2017-01-01

    Marine clastic rocks occurring in the Walash and Naopurdan Groups in the Hasanbag and Qalander areas, Kurdistan region, Iraqi Zagros Suture Zone, are lithic arenites with high proportions of volcanic rock fragments. Geochemical classification of the Eocene Walash and Oligocene Naopurdan clastic rocks indicates that they were mainly derived from associated sub-alkaline basalt and andesitic basalt in back-arc and island arc tectonic settings. Major and trace element geochemical data reveal that the Naopurdan samples are chemically less mature than the Walash samples and both were subjected to moderate weathering. The seaway in the southern Neotethys Ocean was shallow during both Eocene and Oligocene permitting mixing of sediment from the volcanic arcs with sediment derived from the Arabian continental margin. The Walash and Naopurdan clastic rocks enhance an earlier tectonic model of the Zagros Suture Zone with their deposition occurring during the Eocene Walash calc-alkaline back-arc magmatism and Early Oligocene Naopurdan island arc magmatism in the final stages of intra-oceanic subduction before the Miocene closure and obduction of the Neotethys basin.

  16. Nitrogen doping for adhesion improvement of DLC film deposited on Si substrate by Filtered Cathodic Vacuum Arc (FCVA) technique

    Energy Technology Data Exchange (ETDEWEB)

    Bootkul, D., E-mail: mo_duangkhae@hotmail.com [Department of General Science, Faculty of Science, Srinakharinwirot University, Bangkok 10110 (Thailand); Supsermpol, B.; Saenphinit, N. [Western Digital Company, Ayutthaya 13160 (Thailand); Aramwit, C. [Plasma and Beam Physics Research Facility, Department of Physics and Materials Science, Faculty of Science, Chiang Mai University, Chiang Mai 50202 (Thailand); Intarasiri, S., E-mail: saweat@gmail.com [Science and Technology Research Institute, Chiang Mai University, Chiang Mai 50202 (Thailand)

    2014-08-15

    Diamond-like carbon (DLC) films have been used in many applications due to their attractive combination of properties including chemical inertness, corrosion protection, biocompatibility, high hardness, and low wear rates. However, they still have some limitations such as high internal stresses and low toughness which lead to poor adhesion of films. Synthesis of nitrogen-doped DLC (N-DLC) offers the possibility of overcoming these limitations. In this study, DLC films, namely tetrahedral amorphous carbon (ta-C) and nitrogen doped tetrahedral amorphous carbon (ta-C:N) were deposited on single crystalline Si wafer substrates using the Filtered Cathodic Vacuum Arc (FCVA) technique. Film characterizations were carried out by Raman spectroscopy, atomic force microscopy (AFM), scanning electron microscopy (SEM), triboindenter tester and nano-scratch tester. Measurement results showed that intentionally doping with nitrogen reduced the carbon sp{sup 3} content and increased the surface roughness in comparison with that of pure ta-C films. The hardness measurement confirmed the Raman and AFM analyses that adding nitrogen in ta-C films decreased the hardness, especially with high nitrogen content. However, the nano-scratch test revealed the increasing of the critical load with nitrogen. This work, then, extended its scope to investigate the properties of double-layer ta-C films which were composed of ta-C:N interlayer of various thickness around 10–30 nm and ta-C top-layer with thickness of around 80 nm. Microstructure characterization demonstrated that a ta-C:N interlayer gradually decreased the sp{sup 3} fraction in the films and increased film roughness whenever the ta-C:N interlayer thickness increased. In this structure, the tribological property in terms of adhesion to the Si substrate was significantly improved by about 20–90%, but the mechanical property in terms of hardness was gradually degraded by about 2–10%, compared to pure ta-C film, when the ta

  17. Petrology and geochemistry of volcanic rocks from the island of Panarea: implications for mantle evolution beneath the Aeolian island arc (southern Tyrrhenian sea)

    Science.gov (United States)

    Calanchi, N.; Peccerillo, A.; Tranne, C. A.; Lucchini, F.; Rossi, P. L.; Kempton, P.; Barbieri, M.; Wu, T. W.

    2002-06-01

    Major, trace element and radiogenic isotope (Sr, Nd, Pb) data are reported for a suite of rocks from the Panarea volcano, a large structure that is largely hidden below sea level and outcrops only as a group of small islands between Lipari-Vulcano and Stromboli in the eastern Aeolian arc. The exposed rocks mostly consist of high-potassium calc-alkaline (HKCA) andesites, dacites and some rhyolites; shoshonitic basalts have been collected from submarine centres; mafic calc-alkaline (CA) rocks occur as thin layers of late-erupted strombolian scoriae. Major and trace element data are scattered, but define generally linear trends on inter-element diagrams; Sr-isotope ratios do not display significant increase with evolution, although rough positive trends of 87Sr/ 86Sr versus SiO 2 and Rb/Sr can be recognised within some units. The mafic rocks display varying enrichment in potassium, from CA to shoshonitic compositions, and are characterised by variable abundances of incompatible trace elements, which increase with potassium. There is an increase of 87Sr/ 86Sr ratios and a decrease of 143Nd/ 144Nd and 206Pb/ 204Pb ratios from CA to HKCA and shoshonitic mafic rocks. The scattered and incomplete nature of the outcrops make it difficult to constrain magmatic evolution at Panarea; geochemical and isotopic data suggest that AFC and mixing were important evolutionary processes. However, geochemical modelling does not support the possibility that the first-order compositional variations observed in the mafic rocks are the result of these processes, and suggests a genesis in a heterogeneous mantle source. Recent studies have highlighted strong differences in terms of incompatible trace element ratios and isotopic signatures, between the western-central and the eastern Aeolian arc. Rocks from the western islands (Alicudi, Filicudi, Salina, Vulcano) have typical magmatic arc geochemical signatures and relatively unradiogenic Sr-isotope compositions. By contrast, the eastern

  18. STUDY ON DEPOSITION OF MAGNETIC FILMS USING ARC ION PLATING%电弧离子镀沉积磁性薄膜的研究

    Institute of Scientific and Technical Information of China (English)

    常正凯; 肖金泉; 陈育秋; 刘山川; 宫骏; 孙超

    2012-01-01

    Arc ion plating (AIP) has been widely used for depositing various kinds of coatings due to the excellent characteristics of high deposition rate, convenient parameter control, high degree of ionization in the target material, good coating-substrate adhesion, flexibility of target arrangements and merits of producing coatings with high packing density. Magnetic films, with a few micrometers or less, could be utilized in the electronics industry, such as magnetic recording, magnetic microelectrome-chanical systems, magneto optical modulator, and so on. In AIP process, due to magnetic shielding and self-induced magnetic field, arc spot on the surface of the magnetic target moved outside all the time, and the erosion of the magnetic target could not be stable. In this study, arc spot outside moving and unstable erosion of the magnetic target in arc ion plating have been investigated. The distribution of the magnetic field of the nonmagnetic target and the magnetic target under an additional magnetic field was simulated by the finite element method (FEM). The effect of magnetic field on the arc spot movement was researched. With the physical mechanism of the arc spot discharge, the feasibility on the solution of the application problem of the magnetic target has been discussed by the program of the composited structure target, which were composed of magnetic target materials and target shell of low saturation vapor pressure metal, target shell of insulating ceramics, or target shell of soft magnetic metal. The results showed that all these solutions could solve the problem of arc spot outside moving efficiently. In the study, the transition temperature is (136.6±23.0) ℃ in the solutions of the target shell of low saturation vapor pressure metal or insulating ceramics, during which the arc striking frequently transformed to the controlled movement of arc spot.%研究了电弧离子镀磁性靶材使用过程中发生“跑弧”并导致靶材无法稳定刻蚀的问

  19. Eruption processes and deposit characteristics at the monogenetic Mt. Gambier Volcanic Complex, SE Australia: implications for alternating magmatic and phreatomagmatic activity

    Science.gov (United States)

    van Otterloo, Jozua; Cas, Raymond A. F.; Sheard, Malcolm J.

    2013-08-01

    The ˜5 ka Mt. Gambier Volcanic Complex in the Newer Volcanics Province, Australia is an extremely complex monogenetic, volcanic system that preserves at least 14 eruption points aligned along a fissure system. The complex stratigraphy can be subdivided into six main facies that record alternations between magmatic and phreatomagmatic eruption styles in a random manner. The facies are (1) coherent to vesicular fragmental alkali basalt (effusive/Hawaiian spatter and lava flows); (2) massive scoriaceous fine lapilli with coarse ash (Strombolian fallout); (3) bedded scoriaceous fine lapilli tuff (violent Strombolian fallout); (4) thin-medium bedded, undulating very fine lapilli in coarse ash (dry phreatomagmatic surge-modified fallout); (5) palagonite-altered, cross-bedded, medium lapilli to fine ash (wet phreatomagmatic base surges); and (6) massive, palagonite-altered, very poorly sorted tuff breccia and lapilli tuff (phreato-Vulcanian pyroclastic flows). Since most deposits are lithified, to quantify the grain size distributions (GSDs), image analysis was performed. The facies are distinct based on their GSDs and the fine ash to coarse+fine ash ratios. These provide insights into the fragmentation intensities and water-magma interaction efficiencies for each facies. The eruption chronology indicates a random spatial and temporal sequence of occurrence of eruption styles, except for a "magmatic horizon" of effusive activity occurring at both ends of the volcanic complex simultaneously. The eruption foci are located along NW-SE trending lineaments, indicating that the complex was fed by multiple dykes following the subsurface structures related to the Tartwaup Fault System. Possible factors causing vent migration along these dykes and changes in eruption styles include differences in magma ascent rates, viscosity, crystallinity, degassing and magma discharge rate, as well as hydrological parameters.

  20. Energy Deposition and Quench Level Calculations for Millisecond and Steady-State Quench Tests of LHC Arc Quadrupoles at 4 TeV

    CERN Document Server

    Shetty, N V; Chetvertkova, V; Lechner, A; Priebe, A; Sapinski, M; Verweij, A; Wollmann, D

    2014-01-01

    In 2013, beam-induced quench tests with 4 TeV protons were performed to probe the quench level of LHC arc quadrupole magnets at timescales corresponding to millisecond beam losses and steady-state losses. As the energy deposition in magnet coils cannot be measured directly, this study presents corresponding FLUKA simulations as well as estimates of quench levels derived with the QP3 code. Furthermore, beam loss monitor (BLM) signals were simulated and benchmarked against the measurements. Simulated and measured BLM signals are generally found to agree within 30 percent.

  1. The Sierra de Mil Cumbres, Michoacán, México: Transitional volcanism between the Sierra Madre Occidental and the Trans-Mexican Volcanic Belt

    Science.gov (United States)

    Gómez-Vasconcelos, Martha Gabriela; Garduño-Monroy, Víctor Hugo; Macías, José Luis; Layer, Paul W.; Benowitz, Jeff A.

    2015-08-01

    The Sierra de Mil Cumbres is a Miocene volcanic range located in central México, in the north-eastern part of the State of Michoacán, near the city of Morelia. Structurally it is a ENE-trending horst that covers an area of 1022 km2 (approximately 20 km wide × 60 km long) and contains exposures of chemically-bimodal volcanism in the form of ignimbrites, lava domes, lava flows, cinder cones, and related deposits. The main volcanic manifestations of this range are the La Escalera Caldera (16.3-23 Ma), the Garnica Volcanic Complex (18.3-17.9 Ma), the Atécuaro Caldera (16.3-19.4 Ma), and the Indaparapeo Volcanic Complex (14.1-17.5 Ma). The Sierra de Mil Cumbres stands in space and time at the intersection between the Miocene-Recent Trans-Mexican Volcanic Belt and the Late Cretaceous-Early Miocene Sierra Madre Occidental, and so provides new insights into the geological evolution of central México. Arc volcanism in the Sierra de Mil Cumbres was initiated by a massive NNW-SSE extension, probably during the counterclockwise rotation of the Sierra Madre Occidental. New geological mapping, stratigraphic analysis, detailed geochemistry and 40Ar/39Ar geochronology demonstrates that this intra-plate volcanism was emplaced between 14 and 23 Ma.

  2. Deposition of duplex Al 2O 3/aluminum coatings on steel using a combined technique of arc spraying and plasma electrolytic oxidation

    Science.gov (United States)

    Gu, Weichao; Shen, Dejiu; Wang, Yulin; Chen, Guangliang; Feng, Wenran; Zhang, Guling; Fan, Songhua; Liu, Chizi; Yang, Size

    2006-02-01

    Plasma electrolytic oxidation (PEO) is a cost-effective technique that can be used to prepare ceramic coatings on metals such as Ti, Al, Mg, Nb, etc., and their alloys, but this promising technique cannot be used to modify the surface properties of steels, which are the most widely used materials in engineering. In order to prepare metallurgically bonded ceramic coatings on steels, a combined technique of arc spraying and plasma electrolytic oxidation (PEO) was adopted. In this work, metallurgically bonded ceramic coatings on steels were obtained using this method. We firstly prepared aluminum coatings on steels by arc spraying, and then obtained the metallurgically bonded ceramic coatings on aluminum coatings by PEO. The characteristics of duplex coatings were analyzed by X-ray diffractometer (XRD) and scanning electron microscopy (SEM). The corrosion and wear resistance of the ceramic coatings were also studied. The results show that, duplex Al 2O 3/aluminum coatings have been deposited on steel substrate after the combined treatment. The ceramic coatings are mainly composed of α-Al 2O 3, γ-Al 2O 3, θ-Al 2O 3 and some amorphous phase. The duplex coatings show favorable corrosion and wear resistance properties. The investigations indicate that the combination of arc spraying and plasma electrolytic oxidation proves a promising technique for surface modification of steels for protective purposes.

  3. The conjunction of factors that lead to formation of giant gold provinces and deposits in non-arc settings

    Directory of Open Access Journals (Sweden)

    David I. Groves

    2016-05-01

    In contrast to their province scale similarities, the different giant gold deposit styles show contrasting critical controls at the district to deposit scale. For orogenic gold deposits, the giants appear to have formed by conjunction of a greater number of parameters to those that control smaller deposits, with resultant geometrical and lithostratigraphic complexity as a guide to their location. There are few giant IRGS due to their inferior fluid-flux systems relative to orogenic gold deposits, and those few giants are essentially preservational exceptions. Many Carlin-type deposits are giants due to the exceptional conjunction of both structural and lithological parameters that caused reactive and permeable rocks, enriched in syngenetic gold, to be located below an impermeable cap along antiformal “trends”. Hydrocarbons probably played an important role in concentrating metal. The supergiant Post-Betze deposit has additional ore zones in strain heterogeneities surrounding the pre-gold Goldstrike stock. All unequivocal IOCG deposits are giant or near-giant deposits in terms of gold-equivalent resources, partly due to economic factors for this relatively poorly understood, low Cu-Au grade deposit type. The supergiant Olympic Dam deposit, the most shallowly formed deposit among the larger IOCGs, probably owes its origin to eruption of volatile-rich hybrid magma at surface, with formation of a large maar and intense and widespread brecciation, alteration and Cu-Au-U deposition in a huge rock volume.

  4. Structural, nanomechanical and variable range hopping conduction behavior of nanocrystalline carbon thin films deposited by the ambient environment assisted filtered cathodic jet carbon arc technique

    Energy Technology Data Exchange (ETDEWEB)

    Panwar, O.S., E-mail: ospanwar@mail.nplindia.ernet.in [Polymorphic Carbon Thin Films Group, Physics of Energy Harvesting Division, CSIR-National Physical Laboratory, Dr. K. S. Krishnan Road, New Delhi - 110 012 (India); Rawal, Ishpal; Tripathi, R.K. [Polymorphic Carbon Thin Films Group, Physics of Energy Harvesting Division, CSIR-National Physical Laboratory, Dr. K. S. Krishnan Road, New Delhi - 110 012 (India); Srivastava, A.K. [Electron and Ion Microscopy, Sophisticated and Analytical Instruments, CSIR-National Physical Laboratory, Dr. K. S. Krishnan Road, New Delhi - 110 012 (India); Kumar, Mahesh [Ultrafast Opto-Electronics and Tetrahertz Photonics Group, CSIR-National Physical Laboratory, Dr. K. S. Krishnan Road, New Delhi - 110 012 (India)

    2015-04-15

    Highlights: • Nanocrystalline carbon thin films are grown by filtered cathodic jet carbon arc process. • Effect of gaseous environment on the properties of carbon films has been studied. • The structural and nanomechanical properties of carbon thin films have been studied. • The VRH conduction behavior in nanocrystalline carbon thin films has been studied. - Abstract: This paper reports the deposition and characterization of nanocrystalline carbon thin films by filtered cathodic jet carbon arc technique assisted with three different gaseous environments of helium, nitrogen and hydrogen. All the films are nanocrystalline in nature as observed from the high resolution transmission electron microscopic (HRTEM) measurements, which suggests that the nanocrystallites of size ∼10–50 nm are embedded though out the amorphous matrix. X-ray photoelectron spectroscopic studies suggest that the film deposited under the nitrogen gaseous environment has the highest sp{sup 3}/sp{sup 2} ratio accompanied with the highest hardness of ∼18.34 GPa observed from the nanoindentation technique. The film deposited under the helium gaseous environment has the highest ratio of the area under the Raman D peak to G peak (A{sub D}/A{sub G}) and the highest conductivity (∼2.23 S/cm) at room temperature, whereas, the film deposited under the hydrogen environment has the lowest conductivity value (2.27 × 10{sup −7} S/cm). The temperature dependent dc conduction behavior of all the nanocrystalline carbon thin films has been analyzed in the light of Mott’s variable range hopping (VRH) conduction mechanism and observed that all the films obey three dimension VRH conduction mechanism for the charge transport.

  5. Analysis of early bacterial communities on volcanic deposits on the island of Miyake (Miyake-jima), Japan: a 6-year study at a fixed site.

    Science.gov (United States)

    Fujimura, Reiko; Sato, Yoshinori; Nishizawa, Tomoyasu; Nanba, Kenji; Oshima, Kenshiro; Hattori, Masahira; Kamijo, Takashi; Ohta, Hiroyuki

    2012-01-01

    Microbial colonization on new terrestrial substrates represents the initiation of new soil ecosystem formation. In this study, we analyzed early bacterial communities growing on volcanic ash deposits derived from the 2000 Mount Oyama eruption on the island of Miyake (Miyake-jima), Japan. A site was established in an unvegetated area near the summit and investigated over a 6-year period from 2003 to 2009. Collected samples were acidic (pH 3.0-3.6), did not utilize any organic substrates in ECO microplate assays (Biolog), and harbored around 106 cells (g dry weight)(-1) of autotrophic Fe(II) oxidizers by most-probable-number (MPN) counts. Acidithiobacillus ferrooxidans, Acidithiobacillus ferrivorans, and the Leptospirillum groups I, II and III were found to be abundant in the deposits by clone library analysis of bacterial 16S rRNA genes. The numerical dominance of Acidithiobacillus ferrooxidans was also supported by analysis of the gene coding for the large subunit of the form I ribulose 1,5-bisphosphate carboxylase/oxygenase (RubisCO). Comparing the 16S rRNA gene clone libraries from samples differing in age, shifts in Fe(II)-oxidizing populations seemed to occur with deposit aging. The detection of known 16S rRNA gene sequences from Fe(III)-reducing acidophiles promoted us to propose the acidity-driven iron cycle for the early microbial ecosystem on the deposit.

  6. Time relationships between volcanism-plutonism-alteration-mineralization in Cu-stratabound ore deposits from the Michilla mining district, northern Chile: a 40Ar/39Ar geochronological approach

    Science.gov (United States)

    Oliveros, Verónica; Tristá-Aguilera, Dania; Féraud, Gilbert; Morata, Diego; Aguirre, Luis; Kojima, Shoji; Ferraris, Fernando

    2008-01-01

    The Michilla mining district comprises one of the most important stratabound and breccia-style copper deposits of the Coastal Cordillera of northern Chile, hosted by the Middle Jurassic volcanic rocks of the La Negra Formation. 40Ar/39Ar analyses carried out on igneous and alteration minerals from volcanic and plutonic rocks in the district allow a chronological sequence of several magmatic and alteration events of the district to be established. The first event was the extrusion of a thick lava series of the La Negra Formation, dated at 159.9 ± 1.0 Ma (2 σ) from the upper part of the series. A contemporaneous intrusion is dated at 159.6 ± 1.1 Ma, and later intrusive events are dated at 145.5 ± 2.8 and 137.4 ± 1.1 Ma, respectively. Analyzed alteration minerals such as adularia, sericite, and actinolite apparently give valid 40Ar/39Ar plateau and miniplateau ages. They indicate the occurrence of several alteration events at ca. 160-163, 154-157, 143-148, and 135-137 Ma. The first alteration event, being partly contemporaneous with volcanic and plutonic rocks, was probably produced in a high thermal gradient environment. The later events may be related either to a regional low-grade hydrothermal alteration/metamorphism process or to plutonic intrusions. The Cu mineralization of the Michilla district is robustly bracketed between 163.6 ± 1.9 and 137.4 ± 1.1 Ma, corresponding to dating of actinolite coexisting with early-stage chalcocite and a postmineralization barren dyke, respectively. More precisely, the association of small intrusives (a dated stock from the Michilla district) with Cu mineralization in the region strongly suggests that the main Michilla ore deposit is related to a magmatic/hydrothermal event that occurred between 157.4 ± 3.6 and 163.5 ± 1.9 Ma, contemporaneous or shortly after the extrusion of the volcanic sequence. This age is in agreement with the Re-Os age of 159 ± 16 Ma obtained from the mineralization itself (Tristá-Aguilera et al

  7. Petrogenesis and tectonic settings of volcanic rocks of the Ashele Cu-Zn deposit in southern Altay, Xinjiang, Northwest China: Insights from zircon U-Pb geochronology, geochemistry and Sr-Nd isotopes

    Science.gov (United States)

    Wu, Yufeng; Yang, Fuquan; Liu, Feng; Geng, Xinxia; Li, Qiang; Zheng, Jiahao

    2015-11-01

    The Early-Mid-Devonian Ashele Formation of the southern margin of the Chinese Altay hosts the Ashele Cu-Zn volcanogenic massive sulfide (VMS) deposit and consists of intercalated volcanic and sedimentary rocks that have experienced regional greenschist-facies metamorphism. We studied the petrography, zircon U-Pb geochronology, geochemistry, and Sr-Nd isotopes of dacites and basalts in order to understand the petrogenesis of these rocks and the regional tectonic evolution. Two dacites yielded LA-MC-ICP-MS zircon U-Pb ages of 402 ± 6 Ma and 403 ± 2 Ma. The dacites are calc-alkaline, and characterized by high Na2O/K2O ratios (3.6-9.3), and high Mg# values (47-63), enrichment in large ion lithophile elements (LILE) and light rare earth elements (LREE), depletion in Nb, Ta, Ti, and P, and relatively positive εNd(t) values (+3.6 to +7.5), collectively suggesting a sanukitic magma affinity. The variations in the major and trace elements of the dacites indicate that Fe-Ti oxide, plagioclase, and apatite were fractionated during their petrogenesis. The basalts are tholeiitic, and are characterized by high Mg# values (66-73), and negative Nb and Ta anomalies. The geochemical characteristics of the basalts are similar to those of N-MORB. Those characteristics together with the positive εNd(t) values (+6.8 to +9.2) of the basalts, indicate that the precursor magma was derived mainly from an N-MORB-type depleted asthenospheric mantle in an island arc setting. The geochemical similarities between the basalts and dacites indicate that they both originated from a similar depleted mantle source via partial melting under different magmatic conditions in each case, possibly related to ridge subduction.

  8. Influence of pulsed substrate bias on the structure and properties of Ti-Al-N films deposited by cathodic vacuum arc

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, G.P., E-mail: princeterry@163.com [Institute of Physics, Chinese Academy of Science, Beijing 100080 (China); Gao, G.J. [Changchun University of Science and Technology, College of Science, Changchun 130000 (China); Wang, X.Q.; Lv, G.H.; Zhou, L.; Chen, H.; Pang, H.; Yang, S.Z. [Institute of Physics, Chinese Academy of Science, Beijing 100080 (China)

    2012-07-15

    Ti-Al-N films were deposited by cathodic vacuum arc (CVA) technique in N{sub 2} atmosphere with different pulsed substrate bias. The influence of pulsed substrate bias (0 to -800 V) on the deposition rate, surface morphology, crystal structure, and mechanical properties of the Ti-Al-N films were systematically investigated. Increasing pulsed bias voltage resulted in the decrease of deposition rate but the increase of surface roughness. It was found that there was a strong correlation between the pulsed bias and film structure. All the films studied in this paper were composed of TiN, AlN, and Ti-Al-N ternary phases. The grains changed from equiaxial to columnar and exhibited preferred orientation when the pulsed bias increased. With the increase of pulsed bias voltage, the atomic ratio of Ti to Al element increased gradually, while the N to (Ti + Al) ratio decreased. The composite films present an enhanced nanohardness compared with binary TiN and ZrN films. The film deposited with pulsed bias of -200 V possessed the maximum scratch critical load and nanohardness. The minimum friction coefficient with pulsed bias of -300 V was obtained.

  9. Estimating volume of deposits associated with landslides on volcanic landscapes in the SW flank of the volcano Pico de Orizaba, Puebla-Veracruz

    Directory of Open Access Journals (Sweden)

    Gabriel Legorreta Paulín

    2017-03-01

    dangerous situation for more than 360 000 people living on the southern flank of the volcano Pico de Orizaba, where landslides along the hillslopes and the river system threaten towns like Cordova, Orizaba, Rio Blanco, Nogales and Ciudad Mendoza. Today the most common and dangerous landslides are associated with unconsolidated volcanic deposits and heavy seasonal rains. In this paper, the cause, distribution, and link between landslides and the volcanic landscape relief susceptibility are analyzed. Similarly, the volume of displaced material is estimated in order to characterize the landslide instability in volcanic terrains. The Río El Estado watershed on the southwestern flank of Pico de Orizaba volcano is selected to describe and analyze susceptible areas of gravitational processes. The study area allows to show a systematic methodology for landslide mapping and volume calculation in areas with scarce information. The methodology encompasses three main stages of analysis. In the first stage, background information is collected to provide context and establish a generalized characterization of landslide processes, landsforms and volumes within the study area. Background information includes the following maps: topographic, geologic, land use, climate, slope, slope curvature, contributing area, flow direction, saturation, reclassified hypsomety, reclassified slope, and morphography. By retrieval and on-off switching of the background information in the GIS, a base map is created to assist in the digitizing of landslides. The base map and the theoretical aspects of the geomorphological mapping help to develop a conceptual base of support for mapping landslides. Landslides are digitized directly into a geographic information system (GIS, and in parallel, a spatial geodatabase of landslides attributes (eg. size, volume, activity, landslide type, etc. is constructed. Previous landslide mapping in the study area is verified and new landslides are added to the landslide

  10. Warm storage for arc magmas.

    Science.gov (United States)

    Barboni, Mélanie; Boehnke, Patrick; Schmitt, Axel K; Harrison, T Mark; Shane, Phil; Bouvier, Anne-Sophie; Baumgartner, Lukas

    2016-12-06

    Felsic magmatic systems represent the vast majority of volcanic activity that poses a threat to human life. The tempo and magnitude of these eruptions depends on the physical conditions under which magmas are retained within the crust. Recently the case has been made that volcanic reservoirs are rarely molten and only capable of eruption for durations as brief as 1,000 years following magma recharge. If the "cold storage" model is generally applicable, then geophysical detection of melt beneath volcanoes is likely a sign of imminent eruption. However, some arc volcanic centers have been active for tens of thousands of years and show evidence for the continual presence of melt. To address this seeming paradox, zircon geochronology and geochemistry from both the frozen lava and the cogenetic enclaves they host from the Soufrière Volcanic Center (SVC), a long-lived volcanic complex in the Lesser Antilles arc, were integrated to track the preeruptive thermal and chemical history of the magma reservoir. Our results show that the SVC reservoir was likely eruptible for periods of several tens of thousands of years or more with punctuated eruptions during these periods. These conclusions are consistent with results from other arc volcanic reservoirs and suggest that arc magmas are generally stored warm. Thus, the presence of intracrustal melt alone is insufficient as an indicator of imminent eruption, but instead represents the normal state of magma storage underneath dormant volcanoes.

  11. PALEOMAGNETISM OF SILURIAN AND DEVONIAN VOLCANICS FROM THE CHINGIZ ISLAND ARC, KAZAKHSTAN, AND ITS BEARING ON TECTONIC EVOLUTION OF THE URAL-MONGOL BELT

    Directory of Open Access Journals (Sweden)

    Natalia M. Levashova

    2015-09-01

    Full Text Available The tectonic and paleogeographic evolution of the Ural-Mongol belt between the cratons of Baltica, Siberia, and Tarim is the key to the formation of the Eurasian supercontinent during Paleozoic time, but the views on this complicated process remain very disparate and sometimes controversial. Three volcanic formations of the Middle Silurian, LowertoMiddle Devonian and Middle Devonian age from the southwestern boundary of the Chingiz Range (NE Kazakhstan yields what are interpreted as primary paleomagnetic directions that help clarify the evolution of the belt. A singlepolarity characteristic component in midSilurian andesites yields a positive intraformational conglomerate test, whereas dualpolarity prefolding components are isolated from the two Devonian collections. These new data were evaluated together with previously published paleomagnetic results from Paleozoic rocks in the Chingiz Range, and allow us to establish with confidence the hemisphere in which the area was located at a given time. We conclude that NE Kazakhstan was steadily moving northward crossing the equator in Silurian time. These new paleomagnetic data from the Chingiz range also agree with and reinforce the hypothesis that the strongly curved volcanic belts of Kazakhstan underwent oroclinal bending between Middle Devonian and Late Carboniferous time. A comparison of the Chingiz paleolatitudes with those of Siberia shows similarities between the northward motion and rotational history of the Chingiz unit and those of Siberia, which imposes important constraints on the evolving paleogeography of the Ural-Mongol belt.

  12. Mineralogy, Geochemistry and Fluid Inclusion Data from the Tumanpınarı Volcanic Rock-Hosted Fe-Mn-Ba Deposit, Balıkesir-Dursunbey, Turkey

    Directory of Open Access Journals (Sweden)

    Ali Haydar Gultekin

    2016-11-01

    Full Text Available The Tumanpınarı mineralization is a volcanic rock-hosted epithermal Fe-Mn-Ba deposit located in the southwestern part of Dursunbey, Balıkesir, Turkey. The deposit constitutes one of the most important deposits of the Havran-Dursunbey metallogenic sub-province in which numerous Early Miocene Fe-Mn-Ba deposits are distributed. The ore occurs as open-space fillings in faults, fractures, and breccias in the andesite. Early hydrothermal activity was responsible for four types of hypogene alteration in decreasing intensity: silicification, sericitization, hematization and argillic alteration. The mineral assemblage includes pyrolusite, psilomelane, hematite, and barite as well as minor magnetite, manganite, poliannite, limonite, braunite, bixbyite, galena, pyrite, and goethite. Mineralogically, three ore types are recognized as pyrolusite + psilomelane + hematite + barite ore, pyrolusite + psilomelane + poliannite ore and barite + pyrolusite + psilomelane + hematite ore (barite-dominant ore. In addition to Fe, Mn and Ba, the ore contains substantial quantities of Pb, Zn, As. Chemically, the transition from fresh to altered rocks has little effect on the elemental levels for Si, Al, Fe, Ca, Mg, K, Rb, Sr and H2O. The homogenization temperature of fluid inclusions hosted in the main stage quartz and barite ranged from 113 to 410 °C with salinities ranging from 0.4 to 14.9 eq. wt % NaCl, respectively. Overall, the available data suggest that the deposits formed as the result of the interaction of two aqueous fluids: a higher-salinity fluid (probably magmatic and a dilute meteoric fluid.

  13. Mastritherium (Artiodactyla, Anthracotheriidae) from Wadi Sabya, southwestern Saudi Arabia; an earliest Miocene age for continental rift-valley volcanic deposits of the Red Sea margin

    Science.gov (United States)

    Madden, Gary T.; Schmidt, Dwight Lyman; Whitmore, Frank C.

    1983-01-01

    A lower jaw fragment with its last molar (M/3) from the Baid formation in Wadi Sabya, southwestern Saudi Arabia, represents the first recorded occurrence in the Arabian Peninsula of an anthracotheriid artiodactyl (hippo-like, even-toed ungulate). This fossil is identified as a primitive species of Masritherium, a North and East African genus restricted, previously to the later early Miocene. This identification indicates that the age of the Baid formation, long problematical, is early Miocene and, moreover, shows that the age of the fossil site is earliest Miocene (from 25 to 21Ma). The Wadi Sabya anthracothere is the first species of fossil mammal recorded from western Saudi Arabia, and more important, it indicates an early Miocene age for the volcanic deposits of a continental rift-valley that preceded the initial sea-floor spreading of the Red Sea.

  14. ArcGIS在东昆仑西段铁矿资源预测中的应用——以矽卡岩型铁矿为例%Application of software ArcGIS to prediction of iron ore resources in the western segment of the East Kunlun: A case study of skarn-type iron deposits

    Institute of Scientific and Technical Information of China (English)

    刘艳宾; 弓小平; 薛迎喜; 陈斌; 毛磊

    2011-01-01

    GIS在矿产预测中的应用研究日益普及和深化,在矿产勘查领域中已成为一种快速有效成矿预测方法。本文以东昆仑西段矽卡岩型铁矿为例,从研究区的地质背景和已查明的13个矽卡岩型铁矿(点)出发,基于ArcGIS平台,建立本研究区的空间数据库,结合已知矿(点)地质资料和野外验证分析,建立找矿模型与预测区提取模型,由于矽卡岩型矿床主要的共同特点与中酸性侵入体、火山岩和碳酸盐岩等有关,所以总结出本区矽卡岩型铁矿的主要控矿因素取决于:(1)断层;(2)侵入体;(3)岩石组分,从3个方面的证据图层与铁矿(化)点空间关系入手,并对其进行合成,采用证据权模型和加权Logistic回归模型进行成矿有利度评价,共圈定3个矽卡岩型铁矿预测区东昆仑西段地区具有很大的找砖:备如、%With the increasing popularization and deepening of the application research of G[S in ore prediction, GIS has become a fast and effective method for metallogenic forecast. Taking skarn type iron deposits in the western section of the East Kunlun as an example, this work is based on the ArcGIS platform to establish a spatial database in terms of the geological background and 13 known sedimentary-metamorphic iron (point) of the study area~ Combined with the known deposits, geological data and field check analysis, the prospecting and forecast area extraction models are established. Because the main common features of the skarn-type deposits are related to the intermediate-acidic intrusive mass, volcanic and carbonate, this paper concluds the main ore control factors of the skarn type iron deposits as follows : ( 1 ) fault ; ( 2 ) intrusion ; and ( 3 ) rock components. Starting fi'om the these three aspects of evidence and the spatial relationship of iron mineralization, and making synthesis to them, the evidence weight model and

  15. FE-SEM, FIB and TEM Study of Surface Deposits of Apollo 15 Green Glass Volcanic Spherules

    Science.gov (United States)

    Ross, Daniel K.; Thomas-Keprta, K. L.; Rahman, Z.; Wentworth, S. J.; McKay, D. S.

    2011-01-01

    Surface deposits on lunar pyroclastic green (Apollo 15) and orange (Apollo 17) glass spherules have been attributed to condensation from the gas clouds that accompanied fire-fountain eruptions. The fire fountains cast molten lava high above the lunar surface and the silicate melt droplets quenched before landing producing the glass beads. Early investigations showed that these deposits are rich in sulfur and zinc. The deposits are extremely fine-grained and thin, so that it was never possible to determine their chemical compositions cleanly by SEM/EDX or electron probe x-ray analysis because most of the excited volume was in the under-lying silicate glass. We are investigating the surface deposits by TEM, using focused ion beam (FIB) microscopy to extract and thin the surface deposits. Here we report on chemical mapping of a FIB section of surface deposits of an Apollo green glass bead 15401using the ultra-high resolution JEOL 2500 STEM located at NASA Johnson Space Center.

  16. ZrO2 and ZrO2-Y2O3 coatings deposited by double pulsed plasma arc

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    A novel surface technique has been developed to produce ZrO2 and ZrO2-Y2O3 coatings on the surface of alloys by using double pulsed plasma arc to react with a solution film containing nano-oxide particles. These coatings exhibit smooth surface and excellent adhesion with substrate. The morphologies of the ceramic coatings and phases were analyzed. It was shown that the oxidation resistance of l8-8 stainless steel was markedly improved by applying ZrO2 and ZrO2-Y2O3 coatings.

  17. Sr and O isotopes in western Aleutian seafloor lavas: Implications for the source of fluids and trace element character of arc volcanic rocks

    Science.gov (United States)

    Yogodzinski, Gene M.; Kelemen, Peter B.; Hoernle, Kaj; Brown, Shaun T.; Bindeman, Ilya; Vervoort, Jeffrey D.; Sims, Kenneth W. W.; Portnyagin, Maxim; Werner, Reinhard

    2017-10-01

    High Mg# andesites and dacites (Mg# = molar Mg/Mg + Fe) from western Aleutian seafloor volcanoes carry high concentrations of Sr (>1000 ppm) that is unradiogenic (87Sr/86Sr 0.7030). Data patterns in plots of 87Sr/86Sr vs Y/Sr and Nd/Sr imply the existence of an eclogite-melt source component - formed by partial melting of MORB eclogite in the subducting Pacific Plate - which is most clearly expressed in the compositions of western Aleutian andesites and dacites (Nd/Sr and Y/Sr viewed in combination with inversely correlated εNd and 87Sr/86Sr, these patterns rule out aqueous fluids as an important source of Sr because mixtures of fluids from altered oceanic crust with depleted mantle and sediment produce compositions with 87Sr/86Sr higher than in common Aleutian rocks. The unradiogenic nature of Sr in the western Aleutian andesite-dacite end-member may be understood if H2O required to drive melting of the subducting oceanic crust is transported in fluids containing little Sr. Mass balance demonstrates that such fluids may be produced by dewatering of serpentinite in the mantle section of the subducting plate. If the eclogite-melt source component is present throughout the Aleutian arc, melting of the subducting plate must extend into minimally altered parts of the sheeted dike section or upper gabbros, at depths >2 km below the paleo-seafloor. Oxygen isotopes in western Aleutian seafloor lavas, which fall within a narrow range of MORB-like values (δ18 O = 5.1- 5.7), are also consistent with this model. These results indicate that the subducting Pacific lithosphere beneath the Aleutian arc is significantly hotter than indicated my most thermal models.

  18. Nucleation and growth of hydroxyapatite on arc-deposited TiO{sub 2} surfaces studied by quartz crystal microbalance with dissipation

    Energy Technology Data Exchange (ETDEWEB)

    Lilja, Mirjam [Division for Nanotechnology and Functional Materials, Department of Engineering Sciences, The Ångström Laboratory, Uppsala University, Box 534, 75121 Uppsala (Sweden); Sandvik Coromant Sverige AB, Lerkrogsvägen 19, 12680 Stockholm (Sweden); Butt, Umer [Sandvik Coromant Sverige AB, Lerkrogsvägen 19, 12680 Stockholm (Sweden); Berzelii Centre EXSELENT on Porous Materials and Department of Materials and Environmental Chemistry, Arrhenius Laboratory, Stockholm University, 114 18 Stockholm (Sweden); Shen, Zhijian [Berzelii Centre EXSELENT on Porous Materials and Department of Materials and Environmental Chemistry, Arrhenius Laboratory, Stockholm University, 114 18 Stockholm (Sweden); Bjöörn, Dorota, E-mail: dorota.bjoorn@sandvik.com [Sandvik Coromant Sverige AB, Lerkrogsvägen 19, 12680 Stockholm (Sweden)

    2013-11-01

    Understanding of nucleation and growth kinetics of biomimetically deposited hydroxyapatite (HA) on crystalline TiO{sub 2} surfaces is important with respect to the application and performance of HA as functional implant coatings. Arc-evaporation was used to deposit TiO{sub 2} coatings dominated by anatase phase, rutile phase or their mixtures. Subsequent formation of HA from phosphate buffered saline solution (PBS) was investigated in real-time using in situ quartz crystal microbalance with dissipation technique (QCM-D). Scanning electron microscopy (SEM) and X-ray diffraction (XRD) were employed to characterize the presence, morphology and crystal structure of TiO{sub 2} coatings and the formed HA. Increasing temperature of the PBS, increasing flow rate and applying a higher ion concentration in solution were found to accelerate HA nucleation process and hence affect growth kinetics. Lower PBS temperature resulted in the formation of HA coatings with flake-like morphology and increasing HA porosity. All TiO{sub 2} coatings under study enabled HA formation at body temperature, while in contrast Ti reference surfaces only supported HA nucleation and growth at elevated temperatures. QCM-D technique is a powerful tool for studying the impact of process parameters during biomimetic coating deposition on coating structure evolution in real time and provides valuable information for understanding, optimizing as well as tailoring the biomimetic HA growth processes.

  19. Microstructural evolution and mechanical property of Ti-6Al-4V wall deposited by continuous plasma arc additive manufacturing without post heat treatment.

    Science.gov (United States)

    Lin, Jianjun; Lv, Yaohui; Liu, Yuxin; Sun, Zhe; Wang, Kaibo; Li, Zhuguo; Wu, Yixiong; Xu, Binshi

    2017-05-01

    Plasma arc additive manufacturing (PAM) is a novel additive manufacturing (AM) technology due to its big potential in improving efficiency, convenience and being cost-savings compared to other AM processes of high energy bea\\m. In this research, several Ti-6Al-4V thin walls were deposited by optimized weld wire-feed continuous PAM process (CPAM), in which the heat input was gradually decreased layer by layer. The deposited thin wall consisted of various morphologies, which includes epitaxial growth of prior β grains, horizontal layer bands, martensite and basket weave microstructure, that depends on the heat input, multiple thermal cycles and gradual cooling rate in the deposition process. By gradually reducing heat input of each bead and using continuous current in the PAM process, the average yield strength (YS), ultimate tensile strength (UTS) and elongation reach about 877MPa, 968MPa and 1.5%, respectively, which exceed the standard level of forging. The mechanical property was strengthened and toughened due to weakening the aspect ratio of prior β grains and separating nano-dispersoids among α lamellar. Furthermore, this research demonstrates that the CPAM process has a potential to manufacture or remanufacture in AM components of metallic biomaterials without post-processing heat treatment. Copyright © 2016 Elsevier Ltd. All rights reserved.

  20. One-step approach for hydroxyapatite-incorporated TiO{sub 2} coating on titanium via a combined technique of micro-arc oxidation and electrophoretic deposition

    Energy Technology Data Exchange (ETDEWEB)

    Bai, Yu [Department of Dental Biomaterials, School of Dentistry and Institute of Oral Bioscience, Brain Korea 21 Project, Chonbuk National University, Ducjin, Jeonju 561-756 (Korea, Republic of); Park, Il Song, E-mail: ilsong@chonbuk.ac.kr [Department of Dental Biomaterials, School of Dentistry and Institute of Oral Bioscience, Brain Korea 21 Project, Chonbuk National University, Ducjin, Jeonju 561-756 (Korea, Republic of); Lee, Sook Jeong [Neural Injury Research Lab, Department of Neurology, Asan life Science Institute, University of Ulsan, College of Medicine, Seoul 138-736 (Korea, Republic of); Bae, Tae Sung [Department of Dental Biomaterials, School of Dentistry and Institute of Oral Bioscience, Brain Korea 21 Project, Chonbuk National University, Ducjin, Jeonju 561-756 (Korea, Republic of); Duncan, Warwick; Swain, Michael [Department of Oral Sciences, University of Otago, Dunedin, Otago (New Zealand); Lee, Min Ho, E-mail: lmh@chonbuk.ac.kr [Department of Dental Biomaterials, School of Dentistry and Institute of Oral Bioscience, Brain Korea 21 Project, Chonbuk National University, Ducjin, Jeonju 561-756 (Korea, Republic of)

    2011-05-15

    A porous hydroxyapatite (HA) - incorporated TiO{sub 2} coating layer was deposited on the titanium substrate using a combination of micro-arc oxidation and electrophoretic deposition. The size of the synthesized HA nano-particles was approximately 10-20 nm in width and 30-40 nm in length. The microstructure, as well as elemental and phase composition of the coating layers were examined by scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS) and X-ray diffraction (XRD). XRD showed that the coating layers were composed mainly of HA and anatase phases. The composition and surface morphologies were strongly dependent on the applied voltages. The amount of HA deposited into the coating increased with increasing applied voltage. The corrosion behavior of the coating layers in the simulated body fluids (SBF) was evaluated using a potentiodynamic polarization test. The corrosion resistance of the coated sample was higher than that of the untreated titanium sample. Moreover, the corrosion resistance of the coated samples also showed a positive correlation with the applied voltage. In addition, the in vitro cellular responses to the coated samples were assessed to investigate the proliferation, differentiation and morphology of the osteoblast cell line.

  1. Application of fuzzy logic and fuzzy AHP to mineral prospectivity mapping of porphyry and hydrothermal vein copper deposits in the Dananhu-Tousuquan island arc, Xinjiang, NW China

    Science.gov (United States)

    Zhang, Nannan; Zhou, Kefa; Du, Xishihui

    2017-04-01

    Mineral prospectivity mapping (MPM) is a multi-step process that ranks promising target areas for further exploration. Fuzzy logic and fuzzy analytical hierarchy process (AHP) are knowledge-driven MPM approaches. In this study, both approaches were used for data processing, based on which MPM was performed for porphyry and hydrothermal vein copper deposits in the Dananhu-Tousuquan island arc, Xinjiang. The results of the two methods were then compared. The two methods combined expert experience and the Studentized contrast (S(C)) values of the weights-of-evidence approach to calculate the weights of 15 layers, and these layers were then integrated by the gamma operator (γ). Through prediction-area (P-A) plot analysis, the optimal γ for fuzzy logic and fuzzy AHP was determined as 0.95 and 0.93, respectively. The thresholds corresponding to different levels of metallogenic probability were defined via concentration-area (C-A) fractal analysis. The prediction performances of the two methods were compared on this basis. The results showed that in MPM based on fuzzy logic, the area under the receiver operating characteristic (ROC) curve was 0.806 and 81.48% of the known deposits were predicted, whereas in MPM based on fuzzy AHP, the area under the ROC curve was 0.862 and 92.59% of the known deposits were predicted. Therefore, prediction based on fuzzy AHP is more accurate and can provide directions for future prospecting.

  2. Volcano-sedimentary processes operating on a marginal continental arc: the Archean Raquette Lake Formation, Slave Province, Canada

    Science.gov (United States)

    Mueller, W. U.; Corcoran, P. L.

    2001-06-01

    The 200-m thick, volcano-sedimentary Raquette Lake Formation, located in the south-central Archean Slave Province, represents a remnant arc segment floored by continental crust. The formation overlies the gneissic Sleepy Dragon Complex unconformably, is laterally interstratified with subaqueous mafic basalts of the Cameron River volcanic belt, and is considered the proximal equivalent of the turbidite-dominated Burwash Formation. A continuum of events associated with volcanism and sedimentation, and controlled by extensional tectonics, is advocated. A complex stratigraphy with three volcanic and three sedimentary lithofacies constitute the volcano-sedimentary succession. The volcanic lithofacies include: (1) a mafic volcanic lithofacies composed of subaqueous pillow-pillow breccia, and subaerial massive to blocky flows, (2) a felsic volcanic lithofacies representing felsic flows that were deposited in a subaerial environment, and (3) a felsic volcanic sandstone lithofacies interpreted as shallow-water, wave- and storm-reworked pyroclastic debris derived from explosive eruptions. The sedimentary lithofacies are represented by: (1) a conglomerate-sandstone lithofacies consistent with unconfined debris flow, hyperconcentrated flood flow and talus scree deposits, as well as minor high-energy stream flow conglomerates that formed coalescing, steep-sloped, coarse-clastic fan deltas, (2) a sandstone lithofacies, interpreted as hyperconcentrated flood flow deposits that accumulated at the subaerial-subaqueous interface, and (3) a mudstone lithofacies consistent with suspension sedimentation in a small restricted lagoon-type setting. The Raquette Lake Formation is interpreted as a fringing continental arc that displays both high-energy clastic sedimentation and contemporaneous effusive and explosive mafic and felsic volcanism. Modern analogues that develop along active plate margins in which continental crust plays a significant role include Japan and the Baja California

  3. A new genetic interpretation for the Caotaobei uranium deposit associated with the shoshonitic volcanic rocks in the Hecaokeng ore field, southern Jiangxi, China

    Directory of Open Access Journals (Sweden)

    Dong-Sheng Yang

    2017-03-01

    Full Text Available Combined with in-situ laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS zircon UPb geochronology, published and unpublished literature on the Caotaobei uranium deposit in southern Jiangxi province, China, is re-examined to provide an improved understanding of the origin of the main ore (103 Ma. The Caotaobei deposit lies in the Hecaokeng ore field and is currently one of China's largest, volcanic-related uranium producers. Unlike commonly known volcanogenic uranium deposits throughout the world, it is spatially associated with intermediate lavas with a shoshonitic composition. Uranium mineralization (pitchblende occurs predominantly as veinlets, disseminations, and massive ores, hosted by the cryptoexplosive breccias rimming the Caotaobei crater. Zircons from one latite define four distinct 206Pb/238U age groups at 220–235 Ma (Triassic, 188 Ma (Early Jurassic, 131–137 Ma (Early Cretaceous, and 97–103 Ma (Early-Late Cretaceous transition, hereafter termed mid-Cretaceous. The integrated age (134 ± 2 Ma of Early Cretaceous zircons (group III is interpreted as representing the time of lava emplacement. The age data, together with the re-examination of literature, does not definitively support a volcanogenic origin for the generation of the deposit, which was proposed by the previous workers based mainly on the close spatial relationship and the age similarity between the main ore and volcanic lavas. Drill core and grade-control data reveal that rich concentrations of primary uranium ore are common around the granite porphyry dikes cutting the lavas, and that the cryptoexplosive breccias away from the dikes are barren or unmineralized. These observations indicate that the emplacement of the granite porphyries exerts a fundamental control on ore distribution and thus a genetic link exists between main-stage uranium mineralization and the intrusions of the dikes. Zircon overgrowths of mid-Cretaceous age (99.6

  4. Microstructural Characterization and Wear Properties of Fe-Based Amorphous-Crystalline Coating Deposited by Twin Wire Arc Spraying

    Directory of Open Access Journals (Sweden)

    Ana Arizmendi-Morquecho

    2014-01-01

    Full Text Available Twin wire arc spraying (TWAS was used to produce an amorphous crystalline Fe-based coating on AISI 1018 steel substrate using a commercial powder (140MXC in order to improve microhardness and wear properties. The microstructures of coating were characterized by X-ray diffraction (XRD, scanning electron microscopy (SEM, and transmission electron microscopy (TEM as well as the powder precursor. Analysis in the coating showed the formation of an amorphous matrix with boron and tungsten carbides randomly dispersed. At high amplifications were identified boron carbides at interface boron carbide/amorphous matrix by TEM. This kind of carbides growth can be attributed to partial crystallization by heterogeneous nucleation. These interfaces have not been reported in the literature by thermal spraying process. The measurements of average microhardness on amorphous matrix and boron carbides were 9.1 and 23.85 GPa, respectively. By contrast, the microhardness values of unmelted boron carbide in the amorphous phase were higher than in the substrate, approaching 2.14 GPa. The relative wear resistance of coating was 5.6 times that of substrate. These results indicate that the twin wire arc spraying is a promising technique to prepare amorphous crystalline coatings.

  5. Time-Resolved Spectroscopic Observation of Deposition Processes of Ultrananocrystalline Diamond/Amorphous Carbon Composite Films by Using a Coaxial Arc Plasma Gun

    Science.gov (United States)

    Hanada, Kenji; Yoshitake, Tsuyoshi; Nishiyama, Takashi; Nagayama, Kunihito

    2010-08-01

    The deposition of ultrananocrystalline diamond (UNCD)/amorphous carbon composite films using a coaxial arc plasma gun in vacuum and, for comparison, in a 53.3 Pa hydrogen atmosphere was spectroscopically observed using a high-speed camera equipped with narrow-band-pass filters. UNCD crystallites with diameters of approximately 1.6 nm were formed even in vacuum. These extremely small crystallites imply that the formation is predominantly due to nucleation without the subsequent growth. Even in vacuum, emissions from C+ ions, C atoms, and C2 dimers lasted for approximately 100 µs, although the emission lifetimes of these species are generally 10 ns. We consider that the nucleation is due to the supersaturated environment containing excited carbon species with large number densities.

  6. Chemical bonding structural analysis of nitrogen-doped ultrananocrystalline diamond/hydrogenated amorphous carbon composite films prepared by coaxial arc plasma deposition

    Science.gov (United States)

    Gima, Hiroki; Zkria, Abdelrahman; Katamune, Yūki; Ohtani, Ryota; Koizumi, Satoshi; Yoshitake, Tsuyoshi

    2017-01-01

    Nitrogen-doped ultra-nanocrystalline diamond/hydrogenated amorphous carbon composite films prepared in hydrogen and nitrogen mixed-gas atmospheres by coaxial arc plasma deposition with graphite targets were studied electrically and chemical-bonding-structurally. The electrical conductivity was increased by nitrogen doping, accompanied by the production of n-type conduction. From X-ray photoemission, near-edge X-ray absorption fine-structure, hydrogen forward-scattering, and Fourier transform infrared spectral results, it is expected that hydrogen atoms that terminate diamond grain boundaries will be partially replaced by nitrogen atoms and, consequently, π C–N and C=N bonds that easily generate free electrons will be formed at grain boundaries.

  7. Study of the phase composition of silicide coatings, based on layered Nb-Mo structures, obtained by vacuum-arc deposition

    Science.gov (United States)

    Lozovan, A. A.; Betsofen, S. Ya; Lenkovets, A. S.

    2016-07-01

    A multilayer composite ∼1000 μm in thickness, formed by niobium and molybdenum layers (number of layers n = 230), is obtained by vacuum-arc deposition with subsequent siliconization of the surface layers at a temperature of 1200 °C. Layer-by-layer phase analysis is performed by X-ray diffraction and scanning electron microscopy. It is found that in the surface layers ∼130 μm in thickness, single-phase silicides (Nb x Mo1- x )Si2 are formed with the hexagonal C40 structure (Strukturbericht designations). Alternating layers of solid solutions based on niobium and molybdenum with a body-centered cubic (BCC) lattice are observed within the composite. The formation of solid solutions caused by heating of the coating leads to convergence of the values of the linear thermal expansion coefficient and Young's modulus at the interface between the layers.

  8. Effect of partial pressure of reactive gas on chromium nitride and chromium oxide deposited by arc ion plating

    Institute of Scientific and Technical Information of China (English)

    LI Ming-sheng; FENG Chang-jie; WANG Fu-hui

    2006-01-01

    The effects of reactive gas partial pressure on droplet formation,deposition rate and change of preferred orientation of CrN and Cr2O3 coatings were studied. For CrN coatings,as nitrogen partial pressure increases,the number and size of droplets increases,the deposition rate initially increases obviously and then slowly,and the preferred orientation of CrN changes from high-index plane to low-index one. For Cr2O3 coatings,with the increase of oxygen partial pressure,the number and size of droplets decreases,the deposition rate decreases and the (300) becomes the preferred orientation. These differences are ascribed to the formation of CrN (with a lower melting point) and Cr2O3 (with a higher melting point) on the surface of Cr target during the deposition of CrN and Cr2O3. Complete coatings CrN or Cr2O3 film can be formed when reactive gas partial pressure gets up to 0.1 Pa. The optimized N2 partial pressure for CrN deposition is about 0.1-0.2 Pa in order to suppress the formation of droplets and the suitable O2 partial pressure for Cr2O3 deposition is approximately 0.1 Pa for the attempt to prevent the peel of the coating.

  9. Noble gas data from Goldfield and Tonopah epithermal Au-Ag deposits, ancestral Cascades Arc, USA: Evidence for a primitive mantle volatile source

    Science.gov (United States)

    Manning, Andrew H.; Hofstra, Albert H.

    2017-01-01

    The He, Ne, and Ar isotopic composition of fluid inclusions in ore and gangue minerals were analyzed to determine the source of volatiles in the high-grade Goldfield and Tonopah epithermal Au-Ag deposits in southwestern Nevada, USA. Ar and Ne are mainly atmospheric, whereas He has only a minor atmospheric component. Corrected 3He/4He ratios (with atmospheric He removed) range widely from 0.05 to 35.8 times the air 3He/4He ratio (RA), with a median of 1.43 RA. Forty-one percent of measured 3He/4He ratios are ≥4 RA, corresponding to ≥50% mantle He assuming a mantle ratio of 8 RA. These results suggest that mafic magmas were part of the magmatic-hydrothermal system underlying Goldfield and Tonopah, and that associated mantle-sourced volatiles may have played a role in ore formation. The three highest corrected 3He/4He ratios of 17.0, 23.7, and 35.8 RAindicate a primitive mantle He source and are the highest yet reported for any epithermal-porphyry system and for the Cascades arc region. Compiled 3He/4He measurements from epithermal-porphyry systems in subduction-related magmatic arcs around the world (n = 209) display a statistically significant correlation between 3He/4He and Au-Ag grade. The correlation suggests that conditions which promote higher fluid inclusion 3He/4He ratios (abundance of mantle volatiles and focused upward volatile transport) have some relation to conditions that promote higher Au-Ag grades (focused flow of metal-bearing fluids and efficient chemical traps). Results of this and previous investigations of He isotopes in epithermal-porphyry systems are consistent with the hypothesis posed in recent studies that mafic magmas serve an important function in the formation of these deposits.

  10. Volcano collapse along the Aleutian Ridge (western Aleutian Arc

    Directory of Open Access Journals (Sweden)

    C. Montanaro

    2011-03-01

    Full Text Available The Aleutian Ridge, in the western part of the Aleutian Arc, consists of a chain of volcanic islands perched atop the crest of a submarine ridge with most of the active Quaternary stratocones or caldera-like volcanoes being located on the northern margins of the Aleutian Islands. Integrated analysis of marine and terrestrial data resulted in the identification and characterization of 17 extensive submarine debris avalanche deposits from 11 volcanoes. Two morphological types of deposits are recognizable, elongate and lobate, with primary controls on the size and distribution of the volcanic debris being the volume and nature of material involved, proportion of fine grained material, depth of emplacement and the paleo-bathymetry. Volume calculations show the amount of material deposited in debris avalanches is as much as three times larger than the amount of material initially involved in the collapse, suggesting the incorporation of large amounts of submarine material during transport. The orientation of the collapse events is influenced by regional fault systems underling the volcanoes. The western Aleutian Arc has a significant tsunamigenic potential and communities within the Aleutian Islands and surrounding areas of the North Pacific as well as shipping and fishing fleets that cross the North Pacific may be at risk during future eruptions in this area.

  11. Geological and geochemical studies of the Sierra del Morro-Oeste (San Luis Province, Argentina): Meta-sediments and meta-volcanics from a probable back-arc setting

    Science.gov (United States)

    Delakowitz, B.; Höll, R.; Hack, M.; de Brodtkorb, M. K.; Stärk, H.

    The Sierra del Morro-Oeste covers an area of some 40 km 2 in the northeastern part of San Luis Province, Argentina. This area is an integral part of the scheelite- and wolframite-bearing crystalline basement of the Sierras Pampeanas. A "characteristic rock sequence"—several tens of meters thick—is concordantly embedded between uniform country rocks (quartz-oligoclase/andesine micaschists and gneises); it includes layered alternations of banded amphibolites, hornblende-epidote schists, scheelite-bearing calc-silicate rocks, lenses of barren marble, and, locally, tourmaline-bearing micaschists. Chemical analyses of amphibolite samples allow these metamorphic rocks to be interpreted as derivatives of a tholeiite-basaltic volcanism. The amphibolites are subdivided into two groups (A and B) because of significant differences in their chemical composition. These differences are related to hydrothermal seafloor alteration. This sea-water alteration has been most effective in the youngest tholeiite-basaltic lava extrusions. The derivatives of the submarine altered tholeiite-basaltic lavas (amphibolites of Group B) can therefore be interpreted as younger in comparison with the primary lavas of the non-altered amphibolites of Group A. The extrusion of the tholeiite-basaltic lavas obviously took place during an initial stage of back-arc basin rifting on continental crust.

  12. Analysis of Volcanic Deposits From the 2001 Eruption of Mt. Cleveland, Alaska Using Multisensor Satellite Data and Field Observations

    Science.gov (United States)

    Smith, S. J.; Dehn, J.; Moore, R. B.

    2003-12-01

    Eruptive characteristics and histories of Aleutian stratovolcanoes are some of the least understood because of their remote locations, yet they have the ability to cripple the heavily traveled air routes in this region. Remote sensing is useful for gathering information on remote eruption deposits and compliments field observations. Mount Cleveland, on the western part of Chuginadak Island, has been one of the most active of these Aleutian volcanoes over the past century, its most recent eruption disrupted air traffic from February to March 2001. Using field observations of pyroclastic fan deposits preceding an a\\'{}a lava flow down the western flank of Mount Cleveland in 2001 this study attempts to associate spectral characteristics of these deposits (from Advanced Spaceborne Thermal Emission and Reflectance Radiometer (ASTER), Landsat 7 Enhanced Thematic Mapper Plus (ETM+), Second European Remote Sensing Satellite (ERS-2), and RADARSAT-1) to similar characteristics around the entire volcano. By also using Advanced Very High Resolution Radiometer (AVHRR) and Moderate Resolution Imaging Spectroradiometer (MODIS) data this study will present a more accurate chronology of the 2001 eruption. Field observations of the pyroclastic fan deposit reveal the existence of two separate stratigraphic deposits, an initial smooth ˜10-30 m thick a\\'{}a block and ash deposit overlain by a rougher ˜1-15 m thin breadcrust bomb deposit. The southern and northeastern parts of the fan are dominated by the thin breadcrust bomb deposit with an average bomb area of 2.38 m2, while the northwestern part is dominated by very large a\\'{}a blocks with pull-apart fractures and a much larger average block area of 22.44 m2. Initial Landsat 7 ETM+ and photographic analysis of this pyroclastic fan displays a slight coloration difference between the two deposits. The stratigraphic sequence of the pyroclastic fan from 2001 suggests that there was 1) a warm to hot debris flow from the collapse of

  13. Distribution and diversity of carbon monoxide-oxidizing bacteria and bulk bacterial communities across a succession gradient on a Hawaiian volcanic deposit.

    Science.gov (United States)

    Weber, C F; King, G M

    2010-07-01

    Relatively little is known about the distribution and diversity of CO-oxidizing bacteria during succession on volcanic deposits even though they are among the primary colonists. We surveyed CO-oxidizing communities across a vegetation gradient on a 1959 cinder deposit using coxL (large subunit gene of carbon monoxide dehydrogenase) sequences. Sequences most closely related to a coxL sequence from Ktedonobacter racemifer, dominated unvegetated cinders, while Proteobacteria-like sequences dominated vegetated sites. The number of coxL operational taxonomic units (OTUs) increased threefold with increased vegetation, and correlated most strongly with the increased beta-Proteobacteria richness (r = 0.987). These compositional shifts were also reflected in overall bacterial community compositions as determined by 16S rRNA gene analysis. Notably, coxL OTU:16S rRNA OTU ratios increased with increased vegetation, indicating that CO oxidizers became a larger fraction of total bacterial richness during succession. Results from most probable number estimates and maximum potential CO uptake activity assays indicate that increased richness is paralleled by increased CO oxidizer abundance, which likely results from increased vegetation and organic carbon content. Collectively, results suggest that in contrast to patterns observed for plant succession, a versatile bacterial functional group that is important during early colonization and succession can remain important in later stages of succession, irrespective of dramatic environmental changes.

  14. Structure Of Conduits Of The Acidic Volcanism And Related Deposits In The Paraná-Etendeka Magmatic Province, São Marcos Region, South Brazil

    Science.gov (United States)

    Guimarães, L. F.; De Campos, C. P.; Lima, E. F. D.; Janasi, V. A.

    2015-12-01

    Voluminous acidic volcanics from the Paraná-Etendeka Magmatic Province crop out in the southern part of Brazil. The conduits responsible for the feeding of this intermediate/acid volcanism are preserved and well exposed in the São Marcos region (Lima et al. 2012; Geologia USP 12:49-64). Conduits are aligned along a NW-SE trend and have thicknesses up to 1 km. These structures are often characterized by mixing between dacitic and rhyodacitic magmas, with intercalation between two major zones: 1) reddish or grayish vitrophiricdacite/rhyodacite, sub-divided in massive or vesiculated; 2) reddish or grayish vitrophiric fragmented dacite/rhyodacite composed of bubble-rich angular to rounded blocks. Such fragments commonly deform coeval to the flow. A third zone dominated by filaments depicts a chaotic stretching-and-folding process from the mixture of the acid magmas. We used classical field measurements of flow structures and recognized main flow directions in these feeder-dikes. They follow two preferential directions: NW, ranging from N272° to N 355°, and NE, varying from N20° to N85°. These directions are indicative of a transtensive fissural system, which seems to be related to conjugated fractures. Evidence of an important fragmentation process in the conduits point towards the presence of related products in this region, thus rheomorphic deposits such as those observed elsewhere (e.g. Uruguay and Namibia) are expected to occur. Possible vestiges of these deposits could be represented by restricted outcrops of lens-shaped and banded hipohyaline, occasionally bubble-rich, dacites. The presence of continuous pseudotachylitic levels, tightly folded bands with horizontal axial planes together with local deformed bubble-rich pumice-like lens could be indicative of remelting and rheomorphism of previous vulcanoclastic material. Coulees and compound (lobed) dacitic lava flows, reaching up to 5-8 meters length, occur as the uppermost deposits and correspond to the

  15. LA-ICP-MS Pb-U Dating of Young Zircons from the Kos-Nisyros Volcanic Centre, SE Aegean Arc (Greece)

    Science.gov (United States)

    Guillong, M.; Von Quadt, A.; Peytcheva, I.; Bachmann, O.

    2014-12-01

    Zircon Pb-U dating has become a key technique for answering many important questions in geosciences. This paper describes a new LA-ICP-MS approach. We show, using previously dated samples of a large quaternary rhyolitic eruption in the Kos-Nisyros volcanic centre (the 161 ka Kos Plateau Tuff), that the precision of our LA-ICP-MS method is as good as via SHRIMP, while ID-TIMS measurements confirm the accuracy. Gradational age distribution over >140 ka of the Kos zircons and the near-absence of inherited cores indicate near-continuous crystallisation in a growing magma reservoir with little input from wall rocks. Previously undated silicic eruptions from Nisyros volcano (Lower Pumice, Nikia Flow, Upper Pumice), which are stratigraphically constrained to have happened after the Kos Plateau Tuff, are dated to be younger than respectively 124 ± 35 ka, 111 ± 42 ka and 70 ± 24 ka. Samples younger than 1 Ma were corrected for initial thorium disequilibrium using a new formula that also accounts for disequilibrium in 230Th decay. Guillong, M. et al., 2014, JAAS, 29, p. 963-967; doi: 10.1039/c4ja00009a.

  16. Hot Corrosion Behavior of Arc-Sprayed Highly Dense NiCr-Based Coatings in Chloride Salt Deposit

    Science.gov (United States)

    Qin, Enwei; Yin, Song; Ji, Hua; Huang, Qian; Liu, Zekun; Wu, Shuhui

    2017-03-01

    To make cities more environmentally friendly, combustible wastes tend to be incinerated in waste-to-energy power plant boilers. However, release of chlorine gas (Cl2) during incineration causes serious problems related to hot corrosion of boiler tubes and poses a safety threat for such plants. In this study, a pseudo-de Laval nozzle was employed in a twin-wire arc spray system to enhance the velocity of in-flight particles. Highly dense NiCr-based coatings were obtained using the modified nozzle gun. The coating morphology was characterized by optical microscopy and scanning electron microscopy, and hot corrosion testing was carried out in a synthetic molten chloride salt environment. Results showed that the dense NiCr-based coatings exhibited high resistance against corrosion by chlorine, which can be related to the typical splat lamellar microstructure and chemical composition as well as minor alloying elements such as Ti and Mo.

  17. Structural and Physical Characteristics of Ultrananocrystalline Diamond/Hydrogenated Amorphous Carbon Composite Films Deposited Using a Coaxial Arc Plasma Gun

    Science.gov (United States)

    Yoshitake, Tsuyoshi; Nakagawa, You; Nagano, Akira; Ohtani, Ryota; Setoyama, Hiroyuki; Kobayashi, Eiichi; Sumitani, Kazushi; Agawa, Yoshiaki; Nagayama, Kunihito

    2010-01-01

    Ultrananocrystalline diamond (UNCD)/hydrogenated amorphous carbon (a-C:H) films were formed without initial nucleation using a coaxial arc plasma gun. The UNCD crystallite diameters estimated from the X-ray diffraction peaks were approximately 2 nm. The Fourier transform infrared absorption spectrum exhibited an intense sp3-CH peak that might originate from the grain boundaries between UNCD crystallites whose dangling bonds are terminated with hydrogen atoms. A narrow sp3 peak in the photoemission spectrum implied that the film comprises a large number of UNCD crystallites. Large optical absorption coefficients at photon energies larger than 3 eV that might be due to the grain boundaries are specific to the UNCD/a-C:H films.

  18. Hot Corrosion Behavior of Arc-Sprayed Highly Dense NiCr-Based Coatings in Chloride Salt Deposit

    Science.gov (United States)

    Qin, Enwei; Yin, Song; Ji, Hua; Huang, Qian; Liu, Zekun; Wu, Shuhui

    2017-04-01

    To make cities more environmentally friendly, combustible wastes tend to be incinerated in waste-to-energy power plant boilers. However, release of chlorine gas (Cl2) during incineration causes serious problems related to hot corrosion of boiler tubes and poses a safety threat for such plants. In this study, a pseudo-de Laval nozzle was employed in a twin-wire arc spray system to enhance the velocity of in-flight particles. Highly dense NiCr-based coatings were obtained using the modified nozzle gun. The coating morphology was characterized by optical microscopy and scanning electron microscopy, and hot corrosion testing was carried out in a synthetic molten chloride salt environment. Results showed that the dense NiCr-based coatings exhibited high resistance against corrosion by chlorine, which can be related to the typical splat lamellar microstructure and chemical composition as well as minor alloying elements such as Ti and Mo.

  19. Low-temperature deposited ZnO thin films on the flexible substrate by cathodic vacuum arc technology

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Ru-Yuan, E-mail: ryyang@mail.npust.edu.tw [Department of Materials Engineering, National Ping-Tung University of Science and Technology, Taiwan (China); Weng, Min-Hang [Medical Devices and Opto-electronics Equipment Department, Metal Industries Research and Development Center, Taiwan (China); Pan, Cheng-Tang [Department of Mechanical and Electron-Mechanical Engineering, National Sun Yat-Sen University, Kaohsiung County 804, Taiwan (China); Hsiung, Chin-Min; Huang, Chun-Chih [Department of Mechanical Engineering, National Ping-Tung University of Science and Technology, Taiwan (China)

    2011-06-01

    In this paper, un-doped zinc oxide (ZnO) films with various thicknesses (150, 250, 350, 450 and 550 nm) were successfully prepared onto PET substrates using cathodic vacuum arc technique at low-temperature (<40 deg. C). Their microstructure, optical and electrical properties were investigated and discussed. The films showed (0 0 2) peaks, an average transmittance over 80% in the visible region. Calculated values of the band gap are around 3.29-3.33 eV when the film thickness increased, indicating a slight blue shift of optical transmission spectra. The lowest resistivity about 5.26 x 10{sup -3} {Omega} cm could be achieved for the un-doped ZnO film with thickness of 550 nm.

  20. Trace elements deposition in the Tierra del Fuego region (south Patagonia) by using lichen transplants after the Puyehue-Cordón Caulle (north Patagonia) volcanic eruption in 2011.

    Science.gov (United States)

    Conti, Marcelo Enrique; Jasan, Raquel; Finoia, Maria Grazia; Iavicoli, Ivo; Plá, Rita

    2016-04-01

    Lichen Usnea barbata transplants were tested as a biomonitor of atmospheric deposition in an apparently pristine environment that is Tierra del Fuego region (Patagonia, Argentina). The present survey is connected with the volcanic eruption that started in north Patagonia on June 4, 2011 from the Puyehue-Cordón Caulle volcano, Chile (north Patagonia, at 1700 km of distance of our sampling sites). Lichens were collected in September 2011 (one month of exposure) and September 2012 (1 year of exposure) in 27 sites covering the northern region of the province where trees are not present. The atmospheric deposition of 27 elements by using Neutron Activation Analysis (NAA) was determined in the collected samples. The first aim of the study was to evaluate the influence of the volcanic eruption on the regional atmospheric deposition comparing our results with baseline data we determined in U. barbata in 2006 in the same sites. The second aim was to test possible patterns of bioaccumulation between the two sampling campaigns after the volcanic eruption. With respect to 2006 baseline levels, we found significant higher levels for As, Ba, Co, Cr, Cs, Na, Sb and U in lichens collected after 1 month of exposure (first sampling campaign--2011). Between the two sampling campaigns (2011-2012) after the eruption, lichens reflected the natural contamination by volcanic ashes with significantly higher median levels of Br, Cr, Fe, K, Na, Sc, and Se. Results confirmed the very good aptitude of U. barbata to reflect the levels of elements in the environment at global scale and to reflect the volcanic emissions at distant places. Volcanic eruptions cause the emission in the atmosphere of elevated levels of particulate matter. In this regard, our findings demonstrate the importance to evaluate the metal composition of the particles to avoid possible health effects.

  1. New Pliocene-Pleistocene 40Ar/ 39Ar ages fill in temporal gaps in the Nicaraguan volcanic record

    Science.gov (United States)

    Saginor, Ian; Gazel, Esteban; Carr, Michael J.; Swisher, Carl C., III; Turrin, Brent

    2011-04-01

    The volcanic record of western Nicaragua documents a significant lull in volcanic activity that has persisted from the late Miocene (~ 7 Ma) to the formation of the modern volcanic front around 350 ka. This study fills this gap for the first time with samples collected in Northwest Nicaragua between Cosigüina and San Cristóbal volcanoes and with samples collected from the Nicaraguan Depression. We found two previously unknown volcanic units ranging from 3.6 to 1.3 Ma and the improved volcanic record allows us to reconstruct the geochemical evolution of the Nicaraguan arc. U/Th values increased by nearly threefold since the Miocene following the "carbonate crash" at 10 Ma, when dominantly carbonate sediment deposition shifted toward hemipelagic sediment deposition. This transition was thought to be abrupt, however our new data show that it took place gradually over the last 7 Ma. Northwest Nicaragua is a particularly interesting case study because it contains Middle Miocene volcanism on either side of the Nicaraguan Depression, the Coyol Formation (25-7 Ma) to the East and the Tamarindo Formation (14.7-11.7 Ma) to the West. The presence of Mid Miocene volcanism on either side of the Nicaraguan Depression has led to the hypothesis that the two coeval units, currently separated by ~ 100 km, were once connected and have since been separated by extension. Here, we present data suggesting that the Tamarindo and Coyol are geochemically distinct and therefore cannot be considered part of the same unit.

  2. H_2O and CO_2 in magmas from the Mariana arc and back arc systems

    OpenAIRE

    Newman, Sally; Stolper, Edward; STERN, Robert

    2000-01-01

    We examined the H2O and CO2 contents of glasses from lavas and xenoliths from the Mariana arc system, an intraoceanic convergent margin in the western Pacific, which contains an active volcanic arc, an actively spreading back arc basin, and active behind-the-arc cross-chain volcanoes. Samples include (1) glass rims from Mariana arc, Mariana trough, and cross-chain submarine lavas; (2) glass inclusions in arc and trough phenocrysts; and (3) glass inclusions from a gabbro + anorthosite xenolith...

  3. Volcanic Lightning in the Laboratory: The Effect of Ultra-Rapid Melting on Ash Particles

    Science.gov (United States)

    Mueller, S.; Keller, F.; Helo, C.; Buhre, S.; Castro, J. M.

    2016-12-01

    Lightning discharge is a common process occurring at explosive volcanic eruptions. During the formation of ash plumes, the dynamical interaction of ash particles creates charges which can, given a sufficiently large charge gradient, cause lightning discharges within the plume (`plume lightning') or from ground to plume (`near-vent lightning'), respectively. Given the extreme heat release during the short duration of a discharge (potentially > 30.000 K), it is likely that the ash particles suspended in a plume are, in any form, affected by volcanic lightning. Genareau et al. (2015) found evidence of glass spherules and glass aggregates in ash deposits of two explosive eruptions (Eyjafjallajökull, Mt. Redoubt), and linked them to short-term melting processes induced by volcanic lightning (analogue to fulgurites). In order to systematically investigate the potential impact of lightning on air-suspended ash we have designed a new experimental setup. An electric arc between two electrodes is generated by a 400 Amp arc welding device. Ash-sized sample material is then blown into the established lightning arc, and a certain proportion of the injected silicate glasses and/or minerals is melted due to the high temperatures in and around the plasma channel. In a first set of experiments, we have used natural volcanic ash from Laacher See Tephra (Eifel, Germany) in distinct size fractions between 36 and 250 microns, in order to qualitatively investigate melting and amalgamation features. Spherule and aggregate textures similar to those reported by Genareau et al. (2015) were successfully reproduced during these experiments. In a second set of experiments, homogenized phonolitic glass fragments, in different size fractions, were subjected to the electric arc and subsequently analyzed under the EMP, in order to investigate effects of "flash melting" on major element glass chemistry. Genareau K, Wardman JB, Wilson TM, McNutt SR, Izbekov P (2015): Lightning-induced volcanic

  4. The South Tibetan Tadpole Zone: Ongoing density sorting at the Moho beneath the Indus-Tsangpo suture zone (and beneath volcanic arcs?)

    Science.gov (United States)

    Kelemen, Peter; Hacker, Bradley

    2016-04-01

    at less than 700°C (e.g. Jackson 02). We build on earlier studies (LePichon et al 92, 97; Schulte-Pelkum et al 05; Monsalve et al 08) to develop the hypothesis that there is rapid growth of garnet at 80 km and 1000°C within subducting Indian crust, causing increased rock densities. Dense eclogites founder into the mantle, while relatively buoyant lithologies accumulate in thickening lower crust. Mantle return flow plus radioactive heating in thick, felsic crust maintains high temperature, facilitating formation of hybrid magmas and pyroxenites. The crustal volume grows at 760 cubic m/yr/m of strike length. Moho-depth earthquakes may be due to localized deformation and thermal runaway in weak layers and along the margins of dense, foundering diapirs (e.g., Larsen & Yuen 97; Braeck & Podladchikov 07; Kelemen & Hirth 07; Lister et al 08; Kufner et al 16). A similar process may take place at some convergent margins, where forearc crust is thrust beneath hot, magmatic arc crust, leading to extensive, Moho-depth density sorting and hybrid crust-mantle magmatism in Arc Tadpole Zones.

  5. Petrogenesis of volcanic rocks that host the world-class Agsbnd Pb Navidad District, North Patagonian Massif: Comparison with the Jurassic Chon Aike Volcanic Province of Patagonia, Argentina

    Science.gov (United States)

    Bouhier, Verónica E.; Franchini, Marta B.; Caffe, Pablo J.; Maydagán, Laura; Rapela, Carlos W.; Paolini, Marcelo

    2017-05-01

    We present the first study of the volcanic rocks of the Cañadón Asfalto Formation that host the Navidad world-class Ag + Pb epithermal district located in the North Patagonian Massif, Patagonia, Argentina. These volcanic and sedimentary rocks were deposited in a lacustrine environment during an extensional tectonic regime associated with the breakup of Gondwana and represent the mafic to intermediate counterparts of the mainly silicic Jurassic Chon Aike Volcanic Province. Lava flows surrounded by autobrecciated carapace were extruded in subaerial conditions, whereas hyaloclastite and peperite facies suggest contemporaneous subaqueous volcanism and sedimentation. LA-ICPMS Usbnd Pb ages of zircon crystals from the volcanic units yielded Middle Jurassic ages of 173.9 ± 1.9 Ma and 170.8 ± 3 Ma. In the Navidad district, volcanic rocks of the Cañadón Asfalto Formation show arc-like signatures including high-K basaltic-andesite to high-K dacite compositions, Rb, Ba and Th enrichment relative to the less mobile HFS elements (Nb, Ta), enrichment in light rare earth elements (LREE), Ysbnd Ti depletion, and high Zr contents. These characteristics could be explained by assimilation of crustal rocks in the Jurassic magmas, which is also supported by the presence of zircon xenocrysts with Permian and Middle-Upper Triassic ages (281.3 Ma, 246.5, 218.1, and 201.3 Ma) and quartz xenocrysts recognized in these volcanic units. Furthermore, Sr and Nd isotope compositions suggest a contribution of crustal components in these Middle Jurassic magmas. High-K basaltic andesite has initial 87Sr/86Sr ratios of 0.70416-0.70658 and ξNd(t) values of -5.3 and -4. High-K dacite and andesite have initial 87Sr/86Sr compositions of 0.70584-0.70601 and ξNd(t) values of -4,1 and -3,2. The range of Pb isotope values (206Pb/204Pb = 18.28-18.37, 207Pb/204Pb = 15.61-15.62, and 208Pb/204Pb = 38.26-38.43) of Navidad volcanic rocks and ore minerals suggest mixing Pb sources with contributions of

  6. Effect of pulsed bias on the properties of ZrN/TiZrN films deposited by a cathodic vacuum arc

    Institute of Scientific and Technical Information of China (English)

    Zhang Guo-Ping; Wang Xing-Quan; Lü Guo-Hua; Zhou Lan; Huang Jun; Chen Wei; Yang Si-Ze

    2013-01-01

    .ZrN/TiZrN multilayers are deposited by using the cathodic vacuum arc method with different substrate bias (from 0 to-800 V),using Ti and Zr plasma flows in residual N2 atmosphere,combined with ion bombardment of sample surfaces.The effect of pulsed bias on the structure and properties of films is investigated.Microstructure of the coating is analyzed by X-ray diffraction (XRD),and scanning electron microscopy (SEM).In addition,nanohardness,Young's modulus,and scratch tests are performed.The experimental results show that the films exhibit a nanoscale multilayer structure consisting of TiZrN and ZrN phases.Solid solutions are formed for component TiZrN films.The dominant preferred orientation of TiZrN films is (111) and (220).At a pulsed bias of-200 V,the nanohardness and the adhesion strength of the ZrN/TiZrN multilayer reach a maximum of 38 GPa,and 78 N,respectively.The ZrN/TiZrN multilayer demonstrates an enhanced nanohardness compared with binary TiN and ZrN films deposited under equivalent conditions.

  7. Effect of modulation periods on the microstructure and mechanical properties of DLC/TiC multilayer films deposited by filtered cathodic vacuum arc method

    Energy Technology Data Exchange (ETDEWEB)

    Xu, Zhaoying [Key Laboratory of Advanced Technologies of Materials, Ministry of Education of China, School of Materials Science and Engineering, Southwest Jiaotong University, Chengdu 610031, Sichuan (China); State Key Laboratory of Vanadium and Titanium Resources Comprehensive Utilization, Pangang Group Research Institute Co., Ltd., Panzhihua 617000, Sichuan (China); Sun, H. [Key Laboratory of Advanced Technologies of Materials, Ministry of Education of China, School of Materials Science and Engineering, Southwest Jiaotong University, Chengdu 610031, Sichuan (China); Leng, Y.X., E-mail: yxleng@263.net [Key Laboratory of Advanced Technologies of Materials, Ministry of Education of China, School of Materials Science and Engineering, Southwest Jiaotong University, Chengdu 610031, Sichuan (China); Li, Xueyuan; Yang, Wenmao [Institute of Mechanical Manufacturing Technology, China Academy of Engineering Physics, Mianyang 621900, Sichuan (China); Huang, N. [Key Laboratory of Advanced Technologies of Materials, Ministry of Education of China, School of Materials Science and Engineering, Southwest Jiaotong University, Chengdu 610031, Sichuan (China)

    2015-02-15

    Highlights: • DLC/TiC multilayer films with different modulation periods at same modulation ratio 1:1 were deposited by FCVA. • The residual stress of DLC/TiC multilayer films decreases with the modulation periods decrease. • The hardness of the multilayer DLC films decreases with modulation periods increasing. - Abstract: The high stress of diamond-like carbon (DLC) film limits its thickness and adhesion on substrate. Multilayer structure is one approach to overcome this disadvantage. In this paper, the DLC/TiC multilayer films with different modulation periods (80 nm, 106 nm or 160 nm) at same modulation ratio of 1:1 were deposited on Si(1 0 0) wafer and Ti-6Al-4V substrate by filtered cathodic vacuum arc (FCVA) technology. X-ray diffraction (XRD), transmission electron microscopy (TEM), nanoindention and wear test were employed to investigate the effect of modulation periods on the microstructure and mechanical properties of the multilayer films. The results showed that the residual stress of the DLC/TiC multilayer films could be effectively reduced and the residual stress decreased with the modulation periods decreasing. The hardness of the DLC/TiC multilayer films increased with modulation periods decreasing. The DLC/TiC multilayer film with modulation period of 106 nm had the best wear resistance due to the good combination of hardness, ductility and low compressive stress.

  8. Episodic Volcanism and Geochemistry in Western Nicaragua

    Science.gov (United States)

    Saginor, I.; Carr, M. J.; Gazel, E.; Swisher, C.; Turrin, B.

    2007-12-01

    The active volcanic arc in western Nicaragua is separated from the Miocene arc by a temporal gap in the volcanic record, during which little volcanic material was erupted. Previous work suggested that this gap lasted from 7 to 1.6 Ma, during which volcanic production in Nicaragua was limited or nonexistent. Because the precise timing and duration of this gap has been poorly constrained, recent fieldwork has focused on locating samples that may have erupted close to or even during this apparent hiatus in activity. Recent 40Ar/39Ar dates reveal pulses of low- level episodic volcanism at 7 Ma and 1 Ma between the active and Miocene arcs with current volcanism beginning ~350 ka. In addition, sampling from an inactive area between Coseguina and San Cristobal yielded two distinct groupings of ages; one of Tamarindo age (13 Ma) and the other around 3.5 Ma-the only samples of that age collected on-strike with the active arc. This raises the possibility the bases of the other active volcanoes contain lavas that are older than expected, but have been covered by subsequent eruptions. The Miocene arc differs from the active arc in Central America in several ways, with the latter having higher Ba/La and U/Th values due to increased slab input and changes in subducted sediment composition. Analysis of sample C-51 and others taken from the same area may shed light on the timing of this shift from high to low Ba/La and U/Th values. More importantly, it may help explain why the arc experienced such a dramatic downturn in volcanic production during this time. We also report 25 new major and trace element analyses that shed some light on the origins of these minor episodes of Nicaraguan volcanism. These samples are currently awaiting Sr and Nd isotopic analyses.

  9. Tellurium-Gold Mineralization Related to Cryptoexplosive Breccias within Volcanic Pipe in Zhuojiazhuang Gold Deposit,Shandong Province, China

    Institute of Scientific and Technical Information of China (English)

    Zeng Qingdong; Liu Tiebing; Shen Yuanchao; Li Guangming

    2002-01-01

    Zhuojiazhuang gold deposit (ZGD) is the most enriched breccia pipe type gold deposit in East China, resulted from cryptoexplosion related to alkalinic magmatism and orebearing fluid filling. The ZGD is a small-sized mine with over 5 tons of gold reserves and grade of 156g/t in average and the highest 2 728 g/t as known. In addition, tellurium and silver are also valuable.The mineralized breccia pipe is cylinder-like in shape with 15 m long and 10 m wide and controlled by intersection ofNW and EW trend faults. Mining level has reached 170 m below the surface, but the whole pipe mineralization is still stable. Mineralization commonly occurs within the cements of breccias. Gold ores consist of hydrothermal breccia ore, shatteredbreccia ore and cataclastic ore. From the center of the ore body outwards, there is the transition from hydrothermal breccia toshattered breccia and then to cataclastic ores. According to composition and amount of the cements, the hydrothermal brecciaores can further be divided into three subtypes: sulfides cemented, hydrothermal mineral cemented and magma cemented.The content of gold is closely related to the types of the cements. The grade of the sulfide cemented breccia is the highestone, usually more than 1 000 g/t, and the known maximum grade is 2 728 g/t. The composition of the shattered breccia ismainly dioritic porphyrite and cemented by hydrothermal minerals, the grade ranges from ten to several tens g/t. The catsclastic ores are mainly composed of dioritic porphyrite, syenitic porphyry, as well as carbonate with mineralized veins, and the grade is only 35 g/t.Major ore minerals consist of pyrite, native tellurium, sphalerite, with minor calaverite, galena and altaite. Gangueminerals are composed of microcrystalline quartz, decktite and fluorite, with minor sericite and calcite. Brecciated and disseminited structures are main structures of ores. Four ore-forming stages are defined: microcrystalline quartz-pyrite stage

  10. Volcano geodesy in the Cascade arc, USA

    Science.gov (United States)

    Poland, Michael P.; Lisowski, Michael; Dzurisin, Daniel; Kramer, Rebecca; McLay, Megan; Pauk, Ben

    2017-08-01

    Experience during historical time throughout the Cascade arc and the lack of deep-seated deformation prior to the two most recent eruptions of Mount St. Helens might lead one to infer that Cascade volcanoes are generally quiescent and, specifically, show no signs of geodetic change until they are about to erupt. Several decades of geodetic data, however, tell a different story. Ground- and space-based deformation studies have identified surface displacements at five of the 13 major Cascade arc volcanoes that lie in the USA (Mount Baker, Mount St. Helens, South Sister, Medicine Lake, and Lassen volcanic center). No deformation has been detected at five volcanoes (Mount Rainier, Mount Hood, Newberry Volcano, Crater Lake, and Mount Shasta), and there are not sufficient data at the remaining three (Glacier Peak, Mount Adams, and Mount Jefferson) for a rigorous assessment. In addition, gravity change has been measured at two of the three locations where surveys have been repeated (Mount St. Helens and Mount Baker show changes, while South Sister does not). Broad deformation patterns associated with heavily forested and ice-clad Cascade volcanoes are generally characterized by low displacement rates, in the range of millimeters to a few centimeters per year, and are overprinted by larger tectonic motions of several centimeters per year. Continuous GPS is therefore the best means of tracking temporal changes in deformation of Cascade volcanoes and also for characterizing tectonic signals so that they may be distinguished from volcanic sources. Better spatial resolution of volcano deformation can be obtained through the use of campaign GPS, semipermanent GPS, and interferometric synthetic aperture radar observations, which leverage the accumulation of displacements over time to improve signal to noise. Deformation source mechanisms in the Cascades are diverse and include magma accumulation and withdrawal, post-emplacement cooling of recent volcanic deposits, magmatic

  11. Volcano geodesy in the Cascade arc, USA

    Science.gov (United States)

    Poland, Michael; Lisowski, Michael; Dzurisin, Daniel; Kramer, Rebecca; McLay, Megan; Pauk, Benjamin

    2017-01-01

    Experience during historical time throughout the Cascade arc and the lack of deep-seated deformation prior to the two most recent eruptions of Mount St. Helens might lead one to infer that Cascade volcanoes are generally quiescent and, specifically, show no signs of geodetic change until they are about to erupt. Several decades of geodetic data, however, tell a different story. Ground- and space-based deformation studies have identified surface displacements at five of the 13 major Cascade arc volcanoes that lie in the USA (Mount Baker, Mount St. Helens, South Sister, Medicine Lake, and Lassen volcanic center). No deformation has been detected at five volcanoes (Mount Rainier, Mount Hood, Newberry Volcano, Crater Lake, and Mount Shasta), and there are not sufficient data at the remaining three (Glacier Peak, Mount Adams, and Mount Jefferson) for a rigorous assessment. In addition, gravity change has been measured at two of the three locations where surveys have been repeated (Mount St. Helens and Mount Baker show changes, while South Sister does not). Broad deformation patterns associated with heavily forested and ice-clad Cascade volcanoes are generally characterized by low displacement rates, in the range of millimeters to a few centimeters per year, and are overprinted by larger tectonic motions of several centimeters per year. Continuous GPS is therefore the best means of tracking temporal changes in deformation of Cascade volcanoes and also for characterizing tectonic signals so that they may be distinguished from volcanic sources. Better spatial resolution of volcano deformation can be obtained through the use of campaign GPS, semipermanent GPS, and interferometric synthetic aperture radar observations, which leverage the accumulation of displacements over time to improve signal to noise. Deformation source mechanisms in the Cascades are diverse and include magma accumulation and withdrawal, post-emplacement cooling of recent volcanic deposits, magmatic

  12. The magmatic and eruptive response of arc volcanoes to deglaciation: insights from southern Chile

    Science.gov (United States)

    Rawson, Harriet; Mather, Tamsin A.; Pyle, David M.; Smith, Victoria C.; Fontijn, Karen; Lachowycz, Stefan; Naranjo, José A.; Watt, Sebastian F. L.

    2016-04-01

    Volcanism exerts a major influence on Earth's atmosphere and surface environments. Understanding feedbacks between climate and long-term changes in rates or styles of volcanism is important, but unresolved. For example, it has been proposed that a pulse of activity at once-glaciated volcanoes contributed to increasing atmospheric carbon dioxide accelerating early Holocene climate change. In plate-tectonic settings where magmatism is driven by decompression melting there is convincing evidence that activity is modulated by changes in ice- or water-loading across glacial/interglacial cycles. The response of subduction-related volcanoes, where the crust is typically thicker and mantle melting is dominated by flux melting, remains unclear. Since arc volcanoes account for 90% of subaerial eruptions, they are the most significant sources of volcanic gases and tephra directly to the atmosphere. Testing the response of arc volcanoes to deglaciation requires careful work to piece together eruption archives. Records of effusive eruptions from long-lived, arc stratovolcanoes are challenging to obtain and date; while deposits from the explosive eruptions, which dominate arc records, are prone to erosion and reworking. Our new high-resolution post-glacial (Phase 3), eruptive fluxes have been elevated, and dominated by explosive eruptions of intermediate magmas. We propose that this time-varying behaviour reflects changes in crustal plumbing systems, and magma storage timescales. During glaciations, magmas stall in the crust and differentiate to form large, evolved melt reservoirs. After the ice load is removed, much of this stored magma erupts (Phase 1). Subsequently, less-differentiated melts infiltrate the shallow crust (Phase 2). Then, as storage timescales increase, volcanism returns towards more evolved compositions (Phase 3). We suggest that on these short timescales, these observed variations are unlikely to reflect changes in mantle melt flux. Instead, the phenomena are

  13. Contrasting records from mantle to surface of Holocene lavas of two nearby arc volcanic complexes: Caburgua-Huelemolle Small Eruptive Centers and Villarrica Volcano, Southern Chile

    Science.gov (United States)

    Morgado, E.; Parada, M. A.; Contreras, C.; Castruccio, A.; Gutiérrez, F.; McGee, L. E.

    2015-11-01

    Most of the small eruptive centers of the Andean Southern Volcanic Zone are built over the Liquiñe-Ofqui Fault Zone (LOFZ), a NS strike-slip (> 1000 km length) major structure, and close to large stratovolcanoes. This contribution compares textural features, compositional parameters, and pre- and syn-eruptive P,T conditions, between basaltic lavas of the Caburgua-Huelemolle Small Eruptive Centers (CHSEC) and the 1971 basaltic andesite lava of the Villarrica Volcano located 10 km south of the CHSEC. Olivines and clinopyroxenes occur as phenocrysts and forming crystal clots of the studied lavas. They do not markedly show compositional differences, except for the more scattered composition of the CHSEC clinopyroxenes. Plagioclase in CHSEC lavas mainly occur as phenocrysts or as microlites in a glass-free matrix. Two groups of plagioclase phenocrysts were identified in the 1971 Villarrica lava based on crystal size, disequilibrium features and zonation patterns. Most of the CHSEC samples exhibit higher LaN/YbN and more scattered Sr-Nd values than 1971 Villarrica lava samples, which are clustered at higher 143Nd/144Nd values. Pre-eruptive temperatures of the CHSEC-type reservoir between 1162 and 1165 ± 6 °C and pressures between 10.8 and 11.4 ± 1.7 kb consistent with a deep-seated reservoir were obtained from olivine-augite phenocrysts. Conversely, olivine-augite phenocrysts of 1971 Villarrica lava samples record pre-eruptive conditions of two stages or pauses in the magma ascent to the surface: 1208 ± 6 °C and 6.3-8.1 kb ± 1.7 kb (deep-seated reservoir) and 1164-1175 ± 6 °C and ≤ 1.4 kb (shallow reservoir). At shallow reservoir conditions a magma heating prior to the 1971 Villarrica eruption is recorded in plagioclase phenocrysts. Syn-eruptive temperatures of 1081-1133 ± 6 °C and 1123-1148 ± 6 °C were obtained in CHSEC and 1971 Villarrica lava, respectively using equilibrium olivine-augite microlite pairs. The LOFZ could facilitate a direct transport to

  14. High-Temperature Erosion Resistance of FeBSiNb Amorphous Coatings Deposited by Arc Spraying for Boiler Applications

    Science.gov (United States)

    Cheng, J. B.; Liang, X. B.; Chen, Y. X.; Wang, Z. H.; Xu, B. S.

    2013-06-01

    Erosive high-temperature wear in boilers is one of the main causes of downtime and one of the principal engineering problems in these installations. This article discusses the use of FeBSiNb amorphous coatings synthesized by arc spraying to improve elevated-temperature erosion resistance for boiler applications. The influence of test temperature, velocity, and impact angle on material wastage was revealed using air solid particle erosion rig. The experimental results showed that moderate degradation of the coating was predominant at lower impact velocity and impact angles, while severe damage arose for higher velocities and impact angles. The erosion behavior of the coating was sensitive to test temperature. The erosion rates of the coating decreased as a function of environment temperature. The relationship between microstructure and erosion resistance of the coating was also analyzed in details. The FeBSiNb coating had excellent elevated-temperature erosion resistance at temperatures at least up to 600 °C during service.

  15. Achieving high mobility ZnO : Al at very high growth rates by dc filtered cathodic arc deposition

    Energy Technology Data Exchange (ETDEWEB)

    Mendelsberg, R J; Lim, S H N; Wallig, J; Anders, A [Lawrence Berkeley National Laboratory, Plasma Applications Group, Berkeley, CA (United States); Zhu, Y K [Harbin Institute of Technology, Harbin (China); Milliron, D J, E-mail: aanders@lbl.gov [Lawrence Berkeley National Laboratory, Molecular Foundry, Berkeley, CA (United States)

    2011-06-15

    Achieving a high growth rate is paramount for making large-area transparent conducting oxide coatings at a low cost. Unfortunately, the quality of thin films grown by most techniques degrades as the growth rate increases. Filtered dc cathodic arc is a lesser known technique which produces a stream of highly ionized plasma, in stark contrast to the neutral atoms produced by standard sputter sources. Ions bring a large amount of potential energy to the growing surface which is in the form of heat, not momentum. By minimizing the distance from cathode to substrate, the high ion flux gives a very high effective growth temperature near the film surface without causing damage from bombardment. The high surface temperature is a direct consequence of the high growth rate and allows for high-quality crystal growth. Using this technique, 500-1300 nm thick and highly transparent ZnO : Al films were grown on glass at rates exceeding 250 nm min{sup -1} while maintaining resistivity below 5 x 10{sup -4} {Omega} cm with electron mobility as high as 60 cm{sup 2} V{sup -1} s{sup -1}. (fast track communication)

  16. Surface morphology and tribological properties of TiN film deposited with different arc currents%不同弧源电流TiN薄膜的表面形貌及其摩擦学性能研究

    Institute of Scientific and Technical Information of China (English)

    史新伟

    2013-01-01

    TiN films were prepared on Si and stainless steel substrates with different arc currents by the AIP-01 multi-arc ion plating equipment. The hardness, surface morphology and friction coefficient of the as-deposited films were tested.The effect of arc current on the micro-paricles (MP) was analyzed from the perspective of physical mechanism of arc deposition. The results show that with the increasing of arc current,the deposition rate was improved and the hardness was enhanced.But the number and size of the MPs and the friction coefficient increased. So the arc current control is a key problem to get TiN films with good properties.%本文使用AIP-01型国产多弧离子镀膜设备,采用不同的弧源电流在不锈钢衬底及Si片上制备了TiN薄膜,对其硬度、表面形貌以及摩擦系数等进行了测试,从电弧沉积的物理机制角度详细分析了弧源电流对TiN薄膜表面熔滴的影响,结果表明:随着弧源电流的增大,薄膜沉积速率增大、硬度提高,但薄膜表面熔滴(MP)数量增多、尺寸变大,表面粗糙,摩擦系数增大,因此控制最佳弧源电流来获得最好的薄膜性能是离子镀TiN薄膜的关键问题之一.

  17. Seed layer stimulated growth of crystalline high Al containing (Al,Cr){sub 2}O{sub 3} coatings deposited by cathodic arc evaporation

    Energy Technology Data Exchange (ETDEWEB)

    Pohler, M., E-mail: markus.pohler@stud.unileoben.ac.at [Christian Doppler Laboratory for Advanced Hard Coatings at the Department of Physical Metallurgy and Materials Testing, Montanuniversität Leoben, Franz-Josef-Straße 18, A-8700 Leoben (Austria); Franz, R. [Christian Doppler Laboratory for Advanced Hard Coatings at the Department of Physical Metallurgy and Materials Testing, Montanuniversität Leoben, Franz-Josef-Straße 18, A-8700 Leoben (Austria); Ramm, J. [OC Oerlikon Balzers AG, Iramali 18, 9469 Balzers (Liechtenstein); Polcik, P. [PLANSEE Composite Materials GmbH, Siebenbürgerstraße 23, 86983 Lechbruck am See (Germany); Mitterer, C. [Christian Doppler Laboratory for Advanced Hard Coatings at the Department of Physical Metallurgy and Materials Testing, Montanuniversität Leoben, Franz-Josef-Straße 18, A-8700 Leoben (Austria)

    2014-01-01

    Single layer and dual layer (Al{sub x}Cr{sub 1−x}){sub 2}O{sub 3} coatings were synthesised by cathodic arc evaporation with different Al contents to study their growth characteristics. It was demonstrated that variations in the Al content, the energy of incident particles and the coating thickness control the crystallinity and the coating texture. Analysis by X-ray diffraction revealed a distinct (110) out of plane orientation after transition from a fine grained nucleation zone to a columnar growth mode. Furthermore, the impact of (Al{sub x}Cr{sub 1−x}){sub 2}O{sub 3} seed layers with x = 0.25 and 0.5 on the growth of (Al{sub x}Cr{sub 1−x}){sub 2}O{sub 3} top layers with x = 0.7 and 0.85 was evaluated in detail. According to X-ray diffraction and transmission electron microscopy, the development of the corundum-type crystal structure of the top layer was promoted by local epitaxy if the low Al containing seed layer exhibited a pronounced columnar structure. In this way, crystalline corundum-type coatings with an Al content up to x = 0.85 were obtained. - Highlights: • Industrial scale cathodic arc deposition of corundum type (Al{sub x}Cr{sub 1−x}){sub 2}O{sub 3} coatings • Discussion of the growth characteristics for different Al/Cr ratios • Characterisation of growth regimes in dual layer coatings • Template stimulated growth of crystalline corundum-type (Al{sub 0.85}Cr{sub 0.15}){sub 2}O{sub 3} coatings • Influence of bias voltage and seed layer thickness on the template effect.

  18. The structure and mechanical properties of multilayer nanocrystalline TiN/ZrN coatings obtained by vacuum-arc deposition

    Directory of Open Access Journals (Sweden)

    A.V. Demchyshyn

    2007-12-01

    Full Text Available TiN/ZrN multilayered condensates on BK-8 carbide tips substrates (62 HRC were produced by the vacuumarc deposition technique, using Ti and Zr plasma flows in reactive nitrogen gas medium with working pressure of 6.6·10–1 Pa. The TiN/ZrN multilayered condensates consist of TiN and ZrN sublayers, which have a thickness of ~100 nm, controlled by the processing parameters of the used deposition technique. The obtained coatings have hardness of 45 GPa and Young’s modulus of 320 GPa. The obtained results show that mechanical properties of such multilayered composites are considerably improved in comparison to those for the single-component coatings, TiN and ZrN. The dependence of hardness and Young’s modulus of the composites on sublayer thickness within a range of 100 nm was determined. The investigated structure and improved mechanical properties of the TiN/ZrN multilayered condensates would be very good platform for finding their industrial application, such as hard coatings with different purposes.

  19. Refined depositional history and dating of the Tongaporutuan reference section, north Taranaki, New Zealand: new volcanic ash U-Pb zircon ages, biostratigraphy and sedimentation rates

    Science.gov (United States)

    Maier, K.L.; Crundwell, Martin P.; Coble, Matthew A.; Kingsley-Smith, Peter R.; Graham, Stephan A.

    2016-01-01

    This study presents new radiometric ages from volcanic ash beds within a c. 1900 m thick, progradational, deep-water clastic slope succession of late Miocene age exposed along the north Taranaki coast of the North Island, New Zealand. The ash beds yield U–Pb zircon ages ranging from 10.63 ± 0.65 Ma to 8.97 ± 0.22 Ma. The new ages are compatible with and provide corroboration of New Zealand Tongaporutuan Stage planktic foraminiferal and bolboformid biostratigraphic events identified in the same section. The close accord between these two age datasets provides a stratigraphically consistent and coherent basis for examining margin evolution. The arrival of a prograding clastic wedge and ensuing upward shoaling is recorded by sedimentation rates c. 2000 m/Ma–1 that are an order of magnitude higher than sedimentation rates on the precursor deep basin floor. This outcrop study provides new constraints for interpreting analogous subsurface deposits in Taranaki Basin and complements the regional late Miocene biostratigraphic dating framework.

  20. Catastrophic volcanism

    Science.gov (United States)

    Lipman, Peter W.

    1988-01-01

    Since primitive times, catastrophes due to volcanic activity have been vivid in the mind of man, who knew that his activities in many parts of the world were threatened by lava flows, mudflows, and ash falls. Within the present century, increasingly complex interactions between volcanism and the environment, on scales not previously experienced historically, have been detected or suspected from geologic observations. These include enormous hot pyroclastic flows associated with collapse at source calderas and fed by eruption columns that reached the stratosphere, relations between huge flood basalt eruptions at hotspots and the rifting of continents, devastating laterally-directed volcanic blasts and pyroclastic surges, great volcanic-generated tsunamis, climate modification from volcanic release of ash and sulfur aerosols into the upper atmosphere, modification of ocean circulation by volcanic constructs and attendent climatic implications, global pulsations in intensity of volcanic activity, and perhaps triggering of some intense terrestrial volcanism by planetary impacts. Complex feedback between volcanic activity and additional seemingly unrelated terrestrial processes likely remains unrecognized. Only recently has it become possible to begin to evaluate the degree to which such large-scale volcanic processes may have been important in triggering or modulating the tempo of faunal extinctions and other evolutionary events. In this overview, such processes are examined from the viewpoint of a field volcanologist, rather than as a previous participant in controversies concerning the interrelations between extinctions, impacts, and volcanism.

  1. Characterization and Optimization of Ni-WC Composite Weld Matrix Deposited by Plasma-Transferred Arc Process

    Science.gov (United States)

    Tahaei, Ali; Horley, Paul; Merlin, Mattia; Torres-Torres, David; Garagnani, Gian Luca; Praga, Rolando; Vázquez, Felipe J. García; Arizmendi-Morquecho, Ana

    2017-03-01

    This work is dedicated to optimization of carbide particle system in a weld bead deposited by PTAW technique over D2 tool steel with high chromium content. The paper reports partial melting of the original carbide grains of the Ni-based filling powder, and growing of the secondary carbide phase (Cr, Ni)_3W_3C in the form of dendrites with wide branches that enhanced mechanical properties of the weld. The optimization of bead parameters was made with design of experiment methodology complemented by a complex sample characterization including SEM, EDXS, XRD, and nanoindentation measurements. It was shown that the preheat of the substrate to a moderate temperature 523 K (250° C) establishes linear pattern of metal flow in the weld pool, resulting in the most homogeneous distribution of the primary carbides in the microstructure of weld bead.

  2. Characterization and Optimization of Ni-WC Composite Weld Matrix Deposited by Plasma-Transferred Arc Process

    Science.gov (United States)

    Tahaei, Ali; Horley, Paul; Merlin, Mattia; Torres-Torres, David; Garagnani, Gian Luca; Praga, Rolando; Vázquez, Felipe J. García; Arizmendi-Morquecho, Ana

    2017-01-01

    This work is dedicated to optimization of carbide particle system in a weld bead deposited by PTAW technique over D2 tool steel with high chromium content. The paper reports partial melting of the original carbide grains of the Ni-based filling powder, and growing of the secondary carbide phase (Cr, Ni)_3 W_3 C in the form of dendrites with wide branches that enhanced mechanical properties of the weld. The optimization of bead parameters was made with design of experiment methodology complemented by a complex sample characterization including SEM, EDXS, XRD, and nanoindentation measurements. It was shown that the preheat of the substrate to a moderate temperature 523 K (250° C) establishes linear pattern of metal flow in the weld pool, resulting in the most homogeneous distribution of the primary carbides in the microstructure of weld bead.

  3. Faults and volcanoes: Main volcanic structures in the Acambay Graben, Mexico

    Science.gov (United States)

    Aguirre-Diaz, G. J.; Pedrazzi, D.; Suñe-Puchol, I.; Lacan, P.

    2016-12-01

    The Mexican Volcanic Belt (MVB) province is best known by the major stratovolcanoes, such as Popocatepetl and Colima, but most of the province is formed by modest size stratovolcanoes and monogenetic cones. Regional fault systems were developed together with the building of the volcanic province; the most notorious one is Chapala-Tula Fault System (CTFS), which runs parallel to the central sector of the MVB, and thus it is also referred to as the Intra-Arc fault system. Acambay graben (AG) is part of this central system. It is a 20 x 70 km depression located 100 km to the NW of Mexico City, at the easternmost end of the E-W trending CTFS, and was formed as the result of NS to NE oriented extension. Seismically active normal faults, such as the Acambay-Tixmadejé fault, with a mB =7 earthquake in 1912, delimit the AG. The graben includes several volcanic structures and associated deposits ranging in age from Miocene to 3 ka. The main structures are two stratovolcanoes, Altamirano (900 m high) and Temascalcingo (800 m high). There are also several Miocene-Pliocene lava domes, and Quaternary small cinder cones and shield volcanoes. Faulting of the Acambay graben affects all these volcanic forms, but depending on their ages, the volcanoes are cut by several faults or by a few. That is the case of Altamirano and Temascalcingo volcanoes, where the former is almost unaffected whereas the latter is highly dissected by faults. Altamirano is younger than Temascalcingo; youngest pyroclastic deposits from Altamirano are dated at 12-3 ka, and those from Temascalcingo at 40-25 ka (radiocarbon ages). The relatively young ages found in volcanic deposits within the Acambay graben raise the volcanic danger level in this area, originally marked as an inactive volcanic zone, but activity could restart at any time. Supported by DGAPA-PAPIIT-UNAM grant IN-104615.

  4. Record of Plio-Pleistocene extreme event in the Lesser Antilles fore-arc basin. Example of Grande-Terre (Guadeloupe, French West Indies).

    Science.gov (United States)

    Jeanlèn, L.; Philippon, M. M.; Randrianasolo, A.; Jean-Frederic, L.; Cornée, J. J.; Münch, P.

    2015-12-01

    Guadeloupe archipelago is part of the Lesser Antilles active volcanic arc and is therefore subjected to both enhanced seismic and volcanic activity related to the Lesser Antilles subduction zone, along which the Atlantic plate is subducted westward bellow the Caribbean plate. The volcanic arc is composed of several immerged volcanic islands (St Kitts, Nevis Montserrat, Basse Terre, Dominica, Martinique, St Lucia, Grenada) and submerged volcanoes (Kick em'Jenny). These volcanoes are known to be explosives and when they are entering in an eruptive cycle, debris flow could potentially initiate a tsunami and generate peculiar deposits within the sedimentary record recognized as tsunami deposits (or tsunamite). Subduction- related earthquakes might also initiate slope instabilities and trigger debris flow. Another controlling factor of slope (in-)-stabilities and debris flow is massive rainfalls. During cyclonic season (June to December), massive rainfalls are recorded in the area, which moreover is located on the trajectory of Atlantic Hurricanes that are responsible for numerous landslides. As a consequence, tsunami deposit are described and well studied in the Lesser Antilles arc as the islands shoreline and coastal plain are perpetually re-shaped by hurricanes responsible for tempestite deposits. However, the report of these deposit concern recent to actual events, for example present-day deposits consisting of large (metric) boulders, more or less aligned, located in the supralittoral fringe can be observed along Guadeloupe shore. In this study, we investigate the Plio-pleistocene sedimentary sequence of Grande Terre carbonate platform (Guadeloupe), and track the presence of such extreme-event related deposits and discuss our findings in the frame of the Lesser Antilles geological context.

  5. Comparative study of the structure and corrosion behavior of Zr-20%Cr and Zr-20%Ti alloy films deposited by multi-arc ion plating technique

    Energy Technology Data Exchange (ETDEWEB)

    Ali, Farhat, E-mail: ilatahraf@yahoo.com [National Centre for Nanotechnology, Department of Metallurgy and Materials Engineering (DMME), Pakistan Institute of Engineering and Applied Sciences (PIEAS), PO Nilore, Islamabad 45650 (Pakistan); Mehmood, Mazhar, E-mail: mazhar@pieas.edu.pk [National Centre for Nanotechnology, Department of Metallurgy and Materials Engineering (DMME), Pakistan Institute of Engineering and Applied Sciences (PIEAS), PO Nilore, Islamabad 45650 (Pakistan); Qasim, Abdul Mateen; Ahmad, Jamil; Naeem-ur-Rehman [National Centre for Nanotechnology, Department of Metallurgy and Materials Engineering (DMME), Pakistan Institute of Engineering and Applied Sciences (PIEAS), PO Nilore, Islamabad 45650 (Pakistan); Iqbal, Muhammad [Physics Division, Pakistan Institute of Science and Technology (PINSTECH), Islamabad 45650 (Pakistan); Qureshi, Ammad H. [Materials Division, Pakistan Institute of Science and Technology (PINSTECH), Islamabad 45650 (Pakistan)

    2014-08-01

    The primary focus of the present work was to perform comparative study of the structure as well as corrosion behavior of two Zr-rich alloy films, i.e. Zr-20%Cr and Zr-20%Ti, as well as metallic Ti, Cr and Zr films, formed by multi-arc ion plating technique. The required alloy film composition was obtained by co-deposition with proper choice of current for the targets of the constituent metals. The deposited alloy film composition was determined by energy dispersion X-ray spectroscopy, X-ray fluorescence and inductively coupled plasma-atomic emission spectroscopy (ICP-AES) techniques, which were in close agreement with each other. The film thickness lied in the range of 550-620 nm. The crystal structure was studied by X-ray diffraction, which revealed the formation of nanocrystalline and semi-amorphous structures. The corrosion rates of the films were determined through weight loss measurement in 1 M, 6 M and 12 M hydrochloric acid (HCl) by ICP-AES analysis of the solution after immersion for 200-350 h. Anodic (potentiodynamic) polarization was also performed. Zr-20%Cr alloy film exhibited the best corrosion resistance, and its dissolution rate was less than 0.5 μm/year in 6 M HCl and about 4 μm/year in 12 M HCl. - Highlights: • Fine control over the stoichiometry of each alloy film • Development of either nano-crystalline or semi-amorphous alloy films • Development of highly corrosion resistant films.

  6. Caribbean island-arc rifting and back-arc basin development in the Late Cretaceous: Geochemical, isotopic and geochronological evidence from Central Hispaniola

    Science.gov (United States)

    Escuder Viruete, J.; Joubert, M.; Urien, P.; Friedman, R.; Weis, D.; Ullrich, T.; Pérez-Estaún, A.

    2008-08-01

    We present new regional petrologic, geochemical, Sr-Nd isotopic, and U-Pb geochronological data on the Turonian-Campanian mafic igneous rocks of Central Hispaniola that provide important clues on the development of the Caribbean island-arc. Central Hispaniola is made up of three main tectonic blocks—Jicomé, Jarabacoa and Bonao—that include four broad geochemical groups of Late Cretaceous mafic igneous rocks: group I, tholeiitic to calc-alkaline basalts and andesites; group II, low-Ti high-Mg andesites and basalts; group III, tholeiitic basalts and gabbros/dolerites; and group IV, tholeiitic to transitional and alkalic basalts. These igneous rocks show significant differences in time and space, from arc-like to non-arc-like characteristics, suggesting that they were derived from different mantle sources. We interpret these groups as the record of Caribbean arc-rifting and back-arc basin development in the Late Cretaceous. The> 90 Ma group I volcanic rocks and associated cumulate complexes preserved in the Jicomé and Jarabacoa blocks represent the Albian to Cenomanian Caribbean island-arc material. The arc rift stage magmatism in these blocks took place during the deposition of the Restauración Formation from the Turonian-Coniacian transition (~ 90 Ma) to Santonian/Lower Campanian, particularly in its lower part with extrusion at 90-88 Ma of group II low-Ti, high-Mg andesites/basalts. During this time or slightly afterwards adakitic rhyolites erupted in the Jarabacoa block. Group III tholeiitic lavas represent the initiation of Coniacian-Lower Campanian back-arc spreading. In the Bonao block, this stage is represented by back-arc basin-like basalts, gabbros and dolerite/diorite dykes intruded into the Loma Caribe peridotite, as well as the Peralvillo Sur Formation basalts, capped by tuffs, shales and Campanian cherts. This dismembered ophiolitic stratigraphy indicates that the Bonao block is a fragment of an ensimatic back-arc basin. In the Jicomé and

  7. Phase transitions of doped carbon in CrCN coatings with modified mechanical and tribological properties via filtered cathodic vacuum arc deposition

    Science.gov (United States)

    Guan, J. J.; Wang, H. Q.; Qin, L. Z.; Liao, B.; Liang, H.; Li, B.

    2017-04-01

    The CrCN coatings were fabricated onto Si (1 1 1) wafers and SUS304 stainless steel plates using filtered cathodic vacuum arc deposition (FCVAD) technique under different flow ratios of N2/C2H2 gas mixture. The morphology, crystalline structure and chemical composition of the coatings were characterized. It was found that the grain size reduce with increasing carbon content, which makes the CrCN coatings refined and smooth. The quasi-one-dimensional carbolite phase was also found in CrN host lattice with C2H2 content ranging from 5% to 20%, and it will be evolved into amorphous carbon and amorphous CNx phases as C2H2 content exceeds 20%. Moreover, we examined the mechanical and tribological properties of the CrCN coatings, and the experimental results confirmed that the friction coefficient of the coatings descend to the lowest value as 0.39 with 30% C2H2 content, due to the graphite (sp2 Csbnd C) phase embed in CrN host lattice; while the chromium carbon (Cr3C2) and diamond (sp3 Csbnd C) phases may give rise to the increase of the coating hardness with the highest value at 23.97 GPa under 20% C2H2 content.

  8. Effects of Y2O3 on the microstructure and wear resistance of cobalt-based alloy coatings deposited by plasma transferred arc process

    Institute of Scientific and Technical Information of China (English)

    HOU Qingyu; HUANG Zhenyi; GAO Jiasheng

    2007-01-01

    Cobalt-based alloys with different Y2O3 contents were deposited on Q235A-carbon steel using plasma transferred arc (PTA) welding machine. The effect of Y2O3 on the microstructure and wear resistance properties of the cobalt-based alloys were investigated using an optical microscope, a scanning electron microscope (SEM), X-ray diffraction (XRD), and transmission electron microscopy (TEM). It was found that a cobalt-based solid solution with a face-centered cubic crystal structure was presented accompanied by the secondary phase M7C3 with a hexagonal crystal structure in the Y2O3-free cobalt-based alloy coating. Several stacking faults exist in the cobalt-based solid solution. The addition of Y2O3leads to the existence of the Y2O3 phase in the Y2O3-modified coatings. Though stacking fault exists in the Y2O3-modified coatings, its density increases. The addition of Y2O3 can refine the microstructure and can increase the wear resistance properties when its contents are less than or equal to 0.8 wt.%. However, further increase of its contents will lead to the agglomeration of undissolved Y2O3 particles at the γ-Co grain boundary, and will lead to a coarse microstructure and lower wear resistance properties.

  9. Effect of Silane Flow Rate on Structure and Corrosion Resistance of Ti-Si-N Thin Films Deposited by a Hybrid Cathodic Arc and Chemical Vapour Process

    Institute of Scientific and Technical Information of China (English)

    YIN Long-Cheng; LUAN Sen; LV Guo-Hua; WANG Xing-Quan; HUANG Jun; JIN Hui; FENG Ke-Cheng; YANG Si-Ze

    2008-01-01

    Ti-Si-N thin films with different silicon contents are deposited by a cathodic arc technique in an Ar+N2+SiH4mixture atmosphere. With the increase of silane flow rate, the content of silicon in the Ti-Si-N films varies from2.0 at. % to 12.2 at.%. Meanwhile, the cross-sectional morphology of these films changes from an apparent columnar microstructure to a dense fine-grained structure. The x-ray diffractometer (XRD) and x-ray photoelectron spectroscopy (XPS) results show that the Ti-Si-N film consists of TiN crystallites and SiNx amorphous phase.The corrosion resistance is improved with the increase of silane flow rate. Growth defects in the films produced play a key role in the corrosion process, especially for the local corrosion. The porosity of the films decreases from 0.13% to 0.00032% by introducing silane at the flow rate of 14 sccm.

  10. Oligocene-to-Early Miocene depositional and structural evolution of the Calabria-Peloritani Arc southern terrane (Italy) and geodynamic correlations with the Spain Betics and Morocco Rif

    Science.gov (United States)

    Bonardi, Glauco; de Capoa, Paola; Di Staso, Angelida; Estévez, Antonio; Martín-Martín, Manuél; Martín-Rojas, Iván; Perrone, Vincenzo; Tent-Manclús, José Enrique

    2003-11-01

    The Calabria-Peloritani Arc southern terrane is a stack of crystalline basement nappes, some of them provided with a widely outcropping Alpine sedimentary cover, sealed by clastics of the Stilo-Capo d'Orlando Formation (SCOF). New field observations in the Stilo area lead to define a Pignolo Formation as a sedimentary cycle predating the emplacement of the uppermost nappe (Stilo Unit) of the tectonic pile. It includes the well-known Lithothamnium and larger foraminifers bearing calcarenites, previously interpreted as a basal member of the SCOF. The biostratigraphic revision of both formations, together with recently published data about other preorogenic deposits, point to a stacking of the whole terrane between the Aquitanian and the middle-late Burdigalian. A comparison between the sedimentary cycles characterising the Calabria-Peloritani southern terrane during the Oligocene-Early Miocene and those almost coeval of the Betic-Rifian internal units highlights their quite similar evolution. Thus it is reliable that both the orogenic belts originated from contiguous paleogeographic realms. These considerations confirm that the present western Mediterranean Chains were originally segments of a continuous orogenic belt disrupted by the opening of the Balearic and Tyrrhenian basins.

  11. Abundances of platinum group elements in native sulfur condensates from the Niuatahi-Motutahi submarine volcano, Tonga rear arc: Implications for PGE mineralization in porphyry deposits

    Science.gov (United States)

    Park, Jung-Woo; Campbell, Ian H.; Kim, Jonguk

    2016-02-01

    Some porphyry Cu-Au deposits, which are enriched in Pd, are potentially an economic source of Pd. Magmatic volatile phases are thought to transport the platinum group elements (PGEs) from the porphyry source magma to the point of deposition. However, the compatibilities of the PGEs in magmatic volatile phases are poorly constrained. We report PGE and Re contents in native sulfur condensates and associated altered dacites from the Niuatahi-Motutahi submarine volcano, Tonga rear arc, in order to determine the compatibility of PGEs and Re in magmatic volatile phases, and their mobility during secondary hydrothermal alteration. The native sulfur we analyzed is the condensate of a magmatic volatile phase exsolved from the Niuatahi-Motutahi magma. The PGEs are moderately enriched in the sulfur condensates in comparison to the associated fresh dacite, with enrichment factors of 11-285, whereas Au, Cu and Re are strongly enriched with enrichment factors of ∼20,000, ∼5000 and ∼800 respectively. Although the PGEs are moderately compatible into magmatic volatile phases, their compatibility is significantly lower than that of Au, Cu and Re. Furthermore, the compatibility of PGEs decrease in the order: Ru > Pt > Ir > Pd. This trend is also observed in condensates and sublimates from other localities. PGE mineralization in porphyry Cu-Au deposits is characterized by substantially higher Pd/Pt (∼7-60) and Pd/Ir (∼100-10,500) than typical orthomagmatic sulfide deposits (e.g. Pd/Pt ∼0.6 and Pd/Ir ∼20 for the Bushveld). It has previously been suggested that the high mobility of Pd, relative to the other PGEs, may account for the preferential enrichment of Pd in porphyry Cu-Au deposits. However, the low compatibility of Pd in the volatile phase relative to the other PGEs, shown in this study, invalidates this explanation. We suggest that the PGE geochemistry of Pd-rich Cu-Au deposits is principally derived from the PGE characteristics of the magma from which the ore

  12. Upper Paleozoic mafic and intermediate volcanic rocks of the Mount Pleasant caldera associated with the Sn-W deposit in southwestern New Brunswick (Canada): Petrogenesis and metallogenic implications

    Science.gov (United States)

    Dostal, Jaroslav; Jutras, Pierre

    2016-10-01

    Upper Paleozoic ( 365 Ma) mafic and intermediate volcanic rocks of the Piskahegan Group constitute a subordinate part of the Mount Pleasant caldera, which is associated with a significant polymetallic deposit (tungsten-molybdenum-bismuth zones 33 Mt ore with 0.21% W, 0.1% Mo and 0.08% Bi and tin-indium zones 4.8 Mt with 0.82% Sn and 129 g/t In) in southwestern New Brunswick (Canada). The epicontinental caldera complex formed during the opening of the late Paleozoic Maritimes Basin in the northern Appalachians. The mafic and intermediate rocks make up two compositionally distinct associations. The first association includes evolved rift-related continental tholeiitic basalts, and the second association comprises calc-alkaline andesites, although both associations were emplaced penecontemporaneously. The basalts have low Mg# 0.34-0.40, smooth chondrite-normalized REE patterns with (La/Yb)n 5-6, primitive mantle-normalized trace element patterns without noticeable negative Nb-Ta anomalies, and their ɛNd(T) ranges from + 2.5 to + 2.2. The basalts were generated by partial melting of a transition zone between spinel and garnet mantle peridotite at a depth of 70-90 km. The calc-alkaline andesites of the second association have chondrite-normalized REE patterns that are more fractionated, with (La/Yb)n 7-8.5, but without significant negative Eu anomalies. Compared to the basaltic rocks, they have lower ɛNd(T) values, ranging from + 0.5 to + 1.9, and their mantle-normalized trace element plots show negative Nb-Ta anomalies. The ɛNd(T) values display negative correlations with indicators of crustal contamination, such as Th/La, Th/Nb and SiO2. The andesitic rocks are interpreted to have formed by assimilation-fractional crystallization processes, which resulted in the contamination of a precursor basaltic magma with crustal material. The parent basaltic magma for both suites underwent a different evolution. The tholeiitic basalts experienced shallow-seated fractional

  13. Tectonic geomorphology of the Ryukyu Trench-Arc-Backarc System:geological-geophysical exploration and mapping

    Institute of Scientific and Technical Information of China (English)

    FU Mingzuo; LIU Lejun; ZHENG Yanpeng; LIU Baohua; WU Jinlong; XU Xiaowei

    2004-01-01

    Based on an analysis of full-cover multi-beam bathymetric data, seismic and sub-bottom profiling data, and other geological-geophysical data sets, the geomorphologic features of the Ryukyu trench-arc-backarc (T-A-BA) system are delineated, and a geomorphologic map of the system is compiled. The results show that the evolution and spatial distribution patterns of the geomorphologic types of the Ryukyu T-A-BA system are controlled mainly by tectonic movements. The tectonic geomorphologic characteristics of the Ryukyu Arc (RA) differ distinctly from those of the East China Sea (ECS) continental shelf and slope. In term of geological structures, RA consists of the Tokara volcanic ridge,the Ryukyu folded ridge, the fore-arc accretion-wedge ridge and the Amami Depression and the fore-arc depressions between the ridges, which is composed of a complex of alternating island-slope ridges and fault basins. The slope of the ECS is a passive continental margin with stepwise faults. The Okinawa Trough (OT) is a backarc rift in which tectonic movements are intensive, with active volcanic and hydrothermal eruptions and sea floor spreading. The development of geomorphic features of the OT is controlled by the central en echelon spreading axes, the faults along the ECS slope and the marginal faults to the west of the Tokara volcanic ridge.The geomorphic complex of the OT is arranged in the following pattern: the en echelon grabens and volcanic chains formed by rifting and spreading lie in the central part of the trough, the turbidite plains inclining eastwards-southeastwards from the slope foot of the ECS lie in the western-northwestern parts of the OT, and the volcaniclastic deposit plains inclining westward-northwestwards from the western slope foot of the RA lie in the eastern-southeastern parts of the OT. In term of tectonic geomorphology, the OT forms a natural division between the shelf of the ECS and the RA.

  14. Facies And Bedding Analysis of Deep-Marine, Arc-Related, Sediementary Rocks Cored on International Ocean Drilling Program Expedition 351.

    Science.gov (United States)

    Johnson, K. E.; Marsaglia, K. M.

    2015-12-01

    The Izu-Bonin-Mariana (IBM) Arc System, south of Japan, hosts a multitude of active and extinct (remnant) arc volcanic sediment sources. Core extracted adjacent to the proto-IBM arc (Kyushu-Palau Ridge; KPR) in the Amami-Sankaku Basin on International Ocean Discovery Program (IODP) Expedition 351 contains evidence of the variety of sediment sources that have existed in the area as a result of changing tectonic regimes through arc development, backarc basin formation and remnant arc abandonment. Approximately 1000 meters of Eocene to Oligocene volcaniclastic sedimentary rocks were analyzed via shipboard core photos, core descriptions, and thin sections with the intention of understanding the depositional history at this site. These materials contain a crucial record of arc development complementary to the Neogene history preserved in the active reararc (Expedition 350) and compressed whole-arc record in the current forearc (Expedition 352). A database of stratigraphic columns was created to display grain size trends, facies changes, and bedding characteristics. Individual beds (depositional events) were classified using existing and slightly modified classification schemes for muddy, sandy and gravel-rich gravity flow deposits, as well as muddy debris flows and tuffs. Utilizing the deep marine facies classes presented by Pickering et al. (1986), up section changes are apparent. Through time, as the arc developed, facies and bedding types and their proportions change dramatically and relatively abruptly. Following arc initiation facies are primarily mud-rich with intercalated tuffaceous sand. In younger intervals, sand to gravel gravity-flow deposits dominate, becoming more mud-rich. Muddy gravity flow deposits, however, dominate farther upsection. The overall coarsening-upward pattern (Unit III) is consistent with building of the arc edifice. Farther upsection (Unit II) an abrupt fining-upward trend represents the onset of isolation of the KPR as backarc spreading

  15. Deposit model for volcanogenic uranium deposits

    Science.gov (United States)

    Breit, George N.; Hall, Susan M.

    2011-01-01

    Volcanism is a major contributor to the formation of important uranium deposits both close to centers of eruption and more distal as a result of deposition of ash with leachable uranium. Hydrothermal fluids that are driven by magmatic heat proximal to some volcanic centers directly form some deposits. These fluids leach uranium from U-bearing silicic volcanic rocks and concentrate it at sites of deposition within veins, stockworks, breccias, volcaniclastic rocks, and lacustrine caldera sediments. The volcanogenic uranium deposit model presented here summarizes attributes of those deposits and follows the focus of the International Atomic Energy Agency caldera-hosted uranium deposit model. Although inferred by some to have a volcanic component to their origin, iron oxide-copper-gold deposits with economically recoverable uranium contents are not considered in this model.

  16. Late Cenozoic volcanism in the western Woodlark Basin area, SW Pacific: the sources of marine volcanic ash layers based on their elemental and Sr-Nd isotope compositions

    Science.gov (United States)

    Lackschewitz, K. S.; Mertz, D. F.; Devey, C. W.; Garbe-Schönberg, C.-D.

    2002-12-01

    Tephra fallout layers and volcaniclastic deposits, derived from volcanic sources around and on the Papuan Peninsula, form a substantial part of the Woodlark Basin marine sedimentary succession. Sampling by the Ocean Drilling Program Leg 180 in the western Woodlark Basin provides the opportunity to document the distribution of the volcanically-derived components as well as to evaluate their chronology, chemistry, and isotope compositions in order to gain information on the volcanic sources and original magmatic systems. Glass shards selected from 57 volcanogenic layers within the sampled Pliocene-Pleistocene sedimentary sequence show predominantly rhyolitic compositions, with subordinate basaltic andesites, basaltic trachy-andesites, andesites, trachy-andesites, dacites, and phonolites. It was possible to correlate only a few of the volcanogenic layers between sites using geochemical and age information apparently because of the formation of strongly compartmentalised sedimentary realms on this actively rifting margin. In many cases it was possible to correlate Leg 180 volcanic components with their eruption source areas based on chemical and isotope compositions. Likely sources for a considerable number of the volcanogenic deposits are Moresby and Dawson Strait volcanoes (D'Entrecasteaux Islands region) for high-K calc-alkaline glasses. The Dawson Strait volcanoes appear to represent the source for five peralkaline tephra layers. One basaltic andesitic volcaniclastic layer shows affinities to basaltic andesites from the Woodlark spreading tip and Cheshire Seamount. For other layers, a clear identification of the sources proved impossible, although their isotope and chemical signatures suggest similarities to south-west Pacific subduction volcanism, e.g. New Britain and Tonga-Kermadec island arcs. Volcanic islands in the Trobriand Arc (for example, Woodlark Island Amphlett Islands and/or Egum Atoll) are probable sources for several volcaniclastic layers with ages

  17. Characterization of