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Sample records for verre r7t7 etude

  1. Experimental investigation of the effects of aqueous species on the dissolution kinetics of R7T7 glass; Etude experimentale de l`influence d`especes aqueuses sur la cinetique de dissolution du verre nucleaire R7T7

    Energy Technology Data Exchange (ETDEWEB)

    Gin, S

    1994-10-01

    This contribution to the study of aqueous corrosion of the French ``R7T7`` reference nuclear containment glass includes a bibliographic survey of prior investigations, highlighting the problems encountered in interpreting the interactions in systems containing clay materials in contact with the glass. An experimental methodology is proposed to investigate the effects of inorganic aqueous species separately from those of a few organic acids on the dissolution mechanisms and kinetics of R7T7 glass at 90 deg. C. The experimental results discussed support the idea that several glass network forming elements may have a kinetically limiting role. The most likely hypothesis to account for the absence of saturation conditions with respect to the glass in certain clay media involves the formation of complexes with kinetically limiting metallic elements such as aluminum released by glass corrosion. This work contributes to a better understanding of the basic mechanisms of nuclear glass dissolution in a geological repository environment. It facilitates the interpretation of glass alteration studies in realistic or actual solutions and may contribute to specifying near field chemical barriers in the form of additives (amorphous silica, aluminum hydroxides or phosphates) around the glass disposal package to enhance the stability of the glass matrix. (author). 148 refs., 40 figs., 32 tabs., 1 append.

  2. R7T7 glass alteration mechanism in an aqueous closed system: understanding and modelling the long term alteration kinetic; Etude des mecanismes d'alteration par l'eau du verre R7T7 en milieu confine: comprehension et modelisation de la cinetique residuelle

    Energy Technology Data Exchange (ETDEWEB)

    Chave, T

    2007-10-15

    The long term alteration rate of the French R7T7 nuclear glass has been investigated since many years because it will define the overall resistance of the radionuclide containment matrix. Recent studies have shown that the final rate remains constant or is slightly decreasing with time. It never reaches zero. Though this residual rate is very low, only 5 nm per year at 50 C, it would be the dominant alteration phenomenon in a geological repository. Two mechanisms are suggested for explaining such behaviour: diffusion in solution of elements from glass through an amorphous altered layer and precipitation of neo-formed phases. The diffusion processes are in agreement with a solid state diffusion mechanism and can lead to secondary phase precipitation due to solution concentration increases. Observed phases are mainly phyllosilicates and zeolites, in specific conditions. Phyllosilicates are expected to maintain the residual kinetic rate whereas alteration resumption could be observed in presence of zeolites at very high pH or temperature (10.5 at 90 C or temperature above 150 C). Both diffusion and neo-formed phase precipitation have been investigated in order to better understand their impact on the residual alteration rate and have then been modelled by a calculation code, coupling chemistry and transport, in order to be able to better anticipate the long term behaviour of the glass R7T7 in an aqueous closed system. (author)

  3. Alteration of R7T7-type nuclear glass in deep geological storage conditions; Alteration du verre de confinement de dechets type R7T7 en condition de stockage geologique

    Energy Technology Data Exchange (ETDEWEB)

    Combarieu, G de

    2007-02-15

    This PhD thesis is aimed to study the alteration of SON68 glass, French inactive glass of R7T7-type, in contact with near field materials of a deep geological storage (French concept from ANDRA) which are mainly metallic iron and Callovo-Oxfordian clay. Therefore, experiments involving a 'glass-iron-clay' system at lab-scale have been carried out. Interactions between glass, iron and clay have been characterised from submicron to millimeter scale by means of SEM, TEM, XRD and XAS and Raman spectroscopies in terms of chemistry and crystal-chemistry. In the mean time, a conceptual model of glass alteration has been developed to account for most of the experimental observations and known mechanisms of alteration. The model has been then transposed within the transport-chemistry code HYTEC, together with developed models of clay and iron corrosion, to simulate the experiments described above. This work is thus a contribution to the understanding of iron corrosion in Callovo-Oxfordian clay and subsequent glass alteration in the newly formed corrosion products, the whole process being considered as a lab-scale model of a deep geological storage of radioactive wastes. (author)

  4. Alteration of R7T7-type nuclear glass in deep geological storage conditions; Alteration du verre de confinement de dechets type R7T7 en condition de stockage geologique

    Energy Technology Data Exchange (ETDEWEB)

    Combarieu, G. de

    2007-02-15

    This PhD thesis is aimed to study the alteration of SON68 glass, French inactive glass of R7T7-type, in contact with near field materials of a deep geological storage (French concept from ANDRA) which are mainly metallic iron and Callovo-Oxfordian clay. Therefore, experiments involving a 'glass-iron-clay' system at lab-scale have been carried out. Interactions between glass, iron and clay have been characterised from submicron to millimeter scale by means of SEM, TEM, XRD and XAS and Raman spectroscopies in terms of chemistry and crystal-chemistry. In the mean time, a conceptual model of glass alteration has been developed to account for most of the experimental observations and known mechanisms of alteration. The model has been then transposed within the transport-chemistry code HYTEC, together with developed models of clay and iron corrosion, to simulate the experiments described above. This work is thus a contribution to the understanding of iron corrosion in Callovo-Oxfordian clay and subsequent glass alteration in the newly formed corrosion products, the whole process being considered as a lab-scale model of a deep geological storage of radioactive wastes. (author)

  5. Partitioning of the rare earths and actinides between R7T7 nuclear glass alteration products and solution according to disposal conditions; Partage des terres rares et des actinides entre solution et produits d`alteration du verre nucleaire type R7T7 en fonction des conditions de stockage

    Energy Technology Data Exchange (ETDEWEB)

    Menard, O

    1995-10-25

    The alteration of nuclear glass by water is liable to release radionuclides into the environment. Determining the release kinetics of these elements and their aqueous chemical forms are therefore essential steps in establishing the safety of a geological repository site. Leach tests were conducted with a nonradioactive specimen of the French ``R7T7`` light water containment glass spiked with U and Th, and with two R7T7 specimens spiked with {sup 237}Np and {sup 239}Pu, respectively. The alteration solution compositions were representative of deep groundwater and contained carbonate, sulfate, phosphate, fluorine and chlorine ions. The release of U, Th, Np and Pu, as well as of the rare earths La, Ce and Nd were monitored by ICP mass spectrometry and by {alpha} spectrometry. Scanning and transmission electron microscopic examination of the nonradioactive altered glass surfaces was also performed to assess the partitioning balance for the rare earths, U and Th between the glass alteration products and solution. The mobility of these elements depends on two competing mechanisms. The rare earths and thorium are incorporated in the alteration products (gel); the retention process is assumed to involve chemisorption or coprecipitation, enhanced in the gel layer by the presence of phosphate ions in particular. Conversely, the aqueous species in the alteration solutions (mainly anions) form complexes with the actinides and rare earths; this phenomenon is particularly evident with U and Np. The presence of carbonate ions favors this mobility. Plutonium differs from U and Np in that it is adsorbed mainly on colloids formed by glass dissolution, the principal factors governing its chemical evolution in solution. (author). refs., 122 figs., 185 tabs.

  6. Alteration of 'R7T7' type nuclear glasses: statistical approach, experimental validation, local evolution model; Alteration des verres nucleaires de type 'R7T7': demarche statistique, validation experimentale, modele local d'evolution

    Energy Technology Data Exchange (ETDEWEB)

    Thierry, F

    2003-02-01

    The aim of this work is to propose an evolution of nuclear (R7T7-type) glass alteration modeling. The first part of this thesis is about development and validation of the 'r(t)' model. This model which predicts the decrease of alteration rates in confined conditions is based upon a coupling between a first-order dissolution law and a diffusion barrier effect of the alteration gel layer. The values and the uncertainties regarding the main adjustable parameters of the model ({alpha}, Dg and C*) have been determined from a systematic study of the available experimental data. A program called INVERSION has been written for this purpose. This work lead to characterize the validity domain of the 'r(t)' model and to parametrize it. Validation experiments have been undertaken, confirming the validity of the parametrization over 200 days. A new model is proposed in the second part of this thesis. It is based on an inhibition of glass dissolution reaction by silicon coupled with a local description of silicon retention in the alteration gel layer. This model predicts the evolutions of boron and silicon concentrations in solution as well as the concentrations and retention profiles in the gel layer. These predictions have been compared to measurements of retention profiles by the secondary ion mass spectrometry (SIMS) method. The model has been validated on fractions of gel layer which reactivity present low or moderate disparities. (author)

  7. The understanding of the R7T7 glass blocks long term behavior: chemical and transport coupling in fractured media; Comprehension de l'alteration a long terme des colis de verre R7T7: etude du couplage chimie transport dans un milieu fissure

    Energy Technology Data Exchange (ETDEWEB)

    Chomat, L

    2008-04-15

    The long term behavior of nuclear waste glass blocks depends highly on chemical reactions which occur at the surface in contact with water. Studies carried out on inactive fractured glass blocks show that fracture networks play a significant part in reactive surface area. Nevertheless, the complexity of results interpretation, due to a weak knowledge of fracture networks and local lixiviation conditions, does not allow us to comprehend the physical and chemical mechanisms involved. Model cracks are a key step to study chemical and transport coupling in fractured media. Crack lixiviation in aggressive conditions (pH{>=}11) show that the crack's position (horizontal or vertical) determines the dominant transport mechanism (respectively diffusion or convection induced by gravity). This gravity driven flow seems to be negligible in lower pH conditions. The convective velocity is estimated by a 1D model of reactive transport. Two other parameters are studied: the influence of thermal gradient and the influence of interconnected cracks on alteration. A strong retroactive effect of convection, due to thermal gradient, on the alteration kinetic is observed inside the crack. These works lead to a complete alteration experiment of a 163 crack network subject to a thermal gradient. The use of the geochemical software, HYTEC, within the framework of this study shows the potential of the software which is however limited by the kinetics law used. (author)

  8. The understanding of the R7T7 glass blocks long term behavior: chemical and transport coupling in fractured media; Comprehension de l'alteration a long terme des colis de verre R7T7: etude du couplage chimie transport dans un milieu fissure

    Energy Technology Data Exchange (ETDEWEB)

    Chomat, L

    2008-04-15

    The long term behavior of nuclear waste glass blocks depends highly on chemical reactions which occur at the surface in contact with water. Studies carried out on inactive fractured glass blocks show that fracture networks play a significant part in reactive surface area. Nevertheless, the complexity of results interpretation, due to a weak knowledge of fracture networks and local lixiviation conditions, does not allow us to comprehend the physical and chemical mechanisms involved. Model cracks are a key step to study chemical and transport coupling in fractured media. Crack lixiviation in aggressive conditions (pH{>=}11) show that the crack's position (horizontal or vertical) determines the dominant transport mechanism (respectively diffusion or convection induced by gravity). This gravity driven flow seems to be negligible in lower pH conditions. The convective velocity is estimated by a 1D model of reactive transport. Two other parameters are studied: the influence of thermal gradient and the influence of interconnected cracks on alteration. A strong retroactive effect of convection, due to thermal gradient, on the alteration kinetic is observed inside the crack. These works lead to a complete alteration experiment of a 163 crack network subject to a thermal gradient. The use of the geochemical software, HYTEC, within the framework of this study shows the potential of the software which is however limited by the kinetics law used. (author)

  9. Catalyze and chemical inhibition of the R7T7 glass kinetics

    International Nuclear Information System (INIS)

    Gin, St.; Advocat, Th.

    1997-01-01

    This article highlights some phenomena likely to modify the glass alteration kinetics and/or the nature of the alteration products according to the chemical composition of the leaching water. It discusses experimental results showing that in neutral and basic media, the presence of inorganic anions or organic acid (simple carboxylic acid and humic acid) has relatively little effect on the long-term glass matrix alterability Actinide mobility appears to be more dependent on the concentration of complexing agents in the leaching solution. The behavior of phosphate ions, which may inhibit or catalyze the R7T7 glass alteration kinetics depending on the experimental conditions, is discussed; the gel microstructure can be related to the glass alteration kinetics by detailed examination of the alteration products. (authors)

  10. R7T7 glass alteration in the presence of mortar: effect of the cement grade

    International Nuclear Information System (INIS)

    Andriambololona, Z.; Godon, N.; Vernaz, E.

    1991-01-01

    R7T7 glass alteration was investigated in the presence of four mortars prepared from four different cement grades: 'CPA' Portland cement (mortar M1), CPA with pozzolana additive (M2), CPA with amorphous silica additive (M3) and 'CLK' blast furnace slag cement (M4). Glass specimens were also altered in Volvic mineral water and in a cement effluent. Glass corrosion in the cement media was greater than in Volvic water, but well below what could be expected from the high pH (approx 12.5). The relatively low alteration was probably related to the protective action of the calcium-enriched gel layer that formed at the glass surface. The glass corrosion rate was 2 to 3 times lower with cement containing pozzolana or silica gel additives or with CLK cement than with CPA cement alone. 8 refs., 8 figs

  11. Alteration of R7T7-type nuclear glass in deep geological storage conditions

    International Nuclear Information System (INIS)

    Combarieu, G. de

    2007-02-01

    This PhD thesis is aimed to study the alteration of SON68 glass, French inactive glass of R7T7-type, in contact with near field materials of a deep geological storage (French concept from ANDRA) which are mainly metallic iron and Callovo-Oxfordian clay. Therefore, experiments involving a 'glass-iron-clay' system at lab-scale have been carried out. Interactions between glass, iron and clay have been characterised from submicron to millimeter scale by means of SEM, TEM, XRD and XAS and Raman spectroscopies in terms of chemistry and crystal-chemistry. In the mean time, a conceptual model of glass alteration has been developed to account for most of the experimental observations and known mechanisms of alteration. The model has been then transposed within the transport-chemistry code HYTEC, together with developed models of clay and iron corrosion, to simulate the experiments described above. This work is thus a contribution to the understanding of iron corrosion in Callovo-Oxfordian clay and subsequent glass alteration in the newly formed corrosion products, the whole process being considered as a lab-scale model of a deep geological storage of radioactive wastes. (author)

  12. Physicochemical properties and long-term behavior of french R7T7 nuclear waste glass

    International Nuclear Information System (INIS)

    Vernaz, E.

    1990-01-01

    The French R7T7 nuclear glass composition was carefully selected to allow incorporation of some thirty different oxides found in fission product solutions. The resulting glass exhibits very low crystallization, and its physical and chemical properties are very similar to those of standard industrial glasses. Nuclear glasses have been shown to withstand α doses corresponding to several hundred thousand years under repository conditions. Predicting the long-term behavior of fission product glasses subjected to aqueous corrosion is no doubt the most difficult aspect of the problem. Predictions are necessarily based on mathematical models. A substantial research effort has been undertaken to identify all the basic corrosion mechanisms liable to control long-term alteration. These mechanisms are now relatively well understood, and provide the basis for developing the indispensable models. Realistic storage conditions exist under which glass alteration occurs at a very slow rate, and can fulfill its role as the first containment barrier for several tens of thousands of years

  13. Alteration of 'R7T7' type nuclear glasses: statistical approach, experimental validation, local evolution model

    International Nuclear Information System (INIS)

    Thierry, F.

    2003-02-01

    The aim of this work is to propose an evolution of nuclear (R7T7-type) glass alteration modeling. The first part of this thesis is about development and validation of the 'r(t)' model. This model which predicts the decrease of alteration rates in confined conditions is based upon a coupling between a first-order dissolution law and a diffusion barrier effect of the alteration gel layer. The values and the uncertainties regarding the main adjustable parameters of the model (α, Dg and C*) have been determined from a systematic study of the available experimental data. A program called INVERSION has been written for this purpose. This work lead to characterize the validity domain of the 'r(t)' model and to parametrize it. Validation experiments have been undertaken, confirming the validity of the parametrization over 200 days. A new model is proposed in the second part of this thesis. It is based on an inhibition of glass dissolution reaction by silicon coupled with a local description of silicon retention in the alteration gel layer. This model predicts the evolutions of boron and silicon concentrations in solution as well as the concentrations and retention profiles in the gel layer. These predictions have been compared to measurements of retention profiles by the secondary ion mass spectrometry (SIMS) method. The model has been validated on fractions of gel layer which reactivity present low or moderate disparities. (author)

  14. Aqueous corrosion of silicate glasses. Analogy between volcanic glasses and the French nuclear waste glass R7T7

    International Nuclear Information System (INIS)

    Goldschmidt, F.

    1991-01-01

    The behaviour of borosilicate glasses upon aqueous corrosion is controlled for long periods of time (>10,000 years) by processes which are not directly accessible by means of laboratory experiments. The analogical approach consists here to compare leaching performances between the french nuclear waste glass R7T7 and natural volcanic glasses, basaltic and rhyolitic ones. The three glasses were leached in the same conditions; open system, 90 deg C, initial pH of 9.7. Basaltic and R7T7 glasses having the same kinetic of dissolution, the basaltic glass was chosen as the best analogue. (author). refs., figs., tabs

  15. R7T7-type HLW glass alteration under irradiation. Study of the residual alteration rate regime

    International Nuclear Information System (INIS)

    Rolland, Severine

    2012-01-01

    In France, fission products and minor actinides remaining after reprocessing of spent nuclear fuel are confined in a borosilicate glass matrix, named R7T7, for disposal in a geological repository. However, in these conditions, after several thousand years, water could arrive in contact with glass and be radio-lysed. In this work, we investigated the irradiation influence and especially the influence of the energy deposition on the residual glass alteration rate regime in pure water. Two types of leaching tests have been carried out. The first were performed on radioactive glass and the second on a SON68 glass (nonradioactive surrogate of R7T7 glass) under external irradiation γ. (author) [fr

  16. Aqueous corrosion mechanisms of the nuclear glass R7T7. Experimental approach. Kinetics and thermodynamic simulation

    International Nuclear Information System (INIS)

    Advocat, T.

    1991-01-01

    An inactive borosilicate glass made of about 30 oxides is studied. The composition was developed by the CEA for encapsulation of calcinated fission product solutions from reprocessing. Hydration energy of glass is first calculated for 8 glasses and results are compared to experimental data. Dissolution of R7T7 glass is examined at 90 0 C in a large range of pH and S/V ratios (glass surface/solution volume). In dilute media (S/V = 0.1 cm -1 ) dissolution is selective at acid pH and stoichiometric at basic pH. In alkaline media dissolution rate increases with pH. Corrosion products, generally amorphous or badly crystallized are observed on glass surface. For high S/V ratios (4, 20, 80 and 200 cm -1 ) the very low dissolution rate is explained by saturation. Orthosilic acid controls corrosion kinetics. A kinetic equation is proposed taking into account pH, S/V ratio and dissolved silica concentration. Geochemical consequences of R7T7 dissolution are modelled at 100 0 C and 90 0 C. Affinity of dissolution reaction depends upon many factors (pH, silica concentration, nature and crystallinity of secondary phases. Reaction affinity is not constant for the long-term [fr

  17. R7T7 glass alteration mechanism in an aqueous closed system: understanding and modelling the long term alteration kinetic

    International Nuclear Information System (INIS)

    Chave, T.

    2007-10-01

    The long term alteration rate of the French R7T7 nuclear glass has been investigated since many years because it will define the overall resistance of the radionuclide containment matrix. Recent studies have shown that the final rate remains constant or is slightly decreasing with time. It never reaches zero. Though this residual rate is very low, only 5 nm per year at 50 C, it would be the dominant alteration phenomenon in a geological repository. Two mechanisms are suggested for explaining such behaviour: diffusion in solution of elements from glass through an amorphous altered layer and precipitation of neo-formed phases. The diffusion processes are in agreement with a solid state diffusion mechanism and can lead to secondary phase precipitation due to solution concentration increases. Observed phases are mainly phyllosilicates and zeolites, in specific conditions. Phyllosilicates are expected to maintain the residual kinetic rate whereas alteration resumption could be observed in presence of zeolites at very high pH or temperature (10.5 at 90 C or temperature above 150 C). Both diffusion and neo-formed phase precipitation have been investigated in order to better understand their impact on the residual alteration rate and have then been modelled by a calculation code, coupling chemistry and transport, in order to be able to better anticipate the long term behaviour of the glass R7T7 in an aqueous closed system. (author)

  18. Effects of deposited nuclear and electronic energy on the hardness of R7T7-type containment glass

    Energy Technology Data Exchange (ETDEWEB)

    Peuget, S. [Commissariat a l' Energie Atomique, CEA Marcoule, DEN/DTCD/SECM/LMPA, Batiment 166, BP 17171, F-30207 Bagnols-sur-Ceze Cedex (France)]. E-mail: sylvain.peuget@cea.fr; Noel, P.-Y. [Commissariat a l' Energie Atomique, CEA Marcoule, DEN/DTCD/SECM/LMPA, Batiment 166, BP 17171, F-30207 Bagnols-sur-Ceze Cedex (France); Loubet, J.-L. [Laboratoire de Tribologie et Dynamique des Systemes, UMR CNRS 5513, Ecole Centrale de Lyon 36, avenue Guy de Collongue, 69134 Ecully Cedex (France); Pavan, S. [Laboratoire de Tribologie et Dynamique des Systemes, UMR CNRS 5513, Ecole Centrale de Lyon 36, avenue Guy de Collongue, 69134 Ecully Cedex (France); Nivet, P. [Commissariat a l' Energie Atomique, CEA Marcoule, DEN/DTCD/SECM/LMPA, Batiment 166, BP 17171, F-30207 Bagnols-sur-Ceze Cedex (France); Chenet, A. [Commissariat a l' Energie Atomique, CEA Marcoule, DEN/DTCD/SECM/LMPA, Batiment 166, BP 17171, F-30207 Bagnols-sur-Ceze Cedex (France)

    2006-05-15

    The effects of elastic and inelastic interactions induced by cumulative alpha decay on the hardness of R7T7-type nuclear containment glass were investigated on actinide-doped glass specimens and by external irradiation of inactive glass by light and heavy ions. Vickers microindentation and nanoindentation hardness measurements showed that in the deposited energy range investigated (below 3 x 10{sup 22} keV/cm{sup 3}) inelastic effects have no influence on the plastic response of the glass. Conversely, identical hardness variations versus the nuclear energy deposited in the material were observed on curium-doped glass and on glass irradiated by ion bombardment. The observed hardness variation stabilized after the deposited energy reached about 3 x 10{sup 2} keV{sub nucl}/cm{sup 3}. These findings indicate that the change in the plastic response of the glass is a consequence of ballistic effects.

  19. Experimental alteration of R7T7 glass in salt brines at 90 deg C and 150 deg C

    International Nuclear Information System (INIS)

    Godon, N.; Vernaz, E.; Gin, S.; Beaufort, D.; Thomassin, J.H.

    1991-01-01

    Static experiments have been developed to investigate the R7T7 glass corrosion in four natural salt brines (brines 1 and 3: pure halite, brines 2 and 4: high Mg, K fluid inclusions rich halite), at 90 deg C and 150 deg C with 0.7 cm -1 S/V ratio and at 11 different running times. Analysis of brines after alteration (pHmeter and ICP) added to a detailed study of the crystalline phases developed at the interface glass-brine (XRD,SEM and Microprobe), showed that the influence of the compositional difference is more important on the nature of the secondary phases formed than on the corrosion rate of the glass. After 91 days of alteration at 150 deg C stady states to be reached (after 40 days at 90 deg C). A long term experiment (1 year) is necessary to confirm this hypothesis. 7 refs., 7 figs., 2 tabs

  20. Corrosion mechanisms and behaviour of actinides in the 'R7T7' nuclear glass

    International Nuclear Information System (INIS)

    Fillet, Sylvie

    1987-01-01

    This research thesis reports the study of aqueous corrosion of the R7T7 nuclear glass and of the identified corrosion mechanisms in conditions of static lixiviation which are close to that expected during long term storage in a geological environment. More specifically, this work aims at assessing the durability of this glass which has been selected for the vitrification of solutions from pressurized water reactors. The main glass alteration phenomena have been studied. The first part addresses the study of the alteration of the glassy matrix, and aims at identifying corrosion mechanisms in various lixiviation conditions (high temperature, saturation). The second part addresses the action of different materials present in the environment on the glassy matrix by simulating as well as possible a storage case. Based on the obtained results, a mathematical model is developed to predict the glass behaviour on the long term. Finally, the glass confinement power with respect to actinides is studied [fr

  1. Alteration of French waste glass matrix of R7T7 type in deep geological disposal conditions

    International Nuclear Information System (INIS)

    Combarieu, G. de

    2007-02-01

    The Geological disposal is a possible option for safe and long term management of long lived and highly radioactive wastes. In order to predict the release of radionuclides in the environment, the comprehensive knowledge of glass dissolution rates as well as the properties of near- and far-field in which migration will occur is necessary. This thesis is aimed to describe the alteration of SON68 glass, inactive analog of French R7T7 glass, in contact with disposal materials: metallic iron and Callovo-Oxfordian argilite. Therefore, original experiments have been carried out on a laboratory scaled system involving 'glass-iron-argilite' interactions. The transformations of chemistry and crystal-chemistry are investigated with multi-scale probing tools: SEM, TEM, XRD, XRF, EXAFS and Raman spectroscopies. In the same time, the glass alteration is modeled to obtain a source term in good agreement with the major phenomena observed in common experiments. As an end, geochemical models of iron and argilite transformations are also developed and set together in the transport-chemistry code HYTEC to simulate chemical reactions (iron corrosion, argilite evolution, and glass alteration). Simulations and comparison with experiments have improved the overall knowledge of the glass-iron-clay system. (author)

  2. Geochemical modelling of the long-term dissolution behaviour of the French nuclear glass R7T7

    International Nuclear Information System (INIS)

    Michaux, L.; Mouche, E.; Petit, J.-C.; Fritz, B.

    1992-01-01

    The long-term dissolution behaviour of the French nuclear reference glass R7T7 was studied by means of the geochemical code DISSOL. New experimental data which support some of the assumptions of DISSOL are presented: namely, that the dissolution is congruent and that the altered layer can be considered as an assemblage of secondary phases. At 100 o C the main results of modelling are that the altered layer is essentially formed of a pure siliceous phase (amorphous silica or chalcedony) associated with smectites and zeolites. This sequence of secondary minerals is closely linked to the chemical composition of the glass. For high degrees of reaction, corresponding to high B concentration, the ionic strength reaches 1 and the pH varies from 9 to 10 depending on the CO 2 fugacity; B,Li and Na are essentially found in solution and their concentrations depend on the amount of dissolved glass. By contrast Fe,Al and Zn have low solution concentrations which are controlled by solubility products of secondary minerals. Silicon and Ca have an intermediate behaviour which depends on the choice of selected secondary minerals. The total volume of the secondary phases is always lower than that of the corresponding dissolved glass. The results of modelling compared to static leaching experimental results show only minor differences which can be explained by kinetic control or colloid formation. It is concluded that the altered layer is not a barrier to diffusion. The consequences of this work for actinide solubility are also discussed. (author)

  3. Hydrotalcite formed by alteration of R7T7 nuclear waste glass and basaltic glass in salt brine at 190 degrees C

    International Nuclear Information System (INIS)

    Abdelouas, A.; Crovisier, J.L.; Lutze, W.; Mueller, R.; Bernotat, W.

    1994-01-01

    The R7T7 and synthetic basaltic glasses were submitted to corrosion in a saline MgCl 2 dominated solution at 190 degrees C. For both glasses, the early alteration product is a hydrotalcite-like compound in which HPO 4 2- , SO 4 2- and Cl - substitutes to CO 3 2- . The measured d 003 spacing is 7.68 angstrom for the hydrotalcite formed from R7T7 glass and 7.62 angstrom for the hydrotalcite formed from basaltic glass which reflect the high aluminium content. Chemical microanalyses show that the hydrotalcite is subsequently covered by a silica-rich gel which evolves into saponite after few months

  4. Etude de la propagation sous critique dans les fibres de verre par relaxation de la charge

    OpenAIRE

    R'Mili , M.; Godin , N.; Lamon , J.

    2011-01-01

    International audience; Plusieurs fibres inorganiques de type verre ou céramique (à base de carbure de silicium) sont très sensibles à la propagation sous critique de fissures, activée chimiquement ou thermiquement. Dans ce cas la rupture survient d'une façon prématurée à un niveau de contrainte relativement bas comparé à la contrainte de rupture. Cet article propose une approche statistique de la rupture en fatigue statique fondée sur l'analyse de la rupture des fibres dans une mèche sollici...

  5. Mechanisms and kinetics laws of inactive R7T7 reference glass dissolution in water at 90 deg C: initial dissolution rate measurements

    International Nuclear Information System (INIS)

    Advocat, T.; Ghaleb, D.; Vernaz, E.

    1993-02-01

    The initial dissolution rate of inactive R7T7 reference glass was measured at 90 deg C in dilute aqueous solutions first at unspecified pH, then with imposed pH values. In distilled water, R7T7 glass corrosion initially involved preferential extraction of boron and network modifier elements (Li, Na, Ca) as long as the solution pH remained acid. When the solution pH became alkaline, glass dissolution was stoichiometric. These two mechanisms were confirmed by dissolution tests in aqueous solutions at imposed pH values under acid and alkaline conditions. The initial dissolution rate r 0 in mole.cm -3 .s -1 also increased significantly in alkaline media when the pH of the aqueous phase increased: in slightly acid media, selective glass dissolution formed a residual, de-alkalinized, hydrated glass that was characterized by transmission electron microscopy and secondary ion mass spectrometry. Under steady-state dissolution conditions, the initial glass corrosion rate (in mole.cm -3 .s -1 ) was: in acid and alkaline media, amorphous and crystallized alteration products formed after complete dissolution of the silicated glass network. The first products formed consisted mainly of Zr, Rare Earths, Fe and Al. (author). 67 refs., 29 figs., 26 tabs., 21 plates

  6. R7T7 nuclear waste glass behavior in moist clay: role of the clay mass/glass surface area ratio

    International Nuclear Information System (INIS)

    Godon, N.; Vernaz, E.

    1989-01-01

    R7T7 glass alteration was investigated in the presence of various moist clays. In contact with smectite 4a, selected in France as a potential engineered barrier material, the glass was significantly corroded: after 6 months the glass corrosion rate was practically the same as the initial alteration rate in double-distilled water. Substantially lower alteration was observed in contact with bentonite 6 activated by sodium carbonate. Smectite 4a consumes silicon released by glass corrosion, and thus retards the rise to high silicon concentrations in solution at which the glass corrosion rate diminishes. Glass can therefore in some cases be altered as much in moist clay as in water with high renewal rates. Other experiments with smaller quantities of smectite 4a showed that the phenomenon becomes less important in time: its duration is proportional to the ratio between the clay mass (C) and the glass surface area (SA). Comparing the results of studies at different C/SA ratios indicates that low glass corrosion rates are obtained more slowly at higher C/SA ratios. Tests with 239 Pu-doped R7T7 glass also showed that the radionuclide retention factor in the alteration film at the glass surface is only 6, compared with a factor of nearly 50 in double-distilled water

  7. Hydrothermal alteration of the glass R7T7. Glass dissolution kinetics at 150 and 2500, role of neo-formed phases

    International Nuclear Information System (INIS)

    Caurel, J.

    1990-01-01

    The glass R7T7 is chosen in France for vitrification of solution from reprocessing. Safety requires the knowledge of R7T7 long term behavior in deep geologic formations. Temperature dependence of leaching between 50 and 300 0 C is studied by static tests for 7 days. An activation energy of 30kJ/Mole is calculated between 50; 75 or 100 0 C and 250 0 C. Results suggest similar corrosion mechanisms between 90-100 and 250 0 C by a complete change between 250 and 275 0 C. Glass corrosion kinetics at 150 0 C and 250 0 C between 1 day and 1 year evidence the precipitation of aluminosilicates and formation of thick amorphous gels progressively enriched with silica. Glass dissolution at 150 0 C and 250 0 C is simulated with the geochemical DISSOL code. Results suggest that dissolution kinetics are controlled by activity of H 4 SiO 4 in solution only. Silica contained into the gel controls corrosion kinetics different from 0. Even if the nature of dissolution mechanisms does not seem modified between 150 and 250 0 C, sample cracking at 250 0 C induces an increase of dissolved glass that does not allow a direct comparison of corrosion kinetics between 150 and 250 0 C [fr

  8. Effects of MgO on short and long term stabilities in water of R7T7 and M7 nuclear waste glasses

    Energy Technology Data Exchange (ETDEWEB)

    Advocat, T; Vernaz, E; Dussossoy, J [CEA Centre d` Etudes de la Vallee du Rhone, 30 - Marcoule (France). Dept. des Procedes de Retraitement; Crovisier, J L [Centre National de la Recherche Scientifique (CNRS), 67 - Strasbourg (France)

    1993-12-31

    Magnesium oxide was added to the standard R7T7 and M7 glass compositions developed for containment of fission product solutions. M7 differs from the R7T7 reference glass mainly by a larger proportion of network modifier elements and a correspondingly lower proportion of glass network forming elements. The percentage of fission products, simulated in this study by inactive elements, was the same in both cases. Increasing the MgO content of the glass compositions by 2 to 5 wt% resulted in significant variations in the aqueous leaching resistance at 90 and 100 deg C. Experimental findings demonstrated that the initial dissolution rate measured at 100 deg C in a Soxhlet apparatus was proportional to the MgO content and inversely proportional to the network former content (mainly SiO2). This was confirmed by a glass hydration model based on the thermodynamic stability of the glass matrix components. Aqueous corrosion tests were also conducted at 90 deg C under static conditions at various SA/V ratios to simulate the progress of the reaction. Under these conditions, the glass dissolution rate diminished more slowly in time when the initial magnesium content was high and the network former content was low. This may be due primarily to a variation in the glass silica solubility limit related to the glass composition; it may also be related to the formation of secondary silica and magnesia alteration products controlling the glass dissolution reaction affinity.

  9. Effects of β-irradiation in multicomponent glasses simulating the matrix of the French nuclear waste glass (R7T7)

    International Nuclear Information System (INIS)

    Boizot, B.; Ghaleb, D.; Petite, G.

    2001-01-01

    4-, 5- and 6-oxide components alumino-borosilicate glasses, with compositions closed to the matrix of the french nuclear glass 'R7T7' have been irradiated with electrons (β) at 2.5 MeV with a Van de Graff accelerator. These glasses have been studied after irradiation with different spectroscopic methods: Electron Paramagnetic Resonance for the study of defects, Raman Micro-spectroscopy for the study of amorphous network evolution under irradiation, and by 11 B MAS NMR. The results of these studies are presented here. It shows in particular a great sensibility to the irradiation conditions like dose rate and irradiation temperature, who are therefore important parameters for the representativeness of such experiments. (authors)

  10. Partitioning of the rare earths and actinides between R7T7 nuclear glass alteration products and solution according to disposal conditions

    International Nuclear Information System (INIS)

    Menard, O.

    1995-01-01

    The alteration of nuclear glass by water is liable to release radionuclides into the environment. Determining the release kinetics of these elements and their aqueous chemical forms are therefore essential steps in establishing the safety of a geological repository site. Leach tests were conducted with a nonradioactive specimen of the French ''R7T7'' light water containment glass spiked with U and Th, and with two R7T7 specimens spiked with 237 Np and 239 Pu, respectively. The alteration solution compositions were representative of deep groundwater and contained carbonate, sulfate, phosphate, fluorine and chlorine ions. The release of U, Th, Np and Pu, as well as of the rare earths La, Ce and Nd were monitored by ICP mass spectrometry and by α spectrometry. Scanning and transmission electron microscopic examination of the nonradioactive altered glass surfaces was also performed to assess the partitioning balance for the rare earths, U and Th between the glass alteration products and solution. The mobility of these elements depends on two competing mechanisms. The rare earths and thorium are incorporated in the alteration products (gel); the retention process is assumed to involve chemisorption or coprecipitation, enhanced in the gel layer by the presence of phosphate ions in particular. Conversely, the aqueous species in the alteration solutions (mainly anions) form complexes with the actinides and rare earths; this phenomenon is particularly evident with U and Np. The presence of carbonate ions favors this mobility. Plutonium differs from U and Np in that it is adsorbed mainly on colloids formed by glass dissolution, the principal factors governing its chemical evolution in solution. (author). refs., 122 figs., 185 tabs

  11. Hydrolysis of R7T7 nuclear waste glass in dilute media: mechanisms and rate as a function of pH

    International Nuclear Information System (INIS)

    Advocat, T.; Vernaz, E.; Charpentier, H.; Crovisier, J.L.; Ehret, G.

    1990-01-01

    R7T7 nuclear waste glass dissolution in highly dilute aqueous media under static conditions at 90 0 C occurs according to two different mechanisms depending on the solution acidity. In acid media (pH 4.8 and 5.5), preferential extraction of glass network modifiers results in the formation of an alkali metal-depleted surface region on which amorphous and crystallized (phosphate) compounds rich in transition elements precipitate. Steady-state dissolution conditions are not reached, as attested by variable normalized Si, B and Na mass losses. Glass dissolution is stoichiometric in basic media (pH 7 to 10): the strong bonds of the silicated network are broken at a rate that increases with the pH: the glass dissolution rate increases by a factor of 15 between pH 7 and 10. Under these conditions, alteration products at the glass/solution interface do not constitute a short-term kinetic barrier against the release of the major glass components

  12. Experimental alteration of R7T7 nuclear model glass in solutions with different salinities (90/sup 0/C, 1 bar): implications for the selection of geological repositories

    Energy Technology Data Exchange (ETDEWEB)

    Godon, N.; Thomassin, J.H.; Touray, J.C.; Vernaz, E.

    1988-01-01

    In order to simulate the leaching of nuclear wastes in repositories percolated by solutions of variable salinity, leaching tests of R7T7 glass in solutions with different NaCl contents have been performed at 90/sup 0/C and 1 bar using a static procedure. A comparison of the efficiency of the different leachants indicated that the alteration was maximum in pure water and in 23.7 g (NaCl) kg/sup -1/ solution. In deionized water, uranium- and rare-earth elements simulating the actinides were found quite immobile: they have not been detected in solution but are present in the alteration layer. On the other hand, in the 23.7 g (NaCl) kg/sup -1/ solution, high amounts of uranium, cerium and neodymium have been detected in solution and did not accumulate in the solid phases. In the highest salinity brines, the bulk reactivity of the glass decreased. In all leachants, the alteration layer was structured in two parts: hydrated glass and flakes. The flakes were mainly nickel-and zinc-bearing aluminosilicate phases. When crystallized, the flakes were identified as berthierine.

  13. Experimental investigation of aqueous corrosion of R7T7 nuclear glass at 90 degrees C in the presence of humic acids: A kinetic approach

    International Nuclear Information System (INIS)

    Gin, S.; Godon, N.; Mestre, J.P.; Vernaz, E.Y.; Beaufort, D.

    1994-01-01

    The dissolution kinetics of the French open-quotes R7T7close quotes nonradioactive LWR reference glass in solutions containing dissolved humic acids were investigated at 9O degrees C during static tests with imposed or free pH. Experiments conducted in highly dilute media, with a glass-surface-area-to-solution-volume (SA/V) ratio of 5 m -1 , showed that the glass dissolution surface reaction is catalyzed by humic acids. With higher degrees of reaction progress (SA/V = 100 m -1 and free pH) the humic acids impose pH modifications on the system compared with inorganic media; moreover, they directly or indirectly enhance the dissolution of certain alkali metals and transition elements, forming aqueous complexes with the latter. During experiments with an imposed pH of 8.5 (SA/V = 1300 and 5300 m -1 ), the humic acids appear to cause increased silica solubility that cannot be accounted for by the formation of silica complexes. A residual corrosion rate in the humic acid media exceeding the rate measured in inorganic media suggests that, in addition to silica, one or more element complexes formed by humic acids may be a kinetically limiting factor. This hypothesis must be confirmed, however, as the quantity of humic acids per unit glass surface area was too small in this experiment to allow unambiguous characterization of the phenomenon

  14. Long-term alteration of R7T7 glass packages: development of a multi-scale approach to estimate the cracking; Alteration a long terme des colis de verres de type R7T7: developpement d'une approche multi-echelle pour evaluer l'impact de la fracturation

    Energy Technology Data Exchange (ETDEWEB)

    Chomat, L. [Paris-6 Univ. Pierre et Marie Curie, 75 (France)]|[CEA Valrho, Lab. d' Etudes du Comportement Long Terme des Materiaux de Conditionnement (LCLT), 30 - Marcoule (France)

    2006-07-01

    The aim of this work is to model the alteration and transport mechanisms implied in a cracks system and to deduce the evolution of the quantity of leached glass. This quantity will be then compared with those measured in leaching tests carried out on a package of industrial size. To estimate this quantity, several steps are required: 1)study of the local alteration inside a crack (according to the alteration parameters: flow, crack opening, pH..) or in a simple set of cracks (connexion); 2)description of a crack system at the package scale by tomography and SEM of bulk samples: opening, accessibility; 3)determination of the alteration parameters in the ALISE device (leaching device of industrial size in which is altered a package for 2001): temperatures gradients, convection, diffusion, pH..; 4)modelling: passage from the local alteration (crack) to the global alteration (package); 5)design and carrying out of a specific experiment to validate the model: control of the system of known cracks (opening, connectivity..) and of the alterations conditions (thermal gradient..); 6)confrontation of the model with the results obtained on ALISE and the specific experiment indicated in 5). The main experimental results are described. (O.M.)

  15. Mise au point du rheometre a cisaillement annulaire pour l'etude de rheologie d'un mastic bitumineux avec verre incorpore =

    Science.gov (United States)

    El Mansouri, Souleimane

    Dans le domaine viscoelastique lineaire (VEL, domaine des petites deformations), le comportement thermomecanique du bitume et du mastic bitumineux (melange uniforme de bitume et de fillers) a ete caracterise au Laboratoire des Chaussees et Materiaux Bitumineux (LCMB) de l'Ecole de technologie superieure (ETS) avec l'appui de nos partenaires externes : la Societe des Alcools du Quebec (SAQ) et Eco Entreprises Quebec (EEQ). Les proprietes rheologiques des bitumes et des mastics ont ete mesurees grâce a un nouvel outil d'investigation appele, Rheometre a Cisaillement Annulaire (RCA), sous differentes conditions de chargement. Cet appareil permet non seulement de solliciter des eprouvettes de tailles importantes par rapport a celles utilisees lors des essais classiques, mais aussi d'effectuer des essais en conditions quasi-homogenes, ce qui permet de donner acces a la loi de comportement des materiaux. Les essais sont realises sur une large gamme de temperatures et de frequences (de -15 °C a 45°C et de 0,03Hz a 10 Hz). Cette etude a ete menee principalement pour comparer le comportement d'un bitume avec celui d'un mastic bitumineux dans le domaine des petites deformations. neanmoins, dans une seconde perspective, on s'interesse a l'influence des fillers de verre de post-consommation sur le comportement d'un mastic a faibles niveaux de deformations en comparant l'evolution des modules complexes de cisaillements (G*) d'un mastic avec fillers de verre et un mastic avec fillers conventionnels (calcaire). Enfin, le modele analogique 2S2P1D est utilise pour simuler le comportement viscoelastique lineaire des bitumes et des mastics bitumineux testes lors de la campagne experimentale.

  16. Etude du vieillissement des verres : corrélation entre émissivité apparente (IR) et transmittance (visible)

    OpenAIRE

    Guiheneuf , Vincent; Delaleux , Fabien; Riou , Olivier; Logerais , Pierre-Olivier; Durastanti , Jean-Félix

    2015-01-01

    International audience; Le verre joue un rôle majeur comme protection supérieure, substrat et piégeage de la lumière dans la plupart des systèmes PV. Cependant, des travaux ont montré qu'au cours de sa durée de vie, un panneau solaire photovoltaïque perd entre 10 et 15% de son rendement, essentiellement à cause de pertes optiques. Nous avons testé une méthode de contrôle non destructif et non intrusif permettant de diagnostiquer l'état de vieillissement du verre sodocalcique, à l'aide d'une c...

  17. Study of rhyolitic glasses alteration in contact with natural brines (Bolivia). Application to the study of the long-term behaviour of the R7T7 nuclear glass

    International Nuclear Information System (INIS)

    Abdelouas, A.

    1996-01-01

    The purpose of this work is to complement an experimental program on the R7T7 nuclear waste glass alteration in brines at 190 deg C in Germany by the analysis of the structure and the chemical composition of the alteration layers, and to study the alteration of rhyolitic glasses in natural brines from Bolivia as analogue for nuclear waste glasses disposed in salt formations. Alteration experiments with the R7T7 and basaltic glasses and obsidian in MgCl 2 -CaCl 2 -saturated brine at 190 deg. C were also conducted in order to study the influence of the glass composition on the nature of the secondary phases. The experiments with the R7T7 glass in three salt brines, saturated respectively in MgCl 2 , MgCl 2 -CaCl 2 and NaCl, showed that the solubilities of most radionuclides are controlled by the secondary phases. Nd, La, and Pr are trapped in powellite, Ce in cerianite, U in coffinite, and Sr is partially immobilized in barite. These phases are stable for more than one year. There is a good similarity between the secondary phases formed experimentally on volcanic glasses and the R7T7 glass altered in MgCl 2 -CaCl 2 -saturated brine. The abundance of Mg in solution permits the formation of similar magnesian clays on the glass samples independently of the nature of the initial glasses. These results support the use of volcanic glasses alteration patterns in Mg-rich solutions to understand the long-term behavior of nuclear waste glasses and to evaluate the stability of the secondary phases. The study of the sediments of Uyuni (Bolivia) showed that the corrosion rate of the rhyolitic glass in brines at 10 deg. C is 12 to 30 time lower than those of rhyolitic glasses altered in high dilute conditions. The low alteration rate of rhyolitic glasses in brines and the formation of secondary phases such as smectite, barite and cerianite (also formed during the experimental alteration of the R7T7 glass), permit us to expect the low alteration of nuclear waste glasses at long

  18. Etude structurale et propriétés des verres peralumineux de conditionnement des produits de fission et actinides mineurs"

    OpenAIRE

    Gasnier , Estelle

    2013-01-01

    In this work, peraluminous glasses (lack of alkaline and alkaline earth ions regarding aluminum) are under study to assess the potentiality of these matrices to confine fission products and minor actinides (FPA) at higher rate than current R7T7 glass (18,5 wt % FPA). The first part of this work aims at studying the physical and chemical properties of complex peraluminous glasses containing increasing FPA rate (18.5 to 32 wt %) to compare them with the specifications. The very low crystallizat...

  19. Study of nuclear glasses alteration gel and synthesis of some model gels; Etude du gel d`alteration des verres nucleaires et synthese de gels modeles

    Energy Technology Data Exchange (ETDEWEB)

    Ricol, S

    1995-10-05

    This work deals with the general problem of alteration of the reference nuclear glass R7T7. Attention is paid particularly to the altered layer formed at the glass surface during alteration process. In opposition to previous works, related essentially to glass dissolution kinetics based on chemical analyses of lixiviated elements, this thesis deals with alteration problems through structural studies of the reference glass and derived gel. This approach allows the determination of mechanisms for the gel formation and a better understanding of the behaviour of glasses towards lixiviation. Both approaches appeared complementary. Based on several spectroscopic techniques, this work showed the particular role of cations such as calcium, zirconium and iron. Studies of silica-based synthetic gels showed the synergic effect of formers cation and of one highly coordinated cation. The variation of the wavenumber related to Si-O-Si asymmetric stretching vibration can be correlated to O/Si ratio for ternary systems Si/Na/Zr. On the contrary, the Si losses of the materials depend on the number of non-bridging oxygen atoms. In the perspective of long-term behaviour, the alteration gel presents better characteristics than initial glass. It is therefore a highly stable material in static conditions. In the same way, synthetic gels are materials with very low solubilities (much lower than the alteration gel) and could be used as confining matrices. (authors). refs., 71 figs., 37 tabs.

  20. Etude de la structure et du comportement en cristallisation d'un verre nucléaire d'aluminoborosilicate de terre rare

    OpenAIRE

    Quintas , Arnaud

    2007-01-01

    Ce travail de thèse porte sur l'étude d'un verre aluminoborosilicate de terre rare de composition molaire 61,81 SiO2 - 3,05 Al2O3 - 8,94 B2O3 - 14,41 Na2O - 6,33 CaO - 1,90 ZrO2 - 3,56 Nd2O3, destiné au confinement des déchets issus du retraitement de combustibles nucléaires usagés à haut taux de combustion. Au niveau structural, nous nous sommes intéressés principalement au rôle des ions modificateurs sur l'organisation du réseau vitreux par le biais de différents changements de composition ...

  1. Contribution to the study of stimulated emission in neodymium-doped glass; Contribution a l'etude de l'emission stimulee dans le verre dope au neodyme

    Energy Technology Data Exchange (ETDEWEB)

    Jego, J M [Commissariat a l' Energie Atomique, Limeil-Brevannes (France). Centre d' Etudes; Faculte des Sciences de Rennes, 35 (France)

    1969-07-01

    annees pour voir les premieres realisations. Le maser fonctionnant dans le domaine des ondes micrometriques apparait en 1954. Dans le domaine optique, le premier 'LASER' est realise par MAIMAN en 1960. L'atome actif etait le chrome au sein d'une matrice d'alumine (rubis). le monocristal fluorescent etait place entre deux reflecteurs charges de maintenir dans le mileu une inversion provoquee de population jusqu'a atteindre les conditions d'emission. L'effet laser a permis de realiser beaucoup de generateurs de raies (plusieurs centaines) couvrant la gamme optique avec les mileux tant gazeux que liquides ou solides. Parmi ceux ci, le neodyme presente une transition entre les niveaux 4 F{sub 3/2} et 4 I{sub 11/2} qui a permis la realisation de lasers de tres grande puissance. Ce travail etudie les conditions de formation d'une impulsion declenchee et de son amplification dans le verre dope au neodyme. Des mesures precises des divers rendements interessants dans ces processus nous ont permis de connaitre la valeur de l'inversion de population realisee dans le milieu et d'etudier le detail de l'emission stimulee. (auteur)

  2. Characterization of the R7T7 LWR reference glass

    International Nuclear Information System (INIS)

    Pacaud, F.; Fillet, C.; Baudin, G.; Bastien-Thiry, H.

    1990-01-01

    Characterization describes the glass properties by means of standard tests with no attempt to assess its long-term behavior. Characterization involved complementary comparative investigations of nonradioactive laboratory glass specimens, radioactive glass specimens prepared in laboratory hot cells, and nonradioactive industrial glass samples fabricated in the full-scale continuous vitrification prototype facility (specimens were taken from the casting stream and core-samples were taken from a 200 kg glass block after cooling in the canister). Additional measurements are planned on actual radioactive glass samples fabricated in the R7 facility at La Hague. The results are indicated for each of the properties studied: physical, thermal and mechanical properties; structure and homogeneity examination; thermal stability and crystallization; resistance to chemical corrosion; irradiation resistance and volatilization. Comparative examination of glass samples of different origins showed consistent properties

  3. Contribution to the study of the effects of {alpha}-irradiation in nuclear glasses; Contribution a l'etude des effets de l'irradiation {alpha} sur les verres nucleaires

    Energy Technology Data Exchange (ETDEWEB)

    Abbas, A

    2001-07-01

    The main topic of this work is to characterise the effects of {alpha}-disintegration in nuclear waste glasses. Experimental and numerical approaches have been considered. The structure of the French nuclear waste glass (R7T7) has been simulated using four- and six-oxides simplified glasses which contain the main elements of the R7T7 glass: SiO{sub 2}, B{sub 2}O{sub 3}, Na{sub 2}O, ZrO{sub 2}, Al{sub 2}O{sub 3} and CaO. Four- and six-oxides glasses have been irradiated with 1 MeV-He{sup +} (ionisation) and 2.1 MeV-Kr{sup 3+} (ionisation and atomic collisions) ions in order to reproduce the effects of the {alpha}-particle and of the recoil nucleus emitted during {alpha}-disintegration of actinides, and also to differentiate electronic and ballistic effects. Irradiated glasses have been characterised using several techniques, which have been adapted to the peculiarities of our samples (isolated material, small irradiated depth). The results point out the salient role of sodium in the observed modifications: depth concentration profiles obtained with RBS show an accumulation of sodium at the irradiated surface. We found a apparent acceleration of sodium release in leaching experiments which confirm that point. Modifications observed in Raman spectra of irradiated glasses show an increase of the polymerisation (increase of Q{sub 3}/Q{sub 2} ratio) due to sodium migration. In simplified glasses we have found that the modifications of mechanical properties by external irradiations reproduce the modifications observed in actinide doped nuclear glass (decrease of hardness and increase of fracture toughness). At the same time, we performed Molecular Dynamics simulations of a six-oxides glass. We have shown that the surface modifies the glass structure down to a depth of 10 Angstrom: modification of depth concentration profiles, decrease of the atomic coordination number (A1, B and Si). During cascades, we found that atomic displacements are easier near the surface. This

  4. Compared study of the local structure of alteration products of SON 68 glass and natural gels; Etude comparee de la structure locale des produits d'alteration du verre SON 68 et de gels naturels

    Energy Technology Data Exchange (ETDEWEB)

    Pellegrin, E

    2000-07-01

    This study is a contribution in the understanding of the long time behavior of alteration products of the glass SON 68, used to simulate the nuclear glass R7T7. The local structure around Zirconium and iron has been probed using X-ray absorption spectroscopy in altered surface layer of glass SON 68. Alteration products of this glass have been prepared for short (3 hours to 7 days) and long (17 months) time, using various indexes of saturation for the leaching solution with respect to the Si content of the glass (from 0 to 90 %). The evolution of the local structure around Fe has also been studied in recent and old natural ferric gels. Zr, Fe- L{sub 2,3} XANES and Zr, Fe-K EXAFS spectroscopies have shown that, in the pristine glass, these elements are connected to the polymeric network. Zr is found in an environment close to that of a zircon-silicate containing Na and Ca. Trivalent Fe is a network former. The leached layer of glass SON 68 is constituted of poorly ordered Zr-and Fe-(oxi-hydr)oxides that may have been formed by a mechanism of dissolution/precipitation; a relict phase with the same Zr local structure as that observed in the pristine glass, probably obtained thanks to in-situ solid condensation. The structural characteristics of the leached layer are observed from the first steps of alteration for Zr and Fe. Conversely to Fe, the structural status of Zr depends on the leaching kinetic as well as the contents of Ca and Si in the solid. Fe-K EXAFS results in recent natural ferri-hydrides present a clear structural similarity with that determined in glass SON 68 leached products. The study of old paleosols (between 1,800 and 200,000 years) has demonstrated the long time stability of ferric gels, although an increase of medium range order around Fe is seen. (author)

  5. Les adhésifs à photopolymérisation radicalaire employés pour le cpllage structural du verre en conservation-restauration: Etude de la résistance au cisaillement de 4 adhésifs optiques polymérisables aux UV

    OpenAIRE

    Gillioz, Sandra,

    2016-01-01

    Les adhésifs photopolymérisables, dont la prise s’effectue en quelques secondes sous rayonnement ultraviolet (UV), représentent une option séduisante pour le collage du verre en conservationrestauration, particulièrement lorsque les fragments ne peuvent être maintenus de manière temporaire. Dans le présent travail, nous avons étudié la compatibilité des adhésifs photopolymérisables avec le collage du verre en conservation-restauration en nous focalisant sur leur résistance mécanique. Quatre a...

  6. Use of glasses as industrial dosimeters; Utilisation des verres comme dosimetres industriels

    Energy Technology Data Exchange (ETDEWEB)

    Balestic, F. [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires; Le Clerc, P.; Bonnaud, M. [Centre de Recherches des Glaceries de Saint-Gobain (France)

    1959-07-01

    Glasses have the property of colouring under the action of ionizing radiations. We endeavoured to specify the conditions under which the intensity of coloration can be used as a measure of the quantity of radiation to which the glass has been submitted. In the case of a glass loaded with cobalt, a study of the optical density at different wavelengths enabled us to find the factors governing the formation of coloured centres and their conservation in the glass. We give a set of calibrating curves for different values of these parameters (irradiation rate, irradiation temperature; fading time and fading temperature), enabling determination of radiation doses in the range from 10 000 to 1 000 000 rep from measured optical density. (author) [French] Les verres ont la propriete de se colorer sous l'action des rayonnements ionisants. Nous avons cherche a preciser les conditions dans lesquelles l'intensite de la coloration peut servir de mesure de la quantite du rayonnement auquel le verre a ete soumis. Dans le cas d'un verre charge au cobalt, l'etude de la densite optique a differentes longueurs d'onde a mis en evidence divers facteurs dont depend la formation des centres colores et leur conservation dans le verre. En prenant comme parametres ces divers facteurs (temperature d'irradiation, intensite d'irradiation, temperature de conservation et duree de conservation) nous avons etabli des courus d'etalonnage permettant la determination de doses entre 10 000 et 1 000 000 rep d'apres la densite optique observee. (auteur)

  7. Use of glasses as industrial dosimeters; Utilisation des verres comme dosimetres industriels

    Energy Technology Data Exchange (ETDEWEB)

    Balestic, F [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires; Le Clerc, P; Bonnaud, M [Centre de Recherches des Glaceries de Saint-Gobain (France)

    1959-07-01

    Glasses have the property of colouring under the action of ionizing radiations. We endeavoured to specify the conditions under which the intensity of coloration can be used as a measure of the quantity of radiation to which the glass has been submitted. In the case of a glass loaded with cobalt, a study of the optical density at different wavelengths enabled us to find the factors governing the formation of coloured centres and their conservation in the glass. We give a set of calibrating curves for different values of these parameters (irradiation rate, irradiation temperature; fading time and fading temperature), enabling determination of radiation doses in the range from 10 000 to 1 000 000 rep from measured optical density. (author) [French] Les verres ont la propriete de se colorer sous l'action des rayonnements ionisants. Nous avons cherche a preciser les conditions dans lesquelles l'intensite de la coloration peut servir de mesure de la quantite du rayonnement auquel le verre a ete soumis. Dans le cas d'un verre charge au cobalt, l'etude de la densite optique a differentes longueurs d'onde a mis en evidence divers facteurs dont depend la formation des centres colores et leur conservation dans le verre. En prenant comme parametres ces divers facteurs (temperature d'irradiation, intensite d'irradiation, temperature de conservation et duree de conservation) nous avons etabli des courus d'etalonnage permettant la determination de doses entre 10 000 et 1 000 000 rep d'apres la densite optique observee. (auteur)

  8. Electron paramagnetic resonance study of radicals formed by radiolysis at 77 K of nitroalkanes and of their solutions in organic glasses. Chromatography analysis of radiolysis products of nitromethane in ethanol solution in a vitreous medium; Etude par resonance paramagnetique electronique des radicaux formes par radiolyse a 77 K des nitroalcanes et de leurs solutions dans les verres organiques analyse par chromatographie des produits de la radiolyse du nitromethane en solution dans l'ethanol en milieux vitreux

    Energy Technology Data Exchange (ETDEWEB)

    Rosilio, C [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1968-05-01

    etude porte sur la structure et la reactivite des radicaux formes par irradiation 7 des derives nitres a 77 K, et sur le mecanisme de formation et de disparition de ces radicaux dans les differentes matrices utilisees. Les radicaux resultant de l'arrachement d'un hydrogene en {alpha} du groupe NO{sub 2}, et les radicaux resultant de reactions d'addition sur le groupe nitre caracterises par un electron non apparie sur l'azote ont ete identifies, soit dans la radiolyse des nitroalcanes purs, soit dans la radiolyse a 77 K des nitroalcanes en solution dans les verres organiques. La conformation et les mouvements des radicaux dans les matrices, le mecanisme de formation des radicaux observes resultant generalement de la capture par les nitroalcanes des especes primaires de la radiolyse ont ete etudies. Les nitroalcanes en solution dans l'ethanol se manifestent a la fois comme capteurs d'electrons et de radicaux libres. L'etude de la radiolyse des nitroalcanes en solution dans un verre polaire d'ethanol a ete completee par des analyses chimiques des produits finals de la radiolyse; elle nous a permis de deduire l'efficacite de capture des electrons pieges et des radicaux libres par les nitroalcanes dans l'ethanol. Pour cela nous avons dose, pour le systeme nitro-methane - ethanol les rendements radiochimiques de-l'hydrogene, de l'acetaldehyde et du glycol en fonction de la concentration en capteur. Un mecanisme de disparition des radicaux observes a ete propose. (auteur)

  9. Electron paramagnetic resonance study of radicals formed by radiolysis at 77 K of nitroalkanes and of their solutions in organic glasses. Chromatography analysis of radiolysis products of nitromethane in ethanol solution in a vitreous medium; Etude par resonance paramagnetique electronique des radicaux formes par radiolyse a 77 K des nitroalcanes et de leurs solutions dans les verres organiques analyse par chromatographie des produits de la radiolyse du nitromethane en solution dans l'ethanol en milieux vitreux

    Energy Technology Data Exchange (ETDEWEB)

    Rosilio, C. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1968-05-01

    radiolyse. Notre etude porte sur la structure et la reactivite des radicaux formes par irradiation 7 des derives nitres a 77 K, et sur le mecanisme de formation et de disparition de ces radicaux dans les differentes matrices utilisees. Les radicaux resultant de l'arrachement d'un hydrogene en {alpha} du groupe NO{sub 2}, et les radicaux resultant de reactions d'addition sur le groupe nitre caracterises par un electron non apparie sur l'azote ont ete identifies, soit dans la radiolyse des nitroalcanes purs, soit dans la radiolyse a 77 K des nitroalcanes en solution dans les verres organiques. La conformation et les mouvements des radicaux dans les matrices, le mecanisme de formation des radicaux observes resultant generalement de la capture par les nitroalcanes des especes primaires de la radiolyse ont ete etudies. Les nitroalcanes en solution dans l'ethanol se manifestent a la fois comme capteurs d'electrons et de radicaux libres. L'etude de la radiolyse des nitroalcanes en solution dans un verre polaire d'ethanol a ete completee par des analyses chimiques des produits finals de la radiolyse; elle nous a permis de deduire l'efficacite de capture des electrons pieges et des radicaux libres par les nitroalcanes dans l'ethanol. Pour cela nous avons dose, pour le systeme nitro-methane - ethanol les rendements radiochimiques de-l'hydrogene, de l'acetaldehyde et du glycol en fonction de la concentration en capteur. Un mecanisme de disparition des radicaux observes a ete propose. (auteur)

  10. Assessment of the alteration of R7T7-type glass according to storage conditions

    International Nuclear Information System (INIS)

    Jollivet, P.; Minet, Y.; Nicolas, M.; Vernaz, E.

    1997-01-01

    The PREDIVER code was used to estimate the influence of the major parameters of a geological repository site on the alteration oh a high-level vitrified waste package. The kinetic law of glass alteration is based on a deviation concerning saturation with respect to silicic acid. Glass alteration is governed by the coefficient of silicon diffusion in the interstitial water of the gel layer and by the leachate renewal rate (i.e. the flow rate in the repository) if it is of very low magnitude. The effects of other parameters are much less significant. When applied to the alteration of natural basalts, the PREDIVER code overestimates glass alteration, indicating that transport limitations slow down the alteration processes over a long time period. (authors)

  11. The R7/T7 vitrification at La Hague: 10 years of operation

    International Nuclear Information System (INIS)

    Masson, H.; Desvaux, J.L.; Pluche, E.; Jouan, A.

    2001-01-01

    Vitrification of high level wastes from reprocessing of spent nuclear fuels has been carried out at La Hague on an industrial scale for ten years. This paper presents an historical overview of the facilities, and describes the facilities and their operations, startup performance, facility upgrading that has been done, and process control functions. The paper concludes that the technology for vitrification of high level wastes is mature and has been mastered. (author)

  12. Early phyllosilicates formed by alteration of R7T7 glass in water at 250 deg C

    International Nuclear Information System (INIS)

    Vernaz, E.; Dussossoy, J.L.; Caurel, J.; Crovisier, J.L.

    1991-01-01

    T7T7 glass samples have been altered during periods of one and seven days at 250 deg C in distilled water. Ultramicrotomic thin sections were performed in the outermost part of the glass for a study under analytical transmission electron microscope. After one day the alteration layer is about 5 μm thick. It is made up of sheeted silicated particles, tentatively identified as septechlorite (7 A intervals) mixed with an intercrystalline amorphous matrix of different composition. After seven days the alteration layer is about 11 μm thick. It is made up of sheeted silicated particles of smectite type (10 A intervals). No 7 A particles were found in the seven days sample. This study illustrates the capacity of poorly crystalline phyllosilicates to adapt to the chemical changes in solution. 15 refs., 4 tabs., 2 plates

  13. Modeling of solution renewal with the Kindis code: example of R7T7 glass dissolution at 90 deg C

    International Nuclear Information System (INIS)

    Advocat, T.; Vernaz, E.; Crovisier, J.L.; Clement, A.; Gerard, F.

    1994-01-01

    The deep underground environment that would correspond to a geological repository is a system open to fluid flow. It is therefore necessary to investigate the effects of solution renewal on the long-term behavior of glass in contact with water. These effects can now be simulated using the new version of the geochemical KINDIS model (thermodynamic and kinetic model). We tested the model at 90 deg C with an SA/V ratio of 400 m -1 at twelve renewal rates of pure water ranging from 200 to 0 vol% per day. With renewal rates between 200 and 0.065 vol% per day, steady-state conditions were obtained in the reaction system: i.e. the glass corrosion rate remained constant as did the concentrations of the dissolved species in solution (although at different values depending on the renewal rate). The ionic strength never exceeded 1 (the validity limit for the DEBYE-HUCKEL law) and long term predictions of the dissolved glass mass, the solution composition and the potential secondary mineral sequence are possible. For simulated renewal rates of less than 0.065 vol% per day (27% per year), the ionic strength rose above 1 (as in a closed system) before steady-state conditions were reached, making it critical to calculate long-term rates; A constant and empirical long-term rate, derived from laboratory measurement, have to be extrapolated. These calculations were based on a first order equation to describe the glass dissolution kinetic. The results obtained with the KINDIS code show discrepancies with some major experimental kinetic data (the long term rate must decrease with the ''glass-water'' reaction progress, under silica saturation conditions). This clearly indicates that a more refine kinetic relation is needed for the glass matrix. (authors). 16 refs., 4 figs., 4 tabs

  14. The understanding of the R7T7 glass blocks long term behavior: chemical and transport coupling in fractured media

    International Nuclear Information System (INIS)

    Chomat, L.

    2008-04-01

    The long term behavior of nuclear waste glass blocks depends highly on chemical reactions which occur at the surface in contact with water. Studies carried out on inactive fractured glass blocks show that fracture networks play a significant part in reactive surface area. Nevertheless, the complexity of results interpretation, due to a weak knowledge of fracture networks and local lixiviation conditions, does not allow us to comprehend the physical and chemical mechanisms involved. Model cracks are a key step to study chemical and transport coupling in fractured media. Crack lixiviation in aggressive conditions (pH≥11) show that the crack's position (horizontal or vertical) determines the dominant transport mechanism (respectively diffusion or convection induced by gravity). This gravity driven flow seems to be negligible in lower pH conditions. The convective velocity is estimated by a 1D model of reactive transport. Two other parameters are studied: the influence of thermal gradient and the influence of interconnected cracks on alteration. A strong retroactive effect of convection, due to thermal gradient, on the alteration kinetic is observed inside the crack. These works lead to a complete alteration experiment of a 163 crack network subject to a thermal gradient. The use of the geochemical software, HYTEC, within the framework of this study shows the potential of the software which is however limited by the kinetics law used. (author)

  15. Aqueous corrosion of french R7T7 nuclear waste glass: selective then congruent dissolution by pH increase

    International Nuclear Information System (INIS)

    Advocat, T.; Vernaz, E.; Crovisier, J.L.

    1991-01-01

    A study of the corrosion of a borosilicate nuclear glass shows the strong effect of the pH on the dissolution mechanism. Acidic media lead to selective extraction of the glass modifier elements (Li, Na, Ca) as well as B, while dissolution is congruent under alkaline conditions. The silica dissolution rate significantly increases with increasing pH [fr

  16. Retention of actinides and rare earth in the alteration gels of R7T7 nuclear glass

    International Nuclear Information System (INIS)

    Advocat, Th.; Menard, O.; Chouchan, J.L.; Jollivet, P.

    1997-01-01

    Under oxic conditions, over 98.5% of the lanthanides and thorium released from the glass were retained in the alteration products on the glass surface, probably by coprecipitation with a siliceous gel. Uranium and Neptunium retention varied from 40% in carbonated medium to more than 95% in phosphate medium. With carbonate ions, Np and U formed stable complexes, which tend to limit actinide incorporation in the gel layer. Plutonium retention is larger than 90%. This element exhibited atypical behaviour to the extend that it was strongly bonded to colloidal particles in solution. (authors)

  17. The Verrès Castle Access Project

    Directory of Open Access Journals (Sweden)

    Tito Berti Nulli

    2010-10-01

    Full Text Available The article describes the access project of the Verrès castle, located in Aosta Valley in Italy, underlining some urban and transport planning and design elements. This project constitute in fact an interesting example of integration between transport infrastructure planning and design with urban planning strategy for tourism development. The transport infrastructure (in this case a vertical lift for tourism use has furthermore a deep attention to the landscape and social contest and a good architectural design. The Verrès castle access project represents and interesting example of sustainable mobility and of touristic area accessibility which is strong integrated with urban renewal and territorial development. The feasibility study, financed by the Verrès municipality, is part of a the INTERREG IIIA ACOLTRA Project financed by Italy and France with the aim of creating a network of transnational tourist itineraries. Through this initiative Aosta Valley and Haute-Savoy are developing a common tourism strategy that intends to promote cultural heritage and tourism mobility through the RITT (Reseaux d’Itineraires Touristiques Transfrontalieres. In this contest of intervention the study for the accessibility of the Verrès castle is inserted, with the aim of designing a mobility infrastructure for the main attraction of the valley and at the same of strengthening the appeal of tourist attraction of the whole area. The project is located in the small city of Verrés, that lies at 390m, on the banks of the river Evançon. As many of the Valdostani municipalities is characterized by several small urban centers, which are located in a around 8kmq, in a territory where live 2.700 inhabitants. The feasibility study examines three different alternative for a lift that should connect the Verrès centre with the castle. In particular different transport technology (inclined and vertical lift and several path alternatives have been evaluated. The final

  18. Maison de verre / Zonestraal. Relato de dos edificios

    Directory of Open Access Journals (Sweden)

    Jan Molema

    2014-01-01

    Full Text Available Desde los años sesenta del siglo XX el sanatorio Zonnestraal de Hilversum y la Maison de Verre en París han sido descritos extensamente en la literatura de la arquitectura moderna. Sin embargo, no se ha hecho ningún esfuerzo por colocarlos juntos en un mismo relato. Este ensayo es un esfuerzo para enmendar ese vacío. Ambos están relacionados íntimamente por sus autores: Bernard Bijvoet, como codiseñador de los planos de la Maison, y Johannes Duiker, quien trabajó con el anterior en los preliminares de Zonnestraal, aunque lo finalizó en solitario, al mismo tiempo que se terminó el diseño de la casa. En el trabajo se cuestiona además, ofreciendo fundadas conjeturas, la creencia establecida de que se precisó una nueva estructura metálica para sustentar la inalterada vivienda situada encima de la Maison de Verre.

  19. Vitrail, verre et archéologie entre le ve et le xiie siècle

    OpenAIRE

    Sapin, Christian

    2010-01-01

    Depuis longtemps, les fouilles archéologiques ont fait apparaître des fragments de verre en très grand nombre. L’intérêt des archéologues, orienté dans un premier temps vers les verres creux, se tourne de plus en plus vers les fragments de verre plat. Ceci conduit à poser de nouvelles questions sur les diverses utilisations du verre dans l’architecture, tant civile que religieuse, en particulier pour ce qui touche à la fermeture des baies ou au décor intérieur. Cette publication fait un point...

  20. Vitrail, verre et archéologie entre le ve et le xiie siècle

    Directory of Open Access Journals (Sweden)

    Christian Sapin

    2010-10-01

    Full Text Available Depuis longtemps, les fouilles archéologiques ont fait apparaître des fragments de verre en très grand nombre. L’intérêt des archéologues, orienté dans un premier temps vers les verres creux, se tourne de plus en plus vers les fragments de verre plat. Ceci conduit à poser de nouvelles questions sur les diverses utilisations du verre dans l’architecture, tant civile que religieuse, en particulier pour ce qui touche à la fermeture des baies ou au décor intérieur. Cette publication fait un point...

  1. Folds and Etudes

    Science.gov (United States)

    Bean, Robert

    2007-01-01

    In this article, the author talks about "Folds" and "Etudes" which are images derived from anonymous typing exercises that he found in a used copy of "Touch Typing Made Simple". "Etudes" refers to the musical tradition of studies for a solo instrument, which is a typewriter. Typing exercises are repetitive attempts to type words and phrases…

  2. Evaluation de la bioactivité d’un verre synthétisé par voie sol-gel

    OpenAIRE

    BCHELLAOUI, Nizar

    2016-01-01

    D’un point de vue structural, on peut définir un verre comme « un solide non cristallin ». Certains verres se comportent comme des matériaux totalement inertes, d’autres sont biodégradables et d’autres enfin ont présentés une adaptation osseuse très satisfaisante. Ce dernier type particulier de verre; contenant de la silice, du calcium et des phosphates est appelé bioverre ou verre bioactif : il a la propriété de se lier intimement à l’os et de mieux s’adapter aux ti...

  3. Analytic implementation of the GRAAL model: Application to a R7T7-type glass package in a geological disposal environment

    Energy Technology Data Exchange (ETDEWEB)

    Minet, Y., E-mail: yves.minet@cea.f [CEA Marcoule, DTCD/SECM/LCLT, BP 17171, 30207 Bagnols-sur-Ceze Cedex (France); Bonin, B. [CEA Saclay, DEN/DIR/DS, 91191 Gif-sur-Yvette Cedex (France); Gin, S.; Frugier, P. [CEA Marcoule, DTCD/SECM/LCLT, BP 17171, 30207 Bagnols-sur-Ceze Cedex (France)

    2010-09-30

    The Glass Reactivity with Allowance for the Alteration Layer Model (GRAAL) was proposed in 2008 to describe borosilicate nuclear glass alteration based on coupling an affinity law with the formation and dissolution of a passivating reactive interface. It is examined here in a simplified form in which only the affinity with respect to silicon is taken into account with a concentration at saturation C{sub sat}, and the precipitation of neoformed phases is described by an affine relation for silicon above a precipitation threshold C{sub sat}{sup '}. This simplified 'analytical GRAAL' model is capable of predicting the quantities of altered glass and the silicon and boron concentration variations in analytical or semi-analytical form, and thereby identify the main characteristic quantities of the system. The model was tested against a series of laboratory experiments lasting from a few days to a few years; its sensitivity to the parameter values was examined, and the model was validated with respect to SON68 glass alteration in initially pure water. It was then applied to the alteration of a glass package in a repository over periods of up to a million years, by means of exploratory calculations comprising a sensitivity study of the internal model parameters and extrapolation to the temperatures expected in a geological repository in order to identify the parameters and mechanisms having the greatest impact on the residual alteration rate. Alteration is controlled by the precipitation of neoformed phases in every case. The transient conditions are of very limited duration with respect to either silicon or boron (no more than a 100 years, with less than 0.01% alteration of the package). In the precipitation law used in the model, the residual alteration rate and total package lifetime are determined primarily by two parameters: k' (the precipitation kinetics) and {sigma}' (the precipitate surface area per unit volume in the geological barrier). The package lifetime is about 3 x 10{sup 5} years at 30 {sup o}C assuming a reasonable value for {sigma}' (10{sup 6} m{sup -1}), and would be increased by a factor 3-6 if precipitation in the barrier were disregarded. This cursory description of precipitation will be validated and refined through specific laboratory tests at 50 {sup o}C and lower temperatures, coordinated with the development of the 'geochemical GRAAL' model and with integral tests in contact with clay and canister corrosion products.

  4. In situ study of glasses decomposition layer; Etude in situ de la couche d`alteration de verres

    Energy Technology Data Exchange (ETDEWEB)

    Zarembowitch-Deruelle, O

    1997-10-21

    The aim of this work is to understand the involved mechanisms during the decomposition of glasses by water and the consequences on the morphology of the decomposition layer, in particular in the case of a nuclear glass: the R{sub 7} T{sub 7}. The chemical composition of this glass being very complicated, it is difficult to know the influence of the different elements on the decomposition kinetics and on the resulting morphology because several atoms have a same behaviour. Glasses with simplified composition (only 5 elements) have then been synthesized. The morphological and structural characteristics of these glasses have been given. They have then been decomposed by water. The leaching curves do not reflect the decomposition kinetics but the solubility of the different elements at every moment. The three steps of the leaching are: 1) de-alkalinization 2) lattice rearrangement 3) heavy elements solubilization. Two decomposition layer types have also been revealed according to the glass heavy elements rate. (O.M.) 59 refs.

  5. Préparation et caracterisation de composites ll verre-supraconducteur gg

    Science.gov (United States)

    Roblin-Semène, L.; Pradel, A.; Ribes, M.; Belouet, C.

    1994-11-01

    Several types of " glass/superconductor " composites were prepared by a uniaxial hot pressing method. The BiSrCaCuO oxides were the materials under investigation in this work. A preliminary study of glasses obtained in this BiSrCaCuO system indicated that phase separation with nodules of 50 to 100 nm generally occurs. Glasses used as parts of composites are : 1) PbOB2O3 ones because of their low transition temperature and their large thermal stability which were favourable to texturation of superconducting grains, 2) BiSrCaCuO (2212, 2223, 4334) glasses because further recrystallisation could be carried out to improve grain connectivity and at last 3) mixture of BiSrCaCuO glass and V2O5 or PbO-B2O3 to insure a compromise between texturing and connectivity. Resistivity and current density measurements indicated that these types of composites were potential candidates for use as current limiters. Différents composites " verre/supraconducteur " ont été préparés par pressage à chaud uniaxial. Nos travaux ont porté sur les oxydes " BiSrCaCuO ". Une étude préalable des verres de ce système a permis de mettre en évidence une séparation de phase avec présence de nodules dont la taille est comprise entre 50 et 100 nm. Les verres choisis pour l'élaboration de ces composites ont été : 1 ) le verre PbO-B2O3 dont la basse température de transition vitreuse et la grande stabilité thermique étaient des éléments favorables à une bonne texturation des grains supraconducteurs, 2) les verres BiSrCaCuO purs (2212, 2223, 4334) dont la recristallisation partielle par recuit a posteriori devait assurer une meilleure connectivité entre grains, et enfin 3) des mélanges " BiSrCaCuO (V) " + V2O5 OU PbO-B2O3 qui devaient permettre d'assurer un compromis entre texturation et connectivité. Les mesures de résistivité et de densité de courant montrent que ces composites sont de bons candidats pour des applications de limiteur de courant.

  6. Solidification of residual fission-product solutions; laboratory studies; Solidification de solutions residuaires concentrees de produits de fission: etudes de laboratoire

    Energy Technology Data Exchange (ETDEWEB)

    Boniaud, R; Cohen, P; Sombret, C [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1961-07-01

    This paper describes the results obtained, at laboratory scale, during the study of the incorporation of fission products into glasses and synthetic micas. The rate of leaching of fission products from the glass and their volatility during firing were measured. A hot cell was built to complete these results. (author) [French] Ce rapport resume le resultat des etudes faites en laboratoire (activite de l'ordre du millicurie) sur l'incorporation des produits de fission dans des verres et micas synthetiques. On a mesure le taux de lixiviation des produits de fission et leur volatilisation au cours de la cuisson. Une cellule chaude a ete installee pour completer ces resultats au moyen d'essais realises avec une activite superieure. (auteur)

  7. The present state of research on the vitrification of concentrated solutions of fission products (1962); Etat des etudes sur la vitrification des solutions concentrees de produits de fission (1962)

    Energy Technology Data Exchange (ETDEWEB)

    Bonniaud, R; Sombret, C [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1961-07-01

    The present report gives the actual point of studies on vitrification of concentrated solutions of fission products. An active cell, giving glasses in crucibles, permitted to study various glass compositions. The leaching rate from the glass raises 1 to 2 10{sup -7} g of glass/cm{sup 2}/day. Activity loss by volatility during vitrification remains weak and often below 0.1 per cent of total activity. Off gas cleaning is made easier by presence of filter which is compound of granules including iron oxide. After saturation the content of this filter can be melt. Moreover different processes are in experimentation for a more important production. Daily 72 liters of solution containing tracer activity are treated in a continuous calcination and vitrification plant. The loss in {sup 106}Ru is still important and a modification of installation has been necessary. A pot vitrification plant is in study. In order to reduce cost of processing the possibility to pour glass after melting is actuality in study. A production set of very active glass is also in project. (authors) [French] Le present rapport fait le point des etudes menees sur la vitrification des solutions concentrees de produits de fission. Une installation active, produisant des verres en creusets, a permis d'etudier plusieurs compositions de verres. Le taux de perte d'activite par lixiviation a l'eau atteint 1 a 2 10{sup -7} gramme de verre/cm{sup 2}/jour. Les pertes d'activite par volatilite au cours de la cuisson restent faibles et souvent inferieures a 0,1 pour cent de l'activite totale. L'epuration des gaz de cuisson est facilitee par la presence d'un filtre a granules riches en oxyde de fer, dont le contenu peut etre fondu apres saturation. Differentes techniques sont, en outre, en experimentation pour une production plus importante: Une installation de calcination et vitrification continue traite 72 litres par jour de solution contenant une activite traceur. La perte en Ru{sup 106} est encore importante

  8. Le MusVerre, Sars-Poteries, Hauts-de-France

    OpenAIRE

    Schmitt , Daniel

    2017-01-01

    Le MusVerre, inauguré en 2016, présente une collection patrimoniale et contemporaine d'art verrier. Le scénario de la visite propose un parcours en deux temps avec une séquence historique : de l’histoire des « bousillés » à la création du musée avec une galerie technique qui donne un aperçu des gestes de l’art verrier. Puis une séquence contemporaine développe un panorama des collections d’art verrier d’aujourd’hui, dans leur grande richesse et originalité.

  9. Le plafond de verre chez les enseignants chercheurs en sociologie et démographie

    OpenAIRE

    Chenu, Alain; Martin, Olivier

    2016-01-01

    La féminisation de l’enseignement supérieur français va croissante : la discipline « sociologie, démographie » illustre bien cette évolution puisqu’en 2012 44 % des enseignants-chercheurs en « sociologie, démographie » sont des femmes alors que ce taux ne s’élevait qu’à 24 % en 1984. Pourtant, cette féminisation croissante cache la persistance d’un plafond de verre. Cet article en montre l’existence et cherche à l’expliquer. À cet effet, la carrière des enseignants-chercheurs est analysée éta...

  10. Nature de la phase basse temperature des verres de spin Heisenberg en dimension 3

    OpenAIRE

    PETIT , Dorothée

    2002-01-01

    I. A Campbell (Directeur) D.R. Grempel F. Hippert (rapporteur) O. Martin P. Norblad (rapporteur) E. Vincent; La question de l'existence d'une réelle transition de phase entre l'état paramagnétique et l'état verre de spin est une question qui a été débattue pendant de nombreuses années. Il semble dorénavant admis que le gel des spins à basse température ne se fasse pas de façon progressive, et l'existence d'une véritable transition à T9. finie est communément acceptée, mais de nombreuses quest...

  11. Experiments on neutron-attenuation by ordinary concrete; Etude experimentale de l'attenuation des neutrons dans le beton ordinaire

    Energy Technology Data Exchange (ETDEWEB)

    Beauge, R; Millot, J P; Rastoin, J [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1959-07-01

    The penetration of fission-neutrons in water and glass mixtures has been investigated in the NAIADE facility. The slopes of the thermal and fast fluxes (the latter measured with a dosimeter) remain similar when the volume proportion of water is greater than 15 per cent. For smaller water-contents the measurements show the evidence of streaming, presumably due to slowing-down neutrons of energy smaller than 300 keV. Since a volume proportion of about 15 per cent of water in glass corresponds to the composition of ordinary concrete, the present work enables to predict the effects of a desiccation of concrete. Moreover, it is seen that there is no interest in increasing the proportion of water in ordinary concrete beyond the usual values (15-20 per cent). (author) [French] La propagation des neutrons de fission a ete etudiee dans les melanges verre-eau au moyen du dispositif NAIADE. La pente du flux thermique et la pente du flux rapide (obtenue au moyen d'un dosimetre) restent voisines lorsque la proportion d'eau dans le melange depasse 15 pour cent en volume. Pour des proportions d'eau inferieures les mesures mettent en evidence un 'streaming' de neutrons en ralentissement d'energie probablement inferieure a 300 keV. La composition des melanges verre-eau aux environs de 15 pour cent d'eau en volume correspondant au beton ordinaire, la presente etude permet de prevoir les effets d'une dessication du beton, et montre, en outre, qu'il n'y a pas interet a essayer d'augmenter la proportion d'eau dans le beton ordinaire au dela des valeurs usuelles (15 a 20 pour cent). (auteur)

  12. ETUDE DE LA DISTRIBUTION DES CATIONS ECHANGEABLES

    African Journals Online (AJOL)

    SEI Joseph

    été mené dans une serre en verre au département de Biologie (Université de ... taux de Na+ et K+, et fait l'analyse des paramètres physique et chimique du sol .... comportement de cette espèce : Atriplex. halimus vis-à-vis de cinq doses de ...

  13. Determination of the free enthalpies of formation of borosilicate glasses; Determination des enthalpies libres de formation des verres borosilicates. Application a l'etude de l'alteration des verres de confinement de dechets radioactifs

    Energy Technology Data Exchange (ETDEWEB)

    Linard, Y

    2000-07-01

    This work contributes to the study of the thermochemical properties of nuclear waste glasses. Results are used to discuss mechanisms and parameters integrated in alteration models of conditioning materials. Glass is a disordered material defined thermodynamically as a non-equilibrium state. Taking into account one order parameter to characterise its configurational state, the metastable equilibrium for the glass was considered and the main thermochemical properties were determined. Calorimetric techniques were used to measure heat capacities and formation enthalpies of borosilicate glasses (from 3 to 8 constitutive oxides). Formation Entropies were measured too, using the entropy theory of relaxation processes proposed by Adam and Gibbs (1965). The configurational entropy contribution were determined from viscosity measurements. This set of data has allowed the calculation of Gibb's free energies of dissolution of glasses in pure water. By comparison with leaching experiments, it has been demonstrated that the decreasing of the dissolution rate at high reaction progress cannot be associated to the approach of an equilibrium between the sound glass and the aqueous solution. The composition changes of the reaction area at the glass surface need to be considered too. To achieve a complete description of the thermodynamic stability, the equilibrium between hydrated de-alkalinized glass and/or the gel layer with the aqueous solution should also be evaluated. (author)

  14. Influence of nuclear glasses composition on their liability to deterioration; Influence de la composition des verres nucleaires sur leur alterabilite

    Energy Technology Data Exchange (ETDEWEB)

    Tovena, I

    1995-09-29

    This contributes to the study of the nuclear glasses composition influence on their liability to deterioration. The methodology of the experimental research used has lead to define between the thirty oxides which form the reference glass light water, six oxides of interest. For each of these oxides, a composition variation area has been defined. A matrix of twenty glass compositions has then been defined. The preparation of materials of these compositions has sometimes lead to materials weakly heterogeneous which have been characterized before deterioration. This study has been completed by those of three glasses in a composition variation area narrower of the light water nuclear glass : the R7T7 and two glasses at limits having respectively an initial dissolution velocity at 100 degrees Celsius theoretically maximum and minimum. Some deterioration parameters in pure water have been experimentally measured on the twenty three glasses : 1) an initial dissolution velocity at 100 degrees (Vo{sub 1}00) Celsius and another one at 90 degrees Celsius (Vo{sub 9}0) 2) a dissolution velocity in conditions near the saturation at 90 degrees Celsius 3) an apparent solubility of glass based on the ortho silicic acid activity 4) the evolution of the dissolution kinetics at 90 degrees Celsius in sub-saturated medium towards saturated medium 5) the alteration films nature developed at the glasses surface during these last alteration tests. Some thermodynamic and structural models have been studied in order to predict Vo{sub 9}0 and Vo{sub 1}00. The dissolution kinetic law developed from reference glass dissolution results has been studied with the calculation code LIXIVER. It has not been able to be used for most of the glasses compositions studied. As a consequence, the glasses dissolution control by a surface reaction which are itself controlled by the only dissolved silica is an hypothesis which is not verified for the greater part of the glasses. (O.L.). refs., figs., tabs.

  15. Contribution to the study of hydrogenated and oxygenated impurities in liquid sodium; Contribution a l'etude des impuretees hydrogenees et oxygenees dans le sodium liquide

    Energy Technology Data Exchange (ETDEWEB)

    Naud, G [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-07-15

    This study is made up essentially of two parts. The first is devoted to the development of dosage methods for selectively determining the oxygenated and hydrogenated impurities present in sodium, that is the oxide, the hydride and the hydroxide. The second makes use of these methods for a study of the Na-H{sub 2}-O{sub 2} system, as well as of the related problem of the attack of pyrex glass by molten sodium. The conventional method for dosing oxygen by amalgamation was first adapted to the simultaneous measurement of the hydride. We then developed a method for dosing the total hydrogen by measuring successively the concentrations of gas present in the hydride and hydroxide form. This method is based on the thermal decomposition of the hydride and the reaction between sodium and the hydroxide. Our contribution to the study of the Na-H{sub 2}-O{sub 2} System consists first of all in the study of the reaction between hydrogen and sodium in the temperature range from 150 to 250 deg C and at a pressure of about 150 mm of mercury. The study of the thermal decomposition of the hydride in sodium was then studied. It was possible to make some qualitative observations concerning the reaction between sodium and sodium hydroxide. Finally some complementary tests made it possible to define the nature of the phenomena occurring during the attack of pyrex glass by sodium. (author) [French] Cette etude comporte essentiellement deux parties. La premiere est consacree a la mise au point de methodes de dosages permettant de determiner selectivement les impuretes oxygenees et hydrogenees presentes dans le sodium, a savoir l'oxyde, l'hydrure et l'hydroxyde. La seconde met a profit ces methodes en vue de l'etude du systeme Na-H{sub 2}-O{sub 2}. ainsi que du phenomene connexe d'attaque du verre pyrex par le sodium fondu. La methode classique de dosage de l'oxygene par amalgamation a d'abord ete adaptee au dosage simultane de l'hydrure. Nous avons ensuite mis au point le dosage de l

  16. Mécanismes d'action des fines et des granulats de verre sur la réaction alcali-silice et la réaction pouzzolanique

    OpenAIRE

    Idir, Rachida

    2009-01-01

    Le recyclage du verre mixte contenant plusieurs couleurs pour la fabrication de nouveaux verres n'est actuellement pas économiquement viable. Ceci explique la recherche d'autres débouchés que le stockage ou l'enfouissement en décharges. L'une des applications envisageables est sa valorisation dans la fabrication des ciments et des bétons. Néanmoins, il est nécessaire de gérer les deux principaux comportements que peut avoir ce verre lorsqu'il est mis en contact avec une matrice cimentaire, à ...

  17. Criticality studies; Etudes de criticite

    Energy Technology Data Exchange (ETDEWEB)

    Breton, D; Lecorche, P; Clouet d' Orval, Ch [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-07-01

    Criticality studies made at the Commissariat a l'Energie atomique deal on the one hand with experiments on plutonium and uranium solutions, on the other hand with theoretical work on the development and use of computation, methods for the resolution of problems concerning the nuclear safety of chemical and metallurgical plants. I - Since 1958 the experimental studies have dealt with homogeneous media constituted by a fissile salt dissolved in light water. Developed using the reactor Proserpine, the experiments have been carried on at Saclay on the Alecto assemblies where solutions of plutonium or of 90 p.100 - enriched uranium can be made critical. The results already obtained relate to critical masses of cylindrical tanks of diameters from 20 to 50 cm. reflected in several ways (water, concrete, etc. . ) at concentrations up to 100 g/liter. Physical measurements (spectra, reactor noises) and interaction measurements complete the results. Other experiments relating to plutonium solutions were begun in 1963, at the Valduc Center. They deal with the study of critical masses of annular vessels of external diameter 50 cm and internal diameter varying from 10 to 30 cm. These vessels can be water reflected internally, externally, or both. Two of these vessels have been studied in interaction for various geometries. Slabs of various thicknesses were also studied. II - The studies thus undertaken allowed the development of methods of computation which have been tested on several experiments. Particular use has been made of the possibilities of calculations based on transport theory and on Monte Carlo methods. All these theoretical studies are applied to the design and control of industrial plants from the point of view of safety. (authors) [French] Les etudes de criticite effectuees au CEA comportent d'une part des experiences sur des solutions de plutonium et d'uranium enrichi, d'autre part des travaux theoriques portant sur la mise au point et l'exploitation de methodes

  18. Thermal stability of the French nuclear waste glass - long term behavior modeling; Etude de la stabilite thermique du verre nucleaire. Modelisation de son evolution a long terme

    Energy Technology Data Exchange (ETDEWEB)

    Orlhac, X

    2000-07-01

    The thermal stability of the French nuclear waste glass was investigated experimentally and by modeling to predict its long-term evolution at low temperature. The crystallization mechanisms were analyzed by studying devitrification in the supercooled liquid. Three main crystalline phases were characterized (CaMoO{sub 4}, CeCO{sub 2}, ZnCr{sub 2}O{sub 4}). Their crystallisation was TO 4.24 wt%, due to the low concentration of the constituent elements. The nucleation and growth curves showed that platinoid elements catalysed nucleation but did not affect growth, which was governed by volume diffusion. The criteria of classic nucleation theory were applied to determine the thermodynamic and diffusional activation energies. Viscosity measurements illustrate the analogy between the activation energy of viscous flow and diffusion, indicating control of crystallization by viscous flow phenomena. The combined action of nucleation and growth was assessed by TTT plots, revealing a crystallization equilibrium line that enables the crystallized fractions to be predicted over the long term. The authors show that hetero-genetics catalyze the transformation without modifying the maximum crystallized fraction. A kinetic model was developed to describe devitrification in the glass based on the nucleation and growth curves alone. The authors show that the low-temperature growth exhibits scale behavior (between time and temperature) similar to thermo-rheological simplicity. The analogy between the resulting activation energy and that of the viscosity was used to model growth on the basis of viscosity. After validation with a simplified (BaO{sub 2}SiO{sub 2}) glass, the model was applied to the containment glass. The result indicated that the glass remained completely vitreous after a cooling scenario with the one measured at the glass core. Under isothermal conditions, several million years would be required to reach the maximum theoretical crystallization fraction. (author)

  19. Platinoids and molybdenum in nuclear waste containment glasses: a structural study; Les platinoides et le molybdene dans des verres d'interet nucleaires: etude structurale

    Energy Technology Data Exchange (ETDEWEB)

    Le Grand, M. [CEA/VALRHO - site de Marcoule, Dept. de Recherche en Retraitement et en Vitrification (DRRV), 30 - Marcoule (France)]|[Paris-7 Univ., 75 (France)

    2000-07-01

    This work deals with the structure of borosilicate nuclear glasses and with some relationships between structure and macroscopic properties. Two types of elements which may disturb the industrial process - platinoids (Ru and Pd) and molybdenum - are central to this work. Platinoids induce weak modifications on the structure of the glass, causing a depolymerization of the glassy network, an increase of the {sup [3]}B/{sup [4]}B ratio and a modification of the medium range order around Si between 3.3 and 4.5 angstrom. The modifications of viscosity and density induced by platinoids in the glass are not due to the structural effect of the platinoids. The increase of viscosity is attributed to needle shaped RuO{sub 2}. It can be moderated by imposing reducing conditions during the elaboration of the glass. The slight difference between experimental and calculated densities is due to the increase of the volume percentage of bubbles in the glass with increasing platinoid content. Mo is either present in the glass as molybdic groupings, or mobilized in chemically complex molybdic crystalline phases. The chemical composition and mineralogy of these phases has been obtained using electronic microprobe data and XRD with Rietveld analysis. The distribution of the different elements between the crystalline phases and the glass is strongly influenced by the structural role of the various cations in the glass. The Mo present in the glass appears as MoO{sub 4} tetrahedra, independent of the borosilicate network. The formation of the crystalline phases can be explained by the existence of a precursor in which the MoO{sub 4} tetrahedra are concentrated in rich alkali and earth-alkali bearing areas of the glass. (author)

  20. Platinoids and molybdenum in nuclear waste containment glasses: a structural study; Les platinoides et le molybdene dans des verres d'interet nucleaires: etude structurale

    Energy Technology Data Exchange (ETDEWEB)

    Le Grand, M [CEA/VALRHO - site de Marcoule, Dept. de Recherche en Retraitement et en Vitrification (DRRV), 30 - Marcoule (France); [Paris-7 Univ., 75 (France)

    2000-07-01

    This work deals with the structure of borosilicate nuclear glasses and with some relationships between structure and macroscopic properties. Two types of elements which may disturb the industrial process - platinoids (Ru and Pd) and molybdenum - are central to this work. Platinoids induce weak modifications on the structure of the glass, causing a depolymerization of the glassy network, an increase of the {sup [3]}B/{sup [4]}B ratio and a modification of the medium range order around Si between 3.3 and 4.5 angstrom. The modifications of viscosity and density induced by platinoids in the glass are not due to the structural effect of the platinoids. The increase of viscosity is attributed to needle shaped RuO{sub 2}. It can be moderated by imposing reducing conditions during the elaboration of the glass. The slight difference between experimental and calculated densities is due to the increase of the volume percentage of bubbles in the glass with increasing platinoid content. Mo is either present in the glass as molybdic groupings, or mobilized in chemically complex molybdic crystalline phases. The chemical composition and mineralogy of these phases has been obtained using electronic microprobe data and XRD with Rietveld analysis. The distribution of the different elements between the crystalline phases and the glass is strongly influenced by the structural role of the various cations in the glass. The Mo present in the glass appears as MoO{sub 4} tetrahedra, independent of the borosilicate network. The formation of the crystalline phases can be explained by the existence of a precursor in which the MoO{sub 4} tetrahedra are concentrated in rich alkali and earth-alkali bearing areas of the glass. (author)

  1. Conséquences de l'apport de verre pilé à la surface du champ et de son incorporation dans la couche travaillée

    OpenAIRE

    de Louvigny, Nathalie

    2001-01-01

    Pour accroître le taux de recyclage du verre d'emballage, Eco-Emballage et BSN Glasspack ont recherché des débouchés alternatifs pour les 100 à 150.000 tonnes/an de calcin ? soit environ 5% du verre d'emballage - trop pollué pour être valorisé en verrerie. Pour estimer ce que seraient les conséquences de l'incorporation de verre au sol, les effets du verre sont mesurés dans les domaines chimiques biologiques et physiques au cours d'expérimentations au terrain et au laboratoire et les résultat...

  2. Long-term behavior of glass-ceramic zirconolite; Etude du comportement a long terme des vitrocristallins a base de zirconolite

    Energy Technology Data Exchange (ETDEWEB)

    Martin, Ch

    2003-07-01

    This work is a part of the investigation of new containment matrices considered for specific conditioning of radionuclides after separation. The aim was to demonstrate the long-term aqueous corrosion resistance of the glass-ceramic zirconolite considered for the conditioning of plutonium and the minor actinides. This material is composed of crystals of zirconolite (CaZrTi{sub 2}O{sub 7}) dispersed in a residual vitreous phase. It appears that glass-ceramic zirconolite presents a better kinetic behavior than the nuclear glass R 7T7. This is mainly due to a more important rate decrease that occurs more rapidly, that induces a quantity of glass altered at least 10 times as small as for R 7T7 glass. This high slowdown of the alteration rate is attributed to the formation of an alteration film that has been the subject of a specific study. We have demonstrated that the rate decrease was controlled as for the R7T7 glass by the amorphous phase of the alteration film forming a diffusion barrier for reactive species. It seems that the porosity is not the single parameter that explains the protective effect of the gel. The main differences compared with R7T7 glass are that silicon does not control the alteration of the material and that the gel is composed of two distinct phases. We have in particular identified a dense phase enriched in titanium and neodymium that probably influences deeply the kinetics. (author)

  3. Le moulage pour la reconstitution des lacunes en restauration de la céramique et du verre

    Directory of Open Access Journals (Sweden)

    Hélène Blanpain

    2012-06-01

    Full Text Available La technique de reconstitution des lacunes par moulage est très vaste. Elle présente une large gamme de produits et de procédés susceptibles d’être employés dans le domaine de la restauration de la céramique et du verre. Leur choix et leur bonne mise en œuvre dépendront de plusieurs facteurs comme la nature de l’élément à mouler, sa forme et la nature du matériau de comblement choisi.The technique of gap-filling by molding is very vast. It presents a wide range of products and processes than can be used in the field of the restoration of ceramic and glass objects. Their choice depends on several factors : the material of the object, its shape, and the choice of the filling product.

  4. Les adhésifs à photopolymérisation radicalaire employés pour le collage structural du verre en conservation-restauration.

    OpenAIRE

    Gillioz, Sandra

    2016-01-01

    Nous avons étudié la compatibilité des adhésifs photopolymérisables avec le collage du verre en conservation-restauration en nous focalisant sur leur résistance mécanique. Quatre adhésifs photopolymérisables à voie radicalaire ont été sélectionnés – Conloc® 665 (EGO®), Loctite® 350 (Henkel®), NOA® 61 (Norland Optical Adhesives®) et Verifix® LV740 (Bohle®) – en employant à titre de comparaison la résine époxyde de référence pour le collage structural du verre – Hxtal® Nyl-1 (Hxtal Adhesive®). ...

  5. Effet de la nature des ions alcalins et alcalino-terreux sur la structure d'un verre riche en terre

    OpenAIRE

    Quintas , Arnaud; Lenoir , Marion; Caurant , D.; Majérus , Odile; Dussossoy , Jean-Luc; Charpentier , Thibault; Neuville , Daniel R.; Gervais , Christel

    2006-01-01

    Dans le cadre d'une étude structurale d'un verre de confinement de déchets nucléaires de type aluminoborosilicate et riche en terres rares, l'influence de la nature des ions alcalins ou alcalino-terreux est analysée. Pour cela deux séries de verres ont été élaborées dans lesquelles l'ion Na+ (respectivement l'ion Ca2+) présent dans la composition de référence, est totalement substitué par un autre ion alcalin Li+, K+, Rb+ ou Cs+ (respectivement un autre ion alcalino-terreux Mg2+, Sr2+ ou Ba2+...

  6. Variation de la composition de nanoparticules de 1-10 nm obtenues par séparation de phase dans un verre de silice

    OpenAIRE

    Blanc , W; Francois-Saint-Cyr , H; Martin , I; Lecoustumer , P; Hombourger , C; R. Neuville , D.; Larson , D.J.; Prosa , T.J.; Guillermier , C

    2014-01-01

    National audience; Les verres contenant des nanoparticules ont de nombreuses applications industrielles, notamment grâce à leurs excellentes propriétés thermo-mécaniques [1]. Ils présentent aussi un intérêt pour les propriétés optiques. En effet, l'encapsulation d'ions luminescents (ions de terre rare par exemple) dans des nanoparticules entraînent de nouvelles propriétés de luminescence qui n'existeraient pas dans le verre hôte (bande d'émission élargie, efficacité quantique augmentée, etc) ...

  7. High-sensitivity gamma spectroscopy for extended sources. Application to activity measurements on the human body, on glass, and on soil; Spectrographie gamma a grande sensibilite pour sources etendues. Application a la mesure de l'activite du corps humain, du verre et du sol

    Energy Technology Data Exchange (ETDEWEB)

    Jouve, B

    1962-07-01

    The measurement and location by gamma spectroscopy of human body internal contaminations at maximum permissible levels, and, in certain cases, at lower activities such as that due to {sup 40}K was investigated. The characteristics of the high-sensitivity apparatus used are given, and several assemblies using large-volume NaI(Tl) scintillators are described. The relatively light shielding required for natural radioactivity permitted construction of mobile assembly. Conditions of use are described, and the results are given. All gamma emitting elements were measured in 15 min at levels lower than the tolerance dose. Gamma spectroscopy was also used to determine fission products in the earth and to study radioactive elements in the presence of other emitters. (author) [French] La spectrographie gamma du corps humain permet la mesure et la localisation des contaminations internes au niveau des doses de tolerance et, dans certains cas, celle d'activites plus faibles comme la radioactivite naturelle due principalement au potassium 40. Les caracteristiques des appareils a grande sensibilite permettant ces mesures sont exposees et on decrit plusieurs realisations originales utilisant un scintillateur NaI(Tl) de grand volume. L'epaisseur du blindage a ete limitee a 5 cm de plomb, ainsi, pour une protection suffisante contre les rayonnements ambiants, les appareils sont relativement legers et l'une des realisations a pu etre installee dans un laboratoire mobile. Les conditions d'utilisation (mouvement propre, etalonnage) et les resultats obtenus sont donnes; tous les radioelements emetteurs gamma sont mesurables en 15 minutes a un niveau inferieur a la dose de tolerance. On presente enfin des applications a la spectrographie gamma d'echantillons volumineux (poudres ou liquides) et de tres faible activite: elles interessent des domaines tres varies comme, par exemple, la geophysique (etude des retombees radioactives) ou l'industrie chimique (dosage du potassium dans les

  8. High-sensitivity gamma spectroscopy for extended sources. Application to activity measurements on the human body, on glass, and on soil; Spectrographie gamma a grande sensibilite pour sources etendues. Application a la mesure de l'activite du corps humain, du verre et du sol

    Energy Technology Data Exchange (ETDEWEB)

    Jouve, B

    1962-07-01

    The measurement and location by gamma spectroscopy of human body internal contaminations at maximum permissible levels, and, in certain cases, at lower activities such as that due to {sup 40}K was investigated. The characteristics of the high-sensitivity apparatus used are given, and several assemblies using large-volume NaI(Tl) scintillators are described. The relatively light shielding required for natural radioactivity permitted construction of mobile assembly. Conditions of use are described, and the results are given. All gamma emitting elements were measured in 15 min at levels lower than the tolerance dose. Gamma spectroscopy was also used to determine fission products in the earth and to study radioactive elements in the presence of other emitters. (author) [French] La spectrographie gamma du corps humain permet la mesure et la localisation des contaminations internes au niveau des doses de tolerance et, dans certains cas, celle d'activites plus faibles comme la radioactivite naturelle due principalement au potassium 40. Les caracteristiques des appareils a grande sensibilite permettant ces mesures sont exposees et on decrit plusieurs realisations originales utilisant un scintillateur NaI(Tl) de grand volume. L'epaisseur du blindage a ete limitee a 5 cm de plomb, ainsi, pour une protection suffisante contre les rayonnements ambiants, les appareils sont relativement legers et l'une des realisations a pu etre installee dans un laboratoire mobile. Les conditions d'utilisation (mouvement propre, etalonnage) et les resultats obtenus sont donnes; tous les radioelements emetteurs gamma sont mesurables en 15 minutes a un niveau inferieur a la dose de tolerance. On presente enfin des applications a la spectrographie gamma d'echantillons volumineux (poudres ou liquides) et de tres faible activite: elles interessent des domaines tres varies comme, par exemple, la geophysique (etude des retombees radioactives) ou l'industrie chimique

  9. ETUDE - European Trade Union Distance Education.

    Science.gov (United States)

    Creanor, Linda; Walker, Steve

    2000-01-01

    Describes transnational distance learning activities among European trade union educators carried out as part of the European Trade Union Distance Education (ETUDE) project, supported by the European Commission. Highlights include the context of international trade union distance education; tutor training course; tutors' experiences; and…

  10. Instrumental performance of an etude after three methods of practice.

    Science.gov (United States)

    Vanden Ark, S

    1997-12-01

    For 80 fifth-grade students three practice conditions (mental, mental with physical simulation, and physical with singing) produced significant mean differences in instrumental performance of an etude. No significant differences were found for traditional, physical practice.

  11. Fixation of Radioactive Waste in Glass. Part II. The Experimental Evaluation of Phosphate and Borosilicate Glasses; Fixation des Dechets Radioactifs dans le Verre, Deuxieme Partie: Evaluation Experimentale des Verres au Phosphate et au Borosilicate; 0424 0418 041a 0421 0410 0426 0418 042f 0420 0410 0414 0418 041e 0410 041a 0422 0418 0412 041d 042b 0425 041e 0422 0425 041e 0414 041e 0412 0412 0421 0422 0415 041a 041b 0415 . 0427 0410 0421 0422 042c Ii. 042d 041a 0421 041f 0415 0420 0418 041c 0415 041d 0422 0410 041b 042c 041d 0410 042f 041e 0426 0415 041d 041a 0410 041a 0410 0427 0415 0421 0422 0412 0424 041e 0421 0424 0410 0422 041d 042b 0425 0418 0411 041e 0420 041e 0421 0418 041b 0418 041a 0410 0422 041d 042b 0425 0421 0422 0415 041a 041e 041b ; Fijacion de Desechos Radiactivos en Vidrio, Parte II: Evaluacion Experimental de los Vidrios al Fosfato y al Borosilicato

    Energy Technology Data Exchange (ETDEWEB)

    Elliot, M. N.; Grover, J. R.; Hardwick, W. H. [Atomic Energy Research Establishment, Harwell (United Kingdom)

    1963-02-15

    A glass suitable for long-term storage of fission-product wastes must be chosen firstly with regard to the method of storage, and secondly with regard to reliability of manufacture in a highly radioactive plant. The factors that are relevant to storage include leach resistance, thermal and radiation stability and die percentage of waste that can be incorporated, while the physical and chemical nature of glass-forming additives together with the melting point and viscosity of the glass relate to the manufacturing process. The relative importance of these factors is discussed. Experimental studies of the borosilicate glasses that have been chosen for pilot-plant work are described, including the effect of radiation doses of up to 10{sup 12}rad on their physical and chemical properties. Glasses of other kinds have also been examined and their potential value as storage media is compared with the borosilicate glasses. (author) [French] Un verre convenant au.stockage de longue duree des dechets de produits de fission doitetre choisi: premierement, en fonction de la methode de stockage et deuxiemement, eu egard a la securite des operations de traitement dans une usine de haute activite. En ce qui concerne le stockage, les facteurs importants sont la resistance a la corrosion, la stabilite thermique, la stabilite vis a-vis des rayonnements et le pourcentage de dechets pouvant etre incorpores. Au point de vue de la securite des manutentions, il faut tenir compte de la nature physique et chimique des elements intervenant dans la composition du verre, du point de fusion et de la viscosite du verre. Les auteurs examinent l'importance relative de ces facteurs. Ils decrivent les etudes experimentales faites sur les verres au borosilicate choisis pour l'usine pilote, de meme que l'influence des rayonnements sur leurs proprietes chimiques et physiques pour des doses allant jusqu'a 10{sup 12} rad. Ils ont etudie d'autres especes de verre et examine la possibilite de les employer

  12. Irradiations effects on the structure of boro-silicated glasses: long term behaviour of nuclear waste glassy matrices; Effets d'irradiations sur la structure de verres borosilicates - comportement a long terme des matrices vitreuses de stockage des dechets nucleaires

    Energy Technology Data Exchange (ETDEWEB)

    Bonfils, J. de

    2007-09-15

    This work deals with the long term behaviour of R7T7-type nuclear waste glasses and more particularly of non-active boro-silicated glasses made up of 3 or 5 oxides. Radioactivity of active glasses is simulated by multi energies ions implantations which reproduce the same defects. The damages due to the alpha particles are simulated by helium ions implantations and those corresponding to the recoil nucleus are obtained with gold ions ones. Minor actinides, stemming from the used fuel, is simulated by trivalent rare-earths (Eu{sup 3+} and Nd{sup 3+}). In a first part, we have shown by macroscopic experiments (Vickers hardness - swelling) and optical spectroscopies (Raman - ATR-IR) that the structure of the glassy matrices is modified under implantations until a dose of 2,3.10{sup 13} at.cm{sup -2}, which corresponds to a R7T7 storage time estimated at 300 years. Beyond this dose, no additional modifications have been observed. The second part concerns the local environment of the rare-earth ions in glasses. Two different environments were found and identified as follows: one is a silicate rich one and the other is attributed to a borate rich one. (author)

  13. Un verre de trop

    Directory of Open Access Journals (Sweden)

    Pascal Brissette

    2009-09-01

    Full Text Available Au nombre des mythes qui accompagnent la formation de la modernité littéraire, on compte celui de la bohème, qui témoigne, comme Nathalie Heinich l’a bien montré dans L’Élite artiste, des difficultés que les producteurs symboliques éprouvent à conjuguer les critères de la singularité et du travail en communauté. La théâtralité de la « vie de bohème », son excentricité, ses tics et son chic sont au fondement de regroupements d’écrivains qui défendent paradoxalement le caractère vocationnel de ...

  14. PENULISAN ETUDE-ETUDE MUSIK TALEMPONG UNGGAN (Sebuah Usaha Pembelajaran Musik Tradisi Berbasis Literatur

    Directory of Open Access Journals (Sweden)

    Asri MK

    2014-12-01

    Full Text Available “Talempong unggan”, a traditional music from Minangkabau community particularly in Unggan, Sumpur Kudus, Sijunjung Regency, West Sumatera Indonesia is classified into genre of “talempong duduak” (rea. Due to its special musical concept and the playing technics, this traditional music is selected as a practising course in the Karawitan Department of Indonesian Institute of Art (ISI Padang Panjang since 1993 till now. In a system of class learning with many students, Talempong Unggan definitely needs supporting methods and learning technics suitable for the course where the students can reach their maximum skills. All the melody of “talempong unggan” that has been made as a material of practice is transcribed to the system of numeric notation and rhythm motive of “gendang” and “aguang” which is written into signs and special notation. All of qualitative data is formulated into finding methods, technics and etude of learning ensamble of Talempong Unggan the traditional music that learned in Karawitan Department of ISI Padang Panjang. Key words: Talempong Unggan, Methods, Technics, Etude

  15. Etude expérimentale et analyse probabiliste du comportement à la ...

    African Journals Online (AJOL)

    DK

    en traction de composites verre-perlon-acrylique à usage orthopédique. Experimental ... du comportement à la rupture de ces stratifiés ainsi que l'aspect probabiliste de cette dernière sont décrits .... signification physique qui donne au volume.

  16. Study of the performances of acoustic emission testing for glass fibre reinforced plastic pipes containing defects; Etude des performances du controle par emission acoustique de tubes en materiaux composites resine-fibre de verre contenant des defauts

    Energy Technology Data Exchange (ETDEWEB)

    Villard, D.; Vidal, M.C.

    1995-08-01

    Glass fibre reinforced plastic pipes are more and more often used, in nuclear power plants, for building or replacement of water pipings classified `nuclear safety`. Tests have been performed to evaluate the performances of acoustic emission testing for in service inspection of these components. The tests were focused on glass fibre reinforced polyester and vinyl-ester pipes, in as received conditions or containing impacts, and intentionally introduced defects. They have been carried out by CETIM, following the ASTM Standard E 1118 (code CARP), to a maximum pressure lever of 25 Bar The results show that the CARP procedure can be used for detection of defects and evaluation of their noxiousness towards internal pressure: most of the tubes containing low energy impacts could not be distinguished from tubes without defect; on the other hand the important noxiousness of lacks of impregnation of roving layer appeared clearly. Complementary tests have been performed on some tubes at a more important pressure lever, for which the damage of the tubes in enough to deteriorate there elastic properties. The results showed that CARP procedure give valuable informations on damage level. It would be interesting to evaluate acoustic emission on tubes containing realistic in-service degradations. (author). 11 refs., 15 figs., 6 tabs., 2 appends.

  17. Structural and crystallisation study of a rare earth alumino borosilicate glass designed for nuclear waste confinement; Etude de la structure et du comportement en cristallisation d'un verre nucleaire d'aluminoborosilicate de terre rare

    Energy Technology Data Exchange (ETDEWEB)

    Quintas, A

    2007-09-15

    This work is devoted to the study of a rare earth alumino borosilicate glass, which molar composition is 61,81 SiO{sub 2} - 3,05 Al{sub 2}O{sub 3} - 8,94 B{sub 2}O{sub 3} - 14,41 Na{sub 2}O - 6,33 CaO - 1,90 ZrO{sub 2} - 3,56 Nd{sub 2}O{sub 3}, and envisaged for the immobilization of nuclear wastes originating from the reprocessing of high discharge burn up spent fuel. From a structural viewpoint, we investigated the role of the modifier cations on the arrangement of the glass network through different modifications of the glass composition: variation of the Na/Ca ratio and modification of the nature of the alkali and alkaline earth cations. The NMR and Raman spectroscopic techniques were useful to determine the distribution of modifier cations among the glass network and also to cast light on the competition phenomena occurring between alkali and alkaline earth cations for charge compensation of [AlO{sub 4}]{sup -} and [BO{sub 4}]{sup -} species. The neodymium local environment could be probed by optical absorption and EXAFS spectroscopies which enabled to better understand the insertion mode of Nd{sup 3+} ions among the silicate domains of the glass network. Concerning the crystallization behavior we were interested in how the glass composition may influence the crystallization processes and especially the formation of the apatite phase of composition Ca{sub 2}Nd{sub 8}(SiO{sub 4}){sub 6}O{sub 2}. In particular, this work underlined the important role of both alkaline earth and rare earth cations on the crystallization of the apatite phase. (author)

  18. Self-defects and self diffusion in a silica glass: a first-principles study; Etude ab-initio des auto-defauts et des mecanismes d'auto-diffusion dans un verre de silice

    Energy Technology Data Exchange (ETDEWEB)

    Martin, L.; Colomer, S

    2004-11-15

    SiO{sub 2} and silica based compounds are key materials in a variety of scientific and technological fields as, for instance, in microelectronics or nuclear technology. In all these fields, one of the still open questions is their long term aging in a radioactive environment. Due to the complexity of the effects of radiations upon matter, the understanding of the long term aging needs the knowledge of diffusion mechanisms at the atomic scale. In that context, numerical modelling appears as a way to access this scale. We present a first principles study on self-defects and self-diffusion in a silica model. As expected, at variance with SiO{sub 2} crystalline phases, the defects formation energies are distributed, due to the non-equivalence of defects sites. We prove that the formation energy dispersion is correlated to the local stress. Concerning the equilibrium concentrations and oxygen diffusion mechanism, we discuss how the shape of the distribution, as well as impurity levels within the gap, play a main role in the dominance of defect types. Finally we present the main oxygen diffusion mechanism in homogeneous and heterogeneous defect formation regime. (author)

  19. Structure and properties of rare earth-rich glassed for nuclear waste immobilisation; Etude des caracteristiques structurales et des proprietes de verres riches en terres rares destines au confinement des produits de fission et elements a vie longue

    Energy Technology Data Exchange (ETDEWEB)

    Bardez, I

    2004-11-15

    A new nuclear glass composition, able to immobilize highly radioactive liquid wastes from high burn-up UO{sub 2} fuel, was established and its structure studied. The composition of the selected rare earth-rich glass is (molar %): 61.79 SiO{sub 2} - 8.94 B{sub 2}O{sub 3} - 3.05 Al{sub 2}O{sub 3} - 14.41 Na{sub 2}O - 6.32 CaO - 1.89 ZrO{sub 2} - 3.60 RE{sub 2}O{sub 3} (with RE = La, Ce, Pr and Nd). The aim of this study was to determine the local environment of the rare earth in this glass and also to glean information about the effect of glass composition on the rare earth neighbouring (influence of Si, B, Al, Na and Ca contents). To this end, several series of glasses, prepared from the baseline glass, were studied by different characterisation methods such as EXAFS spectroscopy at the neodymium LIII-edge, optical absorption spectroscopy, Raman spectroscopy and {sup 29}Si, {sup 27}Al and {sup 11}B MAS-NMR. By coupling all the results obtained, several hypotheses about the nature of the rare earth neighbouring in the glass were proposed. (author)

  20. Etude des caractéristiques structurales et des propriétés de verres riches en terres rares destinés au confinement des produits de fission et éléments à vie longue

    OpenAIRE

    Bardez , Isabelle

    2004-01-01

    Une nouvelle matrice vitreuse riche en terres rares, capable d'incorporer les déchets issus du retraitement de combustibles nucléaires UOX à hauts taux de combustion (60 GWj/t, à comparer à 33 GWj/t pour le combustible de référence actuel) a été mise au point et étudiée au niveau structural. Sa composition molaire simplifiée est la suivante : 61 ,79 SiO2 - 8,94 B2O3 - 3,05 Al2O3 - 14,41 Na2O - 6,32 CaO - 1,89 ZrO2 - 3,60 TR2O3 (avec TR = La, Ce, Pr et Nd) En particulier, l'environnement local...

  1. Modélisation d'un choc thermique doux d'un verre S.S.C en utilisant l'approche thermomécanique

    Science.gov (United States)

    Malou, Z.; Hamidouche, M.; Madjoubi, M. A.; Bousbaa, C.; Bouaouadja, N.

    2005-05-01

    Dans ce travail, nous avons étudié l'endommagement du verre silico-sodo-calcique (trois différentes épaisseurs : 2mm, 4mm, et 8mm) par choc thermique descendant. Nous avons utilisé l'approche thermomécanique en terme de facteur d'intensité de contrainte en se basant sur un calcul numérique. Le choc thermique descendant, est la mise en contact brutal d'un échantillon, préalablement chauffé à une température Ti, avec un milieu dont la température Tf est inférieure à Ti. Le gradient thermique engendré induit des contraintes de tension dans les couches superficielles du corps. Ces contraintes peuvent conduire à la rupture du matériau. Les hypothèses prises en compte lors de la simulation sont comme suit : Le refroidissement des échantillons en verre chauffés à différentes températures, inférieures à sa température de transition, est fait par jet d'air à 20° C pendant 6 secondes. Ce temps est suffisant pour que la température des échantillons atteigne l'ambiante. Le coefficient de transfert de chaleur est de 600 W/°C.m2. Les températures chaudes ont été variées entre 100° C et 450° C. Lors des calculs, nous avons intégré, l'évolutions en fonction de la température des propriétés thermoélastiques du verre. Dans un premier temps, nous avons déterminé les températures et les contraintes transitoires dans l'échantillon à tout instant du choc thermique. Ensuite, nous avons déterminé l'évolution du facteur d'intensité de contrainte (FIC) durant le refroidissement. Enfin, les FIC calculés sont comparés à la ténacité (K1c) du matériau. Cette dernière a été mesurée en utilisant la mécanique linéaire de la rupture. Nous avons vérifié que quand le facteur FIC atteint la valeur de la ténacité dans la zone des défauts critiques, ces derniers se propagent d'une manière brutale causant ainsi la dégradation de l'échantillon. Par cette technique, nous avons directement accès à l'écart de température critique

  2. Implementing Formative Assessment in Engineering Education: The Use of the Online Assessment System Etude

    Science.gov (United States)

    Dopper, Sofia M.; Sjoer, Ellen

    2004-01-01

    This article describes the possibilities offered by the online assessment system Etude to achieve the benefits of formative assessment. In order to find out the way this works in practice, we carried out an experiment with the use of Etude for formative assessment in the course on collaborative report writing. Results show that online formative…

  3. Study of various processes for marking sediments with gold-198; Etude de divers procedes de marquages de sediments par l'or 198

    Energy Technology Data Exchange (ETDEWEB)

    Jeanneau, B [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1967-12-15

    The use of radioactive isotopes for the study of sediment deposits is based mainly on two methods: marking in the mass - a glass of an element which can be activated replaces the sediment; surface marking - a physico-chemical process is used to deposit a radio-element at the surface of the sediment. The second process is used in particular for sands when it is advantageous to have a large number of particles for statistical analysis. The aim of this work was to develop a rapid and simple method of marking which could be applied on the actual site of the experiment where equipment, may be limited. The method recommended for marking sand with gold-198 is a combination of the Petersen (treatment with tin chloride) and Campbell (treatment with silver) methods combined with prior treatments with nitric acid and caustic soda. Using this method it is possible to deposit 125 mg of gold per kilo of sediment with a yield of 95 per cent (i.e. 10 Ci/kg) using a hydrochloric acid solution containing gold. The problem of the solidity of the deposits, of their value and of their reproducibility is discussed from the point of view of the mineral constitution of the sand. (author) [French] L'utilisation d'isotopes radioactifs pour l'etude des deplacements sedimentaires fait, principalement appel a deux methodes: le marquage massique - un verre contenant un element activable remplace le sediment; le marquage superficiel - un traitement physico-chimique permet de deposer un radioelement a la surface du sediment. Le second procede est surtout employe pour les sables lorsqu'il est utile de disposer d'un grand nombre de grains pour des raisons statistiques. Le but de ce travail etait de mettre au point une methode simple et rapide de marquage pouvant etre appliquee sur le site meme de l'experience pour les utilisateurs disposant d'un equipement limite. Le procede preconise pour le marquage des sables par l'or 198 est une combinaison des methodes Petersen (traitement au chlorure d

  4. Évaluation des caractéristiques mécaniques du polissoir en polyuréthanne utilisé comme porte abrasifs durant le processus du polissage du verre optique

    Science.gov (United States)

    Aliouane, T.; Bouzid, D.; Belkhir, N.; Bouzid, S.; Herold, V.

    2005-05-01

    La fabrication des composants en verre optique nécessite des moyens de grande précision dans les procédés de finition vue l'importance accordée à leur qualité.
Durant le processus de polissage des verres optiques, le polissoir est un élément clé et a un impact direct sur les performances des composants optiques, non seulement il est utilisé comme support de grains abrasifs mais il doit posséder la fonction de transmission de la pression aux grains. La connaissance de ses propriétés, essentiellement mécanique, est impérative afin d'obtenir un état de surface optimal des composants optiques destinés à remplir des fonctions très précises dans des appareils optiques très performants.
Dans cette étude, nous avons constaté que les propriétés des polissoirs en polyuréthanne tel que la dureté, le module d'élasticité et la densité varient au cours du polissage. Ce changement a des effets sur l'état de surface de verre optique, causé par le changement microstructural de la surface du polissoir (distribution et dimensions des pores) et par conséquent sur la quantité des abrasifs (en oxyde de cérium) insérée dans les pores, ce qui influe sur la quantité de verre enlevée et sur l'état de surface du composant.
Sur la base des résultats obtenus, il a été prouvé que le polissoir subit des modifications très importantes ce qui influe considérablement sur son efficacité de polissage.

  5. Experiments on the incorporation of concentrated solutions of fission products in glasses and micas; Essais d'incorporation de solutions concentrees de produits de fission dans des verres et des micas

    Energy Technology Data Exchange (ETDEWEB)

    Bonniaud, R; Cohen, P; Sombret, C [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1958-07-01

    1) The plants designed for extracting the plutonium of the G1, G2, G3 reactors fuel rods will produce extremely concentrated tions of fission products. 2) Let us consider a synthetic solution of the 'G2' type: (2N NO{sub 3}H - 2,25 meq/cm{sup 3} AI{sup +++} - 5.10{sup -3} {sup 134}Cs - {sup 137}Cs tracer). We made various glasses and micas by adding and mixing the necessary adjuvants and baking (900 to 1400 deg. C) in a graphite crucible. 3) The products obtained had either the shape of a cylindrical pellet or were reduced into a fine powder. They were mixed with 300 cm{sup 3} of synthetic sea water during variable periods of time in order to study leaching of the activity. 4) Experiments were first carried on caesium because of its solubility. 5) Fabrication of micas on a large scale sets many technological problems more difficult to solve (1400 deg. C) than in the case of glasses (1000 deg. C). A comparative study on both micas and glasses showed that leaching of activity was more important in the micas. (author)Fren. [French] 1) La mise en service de l'Usine d'Extraction du Plutonium destinee en particulier au traitement des barres de combustibles de G1, G2, G3 fournira des solutions residuaires concentrees de produits de fission. 2) Partant d'une solution synthetique 'G2': (2N NO{sub 3}H - 2,25meq/cm{sup 3} AI{sup +++} - 5.10{sup -3} {sup 134}Cs - {sup 137}Cs traceur) nous avens realise differents verres et micas apres adduction et melange des adjuvants necessaires suivis de cuisson (900 a 1400 deg. C) dans un creuset de graphite. 3) Les produits obtenus ont ete, soit sous forme d'eprouvette cylindrique, soit sous forme de poudre finement broyee, mis en contact et agites avec 300 cm{sup 3} d'eau de mer synthetique, durant des temps varies pour etudier la retention de l'activite. 4) Le cesium a ete choisi pour ces essais a cause de sa solubilite. 5) La fabrication de micas a grande echelle pose des problemes technologiques plus difficiles (1400 deg. C) a

  6. 98 Etude Comparative du Systeme Phonematique et Tonal des ...

    African Journals Online (AJOL)

    98. Etude Comparative du Systeme Phonematique et Tonal des. Deux Parlers: Le Yoruba du Nigeria et L'itsa Parle en. Republique du Benin. Ajani Akinwumi Lateef et Ayuba G. Ajibabi http://dx.doi./org/10.4314/ujah.v18i3.5. Résume. En ce début de l'époque ou la mondialisation et la coexistence des peuples dans le ...

  7. Nuclear study of Melusine; Etude nucleaire de Melusine

    Energy Technology Data Exchange (ETDEWEB)

    Cherot, J [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1959-07-01

    In this report are reviewed - with respect to starting of experiments - the main nuclear characteristics of a 20 per cent enriched uranium lattice, with light water as moderator and reflector. The reactor is to operate at 1 MW. 1) Study of various critical masses. 2) Control. Effectiveness of cadmium. Control rods and of a stainless steel regulating rod. 3) Study of the effect on reactivity of disturbances in the core center. 4) Study of xenon and samarium poisoning. 5) Temperature factor. 6) Heat exchanges in a fuel element. (author) [French] On etudie, dans ce rapport, les principales proprietes nucleaires d'un reseau a uranium enrichi (20 pour cent), dont le moderateur et le reflecteur sont l'eau legere en vue des experiences de demarrage. Ce reacteur devra fonctionner a 1 MW. 1) Etude de diverses masses critiques. 2) Controle. Efficacite des barres de controle en cadmium et d'une barre de reglage en acier inoxydable. 3) Etude de l'effet sur la reactivite de perturbation au centre du coeur. 4) Etude de l'empoisonnement xenon et samarium. 5) Coefficient de temperature. 6) Echanges thermiques dans un element. (auteur)

  8. L’utilisation d’adhésifs optiques réticulables aux UV pour le collage d’objets d’art en verre transparent coloré, à surface d’encollage réduite

    Directory of Open Access Journals (Sweden)

    Viviane Bechoux

    2011-11-01

    Full Text Available La recherche porte sur une double problématique :1° La possibilité d’utiliser les adhésifs réticulables aux UV  pour coller le verre transparent coloré. 2° Le collage du verre  s’avère très complexe quand les éléments à assembler sont fins, fragiles et quand la surface d’encollage est réduite à quelques millimètres.Dans ce cas précis, la solidité mécanique du collage et la rapidité de polymérisation de l’adhésif sont les premiers critères à prendre en compte pour assurer un assemblage final fiable.This research focuses on two issues : 1° The possibility to use UV-crosslinkable adhesives to bond transparent coloured glass.2° The glass bonding is very complex when the parts to be joined are thin, fragile, and when the bonding surface is reduced to a few millimetres in size. In this case, the mechanical strength of the bonding and the speed of the curing process of the adhesive are the first criteria to be taken into account to ensure a reliable final bonding.

  9. Ultimate Disposal of High-Level Radioactive Wastes - Fixation in Phosphate Glass with Emphasis on the Continuous Mode of Plant Operation; Elimination Definitive de Dechets de Haute Activite - Fixation dans du Verre au Phosphate en Vue d'une Exploitation de l'Installation en Continu; ОКОНЧАТЕЛЬНОЕ УДАЛЕНИЕ ВЫСОКОАКТИВНЫХ ОТХОДОВ - ФИКСАЦИЯ В ФОСФАТНОМ СТЕКЛЕ НА НЕПРЕРЫВНО РАБОТАПЦЕЙ УСТАНОВКЕ; Evacuacion Definitiva de Desechos de Elevada Radiactividad. Fijacion en Vidrio al Fosfato Atendiendo Particularmente a la Continuidad de la Marcha de la Instalacion

    Energy Technology Data Exchange (ETDEWEB)

    Hatch, L. P.; Weth, G. C.; Tuthill, E. J. [Brookhaven National Laboratory, Upton, Long Island, NY (United States)

    1963-02-15

    In the study of ultimate disposal of high-level radioactive wastes at Brookhaven National Laboratory emphasis is being placed on the formation of phosphate glasses as a means of incorporating the fission products in stable media. Of primary interest here is the development of a process in which the entire conversion from the raw aqueous wastes to the final.glass product would be carried out in an all-liquid system. The phosphate-glass method offers a number of important advantages in this respect and, in particular, lends itself to the development of a continuous process in which the liquid medium would be readily transferable from one process step to another. The paper presents the results of bench-scale studies on the production of phosphate glasses, with the continuous mode of operation, utilizing various types of aqueous wastes. The studies have been in progress for some 20 months and were carried out to determine essential operating parameters with particular attention paid to corrosion resistance and physical integrity of the high-temperature crucible. In addition, the paper discusses flow-sheet development together with the design and results of operation of. an engineering-scale plant having a capacity of 0.5 ft{sup 3} of glass per day with a continuous feed of simulated non-radioactive wastes. (author) [French] Dans l'etude des methodes d'elimination definitive des dechets de haute activite, le Laboratoire national de Brookhaven attache une grande importance aux verres au phosphate pour la fixation des produits de fission dans un milieu stable. On s'efforce essentiellement de mettre au point un processus dans lequel la transformation, depuis le dechet liquide et l'etat brut jusqu'au produit vitreux final, s'opererait entierement en phase liquide. A cet egard, le verre au phosphate presente un grand nombre d'avantages importants; en particulier, il se prete a la mise au point d'un processus continu dans lequel le milieu liquide pourrait facilement passer d

  10. Influence des défauts de la structure du verre sur la résistance mécanique des fibres optiques

    Science.gov (United States)

    Chmel, A.; Baptizmanski, V. V.; Kharshak, A. A.

    1992-12-01

    For silica (pure and doped) optical fibers prepared from preforms irradiated by thermal neutrons and Ar^+ ions, the measurements of lifetime under transverse stress were carried out. It is found that the neutron bombardment leads to decrease of the lifetime and the strength of fiber while the ion implantation results in increasing of these parameters. The influence of particle irradiation on the glass strength is explained by the generation of structural defects which were observed by the infrared an Raman spectroscopy methods. The direction of the change of mechanical properties of fibers is determined by the type of defects and their distribution in the cross-section of fiber. Des préformes de fibres optiques de silice ont été exposées à un bombardement par des faisceaux de neutrons thermiques et d'ions Ar^+ à énergie de 40 keV afin d'engendrer des défauts de la structure respectivement dans le volume ou dans la couche superficielle des échantillons. Les fibres obtenues des préformes irradiées et non irradiées ont été mises en charge de flexion. On a déterminé leur temps de rupture sous diverses contraintes de traction sur la surface extérieure de la fibre en flexion. On a observé une diminution du temps de rupture des fibres après le bombardement neutronique et une augmentation après l'implantation ionique. L'analyse de la nature des défauts en faisant appel à la spectroscopie infrarouge et Raman a fait ressortir que l'irradiation aux ions entraînait essentiellement des liaisons chimiques dans une fine couche superficielle de l'échantillon alors que l'irradiation aux neutrons occasionnait une déformation des zones du réseau silicique dans toute la section de la préforme et de la fibre. L'amélioration de la résistance mécanique s'explique par une augmentation de la mobilité des éléments structuraux de la matrice de verre par suite d'une rupture partielle des liaisons chimiques et sa diminution par l'apparition de concentrateurs

  11. The development of a cell-assembly for the treatment of irradiated fuels on a semi-industrial scale; Etude concernant la realisation d'un ensemble de cellules destinees a des traitements de combustibles irradies a l'echelle semi-industrielle

    Energy Technology Data Exchange (ETDEWEB)

    Faugeras, P; Couture, J; Lefort, G [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1961-07-01

    The main studies and experiments involved in the development of a cell-assembly for the treatment of irradiated fuels on a semi-industrial scale are described. It must be possible to modify or transform each of these cells without interrupting the rest of the pilot. A full-scale prototype cell (3 x 4 x 6 m) has been built with an {alpha}-protection independent of the {gamma}-protection. It features all the main characteristics: tightness to {gamma} losses, dense glass lighting, ventilation. This cell has made possible trials on transfer, remote-controls and tele-dismantling, as well as the development of new methods of rapidly connecting hydraulic circuits. In conclusion the final form is given of the cells selected for the pilot. (author) [French] Il est decrit les principales etudes et experiences faites en vue de la realisation d'un ensemble de cellules destinees a des traitements de combustibles irradies a l'echelle semi-industrielle. Chacune de ces cellules doit pouvoir etre modifiee ou transformee sans interrompre le reste du pilote. Une cellule prototype vraie grandeur (3x4x6 m) est construite avec une protection {alpha} independante de la protection {gamma}. Elle comporte tous les elements importants: porte {gamma} etanche, eclairage verre dense, ventilation. Cette cellule a permis des experiences de transferts de telemanipulateurs et de teledemontages, ainsi que la mise au point de nouveaux procedes de jonction rapide pour des circuits hydrauliques. En conclusion, on indique la forme definitive des cellules retenues pour le pilote. (auteur)

  12. Le verre à vitre et l’archéologie de la fin de l’Antiquité au XIIe siècle. Premières approches et perspectives

    Directory of Open Access Journals (Sweden)

    Christian Sapin

    2007-08-01

    Full Text Available Le vitrail a longtemps été considéré comme représentatif du plein Moyen Âge (XIe-XIIe siècle au plus tôt. Si quelques textes historiques impliquaient l’existence de vitrail à l’époque mérovingienne, la rareté des verres plats archéologiques, datés, ne permettait pas d’écrire avec précision une histoire du vitrail.Cette histoire est depuis quelques années revisitée par les sources archéologiques, aussi ténues puissent-elles paraître. La révolution la plus importante est, dans les années 1960,...

  13. Génération d'onde stokes du second ordre et effet laser dans une fibre optique a cœur suspendu en verre de chalcogénure AsSe

    OpenAIRE

    Hey Tow , Kenny; Besnard , Pascal; Brilland , Laurent; Toupin , Périne; Troles , Johann; Méchin , David; Trégoat , Denis

    2011-01-01

    National audience; Une étude expérimentale sur les propriétés de la rétrodiffusion Brillouin stimulée dans une fibre optique à cœur suspendu en verre de chalcogénure AsSe est présentée. Avec seulement un mètre de fibre, nous générons suffisamment de gain Brillouin pour obtenir un laser à fibre monomode de type Fabry-Perot. Nous démontrons aussi la génération du second ordre Brillouin dans ces fibres avec 0,5 W de pompe.

  14. Caractérisation expérimentale et modélisation numérique des propriétés spectroscopiques d'absorbants saturables pour le déclenchement passif de laser verre erbium

    Science.gov (United States)

    Girard, S.; Shcherbitsky, V.; Fromager, M.; Aït Ameur, K.; Moncorgé, R.; Ferrand, B.; Montagne, J.

    2002-06-01

    Une comparaison entre différents absorbants saturables (LMA, MALO, ZnS et ZnSe dopés Col^+ et ZnSe dopé Cr^{2+}) utilisables comme interrupteur optique passif pour déclencher les sources lasers verre erbium à 1.53 μm est présentée. Des expériences de saturation en simple passage sont interprétées en tenant compte de la distribution spatiale et temporelle du laser de pompe. Cette technique permet d'obtenir des sections efficaces de saturation effectives fiables et indépendantes des conditions de mesure sans introduire artificiellement d'absorption dans l'état excité qui, en principe, n'existe pas dans ce type de système contrairement aux études effectuées jusqu'ici sur ces matériaux.

  15. Contribution to the study of the mechanism of crack in amorphous silica: study by the molecular dynamics of crack in amorphous silica; Contribution a l'etude des mecanismes de rupture dans les amorphes: etude par dynamique moleculaire de la rupture de verre de silice

    Energy Technology Data Exchange (ETDEWEB)

    Van Brutzel, L

    2000-07-01

    The aim of this thesis was to understand the mechanism which occurs during the crack at the atomic scale in amorphous silica. The difficulties of the experimental observations at this length scale lead us to use numerical studies by molecular dynamics to access to the dynamical and the thermodynamical informations. We have carried out large simulations with 500000 atoms and studied the structure of the amorphous silica before to studying their behaviours under an imposed strain. The structure of this simulated amorphous silica settled in three length scales. In small length scale between 0 and 5 angstrom glass is composed of tetrahedra, this is close to the crystalline structure. In intermediate length scale between 3 and 10 angstrom tetrahedra are connected together and build rings of different sizes composed in majority between 5 and 7 tetrahedra. In bigger length scale between 15 and 60 angstrom, areas with high density of rings are surrounded by areas with low density of rings. These structural considerations play an important role in initiation and propagation of a crack. Indeed. in this length scale. crack propagates by growth and coalescence of some small cavities which appear in area with low density of rings behind the crack tip. The cavities dissipate the stress with carries away a delay to propagation of the crack. This phenomenons seems ductile and leads to non linear elastic behaviour near the crack tip. We have also shown that the addition of alkali in the amorphous silica changes the structure by creation of nano-porosities and leads to enhance the ductility during the crack propagation. (author)

  16. Treatment of effluent at the Saclay Centre d'Etudes Nucleaires (1960); Le traitement des effluents du Centre d'Etudes Nucleaires de Saclay (1960)

    Energy Technology Data Exchange (ETDEWEB)

    Wormser, G [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1960-07-01

    The Centre d'Etudes Nucleaires at Saclay possesses several installations from which liquid radioactive effluent is rejected, and it has thus been found necessary to construct a station for the purification of radioactive liquids and to settle various chemical, analytical and technological problems. This report describes, in the following order: - the disposal possibilities at the Centre d'Etudes Nucleaires, Saclay, - the effluents produced at the centre, - the set-up for collecting effluent, - treatment of the effluent, - results of these treatments. (author) [French] La presence, au Centre d'Etudes Nucleaires de Saclay, de plusieurs installations susceptibles de rejeter des effluents liquides radioactifs a necessite la construction d'une station d'epuration d'eaux radioactives et la mise au point de differents problemes chimiques, analytiques et technologiques. Dans ce rapport, nous exposerons successivement: - les possibilites de rejet du Centre d'Etudes Nucleaires de Saclay, - les effluents du centre, - le dispositif de collecte des effluents, - le traitement de ces effluents, - les resultats de ces traitements. (auteur)

  17. Nederlands pensioenstelsel verre van af

    NARCIS (Netherlands)

    Boot, A.

    2008-01-01

    Het Nederlandse pensioenstelsel wordt verblijd met een nieuw type pensioeninstelling, de API (Algemene Pensioeninstelling). In optimale vrijheid moet deze kunnen functioneren met een toezichtregime dat aansluit op zowel dat van verzekeraars als dat van pensioenfondsen. Het pensioenstelsel is daarmee

  18. Etudes sur le Portugal au Temps de l'Humanisme

    Directory of Open Access Journals (Sweden)

    J. Cruz Costa

    1953-06-01

    Full Text Available BATAILLON (Marcel. — Etudes sur le Portugal au Temps de l'Humanisme.  Acta Universitatis Conimbrigencis, 1952, 309 pp. (Primeiro Parágrafo do Artigo O Prof. Marcel Bataillon, erudito dos mais inteligentes da França atual, autor de uma obra que é hoje impr:scindível para quem pretenda estudar o humanismo renascentista na Espanha ou em Portugal, diríamos melhor, talvez: para quem pretenda estudar o Humanismo e a Renascença, — acaba de publicar, na coleção Acta Universitatis Conimbrigencis, êste volume no qual reune alguns trabalhos da mais alta importância para o conhecimento de muitos aspectos da vida espiritual portuguêsa do século XVI.

  19. (Alpha, gamma) irradiation effect on the alteration of high-level radioactive wastes matrices (UO{sub 2}, hollandite, glass SON68); Effet de l'irradiation (alpha, gamma) sur l'alteration des matrices de dechets nucleaires de hautes activites (UO{sub 2}, hollandite, verre SON68)

    Energy Technology Data Exchange (ETDEWEB)

    Suzuki, T

    2007-06-15

    The aim of this work is to determine the effect of irradiation on the alteration of high level nuclear waste forms matrices. The matrices investigated are UO{sub 2} to simulate the spent fuel, the hollandite for the specific conditioning of Cs, and the inactive glass SON68 representing the nuclear glass R7T7) The alpha irradiation experiments on UO{sub 2} colloids in aqueous carbonate media have enabled to distinguish between the oxidation of UO{sub 2} matrix as initial and dissolution as subsequent step. The simultaneous presence of carbonate and H{sub 2}O{sub 2} (product resulting from water radiolysis) increased the dissolution rate of UO{sub 2} to its maximum value governed by the oxidation rate. ii) The study of hollandite alteration under gamma irradiation confirmed the good retention capacity for Cs and Ba. Gamma irradiation had brought only a little influence on releasing of Cs and Ba in solution. Electronic irradiation had conducted to the amorphization of the hollandite only for a dose 1000 times higher than the auto-induced dose of Ba over millions of years. iii) The experiences of glass irradiation under alpha beam and of helium implantation in the glass SON68 were analyzed by positon annihilation spectroscopy. No effect has been observed on the solid surface for an irradiation dose equal to 1000 years of storage. (author)

  20. Contribution to the study of several chemical hazards in the Centre d'Etudes Nucleaires of Fontenay-aux-Roses; Contribution a l'etude de quelques nuisances chimiques au centre d'etudes nucleaires de Fontenay-aux-Roses

    Energy Technology Data Exchange (ETDEWEB)

    Megemont, C; Grau, C [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1968-10-01

    From the checking of 2750 index cards of hazards, the study relates the distribution of the chemical hazards in the Centre d'Etudes Nucleaires of Fontenay-aux-Roses. Those concerning the greatest number of agents in the Centre are classified according to the categories corresponding to the different conditions of working. Thus, the most important are put forward. Then, the authors rapidly make a review of hazards which may have some special interest because they appear more specific of the nuclear energy or because they are the most frequently noted on the index cards of hazards. The case of the tributylphosphate is studied more precisely. (authors) [French] A partir de l'examen de 2750 fiches de nuisances, l'etude porte sur la repartition des nuisances chimiques au Centre d'Etudes Nucleaires de Fontenay-aux-Roses. Celles qui concernent le plus grand nombre d'agents du Centre sont classees selon les categories correspondant aux differentes conditions de travail. Les plus importantes d'entre elles sont ainsi mises en evidence. | Les auteurs passent ensuite en revue, rapidement, les nuisances qui peuvent presenter un interet particulier soit parce qu'elles semblent plus specifiques de l'Energie Nucleaire, soit parce qu'on les rencontre le plus frequemment sur les fiches de nuisances. Le cas du tributylphosphate est envisage de facon plus detaillee. (auteurs)

  1. Etude de la qualité physico-chimique et biologique des eaux du ...

    African Journals Online (AJOL)

    Etude de la qualité physico-chimique et biologique des eaux du fleuve Niger à Niamey. ... le récepteur principal des rejets d'eaux usées de la ville de Niamey, capital du ... La description de ces taxons montre une variation de la structure des ...

  2. English Department Reforms at the Hautes Etudes Commerciales: Entering the Nineties.

    Science.gov (United States)

    Shanahan, Daniel

    1993-01-01

    Discusses the reforms made in the fall of 1990 in the English department at the Ecole Hautes Etudes Commerciales (Paris, France), which were based on the basis of a combination of literature-culture and second- and foreign-language acquisition pedagogical biases. (four references) (VWL)

  3. Contribution a l'etude des plantes alimentaires mineures dans la ...

    African Journals Online (AJOL)

    Contribution a l'etude des plantes alimentaires mineures dans la prefecture de Dankpen (Togo). AB Kebenzikato, S Akpavi, K Batawila, K Wala, M Dourma, K Kossi-Titrikou, KS Amouzou, I Butare, H Dantsey-Barry, K Akpagana ...

  4. 152 Etude de cas sur l'impact des amendements organiques vis-à ...

    African Journals Online (AJOL)

    john mukalay

    Etude de cas sur l'impact des amendements organiques vis-à-vis de la salinité en culture de bananier. Michel Mazinga KWEY1, Séverin Kalala BANZE2 et John Banza MUKALAY2*. 1Laboratoire des cultures in vitro, Département de phytotechnie, Faculté des sciences agronomiques,. Université de Lubumbashi, BP 1825, ...

  5. 186 Etude théorique du transport électronique par la simulation ...

    African Journals Online (AJOL)

    youness

    Choukria SAYAH et al. 186. Etude théorique du ... For that we carried out the microscopic simulations, based on the Monte. Carlo method. ... intervalles, piezoelectric as well as the interactions of alloy and on ionized impurities. ..... SAYA et al. 198. [5] - R. W. Hockney, J. W. Eastwood, "Computer simulation using particles",.

  6. Etude comparative de la flore aux abords des cours d'eau dans les ...

    African Journals Online (AJOL)

    Etude comparative de la flore aux abords des cours d'eau dans les zones hypo et hyper endémiques d'ulcère de Buruli en Côte d'Ivoire. C. Cisse Boni, E. Ehouman, D. Soro, M.W. Kone, A. Bakayoko, F. Dembele, K. Bauthire, M Dosso ...

  7. Alecto 2 - interaction studies; Alecto 2 - etudes d'interaction

    Energy Technology Data Exchange (ETDEWEB)

    Brunet, J P; Clouet d' Orval, Ch; Mougniot, J C; Penet, F [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1965-07-01

    Weak interactions were experimentally studies with the tank of the critical assembly Alecto II and one, two or three bottles containing solutions of various concentrations. In particular, was studied the validity of certain classical assumptions, shielding effects, screening and semi-reflexion effects, importance of thermal coupling. The method of the 'k{sub eff}, solid angle' is shown to apply to such a system. The determination by divergence and pulsed neutron technique of the reactivity related to a millimeter of solution level affords the obtention of critical heights in terms of reactivity. (authors) [French] Une etude experimentale d'interactions faibles a ete faite entre la cuve de l'experience critique ALECTO II et une, deux ou trois bouteilles contenant des concentrations variees. On etudie, en particulier, la validite de certaines hypotheses classiques, effets d'ombre, d'ecrans, de semi-reflexion, importance du couplage thermique. On montre d'autre part que la methode du 'K{sub eff}, angle solide' peut s'appliquer a un tel systeme. La determination par divergence et neutrons pulses de la reactivite liee au millimetre de solution permet de traduire les hauteurs critiques obtenues, en terme de reactivite. (auteurs)

  8. Baby fission chambers; Etude de chambres a fission miniatures

    Energy Technology Data Exchange (ETDEWEB)

    Guery, U; Tachon, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1957-07-01

    The present report is intended, on the one band, as a study of the main types of fission chambers produced to date, and on the other, to deal more generally with this type of detector. Originally, it was with a view to the charting of neutron scatter in 'Proserpine' that the authors undertook the study of these chambers. During the course of the task, it was considered worth tbe trouble of developing its scope to include a more general application: neutron scatter measurement of various energy neutrons within a reduced volume with slight local disturbance. (author) [French] Le present rapport se propose, d'une part, d'exposer les principales realisations de chambres a fission, d'autre part de faire une mise au point a caractere plus general sur ces detecteurs. Au depart, c'est surtout en vue des mesures de densite neutronique dans 'Proserpine' que les auteurs ont etudie ces chambres; au cours de la mise au point, il a paru interessant de developper leur etude pour des applications plus generales: mesures de densites de neutrons de differentes energies dans un element de volume tres reduit et avec faible perturbation locale. (auteur)

  9. SEPA (Service d'etudes, de Procedes et Analyses)

    International Nuclear Information System (INIS)

    2017-01-01

    The SEPA (Service d'etudes, de Procedes et Analyses), is an engineering department specializing in the analysis and processing of uranium ore. It comes from a long tradition of mining in France that began sixty-five years ago with the French Atomic Energy Commission (CEA) and that has been carried on by COGEMA and then Areva. SEPA brings a combination of experience and excellence to its activities thanks to its multidisciplinary staff (mineralogists, chemists, mechanical engineers, instrumentation specialists...), who come from diverse cultural backgrounds. Today, the SEPA draws on its wealth of know-how and expertise to devise and develop new methods for processing and valorizing ores everywhere in the world. Its mission is to: - Develop and conduct laboratory tests on methods for processing uranium and other valuable elements such as molybdenum, vanadium, rare earths, niobium, tantalum and thorium; - Analyze ores obtained during prospecting at locations all over the world; -Serve as an advisor in the commissioning of Areva industrial units and ore processing plants; -Perform environmental analyses during the full period of mining operations; -Conduct audits and provide advice on processes and analysis methods; -Carry out research and development in all aspects of minerals treatment (including the filing of patents). The SEPA combines experience, skills and a global approach to technologies used in ore processing. Its role is to continually improve the processes for extracting, processing and valorizing ores while protecting the environment

  10. Baby fission chambers; Etude de chambres a fission miniatures

    Energy Technology Data Exchange (ETDEWEB)

    Guery, U.; Tachon, J. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1957-07-01

    The present report is intended, on the one band, as a study of the main types of fission chambers produced to date, and on the other, to deal more generally with this type of detector. Originally, it was with a view to the charting of neutron scatter in 'Proserpine' that the authors undertook the study of these chambers. During the course of the task, it was considered worth tbe trouble of developing its scope to include a more general application: neutron scatter measurement of various energy neutrons within a reduced volume with slight local disturbance. (author) [French] Le present rapport se propose, d'une part, d'exposer les principales realisations de chambres a fission, d'autre part de faire une mise au point a caractere plus general sur ces detecteurs. Au depart, c'est surtout en vue des mesures de densite neutronique dans 'Proserpine' que les auteurs ont etudie ces chambres; au cours de la mise au point, il a paru interessant de developper leur etude pour des applications plus generales: mesures de densites de neutrons de differentes energies dans un element de volume tres reduit et avec faible perturbation locale. (auteur)

  11. Etude aerodynamique d'un jet turbulent impactant une paroi concave

    Science.gov (United States)

    LeBlanc, Benoit

    Etant donne la demande croissante de temperatures elevees dans des chambres de combustion de systemes de propulsions en aerospatiale (turbomoteurs, moteur a reaction, etc.), l'interet dans le refroidissement par jets impactant s'est vu croitre. Le refroidissement des aubes de turbine permet une augmentation de temperature de combustion, ce qui se traduit en une augmentation de l'efficacite de combustion et donc une meilleure economie de carburant. Le transfert de chaleur dans les au bages est influence par les aspects aerodynamiques du refroidissement a jet, particulierement dans le cas d'ecoulements turbulents. Un manque de comprehension de l'aerodynamique a l'interieur de ces espaces confinees peut mener a des changements de transfert thermique qui sont inattendus, ce qui augmente le risque de fluage. Il est donc d'interet pour l'industrie aerospatiale et l'academie de poursuivre la recherche dans l'aerodynamique des jets turbulents impactant les parois courbes. Les jets impactant les surfaces courbes ont deja fait l'objet de nombreuses etudes. Par contre des conditions oscillatoires observees en laboratoire se sont averees difficiles a reproduire en numerique, puisque les structures d'ecoulements impactants des parois concaves sont fortement dependantes de la turbulence et des effets instationnaires. Une etude experimentale fut realisee a l'institut PPRIME a l'Universite de Poitiers afin d'observer le phenomene d'oscillation dans le jet. Une serie d'essais ont verifie les conditions d'ecoulement laminaires et turbulentes, toutefois le cout des essais experimentaux a seulement permis d'avoir un apercu du phenomene global. Une deuxieme serie d'essais fut realisee numeriquement a l'Universite de Moncton avec l'outil OpenFOAM pour des conditions d'ecoulement laminaire et bidimensionnel. Cette etude a donc comme but de poursuivre l'enquete de l'aerodynamique oscillatoire des jets impactant des parois courbes, mais pour un regime d'ecoulement transitoire, turbulent

  12. Contribution to the analytic study of ferrates; Contribution a l'etude analytique des ferrates

    Energy Technology Data Exchange (ETDEWEB)

    Becarud, N [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1965-06-01

    Preparation and chemical properties of potassium, strontium and barium ferrates are described. Separation by glass-paper chromatography, electrochemical studies and infrared spectra are shown. A polarographic determination of ferrate ion have been worked. The stability of these compounds is studied with differential thermal analysis. (author) [French] Ce travail concerne la preparation de divers ferrates ainsi que la recherche de leurs proprietes chimiques. On a etudie les moyens specifiques de les detecter, leur chromatographie sur papier a fibre de verre et leurs proprietes electrochimiques. Une methode de dosage polarographique des ferrates est decrite. Les spectres d'absorption infra-rouge sont fournis. Enfin on a etudie leur decomposition par analyse thermique differentielle. (auteur)

  13. Nucléation et cristallisation dans un verre de chalcogénure du syste`me As sbnd Ge sbnd Se en présence d'un agent nucléant

    Science.gov (United States)

    Hemeda, D.; Tilloca, G.

    1988-05-01

    Le phénome`ne de nucléation initiépar un agent nucléant (HfSe) dans le verre de chalcogénure As 10 Ge 30Se 60 aétéétudiépar microscopieélectronique. La nucléation se caractérise par une période de latence dont la variation suit la solution analytique proposée par Kaschiev. Plusieurs parame`tres ontétéévalués: σ, l'énergie interfaciale; A, le facteur pré-exponentiel de l'équation générale de nucléation; ΔG D, la barrie`re cinétique de nucléation. Les résultats ontétéanalysés par la méthode basée sur les données de la viscositéet l'équation générale de nucléation. Une hypothe`se sur le mécanisme de la nucléation fondée sur l'action de l'agent nucléant aétéenvisagée. Les résultats relatifs au phénome`ne de croissance indiquent que la variation du taux de croissance réduit est analoguea`celle de matériaux ayant une entropie de fusionélevée et pour lesquels le mécanisme de croissance est régi par une nucléation de surface. L'énergie d'activation de croissance calculée est différente de la valeur estimée pour le verre non nucléédans le cas de l'écoulement visqueux. Une hypothe`se aétéenvisagée pour expliquer cetécart. L'évolution avec le temps de traitement thermique de la fraction cristallisée dans les matériaux aétésuivie par la technique de diffraction X quantitative. On observe une variation de type sigmoi¨dale avec une période de latence pour les différentes températuresétudiées. La cinétique de cristallisation suit l'équation de Johnson-Mehl-Avrami. La variation du taux de réaction avec la température est décrite par une expression de type Arrhénius.

  14. The Permanent Disposal of Highly Radioactive Wastes by Incorporation into Glass; Elimination Permanente de Dechets Hautement Radioactifs par Incorporation dans le Verre; 041e 041a 041e 041d 0427 0414 ; La Evacuacion Permanente de Desechos de Elevada Radiactividad Incorporandolos en Vidrio

    Energy Technology Data Exchange (ETDEWEB)

    Watson, L. C.; Aikin, A. M.; Bancroft, A. I. [Atomic Energy of Canada Ltd. (Canada)

    1960-07-01

    Development of a process for the incorporation of the high-level wastes from chemical processing operations into glass for permanent disposal has continued at Chalk River. The process has been demonstrated by making glass containing up to 50 curies of five- to six-year old mixed fission products per kg. The operation was batch wise, on a scale of four kg per batch. These operations showed that the fission products could be incorporated into glass safely and conveniently. Consideration of the many problems involved in the permanent storage or disposal of the highly radioactive glass has resulted in the conclusion that it should be buried in the ground or stored in artificial vaults. In such conditions, the disposal may always be-subjected to further control if required. If disposal is made directly to the ground, the principal method by which fission products can be released to the environment is by leaching from the glass into water. It is therefore considered important to know the rate at which fission products will be dispersed by this mechanism. Considerable data on leaching by water have been obtained in the laboratory. It has been found that the rates of release depend on the composition of the glass. For all the compositions tested the measurements showed that the rate of leaching of fission products from the glass decreased with time. After several months in water the rate of release of several compositions was about 10{sup -4} per cent per year from a two kg hemisphere of glass. The data obtained have been used to estimate the release of fission products from glass containing the large quantities of fission products which will accumulate from operation of power reactors. (author) [French] On poursuit a Chalk River les travaux de mise au point d'un procede permettant d'incorporer dans le verre, pour elimination permanente, des dechets hautement radioactifs provenant d'operations de traitement chimique! Aux fins de demonstration du procede, on a fabrique du

  15. Magnetic resonance studies of solid polymers; Etude des polymeres solides par resonance magnetique

    Energy Technology Data Exchange (ETDEWEB)

    Lenk, R [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1969-07-01

    This paper is a review of the application of nuclear magnetic resonance (NMR) to solid polymers. In the first, theoretical part, the elements of the theory of NMR, which are necessary for the study of the properties of solid polymers are discussed: the moments method, nuclear relaxation and the distribution of correlation times. In the second part the experimental results are presented. (author) [French] Cette etude est une recherche bibliographique sur l'application de la resonance magnetique nucleaire (RMN) aux polymeres solides. Dans la premiere partie theorique on discute les elements de la theorie de RMN, necessaires pour l'etude des proprietes des polymeres solides: la methode des moments, la relaxation nucleaire et la distribution des temps de correlation. La deuxieme partie presente les resultats des experiences. (auteur)

  16. ELABORATION ET ETUDE DES MATERIAUX CHALCOPYRITES AIBIIIC2 IV : LE DISELINURE DE CUIVRE ET D’INDIUM

    Directory of Open Access Journals (Sweden)

    S MEHDAOUI

    2007-06-01

    par évaporation sur des substrats en verre présentent des coefficients d’absorption ( élevées de l’ordre de 5.104 cm-1. Le tracé de la fonction (h2 des couches minces recuites sous vide à différentes températures en fonction de l’énergie des photons incident a mis en relief la nature directe de la transition fondamentale est a permis également de calculer le gap Eg = 1.04 eV.

  17. Singing as a Therapeutic Agent, inThe Etude, 1891-1949.

    Science.gov (United States)

    Hunter

    1999-01-01

    The Etude music magazine, founded by Theodore Presser, was one of a number of popular music magazines published in the years prior to the establishment of the music therapy profession in 1950. During its publication run from 1883 to 1957, over 100 music therapy related articles appeared, including 13 on the health benefits of singing published between 1891 and 1949. Written by authors with diverse backgrounds, such as the famous Battle Creek, Michigan physician John Harvey Kellogg and Boston music critic Louis C. Elson, the articles contained consistent and adamant support regarding the health benefits of singing. The advantages described were both physical and psychological, and were recommended prophylactically for well persons and therapeutically for ill persons. Although the articles varied in perspective, from philosophical to theoretical to pedagogical, there is a consistent holistic medicine theme that appeared almost ahead of its time and no doubt linked to the push for vocal music education in that era. The importance of The Etude in promulgating ideas that helped shape the early practice of music therapy should not be underestimated. For much of its publication run The Etude was the largest music periodical in print, reaching its peak circulation of 250,000 copies per month in 1924.

  18. Thermal and hydrodynamic study of a whirling liquid hydrogen layer under high heat flux; Etude thermique et hydrodynamique d'une couche tourbillonnaire d'hydrogenen liquide sous flux de chaleur eleve

    Energy Technology Data Exchange (ETDEWEB)

    Ewald, R. [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1968-03-01

    In order to achieve a cold neutrons source ({lambda} {>=} 4.10{sup -10} m) in a high flux reactor ({approx} 10{sup 15} neutrons/cm{sup 2}.s), a whirling liquid hydrogen layer (145 mm OD, effective thickness 15 mm, height about 180 mm) was formed, out-of-pile, in a cylindrical transparent glass vessel. The whirling motion was obtained by tangential injection of the liquid, near the wall. Thermal and hydrodynamical conditions of formation and laws of similarity of such a layer were studied. The characteristics of this whirling flow were observed as a function of mass flow rate (5 to 27 g/s; 4.3 to 23 l/mn), and of spillway width (18 and 25 mm). Six different nozzles were used : 1.0; 1.5; 1.9; 2.25; 2.65 and 3.0 mm ID. The total heat influx was found between 8.6 and 10.4 kW. The heat flux density was about 9.4 W/cm{sup 2} and the mean layer density around 80 per cent of that of the liquid hydrogen at 20.4 Kelvin. High speed movies were used to analyze the boiling regime. (author) [French] En vue de realiser une source de neutrons froids ({lambda} {>=} 4.10{sup -10} m) dans un reacteur a haut flux ({approx} 10{sup 15} neutrons thermiques/cm{sup 2}.s), on a forme dans un vase cylindrique transparent en verre, hors-pile, une couche tourbillonnaire ('vortex') d'hydrogene liquide (diametre exterieur 145 mm, epaisseur effective 15 mm, hauteur 180 mm environ). Le mouvement giratoire est obtenu par injection tangentielle du liquide pres de la paroi. L'etude porte sur la determination des conditions thermiques et hydrodynamiques de la formation d'une telle couche et sur les regles de similitude de ce phenomene. On a observe les caracteristiques de l'ecoulement giratoire en fonction du debit (de 5 a 27 g/s, soit de 4.3 a 23 1/mn), de la vitesse d'injection (entre 10 et 110 m/s) et de la largeur du deversoir (18 et 25 mm), ceci pour six diametres differents d'injecteur (1.0 ; 1.5; 1.9; 2.25; 2.65 et 3.0 mm). Le flux de chaleur total mesure

  19. Thermal and hydrodynamic study of a whirling liquid hydrogen layer under high heat flux; Etude thermique et hydrodynamique d'une couche tourbillonnaire d'hydrogenen liquide sous flux de chaleur eleve

    Energy Technology Data Exchange (ETDEWEB)

    Ewald, R [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1968-03-01

    In order to achieve a cold neutrons source ({lambda} {>=} 4.10{sup -10} m) in a high flux reactor ({approx} 10{sup 15} neutrons/cm{sup 2}.s), a whirling liquid hydrogen layer (145 mm OD, effective thickness 15 mm, height about 180 mm) was formed, out-of-pile, in a cylindrical transparent glass vessel. The whirling motion was obtained by tangential injection of the liquid, near the wall. Thermal and hydrodynamical conditions of formation and laws of similarity of such a layer were studied. The characteristics of this whirling flow were observed as a function of mass flow rate (5 to 27 g/s; 4.3 to 23 l/mn), and of spillway width (18 and 25 mm). Six different nozzles were used : 1.0; 1.5; 1.9; 2.25; 2.65 and 3.0 mm ID. The total heat influx was found between 8.6 and 10.4 kW. The heat flux density was about 9.4 W/cm{sup 2} and the mean layer density around 80 per cent of that of the liquid hydrogen at 20.4 Kelvin. High speed movies were used to analyze the boiling regime. (author) [French] En vue de realiser une source de neutrons froids ({lambda} {>=} 4.10{sup -10} m) dans un reacteur a haut flux ({approx} 10{sup 15} neutrons thermiques/cm{sup 2}.s), on a forme dans un vase cylindrique transparent en verre, hors-pile, une couche tourbillonnaire ('vortex') d'hydrogene liquide (diametre exterieur 145 mm, epaisseur effective 15 mm, hauteur 180 mm environ). Le mouvement giratoire est obtenu par injection tangentielle du liquide pres de la paroi. L'etude porte sur la determination des conditions thermiques et hydrodynamiques de la formation d'une telle couche et sur les regles de similitude de ce phenomene. On a observe les caracteristiques de l'ecoulement giratoire en fonction du debit (de 5 a 27 g/s, soit de 4.3 a 23 1/mn), de la vitesse d'injection (entre 10 et 110 m/s) et de la largeur du deversoir (18 et 25 mm), ceci pour six diametres differents d'injecteur (1.0 ; 1.5; 1.9; 2.25; 2.65 et 3.0 mm). Le flux de chaleur total mesure est compris entre 8.6 et 10.4 kW et la

  20. Structure study and properties of rare earth-rich glassed for the conditioning of nuclear waste; Etude des caracteristiques structurales et des proprietes de verres riches en terres rares destines au confinement des produits de fission et elements a vie longue

    Energy Technology Data Exchange (ETDEWEB)

    Bardez, I

    2004-11-15

    A new nuclear glass composition, able to immobilize highly radioactive liquid wastes from high burn-up UO{sub 2} fuel, was established and its structure studied. The composition of the selected rare earth-rich glass is (molar %): 61.79 SiO{sub 2} - 8.94 B{sub 2}O{sub 3} - 3.05 Al{sub 2}O{sub 3} - 14.41 Na{sub 2}O - 6.32 CaO - 1.89 ZrO{sub 2} - 3.60 RE{sub 2}O{sub 3} (with RE = La, Ce, Pr and Nd) The aim of this study was to determine the local environment of the rare earth in this glass and also to glean information about the effect of glass composition on the rare earth neighbouring (influence of Si, B, Al, Na and Ca contents). To this end, several series of glasses, prepared from the baseline glass, were studied by different characterisation methods such as EXAFS spectroscopy at the neodymium L{sub III}-edge, optical absorption spectroscopy, Raman spectroscopy and {sup 29}Si, {sup 27}Al and {sup 11}B MAS-NMR. By coupling all the results obtained, several hypotheses about the nature of the rare earth neighbouring in the glass were proposed. (author)

  1. Etude de l'impact de la variation de la température sur les activités ...

    African Journals Online (AJOL)

    Etude de l'impact de la variation de la température sur les activités microbiennes : application à une population de Listeria monocytogenes CIP 7831, Listeria monocytogenes Scott A CIP 103575 et Escherichia coli ATCC 25922.

  2. Bio-metric study of pig karyotype; Etude biometrique du caryotype du porc

    Energy Technology Data Exchange (ETDEWEB)

    Haag, J; Lacourly, N; Nizza, P [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1969-07-01

    This study has a twofold purpose, the former is to determine the swine karyotype as accurately as possible, the latter is to try and develop a method of automatic classification and to show its possibilities and limits. (authors) [French] Cette etude a un double objet: d'une part, de definir de la facon aussi precise que possible le caryotype du porc et d'autre part, de tenter une methode de classification automatique et d'en montrer les possibilites ainsi que les limites. (auteurs)

  3. The formation of scientists and technicians at the 'Centre d'Etudes Nucleaires' at Saclay

    International Nuclear Information System (INIS)

    Debiesse, J.

    1958-01-01

    The considerable needs in research workers and scientists which are asked by the nuclear energy obliged the Commissariat a l'Energie atomique to deal with a particular effort to increase the quantitative and qualitative formation of scientists. Most various ways have been used. 1- A National Institute of Nuclear Sciences and Nuclear Techniques was created, by a joint decree of the Prime Minister and the Minister for National Education (june 18, 1957). This Institute of Higher Teaching (250 students) indulges in the following matters: atomic engineering, quantum mechanics, theory and technic of particle accelerators, special metallurgy, radiobiology, thermic and mechanics of fluids. 2- An associated centre of the 'Conservatoire National des Arts et Metiers' was created (200 students) for technical assistants, drawers, etc. 3- In contribution with both electronic industry and Ministry of Work, the Centre d'Etudes Nucleaires contributes to an accelerated formation of technical assistants into Professional Centres. Conclusion: Training of scientists and research workers is one of the most important activities of the Centre d'Etudes Nucleaires de Saclay. Without losing its technical efficiency, it has supplied and varied means adapted to the various purposes that we shall reach. (author) [fr

  4. Generalities on the dynamic behaviour of rapid reactors. Preliminary studies on Rapsodie; Generalites sur le comportement dynamique des piles rapides. Etudes preliminaires de rapsodie

    Energy Technology Data Exchange (ETDEWEB)

    Campan, J L; Chaumont, J P; Clauzon, P P; Ghesquiere, G; Leduc, J; Schmitt, A P; Zaleski, C P [Commissariat a l' Energie Atomique, Cadarache (France). Centre d' Etudes Nucleaires

    1963-07-01

    The study of the dynamic behaviour of fast reactors may be divided into three section: 1. Stability studies around equilibrium power only the linear case was examining. S. Transient studies in the case of usual reactor operation (shut down, scram, etc.) with thermal shocks evaluation, for instance. 3. Explosion studies, for the maximum credible accidents. This report presents the status of the studies performed at the 'Physics Research Department' at Cadarache. Methods used are detailed and illustrated with the results obtained on a preliminary metallic core of the Rapsodie Reactor. (authors) [French] Le comportement dynamique des piles rapides, se presente tout naturellement sous trois aspects: 1. Etude de stabilite autour d'un regime d'equilibre (nous nous sommes bornes ici au cas lineaire). 2. Etude de regimes transitoires lors des operations normales de pile (arret, arret d'urgence, etc.) avec evaluation des chocs thermiques par exemple. 3. Etude des regimes transitoires de caractere explosif lors des accidents les plus graves possibles. Ce rapport presente l'etat des etudes a la date du 20 decembre 1961 a la Section d'Etudes de Piles Rapides a CADARACHE. Les methodes employees ont ete detaillees et illustrees a partir des resultats obtenus sur une premiere version 'combustible metallique' de Rapsodie. (auteurs)

  5. Etude cinétique de la dégradation de l'Endosufane en solution ...

    African Journals Online (AJOL)

    Etude cinétique de la dégradation de l'Endosufane en solution. S Traore, K Mamadou, A Dembele, V Yao, Y Bekro, P Mazellier, B Legube, P Houenou. Abstract. Les pesticides sont fréquemment utilisés en Côte d'Ivoire. Leur détection dans les eaux de forage témoigne de leur mauvais usage et d'un grave problème ...

  6. Study of the tributyl phosphate - 30% dodecane solvent; Etude du solvant phosphate tributylique - 30 % dodecane

    Energy Technology Data Exchange (ETDEWEB)

    Leroy, P [Commissariat a l' Energie Atomique, Fontenay-aux-Roses. Centre d' Etudes Nucleaires, 92 (France)

    1967-07-01

    This study, originating mainly from a literature survey, gives the principal chemical and physical features of the tributyl-phosphate (TBP) agent diluted at 30 volumes per cent in dodecane. The mixture is a very commonly used extractant in nuclear fuel processing. In this paper, the main following points are reported: -) the components (TBP and diluents) -) the TBP-diluents systems (non-loaded), -) the TBP-diluents-water systems, -) TBP-diluents-water-nitric acid systems, and -) industrial solvents. (author) [French] Cette etude, d'origine bibliographique, regroupe les caracteristiques physico-chimiques essentielles du phosphate tributylique (TBP) dilue a 30% en volume dans du dodecane. Ce melange constitue un agent d'extraction tres utilise dans le traitement des combustibles nucleaires. Les principaux points traites sont les suivants: -) les constituants (TBP et diluants), -) les systemes TBP-diluants non charges, -) les systemes TBP-diluants-eau, -) les systemes TBP-diluants-eau-acide nitrique, et -) les solvants industriels. (auteur)

  7. An economic study of the site of Marcoule; Etude economique du site de Marcoule

    Energy Technology Data Exchange (ETDEWEB)

    Duprat, H [Commissariat a l' Energie Atomique, Marcoule (France). Centre d' Etudes Nucleaires

    1964-07-01

    The study of this site of the Marcoule Center shows that its regional economical influence is limited to the buying power distributed among its personnel. This entails distortions between first this supplementary buying power and the overall markets within the possible Marcoule influence zone, and secondly the concentration on Bagnols-sur-Ceze and this town's normal extension possibilities. (author) [French] L'etude du site de Marcoule demontre que son influence economique se limite, pour la region, au pouvoir d'achat distribue a son personnel. Ceci entraine une disproportion d'une part entre ce pouvoir d'achat supplementaire et l'ensemble des marches contenus dans l'aire d'influence possible de Marcoule, d'autre part entre la concentration realisee a Bagnole-sur-Ceze et la capacite d'extension normale de cette agglomeration. (auteur)

  8. Neutronic study of the two french heavy water reactors; Etude neutronique des deux piles francaises a eau lourde

    Energy Technology Data Exchange (ETDEWEB)

    Horowitz, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1955-07-01

    The two french reactors - the reactor of Chatillon, named Zoe, and the reactor of Saclay - P2 - were the object of detailed neutronic studies which the main ideas are exposed in this report. These studies were mostly done by the Department of the Reactor Studies (D.E.P.). We have thus studied the distribution of neutronic fluxes; the factors influencing reactivity; the link between reactivity and divergence with the formula of Nordheim; the mean time life of neutrons; neutron spectra s of P2; the xenon effect; or the effect of the different adjustments of the plates and controls bar. (M.B.) [French] Les deux reacteurs francais - la pile de Chatillon, appelee ZOE, et la pile de Saclay, designee dans la suite par P2 - ont fait l'objet d'etudes neutroniques detaillees dont les principales sont exposees dans ce rapport. Ces etudes ont ete pour la plupart effectuees dans le cadre du Departement des Etudes de Piles (D.E.P.). Nous avons ainsi entre autre etudie la distribution du flux neutronique; les facteurs influencants la reactivite; le lien entre reactivite et divergence par la formule de Nordheim; le temps de vie moyen des neutrons; les spectres de neutrons de P2; l'effet xenon; ou encore l'effet des differents reglages des plaques et barres de controles. (M.B.)

  9. Studies on radiation-image detectors; Etudes sur les detecteurs a images de rayonnements; Izuchenie detektorov izobrazheniya radiatsii; Estudios sobre detectores de radiaciones productores de imagenes

    Energy Technology Data Exchange (ETDEWEB)

    Reiffel, L [Armour Research Foundation, Chicago, IL (United States)

    1962-04-15

    collimateur etait constitue par un tube droit de 1 cm sur 1 cm. L'auteur expose l'application de ces compteurs a d'autres etudes neutroniques et presente des observations sur le plus grand pouvoir de resolution que l'on puisse obtenir avec de plus faibles ecartements des electrodes, en procedant a un depouillement dynamique et, eventuellement, par filtrage de l'image optique. Une autre methode generale de detection des rayonnements par l'image consiste dans l'emploi d'ecrans de conversion luminescents ou phosphorescents. Des matrices en fibres luminescentes, composees de tubes de verre tres minces contenant un scintillateur liquide, ont fait l'objet d'essais. Ces matrices sont tres utiles pour la detection des rayons X et des rayonnements {gamma}; les matieres constituant la paroi, ou bien le liquide du coeur, peuvent etre en vue de les rendre sensibles aux neutrons. Le memoire expose de nouvelles methodes de fabrication de divers types d'ecrans en fibres luminescentes, ainsi que des donnees sur le comportement optique, qui ont des rapports avec la technologie de la chambre a scintillation. L'auteur examine brievement des detecteurs a images qui emploieraient des blocs epais de materiaux et qui seraient capables d'emmagasiner des energies non negligeables et d'emettre une phosphorescence stimulee par irradiation; il passe egalement en revue les methodes de lecture utilisant un procede de depouillement optique pour obvier a la diminution du pouvoir de resolution occasionnee par l'epaisseur finie du scintillateur. (author) [Spanish] El autor describe los trabajos sobre detectores de radiaciones capaces de proporcionar informacion sobre la distribucion espacial de estas. Las investigaciones se refieren principalmente al problema de determinar la distribucion de intensidades en un plano, o, si es posible, en una superficie cilindrica. Ello implica estudios sobre difraccion y radiografia neutronicas, sobre radiografia con rayos X y con rayos gamma o sobre la dispersion

  10. Granulometric study of plutonium oxide particles in suspension in the atmosphere of a furnace enclosure during the preparation of U-Pu alloys; Etude granulometrique des particules d'oxyde de plutonium en suspension dans l'atmosphere d'une enceinte de fonderie pendant la fabrication d'alliages U-PU

    Energy Technology Data Exchange (ETDEWEB)

    Bataller, G; Lenkauer, S [Commissariat a l' Energie Atomique, Cadarache (France). Centre d' Etudes Nucleaires

    1964-07-01

    Since the extent of an internal contamination by respiration depends on the diameter of the radioactive particles in the atmosphere, a particle size study has been made of the particles present in the air of a working enclosure at the Plutonium Fuel Element Production Section during the preparation of Uranium Plutonium alloy bars. The air of this vessel is drawn through a glass fibre filter on which the dust is deposited. On these filters the radioactive particles are localized first of all by the luminous spots which they produce on a photographic plate when a scintillator is interposed (silver-activated zinc sulphide). An autoradiographic method then makes it possible to distinguish between, and to measure the particles of the oxides of uranium 235, uranium 238 and plutonium 239. On carrying out a microscopic scanning of the relevant parts of the filter, particles are seen surrounded by radial marks the length of which indicates the nature of the grains, and the number of which makes it possible to calculate the theoretical diameter of the radioactive grain. This latter can be compared with the diameter observed with the microscope. Thus for each category of particles it is possible to define a mean diameter and therefore to predict the path of the various inhaled particles in the human body. These results are compared with the very few weakly positive biological samples taken from the personnel working in this enclosure. (authors) [French] L'importance d'une contamination interne par inhalation etant fonction du diametre des particules radioactives en suspension dans l'atmosphere, une etude granulometrique a ete effectuee sur les poussieres existant dans l'air d'une enceinte de travail a la Section de Fabrication des Elements Combustibles au Plutonium pendant une fabrication de barreaux d'alliage Uranium Plutonium, L'air de ce caisson est aspire a travers un filtre en fibre de verre sur lequel restent fixees les poussieres. Sur ces filtres, les particules

  11. Proposition d'un modèle expérimental pour la caractérisation de la réponse mécanique d'un composite (tissu de verre / résine époxyde)

    Science.gov (United States)

    Naceri, A.; Vautrin, A.

    2005-05-01

    L'objet de cet article est de proposer une géométrie d'éprouvette pour la caractérisation de la réponse mécanique d'un composite constitué de 12 plis de tissus de fibres de verre noyé dans une résine époxyde. Des essais de traction uniaxiale en rampe monotone réalisés sur différentes configurations géométriques d'éprouvettes avec différentes vitesses d'essais et le calcul numérique par éléments finis de la répartition des contraintes dans la zone centrale du modèle expérimental proposé, nous ont permis de justifier le choix d'une éprouvette profilée avec un rayon de 1000 mm qui présente une section réduite au centre et pour laquelle la rupture survient dans la zone centrale sans chute notable des caractéristiques mécaniques ultimes par rapport à l'éprouvette de forme parallélépipédique.

  12. Contribution to the study of french pitchblendes; Contribution a l'etude des pechblendes francaises

    Energy Technology Data Exchange (ETDEWEB)

    Geffroy, J [Commissariat a l' Energie Atomique, Lab. de Mineralogie, Centre de Chatillon (France). Centre d' Etudes Nucleaires; Sarcia, J A [Commissariat a l' Energie Atomique, Div. de la Crouzille, Haute Vienne (France). Centre d' Etudes Nucleaires

    1955-07-01

    The authors first review the characteristics of uraninite-pitchblende, as deduced of present literature. They set apart from typical pitchblende a black oxide aspect, which probably corresponds to neo-formations, and a 'para-pitchblende' aspect, which they relate to deep sur-oxidation of normal pitchblende. They insist on the easy replacement of pitchblende by silica. and give indications as to changes in vein stones (fluorite, quartz, etc...). A detailed study of paragenesis and successions in french uranium districts follows (including discussion of uranium of uranium-bearing coals). The authors attempt to classify french pitchblende veins. They are chiefly epithermal and poor in satellite ores. Three types of deposits are identified: massive - pitchblende type, silica type, fluorite type. These deposits, as those of Portugal, are included in granite, Central-European peri-batholitic types where uranium associates which Ni, Co, Bi and Ag, are in France both rare and poor. Finally, the authors attempt to bring out in the european Hercynian area a particular distribution of paragenetic types. (authors) [French] Les auteurs recapitulent d'abord les caracteres et les occurences de l'uraninite - pechblende, tels qu'ils peuvent etre degages de l'actuelle bibliographie. Ils exposent ensuite les faits qui du point de vue mineralogique seulement ressortent de l'etude mineralogique et chalcographique des pechblendes francaises et de leurs satellites. Ils distinguent de la pechblende-type un facies oxyde noir; correspondant probablement a une neoformation, et un facies parapechblende, qui est rapporte a une sur oxydation hypogene de la pechblende proprement dite. Ils insistent sur le facile remaniement de la pechblende par la slice; et donnent quelques precisions sur les modifications des gangues (fluorine, quartz, etc...). Suit l'etude detaillee des parageneses et des successions dans les districts uraniferes francais: Divisions du Limousin, de Grury, de Lachaux et de

  13. Study of some properties of zirconium phosphate; Etude de quelques proprietes du phosphate de zirconium

    Energy Technology Data Exchange (ETDEWEB)

    Prospert, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1963-05-01

    Zirconium phosphate has been studied with a view to using it as an ion exchanger: the first objective was to develop a method of preparation easy to apply and also reproducible. To this end, several tests were carried out varying the molar ratios of phosphorus and of zirconium. Some physical properties such as the diffraction of X-rays were examined. The work then involved certain chemical properties, particularly the percentages of free water and structural water given by the loss on calcination, the Karl-Fisher method and the weight losses by thermogravimetry. Finally an attempts was made to apply the exchanger to the separation of alkaline ions. The static tests showed that the order of fixation of these ions was Cs{sup +} > Rb{sup +} >> K{sup +} > Na{sup +}. Tests with columns showed that Na{sup +} and K{sup +} were easily separable, as was the Rb{sup +}-Cs{sup +} mixture, this last pair being fairly difficult to dissociate. (author) [French] Le phosphate de zirconium a ete etudie en vue de son utilisation comme echangeur d'ions: le premier but a atteindre a ete de mettre au point une preparation pouvant se reveler facilement utilisable ainsi qu'aisement reproductible. A cet effet, plusieurs essais ont ete effectues en faisant varier les rapports molaires du phosphore et du zirconium. Quelques proprietes physiques, telle la diffraction des rayons X, ont ete abordees. Ensuite, l'etude a porte sur certaines proprietes chimiques, particulierement les pourcentages d'eau libre et d'eau de structure par des pertes au feu, utilisation de la methode de Karl-Fisher, ainsi que des pertes de poids a la thenmobalance. Enfin, on a tente d'utiliser l'echangeur a la separation des ions alcalins. Les etudes statiques ont permis de constater que l'ordre de fixation de ces ions etait Cs{sup +} > Rb{sup +} >> K{sup +} > Na{sup +}. Les essais effectues en colonne ont montre que Na{sup +} et K{sup +} etaient aisement separables entre eux, ainsi que du couple Rb{sup +}-Cs{sup +}, ce

  14. The formation of scientists and technicians at the 'Centre d'Etudes Nucleaires' at Saclay; Formation des scientifiques et des techniciens au Centre d'Etudes Nucleaires de Saclay

    Energy Technology Data Exchange (ETDEWEB)

    Debiesse, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1958-07-01

    The considerable needs in research workers and scientists which are asked by the nuclear energy obliged the Commissariat a l'Energie atomique to deal with a particular effort to increase the quantitative and qualitative formation of scientists. Most various ways have been used. 1- A National Institute of Nuclear Sciences and Nuclear Techniques was created, by a joint decree of the Prime Minister and the Minister for National Education (june 18, 1957). This Institute of Higher Teaching (250 students) indulges in the following matters: atomic engineering, quantum mechanics, theory and technic of particle accelerators, special metallurgy, radiobiology, thermic and mechanics of fluids. 2- An associated centre of the 'Conservatoire National des Arts et Metiers' waeated (200 students) for technical assistants, drawers, etc. 3- In contribution with both electronic industry and Ministry of Work, the Centre d'Etudes Nucleaires contributes to an accelerated formation of technical assistants into Professional Centres. Conclusion: Training of scientists and research workers is one of the most important activities of the Centre d'Etudes Nucleaires de Saclay. Without losing its technical efficiency, it has supplied and varied means adapted to the various purposes that we shall reach. (author)Fren. [French] Les besoins considerables actuels et previsibles en chercheurs et scientifiques necessites par l'avevement de l'energie nucleaire imposaient au Commissariat a I'Energie atomique un effort particulier pour augmenter la formation quantitative et qualitative des scientifiques. Les moyens les plus divers ont ete mis en oeuvre: 1- Creation de l'Institut National des Sciences et Techniques Nucleaires par decret de la Presidence du Conseil et de l'Education Nationale en date du 18.6.57. Cet Institut d'Enseignement Superieur (250 etudiants) donne des cours en: genie atomique, mecanique quantique, theorie et technique des Accelerateurs de particules, metallurgie speciale, radiobiologie

  15. Development of a gas-ionization {beta}-spectrometer; Etude et realisation d'un spectrometre {beta} a ionisation gazeuse

    Energy Technology Data Exchange (ETDEWEB)

    Le Du, R [Commissariat a l' Energie Atomique, Bruyeres-le-Chatel (France). Centre d' Etudes

    1968-05-15

    We intend to develop in our laboratory a {beta}-spectrometer. This apparatus will have two main objectives: 1 - the determination of the nature and the degree of purity of certain {beta}-emitting radioactive substances; 2 - the study of an activity calibration process for {beta}-emitting radioactive sources. (author) [French] Nous nous proposons d'etudier et de realiser dans notre laboratoire un spectrometre {beta}. Cet appareil aura deux buts principaux: 1 - determiner la nature et le degre de purete de certains corps radioactifs emetteurs {beta}; 2 - permettre l'etude d'un procede d'etalonnage en activite de sources radioactives emetteurs {beta}. (auteur)

  16. Preparation and study of dialkyl nitroxide radicals; Preparation et etude de radicaux nitroxydes diacyles

    Energy Technology Data Exchange (ETDEWEB)

    Chenavas, P. [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1969-07-01

    These radicals are obtained by oxidation of N-hydroxy-imides with lead tetracetate or p-nitro-perbenzoic acid. These imides are prepared by heating dicarboxylic acids anhydrides with benzyloxy-amine followed by catalytic hydrogenation of N-benzyloxy-imides so obtained. Two series of radicals have mainly been studied, the first concerning five-membered cyclic imides, the second six-membered cyclic imides, these molecules having methyls substituents or no on the carbon ring. N. M. R. spectra of some O-benzyl-imides have been analysed. These different results have made it possible to study the conformation and stereochemistry of these imides. (author) [French] Ces radicaux sont obtenus par oxydation d'imides N-hydroxyles par le tetracetate de plomb ou l'acide p-nitroperbenzoique; ces imides sont prepares par chauffage d'anhydrides de diacides en presence de benzyloxyamine suivie d'une hydrogenation catalytique des N-benzyloxyimides ainsi obtenus. Deux series de radicaux ont principalement ete etudies: la premiere relative a des imides cycliques a cinq chainons, la seconde a des imides cycliques a six chainons, ces molecules ayant des substituants methyles ou non sur la chaine carbonee. Les derives O-benzyles de quelques-uns de ces imides ont ete analyses en R. M. N. Ces differents resultats ont permis une etude de la conformation et de la stereochimie de ces imides. (auteur)

  17. The abject gaze and the homosexual body: Flandrin's Figure d'Etude.

    Science.gov (United States)

    Camille, M

    1994-01-01

    This article charts the history of the reception, reproduction and appropriation of a single image that has recently become a kind of "gay icon"--the Figure d'Etude in the Louvre, painted by Hippolyte Flandrin in 1835. Initially no more than a neo-classical academic exercise, the formal emptiness of this picture meant that it could be re-invested and reinscribed with new meanings and new titles at every turn. Emblematic of the anxious visibility/invisibility of the newly discovered homosexual body during a period when the gaze still had to be kept a dark secret, Flandrin's image only "came out" in its later photographic reworkings by Frederick Holland Day and Baron von Gloeden. After being reproduced for a specifically homosexual audience early this century, the popular Romantic pose of the young man curled-up in profile became a standard one, reappearing recently in the photographs of Robert Mapplethorpe. The inactive, abject and inward-turned isolation of the figure with its narcissistic self-absorption makes it, in my view, a profoundly negative stereotype of the gay gaze and the homosexual body. Flandrin's figure nonetheless appears today on gay merchandise world-wide as a sign of our separate and secluded subject positions and our community's unwillingness to radically alter older imposed and inherited classical stereotypes.

  18. Study of copper fluorination; Contribution a l'etude de la fluoruration du cuivre

    Energy Technology Data Exchange (ETDEWEB)

    Gillardeau, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1967-02-01

    This report deals with the action of fluorine on copper. Comprehensive descriptions are given of the particular technological methods and of the preparation of the reactants. This fluorination reaction has been studied at medium and low fluorine pressures. A nucleation and growth phenomenon is described. The influence of a pollution of the gas phase on the fluorination process is described. The solid-state reaction between cupric fluoride and cooper has also been studied. A special study has been made of the growth of copper deposits by thermal decomposition of gaseous fluorides. (author) [French] Ce rapport traite de la reaction du fluor sur le cuivre. Les methodes technologiques particulieres ainsi que les preparations des reactifs sont largement developpees. Cette reaction de fluoruration est etudiee sous pressions moyennes et sous basses pressions de fluor. Un phenomene de germination et croissance est decrit. L'influence de la pollution de la phase gazeuse sur le processus de fluoruration est rapportee. La reaction a l'etat solide du fluorure cuivrique sur le cuivre a egalement ete etudiee. La croissance de depots de cuivre par decomposition thermique des fluorures de cuivre gazeux fait l'objet d'une etude speciale. (auteur)

  19. Preparation and study of dialkyl nitroxide radicals; Preparation et etude de radicaux nitroxydes diacyles

    Energy Technology Data Exchange (ETDEWEB)

    Chenavas, P [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1969-07-01

    These radicals are obtained by oxidation of N-hydroxy-imides with lead tetracetate or p-nitro-perbenzoic acid. These imides are prepared by heating dicarboxylic acids anhydrides with benzyloxy-amine followed by catalytic hydrogenation of N-benzyloxy-imides so obtained. Two series of radicals have mainly been studied, the first concerning five-membered cyclic imides, the second six-membered cyclic imides, these molecules having methyls substituents or no on the carbon ring. N. M. R. spectra of some O-benzyl-imides have been analysed. These different results have made it possible to study the conformation and stereochemistry of these imides. (author) [French] Ces radicaux sont obtenus par oxydation d'imides N-hydroxyles par le tetracetate de plomb ou l'acide p-nitroperbenzoique; ces imides sont prepares par chauffage d'anhydrides de diacides en presence de benzyloxyamine suivie d'une hydrogenation catalytique des N-benzyloxyimides ainsi obtenus. Deux series de radicaux ont principalement ete etudies: la premiere relative a des imides cycliques a cinq chainons, la seconde a des imides cycliques a six chainons, ces molecules ayant des substituants methyles ou non sur la chaine carbonee. Les derives O-benzyles de quelques-uns de ces imides ont ete analyses en R. M. N. Ces differents resultats ont permis une etude de la conformation et de la stereochimie de ces imides. (auteur)

  20. Study of {gamma}'s in Naiade; Etude des gamma de Naiade

    Energy Technology Data Exchange (ETDEWEB)

    Millot, J P; Rastoin, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1958-07-01

    Following a study of the gamma sources, the flux of gamma of different energies in the swimming pool is investigated. The biological dose can thus be obtained by calculation, and compared with the results given by photographic plates. The influence of photoneutrons is estimated by calculation, and research is being carried out on their influence on the thermal neutron flux curve on the axis of the uranium plate, with the plate emitting neutrons and with the plate protected by boral. (author) [French] Apres l'etude des sources de gamma, l'on etudie le flux de gamma de differentes energies dans la piscine. La dose biologique peut etre obtenue ainsi par le calcul et comparee avec les resultats donnes par les plaques photographiques. L'influence des photoneutrons est estimee par le calcul et l'on recherche leur influence sur la courbe de flux de neutrons thermiques sur l'axe de la plaque d'uranium, la plaque emettant des neutrons et la plaque protegee par du boral. (auteur)

  1. Technological study of organic fluids; Etudes technologiques des fluides caloporteurs organique

    Energy Technology Data Exchange (ETDEWEB)

    Leveque, P [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-07-01

    Under contract to EURATOM (MM. VAN der VENNE and HANNAERT), the C.E.A. and the Progil Society have collaborated on a technological study of the terphenyls. The results obtained from the radiolysis and pyrolysis of the product OM2 (70 p. 100 m-terphenyl, 25 p. 100 o-terphenyl, 5 p. 100 p-terphenyl) are reported. Using two pile loops at temperatures up to 450 deg. C, a phenomena of accelerated pyrolysis on the radiolized material has been demonstrated. Some by-products of the petroleum industry have also been studied, with a view to finding substitutes for terphenyl. (author) [French] Le C.E.A. et la Societe PROGIL ont entrepris en commun sous contrat EURATOM (MM. VAN der VENNE et HANNAERT) une etude technologique des terphenyles. Les resultats de radiolyse et de pyrolyse obtenus sur le produit OM2 (70 p. 100 m-terphenyle, 25 p. 100 o-terphenyle. 5 p. 100 de p-terphenyle) sont exposes. L'exploitation de deux boucles en pile jusqu'a des temperatures de 450 deg. C a mis en evidence un phenomene de pyrolyse acceleree sur le produit radiolyse. On a etudie egalement quelques sous-produits de l'industrie petroliere dans le but de trouver des substituts au terphenyle. (auteur)

  2. Underground nuclear explosions. Geological survey of the cavities; Explosions nucleaires souterraines etude geologique des cavites

    Energy Technology Data Exchange (ETDEWEB)

    Faure, J [Commissariat a l' Energie Atomique, Bruyeres-le-Chatel (France). Centre d' Etudes

    1969-07-01

    A geological survey of underground nuclear explosions makes it possible to determine the main characteristics of the cavity formed. The lower portion is spherical; the same was very likely true of the roof, which collapses in the majority of media with the exception of rock-salt. Its radius, for a given bomb size, can vary by a factor of two according to the type of rock. The lay-out of its contents depends on the characteristics of the solid and liquid products at the moment of the roof collapse; according to the medium involved, mixing of the rubble and the mud-flow occurs (granite) or does not occur (tuff and alluvia). In all media, the average physical properties can be evaluated. (author) [French] L'etude geologique d'explosions nucleaires souterraines permet de determiner les principaux caracteres de la cavite creee. Sa partie inferieure est spherique; il en etait vraisemblablement de meme de sa voute, effondree dans la plupart des milieux a l'exception du sel gemme. Son rayon, a energie d'engin egale, varie selon les roches du simple au double. La disposition de son contenu depend des caracteristiques des produits solides et liquides au moment de la chute du toit; selon le cas, il n'y a pas (tuf et alluvions) ou il y a (granite) melange des eboulis et des laves. Dans tous les milieux, les proprietes physiques moyennes peuvent etre evaluees. (auteur)

  3. Study: control of atomic energy power plant; Etude de la regulation d'une installation atomique productrice d'energie

    Energy Technology Data Exchange (ETDEWEB)

    Dautray, R; Leny, J C [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1958-07-01

    We are studying the control of a very flexible atomic power plant, able to supply an independent network. Two systems have been examined: in the first the moderator pre-heats the light water, in the second, this preheating is dispensed with, subsequent to a study of the dynamics of the plant. Very complete linear approximation study is being effected on the model of the second system, all effects being taken into account. The reactor is stable at all power levels, though slight reactivity or load variations cause undamped power oscillations around the equilibrium level. (author)Fren. [French] Nous etudions la regulation d'une installation atomique d'une grande souplesse, pouvant eventuellement fournir de l'energie a un reseau isole. Deux versions de l'installation sont etudiees: dans la premiere le moderateur sert a rechauffer l'eau industrielle, mais l'etude dynamique conduit a supprimer ce rechauffage, ce qui donne la deuxieme version. On effectue sur celle-ci une etude en approximation lineaire tres complete ou l'on tient compte de differents effets. L'installation se montre stable a tous les niveaux de puissance. Toutefois, de petites perturbations de reactivite ou de charge entrainent des oscillations de puissance mal amorties autour de la position d'equilibre. (auteur)

  4. Methods for studying the radioactive contamination of plants (1963); Methodes d'etude de la contamination radioactive des vegetaux (1963)

    Energy Technology Data Exchange (ETDEWEB)

    Coulon, R; Jeanmaire, L; Michon, G [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1963-07-01

    The authors first define the doctrine which led to the devising of a method for studying the radioactive pollution of plants, based on the use of simple techniques, having the possibility of being adapted for routine work, and so devised that each stage is proceeded with only if the preceding one justifies it. For each stage a study is effected comparing the results obtained by the use of more exact techniques. The second part describes in detail the techniques used. (authors) [French] Dans une premiere partie lea auteurs definissent la doctrine qui leur a permis d'elaborer une methode d'etude de la pollution radioactive des vegetaux, basee sur l'utilisation de techniques simples, se pretant au travail de serie et concues de telle maniere que chaque etape n'est abordee que si la precedente le justifie. Chaque etape fait l'objet d'une etude qui compare les resultats a ceux obtenue par des techniques plus precises. La deuxieme partie decrit dans le detail les techniques utilisees. (auteurs)

  5. Contribution to the study of french pitchblendes; Contribution a l'etude des pechblendes francaises

    Energy Technology Data Exchange (ETDEWEB)

    Geffroy, J. [Commissariat a l' Energie Atomique, Lab. de Mineralogie, Centre de Chatillon (France). Centre d' Etudes Nucleaires; Sarcia, J.A. [Commissariat a l' Energie Atomique, Div. de la Crouzille, Haute Vienne (France). Centre d' Etudes Nucleaires

    1955-07-01

    The authors first review the characteristics of uraninite-pitchblende, as deduced of present literature. They set apart from typical pitchblende a black oxide aspect, which probably corresponds to neo-formations, and a 'para-pitchblende' aspect, which they relate to deep sur-oxidation of normal pitchblende. They insist on the easy replacement of pitchblende by silica. and give indications as to changes in vein stones (fluorite, quartz, etc...). A detailed study of paragenesis and successions in french uranium districts follows (including discussion of uranium of uranium-bearing coals). The authors attempt to classify french pitchblende veins. They are chiefly epithermal and poor in satellite ores. Three types of deposits are identified: massive - pitchblende type, silica type, fluorite type. These deposits, as those of Portugal, are included in granite, Central-European peri-batholitic types where uranium associates which Ni, Co, Bi and Ag, are in France both rare and poor. Finally, the authors attempt to bring out in the european Hercynian area a particular distribution of paragenetic types. (authors) [French] Les auteurs recapitulent d'abord les caracteres et les occurences de l'uraninite - pechblende, tels qu'ils peuvent etre degages de l'actuelle bibliographie. Ils exposent ensuite les faits qui du point de vue mineralogique seulement ressortent de l'etude mineralogique et chalcographique des pechblendes francaises et de leurs satellites. Ils distinguent de la pechblende-type un facies oxyde noir; correspondant probablement a une neoformation, et un facies parapechblende, qui est rapporte a une sur oxydation hypogene de la pechblende proprement dite. Ils insistent sur le facile remaniement de la pechblende par la slice; et donnent quelques precisions sur les modifications des gangues (fluorine, quartz, etc...). Suit l'etude detaillee des parageneses et des successions dans les districts uraniferes francais: Divisions du

  6. The dynamic behaviour of heat exchangers; Etude du comportement dynamique des echangeurs de chaleur

    Energy Technology Data Exchange (ETDEWEB)

    Fonteray, J; Rozenholc, M [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1963-07-01

    In order to study the dynamics of nuclear power plants, one needs mathematical models made up of ordinary differential equations. This report deals with models for heat exchangers. These models allow exact evaluations of the temperatures for any steady state. The deformation of the temperature maps during transients is taken into account. To do this, average temperatures are evaluated keeping In mind, on one hand the partial differential equations, on the other hand, the physical phenomenons which are involved. Seven ordinary differential equations at most, are necessary for one heat exchanger. Theses models were compared with mathematically exact ones and also with experimental results, that EDF was able to measure on EDF-1 heat exchangers. The results appear to be correct. (authors) [French] Les etudes de dynamique sur les centrales nucleaires exigent l'elaboration de modeles apparaissant sous forme d'equations differentlelles ordinaires. Ce rapport est consacre a la recherche de modeles d'echangeurs. Dans ces modeles les temperatures sont calculees exactement pour n'importe quel regime permanent. Pour tenir compte de la deformation des distributions de temperature en regime transitoire, on evalue les temperatures moyennes dans l'echangeur en s'appuyant, d'une part, sur les equations aux derivees partielles et, d'autre part, sur une analyse des phenomenes physiques. Les modeles contiennent au plus sept equations differentielles ordinaires. Ces modeles ont ete compares aux modeles mathematiques exacts et aussi a des resultats experimentaux, obtenus par l'EDF, sur les echangeurs d'EDF-1. Les resultats paraissent satisfaisants. (auteurs)

  7. Etude theorique et experimentale des evaporateurs de dioxyde de carbone operant dans des conditions de givrage

    Science.gov (United States)

    Bendaoud, Adlane Larbi

    Les evaporateurs de refrigeration sont surtout du type tube a ailettes, appeles serpentins, et fonctionnent dans l'une des conditions suivantes: seche, humide ou avec formation de givre. Il a ete demontre que la formation du givre sur la paroi exterieure de l'echangeur engendre une surconsommation energetique a cause des operations de degivrage puisque 15 a 20% seulement de la chaleur produite sert au degivrage tandis que le reste est dissipee dans l'environnement [1]. Avec l'avenement des nouveaux refrigerants, moins nocifs envers l'environnement, l'industrie du froid se trouve penalisee du fait que peu ou pas de composantes mecaniques (compresseur, pompe, echangeur...etc.) adaptees sont disponibles [3]. Il s'agit pour la communaute des frigoristes de combler ce retard technologique en redeveloppant ces composantes mecaniques afin qu'elles soient adaptees aux nouveaux refrigerants. Dans cette optique, et afin de mieux comprendre le comportement thermique des evaporateurs au CO2 fonctionnant dans des conditions seches, qu'un groupe de chercheurs du CanmetENERGIE avaient lance, en 2000, un programme de R & D. Dans le cadre de programme un outil de simulation des evaporateurs au CO2 a ete developpe et un banc d'essai contenant une boucle secondaire de refrigeration utilisant le CO2 comme refrigerant a ete construit. Comme continuite de ce travail de recherche, en 2006 ce meme groupe de recherche a lance un nouveau projet qui consiste a faire une etude theorique et experimentale des evaporateurs au CO2 operants dans des conditions de givrage. Et, c'est exactement dans le cadre de ce projet que se positionne ce travail de these. Ce travail de recherche a ete entrepris pour mieux comprendre le comportement thermique et hydrodynamique des serpentins fonctionnant dans des conditions de givrage, l'effet des circuits de refrigerant ainsi que celui des parametres geometriques et d'operation. Pour cela, un travail theorique supporte par une etude experimentale a ete effectue

  8. An approach to automated chromosome analysis; Etudes pour une methode d'automatisation des analyses chromosomiques

    Energy Technology Data Exchange (ETDEWEB)

    Le Go, Roland

    1972-05-03

    d'une automatisation des differentes etapes de l'analyse chromosomique. Il est divise en trois tomes dont la matiere est decrite ci-apres. Dans le tome 1 est decrite l'etude d'un selecteur automatique de metaphases. Cet appareil doit realiser au cours du scanning d'une preparation, un processus de decision aboutissant a rejeter toutes images ininteressantes et a conserver les images pertinentes (bonnes metaphases). Ce probleme a ete aborde au moyen d'une etude sur ordinateur par un programme de simulation. La realisation de ce programme a permis d'etablir des algorithmes de selection dont la replique pourra etre realisee dans des circuits logiques electroniques. Dans le tome 2 est traite le probleme de l'automatisation de l'etude morphologique des chromosomes presents dans une metaphase. Cette automatisation necessite le traitement des photographies de metaphases par un appareil convertisseur optique-numerique qui extrait l'information-image et la transcrit sous la forme d'un fichier numerique. Ce fichier comporte pour une image de metaphase, environ 200 000 valeurs de gris, codees selon une echelle a 16, 32 ou 64 ni veaux. Ce fichier numerique est traite par un programme de reconnaissance de forme, qui isole les chromosomes et en recherche les traits caracteristiques: sommets de bras et region centromerique, dans le but d'obtenir des mensurations equivalentes aux longueurs des quatre bras. Le tome 3 etudie un programme d'etablissement automatique du caryotype humain, par appariement optimise des chromosomes. Les donnees proviennent de la numerisation directe des longueurs de bras, effectuee au moyen d'un lecteur digital BENSON. Le programme etablit une liste des appariements, un document graphique imprime representant les paires constituees, dans l'espace: longueur - index centromerique; enfin un document graphique obtenu sur traceur BENSON dans lequel l'auteur donne une representation personnelle des chromosomes, sous forme de croix a bras orthogonaux, dont chaque

  9. Pegase: safety studies - experimental study of burn-out risks in transient operation; Pegase: etude de surete - etude experimentale des risques de burn out en regime transitoire

    Energy Technology Data Exchange (ETDEWEB)

    Vernier, P [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1968-07-01

    canal chaud se met en etat de calefaction au bout de 0.1 s et que sa temperature atteint 500 C en 0.8 s. Les regimes hydrodynamiques rencontres dans les canaux apres l'accident sont des regimes d'expulsion periodiques de periodes courtes 0.2 a 0.5 s, caracteristiques de l'ebullition a basse pression. L'etude en regime permanent de la redistribution de debit dans un by-pass a donne des flux PHI{sub R} de redistribution de 190 W/cm{sup 2} pour une vitesse de 4.5 m/s a 50 C et de 175 W/cm{sup 2} a 60 C. Ces valeurs sont a majorer de 25 pour cent pour une vitesse de 6 m/s. On a montre la distinction a faire entre flux critique PHI{sub C} en regime periodique d'expulsion et flux de redistribution PHI{sub R} en regime permanent. (auteur)

  10. Study of the dynamic behaviour of the reactor Rapsodie; Etude du comportement dynamique de la pile rapsodie

    Energy Technology Data Exchange (ETDEWEB)

    Abdon, R; Chaigne, M [Commissariat a l' Energie Atomique, Cadarache (France). Centre d' Etudes Nucleaires

    1964-07-01

    . The investigation of the control, carried out on analog computer, served to determine the different possible means of starting and changing the conditions of the reactor as well as its automatic control. The calculations were examined in the totality by the construction of a training simulator composed of a board similar to the control board of the reactor, all of whose commands (reactivity and flows) work on an analogue computer which resolves in the real time the dynamic equations of the reactor and which reproduces simultaneously all the parameters representing the state of the installation (power, period, temperatures, etc. ) in the case of various incidents as well as under normal conditions of functioning. (authors) [French] On sait que le developpement des reacteurs surgenerateurs a neutrons rapides pose des problemes nouveaux d'une part dans les domaines mecanique et thermique et d'autre part en ce qui concerne leur comportement dynamique et leur surete. La pile RAPSODIE a ete l'objet de tres nombreuses etudes dynamiques effectuees sur machines analogiques et digitales, pour deux versions du combustible (metal et oxyde). Apres elaboration des modeles mathematiques representatifs de l'ensemble de l'installation (bloc pile et circuit de refroidissement) tant du point de vue neutronique que du point de vue thermodynamique, on a mis au point les schemas analogiques et les codes digitaux utilisables pour mener a bien les simulations d'incidents, de conduite et de stabilite du reacteur. On s'est attache, par rapport aux methodes habituelles a obtenir une precision plus grande, par un decoupage en zones plus fines, par l'emploi de formulations plus representatives du systeme reel, voire solubles analytiquement. Les etudes d'incidents ont ete effectuees par voie analogique pour l'ensemble de l'installation et par voie digitale pour l'etude du bloc pile seul ou de l'installation fonctionnant avec un seul circuit thermique. Un programme complementaire special - qui, a

  11. The study of neutron transport by oscillation method; Etude du transport des neutrons par la methode de modulation

    Energy Technology Data Exchange (ETDEWEB)

    Raievski, V

    1959-07-01

    The oscillation method is of very general use for studying the behavior of thermal neutrons in media. The main experiments are described and a general theory of them is given. This theory, which is presented in the first part, is established using the two-group approximation which has proved its efficiency in the case of thermal neutron piles. The validity of the two-group approximation is recalled. This allows definition of the meaning of the parameters used in the theory and which are measured in these experiments. The experiments carried out by this method are described, especially those performed at the Centre d'Etudes Nucleaires de Saclay where the method has been extensively used. These experiments are interpreted by means of the general theory given previously. In this way, the identity of parameters measured by this method and those given by the theory is proved. This is particularly conclusive is the case of the mean life of neutrons in a pile. (author) [French] La methode de modulation est un procede tres general d'etude des proprietes neutroniques des milieux contenant des neutrons thermiques. Le present rapport a pour but de decrire les principales de ces experiences et d'en donner une theorie generale. Cette theorie, exposee dans la premiere partie, est etablie dons le cadre de l'approximation a deux groupes de vitesse qui a prouve son efficacite dons le cas des piles a neutrons thermiques. Le domaine de validite de l'approximation a deux groupes est rappele au debut, ce qui permet de definir avec precision la signification des parametres qui entrent dons la theorie et qui font l'objet de ces mesures. La deuxieme partie decrit les experiences realisees, en particulier celles effectuees au Centre d'Etudes Nucleaires de Saclay ou la methode a ete considerablement developpee. Ces experiences sont interpretees dans le cadre de la theorie generale exposee precedemment. On prouve ainsi l'identite des parametres mesures par cette methode et de ceux figurant

  12. Randomized control trial for the assessment of the anti-albuminuric effects of topiroxostat in hyperuricemic patients with diabetic nephropathy (the ETUDE study).

    Science.gov (United States)

    Kato, Sawako; Ando, Masahiko; Mizukoshi, Toshihiro; Nagata, Takanobu; Katsuno, Takayuki; Kosugi, Tomoki; Tsuboi, Naotake; Maruyama, Shoichi

    2016-05-01

    Proteinuria is an established risk factor for diabetic nephropathy. Recent studies indicate that some xanthine oxidase inhibitors have a renoprotective effect. The aim of this study was to assess whether topiroxostat reduces albuminuria in hyperuricemic patients with diabetic nephropathy and overt proteinuria. The ETUDE study is an ongoing 24-week, multicenter, open-label, randomized (1:1), parallel group study involving hyperuricemic patients with diabetic nephropathy (estimated glomerular filtration rate [eGFR] ≥ 20 mL/min/1.73 m(2)) and overt proteinuria (0.3 ≤ urine protein to creatinine ratio (UPCR) ETUDE trial is the first randomized controlled study of topiroxostat in hyperuricemic patients with diabetic nephropathy and overt proteinuria. We will clarify the pleiotropic function of topiroxostat including an anti-albumiuric effect as well as its effects on safely decreasing serum uric acid levels.

  13. Etude de la transition ferroelectrique-ferroelastique du KD2PO4 forme du front de phase en fonction du gradient thermique

    OpenAIRE

    Kvítek, Zdeněk

    2010-01-01

    Etude de la transition ferroelectrique-ferroelastique du KD2PO4 forme du front de phase en fonction du gradient thermique The thesis explores complex process of first order transition of KD2PO4 crystal from tetragonal phase to ferroelectric - ferroelastic orthorhombic phase and back at temperature 209 K. The experimental set up of nitrogeneous cryostat allowes temperature and temperature gradient variations during simultaneous three axes optical sample observations, dielectric measurements. T...

  14. Point-of-care ultrasonography adoption in Canada: using diffusion theory and the Evaluation Tool for Ultrasound skills Development and Education (ETUDE).

    Science.gov (United States)

    Woo, Michael Y; Frank, Jason R; Lee, A Curtis

    2014-09-01

    Point-of-care ultrasonography (PoCUS) first appeared in the 1980s in North America, but the extent of the diffusion of its adoption is unknown. We characterized early PoCUS adoption by emergency physicians in Canada and its barriers to use using Rogers' diffusion of innovations theory. We developed a questionnaire based on a pilot study and literature review to assess past, current, and potential use of PoCUS and potential barriers to adoption. A Dillman technique for electronic surveys was used for dissemination. Using Rogers' diffusion of innovations theory, we developed and validated the Evaluation Tool for Ultrasound skills Development and Education (ETUDE). ETUDE scores allowed categorization of respondents into innovators, early adopters, majority, and nonadopters. Descriptive statistics, correlations, and χ² statistics were used to analyze the data. The 296 respondents (36.4% of 814 surveyed) had a median age of 40 and were 72.5% male. Adoption scores using ETUDE revealed nonadopters (18.8%), majority (28.7%), early adopters (34.5%), and innovators (18.0%). Respondents endorsed "always" using PoCUS currently and in the future for focused assessment with sonography in trauma (FAST) (current 41.8%/future 88.4%), first trimester pregnancy (current 23.3%/future 73.7%), suspected abdominal aortic aneurysm (current 32.7%/future 92.6%), basic cardiac indications (current 30.7%/future 87.5%), and central venous catheterization (current 17.0%/future 80.3%). Several barriers to PoCUS were identified for part-time emergency physicians and those working in inner-city/urban/suburban settings. This is the first study to determine the state of adoption and barriers to the introduction of PoCUS in Canadian emergency medicine practice. The novel validated ETUDE instrument should be used to evaluate the uptake of PoCUS over time.

  15. Theoretical study, and construction, of a spherical electrostatic beta spectrometer; Etude theorique et realisation d'un spectrometre beta electrostatique spherique

    Energy Technology Data Exchange (ETDEWEB)

    Moret, R [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1964-03-15

    After a literature survey showing the importance of an electrostatic spectrometer with spherical electrodes for studying disintegration processes, the theoretical characteristics of such an apparatus are derived (determination of the trajectory equations calculation of the transmission and of the resolving power the case of a point source and of an extended source). The apparatus built as a result of these calculations is described. The electrostatic field distribution outside the electrodes is derived. As well as giving electron spectra ({beta} disintegration and conversion electrons) the apparatus make s it possible to study e-{gamma}, e-{beta}, e-e-{gamma} and e-e-{beta} coincidences. In the last part are given experimental characteristics and the results of the first measurements made on conversion electron spectra ({sup 161}Tb, {sup 151}Pm, {sup 155}Eu) and on coincidences ({sup 170}Tm) using this spectrometer. (author) [French] Apres une etude bibliographique montrant l'interet que presente un spectrometre electrostatique a electrodes spheriques pour l'etude des schemas de desintegration, l'auteur etablit les caracteristiques theoriques d'un tel appareil (determination de l'equation des trajectoires calcul de la transmission et du pouvoir de resolution cas d'une source ponctuelle et d'une source etendue). On decrit l'appareil realise d'apres ces calculs. On etablit la repartition du champ electrostatique a l'exterieur des electrodes. Outre le trace des spectres d'electrons (desintegration {beta} et electrons de conversion), l'appareil permet l'etude de coincidences e-{gamma}, e-{beta}, e-e-{gamma} and e-e-{beta}. Dans la derniere partie, sont donnees les caracteristiques experimentales et les premieres etudes de spectres d'electrons de conversion ({sup 161}Tb, {sup 151}Pm, {sup 155}Eu) et de coincidences ({sup 170}Tm) faites a l'aide de ce spectrometre. (auteur)

  16. Experimental study of contamination by inhalation of radioactive iodine aerosols. Biological balance; Etude experimentale de la contamination par inhalation d'aerosols d'iode radioactif bilan biologique

    Energy Technology Data Exchange (ETDEWEB)

    Marble, G [Commissariat a l' Energie Atomique, 92 - Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1968-07-01

    Several articles have been published concerning research into contamination produced by inhalation of radioactive iodine aerosols in monkeys. Results dealing with the biological balance of this contamination are presented and discussed in this report. (author) [French] L'etude experimentale de la contamination par inhalation d'aerosols d'iode radioactif effectuee chez le singe a fait l'objet de plusieurs publications. Les resultats concernant le bilan biologique de cette contamination sont presentes et discutes dans ce rapport. (auteur)

  17. The Measurement of Integrated Gamma-Ray Doses in the Range 50 Mrad to 5 Mrad Using Phosphate Glass and Lithium Fluoride; Mesure, au Moyen de Verre au Phosphate et de Fluorure de Lithium, de Doses Integrees de Rayons Gamma de 50 Mrad a 5 Mrad; 0418 0417 041c 0414 ; Medicion de Dosis Integradas de Rayos Gamma de 50 Mrad a 5 Mrad por Medio de Vidrio al Fosfato y de Fluoruro de Litio

    Energy Technology Data Exchange (ETDEWEB)

    Webb, G. A.M. [Central Electricity Generating Board, Berkeley Nuclear Laboratories, Berkeley, Glos. (United Kingdom)

    1965-06-15

    }-ray fluxes. A comparison is made of the two systems for general convenience and also for use in particular situations. (author) [French] L'auteur a compare la radiophotoluminescence et la coloration du verre au phosphate a la thermoluminescence du fluorure de lithium aux fins de dosimetrie pour des doses de rayons gamma de 50 mrad a 5 Mrad. Il a mesure la luminescence produite dans du verre au phosphate active a l'argent, de faible numero atomique, a l'aide d'un fluorimetre industriel (dosimetre Toshiba au verre au fluor) complete d'un spectrophotometre permettant de mesurer les variations de la densite optique pour les doses elevees. Les effets des differentes methodes de nettoyage du verre ont ete etudies. L'auteur a mesure la thermoluminescence du fluorure de lithium en utilisant un appareil de lecture de laboratoire afin d'obtenir des courbes de luminescence et en integrant ensuite la region situee sous le pic approprie. Il a mesure le spectre d'emission de la thermoluminescence au moyen de filtres optique qui ont egalement servi a reduire au minimum les effets des infrarouges emis par la plaque de chauffage. Il a etudie les effets des filtres optiques et de la mesure sous azote sur le pic de tribothermoluminescence. L'auteur a etudie et compare plusieurs parametres du rendement des deux systemes. Avec le verre, on peut mesurer une gamma d'intensites tres etendue, allant de 5 * 10{sup -2} a 5 * 10{sup 6} rad, soit une etendue de l'ordre de 10{sup 8} ; en revanche, LiF peut etre utilise pour des doses legerement plus faibles, mais il atteint le point de saturation pour les doses superieures a 10{sup 5} rad. Le LiF est presque dependant de l'energie, mais le verre presente un ecart maximum equivalent a sept fois la reponse au {sup 60}Co a 60 keV; cet ecart peut etre corrige a l 'aide d'ecrans qui ont l'inconvenient d'elever la limite inferieure d'energie. Le phenomene d'evanouissement du verre a ete etudie de maniere approfondie; celui du LiF, qui est moins prononce, n

  18. Studies of iron carbon alloys; Contribution a l'etude des alliages dilues de carbone dans le fer {alpha}

    Energy Technology Data Exchange (ETDEWEB)

    Anagnostopoulos, T [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1971-07-01

    Precipitation of carbon in {alpha} iron during a thermal treatment was followed using the magnetic after effect. A study was made of the influence of different parameters such as quenching speed, annealing rate, carbon concentration with or without impurity, irradiation effects. A transient sur-saturation occurs during dissolution of carbon in iron at 500 C. (author) [French] La precipitation du carbone dans le fer au cours d'un traitement thermique a ete suivie au moyen du trainage magnetique. L'etude de differents parametres tels que: vitesse de trempe, mode de recuit, concentration en carbone, presence d'impuretes, effet d'une irradiation, ont ete menes a bien. Un phenomene de sursaturation transitoire au cours de la remise en solution a 500 C a ete mis en evidence. (auteur)

  19. Dosimeter calibration facilities and methods at the Radiation Measurement Laboratory of the Centre d'etudes nucleaires, Grenoble

    International Nuclear Information System (INIS)

    Choudens, H. de; Herbaut, Y.; Haddad, A.; Giroux, J.; Rouillon, J.; CEA Centre d'Etudes Nucleaires de Grenoble, 38

    1975-01-01

    At the Centre d'etudes nucleaires, Grenoble, the Radiation Measurement Laboratory, which forms part of the Environmental Protection and Research Department, serves the entire Centre for purposes of dosimetry and the calibration of dose meters. The needs of radiation protection are such that one must have facilities for checking periodically the calibration of radiation-monitoring instruments and developing special dosimetry techniques. It was thought a good idea to arrange for the dosimetry and radiation protection team to assist other groups working at the Centre - in particular, the staff of the biology and radiobiology laboratories - and also bodies outside the framework of the French Commissariat a l'energie atomique. Thus, technical collaboration has been established with, for example, Grenoble's Centre hospitalier universitaire (university clinic), which makes use of the facilities and skills available at the Radiation Measurement Laboratory for solving special dosimetry problems. With the Laboratory's facilities it is possible to calibrate dose meters for gamma, beta and neutron measurements

  20. Some techniques for studying actomyosin by electron microscopy; Quelques techniques d'etude de l'actomyosine par microscopie electronique

    Energy Technology Data Exchange (ETDEWEB)

    Herzberg, M [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires. Departement de Biologie

    1967-07-01

    A method has been developed for shadowing using a platinum-carbon alloy; it has been applied to the study of the interaction of actomyosin with its substrate ATP. The results obtained seem to favour the hypothesis of a dissociation of the actomyosin into its two components: actin and myosin. Pictures have been obtained showing particles resembling non-polymerized myosin but no rigorous proof of this exists. (author) [French] Une methode d'ombrage par un alliage de platine et carbone a ete mise au point et appliquee a l'etude de l'interaction de l'actomyosine et de son substrat l'ATP. Les resultats obtenus semblent pencher en faveur de la these d'une dissociation de l'actomyosine en ses deux constituants: l'actine et la myosine. Des images ont ete obtenues montrant des particules dont l'identite avec la myosine non polymerisee reste a demontrer plus rigoureusement. (auteur)

  1. Cell for studying electron-adsorbed gas interactions; Cellule d'etudes des interactions electron-gaz adsorbe

    Energy Technology Data Exchange (ETDEWEB)

    Golowacz, H; Degras, D A [Commissariat a l' Energie Atomique, 91 - Saclay (France). Centre d' Etudes Nucleaires, Deptartement de Physique des Plasmas et de la Fusion Controlee, Service de Physique Appliquee, Service de Physique des Interractions Electroniques, Section d' Etude des Interactions Gaz-Solides

    1967-07-01

    The geometry and the technology of a cell used for investigations on electron-adsorbed gas interactions are described. The resonance frequencies of the surface ions which are created by the electron impact on the adsorbed gas are predicted by simplified calculations. The experimental data relative to carbon monoxide and neon are in good agreement with these predictions. (authors) [French] Les caracteristiques geometriques et technologiques generales d'une cellule d'etude des interactions entre un faisceau d'electrons et un gaz adsorbe sont donnees. Un calcul simplifie permet de prevoir les frequences de resonance des ions de surface crees par l'impact des electrons sur le gaz adsorbe. Les donnees experimentales sur l'oxyde de carbone et le neon confirment les previsions du calcul. (auteurs)

  2. The development of a very high stability electrostatic generator (1962); Etude et realisation d'un generateur electrostatique a tres haute stabilite (1962)

    Energy Technology Data Exchange (ETDEWEB)

    Jonckheere, R E.L. [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1962-07-01

    This thesis deals with the study of an electrostatic high voltage generator having a voltage stability of the order of 10{sup -6} per minute. This equipment should be very useful in electron microscopy. The electrostatic generator is studied as a control system element: transfer function, parasitic signals and noise are determined and a mathematical model is proposed. A theoretical study of the open loop transfer function, stability, transient response, voltage stabilization of five different control systems shows which one should be able to fulfill the requirements There follows a detailed study of drift, a description of the actual system and performance data. (author) [French] Cette etude concerne un generateur electrostatique capable de fournir une tres haute tension continue dont la stabilite relative est de l'ordre de 10{sup -6} pendant une minute. Une telle performance rend cet appareillage tres utile en microscopie electronique. La generatrice electrostatique est etudiee en tant qu'element d'un systeme asservi: on determine successivement la fonction de transfert, les perturbations, le bruit de fond et le modele mathematique. L'etude de cinq differents circuits de regulation en ce qui concerne leur fonction de transfert, stabilite, reponse en regime transitoire, attenuation des perturbations, permettra de choisir le systeme qui semble le mieux repondre aux exigences. Viennent ensuite une etude detaillee de la derive, la description de la realisation pratique et les resultats de mesure. (auteur)

  3. A study of the aptitude of soils under natural conditions to retain radiostrontium; Etude de la vocation des sols en place a la retention du radiostrontium

    Energy Technology Data Exchange (ETDEWEB)

    Bovard, P; Grauby, A [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1960-07-01

    Independently of the theoretical study of the propagation of radioactivity in the soil as a result of submersions or of radioactive rain, the authors have studied directly and practically how this radioactivity can vary in the actual soil. To this end a simple, rapid method has been perfected; it makes it possible to maintain for each soil sample the natural parameters (structure, humidity, etc.) without introducing boundary effects. In the laboratory, after charging the soil samples, part of the study of the propagation of radioactivity is done by autoradiography; finally, as a practical application, the study of an atomic site illustrates the methods described. (author) [French] Independamment de l'etude theorique de la propagation de la radioactivite dans le sol a la suite de submersions ou de pluies radioactives, les auteurs ont etudie directement et pratiquement comment pourrait evoluer cette radioactivite dans les sols en place. Pour cela, une methode simple et rapide a ete mise au point; elle permet de conserver pour chaque echantillon de sol, les parametres naturels (structure, humidite, etc...), sans introduire d'effets de paroi. En laboratoire, apres mise en charge des massifs preleves, une partie de l'etude de la propagation des radioelements est realisee par autoradiographie; enfin, une application pratique, l'etude d'un site atomique, illustre l'expose. (auteur)

  4. A study of the aptitude of soils under natural conditions to retain radiostrontium; Etude de la vocation des sols en place a la retention du radiostrontium

    Energy Technology Data Exchange (ETDEWEB)

    Bovard, P.; Grauby, A. [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1960-07-01

    Independently of the theoretical study of the propagation of radioactivity in the soil as a result of submersions or of radioactive rain, the authors have studied directly and practically how this radioactivity can vary in the actual soil. To this end a simple, rapid method has been perfected; it makes it possible to maintain for each soil sample the natural parameters (structure, humidity, etc.) without introducing boundary effects. In the laboratory, after charging the soil samples, part of the study of the propagation of radioactivity is done by autoradiography; finally, as a practical application, the study of an atomic site illustrates the methods described. (author) [French] Independamment de l'etude theorique de la propagation de la radioactivite dans le sol a la suite de submersions ou de pluies radioactives, les auteurs ont etudie directement et pratiquement comment pourrait evoluer cette radioactivite dans les sols en place. Pour cela, une methode simple et rapide a ete mise au point; elle permet de conserver pour chaque echantillon de sol, les parametres naturels (structure, humidite, etc...), sans introduire d'effets de paroi. En laboratoire, apres mise en charge des massifs preleves, une partie de l'etude de la propagation des radioelements est realisee par autoradiographie; enfin, une application pratique, l'etude d'un site atomique, illustre l'expose. (auteur)

  5. Contribution to the study of the stability of water-cooled reactors; Contribution a l'etude de la stabilite des reacteurs refroidis par de l'eau

    Energy Technology Data Exchange (ETDEWEB)

    Coudert, C [Commissariat a l' Energie Atomique, Cadarache (France). Centre d' Etudes Nucleaires

    1969-06-01

    This work is devoted to the study of the stability of reactors cooled by water subjected only to natural convection. It is made up of two parts, a theoretical study and experimental work, each of these parts being devoted to a consideration of linear and non-linear conditions: - calculation of the transfer function of the reactor using neutronic and hydrodynamic linear equations with the determination of the instability threshold; - demonstration of the existence of the limiting oscillation cycle in the case of a linear feedback using MALKIN'S method; - measurement and interpretation of the reactor's transfer functions and of the hydrodynamic transfer functions; and - analysis of the noise due to boiling. (author) [French] Dans ce travail on etudie la stabilite des piles refroidies par de l'eau circulant en convection naturelle. Cette etude se divise en deux parties: un travail theorique et un travail experimental, chacune de ces parties comportant une etude lineaire et une etude non-lineaire: - calcul de la fonction de transfert du reacteur a partir des equations lineaires de la neutronique et de l'hydrodynamique avec determination du seuil d'instabilite; - demonstration de l'existence du cycle limite des oscillations dans le cas d'une retroaction lineaire en utilisant la methode de MALKIN; - mesure et interpretation de la fonction de transfert du reacteur et des fonctions de transfert hydrodynamiques; et - analyse du bruit d'ebullition. (auteur)

  6. The development of a very high stability electrostatic generator (1962); Etude et realisation d'un generateur electrostatique a tres haute stabilite (1962)

    Energy Technology Data Exchange (ETDEWEB)

    Jonckheere, R.E.L. [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1962-07-01

    This thesis deals with the study of an electrostatic high voltage generator having a voltage stability of the order of 10{sup -6} per minute. This equipment should be very useful in electron microscopy. The electrostatic generator is studied as a control system element: transfer function, parasitic signals and noise are determined and a mathematical model is proposed. A theoretical study of the open loop transfer function, stability, transient response, voltage stabilization of five different control systems shows which one should be able to fulfill the requirements There follows a detailed study of drift, a description of the actual system and performance data. (author) [French] Cette etude concerne un generateur electrostatique capable de fournir une tres haute tension continue dont la stabilite relative est de l'ordre de 10{sup -6} pendant une minute. Une telle performance rend cet appareillage tres utile en microscopie electronique. La generatrice electrostatique est etudiee en tant qu'element d'un systeme asservi: on determine successivement la fonction de transfert, les perturbations, le bruit de fond et le modele mathematique. L'etude de cinq differents circuits de regulation en ce qui concerne leur fonction de transfert, stabilite, reponse en regime transitoire, attenuation des perturbations, permettra de choisir le systeme qui semble le mieux repondre aux exigences. Viennent ensuite une etude detaillee de la derive, la description de la realisation pratique et les resultats de mesure. (auteur)

  7. Study of electron groupings in the Saclay linear accelerator; Etude du groupement des electrons dans l'accelerateur lineaire de Saclay

    Energy Technology Data Exchange (ETDEWEB)

    Bergere, R; Veyssiere, A; Beil, H [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1965-07-01

    The classical theory of the linear accelerator buncher does not fit the experimental measurements of the shape of the bunch of electrons performed at Saclay by the method of the energy spectrum. If the spurious effect of the mode converter at the input of the linac is taken into account the theory can fit the experimental results and also explain the variations of the phase of the bunch on the accelerating sine wave. (authors) [French] Une etude classique du groupeur en tete de l'Accelerateur Lineaire de Saclav conduit a des resultats incompatibles avec les resultats experimentaux obtenus sur le groupement des electrons par l'etude du spectre des frequences rayonnees par le faisceau d'electrons ou par l'etude des spectres en energie. Par contre si l'effet parasite du convertisseur de mode a l'entree de l'accelerateur est pris en consideration les resultats theoriques coincident bien avec les resultats experimentaux et permettent en outre d'expliquer les variations du calage en phase des paquets elementaires d'electrons. (auteurs)

  8. Study of thermocouples for control of high temperatures; Etude de thermocouples pour le reperage des hautes temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Villamayor, M [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires; Faculte des Sciences de l' Universite de Lyon - 69 (France)

    1967-07-01

    Previous works have shown that the tungsten-rhenium alloys thermocouples were a good instrument for control of high temperatures. From its, the author has studied the W/W 26 per cent and W 5 per cent Re/W 26 per cent Re french manufactured thermocouples and intended for control of temperatures in nuclear reactors until 2300 deg. C. In 'out-pile' study he determines the general characteristics of these thermocouples: average calibration curves, thermal shocks influence, response times, and alloys allowing the cold source compensation. The evolution of these thermocouples under thermal neutron flux has been determined by 'in-pile' study. The observations have led the author to propose a new type of thermocouples settled of molybdenum-columbium alloys. (author) [French] Des travaux anterieurs ont montre que les thermocouples des alliages tungstene-rhenium etaient susceptibles de reperer avec precision des hautes temperatures. A partir de la, l'auteur a etudie las thermocouples W/W 26 pour cent Re et W 5 pour cent Re/W 26 pour cent Re de fabrication francaise et destines au controle des temperatures dans les reacteurs nucleaires, jusqu'a 2300 deg. C Dans l'etude 'hors-pile' il a determine les caracteristiques generales de ces thermocouples: courbes d'etalonnage moyen, influence des chocs thermiques, temps de reponse, et alliages assurant la compensation de soudure froide. L'etude 'en-pile' a permis de rendre compte de l'evolution de ces thermocouples sous flux neutroniques. Les phenomenes observes ont conduit l'auteur a proposer un nouveau type de thermocouples constitues d'alliages molybdene-niobium. (auteur)

  9. Study of radio-active ions in the atmosphere; Etude des ions radioactifs de l'atmosphere

    Energy Technology Data Exchange (ETDEWEB)

    Renoux, A [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1965-01-01

    A comparative study is made of active, deposits of radon and thoron in suspension in the atmosphere by means of {alpha} radiation counting, using ZELENY tubes, scattering equipment, filter papers or membranes. It has been possible to show the existence of small and large ions which are negative and positive, as well as of neutral radio-active nuclei; their properties are studied. A theoretical interpretation of the results is presented. The average content of radon (using the Ra A concentration) and of Th B in the air has been determined. The radioactive equilibrium between radon and its daughter products in atmospheric air are examined. The techniques developed for active radon and thoron deposits are applied to the study of artificial radio-activity, the analyses being carried out by means of {gamma} spectrometry. (author) [French] On effectue une etude comparative entre les depots actifs du radon et du thoron en suspension dont l'atmosphere a l'aide de comptages de rayonnement {alpha}, en utilisant des tubes de ZELENY, une batterie de diffusion, des papiers filtres ou des membranes. On met ainsi en evidence la presence de petits et gros ions negatifs et positifs, ainsi que celle de noyaux neutres radioactifs, et on etudie leurs proprietes. Une Interpretation theorique des resultats obtenus est developpee. On determine la teneur moyenne de l'air en radon (a partir de la concentration en Ra A) et en Th B. L'equilibre radioactif entre le radon et ses descendants, dans l'air atmospherique, est examine. Les Techniques mises au point pour les depots actifs du radon et du thoron sont appliquees a l'etude de la radioactivite artificielle, les depouillements s'effectuant par spectrometrie {gamma}. (auteur)

  10. Theoretical study for a digital transfer function analyser; Etude theorique pour un transferometre digital

    Energy Technology Data Exchange (ETDEWEB)

    Freycenon, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-07-01

    This study deals with the harmonic analysis of the instantaneous counting rate of a pulse train. This arises from using a fission chamber for reactivity to power transfer function measurements by oscillation methods in reactors. The systematical errors due to the sampling process are computed. The integration carried out when sampling the signal modifies the formulae of the Nyquist theorem on spectrum folding. The statistical errors due to the noise are analysed: it is shown that the bandwidth of the spectral window applied to the noise frequency spectrum is equal to the inverse of the time duration of the experiment. A dead time of 25 per cent of the sampling time does not increase appreciably the bandwidth. A new method is proposed afterwards yielding very approximate results of the Fourier analysis during the experiment. The systematical errors arising from the measuring process are determined, and it is shown that the bandwidth of the corresponding spectral window is still given by the inverse of the time duration of the experiment. (author) [French] Cette etude se rapporte a l'analyse harmonique de la valeur instantanee du taux de comptage d'une suite d'impulsions. On rencontre ce probleme dans l'utilisation de chambres a fission pour les mesures de fonction de transfert reactivite-puissance par la methode d'oscillation dans les piles. On calcule l'erreur systematique due au processus d'echantillonnage ou l'integration operee modifie les formules classiques de recouvrement du spectre. On analyse ensuite les erreurs statistiques dues au bruit de fond. On montre que la largeur de bande de la fenetre spectrale appliquee au spectre de puissance du bruit est donnee par l'inverse du temps de mesure. Un temps mort de 25 pour cent du temps de prelevement n'accroit pas sensiblement cette largeur de bande. On propose ensuite un procede simple qui permet d'obtenir, en cours d'experience, des resultats tres approches de l'analyse de Fourier. On determine les erreurs

  11. Study of the recrystallisation of irradiated uranium; Etude sur l'uranium irradie

    Energy Technology Data Exchange (ETDEWEB)

    Bloch, J; Mustelier, J P; Bussy, P; Blin, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1958-07-01

    1- Study of the recrystallisation of irradiated uranium. The recrystallisation of uranium irradiated to a burnup level of 220 MWj/t, at a temperature of the order of 350 deg. C, has been investigated. The observations were made chiefly by means of micrography an hardness measurements. If the irradiated metal is compared with a cold-drawn metal showing the same shearing of the twinned crystals, and therefore the same rate of plastic deformation, as the irradiated metal, it is noted that the restoring of the irradiated metal takes place at a considerably higher temperature than that of the cold-drawn metal. Pre-crystallisation is very much delayed. Only, a passage of the {alpha}-{beta} transformation point quickly wipes out irradiation effect. 2- Hardening of uranium by irradiation. Using hardness measurements we have studied more especially the effect of very weak irradiations on uranium (integrated flux < 10{sup 16} nvt). The hardness does not increase linearly with the flux, but a period of incubation is observed probably representing the time necessary for saturation of the dislocations. (author)Fren. [French] 1- Etude de la recristallisation de l'uranium irradie. On a etudie la recristallisation d'uranium irradie jusqu'a un taux de combustion de 220 MWj/t a une temperature de l'ordre de 350 deg. C. Les observations ont ete faites principalement a l'aide de la micrographie et de la durete. Si l'on compare le metal irradie avec un metal ecroui presentant le meme cisaillement des macles, donc le meme taux de deformation plastique que le metal irradie, on constate que la restauration du metal irradie se fait a une temperature notablement superieure a celle du metal ecroui. La recristallisation est tres retardee. Seul, un passage du point de transformation {alpha}-{beta} efface rapidement l'effet de l'irradiation. 2- Durcissement de l'uranium par irradiation. Nous avons, a l'aide de la durete, etudie plus particulierement l'effet de tres faibles irrtions sur l

  12. Pore-Scale Flow Simulations: Model Predictions Compared with Experiments on Bi-Dispersed Granular Assemblies Simulation d’écoulements à l’échelle porale : comparaison des prédictions du modèle et d’expériences sur mélanges de billes de verre bi-disperses

    Directory of Open Access Journals (Sweden)

    Tong A.-T.

    2012-11-01

    Full Text Available A method is presented for the simulation of pore flow in granular materials. The numerical model uses a combination of the discrete element method for the solid phase and a novel finite volume formulation for the fluid phase. The solid is modeled as an assembly of spherical particles, where contact interactions are governed by elasto-plastic relations. Incompressible Stokes flow is considered, assuming that inertial forces are small in comparison with viscous forces. Pore geometry and pore connections are defined locally through regular triangulation of spheres, from which a tetrahedral mesh arises. The definition of pore-scale hydraulic conductivities is a key aspect of this model. In this sense, the model is similar to a pore-network model. Permeability measurements on bi-dispersed glass beads are reported and compared with model predictions, validating the definition of local conductivities. Une méthode est présentée pour la simulation de l’écoulement porale dans les matériaux granulaires. Le modèle numérique est basé sur la méthode des éléments discrets pour la phase solide et sur une nouvelle méthode de type volumes finis pour la phase fluide. Le solide est modélisé comme un arrangement de particules sphériques avec des interactions de type élasto-plastique aux contacts. On considère un écoulement de Stokes incompressible en supposant que les forces inertielles sont négligeables par rapport aux forces visqueuses. La géométrie des pores et leur connectivité sont définies sur la base d’une triangulation régulière des sphères qui aboutit à un maillage tétraédrique. La définition des conductivités hydrauliques à l’échelle des pores est un point clef du modèle qui se rapproche sur ce point à des modèles de type pore-network. Des mesures de perméabilités sur des assemblages bi-disperses de billes de verre sont présentées et comparées aux prédictions du modèle ce qui valide la définition des

  13. Production of heavy water in France; Etude sur la production d'eau lourde en France

    Energy Technology Data Exchange (ETDEWEB)

    Lerat, J M; Roth, E [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires; Lefrancois, B [Houllere du Bassin du Nord et du Pas de Calais (France)

    1964-07-01

    Since 1958, studies relating to heavy water production have covered several processes. Each one has been examined to a greater or lesser degree and attention has finally been concentrated on the isotopic exchanges between hydrogen sulphide and water and between ammonia and synthesis gas, the pilot experiment having shown that hydrogen distillation, although technologically satisfactory, was not competitive. NH{sub 3} synthesis gas exchange process; 1) Research was continued and led to the decision to build a production unit, devoted also to the synthesis of ammonia. The process essentially depends on the source of the synthesis gas; the use of a H{sub 2}O/H{sub 2} exchange, which could make it independent, has in fact been rejected for economic reasons. Amongst the various possible designs for the process, the one temperature system was chosen, in spite of certain technological problems, because of it provides: a high enrichment with a reduced number of contact devices. These have now been perfected after large-scale pilot tests. The original industrial experiment to be set in operation will supply useful information for second generation plants, whether they use the one temperature lay out again or whether they adopt the two temperature system. H{sub 2}S-H{sub 2}O exchange process. The pilot plant, described in 1958, has been used for a systematic study of corrosion. It was possible to proceed to preliminary specifications of plants, with 2 or 3 H{sub 2}S - H{sub 2}O stages exchange for primary enrichment. They final stage beyond a 10 to 20 p.100 D{sub 2}O concentration being carried out by the distillation of water. Various heat exchange systems have been studied in detail and it was concluded that choices, as for instance the one of optimum division of the cascade, were eventually to be made according to the particular economic conditions of creation at the chosen location of the plant. (author) [French] Depuis 1958 les etudes concernant la production d

  14. Theoretical study of the paramagnetic scattering of neutrons; Etude theorique de la diffusion paramagnetique des neutrons

    Energy Technology Data Exchange (ETDEWEB)

    Saint-James, D [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1962-02-15

    diverses diffusions (elastique et inelastiques) est calculee pour les terres rares soumises a l'action d'un champ cristallin de symetrie cubique, pour les sesquioxydes d'holmium et d'erbium et pour le chlorure ferreux anhydre (Cl{sub 2}Fe). Elle est suffisamment forte pour permettre une detection experimentale, fournissant ainsi une determination directe de la distance des niveaux par mesure de la variation de longueur d'onde du neutron. Il est, de plus, remarquable que, dans le cas du neodyme, de l'holium et de l'erbium, la section efficace totale calculee pour des neutrons de longueur d'onde aux alentours de l'angstrom soit peu sensible aux effets du champ cristallin. On compare les resultats des calculs ci-dessus aux etudes experimentales existantes. On examine egalement l'influence du moment orbital sur la dependance angulaire de la diffusion pour des ions polarises. La loi I = I{sub 0}sin{sup 2}{beta} n'est qu'approchee; on en donne les limites de validite. On envisage enfin l'influence des interactions d'echange entre les ions magnetiques. Les raies de diffusion elastiques et inelastiques sont elargies. Le comportement de la largeur de raie, avec la longueur du vecteur de diffusion k, est different de celui obtenu dans le cas ou le niveau fondamental de l'ion magnetique est defini par un moment cinetique J . La largeur de raie ne tend pas vers zero avec K. (auteur)

  15. Contribution to the study of samarium-151 excited levels; Contribution a l'etude des niveaux excites du samarium-151

    Energy Technology Data Exchange (ETDEWEB)

    Locard, P [Commissariat a l' Energie Atomique, Centre d' Etudes Nucleaires de Grenoble, 38 (France)

    1967-07-01

    The nucleus of {sup 151}Sm, which has 89 neutrons, happens to be on the lower edge of the deformed nuclei of region II. Therefore, the study of its levels is very interesting for the verification of the goodness of the collective models for deformed nuclei when the deformation is small (we introduce these models in the first chapter). {sup 151}Sm has often been studied, but the direct gamma spectrum measured with a lithium drift-germanium detector (chapter 3) shows many high energy transitions which did not appear in the previous level schemes. In order to settle these transitions, we have undertaken gamma-gamma coincidence spectra (as well as sum-coincidence spectra) experiments with a scintillation spectrometer designed in our laboratory (chapter 2). The investigation of the intensities of these coincidences leads us to modify the last proposed level schemes: we suppress the levels at 405,5 and 650 keV, we add levels at 245,6 - 306,6 - 522 - 952 and 962 keV. We have also verified the multipolarities of the main transitions and measured the half-lives of a few levels (chapter 3) (we find a half-life of 1.1 {+-} 0.5 nanosecond for the level at 167,7 keV). In chapter 4, we compare our results to the predictions of the models described in chapter 1. (author) [French] Le noyau de {sup 151}Sm, qui possede 89 neutrons, se trouve a la limite inferieure des noyaux deformes de la region II. L'etude de ses niveaux excites est donc d'un interet tout particulier pour la verification de la validite des differents modeles collectifs pour les noyaux deformes, lorsque la deformation est petite (nous introduisons ces modeles dans un premier chapitre). Le {sup 151}Sm a deja fait l'objet de nombreuses etudes, mais le spectre gamma direct fait avec une jonction de germanium compense au lithium (chapitre 3), nous a montre l'existence d'un grand nombre de transitions de hautes energies qui ne sont pas placees dans les schemas proposes jusqu'a ce jour. Pour preciser la place de ces

  16. Aerodynamic and thermal studies of cans of gas cooled fuel elements; Etudes aerodynamiques et thermiques de gaines d'elements combustibles refroidis par gaz

    Energy Technology Data Exchange (ETDEWEB)

    Gelin, P [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires; Milliat, J P [Electricite de France (EDF), 75 - Paris (France)

    1964-07-01

    Research on clusters was undertaken at the CEA in 1959, while studies on herring-bone cans were developed at the EDF Laboratory at Chatou and the CEA laboratory at Saclay at the end of 1959. In 1962, a general study on corrugations was begun at the Saclay Laboratory with a view to improving the clusters, and continued later in both laboratories relative to the internal cooling of annular fuel elements. As these studies progressed, trial facilities were extended while experimental methods have improved constantly. At the present time, both laboratories, working in complete collaboration, have powerful means at their disposal. Work on the clusters has been concerned chiefly with pressure losses due to the assembly parts, and with the temperature variations around the elements of the cluster. In this way, we have been able to determine satisfactorily the hot points of the can, the deformations of the rods and the conditions of stability of these deformations. In the case of the herring-bone cans, studies have been directed to the evolution of performances as a function of the geometric parameters on the one hand, and to the special aerodynamic and thermal features caused by the fins and by interruptions of cartridge on the other hand. These studies have led to a very thorough knowledge of the cartridges chosen for the reactors EDF 2 and EDF 3, and now open up very hopeful prospects for future reactors, particularly those fitted with annular elements; among the alternatives suitable for the inner surface of the annular element can, corrugations and longitudinal fins have been fairly extensively tested over a wide range of Reynolds number. (authors) [French] Les etudes de grappes ont ete entreprises au C.E.A. en 1959, tandis que les etudes de gaines a chevrons se sont developpees au Laboratoire de Chatou de l'EDF et au Laboratoire de Saclay du C.E.A. a la fin de l'annee 1959. En 1962, une etude generale sur les corrugations a ete commencee au Laboratoire de Saclay pour

  17. Development of a slow mono-kinetic electron source; Etude et realisation d'une source d'electrons lents monocinetiques

    Energy Technology Data Exchange (ETDEWEB)

    Ballu, Y [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1968-06-01

    A comparative study of already existing slow mono-kinetic electron guns shows that those using a 127 degrees electrostatic selector can be improved still further to arrive at the performances obtained with spherical 180 degrees selectors for example. For this reason we have examined the 127 degrees selector theoretically in more detail; it appears that it should be possible to obtain a resolving power better than 30 mV for a current of about 10{sup -10} A, on condition that certain improvements be made to the instrument as normally designed, in particular concerning the entrance and exit slides. As a result, the usual suppressors for the scattered electrons are no longer necessary. The development of this apparatus has been carried out with particular care: the dimensional characteristics are fixed to an accuracy of a few microns, although the instrument can be baked out at 300 C. The experimental results are in excellent agreement with the theoretical predictions: for a current of 10{sup -10} A, the measured resolving power is 24 {+-} 4 mV. The easy detection of the He{sup -} resonance line at 19.3 eV has confirmed the advantages of this apparatus for the study of atomic collisions. (author) [French] L'etude comparative des canons a electrons lents monocinetiques realises jusqu'a present montre que ceux qui utilisent un selecteur electrostatique a 127 degres peuvent etre encore perfectionnes en vue de parvenir aux performances obtenues avec les selecteurs spheriques a 180 degres par exemple. D'ou notre etude theorique approfondie du selecteur a 127 degres qui nous a conduit a esperer une resolution meilleure que 30 mV pour un courant de l'ordre de 10{sup -10} A a condition d'apporter certaines ameliorations a la conception usuelle de cet instrument notamment au niveau des fentes d'entree et de sortie. Par voie de consequence les suppresseurs habituels d'electrons parasites deviennent inutiles. L'etude et la mise au point de l'appareil ont fait l'objet de soins

  18. Study of cerenkov radiation. Production of {gamma} rays by electron accelerators; Etude du rayonnement de freinage. Production de rayons {gamma} par des accelerateurs d'electrons

    Energy Technology Data Exchange (ETDEWEB)

    Bernard, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1961-07-01

    This study is a critical comparison of the theories of Bremsstrahlung. Experimental results obtained by the production of {gamma} radiation with electron accelerators are compared to the theoretical results in order to estimate the extent to which the various theories are valid. (author) [French] Cette etude est une synthese des theories du rayonnement de freinage. Des resultats experimentaux, obtenus par la production de rayonnements {gamma} avec des accelerateurs d'electrons, sont compares aux resultats theoriques afin d'evaluer les domaines de validite des diverses theories. (auteur)

  19. Use of hydraulic and aerial mock up to study atmospheric pollution; L'utilisation des maquettes aeriennes et hydrauliques pour l'etude de la pollution atmospherique

    Energy Technology Data Exchange (ETDEWEB)

    Facy, L; Perrin De Brichambaut, C; Doury, A; Le Quinio, R

    1962-07-01

    Fundamental studies on turbulent atmospheric diffusion of finely divided particles, cannot remain on a purely theoretical basis. Further experimental studies must be considered. - In full scale, from accidental and induced releases. - On a reduced scale, in aerodynamic wind tunnels or hydraulic water tunnels. A first set of studies on reduced scale models has been worked out according to a contract between French 'Meteorologie Nationale' and French 'Commissariat a l'Energie Atomique' and with the Collaboration of Saint-Cyr 'Institut Aerotechnique'. Essentially two kinds of results have been obtained: - The mathematical model of SUTTON for the turbulent diffusion in the atmosphere, deduced from the SUTTON theory, generally used by us, has been correctly verified, qualitatively and quantitatively whenever experiments were consistent with the theory conditions. - The quantitative assays of photographic and cinematographic visualization have given precise details on the phenomena inaccessible to calculations, due to the influence of obstacles and release conditions. - Generally, it can be asserted, that the atmospheric pollution studies are worked out by mock up experimentations and that, in some cases these experiments never can be replaced by mathematically pure models. (authors) [French] Les etudes fondamentales portant sur la diffusion turbulente dans l'atmosphere de quantites de matieres finement divisees, ne peuvent se maintenir sur un plan exclusivement theorique. C'est pourquoi des etudes experimentales complementaires doivent etre obligatoirement envisagees: - en vraie grandeur, a partir d'emissions accidentelles ou provoquees; - sur modeles reduits, en soufflerie aerodynamique ou en veine hydraulique. En ce qui concerne les modeles reduits, une premiere serie d'etudes a pu etre menee a bien, dans le cadre d'un contrat passe entre la Meteorologie Nationale et le Commissariat a l'Energie Atomique, et avec la collaboration de l'Institut Aerotechnique de Saint

  20. Studies of magnetism with inelastic scattering of cold neutrons; Etudes de magnetisme realisees a l'aide de la diffusion inelastique de neutrons froids

    Energy Technology Data Exchange (ETDEWEB)

    Jacrot, B [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-07-01

    Inelastic scattering of cold neutrons can be used to study some aspects of magnetism: spins waves, exchange integrals, vicinity of Curie point. After description of the experimental set-up, several experiments, in the fields mentioned above, are analysed. (author) [French] La technique de diffusion inelastique des neutrons froids est utilisee pour etudier certains aspects du magnetisme: ondes de spins, integrales d'echange, etude au voisinage du point de Curie, etc. Apres une description de l'appareillage, on analyse diverses experiences effectuees dans les domaines enumeres plus haut. (auteur)

  1. Probes and their application to the study of H.F. plasmoids; Les sondes et leur application dans l'etude des plasmoides H.F

    Energy Technology Data Exchange (ETDEWEB)

    Brunet, A; Geller, R [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1960-07-01

    In the first part of this paper, we study the single Langmuir probe and the double-probe method. In the second part, we describe the probe-technique in connection with R.F. plasmoids. (author) [French] Dans la premiere partie de cet article, nous rappelons les principes d'utilisation de la sonde simple de Langmuir ainsi que la methode de la sonde double. La seconde partie est consacree a la pratique des sondes dans l'etude des plasmoides H.F. (auteur)

  2. Method of research and study of uranium deposits; Methode de recherches et d'etude des gites uraniferes

    Energy Technology Data Exchange (ETDEWEB)

    Lenoble, A [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1955-07-01

    In a first part, the author gives a fast retrospective of the evaluations of the uranium deposits in the French Union. The author established a method of prospecting and studying, modifiable at all times following the experiences and the results, permitting to make the general inventory of uranium resources on the territory. The method is based on: 1 - the determination of geological guides in order to mark the most promising deposits, 2 - the definition of a methodology adapted to every steps of the research, 3 - the choice of the material adapted for each of the steps. This method, originally established for the prospecting in crystalline massifs, is adaptable to the prospecting of the sedimentary formations. (M.B.) [French] Dans une premiere partie, l'auteur donne une retrospective rapide des estimations des gites uraniferes dans l'Union Francaise. L'auteur a etabli une methode de prospection et d'etude, modifiable a tout instant suivant les experiences et les resultats, permettant de faire l'inventaire general des ressources en uranium du territoire. La methode est base sur: 1 - la determination de guides geologiques afin de reperer les gisements les plus prometteurs, 2 - la definition d'une methodologie adaptee a chaque stade de la recherche, 3 - le choix du materiel adapte pour chacun des stades. Cette methode, a l'origine etablie pour la prospection en massifs cristallins, est adaptable a la prospection des formations sedimentaires. (M.B.)

  3. Some equipment for graphite research in swimming pool reactors; Quelques dispositifs d'etude du graphite dans les piles piscines

    Energy Technology Data Exchange (ETDEWEB)

    Seguin, M; Arragon, Ph; Dupont, G; Gentil, J; Tanis, G [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1964-07-01

    The irradiation devices described are used for research concerning reactors of the natural uranium type, moderated by graphite and cooled by carbon dioxide. The devices are generally designed for use in swimming pool reactors. The following points have been particularly studied: - maximum use of the irradiation volume, - use of the simplest technological solutions, - standardization of certain constituent parts. This standardization calls for precision machining and careful assembling; these requirements are also true when a relatively low irradiation temperature is required and the nuclear heating is pronounced. Finally, the design of these devices is suitable for the irradiation of other fissile or non-fissile materials. (authors) [French] Les dispositifs d'irradiation decrits servent aux etudes relatives a la filiere des reacteurs a uranium naturel, moderes au graphite et refroidis par le gaz carbonique. Ils sont generalement concus pour etre utilises dans des piles piscines. L'accent a ete mis sur: - l'utilisation au maximum du volume d'irradiation, - le recours aux solutions technologiques les plus simples, - la standardisation de certaines parties constitutives. Cette standardisation impose un usinage precis et un montage soigne, lesquels sont egalement necessaires lorsqu'on doit obtenir une temperature d'irradiation relativement basse alors que l'echauffement nucleaire est important. Enfin, la conception de ces dispositifs est valable pour irradier d'autres materiaux non fissiles ou fissiles. (auteurs)

  4. Serotonin transporter gene polymorphism and myocardial infarction: Etude Cas-Témoins de l'Infarctus du Myocarde (ECTIM).

    Science.gov (United States)

    Fumeron, Frédéric; Betoulle, Dina; Nicaud, Viviane; Evans, Alun; Kee, Frank; Ruidavets, Jean-Bernard; Arveiler, Dominique; Luc, Gérald; Cambien, François

    2002-06-25

    Depression is a risk factor for myocardial infarction (MI). Selective serotonin reuptake inhibitors reduce this risk. The site of action is the serotonin transporter (SLC6A4), which is expressed in brain and blood cells. A functional polymorphism in the promoter region of the SLC6A4 gene has been described. This polymorphism may be associated with the risk of MI. The SLC6A4 polymorphism has been investigated by polymerase chain reaction in 671 male patients with MI and in 688 controls from the Etude Cas-Témoins de l'Infarctus du Myocarde (ECTIM) multicentric study. Percentages for LL, LS, and SS genotypes were 35.5%, 45.4%, and 19.1%, respectively, for cases versus 28.1%, 49.1%, and 22.8%, respectively, for controls. S allele frequency was 41.8% and 47.4% for cases and controls, respectively. After adjustment for age and center by using multivariable logistic regression, the odds ratio for MI associated with the LL genotype was 1.40 (95% CI 1.11 to 1.76, P=0.0047). The LL genotype of the SLC6A4 polymorphism is associated with a higher risk of MI. This could be attributable to the effect of the polymorphism on serotonin-mediated platelet activation or smooth muscle cell proliferation or on other risk factors, such as depression or response to stress.

  5. Cognitive decline is associated with systemic oxidative stress: the EVA study. Etude du Vieillissement Artériel.

    Science.gov (United States)

    Berr, C; Balansard, B; Arnaud, J; Roussel, A M; Alpérovitch, A

    2000-10-01

    To determine whether systemic oxidative stress status is associated with cognitive decline. A longitudinal population-based study. A cohort study of older subjects in Nantes, France. A total of 1166 high cognitive functioning subjects aged 60 to 70 in the Etude du Vieillissement Arteriel (EVA) cohort with a 4 year follow-up. Subjects completed a baseline interview and a global cognitive test (Mini-Mental Status Examination (MMSE)). Blood samples were obtained at baseline to determine plasma levels of selenium, carotenoids, thiobarbituric acid reactant substances (TBARS), an indicator of lipoperoxidation, and red blood cell vitamin E. Risk of cognitive decline, defined as a loss of 3 points in MMSE score between baseline and the 4 year follow-up, was assessed by oxidative stress level. Subjects with the highest levels of TBARS show an increased risk of cognitive decline (adjusted odds ratio (OR) = 2.25; confidence interval (CI) 95% = 1.26-4.02). This result is reinforced in the lower antioxidant status subgroup. Subjects with low levels of selenium have an increased risk of cognitive decline (OR = 1.58; CI 95% = 1.08-2.31) after adjustment for various confounding factors. These results suggest that increased levels of oxidative stress and/or antioxidant deficiencies may pose risk factors for cognitive decline. The direct implication of oxidative stress in vascular and neurodegenerative mechanisms that lead to cognitive impairment should be further explored.

  6. Some aspects of nuclear graphite production in France; Etude generale sur les graphites nucleaires produits en France

    Energy Technology Data Exchange (ETDEWEB)

    Gueron, J; Hering, H [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires; Legendre, A [Pechiney, 75 - Paris (France)

    1958-07-01

    1) Manufacturing: A summary and results on the CEA-Pechiney purification process are given. Variations in the preparation of green pastes and their effects on graphitized material are described. 2) Physical and mechanical properties: Results are given on: - Statistics of dimensional variatior products having square cross-section. - Statistical variation of thermal expansion coefficients and of electrical conductivity. - Density of normals to carbon layer planes and their connexion with thermal expansion. - Stress-strain cycles and conclusions drawn therefrom. - Mechanical resistance and gas permeability of items for supporting fuel elements. 3) Behaviour under radiation: Alteration under radiation of French graphites irradiated either in G1 pile or in experimental piles, and thermal annealing of those alterations, are given. (author)Fren. [French] 1) Fabrication: On resume le procede d'epuration CEA-PECHINEY, ainsi que diverses modalites de preparation des pates et on expose les resultats obtenus. 2) Proprietes physiques et mecaniques: On indique le resultat d'etudes sur: - la statistique des dimensions de produits a section carree. - celle des variations des coefficients de dilatation thermique et de la conductibilite electrique. - la densite des normales aux plans graphitiques et leur connexion avec la dilatation thermique. - la compression mecanique du graphite. - la solidite mecanique et la permeabilite aux gaz de pieces destinees a supporter des cartouches de combustible. 3) Tenue sous rayonnement: Modification sous rayonnement des graphites fran is irradies soit dans la pile G1, soit dans des piles experimentales, et guerison thermique de ces modifications. (auteur)

  7. Etude des phenomenes dynamiques ultrarapides et des caracteristiques impulsionnelles d'emission terahertz du supraconducteur YBCO

    Science.gov (United States)

    Savard, Stephane

    Les premieres etudes d'antennes a base de supraconducteurs a haute temperature critique emettant une impulsion electromagnetique dont le contenu en frequence se situe dans le domaine terahertz remontent a 1996. Une antenne supraconductrice est formee d'un micro-pont d'une couche mince supraconductrice sur lequel un courant continu est applique. Un faisceau laser dans le visible est focalise sur le micro-pont et place le supraconducteur dans un etat hors-equilibre ou des paires sont brisees. Grace a la relaxation des quasiparticules en surplus et eventuellement de la reformation des paires supraconductrices, nous pouvons etudier la nature de la supraconductivite. L'analyse de la cinetique temporelle du champ electromagnetique emis par une telle antenne terahertz supraconductrice s'est averee utile pour decrire qualitativement les caracteristiques de celle-ci en fonction des parametres d'operation tels que le courant applique, la temperature et la puissance d'excitation. La comprehension de l'etat hors-equilibre est la cle pour comprendre le fonctionnement des antennes terahertz supraconductrices a haute temperature critique. Dans le but de comprendre ultimement cet etat hors-equilibre, nous avions besoin d'une methode et d'un modele pour extraire de facon plus systematique les proprietes intrinseques du materiau qui compose l'antenne terahertz a partir des caracteristiques d'emission de celle-ci. Nous avons developpe une procedure pour calibrer le spectrometre dans le domaine temporel en utilisant des antennes terahertz de GaAs bombarde aux protons H+ comme emetteur et detecteur. Une fois le montage calibre, nous y avons insere une antenne emettrice dipolaire de YBa 2Cu3O7-delta . Un modele avec des fonctions exponentielles de montee et de descente du signal est utilise pour lisser le spectre du champ electromagnetique de l'antenne de YBa 2Cu3O7-delta, ce qui nous permet d'extraire les proprietes intrinseques de ce dernier. Pour confirmer la validite du modele

  8. Studies of the Stabilization of Superconductor Coils; Etudes sur la Stabilisation des Bobines Supraconductrices

    Energy Technology Data Exchange (ETDEWEB)

    Donadieu, L.; Maldy, J. [Compagnie Generale d' Electricite Marcoussis (France)

    1966-12-15

    operation of the coil will be stable and the passage of the I-B characteristic of the material will be reversible; (b) Ic < Im, the operation of the coil is unstable and any sufficiently large disturbances (flux jump, movement of windings, etc. ) can produce blocking. This is inevitably the case with the large coils whose operational limit tends towards Im. Different coils have been constructed with more or leas stabilised materials and the results of tests on them are analysed as a' function of the previous theories. There Is a full discussion of the advantages and disadvantages of coil stabilizations. (author) [French] La stabilisation de l'intensite du courant dans les bobinages supra-conducteurs, qui apparait d'une importance capitale pour la construction de bobinages de grande taille , est etudiee a la fois du point de vue theorique et du point de vue experiment a l. L'etude de la dynamique de la transition d'un supraconducteur transportant du courant, entre l ' e t at supraconducteur a resistance nulle et l ' e tat a resistance normale ( l e blocage), revele l'existence d'une intensite caracteristique, Im, pour laquelle la vitesse de propagation de la region normale est nulle. Cette intensite depend directement des echanges de chaleur entre le supraconducteur et le milieu ambiant, et de la resistance du materiau a l ' e t a t normal; Im depend indirectement de l'intensite du champ magnetique. Si un supraconducteur est utilise avec une intensite de courant inferieure a Im, la vitesse de propagation est negative et le supraconducteur est capable eventuellement de realiser la transition inverse de l ' e t a t normal a l ' e t a t supraconducteur. On peut montrer que pour une intensite Is telle que Is = Im/ Square-Root 2 , la vitesse de propagation qui est negative devient infiniment grande. L'existence de ces 2 intensites caracteristiques permet de distinguer trois cas de comportement differents selon l'intensite du courant qui parcourt le supraconducteur. L'auteur a

  9. Electrochemical study in molten potassium thiocyanate; Etude electrochimique dans le thiocyanate de potassium fondu

    Energy Technology Data Exchange (ETDEWEB)

    Metzger, G [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-07-01

    comparaison des valeurs des potentiels trouves dans le thiocyanate avec celles qui sont connues pour d'autres solvants fondus, nous a permis de rapprocher les proprietes du thiocyanate de celles de certains sels comme les chlorures ou les nitrates fondus. Ainsi les proprietes complexantes de SCN{sup -} vis-a-vis de Cu{sup +} exaltent les proprietes oxydantes de Cu{sup 2+}. Une etude polarographique de complexes dans le bain fondu, nous a revele l'existence de deux complexes cupro-cyanures de formules Cu(CN){sup -}{sub 2} et Cu(CN){sup 3-}{sub 4}, dont nous avons determine, experimentalement les constantes de dissociation. (auteur)

  10. Study of uranium-titanium diffusion; Etude de la diffusion uranium-titane

    Energy Technology Data Exchange (ETDEWEB)

    Adda, Y; Philibert, J [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires; Institut de Recherches de la Siderurgie Francaise (IRSID), 78 - Saint-Germain-en-Laye (France)

    1959-07-01

    . (author) [French] Dans le cadre de recherches sur la diffusion chimique de l'uranium et des metaux de transition, nous avons etudie le systeme uranium-titane. Les couples de diffusion sont prepares, suivant une technique que avons deja decrite, par soudage sous pression de plaquettes d'uranium et de titane. Apres traitement de diffusion sous vide, les echantillons sont etudies micrographiquement suivant une section polie. Cet examen nous a permis de mettre en evidence une diffusion intergranulaire au-dessous de 650 deg. C; aux temperatures superieures, la diffusion a lieu uniquement en volume, et la zone de diffusion apparait alors comme une succession de bandes qui se distinguent par leur aspect micrographique. L'etude de la cinetique de croissance de ces bandes nous a permis de mesurer les 'coefficients de penetration' correspondants. En outre, nous avons observe, dans la zone de diffusion, des variations importantes de microdurete, que nous avons cherche a relier a la variation de concentration. Celle-ci est mesuree par analyse ponctuelle au moyen de la microsonde de Castaing. Nous avons ainsi etabli avec precision les courbes concentration-penetration pour des temperatures comprises entre 950 et 1075 deg. C. A partir de ces courbes nous avons calcule le coefficient de diffusion D en fonction de la concentration c par la methode de Matano. La coube D(c) presente a toutes les temperatures une forme en U, deja observee pour le systeme U-Zr. L'energie d'activation passe par un maximum de 42 kcal/g pour une concentration atomique 0,5. Bien que nous n'ayons observe que rarement la presence de pores dans la zone de diffusion, nous avons neanmoins observe un effet Kirkendall important en etudiant les deplacements x{sub i} d'un interface repere au moyen de fils de tungstene. Ces deplacements peuvent s'exprimer en fonction du temps t et de la temperature T par la relation x{sub i} = 0,9 t {sup 1/2} exp ( - 14600/(RT)). Enfin, au moyen des equations de Darken nous avons calcule

  11. Glass packages in interim storage; Les verres dans les stockages

    Energy Technology Data Exchange (ETDEWEB)

    Jacquet-Francillon, N

    1994-10-01

    This report summarize the current state of knowledge concerning the behavior of type C waste packages consisting of vitrified high-level solutions produced by reprocessing spent fuel. The composition and the physical and chemical properties of the feed solutions are reviewed, and the vitrification process is described. Sodium alumino-borosilicate glass compositions are generally employed - the glass used at la Hague for LWR fuel solutions, for example, contains 45 % SiO{sub 2}. The major physical, chemical, mechanical and thermal properties of the glass are reviewed. In order to allow their thermal power to diminish, the 3630 glass packages produced (as of January 1993) in the vitrification facilities at Marcoule and La Hague are placed in interim storage for several decades. The actual interim storage period has not been defined, as it is closely related to the concept and organization selected for the final destination of the packages: a geological repository. The glass behavior under irradiation is described. Considerable basic and applied research has been conducted to assess the aqueous leaching behavior of nuclear containment glass. The effects of various repository parameters (temperature, flow rate, nature of the environmental materials) have been investigated. The experimental findings have been used to specify a model describing the kinetics of aqueous corrosion of the glass. More generally all the ``source term`` models developed in France by the CEA or by ANDRA are summarized. (author). 152 refs., 33 figs.

  12. Denkers over eenwording van heinde en verre - Ghandi en Europa

    NARCIS (Netherlands)

    prof. dr. Ben Hoetjes

    2006-01-01

    Europa raakt in de publieke beeldvorming in Nederland duidelijk op de achtergrond. Andere zaken - het nieuwe zorgstelsel, de pensioenen, de misdaad, het internationale terrorisme, mensenrechtenschendingen, natuurrampen - hebben allang de voorpagina's overgenomen. Voor Europa-aanhangers zoals

  13. Preliminary study of the preparation of uranium 232 by irradiation of protactinium 231; Etude preliminaire a la preparation d'uranium 232 par irradiation de protactinium 231

    Energy Technology Data Exchange (ETDEWEB)

    Guillot, Ph. [Commissariat a l' Energie Atomique, Fontenay aux Roses (France). Centre d' Etudes Nucleaires

    1965-07-01

    A bibliography about preparation of uranium 232 is done. This even-even isotope of uranium is suitable for radioactive tracer, neutron source through {alpha},n reaction and heat source applications. The irradiation of protactinium 231, the chemical separation and the purification of uranium are studied. (author) [French] Une etude bibliographique de la preparation d'uranium 232 a ete effectuee. Cet isotope pair-pair de l'uranium peut etre utilise en tant que traceur, source d'energie et source de neutrons, lorsqu'il est melange a un element leger tel le beryllium. Une etude du taux de formation des isotopes produits, lors de l'irradiation du protactinium 231 - une des manieres d'obtenir l'uranium 232 - a ete faite a l'aide d'un programme passe sur ordinateur. Les problemes poses par la separation chimique et la purification de l'uranium ont ete egalement envisages dans ce rapport. (auteur)

  14. Castor and Pollux - shielded cells for studying fuel treatment processes; Castor et Pollux chaines blindees d'etudes de procedes de traitement de combustibles

    Energy Technology Data Exchange (ETDEWEB)

    Faudot, G; Bathellier, A [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1969-07-01

    CASTOR and POLLUX, two alpha, beta, gamma cells are described in the present paper. They are located in the CEN at Fontenay-aux-Roses (France). They are designed for improvement studies of the various aqueous separation processes used in irradiated fuels reprocessing plants. Located in the same air-tight steel encasement, they arc inter-connected by a pneumatic transfer. These two cells have a similar in-line conception and they include: a gamma shielding in lead of 10 cm of thickness; an inner air-tight box, made with stainless steel and plexiglas, is maintained in lowering in comparison to room pressure. Eleven Hobson model seven master-slave manipulators allow inner manipulations. Then the inner equipment is described briefly. (author) [French] Le present document decrit les cellules alpha, beta, gamma CASTOR et POLLUX edifiees au Centre d'Etudes Nucleaires de Fontenay-aux-Roses. Elles sont destinees aux etudes visant a l'amelioration des procedes de separation par voie aqueuse utilises dans les usines de retraitement des combustibles irradies. Ces deux chaines, implantees dans le meme caisson et reliees par convoyeur pneumatique, sont de conception identique et comprennent: une protection biologique constituee par 10 cm d'epaisseur de plomb; une enceinte interieure etanche alpha, en acier inoxidable et plexiglas, maintenue en depression. Des telemanipulateurs Hobson, modele 7, permettent les manipulations interieures. On decrit ensuite brievement les installations annexes. (auteur)

  15. Study of point defects in pure iron by means of electrical resistivity; Etude au moyen de la resistivite electrique des defauts ponctuels dans le fer pur

    Energy Technology Data Exchange (ETDEWEB)

    Minier-Cassayre, C [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1965-04-01

    In the first part of this work, after having reviewed the production, observation and the annealing of point defects In metals, we resume the present state of research. In the second part, we explain the techniques we have employed to produce point defects at low temperatures: irradiation, quenching and cold-work; and go on to the study of their migration and annealing. The experimental results obtained for pure iron and for iron containing certain impurities are presented in the third part. In the fourth part we suggest a model which explains the different stages of annealing observed, and their properties. We then compare the energies of interaction between point defects with the values deduced from the theory of elasticity. (author) [French] Dans la premiere partie de cette etude, apres avoir passe en revue la production, l'observation et les modes de guerison des defauts ponctuels dans les metaux, nous exposons l'etat actuel des recherches. La seconde partie est consacree aux techniques que nous avons employees pour produire des defauts ponctuels a basse temperature: irradiations, trempe et ecrouissage puis a l'etude de leur migration et de leur guerison. Les resultats experimentaux obtenus dans le fer pur et le fer contenant certaines impuretes sont presentes dans le troisieme chapitre. Nous proposons ensuite un modele qui explique les differents stades de guerison observes et leurs nombreuses proprietes: nous comparons les energies d'interaction entre defauts ponctuels aux valeurs que l'on pourrait deduire d'un modele elastique. (auteur)

  16. The ultrasonic copper and brass decontamination study; Etude de la decontamination du cuivre et des laitons en presence d'ultra-sons

    Energy Technology Data Exchange (ETDEWEB)

    Courtault, J; Kerdelleau, J de; Mestre, E [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1965-07-01

    The use of ultra-sounds as a decontamination technic does not bring an absolute solution. As a function of the materials it seemed necessary to find what was the optimum conditions for using the ultra-sounds and to define not only the ultra-sonic factors but also the chemical solutions which bring some appreciable decontamination factors without bringing any too important corrosion processus. This report gives the results of this study applied to copper and brass. This study allowed to select some effective treatment baths on the two types of contamination: plutonium and fission products. (authors) [French] L'emploi des ultra-sons comme technique de decontamination n'amene pas une solution absolue. Il est apparu necessaire de rechercher en fonction de la nature du materiau a decontaminer quelles etaient les conditions optimales d'utilisation des ultra-sons et de definir alors non seulement les facteurs ultrasoniques mais encore les solutions chimiques qui apportent des facteurs de decontamination appreciables sans amener des phenomenes de corrosion trop importants. Ce rapport donne les resultats de cette etude appliquee au cuivre et aux laitons. Cette etude a permis de selectionner des bains de traitement efficaces dans les deux cas de contamination: plutonium et produits de fission. (auteurs)

  17. A crystallographic and spectroscopic study of crystal sites in the 'spinel' structure; Etude cristallographique et spectroscopique des sites cristallins dans la structure 'spinelle'

    Energy Technology Data Exchange (ETDEWEB)

    Drifford, M [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1967-06-15

    A crystallographic study on magnesium aluminates led to the determination of crystal site average distortion. A spectroscopic study of transition elements doped spinels gave the position of the doping element in tetrahedral (A) or octahedral (B) sites, and the local distortion of the latter. The comparison of average and local parameters points to differences in the behaviour of doping elements and shows the size of (A) sites are independent of the host crystal composition while the average size of (B) sites varies with the composition. (author) [French] Une etude cristallographique des aluminates de magnesium a permis de determiner la deformation moyenne des sites cristallins. Une etude spectroscopique des aluminates de magnesium dopes avec des elements de transition a permis de localiser les dopants entre les sites tetraedriques (A) et octaedriques (B) et d'etudier la deformation locale de ces sites. La comparaison entre les parametres moyens et locaux a caracterise le comportement du dopant et montre que les dimensions des sites (A) sont independantes de la composition de la matrice, alors que les caracteristiques geometriques moyennes des sites (B) varient continument avec la composition. (auteur)

  18. Stable isotope separation; Separations physicochimiques d'isotopes stables realisations et etudes de petites productions

    Energy Technology Data Exchange (ETDEWEB)

    Botter, F; Molinari, Ph; Dirian, G [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-07-01

    capacite totale environ 2 litres, il a ete realise un appareil preparatif, de faible volume mort, permettant de produire 1 litre de D{sub 2} pur a partir des melange 50 p.100 D{sub 2}, 50 p.100 H{sub 2} en 12 minutes environ. Sur le plan theorique, en premiere approximation, nous assimilions la chromatographie a un fractionnement contre courant en negligeant resistance superficielle a l'echange ainsi que diffusions longitudinale et laterale. On etablit graphiquement ou par calcul, le nombre de plateaux theoriques necessires a un certain enrichissement de la phase gazeuse ce qui permet de comparer l'efficacite de colonnes qui different par leur masse palladiee. DIFFUSION THERMIQUE: Afin d'assurer une separation des isotopes de l'hydrogene, on a realise une installation de diffusion thermique construite en acier inoxydable et entierement telecommandee. La cascade de separation se compose de deux couples identiques de colonnes a fil central chaud. Chaque couple peut travailler isolement ou etre relie par thermosyphon. La temperature du fil chaud est de l'ordre de 1000 deg C entretenue par courant redresse. Avec cette installation, des echantillons d'hydrogene a la teneur isotopique en deuterium inferieure a 0,5 ppm. ont ete obtenus a partir d'un gaz initial a 32 ppm. Il a ainsi ete possible de preparer du tritium a la teneur de 99,3 p. 100 a partir d'un gaz d'une teneur initale de 6 p. 100. Pour la separation quantitative du Xenon enrichi cinq fois en {sup 124}Xe par thermodiffusion on a construit deux cascades identiques de 5 colonnes fonctionnant en parallele, reliees par thermosyphon ou par tube capillaire lie a un oscillateur thermique de gaz. Le fil central en tungstene fonctionne a 1200 deg C. Les colonnes sont groupees a la facon d'un faisceau tubulaire d'un echangeur de chaleur dans une virole de 30 cm de diametre ou circule l'eau de refroidissement. Des etudes sont en cours pour augmenter le facteur de separation de la cascade en utilisant un gaz auxiliaire. ECHANGE

  19. Etude expérimentale et numérique de la résistance interlaminaire en mode I de thermoplastiques à renfort tissé = Experimental and numerical study of the mode I interlaminar resistance of thermoplastic composites

    OpenAIRE

    Avril , Christophe; Perreux , Dominique; Thiebaud , Frédéric; Reck , B.

    2009-01-01

    National audience; Les structures de maintien des projectiles accélérés à l'aide du lanceur électromagnétique PEGASUS de l'ISL sont réalisées sous la forme d'une stratification de couches de polymère renforcées de verre tissé. Une telle composition leur confère leur propriété d'isolant électrique et une résistance mécanique compatible avec les efforts extrêmes qu'ils sont appelés à subir. Le mode d'endommagement le plus couramment observé sur les radiographies-éclair prises en cours d'accélér...

  20. Composes inter-halogenes sous pression: etude des transformations structurales dans le monobromure d'iode sous forme dense

    Science.gov (United States)

    Bouchard, Alexandre

    La famille des composes halogenes et inter-halogenes representent des solides moleculaires adoptant des phases denses communes avec des solides moleculaires diatomiques comme l'azote et l'hydrogene. Parmi les transformations structurales et electroniques induites sous haute pression et observees dans ces solides, on note, entre autres, la dissociation moleculaire et la metallisation. De plus, l'etude des phases denses de l'iode a permis recemment l'observation d'une structure cristalline possedant une modulation dite incommensurable, c'est-a-dire une modulation possedant une periodicite differente de celle de la structure cristalline, jetant ainsi une lumiere nouvelle sur le processus de dissociation moleculaire dans les solides halogenes. Dans ce memoire, on propose d'etudier les changements structuraux dans monobromure d'iode (IBr), un compose inter-halogene possedant des proprietes structurales semblables a celles de deux composes halogenes, soit l'iode (I 2) et le brome (Br2) sous leur forme solide. Des experiences de diffraction des rayons X de poudres en utilisant un rayonnement synchrotron ont ete realisees a temperature ambiante sur l'IBr en variant la pression jusqu'aux environs de 60 GPa. La nature chimique particuliere du compose IBr a necessite la mise au point de techniques de chargement d'echantillon destinees a preserver l'integrite chimique de la substance utilisee. On rapporte egalement l'observation d'une phase de l'IBr presentant une modulation incommensurable. Les phases observees dans l'IBr permettent d'etablir des paralleles avec les phases denses rapportees dans I2 et Br2 par le biais d'un modele phenomenologique decrivant la sequence structurale des solides halogenes sous forme condensee.

  1. Contribution to the study of the uranium-hydrogen system; Contribution a l'etude du systeme uranium-hydrogene

    Energy Technology Data Exchange (ETDEWEB)

    Chevallier, J [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1965-01-01

    Previous work on uranium-hydrogen system is reviewed. The U-H{sub 2}-UH{sub n} equilibrium is then investigated at pressures below one atmosphere, i.e. at temperatures lower than 430 deg. C. The hydride obtained at equilibrium is deficient in hydrogen (UH{sub n<3}), the hydrogen deficit increasing as the temperature rises. Thermodynamic functions for the formation of non-stoichiometric hydride and of one hydrogen vacancy are derived from pressure composition isotherms, in U-H phase diagram is proposed. The hydrogenation of U-UC alloys is also examined at pressures below one atmosphere with regard to the equilibrium: (free U + UC) - H{sub 2}-UH{sub n}. The equilibrium conditions are found different from that observed for pure uranium. (author) [French] Une etude bibliographique du systeme uranium-hydrogene est exposee. L'equilibre U-H{sub 2}-UH{sub n} est ensuite etudie sous des pressions inferieures a une atmosphere, soit aux temperatures inferieures a environ 430 degs. C. L'hydrure obtenu a l'equilibre est deficitaire en hydrogene - UH{sub n<3} - et d'autant plus que la temperature s'eleve. Les grandeurs thermodynamiques relatives a la formation et a la saturation de l'hydrure, ainsi qu'a la formation d'une lacune d'hydrogene sont deduites des pressions d'equilibre. Un modele de diagramme de phases U-H est propose. L'hyduration des alliages U-UC est etudiee egalement sous des pressions inferieures a l'atmosphere, au point de vue de l'equilibre (U libre + UC) - H{sub 2}-UH{sub n}. Les conditions d'equilibre sont trouvees differentes de celles observees sur l'uranium pur. (auteur)

  2. Comparative study of thyroid fixation of different iodine compounds; Etude comparative de la fixation thyroidienne de differents composes iodes

    Energy Technology Data Exchange (ETDEWEB)

    Rinaldi, R; Coeur, A; Raynfeld, Ch [Commissariat a l' Energie Atomique, Grenoble (France).Centre d' Etudes Nucleaires

    1961-07-01

    The aim of this work is to study the thyroid fixation of various iodine compounds in mineral or organic form. The animals (rats) are given therapeutic doses of the derivative orally with the object of saturating the thyroid, and then receive a determined dose of radio-iodine 131 by intra-peritoneal injection; any fixation of this latter is then measured under anaesthetic by means of a scintillation counter. Whatever form of iodine derivative was used whether in ionic (potassium iodide type) or organic form (iodo-tannic syrup) or in the form of elementary iodine (iodinated water), thyroid saturation was always obtained, as shown by practically zero fixation of the 4 {mu}curies of iodine 131 administered by intra-peritoneal injection. (author) [French] Notre travail a pour but l'etude de la fixation thyroidienne de differents composes iodes sous forme minerale ou organique. Les animaux (rats), apres absorption orale de doses therapeutiques de derives destines a saturer leur thyroide recoivent par voie intra-peritoneale une dose determinee de radio-iode {sup 131}I, la fixation eventuelle de ce dernier est ensuite mesuree sous anesthesie en utilisant un compteur a scintillation. Quelle que soit la forme utilisee, c'est-a-dire derive iode sous forme ionique (type iodure de potassium) ou sous forme organique (sirop iodotanique) ou encore sous forme d'iode metalloidique (eau iodee), nous avons obtenu chaque fois une saturation thyroidienne mise en evidence par une fixation pratiquement nulle des 4 {mu}curies de l'iode 131 injectes par voie intraperitoneale. (auteur)

  3. Systematic study of plasma and serum proteins in the pig; Etude systematique des proteines plasmatiques et seriques du porc

    Energy Technology Data Exchange (ETDEWEB)

    Daburon, F; Nizza, P; Hatchikian, C; Schmidt, J -P [Commissariat a l' Energie Atomique (France)

    1966-07-01

    This work has been carried out in the framework of the determination of the physiological constants of a normal pig. The aim was to study the serum and plasma proteins of this animal species, the ultimate object being to discover whether the qualitative and quantitative changes in these proteins can make a significant contribution to the establishment of a biological dosimetry for irradiated pigs. The serum and plasma from a normal pig were analyzed first by various simple electrophoretic methods and then by immuno-electrophoresis. As a result of the particular characteristics of pig serum we have gradually been led to make numerous modifications to the techniques used for human serums or for those of small laboratory animals. Much careful work and patience were required in order to obtain reproducible results. (authors) [French] Ce travail se situe dans le cadre de la determination des constantes physiologiques du porc normal. il s'agissait de proceder a l'etude des proteines seriques et plasmatiques de cette espece animale, le but ulterieur etant de savoir si les modifications qualitatives et quantitatives de ces proteines pourront representer une contribution valable a l'etablissement d'une dosimetrie biologique chez le porc irradie. Le serum et le plasma du porc normal ont ete analyses d'abord par diverses methodes electrophoretiques simples puis par immunoelectrophorese. Les caracteristiques particulieres du serum de porc nous ont conduits a apporter progressivement de nombreuses modifications aux techniques utilisees pour des serums humains ou de petits animaux de laboratoire. L'obtention de resultats reproductible a exige beaucoup de patience et de minutie. (auteurs)

  4. Study of free acidity determinations in aqueous solution; Etude des dosages d'acidite libre en solution aqueuse

    Energy Technology Data Exchange (ETDEWEB)

    Kergreis, A [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1966-04-01

    The object of this work is the study of the principal methods which can be applied to the measurement of 'free' acidity. In the first part, we define the various types of acidity which can exist in aqueous solution; then, after having studied some hydrolysis reactions, we compare the value of the neutralisation pH of the hydrated cation and that of the precipitation of the hydroxide. In the second part we have started to study the determination of the acidity of an aqueous solution. After having rapidly considered the 'total' acidity determination, we deal with the problem of the 'free' acidity titration. We have considered in particular certain methods: extrapolation of the equivalent point, colorimetric titrations with or without a complexing agent, and finally the use of ion-exchange resins with mixed aqueous and solvent solutions. (author) [French] Le but de ce travail est l'etude des principales methodes de determination de l'acidite 'libre'. Dans une premiere partie nous avons defini les differentes sortes d'acidites pouvant exister en solution aqueuse, puis apres avoir etudie quelques reactions d'hydrolyse, nous avons compare la valeur de pH de neutralisation du cation hydrate et celle de precipitation de l'hydroxyde. Dans la seconde partie nous avons aborde l'etuce des dosages de l'acidite d'une solution aqueuse. Apres avoir envisage assez rapidement la determination de l'acidite 'totale', nous traitons du probleme du titrage de l'acidite 'libre'. Nous avons porte notre attention sur certaines methodes: extrapolation du point equivalent, titrimetrie colorimetrique avec ou sans complexant, et enfin utilisation des resines echangeuses d'ions en milieu aqueux et solvant mixte.

  5. Study of superconducting Nb{sub 3}Sn coils; Etude de bobinages supraconducteurs en Nb{sub 3}Sn

    Energy Technology Data Exchange (ETDEWEB)

    Vivet, B

    1963-07-01

    Composite superconducting Nb{sub 3}Sn wires with a diameter of 0.5 mm and a length of about 100 m were made, and Hc-Ic diagrams were plotted up to fields of 80 kgauss for short lengths. Two solenoids producing fields of about 20 kgauss were studied. Nb{sub 3}Sn solenoids, as opposed to those of Nb-Zr or Nb-Ti, appear to have a predictable behavior. Solenoids with less insulation produced stronger fields than heavily insulated solenoids. (author) [French] Une etude des fils composites supraconducteurs de Nb{sub 3}Sn a ete entreprise au C.E.N. Saclay, en collaboration avec la Societe S.O.D.E.R.X. Des fils de 0,5 mm de diametre et d'une centaine de metres de longueur ont ete produits de facon experimentale. Des diagrammes Hc-Ic ont pu etre traces, jusqu'en des champs de 80 kG, sur des echantillons de petite longueur. Deux solenoides ont ete etudies produisant les champs de l'ordre de 20 kg. Il semble que, contrairement aux alliages Nb-Zr ou Nb-Ti, les solenoides en Nb{sub 3}Sn aient un comportement previsible d'apres les tests sur des echantillons courts. On montrera d'autre part qu'un bobinage a faible isolement peut produire un champ notablement plus eleve qu'un bobinage isole. Une production plus extensive permettra, dans les semaines a venir, la fabrication de solenoides de plus grosse dimension et produisant des champs plus eleves. (auteur)

  6. Systematic study of plasma and serum proteins in the pig; Etude systematique des proteines plasmatiques et seriques du porc

    Energy Technology Data Exchange (ETDEWEB)

    Daburon, F.; Nizza, P.; Hatchikian, C.; Schmidt, J.-P. [Commissariat a l' Energie Atomique (France)

    1966-07-01

    This work has been carried out in the framework of the determination of the physiological constants of a normal pig. The aim was to study the serum and plasma proteins of this animal species, the ultimate object being to discover whether the qualitative and quantitative changes in these proteins can make a significant contribution to the establishment of a biological dosimetry for irradiated pigs. The serum and plasma from a normal pig were analyzed first by various simple electrophoretic methods and then by immuno-electrophoresis. As a result of the particular characteristics of pig serum we have gradually been led to make numerous modifications to the techniques used for human serums or for those of small laboratory animals. Much careful work and patience were required in order to obtain reproducible results. (authors) [French] Ce travail se situe dans le cadre de la determination des constantes physiologiques du porc normal. il s'agissait de proceder a l'etude des proteines seriques et plasmatiques de cette espece animale, le but ulterieur etant de savoir si les modifications qualitatives et quantitatives de ces proteines pourront representer une contribution valable a l'etablissement d'une dosimetrie biologique chez le porc irradie. Le serum et le plasma du porc normal ont ete analyses d'abord par diverses methodes electrophoretiques simples puis par immunoelectrophorese. Les caracteristiques particulieres du serum de porc nous ont conduits a apporter progressivement de nombreuses modifications aux techniques utilisees pour des serums humains ou de petits animaux de laboratoire. L'obtention de resultats reproductible a exige beaucoup de patience et de minutie. (auteurs)

  7. Recent research on the pharmaceutical checking of radioelements (1961); Etudes recentes sur le controle pharmaceutique des radioelements (1961)

    Energy Technology Data Exchange (ETDEWEB)

    Cohen, Y; Ingrand, J [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1960-07-01

    Checking on radioactive preparations for medical use is complicated by difficulties due to the radioactivity, the instability and the methods of using these solutions. In effect it is necessary, in order to draw up a practicable set of rules governing such checks, to know both the method of preparation and the properties of the radioelement, as well as special and often contradictory features of its use. These tests fall into three categories: physical, chemical and biological. Preparations of chromium 51, iron 59 and arsenic 76 have been dealt with in recent studies. In each case special tests were necessary, and these will be described in this paper. The practice of these tests is of twofold interest: firstly they provide a maximum guarantee to the user, and secondly they guide the chemist in his manipulations, immediately and thoroughly. (author) [French] Le controle des preparations radioactives a usage medical est complexe par suite des difficultees dues a la radioactivite, a l'instabilite et aux modalites d'utilisation de ces solutions. En effet, l'etablissement justifie d'un protocole de controle necessite la connaissance aussi bien du mode de preparation, que des proprietes du radioelement et des particularites parfois contradictoires de son emploi. Ces controles sont de trois ordres physiques, chimiques, biologiques. Des etudes recentes ont porte sur des preparations de chrome 51, de fer 59, d'arsenic 76. Dans chaque cas, il est apparu necessaire de pratiquer des controles particuliers qui seront exposes dans la communication. La pratique de ces derniers presente un double interet; d'une part, ils assurent a l'utilisateur un maximum de garantie, d'autre part, ils orientent le chimiste dans ses mises au point, immediatement et de facon approfondie. (auteur)

  8. Study of the stopping power of various filters; Etude du pouvoir d'arret de differents filtres

    Energy Technology Data Exchange (ETDEWEB)

    Madelaine, G [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-07-01

    The first part is devoted to a study of aerosols obtained from the combustion of various smoke-producing compounds. A trial aerosol of which the size distribution is the closest possible to that of atmospheric dusts has been defined. The efficiency of various filters has been determined for successive increments of the dimensions and not for the whole range of its diameter distribution. The variation in the efficiency of the filtering layers as a function of the filtering speed and particle size has been studied for aerosols having particle diameters of over 0.3 {mu}. The second part describes an original method for measuring the efficiency of filters for ultra-fine particles (under 0.1 {mu}) using the fixation properties of radioactive atoms resulting from the decay of thoron. (author) [French] La premiere partie est consacree a l'etude des aerosols obtenus a partir de la combustion de divers types de fumigenes. Un aerosol d'essai, dont la repartition granulometrique se rapproche le plus possible des poussieres atmospheriques a ete defini. L'efficacite de plusieurs filtres a ete determinee pour des tranches successives de dimension et non pour l'aerosol pris dans sa totalite. La variation de l'efficacite des couches filtrantes en fonction de la taille des particules et de la vitesse de filtration a ete examinee pour des aerosols superieurs a 0,3 {mu}. La seconde partie decrit une methode originale permettant de mesurer l'efficacite des filtres pour des particules ultrafines (inferieures a 0,1 {mu}) en utilisant la propriete de fixation des atomes radioactifs des descendants du thoron. (auteur)

  9. Contribution to the study of alpha-alpha interaction; Contribution a l'etude de l'interaction alpha - alpha

    Energy Technology Data Exchange (ETDEWEB)

    Darriulai, P [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1965-03-01

    Two sets of measurements of the {alpha}-{alpha} elastic scattering differential cross section are presented. The first set - angular distributions from 50 up to 120 MeV - shows two new resonances, 6{sup +} and 8{sup +}, at 25 and 57 MeV. Complex phase shifts are extracted from the data and a phenomenological potential is given. A description of the 3 {alpha}-particle 0{sup +} states in C{sup 12} is made with this interaction potential. The second set - excitation curves between 20 and 50 MeV - allows investigation of the Be{sup 8} level structure within this energy range - It identifies the 16.6 and 16.9 MeV states as 2{sup +}, but the rise of inelastic processes at higher energies makes further identification of spins and parities more and more difficult. (author) [French] Deux series de mesures de la section efficace differentielle de diffusion {alpha}-{alpha} sont presentees. La premiere - distributions angulaires entre 50 et 120 MeV - fait apparaitre deux nouvelles resonances, 6{sup +} et 8{sup +}, a 25 et 57 MeV d'excitation. Des dephasages complexes en sont extraits et un potentiel phenomenologique est presente. Une etude des etats 0{sup +} a parentage (3{alpha}) de {sup 12}C est faite a partir de ce potentiel. La seconde - courbes d'excitation s'etendant de 20 a 50 MeV - met en evidence la structure de {sup 8}Be dans cette region. Elle montre que les niveaux a 16,6 et 16,9 MeV sont des 2{sup +} mais l'importance des processus inelastiques rend difficile l'identification des niveaux d'excitation plus elevee. (auteur)

  10. Study of beam-plasma interactions in the presence of a magnetic field; Etude d'interactions faisceau-plasma en la presence d'un champ magnetique

    Energy Technology Data Exchange (ETDEWEB)

    Etievant, C [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1963-12-15

    The instabilities developing in a 'beam-plasma' system and in a 'double-beam' system in the presence of a magnetic field are discussed theoretically starting from the conductivity tensor expression for a multi-beam system. Oblique propagation is taken into account and this leads to the introduction of certain instability mechanisms which would not appear in the case of a propagation which is purely parallel or perpendicular to the magnetic field. Two experiments are described: a) Study of the collision of two counterstreaming electron beams: An instability has been observed experimentally which leads to the generation of a stationary cyclotron wave having a frequency of {omega}{sub ce}/2. A description is given of the measurement of the interaction frequency, of the wavelength and of the build-up time of the wave. b) Study of a 'beam-plasma' system: A description is given of the measurement of the spectra of excited waves and of the perturbation of the beam velocity distribution at the plasma-exit. This perturbation is very pronounced when 'plasma-plasma' interaction appears in the system. A study into cyclotron oscillations produced in the plasma by excitation due to the passage of the beam is also described in this report. (author) [French] Les instabilites se developpant dans un systeme 'faisceau-plasma' et dans un systeme 'faisceau-faisceau' en la presence d'un champ magnetique sont discutees theoriquement a partir de l'expression du tenseur de conductivite d'un systeme multi-faisceaux. La propagation oblique est prise en consideration, ce qui introduit certains mecanismes d'instabilite qui n'apparaitraient pas pour une propagation purement parallele ou perpendiculaire au champ magnetique. Deux experiences sont decrites: a) Etude de la collision de deux faisceaux d'electrons: Une instabilite conduisant a la generation d'une onde cyclotronique stationnaire a la frequence {omega}{sub ce}/2 a ete observee experimentalement. Les mesures de la frequence d

  11. Reconstruction de la surface de Fermi dans l'etat normal d'un supraconducteur a haute Tc: Une etude du transport electrique en champ magnetique intense

    Science.gov (United States)

    Le Boeuf, David

    Des mesures de resistance longitudinale et de resistance de Hall en champ magnetique intense transverse (perpendiculaire aux plans CuO2) ont ete effectuees au sein de monocristaux de YBa2Cu3Oy (YBCO) demacles, ordonnes et de grande purete, afin d'etudier l'etat fondamental des supraconducteurs a haute Tc dans le regime sous-dope. Cette etude a ete realisee en fonction du dopage et de l'orientation du courant d'excitation J par rapport a l'axe orthorhombique b de la structure cristalline. Les mesures en champ magnetique intense revelent par suppression de la supraconductivite des oscillations magnetiques des resistances longitudinale et de Hall dans YBa2Cu 3O6.51 et YBa2Cu4O8. La conformite du comportement de ces oscillations quantiques au formalisme de Lifshitz-Kosevich, apporte la preuve de l'existence d'une surface de Fermi fermee a caractere quasi-2D, abritant des quasiparticules coherentes respectant la statistique de Fermi-Dirac, dans la phase pseudogap d'YBCO. La faible frequence des oscillations quantiques, combinee avec l'etude de la partie monotone de la resistance de Hall en fonction de la temperature indique que la surface de Fermi d'YBCO sous-dope comprend une petite poche de Fermi occupee par des porteurs de charge negative. Cette particularite de la surface de Fermi dans le regime sous-dope incompatible avec les calculs de structure de bande est en fort contraste avec la structure electronique presente dans le regime surdope. Cette observation implique ainsi l'existence d'un point critique quantique dans le diagramme de phase d'YBCO, au voisinage duquel la surface de Fermi doit subir une reconstruction induite par l'etablissement d'une brisure de la symetrie de translation du reseau cristallin sous-jacent. Enfin, l'etude en fonction du dopage de la resistance de Hall et de la resistance longitudinale en champ magnetique intense suggere qu'un ordre du type onde de densite (DW) est responsable de la reconstruction de la surface de Fermi. L'analogie de

  12. F{sup 19} relaxation in non-magnetic hexafluorides; Contribution a l'etude de la relaxation des fluors dans les hexafluorures non magnetiques

    Energy Technology Data Exchange (ETDEWEB)

    Rigny, P [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1967-12-01

    The interesting properties of the fluorine magnetic resonance in the hexafluorides of molybdenum, tungsten and uranium, are very much due to large anisotropies of the chemical shift tensors. In the solid phases these anisotropies, the values of which are deduced from line shape studies, allow one to show that the molecules undergo hindered rotations about the metal atom. The temperature and frequency dependence of the fluorine longitudinal relaxation times shows that the relaxation is due to the molecular motion. The dynamical parameters of this motion are then deduced from the complete study of the fluorine relaxation in the rotating frame. In the liquid phases, the existence of anisotropies allows an estimation of the different contributions to the relaxation. In particular, the frequency and temperature dependence of the relaxation shows it to be dominated by the spin-rotation interaction. We have shown that the strength of this interaction can be deduced from the chemical shifts, and the angle through which the molecule rotates quasi-freely can be determined. In the hexafluorides, this angle is roughly one radian at 70 C, and with the help of this value, the friction coefficients which describe the intermolecular interactions are discussed. (author) [French] Les proprietes de la resonance magnetique des fluors dans les hexafluorures de molybdene, tungstene et uranium sont influencees par l'existence de deplacements chimiques tres anisotropes. Dans les phases solides, la valeur de cette anisotropie peut etre determinee par l'analyse des formes de raies et son existence permet de montrer que les molecules sont en rotation empechee autour de leur atome central. L'etude du temps de relaxation longitudinal en fonction de la temperature et de la frequence montre que la relaxation est due aux mouvements moleculaires, aux plus hautes temperatures. Les proprietes dynamiques du mouvement sont obtenues par l'etude complete de la relaxation spin-reseau dans le referentiel

  13. A review of micro-wave techniques in plasma studies; Survol des techniques micro-ondes pour l'etude des plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Consoli, T [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-07-01

    The problem of the application of micro-wave techniques to the study of plasma properties is considered in this report. In section I, the author summarizes a few fundamental laws concerning the theory of waves in an ionised medium as well as measurable effects of transverse and longitudinal propagation. Section II is a rapid review of the experimental methods and of the various measurements which may be effected in very high frequency plasmas. Only recent experimental work carried out since the last U. R.S.I. Assembly is considered. Section III is devoted to micro-wave techniques developed during this period in the laboratories of the Applied Physics Service. These techniques deal with longitudinal propagation and in particular with the propagation along a right mode. Section IV is a general view of similar studies undertaken in European Research Centres working on plasma physics or controlled fusion. Section V is a contribution concerning three particular topics from the Juelich and Max Planck Institute laboratories. (author) [French] On etudie dans ce rapport le probleme de l'application des techniques micro-ondes a l'etude des proprietes d'un plasma. Dans la section I, l'auteur rappelle rapidement quelques lois fondamentales de la theorie des ondes dans un milieu ionise ainsi que les effets mesurables en propagation transversale et longitudinale. La section II est une revue rapide des methodes experimentales et des diverses mesures qui peuvent etre faites dans les plasmas aux tres hautes frequences. On ne considere seulement que les etudes experimentales recentes depuis la derniere assemblee de l'U.R.S.I. La section III est consacree aux techniques hyperfrequences developpees durant la meme periode dans les laboratoires des Services de Physique Appliquee. Ces techniques se rapportent a la propagation longitudinale et particulierement a la propagation suivant le mode droit. La section IV est un panorama de travaux similaires entrepris dans les centres europeens

  14. Development of mercury porosimeter. Application to nuclear graphite studies (1961); Mise au point d'un porosimetre a mercure. Application a l'etude des graphites nucleaires (1961)

    Energy Technology Data Exchange (ETDEWEB)

    Bocquet, M; Genisson, J; Sailleau, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1961-07-01

    A mercury porosimeter, model IFP-CEA, has been developed for application to nuclear graphite studies. The apparatus is based on the capillary depression phenomenon. The relationship between the radius of a pore and the pressure at which mercury fills it is pr = -2 {sigma} cos {theta} ( {sigma} is the surface tension, {theta} the angle of contact of the mercury). After some theoretical consideration, the apparatus is described. The mercury pressure is increased step-wise from 0 to 1000 kg/cm{sup 2} thus yielding the complete distribution of pores from 92 {mu} to 75 A. Results are, then presented concerning nuclear graphites which show the evolution of the porous structure under the effect of bitumen impregnation. In general, the volume of the large pores decreases while that of the small pores increases. The structure of impregnated products appears to depend to a certain extent on that of the starting materials. It has also been possible to study other products with this porosimeter; the range of measurements possible is such that it may be used for the study of the majority of porous materials. (authors) [French] Un porosimetre a mercure modele IFP-CEA a ete mis au point en vue de son application a l'etude de graphites nucleaires. Le fonctionnement de l'appareil repose sur le phenomene de depression capillaire. On etablit la relation existant entre le rayon r d'un pore et la pression p pour laquelle le mercure peut y penetrer: pr = -2 {sigma} cos {theta} ( {sigma} tension superficielle, {theta} angle de contact du mercure). Apres quelques considerations theoriques, l'appareil utilise est decrit. Il permet de faire varier par palier la pression du mercure entre 0 et 1000 kg/cm{sup 2} et d'etablir ainsi la distribution complete des rayons de pores compris entre 92 {mu} et 75 A. Les resultats d'une etude faite sur des graphites nucleaires sont alors presentes faisant apparaitre l'evolution de la structure poreuse sous l'effet des impregnations au brai. D'une facon

  15. The use radioactive tracers in the study of solid transport in water streams; Emploi de traceurs radioactifs pour l'etude du transport solide dans les cours d'eau

    Energy Technology Data Exchange (ETDEWEB)

    Courtois, G [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires; Jaffry, P; Heuzel, M [Laboratoire National d' Hydraulique de Chatou, 78 (France)

    1960-07-01

    The Laboratoire National d'Hydraulique which has been studying, during the last few years in conjunction with the Centre d'Etudes Nucleaires at Saclay, the development of apparatus and of methods of investigation of sediment transport by radioactive tracer techniques, is at the moment trying to perfect a genuinely quantitative method of investigation. Two experiments have recently been carried out in rivers, the first designed to investigate the transport of pebbles in the river Rhone, the other to investigate the movement of sands in the Niger. This second experiment has been supported by parallel experiments carried out on a reduced scale model of the Niger built at the laboratories of Chatou: in this experiment are used the radiation from {sup 56}Mn and {sup 24}Na obtained by direct activation of the crushed apricot store which represents, in the scale model, the natural sediment on the bed of the Niger. The combined efforts of the laboratories of Chatou and of the Centre d'Etudes Nucleaires at Saclay are at the moment directed to the application of radioactive tracers to studies on the scale models with the double aim: a) of having a single investigational method for the actual experiment and for the model making it possible to control the accuracy of the model in the preliminary stage of calibrating this model; b) of making the most of the possibilities of observation and of direct measurement offered by the scale models for studying the possibility of improving the tracer method, in particular with respect to the collecting of quantitative data. (author) [French] La Laboratoire National d'Hydraulique qui, depuis quelques annees a developpe, en collaboration avec le Centre d'Etudes Nucleaires de Saclay, les appareillages et les techniques d'etudes des mouvements de sediments par la methode des traceurs radioactifs, s'efforce actuellement de mettre au point un moyen d'investigation veritablement quantitatif. Deux experiences ont ete effectuees recemment en

  16. Study of the {sup 14}C benzimidazole distribution in mice after inter-peritoneal injection; Etude de la repartition du benzimidazole {sup 14}C chez la souris apres injection intraperitoneale

    Energy Technology Data Exchange (ETDEWEB)

    Tyortyalian, C [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1965-07-01

    In order to provide further information on the mechanism of benzimidazole radioprotective activity, this work studies the tissual repartition in mice of this compound labelled with carbon 14. Experiments have showed that benzimidazole distribution is fast and homogeneous in all the tissues, but however affinity appears at the level of stomach and gastric content. Elimination is made through the urinary system and is very fast. (author) [French] Dans le cadre de l'etude du mecanisme de l'action radioprotectrice du benzimidazole, ce travail a pour objet l'etude de la repartition tissulaire chez la souris de ce compose marque au carbone 14. L'experimentation a montre que le benzimidazole se repartit tres rapidement et de facon pratiquement homogene dans tous les tissus, avec toutefois une affinite paraissant se manifester au niveau de l'estomac et du contenu gastrique. L'elimination, qui se fait par voie urinaire, est tres rapide. (auteur)

  17. Study methods for the drillings around the underground nuclear explosions in the Sahara. Part 1. study of rock samples; Methodes d'etude des forages realises autour des explosions nucleaires souterraines au Sahara. Premiere partie: etude des echantillons de roche

    Energy Technology Data Exchange (ETDEWEB)

    Derlich, S [Commissariat a l' Energie Atomique, Bruyers-le-Chatel (France). Centre d' Etudes

    1969-07-01

    An examination of the mechanical effects produced on rocks by an underground nuclear explosion calls for the use of particular means of exploration which are described in this report, special attention being paid to the equipment used in connection with the French nuclear tests in the Sahara. The drilling methods used (rotary and turbo-drilling) are adapted to the particular conditions of the sampling programme, to the radioactivity and to the temperature in the region of the explosion. A study of the samples makes it possible to obtain the new characteristics of the rock and to assess the chemical and mechanical transformations which it has undergone. An examination of the core obtained from the drilling, together with a knowledge of the drilling parameters (depth of the probe, sample recovery, etc...), makes it possible to study the extent and the characteristics of the zones which have been damaged to different degrees according to their distance from the zero point: cavity, strongly powdered zone, fractured zone, chimney, zones containing high stresses leading to a particular type of fracture of the cores. The problems connected with the interpretation of the results are also presented. (author) [French] L'examen des effets mecaniques provoques par une explosion nucleaire souterraine sur la roche necessite la mise en oeuvre de moyens d'exploration particuliers dont l'expose fait l'objet de ce rapport, essentiellement pour les moyens utilises autour des essais nucleaires francais au Sahara. Les methodes de forage (rotary et turboforage) sont adaptees aux conditions particulieres dues au programme d'echantillonnage, a la radioactivite et a la temperature regnant a proximite du point de tir. L'etude des echantillons permet la determination des nouveaux caracteres de la roche et de ses transformations chimique et mecanique. L'examen des carottes et l'utilisation des parametres de forage (cotes sondeurs, recuperation des echantillons, etc...) permettent d'etudier l

  18. Realisation and tests of a compressed gas Cherenkov counter. Study of the pollution of a beam (1961); Realisation et essais d'un compteur cherenkov a gaz comprime etude de la pollution d'un faisceau (1961)

    Energy Technology Data Exchange (ETDEWEB)

    Duboc, J; Banaigs, J; Detoeuf, J F [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1961-07-01

    The realisation of a compressed as Cherenkov counter permits the study of the pollution of a beam of {pi} mesons with momentum varying from 220 to 11000 MeV/c. (authors) [French] La realisation d'un compteur Cherenkov a gaz sous pression permet l'etude de la pollution d'un faisceau de mesons {pi} d'impulsions comprise entre 220 et 1100 MeV/c. (auteurs)

  19. Experimental study of the hydrodynamic instabilities occurring in boiling-water reactors; Etude experimentale des instabilites hydrodynamiques survenant dans les reacteurs nucleaires a ebullition

    Energy Technology Data Exchange (ETDEWEB)

    Fabreca, S. [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1964-10-01

    The subjects is an experimental out-of pile loop study of the hydrodynamic oscillations occurring in boiling-water reactors. The study was carried out at atmospheric pressure and at pressure of about 8 atmospheres, in channels heated electrically by a constant and uniform specified current. In the test at 8 atmospheres the channel was a round tube of approximately 6 mm interior diameter. At 1 atmosphere a ring-section channel was used, 10 * 20 mm in diameter, with an inner heating tube and an outer tube of pyrex. It was possible to operate with natural convection and also with forced convection with test-channel by-pass. The study consists of 3 parts: 1. Preliminary determination of the laws governing pressure-drop during boiling. 2. Determination of the fronts at which oscillation appears, within a wide range of the parameters involved. 3. A descriptive study of the oscillations and measurement of the periods. The report gives the oscillation fronts with natural and forced convection for various values of the singular pressure drop at the channel inlet and for various riser lengths. The results are presented in non-dimensional form, which is available, in first approximation, for all geometric scales and for all fluids. Besides the following points were observed: - the wall (nature and thickness) can be an important factor ; - oscillation can occur in a horizontal channel. (author) [French] II a ete effectue une etude experimentale, en boucle hors-pile, des oscillations hydrodynamiques survenant dans les reacteurs a ebullition. L'etude a ete effectuee a la pression atmospherique et a une pression voisine de 8 atmospheres dans des canaux chauffes electriquement a puissance imposee constante et uniforme. Dans les essais a 8 atmospheres le canal etait un tube circulaire de diametre interieur 6 mm environ. A 1 atmosphere le canal etait de section annulaire 10 * 20 mm avec un tube interieur chauffant et un tube exterieur en pyrex. Le fonctionnement etait possible

  20. Magnetic study of solid uranium-fluorine complexes; Contribution a l'etude magnetique de composes fluores solides de l'uranium

    Energy Technology Data Exchange (ETDEWEB)

    Dianoux, A J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1969-06-01

    A study of the magnetic susceptibility of uranium V fluorine complexes and of the magnetic resonance of fluorine atoms in uranium VI fluorine complexes has made it possible to put forward a structural model for these compounds for which it is impossible, because of the lack of suitable single crystals for X-ray diffraction work, to deduce the exact position of the fluorine atoms. It is shown that it is difficult to interpret the paramagnetism of uranium fluorides, because the uranium ions are in low-symmetry sites. A theoretical study of the magnetism of the U{sup V} ion in complex fluorides of the type M{sub 3}UF{sub 8} (M = NH{sub 4}, Na, Rb, Cs) leads to an interpretation based on a trigonal deformation of the eight fluorine atom structure surrounding the uranium atom. By applying a Hamiltonian spin formalism and making a systematic use of group theory, it is possible to present the susceptibility calculations very concisely. Study of the resonance and of the relaxation of the fluorine atoms in powdered uranium VI complex fluorides suggests a structural model in the case of NaUF{sub 7}. It is shown that the shape of the magnetic resonance absorption lines is strongly affected by the presence of large anisotropic chemical shifts. In the model proposed here, six fluorine atoms are linked to the uranium, atom by strongly covalent bonds in a deformed UF{sub 6} octahedral structure; the seventh fluorine atom remains ionic. The occurrence of a rotational movement of the octahedron is confirmed by a study of the longitudinal relaxation of the fluorine atoms, the activation energy being 0.46 eV. (author) [French] L'etude de la susceptibilite magnetique de complexes fluores d'uranium V et la resonance magnetique des fluors dans des complexes fluores d'uranium VI permettent de proposer un modele structural pour ces composes, ou la diffraction des rayons X, en l'absence de monocristaux convenables, est incapable de preciser la position des atomes de fluor. Nous montrons

  1. Study of FeC1{sub 2} by neutron diffraction; Etude de Fe C1{sub 2} par diffraction de neutrons

    Energy Technology Data Exchange (ETDEWEB)

    Herpin, A; Meriel, P [Commissariat a l' Energie Atomique, Saclay (France)

    1959-07-01

    Magnetic measurements have shown that anhydrous ferrous chloride behaves as a metamagnetic at temperatures below 24 deg. K, in other words as an antiferromagnetic sensitive to the action of an external field of moderate strength. The aim of the neutron diffraction study is to determine precisely the arrangement of the magnetic moments, and to follow its evolution as a function of the applied field. (author) [French] Des mesures magnetiques ont montre que le chlorure ferreux anhydre se comporte comme un metamagnetique a une temperature inferieure a 24 deg. K, c'est a dire comme un antiferromagnetique sensible a l'action d'un champ exterieur modere. L'etude par diffraction de neutrons a pour buts de preciser la disposition des moments magnetiques et de suivre son evolution en fonction du champ applique. (auteur)

  2. The study of some thiazinic and indaminic dye syntheses induced by ionising radiation; Etude de quelques syntheses de colorants thianziniques et indaminiques amorcees par les rayonnements ionisants

    Energy Technology Data Exchange (ETDEWEB)

    Balestic, S [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1961-03-15

    With a view to finding some radiochemical reactions applicable on an industrial scale for evaluating the radioactive waste from nuclear reactors, a systematic study was made of the radiochemical synthesis of thiazinic dyes such as methylene blue and Lauths' violet, on which the first tests were carried out in 1954. The first part of the study concerned the identification and the dosage, during radiolysis, of dyes by means of their absorption spectra after separation from the reaction medium by adsorption chromatography or ion-exchange; other radiolysis products such as ammonium chloride and hydrogen peroxide were also identified. During a later stage by systematically varying the physico-chemical parameters it was possible to determine the most favourable conditions for radio-synthesis; the maximum radiochemical yields obtained had the following values: G (Lauths' violet) 1,65; G (Methylene blue) = 1,75. Furthermore, the study of the influence of variously substituted aminated products on the radiochemical yield showed the possibility of synthesising Bindsehedlers green and Wursters blue by radiochemical methods. Finally the discovery of a fundamental intermediate product, Wursters red, together with the kinetic study of the chemical synthesis of methylene blue made it possible to determine the main stages of the reaction mechanism and to decide which of these stages could be attributed to ionising radiations in the case of the radiochemical synthesis. (author) [French] Dans le but de trouver des reactions radiochimiques susceptibles d'une application industrielle pour valoriser les dechets radioactifs provenant des reacteurs nucleaires, il a ete entrepris une etude systematique de la synthese radiochimique des colorants thiazimiques tels que le Bleu de Methylene et le Violet de Lauth dont les premiers essais ont ete effectues par Loiseleur en 1954. La premiere partie de l'etude a porte sur l'identification et le dosage des colorants formes au cours de la radiolyse

  3. Study of FeC1{sub 2} by neutron diffraction; Etude de Fe C1{sub 2} par diffraction de neutrons

    Energy Technology Data Exchange (ETDEWEB)

    Herpin, A.; Meriel, P. [Commissariat a l' Energie Atomique, Saclay (France)

    1959-07-01

    Magnetic measurements have shown that anhydrous ferrous chloride behaves as a metamagnetic at temperatures below 24 deg. K, in other words as an antiferromagnetic sensitive to the action of an external field of moderate strength. The aim of the neutron diffraction study is to determine precisely the arrangement of the magnetic moments, and to follow its evolution as a function of the applied field. (author) [French] Des mesures magnetiques ont montre que le chlorure ferreux anhydre se comporte comme un metamagnetique a une temperature inferieure a 24 deg. K, c'est a dire comme un antiferromagnetique sensible a l'action d'un champ exterieur modere. L'etude par diffraction de neutrons a pour buts de preciser la disposition des moments magnetiques et de suivre son evolution en fonction du champ applique. (auteur)

  4. Apparatus for studying the diffusion of rare gases in stainless steel; Appareil pour etude de la diffusion des gaz rares dans l'acier inoxydable

    Energy Technology Data Exchange (ETDEWEB)

    Stohr, J A; Alfille, L [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1959-07-01

    This apparatus enables measurements to be carried out on the diffusion of gaseous fission products and of gases in general across thin metallic walls at high temperatures. This work was initially intended to solve the problems involved in systems for detecting the rupture of a fuel element can (D.R.G.) by the diffusion of fission products through the cans at high temperatures. The extension of the work to other fields is envisaged. (author) [French] Cet appareil permet d'effectuer des mesures sur la diffusion des produits de fission gazeux, et des gaz en general, au travers de parois metalliques minces a haute temperature. Au depart, ce procede devait contribuer a resoudre les problemes poses aux systemes detecteurs de rupture de gaine (D.R.G.), par la diffusion des produits de fission au travers des gaines de cartouches a haute temperature. Son extension a d'autres etudes est envisagee. (auteur)

  5. Contribution to the study of the diffusion of fission products in uranium; Contribution a l'etude de la diffusion des produits de fission dans l'uranium

    Energy Technology Data Exchange (ETDEWEB)

    Tournier, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-10-15

    In this work we have developed a simple method for determining the diffusion constants and the solid-state solubilities of a metal which is volatile and only slightly soluble in second metal. This method has been applied to the behaviour of certain fission products in {gamma} uranium: strontium, barium, lanthanum, samarium and cerium. This work has made it possible to show the effect of the atomic radius of the solute on the diffusion constants. (author) [French] Dans ce travail nous avons mis au point une methode simple permettant de determiner les constantes de diffusion ainsi que les solubilites a l'etat solide d'un metal volatil et peu soluble dans un autre. Cette methode a ete appliquee au comportement de certains produits de fission dans l'uranium {gamma}: strontium, baryum, lanthane, samarium et cerium. Cette etude a permis de mettre en evidence le role du rayon atomique du solute sur les constantes de diffusion. (auteur)

  6. Contribution to the study of the vertical molten zone process (1963); Contribution a l'etude du procede de la zone fondue verticale (1963)

    Energy Technology Data Exchange (ETDEWEB)

    Lenzin, M [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1963-07-01

    Construction and use of several molten zone apparatuses operating either vertically or horizontally. Efficient purification of uranyl nitrate hexahydrate but less successful in the case of other hydrated double salts and of zirconyl chloride in the hydrochloric gel form. Demonstration and study of the dissymmetry in the direction of the transport of the impurity during, the purification by a vertical molten zone process. (author) [French] Construction et utilisation de plusieurs appareils de zone fondue travaillant soit en vertical, soit en horizontal. Purification efficace du nitrate d'uranyle hexahydrate mais peu significative dans le cas des autres couples de sels hydrates et du chlorure de zirconyle a l'etat de gel chlorhydrique. Mise en evidence et etude de la dissymetrie sur le sens de transport de l'impurete au cours de la purification par zone fondue verticale. (auteur)

  7. Beach sediments drift study by means of radioactive tracers; L'etude du transport littoral par la methode des traceurs radioactifs

    Energy Technology Data Exchange (ETDEWEB)

    Hours, R [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires; Jaffry, P [Electricite de France (EDF), 78 - Chatou (France). Lab. National d' Hydraulique

    1959-07-01

    The present state of the sediments drift studies by means of radioactive tracers is exposed. Various processes of labelling, immersion and detection, used in France and other countries, are reviewed. A more extended analysis of some aspects of the problem by the same authors can be found in 'La Houille Blanche', number 3, may-june 1959 (Rapport C.E.A. number 1269). (author) [French] L'etude du transport littoral des sediments et galets par la methode des traceurs radioactifs est en plein developpement. Le present rapport precise l'etat actuel de la question. Les techniques de marquage, d'immersion et de detection utilisees en France et a l'etranger sont decrites; une analyse plus detaillee de certains aspects de la question est presentee par les memes auteurs dans 'La Houille Blanche', numero 3, mai-juin 1959 (Rapport C.E.A. numero 1269). (auteur)

  8. Experimental study of the hydrodynamic instabilities occurring in boiling-water reactors; Etude experimentale des instabilites hydrodynamiques survenant dans les reacteurs nucleaires a ebullition

    Energy Technology Data Exchange (ETDEWEB)

    Fabreca, S [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1964-10-01

    The subjects is an experimental out-of pile loop study of the hydrodynamic oscillations occurring in boiling-water reactors. The study was carried out at atmospheric pressure and at pressure of about 8 atmospheres, in channels heated electrically by a constant and uniform specified current. In the test at 8 atmospheres the channel was a round tube of approximately 6 mm interior diameter. At 1 atmosphere a ring-section channel was used, 10 * 20 mm in diameter, with an inner heating tube and an outer tube of pyrex. It was possible to operate with natural convection and also with forced convection with test-channel by-pass. The study consists of 3 parts: 1. Preliminary determination of the laws governing pressure-drop during boiling. 2. Determination of the fronts at which oscillation appears, within a wide range of the parameters involved. 3. A descriptive study of the oscillations and measurement of the periods. The report gives the oscillation fronts with natural and forced convection for various values of the singular pressure drop at the channel inlet and for various riser lengths. The results are presented in non-dimensional form, which is available, in first approximation, for all geometric scales and for all fluids. Besides the following points were observed: - the wall (nature and thickness) can be an important factor ; - oscillation can occur in a horizontal channel. (author) [French] II a ete effectue une etude experimentale, en boucle hors-pile, des oscillations hydrodynamiques survenant dans les reacteurs a ebullition. L'etude a ete effectuee a la pression atmospherique et a une pression voisine de 8 atmospheres dans des canaux chauffes electriquement a puissance imposee constante et uniforme. Dans les essais a 8 atmospheres le canal etait un tube circulaire de diametre interieur 6 mm environ. A 1 atmosphere le canal etait de section annulaire 10 * 20 mm avec un tube interieur chauffant et un tube exterieur en pyrex. Le fonctionnement etait possible en

  9. Hyperfine coupling in gadolinium-praseodymium alloys by specific heat measurements; Etude du couplage hyperfin dans les alliages gadolinium-praseodyme par mesures de chaleur specifique

    Energy Technology Data Exchange (ETDEWEB)

    Michel, J [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1967-12-01

    We have studied the hyperfine coupling in gadolinium-praseodymium alloys by specific heat measurements down to 0.3 K. In the first part we describe the apparatus used to perform our measurements. The second part is devoted to some theoretical considerations. We have studied in detail the case of praseodymium which is an exception in the rare earth series. The third part shows the results we have obtained. (author) [French] Nous avons etudie le couplage hyperfin d'alliages de gadolinium-praseodyme par des mesures de chaleur specifique jusqu'a 0.3 K. Dans la premiere partie de cette etude nous decrivons le dispositif experimental. La deuxieme partie est consacree a des considerations theoriques. Nous avons etudie en detail le cas du praseodyme qui est une exception dans la serie des terres rares. La troisieme partie est consacree aux resultats experimentaux. (auteur)

  10. Magnetic study of solid uranium-fluorine complexes; Contribution a l'etude magnetique de composes fluores solides de l'uranium

    Energy Technology Data Exchange (ETDEWEB)

    Dianoux, A.J. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1969-06-01

    A study of the magnetic susceptibility of uranium V fluorine complexes and of the magnetic resonance of fluorine atoms in uranium VI fluorine complexes has made it possible to put forward a structural model for these compounds for which it is impossible, because of the lack of suitable single crystals for X-ray diffraction work, to deduce the exact position of the fluorine atoms. It is shown that it is difficult to interpret the paramagnetism of uranium fluorides, because the uranium ions are in low-symmetry sites. A theoretical study of the magnetism of the U{sup V} ion in complex fluorides of the type M{sub 3}UF{sub 8} (M = NH{sub 4}, Na, Rb, Cs) leads to an interpretation based on a trigonal deformation of the eight fluorine atom structure surrounding the uranium atom. By applying a Hamiltonian spin formalism and making a systematic use of group theory, it is possible to present the susceptibility calculations very concisely. Study of the resonance and of the relaxation of the fluorine atoms in powdered uranium VI complex fluorides suggests a structural model in the case of NaUF{sub 7}. It is shown that the shape of the magnetic resonance absorption lines is strongly affected by the presence of large anisotropic chemical shifts. In the model proposed here, six fluorine atoms are linked to the uranium, atom by strongly covalent bonds in a deformed UF{sub 6} octahedral structure; the seventh fluorine atom remains ionic. The occurrence of a rotational movement of the octahedron is confirmed by a study of the longitudinal relaxation of the fluorine atoms, the activation energy being 0.46 eV. (author) [French] L'etude de la susceptibilite magnetique de complexes fluores d'uranium V et la resonance magnetique des fluors dans des complexes fluores d'uranium VI permettent de proposer un modele structural pour ces composes, ou la diffraction des rayons X, en l'absence de monocristaux convenables, est incapable de preciser la position des atomes de

  11. Mineralogical and geochemical investigation of the Oligocene sedimentary series of Saint-Agoulin; Etude mineralogique et geochimique de la serie sedimentaire oligocene de Saint-Agoulin

    Energy Technology Data Exchange (ETDEWEB)

    Mohadjer, K [Commissariat a l' Energie Atomique, 92 - Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires, direction des productions; Faculte des Sciences de l' Universite de Paris, 75 (France)

    1967-07-05

    The mineralogical investigation is based on determination of the amounts of quartz, clays, feldspars and on grain size analysis. A distinction was established between two lithological groups: the lower group with dominant silica the upper with dominant carbonates. Clays of the two groups are comparable with dominant illite, and accessory kaolinite and montmorillonite. The amounts of the elements Si, Al, Fe, Ca, Mg, Na, K, Ti, Mn, P, Ba, Sr, Rb, Pb, Cu, Ni, Co, V, Be, B, Zr, U, were determined by several analytical methods: chemistry, X ray fluorescence, spectrography and fluorimetry. Correlations between the chemical elements and the mineralogical components were computed and plotted. Lastly the conditions of filling up of the basin are defined, taking into account the Oligocene climatic conditions. (author) [French] L'etude mineralogique est basee sur les dosages du quartz, de la calcite, des argiles, des feldspaths et sur les granulometries. On a distingue 2 familles lithologiques: l'une riche en quartz dans la partie inferieure, l'autre riche en carbonate dans la partie superieure. Les argiles des 2 familles sont comparables: illite predominante, kaolinite et montmorillonite accessoires. Les elements: Si, Al, Fe, Ca, Mg, Na, K, Ti, Mn, P, Ba, Sr, Rb, Pb, Cu, Ni, Co, V, Be, B, Zr, U, ont ete doses par differentes methodes d'analyse: analyse chimique, fluorescence X, spectrographie et fluorimetrie. Une etude de correlation entre les elements chimiques et les constituants mineralogiques a ete realisee. Enfin, les conditions de remplissage du Bassin sont definies, en tenant compte du contexte climatique oligocene. (auteur)

  12. Theoretical study and construction of a multichannel {beta} spectrometer with uniform magnetic field; Etude et realisation d'un spectrometre {beta} multivoies a champ magnetique uniforme

    Energy Technology Data Exchange (ETDEWEB)

    Schussler, F [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1965-09-01

    After a brief survey of the interest of a multichannel beta spectrometer for studying decay schemes of short lived nuclides (30 seconds minimum, the theoretically well known characteristics of uniform magnetic field analyser (image of a large source, transmission and resolution) are briefly remembered. In the second part, the apparatus built as a result of these calculations is described. This apparatus allows the determination of beta spectra by simultaneous determination of the beta spectra in coincidence with four gamma rays predetermined in the gamma spectrum of the studied nuclide. Finally, in the last part, the experimental characteristics of the spectrometer (calibration in energy and transmission) and the first measurement of beta spectra ({sup 155}Sm) and of coincidences ({sup 24}Na), are given. (author) [French] Apres avoir brievement souligne l'interet pratique que presente un spectrometre multivoies pour l'etude des schemas de desintegration des corps radioactifs de courtes periodes (30 secondes au maximum), l'auteur effectue un rappel des caracteristiques theoriques bien connues d'un analyseur magnetique a champ uniforme (image d'une source etendue) calcul de la transmission et du pouvoir de resolution. Une deuxieme partie est consacree a la description de l'appareil realise d'apres ces calculs. Cet appareil permet le releve des spectres beta par detection, simultanee de dix groupes d'electrons d'energies differentes; il permet egalement le releve simultane des spectres beta en coincidence avec quatre rayonnements gammas preselectionnes a l'avance dans le spectre gamma du corps etudie. Dans une derniere partie enfin, sont donnees les caracteristiques experimentales du spectrometre (etalonnage en energie et en transmission) ainsi que les premiers resultats des etudes de spectre beta ({sup 155}Sm) et de coincidence ({sup 24}Na). (auteur)

  13. Contribution to the study of uranyl salts in butyl phosphate solutions; Contribution a l'etude des solutions de sels d'uranyle dans les phosphates butyliques

    Energy Technology Data Exchange (ETDEWEB)

    Coulon, A [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1965-06-01

    A spectroscopic study in the normal infrared region and involving the following associations: tri-alkyl phosphates (tri-butyl, tri-ethyl, tri-methyl), uranyl salts (nitrate, chloride, acetate) has confirmed the existence of an interaction between the phosphoryl group and the uranium atom, as shown by a movement of absorption band for the valency P = 0 from {approx} 1270 cm{sup -1} to {approx} 1180 cm{sup -1}. A study of the preparation, analysis and spectroscopy of the solids obtained by the precipitation of uranyl salts by acid butyl phosphates has been carried out. By infrared spectrophotometry it has been shown that the tri-butyl and di-butyl phosphates are associated in non-polar diluents even before the uranium is introduced. The extraction of uranyl salts from acid aqueous solutions by a diluted mixture of tri-butyl and di-butyl phosphates proceeds by different mechanisms according to the nature of the ion (nitrate or chloride). (author) [French] Une etude spectroscopique dans l'infrarouge moyen portant sur les associations: - phosphates trialcoyliques (tributylique - triethylique - trimethylique) - sels d'uranyle (nitrate, chlorure, acetate) a confirme l'existence d'une interaction entre le groupement phosphoryle et l'atome d'uranium, se manifestant par un deplacement de la bande d'absorption de la vibration de valence P = 0 de {approx} 1270 cm{sup -1} a {approx} 1180 cm{sup -1}. Une etude preparative, analytique et spectroscopique des solides obtenus par precipitation de sels d'uranyle par les phosphates butyliques acides a ete effectuee. La spectrophotomerie infrarouge met en evidence l'association, anterieure a toute introduction d'uranium, des phosphates tributylique et dibutylique dans des diluants non polaires. L'extraction de sels d'uranyle, d'une solution aqueuse acide par un melange dilue de phosphates tributylique et dibutylique, s'effectue suivant des processus differents a la nature de l'anion (nitrate ou chlorure). (auteur)

  14. Contribution to the study of deformed heavy nuclei by means of nuclear reactions; Contribution a l'etude des noyaux lourds deformes au moyen de reactions nucleaires

    Energy Technology Data Exchange (ETDEWEB)

    Gastebois, J. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1968-06-01

    The experimental results obtained in the study of the (d,p) reactions, at E{sub d} = 12 MeV, on the three even-even deformed nuclei {sup 170}Yb, {sup 172}Yb and {sup 174}Yb have been analysed in terms of DWBA calculations. The spectroscopic information relative to the odd final nuclei have been compared with the predictions of the collective model and of the Nilsson's model. The effect of various parameters used in the DWBA analysis (form factors, optical wave functions) has been carefully studied. The observed differences between the three final nuclei are qualitatively reproduced in the experimental study of resonances, seen in excitation functions of elastically and inelastically scattered protons on the same target nuclei, and corresponding to analogue states in the three nuclei {sup 171}Lu, {sup 173}Lu and {sup 175}Lu. (author) [French] Les resultats experimentaux de l'etude des reactions (d.p) a E{sub d} = 12 MeV, sur les noyaux deformes pairs-pairs {sup 170}Yb, {sup 172}Yb et {sup 174}Yb ont ete interpretes dans le cadre de l'approximation de Born des ondes deformees. Les informations spectroscopiques relatives aux noyaux impairs finals ont ete comparees aux predictions du modele collectif et du modele de Nilsson, apres avoir examine avec soin l'influence des differents parametres (facteurs de forme, fonctions d'onde 'optiques') utilises lors de l'analyse. Les differences observees entre les trois noyaux finals sont qualitativement reproduites par les resultats experimentaux de l'etude de resonances dans les fonctions d'excitation de diffusion elastique et inelastique de protons sur les memes noyaux-cibles, lors de la recherche d'etats analogues dans les noyaux {sup 171}Lu, {sup 173}Lu et {sup 175}Lu. (auteur)

  15. Physical study of the 'snow flake' version of the reactor EL-3 (1963); Etude physique de la version ''cristal de neige'' de la pile EL-3 (1963)

    Energy Technology Data Exchange (ETDEWEB)

    Abillon, E; Genthon, J P [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1963-07-01

    A systematic study has been made of the different thermodynamic and neutronic aspects of various versions of the 'snow flake' likely to fulfil the aims which were set out (improvement of the reactivity, of the experimental volume, improvement in the working conditions of EL-3). After this systematic study, a choice was made in principle of one version amongst the several available (solutions using 8 or 10 pencils-various methods of heat transfer: corrugation, cartridges which may or may not be filled with helium... etc., variable enrichments... ). The choice is that of a version which can already at the present be considered as feasible, which represents already a notable improvement of the pile and which does not imply the existence of a major problem as far as the possible change-over later to an improved version is concerned. This choice defines a fuel element and a configuration for the core. A detailed recapitulation has been made of all the research being carried out for the possible solutions in this particular case. (authors) [French] On a etudie systematiquement les differents aspects thermodynamiques et neutroniques de diverses versions 'cristal de neige' susceptibles de remplir les buts fixes (amelioration en reactivite, en volume experimental, amelioration des problemes d'exploitation de EL-3). Apres cette etude systematique, on a procede au choix de principe d'une version parmi les differentes solutions possibles (solutions a 8 ou 10 crayons - possibilite de transfert de chaleur divers: corrugations, cartouches remplies He ou non.... etc., enrichissements variables... ). Ce choix est celui d'une version qu'on peut juger viable des aujourd'hui, qui represente deja une amelioration importante de la pile et qui n'implique pas de probleme majeur quant au passage ulterieur et eventuel a une version plus amelioree. Ce choix definit un element combustible, et une configuration de coeur. On a recapitule et detaille sur ce cas particulier de pile les etudes

  16. Kinetic ion exchange studies in ultramarines by the radioactive tracer method; Etudes cinetiques d'echanges d'ions dans les outremers par la technique des traceurs radioactifs

    Energy Technology Data Exchange (ETDEWEB)

    May, S; Goenvec, H; Pinte, G [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1960-07-01

    The possibility of ion exchanges in various ultramarines has been studied in the aqueous phase. The kinetics of the exchange reactions is followed by studying the behaviour of a radioactive ion, either in the solution of the exchanging salt or in the ultramarine itself. The sodium in the make-up of the ultramarine, is found to exchange with various ions in solution. The reaction speeds appear to be governed by a diffusion process inside the grains of ultramarine. The diffusion coefficients and the activation energies are determined for the exchanges studied. Several exchange studies were carried out in an organic medium. The kinetics of ion exchange is also investigated in ultramarines from which most of the constituent sulphur has been eliminated. The results obtained in these ultramarines are compared with the exchange kinetics of the same ions in ordinary ultramarine. (author) [French] Nous avons etudie la possibilite d'echanges ioniques dans differents outremers, en phase aqueuse. L'etude cinetique des reactions d'echanges est suivie en etudiant le comportement d'ion radioactif, soit dans la solution du sel echangeant, soit dans l'outremer lui-meme. C'est le sodium de constitution de l'outremer qui s'echange avec differents ions en solution. Les vitesses de reactions semblent etre controlees par un processus de diffusion a l'interieur des grains d'outremer. Les coefficients de diffusion et les energies d'activation sont determines pour les echanges etudies. Quelques etudes sont realisees en milieu organique ou quelques echanges ont ete etudies. La cinetique d'echange d'ions est egalement etudie dans des outremers dans lesquels la majorite du soufre de constitution a ete eliminee. On compare les resultats obtenus dans ces outremers avec les cinetiques d'echanges des memes ions dans l'outremer ordinaire. (auteur)

  17. Study and achievement of a digital-analog-divider; Etude et realisation d'un diviseur-analogique-numerique

    Energy Technology Data Exchange (ETDEWEB)

    Petin, A [Commissariat a l' Energie Atomique, Cadarache (France). Centre d' Etudes Nucleaires

    1969-04-01

    paragraphes suivants presentent la recherche d'un schema synoptique, l'etude des circuits et la realisation. (auteur)

  18. Experimental study of metal gasketed joints for ultra-high vacuums; Etude experimentale de joints metalliques pour ultra-vide

    Energy Technology Data Exchange (ETDEWEB)

    Boulloud, J. P.; Schweitzer, J. [Commissariat a l' energie atomique et aux energies alternatives - CEA, Service de Physique Appliquee, groupe de Vide, Centre d' Etudes Nucleaires de Saclay (France)

    1960-07-01

    Various type of leak-tight metal joints have been studied with their application in assemblies containing total vacuums in mind. Their integrity has been tested with a helium leak detector, and leaks of about 2 x 10{sup -12} cm{sup 3} Atm/s per meter of joint have been measured, simultaneously with the clamping effort applied at the joint and the deformation of the metal gasket. The integrity to clamping effort ratio curve is not retraced in reverse upon relaxation of the clamping effort, but a 'return curve' analogous to a hysteresis cycle explains why certain types of joint retain their integrity at high temperatures. The use of a tracer gas permits discrimination between external permeation of the joint and gas from occlusions between its mating surfaces. The authors have been led to consider that neither the nature nor the purity or surface condition of the joint have any basic influence on its integrity. Clamping effort values in respect of various joints and necessary for total integrity are indicated. Reprint of a paper published in Le vide, no. 82, Jul-Aug 1959 [French] L'etude de differents types de joints metalliques etanches, en vue de leur application a l'ultra-vide, a ete effectuee a l'aide d'un detecteur de fuite a helium. On a mesure simultanement le debit de fuite, l'effort applique sur le joint et sa deformation. On a reussi a mesurer des debits de fuite de l'ordre de 2 x 10{sup -12} cm{sup 3} Atm/s/m de joint pour l'air. La courbe de l'etancheite en fonction de l'effort applique n'est pas reversible et on a pu mettre en evidence un 'cycle d'hysteresis' qui explique que certains joints conservent leur etancheite a haute temperature. La methode de mesure d'etancheite au moyen d'un gaz traceur a amene a faire une distinction entre la permeation et le degazage des gaz occlus dans l'interface des joints et a considerer que ni la nature, ni la purete et ni l'etat de surface du joint n'ont une influence primordiale sur l'etancheite de joint. Des valeurs

  19. Contribution to the study of internal friction in graphites; Contribution a l'etude du frottement interieur des graphites

    Energy Technology Data Exchange (ETDEWEB)

    Merlin, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1969-03-01

    A study has been made of the internal friction in different graphites between -180 C and +500 C using a torsion pendulum; the graphites had been previously treated thermo-mechanically, by neutron irradiation and subjected to partial annealings. It has been shown that there occurs: a hysteretic type dissipation of energy, connected with interactions between dislocations and other defects in the matrix; a dissipation having a partially hysteretic character which can be interpreted by a Granato-Luke type formalism and which is connected with the presence of an 'ultra-micro porosity'; a dissipation by a relaxation mechanism after a small dose of irradiation; this is attributed to the reorientation of bi-interstitials; a dissipation having the characteristics of a solid state transformation, this during an annealing after irradiation. It is attributed to the reorganization of interstitial defects. Some information has thus been obtained concerning graphites, in particular: their behaviour at low mechanical stresses, the nature of irradiation defects and their behaviour during annealing, the structural changes occurring during graphitization, the relationship between internal friction and macroscopic mechanical properties. (author) [French] L'etude du coefficient de frottement interieur au moyen d'un pendule de torsion entre -180 C et +500 C a ete realisee pour differents graphites apres des traitements thermo-mecaniques, des irradiations neutroniques et des guerisons partielles. Il a ete mis en evidence: une dissipation d'energie a caractere hysteretique, reliee aux interactions des dislocations avec les autres defauts de la matrice; une dissipation a caractere partiellement hysteretique, interpretable par un formalisme type Granato-Lucke et reliee a la presence d'une ''ultra-microporosite''; une dissipation par un mecanisme de relaxation, apres irradiation a faible dose, attribuee a la reorientation de di-interstitiels; une dissipation presentant les caracteristiques d

  20. Experimental study of superconductivity induced by proximity effects; Etude experimentale de la supraconductivite induite par effets de proximite

    Energy Technology Data Exchange (ETDEWEB)

    Martinet, A [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1966-11-15

    We present a study of the proximity effects between a superconductor (InBi or PbBi alloys) and a 'normal' metal (Zn or Sn respectively, above their critical temperature) using essentially the tunneling techniques. On the N side, some specific properties of such an induced superconductivity are described: linear variation of the pair potential near the critical temperature of the binary layer, T{sub CNS}; reduced energy scale at T{sub CNS}; evidence of a thermodynamic critical field (called breakdown field) presented by N above its critical temperature. On the S side, we study crossing from a gapless to a quasi gapless regime. This gives a proof of a finite coherence length at T{sub CNS}. Experimental details (in particular about the preparation and measurement of tunneling junctions) are given in annexe. Possible applications are suggested. (author) [French] Nous presentons une etude experimentale des effets de proximite entre un supraconducteur (alliages d'InBi ou de PbBi) et un metal 'normal' (Zn ou Sn respectivement, pris au-dessus de leur temperature critique), en utilisant principalement des mesures d'effet tunnel. Du cote N, on met en evidence des proprietes specifiques de cette supraconductivite induite: comportement lineaire du potentiel de paires pres de la temperature critique du bilame, T{sub CNS}; echelle d'energie reduite a T{sub CNS}; apparition d'un champ critique thermodynamique (appele champ de basculement) dans N au-dessus de sa temperature critique. Du cote S, nous etudions le passage continu d'une situation 'sans bande interdite' a basse temperature et en champ fort, a une situation 'pratiquement sans bande interdite' pres de T{sub CNS} en champ nul. Ceci fournit une preuve de la non divergence de la longueur de coherence a T{sub CNS}. Les techniques experimentales (et en particulier la preparation et la mesure de jonctions tunnel) sont decrites en detail dans une annexe. On envisage des applications pratiques possibles. (auteur)

  1. Study of the aqueous chemical treatment of uranium zirconium fuels; Etude du traitement chimique des combustibles uraniumzirconium par voie seche

    Energy Technology Data Exchange (ETDEWEB)

    Bourgeois, M; Nollet, P [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1964-07-01

    A dry process has been studied for separating the uranium from the zirconium-either for recovering the enriched uranium from fuel element production waste, or with a view to treating this waste after irradiation. In this process the alloy is treated with hydrochloric acid at 400 deg. C in a fluidized corundum bed which causes the zirconium to volatilize as tetrachloride and the uranium to form the trichloride. This latter is then converted to the hexafluoride by attack with fluorure. After the laboratory tests, a first pilot plant with a capacity of 1 kg of alloy was tried out at the Fontenay-aux-Roses Nuclear Research Centre; this made it possible to fix the operational conditions for the process. An industrial scale plant was then built with the collaboration of the from Kuhlmann, and operated until a satisfactory process had been developed for treating the waste. This installation treats 3 kg/h of alloy with a yield for the hydrochloric acid of about 50 per cent and with a uranium loss in the zirconium tetrachloride of about 0.1 per cent. An active pilot plant capable of treating of treating a few kilos of irradiated alloy is now being studied. (authors) [French] On a etudie un procede de voie seche pour effectuer la separation de l'uranium et du zirconium - soit en vue de la recuperation de l'uranium enrichi contenu dans les dechets de fabrication des elements combustibles - soit en vue du traitement de ceux-ci apres irradiation. Ce procede consiste a attaquer l'alliage par l'acide chlorhydrique a 400 deg. C dans un lit fluidise de corindon, ce qui a pour effet de volatiliser le zirconium sous forme de tetrachlorure et de transformer l'uranium en trichlorure. Ce dernier est ensuite converti en hexafluorure par action du fluor. Apres des essais de laboratoire, un premier pilote a l'echelle de 1 kg d'alliage a ete experimente au Centre d'Etudes Nucleaires de Fontenay-aux-Roses et a permis de determiner les conditions operatoires du procede. En collaboration avec

  2. Study and achievement of a digital-analog-divider; Etude et realisation d'un diviseur-analogique-numerique

    Energy Technology Data Exchange (ETDEWEB)

    Petin, A. [Commissariat a l' Energie Atomique, Cadarache (France). Centre d' Etudes Nucleaires

    1969-04-01

    theorie du systeme, les paragraphes suivants presentent la recherche d'un schema synoptique, l'etude des circuits et la realisation. (auteur)

  3. Study of the low energy gamma transitions of molybdenum 99; Etude des transitions gamma de basse energie du molybdene 99

    Energy Technology Data Exchange (ETDEWEB)

    Ravier, J.

    1959-07-01

    The study of the decay scheme of Mo{sup 99} has been performed on the magnetic iron-less and double focalization spectrograph of the Institute of Nuclear Physics of Lyon. Methods of internal and external conversion have been used. The intensities of the Mo{sup 99} sources used were not strong enough to determine the characteristics of the internal conversion accurately but were sufficient to precise the decay scheme at low energy. We have determined the internal conversion ratio for the transition of 180 KeV, we have got: 0.13 ± 0.03 which is not in agreement with the value given by a previous experiment based on γ-γ coincidence. Our method seems to be more reliable. We confirm the E2 feature of this transition and its 5/2+ spin. We have determined another important parameter for the 180 KeV de-excitation: the percentage of transitions that do not pass by the isomeric level but by the 140 KeV level is (6 ± 2)%, the isomeric level being at 142 KeV. The gamma spectra at low energy has been studied through the photoelectric effect in a lead converter [French] L'etude du schema de desintegration du Mo{sup 99} deja faite par differents auteurs a ete reprise par des methodes de conversion interne et externe, an moyen du spectrographe magnetique sans fer et a double focalisation de l'Institut de Physique Nucleaire de Lyon. Apres avoir cherche les possibilites d'obtention de sources de haute activite specifique par separation isotopique Szilard-Chalmers sur des molybdates alcalins, le spectre de conversion interne a basse energie a ete mesure. Ainsi se trouverent etre determines les coefficients partiaux de conversion interne. Le spectre γ a basse energie a ete etudier au moyen de l'effet photoelectrique sur un convertisseur de plomb. Les coefficients de conversion interne et les intensites relatives des differentes transitions ont ete calcules moyennant certaines hypotheses. La comparaison entre les valeurs donnees par la theorie et l'experience des differentes

  4. Theoretical and Experimental Studies of High-Frequency Plasma Structures; Etudes Theoriques et Experimentales sur les Structures HF a Plasma

    Energy Technology Data Exchange (ETDEWEB)

    Consoli, T. [CEA, Centre d' Etudes Nucleaires de Saclay (France)

    1969-03-15

    currents of more than 20 keV and of about 10 mA/cm{sub 2} were obtained. Ion entrainment for a magnetic field twice that necessary for resonance was also verified. Finally, with the Pleiade I device ({lambda} = 100 cm, P{sub HF} {approx}500 W, CW), the reflection of accelerated plasma jets by a mirror pulse lasting 75 {mu}s was verified. From measurements of the fast neutrals resulting from ion charge exchange (with the residual gas; p {<=} 10{sup -4} mmHg) it was deduced that the density of the ions (directed energy {approx} 1.5 keV) may be increased from 2 x 10{sub 8} cm{sup -3} (direct beam) to 6 x 10{sup 9} cm{sup -3} during the mirror pulse. The accumulated density appears to be limited by the charge exchange, and the increased duration of the mirror pulse to 200 {mu}s with p Less-Than-Or-Equivalent-To 10{sup -4} mmHg (unchanged) hardly improves the accumulation ratio. This agrees with the predictions if one takes into account the fact that the ion lifetime is {approx} 10 {mu}s. (author) [French] Il s'agit des etudes sur les structures HF a la resonance ( {omega}{sub ec} = {omega}{sub HF}) en champ magnetique inhomogene. Les points suivants ont ete developpes theoriquement: description analytique complete (relativiste et non lineaire) du mouvement individuel, compte tenu du fait que le nombre de revolutions des particules dans la zone de resonance est eleve ; etude du champ de charge d' espace autocoherent ( 'self-consistent') en vue d'etablir les conditions pour que l' energie des ions soit de l'ordre de celle gagnee par les electrons dans la zone de resonance; calcul du champ HF autocoherent dans le plasma accelere en vue d' etablir les conditions de fonctionnement optimum de l'accelerateur HF; probleme des pertes aux miroirs. Les resultats experimentaux ont ete obtenus avec divers dispositifs construits en vue de la verification des previsions theoriques.

  5. Autoradiographic methods for studying marked volatile substances (1961); Methode.d'etude autoradiographique de substances marquees volatiles (1961)

    Energy Technology Data Exchange (ETDEWEB)

    Cohen, Y; Wepierre, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1961-07-01

    de Pellerin (1957) evite cette dessication, mais la comparaison a l'echelle histologique de l'autoradiographie avec le document biologique lui-meme est difficile sinon impossible. Cependant, nous nous sommes inspire de certains points de chacune des deux methodes pour proposer la technique suivante d'etude autoradiographique de molecules marquees volatiles: 1- nous preparons la surface du bloc congele a autoradiographier a l'aide d'un microtome a congelation; 2- la derniere coupe de 20 {mu} d'epaisseur, dont les elements histologiques font face a ceux du bloc, est dessechee au froid et sert de document biologique de reference a l'autoradiographie obtenue, comme il est indique en 3; 3- les films radiographiques sont appliques sur le bloc congele a -30 deg. C. Les autoradiographies correspondent a la radioactivite de la molecule volatile et de ses produits de degradation non volatils. 4- De plus, le film radiographique est applique sur la coupe de 20 {mu} prealablement dessechee a -20 deg. C. Cette autoradiographie correspond a la radioactivite des produits de degradation non volatils de la molecule. 5- Nous nous sommes assuree de l'absence de diffusion de la molecule volatile et d'effets pseudo-radiographiques (photochimiques et autres). Cette methode qui nous a permis d'etudier la distribution d'un carbure, le paracymene ({sup 14}C) 7 a l'echelle macroscopique sur la souris entiere et a l'echelle microscopique sur la peau de chien, est susceptible d'une application generale. (auteurs)

  6. Investigation of the glide modes of single crystals of beryllium; Etude des modes de glissement de monocristaux de beryllium

    Energy Technology Data Exchange (ETDEWEB)

    Regnier, P [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1969-05-01

    glissement et des configurations de dislocations. L'etude du glissement prismatique a ete developpee beaucoup plus largement: l'influence de la temperature de la vitesse de deformation, de l'orientation initiale du plan de base et des plans prismatiques ont ete releves sur des echantillons d'orientation soignee, deformes en tension. On a egalement effectue quelques essais de microdeformation et observe de facon detaillee les lignes de glissement et les configurations de dislocations. Le comportement tres particulier observe n'est pas du aux impuretes, mais au glissement devie. On propose un mecanisme de blocage des dislocations permettant de l'expliquer. Comme ce mecanisme suppose que les dislocations a-bar peuvent aussi se dissocier sur les plans prismatiques [101-bar0] on examine cette possibilite et l'on propose plusieurs dissociations eventuelles dont la plus probable correspond a la transformation de phase hexagonale compacte {yields} cubique centree. En generalisant cette hypothese, on montre alors comment on peut rendre compte de la facilite relative des divers modes de glissement dans tous les metaux hexagonaux. (auteur)

  7. Theoretical, physical and experimental study of fissile aqueous media; Etudes theorique, physique et experimentale des milieux fissiles aqueux

    Energy Technology Data Exchange (ETDEWEB)

    Caizergues, R. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1969-04-01

    This thesis consists of a set of theoretical and experimental studies. a) Theoretical calculation methods used for cross-sections and the critical parameters; b) Comparison of the theoretical and experimental results: it is shown that the agreement between these results cannot be improved above a certain limit because of the accuracy with which are known the composition and the dimensions of the media and the microscopic cross-sections; c) Determination of the ratios {eta}{sup 9}-bar / {eta}{sup 5}-bar, {eta}{sup 3}-bar / {eta}{sup 5}-bar for fissile aqueous media ({eta}-bar: number of neutrons emitted per neutron absorbed, averaged over the reactor neutron spectrum). Evaluation of the accuracy to which these ratios are known; d) Effect of {sup 240}Pu: the measurements are carried out on Pu with a {sup 240}Pu content of 1.5 per cent, 3.11 per cent and 9.95 per cent; Calculation of the resonance integral I240 using the experimental results gives values in reasonable agreement with the results obtained by other more conventional methods. e) Measurement of the spectrum indices for aqueous media containing Pu, U5 and U3. With these latter it is possible to obtain mean fission cross-section ratios {sigma}f239-bar / {sigma}f235-bar for these different spectra. A calculation-experiment comparison is carried out using various theoretical methods. (author) [French] Cette these groupe un ensemble d'etudes theoriques et experimentales. a) Methodes theoriques de calcul utilisees pour les sections efficaces et les parametres critiques; b) Comparaisons des resultats theoriques et experimentaux: on montre que l'accord entre ces resultats ne peut etre ameliore au-dela de certaines limites vu la precision avec laquelle sont connues la composition et les dimensions des milieux et les sections efficaces macroscopiques; c) Determination des rapports {eta}{sup 9}-bar / {eta}{sup 5}-bar, {eta}{sup 3}-bar / {eta}{sup 5}-bar pour les milieux fissiles aqueux ({eta}: nombre de

  8. Etude exploratoire des conceptions de la circulation sanguine aupres d'eleves de l'ordre collegial

    Science.gov (United States)

    Robitaille, Jean-Marc

    Il existe peu d'etudes sur les conceptions touchant les domaines de la biologie, notamment sur les conceptions de la circulation sanguine Nous avons observe egalement l'absence de recherche menee aupres d'eleves de l'ordre collegial sur cette question. Nous avons voulu combler une lacune en menant une recherche sur les conceptions de la circulation sanguine aupres d'eleves de l'ordre collegial. Pour mener cette recherche nous nous sommes inspires d'une methode developpee par Treagust (1988). Le premier niveau de formulation didactique etablit l'architecture du systeme et la fonction nutritive de la circulation. Le second niveau de formulation didactique decrit et relie les parametres de la dynamique de la circulation et leur relation: Pression, Debit et Resistance. Le troisieme niveau de formulation didactique s'interesse au controle de la circulation du sang dans un contexte d'homeostasie qui implique la regulation de la pression arterielle. Nous avons construit un questionnaire en nous guidant sur les niveaux de formulation didactique et l'analyse des entrevues menees aupres de dix-huit eleves, representatifs de la population cible. Ce questionnaire fut administre a un echantillon de 2300 eleves disperses dans six colleges de la region de Montreal. Notre echantillon comprend des eleves inscrits a des programmes de l'ordre collegial en Sciences de la nature et en Techniques de la sante et qui n'ont pas suivi le cours sur la circulation sanguine. Notre analyse des reponses des eleves de notre echantillon aux questions sur le premier niveau de formulation didactique revele que la majorite des eleves considerent que le systeme circulatoire relie les organes les uns aux autres dans un circuit en serie. Notre analyse revele egalement que la majorite des eleves estiment que les nutriments sont extraits du sang par les organes selon un processus de selection base sur les besoins determines par la fonction de l'organe. Ces besoins sont differents selon les organes qui ne

  9. Theoretical, physical and experimental study of fissile aqueous media; Etudes theorique, physique et experimentale des milieux fissiles aqueux

    Energy Technology Data Exchange (ETDEWEB)

    Caizergues, R [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1969-04-01

    This thesis consists of a set of theoretical and experimental studies. a) Theoretical calculation methods used for cross-sections and the critical parameters; b) Comparison of the theoretical and experimental results: it is shown that the agreement between these results cannot be improved above a certain limit because of the accuracy with which are known the composition and the dimensions of the media and the microscopic cross-sections; c) Determination of the ratios {eta}{sup 9}-bar / {eta}{sup 5}-bar, {eta}{sup 3}-bar / {eta}{sup 5}-bar for fissile aqueous media ({eta}-bar: number of neutrons emitted per neutron absorbed, averaged over the reactor neutron spectrum). Evaluation of the accuracy to which these ratios are known; d) Effect of {sup 240}Pu: the measurements are carried out on Pu with a {sup 240}Pu content of 1.5 per cent, 3.11 per cent and 9.95 per cent; Calculation of the resonance integral I240 using the experimental results gives values in reasonable agreement with the results obtained by other more conventional methods. e) Measurement of the spectrum indices for aqueous media containing Pu, U5 and U3. With these latter it is possible to obtain mean fission cross-section ratios {sigma}f239-bar / {sigma}f235-bar for these different spectra. A calculation-experiment comparison is carried out using various theoretical methods. (author) [French] Cette these groupe un ensemble d'etudes theoriques et experimentales. a) Methodes theoriques de calcul utilisees pour les sections efficaces et les parametres critiques; b) Comparaisons des resultats theoriques et experimentaux: on montre que l'accord entre ces resultats ne peut etre ameliore au-dela de certaines limites vu la precision avec laquelle sont connues la composition et les dimensions des milieux et les sections efficaces macroscopiques; c) Determination des rapports {eta}{sup 9}-bar / {eta}{sup 5}-bar, {eta}{sup 3}-bar / {eta}{sup 5}-bar pour les milieux fissiles aqueux ({eta}: nombre de neutrons emis

  10. Lethal action of canavanine in Escherichia coli; Etude de l'action lethale de la canavanine sur Escherichia coli

    Energy Technology Data Exchange (ETDEWEB)

    Simonnet, Gerard Marc

    1972-01-04

    We studied the action of canavanine, analog of arginine, on the loss of bacteria viability; macromolecular synthesis (proteins, RNA and DNA) and DNA structure. We used bacteria because among different kinds of cells (ascitic tumor cells, erythrocytes, reticulocytes) they are the only ones which show the best capability of concentrating canavanine. This compound penetrates bacteria cells by active transportation uptake. Canavanine causes an irreversible inhibition of the cell division of bacteria. The loss of viability is connected to the incorporation in proteins of canavanine instead of arginine. Canavanine stimulates RNA synthesis in bacteria, strains RC{sup Str} arg{sup -}, starved of arginine, but it inhibits the incorporation of uracil, UMP and UDP in strains RC{sup str} arg{sup -}. Canavanine allows the completion of pre-initiated DNA chains; this result is similar to that observed of starved amino acid bacteria. The DNA of bacteria incubated with canavanine shows a lesion which results in the breaking of DNA. Part of the DNA does not sediment at 10 000 xg with the membranes. This DNA does not sediment either at 150 000 xg in alkaline sucrose gradient. Our results are consistent with the hypothesis that canavanine death is due to this breaking of the DNA. (author) [French] Dans le present travail, on a etudie l'action de la canavanine, analogue structural de l'arginine, sur la viabilite des bacteries, les syntheses macromoleculaires (proteines, ARN et ADN) et la structure de l'ADN. Les bacteries ont ete utilisees pour cette etude car des differents types de cellules testes (hepatomes ascitiques, reticulocytes et erythrocytes), ce sont elles qui presentent la meilleure permeabilite a la canavanine. Cette substance penetre dans les bacteries par un mecanisme de transport actif. La canavanine inhibe de facon irreversible la division cellulaire des bacteries. Cette perte de viabilite est liee a l'incorporation de la canavanine a la place de l'arginine dans les

  11. A study of the conformation and stability of nitroxide free radicals; Etude de la conformation et de la stabilite de radicaux libres nitroxydes

    Energy Technology Data Exchange (ETDEWEB)

    Briere, R [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1969-03-01

    les constantes de couplage des protons situes en {gamma} de l'azote ont une dependance spatiale tres marquee au meme titre que les protons situes en {beta}, ce que les etudes anterieures n'avaient pu preciser. Une analyse conformationnelle est effectuee par RMN a 310 MHz, en temperature variable. La synthese du di-t-butyl nitroxyde marque au carbone 13 en position {alpha} du groupement nitroxyde a permis de determiner avec certitude la constante d'interaction hyperfine electron carbone 13 quaternaire, grandeur qui n'avait pas ete mesuree jusqu'alors. Les constantes de couplage mesurees dans les radicaux piperidiniques tetramethyles en 2,2,6,6 ont pu etre ensuite attribuees a des carbones 13 situes en {beta} de l'azote, et leur variation a pu etre reliee a la conformation des cycles. C'est l'objet de la seconde partie. Dans un dernier chapitre, l'etude cinetique d'un radical nitroxyde instable, ayant un hydrogene en {beta}, met en evidence une decomposition bimoleculaire qui met en jeu la rupture de la liaison C-H; ceci est demontre par effet isotopique primaire. On peut conclure de cette etude qu'un nitroxyde est stable lorsque les differents groupes attaches a l'atome d'azote ne peuvent provoquer une decomposition du radical, soit intramoleculairement, si la geometrie de la molecule le permet, soit intermoleculairement par dimerisation sur un autre centre d'une molecule voisine, conduisant ainsi a une fragmentation ou a une disproportionation. (auteur)

  12. Electrochemical study in the molten sodium acid sulphate - potassium acid sulphate eutectic; Etude electrochimique dans l'eutectique fondu sulfate acide de sodium - sulfate acide de potassium

    Energy Technology Data Exchange (ETDEWEB)

    Le Ber, F [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-07-01

    protons de HSO{sup -}{sub 4}. Nous avons compare les domaines d'electroactivite obtenus a differentes electrodes (Ag-Au-Graphite-Hg). Nous avons envisage la dissolution de quelques oxydes et halogenures metalliques. Cette etude montre le role des ions HSO{sup -}{sub 4} en tant qu'accepteurs d'ions O{sup 2-}. Nous avons entrepris l'etude electrochimique de quelques systemes oxydo-reducteurs: H{sup +} / H{sub 2}, Ag{down_arrow} / Ag (I), les systemes du vanadium et de l'uranium, du mercure Hg{down_arrow} / Hg{sup 2-}{sub 2} et de l'or Au/Au{sup 3+}; puis l'attaque par le solvant de quelques metaux usuels comme l'aluminium, le fer, le cuivre et le nickel. L'etude des systemes de l'argent nous a permis d'atteindre les produits de solubilite de AgCl et AgBr et d'envisager le titrage coulometrique des ions Cl{sup -} par des ions Ag{sup +}. Nous avons mis en evidence differentes especes chimiques du vanadium pouvant exister dans l'eutectique fondu. (auteur)

  13. Etude hyperfrequence et ultrasonore des supraconducteurs organiques kappa-(ET)(2)X (X = copper(thiocyanogen), copper[N(CN)(2)]bromine)

    Science.gov (United States)

    Frikach, Kamal

    2001-09-01

    Dans ce travail je presente une etude de l'impedance de surface, ainsi que de l'attenuation et la variation de la vitesse ultrasonores dans les etats normal et supraconducteur sur les composes organiques k-(ET)2X (X = Cu(SCN) 2, Cu[N(CN)2]Br). A partir des mesures d'impedance de surface, les deux composantes sigma 1 et sigma2 de la conductivite complexe sont extraites en utilisant le modele de Drude. Ces mesures montrent que la symetrie du parametre d'ordre dans ces composes est differente de celle du cas BCS. Afin de comprendre le profil de sigma1 (T) nous avons etudie les fluctuations supraconductrices a partir de la paraconductivite sigma'( T). Cette etude est rendue possible grace a la structure quasi-2D des composes k-(ET)2X dans lesquelles les fluctuations supraconductrices sont fortes. Ces dernieres sont observees sur deux decades de temperatures dans le Cu(SCN)2. L'application du modele de Aslamazov-Larkin 2D et 3D montre la possibilite du passage du regime 2D a haute temperature au regime 3D au voisinage de Tc. En se basant sur ce resultat, nous avons calcule la paraconductivite en utilisant une approche a l'ordre d'une boucle a partir du modele de Lawrence-Doniach. En tenant compte de la correction par la self energie dans la limite dynamique (17 GHz), l'ajustement de la paraconductivite calculee est en bon accord avec les donnees experimentales. Le couplage interplan obtenu est compatible avec le caractere quasi-2D des composes organiques. Le temps de relaxation des quasi-particules dans l'etat supraconducteur est ensuite extrait pour la premiere fois dans ces composes dont le comportement en fonction de la temperature est compatible avec la presence des noeuds dans le gap. Dans l'etat normal, la variation de la vitesse ultrasonore presente un comportement anormal caracterise par un fort ramollissement a T = 38 K et 50 K dans k-(ET) 2Cu(SCN)2 et k-(ET)2Cu[N(CN) 2]Br respectivement dont l'amplitude est independante du champ magnetique jusqu'a H = Hc 2

  14. Study of the point defects formed in cobalt by electron bombardment; Etude des defauts ponctuels crees par bombardement electronique dans le cobalt

    Energy Technology Data Exchange (ETDEWEB)

    Sulpice, G [Commissariat a l' Energie Atomique, 38 - Grenoble (France). Centre d' Etudes Nucleaires

    1968-12-01

    A study of the point defects formed in cobalt by electron bombardment is presented. The results are compared with those previously obtained for two other ferromagnetic metals of different structure, iron and nickel. In the first part we give a review of the literature concerning the creation of point defects, their contribution to resistivity and their annihilation mode in the three structure types. We then describe the experimental techniques adapted, in particular the study of the resistivity increase during a linear temperature rise. Our investigations concern the following, essential points : the observation of the successive annihilation stages of the point defects formed in pure cobalt, a study of the variations with respect to the doses and energy of the incident particles, and the determination of the annealing kinetics and the corresponding activation energies. The results are finally compared with the various models of point defect annihilation proposed for other metals: none of these interpretations is in perfect agreement with our results. In the case of cobalt we are thus led to modify the model proposed by our laboratory for iron an nickel. The difference between these three metals is explained by the anisotropic character of the cobalt matrix. (author) [French] Nous presentons une etude des defauts ponctuels crees par bombardement electronique dans le cobalt et comparons nos resultats a ceux obtenus precedemment dans deux autres metaux ferromagnetiques de structure differente, le fer et le nickel. Dans une premiere partie nous faisons une mise au point bibliographique comparee sur la creation des defauts, leur contribution a la resistivite et leur mode d'annihilation dans les trois types de structure. Nous decrivons ensuite les techniques experimentales mises au point, en particulier l'etude du revenu de la resistivite au cours d'une montee lineaire de temperature. Au cours de ce travail, nous avons mis en evidence les stades successifs d

  15. Contribution to the study of point defects formed in nickel by electron bombardment; Contribution a l'etude des defauts ponctuels crees par bombardement electronique dans le nickel

    Energy Technology Data Exchange (ETDEWEB)

    Oddou, J L [Commissariat a l' Energie Atomique, 38 - Grenoble (France). Centre d' Etudes Nucleaires

    1968-12-01

    After a short account of the experimental techniques employed in our studies, the experimental results obtained on pure nickel samples are exposed. The apparition of the successive annihilation stages of point defects created by electron bombardment is established by isochronal heat treatments: the annihilation kinetics and the corresponding activation energies are determined. The effect of the incident particle doses is also studied. The experimental results are then compared with R.A. Johnson's theoretical calculations of the stability and the migration of point defects in nickel, and taking into account the results obtained by Peretto in magnetic after effect measurements. This leads us to a model in good agreement with calculations and experiment for the first stages. In a second chapter the behaviour of nickel doped by certain impurities is studied. First, the results concerning the rate of increase of resistivity (function of sample purity) is investigated. Two possible explanations of the observed phenomenon are proposed: either a deviation with respect to Mathiessen's law, or an increase of the number of defects formed in the presence of impurity atoms. Finally, a study of the resistivity recovery of the doped samples permits us to suggest an order of magnitude for the binding energy interstitial/impurity atom in the nickel matrix. (author) [French] Apres avoir brievement rappele les techniques experimentales que nous avons utilisees pour cette etude, nous exposons les resultats experimentaux obtenus sur des echantillons de nickel pur. Les stades successifs d'annihilation des defauts ponctuels crees par bombardement electronique sont mis en evidence par traitements thermiques isochrones; les cinetiques de disparition, et les energies d'activation correspondantes sont determinees. Nous etudions egalement l'effet de la dose des particules incidentes. Les resultats experimentaux sont ensuite compares avec les calculs theoriques de R.A JOHNSON sur la stabilite

  16. Contribution to the micrographic study of uranium and its alloys; Contribution a l'etude micrographique de l'uranium et de ses alliages

    Energy Technology Data Exchange (ETDEWEB)

    Monti, H [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1956-06-15

    The present report is the result of research carried out by the radio metallurgy section, to perfect micrographic techniques applicable to the study of samples of irradiated uranium. In the first part of this work, two polishing baths are developed, having the qualities with a minimum of disadvantages inherent in their respective compositions: they are, on the one hand perchloric acid-ethanol mixtures, and on the other hand a phospho-chromic-ethanol bath. In the chapter following, the micrographic attack of uranium is studied. The only satisfactory process is oxidation by cathode bombardment forming epitaxic layers. In the third chapter, an attempt is made to characterise the different surface states of the uranium by dissolution potential measurements and electronic diffraction. In the fourth chapter are given some examples of the application of these techniques to the micrographic study of various uranium alloys. In an appendix, it is shown how the chemical oxidation after phospho-chromic-alcohol polishing allows the different inclusions present in the molten uranium to be distinguished. By X-ray diffraction, uranium monocarbide and mononitride inclusions in particular are characterised. (author) [French] Le present rapport est le resultat de recherches effectuees au service de radiometallurgie pour la mise au point de techniques micrographiques applicables a l'etude d'echantillons d'uranium irradie. Dans la premiere partie de ce travail, nous mettons au point deux bains de polissage qui presentent les qualites inherentes a leur composition respective, avec le minimum d'inconvenients: ce sont d'une part des melanges acide perchlorique-ethanol, et d'autre part un bain phospho-chromique-ethanol. Dans le chapitre suivant, nous etudions l'attaque micrographique de l'uranium. Seul le procede d'oxydation par bombardement cathodique formant des couches epitaxiques, est satisfaisant. Dans le troisieme chapitre, nous essayons de caracteriser les differents etats de

  17. Some ways for the investigation of the solar modulation of cosmic electrons; Moyens d'etude de la modulation solaire des electrons cosmiques

    Energy Technology Data Exchange (ETDEWEB)

    Mercier, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1969-07-01

    In this report, we are investigating the solar modulation of cosmic electrons, in different ways. By comparing the calculated intensity with the measured intensity of positrons, we can evaluate the solar modulation of positrons, hence the modulation of negatons, since the modulation of negatons is probably the same that for positrons. By comparing the electron spectrum in interstellar space needed to explain the galactic background radio emission with that observed near the earth, we can deduce information about the modulation of electrons. We can investigate the modulation through the observation of its variations during the solar cycle. This different ways lead us to compatible results. In spite of the fact that the precision of the experimental data is poor, the modulation can be represented by: a constant or a form in exp(- K/Ro{beta}) under the rigidity Ro {approx_equal} 0,5 BV; a form in exp(- K/R) or exp(- K/R{beta}) above this rigidity. In addition, the investigation of both electrons and protons displays that the diffusion-convection theory is inadequate to explain all the features of the solar modulation. (author) [French] Dans le present rapport, nous etudions la modulation solaire des electrons cosmiques a l'aide de plusieurs methodes. Par comparaison entre l'intensite calculee et l'intensite mesuree des positons, on peut evaluer la modulation solaire des positons, et aussi des negatons, puisque la modulation des negatons est probablement la meme que celle des positons. Par le calcul, a partir du bruit de fond radio, du flux des electrons a l'exterieur du systeme solaire et sa confrontation avec le flux observe a l'orbite de la Terre permet l'etude de la modulation solaire des electrons. On peut aussi analyser ce phenomene de modulation pour l'etude de ses variations au cours du cycle solaire. Ces diverses methodes donnent des resultats compatibles. En depit de la precision mediocre des donnees experimentales, on peut caracteriser la modulation par: une

  18. Possibilities and limitations of analogue methods for studying the dynamics of nuclear power stations; Possibilites et limitations du calcul analogique pour les etudes dynamiques de centrales nucleaires

    Energy Technology Data Exchange (ETDEWEB)

    Caillet, C; Deat, M [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1958-07-01

    'on decrit en discutant la validite des approximations choisies. 4. Les simulateurs de machines tournantes: on souligne le caractere particulier que presentent les calculs des machines tournantes en raison de la necessite ou l'on est de passer par l'intermediaire d'abaques. On propose l'utilisation d'une memoire a acces aleatoire permettant un traitement analogique de ces problemes. 5. Etude d'une centrale nucleaire: on etudie, sur un exemple, les problemes poses par l'interconnexion d'elements du type precedent pour la simulation de grands ensembles (centrales nucleaires) et on souligne le role des elements ordinaires de calcul. 6. Conclusion: on souligne la necessite pour toutes ces etudes, de disposer d'un materiel de qualite et on discute la signification des resultats ainsi obtenus. (auteur)

  19. Theoretical study of properties due to the curvature in the toroid shape in magnetohydrodynamics; Etude theorique des proprietes dues a la courbure dans les configurations toriques en magnetohydrodynamique

    Energy Technology Data Exchange (ETDEWEB)

    Adam, J C [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1968-03-01

    - We are considering a toroidal plasma centred around a closed {gamma}. When the rotational transform L/2{pi} approach an integer k if some specific relations are not satisfied curvature effects can become very important. When the rotational transform is created by current flowing in the plasma this happen if the coefficient a{sub k} of the Fourier expansion of curvature 1/R(s) of is non equal zero. One find then that the influence of a{sub k} is preponderant and that is possible to neglect all the other members of the series to study the neighbourhood of the corresponding equilibrium singularity. By developing an adapted coordinate system it is thus possible to take into account curvature effects at the lowest order. Equilibrium study bring us to introduce an equilibrium parameter {nu} {<=} 1 characterizing curvature effects. It is shown that the more {nu} is near of 1 the more shear and V{sup {phi}} quantities occurring in the stability criterion are important. Finally stability investigation show that the larger is the integer k the smaller is the domain of stability when L/2{pi} is near of k. (author) [French] Nous considerons un plasma toroidal centre autour d'une courbe fermee {gamma}. Lorsque la transformation rotationnelle L/2{pi} est voisine d'un nombre entier k, si certaines relations ne sont pas satisfaites, les effets de courbure peuvent devenir tres importants. Quand la transformation rotationnelle est cree par les courants circulant dans le plasma ceci se produit si le coefficient a{sub k} du developpement en serie de Fourier de la courbure 1/R(s) de {gamma} est non nul. On trouve alors que l'influence du k-ieme coefficient devient preponderante et il possible de negliger les autres termes pour etudier le voisinage de la singularite d'equilibre correspondante. En developpant un systeme de coordonnees adapte il est alors possible de tenir compte des le premier ordre des effets de courbure. L' etude de l'equilibre conduit a introduire un parametre d

  20. A statistical analysis of electrical cerebral activity; Contribution a l'etude de l'analyse statistique de l'activite electrique cerebrale

    Energy Technology Data Exchange (ETDEWEB)

    Bassant, Marie-Helene

    1971-01-15

    The aim of this work was to study the statistical properties of the amplitude of the electroencephalographic signal. The experimental method is described (implantation of electrodes, acquisition and treatment of data). The program of the mathematical analysis is given (calculation of probability density functions, study of stationarity) and the validity of the tests discussed. The results concerned ten rabbits. Trips of EEG were sampled during 40 s. with very short intervals (500 μs). The probability density functions established for different brain structures (especially the dorsal hippocampus) and areas, were compared during sleep, arousal and visual stimulus. Using a Χ{sup 2} test, it was found that the Gaussian distribution assumption was rejected in 96.7 per cent of the cases. For a given physiological state, there was no mathematical reason to reject the assumption of stationarity (in 96 per cent of the cases). (author) [French] Le but de ce travail est d'etudier les proprietes statistiques des amplitudes du signal electroencephalographique. La methode experimentale est decrite (implantation d'electrodes, acquisition et traitement des donnees). Le programme d'analyse mathematique est precise (calcul des courbes de repartition statistique, etude de la stationnarite du signal) et la validite des tests, discutee. Les resultats de l'etude portent sur 10 lapins. Des sequences de 40 s d'EEG sont echantillonnees. La valeur de la tension est prelevee a un pas d'echantillonnage de 500 μs. Les courbes de repartition statistiques sont comparees d'une region de l'encephale a l'autre (l'hippocampe dorsal a ete specialement analyse) ceci pendant le sommeil, l'eveil et des stimulations visuelles. Le test du Χ{sup 2} rejette l'hypothese de distribution normale dans 97 pour cent des cas. Pour un etat physiologique donne, il n'existe pas de raison mathematique a ce que soit repoussee l'hypothese de stationnarite, ceci dans 96.7 pour cent des cas. (auteur)

  1. Study of liquid hydrogen and liquid deuterium cold neutron sources; Etude de sources de neutrons froids a hydrogene et deuterium liquides

    Energy Technology Data Exchange (ETDEWEB)

    Harig, H D [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1967-12-01

    In view of the plant of the cold neutron source for a high flux reactor (maximal thermal flux of about 10{sup 15} n/cm{sup 2}s) an experimental study of several cold sources of liquid hydrogen and liquid deuterium has been made in a low power reactor (100 kW, about 10{sup 12} n/cm{sup 2}s). We have investigated: -cold neutron sources of liquid hydrogen shaped as annular layers of different thickness. Normal liquid hydrogen was used as well as hydrogen with a high para-percentage. -Cold neutron sources of liquid deuterium in cylinders of 18 and 38 cm diameter. In this case the sources could be placed into different positions to the reactor core within the heavy water reflector. This report gives a general description of the experimental device and deals more detailed with the design of the cryogenic systems. Then, the measured results are communicated, interpreted and finally compared with those of a theoretical study about the same cold moderators which have been the matter of the experimental investigation. (authors) [French] En vue de l'installation d'une source a neutrons froids dans un reacteur a haut flux (flux thermique maximal environ 10{sup 15} n/cm{sup 2}s), nous avons fait une etude neutronique experimentale de differentes sources froides a hydrogene et a deuterium liquides aupres d'un reacteur a faible puissance (100 kW environ 10{sup 12} n/cm{sup 2}s). Nous avons etudie: des couches annulaires de differentes epaisseurs d'hydrogene liquide normal et d'hydrogene a grand pourcentage para, des cellules cylindriques de 18 et 38 cm de diametre, remplies de deuterium liquide et placees a differentes positions dans le reflecteur D{sub 2}O. Ce travail traite l'implantation de l'installation cryogenique et donne une description generale de l'experience. L'interpretation des resultats fait etat entre autres d'une comparaison entre l'experience et une etude theorique portant sur les memes moderateurs. (auteurs)

  2. Contribution to the micrographic study of uranium and its alloys; Contribution a l'etude micrographique de l'uranium et de ses alliages

    Energy Technology Data Exchange (ETDEWEB)

    Monti, H. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1956-06-15

    The present report is the result of research carried out by the radio metallurgy section, to perfect micrographic techniques applicable to the study of samples of irradiated uranium. In the first part of this work, two polishing baths are developed, having the qualities with a minimum of disadvantages inherent in their respective compositions: they are, on the one hand perchloric acid-ethanol mixtures, and on the other hand a phospho-chromic-ethanol bath. In the chapter following, the micrographic attack of uranium is studied. The only satisfactory process is oxidation by cathode bombardment forming epitaxic layers. In the third chapter, an attempt is made to characterise the different surface states of the uranium by dissolution potential measurements and electronic diffraction. In the fourth chapter are given some examples of the application of these techniques to the micrographic study of various uranium alloys. In an appendix, it is shown how the chemical oxidation after phospho-chromic-alcohol polishing allows the different inclusions present in the molten uranium to be distinguished. By X-ray diffraction, uranium monocarbide and mononitride inclusions in particular are characterised. (author) [French] Le present rapport est le resultat de recherches effectuees au service de radiometallurgie pour la mise au point de techniques micrographiques applicables a l'etude d'echantillons d'uranium irradie. Dans la premiere partie de ce travail, nous mettons au point deux bains de polissage qui presentent les qualites inherentes a leur composition respective, avec le minimum d'inconvenients: ce sont d'une part des melanges acide perchlorique-ethanol, et d'autre part un bain phospho-chromique-ethanol. Dans le chapitre suivant, nous etudions l'attaque micrographique de l'uranium. Seul le procede d'oxydation par bombardement cathodique formant des couches epitaxiques, est satisfaisant. Dans le troisieme chapitre, nous essayons

  3. Experimental study of the radio-active contamination of certain cultivated plants by irrigation water; Etude experimentale de la contamination radioactive par l'eau d'irrigation de certaines plantes cultivees

    Energy Technology Data Exchange (ETDEWEB)

    Michon, G. [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires; Barbier, G.; Le Blaye, P.; Brossard, M. [Station Centrale d' Agronomie, 78 - Versailles (France); Fioramonti, S.; Marty, J.R. [Station Agronomique de Toulouse, 31 (France); Benard, P.; Flanzy, M. [Station Centrale de Technologie des Produits Vegetaux, 11 - Narbonne (France); Delas, J.; Delmas, J.; Demias, Ch. [Station d' Agronomie de Bordeaux (Pont de la Maye), 33 (France); Huguet, C. [Station Agronomique d' Avignon, 84 (France)

    1964-07-01

    This report follows on to the CEA reports no 1860 and 2159 and gives the results obtained during the years 1961 and 1962. These results confirm for the most part those obtained previously and deal also with a larger variety of vegetables. Vines and artificial prairies were also dealt with during the course of this work. The large dispersion of the limiting values of the coefficient r (the ratio between the amount of radio-elements in a kilogram of product harvested, to the amount of radio-elements present in a litre of irrigation water) with different types of soil, different plant types, etc... , makes it impossible to draw any general conclusions. Each case of rejection requires a special study of which the outlive is given. At all events it is to be expected that in the majority of cases these studies will lead to a decrease in the norms now in force. (authors) [French] Ce rapport fait suite aux rapports CEA no 1860 et 2159 et rapporte les resultats obtenus pendant les annees 1961 et 1962. Ces resultats confirment dans l'ensemble ceux precedemment obtenus tout en augmentant la variete des legumes etudies. La vigne et les prairies artificielles ont egalement fait l'objet d'etudes. La grande dispersion des valeurs limites du coefficient r (rapport entre la quantite de radioelements dans un kg de produits recoltes a la quantite de radioelements presente dans un litre d'eau d'irrigation) en rapport avec la nature des sols, le type vegetal, etc.., ne permet pas de degager de conclusions generales. Chaque cas de rejet necessite une etude particuliere dont le schema est donne. En tout etat de cause l'on doit s'attendre a ce que dans la plupart des cas ces etudes conduisent a une diminution des normes actuellement utilisees. (auteurs)

  4. Clinical and symptomatological study of pigs subjected to a lethal dose of integral gamma irradiation; Etude clinique et symptomatologique chez le porc soumis a une irradiation gamma totale a dose letale

    Energy Technology Data Exchange (ETDEWEB)

    Vaiman, M; Guenet, J -L; Maas, J; Nizza, P

    1966-05-01

    Results are reported from a clinical and haematological study on a Corsican species of pigs wholly exposed to an approximately lethal dose of {gamma} radiation. The aim of this work was to examine the changes in the irradiation syndrome of irradiation for pigs to make it thus possible to devise further experiments, in particular in the therapeutic field. The dose received was 285 rads (measured as the absorption in the vertical antero-posterior medial plane). Data are presented on cyto-haematological changes in the blood circulating immediately after irradiation, and followed up to death, and changes in the medullary cytology after irradiation. The clinical picture of lethal radiation injury in swine is described. (authors) [French] Les auteurs rapportent les resultats d'une etude clinique et hematologique chez des porcs de race corse irradies in toto a dose sensiblement letale. Le but de cette etude etait de connaitre l'evolution du syndrome aigu d'irradiation chez le porc et de permettre ainsi le developpement d'experimentations ulterieures, en particulier dans le domaine therapeutique. La dose delivree etait de 285 rad (en dose absorbee au niveau du plan median vertical anteroposterieur. L'etude a porte essentiellement: 1. Sur les modifications cyclo-hematologiques du sang circulant immediatement apres l'irradiation, pour les differentes lignees cellulaires; l'evolution de ces modifications a ete notee jusqu'a la mort; 2. Sur les modifications de la cytologie medullaire apres irradiation (evolution du myelogramme et essai d'evaluation de la cellularite de la moelle osseuse);: 3. Sur les signes cliniques, d'ailleurs tres discrets, observes chez les porcs apres irradiation. (auteurs)

  5. Study of the machining of uranium carbide rods obtained by continuous casting under electronic bombardment; Etude de l'usinage de barreaux de carbure d'uranium obtenus par coulee continue sous bombardement electronique

    Energy Technology Data Exchange (ETDEWEB)

    Rousset, P; Accary, A [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1965-07-01

    The authors consider the various methods of machining uranium mono-carbide and compare them critically in the case of their application to uranium carbide obtained by fusion under an electronic bombardment and continuous casting. This study leads them to propose two mechanical machining methods: cylindrical rectification and center-less rectification, preceded by a preliminary roughing out of a cylinder, the latter appearing more suitable. A study of the machining yields as a function of the diameter of the rough bars and of the diameter of the finished rods has shown that an optimum value of the rough bar diameter exists for each value of the finished rod diameter. It is found that the yield increases as the diameter itself increases, this yield rising from 45 per cent to around 70 per cent as the diameter of the rough bars increases from 25-26 mm to 37-38 mm. (authors) [French] Les auteurs envisagent les differentes methodes d'usinage du monocarbure d'uranium et se livrent a une etude critique de celles-ci, dans le cas de leur application a l'usinage de barreaux de carbure d'uranium obtenus par fusion sous bombardement electronique et coulee continue. Cette etude les conduit a proposer deux methodes d'usinage mecanique: la rectification cylindrique et la rectification 'centerless', precedee d'un ebauchage par carottage, la seconde paraissant la plus appropriee. L'etude des rendements d'usinage en fonction du diametre des barreaux bruts et du diametre des barreaux finis, a mis en evidence une valeur optimale du diametre des barreaux bruts pour chaque valeur du diametre des barreaux usines. Elle a montre que le rendement croit lorsque le diametre croit lui-meme, ce rendement passant d'environ 45 pour cent a environ 70 pour cent, lorsque le diametre des barreaux bruts passe de 25-26 mm a 37-38 mm.

  6. Contribution to the development of a gamma radiation camera for use in scintigraphy; Contribution a l'etude et a la realisation d'une camera a rayonnement gamma en vue d'une application a la scintigraphie

    Energy Technology Data Exchange (ETDEWEB)

    Felix, J [Commissariat a l' Energie Atomique, Cadarache (France). Centre d' Etudes Nucleaires

    1969-10-01

    This report constitutes an attempt to study systematically the properties of the detection head of a multichannel collimating grid camera. The object has been to show the disadvantages of present equipment, and to propose possible solutions for overcoming them: firstly by improving the methods used for collecting data, and the performances of the equipment doing the collecting; secondly by devising methods for processing the data so as to reduce image distortion and, first of all, the astigmatism due to the collimator. The first part deals with the study of the formation of the image by means of the collimating grid, the second with the examination of many systems which could be used for acquiring data. The last part summarizes the experiments carried out and proposes an experimental programme for the development of a prototype. (author) [French] Ce rapport constitue une tentative d'etude systematique des proprietes de la tete de detection d'une camera a grille collimatrice multicanal. Le but de cette etude est de souligner les inconvenients des dispositifs actuels et d'esquisser des solutions propres a y remedier: premierement, par l'amelioration du mode d'acquisition des donnees et des performances du sous-ensemble charge de cette acquisition; deuxiemement, par la recherche de methodes de traitement des donnees propres a reduire les distorsions de l'image et en premier lieu l'astigmatisme du au collimateur. La premiere partie en est devolue a l'etude de la formation de l'image par l'intermediaire de la grille collimatrice, la seconde a l'examen de nombreux systemes utilisables pour l'acquisition des donnees. La derniere partie resume les experiences effectuees et propose un programme de manipulations utiles a l'elaboration d'un prototype d'appareil. (auteur)

  7. Studies of elements used in hertzian interferometry (millimetric waves). Measurement of the permittivity of a liquid dielectric; Etudes d'elements utilises en interferometrie hertzienne (ondes millimetriques). Mesure de la permittivite de dielectrique liquide

    Energy Technology Data Exchange (ETDEWEB)

    Dagai, M [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-12-01

    Study of some elements used in EHF interferometry (bond of millimeter waves). This study is about design of the following elements: horns, horns associated with lens, power separators: -) Study of assemblies allowing measurements of complex dielectric constants of liquids. These devices are used in free propagation about wave lengths {<=} 2 mm; -) Studied devices: Interferometer for 2 separated waves and Michelson's type interferometer; -) 4 liquids have been used: {epsilon}'{sub r} Octane from -50 to 70 C (-58 to 158 F), {epsilon}'{sub r} and {epsilon}'' [Monochlorobenzene at 22,8 C (73 F), Mixture of octane with 10,8 per cent citral at 22 C (72 F) and Benzene at 21 C (70 F)]. -) Precision obtained about measurements: {delta}{epsilon}'/{epsilon}' de 1 a 2%, {delta}{epsilon}''/{epsilon}'' de 4 a 6%.(author) [French] Etudes d'elements utilises en interferometrie hertzienne fonctionnant en ondes millimetriques. Cette etude porte sur la realisation des elements suivants: cornets, cornets associes aux lentilles, separateurs de puissance. Etudes des montages permettant les mesures de la constante dielectrique complexe des corps liquides. Ces montages fonctionnent en propagation libre, sur des longueurs d'onde inferieures ou egales a 2 millimetres. Les montages etudies sont: interferometre a deux ondes separees et interferometre du type Michelson. De plus 4 liquides ont ete etudies: {epsilon}'{sub r} octane de -50 a 70 C, {epsilon}'{sub r} et {epsilon}'' [monochlorobenzene a 22,8 C et melange octane avec 10,8 pour cent citral a 22 C, Benzene a 21 C]. Les precisions obtenues sur les mesures sont: {delta}{epsilon}'/{epsilon}' de 1 a 2 pour cent, {delta}{epsilon}''/{epsilon}'' de 4 a 6 pour cent.

  8. Clinical and symptomatological study of pigs subjected to a lethal dose of integral gamma irradiation; Etude clinique et symptomatologique chez le porc soumis a une irradiation gamma totale a dose letale

    Energy Technology Data Exchange (ETDEWEB)

    Vaiman, M.; Guenet, J.-L.; Maas, J.; Nizza, P

    1966-05-01

    Results are reported from a clinical and haematological study on a Corsican species of pigs wholly exposed to an approximately lethal dose of {gamma} radiation. The aim of this work was to examine the changes in the irradiation syndrome of irradiation for pigs to make it thus possible to devise further experiments, in particular in the therapeutic field. The dose received was 285 rads (measured as the absorption in the vertical antero-posterior medial plane). Data are presented on cyto-haematological changes in the blood circulating immediately after irradiation, and followed up to death, and changes in the medullary cytology after irradiation. The clinical picture of lethal radiation injury in swine is described. (authors) [French] Les auteurs rapportent les resultats d'une etude clinique et hematologique chez des porcs de race corse irradies in toto a dose sensiblement letale. Le but de cette etude etait de connaitre l'evolution du syndrome aigu d'irradiation chez le porc et de permettre ainsi le developpement d'experimentations ulterieures, en particulier dans le domaine therapeutique. La dose delivree etait de 285 rad (en dose absorbee au niveau du plan median vertical anteroposterieur. L'etude a porte essentiellement: 1. Sur les modifications cyclo-hematologiques du sang circulant immediatement apres l'irradiation, pour les differentes lignees cellulaires; l'evolution de ces modifications a ete notee jusqu'a la mort; 2. Sur les modifications de la cytologie medullaire apres irradiation (evolution du myelogramme et essai d'evaluation de la cellularite de la moelle osseuse);: 3. Sur les signes cliniques, d'ailleurs tres discrets, observes chez les porcs apres irradiation. (auteurs)

  9. Experimental study of the radio-active contamination of certain cultivated plants by irrigation water; Etude experimentale de la contamination radioactive par l'eau d'irrigation de certaines plantes cultivees

    Energy Technology Data Exchange (ETDEWEB)

    Michon, G [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires; Barbier, G; Le Blaye, P; Brossard, M [Station Centrale d' Agronomie, 78 - Versailles (France); Fioramonti, S; Marty, J R [Station Agronomique de Toulouse, 31 (France); Benard, P; Flanzy, M [Station Centrale de Technologie des Produits Vegetaux, 11 - Narbonne (France); Delas, J; Delmas, J; Demias, Ch [Station d' Agronomie de Bordeaux (Pont de la Maye), 33 (France); Huguet, C [Station Agronomique d' Avignon, 84 (France)

    1964-07-01

    This report follows on to the CEA reports no 1860 and 2159 and gives the results obtained during the years 1961 and 1962. These results confirm for the most part those obtained previously and deal also with a larger variety of vegetables. Vines and artificial prairies were also dealt with during the course of this work. The large dispersion of the limiting values of the coefficient r (the ratio between the amount of radio-elements in a kilogram of product harvested, to the amount of radio-elements present in a litre of irrigation water) with different types of soil, different plant types, etc... , makes it impossible to draw any general conclusions. Each case of rejection requires a special study of which the outlive is given. At all events it is to be expected that in the majority of cases these studies will lead to a decrease in the norms now in force. (authors) [French] Ce rapport fait suite aux rapports CEA no 1860 et 2159 et rapporte les resultats obtenus pendant les annees 1961 et 1962. Ces resultats confirment dans l'ensemble ceux precedemment obtenus tout en augmentant la variete des legumes etudies. La vigne et les prairies artificielles ont egalement fait l'objet d'etudes. La grande dispersion des valeurs limites du coefficient r (rapport entre la quantite de radioelements dans un kg de produits recoltes a la quantite de radioelements presente dans un litre d'eau d'irrigation) en rapport avec la nature des sols, le type vegetal, etc.., ne permet pas de degager de conclusions generales. Chaque cas de rejet necessite une etude particuliere dont le schema est donne. En tout etat de cause l'on doit s'attendre a ce que dans la plupart des cas ces etudes conduisent a une diminution des normes actuellement utilisees. (auteurs)

  10. Contribution to the study on the flow rate adjustment for gas cooled power reactors (1964); Contributiom a l'etude de reglage du debit pour les reacteurs industriels refroidis par gaz (1964)

    Energy Technology Data Exchange (ETDEWEB)

    Milliot, B. [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1961-06-15

    1. This original study firstly defines the problem of the adjustment of the coolant flow rate in a reactor channel as a function of the corresponding heat transfer equations and of the local and temporal neutron flux. The necessity of such an adjustment is pointed out and the modifying parameters are studied. An adjustment study using the envelope of the possible flux curves is developed. A short study on the technology and the economical advantage of this adjustment is presented. Some measurements, made on G-1 and G-2, show the precision one can obtain from adjustment apparatus itself as well as from the complete reactor adjustment system. 2. Evolution of nuclear properties of fuel in an heterogeneous thermal reactor. In the first port of this paper, the phenomena of fuel evolution have been mainly pointed out. Now a bibliographical study more qualitatively than quantitatively has been done. This survey specifies the present theories and relates to a real effective cross section and also yields to the bases of such a nuclear calculation. (author) [French] 1. Cette etude originale definit d'abord le probleme du reglage du debit de refrigerant dans un canal de reacteur en fonction de la formulation du calcul des performances thermodynamiques de ce canal et des variations du flux neutronique dans l'espace et le temps. La necessite du reglage est ensuite mise en evidence et les parametres le modifiant sont etudies. Une methode de reglage, basee sur l'emploi d 'une courbe enveloppe des courbes de flux possibles, est donnee. Une breve etude de la technologie et des incidences economiques du reglage est presentee. Des mesures effectuees sur les reacteurs G-1 et G-2 montrent la precision que l'on peut attendre des dispositifs de reglage comme du reglage d'ensemble du reacteur lui-meme. 2. Evolution des proprietes nucleaires du combustible dans un reacteur heterogene a neutrons thermiques. Les phenomenes d'evolution du combustible

  11. Processing radioactive effluents with ion-exchanging resins: study of result extrapolation; Traitement des effluents radioactifs par resines echangeuses d'ions: etude de l'extrapolation des resultats

    Energy Technology Data Exchange (ETDEWEB)

    Wormser, G.

    1960-05-03

    As a previous study showed the ion-exchanging resins could be used in Saclay for the treatment of radioactive effluents, the author reports a study which aimed at investigating to which extent thus obtained results could be extrapolated to the case of higher industrial columns. The author reports experiments which aimed at determining extrapolation modes which could be used for columns of organic resin used for radioactive effluent decontamination. He notably studied whether the Hiester and Vermeulen extrapolation law could be applied. Experiments are performed at constant percolation flow rate, at varying flow rate, and at constant flow rate [French] Plusieurs etudes ont ete faites dans le but d'examiner les possibilites d'emploi des resines echangeuses d'ions pour le traitement des effluents radioactifs. Dans un rapport preliminaire, nous avons montre dans quelles limites un tel procede pouvait etre utilise au Centre d'Etudes Nucleaires de Saclay. Les essais ont ete effectues sur des petites colonnes de resine au laboratoire; il est apparu ensuite necessaire de prevoir dans quelle mesure les resultats ainsi obtenus peuvent etre extrapoles a des colonnes industrielles, de plus grande hauteur. Les experiences dont les resultats sont exposes dans ce rapport, ont pour but de determiner les modes d'extrapolation qui pourraient etre employes pour des colonnes de resine organique utilisees pour la decontamination d'effluents radioactifs. Nous avons en particulier recherche si la loi d'extrapolation de Hiester et Vermeulen qui donne de bons resultats dans le cas de fixation d'ions radioactifs en presence d'un ion macrocomposant sur des terres, pouvait etre appliquee. Les experiences, en nombre limite, ont montre que la loi d'extrapolation de Hiester et Vermeulen pouvait s'appliquer dans le cas de l'effluent considere quand les debits de percolation sont tres faibles; quand ils sont plus forts, les volumes de liquide percoles, a fixation egale, sont proportionnels aux

  12. Niger Republic Mineral Planning : Part IV - first volume : Main mineral substances specific study and their geological context; Plan Mineral de la Republique du Niger : Tome IV - 1er volume : Etude specifique des principales substances minerals et leur contexte geologique

    Energy Technology Data Exchange (ETDEWEB)

    Franconi, Antoine; Joo' , Julien; Zibo, Idde

    1981-07-01

    This volume contains the detailed study of mineral substances industrially exploited to date : uranium, coal, non metallic building materials and public activities, and non conventionally exploited substances, that are : tin, columbite-tantalite, tungsten, gold, phosphates and evaporates. [French] Ce volume contient l'etude detaillee des substances minerals exploitees industriellement a ce jour : l'uranium, le charbon, les materiaux non metalliques de construction et de travaux publics et les substances exploitees artisanalement qui sont : l'etain, la Colombo-tantalite, le tungstene, l'or, les phosphates et les evaporates.

  13. Study and installation of concrete shielding in the civil engineering of nuclear construction (1960); Etude et mise en place des betons de protection dans le genie civil des ouvrages nucleaires (1960)

    Energy Technology Data Exchange (ETDEWEB)

    Dubois, F [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1960-07-01

    The object of this report is to give technical information about high density concretes which have become very important for radiation biological shielding. The most generally used heavy aggregates (barytes, ilmenite, ferrophosphorus, limonite, magnetite and iron punching) to make these concretes are investigated from the point of view prospecting and physical and chemical characteristics. At first, a general survey of shielding concretes is made involving the study of components, mixing and placing methods, then, a detailed investigation of some high density concretes: barytes concrete, with incorporation of iron punching or iron shot, ferrophosphorus concrete, ilmenite concrete and magnetite concrete, more particularly with regard to grading and mix proportions and testing process. To put this survey in concrete form, two practical designs are described such as they have been carried out at the Saclay Nuclear Station. Specifications are given for diverse concretes and for making the proton-synchrotron 'Saturne' shielding blocks. (author) [French] Ce rapport a pour objet de donner des precisions techniques au sujet des betons a haute densite qui ont pris une grande importance pour la protection biologique contre les rayonnements. Les agregats lourds les plus couramment utilises (barytine, ilmenite, ferrophosphore, limonite, magnetite et riblons) pour la fabrication de ces betons, sont examines du point de vue prospection et caracteristiques physiques et chimiques. On procede d'abord a une etude generale des betons de protection comprenant l'etude des constituants, de la confection et de la mise en place, ensuite, a un examen detaille de quelques betons a haute densite: betons a base de barytine, avec incorporation de riblons ou de grenaille de fonte, betons au ferrophosphore, a base d'ilmenite ou de magnetite, notamment en ce qui concerne la granulometrie, la composition, le dosage et les processus d'essais. Pour concretiser ces etudes, deux applications pratiques

  14. Study and installation of concrete shielding in the civil engineering of nuclear construction (1960); Etude et mise en place des betons de protection dans le genie civil des ouvrages nucleaires (1960)

    Energy Technology Data Exchange (ETDEWEB)

    Dubois, F. [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1960-07-01

    The object of this report is to give technical information about high density concretes which have become very important for radiation biological shielding. The most generally used heavy aggregates (barytes, ilmenite, ferrophosphorus, limonite, magnetite and iron punching) to make these concretes are investigated from the point of view prospecting and physical and chemical characteristics. At first, a general survey of shielding concretes is made involving the study of components, mixing and placing methods, then, a detailed investigation of some high density concretes: barytes concrete, with incorporation of iron punching or iron shot, ferrophosphorus concrete, ilmenite concrete and magnetite concrete, more particularly with regard to grading and mix proportions and testing process. To put this survey in concrete form, two practical designs are described such as they have been carried out at the Saclay Nuclear Station. Specifications are given for diverse concretes and for making the proton-synchrotron 'Saturne' shielding blocks. (author) [French] Ce rapport a pour objet de donner des precisions techniques au sujet des betons a haute densite qui ont pris une grande importance pour la protection biologique contre les rayonnements. Les agregats lourds les plus couramment utilises (barytine, ilmenite, ferrophosphore, limonite, magnetite et riblons) pour la fabrication de ces betons, sont examines du point de vue prospection et caracteristiques physiques et chimiques. On procede d'abord a une etude generale des betons de protection comprenant l'etude des constituants, de la confection et de la mise en place, ensuite, a un examen detaille de quelques betons a haute densite: betons a base de barytine, avec incorporation de riblons ou de grenaille de fonte, betons au ferrophosphore, a base d'ilmenite ou de magnetite, notamment en ce qui concerne la granulometrie, la composition, le dosage et les processus d'essais. Pour concretiser ces

  15. Experimental study of contamination by inhalation of radioactive iodine aerosols. Biological balance; Etude experimentale de la contamination par inhalation d'aerosols d'iode radioactif bilan biologique

    Energy Technology Data Exchange (ETDEWEB)

    Marble, G. [Commissariat a l' Energie Atomique, 92 - Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1968-07-01

    Several articles have been published concerning research into contamination produced by inhalation of radioactive iodine aerosols in monkeys. Results dealing with the biological balance of this contamination are presented and discussed in this report. (author) [French] L'etude experimentale de la contamination par inhalation d'aerosols d'iode radioactif effectuee chez le singe a fait l'objet de plusieurs publications. Les resultats concernant le bilan biologique de cette contamination sont presentes et discutes dans ce rapport. (auteur)

  16. Contribution to the study on the flow rate adjustment for gas cooled power reactors (1964); Contributiom a l'etude de reglage du debit pour les reacteurs industriels refroidis par gaz (1964)

    Energy Technology Data Exchange (ETDEWEB)

    Milliot, B [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1961-06-15

    1. This original study firstly defines the problem of the adjustment of the coolant flow rate in a reactor channel as a function of the corresponding heat transfer equations and of the local and temporal neutron flux. The necessity of such an adjustment is pointed out and the modifying parameters are studied. An adjustment study using the envelope of the possible flux curves is developed. A short study on the technology and the economical advantage of this adjustment is presented. Some measurements, made on G-1 and G-2, show the precision one can obtain from adjustment apparatus itself as well as from the complete reactor adjustment system. 2. Evolution of nuclear properties of fuel in an heterogeneous thermal reactor. In the first port of this paper, the phenomena of fuel evolution have been mainly pointed out. Now a bibliographical study more qualitatively than quantitatively has been done. This survey specifies the present theories and relates to a real effective cross section and also yields to the bases of such a nuclear calculation. (author) [French] 1. Cette etude originale definit d'abord le probleme du reglage du debit de refrigerant dans un canal de reacteur en fonction de la formulation du calcul des performances thermodynamiques de ce canal et des variations du flux neutronique dans l'espace et le temps. La necessite du reglage est ensuite mise en evidence et les parametres le modifiant sont etudies. Une methode de reglage, basee sur l'emploi d 'une courbe enveloppe des courbes de flux possibles, est donnee. Une breve etude de la technologie et des incidences economiques du reglage est presentee. Des mesures effectuees sur les reacteurs G-1 et G-2 montrent la precision que l'on peut attendre des dispositifs de reglage comme du reglage d'ensemble du reacteur lui-meme. 2. Evolution des proprietes nucleaires du combustible dans un reacteur heterogene a neutrons thermiques. Les phenomenes d'evolution du combustible tiennent une place importante dans l'etude

  17. Initiation of detonation by impact on granular explosives; Contribution a l'etude de la generation de la detonation provoquee par impact sur un explosif

    Energy Technology Data Exchange (ETDEWEB)

    Bernier, H [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-05-15

    A good number of experiments have shown up the particular behaviour of granular explosives when they are detonated by barrier transmitted shocks. Similar results can be obtained when the shock is induced by impact. In this case the pressure signal shape applied at the explosive is better known and both its intensity and duration can be varied. By using a mathematical model in which the law of chemical kinetics is a linear function of pressure, and different temperatures are used for solids and gases, it is possible to describe most of the behaviour of detonation initiation in solid granular explosives. (author) [French] De nombreuses etudes experimentales ont montre le comportement particulier des explosifs granulaires lors de la detonation provoquee par choc transmis a travers une barriere. Les memes resultats peuvent etre obtenus lorsque la detonation est engendree par impact. Dans ce cas, la forme du signal de pression induit dans l'explosif est mieux connue, et il est possible d'en faire varier l'intensite et la duree d'application. Un modele mathematique utilisant une loi de cinetique chimique fonction lineaire de la pression et ou les temperatures des etats solide et gazeux pendant la reaction sont differenciees, permet de retrouver la plupart des caracteres specifiques de la generation dans un explosif solide granulaire. (auteur)

  18. Etude de trois souches d'Arthrobotrys oligospora : Caractérisation biologique et effets sur Meloidogyne mayaguensis parasite de la tomate au Sénégal

    Directory of Open Access Journals (Sweden)

    Gueyei, M.

    1997-01-01

    Full Text Available Etude de trois souches d'Arthrobotrys oligospora : Caractérisation biologique et effets sur Meloidogyne mayaguensis parasite de la tomate au Sénégal. Three strains (ORS 18690 S2, ORS 18691 S6 and ORS 18693 S5 of the nematophagous fungus Arthrobotrys oligospora have been isolated in Senegal for the first time. In vitro, two strains (ORS 18690 S2 and ORS 18693 S5 of them trapped 100 % and the other (ORS 18691 S5 80 %> of 7-day-old juvenile Meloidogyne mayaguensis within 48h. Optimal growth occured at 25-30°C and at a pH 5.6, but salinity inhibited development. In order to test the ability of fungi to control M. mayaguensis in pots on tomato, the fungus was incorporated into compost blocks or in vermiculite before sowing or subsequent transplanting. In pot experiments both strains reduced nematode populations ans stimulated seedling growth. However, these effects were higher in compost blocks than in vermiculite.

  19. Contribution to the study of neutron propagation in cavities; Contribution a l'etude de la propagation des neutrons dans les cavites

    Energy Technology Data Exchange (ETDEWEB)

    Hasselin, G [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1965-07-01

    In large size cavities where the dimensions of the holes are greater than the mean free path of the radiations, the neutron propagation calculations are carried out by taking into account the effect of the medium surrounding the hole using a reflection coefficient or albedo. In this work the fast neutron albedos are obtained for various materials and these results are applied for a Monte-Carlo propagation calculation. A comparison of this calculation with experimental results shows the validity of the method. (author) [French] Dans les cavites de grandes dimensions, ou les dimensions des vides sont superieures au libre parcours moyen des rayonnements, le calcul de la propagation des neutrons se fait en essayant de rendre compte de l'effet du milieu entourant le vide, par un coefficient de reflexion ou albedo. Dans cette etude, sont d'une part obtenus des albedo en neutrons rapides sur divers materiaux, d'autre part ces resultats sont appliques pour un calcul de MONTE-CARLO de propagation. La comparaison entre le calcul et l'experience montre la validite de la methode. (auteur)

  20. Application of mathematical methods to the investigation of uranium deposits; Application des methodes mathematiques a l'etude des gisements d'uranium

    Energy Technology Data Exchange (ETDEWEB)

    Formery, P; Ziegler, V [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1958-07-01

    It may be considered approximately that grades, widths and accumulations (grade-width products), in french uranium deposits are distributed according to a lognormal law. This property associated to KRIGE'S and de WIGE'S formulae make a powerful tool in ore deposits surveys. The correlation between radioactivities and grades is realized, in logarithmic coordinates, through a straight line the properties of which are analysed in the paper. MATHERON'S recent works, in association with data of classical statistics and the above mentioned formulae make possible to complete the ore reserves evaluation by computing the accuracy. Statistical methods applied to ore deposits have given birth to a parameter which is as important as the mean grade for characterisation of deposits: the absolute dispersion. (author) [French] On peut considerer en premiere approximation que les teneurs, les puissances et les accumulations se distribuent dans les gisements fran is d'uranium suivant une loi log normale. Cette propriete, associee aux hypotheses de De WIGE et de KRIGE, constitue un puissant instrument d'etude des gisements. La correspondance des radioactivites et des teneurs s'effectue, en coordonnees bilogarithmiques, par une droite dont on etudie les proprietes. Grace aux travaux recents de MATHERON, associes aux donnees de la statistique classique ainsi qu'aux hypotheses enumerees plus haut, il est possible de completer le calcul des reserves d'un gisement par une evaluation de l'erreur commise. Les methodes statistiques ont fait apparaitre un parametre aussi important pour caracteriser un gisement, que la teneur moyenne: la dispersion absolue. (auteur)

  1. Studies on solid-state physics carried out with the Saclay reactor (1962); Etudes de physique du solide realisees a la pile de Saclay (1962)

    Energy Technology Data Exchange (ETDEWEB)

    Herpin, A [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1962-07-01

    This paper deals only with solid-state physics experiments carried out on outgoing beams: rather than giving a general review of the work performed, if refers to only a few of the most important studies or those nearest completion. These are being made with the experimental beams of the two Saclay reactors EL-2, with a central flux of 10{sup 13} n/cm{sup 2}, and - since 1958 - EL-3, whose central flux is equal ta 10{sup 14} n/cm{sup 2}. The experiments are being carried out by two separate groups of physicists, employing different techniques, namely neutron diffraction using a crystal spectrometer, and inelastic scattering using a time-of-flight spectrometer. (author) [French] Cet expose ne relate que des experiences de physique du solide faites sur des faisceaux sortis; plutot que de donner une revue de l'ensemble des travaux effectues, on ne cite que quelques etudes que l'on peut considerer comme plus essentielles ou mieux achevees. On utilise les faisceaux experimentaux des deux piles de Saclay, EL-2 dont le flux au centre est de 10{sup 13}n/cm{sup 2} et, depuis 1958, EL-3 pour laquelle il est egal a 10{sup 14} n/cm{sup 2}. Les experiences sont realisees par deux groupes de physiciens distincts, employant des techniques differentes, la diffraction des neutrons qui utilise un spectrometre a cristal, et la diffusion inelastique avec un spectrometre a temps de vol. (auteur)

  2. Study of the acceptance of a constant gradient synchrotron (1960); Etude de l'acceptance d'un synchrotron a gradient constant (1960)

    Energy Technology Data Exchange (ETDEWEB)

    Bronca, G; Gendreau, G [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1960-07-01

    This paper is a synthesis of the work of H. Bell and E. Persico; a detailed analysis is given of the phenomena which occurs at the time of injection (collision against the back of the inflector, overshooting of the 'useful zone'; collision against the horizontal walls of the chamber) and of capture (assumed to be fast) in a faultless machine. The maximum number of particles which may be injected and captured is determined as a function of various parameters: emittance of the beam injected, radial position of the inflector, synchronous phase or peak HF voltage. A final limitation due to the transverse space charge is then recalled, and lastly conclusions are drawn from the results with particular reference to Saturn. (author) [French] Cette etude est une synthese du travail de H. BELL et E. PERSICO; on analyse en detail les phenomenes a l'injection (choc contre le dos inflecteur, depassement de 'zone utile', choc contre les parois horizontales de la chambre) et a la capture (supposee rapide) pour une machine sans defaut. On determine le nombre maximum de particules injectables et capturables en fonction de divers parametres: emittance du faisceau injecte, position radiale de l'inflecteur, phase synchrone ou tension crete HF. Puis, on rappelle une derniere limitation due a la charge d'espace transversale et enfin les conclusions qu'on tire des resultats en ce qui concerne plus particulierement Saturne. (auteur)

  3. Etudes optiques de nouveaux materiaux laser: Des orthosilicates dopes a l'ytterbium: Le yttrium (lutetium,scandium) pentoxide de silicium

    Science.gov (United States)

    Denoyer, Aurelie

    La decouverte et l'elaboration de nouveaux materiaux laser solides suscitent beaucoup d'interet parmi la communaute scientifique. En particulier les lasers dans la gamme de frequence du micron debouchent sur beaucoup d'applications, en telecommunication, en medecine, dans le domaine militaire, pour la, decoupe des metaux (lasers de puissance), en optique non lineaire (doublage de frequence, bistabilite optique). Le plus couramment utilise actuellement est le Nd:YAG dans cette famille de laser, mais des remplacants plus performants sont toujours recherches. Les lasers a base d'Yb3+ possedent beaucoup d'avantages compares aux lasers Nd3+ du fait de leur structure electronique simple et de leur deterioration moins rapide. Parmi les matrices cristallines pouvant accueillir l'ytterbium, les orthosilicates Yb:Y 2SiO5, Yb:Lu2SiO5 et Yb:Sc2SiO 5 se positionnent tres bien, du fait de leur bonne conductivite thermique et du fort eclatement de leur champ cristallin necessaire a l'elaboration de lasers quasi-3 niveaux. De plus l'etude fine et systematique des proprietes microscopiques de nouveaux materiaux s'avere toujours tres interessante du point de vue de la recherche fondamentale, c'est ainsi que de nouveaux modeles sont concus (par exemple pour le champ cristallin) ou que de nouvelles proprietes inhabituelles sont decouvertes, menant a de nouvelles applications. Ainsi d'autres materiaux dopes a l'ytterbium sont connus pour leurs proprietes de couplage electron-phonon, de couplage magnetique, d'emission cooperative ou encore de bistabilite optique, mais ces proprietes n'ont encore jamais ete mises en evidence dans Yb:Y 2SiO5, Yb:Lu2SiO5 et Yb:Sc2SiO 5. Ainsi, cette these a pour but l'etude des proprietes optiques et des interactions microscopiques dans Yb:Y2SiO 5, Yb:Lu2SiO5 et Yb:Sc2SiO5. Nous utilisons principalement les techniques d'absorption IR et de spectroscopie Raman pour determiner les excitations du champ cristallin et les modes de vibration dans le materiau

  4. Neutron Activation for Studying Hydroelectrolytic Disorders in Child Pathology; Application de l'Activation Neutronique a l'Etude des Troubles Hydroelectrolytiques en Pathologie Infantile

    Energy Technology Data Exchange (ETDEWEB)

    Dubois, J. [Hopital Universitaire St-Pierre, Bruxelles (Belgium); Colard, J. [Centre d' Etude de l' Energie Nucleaire, Mol (Belgium); Vis, H. L. [Institut pour la Recherche Scientifique en Afrique Centrale, Bukavu (Congo, The Democratic Republic of the)

    1967-10-15

    The authors describe a method of determining electrolytes (Na, K, CI) and phosphorus in small fragments of muscle taken from child patients by needle biopsy. This method has been used to study muscular disturbances in hydroelectrolytic illnesses of childhood, whether acute, such as dehydration or toxicosis in infants, or chronic, such as malnutrition or marasmus. The results are discussed in the light of parallel data obtained by other methods of investigation. The authors also discuss the possibility of using this method to estimate intra-cellular hydroelectrolytic disorders in child pathology. (author) [French] Les auteurs presentent la description d'une methode permettant le dosage des electrolytes (Na, K, Cl) et du phosphore sur de petits fragments musculaires preleves par ponction-biopsie chez l'enfant. Cette methode a ete appliquee a l'etude des perturbations du milieu musculaire dans des troubles hydroelectrolytiques aigus (deshydratation et toxicose des nourrissons) et chroniques (malnutrition et denutrition) de l'enfance. Les resultats obtenus sont discutes a la lumiere de donnees recueillies parallelement par d'autres methodes d'investigation. Les auteurs discutent egalement la possibilite d'estimer par cette methode les perturbations hydroelectrolytiques intra-cellulaires en pathologie pediatrique. (author)

  5. Physical activity patterns in the French 18-74-year-old population: French Nutrition and Health Survey (Etude Nationale Nutrition Santé, ENNS) 2006-2007.

    Science.gov (United States)

    Salanave, Benoit; Vernay, Michel; Szego, Emmanuelle; Malon, Aurélie; Deschamps, Valérie; Hercberg, Serge; Castetbon, Katia

    2012-11-01

    To describe detailed physical activity and sedentary behaviour in French adults across physical activity categories. The French Nutrition and Health Survey (Etude Nationale Nutrition Santé, ENNS), conducted in 2006-2007, was a national cross-sectional survey based on three-stage random sampling. The International Physical Activity Questionnaire (IPAQ) was used to classify participants into three physical activity categories. Time spent in a sitting position and time spent in front of a screen were used as markers of sedentary behaviour. France. Adults (n 2971) aged 18 to 74 years were included. Overall, 29·5 % of men and 23·6 % of women were classified into the high-IPAQ category, while 36·1 % of men and 37·5 % of women were in the low-IPAQ category. For each intensity level of physical activity (vigorous intensity, moderate intensity or walking), the number of active days per week decreased from the high- to the low-IPAQ category and daily duration of physical activity was longer in the high-IPAQ category than in the other two categories; 6 % of adults declared neither vigorous nor moderate nor walking activities. For most adults in the low-IPAQ category, an increasing number of active days per week would be sufficient to attain the moderate-IPAQ category. This should be taken into account in public health initiatives aimed at promoting physical activity.

  6. Smoking Trajectories during the Perinatal Period and Their Risk Factors: The Nationally Representative French ELFE (Etude Longitudinale Française Depuis l'Enfance) Birth Cohort Study.

    Science.gov (United States)

    El-Khoury, Fabienne; Sutter-Dallay, Anne-Laure; Van Der Waerden, Judith; Surkan, Pamela; Martins, Silvia; Keyes, Katherine; de Lauzon-Guillain, Blandine; Charles, Marie-Aline; Melchior, Maria

    2017-01-01

    In France, rates of perinatal smoking are among the highest worldwide; however, perinatal smoking trajectories and associated factors have still not been adequately researched. Among women participating in the French nationally representative etude longitudinale française depuis l'enfance birth cohort (n = 15,540), perinatal smoking trajectories were estimated using group-based modelling. Associated characteristics were studied using multinomial logistic regression. Four trajectories were identified: non-smokers (59%), quitters (20%), persistent moderate (12%) and persistent heavy (9%) smokers. Older age, being native French, low socioeconomic position, persistent psychological difficulties and alcohol use in pregnancy, lack of social support, partner's smoking, mistimed pregnancy, and child formula feeding at birth were associated with persistent heavy smoking. Most of these factors were also associated, but to a lesser extent, with persistent moderate smoking, except for age and migrant status, which had opposite effects. Women who successfully lost weight prior to pregnancy had higher levels of quitting smoking. Women's long-term smoking trajectories vary in terms of initial tobacco consumption level but also in relation to socio-demographic, psychological, behavioral and partner characteristics. Health professionals in contact with pregnant smokers should address perceived risks and benefits of smoking, including partner's smoking and weight-gain concerns. © 2017 S. Karger AG, Basel.

  7. A microcosm of musical expression. I. Quantitative analysis of pianists' timing in the initial measures of Chopin's Etude in E major.

    Science.gov (United States)

    Repp, B H

    1998-08-01

    Patterns of expressive timing were measured in bars 1-5 of 115 commercially recorded performances of Chopin's Etude in E major, op. 10, No. 3. These patterns were subjected to principal components analysis, which suggested at least four independent "timing strategies": (1) major ritards at the ends of melodic gestures; (2) acceleration within some of these gestures, without final ritards; (3) extreme lengthening of the initial downbeat; and (4) ritards between as well as within melodic gestures. Strategies 1 and 4 respond in different ways to the melodic-rhythmic grouping structure of the music, and strategy 3 merely represents a local emphasis. Strategy 2 is the one most difficult to rationalize; it does not seem to represent an alternative structural interpretation of the music but rather an alternative gestural shaping. Each individual pianist's timing pattern could be described as a weighted combination of these four strategies plus idiosyncratic variation. A wide variety of combinations was represented, and no two individual patterns were exactly the same. In addition, there was a wide range of basic tempi and of degrees of tempo modulation. There were no strong relationships between any of these variables and sociocultural characteristics of the artists, although some weak trends were observed.

  8. A microcosm of musical expression. III. Contributions of timing and dynamics to the aesthetic impression of pianists' performances of the initial measures of Chopin's Etude in E major.

    Science.gov (United States)

    Repp, B H

    1999-07-01

    Four judges repeatedly assessed the overall aesthetic quality of more than 100 recorded performances of the opening of Chopin's Etude in E major on a 10-point scale. The judgments, which exhibited reasonable reliability and modest intercorrelations, were entered into regression analyses with 16 independent variables derived from earlier objective analyses of the expressive timing and dynamics of the performances [Repp, J. Acoust. Soc. Am. 104, 1085-1100 (1998); 105, 1972-1988 (1999)]. Only between 9% and 18% of the variance in the judges' ratings was accounted for. By contrast, timing variables accounted for 53% of the variance in one judge's ratings of synthesized performances that varied in timing only and mimicked the timing patterns of the original performances. These results indicate, first, that the aesthetic impression of the original recordings rested primarily on aspects other than those measured (such as texture, tone, or aspects of timing and dynamics that eluded the earlier analyses) and, second, that very different patterns of timing and dynamics are aesthetically acceptable for the same music, provided that other, aesthetically more crucial performance aspects are present.

  9. A microcosm of musical expression: II. Quantitative analysis of pianists' dynamics in the initial measures of Chopin's Etude in E major.

    Science.gov (United States)

    Repp, B H

    1999-03-01

    Patterns of expressive dynamics were measured in bars 1-5 of 115 commercially recorded performances of Chopin's Etude in E major, op. 10, No. 3. The grand average pattern (or dynamic profile) was representative of many performances and highly similar to the average dynamic profile of a group of advanced student performances, which suggests a widely shared central norm of expressive dynamics. The individual dynamic profiles were subjected to principal components analysis, which yielded Varimax-rotated components, each representing a different, nonstandard dynamic profile associated with a small subset of performances. Most performances had dynamic patterns resembling a mixture of several components, and no clustering of of performances into distinct groups was apparent. Some weak relationships of dynamic profiles with sociocultural variables were found, most notably a tendency of female pianists to exhibit a greater dynamic range in the melody. Within the melody, there were no significant relationships between expressive timing [Repp, J. Acoust. Soc. Am. 104, 1085-1100 (1998)] and expressive dynamics. These two important dimensions seemed to be controlled independently at this local level and thus offer the artist many degrees of freedom in giving a melody expressive shape.

  10. Contribution to the study of neutron propagation in cavities; Contribution a l'etude de la propagation des neutrons dans les cavites

    Energy Technology Data Exchange (ETDEWEB)

    Hasselin, G. [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1965-07-01

    In large size cavities where the dimensions of the holes are greater than the mean free path of the radiations, the neutron propagation calculations are carried out by taking into account the effect of the medium surrounding the hole using a reflection coefficient or albedo. In this work the fast neutron albedos are obtained for various materials and these results are applied for a Monte-Carlo propagation calculation. A comparison of this calculation with experimental results shows the validity of the method. (author) [French] Dans les cavites de grandes dimensions, ou les dimensions des vides sont superieures au libre parcours moyen des rayonnements, le calcul de la propagation des neutrons se fait en essayant de rendre compte de l'effet du milieu entourant le vide, par un coefficient de reflexion ou albedo. Dans cette etude, sont d'une part obtenus des albedo en neutrons rapides sur divers materiaux, d'autre part ces resultats sont appliques pour un calcul de MONTE-CARLO de propagation. La comparaison entre le calcul et l'experience montre la validite de la methode. (auteur)

  11. Collection and processing of information in biological kinetics studies with radioactive tracers; Collecte et traitement de l'information dans les etudes de cinetique biologique avec traceurs radioactifs

    Energy Technology Data Exchange (ETDEWEB)

    Remy, J; Lafuma, J [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1968-07-01

    The authors present an automatic method for the collection and treatment of information in biological kinetics experiments using radioactive tracers. The recording are made without any time constant on magnetic tape. The information recorded is sampled by a 400 channel multi-scale analyzer and transferred to punched cards. The digital analysis is done by an I.B.M. computer. The method is illustrated by an example: the hepatic fixation of colloidal gold in the pig. Its advantages and requirements are discussed. In the appendix are given the FORTRAN texts for two programmes used in treating the example presented. (authors) [French] Les auteurs presentent une methode automatique de collecte et de traitement de l'information dans les experiences de cinetique biologique utilisant les traceurs radioactifs. Les enregistrements sont realises sans constante de temps sur bande magnetique. L'information enregistree fait l'objet d'un echantillonnage a l'aide d'un analyseur a 400 canaux en mode multi-echelle puis est transferee sur cartes perforees. L'exploitation digitale est confiee a un ordinateur I.B.M.. La methode est illustree par un exemple d'etude de la fixation hepatique de l'or colloidal chez le porc. Ses avantages et ses exigences sont discutes. En annexe figurent les textes en FORTRAN de deux programmes utilises pour le traitement de l'exemple cite. (auteurs)

  12. Design and construction of a faraday cup for measuring small electron currents; Etudes et realisation d'une ''coupe de faraday'' pour les mesures de faibles courants electroniques

    Energy Technology Data Exchange (ETDEWEB)

    Veyssiere, A [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1967-07-01

    This paper describes the design of a device for measuring and integrating very small currents generated by the impact of a charged particle beam upon a Faraday cup. Part one considers the detector as such. The main component is a graphite bloc capable of stopping practically all the incident charges. Part two describes the associated electrode apparatus required to measure better than 10{sup -13} ampere with a precision- of 1 per cent: Integration of such weak currents over periods of several hours, in the presence of a strong background current, is also discussed. (author) [French] Ce rapport decrit l'etude et la realisation d'un ensemble permettant de mesurer et d'integrer sur des periodes de plusieurs heures des courants electroniques tres faibles provenant d'un faisceau de particules chargees, Dans la premiere partie du rapport nous etudierons le capteur proprement dit qui se compose essentiellement d'un bloc de graphite dont la forme et les dimensions sont telles, que la majeure partie des charges (positons et negatons de 60 MeV) est captee (1 pour mille reussissent a s'echapper). Dans la deuxieme partie nous decrivons l'appareillage associe au capteur capable de mesurer moins de 10{sup -13} ampere avec une precision de l'ordre du pour cent et d'integrer ce courant sur des periodes de temps variables, compte tenu de l'ambiance 'bruyante' (Accelerateur Lineaire) dans laquelle la mesure s'effectue. (auteur)

  13. Study of the improvement of the radioprotective power of imidazole; Etude de l'amelioration du pouvoir radioprotecteur de l'imidazole

    Energy Technology Data Exchange (ETDEWEB)

    Mourret, A; Rinaldi, R [Commissariat a l' Energie Atomique, 38 - Grenoble (France). Centre d' Etudes Nucleaires

    1968-07-01

    In studies made on the Imidazole radioprotective power, the authors have attempted to neutralize its convulsive properties by the Depamide so as to decrease drug toxicity. Then, having studied in what manner the two products simultaneous action could carry one increase of radioprotective activity, they have established that if the Depamide permits to decrease very much the Imidazole toxicity, the variation of radioprotection power which is subject to animal sex, generally increases for females and decreases for males. (authors) [French] Dans le cadre de l'etude du pouvoir radioprotecteur de l'Imidazole, les auteurs ont essaye de neutraliser les proprietes convulsivantes de cette substance par le Depamide afin d'en dimunuer la toxicite. Ayant ensuite etudie dans quelle mesure l'action simultanee de ces deux produits pouvait apporter une amelioration de l'activite radioprotectrice, ils ont constate que si le Depamide permet de diminuer tres sensiblement la toxicite de l'Imidazole, la variation du pouvoir radioprotecteur, qui depend du sexe de l'animal, augmente en general pour les femelles et diminue pour les males. (auteurs)

  14. Study of immiscibilities in the trilaurylamine - dodecane - nitric acid - plutonium system; Etude des immiscibilites dans le systeme trilaurylamine - dodecane - acide nitrique - plutonium

    Energy Technology Data Exchange (ETDEWEB)

    Saey, J C [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1968-07-01

    Phase equilibrium in systems made up of trilaurylamine, dodecane, nitric acid tetravalent plutonium is shown by drawing the triangular diagrams. the study of these diagrams provides informations concerning the causes of immiscibility. Heterogeneity of the organic mixtures can be related to some characteristics of the components- dipole moment, molecular polarizability and hydrogen bond exchanging ability-Depending on these, some rules may be established which can be used to make a proper choice of an additive in order to improve the miscibility. As an application a study on the partial substitution of dodecane with decalin, in plutonium extraction experiments, has been done showing a possible improvement of the extraction process. (author) [French] L equilibre des phases dans les systemes formes a partir de trilaurylamine, de dodecane, d'acide nitrique et de plutonium tetravalent est represente en tracant les diagrammes triangulaires. L'examen de ces diagrammes permet d'apporter certaines precisions en ce qui concerne l'origine des immiscibilites. Celles ci sont ensuite reliees a certaines caracteristiques des constituants: le moment dipolaire, la polarisabilite moleculaire et la tendance a former des liaisons hydrogene. Sur les memes bases, il est possible d'etablir un certain nombre de regles pouvant servir a guider le choix d'un additif ameliorant la miscibilite. En application, une etude sur le remplacement partiel du dodecane par la decaline montre l'interet de l'emploi de ce compose dans le procede de purification du plutonium. (auteur)

  15. Study of the molecular structure of uranium hexafluoride; Contribution a l'etude de la structure moleculaire de l'hexafluorure d'uranium

    Energy Technology Data Exchange (ETDEWEB)

    Bougon, R [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1967-06-01

    The vibrational spectrum of uranium hexafluoride has been studied in both the gaseous and solid states. The study of gaseous UF{sub 6} confirms the regular octahedral structure of the fluorine atoms around the central U atom and makes it possible to evaluate some of the vibrational frequencies. From these, some new force constants have been determined. A tetragonal distortion is observed on solid UF{sub 6}; this distortion has only observed up till now by means of X-ray diffraction and nuclear magnetic resonance techniques. (author) [French] Le spectre de vibration de l'hexafluorure d'uranium UF{sub 6} est etudie sous les formes gazeuse et solide. L'etude de l'UF{sub 6} gaz confirme la structure d'octaedre regulier d'atomes de fluor autour de l'atome central d'uranium et apporte une precision sur certaines frequences de vibration. A partir de ces valeurs, de nouvelles determinations de constantes de force ont ete realisees. L'observation de UF{sub 6} solide confirme la deformation tetragonale de l'octaedre, deformation observee jusqu'a present par les seules methodes de resonance magnetique nucleaire et diffraction des rayons X. (auteur)

  16. Electron microscope study of irradiated beryllium oxide; Etude au microscope electronique de l'oxyde de beryllium irradie

    Energy Technology Data Exchange (ETDEWEB)

    Bisson, A A [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1965-06-01

    utilisant des echantillons frittes. Les fractures sont examinees sous differents aspects. Ce sont les frittes les plus denses a fractures intragranulaires qui sont les plus interessants pour l'etude microscopique. Le 'pore' resultant du frittage est differencie de la 'bulle' qui peut se former au cours de traitements thermiques ulterieurs par suite de reactions donnant naissance a des gaz. Apres irradiation, la fragilisation intergranulaire est importante. Par recuit, on suit l'evolution des gaz, produits par les reactions (n. 2n) et (n, {alpha}), qui s'accumulent aux joints de grains. L oxyde de beryllium irradie est ensuite etudie par transmission. Pour cela, une methode simple a ete mise au point; elle consiste a examiner les eclats de cristaux broyes. Les amas de defauts ponctuels, formes par les neutrons, sont ainsi mis en evidence dans les cristaux irradies aux trois doses suivantes: 6.10{sup 19}, 9.10{sup 19} et 2.10{sup 20} n{sub r}.cm{sup -2} a une temperature inferieure a 100 deg. C. Pour l'irradiation a 6.10{sup 19} n{sub r}.cm{sup -2} les defauts sont a peine visibles mais a 2.10{sup 20} n{sub r}.cm{sup -2} les cristaux sont cribles d'amas alors que les lignes de Kikuchi ont disparu des diagrammes de microdiffraction. L'evolution des amas de defauts en boucles de dislocation est etudiee par des recuits successifs. L'energie d'activation de 0.37 eV, calculee a partir des courbes de recuits, incite a penser que ce sont les defauts interstitiels qui se condensent en boucles de dislocation. Des echantillons irradies a haute temperature sont egalement etudies (650, 900 et 1100 deg. C). Dans ceux-ci les boucles de dislocation atteignent un etat d'equilibre different de celui des precedentes. Ces dernieres boucles de dislocation sont etudiees plus specialement et leur vecteur de Burgers est determine par microdiffraction. (auteur)

  17. Study of U - Pu - Fe alloys (Masurca critical experiment); Etudes d'alliages U-Pu-Fe (experience critique MASURCA)

    Energy Technology Data Exchange (ETDEWEB)

    Barthelemy, P; Boucher, R [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1965-07-01

    pour ces deux dernieres teneurs le passage du point de transformation (595 et 590 deg. C respectivement) entraine une deterioration rapide et complete des echantillons sous air. Les essais d'inflammabilite sous air montrent que la temperature de debut d'oxydation se situe vers 250 deg. C et que la reaction ne s'entretient pas d'elle-meme. On n'a pas observe d'inflammation proprement dite lors d'une montee jusqu'a 660 deg. C. L'etude dilatometrique a permis de determiner la temperature de transformation a l'etat solide, la temperature de fusion commencante et les coefficients de dilatation. En dessous de la transformation les alliages sont formes principalement des phases U-Pu zeta et (U, Pu){sub 6}Fe. La conductibilite thermique, le module d'Young, la densite et la chaleur de fusion ont ete mesures. les essais de compatibilite U-Pu-Fe{approx}acier inox NS 22 S montrent qu'au contact des deux alliages se forme une phase du type (U,Pu){sub 6}Fe. L'alliage a 1% de fer parait preferable, la phase (U,Pu){sub 6}Fe formee a l'interface etant 2 a 3 fois moins etendue qu'avec l'alliage a 1,5% de fer. Enfin le probleme de la stabilite thermique a temperature peu elevee a ete considere pour l'alliage a 1% de fer. Le passage du point de transformation a 595 deg. C entraine l'apparition d'une anomalie dilatometrique, au refroidissement, se traduisant par une tres faible dilatation dont l'amplitude diminue en fonction du nombre de cycles effectues entre 20 et 650 deg. C sur l'alliage brut de coulee a l'origine. Par contre, des cyclages thermiques entre 50 et 400 deg. C montrent que les alliages ne presentent pas d'anomalie et sont stables. De meme, des maintiens de 5 mois a 100 deg. C, 200 deg. C, 300 deg. C, sous vide, n'entrainent aucune alteration des alliages. (auteurs)

  18. The Combined Use of Autoradiographic and Electron Microscopic Techniques for Studies on Ultra-Thin Sections of Tritium-Labelled Cells of the Intestinal Epithelium; Emploi Combine de l'Autoradiographie et du Microscope Electronique pour L'Etude de Coupes Ultra-Fines de Cellules Tritiees de l'Epithelium Intestinal; 0421 043e 0432 043c 0435 0414 ; Empleo Combinado de Tecnicas de Autorradiografia y de MicroscopiA Electronica para Estudiar Cortes Ultrafinos de Celulas Tritiadas del Epitelio Intestinal

    Energy Technology Data Exchange (ETDEWEB)

    Hampton, J. C. [Division of Experimental Biology, Baylor University College of Medicine, TX (United States); Quastler, H. [Brookhaven National Laboratory, Upton, Long Island, NY (United States)

    1962-02-15

    The high resolution now obtainable in sectioned cells studied in the electron microscope offers some promise of visualizing some of the intracellular events leading to the synthesis of proteins. The specificity of incorporation of tritiated thymidine into DNA provides a system which can be accurately followed with respect to time and localization within the cell. The work to be reported here demonstrates that it is possible to study ultra-thin sections of labelled cells in the electron microscope, to remove the specimen after suitable electron micrographs have been taken, to apply a coating of emulsion sufficiently thick to obtain an autoradiograph but still thin enough' to permit re-examination of the specimen in the electron microscope and to obtain electron micrographic images of autoradiography of cells previously recorded. The autoradiographic emulsion was applied as follows: a thin film was formed by dipping a small wire loop into liquid emulsion and transferring the film by passing the loop over the mounted specimen which was fixed to the top of a small plastic peg. Adequate control can be achieved by taking a one-half micron section after each ultra-thin section during sectioning, mounting it on a glass slide and applying conventional autoradiographic techniques. Because of the fragile nature of ultra-thin sections, the yield of successful autoradiographs is quite low. In spite of this objection it is expected that with improvements in skill and techniques the method will facilitate a better understanding of vital cell processes. (author) [French] Le haut degre de resolution que l'on peut maintenant obtenir dans l'etude des coupes de cellules au microscope electronique offre quelque possiblite d'observer certains des processus intracellulaires qui menent a la synthese des proteines. Le fait que la thymidine tritiee s'incorpore a l'ADN de facon specifique permet de suivre avec precision le deroulement d'un autre processus dans le temps et leur localisation

  19. Genetic cytological and biochemical study of a tomato chlorophyll mutant of the xanthic type, obtained by irradiation of the seeds; Etude genetique, cytologique et biochimique d'un mutant chlorophyllien de tomate du type xantha, obtenu par irradiation de graines

    Energy Technology Data Exchange (ETDEWEB)

    Lefort, M; Duranton, J; Galmiche, J M; Roux, E [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1958-07-01

    Irradiation of Lycopersicum aesculantum seeds with increasing doses of X-rays and thermal neutrons leads to the appearance of chlorophyll mutations in the descendants of the irradiated seeds. A genetic study of one of these mutants of the xanthic type showed that it was a recessive mutant with typical mono-genetic separation, while the cytological study demonstrated that the differentiation of the plast stopped at the stage of elementary lamella. Finally it is shown that in the light, the mutation brings about a very large deviation of the carbon metabolism towards the synthesis of amino acids and proteins, at the expense of that of glucosides. (author) [French] L'irradiation de graines de Lycopersicum Aesculantum avec des doses croissantes de rayons X et de neutrons thermiques entraine l'apparition de mutations chlorophylliennes dans la descendance des graines irradiees. L'etude genetique d'un de ces mutants du type xantha a montre qu'il s'agissait d'un mutant recessif a disjonction monogenique typique, tandis que l'etude cytologique a revele que la differentiation du plaste s'arretait au stade de lamelles elementaires. Il est apparu enfin qu'a la lumiere la mutation entrainait une deviation tres importante du metabolisme du carbone vers la synthese des acides amines et des proteines, au detriment de celle des glucides. (auteur)

  20. Syntheses and study of pyrrolidinic nitroxide free radicals. Preparation of a nitroxide-type stable bi-radical; Synthese et etudes de radicaux libres nitroxydes pyrrolidiniques. Preparation d'un biradical stable du type nitroxyde

    Energy Technology Data Exchange (ETDEWEB)

    Dupeyre, R M [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires, Laboratoire de chimie organique physique

    1967-12-01

    Syntheses and study of pyrrolidinic nitroxide free radicals: These radicals are obtained by oxidation, with hydrogen peroxide, of pyrrolidinic amines prepared from triacetonamine by ring contraction. The U. V,, I. R, and E.P.R. spectral characteristics have been determined. The oxidation of these amines with hydrogen peroxide has led also to rupture of the pentagonal ring; some of the decomposition products have been identified. The high chemical stability of the nitroxide group has made it possible to synthesize and study a stable bi-radical. (author) [French] Syntheses et etudes de radicaux libres nitroxydes pyrrolidiniques: Ces radicaux sont obtenus par oxydation l'eau oxygenee d'amines pyrrolidiniques preparees a partir de la triacetonamine par contraction de cycle. Les caracteristiques spectroscopiques ultra-violettes, infra-rouge et resonance paramagnetique sont determinees. Cependant, 1'oxydation de ces amines a l'eau oxygenee a entraine la coupure du cycle pentagonal et identification de certaines substances de decomposition obtenues. La grande stabilite chimique de groupement nitroxyde a permis la synthese et l'etude d'un biradical stable. (auteur)

  1. Contribution to the study of recoil species produced by potassium ferrocyanide neutron irradiation; Contribution a l'etude de la reactivite des especes de recul dans le ferrocyanure de potassium irradie aux neutrons thermiques

    Energy Technology Data Exchange (ETDEWEB)

    Meriadec Vernier de Byans, B. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1969-04-01

    The chemical species produced by potassium ferrocyanide neutron irradiation were separated and identified. The study of their behaviour upon thermal annealing has allowed to establish a scheme of reaction as well as a kinetic treatment of the data. Activation energies are determined in different conditions and the effects of radiation dose, oxygen and water of crystallisation upon the activation energies were studied. Preliminary E.S.R. data and its relevance to the decomposition process is also discussed. (authors) [French] On a separe et identifie les differentes especes chimiques produites par irradiation neutronique de ferrocyanure de potassium. L'etude de leur comportement au cours du recuit thermique a permis l'application de differentes cinetiques et l'etablissement d'un schema de reaction. On a deterrmine la valeur des energies d'activation dans differentes conditions de recuit ainsi que l'influence de la dose de radiations, de l'oxygene et de l'eau de cristallisation sur ces energies. Une serie de mesures de resonance paramagnetique electronique a complete cette etude. (auteurs)

  2. Development of an analogue multiplexed regulation for periodic 1. order delayed processes; Etude et realisation d'une regulation analogique multiplexee pour processus aperiodiques du 1. ordre avec retard pur

    Energy Technology Data Exchange (ETDEWEB)

    Amblard, J C [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1967-07-15

    The present note deals with the study regulations of the sampled type, for 1. order process with simple delay. In order to obtain a good stability in such regulations, together with acceptable performances, it is interesting to use polynomial type correctors acting directly on the sampled error signals. The active elements of these correctors can be shared by all the channels to be controlled. Furthermore, the determination of the correction parameters results from an optimal study of the system. In the second part is described the construction of a multiplexed regulation for diffusion ovens. (author) [French] La presente note concerne l'etude des regulations de type echantillonne, pour processus du 1. ordre avec retard pur. Pour obtenir une bonne stabilite de telles regulations, ainsi que des performances correcte il est interessant d'utiliser des correcteurs de type polynomial, agissant directement sur les signaux d'erreur echantillonnes. Les elements actifs de ces correcteurs peuvent etre pris communs a toutes les voies a controler. D'autre part, la determination des parametres de correction decoula d'une etude optimale du systeme. Dans une seconde partie on decrit la realisation d'une regulation multiplexee de fours a diffusion. (auteur)

  3. Radio-vulcanization of natural rubber in the latex phase. Study of an experimental 1 tonne per hour production; Radio-vulcanisation du caoutchouc naturel en phase latex. Etude d'une production experimentale de 1 tonne par heure

    Energy Technology Data Exchange (ETDEWEB)

    Leveque, P; Puig, J R; Roudeix, H [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1968-07-01

    After briefly reviewing the main research carried out on the radio-vulcanization of latex and elastomers, a description is given of 4 types of cell which have been used successively with a view to industrial irradiation. They have made it possible to acquire the information necessary for resolving the main problem arising during irradiation - the formation of coagulum. The first two cell are designed for irradiation by a horizontal beam ('Dynamitron'), the two others use a vertical beam ('Circe'). The study of the properties of the rubber obtained shows it to compare favorably with 'Revultex'. In the appendix are given some characteristics of natural latex and information about its processing. (authors) [French] Apres un rappel des principales etudes sur la radio-vulcanisation du latex et des elastomeres, on decrit les quatre types de cellules successivement essayes en vue de l'irradiation industrielle. Ils ont permis d'acquerir les informations necessaires a la resolution du probleme principal pose par l'irradiation, la formation de coagulum au cours de celle,-ci. Les deux premiers sont concus pour l'irradiation par un faisceau horizontal ('Dynamitron'), les derniers par un faisceau vertical ('Circe'). L'etude des proprietes du caoutchouc obtenu montre qu'il se compare favorablement au 'Revultex'. Un apercu est donne en annexe des caracteristiques du latex naturel et de sa mise en oeuvre. (auteurs)

  4. A crystallographic and spectroscopic study of crystal sites in the 'spinel' structure; Etude cristallographique et spectroscopique des sites cristallins dans la structure 'spinelle'

    Energy Technology Data Exchange (ETDEWEB)

    Drifford, M. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1967-06-15

    A crystallographic study on magnesium aluminates led to the determination of crystal site average distortion. A spectroscopic study of transition elements doped spinels gave the position of the doping element in tetrahedral (A) or octahedral (B) sites, and the local distortion of the latter. The comparison of average and local parameters points to differences in the behaviour of doping elements and shows the size of (A) sites are independent of the host crystal composition while the average size of (B) sites varies with the composition. (author) [French] Une etude cristallographique des aluminates de magnesium a permis de determiner la deformation moyenne des sites cristallins. Une etude spectroscopique des aluminates de magnesium dopes avec des elements de transition a permis de localiser les dopants entre les sites tetraedriques (A) et octaedriques (B) et d'etudier la deformation locale de ces sites. La comparaison entre les parametres moyens et locaux a caracterise le comportement du dopant et montre que les dimensions des sites (A) sont independantes de la composition de la matrice, alors que les caracteristiques geometriques moyennes des sites (B) varient continument avec la composition. (auteur)

  5. Application of the Moessbauer effect to the study of the structure of transition metal complexes; Applications de l'effet Mossbauer a l'etude de la structure des complexes des metaux de transition

    Energy Technology Data Exchange (ETDEWEB)

    Tsymbal, C [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1968-07-01

    In this survey, the structural investigations of transition metal complexes by the hyperfine interactions in the Moessbauer effect are described. The isomer shift provides a unique tool for estimating s electrons covalency in high spin complexes and one of the best pieces of evidence for the importance of bacle donation in low spin complexes. The electric field gradient deriving from quadrupole coupling measurements is correlated with the energy levels distribution of d orbitals in high spin complexes, whereas in low spin complexes it originates from the unbalanced d electrons. (authors) [French] Dans cette etude, nous decrivons les applications des interactions hyperfines dans l' effet Mossbauer a l'etude de la structure des complexes des metaux de transition. Le deplacement isomerique donne des informations tres utiles sur la covalence des electrons s dans les complexes a spin eleve et met en evidence d'une maniere nette l'importance du phenomene de 'bacle donation' dans les complexes a spin faible. Le gradient de champ electrique qui provient des mesures d'interaction quadripolaire est lie a la distribution des niveaux d'energie des orbitales d dans les complexes a spin eleve alors que dans les complexes a spin faible, il est provoque par des electrons d non apparies. (auteurs)

  6. Study of the antithyroid and radioprotective properties of compounds of the 5 thione imidazolidines group; Etude des proprietes antithyroidiennes et radioprotectrices de composes de la famille des 5 thione imidazolidines

    Energy Technology Data Exchange (ETDEWEB)

    Rinaldi, R; Bernard, Y [Commissariat a l' Energie Atomique, Grenoble (France).Centre d' Etudes Nucleaires

    1961-07-01

    Some compounds of the 5 thione imidazolidines group were synthesized by conventional or original methods, and this study is aimed at defining certain pharmacodynamic properties which these substances may be expected to show on the basis of their structure. The properties looked for are: - antithyroid activity, by studying the difference in iodine 131 fixation by the thyroid of rats previously treated or not with these materials; - radioprotective activity, by the comparative study of percentage survival; after 30 days, of mice subjected to a lethal dose of X radiation and having received or not, before irradiation, an intraperitoneal injection of the product under investigation. (author) [French] La synthese de quelques composes de la famille des 5 thione imidazolidines a ete realisee par des methodes classiques ou originales, et le but de ce travail est d'essayer de preciser certaines proprietes pharmacodynamiques que la structure de ces substances peut laisser prevoir. Les proprietes recherchees sont: - l'activite antithyroidienne par l'etude de la difference de la fixation de l'iode 131 par la thyroide de rats prealablement traites ou non par ces produits; - l'activite radioprotectrice par l'etude comparative du pourcentage de survie a 30 jours chez des souris soumises a une dose lethale de rayonnement X, et ayant recu ou non, avant irradiation une injection intraperitoneale du produit a etudier. (auteur)

  7. Development of an analogue multiplexed regulation for periodic 1. order delayed processes; Etude et realisation d'une regulation analogique multiplexee pour processus aperiodiques du 1. ordre avec retard pur

    Energy Technology Data Exchange (ETDEWEB)

    Amblard, J.C. [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1967-07-15

    The present note deals with the study regulations of the sampled type, for 1. order process with simple delay. In order to obtain a good stability in such regulations, together with acceptable performances, it is interesting to use polynomial type correctors acting directly on the sampled error signals. The active elements of these correctors can be shared by all the channels to be controlled. Furthermore, the determination of the correction parameters results from an optimal study of the system. In the second part is described the construction of a multiplexed regulation for diffusion ovens. (author) [French] La presente note concerne l'etude des regulations de type echantillonne, pour processus du 1. ordre avec retard pur. Pour obtenir une bonne stabilite de telles regulations, ainsi que des performances correcte il est interessant d'utiliser des correcteurs de type polynomial, agissant directement sur les signaux d'erreur echantillonnes. Les elements actifs de ces correcteurs peuvent etre pris communs a toutes les voies a controler. D'autre part, la determination des parametres de correction decoula d'une etude optimale du systeme. Dans une seconde partie on decrit la realisation d'une regulation multiplexee de fours a diffusion. (auteur)

  8. E. P. R. spectroscopic study of nitroxide mono- and bi-radicals; Etude par spectroscopie de resonance paramagnetique electronique de monoradicaux et de biradicaux nitroxydes

    Energy Technology Data Exchange (ETDEWEB)

    Lemaire, H [Commissariat a l' Energie Atomique, Grenoble, 38 (France). Centre d' Etudes Nucleaires

    1967-07-01

    A nitroxide is a molecule containing the group N-O where the oxygen atom made only one bond instead of the usual two. The main advantage of these radicals is their exceptional stability; this allows the study of well defined chemical structures while varying at will the experimental conditions. Studies by electron paramagnetic resonance of nitroxide mono-radicals have given the principal directions and the principal values of the electron-nitrogen nucleus hyperfine tensor and of the anisotropic g-factor tensor. The results were then related to the electronic structure of radicals. An understanding was obtained of the influence of the solvent on the principal values of the tensors, and the marked differences observed in the broadening of hyperfine lines when the medium become viscous. In the nitroxide biradicals, the hyperfine spectra depends not only on the magnetic interactions relative to each monomer, but also on the magnitude of the exchange interaction between the singlet and the triplet states of the dimer; the biradicals studied here are the first organic compounds which show clearly the influence of this exchange on the hyperfine structure. The two unpaired electrons also interact by a magnetic dipolar interaction: in the intermediate case, this can be used to derive the sign of the exchange interaction if the bi-radical is studied in a liquid crystal. Just as for mono-radicals, the hyperfine spectra of bi-radicals show selective broadening in viscous media, which is caused by an overall motional modulation of the anisotropic tensors. This gives another way to determine the sign of the exchange interaction. (author) [French] On appelle nitroxyde une molecule contenant le groupement N-O ou l'atome d'oxygene n'a satisfait qu'une seule liaison de valence sur les deux qui lui sont habituelles. L'interet majeur de ces radicaux reside dans leur exceptionnelle stabilite, permettant ainsi de faire varier a loisir les conditions experimentales d'etude de produits

  9. Contribution to the study of the sintering of finely divided alumina; Contribution a l'etude du frittage de l'alumine finement divisee

    Energy Technology Data Exchange (ETDEWEB)

    Vergnon, P [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1966-07-01

    Two crystalline forms of alumina, delta and alpha, were used to prepare compacts. The shrinkage of these compacts was investigated at different temperatures. The samples of alumina are composed of non porous, spherical particles, of a very high purity. Their mean diameter varies between 160 and 1 200 Angstrom for the delta alumina samples and between 400 and 1 200 Angstrom for the alpha alumina samples. The shrinkage of compacts, heated at a linearly increasing temperature (300 deg. C/h, slow heating) was studied in a A.D.A.M.E.L. dilatometer, modified to be used as a retractometer. The kinetics of the isothermal shrinkage of compacts after their rapid introduction (a few seconds, flash heating) in the high temperature zone of the furnace were followed with a photographic technique. It is shown that the heating rate influences the shrinkage of the compacts when they are heated at temperatures over 1 000 deg. C. The kinetics of the isothermal shrinkage, at temperature between 1000 deg. C and 1600 deg. C were thoroughly studied. Values of the apparent activation energy for the different classes of compacts are given. An interpretation of the results is proposed. It takes into account two different but interdependent mechanisms of sintering: the disappearance of porosity as a result of vacancy diffusion and the grain growth as a result of boundary migration. (author) [French] Deux formes cristallines de l'alumine, la forme delta et la forme alpha, ont ete utilisees pour confectionner des comprimes en vue d'une etude cinetique du frittage. Ces alumines d'une tres grande purete sont constituees de particules spheriques non poreuses, sensiblement homodispersees dont le diametre moyen varie entre 160 et 1200 Angstrom pour les echantillons de l'alumine delta et entre 400 et 1200 Angstrom pour ceux de l'alumine alpha. Le retrait des comprimes chauffes a temperature linerairement croissante (300 deg. C/h: chauffage lent) a ete suivi a l'aide du dilotometre A

  10. Contribution to the study of the sintering of finely divided alumina; Contribution a l'etude du frittage de l'alumine finement divisee

    Energy Technology Data Exchange (ETDEWEB)

    Vergnon, P. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1966-07-01

    Two crystalline forms of alumina, delta and alpha, were used to prepare compacts. The shrinkage of these compacts was investigated at different temperatures. The samples of alumina are composed of non porous, spherical particles, of a very high purity. Their mean diameter varies between 160 and 1 200 Angstrom for the delta alumina samples and between 400 and 1 200 Angstrom for the alpha alumina samples. The shrinkage of compacts, heated at a linearly increasing temperature (300 deg. C/h, slow heating) was studied in a A.D.A.M.E.L. dilatometer, modified to be used as a retractometer. The kinetics of the isothermal shrinkage of compacts after their rapid introduction (a few seconds, flash heating) in the high temperature zone of the furnace were followed with a photographic technique. It is shown that the heating rate influences the shrinkage of the compacts when they are heated at temperatures over 1 000 deg. C. The kinetics of the isothermal shrinkage, at temperature between 1000 deg. C and 1600 deg. C were thoroughly studied. Values of the apparent activation energy for the different classes of compacts are given. An interpretation of the results is proposed. It takes into account two different but interdependent mechanisms of sintering: the disappearance of porosity as a result of vacancy diffusion and the grain growth as a result of boundary migration. (author) [French] Deux formes cristallines de l'alumine, la forme delta et la forme alpha, ont ete utilisees pour confectionner des comprimes en vue d'une etude cinetique du frittage. Ces alumines d'une tres grande purete sont constituees de particules spheriques non poreuses, sensiblement homodispersees dont le diametre moyen varie entre 160 et 1200 Angstrom pour les echantillons de l'alumine delta et entre 400 et 1200 Angstrom pour ceux de l'alumine alpha. Le retrait des comprimes chauffes a temperature linerairement croissante (300 deg. C/h: chauffage lent) a ete suivi a l'aide du

  11. Electrochemical study of chemical properties in ethanolamine and its mixtures with water; Etude electrochimique de proprietes chimiques dans l'ethanolamine et ses melanges avec l'eau

    Energy Technology Data Exchange (ETDEWEB)

    Grall, M [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1964-12-01

    This work is concerned with the study of acid-base reactions and of complex formation in ethanolamine and its mixtures with water. The ionic product of the solvent has been determined by an electro-chemical study of the H{sup +}/H{sub 2} system. The reduction curves for ethanolamine-water mixtures, for different acidities, have made it possible to follow the variations in the size of the pH domain as a function of the composition of the solvent. The form of this variation has been explained on the basis of the dielectric constant and the solvation of the proton by the ethanolamine. In the second part, the electrochemical systems of mercury have been studied by anodic polarography. In order to establish a parallel between the acid-base reactions and complex formation reactions, we have studied the stability of Hg (CN){sub 2} in water-ethanolamine mixtures. It has been possible to deduce the law for the variation of pK{sub c} with solvent composition. The representative graph of this function passes through a minimum for a proportion of about 50 per cent of ethanolamine as in the case of acids. This variation has been explained by the predominating influence of {epsilon} for ethanolamine propositions of over 50 per cent and by that of the solvation of Hg{sup 2+} for proportions of under 50 per cent. (author) [French] Ce travail porte sur l'etude des reactions acides-bases et de formation de complexes dans l'ethanolamine et ses melanges avec l'eau. Le produit ionique du solvant a pu etre determine par l'etude electro-chimique du systeme H{sup +}/H{sub 2}. Les courbes de reduction des melanges ethanolamine-eau, pour des acidites variables, ont permis de suivre les variations de l'etendue du domaine de pH, en fonction de la composition du solvant. L'allure de cette variation a ete expliquee en faisant intervenir la constante dielectrique et la solvatation du proton par l'ethanolamine. Dans une deuxieme partie, les systemes electrochimiques du mercure ont ete etudies par

  12. Polarographic study of Cd(2), Pb(2), Hg(1) in anhydrous acetic acid; Etude polarographique de Cd(2), Pb(2), Hg(1) dans l'acide acetique anhydre

    Energy Technology Data Exchange (ETDEWEB)

    Conesa-Botta, M C [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1966-07-01

    }{sup +} + Ac O{sup -} avec K{sub i} = |Ac O H{sub 2}|{sup +} |Ac O{sup -}| = 10{sup -14.5} analogue a 2 H{sub 2}O {r_reversible} H{sub 3}O{sup +} + HO{sup -} avec K{sub i} = |H{sub 3}O{sup +}| |HO{sup -}| = 10{sup -14} Les reactions acides-bases peuvent en principe y etre caracterisees par une echelle de pH, selon une definition analogue a celle du pH en solution aqueuse. Cependant, la difference essentielle entre les solutions aqueuses et les solutions dans l'acide acetique provient du fait que celui-ci possede une faible constante dielectrique. {epsilon} = 6.1 (a 25 deg. C) Les ions y restent donc associes, pratiquement completement, sous forme de 'paires d'ions', par suite des interactions electrostatiques intenses. Ce phenomene nous oblige a modifier les raisonnements que l'on utilise habituellement pour les solutions aqueuses. Les nouveaux raisonnements generaux pour les milieux peu dissociants ont ete etablis et exposes par G. CHARLOT et B, TREMILLON. Nous les utiliserons dans le cas particulier de notre etude. Dans la premiere partie, nous avons mis en oeuvre la methode polarographique pour l'etude des complexes acetate de deux elements: le cadmium (II) et le plomb (II). Dans la seconde partie, nous avons tente de mettre en evidence la formation des halogenures mercureux dans l'acide acetique, et d'en determiner la stabilite. (auteur)

  13. Data processing in gamma spectrometry. Application to the decay schemes study; Traitement des informations en spectrometrie gamma application a l'etude de schemas de desintegration

    Energy Technology Data Exchange (ETDEWEB)

    Boulanger, J P [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires, departement d' electronique generale, service d' instrumentation nucleaire

    1968-06-01

    The purpose of this thesis is the processing of the data issued from a gamma spectrometer, and its applications to the decay schemes study. The mathematical analysis of the full energy peaks, in connection with the very good resolution of semi-conductor detectors, leads to a very accurate determination of the energies. The resolution of complex spectra by the least squares method, completed by a spectra generating process, allows the calculation of branching ratios. Then, the handling of the two dimensional experiments permits the coincidence exam. For each of these methods, the calculation principle, then the systematics tests realized in order to prove their validity and to determine their application ranges as well as some experimental results appropriate to illustrate their possibilities, are presented. The energies of some nuclides, frequently used as standards have been thus measured and the decay schemes of {sup 134}Cs and {sup 110m}Ag determined precisely. (author) [French] Cette these est consacree aux methodes de traitement des informations issues d'un spectrometre {gamma}, et a leur application a l'etude des schemas de desintegration: l'analyse mathematique des pics d'absorption totale, conjuguee avec l'excellent pouvoir de resolution des detecteurs semi-conducteurs, conduit a une determination tres precise des energies. La decomposition des spectres complexes par la methode des moindres carres, completee par un procede de generation de spectres, autorise le calcul des rapports de branchement. Enfin le depouillement des experiences biparametriques permet l'examen des coincidences. Pour chacune de ces methodes, on expose le principe des calculs et les essais systematiques effectues afin d'eprouver leur validite et de definir leurs domaines d'application, ainsi que quelques resultats experimentaux propres a illustrer leurs possibilites. Les energies de quelques isotopes utilises couramment comme etalons ont ainsi ete mesurees, et les schemas de

  14. Study of points defects produced by irradiation of monocrystalline nickel and polycrystalline gadolinium; Etude des defauts ponctuels crees par irradiation dans: - le nickel monocristallin - le gadolinium polycristallin

    Energy Technology Data Exchange (ETDEWEB)

    Cope, R [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1969-07-01

    The work described in this thesis falls into two parts: the first comprises a study of magnetocrystalline nickel by resistivity measurements; the second is a description of resistivity and magnetic after effect measurements on an h.c.p. ferromagnetic crystal other than cobalt, namely gadolinium. For the first part we have demonstrated the existence of a small but definite orientation dependence in the creation of point defects by electron irradiation (20 deg. K) of a nickel single crystal. In particular, the effect is manifested in the form of the stage I{sub C}, II and III in the resistivity recovery. In the second part an important result has emerged: namely that there is no magnetic after effect phenomenon in a neutron irradiated (27 deg. K) ferromagnetic metal. Several considerations are discussed by way of a preliminary interpretation of this important difference between gadolinium and cobalt. (author) [French] Le travail qui a fait l'objet de ce memoire comporte deux parties distinctes: une premiere constituee de l'etude du nickel sous la forme de monocristaux, a l'aide de mesures de resistivite; la seconde partie est composee d'experiences de resistivite et de trainage magnetique sur un cristal h.c.p. ferromagnetique autre que le cobalt, le gadolinium. Dans la premiere partie, nous avons mis en evidence un effet sensible de la direction de l'irradiation electronique (a 20 deg. K) sur la creation des defauts ponctuels dans le nickel monocristallin, en particulier au niveau des stades I{sub C}, II et III des courbes de revenu de la resistivite. Dans la deuxieme partie, un point particulier a ete mis en evidence: l'absence de phenomene de trainage magnetique dans un metal ferromagnetique irradie par des neutrons (a 27 deg. K). Quelques points d'interpretations preliminaires sont avances pour expliquer la difference notable entre le gadolinium et le cobalt. (auteur)

  15. Study of a one-dimensional model for a system of interacting fermions; Etude d'un modele a une dimension pour un systeme de fermions en interaction

    Energy Technology Data Exchange (ETDEWEB)

    Gaudin, M [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1967-11-01

    The subject of this thesis is a one dimensional model for a quantum system of fermions with attractive or repulsive interaction. The eigenvalues and eigenfunctions of the Hamiltonian with periodic boundary conditions are exactly determined. The knowledge of the spectrum is essentially applied on the study of the attractive gas, characterized by the presence of 'pairs' or two particles bound states. This system can be described as a gas of 'one dimensional deuterons', which has some analogy with a boson gas. Some extensive properties of the ground state have been discussed for example energy as a function of the density and magnetization, for all the values of the coupling constant. The analytic properties of the energy function are studied, but not completely resolved. Finally the elementary excitations of the phonon type are considered and the dispersion curves are given. (author) [French] On etudie un modele a une dimension pour un systeme quantique de fermions en interaction attractive ou repulsive dans un volume donne. L'ensemble des niveaux d'energie et des etats propres du systeme est determine exactement. La connaissance du spectre est surtout appliquee a l'etude du gaz attractif, interessant par la presence de 'paires' ou etats lies a deux particules. On peut decrire ce systeme comme un gaz de 'deuterons a une dimension' qui possede quelque ressemblance avec un systeme de bosons. Quelques proprietes extensives de l'etat fondamental sont donnees, comme l'energie en fonction de la densite et de la magnetisation totale, pour toute valeur de la constante de couplage. Les proprietes analytiques de la fonction energie sont etudiees sans etre completement elucidees. On aborde enfin les excitations elementaires du systeme et on etablit la courbe de dispersion d'une excitation de type phonon. (auteur)

  16. Contribution to the study of the Fokker-planck equation; Contribution a l'etude de l'equation de Fokker-planck

    Energy Technology Data Exchange (ETDEWEB)

    Blaquiere, A [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1963-07-01

    In the first paragraphs of this report, the Fokker-Planck equation is presented using the presentation method due to S. Chandrasekhar. Certain conventional resolution methods are given, and then a consideration of the physical interpretation of its various terms leads to a new study method based on the use of Campbell's theorems. This gives a solution to the equation in an integral form. The integral kernel of the solution is a normal centred distribution. Finally, the use of the Laplace transformation leads to a simple determination of the parameters of this integral kernel and connects the present theory to the characteristic function method used in particular in the field of nuclear reactors. The method also makes it possible to calculate the moments of the different orders of the probability distribution without the necessity of solving the Fokker-Planck equation. (author) [French] Dans les premiers paragraphes de ce rapport, l'equation de FOKKER-PLANCK est introduite en utilisant le mode d'expose de S. CHANDRASEKHAR. Puis, apres avoir rappele certaines methodes classiques de resolution, l'interpretation physique de ses differents termes nous conduit a une nouvelle methode d'etude qui repose sur l'utilisation des theoremes de CAMPBELL. On est ainsi conduit a la solution de l'equation sous forme integrale. Le noyau integral de la solution est une distribution normale centree. Enfin l'emploi de la transformation de LAPLACE conduit a une determination simple des parametres de ce noyau integral, et relie la theorie actuelle a la methode de la fonction caracteristique associee, utilisee en particulier dans le domaine des reacteurs nucleaires. Finalement cette methode permet le calcul des moments des differents ordres de la distribution de probabilites, sans passer par la resolution souvent laborieuse de l'equation de FOKKER-PLANCK. (auteur)

  17. The protective cell petrus for the production of californium 252; Cellule blindee petrus pour la production et l'etude du californium 252

    Energy Technology Data Exchange (ETDEWEB)

    Sontag, R; Berger, R [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1967-07-01

    The alpha, beta, gamma, neutron cell which is described in the present paper is devoted to the transplutonium element production and study. It is located at the CEN in Fontenay-aux-Roses (France). The 4 feet ordinary concrete shielding made of stacked blocs allows the manipulation of radioactive sources as high as 1000 curies of 1 MeV gamma rays and with a fast neutrons flux of 10{sup 9} n.cm{sup -2}.s{sup -1}. The airtight alpha containment box is equipped with two transfer systems, one consists of a parallelepiped shaped airtight box located in a turntable, the other uses standard cylindrical containers made of polyethylene. The general equipment and the main setting up are also described. (authors) [French] La cellule alpha, beta, gamma, neutron, qui fait l'objet du present article, est destinee a la production et a l'etude des elements transplutoniens. Elle est construite au C.E.N. de Fontenay-aux-Roses (France). La protection biologique, calculee pour une activite de 1000 curies de rayonnement gamma d'energie 1 MeV accompagnee d'un flux de neutrons rapides de 10{sup 9}/cm{sup 2}s, est constituee par des parois en beton de 1,20 m d'epaisseur. L'enceinte alpha est une boite etanche qui comporte devx systemes de transferts: l'un consiste en une boite parallelepipedique etanche logee dans un barillet, l'autre fait appel a des recipients cylindriques standard en polyethylene. L'equipement general et les installations les plus importantes sont ensuite decrits. (auteurs)

  18. Interleukin-6 gene polymorphisms and susceptibility to myocardial infarction: the ECTIM study. Etude Cas-Témoin de l'Infarctus du Myocarde.

    Science.gov (United States)

    Georges, J L; Loukaci, V; Poirier, O; Evans, A; Luc, G; Arveiler, D; Ruidavets, J B; Cambien, F; Tiret, L

    2001-06-01

    There is growing evidence that interleukin (IL) 6 plays an important role in the atherosclerotic process because of its role in mediating immune and inflammatory responses and inducing cell proliferation. The present study examined whether molecular variations at the IL-6 locus are involved in the predisposition to myocardial infarction. The entire coding region, 1,158 bp of the 5' flanking region and 237 bp of the 3' flanking region of the IL-6 gene were screened. We detected three nucleotide substitutions in the 5' region at positions -174 (G/C), -572 (G/C), and -596 (G/A) from the transcription start site, and one insertion/deletion in the 3' region at position +528 after the Stop codon. These polymorphisms were genotyped in the Etude Cas-Témoin de l'Infarctus du Myocarde study comparing male patients (n=640) and age-matched controls (n=719) from Northern Ireland and France. The IL-6/G-174C and IL-6/G-596A polymorphisms were in nearly complete association. Carriers of the IL-6/-174 C allele were more frequent in patients than in controls. The population-adjusted odds ratio for myocardial infarction associated with genotype CC+CG vs. GG was estimated as 1.34. In French patients the number of coronary arteries with greater than 50% stenosis was assessed by angiography. The IL-6/-174 C allele was more frequent in patients with two or fewer stenosed vessels than in patients with three-vessel lesions. These results suggest that genetic variation at the IL-6 locus is associated with susceptibility to myocardial infarction, especially events occurring on less extended lesions. These findings would be compatible with a lower IL-6 secretion associated with the IL-6/-174 C allele, itself or in combination with other promoter polymorphisms, leading to more unstable plaques.

  19. Observation of allotropic transformations of plutonium with a hot stage microscope; Etude des transformations allotropiques du plutonium au microscopic a platine chauffante

    Energy Technology Data Exchange (ETDEWEB)

    Mars, J; Spftiet, B [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1965-07-01

    A hot stage microscope designed for the examination of plutonium and its alloys is described. This apparatus was used to study the {alpha} {r_reversible} {beta} and {delta} {r_reversible} {epsilon} allotropic transformations of pure or {beta} and {delta} stabilised plutonium. The {alpha} {yields} {beta} transformation is typically a nucleation and growth process. Some particularities caused by the internal stresses due to the volume change during this transformation are examined. The kinetics has been studied as a function of these stresses and a temperature dependent activation energy for nucleation has been deduced. The {beta} {yields} {alpha} transformation presents a memory effect which implies an orientation relationship between the two phases. This fact is probably caused by the stresses created during the {beta} {yields} {alpha} transition. The {beta} {r_reversible} {gamma} and {delta} {r_reversible} {epsilon} transformations are also diffusion governed processes. (authors) [French] On decrit un microscope a platine chauffante permettant l'examen du plutonium et de ses alliages. Cet appareil a servi a l'etude des transformations {alpha} {r_reversible} {gamma} et {delta} {r_reversible} {epsilon} du plutonium pur ou stabilise en phase {beta} et {delta}. La transformation {alpha} {yields} {beta} est une transformation typique par germination et croissance; elle presente des caracteristiques bien particulieres qui sont dues aux contraintes internes qui prennent naissance au changement de volume a la transformation; la cinetique a ete etudiee en fonction de ces contraintes, et on en a deduit une energie d'activation pour la germination variable avec la temperature. La transformation {beta} {yields} {alpha} presente un effet de memoire qui suppose une relation d'orientation entre les deux phases; ce phenomene semble lie comme auparavant aux contraintes creees par le passage {beta} {yields} {alpha}. Les transformations {beta} {r_reversible} {gamma} et {delta} {r

  20. Concerning the study of the irreversible magnetic behaviour of superconductivity; Contribution a l'etude du comportement magnetique irreversible des supraconducteurs

    Energy Technology Data Exchange (ETDEWEB)

    Kuhn, G [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1965-03-01

    The influence of the presence of extended lattice defects on the magnetic behaviour has been studied for the case of type I superconductors, such as Re and Ta, and in a more quantitative manner for the type II superconductor niobium. In this case, measurements of the thermal conductivity have given an estimate of the relative concentration of lattice defects in each specimen. These measurements show that the larger the number of lattice defects, the more irreversible becomes the magnetization curve, and the larger becomes the values of the critical current, which is related by a simple model to the magnetization values. Finally, a study by transmission electron microscopy has confirmed on the one hand the diversity of the extended lattice defects and on the other hand has allowed the formulation of several hypothesis on their respective influence. [French] L'influence de la presence de defauts etendus sur le comportement magnetique a ete etudie pour des supraconducteurs de premiere espece, tels que le rhenium et le tantale, et plus quantitativement pour un supraconducteur de deuxieme espece, le niobium. Dans ce cas, des mesures de conductibilite thermique ont permis d'estimer la concentration relative des defauts du reseau dans chaque echantillon. Ces mesures montrent que plus les defauts du reseau sont nombreux, plus la courbe d'aimantation est irreversible, et plus les valeurs du courant critique, reliees par un modele simple aux valeurs de l'aimantation, sont elevees. Enfin une etude par microscopie electronique en transmission - a permis d'une part de constater la diversite des defauts etendus et d'autre part de formuler quelques hypotheses sur leurs influences respectives.

  1. A study of the fixing of phosphoric ions by zirconium-montmorillonite; Etude de la fixation d'ions phosphoriques par la montmorillonite-zirconium

    Energy Technology Data Exchange (ETDEWEB)

    Bittel, R; Boursat, C; Platzer, R [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1960-07-01

    In connection with the research carried out on the purification of nuclear reactor water, we have undertaken a study of the ion-exchange properties of acid montmorillonite. In a previous paper, we described the preparation of zirconium-montmorillonite small plate. The present article aims to study some of the properties of the clay obtained. We have observed that zirconium-montmorillonite fixes very strongly the phosphorus from solutions of phosphoric acid or of phosphates: on 1 g of clay it is possible to fix 1,2 milli-atoms-gram of zirconium and the zirconium montmorillonite itself fixes 2,1 milli-atoms-gram of phosphorus. An explanation of these experimental results, which is as much chemical as mineralogical, is the hypothesis that the fixing of phosphoric ions modifies the distribution of the ions between the platelets and precipitates a very slightly soluble product of the type diphospho-zirconic acid. (author) [French] En rapport avec des recherches sur I'epuration de l'eau des reacteurs nucleaires nous avons entrepris une etude sur les proprietes d'echangeur d'ions de la montmorillonite-acide. Dans une precedente publication, nous avons decrit la preparation des plaquettes de montmorillonite-zirconium. La presente communication a pour but d'etudier quelques proprietes de l'argile obtenue. Nous avons constate que la montmorilionite-zirconium fixe le phosphore de solutions d'acide phosphorique ou de phosphate avec une grande intensite: sur 1 g d'argile, on peut fixer 1,2 atomes-gramme de zirconium, et la montmorillonite-zirconium fixe a son tour 2,1 milli-atomesgramme de phosphore. Une explication des resultats experimentaux, tant d'ordre chimique que d'ordre mineralogique, consiste en l'hypothese suivant laquelle la fixation d'ions phosphoriques modifierait la repartition des ions entre les feuillets avec precipitation du compose tres peu soluble (type: acide diphosphozirconique). (auteur)

  2. Some investigations on the pitting attack of magnesium and its alloys; Contribution a l'etude de la corrosion par piqures du magnesium et de ses alliages

    Energy Technology Data Exchange (ETDEWEB)

    Blanchet, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-03-01

    The pitting attack of magnesium and its alloys has been studied by means of potentio-kinetic polarisation curves; the following parameters have been considered: structural state and composition of the metal, chloride concentration and pH of the medium. The electrochemical data obtained demonstrate that when pH = 12, a localized corrosion might appear as soon as a 10{sup -3} M NaCl concentration is reached; on the other hand, when pH = 13, a much higher concentration (five times) has no effect. In the same conditions, the coupling of magnesium with various noble materials (graphite, platinum, 18/10 stainless steel) also dramatically increases its susceptibility to pitting, but only when chloride ions are present in the solution. Usual corrosion tests have confirmed these electrochemical results. A micrographic study of the pits has shown that their morphology is connected with the metallurgical state of the specimens. (author) [French] La corrosion par piqures du magnesium est etudiee a l'aide des courbes de polarisation potentiocinetiques en fonction des parametres suivants etat structural et composition du metal, concentration en chlorure et pH de la solution. De ces mesures electrochimiques on deduit qu'a pH 12, des la concentration 10{sup -3} M en NaCl, il existe un risque de corrosion localisee, tandis qu'a pH 13 une concentration cinq fois plus forte doit etre sans effet. Dans les memes conditions on montre que le couplage du magnesium avec differents elements nobles (graphite, platine, acier inoxydable 18/10) accroit fortement sa susceptibilite a l'attaque par piqures, excepte dans les solutions exemptes d'ions chlorures. Des essais classiques de corrosion dans les differentes solutions envisagees precedemment confirment les resultats de cette etude electrochimique. L'examen micrographique des piqures montre que leur morphologie est liee a l'etat metallurgique des echantillons. (auteur)

  3. Study of some ion exchange minerals which can be used in water at high temperature; Etude de quelques echangeurs mineraux utilisables dans l'eau a haute temperature

    Energy Technology Data Exchange (ETDEWEB)

    Hure, J; Platzer, R; Bittel, R [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires; Fourre, J [Societe le Carbone Lorraine, 75 - Paris (France); Wey, R [Faculte des Sciences de Strasbourg, Lab. de Mineralogie, 67 (France)

    1958-07-01

    these impurities (that is to say capable of de-mineralizing polluted water). This paper describes the preliminary results of the investigation. (author) [French] L'etude de l'utilisation des echangeurs d'ions a haute temperature a ete essentiellement faite en vue de l'epuration de l'eau des reacteurs. On connait l'interet qu'il y a a garder dans un circuit de reacteur de l'eau de tres haute resistivite (plusieurs centaines a quelques millions {omega}.cm): abaissement de la corrosion, abaissement du taux de radiolyse, abaissement de la radioactivite des circuits et canalisations, les elements autres que les constituants de l'eau transportes par celle-ci devenant generalement radioactifs par leur passage au coeur du reacteur. Si la circulation d'eau se fait a des temperatures inferieures a 45 deg. C, les resines echangeuses d'ions organiques utilisees en lit melange resolvent tres bien le probleme de l'epuration en continu. Par contre, pour des temperatures plus elevees surtout au-dessus de 100 deg. C, leur utilisation n'est pas possible, la degradation de ces hauts polymeres etant tres rapide. De meme, l'action des rayonnements, par exemple ceux des produits fixes par les echangeurs d'ions, detruit irremediablement les chaines organiques constituant le squelette de ces echangeurs. Nous avons donc cherche d'es composes pouvant assurer une bonne deionisation de l'eau, mais de structures telles qu'elles ne soient pas deteriorees par l'action de la temperature et des rayonnements. Nous nous sommes particulierement orientes dans trois voies: - echangeurs d'ions naturels a structure minerale (argile du type montmorillonite), - composes mineraux naturels traites pour leur conferer les proprietes d'echangeurs d'ions (charbons actives), - composes mineraux synthetiques (sels tres peu solubles, phosphate et hydroxyde de zirconium et de thorium). Dans ces etudes, nous nous sommes attaches a obtenir des produits stables en presence d'eau a haute temperature, tres insolubles et non

  4. Preliminary studies on the closed cycle magneto aerodynamic converter; Etudes preliminaires sur les convertisseurs magnetohydrodynamiques fonctionnant hors d'equilibre thermodynamique

    Energy Technology Data Exchange (ETDEWEB)

    Ricateau, P [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-07-01

    electron heating in argon-potassium can be achieved by magnetic fields from 1 to 2 Ts. Plans are being made to build an important facility which will work on the principle of hot shots. The gas generator will deliver cesium-seeded helium shots at a temperature of 2100 deg. K. The shot will last 1/ 10 s and the instantaneous thermal power will reach 1 MW. (author) [French] A cote des convertisseurs magnetoaerodynamiques a cycle ouvert qui transforment l'energie thermique contenue dans les gaz de combustion on etudie tres attentivement le convertisseur a cycle ferme qui peut tirer son energie de toute source de chaleur a haute temperature et tout particulierement des sources nucleaires. Avant une etude pratique de l'ensemble de la centrale les performances du convertisseur lui-meme doivent etre bien delimitees. Ces performances sont largement fonction de la conductivite du gaz utilise. Mais cette conductivite ne doit pas etre payee par une temperature techniquement inadmissible pour l'echangeur de chaleur. Dans le fluide de conversion on est amene a associer un gaz porteur, helium ou argon, et une semence facilement ionisable cesium ou potassium. L'ionisation purement thermique n'est efficace qu'a partir de 2500 deg. K, par contre le champ electrique developpe par induction dans le convertisseur peut, sous certaines conditions, accroitre la temperature electronique et developper une ionisation bien superieure a la valeur d'equilibre. Il devient alors possible d'ioniser le gaz a temperature moderee. Des travaux en cours ont pour but de preciser les conditions permettant de creer cette ionisation hors d'equilibre dans les gaz rares ensemenses. Des mesures ont ete faites a l'aide d'un plasmatron triphase do 500 kVA alimente a l'argon ensemence de potassium. On a fait debiter cet appareil dans une cellule permettant de mesurer les composantes tensorielles de la conductivite en presence de champ magnetique. Les valeurs trouvees dans les conditions d'equilibre thermodynamique

  5. Contribution to the study of diffusion in poly-phase system; Contribution a l'etude de la diffusion en systeme polyphase

    Energy Technology Data Exchange (ETDEWEB)

    Adda, Y; Philibert, J [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires; Institut de Recherches de la Siderurgie Francaise (IRSID), 78 - Saint-Germain-en-Laye (France)

    1959-07-01

    this latter result and of the anomalies in the coefficient of diffusion should probably take into account the accumulation of reticular defects which would appear after displacement of the phase boundaries. (author) [French] Apres diffusion chimique entre deux metaux, a des temperatures auxquelles le diagramme d'equilibre indique l'existence de plusieurs phases, on observe, sur une section perpendiculaire au front de diffusion, des bandes paralleles correspondant a ces diverses phases. On sait que, dans ce cas, la courbe concentration-penetration presente alors une discontinuite a chaque interface. Les concentrations a l'aplomb de ces discontinuites donnent les limites de solubilites respectives des phases en presence. Au cours de nos essais relatifs au couple uranium-zirconium, nous avons verifie que ces concentrations ne varient pas avec la duree de diffusion et que, donc, les conditions de l'equilibre thermodynamique sont bien remplies. On dispose alors d'une methode interessante pour etablir le diagramme d'equilibre a l'etat solide, methode que nous avons appliquee au systeme U-Zr. Les etudes cinetiques de la diffusion polyphasee sont encore assez rares, par suite des difficultes experimentales. Aussi diverses methodes sont-elles proposees pour evaluer le coefficient de diffusion a partir d'etudes purement micrographiques (mesure des epaisseurs des phases intermediaires). Nos resultats experimentaux montrent que les hypotheses sur lesquelles sont basees ces methodes sont tres rarement valables. En effet, nous avons etabli les courbes concentration-penetration dans les systemes U-Zr (entre 590 deg. C et 950 deg. C), et U-MO (entre 800 deg. C et 1050 deg. C). Celles-ci montrent souvent des courbures tres accentuees, qui traduisent des variations du coefficient de diffusion qui ne peuvent pas s'exprimer suivant des relations simples. Enfin, nous avons observe certaines anomalies au voisinage des interfaces entre phases adjacentes. En outre, nous avons etudie l

  6. Contribution to the study of diffusion in poly-phase system; Contribution a l'etude de la diffusion en systeme polyphase

    Energy Technology Data Exchange (ETDEWEB)

    Adda, Y.; Philibert, J. [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires; Institut de Recherches de la Siderurgie Francaise (IRSID), 78 - Saint-Germain-en-Laye (France)

    1959-07-01

    this latter result and of the anomalies in the coefficient of diffusion should probably take into account the accumulation of reticular defects which would appear after displacement of the phase boundaries. (author) [French] Apres diffusion chimique entre deux metaux, a des temperatures auxquelles le diagramme d'equilibre indique l'existence de plusieurs phases, on observe, sur une section perpendiculaire au front de diffusion, des bandes paralleles correspondant a ces diverses phases. On sait que, dans ce cas, la courbe concentration-penetration presente alors une discontinuite a chaque interface. Les concentrations a l'aplomb de ces discontinuites donnent les limites de solubilites respectives des phases en presence. Au cours de nos essais relatifs au couple uranium-zirconium, nous avons verifie que ces concentrations ne varient pas avec la duree de diffusion et que, donc, les conditions de l'equilibre thermodynamique sont bien remplies. On dispose alors d'une methode interessante pour etablir le diagramme d'equilibre a l'etat solide, methode que nous avons appliquee au systeme U-Zr. Les etudes cinetiques de la diffusion polyphasee sont encore assez rares, par suite des difficultes experimentales. Aussi diverses methodes sont-elles proposees pour evaluer le coefficient de diffusion a partir d'etudes purement micrographiques (mesure des epaisseurs des phases intermediaires). Nos resultats experimentaux montrent que les hypotheses sur lesquelles sont basees ces methodes sont tres rarement valables. En effet, nous avons etabli les courbes concentration-penetration dans les systemes U-Zr (entre 590 deg. C et 950 deg. C), et U-MO (entre 800 deg. C et 1050 deg. C). Celles-ci montrent souvent des courbures tres accentuees, qui traduisent des variations du coefficient de diffusion qui ne peuvent pas s'exprimer suivant des relations simples. Enfin, nous avons observe certaines anomalies au voisinage des interfaces entre phases

  7. Comparative Studies with N-Methyl-2-Pyrrolidone and Furfural As Solvents for Extraction of Lube Distillates Etude comparative de deux solvants, la n-methyl-2 pyrrolidone et le furfural, pour l'extraction de distillats pour huiles lubrifiantes

    Directory of Open Access Journals (Sweden)

    Krishna R.

    2006-11-01

    Full Text Available Solvent extraction of spindle raw lube distillate from Oman crude using n-methyl pyrrolidone (NMP containing 1. 5wt. % water has been studied using a six-stage all-glass mixer-settler. Results of three operating temperatures with NMP are reported. A 65-55°C extraction temperature appears to be most appropriate for this stock. Data obtained at this temperature have been compared with those for furfural on the basis of phase boundary curves, extraction and lube refining indices and selectivity. Comparison of the results shows NMP to be more selective as far as raffinate yield is concerned. It requires lower operating solvent-to-feed ratios and lower temperatures. On étudie dans cet article l'extraction par solvant de distillats bruts pour huiles lubrifiantes spindles au moyen de n-méthyl pyrrolydone (NMP contenant 1,5 % d'eau en poids, dans une unité en verre constituée par une batterie de six mélangeurs-décanteurs. On présente les résultats relatifs à trois températures de fonctionnement avec la NMP. Une température d'extraction de 66-55°C est celle qui convient le mieux pour cette huile de base. On compare les résultats obtenus à cette température avec ceux du furfural, en ce qui concerne les courbes de solubilité, les indices de raffinage et d'extraction, et les sélectivités. La comparaison des résultats montre que la NMP est plus sélective et conduit à un rendement de raffinat plus élevé. Elle nécessite des taux de solvant par rapport à la charge plus faibles ainsi que des températures d'extraction plus basses.

  8. Blowing loop in the EL-4 reactor: CO{sub 2} flow control analogue study; Boucle de soufflage de la centrale EL-4 - regulation du debit CO{sub 2} - etude analogique

    Energy Technology Data Exchange (ETDEWEB)

    Chazal, G; Merle, J P; Guillemard, B [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires; Leroy, C; Robin, L; Jacquin, J C; Cornudet, A [Societe INDATOM, France (France)

    1966-07-01

    This report describes one study which contributed to the construction of the Monts d'Arree nuclear power station: EL-4. The reactor is cooled by a CO{sub 2} current provided by 3 turbo-blower groups. The priming vapour for the turbines is taken at the exit of the main CO{sub 2} - H{sub 2}O exchangers. The operation of EL 4 is based on a high degree of centralization of the controls which attributes an important role to the general regulation circuits. This general regulation includes in particular an internal blowing loop which controls the CO{sub 2} flow. The study of the control of this CO{sub 2} flow is made up of 3 parts: - analogue representation of the reactors cooling circuit and of the turbo blower unit. - first test campaign using the analogue computer describing the natural behaviour of the system in the absence of control. theoretical determination of the regulation factors; definition of the regulation using an analogue computer and second test campaign for recording the performances of the blowing loop. The 4. part of the report deals with the analogue study: analogue equations - development. (authors) [French] Ce rapport prend place parmi les etudes de realisation de la Centrale des Monts d'Arree EL-4. Le reacteur est refroidi par une circulation de CO{sub 2} assuree par 3 groupes turbosoufflantes. La vapeur d'entrainement des turbines est prelevee a la sortie des echangeurs principaux CO{sub 2} - H{sub 2}O. L'exploitation de EL-4 repose sur une centralisation poussee des moyens de controle-commande qui attribue un role essentiel aux circuits de regulation generale. Cette regulation generale comporte en particulier une boucle interne de soufflage qui realise un asservissement du debit de CO{sub 2}. L'etude de cette regulation du debit CO{sub 2} comprend 3 parties: - representation analogique du circuit de refroidissement du reacteur et de l'ensemble turbine-soufflante. - premiere campagne d'essais sur calculateur analogique decrivant le comportement

  9. Study of gamma radiation between 0.1 and 1.0 MeV in the earth's atmosphere; Etude du rayonnement gamma entre 0,1 et 1 Mev dans l'atmosphere terrestre

    Energy Technology Data Exchange (ETDEWEB)

    Boclet, D [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1967-01-01

    The present work is devoted to some of the particular problems arising in the detection and localisation of sources of gamma radiation situated outside the earth's atmosphere. These weak sources can only be detected and localized if care is taken to eliminate gamma and particle radiations coming from other sources in the earth's atmosphere and in space. In order to separate the various sources of background noise, generally much stronger than the radiation under study, use is made of a directional detector whose characteristics are determined as described in the first part of the following report. The closest diffuse source considered is that constituted by the earth's atmosphere. Its detailed study will make it possible both to eliminate its effect when sources outside the earth are to be measured, and to predict the amount of secondary gamma radiation emitted by the same process in other celestial bodies, the moon in particular. This work considered in the 2. and 3. parts of the report. (author) [French] La presente etude est consacree a certains des problemes particuliers poses par la detection et la localisation des sources de rayonnement gamma situees hors de l'atmosphere terrestre. Ces sources faibles ne peuvent etre detectees et localisees que si l'on se protege des rayonnements gamma et particulaires provenant d'autres sources situees dans l'atmosphere terrestre et dans l'espace. Pour separer ces divers composants parasites, en general beaucoup plus intenses que le rayonnement a etudier, nous emploierons un detecteur directif dont nous determinons les caracteristiques dans la premiere partie de l'expose qui suit. La source diffuse la plus proche que nous considerons comme parasite est constituee par l'atmosphere terrestre. Son etude detaillee nous permettra d'une part de nous en proteger lorsque nous voudrons etudier les sources {gamma} extra-terrestres, d'autre part de prevoir le rayonnement gamma secondaire emis par le meme processus pour les autres corps

  10. Study of a photomultiplier for the measurement of low light flows by photon counting; Etude d'un photomultiplicateur en vue de la mesure des faibles flux lumineux par comptage de photons

    Energy Technology Data Exchange (ETDEWEB)

    Haye, Kleber

    1964-03-20

    After a recall of the history of the discovery and use of the photoemission effect, a presentation of the main characteristics of photomultipliers, a discussion of performance and weaknesses of electron multiplier-based cells, this research thesis addresses the study of low light flows. The author tried to determine whether it was possible, at ambient temperature, to reduce the influence of the thermoelectric effect. In order to do so, he made a detailed study of the amplitude spectrum of pulses of photoelectric origin. In order to analyse the influence of temperature of photomultiplier characteristics, he studied, with respect to temperature, the variation of the counting rate corresponding to darkness, the variation of pulse amplitude spectrum, and relative variations of the quantum efficiency for various wavelengths. In parallel with the study by counting, a study has been performed by using the well known mean current measurement [French] Si l'on veut etudier de faibles flux lumineux, c'est surtout l'effet thermoelectronique qui limite a temperature ambiante le domaine possible des mesures. Les electrons qui arrivent en effet a quitter la photocathode ou les dynodes donnent naissance a des groupes supplementaires d'electrons venant s'ajouter a ceux causes par effet photoelectrique. En utilisant une methode de mesure par comptage des groupes d'electrons, nous nous sommes attaches a determiner s'il etait possible a temperature ordinaire de reduire 1'influence de l'effet thermoelectronique. Pour cela, nous avons fait une etude detaillee du spectre d'amplitude des impulsions d'origine photoelectrique. Toutefois, la solution la plus efficace pour combattre l'effet thermoelectronique etant le refroidissement, nous avons essaye d'analyser l'influence de la temperature sur les caracteristiques du photomultiplicateur. Nous avons ainsi etudie en fonction de la temperature la variation du taux de comptage correspondant a l'obscurite, la variation du spectre d

  11. Study of the machining of uranium carbide rods obtained by continuous casting under electronic bombardment; Etude de l'usinage de barreaux de carbure d'uranium obtenus par coulee continue sous bombardement electronique

    Energy Technology Data Exchange (ETDEWEB)

    Rousset, P.; Accary, A. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1965-07-01

    The authors consider the various methods of machining uranium mono-carbide and compare them critically in the case of their application to uranium carbide obtained by fusion under an electronic bombardment and continuous casting. This study leads them to propose two mechanical machining methods: cylindrical rectification and center-less rectification, preceded by a preliminary roughing out of a cylinder, the latter appearing more suitable. A study of the machining yields as a function of the diameter of the rough bars and of the diameter of the finished rods has shown that an optimum value of the rough bar diameter exists for each value of the finished rod diameter. It is found that the yield increases as the diameter itself increases, this yield rising from 45 per cent to around 70 per cent as the diameter of the rough bars increases from 25-26 mm to 37-38 mm. (authors) [French] Les auteurs envisagent les differentes methodes d'usinage du monocarbure d'uranium et se livrent a une etude critique de celles-ci, dans le cas de leur application a l'usinage de barreaux de carbure d'uranium obtenus par fusion sous bombardement electronique et coulee continue. Cette etude les conduit a proposer deux methodes d'usinage mecanique: la rectification cylindrique et la rectification 'centerless', precedee d'un ebauchage par carottage, la seconde paraissant la plus appropriee. L'etude des rendements d'usinage en fonction du diametre des barreaux bruts et du diametre des barreaux finis, a mis en evidence une valeur optimale du diametre des barreaux bruts pour chaque valeur du diametre des barreaux usines. Elle a montre que le rendement croit lorsque le diametre croit lui-meme, ce rendement passant d'environ 45 pour cent a environ 70 pour cent, lorsque le diametre des barreaux bruts passe de 25-26 mm a 37-38 mm.

  12. Study of gamma radiation between 0.1 and 1.0 MeV in the earth's atmosphere; Etude du rayonnement gamma entre 0,1 et 1 Mev dans l'atmosphere terrestre

    Energy Technology Data Exchange (ETDEWEB)

    Boclet, D. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1967-01-01

    The present work is devoted to some of the particular problems arising in the detection and localisation of sources of gamma radiation situated outside the earth's atmosphere. These weak sources can only be detected and localized if care is taken to eliminate gamma and particle radiations coming from other sources in the earth's atmosphere and in space. In order to separate the various sources of background noise, generally much stronger than the radiation under study, use is made of a directional detector whose characteristics are determined as described in the first part of the following report. The closest diffuse source considered is that constituted by the earth's atmosphere. Its detailed study will make it possible both to eliminate its effect when sources outside the earth are to be measured, and to predict the amount of secondary gamma radiation emitted by the same process in other celestial bodies, the moon in particular. This work considered in the 2. and 3. parts of the report. (author) [French] La presente etude est consacree a certains des problemes particuliers poses par la detection et la localisation des sources de rayonnement gamma situees hors de l'atmosphere terrestre. Ces sources faibles ne peuvent etre detectees et localisees que si l'on se protege des rayonnements gamma et particulaires provenant d'autres sources situees dans l'atmosphere terrestre et dans l'espace. Pour separer ces divers composants parasites, en general beaucoup plus intenses que le rayonnement a etudier, nous emploierons un detecteur directif dont nous determinons les caracteristiques dans la premiere partie de l'expose qui suit. La source diffuse la plus proche que nous considerons comme parasite est constituee par l'atmosphere terrestre. Son etude detaillee nous permettra d'une part de nous en proteger lorsque nous voudrons etudier les sources {gamma} extra-terrestres, d'autre part de prevoir le rayonnement gamma

  13. Applications of prospecting geochemical techniques to the search for and to the study of uranium deposits in metropolitan France; Applications des techniques geochimiques de prospection a la recherche et a l'etude des gites uraniferes en France metropolitaine

    Energy Technology Data Exchange (ETDEWEB)

    Grimbert, Arnold

    1957-07-01

    After having recalled facts which leaded the CEA to use new geochemical techniques for the prospecting of uranium deposits through sampling and analysis of soils and waters, the author describes the organisation and methods implemented for this prospecting activity: team composition for sampling and analysis, role of each engineer and technician in the prospecting stages (preliminary study, routine prospecting, result interpretation), sampling and analysis processes. He also reports campaigns of geochemical prospecting: study of the La Chapelle Largeau deposit (objectives, geological context, preliminary study, routine prospecting, study of geochemical anomalies), tactical research on Verneix indices (study of radioactivity anomaly discovered by radio-prospecting), strategical searches in a non prospected area in the South of Avallon. The author discusses the issues of efficiency and cost price of this geochemical prospecting technique in soils and in waters. Appendices present the equipment and operation modality for soil sampling, and for soil sample preparation, and principles, equipment and products for soil analysis and for water analysis [French] A la suite des resultats satisfaisants obtenus dans la recherche de methodes de dosage adaptees au cas de l'uranium, la Direction des Recherches Minieres du Commissariat a l'Energie atomique a decide, en decembre 1954, d'utiliser, conjointement avec les methodes classiques de prospection, les techniques geochimiques pour la recherche et l'etude des gites uraniferes. Ces applications pratiques ont ete confiees a une Section de Geochimie dont l'organisation, les moyens en personnel et en materiel, ainsi que les methodes de travail, font l'objet d'un expose detaille. Quelques exemples de prospection, en France metropolitaine, montrent la nature des problemes poses (etude d'un gisement connu, recherche tactique sur des indices, recherche strategique dans une region non prospectee), les methodes utilisees pour les

  14. Chromosomes and irradiation: in vitro study of the action of X-rays on human lymphocytes; Chromosomes et radiations: etude in vitro de l'action des rayons X sur les lymphocytes humains

    Energy Technology Data Exchange (ETDEWEB)

    Mouriquand, C; Patet, J; Gilly, C; Wolff, C

    1966-07-01

    Radioinduced chromosomal aberrations were studied in vitro on leukocytes of human peripheral blood after x irradiation at 25, 50, 100, 200, and 300 R. The numeric and structural anomalies were examined on 600 karyotypes. The relationship between these disorders and the dose delivered to the blood are discussed. An explanation on their mechanism of formation is tentatively given. (authors) [French] L'etude in vitro des anomalies chromosomiques radioinduites a ete pratiquee sur des leucocytes de sang peripherique preleve chez 4 sujets et irradie aux doses de 25, 50, 100, 200, 300 R. Les aberrations numeriques et structurales ont ete examinees sur 600 caryotypes. Les rapports entre ces anomalies et les doses appliquees sont etudies. Une hypothese sur leur mecanisme de formation est avancee. (auteurs)

  15. Thermodynamic properties of beryllium hydroxide; Proprietes thermodynamiques de l'hydroxyde de beryllium. Etude du systeme BeO - H{sub 2}O - BE(OH){sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Baur, A; Lecocq, A [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-07-01

    The study of the hydro-thermal decomposition of beryllium hydroxide has made it possible to determine the free energy of formation and the entropy. The results obtained are in good agreement with the theoretical values calculated from the solubility product of this substance. They give furthermore the possibility of acquiring a better understanding of the BeO-H{sub 2}O-Be (OH){sub 2} system between 20 and 1500 C. (authors) [French] L'etude de la decomposition hydrothermale de l'hydroxyde de beryllium a permis de determiner l'energie libre de formation et l'entropie. Les resultats obtenus sont en bon accord avec les valeurs theoriques calculees a partir du produit de solubilite de ce corps. Ils donnent en outre la possibilite d'acceder a une meilleure comprehension du systeme BeO - H{sub 2}O - Be(OH){sub 2}, entre 20 C et 1500 C. (auteurs)

  16. Contribution to the study of plasmatic fibrinogen and serum albumin: effects of irradiation; Contribution a l'etude du fibrinogene et de la serum-albumine plasmatiques - effets de l'irradiation

    Energy Technology Data Exchange (ETDEWEB)

    Suscillon, M [Commissariat a l' Energie Atomique, Centre d' Etudes Nucleaires de Grenoble, 38 (France)

    1967-07-01

    The author studies the modifications of properties and structure of serum albumin and fibrinogen solution when subjected to radiation of low energy (X rays). On the other hand, two original techniques are exposed: 1. Amperometric determination of fibrin stabilizing factor or factor XIII of hemostasis. 2. Spectrophotometric study of fibrin formation kinetics. Then showing off and quantitative determination of platelets fibrinogen is exposed. (author) [French] L'auteur etudie les modifications des proprietes et de la structure des molecules de serum-albumine et de fibrinogene en solution soumise a un flux de RX de basse energie. D'autre part deux techniques originales sont exposees : 1. Dosage amperometrique du facteur stabilisant de la fibrine. 2. Etude spectrophotometrique de la cinetique de la fibro-formation. Enfin une mise en evidence et un dosage du fibrinogene plaquettaire sont presentes. (auteur)

  17. Treatment of Radioactive Effluents at the Saclay Nuclear Research Centre; Traitement des Effluents Radioactifs au Centre d'Etudes Nucleaires de Saclay; 041e 0414 ; Tratamiento de los Efluentes Radiactivos en el Centro de Energia Nuclear de Saclay

    Energy Technology Data Exchange (ETDEWEB)

    Wormser, G. [Service de Controle des Radiations et de Genie Radioactif, Commissariat a l' Energie Atomique, Saclay (France)

    1960-07-01

    The Report Gives The Account Of Four Years' Experience In Operating The Treatment Plant For Effluents From The Saclay Nuclear Research Centre. It Contains Data Relating To The Origin, Volume And Treatment Of Waste. (author) [French] Ce rapport presente un bilan d'exploitation de l'installation de traitement des effluents du Centre d'etudes nucleaires de Saclay depuis quatre ans. On donne des chiffres concernant l'origine des residus, leur volume, leur traitement. (author) [Spanish] El autor hace un balance de explotacion de la instalacion de tratamiento de efluentes del centro de Saclay desde hace cuatro anos, dando las cifras correspondientes al origen de los residuos, a su volumen y a su tratamiento. (author) [Russian] V jetom dokumente podvoditsja itog chetyrehletnej jekspluatacii ustanovki po obrabotke zhidkih othotov v Centre jadernyh issledovanij v Sakle. V doklade privodjatsja dannye o proishozhdenii othodov, jh ob'eme i obrabotke. (author)

  18. Study of the age of uranium-containing mineral deposits in the Limouzat, the bois-noir mountains (12963); Etude des ages des mineralisations uraniferes du gisement du Limouzat, Massif des bois-noirs (1963)

    Energy Technology Data Exchange (ETDEWEB)

    Durand, G [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1963-07-01

    The present work is concerned with 7 different samples taken at various levels in the Limouzat mine in the Bois-Noirs mountains. It has been possible to show that the uranium dates from 265 M.Y. and that a rearrangement occurred 65 M.Y. ago. A {gamma}-spectrometer study which was originally intended to show the existence of the lack of balance in the radon circulation, has made it possible to show that the {gamma} spectra recorded on various samples could be erroneous. We observed in effect that the presence of lead, iron, etc., had a strong influence on the {gamma} spectrum of the radium family, whereas all research workers have considered that concentrations in the uranium ore were negligible and had no significant effect on the study of the {gamma} spectra of the samples. It is obvious that an interesting study has to be undertaken on the screen effects of the different cations existing in the ores. We believe that it is possible to show the presence of certain elements directly by {gamma}-spectrometry. The ages measured with the mass spectrometer present two types of disagreement but these have been explained by considering that there occurred a first arrival of lead followed by a rearrangement and, at certain points, a second arrival at this date. Finally, the deposit studied undergoes a circulation of uranium and of radon. (author) [French] La presente etude a porte sur 7 prelevements differents effectues a divers niveaux de la mine du Limouzat, massif des Bois-Noirs. Elle a permis de mettre en evidence une premiere venue d'uranium il y a 265 M.A., suivie d'un remaniements il y a 65 M.A. Une etude au spectrometre {gamma} destinee, a l'origine, a prouver les desequilibres dus aux circulations de radon a permis de montrer que les spectres {gamma} enregistres sur divers echantillons pouvaient etre entaches d'erreurs. Nous nous sommes apercus en effet que la presence de plomb, de fer..., avait une forte influence sur le spectre {gamma} de la famille du radium

  19. Contribution to the study of plasmatic fibrinogen and serum albumin: effects of irradiation; Contribution a l'etude du fibrinogene et de la serum-albumine plasmatiques - effets de l'irradiation

    Energy Technology Data Exchange (ETDEWEB)

    Suscillon, M. [Commissariat a l' Energie Atomique, Centre d' Etudes Nucleaires de Grenoble, 38 (France)

    1967-07-01

    The author studies the modifications of properties and structure of serum albumin and fibrinogen solution when subjected to radiation of low energy (X rays). On the other hand, two original techniques are exposed: 1. Amperometric determination of fibrin stabilizing factor or factor XIII of hemostasis. 2. Spectrophotometric study of fibrin formation kinetics. Then showing off and quantitative determination of platelets fibrinogen is exposed. (author) [French] L'auteur etudie les modifications des proprietes et de la structure des molecules de serum-albumine et de fibrinogene en solution soumise a un flux de RX de basse energie. D'autre part deux techniques originales sont exposees : 1. Dosage amperometrique du facteur stabilisant de la fibrine. 2. Etude spectrophotometrique de la cinetique de la fibro-formation. Enfin une mise en evidence et un dosage du fibrinogene plaquettaire sont presentes. (auteur)

  20. Study of fission product {gamma} spectra in the band 2-500 keV; Etude du spectre {gamma} des produits de fission dans la bande 0-500 keV

    Energy Technology Data Exchange (ETDEWEB)

    Rousseau, A. [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1959-07-01

    In the study of the {gamma} spectrum of uranium fission products, particular attention has been given in this note to the part of the spectrum ranging between 0 and 500 keV after a given pile operating programme and the evolution of this spectrum with time after a pile shutdown has been followed. The study be related to the fission products which appear in the pile as a whole or on those produced in a uranium sample assumed to have been placed in the pile. The latter case has been envisaged here. The spectrum determination is based partly on theory and partly on experiment. The pile operating conditions are different in the two cases, which widens the range of validity of the spectra traced here. (author) [French] Dans l'etude du spectre {gamma} des produits de fission de l'uranium, on s'est plus particulierement interesse dans la presente note a determiner la partie du spectre qui s'etend entre 0 et 500 keV, au bout d'un fonctionnement donne de pile, et a suivre l'evolution de ce spectre dans le temps apres un arret de pile. L'etude peut porter sur les produits de fission apparus dans toute la pile ou sur ceux apparus dans un echantillon d'uranium suppose place en pile. C'est ce dernier cas que nous avons envisage. La determination du spectre s'appuie sur une partie theorique et sur une partie experimentale. Les fonctionnements de pile choisis sont differents dans les deux cas, ce qui permet d'etendre la gamme de validite des spectres traces ici. (auteur)

  1. Study of certain random variations in the measurement of low level radioactivities by means of electric circuits (1963); Etude, au moyen de circuits electroniques, de certaines fluctuations aleatoires dans les mesures de radioactivite a bas niveau (1963)

    Energy Technology Data Exchange (ETDEWEB)

    Moghimi, D [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1963-03-15

    The aim of this work is to find a control method which ensures that there is really a statistical distribution of pulses during the measurement of very low activities. The use of a method based on the distribution of time intervals is examined first, as well as the graphical representation to which it leads. The second method is a study of the distribution of the number of pulses in a given time interval. It makes it possible to use two tests for verifying Gauss's law: Henry's graphical test and the {chi}{sup 2} mathematical test. The electronic devices necessary for these tests have been built; they have made it possible to study the fluctuations in on installation for measuring the natural activity of carbon. (author) [French] Le but de ce travail est de rechercher des methodes de controle qui permettent de s'assurer qu'au cours de mesures de tres faibles activites, on a bien une distribution statistique des impulsions. L'utilisation d'une premiere methode basee sur la distribution des intervalles de temps est d'abord examinee, ainsi que la representation graphique a laquelle elle conduit. La deuxieme methode est une etude de la repartition du nombre d'impulsions pendant un temps determine. Elle permet l'utilisation de 2 tests de verification de la loi de Gauss: le test graphique de Henry et le test mathematique de {chi}{sup 2}. Les dispositifs electroniques necessaires pour l'utilisation de ces tests ont ete realises.; ils ont ensuite permis l'etude des fluctuations dans une installation de mesure d'activite naturelle du carbone. (auteur)

  2. X-spectrographic method for plutonium detection. Application to contamination measurements in humans; Etude d'une methode de detection du plutonium par spectrographie X. Application a la mesure des contaminations sur l'homme

    Energy Technology Data Exchange (ETDEWEB)

    Trouble, Michel [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1967-07-01

    After reviewing the radio-toxicology of plutonium 239 and conventional detection methods using its {alpha}-radiation, the author considers the measurement of the X emission spectrum of plutonium 239 using a proportional counter filled with argon under pressure. This preliminary work leads to the third part of this research involving the detailed study of the possibilities of applying thin alkali halide crystal scintillators to the detection of soft plutonium X-rays; there follows a systematic study of all the parameters liable to render the detection as sensitive as possible: movement due to the photomultiplier itself and its accessory electronic equipment, nature and size of the crystal scintillator as well as its mode of preparation, shielding against external parasitic radiation. Examples of some applications to the measurement of contamination in humans give an idea of the sensitivity of this method. (author) [French] Apres un apercu de la radiotoxicologie du plutonium 239 et des methodes classiques de detection par son rayonnement {alpha}, on etudie le spectre d'emission X du plutonium 239 avec un compteur proportionnel rempli avec de l'argon sous pression. Ce travail preliminaire permet d'aborder la troisieme partie de cette etude dans laquelle nous examinons d'une fagon approfondie les possibilites d'application des cristaux scintillateurs minces d'halogenure alcalin a la detection du rayonnement X mou du plutonium; suit une etude systematique de tous les parametres susceptibles de rendre la detection aussi sensible que possible: mouvement propre du photomultiplicateur et de l'electronique associee, nature et dimensions du cristal scintillateur ainsi que son mode de fabrication, blindage contre les rayonnements parasites exterieurs. Quelques applications a la mesure des contaminations sur l'homme permettent d'apprecier la sensibilite de cette methode. (auteur)

  3. Processing of data issued from {gamma} spectrometer. Application to the study of decay schemes; Traitement des informations issues d'un spectrometre {gamma}. Application a l'etude de schemas de desintegration

    Energy Technology Data Exchange (ETDEWEB)

    Boulanger, J P; Legrand, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1967-07-01

    The main purpose of the following report is the study of a generation method of {gamma} spectra corresponding to any energy, from a library of some basic spectra. Then we point out how to establish the decay scheme of a radio-nuclide, in using an accurate analysis of full-energy peaks which appear in its complex spectrum, followed by a generation of plain spectra corresponding to the energies of the different transitions, and ending with a least-squares fitting procedure of the complex spectrum. The accuracy of the process is examined comparing the calculated spectra to the ones issued from two kinds of spectrometers (Na I(Tl) and Ge(Li)). The method is then applied to the study of {sup 134}Cs and {sup 95}Zr - {sup 95}Nb. (authors) [French] Le present rapport a pour principal objet l'etude d'une methode de generation de spectres {gamma} correspondant a n'importe quelle energie, a partir d'une bibliotheque de quelques spectres de reference. On montre ensuite comment on peut etablir le schema de desintegration d'un radionucleide, a l'aide d'une analyse precise des pics d'absorption totale apparaissant dans son spectre complexe, suivie d'une generation des spectres simples correspondant aux energies des diverses transitions, et en terminant par une decomposition du spectre complexe par la methode des moindres carres. On examine la validite du procede en comparant les spectres calcules a ceux obtenus avec deux types de detecteurs (scintillateurs et semi-conducteurs). On applique alors la methode a l'etude du {sup 134}Cs et du {sup 95}Zr - {sup 95}Nb. (auteurs)

  4. Study of fission product {gamma} spectra in the band 2-500 keV; Etude du spectre {gamma} des produits de fission dans la bande 0-500 keV

    Energy Technology Data Exchange (ETDEWEB)

    Rousseau, A [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1959-07-01

    In the study of the {gamma} spectrum of uranium fission products, particular attention has been given in this note to the part of the spectrum ranging between 0 and 500 keV after a given pile operating programme and the evolution of this spectrum with time after a pile shutdown has been followed. The study be related to the fission products which appear in the pile as a whole or on those produced in a uranium sample assumed to have been placed in the pile. The latter case has been envisaged here. The spectrum determination is based partly on theory and partly on experiment. The pile operating conditions are different in the two cases, which widens the range of validity of the spectra traced here. (author) [French] Dans l'etude du spectre {gamma} des produits de fission de l'uranium, on s'est plus particulierement interesse dans la presente note a determiner la partie du spectre qui s'etend entre 0 et 500 keV, au bout d'un fonctionnement donne de pile, et a suivre l'evolution de ce spectre dans le temps apres un arret de pile. L'etude peut porter sur les produits de fission apparus dans toute la pile ou sur ceux apparus dans un echantillon d'uranium suppose place en pile. C'est ce dernier cas que nous avons envisage. La determination du spectre s'appuie sur une partie theorique et sur une partie experimentale. Les fonctionnements de pile choisis sont differents dans les deux cas, ce qui permet d'etendre la gamme de validite des spectres traces ici. (auteur)

  5. Experimental study of an ion cyclotron instability in a magnetic well confined plasma; Etude experimentale d'une instabilite cyclotronique ionique dans un plasma confine dans un puits magnetique

    Energy Technology Data Exchange (ETDEWEB)

    Brossier, P [Commissariat a l' Energie Atomique, Fontenay-Aux-Roses (France). Centre d' Etudes Nucleaires

    1969-07-01

    This report is a contribution to the study of microinstabilities in macroscopically stable plasmas, in the low-{beta} limit. Ion cyclotron instabilities, with k{sub ||} = 0, have been numerically studied in detail; the computation of the density thresholds and growth rates of the different harmonics showed the relative role played by the following energy sources: density gradient, perpendicular distribution function and cold plasma component. This theoretical model has been compared with the results of a detailed study (density thresholds, wave structure, frequency spectrum, wavelengths, growth rate, amplitude of the electric field) of the instability observed in the DECA II device. This comparison gave a good agreement which shows the destabilising role played by the cold plasma component on a hot plasma with a loss cone distribution function. (author) [French] Ce rapport est une contribution a l'etude des microinstabilites dans les plasmas macroscopiquement stables, dans la limite des {beta} << 1. Les instabilites cyclotroniques ioniques, a k{sub ||} = 0, ont ete etudiees numeriquement en detail; le calcul des seuils de densite et taux de croissance des differents harmoniques a permis de preciser l'importance relative des facteurs destabilisants suivants: gradient de densite, fonction de distribution perpendiculaire, presence de plasma froid. Ce modele theorique a ete confronte avec les resultats d'une etude detaillee (seuils de densite, structure de l'onde, spectres de frequence, longueurs d'onde, taux de croissance, amplitude du champ electrique) de l'instabilite observee dans l'experience DECA II, Cette confrontation aboutit a un accord satisfaisant qui montre le role destabilisant joue par le plasma froid sur un plasma chaud presentant une distribution de cone de pertes. (auteur)

  6. Study and realization of an electron linear accelerator. Dynamics of accelerated electrons; Etude et realisation d'un accelerateur lineaire d'electrons. Dynamique des electrons acceleres

    Energy Technology Data Exchange (ETDEWEB)

    Bernard, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1967-04-01

    chacune de ces relations de dispersion. La deuxieme partie de la these relative a l'etude theorique de la dynamique des electrons dans le guide permet de deduire les parametres du faisceau: etalement en phase, energie, etalement en energie des electrons et caracteristiques en charge theoriques W{sub S} = f (I{sub c}). Les resultats experimentaux relatifs aux premiers essais de l'accelerateur sont donnes et compares aux previsions theoriques. (auteur)

  7. Preliminary studies leading to a conceptual design of a 1000 MWe fast neutron reactor; Etudes preliminaires conduisant a un concept de reacteur a neutrons rapides de 1000 MWe

    Energy Technology Data Exchange (ETDEWEB)

    Vendryes, G.; Zaleski, C.P. [Association Euratom-CEA Cadarache (France). Centre d' Etudes Nucleaires

    1964-07-01

    This report presents the results of studies which seemed important to undertake in connexion with the development of fast neutron reactors. - It points out the advantage of high internal breeding ratios ({approx}1, 1) which are necessary in order to get a small change in time both in power distribution and reactivity (less: than 0.005 {delta}k/k in 18 months). - It shows how to achieve this goal, when simultaneously power distribution flattening is obtained. These results in a higher mean specific power (which is an economic gain) and therefore in a smaller doubling time (about 10 years). - It attempts to find criteria concerning the specific power that should be used in future reactor designs -It presents a conceptional design of a 1000 MWe fast neutron reactor, for the realisation of which no technological impossibility appears. - It shows that the dynamic behaviour seems satisfactory despite a positive total isothermal sodium coefficient. - It tries to predict the development of fast reactors within the future total nuclear program. It does not appear that fissile materials supply problems should in France slow down the development of fast neutron reactors, which will be essentially tied up to its economical ability to produce cheap electric power. (authors) [French] Ce rapport presente les etudes qu'il nous a paru important d'aborder dans le cadre du developpement des reacteurs a neutrons rapides. - Il met en evidence l'interet des taux de regeneration internes eleves ({approx}1, 1) pour obtenir une bonne evolution dans le temps de la distribution de puissance et de la reactivite (moins de 0,005 {delta}k/k pour 18 mois). - Il montre la possibilite d'y parvenir tout en applatissant la distribution des fissions, ce qui se traduit par une puissance specifique moyenne plus elevee (gain economique), et donc un temps de doublement plus faible de l'ordte de 10 ans - Il tente de definir un optimum de la puissance specifique valable pour les

  8. Study of deformation mechanisms of zinc bicrystals by thermal cycling (1963); Etude des mecanismes de deformation par cyclage thermique de bicristaux de zinc (1963)

    Energy Technology Data Exchange (ETDEWEB)

    Mondon, J [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1963-06-15

    'ordre de 10{sup -4} a 10{sup -3} quand le cristal est plastiquement 'dur'. L'etude micrographique montre que la migration du joint accompagne le cisaillement intergranulaire et que le cyclage produit une forte polygonisation dans les grains, confirmant le fait que le joint exerce toujours des contraintes et qu'il se produit un fluage dans le volume des grains. La discussion des resultats montre que le fluage primaire du grain 'dur' d'un bicristal rend la deformation par cyclage irreversible et permet un allongement a chaque cycle si ce grain possede un coefficient de dilatation plus faible que l'autre. (auteur)

  9. Comparative study of the creep behaviour of single crystals and polycrystals of alpha uranium; Etude comparee du comportement au fluage de l'uranium alpha mono et polycristallin

    Energy Technology Data Exchange (ETDEWEB)

    Andre, J P [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-03-01

    In the first chapter, one describes the creep machine developed to study the deformation of uranium at high temperature in vacuum with a continuous recording. The second chapter presents the results concerning the polycrystals of uranium. The application of the DORN method gives an activation energy for creep of 42 {+-} 2 Kc, above 550 Celsius degrees, equal to the activation energy for self-diffusion. The study of the variation of the creep rate with the applied stress and the metallographic observations of the deformation induced polygonization allow to conclude that the deformation is controlled by climb of dislocations. In the third chapter, the deformation above 550 Celsius degrees of single crystals of uranium (obtained by {beta} {yields} {alpha} change) is studied. The major deformation mode is slip. The preexisting polygonization of these single crystals is very stable and the disorientation between adjacent sub-grains increases with the deformation. The activation energy for creep is higher than that for polycrystals. These results show the influence of the polygonization due to the {beta} {yields} {alpha} change on the creep behaviour of {alpha} uranium. (authors) [French] Dans le premier chapitre, on decrit la machine de fluage sous vide a enregistrement continu, mise au point pour etudier le phenomene. Le deuxieme chapitre presente les resultats relatifs aux polycristaux. L'utilisation de la methode de DORN a permis de constater que, au-dessus de 550 degres Celsius, l'energie d'activation pour le fluage avait une valeur constante egale a 42 {+-} 2 Kc, voisine de la chaleur d'autodiffusion. L'etude de l'influence de la contrainte appliquee sur la vitesse de fluage et l'observation micrographique de la polygonisation developpee au cours de la deformation permettent de conclure que le phenomene est controle par la montee des dislocations. Dans le troisieme chapitre, on etudie le comportement au fluage au-dessus de 550 C des monocristaux obtenus par

  10. The use of tracers in the study of the ionic permeability of the nerve; Utilisation des indicateurs nucleaires dans l'etude de la permeabilite ionique du nerf

    Energy Technology Data Exchange (ETDEWEB)

    Guinnebault, M [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1961-07-01

    The use of the radioactive tracers {sup 24}Na and {sup 42}K, and the electrophysiological fine study carried out on the plant Cephalopods nervous cells have made it possible, during ten years, to study the relationships between the electrical phenomena observed during the propagation of the nervous impulse and the ionic movements which occur at the cell membrane between the intra- and extra-cellular media. In the state of rest, the nerve fibres present a certain permeability towards sodium and potassium, a permeability which allows the renewal, from the extra-cellular medium, of the cations contained in the cytoplasm. At the moment of the passage of the nervous impulse, it is possible to demonstrate a temporary increase in the permeability towards the sodium which causes the entry of Na{sup +} ions into the nerve fibre, whilst, a few milliseconds later, the increase in the potassium permeability causes the departure of an equivalent quantity of K{sup +} ions. A recovery phase follows the passage of the nervous impulse, during which the original ionic conditions are re-established. If the potassium movements can be considered as passive, the expulsion of Na{sup +} requires, on the part of the cell, the use of a part of the metabolic energy. (author) [French] L'utilisation des indicateurs radioactifs {sup 24}Na et {sup 42}K, et l'etude electrophysiologique fine realisee sur des cellules nerveuses geantes de Cephalopodes a permis, depuis une dizaine d'annees, d'etudier les rapports entre les phenomenes electriques observes lors de la propagation de l'influx nerveux et les mouvements ioniques qui s'effectuent au niveau de la membrane cellulaire entre milieux intracellulaire et extracellulaire. A l'etat de repos, les fibres nerveuses possedent pour le sodium et le potassium, une permeabilite qui permet le renouvellement, a partir du milieu extracellulaire des cations contenus dans le cytoplasme. Au moment du passage de l'influx nerveux, on peut mettre en evidence une

  11. Crystallographic study and self irradiation damage on plutonium at low temperature; Etude cristallographique et effets de l'auto-irradiation sur le plutonium a basse temperature

    Energy Technology Data Exchange (ETDEWEB)

    Solente, P [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1965-05-01

    We have studied the variation of the parameters of {alpha} plutonium and aluminium stabilised {delta} alloys at low temperature, in order to verify the existence of an antiferromagnetic transition at low temperature. The effects of {alpha} particles on the length of a polycrystal of {alpha} plutonium at 4,2 deg. K are also presented at 18 deg. K a plutonium shows no crystallographic change from its structure at room temperature. The thermal expansion coefficients along the 3 axis seem to be positive at this temperature. Therefore a magnetic contribution on thermal expansion coefficients must be small. A dilatation anomaly of {delta}Pu has been observed at 100 deg. K, together with an anomaly of the diffraction lines intensity. No sur-structure line has been observed at 20 deg. K. The length of {alpha} plutonium Increases with time at a rate of about 5 x 10{sup -6} per hour when held in liquid helium. This effect is attributed to the creation of Frenkel pairs. (author) [French] On presente une etude cristallographique a basse temperature du plutonium {alpha} et stabilise {delta} par des additions d'aluminium en vue de verifier l'existence d'une transformation antiferromagnetique a basse temperature. L'effet des particules {alpha} a 4,2 deg. K sur la longueur d'un polycristal de plutonium {alpha} a egalement ete etudie. Il a ete determine que le plutonium {alpha} ne mange pas de phase allotropique Jusqu'a 18 deg. K, les coefficients de dilatation des trois axes de la maille semblent rester positifs. Une eventuelle contribution magnetique sur les coefficients de dilatation devrait donc etre faible. Une legere anomalie de dilatation de Pu {delta} a ete observee a 100 deg. K ainsi qu'une anomalie d'intensite des raies de diffraction. Aucune raie de surstructure n'a ete observee. Le plutonium {alpha} s'allonge lorsqu'il est plonge dans l'helium liquide d'un taux de l'ordre de 5 x 10{sup -6}/heure. Cet effet a ete attribuee a la creation de paires de Frenkel. (auteur)

  12. Contribution to the crystallographic study of the uranium-oxygenated system; Contribution a l'etude cristallographique du systeme uranium-oxygene

    Energy Technology Data Exchange (ETDEWEB)

    Perio, P [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1955-04-15

    Three uranium oxides, UO{sub 2}, U{sub 3}O{sub 8} and UO{sub 3} are known since a long time. The existence of a fourth, U{sub 2}O{sub 5}, is discussed. The mechanisms of decomposition between UO{sub 3} and U{sub 3}O{sub 8} have even some shadow zones. The aim of this report is the study of the phase relations in an uranium - oxygen system, from the metal until UO{sub 3}. We considered, on the one hand, the equilibrium relations, what should result in a diagram of phases in pressures and temperatures, on the other hand, the transformations bringing one oxide to the other, often by a continuous way and through intermediate of metastable phases. The introduction of the temperature and the consideration of the kinetics effects have permitted to raise the ambiguities. We adopted, to facilitate the presentation of the results, a partition a few arbitrary but convenient, in three chapters,: I - experimental Techniques II - Crystallographic species between U and UO{sub 3}. III - Kinetic of oxidisation of UO{sub 2}. (M.B.) [French] Trois oxydes d'uranium, UO{sub 2}, U{sub 3}O{sub 8} et UO{sub 3} sont connus depuis longtemps. L'existence d'un quatrieme, U{sub 2}O{sub 5}, est en suspend. Les mecanismes de decomposition entre UO{sub 3} et U{sub 3}O{sub 8} possedent encore quelques zones d mbres. Le but propose dans ce memoire est l'etude des relations de phase dans le systeme uranium - oxygene, du metal jusqu'a UO{sub 3}. Nous avons ete amene a considerer, d'une part, les relations a l'equilibre, ce qui devrait se traduire par un diagramme de phases en pressions et temperatures, d'autre part, les transformations amenant, souvent d'une facon continue et par l'intermediaire de phases metastables, d'un oxyde a l'autre. L'introduction de la temperature et la consideration des effets de cinetique ont le plus souvent permis de lever les ambiguites rencontrees. Nous avons adopte, pour faciliter la presentation des resultats, une division un peu arbitraire mais commode, en trois

  13. Etude de la performance des radars hautes-frequences CODAR et WERA pour la mesure des courants marins en presence partielle de glace de mer

    Science.gov (United States)

    Kamli, Emna

    Les radars hautes-frequences (RHF) mesurent les courants marins de surface avec une portee pouvant atteindre 200 kilometres et une resolution de l'ordre du kilometre. Cette etude a pour but de caracteriser la performance des RHF, en terme de couverture spatiale, pour la mesure des courants de surface en presence partielle de glace de mer. Pour ce faire, les mesures des courants de deux radars de type CODAR sur la rive sud de l'estuaire maritime du Saint-Laurent, et d'un radar de type WERA sur la rive nord, prises pendant l'hiver 2013, ont ete utilisees. Dans un premier temps, l'aire moyenne journaliere de la zone ou les courants sont mesures par chaque radar a ete comparee a l'energie des vagues de Bragg calculee a partir des donnees brutes d'acceleration fournies par une bouee mouillee dans la zone couverte par les radars. La couverture des CODARs est dependante de la densite d'energie de Bragg, alors que la couverture du WERA y est pratiquement insensible. Un modele de fetch appele GENER a ete force par la vitesse du vent predite par le modele GEM d'Environnement Canada pour estimer la hauteur significative ainsi que la periode modale des vagues. A partir de ces parametres, la densite d'energie des vagues de Bragg a ete evaluee pendant l'hiver a l'aide du spectre theorique de Bretschneider. Ces resultats permettent d'etablir la couverture normale de chaque radar en absence de glace de mer. La concentration de glace de mer, predite par le systeme canadien operationnel de prevision glace-ocean, a ete moyennee sur les differents fetchs du vent selon la direction moyenne journaliere des vagues predites par GENER. Dans un deuxieme temps, la relation entre le ratio des couvertures journalieres obtenues pendant l'hiver 2013 et des couvertures normales de chaque radar d'une part, et la concentration moyenne journaliere de glace de mer d'autre part, a ete etablie. Le ratio des couvertures decroit avec l'augmentation de la concentration de glace de mer pour les deux types

  14. On the interactions between carbon monoxide and transition metals; Contribution a l'etude des interractions de l'oxyde de carbone et des metaux de transition

    Energy Technology Data Exchange (ETDEWEB)

    Degras, D E [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1966-12-01

    The sticking of carbon monoxide on surface atoms of transition metals is a collective phenomenon: according to the adsorption process period which is considered, this phenomenon may be formally described either by the Elovich equation or essentially from a steric point of view. The process rate depends upon the nature of the metal, the carbon monoxide pressure the temperature and the population densities of the induced and fundamental energy levels of the gas-solid bond. At least one of these induced levels tends to disappear with increasing time. For a localised adsorption and taking into account the surface Rayleigh waves, the analysis of the surface entropy yields the so-called iso-kinetic temperature for thermal desorption. This temperature is correlated with the cohesive energy of the metal surface atoms. Finally, it is shown that the interactions of a low energy electron bean with adsorbed molecules - reflection and energy exchange, desorption, ionization or dissociative ionization are strongly dependent on the energy levels of the gas-solid bond and the relative populations of these levels. (author) [French] La capture des molecules d'oxyde de carbone par les atomes de surface des metaux de transition est un phenomene collectif: il peut etre decrit formellernent soit par l'equation d'Elovich, soit a partir de considerations purement steriques suivant la periode envisagee dans l'evolution du processus d'adsorption. Cette evolution est determinee par la nature du metal, la pression d'oxyde de carbone, la temperature et la densite des populations des niveaux fondamental et induits de la liaison. L'un au moins de ceux-ci tend a disparaitre avec le temps. L' etude de l'entropie du complexe de surface a partir des ondes de Rayleigh en adsorption localisee permet de retrouver theoriquernent la temperature dite isocinetique dans la dissociation thermique de ce complexe. Cette temperature depend de la cohesion des atomes rnetalliques de surface. Enfin l'interaction d

  15. Study of betatron oscillations in a constant field and alternating gradient accelerator; Etude des oscillations betatron dans l'accelerateur a champ fixe et a gradient alterne

    Energy Technology Data Exchange (ETDEWEB)

    Lauzanne, C [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1963-07-01

    The conditions for the stability of a constant energy particle beam circulating in the magnetic field of the F.F.A.G. accelerator are studied. By a mathematical study it is possible to derive the equations for the equilibrium orbit and for the low amplitude oscillations, and the expressions for the amplitude stability limits of the beam. For this, approximation methods are used, in particular the linearization of the differential equations of the movement, and the method of gradual approximation. Numerical investigations carried out with the help of the IBM 7090 computer make it possible to judge the precision of the results given by the theory. A systematic variation of the parameters makes it possible to understand more clearly the mechanism of the amplitude variations of the trajectories. Finally, for the radial sector model, the possibility of introducing zones free from the magnetic field is considered. The case of short straight sections, respecting the field periodicity, and of that of long straight sections creating super-periods are considered. For the two cases are given solutions which should lead to a practical machine. (author) [French] On etudie les conditions de stabilite d'un faisceau de particules circulant a energie constante dans le champ magnetique de l'accelerateur F.F.A.G. Une etude mathematique permet d'etablir les equations de l'orbite d'equilibre et des oscillations de faible amplitude, les expressions des limites de stabilite en amplitude du faisceau. On emploie a cet effet des methodes d'approximation, essentiellement la linearisation des equations differentielles du mouvement et la methode de l'approximation douce. Des investigations numeriques effectuees a l'aide de la calculatrice IBM 7090 permettent d'apprecier l'exactitude des resultats fournis par la theorie. Une variation systematique des parametres permet de mieux comprendre le mecanisme des variations d'amplitude des trajectoires. On etudie enfin, pour le modele a secteur radial

  16. Contribution to the study of the intermediate fluorides of uranium; Contribution a l'etude des fluorures intermediaires d'uranium

    Energy Technology Data Exchange (ETDEWEB)

    Nguyen-Hoang, Nghi [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1961-10-15

    The reaction of gaseous uranium hexafluoride with solid uranium tetrafluoride has been studied between 20 and 300 deg. C. The intermediate fluorides resulting from this reaction were prepared and then identified by chemical analysis and Debye-Scherrer diagrams. Their magnetic susceptibility and action on various common solvents were determined. The kinetic study was carried out up to 45 deg. C at a constant gas pressure equal to 17,7 mm of mercury. The experimental results indicate that the reaction, limited by the diffusion process of ionic reactants, obeys the kinetic law: L (1 - C) = k{radical}t. The observed rate constant K and the diffusion coefficient D vary with the temperature according to the expressions: K min{sup -1/2} = - (1,88 {+-} 0,22) 10{sup 8} exp[-(14100 {+-} 1400 cal/mole)/(RT)]; D cm{sup 2} sec{sup -1} = (1,15 {+-} 0,51) 10{sup 6} exp[-(30200 {+-} 5700 cal/mole)/(RT)]. (author) [French] La reaction de l'hexafluorure d'uranium gazeux sur le tetrafluorure d'uranium solide a ete etudiee entre 20 et 300 deg. C. Les fluorures intermediaires resultant de cette reaction ont ete prepares, puis identifies par analyses chimiques et par diagrammes Debye-Scherrer. Leur susceptibilite magnetique et leur action sur divers solvants usuels ont ete determinees. L'etude cinetique a ete entreprise jusqu'a 45 deg. C, sous une pression de gaz constante et egale a 17,7 mm de mercure. Les resultats experimentaux obtenus indiquent que la reaction, limitee par le processus de diffusion de reactifs ioniques, suit la loi cinetique: L (1 - C) = k{radical}t. La constante de vitesse observee K et le coefficient de diffusion D varient avec la temperature selon les expressions: K min{sup -1/2} = - (1,88 {+-} 0,22) 10{sup 8} exp[-(14100 {+-} 1400 cal/mole)/(RT)]; D cm{sup 2} sec{sup -1} = (1,15 {+-} 0,51) 10{sup 6} exp[-(30200 {+-} 5700 cal/mole)/(RT)]. (auteur)

  17. Study of fast neutron scattering. The displacement cross-section (1962); Etude de la diffusion des neutrons rapides. Section efficace de deplacement (1962)

    Energy Technology Data Exchange (ETDEWEB)

    Millot, J P [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1962-07-01

    We propose a method for calculating the biological efficiency of fast neutrons emitted by in-pile fission sources. This method justifies the empirical theory of Albert and Welton. In making simple assumptions concerning the cross-sections, we have supposed that the propagation can ben reduced to a mono-kinetic problem. A system of orthonormal functions is then set up making it possible to calculate the flux leaving a planar source. This method generalises the results obtained by Platzek to the case where the elastic cross-sections are not isotropic, and make it possible in particular to define a displacement cross-section: extension of the diffusion coefficient. This method can be generalised to the case of neutron diffraction as a function of time, and to the study of slowing-down. Numerical results are given in an appendix for the following: H{sub 2}O, D{sub 2}O, Fe, Be, Pb, CH, CH{sub 2}. These cross-sections have been verified experimentally in water and in graphite for neutrons of 2.5 and 14 MeV using a SAMES accelerator and a 2 MeV Van De Graaff. (author) [French] Nous proposons une methode permettant de calculer l'efficacite biologique des neutrons rapides issus des sources de fission dans la protection d'une pile. Cette methode justifie la theorie empirique d'Albert et Welton. En faisant des hypotheses simples sur les sections efficaces, nous avons suppose que la propagation pouvait etre ramenee a un probleme monocinetique. Nous construisons alors un systeme de fonctions orthonormales qui permet de calculer le flux issu d'une source plane. Cette methode generalise les resultats obtenus par Platzek au cas ou les sections efficaces elastiques ne sont pas isotropes et en particulier permet de definir une section efficace de deplacement: extension du coefficient de diffusion. Cette methode peut etre generalisee a la diffusion des neutrons en fonction du temps et a l'etude du ralentissement. Les resultats numeriques sont donnes en annexe pour les corps. H{sub 2

  18. Data processing in gamma spectrometry. Application to the decay schemes study; Traitement des informations en spectrometrie gamma application a l'etude de schemas de desintegration

    Energy Technology Data Exchange (ETDEWEB)

    Boulanger, J.P. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires, departement d' electronique generale, service d' instrumentation nucleaire

    1968-06-01

    The purpose of this thesis is the processing of the data issued from a gamma spectrometer, and its applications to the decay schemes study. The mathematical analysis of the full energy peaks, in connection with the very good resolution of semi-conductor detectors, leads to a very accurate determination of the energies. The resolution of complex spectra by the least squares method, completed by a spectra generating process, allows the calculation of branching ratios. Then, the handling of the two dimensional experiments permits the coincidence exam. For each of these methods, the calculation principle, then the systematics tests realized in order to prove their validity and to determine their application ranges as well as some experimental results appropriate to illustrate their possibilities, are presented. The energies of some nuclides, frequently used as standards have been thus measured and the decay schemes of {sup 134}Cs and {sup 110m}Ag determined precisely. (author) [French] Cette these est consacree aux methodes de traitement des informations issues d'un spectrometre {gamma}, et a leur application a l'etude des schemas de desintegration: l'analyse mathematique des pics d'absorption totale, conjuguee avec l'excellent pouvoir de resolution des detecteurs semi-conducteurs, conduit a une determination tres precise des energies. La decomposition des spectres complexes par la methode des moindres carres, completee par un procede de generation de spectres, autorise le calcul des rapports de branchement. Enfin le depouillement des experiences biparametriques permet l'examen des coincidences. Pour chacune de ces methodes, on expose le principe des calculs et les essais systematiques effectues afin d'eprouver leur validite et de definir leurs domaines d'application, ainsi que quelques resultats experimentaux propres a illustrer leurs possibilites. Les energies de quelques isotopes utilises couramment comme etalons ont ainsi ete

  19. Preliminary studies leading to a conceptual design of a 1000 MWe fast neutron reactor; Etudes preliminaires conduisant a un concept de reacteur a neutrons rapides de 1000 MWe

    Energy Technology Data Exchange (ETDEWEB)

    Vendryes, G; Zaleski, C P [Association Euratom-CEA Cadarache (France). Centre d' Etudes Nucleaires

    1964-07-01

    This report presents the results of studies which seemed important to undertake in connexion with the development of fast neutron reactors. - It points out the advantage of high internal breeding ratios ({approx}1, 1) which are necessary in order to get a small change in time both in power distribution and reactivity (less: than 0.005 {delta}k/k in 18 months). - It shows how to achieve this goal, when simultaneously power distribution flattening is obtained. These results in a higher mean specific power (which is an economic gain) and therefore in a smaller doubling time (about 10 years). - It attempts to find criteria concerning the specific power that should be used in future reactor designs -It presents a conceptional design of a 1000 MWe fast neutron reactor, for the realisation of which no technological impossibility appears. - It shows that the dynamic behaviour seems satisfactory despite a positive total isothermal sodium coefficient. - It tries to predict the development of fast reactors within the future total nuclear program. It does not appear that fissile materials supply problems should in France slow down the development of fast neutron reactors, which will be essentially tied up to its economical ability to produce cheap electric power. (authors) [French] Ce rapport presente les etudes qu'il nous a paru important d'aborder dans le cadre du developpement des reacteurs a neutrons rapides. - Il met en evidence l'interet des taux de regeneration internes eleves ({approx}1, 1) pour obtenir une bonne evolution dans le temps de la distribution de puissance et de la reactivite (moins de 0,005 {delta}k/k pour 18 mois). - Il montre la possibilite d'y parvenir tout en applatissant la distribution des fissions, ce qui se traduit par une puissance specifique moyenne plus elevee (gain economique), et donc un temps de doublement plus faible de l'ordte de 10 ans - Il tente de definir un optimum de la puissance specifique valable pour les projets de reacteurs futurs

  20. Some magnetic resonance properties of solutions of sodium in liquid ammonia; Contribution a l'etude des solutions de sodium dans l'ammoniac liquide par resonance magnetique

    Energy Technology Data Exchange (ETDEWEB)

    Lambert, C [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1968-02-01

    Dilute solutions of sodium in liquid ammonia are studied by the mean of dynamic polarization techniques, and with the aid of Becker Lindquist and Alder model. Paramagnetic shifts are computed as a function of the 'average spin density', for each of the nuclear spin system. The nuclear contributions to the Overhauser shift are computed in the same way. A theoretical study of the main relaxation processes is carried out for each of the nuclear spin system and for the electronic spin system. The dynamic polarization experiments consist in classical measurement of the Overhauser enhancement for nitrogen, and in direct measurements of nitrogen Knight shift and nuclear contributions to the Overhauser shift by the mean of double irradiation techniques. The results show that, in dilute solutions, the relaxation of nitrogen arises from quadrupole interaction and from hyperfine interaction with unpaired electrons. Both interactions are of the same order of magnitude. Overhauser shift measurements show that the spin density is negative at the proton site, in agreement with Hughes results. (author) [French] Les solutions diluees de sodium dans l'ammoniac sont etudiees au moyen des techniques de la polarisation dynamique, sur la base du modele de Becker Lindquist et Aider. Les deplacements paramagnetiques des raies de resonance nucleaire des differents noyaux sont analyses en faisant appel a la notion de ''densite moyenne de spin'' introduite par l'auteur; et les differentes contributions nucleaires au deplacement d'Overhauser sont calculees en fonction de cette meme grandeur. Une etude theorique de la relaxation de chaque systeme de spin permet d'evaluer l'importance relative des differents mecanismes mis en jeu. Les experiences de polarisation dynamique effectuees au cours de ce travail consistent en mesures classiques de l'effet Overhauser sur l'azote, d'une part, et en la mise en oeuvre de techniques originales pour mesurer le deplacement de Knight de l'azote et les

  1. Contribution to the Chemical and Technological Study of Ammonium Diuranate Precipitation; Contribution a l'etude chimique et technologique de la precipitation de diuranate d'ammonium

    Energy Technology Data Exchange (ETDEWEB)

    Vuillemey, R [Commissariat a l' Energie Atomique. Centre d' Etudes Nucleaires de Saclay, 91 - Gif-sur-Yvette (France)

    1962-07-01

    The present work is designed to study the relationship between the conditions for precipitation by ammonia and the properties of ammonium diuranate obtained either from uranyl nitrate solution or from gaseous uranium hexafluoride. In each case the optimum processes are defined leading on the one hand to uranate which can afterwards be treated in a reduction- fluorination oven to give uranium tetrafluoride, and on the other hand to a uranate suitable for the production of a sinterable uranium oxide. In particular it is shown that the treatment of uranyl nitrate solutions by stoichiometric quantities of ammonia leads to the complete precipitation of the uranium leaving less than 1 mg/litre of uranium in the solution, whereas the treatment of uranium hexafluoride necessitates the use of at least 8 times the stoichiometric quantity. (author) [French] Le present travail a pour objet l'etude des relations entre les conditions de precipitation par l'ammoniaque et les proprietes du diuranate d'ammonium, obtenue soit a partir de nitrate d'uranyle en solution, soit d'hexafluorure d'uranium gazeux. Dans chacun des cas, il est defini les procedes optima conduisant d'une part a un uranate susceptible d'etre traite ulterieurement en four de reduction-fluoruration pour l'obtention de tetrafluorure d'uranium et a un uranate pouvant convenir a la fabrication d'un oxyde d'uranium frittable d'autre part. En particulier, il est mis en evidence que le traitement des solutions de nitrate d'uranyle par des quantites stochiometriques d'ammoniaque entraine une precipitation totale de l'uranium avec moins de 1 mg/litre/U dans les eaux-meres, alors que celui de l'hexafluorure d'uranium necessite au moins huit fois la quantite stochiometrique. La mise au point d'un procede de precipitation en deux temps a l'avantage dans les deux cas de permettre avec le meme appareillage la fabrication de produits differents en faisant varier notamment le rapport des reactifs dans le premier temps. (auteur)

  2. Contribution to the study of light nuclei with polarized deuterons; Contribution a l'etude des noyaux legers au moyen de deutons polarises

    Energy Technology Data Exchange (ETDEWEB)

    Arvieux, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1967-04-15

    We describe roughly the vector and tensor-polarized deuteron source associated with the Saclay fixed energy (22 MeV) cyclotron. This has been used to measure the deuteron asymmetry in d-{alpha} scattering (between 17.7 and 21.4 MeV) and in d-p scattering at 21.7 MeV. Then we develop the formalism of irreducible tensor operators used to describe the polarization of a particle of given spin and we study the helicity formalism used to describe the scattering amplitudes for scattering of deuterons by {alpha} (spin 0) and protons (spin 1/2). We apply the preceding results to the phase shift analysis of scattering cross-sections and: 1) deuteron polarization in d-{alpha} scattering from 10 to 27 MeV from which we obtain indications about the excited states of {sup 6}Li; 2) proton and deuteron polarizations in p-d (or d-p) scattering from 1.5 to 12 MeV so as to get the splitting (due to spin interactions) of P and D waves. (author) [French] On decrit sommairement la source de deutons polarises vectoriellement et tensoriellement associee au cyclotron a energie fixe de Saclay avec laquelle on a mesure l'asymetrie des deutons dans la diffusion d-{alpha} de 17,7 a 21,4 MeV et d-p a 21,7 MeV. Puis or developpe le formalisme des operateurs tensoriels irreductibles utilise pour decrire la polarisation d'une particule de spin quelconque. On etudie ensuite le formalisme de l'helicite dans lequel on etudie la diffusion elastique des deutons diffuses par des particules {alpha} (spin 0) et des protons (spin 1/2). On applique les resultats precedents a l'analyse en dephasages de la section efficace et des polarisations: 1 )des deutons dont la diffusion d-{alpha} de 10 a 27 MeV destinee a donner des indications sur les niveaux excites de {sup 6}Li; 2) des protons et des deutons dans la diffusion p-d de 1,5 a 12 MeV en vue de l'etude de la separation suivant les differentes valeurs du moment total J, des ondes P et D (separation due aux interactions de spin). (auteur)

  3. European Organization for Research and Treatment of Cancer and Groupe d'Etude des Lymphomes de l'Adulte very favorable and favorable, lymphocyte-predominant Hodgkin disease.

    Science.gov (United States)

    Wilder, Richard B; Schlembach, Pamela J; Jones, Dan; Chronowski, Gregory M; Ha, Chul S; Younes, Anas; Hagemeister, Fredrick B; Barista, Ibrahim; Cabanillas, Fernando; Cox, James D

    2002-03-15

    Lymphocyte-predominant Hodgkin disease (LPHD) is rare and has a natural history different from that of classic Hodgkin disease. There is little information in the literature regarding the role of chemotherapy in patients with early-stage LPHD. The objective of this study was to examine recurrence free survival (RFS), overall survival (OS), and patterns of first recurrence in patients with LPHD who were treated with radiotherapy alone or with chemotherapy followed by radiotherapy. From 1963 to 1996, 48 consecutive patients ages 16-49 years (median, 28 years) with Ann Arbor Stage I (n = 30 patients) or Stage II (n = 18 patients), very favorable (VF; n = 5 patients) or favorable (F; n = 43 patients) LPHD, according to the European Organization for Research and Treatment of Cancer and Groupe d'Etude des Lymphomes de l'Adulte (EORTC-GELA) criteria, received radiotherapy alone (n = 37 patients) or received chemotherapy followed by radiotherapy (n = 11 patients). The percentages of patients with VF disease (11% vs. 9% in the radiotherapy group vs. the chemotherapy plus radiotherapy group, respectively) or F disease (89% vs. 91%, respectively) within the two treatment groups were similar (P = 1.00). A median of three cycles of chemotherapy with mechlorethamine, vincristine, procarbazine, and prednisone (MOPP) or with mitoxantrone, vincristine, vinblastine, and prednisone (NOVP) was given initially to six patients and five patients, respectively. A median total radiotherapy dose of 40 grays (Gy) given in daily fractions of 2.0 Gy was delivered to both treatment groups. The median follow-up was 9.3 years, and 98% of patients were observed for > or = 3.0 years. RFS was similar for patients who were treated with radiotherapy alone and patients who were treated with chemotherapy followed by radiotherapy (10-year survival rates: 77% and 68%, respectively; P = 0.89). The OS rate also was similar for the two groups (10-year survival rates: 90% and 100%, respectively; P = 0

  4. Study and development of an optical method for the measurement of convection coefficients; Etude et developpement d'une methode optique pour la mesure du coefficient de convection

    Energy Technology Data Exchange (ETDEWEB)

    Crowther, David J.

    1990-03-06

    a la valeur du coefficient de convection. Sa determination est principalement basee sur l'utilisation des moments temporels d'ordre zero. Les resultats experimentaux obtenus par cette methode, sont compares a ceux donnes par un fluxmetre en regime permanent. L'etude montre que le coefficient de convection n'est pas constant pendant l'experience impulsionnelle, mais passe par un extremum avant de tendre vers une asymptote.

  5. Contribution to the study of {beta} disintegration and of nuclear structure using experiments on certain {beta}-{gamma} cascades: 198{sub Au}, 86{sub Rb}, 170{sub Tm}; Contribution a l'etude de la desintegration beta et a l'etude de la structure nucleaire a l'aide d'experiences sur certaines cascades beta-gamma: 198{sub Au}, 86{sub Rb}, 170{sub Tm}

    Energy Technology Data Exchange (ETDEWEB)

    Lachkar, J. [Commissariat a l' Energie Atomique, Bruyeres-le-Chatel (France). Centre d' Etudes; Paris-11 Univ., fabulte des Sciences 91 - Orsay (France)

    1969-07-01

    {beta}{gamma} directional angular correlations and shapes of inner beta spectra leading to the first excited level of the final nucleus enable one to determine the nuclear matrix elements typical of the {beta} transition. In the three observed first forbidden cases: {sup 170}Tm, {sup 86}Rb, {sup 198}Au, these matrix elements do not confirm the independent shell model theory. Other hypotheses are then suggested and discussed. (author) [French] Les experiences de correlation angulaire {beta}{gamma} et l'etude du spectre {beta} conduisant au premier niveau excite du noyau final permettent de determiner les elements de matrices nucleaires caracteristiques de cette transition. Dans les trois cas etudies (transitions une fois interdites): {sup 170}Tm, {sup 86}Rb, {sup 198}Au, ces elements de matrices ne peuvent etre retrouves a l'aide du modele en couches et a particules independantes. D'autres hypotheses sont alors emises et discutees. (auteur)

  6. Contribution to the study of {beta} disintegration and of nuclear structure using experiments on certain {beta}-{gamma} cascades: 198{sub Au}, 86{sub Rb}, 170{sub Tm}; Contribution a l'etude de la desintegration beta et a l'etude de la structure nucleaire a l'aide d'experiences sur certaines cascades beta-gamma: 198{sub Au}, 86{sub Rb}, 170{sub Tm}

    Energy Technology Data Exchange (ETDEWEB)

    Lachkar, J [Commissariat a l' Energie Atomique, Bruyeres-le-Chatel (France). Centre d' Etudes; Paris-11 Univ., fabulte des Sciences 91 - Orsay (France)

    1969-07-01

    {beta}{gamma} directional angular correlations and shapes of inner beta spectra leading to the first excited level of the final nucleus enable one to determine the nuclear matrix elements typical of the {beta} transition. In the three observed first forbidden cases: {sup 170}Tm, {sup 86}Rb, {sup 198}Au, these matrix elements do not confirm the independent shell model theory. Other hypotheses are then suggested and discussed. (author) [French] Les experiences de correlation angulaire {beta}{gamma} et l'etude du spectre {beta} conduisant au premier niveau excite du noyau final permettent de determiner les elements de matrices nucleaires caracteristiques de cette transition. Dans les trois cas etudies (transitions une fois interdites): {sup 170}Tm, {sup 86}Rb, {sup 198}Au, ces elements de matrices ne peuvent etre retrouves a l'aide du modele en couches et a particules independantes. D'autres hypotheses sont alors emises et discutees. (auteur)

  7. Study of semi-conductor spectrometers for high counting rates. Application to the study of the reaction {sup 31}P (p, {alpha}{sub 0}): E{sub p} < 2 MeV; Etude de spectrometres a semi-conducteurs pour forts taux de comptage application a l'etude de la reaction {sup 31}P (p, {alpha}0): E{sub p} < 2 MeV

    Energy Technology Data Exchange (ETDEWEB)

    Ligeon, E [Commissariat a l' Energie Atomique, 38 - Grenoble (France). Centre d' Etudes Nucleaires

    1967-10-01

    The study of nuclear reactions involving particles of low charge (E < 2 MeV) calls for spectrometers of high resolving power. In many experiments however, the counting rate is high because of Coulomb scattering at the target: this results in a distortion of the experimental spectra and a loss of resolving power in the detection equipment. The first part of the work is devoted to an evaluation of the resolving power obtained with silicon-detector spectrometers. A study of the elastic scattering of protons by {sup 31}P shows which are the factors limiting the resolving power. In the second part we examine the various types of spectrometer which can be used in the case of a high count-rate. We have built an apparatus which can be used for carrying out spectrometry on particles produced by nuclear reactions, for a total, count-rate of 10{sup 5} counts/sec. (author) [French] L'etude des reactions nucleaires avec particules chargees a basse energie (E < 2 MeV) exige des spectrometres de haute resolution. Cependant, dans de nombreuses experiences le taux de comptage est eleve, par suite de la diffusion coulombienne sur la cible; on observe alors une distorsion des spectres experimentaux et une perte de resolution de l'ensemble de detection. La premiere partie de ce travail est consacree a l'evaluation de la resolution obtenue avec des spectrometres utilisant des detecteurs au silicium. L'etude de la diffusion elastique des protons sur le {sup 31}P montre quels sont les facteurs qui limitent la resolution. Dans une deuxieme partie, nous etudions les differents types de spectrometres que l'on peut utiliser dans le cas d'un taux de comptage eleve. Nous avons construit un appareil qui permet de faire la spectrometrie de particules, provenant de reactions nucleaires, pour un taux de comptage total de 10{sup 5} c/s. (auteur)

  8. Study of semi-conductor spectrometers for high counting rates. Application to the study of the reaction {sup 31}P (p, {alpha}{sub 0}): E{sub p} < 2 MeV; Etude de spectrometres a semi-conducteurs pour forts taux de comptage application a l'etude de la reaction {sup 31}P (p, {alpha}0): E{sub p} < 2 MeV

    Energy Technology Data Exchange (ETDEWEB)

    Ligeon, E. [Commissariat a l' Energie Atomique, 38 - Grenoble (France). Centre d' Etudes Nucleaires

    1967-10-01

    The study of nuclear reactions involving particles of low charge (E < 2 MeV) calls for spectrometers of high resolving power. In many experiments however, the counting rate is high because of Coulomb scattering at the target: this results in a distortion of the experimental spectra and a loss of resolving power in the detection equipment. The first part of the work is devoted to an evaluation of the resolving power obtained with silicon-detector spectrometers. A study of the elastic scattering of protons by {sup 31}P shows which are the factors limiting the resolving power. In the second part we examine the various types of spectrometer which can be used in the case of a high count-rate. We have built an apparatus which can be used for carrying out spectrometry on particles produced by nuclear reactions, for a total, count-rate of 10{sup 5} counts/sec. (author) [French] L'etude des reactions nucleaires avec particules chargees a basse energie (E < 2 MeV) exige des spectrometres de haute resolution. Cependant, dans de nombreuses experiences le taux de comptage est eleve, par suite de la diffusion coulombienne sur la cible; on observe alors une distorsion des spectres experimentaux et une perte de resolution de l'ensemble de detection. La premiere partie de ce travail est consacree a l'evaluation de la resolution obtenue avec des spectrometres utilisant des detecteurs au silicium. L'etude de la diffusion elastique des protons sur le {sup 31}P montre quels sont les facteurs qui limitent la resolution. Dans une deuxieme partie, nous etudions les differents types de spectrometres que l'on peut utiliser dans le cas d'un taux de comptage eleve. Nous avons construit un appareil qui permet de faire la spectrometrie de particules, provenant de reactions nucleaires, pour un taux de comptage total de 10{sup 5} c/s. (auteur)

  9. Les activités de conservation des lémuriens par le Groupe d’Etude et de Recherche sur les Primates de Madagascar (GERP Conservation activities of lemurs by the Madagascar Primate Research Group (GERP- Groupe d’Etude et de Recherche sur les Primates de Madagascar

    Directory of Open Access Journals (Sweden)

    Rose Marie Randrianarison

    2011-10-01

    Full Text Available Le Groupe d’Etude et de Recherche sur les Primates de Madagascar, une association de conservation, a été créée en 1994 grâce à l’initiative des Enseignants Chercheurs et étudiants du Département de Paléontologie et d’Anthropologie Biologique et du Département de Biologie Animale de l’Université d’Antananarivo. Le GERP regroupe actuellement des membres scientifiques multidisciplinaires Malgaches et étrangers dont la majorité d’entre eux est constituée par des primatologues. Les principales actions du GERP se focalisent sur les travaux de recherche sur les Primates Prosimiens de Madagascar, l’établissement de leur plan de conservation, la découverte de nouvelles espèces de lémuriens, la translocation et le transfert des lémuriens vivant dans des milieux défrichés ou précaires, le suivi et l’abondance des lémuriens ainsi que la révision de leurs aires de distribution. Les résultats des recherches effectuées sur la conservation ont permis de publier des articles dans des revues de renommée nationale et internationale sur la Primatologie. En outre, le renforcement de capacité et l’éducation de la communauté de base, des systèmes éducatifs primaires et supérieurs sur la conservation des lémuriens et l’appui aux activités de développement durable de la population locale s’avèrent nécessaires pour que la conservation des lémuriens soit pérenne.The Madagascar Primate Research Group (GERP - Groupe d’Etude et de Recherche sur les Primates de Madagascar is a conservation-focused association created in 1994 by the initiative of researcher lecturers and students from the Department of Paleontology and Biological Anthropology and the Department of Animal Biology of the University of Antananarivo. The GERP membership consists of multidisciplinary scientists, both Malagasy and foreign, the majority of whom are primatologists. The principle actions of the association are focused on research on the

  10. Comparison of Dietary Intakes Between a Large Online Cohort Study (Etude NutriNet-Santé) and a Nationally Representative Cross-Sectional Study (Etude Nationale Nutrition Santé) in France: Addressing the Issue of Generalizability in E-Epidemiology.

    Science.gov (United States)

    Andreeva, Valentina A; Deschamps, Valérie; Salanave, Benoît; Castetbon, Katia; Verdot, Charlotte; Kesse-Guyot, Emmanuelle; Hercberg, Serge

    2016-11-01

    Despite some advantages over traditional methods, Web-based studies elicit concerns about generalizability. To address this issue, we compared dietary intakes between an electronic (e-) cohort study and a nationally representative survey. We studied 49,443 French volunteers aged 18-74 years recruited during 2009-2010 in the NutriNet-Santé Study, a general population-based e-cohort study. The Etude Nationale Nutrition Santé (ENNS; 2006-2007), a cross-sectional study with a nationally representative sample of 2,754 French adults aged 18-74 years, served as the reference data set. Reported dietary intakes from three 24-hour dietary records were weighted and compared between the two studies via Student t tests for mean location, using a >5% cutoff for establishing practically meaningful differences. We observed similar intakes as regards carbohydrates, total lipids, protein, and total energy. However, intakes of fruit and vegetables, fiber, vitamins B 6 , B 9 , C, D, and E, iron, and magnesium were higher in the e-cohort than in the ENNS, while intakes of alcohol and nonalcoholic beverages were lower in the e-cohort. Significant sex-specific differences were observed regarding vitamins A and B 12 , zinc, and potassium. True intake differences, mode effects, and volunteer bias might each contribute to explaining the findings. In the future, repeated use of the same tool in large e-cohorts with heterogeneous dietary exposures could serve research purposes and supplement group-level monitoring of dietary trends. The Author 2016. Published by Oxford University Press on behalf of the Johns Hopkins Bloomberg School of Public Health. All rights reserved. For permissions, please e-mail: journals.permissions@oup.com.

  11. Stabilization of mixed carbides of uranium-plutonium by zirconium. Part 1.: uranium carbide with small additions of zirconium; Etude de la stabilisation des carbures mixtes d'uranium et de plutonium par addition de zirconium. 1. partie: etude des carbures d'uranium avec de faibles additions de zirconium

    Energy Technology Data Exchange (ETDEWEB)

    Bocker, S [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1969-07-01

    Cast carbide samples, being of a high density and purity, are preferable for research purposes, to samples produced by powder metallurgy methods. Samples of uranium carbide with small additions of zirconium (1 to 5 per cent) were cast, as rods, in an arc furnace. A single phase carbide with interesting qualities was produced. As cast, a dendrite structure is observed, which does not disappear, after a treatment at 1900 deg. C during 110 hours. In comparison with uranium monocarbide the compatibility with stainless steel is much improved. The specific heat (between room temperature and 2500 deg. C) is similar to the specific heat of uranium monocarbide. A study of these mixed carbides, but having a part of the uranium replaced by plutonium is under way. (author) [French] Les echantillons de monocarbures obtenus par coulee sont tres interessants pour les recherches experimentales a cause de leur grande purete, de leur densite tres elevee et de la facilite d'obtention des lingots de forme et dimensions variees. On a prepare et coule dans un four a arc des echantillons de carbures d'uranium avec de faibles additions de zirconium (1 a 5 at. pour cent). On obtient ainsi des carbures monophases presentant de meilleures proprietes que le monocarbure d'uranium. A l'etat brut de coulee on observe une structure dendritique qui n'est pas detruite par un traitement thermique de 110 heures a 1900 deg. C. La compatibilite avec l'acier inoxydable 316 (a 925 deg. C pendant 500 heures) est nettement amelioree par rapport a UC. La chaleur specifique (entre la temperature ordinaire et 2500 deg. C) et la densite sont tres peu differentes de celles du monocarbure d'uranium. Une etude concernant les composes U-Pu-Zr-C est actuellement en cours. (auteur)

  12. Transformations of highly enriched uranium into metal or oxide; Etudes des procedes de transformation des composes d'uranium a fort enrichissement isotopique

    Energy Technology Data Exchange (ETDEWEB)

    Nollet, P; Sarrat, P [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1964-07-01

    described successively, together with the studies which led to their development The civil engineering construction was begun in June 1962. The workshops are to start production in may 1964. (authors) [French] Les ateliers de traitement d'uranium enrichi de Cadarache ont pour but: d'une part, de transformer l'hexafluorure d'uranium en metal, ou en oxyde, et d'autre part, de recuperer l'uranium contenu dans les dechets divers produits lors des operations de transformation metallurgique. Les principes qui ont ete suivis pour la conception et la securite de ces ateliers sont exposes. La securite nucleaire est basee sur la geometrie des appareils de traitement. Pour mettre au point les procedes et la technologie de ces ateliers, de nombreuses etudes ont ete conduites depuis 1960, dont certaines ont abouti a des realisations originales. La transformation de l'hexafluorure d'uranium a fort enrichissement isotopique s'effectue, soit par injection en phase gazeuse dans l'ammoniaque, soit par un procede original de reduction directe en tetrafluorure d'uranium par l'hydrogene. La recuperation de l'uranium contenu dans les dechets metalliques d'uranium-zirconium s'operera par attaque par l'acide chlorhydrique, puis traitement du chlorure d'uranium par le fluor afin d'obtenir l'uranium sous forme d'hexafluorure. La recuperation de l'uranium contenu dans les dechets divers s'opere par un procede classique de raffinage: grillage des dechets metalliques, dissolution de l'oxyde obtenu dans l'acide nitrique, purification par solvant au tributyl-phosphate, precipitation a l'ammoniaque, calcination reduction fluoruration, calciothermie et traitement des scories. Deux ateliers separes fonctionnent suivant ce procede: l'un traite l'uranium d'un enrichissement isotopique inferieur ou egal a 3 p. 100, l'autre est reserve aux forts enrichissements. La mise en oeuvre, d'une maniere nucleairement sure, de chacune des etapes du procede a pose des problemes technologiques particuliers et a conduit a

  13. Proceedings of the European Symposium on Pressure Equipment - ESOPE 2007; Actes des Journees d'Etudes Europeennes Equipements sous Pression - ESOPE 2007

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2007-07-01

    orientations retained for pressure equipments used in the nuclear industry, the European standards and the international collaboration, the Chinese standards and finally the recent developments of the codes and standards of the ASME in the USA. ESOPE 2007 also includes a Poster Session organized in the context of the international exhibition, which allows the companies to present their industrial realizations in parallel to the Symposium. (author) [French] Tous les trois ans, et depuis maintenant trente ans, l AFIAP organise un symposium ou les experts et acteurs oeuvrant dans le domaine des equipements sous pression, qu'ils soient fixes ou transportables, peuvent se rencontrer et echanger sur tous les developpements touchant a leur activite. Ce qui etait dans un premier temps denomme 'Congres national sur la technologie des appareils a pression', puis 'Journees d'etude sur les appareils a pression', est devenu depuis 2001 les 'Journees d'etude Europeennes sur les equipements sous pression' ou encore 'European Symposium on Pressure Equipment' (ESOPE), marquant ainsi une volonte d'ouverture a l'Europe et a l'international dans un contexte marque par la mise en oeuvre des directives europeennes applicables a ces equipements. Les journees 2001 furent plus particulierement consacrees a la mise en oeuvre des directives harmonisant la construction des equipements, et les journees 2004 ont ete plus particulierement axees sur la gestion des equipements en service. Pour le symposium ESOPE 2007, le comite d organisation a souhaite reprendre ces deux themes sous les aspects de la securite et de la competitivite, ainsi que de l'innovation. La seance pleniere du dernier jour sera entierement consacree a ces themes et comportera une Table Ronde ou s'exprimeront des representants nationaux et europeens des pouvoirs publics, des representants des fabricants et utilisateurs, ainsi que des experts engages dans la

  14. Etude du processus de changement vecu par des familles ayant decide d'adopter volontairement des comportements d'attenuation des changements climatiques

    Science.gov (United States)

    Leger, Michel T.

    recension des ecrits sur le changement de comportement en environnement. Nous explorons egalement la famille comme systeme fonctionnel de sorte a mieux comprendre ce contexte d'action environnementale qui est, a notre connaissance, peu etudie. Dans le deuxieme article, nous presentons nos resultats de recherche concernant les facteurs d'influence observes ainsi que les competences manifestees au cours du processus d'adoption de nouveaux comportements environnementaux dans trois familles. Enfin, le troisieme article presente les resultats du cas d'une quatrieme famille ou les membres vivent depuis longtemps des modes de vie ecologique. Dans le cadre d'une demarche d'analyse par theorisation ancree, l'etude de ce cas modele nous a permis d'approfondir les categories conceptuelles identifiees dans le deuxieme article de sorte a produire une modelisation de l'integration de comportements environnementaux dans le contexte de la famille. Les conclusions degagees grace a la recension des ecrits nous ont permis d'identifier les elements qui pourraient influencer l'adoption de comportements environnementaux dans des familles. La recension a aussi permis une meilleure comprehension des divers facteurs qui peuvent affecter l'adoption de comportements environnementaux et, enfin, elle a permis de mieux cerner le phenomene de changement de comportement dans le contexte de la famille consideree comme un systeme. En appliquant un processus d'analyse inductif, a partir de nos donnees qualitatives, les resultats de notre etude multi-cas nous ont indique que deux construits conceptuels semblent influencer l'adoption de comportements environnementaux en famille : 1) les valeurs biospheriques communes au sein de la famille et 2) les competences collectivement mises a profit collectivement durant l'essai de nouveaux comportements environnementaux. Notre modelisation du processus de changement dans des familles indique aussi qu'une dynamique familiale collaborative et la presence d'un groupe de

  15. Contribution to a research on electron beam welding of metals; Contribution a l'etude de la soudure des metaux par faisceau d'electrons

    Energy Technology Data Exchange (ETDEWEB)

    Stohr, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-03-15

    pressure, occasioned by additional elements with high vapour pressure, put on the formation of the hole. Micrographs made with welded parts of different metals show melting segregations similar to those obtained when filling a mould of great length. One may point out, that the geometrical configuration adopted by these segregations confirm the hypothesis of the metal flow, as previously contemplated. The study of these segregations, observed during examination through an interferential contrast microscope, has been attempted with a Castaing probe and by radiographical inspection of thin plates: no heterogeneity whatever has been observed. Mechanical tests operated on welded parts, did not show any appreciable difference existing between failure, elongation, yield point and impact values of a welded piece and those of a piece of the basic metal. This method applied on stainless steel shows not only excellent results, but also that the number of calories provided per length unit increases slightly with the welded thickness, whereas one could have expected a linear expression. Results obtained during this work, allow us to sift a certain number of data inherent to the electron beam welding, and to reflect on the definition of welding parameters versus aim to be reached. (author) [French] La soudure des metaux par faisceau d'electrons s'effectue par deplacement du point de focalisation du faisceau sur la ligne de jonction des deux pieces a assembler. Les parametres de soudure sont la puissance du canon W, la valeur de la surface d'impact des electrons S, la vitesse de soudure s. Des le debut de notre etude en 1954, est apparu le role essentiel joue par la puissance specifique W/s, sur la forme de la zone soudee et la profondeur de penetration. Une etude plus systematique a ete entreprise aux laboratoires du C.E.N. Saclay sous le patronage de Monsieur le Professeur CHAUDRON pour mieux definir l'Importance des divers parametres de soudure et voir l'influence exercee par eux sur

  16. Microbiological Studies on the Influence of Combined Processes of Heat and Irradiation on the Survival of Saccharomyces Cerevisiae Var. Ellipsoideus; Etudes Microbiologiques sur l'Influence d'un Traitement Mixte par Chauffage et Irradiation sur la Survie de Saccharomyces Cerevisiae Var. Ellipsoideus; Mikrobiologicheskie issledovaniya vliyaniya sovmestnykh protsessov nagreva i oblucheniya na vyzhivanie saccharomyces Cerevisiae Var. Ellipsoideus; Estudios Microbiologicos de la Influencia del Calentamiento e Irradiacion Combinados Sobre la Supervivencia del Saccharomyces Cerevisiae Var. Ellipsoideus

    Energy Technology Data Exchange (ETDEWEB)

    Stehlik, G.; Kaindl, K. [Institute for Biology and Agriculture, Reaktorzentrum, Seibersdorf (Austria)

    1966-11-15

    this treatment are under investigation on apple and grape juice. (author) [French] L'un des principaux sujets de recherche inscrits au programme international sur la conservation des fruits et jus de fruits par irradiation, execute a Seibersdorf, est le probleme de la radiosensibilisation des micro-organismes. En vue d'etudier l'effet d'un traitement par la chaleur et l'irradiation sur la survie des cellules de levures (formation de colonies), une souche a forte radioresistance - Saccharomyces cerevisiae var. ellipsoideus - cultivee sur un milieu nutritif semi-synthetique, a ete soumise des le debut de sa phase logarithmique a un traitement combine par chauffage et irradiation gamma (source au cobalt-60). Le traitement thermique a ete applique, soit immediatement avant l'irradiation, soit pendant ou immediatement apres celle-ci. On a fait varier la temperature entre 20 et 52,5 Degree-Sign C. Pour l'irradiation, effectuee dans Bullet un tube en verre bien aere, on a utilise des doses allant jusqu'a 0, 3 x 10{sup 6} rad. L'effet d'inhibition de ce traitement mixte depend de l'ordre de succession du chauffage et de l'irradiation; les resultats obtenus sont les suivants: la combinaison la plus efficace est un traitement simultane par chauffage et irradiation; la combinaison qui consiste a faire suivre le chauffage d'une irradiation a la temperature ambiante est moins efficace; le moindre effet a ete obtenu par chauffage apres irradiation a la temperature ambiante. Le traitement mixte chaleur/irradiation donne des courbes de survie (fractions d'organismes survivants) qui sont des lignes droites ayant pour coordonnees la dose d'irradiation a une echelle semi-logarithimique, et la temperature dans l'intervalle compris entre la temperature ambiante et 45 Degree-Sign C. Au-dessus de 45 Degree-Sign C, les courbes indiquent, a des doses inferieures a 30 krad, un accroissement du nombre des survivants par rapport a l'echantillon non irradie. En comparant les pentes des courbes de

  17. Fixation of Radioactive Waste in Glass. Part I. Pilot-Plant Experience at Harwell; Fixation des Dechets Radioactifs dans le Verre, Premiere Partie: L'Usine Pilote de Harwell; 0424 0418 041a 0421 0410 0426 0418 042f 0420 0410 0414 0418 041e 0410 041a 0422 0418 0412 041d 042b 0425 041e 0422 0425 041e 0414 041e 0412 0412 0421 0422 0415 041a 041b 0415 ; Fijacion de Desechos Radiactivos en Vidrio. Parte I: Experiencia Adquirida en la Instalacion Piloto de Harwell

    Energy Technology Data Exchange (ETDEWEB)

    Elliot, M. N.; Gayler, R.; Grover, J. R.; Hardwick, W. H. [Atomic Energy Research Establishment, Harwell (United Kingdom)

    1963-02-15

    The reasons for incorporating fission-product wastes into glass for long-term storage are outlined. The flow-sheet and operating cycle of the fixation process which has been developed at Harwell are described. Two years of operation of an inactive pilot plant are surveyed to show how the present operating conditions have been evolved. Full-length runs under these conditions have confirmed the reliability and reproducibility of the process. Engineering components suitable for an active plant have been developed and tested and the layout of die 1000-c pilot plant being commissioned at Harwell is illustrated in sketch form. Factors that affect the scale-up of the process are discussed in relation to the needs of the developing United Kingdom power programme. (author) [French] Les auteurs exposent les raisons pour lesquelles on incorpore les dechets de produits de fission dans le verre en vue d'un stockage de longue duree. Ils donnent le diagramme d'operations et le cycle du procede de fixation mis au point a Harwell. Ils decrivent les deux annees de fonctionnment de l'usine pilote, sans produits radioactifs, pour montrer comment les conditions actuelles d'operations ont ete mises au point. Des cycles complets realises dans ces conditions ont confirme la securite et la reproductibilite du processus. L'appareillage approprie pour une usine de haute activite a ete mis au point et essaye; les auteurs de crivent les grandes lignes de l'usine pilote (activite de 1000 c) en construction a Harwell. Les auteurs discutent les facteurs qui peuvent affecter le developpement de ce processus a plus grande echelle, eu egard aux besoins du programme energetique du Royaume-Uni. (author) [Spanish] Los autores exponen las razones que aconsejan incorporar los desechos y productos de fision a materiales vitreos para almacenarlos por tiempo largo. Describen el diagrama de circu- lacion y el ciclo de operaciones que integran el proceso de fijacion perfeccionado en Harwell. Examinan luego

  18. Entraînement de globules d'huile par un tensio-actif. Etude de la formation du banc Mobilization of Oil Ganglia by a Surfactant Analysis of Bank Formation

    Directory of Open Access Journals (Sweden)

    Moulu J. C.

    2006-11-01

    Full Text Available Lors de l'injection d'une solution de tensio-actif dans un gisement déjà balayé par de l'eau, l'huile résiduelle, piégée sous la forme de globules discontinus, est remise en mouvement et se regroupe éventuellement sous la forme d'un banc d'huile. Le but de la présente étude est d'expliquer la formation de ce banc au cours d'un tel déplacement. Les résultats d'expériences réalisées en micromodèles de billes de verre permettent de constater que : - la récupération globale est corrélable avec le nombre capillaire Nc= uVdf/O, u et Vdf étant la viscosité et la vitesse de Darcy du fluide injecté, O la tension interfaciale avec l'huile en place ; - la vitesse des globules varie différemment avec u, Vdf, O et tend vers la même limite plus grande que la vitesse du fluide injecté pour de grandes valeurs du nombre capillaire Nc ; - le banc d'huile ne se forme que dans le cas où la vitesse des globules atteint celle du fluide injecté. L'huile déplacée reste alors groupée avec une saturation importante au niveau du front de tensio-actif. When a surfactant solution is injected into a reservoir previously waterflooded, the residual oil trapped as discontinuous ganglia is mobilized and eventually bunched together forming an oil bank. The aim of this study is to explain the formation of this bank during such a drive. The results of experiments performed in micromodels of glass beads show that: a Overall recovery can be correlated with the capillary number, Nc = uVfd/O, in which u and Vfd are the viscosity a and Darcy velocity of the injected fluid and O is the interfacial tension with the oil in place. b Ganglia velocity varies differently with u, Vfd and O, and it tends towards the same limit faster than the velocity of the injected fluid for high values of the capillary number Nc. c The oil bank is formed only in the case where globule velocity attaints that of injected fluid. the dispaced oil then remains bunched, with high

  19. A study of some lattice defects with help of channeled {alpha} particles; Etude de quelques defauts cristallins a l'aide de particules {alpha} canalisees

    Energy Technology Data Exchange (ETDEWEB)

    Quere, Y [Commissariat a l' Energie Atomique, 92 - Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1968-07-01

    A method is described in which a metallic foil is irradiated by isotropic {alpha} particles. The thickness of the foil is such that only channeled particles can traverse it. The emerging flux, a function of the local concentration of defects, falls on a collector where an image of the foil is formed. The influence of grain or twin boundaries, of stacking faults, of dislocations, is observed. A quantitative study of dislocation is presented. The effect of a dislocation is represented by the presence of a coaxial dechanneling-cylinder of diameter: {lambda}-bar = [(b d a E)/({alpha}Z{sub 1}Z{sub 2}e{sup 2})]{sup 1/2}, b is the Burgers vector; d the interatomic distance along the channel; a the screening radius of the interaction between the particles (Z{sub 2}) and the metal (Z{sub 1} ); E the energy of the particles; {alpha} a numerical parameter. There is a reasonable agreement with experimental results. Channeling patterns, observed in all metals, are described. They are more numerous if the metal has been treated some time in gaseous atmospheres. They correspond to zones, on the metal, situated on the side of entrance of particles. It is proposed that in these zones, gaseous atoms strengthen the channels and enhance channeling. (author) [French] On decrit une methode qui consiste a irradier une feuille metallique par des particules {alpha} isotropes. La feuille est assez epaisse pour que seules les particules canalisees emergent. Le flux sortant depend alors fortement de la concentration en defauts. Il est recueilli sur un collecteur ou se forme ainsi une image de l'echantillon. On montre l'influence des joints de grains ou de macle, des fautes d'empilement et des dislocations. Dans ce dernier cas, la methode se prete bien a des etudes quantitatives. On represente l'effet d'une dislocation par la presence d'un cylindre de decanalisation coaxial de diametre: {lambda}-bar = [(b d a E)/({alpha}Z{sub 1}Z{sub 2}e{sup 2})]{sup 1/2} ou b est le vecteur de Burgers, d la

  20. Thermal decomposition of uranyl nitrate hexahydrate. Study of intermediate reaction products; Decomposition thermique du nitrate d'uranyle hexahydrate etude des intermediaires de cette decomposition

    Energy Technology Data Exchange (ETDEWEB)

    Chottard, G [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1970-07-01

    The thermal decomposition of uranyl nitrate hexahydrate has been carried but at constant pressure and constant rate of reaction. The following intermediary products have been shown to exist and isolated: UO{sub 2}(NO{sub 3}){sub 2}.3H{sub 2}O; UO{sub 2}(NO{sub 3}){sub 2}. 2H{sub 2}O; UO{sub 2}(NO{sub 3}){sub 2}. H{sub 2}O; UO{sub 2}(NO{sub 3}){sub 2} and UO{sub 3}. These products, together with the hexahydrate UO{sub 2} (NO{sub 3}){sub 2}.6H{sub 2}O, have been studied by: - X-ray diffraction, using the Debye-Scherrer method.- infra-red spectrography: determination of the type of bonding for the water and the nitrate groups. - nuclear magnetic resonance: study of the mobility of water molecules. The main results concern: - the water molecule bonds in the series of hydrates with 6.3 and 2 H{sub 2}O. - isolation and characterization of uranyl nitrate monohydrate, together with the determination of its molecular structure. - the mobility of the water molecules in the series of the hydrates with 6.3 and 2 H{sub 2}O. An analysis is made of the complementary results given by infra-red spectroscopy and nuclear magnetic resonance; they are interpreted for the whole of the hydrate series. [French] La decomposition thermique du nitrate d'uranyle hexahydrate a ete effectuee en operant a pression et vitesse de decomposition constantes. Les produits intermediaires suivants ont ete mis en evidence et isoles: UO{sub 2}(NO{sub 3}){sub 2}, 3H{sub 2}O; UO{sub 2}(NO{sub 3}){sub 2}, 2H{sub 2}O; UO{sub 2}(NO{sub 3}){sub 2},H{sub 2}O; UO{sub 2}(NO{sub 3}){sub 2} et UO{sub 3}. Ces composes, ainsi que l'hexahydrate UO{sub 2}(NO{sub 3} ){sub 2}, 6H{sub 2}O ont ete etudies par: - diffraction des rayons X, selon la methode Debye-Scherrer.- spectrographie infra-rouge: determination des modes de liaison de l'eau et des groupements nitrate. - resonance magnetique nucleaire: etude de la mobilite des molecules d'eau. Les principaux resultats portent sur: - les liaisons des molecules d'eau dans la

  1. Kinetic study of the reaction of uranium with various carbon-containing gases; Etude cinetique de la reaction sur l'uranium de differents gaz carbones

    Energy Technology Data Exchange (ETDEWEB)

    Feron, G [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1963-09-15

    The kinetic study of the reaction U + CO{sub 2} and U + CO has been performed by a thermogravimetric method on a spherical uranium powder, in temperature ranges respectively from 460 to 690 deg. C and from 570 to 850 deg. C. The reaction with carbon dioxide leads to uranium dioxide. A carbon deposition takes place at the same time. The global reactions is the result of two reactions: U + 2 CO{sub 2} {yields} UO{sub 2} + 2 CO U + CO{sub 2} {yields} UO{sub 2} + C The reaction with carbon monoxide leads to a mixture of dioxide UO{sub 2}, dicarbide UC{sub 2} and free carbon. The main reaction can be written. U + CO {yields} 1/2 UO{sub 2} + 1/2 UC{sub 2} The free carbon results of the disproportionation of the carbon monoxide. A remarkable separation of the two phases UO{sub 2} and UC{sub 2} can be observed. A mechanism accounting for the phenomenon has been proposed. The two reactions U + CO{sub 2} and U + CO begin with a long germination period, after which, the reaction velocity seems to be limited in both cases by the ionic diffusion of oxygen through the uranium dioxide. (author) [French] L'etude cinetique des reactions U sol + CO{sub 2} gaz et U sol + CO gaz a ete effectuee par thermogravirnetrie sur une poudre d'uranium a grains spheriques, les domaines de temperature etudies s'etendant respectivement de 460 a 690 deg. C et de 570 a 850 deg. C. L'action du dioxyde de carbone conduit au dioxyde d'uranium UO{sub 2}; il se produit en meme temps un depot de carbone. La reaction globale resulte des deux reactions: U + 2 CO{sub 2} {yields} UO{sub 2} + 2 CO U + CO{sub 2} {yields} UO{sub 2} + C Le mono-oxyde de carbone conduit a un melange de dioxyde UO{sub 2}, de dicarbure UC{sub 2} et de carbone libre. La reaction principale s'ecrit: U + CO {yields} 1/2 UO{sub 2} + 1/2 UC{sub 2} Le carbone libre provient de la dismutation du mono-oxyde de carbone. On observe une separation remarquable des deux phases UO{sub 2} et UC{sub 2}; un mecanisme rendant compte de ce phenomene a

  2. Contribution to the study of porous or very finely divided alumina; Contribution a l'etude des alumines poreuses ou tres finement divisees

    Energy Technology Data Exchange (ETDEWEB)

    Juillet, F [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1961-12-15

    deficit en aluminium apres traitement a 700 deg C entrainant l'apparition des proprietes de semi-conducteur n puis p. Une alumine cristallisee delta sous forme do grains spheriques non poreux soumise a une compression de 1 a 5 t/cm{sup 2} presente egalement une non-stoechiometrie a deficit d'oxygene ou d'aluminium. Aucun de ces phenomenes n'a pu etre enregistre avec l'echantillon non soumis a la compression. L'influence favorable de l'oxygene dans le processus de recristallisation de l'alumine amorphe et dans la transformation delta-alpha de l'alumine cristallisee a ete mise en evidence, De plus, les contraintes developpees par compression de l'alumine delta permettent sa transformation en phase alpha dans l'air a une temperature inferieure a celle necessaire pour observer le meme phenomene dans l'alumine delta non comprimee. L'afumine amorphe subit un frittage intragranulaire des 500 deg C et un frittage intergranulaire a 1 000 deg C. Seul ce dernier s'observe pour l'alumine en grains spheriques. Pour cette derniere les contraintes developpees par la compression abaissent de 100 deg C le seuil de ce frittage par rapport a la temperature necessaire pour observer ce phenomene avec l'echantillon non comprime. Le taux de frittage d'un comprime d'alumine cristallisee depend, en plus, de la vitesse de la mise en temperature. L'ensemble de cette etude tend a montrer que des proprietes nouvelles, ou du moins inhabituelles de l'etat solide peuvent etre observees s'il est fait appel a des solides desorganises ou encore cristallises mais dotes d'une importante surface specifique et soumis a des contraintes. (auteur)

  3. Delayed neutron detection in canning burst detection studies (1961); Etude sur la detection des neutrons differes en vue de la detection des ruptures de gaines (1961)

    Energy Technology Data Exchange (ETDEWEB)

    Perlini, G [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1961-07-01

    This paper describes a theoretical and experimental study on the detection of neutrons present in the primary cooling circuit of a reactor cooled by heavy or light water, with a view to the installation of a canning burst detection unit. The concentration of background neutrons is first calculated, taking into account the neutrons from nitrogen 17 decay, and the photoneutrons produced by the decay of nitrogen 16 and sodium 24. The emission of delayed fission neutrons, originating at a given crack in the canning, has been estimated. Using the D{sub 2}O circuit of the pile EL-3, three units have been developed by means of which the following three types of detector may be compared: 1) BF{sub 3} proportional counter 2) Boron scintillator 3) Fission chamber Under the present experimental conditions the BF{sub 3} counter gave the best results. The influence on these detectors of the {gamma} flux, which in certain cases reaches 200 R/h, is analysed. Finally a calibration is carried out with an experimental crack of 30 mm{sup 2} of uranium exposed to a flux of 5.8 x 10{sup 13} n.cm{sup -2}.s{sup -1}. The sensitivity obtained with the BF{sub 3} counter during this test is 2 counts/s per mm{sup 2} of exposed uranium. (author) [French] Le present rapport est une etude theorique et experimentale sur la detection des neutrons presents dans le circuit primaire de refroidissement d'un reacteur refrigere par l'eau lourde ou l'eau legere, en vue d'une installation de detection de ruptures de gaines. On fait d'abord un calcul sur la concentration des neutrons de bruit de fond en tenant compte: des neutrons de decroissance de l'azote 17 et des photoneutrons produits par les decroissances de l'azote 16 et du sodium 24. L'emission des neutrons differes de fission, qui ont pour origine une fissure de gaine donnee, a ete evaluee. Utilisant le circuit D{sub 2}O de la pile EL3, trois installations ont ete mises au point permettant de comparer les trois types de detecteurs suivants: 1

  4. A study of some radioprotection apparatuses used in the case of pool reactors; Etude de quelques dispositifs de radioprotection en service aupres des piles piscines

    Energy Technology Data Exchange (ETDEWEB)

    Robien, E de; Choudens, H de; Delpuech, J [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1965-07-01

    Various problems of radioprotection concerning swimming-pool reactors in Grenoble have led us to study adequate solutions: a) The automatic verification of the staff-radioactivity when coming out of Melusine or Siloe has been realized thanks to a {beta}{gamma} gate which is insensitive to the ambient background in the reactor-hall; b) The automatic verification of the contamination of the shoes of the agents working in these reactors has been realized with a dedicated device; c) The necessity to measure precisely {gamma} doses with the help of an autonomous apparatus has led to the making of a plastic-scintillator {gamma} dosimeter; d) The obligation to forbid the opening of doors in some places where there might be a great intensity of radiation, has led us to make doors open according to the intensity of radiation inside the rooms; e) The releases of radioactive iodine have been measured with activated charcoal cartridges that surround a scintillator connected with a unique channel selector; f) Finally the control of reactor safety rod fall in case of a radioactive accident has been secured by a chain whose detector is a chamber immersed in the swimming-pool, which offers, in the particular case of the hot thickness swimming-pool reactor a double advantage: first it enables us to regulate the upper hot water layer, second to get free of transitory radiations which appear in the reactor hall as the experimental apparatuses are taken out from the core. (authors) [French] Differents problemes de radioprotection se posant aupres des piles piscines de Grenoble, ils ont necessite l'etude de solutions particulieres: a) le controle automatique de la radioactivite du personnel sortant de Melusine ou de Siloe a ete realise a l'aide d'un portique {beta}{gamma} insensible au bruit de fond ambiant du hall des piles; b) le controle automatique de la contamination des souliers des agents travaillant dans ces piles a ete realise par une passerelle pieds {beta}{gamma}; c) la

  5. Chronological study of beryllium plasma produced by a laser beam; Etude chronologique du plasma de beryllium cree par le faisceau d'un laser

    Energy Technology Data Exchange (ETDEWEB)

    Langer, Ph; Tonon, G; Durand, Y; Buges, J C [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1967-07-01

    l'evolution du plasma pendant toute la duree de l'impulsion laser (largeur a mi-hauteur 40 ns). Ce plasma, visible a partir de - 60 ns (l'origine des temps est prise au sommet de l'impulsion laser) subit une acceleration uniforme de - 30 a + 5 ns; a cet instant sa vitesse d'expansion est maximum et vaut 10{sup 7}cm/s, Des ions Be{sup +}, Be{sup 2+} et Be{sup 3+} (correspondant a un potentiel d'ionisation de 153 eV) sont emis par le plasma des sa creation et possedent une energie cinetique maximum de 1500 eV. L'etude spectroscopique du plasma a mis en evidence l'apparition de raies de recombinaison du beryllium une fois ionise et du beryllium excite a partir respectivement de + 70 ns et + 120 ns. Ces raies sont encore visibles au-dela de + 470 ns et + 720 ns. Des mesures interferometriques effectuees sur ce plasma nous ont revele que sa densite electronique n'est pas uniforme et decroit rapidement au fur et a mesure que l'on s'eloigne de la cible. Par exemple a 0,3 mm de la surface de la cible elle est respectivement de 2,3. 10{sup 18} e/cm{sup 3} et de 5,5. 10{sup 17} e/cm{sup 3} aux instants + 20 ns et + 40 ns. (auteurs)

  6. Study of current instabilities in high resistivity gallium arsenide; Etude des instabilites de courant dans l'arseniure de gallium de haute resistivite

    Energy Technology Data Exchange (ETDEWEB)

    Barraud, A [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1968-07-01

    gallium de haute resistivite. Nous montrons que ces oscillations sont associees a la progression lente d'un domaine de fort champ electrique a travers tout l'echantillon. L'etude experimentale des proprietes de ces instabilites nous a permis de differencier ce phenomene de l'effet Gunn, des effets acoustoelectriques et des effets de contacts. Nous proposons pour rendre compte de ce type d'instabilites un mecanisme de piegeage differentiel sur des impuretes repulsives, capable de depeupler la bande de conduction a champ electrique eleve et de donner naissance a un domaine de champ intense. Le developpement qualitatif de ce modele nous permet de rendre compte de toutes les proprietes des cristaux d'arseniure de gallium de haute resistivite soumis a un champ electrique eleve: augmentation de la constante de Hall, existence d'un seuil de tension pour ces oscillations, formation de domaines de champ intense, lenteur de la propagation de ces domaines, enfin possibilite de renverser le sens de la propagation du domaine sans detruire celui-ci. Le developpement quantitatif du modele permet de calculer les differentes grandeurs caracteristiques de ces instabilites. La comparaison avec l'experience montre une bonne concordance, les legeres divergences provenant surtout de la meconnaissance actuelle des proprietes de transport dans l'arseniure de gallium aux champs electriques eleves. A la lumiere de ce modele, il apparait que le phenomene d'instabilite etudie peut se produire pour une gamme etendue de concentrations en centres repulsifs, et pour toute une gamme de resistivites. Ceci explique qu'il apparaisse systematiquement dans l'arseniure de gallium de moyenne et haute resistivite. (auteurs)

  7. Contribution to the study of the geophysical behaviour of lead-210 by application of alpha spectrometry; Contribution a l'etude du comportement geophysique du plomb 210 par application de la spectrometrie alpha

    Energy Technology Data Exchange (ETDEWEB)

    Nezami, M [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1965-06-01

    A study of the changes in the lead-210 contents of rain-water and of water produced by melting polar ice has required the development of a method for dosing lead-210, an {alpha} emitter. This method is 40 times more sensitive than that which measures the lead-210 by bismuth-210, a ({beta} emitter. The first part of the report presents the study of a spectrometry using semiconductor detectors; a catalogue of a spectra shows the advantages of this method. In the second part will be found at first a new chemical separation method for polonium-210 and the results obtained with this method. The main results obtained on the geophysical behaviour of lead-210 are the following: - the monthly lead-210 and polonium-210 contents in rain water are approximately constant with time. - in the Gif-sur-Yvette region, the clean-up by 'dry fall-out' can attain 40 to 50 per cent of the total fall-out. - a study of Antarctic ice samples makes it possible to determine an annual accumulation rate equivalent to 13.8 cm of water and to show discrepancies in the periodic concentrations which correspond to the latest maxima of solar activity. - a balance is drawn up between the radon produced by the continents and the lead-210 fall-out. (author) [French] Une etude sur les variations de la teneur en plomb 210 des eaux de pluie et des eaux de fusion des glaces polaires a necessite la mise au point d'une methode de dosage du plomb 210 emetteur {alpha}. Cette methode permet d'obtenir une sensibilite quarante fois superieure a celle dosant le plomb 210 par le bismuth 210 emetteur {beta}. La premiere partie du travail presente l'etude de la spectrometrie {alpha} par detecteur a semiconducteurs, un catalogue de spectres {alpha} met en evidence les avantages de cette methode. Dans la deuxieme partie on trouvera en premier lieu une nouvelle methode chimique de separation du polonium 210 ainsi que les resultats obtenus grace a cette methode. Les principaux resultats sur le comportement geophysique du

  8. Study of new structures adapted to gas-graphite and gas-heavy water reactors; Etude de structures nouvelles adaptees aux reacteurs graphite-gaz et eau lourde-gaz

    Energy Technology Data Exchange (ETDEWEB)

    Martin, R; Roche, R [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-07-01

    'EDF d'une part, les conclusions des etudes et essais effectues hors pile d'autre part, conduisent a un changement considerable de la physionomie des reacteurs de la filiere Graphite-Gaz, Les principales modifications envisagees sont analysees dans la communication. L'adoption d'un element combustible annulaire et d'un soufflage descendant permettront d'accroitre considerablement la puissance specifique et la puissance developpee par canal; il en resultera une reduction sensible du nombre des canaux et un accroissement correlatif de la maille du reseau - L'empilement de graphite devra etre adapte a ces nouvelles conditions - Des raisons de securite conduisent a generaliser l'emploi du beton precontraint pour la construction du caisson; elles pourront amener a integrer a l'interieur de celui-ci les echangeurs et l'appareil de manutention du combustible (dispositif dit: 'en grenier'). Une maquette en vraie grandeur de ce grenier a ete construite a Saclay avec la participation d'EURATOM; les resultats d'exploitation en sont presentes, ainsi que des idees de barres de controle de conception nouvelle. En ce qui concerne la filiere Eau-Lourde-Gaz, les etudes sont poursuivies dans deux voies principales; la premiere, qui conserverait l'usage de tubes de force horizontaux, tient compte de l'experience acquise au cours de la construction du reacteur EL4 dont elle constituerait une extrapolation; la seconde, inspiree des etudes poursuivies au titre de la filiere Graphite-Gaz, ferait appel a un caisson en beton precontraint pour tenir la pression, le moderateur etant sensiblement a la pression du fluide refrigerant et le combustible etant dispose dans des canaux verticaux. Les merites respectifs de ces deux variantes sont analyses dans la communication. (auteurs)

  9. Contribution to the study of the geophysical behaviour of lead-210 by application of alpha spectrometry; Contribution a l'etude du comportement geophysique du plomb 210 par application de la spectrometrie alpha

    Energy Technology Data Exchange (ETDEWEB)

    Nezami, M. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1965-06-01

    A study of the changes in the lead-210 contents of rain-water and of water produced by melting polar ice has required the development of a method for dosing lead-210, an {alpha} emitter. This method is 40 times more sensitive than that which measures the lead-210 by bismuth-210, a ({beta} emitter. The first part of the report presents the study of a spectrometry using semiconductor detectors; a catalogue of a spectra shows the advantages of this method. In the second part will be found at first a new chemical separation method for polonium-210 and the results obtained with this method. The main results obtained on the geophysical behaviour of lead-210 are the following: - the monthly lead-210 and polonium-210 contents in rain water are approximately constant with time. - in the Gif-sur-Yvette region, the clean-up by 'dry fall-out' can attain 40 to 50 per cent of the total fall-out. - a study of Antarctic ice samples makes it possible to determine an annual accumulation rate equivalent to 13.8 cm of water and to show discrepancies in the periodic concentrations which correspond to the latest maxima of solar activity. - a balance is drawn up between the radon produced by the continents and the lead-210 fall-out. (author) [French] Une etude sur les variations de la teneur en plomb 210 des eaux de pluie et des eaux de fusion des glaces polaires a necessite la mise au point d'une methode de dosage du plomb 210 emetteur {alpha}. Cette methode permet d'obtenir une sensibilite quarante fois superieure a celle dosant le plomb 210 par le bismuth 210 emetteur {beta}. La premiere partie du travail presente l'etude de la spectrometrie {alpha} par detecteur a semiconducteurs, un catalogue de spectres {alpha} met en evidence les avantages de cette methode. Dans la deuxieme partie on trouvera en premier lieu une nouvelle methode chimique de separation du polonium 210 ainsi que les resultats obtenus grace a cette methode. Les principaux resultats sur le

  10. Dans le labyrinthe de verre. La négociation sur l'effet de serre

    OpenAIRE

    Hourcade , Jean Charles

    2002-01-01

    National audience; En parcourant les étapes principales de la « négociation climat », on fait apparaître le jeu de miroirs qui se déroule entre Europe et États-Unis, dans un contexte historique caractérisé par les débats sur la mondialisation, la volonté de leadership de l'Union européenne sur ce thème, la montée aux États-Unis d'inquiétudes sur le maintien de leur suprématie.On montre aussi pourquoi ce jeu, après avoir masqué des possibilités réelles de compromis, a débouché en 2000 sur l'éc...

  11. Les bracelets en verre de Nages, Gard (Les Castels, fouilles 1958-1981)

    OpenAIRE

    Feugère , Michel; Py , Michel ,

    1989-01-01

    The stratigraphy from Nages, an oppidum settled during the 3rd-Ist c. BC, provides a unique opportunity to set up the chronology of the glass bracelets produced and worn during this very period in Western Europe. Giving the complete inventory of these objects discovered during the excavations, this article allows to appreciate the function of glass bracelets in the female traditional dress of this period, but also to better place the region within the preroman trade networks.; La stratigraphi...

  12. Incorporation de particules de verre post-consommation dans un enrobe bitumineux de type ESG14

    Science.gov (United States)

    Lachance Tremblay, Eric

    In 2008, around 244,000 tons of glass was produced by the Quebec population. From this number, 128,000 tons were collected by various means of collection. Glass recycling is problematic because all the glass that cannot be classified according to the type can't be used to manufacture new products. It is therefore necessary to find new sources of uses for this material. Because the use of recycled materials in road structure material is beneficial from an environmental and sometimes structural point of view, the idea of using recycled glass into asphalt mixture was recently studied at the LCMB. Nowadays, the use of recycled glass in asphalt mixture is not regulated by the MTQ. This research goal was to verify the possibility of using recycled glass particles in a ESG14 asphalt mixture while maintaining equivalent properties and performance compared to a conventional mix. Different dosages of recycled glass particles have been studied to evaluate the effect of glass on the asphalt mixture volumetric characteristics, the ability of compaction and the rutting resistance. These mixes were formulated according to the LC formulation of the MTQ. The first part allowed selecting an optimal dosage of recycled glass particles. Thereafter, the thermo mechanical performance (resistance to low temperatures (TSRST), complex modulus (E*) and resistance to fatigue cracking), physical characteristics (macro texture and surface grip) and durability (resistance to water damage) of the asphalt mixture with the optimal dosage were evaluated and compared with a reference mixture. The results show that the ESG14 mixture with recycled glass formulated with the LC method is more susceptible to rutting than the reference mixture. Therefore, a reduction of the bitumen content can increase the rutting resistance while conserving equivalent properties to a conventional mix regarding resistance to low temperatures, complex modulus, resistance to fatigue cracking as well as the physical characteristics. Therefore, the use of recycled in glass seems to modify the asphalt behavior and increase the moisture susceptibility.

  13. Effet de la poudre de verre sur le fluage du C-S-H

    Science.gov (United States)

    Danilova, Maryna

    Glass is a unique inert material that could be recycled many times without changing its physical and chemical properties. Nevertheless, for some reason, large quantities of glass are still not recycled and therefore are stored as a waste. Its alternative recycling has become, since long, a major environmental problem. Moreover, glass is a potentially useful material for the development of ecological concrete, consequently, this way valorization seems to be imminent. In this research, characterization of the creep of concrete incorporating waste glass in powder form, i.e. glass powder (GP) as a supplementary cementitious material (GP-concrete) was carried out at a macro- and nanolevels. First, results from experimental study on the under load behaviour of GP-concrete are presented. Different types of strain occurring under load or after unload were discussed: quasi-instantaneous deformation, total mechanical deformation due to the maintained uniaxial compressive load during 1 year, total creep, basic creep, elastic recovery and total recovery. Shrinkage under drying conditions and endogenous shrinkage were also studied. After 1 year creep, the effects of constant load and drying on residual strength were also examined. A comparison was made concerning the final state of the porosity. Afterwards, the thesis reveals the results of tests conducted on the cement paste, going down to its composition and properties of the hydrated phases, in particular of calcium silicate hydrates (C-S-H). All of this, in order to conclude on the harmlessness use of GP regarding to the creep. Keywords : Glass powder, Air-entrained concrete, Creep, Shrinkage, C-S-H, Nanoindentation

  14. From glass structure to its chemical durability; De la structure du verre a sa durabilite chimique

    Energy Technology Data Exchange (ETDEWEB)

    Angeli, F.

    2009-07-01

    The author gives an overview of his research activities. He more precisely reports studies related to glass structure based on nuclei observed by NMR and present in glasses of interest for nuclear activities. He discusses the influence of chemical composition on structure, and discusses information which can be extracted from network formers (Al, B) and modifiers (Na, Ca), and from oxygen present in the network linkages of oxide glasses. He discusses the different experimental and modelling approaches which enable structural and morphological information to be obtained at a mesoscopic scale. The last part deals with the investigation of the long term behaviour of confinement matrices (glassy matrix for medium-activity wastes, ceramic matrix)

  15. Modeling of glass fusion furnaces; Modelisation des fours de fusion de verre

    Energy Technology Data Exchange (ETDEWEB)

    Mechitoua, N. [Electricite de France (EDF), 78 - Chatou (France). Direction des Etudes et Recherches; Plard, C. [Electricite de France, 77 - Moret sur Loing (France). Direction des Etudes et Recherches

    1997-12-31

    The furnaces used for glass melting are industrial installations inside which complex and coupled physical and chemical phenomena occur. Thermal engineering plays a major role and numerical simulation is a precious tool for the analysis of the different coupling, of their interaction and of the influence of the different parameters. In order to optimize the functioning of glass furnaces and to improve the quality of the glass produced, Electricite de France (EdF) has developed a specialized version of the ESTET fluid mechanics code, called `Joule`. This paper describes the functioning principle of glass furnaces, the interactions between heat transfers and flows inside the melted glass, the interactions between heat transfers and the thermal regulation of the furnace, the interactions between heat transfers and glass quality and the heat transfer interactions between the melted glass, the furnace walls and the combustion area. (J.S.)

  16. Monte-Carlo method for studying the slowing down of neutrons in a thin plate of hydrogenated matter; Methode de Monte-Carlo pour l'etude du ralentissement des neutrons dans une plaque mince de matiere hydrogenee

    Energy Technology Data Exchange (ETDEWEB)

    Ribon, P; Michaudon, A [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1965-07-01

    The studies of interaction of slow neutrons with atomic nuclei by means of the time of flight methods are made with a pulsed neutron source with a broad energy spectrum. The measurement accuracy needs a high intensity and an output time as short as possible and well defined. If the neutrons source is a target bombarded by the beam of a pulsed accelerator, it is usually required to slow down the neutrons to obtain a sufficient intensity at low energies. The purpose of the Monte-Carlo method which is described in this paper is to study the slowing down properties, mainly the intensity and the output time distribution of the slowed-down neutrons. The choice of the method and parameters studied is explained as well as the principles, some calculations and the program organization. A few results given as examples were obtained in the line of this program, the limits of which are principally due to simplifying physical hypotheses. (author) [French] l'etude de l'interaction des neutrons lents avec les noyaux atomiques par la methode du temps de vol s'effectue avec une source pulsee de neutrons dont le spectre en energie est assez etendu. La precision des mesures demande que la source soit intense et que la duree d'emission des neutrons soit breve et bien definie. Si la source est une cible bombardee par le faisceau de particules d'un accelerateur pulse, il est generalement indispensable de ralentir les neutrons pour avoir une intensite suffisante a basse energie. Nous presentons ici une methode de Monte-Carlo pour l'etude detaillee de ce ralentissement, notamment l'intensite et la distribution des temps de sortie des neutrons ralentis. Cette presentation comprend: la justification du choix de la methode de Monte-Carlo, les principes generaux, les differentes etapes du calcul et du programme ecrit pour le calculateur electronique IBM 7090. Nous indiquons aussi les restrictions qui sont apportees au domaine d'application de ce programme et qui proviennent surtout des

  17. Contribution towards the study of {beta}{yields}{alpha} transformation in uranium and its alloys (1962); Contribution a l'etude de la transformation {beta}{yields}{alpha} dans l'uranium et ses alliages (1962)

    Energy Technology Data Exchange (ETDEWEB)

    Aubert, H. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1962-05-15

    The kinetics of the transformation of uranium alloys containing 0.5 - 0.75 - 1.0 - 1.5 and 3 atoms per cent have been studied. The influence of heat treatment before decomposition has been discussed. The study of the transformation characteristics such as kinetics, residual phases, phenomena connected with the coherence between phases, reversibility below the equilibrium temperature, shows the following mechanisms exhibited during the decomposition of the {beta} phase on lowering the temperature: 1 ) eutectoid, 2) bainitic, 3) martensitic. The study of the TTT diagrams of alloys containing decreasing percentages of chromium indicates that the unalloyed uranium transforms without maintaining the coherence above 600 deg. C, where as at lower temperatures the transformation is mainly martensitic. The various alloying elements can be characterised by their influence on the three TTT curves corresponding to the three possible transformation mechanisms. The ability of the uranium alloys to alpha grain refining during isothermal decomposition or ambient temperature quenching is directly connected with the characteristics of the TTT diagrams and especially to the mode of bainitic transformation. (author) [French] II a ete etudie la cinetique de transformation des alliages uranium-chrome de teneur 0,5 - 0,75 - 1 - 1,5 - et 3 atomes pour cent. L'influence des traitements thermiques precedant la decomposition a ete discutee. L'etude des caracteristiques de la transformation: cinetique, phases residuelles, phenomenes lies a la coherence entre phases, reversibilite au-dessous de la temperature d'equilibre, permet de conclure que la decomposition met en jeu successivement les trois mecanismes eutectoide, bainitique et martensitique quand la temperature baisse. L'etude de l'evolution des diagrammes TTT quand la teneur en Cr decroit indique que dans l'uranium non allie la transformation se fait sans maintien de la coherence au-dessus de 600 deg. C; a

  18. Contribution towards the study of {beta}{yields}{alpha} transformation in uranium and its alloys (1962); Contribution a l'etude de la transformation {beta}{yields}{alpha} dans l'uranium et ses alliages (1962)

    Energy Technology Data Exchange (ETDEWEB)

    Aubert, H [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1962-05-15

    The kinetics of the transformation of uranium alloys containing 0.5 - 0.75 - 1.0 - 1.5 and 3 atoms per cent have been studied. The influence of heat treatment before decomposition has been discussed. The study of the transformation characteristics such as kinetics, residual phases, phenomena connected with the coherence between phases, reversibility below the equilibrium temperature, shows the following mechanisms exhibited during the decomposition of the {beta} phase on lowering the temperature: 1 ) eutectoid, 2) bainitic, 3) martensitic. The study of the TTT diagrams of alloys containing decreasing percentages of chromium indicates that the unalloyed uranium transforms without maintaining the coherence above 600 deg. C, where as at lower temperatures the transformation is mainly martensitic. The various alloying elements can be characterised by their influence on the three TTT curves corresponding to the three possible transformation mechanisms. The ability of the uranium alloys to alpha grain refining during isothermal decomposition or ambient temperature quenching is directly connected with the characteristics of the TTT diagrams and especially to the mode of bainitic transformation. (author) [French] II a ete etudie la cinetique de transformation des alliages uranium-chrome de teneur 0,5 - 0,75 - 1 - 1,5 - et 3 atomes pour cent. L'influence des traitements thermiques precedant la decomposition a ete discutee. L'etude des caracteristiques de la transformation: cinetique, phases residuelles, phenomenes lies a la coherence entre phases, reversibilite au-dessous de la temperature d'equilibre, permet de conclure que la decomposition met en jeu successivement les trois mecanismes eutectoide, bainitique et martensitique quand la temperature baisse. L'etude de l'evolution des diagrammes TTT quand la teneur en Cr decroit indique que dans l'uranium non allie la transformation se fait sans maintien de la coherence au-dessus de 600 deg. C; a plus basse temperature la

  19. Model of a plasma without collisions in a cylindrical geometry by the study of the motions of the particles (1960); Modele d'un plasma sans collisions dans une geometrie cylindrique par l'etude des mouvements de particules (1960)

    Energy Technology Data Exchange (ETDEWEB)

    Rebut, P H [Association Euratom-CEA Cadarache, 13 - Saint-Paul-lez-Durance (France). Dept. de Recherches sur la Fusion Controlee

    1960-07-01

    The Boltzmann equation for a group of particles in the absence of collisions may be written df/dt = 0, where f is the distribution function in the phase space. This equation means that f is an individual motion constant. This leads to a study, of the paths and to a research of the first integrals of the differential system related to them. This study leads also to a confinement condition on the velocities of a particle. The following step is related to the theoretical study of some distribution functions and of the resulting consequences. A differential system is obtained, giving density and magnetic and electric fields. This system has been in a number of cases solved by a digital computer. This solution allows an experimental comparison to be made. The first integrals obtained are still valid when magnetic 'screw-type' fields are concerned, which results in the obtention of a type of helicoidal deformation and of a stability criteria with respect to these deformations. (author) [French] L'equation de Boltzmann pour un groupe de particules en l'absence de collision peut s'ecrire df/dt = 0, ou f est la fonction de distribution dans l'espace des phases. Cette equation signifie que f est une constante du mouvement individuel. On est donc amene a etudier les trajectoires et a rechercher des integrales premieres du systeme differentiel qui leur est lie; cette etude conduit aussi a une condition de confinement portant sur les vitesses d'une particule. L'etape suivante se rapporte a l'etude theorique de certaines fonctions de distribution et des consequences qui en decoulent. On arrive a un systeme differentiel donnant densite, champs magnetiques et electriques, systeme qui a ete resolu dans un certain nombre de cas par une machine a calculer digitale. Cette resolution permet une confrontation experimentale. Les integrales premieres obtenues restent encore valables lors de champs magnetiques en 'vis'; il en resulte l'obtention d'un type de deformation helicoidale et d

  20. Le changement comme tradition dans la recherche et la formation a la recherche en biotechnologie et en peripherie Etude de cas en sciences de la sante, sciences naturelles et genie

    Science.gov (United States)

    Bourque, Claude Julie

    Le champ de la recherche scientifique et de la formation a la recherche est traverse depuis quelques dizaines d'annees par plusieurs courants et discours associes au changement, mais peu de travaux empiriques permettent de comprendre ce qui change concretement. C'est la contribution originale de cette these au champ de l'education, plus specifiquement a l'etude sociologique de l'enseignement superieur ou sont concentrees les activites liees a la triade thematique du programme doctoral dans lequel elle a ete produite : recherche, formation et pratique. L'enquete-terrain a ete realisee en 2009 et 2010 aupres de 808 repondants affilies a 60 etablissements au Quebec et a produit un vaste materiau de nature mixte (donnees quantitatives et qualitatives). Un portrait de la nebuleuse biotechnologique qui touche les secteurs des sciences de la sante, des sciences naturelles et du genie a ete realise. Ce domaine concerne des dizaines de disciplines et se revele de nature transdisciplinaire, mais les pratiques n'y sont pas davantage marquees par le changement que celles d'autres domaines connexes. Les dynamiques sociales ont fait l'objet d'analyses comparatives dans quatre contextes: le choix des programmes, des objets et des methodes, le financement, la diffusion et la planification de la carriere. Les resultats indiquent que les echanges entre les agents traditionnellement situes au coeur des activites de recherche dominent ces dynamiques dans tous les contextes etudies. L'etude des representations au fondement des pratiques a revele l'existence de trois ecoles de pensee qui coexistent dans le champ scientifique: academique, pragmatique et economiste. Ces ecoles permettent de categoriser les agents en fonction des zones de fractures qui marquent leurs oppositions tout en identifiant ce qu'ils ont en commun. Les representations et les pratiques liees a la formation temoignent d'un habitus plutot homogene, alors que les contradictions semblent plus souvent ancrees dans des

  1. Contribution to the study of uranyl salts in butyl phosphate solutions; Contribution a l'etude des solutions de sels d'uranyle dans les phosphates butyliques

    Energy Technology Data Exchange (ETDEWEB)

    Coulon, A. [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1965-06-01

    A spectroscopic study in the normal infrared region and involving the following associations: tri-alkyl phosphates (tri-butyl, tri-ethyl, tri-methyl), uranyl salts (nitrate, chloride, acetate) has confirmed the existence of an interaction between the phosphoryl group and the uranium atom, as shown by a movement of absorption band for the valency P = 0 from {approx} 1270 cm{sup -1} to {approx} 1180 cm{sup -1}. A study of the preparation, analysis and spectroscopy of the solids obtained by the precipitation of uranyl salts by acid butyl phosphates has been carried out. By infrared spectrophotometry it has been shown that the tri-butyl and di-butyl phosphates are associated in non-polar diluents even before the uranium is introduced. The extraction of uranyl salts from acid aqueous solutions by a diluted mixture of tri-butyl and di-butyl phosphates proceeds by different mechanisms according to the nature of the ion (nitrate or chloride). (author) [French] Une etude spectroscopique dans l'infrarouge moyen portant sur les associations: - phosphates trialcoyliques (tributylique - triethylique - trimethylique) - sels d'uranyle (nitrate, chlorure, acetate) a confirme l'existence d'une interaction entre le groupement phosphoryle et l'atome d'uranium, se manifestant par un deplacement de la bande d'absorption de la vibration de valence P = 0 de {approx} 1270 cm{sup -1} a {approx} 1180 cm{sup -1}. Une etude preparative, analytique et spectroscopique des solides obtenus par precipitation de sels d'uranyle par les phosphates butyliques acides a ete effectuee. La spectrophotomerie infrarouge met en evidence l'association, anterieure a toute introduction d'uranium, des phosphates tributylique et dibutylique dans des diluants non polaires. L'extraction de sels d'uranyle, d'une solution aqueuse acide par un melange dilue de phosphates tributylique et dibutylique, s'effectue suivant des processus differents a la

  2. Main results obtained in France in the development of the gaseous diffusion process for uranium isotope separation; Principaux resultats obtenus en France dans les etudes sur la separation des isotopes de l'uranium par diffusion gazeuse

    Energy Technology Data Exchange (ETDEWEB)

    Frejacques, C; Bilous, O; Dixmier, J; Massignon, D; Plurien, P [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1958-07-01

    The main problems which occur in the study of uranium isotope separation by the gaseous diffusion process, concern the development of the porous barrier, the corrosive nature of uranium hexafluoride and also the chemical engineering problems related to process design and the choice of best plant and stage characteristics. Porous barriers may be obtained by chemical attack of non porous media or by agglomeration of very fine powders. Examples of these two types of barriers are given. A whole set of measurement techniques were developed for barrier structure studies, to provide control and guidance of barrier production methods. Uranium hexafluoride reactivity and corrosive properties are the source of many difficult technological problems. A high degree of plant leak tightness must be achieved. This necessity creates a special problem in compressor bearing design. Barrier lifetime is affected by the corrosive properties of the gas, which may lead to a change of barrier structure with time. Barrier hexafluoride permeability measurements have helped to make a systematic study of this point. Finally an example of a plant flowsheet, showing stage types and arrangements and based on a minimisation of enriched product costs is also given as an illustration of some of the chemical engineering problems present. (author) [French] Les principaux problemes qui se sont poses dans l'etude de la separation des isotopes de l'uranium par diffusion gazeuse, sont ceux relatifs a l'obtention de barrieres poreuses, ceux lies a l'utilisation de l'hexafluorure d'uranium, enfin les problemes de genie chimique relatifs au procede et a l'agencement optimum des etages et des cascades entre elles. On peut obtenir des barrieres poreuses soit par attaque de membranes pleines, soit par agglomeration de poudres de petites dimensions. Des exemples de ces deux types de barrieres seront donnes. L'etude des proprietes de texture des barrieres obtenues, necessaire pour orienter les recherches de

  3. Study of microinstabilities due to an anisotropic velocity distribution function of the particles of a homogeneous plasma; Etude des microinstabilities liees a l'anisotropie de la fonction de distribution des vitesses des particules d'un plasma homogene

    Energy Technology Data Exchange (ETDEWEB)

    Hennion, F [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1966-06-01

    A study is made of instabilities in a plasma with an ion velocity distribution function of the form: f{sub oi} = 1 / (2*{pi}*{alpha}{sub p}e{sub i}*{alpha}{sub p}a{sub i}) * {lambda}({nu}{sub p}e - {alpha}{sub p}e{sub i}) * e{sup -}(v{sub pa2}/{alpha}{sub pai2}). The plasma is assumed to have finite dimensions limited by infinitely conductive boundary surfaces. A theoretical and numerical analysis of marginal stability locates the regions of stability as a function of several parameters; i.e. plasma length, ion anisotropy ({tau}) and electron temperature (T{sub e}). A limiting plasma length is found, below which the plasma is stable regardless of its density. For the parameters of the injection experiment M.M.I.I. at Fontenay-aux-roses it is found that the type of instabilities studied here should not occur. (author) [French] L'etude est faite en choisissant une fonction de distribution des ions de la forme f{sub oi} = 1 / (2*{pi}*{alpha}{sub p}e{sub i}*{alpha}{sub p}a{sub i}) * {lambda}({nu}{sub p}e - {alpha}{sub p}e{sub i}) * e{sup -}(v{sub pa2}/{alpha}{sub pai2}) et en supposant une conductivite infinie sur les limites du plasma de dimensions finies. L'etude theorique et numerique de la stabilite marginale determine les domaines de stabilite qui sont etudies en fonction de plusieurs parametres: longueur du plasma, anisotropie des ions ({tau}), temperature electronique (T{sub e}). Il apparait une longueur limite du plasma au-dessous de laquelle le plasma est stable, independemment de la densite. L'application faite avec les valeurs des parametres de l'experience d'injection M.M.I.I, a Fontenay-aux-Roses permet de conclure a la non existence dans cet appareil du type d'instabilite etudie ici. (auteur)

  4. Feasibility study for the installation of a small hydro electric power plant; Etude de faisabilite. Petite centrale hydro-electrique au lieu dit 'Sous les Roches' a Sonceboz

    Energy Technology Data Exchange (ETDEWEB)

    Tissot, N. [MHyLab, Mini-Hydraulics Laboratory, Montcherand (Switzerland); Hausmann, H. [Hans Hausmann, Bevilard (Switzerland)

    2003-07-01

    This report for the Swiss Federal Office of Energy presents a technical, economical and ecological analysis of the feasibility of a small hydroelectric power plant at Sonceboz, in the Swiss Jura mountains. The power of the planed plant would typically be 500 kW for a water head of about 10 m. The study shows that, compared to one single turbine, a pair of Kaplan type turbines would be operational over a larger range of the river's water flow rate. This solution would be a little bit more costly but offer more flexibility for maintenance. Two maximum water flow rates are considered, 4.5 and 6 m{sup 3}/s respectively. According to the economical study, done with current electric kWh prices, both configurations are viable while the largest flow rate leads to a larger profit. The report is rounded up by a sensitivity analysis considering variations in annual power generation, electro-mechanical and construction cost as well as turbine efficiency. It indicates that this last factor could be crucial for the overall profitability. [French] Ce rapport est le resultat detaille de l'analyse technico-economique et ecologique de faisabilite de la realisation d'une petite centrale hydroelectrique basse chute qui pourrait exploiter une denivellation d'environ 10 m pour une puissance de l'ordre de 500 kW pres de Sonceboz dans le Jura suisse. L'etude montre que le couplage de deux turbines Kaplan offrirait une possibilite de fonctionnement sur une plus grande plage de flux ainsi qu'une plus grande flexibilite de maintenance, ceci pour un cout legerement superieur a l'option a une seule turbine. Les debits de 4.5 et 6 m{sup 3}/s sont consideres. L'etude economique montre que le debit de 6 m{sup 3}/s est plus rentable au prix de vente actuel du kWh. L'article se termine par une analyse de sensibilite sur les incertitudes concernant la production annuelle, les prix de l'electromecanique et du genie civil et le rendement des

  5. Study on the bound water of several high specific surface-area oxides (beryllia, alumina, silica-alumina); Etude de l'eau de constitution de plusieurs oxydes a grande surface specifique (glucine, alumine, silice-alumine)

    Energy Technology Data Exchange (ETDEWEB)

    Rouquerol, J. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-11-01

    This study is concerned with the bound water of several oxides (beryllia, alumina, silica-alumina) at different steps of their dehydration (heating temperatures between 150 and 1100 deg. C). The following techniques have been used simultaneously: Thermal analysis (a new method has been developed), nitrogen adsorption (study of the texture), Diborane hydrolysis (qualitative and quantitative analysis of surface water), Infra-red spectrography (in the absorption range of water), Nuclear magnetic resonance (in the resonance range of protons). Thanks to these different techniques, five kinds of bound water have been observed. Attention is called on the great influence of the thermal treatment conditions on the evolution of the products resulting from the decomposition of alumina {alpha}-trihydrate Al(OH){sub 3} and beryllium {alpha}-hydroxide, in the course of the dehydration. Moreover, the author emphasizes the peculiar properties of the two kinds of oxides (alumina and beryllia) prepared through a new method of treatment under low pressure and constant speed of decomposition. Such particular features concern mainly texture, bound water, and consequently, also catalytic activity. (author) [French] Ce travail porte sur l'eau de constitution de plusieurs oxydes (glucine, alumine, silice-alumine) aux differents degres de leur deshydratation (temperatures de traitement comprises entre 150 et 1100 deg. C). Cette etude met simultanement en oeuvre: l'analyse thermique (proposition d'une nouvelle methode), l'adsorption d'azote (etude de texture), l'hydrolyse du diborane (analyse qualitative et quantitative de l'eau de surface), la spectrographie infra-rouge (dans le domaine d'absorption de l'eau), la resonance magnetique nucleaire (dans le domaine de resonance des protons). A l'aide de ces differentes techniques, cinq formes d'eau de constitution ont ete observees. L'attention est attiree sur la tres grande influence

  6. Study on the bound water of several high specific surface-area oxides (beryllia, alumina, silica-alumina); Etude de l'eau de constitution de plusieurs oxydes a grande surface specifique (glucine, alumine, silice-alumine)

    Energy Technology Data Exchange (ETDEWEB)

    Rouquerol, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-11-01

    This study is concerned with the bound water of several oxides (beryllia, alumina, silica-alumina) at different steps of their dehydration (heating temperatures between 150 and 1100 deg. C). The following techniques have been used simultaneously: Thermal analysis (a new method has been developed), nitrogen adsorption (study of the texture), Diborane hydrolysis (qualitative and quantitative analysis of surface water), Infra-red spectrography (in the absorption range of water), Nuclear magnetic resonance (in the resonance range of protons). Thanks to these different techniques, five kinds of bound water have been observed. Attention is called on the great influence of the thermal treatment conditions on the evolution of the products resulting from the decomposition of alumina {alpha}-trihydrate Al(OH){sub 3} and beryllium {alpha}-hydroxide, in the course of the dehydration. Moreover, the author emphasizes the peculiar properties of the two kinds of oxides (alumina and beryllia) prepared through a new method of treatment under low pressure and constant speed of decomposition. Such particular features concern mainly texture, bound water, and consequently, also catalytic activity. (author) [French] Ce travail porte sur l'eau de constitution de plusieurs oxydes (glucine, alumine, silice-alumine) aux differents degres de leur deshydratation (temperatures de traitement comprises entre 150 et 1100 deg. C). Cette etude met simultanement en oeuvre: l'analyse thermique (proposition d'une nouvelle methode), l'adsorption d'azote (etude de texture), l'hydrolyse du diborane (analyse qualitative et quantitative de l'eau de surface), la spectrographie infra-rouge (dans le domaine d'absorption de l'eau), la resonance magnetique nucleaire (dans le domaine de resonance des protons). A l'aide de ces differentes techniques, cinq formes d'eau de constitution ont ete observees. L'attention est attiree sur la tres grande influence des conditions de traitement thermique sur l'evolution des

  7. A comparative study of the {sup 90}Sr/Ca ratio in human diet and bone tissue; Etude comparee chez l'homme du rapport {sup 90}Sr/Ca dans l'alimentation et le tissu osseux

    Energy Technology Data Exchange (ETDEWEB)

    Coulon, R; Madelmont, C [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1969-07-01

    A comparative study of both the evolution of strontium-90 content in the bones of individuals of different ages for the period 1962-1967 as related to calcium, and the corresponding diets allowed to establish the relationship between food contribution and the resulting bone burden. The study is mainly devoted to the group of adults for which a mathematical expression is proposed which allows for the exchangeable form of a skeletal calcium fraction turned over in less than a year from the dietary calcium, and the stabilized form constituting the larger part of bone tissue characterized by a slow turnover. Both the amount of the exchangeable fraction and the turnover rate of the stabilized fraction are determined for vertebrae and ribs. At birth, bone levels indicate that the calcium used for skeleton modelling during foetal life originates from both maternal diet and bone tissue and a value is given, to their relative significance. There appears a good relationship between bone levels in infants from 6 months to 1 year of age and their diets. The physiological parameters particular to this age are quantified. (authors. [French] L'etude comparee de l'evolution de la teneur en strontium 90 rapportee au calcium, mesuree dans les os d'individus a differents ages durant la periode 1962-1967 et celle du regime alimentaire correspondant, a permis d'etablir la relation qui existe entre l'apport du a l'alimentation et la charge osseuse qui en resulte. L'essentiel de l'etude est consacre au cas des adultes. Pour ce groupe la formulation mathematique proposee tient compte de la presence de la forme echangeable d'une fraction du calcium osseux, renouvelee en moins d'un an a partir du calcium alimentaire, et de la forme stabilisee, constituant la majeure partie du tissu osseux, caracterisee par un renouvellement lent. L'importance de la fraction echangeable, ainsi que le taux de renouvellement de la fraction stabilisee sont etablis pour les vertebres et les cotes. La

  8. Study of the form factors of the leptonic decays of the K{sub L}{sup 0}; Etude des facteurs de forme des desintegrations leptoniques du K{sub L}{sup 0}

    Energy Technology Data Exchange (ETDEWEB)

    Zylberajch, S [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1969-04-01

    About 24 000 K{sub L}{sup 0} decays have been observed in a spark chamber spectrometer. 11 000 K{sub e3} and 7 000 K{sub {mu}}{sub 3} decays were identified and their distribution in the Dalitz plot analyzed. In the study of the K{sub {mu}}{sub 3} mode K{sub L}{sup 0} {yields} {pi}{sup {+-}} {mu}{sup {+-}} the interaction is found to be essentially a vectorial one. For the ratio {xi} = f{sub -} / f{sub +} a double solution is found: {xi} = -3.9 {+-} 0.18 and {xi} = 1.5 {+-} 0.18. The first solution is more likely. The study of the K{sub e3} mode K{sub L}{sup 0} {yields} {pi}{sup {+-}} e{sup {+-}} {nu} also confirms the vectorial nature of the interaction. It is found that: | A{sub S} /A{sub V} | < 11 per cent; | A{sub T} /A{sub V} | < 6 per cent. The q{sup 2} dependence of the form factor f{sub +} is weak: {lambda}{sub +} = 0.023 {+-} 0.012. (author) [French] Environ 24 000 desintegrations du K{sub L}{sup 0} ont ete observees et etudiees a l'aide de chambres a etincelles. 11 000 K{sub e3} et 7000 K{sub {mu}}{sub 3} ont ete identifies et etudies en analysant leur repartition dans le diagramme de Dalitz. L'etude du mode K{sub {mu}}{sub 3}: K{sub L}{sup 0} {yields} {pi}{sup {+-}} {mu}{sup {+-}} a confirme la nature essentiellement vectorielle de l'interaction. On trouve pour le rapport {xi} = f{sub -} / f{sub +} une double solution: {xi} = -3.9 {+-} 0.18 and {xi} = 1.5 {+-} 0.18. La premiere est la plus probable. L'etude du mode K{sub e3}: K{sub L}{sup 0} {yields} {pi}{sup {+-}} e{sup {+-}} {nu} confirme egalement la nature vectorielle de l'interaction avec | A{sub S} /A{sub V} | < 11 pour cent; | A{sub T} /A{sub V} | < 6 pour cent. Le facteur de forme f{sub +} varie peu avec le moment transfere. On trouve: {lambda}{sub +} = 0.023 {+-} 0.012. (auteur)

  9. Fast neutron breeder reactor Rapsodie - situation of physics, hydraulic, thermal and dynamics studies and studies of stability early in 1963; Pile rapide rapsodie - point des etudes neutroniques, hydrauliques, thermiques et dynamiques et des etudes de stabilite au debut de l'annee 1963

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1964-07-01

    ) [French] Au debut de 1963, il a ete necessaire de faire un choix entre les deux combustibles etudies pour Rapsodie: l'alliage UPuMo avec double gainage Nb et acier inoxydable et l'oxyde mixte UO{sub 2}-PuO{sub 2}. Ce rapport donne les resultats des etudes menees avec les deux types de combustible. On rappelle d'abord les differents modeles qui ont ete etudies et on donne une description detaillee de coeurs alliage et oxyde tels qu'ils sont envisages au debut de 1963. On rapporte ensuite les principales caracteristiques neutroniques des deux coeurs: flux et spectre des neutrons, valeur des barres de securite - compensation, economie des neutrons, puissance specifique, fraction effective des neutrons retardes, temps de vie des neutrons prompts, coefficients de reactivite. On decrit les etudes et essais hydrauliques qui ont ete faits a propos de ces deux coeurs. On discute les criteres qui ont ete a l'origine des calculs de debits. On donne les resultats des essais de pertes de charge, de soulevement des assemblages, de vibration et d'ecoulement fin entre les aiguilles. On discute les constantes utilisees pour les calculs thermiques et on donne les temperatures maximales du sodium et des combustibles alliage et oxyde, les majorations dues aux points chauds et la limitation du taux de combustion de l'aiguille oxyde ayant pour origine la pression des gaz de fission. On rapporte les hypotheses qui ont ete utilisees pour les calculs dynamiques et l'on decrit les differents incidents qui ont ete etudies. On donne les resultats des calculs, pour chaque incident et pour chaque combustible et l'on montre que l'on peut eviter la fusion du combustible ou l'ebullition du sodium, meme dans le cas des hypotheses les plus pessimistes, en agissant sur les caracteristiques de la pile (valeur de la barre de pilotage ou puissance de la pile avec un seul circuit de refroidissement). La stabilite de la pile a ete evaluee avec les hypotheses utilisees pour les calculs dynamiques, a l

  10. The atomic energy course of the 'Institut National des Sciences et Techniques nucleaires' at the centre d'Etudes Nucleaires at Saclay; L'enseignement de genie atomique de l'Institut national des Sciences et Techniques nucleaires au Centre d'Etudes nucleaires de Saclay

    Energy Technology Data Exchange (ETDEWEB)

    Baissas, H [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1958-07-01

    foreign students. 8- Annexe: list of courses, practical work, pile projects drawn up by the 1957 students. (author)Fren. [French] 1- Les raisons de sa creation. L'electricite de France et l'industrie interessee par le developpement de l'Energie atomique ont demande au Commissariat a l'Energie atomique de former des ingenieurs capables d'etudier des projets de piles et de diriger leur construction. 2- Recrutement et Droits d'inscription. Les demandes d'inscription ont toujours depasse les possibilites. Cette annee, les cours sont suivis par 74 eleves permanents, dont 20 etrangers, et une centaine d'auditeurs libres. Tous les elevont deja ingenieurs ou nantis de grades universitaires eleves. Droit d'inscription: 250 000 F pour les eleves, 125 000 F pour les auditeurs. 3- Organisation de l'Enseignement. II comprend deux options: physique et chimie et dans chaque option: une centaine de conferences, une trentaine de travaux pratiques, des stages dans les services, l'etude d'un projet de reacteur par un groupe de 4 ou 5 eleves. L'ensemble occupe l'annee universitaire du 1 novembre au 14 juillet. 4- Sanction. Un examen final combinant les notes de deux epreuves theoriques, des travaux pratiques, du stage, et du projet conduit a un diplome d'ingenieur en genie atomique. Il n'est pas cree en realite de nouveaux ingenieurs; une mention nouvelle est seulement ajoutee a un diplome deja acquis. Les resultats ont toujours ete excellents. Le pourcentage des echecs est tres faible. 5- Placement des Diplomes. Ils reviennent tous dans leurs industries d'origine qui ont paye leurs salaires et les droits d'inscription en se privant de leurs services pendant les neuf mois de duree des cours. 6- Creations analogues. Un cours analogue a ete cree au Centre d'Etudes Nucleaires de Grenoble. Tandis que celui de SACLAY s'adresse plus specialement aux ingenieurs deja en fonctions, celui de Grenoble est, en principe, destine aux jeunes ingenieurs sortant des ecoles. 7- Conclusion. L

  11. Design of the fuel element 'snow-flake' in uranium oxide, canned with aluminium, for the experimental reactor EL 3 (1960); Etude d'un element combustible en oxyde d'uranium gaine d'aluminium, type ''cristal de neige'' pour la pile EL 3 (1960)

    Energy Technology Data Exchange (ETDEWEB)

    Gauthron, M; Guibert, B [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1960-07-01

    This report sums up the main studies have been carried out on the fuel element 'Snowflake' (uranium oxide, canned with aluminium), designed to replace the present element of the experimental reactor EL3 in order to increase the reactivity without modifying the neutron flux/thermal power ratio. (author) [French] Ce rapport resume les principales etudes qui ont ete faites sur l'element combustible 'Cristal de Neige' (a oxyde d'uranium, gaine d'aluminium) destine a remnlacer l'element actuel du reacteur experimental EL3, afin d'en augmenter la reactivite sans modifier le rapport flux neutronique-puissance thermique. (auteur)

  12. Contribution to the study of 14 MeV neutron scattering by {sup 12}C using a time-of-flight spectrometer (1963); Contribution a l'etude de la diffusion des neutrons de 14 MeV par {sup 12}C, a l'aide d'un spectrometre a temps de vol (1963)

    Energy Technology Data Exchange (ETDEWEB)

    Perrin, P [Commisariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1963-07-15

    Experimental measurements of 14 MeV fast neutrons scattering by {sup 12}C by time-flight spectrometer, with a 1.7 n. sec over-all resolution. The excitation of the 7.65 MeV level is observed. (author) [French] Etude experimentate de la diffusion par {sup 12}C des neutrons rapides de 14 MeV a l'aide d'un spectrometre de resolution totale de 17 n/s. Observation de l'excitation du niveau 0+ de 7,65 MeV. (auteur)

  13. Chrono-potentiometry in molten chlorides. Application to the study of the electrochemical properties of uranium and plutonium in the LiCl-KCl eutectic; Chronopotentiometrie dans les chlorures fondus. Application a l'etude des proprietes electrochimiques de l'uranium et du plutonium dans l'eutectique LiCl-KCl

    Energy Technology Data Exchange (ETDEWEB)

    Leseur, A. [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1969-05-01

    Using solutions of cadmium chloride in the eutectic LiCl-KCl, a chrono-potentiometric method has been developed with a view to its application to the study of molten solutions. Particular attention has been paid to the choice of the indicator electrodes. The method makes it possible to analyze molten solutions quantitatively and to determine diffusion coefficients and their activation energies; it yields furthermore information about the nature and the behaviour of ionic species in solution. The method has been applied to the study of solutions of uranium and plutonium chloride in the eutectic LiCl-KCl. Linear chrono-amperometry has been used for studying these solutions quantitatively, but chrono-potentiometry, of which the theory is better developed, is better suited to a quantitative study. The results obtained have made it possible to determine the diffusion coefficients of the ions Cd{sup 2+}, U{sup 3+}, U{sup 4+} and U(IV) in the presence of F{sup -} and Pu{sup 3+} ions, as well as the activation energy of the diffusion coefficients. (author) [French] La mise au point de la chronopotentiometrie comme moyen d'etude des solutions fondues a ete effectuee avec des solutions de chlorure de cadmium dans l'eutectique LiCl-KCl. Le probleme du choix des electrodes indicatrices a ete particulierement etudie. La methode permet l'analyse quantitative des solutions fondues ainsi que la determination des coefficients de diffusion et de leurs energies d'activation: elle donne en outre des renseignements sur la nature et le comportement des especes ioniques en solution. Elle a ete appliquee a l'etude des solutions des chlorures d'uranium et de plutonium dans l'eutectique LiCl-KCl. La chronoamperometrie lineaire a ete utilisee pour l'etude qualitative de ces solutions, mais la chronopotentiometrie, dont la theorie est plus complete, convient mieux pour l'etude quantitative. Les resultats obtenus ont permis de determiner les

  14. Contribution to the study of radio toxicity of aromatic and medicinal plants using solid state nuclear track detectors; Contribution a l etude de la radio toxicite des plantes aromatiques et medicinales au moyen des detecteurs solides de traces nucleaires

    Energy Technology Data Exchange (ETDEWEB)

    Mortassim, A; Misdaq, M A; Naaman, A

    2009-07-01

    The concentrations of uranium (238 U), thorium (232 Th), radon (222 Rn) and thoron (220 Rn) were measured in twenty aromatic and medicinal plants in {sup f}ind a new method based on using solid state nuclear track detectors type Cr-39 and Rs-115. He emerges from this study that the verbena and salvia have higher levels of uranium (radon) higher than that of other plants while the leaves of olive and saturja have concentrations of thorium (thoron) higher than other plants therefore radio toxicity of these plants is higher than that of others and may pose a radiological hazard if the masses are incorporated by consumers high. [French] Les concentrations en uranium (238U), thorium (232Th), radon (222Rn), et thoron (220Rn) ont ete mesurees dans vingt plantes aromatiques et medicinales en utilsant une nouvelle methode basee sur l utilisation des detecteurs solides de traces nucleaires de types CR-39 et LR-115. Il en sort de cette etude que la verveine et la salvia presentent des teneurs en uranium (radon) superieurs a celle des autres plantes alors que les feuilles d olivier et la saturja presentent des concentrations en thorium (thoron) plus elevee que celles des autres plantes par consequent la radio toxicite de ces plantes est superieure a celles des autres et peuvent presenter un risque radiologique si les masses incorporees par les consommateurs sont elevees.

  15. Study of the radiation around a high energy accelerator. Production and scattering of cascade neutrons; Etude du rayonnement autour d'un accelerateur de haute energie. Production et diffusion des neutrons de cascade

    Energy Technology Data Exchange (ETDEWEB)

    Tardy-Joubert, P [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1966-03-01

    The cascade induced in protective screens by a 3 GeV proton beam has been studied using activation detectors; the results have been compared with the cosmic neutron spectrum in the atmosphere. A study of the secondary neutron spectrum has made, it possible to obtain the distribution of the dose and to determine the maximum permissible fluxes expressed in terms of the energy, taking into account all the daughter products present. The dose calculated has been checked experimentally. The proportion of cascade neutrons has been studied using the idea of an imaginary source. The parameters which have to be introduced into the general equations to take into account scattering in the the air have been determined. (author) [French] La cascade induite dans les ecrans de protection par un faisceau de protons de 3 GeV a ete etudiee au moyen de detecteurs a activation et la comparaison a ete faite avec le spectre des neutrons cosmiques dans l'atmosphere. L'etude du spectre des neutrons secondaires a permis de preciser la distribution de la dose et de determiner les flux maximaux admissibles qui sont exprimes en fonction de l'energie, en tenant compte de l'ensemble des descendants presents. La dose calculee a ete verifiee experimentalement. La propagation des neutrons de cascade a ete etudiee en introduisant la notion de source fictive. Les parametres a introduire dans les equations generales pour rendre compte de la diffusion dans l'air ont ete determines. (auteur)

  16. The accelerator tube of ions of the generator Van de Graaff of the CEA. Survey of development. First results; Le tube accelerateur d'ions du generateur van de graapp du commissariat. Etude de developpement. Premiers resultats

    Energy Technology Data Exchange (ETDEWEB)

    Bruck, H.; Prevot, F. [Commissariat a l' Energie Atomique, Saclay(France). Centre d' Etudes Nucleaires

    1953-07-01

    Rare are the Van de Graaff supplies whose tube doesn't collapse electrically to tensions and currents very lower to those that the generator can provide. We chose the general measurements: length and diameter, and put the accent on the survey of the individual element, so much to the mechanical viewpoint (installation, solidity, tightness and degassing), that to the electric viewpoint (to increase the electric rigidity of it). After modification the breakdown voltage as well as the performances of the tube have been improved greatly. (M.B.) [French] Rares sont les machines de Van de Graaff dont le tube ne s'effondre pas electriquement a des tensions et des courants bien inferieurs a ceux que le generateur peut fournir. Nous avons choisi les dimensions generales: longueur et diametre, et mis l'accent sur l'etude de l'element individuel, tant au point de vue mecanique (montage, solidite, etancheite et degazage), qu'au point de vue electrique (pour en augmenter la rigidite electrique). Apres modification la tension de claquage ainsi que les performances du tube ont ete grandement ameliorees. (M.B.)

  17. A contribution to the study of radioactive waste dilution in the Rhone involving tests with a rhodamine B tracer; Contribution a l'etude de la dilution des effluents radioactifs dans le Rhone par le rejet experimental de rhodamine B

    Energy Technology Data Exchange (ETDEWEB)

    Rodier, J.; Marichal, M. [Commissariat a l' energie atomique et aux energies alternatives - CEA, Centre de production de plutonium de Marcoule, Service de protection contre les radiations (France)

    1961-07-01

    The process whereby waste from the Marcoule plant mixes with the water in the Rhone was followed in tests with rhodamine as a chemical tracer. Satisfactory dispersion was noted less than 4 km downstream from the waste discharge duct outlet, and the degree of homogeneity was considered to be satisfactory at the bridge of Roquemaure, und perfect at Avignon. This investigation not only revealed a complete absence of any preferential flow paths containing high radioactive waste concentrations, but it also enabled the most representative points to be selected at which to take Rhone water samples during future radioactive waste discharges. Reprint of a paper published in 'La Houille Blanche' N. 5 - Aug 196, p. 636-641 [French] L'emploi de la rhodamine comme traceur chimique a permis de suivre l'evolution du melange des effluents du Centre de Marcoule aux eaux du Rhone. La dispersion est deja satisfaisante a moins de 4 km en aval de la conduite des rejets, et l'homogeneite peut etre consideree comme atteinte au pont de Roquemaure et parfaite a Avignon. Cette etude a montre que les veines preferentielles ou se concentrait l'ecoulement des effluents radioactifs n'existent pas. Elle a permis de preciser en outre les emplacements les plus representatifs des points d'echantillonnage des eaux du Rhone au cours des rejets. Reproduction d'un article publie dans 'La houille blanche' N. 5 - Aug 196, p. 636-641.

  18. A Study of the Radioprotective Activity of the Imidazole Nucleus and Some of Its Derivatives; Etude de l'activite radioprotectrice du noyau imidazole et de quelquesuns de ses derives

    Energy Technology Data Exchange (ETDEWEB)

    Rinaldi, R; Bernard, Y [Commissariat a l' Energie Atomique. Centre d' Etudes Nucleaires, 38 - Grenoble (France)

    1962-07-01

    A study was made of the radioprotective properties of 8 compounds derived from imidazole. The effectiveness of the compounds was tested in mice exposed to a lethal dose of x radiation. Results showed that imidazole afforded protection to about 85% of the animals. Little protection was afforded by imidazoline and thione-imidazoline compounds in spite of the existence of a free sulfhydryl group in these compounds. (authors) [French] Cette etude a ete consacree a la determination des proprietes radioprotectrices eventuelles de huit composes derives de l'imidazole. Ces substances ont ete, soit synthetisees, soit obtenues dans le commerce. Leur efficacite a ete mise en evidence par le pourcentage de survie obtenu chez des souris soumises a une dose mortelle de rayons X. Les resultats ont fait apparaitre: - l'activite remarquable de l'imidazole qui protege environ 85 pour cent des animaux; - la protection faible ou nulle obtenue avec les imidazolinones et les thione-imidazolines, malgre la presence dans la molecule de ces dernieres d'un groupement sulfhydrile libre. (auteurs)

  19. Magnetic study of a few antiferromagnets in very-strong pulsed fields (450 kOE); Etude magnetique de quelques antiferromagnetiques dans des champs pulses tres intenses (450 k OE)

    Energy Technology Data Exchange (ETDEWEB)

    Krebs, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1968-01-01

    In this thesis we describe a pulsed field device with which we obtain magnetization curves up to 450 kOE at all temperatures between 1. 6 and 300. We have studied the 'spin-flopping'(and therefore the anisotropy) in MnF{sub 2} versus temperature, below the Neel point. We have also studied the antiferromagnets MnSO{sub 4}. and MnSO{sub 4}.H{sub 2}O which have revealed saturation fields respectively of 250 kOE and 320 kOE. (author) [French] Ce memoire est consacre a la fabrication et a la mise au point d'un app