Oxygenated gasoline release in the unsaturated zone - Part 1: Source zone behavior.

Science.gov (United States)

Freitas, Juliana G; Barker, James F

2011-11-01

Oxygenates present in gasoline, such as ethanol and MTBE, are a concern in subsurface contamination related to accidental spills. While gasoline hydrocarbon compounds have low solubility, MTBE and ethanol are more soluble, ethanol being completely miscible with water. Consequently, their fate in the subsurface is likely to differ from that of gasoline. To evaluate the fate of gasoline containing oxygenates following a release in the unsaturated zone shielded from rainfall/recharge, a controlled field test was performed at Canadian Forces Base Borden, in Ontario. 200L of a mixture composed of gasoline with 10% ethanol and 4.5% MTBE was released in the unsaturated zone, into a trench 20cm deep, about 32cm above the water table. Based on soil cores, most of the ethanol was retained in the source, above the capillary fringe, and remained there for more than 100 days. Ethanol partitioned from the gasoline to the unsaturated pore-water and was retained, despite the thin unsaturated zone at the site (~35cm from the top of the capillary fringe to ground surface). Due to its lower solubility, most of the MTBE remained within the NAPL as it infiltrated deeper into the unsaturated zone and accumulated with the gasoline on top of the depressed capillary fringe. Only minor changes in the distribution of ethanol were noted following oscillations in the water table. Two methods to estimate the capacity of the unsaturated zone to retain ethanol are explored. It is clear that conceptual models for sites impacted by ethanol-fuels must consider the unsaturated zone. Copyright © 2011 Elsevier B.V. All rights reserved.

VOC species and emission inventory from vehicles and their SOA formation potentials estimation in Shanghai, China

OpenAIRE

C. Huang; H. L. Wang; L. Li; Q. Wang; Q. Lu; J. A. de Gouw; M. Zhou; S. A. Jing; J. Lu; C. H. Chen

2015-01-01

VOC species from vehicle exhaust and gas evaporation were investigated by chassis dynamometer and on-road measurements of 9 gasoline vehicles, 7 diesel vehicles, 5 motorcycles, and 4 gas evaporation samples. The SOA mass yields of gasoline, diesel, motorcycle exhausts, and gas evaporation were calculated based on the mixing ratio of individual VOC species. The SOA mass yields of gasoline and motorcycle exhaust were similar to the results of the published smo...

Comparison of the performance of a spark-ignited gasoline engine blended with hydrogen and hydrogen-oxygen mixtures

International Nuclear Information System (INIS)

Wang, Shuofeng; Ji, Changwei; Zhang, Jian; Zhang, Bo

2011-01-01

This paper compared the effects of hydrogen and hydrogen-oxygen blends (hydroxygen) additions on the performance of a gasoline engine at 1400 rpm and a manifolds absolute pressure of 61.5 kPa. The tests were carried out on a 1.6 L gasoline engine equipped with a hydrogen and oxygen injection system. A hybrid electronic control unit was applied to adjust the hydrogen and hydroxygen volume fractions in the intake increasing from 0% to about 3% and keep the hydrogen-to-oxygen mole ratio at 2:1 in hydroxygen tests. For each testing condition, the gasoline flow rate was adjusted to maintain the mixture global excess air ratio at 1.00. The test results confirmed that engine fuel energy flow rate was decreased after hydrogen addition but increased with hydroxygen blending. When hydrogen or hydroxygen volume fraction in the intake was lower than 2%, the hydroxygen-blended gasoline engine produced a higher thermal efficiency than the hydrogen-blended gasoline engine. Both the additions of hydrogen and hydroxygen help reduce flame development and propagation periods of the gasoline engine. HC emissions were reduced whereas NOx emissions were raised with the increase of hydrogen and hydroxygen addition levels. CO was slightly increased after hydrogen blending, but reduced with hydroxygen addition. -- Highlights: → We compared the effects of hydrogen and hydroxygen additions on the gasoline engine performance. → The hydroxygen should be added into the engine only at low blending levels. → CO is decreased with hydroxygen addition whereas increased with hydrogen blending.

Autoignition characteristics of oxygenated gasolines

KAUST Repository

Lee, Changyoul; Ahmed, Ahfaz; Nasir, Ehson Fawad; Badra, Jihad; Kalghatgi, Gautam; Sarathy, Mani; Curran, Henry; Farooq, Aamir

2017-01-01

Gasoline anti-knock quality, defined by the research and motor octane numbers (RON and MON), is important for increasing spark ignition (SI) engine efficiency. Gasoline knock resistance can be increased using a number of blending components

Limited recovery of soil microbial activity after transient exposure to gasoline vapors

DEFF Research Database (Denmark)

Modrzyński, Jakub J.; Christensen, Jan H.; Mayer, Philipp

2016-01-01

During gasoline spills complex mixtures of toxic volatile organic compounds (VOCs) are released to terrestrial environments. Gasoline VOCs exert baseline toxicity (narcosis) and may thus broadly affect soil biota. We assessed the functional resilience (i.e. resistance and recovery of microbial...... functions) in soil microbial communities transiently exposed to gasoline vapors by passive dosing via headspace for 40 days followed by a recovery phase of 84 days. Chemical exposure was characterized with GC-MS, whereas microbial activity was monitored as soil respiration (CO2 release) and soil bacterial...... microbial activity indicating residual soil toxicity, which could not be attributed to BTEX, but rather to mixture toxicity of more persistent gasoline constituents or degradation products. Our results indicate a limited potential for functional recovery of soil microbial communities after transient...

Health assessment of gasoline and fuel oxygenate vapors: immunotoxicity evaluation.

Science.gov (United States)

White, Kimber L; Peachee, Vanessa L; Armstrong, Sarah R; Twerdok, Lorraine E; Clark, Charles R; Schreiner, Ceinwen A

2014-11-01

Female Sprague Dawley rats were exposed via inhalation to vapor condensates of either gasoline or gasoline combined with various fuel oxygenates to assess potential immunotoxicity of evaporative emissions. Test articles included vapor condensates prepared from "baseline gasoline" (BGVC), or gasoline combined with methyl tertiary butyl ether (G/MTBE), ethyl t-butyl ether (G/ETBE), t-amyl methyl ether (G/TAME), diisopropyl ether (G/DIPE), ethanol (G/EtOH), or t-butyl alcohol (G/TBA). Target concentrations were 0, 2000, 10,000 or 20,000mg/mg(3) administered for 6h/day, 5days/week for 4weeks. The antibody-forming cell (AFC) response to the T-dependent antigen, sheep erythrocyte (sRBC), was used to determine the effects of the gasoline vapor condensates on the humoral components of the immune system. Exposure to BGVC, G/MTBE, G/TAME, and G/TBA did not result in significant changes in the IgM AFC response to sRBC, when evaluated as either specific activity (AFC/10(6) spleen cells) or as total spleen activity (AFC/spleen). Exposure to G/EtOH and G/DIPE resulted in a dose-dependent decrease in the AFC response, reaching the level of statistical significance only at the high 20,000mg/m(3) level. Exposure to G/ETBE resulted in a statistically significant decrease in the AFC response at the middle (10,000mg/m(3)) and high (20,000mg/m(3)) exposure concentrations. Copyright © 2014 Elsevier Inc. All rights reserved.

Air emissions scenarios from ethanol as a gasoline oxygenate in Mexico City Metropolitan Area

Energy Technology Data Exchange (ETDEWEB)

Garcia, Carlos A. [Posgrado en Ingenieria Energetica, Universidad Nacional Autonoma de Mexico, Priv. Xochicalco s/n, Col. Centro, Apartado Postal 34, 62580 Temixco, Morelos (Mexico); Manzini, Fabio; Islas, Jorge [Centro de Investigacion en Energia, Universidad Nacional Autonoma de Mexico, Priv. Xochicalco s/n, Col. Centro, Apartado Postal 34, 62580 Temixco, Morelos (Mexico)

2010-12-15

The Mexican Biofuel Introduction Program states that during year 2010 the three biggest Mexican cities will have a gasoline blending with 6% ethanol available for all gasoline on-road vehicle fleet. Also in 2010 Mexican government has programmed to start the substitution of Tier 1 - the adopted US emission standards - by Tier 2, which are more stringent emission standards for motor vehicles and gasoline sulfur control requirements. How will the air emissions in the Mexico City Metropolitan Area (MCMA) be modified by using this blending? Four scenarios up to year 2030 were constructed and simulated using the Long-Range Energy Alternatives Planning model. Beginning with a BAU or reference scenario, in this scenario the current available fuel is a blending composed by 5% methyl tertiary butyl ether and 95% gasoline (MTBE5). Then, three alternative scenarios that use ethanol as an oxygenate are considered, one with the already programmed E6 blending (6% anhydride ethanol, 94% gasoline), for the sake of comparison the E10 blending (10% anhydride ethanol, 90% gasoline), and the other alternative to compare, ETBE13.7 (13.7% ethyl tertiary butyl ether, 86.3% gasoline; where ETBE is an ether composed by 48% anhydride ethanol and 52% isobutene). Emissions of carbon dioxide (CO{sub 2}), carbon monoxide (CO), nitrogen oxides (NOx), particulate matter (PM10), sulfur dioxide (SO{sub 2}), total hydrocarbons (THC), benzene, formaldehyde, acetaldehyde and 1,3-butadiene were calculated using emission factors previously calculated using the adapted US-EPA computer model called MOBILE6-Mexico. Results show that Tier 1 and Tier 2 standards effectively lowers all emissions in all studied scenarios with the exception of PM10 and CO{sub 2} emissions. The alternative scenario E10 has the most total avoided emissions by weight but it is not the best when considering some individual pollutants. The greatest environmental benefit of ethanol in its final use as a gasoline oxygenate is for

Health assessment of gasoline and fuel oxygenate vapors: neurotoxicity evaluation.

Science.gov (United States)

O'Callaghan, James P; Daughtrey, Wayne C; Clark, Charles R; Schreiner, Ceinwen A; White, Russell

2014-11-01

Sprague-Dawley rats were exposed via inhalation to vapor condensates of either gasoline or gasoline combined with various fuel oxygenates to assess potential neurotoxicity of evaporative emissions. Test articles included vapor condensates prepared from "baseline gasoline" (BGVC), or gasoline combined with methyl tertiary butyl ether (G/MTBE), ethyl t-butyl ether (G/ETBE), t-amyl methyl ether (G/TAME), diisopropyl ether (G/DIPE), ethanol (G/EtOH), or t-butyl alcohol (G/TBA). Target concentrations were 0, 2000, 10,000 or 20,000mg/mg(3) and exposures were for 6h/day, 5days/week for 13weeks. The functional observation battery (FOB) with the addition of motor activity (MA) testing, hematoxylin and eosin staining of brain tissue sections, and brain regional analysis of glial fibrillary acidic protein (GFAP) were used to assess behavioral changes, traditional neuropathology and astrogliosis, respectively. FOB and MA data for all agents, except G/TBA, were negative. G/TBA behavioral effects resolved during recovery. Neuropathology was negative for all groups. Analyses of GFAP revealed increases in multiplebrain regions largely limited to males of the G/EtOH group, findings indicative of minor gliosis, most significantly in the cerebellum. Small changes (both increases and decreases) in GFAP were observed for other test agents but effects were not consistent across sex, brain region or exposure concentration. Copyright © 2014 Elsevier Inc. All rights reserved.

Oxygen sensor equipped engine operation on methanol/gasoline blends and phase separation problems

Energy Technology Data Exchange (ETDEWEB)

Last, A J; Lawson, A; Simmons, E W; Mackay, D; Tsang, M; Maund, G B

1980-01-01

A study was made to address problems related to Canadian utilization of methanol/gasoline blends. These problems are: (1) cold weather operation; (2) water sensitivity to phase separation in winter; (3) vehicle compatibility: fuel/air ratio control, flexibility for vehicle movement outside of areas where methanol might be available. Specifically, the operation of the HydroShear (an in-line hydraulic emulsifier) on the two separated phases of a methanol/gasoline/water blend was examined. Fuel maps, by engine dynamometer testing, were generated using methanol/gasoline blends containing 15% to 65% methanol. The capability of an oxygen sensor, located in the exhaust system, to control the fuel/air ratio was found to be adequate within the 15% to 65% methanol/gasoline blends. A fuel injected Volvo 244DL with lambda-sond emission control and a carburetted Chevrolet Monza with 3-way catalyst closed loop feedback emission control system were the two engines selected for this study.

Exhaust and evaporative emissions from motorcycles fueled with ethanol gasoline blends.

Science.gov (United States)

Li, Lan; Ge, Yunshan; Wang, Mingda; Peng, Zihang; Song, Yanan; Zhang, Liwei; Yuan, Wanli

2015-01-01

The emission characteristics of motorcycles using gasoline and E10 (90% gasoline and 10% ethanol by volume) were investigated in this article. Exhaust and evaporative emissions of three motorcycles were investigated on the chassis dynamometer over the Urban Driving Cycle (UDC) and in the Sealed Housing for Evaporative Determination (SHED) including regulated and unregulated emissions. The regulated emissions were detected by an exhaust gas analyzer directly. The unregulated emissions including carbonyls and volatile organic compounds (VOCs) were sampled through battery-operated air pumps using tubes coated with 2,4-dinitrophenylhydrazine (DNPH) and Tenax TA, respectively. The experimental results showed that the emission factors of total hydrocarbons (THC) and carbon monoxide (CO) from E10 fueling motorcycles decreased by 26%-45% and 63%-73%, while the emission factor of NOx increased by 36%-54% compared with those from gasoline fueling motorcycles. For unregulated emissions, the emission amount of VOCs from motorcycles fueled with E10 decreased by 18%-31% while total carbonyls were 2.6-4.5 times higher than those for gasoline. For evaporative emissions of THC and VOCs, for gasoline or E10, the diurnal breathing loss (DBL) was higher than hot soak loss (HSL). Using E10 as a fuel does not make much difference in the amount of evaporative THC, while resulted in a slightly growth of 14%-17% for evaporative BETX (benzene, toluene, ethylbenzene, xylene). Copyright © 2014 Elsevier B.V. All rights reserved.

Volatile organic compounds in a residential and commercial urban area with a diesel, compressed natural gas and oxygenated gasoline vehicular fleet.

Science.gov (United States)

Martins, Eduardo Monteiro; Arbilla, Graciela; Gatti, Luciana Vanni

2010-02-01

Air samples were collected in a typical residential and commercial area in Rio de Janeiro, Brazil, where buses and trucks use diesel and light duty vehicles use compressed natural gas, ethanol, and gasohol (gasoline blended with ethanol) as fuel. A total of 66 C3-C12 volatile organic compounds (VOCs) were identified. The most abundant compounds, on a mass concentration basis, included propane, isobutane, i-pentane, m,p-xylene, 1,3,5-trimethylbenzene, toluene, styrene, ethylbenzene, isopropylbenzene, o-xylene and 1,2,4-trimethylbenzene. Two VOCs photochemical reactivity rankings are presented: one involves reaction with OH and the other involves production of ozone.

[Study on three kinds of gasoline oxygenates-induced DNA damage in mice fibroblasts].

Science.gov (United States)

Song, Chonglin; Zhang, Zhifu; Chen, Xue; Zhang, Yanfeng; Wang, Chunhua; Liu, Keming

2002-10-01

To study DNA damage of three kinds of gasoline oxygenates. Single cell gel electrophoresis assay(Comet assay) was used to detect the damage effects of three gasoline oxygenates[methyl tertiary butyl ether(MTBE), ethanol anhydrous(EA) and dimethyl carbonate(DMC)] on DNA in L-929 mice fibroblasts. In certain concentation(37.500-150.000 mg/ml), MTBE could directly cause DNA damage of L-929 mice fibroblasts. There was obvious dose-effect relationship, i.e. when the concentration of MTBE was increased from 9.375 to 150.000 mg/ml, the comet rate also increased from 4% to 85%, and the length of comet tail changed correspondingly. The results of EA and DMC were negative. Under the condition of this experiment(150.000 mg/ml), MTBE could directly cause DNA damage while the effect of EA and DMC on DNA damage was not found.

Health assessment of gasoline and fuel oxygenate vapors: micronucleus and sister chromatid exchange evaluations.

Science.gov (United States)

Schreiner, Ceinwen A; Hoffman, Gary M; Gudi, Ramadevi; Clark, Charles R

2014-11-01

Micronucleus and sister chromatid exchange (SCE) tests were performed for vapor condensate of baseline gasoline (BGVC), or gasoline with oxygenates, methyl tert-butyl ether (G/MTBE), ethyl tert butyl ether (G/ETBE), t-amyl methyl ether (G/TAME), diisopropyl ether (G/DIPE), t-butyl alcohol (TBA), or ethanol (G/EtOH). Sprague Dawley rats (the same 5/sex/group for both endpoints) were exposed to 0, 2000, 10,000, or 20,000mg/m(3) of each condensate, 6h/day, 5days/week over 4weeks. Positive controls (5/sex/test) were given cyclophosphamide IP, 24h prior to sacrifice at 5mg/kg (SCE test) and 40mg/kg (micronucleus test). Blood was collected from the abdominal aorta for the SCE test and femurs removed for the micronucleus test. Blood cell cultures were treated with 5μg/ml bromodeoxyuridine (BrdU) for SCE evaluation. No significant increases in micronucleated immature erythrocytes were observed for any test material. Statistically significant increases in SCE were observed in rats given BGVC alone or in female rats given G/MTBE. G/TAME induced increased SCE in both sexes at the highest dose only. Although DNA perturbation was observed for several samples, DNA damage was not expressed as increased micronuclei in bone marrow cells. Inclusion of oxygenates in gasoline did not increase the effects of gasoline alone or produce a cytogenetic hazard. Copyright © 2014 Elsevier Inc. All rights reserved.

Source profiles of volatile organic compounds (VOCs) measured in China: Part I

Science.gov (United States)

Liu, Ying; Shao, Min; Fu, Linlin; Lu, Sihua; Zeng, Limin; Tang, Dagang

The profiles of major volatile organic compound (VOC) sources in China, including vehicle exhaust, gasoline vapor, paint, asphalt, industrial and residential coal burning, biomass burning, and the petrochemical industry, were experimentally determined. Source samples were taken using a dilution chamber for mobile and stationary sources, biomass burning in an actual Chinese farmer's house, and ambient air in a petrochemical industrial area. The concentrations of 92 VOC species were quantified using canister sampling and a gas chromatography-flame ionization detection/mass spectrometry system, and VOC source profiles were developed for source apportionment of VOCs in the Pearl River Delta region. Based on the measurement of source profiles, possible tracers for various emission sources were identified; e.g., 2-methylpentane and 1,3-butadiene could be used as tracers for vehicle exhaust; the characteristic compounds of architectural coating were aromatics such as toluene and m, p-xylene; the light hydrocarbons, namely n-butane, trans-2-butene, and n-pentane, dominated the composition of gasoline vapor; and n-nonane, n-decane, and n-undecane were found to be typical of diesel vapor and asphalt application processes. As different emission sources are characterized by overlapping VOC species, the ratio of possible VOC tracers could be used to assess the contribution of various sources. The ratios between n-butane and isobutane, 1,3-butadiene and isoprene, and the ratios of aromatics (e.g., toluene to benzene and ethylbenzene to m, p-xylene) in the measured sources were compared.

Major reactive species of ambient volatile organic compounds (VOCs) and their sources in Beijing

Institute of Scientific and Technical Information of China (English)

SHAO; Min; FU; Linlin; LIU; Ying; LU; Sihua; ZHANG; Yuanhan

2005-01-01

Volatile organic compounds (VOCs) are important precursors of atmospheric chemical processes. As a whole mixture, the ambient VOCs show very strong chemical reactivity. Based on OH radical loss rates in the air, the chemical reactivity of VOCs in Beijing was calculated. The results revealed that alkenes, accounting for only about 15% in the mixing ratio of VOCs, provide nearly 75% of the reactivity of ambient VOCs and the C4 to C5 alkenes were the major reactive species among the alkenes. The study of emission characteristics of various VOCs sources indicated that these alkenes are mainly from vehicle exhaust and gasoline evaporation. The reduction of alkene species in these two sources will be effective in photochemical pollution control in Beijing.

Emission consequences of introducing bio ethanol as a fuel for gasoline cars

DEFF Research Database (Denmark)

Winther, Morten Mentz; Møller, Flemming; Jensen, Thomas Christian

2012-01-01

This article describes the direct vehicle emission impact of the future use of bio ethanol as a fuel for gasoline cars in Denmark arising from the vehicle specific fuel consumption and emission differences between neat gasoline (E0) and E5/E85 gasoline-ethanol fuel blends derived from emission......% in 2030. As predicted by the vehicle specific emission differences the calculated emission impacts of using bio ethanol are small for NOx, VOC and CO. Instead, for FS, BS1 and BS2 large emission reductions are due to the gradually cleaner new sold gasoline cars and the decline in total mileage until...

Health assessment of gasoline and fuel oxygenate vapors: developmental toxicity in rats.

Science.gov (United States)

Roberts, Linda G; Gray, Thomas M; Trimmer, Gary W; Parker, Robert M; Murray, F Jay; Schreiner, Ceinwen A; Clark, Charles R

2014-11-01

Gasoline-vapor condensate (BGVC) or condensed vapors from gasoline blended with methyl t-butyl ether (G/MTBE), ethyl t-butyl ether (G/ETBE), t-amyl methyl ether (G/TAME) diisopropyl ether (G/DIPE), ethanol (G/EtOH), or t-butyl alcohol (G/TBA) were evaluated for developmental toxicity in Sprague-Dawley rats exposed via inhalation on gestation days (GD) 5-20 for 6h/day at levels of 0 (control filtered air), 2000, 10,000, and 20,000mg/m(3). These exposure durations and levels substantially exceed typical consumer exposure during refueling (<1-7mg/m(3), 5min). Dose responsive maternal effects were reduced maternal body weight and/or weight change, and/or reduced food consumption. No significant malformations were seen in any study. Developmental effects occurred at 20,000mg/m(3) of G/TAME (reduced fetal body weight, increased incidence of stunted fetuses), G/TBA (reduced fetal body weight, increased skeletal variants) and G/DIPE (reduced fetal weight) resulting in developmental NOAEL of 10,000mg/m(3) for these materials. Developmental NOAELs for other materials were 20,000mg/m(3) as no developmental toxicity was induced in those studies. Developmental NOAELs were equal to or greater than the concurrent maternal NOAELs which ranged from 2000 to 20,000mg/m(3). There were no clear cut differences in developmental toxicity between vapors of gasoline and gasoline blended with the ether or alcohol oxygenates. Copyright © 2014 Elsevier Inc. All rights reserved.

Potential of secondary aerosol formation from Chinese gasoline engine exhaust.

Science.gov (United States)

Du, Zhuofei; Hu, Min; Peng, Jianfei; Guo, Song; Zheng, Rong; Zheng, Jing; Shang, Dongjie; Qin, Yanhong; Niu, He; Li, Mengren; Yang, Yudong; Lu, Sihua; Wu, Yusheng; Shao, Min; Shuai, Shijin

2018-04-01

Light-duty gasoline vehicles have drawn public attention in China due to their significant primary emissions of particulate matter and volatile organic compounds (VOCs). However, little information on secondary aerosol formation from exhaust for Chinese vehicles and fuel conditions is available. In this study, chamber experiments were conducted to quantify the potential of secondary aerosol formation from the exhaust of a port fuel injection gasoline engine. The engine and fuel used are common in the Chinese market, and the fuel satisfies the China V gasoline fuel standard. Substantial secondary aerosol formation was observed during a 4-5hr simulation, which was estimated to represent more than 10days of equivalent atmospheric photo-oxidation in Beijing. As a consequence, the extreme case secondary organic aerosol (SOA) production was 426±85mg/kg-fuel, with high levels of precursors and OH exposure. The low hygroscopicity of the aerosols formed inside the chamber suggests that SOA was the dominant chemical composition. Fourteen percent of SOA measured in the chamber experiments could be explained through the oxidation of speciated single-ring aromatics. Unspeciated precursors, such as intermediate-volatility organic compounds and semi-volatile organic compounds, might be significant for SOA formation from gasoline VOCs. We concluded that reductions of emissions of aerosol precursor gases from vehicles are essential to mediate pollution in China. Copyright © 2017. Published by Elsevier B.V.

An experimental study on regulated and unregulated pollutants from a spark ignition car fuelled on liquefied petroleum gas and Gasoline

International Nuclear Information System (INIS)

Shah, A.N.; Yun-shan, G.E.; Jun-fang, W.; Jian-wei, T.; Gardezi, S.A.R.

2010-01-01

In the experimental study conducted on a spark ignition (SI) car running on a chassis dynamometer, fuelled on liquefied petroleum gas (LPG) and gasoline, carbon monoxide (CO) and total hydrocarbons (HC) decreased by 37.3% and 46.8%, respectively, while oxides of nitrogen (NOx) increased by 59.7% due to higher compression ratio with LPG, compared with gasoline. In case of LPG fuel, formaldehyde, acetaldehyde, propionaldehyde, 2-butanone, butyraldehyde, benzaldehyde and valeraldehyde decreased, leading to an over all decrease of about 35% and 26% in carbonyls and their ozone forming potential (OFP), respectively, compared with gasoline. Furthermore, benzene, toluene, ethyl benzene, xylene and styrene decreased, resulting in an overall decrease of 38.8% in volatile organic compounds (VOCs) and 39.2% in BTEX (benzene, toluene, ethyl benzene and xylene) species due to more complete combustion with LPG, compared with gasoline. Further, the OFP of VOCs with LPG was 6% lower than that with gasoline fuel. (author)

Oxygen Storage Capacity and Oxygen Mobility of Co-Mn-Mg-Al Mixed Oxides and Their Relation in the VOC Oxidation Reaction

Directory of Open Access Journals (Sweden)

María Haidy Castaño

2015-05-01

Full Text Available Co-Mn-Mg-Al oxides were synthesized using auto-combustion and co-precipitation techniques. Constant ratios were maintained with (Co + Mn + Mg/Al equal to 3.0, (Co + Mn/Mg equal to 1.0 and Co/Mn equal to 0.5. The chemical and structural composition, redox properties, oxygen storage capacity and oxygen mobility were analyzed using X-ray fluorescence (XRF, X-ray diffraction (XRD, Raman spectroscopy, scanning electron microscopy (SEM, temperature-programmed reduction of hydrogen (H2-TPR, oxygen storage capacity (OSC, oxygen storage complete capacity (OSCC and isotopic exchange, respectively. The catalytic behavior of the oxides was evaluated in the total oxidation of a mixture of 250 ppm toluene and 250 ppm 2-propanol. The synthesis methodology affected the crystallite size, redox properties, OSC and oxide oxygen mobility, which determined the catalytic behavior. The co-precipitation method got the most active oxide in the oxidation of the volatile organic compound (VOC mixture because of the improved mobility of oxygen and ability to favor redox processes in the material structure.

Speciated OVOC and VOC emission inventories and their implications for reactivity-based ozone control strategy in the Pearl River Delta region, China.

Science.gov (United States)

Ou, Jiamin; Zheng, Junyu; Li, Rongrong; Huang, Xiaobo; Zhong, Zhuangmin; Zhong, Liuju; Lin, Hui

2015-10-15

The increasing ground-ozone (O3) levels, accompanied by decreasing SO2, NO2, PM10 and PM2.5 concentrations benefited from air pollution control measures implemented in recent years, initiated a serious challenge to control Volatile Organic Compound (VOC) emissions in the Pearl River Delta (PRD) region, China. Speciated VOC emission inventory is fundamental for estimating Ozone Formation Potentials (OFPs) to identify key reactive VOC species and sources in order to formulate efficient O3 control strategies. With the use of the latest bulk VOC emission inventory and local source profiles, this study developed the PRD regional speciated Oxygenated Volatile Organic Compound (OVOC) and VOC emission inventories to identify the key emission-based and OFP-based VOC sources and species. Results showed that: (1) Methyl alcohol, acetone and ethyl acetate were the major constituents in the OVOC emissions from industrial solvents, household solvents, architectural paints and biogenic sources; (2) from the emission-based perspective, aromatics, alkanes, OVOCs and alkenes made up 39.2%, 28.2%, 15.9% and 10.9% of anthropogenic VOCs; (3) from the OFP-based perspective, aromatics and alkenes become predominant with contributions of 59.4% and 25.8% respectively; (4) ethene, m/p-xylene, toluene, 1,2,4-trimethyl benzene and other 24 high OFP-contributing species were the key reactive species that contributed to 52% of anthropogenic emissions and up to 80% of OFPs; and (5) industrial solvents, industrial process, gasoline vehicles and motorcycles were major emission sources of these key reactive species. Policy implications for O3 control strategy were discussed. The OFP cap was proposed to regulate VOC control policies in the PRD region due to its flexibility in reducing the overall OFP of VOC emission sources in practice. Copyright © 2015 Elsevier B.V. All rights reserved.

A deeper look at the response of oxygenated and non oxygenated VOC to mid-term drought over the seasonal cycle: the case study of a drought-resistant species

Science.gov (United States)

Saunier, Amelie; Ormeño Lafuente, Elena; Wortham, Henri; Temime-Roussel, Brice; Fernandez, Catherine

2015-04-01

At the end of this century, climatic models plan an intensification of summer drought in the Mediterranean area due to a 30% rain reduction and a temperature rise of 3.4 °C. Plants respond to drought by modifying their primary (growth) and their secondary metabolism, the later being partly represented by volatile organic compound (VOC) emissions, such as terpenes. With drought, oxygenated and non oxygenated terpene emissions have been observed to increase, decrease or remain unchanged according to drought severity and vegetal model. By contrast, the response of non-terpenic oxygenated compounds to drought has been poorly studied. The aim of this study is to determine the potential impact of a two-year drought period on the full screen of VOC released by Q. pubescens, with a focus on both isoprene and methanol, issued from plant anabolism , and the numerous highly volatile oxygenated VOC, issued from plant catabolism (i.e. issued from oxidation of isoprene or methanol). A 70 years-old Downy oak forest (Quercus pubescens), highly resistant to drought stress, was selected as model ecosystem since it is well widespread in Southern France occupying 321 000 ha. Downy oak also represents the major source of isoprene emissions in the Mediterranean area and, unlike the other major Quercus sp. of the region (i.e. Quercus ilex, a monoterpene emitter) the impact of watering withholding over years has never been tackled. The study was performed at the experimental platform of O3HP (Oak Observatory at Observatoire de Haute Provence) in Southern France which is equipped with both a rain exclusion (by 30 %) and a rain addition structure (simulating the rainiest years of the region), allowing for comparison with naturally watered trees. Using dynamic enclosure chambers at the branch level and PTR-MS-Q-ToF, we screened the anabolic VOC (isoprene, methanol) and the catabolic VOC (e.g. methacrolein, methyl vinyl ketone, C6 aldehydes and carboxylic acids) of trees located under the

Effect of gasoline/methanol blends on motorcycle emissions: Exhaust and evaporative emissions

Science.gov (United States)

Li, Lan; Ge, Yunshan; Wang, Mingda; Li, Jiaqiang; Peng, Zihang; Song, Yanan; Zhang, Liwei

2015-02-01

The emission characteristics of motorcycles using gasoline and M15 (consisting of 85% gasoline and 15% methanol by volume) were investigated in this article. Exhaust and evaporative emissions, including regulated and unregulated emissions, of three motorcycles were investigated on the chassis dynamometer over the Urban Driving Cycle (UDC) and in the Sealed Housing for Evaporative Determination (SHED), respectively. The regulated emissions were detected by an exhaust gas analyzer directly. The unregulated emissions, including carbonyls, volatile organic compounds (VOCs) and methanol, were sampled through battery-operated air pumps using tubes coated with 2,4-dintrophenylhydrazine (DNPH), Tenax TA and silica gel, respectively. The experimental results showed that, for exhaust emission, compared with those from gasoline fueled motorcycles, the concentration of total hydrocarbons (THC) and CO from motorcycles fueled with M15 decreased by 11%-34.5% and 63%-84% respectively, while the concentration of NOx increased by 76.9%-107.7%. Compared with those from gasoline fueled motorcycles, BTEX from motorcycles fueled with M15 decreased by 16%-60% while formaldehyde increased by 16.4%-52.5%. For evaporative emission, diurnal losses were more than hot soak losses and turned out to be dominated in evaporative emissions. In addition, compared with gasoline fueling motorcycles, the evaporative emissions of THC, carbonyls and VOCs from motorcycles fueled with M15 increased by 11.7%-37%, 38%-45% and 16%-42%, respectively. It should be noted that the growth rate of methanol was as high as 297%-1429%. It is important to reduce the evaporative emissions of methanol fueling motorcycles.

Characteristics of Ambient Volatile Organic Compounds (VOCs Measured in Shanghai, China

Directory of Open Access Journals (Sweden)

Guang-Qiang Zhou

2010-08-01

Full Text Available To better understand the characteristics of ambient abundance of volatile organic compounds (VOCs in Shanghai, one of the biggest metropolis of China, VOCs were measured with a gas chromatography system equipped with a mass-selective detector (GC/MSD from July 2006 to February 2010. An intensive measurement campaign was conducted (eight samples per day with a 3 hour interval during May 2009. The comparison of ambient VOCs collected in different regions of Shanghai shows that the concentrations are slightly higher in the busy commercial area (28.9 ppbv at Xujiaui than in the urban administrative area (24.3 ppbv at Pudong. However, during the intensive measurement period, the concentrations in the large steel industrial area (28.7 ppbv at Baoshan were much higher than in the urban administrative area (18 ppbv at Pudong, especially for alkanes, alkenes, and toluene. The seasonal variations of ambient VOC concentrations measured at the Xujiahui sampling site indicate that the VOC concentrations are significantly affected by meteorological conditions (such as wind direction and precipitation. In addition, although alkanes are the most abundant VOCs at the Xujiahui measurement site, the most important VOCs contributing to ozone formation potential (OFP are aromatics, accounting for 57% of the total OFP. The diurnal variations of VOC concentrations show that VOC concentrations are higher on weekdays than in weekends at the Xujiahui sampling site, suggesting that traffic condition and human activities have important impacts on VOC emissions in Shanghai. The evidence also shows that the major sources of isoprene are mainly resulted from gasoline evaporation at a particular time (06:00–09:00 in the busy commercial area. The results gained from this study provide useful information for better understanding the characteristics of ambient VOCs and the sources of VOCs in Shanghai.

Characteristics of Ambient Volatile Organic Compounds (VOCs) Measured in Shanghai, China

Science.gov (United States)

Cai, Chang-Jie; Geng, Fu-Hai; Tie, Xue-Xi; Yu, Qiong; Peng, Li; Zhou, Guang-Qiang

2010-01-01

To better understand the characteristics of ambient abundance of volatile organic compounds (VOCs) in Shanghai, one of the biggest metropolis of China, VOCs were measured with a gas chromatography system equipped with a mass-selective detector (GC/MSD) from July 2006 to February 2010. An intensive measurement campaign was conducted (eight samples per day with a 3 hour interval) during May 2009. The comparison of ambient VOCs collected in different regions of Shanghai shows that the concentrations are slightly higher in the busy commercial area (28.9 ppbv at Xujiaui) than in the urban administrative area (24.3 ppbv at Pudong). However, during the intensive measurement period, the concentrations in the large steel industrial area (28.7 ppbv at Baoshan) were much higher than in the urban administrative area (18 ppbv at Pudong), especially for alkanes, alkenes, and toluene. The seasonal variations of ambient VOC concentrations measured at the Xujiahui sampling site indicate that the VOC concentrations are significantly affected by meteorological conditions (such as wind direction and precipitation). In addition, although alkanes are the most abundant VOCs at the Xujiahui measurement site, the most important VOCs contributing to ozone formation potential (OFP) are aromatics, accounting for 57% of the total OFP. The diurnal variations of VOC concentrations show that VOC concentrations are higher on weekdays than in weekends at the Xujiahui sampling site, suggesting that traffic condition and human activities have important impacts on VOC emissions in Shanghai. The evidence also shows that the major sources of isoprene are mainly resulted from gasoline evaporation at a particular time (06:00–09:00) in the busy commercial area. The results gained from this study provide useful information for better understanding the characteristics of ambient VOCs and the sources of VOCs in Shanghai. PMID:22163629

[Pollution characteristics and health risk assessment of atmospheric VOCs in the downtown area of Guangzhou, China].

Science.gov (United States)

Li, Lei; Li, Hong; Wang, Xue-Zhong; Zhang, Xin-Min; Wen, Chong

2013-12-01

The measurements of 31 kinds of VOCs in the ambient air of a site were carried out in the downtown of Guangzhou by online method from November 5, 2009 to November 9, 2009. The ambient level and composition characteristics, temporal variation characteristics, sources identification, and chemical reactivity of VOCs were studied, and the health risk of VOCs in the ambient air in the study area was assessed by using the international recognized health risk assessment method. Results showed that the mean and the range of the mass concentrations of 31 VOCs were 114.51 microg x m(-3) and 29.42-546.06 microg x m(-3), respectively. The mass concentrations of 31 VOCs, and those of alkanes, alkenes, and aromatics all showed a changing trend of higher in the morning and in the evening, and lower at noontime. Vehicular exhaust, gasoline and liquefied petroleum gas evaporates were the main sources of VOCs with the volatilization of paints and solvents being important emission sources. Toluene, trans-2-butene, m/p-xylene, i-butane, and 1,3,5-trimethylbenzene were the key reactive species among the 31 VOCs. Vehicular exhaust and gasoline evaporation were the main sources of VOCs leading to the formation of ozone. Health risk assessment showed that n-hexane, 1,3-butadiene, benzene, toluene, ethylbenzene, m/p-xylene and o-xylene had no appreciable risk of adverse non-cancer health effect on the exposed population, but 1, 3-butadiene and benzene had potential cancer risk. By comparing the corresponding data about health risk assessment of benzene compounds in some cities in China, it is concluded that benzene can impose relatively high cancer risk to the exposed populations in the ambient air of some cities in China. Therefore, strict countermeasures should be taken to further control the pollution of benzene in the ambient air of cities, and it is imperative to start the related studies and develop the atmospheric environmental health criteria and national ambient air quality

Flux measurement of methanol, acetaldehyde and other oxygenated VOCs from crop harvesting using proton-transfer-reaction mass spectrometry and surface layer gradient method

International Nuclear Information System (INIS)

Lindinger, C.; Jordan, A.; Karl, T.; Guenther, A.; Tschiersch, J.; Ruckerbauer, F.; Paretzke, H.

2002-01-01

PTR-MS technique was used to measure fluxes of various VOC's including oxygenates using surface layer gradient method. The VOC concentrations and temperature were measured at heights of about 0.5 m and 3.9 m above ground at field site in St. Johann in Tirol during and after grass cutting (24th and 25th of May 2000) in order to calculate fluxes. The sensible heat flux was obtained by a sonic anemometer with turbulence data analyzer. The major crop in this part of Austria are perennial grasses used for livestock farming. We observed VOC emission fluxes including methanol and acetaldehyde as the major volatile, C 5 and C 6 leaf wound compounds with lesser amounts and traces of acetone and butanone. This composition of VOC's is very similar to that released from slashed pasture grass. At the same time, VOC fluxes were measured with PTR-MS and eddy covariance method. Comparing the flux data of methanol and acetaldehyde of both days have shown very similar results. (author)

Ambitious coal to gasoline plan

Energy Technology Data Exchange (ETDEWEB)

Taffe, P

1979-06-20

A design study carried out by Badger Energy concludes that the first US commercial gasoline from coal facility could be completed in eight years. The cost of gasoline would be 1.09 US dollars/gal. in 1990 with coal at 25 US dollars/ton. The process involves oxygen-blown coal gasification, conversion to methanol by the Mobil process, gas fractionation and HF alkylation.

Contrasting VOC Composition in London, UK and Beijing, China

Science.gov (United States)

Dunmore, R.; Hopkins, J. R.; Shaw, M.; Squires, F. A.; Lee, J. D.; Lewis, A. C.; Hamilton, J. F.

2017-12-01

With an increasing fraction of the world's population now living in megacities, urban air quality in those locations has the potential to be one of the largest controllable factors for public health. Both London and Beijing are classified as megacities, with the latter almost twice as densely populated. The key drivers and trajectory of air pollution are unique to each location; London has substantially reduced PM10 concentrations over the past two decades but continues to have high urban NO2. Beijing has had well-reported high levels of PM, is now in a phase of gradual decline, and has proportionately low NO2. Both locations however, continue to emit a mix of gas phase pollutants with the potential to form photochemical ozone. Whilst the abundance of NOx in each city is relatively straightforward to quantify, the VOC mixtures that are present differ between these two cities and this has consequential impacts on the downwind ozone formation potential. This work reports a comprehensive assessment of VOC speciation, reactivity and abundance in the two cities using a common set of inter-comparable measurement approaches. Hourly observations of VOCs over the range C2 - C13+ were made using two gas chromatography (GC) instruments; a PLOT column based GC for the most volatile fraction (C2-C7) and a comprehensive two-dimensional GC (GCxGC) for VOCs with more than 7 carbons. London has atmospheric VOC concentrations that in mass and reactivity terms are dominated by longer chain VOCs from diesel fuel. The VOC mixture in ambient Beijing air is dominated by short chain VOCs, a mix of both alkenes from incomplete combustion sources and alkanes and aromatics from petrochemical sources. The substantial difference in the fleet proportions of gasoline and diesel powered vehicles between the two cities is clearly reflected in ambient VOCs. In summertime, isoprene was a notable contributor to VOC reactivity in both cities despite both being highly urbanised locations. The absolute

VOC species and emission inventory from vehicles and their SOA formation potentials estimation in Shanghai, China

Science.gov (United States)

Huang, C.; Wang, H. L.; Li, L.; Wang, Q.; Lu, Q.; de Gouw, J. A.; Zhou, M.; Jing, S. A.; Lu, J.; Chen, C. H.

2015-10-01

Volatile organic compound (VOC) species from vehicle exhausts and gas evaporation were investigated by chassis dynamometer and on-road measurements of nine gasoline vehicles, seven diesel vehicles, five motorcycles, and four gas evaporation samples. The secondary organic aerosol (SOA) mass yields of gasoline, diesel, motorcycle exhausts, and gas evaporation were estimated based on the mixing ratio of measured C2-C12 VOC species and inferred carbon number distributions. High aromatic contents were measured in gasoline exhausts and contributed comparatively more SOA yield. A vehicular emission inventory was compiled based on a local survey of on-road traffic in Shanghai and real-world measurements of vehicle emission factors from previous studies in the cities of China. The inventory-based vehicular organic aerosol (OA) productions to total CO emissions were compared with the observed OA to CO concentrations (ΔOA / ΔCO) in the urban atmosphere. The results indicate that vehicles dominate the primary organic aerosol (POA) emissions and OA production, which contributed about 40 and 60 % of OA mass in the urban atmosphere of Shanghai. Diesel vehicles, which accounted for less than 20 % of vehicle kilometers of travel (VKT), contribute more than 90 % of vehicular POA emissions and 80-90 % of OA mass derived by vehicles in urban Shanghai. Gasoline exhaust could be an important source of SOA formation. Tightening the limit of aromatic content in gasoline fuel will be helpful to reduce its SOA contribution. Intermediate-volatile organic compounds (IVOCs) in vehicle exhausts greatly contribute to SOA formation in the urban atmosphere of China. However, more experiments need to be conducted to determine the contributions of IVOCs to OA pollution in China.

Air exchange rates and migration of VOCs in basements and residences.

Science.gov (United States)

Du, L; Batterman, S; Godwin, C; Rowe, Z; Chin, J-Y

2015-12-01

Basements can influence indoor air quality by affecting air exchange rates (AERs) and by the presence of emission sources of volatile organic compounds (VOCs) and other pollutants. We characterized VOC levels, AERs, and interzonal flows between basements and occupied spaces in 74 residences in Detroit, Michigan. Flows were measured using a steady-state multitracer system, and 7-day VOC measurements were collected using passive samplers in both living areas and basements. A walk-through survey/inspection was conducted in each residence. AERs in residences and basements averaged 0.51 and 1.52/h, respectively, and had strong and opposite seasonal trends, for example, AERs were highest in residences during the summer, and highest in basements during the winter. Airflows from basements to occupied spaces also varied seasonally. VOC concentration distributions were right-skewed, for example, 90th percentile benzene, toluene, naphthalene, and limonene concentrations were 4.0, 19.1, 20.3, and 51.0 μg/m(3), respectively; maximum concentrations were 54, 888, 1117, and 134 μg/m(3). Identified VOC sources in basements included solvents, household cleaners, air fresheners, smoking, and gasoline-powered equipment. The number and type of potential VOC sources found in basements are significant and problematic, and may warrant advisories regarding the storage and use of potentially strong VOCs sources in basements. Few IAQ studies have examined basements. A sizable volume of air can flow between the basement and living area, and AERs in these two zones can differ considerably. In many residences, the basement contains significant emission sources and contributes a large fraction of VOC concentrations found in the living area. Exposures can be lowered by removing VOC sources from the basement; other exposure management options, such as local ventilation or isolation, are unlikely to be practical. © 2014 John Wiley & Sons A/S. Published by John Wiley & Sons Ltd.

Primary Emission and the Potential of Secondary Aerosol Formation from Chinese Gasoline Engine Exhaust

Science.gov (United States)

Hu, Min; Peng, Jianfei; Qin, Yanhong; Du, Zhuofei; Li, Mengjin; Zheng, Rong; Zheng, Jing; Shang, Dongjie; Lu, Sihua; Wu, Yusheng; Zeng, Limin; Guo, Song; Shao, Min; Wang, Yinhui; Shuai, Shijin

2017-04-01

Along with the urbanization and economic growth, vehicle population in China reached 269 million, ranked the second in the world in 2015. Gasoline vehicle is identified to be the main source for urban PM2.5 in China, accounting for 15%-31%. In this study the impact of fuel components on PM2.5 and volatile organic compounds (VOCs) emissions from a gasoline port fuel injection (PFI) engine and a gasoline direct injection (GDI) engine are discussed. Results show that, higher proportion of aromatics, alkenes or sulfur in gasoline fuel will lead to higher PM emissions. The PM from the PFI engine mainly consists of OC and a small amount of EC and inorganic ions, while the PM discharge from the GDI engine mainly consists of EC, OM and a small amount of inorganic ions. Since the GDI engines can reduce fuel consumption and CO2 emissions, and it would become more and more popular in the near future. The characteristics of POM component, emission factors and source profile were investigated from GDI engine, particularly focused on the effect of engine speed, load and the catalyst, which will be very much helpful for source identification as source indicators. Chamber experiments were conducted to quantify the potential of secondary aerosol formation from exhaust of a PFI gasoline engine and China V gasoline fuel. During 4-5 h simulation, equivalent to10 days of atmospheric photo-oxidation in Beijing, the extreme SOA production was 426 ± 85 mg/kg fuel, with high precursors and OH exposure. 14% of SOA measured in the chamber experiments could be explained through the oxidation of speciated single-ring aromatics. Unspeciated precursors, such as intermediate-volatility organic compounds and semi-volatility organic compounds, might be significant for SOA formation from gasoline VOCs. We concluded that reduction of emissions of aerosol precursor gases from vehicles is essential to mediate pollution in China.

Gasoline ether oxygenate occurrence in Europe, and a review of their fate and transport characteristics in the environment

Energy Technology Data Exchange (ETDEWEB)

Stupp, D.; Gass, M.; Leiteritz, H. [Dr. Stupp Consulting DSC, Tauw, Bergisch Gladbach (Germany); Pijls, C. [TAUW, Apeldoorn (Netherlands); Thornton, S. [University of Sheffield, Sheffield (United Kingdom); Smith, J.; Dunk, M.; Grosjean, T.; Den Haan, K. [CONCAWE, Brussels (Belgium)

2012-06-15

Ether oxygenates are added to certain gasoline (petrol) formulations to improve combustion efficiency and to increase the octane rating. In this report the term gasoline ether oxygenates (GEO) refers collectively to methyl tertiary butyl ether (MTBE), ethyl tertiary butyl ether (ETBE), tertiary amyl methyl ether (TAME), diisopropyl ether (DIPE), tertiary amyl ethyl ether (TAEE), tertiary hexyl methyl ether (THxME), and tertiary hexyl ethyl ether (THxEE), as well as the associated tertiary butyl alcohol (TBA). This report presents newly collated data on the production capacities and use of MTBE, ETBE, TAME, DIPE and TBA in 30 countries (27 EU countries and Croatia, Norway and Switzerland) to inform continued and effective environmental management practices for GEO by CONCAWE members. The report comprises data on gasoline use in Europe that were provided by CONCAWE and obtained from the European Commission. Furthermore Societe Generale de Surveillance (SGS) provided detailed analytical data (more than 1,200 sampling campaigns) on the GEO composition of gasoline in European countries in the period 2000-2010. Another major aspect of this report is the investigation of GEO distribution in groundwater, drinking water, surface water, runoff water, precipitation (rain/snow) and air in the European environment. Apart from the general sources of literature for the study, local environmental authorities and institutes in the 30 European countries have been contacted for additional information. Finally, a review of the international literature on GEO natural attenuation processes was undertaken with a focus on international reports and peer-reviewed scientific publications to give an overview on the known fate, transport and degradation mechanisms of GEO in the subsurface, to inform risk-management strategies that may rely on natural attenuation processes. The literature reveals that all GEO compounds used in fuels are highly water soluble and weakly retarded by aquifer

A case study on the application of air sparging with vapor extraction at a gasoline spill site

International Nuclear Information System (INIS)

Marley, M.C.; Walsh, M.T.; Nangeroni, T.E.

1991-01-01

This paper reports that in 1985, remedial activities were implemented at a gasoline spill site in Pawtucket, Rhode Island. The engineering company that contracted to perform the remedial activities designed, installed, and operated a free gasoline product recovery system and a groundwater pump and treat system. An air striping tower was utilized to remove volatile organic hydrocarbons (VOCs) dissolved in the groundwater. Gasoline hydrocarbon vapor migration into nearby basements was controlled through the operation of a soil gas venting system (SGVS), also installed in 1985. The groundwater treatment and free product recovery systems were shut off in may 1987; however, the soil venting system remained in operation and additional vacuum wells were installed to remediate gasoline contaminated vadose zone soils and to recover hydrocarbon vapors in the vicinity of the spill location

Borehole induction logging for the Dynamic Underground Stripping Project LLNL gasoline spill site

International Nuclear Information System (INIS)

Boyd, S.; Newmark, R.; Wilt, M.

1994-01-01

Borehole induction logs were acquired for the purpose of characterizing subsurface physical properties and monitoring steam clean up activities at the Lawrence Livermore National Laboratory. This work was part of the Dynamic Underground Stripping Project's demonstrated clean up of a gasoline spin. The site is composed of unconsolidated days, sands and gravels which contain gasoline both above and below the water table. Induction logs were used to characterize lithology, to provide ''ground truth'' resistivity values for electrical resistance tomography (ERT), and to monitor the movement of an underground steam plume used to heat the soil and drive volatile organic compounds (VOCs) to the extraction wells

Huge supply/demand increases seen in oxygenate forecasts

International Nuclear Information System (INIS)

Rhoades, A.K.

1992-01-01

Industry originally projected that oxygenate supply would not be able to meet the demand created by U.S. oxygenated and reformulated gasoline mandates. This paper reports that those projections have been reserved in two recent industry reports - one from Chemical Market Associates Inc. (CMAI) and one from Pace Consultants Inc. Pace's report, by Paulo Nery and Nathan Sims, predicts gasoline and oxygenates demand, and examines the role ethanol may play in changing those values. CMAI's report estimates captive supply and demand of butylenes and oxygenates. Oxygenates are entering the domestic gasoline market this winter as a result of the 1990 U.S. Clean Air Act Amendments. Methyl tertiary butyl ether (MTBE) is the most important oxygenate, although ethanol, ethyl tertiary butyl ether (ETBE), and tertiary amyl methyl ether (TAME) are gathering market strength. Ethanol's strength is derived from President Bush's ruling granting a waiver to reformulated gasoline containing ethanol. This waiver allows ethanol blends to have a vapor pressure 1 psi higher than other types of gasoline

Removal of gasoline volatile organic compounds via air biofiltration

International Nuclear Information System (INIS)

Miller, R.S.; Saberiyan, A.G.; Esler, C.T.; DeSantis, P.; Andrilenas, J.S.

1995-01-01

Volatile organic compounds (VOCs) generated by vapor extraction and air-stripping systems can be biologically treated in an air biofiltration unit. An air biofilter consists of one or more beds of packing material inoculated with heterotrophic microorganisms capable of degrading the organic contaminant of concern. Waste gases and oxygen are passed through the inoculated packing material, where the microorganisms will degrade the contaminant and release CO 2 + H 2 O. Based on data obtained from a treatability study, a full-scale unit was designed and constructed to be used for treating gasoline vapors generated by a vapor-extraction and groundwater-treatment system at a site in California. The unit is composed of two cylindrical reactors with a total packing volume of 3 m 3 . Both reactors are packed with sphagnum moss and inoculated with hydrocarbon-degrading microorganisms of Pseudomonas and Arthrobacter spp. The two reactors are connected in series for air-flow passage. Parallel lines are used for injection of water, nutrients, and buffer to each reactor. Data collected during the startup program have demonstrated an air biofiltration unit with high organic-vapor-removal efficiency

Catalysts for producing high octane-blending value olefins for gasoline

NARCIS (Netherlands)

Golombok, M.; Bruijn, de J.N.H.

2001-01-01

New restrictions on gasoline components mean that oxygenates and aromatics must be replaced by other high octane components. The dimerization of linear butene to form high octane gasoline blending components is evaluated under liquid phase reaction conditions over a number of different heterogeneous

40 CFR 80.83 - Renewable oxygenate requirements.

Science.gov (United States)

2010-07-01

... reformulated gasoline produced using RBOB that is produced by any refiner at each refinery, or is imported by... reformulated gasoline produced using RBOB, on average, has an oxygen content from such renewable oxygenate that...)Any reformulated gasoline and RBOB that is produced or imported prior to January 1, 1995 shall be...

Comparison of the composition between coal-liquid naphtha and petroleum gasoline

Energy Technology Data Exchange (ETDEWEB)

Miki, Y.; Sugimoto, Y.; Ono, S.; Machida, M. [National Chemical Laboratory for Industry, Tsukuba (Japan)

1997-08-01

Compositional characterization was performed using a gas chromatography-mass spectrometry-atomic emission detector technique on coal-liquid raw naphtha, coal-liquid refined naphtha, coal-liquid reformate and commercial petroleum gasoline. The chemical composition of these oils are divided into five groups: chain hydrocarbons, monocyclic hydrocarbons, bicyclic hydrocarbons, oxygen-containing compounds and other compounds (containing unidentified compounds). Compared to petroleum gasoline, the coal-liquid raw naphtha contains higher concentrations of straight paraffins, cycloparaffins, cycloolefins, bicycloparaffins and oxygen-containing compounds, and contains lower concentrations of brached paraffins and monocyclic aromatic compounds. Phenols and ketones are the major components of oxygen-containing compounds. The total concentration of paraffins and cycloparaffins increased after refining. The hydrogenation of olefins and the hydrodeoxygenation of oxygen-containing compounds are suggested to proceed during the refining process. The reforming treatment increased the concentrations of branched paraffins and monocyclic aromatic compounds; this suggests that coal-liquid reformat could be used as a major blending substance with petroleum gasoline.

Occurrence and temporal variability of methyl tert-butyl ether (MTBE) and other volatile organic compounds in select sources of drinking water : results of the focused survey

Science.gov (United States)

Delzer, Gregory C.; Ivahnenko, Tamara

2003-01-01

The large-scale use of the gasoline oxygenate methyl tert-butyl ether (MTBE), and its high solubility, low soil adsorption, and low biodegradability, has resulted in its detection in ground water and surface water in many places throughout the United States. Studies by numerous researchers, as well as many State and local environmental agencies, have discovered high levels of MTBE in soils and ground water at leaking underground gasoline-storage-tank sites and frequent occurrence of low to intermediate levels of MTBE in reservoirs used for both public water supply and recreational boating.In response to these findings, the American Water Works Association Research Foundation sponsored an investigation of MTBE and other volatile organic compounds (VOCs) in the Nation's sources of drinking water. The goal of the investigation was to provide additional information on the frequency of occurrence, concentration, and temporal variability of MTBE and other VOCs in source water used by community water systems (CWSs). The investigation was completed in two stages: (1) reviews of available literature and (2) the collection of new data. Two surveys were associated with the collection of new data. The first, termed the Random Survey, employed a statistically stratified design for sampling source water from 954 randomly selected CWSs. The second, which is the focus of this report, is termed the Focused Survey, which included samples collected from 134 CWS source waters, including ground water, reservoirs, lakes, rivers, and streams, that were suspected or known to contain MTBE. The general intent of the Focused Survey was to compare results with the Random Survey and provide an improved understanding of the occurrence, concentration, temporal variability, and anthropogenic factors associated with frequently detected VOCs. Each sample collected was analyzed for 66 VOCs, including MTBE and three other ether gasoline oxygenates (hereafter termed gasoline oxygenates). As part of

Experimental investigation on SI engine using gasoline and a hybrid iso-butanol/gasoline fuel

International Nuclear Information System (INIS)

Elfasakhany, Ashraf

2015-01-01

Highlights: • iso-Butanol–gasoline blends (iB) using up to 10 vol.% butanol were examined in SIE. • iB extensively decrease the greenhouse effect of SI engine. • iB without engine tuning led to a drop in engine performance at all speeds. • iB provide higher performance and lower CO and CO 2 emissions than n-butanol blends. • iB grant lower CO and UHC than gasoline at <2900 r/min, but overturn at >2900 r/min. - Abstract: Experimental investigation on pollutant emissions and performance of SI engine fueled with gasoline and iso-butanol–gasoline blends is carried out. Engine was operated at speed range of 2600–3400 r/min for each blend (3, 7 and 10 vol.% iso-butanol) and neat gasoline. Results declare that the CO and UHC emissions of neat gasoline are higher than those of the blended fuels for speeds less than or equal to 2900 r/min; however, for speeds higher than 2900 r/min, we have an opposite impact where the blended fuels produce higher level of CO and UHC emissions than the gasoline fuel. The CO 2 emission at using iso-butanol–gasoline blends is always lower than the neat gasoline at all speeds by up to 43%. The engine performance results demonstrate that using iso-butanol–gasoline blends in SI engine without any engine tuning lead to a drop in engine performance within all speed range. Without modifying the engine system, overall fuel combustion of iso-butanol–gasoline blends was quasi-complete. However, when engine system is optimized for blended fuels, iso-butanol has significant oxygen content and that can lead to a leaner combustion, which improves the completeness of combustion and therefore high performance and less emissions would be obtained. Finally, the performance and emissions of iso-butanol–gasoline blends are compared with those of n-butanol–gasoline blends at similar blended rates and engine working conditions. Such comparison is directed to evaluate the combustion dissimilarity of the two butanol isomers and also to

Occurrence and implications of methyl tert-butyl ether and gasoline hydrocarbons in ground water and source water in the United States and in drinking water in 12 Northeast and Mid-Atlantic States, 1993-2002

Science.gov (United States)

Moran, Michael J.; Zogorski, John S.; Squillace, Paul J.

2004-01-01

The occurrence and implications of methyl tert-butyl ether (MTBE) and gasoline hydrocarbons were examined in three surveys of water quality conducted by the U.S. Geological Survey?one national-scale survey of ground water, one national-scale survey of source water from ground water, and one regional-scale survey of drinking water from ground water. The overall detection frequency of MTBE in all three surveys was similar to the detection frequencies of some other volatile organic compounds (VOCs) that have much longer production and use histories in the United States. The detection frequency of MTBE was higher in drinking water and lower in source water and ground water. However, when the data for ground water and source water were limited to the same geographic extent as drinking-water data, the detection frequencies of MTBE were comparable to the detection frequency of MTBE in drinking water. In all three surveys, the detection frequency of any gasoline hydrocarbon was less than the detection frequency of MTBE. No concentration of MTBE in source water exceeded the lower limit of U.S. Environmental Protection Agency's Drinking-Water Advisory of 20 ?g/L (micrograms per liter). One concentration of MTBE in ground water exceeded 20 ?g/L, and 0.9 percent of drinking-water samples exceeded 20 ?g/L. The overall detection frequency of MTBE relative to other widely used VOCs indicates that MTBE is an important concern with respect to ground-water management. The probability of detecting MTBE was strongly associated with population density, use of MTBE in gasoline, and recharge, and weakly associated with density of leaking underground storage tanks, soil permeability, and aquifer consolidation. Only concentrations of MTBE above 0.5 ?g/L were associated with dissolved oxygen. Ground water underlying areas with high population density, ground water underlying areas where MTBE is used as a gasoline oxygenate, and ground water underlying areas with high recharge has a greater

VOC Control in Kraft Mills; FINAL

International Nuclear Information System (INIS)

Zhu, J.Y.; Chai, X.-S.; Edwards, L.L.; Gu, Y.; Teja, A.S.; Kirkman, A.G.; Pfromm, P.H.; Rezac, M.E.

2001-01-01

The formation of volatile organic compounds (VOCs), such as methanol, in kraft mills has been an environmental concern. Methanol is soluble in water and can increase the biochemical oxygen demand. Furthermore, it can also be released into atmosphere at the process temperatures of kraft mill-streams. The Cluster Rule of the EPA now requires the control of the release of methanol in pulp and paper mills. This research program was conducted to develop a computer simulation tool for mills to predict VOC air emissions. To achieve the objective of the research program, much effort was made in the development of analytical techniques for the analysis of VOC and determination of vapor liquid partitioning coefficient of VOCs in kraft mill-streams using headspace gas chromatography. With the developed analytical tool, methanol formation in alkaline pulping was studied in laboratory to provide benchmark data of the amount of methanol formation in pulping in kraft mills and for the validation of VOC formation and vapor-liquid equilibrium submodels. Several millwide air and liquid samplings were conducted using the analytical tools developed to validate the simulation tool. The VOC predictive simulation model was developed based on the basic chemical engineering concepts, i.e., reaction kinetics, vapor liquid equilibrium, combined with computerized mass and energy balances. Four kraft mill case studies (a continuous digester, two brownstock washing lines, and a pre-evaporator system) are presented and compared with mill measurements. These case studies provide valuable, technical information for issues related to MACT I and MACT II compliance, such as condensate collection and Clean-Condensate-Alternatives (CCA)

Projected reformulated gasoline and AFV use in California

International Nuclear Information System (INIS)

Bemis, G.R.

1995-01-01

In the spring to summer of 1996, California will switch from conventional and oxygenated gasolines to reformulated gasoline. This gasoline will be a designer fuel, and generally not available from sources outside California, since California's fuel specifications then will be unique. Thus, it will be important for California refiners to be able to meet the California reformulated gasoline (Cal-RFG) demand. California refiners are investing over $4 billion to upgrade their facilities for Cal-RFG. This represents approximately 40% of the total cost of making Cal-RFG, and is expected to cost 5--15 cents/gallon more than conventional gasoline to produce. Starting in the year 2000, EPA will require use of a similar fuel in seven geographical areas outside of California. The discussion below focuses on the supply, demand and price projections for Cal-RFG

Impact of a new gasoline benzene regulation on ambient air pollutants in Anchorage, Alaska

Science.gov (United States)

Yano, Yuriko; Morris, Stephen S.; Salerno, Christopher; Schlapia, Anne M.; Stichick, Mathew

2016-05-01

The purpose of this study was to quantify the impact of a new U.S. Environmental Protection Agency (EPA) standard that limits the amount of benzene allowed in gasoline on ambient benzene concentrations. This new standard, together with two companion regulations that limit cold-temperature automotive emissions and the permeability of portable fuel containers, was expected to lower the levels of ambient benzene and other volatile organic compounds (VOCs) nationwide. In this study the impact of the gasoline benzene standard was evaluated in Anchorage, Alaska in a two-phase ambient air monitoring study conducted before and after the new gasoline standard was implemented. Gasoline sold by Anchorage retailers was also evaluated in each phase to determine the content of benzene and other gasoline components. The average benzene content in Anchorage gasoline was reduced by 70%, from 5.05% (w/w) to 1.53% (w/w) following the implementation of the standard. The annual mean ambient benzene concentration fell by 51%, from 0.99 ppbv in Phase 1 to 0.49 ppbv in Phase 2. Analysis suggests the change in gasoline benzene content alone reduced benzene emissions by 46%. The changes in toluene, ethylbenzene, and xylene content in gasoline between Phase 1 and 2 were relatively small and the differences in the mean ambient concentrations of these compounds between phases were modest. Our results suggest that cold winter communities in high latitude and mountainous regions may benefit more from the gasoline benzene standard because of high benzene emissions resulting from vehicle cold start and a tendency to develop atmospheric stagnation conditions in the winter.

Effects of Cold Temperature and Ethanol Content on VOC Emissions from Light-Duty Gasoline Vehicles

Data.gov (United States)

U.S. Environmental Protection Agency — Supporting information Table S6 provides emission rates in g/km of volatile organic compounds measured from gasoline vehicle exhaust during chassis dynamometer...

Ambient volatile organic compounds (VOCs) in Calgary, Alberta: Sources and screening health risk assessment.

Science.gov (United States)

Bari, Md Aynul; Kindzierski, Warren B

2018-08-01

Exposure to ambient volatile organic compound (VOCs) in urban areas is of interest because of their potential chronic and acute adverse effects to public health. Limited information is available about VOC sources in urban areas in Canada. An investigation of ambient VOCs levels, their potential sources and associated risks to public health was undertaken for the urban core of Alberta's largest city (downtown Calgary) for the period 2010-2015. Twenty-four hour arithmetic and geometric mean concentrations of total VOCs were 42μg/m 3 and 39μg/m 3 , respectively and ranged from 16 to 160μg/m 3 , with winter levels about two-fold higher than summer. Alkanes (58%) were the most dominant compounds followed by halogenated VOCs (22%) and aromatics (11%). Mean and maximum 24h ambient concentrations of selected VOCs of public health concern were below chronic and acute health risk screening criteria of the United States regulatory agencies and a cancer screening benchmark used in Alberta equivalent to 1 in 100,000 lifetime risk. The Positive matrix factorization (PMF) model revealed nine VOC sources at downtown Calgary, where oil/natural gas extraction/combustion (26%), fuel combustion (20%), traffic sources including gasoline exhaust, diesel exhaust, mixed fugitive emissions (10-15%), and industrial coatings/solvents (12%) were predominant. Other sources included dry cleaning (3.3%), biogenic (3.5%) and a background source (18%). Source-specific health risk values were also estimated. Estimated cancer risks for all sources were below the Alberta cancer screening benchmark, and estimated non-cancer risks for all sources were well below a safe level. Copyright © 2018 Elsevier B.V. All rights reserved.

Recent progress in gasoline surrogate fuels

KAUST Repository

Sarathy, Mani; Farooq, Aamir; Kalghatgi, Gautam T.

2017-01-01

Petroleum-derived gasoline is currently the most widely used fuel for transportation propulsion. The design and operation of gasoline fuels is governed by specific physical and chemical kinetic fuel properties. These must be thoroughly understood in order to improve sustainable gasoline fuel technologies in the face of economical, technological, and societal challenges. For this reason, surrogate mixtures are formulated to emulate the thermophysical, thermochemical, and chemical kinetic properties of the real fuel, so that fundamental experiments and predictive simulations can be conducted. Early studies on gasoline combustion typically adopted single component or binary mixtures (n-heptane/isooctane) as surrogates. However, the last decade has seen rapid progress in the formulation and utilization of ternary mixtures (n-heptane/isooctane/toluene), as well as multicomponent mixtures that span the entire carbon number range of gasoline fuels (C4–C10). The increased use of oxygenated fuels (ethanol, butanol, MTBE, etc.) as blending components/additives has also motivated studies on their addition to gasoline fuels. This comprehensive review presents the available experimental and chemical kinetic studies which have been performed to better understand the combustion properties of gasoline fuels and their surrogates. Focus is on the development and use of surrogate fuels that emulate real fuel properties governing the design and operation of engines. A detailed analysis is presented for the various classes of compounds used in formulating gasoline surrogate fuels, including n-paraffins, isoparaffins, olefins, naphthenes, and aromatics. Chemical kinetic models for individual molecules and mixtures of molecules to emulate gasoline surrogate fuels are presented. Despite the recent progress in gasoline surrogate fuel combustion research, there are still major gaps remaining; these are critically discussed, as well as their implications on fuel formulation and engine

Recent progress in gasoline surrogate fuels

KAUST Repository

Sarathy, Mani

2017-12-06

Petroleum-derived gasoline is currently the most widely used fuel for transportation propulsion. The design and operation of gasoline fuels is governed by specific physical and chemical kinetic fuel properties. These must be thoroughly understood in order to improve sustainable gasoline fuel technologies in the face of economical, technological, and societal challenges. For this reason, surrogate mixtures are formulated to emulate the thermophysical, thermochemical, and chemical kinetic properties of the real fuel, so that fundamental experiments and predictive simulations can be conducted. Early studies on gasoline combustion typically adopted single component or binary mixtures (n-heptane/isooctane) as surrogates. However, the last decade has seen rapid progress in the formulation and utilization of ternary mixtures (n-heptane/isooctane/toluene), as well as multicomponent mixtures that span the entire carbon number range of gasoline fuels (C4–C10). The increased use of oxygenated fuels (ethanol, butanol, MTBE, etc.) as blending components/additives has also motivated studies on their addition to gasoline fuels. This comprehensive review presents the available experimental and chemical kinetic studies which have been performed to better understand the combustion properties of gasoline fuels and their surrogates. Focus is on the development and use of surrogate fuels that emulate real fuel properties governing the design and operation of engines. A detailed analysis is presented for the various classes of compounds used in formulating gasoline surrogate fuels, including n-paraffins, isoparaffins, olefins, naphthenes, and aromatics. Chemical kinetic models for individual molecules and mixtures of molecules to emulate gasoline surrogate fuels are presented. Despite the recent progress in gasoline surrogate fuel combustion research, there are still major gaps remaining; these are critically discussed, as well as their implications on fuel formulation and engine

Performance and emissions of gasoline blended with terpineol as an octane booster

KAUST Repository

Vallinayagam, R.

2016-11-10

This study investigates the effect of using terpineol as an octane booster for gasoline fuel. Unlike ethanol, terpineol is a high energy density biofuel that is unlikely to result in increased volumetric fuel consumption when used in engines. In this study, terpineol is added to non-oxygenated FACE F gasoline (Research Octane Number = 94.5) in volumetric proportions of 10%, 20% and 30% and tested in a single cylinder spark ignited engine. The performance of terpineol blended fuels are compared against a standard oxygenated EURO V (ethanol blended) gasoline. It was determined that the addition of terpineol to FACE F gasoline enhanced the octane number of the blend, resulting in improved brake thermal efficiency and total fuel consumption. For FACE F + 30% terpineol, break thermal efficiency was improved by 12.1% over FACE F gasoline at full load for maximum brake torque operating point, and similar performance as EURO V gasoline was achieved. Due to its high energy density, total fuel consumption was reduced by 6.2% and 9.7% with 30% terpineol in the blend when compared to FACE F gasoline at low and full load conditions, respectively. Gaseous emissions such as total hydrocarbon and carbon monoxide emission were reduced by 36.8% and 22.7% for FACE F + 30% terpineol compared to FACE F gasoline at full load condition. On the other hand, nitrogen oxide and soot emissions are increased for terpineol blended FACE F gasoline when compared to FACE F and EURO V gasoline. © 2016 Elsevier Ltd

Terpineol as a novel octane booster for extending the knock limit of gasoline

KAUST Repository

Vallinayagam, R.

2016-09-16

Improving the octane number of gasoline offers the potential of improved engine combustion, as it permits spark timing advancement without engine knock. This study proposes the use of terpineol as an octane booster for gasoline in a spark ignited (SI) engine. Terpineol is a bio-derived oxygenated fuel obtained from pine tree resin, and has the advantage of higher calorific value than ethanol. The ignition delay time (IDT) of terpineol was first investigated in an ignition quality tester (IQT). The IQT results demonstrated a long ignition delay of 24.7 ms for terpineol and an estimated research octane number (RON) of 104, which was higher than commercial European (Euro V) gasoline. The octane boosting potential of terpineol was further investigated by blending it with a non-oxygenated gasoline (FACE F), which has a RON (94) lower than Euro V gasoline (RON = 97). The operation of a gasoline direct injection (GDI) SI engine fueled with terpineol-blended FACE F gasoline enabled spark timing advancement and improved engine combustion. The knock intensity of FACE F + 30% terpineol was lower than FACE F gasoline at both maximum brake torque (MBT) and knock limited spark advance (KLSA) operating points. Increasing proportions of terpineol in the blend caused peak heat release rate, in-cylinder pressure, CA50, and combustion duration to be closer to those of Euro V gasoline. Furthermore, FACE F + 30% terpineol displayed improved combustion characteristics when compared to Euro V gasoline. © 2016

Exposure to regular gasoline and ethanol oxyfuel during refueling in Alaska.

OpenAIRE

Backer, L C; Egeland, G M; Ashley, D L; Lawryk, N J; Weisel, C P; White, M C; Bundy, T; Shortt, E; Middaugh, J P

1997-01-01

Although most people are thought to receive their highest acute exposures to gasoline while refueling, relatively little is actually known about personal, nonoccupational exposures to gasoline during refueling activities. This study was designed to measure exposures associated with the use of an oxygenated fuel under cold conditions in Fairbanks, Alaska. We compared concentrations of gasoline components in the blood and in the personal breathing zone (PBZ) of people who pumped regular unleade...

Impact of gasoline inhalation on some neurobehavioural characteristics of male rats

OpenAIRE

Kinawy Amal A

2009-01-01

Abstract Background This paper examines closely and compares the potential hazards of inhalation of two types of gasoline (car fuel). The first type is the commonly use leaded gasoline and the second is the unleaded type enriched with oxygenate additives as lead substituent in order to raise the octane number. The impacts of gasoline exposure on Na+, K+-ATPase, superoxide dismutase (SOD), acetylcholinesterase (AChE), total protein, reduced glutathione (GSH), and lipid peroxidation (TBARS) in ...

Solid phase microextraction: measurement of volatile organic compounds (VOCs) in Dhaka City air pollution.

Science.gov (United States)

Hussam, A; Alauddin, M; Khan, A H; Chowdhury, D; Bibi, H; Bhattacharjee, M; Sultana, S

2002-08-01

A solid phase microextraction (SPME) technique was applied for the sampling of volatile organic compounds (VOCs) in ambient air polluted by two stroke autorickshaw engines and automobile exhausts in Dhaka city, Bangladesh. Analysis was carried out by capillary gas chromatography (GC) and GC-mass spectrometry (MS). The methodology was tested by insitu sampling of an aromatic hydrocarbon mixture gas standard with a precision of +/-5% and an average accuracy of 1-20%. The accuracy for total VOCs concentration measurement was about 7%. VOC's in ambient air were collected by exposing the SPME fiber at four locations in Dhaka city. The chromatograms showed signature similar to that of unburned gasoline (petrol) and weathered diesel containing more than 200 organic compounds; some of these compounds were positively identified. These are normal hydrocarbons pentane (n-C5H2) through nonacosane (n-C29H60), aromatic hydrocarbons: benzene, toluene, ethylbenzene, n-propylbenzene, n-butylbenzene, 1,3,5-trimethylbenzene, xylenes, and 1-isocyanato-3-methoxybenzene. Two samples collected near an autorickshaw station contained 783000 and 1479000 microg/m3 of VOCs. In particular, the concentration of toluene was 50-100 times higher than the threshold limiting value of 2000 microg/m3. Two other samples collected on street median showed 135000 microg/m3 and 180000 microg/m3 of total VOCs. The method detection limit of the technique for most semi-volatile organic compounds was 1 microg/m3.

Customer exposure to gasoline vapors during refueling at service stations.

Science.gov (United States)

Hakkola, M A; Saarinen, L H

2000-09-01

Gasoline is a volatile complex mixture of hydrocarbon compounds that is easily vaporized during handling under normal conditions. Modern reformulated gasoline also contains oxygenates to enhance octane number and reduce ambient pollution. This study measured the difference in the exposure of customers to gasoline and oxygenate vapors during refueling in service stations with and without vapor recovery systems. Field measurements were carried out at two self-service stations. One was equipped with Stage I and the other with Stage II vapor recovery systems. At Stage I stations there is vapor recovery only during delivery from road tanker, and at Stage II stations additional vapor recovery during refueling. The exposure of 20 customers was measured at both stations by collecting air samples from their breathing zone into charcoal tubes during refueling with 95-octane reformulated gasoline. Each sample represented two consecutive refuelings. The samples were analyzed in the laboratory by gas chromatography using mass-selective detection for vapor components. The Raid vapor pressure of gasoline was 70 kPa and an oxygen content 2 wt%. Oxygenated gasoline contained 7 percent methyl tert-butyl ether (MtBE) and 5 percent methyl tert-amyl ether (MtAE). The geometric mean concentrations of hydrocarbons (C3-C11) in the customers' breathing zone was 85 mg/m3 (range 2.5-531 mg/m3) at the Stage I service station and 18 mg/m3 (range service station. The geometric mean of the exposure of customers to MtBE during refueling at the Stage I service station was 15.3 mg/m3 (range 1.8-74 mg/m3), and at the Stage II service station 3.4 mg/m3 (range 0.2-16 mg/m3). The differences in exposure were statistically significant (p station. The measurements were done on consecutive days at the various service stations. The temperature ranged from 10 to 17 degrees C, and wind velocity was 2-4 m/s. The climatic conditions were very similar on the measurement days. Based on this study it was found

Impact of reformulated gasoline on emissions from current and future vehicles

International Nuclear Information System (INIS)

Colucci, J.M.; Benson, J.D.

1993-01-01

Gasolines reformulated specifically for reducing vehicle emissions will result in the most significant changes in the U.S. refining industry since the advent of unleaded gasoline. This paper will review the results from the Auto/Oil Air Quality Improvement Research Program showing the beneficial effects on vehicle emissions of individually decreasing gasoline aromatic, olefin and sulfur contents, 90% distillation temperature, and Reid vapor pressure, and of adding oxygenates. The paper discusses the importance of reformulated gasolines for reducing emissions from existing vehicles by complying with requirements in the Clean Air Act and California's Low Emission Vehicle/Clean Fuels Program. It will show the importance of controlling Vehicle/Clean Fuels Program. It will show the importance of controlling specific aromatic and olefin compounds in gasoline, and it will discuss how automotive manufacturers will utilize reformulated gasolines to meet future stringent vehicle emission standards

Concentrations and fluxes of isoprene and oxygenated VOCs at a French Mediterranean oak forest

International Nuclear Information System (INIS)

Kalogridis, C.; Gros, V.; Sarda-Esteve, R.; Bonsang, B.; Bonnaire, N.; Boissard, C.; Baisnee, D.; Lathiere, J.

2014-01-01

The CANOPEE project aims to better understand the biosphere-atmosphere exchanges of biogenic volatile organic compounds (BVOCs) in the case of Mediterranean ecosystems and the impact of in-canopy processes on the atmospheric chemical composition above the canopy. Based on an intensive field campaign, the objective of our work was to determine the chemical composition of the air inside a canopy as well as the net fluxes of reactive species between the canopy and the boundary layer. Measurements were carried out during spring 2012 at the field site of the Oak Observatory of the Observatoire de Haute Provence (O3HP) located in the southeast of France. The site is a forest ecosystem dominated by downy oak, Quercus pubescens Willd., a typical Mediterranean species which features large isoprene emission rates. Mixing ratios of isoprene, its degradation products methylvinylketone (MVK) and methacrolein (MACR) and several other oxygenated VOC (OxVOC) were measured above the canopy using an online proton transfer reaction mass spectrometer (PTR-MS), and fluxes were calculated by the disjunct eddy covariance approach. The O3HP site was found to be a very significant source of isoprene emissions, with daily maximum ambient concentrations ranging between 2-16 ppbv inside and 2-5 ppbv just above the top of the forest canopy. Significant isoprene fluxes were observed only during daytime, following diurnal cycles with midday net emission fluxes from the canopy ranging between 2.0 and 9.7 mgm -2 h -1 . Net isoprene normalized flux (at 30 C, 1000 μmol quantam -2 s -1 ) was estimated at 7.4 mgm -2 h -1 . Evidence of direct emission of methanol was also found exhibiting maximum daytime fluxes ranging between 0.2 and 0.6 mgm -2 h -1 , whereas flux values for monoterpenes and others OxVOC such as acetone and acetaldehyde were below the detection limit. The MVK+MACR-to-isoprene ratio provided useful information on the oxidation of isoprene, and is in agreement with recent findings

Use of GC/MS Analysis to Distinguish Between Vapor Intrusion and Indoor Sources of VOCs - Standardized Protocol for On-Site Evaluation of Vapor Intrusion

Science.gov (United States)

2014-07-01

Testing a Sealed Crack in a Concrete Floor .................................................................. 14 Figure 5: VOC Responses to...Engineered Fluid Toluene Some paints and adhesives SprayPAK Enamel , Minwax Wood Finish Xylenes Adhesives, paints, gasoline Bonide Tree Sprays and...expansion joints, plumbing penetrations, or cracks . 3 Note that if indoor air concentrations are

Effect of traffic restriction on reducing ambient volatile organic compounds (VOCs): Observation-based evaluation during a traffic restriction drill in Guangzhou, China

Science.gov (United States)

Huang, Xinyu; Zhang, Yanli; Yang, Weiqiang; Huang, Zuzhao; Wang, Yujun; Zhang, Zhou; He, Quanfu; Lü, Sujun; Huang, Zhonghui; Bi, Xinhui; Wang, Xinming

2017-07-01

Traffic restriction (TR) is a widely adopted control measure in case of heavy air pollution particularly in urban areas, yet it is hard to evaluate the effect of TR on reducing VOC emissions based on monitoring data since ambient VOC mixing ratios are influenced not only by source emissions but also by meteorological conditions and atmospheric degradation. Here we collected air samples for analysis of VOCs before, during and after a TR drill carried out in Guangzhou in September 2010 at both a roadside and a rooftop (∼50 m above the ground) site. TR measures mainly included the "odd-even license" rule and banning high-emitting "yellow label" vehicles. The mixing ratios of non-methane hydrocarbons (NMHCs) did not show significant changes at the roadside site with total NMHCs of 39.0 ± 11.8 ppbv during non-TR period and 39.1 ± 14.8 ppbv during TR period, whereas total NMHCs decreased from 30.4 ± 14.3 ppbv during the non-TR period to 22.1 ± 10.6 ppbv during the TR period at rooftop site. However, the ratios of methyl tert-butyl ether (MTBE), benzene and toluene against carbon monoxide (MTBE/CO, T/CO and B/CO) at the both sampling sites dropped significantly. The ratios of toluene to benzene (T/B) instead increased significantly. Changes in these ratios all consistently indicated reduced input from traffic emissions particularly gasoline vehicles. Source attribution by positive matrix factorization (PMF) confirmed that during the TR period gasoline vehicles contributed less VOCs in percentages while industrial sources, biomass burning and LPG shared larger percentages. Assuming that emissions from industrial sources remained unchanged during the TR and non-TR periods, we further used the PMF-retrieved contribution percentages to deduce the reduction rate of traffic-related VOC emissions, and obtained a reduction rate of 31% based on monitoring data at the roadside site and of 34% based on the monitoring data at the rooftop site. Considering VOC emissions from all

Oxygenates in automotive fuels. Consequence analysis - preliminary study

International Nuclear Information System (INIS)

Brandberg, Aa.; Saevbark, B.

1994-01-01

Oxygenates is used in gasoline due to several reasons. They are added as high-octane components in unleaded gasoline and as agents to reduce the emission of harmful substances. Oxygenates produced from biomass might constitute a coming market for alternative fuels. This preliminary study describes the prerequisites and consequences of such an oxygenate utilization. 39 refs, 9 figs, 5 tabs

Field observations of volatile organic compound (VOC) exchange in red oaks

Science.gov (United States)

Cappellin, Luca; Algarra Alarcon, Alberto; Herdlinger-Blatt, Irina; Sanchez, Juaquin; Biasioli, Franco; Martin, Scot T.; Loreto, Francesco; McKinney, Karena A.

2017-03-01

Volatile organic compounds (VOCs) emitted by forests strongly affect the chemical composition of the atmosphere. While the emission of isoprenoids has been largely characterized, forests also exchange many oxygenated VOCs (oVOCs), including methanol, acetone, methyl ethyl ketone (MEK), and acetaldehyde, which are less well understood. We monitored total branch-level exchange of VOCs of a strong isoprene emitter (Quercus rubra L.) in a mixed forest in New England, where canopy-level fluxes of VOCs had been previously measured. We report daily exchange of several oVOCs and investigated unknown sources and sinks, finding several novel insights. In particular, we found that emission of MEK is linked to uptake of methyl vinyl ketone (MVK), a product of isoprene oxidation. The link was confirmed by corollary experiments proving in vivo detoxification of MVK, which is harmful to plants. Comparison of MEK, MVK, and isoprene fluxes provided an indirect indication of within-plant isoprene oxidation. Furthermore, besides confirming bidirectional exchange of acetaldehyde, we also report for the first time direct evidence of benzaldehyde bidirectional exchange in forest plants. Net emission or deposition of benzaldehyde was found in different periods of measurements, indicating an unknown foliar sink that may influence atmospheric concentrations. Other VOCs, including methanol, acetone, and monoterpenes, showed clear daily emission trends but no deposition. Measured VOC emission and deposition rates were generally consistent with their ecosystem-scale flux measurements at a nearby site.

40 CFR 80.212 - What requirements apply to oxygenate blenders?

Science.gov (United States)

2010-07-01

... blend oxygenate into gasoline downstream of the refinery that produced the gasoline or the import facility where the gasoline was imported, are not subject to the requirements of this subpart applicable to... PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Gasoline Sulfur Gasoline Sulfur Standards § 80...

Investigation of gasoline distributions within petrol stations: spatial and seasonal concentrations, sources, mitigation measures, and occupationally exposed symptoms.

Science.gov (United States)

Sairat, Theerapong; Homwuttiwong, Sahalaph; Homwutthiwong, Kritsana; Ongwandee, Maneerat

2015-09-01

We measured levels of VOCs and determined the distributions of benzene concentrations over the area of two petrol stations in all three seasons. Using the concentrations and sampling positions, we created isoconcentration contour maps. The average concentrations ranged 18-1288 μg m(-3) for benzene and 12-81 μg m(-3) for toluene. The contour maps indicate that high-level contours of benzene were found not only at the fuel dispenser areas but also at the storage tank refilling points, open drainage areas where gasoline-polluted wastewater was flowing, and the auto service center located within the station area. An assessment of the benzene to toluene ratio contour plots implicates that airborne benzene and toluene near the fuel dispenser area were attributed to gasoline evaporation although one of the studied stations may be influenced by other VOC sources besides gasoline evaporation. Additionally, during the routine refilling of the underground fuel storage tanks by a tank truck, the ambient levels of benzene and toluene increased tremendously. The implementation of source control by replacing old dispensers with new fuel dispensers that have an efficient cutoff feature and increased delivery speed can reduce spatial benzene concentrations by 77%. Furthermore, a questionnaire survey among 63 service attendants in ten stations revealed that headache was the most reported health complaint with a response rate of 32%, followed by fatigue with 20%. These prominent symptoms could be related to an exposure to high benzene concentrations.

Evaluation of Anti-Knock Quality of Dicyclopentadiene-Gasoline Blends

KAUST Repository

Al-Khodaier, Mohannad

2017-03-28

Increasing the anti-knock quality of gasoline fuels can enable higher efficiency in spark ignition engines. In this study, the blending anti-knock quality of dicyclopentadiene (DCPD), a by-product of ethylene production from naphtha cracking, with various gasoline fuels is explored. The blends were tested in an ignition quality tester (IQT) and a modified cooperative fuel research (CFR) engine operating under homogenous charge compression ignition (HCCI) and knock limited spark advance (KLSA) conditions. Due to current fuel regulations, ethanol is widely used as a gasoline blending component in many markets. In addition, ethanol is widely used as a fuel and literature verifying its performance. Moreover, because ethanol exhibits synergistic effects, the test results of DCPD-gasoline blends were compared to those of ethanol-gasoline blends. The experiments conducted in this work enabled the screening of DCPD auto-ignition characteristics across a range of combustion modes. The synergistic blending nature of DCPD was apparent and appeared to be greater than that of ethanol. The data presented suggests that DCPD has the potential to be a high octane blending component in gasoline; one which can substitute alkylates, isomerates, reformates, and oxygenates.

Evaluation of Anti-Knock Quality of Dicyclopentadiene-Gasoline Blends

KAUST Repository

Al-Khodaier, Mohannad; Bhavani Shankar, Vijai Shankar; Waqas, Muhammad; Naser, Nimal; Sarathy, Mani; Johansson, Bengt

2017-01-01

Increasing the anti-knock quality of gasoline fuels can enable higher efficiency in spark ignition engines. In this study, the blending anti-knock quality of dicyclopentadiene (DCPD), a by-product of ethylene production from naphtha cracking, with various gasoline fuels is explored. The blends were tested in an ignition quality tester (IQT) and a modified cooperative fuel research (CFR) engine operating under homogenous charge compression ignition (HCCI) and knock limited spark advance (KLSA) conditions. Due to current fuel regulations, ethanol is widely used as a gasoline blending component in many markets. In addition, ethanol is widely used as a fuel and literature verifying its performance. Moreover, because ethanol exhibits synergistic effects, the test results of DCPD-gasoline blends were compared to those of ethanol-gasoline blends. The experiments conducted in this work enabled the screening of DCPD auto-ignition characteristics across a range of combustion modes. The synergistic blending nature of DCPD was apparent and appeared to be greater than that of ethanol. The data presented suggests that DCPD has the potential to be a high octane blending component in gasoline; one which can substitute alkylates, isomerates, reformates, and oxygenates.

Nanotechnology in environmental remediation: degradation of volatile organic compounds (VOCs) over visible-light-active nanostructured materials.

Science.gov (United States)

Selvaraj, Rengaraj; Al-Kindy, Salma M Z; Silanpaa, Mika; Kim, Younghun

2014-01-01

Volatile organic compounds (VOCs) are major pollutants and are considered to be one of the most important contaminants generated by human beings living in urban and industrial areas. Methyl tert-butyl ether (MTBE) is a VOC that has been widely used as a gasoline additive to reduce VOC emissions from motor vehicles. However, new gasoline additives like MTBE are having negative environmental impacts. Recent survey reports clearly show that groundwater is often polluted owing to leakage of petroleum products from underground storage tanks. MTBE is highly soluble in water (e.g., 0.35-0.71 M) and has been detected at high concentrations in groundwater. The presence of MTBE in groundwater poses a potential health problem. The documented effects of MTBE exposure are headaches, vomiting, diarrhea, fever, cough, muscle aches, sleepiness, disorientation, dizziness, and skin and eye irritation. To address these problems, photocatalytic treatment is the preferred treatment for polluted water. In the present work, a simple and template-free solution phase synthesis method has been developed for the preparation of novel cadmium sulfide (CdS) hollow microspheres using cadmium nitrate and thioacetamide precursors. The synthesized products have been characterized by a variety of methods, including X-ray powder diffraction, high-resolution scanning electron microscopy (HR-SEM), X-ray photoelectron spectroscopy, and UV-visible diffused reflectance spectroscopy. The HR-SEM measurements revealed the spherical morphology of the CdS microspheres, which evolved by the oriented aggregation of the primary CdS nanocrystals. Furthermore, studies of photocatalytic activity revealed that the synthesized CdS hollow microspheres exhibit an excellent photocatalytic performance in rapidly degrading MTBE in aqueous solution under visible light illumination. These results suggest that CdS microspheres will be an interesting candidate for photocatalytic detoxification studies under visible light

Gasoline marketing

International Nuclear Information System (INIS)

England-Joseph, J.

1991-06-01

This paper is a discussion of two reports. One, issued in April 1990, addresses gasoline octane mislabeling, and the other, issued in February 1991, addresses possible consumer overbuying of premium gasoline. Consumers can purchase several grades of unleaded gasoline with different octane ratings regular (87 octane), mid-grade (89 octane), and premium (91 octane or above). A major concern of consumer buying gasoline is that they purchase gasoline with an octane rating that meets their vehicles' octane requirements. In summary, it was found that consumers may unknowingly be purchasing gasoline with lower octane than needed because octane ratings are mislabeled on gasoline pumps. At the same time, other consumers, believing they may get better performance, may be knowingly buying higher priced premium gasoline when regular gasoline would meet their vehicles' needs. These practices could be coasting consumers hundred of millions of dollars each year

Green Gasoline from Wood using Carbona Gasification and Topsoe TIGAS Process

Energy Technology Data Exchange (ETDEWEB)

Udengaard, Niels [Haldor Topsoe, Inc., Houston, TX (United States); Knight, Richard [Haldor Topsoe, Inc., Houston, TX (United States); Wendt, Jesper [Haldor Topsoe, Inc., Houston, TX (United States); Patel, Jim [Haldor Topsoe, Inc., Houston, TX (United States); Walston, Kip [Haldor Topsoe, Inc., Houston, TX (United States); Jokela, Pekka [Haldor Topsoe, Inc., Houston, TX (United States); Adams, Cheryl [Haldor Topsoe, Inc., Houston, TX (United States)

2015-02-19

This final report presents the results of a four-year technology demonstration project carried out by a consortium of companies sponsored in part by a $25 million funding by the Department of Energy (DOE) under the American Recovery and Reinvestment Act (ARRA). The purpose of the project was to demonstrate a new, economical technology for the thermochemical conversion of woody biomass into gasoline and to demonstrate that the gasoline produced in this way is suitable for direct inclusion in the already existing gasoline pool. The process that was demonstrated uses the Andritz-Carbona fluidized-bed steam-oxygen gasification technology and advanced tar reforming catalytic systems to produce a clean syngas from waste wood, integrated conventional gas cleanup steps, and finally utilizes Haldor Topsoe’s (Topsoe) innovative Topsoe Improved Gasoline Synthesis (TIGASTM) syngas-to-gasoline process. Gas Technology Institute (GTI) carried out the bulk of the testing work at their Flex Fuel development facility in Des Plaines, Illinois; UPM in Minnesota supplied and prepared the feedstocks, and characterization of liquid products was conducted in Phillips 66 labs in Oklahoma. The produced gasoline was used for a single-engine emission test at Southwest Research Institute (SwRI®) in San Antonio, TX, as well as in a fleet test at Transportation Research Center, Inc. (TRC Inc.) in East Liberty, Ohio. The project benefited from the use of existing pilot plant equipment at GTI, including a 21.6 bone dry short ton/day gasifier, tar reformer, Morphysorb® acid gas removal, associated syngas cleanup and gasifier feeding and oxygen systems.

The Effect of Using Ethanol-Gasoline Blends on the Mechanical, Energy and Environmental Performance of In-Use Vehicles

Directory of Open Access Journals (Sweden)

Juan E. Tibaquirá

2018-01-01

Full Text Available The use of ethanol in gasoline has become a worldwide tendency as an alternative to reduce net CO2 emissions to the atmosphere, increasing gasoline octane rating and reducing dependence on petroleum products. However, recently environmental authorities in large urban centers have expressed their concerns on the true effect of using ethanol blends of up to 20% v/v in in-use vehicles without any modification in the setup of the engine control unit (ECU, and on the variations of these effects along the years of operation of these vehicles. Their main concern is the potential increase in the emissions of volatile organic compounds with high ozone formation potential. To address these concerns, we developed analytical and experimental work testing engines under steady-conditions. We also tested carbureted and fuel-injected vehicles every 10,000 km during their first 100,000 km of operation. We measured the effect of using ethanol-gasoline blends on the power and torque generated, the fuel consumption and CO2, CO, NOx and unburned hydrocarbon emissions, including volatile organic compounds (VOCs such as acetaldehyde, formaldehyde, benzene and 1,3-butadiene which are considered important ozone precursors. The obtained results showed statistically no significant differences in these variables when vehicles operate with a blend of 20% v/v ethanol and 80% v/v gasoline (E20 instead of gasoline. Those results remained unchanged during the first 100,000 km of operation of the vehicles. We also observed that when the vehicles operated with E20 at high engine loads, they showed a tendency to operate with greater values of λ (ratio of the actual air-fuel ratio to the stoichiometric air-fuel ratio when compared to their operation with gasoline. According to the Eco-Indicator-99, these results represent a minor reduction (<1.3% on the impact to human health, and on the deterioration of the ecosystem. However, it implies a 12.9% deterioration of the natural

Gasoline marketing

International Nuclear Information System (INIS)

Metzenbaum, H.M.

1991-02-01

Consumers have the option of purchasing several different grades of unleaded gasoline regular, mid-grade, and premium which are classified according to an octane rating. Because of concern that consumers may be needlessly buying higher priced premium unleaded gasoline for their automobiles when regular unleaded gasoline would meet their needs, this paper determines whether consumers were buying premium gasoline that they may not need, whether the higher retail price of premium gasoline includes a price mark-up added between the refinery and the retail pump which is greater than that included in the retail price for regular gasoline, and possible reasons for the price differences between premium and regular gasoline

Attenuation of dissolved aromatic hydrocarbons from residual gasoline : source depletion and bioattenuation controls

Energy Technology Data Exchange (ETDEWEB)

Freitas, J.; Yang, T.; Barker, J. [Waterloo Univ., ON (Canada). Dept. of Earth and Environmental Sciences; Mocanu, M. [CH2M Hill Engineering Ltd., Santa Ana, CA (United States); Molson, J. [Ecole Polytechnique, Montreal, PQ (Canada). Dept. of Civil, Mining and Geological Engineering

2008-07-01

It has become commonplace to add ethanol to normal gasoline because this oxygenate has been touted to reduce greenhouse gas emissions, improve air quality and reduce dependence on non-renewable fossil fuels. It is advantageous from a groundwater quality perspective to substitute ethanol for soluble, toxic and mobile monoaromatics such as benzene, toluene, ethylbenzene and xylenes (BTEX). Ethanol poses minimal direct environmental risk, other than the high biological oxygen demand (BOD) imposed on receiving waters. This paper addressed the misconception that fermentation of ethanol to acetate or methane removes this BOD, thus eliminating ethanol as a competitor with BTEX for electron transfers. A study was conducted in which 50 litres each of normal gasoline and gasoline with 10 per cent ethanol (E10) were placed below the water table in a shallow sand aquifer at Canadian Forces Base (CFB) Borden. Two years of monitoring the downgradient plume revealed that the aromatic hydrocarbon were naturally attenuated. Although the rate of mass depletion in gasoline sources could not be predicted from the core analysis and simple interpretations, the biodegradation rate was well captured. It was concluded that the extent of bioattenuation exceeds that predicted by models considering electron acceptor (oxygen) availability. Ethanol was rapidly biotransformed in the Borden aquifer. It did not seem to impair the biotransformation of benzene when both were derived from E10 gasoline. The study revealed that for homogeneous sand aquifers such as Borden, the heterogeneity of sources will likely be a key cause of heterogeneous pollutant distribution in the downgradient plume. Ongoing research will focus on resolving the issue of insufficient oxygen to account for complete mineralization of ethanol and biotransformed aromatics. 14 refs., 1 tab., 7 figs.

Pollutant emissions from gasoline combustion. 1. Dependence on fuel structural functionalities.

Science.gov (United States)

Zhang, Hongzhi R; Eddings, Eric G; Sarofim, Adel F

2008-08-01

To study the formation of air pollutants and soot precursors (e.g., acetylene, 1,3-butadiene, benzene, and higher aromatics) from aliphatic and aromatic fractions of gasoline fuels, the Utah Surrogate Mechanisms is extended to include submechanisms of gasoline surrogate compounds using a set of mechanism generation techniques. The mechanism yields very good predictions of species concentrations in premixed flames of n-heptane, isooctane, benzene, cyclohexane, olefins, oxygenates, and gasoline using a 23-component surrogate formulation. The 1,3-butadiene emission comes mainly from minor fuel fractions of olefins and cyclohexane. The benzene formation potential of gasoline components shows the following trends as functions of (i) chemical class: n-paraffins produced by the real fuel should have priority when selecting candidate surrogate components for combustion simulations.

Biomass burning contribution to ambient volatile organic compounds (VOCs) in the Chengdu-Chongqing Region (CCR), China

Science.gov (United States)

Li, Lingyu; Chen, Yuan; Zeng, Limin; Shao, Min; Xie, Shaodong; Chen, Wentai; Lu, Sihua; Wu, Yusheng; Cao, Wei

2014-12-01

Ambient volatile organic compounds (VOCs) were measured intensively using an online gas chromatography-mass spectrometry/flame ionization detector (GC-MS/FID) at Ziyang in the Chengdu-Chongqing Region (CCR) from 6 December 2012 to 4 January 2013. Alkanes contributed the most (59%) to mixing ratios of measured non-methane hydrocarbons (NMHCs), while aromatics contributed the least (7%). Methanol was the most abundant oxygenated VOC (OVOC), contributing 42% to the total amount of OVOCs. Significantly elevated VOC levels occurred during three pollution events, but the chemical composition of VOCs did not differ between polluted and clean days. The OH loss rates of VOCs were calculated to estimate their chemical reactivity. Alkenes played a predominant role in VOC reactivity, among which ethylene and propene were the largest contributors; the contributions of formaldehyde and acetaldehyde were also considerable. Biomass burning had a significant influence on ambient VOCs during our study. We chose acetonitrile as a tracer and used enhancement ratio to estimate the contribution of biomass burning to ambient VOCs. Biomass burning contributed 9.4%-36.8% to the mixing ratios of selected VOC species, and contributed most (>30% each) to aromatics, formaldehyde, and acetaldehyde.

Measurement of VOC permeability of polymer bags and VOC solubility in polyethylene drum liner

International Nuclear Information System (INIS)

Liekhus, K.J.; Peterson, E.S.

1995-03-01

A test program conducted at the Idaho National Engineering Laboratory (INEL) investigated the use of a transport model to estimate the volatile organic compound (VOC) concentration in the void volume of a waste drum. Unsteady-state VOC transport model equations account for VOC permeation of polymer bags, VOC diffusion across openings in layers of confinement, and VOC solubility in a polyethylene drum liner. In support of this program, the VOC permeability of polymer bags and VOC equilibrium concentration in a polyethylene drum liner were measured for nine VOCs. The VOCs used in experiments were dichloromethane, carbon tetrachloride, cyclohexane, toluene, 1,1,1-trichloroethane, methanol, 1,1,2-trichloro-1,2,2-trifluoroethane (Freon-113), trichloroethylene, and p-xylene. The experimental results of these measurements as well as a method of estimating both parameters in the absence of experimental data are described in this report

Feedback controlled fuel injection system can accommodate any alcohol-gasoline blend

Energy Technology Data Exchange (ETDEWEB)

Pefley, R K; Pullman, J B; Suga, T P; Espinola, S

1980-01-01

A fuel metering system has been adapted and permits operation on all blends of alcohols and gasoline ranging from pure gasoline to pure ethanol and methanol. It is a closed loop electronic feedback controlled fuel injection system (EFI) with exhaust oxygen sensor. The system is used by Toyota Motor Company in their Supra and Cressida models in conjunction with a 3-way catalytic exhaust system. These models meet California exhaust and evaporative emission standards. An unmodified model has been tested on alcohol gasoline blends from pure gasoline to 50% ethanol-50% gasoline and 30% methanol-70% gasoline and found to meet all exhaust and evaporative emissions standards. A Cressida with modified EFI system is currently being tested. It is capable of operating on pure gasoline, pure methanol or ethanol and all intermediate blends. The testing to date shows that the vehicle meets all exhaust emissions standards while operating over the blend range from pure gasoline to pure ethanol while maintaining driveability and energy based fuel economy. The paper will present the total test evidence for all gasoline-alcohol blends. This will include exhaust and evaporative emissions, fuel economy and driveability as determined in accordance with United States Federal Test Procedures. Additionally, the paper will report experiences accumulated from road operation of the vehicle over a six-month period.

26 CFR 48.4081-4 - Gasoline; special rules for gasoline blendstocks.

Science.gov (United States)

2010-04-01

... 26 Internal Revenue 16 2010-04-01 2010-04-01 true Gasoline; special rules for gasoline blendstocks..., Tread Rubber, and Taxable Fuel Taxable Fuel § 48.4081-4 Gasoline; special rules for gasoline blendstocks... gasoline blendstocks. Generally, under prescribed conditions, tax is not imposed on gasoline blendstocks...

Verification of T2VOC using an analytical solution for VOC transport in vadose zone

Energy Technology Data Exchange (ETDEWEB)

Shan, C. [Lawrence Berkeley Laboratory, Berkeley, CA (United States)

1995-03-01

T2VOC represents an adaption of the STMVOC to the TOUGH2 environment. In may contaminated sites, transport of volatile organic chemicals (VOC) is a serious problem which can be simulated by T2VOC. To demonstrate the accuracy and robustness of the code, we chose a practical problem of VOC transport as the test case, conducted T2VOC simulations, and compared the results of T2VOC with those of an analytical solution. The agreements between T2VOC and the analytical solutions are excellent. In addition, the numerical results of T2VOC are less sensitive to grid size and time step to a certain extent.

Eddy covariance VOC emission and deposition fluxes above grassland using PTR-TOF

Directory of Open Access Journals (Sweden)

T. M. Ruuskanen

2011-01-01

Full Text Available Eddy covariance (EC is the preferable technique for flux measurements since it is the only direct flux determination method. It requires a continuum of high time resolution measurements (e.g. 5–20 Hz. For volatile organic compounds (VOC soft ionization via proton transfer reaction has proven to be a quantitative method for real time mass spectrometry; here we use a proton transfer reaction time of flight mass spectrometer (PTR-TOF for 10 Hz EC measurements of full mass spectra up to m/z 315. The mass resolution of the PTR-TOF enabled the identification of chemical formulas and separation of oxygenated and hydrocarbon species exhibiting the same nominal mass. We determined 481 ion mass peaks from ambient air concentration above a managed, temperate mountain grassland in Neustift, Stubai Valley, Austria. During harvesting we found significant fluxes of 18 compounds distributed over 43 ions, including protonated parent compounds, as well as their isotopes and fragments and VOC-H⁺ – water clusters. The dominant BVOC fluxes were methanol, acetaldehyde, ethanol, hexenal and other C₆ leaf wound compounds, acetone, acetic acid, monoterpenes and sequiterpenes.

The smallest reliable fluxes we determined were less than 0.1 nmol m⁻² s⁻¹, as in the case of sesquiterpene emissions from freshly cut grass. Terpenoids, including mono- and sesquiterpenes, were also deposited to the grassland before and after the harvesting. During cutting, total VOC emission fluxes up to 200 nmolC m⁻² s⁻¹ were measured. Methanol emissions accounted for half of the emissions of oxygenated VOCs and a third of the carbon of all measured VOC emissions during harvesting.

Temporal variability and sources of VOCs in urban areas of the eastern Mediterranean

Directory of Open Access Journals (Sweden)

C. Kaltsonoudis

2016-11-01

Full Text Available During the summer of 2012 volatile organic compounds (VOCs were monitored by proton transfer reaction mass spectrometry (PTR-MS in urban sites, in Athens and Patras, two of the largest cities in Greece. Also, during the winter of 2013, PTR-MS measurements were conducted in the center of the city of Athens. Positive matrix factorization (PMF was applied to the VOC measurements to gain insights about their sources. In summer most of the measured VOCs were due to biogenic and traffic emissions. Isoprene, monoterpenes, and several oxygenated VOCs (oVOCs originated mainly from vegetation either directly or as oxidation products. Isoprene average concentrations in Patras and Athens were 1 and 0.7 ppb respectively, while the monoterpene concentrations were 0.3 and 0.9 ppb respectively. Traffic was the main source of aromatic compounds during summer. For Patras and Athens the average concentrations of benzene were 0.1 and 0.2 ppb, of toluene 0.3 and 0.8 ppb, and of the xylenes 0.3 and 0.7 ppb respectively. Winter measurements in Athens revealed that biomass burning used for residential heating was a major VOC source contributing both aromatic VOCs and biogenic compounds such as monoterpenes. Several episodes related to biomass burning were identified and emission ratios (ERs and emission factors (EFs were estimated.

VOCs and OVOCs distribution and control policy implications in Pearl River Delta region, China

Science.gov (United States)

Louie, Peter K. K.; Ho, Josephine W. K.; Tsang, Roy C. W.; Blake, Donald R.; Lau, Alexis K. H.; Yu, Jian Zhen; Yuan, Zibing; Wang, Xinming; Shao, Min; Zhong, Liuju

2013-09-01

Ambient air measurements of volatile organic compounds (VOCs) and oxygenated volatile organic compounds (OVOCs) were conducted and characterised during a two-year grid study in the Pearl River Delta (PRD) region of southern China. The present grid study pioneered the systematic investigation of the nature and characteristics of complex VOC and OVOC sources at a regional scale. The largest contributing VOCs, accounting over 80% of the total VOCs mixing ratio, were toluene, ethane, ethyne, propane, ethene, butane, benzene, pentane, ethylbenzene, and xylenes. Sub-regional VOC spatial characteristics were identified, namely: i) relatively fresh pollutants, consistent with elevated vehicular and industrial activities, around the PRD estuary; and ii) a concentration gradient with higher mixing ratios of VOCs in the west as compared with the eastern part of PRD. Based on alkyl nitrate aging determination, a high hydroxyl radical (OH) concentration favoured fast hydrocarbon reactions and formation of locally produced ozone. The photochemical reactivity analysis showed aromatic hydrocarbons and alkenes together consisted of around 80% of the ozone formation potential (OFP) among the key VOCs. We also found that the OFP from OVOCs should not be neglected since their OFP contribution was more than one-third of that from VOCs alone. These findings support the choice of current air pollution control policy which focuses on vehicular sources but warrants further controls. Industrial emissions and VOCs emitted by solvents should be the next targets for ground-level ozone abatement.

Increasing the octane number of gasoline using functionalized carbon nanotubes

Energy Technology Data Exchange (ETDEWEB)

Kish, Sara Safari [Faculty of Chemistry, Islamic Azad University, North Tehran Branch, Tehran (Iran, Islamic Republic of); Rashidi, Alimorad, E-mail: rashidiam@ripi.ir [Nanotechnology Research Center, Research Institute of Petroleum Industry (RIPI), West Blvd. Azadi Sport Complex, Tehran 14665-1998 (Iran, Islamic Republic of); Aghabozorg, Hamid Reza [Catalysis Research Center, Research Institute of Petroleum Industry (RIPI), Tehran (Iran, Islamic Republic of); Moradi, Leila [Faculty of Chemistry, Kashan University, Kashan (Iran, Islamic Republic of)

2010-03-15

The octane number is one of the characteristics of spark-ignition fuels such as gasoline. Octane number of fuels can be improved by addition of oxygenates such as ethanol, MTBE (methyl tert-butyl ether), TBF (tertiary butyl formate) and TBA (tertiary butyl alcohol) as well as their blends with gasoline that reduce the cost impact of fuels. Carbon nanotubes (CNTs) are as useful additives for increasing the octane number. Functionalized carbon nanotubes containing amide groups have a high reactivity and can react with many chemicals. These compounds can be solubilized in gasoline to increase the octane number. In this study, using octadecylamine and dodecylamine, CNTs were amidated and the amino-functionalized carbon nanotubes were added to gasoline. Research octane number analysis showed that these additives increase octane number of the desired samples. X-ray diffraction (XRD), Fourier transforms infrared (FTIR), X-ray photoelectron spectroscopy (XPS), and thermal gravimetry analyses (TGA) were used for characterization of the prepared functionalized carbon nanotubes.

Increasing the octane number of gasoline using functionalized carbon nanotubes

International Nuclear Information System (INIS)

Kish, Sara Safari; Rashidi, Alimorad; Aghabozorg, Hamid Reza; Moradi, Leila

2010-01-01

The octane number is one of the characteristics of spark-ignition fuels such as gasoline. Octane number of fuels can be improved by addition of oxygenates such as ethanol, MTBE (methyl tert-butyl ether), TBF (tertiary butyl formate) and TBA (tertiary butyl alcohol) as well as their blends with gasoline that reduce the cost impact of fuels. Carbon nanotubes (CNTs) are as useful additives for increasing the octane number. Functionalized carbon nanotubes containing amide groups have a high reactivity and can react with many chemicals. These compounds can be solubilized in gasoline to increase the octane number. In this study, using octadecylamine and dodecylamine, CNTs were amidated and the amino-functionalized carbon nanotubes were added to gasoline. Research octane number analysis showed that these additives increase octane number of the desired samples. X-ray diffraction (XRD), Fourier transforms infrared (FTIR), X-ray photoelectron spectroscopy (XPS), and thermal gravimetry analyses (TGA) were used for characterization of the prepared functionalized carbon nanotubes.

Influence of solvent addition on the physicochemical properties of Brazilian gasoline

Energy Technology Data Exchange (ETDEWEB)

E.V. Takeshita; R.V.P. Rezende; S.M.A. Guelli; U. de Souza; A.A. Ulson de Souza [Federal University of Santa Catarina, Florianopolis (Brazil). Chemical Engineering Department

2008-08-15

The influence of several solvents (anhydrous ethanol, white spirit, alkylbenzene AB9, diesel) on the physicochemical parameters of gasoline was studied according to ASTM international standard methods. The parameters investigated (distillation curves, density, Reid vapor pressure) showed differentiated behavior, depending on the class of the solvent (oxygenated, light and heavy aliphatic, aromatic) and the quantity added to the gasoline. The azeotropic mixtures formed by ethanol and hydrocarbons showed a strong influence on the behavior of the distillation curves and the location of the point of a sudden change in temperature was shown to be a possible way to detect adulterations and determine the quantity of solvent added to the gasoline. 28 refs., 9 figs., 5 tabs.

Techno-economic Analysis for the Conversion of Lignocellulosic Biomass to Gasoline via the Methanol-to-Gasoline (MTG) Process

Energy Technology Data Exchange (ETDEWEB)

Jones, Susanne B.; Zhu, Yunhua

2009-05-01

Biomass is a renewable energy resource that can be converted into liquid fuel suitable for transportation applications. As a widely available biomass form, lignocellulosic biomass can have a major impact on domestic transportation fuel supplies and thus help meet the Energy Independence and Security Act renewable energy goals (U.S. Congress 2007). With gasification technology, biomass can be converted to gasoline via methanol synthesis and methanol-to-gasoline (MTG) technologies. Producing a gasoline product that is infrastructure ready has much potential. Although the MTG technology has been commercially demonstrated with natural gas conversion, combining MTG with biomass gasification has not been shown. Therefore, a techno-economic evaluation for a biomass MTG process based on currently available technology was developed to provide information about benefits and risks of this technology. The economic assumptions used in this report are consistent with previous U.S. Department of Energy Office of Biomass Programs techno-economic assessments. The feedstock is assumed to be wood chips at 2000 metric ton/day (dry basis). Two kinds of gasification technologies were evaluated: an indirectly-heated gasifier and a directly-heated oxygen-blown gasifier. The gasoline selling prices (2008 USD) excluding taxes were estimated to be $3.20/gallon and $3.68/gallon for indirectly-heated gasified and directly-heated. This suggests that a process based on existing technology is economic only when crude prices are above $100/bbl. However, improvements in syngas cleanup combined with consolidated gasoline synthesis can potentially reduce the capital cost. In addition, improved synthesis catalysts and reactor design may allow increased yield.

Electron beam destruction of contaminant gasoline additives in water

International Nuclear Information System (INIS)

Mezyk, S.P.; Jones, J.; Cooper, W.J.; O'Shea, K.E.; Fim, D.K.

2003-01-01

The U.S. phase-out of tetraethyl lead in the 1970's resulted in ever-increasing amounts of high-octane compounds, notably methyl tert-butyl ether (MTBE), being added to gasoline to give cleaner burning fuel. However, the 1990 Clean Air Act oxygenate requirements led refiners to more than double the amount of these chemicals being blended into gasoline, and this combination of large scale use, high water solubility, low soil adsorption, and only minor biodegradability under normal aquifer conditions has now resulted in large-scale MTBE contamination occurring in natural, ground, and drinking water systems. The remediation of gasoline oxygenate contaminated ground and drinking water remains a pressing environmental problem. Studies of MTBE-contaminated water have shown that conventional air stripping and carbon adsorption are not viable technologies. Therefore Advanced Oxidation (and Reduction) Processes (AOPs) are expected to be required for these remediations. These technologies are defined as those that use the hydroxyl radical (and hydrated electron) and include H 2 O 2 /UV, H 2 O 2 /Fe(II), H 2 O 2 /O 3 , TiO 2 /UV, sonolysis, and electron beam treatment of contaminated waters. The water decontamination of current and potential gasoline oxygenates (MTBE, ethyl tert-butyl ether (ETBE), tert-butyl alcohol (TBA), ethanol, and tert-amyl ether (TAME)) using free radicals produced by the electron beam irradiation AOP has been studied. Kinetic studies have been used to determine rate constants for the reaction of these ethers and alcohols with hydroxyl radicals, hydrated electrons and hydrogen atoms, and also the subsequent formation and decay of their corresponding peroxyl radicals. These kinetic data have been combined with mechanistic degradation and product distribution information to construct a computer kinetic model that can predict the removal of these contaminants under a variety of water conditions. This model was used to compare the predicted MTBE removal

Comparison of different real time VOC measurement techniques in a ponderosa pine forest

Directory of Open Access Journals (Sweden)

L. Kaser

2013-03-01

Full Text Available Volatile organic compound (VOC mixing ratios measured by five independent instruments are compared at a forested site dominated by ponderosa pine (Pinus Ponderosa during the BEACHON-ROCS field study in summer 2010. The instruments included a Proton Transfer Reaction Time of Flight Mass Spectrometer (PTR-TOF-MS, a Proton Transfer Reaction Quadrupole Mass Spectrometer (PTR-MS, a Fast Online Gas-Chromatograph coupled to a Mass Spectrometer (GC/MS; TOGA, a Thermal Dissociation Chemical Ionization Mass Spectrometer (PAN-CIMS and a Fiber Laser-Induced Fluorescence Instrument (FILIF. The species discussed in this comparison include the most important biogenic VOCs and a selected suite of oxygenated VOCs that are thought to dominate the VOC reactivity at this particular site as well as typical anthropogenic VOCs that showed low mixing ratios at this site. Good agreement was observed for methanol, the sum of the oxygenated hemiterpene 2-methyl-3-buten-2-ol (MBO and the hemiterpene isoprene, acetaldehyde, the sum of acetone and propanal, benzene and the sum of methyl ethyl ketone (MEK and butanal. Measurements of the above VOCs conducted by different instruments agree within 20%. The ability to differentiate the presence of toluene and cymene by PTR-TOF-MS is tested based on a comparison with GC-MS measurements, suggesting a study-average relative contribution of 74% for toluene and 26% for cymene. Similarly, 2-hydroxy-2-methylpropanal (HMPR is found to interfere with the sum of methyl vinyl ketone and methacrolein (MVK + MAC using PTR-(TOF-MS at this site. A study-average relative contribution of 85% for MVK + MAC and 15% for HMPR was determined. The sum of monoterpenes measured by PTR-MS and PTR-TOF-MS was generally 20–25% higher than the sum of speciated monoterpenes measured by TOGA, which included α-pinene, β-pinene, camphene, carene, myrcene, limonene, cineole as well as other terpenes. However, this difference is consistent throughout the study

High-molecular products analysis of VOC destruction in atmospheric pressure discharge

International Nuclear Information System (INIS)

Grossmannova, Hana; Ciganek, Miroslav; Krcma, Frantisek

2007-01-01

We investigate the issue of applicability of the solid phase microextraction (SPME) in the analysis of volatile organic compounds (VOCs) destruction products in the gliding arc discharge. Our research is focused on the measurements with the simple one stage gliding arc reactor, applied voltage was varied in the range of 3.5-4 kV. As a carrier gas, the dry air and its mixtures with nitrogen and oxygen, enriched by toluene, with flow rate of 1000-3500 ml/min was used. Total decomposition of toluene of 97 % was achieved at the oxygen content in carrier gas of 60 %. For measurements with air as a carrier gas, the highest efficiency was 95 %. We also tested the SPME technique suitability for the quantitative analysis of exhausts gases and if this technique can be used efficiently in the field to extract byproducts. Carbowax/divinylbenzene and Carboxen/polydimethylsiloxane/divinylbenzene fibres were chosen for sampling. Tens of various high-molecular substances were observed, especially a large number of oxygenous compounds and further several nitrogenous and C x H y compounds. The concentrations of various generated compounds strongly depend on the oxygen content in gas mixture composition. The results showed that the fiber coated by Carbowax/divinylbenzene can extract more products independently on the used VOC compound. The Carboxen/polydimethylsiloxane/divinylbenzene fiber is useful for the analysis of oxygenous compounds and its use will be recommended especially when the destruction is done in the oxygen rich atmosphere. With the higher ratio of oxygen in the carrier gas a distinctive decline of C x H y compounds amount have been observed. We also tried to describe the significant production of some compounds like benzyl alcohol, benzeneacetaldehyde, even in oxygen content is proximate 0 %. Experimental data demonstrated that it is necessary to use several SPME fibres for full-scale high-molecular products analysis

Impact of gasoline inhalation on some neurobehavioural characteristics of male rats

Science.gov (United States)

2009-01-01

Background This paper examines closely and compares the potential hazards of inhalation of two types of gasoline (car fuel). The first type is the commonly use leaded gasoline and the second is the unleaded type enriched with oxygenate additives as lead substituent in order to raise the octane number. The impacts of gasoline exposure on Na+, K+-ATPase, superoxide dismutase (SOD), acetylcholinesterase (AChE), total protein, reduced glutathione (GSH), and lipid peroxidation (TBARS) in the cerebral cortex, and monoamine neurotransmitters dopamine (DA), norepinephrine (NE) and serotonin (5-HT) in the cerebral cortex, hippocampus, cerebellum and hypothalamus were evaluated. The effect of gasoline exposure on the aggressive behaviour tests was also studied. Results The present results revealed that gasoline inhalation induced significant fluctuations in the levels of the monoamine neurotransmitters in the studied brain regions. This was concomitant with a decrease in Na+, K+-ATPase activity and total protein content. Moreover, the group exposed to the unleaded gasoline exhibited an increase in lipid peroxidation and a decrease in AChE and superoxide dismutase activities. These physiological impairments were accompanied with a higher tendency towards aggressive behaviour as a consequence to gasoline inhalation. Conclusion It is concluded from the present work that chronic exposure to either the leaded or the unleaded gasoline vapours impaired the levels of monoamine neurotransmitters and other biochemical parameters in different brain areas and modulated several behavioural aspects related to aggression in rats. PMID:19930677

Impact of gasoline inhalation on some neurobehavioural characteristics of male rats.

Science.gov (United States)

Kinawy, Amal A

2009-11-24

This paper examines closely and compares the potential hazards of inhalation of two types of gasoline (car fuel). The first type is the commonly use leaded gasoline and the second is the unleaded type enriched with oxygenate additives as lead substituent in order to raise the octane number. The impacts of gasoline exposure on Na+, K+-ATPase, superoxide dismutase (SOD), acetylcholinesterase (AChE), total protein, reduced glutathione (GSH), and lipid peroxidation (TBARS) in the cerebral cortex, and monoamine neurotransmitters dopamine (DA), norepinephrine (NE) and serotonin (5-HT) in the cerebral cortex, hippocampus, cerebellum and hypothalamus were evaluated. The effect of gasoline exposure on the aggressive behaviour tests was also studied. The present results revealed that gasoline inhalation induced significant fluctuations in the levels of the monoamine neurotransmitters in the studied brain regions. This was concomitant with a decrease in Na+, K+-ATPase activity and total protein content. Moreover, the group exposed to the unleaded gasoline exhibited an increase in lipid peroxidation and a decrease in AChE and superoxide dismutase activities. These physiological impairments were accompanied with a higher tendency towards aggressive behaviour as a consequence to gasoline inhalation. It is concluded from the present work that chronic exposure to either the leaded or the unleaded gasoline vapours impaired the levels of monoamine neurotransmitters and other biochemical parameters in different brain areas and modulated several behavioural aspects related to aggression in rats.

Impact of gasoline inhalation on some neurobehavioural characteristics of male rats

Directory of Open Access Journals (Sweden)

Kinawy Amal A

2009-11-01

Full Text Available Abstract Background This paper examines closely and compares the potential hazards of inhalation of two types of gasoline (car fuel. The first type is the commonly use leaded gasoline and the second is the unleaded type enriched with oxygenate additives as lead substituent in order to raise the octane number. The impacts of gasoline exposure on Na+, K+-ATPase, superoxide dismutase (SOD, acetylcholinesterase (AChE, total protein, reduced glutathione (GSH, and lipid peroxidation (TBARS in the cerebral cortex, and monoamine neurotransmitters dopamine (DA, norepinephrine (NE and serotonin (5-HT in the cerebral cortex, hippocampus, cerebellum and hypothalamus were evaluated. The effect of gasoline exposure on the aggressive behaviour tests was also studied. Results The present results revealed that gasoline inhalation induced significant fluctuations in the levels of the monoamine neurotransmitters in the studied brain regions. This was concomitant with a decrease in Na+, K+-ATPase activity and total protein content. Moreover, the group exposed to the unleaded gasoline exhibited an increase in lipid peroxidation and a decrease in AChE and superoxide dismutase activities. These physiological impairments were accompanied with a higher tendency towards aggressive behaviour as a consequence to gasoline inhalation. Conclusion It is concluded from the present work that chronic exposure to either the leaded or the unleaded gasoline vapours impaired the levels of monoamine neurotransmitters and other biochemical parameters in different brain areas and modulated several behavioural aspects related to aggression in rats.

Short-term inhalation toxicity of methanol, gasoline, and methanol/gasoline in the rat.

Science.gov (United States)

Poon, R; Chu, I; Bjarnason, S; Vincent, R; Potvin, M; Miller, R B; Valli, V E

1995-01-01

Four- to five-week-old male and female Sprague Dawley rats were exposed to vapors of methanol (2500 ppm), gasoline (3200 ppm), and methanol/gasoline (2500/3200 ppm, 570/3200 ppm) six hours per day, five days per week for four weeks. Control animals were exposed to filtered room air only. Depression in body weight gain and reduced food consumption were observed in male rats, and increased relative liver weight was detected in rats of both sexes exposed to gasoline or methanol/gasoline mixtures. Rats of both sexes exposed to methanol/gasoline mixtures had increased relative kidney weight and females exposed to gasoline and methanol/gasoline mixtures had increased kidney weight. Decreased serum glucose and cholesterol were detected in male rats exposed to gasoline and methanol/gasoline mixtures. Decreased hemoglobin was observed in females inhaling vapors of gasoline and methanol/gasoline at 570/3200 ppm. Urine from rats inhaling gasoline or methanol/gasoline mixtures had up to a fourfold increase in hippuric acid, a biomarker of exposure to the toluene constituent of gasoline, and up to a sixfold elevation in ascorbic acid, a noninvasive biomarker of hepatic response. Hepatic mixed-function oxidase (aniline hydroxylase, aminopyrine N-demethylase and ethoxyresorufin O-deethylase) activities and UDP-glucuronosyltransferase activity were elevated in rats exposed to gasoline and methanol/gasoline mixtures. Histopathological changes were confined to very mild changes in the nasal passages and in the uterus, where decreased incidence or absence of mucosal and myometrial eosinophilia was observed in females inhaling gasoline and methanol/gasoline at 570/3200 ppm. It was concluded that gasoline was largely responsible for the adverse effects, the most significant of which included depression in weight gain in the males, increased liver weight and hepatic microsomal enzyme activities in both sexes, and suppression of uterine eosinophilia. No apparent interactive effects

Reporting a sudden death due to accidental gasoline inhalation.

Science.gov (United States)

Martínez, María Antonia; Ballesteros, Salomé; Alcaraz, Rafael

2012-02-10

The investigation of uncertain fatalities requires accurate determination of the cause of death, with assessment of all factors that may have contributed to it. Gasoline is a complex and highly variable mixture of aliphatic and aromatic hydrocarbons that can lead to cardiac arrhythmias due to sensitization of the myocardium to catecholamines or acts as a simple asphyxiant if the vapors displace sufficient oxygen from the breathing atmosphere. This work describes a sudden occupational fatality involving gasoline. The importance of this petroleum distillate detection and its quantitative toxicological significance is discussed using a validated analytical method. A 51 year-old Caucasian healthy man without significant medical history was supervising the repairs of the telephone lines in a manhole near to a gas station. He died suddenly after inhaling gasoline vapors from an accidental leak. Extensive blistering and peeling of skin were observed on the skin of the face, neck, anterior chest, upper and lower extremities, and back. The internal examination showed a strong odor of gasoline, specially detected in the respiratory tract. The toxicological screening and quantitation of gasoline was performed by means of gas chromatography with flame ionization detector and confirmation was performed using gas chromatography-mass spectrometry. Disposition of gasoline in different tissues was as follows: heart blood, 35.7 mg/L; urine, not detected; vitreous humor, 1.9 mg/L; liver, 194.7 mg/kg; lung, 147.6 mg/kg; and gastric content, 116,6 mg/L (2.7 mg total). Based upon the toxicological data along with the autopsy findings, the cause of death was determined to be gasoline poisoning and the manner of death was accidental. We would like to alert on the importance of testing for gasoline, and in general for volatile hydrocarbons, in work-related sudden deaths involving inhalation of hydrocarbon vapors and/or exhaust fumes. Copyright © 2011 Elsevier Ireland Ltd. All rights

Experimental study on emissions and performance of an internal combustion engine fueled with gasoline and gasoline/n-butanol blends

International Nuclear Information System (INIS)

Elfasakhany, Ashraf

2014-01-01

Highlights: • Using of 3 and 7 vol.% n-butanol blends in SI engine is studied for the first time. • Engine performance and emissions depend on both engine speed and blend rates. • CO and UHC for blended fuels are maximum at 3000–3100 r/min. • The higher the rate of n-butanol, the lower the emissions and performance. • This study strongly supports using low blend rates of n-butanol (<10 vol.%) in ICE. - Abstract: In this paper, exhaust emissions and engine performance have been experimentally studied for neat gasoline and gasoline/n-butanol blends in a wide range of working speeds (2600–3400 r/min) without any tuning or modification on the gasoline engine systems. The experiment has the ability of evaluating performance and emission characteristics, such as break power, torque, in-cylinder pressure, volumetric efficiency, exhaust gas temperature and concentrations of CO 2 , CO and UHC. Results of the engine test indicated that using n-butanol–gasoline blended fuels slightly decrease the output torque, power, volumetric efficiency, exhaust gas temperature and in-cylinder pressure of the engine as a result of the leaning effect caused by the n-butanol addition; CO, CO 2 and UHC emissions decrease dramatically for blended fuels compared to neat gasoline because of the improved combustion since n-butanol has extra oxygen, which allows partial reduction of the CO and UHC through formation of CO 2 . It was also noted that the exhaust emissions depend on the engine speed rather than the n-butanol contents

Toxicity assessment of volatile organic compounds and polycyclic aromatic hydrocarbons in motorcycle exhaust.

Science.gov (United States)

Chang, Chang-Tang; Chen, Bor-Yann

2008-05-30

This study investigates the toxicity of various pollutant species from motorcycle exhaust via dose-response analysis and margin of safety using Escherichia coli DH5 alpha. The toxicity evaluation of the major components of motorcycle exhaust volatile organic compounds (VOCs), collected with impinger, and polycyclic aromatic hydrocarbons (PAHs), collected with filter and XAD-2, is essential to determine emission standards for motorcycles. The toxicity of benzene (B), toluene (T), ethyl benzene (E) and xylene (X) was selected for comparison as standard VOCs emitted from motorcycles. In addition, three types of reformulated gasoline (high oxygenate and high benzene content (No. 1), low oxygen and high benzene (No. 2), and low oxygen and low benzene (No. 3) were prepared to reveal combined toxicity of individual compositions. Motorcycle exhaust is significantly more toxic than BTEX due to the highly toxic VOCs generated from incomplete combustion. Overall toxicity evaluation showed that the toxicity, indicated as EC50, was approximately as follows: PAHs>two-stroke engines>four-stroke engines>BTEX.

Toxicity assessment of volatile organic compounds and polycyclic aromatic hydrocarbons in motorcycle exhaust

International Nuclear Information System (INIS)

Chang, C.-T.; Chen, B.-Y.

2008-01-01

This study investigates the toxicity of various pollutant species from motorcycle exhaust via dose-response analysis and margin of safety using Escherichia coli DH5α. The toxicity evaluation of the major components of motorcycle exhaust volatile organic compounds (VOCs), collected with impinger, and polycyclic aromatic hydrocarbons (PAHs), collected with filter and XAD-2, is essential to determine emission standards for motorcycles. The toxicity of benzene (B), toluene (T), ethyl benzene (E) and xylene (X) was selected for comparison as standard VOCs emitted from motorcycles. In addition, three types of reformulated gasoline (high oxygenate and high benzene content (No. 1), low oxygen and high benzene (No. 2), and low oxygen and low benzene (No. 3) were prepared to reveal combined toxicity of individual compositions. Motorcycle exhaust is significantly more toxic than BTEX due to the highly toxic VOCs generated from incomplete combustion. Overall toxicity evaluation showed that the toxicity, indicated as EC 50 , was approximately as follows: PAHs > two-stroke engines > four-stroke engines > BTEX

Emission inventory of anthropogenic air pollutants and VOC species in the Yangtze River Delta region, China

Directory of Open Access Journals (Sweden)

C. Huang

2011-05-01

Full Text Available The purpose of this study is to develop an emission inventory for major anthropogenic air pollutants and VOC species in the Yangtze River Delta (YRD region for the year 2007. A "bottom-up" methodology was adopted to compile the inventory based on major emission sources in the sixteen cities of this region. Results show that the emissions of SO₂, NO_x, CO, PM₁₀, PM_2.5, VOCs, and NH₃ in the YRD region for the year 2007 are 2392 kt, 2293 kt, 6697 kt, 3116 kt, 1511 kt, 2767 kt, and 459 kt, respectively. Ethylene, mp-xylene, o-xylene, toluene, 1,2,4-trimethylbenzene, 2,4-dimethylpentane, ethyl benzene, propylene, 1-pentene, and isoprene are the key species contributing 77 % to the total ozone formation potential (OFP. The spatial distribution of the emissions shows the emissions and OFPs are mainly concentrated in the urban and industrial areas along the Yangtze River and around Hangzhou Bay. The industrial sources, including power plants other fuel combustion facilities, and non-combustion processes contribute about 97 %, 86 %, 89 %, 91 %, and 69 % of the total SO₂, NO_x, PM₁₀, PM_2.5, and VOC emissions. Vehicles take up 12.3 % and 12.4 % of the NO_x and VOC emissions, respectively. Regarding OFPs, the chemical industry, domestic use of paint & printing, and gasoline vehicles contribute 38 %, 24 %, and 12 % to the ozone formation in the YRD region.

VOC emissions from residential combustion of Southern and mid-European woods

Science.gov (United States)

Evtyugina, Margarita; Alves, Célia; Calvo, Ana; Nunes, Teresa; Tarelho, Luís; Duarte, Márcio; Prozil, Sónia O.; Evtuguin, Dmitry V.; Pio, Casimiro

2014-02-01

Emissions of trace gases (carbon dioxide (CO2), carbon monoxide (CO), total hydrocarbons (THC)), and volatile organic compounds (VOCs) from combustion of European beech, Pyrenean oak and black poplar in a domestic woodstove and fireplace were studied. These woods are widely used as biofuel in residential combustion in Southern and mid-European countries. VOCs in the flue gases were collected in Tedlar bags, concentrated in sorbent tubes and analysed by thermal desorption-gas chromatography-flame ionisation detection (GC-FID). CO2 emissions ranged from 1415 ± 136 to 1879 ± 29 g kg-1 (dry basis). The highest emission factors for CO and THC, 115.8 ± 11.7 and 95.6 24.7 ± 6.3 g kg-1 (dry basis), respectively, were obtained during the combustion of black poplar in the fireplace. European beech presented the lowest CO and THC emission factors for both burning appliances. Significant differences in emissions of VOCs were observed among wood species burnt and combustion devices. In general the highest emission factors were obtained from the combustion of Pyrenean oak in the woodstove. Among the VOCs identified, benzene and related compounds were always the most abundant group, followed by oxygenated compounds and aliphatic hydrocarbons. The amount and the composition of emitted VOCs were strongly affected by the wood composition, the type of burning device and operating conditions. Emission data obtained in this work are useful for modelling the impact of residential wood combustion on air quality and tropospheric ozone formation.

Biofiltration of gasoline and ethanol-amended gasoline vapors.

Science.gov (United States)

Soares, Marlene; Woiciechowski, Adenise L; Kozliak, Evguenii I; Paca, Jan; Soccol, Carlos R

2012-01-01

Assuming the projected increase in use of ethanol as a biofuel, the current study was conducted to compare the biofiltration efficiencies for plain and 25% ethanol-containing gasoline. Two biofilters were operated in a downflow mode for 7 months, one of them being compost-based whereas the other using a synthetic packing material, granulated tire rubber, inoculated with gasoline-degrading microorganisms. Inlet concentrations measured as total hydrocarbon (TH) ranged from 1.9 to 5.8 g m(-3) at a constant empty bed retention time of 6.84 min. Contrary to the expectations based on microbiological considerations, ethanol-amended gasoline was more readily biodegraded than plain hydrocarbons, with the respective steady state elimination capacities of 26-43 and 14-18 gTH m(-3) h(-1) for the compost biofilter. The efficiency of both biofilters significantly declined upon the application of higher loads of plain gasoline, yet immediately recovering when switched back to ethanol-blended gasoline. The unexpected effect of ethanol in promoting gasoline biodegradation was explained by increasing hydrocarbon partitioning into the aqueous phase, with mass transfer being rate limiting for the bulk of components. The tire rubber biofilter, after a long acclimation, surpassed the compost biofilter in performance, presumably due to the 'buffering' effect of this packing material increasing the accessibility of gasoline hydrocarbons to the biofilm. With improved substrate mass transfer, biodegradable hydrocarbons were removed in the tire rubber biofilter's first reactor stage, with most of the remaining poorly degradable smaller-size hydrocarbons being degraded in the second stage.

Recovery of gasoline

Energy Technology Data Exchange (ETDEWEB)

1937-02-27

The abstract describes a process for recovering a maximum quantity of commercial gasoline from a composite hydrocarbon stream containing hydrocarbons within and below the gasoline boiling range, including olefins. The hydrocarbon stream is separated into low vapor pressure gasoline and a gas fraction consisting of hydrocarbons of the 4 carbon atom group and some of the 3 carbon atom group. The gas fraction is subjected to a polymerization operation, characterized by utilizing the products of the polymerization procedure - both liquid polymers and unconverted gases - to increase the yield of gasoline and to adjust the low vapor pressure gasoline to the vapor pressure of commercial gasoline. A fraction of the gaseous products of the polymerization procedure are used for this purpose. The remainder of the gaseous products are recycled through the polymerization operation.

INVESTIGATION OF COMBUSTION, PERFORMANCE AND EMISSION CHARACTERISTICS OF SPARK IGNITION ENGINE FUELLED WITH BUTHANOL – GASOLINE MIXTURE AND A HYDROGEN ENRICHED AIR

OpenAIRE

Alfredas Rimkus; Mindaugas Melaika; Jonas Matijošius; Šarūnas Mikaliūnas; Saugirdas Pukalskas

2016-01-01

In this study, spark ignition engine fuelled with buthanol-gasoline mixture and a hydrogen-enriched air was investigated. Engine performance, emissions and combustion characteristics were investigated with different buthanol (10% and 20% by volume) gasoline mixtures and additionally supplied oxygen and hydrogen (HHO) gas mixture (3.6 l/min) in the sucked air. Hydrogen, which is in the HHO gas, improves gasoline and gasoline-buthanol mixture combustion, increases indicated pressure during comb...

Emissions and photochemistry of oxygenated VOCs in urban plumes in the Northeastern United States

Directory of Open Access Journals (Sweden)

R. Sommariva

2011-07-01

Full Text Available Photochemical processes inside urban plumes in the Northeast of the United States have been studied using a highly detailed chemical model, based upon the Master Chemical Mechanism (MCM. The model results have been compared to measurements of oxygenated VOCs (acetone, methyl ethyl ketone, acetaldehyde, acetic acid and methanol obtained during several flights of the NOAA WP-3D aircraft, which sampled plumes from the New York City area during the ICARTT campaign in 2004. The agreement between the model and the measurements was within 40–60 % for all species, except acetic acid.

The model results have been used to study the formation and photochemical evolution of acetone, methyl ethyl ketone and acetaldehyde. Under the conditions encountered during the ICARTT campaign, acetone is produced from the oxidation of propane (24–28 % and i-propanol (<15 % and from a number of products of i-pentane oxidation. Methyl ethyl ketone (MEK is mostly produced from the oxidation of n-butane (20–30 % and 3-methylpentane (<40 %. Acetaldehyde is formed from several precursors, mostly small alkenes, >C5 alkanes, propanal and MEK. Ethane and ethanol oxidation account, respectively, for 6–23 % and 5–25 % of acetaldehyde photochemical formation. The results highlight the importance of alkanes for the photochemical production of ketones and the role of hydroperoxides in sustaining their formation far from the emission sources.

Gasoline sniffing multifocal neuropathy.

Science.gov (United States)

Burns, T M; Shneker, B F; Juel, V C

2001-11-01

The polyneuropathy caused by chronic gasoline inhalation is reported to be a gradually progressive, symmetric, sensorimotor polyneuropathy. We report unleaded gasoline sniffing by a female 14 years of age that precipitated peripheral neuropathy. In contrast with the previously reported presentation of peripheral neuropathy in gasoline inhalation, our patient developed multiple mononeuropathies superimposed on a background of sensorimotor polyneuropathy. The patient illustrates that gasoline sniffing neuropathy may present with acute multiple mononeuropathies resembling mononeuritis multiplex, possibly related to increased peripheral nerve susceptibility to pressure in the setting of neurotoxic components of gasoline. The presence of tetraethyl lead, which is no longer present in modern gasoline mixtures, is apparently not a necessary factor in the development of gasoline sniffer's neuropathy.

Gasoline from coal in the state of Illinois: feasibility study. Volume I. Design. [KBW gasification process, ICI low-pressure methanol process and Mobil M-gasoline process

Energy Technology Data Exchange (ETDEWEB)

1980-01-01

Volume 1 describes the proposed plant: KBW gasification process, ICI low-pressure methanol process and Mobil M-gasoline process, and also with ancillary processes, such as oxygen plant, shift process, RECTISOL purification process, sulfur recovery equipment and pollution control equipment. Numerous engineering diagrams are included. (LTN)

Modeling VOC transport in simulated waste drums

International Nuclear Information System (INIS)

Liekhus, K.J.; Gresham, G.L.; Peterson, E.S.; Rae, C.; Hotz, N.J.; Connolly, M.J.

1993-06-01

A volatile organic compound (VOC) transport model has been developed to describe unsteady-state VOC permeation and diffusion within a waste drum. Model equations account for three primary mechanisms for VOC transport from a void volume within the drum. These mechanisms are VOC permeation across a polymer boundary, VOC diffusion across an opening in a volume boundary, and VOC solubilization in a polymer boundary. A series of lab-scale experiments was performed in which the VOC concentration was measured in simulated waste drums under different conditions. A lab-scale simulated waste drum consisted of a sized-down 55-gal metal drum containing a modified rigid polyethylene drum liner. Four polyethylene bags were sealed inside a large polyethylene bag, supported by a wire cage, and placed inside the drum liner. The small bags were filled with VOC-air gas mixture and the VOC concentration was measured throughout the drum over a period of time. Test variables included the type of VOC-air gas mixtures introduced into the small bags, the small bag closure type, and the presence or absence of a variable external heat source. Model results were calculated for those trials where the VOC permeability had been measured. Permeabilities for five VOCs [methylene chloride, 1,1,2-trichloro-1,2,2-trifluoroethane (Freon-113), 1,1,1-trichloroethane, carbon tetrachloride, and trichloroethylene] were measured across a polyethylene bag. Comparison of model and experimental results of VOC concentration as a function of time indicate that model accurately accounts for significant VOC transport mechanisms in a lab-scale waste drum

Gasoline poisoning

Science.gov (United States)

... this page: //medlineplus.gov/ency/article/002806.htm Gasoline poisoning To use the sharing features on this ... This article discusses the harmful effects from swallowing gasoline or breathing in its fumes. This article is ...

Formation of secondary aerosols from gasoline vehicle exhaust when mixing with SO2

Directory of Open Access Journals (Sweden)

T. Liu

2016-01-01

Full Text Available Sulfur dioxide (SO2 can enhance the formation of secondary aerosols from biogenic volatile organic compounds (VOCs, but its influence on secondary aerosol formation from anthropogenic VOCs, particularly complex mixtures like vehicle exhaust, remains uncertain. Gasoline vehicle exhaust (GVE and SO2, a typical pollutant from coal burning, are directly co-introduced into a smog chamber, in this study, to investigate the formation of secondary organic aerosols (SOA and sulfate aerosols through photooxidation. New particle formation was enhanced, while substantial sulfate was formed through the oxidation of SO2 in the presence of high concentration of SO2. Homogenous oxidation by OH radicals contributed a negligible fraction to the conversion of SO2 to sulfate, and instead the oxidation by stabilized Criegee intermediates (sCIs, formed from alkenes in the exhaust reacting with ozone, dominated the conversion of SO2. After 5 h of photochemical aging, GVE's SOA production factor revealed an increase by 60–200 % in the presence of high concentration of SO2. The increase could principally be attributed to acid-catalyzed SOA formation as evidenced by the strong positive linear correlation (R2 = 0.97 between the SOA production factor and in situ particle acidity calculated by the AIM-II model. A high-resolution time-of-flight aerosol mass spectrometer (HR-TOF-AMS resolved OA's relatively lower oxygen-to-carbon (O : C (0.44 ± 0.02 and higher hydrogen-to-carbon (H : C (1.40 ± 0.03 molar ratios for the GVE / SO2 mixture, with a significantly lower estimated average carbon oxidation state (OSc of −0.51 ± 0.06 than −0.19 ± 0.08 for GVE alone. The relative higher mass loading of OA in the experiments with SO2 might be a significant explanation for the lower SOA oxidation degree.

Alcohols and ethers improve the gasoline; Alcoois e eteres melhoram a gasolina

Energy Technology Data Exchange (ETDEWEB)

Polati, Eduardo Sala

1996-04-01

This article presents the technical characteristics of the main oxygenated compounds, the way of production, and the performance results in the vehicle engines. The obtained information provide subsides for the debates on the use of ethanol and the MTBE additions to the gasoline.

VOC emission into the atmosphere by trees and leaf litter in Polish forests

Science.gov (United States)

Isidorov, V.; Smolewska, M.; Tyszkiewicz, Z.

2009-04-01

It is generally recognized at present that the vegetation of continents is the principal source of reactive volatile organic compounds (VOC) of the atmosphere. The upper limit of the evaluation of global phytogenic VOC is 1100-1500 Tg/yr (Isidorov, 1990; Guenther et al., 1995). Although these global evaluations showing the place of phytogenic emission among of other VOC sources are important, evaluations for individual countries are also very important. This poster represents the results of the estimation of VOC emission from Polish forests. Calculations took into account the composition and age of forests. According to our estimation, the total VOC emission by the arboreal vegetation differs from 190 to 750 kt/yr, depending of weather conditions in different years. There are only few studies conducted on decaying plant material as a source of atmospheric VOCs, but still they are able to give evidence of the importance of this source. For Polish forests, the litter mass is estimated to be (16-19)106 t/yr. These organic materials undergo decomposition by mesofauna and microorganisms. In these processes volatile organic compounds (VOC) stored in the litter and secondary metabolites of litter-destroying fungi are emitted into the atmosphere. The scale of the phenomenon makes leaf litter an important VOC source in the atmosphere. The filling of numerous gaps in researches of VOC emissions from decomposing leaf litter demands carrying out of long term field experiments in various climatic conditions. In this communication we report also the results of 3.5-year experiment on qualitative and quantitative GC-MS investigations of VOC emitted into the gas phase from leaves litter of some species of deciduous and coniferous trees of Polish forests. Apart from terpenes and their oxygenated derivatives, which are usual in plant tissues, leaf litter intensively emits vast amounts of lower alcohols and carbonyl compounds. We suppose that these volatile substances are products

Concentrations and flux measurements of volatile organic compounds (VOC) in boreal forest soil

Science.gov (United States)

Mäki, Mari; Aaltonen, Hermanni; Heinonsalo, Jussi; Hellén, Heidi; Pumpanen, Jukka; Bäck, Jaana

2017-04-01

Volatile organic compounds (VOC) impact soil processes as VOCs transmit signals between roots and rhizosphere (Ditengou et al., 2015), VOCs can regulate microbial activity (Asensio et al., 2012), and VOCs can also promote root growth (Hung et al., 2012). Belowground concentrations of VOCs have not been measured in situ and for this reason, knowledge of how different soil organisms such as roots, rhizosphere and decomposers contribute to VOC production is limited. The aim of this study was to determine and quantify VOC fluxes and concentrations of different horizons from boreal forest soil. The VOC concentrations and fluxes were measured from Scots pine (Pinus sylvestris) forest soil at the SMEAR II station in southern Finland from 21th of April to 2nd of December in 2016. VOC fluxes were measured using dynamic (flow-through) chambers from five soil collars placed on five different locations. VOC concentrations were also measured in each location from four different soil horizons with the measurement depth 1-107 cm. VOCs were collected from underground gas collectors into the Tenax-Carbopack-B adsorbent tubes using portable pumps ( 100 ml min-1). The VOC concentrations and fluxes of isoprene, 11 monoterpenes, 13 sesquiterpenes and different oxygenated VOCs were measured. Sample tubes were analyzed using thermal desorption-gas chromatograph-mass spectrometry (TD-GC-MS). Soil temperature and soil water content were continuously monitored for each soil horizon. Our preliminary results show that the primary source of VOCs is organic soil layer and the contribution of mineral soil to the VOC formation is minor. VOC fluxes and concentrations were dominated by monoterpenes such as α-pinene, camphene, β-pinene, and Δ3-carene. Monoterpene concentration is almost 10-fold in organic soil compared to the deeper soil layers. However, the highest VOC fluxes on the soil surface were measured in October, whereas the monoterpene concentrations in organic soil were highest in July

Gasoline reformulation to reduce exhaust emissions in Finnish conditions. Influence of sulphur and benzene contents of gasoline on exhaust emissions

International Nuclear Information System (INIS)

Kytoe, M.; Aakko, P.; Lappi, M.

1994-01-01

At earlier stages of the study it was found that the exhaust emissions from cars are reduced when using fuels with no more than 4 wt% of oxygen. At this stage of the study the work focused on impacts of the sulphur and benzene content of gasoline on exhaust emissions in Finland. Sulphur in gasoline retards the operation of the catalyst, and consequently the exhaust emissions of catalyst cars increase if the sulphur content of the fuel increases. In the present study, evaporation during refuelling were measured for fuels with varying vapour pressures and benzene contents of gasoline. The total hydrocarbon evaporation was reduced by 22 % (10 g) when the vapour pressure of gasoline was reduced from 85 kPa to 65 kPa. Correspondingly, benzene evaporation during refuelling was reduced to a third when the benzene content of the fuel was reduced from the level of 3 wt% to 1 wt%. The reduction of the sulphur content of gasoline from 500 ppm to 100 ppm affected regulated exhaust emissions from the catalyst car at +22 deg C as follows: CO emission was reduced on average by 14 % (0.175 g/km), CH emission by 7 % (0.010 g/km) and NO x emission by 9 % (0.011 g/km). At-7 deg C the percentual changes were smaller. When the benzene content of the fuel was reduced from 3 wt% to 1 wt%, the benzene emission from the catalyst cars was reduced by 20-30 % and from the non-catalyst cars on average by 30 % both at +22 deg C and -7 deg C. The benzene emission ranged 3-22 mg/km for the catalyst cars and 40-90 mg/km for the non-catalyst cars at +22 deg C in the FTP test

Stable carbon isotopic composition of gasolines determined by isotope ratio monitoring gas chromatography mass spectrometry

Energy Technology Data Exchange (ETDEWEB)

Smallwood, B.J.; Philp, R.P.; Allen, J.D. [University of Oklahoma, Norman, OK (United States). School of Geology and Geophysics

2002-07-01

A large number of underground gasoline storage facilities in the United States continuously leak gasoline into the subsurface, which makes gasoline a major groundwater contaminant. Gas chromatography (GC) and gas chromatography-mass spectrometry (GC-MS) are used currently to characterize contaminated groundwater and soils. Correlations of contaminants with suspected source(s) are extremely difficult by these techniques because many gasolines have similar hydrocarbon distributions. The present study applied the technique of isotope ratio monitoring gas chromatography-mass spectrometry (irmGC-MS) to 19 gasoline samples from different areas of the USA. This allows a much better correlation of gasoline contaminants to source. Data obtained indicate a wide range of {sup {delta}}{sup 13}C values for 16 ubiquitous compounds in the gasolines. The majority of samples could be distinguished from each other on the basis of {sup {delta}}{sup 13}C hydrocarbon composition. The oxygenated additive methyl tertiary butyl ether (MTBE) was present in ten of the gasolines analyzed, and had a relatively narrow range of {sup {delta}}{sup 13}C values (-30.4 to -28.3 per mille). Preliminary investigations were also made to determine the extent of carbon isotopic fractionation after simple water washing and evaporation experiments. Results indicate that the majority of compounds did not undergo significant carbon isotopic fractionation as a result of these processes. (author)

ANAEROBIC DEGRADATION OF MTBE TO TBA IN GROUND WATER AT GASOLINE SPILL SITES IN ORANGE COUNTY, CALIFORNIA

Science.gov (United States)

Although tert-Butyl Alcohol (TBA) has not been used as a fuel oxygenate in Orange County, California, the concentrations of TBA in ground water at gasoline spill sites are high compared to the concentrations of the conventional fuel oxygenate Methyl tert-Butyl Ether (MTBE). In t...

Innovative approaches to remediation for VOC sites using recirculating wells

International Nuclear Information System (INIS)

Dawson, G.W.

1996-01-01

In-well air stripping with approaches such as the patented NoVOCs system offer both cost and operational advantages over pump and treat, and in situ air sparging technologies. With in-well stripping, the water is treated in the well and discharged without being brought to the surface. Discharged water is circulated through the saturated zone acting as a carrier to continually flush contaminants from the aquifer matrix and transport them to the well for treatment. With pumping rates up to four times those of comparable extraction wells, large radii of influence can be maintained and remediation is achieved faster and more efficiently. In-well stripping is applicable to any strippable contaminant including chlorinated solvents (i.e., TCE and PCE) and hydrocarbons such as the aromatic components in petroleum fuels. Growing costs associated with water discharge, NPDES permits, water rights and, in some areas, salt water intrusion have provided economic incentives to retrofit existing pump and treat systems with NoVOCs units. A large number of wells are amenable to retrofitting depending on their diameter, location and length of screens, and back fill. Even with the new initiatives for intrinsic remediation for petroleum fuel releases, there is a role for the NoVOCs technology. Free product removal wells based on the NoVOCs design eliminate the need to treat and permit water discharges produced when generating a cone of depression for collecting the floating fuel. Additionally, the stripping action and introduction of dissolved oxygen reduce soluble hydrocarbon concentrations to risk levels that can be easily addressed through intrinsic bioremediation

Impact of reformulated fuels on motor vehicle emissions

Science.gov (United States)

Kirchstetter, Thomas

Motor vehicles continue to be an important source of air pollution. Increased vehicle travel and degradation of emission control systems have offset some of the effects of increasingly stringent emission standards and use of control technologies. A relatively new air pollution control strategy is the reformulation of motor vehicle fuels, both gasoline and diesel, to make them cleaner- burning. Field experiments in a heavily traveled northern California roadway tunnel revealed that use of oxygenated gasoline reduced on-road emissions of carbon monoxide (CO) and volatile organic compounds (VOC) by 23 +/- 6% and 19 +/- 8%, respectively, while oxides of nitrogen (NOx) emissions were not significantly affected. The introduction of reformulated gasoline (RFG) in California led to large changes in gasoline composition including decreases in alkene, aromatic, benzene, and sulfur contents, and an increase in oxygen content. The combined effects of RFG and fleet turnover between summers 1994 and 1997 were decreases in on-road vehicle exhaust emissions of CO, non-methane VOC, and NOx by 31 +/- 5, 43 +/- 8, and 18 +/- 4%, respectively. Although it was difficult to separate the fleet turnover and RFG contributions to these changes, it was clear that the effect of RFG was greater for VOC than for NOx. The RFG effect on exhaust emissions of benzene was a 30-40% reduction. Use of RFG reduced the reactivity of liquid gasoline and gasoline headspace vapors by 23 and 19%, respectively. Increased use of methyl tert-butyl ether in gasoline led to increased concentrations of highly reactive formaldehyde and isobutene in vehicle exhaust. As a result, RFG reduced the reactivity of exhaust emissions by only about 5%. Per unit mass of fuel burned, heavy-duty diesel trucks emit about 25 times more fine particle mass and 15-20 times the number of fine particles compared to light-duty vehicles. Exhaust fine particle emissions from heavy-duty diesels contain more black carbon than particulate

Tropospheric VOC measurements by PTR-MS

International Nuclear Information System (INIS)

Hansel, A.; Wisthaler, A.; Graus, M.; Grabmer, W.

2002-01-01

Full text: O 3 is formed photochemically from the photolysis of NO 2 , and because O 3 reacts rapidly with NO these reactions result in a photoequilibrium between NO, NO 2 with no net formation or loss of O 3 , However, in the presence of volatile organic compounds (VOCs), the degradation reactions of VOCs lead to the formation of intermediate peroxy radicals which react with NO, converting NO to NO 2 , which then photolyze to form O 3 . Thus, in order to understand quantitatively tropospheric ozone chemistry, it is necessary to know the VOC distribution within the troposphere as well as VOC fluxes from individual sources. Examples will be presented how the use of Proton Transfer Reaction Mass Spectrometry (PTR-MS) has enhanced our understanding of anthropogenic VOC emissions, biosphere-atmosphere exchange processes, and photochemical processing of both anthropogenic and biogenic VOCs in the troposphere. (author)

VOC emissions control systems

International Nuclear Information System (INIS)

Spessard, J.E.

1993-01-01

The air pollution control equipment marketplace offers many competing technologies for controlling emissions of volatile organic compounds (VOC) in air. If any technology was economically and technically superior under all conditions, it would be the only one on the market. In fact, each technology used to control VOCs is superior under some set of conditions. The reasons for choosing one control technology over another are situation-specific. Some general guidelines to VOC control technologies and the situations where each may be appropriate are presented in this article. The control technologies and applications are summarized in a table

Volatilization of gasoline from soil

International Nuclear Information System (INIS)

Arthus, P.

1993-05-01

Gasoline contaminated soil threatens water resources and air quality. The extent of the threat depends on gasoline behavior in soil, which is affected by various mechanisms such as volatilization. To quantify volatilization, gasoline spills were simulated in the laboratory using a synthetic gasoline and three dry soils. Total gasoline and individual gasoline compound concentrations in soil were monitored as a function of depth and time. The time to reduce overall gasoline concentration in coarse sand, sandy loam, and silt loam to 40% of initial concentration, averaged between surface and a 200-mm depth, ranged from 0.25 d to 10 d. A wicking phenomenon which contributed to gasoline flux toward the atmosphere was indicated by behavior of a low-volatility gasoline compound. Based on separate wicking experiments, this bulk immiscible movement was estimated at an upward velocity of 0.09 m/d for Delhi sandy loam and 0.05 m/d for Elora silt loam. 70 refs., 24 figs., 34 tabs

Dosage direct des alcools dans les carburols par chromatographie en phase gazeuse Direct Gas Chromatographie Determination of Alcohols in Gasolines Blended by Oxygenated Compounds

Directory of Open Access Journals (Sweden)

Petroff N.

2006-11-01

Full Text Available Dans cette étude, on décrit une méthode de chromatographie en phase gazeuse utilisant une colonne remplie ; elle permet de doser, sans préfractionnement, les alcools jusqu'aux butanols dans les carburols (carburants additionnés de composés oxygénés. La phase stationnaire sélectionnée est le glycérol. This report describes a gas chromatographie method using a packed column. It allows the direct determination of alcohols up to butanols in gasolines blended with oxygenated compounds without prefractionation. Glycerol has been selected as stationary phase.

Utilisation of VOC in Diesel Engines. Ignition and combustion of VOC released in crude oil tankers

International Nuclear Information System (INIS)

Melhus, Oeyvin

2002-01-01

The emission of VOC (Volatile Organic Compound) is a significant source of hydrocarbon pollution. In Norway, the offshore oil industry represents a major source. This emission represents both an energy loss and an environmental problem. Gas tankers have used boil-off gas from the cargo tanks as fuel for some time. However, for the current VOC project a new fuel injection concept is designed for tankers to take advantage of the energy present in the VOC evaporated from crude oil. The VOC is mixed with inert gas in these tankers, and thus the utilisation of this gas represents new challenges. The VOC project uses the concept of ''Condensate Diesel Process'' with pilot ignition. An experimental study of ignition and combustion of VOC Fuels reported here was initiated by the time it was decided to start a pilot project converting propulsion engines in shuttle tankers to use VOC Fuel. It is an experimental study carried out at the Marine Technology Centre (MTS). The objective was to study ignition and combustion of the chosen process in comparison with an ordinary diesel process. The experimental results have been discussed and compared with theoretical considerations of injection, ignition and combustion. For experiments on combustion, a rapid compression machine ''DyFo'' was redesigned to use VOC Fuel. The DyFo test rig was initially designed to study ignition and early combustion of spark ignited homogeneous gas/air charges. To study the ignition and early combustion of VOC Fuel injected at high pressure and ignited by pilot diesel fuel, a redesign was necessary. An important feature of the DyFo, is the visualisation of the combustion. The advantage of the DyFo test rig over an engine, is its simplicity and controllability. In an engine the visualisation would suffer from combustion deposits disturbing the view through the quartz glasses, making the images more difficult to interpret. The simplicity is on the other side a drawback. Correct thermal conditions inside

Mixed reforming of simulated gasoline to hydrogen in a BSCFO membrane reactor

Energy Technology Data Exchange (ETDEWEB)

Zhu, Wenliang; Han, Wei; Xiong, Guoxing; Yang, Weishen [State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, P.O. Box 110, Dalian 116023 (China)

2006-10-30

Currently, fuel cells are receiving more and more attention as the most promising new power generation technology, and fuel processing by the mixed reforming of liquid hydrocarbons (MRL) with water and oxygen is regarded as a desirable way for fuel cells. In this paper, we developed a new mixed reforming method for hydrogen production by combining a dense ceramic membrane Ba{sub 0.5}Sr{sub 0.5}Co{sub 0.8}Fe{sub 0.2}O{sub 3-{delta}}(BSCFO) with a catalyst LiLaNiO/{gamma}-Al{sub 2}O{sub 3} in a membrane reactor and reforming a simulated gasoline. During a 500-h long-term test at optimized reaction conditions, all the components in the simulated gasoline converted completely, and around 90% selectivity of CO, around 95% selectivity of H{sub 2} and around 8.0mLcm{sup -2}min{sup -1} oxygen permeation flux were achieved. This provides a new optional way of hydrogen production for fuel cells. (author)

PENINGKATAN KADAR GERANIOL DALAM MINYAK SEREH WANGI DAN APLIKASINYA SEBAGAI BIO ADDITIVE GASOLINE

Directory of Open Access Journals (Sweden)

Widi Astuti

2014-10-01

Full Text Available Sereh wangi merupakan salah satu tanaman penghasil minyak atsiri yang banyak mengandung geraniol. Geraniol merupakan senyawa penyedia oksigen sehingga minyak sereh wangi dimungkinkan dapat digunakan sebagai bio additive gasoline. Penelitian ini bertujuan  meningkatkan kadar geraniol dalam minyak sereh wangi dan menggunakannya sebagai bio additive gasoline.Penelitian dilakukan dalam  tiga tahap, yaitu  pemungutan minyak sereh wangi dari daun sereh wangi, peningkatan kadar geraniol dalam minyak sereh wangi dan aplikasi minyak sereh wangi yang mengandung geraniol tinggi sebagai bio aditive gasoline.Hasil penelitian menunjukkan bahwa pemungutan minyak sereh wangi yang dilakukan dengan metode distilasi uap menghasilkan rendemen sebesar 0,76% dengan kadar geraniol 5,36%.Kadar geraniol dapat ditingkatkan menjadi 21,78% melalui proses distilasi vakum pada suhu 120oC. Pengujian minyak sereh wangi dengan kadar geraniol tinggi sebagai bio additive gasoline meliputi uji performa dan efisiensi konsumsi bahan bakar dengan variasi perbandingan volume gasoline dengan bio additive. Hasilnya, penambahan minyak sereh wangi dengan perbandingan volume gasoline ; minyak sereh wangi = 1000:2 mampu meningkatkan power mesin dari 7,8HP menjadi 8,6HP. Sementara, pada pengujian efisiensi bahan bakar, penambahan minyak sereh wangi dengan perbandingan volume gasoline : minyak sereh wangi = 1000:2 dapat meningkatkan efisiensi mesin sebesar 10,8%. Citronella contains geraniol which is an oxygen provider substances, so it may be used as bio additive. The purpose of this research  is to increase geraniol content in citronella oil and use it as a gasoline bio additive. This research is conducted  in three steps including take the citronella oil from citronella leaf, increase geraniol content in citronella oil and use citronella oil as a gasoline bio additive. The result show that citronella oil produced from citronella leaf using vapor distillation method contains geraniol

Chemical composition of gas-phase organic carbon emissions from motor vehicles and implications for ozone production.

Science.gov (United States)

Gentner, Drew R; Worton, David R; Isaacman, Gabriel; Davis, Laura C; Dallmann, Timothy R; Wood, Ezra C; Herndon, Scott C; Goldstein, Allen H; Harley, Robert A

2013-10-15

Motor vehicles are major sources of gas-phase organic carbon, which includes volatile organic compounds (VOCs) and other compounds with lower vapor pressures. These emissions react in the atmosphere, leading to the formation of ozone and secondary organic aerosol (SOA). With more chemical detail than previous studies, we report emission factors for over 230 compounds from gasoline and diesel vehicles via two methods. First we use speciated measurements of exhaust emissions from on-road vehicles in summer 2010. Second, we use a fuel composition-based approach to quantify uncombusted fuel components in exhaust using the emission factor for total uncombusted fuel in exhaust together with detailed chemical characterization of liquid fuel samples. There is good agreement between the two methods except for products of incomplete combustion, which are not present in uncombusted fuels and comprise 32 ± 2% of gasoline exhaust and 26 ± 1% of diesel exhaust by mass. We calculate and compare ozone production potentials of diesel exhaust, gasoline exhaust, and nontailpipe gasoline emissions. Per mass emitted, the gas-phase organic compounds in gasoline exhaust have the largest potential impact on ozone production with over half of the ozone formation due to products of incomplete combustion (e.g., alkenes and oxygenated VOCs). When combined with data on gasoline and diesel fuel sales in the U.S., these results indicate that gasoline sources are responsible for 69-96% of emissions and 79-97% of the ozone formation potential from gas-phase organic carbon emitted by motor vehicles.

The Energy Information Administration's assessment of reformulated gasoline: An update

International Nuclear Information System (INIS)

1994-12-01

This report (Part II) concludes a two part study of The Energy Information Administration's (EIA) assessment of Reformulated Gasoline (RFG). The data contained herein updates EIA's previous findings and analyses on reformulated gasoline as it affects the petroleum industry. The major findings of Part II have not changed considerably from Part I: Supplies of RFG are adequate to meet demand, but a tight supply-demand balance exists, leaving the RFG system with little ability to absorb unexpected supply or delivery system disruption. In December 1994, the estimated demand for RFG was 2.6 million barrels per day, with the production capability just meeting this demand. The study concludes that current prices for RFG are consistent with the costs underlying the product, and the difference in RFG and conventional gasoline indicates confidence in supply. The study also follows the impact of recent events such as: postponement of the Renewable Oxygenate Standard, the decision to require importers to use the U.S. average baseline for limiting emissions, the disruption of the Colonial Pipeline in Texas, and Pennsylvania's request to opt-out of the RFG program

Gasoline from Wood via Integrated Gasification, Synthesis, and Methanol-to-Gasoline Technologies

Energy Technology Data Exchange (ETDEWEB)

Phillips, S. D.; Tarud, J. K.; Biddy, M. J.; Dutta, A.

2011-01-01

This report documents the National Renewable Energy Laboratory's (NREL's) assessment of the feasibility of making gasoline via the methanol-to-gasoline route using syngas from a 2,000 dry metric tonne/day (2,205 U.S. ton/day) biomass-fed facility. A new technoeconomic model was developed in Aspen Plus for this study, based on the model developed for NREL's thermochemical ethanol design report (Phillips et al. 2007). The necessary process changes were incorporated into a biomass-to-gasoline model using a methanol synthesis operation followed by conversion, upgrading, and finishing to gasoline. Using a methodology similar to that used in previous NREL design reports and a feedstock cost of $50.70/dry ton ($55.89/dry metric tonne), the estimated plant gate price is $16.60/MMBtu ($15.73/GJ) (U.S. $2007) for gasoline and liquefied petroleum gas (LPG) produced from biomass via gasification of wood, methanol synthesis, and the methanol-to-gasoline process. The corresponding unit prices for gasoline and LPG are $1.95/gallon ($0.52/liter) and $1.53/gallon ($0.40/liter) with yields of 55.1 and 9.3 gallons per U.S. ton of dry biomass (229.9 and 38.8 liters per metric tonne of dry biomass), respectively.

VOCs emission characteristics and priority control analysis based on VOCs emission inventories and ozone formation potentials in Zhoushan

Science.gov (United States)

Wang, Qiaoli; Li, Sujing; Dong, Minli; Li, Wei; Gao, Xiang; Ye, Rongmin; Zhang, Dongxiao

2018-06-01

Zhoushan is an island city with booming tourism and service industry, but also has many developed VOCs and/or NOX emission industries. It is necessary to carry out regional VOCs and O3 pollution control in Zhoushan as the only new area owns the provincial economic and social administration rights. Anthropogenic VOCs emission inventories were built based on emission factor method and main emission sources were identified according to the emission inventories. Then, localized VOCs source profiles were built based on in-site sampling and referring to other studies. Furthermore, ozone formation potentials (OFPs) profiles were built through VOCs source profiles and maximum incremental reactivity (MIR) theory. At last, the priority control analysis results showed that industrial processes, especially surface coating, are the key of VOCs and O3 control. Alkanes were the most emitted group, accounting for 58.67%, while aromatics contributed the most to ozone production accounting for 69.97% in total OFPs. n-butane, m/p-xylene, i-pentane, n-decane, toluene, propane, n-undecane, o-xylene, methyl cyclohexane and ethyl benzene were the top 10 VOC species that should be preferentially controlled for VOCs emission control. However, m/p-xylene, o-xylene, ethylene, n-butane, toluene, propene, 1,2,4-trimethyl benzene, 1,3,5-trimethyl benzene, ethyl benzene and 1,2,3-trimethyl benzene were the top 10 VOC species that required preferential control for O3 pollution control.

Evaporation characteristics of ETBE-blended gasoline

International Nuclear Information System (INIS)

Okamoto, Katsuhiro; Hiramatsu, Muneyuki; Hino, Tomonori; Otake, Takuma; Okamoto, Takashi; Miyamoto, Hiroki; Honma, Masakatsu; Watanabe, Norimichi

2015-01-01

Highlights: • We chose 8-component hydrocarbon mixture as a model gasoline, and defined the molar mass of gasoline. • We proposed an evaporation model assuming a 2-component mixture of gasoline and ETBE. • We predicted the change in the vapor pressure of ETBE-blended gasoline by evaporation. • The vapor pressures were measured and compared as a means of verifying the model. • We presented the method for predicting flash points of the ETBE-blended gasoline. - Abstract: To reduce greenhouse gas emissions, which contribute to global warming, production of gasoline blended with ethyl tert-buthyl ether (ETBE) is increasing annually. The flash point of ETBE is higher than that of gasoline, and blending ETBE into gasoline will change the flash point and the vapor pressure. Therefore, it is expected that the fire hazard caused by ETBE-blended gasoline would differ from that caused by normal gasoline. The aim of this study was to acquire the knowledge required for estimating the fire hazard of ETBE-blended gasoline. Supposing that ETBE-blended gasoline was a two-component mixture of gasoline and ETBE, we developed a prediction model that describes the vapor pressure and flash point of ETBE-blended gasoline in an arbitrary ETBE blending ratio. We chose 8-component hydrocarbon mixture as a model gasoline, and defined the relation between molar mass of gasoline and mass loss fraction. We measured the changes in the vapor pressure and flash point of gasoline by blending ETBE and evaporation, and compared the predicted values with the measured values in order to verify the prediction model. The calculated values of vapor pressures and flash points corresponded well to the measured values. Thus, we confirmed that the change in the evaporation characteristics of ETBE-blended gasoline by evaporation could be predicted by the proposed model. Furthermore, the vapor pressure constants of ETBE-blended gasoline were obtained by the model, and then the distillation curves were

Evaporation characteristics of ETBE-blended gasoline

Energy Technology Data Exchange (ETDEWEB)

Okamoto, Katsuhiro, E-mail: okamoto@nrips.go.jp [National Research Institute of Police Science, 6-3-1 Kashiwanoha, Kashiwa, Chiba 277-0882 (Japan); Hiramatsu, Muneyuki [Yamanashi Prefectural Police H.Q., 312-4 Kubonakajima, Isawa-cho, Usui, Yamanashi 406-0036 (Japan); Hino, Tomonori; Otake, Takuma [Metropolitan Police Department, 2-1-1 Kasumigaseki, Chiyoda-ku, Tokyo 100-8929 (Japan); Okamoto, Takashi; Miyamoto, Hiroki; Honma, Masakatsu; Watanabe, Norimichi [National Research Institute of Police Science, 6-3-1 Kashiwanoha, Kashiwa, Chiba 277-0882 (Japan)

2015-04-28

Highlights: • We chose 8-component hydrocarbon mixture as a model gasoline, and defined the molar mass of gasoline. • We proposed an evaporation model assuming a 2-component mixture of gasoline and ETBE. • We predicted the change in the vapor pressure of ETBE-blended gasoline by evaporation. • The vapor pressures were measured and compared as a means of verifying the model. • We presented the method for predicting flash points of the ETBE-blended gasoline. - Abstract: To reduce greenhouse gas emissions, which contribute to global warming, production of gasoline blended with ethyl tert-buthyl ether (ETBE) is increasing annually. The flash point of ETBE is higher than that of gasoline, and blending ETBE into gasoline will change the flash point and the vapor pressure. Therefore, it is expected that the fire hazard caused by ETBE-blended gasoline would differ from that caused by normal gasoline. The aim of this study was to acquire the knowledge required for estimating the fire hazard of ETBE-blended gasoline. Supposing that ETBE-blended gasoline was a two-component mixture of gasoline and ETBE, we developed a prediction model that describes the vapor pressure and flash point of ETBE-blended gasoline in an arbitrary ETBE blending ratio. We chose 8-component hydrocarbon mixture as a model gasoline, and defined the relation between molar mass of gasoline and mass loss fraction. We measured the changes in the vapor pressure and flash point of gasoline by blending ETBE and evaporation, and compared the predicted values with the measured values in order to verify the prediction model. The calculated values of vapor pressures and flash points corresponded well to the measured values. Thus, we confirmed that the change in the evaporation characteristics of ETBE-blended gasoline by evaporation could be predicted by the proposed model. Furthermore, the vapor pressure constants of ETBE-blended gasoline were obtained by the model, and then the distillation curves were

Gasoline prices, gasoline consumption, and new-vehicle fuel economy: Evidence for a large sample of countries

International Nuclear Information System (INIS)

Burke, Paul J.; Nishitateno, Shuhei

2013-01-01

Countries differ considerably in terms of the price drivers pay for gasoline. This paper uses data for 132 countries for the period 1995–2008 to investigate the implications of these differences for the consumption of gasoline for road transport. To address the potential for simultaneity bias, we use both a country's oil reserves and the international crude oil price as instruments for a country's average gasoline pump price. We obtain estimates of the long-run price elasticity of gasoline demand of between − 0.2 and − 0.5. Using newly available data for a sub-sample of 43 countries, we also find that higher gasoline prices induce consumers to substitute to vehicles that are more fuel-efficient, with an estimated elasticity of + 0.2. Despite the small size of our elasticity estimates, there is considerable scope for low-price countries to achieve gasoline savings and vehicle fuel economy improvements via reducing gasoline subsidies and/or increasing gasoline taxes. - Highlights: ► We estimate the determinants of gasoline demand and new-vehicle fuel economy. ► Estimates are for a large sample of countries for the period 1995–2008. ► We instrument for gasoline prices using oil reserves and the world crude oil price. ► Gasoline demand and fuel economy are inelastic with respect to the gasoline price. ► Large energy efficiency gains are possible via higher gasoline prices

Analysis of Sidestream Smoke VOCs and Characterization of their Odor Profiles by VOC Preconcentrator-GC-O Techniques

Directory of Open Access Journals (Sweden)

Higashi N

2014-12-01

Full Text Available Various techniques have been employed in the analysis of volatile organic compounds (VOCs. However, these techniques are insufficient for the precise analysis of tobacco smoke VOCs because of the complexity of the operating system, system instability, or poor sensitivity. To overcome these problems, a combined system of VOC preconcentrator, gas chromatograph, and olfactometer has been developed. The performance of this new system was evaluated in the analysis of VOCs in tobacco smoke and applied to the odor profiling of sidestream smoke (SSS that has not been sufficiently investigated in the past.

Diesel engines vs. spark ignition gasoline engines -- Which is ``greener``?

Energy Technology Data Exchange (ETDEWEB)

Fairbanks, J.W. [Dept. of Energy, Washington, DC (United States)

1997-12-31

Criteria emissions, i.e., NO{sub x}, PM, CO, CO{sub 2}, and H{sub 2}, from recently manufactured automobiles, compared on the basis of what actually comes out of the engines, the diesel engine is greener than spark ignition gasoline engines and this advantage for the diesel engine increases with time. SI gasoline engines tend to get out of tune more than diesel engines and 3-way catalytic converters and oxygen sensors degrade with use. Highway measurements of NO{sub 2}, H{sub 2}, and CO revealed that for each model year, 10% of the vehicles produce 50% of the emissions and older model years emit more than recent model year vehicles. Since 1974, cars with SI gasoline engines have uncontrolled emission until the 3-way catalytic converter reaches operating temperature, which occurs after roughly 7 miles of driving. Honda reports a system to be introduced in 1998 that will alleviate this cold start problem by storing the emissions then sending them through the catalytic converter after it reaches operating temperature. Acceleration enrichment, wherein considerable excess fuel is introduced to keep temperatures down of SI gasoline engine in-cylinder components and catalytic converters so these parts meet warranty, results in 2,500 times more CO and 40 times more H{sub 2} being emitted. One cannot kill oneself, accidentally or otherwise, with CO from a diesel engine vehicle in a confined space. There are 2,850 deaths per year attributable to CO from SI gasoline engine cars. Diesel fuel has advantages compared with gasoline. Refinery emissions are lower as catalytic cracking isn`t necessary. The low volatility of diesel fuel results in a much lower probability of fires. Emissions could be improved by further reducing sulfur and aromatics and/or fuel additives. Reformulated fuel has become the term covering reducing the fuels contribution to emissions. Further PM reduction should be anticipated with reformulated diesel and gasoline fuels.

Airborne VOC measurements on board the Zeppelin NT during the PEGASOS campaigns in 2012 deploying the improvement Fast-GC-MSD system

Energy Technology Data Exchange (ETDEWEB)

Jaeger, Julia Elisabeth

2014-04-01

Volatile organic compounds (VOCs) comprise a large number of different species, estimated to 10{sup 4}-10{sup 6}. They are emitted on the Earth's surface from a variety of biogenic and anthropogenic sources. VOCs are removed by multiple pathways from the atmosphere, by oxidation and finally by dry or wet deposition. Most primary emitted VOCs are non-polar and therefore have a low solubility in water. Oxidation facilitates efficient VOC removal by wet deposition. In the atmosphere the main photochemical VOC oxidation agent is the OH radical. As a consequence the polarity of the VOCs is increased and they can be removed faster. The oxidation of VOCs proceeds in several steps until the VOCs are deposited or are eventually oxidized to carbon dioxide. A downside of the VOCs oxidation process lies in the production of significant amounts ozone if nitrogen oxide is present which is a serious health hazard. Most of the VOC oxidation takes place in lower part of the atmosphere between the altitudes of 100 to 1000 m, which is only sparsely analyzed. Therefore, fast VOCs measurements by GC-MSD on board the Zeppelin NT offered new important insights in the distribution of VOCs. The measurements were performed within the PEAGSOS campaigns in the Netherlands and in Italy in 2012. For the implementation of the GC-MSD system (HCG) on board the Zeppelin it was reconstructed to enhance its performance and to meet aviation requirements. The system was optimized to measure VOCs ranging from C4 to C10 as well as oxygenated VOCs (OVOCs) with a detection limit below 10 ppt. The analyzed VOCs for both parts of the campaigns showed low mean concentration below 5 ppb for all VOCs. Especially, the mixing ratios of the primary emitted VOCs were very low with mean values lower than 200 ppt. Higher concentrations could be observed for the OVOCs with mean concentrations up to 5 ppb. The most abundant OVOCs apart from formaldehyde were methanol, ethanol, acetone and acetaldehyde.

Airborne VOC measurements on board the Zeppelin NT during the PEGASOS campaigns in 2012 deploying the improvement Fast-GC-MSD system

Energy Technology Data Exchange (ETDEWEB)

Jaeger, Julia Elisabeth

2014-04-01

Volatile organic compounds (VOCs) comprise a large number of different species, estimated to 10{sup 4}-10{sup 6}. They are emitted on the Earth's surface from a variety of biogenic and anthropogenic sources. VOCs are removed by multiple pathways from the atmosphere, by oxidation and finally by dry or wet deposition. Most primary emitted VOCs are non-polar and therefore have a low solubility in water. Oxidation facilitates efficient VOC removal by wet deposition. In the atmosphere the main photochemical VOC oxidation agent is the OH radical. As a consequence the polarity of the VOCs is increased and they can be removed faster. The oxidation of VOCs proceeds in several steps until the VOCs are deposited or are eventually oxidized to carbon dioxide. A downside of the VOCs oxidation process lies in the production of significant amounts ozone if nitrogen oxide is present which is a serious health hazard. Most of the VOC oxidation takes place in lower part of the atmosphere between the altitudes of 100 to 1000 m, which is only sparsely analyzed. Therefore, fast VOCs measurements by GC-MSD on board the Zeppelin NT offered new important insights in the distribution of VOCs. The measurements were performed within the PEAGSOS campaigns in the Netherlands and in Italy in 2012. For the implementation of the GC-MSD system (HCG) on board the Zeppelin it was reconstructed to enhance its performance and to meet aviation requirements. The system was optimized to measure VOCs ranging from C4 to C10 as well as oxygenated VOCs (OVOCs) with a detection limit below 10 ppt. The analyzed VOCs for both parts of the campaigns showed low mean concentration below 5 ppb for all VOCs. Especially, the mixing ratios of the primary emitted VOCs were very low with mean values lower than 200 ppt. Higher concentrations could be observed for the OVOCs with mean concentrations up to 5 ppb. The most abundant OVOCs apart from formaldehyde were methanol, ethanol, acetone and acetaldehyde.

Airborne VOC measurements on board the Zeppelin NT during the PEGASOS campaigns in 2012 deploying the improvement Fast-GC-MSD system

International Nuclear Information System (INIS)

Jaeger, Julia Elisabeth

2014-01-01

Volatile organic compounds (VOCs) comprise a large number of different species, estimated to 10 4 -10 6 . They are emitted on the Earth's surface from a variety of biogenic and anthropogenic sources. VOCs are removed by multiple pathways from the atmosphere, by oxidation and finally by dry or wet deposition. Most primary emitted VOCs are non-polar and therefore have a low solubility in water. Oxidation facilitates efficient VOC removal by wet deposition. In the atmosphere the main photochemical VOC oxidation agent is the OH radical. As a consequence the polarity of the VOCs is increased and they can be removed faster. The oxidation of VOCs proceeds in several steps until the VOCs are deposited or are eventually oxidized to carbon dioxide. A downside of the VOCs oxidation process lies in the production of significant amounts ozone if nitrogen oxide is present which is a serious health hazard. Most of the VOC oxidation takes place in lower part of the atmosphere between the altitudes of 100 to 1000 m, which is only sparsely analyzed. Therefore, fast VOCs measurements by GC-MSD on board the Zeppelin NT offered new important insights in the distribution of VOCs. The measurements were performed within the PEAGSOS campaigns in the Netherlands and in Italy in 2012. For the implementation of the GC-MSD system (HCG) on board the Zeppelin it was reconstructed to enhance its performance and to meet aviation requirements. The system was optimized to measure VOCs ranging from C4 to C10 as well as oxygenated VOCs (OVOCs) with a detection limit below 10 ppt. The analyzed VOCs for both parts of the campaigns showed low mean concentration below 5 ppb for all VOCs. Especially, the mixing ratios of the primary emitted VOCs were very low with mean values lower than 200 ppt. Higher concentrations could be observed for the OVOCs with mean concentrations up to 5 ppb. The most abundant OVOCs apart from formaldehyde were methanol, ethanol, acetone and acetaldehyde.

Refining economics of U.S. gasoline: octane ratings and ethanol content.

Science.gov (United States)

Hirshfeld, David S; Kolb, Jeffrey A; Anderson, James E; Studzinski, William; Frusti, James

2014-10-07

Increasing the octane rating of the U.S. gasoline pool (currently ∼ 93 Research Octane Number (RON)) would enable higher engine efficiency for light-duty vehicles (e.g., through higher compression ratio), facilitating compliance with federal fuel economy and greenhouse gas (GHG) emissions standards. The federal Renewable Fuels Standard calls for increased renewable fuel use in U.S. gasoline, primarily ethanol, a high-octane gasoline component. Linear programming modeling of the U.S. refining sector was used to assess the effects on refining economics, CO2 emissions, and crude oil use of increasing average octane rating by increasing (i) the octane rating of refinery-produced hydrocarbon blendstocks for oxygenate blending (BOBs) and (ii) the volume fraction (Exx) of ethanol in finished gasoline. The analysis indicated the refining sector could produce BOBs yielding finished E20 and E30 gasolines with higher octane ratings at modest additional refining cost, for example, ∼ 1¢/gal for 95-RON E20 or 97-RON E30, and 3-5¢/gal for 95-RON E10, 98-RON E20, or 100-RON E30. Reduced BOB volume (from displacement by ethanol) and lower BOB octane could (i) lower refinery CO2 emissions (e.g., ∼ 3% for 98-RON E20, ∼ 10% for 100-RON E30) and (ii) reduce crude oil use (e.g., ∼ 3% for 98-RON E20, ∼ 8% for 100-RON E30).

Production of aviation gasoline

Energy Technology Data Exchange (ETDEWEB)

1938-05-25

A process is described for preparing gasoline possessing properties for use as a fuel, particularly for aviation motors, beginning with gasolines composed among others of cyclic hydrocarbons, especially aromatics, consisting in treating the gasoline by means of selective solvents of aromatic hydrocarbons, especially aromatics, and preferably at the same time employing liquid hydrocarbons which are gaseous under normal conditions and adding to the refined product nonaromatics which boil in the range of the gasoline and have an actane number above 95 or which give the mixture an octane number of 82.5.

Evaporation characteristics of ETBE-blended gasoline.

Science.gov (United States)

Okamoto, Katsuhiro; Hiramatsu, Muneyuki; Hino, Tomonori; Otake, Takuma; Okamoto, Takashi; Miyamoto, Hiroki; Honma, Masakatsu; Watanabe, Norimichi

2015-04-28

To reduce greenhouse gas emissions, which contribute to global warming, production of gasoline blended with ethyl tert-buthyl ether (ETBE) is increasing annually. The flash point of ETBE is higher than that of gasoline, and blending ETBE into gasoline will change the flash point and the vapor pressure. Therefore, it is expected that the fire hazard caused by ETBE-blended gasoline would differ from that caused by normal gasoline. The aim of this study was to acquire the knowledge required for estimating the fire hazard of ETBE-blended gasoline. Supposing that ETBE-blended gasoline was a two-component mixture of gasoline and ETBE, we developed a prediction model that describes the vapor pressure and flash point of ETBE-blended gasoline in an arbitrary ETBE blending ratio. We chose 8-component hydrocarbon mixture as a model gasoline, and defined the relation between molar mass of gasoline and mass loss fraction. We measured the changes in the vapor pressure and flash point of gasoline by blending ETBE and evaporation, and compared the predicted values with the measured values in order to verify the prediction model. The calculated values of vapor pressures and flash points corresponded well to the measured values. Thus, we confirmed that the change in the evaporation characteristics of ETBE-blended gasoline by evaporation could be predicted by the proposed model. Furthermore, the vapor pressure constants of ETBE-blended gasoline were obtained by the model, and then the distillation curves were developed. Copyright © 2015 Elsevier B.V. All rights reserved.

Health assessment of gasoline and fuel oxygenate vapors: reproductive toxicity assessment.

Science.gov (United States)

Gray, Thomas M; Steup, David; Roberts, Linda G; O'Callaghan, James P; Hoffman, Gary; Schreiner, Ceinwen A; Clark, Charles R

2014-11-01

Vapor condensates of baseline gasoline (BGVC), or gasoline-blended with methyl tertiary butyl ether (G/MTBE), ethyl t-butyl ether (G/ETBE), t-amyl methyl ether (G/TAME), diisopropyl ether (G/DIPE), ethanol (G/EtOH), or t-butyl alcohol (G/TBA) were evaluated for reproductive toxicity in rats at target concentrations of 2000, 10,000, or 20,000mg/m(3), 6h/day, 7days/week. BGVC and G/MTBE were assessed over two generations, the others for one generation. BGVC and G/MTBE F1 offspring were evaluated for neuropathology and changes in regional brain glial fibrillary acidic protein content. No neurotoxicity was observed. Male kidney weight was increased consistent with light hydrocarbon nephropathy. In adult rats, decreased body weight gain and increased liver weight were seen. Spleen weight decreased in adults and pups exposed to G/TBA. No pathological changes to reproductive organs occurred in any study. Decreased food consumption was seen in G/TAME lactating females. Transient decreases in G/TAME offspring weights were observed during lactation. Except for a minor increase in time to mating in G/TBA which did not affect other reproductive parameters, there were no adverse reproductive findings. The NOAEL for reproductive and offspring parameters was 20,000mg/m(3) for all vapor condensates except for lower offspring NOAELs of 10,000mg/m(3) for G/TBA and 2000mg/m(3) for G/TAME. Copyright © 2014 Elsevier Inc. All rights reserved.

Standby Gasoline Rationing Plan

Energy Technology Data Exchange (ETDEWEB)

None

1980-06-01

The final rules adopted by the President for a Standby Gasoline Rationing Plan are presented. The plan provides that eligibility for ration allotments will be determined primarily on the basis of motor vehicle registrations, taking into account historical differences in the use of gasoline among states. The regulations also provide authority for supplemental allotments to firms so that their allotment will equal a specified percentage of gasoline use during a base period. Priority classifications, i.e., agriculture, defense, etc., are established to assure adequate gasoline supplies for designated essential services. Ration rights must be provided by end-users to their suppliers for each gallon sold. DOE will regulate the distribution of gasoline at the wholesale level according to the transfer by suppliers of redeemed ration rights and the gasoline allocation regulations. Ration rights are transferable. A ration banking system is created to facilitate transfers of ration rights. Each state will be provided with a reserve of ration rights to provide for hardship needs and to alleviate inequities. (DC)

Volatile organic compounds in Tijuana during the Cal-Mex 2010 campaign: Measurements and source apportionment

Science.gov (United States)

Zheng, Jun; Garzón, Jessica P.; Huertas, María E.; Zhang, Renyi; Levy, Misti; Ma, Yan; Huertas, José I.; Jardón, Ricardo T.; Ruíz, Luis G.; Tan, Haobo; Molina, Luisa T.

2013-05-01

As part of the Cal-Mex 2010 air quality study, a proton transfer reaction-mass spectrometer (PTR-MS) was deployed at the San Diego-Tijuana border area to measure volatile organic compounds (VOCs) from 15 May to 30 June 2010. The major VOCs identified during the study included oxygenated VOCs (e.g., methanol, acetaldehyde, acetone, and methyl ethyl ketone) and aromatics (e.g., benzene, toluene, C8- and C9-aromatics). Biogenic VOCs (e.g., isoprene) were scarce in this region because of the lack of vegetation in this arid area. Using an U.S. EPA positive matrix factorization model, VOCs together with other trace gases (NOx, NOz and SO2) observed in this border region were attributed to four types of sources, i.e., local industrial solvent usage (58% in ppbC), gasoline vehicle exhaust (19% in ppbC), diesel vehicle exhaust (14% in ppbC), and aged plume (9% in ppbC) due to regional background and/or long-range transport. Diesel vehicle emission contributed to 87% of SO2 and 75% of NOx, and aged plume contributed to 92% of NOz. An independent conditional probability function analysis of VOCs, wind direction, and wind speed indicated that the industrial source did not show a significant tendency with wind direction. Both gasoline and diesel engine emissions were associated with air masses passing through two busy cross-border ports. Aged plumes were strongly associated with NW wind, which likely brought in aged air masses from the populated San Diego area.

Bioremediation Of Groundwater Contaminated Wtih Gasoline Hydrocarbons And Oxygenates Using A Membrane-Based Reactor

Science.gov (United States)

The objective of this study was to operate a novel, field-scale, aerobic bioreactor and assess its performance in the ex situ treatment of groundwater contaminated with gasoline from a leaking underground storage tank in Pascoag, RI. The groundwater contained elevated concentrat...

Price changes in the gasoline market: Are Midwestern gasoline prices downward sticky?

International Nuclear Information System (INIS)

1999-03-01

This report examines a recurring question about gasoline markets: why, especially in times of high price volatility, do retail gasoline prices seem to rise quickly but fall back more slowly? Do gasoline prices actually rise faster than they fall, or does this just appear to be the case because people tend to pay more attention to prices when they're rising? This question is more complex than it might appear to be initially, and it has been addressed by numerous analysts in government, academia and industry. The question is very important, because perceived problems with retail gasoline pricing have been used in arguments for government regulation of prices. The phenomenon of prices at different market levels tending to move differently relative to each other depending on direction is known as price asymmetry. This report summarizes the previous work on gasoline price asymmetry and provides a method for testing for asymmetry in a wide variety of situations. The major finding of this paper is that there is some amount of asymmetry and pattern asymmetry, especially at the retail level, in the Midwestern states that are the focus of the analysis. Nevertheless, both the amount asymmetry and pattern asymmetry are relatively small. In addition, much of the pattern asymmetry detected in this and previous studies could be a statistical artifact caused by the time lags between price changes at different points in the gasoline distribution system. In other words, retail gasoline prices do sometimes rise faster than they fall, but this is largely a lagged market response to an upward shock in the underlying wholesale gasoline or crude oil prices, followed by a return toward the previous baseline. After consistent time lags are factored out, most apparent asymmetry disappears

Impacts of using reformulated and oxygenated fuel blends on the regional air quality of the upper Rhine valley

Directory of Open Access Journals (Sweden)

J.-F. Vinuesa

2006-01-01

Full Text Available The effects of using three alternative gasoline fuel blends on regional air quality of the upper Rhine valley have been investigated. The first of the tested fuels is oxygenated by addition of ethyl-tertio-butyl ether (ETBE, the second is based on a reformulation of its composition and the third on is both oxygenated and reformulated. The upper Rhine valley is a very sensitive region for pollution episodes and several meteorological and air quality studies have already been performed. High temporal and spatial emission inventories are available allowing relevant and realistic modifications of the emission inventories. The calculation period, i.e., 11 May 1998, corresponds to a regional photochemical ozone pollution episode during which ozone concentrations exceeded several times the information threshold of the ozone directive of the European Union (180 μg m-3 as 1 hourly average. New emission inventories are set up using specific emission factors related to the alternative fuels by varying the fraction of gasoline passenger cars (from 50% to 100% using the three fuel blends. Then air quality modeling simulations are performed using these emission inventories over the upper Rhine valley. The impact of alternative fuels on regional air quality is evaluated by comparing these simulations with the one using a reference emission inventory, e.g., where no modifications of the fuel composition are included. The results are analyzed by focusing on peak levels and daily averaged concentrations. The use of the alternative fuels leads to general reductions of ozone and volatile organic compounds (VOC and increases of NOx levels. We found different behaviors related to the type of the area of concern i.e. rural or urban. The impacts on ozone are enhanced in urban areas where 15% reduction of the ozone peak and daily averaged concentrations can be reached. This behavior is similar for the NOx for which, in addition, an increase of the levels can be noted

Feasibility study on reduction of gasoline emissions from oil depots and gasoline stations in Indonesia

Energy Technology Data Exchange (ETDEWEB)

NONE

2001-03-01

A field survey was conducted of oil shipment depots in Java and Bali islands owned by Indonesia's state-run oil company to study measures for reduction in greenhouse effect gas emissions. Studies were made on the grasp of the amount of the hydrocarbon vapor emitted into the air, the amount of the gasoline recovered in case of adopting the vapor emission preventive technology, equipment cost/operational cost, etc. Concretely, the following three were studied: change of the gasoline storage tank to the inner floating roof type, and prevention of evaporation loss at the time of receiving and breathing loss caused by temperature changes; replacement with the vapor recovery type loading arm to recover gasoline vapor generated at the time of shipment/filling, and installation of the vapor recovery unit to recover vapor as gasoline; vapor balance system to recover in underground tank the gasoline vapor generated at the time of filling gasoline at gas station. As a result of the study, the recovered gasoline amount was 66,393 Kl/y and the CO2 reduction amount was 14,474 t/y at oil shipment depots and approximately 650 gasoline stations in Jakarta and Surabaya. (NEDO)

Compositional effects on the ignition of FACE gasolines

KAUST Repository

Sarathy, Mani; Kukkadapu, Goutham; Mehl, Marco; Javed, Tamour; Ahmed, Ahfaz; Naser, Nimal; Tekawade, Aniket; Kosiba, Graham; Alabbad, Mohammed; Singh, Eshan; Park, Sungwoo; Rashidi, Mariam Al; Chung, Suk-Ho; Roberts, William L.; Oehlschlaeger, Matthew A.; Sung, Chih-Jen; Farooq, Aamir

2016-01-01

As regulatory measures for improved fuel economy and decreased emissions are pushing gasoline engine combustion technologies towards extreme conditions (i.e., boosted and intercooled intake with exhaust gas recirculation), fuel ignition characteristics become increasingly important for enabling stable operation. This study explores the effects of chemical composition on the fundamental ignition behavior of gasoline fuels. Two well-characterized, high-octane, non-oxygenated FACE (Fuels for Advanced Combustion Engines) gasolines, FACE F and FACE G, having similar antiknock indices but different octane sensitivities and chemical compositions are studied. Ignition experiments were conducted in shock tubes and a rapid compression machine (RCM) at nominal pressures of 20 and 40. atm, equivalence ratios of 0.5 and 1.0, and temperatures ranging from 650 to 1270. K. Results at temperatures above 900. K indicate that ignition delay time is similar for these fuels. However, RCM measurements below 900. K demonstrate a stronger negative temperature coefficient behavior for FACE F gasoline having lower octane sensitivity. In addition, RCM pressure profiles under two-stage ignition conditions illustrate that the magnitude of low-temperature heat release (LTHR) increases with decreasing fuel octane sensitivity. However, intermediate-temperature heat release is shown to increase as fuel octane sensitivity increases. Various surrogate fuel mixtures were formulated to conduct chemical kinetic modeling, and complex multicomponent surrogate mixtures were shown to reproduce experimentally observed trends better than simpler two- and three-component mixtures composed of n-heptane, iso-octane, and toluene. Measurements in a Cooperative Fuels Research (CFR) engine demonstrated that the multicomponent surrogates accurately captured the antiknock quality of the FACE gasolines. Simulations were performed using multicomponent surrogates for FACE F and G to reveal the underlying chemical

Compositional effects on the ignition of FACE gasolines

KAUST Repository

Sarathy, Mani

2016-05-08

As regulatory measures for improved fuel economy and decreased emissions are pushing gasoline engine combustion technologies towards extreme conditions (i.e., boosted and intercooled intake with exhaust gas recirculation), fuel ignition characteristics become increasingly important for enabling stable operation. This study explores the effects of chemical composition on the fundamental ignition behavior of gasoline fuels. Two well-characterized, high-octane, non-oxygenated FACE (Fuels for Advanced Combustion Engines) gasolines, FACE F and FACE G, having similar antiknock indices but different octane sensitivities and chemical compositions are studied. Ignition experiments were conducted in shock tubes and a rapid compression machine (RCM) at nominal pressures of 20 and 40. atm, equivalence ratios of 0.5 and 1.0, and temperatures ranging from 650 to 1270. K. Results at temperatures above 900. K indicate that ignition delay time is similar for these fuels. However, RCM measurements below 900. K demonstrate a stronger negative temperature coefficient behavior for FACE F gasoline having lower octane sensitivity. In addition, RCM pressure profiles under two-stage ignition conditions illustrate that the magnitude of low-temperature heat release (LTHR) increases with decreasing fuel octane sensitivity. However, intermediate-temperature heat release is shown to increase as fuel octane sensitivity increases. Various surrogate fuel mixtures were formulated to conduct chemical kinetic modeling, and complex multicomponent surrogate mixtures were shown to reproduce experimentally observed trends better than simpler two- and three-component mixtures composed of n-heptane, iso-octane, and toluene. Measurements in a Cooperative Fuels Research (CFR) engine demonstrated that the multicomponent surrogates accurately captured the antiknock quality of the FACE gasolines. Simulations were performed using multicomponent surrogates for FACE F and G to reveal the underlying chemical

Knock Resistance and Fine Particle Emissions for Several Biomass-Derived Oxygenates in a Direct-Injection Spark-Ignition Engine

Energy Technology Data Exchange (ETDEWEB)

Ratcliff, Matthew A.; Burton, Jonathan; Sindler, Petr; Christensen, Earl; Fouts, Lisa; Chupka, Gina M.; McCormick, Robert L.

2016-04-01

Several high octane number oxygenates that could be derived from biomass were blended with gasoline and examined for performance properties and their impact on knock resistance and fine particle emissions in a single cylinder direct-injection spark-ignition engine. The oxygenates included ethanol, isobutanol, anisole, 4-methylanisole, 2-phenylethanol, 2,5-dimethyl furan, and 2,4-xylenol. These were blended into a summertime blendstock for oxygenate blending at levels ranging from 10 to 50 percent by volume. The base gasoline, its blends with p-xylene and p-cymene, and high-octane racing gasoline were tested as controls. Relevant gasoline properties including research octane number (RON), motor octane number, distillation curve, and vapor pressure were measured. Detailed hydrocarbon analysis was used to estimate heat of vaporization and particulate matter index (PMI). Experiments were conducted to measure knock-limited spark advance and particulate matter (PM) emissions. The results show a range of knock resistances that correlate well with RON. Molecules with relatively low boiling point and high vapor pressure had little effect on PM emissions. In contrast, the aromatic oxygenates caused significant increases in PM emissions (factors of 2 to 5) relative to the base gasoline. Thus, any effect of their oxygen atom on increasing local air-fuel ratio was outweighed by their low vapor pressure and high double-bond equivalent values. For most fuels and oxygenate blend components, PMI was a good predictor of PM emissions. However, the high boiling point, low vapor pressure oxygenates 2-phenylethanol and 2,4-xylenol produced lower PM emissions than predicted by PMI. This was likely because they did not fully evaporate and combust, and instead were swept into the lube oil.

Leaded gasoline - an environmental problem

International Nuclear Information System (INIS)

Petrushevska, Ljubica

2001-01-01

In the European countries it is a clear trend towards the increasing consumption of unleaded gasolines. Driving force of this trend is, on the one hand the high toxicity of lead compounds and on the other, the necessity of purification of exhaust gases by catalytic converters, for which the lead represent a catalyst poison. In Macedonia, the limit lead content in the leaded gasolines is relatively high (0,6 g/l), as well as the consumption of the leaded gasolines. Rapid and complete transition to unleaded gasolines can be realized by the concept of step by step reduction of lead in our gasolines. (Original)

VOCs in Arid soils: Technology summary

International Nuclear Information System (INIS)

1994-02-01

The Volatile Organic Compounds In Arid Soils Integrated Demonstration (VOC-Arid ID) focuses on technologies to clean up volatile organic compounds and associated contaminants in soil and groundwater at arid sites. The initial host site is the 200 West Area at DOE's Hanford site in southeastern Washington state. The primary VOC contaminant is carbon tetrachloride, in association with heavy metals and radionuclides. An estimated 580--920 metric tons of carbon tetrachloride were disposed of between 1955 and 1973, resulting in extensive soil and groundwater contamination. The VOC-Arid ID schedule has been divided into three phases of implementation. The phased approach provides for: rapid transfer of technologies to the Environmental Restoration (EM-40) programs once demonstrated; logical progression in the complexity of demonstrations based on improved understanding of the VOC problem; and leveraging of the host site EM-40 activities to reduce the overall cost of the demonstrations. During FY92 and FY93, the primary technology demonstrations within the ID were leveraged with an ongoing expedited response action at the Hanford 200 West Area, which is directed at vapor extraction of VOCs from the vadose (unsaturated) zone. Demonstration efforts are underway in the areas of subsurface characterization including: drilling and access improvements, off-gas and borehole monitoring of vadose zone VOC concentrations to aid in soil vapor extraction performance evaluation, and treatment of VOC-contaminated off-gas. These current demonstration efforts constitute Phase 1 of the ID and, because of the ongoing vadose zone ERA, can result in immediate transfer of successful technologies to EM-40

Contribution of biogenic and photochemical sources to ambient VOCs during winter to summer transition at a semi-arid urban site in India.

Science.gov (United States)

Sahu, L K; Tripathi, Nidhi; Yadav, Ravi

2017-10-01

This paper presents the sources and characteristics of ambient volatile organic compounds (VOCs) measured using PTR-TOF-MS instrument in a metropolitan city of India during winter to summer transition period. Mixing ratios of VOCs exhibited strong diurnal, day-to-day and episodic variations. Methanol was the most dominant species with monthly mean values of 18-22 pbbv. The emission ratios of VOCs relative to benzene calculated from nighttime data were used to estimate the relative contributions of vehicle exhaust and other sources. The increasing daytime ratios of oxygenated-VOCs (OVOCs)/benzene and isoprene/benzene from February to March indicates increasing contribution of photo-oxidation and biogenic sources. Daytime fractions of acetone (18%), acetaldehyde (15%) and isoprene (4.5%) to the sum of measured VOCs in March were higher than those in February. Variations of VOCs at lower temperatures (biogenic emissions. The emissions of OVOCs from vehicle exhaust were estimated to be smaller (20-40%) than those from other sources. The contributions of biogenic and secondary sources to OVOCs and isoprene increased by 10-15% from winter to summer. This study provides evidence that the winter-to-summer transition has an impact on sources and composition of VOCs in tropical urban areas. Copyright © 2017 Elsevier Ltd. All rights reserved.

Production of gasoline fraction from bio-oil under atmospheric conditions by an integrated catalytic transformation process

International Nuclear Information System (INIS)

Zhang, Zhaoxia; Bi, Peiyan; Jiang, Peiwen; Fan, Minghui; Deng, Shumei; Zhai, Qi; Li, Quanxin

2015-01-01

This work aimed to develop an integrated process for production of gasoline fraction bio-fuels from bio-oil under atmospheric conditions. This novel transformation process included the catalytic cracking of bio-oil to light olefins and the subsequent synthesis of liquid hydrocarbon bio-fuels from light olefins with two reactors in series. The yield of bio-fuel was up to 193.8 g/(kg bio-oil) along with a very low oxygen content, high RONs (research octane numbers), high LHVs (lower heating values) and low benzene content under the optimizing reaction conditions. Coke deposition seems to be the main cause of catalyst deactivation in view of the fact that the deactivated catalysts was almost recovered by on-line treating the used catalyst with oxygen. The integrated transformation potentially provides a useful way for the development of gasoline range hydrocarbon fuels using renewable lignocellulose biomass. - Graphical abstract: An integrated process for production of gasoline fraction bio-fuels from bio-oil through the catalytic cracking of bio-oil to light olefins followed by the synthesis of liquid hydrocarbon bio-fuels from light olefins in series. - Highlights: • A new route for production of gasoline-range bio-fuels from bio-oil was achieved. • The process was an integrated catalytic transformation at atmospheric pressure. • Bio-oil is converted into light olefins and then converted to biofuel in series. • C_6–C_1_0 bio-fuels derived from bio-oil had high RONs and LHVs.

Suns-VOC characteristics of high performance kesterite solar cells

Science.gov (United States)

Gunawan, Oki; Gokmen, Tayfun; Mitzi, David B.

2014-08-01

Low open circuit voltage (VOC) has been recognized as the number one problem in the current generation of Cu2ZnSn(Se,S)4 (CZTSSe) solar cells. We report high light intensity and low temperature Suns-VOC measurement in high performance CZTSSe devices. The Suns-VOC curves exhibit bending at high light intensity, which points to several prospective VOC limiting mechanisms that could impact the VOC, even at 1 sun for lower performing samples. These VOC limiting mechanisms include low bulk conductivity (because of low hole density or low mobility), bulk or interface defects, including tail states, and a non-ohmic back contact for low carrier density CZTSSe. The non-ohmic back contact problem can be detected by Suns-VOC measurements with different monochromatic illuminations. These limiting factors may also contribute to an artificially lower JSC-VOC diode ideality factor.

Performance and emissions analysis on using acetone–gasoline fuel blends in spark-ignition engine

Directory of Open Access Journals (Sweden)

Ashraf Elfasakhany

2016-09-01

Full Text Available In this study, new blended fuels were formed by adding 3–10 vol. % of acetone into a regular gasoline. According to the best of the author's knowledge, it is the first time that the influence of acetone blends has been studied in a gasoline-fueled engine. The blended fuels were tested for their energy efficiencies and pollutant emissions using SI (spark-ignition engine with single-cylinder and 4-stroke. Experimental results showed that the AC3 (3 vol.% acetone + 97 vol.% gasoline blended fuel has an advantage over the neat gasoline in exhaust gases temperature, in-cylinder pressure, brake power, torque and volumetric efficiency by about 0.8%, 2.3%, 1.3%, 0.45% and 0.9%, respectively. As the acetone content increases in the blends, as the engine performance improved where the best performance obtained in this study at the blended fuel of AC10. In particular, exhaust gases temperature, in-cylinder pressure, brake power, torque and volumetric efficiency increase by about 5%, 10.5%, 5.2%, 2.1% and 3.2%, respectively, compared to neat gasoline. In addition, the use of acetone with gasoline fuel reduces exhaust emissions averagely by about 43% for carbon monoxide, 32% for carbon dioxide and 33% for the unburnt hydrocarbons. The enhanced engine performance and pollutant emissions are attributed to the higher oxygen content, slight leaning effect, lower knock tendency and high flame speeds of acetone, compared to the neat gasoline. Finally the mechanism of acetone combustion in gasoline-fueled engines is proposed in this work; two main pathways for acetone combustion are highlighted; furthermore, the CO, CO2 and UHC (unburnt hydrocarbons mechanisms of formation and oxidation are acknowledged. Such acetone mechanism is employed for further understanding acetone combustion in spark-ignition engines.

Catalytic purification of waste gases containing VOC mixtures with Ce/Zr solid solutions

Energy Technology Data Exchange (ETDEWEB)

Gutierrez-Ortiz, Jose I.; De Rivas, Beatriz; Lopez-Fonseca, Ruben; Gonzalez-Velasco, Juan R. [Chemical Technologies for Environmental Sustainability Group, Department of Chemical Engineering, Faculty of Science and Technology, Universidad del Pais Vasco/EHU, P.O. Box 644, E-48080 Bilbao (Spain)

2006-06-06

This study has been undertaken to investigate the efficiency of ceria, zirconia, and Ce{sub x}Zr{sub 1-x}O{sub 2} mixed oxides as catalysts for the vapour-phase destruction in air of single model VOCs (n-hexane, 1,2-dichloroethane and trichloroethylene) and non-chlorinated VOC/chlorinated VOC binary mixtures. Considering all catalyst compositions examined for the individual destruction of these compounds, activity for complete oxidation decreased in the following order: n-hexane<1,2-dichloroethaneVOCs abatement (Ce{sub 0.5}Zr{sub 0.5}O{sub 2} and Ce{sub 0.15}Zr{sub 0.85}O{sub 2}) were different than that with the best performance for n-hexane oxidation (CeO{sub 2}). Concerning chlorinated VOCs conversion, it was observed that notable improvements in catalyst activity of CeO{sub 2} could be achieved through structural doping with Zr ions. Mixed oxides exhibited promoted redox and acid properties, which resulted catalytically relevant for the oxidation of 1,2-dichloroethane and trichloroethylene. In contrast, the combustion of n-hexane was essentially controlled by surface oxygen species, which were more abundant on CeO{sub 2}. Attainment of high n-hexane conversions with CeO{sub 2} was also attributed in part to the hydrophobicity of the support and the reduced interaction with carbon dioxide. Significant 'mixture effects' on both activity and selectivity were noticed when a given chlorinated feed was decomposed in the presence of n-hexane. On one hand, each VOC decreased the reactivity of the other relative to that of the pure compound resulting in higher operating temperatures to achieve adequate destruction. Competitive adsorption played an important role in the reciprocal inhibition effects detected with all catalysts. On the other hand, the selectivity to HCl was noticeably enhanced when n-hexane was co-fed, probably due to the increased presence of water generated as an

Modeling unsteady-state VOC transport in simulated waste drums

International Nuclear Information System (INIS)

Liekhus, K.J.; Gresham, G.L.; Peterson, E.S.; Rae, C.; Hotz, N.J.; Connolly, M.J.

1994-01-01

This report is a revision of an EG ampersand G Idaho informal report originally titled Modeling VOC Transport in Simulated Waste Drums. A volatile organic compound (VOC) transport model has been developed to describe unsteady-state VOC permeation and diffusion within a waste drum. Model equations account for three primary mechanisms for VOC transport from a void volume within the drum. These mechanisms are VOC permeation across a polymer boundary, VOC diffusion across an opening in a volume boundary, and VOC solubilization in a polymer boundary. A series of lab-scale experiments was performed in which the VOC concentration was measured in simulated waste drums under different conditions. A lab-scale simulated waste drum consisted of a sized-down 55-gal metal drum containing a modified rigid polyethylene drum liner. Four polyethylene bags were sealed inside a large polyethylene bag, supported by a wire cage, and placed inside the drum liner. The small bags were filled with VOC-air gas mixture and the VOC concentration was measured throughout the drum over a period of time. Test variables included the type of VOC-air gas mixtures introduced into the small bags, the small bag closure type, and the presence or absence of a variable external heat source. Model results were calculated for those trials where the permeability had been measured

40 CFR 1065.710 - Gasoline.

Science.gov (United States)

2010-07-01

... 40 Protection of Environment 32 2010-07-01 2010-07-01 false Gasoline. 1065.710 Section 1065.710... PROCEDURES Engine Fluids, Test Fuels, Analytical Gases and Other Calibration Standards § 1065.710 Gasoline. (a) Gasoline for testing must have octane values that represent commercially available fuels for the...

Catalytic purification of waste gases containing VOC mixtures with Ce/Zr solid solutions

International Nuclear Information System (INIS)

Gutierrez-Ortiz, Jose I.; De Rivas, Beatriz; Lopez-Fonseca, Ruben; Gonzalez-Velasco, Juan R.

2006-01-01

This study has been undertaken to investigate the efficiency of ceria, zirconia, and Ce x Zr 1-x O 2 mixed oxides as catalysts for the vapour-phase destruction in air of single model VOCs (n-hexane, 1,2-dichloroethane and trichloroethylene) and non-chlorinated VOC/chlorinated VOC binary mixtures. Considering all catalyst compositions examined for the individual destruction of these compounds, activity for complete oxidation decreased in the following order: n-hexane 0.5 Zr 0.5 O 2 and Ce 0.15 Zr 0.85 O 2 ) were different than that with the best performance for n-hexane oxidation (CeO 2 ). Concerning chlorinated VOCs conversion, it was observed that notable improvements in catalyst activity of CeO 2 could be achieved through structural doping with Zr ions. Mixed oxides exhibited promoted redox and acid properties, which resulted catalytically relevant for the oxidation of 1,2-dichloroethane and trichloroethylene. In contrast, the combustion of n-hexane was essentially controlled by surface oxygen species, which were more abundant on CeO 2 . Attainment of high n-hexane conversions with CeO 2 was also attributed in part to the hydrophobicity of the support and the reduced interaction with carbon dioxide. Significant 'mixture effects' on both activity and selectivity were noticed when a given chlorinated feed was decomposed in the presence of n-hexane. On one hand, each VOC decreased the reactivity of the other relative to that of the pure compound resulting in higher operating temperatures to achieve adequate destruction. Competitive adsorption played an important role in the reciprocal inhibition effects detected with all catalysts. On the other hand, the selectivity to HCl was noticeably enhanced when n-hexane was co-fed, probably due to the increased presence of water generated as an oxidation product. (author)

The gasoline retail market in Quebec

International Nuclear Information System (INIS)

Lapointe, A.

1998-06-01

A comprehensive study of the current status of the gasoline market in Quebec was presented. The study includes: (1) a review of the evolution of the retail market since the 1960s, (2) the development of a highly competitive sales environment, (3) a discussion of governmental interventions in the retail sales of gasoline, and (4) a discussion of the problems associated with the imposition of a minimum gasoline price. The low increase in demand for gasoline in Quebec since the 1980s has led to a considerable restructuring of the gasoline market. Consumers have little loyalty to specific brands but seek the lowest prices or prefer the outlets that offer the widest variety of associated services such as convenience stores, fast-food and car washes. Gasoline has clearly become a commodity in Quebec. An econometric model of gasoline price adjustments for the Montreal and Toronto urban areas and a summary of government interventions in the retail marketing of gasoline in Canada and the USA are included as appendices. tabs

Standby Gasoline Rationing Plan. Contingency gasoline rationing regulations

Energy Technology Data Exchange (ETDEWEB)

1979-02-01

The Economic Regulatory Administration issues final rules with respect to standby gasoline rationing. The plan is designed for and would be used only in the event of a severe gasoline shortage. The plan provides that eligibility for ration allotments will be primarily on the basis of motor vehicle registrations. DOE will mail government ration checks to the parties named in a national vehicle registration file to be maintained by DOE. Ration recipients may cash these checks for ration coupons at various designated coupon issuance points. Retail outlets and other suppliers will be required to redeem the ration coupons received in exchange for gasoline sold. Supplemental gas will be given to high-priority activities. A ration banking system will be established with two separate and distinct of ration accounts: retail outlets and other suppliers will open redemption accounts for the deposit of redeemed ration rights; and individuals or firms may open ration rights accounts, which will operate in much the same manner as monetary checking accounts. A white market will be permitted for the sale of transfer of ration rights. A percentage of the total ration rights to be issued will be reserved for distribution to the states as a State Ration Reserve, to be used by the states primarily for the relief of hardship. A National Ration Reserave will also be established. All sections of the Standby Gasoline Rationing Regulations are analyzed. (MCW)

Asian gasoline and diesel fuel quality

International Nuclear Information System (INIS)

Yamaguchi, Nancy D.

2000-01-01

Despite the economic slowdown in the late 1990s, gasoline and diesel demand in the Asia-Pacific region has increased significantly. Regional demand is the highest in the world and most new refinery projects worldwide during the 1990s have been here. Generalisations are difficult because the region contains countries at different stages of economic development and environmental quality standards. Gasoline and diesel demand for 1985-2005 for Australasia, Southeast Asia, South Asia and East Asia is shown in four histograms. The trend towards unleaded gasoline, average gasoline aromatics levels and the quality of gasoline in Australasia, South Asia, Southeast Asia and East Asia are examined. A further three histograms show the growth in Asia-Pacific unleaded gasoline market share 1991-2000, the rise in octane levels as lead levels fall (1991-2005) and the calculated aromatics content of gasoline in 11 Asia-Pacific countries

Chronic Carcinogenicity Study of Gasoline Vapor Condensate (GVC) and GVC Containing Methyl Tertiary-Butyl Ether in F344 Rats

OpenAIRE

Benson, Janet M.; Gigliotti, Andrew P.; March, Thomas H.; Barr, Edward B.; Tibbetts, Brad M.; Skipper, Betty J.; Clark, Charles R.; Twerdok, Lorraine

2011-01-01

Chronic inhalation studies were conducted to compare the toxicity and potential carcinogenicity of evaporative emissions from unleaded gasoline (GVC) and gasoline containing the oxygenate methyl tertiary-butyl ether (MTBE; GMVC). The test materials were manufactured to mimic vapors people would be exposed to during refueling at gas stations. Fifty F344 rats per gender per exposure level per test article were exposed 6 h/d, 5 d/wk for 104 wk in whole body chambers. Target total vapor concentra...

Reformulated gasoline: lessons from America

International Nuclear Information System (INIS)

Seymour, A.

1995-01-01

Regulating fuel quality is one of the few politically feasible options for improving air quality in the short and medium term. This book explores and studies the reformulated gasoline programme currently underway in the USA. Despite the smoothness of the initial implementation of the programme, difficulties may arise in the future. It is concluded that reformulated gasoline prices are more independent of crude oil price changes than conventional unleaded gasoline. Finally, the study suggests that refiners will not reap great profit from investment in the supply of reformulated gasoline because of government restrictions. (UK)

27 CFR 21.109 - Gasoline.

Science.gov (United States)

2010-04-01

... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Gasoline. 21.109 Section 21.109 Alcohol, Tobacco Products and Firearms ALCOHOL AND TOBACCO TAX AND TRADE BUREAU, DEPARTMENT OF... Gasoline. (a) Distillation range. When 100 ml of gasoline are distilled, none shall distill below 90 °F...

Comparison of combustion characteristics of n-butanol/ethanol–gasoline blends in a HCCI engine

International Nuclear Information System (INIS)

He, Bang-Quan; Liu, Mao-Bin; Zhao, Hua

2015-01-01

counterparts with identical oxygen mass content in the blend at the same IVO/EVC timings regardless of engine speeds. For alcohol–gasoline blends, the effect of IVO/EVC timing on the thermal efficiency of the HCCI engine is dependent on autoignition timing, fuel types and engine speeds. However, advanced autoignition timing for the blends with alcohol worsens the thermal efficiency of the HCCI engine in most cases

Emissions of volatile organic compounds (VOCs) from cooking and their speciation: A case study for Shanghai with implications for China.

Science.gov (United States)

Wang, Hongli; Xiang, Zhiyuan; Wang, Lina; Jing, Shengao; Lou, Shengrong; Tao, Shikang; Liu, Jing; Yu, Mingzhou; Li, Li; Lin, Li; Chen, Ying; Wiedensohler, Alfred; Chen, Changhong

2018-04-15

Cooking emission is one of sources for ambient volatile organic compounds (VOCs), which is deleterious to air quality, climate and human health. These emissions are especially of great interest in large cities of East and Southeast Asia. We conducted a case study in which VOC emissions from kitchen extraction stacks have been sampled in total 57 times in the Megacity Shanghai. To obtain representative data, we sampled VOC emissions from kitchens, including restaurants of seven common cuisine types, canteens, and family kitchens. VOC species profiles and their chemical reactivities have been determined. The results showed that 51.26%±23.87% of alkane and 24.33±11.69% of oxygenated VOCs (O-VOCs) dominate the VOC cooking emissions. Yet, the VOCs with the largest ozone formation potential (OFP) and secondary organic aerosol potential (SOAP) were from the alkene and aromatic categories, accounting for 6.8-97.0% and 73.8-98.0%, respectively. Barbequing has the most potential of harming people's heath due to its significant higher emissions of acetaldehyde, hexanal, and acrolein. Methodologies for calculating VOC emission factors (EF) for restaurants that take into account VOCs emitted per person (EF person ), per kitchen stove (EF kitchen stove ) and per hour (EF hour ) are developed and discussed. Methodologies for deriving VOC emission inventories (S) from restaurants are further defined and discussed based on two categories: cuisine types (S type ) and restaurant scales (S scale ). The range of S type and S scale are 4124.33-7818.04t/year and 1355.11-2402.21t/year, respectively. We also found that S type and S scale for 100,000 people are 17.07-32.36t/year and 5.61-9.95t/year, respectively. Based on Environmental Kuznets Curve, the annual total amount of VOCs emissions from catering industry in different provinces in China was estimated, which was 5680.53t/year, 6122.43t/year, and 66,244.59t/year for Shangdong and Guangdong provinces and whole China, respectively

Monitoring of Gasoline-ethanol Degradation In Undisturbed Soil

Science.gov (United States)

Österreicher-Cunha, P.; Nunes, C. M. F.; Vargas, E. A.; Guimarães, J. R. D.; Costa, A.

Environmental contamination problems are greatly emphasised nowadays because of the direct threat they represent for human health. Traditional remediation methods fre- quently present low efficiency and high costs; therefore, biological treatment is being considered as an accessible and efficient alternative for soil and water remediation. Bioventing, commonly used to remediate petroleum hydrocarbon spills, stimulates the degradation capacity of indigenous microorganisms by providing better subsur- face oxygenation. In Brazil, gasoline and ethanol are mixed (78:22 v/v); some authors indicate that despite gasoline high degradability, its degradation in subsurface is hin- dered by the presence of much more rapidly degrading ethanol. Contaminant distribu- tion and degradation in the subsurface can be monitored by several physical, chemical and microbiological methodologies. This study aims to evaluate and follow the degra- dation of a gasoline-ethanol mixture in a residual undisturbed tropical soil from Rio de Janeiro. Bioventing was used to enhance microbial degradation. Shifts in bacte- rial culturable populations due to contamination and treatment effects were followed by conventional microbiology methods. Ground Penetrating Radar (GPR) measure- ments, which consist of the emission of electro-magnetic waves into the soil, yield a visualisation of contaminant degradation because of changes in soil conductivity due to microbial action on the pollutants. Chemical analyses will measure contaminant residue in soil. Our results disclosed contamination impact as well as bioventing stim- ulation on soil culturable heterotrophic bacterial populations. This multidisciplinary approach allows for a wider evaluation of processes occurring in soil.

MEMBRANE BIOTREATMENT OF VOC-LADEN AIR

Science.gov (United States)

The paper discusses membrane biotreatment of air laden with volatile organic compounds (VOCs). Microporous flat-sheet and hollow-fiber membrane contactors were used to support air-liquid mass transfer interfaces. These modules were used in a two-step process to transfer VOCs fr...

Gasoline Reid Vapor Pressure

Science.gov (United States)

EPA regulates the vapor pressure of gasoline sold at retail stations during the summer ozone season to reduce evaporative emissions from gasoline that contribute to ground-level ozone and diminish the effects of ozone-related health problems.

Ambient Volatile Organic Compounds (VOCs) pollution in Isolo ...

African Journals Online (AJOL)

The adsorbed VOCs were desorbed with carbondisulphide (CS2) and the solution analysed using Gas Chromatography (GC) fitted with Flame Ionization Detector (FID). The results from analysis of the air samples collected showed that twenty-six (26) VOCs were captured in Isolo Industrial area. The VOCs were classified ...

Recent advances in occupational and environmental health hazards of workers exposed to gasoline compounds

Directory of Open Access Journals (Sweden)

Christopher E. Ekpenyong

2017-02-01

Full Text Available The impact of health and environmental hazards, associated with the constituents of gasoline, on occupationally exposed workers has been recorded over the past few decades. However, the scientific literature on their pathogenic potential remains incomplete, which could affect the current understanding of the associated health risks. This review provides current information based on recently improved research techniques to evaluate gasoline toxicity profiles for humans. Our current knowledge provides insight into the intricate mechanism of gasoline-induced adverse effects, including the formation of reactive metabolites via bio-activation and subsequent generation of reactive oxygen species (ROS and oxidative stress, which are involved in multiple mechanisms that are central to the aetiology of gasoline-induced toxicity. These mechanisms include covalent binding to deoxyribonucleic acid (DNA, leading to oxidative damage, tumor-suppression gene activity, and activation of pro-oncogenes. Furthermore, it results in induction of autoimmunity and local inflammatory responses, disruption of multiple neurotransmitters and immune cell function, derangement of various enzyme activities (e.g., sodiumpotassium adenosine triphosphate (Na+/K+/ATPase activity, cytochrome P450 (CYP450, nitric oxide synthase (NOS, antioxidant enzyme activities, etc., conjugation of bile, and non-specific cell membrane interaction, leading to damage of the membrane lipid bilayer and proteins. Available data suggests that exposure to gasoline or gasoline constituents have the potential to cause different types of illnesses. The data highlights the need to maintain safety measures via suitable research, medical surveillance, regulatory control, life style modification, early detection, and intervention to minimize exposure and manage suspected cases. They also present novel opportunities to design and develop effective therapeutic strategies against gasoline-induced detrimental

40 CFR 63.11087 - What requirements must I meet for gasoline storage tanks if my facility is a bulk gasoline...

Science.gov (United States)

2010-07-01

... gasoline storage tanks if my facility is a bulk gasoline terminal, pipeline breakout station, or pipeline... CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants for Source Category: Gasoline... § 63.11087 What requirements must I meet for gasoline storage tanks if my facility is a bulk gasoline...

VOC emissions chambers

Data.gov (United States)

Federal Laboratory Consortium — In order to support the development of test methods and reference materials for volatile organic compounds (VOC) emissions from building materials and furnishings,...

Gasoline engine management systems and components

CERN Document Server

2015-01-01

The call for environmentally compatible and economical vehicles necessitates immense efforts to develop innovative engine concepts. Technical concepts such as gasoline direct injection helped to save fuel up to 20 % and reduce CO2-emissions. Descriptions of the cylinder-charge control, fuel injection, ignition and catalytic emission-control systems provides comprehensive overview of today´s gasoline engines. This book also describes emission-control systems and explains the diagnostic systems. The publication provides information on engine-management-systems and emission-control regulations. Contents History of the automobile.- Basics of the gasoline engine.- Fuels.- Cylinder-charge control systems.- Gasoline injection systems over the years.- Fuel supply.- Manifold fuel injection.- Gasoline direct injection.- Operation of gasoline engines on natural gas.- Ignition systems over the years.- Inductive ignition systems.- Ignition coils.- Spark plugs.- Electronic control.- Sensors.- Electronic control unit.- Exh...

Emissions characteristics of higher alcohol/gasoline blends

International Nuclear Information System (INIS)

Gautam, M.; Martin, D.W.; Carder, D.

2000-01-01

An experimental investigation was conducted to determine the emissions characteristics of higher alcohols and gasoline (UTG96) blends. While lower alcohols (methanol and ethanol) have been used in blends with gasoline, very little work has been done or reported on higher alcohols (propanol, butanol and pentanol). Comparisons of emissions and fuel characteristics between higher alcohol/gasoline blends and neat gasoline were made to determine the advantages and disadvantages of blending higher alcohols with gasoline. All tests were conducted on a single-cylinder Waukesha Cooperative Fuel Research engine operating at steady state conditions and stoichiometric air-fuel (A/F) ratio. Emissions test were conducted at the optimum spark timing-knock limiting compression ratio combination for the particular blend being tested. The cycle emission [mass per unit time (g/h)] of CO, CO 2 and organic matter hydrocarbon equivalent (OMHCE) from the higher alcohol/gasoline blends were very similar to those from neat gasoline. Cycle emissions of NO x from the blends were higher than those from neat gasoline. However, for all the emissions species considered, the brake specific emissions (g/kW h) were significantly lower for the higher alcohol/gasoline blends than for neat gasoline. This was because the blends had greater resistance to knock and allowed higher compression ratios, which increased engine power output. The contribution of alcohols and aldehydes to the overall OMHCE emissions was found to be minimal. Cycle fuel consumption (g/h) of higher alcohol/gasoline blends was slightly higher than with neat gasoline due to the lower stoichiometric A/F ratios required by the blends. However, the brake specific fuel consumption (g/kW h) for the blends was significantly lower than that for neat gasoline. (Author)

Adsorption of VOCs on reduced graphene oxide.

Science.gov (United States)

Yu, Lian; Wang, Long; Xu, Weicheng; Chen, Limin; Fu, Mingli; Wu, Junliang; Ye, Daiqi

2018-05-01

A modified Hummer's method was adopted for the synthesis of graphene oxide (GO) and reduced graphene oxide (rGO). It was revealed that the modified method is effective for the production of GO and rGO from graphite. Transmission electron microscopy (TEM) images of GO and rGO showed a sheet-like morphology. Because of the presence of oxygenated functional groups on the carbon surface, the interlayer spacing of the prepared GO was higher than that of rGO. The presence of OH and CO groups in the Fourier transform infrared spectra (FTIR) spectrum and G-mode and 2D-mode in Raman spectra confirmed the synthesis of GO and rGO. rGO (292.6m 2 /g) showed higher surface area than that of GO (236.4m 2 /g). The prepared rGO was used as an adsorbent for benzene and toluene (model pollutants of volatile organic compounds (VOCs)) under dynamic adsorption/desorption conditions. rGO showed higher adsorption capacity and breakthrough times than GO. The adsorption capacity of rGO for benzene and toluene was 276.4 and 304.4mg/g, respectively. Desorption experiments showed that the spent rGO can be successfully regenerated by heating at 150.0°C. Its excellent adsorption/desorption performance for benzene and toluene makes rGO a potential adsorbent for VOC adsorption. Copyright © 2017. Published by Elsevier B.V.

Plant communication: mediated by individual or blended VOCs?

Science.gov (United States)

Ueda, Hirokazu; Kikuta, Yukio; Matsuda, Kazuhiko

2012-02-01

Plants emit volatile organic compounds (VOCs) as a means to warn other plants of impending danger. Nearby plants exposed to the induced VOCs prepare their own defense weapons in response. Accumulated data supports this assertion, yet much of the evidence has been obtained in laboratories under artificial conditions where, for example, a single VOC might be applied at a concentration that plants do not actually experience in nature. Experiments conducted outdoors suggest that communication occurs only within a limited distance from the damaged plants. Thus, the question remains as to whether VOCs work as a single component or a specific blend, and at which concentrations VOCs elicit insect and pathogen defenses in undamaged plants. We discuss these issues based on available literature and our recent work, and propose future directions in this field.

Health assessment of gasoline and fuel oxygenate vapors: developmental toxicity in mice.

Science.gov (United States)

Roberts, L G; Gray, T M; Marr, M C; Tyl, R W; Trimmer, G W; Hoffman, G M; Murray, F J; Clark, C R; Schreiner, C A

2014-11-01

CD-1 mice were exposed to baseline gasoline vapor condensate (BGVC) alone or to vapors of gasoline blended with methyl tertiary butyl ether (G/MTBE). Inhalation exposures were 6h/d on GD 5-17 at levels of 0, 2000, 10,000, and 20,000mg/m(3). Dams were evaluated for evidence of maternal toxicity, and fetuses were weighed, sexed, and evaluated for external, visceral, and skeletal anomalies. Exposure to 20,000mg/m(3) of BGVC produced slight reductions in maternal body weight/gain and decreased fetal body weight. G/MTBE exposure did not produce statistically significant maternal or developmental effects; however, two uncommon ventral wall closure defects occurred: gastroschisis (1 fetus at 10,000mg/m(3)) and ectopia cordis (1 fetus at 2000mg/m(3); 2 fetuses/1 litter at 10,000mg/m(3)). A second study (G/MTBE-2) evaluated similar exposure levels on GD 5-16 and an additional group exposed to 30,000mg/m(3) from GD 5-10. An increased incidence of cleft palate was observed at 30,000mg/m(3) G/MTBE. No ectopia cordis occurred in the replicate study, but a single observation of gastroschisis was observed at 30,000mg/m(3). The no observed adverse effect levels for maternal/developmental toxicity in the BGVC study were 10,000/2000mg/m(3), 20,000/20,000 for the G/MTBE study, and 10,000/20,000 for the G/MTBE-2 study. Copyright © 2014 The Authors. Published by Elsevier Inc. All rights reserved.

NOx emissions from high swirl turbulent spray flames with highly oxygenated fuels

KAUST Repository

Bohon, Myles; Roberts, William L.

2013-01-01

Combustion of fuels with fuel bound oxygen is of interest from both a practical and a fundamental viewpoint. While a great deal of work has been done studying the effect of oxygenated additives in diesel and gasoline engines, much less has been done

Gasoline surrogate modeling of gasoline ignition in a rapid compression machine and comparison to experiments

Energy Technology Data Exchange (ETDEWEB)

Mehl, M; Kukkadapu, G; Kumar, K; Sarathy, S M; Pitz, W J; Sung, S J

2011-09-15

The use of gasoline in homogeneous charge compression ignition engines (HCCI) and in duel fuel diesel - gasoline engines, has increased the need to understand its compression ignition processes under engine-like conditions. These processes need to be studied under well-controlled conditions in order to quantify low temperature heat release and to provide fundamental validation data for chemical kinetic models. With this in mind, an experimental campaign has been undertaken in a rapid compression machine (RCM) to measure the ignition of gasoline mixtures over a wide range of compression temperatures and for different compression pressures. By measuring the pressure history during ignition, information on the first stage ignition (when observed) and second stage ignition are captured along with information on the phasing of the heat release. Heat release processes during ignition are important because gasoline is known to exhibit low temperature heat release, intermediate temperature heat release and high temperature heat release. In an HCCI engine, the occurrence of low-temperature and intermediate-temperature heat release can be exploited to obtain higher load operation and has become a topic of much interest for engine researchers. Consequently, it is important to understand these processes under well-controlled conditions. A four-component gasoline surrogate model (including n-heptane, iso-octane, toluene, and 2-pentene) has been developed to simulate real gasolines. An appropriate surrogate mixture of the four components has been developed to simulate the specific gasoline used in the RCM experiments. This chemical kinetic surrogate model was then used to simulate the RCM experimental results for real gasoline. The experimental and modeling results covered ultra-lean to stoichiometric mixtures, compressed temperatures of 640-950 K, and compression pressures of 20 and 40 bar. The agreement between the experiments and model is encouraging in terms of first

40 CFR 80.141 - Interim detergent gasoline program.

Science.gov (United States)

2010-07-01

... 40 Protection of Environment 16 2010-07-01 2010-07-01 false Interim detergent gasoline program. 80... (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Detergent Gasoline § 80.141 Interim detergent gasoline... apply to: (i) All gasoline sold or transferred to a party who sells or transfers gasoline to the...

27 CFR 21.110 - Gasoline, unleaded.

Science.gov (United States)

2010-04-01

... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Gasoline, unleaded. 21.110....110 Gasoline, unleaded. Conforms to specifications as established by the American Society for Testing...-79. Any of the “seasonal and geographical” volatility classes for unleaded gasoline are considered...

Size distribution, chemical composition and oxidation reactivity of particulate matter from gasoline direct injection (GDI) engine fueled with ethanol-gasoline fuel

International Nuclear Information System (INIS)

Luo, Yueqi; Zhu, Lei; Fang, Junhua; Zhuang, Zhuyue; Guan, Chun; Xia, Chen; Xie, Xiaomin; Huang, Zhen

2015-01-01

Ethanol-gasoline blended fuels have been widely applied in markets recently, as ethanol reduces life-cycle greenhouse gas emissions and improves anti-knock performance. However, its effects on particulate matter (PM) emissions from gasoline direct injection (GDI) engine still need further investigation. In this study, the effects of ethanol-gasoline blended fuels on particle size distributions, number concentrations, chemical composition and soot oxidation activity of GDI engine were investigated. It was found that ethanol-gasoline blended fuels increased the particle number concentration in low-load operating conditions. In higher load conditions, the ethanol-gasoline was effective for reducing the particle number concentration, indicating that the chemical benefits of ethanol become dominant, which could reduce soot precursors such as large n-alkanes and aromatics in gasoline. The volatile organic mass fraction in ethanol-gasoline particulates matter was higher than that in gasoline particulate matter because ethanol reduced the amount of soot precursors during combustion and thereby reduced the elemental carbon proportions in PM. Ethanol addition also increased the proportion of small particles, which confirmed the effects of ethanol on organic composition. Ethanol-gasoline reduced the concentrations of most PAH species, except those with small aromatic rings, e.g., naphthalene. Soot from ethanol-gasoline has lower activation energy of oxidation than that from gasoline. The results in this study indicate that ethanol-gasoline has positive effects on PM emissions control, as the soot oxidation activity is improved and the particle number concentrations are reduced at moderate and high engine loads. - Highlights: • Ethanol-gasoline reduces elemental carbon in PM. • Ethanol-gasoline increases volatile organic fraction in PM. • Soot generated from ethanol-gasoline has higher oxidation activity.

VOCs elimination and health risk reduction in e-waste dismantling workshop using integrated techniques of electrostatic precipitation with advanced oxidation technologies

Energy Technology Data Exchange (ETDEWEB)

Chen, Jiangyao [State Key Laboratory of Organic Geochemistry and Guangdong Key Laboratory of Environmental Protection and Resources Utilization, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640 (China); Huang, Yong [State Key Laboratory of Organic Geochemistry and Guangdong Key Laboratory of Environmental Protection and Resources Utilization, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640 (China); University of Chinese Academy of Sciences, Beijing 100049 (China); Li, Guiying [State Key Laboratory of Organic Geochemistry and Guangdong Key Laboratory of Environmental Protection and Resources Utilization, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640 (China); An, Taicheng, E-mail: antc99@gig.ac.cn [State Key Laboratory of Organic Geochemistry and Guangdong Key Laboratory of Environmental Protection and Resources Utilization, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640 (China); Hu, Yunkun; Li, Yunlu [Guangzhou Longest Environmental Science and Technology Co., Ltd., Guangzhou 510660 (China)

2016-01-25

Highlights: • Pilot-scale investigation of VOCs removal during e-waste dismantling process. • EP-PC-ozonation integrated reactor show high and stable removal ability to VOCs. • Health risks of target VOCs decrease significantly after the treatment. - Abstract: Volatile organic compounds (VOCs) emitted during the electronic waste dismantling process (EWDP) were treated at a pilot scale, using integrated electrostatic precipitation (EP)-advanced oxidation technologies (AOTs, subsequent photocatalysis (PC) and ozonation). Although no obvious alteration was seen in VOC concentration and composition, EP technology removed 47.2% of total suspended particles, greatly reducing the negative effect of particles on subsequent AOTs. After the AOT treatment, average removal efficiencies of 95.7%, 95.4%, 87.4%, and 97.5% were achieved for aromatic hydrocarbons, aliphatic hydrocarbons, halogenated hydrocarbons, as well as nitrogen- and oxygen-containing compounds, respectively, over 60-day treatment period. Furthermore, high elimination capacities were also seen using hybrid technique of PC with ozonation; this was due to the PC unit’s high loading rates and excellent pre-treatment abilities, and the ozonation unit’s high elimination capacity. In addition, the non-cancer and cancer risks, as well as the occupational exposure cancer risk, for workers exposed to emitted VOCs in workshop were reduced dramatically after the integrated technique treatment. Results demonstrated that the integrated technique led to highly efficient and stable VOC removal from EWDP emissions at a pilot scale. This study points to an efficient approach for atmospheric purification and improving human health in e-waste recycling regions.

Gasoline from Kumkol deposit petroleum

International Nuclear Information System (INIS)

Nadirov, A.N.; Zhizhin, N.I.; Musaeva, Z.G.

1997-01-01

Samples of gasoline from petroleum of Kumkol deposit are investigated by chromatographic analysis. It is found, that gasoline is characterizing by increased content of iso-paraffin hydrocarbons. (author)

Methyl tert-butyl ether (MTBE) detected in abnormally high concentrations in postmortem blood and urine from two persons found dead inside a car containing a gasoline spill.

Science.gov (United States)

Karinen, Ritva; Vindenes, Vigdis; Morild, Inge; Johnsen, Lene; Le Nygaard, Ilah; Christophersen, Asbjørg S

2013-09-01

Two deep frozen persons, a female and a male, were found dead in a car. There had been an explosive fire inside the car which had extinguished itself. On the floor inside the car were large pools of liquid which smelled of gasoline. The autopsy findings and routine toxicological analyses could not explain the cause of death. Carboxyhemoglobin levels in the blood samples were gasoline as a fuel oxygenate. Gasoline poisoning is likely to be the cause of the death in these two cases, and MTBE can be a suitable marker of gasoline exposure, when other volatile components have vaporized. © 2013 American Academy of Forensic Sciences.

Conversion of a gasoline internal combustion engine to operate on hydrogen fuel

International Nuclear Information System (INIS)

Bates, M.; Dincer, I.

2009-01-01

This study deals with the conversion of a gasoline spark ignition internal combustion engine to operate on hydrogen fuel while producing similar power, economy and reliability as gasoline. The conversion engine will have the fuel system redesigned and ignition and fuel timing changed. Engine construction material is of great importance due to the low ignition energy of hydrogen, making aluminum a desirable material in the intake manifold and combustion chamber. The engine selected to convert is a 3400 SFI dual over head cam General Motors engine. Hydrogen reacts with metals causing hydrogen embrittlement which leads to failure due to cracking. There are standards published by American Society of Mechanical Engineers (ASME) to avoid such a problem. Tuning of the hydrogen engine proved to be challenging due to the basic tuning tools of a gasoline engine such as a wide band oxygen sensor that could not measure the 34:1 fuel air mixture needed for the hydrogen engine. Once the conversion was complete the engine was tested on a chassis dynamometer to compare the hydrogen horsepower and torque produced to that of a gasoline engine. Results showed that the engine is not operating correctly. The engine is not getting the proper amount of fuel needed for complete combustion when operated in a loaded state over 3000 rpm. The problem was found to be the use of the stock injector driver that could not deliver enough power for the proper operation of the larger CM4980 injectors. (author)

Biomass to Gasoline and Diesel Using Integrated Hydropyrolysis and Hydroconversion

Energy Technology Data Exchange (ETDEWEB)

Marker, Terry [Gas Technology Inst., Des Plaines, IL (United States); Roberts, Michael [Gas Technology Inst., Des Plaines, IL (United States); Linck, Martin [Gas Technology Inst., Des Plaines, IL (United States); Felix, Larry [Gas Technology Inst., Des Plaines, IL (United States); Ortiz-Toral, Pedro [Gas Technology Inst., Des Plaines, IL (United States); Wangerow, Jim [Gas Technology Inst., Des Plaines, IL (United States); Kraus, Larry [CRI-Criterion, Houston, TX (United States); McLeod, Celeste [CRI-Criterion, Houston, TX (United States); DelPaggio, Alan [CRI-Criterion, Houston, TX (United States); Tan, Eric [National Renewable Energy Lab. (NREL), Golden, CO (United States); Gephart, John [Johnson Timber, Hayward, WI (United States); Gromov, Dmitri [Cargill, Wayzata, MN (United States); Purtle, Ian [Cargill, Wayzata, MN (United States); Starr, Jack [Cargill, Wayzata, MN (United States); Hahn, John [Cargill, Wayzata, MN (United States); Dorrington, Paul [Aquaflow Bionomic Corporation, Nelson (New Zealand); Stevens, James [Blue Marble Biomaterials, Missoula, MT (United States); Shonnard, David [Michigan Technological Univ., Houghton, MI (United States); Maleche, Edwin [Michigan Technological Univ., Houghton, MI (United States)

2013-01-02

Cellulosic and woody biomass can be directly converted to hydrocarbon gasoline and diesel blending components through the use of integrated hydropyrolysis plus hydroconversion (IH²). The IH² gasoline and diesel blending components are fully compatible with petroleum based gasoline and diesel, contain less than 1% oxygen and have less than 1 total acid number (TAN). The IH² gasoline is high quality and very close to a drop in fuel. The DOE funding enabled rapid development of the IH² technology from initial proof-of-principle experiments through continuous testing in a 50 kg/day pilot plant. As part of this project, engineering work on IH² has also been completed to design a 1 ton/day demonstration unit and a commercial-scale 2000 ton/day IH² unit. These studies show when using IH² technology, biomass can be converted directly to transportation quality fuel blending components for the same capital cost required for pyrolysis alone, and a fraction of the cost of pyrolysis plus upgrading of pyrolysis oil. Technoeconomic work for IH² and lifecycle analysis (LCA) work has also been completed as part of this DOE study and shows IH² technology can convert biomass to gasoline and diesel blending components for less than $2.00/gallon with greater than 90% reduction in greenhouse gas emissions. As a result of the work completed in this DOE project, a joint development agreement was reached with CRI Catalyst Company to license the IH² technology. Further larger-scale, continuous testing of IH² will be required to fully demonstrate the technology, and funding for this is recommended. The IH² biomass conversion technology would reduce U.S. dependence on foreign oil, reduce the price of transportation fuels, and significantly lower greenhouse gas (GHG) emissions. It is a breakthrough for the widespread conversion of biomass to transportation fuels.

The effects of hydrous ethanol gasoline on combustion and emission characteristics of a port injection gasoline engine

OpenAIRE

Xiaochen Wang; Zhenbin Chen; Jimin Ni; Saiwu Liu; Haijie Zhou

2015-01-01

Comparative experiments were conducted on a port injection gasoline engine fueled with hydrous ethanol gasoline (E10W), ethanol gasoline (E10) and pure gasoline (E0). The effects of the engine loads and the additions of ethanol and water on combustion and emission characteristics were analyzed deeply. According to the experimental results, compared with E0, E10W showed higher peak in-cylinder pressure at high load. Increases in peak heat release rates were observed for E10W fuel at all the op...

Batteries: Lower cost than gasoline?

International Nuclear Information System (INIS)

Werber, Mathew; Fischer, Michael; Schwartz, Peter V.

2009-01-01

We compare the lifecycle costs of an electric car to a similar gasoline-powered vehicle under different scenarios of required driving range and cost of gasoline. An electric car is cost competitive for a significant portion of the scenarios: for cars of lower range and for higher gasoline prices. Electric cars with ∼150 km range are a technologically viable, cost competitive, high performance, high efficiency alternative that can presently suit the vast majority of consumers' needs.

Who Pays the Gasoline Tax?

OpenAIRE

Chernick, Howard; Reschovsky, Andrew

1997-01-01

Analyzes panel data over 11 years (both backward from 1982 and forward from 1982) to determine the average gasoline tax burden. Considers links between economic mobility, gasoline consumption, and excise tax increases.

Indirect Liquefaction of Biomass to Transportation Fuels Via Mixed Oxygenated Intermediates

Energy Technology Data Exchange (ETDEWEB)

Tan, Eric C.D.

2016-11-14

This paper presents a comparative techno-economic analysis of four emerging conversion pathways from biomass to gasoline-, jet-, and diesel-range hydrocarbons via indirect liquefaction with specific focus on pathways utilizing oxygenated intermediates. The processing steps include: biomass-to-syngas via indirect gasification, gas cleanup, conversion of syngas to alcohols/oxygenates followed by conversion of alcohols/oxygenates to hydrocarbon blendstocks via dehydration, oligomerization, and hydrogenation.

Combustion Kinetic Studies of Gasolines and Surrogates

KAUST Repository

Javed, Tamour

2016-11-01

Future thrusts for gasoline engine development can be broadly summarized into two categories: (i) efficiency improvements in conventional spark ignition engines, and (ii) development of advance compression ignition (ACI) concepts. Efficiency improvements in conventional spark ignition engines requires downsizing (and turbocharging) which may be achieved by using high octane gasolines, whereas, low octane gasolines fuels are anticipated for ACI concepts. The current work provides the essential combustion kinetic data, targeting both thrusts, that is needed to develop high fidelity gasoline surrogate mechanisms and surrogate complexity guidelines. Ignition delay times of a wide range of certified gasolines and surrogates are reported here. These measurements were performed in shock tubes and rapid compression machines over a wide range of experimental conditions (650 – 1250 K, 10 – 40 bar) relevant to internal combustion engines. Using the measured the data and chemical kinetic analyses, the surrogate complexity requirements for these gasolines in homogeneous environments are specified. For the discussions presented here, gasolines are classified into three categories: (i)\\tLow octane gasolines including Saudi Aramco’s light naphtha fuel (anti-knock index, AKI = (RON + MON)/2 = 64; Sensitivity (S) = RON – MON = 1), certified FACE (Fuels for Advanced Combustion Engines) gasoline I and J (AKI ~ 70, S = 0.7 and 3 respectively), and their Primary Reference Fuels (PRF, mixtures of n-heptane and iso-octane) and multi-component surrogates. (ii)\\t Mid octane gasolines including FACE A and C (AKI ~ 84, S ~ 0 and 1 respectively) and their PRF surrogates. Laser absorption measurements of intermediate and product species formed during gasoline/surrogate oxidation are also reported. (iii)\\t A wide range of n-heptane/iso-octane/toluene (TPRF) blends to adequately represent the octane and sensitivity requirements of high octane gasolines including FACE gasoline F and G

Gasoline ingestion: a rare cause of pancytopenia.

Science.gov (United States)

Rahman, Ifad; Narasimhan, Kanakasabai; Aziz, Shahid; Owens, William

2009-11-01

The majority of reported cases of gasoline intoxication involves inhalation or percutaneous absorption. Data are scarce on complications and outcomes after gasoline poisoning by oral ingestion. The major cause of mortality and morbidity associated with the ingestion of gasoline is related to pulmonary aspiration. Despite the high frequency of the ingestions, there is little documentation of nonpulmonary toxic effects of gasoline. After ingestion, the principal toxicity is aspiration pneumonia, but any documented extra pulmonary manifestations of this condition may be important in the overall management of these patients. We are reporting a rare case of pancytopenia along with aspiration pneumonia and multisystem organ failure in a 58-year-old male after prolonged intentional ingestion of gasoline. To our knowledge, this is the only reported case of gasoline toxicity causing pancytopenia.

40 CFR 63.11088 - What requirements must I meet for gasoline loading racks if my facility is a bulk gasoline...

Science.gov (United States)

2010-07-01

... 40 Protection of Environment 14 2010-07-01 2010-07-01 false What requirements must I meet for gasoline loading racks if my facility is a bulk gasoline terminal, pipeline breakout station, or pipeline... § 63.11088 What requirements must I meet for gasoline loading racks if my facility is a bulk gasoline...

Development of aromatic VOC control technology by electron beam hybrid

International Nuclear Information System (INIS)

Kim, Jo-Chun; Kim, Ki-Joon

2006-01-01

As a fundamental study, the decomposition of volatile organic compounds (VOCs) using electron beam (EB) irradiation has been extensively investigated. EB treatments of VOCs such as toluene and styrene are discussed. The degradation characteristics were intensively investigated under various concentrations and irradiation doses to determine and improve VOC removal efficiencies. This work illustrates that the removal efficiencies of aromatic VOCs generally increase as their concentrations decrease and the irradiation doses increase. Based on these basic studies, it was found that by-products produced from EB irradiation of VOCs would cause a secondary pollution problem. Therefore, a novel hybrid technology has been applied to control aromatic VOC emissions by annexing the catalyst technique with conventional treatment study using EB technology. The experiments were carried out using a bench-scale at first, then a pilot-scale system was followed. Toluene was selected as a typical VOC for EB hybrid control to investigate by-products, effects of ceramic and catalyst, and factors affecting overall efficiency of degradation. It was concluded that VOCs could be destroyed more effectively by a novel hybrid system than single EB irradiation. (author)

Contrasting winter and summer VOC mixing ratios at a forest site in the Western Mediterranean Basin: the effect of local biogenic emissions

Science.gov (United States)

Seco, R.; Peñuelas, J.; Filella, I.; Llusià, J.; Molowny-Horas, R.; Schallhart, S.; Metzger, A.; Müller, M.; Hansel, A.

2011-12-01

Atmospheric volatile organic compounds (VOCs) are involved in ozone and aerosol generation, thus having implications for air quality and climate. VOCs and their emissions by vegetation also have important ecological roles as they can protect plants from stresses and act as communication cues between plants and between plants and animals. In spite of these key environmental and biological roles, the reports on seasonal and daily VOC mixing ratios in the literature for Mediterranean natural environments are scarce. We conducted seasonal (winter and summer) measurements of VOC mixing ratios in an elevated (720 m a.s.l.) holm oak Mediterranean forest site near the metropolitan area of Barcelona (NE Iberian Peninsula). Methanol was the most abundant compound among all the VOCs measured in both seasons. While aromatic VOCs showed almost no seasonal variability, short-chain oxygenated VOCs presented higher mixing ratios in summer, presumably due to greater emission by vegetation and increased photochemistry, both enhanced by the high temperatures and solar radiation in summer. Isoprenoid VOCs showed the biggest seasonal change in mixing ratios: they increased by one order of magnitude in summer, as a result of the vegetation's greater physiological activity and emission rates. The maximum diurnal concentrations of ozone increased in summer too, most likely due to more intense photochemical activity and the higher levels of VOCs in the air. The daily variation of VOC mixing ratios was mainly governed by the wind regime of the mountain, as the majority of the VOC species analyzed followed a very similar diel cycle. Mountain and sea breezes that develop after sunrise advect polluted air masses to the mountain. These polluted air masses had previously passed over the urban and industrial areas surrounding the Barcelona metropolitan area, where they were enriched in NOx and in VOCs of biotic and abiotic origin. Moreover, these polluted air masses receive additional biogenic

Ignition studies of two low-octane gasolines

KAUST Repository

Javed, Tamour

2017-07-24

Low-octane gasolines (RON ∼ 50–70 range) are prospective fuels for gasoline compression ignition (GCI) internal combustion engines. GCI technology utilizing low-octane fuels has the potential to significantly improve well-to-wheel efficiency and reduce the transportation sector\\'s environmental footprint by offsetting diesel fuel usage in compression ignition engines. In this study, ignition delay times of two low-octane FACE (Fuels for Advanced Combustion Engines) gasolines, FACE I and FACE J, were measured in a shock tube and a rapid compression machine over a broad range of engine-relevant conditions (650–1200 K, 20 and 40 bar and ϕ = 0.5 and 1). The two gasolines are of similar octane ratings with anti-knock index, AKI = (RON + MON)/2, of ∼ 70 and sensitivity, S = RON–MON, of ∼ 3. However, the molecular compositions of the two gasolines are notably different. Experimental ignition delay time results showed that the two gasolines exhibited similar reactivity over a wide range of test conditions. Furthermore, ignition delay times of a primary reference fuel (PRF) surrogate (n-heptane/iso-octane blend), having the same AKI as the FACE gasolines, captured the ignition behavior of these gasolines with some minor discrepancies at low temperatures (T < 700 K). Multi-component surrogates, formulated by matching the octane ratings and compositions of the two gasolines, emulated the autoignition behavior of gasolines from high to low temperatures. Homogeneous charge compression ignition (HCCI) engine simulations were used to show that the PRF and multi-component surrogates exhibited similar combustion phasing over a wide range of engine operating conditions.

Gasolimp: biodegradable protector for gasoline pumps; Gasolimp: protetor biodegradavel para bomba de gasolina

Energy Technology Data Exchange (ETDEWEB)

Vinas Cortez, Juan Carlos [Universidade Federal da Paraiba (UFPB), Joao Pessoa, PB (Brazil). Dept. de Psicologia. Setor Organizacional do Trabalho

2004-07-01

It is made from an absorbent material that has natural fibers and cellulose in its composition. The polyurethane bio-foam presented excellent levels of absorption of the toxic residues left by gasoline such as carbon monoxide, hydrocarbons, oxygen, nitrogen and sulfur. All the materials used in the composition of Gasolimp are biodegradable. After a four-year research period we found out that from five to eight drops of gasoline are spilt at the moment that car pump is being filled up and they end up either in the cloth the attendant holds in his hand, on his hand, on his clothes, on the car paint or on the soil. The research shows that the toxic effects the gasoline hydrocarbons cause health problems to the attendants such as headaches, lesions on their hands and eyes, dizziness, gastro-intestine problems, heart palpitation, breathing problems and can even affect the central nerve system. The final use of the product has the utmost importance: after thirty days of use Gasolimp must be replaced and when re-used it may be sent to mills and earthenware factories and there it will function as a product that will co-generate power. (author)

Association of Land Use With Detections of VOCs, Pesticides, and Nitrate in Untreated Groundwater Used for Drinking Water in the United States, 1992-99

Science.gov (United States)

Squillace, P. J.; Moran, M. J.

2001-05-01

Between 1992 and 1999, samples of untreated groundwater from 1,497 drinking-water wells were analyzed as part of the National Water-Quality Assessment Program of the U.S. Geological Survey. Well depths ranged from 1.8 to 823 m, with a median depth of 46 m. Domestic wells (1255) had a median well depth of 43 m, and public supply wells (242) had a median depth of 77 m. Up to 144 compounds were analyzed for each sample. Seventy percent of the samples contained at least one volatile organic compound (VOC), pesticide, or anthropogenic nitrate---conservatively assuming concentrations of nitrate >= 3 mg/L were from an anthropogenic source. The total concentration of VOCs and pesticides ranged from about 0.001 to 100 μ g/L, with a median of 0.02 μ g/L. About 12% of the samples exceeded health criteria, primarily due to nitrate concentrations exceeding the Maximum Contaminant Level of 10 mg/L. Almost half (46%) of the samples contained a mixture of two compounds; and 33% contained at least three compounds. There were 402 common mixtures; each mixture was detected in at least one percent of the samples. Although VOCs were detected more frequently (44%) than pesticides (38%) or anthropogenic nitrate (28%), the top 100 common mixtures consisted primarily of persistent pesticides and nitrate, which frequently are applied either together, or sequentially on row crops. VOCs, on the other hand, tended to co-occur with a wider variety of compounds and were common in the remaining 302 mixtures. Groundwater samples with VOCs, pesticides, anthropogenic nitrate, or at least one of the common mixtures of these compounds were associated with areas of higher population density compared to samples without these compounds. The common mixtures had higher concentrations of VOCs, pesticides, and nitrate, and were associated with more intense land development (urban areas, cultivated land, or orchards). Well type, well depth, dissolved oxygen, and aquifer type were tested for their

Understanding gasoline pricing in Canada

International Nuclear Information System (INIS)

2001-04-01

This brochure is designed to help consumers understand how gasoline is priced and explained why prices increase, fluctuate and vary by location, city or region. The price of a litre of gasoline reflects the costs of crude oil, refining, retailing and taxes. Taxes are usually the largest single component of gasoline prices, averaging 40 to 50 per cent of the pump price. The cost of crude oil makes up another 35 to 45 per cent of the price. Refining costs make up 10 to 15 per cent while the remaining 5 to 10 per cent represents retail costs. Gasoline retailers make a profit of about 1 cent per litre. The latest network technology allows national and regional retail chains to constantly monitor price fluctuations to change their prices at gasoline stations at a moments notice to keep up with the competition and to protect their market shares. Several government studies, plus the Conference Board of Canada, have reported that competition is working in favour of Canadian motorists. This brochure also explained the drawbacks of regulating crude and pump prices with the reminder that crude prices were regulated in the 1970s with many negative consequences. 2 tabs., 1 fig

Influence of adhesive bonding on quantity of emissions VOCs

Directory of Open Access Journals (Sweden)

Petr Čech

2008-01-01

Full Text Available The study deals with the influence of urea-formaldehyde glue and veneered bolstering on technological operation veneering on quantity of emission VOCs (volatile organic compounds.The so-called Volatile Organic Compounds (VOC are among the largest pollution sources of both the internal and external environments.VOC is defined as emission of any organic compound or a mixture thereof, with the exception of methane, whereby the compound exerts the pressure of 0.01 kPa or more at the temperature of 20 °C (293.15 K and reaches the corresponding volatility under the specific conditions of its use and can undergo photochemical reactions with nitrogen oxides when exposed to solar radiation.The effects of VOC upon environment can be described by equation:VOC + NOx + UV radiation + heat = tropospheric ozone (O3.In this work there were tested background working environment in various parts of multi-storeyed press, next was judged emissive charge of veneered device and used glue. We used surface material such as chipboard. We used urea-formaldehyde glue KRONOCOL U300 on technological operation veneering.The VOC emissions from the wooden surfaces with or without finishing were tested in the Equipment for VOC Measuring with a small-space chamber. This equipment was installed in and made available by the Institute of Furniture, Design and Habitation. The small-space chamber is suitable for testing small parts of wood products. The device equipped with small-chamber satisfies all conditions mandated in the standard ENV 13 419 DIN -V-ENV 13 419 ”Determination of the emissions of Volatile organic compounds”.The VOC emissions were collected in columns with sorbent Tenax TA. We analyzed the columns with the VOC emissions by: the gas chromatography in conjunction with mass spectrometer and Direct Thermal Desorption.

Direct measurement of VOC diffusivities in tree tissues

DEFF Research Database (Denmark)

Baduru, K.K.; Trapp, Stefan; Burken, Joel G.

2008-01-01

Recent discoveries in the phytoremediation of volatile organic compounds (VOCs) show that vapor-phase transport into roots leads to VOC removal from the vadose zone and diffusion and volatilization out of plants is an important fate following uptake. Volatilization to the atmosphere constitutes one...... in numerous vegetation−VOC interactions, including the phytoremediation of soil vapors and dissolved aqueous-phase contaminants. The diffusion of VOCs through freshly excised tree tissue was directly measured for common groundwater contaminants, chlorinated compounds such as trichloroethylene, perchloroethene......, and tetrachloroethane and aromatic hydrocarbons such as benzene, toluene, and methyl tert-butyl ether. All compounds tested are currently being treated at full scale with tree-based phytoremediation. Diffusivities were determined by modeling the diffusive transport data with a one-dimensional diffusive flux model...

Removal of gasoline vapors from air streams by biofiltration

Energy Technology Data Exchange (ETDEWEB)

Apel, W.A.; Kant, W.D.; Colwell, F.S.; Singleton, B.; Lee, B.D.; Andrews, G.F.; Espinosa, A.M.; Johnson, E.G.

1993-03-01

Research was performed to develop a biofilter for the biodegradation of gasoline vapors. The overall goal of this effort was to provide information necessary for the design, construction, and operation of a commercial gasoline vapor biofilter. Experimental results indicated that relatively high amounts of gasoline vapor adsorption occur during initial exposure of the biofilter bed medium to gasoline vapors. Biological removal occurs over a 22 to 40{degrees}C temperature range with removal being completely inhibited at 54{degrees}C. The addition of fertilizer to the relatively fresh bed medium used did not increase the rates of gasoline removal in short term experiments. Microbiological analyses indicated that high levels of gasoline degrading microbes are naturally present in the bed medium and that additional inoculation with hydrocarbon degrading cultures does not appreciably increase gasoline removal rates. At lower gasoline concentrations, the vapor removal rates were considerably lower than those at higher gasoline concentrations. This implies that system designs facilitating gasoline transport to the micro-organisms could substantially increase gasoline removal rates at lower gasoline vapor concentrations. Test results from a field scale prototype biofiltration system showed volumetric productivity (i.e., average rate of gasoline degradation per unit bed volume) values that were consistent with those obtained with laboratory column biofilters at similar inlet gasoline concentrations. In addition, total benzene, toluene, ethyl-benzene, and xylene (BTEX) removal over the operating conditions employed was 50 to 55%. Removal of benzene was approximately 10 to 15% and removal of the other members of the BTEX group was much higher, typically >80%.

Removal of gasoline vapors from air streams by biofiltration

Energy Technology Data Exchange (ETDEWEB)

Apel, W.A.; Kant, W.D.; Colwell, F.S.; Singleton, B.; Lee, B.D.; Andrews, G.F.; Espinosa, A.M.; Johnson, E.G.

1993-03-01

Research was performed to develop a biofilter for the biodegradation of gasoline vapors. The overall goal of this effort was to provide information necessary for the design, construction, and operation of a commercial gasoline vapor biofilter. Experimental results indicated that relatively high amounts of gasoline vapor adsorption occur during initial exposure of the biofilter bed medium to gasoline vapors. Biological removal occurs over a 22 to 40[degrees]C temperature range with removal being completely inhibited at 54[degrees]C. The addition of fertilizer to the relatively fresh bed medium used did not increase the rates of gasoline removal in short term experiments. Microbiological analyses indicated that high levels of gasoline degrading microbes are naturally present in the bed medium and that additional inoculation with hydrocarbon degrading cultures does not appreciably increase gasoline removal rates. At lower gasoline concentrations, the vapor removal rates were considerably lower than those at higher gasoline concentrations. This implies that system designs facilitating gasoline transport to the micro-organisms could substantially increase gasoline removal rates at lower gasoline vapor concentrations. Test results from a field scale prototype biofiltration system showed volumetric productivity (i.e., average rate of gasoline degradation per unit bed volume) values that were consistent with those obtained with laboratory column biofilters at similar inlet gasoline concentrations. In addition, total benzene, toluene, ethyl-benzene, and xylene (BTEX) removal over the operating conditions employed was 50 to 55%. Removal of benzene was approximately 10 to 15% and removal of the other members of the BTEX group was much higher, typically >80%.

INVESTIGATION OF COMBUSTION, PERFORMANCE AND EMISSION CHARACTERISTICS OF SPARK IGNITION ENGINE FUELLED WITH BUTHANOL – GASOLINE MIXTURE AND A HYDROGEN ENRICHED AIR

Directory of Open Access Journals (Sweden)

Alfredas Rimkus

2016-09-01

Full Text Available In this study, spark ignition engine fuelled with buthanol-gasoline mixture and a hydrogen-enriched air was investigated. Engine performance, emissions and combustion characteristics were investigated with different buthanol (10% and 20% by volume gasoline mixtures and additionally supplied oxygen and hydrogen (HHO gas mixture (3.6 l/min in the sucked air. Hydrogen, which is in the HHO gas, improves gasoline and gasoline-buthanol mixture combustion, increases indicated pressure during combustion phase and decreases effective specific fuel consumption. Buthanol addition decreases the rate of heat release, the combustion temperature and pressure are lower which have an influence on lower nitrous oxide (NOx emission in exhaust gases. Buthanol lowers hydrocarbon (HC formation, but it increases carbon monoxide (CO concentration and fuel consumption. Combustion process analysis was carried out using AVL BOOST software. Experimental research and combustion process numerical simulation showed that using balanced buthanol and hydrogen addition, optimal efficient and ecological parameters could be achieved when engine is working with optimal spark timing, as it would work on gasoline fuel.

Gasoline from biomass through refinery-friendly carbohydrate-based bio-oil produced by ketalization.

Science.gov (United States)

Batalha, Nuno; da Silva, Alessandra V; de Souza, Matheus O; da Costa, Bruna M C; Gomes, Elisa S; Silva, Thiago C; Barros, Thalita G; Gonçalves, Maria L A; Caramão, Elina B; dos Santos, Luciana R M; Almeida, Marlon B B; de Souza, Rodrigo O M A; Lam, Yiu L; Carvalho, Nakédia M F; Miranda, Leandro S M; Pereira, Marcelo M

2014-06-01

The introduction of biomass-derived compounds as an alternative feed into the refinery structure that already exists can potentially converge energy uses with ecological sustainability. Herein, we present an approach to produce a bio-oil based on carbohydrate-derived isopropylidene ketals obtained by reaction with acetone under acidic conditions directly from second-generation biomass. The obtained bio-oil showed a greater chemical inertness and miscibility with gasoil than typical bio-oil from fast pyrolysis. Catalytic upgrading of the bio-oil over zeolites (USY and Beta) yielded gasoline with a high octane number. Moreover, the co-processing of gasoil and bio-oil improved the gasoline yield and quality compared to pure gasoil and also reduced the amount of oxygenated compounds and coke compared with pure bio-oil, which demonstrates a synergistic effect. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Effects of gasoline and ethanol-gasoline exhaust exposure on human bronchial epithelial and natural killer cells in vitro.

Science.gov (United States)

Roth, Michèle; Usemann, Jakob; Bisig, Christoph; Comte, Pierre; Czerwinski, Jan; Mayer, Andreas C R; Beier, Konstantin; Rothen-Rutishauser, Barbara; Latzin, Philipp; Müller, Loretta

2017-12-01

Air pollution exposure, including passenger car emissions, may cause substantial respiratory health effects and cancer death. In western countries, the majority of passenger cars are driven by gasoline fuel. Recently, new motor technologies and ethanol fuels have been introduced to the market, but potential health effects have not been thoroughly investigated. We developed and verified a coculture model composed of bronchial epithelial cells (ECs) and natural killer cells (NKs) mimicking the human airways to compare toxic effects between pure gasoline (E0) and ethanol-gasoline-blend (E85, 85% ethanol, 15% gasoline) exhaust emitted from a flexfuel gasoline car. We drove a steady state cycle, exposed ECs for 6h and added NKs. We assessed exhaust effects in ECs alone and in cocultures by RT-PCR, flow cytometry, and oxidative stress assay. We found no toxic effects after exposure to E0 or E85 compared to air controls. Comparison between E0 and E85 exposure showed a weak association for less oxidative DNA damage after E85 exposure compared to E0. Our results indicate that short-term exposure to gasoline exhaust may have no major toxic effects in ECs and NKs and that ethanol as part of fuel for gasoline cars may be favorable. Copyright © 2017 Elsevier Ltd. All rights reserved.

Performance and exhaust emissions of a gasoline engine with ethanol blended gasoline fuels using artificial neural network

Energy Technology Data Exchange (ETDEWEB)

Najafi, G.; Ghobadian, B.; Tavakoli, T.; Faizollahnejad, M. [Tarbiat Modares University, Jalale-E-Aleahmad Highway, Tehran, P.O. Box: 14115-111 (Iran); Buttsworth, D.R.; Yusaf, T.F. [University of Southern Queensland, Toowoomba, 4350 QLD (Australia)

2009-05-15

The purpose of this study is to experimentally analyse the performance and the pollutant emissions of a four-stroke SI engine operating on ethanol-gasoline blends of 0%, 5%, 10%, 15% and 20% with the aid of artificial neural network (ANN). The properties of bioethanol were measured based on American Society for Testing and Materials (ASTM) standards. The experimental results revealed that using ethanol-gasoline blended fuels increased the power and torque output of the engine marginally. For ethanol blends it was found that the brake specific fuel consumption (bsfc) was decreased while the brake thermal efficiency ({eta}{sub b.th.}) and the volumetric efficiency ({eta}{sub v}) were increased. The concentration of CO and HC emissions in the exhaust pipe were measured and found to be decreased when ethanol blends were introduced. This was due to the high oxygen percentage in the ethanol. In contrast, the concentration of CO{sub 2} and NO{sub x} was found to be increased when ethanol is introduced. An ANN model was developed to predict a correlation between brake power, torque, brake specific fuel consumption, brake thermal efficiency, volumetric efficiency and emission components using different gasoline-ethanol blends and speeds as inputs data. About 70% of the total experimental data were used for training purposes, while the 30% were used for testing. A standard Back-Propagation algorithm for the engine was used in this model. A multi layer perception network (MLP) was used for nonlinear mapping between the input and the output parameters. It was observed that the ANN model can predict engine performance and exhaust emissions with correlation coefficient (R) in the range of 0.97-1. Mean relative errors (MRE) values were in the range of 0.46-5.57%, while root mean square errors (RMSE) were found to be very low. This study demonstrates that ANN approach can be used to accurately predict the SI engine performance and emissions. (author)

FORMULATING ULTRA-LOW-VOC WOOD FURNITURE COATINGS

Science.gov (United States)

The article discusses the formulation of ultra-low volatile organic compound (VOC) wood furniture coatings. The annual U.S. market for wood coatings is about 240, 000 cu m (63 million gal). In this basis, between 57 and 91 million kg (125 and 200 million lb) of VOCs are emitted i...

Cointegration and the demand for gasoline

International Nuclear Information System (INIS)

Bhaskara Rao, B.; Rao, Gyaneshwar

2009-01-01

Since the early 1970s, there has been a worldwide upsurge in the price of energy and in particular of gasoline. Therefore, demand functions for energy and its components like gasoline have received much attention. However, since confidence in the estimated demand functions is important for use in policy and forecasting, following [Amarawickrama, H.A., Hunt, L.C., 2008. Electricity demand for Sri Lanka: A time series analysis. Energy Economics 33, 724-739], this paper estimates the demand for gasoline is estimated with five alternative time series techniques with data from Fiji. Estimates with these alternative techniques are very close, and thus increase our confidence in them. We found that gasoline demand is both price and income inelastic.

Cointegration and the demand for gasoline

Energy Technology Data Exchange (ETDEWEB)

Bhaskara Rao, B. [University of Western Sydney, Sydney1797 (Australia); Rao, Gyaneshwar [University of the South Pacific (Fiji)

2009-10-15

Since the early 1970s, there has been a worldwide upsurge in the price of energy and in particular of gasoline. Therefore, demand functions for energy and its components like gasoline have received much attention. However, since confidence in the estimated demand functions is important for use in policy and forecasting, following [Amarawickrama, H.A., Hunt, L.C., 2008. Electricity demand for Sri Lanka: A time series analysis. Energy Economics 33, 724-739], this paper estimates the demand for gasoline is estimated with five alternative time series techniques with data from Fiji. Estimates with these alternative techniques are very close, and thus increase our confidence in them. We found that gasoline demand is both price and income inelastic. (author)

40 CFR 80.540 - How may a refiner be approved to produce gasoline under the GPA gasoline sulfur standards in 2007...

Science.gov (United States)

2010-07-01

... produce gasoline under the GPA gasoline sulfur standards in 2007 and 2008? 80.540 Section 80.540... Marine Fuel Geographic Phase-in Provisions § 80.540 How may a refiner be approved to produce gasoline under the GPA gasoline sulfur standards in 2007 and 2008? (a) A refiner that has been approved by EPA...

A new bioassay for the ecotoxicological testing of VOCs on groundwater invertebrates and the effects of toluene on Niphargus inopinatus

Energy Technology Data Exchange (ETDEWEB)

Avramov, Maria; Schmidt, Susanne I. [Helmholtz Zentrum München, German Research Center for Environmental Health, Institute of Groundwater Ecology, Ingolstädter Landstrasse 1, D-85764 Neuherberg (Germany); Griebler, Christian, E-mail: christian.griebler@helmholtz-muenchen.de [Helmholtz Zentrum München, German Research Center for Environmental Health, Institute of Groundwater Ecology, Ingolstädter Landstrasse 1, D-85764 Neuherberg (Germany)

2013-04-15

Highlights: ► A new bioassay for testing the toxicity of VOCs on groundwater fauna is presented. ► Results on the toxicity of toluene to Niphargus inopinatus are now available. ► Henry equilibrium needs to be considered when bioassays with VOCs are designed. ► Methodological aspects related to “difficult-to-test substances” are discussed. -- Abstract: A protocol was developed for testing the ecotoxicological effects of volatile organic compounds (VOCs) on groundwater invertebrates. Test substance volatility was addressed in a “closed from start to analysis”-design. Since manifestation of toxic effects may be delayed in ‘slower metabolizing’ organisms such as groundwater fauna, a time-independent (TI-) approach was adopted. Toluene was used as a model substance and its toxicity to the groundwater amphipod Niphargus inopinatus was assessed as an example. The method evaluation process considered various methodological issues such as partitioning of the toxicant between the water and the gas phase (Henry equilibrium), the possible depletion of oxygen in closed test vials, as well as microbial biodegradation of the test substance. For N. inopinatus, an LC{sub 50},{sub 14} {sub days} of 46.6 mg L{sup −1} toluene was obtained. The ultimate LC{sub 50} value was estimated at 23.3 mg L{sup −1} toluene. No oxygen depletion occurred in the test vials and Henry equilibrium was found to be established after 6 h. The new test system proposed now awaits broad practical application.

Locating industrial VOC sources with aircraft observations

International Nuclear Information System (INIS)

Toscano, P.; Gioli, B.; Dugheri, S.; Salvini, A.; Matese, A.; Bonacchi, A.; Zaldei, A.; Cupelli, V.; Miglietta, F.

2011-01-01

Observation and characterization of environmental pollution, focussing on Volatile Organic Compounds (VOCs), in a high-risk industrial area, are particularly important in order to provide indications on a safe level of exposure, indicate eventual priorities and advise on policy interventions. The aim of this study is to use the Solid Phase Micro Extraction (SPME) method to measure VOCs, directly coupled with atmospheric measurements taken on a small aircraft environmental platform, to evaluate and locate the presence of VOC emission sources in the Marghera industrial area. Lab analysis of collected SPME fibres and subsequent analysis of mass spectrum and chromatograms in Scan Mode allowed the detection of a wide range of VOCs. The combination of this information during the monitoring campaign allowed a model (Gaussian Plume) to be implemented that estimates the localization of emission sources on the ground. - Highlights: → Flight plan aimed at sampling industrial area at various altitudes and locations. → SPME sampling strategy was based on plume detection by means of CO 2 . → Concentrations obtained were lower than the limit values or below the detection limit. → Scan mode highlighted presence of γ-butyrolactone (GBL) compound. → Gaussian dispersion modelling was used to estimate GBL source location and strength. - An integrated strategy based on atmospheric aircraft observations and dispersion modelling was developed, aimed at estimating spatial location and strength of VOC point source emissions in industrial areas.

Successful outcome after intravenous gasoline injection.

Science.gov (United States)

Domej, Wolfgang; Mitterhammer, Heike; Stauber, Rudolf; Kaufmann, Peter; Smolle, Karl Heinz

2007-12-01

Gasoline, ingested intentionally or accidentally, is toxic. The majority of reported cases of gasoline intoxication involve oral ingestion or inhalation. Data are scarce on complications and outcomes following hydrocarbon poisoning by intravenous injection. Following a suicide attempt by intravenous self-injection of 10 ml of gasoline, a 26-year-old medical student was admitted to the intensive care unit (ICU) with hemoptysis, symptoms of acute respiratory failure, chest pain, and severe abdominal cramps. Gas exchange was severely impaired and a chest x-ray indicated chemical pneumonitis. Initial treatment consisted of mechanical ventilation, supportive hyperventilation, administration of nitrogen oxide (NO), and prednisone. Unfortunately, the patient developed multi-organ dysfunction syndrome (MODS) complicated by life-threatening severe vasoplegia within 24 hours after gasoline injection. High doses of vasopressors along with massive amounts of parenteral fluids were necessary. Despite fluid replacement, renal function worsened and required hemofiltration on 5 sequential days. After 12 days of intensive care management, the patient recovered completely and was discharged to a psychiatric care facility. Intravenous gasoline injection causes major injury to the lungs, the organ bearing the first capillary bed encountered. Treatment of gasoline poisoning is symptomatic because no specific antidote is available. Early and aggressive supportive care may be conducive to a favorable outcome with minimal residual pulmonary sequelae.

A gas sensor array for the simultaneous detection of multiple VOCs.

Science.gov (United States)

Zhang, Yumin; Zhao, Jianhong; Du, Tengfei; Zhu, Zhongqi; Zhang, Jin; Liu, Qingju

2017-05-16

Air quality around the globe is declining and public health is seriously threatened by indoor air pollution. Typically, indoor air pollutants are composed of a series of volatile organic compounds (VOCs) that are generally harmful to the human body, especially VOCs with low molecular weights (less than 100 Da). Moreover, in some situations, more than one type of VOC is present; thus, a device that can detect one or more VOCs simultaneously would be most beneficial. Here, we synthesized a sensor array with 4 units to detect 4 VOCs: acetone (unit 1), benzene (unit 2), methanol (unit 3) and formaldehyde (unit 4) simultaneously. All units were simultaneously exposed to 2.5 ppm of all four VOCs. The sensitivity of unit 1 was 14.67 for acetone and less than 2.54 for the other VOCs. The sensitivities of units 2, 3 and 4 to benzene, methanol and formaldehyde were 2 18.64, 20.98 and 17.26, respectively, and less than 4.01 for the other VOCs. These results indicated that the sensor array exhibited good selectivity and could be used for the real-time monitoring of indoor air quality. Thus, this device will be useful in situations requiring the simultaneous detection of multiple VOCs.

VOCs and odors: key factors in selecting `green` building materials?

Energy Technology Data Exchange (ETDEWEB)

Coombs, C. [Steven Winter Associates Inc., Norwalk, CT and Washington DC (United States)

1998-12-01

The current state of knowledge available for selecting building materials on the basis of emissions of volatile organic compounds (VOCs) and odors is reviewed. The significance of VOCs and odors in building materials is related to their role in influencing indoor air quality. As far as toxicity is concerned, many of the VOCs detected in indoor air are relatively inert when considered singly. They are not however, unimportant because in actual fact they are invariably found in mixtures some of which can be toxic. Although knowledge of VOCs is incomplete, it is important to specify ozone-resistant polymeric building products, i.e. those that are chemically stable and inert to oxidation. In addition to VOCs, attention should also be focused on semi-volatile organic compounds (SVOCs) since they are even more persistent than VOCs and tend to offgas for prolonged periods of time. Similarly, it is reasonable to specify low-odor materials. Inclusion of issues related to complex indoor chemistry, less volatile emissions, in addition to VOCs and odor, should in time result in expanded choices of building materials that promote indoor air quality. 16 refs.,2 tabs.

40 CFR 79.32 - Motor vehicle gasoline.

Science.gov (United States)

2010-07-01

... 40 Protection of Environment 16 2010-07-01 2010-07-01 false Motor vehicle gasoline. 79.32 Section...) REGISTRATION OF FUELS AND FUEL ADDITIVES Designation of Fuels and Additives § 79.32 Motor vehicle gasoline. (a) The following fuels commonly or commercially known or sold as motor vehicle gasoline are hereby...

Toxicological Assessments of Rats Exposed Prenatally to Inhaled Vapors of Gasoline and Gasoline-Ethanol Blends

Science.gov (United States)

The primary alternative to petroleum-based fuels is ethanol, which is blended with gasoline in the United States at concentrations up to 15% for most automobiles. Efforts to increase the amount of ethanol in gasoline have prompted concerns about the potential toxicity of inhaled ...

Contrasting winter and summer VOC mixing ratios at a forest site in the Western Mediterranean Basin: the effect of local biogenic emissions

Directory of Open Access Journals (Sweden)

R. Seco

2011-12-01

Full Text Available Atmospheric volatile organic compounds (VOCs are involved in ozone and aerosol generation, thus having implications for air quality and climate. VOCs and their emissions by vegetation also have important ecological roles as they can protect plants from stresses and act as communication cues between plants and between plants and animals. In spite of these key environmental and biological roles, the reports on seasonal and daily VOC mixing ratios in the literature for Mediterranean natural environments are scarce.

We conducted seasonal (winter and summer measurements of VOC mixing ratios in an elevated (720 m a.s.l. holm oak Mediterranean forest site near the metropolitan area of Barcelona (NE Iberian Peninsula. Methanol was the most abundant compound among all the VOCs measured in both seasons. While aromatic VOCs showed almost no seasonal variability, short-chain oxygenated VOCs presented higher mixing ratios in summer, presumably due to greater emission by vegetation and increased photochemistry, both enhanced by the high temperatures and solar radiation in summer. Isoprenoid VOCs showed the biggest seasonal change in mixing ratios: they increased by one order of magnitude in summer, as a result of the vegetation's greater physiological activity and emission rates. The maximum diurnal concentrations of ozone increased in summer too, most likely due to more intense photochemical activity and the higher levels of VOCs in the air.

The daily variation of VOC mixing ratios was mainly governed by the wind regime of the mountain, as the majority of the VOC species analyzed followed a very similar diel cycle. Mountain and sea breezes that develop after sunrise advect polluted air masses to the mountain. These polluted air masses had previously passed over the urban and industrial areas surrounding the Barcelona metropolitan area, where they were enriched in NO_x and in VOCs of biotic and abiotic origin. Moreover, these

Fighting against VOC emissions; Lutter contre les emissions de COV

Energy Technology Data Exchange (ETDEWEB)

Fanlo, J.L. [Ecole des Mines d' Ales, 30 (France); Puech, G. [APAVE, 75 - Paris (France); Patoux, R. [Rhodia Rhoditech (France)] [and others

2001-12-01

This document brings together 15 testimonies of experts about the processes used in the industry for the abatement of volatile organic compound (VOC) emissions. The different points approached concern: the first industrial experiments of fight against VOC emissions, how to audit the facilities, how to make a diagnosis, to hierarchized and to measure continuously VOC emissions, how to anticipate the explosion risks linked with VOC treatment processes, the techniques of VOC abatement at the source implemented by industrialists, the implementation of an emission mastery scheme by Crow Cork and Seal company, the implementation of a solvent management plan by Turbomeca company and of a paints strategy by Renault car-making company, the combination of VOC abatement techniques implemented by industrialists, the classification of destruction and recovery processes: the experience feedback of Sanofi Synthelabo and of Air Liquide companies, the combination of upstream and downstream techniques implemented by Pechiney Rhenalu, Ashland Polyester and Quebecor companies. (J.S.)

Hydrogen production by onboard gasoline processing – Process simulation and optimization

Energy Technology Data Exchange (ETDEWEB)

Bisaria, Vega; Smith, R.J. Byron,

2013-12-15

Highlights: • Process flow sheet for an onboard fuel processor for 100 kW fuel cell output was simulated. • Gasoline fuel requirement was found to be 30.55 kg/hr. • The fuel processor efficiency was found to be 95.98%. • An heat integrated optimum flow sheet was developed. - Abstract: Fuel cell vehicles have reached the commercialization stage and hybrid vehicles are already on the road. While hydrogen storage and infrastructure remain critical issues in stand alone commercialization of the technology, researchers are developing onboard fuel processors, which can convert a variety of fuels into hydrogen to power these fuel cell vehicles. The feasibility study of a 100 kW on board fuel processor based on gasoline fuel is carried out using process simulation. The steady state model has been developed with the help of Aspen HYSYS to analyze the fuel processor and total system performance. The components of the fuel processor are the fuel reforming unit, CO clean-up unit and auxiliary units. Optimization studies were carried out by analyzing the influence of various operating parameters such as oxygen to carbon ratio, steam to carbon ratio, temperature and pressure on the process equipments. From the steady state model optimization using Aspen HYSYS, an optimized reaction composition in terms of hydrogen production and carbon monoxide concentration corresponds to: oxygen to carbon ratio of 0.5 and steam to carbon ratio of 0.5. The fuel processor efficiency of 95.98% is obtained under these optimized conditions. The heat integration of the system using the composite curve, grand composite curve and utility composite curve were studied for the system. The most appropriate heat exchanger network from the generated ones was chosen and that was incorporated into the optimized flow sheet of the100 kW fuel processor. A completely heat integrated 100 kW fuel processor flow sheet using gasoline as fuel was thus successfully simulated and optimized.

Hydrogen production by onboard gasoline processing – Process simulation and optimization

International Nuclear Information System (INIS)

Bisaria, Vega; Smith, R.J. Byron

2013-01-01

Highlights: • Process flow sheet for an onboard fuel processor for 100 kW fuel cell output was simulated. • Gasoline fuel requirement was found to be 30.55 kg/hr. • The fuel processor efficiency was found to be 95.98%. • An heat integrated optimum flow sheet was developed. - Abstract: Fuel cell vehicles have reached the commercialization stage and hybrid vehicles are already on the road. While hydrogen storage and infrastructure remain critical issues in stand alone commercialization of the technology, researchers are developing onboard fuel processors, which can convert a variety of fuels into hydrogen to power these fuel cell vehicles. The feasibility study of a 100 kW on board fuel processor based on gasoline fuel is carried out using process simulation. The steady state model has been developed with the help of Aspen HYSYS to analyze the fuel processor and total system performance. The components of the fuel processor are the fuel reforming unit, CO clean-up unit and auxiliary units. Optimization studies were carried out by analyzing the influence of various operating parameters such as oxygen to carbon ratio, steam to carbon ratio, temperature and pressure on the process equipments. From the steady state model optimization using Aspen HYSYS, an optimized reaction composition in terms of hydrogen production and carbon monoxide concentration corresponds to: oxygen to carbon ratio of 0.5 and steam to carbon ratio of 0.5. The fuel processor efficiency of 95.98% is obtained under these optimized conditions. The heat integration of the system using the composite curve, grand composite curve and utility composite curve were studied for the system. The most appropriate heat exchanger network from the generated ones was chosen and that was incorporated into the optimized flow sheet of the100 kW fuel processor. A completely heat integrated 100 kW fuel processor flow sheet using gasoline as fuel was thus successfully simulated and optimized

Comparative engine performance and emission analysis of CNG and gasoline in a retrofitted car engine

International Nuclear Information System (INIS)

Jahirul, M.I.; Masjuki, H.H.; Saidur, R.; Kalam, M.A.; Jayed, M.H.; Wazed, M.A.

2010-01-01

A comparative analysis is being performed of the engine performance and exhaust emission on a gasoline and compressed natural gas (CNG) fueled retrofitted spark ignition car engine. A new 1.6 L, 4-cylinder petrol engine was converted to the computer incorporated bi-fuel system which operated with either gasoline or CNG using an electronically controlled solenoid actuated valve mechanism. The engine brake power, brake specific fuel consumption, brake thermal efficiency, exhaust gas temperature and exhaust emissions (unburnt hydrocarbon, carbon mono-oxide, oxygen and carbon dioxides) were measured over a range of speed variations at 50% and 80% throttle positions through a computer based data acquisition and control system. Comparative analysis of the experimental results showed 19.25% and 10.86% reduction in brake power and 15.96% and 14.68% reduction in brake specific fuel consumption (BSFC) at 50% and 80% throttle positions respectively while the engine was fueled with CNG compared to that with the gasoline. Whereas, the retrofitted engine produced 1.6% higher brake thermal efficiency and 24.21% higher exhaust gas temperature at 80% throttle had produced an average of 40.84% higher NO x emission over the speed range of 1500-5500 rpm at 80% throttle. Other emission contents (unburnt HC, CO, O 2 and CO 2 ) were significantly lower than those of the gasoline emissions.

Life cycle assessment of gasoline and diesel

International Nuclear Information System (INIS)

Furuholt, Edgar

1995-01-01

A life cycle assessment (LCA) has been carried out to compare production and use of three different fuel products: regular gasoline, gasoline with MTBE and diesel. The study quantifies energy consumption and emissions through the production chain and assesses the potential impacts to the environment. Some of the methodological problems performing the LCA are discussed. The study indicates that production of gasoline with MTBE has potentially larger environmental impacts than production of regular gasoline, caused by the extra facilities for production of MTBE. The study also shows that the results are highly sensitive to the actual product specifications and assumptions that are made. Different product specifications can therefore lead to other conclusions. The results also indicate that production of diesel leads to significantly lower potential impacts than the gasolines

Production of high anti-knock gasoline

Energy Technology Data Exchange (ETDEWEB)

1935-09-20

A process is described for producing gasoline of high antiknock value by separating from the gasoline of low antiknock value by treating the gasoline in the vapor phase under pressure equal to or slightly above atmospheric and at a temperature at which it does not form essentially hydrocarbons gaseous at the operating temperature and in contact with catalysts, the process being characterized by the utilization of catalysts of silicates or phosphates except pumice stone and fullers earth.

Investigation of fatalities due to acute gasoline poisoning.

Science.gov (United States)

Martínez, María A; Ballesteros, Salomé

2005-10-01

This paper presents a simple, rapid, reliable, and validated method suited for forensic examination of gasoline in biological samples. The proposed methodology has been applied to the investigation of four fatal cases due to gasoline poisoning that occurred in Spain in 2003 and 2004. Case histories and pathological and toxicological findings are described in order to illustrate the danger of gasoline exposure under several circumstances. Gasoline's tissular distribution, its quantitative toxicological significance, and the possible mechanisms leading to death are also discussed. The toxicological screening and quantitation of gasoline was performed by means of gas chromatography (GC) with flame-ionization detection, and confirmation was performed using GC-mass spectrometry in total ion chromatogram mode. m,p-Xylene peak was selected to estimate gasoline in all biological samples. Gasoline analytical methodology was validated at five concentration levels from 1 to 100 mg/L. The method provided extraction recoveries between 77.6% and 98.3%. The limit of detection was 0.3 mg/L, and the limit of quantitation was 1.0 mg/L. The linearity of the blood calibration curves was excellent with r2 values of > 0.997. Intraday and interday precisions had a coefficient of variation inhalation of gasoline vapor inside a small enclosed space. Case 3 is a death by recreational gasoline inhalation in a male adolescent. Heart blood concentrations were 28.4, 18.0, and 38.3 mg/L, respectively; liver concentrations were 41.4, 52.9, and 124.2 mg/kg, respectively; and lung concentrations were 5.6, 8.4, and 39.3 mg/kg, respectively. Case 4 was an accidental death due to gasoline ingestion of a woman with senile dementia. Peripheral blood concentration was 122.4 mg/L, the highest in our experience. Because pathological findings were consistent with other reports of gasoline intoxication and constituents of gasoline were found in the body, cause of death was attributed to acute gasoline

46 CFR 169.613 - Gasoline fuel systems.

Science.gov (United States)

2010-10-01

... 46 Shipping 7 2010-10-01 2010-10-01 false Gasoline fuel systems. 169.613 Section 169.613 Shipping... Machinery and Electrical Fuel Systems § 169.613 Gasoline fuel systems. (a) Except as provided in paragraph (b) each gasoline fuel system must meet the requirements of § 56.50-70 of this chapter (b) Each...

The US gasoline situation and crude oil prices

International Nuclear Information System (INIS)

Anon.

2004-01-01

Before and during the United States' summer driving season, concern over the country's gasoline supply can potentially influence the direction of the petroleum market. There are three causes of concern: a persistent lack of gasoline-producing capacity; a patchwork of as many as 18 different kinds of gasoline specifications; and the introduction of stringent new specifications for reformulated gasoline. However, gasoline stocks should be able to meet the needs of this year's driving season, at a time of ample crude oil availability, with strong imports. But, unplanned outages in the US logistics system and refining centres, or major disruptions in external gasoline supplies, could trigger price spikes that would, in turn, lead to frequently stronger crude oil prices, especially with the observed robust oil demand growth in China. (Author)

Gasoline Prices and Their Relationship to Drunk-Driving Crashes

OpenAIRE

Guangqing Chi; Xuan Zhou; Timothy McClure; Paul Gilbert; Arthur Cosby; Li Zhang; Angela Robertson; David Levinson

2010-01-01

This study investigates the relationship between changing gasoline prices and drunk-driving crashes. Specifically, we examine the effects of gasoline prices on drunk-driving crashes in Mississippi by age, gender, and race from 2004Ð2008, a period experiencing great fluctuation in gasoline prices. An exploratory visualization by graphs shows that higher gasoline prices are generally associated with fewer drunk-driving crashes. Higher gasoline prices depress drunk- driving crashes among younger...

Thermodynamic analysis of fuels in gas phase: ethanol, gasoline and ethanol - gasoline predicted by DFT method.

Science.gov (United States)

Neto, A F G; Lopes, F S; Carvalho, E V; Huda, M N; Neto, A M J C; Machado, N T

2015-10-01

This paper presents a theoretical study using density functional theory to calculate thermodynamics properties of major molecules compounds at gas phase of fuels like gasoline, ethanol, and gasoline-ethanol mixture in thermal equilibrium on temperature range up to 1500 K. We simulated a composition of gasoline mixture with ethanol for a thorough study of thermal energy, enthalpy, Gibbs free energy, entropy, heat capacity at constant pressure with respect to temperature in order to study the influence caused by ethanol as an additive to gasoline. We used semi-empirical computational methods as well in order to know the efficiency of other methods to simulate fuels through this methodology. In addition, the ethanol influence through the changes in percentage fractions of chemical energy released in combustion reaction and the variations on thermal properties for autoignition temperatures of fuels was analyzed. We verified how ethanol reduces the chemical energy released by gasoline combustion and how at low temperatures the gas phase fuels in thermal equilibrium have similar thermodynamic behavior. Theoretical results were compared with experimental data, when available, and showed agreement. Graphical Abstract Thermodynamic analysis of fuels in gas phase.

26 CFR 48.4081-6 - Gasoline; gasohol.

Science.gov (United States)

2010-04-01

... 26 Internal Revenue 16 2010-04-01 2010-04-01 true Gasoline; gasohol. 48.4081-6 Section 48.4081-6... Fuel Taxable Fuel § 48.4081-6 Gasoline; gasohol. (a) Overview. This section provides rules for determining the applicability of reduced rates of tax on a removal or entry of gasohol or of gasoline used to...

Gasoline toxicology: overview of regulatory and product stewardship programs.

Science.gov (United States)

Swick, Derek; Jaques, Andrew; Walker, J C; Estreicher, Herb

2014-11-01

Significant efforts have been made to characterize the toxicological properties of gasoline. There have been both mandatory and voluntary toxicology testing programs to generate hazard characterization data for gasoline, the refinery process streams used to blend gasoline, and individual chemical constituents found in gasoline. The Clean Air Act (CAA) (Clean Air Act, 2012: § 7401, et seq.) is the primary tool for the U.S. Environmental Protection Agency (EPA) to regulate gasoline and this supplement presents the results of the Section 211(b) Alternative Tier 2 studies required for CAA Fuel and Fuel Additive registration. Gasoline blending streams have also been evaluated by EPA under the voluntary High Production Volume (HPV) Challenge Program through which the petroleum industry provide data on over 80 refinery streams used in gasoline. Product stewardship efforts by companies and associations such as the American Petroleum Institute (API), Conservation of Clean Air and Water Europe (CONCAWE), and the Petroleum Product Stewardship Council (PPSC) have contributed a significant amount of hazard characterization data on gasoline and related substances. The hazard of gasoline and anticipated exposure to gasoline vapor has been well characterized for risk assessment purposes. Copyright © 2014 The Authors. Published by Elsevier Inc. All rights reserved.

Industrial sector-based volatile organic compound (VOC) source profiles measured in manufacturing facilities in the Pearl River Delta, China.

Science.gov (United States)

Zheng, Junyu; Yu, Yufan; Mo, Ziwei; Zhang, Zhou; Wang, Xinming; Yin, Shasha; Peng, Kang; Yang, Yang; Feng, Xiaoqiong; Cai, Huihua

2013-07-01

Industrial sector-based VOC source profiles are reported for the Pearl River Delta (PRD) region, China, based source samples (stack emissions and fugitive emissions) analyzed from sources operating under normal conditions. The industrial sectors considered are printing (letterpress, offset and gravure printing processes), wood furniture coating, shoemaking, paint manufacturing and metal surface coating. More than 250 VOC species were detected following US EPA methods TO-14 and TO-15. The results indicated that benzene and toluene were the major species associated with letterpress printing, while ethyl acetate and isopropyl alcohol were the most abundant compounds of other two printing processes. Acetone and 2-butanone were the major species observed in the shoemaking sector. The source profile patterns were found to be similar for the paint manufacturing, wood furniture coating, and metal surface coating sectors, with aromatics being the most abundant group and oxygenated VOCs (OVOCs) as the second largest contributor in the profiles. While OVOCs were one of the most significant VOC groups detected in these five industrial sectors in the PRD region, they have not been reported in most other source profile studies. Such comparisons with other studies show that there are differences in source profiles for different regions or countries, indicating the importance of developing local source profiles. Crown Copyright © 2013. Published by Elsevier B.V. All rights reserved.

Anticipation, Tax Avoidance, and the Price Elasticity of Gasoline Demand

OpenAIRE

Coglianese, John; Davis, Lucas W; Kilian, Lutz; Stock, James H

2015-01-01

Traditional least squares estimates of the responsiveness of gasoline consumption to changes in gasoline prices are biased toward zero, given the endogeneity of gasoline prices. A seemingly natural solution to this problem is to instrument for gasoline prices using gasoline taxes, but this approach tends to yield implausibly large price elasticities. We demonstrate that anticipatory behavior provides an important explanation for this result. We provide evidence that gasoline buyers increase g...

Modeling the uncertainty of several VOC and its impact on simulated VOC and ozone in Houston, Texas

Science.gov (United States)

Pan, Shuai; Choi, Yunsoo; Roy, Anirban; Li, Xiangshang; Jeon, Wonbae; Souri, Amir Hossein

2015-11-01

A WRF-SMOKE-CMAQ modeling system was used to study Volatile Organic Compound (VOC) emissions and their impact on surface VOC and ozone concentrations in southeast Texas during September 2013. The model was evaluated against the ground-level Automated Gas Chromatograph (Auto-GC) measurement data from the Texas Commission on Environmental Quality (TCEQ). The comparisons indicated that the model over-predicted benzene, ethylene, toluene and xylene, while under-predicting isoprene and ethane. The mean biases between simulated and observed values of each VOC species showed clear daytime, nighttime, weekday and weekend variations. Adjusting the VOC emissions using simulated/observed ratios improved model performance of each VOC species, especially mitigating the mean bias substantially. Simulated monthly mean ozone showed a minor change: a 0.4 ppb or 1.2% increase; while a change of more than 5 ppb was seen in hourly ozone data on high ozone days, this change moved model predictions closer to observations. The CMAQ model run with the adjusted emissions better reproduced the variability in the National Aeronautics and Space Administration (NASA)'s Ozone Monitoring Instrument (OMI) formaldehyde (HCHO) columns. The adjusted model scenario also slightly better reproduced the aircraft HCHO concentrations from NASA's DISCOVER-AQ campaign conducted during the simulation episode period; Correlation, Mean Bias and RMSE improved from 0.34, 1.38 ppb and 2.15 ppb to 0.38, 1.33 ppb and 2.08 ppb respectively. A process analysis conducted for both industrial/urban and rural areas suggested that chemistry was the main process contributing to ozone production in both areas, while the impact of chemistry was smaller in rural areas than in industrial and urban areas. For both areas, the positive chemistry contribution increased in the sensitivity simulation largely due to the increase in emissions. Nudging VOC emissions to match the observed concentrations shifted the ozone hotspots

Persulfate injection into a gasoline source zone

Science.gov (United States)

Sra, Kanwartej S.; Thomson, Neil R.; Barker, Jim F.

2013-07-01

One pore volume of unactivated sodium persulfate was delivered into an emplaced gasoline residual source zone at CFB Borden. Concentrations of inorganic species (S2O82 -, SO42 -, Na+, dissolved inorganic carbon (DIC)) and selected gasoline compounds (benzene, toluene, ethylbenzene, xylenes, trimethylbenzenes and naphthalene) were monitored across a transect equipped with 90 multilevel sampling points for > 10 months post-injection. Mass loading (M˙) of compounds constructed from the transect data was used for assessment purposes. Breakthrough of inorganic species was observed when the injection slug crossed the monitoring transect. An increase in M indicated persulfate consumption during oxidation of gasoline compounds or degradation due to the interaction with aquifer materials. M increased by > 100% suggesting some mineralization of gasoline compounds during treatment. Mass loading for all the monitored gasoline compounds reduced by 46 to 86% as the inorganic slug crossed the monitoring transect. The cumulative mass discharge across the monitoring transect was 19 to 58% lower than that expected without persulfate injection. After the inorganic injection slug was flushed from the source zone a partial rebound (40 to 80% of baseline levels) of mass discharge of the monitored gasoline compounds was observed. The ensemble of data collected provides insight into the fate and transport of the injected persulfate solution, and the accompanying treatment of a gasoline the source zone.

MVMA's 1991 summer gasoline survey and air quality

International Nuclear Information System (INIS)

Anon.

1992-01-01

In a previous newsletter (September 1991 issue of this journal), the results of MVMA's 1990 Summer Gasoline Survey were discussed. It was noted that many gasolines containing high concentrations of olefins (over 15 percent volume) were being marketed in the northeast corridor between Washington, D.C. and Boston. Also noted was the finding that the composition of gasoline plays an important role in determining the emissions from vehicles on the road. In this newsletter, the potential effects on air quality of the more recently surveyed gasolines are discussed. Three grades of unleaded gasoline were covered in the survey (premium, intermediate, and regular). 1 tab

Reducing VOC Press Emission from OSB Manufacturing

Energy Technology Data Exchange (ETDEWEB)

Dr. Gary D. McGinnis; Laura S. WIlliams; Amy E. Monte; Jagdish Rughani: Brett A. Niemi; Thomas M. Flicker

2001-12-31

Current regulations require industry to meet air emission standards with regard to particulates, volatile organic compounds (VOCs), hazardous air pollutants (HAPs) and other gases. One of many industries that will be affected by the new regulations is the wood composites industry. This industry generates VOCs, HAPs, and particulates mainly during the drying and pressing of wood. Current air treatment technologies for the industry are expensive to install and operate. As regulations become more stringent, treatment technologies will need to become more efficient and cost effective. The overall objective of this study is to evaluate the use of process conditions and chemical additives to reduce VOC/HAPs in air emitted from presses and dryers during the production of oriented strand board.

Characterization of the pharmacokinetics of gasoline using PBPK modeling with a complex mixtures chemical lumping approach.

Science.gov (United States)

Dennison, James E; Andersen, Melvin E; Yang, Raymond S H

2003-09-01

Gasoline consists of a few toxicologically significant components and a large number of other hydrocarbons in a complex mixture. By using an integrated, physiologically based pharmacokinetic (PBPK) modeling and lumping approach, we have developed a method for characterizing the pharmacokinetics (PKs) of gasoline in rats. The PBPK model tracks selected target components (benzene, toluene, ethylbenzene, o-xylene [BTEX], and n-hexane) and a lumped chemical group representing all nontarget components, with competitive metabolic inhibition between all target compounds and the lumped chemical. PK data was acquired by performing gas uptake PK studies with male F344 rats in a closed chamber. Chamber air samples were analyzed every 10-20 min by gas chromatography/flame ionization detection and all nontarget chemicals were co-integrated. A four-compartment PBPK model with metabolic interactions was constructed using the BTEX, n-hexane, and lumped chemical data. Target chemical kinetic parameters were refined by studies with either the single chemical alone or with all five chemicals together. o-Xylene, at high concentrations, decreased alveolar ventilation, consistent with respiratory irritation. A six-chemical interaction model with the lumped chemical group was used to estimate lumped chemical partitioning and metabolic parameters for a winter blend of gasoline with methyl t-butyl ether and a summer blend without any oxygenate. Computer simulation results from this model matched well with experimental data from single chemical, five-chemical mixture, and the two blends of gasoline. The PBPK model analysis indicated that metabolism of individual components was inhibited up to 27% during the 6-h gas uptake experiments of gasoline exposures.

Phase-out of leaded gasoline: a prescription for Lebanon

International Nuclear Information System (INIS)

Hashisho, Z.; El-Fadel, M.; Ayoub, G.; Baaj, H.

2000-01-01

Full text.Lead is a toxic heavy metal. Nevertheless, it has been mined and used for more than 800 years. Among the different contemporary sources of lead pollution, emissions from the combustion of leaded gasoline is of particular concern, as it can constitutes more than 90 percent of total lead emissions into the atmosphere in congested urban areas. Concentrations of lead in air and blood are strongly correlated with gasoline lead content and traffic volume. As a result of the increasing awareness about the dangers of lead to human health and the measures to manage urban air pollution, the use of leaded gasoline has been decreasing worldwide. In Lebanon, in the absence of policies to reduce the use of lead in gasoline or to favor the use of unleaded gasoline, leaded gasoline is the predominant grade. The objective of this research work is to analyze the current status of gasoline, and to assess the feasibility and prospect of such action. For this purpose, background information are presented, data about gasoline usage and specifications have been collected, field measurements have been performed and a public survey has been conducted. The comparison of the expected cost savings from phasing out leaded gasoline with the potential costs indicates that such action is economically highly justified. If effective regulatory measures are undertaken, leaded gasoline can be phased-out immediately without a significant cost

Survey of benzene and aromatics in Canadian Gasoline - 1994

International Nuclear Information System (INIS)

Tushingham, M.

1996-01-01

A comprehensive database of the benzene and aromatics levels of gasoline produced in or imported into Canada during 1994, was presented. Environment Canada conducted a survey that requested refineries and importers to report quarterly on benzene and aromatics levels in gasoline. Benzene, which has been declared toxic by the Canadian Environmental Protection Act, is found in gasoline and is formed during the combustion of the aromatic components of gasoline. It was shown that benzene and aromatics levels differ regionally and seasonally. There are also variations in benzene levels between batches of gasoline produced at any one refinery. This report listed the responses to the benzene/aromatics survey. It also described the analytical procedures used to measure benzene and aromatics levels in gasoline, and provided guidelines for reporting gasoline benzene and total aromatics data. 7 tabs., 21 figs

PTR-MS in environmental research: biogenic VOCs

International Nuclear Information System (INIS)

Beauchamp, J.; Grabmer, W.; Graus, M.; Wisthaler, A.; Hansel, A.

2004-01-01

Proton-transfer-reaction mass spectrometry (PTR-MS) is a chemical ionization mass spectrometry technique that allows for on-line measurements of volatile organic compounds (VOCs) at pptV levels. This well established analytical tool has been used in a broad variety of research, including the investigation of VOCs in various foods (e.g. for quality control or food degradation studies), as well as being used as a tool for non-invasive medical diagnostics (e.g. human breath analysis). In addition to these fields of study, PTR-MS has been widely used in environmental research, from trace gas analysis in the troposphere to VOC emissions from plants. Participation in two field campaigns (BEWA and ECHO - both part of the German AFO 2000 program) by the Institute of Ion Physics involved a variety of investigations for monitoring biogenic emissions. These included the technique of disjunct eddy covariance for flux measurements above a forest canopy, C-13 carbon labelling experiments to follow carbon use in a plant, and stress-induced VOC emission investigations to gain understanding of how plants react to stress (e.g. ozone exposure). A selection of results from these investigations will be discussed in this presentation. (author)

New evidence on the asymmetry in gasoline price: volatility versus margin?

International Nuclear Information System (INIS)

Abosedra, S.; Radchenko, S.

2006-01-01

This paper examines recent evidence on the role that gasoline margins and volatility play in the asymmetric response of gasoline prices to changes in oil prices at different stages of distribution process. In a regression model with margins, we find that margins are statistically significant in explaining asymmetry between crude oil and spot gasoline prices, spot gasoline prices and wholesale gasoline prices, and wholesale gasoline prices and retail prices. In a regression model with input volatility, we find evidence that volatility is responsible for asymmetry between wholesale gasoline prices and retail gasoline prices. When both, gasoline margins and gasoline volatility are included in the regression, we find evidence supporting margins, the search theory, volatility, the oligopolistic coordination theory and an explanation of asymmetry. (author)

Gasoline sales post minimal gain in 1986

Energy Technology Data Exchange (ETDEWEB)

1987-06-22

Despite the continuing emphasis on conservation and the growing trend to smaller sized automobiles, sales of motor gasoline across Canada posted a gain of 0.4% in 1986. Figures are included in this survey for Canadian motor gasoline sales categorized by province, type of gasoline, and months of 1985 and 1986. Sales of refiners' diesel fuel oil are also categorized by province and by months of 1985 and 1986. Motor gasoline disposition for 1983-1986 is categorized into retail pump sales, road and urban transport, agriculture, public administration, and commercial and other institutional markets. Also included are figures for refiners' propane sales for 1983-1986 by province.

Application of ion chemistry to tropospheric VOC measurements

International Nuclear Information System (INIS)

Hansel, A.; Wisthaler, A.; Graus, M.; Grabmer, W.

2002-01-01

The main interest in tropospheric volatile organic compounds (VOCs) originating from biogenic sources such as forests and anthropogenic sources such as cities is because these reactive trace gases can have a significant impact on levels of oxidants such as ozone (O 3 ) and the hydroxyl radical (OH). The proton-transfer-reaction mass-spectrometry (PTR-MS) technique developed by Werner Lindingers Laboratory, utilizes positive ion chemistry to measure trace neutral concentrations in air. It has been applied in food research, medicine and environmental studies to gain gas phase information about VOCs at parts per trillion (pptv) levels.The real-time method relies on proton transfer reactions between H 3 O + primary ions and VOCs which have a higher proton affinity than water molecules. Organic trace gases such as hydrocarbons, carbonyls, alcohols, acetonitrile, and others can be monitored on-line.Results on tropospheric VOCs measurements in tropical regions and in cities are discussed. (nevyjel)

Gasoline Prices, Transport Costs, and the U.S. Business Cycles

OpenAIRE

Hakan Yilmazkuday

2014-01-01

The e¡èects of gasoline prices on the U.S. business cycles are investigated. In order to distinguish between gasoline supply and gasoline demand shocks, the price of gasoline is endogenously determined through a transportation sector that uses gasoline as an input of production. The model is estimated for the U.S. economy using five macroeconomic time series, including data on transport costs and gasoline prices. The results show that although standard shocks in the literature (e.g., technolo...

Effect of Ce2O3, La2O3 and ZnO additives on the oxygenates conversion into liquid hydrocarbons

Science.gov (United States)

Kachalov, V. V.; Lavrenov, V. A.; Lishchiner, I. I.; Malova, O. V.; Tarasov, A. L.; Zaichenko, V. M.

2018-01-01

A selective modifying effect of cerium, magnesium and zinc oxide additives on the activity and the selectivity of a pentasil group zeolite catalyst in the reaction of conversion of oxygenates (methanol and dimethyl ether) to liquid hydrocarbons was found. It was found that zinc oxide contributes to the stable operation of the zeolite catalyst in the conversion of oxygenates in the synthesis gas stream and leads to the production of gasolines with low durene content (not more than 6.1 wt%). The obtained results demonstrate the rationale for producing hydrocarbons from synthesis gas without the stage of oxygenate separation with their subsequent conversion to synthetic gasoline.

Tiered gasoline pricing: A personal carbon trading perspective

International Nuclear Information System (INIS)

Li, Yao; Fan, Jin; Zhao, Dingtao; Wu, Yanrui; Li, Jun

2016-01-01

This paper proffers a tiered gasoline pricing method from a personal carbon trading perspective. An optimization model of personal carbon trading is proposed, and then, an equilibrium carbon price is derived according to the market clearing condition. Based on the derived equilibrium carbon price, this paper proposes a calculation method of tiered gasoline pricing. Then, sensitivity analyses and consumers' surplus analyses are conducted. It can be shown that a rise in gasoline price or a more generous allowance allocation would incur a decrease in the equilibrium carbon price, making the first tiered price higher, but the second tiered price lower. It is further verified that the proposed tiered pricing method is progressive because it would relieve the pressure of the low-income groups who consume less gasoline while imposing a greater burden on the high-income groups who consume more gasoline. Based on these results, implications, limitations and suggestions for future studies are provided. - Highlights: • Tiered gasoline pricing is calculated from the perspective of PCT. • Consumers would be burdened with different actual gasoline costs. • A specific example is provided to illustrate the calculation of TGP. • The tiered pricing mechanism is a progressive system.

Persulfate injection into a gasoline source zone.

Science.gov (United States)

Sra, Kanwartej S; Thomson, Neil R; Barker, Jim F

2013-07-01

One pore volume of unactivated sodium persulfate was delivered into an emplaced gasoline residual source zone at CFB Borden. Concentrations of inorganic species (S2O8(2-), SO4(2-), Na(+), dissolved inorganic carbon (DIC)) and selected gasoline compounds (benzene, toluene, ethylbenzene, xylenes, trimethylbenzenes and naphthalene) were monitored across a transect equipped with 90 multilevel sampling points for >10months post-injection. Mass loading (M˙) of compounds constructed from the transect data was used for assessment purposes. Breakthrough of inorganic species was observed when the injection slug crossed the monitoring transect. An increase in [Formula: see text] indicated persulfate consumption during oxidation of gasoline compounds or degradation due to the interaction with aquifer materials. M˙DIC increased by >100% suggesting some mineralization of gasoline compounds during treatment. Mass loading for all the monitored gasoline compounds reduced by 46 to 86% as the inorganic slug crossed the monitoring transect. The cumulative mass discharge across the monitoring transect was 19 to 58% lower than that expected without persulfate injection. After the inorganic injection slug was flushed from the source zone a partial rebound (40 to 80% of baseline levels) of mass discharge of the monitored gasoline compounds was observed. The ensemble of data collected provides insight into the fate and transport of the injected persulfate solution, and the accompanying treatment of a gasoline the source zone. Copyright © 2013 Elsevier B.V. All rights reserved.

Measurements of VOC adsorption/desorption characteristics of typical interior building materials

Energy Technology Data Exchange (ETDEWEB)

An, Y.; Zhang, J.S.; Shaw, C.Y.

2000-07-01

The adsorption/desorption of volatile organic compounds (VOCs) on interior building material surfaces (i.e., the sink effect) can affect the VOC concentrations in a building, and thus need to be accounted for an indoor air quality (IAQ) prediction model. In this study, the VOC adsorption/desorption characteristics (sink effect) were measured for four typical interior building materials including carpet, vinyl floor tile, painted drywall, and ceiling tile. The VOCs tested were ethylbenzene, cyclohexanone, 1,4-dichlorobenzene, benzaldehyde, and dodecane. These five VOCs were selected because they are representative of hydrocarbons, aromatics, ketones, aldehydes, and chlorine substituted compounds. The first order reversible adsorption/desorption model was based on the Langmuir isotherm was used to analyze the data and to determine the equilibrium constant of each VOC-material combination. It was found that the adsorption/desorption equilibrium constant, which is a measure of the sink capacity, increased linearly with the inverse of the VOC vapor pressure. For each compound, the adsorption/desorption equilibrium constant, and the adsorption rate constant differed significantly among the four materials tested. A detailed characterization of the material structure in the micro-scale would improve the understanding and modeling of the sink effect in the future. The results of this study can be used to estimate the impact of sink effect on the VOC concentrations in buildings.

30 CFR 57.4461 - Gasoline use restrictions underground.

Science.gov (United States)

2010-07-01

... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Gasoline use restrictions underground. 57.4461... Prevention and Control Flammable and Combustible Liquids and Gases § 57.4461 Gasoline use restrictions underground. If gasoline is used underground to power internal combustion engines— (a) The mine shall be...

40 CFR 52.787 - Gasoline transfer vapor control.

Science.gov (United States)

2010-07-01

... 40 Protection of Environment 3 2010-07-01 2010-07-01 false Gasoline transfer vapor control. 52.787... (CONTINUED) APPROVAL AND PROMULGATION OF IMPLEMENTATION PLANS Indiana § 52.787 Gasoline transfer vapor control. (a) Gasoline means any petroleum distillate having a Reid vapor pressure of 4 pounds or greater...

Development of tartaric esters as bifunctional additives of methanol-gasoline.

Science.gov (United States)

Zhang, Jie; Yang, Changchun; Tang, Ying; Zhou, Rui; Wang, Xiaoli; Xu, Lianghong

2014-01-01

Methanol has become an alternative fuel for gasoline, which is facing a rapidly rising world demand with a limited oil supply. Methanol-gasoline has been used in China, but phase stability and vapor lock still need to be resolved in methanol-gasoline applications. In this paper, a series of tartaric esters were synthesized and used as phase stabilizers and saturation vapor pressure depressors for methanol-gasoline. The results showed that the phase stabilities of tartaric esters for methanol-gasoline depend on the length of the alkoxy group. Several tartaric esters were found to be effective in various gasoline-methanol blends, and the tartaric esters display high capacity to depress the saturation vapor pressure of methanol-gasoline. According to the results, it can be concluded that the tartaric esters have great potential to be bifunctional gasoline-methanol additives.

Seasonal variability and source apportionment of volatile organic compounds (VOCs in the Paris megacity (France

Directory of Open Access Journals (Sweden)

A. Baudic

2016-09-01

Full Text Available Within the framework of air quality studies at the megacity scale, highly time-resolved volatile organic compound (C2–C8 measurements were performed in downtown Paris (urban background sites from January to November 2010. This unique dataset included non-methane hydrocarbons (NMHCs and aromatic/oxygenated species (OVOCs measured by a GC-FID (gas chromatograph with a flame ionization detector and a PTR-MS (proton transfer reaction – mass spectrometer, respectively. This study presents the seasonal variability of atmospheric VOCs being monitored in the French megacity and their various associated emission sources. Clear seasonal and diurnal patterns differed from one VOC to another as the result of their different origins and the influence of environmental parameters (solar radiation, temperature. Source apportionment (SA was comprehensively conducted using a multivariate mathematical receptor modeling. The United States Environmental Protection Agency's positive matrix factorization tool (US EPA, PMF was used to apportion and quantify ambient VOC concentrations into six different sources. The modeled source profiles were identified from near-field observations (measurements from three distinct emission sources: inside a highway tunnel, at a fireplace and from a domestic gas flue, hence with a specific focus on road traffic, wood-burning activities and natural gas emissions and hydrocarbon profiles reported in the literature. The reconstructed VOC sources were cross validated using independent tracers such as inorganic gases (NO, NO2, CO, black carbon (BC and meteorological data (temperature. The largest contributors to the predicted VOC concentrations were traffic-related activities (including motor vehicle exhaust, 15 % of the total mass on the annual average, and evaporative sources, 10 %, with the remaining emissions from natural gas and background (23 %, solvent use (20 %, wood-burning (18 % and a biogenic source (15 %. An

Volatile Organic Compound (VOC) measurements in the Pearl River Delta (PRD) region, China

Science.gov (United States)

Liu, Ying; Shao, Min; Lu, Sihua; Chang, Chih-Chung; Wang, Jia-Lin; Chen, Gao

2008-03-01

We measured levels of ambient volatile organic compounds (VOCs) at seven sites in the Pearl River Delta (PRD) region of China during the Air Quality Monitoring Campaign spanning 4 October to 3 November 2004. Two of the sites, Guangzhou (GZ) and Xinken (XK), were intensive sites at which we collected multiple daily canister samples. The observations reported here provide a look at the VOC distribution, speciation, and photochemical implications in the PRD region. Alkanes constituted the largest percentage (>40%) in mixing ratios of the quantified VOCs at six sites; the exception was one major industrial site that was dominated by aromatics (about 52%). Highly elevated VOC levels occurred at GZ during two pollution episodes; however, the chemical composition of VOCs did not exhibit noticeable changes during these episodes. We calculated the OH loss rate to estimate the chemical reactivity of all VOCs. Of the anthropogenic VOCs, alkenes played a predominant role in VOC reactivity at GZ, whereas the contributions of reactive aromatics were more important at XK. Our preliminary analysis of the VOC correlations suggests that the ambient VOCs at GZ came directly from local sources (i.e., automobiles); those at XK were influenced by both local emissions and transportation of air mass from upwind areas.

Volatile Organic Compound (VOC measurements in the Pearl River Delta (PRD region, China

Directory of Open Access Journals (Sweden)

Chih-chung Chang

2008-03-01

Full Text Available We measured levels of ambient volatile organic compounds (VOCs at seven sites in the Pearl River Delta (PRD region of China during the Air Quality Monitoring Campaign spanning 4 October to 3 November 2004. Two of the sites, Guangzhou (GZ and Xinken (XK, were intensive sites at which we collected multiple daily canister samples. The observations reported here provide a look at the VOC distribution, speciation, and photochemical implications in the PRD region. Alkanes constituted the largest percentage (>40% in mixing ratios of the quantified VOCs at six sites; the exception was one major industrial site that was dominated by aromatics (about 52%. Highly elevated VOC levels occurred at GZ during two pollution episodes; however, the chemical composition of VOCs did not exhibit noticeable changes during these episodes. We calculated the OH loss rate to estimate the chemical reactivity of all VOCs. Of the anthropogenic VOCs, alkenes played a predominant role in VOC reactivity at GZ, whereas the contributions of reactive aromatics were more important at XK. Our preliminary analysis of the VOC correlations suggests that the ambient VOCs at GZ came directly from local sources (i.e., automobiles; those at XK were influenced by both local emissions and transportation of air mass from upwind areas.

Unleaded gasoline with reduction in benzene and aromatics

International Nuclear Information System (INIS)

Ahmed, I.

2003-01-01

The trend today is towards making gasoline more environment and human friendly or in other words making gasoline a really clean fuel. This paper covers the ill effects of benzene and aromatics and the driving force behind their reduction in gasoline worldwide. It addresses health concerns specifically, and the theme is unleaded gasoline without simultaneously addressing reduction in benzene and aromatics is more harmful. The paper cites worldwide case studies, and also the World Bank (WB), Government of Pakistan (GoP), and United Nations (UN) efforts in this area in Pakistan. (author)

40 CFR 80.375 - What requirements apply to California gasoline?

Science.gov (United States)

2010-07-01

... gasoline? 80.375 Section 80.375 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Gasoline Sulfur Exemptions § 80.375 What requirements apply to California gasoline? (a) Definition. For purposes of this subpart California gasoline...

40 CFR 80.1236 - What requirements apply to California gasoline?

Science.gov (United States)

2010-07-01

... gasoline? 80.1236 Section 80.1236 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Gasoline Benzene Gasoline Benzene Requirements § 80.1236 What requirements apply to California gasoline? (a) Definition. For purposes of this subpart...

40 CFR 80.845 - What requirements apply to California gasoline?

Science.gov (United States)

2010-07-01

... gasoline? 80.845 Section 80.845 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Gasoline Toxics Gasoline Toxics Performance Requirements § 80.845 What requirements apply to California gasoline? (a) Definition. For purposes of this...

Estimation model for evaporative emissions from gasoline vehicles based on thermodynamics.

Science.gov (United States)

Hata, Hiroo; Yamada, Hiroyuki; Kokuryo, Kazuo; Okada, Megumi; Funakubo, Chikage; Tonokura, Kenichi

2018-03-15

In this study, we conducted seven-day diurnal breathing loss (DBL) tests on gasoline vehicles. We propose a model based on the theory of thermodynamics that can represent the experimental results of the current and previous studies. The experiments were performed using 14 physical parameters to determine the dependence of total emissions on temperature, fuel tank fill, and fuel vapor pressure. In most cases, total emissions after an apparent breakthrough were proportional to the difference between minimum and maximum environmental temperatures during the day, fuel tank empty space, and fuel vapor pressure. Volatile organic compounds (VOCs) were measured using a Gas Chromatography Mass Spectrometer and Flame Ionization Detector (GC-MS/FID) to determine the Ozone Formation Potential (OFP) of after-breakthrough gas emitted to the atmosphere. Using the experimental results, we constructed a thermodynamic model for estimating the amount of evaporative emissions after a fully saturated canister breakthrough occurred, and a comparison between the thermodynamic model and previous models was made. Finally, the total annual evaporative emissions and OFP in Japan were determined and compared by each model. Copyright © 2017 Elsevier B.V. All rights reserved.

Microwave-Based Oxidation State and Soot Loading Determination on Gasoline Particulate Filters with Three-Way Catalyst Coating for Homogenously Operated Gasoline Engines.

Science.gov (United States)

Dietrich, Markus; Jahn, Christoph; Lanzerath, Peter; Moos, Ralf

2015-09-02

Recently, a novel method emerged to determine the oxygen storage degree of three way catalysts (TWC) by a microwave-based method. Up to now, this method has been investigated only in lab-scale reactors or under steady state conditions. This work expands those initial studies. A TWC-coated gasoline particulate filter was investigated in a dynamic engine test bench simulating a typical European driving cycle (NEDC). It could be shown that both the oxygen storage degree and the soot loading can be monitored directly, but not simultaneously due to their competitive effects. Under normal driving conditions, no soot accumulation was observed, related to the low raw emissions and the catalytic coating of the filter. For the first time, the quality factor of the cavity resonator in addition to the resonance frequency was used, with the benefit of less cross sensitivity to inconstant temperature and water. Therefore, a temperature dependent calibration of the microwave signal was created and applied to monitor the oxidation state in transient driving cycles. The microwave measurement mirrors the oxidation state determined by lambda probes and can be highly beneficial in start-stop phases (where lambda-probes do not work) and to determine the oxygen storage capacity (OSC) without unnecessary emissions.

Microwave-Based Oxidation State and Soot Loading Determination on Gasoline Particulate Filters with Three-Way Catalyst Coating for Homogenously Operated Gasoline Engines

Directory of Open Access Journals (Sweden)

Markus Dietrich

2015-09-01

Full Text Available Recently, a novel method emerged to determine the oxygen storage degree of three way catalysts (TWC by a microwave-based method. Up to now, this method has been investigated only in lab-scale reactors or under steady state conditions. This work expands those initial studies. A TWC-coated gasoline particulate filter was investigated in a dynamic engine test bench simulating a typical European driving cycle (NEDC. It could be shown that both the oxygen storage degree and the soot loading can be monitored directly, but not simultaneously due to their competitive effects. Under normal driving conditions, no soot accumulation was observed, related to the low raw emissions and the catalytic coating of the filter. For the first time, the quality factor of the cavity resonator in addition to the resonance frequency was used, with the benefit of less cross sensitivity to inconstant temperature and water. Therefore, a temperature dependent calibration of the microwave signal was created and applied to monitor the oxidation state in transient driving cycles. The microwave measurement mirrors the oxidation state determined by lambda probes and can be highly beneficial in start-stop phases (where lambda-probes do not work and to determine the oxygen storage capacity (OSC without unnecessary emissions.

Ionic liquid technology to recover volatile organic compounds (VOCs).

Science.gov (United States)

Salar-García, M J; Ortiz-Martínez, V M; Hernández-Fernández, F J; de Los Ríos, A P; Quesada-Medina, J

2017-01-05

Volatile organic compounds (VOCs) comprise a wide variety of carbon-based materials which are volatile at relatively low temperatures. Most of VOCs pose a hazard to both human health and the environment. For this reason, in the last years, big efforts have been made to develop efficient techniques for the recovery of VOCs produced from industry. The use of ionic liquids (ILs) is among the most promising separation technologies in this field. This article offers a critical overview on the use of ionic liquids for the separation of VOCs both in bulk and in immobilized form. It covers the most relevant works within this field and provides a global outlook on the limitations and future prospects of this technology. The extraction processes of VOCs by using different IL-based assemblies are described in detail and compared with conventional methods This review also underlines the advantages and limitations posed by ionic liquids according to the nature of the cation and the anions present in their structure and the stability of the membrane configurations in which ILs are used as liquid phase. Copyright © 2016 Elsevier B.V. All rights reserved.

46 CFR 56.50-70 - Gasoline fuel systems.

Science.gov (United States)

2010-10-01

... 46 Shipping 2 2010-10-01 2010-10-01 false Gasoline fuel systems. 56.50-70 Section 56.50-70... APPURTENANCES Design Requirements Pertaining to Specific Systems § 56.50-70 Gasoline fuel systems. (a) Material.... Outlets in fuel lines for drawing gasoline for any purpose are prohibited. Valved openings in the bottom...

Comparative TEA for Indirect Liquefaction Pathways to Distillate-Range Fuels via Oxygenated Intermediates

Energy Technology Data Exchange (ETDEWEB)

Tan, Eric; Snowden-Swan, Lesley J.; Talmadge, Michael; Dutta, Abhijit; Jones, Susanne; Ramasamy, Karthikeyan; Gray, Michael; Dagle, Robert; Padmaperuma, Asanga; Gerber, Mark; Sahir, Asad; Tao, Ling; Zhang, Yanan

2017-03-03

This paper presents a comparative techno-economic analysis of five conversion pathways from biomass to gasoline-, jet-, and diesel-range hydrocarbons via indirect liquefaction with specific focus on pathways utilizing oxygenated intermediates (derived either via thermochemical or biochemical conversion steps). The four emerging pathways of interest are compared with one conventional pathway (Fischer-Tropsch) for the production of the hydrocarbon blendstocks. The processing steps of the four emerging pathways include: biomass-to-syngas via indirect gasification, gas cleanup, conversion of syngas to alcohols/oxygenates, followed by conversion of alcohols/oxygenates to hydrocarbon blendstocks via dehydration, oligomerization, and hydrogenation. We show that the emerging pathways via oxygenated intermediates have the potential to be cost competitive with the conventional Fischer-Tropsch process. The evaluated pathways and the benchmark process generally exhibit similar fuel yields and carbon conversion efficiencies. The resulting minimum fuel selling prices are comparable to the benchmark at approximately $3.60 per gallon-gasoline equivalent, with potential for two new pathways to be more economically competitive. Additionally, the coproduct values can play an important role in the economics of the processes with oxygenated intermediates derived via syngas fermentation. Major cost drivers for the integrated processes are tied to achievable fuel yields and conversion efficiency of the intermediate steps, i.e., the production of oxygenates/alcohols from syngas and the conversion of oxygenates/alcohols to hydrocarbon fuels.

Understanding gasoline pricing in Canada

International Nuclear Information System (INIS)

Anon.

2001-01-01

Pricing policies for gasoline by Canadian oil companies are discussed. An attempt is made to demonstrate that competition between oil companies is extremely keen, and markups are so small that to stay in business, retail outlets have to sell huge volumes and sell non-fuel products, as a means to increase revenues and margins. An explanation is provided for why gasoline prices move in unison, and why what appears to the public as collusion and gouging is, in fact, the result of retail dealers attempting to stay in business. The high prices are attributed mainly to taxes by municipalities, the provinces and the federal government; taxes are said to account for 40 to 50 per cent of the pump price. The cost of crude makes up another 35 to 45 per cent, refining adds 10 to 15 per cent, with the remaining 5 to 10 per cent representing retail costs. (Taxes in the United States average 20 to 30 per cent). Over the longer term, gasoline prices consistently reflect the cost of crude oil, dominated by the OPEC countries which supply about 41 per cent of daily world production. Another factor is the rise of global and regional commodity markets for refined products such as gasoline. Commodity traders buy wholesale gasoline cheaply whenever it is in oversupply, and sell it for a profit into markets where the demand is greater. While this is claimed to ensure competitive prices in all markets, the practice can also trigger abrupt changes in regional markets

The elasticity of demand for gasoline in China

International Nuclear Information System (INIS)

Lin, C.-Y. Cynthia; Zeng, Jieyin

2013-01-01

This paper estimates the price and income elasticities of demand for gasoline in China. Our estimates of the intermediate-run price elasticity of gasoline demand range between −0.497 and −0.196, and our estimates of the intermediate-run income elasticity of gasoline demand range between 1.01 and 1.05. We also extend previous studies to estimate the vehicle miles traveled (VMT) elasticity and obtain a range from −0.882 to −0.579. - highlights: • The price elasticity of demand for gasoline in China is between −0.497 and −0.196. • The income elasticity of demand for gasoline in China is between 1.01 and 1.05. • The price elasticity of demand for VMT in China is between −0.882 and −0.579

Evaluation of Motor Gasoline Stability

Science.gov (United States)

1990-12-01

CAMPINNE AIR POLLUTION CONTROL I LABORATOIRE MECANIQUE TRANSPORT 2565 PLYMOUTH ROAD AVENUE DE LA RENAISSANCE, 3D ANN ARBOR MI 48105 B-1040 BRUSSELS 5...CUARTEL GENERAL DEL EJERCITO ATTN: MR K LAURINSEN ATTN: MAJ M ENGO NOGUES GADHOLTVEJ 11 DIVISION DE LOGISTICA (DIAM/LABCAMVE) DK-9900 FREDERIKSHAVN...Gum for Typical Civilian Gasolines Transported by CEPS and F-46 Gasolines Stored by CEPS ...................................... 47 B. Potential Gum

46 CFR 58.50-5 - Gasoline fuel tanks.

Science.gov (United States)

2010-10-01

... 46 Shipping 2 2010-10-01 2010-10-01 false Gasoline fuel tanks. 58.50-5 Section 58.50-5 Shipping... AND RELATED SYSTEMS Independent Fuel Tanks § 58.50-5 Gasoline fuel tanks. (a) Construction—(1) Shape...) Installation. (1) Gasoline fuel tanks used for propulsion shall be located in water-tight compartments separate...

Gasoline taxes or efficiency standards? A heterogeneous household demand analysis

International Nuclear Information System (INIS)

Liu, Weiwei

2015-01-01

Using detailed consumer expenditure survey data and a flexible semiparametric dynamic demand model, this paper estimates the price elasticity and fuel efficiency elasticity of gasoline demand at the household level. The goal is to assess the effectiveness of gasoline taxes and vehicle fuel efficiency standards on fuel consumption. The results reveal substantial interaction between vehicle fuel efficiency and the price elasticity of gasoline demand: the improvement of vehicle fuel efficiency leads to lower price elasticity and weakens consumers’ sensitivity to gasoline price changes. The offsetting effect also differs across households due to demographic heterogeneity. These findings imply that when gasoline taxes are in place, tightening efficiency standards will partially offset the strength of taxes on reducing fuel consumption. - Highlights: • Model household gasoline demand using a semiparametric approach. • Estimate heterogeneous price elasticity and fuel efficiency elasticity. • Assess the effectiveness of gasoline taxes and efficiency standards. • Efficiency standards offset the impact of gasoline taxes on fuel consumption. • The offsetting effect differs by household demographics

Inventories and upstream gasoline price dynamics

NARCIS (Netherlands)

Kuper, Gerard H.

This paper sheds new light on the asymmetric dynamics in upstream U.S. gasoline prices. The model is based on Pindyck's inventory model of commodity price dynamics. We show that asymmetry in gasoline price dynamics is caused by changes in the net marginal convenience yield: higher costs of marketing

[Development of biogenic VOC emissions inventory with high temporal and spatial resolution].

Science.gov (United States)

Hu, Y; Zhang, Y; Xie, S; Zeng, L

2001-11-01

A new method was developed to estimate biogenic VOC emissions with high temporal and spatial resolution by use of Mesoscale Meteorology Modeling System Version5 (MM5). In this method, the isoprene and monoterpene standard emission factors for some types of tree in China were given and the standard VOC emission factors and seasonally average densities of leaf biomass for all types of vegetation were determined. A biogenic VOC emissions inventory in South China was established which could meet the requirement of regional air quality modeling. Total biogenic VOC emissions in a typical summer day were estimated to be 1.12 x 10(4) metric tons in an area of 729 km x 729 km of South China. The results showed the temporal and spatial distributions of biogenic VOC emission rates in this area. The results also showed that the geographical distribution of biogenic VOC emission rates depended on vegetation types and their distributions and the diurnal variation mainly depended on the solar radiation and temperature. The uncertainties of estimating biogenic VOC emissions were also discussed.

Property Analysis of Ethanol--Natural Gasoline--BOB Blends to Make Flex Fuel

Energy Technology Data Exchange (ETDEWEB)

Alleman, Teresa L. [National Renewable Energy Lab. (NREL), Golden, CO (United States); Yanowitz, Janet [Ecoengineering, Inc., Sharonville, OH (United States)

2016-11-01

Ten natural gasolines were analyzed for a wide range of properties, including Reid vapor pressure (RVP), benzene, sulfur, distillation, stability, metals, and aromatic content, to determine their quality. Benzene and sulfur content were sufficiently low in all but one of the samples that they could be blended without further upgrading. Four of these samples were selected to blend with blendstock for oxygenate blending (BOB) and ethanol to produce E51, E70, and E83 blends, targeting 7.8 and 9.0-psi finished fuels. The volume of each component in the blend was estimated using the Reddy model, with the assumption that the BOB and natural gasoline blend linearly and behave as a single component in the model calculations. Results show that the Reddy model adequately predicts the RVP of the finished blend for E51 and E70, but significantly underpredicts the RVP of E83 blends by nearly 2 psi. It is hypothesized that the underprediction is a function of the very low aromatic content of the E83 blends, even compared to the E51 and E70 blends.

Biogenic VOC Emissions from Tropical Landscapes

Science.gov (United States)

Guenther, A.; Greenberg, J.; Harley, P.; Otter, L.; Vanni Gatti, L.; Baker, B.

2003-04-01

Biogenic VOC have an important role in determining the chemical composition of atmosphere. As a result, these compounds are important for visibility, biogeochemical cycling, climate and radiative forcing, and the health of the biosphere. Tropical landscapes are estimated to release about 80% of total global biogenic VOC emissions but have been investigated to lesser extent than temperate regions. Tropical VOC emissions are particularly important due to the strong vertical transport and the rapid landuse change that is occurring there. This presentation will provide an overview of field measurements of biogenic VOC emissions from tropical landscapes in Amazonia (Large-scale Biosphere-atmosphere experiment in Amazonia, LBA) Central (EXPRESSO) and Southern (SAFARI 2000) Africa, Asia and Central America. Flux measurement methods include leaf-scale (enclosure measurements), canopy-scale (above canopy tower measurements), landscape-scale (tethered balloon), and regional-scale (aircraft measurements) observations. Typical midday isoprene emission rates for different landscapes vary by more than a factor of 20 with the lowest emissions observed from degraded forests. Emissions of alpha-pinene vary by a similar amount with the highest emissions associated with landscapes dominated by light dependent monoterpene emitting plants. Isoprene emissions tend to be higher for neotropical forests (Amazon and Costa Rica) in comparison to Africa and Asian tropical forests but considerable differences are observed within regions. Strong seasonal variations were observed in both the Congo and the Amazon rainforests with peak emissions during the dry seasons. Substantial emissions of light dependent monoterpenes, methanol and acetone are characteristic of at least some tropical landscapes.

Environment and Energy. Phase out of gasoline

International Nuclear Information System (INIS)

Magaudda, G.

2000-01-01

The european recommendation 98/07/EEC gives the technical specification of automotive fuels quality, gasoline and diesel fuel and forbid for member countries the commercialization of lead gasoline from 01/01/2001 [it

Environmental Life Cycle Implications of Using Bagasse-Derived Ethanol as a Gasoline Oxygenate in Mumbai (Bombay)

Energy Technology Data Exchange (ETDEWEB)

Kadam, K.

2000-12-07

Bagasse is the fibrous residue generated during sugar production and can be a desirable feedstock for fuel ethanol production. About 15%--25% of the bagasse is left after satisfying the mills' energy requirements, and this excess bagasse can be used in a bioconversion process to make ethanol. It is estimated that a 23 million L/yr ({approximately}6 million gal/yr) ethanol facility is feasible by combining excess bagasse from three larger sugar mills in Maharashtra state. The plant could supply about half of the ethanol demand in Mumbai, assuming that all gasoline is sold as an E10 fuel, a blend of 90% gasoline and 10% ethanol by volume. The life cycle assessment (LCA) performed in this study demonstrated the potentially significant benefits of diverting excess bagasse in Maharashtra to ethanol production, as opposed to disposing it by burning. In particular, lower net values for the ethanol production scenario were observed for the following: fossil energy consumption, and emissions of carbon monoxide , hydrocarbons (except methane), SOx, NOx, particulates, carbon dioxide, and methane. The lower greenhouse potential of the ethanol scenario is also important in the context of Clean Development Mechanism and Joint Implementation because India is a developing country.

Laminar burning velocities at elevated pressures for gasoline and gasoline surrogates associated with RON

KAUST Repository

Mannaa, Ossama

2015-06-01

The development and validation of a new gasoline surrogate using laminar flame speed as a target parameter is presented. Laminar burning velocities were measured using a constant-volume spherical vessel with ignition at the center of the vessel. Tested fuels included iso-octane, n-heptane, toluene, various mixtures of primary reference fuels (PRFs) and toluene reference fuels (TRFs) and three gasoline fuels of 70, 85 and 95 RON (FACE J, C and F) at the initial temperature of 358K and pressures up to 0.6MPa in the equivalence ratio ranging from 0.8 to 1.6. Normalized laminar burning velocity data were mapped into a tri-component mixture space at different experimental conditions to allocate different gasoline surrogates for different gasoline fuels, having RON of 70, 85 and 95. The surrogates of TRF-70-4 (17.94% iso-C8H18 +42.06% n-C7H16 +40% C7H8), TRF-85-1 (77.4% iso-C8H18 +17.6% n-C7H16 +5% C7H8), and TRF-95-1 (88.47% iso-C8H18 +6.53% n-C7H16 +5% C7H8) of RON 70, 85 and 95, respectively, are shown to successfully emulate the burning rate characteristics of the gasoline fuels associated with these RONs under the various experimental conditions investigated. An empirical correlation was derived to obtain laminar burning velocities at pressures that are experimentally unattainable as high as 3.0MPa. Laminar burning velocities were comparable to the simulated values for lean and stoichiometric flames but they were relatively higher than the simulated values for rich flames. A flame instability assessment was conducted by determining Markstein length, critical Pecklet number, and critical Karlovitz number at the onset of flame instability.

Hydrocarbon control strategies for gasoline marketing operations

Energy Technology Data Exchange (ETDEWEB)

Norton, R.L.; Sakaida, R.R.; Yamada, M.M.

1978-05-01

This informational document provides basic and current descriptions of gasoline marketing operations and methods that are available to control hydrocarbon emissions from these operations. The three types of facilities that are described are terminals, bulk plants, and service stations. Operational and business trends are also discussed. The potential emissions from typical facilities, including transport trucks, are given. The operations which lead to emissions from these facilities include (1) gasoline storage, (2) gasoline loading at terminals and bulk plants, (3) gasoline delivery to bulk plants and service stations, and (4) the refueling of vehicles at service stations. Available and possible methods for controlling emissions are described with their estimated control efficiencies and costs. This report also includes a bibliography of references cited in the text, and supplementary sources of information.

Volatile organic compound (VOC) determination in working atmospheres; Determinacion de compuestos organicos volatiles (VOC) en ambiente laboral

Energy Technology Data Exchange (ETDEWEB)

Blass A, Georgina; Panama T, Luz A; Corrales C, Deyanira [Instituto de Investigaciones Electricas, Cuernavaca, Morelos (Mexico)

2003-07-01

The present work describes, in a synthesized way, the implementation and application of procedures based on the normativity related to the subject of the volatile organic compounds (Volatile Organic Compounds VOC), that allow to sample, quantify and evaluate the present contamination in the working atmosphere of a refinery due to the fugitive emissions of VOC and other substances. In accordance with the corresponding normativity, more than 189 organic compounds denominated dangerous air polluting agents (Hazardous Air Pollutants, HAP) can be found in a working atmosphere, but they are the 11 main HAP that can be found in a refinery. In the present article the work made for the sampling and quantification of 5 of the 11 dangerous polluting agents of the air: benzene, toluene, xylene, iso-octane and naphthalene. [Spanish] El presente trabajo describe, de manera sintetizada, la implementacion y aplicacion de procedimientos basados en la normatividad relacionada al tema de los compuestos organicos volatiles (Volatil Organic Compounds, VOC), que permiten muestrear, cuantificar y evaluar la contaminacion presente en el ambiente laboral de una refineria debido a las emisiones fugitivas de VOC y otras sustancias. De acuerdo con la normatividad correspondiente, mas de 189 compuestos organicos denominados contaminantes peligrosos del aire (Hazardous Air Pollutants, HAP), pueden ser encontrados en un ambiente laboral, pero son 11 los principales HAP que pueden ser hallados en una refineria. En el presente articulo se informa el trabajo realizado para el muestreo y cuantificacion de 5 de los 11 contaminantes peligrosos del aire: benceno, tolueno, xileno, iso-octano y naftaleno.

TEMPERATURE INFLUENCE ON PHASE STABILITY OF ETHANOL-GASOLINE MIXTURES

Directory of Open Access Journals (Sweden)

Valerian Cerempei

2011-06-01

Full Text Available The article investigates phase stability of ethanol-gasoline mixtures depending on their composition, water concentration in ethanol and ethanol-gasoline mixture and temperature. There have been determined the perfect functioning conditions of spark ignition engines fueled with ethanol-gasoline mixtures.

Reducing VOC Press Emission from OSB Manufacturing; FINAL

International Nuclear Information System (INIS)

Gary D, McGinnis; Laura S, WIlliams; Amy E, Monte; Jagdish Rughani; Brett A, Niemi; Thomas M, Flicker

2001-01-01

Current regulations require industry to meet air emission standards with regard to particulates, volatile organic compounds (VOCs), hazardous air pollutants (HAPs) and other gases. One of many industries that will be affected by the new regulations is the wood composites industry. This industry generates VOCs, HAPs, and particulates mainly during the drying and pressing of wood. Current air treatment technologies for the industry are expensive to install and operate. As regulations become more stringent, treatment technologies will need to become more efficient and cost effective. The overall objective of this study is to evaluate the use of process conditions and chemical additives to reduce VOC/HAPs in air emitted from presses and dryers during the production of oriented strand board

Transport gasoline demand in Canada

International Nuclear Information System (INIS)

Eltony, M.N.

1993-01-01

This paper provides an estimate of household gasoline demand in Canada by applying a detailed model to pool time-series (1969-1988) and cross-sectional provincial data. The model recognises three major behavioural changes that households can make in response to gasoline price changes: drive fewer miles, purchase fewer cars, and buy more fuel-efficient vehicles. In the model, fuel economy is treated in considerable detail. The two components of the fuel economy of new cars sold-the technical fuel efficiency of various classes of cars and the distribution of new car sales according to their interior volume rather than their weight - are estimated as functions of economic variables. Car manufacturers are assumed to improve the technical fuel economy according to their expectation of consumer's response to future changes in gasoline prices and general economic conditions. (author)

Biofiltration of airborne VOCs with green wall systems-Microbial and chemical dynamics.

Science.gov (United States)

Mikkonen, A; Li, T; Vesala, M; Saarenheimo, J; Ahonen, V; Kärenlampi, S; Blande, J D; Tiirola, M; Tervahauta, A

2018-05-06

Botanical air filtration is a promising technology for reducing indoor air contaminants, but the underlying mechanisms need better understanding. Here, we made a set of chamber fumigation experiments of up to 16 weeks of duration, to study the filtration efficiencies for seven volatile organic compounds (VOCs; decane, toluene, 2-ethylhexanol, α-pinene, octane, benzene, and xylene) and to monitor microbial dynamics in simulated green wall systems. Biofiltration functioned on sub-ppm VOC levels without concentration-dependence. Airflow through the growth medium was needed for efficient removal of chemically diverse VOCs, and the use of optimized commercial growth medium further improved the efficiency compared with soil and Leca granules. Experimental green wall simulations using these components were immediately effective, indicating that initial VOC removal was largely abiotic. Golden pothos plants had a small additional positive impact on VOC filtration and bacterial diversity in the green wall system. Proteobacteria dominated the microbiota of rhizosphere and irrigation water. Airborne VOCs shaped the microbial communities, enriching potential VOC-utilizing bacteria (especially Nevskiaceae and Patulibacteraceae) in the irrigation water, where much of the VOC degradation capacity of the biofiltration systems resided. These results clearly show the benefits of active air circulation and optimized growth media in modern green wall systems. © 2018 John Wiley & Sons A/S. Published by John Wiley & Sons Ltd.

40 CFR 80.66 - Calculation of reformulated gasoline properties.

Science.gov (United States)

2010-07-01

... 40 Protection of Environment 16 2010-07-01 2010-07-01 false Calculation of reformulated gasoline... PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Reformulated Gasoline § 80.66 Calculation of reformulated gasoline properties. (a) All volume measurements required by these regulations shall be...

The effects of hydrous ethanol gasoline on combustion and emission characteristics of a port injection gasoline engine

Directory of Open Access Journals (Sweden)

Xiaochen Wang

2015-09-01

Full Text Available Comparative experiments were conducted on a port injection gasoline engine fueled with hydrous ethanol gasoline (E10W, ethanol gasoline (E10 and pure gasoline (E0. The effects of the engine loads and the additions of ethanol and water on combustion and emission characteristics were analyzed deeply. According to the experimental results, compared with E0, E10W showed higher peak in-cylinder pressure at high load. Increases in peak heat release rates were observed for E10W fuel at all the operating conditions. The usage of E10W increased NOX emissions at a wide load range. However, at low load conditions, E10W reduced HC, CO and CO2 emissions significantly. E10W also produced slightly less HC and CO emissions, while CO2 emissions were not significantly affected at higher operating points. Compared with E10, E10W showed higher peak in-cylinder pressures and peak heat release rates at the tested operating conditions. In addition, decreases in NOX emissions were observed for E10W from 5 Nm to 100 Nm, while HC, CO and CO2 emissions were slightly higher at low and medium load conditions. From the results, it can be concluded that E10W fuel can be regarded as a potential alternative fuel for gasoline engine applications.

[Emission Characteristics of VOCs from Typical Restaurants in Beijing].

Science.gov (United States)

Cui, Tong; Cheng, Jing-chen; He, Wan-qing; Ren, Pei-fang; Nie, Lei; Xu, Dong-yao; Pan, Tao

2015-05-01

Using the EPA method, emission of volatile organic compounds (VOCs) , sampled from barbecue, Chinese and Western fast-food, Sichuan cuisine and Zhejiang cuisine restaurants in Beijing was investigated. VOCs concentrations and components from different cuisines were studied. The results indicated that based on the calibrated baseline ventilation volume, the VOCs emission level from barbecue was the highest, reaching 12.22 mg · m(-3), while those from fast-food of either Chinese or Western, Sichuan cuisine and Zhejiang cuisine were about 4 mg · m(-3). The components of VOCs from barbecue were different from those in the other cuisines, which were mainly propylene, 1-butene, n-butane, etc. The non-barbecue cuisines consisted of high concentration of alcohols, and Western fast-food contained relatively high proportion of aldehydes and ketones organic compounds. According to emission concentration of baseline ventilation volume, barbecue released more pollutants than the non-barbecue cuisines at the same scale. So, barbecue should be supervised and controlled with the top priority.

Epidemic gasoline exposures following Hurricane Sandy.

Science.gov (United States)

Kim, Hong K; Takematsu, Mai; Biary, Rana; Williams, Nicholas; Hoffman, Robert S; Smith, Silas W

2013-12-01

Major adverse climatic events (MACEs) in heavily-populated areas can inflict severe damage to infrastructure, disrupting essential municipal and commercial services. Compromised health care delivery systems and limited utilities such as electricity, heating, potable water, sanitation, and housing, place populations in disaster areas at risk of toxic exposures. Hurricane Sandy made landfall on October 29, 2012 and caused severe infrastructure damage in heavily-populated areas. The prolonged electrical outage and damage to oil refineries caused a gasoline shortage and rationing unseen in the USA since the 1970s. This study explored gasoline exposures and clinical outcomes in the aftermath of Hurricane Sandy. Prospectively collected, regional poison control center (PCC) data regarding gasoline exposure cases from October 29, 2012 (hurricane landfall) through November 28, 2012 were reviewed and compared to the previous four years. The trends of gasoline exposures, exposure type, severity of clinical outcome, and hospital referral rates were assessed. Two-hundred and eighty-three gasoline exposures were identified, representing an 18 to 283-fold increase over the previous four years. The leading exposure route was siphoning (53.4%). Men comprised 83.0% of exposures; 91.9% were older than 20 years of age. Of 273 home-based calls, 88.7% were managed on site. Asymptomatic exposures occurred in 61.5% of the cases. However, minor and moderate toxic effects occurred in 12.4% and 3.5% of cases, respectively. Gastrointestinal (24.4%) and pulmonary (8.4%) symptoms predominated. No major outcomes or deaths were reported. Hurricane Sandy significantly increased gasoline exposures. While the majority of exposures were managed at home with minimum clinical toxicity, some patients experienced more severe symptoms. Disaster plans should incorporate public health messaging and regional PCCs for public health promotion and toxicological surveillance.

Taking the mystery out of gasoline prices

International Nuclear Information System (INIS)

Anon.

2000-01-01

Gasoline price variations in different markets of Canada are primarily driven by market forces, not necessarily by costs, according to a petroleum valuation consultant of the Newfoundland Department of Mines and Energy. Market forces include wholesale prices, the number and efficiency of stations in an area, companies' marketing strategies and customer buying preferences. Prices can be affected by any one of these forces at any time. The prediction is that wholesale prices will continue to be volatile in the next few months as the market adjusts to the changes in crude oil prices determined by OPEC as well as the summer season for gasoline. Changes in crude oil prices are usually reflected in the price of gasoline at the pump, although they do not necessarily move together. Demand which is an important factor in price, is cyclical in both the US and Canada, being lowest in the first quarter of the year, picking up during the second and third quarters with increased driving during good weather, and usually declining again in the fourth quarter with the onset of colder weather. Taxes are also a very significant component of the retail price of gasoline; in July 1998 the combined federal and provincial taxes accounted for 54 per cent of the average retail price of regular unleaded gasoline in Canada. Refining and marketing costs, the distance gasoline has to be transported to market, also influence prices at the pump

Development of synthetic gasoline production process

Energy Technology Data Exchange (ETDEWEB)

Imai, T; Fujita, H; Yamada, K; Suzuki, T; Tsuchida, Y

1986-01-01

As oil deposits are limited, it is very important to develop techniques for manufacturing petroleum alternatives as substitute energy sources to brighten the outlook for the future. The Research Association for Petroleum Alternatives Development (RAPAD) in Japan is engaged in the research and development of production techniques for light hydrocarbon oils such as gasoline, kerosene, and light oil from synthesis gas (CO, H/sub 2/) obtained from the raw materials of natural gas, coal, etc. Regarding the MTG process of synthesizing gasoline via methanol from synthesis gas and the STG process of directly synthesizing gasoline from synthesis gas, Cosmo Oil Co., Ltd. and Mitsubishi Heavy Industries, Ltd., members of RAPAD, have sought jointly to develop catalysts and processes. As a result of this co-operation, the authors have recently succeeded in developing a new catalyst with a long life span capable of providing a high yield and high selectivity. Additionally, the authors are currently on the verge of putting into effect a unique two-step STG process of synthesizing high octane gasoline via dimethyl ether, referred to as the AMSTG process.

40 CFR 80.81 - Enforcement exemptions for California gasoline.

Science.gov (United States)

2010-07-01

... gasoline. 80.81 Section 80.81 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Reformulated Gasoline § 80.81 Enforcement exemptions for California gasoline. (a)(1) The requirements of subparts D, E, F, and J of this part are...

Comparison of receptor models for source apportionment of volatile organic compounds in Beijing, China

International Nuclear Information System (INIS)

Song Yu; Dai Wei; Shao Min; Liu Ying; Lu Sihua; Kuster, William; Goldan, Paul

2008-01-01

Identifying the sources of volatile organic compounds (VOCs) is key to reducing ground-level ozone and secondary organic aerosols (SOAs). Several receptor models have been developed to apportion sources, but an intercomparison of these models had not been performed for VOCs in China. In the present study, we compared VOC sources based on chemical mass balance (CMB), UNMIX, and positive matrix factorization (PMF) models. Gasoline-related sources, petrochemical production, and liquefied petroleum gas (LPG) were identified by all three models as the major contributors, with UNMIX and PMF producing quite similar results. The contributions of gasoline-related sources and LPG estimated by the CMB model were higher, and petrochemical emissions were lower than in the UNMIX and PMF results, possibly because the VOC profiles used in the CMB model were for fresh emissions and the profiles extracted from ambient measurements by the two-factor analysis models were 'aged'. - VOCs sources were similar for three models with CMB showing a higher estimate for vehicles

Comparison of receptor models for source apportionment of volatile organic compounds in Beijing, China

Energy Technology Data Exchange (ETDEWEB)

Song Yu; Dai Wei [Department of Environmental Sciences, Peking University, Beijing 100871 (China); Shao Min [State Joint Key Laboratory of Environmental Simulation and Pollution Control, Peking University, Beijing 100871 (China)], E-mail: mshao@pku.edu.cn; Liu Ying; Lu Sihua [State Joint Key Laboratory of Environmental Simulation and Pollution Control, Peking University, Beijing 100871 (China); Kuster, William; Goldan, Paul [Chemical Sciences Division, NOAA Earth System Research Laboratory, Boulder, CO 80305 (United States)

2008-11-15

Identifying the sources of volatile organic compounds (VOCs) is key to reducing ground-level ozone and secondary organic aerosols (SOAs). Several receptor models have been developed to apportion sources, but an intercomparison of these models had not been performed for VOCs in China. In the present study, we compared VOC sources based on chemical mass balance (CMB), UNMIX, and positive matrix factorization (PMF) models. Gasoline-related sources, petrochemical production, and liquefied petroleum gas (LPG) were identified by all three models as the major contributors, with UNMIX and PMF producing quite similar results. The contributions of gasoline-related sources and LPG estimated by the CMB model were higher, and petrochemical emissions were lower than in the UNMIX and PMF results, possibly because the VOC profiles used in the CMB model were for fresh emissions and the profiles extracted from ambient measurements by the two-factor analysis models were 'aged'. - VOCs sources were similar for three models with CMB showing a higher estimate for vehicles.

The VOC-Ozone connection: a grassland case study

Science.gov (United States)

Wohlfahrt, G.; Hoertnagl, L.; Bamberger, I.; Schnitzhofer, R.; Dunkel, J.; Hammerle, A.; Graus, M.; Hansel, A.

2009-04-01

Trophospheric ozone (O3) is formed in the presence of sunlight through the interaction of volatile organic compounds (VOCs) and NOx (NO, NO2). O3 damages plants in several ways, most importantly by reducing net photosynthesis and growth. The extent of this damage depends on the time-integrated absorbed O3 flux (i.e. the dose), which is a function of leaf stomatal conductance and ambient O3 concentration, and further influenced by plant species specific defence mechanisms. VOCs are produced by plants through a variety of pathways and in response to a large number of different driving forces. A large variety of VOCs are emitted by plants in response to stress conditions, including the foliar uptake of O3. Here we present preliminary data from an ongoing study where concurrent measurements of the fluxes of VOCs and O3 are made above a managed mountain grassland in Tyrol/Austria. Fluxes of several different VOCs and O3 are measured by means of the eddy covariance method and a proton transfer reaction mass spectrometer (PTR-MS) and an ozone analyser, respectively. Our findings show that the Methanol (MeOH) flux is correlated with the daily time-integrated O3 uptake by vegetation (integrated daily from sunrise - a surrogate for the O3 dose absorbed and the oxidative stress experienced by plants) - MeOH deposition and emission prevailing at low and high time-integrated O3 uptake rates, respectively. Fluxes of other VOCs were not related to the time-integrated O3 uptake. Integrated over longer time scales (several weeks) no correlation between the O3 uptake and MeOH emissions were found. Our study thus confirms earlier leaf-level studies, who found that MeOH emission increase with O3 dose, at the ecosystems scale. As the reaction with the hydroxyl radical (OH), which is responsible for the destruction of the greenhouse gas methane (CH4), is the major sink of atmospheric MeOH, this process provides a potentially important indirect radiative forcing.

Competition in the retail gasoline industry

Science.gov (United States)

Brewer, Jedidiah

2007-05-01

This dissertation examines competition in the retail gasoline industry. The first chapter highlights the importance of gasoline in modern society, introduces my work, and places it in the context of the existing academic literature. The second chapter details the institutional structure and profitability of the industry. The vast majority of retail gasoline stations are not directly owned and operated by major oil companies. Instead, most stations are set up under other contractual relationships: lessee-dealer, open-dealer, jobber-owned-and-operated, and independent. Gasoline retailers make relatively low profits, as is the case in many other retail industries, and are substantially less profitable than major oil companies. Gas stations also make less money when retail prices are climbing than when they are falling. As prices rise, total station profits are near zero or negative. When retail prices are constant or falling, retailers can make positive profits. The third chapter describes the entry of big-box stores into the retail gasoline industry over the last decade. The growth of such large retailers, in all markets, has led to a great deal of controversy as smaller competitors with long-term ties to the local community have become less common. I estimate the price impact that big-box stores have on traditional gasoline retailers using cross-sectional data in two geographically diverse cities. I also examine changes in pricing following the entry of The Home Depot into a local retail gasoline market. The results show that big-box stores place statistically and economically significant downward pressure on the prices of nearby gas stations, offering a measure of the impact of the entry of a big-box store. Chapter 4 examines the nature of price competition in markets where some competing retailers sell the same brand. The price effect of having more retailers selling the same brand is theoretically unclear. High brand diversity could give individual retailers

Recent Trends and Patterns of Gasoline Consumption in Nigeria ...

African Journals Online (AJOL)

This article analyses recent trends and spatial patterns of gasoline consumption in Nigeria. In particular, it shows that the volume of gasoline consumption in the country fluctuates with changes in economic growth. The pattern of distribution of gasoline consumption indicates that the largest consumption centres are in the ...

Degradation of tetraethyllead during the degradation of leaded gasoline hydrocarbons in soil

International Nuclear Information System (INIS)

Mulroy, P.T.; Ou, L.T.

1998-01-01

For over 50 years, leaded gasoline was the only fuel for automobiles, and tetraethyllead (TEL) was the major octane number enhancer used in leaded gasoline. Ample information is available on the fate and remediation of gasoline hydrocarbons in contaminated subsoils and groundwater. However, little is known regarding the fate of TEL in leaded gasoline-contaminated subsoils and groundwater. In soil not contaminated with gasoline, TEL was rapidly degraded and completely disappeared in 14 d. In gasoline-contaminated soil, TEL degradation was slower; after 77 d, 4 to 17% of the applied TEL still remained in the contaminated soil. Disappearance of total petroleum hydrocarbons (TPH) was initially rapid but slowed appreciably after 7 to 14 d. As a result, after 77 d, 33 to 51% of the applied gasoline still remained in soil. The retardation of TEL degradation in leaded gasoline-contaminated soil is due to the presence of gasoline hydrocarbons. As long as gasoline hydrocarbons remain in soil, TEL may also remain in soil, most likely in the gasoline hydrocarbon phase

Stabilization of gasoline from shale

Energy Technology Data Exchange (ETDEWEB)

Benedetti, L

1929-03-14

A process is described of stabilizing gasoline from shale, consisting in treating by agitating the gasoline freshly distilled from shale oil with 1.5 percent of its weight of sulfuric acid diluted to more than 10 times its volume, after which separating the pyridine, then treating by agitating with sulfuric acid which treatment separates the unsaturated hydrocarbons and finally treating by agitating with 1.5 percent of its weight of saturated caustic soda solution and washing with water.

Removal of VOCs from groundwater using membrane-assisted solvent extraction

International Nuclear Information System (INIS)

Hutter, J.C.; Vandegrift, G.F.; Nunez, L.; Redfield, D.H.

1992-01-01

A membrane-assisted solvent extraction (MASX) system coupled to a membrane-assisted distillation stripping (MADS) system for use in decontaminating groundwater is discussed. Volatile organic compounds (VOCs) are extracted in the MASX using a sunflower oil solvent. In the MADS, VOCs are stripped from the sunflower oil, and the oil is recycled to the MASX. Thermodynamic data for the sunflower oil-water-VOCs system were experimentally collected. Published membrane-mass transfer results along with these data were used to design the MASX and MADS modules

Analysis of exergy loss of gasoline surrogate combustion process based on detailed chemical kinetics

International Nuclear Information System (INIS)

Sun, Hongjie; Yan, Feng; Yu, Hao; Su, W.H.

2015-01-01

Highlights: • We explored the exergy loss sources of gasoline engine like combustion process. • The model combined non-equilibrium thermodynamics with detailed chemical kinetics. • We explored effects of initial conditions on exergy loss of combustion process. • Exergy loss decreases 15% of fuel chemical exergy by design of initial conditions. • Correspondingly, the second law efficiency increases from 38.9% to 68.9%. - Abstract: Chemical reaction is the most important source of combustion irreversibility in premixed conditions, but details of the exergy loss mechanisms have not been explored yet. In this study numerical analysis based on non-equilibrium thermodynamics combined with detailed chemical kinetics is conducted to explore the exergy loss mechanism of gasoline engine like combustion process which is simplified as constant volume combustion. The fuel is represented by the common accepted gasoline surrogates which consist of four components: iso-octane (57%), n-heptane (16%), toluene (23%), and 2-pentene (4%). We find that overall exergy loss is mainly composed of three peaks along combustion generated from chemical reactions in three stages, the conversion from large fuel molecules into small molecules (as Stage 1), the H 2 O 2 loop-related reactions (as Stage 2), and the violent oxidation reactions of CO, H, and O (as Stage 3). The effects of individual combustion boundaries, including temperature, pressure, equivalence ratio, oxygen concentration, on combustion exergy loss have been widely investigated. The combined effects of combustion boundaries on the total loss of gasoline surrogates are also investigated. We find that in a gasoline engine with a compression ratio of 10, the total loss can be reduced from 31.3% to 24.3% using lean combustion. The total loss can be further reduced to 22.4% by introducing exhaust gas recirculation and boosting the inlet charge. If the compression ratio is increased to 17, the total loss can be decreased to

High octane gasoline components from catalytic cracking gasoline, propylene, and isobutane by disproportionation, clevage and alkylation

Energy Technology Data Exchange (ETDEWEB)

Banks, R.

1980-07-08

A process is described for producing high octane value gasoline which comprises in a disproportionation zone subjecting propylene and a mixture of propylene and ethylene obtained as hereinafter delineated to disproportionation conditions to produce a stream containing ethylene and a stream containing butenes, passing the ethylene-containing stream from said disproportionation zone together with a catalytic cracking gasoline to a cleavage zone under disproportionation conditions and subjecting the mixture of hydrocarbons therin to cleavage to produce said mixture of propylene and ethylene, a C/sub 5//sup +/ gasoline-containing product and butenes and wherein the butenes obtained in the overall operation of the disproportionation zone and the cleavage zone are passed to an alkylation zone wherein said butenes are used to alkylate an isoparaffin to produce additional high octane value product.

Performance of a hybrid hydrogen–gasoline engine under various operating conditions

International Nuclear Information System (INIS)

Ji, Changwei; Wang, Shuofeng; Zhang, Bo

2012-01-01

Highlights: ► We develop a combustion strategy for the hybrid hydrogen–gasoline engine (HHGE). ► The HHGE produced much lower HC and CO emissions at cold start. ► The H 2 -gasoline blends were effective for improving engine performance at idle and part loads. ► The HHGE could run smoothly at lean conditions. -- Abstract: This paper proposed a new combustion strategy for the spark-ignited (SI) engines. A gasoline engine was converted into a hybrid hydrogen–gasoline engine (HHGE) by adding a hydrogen injection system and a hybrid electronic control unit. Different from the conventional gasoline and hydrogen–enriched gasoline engines, the HHGE is fueled with the pure hydrogen at cold start to produce almost zero emissions, with the hydrogen–gasoline blends at idle and part loads to further improve thermal efficiency and reduce emissions, and with the pure gasoline to ensure the engine power output at high loads. Because the HHGE is fueled with the pure gasoline at high loads and speeds, experiments are only conducted at clod start, idle and part load conditions. Since lean combustion avails the further improvement of the engine performance, the HHGE was fueled with the lean mixtures in all tests. The experimental results showed that the hybrid hydrogen–gasoline engine was started successfully with the pure hydrogen, which produced 94.7% and 99.5% reductions in HC and CO emissions within 100 s from the onset of the cold start, compared with the original gasoline engine. At an excess air ratio of 1.37 and idle conditions, indicated thermal efficiency of the 3% hydrogen–blended gasoline engine was 46.3% higher than that of the original engine. Moreover, the engine cyclic variation was eased, combustion duration was shortened and HC, CO and NOx emissions were effectively reduced for the hybrid hydrogen–gasoline engines.

Gasoline tax best path to reduced emissions

International Nuclear Information System (INIS)

Brinner, R.E.

1991-01-01

Lowering gasoline consumption is the quickest way to increase energy security and reduce emissions. Three policy initiatives designed to meet such goals are current contenders in Washington, DC: higher gasoline taxes; higher CAFE (Corporate Average Fuel Economy) standards; and an auto registration fee scheme with gas-guzzler taxes and gas-sipper subsidies. Any of these options will give us a more fuel-efficient auto fleet. The author feels, however, the gasoline tax holds several advantages: it is fair, flexible, smart, and honest. But he notes that he is proposing a substantial increase in the federal gasoline tax. Real commitment would translate into an additional 50 cents a gallon at the pump. While the concept of increasing taxes at the federal level is unpopular with voters and, thus, with elected officials, there are attractive ways to recycle the $50 billion in annual revenues that higher gas taxes would produce

Investigation of VOC emissions from indoor and outdoor painting processes in shipyards

Science.gov (United States)

Celebi, Ugur Bugra; Vardar, Nurten

Volatile organic compounds (VOCs) from painting solvents are one of the most important sources of pollutant outputs for the shipbuilding and ship repair industry. Two ships of equal tonnage with the same painted area as each other, which were built in Turkish shipyards, are compared in terms of VOCs produced during painting and coating. Total area of all painted surfaces and total paint consumption of a 3500 deadweight tonne (DWT) oil/chemical tanker and a general cargo ship are calculated. An improved model for calculating the surface emissions of VOCs from painting and coating processes is utilized. Material balance emission estimation approach is employed to calculate the amount of VOCs, since it is used most often where a relatively large amount of material is emitted during use, and/or all air emissions are uncaptured. For both ships calculated VOCs are presented in figures. For the years 2005 and 2006 the total deadweight tonnage of ships delivered in Tuzla region, where 42 shipyards are located, is known. Therefore, a linear estimation is made to guess the total annual VOC emissions caused by painting operations. Finally, this information is used to project the total amount of VOCs emitted to the atmosphere for the year 2010.

Comparison of decomposition characteristics between aromatic and aliphatic VOCs using electron beam

International Nuclear Information System (INIS)

Kim, Jo-Chun

2011-01-01

The removal efficiency of n-decane (C 10 H 22 ) by electron beam was the highest among aliphatic VOCs of concern, and that of n-hexane (C 6 H 14 ), n-butane (C 4 H 10 ), and methane (CH 4 ) followed. On the other hand, in terms of aromatic VOC decomposition efficiencies, benzene (C 6 H 6 ) decomposition was the lowest and that of toluene (C 7 H 8 ), ethylbenzene (C 8 H 10 ), and p-xylene (C 8 H 10 ) were similar. It was also found that there was increase in by-product (untreated VOC, CO, CO 2 , O 3 , and other compounds) formation as well as all VOC removal efficiencies. It was demonstrated that the removal efficiency of VOC increased as its concentration decreased and the irradiation dose increased. In addition, low removal efficiency was observed because helium was relatively stable compared to the other gases, and nothing but electrons produced by electron accelerator reacted with VOC. It was also found that relative humidity had some effects on the decomposition rates of VOC. The removal efficiency at the 100% RH condition was slightly higher than that at 7.4% RH (dry condition) due to OH radical formation. (author)

Combustion characteristics of a gasoline engine with independent intake port injection and direct injection systems for n-butanol and gasoline

International Nuclear Information System (INIS)

He, Bang-Quan; Chen, Xu; Lin, Chang-Lin; Zhao, Hua

2016-01-01

Highlights: • Different injection approaches for n-butanol and gasoline affect combustion events. • High n-butanol percentage in the total energy of fuels improves combustion stability. • N-butanol promotes ignition and shortens combustion duration. • Lean burn increases indicated mean effective pressure at fixed total energy of fuels. • Different fuel injection methods slightly affect indicated mean effective pressure. - Abstract: N-butanol, as a sustainable biofuel, is usually used as a blend with gasoline in spark ignition engines. In this study, the combustion characteristics were investigated on a four-cylinder spark ignition gasoline engine with independent port fuel injection and direct injection systems for n-butanol and gasoline in different operating conditions. The results show that in the case of port fuel injection of n-butanol with direct injection gasoline at a given total energy released in a cycle, indicated mean effective pressure is slightly affected by spark timing at stoichiometry while it changes much more with delayed spark timing in lean burn conditions and is much higher in lean burn conditions compared to stoichiometry at given spark timings. With the increase of n-butanol percentage in a fixed total energy released in a cycle at given spark timings, ignition timing advances, combustion duration shortens, indicated mean effective pressure and indicated thermal efficiency increase. For the cases of port fuel injection of n-butanol with direction injection gasoline and port fuel injection of gasoline with direction injection n-butanol at a fixed total energy released in a cycle, their indicated mean effective pressures are close. But their combustion processes are dependent on fuel injection approaches.

Acute toxicity of water soluble fraction of petroleum, diesel and gasoline for newly hatched larvae of marine pejerrey Odontesthes Argentinensis

Energy Technology Data Exchange (ETDEWEB)

Rodrigues, Ricardo V.; Miranda-Filho, Kleber C.; Gusmao, Emeline P.; Moreira, Caue B.; Santos, Renato A.; Oliveira, Marcelo G.; Sampaio, Luis Andre [Fundacao Universidade do Rio Grande (FURG), RS (Brazil)

2008-07-01

The hydrocarbons of petroleum are the main aquatic pollutants and can cause toxicity to aquatic organisms, however, only a few toxicological studies were already conducted with early life stages of fish. The aim of this work was to determine the toxicity (LC50-96h) of water soluble fraction (WSF) of petroleum, diesel and gasoline for newly hatched larvae of marine pejerrey Odontesthes argentinensis. During the experiments the concentrations tested were: to petroleum (5%, 10%, 25%, 50%, 75%, and 100% of), to diesel (1%, 2%, 4%, 8%, 16%, 32%, e 64% of WSF) and to gasoline (1%, 2.5%, 5%, 10%, and 20% of WSF) plus a control to each pollutant. All treatments were done with 3 repetitions and 30 larvae. During the experiments the water quality were maintained at temperature 22,5 deg C, salinity 30, pH 7.95 and dissolved oxygen approximately around 4mg/L. The petroleum presented an CL50-96h equal to 70.68% (65.73 - 76.01), while the diesel and gasoline presented the toxicity values of 13.46% (10.19-17.79) and 5.48% (4.85-6.20), respectively. The results demonstrated a higher toxicity of light fuels (diesel and gasoline) compared to heavy petroleum. (author)

VOC-Arid Integrated Demonstration guide to preparation of demonstration documents

International Nuclear Information System (INIS)

Jensen, E.J.; Brouns, T.M.; Koegler, K.J.; McCabe, G.H.; Morris, F.A.

1994-06-01

This guide has been prepared by Demonstration Operations of the Volatile Organic Compound-Arid Integrated Demonstration (VOC-Arid ID). Its purpose is to describe demonstration documents, designate responsibilities for these documents, and guide the Principal Investigator (PI) and others in their preparation. The main emphasis of this guide is to describe the documentation required of the PI. However, it does cover some of the responsibilities of other members of the VOC-Arid ID team. The VOC-Arid ID is one of several US Department of Energy (DOE) integrated demonstrations designed to support the demonstration of emerging environmental management and restoration technologies. The principal objective of the VOC-Arid ID is to identify, develop, and demonstrate new and innovative technologies for environmental restoration at arid or semiarid sites containing volatile organic compounds with or without associated contamination (e.g., radionuclides and metals)

Volatile organic compounds (VOCs) source profiles of on-road vehicle emissions in China.

Science.gov (United States)

Hong-Li, Wang; Sheng-Ao, Jing; Sheng-Rong, Lou; Qing-Yao, Hu; Li, Li; Shi-Kang, Tao; Cheng, Huang; Li-Ping, Qiao; Chang-Hong, Chen

2017-12-31

Volatile Organic Compounds (VOCs) source profiles of on-road vehicles were widely studied as their critical roles in VOCs source apportionment and abatement measures in megacities. Studies of VOCs source profiles from on-road motor vehicles from 2001 to 2016 were summarized in this study, with a focus on the comparisons among different studies and the potential impact of different factors. Generally, non-methane hydrocarbons dominated the source profile of on-road vehicle emissions. Carbonyls, potential important components of vehicle emission, were seldom considered in VOCs emissions of vehicles in the past and should be paid more attention to in further study. VOCs source profiles showed some variations among different studies, and 6 factors were extracted and studied due to their impact to VOCs source profile of on-road vehicles. Vehicle types, being dependent on engine types, and fuel types were two dominant factors impacting VOCs sources profiles of vehicles. In comparison, impacts of ignitions, driving conditions and accumulated mileage were mainly due to their influence on the combustion efficiency. An opening and interactive database of VOCs from vehicle emissions was critically essential in future, and mechanisms of sharing and inputting relative research results should be formed to encourage researchers join the database establishment. Correspondingly, detailed quality assurance and quality control procedures were also very important, which included the information of test vehicles and test methods as detailed as possible. Based on the community above, a better uncertainty analysis could be carried out for the VOCs emissions profiles, which was critically important to understand the VOCs emission characteristics of the vehicle emissions. Copyright © 2017 Elsevier B.V. All rights reserved.

Diurnally resolved particulate and VOC measurements at a rural site: indication of significant biogenic secondary organic aerosol formation

Science.gov (United States)

Sjostedt, S. J.; Slowik, J. G.; Brook, J. R.; Chang, R. Y.-W.; Mihele, C.; Stroud, C. A.; Vlasenko, A.; Abbatt, J. P. D.

2011-06-01

We report simultaneous measurements of volatile organic compound (VOC) mixing ratios including C6 to C8 aromatics, isoprene, monoterpenes, acetone and organic aerosol mass loadings at a rural location in southwestern Ontario, Canada by Proton-Transfer-Reaction Mass Spectrometry (PTR-MS) and Aerosol Mass Spectrometry (AMS), respectively. During the three-week-long Border Air Quality and Meteorology Study in June-July 2007, air was sampled from a range of sources, including aged air from the polluted US Midwest, direct outflow from Detroit 50 km away, and clean air with higher biogenic input. After normalization to the diurnal profile of CO, a long-lived tracer, diurnal analyses show clear photochemical loss of reactive aromatics and production of oxygenated VOCs and secondary organic aerosol (SOA) during the daytime. Biogenic VOC mixing ratios increase during the daytime in accord with their light- and temperature-dependent sources. Long-lived species, such as hydrocarbon-like organic aerosol and benzene show little to no photochemical reactivity on this timescale. From the normalized diurnal profiles of VOCs, an estimate of OH concentrations during the daytime, measured O3 concentrations, and laboratory SOA yields, we calculate integrated local organic aerosol production amounts associated with each measured SOA precursor. Under the assumption that biogenic precursors are uniformly distributed across the southwestern Ontario location, we conclude that such precursors contribute significantly to the total amount of SOA formation, even during the period of Detroit outflow. The importance of aromatic precursors is more difficult to assess given that their sources are likely to be localized and thus of variable impact at the sampling location.

Optimization of the octane response of gasoline/ethanol blends

KAUST Repository

Badra, Jihad; AlRamadan, Abdullah S.; Sarathy, Mani

2017-01-01

The octane responses of gasoline/ethanol mixtures are not well understood because of the unidentified intermolecular interactions in such blends. In general, when ethanol is blended with gasoline, the Research Octane Number (RON) and the Motor Octane Number (MON) non-linearly increase or decrease, and the non-linearity is determined by the composition of the base gasoline and the amount of added ethanol. The complexity of commercial gasolines, comprising of hundreds of different components, makes it challenging to understand ethanol-gasoline synergistic/antagonistic blending effects. Understanding ethanol blending effects with simpler gasoline surrogates is critical to acquire knowledge about ethanol blending with complex multi-component gasoline fuels. In this study, the octane numbers (ON) of ethanol blends with five relevant gasoline surrogate molecules were measured. The molecules investigated in this study include: n-pentane, iso-pentane, 1,2,4-trimethylbenzene, cyclopentane and 1-hexene. These new measurements along with the available data of n-heptane, iso-octane, toluene, various primary reference fuels (PRF) and toluene primary reference fuels (TPRF) with ethanol are used to develop a blending rule for the octane response (RON and MON) of multi-component blends with ethanol. In addition, new ON data are collected for six Fuels for Advanced Combustion Engine (FACE) with ethanol. The relatively simple volume based model successfully predicts the octane numbers (ON) of the various ethanol/PRF and ethanol/TPRF blends with the majority of predictions being within the ASTM D2699 (RON) and D2700 (MON) reproducibility limits. The model is also successfully validated against the ON of the FACE gasolines blended with ethanol with the majority of predictions being within the reproducibility limits. Finally, insights into the possible causes of the synergistic and antagonistic effects of different molecules with ethanol are provided.

Optimization of the octane response of gasoline/ethanol blends

KAUST Repository

Badra, Jihad

2017-07-04

The octane responses of gasoline/ethanol mixtures are not well understood because of the unidentified intermolecular interactions in such blends. In general, when ethanol is blended with gasoline, the Research Octane Number (RON) and the Motor Octane Number (MON) non-linearly increase or decrease, and the non-linearity is determined by the composition of the base gasoline and the amount of added ethanol. The complexity of commercial gasolines, comprising of hundreds of different components, makes it challenging to understand ethanol-gasoline synergistic/antagonistic blending effects. Understanding ethanol blending effects with simpler gasoline surrogates is critical to acquire knowledge about ethanol blending with complex multi-component gasoline fuels. In this study, the octane numbers (ON) of ethanol blends with five relevant gasoline surrogate molecules were measured. The molecules investigated in this study include: n-pentane, iso-pentane, 1,2,4-trimethylbenzene, cyclopentane and 1-hexene. These new measurements along with the available data of n-heptane, iso-octane, toluene, various primary reference fuels (PRF) and toluene primary reference fuels (TPRF) with ethanol are used to develop a blending rule for the octane response (RON and MON) of multi-component blends with ethanol. In addition, new ON data are collected for six Fuels for Advanced Combustion Engine (FACE) with ethanol. The relatively simple volume based model successfully predicts the octane numbers (ON) of the various ethanol/PRF and ethanol/TPRF blends with the majority of predictions being within the ASTM D2699 (RON) and D2700 (MON) reproducibility limits. The model is also successfully validated against the ON of the FACE gasolines blended with ethanol with the majority of predictions being within the reproducibility limits. Finally, insights into the possible causes of the synergistic and antagonistic effects of different molecules with ethanol are provided.

40 CFR 86.340-79 - Gasoline-fueled engine dynamometer test run.

Science.gov (United States)

2010-07-01

... 40 Protection of Environment 18 2010-07-01 2010-07-01 false Gasoline-fueled engine dynamometer... Emission Regulations for New Gasoline-Fueled and Diesel-Fueled Heavy-Duty Engines; Gaseous Exhaust Test Procedures § 86.340-79 Gasoline-fueled engine dynamometer test run. (a) This section applies to gasoline...

POLLUTION PREVENTION CASE STUDIES: LOW-VOC/HAP WOOD FURNITURE COATINGS

Science.gov (United States)

This article provides a brief profile of the wood furniture industry, discusses pollution prevention activities typically implemented, describes the four low-VOC/HAP coating technologies studied. and summarizes one case study for each of the low-VOC/HAP coating yechnologies inves...

Report from Workshop on VOCs in diving chambers

International Nuclear Information System (INIS)

Crosbie, A.; Simpson, M.

2000-05-01

This report of the 'Setting the Standards' workshop on the problems of volatile organic compounds (VOCs) in diving in offshore operations, sponsored jointly by the UK Health and Safety Executive Offshore Safety Division and the Stolt Rockwater Joint Venture, gives details of the papers presented covering the chemical contamination of diver's atmosphere, sampling protocols and methods, analytical procedures used for VOCs in hyperbaric chambers, and contamination in buildings. The setting of exposure limits in the UK, the derivation of threshold limiting values (TVLs), the selection of Tenax tubes for atmospheric sampling, organic contaminant monitoring, and NASA's approach to contamination in the space environment are examined, and dealing with contamination problems in a submarine atmosphere, and the simulation of a condensate spillage in a diving bell are discussed. Guidelines for the measurement of VOCs in hyperbaric chambers are given in the appendices

Impact of unleaded gasoline in reducing emissions in Saudi Arabia

Energy Technology Data Exchange (ETDEWEB)

Hamid, S.H.

2001-01-15

Saudi Arabia is dealing progressively with tighter restrictions on refined product qualities. Efforts are ongoing within the country concerning the phase-out of lead in motor gasoline and the reduction of sulfur in diesel as well. The removal of lead is the main characteristic of environmental friendly gasoline. The detrimental health effects of using leaded gasoline are many, and lead exposure can cause kidney failure, brain dysfunction, behavioral problems, and neurological impairment. Saudi Arabia is moving towards using unleaded gasoline, and efforts are being put forward by research organizations to produce lead-free gasoline in the Kingdom. A high severity fluid catalytic cracking process is being developed for converting vacuum gas oil into high-octane gasoline components. This process requires high temperature and pressure and low contact time as compared to the conventional FCC process. (author)

Stream remediation following a gasoline spill

International Nuclear Information System (INIS)

Owens, E.H.; Reiter, G.A.; Challenger, G.

2000-01-01

On June 10, 1999, a pipe ruptured on the Olympic Pipe Line causing the release, explosion and fire of up to one million litres of gasoline in Bellingham, Washington. It affected approximately 5 km of the Whatcom Creek ecosystem. Following the incident, several concurrent activities in the source area and downstream occurred. This paper discussed the remediation of the affected stream bed sections. During the period July 6 - August 16, an interagency project was implemented. It involved mechanical, manual, and hydraulic in-situ treatment techniques to remove the gasoline from the stream bed and the banks. In addition, a series of controlled, hydraulic flushes were conducted. The sluice or control gates at the head of the Whatcom Creek were opened each night, and bigger flushes took place before and after the treatments. Simultaneously, water and sediment were sampled and analysed. The data obtained provided information on the state of the initial stream water and stream sediment and on the effects that the remediation had had. The residual gasoline was successfully removed from the sediments and river banks in six weeks. No downstream movement of the released gasoline towards Bellingham was detected. 3 refs., 2 tabs., 11 figs

Rapid detection of pathogenic bacteria by volatile organic compound (VOC) analysis

Science.gov (United States)

Senecal, Andre G.; Magnone, Joshua; Yeomans, Walter; Powers, Edmund M.

2002-02-01

Developments in rapid detection technologies have made countless improvements over the years. However, because of the limited sample that these technologies can process in a single run, the chance of capturing and identifying a small amount of pathogens is difficult. The problem is further magnified by the natural random distribution of pathogens in foods. Methods to simplify pathogenic detection through the identification of bacteria specific VOC were studied. E. coli O157:H7 and Salmonella typhimurium were grown on selected agar medium to model protein, and carbohydrate based foods. Pathogenic and common spoilage bacteria (Pseudomonas and Morexella) were screened for unique VOC production. Bacteria were grown on agar slants in closed vials. Headspace sampling was performed at intervals up to 24 hours using Solid Phase Micro-Extraction (SPME) techniques followed by GC/MS analysis. Development of unique volatiles was followed to establish sensitivity of detection. E. coli produced VOC not found in either Trypticase Soy Yeast (TSY) agar blanks or spoilage organism samples were - indole, 1-decanol, and 2-nonanone. Salmonella specific VOC grown on TSY were 3-methyl-1-butanol, dimethyl sulfide, 2-undecanol, 2-pentadecanol and 1-octanol. Trials on potato dextrose agar (PDA) slants indicated VOC specific for E. coli and Salmonella when compared to PDA blanks and Pseudomonas samples. However, these VOC peaks were similar for both pathogens. Morexella did not grow on PDA slants. Work will continue with model growth mediums at various temperatures, and mixed flora inoculums. As well as, VOC production based on the dynamics of bacterial growth.

Long Term Processing Using Integrated Hydropyrolysis plus Hydroconversion (IH2) for the Production of Gasoline and Diesel from Biomass

Energy Technology Data Exchange (ETDEWEB)

Marker, Terry [Gas Technology Institute; Roberts, Michael [Gas Technology Institute; Linck, Martin [Gas Technology Institute; Felix, Larry [Gas Technology Institute; Ortiz-Toral, Pedro [Gas Technology Institute; Wangerow, Jim [Gas Technology Institute; McLeod, Celeste [CRI Catalyst; Del Paggio, Alan [CRI Catalyst; Gephart, John [Johnson Timber; Starr, Jack [Cargill; Hahn, John [Cargill

2013-06-09

Cellulosic and woody biomass can be directly converted to hydrocarbon gasoline and diesel blending components through the use of a new, economical, technology named integrated hydropyrolysis plus hydroconversion (IH2). The IH2 gasoline and diesel blending components are fully compatible with petroleum based gasoline and diesel, contain less than 1% oxygen and have less than 1 total acid number (TAN). The IH2 gasoline is high quality and very close to a drop in fuel. The life cycle analysis (LCA) shows that the use of the IH2 process to convert wood to gasoline and diesel results in a greater than 90% reduction in greenhouse gas emission compared to that found with fossil derived fuels. The technoeconomic analysis showed the conversion of wood using the IH2 process can produce gasoline and diesel at less than $2.00/gallon. In this project, the previously reported semi-continuous small scale IH2 test results were confirmed in a continuous 50 kg/day pilot plant. The continuous IH2 pilot plant used in this project was operated round the clock for over 750 hours and showed good pilot plant operability while consistently producing 26-28 wt % yields of high quality gasoline and diesel product. The IH2 catalyst showed good stability, although more work on catalyst stability is recommended. Additional work is needed to commercialize the IH2 technology including running large particle size biomass, modeling the hydropyrolysis step, studying the effects of process variables and building and operating a 1-50 ton/day demonstration scale plant. The IH2 is a true game changing technology by utilizing U.S. domestic renewable biomass resources to create transportation fuels, sufficient in quantity and quality to substantially reduce our reliance on foreign crude oil. Thus, the IH2 technology offers a path to genuine energy independence for the U. S., along with the creation of a significant number of new U.S. jobs to plant, grow, harvest, and process biomass crops into fungible

Total OH reactivity study from VOC photochemical oxidation in the SAPHIR chamber

Science.gov (United States)

Yu, Z.; Tillmann, R.; Hohaus, T.; Fuchs, H.; Novelli, A.; Wegener, R.; Kaminski, M.; Schmitt, S. H.; Wahner, A.; Kiendler-Scharr, A.

2015-12-01

It is well known that hydroxyl radicals (OH) act as a dominant reactive species in the degradation of VOCs in the atmosphere. In recent field studies, directly measured total OH reactivity often showed poor agreement with OH reactivity calculated from VOC measurements (e.g. Nölscher et al., 2013; Lu et al., 2012a). This "missing OH reactivity" is attributed to unaccounted biogenic VOC emissions and/or oxidation products. The comparison of total OH reactivity being directly measured and calculated from single component measurements of VOCs and their oxidation products gives us a further understanding on the source of unmeasured reactive species in the atmosphere. This allows also the determination of the magnitude of the contribution of primary VOC emissions and their oxidation products to the missing OH reactivity. A series of experiments was carried out in the atmosphere simulation chamber SAPHIR in Jülich, Germany, to explore in detail the photochemical degradation of VOCs (isoprene, ß-pinene, limonene, and D6-benzene) by OH. The total OH reactivity was determined from the measurement of VOCs and their oxidation products by a Proton Transfer Reaction Time of Flight Mass Spectrometer (PTR-TOF-MS) with a GC/MS/FID system, and directly measured by a laser-induced fluorescence (LIF) at the same time. The comparison between these two total OH reactivity measurements showed an increase of missing OH reactivity in the presence of oxidation products of VOCs, indicating a strong contribution to missing OH reactivity from uncharacterized oxidation products.

Do Daily Retail Gasoline Prices adjust Asymmetrically?

NARCIS (Netherlands)

L.J.H. Bettendorf (Leon); S.A. van der Geest (Stéphanie); G. Kuper

2005-01-01

textabstractThis paper analyzes adjustments in the Dutch retail gasoline prices. We estimate an error correction model on changes in the daily retail price for gasoline (taxes excluded) for the period 1996-2004 taking care of volatility clustering by estimating an EGARCH model. It turns out the

Understanding retail gasoline pricing : An empirical approach

NARCIS (Netherlands)

Bruzikas, Tadas

2017-01-01

Retail gasoline markets offer an abundance of price data at the daily and, more recently, hourly level. Firms in this industry use sophisticated price strategies. Moreover, there have been a number of important recent market developments. All this makes retail gasoline a promising industry to study

Emission characteristics of VOCs emitted from consumer and commercial products and their ozone formation potential.

Science.gov (United States)

Dinh, Trieu-Vuong; Kim, Su-Yeon; Son, Youn-Suk; Choi, In-Young; Park, Seong-Ryong; Sunwoo, Young; Kim, Jo-Chun

2015-06-01

The characteristics of volatile organic compounds (VOCs) emitted from several consumer and commercial products (body wash, dishwashing detergent, air freshener, windshield washer fluid, lubricant, hair spray, and insecticide) were studied and compared. The spray products were found to emit the highest amount of VOCs (~96 wt%). In contrast, the body wash products showed the lowest VOC contents (~1.6 wt%). In the spray products, 21.6-96.4 % of the VOCs were propane, iso-butane, and n-butane, which are the components of liquefied petroleum gas. Monoterpene (C10H16) was the dominant component of the VOCs in the non-spray products (e.g., body wash, 53-88 %). In particular, methanol was present with the highest amount of VOCs in windshield washer fluid products. In terms of the number of carbon, the windshield washer fluids, lubricants, insecticides, and hair sprays comprised >95 % of the VOCs in the range C2-C5. The VOCs in the range C6-C10 were predominantly found in the body wash products. The dishwashing detergents and air fresheners contained diverse VOCs from C2 to C11. Besides comprising hazardous VOCs, VOCs from consumer products were also ozone precursors. The ozone formation potential of the consumer and commercial spray products was estimated to be higher than those of liquid and gel materials. In particular, the hair sprays showed the highest ozone formation potential.

The Impact of Ethanol Blending on U.S. Gasoline Prices

Energy Technology Data Exchange (ETDEWEB)

none,

2008-11-01

This study assesses the impact of ethanol blending on gasoline prices in the United States today and the potential impact of ethanol on gasoline prices at higher blending concentrations (10%, 15% and 20% of the total U.S. gasoline consumption).

Volatile Organic Compound (VOC) Emissions from Dairy Cows and Their Waste

Science.gov (United States)

Shaw, S.; Holzinger, R.; Mitloehner, F.; Goldstein, A.

2005-12-01

Biogenic VOCs are typically defined as those directly emitted from plants, but approximately 6% of global net primary production is consumed by cattle that carry out enteric fermentation and then emit VOCs that could also be considered biogenic. Current regulatory estimates suggest that dairy cattle in central California emit VOCs at rates comparable to those from passenger vehicles in the region, and thus contribute significantly to the extreme non-attainment of ozone standards there. We report PTR-MS measurements of ammonia and VOCs, and cavity-enhanced-absorption gas analyzer (Los Gatos Research, Inc.) measurements of CH4, emitted from dairy cattle in various stages of pregnancy/lactation and their waste. Experiments were conducted in chambers at UC Davis that simulate freestall cow housing conditions. CH4 fluxes ranged from 125-374 lb/cow/year. The compounds with the highest fluxes from '3 cows+waste' treatments were: ammonia (1-18), methanol (0-2.3), acetone+propanal (0.2-0.7), dimethylsulfide (0-0.4), and mass 109 (likely ID = p-cresol; 0-0.3) in lb/cow/year. Mass 60 (likely ID = trimethylamine) and acetic acid were also abundant. There were 10s of additional compounds with detectable, but small, emissions. A few compounds that were likely emitted (i.e. ethanol, formaldehyde, and dimethylamine) were not quantified by the PTR-MS. The total flux for all measured organic gases (TOG = CH4 + PTR-MS VOCs(including acetone+propanal)) averaged 246±45 lb/cow/year for '3 cows+waste' treatments, and was dominated by methane (>98%). TOG flux for 'waste only' treatments averaged 1.1±0.1 lb/cow/year, and was instead dominated by VOC (>84%). The PTR-MS VOCs as a percent of TOG (0.6±0.2%) emitted from '3 cows+waste' treatments in chamber conditions was a factor of 10 smaller than that currently estimated by the California Air Resources Board. In addition, the ozone forming potentials of the most abundant VOCs are only about 10% those of typical combustion or plant

Economic and environmental benefits of higher-octane gasoline.

Science.gov (United States)

Speth, Raymond L; Chow, Eric W; Malina, Robert; Barrett, Steven R H; Heywood, John B; Green, William H

2014-06-17

We quantify the economic and environmental benefits of designing U.S. light-duty vehicles (LDVs) to attain higher fuel economy by utilizing higher octane (98 RON) gasoline. We use engine simulations, a review of experimental data, and drive cycle simulations to estimate the reduction in fuel consumption associated with using higher-RON gasoline in individual vehicles. Lifecycle CO2 emissions and economic impacts for the U.S. LDV fleet are estimated based on a linear-programming refinery model, a historically calibrated fleet model, and a well-to-wheels emissions analysis. We find that greater use of high-RON gasoline in appropriately tuned vehicles could reduce annual gasoline consumption in the U.S. by 3.0-4.4%. Accounting for the increase in refinery emissions from production of additional high-RON gasoline, net CO2 emissions are reduced by 19-35 Mt/y in 2040 (2.5-4.7% of total direct LDV CO2 emissions). For the strategies studied, the annual direct economic benefit is estimated to be $0.4-6.4 billion in 2040, and the annual net societal benefit including the social cost of carbon is estimated to be $1.7-8.8 billion in 2040. Adoption of a RON standard in the U.S. in place of the current antiknock index (AKI) may enable refineries to produce larger quantities of high-RON gasoline.

Flow of gasoline-in-water microemulsion through water-saturated soil columns

International Nuclear Information System (INIS)

Ouyang, Y.; Mansell, R.S.; Rhue, R.D.

1995-01-01

Much consideration has been given to the use of surfactants to clean up nonaqueous phase liquids (NAPLs) from contaminated soil and ground water. Although this emulsification technique has shown significant potential for application in environmental remediation practices, a major obstacle leading to low washing efficiency is the potential formation of macroemulsion with unfavorable flow characteristics in porous media. This study investigated influences of the flow of leaded-gasoline-in-water (LG/W) microemulsion upon the transport of gasoline and lead (Pb) species in water-saturated soil columns. Two experiments were performed: (1) the immiscible displacement of leaded gasoline and (2) the miscible displacement of LG/W microemulsion through soil columns, followed by sequentially flushing with NaCl solution and a water/surfactant/cosurfactant (W/S/CoS) mixture. Comparison of breakthrough curves (BTC) for gasoline between the two experiments shows that about 90% of gasoline and total Pb were removed from the soil columns by NaCl solution in the LG/W microemulsion experiment as compared to 40% removal of gasoline and 10% removal of total Pb at the same process in the leaded gasoline experiment. Results indicate that gasoline and Pb species moved much more effectively through soil during miscible flow of LG/W microemulsion than during immiscible flow of leaded gasoline. In contrast to the adverse effects of macroemulsion on the transport of NAPLs, microemulsion was found to enhance the transport of gasoline through water-saturated soil. Mass balance analysis shows that the W/S/CoS mixture had a high capacity for removing residual gasoline and Pb species from contaminated soil. Comparison of water-pressure differences across the soil columns for the two experiments indicates that pore clogging by gasoline droplets was greatly minimized in the LG/W microemulsion experiment

Comparison of decomposition characteristics between aromatic and aliphatic VOCs using electron beam

Energy Technology Data Exchange (ETDEWEB)

Kim, Jo-Chun [Department of Environmental Engineering, Konkuk University, Seoul (Korea, Republic of)

2011-07-01

The removal efficiency of n-decane (C{sub 10}H{sub 22}) by electron beam was the highest among aliphatic VOCs of concern, and that of n-hexane (C{sub 6}H{sub 14}), n-butane (C{sub 4}H{sub 10}), and methane (CH{sub 4}) followed. On the other hand, in terms of aromatic VOC decomposition efficiencies, benzene (C{sub 6}H{sub 6}) decomposition was the lowest and that of toluene (C{sub 7}H{sub 8}), ethylbenzene (C{sub 8}H{sub 10}), and p-xylene (C{sub 8}H{sub 10}) were similar. It was also found that there was increase in by-product (untreated VOC, CO, CO{sub 2}, O{sub 3}, and other compounds) formation as well as all VOC removal efficiencies. It was demonstrated that the removal efficiency of VOC increased as its concentration decreased and the irradiation dose increased. In addition, low removal efficiency was observed because helium was relatively stable compared to the other gases, and nothing but electrons produced by electron accelerator reacted with VOC. It was also found that relative humidity had some effects on the decomposition rates of VOC. The removal efficiency at the 100% RH condition was slightly higher than that at 7.4% RH (dry condition) due to OH radical formation. (author)

Origin of 2-ethylhexanol as a VOC

International Nuclear Information System (INIS)

Nalli, Sandro; Horn, Owen J.; Grochowalski, Adam R.; Cooper, David G.; Nicell, Jim A.

2006-01-01

2-Ethylhexanol has been identified as a volatile organic compound (VOC) that contributes to the deterioration of indoor air quality. Plasticizers are common components of dust and building materials and are shown to be degraded by a variety of bacteria and fungi to produce 2-ethyhexanol and other metabolites. Of these, the 2-ethylhexanol has significant volatility and was observed in appreciable quantities. The degree to which 2-ethylhexanol is observed as a VOC in air samples would be limited by the fact that many of the microorganisms that are capable of producing this compound are also able to oxidize it to 2-ethylhexanoic acid, which is much less volatile. It is argued that an abiotic degradation mechanism of plasticizers that results in the generation of 2-ethylhexanol is unlikely and, if this did occur, other metabolites should have been observed. Thus, the microbial degradation of plasticizers is the most likely source of 2-ethylhexanol in indoor air. - A link has been observed between the partial biodegradation of plasticizers by microorganisms and VOCs associated with poor indoor air quality

Do daily retail gasoline prices adjust asymmetrically?

NARCIS (Netherlands)

Bettendorf, L.; van der Geest, S. A.; Kuper, G. H.

2009-01-01

This paper analyses adjustments in the Dutch retail gasoline prices. We estimate an error correction model on changes in the daily retail price for gasoline (taxes excluded) for the period 1996-2004, taking care of volatility clustering by estimating an EGARCH model. It turns out that the volatility

Gasoline, Ethanol and Methanol (GEM) Ternary Blends utilization as an Alternative to Conventional Iraqi Gasoline to Suppress Emitted Sulfur and Lead Components to Environment

OpenAIRE

Miqdam Tariq Chaichan

2016-01-01

Iraqi conventional gasoline characterized by its low octane number not exceed 82 and high lead and sulfur content. In this paper tri-component or ternary, blends of gasoline, ethanol, and methanol presented as an alternative fuel for Iraqi conventional gasoline. The study conducted by using GEM blend that equals E85 blend in octane rating. The used GEM selected from Turner, 2010 collection. G37 E20 M43 (37% gasoline + 20% ethanol+ 43% methanol) was chosen as GEM in present study. This blend u...

40 CFR 80.78 - Controls and prohibitions on reformulated gasoline.

Science.gov (United States)

2010-07-01

... reformulated gasoline. 80.78 Section 80.78 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Reformulated Gasoline § 80.78 Controls and prohibitions on reformulated gasoline. (a) Prohibited activities. (1) No person may manufacture...

Removal of VOCs by hybrid electron beam reactor with catalyst bed

International Nuclear Information System (INIS)

Kim, Jinkyu; Han, Bumsoo; Kim, Yuri; Lee, J.H.; Park, C.R.; Kim, J.C.; Kim, J.C.; Kim, K.J.

2004-01-01

Electron beam decomposition of volatile organic compounds (VOCs) was studied in order to obtain information for developing effective treatment method of off-gases from industries. We have examined the combination of electron beam and catalyst honeycomb which is either 1% platinum based or ceramic honeycomb- based aluminum oxide, using a hybrid reactor in order to improve removal efficiency and CO 2 formation; and to suppress undesirable by-product formation e.g. O 3 , aerosol, H x C y. , and tar. The experiments were conducted using a pilot-scale treatment system (maximum capacity; 1800 N m 3 /h) that fitted the field size to scale up from the traditional laboratory scale system for VOC removal with electron beam irradiation. Toluene was selected as a typical VOC that was irradiated to investigate product formation, effect of ceramic and catalyst, and factors effecting overall efficiency of degradation. Styrene was selected as the most odorous compound among the VOCs of interest. It was found that VOCs could be destroyed more effectively using a hybrid system with catalyst bed than with electron beam irradiation only

[CoCuMnOx Photocatalyzed Oxidation of Multi-component VOCs and Kinetic Analysis].

Science.gov (United States)

Meng, Hai-long; Bo, Long-li; Liu, Jia-dong; Gao, Bo; Feng, Qi-qi; Tan, Na; Xie, Shuai

2016-05-15

Solar energy absorption coating CoCuMnOx was prepared by co-precipitation method and applied to photodegrade multi- component VOCs including toluene, ethyl acetate and acetone under visible light irradiation. The photocatalytic oxidation performance of toluene, ethyl acetate and acetone was analyzed and reaction kinetics of VOCs were investigated synchronously. The research indicated that removal rates of single-component toluene, ethyl acetate and acetone were 57%, 62% and 58% respectively under conditions of 400 mg · m⁻³ initial concentration, 120 mm illumination distance, 1 g/350 cm² dosage of CoCuMnOx and 6 h of irradiation time by 100 W tungsten halogen lamp. Due to the competition among different VOCs, removal efficiencies in three-component mixture were reduced by 5%-26% as compared with single VOC. Degradation processes of single-component VOC and three-component VOCs both fitted pseudo first order reaction kinetics, and kinetic constants of toluene, ethyl acetate and acetone were 0.002, 0.002 8 and 0.002 33 min⁻¹ respectively under single-component condition. Reaction rates of VOCs in three-component mixture were 0.49-0.88 times of single components.

Comparative techno-economic analysis and process design for indirect liquefaction pathways to distillate-range fuels via biomass-derived oxygenated intermediates upgrading: Liquid Transportation Fuel Production via Biomass-derived Oxygenated Intermediates Upgrading

Energy Technology Data Exchange (ETDEWEB)

Tan, Eric C. D. [National Renewable Energy Laboratory, Golden CO USA; Snowden-Swan, Lesley J. [Pacific Northwest National Laboratory, Richland WA USA; Talmadge, Michael [National Renewable Energy Laboratory, Golden CO USA; Dutta, Abhijit [National Renewable Energy Laboratory, Golden CO USA; Jones, Susanne [Pacific Northwest National Laboratory, Richland WA USA; Ramasamy, Karthikeyan K. [Pacific Northwest National Laboratory, Richland WA USA; Gray, Michel [Pacific Northwest National Laboratory, Richland WA USA; Dagle, Robert [Pacific Northwest National Laboratory, Richland WA USA; Padmaperuma, Asanga [Pacific Northwest National Laboratory, Richland WA USA; Gerber, Mark [Pacific Northwest National Laboratory, Richland WA USA; Sahir, Asad H. [National Renewable Energy Laboratory, Golden CO USA; Tao, Ling [National Renewable Energy Laboratory, Golden CO USA; Zhang, Yanan [National Renewable Energy Laboratory, Golden CO USA

2016-09-27

This paper presents a comparative techno-economic analysis (TEA) of five conversion pathways from biomass to gasoline-, jet-, and diesel-range hydrocarbons via indirect liquefaction with specific focus on pathways utilizing oxygenated intermediates. The four emerging pathways of interest are compared with one conventional pathway (Fischer-Tropsch) for the production of the hydrocarbon blendstocks. The processing steps of the four emerging pathways include: biomass to syngas via indirect gasification, gas cleanup, conversion of syngas to alcohols/oxygenates followed by conversion of alcohols/oxygenates to hydrocarbon blendstocks via dehydration, oligomerization, and hydrogenation. Conversion of biomass-derived syngas to oxygenated intermediates occurs via three different pathways, producing: 1) mixed alcohols over a MoS2 catalyst, 2) mixed oxygenates (a mixture of C2+ oxygenated compounds, predominantly ethanol, acetic acid, acetaldehyde, ethyl acetate) using an Rh-based catalyst, and 3) ethanol from syngas fermentation. This is followed by the conversion of oxygenates/alcohols to fuel-range olefins in two approaches: 1) mixed alcohols/ethanol to 1-butanol rich mixture via Guerbet reaction, followed by alcohol dehydration, oligomerization, and hydrogenation, and 2) mixed oxygenates/ethanol to isobutene rich mixture and followed by oligomerization and hydrogenation. The design features a processing capacity of 2,000 tonnes/day (2,205 short tons) of dry biomass. The minimum fuel selling prices (MFSPs) for the four developing pathways range from $3.40 to $5.04 per gasoline-gallon equivalent (GGE), in 2011 US dollars. Sensitivity studies show that MFSPs can be improved with co-product credits and are comparable to the commercial Fischer-Tropsch benchmark ($3.58/GGE). Overall, this comparative TEA study documents potential economics for the developmental biofuel pathways via mixed oxygenates.

Respirometric oxygen demand determinations of laboratory- and field-scale biofilters

International Nuclear Information System (INIS)

Rho, D.; Mercier, P.; Jette, J.F.

1995-01-01

A biofiltration experiment operated at three inlet concentrations (425, 830, and 1,450 mg m -3 ), showed that the specific oxygen consumption rate was highly correlated (R = 0.938, n = 23) with the toluene elimination capacity. A radiorespirometric test was found to be more sensitive and appropriate for the field-scale biofilter treating gasoline vapors

Degradation of tetraethyllead in leaded gasoline contaminated and uncontaminated soils

International Nuclear Information System (INIS)

Ou, L.; Jing, W.; Thomas, J.; Mulroy, P.

1995-01-01

For over 50 years, since its introduction in 1923 by General Motors, tetraethyllead (TEL) was the major antiknock agent used in leaded gasoline. Since the middle of 1970, use of leaded gasoline in automobiles was gradually phased out. The main objective of this study is to determine the degradation rates and metabolites of TEL in gasoline contaminated and uncontaminated soils. TEL in uncontaminated soils disappeared rapidly. Ionic triethyllead (TREL) was the major organolead metabolite in these soils, with ionic diethyllead (DEL) being the minor product. Nonsterile soils, but not autoclaved soils, had limited capacity to mineralize 14 C-TEL to 14 CO 2 , H 2 0, and Pb 2+ . Unlike TEL in uncontaminated soils, petroleum hydrocarbons protected TEL in leaded gasoline contaminated soils from being degraded. Both disappearance and mineralization rates of TEL in leaded gasoline contaminated soils decreased with the increase in gasoline concentration. It appears that TEL in leaded gasoline contaminated soils is relatively stable until the level of petroleum hydrocarbons falls below a critical value. TEL is then rapidly degraded. Hydrocarbon degrading microorganisms may be involved, to some extent, in the degradation of TEL

Closing the gasoline system

International Nuclear Information System (INIS)

Hutcheson, R.C.

1992-01-01

In this paper, a representative of the Oil Companies' European Organization for Environmental and Health Protection (CONCAWE), argues the advantages of closing the gasoline system. Because this decouples the product from the environment, health risks and environmental damage are reduced. It is also more effective than changing the composition of gasoline because it offers better cost effectiveness, energy efficiency and the minimization of carbon dioxide release into the environment. However it will take time and political will to change until all European vehicles are fitted with three way catalysts and carbon canisters: control systems to monitor such systems will also need to be set up. However CONCAWE still recommends its adoption. (UK)

Standardized Gasoline Compression Ignition Fuels Matrix

KAUST Repository

Badra, Jihad; Bakor, Radwan; AlRamadan, Abdullah; Almansour, Mohammed; Sim, Jaeheon; Ahmed, Ahfaz; Viollet, Yoann; Chang, Junseok

2018-01-01

Direct injection compression ignition engines running on gasoline-like fuels have been considered an attractive alternative to traditional spark ignition and diesel engines. The compression and lean combustion mode eliminates throttle losses yielding higher thermodynamic efficiencies and the better mixing of fuel/air due to the longer ignition delay times of the gasoline-like fuels allows better emission performance such as nitric oxides (NOx) and particulate matter (PM). These gasoline-like fuels which usually have lower octane compared to market gasoline have been identified as a viable option for the gasoline compression ignition (GCI) engine applications due to its lower reactivity and lighter evaporation compared to diesel. The properties, specifications and sources of these GCI fuels are not fully understood yet because this technology is relatively new. In this work, a GCI fuel matrix is being developed based on the significance of certain physical and chemical properties in GCI engine operation. Those properties were chosen to be density, temperature at 90 volume % evaporation (T90) or final boiling point (FBP) and research octane number (RON) and the ranges of these properties were determined from the data reported in literature. These proposed fuels were theoretically formulated, while applying realistic constraints, using species present in real refinery streams. Finally, three-dimensional (3D) engine computational fluid dynamics (CFD) simulations were performed using the proposed GCI fuels and the similarities and differences were highlighted.

Standardized Gasoline Compression Ignition Fuels Matrix

KAUST Repository

Badra, Jihad

2018-04-03

Direct injection compression ignition engines running on gasoline-like fuels have been considered an attractive alternative to traditional spark ignition and diesel engines. The compression and lean combustion mode eliminates throttle losses yielding higher thermodynamic efficiencies and the better mixing of fuel/air due to the longer ignition delay times of the gasoline-like fuels allows better emission performance such as nitric oxides (NOx) and particulate matter (PM). These gasoline-like fuels which usually have lower octane compared to market gasoline have been identified as a viable option for the gasoline compression ignition (GCI) engine applications due to its lower reactivity and lighter evaporation compared to diesel. The properties, specifications and sources of these GCI fuels are not fully understood yet because this technology is relatively new. In this work, a GCI fuel matrix is being developed based on the significance of certain physical and chemical properties in GCI engine operation. Those properties were chosen to be density, temperature at 90 volume % evaporation (T90) or final boiling point (FBP) and research octane number (RON) and the ranges of these properties were determined from the data reported in literature. These proposed fuels were theoretically formulated, while applying realistic constraints, using species present in real refinery streams. Finally, three-dimensional (3D) engine computational fluid dynamics (CFD) simulations were performed using the proposed GCI fuels and the similarities and differences were highlighted.

An updated emission inventory of vehicular VOCs and IVOCs in China

Science.gov (United States)

Liu, Huan; Man, Hanyang; Cui, Hongyang; Wang, Yanjun; Deng, Fanyuan; Wang, Yue; Yang, Xiaofan; Xiao, Qian; Zhang, Qiang; Ding, Yan; He, Kebin

2017-10-01

Currently, the emission inventory of vehicular volatile organic compounds (VOCs) is one of those with the largest errors and uncertainties due to suboptimal estimation methods and the lack of first-hand basic data. In this study, an updated speciated emission inventory of VOCs and an estimation of intermediate-volatility organic compounds (IVOCs) from vehicles in China at the provincial level for the year of 2015 are developed based on a set of state-of-the-art methods and an abundance of local measurement data. Activity data for light-duty vehicles are derived from trajectories of more than 70 000 cars for 1 year. The annual mileage of trucks are calculated from reported data by more than 2 million trucks in China. The emission profiles are updated using measurement data. Vehicular tailpipe emissions (VTEs) and four types of vehicular evaporation emissions (VEEs), including refueling, hot soak, diurnal and running loss, are taken into account. Results show that the total vehicular VOC emissions in China are 4.21 Tg (with a 95 % confidence interval range from 2.90 to 6.54 Tg) and the IVOC emissions are 200.37 Gg in 2015. VTEs are still the predominant contributor, while VEEs are responsible for 39.20 % of VOC emissions. The control of VEEs is yet to be optimized in China. Among VTEs, passenger vehicles emissions have the largest share (49.86 %), followed by trucks (28.15 %) and motorcycles (21.99 %). Among VEEs, running loss is the largest contributor (81.05 %). For both VTEs and VEEs, Guangdong, Shandong and Jiangsu province are three of the highest, with a respective contribution of 10.66, 8.85 and 6.54 % to the total amounts of VOCs from vehicles. 97 VOC species are analyzed in this VOC emission inventory. i-Pentane, toluene and formaldehyde are found to be the most abundant species in China's vehicular VOC emissions. The estimated IVOCs are another inconvenient truth, concluding that precursor emissions for secondary organic aerosol (SOA) from vehicles are much

Evaluation of impact factors on VOC emissions and concentrations from wooden flooring based on chamber tests

Energy Technology Data Exchange (ETDEWEB)

Lin, Chi-Chi [Department of Civil and Environmental Engineering, National University of Kaohsiung, No. 700, Kaohsiung University Rd., Kaohsiung (China); Yu, Kuo-Pin [Institute of Environmental and Occupational Health Sciences, National Yang-Ming University, No.155, Sec.2, Linong Street, Taipei (China); Zhao, Ping [Filtration Group Inc., 912 E. Washington Street, Joliet, IL 60433 (United States); Whei-May Lee, Grace [Graduate Institute of Environmental Engineering, National Taiwan University, 71, Chou-Shan Rd., Taipei (China)

2009-03-15

In this study, the impact factors of temperature, relative humidity (RH), air exchange rate, and volatile organic compound (VOC) properties on the VOC (toluene, n-butyl acetate, ethylbenzene, and m,p-xylene) specific emission rates (SERs) and concentrations from wooden flooring were investigated by chamber test for 8 days. The tested wood in this study is not common solid wood, but composite wood made of combined wood fibers. The experiments were conducted in a stainless-steel environmental test chamber coated with Teflon. The experimental results within 8 days of testing showed that, when the temperature increased from 15 to 30 C, the VOC SERs and concentrations increased 1.5-129 times. When the RH increased from 50% to 80%, the VOC concentrations and SERs increased 1-32 times. When the air change rate increased from 1 to 2 h{sup -1}, the VOC concentrations decreased 9-40%, while the VOC SERs increased 6-98%. The relations between the boiling points of the VOCs and each of the normalized VOC SERs and concentrations were linear with negative slopes. The relations between the vapor pressures of the VOCs and each of the normalized VOC SERs and concentrations were linear with positive slopes. At 15 C, RH50%, the relations between the diffusivities of VOCs and each of the normalized VOC equilibrium SERs and concentrations were linear with a positive slope. (author)

Building materials. VOC emissions, diffusion behaviour and implications from their use.

Science.gov (United States)

Katsoyiannis, Athanasios; Leva, Paolo; Barrero-Moreno, Josefa; Kotzias, Dimitrios

2012-10-01

Five cement- and five lime-based building materials were examined in an environmental chamber for their emissions of Volatile Organic Compounds (VOCs). Typical VOCs were below detection limits, whereas not routinely analysed VOCs, like neopentyl glycol (NPG), dominated the cement-based products emissions, where, after 72 h, it was found to occur, in levels as high as 1400 μg m(-3), accounting for up to 93% of total VOCs. The concentrations of NPG were not considerably changed between the 24 and 72 h of sampling. The permeability of building materials was assessed through experiments with a dual environmental chamber; it was shown that building materials facilitate the diffusion of chemicals through their pores, reaching equilibrium relatively fast (6 h). Copyright © 2012 Elsevier Ltd. All rights reserved.

Gasoline prices and traffic crashes in Alabama, 1999-2009.

Science.gov (United States)

Chi, Guangqing; McClure, Timothy E; Brown, David B

2012-09-01

The price of gasoline has been found to be negatively associated with traffic crashes in a limited number of studies. However, most of the studies have focused either on fatal crashes only or on all crashes but measured over a very short time period. In this study, we examine gasoline price effects on all traffic crashes by demographic groups in the state of Alabama from 1999 to 2009. Using negative binomial regression techniques to examine monthly data from 1999 to 2009 in the state of Alabama, we estimate the effects of changes in gasoline price on changes in automobile crashes. We also examine how these effects differ by age group (16-20, 21-25, 26-30, 31-64, and 65+), gender (male and female), and race/ethnicity (non-Hispanic white, non-Hispanic black, and Hispanic). The results show that gasoline prices have both short-term and long-term effects on reducing total traffic crashes and crashes of each age, gender, and race/ethnicity group (except Hispanic due to data limitations). The short-term and long-term effects are not statistically different for each individual demographic group. Gasoline prices have a stronger effect in reducing crashes involving drivers aged 16 to 20 than crashes involving drivers aged 31 to 64 and 65+ in the short term; the effects, however, are not statistically different across other demographic groups. Although gasoline price increases are not favored, our findings show that gasoline price increases (or decreases) are associated with reductions (or increases) in the incidence of traffic crashes. If gasoline prices had remained at the 1999 level of $1.41 from 1999 to 2009, applying the estimated elasticities would result in a predicted increase in total crashes of 169,492 (or 11.3%) from the actual number of crashes. If decision makers wish to reduce traffic crashes, increasing gasoline taxes is a possible option-however, doing so would increase travel costs and lead to equity concerns. These findings may help to shape transportation

Gasoline risk management: a compendium of regulations, standards, and industry practices.

Science.gov (United States)

Swick, Derek; Jaques, Andrew; Walker, J C; Estreicher, Herb

2014-11-01

This paper is part of a special series of publications regarding gasoline toxicology testing and gasoline risk management; this article covers regulations, standards, and industry practices concerning gasoline risk management. Gasoline is one of the highest volume liquid fuel products produced globally. In the U.S., gasoline production in 2013 was the highest on record (API, 2013). Regulations such as those pursuant to the Clean Air Act (CAA) (Clean Air Act, 2012: § 7401, et seq.) and many others provide the U.S. federal government with extensive authority to regulate gasoline composition, manufacture, storage, transportation and distribution practices, worker and consumer exposure, product labeling, and emissions from engines and other sources designed to operate on this fuel. The entire gasoline lifecycle-from manufacture, through distribution, to end-use-is subject to detailed, complex, and overlapping regulatory schemes intended to protect human health, welfare, and the environment. In addition to these legal requirements, industry has implemented a broad array of voluntary standards and best management practices to ensure that risks from gasoline manufacturing, distribution, and use are minimized. Copyright © 2014 The Authors. Published by Elsevier Inc. All rights reserved.

40 CFR 80.27 - Controls and prohibitions on gasoline volatility.

Science.gov (United States)

2010-07-01

... 40 Protection of Environment 16 2010-07-01 2010-07-01 false Controls and prohibitions on gasoline... prohibitions on gasoline volatility. (a)(1) Prohibited activities in 1991. During the 1991 regulatory control... shall sell, offer for sale, dispense, supply, offer for supply, or transport gasoline whose Reid vapor...

Belowground communication: impacts of volatile organic compounds (VOCs) from soil fungi on other soil-inhabiting organisms.

Science.gov (United States)

Werner, Stephanie; Polle, Andrea; Brinkmann, Nicole

2016-10-01

We reviewed the impact of fungal volatile organic compounds (VOCs) on soil-inhabiting organisms and their physiological and molecular consequences for their targets. Because fungi can only move by growth to distinct directions, a main mechanism to protect themselves from enemies or to manipulate their surroundings is the secretion of exudates or VOCs. The importance of VOCs in this regard has been significantly underestimated. VOCs not only can be means of communication, but also signals that are able to specifically manipulate the recipient. VOCs can reprogram root architecture of symbiotic partner plants or increase plant growth leading to enlarged colonization surfaces. VOCs are also able to enhance plant resistance against pathogens by activating phytohormone-dependent signaling pathways. In some cases, they were phytotoxic. Because the response was specific to distinct species, fungal VOCs may contribute to regulate the competition of plant communities. Additionally, VOCs are used by the producing fungus to attack rivaling fungi or bacteria, thereby protecting the emitter or its nutrient sources. In addition, animals, like springtails, nematodes, and earthworms, which are important components of the soil food web, respond to fungal VOCs. Some VOCs are effective repellents for nematodes and, therefore, have applications as biocontrol agents. In conclusion, this review shows that fungal VOCs have a huge impact on soil fauna and flora, but the underlying mechanisms, how VOCs are perceived by the recipients, how they manipulate their targets and the resulting ecological consequences of VOCs in inter-kingdom signaling is only partly understood. These knowledge gaps are left to be filled by future studies.

Estimation of sources and factors affecting indoor VOC levels using basic numerical methods

Directory of Open Access Journals (Sweden)

Sibel Mentese

2016-11-01

Full Text Available Volatile Organic Compounds (VOCs are a concern due to their adverse health effects and extensive usage. Levels of indoor VOCs were measured in six homes located in three different towns in Çanakkale, Turkey. Monthly indoor VOC samples were collected by passive sampling throughout a year. The highest levels of total volatile organic compounds (TVOC, benzene, toluene, and xylenes occurred in industrial, rural, and urban sites in a descending order. VOC levels were categorized as average values annually, during the heating period, and non-heating period. Several building/environmental factors together with occupants’ habits were scored to obtain a basic indoor air pollution index (IAPi for the homes. Bivariate regression analysis was applied to find the associations between the pollutant levels and home scores. IAPi scores were found to be correlated with average indoor VOC levels. In particular, very strong associations were found for occupants’ habits. Furthermore, observed indoor VOC levels were categorized by using self-organizing map (SOM and two simple scoring approaches, rounded average and maximum value methods, to classify the indoor environments based on their VOC compositions (IAPvoc. Three classes were used for both IAPi and IAPvoc approaches, namely “good”, “moderate”, and “bad”. There is an urgent need for indexing studies to determine the potential sources and/or factors affecting observed VOCs. This study gives a basic but good start for further studies.

Variability of indoor and outdoor VOC measurements: An analysis using variance components

International Nuclear Information System (INIS)

Jia, Chunrong; Batterman, Stuart A.; Relyea, George E.

2012-01-01

This study examines concentrations of volatile organic compounds (VOCs) measured inside and outside of 162 residences in southeast Michigan, U.S.A. Nested analyses apportioned four sources of variation: city, residence, season, and measurement uncertainty. Indoor measurements were dominated by seasonal and residence effects, accounting for 50 and 31%, respectively, of the total variance. Contributions from measurement uncertainty (<20%) and city effects (<10%) were small. For outdoor measurements, season, city and measurement variation accounted for 43, 29 and 27% of variance, respectively, while residence location had negligible impact (<2%). These results show that, to obtain representative estimates of indoor concentrations, measurements in multiple seasons are required. In contrast, outdoor VOC concentrations can use multi-seasonal measurements at centralized locations. Error models showed that uncertainties at low concentrations might obscure effects of other factors. Variance component analyses can be used to interpret existing measurements, design effective exposure studies, and determine whether the instrumentation and protocols are satisfactory. - Highlights: ► The variability of VOC measurements was partitioned using nested analysis. ► Indoor VOCs were primarily controlled by seasonal and residence effects. ► Outdoor VOC levels were homogeneous within neighborhoods. ► Measurement uncertainty was high for many outdoor VOCs. ► Variance component analysis is useful for designing effective sampling programs. - Indoor VOC concentrations were primarily controlled by seasonal and residence effects; and outdoor concentrations were homogeneous within neighborhoods. Variance component analysis is a useful tool for designing effective sampling programs.

Gasoline prices and the public interest

International Nuclear Information System (INIS)

1997-12-01

The concerns that have been raised about gasoline prices in Newfoundland were addressed and the reasons why they differ significantly from one part of Newfoundland to another were examined. A research and investigation program was established to identify the factors contributing to the price of, and price variation in gasoline sold in the province. Companies directly involved in the gasoline retail business in the province were invited to answer an extensive questionnaire which asked detailed, confidential information concerning the company's operations. This report contains the results of the analysis of the responses, and provides a comprehensive picture of the operation of the petroleum industry. It also contains a series of recommendations for the government with respect to monitoring price fluctuations, gathering data about the industry, and constructing an independently owned and operated terminal storage facility. The report recommends against direct regulation. tabs., figs

The butane as a component for the gasoline blending

International Nuclear Information System (INIS)

Gicheva, Ljubica

2002-01-01

In OKTA Crude Oil Refinery - Skopje the production of butane as a pure component is based on a liquid phase and it is used for both TNG (propane-butane gas) and motor gasoline production with a quality that satisfy the standard. By using the butane as a gasoline component the quality of the MB-98 and BMB has been improved. The butane itself ensures octane improvement of the pool, by what the content of the lead additives or the octane of the main component - reformat decreases. Also, the butane addition decreases the density of the final products by what the financial effects have been improved. It is also interesting to explain the usage of butane for gasoline production concerning the new proposed standard. The paper presents the practical results, through tables and diagrams, of the butane usage as a component for gasoline production, as well as the butane influence to the quality of the produced gasoline. (Original)

Dynamic behavior of gasoline fuel cell electric vehicles

Science.gov (United States)

Mitchell, William; Bowers, Brian J.; Garnier, Christophe; Boudjemaa, Fabien

As we begin the 21st century, society is continuing efforts towards finding clean power sources and alternative forms of energy. In the automotive sector, reduction of pollutants and greenhouse gas emissions from the power plant is one of the main objectives of car manufacturers and innovative technologies are under active consideration to achieve this goal. One technology that has been proposed and vigorously pursued in the past decade is the proton exchange membrane (PEM) fuel cell, an electrochemical device that reacts hydrogen with oxygen to produce water, electricity and heat. Since today there is no existing extensive hydrogen infrastructure and no commercially viable hydrogen storage technology for vehicles, there is a continuing debate as to how the hydrogen for these advanced vehicles will be supplied. In order to circumvent the above issues, power systems based on PEM fuel cells can employ an on-board fuel processor that has the ability to convert conventional fuels such as gasoline into hydrogen for the fuel cell. This option could thereby remove the fuel infrastructure and storage issues. However, for these fuel processor/fuel cell vehicles to be commercially successful, issues such as start time and transient response must be addressed. This paper discusses the role of transient response of the fuel processor power plant and how it relates to the battery sizing for a gasoline fuel cell vehicle. In addition, results of fuel processor testing from a current Renault/Nuvera Fuel Cells project are presented to show the progress in transient performance.

Gasoline Biodesulfurization DE-FC07-97ID13570 FINAL REPORT

Energy Technology Data Exchange (ETDEWEB)

Pienkos, Philip T.

2002-01-15

Nine strains were identified to grow with gasoline as sole sulfur source. Two different genes were cloned from Gordonia terrae KGB1 and tested for the ability to support gasoline BDS. The first of these, fmoA, was cloned by screening a KGB1 gene library for the ability to convert indole to indigo (a sulfur-regulated capability in KGB1). The fmoA gene was overexpressed in a gasoline tolerant strain of Pseudomonas putida PpG1 and the recombinant strain was shown to convert thiophene to a dimer of thiophene sulfoxide at rates nearly two orders of magnitude higher than KGB1 could catalyze the reaction. Despite this high activity the recombinant PpG1 was unable to demonstrate any activity against gasoline either in shake flask or in bench-scale gasoline BDS bioreactor. A second gene (toeA) was cloned from KGB1 and shown to support growth of Rhodococcus erythropolis JB55 on gasoline. The toeA gene was also identified in another gasoline strain T. wratislaviensis EMT4, and was identified as a homolog of dszA from R. erythropolis IGTS8. Expression of this gene in JB55 supported conversion of DBTO2 (the natural substrate for DszA) to HPBS, but activity against gasoline was low and BDS results were inconsistent. It appeared that activity was directed against C2- and C3-thiophenes. Efforts to increase gene expression by plasmid manipulation, by addition of flavin reductase genes, or by expression in PpG1 were unsuccessful. The DszC protein (DBT monooxygenase) from IGTS8 has very little activity against the sulfur compounds in gasoline, but a mutant enzyme with a substitution of phenylalanine for valine at position 261 was shown to have an altered substrate range. This alteration resulted in increased activity against gasoline, with activity towards mainly C3- and C4-thiophenes and benzothiophene. A mutant library of dszB was constructed by RACHITT (W. C. Coco et al., DNA shuffling method for generating highly recombined genes and evolved enzymes. 2001. Nature Biotech. 19

Selection of Sustainable Technology for VOC Abatement in an Industry: An Integrated AHP-QFD Approach

Science.gov (United States)

Gupta, Alok Kumar; Modi, Bharat A.

2018-04-01

Volatile organic compounds (VOCs) are universally present in global atmospheric pollutants. These VOCs are responsible for photo chemical reaction in atmosphere leading to serious harmful effects on human health and environment. VOCs are produced from both natural and man-made sources and may have good commercial value if it can be utilized as alternate fuel. As per data from US EPA, 15% of total VOC emissions are generated from surface coating industry but VOC concentration and exhaust air volume varies to a great extent and is dependent on processes used by industry. Various technologies are available for abatement of VOCs. Physical, Chemical and Biological technologies are available to remove VOCs by either recovery or destruction with many advantages and limitations. With growing environmental awareness and considering the resource limitations of medium and small scale industries, requirement of a tool for selecting appropriate techno economically viable solution for removal of VOCs from industrial process exhaust is envisaged. The aim of the present study is to provide management a tool to determine the overall effect of implementation of VOC abatement technology on business performance and VOC emissions. The primary purpose of this work is to outline a methodology to rate various VOC abatement technologies with respect to the constraint of meeting current and foreseeable future regulatory requirements, operational flexibility and Over All Economics Parameters considering conservation of energy. In this paper an integrated approach has been proposed to select most appropriate abatement technology strategically. Analytical hierarchy process and Quality function deployment have been integrated for Techno-commercial evaluation. A case study on selection of VOC abatement technology for a leading aluminium foil surface coating, lamination and printing facility using this methodology is presented in this study.

Content and Formation Cause of VOCs in Medical Waste Non-incineration Treatment Project

Science.gov (United States)

Dengchao, Jin; Hongjun, Teng; Zhenbo, Bao; Yang, Li

2018-02-01

When medical waste is treated by non-incineration technology, volatile organic compounds in the waste will be volatile out and form odor pollution. This paper studied VOCs productions in medical waste steam treatment project, microwave treatment project and chemical dinifection project. Sampling and analysis were carried out on the waste gas from treatment equipment and the gas in treatment workshop. The contents of nine VOCs were determined. It was found that the VOCs content in the exhaust gas at the outlet of steam treatment unit was much higher than that of microwave and chemical treatment unit, while the content of VOCs in the chemical treatment workshop was higher than that in the steam and microwave treatment workshop. The formation causes of VOCs were also analyzed and discussed in this paper.

688 AMBIENT VOLATILE ORGANIC COMPOUNDS (VOCS ...

African Journals Online (AJOL)

Osondu

using Gas Chromatography (GC) fitted with Flame Ionization Detector (FID). ... and Industrial emission were identified as sources of VOCs in the studied .... Wax, IIasamaja Market, Chesebrough way, ... A validation processes for diffusive.

Membrane Biotreatment of VOC-Laden Air

National Research Council Canada - National Science Library

Peretti, Stephen

2000-01-01

...%, depending primarily on air contact time. Octanol was used as the stripping fluid because of its low vapor pressure and water solubility, its high partitioning of VOCs from air, and its compatibility...

Building materials. VOC emissions, diffusion behaviour and implications from their use

International Nuclear Information System (INIS)

Katsoyiannis, Athanasios; Leva, Paolo; Barrero-Moreno, Josefa; Kotzias, Dimitrios

2012-01-01

Five cement- and five lime-based building materials were examined in an environmental chamber for their emissions of Volatile Organic Compounds (VOCs). Typical VOCs were below detection limits, whereas not routinely analysed VOCs, like neopentyl glycol (NPG), dominated the cement-based products emissions, where, after 72 h, it was found to occur, in levels as high as 1400 μg m −3 , accounting for up to 93% of total VOCs. The concentrations of NPG were not considerably changed between the 24 and 72 h of sampling. The permeability of building materials was assessed through experiments with a dual environmental chamber; it was shown that building materials facilitate the diffusion of chemicals through their pores, reaching equilibrium relatively fast (6 h). - Highlights: ► Neopentyl glycol is reported in emissions from building materials for the first time. ► Neopentyl glycol dominates the VOC emissions from cement-based building materials. ► A dual chamber was developed to control diffusion through building materials. ► Building materials facilitate diffusion of indoor air pollutants through their pores. - Neopentyl glycol was detected in high concentrations in emissions from building materials.

FEV manoeuvre induced changes in breath VOC compositions: an unconventional view on lung function tests

Science.gov (United States)

Sukul, Pritam; Schubert, Jochen K.; Oertel, Peter; Kamysek, Svend; Taunk, Khushman; Trefz, Phillip; Miekisch, Wolfram

2016-06-01

Breath volatile organic compound (VOC) analysis can open a non-invasive window onto pathological and metabolic processes in the body. Decades of clinical breath-gas analysis have revealed that changes in exhaled VOC concentrations are important rather than disease specific biomarkers. As physiological parameters, such as respiratory rate or cardiac output, have profound effects on exhaled VOCs, here we investigated VOC exhalation under respiratory manoeuvres. Breath VOCs were monitored by means of real-time mass-spectrometry during conventional FEV manoeuvres in 50 healthy humans. Simultaneously, we measured respiratory and hemodynamic parameters noninvasively. Tidal volume and minute ventilation increased by 292 and 171% during the manoeuvre. FEV manoeuvre induced substance specific changes in VOC concentrations. pET-CO2 and alveolar isoprene increased by 6 and 21% during maximum exhalation. Then they decreased by 18 and 37% at forced expiration mirroring cardiac output. Acetone concentrations rose by 4.5% despite increasing minute ventilation. Blood-borne furan and dimethyl-sulphide mimicked isoprene profile. Exogenous acetonitrile, sulphides, and most aliphatic and aromatic VOCs changed minimally. Reliable breath tests must avoid forced breathing. As isoprene exhalations mirrored FEV performances, endogenous VOCs might assure quality of lung function tests. Analysis of exhaled VOC concentrations can provide additional information on physiology of respiration and gas exchange.

Source apportionment of ambient volatile organic compounds in the Pearl River Delta, China: Part II

Science.gov (United States)

Liu, Ying; Shao, Min; Lu, Sihua; Chang, Chih-Chung; Wang, Jia-Lin; Fu, Linlin

The chemical mass balance receptor model was applied to the source apportionment of 58 hydrocarbons measured at seven sites in a field campaign that examined regional air quality in the Pearl River Delta (PRD) region in the fall of 2004. A total of 12 volatile organic compound (VOC) emission sources were considered, including gasoline- and diesel-powered vehicle exhausts, headspace vapors of gasoline and diesel fuel, vehicle evaporative emissions, liquid petroleum gas (LPG) leakage, paint vapors, asphalt emissions from paved roads, biomass combustion, coal combustion, the chemical industry, and petroleum refineries. Vehicle exhaust was the largest source of VOCs, contributing to >50% of ambient VOCs at the three urban sites (Guangzhou, Foshan, and Zhongshan). LPG leakage played an important role, representing 8-16% of emissions at most sites in the PRD. Solvent usage was the biggest emitter of VOCs at Dongguan, an industrial site, contributing 33% of ambient VOCs. Similarly, at Xinken, a non-urban site, the evaporation of solvents and coatings was the largest emission source, accounting for 31% of emissions, probably because it was downwind of Dongguan. Local biomass combustion was a noticeable source of VOCs at Xinken; although its contribution was estimated at 14.3%, biomass combustion was the third largest VOC source at this site.

Use of biofilters and suspended-growth reactors to treat VOC's

Energy Technology Data Exchange (ETDEWEB)

Neal, A.B.; Loehr, R.C.

2000-07-01

The greater limits placed on volatile organic compound (VOC) emissions by the Clean Air Act Amendments have stimulated evaluation of various VOC treatment methods. Two applicable gas phase treatment technologies are biofiltration and suspended growth reactors. Biofiltration removes contaminants from gas streams that are passed through a bed of biologically active solids. An aerobic suspended-growth reactor (SGR) removes VOCs by biologically treating contaminated air bubbled through an aqueous suspension of active microorganisms. This research compared the performance of a typical compost biofilter to a SGR for the removal of a common VOC (toluene) from gas streams. The objective was to evaluate the impact of mass loading on process performance. Major performance parameters investigated were (1) mass emitted and elimination capacity, (2) off-gas concentrations exiting each type of reactor for various mass loadings, and (3) removal efficiencies obtained by each type of reactor. The results indicated that SGRs can effectively treat gases containing VOCs. For mass loadings ranging from 5 to 30 mg/l-h, the biofilters and SGRs achieved similar VOC removals, in the range of 96--99.7%. Drying of the biofilter medium occurred a high mass loadings. In the SGRs, at mass loadings greater than 17 mg/l-h, process performance decreased when an unknown colored substance was present.

Laminar Burning Velocities of Fuels for Advanced Combustion Engines (FACE) Gasoline and Gasoline Surrogates with and without Ethanol Blending Associated with Octane Rating

KAUST Repository

Mannaa, Ossama

2016-05-04

Laminar burning velocities of fuels for advanced combustion engines (FACE) C gasoline and of several blends of surrogate toluene reference fuels (TRFs) (n-heptane, iso-octane, and toluene mixtures) of the same research octane number are presented. Effects of ethanol addition on laminar flame speed of FACE-C and its surrogate are addressed. Measurements were conducted using a constant volume spherical combustion vessel in the constant pressure, stable flame regime at an initial temperature of 358 K and initial pressures up to 0.6 MPa with the equivalence ratios ranging from 0.8 to 1.6. Comparable values in the laminar burning velocities were measured for the FACE-C gasoline and the proposed surrogate fuel (17.60% n-heptane + 77.40% iso-octane + 5% toluene) over the range of experimental conditions. Sensitivity of flame propagation to total stretch rate effects and thermo-diffusive instability was quantified by determining Markstein length. Two percentages of an oxygenated fuel of ethanol as an additive, namely, 60 vol% and 85 vol% were investigated. The addition of ethanol to FACE-C and its surrogate TRF-1 (17.60% n-heptane + 77.40% iso-octane + 5% toluene) resulted in a relatively similar increase in the laminar burning velocities. The high-pressure measured values of Markstein length for the studied fuels blended with ethanol showed minimal influence of ethanol addition on the flame’s response to stretch rate and thermo-diffusive instability. © 2016 Taylor & Francis.

Laminar Burning Velocities of Fuels for Advanced Combustion Engines (FACE) Gasoline and Gasoline Surrogates with and without Ethanol Blending Associated with Octane Rating

KAUST Repository

Mannaa, Ossama; Mansour, Morkous S.; Roberts, William L.; Chung, Suk-Ho

2016-01-01

Laminar burning velocities of fuels for advanced combustion engines (FACE) C gasoline and of several blends of surrogate toluene reference fuels (TRFs) (n-heptane, iso-octane, and toluene mixtures) of the same research octane number are presented. Effects of ethanol addition on laminar flame speed of FACE-C and its surrogate are addressed. Measurements were conducted using a constant volume spherical combustion vessel in the constant pressure, stable flame regime at an initial temperature of 358 K and initial pressures up to 0.6 MPa with the equivalence ratios ranging from 0.8 to 1.6. Comparable values in the laminar burning velocities were measured for the FACE-C gasoline and the proposed surrogate fuel (17.60% n-heptane + 77.40% iso-octane + 5% toluene) over the range of experimental conditions. Sensitivity of flame propagation to total stretch rate effects and thermo-diffusive instability was quantified by determining Markstein length. Two percentages of an oxygenated fuel of ethanol as an additive, namely, 60 vol% and 85 vol% were investigated. The addition of ethanol to FACE-C and its surrogate TRF-1 (17.60% n-heptane + 77.40% iso-octane + 5% toluene) resulted in a relatively similar increase in the laminar burning velocities. The high-pressure measured values of Markstein length for the studied fuels blended with ethanol showed minimal influence of ethanol addition on the flame’s response to stretch rate and thermo-diffusive instability. © 2016 Taylor & Francis.

A comparative study of fungal and bacterial biofiltration treating a VOC mixture

International Nuclear Information System (INIS)

Estrada, José M.; Hernández, Sergio; Muñoz, Raúl; Revah, Sergio

2013-01-01

Highlights: ► Bacterial biofilter showed better EC and ΔP than fungal biofilter. ► The preferential biodegradation order was: propanal > hexanol > MIBK > toluene. ► Propanal partially inhibited the biodegradation of the rest of VOCs. ► The two-stage biofilter showed a higher stability than the individual units. -- Abstract: Bacterial biofilters usually exhibit a high microbial diversity and robustness, while fungal biofilters have been claimed to better withstand low moisture contents and pH values, and to be more efficient coping with hydrophobic volatile organic compounds (VOCs). However, there are only few systematic evaluations of both biofiltration technologies. The present study compared fungal and bacterial biofiltration for the treatment of a VOC mixture (propanal, methyl isobutyl ketone-MIBK, toluene and hexanol) under the same operating conditions. Overall, fungal biofiltration supported lower elimination capacities than its bacterial counterpart (27.7 ± 8.9 vs 40.2 ± 5.4 g C m −3 reactor h −1 ), which exhibited a final pressure drop 60% higher than that of the bacterial biofilter due to mycelial growth. The VOC mineralization ratio was also higher in the bacterial bed (≈63% vs ≈43%). However, the substrate biodegradation preference order was similar for both biofilters (propanal > hexanol > MIBK > toluene) with propanal partially inhibiting the consumption of the rest of the VOCs. Both systems supported an excellent robustness versus 24 h VOC starvation episodes. The implementation of a fungal/bacterial coupled system did not significantly improve the VOC removal performance compared to the individual biofilter performances

A comparative study of fungal and bacterial biofiltration treating a VOC mixture

Energy Technology Data Exchange (ETDEWEB)

Estrada, José M. [Departamento de Procesos y Tecnología, Universidad Autónoma Metropolitana-Cuajimalpa, Artificios 40, Col. Miguel Hidalgo, Delegación Álvaro Obregón (Mexico); Departamento de Ingeniería Química y Tecnología del Medio Ambiente – Universidad de Valladolid, Valladolid (Spain); Hernández, Sergio [Departmento de Procesos e Hidráulica – Universidad Autónoma Metropolitana – Iztapalapa Mexico D.F. Mexico (Mexico); Muñoz, Raúl [Departamento de Ingeniería Química y Tecnología del Medio Ambiente – Universidad de Valladolid, Valladolid (Spain); Revah, Sergio, E-mail: srevah@xanum.uam.mx [Departamento de Procesos y Tecnología, Universidad Autónoma Metropolitana-Cuajimalpa, Artificios 40, Col. Miguel Hidalgo, Delegación Álvaro Obregón (Mexico)

2013-04-15

Highlights: ► Bacterial biofilter showed better EC and ΔP than fungal biofilter. ► The preferential biodegradation order was: propanal > hexanol > MIBK > toluene. ► Propanal partially inhibited the biodegradation of the rest of VOCs. ► The two-stage biofilter showed a higher stability than the individual units. -- Abstract: Bacterial biofilters usually exhibit a high microbial diversity and robustness, while fungal biofilters have been claimed to better withstand low moisture contents and pH values, and to be more efficient coping with hydrophobic volatile organic compounds (VOCs). However, there are only few systematic evaluations of both biofiltration technologies. The present study compared fungal and bacterial biofiltration for the treatment of a VOC mixture (propanal, methyl isobutyl ketone-MIBK, toluene and hexanol) under the same operating conditions. Overall, fungal biofiltration supported lower elimination capacities than its bacterial counterpart (27.7 ± 8.9 vs 40.2 ± 5.4 g C m{sup −3} reactor h{sup −1}), which exhibited a final pressure drop 60% higher than that of the bacterial biofilter due to mycelial growth. The VOC mineralization ratio was also higher in the bacterial bed (≈63% vs ≈43%). However, the substrate biodegradation preference order was similar for both biofilters (propanal > hexanol > MIBK > toluene) with propanal partially inhibiting the consumption of the rest of the VOCs. Both systems supported an excellent robustness versus 24 h VOC starvation episodes. The implementation of a fungal/bacterial coupled system did not significantly improve the VOC removal performance compared to the individual biofilter performances.

Sources of long-lived atmospheric VOCs at the rural boreal forest site, SMEAR II

Science.gov (United States)

Patokoski, J.; Ruuskanen, T. M.; Kajos, M. K.; Taipale, R.; Rantala, P.; Aalto, J.; Ryyppö, T.; Nieminen, T.; Hakola, H.; Rinne, J.

2015-12-01

In this study a long-term volatile organic compound (VOCs) concentration data set, measured at the SMEAR II (Station for Measuring Ecosystem-Atmosphere Relations) boreal forest site in Hyytiälä, Finland during the years 2006-2011, was analyzed in order to identify source areas and profiles of the observed VOCs. VOC mixing ratios were measured using proton transfer reaction mass spectrometry. Four-day HYSPLIT 4 (Hybrid Single Particle Lagrangian Integrated Trajectory) backward trajectories and the Unmix 6.0 receptor model were used for source area and source composition analysis. Two major forest fire events in Russia took place during the measurement period. The effect of these fires was clearly visible in the trajectory analysis, lending confidence to the method employed with this data set. Elevated volume mixing ratios (VMRs) of non-biogenic VOCs related to forest fires, e.g. acetonitrile and aromatic VOCs, were observed. Ten major source areas for long-lived VOCs (methanol, acetonitrile, acetaldehyde, acetone, benzene, and toluene) observed at the SMEAR II site were identified. The main source areas for all the targeted VOCs were western Russia, northern Poland, Kaliningrad, and the Baltic countries. Industrial areas in northern continental Europe were also found to be source areas for certain VOCs. Both trajectory and receptor analysis showed that air masses from northern Fennoscandia were less polluted with respect to both the VOCs studied and other trace gases (CO, SO2 and NOx), compared to areas of eastern and western continental Europe, western Russia, and southern Fennoscandia.

Application of positive matrix factorization to on-road measurements for source apportionment of diesel- and gasoline-powered vehicle emissions in Mexico City

Directory of Open Access Journals (Sweden)

D. A. Thornhill

2010-04-01

-based estimates of emissions are lower than in the official inventory for CO and NO_x and higher for VOCs. For NO_x, the fuel-based estimates are lower for gasoline-powered vehicles but higher for diesel-powered ones compared to the official inventory. While conclusions regarding the inventory should be interpreted with care because of the small sample size, 3.5 h of driving, the discrepancies with the official inventory agree with those reported in other studies.

Non-thermal plasmas for non-catalytic and catalytic VOC abatement

International Nuclear Information System (INIS)

Vandenbroucke, Arne M.; Morent, Rino; De Geyter, Nathalie; Leys, Christophe

2011-01-01

Highlights: → We review the current status of catalytic and non-catalytic VOC abatement based on a vast number of research papers. → The underlying mechanisms of plasma-catalysis for VOC abatement are discussed. → Critical process parameters that determine the influent are discussed and compared. - Abstract: This paper reviews recent achievements and the current status of non-thermal plasma (NTP) technology for the abatement of volatile organic compounds (VOCs). Many reactor configurations have been developed to generate a NTP at atmospheric pressure. Therefore in this review article, the principles of generating NTPs are outlined. Further on, this paper is divided in two equally important parts: plasma-alone and plasma-catalytic systems. Combination of NTP with heterogeneous catalysis has attracted increased attention in order to overcome the weaknesses of plasma-alone systems. An overview is given of the present understanding of the mechanisms involved in plasma-catalytic processes. In both parts (plasma-alone systems and plasma-catalysis), literature on the abatement of VOCs is reviewed in close detail. Special attention is given to the influence of critical process parameters on the removal process.

Smartphone-based sensing system using ZnO and graphene modified electrodes for VOCs detection.

Science.gov (United States)

Liu, Lei; Zhang, Diming; Zhang, Qian; Chen, Xing; Xu, Gang; Lu, Yanli; Liu, Qingjun

2017-07-15

Volatile organic compounds (VOCs) detection is in high demand for clinic treatment, environment monitoring, and food quality control. Especially, VOCs from human exhaled breath can serve as significant biomarkers of some diseases, such as lung cancer and diabetes. In this study, a smartphone-based sensing system was developed for real-time VOCs monitoring using alternative current (AC) impedance measurement. The interdigital electrodes modified with zinc oxide (ZnO), graphene, and nitrocellulose were used as sensors to produce impedance responses to VOCs. The responses could be detected by a hand-held device, sent out to a smartphone by Bluetooth, and reported with concentration on an android program of the smartphone. The smartphone-based system was demonstrated to detect acetone at concentrations as low as 1.56ppm, while AC impedance spectroscopy was used to distinguish acetone from other VOCs. Finally, measurements of the exhalations from human being were carried out to obtain the concentration of acetone in exhaled breath before and after exercise. The results proved that the smartphone-based system could be applied on the detection of VOCs in real settings for healthcare diagnosis. Thus, the smartphone-based system for VOCs detection provided a convenient, portable and efficient approach to monitor VOCs in exhaled breath and possibly allowed for early diagnosis of some diseases. Copyright © 2016 Elsevier B.V. All rights reserved.

An updated emission inventory of vehicular VOCs and IVOCs in China

Directory of Open Access Journals (Sweden)

H. Liu

2017-10-01

Full Text Available Currently, the emission inventory of vehicular volatile organic compounds (VOCs is one of those with the largest errors and uncertainties due to suboptimal estimation methods and the lack of first-hand basic data. In this study, an updated speciated emission inventory of VOCs and an estimation of intermediate-volatility organic compounds (IVOCs from vehicles in China at the provincial level for the year of 2015 are developed based on a set of state-of-the-art methods and an abundance of local measurement data. Activity data for light-duty vehicles are derived from trajectories of more than 70 000 cars for 1 year. The annual mileage of trucks are calculated from reported data by more than 2 million trucks in China. The emission profiles are updated using measurement data. Vehicular tailpipe emissions (VTEs and four types of vehicular evaporation emissions (VEEs, including refueling, hot soak, diurnal and running loss, are taken into account. Results show that the total vehicular VOC emissions in China are 4.21 Tg (with a 95 % confidence interval range from 2.90 to 6.54 Tg and the IVOC emissions are 200.37 Gg in 2015. VTEs are still the predominant contributor, while VEEs are responsible for 39.20 % of VOC emissions. The control of VEEs is yet to be optimized in China. Among VTEs, passenger vehicles emissions have the largest share (49.86 %, followed by trucks (28.15 % and motorcycles (21.99 %. Among VEEs, running loss is the largest contributor (81.05 %. For both VTEs and VEEs, Guangdong, Shandong and Jiangsu province are three of the highest, with a respective contribution of 10.66, 8.85 and 6.54 % to the total amounts of VOCs from vehicles. 97 VOC species are analyzed in this VOC emission inventory. i-Pentane, toluene and formaldehyde are found to be the most abundant species in China's vehicular VOC emissions. The estimated IVOCs are another inconvenient truth, concluding that precursor emissions for secondary organic

Assessment of subsurface VOCs using a chemical microsensor array

International Nuclear Information System (INIS)

Batterman, S.A.; Zellers, E.T.

1993-06-01

This report describes the results of laboratory investigations of several performance parameters relevant to surface-acoustic-wave (SAW) chemical sensor arrays for the measurement of volatile organic compounds (VOCs) in contaminated soil and groundwater. The small size, low cost, sensitivity and selectivity of such instruments promise improvements in the quality and quantity of data used to guide site assessment and restoration efforts. In this investigation, calibrations were performed for 15 different coated SAW sensors. Each sensor was exposed to six VOCs selected to represent three chemical classes of contaminants that are commonly found at waste sites (i.e., aliphatic, aromatic and chlorinated hydrocarbons). A new pattern recognition method was developed for determining which coated sensors would maximize the selectivity and accuracy of quantitation for a given set of vapor contaminants. Using this method, an optimal subwet of four coated sensors was selected for testing in a prototype microsensor instrument. Additional laboratory experiments were performed with this optimized array to assess the limits of detection and linear response ranges for the representative vapors, as well as the additivity of responses to vapors in binary mixtures, temperature and humidity effects, aging effects, and other performance parameters related to the application of this technology to soil and groundwater VOC monitoring. Results demonstrate that SAW microsensor arrays can identify and quantify specific VOCs at concentrations in the μg/L to mg/L range when present alone or in simple (e.g., binary) mixtures. SAW sensor technology offers a potentially effective alternative to existing field instrumentation for headspace analysis, soil vapor monitoring, and vacuum extraction process monitoring of VOCs in subsurface media

VOCs in Non-Arid Soils Integrated Demonstration: Technology summary

International Nuclear Information System (INIS)

1994-02-01

The Volatile Organic Compounds (VOCs) in Non-Arid Soils Integrated Demonstration (ID) was initiated in 1989. Objectives for the ID were to test the integrated demonstration concept, demonstrate and evaluate innovative technologies/systems for the remediation of VOC contamination in soils and groundwater, and to transfer technologies and systems to internal and external customers for use in fullscale remediation programs. The demonstration brought together technologies from DOE laboratories, other government agencies, and industry for demonstration at a single test bed. The Savannah River Site was chosen as the location for this ID as the result of having soil and groundwater contaminated with VOCS. The primary contaminants, trichlorethylene and tetrachloroethylene, originated from an underground process sewer line servicing a metal fabrication facility at the M-Area. Some of the major technical accomplishments for the ID include the successful demonstration of the following: In situ air stripping coupled with horizontal wells to remediate sites through air injection and vacuum extraction; Crosshole geophysical tomography for mapping moisture content and lithologic properties of the contaminated media; In situ radio frequency and ohmic heating to increase mobility, of the contaminants, thereby speeding recovery and the remedial process; High-energy corona destruction of VOCs in the off-gas of vapor recovery wells; Application of a Brayton cycle heat pump to regenerate carbon adsorption media used to trap VOCs from the offgas of recovery wells; In situ permeable flow sensors and the colloidal borescope to determine groundwater flow; Chemical sensors to rapidly quantify chlorinated solvent contamination in the subsurface; In situ bioremediation through methane/nutrient injection to enhance degradation of contaminants by methanotrophic bateria

Increasing competitiveness of wine producers in strategic alliances VOC

Directory of Open Access Journals (Sweden)

Martin Prokeš

2012-01-01

Full Text Available The paper describes the main reasons for the formation of new regional association of wineries, based on a different origin for wines in the wine region of Moravia in the southeast part of the Czech Republic. This research aim is to create a plan for new development of such strategic alliances on the basis of results of localization factors. There coefficient of localization is used for identification of cluster. Results are compared with already operating on associations for the appellation in Austria DAC. They were traced changes in consumer preferences in the Czech wine market. Consumers are placing more emphasis on the selection of wine on its descent from a particular area, growing community and the individual grower. This paper specifically introduces new associations for appellation system VOC. This alliance is described in the context of the establishment, operation, development and expansion, respectively the possibility of involvement of additional organizations suppliers and research institutions. The application of the results of research was a plan for the establishment of new alliance VOC Modré Hory, where are associated 30 wine producers of wine in 5 villages around the center Velké Pavlovice. Based on the experience of newly emerging VOC system of appellations was setting up a plan of formation association with the proposed methodological approach. Open cooperation between associations VOC appellation and other entities involving suppliers, customers, research institutions and universities has the possibility of creating an institutionalized wine cluster. The plan to create a wine cluster was proposed to establish cooperation between the newly emerging associations of VOC at three sub-regions of South Moravia, in order to achieve competitive advantage.

Polycaprolactone-Polydiacetylene Electrospun Fibers for Colorimetric Detection of Fake Gasoline

Directory of Open Access Journals (Sweden)

Shamshad Ali

2016-04-01

Full Text Available PCDA (Pentacosadiynoic Acid monomers were successfully embedded in PCL (Poly ?-Caprolactone polymer matrix by electrospinning process for the first time. The resultant EFM (Electrospun Fibers Mat was photo-polymerized under 254 nm UV light that enables colorimetric detection of fake gasoline. Results revealed that the fake gasoline develops a red color mat within 5 sec. FE-SEM images showed that the fake gasoline treatment dissolved the PCL EFM that give access to interact with PDA polymer. The proposed litmus-type sensor based on PCL-PDA EFM is highly sensitive to fake gasoline and can be fabricated easily

40 CFR 80.240 - What are the small refiner gasoline sulfur standards?

Science.gov (United States)

2010-07-01

... volume of gasoline produced by a small refiner's refinery up to the lesser of: (i) 105% of the baseline gasoline volume as determined under § 80.250(a)(1); or (ii) The volume of gasoline produced at that... 40 Protection of Environment 16 2010-07-01 2010-07-01 false What are the small refiner gasoline...

The crisis of gasoline consumption in the Iran's transportation sector

International Nuclear Information System (INIS)

Houri Jafari, H.; Baratimalayeri, A.

2008-01-01

Fossil fuels have the greatest share in supplying the world's energy demands. Regarding the limited natural resources, fuel consumption management and energy planning in the end-user sectors are two great matters of importance. Among the fossil fuels, gasoline is the principal fuel for light-duty vehicles. In Iran, fuel consumption, especially that of gasoline, has increased sharply with the growth rate of 10.2% for the year 2006 in comparison with that in 2005, turning into a big crisis in the recent years. On the other hand, enormous subsidies for importing 40% of domestic demands, which have reached more than 10 billion US$, are too much to be supplied. In this study, we have assessed the gasoline consumption, production, import and prices; reviewed main causes of the tremendous growth rate of consumption, current conservation policies and their advantages or disadvantages (SWOT analysis); proposed short- to long-term solutions and strategies for efficient gasoline consumption management; and finally, current strategies and proposed solutions are analyzed and evaluated. A foregone conclusion strongly suggests that not only the low price of motor gasoline but also mass production of vehicles with the conventional technology, likewise, affects motor gasoline demand. A second conclusion is that gasoline crisis in Iran has no straight solution, and that fundamental strategies and policies are needed to solve the problem. (author)

Hige Compression Ratio Turbo Gasoline Engine Operation Using Alcohol Enhancement

Energy Technology Data Exchange (ETDEWEB)

Heywood, John [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Jo, Young Suk [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Lewis, Raymond [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Bromberg, Leslie [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Heywood, John [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)

2016-01-29

The overall objective of this project was to quantify the potential for improving the performance and efficiency of gasoline engine technology by use of alcohols to suppress knock. Knock-free operation is obtained by direct injection of a second “anti-knock” fuel such as ethanol, which suppresses knock when, with gasoline fuel, knock would occur. Suppressing knock enables increased turbocharging, engine downsizing, and use of higher compression ratios throughout the engine’s operating map. This project combined engine testing and simulation to define knock onset conditions, with different mixtures of gasoline and alcohol, and with this information quantify the potential for improving the efficiency of turbocharged gasoline spark-ignition engines, and the on-vehicle fuel consumption reductions that could then be realized. The more focused objectives of this project were therefore to: Determine engine efficiency with aggressive turbocharging and downsizing and high compression ratio (up to a compression ratio of 13.5:1) over the engine’s operating range; Determine the knock limits of a turbocharged and downsized engine as a function of engine speed and load; Determine the amount of the knock-suppressing alcohol fuel consumed, through the use of various alcohol-gasoline and alcohol-water gasoline blends, for different driving cycles, relative to the gasoline consumed; Determine implications of using alcohol-boosted engines, with their higher efficiency operation, in both light-duty and medium-duty vehicle sectors.

75 FR 74044 - Agency Information Collection Activities; Proposed Collection; Comment Request; Gasoline Volatility

Science.gov (United States)

2010-11-30

...; Gasoline Volatility AGENCY: Environmental Protection Agency (EPA). ACTION: Notice. SUMMARY: In compliance... entities: Entities potentially affected by this action are those who produce or import gasoline containing... Additives: Gasoline Volatility, Reporting Requirements for Parties Which Produce of Import Gasoline...

The economics of gasoline subsidy cost reduction policy: Case study of Indonesia

Science.gov (United States)

Akimaya, Muhammad I.

A gasoline subsidy distorts the gasoline market with the resulting inefficiencies and takes substantial revenues that arguably could be spent elsewhere with a better impact on economic growth. Governments with such subsidies are aware of their cost yet face difficulties in removing the policy because of strong resistance from the public. This thesis discusses in three essays the problem faced by the government in removing the gasoline subsidy and provides an alternative policy in reducing the subsidy cost applied to the case of Indonesia. In the first essay, we examine the decision-making process from the government's perspective that has an objective of generating savings to fund other programs while maintaining political power, and the influence that the general population has over the decision. Despite the immense literature on political power, there has yet to be any research that mathematically models the decision-making process of a government with influences from the general population. Under the benchmark scenario, the equilibrium strategy is to keep the subsidy intact. However, the results are found to be very sensitive to the magnitude of the shift in political power as well as the preferences of both the government and the people. In the second essay, we estimate the cross-price elasticity of regular gasoline with respect to premium gasoline price. The importance of such knowledge is to accurately determine the impact of fuel pricing policy that tends to have different rates of tax or subsidy depending on the grade of gasoline. Using data on the Mexican gasoline market, regular gasoline demand is estimated with an Autoregressive Distributed Lag (ARDL) model. Endogeneity of the price and structural break are also investigated. The cross-price elasticities between regular and premium gasoline is found to be -0.895, which confirms high substitutability among gasoline with different grades. In the third essay, we look at the unique case of Indonesia that

Rising gasoline prices increase new motorcycle sales and fatalities.

Science.gov (United States)

Zhu, He; Wilson, Fernando A; Stimpson, Jim P; Hilsenrath, Peter E

2015-12-01

We examined whether sales of new motorcycles was a mechanism to explain the relationship between motorcycle fatalities and gasoline prices. The data came from the Motorcycle Industry Council, Energy Information Administration and Fatality Analysis Reporting System for 1984-2009. Autoregressive integrated moving average (ARIMA) regressions estimated the effect of inflation-adjusted gasoline price on motorcycle sales and logistic regressions estimated odds ratios (ORs) between new and old motorcycle fatalities when gasoline prices increase. New motorcycle sales were positively correlated with gasoline prices (r = 0.78) and new motorcycle fatalities (r = 0.92). ARIMA analysis estimated that a US$1 increase in gasoline prices would result in 295,000 new motorcycle sales and, consequently, 233 new motorcycle fatalities. Compared to crashes on older motorcycle models, those on new motorcycles were more likely to be young riders, occur in the afternoon, in clear weather, with a large engine displacement, and without alcohol involvement. Riders on new motorcycles were more likely to be in fatal crashes relative to older motorcycles (OR 1.14, 95 % confidence interval (CI) 1.02-1.28) when gasoline prices increase. Our findings suggest that, in response to increasing gasoline prices, people tend to purchase new motorcycles, and this is accompanied with significantly increased crash risk. There are several policy mechanisms that can be used to lower the risk of motorcycle crash injuries through the mechanism of gas prices and motorcycle sales such as raising awareness of motorcycling risks, enhancing licensing and testing requirements, limiting motorcycle power-to-weight ratios for inexperienced riders, and developing mandatory training programs for new riders.

Development of a novel biofilter for aerobic biodegradation of volatile organic compounds (VOCs)

International Nuclear Information System (INIS)

Govind, R.; Utgikar, V.; Shan, Y.; Zhao, Wang; Sayles, G.D.; Bishop, D.F.; Safferman, S.I.

1992-01-01

In recent years, the emission into the atmosphere of volatile organic compounds (VOCs) has undergone increased regulation by EPA, OSHA and other government agencies due to potential human health hazards. The sources of these VOCs include releases during industrial production and use, from contaminated wastewaters in collection systems and treatment plants, and from hazardous wastes in landfills and contaminated ground water. Conventional methods for treating VOC emissions include adsorption on solids, absorption in solvents, incineration and catalytic oxidation. One alternative to these conventional treatment methods is the biological destruction of the VOCs in gas phase biofilters. This method has the advantage of pollution destruction (as compared to transfer to another medium) at lower operation and maintenance costs. The biofilter method also can be combined with various stripping or vapor extraction separation processes which effectively transfer VOCs from liquid or solid matrices into the gas phase entering biofilters

Pollution characteristic of VOCs of ambient air in winter and spring in Shijiazhuang City

Directory of Open Access Journals (Sweden)

Qing CHANG

2015-06-01

Full Text Available In order to further explore the pollution characteristics of volatile organic compounds in ambient air in winter and spring in Shijiazhuang City, the pollution characteristics of 62 volatile organic compounds (VOCs, monthly and quarterly variation, the correlation between VOCs and PM2.5, and the main sources of VOCs are investigated by using EPA TO-15 method. It shows that 40 organic compounds of the 64 VOCs have been quantitatively determined in winter and spring in the city, which are mainly acetone, benzene, carbon tetrachloride, dichloromethane, toluene, ethyl acetate, etc.. In the no-quantitatively determined components, higher ethanol, butyl acetate, butane etc. are detected. The VOCs concentration has positive correlation with the PM2.5 concentration during haze days.

Electrokinetic enhanced bioventing of gasoline in clayey soil: A case history

International Nuclear Information System (INIS)

Loo, W.W.; Wang, I.S.; Fan, J.

1994-01-01

This paper presents a case history on the bioventing of gasoline in soil with electrokinetic enhancement. The gasoline in soil was related to a 10,000-gallon underground storage tank spill, San Diego, California. The gasoline soil plume covers an area of about 2,400 square feet and to a depth of about 30 feet. The upper 15 feet of the soil plume consists of highly conductive marine clay. The lower 15 feet of the soil plume consists of dense cemented conglomerate sandstone. The gasoline concentration in the soil plume range from 100 to 2,200 mg/Kg(ppm) and the target cleanup level is below 100 ppm. Total gasoline in soil plume is estimated at about 1,000 pounds of gasoline in about 3,500 tons of soil. The soil remediation effort was completed after about 90 days of treatment. The concentration of gasoline in soil after treatment was way below the proposed cleanup level of less than 100 mg/Kg(ppm). The cost of treatment is about $50 per ton for this advanced soil treatment process which provides a cost effective solution to this soil plume with minimum disruption to business operation at the facility

Atomization and spray characteristics of bioethanol and bioethanol blended gasoline fuel injected through a direct injection gasoline injector

International Nuclear Information System (INIS)

Park, Su Han; Kim, Hyung Jun; Suh, Hyun Kyu; Lee, Chang Sik

2009-01-01

The focus of this study was to investigate the spray characteristics and atomization performance of gasoline fuel (G100), bioethanol fuel (E100), and bioethanol blended gasoline fuel (E85) in a direct injection gasoline injector in a gasoline engine. The overall spray and atomization characteristics such as an axial spray tip penetration, spray width, and overall SMD were measured experimentally and predicted by using KIVA-3V code. The development process and the appearance timing of the vortices in the test fuels were very similar. In addition, the numerical results accurately described the experimentally observed spray development pattern and shape, the beginning position of the vortex, and the spray breakup on the spray surface. Moreover, the increased injection pressure induced the occurrence of a clear circular shape in the downstream spray and a uniform mixture between the injected spray droplets and ambient air. The axial spray tip penetrations of the test fuels were similar, while the spray width and spray cone angle of E100 were slightly larger than the other fuels. In terms of atomization performance, the E100 fuel among the tested fuels had the largest droplet size because E100 has a high kinematic viscosity and surface tension.

40 CFR 63.650 - Gasoline loading rack provisions.

Science.gov (United States)

2010-07-01

... 40 Protection of Environment 10 2010-07-01 2010-07-01 false Gasoline loading rack provisions. 63... loading rack provisions. (a) Except as provided in paragraphs (b) through (c) of this section, each owner or operator of a Group 1 gasoline loading rack classified under Standard Industrial Classification...

Effect of ethanol–gasoline blends on CO and HC emissions in last generation SI engines within the cold-start transient: An experimental investigation

International Nuclear Information System (INIS)

Iodice, Paolo; Senatore, Adolfo; Langella, Giuseppe; Amoresano, Amedeo

2016-01-01

Highlights: • This study assesses the effect of ethanol–gasoline blends on cold emissions. • A last generation motorcycle was operated on the chassis dynamometer. • A new calculation procedure was applied to model the cold transient behaviour. • The 20% v/v ethanol blend shows the highest reduction of CO and HC cold emissions. - Abstract: Urban areas in developed countries are characterized by an increasing decline in air quality state mainly due to the exhaust emissions from vehicles. Besides, due to catalyst improvements and electronic mixture control of last generation engines, nowadays CO and HC cold start extra-emissions are heavily higher than emissions exhausted in hot conditions, with a clear consequence on air quality of the urban contexts. Ethanol combined with gasoline can be widely used as an alternative fuel due to the benefit of its high octane number and its self-sustaining characteristics. Ethanol, in fact, is well known as potential alcohol alternative fuel for SI engines, since it can be blended with gasoline to increase oxygen content, then decreasing CO and HC emissions and the depletion of fossil fuels. Literature data about cold emissive behaviour of SI engines powered with ethanol/gasoline blended fuels are rather limited. For this reason, the aim of this study is to experimentally investigate the effect of ethanol/gasoline blends on CO and HC cold start emissions of four-stroke SI engines: a last generation motorcycle was operated on the chassis dynamometer for exhaust emission measurements without change to the engine design, while the ethanol was mixed with unleaded gasoline in different percentages (10, 20 and 30 vol.%). Results of the experimental tests and the application of a new calculation procedure, designed and optimised to model the cold transient behaviour of SI engines using different ethanol–gasoline blends, indicate that CO and HC cold start emissions decrease compared to the use of commercial gasoline, with the 20

46 CFR 169.629 - Compartments containing gasoline machinery or fuel tanks.

Science.gov (United States)

2010-10-01

... 46 Shipping 7 2010-10-01 2010-10-01 false Compartments containing gasoline machinery or fuel tanks. 169.629 Section 169.629 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) NAUTICAL... gasoline machinery or fuel tanks. Spaces containing gasoline machinery or fuel tanks must have natural...

Misunderstood markets: The case of California gasoline

Science.gov (United States)

Thompson, Jennifer Ruth

In 1996, the California Air Resources Board (CARB) implemented a new benchmark for cleaner burning gasoline that is unique to California. Since then, government officials have often expressed concern that the uniqueness of petroleum products in California segregates the industry, allowing for gasoline prices in the State that are too high and too volatile. The growing concern about the segmentation of the California markets lends itself to analysis of spatial pricing. Spatial price spreads of wholesale gasoline within the state exhibit some characteristics that seem, on the surface, inconsistent with spatial price theory. Particularly, some spatial price spreads of wholesale gasoline appear larger than accepted transportation rates and other spreads are negative, giving a price signal for transportation against the physical flow of product. Both characteristics suggest some limitation in the arbitrage process. Proprietary data, consisting of daily product prices for the years 2000 through 2002, disaggregated by company, product, grade, and location is used to examine more closely spatial price patterns. My discussion of institutional and physical infrastructure outlines two features of the industry that limit, but do not prohibit, arbitrage. First, a look into branding and wholesale contracting shows that contract terms, specifically branding agreements, reduces the price-responsiveness of would-be arbitrageurs. Second, review of maps and documents illustrating the layout of physical infrastructure, namely petroleum pipelines, confirms the existence of some connections among markets. My analysis of the day-of-the-week effects on wholesale prices demonstrates how the logistics of the use of transportation infrastructure affect market prices. Further examination of spatial price relationships shows that diesel prices follow closely the Augmented Law of One Price (ALOP), and that branding agreements cause gasoline prices to deviate substantially ALOP. Without branding

VOCs Air Pollutant Cleaning with Polyacrylonitrile/Fly Ash Nanocomposite Electrospun Nanofibrous Membranes

Science.gov (United States)

Cong Ge, Jun; Wang, Zi Jian; Kim, Min Soo; Choi, Nag Jung

2018-01-01

Volatile organic compounds (VOCs) as an environmental pollution, which have many kinds of chemical structures, and many of them are very toxic. Therefore, controlling and reducing the presence of VOCs has become a hot topic among researchers for many years. In this study, the VOCs adsorption capacity of polyacrylonitrile/fly ash (PAN/FA) nanocomposite electrospun nanofibrous membranes were investigated. The results indicated that the PAN with different contents of FA powder (20%, 40%, 60%, 80%, and 100% compared with PAN by weight) could be spun well by electrospinning. The diameter of the fiber was very fine and its arrangement was irregular. The PAN nanofibrous membrane containing 60 wt% FA powder had the highest VOCs absorption capacity compared with other nanofibrous membranes due to its large specific surface area.

Using stable isotope analysis to discriminate gasoline on the basis of its origin.

Science.gov (United States)

Heo, Su-Young; Shin, Woo-Jin; Lee, Sin-Woo; Bong, Yeon-Sik; Lee, Kwang-Sik

2012-03-15

Leakage of gasoline and diesel from underground tanks has led to a severe environmental problem in many countries. Tracing the production origin of gasoline and diesel is required to enable the development of dispute resolution and appropriate remediation strategies for the oil-contaminated sites. We investigated the bulk and compound-specific isotopic compositions of gasoline produced by four oil companies in South Korea: S-Oil, SK, GS and Hyundai. The relative abundance of several compounds in gasoline was determined by the peak height of the major ion (m/z 44). The δ(13)C(Bulk) and δD(Bulk) values of gasoline produced by S-Oil were significantly different from those of SK, GS and Hyundai. In particular, the compound-specific isotopic value (δ(13)C(CSIA)) of methyl tert-butyl ether (MTBE) in S-Oil gasoline was significantly lower than that of gasoline produced by other oil companies. The abundance of several compounds in gasoline, such as n-pentane, MTBE, n-hexane, toluene, ethylbenzene and o-xylene, differed widely among gasoline from different oil companies. This study shows that gasoline can be forensically discriminated according to the oil company responsible for its manufacture using stable isotope analysis combined with multivariate statistical analysis. Copyright © 2012 John Wiley & Sons, Ltd.

Implementation of VOC source reduction practices in a manufactured house and in school classrooms

International Nuclear Information System (INIS)

Hodgson, A.T.; Apte, M.G.; Shendell, D.G.; Beal, D.; McIlvaine, J.E.R.

2002-01-01

Detailed studies of a new manufactured house and four new industrialized relocatable school classrooms were conducted to determine the emission sources of formaldehyde and other VOCs and to identify and implement source reduction practices. Procedures were developed to generate VOC emission factors that allowed reasonably accurate predictions of indoor air VOC concentrations. Based on the identified sources of formaldehyde and other aldehydes, practices were developed to reduce the concentrations of these compounds in new house construction. An alternate ceiling panel reduced formaldehyde concentrations in the classrooms. Overall, the classrooms had relatively low VOC concentrations

Photocatalysts: ambient temperature destruction of VOCs

Energy Technology Data Exchange (ETDEWEB)

Miller, R [IT Corp., Oak Ridge, TN (United States)

1994-12-31

Photocatalysis was a failure as a solar energy driven organic synthesis technique, but as this study indicates, it has undergone a renaissance as a promising treatment method for volatile organic compounds (VOCs) in air streams. Photocatalytic oxidation (PCO) relies upon the ability of certain semiconductors to be stimulated by UV radiation. UV light excites valence band electrons in the semiconductor catalyst to jump to a conductance band leaving holes in the valence band. The electrons and holes can react with compounds such as organic contaminants present in an air stream. Hallmarks of the technology include rapid destruction kinetics for many VOCs at ambient temperature and efficient use energy in the form of UV-A photons. Studies clearly indicate that PCO is competitive on capital cost and offers significant operating cost savings on selected applications. 6 refs., 3 tabs., 2 figs.

Photocatalysts: ambient temperature destruction of VOCs

International Nuclear Information System (INIS)

Miller, R.

1994-01-01

Photocatalysis was a failure as a solar energy driven organic synthesis technique, but as this study indicates, it has undergone a renaissance as a promising treatment method for volatile organic compounds (VOCs) in air streams. Photocatalytic oxidation (PCO) relies upon the ability of certain semiconductors to be stimulated by UV radiation. UV light excites valence band electrons in the semiconductor catalyst to jump to a conductance band leaving holes in the valence band. The electrons and holes can react with compounds such as organic contaminants present in an air stream. Hallmarks of the technology include rapid destruction kinetics for many VOCs at ambient temperature and efficient use energy in the form of UV-A photons. Studies clearly indicate that PCO is competitive on capital cost and offers significant operating cost savings on selected applications. 6 refs., 3 tabs., 2 figs

Comparison Pore Aggregate Levels After Extraction With Solvents Pertamax Plus And Gasoline

Science.gov (United States)

Anggraini, Muthia

2017-12-01

Loss of asphalt content extraction results become problems in Field Work For implementing parties. The use of solvents with high octane (pertamax plus) for the extraction, dissolving the asphalt more than gasoline. By comparing the levels of aggregate pores after using solvent extraction pertamax plus compared to gasoline could answer that pertamax plus more solvent dissolves the bitumen compared to gasoline. This study aims to obtain comparative levels of porous aggregate mix AC-WC after using solvent extraction pertamax plus compared to gasoline. This study uses the aggregate that has been extracted from the production of asphalt mixtures, when finisher and after compaction field. The method used is the assay of coarse and fine aggregate pores, extraction of bitumen content to separate the aggregate with bitumen. Results of testing the total absorption after extraction using a solvent preta max plus in the production of asphalt mixtures 0.80%, while gasoline solvent 0.67% deviation occurs 0.13%. In the finisher after the solvent extraction preta max plus 0.77%, while 0.67% gasoline solvent occurs deviation of 0.1%. At the core after extraction and solvent pertamax plus 0.71%, while gasoline solvent 0.60% 0.11% deviation occurs. The total water absorption after extraction using a solvent pertamax plus greater than gasoline. This proves that the solvent dissolves pertamax plus more asphalt than gasoline.

Theoretical study of simultaneous water and VOCs adsorption and desorption in a silica gel rotor

DEFF Research Database (Denmark)

Zhang, G.; Zhang, Y.F.; Fang, Lei

2008-01-01

One-dimensional partial differential equations were used to model the simultaneous water and VOC (Volatile Organic Compound) adsorption and desorption in a silica gel rotor which was recommended for indoor air cleaning. The interaction among VOCs and moisture in the adsorption and desorption...... process was neglected in the model as the concentrations of VOC pollutants in typical indoor environment were much lower than that of moisture and the adsorbed VOCs occupied only a minor portion of adsorption capacity of the rotor. Consequently VOC transfer was coupled with heat and moisture transfer only...... by the temperatures of the rotor and the air stream. The VOC transfer equations were solved by discretizing them into explicit up-wind finite differential equations. The model was validated with experimental data. The calculated results suggested that the regeneration time designed for dehumidification may...

40 CFR 52.255 - Gasoline transfer vapor control.

Science.gov (United States)

2010-07-01

... 40 Protection of Environment 3 2010-07-01 2010-07-01 false Gasoline transfer vapor control. 52.255... (CONTINUED) APPROVAL AND PROMULGATION OF IMPLEMENTATION PLANS California § 52.255 Gasoline transfer vapor control. (a) “Gasoline” means any petroleum distillate having a Reid vapor pressure of 4 pounds or greater...

Occurrence of Indoor VOCs in Nursery School - Case Study

Science.gov (United States)

Juhasova Senitkova, Ingrid

2017-10-01

Children’s exposure to air pollutants is an important public health challenge. Particular attention should be paid to preschools because younger children are more vulnerable to air pollution than higher grade children and spend more time indoors. The concentrations of volatile organic compounds (VOCs) as well as carbon dioxide (CO2) concentrations in younger and older children’s classrooms during the winter season were studied. An electronic nose based on gas chromatography was used for the analysis of individual VOCs and a photoionization detector with a UV lamp was used for the determination of total volatile organic compounds (TVOC) concentration. Continuous measurements of CO2 concentrations both inside classrooms and outside each building were performed using automatic portable monitors. Improving ventilation, decreasing the occupancy per room and completing cleaning activities following occupancy periods can contribute to alleviating high CO2 and VOCs occurrence levels.

Genotoxic Effects of Exposure to Gasoline Fumes on Petrol Pump Workers.

Science.gov (United States)

Shaikh, Amrin; Barot, Darshana; Chandel, Divya

2018-04-01

Petrol pump workers are occupationally exposed to gasoline and its fumes consisting of several mutagenic chemicals. To evaluate the genotoxic effects of exposure to gasoline fumes on petrol pump workers. The study groups included 70 petrol pump workers (exposed group) and 70 healthy age-matched individuals with no known exposure (comparison group). Buccal micronucleus cytome assay (BMCyt) was performed to check the genotoxicity caused due to inhalation of gasoline fumes. The frequencies of micronucleated cells, nuclear bud, condensed chromatin cells, karyorrhectic cells, pyknotic cells, and karyolytic cells were significantly higher in the exposed workers compared to the comparison group. Exposure to gasoline fumes is associated with increased frequency of cell abnormalities. This may lead to various health consequences including cancer in those occupationally exposed to gasoline fumes.

Investigation of bifunctional ester additives for methanol-gasoline system

International Nuclear Information System (INIS)

Zhang, J.; Yang, C.; Tang, Y.; Du, Q.; Song, N.; Zhang, Z.

2014-01-01

To explore new and multifunctional additives for methanol-gasoline, tartaric ester were synthesized and screened as phase stabilizer and saturation vapor pressure depressor for methanol-gasoline. The effect of the esters structure on the efficiency was discussed. The results show that the stabilities of the blends depend on the length of the glycolic esters alkoxy group. In addition, the tartaric esters also can depress the saturation vapor pressure of methanol-gasoline effectively in M15. Effect of the structure on the efficiency was also discussed. (author)

Dynamic relationship between the VOC emissions from a Scots pine stem and the tree water relations

Science.gov (United States)

Vanhatalo, Anni; Chan, Tommy; Aalto, Juho; Kolari, Pasi; Rissanen, Kaisa; Hakola, Hannele; Hölttä, Teemu; Bäck, Jaana

2013-04-01

The stems of coniferous trees contain huge storages of oleoresin. The composition of oleoresin depends on e.g. tree species, age, provenance, health status, and environmental conditions. Oleoresin is under pressure in the extensive network of resin ducts in wood and needles. It flows out from a mechanically damaged site to protect the tree by sealing the wounded site. Once in contact with air, volatile parts of oleoresin evaporate, and the residual compounds harden to make a solid protective seal over damaged tissues. The hardening time of the resin depends on evaporation rate of the volatiles which in turn depends on temperature. The storage is also toxic to herbivores and attracts predators that restrict the herbivore damage. Despite abundant knowledge on emissions of volatile isoprenoids from foliage, very little is known about their emissions from woody plant parts. We set up an experiment to measure emissions of isoprene and monoterpenes as well as two oxygenated VOCs, methanol and acetone, from a Scots pine (Pinus sylvestris) stem and branches. The measurements were started in early April and continued until mid-June, 2012. Simultaneously, we measured the dynamics of whole stem and xylem diameter changes, stem sap flow rate and foliage transpiration rate. These measurements were used to estimate A) pressure changes inside the living stem tissue and the water conducting xylem, B) the refilling of stem water stores after winter dehydration (the ratio of sap flow at the stem base to water loss by foliage), and C) the increase in tree water transport capacity (the ratio of maximum daily sap flow rate to the diurnal variation in xylem pressure) during spring due to winter embolism refilling and/or the temperature dependent root water uptake capacity. The results show that already very early in spring, significant VOC emissions from pine stem can be detected, and that they exhibit a diurnal cycle similar to that of ambient temperature. During the highest emission

Extended Research on Detection of Deception Using Volatile Organic Compound (VOC) Emissions

Energy Technology Data Exchange (ETDEWEB)

Center for Human Reliability Studies

2006-06-01

A system that captures and analyzes volatile organic compound (VOC) emissions from skin surfaces may offer a viable alternative method to the polygraph instrument currently in use for detecting deception in U.S. government settings. Like the involuntary autonomic central nervous system response data gathered during polygraph testing, VOC emissions from the skin may provide data that can be used to detect stress caused by deception. Detecting VOCs, then, may present a noninvasive, non-intrusive method for observing, recording, and quantifying evidence of stress or emotional change.

Gasoline Biodesulfurization DE-FC07-97ID13570 FINAL REPORT; FINAL

International Nuclear Information System (INIS)

Pienkos, Philip T.

2002-01-01

Nine strains were identified to grow with gasoline as sole sulfur source. Two different genes were cloned from Gordonia terrae KGB1 and tested for the ability to support gasoline BDS. The first of these, fmoA, was cloned by screening a KGB1 gene library for the ability to convert indole to indigo (a sulfur-regulated capability in KGB1). The fmoA gene was overexpressed in a gasoline tolerant strain of Pseudomonas putida PpG1 and the recombinant strain was shown to convert thiophene to a dimer of thiophene sulfoxide at rates nearly two orders of magnitude higher than KGB1 could catalyze the reaction. Despite this high activity the recombinant PpG1 was unable to demonstrate any activity against gasoline either in shake flask or in bench-scale gasoline BDS bioreactor. A second gene (toeA) was cloned from KGB1 and shown to support growth of Rhodococcus erythropolis JB55 on gasoline. The toeA gene was also identified in another gasoline strain T. wratislaviensis EMT4, and was identified as a homolog of dszA from R. erythropolis IGTS8. Expression of this gene in JB55 supported conversion of DBTO2 (the natural substrate for DszA) to HPBS, but activity against gasoline was low and BDS results were inconsistent. It appeared that activity was directed against C2- and C3-thiophenes. Efforts to increase gene expression by plasmid manipulation, by addition of flavin reductase genes, or by expression in PpG1 were unsuccessful. The DszC protein (DBT monooxygenase) from IGTS8 has very little activity against the sulfur compounds in gasoline, but a mutant enzyme with a substitution of phenylalanine for valine at position 261 was shown to have an altered substrate range. This alteration resulted in increased activity against gasoline, with activity towards mainly C3- and C4-thiophenes and benzothiophene. A mutant library of dszB was constructed by RACHITT (W. C. Coco et al., DNA shuffling method for generating highly recombined genes and evolved enzymes. 2001. Nature Biotech. 19

Phasing out lead from gasoline in Pakistan: a benefit cost analysis

International Nuclear Information System (INIS)

Martin, R.P.; Zaman, Q.U.

1999-01-01

Medical research has established a clear link between elevated blood lead levels nd adverse health effects in humans including the retardation of neurological development, hypertension, and cardiovascular ailments. Due to this, a large number of countries now restrict the sale of leaded gasoline. In contrast, only highly leaded gasoline is readily available in Pakistan, resulting in serious health concerns in certain areas. This paper presents the findings of a study to evaluate consumers' perceived benefits and actual costs of switching to unleaded gasoline in Pakistan. Policy implications are noted. The study indicates a concentration of adverse health effects in the major urban centers. Of special interest is the loss of approximately 2,5000 IQ points annually in Karachi and Lahore as a result of gasoline linked lead exposure. Consumers' willingness to pay for the removal of lead from gasoline, as estimated using a contingent valuation technique, is shown to be positively related to both educational attainment and income. Once consumers are informed of the adverse health effects associated with lead exposure, their willingness to pay for a switch to unleaded gasoline for exceeds the costs incurred. This suggests that significant gains in social welfare may be obtained by phasing out lead from gasoline in Pakistan. The benefits are most pronounced in urban areas, while in rural villages and small cities the costs are likely to out weight the benefits. A flexible program to restrict the sale of leaded gasoline in urban areas is thus recommended. (author)

Residential proximity to gasoline service stations and preterm birth.

Science.gov (United States)

Huppé, Vicky; Kestens, Yan; Auger, Nathalie; Daniel, Mark; Smargiassi, Audrey

2013-10-01

Preterm birth (PTB) is a growing public health problem potentially associated with ambient air pollution. Gasoline service stations can emit atmospheric pollutants, including volatile organic compounds potentially implicated in PTB. The objective of this study was to evaluate the relationship between residential proximity to gasoline service stations and PTB. Singleton live births on the Island of Montreal from 1994 to 2006 were obtained (n=267,478). Gasoline service station locations, presence of heavy-traffic roads, and neighborhood socioeconomic status (SES) were determined using a geographic information system. Multivariable logistic regression was used to analyze the association between PTB and residential proximity to gasoline service stations (50, 100, 150, 200, 250, and 500 m), accounting for maternal covariates, neighborhood SES, and heavy-traffic roads. For all distance categories beyond 50 m, presence of service stations was associated with a greater odds of PTB. Associations were robust to adjustment for maternal covariates for distance categories of 150 and 200 m but were nullified when adjusting for neighborhood SES. In analyses accounting for the number of service stations, the likelihood of PTB within 250 m was statistically significant in unadjusted models. Associations were, however, nullified in models accounting for maternal covariates or neighborhood SES. Our results suggest that there is no clear association between residential proximity to gasoline service stations in Montreal and PTB. Given the correlation between proximity of gasoline service stations and SES, it is difficult to delineate the role of these factors in PTB.

Gasoline on hands: preliminary study on collection and persistence.

Science.gov (United States)

Darrer, Melinda; Jacquemet-Papilloud, Joëlle; Delémont, Olivier

2008-03-05

The identification of an arsonist remains one of the most difficult challenges a fire investigation has to face. Seeking and detection of traces of gasoline could provide a valuable information to link a suspect with an arson scene where gasoline was used to set-up the fire. In this perspective, a first study was undertaken to evaluate a simple, fast and efficient method for collecting gasoline from hands, and to assess its persistence over time. Four collection means were tested: PVC, PE and Latex gloves, as well as humidified filter paper. A statistical assessment of the results indicates that Latex and PVC gloves worn for about 20 min, as well as paper filter rubbed on hands, allow an efficient collection of gasoline applied to hands. Due to ease of manipulation and to a reduced amount of volatile compounds detected from the matrix, PVC gloves were selected for the second set of experiments. The evaluation of the persistence of gasoline on hands was then carried out using two initial quantities (500 and 1000 microl). Collection was made with PVC gloves after 0, 30 min, 1, 2 and 4h, on different volunteers. The results show a common tendency of massive evaporation of gasoline during the first 30 min: a continued but non-linear decrease was observed along different time intervals. The results of this preliminary study are in agreement with other previous researches conducted on the detection of flammable liquid residues on clothes, shoes and skin.

Impact of intentionally introduced sources on indoor VOC levels

Energy Technology Data Exchange (ETDEWEB)

Davis, C.S. [BOVAR Environmental, Downsview, Ontario (Canada); Otson, R. [Health Canada, Ottawa, Ontario (Canada). Environmental Health Centre

1997-12-31

The concentrations of 33 target volatile organic compounds (VOC) were measured in outdoor air and in indoor air before and after the introduction of dry-cleaned clothes, and consumer products into two suburban homes. Emissions from the household products (air fresheners, furniture polishes, mothballs, and dry-cleaned clothes), showering, and two paints were analyzed to obtain source profiles. There were measurable increases in the 24 h average concentrations for 10 compounds in one house and 8 compounds in the second house after introduction of the sources. A contribution by showering to indoor VOC was not evident although the impact of the other sources and outdoor air could be discerned, based on results for the major constituents of source emissions. Also, contributions by paints, applied three to six weeks prior to the monitoring, to indoor VOC concentrations were evident. The pattern of concentrations indicated that sink effects need to be considered in explaining the indoor concentrations that result when sources are introduced into homes. Quantitative estimates of the relative contributions of the sources to indoor VOC levels were not feasible through the use of chemical mass balance since the number of tracer species detected (up to 6) and that could be used for source apportionment was similar to the number of sources to be apportioned (up to 7).

78 FR 20102 - Proposed Information Collection Request; Comment Request; Reformulated Gasoline Commingling...

Science.gov (United States)

2013-04-03

... Request; Comment Request; Reformulated Gasoline Commingling Provisions AGENCY: Environmental Protection... information collection request (ICR), ``Reformulated Gasoline Commingling Provisions'' (EPA ICR No.2228.04.... Abstract: EPA would like to continue collecting notifications from gasoline retailers and wholesale...

Glutathione S-Transferase Gene Polymorphisms: Modulator of Genetic Damage in Gasoline Pump Workers.

Science.gov (United States)

Priya, Kanu; Yadav, Anita; Kumar, Neeraj; Gulati, Sachin; Aggarwal, Neeraj; Gupta, Ranjan

2015-01-01

This study investigated genetic damage in gasoline pump workers using the cytokinesis blocked micronucleus (CBMN) assay. Blood and urine samples were collected from 50 gasoline pump workers and 50 control participants matched with respect to age and other confounding factors except for exposure to benzene through gasoline vapors. To determine the benzene exposure, phenol was analyzed in urinary samples of exposed and control participants. Urinary mean phenol level was found to be significantly high (P gasoline pump workers (6.70 ± 1.78) when compared to control individuals (2.20 ± 0.63; P gasoline vapors can increase genotoxic risk in gasoline pump workers. © The Author(s) 2015.

Hydrodeoxygenation of oxidized distilled bio-oil for the production of gasoline fuel type

International Nuclear Information System (INIS)

Luo, Yan; Guda, Vamshi Krishna; Hassan, El Barbary; Steele, Philip H.; Mitchell, Brian; Yu, Fei

2016-01-01

Highlights: • Oxidation had more influence on the yield of total hydrocarbons than distillation. • The highest total hydrocarbon yield was obtained from oxidized distilled bio-oil. • The 2nd-stage hydrocarbons were in the range of gasoline fuel boiling points. • The main products for upgrading of oxidized bio-oil were aliphatic hydrocarbons. • The main products for upgrading of non-oxidized bio-oil were aromatic hydrocarbons. - Abstract: Distilled and oxidized distilled bio-oils were subjected to 1st-stage mild hydrodeoxygenation and 2nd-stage full hydrodeoxygenation using nickel/silica–alumina catalyst as a means to enhance hydrocarbon yield. Raw bio-oil was treated for hydrodeoxygenation as a control to which to compare study treatments. Following two-stage hydrodeoxygenation, four types of hydrocarbons were mainly comprised of gasoline and had water contents, oxygen contents and total acid numbers of nearly zero and higher heating values of 44–45 MJ/kg. Total hydrocarbon yields for raw bio-oil, oxidized raw bio-oil, distilled bio-oil and oxidized distilled bio-oil were 11.6, 16.2, 12.9 and 20.5 wt.%, respectively. The results indicated that oxidation had the most influence on increasing the yield of gasoline fuel type followed by distillation. Gas chromatography/mass spectrometry characterization showed that 66.0–76.6% of aliphatic hydrocarbons and 19.5–31.6% of aromatic hydrocarbons were the main products for oxidized bio-oils while 35.5–38.7% of aliphatic hydrocarbons and 58.2–63.1% of aromatic hydrocarbons were the main products for non-oxidized bio-oils. Both aliphatic and aromatic hydrocarbons are important components for liquid transportation fuels and chemical products.

Gasoline-related injuries and fatalities in the United States, 1995-2014.